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Sample records for knoop hardness values

  1. Influence of curing tip distance on composite Knoop hardness values.

    PubMed

    Sobrinho, L C; de Lima, A A; Consani, S; Sinhoreti, M A; Knowles, J C

    2000-01-01

    The purpose of this paper was to study the influence of curing tip distance on Knoop hardness values, at different depths, of two composites, Z100 and Silux Plus. Specimens (5 mm in diameter and 2.5 mm in height) were prepared in a copper mold, covered with mylar strip and polymerized for 40 s, at 3 tip-to-composite surface distances: 0 mm (surface contact), 6 and 12 mm, utilizing an XL 3000 curing unit, with 750 mW/cm2 power. The specimens were then stored at 37 degrees C for 24 h. Knoop hardness values were measured using a microhardness tester, with a load of 50 g for 30 s for each indentation. Four specimens were made for each distance and composite and eighteen indentations were made of each specimen. The results were submitted to analysis of variance and Tukey test at 5% significance level. The results indicated that 1) composite Z100: the larger the curing tip distance in relation to the composite, the lower the Knoop hardness values; 2) Silux Plus: increasing the curing tip distance did not produce a statistically significant difference in the Knoop hardness values; however, at 6 and 12 mm, the deeper layers showed lower Knoop hardness values in relation to the surface; 3) Z100: statistically superior in relation to Silux Plus at all three curing tip distances and at all depths (P < 0.05).

  2. Knoop Hardness - Apparent Yield Stress Relationship in Ceramics

    SciTech Connect

    Swab, Jeffrey J; LaSalvia, Jerry; Wereszczak, Andrew A; Strong, Kevin T; Danna, Dominic; Ragan, Meredith E; Ritt, Patrick J

    2012-01-01

    In Tabor's classical studies of the deformation of metals, the yield stress (Y) and hardness (H) were shown to be related according to H/Y {approx} 3 for complete or fully plastic deformation. Since then it has been anecdotally shown for ceramics that this ratio is <3. Interest exists to explore this further so Hertzian indentation was used to measure the apparent yield stress of numerous ceramics and metals and their results were compared with each material's load-dependent Knoop hardness. The evaluated ceramics included standard reference materials for hardness (silicon nitride and tungsten carbide), silicon carbide, alumina, and glass. Several steel compositions were also tested for comparison. Knoop hardness measurements at 19.6 N (i.e., toward 'complete or fully plastic deformation'), showed that 2 < H/Y < 3 for the metals and 0.8 < H/Y < 1.8 for the glasses and ceramics. Being that H/Y {ne} 3 for the ceramics indicates that Tabor's analysis is either not applicable to ceramics or that full plastic deformation is not achieved with a Knoop indentation or both.

  3. Influence of photoactivation method and mold for restoration on the Knoop hardness of resin composite restorations.

    PubMed

    Brandt, William Cunha; Silva-Concilio, Lais Regiane; Neves, Ana Christina Claro; de Souza-Junior, Eduardo Jose Carvalho; Sinhoreti, Mario Alexandre Coelho

    2013-09-01

    The aim of this study was to evaluate in vitro the Knoop hardness in the top and bottom of composite photo activated by different methods when different mold materials were used. Z250 (3M ESPE) and XL2500 halogen unit (3M ESPE) were used. For hardness test, conical restorations were made in extracted bovine incisors (tooth mold) and also metal mold (approximately 2 mm top diameter × 1.5 mm bottom diameter × 2 mm in height). Different photoactivation methods were tested: high-intensity continuous (HIC), low-intensity continuous (LIC), soft-start, or pulse-delay (PD), with constant radiant exposure. Knoop readings were performed on top and bottom restoration surfaces. Data were submitted to two-way ANOVA and Tukey's test (p = 0.05). On the top, regardless of the mold used, no significant difference in the Knoop hardness (Knoop hardness number, in kilograms-force per square millimeter) was observed between the photoactivation methods. On the bottom surface, the photoactivation method HIC shows higher means of hardness than LIC when tooth and metal were used. Significant differences of hardness on the top and in the bottom were detected between tooth and metal. The photoactivation method LIC and the material mold can interfere in the hardness values of composite restorations.

  4. Halogen and LED light curing of composite: temperature increase and Knoop hardness.

    PubMed

    Schneider, L F; Consani, S; Correr-Sobrinho, L; Correr, A B; Sinhoreti, M A

    2006-03-01

    This study assessed the Knoop hardness and temperature increase provided by three light curing units when using (1) the manufacturers' recommended times of photo-activation and (2) standardizing total energy density. One halogen--XL2500 (3M/ESPE)--and two light-emitting diode (LED) curing units--Freelight (3M/ESPE) and Ultrablue IS (DMC)--were used. A type-K thermocouple registered the temperature change produced by the composite photo-activation in a mold. Twenty-four hours after the photo-activation procedures, the composite specimens were submitted to a hardness test. Both temperature increase and hardness data were submitted to ANOVA and Tukey's test (5% significance). Using the first set of photo-activation conditions, the halogen unit produced a statistically higher temperature increase than did both LED units, and the Freelight LED resulted in a lower hardness than did the other curing units. When applying the second set of photo-activation conditions, the two LED units produced statistically greater temperature increase than did the halogen unit, whereas there were no statistical differences in hardness among the curing units.

  5. Dual resin cement knoop hardness after different activation modes through dental ceramics.

    PubMed

    Valentino, Thiago Assunção; Borges, Gilberto Antonio; Borges, Luis Henrique; Vishal, Jain; Martins, Luis Roberto Marcondes; Correr-Sobrinho, Lourenço

    2010-01-01

    This study investigated the influence of ceramic compositions on Knoop Hardness Number (KHN) immediately and 24 h after polymerization and the effect of activation modes on the KHN of a resin cement. Ten Panavia F 2.0 resin cement discs were activated either directly using curing light, or chemically without light, or through 1.2-thick ceramic discs. The following ceramics were evaluated: Duceram, Cergogold, IPS Empress, IPS Empress 2, Procera, Cercon, In Ceram Alumina and In Ceram Zirconia. The KHN was obtained immediately and after 24-h testing time. Two-way ANOVA and Tukey's test were performed for statistical analysis (p<0.05). Direct activation showed higher KHN than activation through ceramics and chemical activation for both immediate and 24-h post activation. The KHN for 24-h post activation time was higher than that of the immediate post activation time except for the direct activation mode. The glass and di-silicate based ceramics showed higher KHN than alumina- and zirconia-based ceramics, immediately and after 24-h. The reinforced and opaque ceramics had the lowest KHN. The ceramic composition resulted in light attenuation, lower polymerization and lower KHN, and the 24-h testing time promoted an improvement of KHN except for direct activation mode.

  6. Influence of irradiance on Knoop hardness, degree of conversion, and polymerization shrinkage of nanofilled and microhybrid composite resins.

    PubMed

    Fugolin, Ana Paula Piovezan; Correr-Sobrinho, Lourenço; Correr, Américo Bortolazzo; Sinhoreti, Mário Alexandre Coelho; Guiraldo, Ricardo Danil; Consani, Simonides

    2016-01-01

    The purpose of this study was to investigate the influence of the irradiance emitted by a light-curing unit on microhardness, degree of conversion (DC), and gaps resulting from shrinkage of 2 dental composite resins. Cylinders of nanofilled and microhybrid composites were fabricated and light cured. After 24 hours, the tops and bottoms of the specimens were evaluated via indentation testing and Fourier transform infrared spectroscopy to determine Knoop hardness number (KHN) and DC, respectively. Gap width (representing polymerization shrinkage) was measured under a scanning electron microscope. The nanofilled composite specimens presented significantly greater KHNs than did the microhybrid specimens (P < 0.05). The microhybrid composite resin exhibited significantly greater DC and gap width than the nanofilled material (P < 0.05). Irradiance had a mostly material-dependent influence on the hardness and DC, but not the polymerization shrinkage, of composite resins. PMID:26943085

  7. Effect of different light-curing devices and aging procedures on composite knoop microhardness.

    PubMed

    Voltarelli, Fernanda Regina; dos Santos-Daroz, Claudia Batitucci; Alves, Marcelo Corrêa; Peris, Alessandra Rezende; Marchi, Giselle Maria

    2009-01-01

    The aim of this study was to evaluate the effect of light-curing devices (Halogen/HAL, Light Emitting Diodes/LED, Argon Laser/LAS and Plasma Arc/PAC) and aging procedures (Mechanical Cycling/MC, Thermal Cycling/TC, Storage/S, MC+TC and MC+TC+S) on the micro-hardness of bottom/B and top/T surfaces of 2-mm-high composite resin cylinders. The Knoop microhardness test (25 g, 20 s) on both B and T was performed before and after each aging procedure. For B and T, before aging procedures, PAC showed reduced polymerization effectiveness when compared with HAL. In the T, after TC, PAC and LAS had also showed reduced polymerization effectiveness when compared to HAL and LED. For all light-curing devices, MC+TC+S and S affected the Knoop microhardness values. In the B, no difference could be observed among the aging procedures for PAC. From all light-curing units, PAC may have rendered composites of reduced quality and the storage aging procedures were the most harmful to the polymer hardness.

  8. Elasticity and hardness of nano-polycrystalline boron nitrides: The apparent Hall-Petch effect

    SciTech Connect

    Nagakubo, A.; Ogi, H. Hirao, M.; Sumiya, H.

    2014-08-25

    Nano-polycrystalline boron nitride (BN) is expected to replace diamond as a superhard and superstiff material. Although its hardening was reported, its elasticity remains unclear and the as-measured hardness could be significantly different from the true value due to the elastic recovery. In this study, we measured the longitudinal-wave elastic constant of nano-polycrystalline BNs using picosecond ultrasound spectroscopy and confirmed the elastic softening for small-grain BNs. We also measured Vickers and Knoop hardness for the same specimens and clarified the relationship between hardness and stiffness. The Vickers hardness significantly increased as the grain size decreased, while the Knoop hardness remained nearly unchanged. We attribute the apparent increase in Vickers hardness to the elastic recovery and propose a model to support this insight.

  9. The effect of annealing on the Knoop microhardness of nitrogen implanted Ti6Al4V alloy

    NASA Astrophysics Data System (ADS)

    Nath, V. C.; Sood, D. K.; Manory, R. R.

    1991-07-01

    The implantation of the Ti6Al4V alloy with nitrogen has been previously studied, and the treatment has been shown to improve the microhardness significantly [R.G. Vardiman, Defect and Diffusion Forum 57/58 (1988) 135, and references therein]. The effects of post-implantation annealing on the properties has not been studied systematically, and this is the principal aim of the RMIT work. Initial results of this study are presented and discussed. It was found that N + implantation of this alloy at 80 keV with fluences varying in the range (0.5-1.5) × 10 17ions/cm 2 caused an improvement in Knoop hardness up to 100%. Rutherford backscattering results show a buried layer containing up to 25% nitrogen in the as-implanted specimens at a depth of 130 nm. After annealing the sample implanted with 1.5 × 10 17 at 705°C, both the nitrogen concentration and the depth of the layer decrease to approximately half of their as-implanted values. The observed reduction in hardness can be attributed to the decrease in the nitrogen concentration of the buried layer, as well as to repair of the lattice. These results may indicate that only a limited amount of TiN forms directly during implantation.

  10. In-depth polymerization of dual-cured resin cement assessed by hardness.

    PubMed

    Reges, Rogério V; Moraes, Rafael R; Correr, Américo B; Sinhoreti, Mário A C; Correr-Sobrinho, Lourenço; Piva, Evandro; Nouer, Paulo R A

    2008-07-01

    This study investigates the in-depth polymerization of dual-cured resin cement (Enforce; Dentsply, shades A2, B1, and opaque). Cylindrical specimens are obtained by photo-activation through ceramic. Control samples are light-cured without using ceramic. Samples are tested after 15 min or 24 h. Knoop hardness readings are made at 100, 300, 500, and 700 microm depth. Hardness is generally dependent on the mode of activation and post-cure time. Shades A2 and B1 show higher hardness values than opaque resin. Hardness at 100 microm is higher than at 700 microm. A linear relationship between hardness and depth is observed.

  11. Determination of the Mechanical Properties of Plasma-Sprayed Hydroxyapatite Coatings Using the Knoop Indentation Technique

    NASA Astrophysics Data System (ADS)

    Hasan, Md. Fahad; Wang, James; Berndt, Christopher

    2015-06-01

    The microhardness and elastic modulus of plasma-sprayed hydroxyapatite coatings were evaluated using Knoop indentation on the cross section and on the top surface. The effects of indentation angle, testing direction, measurement location and applied load on the microhardness and elastic modulus were investigated. The variability and distribution of the microhardness and elastic modulus data were statistically analysed using the Weibull modulus distribution. The results indicate that the dependence of microhardness and elastic modulus on the indentation angle exhibits a parabolic shape. Dependence of the microhardness values on the indentation angle follows Pythagoras's theorem. The microhardness, Weibull modulus of microhardness and Weibull modulus of elastic modulus reach their maximum at the central position (175 µm) on the cross section of the coatings. The Weibull modulus of microhardness revealed similar values throughout the thickness, and the Weibull modulus of elastic modulus shows higher values on the top surface compared to the cross section.

  12. Traceability in hardness measurements: from the definition to industry

    NASA Astrophysics Data System (ADS)

    Germak, Alessandro; Herrmann, Konrad; Low, Samuel

    2010-04-01

    The measurement of hardness has been and continues to be of significant importance to many of the world's manufacturing industries. Conventional hardness testing is the most commonly used method for acceptance testing and production quality control of metals and metallic products. Instrumented indentation is one of the few techniques available for obtaining various property values for coatings and electronic products in the micrometre and nanometre dimensional scales. For these industries to be successful, it is critical that measurements made by suppliers and customers agree within some practical limits. To help assure this measurement agreement, a traceability chain for hardness measurement traceability from the hardness definition to industry has developed and evolved over the past 100 years, but its development has been complicated. A hardness measurement value not only requires traceability of force, length and time measurements but also requires traceability of the hardness values measured by the hardness machine. These multiple traceability paths are needed because a hardness measurement is affected by other influence parameters that are often difficult to identify, quantify and correct. This paper describes the current situation of hardness measurement traceability that exists for the conventional hardness methods (i.e. Rockwell, Brinell, Vickers and Knoop hardness) and for special-application hardness and indentation methods (i.e. elastomer, dynamic, portables and instrumented indentation).

  13. It's hard to be green: Reverse green value chain.

    PubMed

    Couto, João; Tiago, Teresa; Gil, Artur; Tiago, Flávio; Faria, Sandra

    2016-08-01

    Firms have recently discovered that it is not enough to optimize internal processes and relationships with partners along the value chain to create a sustainable competitive market position. A clear customer orientation, which acknowledges that consumer buying behavior is complex and includes many elements implied in the value chain, is required. As companies offering green products are no exception to this rule, this study analyzes consumer behavior in Europe from a reserve green supply chain management perspective, using descriptive analyses and a structural equation model, with data collected by Flash Barometer comprising 26,573 responses from 28 European countries. The results suggest that European consumers are conscious of the green concept, but are not willing to buy or pay more for these products since the value is unclear. Companies offering green products must therefore rethink their strategies, especially in terms of value proposition, communication strategies, and eco-labeling.

  14. It's hard to be green: Reverse green value chain.

    PubMed

    Couto, João; Tiago, Teresa; Gil, Artur; Tiago, Flávio; Faria, Sandra

    2016-08-01

    Firms have recently discovered that it is not enough to optimize internal processes and relationships with partners along the value chain to create a sustainable competitive market position. A clear customer orientation, which acknowledges that consumer buying behavior is complex and includes many elements implied in the value chain, is required. As companies offering green products are no exception to this rule, this study analyzes consumer behavior in Europe from a reserve green supply chain management perspective, using descriptive analyses and a structural equation model, with data collected by Flash Barometer comprising 26,573 responses from 28 European countries. The results suggest that European consumers are conscious of the green concept, but are not willing to buy or pay more for these products since the value is unclear. Companies offering green products must therefore rethink their strategies, especially in terms of value proposition, communication strategies, and eco-labeling. PMID:27209347

  15. Evaluation of the Various Drying Methods on Surface Hardness of Type IV Dental Stone

    PubMed Central

    Sudhakar, A; Srivatsa, G; Shetty, Rohit; Rajeswari, C L; Manvi, Supriya

    2015-01-01

    Background: Studies regarding the effect of various methods to increase the surface hardness of Type IV dental stone are not conclusive. Therefore, this study was carried out to evaluate the effect of air drying, micro oven drying and die hardener on surface hardness of Type IV dental stone. Materials and Methods: A standard metal die was fabricated; polyvinyl siloxane impression material was used to make the molds of metal die. A total of 120 specimens were obtained from two different die stones and were grouped as Group A (kalrock) and Group B (pearl stone), and were subjected to air drying for 24 h, micro oven drying and application of die hardener. These models were then subjected to surface hardness testing using the knoop hardness instrument. The obtained data were subjected to statistical analysis. Results: The hardness of Group A specimens was 64 ± 0.54 Knoop hardness number (KHN) after application of die hardener, 60.47 ± 0.41 KHN after 24 h air drying, 58.2 ± 0.88 after microwave oven drying and 24.6 ± 0.4 after 1 h air drying. The hardness of Group B specimens was 45.59 ± 0.63 KHN after application of die hardener, 40.2 ± 0.63 KHN after 24 h air drying, 38.28 ± 0.55 KHN after microwave oven drying and 19.91 ± 0.64 KHN after 1 h air drying. Conclusion: Group A showed better results than Group B at all times. Application of the die hardener showed highest hardness values followed in the order by 24 h air drying, microwave oven drying and 1 h air drying in both groups. The study showed that air drying the dies for 24 h followed by application of a single layer of the die hardener produced the best surface hardness and is recommended to be followed in practice. PMID:26124610

  16. Can cone beam CT predict the hardness of interradicular cortical bone?

    PubMed Central

    2014-01-01

    Objectives Orthodontic mini implants can be inserted at the interradicular site. The bone quality at this site may affect the stability and anchorage of the implant. Bone density is clinically evaluated by Hounsfield units (HU) obtained from cone beam CT (CBCT). The objective of this study was to determine the correlations between HU, microhardness and cortical bone thickness of interradicular site at various segments (anterior/posterior) and aspects (buccal/lingual) of both jaws in a swine model. Materials and methods Eight mandible and maxilla swine bones were scanned by CBCT. The HU and thickness of the above-mentioned sites were determined. Then, a Knoop microhardness test was applied and the Knoop Hardness Number was obtained (KHN). Results The mandible parameters spread over a wider range than the maxilla. The buccal aspect of the maxilla had higher HU and KHN values than the mandible. The lingual aspect of the mandible had higher KHN values than the maxilla. Posterior segments had higher HU and KHN values. The thickness of the alveolar cortical bone was greater in the maxilla than in the mandible. Correlations were found between HU and KHN for 3 of the 4 sites (anterior or posterior, buccal or lingual) of the mandible only. No correlations were found for the maxilla. Upon pooling the HU and KHN data for the whole jaw, correlation was found for the maxilla as well. Conclusions Relying on HU values as a predictor of cortical bone hardness should be considered with caution. PMID:24735746

  17. Singular Values of Products of Ginibre Random Matrices, Multiple Orthogonal Polynomials and Hard Edge Scaling Limits

    NASA Astrophysics Data System (ADS)

    Kuijlaars, Arno B. J.; Zhang, Lun

    2014-12-01

    Akemann, Ipsen and Kieburg recently showed that the squared singular values of products of M rectangular random matrices with independent complex Gaussian entries are distributed according to a determinantal point process with a correlation kernel that can be expressed in terms of Meijer G-functions. We show that this point process can be interpreted as a multiple orthogonal polynomial ensemble. We give integral representations for the relevant multiple orthogonal polynomials and a new double contour integral for the correlation kernel, which allows us to find its scaling limits at the origin (hard edge). The limiting kernels generalize the classical Bessel kernels. For M = 2 they coincide with the scaling limits found by Bertola, Gekhtman, and Szmigielski in the Cauchy-Laguerre two-matrix model, which indicates that these kernels represent a new universality class in random matrix theory.

  18. Vickers microhardness of K2Co(SO4)2 · 6H2O single crystals and fracture geometry around impressions of vickers, knoop, and spherical indenters

    NASA Astrophysics Data System (ADS)

    Sizova, N. L.; Novikova, N. E.; Manomenova, V. L.; Rudneva, E. B.; Voloshin, A. E.

    2016-05-01

    The microhardness on the (010) and (001) planes in K2Co(SO4)2 · 6H2O crystal has been measured by the Vickers indentation method. Its values are, respectively, 11500 and 1300 MPa. No microhardness anisotropy of the first kind is revealed on either plane. The fracture geometry under indentation by a spherical indenter and Vickers and Knoop indenters is studied. The crystal has lower brittleness than the isomorphic Cs2Ni(SO4)2 · 6H2O crystal.

  19. Hardness correlation for uranium and its alloys

    SciTech Connect

    Humphreys, D L; Romig, Jr, A D

    1983-03-01

    The hardness of 16 different uranium-titanium (U-Ti) alloys was measured on six (6) different hardness scales (R/sub A/, R/sub B/, R/sub C/, R/sub D/, Knoop, and Vickers). The alloys contained between 0.75 and 2.0 wt % Ti. All of the alloys were solutionized (850/sup 0/C, 1 h) and ice-water quenched to produce a supersaturated martensitic phase. A range of hardnesses was obtained by aging the samples for various times and temperatures. The correlation of various hardness scales was shown to be virtually identical to the hardness-scale correlation for steels. For more-accurate conversion from one hardness scale to another, least-squares-curve fits were determined for the various hardness-scale correlations. 34 figures, 5 tables.

  20. Applying critical thinking skills to character education and values clarification with students who are deaf or hard of hearing.

    PubMed

    Easterbrooks, Susan R; Scheetz, Nanci A

    2004-01-01

    Students who are deaf or hard of hearing must learn to think critically. Character education (CE) refers to the effort to teach basic values and moral reasoning (Doyle & Ponder, 1977). Values clarification (VC) is the process of examining one's basic values and moral reasoning (Rokeach, 1973). Character education and values clarification as subject matter foster the development of critical thinking (CT), a tool used both to develop and to modify values and moral reasoning. These three areas mutually support one another. The development of a set of values and their underlying moral reasoning is the foundation for thinking critically about values. The authors examine the components of critical thinking, character education, and values clarification, summarize the literature, and provide a template for appropriate lesson plans. They also describe strategies that promote the development of critical thinking, character education, and values clarification.

  1. Applying critical thinking skills to character education and values clarification with students who are deaf or hard of hearing.

    PubMed

    Easterbrooks, Susan R; Scheetz, Nanci A

    2004-01-01

    Students who are deaf or hard of hearing must learn to think critically. Character education (CE) refers to the effort to teach basic values and moral reasoning (Doyle & Ponder, 1977). Values clarification (VC) is the process of examining one's basic values and moral reasoning (Rokeach, 1973). Character education and values clarification as subject matter foster the development of critical thinking (CT), a tool used both to develop and to modify values and moral reasoning. These three areas mutually support one another. The development of a set of values and their underlying moral reasoning is the foundation for thinking critically about values. The authors examine the components of critical thinking, character education, and values clarification, summarize the literature, and provide a template for appropriate lesson plans. They also describe strategies that promote the development of critical thinking, character education, and values clarification. PMID:15552336

  2. [Effect of the methods of photoactivation and insertion on the hardness of composite resins].

    PubMed

    Consani, Simonides; Pereira, Samira Buselli; Sinhoreti, Mario Alexandre Coelho; Correr Sobrinho, Lourenço

    2002-01-01

    The purpose of this study was to assess the effect of methods of photoactivation and insertion on the Knoop hardness of the Z100 and Alert composite resins. The specimens were confected in cavities measuring 4 x 4 mm. The insertion of material was carried out by means of two methods: single-portion technique and insertion of two 2-mm-thick layers. When inserted in a single portion, the resin was compressed with a static load of 1 kgf on a glass slab recovered with a polyester strip, in order to remove the excess of material. After the removal of the glass slab and polyester strip, the materials were photoactivated by means of continuous light emitted by a XL 3000 unit with a light intensity of 520 mW/cm2 for 40 seconds; double pulse, with light emission of 150 mW/cm2 for 10 seconds, plus 30 seconds with light intensity of 520 mW/cm2 emitted by a XL 3000 unit; and pulsatile light of 520 mW/cm emitted by the Optilux 400 unit, turned on for 2 seconds and off for 2 seconds, during 60 seconds. The two layers of the material submitted to double insertion were photoactivated in the same conditions as the bulk-inserted material, and the excess of material was also removed from the second layer. After storage in a stove at 37 C and 100% relative humidity for 24 hours, the specimens were embedded in polyester resin, trimmed and polished with sandpaper and diamond slurry. Knoop hardness was assessed in 4 depths with a HMV Shimadzu penetrometer under the load of 50 g during 30 seconds. The data submitted to ANOVA and Tukey's test revealed that Z100 presented greater hardness values; double insertion was better than single insertion; the hardness at the surface was smaller than that at the bottom of the specimen, regardless of other factors. For Z100, all activation methods produced smaller hardness values when double insertion was carried out. Meanwhile, for Alert, continuous light promoted statistical similarity between the insertion techniques. For Z100, there was

  3. Effect of inhomogeneity of light from light curing units on the surface hardness of composite resin.

    PubMed

    Arikawa, Hiroyuki; Kanie, Takahito; Fujii, Koichi; Takahashi, Hideo; Ban, Seiji

    2008-01-01

    This study investigated the characteristics of output light from different types of light curing units, and their effects on polymerization of light-activated composite resin. Three quartz-tungsten-halogen lamps, one plasma arc lamp, and one LED light curing unit were used. Intensity distribution of light emitted from the light guide tip was measured at 1.0-mm intervals across the guide tip. Distribution of Knoop hardness number on the surface of resin irradiated with the light curing units was also measured. For all units, inhomogeneous distribution of light intensity across the guide tip was observed. Minimum light intensity values were 19-80% of the maximum values. In terms of surface hardness, inhomogeneous distribution was also observed for the materials irradiated with the tested units. Minimum values were 53-92% of the maximum values. Our results indicated that markedly inhomogeneous light emitted from light curing unit could result in inhomogeneous polymerization in some areas of the restoration below the light guide tip. PMID:18309608

  4. Hardness, polymerization depth, and internal adaptation of Class II silorane composite restorations as a function of polymerization protocol

    PubMed Central

    Bechtold, Janaina; dos Santos, Priscila Jaques; Anido-Anido, Andrea; Di Hipólito, Vinícius; Alonso, Roberta Caroline Bruschi; D’Alpino, Paulo Henrique Perlatti

    2012-01-01

    Objectives: To evaluate the influence of various photoactivation techniques on the internal gap, Knoop-hardness, and polymerization depth of silorane- and methacrylate-based composites in Class II restorations. Methods: Preparations were made in third molars (n = 10), according to composites (Filtek P60: methacrylate; Filtek P90: silorane) and photoactivation techniques (OC: occlusal photoactivation (control); OBL: occlusal+buccal+lingual photoactivation; and BLO: buccal+lingual+occlusal photoactivation (transdental)). Composites were inserted in two increments, both individually photoactivated for 20s. After 24h, specimens were sectioned and the ratio of internal gaps to interface length (%) recorded. Hardness was tested across the transversal section of restorations (1–4 mm below the surface). Results: Silorane restorations showed significantly lower gaps compared with methacrylate, regardless of polymerization technique (P<.05). Supplementary energy dose in OBL and BLO protocols caused significant increase in gaps in silorane restorations (P<.05). For methacrylate restorations, OBL activation caused significantly higher gap formation (P<.05). Significantly lower hardness values were seen for silorane than for methacrylate composites (P<.05), regardless of depth and photoactivation. Significantly higher hardness values were seen in BLO activation for methacrylate restorations compared with control (P<.05); for silorane, no differences were observed. Significantly higher hardness values were observed at 1 and 3 mm compared to 2 and 4 mm for both composites. Conclusions: Internal gaps and hardness are affected by composite type and photoactivation. Despite the reduced values, hardness of silorane is not influenced by photoactivation or by depth. Internal gaps are dependent on the energy dose for both composites, with silorane showing lower internal gaps. PMID:22509115

  5. Comparison of CT-Number and Gray Scale Value of Different Dental Materials and Hard Tissues in CT and CBCT

    PubMed Central

    Emadi, Naghmeh; Safi, Yaser; Akbarzadeh Bagheban, Alireza; Asgary, Saeed

    2014-01-01

    Introduction: Computed tomography (CT) and cone-beam CT (CBCT) are valuable diagnostic aids for many clinical applications. This study was designed to compare the gray scale value (GSV) and Hounsfield unit (HU) of selected dental materials and various hard tissues using CT or CBCT. Methods and Materials: Three samples of all test materials including amalgam (AM), composite resin (CR), glass ionomer (GI), zinc-oxide eugenol (ZOE), calcium-enriched mixture (CEM) cement, AH-26 root canal sealer (AH-26), gutta-percha (GP), Coltosol (Col), Dycal (DL), mineral trioxide aggregate (MTA), zinc phosphate (ZP), and polycarbonate cement (PC) were prepared and scanned together with samples of bone, dentin and enamel using two CBCT devices, Scanora 3D (S3D) and NewTom VGi (NTV) and a spiral CT (SCT) scanner (Somatom Emotion 16 multislice spiral CT);. Subsequently, the HU and GSV values were determined and evaluated. The data were analyzed by the Kruskal-Wallis and Mann-Whitney U tests. The level of significance was determined at 0.05. Results: There were significant differences among the three different scanners (P<0.05). The differences between HU/GSV values of 12 selected dental materials using NTV was significant (P<0.05) and for S3D and SCT was insignificant (P>0.05). All tested materials showed maximum values in S3D and SCT (3094 and 3071, respectively); however, bone and dentin showed low/medium values (P<0.05). In contrast, the tested materials and tissues showed a range of values in NTV (366 to15383; P<0.05). Conclusion: Scanner system can influence the obtained HU/GSV of dental materials. NTV can discriminate various dental materials, in contrast to S3D/SCT scanners. NTV may be a more useful diagnostic aid for clinical practice. PMID:25386210

  6. Singular Values for Products of Complex Ginibre Matrices with a Source: Hard Edge Limit and Phase Transition

    NASA Astrophysics Data System (ADS)

    Forrester, Peter J.; Liu, Dang-Zheng

    2016-05-01

    The singular values squared of the random matrix product {Y = {Gr G_{r-1}} ldots G1 (G0 + A)}, where each {Gj} is a rectangular standard complex Gaussian matrix while A is non-random, are shown to be a determinantal point process with the correlation kernel given by a double contour integral. When all but finitely many eigenvalues of A* A are equal to bN, the kernel is shown to admit a well-defined hard edge scaling, in which case a critical value is established and a phase transition phenomenon is observed. More specifically, the limiting kernel in the subcritical regime of {0 < b < 1} is independent of b, and is in fact the same as that known for the case b = 0 due to Kuijlaars and Zhang. The critical regime of b = 1 allows for a double scaling limit by choosing {{b = (1 - τ/√{N})^{-1}}}, and for this the critical kernel and outlier phenomenon are established. In the simplest case r = 0, which is closely related to non-intersecting squared Bessel paths, a distribution corresponding to the finite shifted mean LUE is proven to be the scaling limit in the supercritical regime of {b > 1} with two distinct scaling rates. Similar results also hold true for the random matrix product {Tr T_{r-1} ldots T1 (G0 + A)}, with each {Tj} being a truncated unitary matrix.

  7. A Terrible Predicament: The De-Evolution of Values in Flannery O'Connor's "A Good Man Is Hard to Find."

    ERIC Educational Resources Information Center

    Tietz, Stephen; Logsdon, Loren

    2001-01-01

    Addresses problems concerning the ways Flannery O'Connor's fiction has been read. Proposes an alternate reading of "A Good Man Is Hard to Find." Suggests the primary theme of the story is the idea that each generation has the responsibility to pass on values to the next. (PM)

  8. Comparative evaluation of surface hardness and depth of cure of silorane and methacrylate-based posterior composite resins: An in vitro study

    PubMed Central

    Agrawal, Abhishek; Manwar, Narendra U; Hegde, Shubha G; Chandak, Manoj; Ikhar, Anuja; Patel, Aditya

    2015-01-01

    Aim: This in vitro study was carried out to compare the effect of LED light curing system on polymerization and hardness of silorane-based and methacrylate-based posterior composite resin. Materials and Methods: A total of 40 samples, 20 of silorane-based composite Filtek P-90 and 20 of methacrylate-based composite Heliomolar HB measuring 2 mm thickness and 8 mm diameter were prepared using Teflon molds and cured using LED curing light. The samples were polished and tested in Knoop hardness tester using a 50-gram load and dwell time of 15 seconds on top and bottom surfaces. The percentage depth of cure was calculated, and statistical analysis was performed using two-way ANOVA test and Student t- test. Results: Higher statistically significant values were seen for both the top and bottom surface hardness in silorane-based resins than methacrylate-based resins on LED light curing. Conclusion: Greater depth of cure was achieved in silorane-based posterior composite than in methacrylate-based posterior composite resins with a statistically significant difference. PMID:25829693

  9. A Case Study on Investigating the Effect of Genetic Algorithm Operators on Predicting the Global Minimum Hardness Value of Biomaterial Extrudate

    SciTech Connect

    Shankar, T.J.; Sokhansanj, Shahabaddine

    2010-02-01

    Crossover and mutation are the main search operators of genetic algorithm, one of the most important features which distinguish it from other search algorithms like simulated annealing. A genetic algorithm adopts crossover and mutation as their main genetic operators. The present work was aimed to see the effect of genetic algorithm operators like crossover and mutation (Pc & Pm), population size (n), and number of iterations (I) on predicting the minimum hardness (N) of the biomaterial extrudate. The second order polynomial regression equation developed for the extrudate property hardness in terms of the independent variables like barrel temperature, screw speed, fish content of the feed, and feed moisture content was used as the objective function in the GA analysis. A simple genetic algorithm (SGA) with a crossover and mutation operators was used in the present study. A program was developed in C language for a SGA with a rank based fitness selection method. The upper limit of population and iterations were fixed at 100. It was observed that increasing population and iterations the prediction of function minimum improved drastically. Minimum predicted hardness values were achievable with a medium population of 50, iterations of 50 and crossover and mutation probabilities of 50 % and 0.5 %. Further the Pareto charts indicated that the effect of Pc was found to be more significant when population is 50 and Pm played a major role at low population ( 10). A crossover probability of 50 % and mutation probability of 0.5 % are the threshold values for the convergence of GA to reach a global search space. A minimum predicted hardness value of 3.82 (N) was observed for n = 60 and I = 100 and Pc & Pm of 85 % and 0.5 %.

  10. Effect of curing mode on the hardness of dual-cured composite resin core build-up materials.

    PubMed

    Arrais, César Augusto Galvão; Kasaz, Aline de Cerqueira; Albino, Luís Gustavo Barrote; Rodrigues, José Augusto; Reis, Andre Figueiredo

    2010-01-01

    This study evaluated the Knoop Hardness (KHN) values of two dual-cured composite resin core build-up materials and one resin cement exposed to different curing conditions. Two dual-cured core build-up composite resins (LuxaCore-Dual, DMG; and FluoroCore2, Dentsply Caulk), and one dual-cured resin cement (Rely X ARC, 3M ESPE) were used in the present study. The composite materials were placed into a cylindrical matrix (2 mm in height and 3 mm in diameter), and the specimens thus produced were either light-activated for 40 s (Optilux 501, Demetron Kerr) or were allowed to self-cure for 10 min in the dark (n = 5). All specimens were then stored in humidity at 37 degrees C for 24 h in the dark and were subjected to KHN analysis. The results were submitted to 2-way ANOVA and Tukey's post-hoc test at a pre-set alpha of 5%. All the light-activated groups exhibited higher KHN values than the self-cured ones (p = 0.00001), regardless of product. Among the self-cured groups, both composite resin core build-up materials showed higher KHN values than the dual-cured resin cement (p = 0.00001). LuxaCore-Dual exhibited higher KHN values than FluoroCore2 (p = 0.00001) when they were allowed to self-cure, while no significant differences in KHN values were observed among the light-activated products. The results suggest that dual-cured composite resin core build-up materials may be more reliable than dual-cured resin cements when curing light is not available.

  11. Hybrid hard- and soft-modeling of spectrophotometric data for monitoring of ciprofloxacin and its main photodegradation products at different pH values

    NASA Astrophysics Data System (ADS)

    Razuc, Mariela; Garrido, Mariano; Caro, Yamile S.; Teglia, Carla M.; Goicoechea, Héctor C.; Fernández Band, Beatriz S.

    2013-04-01

    A simple and fast on line spectrophotometric method combined with a hybrid hard-soft modeling multivariate curve resolution (HS-MCR) was proposed for the monitoring of photodegradation reaction of ciprofloxacin under UV radiation. The studied conditions attempt to emulate the effect of sunlight on these antibiotics that could be eventually present in the environment. The continuous flow system made it possible to study the ciprofloxacin degradation at different pH values almost at real time, avoiding errors that could arise from typical batch monitoring of the reaction. On the base of a concentration profiles obtained by previous pure soft-modeling approach, reaction pathways have been proposed for the parent compound and its photoproducts at different pH values. These kinetic models were used as a constraint in the HS-MCR analysis. The kinetic profiles and the corresponding pure response profile (UV-Vis spectra) of ciprofloxacin and its main degradation products were recovered after the application of HS-MCR analysis to the spectra recorded throughout the reaction. The observed behavior showed a good agreement with the photodegradation studies reported in the bibliography. Accordingly, the photodegradation reaction was studied by high performance liquid chromatography coupled with UV-Vis diode array detector (HPLC-DAD). The spectra recorded during the chromatographic analysis present a good correlation with the ones recovered by UV-Vis/HS-MCR method.

  12. Hybrid hard- and soft-modeling of spectrophotometric data for monitoring of ciprofloxacin and its main photodegradation products at different pH values.

    PubMed

    Razuc, Mariela; Garrido, Mariano; Caro, Yamile S; Teglia, Carla M; Goicoechea, Héctor C; Fernández Band, Beatriz S

    2013-04-01

    A simple and fast on line spectrophotometric method combined with a hybrid hard-soft modeling multivariate curve resolution (HS-MCR) was proposed for the monitoring of photodegradation reaction of ciprofloxacin under UV radiation. The studied conditions attempt to emulate the effect of sunlight on these antibiotics that could be eventually present in the environment. The continuous flow system made it possible to study the ciprofloxacin degradation at different pH values almost at real time, avoiding errors that could arise from typical batch monitoring of the reaction. On the base of a concentration profiles obtained by previous pure soft-modeling approach, reaction pathways have been proposed for the parent compound and its photoproducts at different pH values. These kinetic models were used as a constraint in the HS-MCR analysis. The kinetic profiles and the corresponding pure response profile (UV-Vis spectra) of ciprofloxacin and its main degradation products were recovered after the application of HS-MCR analysis to the spectra recorded throughout the reaction. The observed behavior showed a good agreement with the photodegradation studies reported in the bibliography. Accordingly, the photodegradation reaction was studied by high performance liquid chromatography coupled with UV-Vis diode array detector (HPLC-DAD). The spectra recorded during the chromatographic analysis present a good correlation with the ones recovered by UV-Vis/HS-MCR method. PMID:23376269

  13. Effect of Polymerization Cycles on Gloss, Roughness, Hardness and Impact Strength of Acrylic Resins.

    PubMed

    Consani, Rafael Leonardo Xediek; Folli, Bianca L; Nogueira, Moises C F; Correr, Americo Bortolazzo; Mesquita, Marcelo F

    2016-01-01

    The aim of this study was to evaluate the conventional and boiled polymerization cycles on gloss, roughness, hardness and impact strength of acrylic resins. Samples were made for each Classico and QC-20 materials (n=10) in dental stone molds obtained from rectangular metallic matrices embedded in metallic flasks. The powder-liquid ratio and manipulation of the acrylic resins' were accomplished according to manufacturers' instructions and the resins were conventionally packed in metallic flasks. After polymerization by (1) conventional: 74 °C for 9 h (Classico) and (2) boiled: 20 min (QC-20) cycles, the samples were deflasked after cooling at room temperature and conventionally finished and polished. The properties were evaluated after storage in water at 37 °C for 24 h. Gloss was verified with Multi Gloss 268 meter (Konica Minolta), surface roughness was measured with Surfcorder SE 1700 rugosimeter (Kosaka), Knoop hardness number was obtained with HMV-200 microdurometer, and impact strength was measured in an Otto Wolpert-Werke device by Charpy system (40 kpcm). Data were subjected to Student's t-test (at α=0.05). The results were: Gloss: 67.7 and 62.2 for Classico and QC-20 resins, respectively; Surface roughness: 0.874 and 1.469 Ra-µm for Classico and QC-20, respectively; Knoop hardness: 27.4 and 26.9 for Classico and QC-20, respectively; and Impact strength: 37.6 and 33.6 kgf/cm2 for Classico and QC-20, respectively. No statistically significant difference (p>0.05)were found between the resins for the evaluated properties. In conclusion, conventional and boiled polymerization cycles had similar effects on gloss, roughness, hardness and impact strength of both Classico and QC-20 resins.

  14. Transdental photo-activation technique: hardness and marginal adaptation of composite restorations using different light sources.

    PubMed

    Alves, Eliane Bemerguy; Alonso, Roberta Caroline Bruschi; Correr, Gisele Maria; Correr, Américo Bortolazzo; de Moraes, Rafael Ratto; Sinhoreti, Mário Alexandre Coelho; Correr-Sobrinho, Lourenço

    2008-01-01

    This study investigated the influence of different light sources associated with a transdental photoactivation technique on the marginal adaptation and hardness of composite restorations. Cavities (3 mm wide x 3 mm long x 1.5 mm in deep) were prepared on flattened bovine dentin and filled with Z250 composite (3M ESPE). Nine groups (n=10) were defined according to the curing technique (direct; transdental--photo-activation through 1 mm of enamel and 2 mm of dentin; mixed--transdental + direct) and light source (QTH XL2500, 3M ESPE; PAC Apollo 95E, DMD; LED Ultrablue Is, DMC) combination. Marginal adaptation was evaluated using a dye staining method, and the percentage of stained margins was recorded. Knoop Hardness readings were made across the transversal section of the fillings. Data were submitted to two-way ANOVA and Tukey's test (p< or =0.05). For margin analysis, although none of the curing conditions provided perfect adaptation, the mixed technique showed lower gap formation. No significant differences were detected between the transdental and other techniques, and no significant differences were detected among the light sources. For hardness, the direct technique showed slightly greater hardness than the mixed technique. Also, the mixed technique yielded greater hardness than the transdental technique. Among the light sources, the LED showed greater hardness than the PAC; whereas, no significant differences between the QTH and other sources were detected. The mixed technique might improve the marginal adaptation of restorations, while not being detrimental to composite hardness.

  15. The effect of prolonged packing on the surface hardness of posterior composites.

    PubMed

    Stockton, Lawrence W; Williams, P T; Attallah, C

    2002-01-01

    This study evaluated the effect of four different packing times on the Knoop Hardness Number of three composites (Surefil, Z100 and Spectrum TPH). Ten samples of each composite were prepared for each packing time and 10 readings were made on each sample to produce the KHN. Photomicrographs were made of 147 indentations to determine whether the indentations had routinely been made on porosity-free sites. Statistical analysis was made using two-way ANOVA and least square means. Generally, as the packing time increased, the KHN decreased,and although the indentations appeared to have been made in porosity-free composite, the potential effect of porosities was not discounted. Increasing the packing time for clinical composites may result in a lower KHN and increased clinical wear, which would further increase if also associated with porosities within the composite.

  16. SUPER HARD SURFACED POLYMERS

    SciTech Connect

    Mansur, Louis K; Bhattacharya, R; Blau, Peter Julian; Clemons, Art; Eberle, Cliff; Evans, H B; Janke, Christopher James; Jolly, Brian C; Lee, E H; Leonard, Keith J; Trejo, Rosa M; Rivard, John D

    2010-01-01

    High energy ion beam surface treatments were applied to a selected group of polymers. Of the six materials in the present study, four were thermoplastics (polycarbonate, polyethylene, polyethylene terephthalate, and polystyrene) and two were thermosets (epoxy and polyimide). The particular epoxy evaluated in this work is one of the resins used in formulating fiber reinforced composites for military helicopter blades. Measures of mechanical properties of the near surface regions were obtained by nanoindentation hardness and pin on disk wear. Attempts were also made to measure erosion resistance by particle impact. All materials were hardness tested. Pristine materials were very soft, having values in the range of approximately 0.1 to 0.5 GPa. Ion beam treatment increased hardness by up to 50 times compared to untreated materials. For reference, all materials were hardened to values higher than those typical of stainless steels. Wear tests were carried out on three of the materials, PET, PI and epoxy. On the ion beam treated epoxy no wear could be detected, whereas the untreated material showed significant wear.

  17. Structure of hard particle fluids near a hard wall. II. yw(z) for hard spheres

    NASA Astrophysics Data System (ADS)

    Labik, S.; Smith, William R.; Speedy, Robin J.

    1988-02-01

    Predictions of the wall-cavity correlation function yw(z) for hard spheres against a hard wall are tested using the treatment that Smith and Speedy developed and examined for the case of hard disks in part I of this series, as well as an extension of this approach using an alternative procedure. yw(z) in the range 0≤z≤1 may be accurately predicted using only the thermodynamic properties of the bulk fluid, for which precise expressions are available. These predictions are tested by determining yw(z) and the cavity concentration profile nwo(z) in a computer simulation study. We also derive a new integral equation relating yw(z) near the wall to its values just outside the wall and illustrate this in examining the consistency of our computer simulation results.

  18. "We Can Get Everything We Want if We Try Hard": Young People, Celebrity, Hard Work

    ERIC Educational Resources Information Center

    Mendick, Heather; Allen, Kim; Harvey, Laura

    2015-01-01

    Drawing on 24 group interviews on celebrity with 148 students aged 14-17 across six schools, we show that "hard work" is valued by young people in England. We argue that we should not simply celebrate this investment in hard work. While it opens up successful subjectivities to previously excluded groups, it reproduces neoliberal…

  19. Session: Hard Rock Penetration

    SciTech Connect

    Tennyson, George P. Jr.; Dunn, James C.; Drumheller, Douglas S.; Glowka, David A.; Lysne, Peter

    1992-01-01

    This session at the Geothermal Energy Program Review X: Geothermal Energy and the Utility Market consisted of five presentations: ''Hard Rock Penetration - Summary'' by George P. Tennyson, Jr.; ''Overview - Hard Rock Penetration'' by James C. Dunn; ''An Overview of Acoustic Telemetry'' by Douglas S. Drumheller; ''Lost Circulation Technology Development Status'' by David A. Glowka; ''Downhole Memory-Logging Tools'' by Peter Lysne.

  20. Hardness Tester for Polyur

    NASA Technical Reports Server (NTRS)

    Hauser, D. L.; Buras, D. F.; Corbin, J. M.

    1987-01-01

    Rubber-hardness tester modified for use on rigid polyurethane foam. Provides objective basis for evaluation of improvements in foam manufacturing and inspection. Typical acceptance criterion requires minimum hardness reading of 80 on modified tester. With adequate correlation tests, modified tester used to measure indirectly tensile and compressive strengths of foam.

  1. Roles of hardness in the sliding behavior of materials

    NASA Astrophysics Data System (ADS)

    Rigney, D. A.

    1994-06-01

    It is generally recognized that hardness is one of the key factors which influence the sliding behavior of different materials combinations. However, in many discussions the only hardness value considered is that of the softer of the two materials in a tribological pair. This is usually the case when a simple linear wear equation (Holm, Archard, Khruschov) is cited. Observations on many materials combinations demonstrate that the effects of hardness are much more complex. Hardness varies with position and time. It can depend on temperature, sliding speed and the chemical environment. The sign of hardness gradients adjacent to the sliding surface affects sliding behavior. Transfer and subsequent mechanical mixing strongly influence local hardness. Changes in hardness can affect transitions in friction and wear. Relative hardness values can help to explain differences in debris and in smooth and rough sliding. They can also help us to understand geometric effects such as those noted when materials are interchanged in a test system. Examples are described.

  2. The hard metal diseases

    SciTech Connect

    Cugell, D.W. )

    1992-06-01

    Hard metal is a mixture of tungsten carbide and cobalt, to which small amounts of other metals may be added. It is widely used for industrial purposes whenever extreme hardness and high temperature resistance are needed, such as for cutting tools, oil well drilling bits, and jet engine exhaust ports. Cobalt is the component of hard metal that can be a health hazard. Respiratory diseases occur in workers exposed to cobalt--either in the production of hard metal, from machining hard metal parts, or from other sources. Adverse pulmonary reactions include asthma, hypersensitivity pneumonitis, and interstitial fibrosis. A peculiar, almost unique form of lung fibrosis, giant cell interstitial pneumonia, is closely linked with cobalt exposure.66 references.

  3. The hard metal diseases.

    PubMed

    Cugell, D W

    1992-06-01

    Hard metal is a mixture of tungsten carbide and cobalt, to which small amounts of other metals may be added. It is widely used for industrial purposes whenever extreme hardness and high temperature resistance are needed, such as for cutting tools, oil well drilling bits, and jet engine exhaust ports. Cobalt is the component of hard metal that can be a health hazard. Respiratory diseases occur in workers exposed to cobalt--either in the production of hard metal, from machining hard metal parts, or from other sources. Adverse pulmonary reactions include asthma, hypersensitivity pneumonitis, and interstitial fibrosis. A peculiar, almost unique form of lung fibrosis, giant cell interstitial pneumonia, is closely linked with cobalt exposure.

  4. The hard metal diseases.

    PubMed

    Cugell, D W

    1992-06-01

    Hard metal is a mixture of tungsten carbide and cobalt, to which small amounts of other metals may be added. It is widely used for industrial purposes whenever extreme hardness and high temperature resistance are needed, such as for cutting tools, oil well drilling bits, and jet engine exhaust ports. Cobalt is the component of hard metal that can be a health hazard. Respiratory diseases occur in workers exposed to cobalt--either in the production of hard metal, from machining hard metal parts, or from other sources. Adverse pulmonary reactions include asthma, hypersensitivity pneumonitis, and interstitial fibrosis. A peculiar, almost unique form of lung fibrosis, giant cell interstitial pneumonia, is closely linked with cobalt exposure. PMID:1511554

  5. Photopolymerized resins: surface hardness variation in relation to time of polymerization and setting.

    PubMed

    Turbino, M L; Vinha, D; Centola, A L; Campos, G M

    1993-01-01

    The authors studied the superficial hardness of composite resins cured for two different times: 20 and 40 seconds of light exposure. The hardness values were read immediately and 24 hours after polymerization. A significant increase in hardness was observed with 40 s exposure as compared to 20 s. Hardness values were significantly higher at 24 h than immediately after polymerization.

  6. Effects of preheating and precooling on the hardness and shrinkage of a composite resin cured with QTH and LED.

    PubMed

    Osternack, F H; Caldas, D B M; Almeida, J B; Souza, E M; Mazur, R F

    2013-01-01

    The aim of this study was to evaluate in vitro the hardness and shrinkage of a pre-cooled or preheated hybrid composite resin cured by a quartz-tungsten-halogen light (QTH) and light-emitting diode (LED) curing units. The temperature on the tip of the devices was also investigated. Specimens of Charisma resin composite were produced with a metal mold kept under 37°C. The syringes were submitted to 4°C, 23°C, and 60°C (n=20) before light-curing, which was carried out with the Optilux 501 VCL and Elipar FreeLight 2 units for 20 seconds. The specimens were kept under 37°C in a high humidity condition and darkness for 48 hours. The Knoop hardness test was carried out with a 50 gram-force (gf) load for 10 seconds, and the measurement of the shrinkage gap was carried out using an optical microscope. The data were subjected to analysis of variance and the Games-Howell test (α=0.05). The mean hardness of the groups were similar, irrespective of the temperatures (p>0.05). For 4°C and 60°C, the top surface light-cured by LED presented significantly reduced shrinkage when compared with the bottom and to both surfaces cured by QTH (p<0.05). It was concluded that the hardness was not affected by pre-cooling or preheating. However, polymerization shrinkage was slightly affected by different pre-polymerization temperatures. The QTH-curing generated greater shrinkage than LED-curing only when the composite was preheated. Different temperatures did not affect the composite hardness and shrinkage when cured by a LED curing unit. PMID:23088189

  7. Organizing Your Hard Disk.

    ERIC Educational Resources Information Center

    Stocker, H. Robert; Hilton, Thomas S. E.

    1991-01-01

    Suggests strategies that make hard disk organization easy and efficient, such as making, changing, and removing directories; grouping files by subject; naming files effectively; backing up efficiently; and using PATH. (JOW)

  8. Novel hard compositions and methods of preparation

    DOEpatents

    Sheinberg, H.

    1981-02-03

    Novel very hard compositions of matter are prepared by using in all embodiments only a minor amount of a particular carbide (or materials which can form the carbide in situ when subjected to heat and pressure); and no strategic cobalt is needed. Under a particular range of conditions, densified compositions of matter of the invention are prepared having hardnesses on the Rockwell A test substantially equal to the hardness of pure tungsten carbide and to two of the hardest commercial cobalt-bonded tungsten carbides. Alternately, other compositions of the invention which have slightly lower hardnesses than those described above in one embodiment also possess the advantage of requiring no tungsten and in another embodiment possess the advantage of having a good fracture toughness value.

  9. Effects of Hard Water on Hair

    PubMed Central

    Srinivasan, Gautham; Srinivas, Chakravarthi Rangachari; Mathew, Anil C; Duraiswami, Divakar

    2013-01-01

    Background: Hardness of water is determined by the amount of salts (calcium carbonate [CaCO3] and magnesium sulphate [MgSO4]) present in water. The hardness of the water used for washing hair may cause fragility of hair. Objective: The objective of the following study is to compare the tensile strength and elasticity of hair treated in hard water and hair treated in distilled water. Materials and Methods: 10-15 strands of hair of length 15-20 cm, lost during combing were obtained from 15 volunteers. Each sample was cut in the middle to obtain 2 sets of hair per volunteer. One set of 15 samples was immersed in hard water and the other set in distilled water for 10 min on alternate days. Procedure was repeated for 30 days. The tensile strength and elasticity of the hair treated in hard water and distilled water was determined using INSTRON universal strength tester. Results: The CaCO3 and MgSO4 content of hard water and distilled water were determined as 212.5 ppm of CaCO3 and 10 ppm of CaCO3 respectively. The tensile strength and elasticity in each sample was determined and the mean values were compared using t-test. The mean (SD) of tensile strength of hair treated in hard water was 105.28 (27.59) and in distilled water was 103.66 (20.92). No statistical significance was observed in the tensile strength, t = 0.181, P = 0.858. The mean (SD) of elasticity of hair treated in hard water was 37.06 (2.24) and in distilled water was 36.84 (4.8). No statistical significance was observed in the elasticity, t = 0.161, P = 0.874. Conclusion: The hardness of water does not interfere with the tensile strength and elasticity of hair. PMID:24574692

  10. Budgeting in Hard Times.

    ERIC Educational Resources Information Center

    Parrino, Frank M.

    2003-01-01

    Interviews with school board members and administrators produced a list of suggestions for balancing a budget in hard times. Among these are changing calendars and schedules to reduce heating and cooling costs; sharing personnel; rescheduling some extracurricular activities; and forming cooperative agreements with other districts. (MLF)

  11. Hard (and Soft) Facts.

    ERIC Educational Resources Information Center

    Kennedy, Mike

    1999-01-01

    Provides guidelines to help schools maintain hard floors and carpets, including special areas in schools and colleges that need attention and the elements needed to have a successful carpet-maintenance program. The importance of using heavy equipment to lessen time and effort is explained as are the steps maintenance workers can take to make the…

  12. CSI: Hard Drive

    ERIC Educational Resources Information Center

    Sturgeon, Julie

    2008-01-01

    Acting on information from students who reported seeing a classmate looking at inappropriate material on a school computer, school officials used forensics software to plunge the depths of the PC's hard drive, searching for evidence of improper activity. Images were found in a deleted Internet Explorer cache as well as deleted file space.…

  13. Running in Hard Times

    ERIC Educational Resources Information Center

    Berry, John N., III

    2009-01-01

    Roberta Stevens and Kent Oliver are campaigning hard for the presidency of the American Library Association (ALA). Stevens is outreach projects and partnerships officer at the Library of Congress. Oliver is executive director of the Stark County District Library in Canton, Ohio. They have debated, discussed, and posted web sites, Facebook pages,…

  14. A Modified Theoretical Model of Intrinsic Hardness of Crystalline Solids

    PubMed Central

    Dai, Fu-Zhi; Zhou, Yanchun

    2016-01-01

    Super-hard materials have been extensively investigated due to their practical importance in numerous industrial applications. To stimulate the design and exploration of new super-hard materials, microscopic models that elucidate the fundamental factors controlling hardness are desirable. The present work modified the theoretical model of intrinsic hardness proposed by Gao. In the modification, we emphasize the critical role of appropriately decomposing a crystal to pseudo-binary crystals, which should be carried out based on the valence electron population of each bond. After modification, the model becomes self-consistent and predicts well the hardness values of many crystals, including crystals composed of complex chemical bonds. The modified model provides fundamental insights into the nature of hardness, which can facilitate the quest for intrinsic super-hard materials. PMID:27604165

  15. A Modified Theoretical Model of Intrinsic Hardness of Crystalline Solids

    NASA Astrophysics Data System (ADS)

    Dai, Fu-Zhi; Zhou, Yanchun

    2016-09-01

    Super-hard materials have been extensively investigated due to their practical importance in numerous industrial applications. To stimulate the design and exploration of new super-hard materials, microscopic models that elucidate the fundamental factors controlling hardness are desirable. The present work modified the theoretical model of intrinsic hardness proposed by Gao. In the modification, we emphasize the critical role of appropriately decomposing a crystal to pseudo-binary crystals, which should be carried out based on the valence electron population of each bond. After modification, the model becomes self-consistent and predicts well the hardness values of many crystals, including crystals composed of complex chemical bonds. The modified model provides fundamental insights into the nature of hardness, which can facilitate the quest for intrinsic super-hard materials.

  16. A Modified Theoretical Model of Intrinsic Hardness of Crystalline Solids.

    PubMed

    Dai, Fu-Zhi; Zhou, Yanchun

    2016-01-01

    Super-hard materials have been extensively investigated due to their practical importance in numerous industrial applications. To stimulate the design and exploration of new super-hard materials, microscopic models that elucidate the fundamental factors controlling hardness are desirable. The present work modified the theoretical model of intrinsic hardness proposed by Gao. In the modification, we emphasize the critical role of appropriately decomposing a crystal to pseudo-binary crystals, which should be carried out based on the valence electron population of each bond. After modification, the model becomes self-consistent and predicts well the hardness values of many crystals, including crystals composed of complex chemical bonds. The modified model provides fundamental insights into the nature of hardness, which can facilitate the quest for intrinsic super-hard materials. PMID:27604165

  17. Hard Times Hit Schools

    ERIC Educational Resources Information Center

    McNeil, Michele

    2008-01-01

    Hard-to-grasp dollar amounts are forcing real cuts in K-12 education at a time when the cost of fueling buses and providing school lunches is increasing and the demands of the federal No Child Left Behind Act still loom larger over states and districts. "One of the real challenges is to continue progress in light of the economy," said Gale Gaines,…

  18. Hard Diffraction at CDF

    SciTech Connect

    Melese, P.; CDF Collaboration

    1997-06-01

    We present results on diffractive production of hard processes in {anti p}p collisions at {radical}s = 1.8 TeV at the Tevatron using the CDF detector. The signatures used to identify diffractive events are the forward rapidity gap and/or the detection of a recoil antiproton with high forward momentum. We have observed diffractive W- boson, dijet, and heavy quark production. We also present results on double-pomeron production of dijets.

  19. Work Hard. Be Nice

    ERIC Educational Resources Information Center

    Mathews, Jay

    2009-01-01

    In 1994, fresh from a two-year stint with Teach for America, Mike Feinberg and Dave Levin inaugurated the Knowledge Is Power Program (KIPP) in Houston with an enrollment of 49 5th graders. By this Fall, 75 KIPP schools will be up and running, setting children from poor and minority families on a path to college through a combination of hard work,…

  20. Ultrasonic characterization of materials hardness

    PubMed

    Badidi Bouda A; Benchaala; Alem

    2000-03-01

    In this paper, an experimental technique has been developed to measure velocities and attenuation of ultrasonic waves through a steel with a variable hardness. A correlation between ultrasonic measurements and steel hardness was investigated.

  1. Hard metal composition

    DOEpatents

    Sheinberg, H.

