NASA Technical Reports Server (NTRS)
Pinelli, Thomas E.; Barclay, Rebecca O.; Kennedy, John M.
1994-01-01
The U.S. government technical report is a primary means by which the results of federally funded research and development (R&D) are transferred to the U.S. aerospace industry. However, little is known about this information product in terms of its actual use, importance, and value in the transfer of federally funded R&D. To help establish a body of knowledge, the U.S. government technical report is being investigated as part of the NASA/DOD Aerospace Knowledge Diffusion Research Project. In this report, we summarize the literature on technical reports and provide a model that depicts the transfer of federally funded aerospace R&D via the U.S. government technical report. We present results from our investigation of aerospace knowledge diffusion vis-a-vis the U.S. government technical report, and present the results of research that investigated aerospace knowledge diffusion vis-a-vis U.S. academic librarians and technical information specialists as information intermediaries.
NASA Technical Reports Server (NTRS)
Pinelli, Thomas E.; Barclay, Rebecca O.; Kennedy, John M.
1994-01-01
The U.S. government technical report is a primary means by which the results of federally funded research and development (R&D) are transferred to the U.S. aerospace industry. However, little is known about this information product in terms of its actual use, importance, and value in the transfer of federally funded R&D. To help establish a body of knowledge, the U.S. government technical report is being investigated as part of the NASA/DOD Aerospace Knowledge Diffusion Research Project. In this report, we summarize the literature on technical reports and provide a model that depicts the transfer of federally funded aerospace R&D via the U.S. government technical report. We present results from our investigation of aerospace knowledge diffusion vis-a-vis the U.S. government technical report, and present the results of research that investigated aerospace knowledge diffusion vis-a-vis U.S. aerospace engineering faculty and students.
NASA Technical Reports Server (NTRS)
Pinelli, Thomas E.; Barclay, Rebecca O.; Kennedy, John M.
1995-01-01
The U.S. government technical report is a primary means by which the results of federally funded research and development (R&D) are transferred to the U.S. aerospace industry. However, little is known about this information product in terms of its actual use, importance, and value in the transfer of federally funded R&D. To help establish a body of knowledge, the U.S. government technical report is being investigated as part of the NASA/DOD Aerospace Knowledge Diffusion Research Project. In this report, we summarize the literature on technical reports and provide a model that depicts the transfer of federally funded aerospace R&D via the U.S. government technical report. We present results from our investigation of aerospace knowledge diffusion vis-a-vis the U.S. government technical report, and present the results of research that investigated aerospace knowledge diffusion vis-a-vis the technical communications practices of U.S. aerospace engineers and scientists who are members of the American Institute of Aeronautics and Astronautics (AIAA).
NASA Technical Reports Server (NTRS)
Pinelli, Thomas E.; Barclay, Rebecca O.; Kennedy, John M.
1994-01-01
The U.S. government technical report is a primary means by which the results of federally funded research and development (R&D) are transferred to the U.S. aerospace industry. However, little is known about this information product in terms of its actual use, importance, and value in the transfer of federally funded R&D. To help establish a body of knowledge, the U.S. government technical report is being investigated as part of the NASA/DOD Aerospace Knowledge Diffusion Research Project. In this report, we summarize the literature on technical reports and provide a model that depicts the transfer of federally funded aerospace R&D via the U.S. government technical report. We present results from our investigation of aerospace knowledge diffusion vis-a-vis the U.S. government technical report, and present the results of research that investigated aerospace knowledge diffusion vis-a-vis the technical communications practices of U.S. aerospace engineers and scientists affiliated with the Society of Automotive Engineers (SAE).
NASA Technical Reports Server (NTRS)
Pinelli, Thomas E.; Barclay, Rebecca O.; Kennedy, John M.
1994-01-01
The U.S. government technical report is a primary means by which the results of federally funded research and development (R&D) are transferred to the U.S. aerospace industry. However, little is known about this information product in terms of its actual use, importance, and value in the transfer of federally funded R&D. To help establish a body of knowledge, the U.S. government technical report is being investigated as part of the NASA/DOD Aerospace Knowledge Diffusion Research Project. In this report, we summarize the literature on technical reports and provide a model that depicts the transfer of federally funded aerospace R&D via the U.S. government technical report. We present results from our investigation of aerospace knowledge diffusion vis-a-vis the U.S. government technical report, and present the results of research that investigated aerospace knowledge diffusion vis-a-vis the technical communications practices of British aerospace engineers and scientists.
NASA Technical Reports Server (NTRS)
Pinelli, Thomas E.; Barclay, Rebecca O.; Kennedy, John M.
1994-01-01
The U.S. government technical report is a primary means by which the results of federally funded research and development (R&D) are transferred to the U.S. aerospace industry. However, little is known about this information product in terms of its actual use, importance, and value in the transfer of federally funded R&D. To help establish a body of knowledge, the U.S. government technical report is being investigated as part of the NASA/DoD Aerospace Knowledge Diffusion Research Project. In this report, we summarize the literature on technical reports and provide a model that depicts the transfer of federally funded aerospace R&D via the U.S. government technical report. We present results from our investigation of aerospace knowledge diffusion vis-a-vis the U.S. government technical report, and present the results of research that investigated aerospace knowledge diffusion vis-a-vis U.S. aerospace industry librarians and technical information specialists as information intermediaries.
NASA Technical Reports Server (NTRS)
Pinelli, Thomas E.; Barclay, Rebecca O.; Kennedy, John M.
1996-01-01
The U.S. government technical report is a primary means by which the results of federally funded research and development (R&D) are transferred to the U.S. aerospace industry. However, little is known about this information product in terms of its actual use, importance, and value in the transfer of federally funded R&D. To help establish a body of knowledge, the U.S. government technical report is being investigated as part of the NASA/DOD Aerospace Knowledge Diffusion Research Project. In this report, we summarize the literature on technical reports and provide a model that depicts the transfer of federally funded aerospace R&D via the U.S. government technical report. We present results from our investigation of aerospace knowledge diffusion vis-a-vis the U.S. government technical report, and present the results of research that investigated aerospace knowledge diffusion vis-a-vis the technical communication practices of U.S. aerospace engineers and scientists who were members of the Society of Manufacturing Engineers.
NASA Technical Reports Server (NTRS)
Pinelli, Thomas E.; Barclay, Rebecca O.; Kennedy, John M.
1995-01-01
The U.S. government technical report is a primary means by which the results of federally funded research and development (R&D) are transferred to the U.S. aerospace industry. However, little is known about this information product in terms of its actual use, importance, and value in the transfer of federally funded R&D. To help establish a body of knowledge, the U.S. government technical report is being investigated as part of the NASA/DOD Aerospace Knowledge Diffusion Research Project. In this report, we summarize the literature on technical reports and provide a model that depicts the transfer of federally funded aerospace R&D via the U.S. government technical report. We present results from our investigation of aerospace knowledge diffusion vis-a-vis the U.S. government technical report, and present the results of research that investigated aerospace knowledge diffusion vis-a-vis the production and use of information by U.S. aerospace engineers and scientists who had changed their American Institute of Aeronautics and Astronautics (AIAA) membership from student to professional in the past five years.
NASA Technical Reports Server (NTRS)
Pinelli, Thomas E.; Barclay, Rebecca O.; Kennedy, John M.
1995-01-01
The U.S. government technical report is a primary means by which the results of federally funded research and development (R&D) are transferred to the U.S. aerospace industry. However, little is known about this information product in terms of its actual use, importance, and value in the transfer of federally funded R&D. To help establish a body of knowledge, the U.S. government technical report is being investigated as part of the NASA/DOD Aerospace Knowledge Diffusion Research Project. In this report, we summarize the literature on technical reports and provide a model that depicts the transfer of federally funded aerospace R&D via the U.S. government technical report. We present results from our investigation of aerospace knowledge diffusion vis-a-vis the U.S. government technical report, and present the results of research that investigated aerospace knowledge diffusion vis-a-vis the technical communications practices of U.S. aerospace engineers and scientists who were assigned to the Research and Technology Group (RTG) at the NASA Langley Research Center in September 1995.
NASA Technical Reports Server (NTRS)
Pinelli, Thomas E.; Khan, A. Rahman; Barclay, Rebecca O.; Kennedy, John M.
1993-01-01
The U.S. government technical report is a primary means by which the results of federally funded research and development (R&D) are transferred to the U.S. aerospace industry. However, little is known about this information product in terms of its actual use, importance, and value in the transfer of federally funded (U.S.) R&D. To help establish a body of knowledge, the U.S. government technical report is being investigated as part of the NASA/DOD Aerospace Knowledge Diffusion Research Project. In this paper, we summarize the literature on technical reports and provide a model that depicts the transfer of federally funded aerospace R&D via the U.S. government technical report. We present results from two surveys (one of five studies) of our investigation of aerospace knowledge diffusion vis-a-vis the U.S. government technical report and close with a brief overview of on-going research into the use of the U.S. government technical report as a rhetorical device for transferring federally funded aerospace R&D.
NASA Technical Reports Server (NTRS)
Pinelli, Thomas E.; Barclay, Rebecca O.; Kennedy, John M.
1994-01-01
The U.S. government technical report is a primary means by which the results of federally funded research and development (R&D) are transferred to the U.S. aerospace industry. However, little is known about this information product in terms of its actual use, importance, and value in the transfer of federally, funded R&D. To help establish a body of knowledge, the U.S. government technical report is being investigated as part of the NASA/DoD Aerospace Knowledge Diffusion Research Project. In this report, we summarize the literature on technical reports and provide a model that depicts the transfer of federally funded aerospace R&D via the U.S. government technical report. We present results from two surveys of our investigation of aerospace knowledge diffusion vis-a-vis the U.S. government technical report and close with a brief overview of on-going research into aerospace knowledge diffusion focusing on the role of the industry-affiliated information intermediary.
NASA Technical Reports Server (NTRS)
Pinelli, Thomas E.; Barclay, Rebecca O.; Kennedy, John M.
1994-01-01
The U.S. government technical report is a primary means by which the results of federally funded research and development (R&D) are transferred to the U.S. aerospace industry. However, little is known about this information product in terms of its actual use, importance, and value in the transfer of federally funded R&D. To help establish a body of knowledge, the U.S. government technical report is being investigated as part of the NASA/DOD Aerospace Knowledge Diffusion Research Project. In this report, we summarize the literature on technical reports and provide a model that depicts the transfer of federally funded aerospace R&D via the U.S. government technical report. We present results from our investigation of aerospace knowledge diffusion vis-a-vis the U.S. government technical communications practices of U.S. aerospace engineers and scientists affiliated with, not necessarily belonging to, the Society of Manufacturing Engineers (SME).
NASA Technical Reports Server (NTRS)
Pinelli, Thomas E.; Barclay, Rebecca O.; Kennedy, John M.
1994-01-01
The U.S. government technical report is a primary means by which the results of federally funded research and development are transferred to the U.S. aerospace industry. However, little is known about this information product in terms of its actual use, importance, and value in the transfer of federally funded R&D. To help establish a body of knowledge, the U.S. government technical report is being investigated as part of the 'NASA/DoD Aerospace Knowledge Diffusion Research Project'. In this report, we summarize the literature on technical reprts and provide a model that depicts the transfer of federally funded aerospace R&D via the U.S. government technical report. We present results from five studies of our investigation of aerospace knowledge diffusion vis-a-vis the U.S. government technical report and close with a brief overview of on-going research into the use of the U.S. government technical report as a rhetorical device for transferring federally funded aerospace R&D.
NASA Technical Reports Server (NTRS)
Pinelli, Thomas E.; Barclay, Rebecca O.; Kennedy, John M.
1996-01-01
The U.S. government technical report is a primary means by which the results of federally funded research and development (R&D) are transferred to the U.S. aerospace industry. However, little is known about this information product in terms of its actual use, importance, and value in the transfer of federally funded R&D. Little is also known about the intermediary-based system that is used to transfer the results of federally funded R&D to the U.S. aerospace industry. To help establish a body of knowledge, the U.S. government technical report is being investigated as part of the NASA/DOD Aerospace Knowledge Diffusion Research Project. In this report, we summarize the literature on technical reports, present a model that depicts the transfer of federally funded aerospace R&D via the U.S. government technical report, and present the results of research that investigated aerospace knowledge diffusion vis-a-vis the technical communication practices of U.S. aerospace engineers and scientists who were members of the American Institute of Aeronautics and Astronautics (AIAA) and identified themselves as educators.
ERIC Educational Resources Information Center
Darr, Dietrich; Pretzsch, Jurgen
2008-01-01
Purpose: The objective of this paper is to assess the effectiveness of innovation diffusion under group-oriented and individual-oriented extension. Current theoretical notions of innovation diffusion in social networks shall be briefly reviewed, and the concepts of "search" and "innovation" vis-a-vis "transfer" and…
NASA Astrophysics Data System (ADS)
Kumar, Raj; Sharma, Vishal
2017-03-01
The present research is focused on the analysis of writing inks using destructive UV-Vis spectroscopy (dissolution of ink by the solvent) and non-destructive diffuse reflectance UV-Vis-NIR spectroscopy along with Chemometrics. Fifty seven samples of blue ballpoint pen inks were analyzed under optimum conditions to determine the differences in spectral features of inks among same and different manufacturers. Normalization was performed on the spectroscopic data before chemometric analysis. Principal Component Analysis (PCA) and K-mean cluster analysis were used on the data to ascertain whether the blue ballpoint pen inks could be differentiated by their UV-Vis/UV-Vis NIR spectra. The discriminating power is calculated by qualitative analysis by the visual comparison of the spectra (absorbance peaks), produced by the destructive and non-destructive methods. In the latter two methods, the pairwise comparison is made by incorporating the clustering method. It is found that chemometric method provides better discriminating power (98.72% and 99.46%, in destructive and non-destructive, respectively) in comparison to the qualitative analysis (69.67%).
Knowledge management in healthcare: towards 'knowledge-driven' decision-support services.
Abidi, S S
2001-09-01
In this paper, we highlight the involvement of Knowledge Management in a healthcare enterprise. We argue that the 'knowledge quotient' of a healthcare enterprise can be enhanced by procuring diverse facets of knowledge from the seemingly placid healthcare data repositories, and subsequently operationalising the procured knowledge to derive a suite of Strategic Healthcare Decision-Support Services that can impact strategic decision-making, planning and management of the healthcare enterprise. In this paper, we firstly present a reference Knowledge Management environment-a Healthcare Enterprise Memory-with the functionality to acquire, share and operationalise the various modalities of healthcare knowledge. Next, we present the functional and architectural specification of a Strategic Healthcare Decision-Support Services Info-structure, which effectuates a synergy between knowledge procurement (vis-à-vis Data Mining) and knowledge operationalisation (vis-à-vis Knowledge Management) techniques to generate a suite of strategic knowledge-driven decision-support services. In conclusion, we argue that the proposed Healthcare Enterprise Memory is an attempt to rethink the possible sources of leverage to improve healthcare delivery, hereby providing a valuable strategic planning and management resource to healthcare policy makers.
Kumar, Raj; Sharma, Vishal
2017-03-15
The present research is focused on the analysis of writing inks using destructive UV-Vis spectroscopy (dissolution of ink by the solvent) and non-destructive diffuse reflectance UV-Vis-NIR spectroscopy along with Chemometrics. Fifty seven samples of blue ballpoint pen inks were analyzed under optimum conditions to determine the differences in spectral features of inks among same and different manufacturers. Normalization was performed on the spectroscopic data before chemometric analysis. Principal Component Analysis (PCA) and K-mean cluster analysis were used on the data to ascertain whether the blue ballpoint pen inks could be differentiated by their UV-Vis/UV-Vis NIR spectra. The discriminating power is calculated by qualitative analysis by the visual comparison of the spectra (absorbance peaks), produced by the destructive and non-destructive methods. In the latter two methods, the pairwise comparison is made by incorporating the clustering method. It is found that chemometric method provides better discriminating power (98.72% and 99.46%, in destructive and non-destructive, respectively) in comparison to the qualitative analysis (69.67%). Copyright © 2016 Elsevier B.V. All rights reserved.
Agustsson, Jon; Akermann, Oliver; Barry, D Andrew; Rossi, Luca
2014-08-01
Water contamination is an important environmental concern underlining the need for reliable real-time information on contaminant concentrations in natural waters. Here, a new non-contact UV-Vis spectroscopic approach for monitoring contaminants in water, and especially wastewater, is proposed. Diffuse reflectance UV-Vis spectroscopy was applied to measure simultaneously the chemical oxygen demand (COD) and turbidity (TUR) concentrations in water. The measurements were carried out in the wavelength range from 200-1100 nm. The measured spectra were analysed using partial-least-squares (PLS) regression. The correlation coefficient between the measured and the reference concentrations of COD and TUR in the water samples were R(2) = 0.85 and 0.96, respectively. These results highlight the potential of non-contact UV-Vis spectroscopy for the assessment of water contamination. A system built on the concept would be able to monitor wastewater pollution continuously, without the need for laborious sample collection and subsequent laboratory analysis. Furthermore, since no parts of the system are in contact with the wastewater stream the need for maintenance is minimised.
Hezri, A A
2004-12-01
Formulation of effective sustainability indicators for national assessment demands a comprehensive understanding of the utilisation, diffusion and dissemination of information in policy processes. To illustrate the dynamic of sustainability assessment within the context of policy processes, this paper uses a case study of national sustainability indicators development in Malaysia. Subsequently, this paper ascribes the limited achievement of national sustainability assessment in Malaysia to four types of constraints: meta-policy issues; technical capacities; communication concerns; and the inherent knowledge gaps within the indicator developer community vis-a-vis their theoretical limitations. It is proposed that such constraints will be encountered in many countries. Drawing from the literature on public policy, this paper outlines a framework for investigating indicator behaviour within policy processes based on well-established concepts such as knowledge utilisation and policy learning. I conclude this paper by elaborating on the corresponding future challenges that must be addressed before effective integration of sustainability indicators within policy systems can occur.
Facing the Knowledge Society: Mexico's Public Universities
ERIC Educational Resources Information Center
Varela-Petito, Gonzalo
2010-01-01
Public higher education in Mexico faces major challenges vis-a-vis its position within the modern knowledge society, sparking concern among educational authorities. In the second half of the 20th century Mexican universities ceased to be selective, elitist schools, becoming, instead, massive institutions that reflect social and intellectual…
Fuji apple storage time rapid determination method using Vis/NIR spectroscopy.
Liu, Fuqi; Tang, Xuxiang
2015-01-01
Fuji apple storage time rapid determination method using visible/near-infrared (Vis/NIR) spectroscopy was studied in this paper. Vis/NIR diffuse reflection spectroscopy responses to samples were measured for 6 days. Spectroscopy data were processed by stochastic resonance (SR). Principal component analysis (PCA) was utilized to analyze original spectroscopy data and SNR eigen value. Results demonstrated that PCA could not totally discriminate Fuji apples using original spectroscopy data. Signal-to-noise ratio (SNR) spectrum clearly classified all apple samples. PCA using SNR spectrum successfully discriminated apple samples. Therefore, Vis/NIR spectroscopy was effective for Fuji apple storage time rapid discrimination. The proposed method is also promising in condition safety control and management for food and environmental laboratories.
Fuji apple storage time rapid determination method using Vis/NIR spectroscopy
Liu, Fuqi; Tang, Xuxiang
2015-01-01
Fuji apple storage time rapid determination method using visible/near-infrared (Vis/NIR) spectroscopy was studied in this paper. Vis/NIR diffuse reflection spectroscopy responses to samples were measured for 6 days. Spectroscopy data were processed by stochastic resonance (SR). Principal component analysis (PCA) was utilized to analyze original spectroscopy data and SNR eigen value. Results demonstrated that PCA could not totally discriminate Fuji apples using original spectroscopy data. Signal-to-noise ratio (SNR) spectrum clearly classified all apple samples. PCA using SNR spectrum successfully discriminated apple samples. Therefore, Vis/NIR spectroscopy was effective for Fuji apple storage time rapid discrimination. The proposed method is also promising in condition safety control and management for food and environmental laboratories. PMID:25874818
Education for Citizenship: A Bicentennial Survey. Citizenship/Social Studies Report.
ERIC Educational Resources Information Center
Education Commission of the States, Denver, CO. National Assessment of Educational Progress.
A survey of student attitudes and knowledge vis a vis the American political system is presented. Student performance in the areas of social behavior, political attitudes, political knowledge, and political education is described for 13- and 17-year-olds for seven variables--geographical region, sex, race, parental education, size and type of…
The Collaboratory Notebook: A Networked Knowledge-Building Environment for Project Learning.
ERIC Educational Resources Information Center
O'Neill, D. Kevin; Gomez, Louis M.
The Collaboratory Notebook, developed as part of the Learning Through Collaborative Visualization Project (CoVis), is a networked, multimedia knowledge-building environment which has been designed to help students, teachers and scientists share inquiry over the boundaries of time and space. CoVis is an attempt to change the way that science is…
Chakraborty, Somsubhra; Weindorf, David C; Morgan, Cristine L S; Ge, Yufeng; Galbraith, John M; Li, Bin; Kahlon, Charanjit S
2010-01-01
In the United States, petroleum extraction, refinement, and transportation present countless opportunities for spillage mishaps. A method for rapid field appraisal and mapping of petroleum hydrocarbon-contaminated soils for environmental cleanup purposes would be useful. Visible near-infrared (VisNIR, 350-2500 nm) diffuse reflectance spectroscopy (DRS) is a rapid, nondestructive, proximal-sensing technique that has proven adept at quantifying soil properties in situ. The objective of this study was to determine the prediction accuracy of VisNIR DRS in quantifying petroleum hydrocarbons in contaminated soils. Forty-six soil samples (including both contaminated and reference samples) were collected from six different parishes in Louisiana. Each soil sample was scanned using VisNIR DRS at three combinations of moisture content and pretreatment: (i) field-moist intact aggregates, (ii) air-dried intact aggregates, (iii) and air-dried ground soil (sieved through a 2-mm sieve). The VisNIR spectra of soil samples were used to predict total petroleum hydrocarbon (TPH) content in the soil using partial least squares (PLS) regression and boosted regression tree (BRT) models. Each model was validated with 30% of the samples that were randomly selected and not used in the calibration model. The field-moist intact scan proved best for predicting TPH content with a validation r2 of 0.64 and relative percent difference (RPD) of 1.70. Because VisNIR DRS was promising for rapidly predicting soil petroleum hydrocarbon content, future research is warranted to evaluate the methodology for identifying petroleum contaminated soils.
Chakraborty, Somsubhra; Weindorf, David C; Li, Bin; Ali Aldabaa, Abdalsamad Abdalsatar; Ghosh, Rakesh Kumar; Paul, Sathi; Nasim Ali, Md
2015-05-01
Using 108 petroleum contaminated soil samples, this pilot study proposed a new analytical approach of combining visible near-infrared diffuse reflectance spectroscopy (VisNIR DRS) and portable X-ray fluorescence spectrometry (PXRF) for rapid and improved quantification of soil petroleum contamination. Results indicated that an advanced fused model where VisNIR DRS spectra-based penalized spline regression (PSR) was used to predict total petroleum hydrocarbon followed by PXRF elemental data-based random forest regression was used to model the PSR residuals, it outperformed (R(2)=0.78, residual prediction deviation (RPD)=2.19) all other models tested, even producing better generalization than using VisNIR DRS alone (RPD's of 1.64, 1.86, and 1.96 for random forest, penalized spline regression, and partial least squares regression, respectively). Additionally, unsupervised principal component analysis using the PXRF+VisNIR DRS system qualitatively separated contaminated soils from control samples. Fusion of PXRF elemental data and VisNIR derivative spectra produced an optimized model for total petroleum hydrocarbon quantification in soils. Copyright © 2015 Elsevier B.V. All rights reserved.
Healthcare knowledge management through building and operationalising healthcare enterprise memory.
Cheah, Y N; Abidi, S S
1999-01-01
In this paper we suggest that the healthcare enterprise needs to be more conscious of its vast knowledge resources vis-à-vis the exploitation of knowledge management techniques to efficiently manage its knowledge. The development of healthcare enterprise memory is suggested as a solution, together with a novel approach advocating the operationalisation of healthcare enterprise memories leading to the modelling of healthcare processes for strategic planning. As an example, we present a simulation of Service Delivery Time in a hospital's OPD.
Language Teacher Associations in Japan: Knowledge Producers and/or Knowledge Disseminators
ERIC Educational Resources Information Center
Stewart, Alison; Miyahara, Masuko
2016-01-01
To investigate the role of language teacher associations (LTAs) vis-à-vis their members, the case of Japan is notable for the apparent disparateness among the more than 50 associations that have formed over the past 90 years. An historical overview reveals that LTAs in Japan have emerged in four distinct waves, and a survey of representative…
On Becoming an Educated Person: Salvadoran Adult Learners' Cultural Model of Educacion/Education
ERIC Educational Resources Information Center
Prins, Esther
2011-01-01
Background/Context: In contrast to cultural constructs that equate education with cognitive development and formal schooling, the Latin American cultural model of educacion encompasses academic knowledge and social competence. Prior scholarship has mainly investigated parental notions of educacion vis-a-vis childrearing and schooling, primarily…
Language Variation and Public School Education vis a vis Jelly Beans and Designer Genes.
ERIC Educational Resources Information Center
Pietras, Thomas P.
Language variation, be it foreign or dialect, receives little tolerance and understanding by the general public. Thus, there are two major challenges for the decade of the 1980s in language arts instruction. The first is for teachers to become thoroughly informed about the nature of language and its role in our society. A knowledge of language…
Sandmann, Henner; Stick, Carsten
2014-01-01
Spatial measurements of the diffusely scattered sky radiance at a seaside resort under clear sky and slightly overcast conditions have been used to calculate the sky radiance distribution across the upper hemisphere. The measurements were done in the summer season when solar UV radiation is highest. The selected wavelengths were 307, 350 and 550 nm representing the UVB, UVA and VIS band. Absolute values of radiance differ considerably between the wavelengths. Normalizing the measured values by use of direct solar radiance made the spatial distributions of unequal sky radiance comparable. The results convey a spatial impression of the different distributions of the radiance at the three wavelengths. Relative scattered radiance intensity is one order of magnitude greater in UVB than in VIS, whereas in UVA lies roughly in between. Under slightly overcast conditions scattered radiance is increased at all three wavelengths by about one order of magnitude. These measurements taken at the seaside underline the importance of diffuse scattered radiance. The effect of shading parts of the sky can be estimated from the distribution of sky radiance. This knowledge might be useful for sun seekers and in the treatment of people staying at the seaside for therapeutic purposes. © 2013 The American Society of Photobiology.
Georgieva, Ivelina; Danchova, Nina; Gutzov, Stoyan; Trendafilova, Natasha
2012-06-01
Theoretical and spectroscopic studies of a series of monomeric and dimeric complexes formed through the modification of a zirconium butoxide precursor with acetylacetone and subsequent hydrolysis and/or condensation have been performed by applying DFT/B3LYP/6-31++G(d) and highly accurate RI-ADC(2) methods as well as IR and UV-Vis transmittance and diffuse reflectance spectroscopies. Based on DFT model calculations and simulated and experimental UV-Vis and IR spectra of all the studied structures, the most probable building units of the Zr(IV)-AcAc gel were predicted: the dimeric double hydroxo-bridged complex Zr(2)(AcAc)(2)(OH)(4)(OH)(2br) 9 and the monooxo-bridged complex Zr(2)(AcAc)(2)(OH)(4)O(br)·2H(2)O 12. In both structures, the two AcAc ligands are coordinated to one Zr atom. It was shown that building units 9 and 12 determine the photophysical and vibrational properties of the gel material. The observed UV-Vis and IR spectra of Zr(IV)-AcAc gel were interpreted and a relation between the spectroscopic and structural data was derived. The observed UV-Vis bands at 315 nm and 298/288 nm were assigned to partial ligand-metal transitions and to intra-/inter-AcAc ligand transitions, respectively.
NASA Astrophysics Data System (ADS)
Li, Hailong; Gao, Yan; Xiong, Zhuo; Liao, Chen; Shih, Kaimin
2018-05-01
A series of Au-g-C3N4 (Au-CN) catalysts were prepared through a NaBH4-reduction method using g-C3N4 (CN) from pyrolysis of urea as precursor. The catalysts' surface area, crystal structure, surface morphology, chemical state, functional group composition and optical properties were characterized by X-ray diffraction, transmission electron microscope, X-ray photoelectron spectroscopy, ultraviolet visible (UV-vis) diffuse reflectance spectra, fourier transform infrared, photoluminescence and transient photocurrent analysis. The carbon dioxide (CO2) photoreduction activities under ultraviolet visible (UV-vis) light irradiation were significantly enhanced when gold (Au) was loaded on the surface of CN. 2Au-CN catalyst with Au to CN mole ratio of 2% showed the best catalytic activity. After 2 h UV-vis light irradiation, the methane (CH4) yield over the 2Au-CN catalyst was 9.1 times higher than that over the pure CN. The CH4 selectivity also greatly improved for the 2Au-CN compared to the CN. The deposited Au nanoparticles facilitated the separation of electron-hole pairs on the CN surface. Moreover, the surface plasmon resonance effect of Au further promoted the generation of hot electrons and visible light absorption. Therefore, Au loading significantly improved CO2 photoreduction performance of CN under UV-vis light irradiation.
ERIC Educational Resources Information Center
AlFuqaha, Isam Najib
2013-01-01
This paper attempts to delineate the frameworks of learner-centered vis-à-vis teacher-centered processes of learning prevalent in the second decade of the twenty-first century. It defines the pedagogical changes that have emerged due to the development of delivery technologies, and the interrelations among teachers, students, and knowledge. The…
Bias Factors in Mathematics Achievement Tests among Israeli Students from the Former Soviet Union
ERIC Educational Resources Information Center
Levi-Keren, Michal
2016-01-01
This study explains mathematical difficulties of students who immigrated from the Former Soviet Union (FSU) vis-à-vis Israeli students, by identifying the existing bias factors in achievement tests. These factors are irrelevant to the mathematical knowledge being measured, and therefore threaten the test results. The bias factors were identified…
NASA Astrophysics Data System (ADS)
Karnan, Thenmozhi; Selvakumar, Stanly Arul Samuel
2016-12-01
In the present study, describes the synthesis of ZnO nanoparticles from rambutan (Nephelium lappaceumL.) peel extract via bio synthesis method and developed a new low cost technology to prepare ZnO nanoparticles. During the synthesis, fruit peel extract act as a natural ligation agent. The successfully prepared product was analyzed with some standard characterization studies like X-Ray Diffraction (XRD), UV-VIS Diffuse reflectance spectra (UV-Vis DRS), Field Emission Scanning Electron Microscope (FESEM), High resolution transmittance electron microscope (HR-TEM), N2 adsorption-desorption isotherm and UV-Vis absorption Spectroscopy. The photocatalytic activity of ZnO nanoparticles was evaluated by photodegradation of methyl orange (MO) dye under UV light and the result depicts around 83.99% decolorisation efficiency at 120 min of illumination. In addition with photodecolorisation, mineralization was also achieved. The mineralization has been confirmed by measuring Chemical Oxygen Demand (COD) values.
Wang, Jia-hua; Qi, Shu-ye; Tang, Zhi-hui; Jia, Shou-xing; Li, Yong-yu
2012-05-01
Visible (Vis)/near infrared (NIR) spectroscopy has been used successfully to measure soluble solids content (SSC) in fruit. However, for practical implementation, the NIR technique needs to be able to compensate for fruit temperature fluctuations, as it was observed that the sample temperature affects the NIR spectrum. A portable Vis/NIR spectrometer was used to collect diffused transmittance spectra of apples at different temperatures (0-30 degrees C). The spectral data of apple at 20 degrees C was used to develop a norm partial least squares (PLS) model. Slope/bias technique was found to well suits to control the accuracy of the calibration model for SSC concerning temperature fluctuations. The correctional PLS models were used to predict the SSC of apple at 0, 10 and 30 degrees C, respectively. The correctional method was found to perform well with Q values of 0.810, 0.822 and 0.802, respectively. When no precautions are taken, the Q value on the SSC may be as small as 0.525-0.680. The results obtained highlight the potential of portable Vis/NIR instruments for assessing internal quality of fruits on site under varying weather conditions.
Application of ZnO Nanoparticle as Sulphide Gas Sensor Using UV/VIS/NIR-Spectrophotometer
NASA Astrophysics Data System (ADS)
Juliasih, N.; Buchari; Noviandri, I.
2017-04-01
The nanoparticle of metal oxides has great unique characteristics that applicable to the wide industrial as sensors and catalysts for reducing environmental pollution. Sulphide gas monitors and detectors are required for assessing safety aspects, due to its toxicity level. A thin film of ZnO as the sulphide gas sensor was synthesised by the simple method of chemical liquid deposition with variation of annealing temperature from 200 ºC to 500 ºC, and characterised by Scanning Electron Microscope (SEM), X-Ray Diffraction (XRD), and UV/VIS/NIR-Spectrophotometer. Characterization studies showed nanoparticle size from the range 62 - 92 nm of diameters. The application this ZnO thin film to sulfide gas, detected by UV/VIS/NIR Spectrophotometer with diffuse reflectance, showed specific chemical reaction by the shifting of maximum % Reflectance peak. The gas sensing using this method is applicable at room.
Vision and Quality of Life Index: validation of the Indian version using Rasch analysis.
Gothwal, Vijaya K; Bagga, Deepak K
2013-07-18
A multi-attribute utility instrument (MAUI) consists of a descriptive system in which the items and responses seek information about a concept of the universe of health-related quality of life (QoL), and responses to these items then are weighted and combined to produce the index. To our knowledge, the 6-item Vision and Quality of Life Index (VisQoL) is the only available vision-related MAUI, developed and validated in Australia, specifically for visually impaired (VI) populations. To our knowledge, the psychometric properties of the VisQoL have not yet been investigated in an Indian VI sample; this was the aim of our study. The Indian VisQoL was administered to 349 VI adults face-to-face by a trained interviewer at the Vision Rehabilitation Centres of a tertiary eye care facility, South India. Rasch analysis was used to assess the psychometric properties. Rescoring was necessary for all except one item before ordered thresholds were obtained. All items fit the Rasch model and unidimensionality was confirmed. Person separation was acceptable (2.01), indicating that the instrument can discriminate among three strata of participants" vision-related QoL (VRQoL). The VisQoL items were targeted substantially to the participants" VRQoL (-0.69 logits). One item ("ability to have friendships") demonstrated large differential item functioning by work status; working participants reported the item to be more difficult (-1.13 logits) relative to other items when compared to the nonworking participants. The 6-item Indian VisQoL satisfies unidimensional Rasch model expectations in VI patients. Disordering of response categories was evident; replication is required before a common rescoring option should be considered.
Gallo, Erik; Gorelov, Evgeny; Guda, Alexander A; Bugaev, Aram L; Bonino, Francesca; Borfecchia, Elisa; Ricchiardi, Gabriele; Gianolio, Diego; Chavan, Sachin; Lamberti, Carlo
2017-12-04
We used Ni K-edge resonant-valence-to-core X-ray emission spectroscopy (RVtC-XES, also referred to as direct RIXS), an element-selective bulk-sensitive synchrotron-based technique, to investigate the electronic structure of the CPO-27-Ni metal-organic framework (MOF) upon molecular adsorption of significant molecular probes: H 2 O, CO, H 2 S, and NO. We compare RVtC-XES with UV-vis spectroscopy, and we show that the element selectivity of RVtC-XES is of strategic significance to observe the full set of d-d excitations in Ni 2+ , which are partially overshadowed by the low-energy π-π* transitions of the Ni ligands in standard diffuse-reflectance UV-vis experiments. Our combined RVtC-XES/UV-vis approach provides access to the whole set of d-d excitations, allowing us a complete discussion of the changes undergone by the electronic configuration of the Ni 2+ sites hosted within the MOF upon molecular adsorption. The experimental data have been interpreted by multiplet ligand-field theory calculations based on Wannier orbitals. This study represents a step further in understanding the ability of the CPO-27-Ni MOFs in molecular sorption and separation applications.
Ramakrishna, Wusirika; Deng, Zhiping; Ding, Chang-Kui; Handa, Avtar K.; Ozminkowski, Richard H.
2003-01-01
We have characterized a novel small heat shock protein gene, viscosity 1 (vis1) from tomato (Lycopersicon esculentum) and provide evidence that it plays a role in pectin depolymerization and juice viscosity in ripening fruits. Expression of vis1 is negatively associated with juice viscosity in diverse tomato genotypes. vis1 exhibits DNA polymorphism among tomato genotypes, and the alleles vis1-hta (high-transcript accumulator; accession no. AY128101) and vis1-lta (low transcript accumulator; accession no. AY128102) are associated with thinner and thicker juice, respectively. Segregation of tomato lines heterogeneous for vis1 alleles indicates that vis1 influences pectin depolymerization and juice viscosity in ripening fruits. vis1 is regulated by fruit ripening and high temperature and exhibits a typical heat shock protein chaperone function when expressed in bacterial cells. We propose that VIS1 contributes to physiochemical properties of juice, including pectin depolymerization, by reducing thermal denaturation of depolymerizing enzymes during daytime elevated temperatures. PMID:12586896
[On-site evaluation of raw milk qualities by portable Vis/NIR transmittance technique].
Wang, Jia-Hua; Zhang, Xiao-Wei; Wang, Jun; Han, Dong-Hai
2014-10-01
To ensure the material safety of dairy products, visible (Vis)/near infrared (NIR) spectroscopy combined with che- mometrics methods was used to develop models for fat, protein, dry matter (DM) and lactose on-site evaluation. A total of 88 raw milk samples were collected from individual livestocks in different years. The spectral of raw milk were measured by a porta- ble Vis/NIR spectrometer with diffused transmittance accessory. To remove the scatter effect and baseline drift, the diffused transmittance spectra were preprocessed by 2nd order derivative with Savitsky-Golay (polynomial order 2, data point 25). Changeable size moving window partial least squares (CSMWPLS) and genetic algorithms partial least squares (GAPLS) meth- ods were suggested to select informative regions for PLS calibration. The PLS and multiple linear regression (MLR) methods were used to develop models for predicting quality index of raw milk. The prediction performance of CSMWPLS models were similar to GAPLS models for fat, protein, DM and lactose evaluation, the root mean standard errors of prediction (RMSEP) were 0.115 6/0.103 3, 0.096 2/0.113 7, 0.201 3/0.123 7 and 0.077 4/0.066 8, and the relative standard deviations of prediction (RPD) were 8.99/10.06, 3.53/2.99, 5.76/9.38 and 1.81/2.10, respectively. Meanwhile, the MLR models were also cal- ibrated with 8, 10, 9 and 7 variables for fat, protein, DM and lactose, respectively. The prediction performance of MLR models was better than or close to PLS models. The MLR models to predict fat, protein, DM and lactose yielded the RMSEP of 0.107 0, 0.093 0, 0.136 0 and 0.065 8, and the RPD of 9.72, 3.66, 8.53 and 2.13, respectively. The results demonstrated the usefulness of Vis/NIR spectra combined with multivariate calibration methods as an objective and rapid method for the quality evaluation of complicated raw milks. And the results obtained also highlight the potential of portable Vis/NIR instruments for on-site assessing quality indexes of raw milk.
NASA Astrophysics Data System (ADS)
Kanjilal, Baishali; Iram, Samreen; Das, Atreyee; Chakrabarti, Haimanti
2018-05-01
This work reports a novel two dimensional approach to the theoretical computation of the glass transition temperature in simple hypothetical icosahedral packed structures based on Thin Film metallic glasses using liquid state theories in the realm of transport properties. The model starts from Navier-Stokes equation and evaluates the statistical average velocity of each different species of atom under the condition of ensemble equality to compute diffusion lengths and the diffusion coefficients as a function of temperature. The additional correction brought in is that of the limited states due to tethering of one nodule vis -a-vis the others. The movement of the molecules use our Twin Cell Model a typical model pertinent for modeling chain motions. A temperature viscosity correction by Cohen and Grest is included through the temperature dependence of the relaxation times for glass formers.
Nordvang, Emily C; Borodina, Elena; Ruiz-Martínez, Javier; Fehrmann, Rasmus; Weckhuysen, Bert M
2015-01-01
The catalytic activity of large zeolite H-ZSM-5 crystals in methanol (MTO) and ethanol-to-olefins (ETO) conversions was investigated and, using operando UV/Vis measurements, the catalytic activity and deactivation was correlated with the formation of coke. These findings were related to in situ single crystal UV/Vis and confocal fluorescence micro-spectroscopy, allowing the observation of the spatiotemporal formation of intermediates and coke species during the MTO and ETO conversions. It was observed that rapid deactivation at elevated temperatures was due to the fast formation of aromatics at the periphery of the H-ZSM-5 crystals, which are transformed into more poly-aromatic coke species at the external surface, preventing the diffusion of reactants and products into and out of the H-ZSM-5 crystal. Furthermore, we were able to correlate the operando UV/Vis spectroscopy results observed during catalytic testing with the single crystal in situ results. PMID:26463581
Size determination of gold nanoparticles in silicate glasses by UV-Vis spectroscopy
NASA Astrophysics Data System (ADS)
Ali, Shahid; Khan, Younas; Iqbal, Yaseen; Hayat, Khizar; Ali, Muhammad
2017-01-01
A relatively easier and more accurate method for the determination of average size of metal nanoparticles/aggregates in silicate glasses based on ultraviolet visible (UV-Vis) spectra fitted with the Mie and Mie-Gans models was reported. Gold ions were diffused into sodalime silicate and borosilicate glasses by field-assisted solid-state ion-exchange technique using the same experimental parameters for both glasses. Transmission electron microscopy was performed to directly investigate the morphology and distribution of the dopant nanoparticles. UV-Vis spectra of the doped glasses showed broad surface plasmon resonance peaks in their fingerprint regions, i.e., at 525 and 500 nm for sodalime silicate and borosilicate glass matrices, respectively. These spectra were fitted with the Mie model for spherical nanoparticles and the Mie-Gans model for spheroidal nanoparticles. Although both the models were developed for colloidal nanoparticles, the size of the nanoparticles/aggregates calculated was accurate to within ˜10% in both the glass matrices in comparison to the size measured directly from the transmission electron microscope images.
VisIVO: A Library and Integrated Tools for Large Astrophysical Dataset Exploration
NASA Astrophysics Data System (ADS)
Becciani, U.; Costa, A.; Ersotelos, N.; Krokos, M.; Massimino, P.; Petta, C.; Vitello, F.
2012-09-01
VisIVO provides an integrated suite of tools and services that can be used in many scientific fields. VisIVO development starts in the Virtual Observatory framework. VisIVO allows users to visualize meaningfully highly-complex, large-scale datasets and create movies of these visualizations based on distributed infrastructures. VisIVO supports high-performance, multi-dimensional visualization of large-scale astrophysical datasets. Users can rapidly obtain meaningful visualizations while preserving full and intuitive control of the relevant parameters. VisIVO consists of VisIVO Desktop - a stand-alone application for interactive visualization on standard PCs, VisIVO Server - a platform for high performance visualization, VisIVO Web - a custom designed web portal, VisIVOSmartphone - an application to exploit the VisIVO Server functionality and the latest VisIVO features: VisIVO Library allows a job running on a computational system (grid, HPC, etc.) to produce movies directly with the code internal data arrays without the need to produce intermediate files. This is particularly important when running on large computational facilities, where the user wants to have a look at the results during the data production phase. For example, in grid computing facilities, images can be produced directly in the grid catalogue while the user code is running in a system that cannot be directly accessed by the user (a worker node). The deployment of VisIVO on the DG and gLite is carried out with the support of EDGI and EGI-Inspire projects. Depending on the structure and size of datasets under consideration, the data exploration process could take several hours of CPU for creating customized views and the production of movies could potentially last several days. For this reason an MPI parallel version of VisIVO could play a fundamental role in increasing performance, e.g. it could be automatically deployed on nodes that are MPI aware. A central concept in our development is thus to produce unified code that can run either on serial nodes or in parallel by using HPC oriented grid nodes. Another important aspect, to obtain as high performance as possible, is the integration of VisIVO processes with grid nodes where GPUs are available. We have selected CUDA for implementing a range of computationally heavy modules. VisIVO is supported by EGI-Inspire, EDGI and SCI-BUS projects.
GO(vis), a gene ontology visualization tool based on multi-dimensional values.
Ning, Zi; Jiang, Zhenran
2010-05-01
Most of gene product similarity measurements concentrate on the information content of Gene Ontology (GO) terms or use a path-based similarity between GO terms, which may ignore other important information contained in the structure of the ontology. In our study, we integrate different GO similarity measure approaches to analyze the functional relationship of genes and gene products with a new triangle-based visualization tool called GO(Vis). The purpose of this tool is to demonstrate the effect of three important information factors when measuring the similarity between gene products. One advantage of this tool is that its important ratio can be adjusted to meet different measuring requirements according to the biological knowledge of each factor. The experimental results demonstrate that GO(Vis) can display diagrams of the functional relationship for gene products effectively.
VIS: Technology for Multicultural Teacher Education.
ERIC Educational Resources Information Center
Bruning, Merribeth J.
1992-01-01
Video Information Systems (VIS) is fiber optics network that connects campus classrooms to VIS central library. Remotely controlled by instructors, VIS incorporates use of number of audiovisual materials and can be used in cross-cultural training in which visual aids assist in showing cultural differences. VIS assists in education of future…
Okparanma, Reuben N; Coulon, Frederic; Mayr, Thomas; Mouazen, Abdul M
2014-09-01
In this study, we used data from spectroscopic models based on visible and near-infrared (vis-NIR; 350-2500 nm) diffuse reflectance spectroscopy to develop soil maps of polycyclic aromatic hydrocarbons (PAHs) and total toxicity equivalent concentrations (TTEC) of the PAH mixture. The TTEC maps were then used for hazard assessment of three petroleum release sites in the Niger Delta province of Nigeria (5.317°N, 6.467°E). As the paired t-test revealed, there were non-significant (p > 0.05) differences between soil maps of PAH and TTEC developed with chemically measured and vis-NIR-predicted data. Comparison maps of PAH showed a slight to moderate agreement between measured and predicted data (Kappa coefficient = 0.19-0.56). Using proposed generic assessment criteria, hazard assessment showed that the degree of action for site-specific risk assessment and/or remediation is similar for both measurement methods. This demonstrates that the vis-NIR method may be useful for monitoring hydrocarbon contamination in a petroleum release site. Copyright © 2014 Elsevier Ltd. All rights reserved.
Influenza (flu) vaccine (Inactivated or Recombinant): What you need to know
... taken in its entirety from the CDC Inactivated Influenza Vaccine Information Statement (VIS) www.cdc.gov/vaccines/hcp/vis/vis-statements/flu.html CDC review information for Inactivated Influenza VIS: ...
IS Staffing during a Recession: Comparing Student and IS Recruiter Perceptions
ERIC Educational Resources Information Center
Pratt, Jean A.; Hauser, Karina; Ross, Steven C.
2010-01-01
The current economic situation in the United States has associated ramifications for IS employment. This study identifies IS recruiters' perceptions vis-a-vis IT budget cuts and layoffs at their organizations. Additionally, it identifies IS student perceptions vis-a-vis employment opportunities and academic preparation. Similar surveys were…
Douglas, R K; Nawar, S; Alamar, M C; Mouazen, A M; Coulon, F
2018-03-01
Visible and near infrared spectrometry (vis-NIRS) coupled with data mining techniques can offer fast and cost-effective quantitative measurement of total petroleum hydrocarbons (TPH) in contaminated soils. Literature showed however significant differences in the performance on the vis-NIRS between linear and non-linear calibration methods. This study compared the performance of linear partial least squares regression (PLSR) with a nonlinear random forest (RF) regression for the calibration of vis-NIRS when analysing TPH in soils. 88 soil samples (3 uncontaminated and 85 contaminated) collected from three sites located in the Niger Delta were scanned using an analytical spectral device (ASD) spectrophotometer (350-2500nm) in diffuse reflectance mode. Sequential ultrasonic solvent extraction-gas chromatography (SUSE-GC) was used as reference quantification method for TPH which equal to the sum of aliphatic and aromatic fractions ranging between C 10 and C 35 . Prior to model development, spectra were subjected to pre-processing including noise cut, maximum normalization, first derivative and smoothing. Then 65 samples were selected as calibration set and the remaining 20 samples as validation set. Both vis-NIR spectrometry and gas chromatography profiles of the 85 soil samples were subjected to RF and PLSR with leave-one-out cross-validation (LOOCV) for the calibration models. Results showed that RF calibration model with a coefficient of determination (R 2 ) of 0.85, a root means square error of prediction (RMSEP) 68.43mgkg -1 , and a residual prediction deviation (RPD) of 2.61 outperformed PLSR (R 2 =0.63, RMSEP=107.54mgkg -1 and RDP=2.55) in cross-validation. These results indicate that RF modelling approach is accounting for the nonlinearity of the soil spectral responses hence, providing significantly higher prediction accuracy compared to the linear PLSR. It is recommended to adopt the vis-NIRS coupled with RF modelling approach as a portable and cost effective method for the rapid quantification of TPH in soils. Copyright © 2017 Elsevier B.V. All rights reserved.
Partial Fourier techniques in single-shot cross-term spatiotemporal encoded MRI.
Zhang, Zhiyong; Frydman, Lucio
2018-03-01
Cross-term spatiotemporal encoding (xSPEN) is a single-shot approach with exceptional immunity to field heterogeneities, the images of which faithfully deliver 2D spatial distributions without requiring a priori information or using postacquisition corrections. xSPEN, however, suffers from signal-to-noise ratio penalties due to its non-Fourier nature and due to diffusion losses-especially when seeking high resolution. This study explores partial Fourier transform approaches that, acting along either the readout or the spatiotemporally encoded dimensions, reduce these penalties. xSPEN uses an orthogonal (e.g., z) gradient to read, in direct space, the low-bandwidth (e.g., y) dimension. This substantially changes the nature of partial Fourier acquisitions vis-à-vis conventional imaging counterparts. A suitable theoretical analysis is derived to implement these procedures, along either the spatiotemporally or readout axes. Partial Fourier single-shot xSPEN images were recorded on preclinical and human scanners. Owing to their reduction in the experiments' acquisition times, this approach provided substantial sensitivity gains vis-à-vis previous implementations for a given targeted in-plane resolution. The physical origins of these gains are explained. Partial Fourier approaches, particularly when implemented along the low-bandwidth spatiotemporal dimension, provide several-fold sensitivity advantages at minimal costs to the execution and processing of the single-shot experiments. Magn Reson Med 79:1506-1514, 2018. © 2017 International Society for Magnetic Resonance in Medicine. © 2017 International Society for Magnetic Resonance in Medicine.
Interactive access and management for four-dimensional environmental data sets using McIDAS
NASA Technical Reports Server (NTRS)
Hibbard, William L.; Tripoli, Gregory J.
1991-01-01
Significant accomplishments in the following areas are presented: (1) enhancements to the visualization of 5-D data sets (VIS-5D); (2) development of the visualization of global images (VIS-GI) application; (3) design of the Visualization for Algorithm Development (VIS-AD) System; and (4) numerical modeling applications. The focus of current research and future research plans is presented and the following topics are addressed: (1) further enhancements to VIS-5D; (2) generalization and enhancement of the VIS-GI application; (3) the implementation of the VIS-AD System; and (4) plans for modeling applications.
XRF and UV-Vis-NIR analyses of medieval wall paintings of al-Qarawiyyin Mosque (Morocco)
NASA Astrophysics Data System (ADS)
Fikri, I.; El Amraoui, M.; Haddad, M.; Ettahiri, A. S.; Bellot-Gurlet, L.; Falguères, C.; Lebon, M.; Nespoulet, R.; Ait Lyazidi, S.; Bejjit, L.
2018-05-01
Medieval wall painting fragments, taken at the medieval Mosque of al-Qarawiyyin in Fez, have been investigated by means of X-ray fluorescence and UV-Vis-NIR diffuse reflectance spectroscopies. The analyses permitted to determine the palette of pigments used by craftsmen of the time. Hematite or red ochre were used to obtain red brown colours, calcite for white, copper-based pigments for blue and blue-grey shades while a mixture of cinnabar, lead-based pigments and hematite was adopted to make red-orange colours. Furthermore, the analysis of mortars (external layer and plaster) on these wall painting samples revealed that they are composed mainly by calcite and sometimes by additional compounds such as quartz and gypsum.
Profile soil property estimation using a VIS-NIR-EC-force probe
USDA-ARS?s Scientific Manuscript database
Combining data collected in-field from multiple soil sensors has the potential to improve the efficiency and accuracy of soil property estimates. Optical diffuse reflectance spectroscopy (DRS) has been used to estimate many important soil properties, such as soil carbon, water content, and texture. ...
NASA Astrophysics Data System (ADS)
Sujatha, N.; Anand, B. S. Suresh; Nivetha, K. Bala; Narayanamurthy, V. B.; Seshadri, V.; Poddar, R.
2015-07-01
Light-based diagnostic techniques provide a minimally invasive way for selective biomarker estimation when tissues transform from a normal to a malignant state. Spectroscopic techniques based on diffuse reflectance characterize the changes in tissue hemoglobin/oxygenation levels during the tissue transformation process. Recent clinical investigations have shown that changes in tissue oxygenation and microcirculation are observed in diabetic subjects in the initial and progressive stages. In this pilot study, we discuss the potential of diffuse reflectance spectroscopy (DRS) in the visible (Vis) range to differentiate the skin microcirculatory hemoglobin levels between normal and advanced diabetic subjects with and without neuropathy. Average concentration of hemoglobin as well as hemoglobin oxygen saturation within the probed tissue volume is estimated for a total of four different sites in the foot sole. The results indicate a statistically significant decrease in average total hemoglobin and increase in hemoglobin oxygen saturation levels for diabetic foot compared with a normal foot. The present study demonstrates the ability of reflectance spectroscopy in the Vis range to determine and differentiate the changes in tissue hemoglobin and hemoglobin oxygen saturation levels in normal and diabetic subjects.
NASA Astrophysics Data System (ADS)
Gobrecht, Alexia; Bendoula, Ryad; Roger, Jean-Michel; Bellon-Maurel, Véronique
2014-05-01
Visible - Near-infrared spectroscopy (Vis-NIRS) is now commonly used to measure different physical and chemical parameters of soils, including carbon content. However, prediction model accuracy is insufficient for Vis-NIRS to replace routine laboratory analysis. One of the biggest issues this technique is facing up to is light scattering due to soil particles. It causes departure in the assumed linear relationship between the Absorbance spectrum and the concentration of the chemicals of interest as stated by Beer-Lambert's Law, which underpins the calibration models. Therefore it becomes essential to improve the metrological quality of the measured signal in order to optimize calibration as light/matter interactions are at the basis of the resulting linear modeling. Optics can help to mitigate scattering effect on the signal. We put forward a new optical setup coupling linearly polarized light with a Vis-NIR spectrometer to free the measured spectra from multi-scattering effect. The corrected measured spectrum was then used to compute an Absorbance spectrum of the sample, using Dahm's Equation in the frame of the Representative Layer Theory. This method has been previously tested and validated on liquid (milk+ dye) and powdered (sand + dye) samples showing scattering (and absorbing) properties. The obtained Absorbance was a very good approximation of the Beer-Lambert's law absorbance. Here, we tested the method on a set of 54 soil samples to predict Soil Organic Carbon content. In order to assess the signal quality improvement by this method, we built and compared calibration models using Partial Least Square (PLS) algorithm. The prediction model built from new Absorbance spectrum outperformed the model built with the classical Absorbance traditionally obtained with Vis-NIR diffuse reflectance. This study is a good illustration of the high influence of signal quality on prediction model's performances.
Labview virtual instruments for calcium buffer calculations.
Reitz, Frederick B; Pollack, Gerald H
2003-01-01
Labview VIs based upon the calculator programs of Fabiato and Fabiato (J. Physiol. Paris 75 (1979) 463) are presented. The VIs comprise the necessary computations for the accurate preparation of multiple-metal buffers, for the back-calculation of buffer composition given known free metal concentrations and stability constants used, for the determination of free concentrations from a given buffer composition, and for the determination of apparent stability constants from absolute constants. As implemented, the VIs can concurrently account for up to three divalent metals, two monovalent metals and four ligands thereof, and the modular design of the VIs facilitates further extension of their capacity. As Labview VIs are inherently graphical, these VIs may serve as useful templates for those wishing to adapt this software to other platforms.