    1983-07-26

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 wt % boron carbide and the remainder a metal mixture comprising from 70 to 90% tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 and 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  2. Hard metal composition

    DOEpatents

    Sheinberg, Haskell

    1986-01-01

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 weight percent boron carbide and the remainder a metal mixture comprising from 70 to 90 percent tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 to 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  3. Hard Exclusive Pion Leptoproduction

    NASA Astrophysics Data System (ADS)

    Kroll, Peter

    2016-08-01

    In this talk it is reported on an analysis of hard exclusive leptoproduction of pions within the handbag approach. It is argued that recent measurements of this process performed by HERMES and CLAS clearly indicate the occurrence of strong contributions from transversely polarized photons. Within the handbag approach such γ ^{ *}_T→ π transitions are described by the transversity GPDs accompanied by twist-3 pion wave functions. It is shown that the handbag approach leads to results on cross sections and single-spin asymmetries in fair agreement with experiment. Predictions for other pseudoscalar meson channels are also briefly discussed.

  4. Novel hard compositions and methods of preparation

    DOEpatents

    Sheinberg, H.

    1983-08-23

    Novel very hard compositions of matter are prepared by using in all embodiments only a minor amount of a particular carbide (or materials which can form the carbide in situ when subjected to heat and pressure); and no strategic cobalt is needed. Under a particular range of conditions, densified compositions of matter of the invention are prepared having hardnesses on the Rockwell A test substantially equal to the hardness of pure tungsten carbide and to two of the hardest commercial cobalt-bonded tungsten carbides. Alternately, other compositions of the invention which have slightly lower hardnesses than those described above in one embodiment also possess the advantage of requiring no tungsten and in another embodiment possess the advantage of having a good fracture toughness value. Photomicrographs show that the shapes of the grains of the alloy mixture with which the minor amount of carbide (or carbide-formers) is mixed are radically altered from large, rounded to small, very angular by the addition of the carbide. Superiority of one of these hard compositions of matter over cobalt-bonded tungsten carbide for ultra-high pressure anvil applications was demonstrated. 3 figs.

  5. Novel hard compositions and methods of preparation

    DOEpatents

    Sheinberg, Haskell

    1983-08-23

    Novel very hard compositions of matter are prepared by using in all embodiments only a minor amount of a particular carbide (or materials which can form the carbide in situ when subjected to heat and pressure); and no strategic cobalt is needed. Under a particular range of conditions, densified compositions of matter of the invention are prepared having hardnesses on the Rockwell A test substantially equal to the hardness of pure tungsten carbide and to two of the hardest commercial cobalt-bonded tungsten carbides. Alternately, other compositions of the invention which have slightly lower hardnesses than those described above in one embodiment also possess the advantage of requiring no tungsten and in another embodiment possess the advantage of having a good fracture toughness value. Photomicrographs show that the shapes of the grains of the alloy mixture with which the minor amount of carbide (or carbide-formers) is mixed are radically altered from large, rounded to small, very angular by the addition of the carbide. Superiority of one of these hard compositions of matter over cobalt-bonded tungsten carbide for ultra-high pressure anvil applications was demonstrated.

  6. Water hardness and sodium trends in Texas aquifers.

    PubMed

    Hudak, P F

    2001-05-01

    Median hardness and sodium levels in groundwater were calculated for 244 Texas counties from measurements at 7728 water wells. The data were mapped and analyzed with a geographic information system (GIS). County median hardness levels varied widely, from 4-2304 mg L-1. More than 60% of the counties had hardness medians above 180 mg L-1. County medium sodium concentrations ranged from 6-1170 mg L-1, with more than 90% of those values exceeding 20 mg L-1. There was a significant positive correlation between hardness and sodium concentrations in six of Texas' nine major aquifers. A significant negative correlation between hardness and sodium was observed in two aquifers. Several factors control hardness and sodium variations in Texas aquifers including rock/sediment composition, groundwater chemical evolution, and seepage from nearby formations. Probable human controls include agricultural return flow and pumping-induced saltwater intrusion. PMID:11411143

  7. The Dubious Value of Value Neutrality

    ERIC Educational Resources Information Center

    Balch, Stephen H.

    2006-01-01

    Hard science is properly value neutral. But when that ideological neutrality extends to the whole university, the traditional foundation crumbles. Steve Balch laments the moral vacuum that now substitutes for fundamental principles, because it is impossible to frame a program of education--especially in the humanities and social sciences--without…

  8. Informativeness Improvement of Hardness Test Methods for Metal Product Assessment

    NASA Astrophysics Data System (ADS)

    Osipov, S.; Podshivalov, I.; Osipov, O.; Zhantybaev, A.

    2016-06-01

    The paper presents a combination of theoretical suggestions, results, and observations allowing to improve the informativeness of hardness testing process in solving problems of metal product assessment while in operation. The hardness value of metal surface obtained by a single measurement is considered to be random. Various measures of location and scattering of the random variable were experimentally estimated for a number of test samples using the correlation analysis, and their close interaction was studied. It was stated that in metal assessment, the main informative characteristics of hardness testing process are its average value and mean-square deviation for measures of location and scattering, respectively.

  9. Overview: Hard Rock Penetration

    SciTech Connect

    Dunn, J.C.

    1992-01-01

    The Hard Rock Penetration program is developing technology to reduce the costs of drilling and completing geothermal wells. Current projects include: lost circulation control, rock penetration mechanics, instrumentation, and industry/DOE cost shared projects of the Geothermal Drilling organization. Last year, a number of accomplishments were achieved in each of these areas. A new flow meter being developed to accurately measure drilling fluid outflow was tested extensively during Long Valley drilling. Results show that this meter is rugged, reliable, and can provide useful measurements of small differences in fluid inflow and outflow rates. By providing early indications of fluid gain or loss, improved control of blow-out and lost circulation problems during geothermal drilling can be expected. In the area of downhole tools for lost circulation control, the concept of a downhole injector for injecting a two-component, fast-setting cementitious mud was developed. DOE filed a patent application for this concept during FY 91. The design criteria for a high-temperature potassium, uranium, thorium logging tool featuring a downhole data storage computer were established, and a request for proposals was submitted to tool development companies. The fundamental theory of acoustic telemetry in drill strings was significantly advanced through field experimentation and analysis. A new understanding of energy loss mechanisms was developed.

  10. Overview: Hard Rock Penetration

    SciTech Connect

    Dunn, J.C.

    1992-08-01

    The Hard Rock Penetration program is developing technology to reduce the costs of drilling and completing geothermal wells. Current projects include: lost circulation control, rock penetration mechanics, instrumentation, and industry/DOE cost shared projects of the Geothermal Drilling organization. Last year, a number of accomplishments were achieved in each of these areas. A new flow meter being developed to accurately measure drilling fluid outflow was tested extensively during Long Valley drilling. Results show that this meter is rugged, reliable, and can provide useful measurements of small differences in fluid inflow and outflow rates. By providing early indications of fluid gain or loss, improved control of blow-out and lost circulation problems during geothermal drilling can be expected. In the area of downhole tools for lost circulation control, the concept of a downhole injector for injecting a two-component, fast-setting cementitious mud was developed. DOE filed a patent application for this concept during FY 91. The design criteria for a high-temperature potassium, uranium, thorium logging tool featuring a downhole data storage computer were established, and a request for proposals was submitted to tool development companies. The fundamental theory of acoustic telemetry in drill strings was significantly advanced through field experimentation and analysis. A new understanding of energy loss mechanisms was developed.

  11. Overview - Hard Rock Penetration

    SciTech Connect

    Dunn, James C.

    1992-03-24

    The Hard Rock Penetration program is developing technology to reduce the costs of drilling and completing geothermal wells. Current projects include: lost circulation control, rock penetration mechanics, instrumentation, and industry/DOE cost shared projects of the Geothermal Drilling Organization. Last year, a number of accomplishments were achieved in each of these areas. A new flow meter being developed to accurately measure drilling fluid outflow was tested extensively during Long Valley drilling. Results show that this meter is rugged, reliable, and can provide useful measurements of small differences in fluid inflow and outflow rates. By providing early indications of fluid gain or loss, improved control of blow-out and lost circulation problems during geothermal drilling can be expected. In the area of downhole tools for lost circulation control, the concept of a downhole injector for injecting a two-component, fast-setting cementitious mud was developed. DOE filed a patent application for this concept during FY 91. The design criteria for a high-temperature potassium, uranium, thorium logging tool featuring a downhole data storage computer were established, and a request for proposals was submitted to tool development companies. The fundamental theory of acoustic telemetry in drill strings was significantly advanced through field experimentation and analysis. A new understanding of energy loss mechanisms was developed.

  12. Measuring the Hardness of Minerals

    ERIC Educational Resources Information Center

    Bushby, Jessica

    2005-01-01

    The author discusses Moh's hardness scale, a comparative scale for minerals, whereby the softest mineral (talc) is placed at 1 and the hardest mineral (diamond) is placed at 10, with all other minerals ordered in between, according to their hardness. Development history of the scale is outlined, as well as a description of how the scale is used…

  13. Superhard material comparable in hardness to diamond

    SciTech Connect

    Badzian, A.R.

    1988-12-19

    Superhard boron suboxides, with hardness close to that of diamond, were synthesized from boron/boron oxide mixtures. Such hardness is expected when a material's molar volume approaches the value characteristic for diamond. These materials consist of boron-rich phases belonging to the boron-oxygen system. The phase which contains 4 at. % oxygen and a crystal structure related to ..beta..rhombohedral boron can scratch diamond faces. During scratching of diamond the suboxide is worn also, and the wear debris is amorphized. Wear on the lt. slash/100/ diamond faces results from a cleavage mechanism which leaves a rough surface covered with cleaved lt. slash/111/ microfaces. The lt. slash/100/ faces are more easily abraded than the lt. slash/111/ diamond faces. Wear on lt. slash/111/ faces consumes much more energy and leaves grooves of plastically deformed diamond.

  14. Superhard material comparable in hardness to diamond

    NASA Astrophysics Data System (ADS)

    Badzian, Andrzej R.

    1988-12-01

    Superhard boron suboxides, with hardness close to that of diamond, were synthesized from boron/boron oxide mixtures. Such hardness is expected when a material's molar volume approaches the value characteristic for diamond. These materials consist of boron-rich phases belonging to the boron-oxygen system. The phase which contains 4 at. % oxygen and a crystal structure related to β-rhombohedral boron can scratch diamond faces. During scratching of diamond the suboxide is worn also, and the wear debris is amorphized. Wear on the {100} diamond faces results from a cleavage mechanism which leaves a rough surface covered with cleaved {111} microfaces. The {100} faces are more easily abraded than the {111} diamond faces. Wear on {111} faces consumes much more energy and leaves grooves of plastically deformed diamond.

  15. Genetic Evolutionary Approach for Cutting Forces Prediction in Hard Milling

    NASA Astrophysics Data System (ADS)

    Taylan, Fatih; Kayacan, Cengiz

    2011-11-01

    Hard milling is a very common used machining procedure in the last years. Therefore the prediction of cutting forces is important. The paper deals with this prediction using genetic evolutionary programming (GEP) approach to set mathematical expression for out cutting forces. In this study, face milling was performed using DIN1.2842 (90MnCrV8) cold work tool steel, with a hardness of 61 HRC. Experimental parameters were selected using stability measurements and simulations. In the hard milling experiments, cutting force data in a total of three axes were collected. Feed direction (Fx) and tangential direction (Fy) cutting forces generated using genetic evolutionary programming were modelled. Cutting speed and feed rate values were treated as inputs in the models, and average cutting force values as output. Mathematical expressions were created to predict average Fxand Fy forces that can be generated in hard material milling.

  16. Hardness and Microstructure of Binary and Ternary Nitinol Compounds

    NASA Technical Reports Server (NTRS)

    Stanford, Malcolm K.

    2016-01-01

    The hardness and microstructure of twenty-six binary and ternary Nitinol (nickel titanium, nickel titanium hafnium, nickel titanium zirconium and nickel titanium tantalum) compounds were studied. A small (50g) ingot of each compound was produced by vacuum arc remelting. Each ingot was homogenized in vacuum for 48 hr followed by furnace cooling. Specimens from the ingots were then heat treated at 800, 900, 1000 or 1100 degree C for 2 hr followed by water quenching. The hardness and microstructure of each specimen was compared to the baseline material (55-Nitinol, 55 at.% nickel - 45 at.% titanium, after heat treatment at 900 degC). The results show that eleven of the studied compounds had higher hardness values than the baseline material. Moreover, twelve of the studied compounds had measured hardness values greater 600HV at heat treatments from 800 to 900 degree C.

  17. Effect of Water Hardness on Bioremoval of Arsenic and Nickel

    NASA Astrophysics Data System (ADS)

    Sternberg, S. P.

    2008-12-01

    Laboratory experiments explored the effect of water hardness on the ability of Lemna m to sorb Arsenic and Nickel from water. System variables included the presence of hardness (100 mg/L as CaCO3), Arsenic (1.0 mg/L), Nickel (1.0 mg/L), and the aquatic plant Lemna m. Values were chosen to represent approximate values from drainage water in a sulfide mine. A four factor, two level factorial experimental design was used to determine the effect of each variable and the interactions between the variables. Results suggest no significant interaction between water hardness and the bioremoval of As or Ni. This finding suggests a useful alternative to chemical precipitation based removals which commonly must reduce water hardness before removing other contaminants.

  18. Beta Backscatter Measures the Hardness of Rubber

    NASA Technical Reports Server (NTRS)

    Morrissey, E. T.; Roje, F. N.

    1986-01-01

    Nondestructive testing method determines hardness, on Shore scale, of room-temperature-vulcanizing silicone rubber. Measures backscattered beta particles; backscattered radiation count directly proportional to Shore hardness. Test set calibrated with specimen, Shore hardness known from mechanical durometer test. Specimen of unknown hardness tested, and radiation count recorded. Count compared with known sample to find Shore hardness of unknown.

  19. Melting of polydisperse hard disks.

    PubMed

    Pronk, Sander; Frenkel, Daan

    2004-06-01

    The melting of a polydisperse hard-disk system is investigated by Monte Carlo simulations in the semigrand canonical ensemble. This is done in the context of possible continuous melting by a dislocation-unbinding mechanism, as an extension of the two-dimensional hard-disk melting problem. We find that while there is pronounced fractionation in polydispersity, the apparent density-polydispersity gap does not increase in width, contrary to 3D polydisperse hard spheres. The point where the Young's modulus is low enough for the dislocation unbinding to occur moves with the apparent melting point, but stays within the density gap, just like for the monodisperse hard-disk system. Additionally, we find that throughout the accessible polydispersity range, the bound dislocation-pair concentration is high enough to affect the dislocation-unbinding melting as predicted by Kosterlitz, Thouless, Halperin, Nelson, and Young.

  20. Instabilities in the equations of state of hard-disk and hard-sphere fluids from the virial expansions

    NASA Astrophysics Data System (ADS)

    Maeso, M. J.; Solana, J. R.

    1993-07-01

    Equations of state for hard-disk and hard-sphere fluids are obtained from a generalization of the Carnahan-Starling method of direct summation of the virial series. The equations of state thus obtained, besides reproducing all known virial coefficients, agree very accurately with simulation data for stable fluids. If appropriate values for the sixth and seventh virial coefficients are chosen within their uncertainty, the equations of state predict that the fluids become unstable at Kauzmann's density.

  1. The hard truth

    SciTech Connect

    Hanson, K.M.; Cunningham, C.S.

    1994-12-31

    In the Bayesian methodology, the posterior probability combines uncertainty about prior knowledge, and available data about alternative models of reality. The posterior quantifies the degree of certainty one has in inferring the truth in terms of those models. We propose a method to determine the reliability of a specific feature of a Bayesian solution. Our approach is based on an analogy between the negative logarithm of the posterior and a physical potential. This analogy leads to the interpretation of gradient of this potential as a force that acts on the model. As model parameters are perturbed from their maximum a posteriori (MAP) values, the strength of the restoring force that drives them back to the MAP solution is directly related to the reliability of those parameter estimates. The correlations between the uncertainties of parameter estimates can be elucidated.

  2. Hard Constraints in Optimization Under Uncertainty

    NASA Technical Reports Server (NTRS)

    Crespo, Luis G.; Giesy, Daniel P.; Kenny, Sean P.

    2008-01-01

    This paper proposes a methodology for the analysis and design of systems subject to parametric uncertainty where design requirements are specified via hard inequality constraints. Hard constraints are those that must be satisfied for all parameter realizations within a given uncertainty model. Uncertainty models given by norm-bounded perturbations from a nominal parameter value, i.e., hyper-spheres, and by sets of independently bounded uncertain variables, i.e., hyper-rectangles, are the focus of this paper. These models, which are also quite practical, allow for a rigorous mathematical treatment within the proposed framework. Hard constraint feasibility is determined by sizing the largest uncertainty set for which the design requirements are satisfied. Analytically verifiable assessments of robustness are attained by comparing this set with the actual uncertainty model. Strategies that enable the comparison of the robustness characteristics of competing design alternatives, the description and approximation of the robust design space, and the systematic search for designs with improved robustness are also proposed. Since the problem formulation is generic and the tools derived only require standard optimization algorithms for their implementation, this methodology is applicable to a broad range of engineering problems.

  3. Evaluation of mechanical properties of some glycine complexes

    SciTech Connect

    Nagaraju, D.; Raja Shekar, P. V.; Chandra, Ch. Sateesh; Rao, K. Kishan; Krishna, N. Gopi

    2014-04-24

    The variation of Vickers hardness with load for (101) glycine zinc chloride (GZC), (001) glycine lithium sulphate (GLS), (001) triglycine sulphate (TGS) and (010) glycine phosphite (GPI) crystals was studied. From the cracks initiated along the corners of the indentation impression, crack lengths were measured and the fracture toughness value and brittle index number were determined. The hardness related parameters viz. yield strength and Young’s modulus were also estimated. The anisotropic nature of the crystals was studied using Knoop indentation technique.

  4. Valuing Essays: Essaying Values

    ERIC Educational Resources Information Center

    Badley, Graham

    2010-01-01

    The essay regularly comes under attack. It is criticised for being rigidly linear rather than flexible and reflective. I first challenge this view by examining reasons why the essay should be valued as an important genre. Secondly, I propose that in using the essay form students and academics necessarily exemplify their own critical values. Essays…

  5. A new algorithm for the evaluation of the global hardness of polyatomic molecules

    NASA Astrophysics Data System (ADS)

    Islam, Nazmul; Ghosh, Dulal Chandra

    2011-03-01

    Relying upon the commonality of the basic philosophy of the origin and development of electronegativity and hardness, we have attempted to explore whether a hardness equalization principle can be conceived for polyatomic molecules analogous to the electronegativity equalization principle. Starting from the new radial-dependent electrostatic definition of hardness of atoms suggested by the present authors and assuming that the hardness equalization principle is operative and valid, we have derived a formula for evaluating the hardness of polyatomic molecule, ? , where n is the number of ligands, ri is the atomic radius of the ith atom and C is a constant. The formula has been used to calculate the hardness values of 380 polyatomic molecules with widely divergent physico-chemical properties. The computed hardness data of a set of representative molecules are in good agreement with the corresponding hardness data evaluated quantum mechanically. The hardness data of the present work are found to be quite efficacious in explaining the known reaction surfaces of some well-known hard-soft acid-base exchange reactions in the real world. However, the hardness data evaluated through the ansatz and operational and approximate formula of Parr and Pearson poorly correlate the same reaction surface. This study reveals that the new definition of hardness and the assumed model of hardness equalization are scientifically acceptable valid propositions.

  6. Exchange-spring mechanism of soft and hard ferrite nanocomposites

    SciTech Connect

    Manjura Hoque, S.; Srivastava, C.; Kumar, V.; Venkatesh, N.; Das, H.N.; Saha, D.K.; Chattopadhyay, K.

    2013-08-01

    Graphical abstract: - Highlights: • Exchange-spring behaviour of soft and hard ferrites was studied. • XRD patterns indicated soft and hard ferrites as fcc and hcp structure. • Hysteresis loops indicate wide difference in coercivity of soft and hard phases. • Nanocomposites produced convex hysteresis loop characteristic of single-phase. - Abstract: The paper reports exchange-spring soft and hard ferrite nanocomposites synthesized by chemical co-precipitation with or without the application of ultrasonic vibration. The composites contained BaFe{sub 12}O{sub 19} as the hard phase and CoFe{sub 2}O{sub 4}/MgFe{sub 2}O{sub 4} as the soft phase. X-ray diffraction patterns of the samples in the optimum calcined condition indicated the presence of soft ferrites as face-centred cubic (fcc) and hard ferrites as hexagonal close packed (hcp) structure respectively. Temperature dependence of magnetization in the range of 20–700 °C demonstrated distinct presence of soft and hard ferrites as magnetic phases which are characterized by wide difference in magnetic anisotropy and coercivity. Exchange-spring mechanism led these nanocomposite systems to exchange-coupled, which ultimately produced convex hysteresis loops characteristic of a single-phase permanent magnet. Fairly high value of coercivity and maximum energy product were observed for the samples in the optimum calcined conditions with a maximum applied field of 1600 kA/m (2 T)

  7. Demixing in binary mixtures of apolar and dipolar hard spheres

    NASA Astrophysics Data System (ADS)

    Almarza, N. G.; Lomba, E.; Martín, C.; Gallardo, A.

    2008-12-01

    We study the demixing transition of mixtures of equal size hard spheres and dipolar hard spheres using computer simulation and integral equation theories. Calculations are carried out at constant pressure, and it is found that there is a strong correlation between the total density and the composition. The critical temperature and the critical total density are found to increase with pressure. The critical mole fraction of the dipolar component on the contrary decreases as pressure is augmented. These qualitative trends are reproduced by the theoretical approaches that on the other hand overestimate by far the value of the critical temperature. Interestingly, the critical parameters for the liquid-vapor equilibrium extrapolated from the mixture results in the limit of vanishing neutral hard sphere concentration agree rather well with recent estimates based on the extrapolation of charged hard dumbbell phase equilibria when dumbbell elongation shrinks to zero [G. Ganzenmüller and P. J. Camp, J. Chem. Phys. 126, 191104 (2007)].

  8. Effect of coatings on hardness of commercial marbles

    NASA Astrophysics Data System (ADS)

    Zedef, Veysel

    2016-04-01

    In this study, three type of marble and one granite were chosen to understand if the coating is effective on hardness of the commercial rocks. To understand the hardness of the rock, Schmidt hammer tests were undertaken. The used device allowed us uniaxial compressive strength (UCS) as well as Schmidt rebound (R). The coated samples have clearly high R and UCS values when compared to uncoated samples. The Elazig visne, the well-known marble of Turkey, have 35.6 R and 44.2 MPa UCS values of coated samples. On the other hand, uncoated surface of the same marble have 30.5 R and 35.4 MPa UCS.

  9. Hard diffraction in Pythia 8

    NASA Astrophysics Data System (ADS)

    Overgaard Rasmussen, Christine

    2016-07-01

    We present an overview of the options for diffraction implemented in the general-purpose event generator Pythia 8 [1]. We review the existing model for soft diffraction and present a new model for hard diffraction. Both models use the Pomeron approach pioneered by Ingelman and Schlein, factorising the diffractive cross section into a Pomeron flux and a Pomeron PDF, with several choices for both implemented in Pythia 8. The model of hard diffraction is implemented as a part of the multiparton interactions (MPI) framework, thus introducing a dynamical gap survival probability that explicitly breaks factorisation.

  10. Hardness of ion implanted ceramics

    SciTech Connect

    Oliver, W.C.; McHargue, C.J.; Farlow, G.C.; White, C.W.

    1985-01-01

    It has been established that the wear behavior of ceramic materials can be modified through ion implantation. Studies have been done to characterize the effect of implantation on the structure and composition of ceramic surfaces. To understand how these changes affect the wear properties of the ceramic, other mechanical properties must be measured. To accomplish this, a commercially available ultra low load hardness tester has been used to characterize Al/sub 2/O/sub 3/ with different implanted species and doses. The hardness of the base material is compared with the highly damaged crystalline state as well as the amorphous material.

  11. Hard-on-Hard Total Hip Impingement Causes Extreme Contact Stress Concentrations

    PubMed Central

    Elkins, Jacob M.; O’Brien, Megan K.; Stroud, Nicholas J.; Pedersen, Douglas R.; Callaghan, John J.

    2010-01-01

    Background Impingement events, in addition to their role immediately proximate to frank dislocation, hold the potential to damage new-generation hard-on-hard bearings as a result of the relatively unforgiving nature of the materials and designs. Because of the higher stiffness and tighter design tolerances of metal-on-metal and ceramic implants, surgical positioning plausibly has become even more important. Questions/purposes We asked (1) whether, and under what cup orientation conditions, hard-on-hard impingements might challenge implant material failure strength; and (2) whether particle generation propensity at impingement and egress sites would show similar dependence on cup orientation. Methods Realistic computational simulations were enabled by multistage finite element analyses, addressing both global construct motion and loading, and focal stress concentrations at neck impingement and rim egress sites. The global model, validated by a cadaveric simulation in a servohydraulic hip simulator, included both hardware components and advanced anisotropic capsule characterization. Parametric computational runs explored the effect of cup orientation for both ceramic-on-ceramic and metal-on-metal bearing couples for two distinct motion sequences associated with dislocation. Results Stress concentrations from impingement increased nearly linearly with increased cup tilt and with cup anteversion. In some situations, peak values of stress approached or exceeded 1 GPa, levels challenging the yield strength of cobalt-chromium implants, and potentially the fracture strength of ceramics. The tendency for impingement events to generate debris, indexed in terms of a new scraping severity metric, showed orientation dependences similar to that for bulk material failure. Conclusions Damage propensity arising from impingement events in hard total hip bearings is highly orientation-dependent. PMID:20953853

  12. FATIGUE OF BIOMATERIALS: HARD TISSUES.

    PubMed

    Arola, D; Bajaj, D; Ivancik, J; Majd, H; Zhang, D

    2010-09-01

    The fatigue and fracture behavior of hard tissues are topics of considerable interest today. This special group of organic materials comprises the highly mineralized and load-bearing tissues of the human body, and includes bone, cementum, dentin and enamel. An understanding of their fatigue behavior and the influence of loading conditions and physiological factors (e.g. aging and disease) on the mechanisms of degradation are essential for achieving lifelong health. But there is much more to this topic than the immediate medical issues. There are many challenges to characterizing the fatigue behavior of hard tissues, much of which is attributed to size constraints and the complexity of their microstructure. The relative importance of the constituents on the type and distribution of defects, rate of coalescence, and their contributions to the initiation and growth of cracks, are formidable topics that have not reached maturity. Hard tissues also provide a medium for learning and a source of inspiration in the design of new microstructures for engineering materials. This article briefly reviews fatigue of hard tissues with shared emphasis on current understanding, the challenges and the unanswered questions.

  13. FATIGUE OF BIOMATERIALS: HARD TISSUES

    PubMed Central

    Arola, D.; Bajaj, D.; Ivancik, J.; Majd, H.; Zhang, D.

    2009-01-01

    The fatigue and fracture behavior of hard tissues are topics of considerable interest today. This special group of organic materials comprises the highly mineralized and load-bearing tissues of the human body, and includes bone, cementum, dentin and enamel. An understanding of their fatigue behavior and the influence of loading conditions and physiological factors (e.g. aging and disease) on the mechanisms of degradation are essential for achieving lifelong health. But there is much more to this topic than the immediate medical issues. There are many challenges to characterizing the fatigue behavior of hard tissues, much of which is attributed to size constraints and the complexity of their microstructure. The relative importance of the constituents on the type and distribution of defects, rate of coalescence, and their contributions to the initiation and growth of cracks, are formidable topics that have not reached maturity. Hard tissues also provide a medium for learning and a source of inspiration in the design of new microstructures for engineering materials. This article briefly reviews fatigue of hard tissues with shared emphasis on current understanding, the challenges and the unanswered questions. PMID:20563239

  14. What Value "Value Added"?

    ERIC Educational Resources Information Center

    Richards, Andrew

    2015-01-01

    Two quantitative measures of school performance are currently used, the average points score (APS) at Key Stage 2 and value-added (VA), which measures the rate of academic improvement between Key Stage 1 and 2. These figures are used by parents and the Office for Standards in Education to make judgements and comparisons. However, simple…

  15. Exclusive, hard diffraction in QCD

    NASA Astrophysics Data System (ADS)

    Freund, Andreas

    In the first chapter we give an introduction to hard diffractive scattering in QCD to introduce basic concepts and terminology, thus setting the stage for the following chapters. In the second chapter we make predictions for nondiagonal parton distributions in a proton in the LLA. We calculate the DGLAP-type evolution kernels in the LLA, solve the nondiagonal GLAP evolution equations with a modified version of the CTEQ-package and comment on the range of applicability of the LLA in the asymmetric regime. We show that the nondiagonal gluon distribution g(x1,x2,t,μ2) can be well approximated at small x by the conventional gluon density xG(x,μ2). In the third chapter, we discuss the algorithms used in the LO evolution program for nondiagonal parton distributions in the DGLAP region and discuss the stability of the code. Furthermore, we demonstrate that we can reproduce the case of the LO diagonal evolution within less than 0.5% of the original code as developed by the CTEQ-collaboration. In chapter 4, we show that factorization holds for the deeply virtual Compton scattering amplitude in QCD, up to power suppressed terms, to all orders in perturbation theory. Furthermore, we show that the virtuality of the produced photon does not influence the general theorem. In chapter 5, we demonstrate that perturbative QCD allows one to calculate the absolute cross section of diffractive exclusive production of photons at large Q2 at HERA, while the aligned jet model allows one to estimate the cross section for intermediate Q2~2GeV2. Furthermore, we find that the imaginary part of the amplitude for the production of real photons is larger than the imaginary part of the corresponding DIS amplitude, leading to predictions of a significant counting rate for the current generation of experiments at HERA. We also find a large azimuthal angle asymmetry in ep scattering for HERA kinematics which allows one to directly measure the real part of the DVCS amplitude and hence the

  16. Hard processes in hadronic interactions

    SciTech Connect

    Satz, H. |; Wang, X.N.

    1995-07-01

    Quantum chromodynamics is today accepted as the fundamental theory of strong interactions, even though most hadronic collisions lead to final states for which quantitative QCD predictions are still lacking. It therefore seems worthwhile to take stock of where we stand today and to what extent the presently available data on hard processes in hadronic collisions can be accounted for in terms of QCD. This is one reason for this work. The second reason - and in fact its original trigger - is the search for the quark-gluon plasma in high energy nuclear collisions. The hard processes to be considered here are the production of prompt photons, Drell-Yan dileptons, open charm, quarkonium states, and hard jets. For each of these, we discuss the present theoretical understanding, compare the resulting predictions to available data, and then show what behaviour it leads to at RHIC and LHC energies. All of these processes have the structure mentioned above: they contain a hard partonic interaction, calculable perturbatively, but also the non-perturbative parton distribution within a hadron. These parton distributions, however, can be studied theoretically in terms of counting rule arguments, and they can be checked independently by measurements of the parton structure functions in deep inelastic lepton-hadron scattering. The present volume is the work of Hard Probe Collaboration, a group of theorists who are interested in the problem and were willing to dedicate a considerable amount of their time and work on it. The necessary preparation, planning and coordination of the project were carried out in two workshops of two weeks` duration each, in February 1994 at CERn in Geneva andin July 1994 at LBL in Berkeley.

  17. Segregation of Fluidized Binary Hard-Sphere Systems Under Gravity

    NASA Astrophysics Data System (ADS)

    Kim, Soon-Chul

    We have derived an analytic expression for the contact value of the local density of binary hard-sphere systems under gravity. We have obtained the crossover conditions for the Brazil-nut type segregation of binary hard-sphere mixtures and binary hard-sphere chain mixtures from the segregation criterion, where the segregation occurs when the density (or the pressure) of the small spheres at the bottom is higher than that of the large spheres, or vice versa. For the binary hard-sphere chain mixtures, the crossover condition for the segregation depends on the number of monomers composed of hard-sphere chains as well as the mass and the diameter of each species. The fundamental-measure theories (FMTs) and local density approximation (LDA) are employed to examine the crossover condition for the segregation of the gravity-induced hard-sphere mixtures. The calculated results show that the LDA does not explain the density oscillation near the bottom, whereas the modified fundamental-measure theory (MFMT) compares with molecular dynamics simulations.

  18. A finger-like hardness tester based on the contact electromechanical impedance of a piezoelectric bimorph cantilever

    NASA Astrophysics Data System (ADS)

    Fu, Ji; Li, Faxin

    2015-10-01

    We proposed a finger-like hardness tester based on the electromechanical impedance of a piezoelectric bimorph cantilever. A Vickers indenter was fabricated to the free end of the bimorph to contact the sample. The contact force was monitored by a strain gauge and the contact area was obtained by tracking the bimorph's resonance frequency. The bimorph-sample contact system was modeled by the electromechanical equivalent circuit method. Verification experiments on standard hardness samples were conducted and the measured hardness values agreed well with those given by a conventional Vickers hardness tester. Further hardness measurement on a gear wheel showed that the proposed hardness tester is very adaptive and can be used for inner surface testing or in situ testing, where other hardness testers may not be applicable. The proposed hardness tester can be regarded as an improved ultrasonic hardness tester.

  19. Ultrasonic material hardness depth measurement

    DOEpatents

    Good, Morris S.; Schuster, George J.; Skorpik, James R.

    1997-01-01

    The invention is an ultrasonic surface hardness depth measurement apparatus and method permitting rapid determination of hardness depth of shafts, rods, tubes and other cylindrical parts. The apparatus of the invention has a part handler, sensor, ultrasonic electronics component, computer, computer instruction sets, and may include a display screen. The part handler has a vessel filled with a couplant, and a part rotator for rotating a cylindrical metal part with respect to the sensor. The part handler further has a surface follower upon which the sensor is mounted, thereby maintaining a constant distance between the sensor and the exterior surface of the cylindrical metal part. The sensor is mounted so that a front surface of the sensor is within the vessel with couplant between the front surface of the sensor and the part.

  20. Overview-hard rock penetration

    SciTech Connect

    Dunn, J.C. )

    1993-01-01

    The Hard Rock Penetration program is developing technology to reduce the costs of drilling and completing geothermal wells. Current projects include: lost circulation control, borehole instrumentation, acoustic telemetry, slimhole drilling, geothermal heat pumps. A new project to improve synthetic diamond drill bits for hard rock drilling was initiated during the year. Accomplishments during the year include completion of important acoustic telemetry tests in the Long Valley Well. These tests produced the first set of reliable, repeatable data in a drill hole. The results indicate the promise of acoustic transmission through drill pipe for great distances without repeaters. The rolling float meter for measuring drilling fluid outflow was duplicated and sent to six different companies for evaluation in the field. A new slimhole spectral gamma tool for operation at temperatures up to 300 C was fabricated and evaluated in the laboratory. Slimhole drilling for exploration and reservoir characterization was begun with several projects jointly completed with industry.

  1. Ultrasonic material hardness depth measurement

    DOEpatents

    Good, M.S.; Schuster, G.J.; Skorpik, J.R.

    1997-07-08

    The invention is an ultrasonic surface hardness depth measurement apparatus and method permitting rapid determination of hardness depth of shafts, rods, tubes and other cylindrical parts. The apparatus of the invention has a part handler, sensor, ultrasonic electronics component, computer, computer instruction sets, and may include a display screen. The part handler has a vessel filled with a couplant, and a part rotator for rotating a cylindrical metal part with respect to the sensor. The part handler further has a surface follower upon which the sensor is mounted, thereby maintaining a constant distance between the sensor and the exterior surface of the cylindrical metal part. The sensor is mounted so that a front surface of the sensor is within the vessel with couplant between the front surface of the sensor and the part. 12 figs.

  2. Microwave assisted hard rock cutting

    DOEpatents

    Lindroth, David P.; Morrell, Roger J.; Blair, James R.

    1991-01-01

    An apparatus for the sequential fracturing and cutting of subsurface volume of hard rock (102) in the strata (101) of a mining environment (100) by subjecting the volume of rock to a beam (25) of microwave energy to fracture the subsurface volume of rock by differential expansion; and , then bringing the cutting edge (52) of a piece of conventional mining machinery (50) into contact with the fractured rock (102).

  3. Results on hard diffractive production

    SciTech Connect

    Goulianos, K.

    1995-07-01

    The results of experiments at hadron colliders probing the structure of the pomeron through hard diffraction are reviewed. Some results on deep inelastic diffractive scattering obtained a HERA are also discussed and placed in perspective. By using a properly normalized pomeron flux factor in single diffraction dissociation, as dictated by unitarity, the pomeron emerges as a combination of valence quark and gluon color singlets in a ratio suggested by asymptopia.

  4. Schwannoma of the hard palate

    PubMed Central

    Sahoo, Pradyumna Kumar; Mandal, Palash Kumar; Ghosh, Saradindu

    2014-01-01

    Schwannomas are benign encapsulated perineural tumors. The head and neck region is the most common site. Intraoral origin is seen in only 1% of cases, tongue being the most common site; its location in the palate is rare. We report a case of hard-palate schwannoma with bony erosion which was immunohistochemically confirmed. The tumor was excised completely intraorally. After two months of follow-up, the defect was found to be completely covered with palatal mucosa. PMID:25298716

  5. Submicron cubic boron nitride as hard as diamond

    NASA Astrophysics Data System (ADS)

    Liu, Guoduan; Kou, Zili; Yan, Xiaozhi; Lei, Li; Peng, Fang; Wang, Qiming; Wang, Kaixue; Wang, Pei; Li, Liang; Li, Yong; Li, Wentao; Wang, Yonghua; Bi, Yan; Leng, Yang; He, Duanwei

    2015-03-01

    Here, we report the sintering of aggregated submicron cubic boron nitride (sm-cBN) at a pressure of 8 GPa. The sintered cBN compacts exhibit hardness values comparable to that of single crystal diamond, fracture toughness about 5-fold that of cBN single crystal, in combination with a high oxidization temperature. Thus, another way has been demonstrated to improve the mechanical properties of cBN besides reducing the grain size to nano scale. In contrast to other ultrahard compacts with similar hardness, the sm-cBN aggregates are better placed for potential industrial application, as their relative low pressure manufacturing perhaps be easier and cheaper.

  6. Virial coefficients and equations of state for mixtures of hard discs, hard spheres and hard hyperspheres

    NASA Astrophysics Data System (ADS)

    Santos, A.; Yuste, S. B.; López de Haro, M.

    The composition-independent virial coefficients of a d-dimensional binary mixture of (additive) hard hyperspheres following from a recent proposal for the equation of state of the mixture (SANTOS, A., YUSTE, S. B., and LÓPEZ DE HARO, M., 1999, Molec. Phys., 96 , 1) are examined. Good agreement between theoretical estimates and available exact or numerical results is found for d = 2, 3, 4 and 5, except for mixtures whose components are very disparate in size. A slight modification that remedies this deficiency is introduced and the resummation of the associated virial series is carried out, leading to a new proposal for the equation of state. The case of binary hard sphere mixtures (d = 3) is analysed in some detail.

  7. Comparison of time-dependent changes in the surface hardness of different composite resins

    PubMed Central

    Ozcan, Suat; Yikilgan, Ihsan; Uctasli, Mine Betul; Bala, Oya; Kurklu, Zeliha Gonca Bek

    2013-01-01

    Objective: The aim of this study was to evaluate the change in surface hardness of silorane-based composite resin (Filtek Silorane) in time and compare the results with the surface hardness of two methacrylate-based resins (Filtek Supreme and Majesty Posterior). Materials and Methods: From each composite material, 18 wheel-shaped samples (5-mm diameter and 2-mm depth) were prepared. Top and bottom surface hardness of these samples was measured using a Vicker's hardness tester. The samples were then stored at 37°C and 100% humidity. After 24 h and 7, 30 and 90 days, the top and bottom surface hardness of the samples was measured. In each measurement, the rate between the hardness of the top and bottom surfaces were recorded as the hardness rate. Statistical analysis was performed by one-way analysis of variance, multiple comparisons by Tukey's test and binary comparisons by t-test with a significance level of P = 0.05. Results: The highest hardness values were obtained from each two surfaces of Majesty Posterior and the lowest from Filtek Silorane. Both the top and bottom surface hardness of the methacrylate based composite resins was high and there was a statistically significant difference between the top and bottom hardness values of only the silorane-based composite, Filtek Silorane (P < 0.05). The lowest was obtained with Filtek Silorane. The hardness values of all test groups increased after 24 h (P < 0.05). Conclusion: Although silorane-based composite resin Filtek Silorane showed adequate hardness ratio, the use of incremental technic during application is more important than methacrylate based composites. PMID:24966724

  8. 7 CFR 201.57 - Hard seeds.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... REGULATIONS Germination Tests in the Administration of the Act § 201.57 Hard seeds. Seeds which remain hard at..., are to be counted as “hard seed.” If at the end of the germination period provided for legumes, okra... percentage of germination. For flatpea, continue the swollen seed in test for 14 days when germinating at...

  9. 7 CFR 201.57 - Hard seeds.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... REGULATIONS Germination Tests in the Administration of the Act § 201.57 Hard seeds. Seeds which remain hard at..., are to be counted as “hard seed.” If at the end of the germination period provided for legumes, okra... percentage of germination. For flatpea, continue the swollen seed in test for 14 days when germinating at...

  10. 7 CFR 201.57 - Hard seeds.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... REGULATIONS Germination Tests in the Administration of the Act § 201.57 Hard seeds. Seeds which remain hard at..., are to be counted as “hard seed.” If at the end of the germination period provided for legumes, okra... percentage of germination. For flatpea, continue the swollen seed in test for 14 days when germinating at...

  11. 7 CFR 201.57 - Hard seeds.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... REGULATIONS Germination Tests in the Administration of the Act § 201.57 Hard seeds. Seeds which remain hard at..., are to be counted as “hard seed.” If at the end of the germination period provided for legumes, okra... percentage of germination. For flatpea, continue the swollen seed in test for 14 days when germinating at...

  12. 7 CFR 201.57 - Hard seeds.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... REGULATIONS Germination Tests in the Administration of the Act § 201.57 Hard seeds. Seeds which remain hard at..., are to be counted as “hard seed.” If at the end of the germination period provided for legumes, okra... percentage of germination. For flatpea, continue the swollen seed in test for 14 days when germinating at...

  13. 7 CFR 201.30 - Hard seed.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 3 2012-01-01 2012-01-01 false Hard seed. 201.30 Section 201.30 Agriculture..., Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE (CONTINUED) FEDERAL SEED ACT FEDERAL SEED ACT REGULATIONS Labeling Vegetable Seeds § 201.30 Hard seed. The label shall show the percentage of hard seed,...

  14. 7 CFR 201.30 - Hard seed.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 3 2014-01-01 2014-01-01 false Hard seed. 201.30 Section 201.30 Agriculture..., Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE (CONTINUED) FEDERAL SEED ACT FEDERAL SEED ACT REGULATIONS Labeling Vegetable Seeds § 201.30 Hard seed. The label shall show the percentage of hard seed,...

  15. 7 CFR 201.21 - Hard seed.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 3 2013-01-01 2013-01-01 false Hard seed. 201.21 Section 201.21 Agriculture..., Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE (CONTINUED) FEDERAL SEED ACT FEDERAL SEED ACT REGULATIONS Labeling Agricultural Seeds § 201.21 Hard seed. The label shall show the percentage of hard...

  16. 7 CFR 201.21 - Hard seed.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 3 2012-01-01 2012-01-01 false Hard seed. 201.21 Section 201.21 Agriculture..., Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE (CONTINUED) FEDERAL SEED ACT FEDERAL SEED ACT REGULATIONS Labeling Agricultural Seeds § 201.21 Hard seed. The label shall show the percentage of hard...

  17. 7 CFR 201.30 - Hard seed.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 3 2011-01-01 2011-01-01 false Hard seed. 201.30 Section 201.30 Agriculture..., Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE (CONTINUED) FEDERAL SEED ACT FEDERAL SEED ACT REGULATIONS Labeling Vegetable Seeds § 201.30 Hard seed. The label shall show the percentage of hard seed,...

  18. 7 CFR 201.21 - Hard seed.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Hard seed. 201.21 Section 201.21 Agriculture..., Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE (CONTINUED) FEDERAL SEED ACT FEDERAL SEED ACT REGULATIONS Labeling Agricultural Seeds § 201.21 Hard seed. The label shall show the percentage of hard...

  19. 7 CFR 201.30 - Hard seed.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Hard seed. 201.30 Section 201.30 Agriculture..., Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE (CONTINUED) FEDERAL SEED ACT FEDERAL SEED ACT REGULATIONS Labeling Vegetable Seeds § 201.30 Hard seed. The label shall show the percentage of hard seed,...

  20. 7 CFR 201.21 - Hard seed.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 3 2014-01-01 2014-01-01 false Hard seed. 201.21 Section 201.21 Agriculture..., Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE (CONTINUED) FEDERAL SEED ACT FEDERAL SEED ACT REGULATIONS Labeling Agricultural Seeds § 201.21 Hard seed. The label shall show the percentage of hard...

  1. 7 CFR 201.21 - Hard seed.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 3 2011-01-01 2011-01-01 false Hard seed. 201.21 Section 201.21 Agriculture..., Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE (CONTINUED) FEDERAL SEED ACT FEDERAL SEED ACT REGULATIONS Labeling Agricultural Seeds § 201.21 Hard seed. The label shall show the percentage of hard...

  2. 7 CFR 201.30 - Hard seed.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 3 2013-01-01 2013-01-01 false Hard seed. 201.30 Section 201.30 Agriculture..., Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE (CONTINUED) FEDERAL SEED ACT FEDERAL SEED ACT REGULATIONS Labeling Vegetable Seeds § 201.30 Hard seed. The label shall show the percentage of hard seed,...

  3. 30 CFR 56.15002 - Hard hats.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Hard hats. 56.15002 Section 56.15002 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Personal Protection § 56.15002 Hard hats. All persons shall wear suitable hard hats when in or around a mine or plant where falling...

  4. 30 CFR 57.15002 - Hard hats.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Hard hats. 57.15002 Section 57.15002 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND... Underground § 57.15002 Hard hats. All persons shall wear suitable hard hats when in or around a mine or...

  5. Charpy Impact Energy and Microindentation Hardness of 60-NITINOL

    NASA Technical Reports Server (NTRS)

    Stanford, Malcolm K.

    2012-01-01

    60-NITINOL (60 wt.% Ni 40 wt.% Ti) is being studied as a material for advanced aerospace components. The Charpy impact energy and microindentation hardness has been studied for this material, fabricated by vacuum induction skull melting (casting) and by hot isostatic pressing. Test specimens were prepared in various hardened and annealed heat treatment conditions. The average impact energy ranged from 0.33 to 0.49J for the hardened specimens while the annealed specimens had impact energies ranging from 0.89 to 1.18J. The average hardness values of the hardened specimens ranged from 590 to 676 HV while that of the annealed specimens ranged from 298 to 366 HV, suggesting an inverse relationship between impact energy and hardness. These results are expected to provide guidance in the selection of heat treatment processes for the design of mechanical components.

  6. Tuning hardness in calcite by incorporation of amino acids

    NASA Astrophysics Data System (ADS)

    Kim, Yi-Yeoun; Carloni, Joseph D.; Demarchi, Beatrice; Sparks, David; Reid, David G.; Kunitake, Miki E.; Tang, Chiu C.; Duer, Melinda J.; Freeman, Colin L.; Pokroy, Boaz; Penkman, Kirsty; Harding, John H.; Estroff, Lara A.; Baker, Shefford P.; Meldrum, Fiona C.

    2016-08-01

    Structural biominerals are inorganic/organic composites that exhibit remarkable mechanical properties. However, the structure-property relationships of even the simplest building unit--mineral single crystals containing embedded macromolecules--remain poorly understood. Here, by means of a model biomineral made from calcite single crystals containing glycine (0-7 mol%) or aspartic acid (0-4 mol%), we elucidate the origin of the superior hardness of biogenic calcite. We analysed lattice distortions in these model crystals by using X-ray diffraction and molecular dynamics simulations, and by means of solid-state nuclear magnetic resonance show that the amino acids are incorporated as individual molecules. We also demonstrate that nanoindentation hardness increased with amino acid content, reaching values equivalent to their biogenic counterparts. A dislocation pinning model reveals that the enhanced hardness is determined by the force required to cut covalent bonds in the molecules.

  7. Tuning hardness in calcite by incorporation of amino acids.

    PubMed

    Kim, Yi-Yeoun; Carloni, Joseph D; Demarchi, Beatrice; Sparks, David; Reid, David G; Kunitake, Miki E; Tang, Chiu C; Duer, Melinda J; Freeman, Colin L; Pokroy, Boaz; Penkman, Kirsty; Harding, John H; Estroff, Lara A; Baker, Shefford P; Meldrum, Fiona C

    2016-08-01

    Structural biominerals are inorganic/organic composites that exhibit remarkable mechanical properties. However, the structure-property relationships of even the simplest building unit-mineral single crystals containing embedded macromolecules-remain poorly understood. Here, by means of a model biomineral made from calcite single crystals containing glycine (0-7 mol%) or aspartic acid (0-4 mol%), we elucidate the origin of the superior hardness of biogenic calcite. We analysed lattice distortions in these model crystals by using X-ray diffraction and molecular dynamics simulations, and by means of solid-state nuclear magnetic resonance show that the amino acids are incorporated as individual molecules. We also demonstrate that nanoindentation hardness increased with amino acid content, reaching values equivalent to their biogenic counterparts. A dislocation pinning model reveals that the enhanced hardness is determined by the force required to cut covalent bonds in the molecules. PMID:27135858

  8. The Hard Problem of Cooperation

    PubMed Central

    Eriksson, Kimmo; Strimling, Pontus

    2012-01-01

    Based on individual variation in cooperative inclinations, we define the “hard problem of cooperation” as that of achieving high levels of cooperation in a group of non-cooperative types. Can the hard problem be solved by institutions with monitoring and sanctions? In a laboratory experiment we find that the answer is affirmative if the institution is imposed on the group but negative if development of the institution is left to the group to vote on. In the experiment, participants were divided into groups of either cooperative types or non-cooperative types depending on their behavior in a public goods game. In these homogeneous groups they repeatedly played a public goods game regulated by an institution that incorporated several of the key properties identified by Ostrom: operational rules, monitoring, rewards, punishments, and (in one condition) change of rules. When change of rules was not possible and punishments were set to be high, groups of both types generally abided by operational rules demanding high contributions to the common good, and thereby achieved high levels of payoffs. Under less severe rules, both types of groups did worse but non-cooperative types did worst. Thus, non-cooperative groups profited the most from being governed by an institution demanding high contributions and employing high punishments. Nevertheless, in a condition where change of rules through voting was made possible, development of the institution in this direction was more often voted down in groups of non-cooperative types. We discuss the relevance of the hard problem and fit our results into a bigger picture of institutional and individual determinants of cooperative behavior. PMID:22792282

  9. Making Nozzles From Hard Materials

    NASA Technical Reports Server (NTRS)

    Wells, Dennis L.

    1989-01-01

    Proposed method of electrical-discharge machining (EDM) cuts hard materials like silicon carbide into smoothly contoured parts. Concept developed for fabrication of interior and exterior surfaces and internal cooling channels of convergent/divergent nozzles. EDM wire at skew angle theta creates hyperboloidal cavity in tube. Wire offset from axis of tube and from axis of rotation by distance equal to throat radius. Maintaining same skew angle as that used to cut hyperboloidal inner surface but using larger offset, cooling channel cut in material near inner hyperboloidal surface.

  10. Radiation Hardness Assurance (RHA) Guideline

    NASA Technical Reports Server (NTRS)

    Campola, Michael J.

    2016-01-01

    Radiation Hardness Assurance (RHA) consists of all activities undertaken to ensure that the electronics and materials of a space system perform to their design specifications after exposure to the mission space environment. The subset of interests for NEPP and the REAG, are EEE parts. It is important to register that all of these undertakings are in a feedback loop and require constant iteration and updating throughout the mission life. More detail can be found in the reference materials on applicable test data for usage on parts.

  11. Elasticity of interfacial rafts of hard particles with soft shells.

    PubMed

    Knoche, Sebastian; Kierfeld, Jan

    2015-05-19

    We study an elasticity model for compressed protein monolayers or particle rafts at a liquid interface. Based on the microscopic view of hard-core particles with soft shells, a bead-spring model is formulated and analyzed in terms of continuum elasticity theory. The theory can be applied, for example, to hydrophobin-coated air-water interfaces or, more generally, to liquid interfaces coated with an adsorbed monolayer of interacting hard-core particles. We derive constitutive relations for such particle rafts and describe the buckling of compressed planar liquid interfaces as well as their apparent Poisson ratio. We also use the constitutive relations to obtain shape equations for pendant or buoyant capsules attached to a capillary, and to compute deflated shapes of such capsules. A comparison with capsules obeying the usual Hookean elasticity (without hard cores) reveals that the hard cores trigger capsule wrinkling. Furthermore, it is shown that a shape analysis of deflated capsules with hard-core/soft-shell elasticity gives apparent elastic moduli which can be much higher than the original values if Hookean elasticity is assumed.

  12. Elasticity of interfacial rafts of hard particles with soft shells.

    PubMed

    Knoche, Sebastian; Kierfeld, Jan

    2015-05-19

    We study an elasticity model for compressed protein monolayers or particle rafts at a liquid interface. Based on the microscopic view of hard-core particles with soft shells, a bead-spring model is formulated and analyzed in terms of continuum elasticity theory. The theory can be applied, for example, to hydrophobin-coated air-water interfaces or, more generally, to liquid interfaces coated with an adsorbed monolayer of interacting hard-core particles. We derive constitutive relations for such particle rafts and describe the buckling of compressed planar liquid interfaces as well as their apparent Poisson ratio. We also use the constitutive relations to obtain shape equations for pendant or buoyant capsules attached to a capillary, and to compute deflated shapes of such capsules. A comparison with capsules obeying the usual Hookean elasticity (without hard cores) reveals that the hard cores trigger capsule wrinkling. Furthermore, it is shown that a shape analysis of deflated capsules with hard-core/soft-shell elasticity gives apparent elastic moduli which can be much higher than the original values if Hookean elasticity is assumed. PMID:25901364

  13. Hard and Soft Safety Verifications

    NASA Technical Reports Server (NTRS)

    Wetherholt, Jon; Anderson, Brenda

    2012-01-01

    The purpose of this paper is to examine the differences between and the effects of hard and soft safety verifications. Initially, the terminology should be defined and clarified. A hard safety verification is datum which demonstrates how a safety control is enacted. An example of this is relief valve testing. A soft safety verification is something which is usually described as nice to have but it is not necessary to prove safe operation. An example of a soft verification is the loss of the Solid Rocket Booster (SRB) casings from Shuttle flight, STS-4. When the main parachutes failed, the casings impacted the water and sank. In the nose cap of the SRBs, video cameras recorded the release of the parachutes to determine safe operation and to provide information for potential anomaly resolution. Generally, examination of the casings and nozzles contributed to understanding of the newly developed boosters and their operation. Safety verification of SRB operation was demonstrated by examination for erosion or wear of the casings and nozzle. Loss of the SRBs and associated data did not delay the launch of the next Shuttle flight.

  14. Hardness analysis of cubic metal mononitrides from first principles

    NASA Astrophysics Data System (ADS)

    Fulcher, B. D.; Cui, X. Y.; Delley, B.; Stampfl, C.

    2012-05-01

    Density functional theory calculations are performed to evaluate the hardness of various cubic metal nitrides: rocksalt TiN, VN, ZrN, NbN, AlN, and SiN; zincblende AlN and BN; and diamond C for comparison. The isotropic elastic stiffness constants cij, bulk modulus K, shear modulus G, Young's modulus E, and isotropic Poisson's ratio ν¯ are calculated. From simulated uniaxial stress-strain curves, ideal strength values σmax in the [100], [110], and [111] directions are also evaluated for all systems. In particular, rocksalt AlN is found to possess both high elastic moduli and ideal strength. These quantities are then compared for correlations with existing experimental Vicker's hardness data. The bulk modulus is found to be a poor indicator of hardness, while E, G, 1/ν¯, and σmax all exhibit stronger correlations. With a view to circumvent the need to run computationally expensive relaxation steps, different methodologies for approximating uniaxial stress-strain curves are introduced. Utilizing the anisotropic Poisson's ratio to approximate the relaxed transverse lattice parameters at a given axial strain is a good approximation to stress-strain curves, and the ideal strengths obtained in this way exhibit strong correlations to experimental Vicker's hardness values.

  15. Acute toxicity of organophosphate insecticide, dichlorvos in relation to selected water hardness for the freshwater zooplankters.

    PubMed

    Gupta, Ashok Kumar; Verma, Girraj Prasad; Jain, Khyali Lal

    2008-11-01

    Toxicity of organophosphate insecticide, i.e. dichlorvos has been investigated in relation to selected water hardness for the freshwater zooplankters such as Moina, Daphnia, cyclops and nauplii. Results revealed that dichlorvos was highly toxic to the tested zooplankters, as the LC50 values are noticed in ppb. Trend of sensitivity for different zooplankters to dichlorvos was recorded as Moina < Daphnia < nauplii < cyclops. The LC50 were found to change significantly with the change in water hardness. The zooplankters were more susceptible to dichlorvos at water hardness of 275 mgl(-1) as compared to water hardness of 540 mgl(-1) as revealed from low LC50 values. The range of safe dischargeable concentrations (1.063-1.137ppb) were too low as compared to harmless or safe concentrations (43.895-89.194 ppb) for the zooplankters at both the hardness.

  16. Acute toxicity of organophosphate insecticide, dichlorvos in relation to selected water hardness for the freshwater zooplankters.

    PubMed

    Gupta, Ashok Kumar; Verma, Girraj Prasad; Jain, Khyali Lal

    2008-11-01

    Toxicity of organophosphate insecticide, i.e. dichlorvos has been investigated in relation to selected water hardness for the freshwater zooplankters such as Moina, Daphnia, cyclops and nauplii. Results revealed that dichlorvos was highly toxic to the tested zooplankters, as the LC50 values are noticed in ppb. Trend of sensitivity for different zooplankters to dichlorvos was recorded as Moina < Daphnia < nauplii < cyclops. The LC50 were found to change significantly with the change in water hardness. The zooplankters were more susceptible to dichlorvos at water hardness of 275 mgl(-1) as compared to water hardness of 540 mgl(-1) as revealed from low LC50 values. The range of safe dischargeable concentrations (1.063-1.137ppb) were too low as compared to harmless or safe concentrations (43.895-89.194 ppb) for the zooplankters at both the hardness. PMID:19297975

  17. Depletion effects in smectic phases of hard-rod-hard-sphere mixtures.

    PubMed

    Martínez-Ratón, Y; Cinacchi, G; Velasco, E; Mederos, L

    2006-10-01

    It is known that when hard spheres are added to a pure system of hard rods the stability of the smectic phase may be greatly enhanced, and that this effect can be rationalised in terms of depletion forces. In the present paper we first study the effect of orientational order on depletion forces in this particular binary system, comparing our results with those obtained adopting the usual approximation of considering the rods parallel and their orientations frozen. We consider mixtures with rods of different aspect ratios and spheres of different diameters, and we treat them within Onsager theory. Our results indicate that depletion effects, and consequently smectic stability, decrease significantly as a result of orientational disorder in the smectic phase when compared with corresponding data based on the frozen-orientation approximation. These results are discussed in terms of the tau parameter, which has been proposed as a convenient measure of depletion strength. We present closed expressions for tau, and show that it is intimately connected with the depletion potential. We then analyse the effect of particle geometry by comparing results pertaining to systems of parallel rods of different shapes (spherocylinders, cylinders and parallelepipeds). We finally provide results based on the Zwanzig approximation of a fundamental-measure density-functional theory applied to mixtures of parallelepipeds and cubes of different sizes. In this case, we show that the tau parameter exhibits a linear asymptotic behaviour in the limit of large values of the hard-rod aspect ratio, in conformity with Onsager theory, as well as in the limit of large values of the ratio of rod breadth to cube side length, d, in contrast to Onsager approximation, which predicts tau approximately d (3). Based on both this result and the Percus-Yevick approximation for the direct correlation function for a hard-sphere binary mixture in the same limit of infinite asymmetry, we speculate that, for

  18. Formation of Diamond-like Carbon Thin Films by Ion Beam Assisted Deposition Method

    NASA Astrophysics Data System (ADS)

    Nakamura, Isao; Takano, Ichiro; Sasaki, Michiko; Takashika, Masaru; Kasiwagi, Tomohumi; Sawada, Yohio

    The mechanical properties of diamond-like carbon (DLC) thin films on SUS304 substrate have been studied. DLC thin films were prepared by the ion beam assisted deposition method. In this method, He+ ion irradiation was carried out in a C2H4 gas atmosphere. He+ ions were accelerated at an energy of 15 keV, and the ion beam current densities were changed from 10 to 100 μA/cm2. Atomic concentration and structure of the films were investigated by X-ray photoelectron spectroscopy and Raman spectroscopy. The mechanical properties of hardness and friction coefficient were determined using the Knoop hardness tester and the pin-on-disk tribometer. The DLC thin films had amorphous structure that composed chiefly of graphite and disorder of graphite states. The Knoop hardness of the films increased with increasing He+ ion current density, and the film prepared at a current density of 80 μA/cm2 showed the maximum Knoop hardness value of 890 kgf/cm2. The friction coefficient of the film prepared at a current density of 60 μA/cm2 indicated lower value than that of the other current densities. From these results, it was cleared that the mechanical properties and structure of DLC thin films were greatly affected by the He+ ion beam current density.