Running VisIt Software on the Peregrine System | High-Performance Computing
kilobyte range. VisIt features a robust remote visualization capability. VisIt can be started on a local machine and used to visualize data on a remote compute cluster.The remote machine must be able to send VisIt module must be loaded as part of this process. To enable remote visualization the 'module load
LabVIEW Task Manager v. 1.10.0
DOE Office of Scientific and Technical Information (OSTI.GOV)
Vargo, Timothy D.
LabVIEW Task Manager is a debugging tool for use during code development in the National Instruments (NI) LabVIEW® IDE. While providing a dynamic & big-picture view of running code, an expandable/collapsible tree diagram displays detailed information (both static and dynamic) on all VIs in memory, belonging to a selected project/target. It allows for interacting with single or multiple selected VIs at a time, providing significant benefits while troubleshooting, and has the following features: Look & Feel similar to Windows® Task Manager; Selection of project/target; Lists all VIs in memory, grouped by class/library; Searches for and enumerates clones in memory; DropInmore » VI for including dynamically referenced clones (Clone Beacon); 'Refresh Now' (F5) re-reads all VIs in memory and adds new ones to the tree; Displays VI name, owning class/library, state, path, data size & code size; Displays VI FP Behavior, Reentrant?, Reentrancy Type, Paused? & Highlight?; Sort by any column, including by library name; Filter by item types vi, ctl, and vit/ctt; Filter out vi.lib and global VIs; Tracking of, and ability to toggle, execution highlighting on multiple selected VIs; Tracking of paused VIs with ability to Pause/Resume/TogglePause multiple selected VIs; DropIn VI for pausing on a condition; If a clone initiates a pause, a different pause symbol is used for all clones of that same reentrant original VI; Select multiple VIs and open or close their FPs or BDs; Double Click a VI from the tree to bring the BD (first choice) or FP to front, if already open; and Select multiple top-level VIs and Abort them.« less
On-ground characterization of the Euclid's CCD273-based readout chain
NASA Astrophysics Data System (ADS)
Szafraniec, Magdalena; Azzollini, R.; Cropper, M.; Pottinger, S.; Khalil, A.; Hailey, M.; Hu, D.; Plana, C.; Cutts, A.; Hunt, T.; Kohley, R.; Walton, D.; Theobald, C.; Sharples, R.; Schmoll, J.; Ferrando, P.
2016-07-01
Euclid is a medium class European Space Agency mission scheduled for launch in 2020. The goal of the survey is to examine the nature of Dark Matter and Dark Energy in the Universe. One of the cosmological probes used to analyze Euclid's data, the weak lensing technique, measures the distortions of galaxy shapes and this requires very accurate knowledge of the system point spread function (PSF). Therefore, to ensure that the galaxy shape is not affected, the detector chain of the telescope's VISible Instrument (VIS) needs to meet specific performance performance requirements. Each of the 12 VIS readout chains consisting of 3 CCDs, readout electronics (ROE) and a power supply unit (RPSU) will undergo a rigorous on-ground testing to ensure that these requirements are met. This paper reports on the current status of the warm and cold testing of the VIS Engineering Model readout chain. Additionally, an early insight to the commissioning of the Flight Model calibration facility and program is provided.
Creating a Parallel Version of VisIt for Microsoft Windows
DOE Office of Scientific and Technical Information (OSTI.GOV)
Whitlock, B J; Biagas, K S; Rawson, P L
2011-12-07
VisIt is a popular, free interactive parallel visualization and analysis tool for scientific data. Users can quickly generate visualizations from their data, animate them through time, manipulate them, and save the resulting images or movies for presentations. VisIt was designed from the ground up to work on many scales of computers from modest desktops up to massively parallel clusters. VisIt is comprised of a set of cooperating programs. All programs can be run locally or in client/server mode in which some run locally and some run remotely on compute clusters. The VisIt program most able to harness today's computing powermore » is the VisIt compute engine. The compute engine is responsible for reading simulation data from disk, processing it, and sending results or images back to the VisIt viewer program. In a parallel environment, the compute engine runs several processes, coordinating using the Message Passing Interface (MPI) library. Each MPI process reads some subset of the scientific data and filters the data in various ways to create useful visualizations. By using MPI, VisIt has been able to scale well into the thousands of processors on large computers such as dawn and graph at LLNL. The advent of multicore CPU's has made parallelism the 'new' way to achieve increasing performance. With today's computers having at least 2 cores and in many cases up to 8 and beyond, it is more important than ever to deploy parallel software that can use that computing power not only on clusters but also on the desktop. We have created a parallel version of VisIt for Windows that uses Microsoft's MPI implementation (MSMPI) to process data in parallel on the Windows desktop as well as on a Windows HPC cluster running Microsoft Windows Server 2008. Initial desktop parallel support for Windows was deployed in VisIt 2.4.0. Windows HPC cluster support has been completed and will appear in the VisIt 2.5.0 release. We plan to continue supporting parallel VisIt on Windows so our users will be able to take full advantage of their multicore resources.« less
NIST High Accuracy Reference Reflectometer-Spectrophotometer
Proctor, James E.; Yvonne Barnes, P.
1996-01-01
A new reflectometer-spectrophotometer has been designed and constructed using state-of-the-art technology to enhance optical properties of materials measurements over the ultraviolet, visible, and near-infrared (UV-Vis-NIR) wavelength range (200 nm to 2500 nm). The instrument, Spectral Tri-function Automated Reference Reflectometer (STARR), is capable of measuring specular and diffuse reflectance, bidirectional reflectance distribution function (BRDF) of diffuse samples, and both diffuse and non-diffuse transmittance. Samples up to 30 cm by 30 cm can be measured. The instrument and its characterization are described. PMID:27805081
Utility values in the visually impaired: comparing time-trade off and VisQoL.
Gothwal, Vijaya K; Bagga, Deepak K
2013-08-01
Visual impairment (VI) negatively affects quality of life (QoL). Utilities represent a way of measuring the QoL impact associated with a particular health state, like VI, and are also useful in economic evaluations of health care interventions. Utilities can be determined either directly or indirectly. Here we determine whether the Vision and Quality of Life Index, VisQoL (indirect approach), is acceptable to use in patients with VI in an urban setting in South India; whether the VisQoL utility values, derived from an Australian sample of both visually impaired and normally sighted participants, demonstrate agreement (if any) with direct utilities, determined by time trade-off (TTO), from visually impaired South Indian patients; and determine the relationship between utilities and self-reported visual disability. Three hundred forty-nine adults with VI were administered the two-item TTO item, six-item VisQoL, and the 16-item Andhra Pradesh Eye Disease-Visual Function Questionnaire (APEDS-VFQ) in a face-to-face interview. The VisQoL utilities were derived from the utility scoring algorithm. Rasch-scaled scores of the APEDS-VFQ were obtained using the conversion scores sheets. Agreement between TTO and utilities VisQoL was assessed using the Bland-Altman method. All participants (response rate, 100%) completed the VisQoL as compared with 72% for the TTO. There was no statistically significant difference in the mean utilities from the two methods (0.65 ± 0.31 by TTO vs. 0.66 ± 0.27 by VisQoL, p = 0.67). However, the 95% limits of agreement on the Bland-Altman plot were wide (-0.65, 0.67), implying a lack of agreement between the methods. The VisQoL relates relatively strongly with APEDS-VFQ as compared with TTO (TTO vs. APEDS-VFQ, r = -0.23, VisQoL vs. APEDS-VFQ, r = -0.66, z = -6.70; p < 0.001 for both). Older participants, female, and those with less than 12 years of education had lower utilities. The direct (TTO) and indirect (VisQoL) methods of utility evaluation tend to disagree in our patients with VI. Given the high completion rates of the VisQoL as compared with the TTO, the VisQoL may be a suitable alternative for utility assessment in an Indian population.
Estimation of soil profile physical and chemical properties using a VIS-NIR-EC-force probe
USDA-ARS?s Scientific Manuscript database
Combining data collected in-field from multiple soil sensors has the potential to improve the efficiency and accuracy of soil property estimates. Optical diffuse reflectance spectroscopy (DRS) has been used to estimate many important soil properties, such as soil carbon, water content, and texture. ...
Perone, J M; Popovici, A; Ouled-Moussa, R; Herasymyuk, O; Reynders, S
2007-01-01
VisThesia is a new ophthalmic viscosurgical device (OVD) which has 1% lidocaine combined with 1.5% sodium hyaluronate. This is a prospective evaluation of the safety and efficacy of VisThesia used in association with phacoemulsification. A total of 114 eyes were divided into two groups. Fifty-nine eyes were treated with tetracaine + oxybuprocaine topical anesthesia and DuoVisc OVD and 55 eyes were treated with VisThesia, for use as both topical anesthetic and OVD. Endothelial cell counts were measured at 30 days postoperatively and compared to preoperative baseline values. Pain and discomfort was subjectively evaluated by patients using a visual analog pain scale (0-10). All surgeries were uneventful with no intraoperative or immediate postoperative complications. Patients receiving topical anesthesia had a mean pain score of 1.1+/-6.8 compared to a mean score of 1.3+/-4.6 for patients receiving VisThesia (p=0.59). Postoperatively, endothelial cell loss at 1 month was greater for patients receiving VisThesia (20.32%+/-43.75) than for those receiving the topical anesthetic (8.8%+/-59.6; p<0.0001). The results from the visual analog pain scale were comparable between groups, showing that VisThesia provides similar pain relief to topical anesthesia. Specular microscopy performed at 30 days postoperatively showed a significantly greater loss of endothelial cells with the use of VisThesia, suggesting that the 1% lidocaine concentration used in VisThesia may be toxic to corneal endothelial cells.
Guo, Yujie; Van Bilzen, Bart; Locquet, Jean Pierre; Seo, Jin Won
2015-12-11
One-dimensional single crystalline InGaO3(ZnO)n (IGZO) nanostructures have great potential for various electrical and optical applications. This paper demonstrates for the first time, to our knowledge, a non-vacuum route for the synthesis of IGZO nanowires by annealing ZnO nanowires covered with solution-based IGZO precursor. This method results in nanowires with highly periodic IGZO superlattice structure. The phase transition of IGZO precursor during thermal treatment was systematically studied. Transmission electron microscopy studies reveal that the formation of the IGZO structure is driven by anisotropic inter-diffusion of In, Ga, and Zn atoms, and also by the crystallization of the IGZO precursor. Optical measurements using cathodoluminescence and UV-vis spectroscopy confirm that the nanowires consist of the IGZO compound with wide optical band gap and suppressed luminescence.
ERIC Educational Resources Information Center
Manan, Syed Abdul; David, Maya Khemlani
2014-01-01
This study critically examines the literacy levels of undergraduate students in Pakistan to compare and contrast the proficiency levels, particularly reading and writing of their mother tongues versus Urdu and English, and to study real and perceived vitality of local/regional mother tongues vis-à-vis Urdu and English. The research investigated…
NASA Astrophysics Data System (ADS)
Krukowska, Anna; Trykowski, Grzegorz; Winiarski, Michal Jerzy; Klimczuk, Tomasz; Lisowski, Wojciech; Mikolajczyk, Alicja; Pinto, Henry P.; Zaleska-Medynska, Adriana
2018-05-01
Novel mono- and bimetallic nanoparticles (MNPs and BNPs) decorated surface of perovskite-type KTaO3 photocatalysts were successfully synthesized by hydrothermal reaction of KTaO3 followed by photodeposition of MNPs/BNPs. The effect of noble metal type (MNPs = Au, Ag, Pt, Pd, Rh, Ru or BNPs = Au/Pt, Ag/Pd, Rh/Ru), amount of metal precursor (0.5, 1.0, 1.5 or 2.0 wt%) as well as photoreduction method (simultaneous (both) or subsequent (seq) deposition of two metals) on the physicochemical and photocatalytic properties of MNPs- and BNPs-KTaO3 have been investigated. All as-prepared photocatalysts were subsequently characterized by UV-Vis diffuse reflectance spectroscopy (DRS), Brunauer-Emmett-Teller (BET) specific surface area and pore size distribution measurement, scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), powder X-ray diffraction (PXRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and photoluminescence (PL) emission spectroscopy. The crystal structure was performed using visualization for electronic and structural analysis (VESTA). The photocatalytic activity under Vis light irradiation was estimated in phenol degradation in aqueous phase and toluene removal in gas phase, while under UV-Vis light irradiation was measured amount of H2 generation from formic acid solution. The absorption properties of O2 and H2O molecules on KTaO3(1 0 0) surface supported by Au or Au/Pt NPs was also investigated using density-functional theory (DFT). The experimental results show that, both MNPs-KTaO3 and BNPs-KTaO3 exhibit greatly enhanced pollutant decomposition efficiency under Vis light irradiation and highly improved H2 production under UV-Vis light irradiation compared with pristine KTaO3. MNPs deposition on KTaO3 surface effects by disperse metal particle size ranging from 11 nm (Ru NPs) to 112 nm (Au NPs). Simultaneous addition of Au/Pt precursors results in formation of agglomerated larger metal nanoparticles (50-100 nm) on KTaO3 surface than subsequent deposition of Au/Pt with composition of concentrated smaller metal nanoparticles (>50 nm) on KTaO3 surface. The 0.5 Au/1.5 Pt-KTaO3_both and 2.0 Rh-KTaO3 reveal the highest Vis-induced activity among prepared samples in aqueous phase (14.75% of phenol decomposition after 90 min of irradiation) and gas phase (41.98% of toluene removal after 60 min of irradiation), respectively. The theoretical calculations confirmed that adsorption energy of O2 and H2O molecules was increased after loading of Au or Au/Pt NPs on KTaO3(1 0 0) surface. Control tests with scavengers show that O2rad - radical is significantly involved in phenol oxidation under Vis light irradiation, which proposed mechanism is based on direct electron transfer from MNPs/BNPs to conduction band of KTaO3. The highest amount of H2 evaluation is obtained also by 0.5 Au/1.5 Pt-KTaO3_both after 240 min of UV-Vis light irradiation (76.53 μmol/min), which is eleven times higher than for pristine KTaO3 (6.69 μmol/min). Moreover, the most photocatalytic samples for each model reaction present good repeatability and stability after subsequent three cycles. Summarized, MNPs- and BNPs-KTaO3 are promising material in advanced applications of photocatalysis.
Han, Lei; Wulie, Buzha; Yang, Yiling; Wang, Hongqing
2015-01-05
This study investigated a novel method of fusing visible (VIS) and infrared (IR) images with the major objective of obtaining higher-resolution IR images. Most existing image fusion methods focus only on visual performance and many fail to consider the thermal physical properties of the IR images, leading to spectral distortion in the fused image. In this study, we use the IR thermal physical property to correct the VIS image directly. Specifically, the Stefan-Boltzmann Law is used as a strong constraint to modulate the VIS image, such that the fused result shows a similar level of regional thermal energy as the original IR image, while preserving the high-resolution structural features from the VIS image. This method is an improvement over our previous study, which required VIS-IR multi-wavelet fusion before the same correction method was applied. The results of experiments show that applying this correction to the VIS image directly without multi-resolution analysis (MRA) processing achieves similar results, but is considerably more computationally efficient, thereby providing a new perspective on VIS and IR image fusion.
Han, Lei; Wulie, Buzha; Yang, Yiling; Wang, Hongqing
2015-01-01
This study investigated a novel method of fusing visible (VIS) and infrared (IR) images with the major objective of obtaining higher-resolution IR images. Most existing image fusion methods focus only on visual performance and many fail to consider the thermal physical properties of the IR images, leading to spectral distortion in the fused image. In this study, we use the IR thermal physical property to correct the VIS image directly. Specifically, the Stefan-Boltzmann Law is used as a strong constraint to modulate the VIS image, such that the fused result shows a similar level of regional thermal energy as the original IR image, while preserving the high-resolution structural features from the VIS image. This method is an improvement over our previous study, which required VIS-IR multi-wavelet fusion before the same correction method was applied. The results of experiments show that applying this correction to the VIS image directly without multi-resolution analysis (MRA) processing achieves similar results, but is considerably more computationally efficient, thereby providing a new perspective on VIS and IR image fusion. PMID:25569749
Visualization Software for VisIT Java Client
DOE Office of Scientific and Technical Information (OSTI.GOV)
Billings, Jay Jay; Smith, Robert W
The VisIT Java Client (JVC) library is a lightweight thin client that is designed and written purely in the native language of Java (the Python & JavaScript versions of the library use the same concept) and communicates with any new unmodified standalone version of VisIT, a high performance computing parallel visualization toolkit, over traditional or web sockets and dynamically determines capabilities of the running VisIT instance whether local or remote.
Effect of fusion mixture treatment on the surface of low grade natural ruby
NASA Astrophysics Data System (ADS)
Sakthivel, R.; Pradhan, K. C.; Nayak, B. B.; Dash, Tapan; Sahu, R. K.; Mishra, B. K.
2017-05-01
Improvement in aesthetic look of low grade natural ruby (gemstone) surface was clearly evident after fusion mixture treatment. Surface impurities of the gemstone were significantly reduced to give it a face lift. The processing consists of heat treatment (1000 °C) of the raw gemstone with fusion mixture (sodium and potassium carbonates), followed by hydrochloric acid digestion (90 °C) and ultrasonic cleaning.Both the untreated and the treated gemstone were characterized by X-ray diffraction, UV-vis spectroscopy (diffuse reflectance),photoluminescence and X-ray photoelectron spectroscopy. The paper consolidates the results of these studies and presents the effect of the typical chemical treatment (stated above) on the low grade natural ruby. While X-ray diffraction study identifies the occurrence of alumina phase in both the treated and the untreated gemstones, the UV-vis spectra exhibit strong characteristic absorption of Cr3+at 400 and 550 nm wavelength for the treated gemstone in contrast to weak absorption observed for the untreated gemstone at such wavelengths, thus showing the beneficial effect of fusion mixture treatment. Peaks observed for the gemstone (for both treated and untreated samples) in the excitation spectra of photoluminescence show a good correlation with observed UV-vis (diffuse reflectance) spectra. Photoluminescence emission spectra of the untreated gemstone show characteristic emission at 695 nm for Cr3+ ion (as in alumina matrix), but its emission intensity significantly reduces after fusion mixture treatment. It is found that the surface of the fusion mixture treated ruby gemstone looks much brighter than the corresponding untreated surface.
Global Ultraviolet Imaging Processing for the GGS Polar Visible Imaging System (VIS)
NASA Technical Reports Server (NTRS)
Frank, L. A.
1997-01-01
The Visible Imaging System (VIS) on Polar spacecraft of the NASA Goddard Space Flight Center was launched into orbit about Earth on February 24, 1996. Since shortly after launch, the Earth Camera subsystem of the VIS has been operated nearly continuously to acquire far ultraviolet, global images of Earth and its northern and southern auroral ovals. The only exceptions to this continuous imaging occurred for approximately 10 days at the times of the Polar spacecraft re-orientation maneuvers in October, 1996 and April, 1997. Since launch, approximately 525,000 images have been acquired with the VIS Earth Camera. The VIS instrument operational health continues to be excellent. Since launch, all systems have operated nominally with all voltages, currents, and temperatures remaining at nominal values. In addition, the sensitivity of the Earth Camera to ultraviolet light has remained constant throughout the operation period. Revised flight software was uploaded to the VIS in order to compensate for the spacecraft wobble. This is accomplished by electronic shuttering of the sensor in synchronization with the 6-second period of the wobble, thus recovering the original spatial resolution obtainable with the VIS Earth Camera. In addition, software patches were uploaded to make the VIS immune to signal dropouts that occur in the sliprings of the despun platform mechanism. These changes have worked very well. The VIS and in particular the VIS Earth Camera is fully operational and will continue to acquire global auroral images as the sun progresses toward solar maximum conditions after the turn of the century.
Pneumococcal conjugate vaccine (PCV13) - What you need to know
... the CDC Information Statement (VIS): www.cdc.gov/vaccines/hcp/vis/vis-statements/pcv13.html CDC review ... at the highest risk. Before there was a vaccine, the United States saw: more than 700 cases ...
NASA Astrophysics Data System (ADS)
Chen, Jie; Luo, Min; Ye, Ning
2014-10-01
A novel nonlinear optical (NLO) material Na5Sc(CO3)4·2H2O has been synthesized under a subcritical hydrothermal condition. The structure is determined by single-crystal X-ray diffraction and further characterized by TG analyses and UV-vis-NIR diffuse reflectance spectrum. It crystallizes in the tetragonal space group P-421c, with a = b = 7.4622(6) Å, C = 11.5928(15) Å. The Second-harmonic generation (SHG) on polycrystalline samples was measured using the Kurtz and Perry technique, which indicated that Na5Sc(CO3)4·2H2O was a phase-matchable material, and its measured SHG coefficient was about 1.8 times as large as that of d36 (KDP). The results from the UV-vis diffuse reflectance spectroscopy study of the powder samples indicated that the short-wavelength absorption edges of Na5Sc(CO3)4·2H2O is about 220 nm, suggesting that this crystal is a promising UV nonlinear optical (NLO) materials.
Aernouts, B; Polshin, E; Lammertyn, J; Saeys, W
2011-11-01
The composition of produced milk has great value for the dairy farmer. It determines the economic value of the milk and provides valuable information about the metabolism of the corresponding cow. Therefore, online measurement of milk components during milking 2 or more times per day would provide knowledge about the current health and nutritional status of each cow individually. This information provides a solid basis for optimizing cow management. The potential of visible and near-infrared (Vis/NIR) spectroscopy for predicting the fat, crude protein, lactose, and urea content of raw milk online during milking was, therefore, investigated in this study. Two measurement modes (reflectance and transmittance) and different wavelength ranges for Vis/NIR spectroscopy were evaluated and their ability to measure the milk composition online was compared. The Vis/NIR reflectance measurements allowed for very accurate monitoring of the fat and crude protein content in raw milk (R(2)>0.95), but resulted in poor lactose predictions (R(2)<0.75). In contrast, Vis/NIR transmittance spectra of the milk samples gave accurate fat and crude protein predictions (R(2)>0.90) and useful lactose predictions (R(2)=0.88). Neither Vis/NIR reflectance nor transmittance spectroscopy lead to an acceptable prediction of the milk urea content. Transmittance spectroscopy can thus be used to predict the 3 major milk components, but with lower accuracy for fat and crude protein than the reflectance mode. Moreover, the small sample thickness (1mm) required for NIR transmittance measurement considerably complicates its online use. Copyright © 2011 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.
Stability and morphology of Ag nanoplatelets probed by depolarized dynamic light scattering
NASA Astrophysics Data System (ADS)
Zimbone, M.; Contino, A.; Maccarrone, G.; Musumeci, P.; Lo Faro, M. J.; Calcagno, L.
2018-06-01
The stability of silver nanoplatelet (NP) suspensions prepared with different concentrations of trisodium citrate (TSC) was studied by depolarized dynamic light scattering (DDLS) and UV–vis spectrometry. The morphology of the nanoparticles, as well as the color and stability of the sols, are tuned by the concentration of the capping agent. The nanoparticles prepared with high TSC concentration (>10‑4 M) are blue triangular NPs showing a slight truncation of the tips with aging. When low TSC concentrations are used, the color of the sols changes from blue to yellow with aging time and a strong modification of the morphology occurs: the nanoparticle shape changes from triangular to spherical. Remarkably, they show a high degree of anisotropy. The aging process was followed by the UV–vis spectra and by measuring the rotational diffusion coefficient by DDLS, providing information on the nanoparticle size and shape evolution. The high intensity of depolarized signal and the high value of rotational diffusion coefficient suggest that the aging process increases the thickness and the roughness of the nanoparticles
Etymology as an Aid to Understanding Chemistry Concepts
NASA Astrophysics Data System (ADS)
Sarma, Nittala S.
2004-10-01
Recognition of word roots and the pattern of evolution of scientific terms can be helpful in understanding chemistry concepts (gaining knowledge of new concepts represented by related terms). The meaning and significance of various etymological roots, occurring as prefixes and suffixes in technical terms particularly of organic chemistry, are explained in a unified manner in order to show the connection of various concepts vis à vis the terms in currency. The meanings of some special words and many examples are provided. The interesting aspects of history and culture often involved in the evolution of terms will help sustain an abiding engagement in the study of chemistry.
Reflection measurements for luminescent powders
NASA Astrophysics Data System (ADS)
Kroon, R. E.
2018-04-01
Luminescent materials are useful in applications varying from lighting and display technologies to document security features and medical research, amongst many others. Measurement of the excitation range is an important consideration, and absorption bands are often determined from a decrease in the measured diffuse reflectance of the material using a ultraviolet-visible (UV-vis) spectrophotometer with an integrating sphere. Such a system may provide questionable results when used to measure the reflectance of a luminescence material, which is demonstrated for a Tb doped silica phosphor, because the system cannot differentiate between the reflected light and luminescence. It is shown that more reliable results are achieved for this phosphor by measuring the reflectance using a synchronous zero-offset scan in a fluorescence spectrometer equipped with an integrating sphere. This method is therefore recommended instead of traditional reflectance measurements using a UV-vis spectrophotometer for luminescent powders.
Preparation and spectral properties of europium hydrogen squarate microcrystals
NASA Astrophysics Data System (ADS)
Kolev, T.; Danchova, N.; Shandurkov, D.; Gutzov, S.
2018-04-01
A simple scheme for preparation of europium hydrogen squarate octahydrate microcrystals, Eu(HSq)3·8H2O is demonstrated. The microcrystalline powders obtained have a potential application as non-centrosymmetric and UV radiation - protective hybrid optical material. The site-symmetry of the Eu - ion is C2V or lower, obtained from diffuse reflectance spectra. The formation of europium hydrogen squarate is supported by IR - spectroscopy, UV-vis spectroscopy, chemical analysis and X-ray diffraction. A detailed analysis of the UV-vis and IR spectra of the micropowders prepared is presented. The reaction between europium oxide and squaric acid leads to formation of microcrystalline plate-like crystals of europium hydrogen squarate Eu(HSq)3·8H2O, a non-centrosymmetric hybrid optical material with a potential application as UV radiation - protective coatings.
A spectroscopic study of the chromatic properties of GafChromicEBT3 films.
Callens, M; Crijns, W; Simons, V; De Wolf, I; Depuydt, T; Maes, F; Haustermans, K; D'hooge, J; D'Agostino, E; Wevers, M; Pfeiffer, H; Van Den Abeele, K
2016-03-01
This work provides an interpretation of the chromatic properties of GafChromicEBT3 films based on the chemical nature of the polydiacetylene (PDA) molecules formed upon interaction with ionizing radiation. The EBT3 films become optically less transparent with increasing radiation dose as a result of the radiation-induced polymerization of diacetylene monomers. In contrast to empirical quantification of the chromatic properties, less attention has been given to the underlying molecular mechanism that induces the strong decrease in transparency. Unlaminated GafChromicEBT3 films were irradiated with a 6 MV photon beam to dose levels up to 20 Gy. The optical absorption properties of the films were investigated using visible (vis) spectroscopy. The presence of PDA molecules in the active layer of the EBT3 films was investigated using Raman spectroscopy, which probes the vibrational modes of the molecules in the layer. The vibrational modes assigned to PDA's were used in a theoretical vis-absorption model to fit our experimental vis-absorption spectra. From the fit parameters, one can assess the relative contribution of different PDA conformations and the length distribution of PDA's in the film. Vis-spectroscopy shows that the optical density increases with dose in the full region of the visible spectrum. The Raman spectrum is dominated by two vibrational modes, most notably by the ν(C≡C) and the ν(C=C) stretching modes of the PDA backbone. By fitting the vis-absorption model to experimental spectra, it is found that the active layer contains two distinct PDA conformations with different absorption properties and reaction kinetics. Furthermore, the mean PDA conjugation length is found to be 2-3 orders of magnitude smaller than the crystals PDA's are embedded in. Vis- and Raman spectroscopy provided more insight into the molecular nature of the radiochromic properties of EBT3 films through the identification of the excited states of PDA and the presence of two PDA conformations. The improved knowledge on the molecular composition of EBT3's active layer provides a framework for future fundamental modeling of the dose-response.
Material Interface Reconstruction in VisIt
DOE Office of Scientific and Technical Information (OSTI.GOV)
Meredith, J S
In this paper, we first survey a variety of approaches to material interface reconstruction and their applicability to visualization, and we investigate the details of the current reconstruction algorithm in the VisIt scientific analysis and visualization tool. We then provide a novel implementation of the original VisIt algorithm that makes use of a wide range of the finite element zoo during reconstruction. This approach results in dramatic improvements in quality and performance without sacrificing the strengths of the VisIt algorithm as it relates to visualization.
VisIVO: A Tool for the Virtual Observatory and Grid Environment
NASA Astrophysics Data System (ADS)
Becciani, U.; Comparato, M.; Costa, A.; Larsson, B.; Gheller, C.; Pasian, F.; Smareglia, R.
2007-10-01
We present the new features of VisIVO, software for the visualization and analysis of astrophysical data which can be retrieved from the Virtual Observatory framework and used for cosmological simulations running both on Windows and GNU/Linux platforms. VisIVO is VO standards compliant and supports the most important astronomical data formats such as FITS, HDF5 and VOTables. It is free software and can be downloaded from the web site http://visivo.cineca.it. VisIVO can interoperate with other astronomical VO compliant tools through PLASTIC (PLatform for AStronomical Tool InterConnection). This feature allows VisIVO to share data with many other astronomical packages to further analyze the loaded data.
visPIG--a web tool for producing multi-region, multi-track, multi-scale plots of genetic data.
Scales, Matthew; Jäger, Roland; Migliorini, Gabriele; Houlston, Richard S; Henrion, Marc Y R
2014-01-01
We present VISual Plotting Interface for Genetics (visPIG; http://vispig.icr.ac.uk), a web application to produce multi-track, multi-scale, multi-region plots of genetic data. visPIG has been designed to allow users not well versed with mathematical software packages and/or programming languages such as R, Matlab®, Python, etc., to integrate data from multiple sources for interpretation and to easily create publication-ready figures. While web tools such as the UCSC Genome Browser or the WashU Epigenome Browser allow custom data uploads, such tools are primarily designed for data exploration. This is also true for the desktop-run Integrative Genomics Viewer (IGV). Other locally run data visualisation software such as Circos require significant computer skills of the user. The visPIG web application is a menu-based interface that allows users to upload custom data tracks and set track-specific parameters. Figures can be downloaded as PDF or PNG files. For sensitive data, the underlying R code can also be downloaded and run locally. visPIG is multi-track: it can display many different data types (e.g association, functional annotation, intensity, interaction, heat map data,…). It also allows annotation of genes and other custom features in the plotted region(s). Data tracks can be plotted individually or on a single figure. visPIG is multi-region: it supports plotting multiple regions, be they kilo- or megabases apart or even on different chromosomes. Finally, visPIG is multi-scale: a sub-region of particular interest can be 'zoomed' in. We describe the various features of visPIG and illustrate its utility with examples. visPIG is freely available through http://vispig.icr.ac.uk under a GNU General Public License (GPLv3).
Chen, Yan; Wang, Jing; Liu, Chunmeng; Tang, Jinke; Kuang, Xiaojun; Wu, Mingmei; Su, Qiang
2013-02-11
An efficient near-infrared (NIR) phosphor LiSrPO(4):Eu(2+), Pr(3+) is synthesized by solid-state reaction and systematically investigated using x-ray diffraction, diffuse reflection spectrum, photoluminescence spectra at room temperature and 3 K, and the decay curves. The UV-Vis-NIR energy transfer mechanism is proposed based on these results. The results demonstrate Eu(2+) can be an efficient sensitizer for harvesting UV photon and greatly enhancing the NIR emission of Pr(3+) between 960 and 1060 nm through efficient energy feeding by allowed 4f-5d absorption of Eu(2+) with high oscillator strength. Eu(2+)/Pr(3+) may be an efficient donor-acceptor pair as solar spectral converter for Si solar cells.
The MPI-Mainz UV/VIS Spectral Atlas of Gaseous Molecules of Atmospheric Interest
NASA Astrophysics Data System (ADS)
Keller-Rudek, H.; Moortgat, G. K.; Sander, R.; Sörensen, R.
2013-12-01
We present the MPI-Mainz UV/VIS Spectral Atlas of Gaseous Molecules, which is a large collection of absorption cross sections and quantum yields in the ultraviolet and visible (UV/VIS) wavelength region for gaseous molecules and radicals primarily of atmospheric interest. The data files contain results of individual measurements, covering research of almost a whole century. To compare and visualize the data sets, multicoloured graphical representations have been created. The MPI-Mainz UV/VIS Spectral Atlas is available on the Internet at http://www.uv-vis-spectral-atlas-mainz.org. It now appears with improved browse and search options, based on new database software. In addition to the Web pages, which are continuously updated, a frozen version of the data is available under the doi:10.5281/zenodo.6951.
VisBOL: Web-Based Tools for Synthetic Biology Design Visualization.
McLaughlin, James Alastair; Pocock, Matthew; Mısırlı, Göksel; Madsen, Curtis; Wipat, Anil
2016-08-19
VisBOL is a Web-based application that allows the rendering of genetic circuit designs, enabling synthetic biologists to visually convey designs in SBOL visual format. VisBOL designs can be exported to formats including PNG and SVG images to be embedded in Web pages, presentations and publications. The VisBOL tool enables the automated generation of visualizations from designs specified using the Synthetic Biology Open Language (SBOL) version 2.0, as well as a range of well-known bioinformatics formats including GenBank and Pigeoncad notation. VisBOL is provided both as a user accessible Web site and as an open-source (BSD) JavaScript library that can be used to embed diagrams within other content and software.
Vispubdata.org: A Metadata Collection About IEEE Visualization (VIS) Publications.
Isenberg, Petra; Heimerl, Florian; Koch, Steffen; Isenberg, Tobias; Xu, Panpan; Stolper, Charles D; Sedlmair, Michael; Chen, Jian; Moller, Torsten; Stasko, John
2017-09-01
We have created and made available to all a dataset with information about every paper that has appeared at the IEEE Visualization (VIS) set of conferences: InfoVis, SciVis, VAST, and Vis. The information about each paper includes its title, abstract, authors, and citations to other papers in the conference series, among many other attributes. This article describes the motivation for creating the dataset, as well as our process of coalescing and cleaning the data, and a set of three visualizations we created to facilitate exploration of the data. This data is meant to be useful to the broad data visualization community to help understand the evolution of the field and as an example document collection for text data visualization research.
Flat-plate techniques for measuring reflectance of macro-algae (Ulva curvata)
Ramsey, Elijah W.; Rangoonwala, Amina; Thomsen, Mads Solgaard; Schwarzschild, Arthur
2012-01-01
We tested the consistency and accuracy of flat-plate spectral measurements (400–1000 nm) of the marine macrophyte Ulva curvata. With sequential addition of Ulva thallus layers, the reflectance progressively increased from 6% to 9% with six thalli in the visible (VIS) and from 5% to 19% with ten thalli in the near infrared (NIR). This progressive increase was simulated by a mathematical calculation based on an Ulva thallus diffuse reflectance weighted by a transmittance power series. Experimental and simulated reflectance differences that were particularly high in the NIR most likely resulted from residual water and layering structure unevenness in the experimental progression. High spectral overlap existed between fouled and non-fouled Ulva mats and the coexistent lagoon mud in the VIS, whereas in the NIR, spectral contrast was retained but substantially dampened by fouling.
Oh, Junghoon; Chang, Yun Hee; Kim, Yong-Hyun; Park, Sungjin
2016-04-28
Photocatalysts use sustainable solar light energy to trigger various catalytic reactions. Metal-free nanomaterials have been suggested as cost-effective and environmentally friendly photocatalysts. In this work, we propose thickness-controlled graphite oxide (GO) as a metal-free photocatalyst, which is produced by exfoliating thick GO particles via stirring and sonication. All GO samples exhibit photocatalytic activity for degrading an organic pollutant, rhodamine B under visible light, and the thickest sample shows the best catalytic performance. UV-vis-NIR diffuse reflectance absorption spectra indicate that thicker GO samples absorb more vis-NIR light than thinner ones. Density-functional theory calculations show that GO has a much smaller band gap than that of single-layer graphene oxide, and thus suggest that the largely-reduced band gap is responsible for this trend of light absorption.
Student Assessment of an Electronic Learning System.
ERIC Educational Resources Information Center
Fissel, Mark Charles
1993-01-01
The Video Information System (VIS) permits the fiber-optic distribution of teaching media from a central resource facility to the classroom. Undergraduate students taking a Western civilization course that used VIS, reported that VIS helped their notetaking, made the textbook more understandable, and encouraged learning. (KS)
The Vehicular Information Space Framework
NASA Astrophysics Data System (ADS)
Prinz, Vivian; Schlichter, Johann; Schweiger, Benno
Vehicular networks are distributed, self-organizing and highly mobile ad hoc networks. They allow for providing drivers with up-to-the-minute information about their environment. Therefore, they are expected to be a decisive future enabler for enhancing driving comfort and safety. This article introduces the Vehicular Information Space framework (VIS). Vehicles running the VIS form a kind of distributed database. It enables them to provide information like existing hazards, parking spaces or traffic densities in a location aware and fully distributed manner. In addition, vehicles can retrieve, modify and delete these information items. The underlying algorithm is based on features derived from existing structured Peer-to-Peer algorithms and extended to suit the specific characteristics of highly mobile ad hoc networks. We present, implement and simulate the VIS using a motorway and an urban traffic environment. Simulation studies on VIS message occurrence show that the VIS implies reasonable traffic overhead. Also, overall VIS message traffic is independent from the number of information items provided.
VisFlow - Web-based Visualization Framework for Tabular Data with a Subset Flow Model.
Yu, Bowen; Silva, Claudio T
2017-01-01
Data flow systems allow the user to design a flow diagram that specifies the relations between system components which process, filter or visually present the data. Visualization systems may benefit from user-defined data flows as an analysis typically consists of rendering multiple plots on demand and performing different types of interactive queries across coordinated views. In this paper, we propose VisFlow, a web-based visualization framework for tabular data that employs a specific type of data flow model called the subset flow model. VisFlow focuses on interactive queries within the data flow, overcoming the limitation of interactivity from past computational data flow systems. In particular, VisFlow applies embedded visualizations and supports interactive selections, brushing and linking within a visualization-oriented data flow. The model requires all data transmitted by the flow to be a data item subset (i.e. groups of table rows) of some original input table, so that rendering properties can be assigned to the subset unambiguously for tracking and comparison. VisFlow features the analysis flexibility of a flow diagram, and at the same time reduces the diagram complexity and improves usability. We demonstrate the capability of VisFlow on two case studies with domain experts on real-world datasets showing that VisFlow is capable of accomplishing a considerable set of visualization and analysis tasks. The VisFlow system is available as open source on GitHub.
SAHM:VisTrails (Software for Assisted Habitat Modeling for VisTrails): training course
Holcombe, Tracy
2014-01-01
VisTrails is an open-source management and scientific workflow system designed to integrate the best of both scientific workflow and scientific visualization systems. Developers can extend the functionality of the VisTrails system by creating custom modules for bundled VisTrails packages. The Invasive Species Science Branch of the U.S. Geological Survey (USGS) Fort Collins Science Center (FORT) and the U.S. Department of the Interior’s North Central Climate Science Center have teamed up to develop and implement such a module—the Software for Assisted Habitat Modeling (SAHM). SAHM expedites habitat modeling and helps maintain a record of the various input data, the steps before and after processing, and the modeling options incorporated in the construction of an ecological response model. There are four main advantages to using the SAHM:VisTrails combined package for species distribution modeling: (1) formalization and tractable recording of the entire modeling process; (2) easier collaboration through a common modeling framework; (3) a user-friendly graphical interface to manage file input, model runs, and output; and (4) extensibility to incorporate future and additional modeling routines and tools. In order to meet increased interest in the SAHM:VisTrails package, the FORT offers a training course twice a year. The course includes a combination of lecture, hands-on work, and discussion. Please join us and other ecological modelers to learn the capabilities of the SAHM:VisTrails package.
Chiao holds an Electronic Box Assembly from the TVIS in the SM during Expedition 10
2005-02-17
ISS010-E-18164 (17 February 2005) --- Astronaut Leroy Chiao, Expedition 10 commander and NASA ISS science officer, holds an Electronic Box Assembly, and Violation Isolation and Stabilization (VIS) Controller Assembly, which is part of the Treadmill Vibration Isolation System (TVIS) in the Zvezda Service Module of the International Space Station (ISS). Also in view is a VIS/TM data cable and VIS/TM power cable. This box receives power and distributes it between the treadmill and the VIS subassemblies.
M, Sundrarajan; K, Bama; M, Bhavani; S, Jegatheeswaran; S, Ambika; A, Sangili; P, Nithya; R, Sumathi
2017-06-01
In this work, we synthesized titanium dioxide (TiO 2 ) nanoparticles using leaf extract of Morinda citrifolia (M. citrifolia) by the advanced hydrothermal method. The synthesized TiO 2 nanoparticles were characterized by X-ray diffraction (XRD), Fourier transmission infrared (FT-IR), Ultraviolet-visible diffuse reflectance (UV-Vis DRS), Ultraviolet-visible spectroscopy (UV-Vis), Raman spectroscopy, and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM with EDX) techniques. The XRD major peak at 27.3° corresponds to the (110) lattice plane of tetragonal rutile TiO 2 phase and average crystalline size of nanoparticles is 10nm. The FT-IR result confirmed that TiO 2 nanoparticles and the presences of very few amount of anthraquinone and phenolic compounds of the leaf extract. The obtained nanoparticles were also characterized by UV-Vis DRS absorption spectroscopy and an intense band at 423nm clearly reveals the formation of nanoparticles. SEM images with EDX spectra clearly reveal the size of the nanoparticles, between 15 and 19nm in excellent quasi-spherical shape, by virtue of stabilization (capping) agent. The presence of elements-titanium and oxygen was verified with EDX spectrum. Furthermore, the inhibitory activity of green synthesized TiO 2 nanoparticles was tested against human pathogens like Staphylococcus aureus, Escherichia coli, Bacillus subtilis, Pseudomonas aeruginosa, Candida albicans, and Aspergillus niger by the agar well-diffusion method. The TiO 2 nanoparticles exhibited superior antimicrobial activity against Gram-positive bacteria, demonstrating their antimicrobial value against pathogenic diseases. Copyright © 2017 Elsevier B.V. All rights reserved.
Cheng, Shuying; Gao, Feng; Krummel, Karl I; Garland, Marc
2008-02-15
Two different organometallic ligand substitution reactions were investigated: (1) an achiral reactive system consisting of Rh(4)(CO)(12)+PPh(3)right harpoon over left harpoonRh(4)(CO)(11)PPh(3)+CO in n-hexane under argon; and (2) a chiral reactive system consisting of Rh(4)(CO)(12)+(S)-BINAPright harpoon over left harpoonRh(4)(CO)(10)BINAP+2CO in cyclohexane under argon. These two reactions were run at ultra high dilution. In both multi-component reactive systems the concentrations of all the solutes were less than 40ppm and many solute concentrations were just 1-10ppm. In situ spectroscopic measurements were carried out using UV-vis (Ultraviolet-visible) spectroscopy and UV-vis CD spectroscopy on the reactive organometallic systems (1) and (2), respectively. The BTEM algorithm was applied to these spectroscopic data sets. The reconstructed UV-vis pure component spectra of Rh(4)(CO)(12), Rh(4)(CO)(11)PPh(3) and Rh(4)(CO)(10)BINAP as well as the reconstructed UV-vis CD pure component spectra of Rh(4)(CO)(10)BINAP were successfully obtained from BTEM analyses. All these reconstructed pure component spectra are in good agreement with the experimental reference spectra. The concentration profiles of the present species were obtained by performing a least square fit with mass balance constraints for the reactions (1) and (2). The present results indicate that UV-vis and UV-vis-CD spectroscopies can be successfully combined with an appropriate chemometric technique in order to monitor reactive organometallic systems having UV and Vis chromophores.
Consistency of vegetation index seasonality across the Amazon rainforest
NASA Astrophysics Data System (ADS)
Maeda, Eduardo Eiji; Moura, Yhasmin Mendes; Wagner, Fabien; Hilker, Thomas; Lyapustin, Alexei I.; Wang, Yujie; Chave, Jérôme; Mõttus, Matti; Aragão, Luiz E. O. C.; Shimabukuro, Yosio
2016-10-01
Vegetation indices (VIs) calculated from remotely sensed reflectance are widely used tools for characterizing the extent and status of vegetated areas. Recently, however, their capability to monitor the Amazon forest phenology has been intensely scrutinized. In this study, we analyze the consistency of VIs seasonal patterns obtained from two MODIS products: the Collection 5 BRDF product (MCD43) and the Multi-Angle Implementation of Atmospheric Correction algorithm (MAIAC). The spatio-temporal patterns of the VIs were also compared with field measured leaf litterfall, gross ecosystem productivity and active microwave data. Our results show that significant seasonal patterns are observed in all VIs after the removal of view-illumination effects and cloud contamination. However, we demonstrate inconsistencies in the characteristics of seasonal patterns between different VIs and MODIS products. We demonstrate that differences in the original reflectance band values form a major source of discrepancy between MODIS VI products. The MAIAC atmospheric correction algorithm significantly reduces noise signals in the red and blue bands. Another important source of discrepancy is caused by differences in the availability of clear-sky data, as the MAIAC product allows increased availability of valid pixels in the equatorial Amazon. Finally, differences in VIs seasonal patterns were also caused by MODIS collection 5 calibration degradation. The correlation of remote sensing and field data also varied spatially, leading to different temporal offsets between VIs, active microwave and field measured data. We conclude that recent improvements in the MAIAC product have led to changes in the characteristics of spatio-temporal patterns of VIs seasonality across the Amazon forest, when compared to the MCD43 product. Nevertheless, despite improved quality and reduced uncertainties in the MAIAC product, a robust biophysical interpretation of VIs seasonality is still missing.
Consistency of Vegetation Index Seasonality Across the Amazon Rainforest
NASA Technical Reports Server (NTRS)
Maeda, Eduardo Eiji; Moura, Yhasmin Mendes; Wagner, Fabien; Hilker, Thomas; Lyapustin, Alexei I.; Wang, Yujie; Chave, Jerome; Mottus, Matti; Aragao, Luiz E.O.C.; Shimabukuro, Yosio
2016-01-01
Vegetation indices (VIs) calculated from remotely sensed reflectance are widely used tools for characterizing the extent and status of vegetated areas. Recently, however, their capability to monitor the Amazon forest phenology has been intensely scrutinized. In this study, we analyze the consistency of VIs seasonal patterns obtained from two MODIS products: the Collection 5 BRDF product (MCD43) and the Multi-Angle Implementation of Atmospheric Correction algorithm (MAIAC). The spatio-temporal patterns of the VIs were also compared with field measured leaf litterfall, gross ecosystem productivity and active microwave data. Our results show that significant seasonal patterns are observed in all VIs after the removal of view-illumination effects and cloud contamination. However, we demonstrate inconsistencies in the characteristics of seasonal patterns between different VIs and MODIS products. We demonstrate that differences in the original reflectance band values form a major source of discrepancy between MODIS VI products. The MAIAC atmospheric correction algorithm significantly reduces noise signals in the red and blue bands. Another important source of discrepancy is caused by differences in the availability of clear-sky data, as the MAIAC product allows increased availability of valid pixels in the equatorial Amazon. Finally, differences in VIs seasonal patterns were also caused by MODIS collection 5 calibration degradation. The correlation of remote sensing and field data also varied spatially, leading to different temporal offsets between VIs, active microwave and field measured data. We conclude that recent improvements in the MAIAC product have led to changes in the characteristics of spatio-temporal patterns of VIs seasonality across the Amazon forest, when compared to the MCD43 product. Nevertheless, despite improved quality and reduced uncertainties in the MAIAC product, a robust biophysical interpretation of VIs seasonality is still missing.
VisRseq: R-based visual framework for analysis of sequencing data
2015-01-01
Background Several tools have been developed to enable biologists to perform initial browsing and exploration of sequencing data. However the computational tool set for further analyses often requires significant computational expertise to use and many of the biologists with the knowledge needed to interpret these data must rely on programming experts. Results We present VisRseq, a framework for analysis of sequencing datasets that provides a computationally rich and accessible framework for integrative and interactive analyses without requiring programming expertise. We achieve this aim by providing R apps, which offer a semi-auto generated and unified graphical user interface for computational packages in R and repositories such as Bioconductor. To address the interactivity limitation inherent in R libraries, our framework includes several native apps that provide exploration and brushing operations as well as an integrated genome browser. The apps can be chained together to create more powerful analysis workflows. Conclusions To validate the usability of VisRseq for analysis of sequencing data, we present two case studies performed by our collaborators and report their workflow and insights. PMID:26328469
VisRseq: R-based visual framework for analysis of sequencing data.
Younesy, Hamid; Möller, Torsten; Lorincz, Matthew C; Karimi, Mohammad M; Jones, Steven J M
2015-01-01
Several tools have been developed to enable biologists to perform initial browsing and exploration of sequencing data. However the computational tool set for further analyses often requires significant computational expertise to use and many of the biologists with the knowledge needed to interpret these data must rely on programming experts. We present VisRseq, a framework for analysis of sequencing datasets that provides a computationally rich and accessible framework for integrative and interactive analyses without requiring programming expertise. We achieve this aim by providing R apps, which offer a semi-auto generated and unified graphical user interface for computational packages in R and repositories such as Bioconductor. To address the interactivity limitation inherent in R libraries, our framework includes several native apps that provide exploration and brushing operations as well as an integrated genome browser. The apps can be chained together to create more powerful analysis workflows. To validate the usability of VisRseq for analysis of sequencing data, we present two case studies performed by our collaborators and report their workflow and insights.
Interpreting Observations of Large-Scale Traveling Ionospheric Disturbances by Ionospheric Sounders
NASA Astrophysics Data System (ADS)
Pederick, L. H.; Cervera, M. A.; Harris, T. J.
2017-12-01
From July to October 2015, the Australian Defence Science and Technology Group conducted an experiment during which a vertical incidence sounder (VIS) was set up at Alice Springs Airport. During September 2015 this VIS observed the passage of many large-scale traveling ionospheric disturbances (TIDs). By plotting the measured virtual heights across multiple frequencies as a function of time, the passage of the TID can be clearly displayed. Using this plotting method, we show that all the TIDs observed during the campaign by the VIS at Alice Springs show an apparent downward phase progression of the crests and troughs. The passage of the TID can be more clearly interpreted by plotting the true height of iso-ionic contours across multiple plasma frequencies; the true heights can be obtained by inverting each ionogram to obtain an electron density profile. These plots can be used to measure the vertical phase speed of a TID and also reveal a time lag between events seen in true height compared to virtual height. To the best of our knowledge, this style of analysis has not previously been applied to other swept-frequency sounder observations. We develop a simple model to investigate the effect of the passage of a large-scale TID on a VIS. The model confirms that for a TID with a downward vertical phase progression, the crests and troughs will appear earlier in virtual height than in true height and will have a smaller apparent speed in true height than in virtual height.
Diffusion-advection within dynamic biological gaps driven by structural motion
NASA Astrophysics Data System (ADS)
Asaro, Robert J.; Zhu, Qiang; Lin, Kuanpo
2018-04-01
To study the significance of advection in the transport of solutes, or particles, within thin biological gaps (channels), we examine theoretically the process driven by stochastic fluid flow caused by random thermal structural motion, and we compare it with transport via diffusion. The model geometry chosen resembles the synaptic cleft; this choice is motivated by the cleft's readily modeled structure, which allows for well-defined mechanical and physical features that control the advection process. Our analysis defines a Péclet-like number, AD, that quantifies the ratio of time scales of advection versus diffusion. Another parameter, AM, is also defined by the analysis that quantifies the full potential extent of advection in the absence of diffusion. These parameters provide a clear and compact description of the interplay among the well-defined structural, geometric, and physical properties vis-a ̀-vis the advection versus diffusion process. For example, it is found that AD˜1 /R2 , where R is the cleft diameter and hence diffusion distance. This curious, and perhaps unexpected, result follows from the dependence of structural motion that drives fluid flow on R . AM, on the other hand, is directly related (essentially proportional to) the energetic input into structural motion, and thereby to fluid flow, as well as to the mechanical stiffness of the cleftlike structure. Our model analysis thus provides unambiguous insight into the prospect of competition of advection versus diffusion within biological gaplike structures. The importance of the random, versus a regular, nature of structural motion and of the resulting transient nature of advection under random motion is made clear in our analysis. Further, by quantifying the effects of geometric and physical properties on the competition between advection and diffusion, our results clearly demonstrate the important role that metabolic energy (ATP) plays in this competitive process.
Interactive access and management for four-dimensional environmental data sets using McIDAS
NASA Technical Reports Server (NTRS)
Hibbard, William L.; Tripoli, Gregory J.
1993-01-01
Significant accomplishments in the past year are presented and include the following: (1) enhancements to VIS-5D; (2) Implementation of the VIS AD System; and (3) numerical modeling applications. Focus of current research and plans for next year in the following areas are briefly discussed: (1) continued development and application of the VIS-AD system; (2) further enhancements to VIS-5D; and (3) plans for modeling applications.
VisEL: Visualisation of Expertise Level in a Special Interest Group Knowledge Portal
NASA Astrophysics Data System (ADS)
Zulhafizsyam Wan Ahmad, Wan Muhammad; Sulaiman, Shahida; Yusof, Umi Kalsom
A variety of portals are available nowadays to support diverse purposes such as commercial, publishing, personal, affinity and corporate portals. Affinity portals promote electronic communities who share common interest such as a special interest group (SIG). Knowledge portal is an emerging trend that benefits the existing portal technology by designing such portals with proper representation of the members' shared knowledge. Besides textual representation for diverse expertise levels, graphical visualisation will be able to support the requirements in searching and representing expertise level among e-community. There is a number of existing SIG portals available. However, they do not visualise effectively and accurately the expertise level of members and make it difficult for users to search their targeted experts for instance searching the highest expertise level to have a discussion and to solve their problems related to a project. The goal of this paper is to propose a graphical visualisation of expertise level method (VisEL) using an interactive tag cloud technique that represents expertise level of each member based on their knowledge in a software engineering SIG portal.
Tropospheric Ozone Profiling Using Simulated GEO-CAPE Measurement
NASA Technical Reports Server (NTRS)
Natraj, Vijay; Li, Xiong; Kulawik, Susan; Chance, Kelly; Chatfield, Robert; Edwards, David P .; Eldering, Annmarie; Francis, Gene; Kurosu, Thomas; Pickering, Kenneth;
2011-01-01
Multi-spectral retrievals (UV+VIS, UV+TIR, UV+VIS+TIR) improve sensitivity to the variability in near-surface O3 by a factor of 2 - 2.7 over those from UV or TIR alone. Multi-spectral retrievals provide the largest benefit when there is enhanced O3 near the surface. Combining all 3 wavelengths (UV+VIS+TIR) provides the greatest sensitivity below 850 hPa, with a 36% improvement over UV+VIS and a 17% improvement over UV+TIR. The impacts of clouds and aerosols are being assessed.
Joshi, Ashish; de Araujo Novaes, Magdala; Machiavelli, Josiane; Iyengar, Sriram; Vogler, Robert; Johnson, Craig; Zhang, Jiajie; Hsu, Chiehwen E
2012-01-01
Public health data is typically organized by geospatial unit. GeoVisualization (GeoVis) allows users to see information visually on a map. Examine telehealth users' perceptions towards existing public health GeoVis applications and obtains users' feedback about features important for the design and development of Human Centered GeoVis application "the SanaViz". We employed a cross sectional study design using mixed methods approach for this pilot study. Twenty users involved with the NUTES telehealth center at Federal University of Pernambuco (UFPE), Recife, Brazil were enrolled. Open and closed ended questionnaires were used to gather data. We performed audio recording for the interviews. Information gathered included socio-demographics, prior spatial skills and perception towards use of GeoVis to evaluate telehealth services. Card sorting and sketching methods were employed. Univariate analysis was performed for the continuous and categorical variables. Qualitative analysis was performed for open ended questions. Existing Public Health GeoVis applications were difficult to use. Results found interaction features zooming, linking and brushing and representation features Google maps, tables and bar chart as most preferred GeoVis features. Early involvement of users is essential to identify features necessary to be part of the human centered GeoVis application "the SanaViz".
Yao Chen; Yongming Fan; Mandla A. Tshabalala; Nicole M. Stark; Jianmin Gao
2012-01-01
To investigate the optical properties of chemithermomechanical pulp (CTMP) from Eucalyptus camaldulensis, one group of samples of CTMP was aged by heating, and another group was first subjected to bleaching with different bleaching agents, and then aging by exposure to sunlight. Chromophores were analyzed using diffuse reflectance UV-Vis spectra (...