  19. Development of radiation hard scintillators

    SciTech Connect

    Markley, F.; Woods, D.; Pla-Dalmau, A.; Foster, G. ); Blackburn, R. )

    1992-05-01

    Substantial improvements have been made in the radiation hardness of plastic scintillators. Cylinders of scintillating materials 2.2 cm in diameter and 1 cm thick have been exposed to 10 Mrads of gamma rays at a dose rate of 1 Mrad/h in a nitrogen atmosphere. One of the formulations tested showed an immediate decrease in pulse height of only 4% and has remained stable for 12 days while annealing in air. By comparison a commercial PVT scintillator showed an immediate decrease of 58% and after 43 days of annealing in air it improved to a 14% loss. The formulated sample consisted of 70 parts by weight of Dow polystyrene, 30 pbw of pentaphenyltrimethyltrisiloxane (Dow Corning DC 705 oil), 2 pbw of p-terphenyl, 0.2 pbw of tetraphenylbutadiene, and 0.5 pbw of UVASIL299LM from Ferro.

  20. Hard X-ray astrophysics

    NASA Technical Reports Server (NTRS)

    Rothschild, R. E.

    1981-01-01

    Past hard X-ray and lower energy satellite instruments are reviewed and it is shown that observation above 20 keV and up to hundreds of keV can provide much valuable information on the astrophysics of cosmic sources. To calculate possible sensitivities of future arrays, the efficiencies of a one-atmosphere inch gas counter (the HEAO-1 A-2 xenon filled HED3) and a 3 mm phoswich scintillator (the HEAO-1 A-4 Na1 LED1) were compared. Above 15 keV, the scintillator was more efficient. In a similar comparison, the sensitivity of germanium detectors did not differ much from that of the scintillators, except at high energies where the sensitivity would remain flat and not rise with loss of efficiency. Questions to be addressed concerning the physics of active galaxies and the diffuse radiation background, black holes, radio pulsars, X-ray pulsars, and galactic clusters are examined.

  1. The Relationship Between Grain Hardness, Dough Mixing Parameters and Bread-Making Quality in Winter Wheat

    PubMed Central

    Salmanowicz, Bolesław P.; Adamski, Tadeusz; Surma, Maria; Kaczmarek, Zygmunt; Karolina, Krystkowiak; Kuczyńska, Anetta; Banaszak, Zofia; Ługowska, Bogusława; Majcher, Małgorzata; Obuchowski, Wiktor

    2012-01-01

    The influence of grain hardness, determined by using molecular markers and physical methods (near-infrared (NIR) technique and particle size index—PSI) on dough characteristics, which in turn were determined with the use of a farinograph and reomixer, as well as bread-making properties were studied. The material covered 24 winter wheat genotypes differing in grain hardness. The field experiment was conducted at standard and increased levels of nitrogen fertilization. Results of molecular analyses were in agreement with those obtained by the use of physical methods for soft-grained lines. Some lines classified as hard (by physical methods) appeared to have the wild-type Pina and Pinb alleles, similar to soft lines. Differences in dough and bread-making properties between lines classified as hard and soft on the basis of molecular data appeared to be of less significance than the differences between lines classified as hard and soft on the basis of physical analyses of grain texture. Values of relative grain hardness at the increased nitrogen fertilization level were significantly higher. At both fertilization levels the NIR parameter determining grain hardness was significantly positively correlated with the wet gluten and sedimentation values, with most of the rheological parameters and bread yield. Values of this parameter correlated with quality characteristics in a higher degree than values of particle size index. PMID:22605973

  2. Estimation of Young's modulus and of hardness by ultra-low load hardness tests with a Vickers indenter

    SciTech Connect

    Trindade, A.C. . Escola Superior de Tecnologia); Cavaleiro, A.; Fernandes, J.V. . Dept. de Engenharia Mecanica)

    1994-07-01

    The evaluation of the elastic-plastic properties of a material by using an ultra-low load hardness test requires a geometrical calibration that must take into account the imperfect form of the diamond indenter. In the present work, the Vickers indenter offset of the microindentation equipment was estimated using differently heat-treated steel samples. To this end, the dimensions of the indentations have been evaluated by two different methods: optical measurement of the diagonals and direct measurement of the penetration depth during the test. The elastic-plastic properties are then calculated from the analysis of the penetration depth/indentation load curves. The Young's modulus values determined for the different high-speed steel samples were very similar and close to the literature value for steel if the appropriate corrections are performed. The hardness values decrease when the determination procedure includes the geometrical correction of the indenter offset, and still further when using the total correction obtained by means of optical measurements of the indenter diagonal. Variation of the hardness values with the applied load is much less when the corrections are carried out.

  3. Habitat Suitability Index Models: Hard clam

    USGS Publications Warehouse

    Mulholland, Rosemarie

    1984-01-01

    Two species of hard clams occur along the Atlantic and Gulf of Mexico coasts of North America: the southern hard clam, Mercenaria campechiensis Gmelin 1791, and the northern hard clam, ~lercenaria mercenaria Linne 1758 (Wells 1957b). The latter species, also commonly kno\\'m as the quahog, was formerly named Venus mercenaria. The two species are closely related, produce viable hybrids (Menzel and Menzel 1965), and may be a single species.

  4. Hard and fragile holmium-based bulk metallic glasses

    SciTech Connect

    Luo, Q.; Zhao, D.Q.; Pan, M.X.; Wang, R.J.; Wang, W.H.

    2006-05-01

    A family of holmium-based bulk metallic glasses (BMGs) with high glass-forming ability is obtained. The Ho-based BMGs exhibit much larger elastic moduli and high thermal stability in contrast to other known rare-earth (RE)-based BMGs. In particular, the BMGs show a large value of fragility. It is expected that the hard RE-based glasses with high glass-forming ability and fragile behaviors make them the appropriate candidate for glass transition study.

  5. Specific Energy of Hard Coal Under Load

    NASA Astrophysics Data System (ADS)

    Bogusz, Anna; Bukowska, Mirosława

    2015-03-01

    The article presents results of experimental tests of energy parameters of hard coals under loading, collected from research sites located within five main geologic structures of Upper Silesian Coal Basin (GZW) - Main Trough, Main Anticline, Bytom Trough, Rybnik Trough and Chwałowice Trough. Coals from12 mines were analysed, starting with seams of group 200, through groups 400, 500, 600 and, finally, seams of group 700. Coal of each of the groups of seams underwent uniaxial compression stress of the energy parameters, in a servo-controlled testing machine MTS-810NEW, for the full range of strain of the tested coal samples. Based on the tests the dependence of different types of specific energy of longitudinal strain of coals on the value of uniaxial compression strength was determined. The dependence of the value of dissipated energy and kinetic energy of coals on the uniaxial compression strength was described with a linear function, both for coals which due to their age belong to various bed sand for various lithotypes of coal. An increase in the value of dissipated energy and in kinetic energy was observed, which was correlated with an increase in uniaxial compression strength of coal. The share of dissipated energy is dominant in the total energy of strain. Share of recoverable energy in the total energy of strain is small, independent of the compression strength of coals and is at most a few per cent high. In coals of low strength and dominant share of dissipated energy, share of recoverable energy is the biggest among the tested coals. It was shown that following an increase in compression strength the share of recoverable energy decreases, while the share of dissipated energy in the total energy increases. Further studies of specific energy of longitudinal strain of rocks in the full-range strain will be the next step inperfecting methodology of research into natural rock burst susceptibility of Carboniferous rock mass and changes in the susceptibility

  6. Prediction of Forming Limit Curves from Hardness for Steels

    NASA Astrophysics Data System (ADS)

    Pavlina, Erik J.; Van Tyne, Chester J.

    2016-08-01

    This paper presents a method for predicting the strain-based forming limit curve (FLC) for steels using hardness. The stretching side (positive minor strain component) of the FLC was calculated by using a Marciniak-Kuczyński model with a non-quadratic yield function, while the drawing side (negative minor strain component) of the FLC was predicted based on the relationship between the major and minor critical strains, in accordance with the theory of maximum sheet tension for local necking. The requisite parameter that describes the plastic flow behavior (in this case, the strain hardening exponent) was calculated, based on correlations with the measured microhardness. Additionally, the strain rate sensitivity was considered in the model by using a newly developed empirical correlation between hardness and strain rate sensitivity. This hardness-based model was used to predict FLCs that demonstrate good agreement with experimental FLCs of a high-strength low-alloy steel and a dual-phase steel. Equations are provided that enable the calculation of the FLC from given hardness values for different severities of the material inhomogeneity.

  7. Velocity and energy distributions in microcanonical ensembles of hard spheres

    NASA Astrophysics Data System (ADS)

    Scalas, Enrico; Gabriel, Adrian T.; Martin, Edgar; Germano, Guido

    2015-08-01

    In a microcanonical ensemble (constant N V E , hard reflecting walls) and in a molecular dynamics ensemble (constant N V E PG , periodic boundary conditions) with a number N of smooth elastic hard spheres in a d -dimensional volume V having a total energy E , a total momentum P , and an overall center of mass position G , the individual velocity components, velocity moduli, and energies have transformed beta distributions with different arguments and shape parameters depending on d , N , E , the boundary conditions, and possible symmetries in the initial conditions. This can be shown marginalizing the joint distribution of individual energies, which is a symmetric Dirichlet distribution. In the thermodynamic limit the beta distributions converge to gamma distributions with different arguments and shape or scale parameters, corresponding respectively to the Gaussian, i.e., Maxwell-Boltzmann, Maxwell, and Boltzmann or Boltzmann-Gibbs distribution. These analytical results agree with molecular dynamics and Monte Carlo simulations with different numbers of hard disks or spheres and hard reflecting walls or periodic boundary conditions. The agreement is perfect with our Monte Carlo algorithm, which acts only on velocities independently of positions with the collision versor sampled uniformly on a unit half sphere in d dimensions, while slight deviations appear with our molecular dynamics simulations for the smallest values of N .

  8. 30 CFR 75.1720-1 - Distinctively colored hard hats, or hard caps; identification for newly employed, inexperienced...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Distinctively colored hard hats, or hard caps... STANDARDS-UNDERGROUND COAL MINES Miscellaneous § 75.1720-1 Distinctively colored hard hats, or hard caps; identification for newly employed, inexperienced miners. Hard hats or hard caps distinctively different in...

  9. 30 CFR 77.1710-1 - Distinctively colored hard hats or hard caps; identification for newly employed, inexperienced...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Distinctively colored hard hats or hard caps... Distinctively colored hard hats or hard caps; identification for newly employed, inexperienced miners. Hard hats or hard caps distinctively different in color from those worn by experienced miners shall be worn...

  10. Tale of two hard Pomerons

    SciTech Connect

    Berera, Arjun

    2000-07-01

    Two mechanisms are examined for hard double ''pomeron'' exchange dijet production, the factorized model of Ingelman-Schlein, and the nonfactorized model of lossless jet production which exhibits the Collins-Frankfurt-Strikman mechanism. Comparisons between these two mechanisms are made of the total cross section, E{sub T} spectra, and mean rapidity spectra. For both mechanisms, several specific models are examined with the cuts of the collider detector at Fermilab (CDF), DOe, and representative cuts of CERN LHC. Distinct qualitative differences are predicted by the two mechanisms for the CDF y{sub +} spectra and for the E{sub T} spectra for all three experimental cuts. The preliminary CDF and DOe experimental data for this process are interpreted in terms of these two mechanisms. The y{sub +} spectra of the CDF data are suggestive of domination by the factorized Ingelman-Schlein mechanism, whereas the DOe data show no greater preference for either mechanism. An inconsistency is found among all the theoretical models in attempting to explain the ratio of the cross sections given by the data from these two experiments. (c) 2000 The American Physical Society.

  11. Radiation Hardness of Trigger Electronics

    NASA Astrophysics Data System (ADS)

    Zawisza, Irene; Safonov, Alexei; Gilmore, Jason; Khotilovich, Vadim

    2011-10-01

    As the maximum intensity of particle accelerators increases, probing the most basic questions of the Universe, detectors and electronics must be designed to insure reliability in high-radiation environments. As the Large Hadron Collider (LHC) beam intensity is increased, it is necessary to upgrade the electronics in the Compact Muon Solenoid (CMS). To select interesting events, CMS utilizes fast electronics, which are installed in the experimental cavern. However, much higher post-upgrade levels of radiation in the cavern set tight requirements on the radiation hardness of the new electronics. Damaging effects of high and low energy radiation leads to disruption of digital circuits and accumulated degradation of silicon components. Quantifying the radiation exposure is required for the design of a radiation-tolerant system, but current simulation studies suffer from large uncertainties. We compare simulation predictions with measured performance in two different experimental studies, which evaluate component performance for pre and post irradiation determining the survivability of electronics in the harsh CMS environment. Funded by DOE and NSF-REU Program.

  12. Indentation Load Effect on Young's Modulus and Hardness of Porous Sialon Ceramic by Depth Sensing Indentation Tests

    NASA Astrophysics Data System (ADS)

    Osman, Sahin

    2007-11-01

    Depth sensing indentation (DSI) tests at the range of 200-1800 mN are performed on porous sialon ceramic to determine the indentation load on Young's modulus and hardness values. The Young modulus and hardness (Dynamic and Martens) values are deduced by analysing the unloading segments of the DSI test load-displacement curves using the Oliver-Pharr method. It is found that Young's modulus Er, the dynamic hardness HD and the Martens hardness HM exhibit significant indentation load dependences. The values of Young's modulus and hardness decrease with the increasing indentation load, as a result of indentation load effect. The experimental hf/hm ratios lower than the critical value 0.7, with hm being the maximum penetration depth during loading and hf the final unloading depth, indicate that our sample shows the work hardening behaviour.

  13. "Hard Science" for Gifted 1st Graders

    ERIC Educational Resources Information Center

    DeGennaro, April

    2006-01-01

    "Hard Science" is designed to teach 1st grade gifted students accurate and high level science concepts. It is based upon their experience of the world and attempts to build a foundation for continued love and enjoyment of science. "Hard Science" provides field experiences and opportunities for hands-on discovery working beside experts in the field…

  14. 21 CFR 133.150 - Hard cheeses.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 2 2010-04-01 2010-04-01 false Hard cheeses. 133.150 Section 133.150 Food and... CONSUMPTION CHEESES AND RELATED CHEESE PRODUCTS Requirements for Specific Standardized Cheese and Related Products § 133.150 Hard cheeses. (a) The cheeses for which definitions and standards of identity...

  15. Retraction of Hard, Lozano, and Tversky (2006)

    ERIC Educational Resources Information Center

    Hard, B. M.; Lozano, S. C.; Tversky, B.

    2008-01-01

    Reports a retraction of "Hierarchical encoding of behavior: Translating perception into action" by Bridgette Martin Hard, Sandra C. Lozano and Barbara Tversky (Journal of Experimental Psychology: General, 2006[Nov], Vol 135[4], 588-608). All authors retract this article. Co-author Tversky and co-author Hard believe that the research results cannot…

  16. Measurements of the hard-x-ray reflectivity of iridium

    SciTech Connect

    Romaine, S.; Bruni, R.; Gorenstein, P.; Zhong, Z

    2007-01-10

    In connection with the design of a hard-x-ray telescope for the Constellation X-Ray Observatory we measured the reflectivity of an iridium-coated zerodur substrate as a function of angle at 55, 60, 70, and 80 keV at the National Synchrotron Light Source of Brookhaven National Laboratory. The optical constants were derived from the reflectivity data. The real component of the index of refraction is in excellent agreement with theoretical values at all four energies. However, the imaginary component, which is related to the mass attenuation coefficient, is 50% to 70% larger at 55, 60, and 70 keV than theoretical values.

  17. Plasticity characteristics obtained through hardness measurement

    SciTech Connect

    Milman, Y.V.; Galanov, B.A.; Chugunova, S.I. )

    1993-09-01

    A characteristic of material plasticity [delta][sub H] is proposed. [delta][sub H] is determined as a part of plastic deformation in the total deformation during indentation. The following analytic expressions for the elastic deformation [epsilon][sub e] and for the total deformation [epsilon] on the contact area indenter-specimen in the direction of loading force are obtained, [epsilon][sub e] = 1.08(1 [minus] v [minus] 2v[sup 2])H[sub V/E], [epsilon] [approx] 0.076, where H[sub V] is the Vickers hardness, E is Young's modulus, v is the Poisson ratio, and [delta][sub H] = 1 [minus] ([epsilon][sub e]/[epsilon]). The [delta][sub H] value is calculated for various crystalline materials at different temperatures and in different structural states. [delta][sub H] is consistent with the concept of plasticity established before, and to characterize the influence of temperature, alloying and strain hardening on plasticity. The necessary condition for revealing ductility at tension and bending is [delta][sub H] [>=] 0.9. [delta][sub H] can be used as a plasticity characteristic of brittle materials.

  18. Implementing QML for radiation hardness assurance

    NASA Astrophysics Data System (ADS)

    Winokur, P. S.; Sexton, F. W.; Fleetwood, D. M.; Terry, M. D.; Shaneyfelt, M. R.

    1990-12-01

    The US government has proposed a qualified manufacturers list (QML) methodology to qualify integrated circuits for high reliability and radiation hardness. An approach to implementing QML for single-event upset (SEU) immunity on 16k SRAMs that involves relating values of feedback resistance to system error rates is demonstrated. It is seen that the process capability indices, Cp and Cpk, for the manufacture of 400-k-ohm feedback resistors required to provide SEU tolerance do not conform to 6 sigma quality standards. For total-dose, interface trap charge, Delta Vit, shifts measured on transistors are correlated with circuit response in the space environment. Statistical process control (SPC) is illustrated for Delta Vit, and violations of SPC rules are interpreted in terms of continuous improvement. Design validation for SEU and quality conformance inspections for total-dose are identified as major obstacles to cost-effective QML implementation. Techniques and tools that will help QML provide real cost savings are identified as physical models, 3-D device-plus-circuit codes, and improved design simulators.

  19. High hardness in the biocompatible intermetallic compound β-Ti3Au

    PubMed Central

    Svanidze, Eteri; Besara, Tiglet; Ozaydin, M. Fevsi; Tiwary, Chandra Sekhar; Wang, Jiakui K.; Radhakrishnan, Sruthi; Mani, Sendurai; Xin, Yan; Han, Ke; Liang, Hong; Siegrist, Theo; Ajayan, Pulickel M.; Morosan, E.

    2016-01-01

    The search for new hard materials is often challenging, but strongly motivated by the vast application potential such materials hold. Ti3Au exhibits high hardness values (about four times those of pure Ti and most steel alloys), reduced coefficient of friction and wear rates, and biocompatibility, all of which are optimal traits for orthopedic, dental, and prosthetic applications. In addition, the ability of this compound to adhere to ceramic parts can reduce both the weight and the cost of medical components. The fourfold increase in the hardness of Ti3Au compared to other Ti–Au alloys and compounds can be attributed to the elevated valence electron density, the reduced bond length, and the pseudogap formation. Understanding the origin of hardness in this intermetallic compound provides an avenue toward designing superior biocompatible, hard materials. PMID:27453942

  20. Maximum hardness and minimum polarizability principles through lattice energies of ionic compounds

    NASA Astrophysics Data System (ADS)

    Kaya, Savaş; Kaya, Cemal; Islam, Nazmul

    2016-03-01

    The maximum hardness (MHP) and minimum polarizability (MPP) principles have been analyzed using the relationship among the lattice energies of ionic compounds with their electronegativities, chemical hardnesses and electrophilicities. Lattice energy, electronegativity, chemical hardness and electrophilicity values of ionic compounds considered in the present study have been calculated using new equations derived by some of the authors in recent years. For 4 simple reactions, the changes of the hardness (Δη), polarizability (Δα) and electrophilicity index (Δω) were calculated. It is shown that the maximum hardness principle is obeyed by all chemical reactions but minimum polarizability principles and minimum electrophilicity principle are not valid for all reactions. We also proposed simple methods to compute the percentage of ionic characters and inter nuclear distances of ionic compounds. Comparative studies with experimental sets of data reveal that the proposed methods of computation of the percentage of ionic characters and inter nuclear distances of ionic compounds are valid.

  1. High hardness in the biocompatible intermetallic compound β-Ti3Au.

    PubMed

    Svanidze, Eteri; Besara, Tiglet; Ozaydin, M Fevsi; Tiwary, Chandra Sekhar; Wang, Jiakui K; Radhakrishnan, Sruthi; Mani, Sendurai; Xin, Yan; Han, Ke; Liang, Hong; Siegrist, Theo; Ajayan, Pulickel M; Morosan, E

    2016-07-01

    The search for new hard materials is often challenging, but strongly motivated by the vast application potential such materials hold. Ti3Au exhibits high hardness values (about four times those of pure Ti and most steel alloys), reduced coefficient of friction and wear rates, and biocompatibility, all of which are optimal traits for orthopedic, dental, and prosthetic applications. In addition, the ability of this compound to adhere to ceramic parts can reduce both the weight and the cost of medical components. The fourfold increase in the hardness of Ti3Au compared to other Ti-Au alloys and compounds can be attributed to the elevated valence electron density, the reduced bond length, and the pseudogap formation. Understanding the origin of hardness in this intermetallic compound provides an avenue toward designing superior biocompatible, hard materials. PMID:27453942

  2. Kinetics of hardness evolution during annealing of gamma-irradiated polycarbonate

    SciTech Connect

    Yeh, S. H.; Chen, P. Y.; Lee, Sanboh; Harmon, Julie

    2012-12-01

    This study focuses on the evolution in microhardness values that accompany isothermal annealing in gamma-irradiated polycarbonate (PC). Hardness increases with increasing annealing time, temperature, and gamma radiation dose. A model composed of a mixture of first and zero order structure relaxation is proposed to interpret the hardness data. The rate constant data fit the Arrhenius equation, and the corresponding activation energy decreases with increasing dose. The extent of structural relaxation that controls the hardness in post-annealed PC increases with increasing annealing temperature and dose. The model demonstrates that hardness evolution in PC is an endothermic process. By contrast, when the model is applied to irradiated poly(methyl methacrylate) and hydroxyethyl methacrylate copolymer, hardness evolution is an exothermic process.

  3. Hardness Evolution of Gamma-Irradiated Polyoxymethylene

    NASA Astrophysics Data System (ADS)

    Hung, Chuan-Hao; Harmon, Julie P.; Lee, Sanboh

    2016-04-01

    This study focuses on analyzing hardness evolution in gamma-irradiated polyoxymethylene (POM) exposed to elevated temperatures after irradiation. Hardness increases with increasing annealing temperature and time, but decreases with increasing gamma ray dose. Hardness changes are attributed to defects generated in the microstructure and molecular structure. Gamma irradiation causes a decrease in the glass transition temperature, melting point, and extent of crystallinity. The kinetics of defects resulting in hardness changes follow a first-order structure relaxation. The rate constant adheres to an Arrhenius equation, and the corresponding activation energy decreases with increasing dose due to chain scission during gamma irradiation. The structure relaxation of POM has a lower energy barrier in crystalline regions than in amorphous ones. The hardness evolution in POM is an endothermic process due to the semi-crystalline nature of this polymer.

  4. Exclusive, Hard Diffraction in QCD

    NASA Astrophysics Data System (ADS)

    Freund, Andreas

    1999-03-01

    In the first chapter we give an introduction to hard diffractive scattering in QCD to introduce basic concepts and terminology. In the second chapter we make predictions for the evolution of skewed parton distributions in a proton in the LLA. We calculate the DGLAP-type evolution kernels in the LLA and solve the skewed GLAP evolution equations with a modified version of the CTEQ-package. In the third chapter, we discuss the algorithms used in the LO evolution program for skewed parton distributions in the DGLAP region, discuss the stability of the code and reproduce the LO diagonal evolution within less than 0.5% of the original CTEQ-code. In chapter 4, we show that factorization holds for the deeply virtual Compton scattering amplitude in QCD, up to power suppressed terms, to all orders in perturbation theory. In chapter 5, we demonstrate that perturbative QCD allows one to calculate the absolute cross section of diffractive, exclusive production of photons (DVCS) at large Q^2 at HERA, while the aligned jet model allows one to estimate the cross section for intermediate Q^2 ˜ 2 GeV^2. We find a significant DVCS counting rate for the current generation of experiments at HERA and a large azimuthal angle asymmetry for HERA kinematics. In the last chapter, we propose a new methodology of gaining shape fits to skewed parton distributions and, for the first time, to determine the ratio of the real to imaginary part of the DIS amplitude. We do this by using several recent fits to F_2(x,Q^2) to compute the asymmetry A for the combined DVCS and Bethe-Heitler cross section. In the appendix, we give an application of distributional methods as discussed abstractly in chapter 4.

  5. Effect of Substrates on Film Hardness Measurements of Nanometer Thick Amorphous Carbon Films

    NASA Astrophysics Data System (ADS)

    Akasaka, Hiroki; Ito, Hiroki; Nakano, Masayuki; Ohshio, Shigeo; Saitoh, Hidetoshi

    Amorphous carbon film (a-C:H) applications, such as hard disks, require films with nanometer thicknesses. In an indentation test, the obtained hardness values of these films are affected by substrates. On the indentation tests, we studied the effect of substrate hardness on films less than 200 nm in thickness. a-C:H and Si doped a-C:H (a-C:Si:H) films were deposited by electron cyclotron resonance plasma chemical vapor deposition onto aluminum (Al) and silicon (Si) substrates. The film thicknesses were approximately 140 nm. The hardnesses of the a-C:H film and substrates were obtained using a high-resolution indentation tester (pico-dentor) with a Vickers tip whose depth resolution was 0.04 nm. Maximum indentation loads were varied from 0.01 to 0.5 mN. The Martens hardnesses of films on the Al and Si substrates were 600 and 7000 N/mm2, respectively. On the a-C:Si:H film deposited on the Al substrate, the hardnesses increased from 1600 to 3900 N/mm2 with decreasing indentation load. The hardnesses of the films deposited on the Si substrate decreased from 5300 to 3500 N/mm2 when the maximum indentation loads were reduced. The effect of the substrates increased with the maximum load increasing. From these findings, the actual hardness value was determined to be 3600 N/mm2. These results indicate that the high-resolution indentation test achieved hardness estimations for nanometer-thick films with certain hardnesses.

  6. Dentinogenesis imperfecta - hardness and Young's modulus of teeth.

    PubMed

    Wieczorek, Aneta; Loster, Jolanta; Ryniewicz, Wojciech; Ryniewicz, Anna M

    2013-01-01

    Dentinogenesis imperfecta type II (DI-II) is the most common dental genetic disease with reported incidence 1 in 8000. Elasticity and hardness of the enamel of teeth are important values which are connected with their resistance to attrition. It is hypothesized that values of physical properties for healthy teeth and teeth with DI-II are different. The aim of the study was to investigate some physical properties of teeth extracted from patients with DI-II in comparison with normal teeth. The material of the study was six teeth: three lower molars, with clinical signs of DI-II, which were extracted due to complications of pulp inflammation and three other lower molars which were extracted for orthodontic reasons - well formed, without any signs of pathology. The surfaces of DI-II and normal teeth were tested on the CSM Instruments Scratch Tester machine (producer CSEM Switzerland) by Oliver and Pharr method. The indenter used was Vicker's VG-73 diamond indenter. Additionally, the Scanning Electron Microscopy (SEM) analysis of the surface of the teeth with DI-II was made. Vickers hardness of the teeth with dental pathology (DI-II) was seven times smaller, and Young's modulus six times smaller than those of healthy teeth. The parameters of hardness and elasticity of enamel of teeth with clinical diagnosis of DI-II were very much smaller than in normal teeth and because of that can be responsible for attrition.

  7. [Determination of Hard Rate of Alfalfa (Medicago sativa L.) Seeds with Near Infrared Spectroscopy].

    PubMed

    Wang, Xin-xun; Chen, Ling-ling; Zhang, Yun-wei; Mao, Pei-sheng

    2016-03-01

    Alfalfa (Medicago sativa L.) is the most commonly grown forage crop due to its better quality characteristics and high adaptability in China. However, there was 20%-80% hard seeds in alfalfa which could not be identified easily from non hard seeds which would cause the loss of seed utilization value and plant production. This experiment was designed for 121 samples of alfalfa. Seeds were collected according to different regions, harvested year and varieties. 31 samples were artificial matched as hard rates ranging from 20% to 80% to establish a model for hard seed rate by near infrared spectroscopy (NIRS) with Partial Least Square (PLS). The objective of this study was to establish a model and to estimate the efficiency of NIRS for determining hard rate of alfalfa seeds. The results showed that the correlation coefficient (R2(cal)) of calibration model was 0.981 6, root mean square error of cross validation (RMSECV) was 5.32, and the ratio of prediction to deviation (RPD) was 3.58. The forecast model in this experiment presented the satisfied precision. The proposed method using NIRS technology is feasible for identification and classification of hard seed in alfalfa. A new method, as nondestructive testing of hard seed rate, was provided to theoretical basis for fast nondestructive detection of hard seed rates in alfalfa. PMID:27400509

  8. [Determination of Hard Rate of Alfalfa (Medicago sativa L.) Seeds with Near Infrared Spectroscopy].

    PubMed

    Wang, Xin-xun; Chen, Ling-ling; Zhang, Yun-wei; Mao, Pei-sheng

    2016-03-01

    Alfalfa (Medicago sativa L.) is the most commonly grown forage crop due to its better quality characteristics and high adaptability in China. However, there was 20%-80% hard seeds in alfalfa which could not be identified easily from non hard seeds which would cause the loss of seed utilization value and plant production. This experiment was designed for 121 samples of alfalfa. Seeds were collected according to different regions, harvested year and varieties. 31 samples were artificial matched as hard rates ranging from 20% to 80% to establish a model for hard seed rate by near infrared spectroscopy (NIRS) with Partial Least Square (PLS). The objective of this study was to establish a model and to estimate the efficiency of NIRS for determining hard rate of alfalfa seeds. The results showed that the correlation coefficient (R2(cal)) of calibration model was 0.981 6, root mean square error of cross validation (RMSECV) was 5.32, and the ratio of prediction to deviation (RPD) was 3.58. The forecast model in this experiment presented the satisfied precision. The proposed method using NIRS technology is feasible for identification and classification of hard seed in alfalfa. A new method, as nondestructive testing of hard seed rate, was provided to theoretical basis for fast nondestructive detection of hard seed rates in alfalfa.

  9. Value of Fundamental Science

    NASA Astrophysics Data System (ADS)

    Burov, Alexey

    Fundamental science is a hard, long-term human adventure that has required high devotion and social support, especially significant in our epoch of Mega-science. The measure of this devotion and this support expresses the real value of the fundamental science in public opinion. Why does fundamental science have value? What determines its strength and what endangers it? The dominant answer is that the value of science arises out of curiosity and is supported by the technological progress. Is this really a good, astute answer? When trying to attract public support, we talk about the ``mystery of the universe''. Why do these words sound so attractive? What is implied by and what is incompatible with them? More than two centuries ago, Immanuel Kant asserted an inseparable entanglement between ethics and metaphysics. Thus, we may ask: which metaphysics supports the value of scientific cognition, and which does not? Should we continue to neglect the dependence of value of pure science on metaphysics? If not, how can this issue be addressed in the public outreach? Is the public alienated by one or another message coming from the face of science? What does it mean to be politically correct in this sort of discussion?

  10. Monolayers of hard rods on planar substrates. I. Equilibrium.

    PubMed

    Oettel, M; Klopotek, M; Dixit, M; Empting, E; Schilling, T; Hansen-Goos, H

    2016-08-21

    The equilibrium properties of hard rod monolayers are investigated in a lattice model (where position and orientation of a rod are restricted to discrete values) as well as in an off-lattice model featuring spherocylinders with continuous positional and orientational degrees of freedom. Both models are treated using density functional theory and Monte Carlo simulations. Upon increasing the density of rods in the monolayer, there is a continuous ordering of the rods along the monolayer normal ("standing up" transition). The continuous transition also persists in the case of an external potential which favors flat-lying rods in the monolayer. This behavior is found in both the lattice and the continuum models. For the lattice model, we find very good agreement between the results from the specific DFT used (lattice fundamental measure theory) and simulations. The properties of lattice fundamental measure theory are further illustrated by the phase diagrams of bulk hard rods in two and three dimensions. PMID:27544121

  11. Submicron cubic boron nitride as hard as diamond

    SciTech Connect

    Liu, Guoduan; Kou, Zili E-mail: yanxz@hpstar.ac.cn; Lei, Li; Peng, Fang; Wang, Qiming; Wang, Kaixue; Wang, Pei; Li, Liang; Li, Yong; Wang, Yonghua; Yan, Xiaozhi E-mail: yanxz@hpstar.ac.cn; Li, Wentao; Bi, Yan; Leng, Yang; He, Duanwei

    2015-03-23

    Here, we report the sintering of aggregated submicron cubic boron nitride (sm-cBN) at a pressure of 8 GPa. The sintered cBN compacts exhibit hardness values comparable to that of single crystal diamond, fracture toughness about 5-fold that of cBN single crystal, in combination with a high oxidization temperature. Thus, another way has been demonstrated to improve the mechanical properties of cBN besides reducing the grain size to nano scale. In contrast to other ultrahard compacts with similar hardness, the sm-cBN aggregates are better placed for potential industrial application, as their relative low pressure manufacturing perhaps be easier and cheaper.

  12. Radial distribution function for hard spheres in fractal dimensions: A heuristic approximation

    NASA Astrophysics Data System (ADS)

    Santos, Andrés; de Haro, Mariano López

    2016-06-01

    Analytic approximations for the radial distribution function, the structure factor, and the equation of state of hard-core fluids in fractal dimension d (1 ≤d ≤3 ) are developed as heuristic interpolations from the knowledge of the exact and Percus-Yevick results for the hard-rod and hard-sphere fluids, respectively. In order to assess their value, such approximate results are compared with those of recent Monte Carlo simulations and numerical solutions of the Percus-Yevick equation for a fractal dimension [M. Heinen et al., Phys. Rev. Lett. 115, 097801 (2015), 10.1103/PhysRevLett.115.097801], a good agreement being observed.

  13. Take a Long, Hard Look

    ERIC Educational Resources Information Center

    Mackney, Paul

    2008-01-01

    The mooted development of a set of core British values demands a thorough re-examination of what it means to be British. The author argues that British people need to look at Britishness a bit more as others see them. For many the experience of Britishness was brutishness and it is still seen that way in the Middle East and not just by those in…

  14. Monte Carlo computer simulation of sedimentation of charged hard spherocylinders

    SciTech Connect

    Viveros-Méndez, P. X. Aranda-Espinoza, S.

    2014-07-28

    In this article we present a NVT Monte Carlo computer simulation study of sedimentation of an electroneutral mixture of oppositely charged hard spherocylinders (CHSC) with aspect ratio L/σ = 5, where L and σ are the length and diameter of the cylinder and hemispherical caps, respectively, for each particle. This system is an extension of the restricted primitive model for spherical particles, where L/σ = 0, and it is assumed that the ions are immersed in an structureless solvent, i.e., a continuum with dielectric constant D. The system consisted of N = 2000 particles and the Wolf method was implemented to handle the coulombic interactions of the inhomogeneous system. Results are presented for different values of the strength ratio between the gravitational and electrostatic interactions, Γ = (mgσ)/(e{sup 2}/Dσ), where m is the mass per particle, e is the electron's charge and g is the gravitational acceleration value. A semi-infinite simulation cell was used with dimensions L{sub x} ≈ L{sub y} and L{sub z} = 5L{sub x}, where L{sub x}, L{sub y}, and L{sub z} are the box dimensions in Cartesian coordinates, and the gravitational force acts along the z-direction. Sedimentation effects were studied by looking at every layer formed by the CHSC along the gravitational field. By increasing Γ, particles tend to get more packed at each layer and to arrange in local domains with an orientational ordering along two perpendicular axis, a feature not observed in the uncharged system with the same hard-body geometry. This type of arrangement, known as tetratic phase, has been observed in two-dimensional systems of hard-rectangles and rounded hard-squares. In this way, the coupling of gravitational and electric interactions in the CHSC system induces the arrangement of particles in layers, with the formation of quasi-two dimensional tetratic phases near the surface.

  15. Analysis of Hard Thin Film Coating

    NASA Technical Reports Server (NTRS)

    Shen, Dashen

    1998-01-01

    MSFC is interested in developing hard thin film coating for bearings. The wearing of the bearing is an important problem for space flight engine. Hard thin film coating can drastically improve the surface of the bearing and improve the wear-endurance of the bearing. However, many fundamental problems in surface physics, plasma deposition, etc, need further research. The approach is using electron cyclotron resonance chemical vapor deposition (ECRCVD) to deposit hard thin film an stainless steel bearing. The thin films in consideration include SiC, SiN and other materials. An ECRCVD deposition system is being assembled at MSFC.

  16. Analysis of Hard Thin Film Coating

    NASA Technical Reports Server (NTRS)

    Shen, Dashen

    1998-01-01

    Marshall Space Flight Center (MSFC) is interested in developing hard thin film coating for bearings. The wearing of the bearing is an important problem for space flight engine. Hard thin film coating can drastically improve the surface of the bearing and improve the wear-endurance of the bearing. However, many fundamental problems in surface physics, plasma deposition, etc, need further research. The approach is using Electron Cyclotron Resonance Chemical Vapor Deposition (ECRCVD) to deposit hard thin film on stainless steel bearing. The thin films in consideration include SiC, SiN and other materials. An ECRCVD deposition system is being assembled at MSFC.

  17. Differential cross-sections with hard targets

    NASA Astrophysics Data System (ADS)

    Brun, J. L.; Pacheco, A. F.

    2005-09-01

    When the concept of scattering differential cross-section is introduced in classical mechanics textbooks, usually it is first supposed that the target is a fixed, hard sphere. In this paper we calculate the scattering differential cross-section in the case of the hard target being a fixed figure of revolution of any shape. When the target is a paraboloid of revolution, we find the well-known formula corresponding to Rutherford's scattering. In addition, we analyse the inverse problem, i.e. given a differential cross-section, what is the profile of the corresponding hard target?

  18. [Methods for evaluation of penile erection hardness].

    PubMed

    Yuan, Yi-Ming; Zhou, Su; Zhang, Kai

    2010-07-01

    Penile erection hardness is one of the key factors for successful sexual intercourse, as well as an important index in the diagnosis and treatment of erectile dysfunction (ED). This article gives an overview on the component and impact factors of erection hardness, summarizes some commonly used evaluation methods, including those for objective indexes, such as Rigiscan, axial buckling test and color Doppler ultrasonography, and those for subjective indexes of ED patients, such as IIEF, the Erectile Function Domain of IIEF (IIEF-EF), and Erection Hardness Score (EHS), and discusses the characteristics of these methods.

  19. Influence of design variables on radiation hardness of silicon MINP solar cells

    NASA Technical Reports Server (NTRS)

    Anderson, W. A.; Solaun, S.; Rao, B. B.; Banerjee, S.

    1985-01-01

    Metal-insulator-N/P silicon (MINP) solar cells were fabricated using different substrate resistivity values, different N-layer designs, and different I-layer designs. A shallow junction into an 0.3 ohm-cm substrate gave best efficiency whereas a deeper junction into a 1 to 4 ohm-cm substrate gave improved radiation hardness. I-layer design variation did little to influence radiation hardness.

  20. Estimate of snow density knowing grain and share hardness

    NASA Astrophysics Data System (ADS)

    Valt, Mauro; Cianfarra, Paola; Cagnati, Anselmo; Chiambretti, Igor; Moro, Daniele

    2010-05-01

    Alpine avalanche warning services produces, weekly, snow profiles. Usually such profiles are made in horizontal snow fields, homogenously distributed by altitude and climatic micro-areas. Such profile allows grain shape, dimension and hardness (hand test) identification. Horizontal coring of each layer allows snow density identification. Such data allows the avalanche hazard evaluation and an estimation of the Snow Water Equivalent (SWE). Nevertheless the measurement of snow density, by coring, of very thin layers (less than 5 cm of thickness) is very difficult and are usually not measured by snow technicians. To bypass such problems a statistical analysis was performed to assign density values also to layers which cannot be measured. This system allows, knowing each layer thickness and its density, to correctly estimate SWE. This paper presents typical snow density values for snow hardness values and grain types for the Eastern Italian Alps. The study is based onto 2500 snow profiles with 17000 sampled snow layers from the Dolomites and Venetian Prealps (Eastern Alps). The table of typical snow density values for each grain type is used by YETI Software which elaborate snow profiles and automatically evaluate SWE. This method allows a better use of Avalanche Warning Services datasets for SWE estimation and local evaluation of SWE yearly trends for each snow field.

  1. Wear and hardness of different core build-up materials.

    PubMed

    Schmage, Petra; Nergiz, Ibrahim; Sito, Fekry; Platzer, Ursula; Rosentritt, Martin

    2009-10-01

    Before crown preparation, teeth with extensive coronal destructions are built up with core materials. Sometimes, these build ups are exposed to the oral environment without the protection of crowns. Therefore, this in vitro investigation was aimed at evaluating the wear, surface roughness, Vickers hardness, and surface structure of 10 core composites, two glass ionomer cements (GICs), and four posterior restoration composites. The three-body wear was tested after water storage and 2,00,000 cycles. We measured both surface roughness and Vickers hardness (DIN 50133) and evaluated the surface structures by scanning electron microscopy. Results were statistically analyzed by use of the Mann-Whitney U test (alpha = 0.05). Lowest wear was found for the restorative composites (20 microm Grandio; others about 40 microm). A comparison of the composites Build-It, Chroma Core, Rebilda LC, and Rebilda DC to Quixfil showed similar wear values for each material (43-50 microm). Wear values of GICs and all others core composites ranged between 58 and 75 microm. Only Ti-Core showed significantly higher wear than all other materials (p < 0.05). All core materials except Ti-Core (35 HV) showed Vickers hardness values between 42 and 61 HV. Most core composites, particularly Build-It, Multicore Flow, Rebilda LC, Ecusit, and Tetric Evo Ceram, showed more homogenous surface structures compared to GICs and restorative composites. Therefore, wear values of core build-up materials not only differed widely but were higher than those of conventional restorative materials; yet, core build-up materials showed advantageous surface structures.

  2. Value Added?

    ERIC Educational Resources Information Center

    UCLA IDEA, 2012

    2012-01-01

    Value added measures (VAM) uses changes in student test scores to determine how much "value" an individual teacher has "added" to student growth during the school year. Some policymakers, school districts, and educational advocates have applauded VAM as a straightforward measure of teacher effectiveness: the better a teacher, the better students…

  3. Effect of gamma radiation on micromechanical hardness of lead-free solder joint

    SciTech Connect

    Paulus, Wilfred; Rahman, Irman Abdul; Jalar, Azman; Kamil, Insan; Bakar, Maria Abu; Yusoff, Wan Yusmawati Wan

    2015-09-25

    Lead-free solders are important material in nano and microelectronic surface mounting technology for various applications in bio medicine, environmental monitoring, spacecraft and satellite instrumentation. Nevertheless solder joint in radiation environment needs higher reliability and resistance to any damage caused by ionizing radiations. In this study a lead-free 99.0Sn0.3Ag0.7Cu wt.% (SAC) solder joint was developed and subjected to various doses of gamma radiation to investigate the effects of the ionizing radiation to micromechanical hardness of the solder. Averaged hardness of the SAC joint was obtained from nanoindentation test. The results show a relationship between hardness values of indentations and the increment of radiation dose. Highest mean hardness, 0.2290 ± 0.0270 GPa was calculated on solder joint which was exposed to 5 Gray dose of gamma radiation. This value indicates possible radiation hardening effect on irradiated solder. The hardness gradually decreased to 0.1933 ± 0.0210 GPa and 0.1631 ± 0.0173 GPa when exposed to doses 50 and 500 gray respectively. These values are also lower than the hardness of non irradiated sample which was calculated as 0.2084 ± 0.0.3633 GPa indicating possible radiation damage and needs further related atomic dislocation study.

  4. Hard evidence on soft skills.

    PubMed

    Heckman, James J; Kautz, Tim

    2012-08-01

    This paper summarizes recent evidence on what achievement tests measure; how achievement tests relate to other measures of "cognitive ability" like IQ and grades; the important skills that achievement tests miss or mismeasure, and how much these skills matter in life. Achievement tests miss, or perhaps more accurately, do not adequately capture, soft skills-personality traits, goals, motivations, and preferences that are valued in the labor market, in school, and in many other domains. The larger message of this paper is that soft skills predict success in life, that they causally produce that success, and that programs that enhance soft skills have an important place in an effective portfolio of public policies.

  5. RAD hard PROM design study

    NASA Technical Reports Server (NTRS)

    1981-01-01

    The results of a preliminary study on the design of a radiation hardened fusible link programmable read-only memory (PROM) are presented. Various fuse technologies and the effects of radiation on MOS integrated circuits are surveyed. A set of design rules allowing the fabrication of a radiation hardened PROM using a Si-gate CMOS process is defined. A preliminary cell layout was completed and the programming concept defined. A block diagram is used to describe the circuit components required for a 4 K design. A design goal data sheet giving target values for the AC, DC, and radiation parameters of the circuit is presented.

  6. Automated radiation hard ASIC design tool

    NASA Technical Reports Server (NTRS)

    White, Mike; Bartholet, Bill; Baze, Mark

    1993-01-01

    A commercial based, foundry independent, compiler design tool (ChipCrafter) with custom radiation hardened library cells is described. A unique analysis approach allows low hardness risk for Application Specific IC's (ASIC's). Accomplishments, radiation test results, and applications are described.

  7. Financial Incentives for Staffing Hard Places.

    ERIC Educational Resources Information Center

    Prince, Cynthia D.

    2002-01-01

    Describes examples of financial incentives used to recruit teachers for low-achieving and hard-to-staff schools. Includes targeted salary increases, housing incentives, tuition assistance, and tax credits. (PKP)

  8. Electronic Teaching: Hard Disks and Networks.

    ERIC Educational Resources Information Center

    Howe, Samuel F.

    1984-01-01

    Describes floppy-disk and hard-disk based networks, electronic systems linking microcomputers together for the purpose of sharing peripheral devices, and presents points to remember when shopping for a network. (MBR)

  9. Density functional theory for hard polyhedra.

    PubMed

    Marechal, Matthieu; Löwen, Hartmut

    2013-03-29

    Using the framework of geometry-based fundamental-measure theory, we develop a classical density functional for hard polyhedra and their mixtures and apply it to inhomogeneous fluids of Platonic solids near a hard wall. As revealed by Monte Carlo simulations, the faceted shape of the polyhedra leads to complex layering and orientational ordering near the wall, which is excellently reproduced by our theory. These effects can be verified in real-space experiments on polyhedral colloids.

  10. Breakdown of QCD factorization in hard diffraction

    NASA Astrophysics Data System (ADS)

    Kopeliovich, B. Z.

    2016-07-01

    Factorization of short- and long-distance interactions is severely broken in hard diffractive hadronic collisions. Interaction with the spectator partons leads to an interplay between soft and hard scales, which results in a leading twist behavior of the cross section, on the contrary to the higher twist predicted by factorization. This feature is explicitly demonstrated for diffractive radiation of abelian (Drell-Yan, gauge bosons, Higgs) and non-abelian (heavy flavors) particles.

  11. A Novel Approach to Hardness Testing

    NASA Technical Reports Server (NTRS)

    Spiegel, F. Xavier; West, Harvey A.

    1996-01-01

    This paper gives a description of the application of a simple rebound time measuring device and relates the determination of relative hardness of a variety of common engineering metals. A relation between rebound time and hardness will be sought. The effect of geometry and surface condition will also be discussed in order to acquaint the student with the problems associated with this type of method.

  12. Laser Ablatin of Dental Hard Tissue

    SciTech Connect

    Seka, W.; Rechmann, P.; Featherstone, J.D.B.; Fried, D.

    2007-07-31

    This paper discusses ablation of dental hard tissue using pulsed lasers. It focuses particularly on the relevant tissue and laser parameters and some of the basic ablation processes that are likely to occur. The importance of interstitial water and its phase transitions is discussed in some detail along with the ablation processes that may or may not directly involve water. The interplay between tissue parameters and laser parameters in the outcome of the removal of dental hard tissue is discussed in detail.

  13. Hard evidence on soft skills✩

    PubMed Central

    Heckman, James J.; Kautz, Tim

    2012-01-01

    This paper summarizes recent evidence on what achievement tests measure; how achievement tests relate to other measures of “cognitive ability” like IQ and grades; the important skills that achievement tests miss or mismeasure, and how much these skills matter in life. Achievement tests miss, or perhaps more accurately, do not adequately capture, soft skills—personality traits, goals, motivations, and preferences that are valued in the labor market, in school, and in many other domains. The larger message of this paper is that soft skills predict success in life, that they causally produce that success, and that programs that enhance soft skills have an important place in an effective portfolio of public policies. PMID:23559694

  14. Hard evidence on soft skills.

    PubMed

    Heckman, James J; Kautz, Tim

    2012-08-01

    This paper summarizes recent evidence on what achievement tests measure; how achievement tests relate to other measures of "cognitive ability" like IQ and grades; the important skills that achievement tests miss or mismeasure, and how much these skills matter in life. Achievement tests miss, or perhaps more accurately, do not adequately capture, soft skills-personality traits, goals, motivations, and preferences that are valued in the labor market, in school, and in many other domains. The larger message of this paper is that soft skills predict success in life, that they causally produce that success, and that programs that enhance soft skills have an important place in an effective portfolio of public policies. PMID:23559694

  15. Evaluating the role of ion composition on the toxicity of copper to Ceriodaphnia dubia in very hard waters.

    PubMed

    Gensemer, Robert W; Naddy, Rami B; Stubblefield, William A; Hockett, J Russell; Santore, Robert; Paquin, Paul

    2002-09-01

    The mitigating effect of increasing hardness on metal toxicity is reflected in water quality criteria in the United States over the range of 25-400 mgl(-1) (as CaCO(3)). However, waters in the arid west of the US frequently exceed 400 mgl(-1) hardness, and the applicability of hardness-toxicity relationships in these waters is unknown. Acute toxicity tests with Ceriodaphnia dubia were conducted at hardness levels ranging from approximately 300 to 1,200 mgl(-1) using reconstituted waters that mimic two natural waters with elevated hardness: (1) alkaline desert southwest streams (Las Vegas Wash, NV), and (2) low alkalinity waters from a CaSO(4)-treated mining effluent in Colorado. The moderately-alkaline EPA synthetic hard water was also included for comparison. Copper toxicity did not consistently vary as a function of hardness, but likely as a function of other water quality characteristics (e.g., alkalinity or other correlated factors). The hardness equations used in regulatory criteria, therefore, may not provide an accurate level of protection against copper toxicity in all types of very hard waters. However, the mechanistic Biotic ligand model generally predicted copper toxicity within +/-2X of observed EC(50) values, and thus may be more useful than hardness for modifying water quality criteria.

  16. Hard Gamma Ray Emission from the Starburst Galaxy NGC 253

    NASA Technical Reports Server (NTRS)

    Jackson, James M.; Marscher, Alan M.

    1996-01-01

    We have completed the study to search for hard gamma ray emission from the starburst galaxy NGC 253. Since supernovae are thought to provide the hard gamma ray emission from the Milky Way, starburst galaxies, with their extraordinarily high supernova rates, are prime targets to search for hard gamma ray emission. We conducted a careful search for hard gamma ray emission from NGC 253 using the archival data from the EGRET experiment aboard the CGRO. Because this starburst galaxy happens to lie near the South Galactic Pole, the Galactic gamma ray background is minimal. We found no significant hard gamma ray signal toward NGC 253, although a marginal signal of about 1.5 sigma was found. Because of the low Galactic background, we obtained a very sensitive upper limit to the emission of greater than 100 MeV gamma-rays of 8 x 10(exp -8) photons/sq cm s. Since we expected to detect hard gamma ray emission, we investigated the theory of gamma ray production in a dense molecular medium. We used a leaky-box model to simulate diffusive transport in a starburst region. Since starburst galaxies have high infrared radiation fields, we included the effects of self-Compton scattering, which are usually ignored. By modelling the expected gamma-ray and synchrotron spectra from NGC 253, we find that roughly 5 - 15% of the energy from supernovae is transferred to cosmic rays in the starburst. This result is consistent with supernova acceleration models, and is somewhat larger than the value derived for the Galaxy (3 - 10%). Our calculations match the EGRET and radio data very well with a supernova rate of 0.08/ yr, a magnetic field B approx. greater than 5 x 10(exp -5) G, a density n approx. less than 100/sq cm, a photon density U(sub ph) approx. 200 eV/sq cm, and an escape time scale tau(sub 0) approx. less than 10 Myr. The models also suggest that NGC 253 should be detectable with only a factor of 2 - 3 improvement in sensitivity. Our results are consistent with the standard picture

  17. Microindentation in bone: hardness variation with five independent variables.

    PubMed

    Johnson, Wesley M; Rapoff, Andrew J

    2007-04-01

    Microindentation is an investigational tool often used to determine hardness and other derived material properties of the material bone. This study explored the variation of microindentation hardness results with five independent variables. The variables were: applied mass, dwell time, drying time, time between indentation and measurement, and distance between the center of an indentation and the edge of other indentations and pores. These variables were selected because they represented a reasonable range of specimen investigational steps. We also investigated the cross sections of typical indentation residual impressions to determine the degree of material pile-up at the edges of the impressions. We found that microindentation hardness varied with applied mass and with distance between the indentation and neighboring indentations and pores but not with the other variables. Our recommended minimum applied mass is 0.10 kg versus a previously published value of 0.05 kg. We also found no discernable material pile-up at the residual impression edges, in contrast to reports of others.

  18. Hard and Soft Constraints in Reliability-Based Design Optimization

    NASA Technical Reports Server (NTRS)

    Crespo, L.uis G.; Giesy, Daniel P.; Kenny, Sean P.

    2006-01-01

    This paper proposes a framework for the analysis and design optimization of models subject to parametric uncertainty where design requirements in the form of inequality constraints are present. Emphasis is given to uncertainty models prescribed by norm bounded perturbations from a nominal parameter value and by sets of componentwise bounded uncertain variables. These models, which often arise in engineering problems, allow for a sharp mathematical manipulation. Constraints can be implemented in the hard sense, i.e., constraints must be satisfied for all parameter realizations in the uncertainty model, and in the soft sense, i.e., constraints can be violated by some realizations of the uncertain parameter. In regard to hard constraints, this methodology allows (i) to determine if a hard constraint can be satisfied for a given uncertainty model and constraint structure, (ii) to generate conclusive, formally verifiable reliability assessments that allow for unprejudiced comparisons of competing design alternatives and (iii) to identify the critical combination of uncertain parameters leading to constraint violations. In regard to soft constraints, the methodology allows the designer (i) to use probabilistic uncertainty models, (ii) to calculate upper bounds to the probability of constraint violation, and (iii) to efficiently estimate failure probabilities via a hybrid method. This method integrates the upper bounds, for which closed form expressions are derived, along with conditional sampling. In addition, an l(sub infinity) formulation for the efficient manipulation of hyper-rectangular sets is also proposed.

  19. Effects of Organogel Hardness and Formulation on Acceptance of Frankfurters.

    PubMed

    Barbut, S; Wood, J; Marangoni, A G

    2016-09-01

    Different organogel formulations used as beef fat (BF) replacement (0%, 20%, 40%, 60%, and 80%) were utilized to optimize the mechanical properties of frankfurters. Organogels, made of canola oil (CO), included different concentrations of ethyl cellulose (EC) and sorbitan monostearate (SMS). They consisted of: 8% EC + 1.5% SMS referred to as organogel-I (OG-I), 8% EC + 3.0% SMS (OG-II), and 10% EC + 1.5% SMS (OG-III), which were found promising in a previous study when used at 100% replacement. Replacement of BF with organogels at all levels could bring down the very high hardness values (texture profile analysis and sensory) of frankfurters prepared using CO by itself, relative to the BF control. OG-I and OG-II quantity had no significant effect on hardness and springiness, being similar in many cases to the BF and lower than the CO control. Shear force values of all organogel treatments were not significantly different from one another, and were between the BF and CO controls. Smokehouse yield showed a pattern of decreasing losses with increasing organogel replacement level. Sensory analysis revealed that using CO by itself significantly increased hardness, but structuring the oil (via organogelation), brought it down to the BF control value in all OG-I and OG-II formulations. Juiciness was significantly reduced by using liquid oil but increased with raising the amount of organogels. Oiliness sensation increased with higher organogel substitution and was actually higher than the beef control. The study demonstrates the potential use of vegetable oil structuring in replacing the more saturated BF in emulsion-type meat products. PMID:27514694

  20. Classical growth of hard-sphere colloidal crystals

    NASA Astrophysics Data System (ADS)

    Ackerson, Bruce J.; Schätzel, Klaus

    1995-12-01

    The classical theory of nucleation and growth of crystals is examined for concentrated suspensions of hard-sphere colloidal particles. The work of Russel is modified, extended, and evaluated, explicitly. Specifically, the Wilson-Frenkel growth law is modified to include the Gibbs-Thomson effect and is evaluated numerically. The results demonstrate that there is a critical nucleus radius below which crystal nuclei will not grow. A kinetic coefficient determines the maximum growth velocity possible. For large values of this coefficient, quenches to densities above the melting density show interface limited growth with the crystal radius increasing linearly with time. For quenches into the coexistence region the growth is diffusion limited, with the crystal radius increasing as the square root of elapsed time. Smaller values of the kinetic coefficient produce long lived transients which evidence quasi-power-law growth behavior with exponents between one half and unity. The smaller kinetic coefficients also lead to larger crystal compression. Crystal compression and nonclassical exponents have been observed in recent experiments. The theory is compared to data from small angle scattering studies of nucleation and growth in suspensions of hard colloidal spheres. The experimental nucleation rate is much larger than the theoretically predicted value as the freezing point is approached but shows better agreement near the melting point. The crystal growth with time is described reasonably well by the theory and suggests that the experiments are observing long lived transient rather than asymptotic growth behavior. (c) 1995 The American Physical Society

  1. Developing and Studying the Methods of Hard-Facing with Heat-Resisting High-Hardness Steels

    NASA Astrophysics Data System (ADS)

    Malushin, N. N.; Kovalev, A. P.; Valuev, D. V.; Shats, E. A.; Borovikov, I. F.

    2016-08-01

    The authors develop the methods of hard-facing of mining-metallurgic equipment parts with heat-resisting high-hardness steels on the base of plasma-jet hard-facing in the shielding-alloying nitrogen atmosphere.

  2. Modeling of the flow stress for AISI H13 Tool Steel during Hard Machining Processes

    NASA Astrophysics Data System (ADS)

    Umbrello, Domenico; Rizzuti, Stefania; Outeiro, José C.; Shivpuri, Rajiv

    2007-04-01

    In general, the flow stress models used in computer simulation of machining processes are a function of effective strain, effective strain rate and temperature developed during the cutting process. However, these models do not adequately describe the material behavior in hard machining, where a range of material hardness between 45 and 60 HRC are used. Thus, depending on the specific material hardness different material models must be used in modeling the cutting process. This paper describes the development of a hardness-based flow stress and fracture models for the AISI H13 tool steel, which can be applied for range of material hardness mentioned above. These models were implemented in a non-isothermal viscoplastic numerical model to simulate the machining process for AISI H13 with various hardness values and applying different cutting regime parameters. Predicted results are validated by comparing them with experimental results found in the literature. They are found to predict reasonably well the cutting forces as well as the change in chip morphology from continuous to segmented chip as the material hardness change.

  3. Communication: radial distribution functions in a two-dimensional binary colloidal hard sphere system.

    PubMed

    Thorneywork, Alice L; Roth, Roland; Aarts, Dirk G A L; Dullens, Roel P A

    2014-04-28

    Two-dimensional hard disks are a fundamentally important many-body model system in classical statistical mechanics. Despite their significance, a comprehensive experimental data set for two-dimensional single component and binary hard disks is lacking. Here, we present a direct comparison between the full set of radial distribution functions and the contact values of a two-dimensional binary colloidal hard sphere model system and those calculated using fundamental measure theory. We find excellent quantitative agreement between our experimental data and theoretical predictions for both single component and binary hard disk systems. Our results provide a unique and fully quantitative mapping between experiments and theory, which is crucial in establishing the fundamental link between structure and dynamics in simple liquids and glass forming systems. PMID:24784245

  4. Value Added

    ERIC Educational Resources Information Center

    Wilson, M. Roy

    2015-01-01

    With more than a thousand honors programs or colleges in the United States and that number growing every year, defining the value of honors is a significant undertaking. Honors seems to have become an obligatory upgrade that no college or university president can afford to be without, but there is more than institutional trending to be considered,…

  5. Value Added

    ERIC Educational Resources Information Center

    Welch, Matt

    2004-01-01

    This article profiles retiring values teacher Gene Doxey and describes his foundational contributions to the students of California's Ramona Unified School District. Every one of the Ramona Unified School District's 7,200 students is eventually funneled through Doxey's Contemporary Issues class, a required rite of passage between elementary school…

  6. A study on hardness behavior of geopolymer paste in different condition

    NASA Astrophysics Data System (ADS)

    Zainal, Farah Farhana; Hussin, Kamarudin; Rahmat, Azmi; Abdullah, Mohd Mustafa Al Bakri; Shamsudin, Shaiful Rizam

    2016-07-01

    This study has been conducted to understand the hardness behavior of geopolymer paste in different conditions; with and without being immersed in water. Geopolymer paste has been used nowadays as an alternative way to reduce global warming pollution by carbon dioxide (CO2) released to the air caused from the production of Ordinary Portland Cement (OPC). Geopolymer has many advantages such as high compressive strength, lower water absorption and lower porosity. Geopolymer paste in this study was made from a mixture of fly ash and alkaline activators. The alkaline activators that have been used were sodium hydroxide (NaOH) solution and sodium silicate (Na2SiO3) solution. Then the mixture was allowed to harden for 24hrs at ambient temperature and then placed in the oven for 24hrs with 60°C for the curing process. The hardness testing was conducted after a few months when the samples already achieved the optimum design. The samples were divided to two conditions; without immersion which was placed at ambient temperature (S1) and immersed in water for one week (S2). The samples then are divided into two at the center and testing was conducted into 4 parts which are part 1, part 2, part 3 and part 4. Various methods of non-destructively testing concrete and mortar have been in use for many years such as Vickers hardness test, Rockwell hardness test, Brinell hardness test and many more. The Rockwell hardness test method as defined in ASTM E-18 is the most commonly used hardness test method which is also used in this study. From the results, S1 has higher hardness value than S2 for all parts with the maximum value of S1 is 118.6 and the minimum value is 71.8. The maximum value of S2 is 114.4 and the minimum value is 0. The central part of the geopolymer paste also showed greater hardness values than the edge area of the samples.

  7. Research in the Hard Sciences, and in Very Hard "Softer" Domains

    ERIC Educational Resources Information Center

    Phillips, D. C.

    2014-01-01

    The author of this commentary argues that physical scientists are attempting to advance knowledge in the so-called hard sciences, whereas education researchers are laboring to increase knowledge and understanding in an "extremely hard" but softer domain. Drawing on the work of Popper and Dewey, this commentary highlights the relative…

  8. Hard Water and Soft Soap: Dependence of Soap Performance on Water Hardness

    ERIC Educational Resources Information Center

    Osorio, Viktoria K. L.; de Oliveira, Wanda; El Seoud, Omar A.; Cotton, Wyatt; Easdon, Jerry

    2005-01-01

    The demonstration of the performance of soap in different aqueous solutions, which is due to water hardness and soap formulation, is described. The demonstrations use safe, inexpensive reagents and simple glassware and equipment, introduce important everyday topics, stimulates the students to consider the wider consequences of water hardness and…

  9. Pion Form Factor in Chiral Limit of Hard-Wall AdS/QCD Model

    SciTech Connect

    Anatoly Radyushkin; Hovhannes Grigoryan

    2007-12-01

    We develop a formalism to calculate form factor and charge density distribution of pion in the chiral limit using the holographic dual model of QCD with hard-wall cutoff. We introduce two conjugate pion wave functions and present analytic expressions for these functions and for the pion form factor. They allow to relate such observables as the pion decay constant and the pion charge electric radius to the values of chiral condensate and hard-wall cutoff scale. The evolution of the pion form factor to large values of the momentum transfer is discussed, and results are compared to existing experimental data.

  10. Effects of Water Hardness on Textile Detergency Performance in Aqueous Cleaning Systems.

    PubMed

    Gotoh, Keiko; Horibe, Kaori; Mei, Yang; Tsujisaka, Toshiyuki

    2016-01-01

    The effects of water hardness on textile detergency in aqueous solutions were systematically investigated using four surfactants: sodium oleate (OLNa), linear dodecylbenzene sulfonate (LAS), sodium dodecyl sulfate (AS), and polyoxyethylene (10) dodecyl ether (AE). Water hardness was adjusted according to the standard procedure described in IEC 60734:2012. As expected, by adding hardness salts the surface tension of the OLNa solution increased. Surprisingly, the addition of hardness salts lowers the surface tension for the LAS and AS solutions. In the case of the AE solution, hardness salt did not affect the surface tension. A decrease in transmittance and foamability after adding hardness salts was observed for every anionic surfactant solution, indicating that anionic surfactants can combine with divalent ions to form insoluble precipitates. Detergency experiments were performed using cotton plain-woven and towel fabrics soiled with a carbon black and oleic acid mixture. One piece each of untreated and soiled fabric were stacked and placed horizontally in detergent solution with or without hardness salts. As a mechanical action of soil removal, the shaking of 190 spm was applied. Soil removal and redeposition due to washing were evaluated from changes in values of the Kubelka-Munk function for both fabrics. With increasing water hardness, soil removal decreased and redeposition increased. In order of decreasing detergency, the surfactants were as follows: LAS > OLNa ≈ AS > AE. The results indicate that precipitates, formed by reaction of LAS or AS with hardness salts, are strongly adsorbed on the water surface because of their hydrophobicity, but they have no detergency power. The field emission scanning electron microscopic observation and X-ray photoelectron spectroscopic analysis showed that Ca(LAS)2 precipitation clung to fiber surfaces, and remained on the surfaces after washing. Significant changes in the cotton fabric due to washing were observed in

  11. Effects of Water Hardness on Textile Detergency Performance in Aqueous Cleaning Systems.

    PubMed

    Gotoh, Keiko; Horibe, Kaori; Mei, Yang; Tsujisaka, Toshiyuki

    2016-01-01

    The effects of water hardness on textile detergency in aqueous solutions were systematically investigated using four surfactants: sodium oleate (OLNa), linear dodecylbenzene sulfonate (LAS), sodium dodecyl sulfate (AS), and polyoxyethylene (10) dodecyl ether (AE). Water hardness was adjusted according to the standard procedure described in IEC 60734:2012. As expected, by adding hardness salts the surface tension of the OLNa solution increased. Surprisingly, the addition of hardness salts lowers the surface tension for the LAS and AS solutions. In the case of the AE solution, hardness salt did not affect the surface tension. A decrease in transmittance and foamability after adding hardness salts was observed for every anionic surfactant solution, indicating that anionic surfactants can combine with divalent ions to form insoluble precipitates. Detergency experiments were performed using cotton plain-woven and towel fabrics soiled with a carbon black and oleic acid mixture. One piece each of untreated and soiled fabric were stacked and placed horizontally in detergent solution with or without hardness salts. As a mechanical action of soil removal, the shaking of 190 spm was applied. Soil removal and redeposition due to washing were evaluated from changes in values of the Kubelka-Munk function for both fabrics. With increasing water hardness, soil removal decreased and redeposition increased. In order of decreasing detergency, the surfactants were as follows: LAS > OLNa ≈ AS > AE. The results indicate that precipitates, formed by reaction of LAS or AS with hardness salts, are strongly adsorbed on the water surface because of their hydrophobicity, but they have no detergency power. The field emission scanning electron microscopic observation and X-ray photoelectron spectroscopic analysis showed that Ca(LAS)2 precipitation clung to fiber surfaces, and remained on the surfaces after washing. Significant changes in the cotton fabric due to washing were observed in

  12. Potential Health Impacts of Hard Water

    PubMed Central

    Sengupta, Pallav

    2013-01-01

    In the past five decades or so evidence has been accumulating about an environmental factor, which appears to be influencing mortality, in particular, cardiovascular mortality, and this is the hardness of the drinking water. In addition, several epidemiological investigations have demonstrated the relation between risk for cardiovascular disease, growth retardation, reproductive failure, and other health problems and hardness of drinking water or its content of magnesium and calcium. In addition, the acidity of the water influences the reabsorption of calcium and magnesium in the renal tubule. Not only, calcium and magnesium, but other constituents also affect different health aspects. Thus, the present review attempts to explore the health effects of hard water and its constituents. PMID:24049611

  13. Erosion testing of hard materials and coatings

    SciTech Connect

    Hawk, Jeffrey A.

    2005-04-29

    Erosion is the process by which unconstrained particles, usually hard, impact a surface, creating damage that leads to material removal and component failure. These particles are usually very small and entrained in fluid of some type, typically air. The damage that occurs as a result of erosion depends on the size of the particles, their physical characteristics, the velocity of the particle/fluid stream, and their angle of impact on the surface of interest. This talk will discuss the basics of jet erosion testing of hard materials, composites and coatings. The standard test methods will be discussed as well as alternative approaches to determining the erosion rate of materials. The damage that occurs will be characterized in genera1 terms, and examples will be presented for the erosion behavior of hard materials and coatings (both thick and thin).

  14. Potential health impacts of hard water.

    PubMed

    Sengupta, Pallav

    2013-08-01

    In the past five decades or so evidence has been accumulating about an environmental factor, which appears to be influencing mortality, in particular, cardiovascular mortality, and this is the hardness of the drinking water. In addition, several epidemiological investigations have demonstrated the relation between risk for cardiovascular disease, growth retardation, reproductive failure, and other health problems and hardness of drinking water or its content of magnesium and calcium. In addition, the acidity of the water influences the reabsorption of calcium and magnesium in the renal tubule. Not only, calcium and magnesium, but other constituents also affect different health aspects. Thus, the present review attempts to explore the health effects of hard water and its constituents.

  15. Equation of state for fluid mixtures of hard spheres and heteronuclear hard dumbbells

    NASA Astrophysics Data System (ADS)

    Barrio, C.; Solana, J. R.

    1999-09-01

    A theoretically founded equation of state is developed for mixtures of hard spheres with heteronuclear hard dumbbells. It is based on a model previously developed for hard-convex-body fluid mixtures, and further extended to fluid mixtures of homonuclear hard dumbbells. The equation scales the excess compressibility factor for an equivalent hard-sphere fluid mixture to obtain that corresponding to the true mixture. The equivalent mixture is one in which the averaged volume of a sphere is the same as the effective molecular volume of a molecule in the real mixture. Thus, the theory requires two parameters, namely the averaged effective molecular volume of the molecules in the mixture and the scaling factor, which is the effective nonsphericity parameter. Expressions to determine these parameters are derived in terms of the geometrical characteristics of the molecules that form the mixture. The overall results are in closer agreement with simulation data than those obtained with other theories developed for these kinds of mixtures.

  16. Novel Aspects of Hard Diffraction in QCD

    SciTech Connect

    Brodsky, Stanley J.; /SLAC

    2005-12-14

    Initial- and final-state interactions from gluon-exchange, normally neglected in the parton model have a profound effect in QCD hard-scattering reactions, leading to leading-twist single-spin asymmetries, diffractive deep inelastic scattering, diffractive hard hadronic reactions, and nuclear shadowing and antishadowing--leading-twist physics not incorporated in the light-front wavefunctions of the target computed in isolation. I also discuss the use of diffraction to materialize the Fock states of a hadronic projectile and test QCD color transparency.

  17. UV curable hard coatings on polyesters

    NASA Astrophysics Data System (ADS)

    Datashvili, Tea; Brostow, Witold; Kao, David

    2006-10-01

    UV curable, hard and transparent hybrid inorganic-organic coatings with covalent links between the inorganic and the organic networks were prepared using organically crosslinked heteropolysiloxanes based on the sol-gel process. The materials were applied onto polyester sheets and UV cured. The deposition was followed by a thermal treatment to improve mechanical properties of the coatings. High light transmission and the resulting thermophysical properties indicate the presence of a nanoscale hybrid composition. The coatings show excellent adhesion to polyesters even without using primers. Further mechanical characterization shows that the coatings provide high hardness and good abrasion resistance.

  18. Radiation-hard static induction transistor

    SciTech Connect

    Hanes, M.H.; Bartko, J.; Hwang, J.M.; Rai-Choudhury, P.; Leslie, S.G.

    1988-12-01

    The static induction transistor (SIT) has been proposed as a preferred power switching device for applications in military and space environments because of its potential for radiation hardness, high-frequency operation, and the incorporation of on-chip smart power sensor and logic functions. Design, fabrication, and characteristics of a 350 V, 100 A buried gate SIT are described. The potential radiation hardness of this class of devices was evaluated by measurement of SIT characteristics after irradiation with 100 Mrad electrons (2 MeV), and up to 10%16% fission neutrons/cm/sup 2/. High-temperature operation and the possibility of radiation damage self-annealing are discussed.

  19. [Necrotizing sialometaplasia of the hard palate].

    PubMed

    Topstad, T K; Olofsson, J; Myking, A

    1991-11-30

    Necrotizing sialometaplasia is a benign, self-healing disease of salivary gland tissue and is usually confined to the minor salivary glands of the hard palate. It has clinical and histological features that simulate malignancies such as mucoepidermoid and squamous cell carcinomas. Wrong diagnosis has led to unnecessary mutilating surgical procedures. The etiology of the disease is unknown, but an ischaemic process is considered most likely. We describe two patients with necrotizing sialometaplasia, one with midline and one with bilateral symmetrical affection of the hard palate.

  20. Evaluation of surface roughness and hardness of different glass ionomer cements

    PubMed Central

    Bala, Oya; Arisu, Hacer Deniz; Yikilgan, Ihsan; Arslan, Seda; Gullu, Abdulkadir

    2012-01-01

    Objectives: The aim of this study was to evaluate surface roughness and hardness of a nanofiller GIC, a resin-modified GIC, three conventional GICs, and a silver-reinforced GIC. Methods: For each material, 11 spcecimens were prepared and then stored in distilled water at 37 °C for 24 h. The surface roughness of 5 specimens was measured using a surface profilometer before polishing and after polishing with coarse, medium, fine, superfine aluminum oxide abrasive Sof-Lex discs respectively. The hardness of the upper surfaces of the remaining 6 specimens was measured with a Vickers microhardness measuring instrument. Results: All tested GICs showed lower surface roughness values after the polishing procedure. Surface finish of nanofiller GIC was smoother than the other tested GICs after polishing. This was followed by resin-modified GIC, Fuji II LC; then silver-reinforced GIC, Argion Molar, conventional GICs, Aqua Ionofil Plus, Fuji IX, and Ionofil Molar, respectively. The result of the hardness test indicated that the microhardness value of silver-reinforced GIC was greater than that of the other GICs. When the hardness values of all tested GICs were compared, the differences between materials (except Aqua Ionofil Plus with Ionofil Molar and Ketac N100 with Fuji II LC (P>.05)) were found statistically significant (P<.05). Conclusions: According to the results of this study, it can be concluded that the differences in the composition of GICs may affect their surface roughness and hardness. PMID:22229011

  1. Effect of sintering atmosphere on the hardness of ThO2

    NASA Astrophysics Data System (ADS)

    Baena, Angela; Cardinaels, Thomas; Van Eyken, Jelle; Puzzolante, Jean Louis; Binnemans, Koen; Verwerft, Marc

    2016-08-01

    The hardness and toughness of ThO2 sintered under reducing and oxidizing conditions has been investigated and, quite unexpectedly, a significant difference in hardness was observed for the entire range of porosities studied. Reducing conditions systematically yielded higher hardness values than oxidizing conditions. Extrapolated to zero porosity, the hardness for ThO2 is H0 = 10.5 ± 0.3 GPa for oxidizing conditions and H0 = 12.4 ± 0.7 GPa for reducing conditions. Toughness values have been derived from Vickers indentations; differences in toughness were insignificant and only a single value is proposed: KIC = 0.97 ± 0.12 MPa √m. The difference in hardness is attributed to the presence of point defects, also acting as color centers and causing grey coloration of ThO2 sintered under reducing conditions. Furthermore, and of interest for nuclear fuel production, is the finding that ThO2 sintered under reducing conditions is significantly easier to grind compared to material sintered under oxidizing conditions.

  2. Abrasivity Assessment of Granitic Building Stones in Relation to Diamond Tool Wear Rate Using Mineralogy-Based Rock Hardness Indexes

    NASA Astrophysics Data System (ADS)

    Yılmaz, Nurdan Güneş

    2011-11-01

    The objective of the present study was to determine the abrasive wear potential of granites in circular sawing using some mineralogy-based rock hardness indexes. A literature study indicated that little or no attention has been given to assessing this kind of relationship in the field of stone processing. To accomplish this objective, sawing experiments were performed on nine different granites used widely as building and decorative stone materials. The measured sawblade-specific wear rates were correlated with three different rock hardness indexes attained by combining the percentage content of hard mineral constituents with their known hardness values. Statistical analysis of the experimental data revealed that rock hardness indexes that are based on both Vickers hardness number and Rosiwal hardness could be accepted as reliable indicators of granite abrasivity. These two indexes were also found to correlate well with the average power drawn during the process. However, the rock abrasivity index based on Mohs relative scratch hardness did not show statistically significant correlations with sawblade wear rate and power drawn. Although quartz percentage content is regarded as an important abrasivity parameter by practitioners, the observations made here indicate that consideration of quartz percentage content alone is not sufficient to describe the abrasive potential of granites, and thus incorporation of other hard mineral constituents could be more suitable.

  3. Uniform shear flow in dissipative gases: Computer simulations of inelastic hard spheres and frictional elastic hard spheres

    NASA Astrophysics Data System (ADS)

    Astillero, Antonio; Santos, Andrés

    2005-09-01

    In the preceding paper, we have conjectured that the main transport properties of a dilute gas of inelastic hard spheres (IHSs) can be satisfactorily captured by an equivalent gas of elastic hard spheres (EHSs), provided that the latter are under the action of an effective drag force and their collision rate is reduced by a factor (1+α)/2 (where α is the constant coefficient of normal restitution). In this paper we test the above expectation in a paradigmatic nonequilibrium state, namely, the simple or uniform shear flow, by performing Monte Carlo computer simulations of the Boltzmann equation for both classes of dissipative gases with a dissipation range 0.5⩽α⩽0.95 and two values of the imposed shear rate a . It is observed that the evolution toward the steady state proceeds in two stages: a short kinetic stage (strongly dependent on the initial preparation of the system) followed by a slower hydrodynamic regime that becomes increasingly less dependent on the initial state. Once conveniently scaled, the intrinsic quantities in the hydrodynamic regime depend on time, at a given value of α , only through the reduced shear rate a*(t)∝a/T(t) , until a steady state, independent of the imposed shear rate and of the initial preparation, is reached. The distortion of the steady-state velocity distribution from the local equilibrium state is measured by the shear stress, the normal stress differences, the cooling rate, the fourth and sixth cumulants, and the shape of the distribution itself. In particular, the simulation results seem to be consistent with an exponential overpopulation of the high-velocity tail. These properties are common to both the IHS and EHS systems. In addition, the EHS results are in general hardly distinguishable from the IHS ones if α≳0.7 , so that the distinct signature of the IHS gas (higher anisotropy and overpopulation) only manifests itself at relatively high dissipations.

  4. Ototraumatic effects of hard rock music.

    PubMed

    Reddell, R C; Lebo, C P

    1972-01-01

    Temporary and permanent shifts in auditory thresholds were found in 43 hard rock musicians and temporary shifts were also observed in some listeners. The threshold shifts involved all of the conventional puretone test frequencies. Custom-fitted polyvinyl chloride ear protectors were found to be effective in prevention of these noise-induced hearing losses.

  5. Sustaining Transformation: "Resiliency in Hard Times"

    ERIC Educational Resources Information Center

    Guarasci, Richard; Lieberman, Devorah

    2009-01-01

    The strategic, systemic, and encompassing evolution of a college or university spans a number of years, and the vagaries of economic cycles inevitably catch transforming institutions in mid-voyage. "Sustaining Transformation: Resiliency in Hard Times" presents a study of Wagner College as it moves into its second decade of purposeful institutional…

  6. Hard Times: Philosophy and the Fundamentalist Imagination

    ERIC Educational Resources Information Center

    Allsup, Randall Everett

    2005-01-01

    A close reading of Gradgrind's opening monologue of Hard Times by Charles Dickens will provide the starting off point for an examination of the role and place of philosophy in the music curriculum. The Gradgrind philosophy finds easy parallel to current thinking in American education. In the fundamentalist imagination, sources of ambiguity must be…

  7. Registration of 'Advance' Hard Red Spring Wheat

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Grower and end-user acceptance of new hard red spring wheat (HRSW; Triticum aestivum L.) cultivars is largely contingent on satisfactory agronomic performance, end-use quality potential, and disease resistance levels. Additional characteristics, such as desirable plant height, can also help to maxi...

  8. Hard thermal loops in static external fields

    SciTech Connect

    Frenkel, J.; Takahashi, N.; Pereira, S. H.

    2009-04-15

    We examine, in the imaginary-time formalism, the high temperature behavior of n-point thermal loops in static Yang-Mills and gravitational fields. We show that in this regime, any hard thermal loop gives the same leading contribution as the one obtained by evaluating the loop integral at zero external energies and momenta.

  9. Classic and Hard-Boiled Detective Fiction.

    ERIC Educational Resources Information Center

    Reilly, John M.

    Through an analysis of several stories, this paper defines the similarities and differences between classic and hard-boiled detective fiction. The characters and plots of three stories are discussed: "The Red House" by A. A. Milne; "I, The Jury" by Mickey Spillane; and "League of Frightened Men" by Rex Stout. The classic detective story is defined…

  10. PROTEIN TEMPLATES IN HARD TISSUE ENGINEERING

    PubMed Central

    George, Anne; Ravindran, Sriram

    2010-01-01

    Biomineralization processes such as formation of bones and teeth require controlled mineral deposition and self-assembly into hierarchical biocomposites with unique mechanical properties. Ideal biomaterials for regeneration and repair of hard tissues must be biocompatible, possess micro and macroporosity for vascular invasion, provide surface chemistry and texture that facilitate cell attachment, proliferation, differentiation of lineage specific progenitor cells, and induce deposition of calcium phosphate mineral. To expect in-vivo like cellular response several investigators have used extracellular matrix proteins as templates to recreate in-vivo microenvironment for regeneration of hard tissues. Recently, several novel methods of designing tissue repair and restoration materials using bioinspired strategies are currently being formulated. Nanoscale structured materials can be fabricated via the spontaneous organization of self-assembling proteins to construct hierarchically organized nanomaterials. The advantage of such a method is that polypeptides can be specifically designed as building blocks incorporated with molecular recognition features and spatially distributed bioactive ligands that would provide a physiological environment for cells in-vitro and in-vivo. This is a rapidly evolving area and provides a promising platform for future development of nanostructured templates for hard tissue engineering. In this review we try to highlight the importance of proteins as templates for regeneration and repair of hard tissues as well as the potential of peptide based nanomaterials for regenerative therapies. PMID:20802848

  11. Registration of 'Prevail' hard red spring wheat

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Grower and end-user acceptance of new Hard Red Spring Wheat (HRSW; Triticum aestivum L.) cultivars is largely contingent upon satisfactory agronomic performance, end-use quality potential, and disease resistance levels. Additional characteristics, such as desirable plant height, can also contribute...

  12. Radiation-Hardness Data For Semiconductor Devices

    NASA Technical Reports Server (NTRS)

    Price, W. E.; Nichols, D. K.; Brown, S. F.; Gauthier, M. K.; Martin, K. E.

    1984-01-01

    Document presents data on and analysis of radiation hardness of various semiconductor devices. Data specifies total-dose radiation tolerance of devices. Volume 1 of report covers diodes, bipolar transistors, field effect transistors, silicon controlled rectifiers and optical devices. Volume 2 covers integrated circuits. Volume 3 provides detailed analysis of data in volumes 1 and 2.

  13. Remember Hard But Think Softly: Metaphorical Effects of Hardness/Softness on Cognitive Functions.

    PubMed

    Xie, Jiushu; Lu, Zhi; Wang, Ruiming; Cai, Zhenguang G

    2016-01-01

    Previous studies have found that bodily stimulation, such as hardness biases social judgment and evaluation via metaphorical association; however, it remains unclear whether bodily stimulation also affects cognitive functions, such as memory and creativity. The current study used metaphorical associations between "hard" and "rigid" and between "soft" and "flexible" in Chinese, to investigate whether the experience of hardness affects cognitive functions whose performance depends prospectively on rigidity (memory) and flexibility (creativity). In Experiment 1, we found that Chinese-speaking participants performed better at recalling previously memorized words while sitting on a hard-surface stool (the hard condition) than a cushioned one (the soft condition). In Experiment 2, participants sitting on a cushioned stool outperformed those sitting on a hard-surface stool on a Chinese riddle task, which required creative/flexible thinking, but not on an analogical reasoning task, which required both rigid and flexible thinking. The results suggest the hardness experience affects cognitive functions that are metaphorically associated with rigidity or flexibility. They support the embodiment proposition that cognitive functions and representations can be grounded in bodily states via metaphorical associations. PMID:27672373

  14. Remember Hard But Think Softly: Metaphorical Effects of Hardness/Softness on Cognitive Functions.

    PubMed

    Xie, Jiushu; Lu, Zhi; Wang, Ruiming; Cai, Zhenguang G

    2016-01-01

    Previous studies have found that bodily stimulation, such as hardness biases social judgment and evaluation via metaphorical association; however, it remains unclear whether bodily stimulation also affects cognitive functions, such as memory and creativity. The current study used metaphorical associations between "hard" and "rigid" and between "soft" and "flexible" in Chinese, to investigate whether the experience of hardness affects cognitive functions whose performance depends prospectively on rigidity (memory) and flexibility (creativity). In Experiment 1, we found that Chinese-speaking participants performed better at recalling previously memorized words while sitting on a hard-surface stool (the hard condition) than a cushioned one (the soft condition). In Experiment 2, participants sitting on a cushioned stool outperformed those sitting on a hard-surface stool on a Chinese riddle task, which required creative/flexible thinking, but not on an analogical reasoning task, which required both rigid and flexible thinking. The results suggest the hardness experience affects cognitive functions that are metaphorically associated with rigidity or flexibility. They support the embodiment proposition that cognitive functions and representations can be grounded in bodily states via metaphorical associations.

  15. Nanoindentation of a hard ceramic coating formed on a soft substrate

    NASA Astrophysics Data System (ADS)

    Surmeneva, M. A.; Surmenev, R. A.; Tyurin, A. I.; Pirozhkova, T. S.; Shuvarin, I. A.

    2016-09-01

    The hardness and Young's modulus of the thin hydroxyapatite-based coatings deposited by RF magnetron sputtering onto magnesium alloy, titanium, and steel substrates are studied. As the penetration depth increases, the hardness and Young's modulus of these coatings are found to tend toward the values that are characteristic of the substrates. It is shown that the difference between the values of hardness and Young's modulus at small penetration depths ( h < 80-100 nm) can be caused by the difference between the physicomechanical properties inside the coatings and that this difference at large penetration depths ( h > 100 nm) can be induced by an additional effect of the strength properties of the substrate material.

  16. Theoretical Studies on Bond Properties and Hardness of ABC2 (a = Zn, Cd, Cu, Ag; B = Si, Ge, Sn; C = P, As, S, Se, Te) Semiconductor with Chalcopyrites Structure

    NASA Astrophysics Data System (ADS)

    Zhao, Guangping; Yu, Bingjie

    2012-07-01

    The chemical bond parameters of II-IV-V2 and I-III-VI2 compounds have calculated using the chemical bond theory of complex crystals. Their hardnesses have been predicted by the chemical bond definition of hardness. The calculated results are in agreement with their experimental values. The calculation of hardness indicates that all of compounds possess good mechanical properties.

  17. Valuing Stillbirths.

    PubMed

    Phillips, John; Millum, Joseph

    2015-07-01

    Estimates of the burden of disease assess the mortality and morbidity that affect a population by producing summary measures of health such as quality-adjusted life years (QALYs) and disability-adjusted life years (DALYs). These measures typically do not include stillbirths (fetal deaths occurring during the later stages of pregnancy or during labor) among the negative health outcomes they count. Priority-setting decisions that rely on these measures are therefore likely to place little value on preventing the more than three million stillbirths that occur annually worldwide. In contrast, neonatal deaths, which occur in comparable numbers, have a substantial impact on burden of disease estimates and are commonly seen as a pressing health concern. In this article we argue in favor of incorporating unintended fetal deaths that occur late in pregnancy into estimates of the burden of disease. Our argument is based on the similarity between late-term fetuses and newborn infants and the assumption that protecting newborns is important. We respond to four objections to counting stillbirths: (1) that fetuses are not yet part of the population and so their deaths should not be included in measures of population health; (2) that valuing the prevention of stillbirths will undermine women's reproductive rights; (3) that including stillbirths implies that miscarriages (fetal deaths early in pregnancy) should also be included; and (4) that birth itself is in fact ethically significant. We conclude that our proposal is ethically preferable to current practice and, if adopted, is likely to lead to improved decisions about health spending.

  18. Valuing Stillbirths.

    PubMed

    Phillips, John; Millum, Joseph

    2015-07-01

    Estimates of the burden of disease assess the mortality and morbidity that affect a population by producing summary measures of health such as quality-adjusted life years (QALYs) and disability-adjusted life years (DALYs). These measures typically do not include stillbirths (fetal deaths occurring during the later stages of pregnancy or during labor) among the negative health outcomes they count. Priority-setting decisions that rely on these measures are therefore likely to place little value on preventing the more than three million stillbirths that occur annually worldwide. In contrast, neonatal deaths, which occur in comparable numbers, have a substantial impact on burden of disease estimates and are commonly seen as a pressing health concern. In this article we argue in favor of incorporating unintended fetal deaths that occur late in pregnancy into estimates of the burden of disease. Our argument is based on the similarity between late-term fetuses and newborn infants and the assumption that protecting newborns is important. We respond to four objections to counting stillbirths: (1) that fetuses are not yet part of the population and so their deaths should not be included in measures of population health; (2) that valuing the prevention of stillbirths will undermine women's reproductive rights; (3) that including stillbirths implies that miscarriages (fetal deaths early in pregnancy) should also be included; and (4) that birth itself is in fact ethically significant. We conclude that our proposal is ethically preferable to current practice and, if adopted, is likely to lead to improved decisions about health spending. PMID:25395144

  19. Financial and environmental modelling of water hardness--implications for utilising harvested rainwater in washing machines.

    PubMed

    Morales-Pinzón, Tito; Lurueña, Rodrigo; Gabarrell, Xavier; Gasol, Carles M; Rieradevall, Joan

    2014-02-01

    A study was conducted to determine the financial and environmental effects of water quality on rainwater harvesting systems. The potential for replacing tap water used in washing machines with rainwater was studied, and then analysis presented in this paper is valid for applications that include washing machines where tap water hardness may be important. A wide range of weather conditions, such as rainfall (284-1,794 mm/year); water hardness (14-315 mg/L CaCO3); tap water prices (0.85-2.65 Euros/m(3)) in different Spanish urban areas (from individual buildings to whole neighbourhoods); and other scenarios (including materials and water storage capacity) were analysed. Rainfall was essential for rainwater harvesting, but the tap water prices and the water hardness were the main factors for consideration in the financial and the environmental analyses, respectively. The local tap water hardness and prices can cause greater financial and environmental impacts than the type of material used for the water storage tank or the volume of the tank. The use of rainwater as a substitute for hard water in washing machines favours financial analysis. Although tap water hardness significantly affects the financial analysis, the greatest effect was found in the environmental analysis. When hard tap water needed to be replaced, it was found that a water price of 1 Euro/m(3) could render the use of rainwater financially feasible when using large-scale rainwater harvesting systems. When the water hardness was greater than 300 mg/L CaCO3, a financial analysis revealed that an net present value greater than 270 Euros/dwelling could be obtained at the neighbourhood scale, and there could be a reduction in the Global Warming Potential (100 years) ranging between 35 and 101 kg CO2 eq./dwelling/year.

  20. The unconstrained local hardness: an intriguing quantity, beset by problems.

    PubMed

    Cuevas-Saavedra, Rogelio; Rabi, Nataly; Ayers, Paul W

    2011-11-21

    Developing a mathematical approach to the local hard/soft acid/base principle requires an unambiguous definition for the local hardness. One such quantity, which has aroused significant interest in recent years, is the unconstrained local hardness. Key identities are derived for the unconstrained local hardness, δμ/δρ(r). Several identities are presented which allow one to determine the unconstrained local hardness either explicitly using the hardness kernel and the inverse-linear response function, or implicitly by solving a system of linear equations. One result of this analysis is that the problem of determining the unconstrained local hardness is infinitely ill-conditioned because arbitrarily small changes in electron density can cause enormous changes in the chemical potential. This is manifest in the exponential divergence of the unconstrained local hardness as one moves away from the system. This suggests that one should be very careful when using the unconstrained local hardness for chemical interpretation. PMID:21984043

  1. Physiological, perceptual, and technical responses to on-court tennis training on hard and clay courts.

    PubMed

    Reid, Machar M; Duffield, Rob; Minett, Geoffrey M; Sibte, Narelle; Murphy, Alistair P; Baker, John

    2013-06-01

    The aim of this study was to investigate the effect of court surface (clay vs. hard court) on technical, physiological, and perceptual responses to on-court tennis training. Four high-performance junior male players performed 2 identical training sessions on hard and clay courts, respectively. Sessions included both physical conditioning and technical elements as led by the coach. Each session was filmed for later notational analysis of stroke count and error rates. Furthermore, players wore a global positioning satellite device to measure distance covered during each session, while heart rate, countermovement jump distance, and capillary blood measures of metabolites were measured before, during, and after each session. Additionally, a respective coach and athlete rating of perceived exertion (RPE) were measured after each session. Total duration and distance covered during each session were comparable (p > 0.05; d < 0.20). Although forehand and backhands stroke volume did not differ between sessions (p > 0.05; d < 0.30), large effects for increased unforced and forced errors were present on the hard court (p > 0.05; d > 0.90). Furthermore, large effects for increased heart rate, blood lactate, and RPE values were evident on clay compared with hard courts (p > 0.05; d > 0.90). Additionally, although player and coach RPE on hard courts were similar, there were large effects for coaches to underrate the RPE of players on clay courts (p > 0.05; d > 0.90). In conclusion, training on clay courts results in trends for increased heart rate, lactate, and RPE values, suggesting that sessions on clay courts tend towards higher physiological and perceptual loads than hard courts. Furthermore, coaches seem effective at rating player RPE on hard courts but may underrate the perceived exertion of sessions on clay courts.

  2. Note: equation of state and the freezing point in the hard-sphere model.

    PubMed

    Robles, Miguel; López de Haro, Mariano; Santos, Andrés

    2014-04-01

    The merits of different analytical equations of state for the hard-sphere system with respect to the recently computed high-accuracy value of the freezing-point packing fraction are assessed. It is found that the Carnahan-Starling-Kolafa and the branch-point approximant equations of state yield the best performance.

  3. Measurement of blend concentrations of conventional and waxy hard wheats using NIR spectroscopy

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Breeding development of waxy hard wheat lines adapted to the North American climate has been underway for more than a decade, with releases of viable varieties imminent. Because of an anticipated premium value placed on waxy lots, a rapid and accurate method is desired to identify and quantify the m...

  4. Soft Power and Hard Measures: Large-Scale Assessment, Citizenship and the European Union

    ERIC Educational Resources Information Center

    Rutkowski, David; Engel, Laura C.

    2010-01-01

    This article explores the International Civic and Citizenship Education Study (ICCS) with particular emphasis on the European Union's (EU's) involvement in the regional portion. Using the ICCS, the EU actively combines hard measures with soft power, allowing the EU to define and steer cross-national rankings of values of EU citizenship. The…

  5. Improvement of Quench Factor Analysis in Phase and Hardness Prediction of a Quenched Steel

    NASA Astrophysics Data System (ADS)

    Kianezhad, M.; Sajjadi, S. A.

    2013-05-01

    The accurate prediction of alloys' properties introduced by heat treatment has been considered by many researchers. The advantages of such predictions are reduction of test trails and materials' consumption as well as time and energy saving. One of the most important methods to predict hardness in quenched steel parts is Quench Factor Analysis (QFA). Classical QFA is based on the Johnson-Mehl-Avrami-Kolmogorov (JMAK) equation. In this study, a modified form of the QFA based on the work by Rometsch et al. is compared with the classical QFA, and they are applied to prediction of hardness of steels. For this purpose, samples of CK60 steel were utilized as raw material. They were austenitized at 1103 K (830 °C). After quenching in different environments, they were cut and their hardness was determined. In addition, the hardness values of the samples were fitted using the classical and modified equations for the quench factor analysis and the results were compared. Results showed a significant improvement in fitted values of the hardness and proved the higher efficiency of the new method.

  6. Effects of different solutions on the surface hardness of composite resin materials.

    PubMed

    Yanikoğlu, Nuran; Duymuş, Zeynep Yeşil; Yilmaz, Baykal

    2009-05-01

    In this study, the surface hardness of five light-cured composite resins were evaluated, namely: filled (Estelite), nanofil (AElite), unfilled (Valux Plus), hybrid (Tetric ceram), and Ormocer-based (Admira) composite resins. The microhardness values of composite specimens were measured at the top and bottom surfaces after 24 hours or 30 days of immersion in different solutions (tea, coffee, Turkish coffee, mouthwash, cola, and distilled water). Comparisons were made with univariate analysis of variance and Duncan's multiple range test. It was found that rough specimens of reinforced nano-hybrid composite material immersed in cola for 30 days had the lowest surface hardness (33.20), whereas rough specimens of hybrid composite material immersed in cola for 24 hours had the highest surface hardness (156.00). In both tea and coffee, the top surfaces tended to be harder than the bottom ones. In conclusion, the five different materials exhibited different hardnesses, and that the hardness values of composite materials were statistically different in different immersion solutions.

  7. Valuing vaccination

    PubMed Central

    Bärnighausen, Till; Bloom, David E.; Cafiero-Fonseca, Elizabeth T.; O’Brien, Jennifer Carroll

    2014-01-01

    Vaccination has led to remarkable health gains over the last century. However, large coverage gaps remain, which will require significant financial resources and political will to address. In recent years, a compelling line of inquiry has established the economic benefits of health, at both the individual and aggregate levels. Most existing economic evaluations of particular health interventions fail to account for this new research, leading to potentially sizable undervaluation of those interventions. In line with this new research, we set forth a framework for conceptualizing the full benefits of vaccination, including avoided medical care costs, outcome-related productivity gains, behavior-related productivity gains, community health externalities, community economic externalities, and the value of risk reduction and pure health gains. We also review literature highlighting the magnitude of these sources of benefit for different vaccinations. Finally, we outline the steps that need to be taken to implement a broad-approach economic evaluation and discuss the implications of this work for research, policy, and resource allocation for vaccine development and delivery. PMID:25136129

  8. Hard-on-Hard Lubrication in the Artificial Hip under Dynamic Loading Conditions

    PubMed Central

    Sonntag, Robert; Reinders, Jörn; Rieger, Johannes S.; Heitzmann, Daniel W. W.; Kretzer, J. Philippe

    2013-01-01

    The tribological performance of an artificial hip joint has a particularly strong influence on its success. The principle causes for failure are adverse short- and long-term reactions to wear debris and high frictional torque in the case of poor lubrication that may cause loosening of the implant. Therefore, using experimental and theoretical approaches models have been developed to evaluate lubrication under standardized conditions. A steady-state numerical model has been extended with dynamic experimental data for hard-on-hard bearings used in total hip replacements to verify the tribological relevance of the ISO 14242-1 gait cycle in comparison to experimental data from the Orthoload database and instrumented gait analysis for three additional loading conditions: normal walking, climbing stairs and descending stairs. Ceramic-on-ceramic bearing partners show superior lubrication potential compared to hard-on-hard bearings that work with at least one articulating metal component. Lubrication regimes during the investigated activities are shown to strongly depend on the kinematics and loading conditions. The outcome from the ISO gait is not fully confirmed by the normal walking data and more challenging conditions show evidence of inferior lubrication. These findings may help to explain the differences between the in vitro predictions using the ISO gait cycle and the clinical outcome of some hard-on-hard bearings, e.g., using metal-on-metal. PMID:23940772

  9. Hard-on-hard lubrication in the artificial hip under dynamic loading conditions.

    PubMed

    Sonntag, Robert; Reinders, Jörn; Rieger, Johannes S; Heitzmann, Daniel W W; Kretzer, J Philippe

    2013-01-01

    The tribological performance of an artificial hip joint has a particularly strong influence on its success. The principle causes for failure are adverse short- and long-term reactions to wear debris and high frictional torque in the case of poor lubrication that may cause loosening of the implant. Therefore, using experimental and theoretical approaches models have been developed to evaluate lubrication under standardized conditions. A steady-state numerical model has been extended with dynamic experimental data for hard-on-hard bearings used in total hip replacements to verify the tribological relevance of the ISO 14242-1 gait cycle in comparison to experimental data from the Orthoload database and instrumented gait analysis for three additional loading conditions: normal walking, climbing stairs and descending stairs. Ceramic-on-ceramic bearing partners show superior lubrication potential compared to hard-on-hard bearings that work with at least one articulating metal component. Lubrication regimes during the investigated activities are shown to strongly depend on the kinematics and loading conditions. The outcome from the ISO gait is not fully confirmed by the normal walking data and more challenging conditions show evidence of inferior lubrication. These findings may help to explain the differences between the in vitro predictions using the ISO gait cycle and the clinical outcome of some hard-on-hard bearings, e.g., using metal-on-metal.

  10. Remember Hard But Think Softly: Metaphorical Effects of Hardness/Softness on Cognitive Functions

    PubMed Central

    Xie, Jiushu; Lu, Zhi; Wang, Ruiming; Cai, Zhenguang G.

    2016-01-01

    Previous studies have found that bodily stimulation, such as hardness biases social judgment and evaluation via metaphorical association; however, it remains unclear whether bodily stimulation also affects cognitive functions, such as memory and creativity. The current study used metaphorical associations between “hard” and “rigid” and between “soft” and “flexible” in Chinese, to investigate whether the experience of hardness affects cognitive functions whose performance depends prospectively on rigidity (memory) and flexibility (creativity). In Experiment 1, we found that Chinese-speaking participants performed better at recalling previously memorized words while sitting on a hard-surface stool (the hard condition) than a cushioned one (the soft condition). In Experiment 2, participants sitting on a cushioned stool outperformed those sitting on a hard-surface stool on a Chinese riddle task, which required creative/flexible thinking, but not on an analogical reasoning task, which required both rigid and flexible thinking. The results suggest the hardness experience affects cognitive functions that are metaphorically associated with rigidity or flexibility. They support the embodiment proposition that cognitive functions and representations can be grounded in bodily states via metaphorical associations. PMID:27672373

  11. Remember Hard But Think Softly: Metaphorical Effects of Hardness/Softness on Cognitive Functions

    PubMed Central

    Xie, Jiushu; Lu, Zhi; Wang, Ruiming; Cai, Zhenguang G.

    2016-01-01

    Previous studies have found that bodily stimulation, such as hardness biases social judgment and evaluation via metaphorical association; however, it remains unclear whether bodily stimulation also affects cognitive functions, such as memory and creativity. The current study used metaphorical associations between “hard” and “rigid” and between “soft” and “flexible” in Chinese, to investigate whether the experience of hardness affects cognitive functions whose performance depends prospectively on rigidity (memory) and flexibility (creativity). In Experiment 1, we found that Chinese-speaking participants performed better at recalling previously memorized words while sitting on a hard-surface stool (the hard condition) than a cushioned one (the soft condition). In Experiment 2, participants sitting on a cushioned stool outperformed those sitting on a hard-surface stool on a Chinese riddle task, which required creative/flexible thinking, but not on an analogical reasoning task, which required both rigid and flexible thinking. The results suggest the hardness experience affects cognitive functions that are metaphorically associated with rigidity or flexibility. They support the embodiment proposition that cognitive functions and representations can be grounded in bodily states via metaphorical associations.

  12. Hard-on-hard lubrication in the artificial hip under dynamic loading conditions.

    PubMed

    Sonntag, Robert; Reinders, Jörn; Rieger, Johannes S; Heitzmann, Daniel W W; Kretzer, J Philippe

    2013-01-01

    The tribological performance of an artificial hip joint has a particularly strong influence on its success. The principle causes for failure are adverse short- and long-term reactions to wear debris and high frictional torque in the case of poor lubrication that may cause loosening of the implant. Therefore, using experimental and theoretical approaches models have been developed to evaluate lubrication under standardized conditions. A steady-state numerical model has been extended with dynamic experimental data for hard-on-hard bearings used in total hip replacements to verify the tribological relevance of the ISO 14242-1 gait cycle in comparison to experimental data from the Orthoload database and instrumented gait analysis for three additional loading conditions: normal walking, climbing stairs and descending stairs. Ceramic-on-ceramic bearing partners show superior lubrication potential compared to hard-on-hard bearings that work with at least one articulating metal component. Lubrication regimes during the investigated activities are shown to strongly depend on the kinematics and loading conditions. The outcome from the ISO gait is not fully confirmed by the normal walking data and more challenging conditions show evidence of inferior lubrication. These findings may help to explain the differences between the in vitro predictions using the ISO gait cycle and the clinical outcome of some hard-on-hard bearings, e.g., using metal-on-metal. PMID:23940772

  13. Further links between the maximum hardness principle and the hard/soft acid/base principle: insights from hard/soft exchange reactions.

    PubMed

    Chattaraj, Pratim K; Ayers, Paul W; Melin, Junia

    2007-08-01

    Ayers, Parr, and Pearson recently showed that insight into the hard/soft acid/base (HSAB) principle could be obtained by analyzing the energy of reactions in hard/soft exchange reactions, i.e., reactions in which a soft acid replaces a hard acid or a soft base replaces a hard base [J. Chem. Phys., 2006, 124, 194107]. We show, in accord with the maximum hardness principle, that the hardness increases for favorable hard/soft exchange reactions and decreases when the HSAB principle indicates that hard/soft exchange reactions are unfavorable. This extends the previous work of the authors, which treated only the "double hard/soft exchange" reaction [P. K. Chattaraj and P. W. Ayers, J. Chem. Phys., 2005, 123, 086101]. We also discuss two different approaches to computing the hardness of molecules from the hardness of the composing fragments, and explain how the results differ. In the present context, it seems that the arithmetic mean of fragment softnesses is the preferable definition.

  14. Influence of pre-heat treatment and different light-curing units on Vickers hardness of a microhybrid composite resin

    NASA Astrophysics Data System (ADS)

    Saade, E. G.; Bandeca, M. C.; Rastelli, A. N. S.; Bagnato, V. S.; Porto-Neto, S. T.

    2009-06-01

    The aim of this study was to evaluate the hardness of a dental composite resin submitted to temperature changes before photo-activation with two light-curing unite (LCUs). Five samples (4 mm in diameter and 2 mm in thickness) for each group were made with pre-cure temperatures of 37, 54, and 60°C. The samples were photo-activated with a conventional quartz-tungsten-halogen (QTH) and blue LED LCUs during 40 s. The hardness Vickers test (VHN) was performed on the top and bottom surfaces of the samples. According to the interaction between light-curing unit and different pre-heating temperatures of composite resin, only the light-curing unit provided influences on the mean values of initial Vickers hardness. The light-curing unit based on blue LED showed hardness mean values more homogeneous between the top and bottom surfaces. The hardness mean values were not statistically significant difference for the pre-cure temperature used. According to these results, the pre-heating of the composite resin provide no influence on Vickers hardness mean values, however the blue LED showed a cure more homogeneous than QTH LCU.

  15. Spin effects in hard collision processes

    SciTech Connect

    Ranft, G.; Ranft, J.

    1984-05-01

    Questions of conservation and nonconservation of parity in phenomena associated with particle spin are reviewed. The main attention is concentrated on the production of hadrons, jets, and photons with large momentum transfer and the production of lepton pairs. The mechanisms of the hard-scattering subprocess include exchange of W/sup + -/ and Z/sup 0/ mesons, QCD and QED, and also interference between QCD and the weak interactions and between QED and the weak interactions. Effective cross sections of hard scattering processes are calculated, a factorization of the hadron--hadron scattering cross section is proposed, and the possible types of spin effects manifested in the hadronic subprocesses are classified and discussed. The properties of the polarized proton distributions and polarized structure functions are given in two appendices.

  16. Laser ablated hard coating for microtools

    DOEpatents

    McLean, W. II; Balooch, M.; Siekhaus, W.J.

    1998-05-05

    Wear-resistant coatings composed of laser ablated hard carbon films, are deposited by pulsed laser ablation using visible light, on instruments such as microscope tips and micro-surgical tools. Hard carbon, known as diamond-like carbon (DLC), films produced by pulsed laser ablation using visible light enhances the abrasion resistance, wear characteristics, and lifetimes of small tools or instruments, such as small, sharp silicon tips used in atomic probe microscopy without significantly affecting the sharpness or size of these devices. For example, a 10--20 nm layer of diamond-like carbon on a standard silicon atomic force microscope (AFM) tip, enables the useful operating life of the tip to be increased by at least twofold. Moreover, the low inherent friction coefficient of the DLC coating leads to higher resolution for AFM tips operating in the contact mode. 12 figs.

  17. Laser ablated hard coating for microtools

    DOEpatents

    McLean, II, William; Balooch, Mehdi; Siekhaus, Wigbert J.

    1998-05-05

    Wear-resistant coatings composed of laser ablated hard carbon films, are deposited by pulsed laser ablation using visible light, on instruments such as microscope tips and micro-surgical tools. Hard carbon, known as diamond-like carbon (DLC), films produced by pulsed laser ablation using visible light enhances the abrasion resistance, wear characteristics, and lifetimes of small tools or instruments, such as small, sharp silicon tips used in atomic probe microscopy without significantly affecting the sharpness or size of these devices. For example, a 10-20 nm layer of diamond-like carbon on a standard silicon atomic force microscope (AFM) tip, enables the useful operating life of the tip to be increased by at least twofold. Moreover, the low inherent friction coefficient of the DLC coating leads to higher resolution for AFM tips operating in the contact mode.

  18. Hard diffraction with dynamic gap survival

    NASA Astrophysics Data System (ADS)

    Rasmussen, Christine O.; Sjöstrand, Torbjörn

    2016-02-01

    We present a new framework for the modelling of hard diffraction in pp and poverline{p} collisions. It starts from the the approach pioneered by Ingelman and Schlein, wherein the single diffractive cross section is factorized into a Pomeron flux and a Pomeron PDF. To this it adds a dynamically calculated rapidity gap survival factor, derived from the modelling of multiparton interactions. This factor is not relevant for diffraction in ep collisions, giving non-universality between HERA and Tevatron diffractive event rates. The model has been implemented in P ythia 8 and provides a complete description of the hadronic state associated with any hard single diffractive process. Comparisons with poverline{p} and pp data reveal improvement in the description of single diffractive events.

  19. Hardness/intensity correlations among BATSE bursts

    NASA Technical Reports Server (NTRS)

    Paciesas, William S.; Pendleton, Geoffrey N.; Kouveliotou, Chryssa; Fishman, Gerald J.; Meegan, Charles A.; Wilson, Robert B.

    1992-01-01

    Conclusions about the nature of gamma-ray bursts derived from the size-frequency distribution may be altered if a significant correlation exists between burst intensity and spectral shape. Moreover, if gamma-ray bursts have a cosmological origin, such a correlation may be expected to result from the expansion of the universe. We have performed a rudimentary search of the BATSE bursts for hardness/intensity correlations. The range of spectral shapes was determined for each burst by computing the ratio of the intensity in the range 100-300 keV to that in 55-300 keV. We find weak evidence for the existence of a correlation, the strongest effect being present when comparing the maximum hardness ratio for each burst with its maximum rate.

  20. Rad-Hard/HI-REL FPGA

    NASA Technical Reports Server (NTRS)

    Wang, Jih-Jong; Cronquist, Brian E.; McGowan, John E.; Katz, Richard B.

    1997-01-01

    The goals for a radiation hardened (RAD-HARD) and high reliability (HI-REL) field programmable gate array (FPGA) are described. The first qualified manufacturer list (QML) radiation hardened RH1280 and RH1020 were developed. The total radiation dose and single event effects observed on the antifuse FPGA RH1280 are reported on. Tradeoffs and the limitations in the single event upset hardening are discussed.

  1. Radiation Hardness Assurance for Space Systems

    NASA Technical Reports Server (NTRS)

    Poivey, Christian; Day, John H. (Technical Monitor)

    2002-01-01

    The space radiation environment can lead to extremely harsh operating conditions for on-board electronic box and systems. The characteristics of the radiation environment are highly dependent on the type of mission (date, duration and orbit). Radiation accelerates the aging of the electronic parts and material and can lead to a degradation of electrical performance; it can also create transient phenomena on parts. Such damage at the part level can induce damage or functional failure at electronic box, subsystem, and system levels. A rigorous methodology is needed to ensure that the radiation environment does not compromise the functionality and performance of the electronics during the system life. This methodology is called hardness assurance. It consists of those activities undertaken to ensure that the electronic piece parts placed in the space system perform to their design specifications after exposure to the space environment. It deals with system requirements, environmental definitions, part selection, part testing, shielding and radiation tolerant design. All these elements should play together in order to produce a system tolerant to.the radiation environment. An overview of the different steps of a space system hardness assurance program is given in section 2. In order to define the mission radiation specifications and compare these requirements to radiation test data, a detailed knowledge of the space environment and the corresponding electronic device failure mechanisms is required. The presentation by J. Mazur deals with the Earth space radiation environment as well as the internal environment of a spacecraft. The presentation by J. Schwank deals with ionization effects, and the presentation by T. Weatherford deals with Single particle Event Phenomena (SEP) in semiconductor devices and microcircuits. These three presentations provide more detailed background to complement the sections 3 and 4. Part selection and categorization are discussed in section

  2. The PASCO Half-Byte Hard Drive

    NASA Astrophysics Data System (ADS)

    Anderson, Peter S.

    2005-03-01

    To provide an interesting application of Faraday's law, Brad Hinaus and Mick Veum created an experiment constructing a scaled-up model of a computer hard drive. They mounted permanent magnets on a wooden disk. When the disk was spun, an emf was induced in a "read" head (solenoid) and recorded by a computer. I have found a way to do a similar experiment using only PASCO equipment.2

  3. Nanotwinned diamond with unprecedented hardness and stability.

    PubMed

    Huang, Quan; Yu, Dongli; Xu, Bo; Hu, Wentao; Ma, Yanming; Wang, Yanbin; Zhao, Zhisheng; Wen, Bin; He, Julong; Liu, Zhongyuan; Tian, Yongjun

    2014-06-12

    Although diamond is the hardest material for cutting tools, poor thermal stability has limited its applications, especially at high temperatures. Simultaneous improvement of the hardness and thermal stability of diamond has long been desirable. According to the Hall-Petch effect, the hardness of diamond can be enhanced by nanostructuring (by means of nanograined and nanotwinned microstructures), as shown in previous studies. However, for well-sintered nanograined diamonds, the grain sizes are technically limited to 10-30 nm (ref. 3), with degraded thermal stability compared with that of natural diamond. Recent success in synthesizing nanotwinned cubic boron nitride (nt-cBN) with a twin thickness down to ∼3.8 nm makes it feasible to simultaneously achieve smaller nanosize, ultrahardness and superior thermal stability. At present, nanotwinned diamond (nt-diamond) has not been fabricated successfully through direct conversions of various carbon precursors (such as graphite, amorphous carbon, glassy carbon and C60). Here we report the direct synthesis of nt-diamond with an average twin thickness of ∼5 nm, using a precursor of onion carbon nanoparticles at high pressure and high temperature, and the observation of a new monoclinic crystalline form of diamond coexisting with nt-diamond. The pure synthetic bulk nt-diamond material shows unprecedented hardness and thermal stability, with Vickers hardness up to ∼200 GPa and an in-air oxidization temperature more than 200 °C higher than that of natural diamond. The creation of nanotwinned microstructures offers a general pathway for manufacturing new advanced carbon-based materials with exceptional thermal stability and mechanical properties.

  4. Nanotwinned diamond with unprecedented hardness and stability

    NASA Astrophysics Data System (ADS)

    Huang, Quan; Yu, Dongli; Xu, Bo; Hu, Wentao; Ma, Yanming; Wang, Yanbin; Zhao, Zhisheng; Wen, Bin; He, Julong; Liu, Zhongyuan; Tian, Yongjun

    2014-06-01

    Although diamond is the hardest material for cutting tools, poor thermal stability has limited its applications, especially at high temperatures. Simultaneous improvement of the hardness and thermal stability of diamond has long been desirable. According to the Hall-Petch effect, the hardness of diamond can be enhanced by nanostructuring (by means of nanograined and nanotwinned microstructures), as shown in previous studies. However, for well-sintered nanograined diamonds, the grain sizes are technically limited to 10-30 nm (ref. 3), with degraded thermal stability compared with that of natural diamond. Recent success in synthesizing nanotwinned cubic boron nitride (nt-cBN) with a twin thickness down to ~3.8 nm makes it feasible to simultaneously achieve smaller nanosize, ultrahardness and superior thermal stability. At present, nanotwinned diamond (nt-diamond) has not been fabricated successfully through direct conversions of various carbon precursors (such as graphite, amorphous carbon, glassy carbon and C60). Here we report the direct synthesis of nt-diamond with an average twin thickness of ~5 nm, using a precursor of onion carbon nanoparticles at high pressure and high temperature, and the observation of a new monoclinic crystalline form of diamond coexisting with nt-diamond. The pure synthetic bulk nt-diamond material shows unprecedented hardness and thermal stability, with Vickers hardness up to ~200 GPa and an in-air oxidization temperature more than 200 °C higher than that of natural diamond. The creation of nanotwinned microstructures offers a general pathway for manufacturing new advanced carbon-based materials with exceptional thermal stability and mechanical properties.

  5. Dynamic Hardness Tester and Cure Meter

    NASA Technical Reports Server (NTRS)

    Madigosky, Walter M.; Fiorito, Ralph B.

    1993-01-01

    The Shore hardness tester is used extensively throughout industry to determine the static modulus of materials. The new apparatus described here extends the capability of an indentor-type tester into the dynamic regime, and provides a measurement of the dynamic shear or Young's modulus and loss factor as a function of frequency. The instrument, model and data of typical rubber samples are given and compared to other dynamic measurements.

  6. Experiments on asteroids using hard landers

    NASA Technical Reports Server (NTRS)

    Turkevich, A.; Economou, T.

    1978-01-01

    Hard lander missions to asteroids are examined using the Westphal penetrator study as a basis. Imagery and chemical information are considered to be the most significant science to be obtained. The latter, particularly a detailed chemical analysis performed on an uncontaminated sample, may answer questions about the relationships of asteroids to meteorites and the place of asteroids in theories of the formation of the solar system.

  7. Nematic-columnar phase transition in oriented hard rectangles

    NASA Astrophysics Data System (ADS)

    Nath, Trisha; Dhar, Deepak; Rajesh, R.

    We consider an assembly of monodispersed hard rectangles of size 2 × d on a square lattice with only hard core interactions amongst them. The long axes of the rectangles can be oriented along the horizontal or vertical directions. For large enough aspect ratio, it is known that this system undergoes three phase transitions as the density (ρ) of rectangles is increased: first an isotropic-nematic transition (at ρ1*), second a nematic-columnar transition (at ρ2*), and third a columnar-sublattice transition (at ρ3*). In the nematic phase, only the orientational symmetry is broken. The columnar and sublattice phases correspond to additional broken translational symmetries along one (perpendicular to the nematic orientation) and both directions respectively. Interestingly, the critical value ρ2* remains finite, approximately 0 . 73 , even as d --> ∞ . We develop a systematic high density expansion for the surface tension between two differently-ordered columnar phases. Keeping only the first order perturbative correction term and setting this surface tension to zero, we get an estimate of ρ2* in excellent agreement with estimates from Monte Carlo simulations, for all d >= 2 .

  8. Hard and soft spectral states of ULXs

    NASA Astrophysics Data System (ADS)

    Soria, R.

    2011-05-01

    I discuss some differences between the observed spectral states of ultraluminous X-ray sources (ULXs) and the canonical scheme of spectral states defined in Galactic black holes. The standard interpretation of ULXs with a curved spectrum, or a moderately steep power-law with soft excess and high-energy downturn, is that they are an extension of the very high state, up to luminosities {≈ 1}-3 L_Edd. Two competing models are Comptonization in a warm corona, and slim disk; I suggest bulk motion Comptonization in the radiatively-driven outflow as another possibility. The interpretation of ULXs with a hard power-law spectrum is more problematic. Some of them remain in that state over a large range of luminosities; others switch directly to a curved state without going through a canonical high/soft state. I suggest that those ULXs are in a high/hard state not seen in Galactic black holes; that state may overlap with the low/hard state at lower accretion rates, and extend all the way to Eddington accretion rates. If some black holes can reach Eddington accretion rates without switching to a standard-disk-dominated state, it is also possible that they never quench their steady jets.

  9. Hardness variability in commercial and hardened technologies

    SciTech Connect

    Shaneyfelt, M.R.; Winokur, P.S.; Meisenheimer, T.L.; Sexton, F.W.; Roeske, S.B.; Knoll, M.G.