[Corporate and technological changes in São Paulo medicine in 1930].
Mota, André; Schraiber, Lilia Blima
2009-01-01
Through the historical study of the corporate and technological changes experienced by doctors in São Paulo in the 1930s, we intend to identify how changes in the fields of equipment and knowledge came from the emergence of specialties, which led to corporate changes and rearrangements in the face of the dilemmas introduced by the Getúlio Vargas government and its policy of centralizing power. Connections are pointed out of a symbolic and representative order, backed by doctors considered 'old-school' and those that represented the 'new' times in medicine, evidencing the clashes between these currents vis-à-vis the specialization movement and particular landmarks in the history of São Paulo.
Sharipov holds an Electronic Box Assembly from the TVIS in the SM during Expedition 10
2005-02-17
ISS010-E-18167 (17 February 2005) --- Cosmonaut Salizhan S. Sharipov, Expedition 10 flight engineer representing Russia's Federal Space Agency, holds an Electronic Box Assembly, and Violation Isolation and Stabilization (VIS) Controller Assembly, which is part of the Treadmill Vibration Isolation System (TVIS) in the Zvezda Service Module of the International Space Station (ISS). Also in view is a VIS/TM data cable and VIS/TM power cable. This box receives power and distributes it between the treadmill and the VIS subassemblies.
Zhao, Weirong; Ai, Zhuyu; Dai, Jiusong; Zhang, Meng
2014-01-01
Photocatalytic water splitting for hydrogen evolution is a potential way to solve many energy and environmental issues. Developing visible-light-active photocatalysts to efficiently utilize sunlight and finding proper ways to improve photocatalytic activity for H2 evolution have always been hot topics for research. This study attempts to expand the use of sunlight and to enhance the photocatalytic activity of TiO2 by N doping and Au loading. Au/N-doped TiO2 photocatalysts were synthesized and successfully used for photocatalytic water splitting for H2 evolution under irradiation of UV and UV-vis light, respectively. The samples were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (DRS), photoluminescence spectroscopy (PL), and photoelectrochemical characterizations. DRS displayed an extension of light absorption into the visible region by doping of N and depositing with Au, respectively. PL analysis indicated electron-hole recombination due to N doping and an efficient inhibition of electron-hole recombination due to the loaded Au particles. Under the irradiation of UV light, the photocatalytic hydrogen production rate of the as-synthesized samples followed the order Au/TiO2 > Au/N-doped TiO2 > TiO2 > N-doped TiO2. While under irradiation of UV-vis light, the N-TiO2 and Au/N-TiO2 samples show higher H2 evolution than their corresponding nitrogen-free samples (TiO2 and Au/TiO2). This inconsistent result could be attributed to the doping of N and the surface plasmonic resonance (SPR) effect of Au particles extending the visible light absorption. The photoelectrochemical characterizations further indicated the enhancement of the visible light response of Au/N-doped TiO2. Comparative studies have shown that a combination of nitrogen doping and Au loading enhanced the visible light response of TiO2 and increased the utilization of solar energy, greatly boosting the photocatalytic activity for hydrogen production under UV-vis light.
Glenn, Edward P; Huete, Alfredo R; Nagler, Pamela L; Nelson, Stephen G
2008-03-28
Vegetation indices (VIs) are among the oldest tools in remote sensing studies. Although many variations exist, most of them ratio the reflection of light in the red and NIR sections of the spectrum to separate the landscape into water, soil, and vegetation. Theoretical analyses and field studies have shown that VIs are near-linearly related to photosynthetically active radiation absorbed by a plant canopy, and therefore to light-dependent physiological processes, such as photosynthesis, occurring in the upper canopy. Practical studies have used time-series VIs to measure primary production and evapotranspiration, but these are limited in accuracy to that of the data used in ground truthing or calibrating the models used. VIs are also used to estimate a wide variety of other canopy attributes that are used in Soil-Vegetation-Atmosphere Transfer (SVAT), Surface Energy Balance (SEB), and Global Climate Models (GCM). These attributes include fractional vegetation cover, leaf area index, roughness lengths for turbulent transfer, emissivity and albedo. However, VIs often exhibit only moderate, non-linear relationships to these canopy attributes, compromising the accuracy of the models. We use case studies to illustrate the use and misuse of VIs, and argue for using VIs most simply as a measurement of canopy light absorption rather than as a surrogate for detailed features of canopy architecture. Used this way, VIs are compatible with "Big Leaf" SVAT and GCMs that assume that canopy carbon and moisture fluxes have the same relative response to the environment as any single leaf, simplifying the task of modeling complex landscapes.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Baker, M Pauline
2007-06-30
The VisPort visualization portal is an experiment in providing Web-based access to visualization functionality from any place and at any time. VisPort adopts a service-oriented architecture to encapsulate visualization functionality and to support remote access. Users employ browser-based client applications to choose data and services, set parameters, and launch visualization jobs. Visualization products typically images or movies are viewed in the user's standard Web browser. VisPort emphasizes visualization solutions customized for specific application communities. Finally, VisPort relies heavily on XML, and introduces the notion of visualization informatics - the formalization and specialization of information related to the process and productsmore » of visualization.« less
NASA Astrophysics Data System (ADS)
Phenglengdi, Butsari
This research evaluates the use of a molecular level visualisation approach in Thai secondary schools. The goal is to obtain insights about the usefulness of this approach, and to examine possible improvements in how the approach might be applied in the future. The methodology used for this research used both qualitative and quantitative approaches. Data were collected in the form of pre- and post-intervention multiple choice questions, open-ended-questions, drawing exercises, one-to-one interviews and video recordings of class activity. The research was conducted in two phases, involving a total of 261 students from the 11th Grade in Thailand. The use of VisChem animations in three studies was evaluated in Phase I. Study 1 was a pilot study exploring the benefits of incorporating VisChem animations to portray the molecular level. Study 2 compared test results between students exposed to these animations of molecular level events, and those not. Finally, in Study 3, test results were gathered from different types of schools (a rural school, a city school, and a university school). The results showed that students (and teachers) had misconceptions at the molecular level, and VisChem animations could help students understand chemistry concepts at the molecular level across all three types of schools. While the animation treatment group had a better score on the topic of states of water, the non-animation treatment group had a better score on the topic of dissolving sodium chloride in water than the animation group. The molecular level visualisation approach as a learning design was evaluated in Phase II. This approach involved a combination of VisChem animations, pictures, and diagrams together with the seven-step VisChem learning design. The study involved three classes of students, each with a different treatment, described as Class A - Traditional approach; Class B - VisChem animations with traditional approach; and Class C - Molecular level visualisation approach. Pre-test and post-test scores were compared across the three classes. The results from the multiple choice and calculation tests showed that the Class C - molecular level visualisation approach group demonstrated a deeper understanding of chemistry concepts than students in Classes A and B. However, the results showed that all the students were unable to perform satisfactorily on the calculation tests because the students had insufficient prior knowledge about stoichiometry to connect with the new knowledge. In the drawing tests the students exposed to the molecular level visualisation approach had a better mental model than the other classes, albeit with some remaining misconceptions. The findings highlight the intersecting nature of the teacher, student, and modelling in chemistry teaching. Use of a multi-step molecular level visualisation approach that encourages observation, reflection of prior understanding, and multiple opportunities at viewing (and using various visualisation elements), are key elements leading to a deeper understanding of chemistry. Presentation of the multi-step molecular level visualisation approach must be coupled with careful consideration of student prior knowledge, and with adequate guidance from a teacher who understands the topics at a deep level.
Analysis of laser printer and photocopier toners by spectral properties and chemometrics
NASA Astrophysics Data System (ADS)
Verma, Neha; Kumar, Raj; Sharma, Vishal
2018-05-01
The use of printers to generate falsified documents has become a common practice in today's world. The examination and identification of the printed matter in the suspected documents (civil or criminal cases) may provide important information about the authenticity of the document. In the present study, a total number of 100 black toner samples both from laser printers and photocopiers were examined using diffuse reflectance UV-Vis Spectroscopy. The present research is divided into two parts; visual discrimination and discrimination by using multivariate analysis. A comparison between qualitative and quantitative analysis showed that multivariate analysis (Principal component analysis) provides 99.59%pair-wise discriminating power for laser printer toners while 99.84% pair-wise discriminating power for photocopier toners. The overall results obtained confirm the applicability of UV-Vis spectroscopy and chemometrics, in the nondestructive analysis of toner printed documents while enhancing their evidential value for forensic applications.
Large-Scale Astrophysical Visualization on Smartphones
NASA Astrophysics Data System (ADS)
Becciani, U.; Massimino, P.; Costa, A.; Gheller, C.; Grillo, A.; Krokos, M.; Petta, C.
2011-07-01
Nowadays digital sky surveys and long-duration, high-resolution numerical simulations using high performance computing and grid systems produce multidimensional astrophysical datasets in the order of several Petabytes. Sharing visualizations of such datasets within communities and collaborating research groups is of paramount importance for disseminating results and advancing astrophysical research. Moreover educational and public outreach programs can benefit greatly from novel ways of presenting these datasets by promoting understanding of complex astrophysical processes, e.g., formation of stars and galaxies. We have previously developed VisIVO Server, a grid-enabled platform for high-performance large-scale astrophysical visualization. This article reviews the latest developments on VisIVO Web, a custom designed web portal wrapped around VisIVO Server, then introduces VisIVO Smartphone, a gateway connecting VisIVO Web and data repositories for mobile astrophysical visualization. We discuss current work and summarize future developments.
Mathis, John E.; Lieffers, Justin J.; Mitra, Chandrima; ...
2015-11-06
The composition of anatase TiO 2 was modified by codoping using combinations of a transition metal and nitrogen in order to increase its photocatalytic activity and extend it performance in the visible region of the electromagnetic spectrum. The transition metals (Mn, Co, Ni, Cu) were added during the hydrothermal preparation of mesoporous TiO 2 particles, and the nitrogen was introduced by post-annealing in flowing ammonia gas at high temperature. The samples were analyzed by SEM, XRD, BET, inductively-coupled plasma spectroscopy, and diffuse reflectance UV-vis spectroscopy. The photocatalytic activity was assessed by observing the change in methylene blue concentrations under bothmore » UV-vis and visible-only light irradiation. As a result, the photocatalytic activity of the (Mn,N), (Co,N), (Cu,N), and Ni,N) codoped TiO 2 was significantly enhanced relative to (N) TiO 2.« less
NASA Astrophysics Data System (ADS)
Truong, Quang Duc; Le, Thanh Son; Ling, Yong-Chien
2014-12-01
C, N codoped TiO2 catalyst has been synthesized by thermal decomposition of a novel water-soluble titanium complex. The structure, morphology, and optical properties of the synthesized TiO2 catalyst were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, and UV-vis diffuse reflectance spectroscopy. The photocatalytic activity of the Pt deposited TiO2 catalysts synthesized at different temperatures was evaluated by means of hydrogen evolution reaction under both UV-vis and visible light irradiation. The investigation results reveal that the photocatalytic H2 evolution rate strongly depended on the crystalline grain size as well as specific surface area of the synthesized catalyst. Our studies successfully demonstrate a simple method for the synthesis of visible-light responsive Pt deposited TiO2 catalyst for solar hydrogen production.
Development of an analysis tool for cloud base height and visibility
NASA Astrophysics Data System (ADS)
Umdasch, Sarah; Reinhold, Steinacker; Manfred, Dorninger; Markus, Kerschbaum; Wolfgang, Pöttschacher
2014-05-01
The meteorological variables cloud base height (CBH) and horizontal atmospheric visibility (VIS) at surface level are of vital importance for safety and effectiveness in aviation. Around 20% of all civil aviation accidents in the USA from 2003 to 2007 were due to weather related causes, around 18% of which were owing to decreased visibility or ceiling (main CBH). The aim of this study is to develop a system generating quality-controlled gridded analyses of the two parameters based on the integration of various kinds of observational data. Upon completion, the tool is planned to provide guidance for nowcasting during take-off and landing as well as for flights operated under visual flight rules. Primary input data consists of manual as well as instrumental observation of CBH and VIS. In Austria, restructuring of part of the standard meteorological stations from human observation to automatic measurement of VIS and CBH is currently in progress. As ancillary data, satellite derived products can add 2-dimensional information, e.g. Cloud Type by NWC SAF (Nowcasting Satellite Application Facilities) MSG (Meteosat Second Generation). Other useful available data are meteorological surface measurements (in particular of temperature, humidity, wind and precipitation), radiosonde, radar and high resolution topography data. A one-year data set is used to study the spatial and weather-dependent representativeness of the CBH and VIS measurements. The VERA (Vienna Enhanced Resolution Analysis) system of the Institute of Meteorology and Geophysics of the University of Vienna provides the framework for the analysis development. Its integrated "Fingerprint" technique allows the insertion of empirical prior knowledge and ancillary information in the form of spatial patterns. Prior to the analysis, a quality control of input data is performed. For CBH and VIS, quality control can consist of internal consistency checks between different data sources. The possibility of two-dimensional consistency checks has to be explored. First results in the development of quality control features and fingerprints will be shown.
Paisani, Denise de Moraes; Lunardi, Adriana Claudia; da Silva, Cibele Cristine Berto Marques; Porras, Desiderio Cano; Tanaka, Clarice; Carvalho, Celso Ricardo Fernandes
2013-08-01
Incentive spirometers are widely used in clinical practice and classified as flow-oriented (FIS) and volume-oriented (VIS). Until recently the respiratory inductive plethysmography used to evaluate the effects of incentive spirometry on chest wall mechanics presented limitations, which may explain why the impact of VIS and FIS remains poorly known. To compare the effects of VIS and FIS on thoracoabdominal mechanics and respiratory muscle activity in healthy volunteers. This cross-sectional trial assessed 20 subjects (12 female, ages 20-40 years, body mass index 20-30 kg/m(2)). All subjects performed 8 quiet breaths and 8 deep breaths with FIS and VIS, in a randomized order. We measured thoracoabdominal chest wall, upper and lower rib-cage, and abdominal volumes with optoelectronic plethysmography, and the muscle activity of the sternocleidomastoid and superior and inferior intercostal muscles with electromyography. VIS increased chest wall volume more than did FIS (P = .007) and induced a larger increase in the upper and lower rib-cages and abdomen (156%, 91%, and 151%, respectively, P < .001). By contrast, FIS induced more activity in the accessory muscles of respiration than did VIS (P < .001). VIS promotes a greater increase in chest wall volume, with a larger abdominal contribution and lower respiratory muscle activity, than does FIS in healthy adults.
NASA Astrophysics Data System (ADS)
Sivakumar, S.; Venkatesan, A.; Soundhirarajan, P.; Khatiwada, Chandra Prasad
2015-02-01
In the present study, synthesized pure and Ag (1%, 2%, and 3%) doped Cadmium Oxide (CdO) nanoparticles by chemical precipitation method. Then, the synthesized products were characterized by thermo gravimetric-differential thermal analysis (TG-DTA), X-ray diffraction (XRD) analysis, Fourier transform infrared (FT-IR) spectroscopy, Ultra violet-Vis diffused reflectance spectroscopy (UV-Vis-DRS), Scanning electron microscopy (SEM), Energy dispersive X-rays (EDX) spectroscopy, and anti-bacterial activities, respectively. The transition temperatures and phase transitions of Cd(OH)2 to CdO at 400 °C was confirmed by TG-DTA analysis. The XRD patterns show the cubic shape and average particle sizes are 21, 40, 34, and 37 nm, respectively for pure and Ag doped samples. FT-IR study confirmed the presence of CdO and Ag at 677 and 459 cm-1, respectively. UV-Vis-DRS study shows the variation on direct and indirect band gaps. The surface morphologies and elemental analysis have been confirmed from SEM and with EDX. In addition, the synthesized products have been characterized by antibacterial activities against Gram-positive and negative bacteria. Further, the present investigation suggests that CdO nanoparticles have the great potential applications on various industrial and medical fields of research.
NASA Astrophysics Data System (ADS)
Klein, Marek; Nadolna, Joanna; Gołąbiewska, Anna; Mazierski, Paweł; Klimczuk, Tomasz; Remita, Hynd; Zaleska-Medynska, Adriana
2016-08-01
TiO2 (P25) was modified with small and relatively monodisperse mono- and bimetallic clusters (Ag, Pd, Pt, Ag/Pd, Ag/Pt and Pd/Pt) induced by radiolysis to improve its photocatalytic activity. The as-prepared samples were characterized by X-ray fluorescence spectrometry (XRF), photoluminescence spectrometry (PL), diffuse reflectance spectroscopy (DRS), X-ray powder diffractometry (XRD), scanning transition electron microscopy (STEM) and BET surface area analysis. The effect of metal type (mono- and bimetallic modification) as well as deposition method (simultaneous or subsequent deposition of two metals) on the photocatalytic activity in toluene removal in gas phase under UV-vis irradiation (light-emitting diodes- LEDs) and phenol degradation in liquid phase under visible light irradiation (λ > 420 nm) were investigated. The highest photoactivity under Vis light was observed for TiO2 co-loaded with platinum (0.1%) and palladium (0.1%) clusters. Simultaneous addition of metal precursors results in formation of larger metal nanoparticles (15-30 nm) on TiO2 surface and enhances the Vis-induced activity of Ag/Pd-TiO2 up to four times, while the subsequent metal ions addition results in formation of metal particle size ranging from 4 to 20 nm. Subsequent addition of metal precursors results in formation of BNPs (bimetallic nanoparticle) composites showing higher stability in four cycles of toluene degradation under UV-vis. Obtained results indicated that direct electron transfer from the BNPs to the conduction band of the semiconductor is responsible for visible light photoactivity, whereas superoxide radicals (such as O2rad- and rad OOH) are responsible for pollutants degradation over metal-TiO2 composites.
The MPI-Mainz UV/VIS Spectral Atlas of Gaseous Molecules of Atmospheric Interest
NASA Astrophysics Data System (ADS)
Keller-Rudek, H.; Moortgat, G. K.; Sander, R.; Sörensen, R.
2013-08-01
We present the MPI-Mainz UV/VIS Spectral Atlas, which is a large collection of absorption cross sections and quantum yields in the ultraviolet and visible (UV/VIS) wavelength region for gaseous molecules and radicals primarily of atmospheric interest. The data files contain results of individual measurements, covering research of almost a whole century. To compare and visualize the data sets, multicoloured graphical representations have been created. The Spectral Atlas is available on the internet at http://www.uv-vis-spectral-atlas-mainz.org. It now appears with improved browse and search options, based on new database software. In addition to the web pages, which are continuously updated, a frozen version of the data is available under the doi:10.5281/zenodo.6951.
NASA Astrophysics Data System (ADS)
Piantanida, Ivo; Mašić, Lozika; Rusak, Gordana
2009-04-01
Interactions of five flavonoids with dsRNA and single stranded ssRNA were studied by UV/vis titrations. The results obtained supported the intercalative binding mode as a dominant interaction of studied flavonoids with dsRNA as well as major interaction with ssRNA. Furthermore, changes of the UV/vis spectra of flavonoids induced by addition of poly G or poly C, respectively, are significantly stronger than changes induced by double stranded poly G-poly C, pointing to essential role of the free poly G or poly C sequence (not hydrogen bonded in double helix). Exclusively poly G caused significant batochromic shift of the UV/vis maxima of all studied flavonoids, whereby the intensity of batochromic shift is nicely correlated to the number of OH groups of flavonoid. Unlikely to poly G, addition of poly A and poly U induced measurable changes only in the UV/vis spectra of flavonoids characterised by no OH (galangin) or three OH groups (myricetin) on the phenyl part of the molecule. Consequently, flavonoids with one- or two-OH groups on the phenyl part of the molecule (luteolin, fisetin, kaempferol) specifically differentiate between poly A, poly U (negligible changes in the UV/Vis spectra) and poly G (strong changes in the UV/Vis spectra) as well as poly C (moderate changes in the UV/Vis spectra).
VisBricks: multiform visualization of large, inhomogeneous data.
Lex, Alexander; Schulz, Hans-Jörg; Streit, Marc; Partl, Christian; Schmalstieg, Dieter
2011-12-01
Large volumes of real-world data often exhibit inhomogeneities: vertically in the form of correlated or independent dimensions and horizontally in the form of clustered or scattered data items. In essence, these inhomogeneities form the patterns in the data that researchers are trying to find and understand. Sophisticated statistical methods are available to reveal these patterns, however, the visualization of their outcomes is mostly still performed in a one-view-fits-all manner. In contrast, our novel visualization approach, VisBricks, acknowledges the inhomogeneity of the data and the need for different visualizations that suit the individual characteristics of the different data subsets. The overall visualization of the entire data set is patched together from smaller visualizations, there is one VisBrick for each cluster in each group of interdependent dimensions. Whereas the total impression of all VisBricks together gives a comprehensive high-level overview of the different groups of data, each VisBrick independently shows the details of the group of data it represents. State-of-the-art brushing and visual linking between all VisBricks furthermore allows the comparison of the groupings and the distribution of data items among them. In this paper, we introduce the VisBricks visualization concept, discuss its design rationale and implementation, and demonstrate its usefulness by applying it to a use case from the field of biomedicine. © 2011 IEEE
NASA Astrophysics Data System (ADS)
Nadeem, Saad; Iqbal, Farukh; Mutalib, Mohamed Ibrahim Abdul; Abdullah, Bawadi; Shaharun, Maizatul Shima
2017-10-01
Metal composite materials-48 (MCM-48) with silica zirconia mesoporous matrix (having a Zr/Si ratio of 0.02) has been developed successfully using autogenous conditions and Copper tetra phenyl porphyrin (CuTPP) inclusion via flexible ligand approach. Thermo gravimetric analysis (TGA) was used to study the thermal stability which gives the stability up to 700°C, Fourier transform infrared spectroscopy (FTIR) for the functional group attachment also confirmed the MCM-48 structure and the Zirconia addition and X-Ray photon spectroscopy (XPS) for the binding energies and bonding also revealed the surface Zr4+ states. DRS-UV-Vis study for the photophysical behaviour, visible light activation and band gap reduction which reduced from 5.6 to 2.8 eV. All the characterizations have confirmed that nanoscale mesoporous silica with successful inclusion of zirconia in the matrix and the encapsulation of CuTPP was confirmed via diffuse reflectance (DR Uv-Vis) spectroscopy.
NASA Astrophysics Data System (ADS)
Hajian, Robabeh; Ehsanikhah, Amin
2018-01-01
This study describes the immobilization of tetraphenylporphyrinatomanganese(III) chloride, (MnPor), onto imidazole functionalized MCM-41 with magnetite nanoparticle core (Fe3O4@MCM-41-Im). The resultant material (Fe3O4@MCM-41-Im@MnPor) was characterized by X-ray diffractometry (XRD), Fourier transform infra-red (FT-IR), diffuse reflectance UV-Vis spectrophotometry (DR UV-Vis), field emission scanning electron microscopy (FESEM), Inductively coupled plasma (ICP), analyzer transmission electron microscopy (TEM) and Brunauer-Emmett-Teller (BET) surface area. This new heterogenized catalyst was applied as an efficient catalyst for the epoxidation of a variety of cyclic and linear olefins with NaIO4 under mild conditions. The prepared catalyst can be easily recovered through the application of an external magnet, and reused several times without any significant decrease in activity and magnetic properties.
The ethics of silence: Does conflict of interest explain employee silence?
Anderson, James
2018-03-01
Employee silence constitutes a significant threat to organizational success. This article argues that silence is a by-product of a structural Conflict of Interest (COI) between employees and their employers. This argument turns on the claim, also defended here, that employees are in a privileged position vis-à-vis knowledge of their work and that leaders-whether they recognize it or not-are dependent on their employees for reliable information about the work they are doing. Employee voice, therefore, is an organizational necessity. It is also a moral achievement as it involves risking one's personal interests for the sake of the organization. Leaders must take steps to mitigate COI and encourage employee voice; this article provides several strategies for doing exactly that.
Hall, Ronald E; Breland-Noble, Alfiee
2011-01-01
Due to the historical preponderance of racial and/or intellectual homogeneity in the field of psychology, Eurocentrism set the "gold standard" for its method of intervention. As such, it might be argued that psychology remains a bastion of Eurocentric thought despite the globalization of knowledge and the influx of racially and ethnically diverse scientists into the research endeavor. At the same time and the significant increase in the immigrant Arab population, Arab Americans remain a less familiar component of society. Among the various Arab populations, spirituality through Islam is fundamental. Thus, psychologists would be remiss to exclude a critical aspect of Arab American life from intervention when it is essential to well-being.
Kumar, Raj; Kumar, Vinay; Sharma, Vishal
2015-06-01
Diffuse reflectance ultraviolet-visible-near-infrared (UV-Vis-NIR) spectroscopy is applied as a means of differentiating various types of writing, office, and photocopy papers (collected from stationery shops in India) on the basis of reflectance and absorbance spectra that otherwise seem to be almost alike in different illumination conditions. In order to minimize bias, spectra from both sides of paper were obtained. In addition, three spectra from three different locations (from one side) were recorded covering the upper, middle, and bottom portions of the paper sample, and the mean average reflectivity of both the sides was calculated. A significant difference was observed in mean average reflectivity of Side A and Side B of the paper using Student's pair >t-test. Three different approaches were used for discrimination: (1) qualitative features of the whole set of samples, (2) principal component analysis, and (3) a combination of both approaches. On the basis of the first approach, i.e., qualitative features, 96.49% discriminating power (DP) was observed, which shows highly significant results with the UV-Vis-NIR technique. In the second approach the discriminating power is further enhanced by incorporating the principal component analysis (PCA) statistical method, where this method describes each UV-Vis spectrum in a group through numerical loading values connected to the first few principal components. All components described 100% variance of the samples, but only the first three PCs are good enough to explain the variance (PC1 = 51.64%, PC2 = 47.52%, and PC3 = 0.54%) of the samples; i.e., the first three PCs described 99.70% of the data, whereas in the third approach, the four samples, C, G, K, and N, out of a total 19 samples, which were not differentiated using qualitative features (approach no. 1), were therefore subjected to PCA. The first two PCs described 99.37% of the spectral features. The discrimination was achieved by using a loading plot between PC1 and PC2. It is therefore concluded that maximum discrimination of writing, office, and photocopy paper could be achieved on the basis of the second approach. Hence, the present inexpensive analytical method can be appropriate for application to routine questioned document examination work in forensic laboratories because it provides nondestructive, quantitative, reliable, and repeatable results.
Glenn, Edward P.; Huete, Alfredo R.; Nagler, Pamela L.; Nelson, Stephen G.
2008-01-01
Vegetation indices (VIs) are among the oldest tools in remote sensing studies. Although many variations exist, most of them ratio the reflection of light in the red and NIR sections of the spectrum to separate the landscape into water, soil, and vegetation. Theoretical analyses and field studies have shown that VIs are near-linearly related to photosynthetically active radiation absorbed by a plant canopy, and therefore to light-dependent physiological processes, such as photosynthesis, occurring in the upper canopy. Practical studies have used time-series VIs to measure primary production and evapotranspiration, but these are limited in accuracy to that of the data used in ground truthing or calibrating the models used. VIs are also used to estimate a wide variety of other canopy attributes that are used in Soil-Vegetation-Atmosphere Transfer (SVAT), Surface Energy Balance (SEB), and Global Climate Models (GCM). These attributes include fractional vegetation cover, leaf area index, roughness lengths for turbulent transfer, emissivity and albedo. However, VIs often exhibit only moderate, non-linear relationships to these canopy attributes, compromising the accuracy of the models. We use case studies to illustrate the use and misuse of VIs, and argue for using VIs most simply as a measurement of canopy light absorption rather than as a surrogate for detailed features of canopy architecture. Used this way, VIs are compatible with “Big Leaf” SVAT and GCMs that assume that canopy carbon and moisture fluxes have the same relative response to the environment as any single leaf, simplifying the task of modeling complex landscapes. PMID:27879814
Crystal Structure, Magnetic and Optical Properties of Mn-Doped BiFeO₃ by Hydrothermal Synthesis.
Zhang, Ning; Wei, Qinhua; Qin, Laishun; Chen, Da; Chen, Zhi; Niu, Feng; Wang, Jiangying; Huanag, Yuexiang
2017-01-01
In this paper, Mn doped BiFeO₃ were firstly synthesized by hydrothermal process. The influence of Mn doping on structural, optical and magnetic properties of BiFeO₃ was studied. The different amounts of Mn doping in BiFeO₃ were characterized by X-ray diffraction, Scanning Electron Microscope, Energy Dispersive X-ray Spectroscope, UV-Vis diffuse reflectance spectroscopy and magnetic measurements. The X-ray diffraction (XRD) patterns confirmed the formation of pure phase rhombohedral structure in BiFe(1−x) Mn (x) O₃ (x = 0.01, 0.03, 0.05, 0.07) samples. The morphologies and chemical compositions of as-prepared samples could be observed by Scanning Electron Microscope (SEM) and Energy Dispersive X-ray Spectroscope (EDS). A relative large saturated magnetization (Ms) of 0.53 emu/g for x = 0.07 sample was obtained at room temperature, which is considered to be Mn ions doping. UV-Vis diffuse reflectance spectroscopy showed strong absorption of light in the range of 200–1000 nm, indicating the optical band gap in the visible region for these samples. This implied that BiFe(1−x) Mn(x)O₃ may be a potential photocatalyst for utilizing solar energy.
Marković, Svetlana; Tošović, Jelena
2015-09-03
The UV-vis properties of 22 natural phenolic compounds, comprising anthraquinones, neoflavonoids, and flavonoids were systematically examined. The time-dependent density functional theory (TDDFT) approach in combination with the B3LYP, B3LYP-D2, B3P86, and M06-2X functionals was used to simulate the UV-vis spectra of the investigated compounds. It was shown that all methods exhibit very good (B3LYP slightly better) performance in reproducing the examined UV-vis spectra. However, the shapes of the Kohn-Sham molecular orbitals (MOs) involved in electronic transitions were misleading in constructing the MO correlation diagrams. To provide better understanding of redistribution of electron density upon excitation, the natural bond orbital (NBO) analysis was applied. Bearing in mind the spatial and energetic separations, as well as the character of the π bonding, lone pair, and π* antibonding natural localized molecular orbitals (NLMOs), the "NLMO clusters" were constructed. NLMO cluster should be understood as a part of a molecule characterized with distinguished electron density. It was shown that all absorption bands including all electronic transitions need to be inspected to fully understand the UV-vis spectrum of a certain compound, and, thus, to learn more about its UV-vis light absorption. Our investigation showed that the TDDFT and NBO theories are complementary, as the results from the two approaches can be combined to interpret the UV-vis spectra. Agreement between the predictions of the TDDFT approach and those based on the NLMO clusters is excellent in the case of major electronic transitions and long wavelengths. It should be emphasized that the approach for investigation of UV-vis light absorption based on the NLMO clusters is applied for the first time.
VIS: the visible imager for Euclid
NASA Astrophysics Data System (ADS)
Cropper, Mark; Pottinger, S.; Niemi, S.; Azzollini, R.; Denniston, J.; Szafraniec, M.; Awan, S.; Mellier, Y.; Berthe, M.; Martignac, J.; Cara, C.; Di Giorgio, A.-M.; Sciortino, A.; Bozzo, E.; Genolet, L.; Cole, R.; Philippon, A.; Hailey, M.; Hunt, T.; Swindells, I.; Holland, A.; Gow, J.; Murray, N.; Hall, D.; Skottfelt, J.; Amiaux, J.; Laureijs, R.; Racca, G.; Salvignol, J.-C.; Short, A.; Lorenzo Alvarez, J.; Kitching, T.; Hoekstra, H.; Massey, R.; Israel, H.
2016-07-01
Euclid-VIS is the large format visible imager for the ESA Euclid space mission in their Cosmic Vision program, scheduled for launch in 2020. Together with the near infrared imaging within the NISP instrument, it forms the basis of the weak lensing measurements of Euclid. VIS will image in a single r+i+z band from 550-900 nm over a field of view of ~0.5 deg2. By combining 4 exposures with a total of 2260 sec, VIS will reach to deeper than mAB=24.5 (10σ) for sources with extent ~0.3 arcsec. The image sampling is 0.1 arcsec. VIS will provide deep imaging with a tightly controlled and stable point spread function (PSF) over a wide survey area of 15000 deg2 to measure the cosmic shear from nearly 1.5 billion galaxies to high levels of accuracy, from which the cosmological parameters will be measured. In addition, VIS will also provide a legacy dataset with an unprecedented combination of spatial resolution, depth and area covering most of the extra-Galactic sky. Here we will present the results of the study carried out by the Euclid Consortium during the period up to the Critical Design Review.
Interactive access and management for four-dimensional environmental data sets using McIDAS
NASA Technical Reports Server (NTRS)
Hibbard, William L.; Tripoli, Gregory J.
1995-01-01
This grant has fundamentally changed the way that meteorologists look at the output of their atmospheric models, through the development and wide distribution of the Vis5D system. The Vis5D system is also gaining acceptance among oceanographers and atmospheric chemists. Vis5D gives these scientists an interactive three-dimensional movie of their very large data sets that they can use to understand physical mechanisms and to trace problems to their sources. This grant has also helped to define the future direction of scientific visualization through the development of the VisAD system and its lattice data model. The VisAD system can be used to interactively steer and visualize scientific computations. A key element of this capability is the flexibility of the system's data model to adapt to a wide variety of scientific data, including the integration of several forms of scientific metadata.
Design of a Braille Learning Application for Visually Impaired Students in Bangladesh.
Nahar, Lutfun; Jaafar, Azizah; Ahamed, Eistiak; Kaish, A B M A
2015-01-01
Visually impaired students (VIS) are unable to get visual information, which has made their learning process complicated. This paper discusses the overall situation of VIS in Bangladesh and identifies major challenges that they are facing in getting education. The Braille system is followed to educate blind students in Bangladesh. However, lack of Braille based educational resources and technological solutions have made the learning process lengthy and complicated for VIS. As a developing country, Bangladesh cannot afford for the costly Braille related technological tools for VIS. Therefore, a mobile phone based Braille application, "mBRAILLE", for Android platform is designed to provide an easy Braille learning technology for VIS in Bangladesh. The proposed design is evaluated by experts in assistive technology for students with disabilities, and advanced learners of Braille. The application aims to provide a Bangla and English Braille learning platform for VIS. In this paper, we depict iterative (participatory) design of the application along with a preliminary evaluation with 5 blind subjects, and 1 sighted and 2 blind experts. The results show that the design scored an overall satisfaction level of 4.53 out of 5 by all respondents, indicating that our design is ready for the next step of development.
Visualization of Metabolic Interaction Networks in Microbial Communities Using VisANT 5.0
Wang, Yan; DeLisi, Charles; Segrè, Daniel; Hu, Zhenjun
2016-01-01
The complexity of metabolic networks in microbial communities poses an unresolved visualization and interpretation challenge. We address this challenge in the newly expanded version of a software tool for the analysis of biological networks, VisANT 5.0. We focus in particular on facilitating the visual exploration of metabolic interaction between microbes in a community, e.g. as predicted by COMETS (Computation of Microbial Ecosystems in Time and Space), a dynamic stoichiometric modeling framework. Using VisANT’s unique metagraph implementation, we show how one can use VisANT 5.0 to explore different time-dependent ecosystem-level metabolic networks. In particular, we analyze the metabolic interaction network between two bacteria previously shown to display an obligate cross-feeding interdependency. In addition, we illustrate how a putative minimal gut microbiome community could be represented in our framework, making it possible to highlight interactions across multiple coexisting species. We envisage that the “symbiotic layout” of VisANT can be employed as a general tool for the analysis of metabolism in complex microbial communities as well as heterogeneous human tissues. VisANT is freely available at: http://visant.bu.edu and COMETS at http://comets.bu.edu. PMID:27081850
Visualization of Metabolic Interaction Networks in Microbial Communities Using VisANT 5.0.
Granger, Brian R; Chang, Yi-Chien; Wang, Yan; DeLisi, Charles; Segrè, Daniel; Hu, Zhenjun
2016-04-01
The complexity of metabolic networks in microbial communities poses an unresolved visualization and interpretation challenge. We address this challenge in the newly expanded version of a software tool for the analysis of biological networks, VisANT 5.0. We focus in particular on facilitating the visual exploration of metabolic interaction between microbes in a community, e.g. as predicted by COMETS (Computation of Microbial Ecosystems in Time and Space), a dynamic stoichiometric modeling framework. Using VisANT's unique metagraph implementation, we show how one can use VisANT 5.0 to explore different time-dependent ecosystem-level metabolic networks. In particular, we analyze the metabolic interaction network between two bacteria previously shown to display an obligate cross-feeding interdependency. In addition, we illustrate how a putative minimal gut microbiome community could be represented in our framework, making it possible to highlight interactions across multiple coexisting species. We envisage that the "symbiotic layout" of VisANT can be employed as a general tool for the analysis of metabolism in complex microbial communities as well as heterogeneous human tissues. VisANT is freely available at: http://visant.bu.edu and COMETS at http://comets.bu.edu.
[The UV-Vis spectra and substituent effect of organoimido derivatives of polyoxometalates].
Li, Qiang; Wei, Yong-ge; Wang, Yuan; Guo, Hong-you
2005-06-01
In the presence of a carbodiimine, i.e. DCC, a series of organoimido derivatives of polyoxometalates have been synthesized via the reaction of [alpha-Mo8O26]4- with aromatic amines and its hydrochloride salt. Elemental analysis, IR, 1H-NMR and UV-Vis spectra were used to characterize those hybrids, in particular their UV-Vis spectra have been studied. The results show that typical metal-ligand charge transfer (MLCT) transitions occur in the organic-inorganic hybrid molecules. There is a good linear relationship between the shift of UV-Vis absorptions (delta lamda max) and conjugation effect of the p-substituted group (sigmaR).
`VIS/NIR mapping of TOC and extent of organic soils in the Nørre Å valley
NASA Astrophysics Data System (ADS)
Knadel, M.; Greve, M. H.; Thomsen, A.
2009-04-01
Organic soils represent a substantial pool of carbon in Denmark. The need for carbon stock assessment calls for more rapid and effective mapping methods to be developed. The aim of this study was to compare traditional soil mapping with maps produced from the results of a mobile VIS/NIR system and to evaluate the ability to estimate TOC and map the area of organic soils. The Veris mobile VIS/NIR spectroscopy system was compared to traditional manual sampling. The system is developed for in-situ near surface measurements of soil carbon content. It measures diffuse reflectance in the 350 nm-2200 nm region. The system consists of two spectrophotometers mounted on a toolbar and pulled by a tractor. Optical measurements are made through a sapphire window at the bottom of the shank. The shank was pulled at a depth of 5-7 cm at a speed of 4-5 km/hr. 20-25 spectra per second with 8 nm resolution were acquired by the spectrometers. Measurements were made on 10-12 m spaced transects. The system also acquired soil electrical conductivity (EC) for two soil depths: shallow EC-SH (0- 31 cm) and deep conductivity EC-DP (0- 91 cm). The conductivity was recorded together with GPS coordinates and spectral data for further construction of the calibration models. Two maps of organic soils in the Nørre Å valley (Central Jutland) were generated: (i) based on a conventional 25 m grid with 162 sampling points and laboratory analysis of TOC, (ii) based on in-situ VIS/NIR measurements supported by chemometrics. Before regression analysis, spectral information was compressed by calculating principal components. The outliers were determined by a mahalanobis distance equation and removed. Clustering using a fuzzy c- means algorithm was conducted. Within each cluster a location with the minimal spatial variability was selected. A map of 15 representative sample locations was proposed. The interpolation of the spectra into a single spectrum was performed using a Gaussian kernel weighting function. Spectra obtained near a sampled location were averaged. The collected spectra were correlated to TOC of the 15 representative samples using multivariate regression techniques (Unscrambler 9.7; Camo ASA, Oslo, Norway). Two types of calibrations were performed: using only spectra and using spectra together with the auxiliary data (EC-SH and EC-DP). These calibration equations were computed using PLS regression, segmented cross-validation method on centred data (using the raw spectral data, log 1/R). Six different spectra pre-treatments were conducted: (1) only spectra, (2) Savitsky-Golay smoothing over 11 wavelength points and transformation to a (3) 1'st and (4) 2'nd Savitzky and Golay derivative algorithm with a derivative interval of 21 wavelength points, (5) with or (6) without smoothing. The best treatment was considered to be the one with the lowest Root Mean Square Error of Prediction (RMSEP), the highest r2 between the VIS/NIR-predicted and measured values in the calibration model and the lowest mean deviation of predicted TOC values. The best calibration model was obtained with the mathematical pre-treatment's including smoothing, calculating the 2'nd derivative and outlier removal. The two TOC maps were compared after interpolation using kriging. They showed a similar pattern in the TOC distribution. Despite the unfavourable field conditions the VIS/NIR system performed well in both low and high TOC areas. Water content in places exceeding field capacity in the lower parts of the investigated field did not seriously degrade measurements. The present study represents the first attempt to apply the mobile Veris VIS/NIR system to the mapping of TOC of peat soils in Denmark. The result from this study show that a mobile VIS/NIR system can be applied to cost effective TOC mapping of mineral and organic soils with highly varying water content. Key words: VIS/NIR spectroscopy, organic soils, TOC
Spectroscopic characterization of the quantum wires in titanosilicates ETS-4 and ETS-10
NASA Astrophysics Data System (ADS)
Yilmaz, Bilge; Warzywoda, Juliusz; Sacco, Albert, Jr.
2006-08-01
Titanosilicates ETS-4 and ETS-10 contain octahedrally coordinated monatomic semiconductor \\cdots \\mathrm {Ti} -O-Ti-O-\\mathrm {Ti}\\cdots (titania) chains in their frameworks. Titania chains are isolated from one another by a siliceous matrix. Thus, these chains can be regarded as one-dimensional nanostructures, i.e., 'quantum wires'. Diffuse reflectance UV-vis (DR-UV-vis) spectroscopy analysis demonstrated a significant blue-shift of the optical absorption edge (>60 nm) for both ETS-4 and ETS-10 compared to bulk titania. This blue-shift is consistent with the hypothesis that the titania chains in ETS-4 and ETS-10 are acting as quantum wires. A broad range of ETS-4 and ETS-10 samples with diverse crystallo-chemical characteristics was prepared. The DR-UV-vis and Raman spectra of various ETS-4 and ETS-10 samples exhibited different characteristics, which were hypothesized to be related to the titania chain 'quality'. Detailed investigation of the spectroscopic bands associated with the titania chains in ETS-4 was performed for the first time. The 'quality' of these titania chains/quantum wires in ETS-4 and ETS-10 was correlated with the crystal growth mechanisms of these materials. Comparison of the growth mechanisms and the spectroscopic behaviour for ETS-4 and ETS-10 suggests that the control of 'quantum wire quality' via hydrothermal synthesis is possible in ETS-4 but would be difficult in ETS-10.
Study on fast measurement of sugar content of yogurt using Vis/NIR spectroscopy techniques
NASA Astrophysics Data System (ADS)
He, Yong; Feng, Shuijuan; Wu, Di; Li, Xiaoli
2006-09-01
In order to measuring the sugar content of yogurt rapidly, a fast measurement of sugar content of yogurt using Vis/NIR-spectroscopy techniques was established. 25 samples selected separately from five different brands of yogurt were measured by Vis/NIR-spectroscopy. The sugar content of yogurt on positions scanned by spectrum were measured by a sugar content meter. The mathematical model between sugar content and Vis/NIR spectral measurements was established and developed based on partial least squares (PLS). The correlation coefficient of sugar content based on PLS model is more than 0.894, and standard error of calibration (SEC) is 0.356, standard error of prediction (SEP) is 0.389. Through predicting the sugar content quantitatively of 35 samples of yogurt from 5 different brands, the correlation coefficient between predictive value and measured value of those samples is more than 0.934. The results show the good to excellent prediction performance. The Vis/NIR spectroscopy technique had significantly greater accuracy for determining the sugar content. It was concluded that the Vis/NIRS measurement technique seems reliable to assess the fast measurement of sugar content of yogurt, and a new method for the measurement of sugar content of yogurt was established.
UV-Vis reflection spectroscopy under variable angle incidence at the air-liquid interface.
Roldán-Carmona, Cristina; Rubia-Payá, Carlos; Pérez-Morales, Marta; Martín-Romero, María T; Giner-Casares, Juan J; Camacho, Luis
2014-03-07
The UV-Vis reflection spectroscopy (UV-Vis-RS) in situ at the air-liquid interface provides information about tilt and aggregation of chromophores in Langmuir monolayers. This information is particularly important given in most cases the chromophore is located at the polar region of the Langmuir monolayer. This region of the Langmuir monolayers has been hardly accessible by other experimental techniques. In spite of its enormous potential, the application of UV-Vis-RS has been limited mainly to reflection measurements under light normal incidence or at lower incidence angles than the Brewster angle. Remarkably, this technique is quite sensitive to the tilt of the chromophores at values of incidence angles close to or larger than the Brewster angle. Therefore, a novel method to obtain the order parameter of the chromophores at the air-liquid interface by using s- and p-polarized radiation at different incidence angles is proposed. This method allowed for the first time the experimental observation of the two components with different polarization properties of a single UV-Vis band at the air-liquid interface. The method of UV-Vis spectroscopy under variable angle incidence is presented as a new tool for obtaining rich detailed information on Langmuir monolayers.
Synthesis and photocatalytic activity of ytterbium-doped titania/diatomite composite photocatalysts
NASA Astrophysics Data System (ADS)
Tang, Wenjian; Qiu, Kehui; Zhang, Peicong; Yuan, Xiqiang
2016-01-01
Ytterbium-doped titanium dioxide (Yb-TiO2)/diatomite composite materials with different Yb concentrations were prepared by sol-gel method. The phase structure, morphology, and chemical composition of the as-prepared composites were well characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy, Raman spectroscopy, scanning electron microscopy (SEM), and ultraviolet-visible (UV-vis) diffuse reflection spectroscopy. The XRD and Raman spectroscopy analysis indicated that the TiO2 existed in the form of pure anatase in the composites. The SEM images exhibited the well deposition and dispersion of TiO2 nanoparticles with little agglomeration on the surfaces of diatoms. The UV-vis diffuse reflection spectra showed that the band gap of TiO2 could be narrowed by the introduction of Yb species, which was further affected by doping concentration of Yb. The photocatalytic activity of synthesized samples was investigated by the degradation of methylene blue (MB) under UV light irradiation. It was observed that the photocatalytic degradation followed a pseudo-first-order kinetics according to the Langmuir-Hinshelwood model. Compared to TiO2 and TiO2/diatomite, the Yb-TiO2/diatomite composites exhibited higher photocatalytic activity toward degradation of MB using UV light irradiation.
Performance of vegetation indices from Landsat time series in deforestation monitoring
NASA Astrophysics Data System (ADS)
Schultz, Michael; Clevers, Jan G. P. W.; Carter, Sarah; Verbesselt, Jan; Avitabile, Valerio; Quang, Hien Vu; Herold, Martin
2016-10-01
The performance of Landsat time series (LTS) of eight vegetation indices (VIs) was assessed for monitoring deforestation across the tropics. Three sites were selected based on differing remote sensing observation frequencies, deforestation drivers and environmental factors. The LTS of each VI was analysed using the Breaks For Additive Season and Trend (BFAST) Monitor method to identify deforestation. A robust reference database was used to evaluate the performance regarding spatial accuracy, sensitivity to observation frequency and combined use of multiple VIs. The canopy cover sensitive Normalized Difference Fraction Index (NDFI) was the most accurate. Among those tested, wetness related VIs (Normalized Difference Moisture Index (NDMI) and the Tasselled Cap wetness (TCw)) were spatially more accurate than greenness related VIs (Normalized Difference Vegetation Index (NDVI) and Tasselled Cap greenness (TCg)). When VIs were fused on feature level, spatial accuracy was improved and overestimation of change reduced. NDVI and NDFI produced the most robust results when observation frequency varies.
Han, Chuang; Quan, Quan; Chen, Hao Ming; Sun, Yugang; Xu, Yi-Jun
2017-04-01
Surface plasmon resonance (SPR)-mediated photocatalysis without the bandgap limitations of traditional semiconductor has aroused significant attention in solar-to-chemical energy conversion. However, the photocatalytic efficiency barely initiated by the SPR effects is still challenged by the low concentration and ineffective extraction of energetic hot electrons, slow charge migration rates, random charge diffusion directions, and the lack of highly active sites for redox reactions. Here, the tunable, progressive harvesting of visible-to-near infrared light (vis-NIR, λ > 570 nm) by designing plasmonic Au nanorods and metal (Au, Ag, or Pt) nanoparticle codecorated 1D CdS nanowire (1D CdS NW) ensemble is reported. The intimate integration of these metal nanostructures with 1D CdS NWs promotes the extraction and manipulated directional separation and migration of hot charge carriers in a more effective manner. Such cooperative synergy with tunable control of interfacial interaction, morphology optimization, and cocatalyst strategy results in the distinctly boosted performance for vis-NIR-driven plasmonic photocatalysis. This work highlights the significance of rationally progressive design of plasmonic metal-semiconductor-based composite system for boosting the regulated directional flow of hot charge carrier and thus the more efficient use of broad-spectrum solar energy conversion. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
NASA Astrophysics Data System (ADS)
Valizadeh, S.; Rasoulifard, M. H.; Dorraji, M. S. Seyed
2014-11-01
The magnetite-hydroxyapatite (M-HAP) nanocomposites were prepared by a chemical co- precipitation procedure and characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and diffuse reflectance spectra (DRS). The ability of the synthesized catalyst for photocatalytic degradation of Acid Blue 25 (AB25), as an organic dye, under UV irradiation was studied. The catalyst was modified employing transition metals (Mn, Fe, Co, Ni, Cu and Zn) trying to improve the catalytic performance of HAP in absence of UV irradiation and in the presence of hydrogen peroxide i.e. a Fenton like reaction. The best results obtained for Cu and Co modified M-HAPs and the effect of operational parameters such pH, amount of catalyst and hydrogen peroxide concentration was studied. In order to investigate the performance of HAP based photocatalyst in visible light region, M-HAP was modified with silver ions. At the end, Langmuir-Hinshelwood kinetic expression used to evaluate and compare the catalytic systems. The strongest degradation activity was observed for Ag-M-HAP/Vis system because of Ag3PO4 formation. Apparent reaction rate constant (Kapp) by Ag-M-HAP/Vis was 63, 36 and 19 times faster than Cu-M-HAP(II)/H2O2, Co-M-HAP(II)/H2O2 and M-HAP (I)/UV systems, respectively.
Begum, Robina; Farooqi, Zahoor H; Naseem, Khalida; Ali, Faisal; Batool, Madeeha; Xiao, Jianliang; Irfan, Ahmad
2018-11-02
Noble metal nanoparticles loaded smart polymer microgels have gained much attention due to fascinating combination of their properties in a single system. These hybrid systems have been extensively used in biomedicines, photonics, and catalysis. Hybrid microgels are characterized by using various techniques but UV/Vis spectroscopy is an easily available technique for characterization of noble metal nanoparticles loaded microgels. This technique is widely used for determination of size and shape of metal nanoparticles. The tuning of optical properties of noble metal nanoparticles under various stimuli can be studied using UV/Vis spectroscopic method. Time course UV/Vis spectroscopy can also be used to monitor the kinetics of swelling and deswelling of microgels and hybrid microgels. Growth of metal nanoparticles in polymeric network or growth of polymeric network around metal nanoparticle core can be studied by using UV/Vis spectroscopy. This technique can also be used for investigation of various applications of hybrid materials in catalysis, photonics, and sensing. This tutorial review describes the uses of UV/Vis spectroscopy in characterization and catalytic applications of responsive hybrid microgels with respect to recent research progress in this area.
VisANT 3.0: new modules for pathway visualization, editing, prediction and construction.
Hu, Zhenjun; Ng, David M; Yamada, Takuji; Chen, Chunnuan; Kawashima, Shuichi; Mellor, Joe; Linghu, Bolan; Kanehisa, Minoru; Stuart, Joshua M; DeLisi, Charles
2007-07-01
With the integration of the KEGG and Predictome databases as well as two search engines for coexpressed genes/proteins using data sets obtained from the Stanford Microarray Database (SMD) and Gene Expression Omnibus (GEO) database, VisANT 3.0 supports exploratory pathway analysis, which includes multi-scale visualization of multiple pathways, editing and annotating pathways using a KEGG compatible visual notation and visualization of expression data in the context of pathways. Expression levels are represented either by color intensity or by nodes with an embedded expression profile. Multiple experiments can be navigated or animated. Known KEGG pathways can be enriched by querying either coexpressed components of known pathway members or proteins with known physical interactions. Predicted pathways for genes/proteins with unknown functions can be inferred from coexpression or physical interaction data. Pathways produced in VisANT can be saved as computer-readable XML format (VisML), graphic images or high-resolution Scalable Vector Graphics (SVG). Pathways in the format of VisML can be securely shared within an interested group or published online using a simple Web link. VisANT is freely available at http://visant.bu.edu.
Community knowledge, attitudes, and beliefs towards depression in the state of Penang, Malaysia.
Khan, Tahir M; Sulaiman, Syed A Syed; Hassali, Mohamed A; Anwar, Mudassir; Wasif, G; Khan, Amer H
2010-02-01
This study was intended to evaluate the mental health literacy vis-à-vis depression among inhabitants of Penang state in North Malaysia. Using a clustered random sampling method, 1,855 respondents were approached to participate in the survey. A total of 1,149 respondents actually participated, for a 61.9% response rate. Face to face interviews were then conducted using a pre-validated 21-item questionnaire. The mean age of the respondents was 30 years (SD +/-11.5). The majority (n = 884; 76.9%) could recognize three or more symptoms of depression. Chinese and/or female respondents performed the best in this domain. Respondents with a personal experience of depression displayed a significantly better knowledge of symptoms of and therapies for depression than those who did not (t = -35.745, P = <0.001). Overall, a moderate knowledge level of the symptoms of depression and a cursory knowledge towards therapy were observed among the general population in Penang. Notably, respondents were generally inclined towards the use of alternative medicine. The study suggests that strong beliefs in alternative and traditional medicines could undermine the respondents' willingness and ability to seek evidence-based mental health care.
MODIS Solar Diffuser: Modelled and Actual Performance
NASA Technical Reports Server (NTRS)
Waluschka, Eugene; Xiong, Xiao-Xiong; Esposito, Joe; Wang, Xin-Dong; Krebs, Carolyn (Technical Monitor)
2001-01-01
The Moderate Resolution Imaging Spectroradiometer (MODIS) instrument's solar diffuser is used in its radiometric calibration for the reflective solar bands (VIS, NTR, and SWIR) ranging from 0.41 to 2.1 micron. The sun illuminates the solar diffuser either directly or through a attenuation screen. The attenuation screen consists of a regular array of pin holes. The attenuated illumination pattern on the solar diffuser is not uniform, but consists of a multitude of pin-hole images of the sun. This non-uniform illumination produces small, but noticeable radiometric effects. A description of the computer model used to simulate the effects of the attenuation screen is given and the predictions of the model are compared with actual, on-orbit, calibration measurements.
NASA Technical Reports Server (NTRS)
Maney, Tucker; Hamburger, Henry
1993-01-01
VIS/ACT is a multi-media educational system for aircrew coordination training (ACT). Students view video segments, answer questions that are adjusted to individual performance, and engage in related activities. Although the system puts the student in a reactive critiquing role, it has proved effective in improving performance on active targeted ACT skills, in group simulation tasks. VIS/ACT itself is the product of coordination among three Navy agencies.
NASA Astrophysics Data System (ADS)
Fatimah, I.
2017-02-01
TiO2-SiO2have been synthesized by the sol-gel method from titanium isopropoxide and varied silica precursors: tetraethyl orthosilicate and tetra methyl ortho silicate. To study the effect of the precursor, prepared materials were characterized by X-ray diffraction, scanning electron microscopy, Diffuse Reflectance UV-vis optical absorption, and also gas sorption analysis. XRD patterns showed the formation of TiO2 anatase in the TiO2-SiO2 composite with different crystallite size from different silica precursor as well as the different surface morphology. The DRUV-vis absorption spectra exhibit similar band gap energy correspond to 3.21eV value while the surface area, pore volume and pore radius of the materials seems to be affected by the precursor. The higher specific surface area contributes to give the enhanced activity in phenol hydroxylation and methylene blue photodegradation.