    1994-03-01

    Over the past 10 years, there have been a number of advances in methods to assess and assure the radiation hardness of microelectronics in military and space applications. At the forefront of these is the Qualified Manufacturers List (QML) methodology, in which the hardness of product is ``built-in`` through statistical process control (SPC) of technology parameters relevant to the radiation response, test structure to integrated circuit (IC) correlations, and techniques for extrapolating laboratory test results to varying radiation scenarios. At the same time, there has been renewed interest in the use of commercial technology -- with its enhanced performance, reduced cost, and higher reliability -- in military and space systems. In this paper, we initially demonstrate the application of QML techniques to assure and control the radiation response of hardened technologies. Through several examples, we demonstrate intra-die, wafer-to-wafer, and lot-to-lot variations in a hardened technology. We observe 10 to 30% variations in key technology parameters that result from variability in geometry, process, and design layout. Radiation-induced degradation is seen to mirror preirradiation characteristics. We then evaluate commercial technologies and report considerably higher variability in radiation hardness, i.e., variations by a factor of two to five. This variability is shown to arise from a lack of control of technology parameters relevant to the radiation response, which a commercial manufacturer has no interest in controlling in a normal process flow.

  10. Hardness variability in commercial and hardened technologies

    NASA Astrophysics Data System (ADS)

    Shaneyfelt, M. R.; Winokur, P. S.; Meisenheimer, T. L.; Sexton, F. W.; Roeske, S. B.; Knoll, M. G.

    1994-01-01

    Over the past 10 years, there have been a number of advances in methods to assess and assure the radiation hardness of microelectronics in military and space applications. At the forefront of these is the Qualified Manufacturers List (QML) methodology, in which the hardness of product is 'built-in' through statistical process control (SPC) of technology parameters relevant to the radiation response, test structure to integrated circuit (IC) correlations, and techniques for extrapolating laboratory test results to varying radiation scenarios. At the same time, there has been renewed interest in the use of commercial technology -- with its enhanced performance, reduced cost, and higher reliability -- in military and space systems. In this paper, we initially demonstrate the application of QML techniques to assure and control the radiation response of hardened technologies. Through several examples, we demonstrate intra-die, wafer-to-wafer, and lot-to-lot variations in a hardened technology. We observe 10 to 30% variations in key technology parameters that result from variability in geometry, process, and design layout. Radiation-induced degradation is seen to mirror preirradiation characteristics. We then evaluate commercial technologies and report considerably higher variability in radiation hardness, i.e., variations by a factor of two to five. This variability is shown to arise from a lack of control of technology parameters relevant to the radiation response, which a commercial manufacturer has no interest in controlling in a normal process flow.

  11. Effect of supraglottic and super-supraglottic swallows on tongue pressure production against hard palate.

    PubMed

    Fujiwara, Shigehiro; Ono, Takahiro; Minagi, Yoshitomo; Fujiu-Kurachi, Masako; Hori, Kazuhiro; Maeda, Yoshinobu; Boroumand, Sara; Nitschke, Ina; Ursula, Vith; Bohlender, Jörg

    2014-12-01

    The objectives of this study were to evaluate the state of tongue pressure production during supraglottic swallow (SS) and super-supraglottic swallow (SSS) performed by healthy adults, and to investigate the effects of these swallowing maneuvers on the oral stage of swallowing. The participants were 19 healthy individuals. Tongue pressure against the hard palate during swallowing was measured using a tongue pressure sensor sheet system with five pressure-sensitive points. The tasks comprised swallowing 5 mL of water by normal wet swallow, SS, and SSS, and the parameters for analysis were the duration, the maximal magnitude, and the integrated value of tongue pressure during swallowing. The duration of tongue pressure was significantly longer at the anterior-median part of the hard palate during both SS and SSS than with normal wet swallow. The maximal magnitude increased significantly only at the posterior part of the hard palate during SS, but at all points during SSS. The integrated value increased significantly only at the posterior-median part of the hard palate during SS, but at all points except the mid-median part of the hard palate during SSS. The maximal magnitude and integrated value were also significantly higher at the anterior-median and posterior circumferential parts during SSS than during SS. These results show that these two swallowing maneuvers, which are known primarily as techniques to protect the airway, also function to strengthen the tongue pressure produced by the contact between the tongue and the hard palate during swallowing and this effect is more pronounced during SSS.

  12. The electronic structure of hard materials

    NASA Astrophysics Data System (ADS)

    Winarski, Robert Paul

    This research dissertation involves an experimental as well as a theoretical examination of the electronic structure of hard materials. The materials that are presented in this dissertation cover a wide class of materials, consisting of transition metal borides, irradiated polymer films, theoretically predicted superhard semiconductors, doped intermetallic alloys, and transition metal carbides. The borides are traditionally used in high temperature, hard coating applications, such as rocket nozzle linings, extreme wear surfaces, and corrosion coatings. Measurements of the borides appear to show that the bonding in these hard materials is primarily between the boron atoms in these systems. Also of note are the remarkably short interatomic distances between the boron atoms and between the boron and metal atoms in these materials. Irradiated polymer films are being developed for electronic applications, in the hopes that circuits can be developed that can benefit from the high thermal stability, dielectric properties, and mechanical properties provided by these materials. C3N4 is a theoretically predicted superhard material, and some of the first soft x-ray emission measurements of well-characterized samples of this compound are discussed in this work. Intermetallic alloys, in particular Ni3Al, are rather hard, but brittle metallic alloys. It has been found that the addition of boron atoms, in rather low concentrations, can increase the ductility of these alloys, allowing them to be utilized in a wider variety of applications. Measurements of this system have examined a question regarding the positioning of the boron atoms in the structures of this alloy. Finally, the transition metal carbides are used extensively as coatings in industrial applications such as cutting and grinding tools, and polishing compounds. Measurements of these materials suggest that the high degree of covalency between the metal and carbon atoms is primarily responsible for the hardness of

  13. Fault-Tolerant, Radiation-Hard DSP

    NASA Technical Reports Server (NTRS)

    Czajkowski, David

    2011-01-01

    Commercial digital signal processors (DSPs) for use in high-speed satellite computers are challenged by the damaging effects of space radiation, mainly single event upsets (SEUs) and single event functional interrupts (SEFIs). Innovations have been developed for mitigating the effects of SEUs and SEFIs, enabling the use of very-highspeed commercial DSPs with improved SEU tolerances. Time-triple modular redundancy (TTMR) is a method of applying traditional triple modular redundancy on a single processor, exploiting the VLIW (very long instruction word) class of parallel processors. TTMR improves SEU rates substantially. SEFIs are solved by a SEFI-hardened core circuit, external to the microprocessor. It monitors the health of the processor, and if a SEFI occurs, forces the processor to return to performance through a series of escalating events. TTMR and hardened-core solutions were developed for both DSPs and reconfigurable field-programmable gate arrays (FPGAs). This includes advancement of TTMR algorithms for DSPs and reconfigurable FPGAs, plus a rad-hard, hardened-core integrated circuit that services both the DSP and FPGA. Additionally, a combined DSP and FPGA board architecture was fully developed into a rad-hard engineering product. This technology enables use of commercial off-the-shelf (COTS) DSPs in computers for satellite and other space applications, allowing rapid deployment at a much lower cost. Traditional rad-hard space computers are very expensive and typically have long lead times. These computers are either based on traditional rad-hard processors, which have extremely low computational performance, or triple modular redundant (TMR) FPGA arrays, which suffer from power and complexity issues. Even more frustrating is that the TMR arrays of FPGAs require a fixed, external rad-hard voting element, thereby causing them to lose much of their reconfiguration capability and in some cases significant speed reduction. The benefits of COTS high

  14. Lead in bones and drinking water in towns with hard and soft water.

    PubMed

    Crawford, M D; Clayton, D G

    1973-04-01

    In two comparable series of medicolegal necropsies the lead content of ribs was found to be much higher in three soft water than in three hard water towns in England and Wales. Fourteen out of 96 "overnight" tap water samples from five soft water and five hard water towns in England and Wales and from Glasgow (soft water) had lead concentrations of over 0.1 p.p.m.; values over 0.3 p.p.m. were found only in Glasgow. The possible relevance of the findings to the association of cardiovascular disease and soft drinking water is discussed.

  15. Contact pair correlation functions and equation of state for additive hard disk fluid mixtures

    NASA Astrophysics Data System (ADS)

    Barrio, C.; Solana, J. R.

    2001-10-01

    The contact pair correlation functions and the equation of state for a binary mixture of additive hard disks is obtained using a procedure similar to that leading to the Boublı´k-Mansoori-Carnahan-Starling-Leland equation of state for mixtures of additive hard spheres. The results from the derived equations are tested against new Monte Carlo data obtained for several diameter ratios and mole fractions. The overall agreement is excellent. The equation of state reproduces exactly the second virial coefficient of the mixture and the third with great accuracy. Predicted values of the fourth and fifth virial coefficients are also in very good agreement with numerical data.

  16. Arsenic, nitrate, iron, and hardness in ground water, Chena Ridge vicinity, Fairbanks, Alaska

    USGS Publications Warehouse

    Krumhardt, Andrea P.

    1979-01-01

    The report presents all data on hardness, iron, nitrate and arsenic in well water in the Chena Ridge area of Fairbanks, Alaska, through June 1979. Concentrations range as follows: arsenic - 0 to 28 micrograms per liter; nitrate - 0 to 20 milligrams per liter; iron - 0 to 18 milligrams per liter and hardness - 72 to 1,400 milligrams per liter. Values at the upper ends of the ranges for iron and nitrate exceed limits recommended by the Environmental Protection Agency for public water supplies. A map of the area showing the location of sampled wells and a table of chemical analysis are included. (Kosco-USGS)

  17. Lead in Bones and Drinking Water in Towns with Hard and Soft Water

    PubMed Central

    Crawford, M. D.; Clayton, D. G.

    1973-01-01

    In two comparable series of medicolegal necropsies the lead content of ribs was found to be much higher in three soft water than in three hard water towns in England and Wales. Fourteen out of 96 “overnight” tap water samples from five soft water and five hard water towns in England and Wales and from Glasgow (soft water) had lead concentrations of over 0·1 p.p.m.; values over 0·3 p.p.m. were found only in Glasgow. The possible relevance of the findings to the association of cardiovascular disease and soft drinking water is discussed. PMID:4695691

  18. Hard Times May Exact a Toll on Brain Health

    MedlinePlus

    ... https://medlineplus.gov/news/fullstory_161283.html Hard Times May Exact a Toll on Brain Health Poverty ... a cause-and-effect relationship between hard economic times and brain health and aging. The findings were ...

  19. Toughness enhancement in zirconium-tungsten-nitride nanocrystalline hard coatings

    NASA Astrophysics Data System (ADS)

    Dubey, P.; Srivastava, S.; Chandra, R.; Ramana, C. V.

    2016-07-01

    An approach is presented to increase the toughness (KIC) while retaining high hardness (H) of Zr-W-N nanocrystalline coatings using energetic ions bombardment. Tuning KIC and H values was made possible by a careful control over the substrate bias, i.e., the kinetic energy (Uk˜9-99 J/cm3) of the bombarding ions, while keeping the deposition temperature relatively low (200 oC). Structural and mechanical characterization revealed a maximum wear resistance (H/Er˜0.23) and fracture toughness (KIC˜2.25 MPa √{ m } ) of ZrWN coatings at Uk˜72 J/cm3. A direct Uk-microstructure-KIC-H relationship suggests that tailoring mechanical properties for a given application is possible by tuning Uk and, hence, ZrWN-coatings' microstructure.

  20. Hard X-ray Microscopic Images of the Human Hair

    SciTech Connect

    Goo, Jawoong; Jeon, Soo Young; Oh, Tak Heon; Hong, Seung Phil; Lee, Won-Soo; Yon, Hwa Shik

    2007-01-19

    The better visualization of the human organs or internal structure is challenging to the physicist and physicians. It can lead to more understanding of the morphology, pathophysiology and the diagnosis. Conventionally used methods to investigate cells or architectures, show limited value due to sample processing procedures and lower resolution. In this respect, Zernike type phase contrast hard x-ray microscopy using 6.95keV photon energy has advantages. We investigated hair fibers of the normal healthy persons. Coherence based phase contrast images revealed three distinct structures of hair, medulla, cortex, and cuticular layer. Some different detailed characters of each sample were noted. And further details would be shown and these results would be utilized as basic data of morphologic study of human hair.

  1. Hard X-ray Microscopic Images of the Human Hair

    NASA Astrophysics Data System (ADS)

    Goo, Jawoong; Jeon, Soo Young; Oh, Tak Heon; Hong, Seung Phil; Yon, Hwa Shik; Lee, Won-Soo

    2007-01-01

    The better visualization of the human organs or internal structure is challenging to the physicist and physicians. It can lead to more understanding of the morphology, pathophysiology and the diagnosis. Conventionally used methods to investigate cells or architectures, show limited value due to sample processing procedures and lower resolution. In this respect, Zernike type phase contrast hard x-ray microscopy using 6.95keV photon energy has advantages. We investigated hair fibers of the normal healthy persons. Coherence based phase contrast images revealed three distinct structures of hair, medulla, cortex, and cuticular layer. Some different detailed characters of each sample were noted. And further details would be shown and these results would be utilized as basic data of morphologic study of human hair.

  2. Sticky hard spheres beyond the Percus-Yevick approximation

    NASA Astrophysics Data System (ADS)

    Yuste, S. Bravo; Santos, A.

    1993-12-01

    The radial distribution function g(r) of a sticky-hard-sphere fluid is obtained by assuming a rational-function form for a function related to the Laplace transform of rg(r), compatible with the conditions of finite y(r)==g(r)ecphi(r)/kBT at c ontact point and finite isothermal compressibility. In a recent paper [S. Bravo Yuste and A. Santos, J. Stat. Phys. 72, 703 (1993)] we have shown that the simplest rational-function approximation, namely, the Padé approximant (2,3), leads to Baxter's exact solution of the Percus-Yevick equation. Here we consider the next approximation, i.e., the Padé approximant (3,4), and determine the two new parameters by imposing the values of y(r) at contact point and of the isothermal compressibility. Comparison with Monte Carlo simulation results shows a significant improvement over the Percus-Yevick approximation.

  3. Packaging of hard solder 500W QCW diode laser array

    NASA Astrophysics Data System (ADS)

    Li, Xiaoning; Wang, Jingwei; Hou, Dong; Nie, Zhiqiang; Liu, Xingsheng

    2016-03-01

    The package structure critically influences the major characteristics of diode laser, such as thermal behavior, output power, wavelength and smile effect. In this work, a novel micro channel cooler (MCC) for stack array laser with good heat dissipation capability and high reliability is presented. Numerical simulations of thermal management with different MCC structure are conducted and analyzed. Based on this new MCC packaging structure, a series of QCW 500W high power laser arrays with hard solder packaging technology has been fabricated. The performances of the laser arrays are characterized. A narrow spectrum of 3.12 nm and an excellent smile value are obtained. The lifetime of the laser array is more than 1.38×109 shots and still ongoing.

  4. Process for casting hard-faced, lightweight camshafts and other cylindrical products

    DOEpatents

    Hansen, Jeffrey S.; Turner, Paul C.; Argetsinger, Edward R.; Wilson, Rick D.

    1996-01-01

    A process for casting a hard-faced cylindrical product such as an automobile camshaft includes the steps of: (a) preparing a composition formed from a molten base metal and an additive in particle form and having a hardness value greater than the hardness value of the base metal; (b) introducing the composition into a flask containing a meltable pattern of a cylindrical product such as an automobile camshaft to be manufactured and encased in sand to allow the composition to melt the pattern and assume the shape of the pattern within the sand; and (c) rotating the flask containing the pattern about the longitudinal axes of both the flask and the pattern as the molten base metal containing the additive in particle form is introduced into the flask to cause particles of the additive entrained in the molten base metal to migrate by centrifugal action to the radial extremities of the pattern and thereby provide a cylindrical product having a hardness value greater at it's radial extremities than at its center when the molten base metal solidifies.

  5. Evaluation of hardness and color stability in the soft lining materials after thermocycling and chemical polishing.

    PubMed

    Goiato, Marcelo Coelho; Falcón-Antenucci, Rosse Mary; Santos, Daniela Micheline dos; Pellizzer, Eduardo Piza

    2009-01-01

    The aim of this study was to evaluate the Shore A hardness and color stability of two soft lining materials after thermocycling and when chemical polishing was used or omitted. Two acrylic-based soft lining materials were tested: Coe-Soft and Soft Confort, 14 specimens were made for each material. They were distributed in four groups according to the treatment performed. The specimens were thermocycled (1000 cycles) and half of the group submitted to chemical polishing (methyl methacrylate). Shore A hardness was determined and color stability was calculated by means of Commission International de l'Eclairage Lab uniform color scale using a spectrophotometer, the measurements were made immediately after deflasked, chemical polishing and thermocycling. Analysis of variance (ANOVA) and Tukey's tests were performed at p < 0.01. Color changes (deltaE) were observed after thermocycling in both soft lining materials: Soft Confort (10.60) showed significantly higher values than Coe-Soft (4.57). Coe-Soft (26.42) showed higher Shore A hardness values than Soft Confort (19.42). Chemical polishing did not influence in the color stability of both materials; however, influenced in the hardness values of Coe-Soft.

  6. Evaluation of hardness and color stability in the soft lining materials after thermocycling and chemical polishing.

    PubMed

    Goiato, Marcelo Coelho; Falcón-Antenucci, Rosse Mary; Santos, Daniela Micheline dos; Pellizzer, Eduardo Piza

    2009-01-01

    The aim of this study was to evaluate the Shore A hardness and color stability of two soft lining materials after thermocycling and when chemical polishing was used or omitted. Two acrylic-based soft lining materials were tested: Coe-Soft and Soft Confort, 14 specimens were made for each material. They were distributed in four groups according to the treatment performed. The specimens were thermocycled (1000 cycles) and half of the group submitted to chemical polishing (methyl methacrylate). Shore A hardness was determined and color stability was calculated by means of Commission International de l'Eclairage Lab uniform color scale using a spectrophotometer, the measurements were made immediately after deflasked, chemical polishing and thermocycling. Analysis of variance (ANOVA) and Tukey's tests were performed at p < 0.01. Color changes (deltaE) were observed after thermocycling in both soft lining materials: Soft Confort (10.60) showed significantly higher values than Coe-Soft (4.57). Coe-Soft (26.42) showed higher Shore A hardness values than Soft Confort (19.42). Chemical polishing did not influence in the color stability of both materials; however, influenced in the hardness values of Coe-Soft. PMID:19601498

  7. High-energy strong interactions: from `hard' to `soft'

    NASA Astrophysics Data System (ADS)

    Ryskin, M. G.; Martin, A. D.; Khoze, V. A.

    2011-04-01

    We discuss the qualitative features of the recent data on multiparticle production observed at the LHC. The tolerable agreement with Monte Carlos based on LO DGLAP evolution indicates that there is no qualitative difference between `hard' and `soft' interactions; and that a perturbative QCD approach may be extended into the soft domain. However, in order to describe the data, these Monte Carlos need an additional infrared cutoff k min with a value k min ˜2-3 GeV which is not small, and which increases with collider energy. Here we explain the physical origin of the large k min . Using an alternative model which matches the `soft' high-energy hadron interactions smoothly on to perturbative QCD at small x, we demonstrate that this effective cutoff k min is actually due to the strong absorption of low k t partons. The model embodies the main features of the BFKL approach, including the diffusion in transverse momenta, ln k t , and an intercept consistent with resummed next-to-leading log corrections. Moreover, the model uses a two-channel eikonal framework, and includes the contributions from the multi-Pomeron exchange diagrams, both non-enhanced and enhanced. The values of a small number of physically-motivated parameters are chosen to reproduce the available total, elastic and proton dissociation cross section (pre-LHC) data. Predictions are made for the LHC, and the relevance to ultra-high-energy cosmic rays is briefly discussed. The low x inclusive integrated gluon PDF, and the diffractive gluon PDF, are calculated in this framework, using the parameters which describe the high-energy pp and pbar{p} ` soft' data. Comparison with the PDFs obtained from the global parton analyses of deep inelastic and related hard scattering data and from diffractive deep inelastic data looks encouraging.

  8. Hard Cap Espresso Machines in Analytical Chemistry: What Else?

    PubMed

    Armenta, Sergio; de la Guardia, Miguel; Esteve-Turrillas, Francesc A

    2016-06-21

    A hard cap espresso machine has been used in combination with liquid chromatography with molecular fluorescence detection for the determination of polycyclic aromatic hydrocarbons (PAHs) from contaminated soils and sediments providing appropriate extraction efficiencies and quantitative results. Naphthalene, acenaphthene, fluorene, phenanthrene, anthracene, fluoranthene, pyrene, benz[a]anthracene, chrysene, benz[b]fluoranthene, benz[k]fluoranthene, benz[a]pyrene, dibenz[a,h]anthracene, benz[ghi]perylene, and indeno[1,2,3-cd]pyrene were used as target compounds. It should be mentioned that the pairs benz[a]anthracene-chrysene and dibenz[a,h]anthracene-benz[ghi]perylene peaks coelute under the employed chromatographic conditions; thus, those compounds were determined together. PAHs were extracted from 5.0 g of soil, previously homogenized, freeze-dried, and sieved to 250 μm, with 50 mL of 40% (v/v) acetonitrile in water at a temperature of 72 ± 3 °C. The proposed procedure is really fast, with an extraction time of 11 s, and it reduces the required amount of organic solvent to do the sample preparation. The obtained limit of detection for the evaluated PAHs was from 1 to 38 μg kg(-1). Recoveries were calculated using clean soils spiked with 100, 500, 1000, and 2000 μg kg(-1) PAHs with values ranging from 81 to 121% and good precision with relative standard deviation values lower than 30%. The method was validated using soil and sediment certified reference materials and also using real samples by comparison with ultrasound-assisted extraction, as reference methodology, obtaining statistically comparable results. Thus, the use of hard cap espresso machines in the analytical laboratories offers tremendous possibilities as low cost extraction units for the extraction of solid samples.

  9. Equation of state for hard convex body fluid mixtures

    NASA Astrophysics Data System (ADS)

    Barrio, C.; Solana, J. R.

    A model previously developed for the equation of state of pure fluids consisting of hard convex body molecules is extended to mixtures. The parameters of the model can be determined from the geometrical characteristics of the molecules which form the mixture. The equation of state is in excellent agreement with simulation data for mixtures of hard spheres with hard spherocylinders.

  10. 21 CFR 133.148 - Hard grating cheeses.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 2 2011-04-01 2011-04-01 false Hard grating cheeses. 133.148 Section 133.148 Food... Related Products § 133.148 Hard grating cheeses. (a) The cheeses for which definitions and standards of identity are prescribed by this section are hard grating cheeses for which specifically...

  11. 75 FR 4031 - Streamlining Hard-Copy Postage Statement Processing

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-26

    ... 111 Streamlining Hard-Copy Postage Statement Processing AGENCY: Postal Service\\TM\\. ACTION: Proposed... Postal Service, Domestic Mail Manual (DMM ), to reflect changes in the processing of hard-copy postage... complete the ``USPS Use Only'' section of, or round date, hard-copy postage statements...

  12. Study of hot hardness characteristics of tool steels

    NASA Technical Reports Server (NTRS)

    Chevalier, J. L.; Dietrich, M. W.; Zaretsky, E. V.

    1972-01-01

    Hardness measurements of tool steel materials in electric furnace at elevated temperatures and low oxygen environment are discussed. Development of equation to predict short term hardness as function of intial room temperature hardness of steel is reported. Types of steel involved in the process are identified.

  13. Hardness of Al-based quasicrystals evaluated via cluster-plus-glue-atom model

    NASA Astrophysics Data System (ADS)

    Chen, Hua; Luo, Lingjie; Qiang, Jianbing; Wang, Yingmin; Dong, Chuang

    2014-05-01

    In this paper, the hardness of ternary Al-based quasicrystals was assessed through an application of the cluster-plus-glue-atom model. In this model, any structure is decomposed into a first-neighbour strongly bonded cluster part and second-neighbour weakly bonded glue-atom part so that the overall structural information is condensed into a local structural unit [cluster](glue atom)x. For quasicrystals, the averaged local units are formulated as [icosahedron] TM0,1(Transition Metal) and could be visualized as single icosahedron packing. Then, the hardness of quasicrystals was related to the rupture of weak inter-cluster bonds. Typically, theoretical hardness values of 8-9 GPa were obtained using 19 broken inter-cluster bonds, which accounts for about half of all the surface bonds of an icosahedron in the Mackay-type environment. The unit cluster formulas would act as rigid units during deformation and cracking.

  14. Radial distribution function for hard spheres in fractal dimensions: A heuristic approximation.

    PubMed

    Santos, Andrés; de Haro, Mariano López

    2016-06-01

    Analytic approximations for the radial distribution function, the structure factor, and the equation of state of hard-core fluids in fractal dimension d (1≤d≤3) are developed as heuristic interpolations from the knowledge of the exact and Percus-Yevick results for the hard-rod and hard-sphere fluids, respectively. In order to assess their value, such approximate results are compared with those of recent Monte Carlo simulations and numerical solutions of the Percus-Yevick equation for a fractal dimension [M. Heinen et al., Phys. Rev. Lett. 115, 097801 (2015)PRLTAO0031-900710.1103/PhysRevLett.115.097801], a good agreement being observed.

  15. Radial distribution function for hard spheres in fractal dimensions: A heuristic approximation.

    PubMed

    Santos, Andrés; de Haro, Mariano López

    2016-06-01

    Analytic approximations for the radial distribution function, the structure factor, and the equation of state of hard-core fluids in fractal dimension d (1≤d≤3) are developed as heuristic interpolations from the knowledge of the exact and Percus-Yevick results for the hard-rod and hard-sphere fluids, respectively. In order to assess their value, such approximate results are compared with those of recent Monte Carlo simulations and numerical solutions of the Percus-Yevick equation for a fractal dimension [M. Heinen et al., Phys. Rev. Lett. 115, 097801 (2015)PRLTAO0031-900710.1103/PhysRevLett.115.097801], a good agreement being observed. PMID:27415227

  16. The material co-construction of hard science fiction and physics

    NASA Astrophysics Data System (ADS)

    Hasse, Cathrine

    2015-12-01

    This article explores the relationship between hard science fiction and physics and a gendered culture of science. Empirical studies indicate that science fiction references might spur some students' interest in physics and help develop this interest throughout school, into a university education and even further later inspire the practice of doing science. There are many kinds of fiction within the science fiction genre. In the presented empirical exploration physics students seem particularly fond of what is called `hard science fiction': a particular type of science fiction dealing with technological developments (Hartwell and Cramer in The hard SF renaissance, Orb/TOR, New York, 2002). Especially hard science fiction as a motivating fantasy may, however, also come with a gender bias. The locally materialized techno-fantasies spurring dreams of the terraforming of planets like Mars and travels in time and space may not be shared by all physics students. Especially female students express a need for other concerns in science. The entanglement of physics with hard science fiction may thus help develop some students' interest in learning school physics and help create an interest for studying physics at university level. But research indicates that especially female students are not captured by the hard techno-fantasies to the same extent as some of their male colleagues. Other visions (e.g. inspired by soft science fiction) are not materialized as a resource in the local educational culture. It calls for an argument of how teaching science is also teaching cultural values, ethics and concerns, which may be gendered. Teaching materials, like the use of hard science fiction in education, may not just be (yet another) gender bias in science education but also carrier of particular visions for scientific endeavours.

  17. Relative importance of calcium and magnesium in hardness-based modification of copper toxicity

    SciTech Connect

    Welsh, P.G.; Lipton, J.; Chapman, G.A.; Podrabsky, T.L.

    2000-06-01

    Because of the relationship between water hardness and the toxicity of many metals, total hardness is used as a model parameter to calculate ambient water quality criteria for copper and other metals. However, the relative contribution of the Ca and Mg components of total hardness as modifiers of metals toxicity is not considered in the water quality criteria. Acute Cu toxicity was measured in rainbow trout (Oncorhynchus mykiss) and chinook salmon (O. tshawytscha) swim-up fry in laboratory waters that were formulated to have similar total hardness and alkalinity but different Ca and Mg concentrations. Experiments were performed at nominal total hardness values of 40 and 90 mg/L (as CaCO{sub 3}). In four paired toxicity tests, acute Cu toxicity was significantly lower, i.e., 96-h LC50s were higher, in laboratory waters containing proportionately more Ca (Ca:Mg molar ratios of 1.5--5.2) than in waters containing less Ca (Ca:Mg molar ratios of 0.2--0.8). the relative increase in the 96-h Cu LC50 at higher Ca concentrations, but similar total hardness concentrations, was between 29 and 86% when the low Ca treatment was similar to American Society for Testing and Materials laboratory water. Failure to account for differences in Ca when matching or adjusting for total hardness thus exerts an important influence on the prediction of metal toxicity. These differences must be addressed in water-effect ratio testing in which paired tests with laboratory and site waters are conducted.

  18. CO2 laser milling of hard tissue

    NASA Astrophysics Data System (ADS)

    Werner, Martin; Ivanenko, Mikhail; Harbecke, Daniela; Klasing, Manfred; Steigerwald, Hendrik; Hering, Peter

    2007-02-01

    Drilling of bone and tooth tissue belongs to recurrent medical procedures (screw- and pin-bores, bores for implant inserting, trepanation etc.). Small round bores can be in general quickly produced with mechanical drills. Problems arise however by angled drilling, by the necessity to fulfill the drilling without damaging of sensitive soft tissue beneath the bone, or by the attempt to mill precisely noncircular small cavities. We present investigations on laser hard tissue "milling", which can be advantageous for solving these problems. The "milling" is done with a CO2 laser (10.6 μm) with pulse duration of 50 - 100 μs, combined with a PC-controlled galvanic beam scanner and with a fine water-spray, which helps to avoid thermal side-effects. The damaging of underlying soft tissue can be prevented through control of the optical or acoustical ablation signal. The ablation of hard tissue is accompanied with a strong glowing, which is absent during the laser beam action on soft tissue. The acoustic signals from the diverse tissue types exhibit distinct differences in the spectral composition. Also computer image analysis could be a useful tool to control the operation. Laser "milling" of noncircular cavities with 1 - 4 mm width and about 10 mm depth is particularly interesting for dental implantology. In ex-vivo investigations we found conditions for fast laser "milling" of the cavities without thermal damage and with minimal tapering. It included exploration of different filling patterns (concentric rings, crosshatch, parallel lines and their combinations), definition of maximal pulse duration, repetition rate and laser power, optimal position of the spray. The optimized results give evidences for the applicability of the CO2 laser for biologically tolerable "milling" of deep cavities in the hard tissue.

  19. Results on hard diffraction from CDF

    SciTech Connect

    Goulianos, K.

    1997-05-01

    We present results from studies of hard diffractive processes in {anti p}p collisions at {radical}s=1.8 TeV at the Tevatron using the CDF detector. Diffractive events are identified by the characteristic signature of a rapidity gap and/or by detecting a recoil antiproton with high forward momentum. Reactions studied include the diffractive production of W-bosons and of two-jet (dijet) events, diffractive heavy quark production, and dijet production by double-pomeron exchange.

  20. Justified hard paternalism: a response to Ten.

    PubMed

    Rainbolt, George W

    1989-04-01

    In a brief response to C.L. Ten's critique in the same issue of Bioethics of an earlier article by Rainbolt, Rainbolt defends his thesis that prescription drug laws are examples of permissible hard paternalism. They are not justifiable by soft paternalism, which permits interference with people's conduct only when their choices are insufficiently voluntary, because people who buy prescription drugs have good metaknowledge, i.e., they know that they do not know much about drugs and are making a decision based on this knowledge. PMID:11649244

  1. Arching in tapped deposits of hard disks.

    PubMed

    Pugnaloni, Luis A; Valluzzi, Marcos G; Valluzzi, Lucas G

    2006-05-01

    We simulate the tapping of a bed of hard disks in a rectangular box by using a pseudodynamic algorithm. In these simulations, arches are unambiguously defined and we can analyze their properties as a function of the tapping amplitude. We find that an order-disorder transition occurs within a narrow range of tapping amplitudes as has been seen by others. Arches are always present in the system although they exhibit regular shapes in the ordered regime. Interestingly, an increase in the number of arches does not always correspond to a reduction in the packing fraction. This is in contrast with what is found in three-dimensional systems.

  2. Nonvolatile Rad-Hard Holographic Memory

    NASA Technical Reports Server (NTRS)

    Chao, Tien-Hsin; Zhou, Han-Ying; Reyes, George; Dragoi, Danut; Hanna, Jay

    2001-01-01

    We are investigating a nonvolatile radiation-hardened (rad-hard) holographic memory technology. Recently, a compact holographic data storage (CHDS) breadboard utilizing an innovative electro-optic scanner has been built and demonstrated for high-speed holographic data storage and retrieval. The successful integration of this holographic memory breadboard has paved the way for follow-on radiation resistance test of the photorefractive (PR) crystal, Fe:LiNbO3. We have also started the investigation of using two-photon PR crystals that are doubly doped with atoms of iron group (Ti, Cr, Mn, Cu) and of rare-earth group (Nd, Tb) for nonvolatile holographic recordings.

  3. Effect of Austenitizing Heat Treatment on the Microstructure and Hardness of Martensitic Stainless Steel AISI 420

    NASA Astrophysics Data System (ADS)

    Barlow, L. D.; Du Toit, M.

    2012-07-01

    The effect of austenitizing on the microstructure and hardness of two martensitic stainless steels was examined with the aim of supplying heat-treatment guidelines to the user that will ensure a martensitic structure with minimal retained austenite, evenly dispersed carbides and a hardness of between 610 and 740 HV (Vickers hardness) after quenching and tempering. The steels examined during the course of this examination conform in composition to medium-carbon AISI 420 martensitic stainless steel, except for the addition of 0.13% vanadium and 0.62% molybdenum to one of the alloys. Steel samples were austenitized at temperatures between 1000 and 1200 °C, followed by oil quenching. The as-quenched microstructures were found to range from almost fully martensitic structures to martensite with up to 35% retained austenite after quenching, with varying amounts of carbides. Optical and scanning electron microscopy was used to characterize the microstructures, and X-ray diffraction was employed to identify the carbide present in the as-quenched structures and to quantify the retained austenite contents. Hardness tests were performed to determine the effect of heat treatment on mechanical properties. As-quenched hardness values ranged from 700 to 270 HV, depending on the amount of retained austenite. Thermodynamic predictions (using the CALPHAD™ model) were employed to explain these microstructures based on the solubility of the carbide particles at various austenitizing temperatures.

  4. Superhard nanocomposite of dense polymorphs of boron nitride: Noncarbon material has reached diamond hardness

    NASA Astrophysics Data System (ADS)

    Dubrovinskaia, Natalia; Solozhenko, Vladimir L.; Miyajima, Nobuyoshi; Dmitriev, Vladimir; Kurakevych, Oleksandr O.; Dubrovinsky, Leonid

    2007-03-01

    The authors report a synthesis of unique superhard aggregated boron nitride nanocomposites (ABNNCs) showing the enhancement of hardness up to 100% in comparison with single crystal c-BN. Such a great hardness increase is due to the combination of the Hall-Petch and the quantum confinement effects. The decrease of the grain size down to 14nm and the simultaneous formation of the two dense BN phases with hexagonal and cubic structures within the grains at nano- and subnanolevel result in enormous mechanical property enhancement with maximum hardness of 85(5)GPa. Thus, ABNNC is the first non-carbon-based bulk material with the value of hard-ness approaching that of single crystal and polycrystalline diamond and aggregated diamond nanorods. ABNNC also has an unusually high fracture toughness for superhard materials (K1C=15MPam0.5) and wear resistance (WH=11; compare, for industrial polycrystalline diamond, WH=3-4), in combination with high thermal stability (above 1600K in air), making it an exceptional superabrasive.

  5. Hardness evaluation of prosthetic silicones containing opacifiers following chemical disinfection and accelerated aging.

    PubMed

    Goiato, Marcelo Coelho; Haddad, Marcela Filié; Santos, Daniela Micheline dos; Pesqueira, Aldiéris Alves; Moreno, Amália

    2010-01-01

    We evaluated the effects of disinfection and aging on the hardness of silicones containing opacifiers and intended for use in facial prosthetics. A total of 90 samples were produced using a cylindrical metal mold 3 mm in height and 30 mm in diameter. The samples were fabricated from Silastic MDX 4-4210 silicone in three groups: GI contained no opacifier, GII contained barium sulfate (Ba), and GIII contained titanium dioxide (Ti). The samples were disinfected using effervescent tablets (Ef), neutral soap (Ns), or 4% chlorhexidine (Cl) 3 times a week for 60 days. After this period the samples underwent 1,008 hours of accelerated aging. The hardness was measured using a durometer immediately following the disinfection period and after 252, 504, and 1,008 hours of aging. The data were statistically analyzed using 3-way ANOVA and the Tukey test (p < .05). The GIII group exhibited the greatest variation in hardness regardless of elapsed time. All groups displayed greater hardness after 1,008 hours of accelerated aging independent of disinfectant type. All of the hardness values were within the clinically acceptable range.

  6. Hardness of FeB{sub 4}: Density functional theory investigation

    SciTech Connect

    Zhang, Miao; Du, Yonghui; Gao, Lili; Lu, Mingchun; Lu, Cheng; Liu, Hanyu

    2014-05-07

    A recent experimental study reported the successful synthesis of an orthorhombic FeB{sub 4} with a high hardness of 62(5) GPa [H. Gou et al., Phys. Rev. Lett. 111, 157002 (2013)], which has reignited extensive interests on whether transition-metal borides compounds will become superhard materials. However, it is contradicted with some theoretical studies suggesting transition-metal boron compounds are unlikely to become superhard materials. Here, we examined structural and electronic properties of FeB{sub 4} using density functional theory. The electronic calculations show the good metallicity and covalent Fe–B bonding. Meanwhile, we extensively investigated stress-strain relations of FeB{sub 4} under various tensile and shear loading directions. The calculated weakest tensile and shear stresses are 40 GPa and 25 GPa, respectively. Further simulations (e.g., electron localization function and bond length along the weakest loading direction) on FeB{sub 4} show the weak Fe–B bonding is responsible for this low hardness. Moreover, these results are consistent with the value of Vickers hardness (11.7–32.3 GPa) by employing different empirical hardness models and below the superhardness threshold of 40 GPa. Our current results suggest FeB{sub 4} is a hard material and unlikely to become superhard (>40 GPa)

  7. Investigation of structural, dielectric, and magnetic properties of hard and soft mixed ferrite composites

    NASA Astrophysics Data System (ADS)

    Kotnala, R. K.; Ahmad, Shahab; Ahmed, Arham S.; Shah, Jyoti; Azam, Ameer

    2012-09-01

    Barium ferrite (hard ferrite) and manganese nickel zinc ferrite (soft ferrite) were successfully synthesized by citrate gel combustion technique. They were used to form the composites by mixing them properly in required compositions (x)BaFe12O19-(1-x)Mn0.2Ni0.4Zn0.4Fe2O4 (0 ≤ x ≤ 1). X-ray diffraction (XRD) and scanning electron microscopy (SEM) were utilized to investigate the different structural and morphological parameters of pure and mixed ferrite composites. XRD and SEM results confirmed the coexistence of both phases in the composite material. Moreover, it has been observed that the composites were constituted by nanosized particles. Structure of pure soft ferrite was found to be cubic and that of pure hard ferrite was hexagonal. Dielectric constant (ɛ' and ɛ″) and dielectric loss (tan δ) were analyzed as a function of frequency and composition and the behaviour is explained on the basis of Maxwell-Wagner model. It was observed that the dielectric loss decreases with the increase of hard ferrite content in the composite material. Magnetic measurements suggest the exchange coupling between the magnetizations of soft and hard ferrite grains. It has been observed that the coercivity increases with the increase of the volume of the hard phase in the composite material after an optimal value.

  8. Equation of state for fluid mixtures of hard spheres and linear homonuclear fused hard spheres

    NASA Astrophysics Data System (ADS)

    Largo, J.; Solana, J. R.

    1998-08-01

    This paper develops a theoretically based equation of state for fluid mixtures consisting of hard spheres and linear homonuclear fused hard spheres. The procedure is based on the equation of state previously developed for monocomponent athermal fluids. The equation of state only requires two parameters, namely the averaged effective molecular volume of the molecules in the mixture and the corresponding effective nonsphericity parameter. These parameters can be obtained from the geometry of the molecules forming the mixture. The results are in excellent agreement with simulation data and compare favorably with those obtained from other theories for athermal fluid mixtures.

  9. Influence of Gene Expression on Hardness in Wheat

    PubMed Central

    Nirmal, Ravi C.; Wrigley, Colin

    2016-01-01

    Puroindoline (Pina and Pinb) genes control grain texture or hardness in wheat. Wild-type/soft alleles lead to softer grain while a mutation in one or both of these genes results in a hard grain. Variation in hardness in genotypes with identical Pin alleles (wild-type or mutant) is known but the molecular basis of this is not known. We now report the identification of wheat genotypes with hard grain texture and wild-type/soft Pin alleles indicating that hardness in wheat may be controlled by factors other than mutations in the coding region of the Pin genes. RNA-Seq analysis was used to determine the variation in the transcriptome of developing grains of thirty three diverse wheat genotypes including hard (mutant Pin) and soft (wild type) and those that were hard without having Pin mutations. This defined the role of pin gene expression and identified other candidate genes associated with hardness. Pina was not expressed in hard wheat with a mutation in the Pina gene. The ratio of Pina to Pinb expression was generally lower in the hard non mutant genotypes. Hardness may be associated with differences in Pin expression and other factors and is not simply associated with mutations in the PIN protein coding sequences. PMID:27741295

  10. Statistical Physics of Hard Optimization Problems

    NASA Astrophysics Data System (ADS)

    Zdeborová, Lenka

    2008-06-01

    Optimization is fundamental in many areas of science, from computer science and information theory to engineering and statistical physics, as well as to biology or social sciences. It typically involves a large number of variables and a cost function depending on these variables. Optimization problems in the NP-complete class are particularly difficult, it is believed that the number of operations required to minimize the cost function is in the most difficult cases exponential in the system size. However, even in an NP-complete problem the practically arising instances might, in fact, be easy to solve. The principal question we address in this thesis is: How to recognize if an NP-complete constraint satisfaction problem is typically hard and what are the main reasons for this? We adopt approaches from the statistical physics of disordered systems, in particular the cavity method developed originally to describe glassy systems. We describe new properties of the space of solutions in two of the most studied constraint satisfaction problems - random satisfiability and random graph coloring. We suggest a relation between the existence of the so-called frozen variables and the algorithmic hardness of a problem. Based on these insights, we introduce a new class of problems which we named "locked" constraint satisfaction, where the statistical description is easily solvable, but from the algorithmic point of view they are even more challenging than the canonical satisfiability.

  11. Statistical physics of hard optimization problems

    NASA Astrophysics Data System (ADS)

    Zdeborová, Lenka

    2009-06-01

    Optimization is fundamental in many areas of science, from computer science and information theory to engineering and statistical physics, as well as to biology or social sciences. It typically involves a large number of variables and a cost function depending on these variables. Optimization problems in the non-deterministic polynomial (NP)-complete class are particularly difficult, it is believed that the number of operations required to minimize the cost function is in the most difficult cases exponential in the system size. However, even in an NP-complete problem the practically arising instances might, in fact, be easy to solve. The principal question we address in this article is: How to recognize if an NP-complete constraint satisfaction problem is typically hard and what are the main reasons for this? We adopt approaches from the statistical physics of disordered systems, in particular the cavity method developed originally to describe glassy systems. We describe new properties of the space of solutions in two of the most studied constraint satisfaction problems - random satisfiability and random graph coloring. We suggest a relation between the existence of the so-called frozen variables and the algorithmic hardness of a problem. Based on these insights, we introduce a new class of problems which we named "locked" constraint satisfaction, where the statistical description is easily solvable, but from the algorithmic point of view they are even more challenging than the canonical satisfiability.

  12. Combinatorics of bicubic maps with hard particles

    NASA Astrophysics Data System (ADS)

    Bouttier, J.; Di Francesco, P.; Guitter, E.

    2005-05-01

    We present a purely combinatorial solution of the problem of enumerating planar bicubic maps with hard particles. This is done by the use of a bijection with a particular class of blossom trees with particles, obtained by an appropriate cutting of the maps. Although these trees have no simple local characterization, we prove that their enumeration may be performed upon introducing a larger class of 'admissible' trees with possibly doubly occupied edges and summing them with appropriate signed weights. The proof relies on an extension of the cutting procedure allowing for the presence on the maps of special non-sectile edges. The admissible trees are characterized by simple local rules, allowing eventually for an exact enumeration of planar bicubic maps with hard particles. We also discuss generalizations for maps with particles subject to more general exclusion rules and show how to re-derive the enumeration of quartic maps with Ising spins in the present framework of admissible trees. We finally comment on a possible interpretation in terms of branching processes.

  13. Solving the hard problem of Bertrand's paradox

    SciTech Connect

    Aerts, Diederik; Sassoli de Bianchi, Massimiliano

    2014-08-15

    Bertrand's paradox is a famous problem of probability theory, pointing to a possible inconsistency in Laplace's principle of insufficient reason. In this article, we show that Bertrand's paradox contains two different problems: an “easy” problem and a “hard” problem. The easy problem can be solved by formulating Bertrand's question in sufficiently precise terms, so allowing for a non-ambiguous modelization of the entity subjected to the randomization. We then show that once the easy problem is settled, also the hard problem becomes solvable, provided Laplace's principle of insufficient reason is applied not to the outcomes of the experiment, but to the different possible “ways of selecting” an interaction between the entity under investigation and that producing the randomization. This consists in evaluating a huge average over all possible “ways of selecting” an interaction, which we call a universal average. Following a strategy similar to that used in the definition of the Wiener measure, we calculate such universal average and therefore solve the hard problem of Bertrand's paradox. The link between Bertrand's problem of probability theory and the measurement problem of quantum mechanics is also briefly discussed.

  14. The Relationship Between the Accumulated Number of Role Transitions and Hard Drug Use among Hispanic Emerging Adults.

    PubMed

    Allem, Jon-Patrick; Soto, Daniel; Baezconde-Garbanati, Lourdes; Unger, Jennifer

    2015-01-01

    Emerging adults (ages 18 to 25) who experience multiple role transitions in a short period of time may engage in hard drug use as a maladaptive coping strategy to avoid negative emotions from stress. Given the collectivistic values Hispanics encounter growing up, they may experience additional role transitions due to their group-oriented cultural paradigm. This study examined whether those who experience many role transitions are at greater risk for hard drug use compared to those who experience few transitions among Hispanic emerging adults. Participants completed surveys indicating their hard drug use in emerging adulthood, role transitions in the past year of emerging adulthood, age, gender, and hard drug use in high school. Simulation analyses indicated that an increase in the number of role transitions, from 0 to 13, was associated with a 14% (95% CI, 4 to 29) higher probability of hard drug use. Specific role transitions were found to be associated with hard drug use, such as starting to date or experiencing a breakup. Intervention/prevention programs may benefit from acknowledging individual reactions to transitions in emerging adulthood, as these processes may be catalysts for personal growth where identities are consolidated and decisions regarding hard drug use are formed.

  15. The Relationship Between the Accumulated Number of Role Transitions and Hard Drug Use Among Hispanic Emerging Adults

    PubMed Central

    Allem, Jon-Patrick; Soto, Daniel; Baezconde-Garbanati, Lourdes; Unger, Jennifer

    2014-01-01

    Emerging adults (ages 18 to 25) who experience multiple role transitions in a short period of time may engage in hard drug use as a maladaptive coping strategy to avoid negative emotions from stress. Given the collectivistic values Hispanics encounter growing up, they may experience additional role transitions due to their group oriented cultural paradigm. This study examined whether those who experience many role transitions are at greater risk for hard drug use compared to those who experience few transitions among Hispanic emerging adults. Participants completed surveys indicating their hard drug use in emerging adulthood, role transitions in the past year of emerging adulthood, age, gender, and hard drug use in high school. Simulation analyses indicated that an increase in the number of role transitions, from 0 to 13, was associated with a 14% (95% CI, 4 to 29) higher probability of hard drug use. Specific role transitions were found to be associated with hard drug use, such as starting to date or experiencing a breakup. Intervention/prevention programs may benefit from acknowledging individual reactions to transitions in emerging adulthood, as these processes may be catalysts for personal growth where identities are consolidated, and decisions regarding hard drug use are formed. PMID:25715073

  16. Reliability and validity of quantifying absolute muscle hardness using ultrasound elastography.

    PubMed

    Chino, Kentaro; Akagi, Ryota; Dohi, Michiko; Fukashiro, Senshi; Takahashi, Hideyuki

    2012-01-01

    Muscle hardness is a mechanical property that represents transverse muscle stiffness. A quantitative method that uses ultrasound elastography for quantifying absolute human muscle hardness has been previously devised; however, its reliability and validity have not been completely verified. This study aimed to verify the reliability and validity of this quantitative method. The Young's moduli of seven tissue-mimicking materials (in vitro; Young's modulus range, 20-80 kPa; increments of 10 kPa) and the human medial gastrocnemius muscle (in vivo) were quantified using ultrasound elastography. On the basis of the strain/Young's modulus ratio of two reference materials, one hard and one soft (Young's moduli of 7 and 30 kPa, respectively), the Young's moduli of the tissue-mimicking materials and medial gastrocnemius muscle were calculated. The intra- and inter-investigator reliability of the method was confirmed on the basis of acceptably low coefficient of variations (≤6.9%) and substantially high intraclass correlation coefficients (≥0.77) obtained from all measurements. The correlation coefficient between the Young's moduli of the tissue-mimicking materials obtained using a mechanical method and ultrasound elastography was 0.996, which was equivalent to values previously obtained using magnetic resonance elastography. The Young's moduli of the medial gastrocnemius muscle obtained using ultrasound elastography were within the range of values previously obtained using magnetic resonance elastography. The reliability and validity of the quantitative method for measuring absolute muscle hardness using ultrasound elastography were thus verified.

  17. Influence of shade and irradiation time on the hardness of composite resins.

    PubMed

    Della Bona, Alvaro; Rosa, Vinícius; Cecchetti, Dileta

    2007-01-01

    This study tested the following hypotheses: 1. increasing light irradiation time (IT) produces greater values of superficial hardness on different depths (0 and 3 mm); and 2. a dark shade composite (A3) needs longer IT than a light shade composite (A1) to produce similar hardness. Disk-shaped specimens (n=24 per shade) were fabricated using a 3-mm-thick increment of composite resin (Z100). Specimens were randomly assigned to 3 groups (n=8) according to the IT (400 mW/cm2) at the upper (U) surface: A1-10 and A3-10: 10 s; A1-20 and A3-20: 20 s; A1-40 and A3-40: 40 s. Specimens were stored in black lightproof containers at 37 masculineC for 24 h before indentation in a hardness tester. Three Vickers indentations were performed on the U and lower (L) surfaces of each specimen. The indent diagonals were measured and the hardness value calculated. The results were analyzed statistically by ANOVA and Tukey's test (alpha=0.05). Statistically significant differences were found between U and L surfaces of each composite shade-IT combination (p=0.0001) and among the ITs of same shade-surface combination (p=0.0001), except between groups A1-20U and A1-40U, confirming the study hypothesis 1 and partially rejecting the hypothesis 2.

  18. Fate of Mycobacterium avium subsp. paratuberculosis in Swiss hard and semihard cheese manufactured from raw milk.

    PubMed

    Spahr, U; Schafroth, K

    2001-09-01

    Raw milk was artificially contaminated with declumped cells of Mycobacterium avium subsp. paratuberculosis at a concentration of 10(4) to 10(5) CFU/ml and was used to manufacture model hard (Swiss Emmentaler) and semihard (Swiss Tisliter) cheese. Two different strains of M. avium subsp. paratuberculosis were tested, and for each strain, two model hard and semihard cheeses were produced. The survival of M. avium subsp. paratuberculosis cells was monitored over a ripening period of 120 days by plating out homogenized cheese samples onto 7H10-PANTA agar. In both the hard and the semihard cheeses, counts decreased steadily but slowly during cheese ripening. Nevertheless, viable cells could still be detected in 120-day cheese. D values were calculated at 27.8 days for hard and 45.5 days for semihard cheese. The most important factors responsible for the death of M. avium subsp. paratuberculosis in cheese were the temperatures applied during cheese manufacture and the low pH at the early stages of cheese ripening. Since the ripening period for these raw milk cheeses lasts at least 90 to 120 days, the D values found indicate that 10(3) to 10(4) cells of M. avium subsp. paratuberculosis per g will be inactivated.

  19. Fate of Mycobacterium avium subsp. paratuberculosis in Swiss Hard and Semihard Cheese Manufactured from Raw Milk

    PubMed Central

    Spahr, U.; Schafroth, K.

    2001-01-01

    Raw milk was artificially contaminated with declumped cells of Mycobacterium avium subsp. paratuberculosis at a concentration of 104 to 105 CFU/ml and was used to manufacture model hard (Swiss Emmentaler) and semihard (Swiss Tisliter) cheese. Two different strains of M. avium subsp. paratuberculosis were tested, and for each strain, two model hard and semihard cheeses were produced. The survival of M. avium subsp. paratuberculosis cells was monitored over a ripening period of 120 days by plating out homogenized cheese samples onto 7H10-PANTA agar. In both the hard and the semihard cheeses, counts decreased steadily but slowly during cheese ripening. Nevertheless, viable cells could still be detected in 120-day cheese. D values were calculated at 27.8 days for hard and 45.5 days for semihard cheese. The most important factors responsible for the death of M. avium subsp. paratuberculosis in cheese were the temperatures applied during cheese manufacture and the low pH at the early stages of cheese ripening. Since the ripening period for these raw milk cheeses lasts at least 90 to 120 days, the D values found indicate that 103 to 104 cells of M. avium subsp. paratuberculosis per g will be inactivated. PMID:11526024

  20. Fractions, Decimals, Ratios, & Percents: Hard To Teach and Hard To Learn? Mathematics Teaching Cases.

    ERIC Educational Resources Information Center

    Barnett, Carne, Ed.; And Others

    This book presents teacher-written cases relating stories, insights, and experiences about the teaching of fractions, decimals, ratios, and percents. The cases were written to stimulate colleagues to examine their own practice, to think hard about the mathematics they teach and would like to teach, and to initiate inquiries and discussions that…

  1. Hard-Boiled for Hard Times in Leonardo Padura Fuentes's Detective Fiction

    ERIC Educational Resources Information Center

    Song, H. Rosi

    2009-01-01

    Focusing on Leonardo Padura Fuentes's hard-boiled fiction, this essay traces the origin and evolution of the genre in Cuba. Padura Fuentes has challenged the officially sanctioned socialist "literatura policial" that became popular in the 1970s and 1980s. creating a new model of criticism that is not afraid to confront the island's socio-economic…

  2. Observational Aspects of Hard X-ray Polarimetry

    NASA Astrophysics Data System (ADS)

    Chattopadhyay, Tanmoy

    2016-04-01

    of such hard X-ray telescopes, which may provide sensitive polarization measurements due to flux concentration in hard X-rays with a very low background. On the other hand, such a configuration ensures implementation of an optimized geometry close to an ideal one for the Compton polarimeters. In this context, we initiated the development of a focal plane Compton polarimeter, consisting of a plastic scatterer surrounded by a cylindrical array of CsI(Tl) scintillators. Geant-4 simulations of the planned configuration estimates 1% MDP for a 100 mCrab source in 1 million seconds of exposure. Sensitivity of the instrument is found to be critically dependent on the lower energy detection limit of the plastic scatterer; lower the threshold, better is the sensitivity. In the actual experiment, the plastic is readout by a photomultiplier tube procured from Saint-Gobain. We carried out extensive experiments to characterize the plastic especially for lower energy depositions. The CsI(Tl) scintillators are readout by Si photomultipliers (SiPM). SiPMs are small in size and robust and therefore provide the compactness necessary for the designing of focal plane detectors. Each of the CsI(Tl)-SiPM systems was characterized precisely to estimate their energy threshold and detection probability along the length of the scintillators away from SiPM. Finally, we integrated the Compton polarimeter and tested its response to polarized and unpolarized radiation and compared the experimental results with Geant-4 simulation. Despite the growing realization of the scientific values of X-ray polarimetry and the efforts in developing sensitive X-ray polarimeters, there has not been a single dedicated X-ray polarimetry mission planned in near future. In this scenario, it is equally important to attempt polarization measurements from the existing or planned instruments which are not meant for X-ray polarization measurements but could be sensitive to it. There have been several attempts in past in

  3. The gray-scale ink-jet printer: value in making hard copies of digital images.

    PubMed

    Combs, M J; Snell, J; Cail, W S; Maier, T; Buck, D A

    1995-01-01

    Referring physicians often are supplied with copies of images to illustrate a report of the findings of a radiologic study or so that the radiologist can retain the original images. The increasing costs of production, film, and recovery of chemicals have enhanced the requirement for a clean, low-cost dry printing process. An ink-jet gray-scale paper printer (Unitone, Scitex Medical Systems, Bedford, MA) can print high-quality (300 dots per inch [dpi]) images with an effective 10-bit gray scale range by using the Hertz continuous ink-jet method [1-3], which does not require the use of a darkroom or hazardous chemicals. Several types of media (matte paper, glossy paper, transparency film) with a printing area of 26.9 x 43.7 cm (10.6 x 17.4 inches) may be used. The consumables are approximately 50-70% less expensive than the cost of silver halide film, providing a cost advantage over film for referral and archival copies. The results of an initial evaluation of the ink-jet printer at our institution are reported here.

  4. An improved generalized Newton method for absolute value equations.

    PubMed

    Feng, Jingmei; Liu, Sanyang

    2016-01-01

    In this paper, we suggest and analyze an improved generalized Newton method for solving the NP-hard absolute value equations [Formula: see text] when the singular values of A exceed 1. We show that the global and local quadratic convergence of the proposed method. Numerical experiments show the efficiency of the method and the high accuracy of calculation. PMID:27462490

  5. Addendum to: Uniform Elongation and the Stress-Strain Flow Curve of Steels Calculated from Hardness Using Empirical Correlations

    NASA Astrophysics Data System (ADS)

    Pavlina, Erik J.; Van Tyne, Chester J.

    2015-11-01

    The original study by Pavlina and Van Tyne developed correlations of hardness and strength (yield and ultimate tensile strength) (Pavlina and Van Tyne in J Mater Eng Perform 17:888-893, 2008). As an extension to this original work, a later paper developed an empirical relationship between the hardness and uniform elongation of non-austenitic hypoeutectoid steels (Pavlina and Van Tyne in J Mater Eng Perform 23:2247-2254, 2014). The empirical hardness-elongation relationship was combined with the correlations in the original study to show how a single hardness test could predict a reasonable stress-strain flow curve for a steel. The current study provides tables of parameter values for four different hardening models, based on the hardness correlations that were developed in the two previous studies. The models are the two-parameter Holloman model and the three-parameter Ludwig, Swift, and Voce models. Although they are empirical, these parameters allow the flow behavior of steels to be reasonably well characterized, based on a single hardness value. These tables should only be used when limited material is available, or when insufficient data are available for the specific grade of steel needing characterization.

  6. Magnetic susceptibility and hardness of Au-xPt-yNb alloys for biomedical applications.

    PubMed

    Uyama, Emi; Inui, Shihoko; Hamada, Kenichi; Honda, Eiichi; Asaoka, Kenzo

    2013-09-01

    Metal devices in the human body induce serious metal artifacts in magnetic resonance imaging (MRI). Metals artifacts are mainly caused by a volume magnetic susceptibility (χv) mismatch between a metal device and human tissue. In this research, Au-xPt-yNb alloys were developed for fabricating MRI artifact-free biomedical metal devices. The magnetic properties, hardness and phase constitutions of these alloys were investigated. The Au-xPt-8Nb alloys showed satisfactory χv values. Heat treatments did not clearly change the χv values for Au-xPt-8Nb alloys. The Vickers hardness (HV) of these two alloys was much higher than that of high-Pt alloys; moreover, aging at 700°C increased the HV values of these two alloys. A dual phase structure consisting of face-centered cubic α1 and α2 phases was observed and aging at 700°C promoted phase separation. The Au-5Pt-8Nb and Au-10Pt-8Nb alloys showed satisfactory χv values and high hardness and are thus suggested as candidates for MRI artifact-free alloys for biomedical applications.

  7. GaN as a radiation hard particle detector

    NASA Astrophysics Data System (ADS)

    Grant, J.; Bates, R.; Cunningham, W.; Blue, A.; Melone, J.; McEwan, F.; Vaitkus, J.; Gaubas, E.; O'Shea, V.