Improvements of VIIRS and MODIS Solar Diffuser and Lunar Calibration
NASA Technical Reports Server (NTRS)
Xiong, Xiaoxiong; Butler, James J.; Lei, Ning; Sun, Junqiang; Fulbright, Jon; Wang, Zhipeng; McIntire, Jeff; Angal, Amit Avinash
2013-01-01
Both VIIRS and MODIS instruments use solar diffuser (SD) and lunar observations to calibrate their reflective solar bands (RSB). A solar diffuser stability monitor (SDSM) is used to track the SD on-orbit degradation. On-orbit observations have shown similar wavelength-dependent SD degradation (larger at shorter VIS wavelengths) and SDSM detector response degradation (larger at longer NIR wavelengths) for both VIIRS and MODIS instruments. In general, the MODIS scan mirror has experienced more degradation in the VIS spectral region whereas the VIIRS rotating telescope assembly (RTA) mirrors have seen more degradation in the NIR and SWIR spectral region. Because of this wavelength dependent mirror degradation, the sensor's relative spectral response (RSR) needs to be modulated. Due to differences between the solar and lunar spectral irradiance, the modulated RSR could have different effects on the SD and lunar calibration. In this paper, we identify various factors that should be considered for the improvements of VIIRS and MODIS solar and lunar calibration and examine their potential impact. Specifically, we will characterize and assess the calibration impact due to SD and SDSM attenuation screen transmission (uncertainty), SD BRF uncertainty and onorbit degradation, SDSM detector response degradation, and modulated RSR resulting from the sensor's optics degradation. Also illustrated and discussed in this paper are the calibration strategies implemented in the VIIRS and MODIS SD and lunar calibrations and efforts that could be made for future improvements.
Tracing the trilobite tree from the root to the tips: a model marriage of fossils and phylogeny.
Lieberman, Bruce S; Karim, Talia S
2010-01-01
Trilobites are a highly diverse group of extinct arthropods that persisted for nearly 300 million years. During that time, there was a profusion of morphological form, and they occupied a plethora of marine habitats. Their diversity, relative abundance, and complex morphology make them excellent candidates for phylogenetic analysis, and partly as a consequence they have been the subject of many cladistic studies. Although phylogenetic knowledge is certainly incomplete, our understanding of evolutionary patterns within the group has dramatically increased over the last 30 years. Moreover, trilobites have formed an important component of various studies of macroevolutionary processes. Here, we summarize the phylogenetic breadth of knowledge on the Trilobita, and present various hypotheses about phylogenetic patterns within the group, from the highest to the lowest taxonomic levels. Key topics we consider include the question of trilobite monophyly, the phylogenetic position of trilobites vis à vis extant arthropod groups, and inter- and intra-ordinal relationships. Copyright (c) 2009 Elsevier Ltd. All rights reserved.
Musil, Karel; Florianova, Veronika; Bucek, Pavel; Dohnal, Vlastimil; Kuca, Kamil; Musilek, Kamil
2016-01-05
Acetylcholinesterase reactivators (oximes) are compounds used for antidotal treatment in case of organophosphorus poisoning. The dissociation constants (pK(a1)) of ten standard or promising acetylcholinesterase reactivators were determined by ultraviolet absorption spectrometry. Two methods of spectra measurement (UV-vis spectrometry, FIA/UV-vis) were applied and compared. The soft and hard models for calculation of pK(a1) values were performed. The pK(a1) values were recommended in the range 7.00-8.35, where at least 10% of oximate anion is available for organophosphate reactivation. All tested oximes were found to have pK(a1) in this range. The FIA/UV-vis method provided rapid sample throughput, low sample consumption, high sensitivity and precision compared to standard UV-vis method. The hard calculation model was proposed as more accurate for pK(a1) calculation. Copyright © 2015 Elsevier B.V. All rights reserved.
Moreno-Indias, Isabel; Coín-Aragüez, Leticia; Lhamyani, Said; Alcaide Torres, Juan; Fernández-Veledo, Sonia; Vendrell, Joan; Camargo, Antonio; El Bekay, Rajaa; Tinahones, Francisco José
2017-01-01
Background/Objectives Multiple studies suggest that hypoxia, together with inflammation, could be one of the phenomena involved in the onset and progression of obesity-related insulin resistance. In addition, dysfunction of adipose tissue in obese subjects with metabolic syndrome is associated with decreased angiogenesis. However, some subjects with a high body mass index do not develop metabolic abnormalities associated with obesity. The aim of the current study was to examine the neovascular properties of visceral adipose tissue-derived multipotent mesenchymal cells subjected to hypoxia (hypox-visASCs) from normal-weight subjects (Nw) and obese patients with metabolic syndrome (MS) and without metabolic syndrome (NonMS). Methods This was a 2-year study to enroll subjects who underwent bariatric surgery or cholecystectomy. Eight patients who underwent either bariatric surgery or cholecystectomy (27 patients) participated in the study. Visceral adipose tissue samples from Nw, MS and NonMS subjects were processed by enzymatic digestion. VisASCs cultured under hypoxic conditions were characterized by tubule formation assay, ELISA, flow cytometry, migration rate, and qRT-PCR, and the effects of visASCs-conditioned medium on survival and endothelial cell tubule formation were evaluated. Results Hypox-visASCs from NonMS subjects showed a greater capacity for tubule formation than hypox-visASCs from Nw and MS subjects. The lower percentage of CD140b+/CD44+ and CD140b+/CD184+ cells observed in hypox-visASCs from NonMS subjects compared to MS subjects was accompanied not only by a lower migration rate from the chemotactic effects of stromal cell derived factor 1α, but also by lower levels of NOX5 mRNA expression. While the levels of monocyte chemoattractant protein 1 mRNA expressed by hypox-visASCs correlated positively with the body mass index and waist circumference of the subjects, the concentration of vascular endothelial growth factor present in hypox-visASC-conditioned culture medium decreased significantly with increasing plasma glucose. The survival rate and tubules formed by endothelial cells cultured in hypox-visASC-conditioned medium decreased significantly with increasing homeostasis model assessment to quantify insulin resistance. Conclusions Our results suggest that hypox-visASCs from NonMS subjects could promote healthy adipose tissue expansion, while hypox-visASCs from MS subjects appear to contribute to the decreased angiogenic potential and increased inflammation underlying adipose tissue dysfunction in obesity. Our results emphasize the importance of taking into account not only the BMI but also the metabolic profile of the subjects during the implementation of ASCs-based therapy to promote neovascularization. PMID:29166648
Application of in operando UV/Vis spectroscopy in lithium-sulfur batteries.
Patel, Manu U M; Dominko, Robert
2014-08-01
Application of UV/Vis spectroscopy for the qualitative and quantitative determination of differences in the mechanism of lithium-sulfur battery behavior is presented. With the help of catholytes prepared from chemically synthesized stoichiometric mixtures of lithium and sulfur, calibration curves for two different types of electrolyte can be constructed. First-order derivatives of UV/Vis spectra show five typical derivative peak positions in both electrolytes. In operando measurements show a smooth change in the UV/Vis spectra in the wavelength region between λ=650 and 400 nm. Derivatives are in agreement with derivative peak positions observed with catholytes. Recalculation of normalized reflections of UV/Vis spectra obtained in operando mode enable the formation of polysulfides and their concentrations to be followed. In such a way, it is possible to distinguish differences in the mechanism of polysulfide shuttling between two electrolytes and to correlate differences in capacity fading. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Using DNA to Design Plasmonic Metamaterials with Tunable Optical Properties
2014-01-01
using both UV –vis spectroscopy for ensemble measurements and optical micro- spectrophotometry for individual superlattice electric fi elds at...lated data). The red-shift seen between the micro-spectropho- tometer measurements (Figure 3 b) and the UV –vis ensemble measurements (Figure 3 a...the measurements. Using UV –vis spectroscopy ( Figure 3 a), red- shifting of the superlattices’ bulk LSPR with decreased nano- particle spacing is
Integration of the HTC Vive into the medical platform MeVisLab
NASA Astrophysics Data System (ADS)
Egger, Jan; Gall, Markus; Wallner, Jürgen; de Almeida Germano Boechat, Pedro; Hann, Alexander; Li, Xing; Chen, Xiaojun; Schmalstieg, Dieter
2017-03-01
Virtual Reality (VR) is an immersive technology that replicates an environment via computer-simulated reality. VR gets a lot of attention in computer games but has also great potential in other areas, like the medical domain. Examples are planning, simulations and training of medical interventions, like for facial surgeries where an aesthetic outcome is important. However, importing medical data into VR devices is not trivial, especially when a direct connection and visualization from your own application is needed. Furthermore, most researcher don't build their medical applications from scratch, rather they use platforms, like MeVisLab, Slicer or MITK. The platforms have in common that they integrate and build upon on libraries like ITK and VTK, further providing a more convenient graphical interface to them for the user. In this contribution, we demonstrate the usage of a VR device for medical data under MeVisLab. Therefore, we integrated the OpenVR library into MeVisLab as an own module. This enables the direct and uncomplicated usage of head mounted displays, like the HTC Vive under MeVisLab. Summarized, medical data from other MeVisLab modules can directly be connected per drag-and-drop to our VR module and will be rendered inside the HTC Vive for an immersive inspection.
McIntyre, J Oliver; Fingleton, Barbara; Wells, K Sam; Piston, David W; Lynch, Conor C; Gautam, Shiva; Matrisian, Lynn M
2004-01-01
The present study describes the in vivo detection and imaging of tumour-associated MMP-7 (matrix metalloproteinase-7 or matrilysin) activity using a novel polymer-based fluorogenic substrate PB-M7VIS, which serves as a selective 'proteolytic beacon' (PB) for this metalloproteinase. PB-M7VIS is built on a PAMAM (polyamido amino) dendrimer core of 14.2 kDa, covalently coupled with an Fl (fluorescein)-labelled peptide Fl(AHX)RPLALWRS(AHX)C (where AHX stands for aminohexanoic acid) and with TMR (tetramethylrhodamine). PB-M7VIS is efficiently and selectively cleaved by MMP-7 with a k (cat)/ K (m) value of 1.9x10(5) M(-1).s(-1) as measured by the rate of increase in Fl fluorescence (up to 17-fold for the cleavage of an optimized PB-M7VIS) with minimal change in the TMR fluorescence. The K (m) value for PB-M7VIS is approx. 0.5 microM, which is approx. two orders of magnitude lower when compared with that for an analogous soluble peptide, indicating efficient interaction of MMP-7 with the synthetic polymeric substrate. With MMP-2 or -3, the k (cat)/ K (m) value for PB-M7VIS is approx. 56- or 13-fold lower respectively, when compared with MMP-7. In PB-M7VIS, Fl(AHX)RPLALWRS(AHX)C is a selective optical sensor of MMP-7 activity and TMR serves to detect both the uncleaved and cleaved reagents. Each of these can be visualized as subcutaneous fluorescent phantoms in a mouse and optically discriminated based on the ratio of green/red (Fl/TMR) fluorescence. The in vivo specificity of PB-M7VIS was tested in a mouse xenograft model. Intravenous administration of PB-M7VIS gave significantly enhanced Fl fluorescence from MMP-7-positive tumours, but not from control tumours ( P <0.0001), both originally derived from SW480 human colon cancer cells. Prior systemic treatment of the tumour-bearing mice with an MMP inhibitor BB-94 ([4-( N -hydroxyamino)-2 R -isobutyl-3 S -(thienylthiomethyl)-succinyl]-L-phenylalanine- N -methylamide), markedly decreased the Fl fluorescence over the MMP-7-positive tumour by approx. 60%. Thus PB-M7VIS functions as a PB for in vivo detection of MMP-7 activity that serves to light this optical beacon and is, therefore, a selective in vivo optical molecular imaging contrast reagent. PMID:14556651
Methods of editing cloud and atmospheric layer affected pixels from satellite data
NASA Technical Reports Server (NTRS)
Nixon, P. R. (Principal Investigator); Wiegand, C. L.; Richardson, A. J.; Johnson, M. P.
1981-01-01
Plotted transects made from south Texas daytime HCMM data show the effect of subvisible cirrus (SCI) clouds in the emissive (IR) band but the effect is unnoticable in the reflective (VIS) band. The depression of satellite indicated temperatures ws greatest in the center of SCi streamers and tapered off at the edges. Pixels of uncontaminated land and water features in the HCMM test area shared identical VIS and IR digital count combinations with other pixels representing similar features. A minimum of 0.015 percent repeats of identical VIS-IR combinations are characteristic of land and water features in a scene of 30 percent cloud cover. This increases to 0.021 percent of more when the scene is clear. Pixels having shared VIS-IR combinations less than these amounts are considered to be cloud contaminated in the cluster screening method. About twenty percent of SCi was machine indistinguishable from land features in two dimensional spectral space (VIS vs IR).
Visual identification system for homeland security and law enforcement support
NASA Astrophysics Data System (ADS)
Samuel, Todd J.; Edwards, Don; Knopf, Michael
2005-05-01
This paper describes the basic configuration for a visual identification system (VIS) for Homeland Security and law enforcement support. Security and law enforcement systems with an integrated VIS will accurately and rapidly provide identification of vehicles or containers that have entered, exited or passed through a specific monitoring location. The VIS system stores all images and makes them available for recall for approximately one week. Images of alarming vehicles will be archived indefinitely as part of the alarming vehicle"s or cargo container"s record. Depending on user needs, the digital imaging information will be provided electronically to the individual inspectors, supervisors, and/or control center at the customer"s office. The key components of the VIS are the high-resolution cameras that capture images of vehicles, lights, presence sensors, image cataloging software, and image recognition software. In addition to the cameras, the physical integration and network communications of the VIS components with the balance of the security system and client must be ensured.
Methodology and software to detect viral integration site hot-spots
2011-01-01
Background Modern gene therapy methods have limited control over where a therapeutic viral vector inserts into the host genome. Vector integration can activate local gene expression, which can cause cancer if the vector inserts near an oncogene. Viral integration hot-spots or 'common insertion sites' (CIS) are scrutinized to evaluate and predict patient safety. CIS are typically defined by a minimum density of insertions (such as 2-4 within a 30-100 kb region), which unfortunately depends on the total number of observed VIS. This is problematic for comparing hot-spot distributions across data sets and patients, where the VIS numbers may vary. Results We develop two new methods for defining hot-spots that are relatively independent of data set size. Both methods operate on distributions of VIS across consecutive 1 Mb 'bins' of the genome. The first method 'z-threshold' tallies the number of VIS per bin, converts these counts to z-scores, and applies a threshold to define high density bins. The second method 'BCP' applies a Bayesian change-point model to the z-scores to define hot-spots. The novel hot-spot methods are compared with a conventional CIS method using simulated data sets and data sets from five published human studies, including the X-linked ALD (adrenoleukodystrophy), CGD (chronic granulomatous disease) and SCID-X1 (X-linked severe combined immunodeficiency) trials. The BCP analysis of the human X-linked ALD data for two patients separately (774 and 1627 VIS) and combined (2401 VIS) resulted in 5-6 hot-spots covering 0.17-0.251% of the genome and containing 5.56-7.74% of the total VIS. In comparison, the CIS analysis resulted in 12-110 hot-spots covering 0.018-0.246% of the genome and containing 5.81-22.7% of the VIS, corresponding to a greater number of hot-spots as the data set size increased. Our hot-spot methods enable one to evaluate the extent of VIS clustering, and formally compare data sets in terms of hot-spot overlap. Finally, we show that the BCP hot-spots from the repopulating samples coincide with greater gene and CpG island density than the median genome density. Conclusions The z-threshold and BCP methods are useful for comparing hot-spot patterns across data sets of disparate sizes. The methodology and software provided here should enable one to study hot-spot conservation across a variety of VIS data sets and evaluate vector safety for gene therapy trials. PMID:21914224
Perioperative outcome in sarcoma surgery.
Wente, Moritz N; Schwarzbach, Matthias H M; Hinz, Ulf; Leowardi, Christine; Mechtersheimer, Gunhild; Krempien, Robert; Egerer, Gerlinde; Friess, Helmut; Büchler, Markus W
2007-01-01
Soft tissue sarcomas (STS) are rare tumors accounting for less than 1% of all malignancies. Although disease-specific surgical management is increasingly important, only few data are available for STS. Here, we analyze a single institution setting focusing on perioperative surgical and clinical parameters. Prospectively gathered data of all adult patients undergoing surgery for STS including gastrointestinal stroma tumors (GIST) between October 2001 and October 2004. Patients undergoing only biopsy or ambulatory surgery were excluded. Statistical analysis was performed using SAS(R) software and patient's data from a computerized sarcoma registry. 159 patients with a median age of 60.2 years underwent a total of 179 operations. Three major sites of occurrence were notified: the visceral cavity (VIS) (36.3%), the retroperitoneum (RET) (31.3%), and the extremities (EXT) (27.4%). GIST (53.9%) were the most common type in the VIS, liposarcoma (62.5%) in the RET, and either liposarcoma (30.6%) or malignant fibrous histiocytoma (28.6%) in the EXT. Recurrence was treated in more than half of the patients with RET STS, and in almost one third of the EXT lesions, while primary occurrence dominated in the VIS. Median operation times in the VIS, RET, and EXT were 210, 240, and 120 min, respectively. Blood loss was 300, 500, and 50 ml for VIS, RET, and EXT operations. Morbidity was 26.2, 30.4, and 34.7% in VIS, RET, and EXT operations, respectively (reoperation rates were 9.4, 5.4, and 14.3%). Mortality was 1.5, 8.9, and 2.0% for VIS, RET, and EXT. Length of hospital stay in the groups was comparable. STS surgery of a single surgical unit contains predominantly VIS, RET, and EXT tumors. The STS subtype varies with location, as does length of operation, blood loss, morbidity, mortality, and reoperation rate. These data are helpful for planning the perioperative management of adult patients with STS and can be used for prognostic analyses.
An Integrative Review of Sleep for Nutrition Professionals12
Golem, Devon L.; Martin-Biggers, Jennifer T.; Koenings, Mallory M.; Davis, Katherine Finn; Byrd-Bredbenner, Carol
2014-01-01
Sleep is an essential lifestyle factor that contributes to overall health. The inverse relation between sleep duration and weight status has revealed the importance of sleep in nutritional health. This integrative review builds foundational knowledge with regard to sleep vis-à-vis nutrition by summarizing the importance and process of sleep, current sleep recommendations and trends, as well as lifestyle contributors to poor sleep. Additionally, it details the association between sleep and obesity and potential mechanisms for this association. Furthermore, guidance is offered regarding the incorporation of sleep considerations in nutrition counseling, communication, and research. Like many other lifestyle factors that contribute to nutritional health, sleep needs to be considered when examining weight management and health promotion. PMID:25398735
An integrative review of sleep for nutrition professionals.
Golem, Devon L; Martin-Biggers, Jennifer T; Koenings, Mallory M; Davis, Katherine Finn; Byrd-Bredbenner, Carol
2014-11-01
Sleep is an essential lifestyle factor that contributes to overall health. The inverse relation between sleep duration and weight status has revealed the importance of sleep in nutritional health. This integrative review builds foundational knowledge with regard to sleep vis-à-vis nutrition by summarizing the importance and process of sleep, current sleep recommendations and trends, as well as lifestyle contributors to poor sleep. Additionally, it details the association between sleep and obesity and potential mechanisms for this association. Furthermore, guidance is offered regarding the incorporation of sleep considerations in nutrition counseling, communication, and research. Like many other lifestyle factors that contribute to nutritional health, sleep needs to be considered when examining weight management and health promotion. © 2014 American Society for Nutrition.
Fotiou, Theodora; Triantis, Theodoros M; Kaloudis, Triantafyllos; O'Shea, Kevin E; Dionysiou, Dionysios D; Hiskia, Anastasia
2016-03-01
Visible light (VIS) photocatalysis has large potential as a sustainable water treatment process, however the reaction pathways and degradation processes of organic pollutants are not yet clearly defined. The presence of cyanobacteria cause water quality problems since several genera can produce potent cyanotoxins, harmful to human health. In addition, cyanobacteria produce taste and odor compounds, which pose serious aesthetic problems in drinking water. Although photocatalytic degradation of cyanotoxins and taste and odor compounds have been reported under UV-A light in the presence of TiO2, limited studies have been reported on their degradation pathways by VIS photocatalysis of these problematic compounds. The main objectives of this work were to study the VIS photocatalytic degradation process, define the reactive oxygen species (ROS) involved and elucidate the reaction mechanisms. We report carbon doped TiO2 (C-TiO2) under VIS leads to the slow degradation of cyanotoxins, microcystin-LR (MC-LR) and cylindrospermopsin (CYN), while taste and odor compounds, geosmin and 2-methylisoborneol, were not appreciably degraded. Further studies were carried-out employing several specific radical scavengers (potassium bromide, isopropyl alcohol, sodium azide, superoxide dismutase and catalase) and probes (coumarin) to assess the role of different ROS (hydroxyl radical OH, singlet oxygen (1)O2, superoxide radical anion [Formula: see text] ) in the degradation processes. Reaction pathways of MC-LR and CYN were defined through identification and monitoring of intermediates using liquid chromatography tandem mass spectrometry (LC-MS/MS) for VIS in comparison with UV-A photocatalytic treatment. The effects of scavengers and probes on the degradation process under VIS, as well as the differences in product distributions under VIS and UV-A, suggested that the main species in VIS photocatalysis is [Formula: see text] , with OH and (1)O2 playing minor roles in the degradation. Copyright © 2015 Elsevier Ltd. All rights reserved.
NASA Technical Reports Server (NTRS)
Zhang, Qingyuan; Cheng, Yen-Ben; Lyapustin, Alexei I.; Wang, Yujie; Zhang, Xiaoyang; Suyker, Andrew; Verma, Shashi; Shuai, Yanmin; Middleton, Elizabeth M.
2015-01-01
Satellite remote sensing estimates of Gross Primary Production (GPP) have routinely been made using spectral Vegetation Indices (VIs) over the past two decades. The Normalized Difference Vegetation Index (NDVI), the Enhanced Vegetation Index (EVI), the green band Wide Dynamic Range Vegetation Index (WDRVIgreen), and the green band Chlorophyll Index (CIgreen) have been employed to estimate GPP under the assumption that GPP is proportional to the product of VI and photosynthetically active radiation (PAR) (where VI is one of four VIs: NDVI, EVI, WDRVIgreen, or CIgreen). However, the empirical regressions between VI*PAR and GPP measured locally at flux towers do not pass through the origin (i.e., the zero X-Y value for regressions). Therefore they are somewhat difficult to interpret and apply. This study investigates (1) what are the scaling factors and offsets (i.e., regression slopes and intercepts) between the fraction of PAR absorbed by chlorophyll of a canopy (fAPARchl) and the VIs, and (2) whether the scaled VIs developed in (1) can eliminate the deficiency and improve the accuracy of GPP estimates. Three AmeriFlux maize and soybean fields were selected for this study, two of which are irrigated and one is rainfed. The four VIs and fAPARchl of the fields were computed with the MODerate resolution Imaging Spectroradiometer (MODIS) satellite images. The GPP estimation performance for the scaled VIs was compared to results obtained with the original VIs and evaluated with standard statistics: the coefficient of determination (R2), the root mean square error (RMSE), and the coefficient of variation (CV). Overall, the scaled EVI obtained the best performance. The performance of the scaled NDVI, EVI and WDRVIgreen was improved across sites, crop types and soil/background wetness conditions. The scaled CIgreen did not improve results, compared to the original CIgreen. The scaled green band indices (WDRVIgreen, CIgreen) did not exhibit superior performance to either the scaled EVI or NDVI in estimating crop daily GPP at these agricultural fields. The scaled VIs are more physiologically meaningful than original un-scaled VIs, but scaling factors and offsets may vary across crop types and surface conditions.
SemVisM: semantic visualizer for medical image
NASA Astrophysics Data System (ADS)
Landaeta, Luis; La Cruz, Alexandra; Baranya, Alexander; Vidal, María.-Esther
2015-01-01
SemVisM is a toolbox that combines medical informatics and computer graphics tools for reducing the semantic gap between low-level features and high-level semantic concepts/terms in the images. This paper presents a novel strategy for visualizing medical data annotated semantically, combining rendering techniques, and segmentation algorithms. SemVisM comprises two main components: i) AMORE (A Modest vOlume REgister) to handle input data (RAW, DAT or DICOM) and to initially annotate the images using terms defined on medical ontologies (e.g., MesH, FMA or RadLex), and ii) VOLPROB (VOlume PRObability Builder) for generating the annotated volumetric data containing the classified voxels that belong to a particular tissue. SemVisM is built on top of the semantic visualizer ANISE.1
[Temporal and spatial variation of MODIS vegetation indices in Hunan Province].
Lin, Hui; Xiong, Yu-Jiu; Wan, Ling-Feng; Mo, Deng-Kui; Sun, Hua
2007-03-01
Based on MODIS images and by using the algorithm of maximum value composite (MVC), the monthly vegetation indices (VIs) in 2005 in Hunan Province were obtained. Through the analysis of the MODIS VIs, Hunan Province was divided into six districts to describe the spatial distribution of the VIs, and by using the monthly mean temperature and rainfall data collected from 5 climatic monitoring stations in this province, the temporal variation of the VIs was analyzed. The results showed that the spatial distribution of MODIS VIs was positively correlated with vegetation cover, and appeared regional characteristics. The MODIS VIs varied with season, and the curves of their monthly mean values were downwards opening quadratic parabolas, with the maximum appeared in July. The value of MODIS EVI was smaller than that of MODIS NDVI. MODIS VI was mainly affected by monthly mean temperature, but this effect was decreased with decreasing latitude. The variation pattern of MODIS EVI was more apparent than that of MODIS NDVI, i. e. , the quadratic parabola of MODIS EVI was smoother, going gradually from minimum to maximum and then going down, while that of MODIS NDVI had tiny fluctuations on both sides of the maximum point.
VisIt: An End-User Tool for Visualizing and Analyzing Very Large Data
DOE Office of Scientific and Technical Information (OSTI.GOV)
Childs, Hank; Brugger, Eric; Whitlock, Brad
2012-11-01
VisIt is a popular open source tool for visualizing and analyzing big data. It owes its success to its foci of increasing data understanding, large data support, and providing a robust and usable product, as well as its underlying design that fits today's supercomputing landscape. This report, which draws heavily from an earlier publication at the SciDAC Conference in 2011 describes the VisIt project and its accomplishments.
Army 86 Cost Sensitivity Analysis Verification.
1980-09-01
NIGHT VIS SI AN/TAS-6 11 P21220 (Z50154) P-A DET SYS AN/USQ-70 24 QUANTITY LINE ITEM NUMBER NOMENCLATURE 26 Q16110 RADAR SET AN/PPS- SALP 54 Q16173...4 W/IMG 48 N04982 NIGHT VIS SI AN/TAS-4 55 NOSOSO NIGHT VIS SI AN/TAS-6 13 P21220 (Z50154) P-A BET SYS AN/USQ-70 -6 Q16110 RADAR SET AN/PPS- SALP 36
Hernández, Carla Navarro; Martín-Yerga, Daniel; González-García, María Begoña; Hernández-Santos, David; Fanjul-Bolado, Pablo
2018-02-01
Naratriptan, active pharmaceutical ingredient with antimigraine activity was electrochemically detected in untreated screen-printed carbon electrodes (SPCEs). Cyclic voltammetry and differential pulse voltammetry were used to carry out quantitative analysis of this molecule (in a Britton-Robinson buffer solution at pH 3.0) through its irreversible oxidation (diffusion controlled) at a potential of +0.75V (vs. Ag pseudoreference electrode). Naratriptan oxidation product is an indole based dimer with a yellowish colour (maximum absorption at 320nm) so UV-VIS spectroelectrochemistry technique was used for the very first time as an in situ characterization and quantification technique for this molecule. A reflection configuration approach allowed its measurement over the untreated carbon based electrode. Finally, time resolved Raman Spectroelectrochemistry is used as a powerful technique to carry out qualitative and quantitative analysis of Naratriptan. Electrochemically treated silver screen-printed electrodes are shown as easy to use and cost-effective SERS substrates for the analysis of Naratriptan. Copyright © 2017 Elsevier B.V. All rights reserved.
NASA Technical Reports Server (NTRS)
Allamandola, L. J.
1992-01-01
Our fundamental knowledge of interstellar grain composition has grown substantially during the past two decades thanks to significant advances in two areas: astronomical infrared spectroscopy and laboratory astrophysics. The opening of the mid-infrared, the spectral range from 4000-400 cm(sup -1) (2.5-25 microns), to spectroscopic study has been critical to this progress because spectroscopy in this region reveals more about a materials molecular composition and structure than any other physical property. Infrared spectra which are diagnostic of interstellar grain composition fall into two categories: absorption spectra of the dense and diffuse interstellar media, and emission spectra from UV-Vis rich dusty regions. The former will be presented in some detail, with the latter only very briefly mentioned. This paper summarized what we have learned from these spectra and presents 'doorway' references into the literature. Detailed reviews of many aspects of interstellar dust are given.
Towards Infusing Giovanni with a Semantic and Provenance Aware Visualization System
NASA Astrophysics Data System (ADS)
Del Rio, N.; Pinheiro da Silva, P.; Leptoukh, G. G.; Lynnes, C.
2011-12-01
Giovanni is a Web-based application developed by GES DISC that provides simple and intuitive ways to visualize, analyze, and access vast amounts of Earth science remote sensed data. Currently, the Giovanni visualization module is only aware of the physical links (i.e., hard-coded) between data and services and consequently cannot be easily adapted to new visualization scenarios. VisKo, a semantically enabled visualization framework, can be leveraged by Giovanni as a semantic bridge between data and visualization. VisKo relates data and visualization services at conceptual (i.e., ontological) levels and relies on reasoning systems to leverage the conceptual relationships to automatically infer physical links, facilitating an adaptable environment for new visualization scenarios. This is particularly useful for Giovanni, which has been constantly retrofitted with new visualization software packages to keep up with advancement in visualization capabilities. During our prototype integration of Giovanni with VisKo, a number of future steps were identified that if implemented could cement the integration and promote our prototype to operational status. A number of integration issues arose including the mediation of different languages used by each system to characterize datasets; VisKo relies on semantic data characterization to "match-up" data with visualization processes. It was necessary to identify mappings between Giovanni XML provenance and Proof Markup Language, which is understood by VisKo. Although a translator was implemented based on identified mappings, a more elegant solution is to develop a domain data ontology specific to Giovanni and to "align" this ontology with PML, enabling VisKo to directly ingest the semantic descriptions of Giovanni data. Additionally, the relationship between dataset components (e.g., variables and attributes) and visualization plot components (e.g., geometries, axes, titles) should also be modeled. In Giovanni, meta-data descriptions are used to configure the different properties of the plots such as titles, color-tables, and variable-to-axis bindings. Giovanni services rely on a set of custom attributes and naming conventions that help identify the relationships between dataset components and plot properties. VisKo visualization services however are generic modules that do not rely on any domain specific conventions for identifying relationships between dataset attributes and plot configuration. Rather, VisKo services rely on parameters to configure specific behaviors of the generic services. The relationship between VisKo parameters and plot properties however has yet to formally documented, partly because VisKo regards plots as holistic entities without any internal structure from which to relate parameters. We understand the need for a visualization plot ontology that defines plot components, their retinal properties, such as position and color, and the relationship between the plot properties to controlling service parameter sets. The plot ontology would also be linked to our domain data ontology, providing VisKo with the comprehensive understanding about how data attributes can cue the configuration of plots, and how a specific plot configuration relates to service parameters.
On the Origin of Quantum Diffusion Coefficient and Quantum Potential
NASA Astrophysics Data System (ADS)
Gupta, Aseem
2016-03-01
Synchronizability of space and time experiences between different inhabitants of a spacetime is abstracted as a fundamental premise of Classical physics. Absence thereof i.e. desynchronization between space and time experiences of a system under study and the observer is then studied for a single dimension single particle system. Desynchronization fundamentally makes probability concepts enter physics ab-initio and not as secondary tools to deal with situations wherein incomplete information in situation following perfectly deterministic dynamics demands its introduction. Desynchronization model based on Poisson distribution of events vis-à-vis an observer, leads to expectation of particle's motion as a Brownian motion deriving Nelson's quantum diffusion coefficient naturally, without needing to postulate it. This model also incorporates physical effects akin to those of Bohm's Quantum Potential, again without needing any sub-quantum medium. Schrodinger's equation is shown to be derivable incorporating desynchronization only of space while Quantum Field Theory is shown to model desynchronization of time as well. Fundamental suggestion of the study is that it is desynchronization that is at the root of quantum phenomena rather than sub-micro scales of spacetime. Absence of possibility of synchronization between system's space and time and those of observer is studied. Mathematical modeling of desynchronized evolution explains some intriguing aspects of Quantum Mechanical theory.
Characterization of low-dose doxorubicin-loaded silica-based nanocomposites
NASA Astrophysics Data System (ADS)
Prokopowicz, Magdalena
2018-01-01
In this study, we synthesized multicomponent solid films of low-dose doxorubicin (DOX)-loaded polydimethylsiloxane (PDMS)-SiO2/CaP nanocomposites via sol-gel process combined with the method of evaporation-induced self-assembly (EISA) at low temperature. Nanomechanical properties (elasticity and adhesion) of the synthesized multicomponent films were determined by using atomic force microscopy with a PeakForce™ quantitative nanomechanical mapping imaging technique. Solid state of DOX in the synthesized films was studied by using UV-vis and fluorescence spectroscopy. The release profile of different concentrations of DOX loaded (1, 3, and 5 wt%) on the multicomponent films was assessed using USP Apparatus 4 and via UV-vis end analysis. Results indicate drug-component interactions on the overall morphology of domains (size and shape), nanomechanical properties, and release behavior of the DOX-loaded nanocomposites. We observed a progressive increase in surface roughness and mean adhesive value with increasing concentration of DOX loaded (0-5 wt%). In addition, for all the different concentrations of DOX-loaded, we observed a diffusion-controlled drug release.
Chang, Fei; Xie, Yunchao; Chen, Juan; Luo, Jieru; Li, Chenlu; Hu, Xuefeng; Xu, Bin
2015-02-01
Preparation of uniform BiOCI flower-like microspheres was facilely accomplished through a sim- ple protocol involving regulation of pH value in aqueous with sodium hydroxide in the presence of n-propanol. The as-prepared samples were characterized by a collection of techniques, such as X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), UV-vis diffuse reflectance spectroscopy (UV-vis DRS), and nitrogen adsorption-desorption isotherms. Based upon the SEM analyses, uniform microspheres could be formed with coexistence of some fragments of BiOCI nanosheets without n-propanol. The addition of appropriate amount of n-propanol was beneficial to provide BiOCI samples containing only flower-like microspheres, which were further subjected to the photocatalytic measurements towards Rhodamine B in aqueous under visible light irradiation and exhibited the best catalytic performance among all samples tested. In addition, the photocatalytic process was confirmed to undergo through a photosensitization pathway, in which superoxide radicals (.O-) played critical roles.
NASA Astrophysics Data System (ADS)
Kuratli, Jasmin; Pesch, Theresa; Marti, Hanna; Blenn, Christian; Borel, Nicole
2018-02-01
Infections with Chlamydia trachomatis are the major cause for infectious blindness and still represent the most common bacterial sexually transmitted disease worldwide. Considering the possible side effects of antibiotic therapy and the increasing threat of antibiotic resistance, alternative therapeutic strategies are needed. Previous studies showed a reduction of C. trachomatis infectivity after irradiation with water filtered infrared A alone (wIRA) or in combination with visible light (wIRA/VIS). In this study, we aimed to gain further insight into the working mechanism of wIRA/VIS by analyzing cytokine and chemokine levels of infected and non-infected HeLa cells following triple dose irradiation at 24, 36 and 40 hours post infection. Subsequently, we examined the influence of cytokines on irradiation and chlamydial infection using a cytokine/chemokine inhibitor (Azelastine) and by IL-6 and IL-8 gene silencing. A triple dose irradiation significantly reduced chlamydial infectivity in HeLa cells without inducing the chlamydial stress response. The reducing effect was present regardless of the addition of cycloheximide (CHX), a host protein synthesis inhibitor. Chlamydial infection, wIRA/VIS treatment and the combination of both revealed a similar release pattern of a subset of pro-inflammatory cytokines (IL-6, IL-8, RANTES, Serpin E1). The addition of Azelastine induced the chlamydial stress response in non-irradiated samples. This effect was even more pronounced in wIRA/VIS-treated conditions. Silencing of IL-6 and IL-8 resulted in a lower chlamydial infectivity. However, wIRA/VIS treatment of infected and silenced cells reduced the chlamydial infectivity similar to wIRA/VIS treated control cells. Further studies are needed to elucidate the working mechanism of wIRA/VIS.
Rodriguez, Mabel; Spaniel, Filip; Konradova, Lucie; Sedlakova, Katerina; Dvorska, Karolina; Prajsova, Jitka; Kratochvilova, Zuzana; Levcik, David; Vlcek, Kamil; Fajnerova, Iveta
2015-01-01
Objectives: Deficit in visuospatial functions can influence both simple and complex daily life activities. Despite the fact that visuospatial deficit was reported in schizophrenia, research on visuospatial functions as an independent entity is limited. Our study aims to elucidate the impact of visuospatial deficit in comparison with verbal deficit on global functioning and quality of life in the first psychotic episode of schizophrenia spectrum disorder (FES). The significance of clinical symptoms and antipsychotic medication was also studied. Methods: Thirty-six FES patients and a matched group of healthy controls (HC group) were assessed with a neuropsychological battery focused on visuospatial (VIS) and verbal (VERB) functions. Using multiple regression analysis, we evaluated the cumulative effect of VERB and VIS functions, psychiatric symptoms (PANSS) and antipsychotic medication on global functioning (GAF) and quality of life (WHOQOL-BREF) in the FES group. Results: The FES group demonstrated significant impairment both in VIS and VERB cognitive abilities compared to the HC group. Antipsychotic medication did not significantly affect either VIS or VERB functioning. PANSS was not related to cognitive functioning, apart from the Trail Making Test B. In the FES group, the GAF score was significantly affected by the severity of positive symptoms and VERB functioning, explaining together 60% of GAF variability. The severity of negative and positive symptoms affected only the Physical health domain of WHOQOL-BREF. The degree of VERB deficit was associated with both Physical and Psychological health. Although we did not find any relation between VIS functioning, GAF, and WHOQOL-BREF, a paradoxical finding emerged in the Environment quality domain, where a worse quality of the environment was associated with better VIS functioning. Conclusions: Our results suggest that the deficit in VIS functions is an integral part of cognitive deficit in schizophrenia spectrum disorders, rather than a side effect of symptomatology or antipsychotic medication. Moreover, VERB functioning was a better predictor of GAF and WHOQOL-BREF than VIS functioning. Given the findings of negative or missing effect of VIS deficit on WHOQOL-BREF and GAF, the accuracy of these measures in evaluating the impact of global cognitive deficit on everyday life in schizophrenia could be questioned. PMID:26733828
NASA Astrophysics Data System (ADS)
Dong, Rui; Wang, Yuan; Wang, Ningning; Xu, Lei; He, Jie; Wu, Shanshan; Lan, Yunxiang; Hu, Jinsong
2016-09-01
Layered photocatalytic materials M1/3TiNbO5 (M = Fe, Ce) were prepared by ion-exchange of KTiNbO5 with M(NO3)3. The parent KTiNbO5 was synthesized with titanium (IV) isopropoxide and niobium oxalate by a novel polymerized complex (PC) method. The micro-structures and spectral response features of the as-prepared samples were characterized by powder X-ray diffraction (XRD), transmission electron microscope (TEM), laser Raman spectroscopy (LRS) and UV-vis diffuse reflectance spectroscopy (UV-vis DRS). The results revealed that there was a significant interaction between the interlayer cation and the terminal Nbdbnd O (Tidbnd O) bond in the NbO6 (TiO6) unit of the laminates. Photocatalytic performance was evaluated in oxidation of ethyl mercaptan under natural and UV light irradiation. It can be deduced that the photocatalytic oxidization performance can be directly affected by the characteristics of the interlayer cations.
HTC Vive MeVisLab integration via OpenVR for medical applications
Egger, Jan; Gall, Markus; Wallner, Jürgen; Boechat, Pedro; Hann, Alexander; Li, Xing; Chen, Xiaojun; Schmalstieg, Dieter
2017-01-01
Virtual Reality, an immersive technology that replicates an environment via computer-simulated reality, gets a lot of attention in the entertainment industry. However, VR has also great potential in other areas, like the medical domain, Examples are intervention planning, training and simulation. This is especially of use in medical operations, where an aesthetic outcome is important, like for facial surgeries. Alas, importing medical data into Virtual Reality devices is not necessarily trivial, in particular, when a direct connection to a proprietary application is desired. Moreover, most researcher do not build their medical applications from scratch, but rather leverage platforms like MeVisLab, MITK, OsiriX or 3D Slicer. These platforms have in common that they use libraries like ITK and VTK, and provide a convenient graphical interface. However, ITK and VTK do not support Virtual Reality directly. In this study, the usage of a Virtual Reality device for medical data under the MeVisLab platform is presented. The OpenVR library is integrated into the MeVisLab platform, allowing a direct and uncomplicated usage of the head mounted display HTC Vive inside the MeVisLab platform. Medical data coming from other MeVisLab modules can directly be connected per drag-and-drop to the Virtual Reality module, rendering the data inside the HTC Vive for immersive virtual reality inspection. PMID:28323840
HTC Vive MeVisLab integration via OpenVR for medical applications.
Egger, Jan; Gall, Markus; Wallner, Jürgen; Boechat, Pedro; Hann, Alexander; Li, Xing; Chen, Xiaojun; Schmalstieg, Dieter
2017-01-01
Virtual Reality, an immersive technology that replicates an environment via computer-simulated reality, gets a lot of attention in the entertainment industry. However, VR has also great potential in other areas, like the medical domain, Examples are intervention planning, training and simulation. This is especially of use in medical operations, where an aesthetic outcome is important, like for facial surgeries. Alas, importing medical data into Virtual Reality devices is not necessarily trivial, in particular, when a direct connection to a proprietary application is desired. Moreover, most researcher do not build their medical applications from scratch, but rather leverage platforms like MeVisLab, MITK, OsiriX or 3D Slicer. These platforms have in common that they use libraries like ITK and VTK, and provide a convenient graphical interface. However, ITK and VTK do not support Virtual Reality directly. In this study, the usage of a Virtual Reality device for medical data under the MeVisLab platform is presented. The OpenVR library is integrated into the MeVisLab platform, allowing a direct and uncomplicated usage of the head mounted display HTC Vive inside the MeVisLab platform. Medical data coming from other MeVisLab modules can directly be connected per drag-and-drop to the Virtual Reality module, rendering the data inside the HTC Vive for immersive virtual reality inspection.
The Classification of Ground Roasted Decaffeinated Coffee Using UV-VIS Spectroscopy and SIMCA Method
NASA Astrophysics Data System (ADS)
Yulia, M.; Asnaning, A. R.; Suhandy, D.
2018-05-01
In this work, an investigation on the classification between decaffeinated and non- decaffeinated coffee samples using UV-VIS spectroscopy and SIMCA method was investigated. Total 200 samples of ground roasted coffee were used (100 samples for decaffeinated coffee and 100 samples for non-decaffeinated coffee). After extraction and dilution, the spectra of coffee samples solution were acquired using a UV-VIS spectrometer (Genesys™ 10S UV-VIS, Thermo Scientific, USA) in the range of 190-1100 nm. The multivariate analyses of the spectra were performed using principal component analysis (PCA) and soft independent modeling of class analogy (SIMCA). The SIMCA model showed that the classification between decaffeinated and non-decaffeinated coffee samples was detected with 100% sensitivity and specificity.
Visualization of metabolic interaction networks in microbial communities using VisANT 5.0
Granger, Brian R.; Chang, Yi -Chien; Wang, Yan; ...
2016-04-15
Here, the complexity of metabolic networks in microbial communities poses an unresolved visualization and interpretation challenge. We address this challenge in the newly expanded version of a software tool for the analysis of biological networks, VisANT 5.0. We focus in particular on facilitating the visual exploration of metabolic interaction between microbes in a community, e.g. as predicted by COMETS (Computation of Microbial Ecosystems in Time and Space), a dynamic stoichiometric modeling framework. Using VisANT's unique meta-graph implementation, we show how one can use VisANT 5.0 to explore different time-dependent ecosystem-level metabolic networks. In particular, we analyze the metabolic interaction networkmore » between two bacteria previously shown to display an obligate cross-feeding interdependency. In addition, we illustrate how a putative minimal gut microbiome community could be represented in our framework, making it possible to highlight interactions across multiple coexisting species. We envisage that the "symbiotic layout" of VisANT can be employed as a general tool for the analysis of metabolism in complex microbial communities as well as heterogeneous human tissues.« less
DisVis: Visualizing Discussion Threads in Online Health Communities.
Nakikj, Drashko; Mamykina, Lena
2016-01-01
An increasing number of individuals turn to online health communities (OHC) for information, advice and support about their health condition or disease. As a result of users' active participation, these forums store overwhelming volumes of information, which can make access to this information challenging and frustrating. To help overcome this problem we designed a discussion visualization tool DisVis. DisVis includes features for overviewing, browsing and finding particular information in a discussion. In a between subjects study, we tested the impact of DisVis on individuals' ability to provide an overview of a discussion, find topics of interest and summarize opinions. The study showed that after using the tool, the accuracy of participants' answers increased by 68% (p-value = 0.023) while at the same time exhibiting trends for reducing the time to answer by 38% with no statistical significance (p-value = 0.082). Qualitative interviews showed general enthusiasm regarding tools for improving browsing and searching for information within discussion forums, suggested different usage scenarios, highlighted opportunities for improving the design of DisVis, and outlined new directions for visualizing user-generated content within OHCs.
Evaluating Renal Transplant Status Using Viscoelastic Response (VisR) Ultrasound.
Hossain, Md Murad; Selzo, Mallory R; Hinson, Robert M; Baggesen, Leslie M; Detwiler, Randal K; Chong, Wui K; Burke, Lauren M; Caughey, Melissa C; Fisher, Melrose W; Whitehead, Sonya B; Gallippi, Caterina M
2018-05-10
Chronic kidney disease is most desirably and cost-effectively treated by renal transplantation, but graft survival is a major challenge. Although irreversible graft damage can be averted by timely treatment, intervention is delayed when early graft dysfunction goes undetected by standard clinical metrics. A more sensitive and specific parameter for delineating graft health could be the viscoelastic properties of the renal parenchyma, which are interrogated non-invasively by Viscoelastic Response (VisR) ultrasound, a new acoustic radiation force (ARF)-based imaging method. Assessing the performance of VisR imaging in delineating histologically confirmed renal transplant pathologies in vivo is the purpose of the study described here. VisR imaging was performed in patients with (n = 19) and without (n = 25) clinical indication for renal allograft biopsy. The median values of VisR outcome metrics (τ, relative elasticity [RE] and relative viscosity [RV]) were calculated in five regions of interest that were manually delineated in the parenchyma (outer, center and inner) and in the pelvis (outer and inner). The ratios of a given VisR metric for all possible region-of-interest combinations were calculated, and the corresponding ratios were statistically compared between biopsied patients subdivided by diagnostic categories versus non-biopsied, control allografts using the two-sample Wilcoxon test (p <0.05). Although τ ratios non-specifically differentiated allografts with vascular disease, tubular/interstitial scarring, chronic allograft nephropathy and glomerulonephritis from non-biopsied control allografts, RE distinguished only allografts with vascular disease and tubular/interstitial scarring, and RV distinguished only vascular disease. These results suggest that allografts with scarring and vascular disease can be identified using non-invasive VisR RE and RV metrics. Copyright © 2018 World Federation for Ultrasound in Medicine and Biology. Published by Elsevier Inc. All rights reserved.
2014-07-30
of the IEEE Intl. Conf. on Comp. Vis. and Patt . Recog. (CVPR). 07-JAN-14, . : , B. Taylor, A. Ayvaci, A. Ravichandran, and S. Soatto.. Semantic video...detection, localization and tracking, Intl. Conf. on Comp. Vis. Patt . Recog.. 06-JAN-11, . : , Michalis Raptis, Iasonas Kokkinos, Stefano Soatto...of the IEEE Intl. Conf. on Comp. Vis. and Patt . Recog., 2012. [12] M. Raptis and S. Soatto. Tracklet descriptors for action modeling and video
Study of Vis/NIR spectroscopy measurement on acidity of yogurt
NASA Astrophysics Data System (ADS)
He, Yong; Feng, Shuijuan; Wu, Di; Li, Xiaoli
2006-09-01
A fast measurement of pH of yogurt using Vis/NIR-spectroscopy techniques was established in order to measuring the acidity of yogurt rapidly. 27 samples selected separately from five different brands of yogurt were measured by Vis/NIR-spectroscopy. The pH of yogurt on positions scanned by spectrum was measured by a pH meter. The mathematical model between pH and Vis/NIR spectral measurements was established and developed based on partial least squares (PLS) by using Unscramble V9.2. Then 25 unknown samples from 5 different brands were predicted based on the mathematical model. The result shows that The correlation coefficient of pH based on PLS model is more than 0.890, and standard error of calibration (SEC) is 0.037, standard error of prediction (SEP) is 0.043. Through predicting the pH of 25 samples of yogurt from 5 different brands, the correlation coefficient between predictive value and measured value of those samples is more than 0918. The results show the good to excellent prediction performances. The Vis/NIR spectroscopy technique had a significant greater accuracy for determining the value of pH. It was concluded that the VisINIRS measurement technique can be used to measure pH of yogurt fast and accurately, and a new method for the measurement of pH of yogurt was established.
Suarnaba, Emee Grace Tabares; Lee, Yi Fuan; Yamada, Hiroshi; Tagawa, Tomohiko
2016-11-01
An ultraviolet visible (UV-Vis) microspectroscopic system was designed for the in situ characterization of the activity of the silica supported platinum (Pt) catalyst toward the dehydrogenation of 1-methyl-1,4-cyclohexadiene carried out in a custom-designed catalytic microreactor cell. The in situ catalytic microreactor cell (ICMC) with inlet/outlet ports was prepared using quartz cover as the optical window to facilitate UV-Vis observation. A fabricated thermometric stage was adapted to the UV-Vis microspectrophotometer to control the reaction temperature inside the ICMC. The spectra were collected by focusing the UV-Vis beam on a 30 × 30 µm area at the center of ICMC. At 393 K, the sequential measurement of the spectra recorded during the reaction exhibited a broad absorption peak with maximum absorbance at 260 nm that is characteristic for gaseous toluene. This result indicates that the silica supported Pt catalyst is active towards the dehydrogenation of 1-methyl-1,4-cyclohexadiene at the given experimental conditions. The onset of coke formation was also detected based on the appearance of absorption bands at 300 nm. The UV-Vis microspectroscopic system developed can be used further in studying the mechanism of the dehydrogenation reaction. © The Author(s) 2016.
Photocatalytic degradation of diethyl phthalate using TiO{sub 2} nanoparticles
DOE Office of Scientific and Technical Information (OSTI.GOV)
Singla, Pooja, E-mail: pooja.singla@thapar.edu; Pandey, O. P., E-mail: pooja.singla@thapar.edu; Singh, K., E-mail: pooja.singla@thapar.edu
2014-04-24
TiO{sub 2} nanoparticles predominantly in rutile phase are synthesized by ultrasonication assisted sol-gel method. TiO{sub 2} powder is characterized using X-ray powder diffraction and UV-vis diffuse reflectance. TiO{sub 2} is used as catalyst in photocatalytic degradation of Diethyl Phthalate. TiO{sub 2} exhibits good photocatalytic activity for the degradation of diethyl phthalate.
Huang, Y; Andueza, D; de Oliveira, L; Zawadzki, F; Prache, S
2015-11-01
Since consumers are showing increased interest in the origin and method of production of their food, it is important to be able to authenticate dietary history of animals by rapid and robust methods used in the ruminant products. Promising breakthroughs have been made in the use of spectroscopic methods on fat to discriminate pasture-fed and concentrate-fed lambs. However, questions remained on their discriminatory ability in more complex feeding conditions, such as concentrate-finishing after pasture-feeding. We compared the ability of visible reflectance spectroscopy (Vis RS, wavelength range: 400 to 700 nm) with that of visible-near-infrared reflectance spectroscopy (Vis-NIR RS, wavelength range: 400 to 2500 nm) to differentiate between carcasses of lambs reared with three feeding regimes, using partial least square discriminant analysis (PLS-DA) as a classification method. The sample set comprised perirenal fat of Romane male lambs fattened at pasture (P, n = 69), stall-fattened indoors on commercial concentrate and straw (S, n = 55) and finished indoors with concentrate and straw for 28 days after pasture-feeding (PS, n = 65). The overall correct classification rate was better for Vis-NIR RS than for Vis RS (99.0% v. 95.1%, P < 0.05). Vis-NIR RS allowed a correct classification rate of 98.6%, 100.0% and 98.5% for P, S and PS lambs, respectively, whereas Vis RS allowed a correct classification rate of 98.6%, 94.5% and 92.3% for P, S and PS lambs, respectively. This study suggests the likely implication of molecules absorbing light in the non-visible part of the Vis-NIR spectra (possibly fatty acids), together with carotenoid and haem pigments, in the discrimination of the three feeding regimes.
NASA Astrophysics Data System (ADS)
Tower, J. R.; Cope, A. D.; Pellon, L. E.; McCarthy, B. M.; Strong, R. T.
1986-06-01
Two solid-state sensors for use in remote sensing instruments operating in the pushbroom mode are examined. The design and characteristics of the visible/near-infrared (VIS/NIR) device and the short-wavelength infrared (SWIR) device are described. The VIS/NIR is a CCD imager with four parallel sensor lines, each 1024 pixel long; the chip design and filter system of the VIS/NIR are studied. The performance of the VIS/NIR sensor with mask and its system performance are measured. The SWIR is a dual-band line imager consisting of palladium silicide Schottky-barrier detectors coupled to CCD multiplexers; the performance of the device is analyzed. The substrate materials and layout designs used to assemble the 4 x 5120-element VIS/NIR array and the 2 x 2560-element SWIR array are discussed, and the planarity of the butted arrays are verified using a profilometer. The optical and electrical characteristics, and the placement and butting accuracy of the arrays are evaluated. It is noted that the arrays met or exceed their expected performance.
Measurement of phenols dearomatization via electrolysis: the UV-Vis solid phase extraction method.
Vargas, Ronald; Borrás, Carlos; Mostany, Jorge; Scharifker, Benjamin R
2010-02-01
Dearomatization levels during electrochemical oxidation of p-methoxyphenol (PMP) and p-nitrophenol (PNP) have been determined through UV-Vis spectroscopy using solid phase extraction (UV-Vis/SPE). The results show that the method is satisfactory to determine the ratio between aromatic compounds and aliphatic acids and reaction kinetics parameters during treatment of wastewater, in agreement with results obtained from numerical deconvolution of UV-Vis spectra. Analysis of solutions obtained from electrolysis of substituted phenols on antimony-doped tin oxide (SnO(2)--Sb) showed that an electron acceptor substituting group favored the aromatic ring opening reaction, preventing formation of intermediate quinone during oxidation. (c) 2009 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Perez-Priego, O.; Guan, J.; Fava, F.; Rossini, M.; Wutzler, T.; Moreno, G.; Carrara, A.; Kolle, O.; Schrumpf, M.; Reichstein, M.; Migliavacca, M.
2014-12-01
Recent studies have shown how human induced N:P imbalances are affecting essential processes (e.g. photosynthesis, plant growth rate) that lead to important changes in ecosystem structure and function. In this regard, the accuracy of the approaches based on remotely-sensed data for monitoring and modeling gross primary production (GPP) relies on the ability of vegetation indices (VIs) to track the dynamics of vegetation physiological and biophysical properties/variables. Promising results have been recently obtained when Chlorophyll-sensitive VIs and Chlorophyll fluorescence are combined with structural indices in the framework of the Monteith's light use efficiency (LUE) model. However, further ground-based experiments are required to validate LUE model performances, and their capability to be generalized under different nutrient availability conditions. In this study, the overall objective was to investigate the sensitivity of VIs to track short- and long-term GPP variations in a Mediterranean grassland under different N and P fertilization treatments. Spectral VIs were acquired manually using high resolution spectrometers (HR4000, OceanOptics, USA) along a phenological cycle. The VIs examined included photochemical reflectance index (PRI), MERIS terrestrial-chlorophyll index (MTCI) and normalized difference vegetation index (NDVI). Solar-induced chlorophyll fluorescence calculated at the oxygen absorption band O2-A (F760) using spectral fitting methods was also used. Simultaneously, measurements of GPP and environmental variables were conducted using a transient-state canopy chamber. Overall, GPP, F760 and VIs showed a clear seasonal time-trend in all treatments, which was driven by the phenological development of the grassland. Results showed significant differences (p<0.05) in midday GPP values between N and without N addition plots, in particular at the peak of the growing season during the flowering stage and at the end of the season during senescence. While NDVI did not show any significant difference between treatments, VIs sensitive to pigment variations and physiology (PRI, MTCI) and F760 behaved as GPP. Model performance test indicated that VIs related to physiology and fluorescence are key to account for nutrient availability in LUE models and to better predict GPP.
Din, Mairaj; Zheng, Wen; Rashid, Muhammad; Wang, Shanqin; Shi, Zhihua
2017-01-01
Hyperspectral reflectance derived vegetation indices (VIs) are used for non-destructive leaf area index (LAI) monitoring for precise and efficient N nutrition management. This study tested the hypothesis that there is potential for using various hyperspectral VIs for estimating LAI at different growth stages of rice under varying N rates. Hyperspectral reflectance and crop canopy LAI measurements were carried out over 2 years (2015 and 2016) in Meichuan, Hubei, China. Different N fertilization, 0, 45, 82, 127, 165, 210, 247, and 292 kg ha-1, were applied to generate various scales of VIs and LAI values. Regression models were used to perform quantitative analyses between spectral VIs and LAI measured under different phenological stages. In addition, the coefficient of determination and RMSE were employed to evaluate these models. Among the nine VIs, the ratio vegetation index, normalized difference vegetation index (NDVI), modified soil-adjusted vegetation index (MSAVI), modified triangular vegetation index (MTVI2) and exhibited strong and significant relationships with the LAI estimation at different phenological stages. The enhanced vegetation index performed moderately. However, the green normalized vegetation index and blue normalized vegetation index confirmed that there is potential for crop LAI estimation at early phenological stages; the soil-adjusted vegetation index and optimized soil-adjusted vegetation index were more related to the soil optical properties, which were predicted to be the least accurate for LAI estimation. The noise equivalent accounted for the sensitivity of the VIs and MSAVI, MTVI2, and NDVI for the LAI estimation at phenological stages. The results note that LAI at different crop phenological stages has a significant influence on the potential of hyperspectral derived VIs under different N management practices. PMID:28588596
NASA Astrophysics Data System (ADS)
Arantes Camargo, Livia; Marques Júnior, José; Reynaldo Ferracciú Alleoni, Luís; Tadeu Pereira, Gener; De Bortoli Teixeira, Daniel; Santos Rabelo de Souza Bahia, Angélica
2017-04-01
Environmental impact assessments may be assisted by spatial characterization of potentially toxic elements (PTEs). Diffuse reflectance spectroscopy (DRS) and X-ray fluorescence spectroscopy (XRF) are rapid, non-destructive, low-cost, prediction tools for a simultaneous characterization of different soil attributes. Although low concentrations of PTEs might preclude the observation of spectral features, their contents can be predicted using spectroscopy by exploring the existing relationship between the PTEs and soil attributes with spectral features. This study aimed to evaluate, in three geomorphic surfaces of Oxisols, the capacity for predicting PTEs (Ba, Co, and Ni) and their spatial variability by means of diffuse reflectance spectroscopy (DRS) and X-ray fluorescence spectroscopy (XRF). For that, soil samples were collected from three geomorphic surfaces and analyzed for chemical, physical, and mineralogical properties, and then analyzed in DRS (visible + near infrared - VIS+NIR and medium infrared - MIR) and XRF equipment. PTE prediction models were calibrated using partial least squares regression (PLSR). PTE spatial distribution maps were built using the values calculated by the calibrated models that reached the best accuracy using geostatistics. PTE prediction models were satisfactorily calibrated using MIR DRS for Ba, and Co (residual prediction deviation - RPD > 3.0), Vis DRS for Ni (RPD > 2.0) and FRX for all the studied PTEs (RPD > 1.8). DRS- and XRF-predicted values allowed the characterization and the understanding of spatial variability of the studied PTEs.
Quidu, F; Escaffre, J P
2010-01-01
The concept of policy management in psychiatry requires knowledge representations of the "mad", the "mentally ill" and "depressed" by the people. It is therefore to highlight the diversity of definitions that it attributes to individual psychiatric disorders, particularly by cultural norms typically associated with geographic locations. To do this, we successively study the forms of stigmatisations broadly, and then by site, and the causes of thereof. But this does not suffice for the design of any policy in this area must also take into account the attitudes and behaviours of the population vis-à-vis the existing psychiatric facilities globally and per site. The treatments were carried out using data from the socio-anthropological and epidemiological "Mental Health in the general population: images and realities" made by the French Collaborating Centre of WHO for research and training Mental Health (WHOCC, Lille, France) and the Directorate of Research, Studies, Evaluation and Statistics (DREES) with 40 000 people aged 18 and older in metropolitan France and in the departments of overseas between 1999 and 2003. The techniques used range from descriptive statistics to multivariate analysis (correspondence analysis and multiple ascending hierarchical classification). The images of the "madness", the "mentally ill" or the "depression" in the French population are disparate. Nevertheless, some characteristics are found with high frequency: the "depressive" is rather seen as an isolated person, the "mentally ill" as a mental defective with bizarre speech, while "crazy" would rather characterized by violence (delusions and violent towards others, beat his family, incest). The "mentally ill" is sometimes defined by these last criteria. These images are not influenced by knowledge of a relative suffering from mental illness or a psychiatric episode experienced by the interviewee. The causes of mental illness (the "madness" and "mentally ill"), two contradictory trends have expressed. Some believe it has a physical origin, and in that case the healing is difficult and care must be hospitable. Others believe it was originally a non-physical (social), and in this case, recovery is possible, and care must be ambulatory. People surveyed in some sites have homogeneous opinions in this regard: Berk, Thuir or Guéret, the first opinion is mainly expressed, whereas the opposite trend was observed in Villejuif, Niort, Lille, Poitiers, Paris15, Paris10. In contrast, for depression, the cause is, for almost the entire population, non-physical. Overall, 41% of French people support psychiatric hospitals, while 32% oppose, preferring ambulatory solutions. In fact, opinions differ so widely among survey sites. They are not influenced by the images of people surveyed vis-à-vis the "madness", the "mentally ill" or the "depression". The way of organizing psychiatric sectorization (taken care rather intra-hospital versus extra-hospital, number of agents, etc.) does not influence either the image of "mad", the "mentally ill" or "depression" in population, nor the opinions vis-à-vis psychiatric hospitals. We deduce that these images are generated by other factors, probably cultural factors. Copyright 2010 L’Encéphale. Published by Elsevier Masson SAS.. All rights reserved.
Student Recruitment: A Market Research Primer.
ERIC Educational Resources Information Center
Moore, Richard W.
1987-01-01
Illustrates how proprietary schools and community colleges have used market research techniques to identify marketing problems, determine student characteristics, measure market penetration, understand market position vis-a-vis the competition, and assess applicants' perceptions. (AYC)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lee Spangler; Ross Bricklemyer; David Brown
2012-03-15
There is growing need for rapid, accurate, and inexpensive methods to measure, and verify soil organic carbon (SOC) change for national greenhouse gas accounting and the development of a soil carbon trading market. Laboratory based soil characterization typically requires significant soil processing, which is time and resource intensive. This severely limits application for large-region soil characterization. Thus, development of rapid and accurate methods for characterizing soils are needed to map soil properties for precision agriculture applications, improve regional and global soil carbon (C) stock and flux estimates and efficiently map sub-surface metal contamination, among others. The greatest gains for efficientmore » soil characterization will come from collecting soil data in situ, thus minimizing soil sample transportation, processing, and lab-based measurement costs. Visible and near-infrared diffuse reflectance spectroscopy (VisNIR) and laser-induced breakdown spectroscopy (LIBS) are two complementary, yet fundamentally different spectroscopic techniques that have the potential to meet this need. These sensors have the potential to be mounted on a soil penetrometer and deployed for rapid soil profile characterization at field and landscape scales. Details of sensor interaction, efficient data management, and appropriate statistical analysis techniques for model calibrations are first needed. In situ or on-the-go VisNIR spectroscopy has been proposed as a rapid and inexpensive tool for intensively mapping soil texture and organic carbon (SOC). While lab-based VisNIR has been established as a viable technique for estimating various soil properties, few experiments have compared the predictive accuracy of on-the-go and lab-based VisNIR. Eight north central Montana wheat fields were intensively interrogated using on-the-go and lab-based VisNIR. Lab-based spectral data consistently provided more accurate predictions than on-the-go data. However, neither in situ nor lab-based spectroscopy yielded even semi-quantitative SOC predictions. There was little SOC variability to explain across the eight fields, and on-the-go VisNIR was not able to capture the subtle SOC variability in these Montana soils. With more variation in soil clay content compared to SOC, both lab and on-the-go VisNIR showed better explanatory power. There are several potential explanations for poor on-the-go predictive accuracy: soil heterogeneity, field moisture, consistent sample presentation, and a difference between the spatial support of on-the-go measurements and soil samples collected for laboratory analyses. Though the current configuration of a commercially available on-the-go VisNIR system allows for rapid field scanning, on-the-go soil processing (i.e. drying, crushing, and sieving) could improve soil carbon predictions. Laser-induced breakdown spectroscopy (LIBS) is an emerging elemental analysis technology with the potential to provide rapid, accurate and precise analysis of soil constituents, such as carbon, in situ across landscapes. The research team evaluated the accuracy of LIBS for measuring soil profile carbon in field-moist, intact soil cores simulating conditions that might be encountered by a probe-mounted LIBS instrument measuring soil profile carbon in situ. Over the course of three experiments, more than120 intact soil cores from eight north central Montana wheat fields and the Washington State University (WSU) Cook Agronomy Farm near Pullman, WA were interrogated with LIBS for rapid total carbon (TC), inorganic carbon (IC), and SOC determination. Partial least squares regression models were derived and independently validated at field- and regional scales. Researchers obtained the best LIBS validation predictions for IC followed by TC and SOC. Laser-induced breakdown spectroscopy is fundamentally an elemental analysis technique, yet LIBS PLS2 models appeared to discriminate IC from TC. Regression coefficients from initial models suggested a reliance upon stoichiometric relationships between carbon (247.8 nm) and other elements related to total and inorganic carbon in the soil matrix [Ca (210.2 nm, 211.3 nm, and 220.9 nm), Mg (279.55-280.4 nm, 285.26 nm), and Si (251.6 nm, 288.1 nm)]. Expanding the LIBS spectral range to capture emissions from a broader range of elements related to soil organic matter was explored using two spectrometer systems to improve SOC predictions. Results for increasing the spectral range of LIBS to the full 200-800 nm found modest gains in prediction accuracy for IC, but no gains for predicting TC or SOC. Poor SOC predictions are likely a function of (1) the lack of a consistent/definable molecular composition of SOC, (2) relatively little variation in SOC across field sites, and (3) inorganic carbon constituting the primary form of soil carbon, particularly for Montana soils.« less
Measuring the Impact of Programs that Challenge the Public Stigma of Mental Illness
Corrigan, Patrick W.; Shapiro, Jenessa R.
2010-01-01
Public stigma robs people with mental illnesses from rightful opportunities related to work and other important life goals. Advocates have developed anti-stigma programs meant to address the prejudice and discrimination associated with these conditions. Evidence is now needed to make sense of program impact; this paper looks at measurement issues related to stigma change. Community based participatory research is central to this research and includes the involvement of a diverse collection of stakeholders in all phases of evaluation. Investigators should be cautious about measures vis-à-vis social desirability effects and should directed by social validity of targeted audiences. Conceptual domains with some research support that correspond with assessments include behavior, penetration, psychological perspective, knowledge, and physiological/information processes. These issues are summarized as ten recommendations for evaluation of anti-stigma programs. PMID:20674114
Negotiating community engagement and science in the federal environmental public health sector.
Little, Peter C
2009-06-01
In this case study, I use ethnographic data to explore how community engagement and science are deployed at the U.S. Agency for Toxic Substances and Disease Registry, with the goal of formulating an understanding of the personalized meanings of science-community relations for key environmental public health experts. In focus is the cultural discourse circulating in the agency that exposes the real concerns, beliefs, and attitudes of these scientists and experts vis-&-vis their community engagement experiences. Finally, I propose that critical attention to the place of power relations, knowledge politics, and environmental justice are fundamental to studies of toxic contamination where commitments to community engagement and quality science are joined to form a positive research goal and where attempts are made to improve the conditions of quality environmental public health service.
Moran, Mika R; Eizenberg, Efrat; Plaut, Pnina
2017-06-06
The literature on environmental walkability to date has mainly focused on walking and related health outcomes. While previous studies suggest associations between walking and spatial knowledge, the associations between environmental walkability and spatial knowledge is yet to be explored. The current study addresses this lacuna in research by exploring children's mental representations of their home-school (h-s) route, vis.
The Autonomous Student: A Footnote.
ERIC Educational Resources Information Center
Long, Jancis
1987-01-01
An argument that rationality is a learned behavior, rather than a natural facility, is developed vis-a-vis certain educational theories. The difficulties students face in maintaining a rational stance in an autonomous classroom are also discussed. (JL)
NASA Astrophysics Data System (ADS)
Balzarolo, M.; Vescovo, L.; Hammerle, A.; Gianelle, D.; Papale, D.; Tomelleri, E.; Wohlfahrt, G.
2015-05-01
In this paper we explore the skill of hyperspectral reflectance measurements and vegetation indices (VIs) derived from these in estimating carbon dioxide (CO2) fluxes of grasslands. Hyperspectral reflectance data, CO2 fluxes and biophysical parameters were measured at three grassland sites located in European mountain regions using standardized protocols. The relationships between CO2 fluxes, ecophysiological variables, traditional VIs and VIs derived using all two-band combinations of wavelengths available from the whole hyperspectral data space were analysed. We found that VIs derived from hyperspectral data generally explained a large fraction of the variability in the investigated dependent variables but differed in their ability to estimate midday and daily average CO2 fluxes and various derived ecophysiological parameters. Relationships between VIs and CO2 fluxes and ecophysiological parameters were site-specific, likely due to differences in soils, vegetation parameters and environmental conditions. Chlorophyll and water-content-related VIs explained the largest fraction of variability in most of the dependent variables. Band selection based on a combination of a genetic algorithm with random forests (GA-rF) confirmed that it is difficult to select a universal band region suitable across the investigated ecosystems. Our findings have major implications for upscaling terrestrial CO2 fluxes to larger regions and for remote- and proximal-sensing sampling and analysis strategies and call for more cross-site synthesis studies linking ground-based spectral reflectance with ecosystem-scale CO2 fluxes.
MeetingVis: Visual Narratives to Assist in Recalling Meeting Context and Content.
Shi, Yang; Bryan, Chris; Bhamidipati, Sridatt; Zhao, Ying; Zhang, Yaoxue; Ma, Kwan-Liu
2018-06-01
In team-based workplaces, reviewing and reflecting on the content from a previously held meeting can lead to better planning and preparation. However, ineffective meeting summaries can impair this process, especially when participants have difficulty remembering what was said and what its context was. To assist with this process, we introduce MeetingVis, a visual narrative-based approach to meeting summarization. MeetingVis is composed of two primary components: (1) a data pipeline that processes the spoken audio from a group discussion, and (2) a visual-based interface that efficiently displays the summarized content. To design MeetingVis, we create a taxonomy of relevant meeting data points, identifying salient elements to promote recall and reflection. These are mapped to an augmented storyline visualization, which combines the display of participant activities, topic evolutions, and task assignments. For evaluation, we conduct a qualitative user study with five groups. Feedback from the study indicates that MeetingVis effectively triggers the recall of subtle details from prior meetings: all study participants were able to remember new details, points, and tasks compared to an unaided, memory-only baseline. This visual-based approaches can also potentially enhance the productivity of both individuals and the whole team.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Choo, Jaegul; Kim, Hannah; Clarkson, Edward
In this paper, we present an interactive visual information retrieval and recommendation system, called VisIRR, for large-scale document discovery. VisIRR effectively combines the paradigms of (1) a passive pull through query processes for retrieval and (2) an active push that recommends items of potential interest to users based on their preferences. Equipped with an efficient dynamic query interface against a large-scale corpus, VisIRR organizes the retrieved documents into high-level topics and visualizes them in a 2D space, representing the relationships among the topics along with their keyword summary. In addition, based on interactive personalized preference feedback with regard to documents,more » VisIRR provides document recommendations from the entire corpus, which are beyond the retrieved sets. Such recommended documents are visualized in the same space as the retrieved documents, so that users can seamlessly analyze both existing and newly recommended ones. This article presents novel computational methods, which make these integrated representations and fast interactions possible for a large-scale document corpus. We illustrate how the system works by providing detailed usage scenarios. Finally, we present preliminary user study results for evaluating the effectiveness of the system.« less
Choo, Jaegul; Kim, Hannah; Clarkson, Edward; ...
2018-01-31
In this paper, we present an interactive visual information retrieval and recommendation system, called VisIRR, for large-scale document discovery. VisIRR effectively combines the paradigms of (1) a passive pull through query processes for retrieval and (2) an active push that recommends items of potential interest to users based on their preferences. Equipped with an efficient dynamic query interface against a large-scale corpus, VisIRR organizes the retrieved documents into high-level topics and visualizes them in a 2D space, representing the relationships among the topics along with their keyword summary. In addition, based on interactive personalized preference feedback with regard to documents,more » VisIRR provides document recommendations from the entire corpus, which are beyond the retrieved sets. Such recommended documents are visualized in the same space as the retrieved documents, so that users can seamlessly analyze both existing and newly recommended ones. This article presents novel computational methods, which make these integrated representations and fast interactions possible for a large-scale document corpus. We illustrate how the system works by providing detailed usage scenarios. Finally, we present preliminary user study results for evaluating the effectiveness of the system.« less
Gallo, Edmundo; Setti, Andréia Faraoni Freitas
2014-11-01
The post-2015 development agenda highlights the incorporation of sustainability in approaches developed and/or applied to distinct fields of knowledge and action and the demonstration of the effectiveness of experiences of sustainable and healthy territories. This process results from the confrontation of different viewpoints which seek to address social production vis-à-vis their project, with the possibility of updating the hegemonic mode of production and consumption or the emergence of counter-hegemonic rationales. Health, as one of the SDGs, has the challenge of imposing an intersectorial agenda that addresses its social determinants, in a process of participative governance able to build a hierarchy of priorities based on the needs of the territory and build techno-political solutions based on the ecology of knowledge, constituting a strategic-situational and communicative management process. The consistency in formulation of the agenda and potential challenges to its implementation are analyzed, considering its intersectoriality, its strategic governance and management, and especially an assessment of its effectiveness. Moreover, it tests the evaluative tools used and their ability to analyze the consistency in the formulation of the agenda.
Effect of titanium on the structural and optical property of NiO nano powders
NASA Astrophysics Data System (ADS)
Amin, Ruhul; Mishra, Prashant; Khatun, Nasima; Ayaz, Saniya; Srivastava, Tulika; Sen, Somaditya
2018-05-01
Nickel Oxide (NiO) and Ti doped NiO nanoparticles were prepared by sol-gel auto combustion method. Powder x-ray diffraction (PXRD) structural studies revealed face centered cubic (FCC) structure of the NiO nanopowders. The crystallite size decreased with Ti incorporation. UV-Vis spectroscopy carried out in diffused reflectance mode revealed decrease in band gap with increment in Urbach energy with doping.
NASA Astrophysics Data System (ADS)
Gopinath, K.; Kumaraguru, S.; Bhakyaraj, K.; Thirumal, S.; Arumugam, A.
2016-04-01
Driven by the demand of pure TiO2, Au and Pt doped TiO2 NPs were successfully synthesized using Terminalia arjuna bark extract. The eco-friendly synthesized NPs were characterized by UV-Vis-DRS, ATR-FT-IR, PL, XRD, Raman, SEM with EDX and TEM analysis. The synthesized NPs were investigation for dye sensitized solar cell applications. UV-Vis-Diffused Reflectance Spectra clearly showed that the expected TiO2 inter band absorption below 306 nm, incorporation of gold shows surface plasma resonant (SPR) near 555 nm and platinum incorporated TiO2 NPs shows absorbance at 460 nm. The energy conversion efficiency for Au doped TiO2 NPs when compared to pure and Pt doped TiO2 NPs. In addition to that, Au noble metal present TiO2 matrix and an improve open-circuit voltage (Voc) of DSSC. Synthesized NPs was evaluated into antibacterial and antifungal activities by disk diffusion method. It is observed that NPs have not shown any activities in all tested bacterial and fungal strains. In this eco-friendly synthesis method to provide non toxic and environmental friendly nanomaterials can be used for solar energy device application.
Didukh, Natalia O; Zatsikha, Yuriy V; Rohde, Gregory T; Blesener, Tanner S; Yakubovskyi, Viktor P; Kovtun, Yuriy P; Nemykin, Victor N
2016-10-04
Diferrocene-containing meso-cyano-BODIPY (4) was prepared by the direct cyanation/oxidation reaction of symmetric BODIPY 1 followed by Knoevenagel condensation with ferrocenealdehyde. Ferrocene-containing BODIPY 4 was characterized by a variety of spectroscopic, electrochemical, and theoretical methods and its UV-Vis-NIR spectrum has a striking similarity with a UV-Vis-NIR spectrum of the previously reported magnesium 2(3),7(8),12(13),17(18)-tetracyano-3(2),8(7),13(12),18(17)-tetraferrocenyl-5,10,15,20-tetraazaporphyrin.
Visible-light optical coherence tomography: a review
NASA Astrophysics Data System (ADS)
Shu, Xiao; Beckmann, Lisa; Zhang, Hao F.
2017-12-01
Visible-light optical coherence tomography (vis-OCT) is an emerging imaging modality, providing new capabilities in both anatomical and functional imaging of biological tissue. It relies on visible light illumination, whereas most commercial and investigational OCTs use near-infrared light. As a result, vis-OCT requires different considerations in engineering design and implementation but brings unique potential benefits to both fundamental research and clinical care of several diseases. Here, we intend to provide a summary of the development of vis-OCT and its demonstrated applications. We also provide perspectives on future technology improvement and applications.
Choi, Ra-Young; Lee, Chang-Hee; Jun, Chul-Ho
2018-05-18
A methallylsilane coupling reagent, containing both a N-hydroxysuccinimidyl(NHS)-ester group and a UV/vis absorbing azobenzene linker undergoes acid-catalyzed immobilization on silica. Analysis of the UV/vis absorption band associated with the azobenzene group in the adduct enables facile quantitative determination of the extent of loading of the NHS groups. Reaction of NHS-groups on the silica surface with amine groups of GOx and rhodamine can be employed to generate enzyme or dye-immobilized silica for quantitative analysis.
Mohamed, Gehad G; El-Gamel, Nadia E A
2004-11-01
The ternary piroxicam (Pir; 4-hydroxy-2-methyl-N-(2-pyridyl)-2H-1,2-benzothiazine-3-carboxamide 1,1-dioxide) complexes of Fe(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) with various amino acids (AA) such as glycine (Gly) or DL-phenylalanine (PhA) were prepared and characterized by elemental analyses, molar conductance, IR, UV-Vis, magnetic moment, diffuse reflectance and X-ray powder diffraction. The UV-Vis spectra of Pir and the effect of metal chelation on the different interligand transitions are discussed in detailed manner. IR and UV-Vis spectra confirm that Pir behaves as a neutral bidentate ligand coordinated to the metal ions via the pyridine-N and carbonyl group of the amide moiety. Gly molecule acted as a uninegatively monodentate ligand and coordinate to the metal ions through its carboxylic group, in addition PhA acted as a uninegatively bidentate ligand and coordinate to the metal ions through its carboxylic and amino groups. All the chelates have octahedral geometrical structures while Cu(II)- and Zn(II)-ternary chelates with PhA have square planar geometrical structures. The molar conductance data reveal that most of these chelates are non electrolytes, while Fe(III)-Pir-Gly, Co(II)-, Ni(II)-, Cu(II)- and Zn(II)-Pir-PhA chelates were 1:1 electrolytes. X-ray powder diffraction is used as a new tool to estimate the crystallinity of chelates as well as to elucidate their geometrical structures.
NASA Astrophysics Data System (ADS)
Mohamed, Gehad G.; El-Gamel, Nadia E. A.
2004-11-01
The ternary piroxicam (Pir; 4-hydroxy-2-methyl- N-(2-pyridyl)-2H-1,2-benzothiazine-3-carboxamide 1,1-dioxide) complexes of Fe(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) with various amino acids (AA) such as glycine (Gly) or DL-phenylalanine (PhA) were prepared and characterized by elemental analyses, molar conductance, IR, UV-Vis, magnetic moment, diffuse reflectance and X-ray powder diffraction. The UV-Vis spectra of Pir and the effect of metal chelation on the different interligand transitions are discussed in detailed manner. IR and UV-Vis spectra confirm that Pir behaves as a neutral bidentate ligand coordinated to the metal ions via the pyridine- N and carbonyl group of the amide moiety. Gly molecule acted as a uninegatively monodentate ligand and coordinate to the metal ions through its carboxylic group, in addition PhA acted as a uninegatively bidentate ligand and coordinate to the metal ions through its carboxylic and amino groups. All the chelates have octahedral geometrical structures while Cu(II)- and Zn(II)-ternary chelates with PhA have square planar geometrical structures. The molar conductance data reveal that most of these chelates are non electrolytes, while Fe(III)-Pir-Gly, Co(II)-, Ni(II)-, Cu(II)- and Zn(II)-Pir-PhA cheletes were 1:1 electrolytes. X-ray powder diffraction is used as a new tool to estimate the crystallinity of chelates as well as to elucidate their geometrical structures.
Synthesis of Cu/CuO nanoparticles in mesoporous material by solid state reaction
NASA Astrophysics Data System (ADS)
Sohrabnezhad, Sh.; Valipour, A.
2013-10-01
The Mobil Composition of Matter No. 41 (MCM-41) containing 1.0 and 5.0 wt.% of Cu was synthesized under solid state reaction. The calcinations of samples were done at two different temperatures, 500 and 300 °C. X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS), Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM) were used for samples characterization. Powder X-ray diffraction showed that when Cu(CH3COO)2 content is about 1.0 wt.% in Cu/MCM-41, the guest CuO-NPs and copper ions is formed on the silica channel wall, and more exists in the crystalline state. When Cu(CH3COO)2 content exceeds this value (5.0 wt.%), CuO nanoparticles and Cu2+ ions can be observed in low crystalline state. From the diffuse reflectance spectra it was confirmed that 5 wt.% Cu/MCM-41 sample calcined at 500 °C show plasmon resonance band due to Cu nanoparticles in the range between 500 and 600 nm and small copper clusters Cun in 450 nm. It also shows that some of the Cu2+ ions are present octahedrally in extraframework position in all samples. Both fourier transform infrared and diffuse reflectance spectra indicate that some of Cu2+ ions are tetrahedrally within the framework position in 1 wt.% Cu/MCM-41 samples. TEM images indicated that nanoparticles size of CuO is in range of 30-40 nm.
Jerković, Igor; Kranjac, Marina; Marijanović, Zvonimir; Zekić, Marina; Radonić, Ani; Tuberoso, Carlo Ignazio Giovanni
2016-03-21
The samples of Satureja subspicata Vis. honey were confirmed to be unifloral by melissopalynological analysis with the characteristic pollen share from 36% to 71%. Bioprospecting of the samples was performed by HPLC-DAD, GC-FID/MS, and UV/VIS. Prephenate derivatives were shown to be dominant by the HPLC-DAD analysis, particularly phenylalanine (167.8 mg/kg) and methyl syringate (MSYR, 114.1 mg/kg), followed by tyrosine and benzoic acid. Higher amounts of MSYR (3-4 times) can be pointed out for distinguishing S. subspicata Vis. honey from other Satureja spp. honey types. GC-FID/MS analysis of ultrasonic solvent extracts of the samples revealed MSYR (46.68%, solvent pentane/Et2O 1:2 (v/v); 52.98%, solvent CH2Cl2) and minor abundance of other volatile prephenate derivatives, as well as higher aliphatic compounds characteristic of the comb environment. Two combined extracts (according to the solvents) of all samples were evaluated for their antioxidant properties by FRAP and DPPH assay; the combined extracts demonstrated higher activity (at lower concentrations) in comparison with the average honey sample. UV/VIS analysis of the samples was applied for determination of CIE Lab colour coordinates, total phenolics (425.38 mg GAE/kg), and antioxidant properties (4.26 mmol Fe(2+)/kg (FRAP assay) and 0.8 mmol TEAC/kg (DDPH assay)).
Visual analysis of large heterogeneous social networks by semantic and structural abstraction.
Shen, Zeqian; Ma, Kwan-Liu; Eliassi-Rad, Tina
2006-01-01
Social network analysis is an active area of study beyond sociology. It uncovers the invisible relationships between actors in a network and provides understanding of social processes and behaviors. It has become an important technique in a variety of application areas such as the Web, organizational studies, and homeland security. This paper presents a visual analytics tool, OntoVis, for understanding large, heterogeneous social networks, in which nodes and links could represent different concepts and relations, respectively. These concepts and relations are related through an ontology (also known as a schema). OntoVis is named such because it uses information in the ontology associated with a social network to semantically prune a large, heterogeneous network. In addition to semantic abstraction, OntoVis also allows users to do structural abstraction and importance filtering to make large networks manageable and to facilitate analytic reasoning. All these unique capabilities of OntoVis are illustrated with several case studies.
Ruan, Yudi; Wu, Lie; Jiang, Xiue
2016-05-23
Water-soluble nitrogen-doped carbon nanoparticles (N-CNPs) prepared by the one-step hydrothermal treatment of uric acid were found to show ratiometric changes in their UV-vis spectra due to Hg(2+)-mediated self-assembly. For the first time, such a property was developed into a UV-vis optical sensor for detecting Hg(2+) in aqueous solutions with high sensitively and selectively (detection limit = 1.4 nM). More importantly, this novel sensor exhibits a higher linear sensitivity over a wider concentration range compared with the fluorescence sensor based on the same N-CNPs. This work opens an exciting new avenue to explore the use of carbon nanoparticles in constructing UV-vis optical sensors for the detection of metal ions and the use of carbon nanoparticles as a new building block to self-assemble into superlattices.
2015-11-20
Today's VIS image shows a number of unnamed channels located on the northeastern margin of Terra Sabaea. Orbit Number: 61049 Latitude: 33.5036 Longitude: 58.6967 Instrument: VIS Captured: 2015-09-18 12:54 http://photojournal.jpl.nasa.gov/catalog/PIA20097
Fonteneau, Yannick; Viard, Jérôme
The concept of mechanical work is inherited from the concepts of potentia absoluta and men's work, both implemented in the section IX of Daniel Bernoulli's Hydrodynamica in 1738. Nonetheless, Bernoulli did not confuse these two entities: he defined a link from gender to species between the former, which is general, and the latter, which is organic. In addition, Bernoulli clearly distinguished between vis viva and potentia absoluta (or work). Their reciprocal conversions are rarely mentioned explicitly in this book, except once, in the section X of his work, from vis viva to work, and subordinated to the mediation of a machine, in a driving forces substitution problem. His attitude evolved significantly in a text in 1753, in which work and vis viva were unambiguously connected, while the concept of potentia absoluta was reduced to that of human work, and the expression itself was abandoned. It was then accepted that work can be converted into vis viva, but the opposite is true in only one case, the intra-organic one. It is the concept of fatigue, seen as an expenditure of animal spirits themselves conceived of as little tensed springs releasing vis viva, that allowed the conversion, never quantified and listed simply as a model, from vis viva to work. Thus, work may have ultimately appeared as a transitional state between two kinds of vis viva, of which the first is non-quantifiable. At the same time, the natural elements were discredited from any hint of profitable production. Only men and animals were able to work in the strict sense of the word. Nature, left to itself, does not work, according to Bernoulli. In spite of his wish to bring together rational mechanics and practical mechanics, one perceived in the work of Bernoulli the subsistence of a rarely crossed disjunction between practical and theoretical fields.
Health Information in Hmong (Hmoob)
... Expand Section Salmonella Infections Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - Hmoob (Hmong) ...
NASA Astrophysics Data System (ADS)
Mahalingam, S.; Abdullah, H.; Ashaari, I.; Shaari, S.; Muchtar, A.
2016-02-01
This study focuses on the influence of an acid treatment process of single-walled carbon nanotubes (SWCNTs) in In2O3-based dye-sensitized solar cells (DSSCs). Pure In2O3, In2O3-SWCNTs with acid treatment and In2O3-SWCNTs without acid treatment were prepared using the sol-gel method via a spin coating technique annealed at 450 °C. The optical, morphology and electrical properties of the photoanodes were characterized by means of UV-Vis analysis, atomic force microscopy and field-emission scanning electron microscopy, and J-V curve measurements, respectively. The optical band gap obtained through UV-Vis analysis showed that the acid treatment process modified the band gap of the photoanode, which enhances the V oc of the DSSCs. In addition, In2O3-SWCNTs with acid treatment possess a porous structure that improves the power conversion efficiency (PCE) of the DSSCs. In addition, the diameter of acid-treated SWCNTs was reduced compared to pristine SWCNTs. In2O3-SWCNTs with acid treatment exhibited the highest PCE of 1.40% with J sc of 7.6 mA cm-2, V oc of 0.51 V, and fill factor of 0.36. The increment in V oc is due to the higher band gap obtained through the UV-Vis absorption spectrum. Moreover, In2O3-SWCNTs with acid treatment has a higher electron lifetime with a higher effective diffusion coefficient that slows down the recombination rate and speeds up the electron transport process.
A Real-Time Ultraviolet Radiation Imaging System Using an Organic Photoconductive Image Sensor†
Okino, Toru; Yamahira, Seiji; Yamada, Shota; Hirose, Yutaka; Odagawa, Akihiro; Kato, Yoshihisa; Tanaka, Tsuyoshi
2018-01-01
We have developed a real time ultraviolet (UV) imaging system that can visualize both invisible UV light and a visible (VIS) background scene in an outdoor environment. As a UV/VIS image sensor, an organic photoconductive film (OPF) imager is employed. The OPF has an intrinsically higher sensitivity in the UV wavelength region than those of conventional consumer Complementary Metal Oxide Semiconductor (CMOS) image sensors (CIS) or Charge Coupled Devices (CCD). As particular examples, imaging of hydrogen flame and of corona discharge is demonstrated. UV images overlapped on background scenes are simply made by on-board background subtraction. The system is capable of imaging weaker UV signals by four orders of magnitude than that of VIS background. It is applicable not only to future hydrogen supply stations but also to other UV/VIS monitor systems requiring UV sensitivity under strong visible radiation environment such as power supply substations. PMID:29361742
DSM-V from the perspective of the DSM-IV experience.
Walsh, B Timothy
2007-11-01
This article provides a brief overview of the development of the diagnostic criteria for eating disorders in DSM-IV. The process by which DSM-IV was developed is reviewed, including perspectives on what constitutes diagnostic validity and clinical utility, and their importance in assessing proposed changes in diagnostic criteria. The question of whether alterations in diagnostic criteria would clearly improve clinical utility was a major consideration in the DSM-IV process. Because of concerns that changes in diagnostic criteria would be disruptive and might entail loss of established knowledge, the DSM-IV Task Force assumed a generally conservative stance vis-à-vis change. The process of developing DSM-V is just beginning, and it is far from clear what alterations in diagnostic criteria for eating disorders will occur. However, the evolution of DSM-IV may provide a useful perspective on the development of DSM-V. (c) 2007 by Wiley Periodicals, Inc.
Evaluating Leaf and Canopy Reflectance of Stressed Rice Plants to Monitor Arsenic Contamination.
Bandaru, Varaprasad; Daughtry, Craig S; Codling, Eton E; Hansen, David J; White-Hansen, Susan; Green, Carrie E
2016-06-18
Arsenic contamination is a serious problem in rice cultivated soils of many developing countries. Hence, it is critical to monitor and control arsenic uptake in rice plants to avoid adverse effects on human health. This study evaluated the feasibility of using reflectance spectroscopy to monitor arsenic in rice plants. Four arsenic levels were induced in hydroponically grown rice plants with application of 0, 5, 10 and 20 µmol·L(-1) sodium arsenate. Reflectance spectra of upper fully expanded leaves were acquired over visible and infrared (NIR) wavelengths. Additionally, canopy reflectance for the four arsenic levels was simulated using SAIL (Scattering by Arbitrarily Inclined Leaves) model for various soil moisture conditions and leaf area indices (LAI). Further, sensitivity of various vegetative indices (VIs) to arsenic levels was assessed. Results suggest that plants accumulate high arsenic amounts causing plant stress and changes in reflectance characteristics. All leaf spectra based VIs related strongly with arsenic with coefficient of determination (r²) greater than 0.6 while at canopy scale, background reflectance and LAI confounded with spectral signals of arsenic affecting the VIs' performance. Among studied VIs, combined index, transformed chlorophyll absorption reflectance index (TCARI)/optimized soil adjusted vegetation index (OSAVI) exhibited higher sensitivity to arsenic levels and better resistance to soil backgrounds and LAI followed by red edge based VIs (modified chlorophyll absorption reflectance index (MCARI) and TCARI) suggesting that these VIs could prove to be valuable aids for monitoring arsenic in rice fields.
Nemeth, Gabor; Szalai, Eszter; Hassan, Ziad; Lipecz, Agnes; Flasko, Zsuzsa; Modis, Laszlo
2017-01-01
AIM To analyze the correlations between ocular biomechanical and biometric data of the eye, measured by Scheimpflug-based devices on healthy subjects. METHODS Three consecutive measurements were carried out using the corneal visualization Scheimpflug technology (CorVis ST) device on healthy eyes and the 10 device-specific parameters were recorded. Pentacam HR-derived parameters (corneal curvature radii on the anterior and posterior surfaces; apical pachymetry; corneal volume; corneal aberration data; depth, volume and angle of the anterior chamber) and axial length (AL) from IOLMaster were correlated with the 10 specific CorVis ST parameters. RESULTS Measurements were conducted in 43 eyes of 43 volunteers (age 61.24±15.72y). The 10 specific CorVis ST data showed significant relationships with corneal curvature radii both on the anterior and posterior surface, pachymetric data, root mean square (RMS) data of lower-order aberrations, and posterior RMS of higher-order aberrations and spherical aberration of the posterior cornea. Anterior chamber depth showed a significant relationship, but there were no significant correlations between corneal volume, anterior chamber volume, mean chamber angle or AL and the 10 specific CorVis ST parameters. CONCLUSIONS CorVis ST-generated parameters are influenced by corneal curvature radii, some corneal RMS data, but corneal volume, anterior chamber volume, chamber angle and AL have no correlation with the biomechanical parameters. The parameters measured by CorVis ST seem to refer mostly to corneal properties of the eye. PMID:28251079
Nemeth, Gabor; Szalai, Eszter; Hassan, Ziad; Lipecz, Agnes; Flasko, Zsuzsa; Modis, Laszlo
2017-01-01
To analyze the correlations between ocular biomechanical and biometric data of the eye, measured by Scheimpflug-based devices on healthy subjects. Three consecutive measurements were carried out using the corneal visualization Scheimpflug technology (CorVis ST) device on healthy eyes and the 10 device-specific parameters were recorded. Pentacam HR-derived parameters (corneal curvature radii on the anterior and posterior surfaces; apical pachymetry; corneal volume; corneal aberration data; depth, volume and angle of the anterior chamber) and axial length (AL) from IOLMaster were correlated with the 10 specific CorVis ST parameters. Measurements were conducted in 43 eyes of 43 volunteers (age 61.24±15.72y). The 10 specific CorVis ST data showed significant relationships with corneal curvature radii both on the anterior and posterior surface, pachymetric data, root mean square (RMS) data of lower-order aberrations, and posterior RMS of higher-order aberrations and spherical aberration of the posterior cornea. Anterior chamber depth showed a significant relationship, but there were no significant correlations between corneal volume, anterior chamber volume, mean chamber angle or AL and the 10 specific CorVis ST parameters. CorVis ST-generated parameters are influenced by corneal curvature radii, some corneal RMS data, but corneal volume, anterior chamber volume, chamber angle and AL have no correlation with the biomechanical parameters. The parameters measured by CorVis ST seem to refer mostly to corneal properties of the eye.
VisGets: coordinated visualizations for web-based information exploration and discovery.
Dörk, Marian; Carpendale, Sheelagh; Collins, Christopher; Williamson, Carey
2008-01-01
In common Web-based search interfaces, it can be difficult to formulate queries that simultaneously combine temporal, spatial, and topical data filters. We investigate how coordinated visualizations can enhance search and exploration of information on the World Wide Web by easing the formulation of these types of queries. Drawing from visual information seeking and exploratory search, we introduce VisGets--interactive query visualizations of Web-based information that operate with online information within a Web browser. VisGets provide the information seeker with visual overviews of Web resources and offer a way to visually filter the data. Our goal is to facilitate the construction of dynamic search queries that combine filters from more than one data dimension. We present a prototype information exploration system featuring three linked VisGets (temporal, spatial, and topical), and used it to visually explore news items from online RSS feeds.
Health Information in Tagalog (Wikang Tagalog)
... Expand Section Salmonella Infections Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - Wikang Tagalog ( ...
Importance of Vibronic Effects in the UV-Vis Spectrum of the 7,7,8,8-Tetracyanoquinodimethane Anion.
Tapavicza, Enrico; Furche, Filipp; Sundholm, Dage
2016-10-11
We present a computational method for simulating vibronic absorption spectra in the ultraviolet-visible (UV-vis) range and apply it to the 7,7,8,8-tetracyanoquinodimethane anion (TCNQ - ), which has been used as a ligand in black absorbers. Gaussian broadening of vertical electronic excitation energies of TCNQ - from linear-response time-dependent density functional theory produces only one band, which is qualitatively incorrect. Thus, the harmonic vibrational modes of the two lowest doublet states were computed, and the vibronic UV-vis spectrum was simulated using the displaced harmonic oscillator approximation, the frequency-shifted harmonic oscillator approximation, and the full Duschinsky formalism. An efficient real-time generating function method was implemented to avoid the exponential complexity of conventional Franck-Condon approaches to vibronic spectra. The obtained UV-vis spectra for TCNQ - agree well with experiment; the Duschinsky rotation is found to have only a minor effect on the spectrum. Born-Oppenheimer molecular dynamics simulations combined with calculations of the electronic excitation energies for a large number of molecular structures were also used for simulating the UV-vis spectrum. The Born-Oppenheimer molecular dynamics simulations yield a broadening of the energetically lowest peak in the absorption spectrum, but additional vibrational bands present in the experimental and simulated quantum harmonic oscillator spectra are not observed in the molecular dynamics simulations. Our results underline the importance of vibronic effects for the UV-vis spectrum of TCNQ - , and they establish an efficient method for obtaining vibronic spectra using a combination of linear-response time-dependent density functional theory and a real-time generating function approach.
NASA Astrophysics Data System (ADS)
Subbaraj, P.; Ramu, A.; Raman, N.; Dharmaraja, J.
2014-01-01
A novel bidentate Schiff base ligand has been synthesized using 2,4-dihydroxybenzophenone and aniline. Its mixed ligand complexes of MAB type [M = Mn(II), Co(II), Ni(II), Cu(II) and Zn(II); HA = Schiff base and B = 2-aminophenol/2-aminobenzoic acid] have been synthesized and characterized on the basis of spectral data UV-Vis, IR, 1H NMR, FAB-Mass, EPR, SEM and magnetic studies. All the complexes were soluble in DMF and DMSO. Elemental analysis and molar conductance values indicate that the complexes are non-electrolytes. HA binds with M(II) ions through azomethine and deprotonated phenolic group and B binds through the primary amine group and deprotonated phenolic/carboxylic groups. Using FAB-Mass the cleavage pattern of the ligand (HA) has been established. All the complexes adopt octahedral geometry around the metal ions. It has been confirmed with the help of UV-Vis, IR, 1H NMR and FAB-Mass spectral data. DNA binding activities of the complexes 1d and 2d are studied by UV-Vis spectroscopy and cleavage studies of Schiff base ligand and its complexes 1d and 2d have been by agarose gel electrophoresis method. In vitro biological activities of the free ligand (HA) and their metal complexes (1a-1e and 2a-2e) were screened against few bacteria, Escherichia coli, Staphylococcus saphyphiticus, Staphylococcus aureus, Pseudomonas aeruginosa and fungi Aspergillus niger, Enterobacter species, Candida albicans by well diffusion technique.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Okuno, T., E-mail: t093507@edu.imc.tut.ac.jp; Kawamura, G., E-mail: gokawamura@ee.tut.ac.jp; Muto, H., E-mail: muto@ee.tut.ac.jp
Mesoporous SiO{sub 2} templates deposited TiO{sub 2} nanocrystals are synthesized via a sol–gel route, and Au nanoparticles (NPs) are deposited in the tubular mesopores of the templates by a photodeposition method (Au/SiO{sub 2}–TiO{sub 2}). The photocatalytic characteristics of Au/SiO{sub 2}–TiO{sub 2} are discussed with the action spectra of photoreactions of 2-propanol and methylene blue. Photocatalytic activities of SiO{sub 2}–TiO{sub 2} under individual ultraviolet (UV) and visible (Vis) light illumination are enhanced by deposition of Au NPs. Furthermore, Au/SiO{sub 2}–TiO{sub 2} shows higher photocatalytic activities under simultaneous irradiation of UV and Vis light compared to the activity under individual UV andmore » Vis light irradiation. Since the photocatalytic activity under simultaneous irradiation is almost the same as the total activities under individual UV and Vis light irradiation, it is concluded that the electrons and the holes generated by lights of different wavelengths are efficiently used for photocatalysis without carrier recombination. - Graphical abstract: This graphic shows the possible charge behavior in Au/SiO{sub 2}–TiO{sub 2} under independent light irradiation of ultraviolet and visible light irradiation. Both reactions under independent UV and Vis light irradiation occurred in parallel when Au/SiO{sub 2}–TiO{sub 2} photocatalyst was illuminated UV and Vis light simultaneously, and then photocatalytic activity is improved by simultaneous irradiation. - Highlights: • Au nanoparticles were deposited in mesoporous SiO{sub 2}–TiO{sub 2} by a photodeposition method. • Photocatalytic activity under UV and Vis light was enhanced by deposition of Au. • Photocatalytic activity of Au/SiO{sub 2}–TiO{sub 2} was improved by simultaneous irradiation.« less
Relational caring: the use of the victim impact statement by sexually assaulted women.
Miller, Karen-Lee
2014-01-01
The victim impact statement (VIS) is a written account of harms experienced as a result of crime. This study investigates VIS use by sexually assaulted women through interviews with Canadian victims, victim services workers, and feminist advocates (N = 35). Findings suggest that victims use the VIS to express relational caring. Relational caring is an ethic of care that prioritizes others through privileging the harms experienced by others because of witnessing the sexual assault or coping with the victim's postassault sequelae, protecting future or hypothetical victims, and promoting the interests of intimate partner offenders. Relational caring challenges traditional conceptions of victim agency and VIS use for instrumental purposes, as well as the targets and temporalities of sexual assault harms that are detailed in the statement. Relational caring has unique implications for victims who are mothers, especially those abused as minors, and for intimate partners. Legal, therapeutic, and social service consequences are discussed.
The MPI-Mainz UV/VIS Spectral Atlas of Gaseous Molecules of Atmospheric Interest
NASA Astrophysics Data System (ADS)
Sander, Rolf; Keller-Rudek, Hannelore; Moortgat, Geert; Sörensen, Rüdiger
2014-05-01
Measurements from satellites can be used to obtain global concentration maps of atmospheric trace constituents. Critical parameters needed in the analysis of the satellite data are the absorption cross sections of the observed molecules. Here, we present the MPI-Mainz UV/VIS Spectral Atlas, which is a large collection of more than 5000 absorption cross section and quantum yield data files in the ultraviolet and visible (UV/VIS) wavelength region for gaseous molecules and radicals primarily of atmospheric interest. The data files contain results of individual measurements, covering research of almost a whole century. To compare and visualize the data sets, multicoloured graphical representations have been created. The Spectral Atlas is available on the internet at http://www.uv-vis-spectral-atlas-mainz.org. It has been completely overhauled and now appears with improved browse and search options, based on PostgreSQL, Django and Python database software. The web pages are continuously updated.
Razban, Rostam M; Gilson, Amy I; Durfee, Niamh; Strobelt, Hendrik; Dinkla, Kasper; Choi, Jeong-Mo; Pfister, Hanspeter; Shakhnovich, Eugene I
2018-05-08
Protein evolution spans time scales and its effects span the length of an organism. A web app named ProteomeVis is developed to provide a comprehensive view of protein evolution in the S. cerevisiae and E. coli proteomes. ProteomeVis interactively creates protein chain graphs, where edges between nodes represent structure and sequence similarities within user-defined ranges, to study the long time scale effects of protein structure evolution. The short time scale effects of protein sequence evolution are studied by sequence evolutionary rate (ER) correlation analyses with protein properties that span from the molecular to the organismal level. We demonstrate the utility and versatility of ProteomeVis by investigating the distribution of edges per node in organismal protein chain universe graphs (oPCUGs) and putative ER determinants. S. cerevisiae and E. coli oPCUGs are scale-free with scaling constants of 1.79 and 1.56, respectively. Both scaling constants can be explained by a previously reported theoretical model describing protein structure evolution (Dokholyan et al., 2002). Protein abundance most strongly correlates with ER among properties in ProteomeVis, with Spearman correlations of -0.49 (p-value<10-10) and -0.46 (p-value<10-10) for S. cerevisiae and E. coli, respectively. This result is consistent with previous reports that found protein expression to be the most important ER determinant (Zhang and Yang, 2015). ProteomeVis is freely accessible at http://proteomevis.chem.harvard.edu. Supplementary data are available at Bioinformatics. shakhnovich@chemistry.harvard.edu.
Saviello, Daniela; Trabace, Maddalena; Alyami, Abeer; Mirabile, Antonio; Giorgi, Rodorico; Baglioni, Piero; Iacopino, Daniela
2018-05-01
The development of protocols for the protection of the large patrimony of works of art created by felt tip pen media since the 1950's requires detailed knowledge of the main dyes constituting commercial ink mixtures. In this work Surface Enhanced Raman Scattering (SERS) and UV-vis spectroscopy were used for the first time for the systematic identification of dye composition in commercial felt tip pens. A large selection of pens comprising six colors of five different brands was analyzed. Intense SERS spectra were obtained for all colors, allowing identification of main dye constituents. Poinceau 4R and Eosin dyes were found to be the main constituents of red and pink colors; Rhodamine and Tartrazine were found in orange and yellow colors; Erioglaucine was found in green and blue colors. UV-vis analysis of the same inks was used to support SERS findings but also to unequivocally assign some uncertain dye identifications, especially for yellow and orange colors. The spectral data of all felt tip pens collected through this work were assembled in a database format. The data obtained through this systematic investigation constitute the basis for the assembly of larger reference databases that ultimately will support the development of conservation protocols for the long term preservation of modern art collections. Copyright © 2018 Elsevier B.V. All rights reserved.
Advanced methodology to determine plant stresses using in-situ spectral data
NASA Astrophysics Data System (ADS)
Polinova, Maria; Brook, Anna; Housh, Mashor
2017-04-01
Fluorescence method in remote sensing has long been a traditional method estimating plant state. Vegetation indices (VIs) are tool for assessment plants' state based on its spectral characteristics. During the last half-century, in this domain were developed many vegetation indices and even more modifications of these indices. Nowadays, visible range across electromagnetic waves allows assessing plants' health and calculating its physical parameters. One of the VI's capabilities is detecting stress in plants. This approach has application in different areas. For discerning external environment (unnatural) stress from features of plant's development most of VIs have border values for greenness and health. This is the reason for these methods to be superficial and insufficient detecting and estimating stresses on the early stages. This limits plays especial importance in agriculture. Late stress detection leads to irreversible damage in crops and yield loss. We propose new principle of VI analysis for determination unnatural stress on early stages. Novelty of this method is common consideration several VIs related to plant's pigmentation: chlorophyll, carotenoids and anthocyanins. We have tasted this method on two agriculture fields: tomatoes and cotton. The goal of study was to determinate water crop stress at its beginning. A single VI shows reactions on emergence growth stage, fruit producing and ripening phase. It was hard to isolate crops' reaction on water from reaction on growth changes. Nevertheless, we have noted that there is correlation between chlorophyll VIs and carotenoid VIs. The correlation strength was depended on stress type. Based on common VIs analysis we were able to identify dryness and over irrigation stress. In addition, we have determine reaction on fertilizers input. Common VIs analysis can improve existing fluorescence method of remote sensing monitoring. It can find application in areas where the early plant's stress detection is very impotent (e.g. agriculture). Another advantage of this method is identifying stress type. It can increase the role of spectral data for design making.
Strasser, Torsten; Peters, Tobias; Jägle, Herbert; Zrenner, Eberhart
2018-02-01
The ISCEV standards and recommendations for electrophysiological recordings in ophthalmology define a set of protocols with stimulus parameters, acquisition settings, and recording conditions, to unify the data and enable comparability of results across centers. Up to now, however, there are no standards to define the storage and exchange of such electrophysiological recordings. The aim of this study was to develop an open standard data format for the exchange and storage of visual electrophysiological data (ElVisML). We first surveyed existing data formats for biomedical signals and examined their suitability for electrophysiological data in ophthalmology. We then compared the suitability of text-based and binary formats, as well as encoding in Extensible Markup Language (XML) and character/comma-separated values. The results of the methodological consideration led to the development of ElVisML with an XML-encoded text-based format. This allows referential integrity, extensibility, the storing of accompanying units, as well as ensuring confidentiality and integrity of the data. A visualization of ElVisML documents (ElVisWeb) has additionally been developed, which facilitates the exchange of recordings on mailing lists and allows open access to data along with published articles. The open data format ElVisML ensures the quality, validity, and integrity of electrophysiological data transmission and storage as well as providing manufacturer-independent access and long-term archiving in a future-proof format. Standardization of the format of such neurophysiology data would promote the development of new techniques and open software for the use of neurophysiological data in both clinic and research.
NASA Astrophysics Data System (ADS)
Wanag, Agnieszka; Kusiak-Nejman, Ewelina; Kowalczyk, Łukasz; Kapica-Kozar, Joanna; Ohtani, Bunsho; Morawski, Antoni W.
2018-04-01
In this paper titanium dioxide carbon modification with benzene as a carbon source is presented. A TiO2/graphitic carbon nanocomposites were synthesized by thermal modification in the presence of benzene vapours at different temperature (300-700 °C). The new materials were characterized by a various techniques, such as: X-ray diffraction (XRD), scanning electron microscopy (SEM), diffuse reflectance spectroscopy (UV-vis/DR), surface-enhanced Raman spectroscopy. BET specific surface area was also measured. The photocatalytic activity of obtained nanocomposites was measured by the decomposition of acetic acid and methylene blue under UV-vis irradiation. The results show that photocatalytic activity increasing with increase in carbon concentration and temperature of modification. It can be noted that adsorption degree has a very high impact on methylene blue decomposition. The highest photocatalytic activity was found for the photocatalyst modified at 600 °C contains 1.13 wt% of carbon. It should be noted that, the influence of crystallite size, crystal structure changes and specific surface area for photocatalytic activity are presented.
VisTrails SAHM: visualization and workflow management for species habitat modeling
Morisette, Jeffrey T.; Jarnevich, Catherine S.; Holcombe, Tracy R.; Talbert, Colin B.; Ignizio, Drew A.; Talbert, Marian; Silva, Claudio; Koop, David; Swanson, Alan; Young, Nicholas E.
2013-01-01
The Software for Assisted Habitat Modeling (SAHM) has been created to both expedite habitat modeling and help maintain a record of the various input data, pre- and post-processing steps and modeling options incorporated in the construction of a species distribution model through the established workflow management and visualization VisTrails software. This paper provides an overview of the VisTrails:SAHM software including a link to the open source code, a table detailing the current SAHM modules, and a simple example modeling an invasive weed species in Rocky Mountain National Park, USA.
Response of spectral vegetation indices to soil moisture in grasslands and shrublands
Zhang, Li; Ji, Lei; Wylie, Bruce K.