    2007-06-01

    Semiconductor tracking detectors at experiments such as ATLAS and LHCb at the CERN Large Hadron Collider (LHC) will be subjected to intense levels of radiation. The proposed machine upgrade, the Super-LHC (SLHC), to 10 times the initial luminosity of the LHC will require detectors that are ultra-radiation hard. Much of the current research into finding a detector that will meet the requirements of the SLHC has focused on using silicon substrates with enhanced levels of oxygen, for example Czochralski silicon and diffusion oxygenated float zone silicon, and into novel detector structures such as 3D devices. Another avenue currently being investigated is the use of wide band gap semiconductors such as silicon carbide (SiC) and gallium nitride (GaN). Both SiC and GaN should be intrinsically more radiation hard than silicon. Pad and guard ring structures were fabricated on three epitaxial GaN wafers. The epitaxial GaN thickness was either 2.5 or 12 μm and the fabricated detectors were irradiated to various fluences with 24 GeV/c protons and 1 MeV neutrons. Detectors were characterised pre- and post-irradiation by performing current-voltage ( I- V) and charge collection efficiency (CCE) measurements. Devices fabricated on 12 μm epitaxial GaN irradiated to fluences of 1016 protons cm-2 and 1016 neutrons cm-2 show maximum CCE values of 26% and 20%, respectively, compared to a maximum CCE of 53% of the unirradiated device.

  8. Implementing QML (Qualified Manufacturers List) for radiation hardness assurance

    SciTech Connect

    Winokur, P.S.; Sexton, F.W.; Fleetwood, D.M.; Terry, M.D.; Shaneyfelt, M.R.; Dressendorfer, P.V.; Schwank, J.R.

    1990-01-01

    Statistical process control (SPC) of technology parameters relevant to radiation hardness, test structure to Integrated Circuit (IC) correlation, and extrapolation from laboratory to threat scenarios are keys to implementing Qualified Manufacture's List (QML) for radiation hardness assurance in a cost-effective manner. Data from approximately 300 wafer lots fabricated in Sandia's 4/3-{mu}m and Complementry Metal Oxide Semiconductor (CMOS) IIIA (2-{mu}m) technologies are used to demonstrate approaches to, and highlight issues associated with, implementing QML for radiation-hardened CMOS in space applications. An approach is demonstrated to implement QML for signal-event upset SEU immunity on 16k SRAMs that involves relating values of feedback resistance to system error rates. It is seen that the process capability indices, C{sub p} and C{sub pk}, for the manufacture of 400 k{Omega} feedback resistors required to provide SEU tolerance do not conform to 6{sigma}'' quality standards. For total-dose, {triangle}V{sub it} shifts measured on transistors are correlated with circuit response in the space environment. SPC is illustrated for {triangle}V{sub it}, and violations of SPC rules are interpreted in terms of continuous improvement. Finally, design validation for SEU, and quality conformance inspections for total-dose, are identified as major obstacles to cost-effective QML implementation. Techniques and tools that will help QML provide real cost savings are identified as physical models, three-dimensional device-plus-circuit codes, and improved design simulators. 29 refs., 10 figs., 1 tab.

  9. Ab initio study on structural, electronic properties, and hardness of re-doped W2B5

    NASA Astrophysics Data System (ADS)

    Feng, ShiQuan; Li, XiaoDong; Su, Lei; Li, HaiNing; Yang, Hongyan; Cheng, Xinlu

    2016-11-01

    Using first principle calculations method, we calculated the structural stability, electronic properties and hardness for three Re-doped hexagonal W2B5 compounds. The electronic properties were carried out to discuss the effect of doped Re on the conductivity, chemical bonding components and orbital hybridization of W2B5. What is more, the hardness of these three doped crystals was calculated by a semiempirical method considering the role of metallic components. A Re-doped W2B5 compound with a greater hardness value than that of pure W2B5 was obtained. And the effect of doping on the hardness of hexagonal W2B5was discussed.

  10. CONDENSED MATTER: STRUCTURE, MECHANICAL AND THERMAL PROPERTIES: Crystal Structure and High Hardness Mechanism of Orthorhomic Si2N2O

    NASA Astrophysics Data System (ADS)

    Xiong, Lan-Tian; Cao, Mao-Sheng; Hou, Zhi-Ling

    2009-07-01

    A quasi-single-phase orthorombic Si2N2O compound is obtained by hot-pressing sintering using homogeneous precursors as raw materials under nitrogen atmosphere. The bulk hardness of orthorombic Si2N2O (o-Si2N2O) is investigated by a nanoindenter experiment; the results show that o-Si2N2O with maximal value about 19GPa has a high hardness covalent crystal besides β-Si3N4. It is discovered that the high hardness is mainly attributed to the unique crystal structure. The bridging O atoms in the o-Si2N2O are responsible for decreasing hardness. It is found that the Si-O bonds in the open tetrahedral crystal structure are more easily broken and tilted than other bonds.

  11. Tetraphosphonated thiophene ligand: mixing the soft and the hard.

    PubMed

    Brandel, Jérémy; Lecointre, Alexandre; Kollek, Julien; Michel, Sylvia; Hubscher-Bruder, Véronique; Déchamps-Olivier, Isabelle; Platas-Iglesias, Carlos; Charbonnière, Loïc J

    2014-06-28

    The synthesis of ligand L(T)H8, based on a thiophene framework containing two bis(aminomethyldiphosphonate) functions in the ortho position to the central sulfur atom, is described, together with the characterization of the intermediate compounds. The physico-chemical properties of the ligand were first studied by means of potentiometry and UV-Vis absorption spectrophotometric titrations to determine its pK values. Six successive equilibrium constants were determined in aqueous solutions. The same means were then used to quantify the interactions of the ligand with Ni(II), Cu(II) and Zn(II). Following the conventional Irving-Williams trend, L(T) was shown to have the highest affinity towards Cu(II) (log K(CuL(T)) = 16.11(3)), while Zn(II) and Ni(II) showed similar values (log K(ML(T)) = 10.81(8) and 10.9(1), respectively), revealing a large selectivity of L(T) toward Cu(II). Based on a combination of UV-Vis absorption spectroscopy and EPR measurements as a function of pH, along with DFT calculations, the coordination behavior of the hard phosphonate, medium amino and soft thiophene entities are questioned regarding their coordination to the Cu atom.

  12. Fluid-solid transition in hard hypersphere systems.

    PubMed

    Estrada, C D; Robles, M

    2011-01-28

    In this work we present a numerical study, based on molecular dynamics simulations, to estimate the freezing point of hard spheres and hypersphere systems in dimension D = 4, 5, 6, and 7. We have studied the changes of the radial distribution function (RDF) as a function of density in the coexistence region. We started our simulations from crystalline states with densities above the melting point, and moved down to densities in the liquid state below the freezing point. For all the examined dimensions (including D = 3), it was observed that the height of the first minimum of the RDF changes in an almost continuous way around the freezing density and resembles a second order phase transition. With these results we propose a numerical method to estimate the freezing point as a function of the dimension D using numerical fits and semiempirical approaches. We find that the estimated values of the freezing point are very close to the previously reported values from simulations and theoretical approaches up to D = 6, reinforcing the validity of the proposed method. This was also applied to numerical simulations for D = 7 giving new estimations of the freezing point for this dimensionality.

  13. Hard implant coatings with antimicrobial properties.

    PubMed

    Moseke, Claus; Gbureck, Uwe; Elter, Patrick; Drechsler, Peter; Zoll, Andreas; Thull, Roger; Ewald, Andrea

    2011-12-01

    Infection of orthopaedic implants often leads to inflammation immediately after surgery and increases patient morbidity due to repetitive operations. Silver ions have been shown to combine good biocompatibility with a low risk of inducing bacterial resistance. In this study a physical vapour deposition system using both arc deposition and magnetron sputtering has been utilized to produce silver ion doped TiN coatings on Ti substrates. This biphasic system combines the advantages of silver induced bactericidity with the good mechanical properties of TiN. Crystallographic analysis by X-ray diffraction showed that silver was deposited as well in its elementary form as it was incorporated into the crystal lattice of TiN, which resulted in increasing hardness of the TiN-coatings. Elution experiments revealed a continuous release of Ag ions in phosphate buffered saline. The coatings showed significant inhibitory effects on the growth of Staphylococcus epidermidis and Staphylococcus aureus and practically no cell-toxicity in cytocompatibility tests.

  14. Hard turning micro-machine tool

    DOEpatents

    DeVor, Richard E; Adair, Kurt; Kapoor, Shiv G

    2013-10-22

    A micro-scale apparatus for supporting a tool for hard turning comprises a base, a pivot coupled to the base, an actuator coupled to the base, and at least one member coupled to the actuator at one end and rotatably coupled to the pivot at another end. A tool mount is disposed on the at least one member. The at least one member defines a first lever arm between the pivot and the tool mount, and a second lever arm between the pivot and the actuator. The first lever arm has a length that is less than a length of the second lever arm. The actuator moves the tool mount along an arc.

  15. Peripheral osteoma of the hard palate

    PubMed Central

    Prabhuji, M. L. V.; Kishore, H. C.; Sethna, Gulnar; Moghe, Ameya G.

    2012-01-01

    Osteomas are benign slow growing, osteogenic lesions which may arise from proliferation of either cancellous or compact bone. They are usually sessile tumours composed of dense sclerotic, well formed bone projecting out from the cortical surface, most often of the skull and facial bones. This paper reports a case of a peripheral osteoma in the hard palate of a 45-year-old man, which was treated by periodontal flap surgery with surgical excision of the bony lesion. Peripheral osteomas of jaw bone are uncommon and usually associated with Gardner's syndrome. Histological examination confirmed the clinical impression of a peripheral osteoma. Patient was reviewed after one year and was asymptomatic with no recurrence of the lesion. PMID:22628981

  16. Nanomechanics of hard films on compliant substrates.

    SciTech Connect

    Reedy, Earl David, Jr.; Emerson, John Allen; Bahr, David F.; Moody, Neville Reid; Zhou, Xiao Wang; Hales, Lucas; Adams, David Price; Yeager,John; Nyugen, Thao D.; Corona, Edmundo; Kennedy, Marian S.; Cordill, Megan J.

    2009-09-01

    a result, our understanding of the critical relationship between adhesion, properties, and fracture for hard films on compliant substrates is limited. To address this issue, we integrated nanomechanical testing and mechanics-based modeling in a program to define the critical relationship between deformation and fracture of nanoscale films on compliant substrates. The approach involved designing model film systems and employing nano-scale experimental characterization techniques to isolate effects of compliance, viscoelasticity, and plasticity on deformation and fracture of thin hard films on substrates that spanned more than two orders of compliance magnitude exhibit different interface structures, have different adhesion strengths, and function differently under stress. The results of this work are described in six chapters. Chapter 1 provides the motivation for this work. Chapter 2 presents experimental results covering film system design, sample preparation, indentation response, and fracture including discussion on the effects of substrate compliance on fracture energies and buckle formation from existing models. Chapter 3 describes the use of analytical and finite element simulations to define the role of substrate compliance and film geometry on the indentation response of thin hard films on compliant substrates. Chapter 4 describes the development and application of cohesive zone model based finite element simulations to determine how substrate compliance affects debond growth. Chapter 5 describes the use of molecular dynamics simulations to define the effects of substrate compliance on interfacial fracture of thin hard tungsten films on silicon substrates. Chapter 6 describes the Workshops sponsored through this program to advance understanding of material and system behavior.

  17. Radiation Hardness Assurance (RHA) for Space Systems

    NASA Technical Reports Server (NTRS)

    Poivey, Christian; Buchner, Stephen

    2007-01-01

    This presentation discusses radiation hardness assurance (RHA) for space systems, providing both the programmatic aspects of RHA and the RHA procedure. RHA consists of all activities undertaken to ensure that the electronics and materials of a space system perform to their design specifications after exposure to the space radiation environment. RHA also pertains to environment definition, part selection, part testing, spacecraft layout, radiation tolerant design, and mission/system/subsystems requirements. RHA procedure consists of establishing mission requirements, defining and evaluating the radiation hazard, selecting and categorizing the appropriate parts, and evaluating circuit response to hazard. The RHA approach is based on risk management and is confined only to parts, it includes spacecraft layout, system/subsystem/circuit design, and system requirements and system operations. RHA should be taken into account in the early phases of a program including the proposal and feasibility analysis phases.

  18. Aging dynamics of colloidal hard sphere glasses.

    PubMed

    Martinez, V A; Bryant, G; van Megen, W

    2010-09-21

    We report the results of dynamic light scattering measurements of the coherent intermediate scattering function (ISF) of glasses of colloidal hard spheres for several volume fractions and a range of scattering vectors around the primary peak of the static structure factor. The ISF shows a clear crossover from an initial fast decay to a slower nonstationary decay. Aging is quantified in several different ways. However, regardless of the method chosen, the perfect "aged" glass is approached in a power law fashion. In particular the coupling between the fast and slow decays, as measured by the degree of stretching of the ISF at the crossover, also decreases algebraically with waiting time. The nonstationarity of this coupling implies that even the fastest detectable processes are themselves nonstationary. PMID:20866156

  19. Using Cell Phone Keyboards Is (NP) Hard

    NASA Astrophysics Data System (ADS)

    Boothe, Peter

    Sending text messages on cell phones which only contain the keys 0 through 9 and # and * can be a painful experience. We consider the problem of designing an optimal mapping of numbers to sets of letters to act as an alternative to the standard {2→{abc}, 3→{def}...}. Our overall goal is to minimize the expected number of buttons that must be pressed to enter a message in English. Some variations of the problem are efficiently solvable, either by being small instances or by being in P, but the most realistic version of the problem is NP hard. To prove NP-completeness, we describe a new graph coloring problem UniquePathColoring. We also provide numerical results for the English language on a standard corpus which describe several mappings that improve upon the standard one. With luck, one of these new mappings will achieve success similar to that of the Dvorak layout for computer keyboards.

  20. Shock compression synthesis of hard materials

    SciTech Connect

    Willson, C.G.

    1999-03-01

    The purpose of this research was to adapt the high explosives technology that was developed in conjunction with nuclear weapons programs to subjecting materials to ultra-high pressures and to explore the utility of this technique for the synthesis of hard materials. The research was conducted in collaboration with researchers at the University of Texas, Texas Tech University and Pantex (Mason and Hanger Corp.). The group designed, modeled, built, and tested a new device that allows quantitative recovery of grams of material that have been subjected to unprecedented pressures. The modeling work was done at Texas Tech and Pantex. The metal parts and material samples were made at the University of Texas, and Pantex machined the explosives, assembled the devices and conducted the detonations. Sample characterization was carried out at the University of Texas and Texas Tech.

  1. Coendangered hard-ticks: threatened or threatening?

    PubMed

    Mihalca, Andrei Daniel; Gherman, Călin Mircea; Cozma, Vasile

    2011-01-01

    The overwhelming majority of animal conservation projects are focused on vertebrates, despite most of the species on Earth being invertebrates. Estimates state that about half of all named species of invertebrates are parasitic in at least one stage of their development. The dilemma of viewing parasites as biodiversity or pest has been discussed by several authors. However, ticks were omitted. The latest taxonomic synopses of non-fossil Ixodidae consider valid 700 species. Though, how many of them are still extant is almost impossible to tell, as many of them are known only from type specimens in museums and were never collected since their original description. Moreover, many hosts are endangered and as part of conservation efforts of threatened vertebrates, a common practice is the removal of, and treatment for external parasites, with devastating impact on tick populations. There are several known cases when the host became extinct with subsequent coextinction of their ectoparasites. For our synoptic approach we have used the IUCN status of the host in order to evaluate the status of specifically associated hard-ticks. As a result, we propose a number of 63 coendangered and one extinct hard-tick species. On the other side of the coin, the most important issue regarding tick-host associations is vectorial transmission of microbial pathogens (i.e. viruses, bacteria, protozoans). Tick-borne diseases of threatened vertebrates are sometimes fatal to their hosts. Mortality associated with pathogens acquired from ticks has been documented in several cases, mostly after translocations. Are ticks a real threat to their coendangered host and should they be eliminated? Up to date, there are no reliable proofs that ticks listed by us as coendangered are competent vectors for pathogens of endangered animals. PMID:21554736

  2. The hard side of change management.

    PubMed

    Sirkin, Harold L; Keenan, Perry; Jackson, Alan

    2005-10-01

    Everyone agrees that managing change is tough, but few can agree on how to do it. Most experts are obsessed with "soft" issues, such as culture and motivation, but, say the authors, focusing on these issues alone won't bring about change. Companies also need to consider the hard factors-like the time it takes to complete a change initiative, the number of people required to execute it, and so forth. When the authors studied change initiatives at 225 companies, they found a consistent correlation between the outcomes of change programs (success versus failure) and four hard factors, which they called DICE: project duration, particularly the time between project reviews; integrity of performance, or the capabilities of project teams; the level of commitment of senior executives and staff; and the additional effort required of employees directly affected by the change. The DICE framework is a simple formula for calculating how well a company is implementing, or will be able to implement, its change initiatives. The framework comprises a set of simple questions that help executives score their projects on each of the four factors; the lower the score, the more likely the project will succeed. Companies can use DICE assessments to force conversations a bout projects, to gauge whether projects are on track or in trouble, and to manage project portfolios. The authors have used these four factors to predict the outcomes and guide the execution of more than 1,000 change management programs worldwide. Not only has the correlation held, but no other factors (or combination of factors) have predicted outcomes as successfully.

  3. A multi-step system for screening and localization of hard exudates in retinal images

    NASA Astrophysics Data System (ADS)

    Bopardikar, Ajit S.; Bhola, Vishal; Raghavendra, B. S.; Narayanan, Rangavittal

    2012-03-01

    The number of people being affected by Diabetes mellitus worldwide is increasing at an alarming rate. Monitoring of the diabetic condition and its effects on the human body are therefore of great importance. Of particular interest is diabetic retinopathy (DR) which is a result of prolonged, unchecked diabetes and affects the visual system. DR is a leading cause of blindness throughout the world. At any point of time 25 - 44% of people with diabetes are afflicted by DR. Automation of the screening and monitoring process for DR is therefore essential for efficient utilization of healthcare resources and optimizing treatment of the affected individuals. Such automation would use retinal images and detect the presence of specific artifacts such as hard exudates, hemorrhages and soft exudates (that may appear in the image) to gauge the severity of DR. In this paper, we focus on the detection of hard exudates. We propose a two step system that consists of a screening step that classifies retinal images as normal or abnormal based on the presence of hard exudates and a detection stage that localizes these artifacts in an abnormal retinal image. The proposed screening step automatically detects the presence of hard exudates with a high sensitivity and positive predictive value (PPV ). The detection/localization step uses a k-means based clustering approach to localize hard exudates in the retinal image. Suitable feature vectors are chosen based on their ability to isolate hard exudates while minimizing false detections. The algorithm was tested on a benchmark dataset (DIARETDB1) and was seen to provide a superior performance compared to existing methods. The two-step process described in this paper can be embedded in a tele-ophthalmology system to aid with speedy detection and diagnosis of the severity of DR.

  4. Chemical-potential route: a hidden Percus-Yevick equation of state for hard spheres.

    PubMed

    Santos, Andrés

    2012-09-21

    The chemical potential of a hard-sphere fluid can be expressed in terms of the contact value of the radial distribution function of a solute particle with a diameter varying from zero to that of the solvent particles. Exploiting the explicit knowledge of such a contact value within the Percus-Yevick theory, and using standard thermodynamic relations, a hitherto unknown Percus-Yevick equation of state, p/ρk(B)T = -(9/η) ln(1-η)-(16-31η)/2(1-η)(2), is unveiled. This equation of state turns out to be better than the one obtained from the conventional virial route. Interpolations between the chemical-potential and compressibility routes are shown to be more accurate than the widely used Carnahan-Starling equation of state. The extension to polydisperse hard-sphere systems is also presented.

  5. Factorization and non-factorization in diffractive hard scattering

    SciTech Connect

    Berera, Arjun

    1997-04-20

    Factorization, in the sense defined for inclusive hard scattering, is discussed for diffractive hard scattering. A factorization theorem similar to its inclusive counterpart is presented for diffractive DIS. For hadron-hadron diffractive hard scattering, in contrast to its inclusive counterpart, the expected breakdown of factorization is discussed. Cross section estimates are given from a simple field theory model for non-factorizing double-pomeron-exchange (DPE) dijet production with and without account for Sudakov suppression.

  6. Radiation Hard AlGaN Detectors and Imager

    SciTech Connect

    2012-05-01

    Radiation hardness of AlGaN photodiodes was tested using a 65 MeV proton beam with a total proton fluence of 3x10{sup 12} protons/cm{sup 2}. AlGaN Deep UV Photodiode have extremely high radiation hardness. These new devices have mission critical applications in high energy density physics (HEDP) and space explorations. These new devices satisfy radiation hardness requirements by NIF. NSTec is developing next generation AlGaN optoelectronics and imagers.

  7. Estimating aquifer properties and distributed groundwater recharge in a hard-rock catchment of Udaipur, India

    NASA Astrophysics Data System (ADS)

    Machiwal, Deepesh; Singh, P. K.; Yadav, K. K.

    2016-09-01

    The present study determined aquifer parameters in hard-rock aquifer system of Ahar River catchment, Udaipur, India by conducting 19 pumping tests in large-diameter wells. Spreadsheet programs were developed for analyzing pumping test data, and their accuracy was evaluated by root mean square error (RMSE) and correlation coefficient (R). Histograms and Shapiro-Wilk test indicated non-normality (p value <0.01) of pre- and post-monsoon groundwater levels at 50 sites for years 2006-2008, and hence, logarithmic transformations were done. Furthermore, recharge was estimated using GIS-based water table fluctuation method. The groundwater levels were found to be influenced by the topography, presence of structural hills, density of pumping wells, and seasonal recharge. The results of the pumping tests revealed that the transmissivity (T) ranges from 68-2239 m2/day, and the specific yield (S y) varies from 0.211 to 0.51 × 10-5. The T and S y values were found reasonable for the hard-rock formations in the area, and the spreadsheet programs were found reliable (RMSE ~0.017-0.339 m; R > 0.95). Distribution of the aquifer parameters and recharge indicated that the northern portion with high ground elevations (575-700 m MSL), and high S y (0.08-0.25) and T (>600 m2/day) values may act as recharge zone. The T and S y values revealed significant spatial variability, which suggests strong heterogeneity of the hard-rock aquifer system. Overall, the findings of this study are useful to formulate appropriate strategies for managing water resources in the area. Also, the developed spreadsheet programs may be used to analyze the pumping test data of large-diameter wells in other hard-rock regions of the world.

  8. New closed virial equation of state for hard-sphere fluids.

    PubMed

    Tian, Jianxiang; Gui, Yuanxing; Mulero, Angel

    2010-10-28

    A new closed virial equation of state of hard-sphere fluids is proposed which reproduces the calculated or estimated values of the first 16 virial coefficients and at the same time gives very good accuracy when compared with computer simulation data for the compressibility factor over the entire fluid range, as well as having a pole at the correct closest packing density. PMID:20883000

  9. Friction and the development of hard alloy surface microstructures during wear

    NASA Astrophysics Data System (ADS)

    Gnyusov, S. F.; Tarassov, S. Yu.

    1997-12-01

    Investigations of wear in sliding friction of WC-Hadfield steel hard alloy against cast tool steel have been carried out in a broad range of velocities and pressure values. Structural and phase composition variations have been revealed. Friction-affected zone was found to be 450 µm in depth. Structural γ → α, γ → transformation regions are located within 100 μm of the surface. These transformations contributed to the total solid solution deformation hardening.

  10. Influence of mouth rinses on the surface hardness of dental resin nano-composite

    PubMed Central

    Khan, Aftab Ahmed; Siddiqui, Adel Zia; Mohsin, Syed Fareed; Al-Kheraif, Abdulaziz A.

    2015-01-01

    Objective: The aim of this research was to assess the effect of mouth rinses with and without alcohol on the hardness of dental nano-filled composite. Methods: The micro-hardness of fifty circular disk shaped specimens of 7 mm x 2 mm were measured after 14 days. Specimens were immersed into alcohol containing (Listerine and Colgate Perioguard) and alcohol-free (Prodent and Sensodyne Oral antiseptic) mouth rinse solutions. Artificial saliva served as the control. Vickers Micro-hardness was measured with a 30gram load for 30 seconds dwell time by using a diamond indenter. Significant differences were represented by p<0.05, whereas highly significant difference represented by p<0.01. The level of significance (p) was calculated with the help of repeated measure ANOVA. For multiple comparisons, Tukey’s multiple comparison test was used. Results: Statistical analysis revealed highly significant difference between specimens immersed in artificial saliva (control) and Listerine (p<0.01). Whereas significant difference were observed between control and Colgate Periogard (p<0.05). However, no significant difference was observed on comparing Prodent and Sensodyne Oral antiseptic mouth rinses with control group(p>0.05). Control specimens depicted highest value of micro-hardness(60.5746 ± 3.2703) compared to the lowest value seen in specimens immersed in Listerine solvent(54.4687 ± 1.0937). Conclusion: Alcohol containing mouth rinsing solutions have more deleterious effect on hardness of nano composites as compared to alcohol-free mouth rinses. PMID:26870121

  11. Hard and soft acids and bases: structure and process.

    PubMed

    Reed, James L

    2012-07-01

    Under investigation is the structure and process that gives rise to hard-soft behavior in simple anionic atomic bases. That for simple atomic bases the chemical hardness is expected to be the only extrinsic component of acid-base strength, has been substantiated in the current study. A thermochemically based operational scale of chemical hardness was used to identify the structure within anionic atomic bases that is responsible for chemical hardness. The base's responding electrons have been identified as the structure, and the relaxation that occurs during charge transfer has been identified as the process giving rise to hard-soft behavior. This is in contrast the commonly accepted explanations that attribute hard-soft behavior to varying degrees of electrostatic and covalent contributions to the acid-base interaction. The ability of the atomic ion's responding electrons to cause hard-soft behavior has been assessed by examining the correlation of the estimated relaxation energies of the responding electrons with the operational chemical hardness. It has been demonstrated that the responding electrons are able to give rise to hard-soft behavior in simple anionic bases.

  12. Mapping a hard-sphere fluid mixture onto a single component hard-sphere fluid

    NASA Astrophysics Data System (ADS)

    Barrio, C.; Solana, J. R.

    2005-06-01

    The possibility of obtaining the thermodynamic and structural properties of a binary additive hard-sphere fluid mixture on the basis of the corresponding properties of a suitable single-component hard-sphere fluid is analyzed. To this end, Monte Carlo simulations have been performed for binary mixtures of hard spheres for different densities, compositions and diameter ratios in order to obtain the compressibility factor Z and the partial radial distribution functions gij(r) for pairs ij of the mixtures. These data are used to test the reliability of different proposals available in the literature for mapping the thermodynamic and structural properties of conformal mixtures onto those of a single-component fluid. It is found that, while the averaged radial distribution function and the equation of state of the mixture can be reasonably well reproduced by means of those of an equivalent single-component fluid, the partial radial distribution functions cannot be obtained with enough accuracy from the radial distribution function of the equivalent fluid. A possible explanation for this fact is suggested.

  13. Peroxide interactions with hard tissues: effects on surface hardness and surface/subsurface ultrastructural properties.

    PubMed

    White, Donald J; Kozak, Kathy M; Zoladz, James R; Duschner, Heinz; Götz, Hermann

    2002-01-01

    Laboratory studies were performed to assess the impact of peroxide bleaching on enamel surface and subsurface physical and ultrastructural properties. Human enamel blocks were prepared, polished, and measured for native color. Cyclic bleaching treatments were carried out with soaks in whole stimulated saliva interspersed with bleaching treatments using bulk bleaching gels from commercial bleaching systems including Opalescence (20% and 10% carbamide peroxide systems) and Crest Whitestrips, a hydrogen peroxide gel formula, at doses of 5.3% and 6.5% hydrogen peroxide. Treatments ranged from conditions of normal use (14 hours as recommended for Crest Whitestrips) to excessive bleaching (70 hours). Controls included nontreated as well as treatments with placebo (not containing peroxide) gels. Surface hardness and confocal laser scanning microscopy (CLSM) techniques were used to characterize the effects of bleaching on the physical properties and ultrastructure of the teeth. Tooth color measurements revealed dose-response bleaching in vitro with the increases in L* and decreases in b* normally expected with effective bleaching. Placebo control treatments did not bleach. Surface hardness measurements showed no decreases associated with tooth bleaching. CLSM measurements also showed no effects from tooth bleaches on the surface or subsurface prism architecture of enamel. This was opposed to significant changes seen with even moderate levels of demineralization associated with the caries process. These studies support: (1) the safety of Crest Whitestrips formulas for enamel surfaces and tooth subsurfaces; and (2) the generic safety of peroxide bleaching of hard tissues associated with conditions of both recommended use and overuse.

  14. Comparison of structure and transport properties of concentrated hard and soft sphere fluids.

    PubMed

    Lange, Erik; Caballero, Jose B; Puertas, Antonio M; Fuchs, Matthias

    2009-05-01

    Using Newtonian and Brownian dynamics simulations, the structural and transport properties of hard and soft spheres have been studied. The soft spheres were modeled using inverse power potentials (V approximately r(-n), with 1n the potential softness). Although, at constant density, the pressure, diffusion coefficient, and viscosity depend on the particle softness up to extremely high values of n, we show that scaling the density with the freezing point for every system effectively collapses these parameters for n > or = 18 (including hard spheres) for large densities. At the freezing points, the long range structure of all systems is identical, when length is measured in units of the interparticle distance, but differences appear at short distances (due to the different shapes of the interaction potential). This translates into differences at short times in the velocity and stress autocorrelation functions, although they concur to give the same value of the corresponding transport coefficient (for the same density to freezing ratio); the microscopic dynamics also affects the short time behavior of the correlation functions and absolute values of the transport coefficients, but the same scaling with the freezing density works for Newtonian or Brownian dynamics. For hard spheres, the short time behavior of the stress autocorrelation function has been studied in detail, confirming quantitatively the theoretical forms derived for it.

  15. Effect of Annealing Temperature on Hardness and Wear Resistance of Electroless Ni-B-Mo Coatings

    NASA Astrophysics Data System (ADS)

    Serin, Ihsan Gökhan; Göksenli, Ali

    2015-06-01

    Formation of nickel-boron-molybdenum (Ni-B-Mo) coating on steel by electroless plating and evaluation of their morphology, hardness and tribological properties post heat treatment at different temperatures for 1 h is investigated. The 25 μm thick coating is uniform and adhesion between the substrate and coating is good. Ni-B-Mo coating was amorphous-like structure in their as-plated condition and by 400°C heat-treated coating, nickel fully crystallized and nickel borides and molybdenum carbide were formed. All coatings exhibited higher hardness than the substrate steel. Hardness values of all coatings up to 400°C did not change distinctively but decreased partly beyond 400°C. Friction coefficient reached lowest value post heat treatment at 300°C but later increased with increasing tempering temperature. Wear resistance was lowest in as-plated coating; however it reached the highest value at 300°C. Worn surface of the coatings showed the abrasive wear as the dominant wear mechanism. An additional adhesive wear mechanism was detected in coating tempered at 550°C. Moreover, our results confirmed that the molybdenum addition improved the thermal stability of the resulting coating. Therefore, Ni-B-Mo coating has potential for application in precision mould, optical parts mould or bipolar plates, where thermal stability is essential.

  16. Annealing of Co-Cr dental alloy: effects on nanostructure and Rockwell hardness

    PubMed Central

    Soylu, Elif Hilal; İde, Semra; Kılıç, Selim; Sipahi, Cumhur; Pişkin, Bulent; Gökçe, Hasan Suat

    2013-01-01

    PURPOSE The aim of the study was to evaluate the effect of annealing on the nanostructure and hardness of Co-Cr metal ceramic samples that were fabricated with a direct metal laser sintering (DMLS) technique. MATERIALS AND METHODS Five groups of Co-Cr dental alloy samples were manufactured in a rectangular form measuring 4 × 2 × 2 mm. Samples fabricated by a conventional casting technique (Group I) and prefabricated milling blanks (Group II) were examined as conventional technique groups. The DMLS samples were randomly divided into three groups as not annealed (Group III), annealed in argon atmosphere (Group IV), or annealed in oxygen atmosphere (Group V). The nanostructure was examined with the small-angle X-ray scattering method. The Rockwell hardness test was used to measure the hardness changes in each group, and the means and standard deviations were statistically analyzed by one-way ANOVA for comparison of continuous variables and Tukey's HSD test was used for post hoc analysis. P values of <.05 were accepted as statistically significant. RESULTS The general nanostructures of the samples were composed of small spherical entities stacked atop one another in dendritic form. All groups also displayed different hardness values depending on the manufacturing technique. The annealing procedure and environment directly affected both the nanostructure and hardness of the Co-Cr alloy. Group III exhibited a non-homogeneous structure and increased hardness (48.16 ± 3.02 HRC) because the annealing process was incomplete and the inner stress was not relieved. Annealing in argon atmosphere of Group IV not only relieved the inner stresses but also decreased the hardness (27.40 ± 3.98 HRC). The results of fitting function presented that Group IV was the most homogeneous product as the minimum bilayer thickness was measured (7.11 Å). CONCLUSION After the manufacturing with DMLS technique, annealing in argon atmosphere is an essential process for Co-Cr metal ceramic

  17. Comparison Between Neck and Shoulder Stiffness Determined by Shear Wave Ultrasound Elastography and a Muscle Hardness Meter.

    PubMed

    Akagi, Ryota; Kusama, Saki

    2015-08-01

    The goals of this study were to compare neck and shoulder stiffness values determined by shear wave ultrasound elastography with those obtained with a muscle hardness meter and to verify the correspondence between objective and subjective stiffness in the neck and shoulder. Twenty-four young men and women participated in the study. Their neck and shoulder stiffness was determined at six sites. Before the start of the measurements, patients rated their present subjective symptoms of neck and shoulder stiffness on a 6-point verbal scale. At all measurement sites, the correlation coefficients between the values of muscle hardness indices determined by the muscle hardness meter and shear wave ultrasound elastography were not significant. Furthermore, individuals' subjective neck and shoulder stiffness did not correspond to their objective symptoms. These results suggest that the use of shear wave ultrasound elastography is essential to more precisely assess neck and shoulder stiffness.

  18. Impact and hardness optimisation of composite materials inspired by the babassu nut (Orbignya speciosa).

    PubMed

    Staufenberg, Gerrit; Graupner, Nina; Müssig, Jörg

    2015-10-01

    The babassu nut is the fruit of the babassu palm Orbignya speciosa. The combination of hardness and impact strength is difficult to acquire for artificial materials, making the babassu nut a promising source for biomimetic inspiration. Unnotched Charpy impact tests, Shore D hardness tests and scanning electron microscopy were used for mechanical and microscopical analysis of the pericarp. Four major principles were found for a biomimetic approach: a hard core ((1); endocarp) is embedded in a soft outer layer of high impact strength ((2); epicarp) and is reinforced with fibres of variable fineness (3), some of which are oriented radial to the core (4). Biomimetic fibre-reinforced composites were produced using abstracted mechanisms of the babassu nut based on regenerated cellulose fibres (lyocell, L) with two different fineness values as reinforcement embedded in a polylactide (PLA) core matrix and polypropylene (PP) based outer layers. The biomimetic fibre composite reaches a significantly higher impact strength that is 1.6 times higher than the reference sample produced from a PLA/PP/L-blend. At the same time the hardness is slightly increased compared to PP/L. PMID:26291183

  19. Impact and hardness optimisation of composite materials inspired by the babassu nut (Orbignya speciosa).

    PubMed

    Staufenberg, Gerrit; Graupner, Nina; Müssig, Jörg

    2015-08-20

    The babassu nut is the fruit of the babassu palm Orbignya speciosa. The combination of hardness and impact strength is difficult to acquire for artificial materials, making the babassu nut a promising source for biomimetic inspiration. Unnotched Charpy impact tests, Shore D hardness tests and scanning electron microscopy were used for mechanical and microscopical analysis of the pericarp. Four major principles were found for a biomimetic approach: a hard core ((1); endocarp) is embedded in a soft outer layer of high impact strength ((2); epicarp) and is reinforced with fibres of variable fineness (3), some of which are oriented radial to the core (4). Biomimetic fibre-reinforced composites were produced using abstracted mechanisms of the babassu nut based on regenerated cellulose fibres (lyocell, L) with two different fineness values as reinforcement embedded in a polylactide (PLA) core matrix and polypropylene (PP) based outer layers. The biomimetic fibre composite reaches a significantly higher impact strength that is 1.6 times higher than the reference sample produced from a PLA/PP/L-blend. At the same time the hardness is slightly increased compared to PP/L.

  20. The Influence of Wheel/Rail Contact Conditions on the Microstructure and Hardness of Railway Wheels

    PubMed Central

    Davis, Claire

    2014-01-01

    The susceptibility of railway wheels to wear and rolling contact fatigue damage is influenced by the properties of the wheel material. These are influenced by the steel composition, wheel manufacturing process, and thermal and mechanical loading during operation. The in-service properties therefore vary with depth below the surface and with position across the wheel tread. This paper discusses the stress history at the wheel/rail contact (derived from dynamic simulations) and observed variations in hardness and microstructure. It is shown that the hardness of an “in-service” wheel rim varies significantly, with three distinct effects. The underlying hardness trend with depth can be related to microstructural changes during manufacturing (proeutectoid ferrite fraction and pearlite lamellae spacing). The near-surface layer exhibits plastic flow and microstructural shear, especially in regions which experience high tangential forces when curving, with consequentially higher hardness values. Between 1 mm and 7 mm depth, the wheel/rail contacts cause stresses exceeding the material yield stress, leading to work hardening, without a macroscopic change in microstructure. These changes in material properties through the depth of the wheel rim would tend to increase the likelihood of crack initiation on wheels toward the end of their life. This correlates with observations from several train fleets. PMID:24526883

  1. Mechanical properties, anisotropy and hardness of group IVA ternary spinel nitrides

    NASA Astrophysics Data System (ADS)

    Ding, Ying-Chun; Chen, Min

    2013-10-01

    In this work, new ternary cubic spinel structures are designed by the substitutional method. The structures, elasticity properties, intrinsic hardness and Debye temperature of the cubic ternary spinel nitrides are studied by first principles based on the density-functional theory. The results show that γ-CSn2N4, γ-SiC2N4, γ-GeC2N4 and γ-SnC2N4 are not mechanically stable. The elastic constants Cij of these cubic spinel structures are obtained using the stress-strain method. Derived elastic constants, such as bulk modulus, shear modulus, Young's modulus, Poisson coefficient and brittle/ductile behaviour are estimated using Voigt-Reuss-Hill theories. The B/G value, the Poisson's ratio and anisotropic factor are calculated for eight ternary stable crystals. Based on the microscopic hardness model, we further estimate the Vickers hardness of all the stable crystals. From the calculated hardness of the stable group IVA ternary spinel nitrides by Gao's and Jiang's methods, it is observed that the stable group IVA ternary spinel nitrides are not superhard materials except for γ-CSi2N4. Furthermore, the Debye temperature for the eight stable crystals is also estimated.

  2. The influence of wheel/rail contact conditions on the microstructure and hardness of railway wheels.

    PubMed

    Molyneux-Berry, Paul; Davis, Claire; Bevan, Adam

    2014-01-01

    The susceptibility of railway wheels to wear and rolling contact fatigue damage is influenced by the properties of the wheel material. These are influenced by the steel composition, wheel manufacturing process, and thermal and mechanical loading during operation. The in-service properties therefore vary with depth below the surface and with position across the wheel tread. This paper discusses the stress history at the wheel/rail contact (derived from dynamic simulations) and observed variations in hardness and microstructure. It is shown that the hardness of an "in-service" wheel rim varies significantly, with three distinct effects. The underlying hardness trend with depth can be related to microstructural changes during manufacturing (proeutectoid ferrite fraction and pearlite lamellae spacing). The near-surface layer exhibits plastic flow and microstructural shear, especially in regions which experience high tangential forces when curving, with consequentially higher hardness values. Between 1 mm and 7 mm depth, the wheel/rail contacts cause stresses exceeding the material yield stress, leading to work hardening, without a macroscopic change in microstructure. These changes in material properties through the depth of the wheel rim would tend to increase the likelihood of crack initiation on wheels toward the end of their life. This correlates with observations from several train fleets.

  3. RAPID SPECTRAL CHANGES OF CYGNUS X-1 IN THE LOW/HARD STATE WITH SUZAKU

    SciTech Connect

    Yamada, S.; Makishima, K.; Negoro, H.; Torii, S.; Noda, H.; Mineshige, S.

    2013-04-20

    Rapid spectral changes in the hard X-ray on a timescale down to {approx}0.1 s are studied by applying a ''shot analysis'' technique to the Suzaku observations of the black hole binary Cygnus X-1, performed on 2008 April 18 during the low/hard state. We successfully obtained the shot profiles, covering 10-200 keV with the Suzaku HXD-PIN and HXD-GSO detector. It is notable that the 100-200 keV shot profile is acquired for the first time owing to the HXD-GSO detector. The intensity changes in a time-symmetric way, though the hardness changes in a time-asymmetric way. When the shot-phase-resolved spectra are quantified with the Compton model, the Compton y-parameter and the electron temperature are found to decrease gradually through the rising phase of the shot, while the optical depth appears to increase. All the parameters return to their time-averaged values immediately within 0.1 s past the shot peak. We have not only confirmed this feature previously found in energies below {approx}60 keV, but also found that the spectral change is more prominent in energies above {approx}100 keV, implying the existence of some instant mechanism for direct entropy production. We discuss possible interpretations of the rapid spectral changes in the hard X-ray band.

  4. Revisiting the phase diagram of hard ellipsoids

    NASA Astrophysics Data System (ADS)

    Odriozola, Gerardo

    2012-04-01

    In this work, the well-known Frenkel-Mulder phase diagram of hard ellipsoids of revolution [D. Frenkel and B. M. Mulder, Mol. Phys. 55, 1171 (1985), 10.1080/00268978500101971] is revisited by means of replica exchange Monte Carlo simulations. The method provides good sampling of dense systems and so, solid phases can be accessed without the need of imposing a given structure. At high densities, we found plastic solids and fcc-like crystals for semi-spherical ellipsoids (prolates and oblates), and SM2 structures [P. Pfleiderer and T. Schilling, Phys. Rev. E 75, 020402 (2007)] for x : 1-prolates and 1 : x-oblates with x ≥ 3. The revised fluid-crystal and isotropic-nematic transitions reasonably agree with those presented in the Frenkel-Mulder diagram. An interesting result is that, for small system sizes (100 particles), we obtained 2:1- and 1.5:1-prolate equations of state without transitions, while some order is developed at large densities. Furthermore, the symmetric oblate cases are also reluctant to form ordered phases.

  5. Dynamics of hard sphere colloidal dispersions

    NASA Technical Reports Server (NTRS)

    Zhu, J. X.; Chaikin, Paul M.; Phan, S.-E.; Russel, W. B.

    1994-01-01

    Our objective is to perform on homogeneous, fully equilibrated dispersions the full set of experiments characterizing the transition from fluid to solid and the properties of the crystalline and glassy solid. These include measurements quantifying the nucleation and growth of crystallites, the structure of the initial fluid and the fully crystalline solid, and Brownian motion of particles within the crystal, and the elasticity of the crystal and the glass. Experiments are being built and tested for ideal microgravity environment. Here we describe the ground based effort, which exploits a fluidized bed to create a homogeneous, steady dispersion for the studies. The differences between the microgravity environment and the fluidized bed is gauged by the Peclet number Pe, which measures the rate of convection/sedimentation relative to Brownian motion. We have designed our experiment to accomplish three types of measurements on hard sphere suspensions in a fluidized bed: the static scattering intensity as a function of angle to determine the structure factor, the temporal autocorrelation function at all scattering angles to probe the dynamics, and the amplitude of the response to an oscillatory forcing to deduce the low frequency viscoelasticity. Thus the scattering instrument and the colloidal dispersion were chosen such as that the important features of each physical property lie within the detectable range for each measurement.

  6. Unraveling Quantum Annealers using Classical Hardness.

    PubMed

    Martin-Mayor, Victor; Hen, Itay

    2015-01-01

    Recent advances in quantum technology have led to the development and manufacturing of experimental programmable quantum annealing optimizers that contain hundreds of quantum bits. These optimizers, commonly referred to as 'D-Wave' chips, promise to solve practical optimization problems potentially faster than conventional 'classical' computers. Attempts to quantify the quantum nature of these chips have been met with both excitement and skepticism but have also brought up numerous fundamental questions pertaining to the distinguishability of experimental quantum annealers from their classical thermal counterparts. Inspired by recent results in spin-glass theory that recognize 'temperature chaos' as the underlying mechanism responsible for the computational intractability of hard optimization problems, we devise a general method to quantify the performance of quantum annealers on optimization problems suffering from varying degrees of temperature chaos: A superior performance of quantum annealers over classical algorithms on these may allude to the role that quantum effects play in providing speedup. We utilize our method to experimentally study the D-Wave Two chip on different temperature-chaotic problems and find, surprisingly, that its performance scales unfavorably as compared to several analogous classical algorithms. We detect, quantify and discuss several purely classical effects that possibly mask the quantum behavior of the chip. PMID:26483257

  7. Computational Modeling Develops Ultra-Hard Steel

    NASA Technical Reports Server (NTRS)

    2007-01-01

    Glenn Research Center's Mechanical Components Branch developed a spiral bevel or face gear test rig for testing thermal behavior, surface fatigue, strain, vibration, and noise; a full-scale, 500-horsepower helicopter main-rotor transmission testing stand; a gear rig that allows fundamental studies of the dynamic behavior of gear systems and gear noise; and a high-speed helical gear test for analyzing thermal behavior for rotorcraft. The test rig provides accelerated fatigue life testing for standard spur gears at speeds of up to 10,000 rotations per minute. The test rig enables engineers to investigate the effects of materials, heat treat, shot peen, lubricants, and other factors on the gear's performance. QuesTek Innovations LLC, based in Evanston, Illinois, recently developed a carburized, martensitic gear steel with an ultra-hard case using its computational design methodology, but needed to verify surface fatigue, lifecycle performance, and overall reliability. The Battelle Memorial Institute introduced the company to researchers at Glenn's Mechanical Components Branch and facilitated a partnership allowing researchers at the NASA Center to conduct spur gear fatigue testing for the company. Testing revealed that QuesTek's gear steel outperforms the current state-of-the-art alloys used for aviation gears in contact fatigue by almost 300 percent. With the confidence and credibility provided by the NASA testing, QuesTek is commercializing two new steel alloys. Uses for this new class of steel are limitless in areas that demand exceptional strength for high throughput applications.

  8. The smallest hard X-ray flare?

    NASA Astrophysics Data System (ADS)

    Glesener, Lindsay; Krucker, Sam; Hannah, Iain; Smith, David M.; Grefenstette, Brian; Marsh, Andrew; Hudson, Hugh S.; White, Stephen M.; Chen, Bin

    2016-05-01

    We report a NuSTAR observation of a small solar flare on 2015 September 1, estimated to be on the order of a GOES class A.05 flare in brightness. This flare is fainter than any hard X-ray (HXR) flares in the existing literature, and with a peak rate of only ˜5 counts s-1 detector-1 observed by RHESSI, is effectively the smallest that can just barely be detected by the current standard (indirectly imaging) solar HXR instrumentation, though we expect that smaller flares will continue to be discovered as instrumental and observational techniques progress. The flare occurred during a solar observation by the highly sensitive NuSTAR astrophysical HXR spacecraft, which used its direct focusing optics to produce detailed flare spectra and images. The flare exhibits properties commonly observed in larger flares, including a fast rise and more gradual decay, and similar spatial dimensions to the RHESSI microflares. We will discuss the presence of non-thermal (flare-accelerated) electrons during the impulsive phase. The flare is small in emission measure, temperature, and energy, though not in physical dimensions. Its presence is an indication that flares do indeed scale down to smaller energies and retain what we customarily think of as “flarelike” properties.

  9. Hard cosmic X-ray sources.

    NASA Technical Reports Server (NTRS)

    Peterson, L. E.

    1973-01-01

    A review of the observational status of X-ray sources detected in the 20 to 500 keV range is presented. Of the approximately 115 sources listed in the March 1972 edition of the UHURU 2-6 keV sky survey catalog, about 15 sources have been studied in hard X rays. Most of the data have been obtained from balloons, although the OSO-3, and more recently the OSO-7, have contributed. With the exception of CEN A, the SMC, and possibly M-87, all the sources detected at higher energies are galactic and heavily concentrated in the galactic plane. The Crab Nebula has been measured to about 500 keV in continuous emission and a component at the 33-msec pulsar period comprising about 20% of the total emission has been detected to 10 MeV. Objects such as SCO-1 and CYG-2 are characterized by an exponential spectrum, which varies over a 10-min time scale about a factor of two, and a flatter spectrum extending to above 40 keV which exhibits independent variability.

  10. Unraveling Quantum Annealers using Classical Hardness.

    PubMed

    Martin-Mayor, Victor; Hen, Itay

    2015-10-20

    Recent advances in quantum technology have led to the development and manufacturing of experimental programmable quantum annealing optimizers that contain hundreds of quantum bits. These optimizers, commonly referred to as 'D-Wave' chips, promise to solve practical optimization problems potentially faster than conventional 'classical' computers. Attempts to quantify the quantum nature of these chips have been met with both excitement and skepticism but have also brought up numerous fundamental questions pertaining to the distinguishability of experimental quantum annealers from their classical thermal counterparts. Inspired by recent results in spin-glass theory that recognize 'temperature chaos' as the underlying mechanism responsible for the computational intractability of hard optimization problems, we devise a general method to quantify the performance of quantum annealers on optimization problems suffering from varying degrees of temperature chaos: A superior performance of quantum annealers over classical algorithms on these may allude to the role that quantum effects play in providing speedup. We utilize our method to experimentally study the D-Wave Two chip on different temperature-chaotic problems and find, surprisingly, that its performance scales unfavorably as compared to several analogous classical algorithms. We detect, quantify and discuss several purely classical effects that possibly mask the quantum behavior of the chip.

  11. Hard Exclusive Meson Production at COMPASS

    NASA Astrophysics Data System (ADS)

    Ter Wolbeek, Johannes

    2016-02-01

    The concept of Generalized Parton Distributions (GPDs) combines two-dimensional spatial information given by form factors, with longitudinal momentum information from Parton Distribution Functions. GPDs provide comprehensive description of the nucleon structure involving a wealth of new information. For instance, according to Ji’s sum rule, the GPDs H and E enable access to the total angular momenta of quarks, antiquarks and gluons. While H can be approached using measurements of electroproduction cross sections, asymmetry measurements in hard exclusive meson production off transversely polarized targets can help to constrain the GPD E and chiral-odd GPDs. In 2007 and 2010 the COMPASS experiment at CERN collected data by scattering a 160GeV/c muon beam off a transversely polarized NH3 target. Exclusive vector-meson production μ + p → μ‧ + p + V with a ρ0 or ω meson in the final state is studied and five single-spin and three double-spin azimuthal asymmetries are measured.

  12. Revisiting the phase diagram of hard ellipsoids.

    PubMed

    Odriozola, Gerardo

    2012-04-01

    In this work, the well-known Frenkel-Mulder phase diagram of hard ellipsoids of revolution [D. Frenkel and B. M. Mulder, Mol. Phys. 55, 1171 (1985)] is revisited by means of replica exchange Monte Carlo simulations. The method provides good sampling of dense systems and so, solid phases can be accessed without the need of imposing a given structure. At high densities, we found plastic solids and fcc-like crystals for semi-spherical ellipsoids (prolates and oblates), and SM2 structures [P. Pfleiderer and T. Schilling, Phys. Rev. E 75, 020402 (2007)] for x : 1-prolates and 1 : x-oblates with x ≥ 3. The revised fluid-crystal and isotropic-nematic transitions reasonably agree with those presented in the Frenkel-Mulder diagram. An interesting result is that, for small system sizes (100 particles), we obtained 2:1- and 1.5:1-prolate equations of state without transitions, while some order is developed at large densities. Furthermore, the symmetric oblate cases are also reluctant to form ordered phases.

  13. Escape dynamics of many hard disks.

    PubMed

    Taniguchi, Tooru; Murata, Hiroki; Sawada, Shin-Ichi

    2014-11-01

    Many-particle effects in escapes of hard disks from a square box via a hole are discussed in a viewpoint of dynamical systems. Starting from N disks in the box at the initial time, we calculate the probability P_{n}(t) for at least n disks to remain inside the box at time t for n=1,2,...,N. At early times, the probabilities P_{n}(t),n=2,3,...,N-1, are described by superpositions of exponential decay functions. On the other hand, after a long time the probability P_{n}(t) shows a power-law decay ∼t^{-2n} for n≠1, in contrast to the fact that it decays with a different power law ∼t^{-n} for cases without any disk-disk collision. Chaotic or nonchaotic properties of the escape systems are discussed by the dynamics of a finite-time largest Lyapunov exponent, whose decay properties are related with those of the probability P_{n}(t). PMID:25493874

  14. Impact of the hard-coded parameters on the hydrologic fluxes of the land surface model Noah-MP

    NASA Astrophysics Data System (ADS)

    Cuntz, Matthias; Mai, Juliane; Samaniego, Luis; Clark, Martyn; Wulfmeyer, Volker; Attinger, Sabine; Thober, Stephan

    2016-04-01

    Land surface models incorporate a large number of processes, described by physical, chemical and empirical equations. The process descriptions contain a number of parameters that can be soil or plant type dependent and are typically read from tabulated input files. Land surface models may have, however, process descriptions that contain fixed, hard-coded numbers in the computer code, which are not identified as model parameters. Here we searched for hard-coded parameters in the computer code of the land surface model Noah with multiple process options (Noah-MP) to assess the importance of the fixed values on restricting the model's agility during parameter estimation. We found 139 hard-coded values in all Noah-MP process options, which are mostly spatially constant values. This is in addition to the 71 standard parameters of Noah-MP, which mostly get distributed spatially by given vegetation and soil input maps. We performed a Sobol' global sensitivity analysis of Noah-MP to variations of the standard and hard-coded parameters for a specific set of process options. 42 standard parameters and 75 hard-coded parameters were active with the chosen process options. The sensitivities of the hydrologic output fluxes latent heat and total runoff as well as their component fluxes were evaluated. These sensitivities were evaluated at twelve catchments of the Eastern United States with very different hydro-meteorological regimes. Noah-MP's hydrologic output fluxes are sensitive to two thirds of its standard parameters. The most sensitive parameter is, however, a hard-coded value in the formulation of soil surface resistance for evaporation, which proved to be oversensitive in other land surface models as well. Surface runoff is sensitive to almost all hard-coded parameters of the snow processes and the meteorological inputs. These parameter sensitivities diminish in total runoff. Assessing these parameters in model calibration would require detailed snow observations or the

  15. Observational Aspects of Hard X-ray Polarimetry

    NASA Astrophysics Data System (ADS)

    Chattopadhyay, Tanmoy

    2016-04-01

    of such hard X-ray telescopes, which may provide sensitive polarization measurements due to flux concentration in hard X-rays with a very low background. On the other hand, such a configuration ensures implementation of an optimized geometry close to an ideal one for the Compton polarimeters. In this context, we initiated the development of a focal plane Compton polarimeter, consisting of a plastic scatterer surrounded by a cylindrical array of CsI(Tl) scintillators. Geant‑4 simulations of the planned configuration estimates 1% MDP for a 100 mCrab source in 1 million seconds of exposure. Sensitivity of the instrument is found to be critically dependent on the lower energy detection limit of the plastic scatterer; lower the threshold, better is the sensitivity. In the actual experiment, the plastic is readout by a photomultiplier tube procured from Saint-Gobain. We carried out extensive experiments to characterize the plastic especially for lower energy depositions. The CsI(Tl) scintillators are readout by Si photomultipliers (SiPM). SiPMs are small in size and robust and therefore provide the compactness necessary for the designing of focal plane detectors. Each of the CsI(Tl)-SiPM systems was characterized precisely to estimate their energy threshold and detection probability along the length of the scintillators away from SiPM. Finally, we integrated the Compton polarimeter and tested its response to polarized and unpolarized radiation and compared the experimental results with Geant‑4 simulation. Despite the growing realization of the scientific values of X-ray polarimetry and the efforts in developing sensitive X-ray polarimeters, there has not been a single dedicated X-ray polarimetry mission planned in near future. In this scenario, it is equally important to attempt polarization measurements from the existing or planned instruments which are not meant for X-ray polarization measurements but could be sensitive to it. There have been several attempts in past

  16. Respiratory effects of hard-metal dust exposure

    SciTech Connect

    Balmes, J.R.

    1987-04-01

    Workers exposed to hard-metal dust are at risk of developing interstitial pulmonary fibrosis. Focusing on the lung parenchymal disorders that result, the author thoroughly reviews the background of the problem, animal studies and recent environmental data related to hard-metal disease, the clinical presentation, and finally its etiology.

  17. Effective volumes of hard homonuclear nonlinear triatomic molecules

    NASA Astrophysics Data System (ADS)

    Maeso, M. J.; Solana, J. R.

    Expressions to determine effective molecular volumes for nonlinear hard homonuclear triatomic molecules are derived. They are used, in combination with an equation of state previously proposed for hard-body molecular fluids, to reproduce accurately the existing simulation data for this kind of fluid, covering a wide range of bond angles.

  18. Equations of state for fused-hard-sphere fluids

    NASA Astrophysics Data System (ADS)

    Maeso, M. J.; Solana, J. R.

    1993-09-01

    Analytical equations of state for fused-hard-sphere fluids are developed from a generalization of the Carnahan-Starling method for obtaining the equation of state of the hard-sphere fluid. The results are in good agreement with existing simulation data.

  19. Correlation between magnetic properties and the hardness of powder steels

    SciTech Connect

    Ul`yanov, A.I.; Merzlyakov, E.F.; Faizullin, R.G.

    1994-07-01

    Density and carbon content are studied for their effect on strength (hardness) and magnetic (coercive force, saturation magnetization) properties of powder steels ZhGr1 and ZhGr1D3. It is shown that the hardness of articles made of these steels may be determined indirectly by measuring two magnetic characteristics.

  20. Wheat Quality Council, Hard Spring Wheat Technical Committee, 2014 Crop

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Eleven experimental lines of hard spring wheat were grown at up to five locations in 2014 and evaluated for kernel, milling, and bread baking quality against the check variety Glenn. Wheat samples were submitted through the Wheat Quality Council and processed and milled at the USDA-ARS Hard Red Spr...

  1. Educating Hard of Hearing Children. Special Education in Transition 2.

    ERIC Educational Resources Information Center

    Ross, Mark, Ed.; Nober, Linda W., Ed.

    Viewpoints of an audiologist, speech-language pathologist, special educator, classroom teacher, and parent are presented in the book on the implications of P.L. 94-142, the Education for All Handicapped Children Act, for hard of hearing students. In the introduction, M. Ross considers the status of many hard of hearing students, noting the…

  2. Critical Configurations of Hard Disks on the Torus

    2013-04-16

    CCHDT constructs and classifies various arrangements of hard disks of a single radius places on the unit square with periodic boundary conditions. Specifially, a given configuration is evolved to the nearest critical point on a smoothed hard disk energy fuction, and is classified by the adjacency matrix of the canonically labelled contact graph.

  3. [A woman with a pigmentation of the hard palate].

    PubMed

    van der Meij, Erik H; Nieken, Judith; de Visscher, Jan G A M

    2013-01-01

    A bluish flat pigmented lesion of the hard palate of a 51-year-old woman was excised to exclude malignancy, in particular oral malignant melanoma. On histopathological examination, depositions of black pigment were seen accompanied by several foreign body giant cells. Probably due to a childhood trauma, a pencil point had penetrated the hard palate. PMID:24330792

  4. Hardness Analysis. Training Module 5.215.2.77.

    ERIC Educational Resources Information Center

    Bonte, John L.; Davidson, Arnold C.

    This document is an instructional module package prepared in objective form for use by an instructor familiar with hardness analysis using the EDTA method and the calculation of hardness given metal ion concentrations and a factor table. Included are objectives, an instructor guide, student handouts, and transparency masters. A video tape is also…

  5. Surface Effects on Young's Modulud and Hardness of Fused Silica by Nanoindentation Study

    SciTech Connect

    Zheng, L.; Schmid, A.W.; Lambropoulos, J.C.

    2007-01-24

    The surface Young's modulus (E) and hardness (H) of fused silica samples have been studied by nanoindentation. Two factors strongly affect the results of E and H. One factor is the polishing quality of the fused silica surface. Poor polishing quality produces much smaller E and H than the literature values for bulk fused silica. The second factor is surface flatness. Even for a well-polished silica surface, an "arch bridge effect" may hinder the measurements of the true values of E and H. A correction procedure is proposed to eliminate this effect, and the corrected results show substantial improvements.