2011-01-01
The relationships between satellite-derived vegetation indices (VIs) and soil moisture are complicated because of the time lag of the vegetation response to soil moisture. In this study, we used a distributed lag regression model to evaluate the lag responses of VIs to soil moisture for grasslands and shrublands at Soil Climate Analysis Network sites in the central and western United States. We examined the relationships between Moderate Resolution Imaging Spectroradiometer (MODIS)-derived VIs and soil moisture measurements. The Normalized Difference Vegetation Index (NDVI) and Normalized Difference Water Index (NDWI) showed significant lag responses to soil moisture. The lag length varies from 8 to 56 days for NDVI and from 16 to 56 days for NDWI. However, the lag response of NDVI and NDWI to soil moisture varied among the sites. Our study suggests that the lag effect needs to be taken into consideration when the VIs are used to estimate soil moisture.
Role Of Expectancy Manipulation In Systematic Desensitization
ERIC Educational Resources Information Center
Brown, H. Alan
1973-01-01
Expectancy, relaxation, and hierarchy content were manipulated. Findings did not support the hypothesis that expectancy was the only factor in desensitization, but did clarify the role of expectancy vis-a-vis the counterconditioning elements typically discussed in the literature. (Author)
The 1982 Goddard Space Flight Center Battery Workshop
NASA Technical Reports Server (NTRS)
Halpert, G. (Editor)
1983-01-01
Various topics concerned with advanced battery technology are addressed including lithium cell and battery safety developments, mathematical modelling, charge control of aerospace power systems, and the application of nickel hydrogen cells/batteries vis-a-vis nickel cadmium cells/batteries.
TU-G-BRA-02: Can We Extract Lung Function Directly From 4D-CT Without Deformable Image Registration?
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kipritidis, J; Woodruff, H; Counter, W
Purpose: Dynamic CT ventilation imaging (CT-VI) visualizes air volume changes in the lung by evaluating breathing-induced lung motion using deformable image registration (DIR). Dynamic CT-VI could enable functionally adaptive lung cancer radiation therapy, but its sensitivity to DIR parameters poses challenges for validation. We hypothesize that a direct metric using CT parameters derived from Hounsfield units (HU) alone can provide similar ventilation images without DIR. We compare the accuracy of Direct and Dynamic CT-VIs versus positron emission tomography (PET) images of inhaled {sup 68}Ga-labelled nanoparticles (‘Galligas’). Methods: 25 patients with lung cancer underwent Galligas 4D-PET/CT scans prior to radiation therapy.more » For each patient we produced three CT- VIs. (i) Our novel method, Direct CT-VI, models blood-gas exchange as the product of air and tissue density at each lung voxel based on time-averaged 4D-CT HU values. Dynamic CT-VIs were produced by evaluating: (ii) regional HU changes, and (iii) regional volume changes between the exhale and inhale 4D-CT phase images using a validated B-spline DIR method. We assessed the accuracy of each CT-VI by computing the voxel-wise Spearman correlation with free-breathing Galligas PET, and also performed a visual analysis. Results: Surprisingly, Direct CT-VIs exhibited better global correlation with Galligas PET than either of the dynamic CT-VIs. The (mean ± SD) correlations were (0.55 ± 0.16), (0.41 ± 0.22) and (0.29 ± 0.27) for Direct, Dynamic HU-based and Dynamic volume-based CT-VIs respectively. Visual comparison of Direct CT-VI to PET demonstrated similarity for emphysema defects and ventral-to-dorsal gradients, but inability to identify decreased ventilation distal to tumor-obstruction. Conclusion: Our data supports the hypothesis that Direct CT-VIs are as accurate as Dynamic CT-VIs in terms of global correlation with Galligas PET. Visual analysis, however, demonstrated that different CT-VI algorithms might have varying accuracy depending on the underlying cause of ventilation abnormality. This research was supported by a National Health and Medical Research Council (NHMRC) Australia Fellowship, an Cancer Institute New South Wales Early Career Fellowship 13-ECF-1/15 and NHMRC scholarship APP1038399. No commercial funding was received for this work.« less
Health Information in Korean (한국어)
... Information Translations Salmonella Infections Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - 한국어 (Korean) ...
Health Information in Spanish (español)
... Roads Media Salmonella Infections Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - español (Spanish) ...
Health Information in Haitian Creole (Kreyol ayisyen)
... Section Bacterial Infections Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - Kreyol ...
Health Information in Portuguese (português)
... Section Bacterial Infections Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - português ( ...
2016-12-05
Today's VIS image shows part of the canyon wall of Melas Chasma. Orbit Number: 65682 Latitude: -9.38343 Longitude: 289.417 Instrument: VIS Captured: 2016-10-04 02:52 http://photojournal.jpl.nasa.gov/catalog/PIA21181
2015-08-31
The linear depression in today's VIS image is part of Nili Fossae. Orbit Number: 60318 Latitude: 24.7944 Longitude: 80.7404 Instrument: VIS Captured: 2015-07-20 08:53 http://photojournal.jpl.nasa.gov/catalog/PIA19763
Ali, Imran; Wani, Waseem A; Khan, Amber; Haque, Ashanul; Ahmad, Aijaz; Saleem, Kishwar; Manzoor, Nikhat
2012-08-01
A pyrazoline based ligand; (5-(4-chlorophenyl)-3-phenyl-4, 5-dihydro-1H-pyrazole-1-carbothioamide) has been synthesized by Claisen-Schmidt condensation of acetophenone with p-chlorobenzaldehyde, followed by sodium hydroxide assisted cyclization of the resulting chalcone with thiosemicarbazide. Metal ion complexes of the synthesized ligand were prepared with Cu(II) and Ni(II) metal ions, separately and respectively. Ligand and the metal complexes were characterized by elemental analysis, FT-IR, UV-Vis, (1)HNMR, ESI-MS and (13)CNMR spectroscopic techniques. Molar conductance measurements in DMSO suggested non-electrolytic nature of the complexes. Tetragonally distorted octahedral geometry for copper and octahedral geometry for the nickel complexes was proposed on the basis of UV-Vis spectroscopic studies and magnetic moment measurements. The complexes were investigated for their ability to kill human fungal pathogen Candida by determining MICs (Minimum inhibitory concentrations), inhibition in solid media and ability to produce a possible synergism with conventional most clinically practiced antifungals by disc diffusion assay and FICI (fractional inhibitory concentration index). Copyright © 2012 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Xing, Weinan; Ni, Liang; Huo, Pengwei; Lu, Ziyang; Liu, Xinlin; Luo, Yingying; Yan, Yongsheng
2012-10-01
A novel nanocatalyst CdS/halloysite nanotubes (HNTs) was synthesized by hydrothermal method with direct growth of CdS nanoparticles on the surface of HNTs. The as-prepared photocatalysts had been characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), UV-vis diffuse reflectance spectra (UV-vis DRS), Fourier transform infrared (FT-IR) and the thermo gravimetric analysis (TGA). The photocatalytic activity of the sample was evaluated by the degradation of tetracycline (TC) under visible light irradiation. Benefit from the excellent properties of CdS and HNTs, the photocatalyst exhibited good photocatalytic activity and stability. In order to find out the optimum synthesis condition to obtain the best photocatalytic activity, a series of experiments were performed with different CdS loading capacity, different sources of sulfide and different hydrothermal temperatures, etc. The best photodegradation rate could reach 93% in 60 min under visible light irradiation. Therefore, the combination of CdS nanoparticles with HNTs endowed this material with a potential use in environmental treatments in industries.
VisAdapt: A Visualization Tool to Support Climate Change Adaptation.
Johansson, Jimmy; Opach, Tomasz; Glaas, Erik; Neset, Tina-Simone; Navarra, Carlo; Linner, Bjorn-Ola; Rod, Jan Ketil
2017-01-01
The web-based visualization VisAdapt tool was developed to help laypeople in the Nordic countries assess how anticipated climate change will impact their homes. The tool guides users through a three-step visual process that helps them explore risks and identify adaptive actions specifically modified to their location and house type. This article walks through the tool's multistep, user-centered design process. Although VisAdapt's target end users are Nordic homeowners, the insights gained from the development process and the lessons learned from the project are applicable to a wide range of domains.
Visible-light OCT to quantify retinal oxygen metabolism (Conference Presentation)
NASA Astrophysics Data System (ADS)
Zhang, Hao F.; Yi, Ji; Chen, Siyu; Liu, Wenzhong; Soetikno, Brian T.
2016-03-01
We explored, both numerically and experimentally, whether OCT can be a good candidate to accurately measure retinal oxygen metabolism. We first used statistical methods to numerically simulate photon transport in the retina to mimic OCT working under different spectral ranges. Then we analyze accuracy of OCT oximetry subject to parameter variations such as vessel size, pigmentation, and oxygenation. We further developed an experimental OCT system based on the spectral range identified by our simulation work. We applied the newly developed OCT to measure both retinal hemoglobin oxygen saturation (sO2) and retinal retinal flow. After obtaining the retinal sO2 and blood velocity, we further measured retinal vessel diameter and calculated the retinal oxygen metabolism rate (MRO2). To test the capability of our OCT, we imaged wild-type Long-Evans rats ventilated with both normal air and air mixtures with various oxygen concentrations. Our simulation suggested that OCT working within visible spectral range is able to provide accurate measurement of retinal MRO2 using inverse Fourier transform spectral reconstruction. We called this newly developed technology vis-OCT, and showed that vis-OCT was able to measure the sO2 value in every single major retinal vessel around the optical disk as well as in micro retinal vessels. When breathing normal air, the averaged sO2 in arterial and venous blood in Long-Evans rats was measured to be 95% and 72%, respectively. When we challenge the rats using air mixtures with different oxygen concentrations, vis-OCT measurement followed analytical models of retinal oxygen diffusion and pulse oximeter well.
A visible light-curable yet visible wavelength-transparent resin for stereolithography 3D printing
NASA Astrophysics Data System (ADS)
Park, Hong Key; Shin, Mikyung; Kim, Bongkyun; Park, Jin Woo; Lee, Haeshin
2018-04-01
Herein, a new polymeric resin for stereolithography (SLA) three-dimensional printing (SLA-3DP) is reported. An ultraviolet (UV) or visible (VIS) light source is critical for SLA printing technology. UV light can be used to manufacture 3D objects in SLA-3DP, but there are significant occupational safety and health issues (particularly for eyes). These issues prevent the widespread use of SLA-3DP at home or in the office. Through the use of VIS light, the safety and health issues can largely be solved, but only non-transparent 3D objects can be manufactured, which prevents the application of 3DP to the production of various common transparent consumer products. For these reasons, we developed a VIS light-curable yet visibly transparent resin for SLA-3DP, which also retains UV curability. The key was to identify the photoinitiator diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (DPTBP). DPTBP was originally designed as a UV photoinitiator, but we found that VIS light irradiation is sufficient to split DPTBP and generate radicals due to its slight VIS light absorption up to 420 nm. The cured resin displays high transparency and beautiful transparent colors by incorporating various dyes; additionally, its mechanical properties are superior to those of commercial resins (Arario 410) and photoinitiators (Irgacure 2959).
Sboui, Mouheb; Nsib, Mohamed Faouzi; Rayes, Ali; Swaminathan, Meenakshisundaram; Houas, Ammar
2017-10-01
A novel photocatalyst based on TiO 2 -PANI composite supported on small pieces of cork has been reported. It was prepared by simple impregnation method of the polyaniline (PANI)-modified TiO 2 on cork. The TiO 2 -PANI/Cork catalyst shows the unique feature of floating on the water surface. The as-synthesized catalyst was characterized by X-ray diffraction (XRD), scanning electron micrograph (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), UV-vis diffuse reflectance spectra (UV-vis DRS) and the Brunauer-Emmett-Teller (BET) surface area analysis. Characterization suggested the formation of anatase highly dispersed on the cork surface. The prepared floating photocatalyst showed high efficiency for the degradation of methyl orange dye and other organic pollutants under solar irradiation and constrained conditions, i.e., no-stirring and no-oxygenation. The TiO 2 -PANI/Cork floating photocatalyst can be reused for at least four consecutive times without significant decrease of the degradation efficiency. Copyright © 2017. Published by Elsevier B.V.
Novel Bi/BiOBr/AgBr composite microspheres: Ion exchange synthesis and photocatalytic performance
NASA Astrophysics Data System (ADS)
Lyu, Jianchang; Li, Zhenlu; Ge, Ming
2018-06-01
Novel Bi/BiOBr/AgBr composite microspheres were prepared by a rational in situ ion exchange reaction between Bi/BiOBr microspheres and AgNO3. The characteristic of the as-obtained ternary microspheres was tested by X-ray diffraction (XRD), energy dispersive X-ray spectrometer (EDS), scanning electron microscope (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (UV-vis DRS) and photoluminescence (PL). Under visible light irradiation, Bi/BiOBr/AgBr microspheres exhibited an excellent photocatalytic efficiency for rhodamine B (RhB) degradation, which was about 1.4 and 4.9 times as high as that of Bi/BiOBr and BiOBr/AgBr, demonstrating that the highest separation efficiency of charge carriers in the heterostructured Bi/BiOBr/AgBr. The photocatalytic activity of Bi/BiOBr/AgBr microspheres just exhibited a slight decrease after three consecutive cycles. The photocatalytic mechanism investigation confirmed that the superoxide radicals (O2•-) were the dominant reactive oxygen species for RhB degradation in Bi/BiOBr/AgBr suspension.
Preparation of Ag/AgCl/BiMg{sub 2}VO{sub 6} composite and its visible-light photocatalytic activity
DOE Office of Scientific and Technical Information (OSTI.GOV)
Guo, Rui; Zhang, Gaoke, E-mail: gkzhang@whut.edu.cn; Liu, Jiu
2013-05-15
Graphical abstract: - Abstract: A novel composite photocatalyst Ag/AgCl/BiMg{sub 2}VO{sub 6} was synthesized by depositing Ag/AgCl nanoparticles on BiMg{sub 2}VO{sub 6} substrate via a precipitation–photoreduction method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray analysis (EDXA), X-ray photoelectron spectroscopy (XPS) and UV–vis diffuse reflectance spectrophotometer (UV–vis DRS). The photocatalyst showed high and stable photocatalytic activity for photocatalytic degradation of acid red G under visible-light irradiation (λ > 420 nm). In addition, the active ·O{sub 2}{sup −} and h{sup +}, as main reactive species, played the major roles during the reaction process.more » The high photocatalytic activity of the composite may be related to the efficient electron–hole pairs separation at the photocatalyst interfaces, as well as the surface plasmon resonance of Ag nanoparticles formed on AgCl particles in the degradation reaction.« less
NASA Astrophysics Data System (ADS)
Li, Xiaojuan; Jin, Bo; Huang, Jingwen; Zhang, Qingchun; Peng, Rufang; Chu, Shijin
2018-06-01
In this study, novel ternary Fe2O3/ZnO/ZnFe2O4 (ZFO) composites were successfully prepared through a simple hydrothermal reaction with subsequent thermal treatment. The as-prepared products were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET) analysis, Barrett-Joyner-Halenda (BJH) measurement, and UV-vis diffuse reflectance spectroscopy (UV-vis DRS). The photocatalytic degradation of rhodamine B (Rh B) under visible light irradiation indicated that the ZFO composites calcined at 500 °C has the best photocatalytic activity (the photocatalytic degradation efficiency can reach up to 95.7% within 60 min) and can maintain a stable photocatalytic degradation efficiency for at least three cycles. In addition, the photocatalytic activity of ZFO composites toward dye decomposition follows the order cationic Rh B > anionic methyl orange. Finally, using different scavengers, superoxide and hydroxyl radicals were identified as the primary active species during the degradation reaction of Rh B.
NASA Astrophysics Data System (ADS)
Visconti, Anthony Joseph
The fabrication of gradient-index (GRIN) optical elements is quite challenging, which has traditionally restricted their use in many imaging systems; consequently, commercial-level GRIN components usually exist in one particular market or niche application space. One such fabrication technique, ion exchange, is a well-known process used in the chemical strengthening of glass, the fabrication of waveguide devices, and the production of small diameter GRIN optical relay systems. However, the manufacturing of large diameter ion-exchanged GRIN elements has historically been limited by long diffusion times. For example, the diffusion time for a 20 mm diameter radial GRIN lens in commercially available ion exchange glass for small diameter relays, is on the order of a year. The diffusion time can be dramatically reduced by addressing three key ion exchange process parameters; the composition of the glass, the diffusion temperature, and the composition of the salt bath. Experimental work throughout this thesis aims to (1) scale up the ion exchange diffusion process to 20 mm diameters for a fast-diffusing titania silicate glass family in both (2) sodium ion for lithium ion (Na+ for Li+) and lithium ion for sodium ion (Li+ for Na+) exchange directions, while (3) utilizing manufacturing friendly salt bath compositions. In addition, optical design studies have demonstrated that an important benefit of gradient-index elements in imaging systems is the added degree of freedom introduced with a gradient's optical power. However, these studies have not investigated the potential usefulness of GRIN materials in dual-band visible to short-wave infrared (vis-SWIR) imaging systems. The unique chromatic properties of the titania silicate ion exchange glass become a significant degree of freedom in the design process for these color-limited, broadband imaging applications. A single GRIN element can replace a cemented doublet or even a cemented triplet, without loss in overall system performance. In this work, a polychromatic vis-SWIR gradient-index design model is constructed based on the homogeneous material properties of the titania silicate ion exchange glass. This model is verified by measuring the dispersion of fabricated GRIN profiles across the vis-SWIR spectrum. Finally, the polychromatic GRIN design model is implemented into commercial design software and several design studies are presented which validate the beneficial chromatic properties of the titania silicate GRIN material. In addition, system-level tolerancing with gradient-index elements is a largely unexplored area. This work introduces new methods and techniques for incorporating GRIN manufacturing errors directly into the design and tolerancing analysis of a multi-element optical system. These methods allow for the optical engineer to utilize manufacturable GRIN profiles throughout the design process and to better predict the final performance of an as-built system. Based on these techniques, a true design-for-manufacture high-performance eyepiece, utilizing a spherical gradient-index element, is designed, toleranced, and commissioned for build.
Health Information in Vietnamese (Tiếng Việt)
... Information Translations Salmonella Infections Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - Tiếng Việt ( ...
Health Information in Turkish (Türkçe)
... Expand Section Salmonella Infections Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - Türkçe (Turkish) ...
Health Information in French (français)
... Translations Bacterial Infections Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - français ( ...
Pneumonia - Multiple Languages
... Control and Prevention Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - العربية ( ...
Health Information in Japanese (日本語)
... Translations Bacterial Infections Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - 日本語 ( ...
Encephalitis - Multiple Languages
... dialect) (繁體中文) Expand Section Vaccine Information Statement (VIS) -- Japanese Encephalitis Vaccine: What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Japanese Encephalitis Vaccine: What You Need to Know - 繁體中文 ( ...
Traveler's Health - Multiple Languages
... dialect) (繁體中文) Expand Section Vaccine Information Statement (VIS) -- Japanese Encephalitis Vaccine: What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Japanese Encephalitis Vaccine: What You Need to Know - 繁體中文 ( ...
2015-09-02
The intersecting linear depressions in this VIS image are part of Hephaestus Fossae. Orbit Number: 60373 Latitude: 21.9161 Longitude: 122.075 Instrument: VIS Captured: 2015-07-24 20:50 http://photojournal.jpl.nasa.gov/catalog/PIA19765
Polio vaccine - what you need to know
... is taken in its entirety from the CDC Polio Vaccine Information Statement (VIS): www.cdc.gov/vaccines/ ... statements/ipv.html CDC review information for the Polio VIS: Page last reviewed: July 20, 2016 Page ...
Conversion of NIMROD simulation results for graphical analysis using VisIt
DOE Office of Scientific and Technical Information (OSTI.GOV)
Romero-Talamas, C A
Software routines developed to prepare NIMROD [C. R. Sovinec et al., J. Comp. Phys. 195, 355 (2004)] results for three-dimensional visualization from simulations of the Sustained Spheromak Physics Experiment (SSPX ) [E. B. Hooper et al., Nucl. Fusion 39, 863 (1999)] are presented here. The visualization is done by first converting the NIMROD output to a format known as legacy VTK and then loading it to VisIt, a graphical analysis tool that includes three-dimensional rendering and various mathematical operations for large data sets. Sample images obtained from the processing of NIMROD data with VisIt are included.
Joshi, Ashish; de Araujo Novaes, Magdala; Machiavelli, Josiane; Iyengar, Sriram; Vogler, Robert; Johnson, Craig; Zhang, Jiajie; Hsu, Chiehwen E
2012-01-01
Public health data is typically organized by geospatial units. Routine geographic monitoring of health data enables an understanding of the spatial patterns of events in terms of causes and controls. GeoVisualization (GeoVis) allows users to see information hidden both visually and explicitly on a map. Despite the applicability of GeoVis in public health, it is still underused for visualizing public health data. The objective of this study is to examine the perception of telehealth users' to utilize GeoVis as a proof of concept to facilitate visual exploration of telehealth data in Brazil using principles of human centered approach and cognitive fit theory. A mixed methods approach combining qualitative and quantitative assessments was utilized in this cross sectional study conducted at the Telehealth Center of the Federal University of Pernambuco (NUTE-UFPE), Recife, Brazil. A convenient sample of 20 participants currently involved in NUTES was drawn during a period of Sep-Oct 2011. Data was gathered using previously tested questionnaire surveys and in-person interviews. Socio-demographic Information such as age, gender, prior education, familiarity with the use of computer and GeoVis was gathered. Other information gathered included participants' prior spatial analysis skills, level of motivation and use of GeoVis in telehealth. Audio recording was done for all interviews conducted in both English and Portuguese, and transcription of the audio content to English was done by a certified translator. Univariate analysis was performed and means and standard deviations were reported for the continuous variables and frequency distributions for the categorical variables. For the open-ended questions, we utilized a grounded theory to identify themes and their relationship as they emerge from the data. Analysis of the quantitative data was performed using SAS V9.1 and qualitative data was performed using NVivo9. The average age of participants was 28 years (SD=7), a majority of them were females and 100% were professionals with graduate degrees. The users had diverse backgrounds including nursing, computer science, biomedical informatics, statistics, dentistry, administration and engineering. The users had varied roles and responsibilities, used computers frequently but only 5% of them were familiar with GeoVis. Google maps were the most common GeoVis application that the users were familiar with. Despite having minimal spatial skills, there was a strong motivation and relevance among the telehealth users to use GeoVis to facilitate visual exploration of telehealth data for better informed decision making. Results also showed that of the 60% participants with no GeoVis familiarity; 33% had moderate to large data exploratory role, 83% had no spatial skills but 58% preferred analyzing both spatial and temporal dimensions of the data. Majority of the participants agreed to have maps as the first choice to represent the data as it will be able to display the events both in place and time. The results demonstrate a potentially growing need for the use of GeoVis applications to evaluate telehealth data. Understanding of user needs is essential to ensure that the technology is appropriately functional and will be useful to complete the tasks.
2018-04-27
Today's VIS image shows a section of Bahram Vallis. This channel is located in northern Lunae Planum, south of Kasei Valles. Orbit Number: 71256 Latitude: 21.0762 Longitude: 301.486 Instrument: VIS Captured: 2018-01-06 08:51 https://photojournal.jpl.nasa.gov/catalog/PIA22379
Model-Selection Theory: The Need for a More Nuanced Picture of Use-Novelty and Double-Counting
Steele, Katie; Werndl, Charlotte
2018-01-01
Abstract This article argues that common intuitions regarding (a) the specialness of ‘use-novel’ data for confirmation and (b) that this specialness implies the ‘no-double-counting rule’, which says that data used in ‘constructing’ (calibrating) a model cannot also play a role in confirming the model’s predictions, are too crude. The intuitions in question are pertinent in all the sciences, but we appeal to a climate science case study to illustrate what is at stake. Our strategy is to analyse the intuitive claims in light of prominent accounts of confirmation of model predictions. We show that on the Bayesian account of confirmation, and also on the standard classical hypothesis-testing account, claims (a) and (b) are not generally true; but for some select cases, it is possible to distinguish data used for calibration from use-novel data, where only the latter confirm. The more specialized classical model-selection methods, on the other hand, uphold a nuanced version of claim (a), but this comes apart from (b), which must be rejected in favour of a more refined account of the relationship between calibration and confirmation. Thus, depending on the framework of confirmation, either the scope or the simplicity of the intuitive position must be revised. 1 Introduction2 A Climate Case Study3 The Bayesian Method vis-à-vis Intuitions4 Classical Tests vis-à-vis Intuitions5 Classical Model-Selection Methods vis-à-vis Intuitions 5.1 Introducing classical model-selection methods 5.2 Two cases6 Re-examining Our Case Study7 Conclusion PMID:29780170
Model-Selection Theory: The Need for a More Nuanced Picture of Use-Novelty and Double-Counting.
Steele, Katie; Werndl, Charlotte
2018-06-01
This article argues that common intuitions regarding (a) the specialness of 'use-novel' data for confirmation and (b) that this specialness implies the 'no-double-counting rule', which says that data used in 'constructing' (calibrating) a model cannot also play a role in confirming the model's predictions, are too crude. The intuitions in question are pertinent in all the sciences, but we appeal to a climate science case study to illustrate what is at stake. Our strategy is to analyse the intuitive claims in light of prominent accounts of confirmation of model predictions. We show that on the Bayesian account of confirmation, and also on the standard classical hypothesis-testing account, claims (a) and (b) are not generally true; but for some select cases, it is possible to distinguish data used for calibration from use-novel data, where only the latter confirm. The more specialized classical model-selection methods, on the other hand, uphold a nuanced version of claim (a), but this comes apart from (b), which must be rejected in favour of a more refined account of the relationship between calibration and confirmation. Thus, depending on the framework of confirmation, either the scope or the simplicity of the intuitive position must be revised. 1 Introduction 2 A Climate Case Study 3 The Bayesian Method vis-à-vis Intuitions 4 Classical Tests vis-à-vis Intuitions 5 Classical Model-Selection Methods vis-à-vis Intuitions 5.1 Introducing classical model-selection methods 5.2 Two cases 6 Re-examining Our Case Study 7 Conclusion .
Zhang, Ning; Brugger, Joël; Etschmann, Barbara; Ngothai, Yung; Zeng, Dewen
2015-01-01
Knowledge of the structure and speciation of aqueous Ni(II)-chloride complexes is important for understanding Ni behavior in hydrometallurgical extraction. The effect of concentration on the first-shell structure of Ni(II) in aqueous NiCl2 and NiCl2-MgCl2 solutions was investigated by Ni K edge X-ray absorption (XAS) and UV-Vis spectroscopy at ambient conditions. Both techniques show that no large structural change (e.g., transition from octahedral to tetrahedral-like configuration) occurs. Both methods confirm that the Ni(II) aqua ion (with six coordinated water molecules at R Ni-O = 2.07(2) Å) is the dominant species over the whole NiCl2 concentration range. However, XANES, EXAFS and UV-Vis data show subtle changes at high salinity (> 2 mol∙kg-1 NiCl2), which are consistent with the formation of small amounts of the NiCl+ complex (up to 0.44(23) Cl at a Ni-Cl distance of 2.35(2) Å in 5.05 mol∙kg-1 NiCl2) in the pure NiCl2 solutions. At high Cl:Ni ratio in the NiCl2-MgCl2-H2O solutions, small amounts of [NiCl2]0 are also present. We developed a speciation-based mixed-solvent electrolyte (MSE) model to describe activity-composition relationships in NiCl2-MgCl2-H2O solutions, and at the same time predict Ni(II) speciation that is consistent with our XAS and UV-Vis data and with existing literature data up to the solubility limit, resolving a long-standing uncertainty about the role of chloride complexing in this system. PMID:25885410
NASA Astrophysics Data System (ADS)
Tanaka, Osamu; Iida, Takayoshi; Komeda, Hisao; Tamaki, Masayoshi; Seike, Kensaku; Kato, Daiki; Yokoyama, Takamasa; Hirose, Shigeki; Kawaguchi, Daisuke
2016-12-01
Visualization of markers is critical for imaging modalities such as computed tomography (CT) and magnetic resonance imaging (MRI). However, the size of the marker varies according to the imaging technique. While a large-sized marker is more useful for visualization in MRI, it results in artifacts on CT and causes substantial pain on administration. In contrast, a small-sized marker reduces the artifacts on CT but hampers MRI detection. Herein, we report a new ironcontaining marker and compare its utility with that of non-iron-containing markers. Five patients underwent CT/MRI fusion-based intensity-modulated radiotherapy, and the markers were placed by urologists. A Gold Anchor™ (GA; diameter, 0.28 mm; length, 10 mm) was placed using a 22G needle on the right side of the prostate. A VISICOIL™ (VIS; diameter, 0.35 mm; length, 10 mm) was placed using a 19G needle on the left side. MRI was performed using T2*-weighted imaging. Three observers evaluated and scored the visual qualities of the acquired images. The mean score of visualization was almost identical between the GA and VIS in radiography and cone-beam CT (Novalis Tx). The artifacts in planning CT were slightly larger using the GA than using the VIS. The visualization of the marker on MRI using the GA was superior to that using the VIS. In conclusion, the visualization quality of radiography, conebeam CT, and planning CT was roughly equal between the GA and VIS. However, the GA was more strongly visualized than was the VIS on MRI due to iron containing.
NASA Astrophysics Data System (ADS)
Mahesh, K. P. O.; Kuo, Dong-Hau
2015-12-01
Highly photocatalytic active Ni magnetic nanoparticles-decorated SiO2 core/TiO2 shell (Ni-SiO2/TiO2) particles have been prepared by the simultaneous hydrolysis and condensation of titanium tetra-isopropoxide on SiO2 sphere of ∼300 nm in size followed by the reduction of nickel chloride using hydrazine hydrate as a reducing agent. The crystalline nature, surface morphology, electrochemical impedance spectra and UV-vis diffuse reflectance spectra of the Ni-SiO2/TiO2 magnetic spheres were characterized by PXRD, FE-SEM, TEM, EIS and UV-vis DRS. The Ni-SiO2/TiO2 magnetic photocatalyst was used for the degradation of Acid Black 1 (AB 1) dye under UV irradiation. The effects of different concentrations of the Ni nanoparticles deposited on the SiO2/TiO2 composite spheres for the photo-mineralization of AB 1 dye were analyzed. The results showed the Ni-SiO2/TiO2 magnetic photocatalyst to be efficient and reusable.
Solar photocatalytic degradation of isoproturon over TiO2/H-MOR composite systems.
Sharma, Mangalampalli V Phanikrishna; Durgakumari, Valluri; Subrahmanyam, Machiraju
2008-12-30
The photocatalytic degradation and mineralization of isoproturon herbicide was investigated in aqueous solution containing TiO2 over H-mordenite (H-MOR) photocatalysts under solar light. The catalysts are characterized by X-ray diffraction (XRD), UV-Vis diffused reflectance spectra (UV-Vis DRS), Fourier transform-infra red spectra (FT-IR) and scanning electron microscopy (SEM) techniques. The effect of TiO2, H-MOR support and different wt% of TiO2 over the support on the photocatalytic degradation and influence of parameters such as TiO2 loading, catalyst amount, pH and initial concentration of isoproturon on degradation are evaluated. 15wt% TiO2/H-MOR composite is found to be optimum. The degradation reaction follows pseudo-first order kinetics and is discussed in terms of Langmuir-Hinshelwood (L-H) kinetic model. The extent of isoproturon mineralization studied with chemical oxygen demand (COD) and total organic carbon (TOC) measurements and approximately 80% mineralization occurred in 5h. A plausible mechanism is proposed based on the intermediates identified by liquid chromatography-mass spectroscopy (LC-MS).
Houska, Treva R.; Johnson, A.P.
2012-01-01
The Global Visualization Viewer (GloVis) trifold provides basic information for online access to a subset of satellite and aerial photography collections from the U.S. Geological Survey Earth Resources Observation and Science (EROS) Center archive. The GloVis (http://glovis.usgs.gov/) browser-based utility allows users to search and download National Aerial Photography Program (NAPP), National High Altitude Photography (NHAP), Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), Earth Observing-1 (EO-1), Global Land Survey, Moderate Resolution Imaging Spectroradiometer (MODIS), and TerraLook data. Minimum computer system requirements and customer service contact information also are included in the brochure.
Pneumococcal Infections - Multiple Languages
... Control and Prevention Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - العربية ( ...
Pneumococcal polysaccharide vaccine - what you need to know
... taken in its entirety from the CDC Pneumococcal Polysaccharide Vaccine Information Statement (VIS): www.cdc.gov/vaccines/ ... statements/ppv.html CDC review information for Pneumococcal Polysaccharide VIS: Page last reviewed: April 24, 2015 Page ...
HPV (Human Papillomavirus) vaccine - what you need to know
... taken in its entirety from the CDC HPV (Human Papillomavirus) Vaccine Information Statement (VIS): www.cdc.gov/ ... statements/hpv.html . CDC review information for HPV (Human Papillomavirus) VIS: Page last reviewed: December 2, 2016 ...
Hemorrhagic Fevers - Multiple Languages
... dialect) (繁體中文) Expand Section Vaccine Information Statement (VIS) -- Yellow Fever Vaccine: What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Yellow Fever Vaccine: What You Need to Know - 繁體中文 (Chinese, Traditional ( ...
Varicella (chickenpox) vaccine - what you need to know
... is taken in its entirety from the CDC Chickenpox Vaccine Information Statement (VIS): www.cdc.gov/vaccines/ ... statements/varicella.html CDC review information for the Chickenpox VIS: Page last reviewed: February 12, 2018 Page ...
MMR (measles, mumps, and rubella) vaccine - what you need to know
Centers for Disease Control and Prevention website. MMR (measles, mumps, and rubella) vaccine. www.cdc.gov/vaccines/hcp/vis/vis-statements/mmr.html . Updated February 12, 2018. Accessed February 14, 2018.
ChtVis-Tomato, a genetic reporter for in vivo visualization of chitin deposition in Drosophila
Sobala, Lukasz F.; Wang, Ying; Adler, Paul N.
2015-01-01
Chitin is a polymer of N-acetylglucosamine that is abundant and widely found in the biological world. It is an important constituent of the cuticular exoskeleton that plays a key role in the insect life cycle. To date, the study of chitin deposition during cuticle formation has been limited by the lack of a method to detect it in living organisms. To overcome this limitation, we have developed ChtVis-Tomato, an in vivo reporter for chitin in Drosophila. ChtVis-Tomato encodes a fusion protein that contains an apical secretion signal, a chitin-binding domain (CBD), a fluorescent protein and a cleavage site to release it from the plasma membrane. The chitin reporter allowed us to study chitin deposition in time lapse experiments and by using it we have identified unexpected deposits of chitin fibers in Drosophila pupae. ChtVis-Tomato should facilitate future studies on chitin in Drosophila and other insects. PMID:26395478
Low-loss VIS/IR-XUV beam splitter for high-power applications.
Pupeza, Ioachim; Fill, Ernst E; Krausz, Ferenc
2011-06-20
We present a low-loss VIS/IR-XUV beam splitter, suitable for high-power operation. The spatial separation of the VIS/IR and XUV components of a beam is achieved by the wedged top layer of a dielectric multilayer structure, onto which the beam is impinging under Brewster's angle (for VIS/IR). With a fused silica wedge with an angle of 0.5° we achieve a separation angle of 2.2° and an IR reflectivity of 0.9995. Typical XUV reflectivities amount to 0.1-0.2. The novel element is mechanically robust, exhibiting two major advantages over free-standing Brewster plates: (i) a significant improvement of heat conduction and (ii) easier handling, in particular for high-optical-quality fabrication. The beam splitter could be used as an output coupler for intracavity-generated XUV radiation, promising a boost of the power regime of current MHz-HHG experiments. It is also suited for single-pass experiments and as a beam combiner for pump-probe experiments.
Performance evaluation of spectral vegetation indices using a statistical sensitivity function
Ji, Lei; Peters, Albert J.
2007-01-01
A great number of spectral vegetation indices (VIs) have been developed to estimate biophysical parameters of vegetation. Traditional techniques for evaluating the performance of VIs are regression-based statistics, such as the coefficient of determination and root mean square error. These statistics, however, are not capable of quantifying the detailed relationship between VIs and biophysical parameters because the sensitivity of a VI is usually a function of the biophysical parameter instead of a constant. To better quantify this relationship, we developed a “sensitivity function” for measuring the sensitivity of a VI to biophysical parameters. The sensitivity function is defined as the first derivative of the regression function, divided by the standard error of the dependent variable prediction. The function elucidates the change in sensitivity over the range of the biophysical parameter. The Student's t- or z-statistic can be used to test the significance of VI sensitivity. Additionally, we developed a “relative sensitivity function” that compares the sensitivities of two VIs when the biophysical parameters are unavailable.
Macromolecules Vis-a-Vis the Traditions of Chemistry
ERIC Educational Resources Information Center
Flory, Paul J.
1973-01-01
Summarizes the history of concepts concerning the molecular nature of polymers, involving the carbon chain theory, graphic formula, polycondensation, colloidal properties, polypeptide hypothesis, secondary aggregation, and Watson-Crick model. Indicates that macromolecular science should be accommodated within the discipline of molecular science…
NASA Astrophysics Data System (ADS)
Bacon, Christina P.; Rose, J. B.; Patten, K.; Garcia-Rubio, Luis H.
1995-05-01
Cryptosporidium and Giardia are enteric protozoa which cause waterborne diseases. To date, the detection of these organisms in water has relied upon microscopic immunofluorescent assay technology which uses antibodies directed against the cyst and oocyst forms of the protozoa. In this paper, the uv/vis extinction spectra of aqueous dispersions of Cryptosporidium and Giardia have been studied to investigate the potential use of light scattering-spectral deconvolution techniques as a rapid method for the identification and quantification of protozoa in water. Examination of purified samples of Cryptosporidium and Giardia suggests that spectral features apparent in the short wavelength region of the uv/vis spectra contain information that may be species specific for each protozoa. The spectral characteristics, as well as the particle size analysis, determined from the same spectra, allow for the quantitative classification, identification, and possibly, the assessment of the viability of the protozoa. To further increase the sensitivity of this technique, specific antibodies direction against these organisms, labelled with FITC and rhodamine are being used. It is demonstrated that uv/vis spectroscopy provides an alternative method for the characterization of Giardia and Cryptosporidium. The simplicity and reproducibility of uv/vis spectroscopy measurements makes this technique ideally suited for the development of on-line instrumentation for the rapid detection of microorganisms in water supplies.
AppVis: Enabling data-rich apps in app inventor
NASA Astrophysics Data System (ADS)
Harunani, Farzeen
MIT App Inventor has enabled middle school students to learn computing while creating their own apps--including apps that serve community needs. However, few resources exist for building apps that gather and share data. There is a need for new tools and an instructional materials for students to build data-enabled, community-focused apps. We developed an extension for App Inventor, called AppVis, which allows app-makers to publish and retrieve data from iSENSE, our existing web-based collaborative data visualization platform. We used AppVis and supporting instructional materials in two one-week summer camps attended by a total of 33 middle school students. Based on student interview data and analysis of their final apps, our approach was broadly accessible to a diverse population of students. Students were motivated to build apps that could be used by their own communities. This thesis presents the design of AppVis and results from students' work in summer camps.
Health Information in Chinese, Traditional (Cantonese dialect) (繁體中文)
... Expand Section Salmonella Infections Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - 繁體中文 (Chinese, ...
Health Information in Khmer (ភាសាខ្មែរ)
... Expand Section Salmonella Infections Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Typhoid Vaccines: What You Need to Know - ភាសា ...
Haemophilus influenzae Type b (Hib) vaccine - what you need to know
... taken in its entirety from the CDC Hib (Haemophilus Influenzae Type b) Vaccine Information Statement (VIS): www. ... statements/hib.pdf . CDC review information for Hib (Haemophilus Influenzae Type b) VIS: Page last reviewed: April ...
2017-03-27
Today's VIS image shows part of the large dune form on the floor of Russell Crater. Orbit Number: 67151 Latitude: -54.3002 Longitude: 13.0603 Instrument: VIS Captured: 2017-02-02 03:15 http://photojournal.jpl.nasa.gov/catalog/PIA21517
Hepatitis B vaccine - what you need to know
... is taken in its entirety from the CDC Hepatitis B Vaccine Information Statement (VIS): www.cdc.gov/vaccines/ ... statements/hep-b.html CDC review information for Hepatitis B VIS: Page last reviewed: July 20, 2016 Page ...
Rationality and the Role of the University: A Response to Philip Higgs.
ERIC Educational Resources Information Center
Waghid, Y.
2002-01-01
Challenges Higgs'"ambivalent" position about the role of the university (presented in a previous article), contending that the university can still retain its character as "a community of reason" (Higgs' main argument) without abandoning its social role vis-a-vis nation building. (EV)
NASA Astrophysics Data System (ADS)
Richards, B. C.; Nikolaeva, S. V.; Kulagina, E. I.; Alekseev, A. S.; Gorozhanina, E. N.; Gorozhanin, V. M.; Konovalova, V. A.; Goreva, N. V.; Joachimski, M. M.; Gatovsky, Y. A.
2017-12-01
The Verkhnyaya Kardailovka section is one of the best candidates for the GSSP (Global Stratotype Section and Point) at the base of the Stage (Mississippian). For boundary definition, the first appearance of the conodont Lochriea ziegleri Nemirovskaya, Perret et Meischner, 1994 in the lineage Lochriea nodosa (Bischoff, 1957)- L. ziegleri is used. L. ziegleri appears in the Venevian Substage somewhat below the base of the Serpukhovian in the Moscow Basin. The position of the FAD of L. ziegleri within the Hypergoniatites- Ferganoceras Genozone is confirmed and lies between 19.53 and 19.63 m above the section's base. Before 2010, deep-water stylonodular limestone containing the boundary in unnamed formation C at Kardailovka was well exposed but only 3 m of Viséan strata cropped out immediately below. Recent trenching exposed another 10 m of underlying Viséan carbonates in formation C and older Viséan siliciclastics and volcanics in unnamed formation B. The contact between formation B and underlying crinoidal limestones in unnamed formation A representing the middle Viséan Zhukovian (Tulian) regional Substage was excavated. The boundary succession, situated in the Magnitogorsk tectonic zone above the Devonian Magnitogorsk arc and Mississippian magmatic and sedimentary rift succession, was deposited west of the Kazakhstanian continent during closure of the Ural Ocean. In the lower part of the section, Viséan tuffaceous siliciclastics and volcanics of formation B record rapid deepening after deposition of neritic middle Viséan crinoid lime grainstone of formation A and subsequent subaerial exposure. The overlying condensed upper Viséan to Serpukhovian succession in formation C comprises deep-water limestone deposited in a sediment-starved basin recording minor turbidite influx and carbonate-mound development. The δ13Ccarb plot shows a positive shift of 1‰ V-PDB (from +2 to +3‰) between 17.0 and 17.75 m (3.05 and 1.97 m below FAD L. ziegleri). The δ18Oapatite graph displays a prominent upward shift from 19.9 to 21.1‰ V-SMOW (at 19.15 to 19.51 m) in the nodosa Zone below FAD of Lochriea ziegleri.
Jeong, Kwang-Eun; Cho, Chin-Soo; Chae, Ho-Jeong; Kim, Chul-Ung; Jeong, Soon-Yong
2010-05-01
Titanium containing mesoporous molecular sieve (Ti-MMS) catalysts were studied for the oxidative desulfurization of refractory sulfur compounds. Ti-MMS catalysts were synthesized from fluorosilicon compounds and Ti with the hydrolysis reaction of H2SiF6 in an ammonia-surfactant mixed solution. The solid products were characterized by XRD, XRF, nitrogen adsorption, and diffuse reflectance UV-vis spectroscopy. Effects of Ti loading and oxidant/sulfur mole ratio, and sulfur species on ODS activity were investigated.
Price, Margaux M; Crumley-Branyon, Jessica J; Leidheiser, William R; Pak, Richard
2016-06-01
Technology gains have improved tools for evaluating complex tasks by providing environmental supports (ES) that increase ease of use and improve performance outcomes through the use of information visualizations (info-vis). Complex info-vis emphasize the need to understand individual differences in abilities of target users, the key cognitive abilities needed to execute a decision task, and the graphical elements that can serve as the most effective ES. Older adults may be one such target user group that would benefit from increased ES to mitigate specific declines in cognitive abilities. For example, choosing a prescription drug plan is a necessary and complex task that can impact quality of life if the wrong choice is made. The decision to enroll in one plan over another can involve comparing over 15 plans across many categories. Within this context, the large amount of complex information and reduced working memory capacity puts older adults' decision making at a disadvantage. An intentionally designed ES, such as an info-vis that reduces working memory demand, may assist older adults in making the most effective decision among many options. The objective of this study is to examine whether the use of an info-vis can lower working memory demands and positively affect complex decision-making performance of older adults in the context of choosing a Medicare prescription drug plan. Participants performed a computerized decision-making task in the context of finding the best health care plan. Data included quantitative decision-making performance indicators and surveys examining previous history with purchasing insurance. Participants used a colored info-vis ES or a table (no ES) to perform the decision task. Task difficulty was manipulated by increasing the number of selection criteria used to make an accurate decision. A repeated measures analysis was performed to examine differences between the two table designs. Twenty-three older adults between the ages of 66 and 80 completed the study. There was a main effect for accuracy such that older adults made more accurate decisions in the color info-vis condition than the table condition. In the low difficulty condition, participants were more successful at choosing the correct answer when the question was about the gap coverage attribute in the info-vis condition. Participants also made significantly faster decisions in the info-vis condition than in the table condition. Reducing the working memory demand of the task through the use of an ES can improve decision accuracy, especially when selection criteria is only focused on a single attribute of the insurance plan.
NASA Astrophysics Data System (ADS)
Isaienko, Oleksandr; Borguet, Eric
A non-collinear KTP-OPA to provide ultra-broadband mid-infrared pulses was designed and characterized. With proper pulse-front and phase correction, the system has a potential for high-time resolution vibrational VIS-IR-SFG spectroscopy.
Simulated In Situ Determination of Soil Profile Organic and Inorganic Carbon With LIBS and VisNIR
NASA Astrophysics Data System (ADS)
Bricklemyer, R. S.; Brown, D. J.; Clegg, S. M.; Barefield, J. E.
2008-12-01
There is growing need for rapid, accurate, and inexpensive methods to measure, and verify soil organic carbon (SOC) change for national greenhouse gas accounting and the development of a soil carbon trading market. Laser Induced Breakdown Spectroscopy (LIBS) and Visible and Near Infrared Spectroscopy (VisNIR) are complementary analytical techniques that have the potential to fill that need. The LIBS method provides precise elemental analysis of soils, but generally cannot distinguish between organic C and inorganic C. VisNIR has been established as a viable technique for measuring soil properties including SOC and inorganic carbon (IC). As part of the Big Sky Carbon Sequestration Regional Partnership, 240 intact core samples (3.8 x 50 cm) have been collected from six agricultural fields in north central Montana, USA. Each of these core samples were probed concurrently with LIBS and VisNIR at 2.5, 7.5, 12.5, 17.5, 22.5, 27.5, 35 and 45 cm (+/- 1.5 cm) depths. VisNIR measurements were taken using an Analytical Spectral Devices (ASD, Boulder, CO, USA) Agrispec spectrometer to determine the partition of SOC vs. IC in the samples. The LIBS scans were collected with the LANL LIBS Core Scanner Instrument which collected the entire 200 - 900 nm plasma emission including the 247.8 nm carbon emission line. This instrument also collected the emission from the elements typically found in inorganic carbon (Ca and Mg) and organic carbon (H, O, and N). Subsamples of soil (~ 4 g) were taken from interrogation points for laboratory determination of SOC and IC. Using this analytical data, we constructed several full spectrum multivariate VisNIR/LIBS calibration models for SOC and IC. These models were then applied to independent validation cores for model evaluation.
2016-08-26
This VIS image of the south polar cap shows a surface with hundreds of circular depressions. This texture similar in appearance to swiss cheese. Orbit Number: 64535 Latitude: -86.8715 Longitude: 354.786 Instrument: VIS Captured: 2016-07-01 14:50 http://photojournal.jpl.nasa.gov/catalog/PIA20974
Instrumental Analysis in the High School Classroom: UV-Vis Spectroscopy
ERIC Educational Resources Information Center
Erhardt, Walt
2007-01-01
Note is presented on the standard lab from a second year chemistry course. The lab "Determining which of the Seven FD&C Food-Approved Dyes are Used in Making Green Skittles", familiarizes students with the operation of the CHEM2000 UV-Vis spectrophorometer.
Studies of ambient particulate matter (PM) in several venues around the world have shown consistent health impacts vis-a-vis mortality and morbidity. However, recent studies have reported varied and sometimes disparate outcomes with respect to observed effects on cardiopulmonary ...
Global Visualization (GloVis) Viewer
,
2005-01-01
GloVis (http://glovis.usgs.gov) is a browse image-based search and order tool that can be used to quickly review the land remote sensing data inventories held at the U.S. Geological Survey (USGS) Center for Earth Resources Observation and Science (EROS). GloVis was funded by the AmericaView project to reduce the difficulty of identifying and acquiring data for user-defined study areas. Updated daily with the most recent satellite acquisitions, GloVis displays data in a mosaic, allowing users to select any area of interest worldwide and immediately view all available browse images for the following Landsat data sets: Multispectral Scanner (MSS), Multi-Resolution Land Characteristics (MRLC), Orthorectified, Thematic Mapper (TM), Enhanced Thematic Mapper Plus (ETM+), and ETM+ Scan Line Corrector-off (SLC-off). Other data sets include Terra Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and Moderate Resolution Imaging Spectroradiometer (MODIS), Aqua MODIS, and the Earth Observing-1 (EO-1) Advanced Land Imager (ALI) and Hyperion data.
Assessing Jail Inmates’ Proneness to Shame and Guilt: Feeling Bad About the Behavior or the Self?
Tangney, June P.; Stuewig, Jeffrey; Mashek, Debra; Hastings, Mark
2011-01-01
This study of 550 jail inmates (379 male and 171 female) held on felony charges examines the reliability and validity of the Test of Self Conscious Affect –Socially Deviant Version (TOSCA-SD; Hanson & Tangney, 1996) as a measure of offenders’ proneness to shame and proneness to guilt. Discriminant validity (e.g., vis-à-vis self-esteem, negative affect, social desirability/impression management) and convergent validity (e.g., vis-à-vis correlations with empathy, externalization of blame, anger, psychological symptoms, and substance use problems) was supported, paralleling results from community samples. Further, proneness to shame and guilt were differentially related to widely used risk measures from the field of criminal justice (e.g., criminal history, psychopathy, violence risk, antisocial personality). Guilt-proneness appears to be a protective factor, whereas there was no evidence that shame-proneness serves an inhibitory function. Subsequent analyses indicate these findings generalize quite well across gender and race. Implications for intervention and sentencing practices are discussed. PMID:21743757
A broadly neutralizing human monoclonal antibody is effective against H7N9.
Tharakaraman, Kannan; Subramanian, Vidya; Viswanathan, Karthik; Sloan, Susan; Yen, Hui-Ling; Barnard, Dale L; Leung, Y H Connie; Szretter, Kristy J; Koch, Tyree J; Delaney, James C; Babcock, Gregory J; Wogan, Gerald N; Sasisekharan, Ram; Shriver, Zachary
2015-09-01
Emerging strains of influenza represent a significant public health threat with potential pandemic consequences. Of particular concern are the recently emerged H7N9 strains which cause pneumonia with acute respiratory distress syndrome. Estimates are that nearly 80% of hospitalized patients with H7N9 have received intensive care unit support. VIS410, a human antibody, targets a unique conserved epitope on influenza A. We evaluated the efficacy of VIS410 for neutralization of group 2 influenza strains, including H3N2 and H7N9 strains in vitro and in vivo. VIS410, administered at 50 mg/kg, protected DBA mice infected with A/Anhui/2013 (H7N9), resulting in significant survival benefit upon single-dose (-24 h) or double-dose (-12 h, +48 h) administration (P < 0.001). A single dose of VIS410 at 50 mg/kg (-12 h) combined with oseltamivir at 50 mg/kg (-12 h, twice daily for 7 d) in C57BL/6 mice infected with A/Shanghai 2/2013 (H7N9) resulted in significant decreased lung viral load (P = 0.002) and decreased lung cytokine responses for nine of the 11 cytokines measured. Based on these results, we find that VIS410 may be effective either as monotherapy or combined with antivirals in treating H7N9 disease, as well as disease from other influenza strains.
Ikeogu, Ugochukwu N; Davrieux, Fabrice; Dufour, Dominique; Ceballos, Hernan; Egesi, Chiedozie N; Jannink, Jean-Luc
2017-01-01
Portable Vis/NIRS are flexible tools for fast and unbiased analyses of constituents with minimal sample preparation. This study developed calibration models for dry matter content (DMC) and carotenoids in fresh cassava roots using a portable Vis/NIRS system. We examined the effects of eight data pre-treatment combinations on calibration models and assessed calibrations on processed and intact root samples. We compared Vis/NIRS derived-DMC to other phenotyping methods. The results of the study showed that the combination of standard normal variate and de-trend (SNVD) with first derivative calculated on two data points and no smoothing (SNVD+1111) was adequate for a robust model. Calibration performance was higher with processed than the intact root samples for all the traits although intact root models for some traits especially total carotenoid content (TCC) (R2c = 96%, R2cv = 90%, RPD = 3.6 and SECV = 0.63) were sufficient for screening purposes. Using three key quality traits as templates, we developed models with processed fresh root samples. Robust calibrations were established for DMC (R2c = 99%, R2cv = 95%, RPD = 4.5 and SECV = 0.9), TCC (R2c = 99%, R2cv = 91%, RPD = 3.5 and SECV = 2.1) and all Trans β-carotene (ATBC) (R2c = 98%, R2cv = 91%, RPD = 3.5 and SECV = 1.6). Coefficient of determination on independent validation set (R2p) for these traits were also satisfactory for ATBC (91%), TCC (88%) and DMC (80%). Compared to other methods, Vis/NIRS-derived DMC from both intact and processed roots had very high correlation (>0.95) with the ideal oven-drying than from specific gravity method (0.49). There was equally a high correlation (0.94) between the intact and processed Vis/NIRS DMC. Therefore, the portable Vis/NIRS could be employed for the rapid analyses of DMC and quantification of carotenoids in cassava for nutritional and breeding purposes.
Xing, Lin; Zheng, Xiaoyu; Sun, Wenyu; Yuan, Hua; Hu, Lei; Yan, Zhengquan
2018-06-05
A multi-hydroxyl Schiff-base derivative, N-2'-hydroxyl-1'-naphthyl methylene-2-amino phenol (HNMAP), was synthesized and characterized by FTIR, 1 H NMR and UV-vis spectroscopy. It was noted to find there was great effect for solvent and pH on the UV-vis spectroscopy of HNMAP. Especially, some metal ions could make its UV-vis spectra changed regularly with different time-resolved effects. For example, a real-time and multi-wavelength response to Fe 2+ at 520 nm, 466 nm and 447 nm and a quite slow one about 26 min to Fe 3+ at 447 nm and 466 nm, respectively. Under the optimized conditions, the changes in the corresponding absorption intensities at above wavelengths were in proportion to c Fe 2+ or c Fe 3+ during respectively partitioned linear ranges, which realized to quantitatively detect Fe 2+ or Fe 3+ with a large linear range more than two orders of magnitude. A 1:1 complex mode for HNMAP-Fe 2+ and 1:2 for HNMAP-Fe 3+ were proposed from UV-vis spectral titration and Job's plot. HNMAP would be a potential sensor for colorimetric detection of Fe 2+ and Fe 3+ in practice. Copyright © 2018 Elsevier B.V. All rights reserved.
NASA Astrophysics Data System (ADS)
Özkınalı, Sevil; Çavuş, M. Serdar; Ceylan, Abdullah; Gür, Mahmut
2017-12-01
To the best of our knowledge, this is the first study reporting the synthesis and characterization of o,o‧-dihydroxyazo dyes bearing an acryloyl group. The o,o‧-dihydroxyazo dyes were synthesized through coupling of resorcinol with the diazonium salts of 2-amino-4-methylphenol, 2-aminophenol, 2-amino-4-chlorophenol, and 2-amino-4-nitrophenol. Their acryloyl derivatives were synthesized using metallic sodium and acryloyl chloride under an inert atmosphere. Characterization of the compounds was conducted using infrared (IR), ultraviolet-visible (UV-vis), proton nuclear magnetic resonance (1H NMR), and carbon nuclear magnetic resonance (13C NMR) spectroscopic methods. The tautomerism of the synthesized compounds' was also evaluated. The results were compared with theoretical results obtained by density functional theory (DFT). The DFT calculations were performed to obtain ground-state optimized geometries and calculate the relevant electronic and chemical reactivity parameters. Furthermore, possible tautomers deduced from the UV-vis spectra were investigated using theoretical calculations. Both the IR and NMR spectral data showed that azo tautomers predominate in the solid state and DMSO solvent. The effects of pH, solvent, and substituent on the predominant tautomers were further investigated through UV-vis spectroscopy. The results indicate that hydrazone tautomers were dominant at pH 12 in dimethylformamide (DMF), whereas azo tautomers were dominant at pH 2 in EtOH or CHCl3.