  6. INFLUENCE OF THE DISTANCE OF THE CURING LIGHT SOURCE AND COMPOSITE SHADE ON HARDNESS OF TWO COMPOSITES

    PubMed Central

    Thomé, Thaís; Steagall, Washington; Tachibana, Arlene; Braga, Sheila Regina Maia; Turbino, Miriam Lacalle

    2007-01-01

    This study evaluated the influence of curing tip distance, shade and filler particle size on Vickers microhardness (VHN) of composite resins. Two composites were tested: Filtek Z250 microhybrid (3M ESPE; shades A1 and A3.5) and Filtek Supreme nanofilled (3M ESPE; shades A1B and A3.5B). For each resin, 42 specimens (5 mm in diameter and 2 mm height) were prepared being 21 for each shade. The specimens were exposed using a 20-second exposure to a quartz-tungsten-halogen light source with an irradiance of approximately 560 mW/cm2, at the following distances: 0 mm (surface contact), 6 mm and 12 mm from composite surface. Effectiveness of cure of different resins, shades and curing distances was determined by measuring the top and bottom hardness (VHN) of specimens using a digital microhardness tester (load: 50 g; dwell time: 45 seconds) 24 hours following curing. The hardness ratio was calculated by dividing VHN of the bottom surface by VHN of top surface. Three-way ANOVA and Tukey's post-hoc test (p<0.05) revealed statistically significant differences for all analyzed factors. As for top hardness, as microhardness ratio (bottom/top), the factors shade, distance and composite filler particle size exerted influence on resin curing. Lighter shade composites (A1 and A1B) showed higher hardness values. At 6 and 12 mm curing tip distances, hardness was lower when compared to 0 mm. The microhybrid composite resin presented higheer hardness, being its microhardness ratio satisfactory only at 0 mm for both shades and at 6 mm for the lighter shade. The nanofilled composite resin did not present satisfactory microhardness at the bottom while the microhybrid composite resin had higher hardness than the nanofilled. Composite's curing tip distance and shade can influence hardness. PMID:19089185

  7. Fuzzy and hard clustering analysis for thyroid disease.

    PubMed

    Azar, Ahmad Taher; El-Said, Shaimaa Ahmed; Hassanien, Aboul Ella

    2013-07-01

    Thyroid hormones produced by the thyroid gland help regulation of the body's metabolism. A variety of methods have been proposed in the literature for thyroid disease classification. As far as we know, clustering techniques have not been used in thyroid diseases data set so far. This paper proposes a comparison between hard and fuzzy clustering algorithms for thyroid diseases data set in order to find the optimal number of clusters. Different scalar validity measures are used in comparing the performances of the proposed clustering systems. To demonstrate the performance of each algorithm, the feature values that represent thyroid disease are used as input for the system. Several runs are carried out and recorded with a different number of clusters being specified for each run (between 2 and 11), so as to establish the optimum number of clusters. To find the optimal number of clusters, the so-called elbow criterion is applied. The experimental results revealed that for all algorithms, the elbow was located at c=3. The clustering results for all algorithms are then visualized by the Sammon mapping method to find a low-dimensional (normally 2D or 3D) representation of a set of points distributed in a high dimensional pattern space. At the end of this study, some recommendations are formulated to improve determining the actual number of clusters present in the data set. PMID:23357404

  8. The impulsive hard X-rays from solar flares

    NASA Technical Reports Server (NTRS)

    Leach, J.

    1984-01-01

    A technique for determining the physical arrangement of a solar flare during the impulsive phase was developed based upon a nonthermal model interpretation of the emitted hard X-rays. Accurate values are obtained for the flare parameters, including those which describe the magnetic field structure and the beaming of the energetic electrons, parameters which have hitherto been mostly inaccessible. The X-ray intensity height structure can be described readily with a single expression based upon a semi-empirical fit to the results from many models. Results show that the degree of linear polarization of the X-rays from a flaring loop does not exceed 25 percent and can easily and naturally be as low as the polarization expected from a thermal model. This is a highly significant result in that it supersedes those based upon less thorough calculations of the electron beam dynamics and requires that a reevaluation of hopes of using polarization measurements to discriminate between categories of flare models.

  9. Combining Hard and Soft Data in Drought Research

    NASA Astrophysics Data System (ADS)

    Van Loon, A.

    2014-12-01

    As natural scientists we are used to doing quantitative analysis on observations or simulations of hydrometeorological variables. In many fields of hydrology, however, other sources of information are available that can broaden our knowledge of a hydrological system or process. In this pop-up I will show how the combination of hard and soft data in drought research has improved our knowledge of drought in cold climates and the impacts of drought on agriculture. We used data from historical archives and modern drought impact databases and used this information side-by-side with hydrometeorological observations and outcomes of large-scale hydrological models. I will present the pros and cons of using different types of data. This presentation has two aims: i) it is an example to other fields of hydrology, in which other data sources and different type of analysis could have an added value as well, and, ii) it calls for a wider accessibility, collection and consolidation of soft data to serve its use in hydrology.

  10. Universal jamming phase diagram in the hard-sphere limit.

    PubMed

    Haxton, Thomas K; Schmiedeberg, Michael; Liu, Andrea J

    2011-03-01

    We present a new formulation of the jamming phase diagram for a class of glass-forming fluids consisting of spheres interacting via finite-ranged repulsions at temperature T, packing fraction ϕ or pressure p, and applied shear stress Σ. We argue that the natural choice of axes for the phase diagram are the dimensionless quantities T/pσ³, pσ³/ε, and Σ/p, where T is the temperature, p is the pressure, Σ is the stress, σ is the sphere diameter, ε is the interaction energy scale, and m is the sphere mass. We demonstrate that the phase diagram is universal at low pσ³/ε; at low pressure, observables such as the relaxation time are insensitive to details of the interaction potential and collapse onto the values for hard spheres, provided the observables are nondimensionalized by the pressure. We determine the shape of the jamming surface in the jamming phase diagram, organize previous results in relation to the jamming phase diagram, and discuss the significance of various limits.

  11. Hard proximity induced superconducting gap in semiconductor - superconductor epitaxial hybrids

    NASA Astrophysics Data System (ADS)

    Jespersen, Thomas; Krogstrup, Peter; Ziino, Nino; Albrecht, Sven; Chang, Willy; Madsen, Morten; Johnson, Erik; Kuemmeth, Ferdinand; Nygård, Jesper; Marcus, Charles

    2015-03-01

    We present molecular beam epitaxy grown InAs semiconductor nanowires capped with a shell of aluminum (superconductor). The hybrid wires are grown without breaking vacuum, resulting in an epitaxial interface between the two materials as demonstrated by detailed transmission electron microscopy and simulations. The domain matching at the interface is discussed. Incorporating the epitaxial nanowire hybrids in electrical devices we performed detailed tunneling spectroscopy of the proximity induced superconducting gap in the InAs core at 20 mK. We find the sub-gap conductance being at least a factor 200 smaller than the normal state value (gap hardness). This is a significant improvement compared to devices fabricated by conventional lithographic methods and metal evaporation showing no more than a factor of ~ 5 . The epitaxial hybrids seem to solve the soft gap problem associated with the use of nanowire hybrids for future applications in topological quantum information based on Majorana zero modes. Research supported by Microsoft Station Q, Danish National Research Foundation, Villum Foundation, Lundbeck Foundation, and the European Commission.

  12. Properties of vaccum arc deposited amorphous hard carbon films

    SciTech Connect

    Anders, S.; Anders, A.; Raoux, S.

    1995-12-31

    Amorphous hard carbon films formed by vacuum arc deposition are, hydrogen-free, dense, and very hard. The properties of amorphous hard carbon films depend strongly on the energy of the incident ions. A technique which is called Plasma Immersion Ion Implantation can be applied to vacuum arc deposition of amorphous hard carbon films to influence the ion energy. We have studied the influence of the ion energy on the elastic modulus determined by an ultrasonic method, and have measured the optical gap for films with the highest sp{sup 3} content we have obtained so far with this deposition technique. The results show an elastic modulus close to that of diamond, and an optical gap of 2.1 eV which is much greater than for amorphous hard carbon films deposited by other techniques.

  13. Boron suboxide: As hard as cubic boron nitride

    NASA Astrophysics Data System (ADS)

    He, Duanwei; Zhao, Yusheng; Daemen, L.; Qian, J.; Shen, T. D.; Zerda, T. W.

    2002-07-01

    The Vickers hardness of boron suboxide single crystals was measured using a diamond indentation method. Under a loading force of 0.98 N, our test gave an average Vickers hardness of 45 GPa. The average fracture toughness was measured as 4.5 MPa m1/2. We also measured the hardness of the cubic boron nitride and sapphire single crystals for comparison. The average measured hardness for boron suboxide was found to be very close to that of cubic boron nitride under the same loading force. Our results suggest that the boron suboxide could be a new superhard material for industrial applications, surpassed in hardness only by diamond and cubic boron nitride.

  14. Properties of vacuum arc deposited amorphous hard carbon films

    SciTech Connect

    Anders, S.; Anders, A.; Raoux, S.

    1995-04-01

    Amorphous hard carbon films formed by vacuum arc deposition are hydrogen-free, dense, and very hard. The properties of amorphous hard carbon films depend strongly on the energy of the incident ions. A technique which is called Plasma Immersion Ion Implantation can be applied to vacuum arc deposition of amorphous hard carbon films to influence the ion energy. The authors have studied the influence of the ion energy on the elastic modulus determined by an ultrasonic method, and have measured the optical gap for films with the highest sp{sup 3} content they have obtained so far with this deposition technique. The results show an elastic modulus close to that of diamond, and an optical gap of 2.1 eV which is much greater than for amorphous hard carbon films deposited by other techniques.

  15. Aroma Stability of Lemon-Flavored Hard Iced Tea Assessed by Chirality and Aroma Extract Dilution Analysis.

    PubMed

    Yuan, Fang; He, Fei; Qian, Yanping; Zheng, Jia; Qian, Michael C

    2016-07-20

    The aroma of fresh and aged lemon-flavored hard tea was investigated by aroma extract dilution analysis (AEDA), quantitative comparison, and two-dimensional chirality analysis. Aroma extract dilution analysis of fresh hard tea samples showed 3-methylbutanal, isoamyl alcohol, β-damascenone, β-ionone, 2-phenylethanol, 4-hydroxy-2,5-dimethyl-3(2H)-furanone, and vanillin could be the most important aroma contributors to the hard tea due to their high FD values. The analysis of the aged hard tea samples did not reveal new compound formation during storage; however, compared with fresh samples, the flavor dilution value changed substantially in the aged samples. Both AEDA and quantitative analysis demonstrated that β-damascenone increased substantially in aged samples, whereas terpene aldehydes decreased substantially after storage. In addition, the FD value of linalool decreased dramatically in aged samples. Two-dimensional GC-MS chirality analysis revealed the FD value decrease of linalool in aged samples was largely due to the transformation of (R)-linalool to (S)-linalool, which has a higher sensory threshold. PMID:27319225

  16. Converting hard copy documents for electronic dissemination

    SciTech Connect

    Hoffman, F.

    1994-12-31

    Since the advent of computer systems, the goal of a paperless office, and even a paperless society, has been pursued. While the normal paper flow in an organization is far from totally automated, particularly for items requiring signatures or authorizations, electronic information dissemination is becoming an almost simple task. The reasons for providing on-line documents are many and include faster and easier access for everyone, elimination of printing costs, reduction of wasted shelf and desk space, and the security of having a centrally-located, always up-to-date document. New computer software even provides the user with the ability to annotate documents and to have bookmarks so that the old scribbled-in and dog-eared manual can be replaced without loosing this `customizability`. Moreover, new hypermedia capabilities mean that documents can be read in a non-linear fashion and can include color figures and photographs, audio, and even animation sequences, capabilities which exceed those of paper. The proliferation of network-based information servers, coupled with the growth of the Internet, has enticed academic, governmental, and even commercial organizations to provide increasing numbers of documents and data bases in electronic form via the network, not just to internal staff, but to the public as well. Much of this information, which includes everything from mundane company procedures to spiffy marketing brochures, was previously published only in hard copy. Converting existing documents to electronic form and producing only electronic versions of new documents poses some interesting challenges to the maintainer or author.

  17. Hard magnetism in structurally engineered silica nanocomposite.

    PubMed

    Song, Hyon-Min; Zink, Jeffrey I

    2016-09-21

    Creation of structural complexity by simple experimental control will be an attractive approach for the preparation of nanomaterials, as a classical bottom-up method is supplemented by a more efficient and more direct artificial engineering method. In this study, structural manipulation of MCM-41 type mesoporous silica is investigated by generating and imbedding hard magnetic CoFe2O4 nanoparticles into mesoporous silica. Depending on the heating rate and target temperature, mesoporous silica undergoes a transformation in shape to form hollow silica, framed silica with interior voids, or melted silica with intact mesostructures. Magnetism is governed by the major CoFe2O4 phase, and it is affected by antiferromagnetic hematite (α-Fe2O3) and olivine-type cobalt silicate (Co2SiO4), as seen in its paramagnetic behavior at the annealing temperature of 430 °C. The early formation of Co2SiO4 than what is usually observed implies the effect of the partial substitution of Fe in the sites of Co. Under slow heating (2.5 °C min(-1)) mesostructures are preserved, but with significantly smaller mesopores (d100 = 1.5 nm). In addition, nonstoichiometric CoxFe1-xO with metal vacancies at 600 °C, and spinel Co3O4 at 700 °C accompany major CoFe2O4. The amorphous nature of silica matrix is thought to contribute significantly to these structurally diverse and rich phases, enabled by off-stoichiometry between Si and O, and accelerated by the diffusion of metal cations into SiO4 polyhedra at an elevated temperature. PMID:27537252

  18. Reliability of hard plastic clad silica fibers

    NASA Astrophysics Data System (ADS)

    Skutnik, Bolesh J.; Spaniol, Stefan

    2006-04-01

    New formulations of cladding materials have become available in recent times for Hard Plastic Clad Silica (HPCS) fibers, Initial data showed gains in some properties, particularly dynamic strength, especially for high numerical aperture (NA) fibers. A systematic study has been undertaken to determine the full strength and fatigue behavior of these HPCS fibers and to make comparisons to earlier HPCS fibers. Preliminary results, now confirmed, has shown improved median dynamic strength and higher Weibull slope. Full results are presented below including fatigue behavior and optical properties. These fibers have many applications and benefits in the high power delivery and medical laser uses as highlighted below. High power diode laser systems with their laser diode bars and arrays not only require special fibers to couple directly to the diode emitters, but also require special fibers to couple from the laser to application sites. These latter power delivery fibers are much larger than the internal fibers but still must be flexible, and have not only good strength but also good fatigue behavior. This particularly important industrial systems using robotic arms to apply the high power laser energy at a treatment site. The optical properties of HPCS fibers are well suited for the needs of the delivery of high power from diode laser bars and arrays to an application site. Benefits of strong median dynamic strengths and tighter flaw distributions in such cases will be discussed. Many medical applications, especially endoscopic ones, can benefit from the use of highly flexible, high NA, cost effective, HPCS optical fibers. Benefits of high strength and good fatigue behavior for such fibers in endoscopic procedures, including laser surgery, are discussed briefly including implications for mechanical reliability in medical and industrial settings.

  19. Hard magnetism in structurally engineered silica nanocomposite.

    PubMed

    Song, Hyon-Min; Zink, Jeffrey I

    2016-09-21

    Creation of structural complexity by simple experimental control will be an attractive approach for the preparation of nanomaterials, as a classical bottom-up method is supplemented by a more efficient and more direct artificial engineering method. In this study, structural manipulation of MCM-41 type mesoporous silica is investigated by generating and imbedding hard magnetic CoFe2O4 nanoparticles into mesoporous silica. Depending on the heating rate and target temperature, mesoporous silica undergoes a transformation in shape to form hollow silica, framed silica with interior voids, or melted silica with intact mesostructures. Magnetism is governed by the major CoFe2O4 phase, and it is affected by antiferromagnetic hematite (α-Fe2O3) and olivine-type cobalt silicate (Co2SiO4), as seen in its paramagnetic behavior at the annealing temperature of 430 °C. The early formation of Co2SiO4 than what is usually observed implies the effect of the partial substitution of Fe in the sites of Co. Under slow heating (2.5 °C min(-1)) mesostructures are preserved, but with significantly smaller mesopores (d100 = 1.5 nm). In addition, nonstoichiometric CoxFe1-xO with metal vacancies at 600 °C, and spinel Co3O4 at 700 °C accompany major CoFe2O4. The amorphous nature of silica matrix is thought to contribute significantly to these structurally diverse and rich phases, enabled by off-stoichiometry between Si and O, and accelerated by the diffusion of metal cations into SiO4 polyhedra at an elevated temperature.

  20. Valuing Opportunities to Learn

    ERIC Educational Resources Information Center

    Bullock, Quintin B.

    2015-01-01

    With community colleges in the national spotlight as never before, a lot of talk has focused on the excellent work that community colleges are doing to help students succeed, especially the inroads that community colleges are making among their most academically vulnerable students. Thanks to the efforts of hard-working, dedicated faculty and…

  1. From Hard to Reach to How to Reach: A Systematic Review of the Literature on Hard-to-Reach Families

    ERIC Educational Resources Information Center

    Boag-Munroe, Gill; Evangelou, Maria

    2012-01-01

    This paper presents a review of the literature relating to hard-to-reach families which has been published over the last 12 years in the UK, USA, Canada and Australia. The purpose of the review was twofold: to gain insights to understandings of the term "hard-to-reach" within these services--education, health and social--which might be aiming to…

  2. The Value of Reciprocity

    ERIC Educational Resources Information Center

    Molm, Linda D.; Schaefer, David R.; Collett, Jessica L.

    2007-01-01

    The value of reciprocity in social exchange potentially comprises both instrumental value (the value of the actual benefits received from exchange) and communicative or symbolic value (the expressive and uncertainty reduction value conveyed by features of the act of reciprocity itself). While all forms of exchange provide instrumental value, we…

  3. Influence of water hardness and sulfate on the acute toxicity of chloride to sensitive freshwater invertebrates.

    PubMed

    Soucek, David J; Linton, Tyler K; Tarr, Christopher D; Dickinson, Amy; Wickramanayake, Nilesh; Delos, Charles G; Cruz, Luis A

    2011-04-01

    Total dissolved solids (TDS) represent the sum of all common ions (e.g., Na, K, Ca, Mg, chloride, sulfate, and bicarbonate) in freshwater. Currently, no federal water quality criteria exist for the protection of aquatic life for TDS, but because the constituents that constitute TDS are variable, the development of aquatic life criteria for specific ions is more practical than development of aquatic life criteria for TDS. Chloride is one such ion for which aquatic life criteria exist; however, the current aquatic life criteria dataset for chloride is more than 20 years old. Therefore, additional toxicity tests were conducted in the current study to confirm the acute toxicity of chloride to several potentially sensitive invertebrates: water flea (Ceriodaphnia dubia), fingernail clams (Sphaerium simile and Musculium transversum), snail (Gyraulus parvus), and worm (Tubifex tubifex), and determine the extent to which hardness and sulfate modify chloride toxicity. The results indicated a significant ameliorating effect of water hardness (calcium and magnesium) on chloride toxicity for all species tested except the snail; for example, the 48-h chloride median lethal concentration (LC50) for C. dubia at 50 mg/L hardness (977 mg Cl(-) /L) was half that at 800 mg/L hardness (1,836 mg Cl(-) /L). Conversely, sulfate over the range of 25 to 600 mg/L exerted a negligible effect on chloride toxicity to C. dubia. Rank order of LC50 values for chloride at a given water hardness was in the order (lowest to highest): S. simile < C. dubia < M. transversum < G. parvus < T. tubifex. Results of the current study support the contention that the specific conductivity or TDS concentration of a water body alone is not a sufficient predictor of acute toxicity and that knowledge of the specific ion composition is critical.

  4. Relation between hardness and ultrasonic velocity on pipeline steel welded joints

    NASA Astrophysics Data System (ADS)

    Carreón, H.; Barrera, G.; Natividad, C.; Salazar, M.; Contreras, A.

    2016-04-01

    In general, the ultrasonic techniques have been used to determine the mechanical properties of materials based on their relationship with metallurgical characteristics. In this research work, the relationship between ultrasonic wave velocity, hardness and the microstructure of steel pipeline welded joints is investigated. Measurements of ultrasonic wave velocity were made as a function of the location across the weld. Hardness measurements were performed in an attempt to correlate with ultrasonic response. In addition, the coarse and dendritic grain structure of the weld material is extreme and unpredictably anisotropic. Thus, due to the acoustic anisotropy of the crystal, weld material of studied joints is anisotropic too. Such structure is no longer direction-independent to the ultrasonic wave propagation; therefore, the ultrasonic beam deflects and redirects and the wave front becomes distorted. Thus, the use of conventional ultrasonic testing techniques using fixed beam angles is very limited and the application of conventional ultrasonic phased array techniques becomes desirable. This technique is proposed to assist pipeline operators in estimating the hardness through ultrasonic measures to evaluate the susceptibility to stress sulphide cracking and hydrogen-induced cracking due to hard spots in steel pipeline welded joints in service. Sound wave velocity and hardness measurements have been carried out on a steel welded joint. For each section of the welding, weld bead, fusion zone, heat affected zone and base metal were found to correspond particular values of the ultrasound velocity. These results were correlated with electron microscopy observations of the microstructure and sectorial scan view of welded joints by ultrasonic phased array.

  5. Nanoindentation of soft films on hard substrates: Experiments and finite element simulations

    SciTech Connect

    Pharr, G.M.; Tsui, T.Y.; Bolshakov, A.; Hay, J.C.

    1997-12-31

    Experiments and finite element simulations have been performed to examine error measurement of hardness and elastic modulus caused by pile-up when soft films deposited on hard substrates are tested by nanoindentation methods. Pile-up is exacerbated in soft-film/hard-substrate systems by the constraint imposed on plastic deformation in the film by the relatively non-deformable substrate. To experimentally examine pile-up effects, soft aluminum films with thicknesses of 240, 650, and 1700 nm were deposited on hard soda-lime glass substrates and tested by nanoindentation techniques. This system is attractive because the elastic modulus of the film and the substrate are approximately the same, but the substrate is harder than the film by a factor of about ten. Consequently, substrate influences on the indentation load-displacement behavior are manifested primarily by differences in the plastic flow characteristics alone. The elastic modulus of the film/substrate system, as measured by nanoindentation techniques, exhibits an increase with indenter penetration depth which peaks at a value approximately 30% greater than the true film modulus at a penetration depth close to the film thickness. Finite element simulation shows that this unusual behavior is caused by substrate-induced enhancement of pile-up. Finite element simulation also shows that the amount of pile-up increases with increasing penetration depth, and that the pile-up geometry depends on the work-hardening characteristics of the film. Because of these effects, nanoindentation techniques overestimate the true film hardness and elastic modulus by as much as 68% and 35%, respectively, depending on the work-hardening behavior of the film and the indenter penetration depth. The largest errors occur in non-work-hardening materials at penetration depths close to the film thickness, for which substrate-induced enhancement of pile-up is greatest.

  6. Hardness and microstructural variation of Al-Mg-Mn-Sc-Zr alloy.

    PubMed

    Ikeshita, Sumiha; Strodahs, Ansis; Saghi, Zineb; Yamada, Kazuhiro; Burdet, Pierre; Hata, Satoshi; Ikeda, Ken-Ichi; Midgley, Paul A; Kaneko, Kenji

    2016-03-01

    Variations of Vickers hardness were observed in Al-Mg-Mn alloy and Al-Mg-Mn-Sc-Zr alloy at different ageing times, ranging from a peak value of 81.2 HV at 54 ks down to 67.4 HV at 360 ks, below the initial hardness value, 71.8 HV at 0 ks for the case of Al-Mg-Mn-Sc-Zr alloy. Microstructures of samples at each ageing stage were examined carefully by transmission electron microscopes (TEMs) both in two-dimensions and three-dimensions. The presence of different types, densities, and sizes of particles were observed dispersed spherical Al3Sc1-xZrx and also block-shaped Al3Sc precipitates growing along <100>Al with facets {100} and {110} of the precipitates. TEM analysis both in two-dimensions and three-dimensions, performed on various samples, confirmed the direct correlation between the hardness and the density of Al3Sc.

  7. Hardness and microstructural variation of Al-Mg-Mn-Sc-Zr alloy.

    PubMed

    Ikeshita, Sumiha; Strodahs, Ansis; Saghi, Zineb; Yamada, Kazuhiro; Burdet, Pierre; Hata, Satoshi; Ikeda, Ken-Ichi; Midgley, Paul A; Kaneko, Kenji

    2016-03-01

    Variations of Vickers hardness were observed in Al-Mg-Mn alloy and Al-Mg-Mn-Sc-Zr alloy at different ageing times, ranging from a peak value of 81.2 HV at 54 ks down to 67.4 HV at 360 ks, below the initial hardness value, 71.8 HV at 0 ks for the case of Al-Mg-Mn-Sc-Zr alloy. Microstructures of samples at each ageing stage were examined carefully by transmission electron microscopes (TEMs) both in two-dimensions and three-dimensions. The presence of different types, densities, and sizes of particles were observed dispersed spherical Al3Sc1-xZrx and also block-shaped Al3Sc precipitates growing along <100>Al with facets {100} and {110} of the precipitates. TEM analysis both in two-dimensions and three-dimensions, performed on various samples, confirmed the direct correlation between the hardness and the density of Al3Sc. PMID:26748212

  8. Example of quality assurance and optimization system for super hard materials turning

    NASA Astrophysics Data System (ADS)

    Kowalczyk, R.; Zebala, W.

    2014-11-01

    This paper introduces an example of automated intelligent system for super hard materials turning process that works according to a designed algorithm. Main task of the proposed system is to supervise the super hard materials turning process (acronym: ISSSHMT - Intelligent Supervision System of Super Hard Materials Turning) with the maximal metal removal rate Qvmax, the amplitude of natural tool wear and the measurement of values that define the state of the turning process (e.g. magnitude of cutting force, surface quality, temperature in workspace). Based on the measured values it is possible to select the optimal machining parameters (vc, ap, f), for which desired surface quality and dimensional precision can be achieved for the maximal metal removal rate Qvmax. Presented system (ISSSHMT) can be used for any CNC machine - accommodation for workspace and construction of the machine. An example of NC-code program that allows using the data acquired from the ISSSHMT system by a CNC machine control unit is presented. Optimization of the process and cost cutting can be achieved with the usage of proper target functions, for products machined with required precision class.

  9. Thermodynamics of dipolar hard spheres with low-to-intermediate coupling constants.

    PubMed

    Elfimova, Ekaterina A; Ivanov, Alexey O; Camp, Philip J

    2012-08-01

    The thermodynamic properties of the dipolar hard-sphere fluid are studied using theory and simulation. A new theory is derived using a convenient mathematical approximation for the Helmholtz free energy relative to that for the hard-sphere fluid. The approximation is designed to give the correct low-density virial expansion. New theoretical and numerical results for the fourth virial coefficient are given. Predictions of thermodynamic functions for dipolar coupling constants λ=1 and 2 show excellent agreement with simulation results, even at the highest value of the particle volume fraction φ. For higher values of λ, there are deviations at high volume fractions, but the correct low-density behavior is retained. The theory is compared critically against the established thermodynamic perturbation theory; it gives significant improvements at low densities and is more convenient in terms of the required numerics. Dipolar hard spheres provide a basic model for ferrofluids, and the theory is accurate for typical experimental parameters λ

  10. Prediction of tablet hardness based on near infrared spectra of raw mixed powders by chemometrics.

    PubMed

    Otsuka, Makoto; Yamane, Ikuro

    2006-07-01

    The purpose of this research is to elucidate the effect of lubricant mixing on tablet hardness by near-infrared (NIR) chemometrics as a basic study of process analytical technology. Formulation cellulose (F-C) consisted of sulpyrine (SP), microcrystalline cellulose (MC), and magnesium stearate (MgSt). Formulation lactose/starch (F-L) consisted of SP bulk drug powder, spray-dried lactose (SL), corn starch (CS), and MgSt. First, F-L and F-C without MgSt were mixed in a twin-shell mixer for 60 min. MgSt was added to the mixed powder, and was mixed for various mixing times, after which the mixed powders were compressed by 8-mm diameter punch and die. NIR spectra of raw mixed powders of F-L and F-C were taken using a reflection type of Fourier transform NIR spectra spectrometer, and chemometric analysis was performed using principal component regression (PCR). The tablet hardnesses of F-L and F-C decreased with increasing mixing time. All NIR spectra of the mixed powders of F-L and F-C fluctuated depending on mixing time. In order to predict tablet hardness before tablet compression, NIR spectra of F-L and F-C mixed powders were analyzed and evaluated for hardness by PCR. The minimum standard error of cross-validation values could be realized by using five- and six-principal component models, respectively. In the cases of F-L and F-C, the relationships between the actual and predicted tablet hardnesses showed straight lines, respectively. In the regression vectors of F-L and FC, the peaks related to hydrogen groups of SP, CS, and MC appeared as positive peaks. In contrast, the peaks related to hydrocarbon due to MgSt appeared as negative peaks in the regression vectors. The calibration models to evaluate the tablet hardness were obtained based on NIR spectra of raw mixed powders by PCR. This approach to predicting tablet hardness prior to compression could be used as a routine test to indicate the quality of the final product without spending time and energy to produce

  11. INFLUENCE OF POST-CURE TREATMENTS ON HARDNESS AND MARGINAL ADAPTATION OF COMPOSITE RESIN INLAY RESTORATIONS: AN IN VITRO STUDY

    PubMed Central

    Poskus, Laiza Tatiana; Latempa, Antonio Marcelo Accetta; Chagas, Maurício Alves; da Silva, Eduardo Moreira; Leal, Mariana Pareira da Silva; Guimarães, José Guilherme Antunes

    2009-01-01

    Objectives: The purpose of this study was to evaluate the Vickers hardness number (VHN) and the in vitro marginal adaptation of inlay restorations of three hybrid composite resins (Filtek Z250, Opallis and Esthet-X) subjected to two post-cure treatments. Material and Methods: For the microhardness test, three different groups were prepared in accordance with the post-cure treatments: control group (only light cure for 40 s), autoclave group (light cure for 40 s + autoclave for 15 min at 130°C); and microwave group (light cure for 40 s + microwave for 3 min at 450 W). To assess the marginal adaptation, the composite resin was inserted incrementally into a mesial-occlusal-distal cavity brass mold and each increment light-cured for 40 s. A previous reading in micrometers was taken at the cervical wall, using a stereomicroscope magnifying glass equipped with a digital video camera and image-analysis software. Subsequently, the specimens were subjected to the post-cure treatments (autoclave and microwave) and a reading was taken again at the cervical wall. Data were compared using ANOVA for the hardness test, split-plot ANOVA for the adaptation assessment and Tukey's test for multiple comparisons. A significance level of 5% was adopted for all analyses. Results: The post-cure treatments increased the hardness of conventional composites (p<0.001) and the gap values of inlay restorations (p<0.01). Filtek Z250 showed higher hardness (p<0.001) and lower gap values than Opallis and Esthet-X (p<0.05). Gap values did not exceed 90 μm for any of the experimental conditions. Conclusion: The post-cure treatments increased the VHN and the gap values on the cervical floor of composite resin inlays. Moreover, Filtek Z250 showed the best results, with higher hardness and lower gap values. PMID:20027437

  12. Self-healing phenomenon and dynamic hardness of C60-based nanocomposite coatings.

    PubMed

    Penkov, Oleksiy V; Pukha, Volodymyr E; Devizenko, Alexander Yu; Kim, Hae-Jin; Kim, Dae-Eun

    2014-05-14

    The phenomenon of surface self-healing in C60-based polymer coatings deposited by ion-beam assisted physical vapor deposition was investigated. Nanoindentation of the coatings led to the formation of a protrusion rather than an indent. This protrusion was accompanied by an abnormal shape of the force-distance curve, where the unloading curve lies above the loading curve due to an additional force applied in pulling the indenter out of the media. The coatings exhibited a nanocomposite structure that was strongly affected by the ratio of C60 ion and C60 molecular beam intensities during deposition. The coatings also demonstrated the dynamic hardness effect, where the effective value of the hardness depends significantly on the indentation speed.

  13. Theory and computer simulation for the equation of state of additive hard-disk fluid mixtures

    NASA Astrophysics Data System (ADS)

    Barrio, C.; Solana, J. R.

    2001-01-01

    A procedure previously developed by the authors to obtain the equation of state for a mixture of additive hard spheres on the basis of a pure fluid equation of state is applied here to a binary mixture of additive hard disks in two dimensions. The equation of state depends on two parameters which are determined from the second and third virial coefficients for the mixture, which are known exactly. Results are compared with Monte Carlo calculations which are also reported. The agreement between theory and simulation is very good. For the fourth and fifth virial coefficients of the mixture, the equation of state gives results which are also in close agreement with exact numerical values reported in the literature.

  14. Optimization of hard clams, polychaetes, physical disturbance and denitrifying bacteria of removing nutrients in marine sediment.

    PubMed

    Shen, Hui; Thrush, Simon F; Wan, Xihe; Li, Hui; Qiao, Yi; Jiang, Ge; Sun, Ruijian; Wang, LiBao; He, Peimin

    2016-09-15

    Marine organisms are known to play important roles in transforming nutrients in sediments, however, guidelines to optimize sediment restoration are not available. We conducted a laboratory mesocosm experiment to investigate the role of hard clams, polychaetes, the degree of physical disturbance and denitrifying bacterial concentrations in removing total nitrogen (TN), total phosphorus (TP), and total organic carbon (TOC) in marine sediments. Response surface methodology was employed to analyze the results of initial experiments and in a subsequent experiment identified optimal combinations of parameters. Balancing the TN, TP, TOC removal efficiency, our model predicted 39% TN removal, 33% TP removal, and 42% TOC removal for a 14-day laboratory bioremediation trial using hard clams biomass of 1.2kgm(-2), physical disturbance depth of 16.4cm, bacterial density of 0.18Lm(-2), and polychaetes biomass of 0.16kgm(-2), respectively. These results emphasize the value of combining different species in field-based bioremediation.

  15. Equation of state of nonadditive d-dimensional hard-sphere mixtures

    NASA Astrophysics Data System (ADS)

    Santos, A.; López de Haro, M.; Yuste, S. B.

    2005-01-01

    An equation of state for a multicomponent mixture of nonadditive hard spheres in d dimensions is proposed. It yields a rather simple density dependence and constitutes a natural extension of the equation of state for additive hard spheres proposed by us [A. Santos, S. B. Yuste, and M. López de Haro, Mol. Phys. 96, 1 (1999)]. The proposal relies on the known exact second and third virial coefficients and requires as input the compressibility factor of the one-component system. A comparison is carried out both with another recent theoretical proposal based on a similar philosophy and with the available exact results and simulation data in d=1, 2, and 3. Good general agreement with the reported values of the virial coefficients and of the compressibility factor of binary mixtures is observed, especially for high asymmetries and/or positive nonadditivities.

  16. The high density phase of the k-NN hard core lattice gas model

    NASA Astrophysics Data System (ADS)

    Nath, Trisha; Rajesh, R.

    2016-07-01

    The k-NN hard core lattice gas model on a square lattice, in which the first k next nearest neighbor sites of a particle are excluded from being occupied by another particle, is the lattice version of the hard disc model in two dimensional continuum. It has been conjectured that the lattice model, like its continuum counterpart, will show multiple entropy-driven transitions with increasing density if the high density phase has columnar or striped order. Here, we determine the nature of the phase at full packing for k up to 820 302 . We show that there are only eighteen values of k, all less than k  =  4134, that show columnar order, while the others show solid-like sublattice order.

  17. Optimization of hard clams, polychaetes, physical disturbance and denitrifying bacteria of removing nutrients in marine sediment.

    PubMed

    Shen, Hui; Thrush, Simon F; Wan, Xihe; Li, Hui; Qiao, Yi; Jiang, Ge; Sun, Ruijian; Wang, LiBao; He, Peimin

    2016-09-15

    Marine organisms are known to play important roles in transforming nutrients in sediments, however, guidelines to optimize sediment restoration are not available. We conducted a laboratory mesocosm experiment to investigate the role of hard clams, polychaetes, the degree of physical disturbance and denitrifying bacterial concentrations in removing total nitrogen (TN), total phosphorus (TP), and total organic carbon (TOC) in marine sediments. Response surface methodology was employed to analyze the results of initial experiments and in a subsequent experiment identified optimal combinations of parameters. Balancing the TN, TP, TOC removal efficiency, our model predicted 39% TN removal, 33% TP removal, and 42% TOC removal for a 14-day laboratory bioremediation trial using hard clams biomass of 1.2kgm(-2), physical disturbance depth of 16.4cm, bacterial density of 0.18Lm(-2), and polychaetes biomass of 0.16kgm(-2), respectively. These results emphasize the value of combining different species in field-based bioremediation. PMID:27371956

  18. Clusters in sedimentation equilibrium for an experimental hard-sphere-plus-dipolar Brownian colloidal system

    PubMed Central

    Newman, Hugh D.; Yethiraj, Anand

    2015-01-01

    In this work, we use structure and dynamics in sedimentation equilibrium, in the presence of gravity, to examine, via confocal microscopy, a Brownian colloidal system in the presence of an external electric field. The zero field equation of state (EOS) is hard sphere without any re-scaling of particle size, and the hydrodynamic corrections to the long-time self-diffusion coefficient are quantitatively consistent with the expected value for hard spheres. Care is taken to ensure that both the dimensionless gravitational energy, which is equivalent to a Peclet number Peg, and dipolar strength Λ are of order unity. In the presence of an external electric field, anisotropic chain-chain clusters form; this cluster formation manifests itself with the appearance of a plateau in the diffusion coefficient when the dimensionless dipolar strength Λ ~ 1. The structure and dynamics of this chain-chain cluster state is examined for a monodisperse system for two particle sizes. PMID:26323363

  19. Microstructural characterization and hardness properties of electric resistance welding titanium joints for dental applications.

    PubMed

    Ceschini, Lorella; Boromei, Iuri; Morri, Alessandro; Nardi, Diego; Sighinolfi, Gianluca; Degidi, Marco

    2015-06-01

    The electric resistance welding procedure is used to join a titanium bar with specific implant abutments in order to produce a framework directly in the oral cavity of the patient. This investigation studied the effects of the welding process on microstructure and hardness properties of commercially pure (CP2 and CP4) Ti components. Different welding powers and cooling procedures were applied to bars and abutments, normally used to produce the framework, in order to simulate the clinical intraoral welding procedure. The analyses highlighted that the joining process did not induce appreciable changes in the geometry of the abutments. However, because of unavoidable microstructural modifications in the welded zones, the hardness decreased to values lower than those of the unwelded CP2 and CP4 Ti grades, irrespective of the welding environments and parameters. PMID:26045042

  20. Microstructural characterization and hardness properties of electric resistance welding titanium joints for dental applications.

    PubMed

    Ceschini, Lorella; Boromei, Iuri; Morri, Alessandro; Nardi, Diego; Sighinolfi, Gianluca; Degidi, Marco

    2015-06-01

    The electric resistance welding procedure is used to join a titanium bar with specific implant abutments in order to produce a framework directly in the oral cavity of the patient. This investigation studied the effects of the welding process on microstructure and hardness properties of commercially pure (CP2 and CP4) Ti components. Different welding powers and cooling procedures were applied to bars and abutments, normally used to produce the framework, in order to simulate the clinical intraoral welding procedure. The analyses highlighted that the joining process did not induce appreciable changes in the geometry of the abutments. However, because of unavoidable microstructural modifications in the welded zones, the hardness decreased to values lower than those of the unwelded CP2 and CP4 Ti grades, irrespective of the welding environments and parameters.

  1. AeSPoe HARD ROCK LABORATORY

    SciTech Connect

    Svemar, C; Pettersson, S.; Hedman, T.

    2003-02-27

    Aespoe Hard Rock Laboratory (AEHRL) has been constructed in virgin bedrock as part of the development of a deep geological repository for spent nuclear fuel in Sweden, the role being to provide input to the performance assessment, to test engineered barrier systems and to develop and refine full scale methods and machines for construction and operation of the real repository. The AEHRL extends down to 460 m depth with access via both ramp and shaft. Work in the laboratory has been separated into 4 different stage goals: (1) Verification of site investigation methods. (2) Development of detailed investigation methodology. (3) Testing of models for description of the barrier function of the host rock. (4) Demonstration of technology for and function of important parts of the repository system Stage goals 1 and 2 were in focus during the period 1986-95 and are now completed. Stage goal 1 concerns investigations carried out from ground surface and stage goal 2 investigations carried out underground, in this case during excavation of the ramp. The present work is focused on the two operative stage goals 3 and 4. The activities on barrier function of the host rock comprises primarily in-situ tests with tracer migration in natural fractures and migration of actinides in small samples of rock or bentonite inside a chemical laboratory probe installed in a borehole. The data collected from the tests are used for model development and verification. The demonstration of technology includes studies of engineered barriers and comprises tests of copper stability, bentonite buffer, backfill, plugging and practical development of the main disposal sequences. Up today five full scale deposition holes with buffer and canister, and one full-scale test of backfill and plugging have been installed. The prototype for the deposition machine is in operation. The work is conducted in an international environment and altogether eight organizations from seven countries besides Sweden take

  2. The uptake of water hardness metals by human hair.

    PubMed

    Evans, A O; Marsh, J M; Wickett, R R

    2011-01-01

    The objective of this work was to examine the variables that influence the interaction between water hardness metals and human hair. Hair extracts various constituents from the tap water used during daily hygiene practices and chemical treatments. Calcium and magnesium metal ions are the most prevalent and give water "hardness." Inductively coupled plasma atomic emission spectroscopy (ICP-AES) was employed to quantify the metal content of hair, which was studied as a function of the following variables: hair condition (oxidative damage), level of water hardness, and water pH. We have demonstrated that these variables impact water hardness metal uptake to varying extents, and the effects are driven primarily by the binding capacity (available anionic sites) of the hair. The condition of the hair, a key representation of the binding capacity, was most influential. Interestingly, water hardness levels had only a small effect on uptake; hair became saturated with notable amounts of water hardness metals even after repeated exposure to soft water. Water pH influenced metal uptake since side chains of hair proteins deprotonate with increasing alkalinity. These insights highlight the importance to the hair care industry of understanding the interaction between water hardness metals and hair.

  3. Low hardness organisms: Culture methods, sensitivities, and practical applications

    SciTech Connect

    DaCruz, A.; DaCruz, N.; Bird, M.

    1995-12-31

    EPA Regulations require biomonitoring of permitted effluent and stormwater runoff. Several permit locations were studied, in Virginia, that have supply water and or stormwater runoff which ranges in hardness from 5--30 mg/L. Ceriodaphnia dubia (dubia) and Pimephales promelas (fathead minnow) were tested in reconstituted water with hardnesses from 5--30 mg/L. Results indicated osmotic stresses present in the acute tests with the fathead minnow as well as chronic tests for the dubia and the fathead minnow. Culture methods were developed for both organism types in soft (30 mg) reconstituted freshwater. Reproductivity and development for each organisms type meets or exceeds EPA testing requirements for moderately hard organisms. Sensitivities were measured over an 18 month interval using cadmium chloride as a reference toxicant. Additionally, sensitivities were charted in contrast with those of organisms cultured in moderately hard water. The comparison proved that the sensitivities of both the dubia and the fathead minnow cultured in 30 mg water increased, but were within two standard deviations of the organism sensitivities of those cultured in moderately hard water. Latitude for use of organisms cultured in 30 mg was documented for waters ranging in hardness from 10--100 mg/L with no acclimation period required. The stability of the organism sensitivity was also validated. The application was most helpful in stormwater runoff and in effluents where the hardness was 30 mg/L or less.

  4. Manifold-valued Dirichlet Processes

    PubMed Central

    Kim, Hyunwoo J.; Xu, Jia; Vemuri, Baba C.; Singh, Vikas

    2016-01-01

    Statistical models for manifold-valued data permit capturing the intrinsic nature of the curved spaces in which the data lie and have been a topic of research for several decades. Typically, these formulations use geodesic curves and distances defined locally for most cases — this makes it hard to design parametric models globally on smooth manifolds. Thus, most (manifold specific) parametric models available today assume that the data lie in a small neighborhood on the manifold. To address this ‘locality’ problem, we propose a novel nonparametric model which unifies multivariate general linear models (MGLMs) using multiple tangent spaces. Our framework generalizes existing work on (both Euclidean and non-Euclidean) general linear models providing a recipe to globally extend the locally-defined parametric models (using a mixture of local models). By grouping observations into sub-populations at multiple tangent spaces, our method provides insights into the hidden structure (geodesic relationships) in the data. This yields a framework to group observations and discover geodesic relationships between covariates X and manifold-valued responses Y, which we call Dirichlet process mixtures of multivariate general linear models (DP-MGLM) on Riemannian manifolds. Finally, we present proof of concept experiments to validate our model. PMID:26973982

  5. Does the temperature of beverages affect the surface roughness, hardness, and color stability of a composite resin?

    PubMed Central

    Tuncer, Duygu; Karaman, Emel; Firat, Esra

    2013-01-01

    Objective: To investigate the effect of beverages’ temperature on the surface roughness, hardness, and color stability of a composite resin. Materials and Methods: Fifty specimens of the Filtek Z250 composite (3M ESPE, Dental Products, St.Paul, MN, USA) were prepared and initial roughness, microhardness, and color were measured. Then the specimens were randomly divided into five groups of 10 specimens each: Coffee at 70°C, coffee at 37°C, cola at 10°C, cola at 37°C, and artificial saliva (control). After the samples were subjected to 15 min × 3 cycles per day of exposure to the solutions for 30 days, the final measurements were recorded. Results: After immersion in beverages, the artificial saliva group showed hardness values higher than those of the other groups (P < 0.001) and the microhardness values were significantly different from the initial values in all groups except for the control group. Both cola groups showed roughness values higher than the baseline values (P < 0.05), while the other groups showed values similar to the baseline measurements. When ΔE measurements were examined, the 70°C coffee group showed the highest color change among all the groups (P < 0.05). Conclusion: High-temperature solutions caused alterations in certain properties of composites, such as increased color change, although they did not affect the hardness or roughness of the composite resin material tested. PMID:24883021

  6. Hard Photodisintegration of Proton Pairs in {sup 3}He

    SciTech Connect

    Piasetzky, Eli; Pomerantz, Ishay; Higinbotham, D.; Strauch, S.; Gilman, R.

    2008-10-13

    Hard deuteron photodisintegration has been investigated for 20 years, as its cross section follows the constituent counting rule and it provides insight into the interplay between hadronic and quark-gluon degrees of freedom in high-momentum transfer exclusive reactions. We have now measured for the first time hard pp-pair disintegration in the reaction {gamma}{sup 3}He{yields}pp+n, using kinematics corresponding to a spectator neutron. Cross sections were measured for 90 deg. c.m. at 8 beam energies, from 0.8 to 4.7 GeV. Preliminary results will be presented and compared to the hard deuteron photodisintegration data.

  7. Connection between micro and macro hardness pearlitic-ferritic steel

    NASA Astrophysics Data System (ADS)

    Duka, Edlira; Oettel, Heinrich; Dilo, Teuta

    2012-09-01

    Many physical and mechanical properties of materials are closely related to their microstructure, technologies to control the microstructure of materials have been well developed to obtain suitable properties. We measured the volume fraction of perlite and ferrite, micro Vickers hardness in pearlite and ferrite and macro hardness using different sample with different carbon content. The volume fraction of pearlite increases by increasing carbon content. By increasing carbon content, micro and macro hardness increase. We can conclude that for those conditional the mixing rule can't be use.

  8. Maslow and Values Education

    ERIC Educational Resources Information Center

    Farmer, Rodney

    1978-01-01

    Identifies major value bases which have been used to teach values in the classroom and outlines a values education program which stresses teaching about values without indoctrination. Based upon the hierarchy of human needs developed by psychologist Abraham Maslow, the program is based upon universal values, basic human needs, and recognition of…

  9. Perpendicular recording media for hard disk drives

    NASA Astrophysics Data System (ADS)

    Piramanayagam, S. N.

    2007-07-01

    Perpendicular recording technology has recently been introduced in hard disk drives for computer and consumer electronics applications. Although conceptualized in the late 1970s, making a product with perpendicular recording that has competing performance, reliability, and price advantage over the prevalent longitudinal recording technology has taken about three decades. One reason for the late entry of perpendicular recording is that the longitudinal recording technology was quite successful in overcoming many of its problems and in staying competitive. Other reasons are the risks, problems, and investment needed in making a successful transition to perpendicular recording technology. Iwasaki and co-workers came up with many inventions in the late 1970s, such as single-pole head, CoCr alloy media with a perpendicular anisotropy, and recording media with soft magnetic underlayers [S. Iwasaki and K. Takemura, IEEE Trans. Magn. 11, 1173 (1975); S. Iwasaki and Y. Nakamura, IEEE Trans. Magn. 14, 436 (1978); S. Iwasaki, Y. Nakamura, and K. Ouchi, IEEE Trans. Magn. 15, 1456 (1979)]. Nevertheless, the research on perpendicular recording media has been intense only in the past five years or so. The main reason for the current interest comes from the need to find an alternative technology to get away from the superparamagnetic limit faced by the longitudinal recording. Out of the several recording media materials investigated in the past, oxide based CoCrPt media have been considered a blessing. The media developed with CoCrPt-oxide or CoCrPt -SiO2 have shown much smaller grain sizes, lower noise, and larger thermal stability than the perpendicular recording media of the past, which is one of the reasons for the success of perpendicular recording. Moreover, oxide-based perpendicular media have also overtaken the current longitudinal recording media in terms of better recording performance. Several issues that were faced with the soft underlayers have also been solved by the

  10. A Comparative Clinical Study of the Effect of Denture Cleansing on the Surface Roughness and Hardness of Two Denture Base Materials

    PubMed Central

    Moussa, Amani Ramadan; Dehis, Wessam Mohamed; Elboraey, Asmaa Nabil; ElGabry, Hisham Samir

    2016-01-01

    AIM: This study aimed to verify the influence of oral environment and denture cleansers on the surface roughness and hardness of two different denture base materials. METHODS: A total of sixteen identical removable disc specimens (RDS) were processed. Eight RDS were made from heat-cured acrylic resin (AR) and the other eight were fabricated from thermoplastic injection moulded resin (TR). Surface roughness and hardness of DRS were measured using ultrasonic profilometry and Universal testing machine respectively. Then the four RDS (two AR and two of TR) were fixed to each maxillary denture, after three months RDS were retrieved. Surface roughness and hardness of RDS have measured again. RESULTS: The surface roughness measurements revealed no significant difference (p >0.05) for both disc groups at baseline. However, both groups showed a significant increase in the surface roughness after three months with higher mean value for (TR) group. On the other hand, the (AR) group showed higher hardness mean value than (TR) group at baseline with no significant decrease in the hardness values (p >0.05) following three months follow-up period. CONCLUSIONS: Denture cleansers have an effect on the denture’s surface roughness and hardness concurrently with an oral condition which will consequently influence the complete dentures’ lifetime and patients’ satisfaction. PMID:27703578

  11. Approximate resolution of hard numbering problems

    SciTech Connect

    Bailleux, O.; Chabrier, J.J.

    1996-12-31

    We present a new method for estimating the number of solutions of constraint satisfaction problems. We use a stochastic forward checking algorithm for drawing a sample of paths from a search tree. With this sample, we compute two values related to the number of solutions of a CSP instance. First, an unbiased estimate, second, a lower bound with an arbitrary low error probability. We will describe applications to the Boolean Satisfiability problem and the Queens problem. We shall give some experimental results for these problems.

  12. Comparative study of carp otolith hardness: lapillus and asteriscus.

    PubMed

    Ren, Dongni; Meyers, Marc André; Zhou, Bo; Feng, Qingling

    2013-05-01

    Otoliths are calcium carbonate biominerals in the inner ear of vertebrates; they play a role in balance, movement, and sound perception. Two types of otoliths in freshwater carp are investigated using nano- and micro-indentation: asteriscus and lapillus. The hardness, modulus, and creep of asteriscus (vaterite crystals) and lapillus (aragonite crystals) are compared. The hardness and modulus of lapillus are higher than those of asteriscus both in nano- and micro-testing, which is attributed to the different crystal polymorphs. Both materials exhibit a certain degree of creep, which indicates some time dependence of the mechanical behavior and is attributed to the organic components. The nano-indentation hardnesses are higher than micro-hardnesses for both otoliths, a direct result of the scale dependence of strength; fewer flaws are encountered by the nano than by the microindenter.

  13. Hard-real-time resource management for autonomous spacecraft

    NASA Technical Reports Server (NTRS)

    Gat, E.

    2000-01-01

    This paper describes tickets, a computational mechanism for hard-real-time autonomous resource management. Autonomous spacecraftcontrol can be considered abstractly as a computational process whose outputs are spacecraft commands.

  14. Equation of state for fused-hard-sphere fluid mixtures

    NASA Astrophysics Data System (ADS)

    Largo, J.; Solana, J. R.

    This paper develops a theoretically-based equation of state for fused-hard-sphere fluid mixtures on the basis of an equation of state previously derived for hard-convex-body fluid mixtures. The equation uses as a reference the equation of state for an equivalent hard-sphere fluid mixture in which each component has the same molecular volume as the effective molecular volume of one of the components of the fused-hard-sphere mixture. The two parameters required by the theory, namely the averaged effective molecular volume of the molecules in the mixture and the corresponding effective non-sphericity parameter, are obtained from the geometrical characteristics of the molecules that form the mixture. The results are, on the whole, in closer agreement with simulation data than those obtained with other theories developed for this kind of mixture.

  15. [QUESTING BEHAVIOR OF HARD TICKS (IXODIDAE) IN ONTOGENESIS].

    PubMed

    Leonovich, S A

    2015-01-01

    Literary and own data on questing behavior of larvae, nymphs, and adults in main genera of hard ticks are analyzed. Evolutionary patterns of this behavior and the role of different life stages in this process are discussed. PMID:26827487

  16. Hard turbulent thermal convection and thermal evolution of the mantle

    NASA Technical Reports Server (NTRS)

    Yuen, D. A.; Hansen, U.; Zhao, W.; Vincent, A. P.; Malevsky, A. V.

    1993-01-01

    Hard turbulent convection is investigated using laboratory experiments and numerical simulations. In Newtonian mantle convection, the appearance of disconnected plumes marks the transition from soft to hard turbulence. For non-Newtonian rheology, the transition to hard turbulence takes place at much lower Nusselt numbers than it does for Newtonian rheology. This has important ramifications for the mantle. Large curvatures are developed in the trajectories of non-Newtonian plumes in the hard turbulent regime, in contrast to the trajectories of Newtonian plumes. When phase transitions are considered, mantle convection tends to become more layered with increasing Rayleigh numbers. The manner of mantle convection might have changed with time from a layered to a more whole mantle type of flow. Superplume events could have been caused by catastrophic overturns associated with strong gravitational instabilities in the transition zone.

  17. New Biologic Drug Tackles Hard-To-Control Asthma

    MedlinePlus

    ... page: https://medlineplus.gov/news/fullstory_160833.html New Biologic Drug Tackles Hard-to-Control Asthma Benralizumab ... 2016 WEDNESDAY, Sept. 7, 2016 (HealthDay News) -- A new injectable drug reduces flare-ups in patients with ...

  18. USE OF FUME SUPPRESSANTS IN HARD CHROMIUM BATHS - QUALITY TESTING

    EPA Science Inventory

    The EPA Common Sense Initiative (CSI) is a cooperative effort of government, industry, environmental and other stakeholder groups to find "cleaner, cheaper, smarter" approaches to environmental management in industrial sectors. The purpose of the project is to help hard chromium ...

  19. CAPSULE REPORT: HARD CHROME FUME SUPPRESSANTS & CONTROL TECHNOLOGIES

    EPA Science Inventory

    All existing information which includes the information extrapolated from the Hard Chrome Pollution Prevention Demonstration Project(s) and other sources derived from plating facilities and industry contacts, will be condensed and featured in this document. At least five chromium...

  20. Vascular changes in hard palate sialolipoma: Sialoangiolipoma or vascular malformation?

    PubMed Central

    Handra-Luca, Adriana

    2015-01-01

    Palate sialolipomas are rare. Less than 10 cases located in the hard palate are reported to our knowledge. We report a case of hard palate sialolipoma, peculiar by the intratumor vascular patterns. A 67-year-old man presented with a 1.5 cm lesion of the oral hard palate. The lesion was surgically resected. On microscopy, the lesion, partly encapsulated, consisted of a proliferation of mature adipocytes containing normal minor salivary gland tissue and branching intratumoral vessels of varied size with irregularly thickened wall and papillary projections or tufts. The microscopic features of the tumor we report suggest that vascular malformation-like patterns may occur in sialolipomas of the hard palate. This morphological vascular peculiarity should be acknowledged since it may represent source of hemorrhage. PMID:26604516

  1. USE OF FUME SUPPRESSANTS IN HARD CHROMIUM BATHS - EMISSION TESTING

    EPA Science Inventory

    The EPA Common Sense Initiative (CSI) is a cooperative effort of government, industry, environmental, and other stakeholder groups to find "cleaner, cheaper, smarter" approaches to environmental management in industrial sectors. The purpose of the project is to assist hard chrome...

  2. Quantitative analyses of the biomineralization of different hard tissues.

    PubMed

    Arnold, S; Plate, U; Wiesmann, H P; Stratmann, U; Kohl, H; Höhling, H J

    2001-06-01

    The primary crystallites of the different developing hard tissues have an apatite structure. However, they have crystal lattice distortions representing an intermediate state between amorphous and fully crystalline. We have applied energy-filtering transmission electron microscopy in the selected area electron diffraction mode to analyse different stages of crystal formation in dentine, bone, enamel and inorganic apatite mineral. We have obtained quantitative information on the degree of crystal lattice distortion using the paracrystal theory of Hosemann and Bagchi. We have found that the early formed crystallites of the hard tissues being analysed have a paracrystalline character comparable to biopolymers. However, with maturation, the lattice fluctuations of the crystallites of the hard tissues bone, enamel and dentine decrease to form a typical (para)crystalline character. Also the decrease of the organic proportion in the matrix corresponds to the decrease of the lattice fluctuation of the crystallites in the different hard tissues during maturation.

  3. Prepulse dependence in hard x-ray generation from microdroplets

    SciTech Connect

    Anand, M.; Kahaly, S.; Kumar, G. Ravindra; Sandhu, A. S.; Gibbon, P.; Krishnamurthy, M.

    2006-04-07

    We report on experiments which show that liquid microdroplets are very efficient in hard x-ray generation. We make a comparative study of hard x-ray emission from 15 {mu}m methanol microdroplets and a plain slab target of similar atomic composition at similar laser intensities. The hard X-ray yield from droplet plasmas is about 35 times more than that obtained from solid plasmas. A prepulse that is about 10ns and at least 2% in intensity of the main pulse is essential for hard x-ray generation from the droplets at about 1015 W cm-2. A hot electron temperature of 36 keV is measured from the droplets at 8 x 1014 W cm-2; three times higher intensity is needed to obtain similar hot electron temperature from solid plasmas that have similar atomic composition. We use 1D-PIC simulation to obtain qualitative correlation to the experimental observations.

  4. Compressibility and hardness of Co-based bulk metallic glass: A combined experimental and density functional theory study

    SciTech Connect

    Wang Jianfeng; Li Ran; Xu Tao; Li Yan; Liu Zengqian; Huang Lu; Hua Nengbin; Zhang Tao; Xiao Ruijuan; Li Gong; Li Yanchun

    2011-10-10

    An incompressible Co{sub 54}Ta{sub 11}B{sub 35} bulk metallic glass (BMG) was investigated using in situ high-pressure synchrotron diffraction and nanoindendation. The elastic constants were deduced from the experiments based on the isotropic model. The Vickers hardness was measured to be 17.1 GPa. The elastic moduli and hardness are the highest values known in BMGs. The theoretically calculated elastic properties by density-functional study were well consistent with experimental measurements. The analysis of charge density and bonding character indicates the covalent character of Co-B and B-B bonds, underlying the unusually high elastic modulus and hardness in this material.

  5. Elasticity of two-dimensional crystals of polydisperse hard disks near close packing: Surprising behavior of the Poisson's ratio

    NASA Astrophysics Data System (ADS)

    Tretiakov, Konstantin V.; Wojciechowski, Krzysztof W.

    2012-05-01

    The equation of state, elastic constants, and Poisson's ratio of a crystalline two-dimensional polydisperse hard disk system were determined in the close packing limit. Monte Carlo simulations in the NpT ensemble with variable shape of the periodic box reveal that the pressure and elastic constants grow with increasing polydispersity. The equation of state and the bulk modulus are well described by the free volume approximation. The latter approximation fails, however, for the shear modulus. The simulations also show that the introduction of any amount of size polydispersity in the hard disk systems causes a discontinuous "jump" of the Poisson's ratio in the close packing limit from the value νδ=0 = 0.1308(22), obtained for equidiameter hard disks, to νδ>0 ≈ 1, estimated for the polydisperse disks.

  6. Spectral evolution of gamma-ray bursts detected by the SIGNE experiment. 1: Correlation between intensity and spectral hardness

    NASA Technical Reports Server (NTRS)

    Kargatis, Vincent E.; Liang, Edison P.; Hurley, Kevin C.; Barat, C.; Eveno, E.; Niel, M.

    1994-01-01

    We study the continuum spectral evolution of 16 gamma-ray bursts detected by the Franco-Soviet SIGNE experiment in 1981-1982 by fitting time resolved (0.5 s) spectra in count space with simple thermal bremsstrahlung and synchrotron models. We find that there is no single characteristic of spectral evolution: we see hard-to-soft, soft-to-hard, luminosity-hardness tracking, and chaotic evolution. We perform correlation studies between instantaneous burst intensity and spectral temperature for seven bursts. While we basically confirm the existence of a correlation between these variables as originally claimed by Golenetskii et al. (1983) we find higher values and a broader range of correlation indices.

  7. Glass formation in a mixture of hard disks and hard ellipses.

    PubMed

    Xu, Wen-Sheng; Duan, Xiaozheng; Sun, Zhao-Yan; An, Li-Jia

    2015-06-14

    We present an event-driven molecular dynamics study of glass formation in two-dimensional binary mixtures composed of hard disks and hard ellipses, where both types of particles have the same area. We demonstrate that characteristic glass-formation behavior appears upon compression under appropriate conditions in such systems. In particular, while a rotational glass transition occurs only for the ellipses, both types of particles undergo a kinetic arrest in the translational degrees of freedom at a single density. The translational dynamics for the ellipses is found to be faster than that for the disks within the same system, indicating that shape anisotropy promotes the translational motion of particles. We further examine the influence of mixture's composition and aspect ratio on the glass formation. For the mixtures with an ellipse aspect ratio of k = 2, both translational and rotational glass transition densities decrease with increasing the disk concentration at a similar rate, and hence, the two glass transitions remain close to each other at all concentrations investigated. By elevating k, however, the rotational glass transition density diminishes at a faster rate than the translational one, leading to the formation of an orientational glass for the ellipses between the two transitions. Our simulations imply that mixtures of particles with different shapes emerge as a promising model for probing the role of particle shape in determining the properties of glass-forming liquids. Furthermore, our work illustrates the potential of using knowledge concerning the dependence of glass-formation properties on mixture's composition and particle shape to assist in the rational design of amorphous materials. PMID:26071719

  8. Hard water softening effect of a baby cleanser

    PubMed Central

    Walters, Russel M; Anim-Danso, Emmanuel; Amato, Stephanie M; Capone, Kimberly A; Mack, M Catherine; Telofski, Lorena S; Mays, David A

    2016-01-01

    Background Hard water is associated with atopic dermatitis (eczema). We wanted to determine if a baby cleanser and its individual components altered free ionized calcium (Ca2+) in a simulated hard water baby bath. For these studies, an in vitro determination of free Ca2+ in a simulated hard water baby bath, and an in vivo exploratory study of free Ca2+ absorption into skin from hard water were performed. Methods Free Ca2+ was measured with an ion-sensitive electrode in vitro in hard water (100–500 ppm, Ca2+) before and after addition of the cleanser and/or its components. In an exploratory study, absorption of Ca2+ into skin from hard water was determined in three female participants (aged 21–29 years). Results At an in-use dilution of 1%, the test cleanser reduced free Ca2+ from ~500 ppm to <200 ppm; a 10% in-use dilution bound virtually all free Ca2+. The anionic surfactant component contributed the most to this effect. In the exploratory in vivo study, we measured a reduction of ~15% in free Ca2+ from simulated hard water over 10 minutes. Conclusion Baby cleansers can bind free Ca2+ and reduce the effective water hardness of bath water. Reducing the amount of free Ca2+ in the water will reduce the availability of the ion for binding to the skin. Altering or reducing free Ca2+ concentrations in bath water may be an important parameter in creating the ideal baby bath. PMID:27789967

  9. Caring for patients who are deaf or hard of hearing.

    PubMed

    Brown, Heather L; Hughes-Bell, Aileen; McDuffie, Anna W

    2015-12-01

    Patients who are deaf and hard of hearing often find the American healthcare system to be inaccessible due to communication barriers. This article describes facilities' and providers' requirements under the Americans with Disabilities Act to provide qualified interpreters and other assistive devices to patients who are deaf or hard of hearing. Removing communication barriers can protect healthcare providers from potential legal action and lets them deliver consistent, quality healthcare to all patients. PMID:26595695

  10. Marine plastic litter as an artificial hard bottom fouling ground

    NASA Astrophysics Data System (ADS)

    Harms, J.

    1990-09-01

    20 fouling organisms were observed on plastic litter dredged from the Elbe estuary during July 1990; 60% of the species were typical sessile hard bottom organisms. Most individuals found on this artificial hard bottom were barnacles ( Balanus crenatus, Elminius modestus), the mussel Mytilus edulis and the polychaete Lanice conchilega. All individuals were juveniles which had settled only recently on the plastics. The earliest settlers were not much older than 4 8 weeks.

  11. Improvement in hardness of soda-lime-silica glass

    NASA Astrophysics Data System (ADS)

    Chakraborty, Riya; De, Moumita; Roy, Sudakshina; Dey, Arjun; Biswas, Sampad K.; Middya, Tapas Ranjan; Mukhopadhyay, Anoop K.

    2012-06-01

    Hardness is a key design parameter for structural application of brittle solids like glass. Here we report for the first time the significant improvement of about 10% in Vicker's hardness of a soda-lime-silica glass with loading rate in the range of 0.1-10 N.s-1. Corroborative dark field optical and scanning electron microscopy provided clue to this improvement through evidence of variations in spatial density of shear deformation band formation as a function of loading rate.

  12. Semi empirical hardness predictive model for AZ91 nanocomposite

    NASA Astrophysics Data System (ADS)

    Zaidi, N. H. A.; Jamaludin, S. B.; Zaidi, A. M. A.; Ahmad, K. R.

    2016-07-01

    AZ91 nanocomposite was exposed to several heat treatment processes and the effect of precipitation hardening on hardness was studied as a function of time and temperature. The investigation shows the significant of time and temperature are the main role in the precipitation hardening process of the nanocomposite. Kinetics study show a deceptive activation energy of 21 kJ/mol of the AZ91 nanocomposite. A relationship was derived to predict the maximum hardness at given time and temperature.

  13. The Hard X-Ray Sky: Recent Observational Progress

    NASA Technical Reports Server (NTRS)

    Gehrels, Neil; Cannizzo, John K.

    2010-01-01

    The last fifty years have witnessed the birth, development, and maturation to full potential of hard X-ray astrophysics. The primary force driving the history of the field has been the development of space-based instrumentation optimized for getting the maximum science out of observations of high-energy photons from astrophysical sources. Hard X-ray telescopes are leading research in areas such as galactic diffuse emission, galactic transients, and active galactic nuclei.

  14. The Hard X-ray Sky: Recent Observational Progress

    SciTech Connect

    Gehrels, Neil

    2009-05-11

    The last fifty years have witnessed the birth, development, and maturation to full potential of hard X-ray astrophysics. The primary force driving the history of the field has been the development of space-based instrumentation optimized for getting the maximum science out of observations of high-energy photons from astrophysical sources. Hard X-ray telescopes are leading research in areas such as galactic diffuse emission, galactic transients, and active galactic nuclei.

  15. Palaeoecology and evolution of marine hard substrate communities

    NASA Astrophysics Data System (ADS)

    Taylor, P. D.; Wilson, M. A.

    2003-07-01

    Marine organisms have occupied hard substrates since the Archaean. Shells, rocks, wood and sedimentary hardgrounds offer relatively stable habitats compared to unconsolidated sediments, but the plants and animals which inhabit them must develop means to gain and defend this premium attachment space. Hard substrate communities are formed by organisms with a variety of strategies for adhering to and/or excavating the substrates they inhabit. While mobile grazers, organically attached and even soft-bodied organisms may leave evidence of their former presence in ancient hard substrate communities, a superior fossil record is left by sessile encrusters with mineralised skeletons and by borers which leave trace fossils. Furthermore, encrusters and borers are preserved in situ, retaining their spatial relationships to one another and to the substrate. Spatial competition, ecological succession, oriented growth, and differential utilisation of exposed vs. hidden substrate surfaces can all be observed or inferred. Hard substrate communities are thus excellent systems with which to study community evolution over hundreds of millions of years. Here we review the research on modern and ancient hard substrate communities, and point to some changes that have affected them over geological time scales. Such changes include a general increase in bioerosion of hard substrates, particularly carbonate surfaces, through the Phanerozoic. This is, at least in part, analogous to the infaunalisation trends seen in soft substrate communities. Encrusting forms show an increase in skeletalisation from the Palaeozoic into the Mesozoic and Cenozoic, which may be a response to increasing levels of predation. Hard substrate communities, considering borers and encrusters together, show a rough increase in tiering through the Phanerozoic which again parallels trends seen in soft substrate communities. This extensive review of the literature on living and fossil hard substrate organisms shows that

  16. Hard X-Ray Emission from X-Ray Bursters

    NASA Technical Reports Server (NTRS)

    Halpern, Jules P.; Kaaret, Philip

    1999-01-01

    The scientific goal of this project is to study the hard x-ray emission from x-ray bursters. One target of opportunity observation was made for this investigation during 1997. We obtained 38ks of data on the source 4UI705-44. The project is closely related to "Monitoring x-ray emission from x-ray bursters", and "Long-Term Hard X-Ray Monitoring of X-Ray Bursters."

  17. Neural network based detection of hard exudates in retinal images.

    PubMed

    García, María; Sánchez, Clara I; López, María I; Abásolo, Daniel; Hornero, Roberto

    2009-01-01

    Diabetic retinopathy (DR) is an important cause of visual impairment in developed countries. Automatic recognition of DR lesions in fundus images can contribute to the diagnosis of the disease. The aim of this study is to automatically detect one of these lesions, hard exudates (EXs), in order to help ophthalmologists in the diagnosis and follow-up of the disease. We propose an algorithm which includes a neural network (NN) classifier for this task. Three NN classifiers were investigated: multilayer perceptron (MLP), radial basis function (RBF) and support vector machine (SVM). Our database was composed of 117 images with variable colour, brightness, and quality. 50 of them (from DR patients) were used to train the NN classifiers and 67 (40 from DR patients and 27 from healthy retinas) to test the method. Using a lesion-based criterion, we achieved a mean sensitivity (SE(l)) of 88.14% and a mean positive predictive value (PPV(l)) of 80.72% for MLP. With RBF we obtained SE(l)=88.49% and PPV(l)=77.41%, while we reached SE(l)=87.61% and PPV(l)=83.51% using SVM. With an image-based criterion, a mean sensitivity (SE(i)) of 100%, a mean specificity (SP(i)) of 92.59% and a mean accuracy (AC(i)) of 97.01% were obtained with MLP. Using RBF we achieved SE(i)=100%, SP(i)=81.48% and AC(i)=92.54%. With SVM the image-based results were SE(i)=100%, SP(i)=77.78% and AC(i)=91.04%.

  18. Debris-bed friction of hard-bedded glaciers

    USGS Publications Warehouse

    Cohen, D.; Iverson, N.R.; Hooyer, T.S.; Fischer, U.H.; Jackson, M.; Moore, P.L.

    2005-01-01

    [1] Field measurements of debris-bed friction on a smooth rock tablet at the bed of Engabreen, a hard-bedded, temperate glacier in northern Norway, indicated that basal ice containing 10% debris by volume exerted local shear traction of up to 500 kPa. The corresponding bulk friction coefficient between the dirty basal ice and the tablet was between 0.05 and 0.08. A model of friction in which nonrotating spherical rock particles are held in frictional contact with the bed by bed-normal ice flow can account for these measurements if the power law exponent for ice flowing past large clasts is 1. A small exponent (n < 2) is likely because stresses in ice are small and flow is transient. Numerical calculations of the bed-normal drag force on a sphere in contact with a flat bed using n = 1 show that this force can reach values several hundred times that on a sphere isolated from the bed, thus drastically increasing frictional resistance. Various estimates of basal friction are obtained from this model. For example, the shear traction at the bed of a glacier sliding at 20 m a-1 with a geothermally induced melt rate of 0.006 m a-1 and an effective pressure of 300 kPa can exceed 100 kPa. Debris-bed friction can therefore be a major component of sliding resistance, contradicting the common assumption that debris-bed friction is negligible. Copyright 2005 by the American Geophysical Union.

  19. Curing depth of a resin-modified glass ionomer and two resin-based luting agents.

    PubMed

    Sigemori, Ricardo Massao; Reis, André Figueiredo; Giannini, Marcelo; Paulillo, Luís Alexandre M S

    2005-01-01

    The degree of conversion of resin-based luting agents used for retention of prefabricated posts has been questioned due to the difficulty of light penetration into the resin-filled root canal. This study evaluated the depth of cure of a resin-modified glass ionomer cement (Rely X--3M ESPE) and two resin-based luting agents (Rely X ARC--3M ESPE and Enforce-Dentsply). Twenty-four 14x2x2mm3 specimens were prepared in a Teflon split mold with the three luting agents (n=8). After preparation, the specimens were stored at 37 degrees C in a dark box for 24 hours prior to microhardness testing. Measurements of Knoop hardness were performed at three different depths: superficial, medium and deep thirds. The results (KHN) were statistically analyzed by repeated measures ANOVA and Tukey test (0.05), which showed that resin-based luting agents presented the highest Knoop hardness values within the superficial third. Within the medium third, there were no significant differences among luting materials. However, within the deep third, Rely X presented the highest values. KHN values of resin-based luting agents decreased remarkably as depth increased.

  20. Evaluation of hardness and wear resistance of interim restorative materials

    PubMed Central

    Savabi, Omid; Nejatidanesh, Farahnaz; Fathi, Mohamad Hossein; Navabi, Amir Arsalan; Savabi, Ghazal

    2013-01-01

    Background: The interim restorative materials should have certain mechanical properties to withstand in oral cavity. The aim of this study was to evaluate the hardness and wear resistance of interim restorative materials. Materials and Methods: Fifteen identical rectangular shape specimens with dimensions of 2 mm × 10 mm × 30 mm were made from 7 interim materials (TempSpan, Protemp 3 Garant, Revotek, Unifast LC, Tempron, Duralay, and Acropars). The Vickers hardness and abrasive wear of specimens were tested in dry conditions and after 1 week storage in artificial saliva. The depth of wear was measured using surface roughness inspection device. Data were subjected to Kruskal–Wallis and Mann–Whitney tests. The Pearson correlation coefficient was used to determine the relationship between hardness and wear (α =0.05). Results: TempSpan had the highest hardness. The wear resistance of TempSpan (in dry condition) and Revotek (after conditioning in artificial saliva) was significantly higher (P < 0.05). There was no statistically significant correlation between degree of wear and hardness of the materials (P = 0.281, r = −0.31). Conclusion: Hardness and wear resistance of interim resins are material related rather than category specified. PMID:23946734

  1. Effects of cyclic temperature changes on hardness of composite restoratives.

    PubMed

    Yap, A U J; Wee, K E C; Teoh, S H

    2002-01-01

    The clinical durability of some composite restorative materials may be significantly affected by cyclic temperature changes. This study investigated the effects of cyclic temperature changes on surface hardness of four commercial composite resins (Silux, Z100, Ariston and Surefil). Eighteen specimens of each material were divided into three treatment groups comprising a control and two different thermal cycling regimes. Control specimens were stored in distilled water at 35 degrees C for 178 hours. Thermal cycled specimens were stored in distilled water at 35 degrees C for 173 hours and subjected to five hours (300 cycles) of a thermal cycling regime consisting of the cycle ABAC, where A and B represent the fixed temperatures of 35 degrees C (28 seconds) and 15 degrees C (two seconds) and C, depending on the treatment group, either 45 degrees C or 60 degrees C (two seconds). All specimens were subsequently subjected to hardness testing (KHN) using a digital microhardness tester (load = 500 gf; dwell time = 15 seconds). Results were analyzed using ANOVA/Scheffe's test (p<0.05). The effect of thermal cycling on hardness was material-dependent. While thermal cycling significantly increased the surface hardness of Z100 and Surefil, it significantly decreased the hardness of Ariston. The hardness of Silux was not significantly affected by cyclic temperature changes. For all treatment groups, Z100 was significantly harder than the other composite resins evaluated and Surefil was significantly harder than Silux and Ariston. For both thermal cycled groups, Silux was significantly harder than Ariston.

  2. Electronic mechanism of hardness enhancement in transition-metal carbonitrides

    NASA Astrophysics Data System (ADS)

    Jhi, Seung-Hoon; Ihm, Jisoon; Louie, Steven G.; Cohen, Marvin L.

    1999-05-01

    Transition-metal carbides and nitrides are hard materials widely used for cutting tools and wear-resistant coatings. Their hardness is not yet understood at a fundamental level. A clue may lie in the puzzling fact that transition-metal carbonitrides that have the rock-salt structure (such as TiCxN1-x) have the greatest hardness for a valence-electron concentration of about 8.4 per cell, which suggests that the hardness may be determined more by the nature of the bonding than by the conventional microstructural features that determine the hardness of structural metals and alloys. To investigate this possibility, we have evaluated the shear modulus of various transition-metal carbides and nitrides using ab initio pseudopotential calculations. Our results show that the behaviour of these materials can be understood on a fundamental level in terms of their electronic band structure. The unusual hardness originates from a particular band of σ bonding states between the non-metal p orbitals and the metal d orbitals that strongly resists shearing strain or shape change. Filling of these states is completed at a valence-electron concentration of about 8.4, and any additional electrons would go into a higher band which is unstable against shear deformations.

  3. Hard Braking Events Among Novice Teenage Drivers By Passenger Characteristics

    PubMed Central

    Simons-Morton, Bruce G.; Ouimet, Marie Claude; Wang, Jing; Klauer, Sheila G.; Lee, Suzanne E.; Dingus, Thomas A.

    2010-01-01

    Summary In a naturalistic study of teenage drivers (N = 42) hard braking events of ≤−0.45 g were assessed over the first 6 months of licensure. A total of 1,721 hard braking events were recorded. The video footage of a sample (816) of these events was examined to evaluate validity and reasons for hard braking. Of these, 788 (96.6%) were estimated valid, of which 79.1% were due to driver misjudgment, 10.8% to risky driving behavior, 5.3% to legitimate evasive maneuvers, and 4.8% to distraction. Hard braking events per 10 trips and per 100 miles were compared across passenger characteristics. Hard braking rates per 10 trips among newly licensed teenagers during the first 6 months of licensure were significantly higher when driving with teen passengers and lower with adult passengers than driving alone; rates per 100 miles were lower with adult passengers than with no passengers. Further examination of the results indicates that rates of hard braking with teenage passengers were significantly higher compared with no passengers: 1) for male drivers; 2) during the first month of licensure. The data suggest that that novice teenage driving performance may not be as good or safe when driving alone or with teenage passengers than with adult passengers and provide support for the hypothesis that teenage passengers increase driving risks, particularly during the first month of licensure. PMID:21243109

  4. Mongoose: Creation of a Rad-Hard MIPS R3000

    NASA Technical Reports Server (NTRS)

    Lincoln, Dan; Smith, Brian

    1993-01-01

    This paper describes the development of a 32 Bit, full MIPS R3000 code-compatible Rad-Hard CPU, code named Mongoose. Mongoose progressed from contract award, through the design cycle, to operational silicon in 12 months to meet a space mission for NASA. The goal was the creation of a fully static device capable of operation to the maximum Mil-883 derated speed, worst-case post-rad exposure with full operational integrity. This included consideration of features for functional enhancements relating to mission compatibility and removal of commercial practices not supported by Rad-Hard technology. 'Mongoose' developed from an evolution of LSI Logic's MIPS-I embedded processor, LR33000, code named Cobra, to its Rad-Hard 'equivalent', Mongoose. The term 'equivalent' is used to infer that the core of the processor is functionally identical, allowing the same use and optimizations of the MIPS-I Instruction Set software tool suite for compilation, software program trace, etc. This activity was started in September of 1991 under a contract from NASA-Goddard Space Flight Center (GSFC)-Flight Data Systems. The approach affected a teaming of NASA-GSFC for program development, LSI Logic for system and ASIC design coupled with the Rad-Hard process technology, and Harris (GASD) for Rad-Hard microprocessor design expertise. The program culminated with the generation of Rad-Hard Mongoose prototypes one year later.

  5. Assessing spatial trends of cultural stone weathering intensity using a hardness tester: The case of Manglieu Saint-Sébastien church (France)

    NASA Astrophysics Data System (ADS)

    Roussel, Erwan; Gruson, Soizic; Vautier, Franck; Voldoire, Olivier; André, Marie-Françoise

    2014-05-01

    In heritage science, the quantitative assessment of rock hardness is of primary interest to characterize the degree of weathering of a cultural stone. Modern hardness testers are non-destructive and can be used on cultural heritage materials to collect repeated measurements of rock strength without causing damage. Furthermore, the development of portable solutions such as the Equotip Piccolo 2 facilitates the in situ hardness survey of a whole façade of a monument. It allows to address the question of spatial variability of weathering intensity within a monument, and the mapping of hardness values can reveal strong gradients or discontinuities in stone decay induced by restoration operations. The present study deals with the spatial distribution of stone hardness on the façade of the Saint-Sébastien Romanesque abbey church at Manglieu, in the French Massif Central. It was built during the twelfth century and listed as a protected historic monument in 1840. During the Late 19th century, the lower part of the west-facing wall was restored and the original gneissic material was replaced by granitic ashlars. Since this operation, an intense deterioration has affected the original gneissic stones overlying the granitic base of the wall. Our objective is to quantitatively assess the effect of this restoration on the current spatial trends of the gneiss hardness. Rock strength values were collected using the portable hardness tester Equotip Piccolo 2, and the spatial distribution was investigated at two scales: (i) At the portal scale, the hardness values of all stones were measured based on 30 values per stone; (ii) At the stone scale, a systematic sampling method was performed on two gneissic ashlars in order to collect hardness values over a grid of 9 cm resolution. On each sample, the repeated impact method was performed: 20 consecutive measurements at the same location were collected in order to reconstruct the spatial variation of weathering degree within the

  6. Effect of water hardness on surface tension and dilational visco-elasticity of sodium dodecyl sulphate solutions.

    PubMed

    Fainerman, V B; Lylyk, S V; Aksenenko, E V; Kovalchuk, N M; Kovalchuk, V I; Petkov, J T; Miller, R

    2012-07-01

    The complementary drop and bubble profile analysis and maximum bubble pressure tensiometry are used to measure the dynamic surface tension of aqueous SDS solutions in the presence of hardness salts (CaCl(2) and MgCl(2) in the ratio of 2:1 at concentrations of 6 and 40FH). The presence of hardness salts results in an essential increase of the SDS adsorption activity, which indicates the formation of Ca(DS)(2) and Mg(DS)(2) in the SDS solutions. The surface tension isotherms of SDS in presence of Ca(DS)(2) and Mg(DS)(2) are described using the generalised Frumkin model. The presence of hardness salts accelerates the ageing of SDS solutions as compared with the addition of 0.01 M NaCl due to a faster hydrolysis and hence formation of dodecanol. These results are used to estimate the possible concentration of dodecanol in the studied SDS solutions. The buoyant bubble profile method with harmonic surface oscillations is used to measure the dilational rheology of SDS solutions in presence of hardness salts in the frequency range between 0.005 Hz and 0.2 Hz. The visco-elasticity modulus in the presence of hardness salts is higher as compared with its values in the presence of 0.01 M NaCl additions. The ageing of SDS solutions leads to an essential increase of the visco-elastic modulus.

  7. Heat generation caused by ablation of dental hard tissues with an ultrashort pulse laser (USPL) system.

    PubMed

    Braun, Andreas; Krillke, Raphael Franz; Frentzen, Matthias; Bourauel, Christoph; Stark, Helmut; Schelle, Florian

    2015-02-01

    Heat generation during the removal of dental hard tissues may lead to a temperature increase and cause painful sensations or damage dental tissues. The aim of this study was to assess heat generation in dental hard tissues following laser ablation using an ultrashort pulse laser (USPL) system. A total of 85 specimens of dental hard tissues were used, comprising 45 specimens of human dentine evaluating a thickness of 1, 2, and 3 mm (15 samples each) and 40 specimens of human enamel with a thickness of 1 and 2 mm (20 samples each). Ablation was performed with an Nd:YVO4 laser at 1,064 nm, a pulse duration of 9 ps, and a repetition rate of 500 kHz with an average output power of 6 W. Specimens were irradiated for 0.8 s. Employing a scanner system, rectangular cavities of 1-mm edge length were generated. A temperature sensor was placed at the back of the specimens, recording the temperature during the ablation process. All measurements were made employing a heat-conductive paste without any additional cooling or spray. Heat generation during laser ablation depended on the dental hard tissue (enamel or dentine) and the thickness of the respective tissue (p < 0.05). Highest temperature increase could be observed in the 1-mm thickness group for enamel. Evaluating the 1-mm group for dentine, a significantly lower temperature increase could be measured (p < 0.05) with lowest values in the 3-mm group (p < 0.05). A time delay for temperature increase during the ablation process depending on the material thickness was observed for both hard tissues (p < 0.05). Employing the USPL system to remove dental hard tissues, heat generation has to be considered. Especially during laser ablation next to pulpal tissues, painful sensations and potential thermal injury of pulp tissue might occur.

  8. Equation of state for hard convex body fluids from the equation of state of the hard sphere fluid

    NASA Astrophysics Data System (ADS)

    Maeso, M. J.; Solana, J. R.

    1994-02-01

    A simple and accurate equation of state for fluids of hard convex molecules is derived from the pressure equation and the equation of state of the hard sphere fluid. The equation of state provides theoretical support to some equations of state used in perturbation theories for real molecular liquids. The equation of state reproduces the simulation data with an accuracy comparable to that derived from density functional theory.

  9. A soft-hard combination-based cooperative spectrum sensing scheme for cognitive radio networks.

    PubMed

    Do, Nhu Tri; An, Beongku

    2015-01-01

    In this paper we propose a soft-hard combination scheme, called SHC scheme, for cooperative spectrum sensing in cognitive radio networks. The SHC scheme deploys a cluster based network in which Likelihood Ratio Test (LRT)-based soft combination is applied at each cluster, and weighted decision fusion rule-based hard combination is utilized at the fusion center. The novelties of the SHC scheme are as follows: the structure of the SHC scheme reduces the complexity of cooperative detection which is an inherent limitation of soft combination schemes. By using the LRT, we can detect primary signals in a low signal-to-noise ratio regime (around an average of -15 dB). In addition, the computational complexity of the LRT is reduced since we derive the closed-form expression of the probability density function of LRT value. The SHC scheme also takes into account the different effects of large scale fading on different users in the wide area network. The simulation results show that the SHC scheme not only provides the better sensing performance compared to the conventional hard combination schemes, but also reduces sensing overhead in terms of reporting time compared to the conventional soft combination scheme using the LRT. PMID:25688589

  10. Comparison of Hard Surface and Soft Soil Impact Performance of a Crashworthy Composite Fuselage Concept

    NASA Technical Reports Server (NTRS)

    Sareen, Ashish K.; Sparks, Chad; Mullins, B. R., Jr.; Fasanella, Edwin; Jackson, Karen

    2002-01-01

    A comparison of the soft soil and hard surface impact performance of a crashworthy composite fuselage concept has been performed. Specifically, comparisons of the peak acceleration values, pulse duration, and onset rate at specific locations on the fuselage were evaluated. In a prior research program, the composite fuselage section was impacted at 25 feet per second onto concrete at the Impact Dynamics Research Facility (IDRF) at NASA Langley Research Center. A soft soil test was conducted at the same impact velocity as a part of the NRTC/RITA Crashworthy and Energy Absorbing Structures project. In addition to comparisons of soft soil and hard surface test results, an MSC. Dytran dynamic finite element model was developed to evaluate the test analysis correlation. In addition, modeling parameters and techniques affecting test analysis correlation are discussed. Once correlated, the analytical methodology will be used in follow-on work to evaluate the specific energy absorption of various subfloor concepts for improved crash protection during hard surface and soft soil impacts.

  11. Orientational ordering in hard rectangles: The role of three-body correlations.

    PubMed

    Martínez-Ratón, Yuri; Velasco, Enrique; Mederos, Luis

    2006-07-01

    We investigate the effect of three-body correlations on the phase behavior of hard rectangle two-dimensional fluids. The third virial coefficient B3 is incorporated via an equation of state that recovers scaled particle theory for parallel hard rectangles. This coefficient, a functional of the orientational distribution function, is calculated by Monte Carlo integration, using an accurate parametrized distribution function, for various particle aspect ratios in the range of 1-25. A bifurcation analysis of the free energy calculated from the obtained equation of state is applied to find the isotropic (I)-uniaxial nematic (N(u)) and isotropic-tetratic nematic (N(t)) spinodals and to study the order of these phase transitions. We find that the relative stability of the N(t) phase with respect to the isotropic phase is enhanced by the introduction of B3. Finally, we have calculated the complete phase diagram using a variational procedure and compared the results with those obtained from scaled particle theory and with Monte Carlo simulations carried out for hard rectangles with various aspect ratios. The predictions of our proposed equation of state as regards the transition densities between the isotropic and orientationally ordered phases for small aspect ratios are in fair agreement with simulations. Also, the critical aspect ratio below which the N(t) phase becomes stable is predicted to increase due to three-body correlations, although the corresponding value is underestimated with respect to simulation. PMID:16863310

  12. Correlation between water hardness and cardiovascular diseases in Mostar city, Bosnia and Herzegovina.

    PubMed

    Knezović, Nevenka J; Memić, Mustafa; Mabić, Mirela; Huremović, Jasna; Mikulić, Ivanka

    2014-12-01

    The aim of this study was to determine the association of cardiovascular disease (CVD) of selected human subjects with the hardness of water they consume. Laboratory testing of physical and chemical parameters of water were made using standardized methods: Standard Methods 19th edn, 1995 (APHA, AWWA & WEF, Washington, DC), and ISO 7888:1985, ISO 10523:1998. Pearson's chi-squared test was used for the statistical analysis of data, with the significance level of 0.05. The obtained data were analysed using the statistical program SPSS 16.0. The study sample consisted of 1,021 individuals divided into two groups: soft water consumers, 603 individuals, and, hard water consumers, 618 individuals. Results indicate that a statistically significant (χ(2) = 5.315; df = 1; p = 0.021) number of individuals with CVD drink soft water. The prevalence of CVD in the age group 45-60 years in the study area where soft water is consumed was 21.3% and in the study area where hard water is consumed the prevalence of CVD was 13.7%. The summary results indicate significant correlation between the prevalence of CVD in the population group who drink soft water. The value of the relative risk is 1.127.

  13. Manufacture, microstructure and mechanical properties of Wsbnd Tasbnd N nano-structured hard films

    NASA Astrophysics Data System (ADS)

    Yang, J. F.; Jiang, Y.; Yuan, Z. G.; Wang, X. P.; Fang, Q. F.

    2012-08-01

    W1-xTaxNy (x = 0-0.95) hard films were deposited on Si substrates using reactive direct current magnetron sputtering. The effect of tantalum concentration on phase composition, microstructure, surface morphology, adhesion strength, and hardness of the films has been studied by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, energy dispersive spectroscopy, atomic force microscopy, nano-indenter, and scratch tester. It was found that regardless of tantalum concentration all the W1-xTaxNy films show face centered cubic structure, and form Wsbnd Tasbnd N solid solution. The hardness and Youngs' modulus of W1-xTaxNy films initially increase and then decrease with increasing tantalum concentration, after passing the maximum value of 38 GPa and 360 GPa at x = 0.31, respectively. The adhesion strength of coating to silicon substrate is in the range of 27-35 N, no obvious variation trend of adhesion strength with tantalum concentration was observed.

  14. Study of Flux Ratio of C60 to Ar Cluster Ion for Hard DLC Film deposition

    SciTech Connect

    Miyauchi, K.; Toyoda, N.; Kanda, K.; Matsui, S.; Kitagawa, T.; Yamada, I.

    2003-08-26

    To study the influence of the flux ratio of C60 molecule to Ar cluster ion on (diamond like carbon) DLC film characteristics, DLC films deposited under various flux ratios were characterized with Raman spectrometry and Near Edge X-ray Absorption Fine Structure (NEXAFS). From results of these measurements, hard DLC films were deposited when the flux ratio of C60 to Ar cluster ion was between 0.7 and 4. Furthermore the DLC film with constant sp2 content was obtained in the range of the ratio from 0.7 to 4, which contents are lower values than that of conventional films such as RF plasma. DLC films deposited under the ratio from 1 to 4 had hardness from 40 to 45GPa. It was shown that DLC films with stable properties of low sp2 content and high hardness were formed even when the fluxes were varied from 1 to 4 during deposition. It was indicated that this process was useful in the view of industrial application.

  15. A soft-hard combination-based cooperative spectrum sensing scheme for cognitive radio networks.

    PubMed

    Do, Nhu Tri; An, Beongku

    2015-02-13

    In this paper we propose a soft-hard combination scheme, called SHC scheme, for cooperative spectrum sensing in cognitive radio networks. The SHC scheme deploys a cluster based network in which Likelihood Ratio Test (LRT)-based soft combination is applied at each cluster, and weighted decision fusion rule-based hard combination is utilized at the fusion center. The novelties of the SHC scheme are as follows: the structure of the SHC scheme reduces the complexity of cooperative detection which is an inherent limitation of soft combination schemes. By using the LRT, we can detect primary signals in a low signal-to-noise ratio regime (around an average of -15 dB). In addition, the computational complexity of the LRT is reduced since we derive the closed-form expression of the probability density function of LRT value. The SHC scheme also takes into account the different effects of large scale fading on different users in the wide area network. The simulation results show that the SHC scheme not only provides the better sensing performance compared to the conventional hard combination schemes, but also reduces sensing overhead in terms of reporting time compared to the conventional soft combination scheme using the LRT.

  16. Agricultural Education: Value Adding.

    ERIC Educational Resources Information Center

    Riesenberg, Lou E.; And Others

    1989-01-01

    This issue develops the theme of "Agricultural Education--Value Adding." The concept value adding has been a staple in the world of agricultural business for describing adding value to a commodity that would profit the producer and the local community. Agricultural education should add value to individuals and society to justify agricultural…

  17. Teaching Absolute Value Meaningfully

    ERIC Educational Resources Information Center

    Wade, Angela

    2012-01-01

    What is the meaning of absolute value? And why do teachers teach students how to solve absolute value equations? Absolute value is a concept introduced in first-year algebra and then reinforced in later courses. Various authors have suggested instructional methods for teaching absolute value to high school students (Wei 2005; Stallings-Roberts…

  18. On Literature and Values.

    ERIC Educational Resources Information Center

    Beach, Richard

    In reviewing the ancient, well-worn debate on the relationship between literature and values, it may be seen that the current pedagogical theory of developing response to literature is parallel to the argument for helping students articulate their own values. Two approaches to clarifying values are the values clarification approach (Louis Raths,…

  19. Five Values of Giftedness

    ERIC Educational Resources Information Center

    Besjes-de Bock, Karin M.; de Ruyter, Doret J.

    2011-01-01

    This article describes five values attributed to giftedness. The ascription of values to this phenomenon resembles values attached to gifts in gift-giving processes. Whereas gift-giving often includes expectations of reciprocity, each gift possesses a numerical, utility, social, personal, and intrinsic value. Developmental models of giftedness and…

  20. Rad-Hard, Miniaturized, Scalable, High-Voltage Switching Module for Power Applications Rad-Hard, Miniaturized

    NASA Technical Reports Server (NTRS)

    Adell, Philippe C.; Mojarradi, Mohammad; DelCastillo, Linda Y.; Vo, Tuan A.

    2011-01-01

    A paper discusses the successful development of a miniaturized radiation hardened high-voltage switching module operating at 2.5 kV suitable for space application. The high-voltage architecture was designed, fabricated, and tested using a commercial process that uses a unique combination of 0.25 micrometer CMOS (complementary metal oxide semiconductor) transistors and high-voltage lateral DMOS (diffusion metal oxide semiconductor) device with high breakdown voltage (greater than 650 V). The high-voltage requirements are achieved by stacking a number of DMOS devices within one module, while two modules can be placed in series to achieve higher voltages. Besides the high-voltage requirements, a second generation prototype is currently being developed to provide improved switching capabilities (rise time and fall time for full range of target voltages and currents), the ability to scale the output voltage to a desired value with good accuracy (few percent) up to 10 kV, to cover a wide range of high-voltage applications. In addition, to ensure miniaturization, long life, and high reliability, the assemblies will require intensive high-voltage electrostatic modeling (optimized E-field distribution throughout the module) to complete the proposed packaging approach and test the applicability of using advanced materials in a space-like environment (temperature and pressure) to help prevent potential arcing and corona due to high field regions. Finally, a single-event effect evaluation would have to be performed and single-event mitigation methods implemented at the design and system level or developed to ensure complete radiation hardness of the module.

  1. The noble gases: how their electronegativity and hardness determines their chemistry.

    PubMed

    Furtado, Jonathan; De Proft, Frank; Geerlings, Paul

    2015-02-26

    The establishment of an internally consistent scale of noble gas electronegativities is a long-standing problem. In the present study, the problem is attacked via the Mulliken definition, which in recent years gained widespread use to its natural appearance in the context of conceptual density functional theory. Basic ingredients of this scale are the electron affinity and the ionization potential. Whereas the latter can be computed routinely, the instability of the anion makes the judicious choice of computational technique for evaluating electron affinities much more tricky. We opted for Puiatti's approach, extrapolating the energy of high ε solvent stabilized anions to the ε = 1 (gas phase) case. The results give negative electron affinity values, monotonically increasing (except for helium which is an outlier in most of the story) to almost zero at eka-radon in agreement with high level calculations. The stability of the B3LYP results is successfully tested both via improving the level of theory (CCSD(T)) and expanding the basis set. Combined with the ionization energies (in good agreement with experiment), an electronegativity scale is obtained displaying (1) a monotonic decrease of χ when going down the periodic table, (2) top values not for the noble gases but for the halogens, as opposed to most (extrapolation) procedures of existing scales, invariably placing the noble gases on top, and (3) noble gases having electronegativities close to the chalcogens. In the accompanying hardness scale (hardly, if ever, discussed in the literature) the noble gases turn out to be by far the farthest the hardest elements, again with a continuous decrease with increasing Z. Combining χ value of the halogens and the noble gases the Ng(δ+)F(δ-) bond polarity emerging from ab initio calculations naturally emerges. In conclusion, the chemistry of the noble gases is for a large part determined by their extreme hardness, equivalent to a high resistance to change in its

  2. Non-effect of water hardness on the accumulation and toxicity of copper in a freshwater macrophyte (Ceratophyllum demersum): how useful are hardness-modified copper guidelines for protecting freshwater biota?

    PubMed

    Markich, Scott J; King, Angus R; Wilson, Scott P

    2006-12-01

    Several nations have adopted hardness-modified copper (Cu) guidelines for protecting freshwater biota. However, there is a lack of good quality data and mechanistic understanding on the effects of true water hardness (calcium (Ca) and magnesium (Mg)) on the bioavailability and toxicity of Cu to freshwater biota, particularly macrophytes. This study determined the effect of true water hardness (35, 90 and 335 mg CaCO(3)/l, added as Ca and Mg chloride in a 1:1 mole ratio) on the cell surface binding affinity (log K), accumulation and toxicity (96 h growth (biomass and stem length) and photosynthetic pigment inhibition) of Cu in the free-floating submerged macrophyte, Ceratophyllum demersum, in a synthetic freshwater with constant alkalinity (16 mg CaCO(3)/l) and pH (7.0). There were no significant (P>0.05) differences in the cell surface binding affinity, accumulation or toxicity of Cu in C. demersum with a 10-fold increase in water hardness from 35 to 335 mg CaCO(3)/l. The mean 96 h EC(50) values (and 95% confidence intervals) for biomass, the most sensitive endpoint, were 8.4 (7.6-9.2), 8.9 (8.0-9.8) and 9.9 (9.1-10.7) microg/l Cu for 35, 90 and 335 mg CaCO(3)/l, respectively. Speciation calculations indicated only very small (1-6%) differences in the percentage distribution (i.e. bioavailability) of Cu over the hardness range. These collective results indicate no apparent competition between Cu and Ca/Mg for binding sites on the cell surface. Given that the mechanism of Cu uptake (via Cu-specific and Na-linked transporters) is fundamentally different to that of Cd, Ni, Pb and Zn (via Ca transporters), for which other hardness-dependent algorithms have been developed, it is doubtful whether a hardness-modified Cu guideline value will be sufficiently protective of sensitive freshwater biota, such as C. demersum, particularly in medium-hard fresh surface waters with low levels of dissolved organic carbon. The biotic ligand model offers a more flexible and mechanistic

  3. Non-effect of water hardness on the accumulation and toxicity of copper in a freshwater macrophyte (Ceratophyllum demersum): how useful are hardness-modified copper guidelines for protecting freshwater biota?

    PubMed

    Markich, Scott J; King, Angus R; Wilson, Scott P

    2006-12-01

    Several nations have adopted hardness-modified copper (Cu) guidelines for protecting freshwater biota. However, there is a lack of good quality data and mechanistic understanding on the effects of true water hardness (calcium (Ca) and magnesium (Mg)) on the bioavailability and toxicity of Cu to freshwater biota, particularly macrophytes. This study determined the effect of true water hardness (35, 90 and 335 mg CaCO(3)/l, added as Ca and Mg chloride in a 1:1 mole ratio) on the cell surface binding affinity (log K), accumulation and toxicity (96 h growth (biomass and stem length) and photosynthetic pigment inhibition) of Cu in the free-floating submerged macrophyte, Ceratophyllum demersum, in a synthetic freshwater with constant alkalinity (16 mg CaCO(3)/l) and pH (7.0). There were no significant (P>0.05) differences in the cell surface binding affinity, accumulation or toxicity of Cu in C. demersum with a 10-fold increase in water hardness from 35 to 335 mg CaCO(3)/l. The mean 96 h EC(50) values (and 95% confidence intervals) for biomass, the most sensitive endpoint, were 8.4 (7.6-9.2), 8.9 (8.0-9.8) and 9.9 (9.1-10.7) microg/l Cu for 35, 90 and 335 mg CaCO(3)/l, respectively. Speciation calculations indicated only very small (1-6%) differences in the percentage distribution (i.e. bioavailability) of Cu over the hardness range. These collective results indicate no apparent competition between Cu and Ca/Mg for binding sites on the cell surface. Given that the mechanism of Cu uptake (via Cu-specific and Na-linked transporters) is fundamentally different to that of Cd, Ni, Pb and Zn (via Ca transporters), for which other hardness-dependent algorithms have been developed, it is doubtful whether a hardness-modified Cu guideline value will be sufficiently protective of sensitive freshwater biota, such as C. demersum, particularly in medium-hard fresh surface waters with low levels of dissolved organic carbon. The biotic ligand model offers a more flexible and mechanistic

  4. Viscosity to entropy ratio of QGP in relativistic heavy ion collision: Hard thermal loop corrections

    NASA Astrophysics Data System (ADS)

    Pari, Sharareh Mehrabi; Javidan, Kurosh; Shahri, Fatemeh Taghavi

    2016-06-01

    In this work, we report on our computation results for the best value of the shear viscosity to entropy ratio of quark-gluon plasma produced in the relativistic Au-Au collisions at s NN = 200GeV. Time evolution of heavy quarks distribution functions is calculated by solving the Fokker-Planck evolution equation using the new technique: Iterative Laplace transform method. We compute the drag and diffusion coefficients by considering the hard thermal loop corrections and also temperature dependence running strong coupling, up to complete interactions of leading order.

  5. Ground-state properties of a dilute homogeneous Bose gas of hard disks in two dimensions

    SciTech Connect

    Mazzanti, F.; Polls, A.; Fabrocini, A.

    2005-03-01

    The energy and structure of a dilute hard-disks Bose gas are studied in the framework of a variational many-body approach based on a Jastrow correlated ground-state wave function. The asymptotic behaviors of the radial distribution function and the one-body density matrix are analyzed after solving the Euler equation obtained by a free minimization of the hypernetted chain energy functional. Our results show important deviations from those of the available low density expansions, already at gas parameter values x{approx}0.001. The condensate fraction in 2D is also computed and found generally lower than the 3D one at the same x.

  6. Effects of cold rolling deformation on microstructure, hardness, and creep behavior of high nitrogen austenitic stainless steel

    NASA Astrophysics Data System (ADS)

    Sun, Shi-Cheng; Sun, Gui-Xun; Jiang, Zhong-Hao; Ji, Chang-Tao; Liu, Jia-An; Lian, Jian-She

    2014-02-01

    Effects of cold rolling deformation on the microstructure, hardness, and creep behavior of high nitrogen austenitic stainless steel (HNASS) are investigated. Microstructure characterization shows that 70% cold rolling deformation results in significant refinement of the microstructure of this steel, with its average twin thickness reducing from 6.4 μm to 14 nm. Nanoindentation tests at different strain rates demonstrate that the hardness of the steel with nano-scale twins (nt-HNASS) is about 2 times as high as that of steel with micro-scale twins (mt-HNASS). The hardness of nt-HNASS exhibits a pronounced strain rate dependence with a strain rate sensitivity (m value) of 0.0319, which is far higher than that of mt-HNASS (m = 0.0029). nt-HNASS shows more significant load plateaus and a higher creep rate than mt-HNASS. Analysis reveals that higher hardness and larger m value of nt-HNASS arise from stronger strain hardening role, which is caused by the higher storage rate of dislocations and the interactions between dislocations and high density twins. The more significant load plateaus and higher creep rates of nt-HNASS are due to the rapid relaxation of the dislocation structures generated during loading.

  7. The influence of milling parameters on the material hardness in the case of magnesium alloy AZ61A

    NASA Astrophysics Data System (ADS)

    Grigoraş, C. C.; Brabie, G.

    2015-11-01

    This study was conducted in order to determine the material hardness value due to modification of the milling cutting parameters. The alloy hardness was analysed as a function of different cutting parameters for milling operations (speed, feed and depth of cut), using a face mill. A total number of 17 samples were machined using parameters obtained by combining the input parameters. The total number of combinations is reduced by a preoptimization, using the DesignExpert software. The cutting process was performed in dry conditions, and it was recorded that dry cutting magnesium-aluminium alloy AZ61A with the used parameters did not lead to chip ignition. The surface hardness was determined based on the Vickers scale (HV), its values ranging from 110.59 [HV] to 121.37 [HV]. The obtained results showed that the feed has a significant contribution in the surface harness modification. The application of the Taguchi method reveals that the material hardness can be improved, together with the manufacturing time, by means of the speed, feed and depth of cut maximization.

  8. Investigation of the correlation between the different mechanical properties of resin composites.

    PubMed

    Jun, Soo-Kyung; Kim, Dong-Ae; Goo, Hyo-Jin; Lee, Hae-Hyoung

    2013-01-01

    The aim of this study was to investigate the relationship between the different mechanical properties with the filler fraction of various resin composites. Mechanical properties of eighteen different resin composites were investigated in this study; flexural strength (FS), flexural modulus (FM), fracture toughness (FT), compressive strength (CS), diametral tensile strength (DTS), Barcol hardness (BH), Vickers hardness (HV), and Knoop hardness (HK). The mean values of mechanical properties and the filler fractions (V(f )) obtained from the literature and the manufacturer were analyzed using Pearson's correlation test at p<0.01. The relationships were compared with the data retrieved from previous studies. Strong correlations between Vf and BH/HV/HK and V(f) and FM were evident in the results of the present study and these results were supported by the retrieved data from previous studies. The other relationships between mechanical properties, such as that between FS and FM and between CS and HV were not significant. PMID:23370870

  9. The effect of water hardness on the toxicity of uranium to a tropical freshwater alga Chlorella sp.

    PubMed

    Charles, Amanda L; Markich, Scott J; Stauber, Jennifer L; De Filippis, Lou F

    2002-10-01

    Uranium (U) derived from mining activities is of potential ecotoxicological concern to freshwater biota in tropical northern Australia. Few data are available on the effects of water hardness (Ca and/or Mg), which is elevated in U mine wastewaters, on the toxicity and bioavailability of U to freshwater biota, particularly algae. This study determined the effect of water hardness (8, 40, 100 and 400 mg CaCO(3) x l(-1), added as calcium (Ca) and magnesium (Mg) sulphate) on the toxicity (72 h growth rate inhibition) of U to the unicellular green alga, Chlorella sp., in synthetic freshwater, at constant pH (7.0) and alkalinity (8 mg CaCO(3) x l(-1)), similar in chemical composition to sandy coastal streams in tropical northern Australia. A 50-fold increase in water hardness resulted in a 5-fold decrease (Phardness includes: (i) competition between U and Ca and/or Mg for binding sites on the cell surface; and (ii) a change in U speciation, and hence, bioavailability. Results showed that extracellular (cell-surface) and intracellular U concentrations significantly (P<0.05) decreased (2-5-fold) as water hardness increased from 8 to 400 mg CaCO(3)x l(-1). Calculation of U speciation using the geochemical model HARPHRQ showed that there were no significant (P>0.05) differences in the predicted speciation (% distribution) of U amongst the four water hardness levels. The reduction in U toxicity with increasing water hardness was most likely due to competition between U and Ca and/or Mg for binding sites on the algal cell surface. The minimum detectable effect concentrations of U were approximately 3 and 24 times higher (at 8 and 400 mg CaCO(3)x l(-1) hardness, respectively) than the national interim U guideline value (0.5 micro g x l(-1)) for protecting aquatic ecosystems. Overall, the results reinforce the

  10. Analysis of changes in hardness of a metal surface layer in areas of high stress and methods of determining residual life of parts for mining machines

    NASA Astrophysics Data System (ADS)

    Zvonarev, I. E.; Ivanov, S. L.

    2016-02-01

    The methodological bases for determining the energy resource of mechanical transmissions details for mining machines are considered. Based on the analysis of the accumulation of damage in metal gears, a method of estimating residual life of coarse-toothed wheels by periodically measuring the hardness of the surface layer of the teeth is justified. The regularities in change of hardness of coarse-tooth gear, conditioned by a change in metal strength properties that take into account the micro- and macromechanisms of plastic and elastic deformation, distortion of the metal crystal lattice with formation and movement of vacancies and dislocations. Experimental setup was built and the results of laboratory experiments are given related to the process of destruction of non-standard samples under different loads. Comparison of dimensions and hardness values of the sample allows concluding that a larger deformation corresponds to a greater increase in hardness, their limit value for the material being in the fracture zone. It is established that the detected changes in the local hardness occurs in areas of increased stresses above the limit of proportionality and the work of fracture forces attributed to dislocations density adjacent to the fracture plane expressed in terms of hardness increment is constant.

  11. HARD X-RAY AND MICROWAVE EMISSIONS FROM SOLAR FLARES WITH HARD SPECTRAL INDICES

    SciTech Connect

    Kawate, T.; Nishizuka, N.; Oi, A.; Ohyama, M.; Nakajima, H.

    2012-03-10

    We analyze 10 flare events that radiate intense hard X-ray (HXR) emission with significant photons over 300 keV to verify that the electrons that have a common origin of acceleration mechanism and energy power-law distribution with solar flares emit HXRs and microwaves. Most of these events have the following characteristics. HXRs emanate from the footpoints of flare loops, while microwaves emanate from the tops of flare loops. The time profiles of the microwave emission show delays of peak with respect to those of the corresponding HXR emission. The spectral indices of microwave emissions show gradual hardening in all events, while the spectral indices of the corresponding HXR emissions are roughly constant in most of the events, though rather rapid hardening is simultaneously observed in some for both indices during the onset time and the peak time. These characteristics suggest that the microwave emission emanates from the trapped electrons. Then, taking into account the role of the trapping of electrons for the microwave emission, we compare the observed microwave spectra with the model spectra calculated by a gyrosynchrotron code. As a result, we successfully reproduce the eight microwave spectra. From this result, we conclude that the electrons that have a common acceleration and a common energy distribution with solar flares emit both HXR and microwave emissions in the eight events, though microwave emission is contributed to by electrons with much higher energy than HXR emission.

  12. The nano-hardness and elastic modulus of sound deciduous canine dentin and young premolar dentin--preliminary study.

    PubMed

    Hosoya, Y; Marshall, G W

    2005-01-01

    The purpose of this study was to compare the nano-hardness and elastic modulus among deciduous and permanent dentin, buccal and lingual sides, incisal, center and cervical areas, and outer, middle and inner layers. Three premolars and three deciduous canines were bucco lingually (BL) sectioned, and three deciduous canines were mesio-distally (MD) sectioned parallel to the long axis at the center of the tooth. Hardness (H), plastic hardness (PH) and Young's modulus (Y) were measured using a nano-indentation tester. The H, PH and Y values from the deciduous canine dentin were significantly lower than those from the premolar dentin at most sites. For deciduous canine dentin, the H and PH values of the MD sectioned dentin were significantly higher than those of the BL sectioned dentin in many layers of many areas. Generally deciduous canine dentin had H, PH and Y values that decreased from outer toward the inner layers and significant differences were obtained among the layers in many areas. For MD sectioned deciduous canine and BD sectioned premolar dentin, the H, PH and Y values of the cervical area were significantly lower than those of the incisal and center areas in many layers. It is possible that optimum bonding may require different treatments for deciduous and permanent dentin and perhaps also for different intratooth locations.

  13. Hard palate and retropalatal space in adult Japanese dry skulls.

    PubMed

    Mahmud, S

    1989-08-01

    This is a basic study designed to elucidate the correlation between the lengths of the hard palate and retropalatal space. We also measured the mean lengths of the hard palate and the retropalatal space, emphasizing on measuring the mean proportional lengths of the hard palate and retropalatal space in relation to the total lengths of these two. This osteometric study was done on 89 adult Japanese dry skulls involving, the measurement of five linear dimensions including two modified dimensions. The lengths of the hard palate had a statistically significant correlation with the retropalatal space length. Clinical significance of this study is that, it will be advantageous for the better assessment of the bony anatomy of palatal inadequacy patients, with speech problems, resulting from abnormalities in the palate and the velopharyngeal port. This study also reports a new term "RETROPALATAL SPACE" to represent the gap in the base of dry skulls between the posterior border of the hard palate and the anterior margin of the for-a men magnum.

  14. Investigation of hard magnetic silicone elastomer thin films

    NASA Astrophysics Data System (ADS)

    Yao, Zhongmei; Fang, Ji; Chen, Jackie C.; Wang, Weisong

    2003-01-01

    The hard magnetic materials with a high remnant magnetic moment, Mr, have the unique advantages that can achieve bi-directional (push-pull) movement in an external magnetic field. This paper presents the results on fabrication and testing of the novel hard magnetic silicone elastomer thin films. The micro-size hard ferrite powder, NdFeB powder and different silicone elastomers have been used to fabricate the various large elongation hard magnetic thin films. The uniform thin films range from 40 μm to 216 μm and they are successfully fabricated. Three different fabrication processing have been investigated and the mechanical properties, like Young"s modulus and deflection force, have been evaluated. The simulation results with ANSYS match the experimental data. In comparison to electrostatic or piezoelectric actuation, the magnetic actuation can provide stronger forces and larger deflections. The large elongation hard magnetic thin film provides an excellent diaphragm material, which plays an important role in the micro pump or valve. This film movement has been tested in the external magnetic field, and proved to have large deflections and high performances.

  15. Computational polymer physics: Hard-sphere chain in solvent systems

    NASA Astrophysics Data System (ADS)

    Gautam, Avinash; Gavazzi, Daniel; Taylor, Mark

    2009-10-01

    In this work we present results for chain conformation in two simple chain-in-solvent systems constructed from hard-sphere monomers of diameter D. The first system consists of a flexible chain of fused hard spheres (i.e., bond length L=D) in a monomeric hard-sphere solvent. The second system consists of a flexible tangent hard-sphere chain (L=D) in a dimeric hard-sphere solvent with L=D. These systems are studied using Monte Carlo simulations which employ both single-site crankshaft and multi-site pivot moves to sample the configuration space of the chain. We report chain structure, in terms of site-site probability functions, as a function of solvent density. In all cases, increasing solvent density leads to an overall compression of the chain. At high solvent density the chain conformation is closely coupled to the local solvent structure and we speculate that incommensurate structures may lead to interesting conformational transitions.

  16. Proceedings of the Tungsten Workshop for Hard Target Weapons Program

    SciTech Connect

    Mackiewicz-Ludtka, G.; Hayden, H.W.; Davis, R.M.

    1995-06-01

    The purpose of this meeting was to review and exchange information and provide technical input for improving technologies relevant to the Hard Target Weapons Program. This workshop was attended by representatives from 17 organizations, including 4 Department of Defense (DoD) agencies, 8 industrial companies, and 5 laboratories within DOE. Hard targets are defined as reinforced underground structures that house enemy forces, weapon systems, and support equipment. DOE-ORO and Martin Marietta Energy Systems, Inc. (Energy Systems) have been involved in advanced materials research and development (R&D) for several DOE and DoD programs. These programs are conducted in close collaboration with Eglin AFB, Department of the Army`s Picatinny Arsenal, and other DoD agencies. As part of this ongoing collaboration, Eglin AFB and Oak Ridge National Laboratory planned and conducted this workshop to support the Hard Target Weapons Program. The objectives of this workshop were to (1) review and identify the technology base that exists (primarily due to anti-armor applications) and assess the applicability of this technology to the Hard Target Weapons Program requirements; (2) determine future directions to establish the W materials, processing, and manufacturing technologies suitable for use in fixed, hard target penetrators; and (3) identify and prioritize the potential areas for technical collaboration among the participants.

  17. Exploring Existence Value

    NASA Astrophysics Data System (ADS)

    Madariaga, Bruce; McConnell, Kenneth E.

    1987-05-01

    The notion that individuals value the preservation of water resources independent of their own use of these resources is discussed. Issues in defining this value, termed "existence value," are explored. Economic models are employed to assess the role of existence value in benefit-cost analysis. The motives underlying existence value are shown to matter to contingent valuation measurement of existence benefits. A stylized contingent valuation experiment is used to study nonusers' attitudes regarding projects to improve water quality in the Chesapeake Bay. Survey results indicate that altruism is one of the motives underlying existence value and that goods other than environmental and natural resources may provide existence benefits.

  18. The fitness value of information

    PubMed Central

    Donaldson-Matasci, Matina C.; Bergstrom, Carl T.; Lachmann, Michael

    2013-01-01

    Communication and information are central concepts in evolutionary biology. In fact, it is hard to find an area of biology where these concepts are not used. However, quantifying the information transferred in biological interactions has been difficult. How much information is transferred when the first spring rainfall hits a dormant seed, or when a chick begs for food from its parent? One measure that is commonly used in such cases is fitness value: by how much, on average, an individual’s fitness would increase if it behaved optimally with the new information, compared to its average fitness without the information. Another measure, often used to describe neural responses to sensory stimuli, is the mutual information—a measure of reduction in uncertainty, as introduced by Shannon in communication theory. However, mutual information has generally not been considered to be an appropriate measure for describing developmental or behavioral responses at the organismal level, because it is blind to function; it does not distinguish between relevant and irrelevant information. In this paper we show that there is in fact a surprisingly tight connection between these two measures in the important context of evolution in an uncertain environment. In this case, a useful measure of fitness benefit is the increase in the long-term growth rate, or the fold increase in number of surviving lineages. We show that in many cases the fitness value of a developmental cue, when measured this way, is exactly equal to the reduction in uncertainty about the environment, as described by the mutual information. PMID:25843980

  19. Evaluation of some properties of dental ceramic as affected by different types of lasers and gamma radiations

    NASA Astrophysics Data System (ADS)

    Badr, Yehia; El'Khoudary, M. A.; Annan, Iman

    2004-05-01

    Dental ceramic:Duceram porcelain(Ducera,Dental-Gesellschaft mbH, FrankFurt, Germany) low fusing dental porcelain was subjected in this investigation to different types of laser radiations: a) Nd:YAG laser pulses o 8 ns, 200mJ/pulse for 5&10 minutes b) Tsonamy 70 fs laser pulses for 1 & 5 minutes c)193 nm Excimer laser pulses 6 &13 mJ/pulse for 5 & 10 minutes and finally d) 0.1, 0.3, 0.5 and 1 MRad of Gamma radiations using 10 samples for each type of radiation. Knoop hardness values of test samples were measured using a knoop hardness tester(KHN-Ernst Leitz Wetzlar Germany)showing increased hardness values for all test irradiated samples as compared with the control. Highest hardness value were recorded for Excimer laser 13 mJ/pulse-10 minutes(670kg/mm2 as compared with 410kg/mm2 for the control. On the other hand, the highest value for the transverse strength was obtained for Excimer laser 3.8mJ/pulse-10 minutes). To account for the structural changes occurring due to laser irradiations and leading to the detected here improvement in the mechanical properties we used several techniques which are known to be sensitive to any structural changes such as: x-ray diffraction, SE-Microscopy, FTIR & Raman spectroscopy. Our observations showed series of variations indicating good accordance in the introduced here results. A reasonable interpretation is given here for the effects and variations observed in our measurements and spectra as a result of both Gamma and Laser irradiation. Finally, the given here results indicated that Laser irradiation can be used as a powerful tool for improving the hardness and transverse strength of dental ceramic.

  20. Share Your Values

    MedlinePlus

    ... Español Text Size Email Print Share Share Your Values Page Content Article Body Today, teenagers are bombarded ... mid-twenties. The Most Effective Way to Instill Values? By Example Your words will carry more weight ...