A Look at Technologies Vis-a-vis Information Handling Techniques.
ERIC Educational Resources Information Center
Swanson, Rowena W.
The paper examines several ideas for information handling implemented with new technologies that suggest directions for future development. These are grouped under the topic headings: Handling Large Data Banks, Providing Personalized Information Packages, Providing Information Specialist Services, and Expanding Man-Machine Interaction. Guides in…
Aerosol column absorption measurements using co-located UV-MFRSR and AERONET CIMEL instruments
NASA Astrophysics Data System (ADS)
Krotkov, N.; Labow, G.; Herman, J.; Slusser, J.; Tree, R.; Janson, G.; Durham, B.; Eck, T.; Holben, B.
2009-08-01
Column aerosol absorption properties in the visible wavelengths are measured routinely in worldwide locations by NASA AERONET network (http://aeronet.gsfc.nasa.gov), while similar optical properties in UV can be derived from diffuse and global irradiance measurements measured with Multifilter Rotating Shadowband Radiometer (MFRSR) instruments of the USDA UV-MFRSR network (http://uvb.nrel.colostate.edu). To enable direct comparisons between the two techniques, we have modified our UV-MFRSR by replacing standard 300nm filter with 440nm filter used in AERONET network. The modified UV/VIS-MFRSR has been mostly deployed at AERONET calibration site at NASA GSFC in Greenbelt, MD, but also at number of field campaigns. While the UV-MSFRSR instrument is highly susceptible to calibration drifts, these drifts can be accurately assessed using co-located AERONET direct-sun AOT data. In 2006 quartz dome has been installed atop the MFRSR diffuser, which stabilized calibration drifts in 2007-2009. After correcting for remaining calibration changes, the AOT and single scattering albedo (SSA) at the UV wavelengths can be accurately inferred by fitting the measurements of global and diffuse atmospheric transmittances with the forward RT model at each UV-MFRSR spectral channel. Derived AOT and SSA at common wavelength 440nm by two different techniques are generally in good agreement. We also found that SSA becomes smaller in the UV wavelengths and has strong wavelength dependence across blue and near-UV spectral range. The measured enhanced UV absorption might suggest the presence of selectively UV absorbing aerosols. High spectral resolution SSA measurements in UV-VIS wavelengths are called for.
CAMBerVis: visualization software to support comparative analysis of multiple bacterial strains.
Woźniak, Michał; Wong, Limsoon; Tiuryn, Jerzy
2011-12-01
A number of inconsistencies in genome annotations are documented among bacterial strains. Visualization of the differences may help biologists to make correct decisions in spurious cases. We have developed a visualization tool, CAMBerVis, to support comparative analysis of multiple bacterial strains. The software manages simultaneous visualization of multiple bacterial genomes, enabling visual analysis focused on genome structure annotations. The CAMBerVis software is freely available at the project website: http://bioputer.mimuw.edu.pl/camber. Input datasets for Mycobacterium tuberculosis and Staphylocacus aureus are integrated with the software as examples. m.wozniak@mimuw.edu.pl Supplementary data are available at Bioinformatics online.
Lunardi, Adriana C; Porras, Desiderio C; Barbosa, Renata Cc; Paisani, Denise M; Marques da Silva, Cibele C B; Tanaka, Clarice; Carvalho, Celso R F
2014-03-01
Aging causes physiological and functional changes that impair pulmonary function. Incentive spirometry is widely used for lung expansion, but the effects of volume-oriented incentive spirometry (VIS) versus flow-oriented incentive spirometry (FIS) on chest wall volumes, inspiratory muscle activity, and thoracoabdominal synchrony in the elderly are poorly understood. We compared VIS and FIS in elderly subjects and healthy adult subjects. Sixteen elderly subjects (9 women, mean ± SD age 70.6 ± 3.9 y, mean ± SD body mass index 23.8 ± 2.5 kg/m(2)) and 16 healthy adults (8 women, mean ± age 25.9 ± 4.3 y, mean ± body mass index 23.6 ± 2.4 kg/m(2)) performed quiet breathing, VIS, and FIS in randomized sequence. Chest wall kinematics (via optoelectronic plethysmography) and inspiratory muscle activity (via surface electromyography) were assessed simultaneously. Synchrony between the superior thorax and abdominal motion was calculated (phase angle). In the elderly subjects both types of incentive spirometry increased chest wall volumes similarly, whereas in the healthy adult subjects VIS increased the chest wall volume more than did FIS. FIS and VIS triggered similar lower thoracoabdominal synchrony in the elderly subjects, whereas in the healthy adults FIS induced lower synchrony than did VIS. FIS required more muscle activity in the elderly subjects to create an increase in chest wall volume. Incentive spirometry performance is influenced by age, and the differences between elderly and healthy adults response should be considered in clinical practice.
NASA Astrophysics Data System (ADS)
Dalton, Rebecca Marie
The development of student's mental models of chemical substances and processes at the molecular level was studied in a three-phase project. Animations produced in the VisChem project were used as an integral part of the chemistry instruction to help students develop their mental models. Phase one of the project involved examining the effectiveness of using animations to help first-year university chemistry students develop useful mental models of chemical phenomena. Phase two explored factors affecting the development of student's mental models, analysing results in terms of a proposed model of the perceptual processes involved in interpreting an animation. Phase three involved four case studies that served to confirm and elaborate on the effects of prior knowledge and disembedding ability on student's mental model development, and support the influence of study style on learning outcomes. Recommendations for use of the VisChem animations, based on the above findings, include: considering the prior knowledge of students; focusing attention on relevant features; encouraging a deep approach to learning; using animation to teach visual concepts; presenting ideas visually, verbally and conceptually; establishing 'animation literacy'; minimising cognitive load; using animation as feedback; using student drawings; repeating animations; and discussing 'scientific modelling'.
Vis-A-Plan /visualize a plan/ management technique provides performance-time scale
NASA Technical Reports Server (NTRS)
Ranck, N. H.
1967-01-01
Vis-A-Plan is a bar-charting technique for representing and evaluating project activities on a performance-time basis. This rectilinear method presents the logic diagram of a project as a series of horizontal time bars. It may be used supplementary to PERT or independently.
NASA Astrophysics Data System (ADS)
Długokęcka, Marta; Łuczak, Justyna; Polkowska, Żaneta; Zaleska-Medynska, Adriana
2017-05-01
A series of microemulsion (ME) system, constituted by different water to surfactant molar ratios (Wo) and oil to surfactant mass ratios (S), have been applied for Pd-TiO2 preparation. The effect of ME properties on the morphology of Pd nanoparticles formed at TiO2 surface and an effect of Pd size and distribution on the surface and photocatalytic properties of Pd-TiO2 were investigated. Microemulsion systems were characterized by means of viscosity, density, dynamic light scattering as well as surface tension measurements to find a correlation between the conditions of Pd nanoparticles formation, their morphology and photocatalyst features. The photocatalysts were characterized by transmission electron microscopy (TEM), X-ray diffraction analysis (XRD), UV-vis diffuse-reflectance spectroscopy (DRS), BET surface area and elemental analysis. The photocatalytic properties of Pd-modified TiO2 particles were studied in a model reaction of phenol photodegradation under Vis irradiation, as well as active species involved in the photocatalytic reaction were determined. Microemulsion composition was found to be a crucial parameter in determining the features of the TiO2-based photocatalysts covered by metallic nanoparticles. The highest photocatalytic activity under Vis radiation was observed for the Pd-TiO2 sample (average diameter 2.4 nm) obtained using 0.1 mol% Pd in the ME system containing 1.5 wt% of water and 82.8 wt% of cyclohexane with average droplet size of 2.83 ± 0.18 nm. In this regard, synthesis of such metal-semiconductor composites through the microemulsion route should always be preceded by investigation of ME properties in order to the eliminate the inhibitory effect of ME internal structure.
Health Information in Chinese, Simplified (Mandarin dialect) (简体中文)
... Translations Bacterial Infections Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - 简体中文 ( ...
Automated cart with VIS/NIR hyperspectral reflectance and fluorescence imaging capabilities
USDA-ARS?s Scientific Manuscript database
A system to take high-resolution VIS/NIR hyperspectral reflectance and fluorescence images in outdoor fields using ambient lighting or a pulsed laser (355 nm), respectively, for illumination was designed, built, and tested. Components of the system include a semi-autonomous cart, a gated-intensified...
Quantification of taurine in energy drinks using ¹H NMR.
Hohmann, Monika; Felbinger, Christine; Christoph, Norbert; Wachter, Helmut; Wiest, Johannes; Holzgrabe, Ulrike
2014-05-01
The consumption of so called energy drinks is increasing, especially among adolescents. These beverages commonly contain considerable amounts of the amino sulfonic acid taurine, which is related to a magnitude of various physiological effects. The customary method to control the legal limit of taurine in energy drinks is LC-UV/vis with postcolumn derivatization using ninhydrin. In this paper we describe the quantification of taurine in energy drinks by (1)H NMR as an alternative to existing methods of quantification. Variation of pH values revealed the separation of a distinct taurine signal in (1)H NMR spectra, which was applied for integration and quantification. Quantification was performed using external calibration (R(2)>0.9999; linearity verified by Mandel's fitting test with a 95% confidence level) and PULCON. Taurine concentrations in 20 different energy drinks were analyzed by both using (1)H NMR and LC-UV/vis. The deviation between (1)H NMR and LC-UV/vis results was always below the expanded measurement uncertainty of 12.2% for the LC-UV/vis method (95% confidence level) and at worst 10.4%. Due to the high accordance to LC-UV/vis data and adequate recovery rates (ranging between 97.1% and 108.2%), (1)H NMR measurement presents a suitable method to quantify taurine in energy drinks. Copyright © 2013 Elsevier B.V. All rights reserved.
Photo-oxidation of cork manufacturing wastewater.
Silva, Carla A; Madeira, Luis M; Boaventura, Rui A; Costa, Carlos A
2004-04-01
Several photo-activated processes have been investigated for oxidation of a cork manufacturing wastewater. A comparative activity study is made between different homogeneous (H2O2/UV-Vis and H2O2/Fe2+/UV-Vis) and heterogeneous (TiO2/UV-Vis and TiO2/H2O2/UV-Vis) systems, with degradation performances being evaluated in terms of total organic carbon (TOC) removal. Results obtained in a batch photo-reactor show that photo-catalysis with TiO2 is not suitable for this kind of wastewater while the H2O2/UV-Vis oxidation process, for which the effect of some operating conditions was investigated, allows to remove 39% of TOC after 4 h of operation (for C(H2O2)=0.59 M, pH=10 and T=35 degrees C). The combined photo-activated process, i.e., using both TiO2 and H2O2, yields an overall TOC decrease of 46% (for C(TiO2)=1.0 gl(-1)). The photo-Fenton process proved to be the most efficient, proceeds at a much higher oxidation rate and allows to achieve 66% mineralization in just 10 min of reaction time (for C(H2O2)=0.31 M, T=30 degrees C, Fe2+:H2O2=0.12 (mol) and pH=3.2).
Subbaraj, P; Ramu, A; Raman, N; Dharmaraja, J
2014-01-03
A novel bidentate Schiff base ligand has been synthesized using 2,4-dihydroxybenzophenone and aniline. Its mixed ligand complexes of MAB type [M=Mn(II), Co(II), Ni(II), Cu(II) and Zn(II); HA=Schiff base and B=2-aminophenol/2-aminobenzoic acid] have been synthesized and characterized on the basis of spectral data UV-Vis, IR, (1)H NMR, FAB-Mass, EPR, SEM and magnetic studies. All the complexes were soluble in DMF and DMSO. Elemental analysis and molar conductance values indicate that the complexes are non-electrolytes. HA binds with M(II) ions through azomethine and deprotonated phenolic group and B binds through the primary amine group and deprotonated phenolic/carboxylic groups. Using FAB-Mass the cleavage pattern of the ligand (HA) has been established. All the complexes adopt octahedral geometry around the metal ions. It has been confirmed with the help of UV-Vis, IR, (1)H NMR and FAB-Mass spectral data. DNA binding activities of the complexes 1d and 2d are studied by UV-Vis spectroscopy and cleavage studies of Schiff base ligand and its complexes 1d and 2d have been by agarose gel electrophoresis method. In vitro biological activities of the free ligand (HA) and their metal complexes (1a-1e and 2a-2e) were screened against few bacteria, Escherichia coli, Staphylococcus saphyphiticus, Staphylococcus aureus, Pseudomonas aeruginosa and fungi Aspergillus niger, Enterobacter species, Candida albicans by well diffusion technique. Copyright © 2013 Elsevier B.V. All rights reserved.
Catholic Theological Education in a Religiously Pluralistic Age
ERIC Educational Resources Information Center
Lefebure, Leo D.
2006-01-01
This article describes the transformation of Catholic theological education over the last fifty years from a highly defensive posture vis-a-vis other religions toward dialogical engagement with members of other religions and all persons of good will. Until Vatican II, most Catholic theologians and officials distrusted exploration of other…
The Three Fs of Classroom Management
ERIC Educational Resources Information Center
Daniels, Mark L.
2009-01-01
This article describes a cohesive theory of classroom management, developed by the author. This "three Fs" theory, predicated upon extant empiricism and scholarship vis-a-vis classroom management, was devised and implemented over several semesters within a field-based course at the University of Texas at Austin for preservice mathematics majors…
Elementary Teachers' Perceptions of Elementary Principals' Effectiveness
ERIC Educational Resources Information Center
Fridenvalds, Kriss R.
2012-01-01
This dissertation examined the beliefs of elementary teachers to determine if their perceptions of effective principal leadership align to transformational leadership theory vis-a-vis the Educational Leadership Policy Standards (ELPS). A phenomenological, single-case study approach was utilized by means of a mixed-methodological, Web-based survey,…
NASA Astrophysics Data System (ADS)
Jevtić, Dubravka R.; Avramov Ivić, Milka L.; Reljin, Irini S.; Reljin, Branimir D.; Plavec, Goran I.; Petrović, Slobodan D.; Mijin, Dušan Ž.
2014-06-01
The automated, computer-aided method for differentiation and classification of malignant (M) from benign (B) cases, by analyzing the UV/VIS spectra of pleural effusions is described. It was shown that by two independent objective features, the maximum of Katz fractal dimension (KFDmax) and the area under normalized UV/VIS absorbance curve (Area), highly reliable M-B classification is possible. In the Area-KFDmax space M and B samples are linearly separable permitting thus the use of linear support vector machine as a classification tool. By analyzing 104 samples of UV/VIS spectra of pleural effusions (88 M and 16 B) collected from patients at the Clinic for Lung Diseases and Tuberculosis, Military Medical Academy in Belgrade, the accuracy of 95.45% for M cases and 100% for B cases are obtained by using the proposed method. It was shown that by applying some modifications, which are suggested in the paper, the accuracy of 100% for M cases can be reached.
Zhang, Wenhui; Cai, Chunxue; Wang, Jing; Mao, Zhen; Li, Yueqiu; Ding, Liang; Shen, Shigang; Dou, Haiyang
2017-08-08
Home-made asymmetrical flow field-flow fractionation (AF4) system, online coupled with ultraviolet/visible (UV/Vis) detector was employed for the separation and size characterization of low density lipoprotein (LDL) in egg yolk plasma. At close to natural condition of egg yolk, the effects of cross flow rate, sample loading, and type of membrane on the size distribution of LDL were investigated. Under the optimal operation conditions, AF4-UV/Vis provides the size distribution of LDL. Moreover, the precision of AF4-UV/Vis method proposed in this work for the analysis of LDL in egg yolk plasma was evaluated. The intra-day precisions were 1.3% and 1.9% ( n =7) and the inter-day precisions were 2.4% and 2.3% ( n =7) for the elution peak height and elution peak area of LDL, respectively. Results reveal that AF4-UV/Vis is a useful tool for the separation and size characterization of LDL in egg yolk plasma.
The Nature of Prejudice Revisited: Implications for Counseling Intervention.
ERIC Educational Resources Information Center
Ponterotto, Joseph G.
1991-01-01
Presents perspective on prejudice and counseling's role in prejudice prevention. Documents increasing race-based intergroup conflict; explaining conflict vis-a-vis racial identity theory, rapidly changing demographics, and Flight or Fight Response Theory of Racial Stress. Presents developmentally based interventions across elementary, high school,…
MODELING ACUTE EXPOSURE TO SOLAR RADIATION
One of the major technical challenges in calculating solar flux on the human form has been the complexity of the surface geometry (i.e., the surface normal vis a vis the incident radiation). The American Cancer Society reports that over 80% of skin cancers occur on the face, he...
Supersonic transport vis-a-vis energy savings
NASA Technical Reports Server (NTRS)
Cormery, G.
1979-01-01
The energy and economic saving modifications in supersonic transportation are studied. Modifications in the propulsion systems and in the aerodynamic configurations of the Concorde aircraft to reduce noise generation and increase fuel efficiency are discussed. The conversion of supersonic aircraft from fuel oils to synthetic fuels is examined.
Zheng, Dong; Yuan, Xiang-Ai; Ma, Haibo; Li, Xiaoxiong; Wang, Xizhang; Liu, Ziteng
2018-01-01
Cresol is a prototype molecule in understanding intermolecular interactions in material and biological systems, because it offers different binding sites with various solvents and protonation states under different pH values. It is found that the UV/Vis absorption spectra of o-cresol in aromatic solvents (benzene, toluene) are characterized by a sharp peak, unlike the broad double-peaks in 11 non-aromatic solvents. Both molecular dynamics simulations and electronic structure calculations revealed the formation of intermolecular π-complexation between o-cresol and aromatic solvents. The thermal movements of solvent and solute molecules render the conformations of o-cresol changing between trans and cis isomers. The π-interaction makes the cis configuration a dominant isomer, hence leading to the single keen-edged UV/Vis absorption peak at approximately 283 nm. The free conformation changes between trans and cis in aqueous solution rationalize the broader absorption peaks in the range of 260–280 nm. The pH dependence of the UV/Vis absorption spectra in aqueous solutions is also rationalized by different protonation states of o-cresol. The explicit solvent model with long-ranged interactions is vital to describe the effects of π-complexation and electrostatic interaction on the UV/Vis absorption spectra of o-cresol in toluene and alkaline aqueous (pH > 10.3) solutions, respectively. PMID:29657794
Zheng, Dong; Yuan, Xiang-Ai; Ma, Haibo; Li, Xiaoxiong; Wang, Xizhang; Liu, Ziteng; Ma, Jing
2018-03-01
Cresol is a prototype molecule in understanding intermolecular interactions in material and biological systems, because it offers different binding sites with various solvents and protonation states under different pH values. It is found that the UV/Vis absorption spectra of o -cresol in aromatic solvents (benzene, toluene) are characterized by a sharp peak, unlike the broad double-peaks in 11 non-aromatic solvents. Both molecular dynamics simulations and electronic structure calculations revealed the formation of intermolecular π-complexation between o -cresol and aromatic solvents. The thermal movements of solvent and solute molecules render the conformations of o -cresol changing between trans and cis isomers. The π-interaction makes the cis configuration a dominant isomer, hence leading to the single keen-edged UV/Vis absorption peak at approximately 283 nm. The free conformation changes between trans and cis in aqueous solution rationalize the broader absorption peaks in the range of 260-280 nm. The pH dependence of the UV/Vis absorption spectra in aqueous solutions is also rationalized by different protonation states of o -cresol. The explicit solvent model with long-ranged interactions is vital to describe the effects of π-complexation and electrostatic interaction on the UV/Vis absorption spectra of o -cresol in toluene and alkaline aqueous (pH > 10.3) solutions, respectively.
NASA Astrophysics Data System (ADS)
Gür, Mahmut; Şener, Nesrin; Muğlu, Halit; Çavuş, M. Serdar; Özkan, Osman Emre; Kandemirli, Fatma; Şener, İzzet
2017-07-01
In the study, some new 1,3,4-thiadiazole compounds were synthesized and we have reported identification of the structures by using UV-Vis, FT-IR, 1H NMR, 13C NMR and Mass spectroscopic methods. Antimicrobial activities of the compounds against three microorganisms, namely, Candida albicans ATCC 26555, Staphylococcus aureus ATCC 9144, and Escherichia coli ATCC 25922 were investigated by using disk diffusion method. These thiadiazoles exhibited an antimicrobial activity against Staphylococcus aureus and Candida albicans. The experimental data was supported by the quantum chemical calculations. Density functional theory (DFT) calculations were carried out to obtain the ground state optimized geometries of the molecules using the B3LYP, M06 and PBE1PBE methods with 3-21 g, 4-31 g, 6-311++g(2d,2p), cc-pvtz and cc-pvqz basis sets in the different combinations. Frontier molecular orbitals (FMOs) energies, band gap energies and some chemical reactivity parameters were calculated by using the aforementioned methods and basis sets, and the results were also compared with the experimental UV-Vis data.
Prediction of Pork Longissimus Lean Color Stability Using VIS/NIR
USDA-ARS?s Scientific Manuscript database
Insufficient case-life is a costly problem facing pork processors. To assess Visible and Near-Infrared (VIS/NIR) spectroscopy as a technology to sort pork loins according to lean color stability, center-cut pork loins (n = 1208) were selected from the boning lines of four large-scale pork processor...
Feminism Vis a Vis Social Change.
ERIC Educational Resources Information Center
Adickes, Sandra
While demonstrating the potential of feminist education to promote positive social change, experiences with the women's studies programs at Staten Island Community College (SICC) and Brooklyn College (BC) also dramatize the need for women's studies to overcome factionalism and middle-class elitism in order to construct a pedagogy for oppressed…
Candidate Socioemotional Remediation Program for Individuals with Intellectual Disability
ERIC Educational Resources Information Center
Glaser, Bronwyn; Lothe, Amelie; Chabloz, Melanie; Dukes, Daniel; Pasca, Catherine; Redoute, Jerome; Eliez, Stephan
2012-01-01
The authors developed a computerized program, Vis-a-Vis (VAV), to improve socioemotional functioning and working memory in children with developmental disabilities. The authors subsequently tested whether participants showed signs of improving the targeted skills. VAV is composed of three modules: Focus on the Eyes, Emotion Recognition and…
VisSearch: A Collaborative Web Searching Environment
ERIC Educational Resources Information Center
Lee, Young-Jin
2005-01-01
VisSearch is a collaborative Web searching environment intended for sharing Web search results among people with similar interests, such as college students taking the same course. It facilitates students' Web searches by visualizing various Web searching processes. It also collects the visualized Web search results and applies an association rule…
Tense-Aspect Processing in Second Language Learners
ERIC Educational Resources Information Center
Chan, Ho Leung
2012-01-01
This dissertation provides a language processing perspective on the study of second language acquisition (SLA) of tense and aspect. Of special interest are the universal vis-a-vis language-specific dimensions of temporal and aspectual semantics involved. According to the Aspect Hypothesis (AH, e.g. Andersen & Shirai, 1994), the initial…
Semio-Pragmatic Analysis of Cartoons Discourse: A Step towards Semiotranslation
ERIC Educational Resources Information Center
AlBzour, Naser Naif
2011-01-01
The primary concern of this study is to explore the subtle implications of the "Semiotranslation Approach vis-a-vis" analyzing the semiotic elements of discourse in Jordanian cartoons as creative artistic texts in which various signs manifest simultaneous interaction, thus achieving both entertainment and purposeful satire. Therefore,…
The 1977 National Women's Conference in Houston--Gains and Disappointments for Hispanas.
ERIC Educational Resources Information Center
Burciaga, Cecilia P.
1978-01-01
The article presents the outcomes of the women's conference, not only as a single event, but also as an analysis of the dynamics that were, and are, currently operating in the women's movement vis-a-vis Hispanic women in general, and Chicanas in particular. (NQ)
Instrumentation: Photodiode Array Detectors in UV-VIS Spectroscopy. Part II.
ERIC Educational Resources Information Center
Jones, Dianna G.
1985-01-01
A previous part (Analytical Chemistry; v57 n9 p1057A) discussed the theoretical aspects of diode ultraviolet-visual (UV-VIS) spectroscopy. This part describes the applications of diode arrays in analytical chemistry, also considering spectroelectrochemistry, high performance liquid chromatography (HPLC), HPLC data processing, stopped flow, and…
NASA Astrophysics Data System (ADS)
Watanabe, Shinta; Sato, Toshikazu; Yoshida, Tomoko; Nakaya, Masato; Yoshino, Masahito; Nagasaki, Takanori; Inaba, Yusuke; Takeshita, Kenji; Onoe, Jun
2018-04-01
We have investigated the chemical forms of palladium (Pd) ion in nitric acid solution, using XAFS/UV-vis spectroscopic and first-principles methods in order to develop the disposal of high-level radioactive nuclear liquid wastes (HLLW: radioactive metal ions in 2 M nitric acid solution). The results of theoretical calculations and XAFS/UV-vis spectroscopy indicate that Pd is a divalent ion and forms a square-planar complex structure coordinated with four nitrate ions, [Pd(NO3)4]2-, in nitric acid solution. This complex structure is also thermodynamically predicted to be most stable among complexes [Pd(H2O)x(NO3)4-x]x-2 (x = 0-4). Since the overall feature of UV-vis spectra of the Pd complex was independent of nitric acid concentration in the range 1-6 M, the structure of the Pd complex remains unchanged in this range. Furthermore, we examined the influence of γ-ray radiation on the [Pd(NO3)4]2- complex, using UV-vis spectroscopy, and found that UV-vis spectra seemed not to be changed even after 1.0 MGy irradiation. This implies that the Pd complex structure will be still stable in actual HLLW. These findings obtained above are useful information to develop the vitrification processes for disposal of HLLW.
Liu, Xiaoxia; Tian, Miaomiao; Camara, Mohamed Amara; Guo, Liping; Yang, Li
2015-10-01
We present sequential CE analysis of amino acids and L-asparaginase-catalyzed enzyme reaction, by combing the on-line derivatization, optically gated (OG) injection and commercial-available UV-Vis detection. Various experimental conditions for sequential OG-UV/vis CE analysis were investigated and optimized by analyzing a standard mixture of amino acids. High reproducibility of the sequential CE analysis was demonstrated with RSD values (n = 20) of 2.23, 2.57, and 0.70% for peak heights, peak areas, and migration times, respectively, and the LOD of 5.0 μM (for asparagine) and 2.0 μM (for aspartic acid) were obtained. With the application of the OG-UV/vis CE analysis, sequential online CE enzyme assay of L-asparaginase-catalyzed enzyme reaction was carried out by automatically and continuously monitoring the substrate consumption and the product formation every 12 s from the beginning to the end of the reaction. The Michaelis constants for the reaction were obtained and were found to be in good agreement with the results of traditional off-line enzyme assays. The study demonstrated the feasibility and reliability of integrating the OG injection with UV/vis detection for sequential online CE analysis, which could be of potential value for online monitoring various chemical reaction and bioprocesses. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Health Information in Armenian (Հայերեն)
... Section Bacterial Infections Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - Հայերեն ( ...
Bacterial Infections - Multiple Languages
... العربية) Expand Section Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - العربية ( ...
Health Information in Russian (Русский)
... Translations Bacterial Infections Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - English PDF Vaccine Information Statement (VIS) -- Pneumococcal Polysaccharide Vaccine (PPSV): What You Need to Know - Русский ( ...
Cheng, Zhangxiang; Wang, Tianjie; Li, Xiao; Zhang, Yihe; Yu, Haifeng
2015-12-16
To take full advantage of sunlight for photomechanical materials, NIR-vis-UV light-responsive actuator films of polymer-dispersed liquid crystal (PDLC)/graphene oxide (GO) nanocomposites were fabricated. The strategy is based on phase transition of LCs from nematic to isotropic phase induced by combination of photochemical and photothermal processes in the PDLC/GO nanocomposites. Upon mechanical stretching of the film, both topological shape change and mesogenic alignment occurred in the separated LC domains, enabling the film to respond to NIR-vis-UV light. The homodispersed GO flakes act as photoabsorbent and nanoscale heat source to transfer NIR or VIS light into thermal energy, heating the film and photothermally inducing phase transition of LC microdomains. By utilizing photochemical phase transition of LCs upon UV-light irradiation, one azobenzene dye was incorporated into the LC domains, endowing the nanocomposite films with UV-responsive property. Moreover, the light-responsive behaviors can be well-controlled by adjusting the elongation ratio upon mechanical treatment. The NIR-vis-UV light-responsive PDLC/GO nanocomposite films exhibit excellent properties of easy fabrication, low-cost, and good film-forming and mechanical features, promising their numerous applications in the field of soft actuators and optomechanical systems driven directly by sunlight.
Ultra-accelerated natural sunlight exposure testing facilities
Lewandowski, Allan A.; Jorgensen, Gary J.
2003-08-12
A multi-faceted concentrator apparatus for providing ultra-accelerated natural sunlight exposure testing for sample materials under controlled weathering conditions comprising: facets that receive incident natural sunlight, transmits VIS/NIR and reflects UV/VIS to deliver a uniform flux of UV/VIS onto a sample exposure plane located near a center of a facet array in chamber means that provide concurrent levels of temperature and/or relative humidity at high levels of up to 100.times. of natural sunlight that allow sample materials to be subjected to accelerated irradiance exposure factors for a significant period of time of about 3 to 10 days to provide a corresponding time of about at least a years worth representative weathering of sample materials.
A portable device for detecting fruit quality by diffuse reflectance Vis/NIR spectroscopy
NASA Astrophysics Data System (ADS)
Sun, Hongwei; Peng, Yankun; Li, Peng; Wang, Wenxiu
2017-05-01
Soluble solid content (SSC) is a major quality parameter to fruit, which has influence on its flavor or texture. Some researches on the on-line non-invasion detection of fruit quality were published. However, consumers desire portable devices currently. This study aimed to develop a portable device for accurate, real-time and nondestructive determination of quality factors of fruit based on diffuse reflectance Vis/NIR spectroscopy (520-950 nm). The hardware of the device consisted of four units: light source unit, spectral acquisition unit, central processing unit, display unit. Halogen lamp was chosen as light source. When working, its hand-held probe was in contact with the surface of fruit samples thus forming dark environment to shield the interferential light outside. Diffuse reflectance light was collected and measured by spectrometer (USB4000). ARM (Advanced RISC Machines), as central processing unit, controlled all parts in device and analyzed spectral data. Liquid Crystal Display (LCD) touch screen was used to interface with users. To validate its reliability and stability, 63 apples were tested in experiment, 47 of which were chosen as calibration set, while others as prediction set. Their SSC reference values were measured by refractometer. At the same time, samples' spectral data acquired by portable device were processed by standard normalized variables (SNV) and Savitzky-Golay filter (S-G) to eliminate the spectra noise. Then partial least squares regression (PLSR) was applied to build prediction models, and the best predictions results was achieved with correlation coefficient (r) of 0.855 and standard error of 0.6033° Brix. The results demonstrated that this device was feasible to quantitatively analyze soluble solid content of apple.
NASA Astrophysics Data System (ADS)
Chang, Fei; Jiao, Mingzhi; Xu, Quan; Deng, Baoqing; Hu, Xuefeng
2018-03-01
A series of mesoporous iron-titanium-containing silica Fe-TiO2-SBA15 (FTS) were constructed via a facile one-pot hydrothermal route and subsequently characterized by X-ray diffraction patterns, UV-vis diffuse reflection spectroscopy, transmission electron microscopy, scanning electron microscopy, nitrogen adsorption-desorption, X-ray photoelectron spectroscopy, and X-ray energy dispersion spectroscopy. By analyses, these samples possessed ordered two-dimensional hexagonal mesoporous structures, mainly involving mixed dual-phases of anatase and rutile TiO2, like commercial titania P25. The UV-vis diffuse reflection spectra demonstrated the presence of Fe species that was further confirmed by the X-ray photoelectron spectra and X-ray energy dispersion spectrum. The existence of Fe species in form of Fe3+ cations played an important role on the phase composition and electronic structure of these samples. With structural and morphological merits, these samples exhibited relatively high photocatalytic efficiency toward the degradation of dye methylene blue (MB) and reduction of Cr(VI) under visible-light irradiation, comparing with P25. In addition, among all candidates, the sample with a Fe/Si molar ratio of 0.03 showed the highest catalytic performance under optimal conditions, especially in the coexistence of both MB and Cr(VI), revealing an obviously synergistic effect when the consumption of both contaminants occurred. Finally, a primary catalytic mechanism was speculated on basis of active species capture experiments.
Voicing Solidarity: Linguistic Hospitality and Poststructuralism in the Real World
ERIC Educational Resources Information Center
Phipps, Alison
2012-01-01
Structuralism has dominated the field of applied linguistics, which has consequences for the positioning of applied linguistics "vis-a-vis" policy makers, educational practice, and also theoretical and methodological innovations. These consequences pertain to how the field advocates, takes sides, balances its descriptive modes with its discursive…
School Leadership and Curriculum: German Perspectives
ERIC Educational Resources Information Center
Huber, Stephan; Tulowitzki, Pierre; Hameyer, Uwe
2017-01-01
This article looks at the role of school leadership vis-à-vis the curriculum. First, it offers a brief overview of school leadership in Germany. Next, curriculum development and curriculum research in Germany is briefly recapped. We present empirical data on school leadership preferences, strain experience, and practices as to curriculum work.…
Predicting water-holding capacity of intact chicken broiler breast fillets with Vis/NIR spectroscopy
USDA-ARS?s Scientific Manuscript database
The ability of using visible and near-infrared (Vis/NIR) spectroscopy to predict water-holding capacity (WHC) of intact chicken broiler breast fillets (pectoralis major) was assessed in this study. Boneless and skinless chicken fillets (214 in total) were procured from a commercial processing plant ...
2016-09-21
This VIS image shows part of the South Polar cap. In this region the surface has numerous circular depressions, which give the appearance of a slice of swiss cheese. Orbit Number: 64848 Latitude: -86.7725 Longitude: 355.096 Instrument: VIS Captured: 2016-07-27 09:35 http://photojournal.jpl.nasa.gov/catalog/PIA20993
Employee Development and Turnover Intention: Theory Validation
ERIC Educational Resources Information Center
Rahman, Wali; Nas, Zekeriya
2013-01-01
Purpose: This study aims to examine the pattern of behavior of turnover intentions in developing countries "vis-a-vis" the one in advanced countries through the empirical data from public universities in Khyber Pakhtunkhwa, Pakistan. The study provides empirical evidence from academia in Pakistan, thereby enriching the understanding of…
Extraction of Shrimp Ponds Using Object Oriented Classification vis-a-vis Pixel Based Classification
2004-11-01
302 25th ACRS 2004 Chiang Mai , Thailand B-3.6 Data Processing...Proceedings of the 25th Asian Conference on Remote Sensing, Held in Chiang Mai , Thailand on 22-26 November 2004. Copyrighted; Government Purpose Rights... Chiang Mai , Thailand B-3.6 Data Processing
Interactive Learning System "VisMis" for Scientific Visualization Course
ERIC Educational Resources Information Center
Zhu, Xiaoming; Sun, Bo; Luo, Yanlin
2018-01-01
Now visualization courses have been taught at universities around the world. Keeping students motivated and actively engaged in this course can be a challenging task. In this paper we introduce our developed interactive learning system called VisMis (Visualization and Multi-modal Interaction System) for postgraduate scientific visualization course…
TEFL/TESL Newsletter, Volume 4, Number 4.
ERIC Educational Resources Information Center
Australian Dept. of Education, Canberra. Language Teaching Branch.
This issue is devoted to driving and traffic safety. Based on information found in drivers' manuals from the various Australian states, instructions are given vis-a-vis pedestrians, cyclists and motorcyclists, driving regulations, seat belts, alcohol and drugs, lines and signs, and registration and licensing. Sample questions and suggested…
Visible/near-infrared spectroscopy to predict water holding capacity in broiler breast meat
USDA-ARS?s Scientific Manuscript database
Visible/Near-infrared spectroscopy (Vis/NIRS) was examined as a tool for rapidly determining water holding capacity (WHC) in broiler breast meat. Both partial least squares (PLS) and principal component analysis (PCA) models were developed to relate Vis/NIRS spectra of 85 broiler breast meat sample...
MODELING THE ANATOMICAL DISTRIBUTION OF SUNLIGHT
One of the major technical challenges in calculating solar irradiance on the human form has been the complexity of the surface geometry (i.e. the surface normal vis a vis the incident radiation. Over 80 percent of skin cancers occur on the face, head, and back of the hands. The...
NASA Astrophysics Data System (ADS)
Xu, Fangcheng; Wang, Xin; Xu, Huajia; Wang, Kai
2016-01-01
Tuberculous meningitis (TBM) is a very common infectious disease in the central nervous system. The delay of diagnosing and treating TBM will lead to high disability and mortality of TBM. Hence, it is very important to promptly diagnose TBM early. In this work, we proposed a new method for diagnosing TBM with CSF samples by using UV-Vis absorption spectroscopy. CSF samples from TBM patients and non-TBM persons were compared, and the sensitivity, specificity, accuracy, positive predictive value reached 83.6%, 69.8%, 77.2%, 76.1% respectively. Our work indicated investigation of CSF using UV-Vis absorption spectroscopy might become a potentially useful method for TBM diagnosis.
Naresh, Gollapally; Mandal, Tapas Kumar
2014-12-10
Aurivillius phase layered perovskites, Bi5-xLaxTi3FeO15 (x = 1, 2) are synthesized by solid-state reaction. The compounds are characterized by powder X-ray diffraction (PXD), field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), UV-vis diffuse reflectance (UV-vis DRS), and photoluminescence (PL) spectroscopy. UV-vis DRS data revealed that the compounds are visible light absorbing semiconductors with band gaps ranging from ∼2.0-2.7 eV. Photocatalytic activity studies by Rhodamine B (RhB) degradation under sun-light irradiation showed that these layered oxides are very efficient photocatalysts in mild acidic medium. Scavenger test studies demonstrated that the photogenerated holes and superoxide radicals (O2(•-)) are the active species responsible for RhB degradation over the Aurivillius layered perovskites. Comparison of PL intensity, dye adsorption and ζ-potential suggested that a slow e(-)-h(+) recombination and effective dye adsorption are crucial for the degradation process over these photocatalysts. Moreover, relative positioning of the valence and conduction band edges of the semiconductors, O2/O2(•-), (•)OH/H2O potential and HOMO-LUMO levels of RhB appears to be responsible for making the degradation hole-specific. Photocatalytic cycle tests indicated high stability of the catalysts in the reaction medium without any observable loss of activity. This work shows great potential in developing novel photocatalysts with layered structures for sun-light-driven oxidation and degradation processes largely driven by holes and without any intervention of hydroxyl radicals, which is one of the most common reactive oxygen species (ROS) in many advanced oxidation processes.
Diehl, Eliana Elisabeth; Langdon, Esther Jean; Dias-Scopel, Raquel Paiva
2012-05-01
Indigenous community health workers are part of a strategy developed by Brazil in the last two decades to promote a special healthcare model for indigenous peoples. Their role is designed to deal with various aspects of the special health policy, including the link between the heath team and the community and mediation between scientific and indigenous medical knowledge. Despite a significant increase in the number of indigenous community health workers in recent years, an evaluation of their responsibilities and contributions to the success of special care had not been conducted previously. This article, based on a literature review and original research by the authors, analyzes the role of the indigenous community health workers vis-à-vis their training and participation in health teams in different contexts in Brazil. Considering the importance assigned to the role of indigenous community health workers, this analysis reveals various ambiguities and contradictions that hinder both their performance and their potential contribution to the special health services.
UV-Vis as quantification tool for solubilized lignin following a single-shot steam process.
Lee, Roland A; Bédard, Charles; Berberi, Véronique; Beauchet, Romain; Lavoie, Jean-Michel
2013-09-01
In this short communication, UV/Vis was used as an analytical tool for the quantification of lignin concentrations in aqueous mediums. A significant correlation was determined between absorbance and concentration of lignin in solution. For this study, lignin was produced from different types of biomasses (willow, aspen, softwood, canary grass and hemp) using steam processes. Quantification was performed at 212, 225, 237, 270, 280 and 287 nm. UV-Vis quantification of lignin was found suitable for different types of biomass making this a timesaving analytical system that could lead to uses as Process Analytical Tool (PAT) in biorefineries utilizing steam processes or comparable approaches. Copyright © 2013 Elsevier Ltd. All rights reserved.
HPV (Human Papillomavirus) Gardasil® Vaccine - what you need to know
... all lots of Gardasil® (quadrivalent HPV vaccine) already distributed in the United States have expired. Continue using this VIS when administering Gardasil®. When all remaining doses have expired in May of 2017, this VIS will be removed.
Photocatalytic antibacterial effects on TiO2-anatase upon UV-A and UV-A/VIS threshold irradiation.
Wu, Yanyun; Geis-Gerstorfer, Jürgen; Scheideler, Lutz; Rupp, Frank
2016-01-01
Photocatalysis mediated by the anatase modification of titanium dioxide (TiO2) has shown antibacterial effects in medical applications. The aim of this study was to investigate the possibility of expanding the excitation wavelengths for photocatalytic antibacterial effects from ultraviolet (UV) into the visible light range. After deposition of salivary pellicle and adhesion of Streptococcus gordonii on anatase, different irradiation protocols were applied to induce photocatalysis: ultraviolet A (UV-A) > 320 nm; ultraviolet/visible (UV-A/VIS) light > 380 nm and > 390 nm; and VIS light 400-410 nm. A quartz crystal microbalance with dissipation (QCM-D) tests and microscopic examination were used to observe the photoinduced antibacterial effects. Salivary pellicle could be photocatalytically decomposed under all irradiation protocols. In contrast, effective photocatalytic attack of bacteria could be observed by UV-A as well as by UV-A/VIS at 380 nm < λ < 390 nm only. Wavelengths above 380 nm show promise for in situ therapeutic antifouling applications.
Minayo, Maria Cecília de Souza
2015-09-01
This is an interview with Maria Cecília de Souza Minayo, by university lecturers Iara Coelho Zito Guerriero and Maria Lúcia Magalhães Bosi. It reflects the heat of the current debates surrounding implementation of a specific protocol for evaluation of research in the Human and Social Sciences (HSS), vis-à-vis the current rules set by the National Health Council, which have a clearly biomedical bias. The interview covers the difficulties of introducing appropriate and fair rules for judgment of HSS projects, in the face of a hegemonic understanding of the very concept of science by biologists and medical doctors, who tend not to recognize other approaches unless those approaches adopt their frames of reference. In this case, the National Health Council becomes the arena of this polemic, leading researchers in the human and social sciences to ask themselves whether the health sector has the competency to create rules for other areas of knowledge.
Adult Hispanic ESL Students and Graded Readers
ERIC Educational Resources Information Center
Martinez, Liza E.
2017-01-01
This study examined the extent to which graded readers vis-à-vis scaffolded silent reading (ScSR) resulted in increased vocabulary, reading comprehension, and a positive attitude toward reading. A mixed-methods study was administered to two upper-intermediate adult ESL classes at a community college in southwestern Arizona. Both groups took The…
Social Work Education in a Hostile Environment: Programs Under Academic Attack
ERIC Educational Resources Information Center
Shimer, Eliot R.
1977-01-01
Administrative and structural positions of undergraduate social work programs are examined vis a vis other academic disciplines in liberal arts colleges. Causes of departmental dissention both indicating and contraindicating separation are discussed with emphasis on programs operating in a hostile atmosphere or in one that places them at a…
Autonomy in Second Language Phonology: Choice vs. Limits
ERIC Educational Resources Information Center
Moyer, Alene
2017-01-01
Learning a new sound system poses challenges of a social, psychological, and cognitive nature, but the learner's decisions are key to ultimate attainment. This presentation focuses on two essential concepts: CHOICE, or how one wants to sound in the target language; and LIMITS, or various challenges to one's goals vis-a-vis accent. Qualitative and…
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lin, Shaohua, E-mail: linsh75@163.com; Zhang, Xiwang; Sun, Qinju
2013-11-15
Graphical abstract: - Highlights: • Fe-doped TiO{sub 2} immobilized on glass-fiber net were prepared by sol–gel method. • Fe inhibited the phase transition of TiO{sub 2} from anatase to rutile. • The optimal Fe doping dose was around 0.005 wt%. • The optimal calcination temperature was around 600 °C. - Abstract: Iron-doped anatase titanium dioxide catalysts coated on glass-fiber were successfully synthesized by a dip-coating sol–gel method. The prepared catalysts were characterized by scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis, X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy to understand the synthesis mechanism, and their photocatalytic activities weremore » evaluated by photodegradation of phenol under simulated solar irradiation. EDX analysis confirmed the existence of iron in the immobilized catalysts. XRD suggested that the phase transition of the catalysts from anatase to rutile were restrained, and almost pure anatase TiO{sub 2} could retain even the calcination temperature reached 800 °C. The UV-Vis diffuse reflectance spectroscopy of the catalysts showed a red shift and increased photoabsorbance in the visible range for all the doped samples. Iron loading and calcination temperature have obvious influences on photocatalytic activity. In this study, the optimal doping dose and calcination temperature were around 0.005 wt% and 600 °C, respectively.« less
Reference-dependent preferences for maternity wards: an exploration of two reference points.
Neuman, Einat
2014-01-01
It is now well established that a person's valuation of the benefit from an outcome of a decision is determined by the intrinsic "consumption utility" of the outcome itself and also by the relation of the outcome to some reference point. The most notable expression of such reference-dependent preferences is loss aversion. What precisely this reference point is, however, is less clear. This paper claims and provides empirical evidence for the existence of more than one reference point. Using a discrete choice experiment in the Israeli public health-care sector, within a sample of 219 women who had given birth, it is shown that respondents refer to two reference points : (i) a constant scenario that is used in the experiment; and (ii) also the actual state of the quantitative attributes of the service (number of beds in room of hospitalization; and travel time from residence to hospital). In line with the loss aversion theory, it is also shown that losses (vis-à-vis the constant scenario and vis-à-vis the actual state) accumulate and have reinforced effects, while gains do not.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Granger, Brian R.; Chang, Yi -Chien; Wang, Yan
Here, the complexity of metabolic networks in microbial communities poses an unresolved visualization and interpretation challenge. We address this challenge in the newly expanded version of a software tool for the analysis of biological networks, VisANT 5.0. We focus in particular on facilitating the visual exploration of metabolic interaction between microbes in a community, e.g. as predicted by COMETS (Computation of Microbial Ecosystems in Time and Space), a dynamic stoichiometric modeling framework. Using VisANT's unique meta-graph implementation, we show how one can use VisANT 5.0 to explore different time-dependent ecosystem-level metabolic networks. In particular, we analyze the metabolic interaction networkmore » between two bacteria previously shown to display an obligate cross-feeding interdependency. In addition, we illustrate how a putative minimal gut microbiome community could be represented in our framework, making it possible to highlight interactions across multiple coexisting species. We envisage that the "symbiotic layout" of VisANT can be employed as a general tool for the analysis of metabolism in complex microbial communities as well as heterogeneous human tissues.« less
Computational Photophysics in the Presence of an Environment
NASA Astrophysics Data System (ADS)
Nogueira, Juan J.; González, Leticia
2018-04-01
Most processes triggered by ultraviolet (UV) or visible (vis) light in nature take place in complex biological environments. The first step in these photophysical events is the excitation of the absorbing system or chromophore to an electronically excited state. Such an excitation can be monitored by the UV-vis absorption spectrum. A precise calculation of the UV-vis spectrum of a chromophore embedded in an environment is a challenging task that requires the consideration of several ingredients, besides an accurate electronic-structure method for the excited states. Two of the most important are an appropriate description of the interactions between the chromophore and the environment and accounting for the vibrational motion of the whole system. In this contribution, we review the most common theoretical methodologies to describe the environment (including quantum mechanics/continuum and quantum mechanics/molecular mechanics models) and to account for vibrational sampling (including Wigner sampling and molecular dynamics). Further, we illustrate in a series of examples how the lack of these ingredients can lead to a wrong interpretation of the electronic features behind the UV-vis absorption spectrum.
How Can France’s New NATO Policy Be Explained vis-a-vis European Security Cooperation?
2010-05-21
Dunkirk negotiations. The differences stemmed from what should constitute a threat requiring support from an ally; an actual invasion, as the U.K...strategic approaches between the U.K. and France, dating back to the 1947 Treaty of Dunkirk negotiations, were finally coming to an end
2016-10-05
The linear depressions in this VIS image are some of the numerous graben that make up Claritas Fossae. Graben form when two faults cause a block of material to be dropped to a lower elevation. Orbit Number: 65197 Latitude: -35.7709 Longitude: 251.553 Instrument: VIS Captured: 2016-08-25 03:51 http://photojournal.jpl.nasa.gov/catalog/PIA21004
German in Belgium: Linguistic Variation from a Contact Linguistic Point of View.
ERIC Educational Resources Information Center
Nelde, Peter; Darquennes, Jeroen
2002-01-01
Discusses the situation of German Minorities in Old and New Belgium. Describes the process of federalization and its repercussions for East Belgium. Examines linguistic factors vis-a-vis these minorities located along the Germanic-Romance linguistic border. Looks at external linguistic factors and one internal factor and concludes by focusing on…
Resident Assistants as Rule Enforcers versus Friends: An Exploratory Study of Role Conflict
ERIC Educational Resources Information Center
Everett, Diane D.; Loftus, Zachary V.
2011-01-01
Using data from both qualitative interviews and quantitative questionnaires from 32 undergraduate resident assistants (RAs) at a private, residential university, this study explored RAs' role conflict derived from their simultaneous positions as rule enforcers and friends, vis-a-vis their residents. Most RAs reported that they were friends with…
Middle School Mathematics Teachers Panel Perspectives of Instructional Practicess
ERIC Educational Resources Information Center
Ziegler, Cindy
2017-01-01
In a local middle school, students were not meeting standards on the state mathematics tests. The purpose of this qualitative study was to explore mathematics teachers' perspectives on effective mathematics instruction vis-a-vis the principles of the National Council of Teachers of Mathematics (NCTM). Within this framework, the 6 principles in the…
Professionalism: A Comparative Case Study of Teachers, Nurses, and Social Workers
ERIC Educational Resources Information Center
Bair, Mary Antony
2016-01-01
While there are numerous calls to enhance the professionalism of teachers, there is little empirical research in the United States that examines educators' understanding of the concept. This comparative case study compared the conceptualisation of professionalism by faculty and students in a college of education vis-à-vis the conceptualisation of…
A broadly neutralizing human monoclonal antibody is effective against H7N9
Tharakaraman, Kannan; Subramanian, Vidya; Viswanathan, Karthik; Sloan, Susan; Yen, Hui-Ling; Barnard, Dale L.; Leung, Y. H. Connie; Szretter, Kristy J.; Koch, Tyree J.; Delaney, James C.; Babcock, Gregory J.; Wogan, Gerald N.; Sasisekharan, Ram; Shriver, Zachary
2015-01-01
Emerging strains of influenza represent a significant public health threat with potential pandemic consequences. Of particular concern are the recently emerged H7N9 strains which cause pneumonia with acute respiratory distress syndrome. Estimates are that nearly 80% of hospitalized patients with H7N9 have received intensive care unit support. VIS410, a human antibody, targets a unique conserved epitope on influenza A. We evaluated the efficacy of VIS410 for neutralization of group 2 influenza strains, including H3N2 and H7N9 strains in vitro and in vivo. VIS410, administered at 50 mg/kg, protected DBA mice infected with A/Anhui/2013 (H7N9), resulting in significant survival benefit upon single-dose (−24 h) or double-dose (−12 h, +48 h) administration (P < 0.001). A single dose of VIS410 at 50 mg/kg (−12 h) combined with oseltamivir at 50 mg/kg (−12 h, twice daily for 7 d) in C57BL/6 mice infected with A/Shanghai 2/2013 (H7N9) resulted in significant decreased lung viral load (P = 0.002) and decreased lung cytokine responses for nine of the 11 cytokines measured. Based on these results, we find that VIS410 may be effective either as monotherapy or combined with antivirals in treating H7N9 disease, as well as disease from other influenza strains. PMID:26283346
Climate change and human health: Indian context.
Singh, Poonam K; Dhiman, Ramesh C
2012-06-01
The article reviews the issue of climate change and health in the Indian context. The importance of climate change leading to estimated loss of above 2.5 million DALYs in southeast Asia, mortality due to heat waves, and the importance of air quality related respiratory diseases, disasters due to excessive floods, malnutrition due to reduction in rice, maize and sorghum crops etc. Latest work undertaken in India, vis-a-vis current scenario and need for further work has been discussed. There is felt need of further studies on assessing the impact on dengue and chikungunya as the transmission dynamics of these diseases involve water availability, storage and life style, etc. Uncertainties and knowledge gaps identified in the studies undertaken so far have also been highlighted. As regards to vector borne diseases, there is a need to concentrate in the areas which are presently free from malaria and with use of best available tools of interventions in already disease endemic areas like northeastern states, the risk of climate change impacts can be minimized.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mitchell, Christopher J; Ahrens, James P; Wang, Jun
2010-10-15
Petascale simulations compute at resolutions ranging into billions of cells and write terabytes of data for visualization and analysis. Interactive visuaUzation of this time series is a desired step before starting a new run. The I/O subsystem and associated network often are a significant impediment to interactive visualization of time-varying data; as they are not configured or provisioned to provide necessary I/O read rates. In this paper, we propose a new I/O library for visualization applications: VisIO. Visualization applications commonly use N-to-N reads within their parallel enabled readers which provides an incentive for a shared-nothing approach to I/O, similar tomore » other data-intensive approaches such as Hadoop. However, unlike other data-intensive applications, visualization requires: (1) interactive performance for large data volumes, (2) compatibility with MPI and POSIX file system semantics for compatibility with existing infrastructure, and (3) use of existing file formats and their stipulated data partitioning rules. VisIO, provides a mechanism for using a non-POSIX distributed file system to provide linear scaling of 110 bandwidth. In addition, we introduce a novel scheduling algorithm that helps to co-locate visualization processes on nodes with the requested data. Testing using VisIO integrated into Para View was conducted using the Hadoop Distributed File System (HDFS) on TACC's Longhorn cluster. A representative dataset, VPIC, across 128 nodes showed a 64.4% read performance improvement compared to the provided Lustre installation. Also tested, was a dataset representing a global ocean salinity simulation that showed a 51.4% improvement in read performance over Lustre when using our VisIO system. VisIO, provides powerful high-performance I/O services to visualization applications, allowing for interactive performance with ultra-scale, time-series data.« less
Yu, Jung-Hoon; Nam, Sang-Hun; Lee, Ji Won; Boo, Jin-Hyo
2016-07-09
This paper presents the preparation of high-quality vanadium dioxide (VO₂) thermochromic thin films with enhanced visible transmittance (T vis ) via radio frequency (RF) sputtering and plasma enhanced chemical vapor deposition (PECVD). VO₂ thin films with high T vis and excellent optical switching efficiency (E os ) were successfully prepared by employing SiO₂ as a passivation layer. After SiO₂ deposition, the roughness of the films was decreased 2-fold and a denser structure was formed. These morphological changes corresponded to the results of optical characterization including the haze, reflectance and absorption spectra. In spite of SiO₂ coating, the phase transition temperature (T c ) of the prepared films was not affected. Compared with pristine VO₂, the total layer thickness after SiO₂ coating was 160 nm, which is an increase of 80 nm. Despite the thickness change, the VO₂ thin films showed a higher T vis value (λ 650 nm, 58%) compared with the pristine samples (λ 650 nm, 43%). This enhancement of T vis while maintaining high E os is meaningful for VO₂-based smart window applications.
Yi, Ji; Chen, Siyu; Shu, Xiao; Fawzi, Amani A.; Zhang, Hao F.
2015-01-01
We achieved human retinal imaging using visible-light optical coherence tomography (vis-OCT) guided by an integrated scanning laser ophthalmoscopy (SLO). We adapted a spectral domain OCT configuration and used a supercontinuum laser as the illumating source. The center wavelength was 564 nm and the bandwidth was 115 nm, which provided a 0.97 µm axial resolution measured in air. We characterized the sensitivity to be 86 dB with 226 µW incidence power on the pupil. We also integrated an SLO that shared the same optical path of the vis-OCT sample arm for alignment purposes. We demonstrated the retinal imaging from both systems centered at the fovea and optic nerve head with 20° × 20° and 10° × 10° field of view. We observed similar anatomical structures in vis-OCT and NIR-OCT. The contrast appeared different from vis-OCT to NIR-OCT, including slightly weaker signal from intra-retinal layers, and increased visibility and contrast of anatomical layers in the outer retina. PMID:26504622
Probing insect backscatter cross section and melanization using kHz optical remote detection system
NASA Astrophysics Data System (ADS)
Gebru, Alem; Brydegaard, Mikkel; Rohwer, Erich; Neethling, Pieter
2017-01-01
A kHz optical remote sensing system is implemented to determine insect melanization features. This is done by measuring the backscatter signal in the visible and near-infrared (VIS-NIR) and short-wave infrared (SWIR) in situ. It is shown that backscatter cross section in the SWIR is insensitive to melanization and absolute melanization can be derived from the ratio of backscatter cross section of different bands (SWIR/VIS-NIR). We have shown that reflectance from insect is stronger in the SWIR as compared to NIR and VIS. This reveals that melanization plays a big role to determine backscatter cross section. One can use this feature as a tool to improve insect species and age classification. To support the findings, we illustrated melanization feature using three different insects [dead, dried specimens of snow white moth (Spilosoma genus), fox moth (Macrothylacia), and leather beetle (Odontotaenius genus)]. It is shown that reflectance from the leather beetle in the VIS and NIR is more affected by melanization as compared with snow white moth.
Ehrenreich, Philipp; Birkhold, Susanne T; Zimmermann, Eugen; Hu, Hao; Kim, Kwang-Dae; Weickert, Jonas; Pfadler, Thomas; Schmidt-Mende, Lukas
2016-09-01
Polymer morphology and aggregation play an essential role for efficient charge carrier transport and charge separation in polymer-based electronic devices. It is a common method to apply the H-aggregate model to UV/Vis or photoluminescence spectra in order to analyze polymer aggregation. In this work we present strategies to obtain reliable and conclusive information on polymer aggregation and morphology based on the application of an H-aggregate analysis on UV/Vis and photoluminescence spectra. We demonstrate, with P3HT as model system, that thickness dependent reflection behavior can lead to misinterpretation of UV/Vis spectra within the H-aggregate model. Values for the exciton bandwidth can deviate by a factor of two for polymer thicknesses below 150 nm. In contrast, photoluminescence spectra are found to be a reliable basis for characterization of polymer aggregation due to their weaker dependence on the wavelength dependent refractive index of the polymer. We demonstrate this by studying the influence of surface characteristics on polymer aggregation for spin-coated thin-films that are commonly used in organic and hybrid solar cells.
NASA Astrophysics Data System (ADS)
Uríčková, Veronika; Sádecká, Jana
2015-09-01
The identification of the geographical origin of beverages is one of the most important issues in food chemistry. Spectroscopic methods provide a relative rapid and low cost alternative to traditional chemical composition or sensory analyses. This paper reviews the current state of development of ultraviolet (UV), visible (Vis), near infrared (NIR) and mid infrared (MIR) spectroscopic techniques combined with pattern recognition methods for determining geographical origin of both wines and distilled drinks. UV, Vis, and NIR spectra contain broad band(s) with weak spectral features limiting their discrimination ability. Despite this expected shortcoming, each of the three spectroscopic ranges (NIR, Vis/NIR and UV/Vis/NIR) provides average correct classification higher than 82%. Although average correct classification is similar for NIR and MIR regions, in some instances MIR data processing improves prediction. Advantage of using MIR is that MIR peaks are better defined and more easily assigned than NIR bands. In general, success in a classification depends on both spectral range and pattern recognition methods. The main problem still remains the construction of databanks needed for all of these methods.
The Determination of Caffeine in Coffee: Sense or Nonsense?
ERIC Educational Resources Information Center
Beckers, Jozef L.
2004-01-01
The presence of caffeine in coffee is determined by the use of separation devices and UV-vis spectrophotometry. The results indicate that the use of various analytical tools helps to perceive the higher concentration values obtained through UV-vis spectrophotometry than with separation methods.
Price, Margaux M; Crumley-Branyon, Jessica J; Leidheiser, William R
2016-01-01
Background Technology gains have improved tools for evaluating complex tasks by providing environmental supports (ES) that increase ease of use and improve performance outcomes through the use of information visualizations (info-vis). Complex info-vis emphasize the need to understand individual differences in abilities of target users, the key cognitive abilities needed to execute a decision task, and the graphical elements that can serve as the most effective ES. Older adults may be one such target user group that would benefit from increased ES to mitigate specific declines in cognitive abilities. For example, choosing a prescription drug plan is a necessary and complex task that can impact quality of life if the wrong choice is made. The decision to enroll in one plan over another can involve comparing over 15 plans across many categories. Within this context, the large amount of complex information and reduced working memory capacity puts older adults’ decision making at a disadvantage. An intentionally designed ES, such as an info-vis that reduces working memory demand, may assist older adults in making the most effective decision among many options. Objective The objective of this study is to examine whether the use of an info-vis can lower working memory demands and positively affect complex decision-making performance of older adults in the context of choosing a Medicare prescription drug plan. Methods Participants performed a computerized decision-making task in the context of finding the best health care plan. Data included quantitative decision-making performance indicators and surveys examining previous history with purchasing insurance. Participants used a colored info-vis ES or a table (no ES) to perform the decision task. Task difficulty was manipulated by increasing the number of selection criteria used to make an accurate decision. A repeated measures analysis was performed to examine differences between the two table designs. Results Twenty-three older adults between the ages of 66 and 80 completed the study. There was a main effect for accuracy such that older adults made more accurate decisions in the color info-vis condition than the table condition. In the low difficulty condition, participants were more successful at choosing the correct answer when the question was about the gap coverage attribute in the info-vis condition. Participants also made significantly faster decisions in the info-vis condition than in the table condition. Conclusions Reducing the working memory demand of the task through the use of an ES can improve decision accuracy, especially when selection criteria is only focused on a single attribute of the insurance plan. PMID:27251110
NASA Astrophysics Data System (ADS)
Dayamani, Allumolu; Shinde, Ganesh S.; Chaupatnaik, Anshuman; Rao, R. Prasada; Adams, Stefan; Barpanda, Prabeer
2018-05-01
Solvothermal synthetic routes can provide energy-savvy platforms to fabricate battery anode materials involving relatively milder annealing steps vis-à-vis the conventional solid-state synthesis. These energy efficient routes in turn restrict aggressive grain growth to form nanoscale particles favouring efficient Li+ diffusion. Here, we report an economic solution combustion synthesis of SrLi2Ti6O14 anode involving nitrate-urea complexation with a short annealing duration of only 2 h (900 °C). Rietveld refinement confirms the phase purity of target product assuming an orthorhombic framework (Cmca symmetry). It delivers reversible capacity of ∼125 mAh.g-1 at a rate of C/20 involving a 1.38 V Ti4+/Ti3+ redox activity with excellent rate kinetics and cycling stability. Bond valence site energy (BVSE) calculations gauge SrLi2Ti6O14 to be an anisotropic 3D Li+ ion conductor with the highest ionic conductivity along the c direction. The electrochemical and diffusional pathways have been elucidated for combustion prepared SrLi2Ti6O14 as an efficient and safe negative electrode candidate for Li-ion batteries.
Synthesis and characterization of Ag embedded graphitic carbon nitride
NASA Astrophysics Data System (ADS)
Patra, P. C.; Mohapatra, Y. N.
2018-05-01
Silver embedded graphitic carbon nitride (g-C3N4:Ag) was prepared by a simple wet chemical pathway using dimethylformamide (DMF) as a common solvent which facilitate homogenous distribution of Ag nanoparticles under ambient conditions. The phase, chemical structure and thermal stability of the as prepared g-C3N4:Ag composite was characterized by X-ray diffraction (XRD), Fourier transmission infrared (FTIR) spectroscopy and Thermo gravimetric analysis (TGA). The optical properties of g-C3N4:Ag were investigated by diffuse reflectance UV/vis spectroscopy and steady state photoluminescence (PL) spectroscopy. The bandgap of g-C3N4:Ag is determined to be 2.72 eV compared to 2.85 eV for that of pure g-C3N4 using Kubelka-Monk function. Comparing the UV/vis spectra, there is a broad spectrum in the region 2.3 to 2.6 eV in the case of g-C3N4:Ag, which is attributed to the presence of Ag nanoparticles. The emission peak of g-C3N4:Ag is slightly broadened and quenched in intensity to that of pure g-C3N4.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sun, Mingxuan, E-mail: mingxuansun@sues.edu.cn; Li, Weibin; Sun, Shanfu
2015-01-15
Chemically bonded graphene/TiO{sub 2} nanorod hybrid composites with superior dispersity were synthesized by a one-step in situ hydrothermal method using graphene oxide (GO) and TiO{sub 2} (P25) as the starting materials. The as-prepared samples were characterized by XRD, XPS, TEM, FE-SEM, EDX, Raman, N{sub 2} adsorption, and UV–vis DRS techniques. Enhanced light absorption and a red shift of absorption edge were observed for the composites in the ultraviolet–visible diffuse reflectance spectroscopy (UV–vis DRS). Their effective photocatalytic activity was evaluated by the photodegradation of methylene blue under visible light irradiation. An enhancement of photocatalytic performance was observed over graphene/TiO{sub 2} nanorodmore » hybrid composite photocatalysts, as 3.7 times larger than that of pristine TiO{sub 2} nanorods. This work demonstrated that the synthesis of TiO{sub 2} nanorods and simultaneous conversion of GO to graphene “without using reducing agents” had shown to be a rapid, direct and clean approach to fabricate chemically bonded graphene/TiO{sub 2} nanorod hybrid composites with enhanced photocatalytic performance.« less
Immersive Virtual Worlds in University-Level Human Geography Courses
ERIC Educational Resources Information Center
Dittmer, Jason
2010-01-01
This paper addresses the potential for increased deployment of immersive virtual worlds in higher geographic education. An account of current practice regarding popular culture in the geography classroom is offered, focusing on the objectification of popular culture rather than its constitutive role vis-a-vis place. Current e-learning practice is…
In Early Childhood: What's Language about?
ERIC Educational Resources Information Center
Mozere, Liane
2007-01-01
This paper argues that in daycare centres in France, where children are cared for from four months to age three, the competence of female staff members is usually denied and unvalued vis a vis the expert opinions. The paper highlights empirical research on early childhood and gender, providing pragmatic access to children's languages of desire, a…
The "F" Word: Is Feminism Incompatible with Beauty and Romance?
ERIC Educational Resources Information Center
Rudman, Laurie A.; Fairchild, Kimberly
2007-01-01
Three studies examined the predictive utility of heterosexual relationship concerns vis-a-vis support for feminism. Study 1 showed that beauty is perceived to be at odds with feminism, for both genders. The stereotype that feminists are unattractive was robust, but fully accounted for by romance-related attributions. Moreover, more attractive…
Prospects for Integrating Service Learning into Short-Term International Study
ERIC Educational Resources Information Center
Daly, Donna M.; Baker, Suzanne; Williams, Stephen J.
2014-01-01
In an era of significant social, political, and economic globalization, it is crucial for health and human services educators to adopt a more hands on international view vis-à-vis student education. This article presents information that will assist educators in extending domestic service learning concepts and activities into the undergraduate…
Soviet Language Policy vis-a-vis Minority Languages: The Road to Disintegration
ERIC Educational Resources Information Center
Das, Alok Kumar
2011-01-01
The present linguistic situation in Russia, however much it may have been affected by political and economic considerations, is overwhelmingly the consequence of what people have made of their geographical conditions, their history and their long-standing language and ethnic contacts over many centuries. The present linguistic complexity of Russia…
2016-10-24
The elongated hills in this VIS image are a feature termed yardangs. Yardangs are formed by wind activity in regions where the surface material is not well cemented. The elongation indicates the direction of the wind. Orbit Number: 65299 Latitude: -10.1078 Longitude: 183.91 Instrument: VIS Captured: 2016-09-02 13:39 http://photojournal.jpl.nasa.gov/catalog/PIA21019
ERIC Educational Resources Information Center
Baker, Jason R.
2017-01-01
The goals of the present action research study were to understand intelligence analysts' perceptions of weapon systems visual recognition ("vis-recce") training and to determine the impact of a Critical Thinking Training (CTT) Seminar and Formative Assessments on unit-level intelligence analysts' "vis-recce" performance at a…
Privacy and Information Systems: An Argument and an Implementation.
ERIC Educational Resources Information Center
Hellman, J. J.
The report is presented in two parts. The first examines the social and technical implications of information systems vis a vis the individual's ability to control the dissemination of information about himself. It is argued that information systems must incorporate certain properties in their initial design in order to safeguard man's…
Competition and coexistence in mustelid communities
Roger A. Powell; William J. Zielinski
1983-01-01
The family Mustelidae is large and many mustelid species guilds are larger than other carnivore guilds. For example, in northeastern North America half the native carnivore species are mustelids (Hail 1981). Though competition between mustelids has not been proven (vis-a-vis Connor & Simberloff 1979), mustelid sympatry has always been explained by size differences...
Formulating Social Policy vis-a-vis Immigrants: Win-Win or Zero-Sum Game?
ERIC Educational Resources Information Center
Kissam, Ed
This paper examines the effectiveness of social services provided to Mexican immigrants in rural California. In addition, the paper offers recommendations for service delivery models and for rethinking the objectives of immigrant social policy. At the most basic level, current social program planning and associated analyses of policy options fail…
Land-use and land-cover change in three corn belt ecoregions: Similarities and differences
Auch, Roger F.; Laingen, Chris R.; Drummond, Mark A.; Sayler, Kristi L.; Reker, Ryan R.; Bouchard, Michelle A.; Danielson, Jeffrey J.
2013-01-01
Land use categorical changes, though not as numerous as one might suspect, vary by type within the three designated ecozones of the Corn Belt with the westernmost zone showing the most temporary change vis-a-vis the more permanent changes taking place in the eastern and central zones.
An Information-Theoretic-Cluster Visualization for Self-Organizing Maps.
Brito da Silva, Leonardo Enzo; Wunsch, Donald C
2018-06-01
Improved data visualization will be a significant tool to enhance cluster analysis. In this paper, an information-theoretic-based method for cluster visualization using self-organizing maps (SOMs) is presented. The information-theoretic visualization (IT-vis) has the same structure as the unified distance matrix, but instead of depicting Euclidean distances between adjacent neurons, it displays the similarity between the distributions associated with adjacent neurons. Each SOM neuron has an associated subset of the data set whose cardinality controls the granularity of the IT-vis and with which the first- and second-order statistics are computed and used to estimate their probability density functions. These are used to calculate the similarity measure, based on Renyi's quadratic cross entropy and cross information potential (CIP). The introduced visualizations combine the low computational cost and kernel estimation properties of the representative CIP and the data structure representation of a single-linkage-based grouping algorithm to generate an enhanced SOM-based visualization. The visual quality of the IT-vis is assessed by comparing it with other visualization methods for several real-world and synthetic benchmark data sets. Thus, this paper also contains a significant literature survey. The experiments demonstrate the IT-vis cluster revealing capabilities, in which cluster boundaries are sharply captured. Additionally, the information-theoretic visualizations are used to perform clustering of the SOM. Compared with other methods, IT-vis of large SOMs yielded the best results in this paper, for which the quality of the final partitions was evaluated using external validity indices.
Analysis of key technologies for virtual instruments metrology
NASA Astrophysics Data System (ADS)
Liu, Guixiong; Xu, Qingui; Gao, Furong; Guan, Qiuju; Fang, Qiang
2008-12-01
Virtual instruments (VIs) require metrological verification when applied as measuring instruments. Owing to the software-centered architecture, metrological evaluation of VIs includes two aspects: measurement functions and software characteristics. Complexity of software imposes difficulties on metrological testing of VIs. Key approaches and technologies for metrology evaluation of virtual instruments are investigated and analyzed in this paper. The principal issue is evaluation of measurement uncertainty. The nature and regularity of measurement uncertainty caused by software and algorithms can be evaluated by modeling, simulation, analysis, testing and statistics with support of powerful computing capability of PC. Another concern is evaluation of software features like correctness, reliability, stability, security and real-time of VIs. Technologies from software engineering, software testing and computer security domain can be used for these purposes. For example, a variety of black-box testing, white-box testing and modeling approaches can be used to evaluate the reliability of modules, components, applications and the whole VI software. The security of a VI can be assessed by methods like vulnerability scanning and penetration analysis. In order to facilitate metrology institutions to perform metrological verification of VIs efficiently, an automatic metrological tool for the above validation is essential. Based on technologies of numerical simulation, software testing and system benchmarking, a framework for the automatic tool is proposed in this paper. Investigation on implementation of existing automatic tools that perform calculation of measurement uncertainty, software testing and security assessment demonstrates the feasibility of the automatic framework advanced.
Ač, Alexander; Malenovský, Zbyněk; Urban, Otmar; Hanuš, Jan; Zitová, Martina; Navrátil, Martin; Vráblová, Martina; Olejníčková, Julie; Špunda, Vladimír; Marek, Michal
2012-01-01
We explored ability of reflectance vegetation indexes (VIs) related to chlorophyll fluorescence emission (R 686/R 630, R 740/R 800) and de-epoxidation state of xanthophyll cycle pigments (PRI, calculated as (R 531 − R 570)/(R 531 − R 570)) to track changes in the CO2 assimilation rate and Light Use Efficiency (LUE) in montane grassland and Norway spruce forest ecosystems, both at leaf and also canopy level. VIs were measured at two research plots using a ground-based high spatial/spectral resolution imaging spectroscopy technique. No significant relationship between VIs and leaf light-saturated CO2 assimilation (A MAX) was detected in instantaneous measurements of grassland under steady-state irradiance conditions. Once the temporal dimension and daily irradiance variation were included into the experimental setup, statistically significant changes in VIs related to tested physiological parameters were revealed. ΔPRI and Δ(R 686/R 630) of grassland plant leaves under dark-to-full sunlight transition in the scale of minutes were significantly related to A MAX (R 2 = 0.51). In the daily course, the variation of VIs measured in one-hour intervals correlated well with the variation of Gross Primary Production (GPP), Net Ecosystem Exchange (NEE), and LUE estimated via the eddy-covariance flux tower. Statistical results were weaker in the case of the grassland ecosystem, with the strongest statistical relation of the index R 686/R 630 with NEE and GPP. PMID:22701368
Resource Efficient Metal and Material Recycling
NASA Astrophysics Data System (ADS)
Reuter, Markus A.; van Schaik, Antoinette
Metals enable sustainability through their use and their recyclability. However, various factors can affect the Resource Efficiency of Metal Processing and Recycling. Some typical factors that enable Resource Efficiency include and arranged under the drivers of sustainability: Environment (Maximize Resource Efficiency — Energy, Recyclates, Materials, Water, Sludges, Emissions, Land); Economic Feasibility (BAT & Recycling Systems Simulation / Digitalization, Product vis-à-vis Material Centric Recycling); and Social — Licence to Operate (Legislation, consumer, policy, theft, manual labour.). In order to realize this primary production has to be linked systemically with typical actors in the recycling chain such as Original Equipment Manufacturers (OEMs), Recyclers & Collection, Physical separation specialists as well as process metallurgical operations that produce high value metals, compounds and products that recycle back to products. This is best done with deep knowledge of multi-physics, technology, product & system design, process control, market, life cycle management, policy, to name a few. The combination of these will be discussed as Design for Sustainability (DfS) and Design for Recycling (DfR) applications.
Ultra-Accelerated Natural Sunlight Exposure Testing Facilities
Lewandowski, Allan A.; Jorgensen, Gary J.
2004-11-23
A multi-faceted concentrator apparatus for providing ultra-accelerated natural sunlight exposure testing for sample materials under controlled weathering conditions comprising: facets that receive incident natural sunlight, transmits VIS/NIR and reflects UV/VIS onto a secondary reflector that delivers a uniform flux of UV/VIS onto a sample exposure plane located near a center of a facet array in a chamber that provide concurrent levels of temperature and/or relative humidity at high levels of up to 100.times. of natural sunlight that allow sample materials to be subjected to accelerated irradiance exposure factors for a significant period of time of about 3 to 10 days to provide a corresponding time of about at least a years worth representative weathering of sample materials.
Qualities of a Psychiatric Mentor: A Quantitative Singaporean Survey
ERIC Educational Resources Information Center
Tor, Phern-Chern; Goh, Lee-Gan; Ang, Yong-Guan; Lim, Leslie; Winslow, Rasaiah-Munidasa; Ng, Beng-Yeong; Wong, Sze-Tai; Ng, Tse-Pin; Kia, Ee-Heok
2011-01-01
Objective: Psychiatric mentors are an important part of the new, seamless training program in Singapore. There is a need to assess the qualities of a good psychiatric mentor vis-a-vis those of a good psychiatrist. Method: An anonymous survey was sent out to all psychiatry trainees and psychiatrists in Singapore to assess quantitatively the…
Nwaorgu, Obioma C; Onyeneho, Nkechi G; Okolo, May; Obadike, Ebele; Enibe, Gloria
2008-08-01
This was designed to provide background information for the implementation of family life and HIV/AIDS education in post primary schools in the Enugu State. A cross sectional survey of the reproductive health knowledge and practices of 412 junior secondary school pupils from 12 schools in Enugu State, Nigeria was undertaken using a uniform set of structured self-administered questionnaire. The results revealed that while the pupils demonstrated fair knowledge of human biology, they lacked knowledge of self-protective mechanisms as it related to sexual health. About (50%) of the participants reported that they have had sex, at the age of less than 11 years when they must have been in the primary school and most (89.3%) at age 11-14 years. Half (50.9%) of the respondents hold the belief that a girl would not get pregnant in her first sexual encounter. Statistically more of those who have ever had sex were betrayed this ignorance (p = 0.004). The boys were less certain about what constitutes the wrong ideas about reproductive health systems than the girls (p = 0.042). In the same vein, there was a difference (p < 0.0001) in the proportion of the rural residents, vis-a-vis their urban counterparts that could correctly identify the wrong ideas about human reproduction. This situation urgently calls for concerted efforts at addressing the poor reproductive health knowledge of these sexually active young people, for the millennium development goals (MDGs) target to be realized in Nigeria.
Ahuja, Naveen; Katare, Om Prakash; Singh, Bhupinder
2007-01-01
Role of various water-soluble carriers was studied for dissolution enhancement of a poorly soluble model drug, rofecoxib, using solid dispersion approach. Diverse carriers viz. polyethylene glycols (PEG 4000 and 6000), polyglycolized fatty acid ester (Gelucire 44/14), polyvinylpyrollidone K25 (PVP), poloxamers (Lutrol F127 and F68), polyols (mannitol, sorbitol), organic acid (citric acid) and hydrotropes (urea, nicotinamide) were investigated for the purpose. Phase-solubility studies revealed AL type of curves for each carrier, indicating linear increase in drug solubility with carrier concentration. The sign and magnitude of the thermodynamic parameter, Gibbs free energy of transfer, indicated spontaneity of solubilization process. All the solid dispersions showed dissolution improvement vis-à-vis pure drug to varying degrees, with citric acid, PVP and poloxamers as the most promising carriers. Mathematical modeling of in vitro dissolution data indicated the best fitting with Korsemeyer-Peppas model and the drug release kinetics primarily as Fickian diffusion. Solid state characterization of the drug-poloxamer binary system using XRD, FTIR, DSC and SEM techniques revealed distinct loss of drug crystallinity in the formulation, ostensibly accounting for enhancement in dissolution rate.
Yi, Ji; Liu, Wenzhong; Chen, Siyu; Backman, Vadim; Sheibani, Nader; Sorenson, Christine M.; Fawzi, Amani A.; Linsenmeier, Robert A.; Zhang, Hao F.
2015-01-01
The lack of capability to quantify oxygen metabolism noninvasively impedes both fundamental investigation and clinical diagnosis of a wide spectrum of diseases including all the major blinding diseases such as age-related macular degeneration, diabetic retinopathy, and glaucoma. Using visible light optical coherence tomography (vis-OCT), we demonstrated accurate and robust measurement of retinal oxygen metabolic rate (rMRO2) noninvasively in rat eyes. We continuously monitored the regulatory response of oxygen consumption to a progressive hypoxic challenge. We found that both oxygen delivery, and rMRO2 increased from the highly regulated retinal circulation (RC) under hypoxia, by 0.28 ± 0.08 μL min−1 (p < 0.001), and 0.20 ± 0.04 μL min−1 (p < 0.001) per 100 mmHg systemic pO2 reduction, respectively. The increased oxygen extraction compensated for the deficient oxygen supply from the poorly regulated choroidal circulation. Results from an oxygen diffusion model based on previous oxygen electrode measurements corroborated our in vivo observations. We believe that vis-OCT has the potential to reveal the fundamental role of oxygen metabolism in various retinal diseases. PMID:26658555
Precursor effect on the property and catalytic behavior of Fe-TS-1 in butadiene epoxidation
NASA Astrophysics Data System (ADS)
Wu, Mei; Zhao, Huahua; Yang, Jian; Zhao, Jun; Song, Huanling; Chou, Lingjun
2017-11-01
The effect of iron precursor on the property and catalytic behavior of iron modified titanium silicalite molecular sieve (Fe-TS-1) catalysts in butadiene selective epoxidation has been studied. Three Fe-TS-1 catalysts were prepared, using iron nitrate, iron chloride and iron sulfate as precursors, which played an important role in adjusting the textural properties and chemical states of TS-1. Of the prepared Fe-TS-1 catalysts, those modified by iron nitrate (FN-TS-1) exhibited a significant enhanced performance in butadiene selective epoxidation compared to those derived from iron sulfate (FS-TS-1) or iron chloride (FC-TS-1) precursors. To obtain a deep understanding of their structure-performance relationship, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Temperature programmed desorption of NH3 (NH3-TPD), Diffuse reflectance UV-Vis spectra (DR UV-Vis), Fourier transformed infrared spectra (FT-IR) and thermal gravimetric analysis (TGA) were conducted to characterize Fe-TS-1 catalysts. Experimental results indicated that textural structures and acid sites of modified catalysts as well as the type of Fe species influenced by the precursors were all responsible for the activity and product distribution.
ERIC Educational Resources Information Center
Ho, Jeanne Marie; Ng, David
2012-01-01
This study examined the process of Information Communication Technology reform in a Singapore school. The focus was on distributed leadership actions, and the factors which enabled and constrained the distribution of leadership. This study adopted a naturalistic inquiry approach, involving the case study of a school. The study found that…
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Effects of Regolith Properties on UV/VIS Spectra and Implications for Lunar Remote Sensing
NASA Astrophysics Data System (ADS)
Coman, Ecaterina Oana
Lunar regolith chemistry, mineralogy, various maturation factors, and grain size dominate the reflectance of the lunar surface at ultraviolet (UV) to visible (VIS) wavelengths. These regolith properties leave unique fingerprints on reflectance spectra in the form of varied spectral shapes, reflectance intensity values, and absorption bands. With the addition of returned lunar soils from the Apollo and Luna missions as ground truth, these spectral fingerprints can be used to derive maps of global lunar chemistry or mineralogy to analyze the range of basalt types on the Moon, their spatial distribution, and source regions for clues to lunar formation history and evolution. The Lunar Reconnaissance Orbiter Camera (LROC) Wide Angle Camera (WAC) is the first lunar imager to detect bands at UV wavelengths (321 and 360 nm) in addition to visible bands (415, 566, 604, 643, and 689 nm). This dissertation uses a combination of laboratory and remote sensing studies to examine the relation between TiO2 concentration and WAC UV/VIS spectral ratios and to test the effects of variations in lunar chemistry, mineralogy, and soil maturity on ultraviolet and visible wavelength reflectance. Chapter 1 presents an introduction to the dissertation that includes some background in lunar mineralogy and remote sensing. Chapter 2 covers coordinated analyses of returned lunar soils using UV-VIS spectroscopy, X-ray diffraction, and micro X-ray fluorescence. Chapter 3 contains comparisons of local and global remote sensing observations of the Moon using LROC WAC and Clementine UVVIS TiO2 detection algorithms and Lunar Prospector (LP) Gamma Ray Spectrometer (GRS)-derived FeO and TiO2 concentrations. While the data shows effects from maturity and FeO on the UV/VIS detection algorithm, a UV/VIS relationship remains a simple yet accurate method for TiO2 detection on the Moon.
Malec, J F; Buffington, A L; Moessner, A M; Degiorgio, L
2000-08-01
To evaluate initial placement and 1-year employment outcomes of a Medical/Vocational Case Coordination System (MVCCS) for persons with brain injury (BI) that provides: (1) early case identification and coordination, (2) appropriate medical and vocational rehabilitation interventions, (3) work trials, and (4) supported employment interventions including job coaching. One hundred fourteen Minnesota residents, ages 18 to 65 years, with acquired BI. Five levels of Vocational Independence Scale (VIS). Preinjury employment status (VIS) and years of education, severity of initial injury, time since injury, current impairment/disability as measured by the Rasch-analyzed Staff Mayo-Portland Adaptability Inventory (MPAI), and impaired self-awareness measured by staff rating and the difference between Staff MPAI and Survivor MPAI. At placement, 46% in independent work; 25% in transitional placements; 9% in long-term supported employment; 10% in sheltered work; and 10% not placed. At 1-year follow-up (n = 101), 53% in independent work; 19% in transitional placement; 9% in supported work; 6% in sheltered work; and 13% unemployed. Regression analyses showed time since injury and Rasch Staff MPAI predicted VIS at placement; only VIS at placement independently predicted VIS at 1-year follow-up; Rasch Staff MPAI and preinjury education level predicted time to placement. The MVCCS optimized vocational outcome after BI. Time since injury and impairment/disability best predicted vocational placement. Level of initial placement best predicted employment status at follow-up. Persons with greater disability required more extended time and more extensive rehabilitation services before placement.
Kamberi, Marika; Tran, Thu-Ngoc
2012-11-01
High-throughput 96-well solid phase extraction (SPE) plate with C-18 reversed phase sorbent followed by UV-visible (UV-Vis) microplate reader was applied to the analysis of hydrophobic drugs in surfactant-containing dissolution media, which are often used to evaluate the in-vitro drug release of drug eluting stents (DES). Everolimus and dissolution medium containing Triton X-405 were selected as representatives, and the appropriate SPE conditions (adsorption, washing and elution) were investigated to obtain a practical and reliable sample clean-up. It was shown that the developed SPE procedure was capable of removing interfering components (Triton X-405 and its impurities), allowing for an accurate automated spectrophotometric analysis to be performed. The proposed UV-Vis spectrophotometric method yielded equivalent results compared to a classical LC analysis method. Linear regression analysis indicated that both methods have the ability to obtain test results that are directly proportional to the concentration of analyte in the sample within the selected range of 1.0-10 μg/ml for everolimus, with a coefficient of correlation (r(2)) value of >0.998 and standard deviation of the residuals (Syx) of <2%. The individual recoveries of everolimus ranged from 97 to 104% for the UV-Vis spectrophotometric method and from 98 to 102 for the HPLC method, respectively. The 95% CI of the mean recovery for the UV-Vis spectrophotometric method was 99-102% and for the HPLC method was 99-101%. No statistical difference was found between the mean recoveries of the methods (p=0.42). Hence the methods are free from interference due to Triton and other chemicals present in the dissolution medium. The variation in the amount of everolimus estimated by UV-Vis spectrophotometric and HPLC methods was ≤3.5%, and the drug release profiles obtained by both methods were found to be equivalent by evaluation with two-one-sided t-test (two-tailed, p=0.62; mean of differences, 0.17; 95% CI, 0.62-0.96) and similarity factor f2 (f2 value, 87). The excellent conformity of the results makes UV-Vis spectrophotometer an ideal tool for analyzing the drugs in the media containing surfactants, after SPE. The 96-well SPE plates in combination with UV-Vis microplate reader provide a high throughput method for the determination of in-vitro drug release profile of DES. Switching from HPLC to UV-Vis spectrophotometer microplate reader assay reduces the solvent consumption and labor required for the sample analyses. This directly impacts the profitability of the laboratory. Copyright © 2012 Elsevier B.V. All rights reserved.
On Nature, Christianity and Deep Ecology--A Response to W. S. Helton and N. D. Helton
ERIC Educational Resources Information Center
Marangudakis, Manussos
2008-01-01
Establishing factually-based public support for the intrinsic value of nature, vis-a-vis a "domineering" or "stewardship" relation with the natural environment, necessitates the prior theoretical and methodological establishment of the above normative distinction. In this reply I argue that the Modified New Environmental Paradigm used by Helton…
What's New in Decision Support: Executive Information Systems. AIR 1990 Annual Forum Paper.
ERIC Educational Resources Information Center
Viehland, Dennis W.
The Executive information System (EIS), a decision support system for the executive, is defined, a comparison is made between EIS and its predecessors, and the differences between EIS in academic institutions vis-a-vis private business firms are discussed. An outline is also provided of the technological and data requirements for executive…
Learning to Read the Bible with Desire: Teaching the Eros of Exegesis in the Theological Classroom
ERIC Educational Resources Information Center
Vaage, Leif E.
2007-01-01
The article begins with two brief theoretical descriptions of a pedagogy of desire vis-a-vis the Christian Bible. The first of these is a poem; the second summarizes the conversation constituted by four quite different books: the "Confessions" by Augustine of Hippo, "Freud & Philosophy" by Paul Ricoeur, "Pedagogy of…
Science Advice as Procedural Rationality: Reflections on the National Research Council
ERIC Educational Resources Information Center
Feuer, Michael J.; Maranto, Christina J.
2010-01-01
Since its founding in 1863, the National Academy of Sciences (NAS) has occupied a special niche in the complex ecology of advice-giving in the United States. Established as a small, private organization with special responsibilities and obligations vis a vis the American people and government, the Academy has expanded considerably in the past…
ERIC Educational Resources Information Center
Jamali, Dima; Sidani, Yusuf
2008-01-01
Purpose: The purpose of this paper is to assess the performance of a sample of Lebanese organizations vis-a-vis some of the core learning organization dimensions identified in the literature, focusing specifically on those dimensions that are considered most salient and relevant in the Lebanese context. Design/methodology/approach: The paper…
ERIC Educational Resources Information Center
Campbell, Corbin M.; Cabrera, Alberto F.
2011-01-01
The National Survey of Student Engagement (NSSE) Benchmarks has emerged as a competing paradigm for assessing institutional effectiveness vis-a-vis the U.S. News & World Report. However, Porter (2009) has critiqued it for failing to meet validity and reliability standards. This study investigated whether the NSSE five benchmarks had construct…
ERIC Educational Resources Information Center
Bess, James L.
This paper suggests that undergraduate higher education is at a severe competitive disadvantage vis-a-vis other socializing and educating agencies in society and proposes some strategies to compensate for this disadvantage. First, the paper notes difficulties with mandated assessment as a major means of educational improvement. It then identifies…
ERIC Educational Resources Information Center
Warhol, Larisa; Mayer, Anysia
2012-01-01
This article explores local state bilingual-education policy vis-a-vis pervasive dominant-language ideologies about language-education policy and practice. State-level language-education policy, especially for English Language Learners (ELs), spans a wide range, from states that through policy legally require some form of bilingual education to…
Preparation of carbon nanotubes/BiOBr composites with higher visible light photocatalytic activity
NASA Astrophysics Data System (ADS)
You, Y. J.; Zhang, Y. X.; Li, R. R.; Li, C. H.
2014-12-01
A novel flower-like photocatalyst CNTs/BiOBr was successfully prepared by a facile hydrothermal method. The morphology and the physicochemical properties of the prepared samples were investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive X-ray spectrometry (EDX), and UV-visible diffuse reflectance spectroscopy (UV-vis DRS). The photocatalytic activity was evaluated by degradation of Rhodamin B (RhB) dye. It was demonstrated that CNTs/BiOBr photocatalyst could effectively photodegrade RhB under visible light (VL) irradiation.
García-Rodríguez, M Valle; López-Córcoles, Horacio; Alonso, Gonzalo L; Pappas, Christos S; Polissiou, Moschos G; Tarantilis, Petros A
2017-04-15
The aim of this work was a comparison of the ISO 3632 (2011) method and an HPLC-DAD method for safranal quantity determination in saffron. Samples from different origins were analysed by UV-vis according to ISO 3632 (2011) and by HPLC-DAD. Both methods were compared, and there was no correlation between the safranal content obtained by UV-vis and HPLC-DAD. An over-estimation in the UV-vis experiment was observed, which was related to the cis-crocetin esters content, as well as other compounds. The results demonstrated that there was no relationship between ISO quality categories and safranal content using HPLC-DAD. Therefore, HPLC-DAD might be preferable to UV-vis for determining the safranal content and the classification of saffron for commercial purposes. In addition, HPLC-DAD was adequate for determining the three foremost parameters that define the quality of saffron (crocetin esters, picrocrocin and safranal); therefore, this approach could be included in the ISO 3632 method (2011). Copyright © 2016 Elsevier Ltd. All rights reserved.
Photodetachment and UV-Vis spectral properties of Cl2rad -·nHO clusters: Extrapolation to bulk
NASA Astrophysics Data System (ADS)
Pathak, A. K.; Mukherjee, T.; Maity, D. K.
2008-03-01
Vertical detachment energy (VDE) and UV-Vis spectra of Cl2rad -·nHO clusters ( n = 1-11) are reported based on first principle electronic structure calculations. VDE of the hydrated clusters are calculated following second order Moller-Plesset perturbation (MP2) as well as coupled cluster theory with 6-311++G(d,p) set of basis function. The excess electron in these hydrated clusters is mainly localized over the solute Cl atoms. A linear relationship is obtained for VDE vs. ( n + 2.6) -1/3 and bulk VDE of Cl2rad - aqueous solution is calculated as 10.61 eV at CCSD(T) level of theory. UV-Vis spectra of these hydrated clusters are calculated applying CI with single electron (CIS) excitation procedure. Simulated UV-Vis spectra of Cl2rad -·10HO cluster is noted to be in excellent agreement with the reported spectra of Cl2rad - (aq) system, λmax for Cl2rad -·11HO system is calculated to be red shifted though.
ERIC Educational Resources Information Center
Katz, Idit; Shahar, Bat-Hen
2015-01-01
Findings from several studies suggest that teachers who embrace an autonomy-supportive style vis-à-vis their students promote student motivation. However, the question of what makes teachers adopt this supportive style remains unanswered. Using Self-Determination Theory as a framework, we suggest that teachers' own motivation and their beliefs…
Format of Options in Multiple Choice Test vis-a-vis Test Performance
ERIC Educational Resources Information Center
Bendulo, Hermabeth O.; Tibus, Erlinda D.; Bande, Rhodora A.; Oyzon, Voltaire Q.; Milla, Norberto E.; Macalinao, Myrna L.
2017-01-01
Testing or evaluation in an educational context is primarily used to measure or evaluate and authenticate the academic readiness, learning advancement, acquisition of skills, or instructional needs of learners. This study tried to determine whether the varied combinations of arrangements of options and letter cases in a Multiple-Choice Test (MCT)…
Constructing the Cosmopolitan Subject: Teaching Secondary School Literature in Singapore
ERIC Educational Resources Information Center
Poon, Angelia Mui Cheng
2010-01-01
This article discusses the ambitious educational reforms of the Singapore government in response to the challenges of globalization vis-a-vis the specific issues arising from the case of teaching Literature in secondary schools. It shows how the Singapore state is invested in a particular view of globalization and argues how recent scholarly moves…
Distance Education in the U.S.: A Paradox
ERIC Educational Resources Information Center
Forte, Glenn J.; Schwandt, David R.; Swayze, Susan; Butler, Joan; Ashcraft, Merrill
2016-01-01
Over the last several years distance education (DE) class offerings at U.S. universities and colleges have been increasing at a rate of approximately 10% or more per year (Allen & Seaman, 2014). While the effectiveness of DE classes vis-à-vis that of face-to-face (F2F) classes has been sufficiently documented, there are few studies that…
Social Class, Solipsism, and Contextualism: How the Rich Are Different from the Poor
ERIC Educational Resources Information Center
Kraus, Michael W.; Piff, Paul K.; Mendoza-Denton, Rodolfo; Rheinschmidt, Michelle L.; Keltner, Dacher
2012-01-01
Social class is shaped by an individual's material resources as well as perceptions of rank vis-a-vis others in society, and in this article, we examine how class influences behavior. Diminished resources and lower rank create contexts that constrain social outcomes for lower-class individuals and enhance contextualist tendencies--that is, a focus…
"Tough Love and Tears": Learning Doctoral Writing in the Sciences
ERIC Educational Resources Information Center
Aitchison, Claire; Catterall, Janice; Ross, Pauline; Burgin, Shelley
2012-01-01
Contemporary changes to the doctorate mean student researchers are likely to be expected to write differently, write more and more often, and yet, despite a growing interest in doctoral education, we still know relatively little about the teaching and learning practices of students and supervisors vis-a-vis doctoral writing. This paper draws from…
Bond Length Dependence on Quantum States as Shown by Spectroscopy
ERIC Educational Resources Information Center
Lim, Kieran F.
2005-01-01
A discussion on how a spreadsheet simulation of linear-molecular spectra could be used to explore the dependence of rotational band spacing and contours on average bond lengths in the initial and final quantum states is presented. The simulation of hydrogen chloride IR, iodine UV-vis, and nitrogen UV-vis spectra clearly show whether the average…
"I'm Not a Computer Person": Negotiating Participation in Academic Discourses
ERIC Educational Resources Information Center
Lohnes Watulak, Sarah
2012-01-01
While there is little doubt that technology is, in many ways, central to the college student experience today, the expectations of students and colleges vis-a-vis technology may not always be the same. This research explores the role of technology in the lives of today's college students, particularly within the institutional context of the…
ERIC Educational Resources Information Center
Castro, Juan F.; Yamada, Gustavo; Arias, Omar
2016-01-01
This paper analyzes the relative importance of short-term financial constraints "vis-a-vis" skills and other background factors when explaining higher education access in Peru. We focus on the disparities in university enrollment between rich and poor households. We use a novel household survey that includes special tests to measure…
ERIC Educational Resources Information Center
Oba, Jun
2005-01-01
In April 2004, all national universities, which had previously been legally subordinate to MEXT (Ministry of Education, Sports and Culture), were given a legal personality and became "National University Corporations". With this change, each national university now enjoys greater autonomy vis-a-vis the government in terms of how it uses…
Public Ethnic Regard and Academic Adjustment among Latino Adolescents
ERIC Educational Resources Information Center
Rivas-Drake, Deborah
2011-01-01
This study examined whether Latino adolescents' perceptions of personal support vis-a-vis those of ethnic regard by adults at school differentially relate to academic outcomes. Data were drawn from a sample of 156 Latino students (age M = 16.17, SD = 1.27; 61% girls, 39% boys) attending an urban high school. As expected, youth who perceived more…
ERIC Educational Resources Information Center
Okoli, B. E.; Azih, N.
2015-01-01
The paper reviewed a business education programme in Nigeria vis-a-vis its role in human resource development and highlighted deficiencies in programme curricular and delivery changes needed in remodeling of the programme to enhance learning outcomes, increase skill acquisition, meet world's standards and current labour demands in business…
NASA Astrophysics Data System (ADS)
Li, Ling; Zhuang, Huisheng; Bu, Dan
2011-08-01
The novel visible-light-activated La/I/TiO 2 nanocomposition photocatalyst was successfully synthesized using precipitation-dipping method, and characterized by X-ray powder diffraction (XRD), the Brunauer-Emmett-Teller (BET) method, transmission electron microscopy (TEM), thermogravimetry-differential scanning calorimetry (TG-DSC) and UV-vis diffuse reflectance spectroscopy (UV-vis DRS). The photocatalytic activity of La/I/TiO 2 was evaluated by studying photodegradation of reactive blue 19 as a probe reaction under simulated sunlight irradiation. Photocatalytic experiment results showed that the maximum specific photocatalytic activity of the La/I/TiO 2 photocatalyst appeared when the molar ratio of La/Ti was 2.0 at%, calcined at 350 °C for 2 h, due to the sample with good crystallization, high BET surface area and small crystal size. Under simulated sunlight irradiation, the degradation of reactive blue 19 aqueous solution reached 98.6% in 80 min, which showed La/I/TiO 2 photocatalyst to be much higher photocatalytic activity compared to standard Degussa P25 photocatalyst. The higher visible light activity is due to the codoping of lanthanum and iodine.
NASA Astrophysics Data System (ADS)
Vignesh, K.; Suganthi, A.; Min, Bong-Ki; Kang, Misook
2015-01-01
In this present work, BiOI sensitized zirconia (BiOI-ZrO2) nanoparticles were fabricated using a precipitation-deposition method. The physicochemical characteristics of BiOI/ZrO2 were studied through X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), BET-surface area, X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (UV-vis-DRS) and photoluminescence (PL) spectroscopy techniques. The absorption maximum of ZrO2 was shifted to the visible region after sensitization with BiOI. BET-surface area results inferred that the prepared hetero-junctions were meso-porous in nature. The photocatalytic activity of BiOI-ZrO2 for the degradation of methyl violet (MV) dye under simulated solar light irradiation was investigated in detail. 3% BiOI-ZrO2 exhibited the highest photocatalytic performance (98% of MV degradation) when compared with ZrO2 and BiOI. The enhancement in the photocatalytic activity of BiOI-ZrO2 is ascribed to the sensitization effect of BiOI, suppression of electron-hole recombination and the formation of p-n hetero-junction.
NASA Astrophysics Data System (ADS)
Huo, Pengwei; Yan, Yongsheng; Li, Songtian; Li, Huaming; Huang, Weihong
2010-03-01
A series of poly-o-phenylenediamine/TiO 2/fly-ash cenospheres(POPD/TiO 2/fly-ash cenospheres) composites have been prepared from o-phenylenediamine and TiO 2/fly-ash cenospheres under various polymerization conditions. The properties of the samples were characterized by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), specific surface area (BET), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) and UV-vis diffuse reflectance spectrum (UV-vis DRS). Photocatalytic activity was studied by degradation of antibiotics waste water under visible light. The results indicate that the photo-induced method is viable for preparing modified photocatalysts, and the modified photocatalysts have good absorption in visible light range. The photocatalysts of POPD/TiO 2/fly-ash cenospheres which have good performance are prepared at pH 3 and 4, and the polymerized time around 40 min. When the photocatalysts are prepared under the conditions of pH 3 and polymerized time 40 min, the degradation rate of roxithromycin waste water could reach near 60%, and it indicates that the way of POPD modified TiO 2/fly-ash cenospheres to degrade the antibiotics waste water is viable.
NASA Astrophysics Data System (ADS)
Nada, Amr A.; Tantawy, Hesham R.; Elsayed, Mohamed A.; Bechelany, Mikhael; Elmowafy, Mohamed E.
2018-04-01
In this paper, magnetic nanocomposites are synthesized by loading reduced graphene oxide (RG) with two components of nanoparticles consisting of titanium dioxide (TiO2) and magnetite (Fe3O4) with varying amounts. The structural and magnetic features of the prepared composite photocatalysts were investigated by powder X-ray diffraction (XRD), Fourier transform infrared spectra (FT-IR), transmission electron microscopy (TEM), UV-vis diffuse reflectance spectra (UV-vis/DRS), Raman and vibrating sample magnetometer (VSM). The resulting TiO2/magnetite reduced graphene oxide (MRGT) composite demonstrated intrinsic visible light photocatalytic activity, on degradation of tartrazine (TZ) dye from a synthetic aqueous solution. Specifically, it exhibits higher photocatalytic activity than magnetite reduced graphene oxide (MRG) and TiO2 nanoparticles. The photocatalytic degradation of TZ dye when using MRG and TiO2 for 3 h under visible light was 35% and 10% respectively, whereas for MRGT it was more than 95%. The higher photocatalytic efficiency of MRGT is due to the existence of reduced graphene oxide and magnetite which enhances the photocatalytic efficiency of the composite in visible light towards the degradation of harmful soluble azo dye (tartrazine).
NASA Astrophysics Data System (ADS)
Saputra, I. S.; Yulizar, Y.
2017-04-01
ZnO nanoparticles (ZnO NPs) were biosynthesized.The growth was observed by a sol-gel method. ZnO were successfully formed through the reaction of zinc nitrate tetrahydrate Zn(NO3)2.4H2O precursor with aqueous leaf extract of Imperata cylindrica L (ICL). The structural and optical properties of ZnO were investigated. The as-synthesized products were characterized by UV-Visible (UV-Vis), UV diffuse reflectance spectroscopy (UV-DRS), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDS). UV-Vis absorption data showed hydrolysis and characteristic of absorption peak at 300 nm of Zn(OH)2. UV-DRS confirmed that ZnO NPs has the indirect band gap at 3.13 eV. FTIR spectrum revealed the functional groups and indicated the presence of protein as the capping and stabilizing agent on the ZnO surface. Powder XRD studies indicated the formation of pure wurtzite hexagonal structure with particle size of 11.9 nm. The detailed morphological and structural characterizations revealed that the synthesized products were hexagonal nanochip.
Development and applications of ruggedized VIS/NIR spectrometer system for oilfield wellbores
NASA Astrophysics Data System (ADS)
Fujisawa, Go; Yamate, Tsutomu
2013-12-01
The development and applications of a ruggedized visible to near-infrared (VIS/NIR) spectrometer system capable of measuring fluid spectra in oilfield wellbores are presented. Real-time assessment of formation fluid properties penetrated by an oilfield wellbore is critically important for oilfield operating companies to make informed decisions to optimize the development plan of the well and hydrocarbon reservoir. A ruggedized VIS/NIR spectrometer was designed and built to measure and analyze hydrocarbon spectra reliably under the harsh conditions of the oilfield wellbore environment, including temperature up to 175 °C, pressure up to 170 MPa, and severe mechanical shocks and vibrations. The accuracy of hydrocarbon group composition analysis was compared well with gas chromatography results in the laboratory.
Science Technology and Engineering Teachers' Emotional Intelligence vis-à-vis Classroom Management
ERIC Educational Resources Information Center
Llego, Jordan Hiso
2017-01-01
This study aimed to determine the relationship of emotional intelligence of science STE teachers' with their classroom management. This study used descriptive-correlational using survey questionnaire with total population sampling who are offering Science, Technology and Engineering curriculum in Region 1, Philippines with 113 respondents.…
Hybrid Citizenship: Latina Youth and the Politics of Belonging
ERIC Educational Resources Information Center
Bondy, Jennifer M.
2015-01-01
Drawing from interview data collected from high school students in Broward County, Florida, this article explores how eight adolescent Latinas understand citizenship and belonging vis-à-vis circulating images and discourses on Latina/o immigration, immigrant, and Latina. The author examines Latina youths' citizenship identities and belonging using…
School Discipline, School Uniforms and Academic Performance
ERIC Educational Resources Information Center
Baumann, Chris; Krskova, Hana
2016-01-01
Purpose: The purpose of this paper is to examine the role of school discipline in achieving academic performance. The study aims to clarify the role of permissive "vis-à-vis" authoritative teaching styles with an overarching hypothesis that better discipline leads to better academic performance. The authors also probe whether uniformed…
Investigating the Effect of Situational Awareness on Persistence of Doctoral Distance Learners
ERIC Educational Resources Information Center
Harleman, Thomas G.
2013-01-01
This quantitative study sought to identify the effect of heightened situational awareness (SA) on persistence of doctoral distance learners. Factors in the distance learners' micro-environment, vis-à-vis Urie Bronfenbrenner's (1979) ecology theory of human development, were the focus. Study participants included new doctoral candidates continuing…
Lifelong Learning to Empowerment: Beyond Formal Education
ERIC Educational Resources Information Center
Carr, Alexis; Balasubramanian, K.; Atieno, Rosemary; Onyango, James
2018-01-01
This paper discusses the relevance of lifelong learning vis-à-vis the Sustainable Development Goals (SDGs) and stresses the need for an approach blending formal education, non-formal and informal learning. The role of Open and Distance Learning (ODL) in moving beyond formal education and the importance of integrating pedagogy, andragogy and…
Reading Attitudes of Texas High School Students
ERIC Educational Resources Information Center
Bussert-Webb, Kathy; Zhang, Zhidong
2016-01-01
Through random sampling, we surveyed 2,568 high school students throughout Texas to determine their reading attitudes vis-à-vis individual and school background variables. Sources were the Rhody reading attitude scale and public domain campus summary data; the lenses of attitude theory and social justice informed this study. Significant…
Aspects of birth history and outcome in diplegics attending specialised educational facilities.
Bischof, Faith; Rothberg, Alan; Ratcliffe, Ingrid
2012-03-21
We aimed to study functional mobility and visual performance in spastic diplegic children and adolescents attending specialised schools. Spastic diplegia (SD) was confirmed by clinical examination. Birth and related history were added to explore relationships between SD, birth weight (BW) and duration of pregnancy. Place of birth, BW, gestational age (GA) and length of hospital stay were obtained by means of parental recall. Outcome measures included the functional mobility scale (FMS) and Beery tests of visuomotor integration (VMI) and visual perception (VIS). Forty participants were included (age 7 years 5 months - 19 years 6 months). Term and preterm births were almost equally represented. Functional mobility assessments showed that 20 were walking independently in school and community settings and the remainder used walking aids or wheelchairs. There were no significant correlations between BW or GA and outcomes (FMS, VIS-Z scores or VMI-Z scores) and Z scores were low. VIS scores correlated significantly with chronological age (p=0.024). There were also significant correlations between VIS and VMI scores and school grade appropriateness (p=0.004;p=0.027 respectively). Both term and preterm births were represented, and outcomes were similar regardless of GA. VIS and VMI were affected in both groups. Half of the group used assistive mobility devices and three-fifths were delayed in terms of their educational level. These problems require specialised teaching strategies, appropriate resources and a school environment that caters for mobility limitations.
Hydrothermal synthesis of tungsten doped tin dioxide nanocrystals
NASA Astrophysics Data System (ADS)
Zhou, Cailong; Li, Yufeng; Chen, Yiwen; Lin, Jing
2018-01-01
Tungsten doped tin dioxide (WTO) nanocrystals were synthesized through a one-step hydrothermal method. The structure, composition and morphology of WTO nanocrystals were characterized by x-ray diffraction, x-ray photoelectron spectroscopy, energy dispersive x-ray spectroscopy, UV-vis diffuse reflectance spectra, zeta potential analysis and high-resolution transmission electron microscopy. Results show that the as-prepared WTO nanocrystals were rutile-type structure with the size near 13 nm. Compared with the undoped tin dioxide nanocrystals, the WTO nanocrystals possessed better dispersity in ethanol phase and formed transparent sol.
1987-02-12
in 1985 production was just 11 million tons. Nevertheless, the disadvantage vis-a-vis the EEC’s steel industry is clearly reflected in the foreign...Privatization in Nordic Countries: Progress, Rethinking (NORDISK KONTAKT, No 14, 1986) • 54 FRANCE Industry Minister Details Restructuring of Ministry...Problems Facing Industrial Reconversion Plan Outlined (ACTUALIDAD ECONOMICA, 15 Dec 86) 68 MILITARY AUSTRIA Development of Air Space
Learning by Doing: Preparation of Baha'i Nonformal Tutors
ERIC Educational Resources Information Center
Closson, Rosemary B.; Kaye, Sylvia B.
2012-01-01
The Baha'i Faith, which was founded in 1863, holds as its purpose the awakening of humanity to invisible possibilities, providing humankind with conscious direction and hope vis-a-vis the challenges and perplexities of time (Rosen, 2010). The Baha'i writings explain that spiritual forces are the foundation of reality and that the Word of God is…
USDA-ARS?s Scientific Manuscript database
Visible/near-infrared (Vis/NIR) spectroscopy with wavelength range between 400 and 2500 nm combined with factor analysis method was tested to predict quality attributes of chicken breast fillets. Quality attributes, including color (L*, a*, b*), pH, and drip loss were analyzed using factor analysis ...
Cell Phone and Face-to-Face Interview Responses in Population-Based Surveys: How Do They Compare?
ERIC Educational Resources Information Center
Mahfoud, Ziyad; Ghandour, Lilian; Ghandour, Blanche; Mokdad, Ali H.; Sibai, Abla M.
2015-01-01
Findings on the reliability and cost-effectiveness of the use of cellular phones vis-à-vis face-to-face interviews in investigating health behaviors and conditions are presented for a national epidemiological sample from Lebanon. Using self-reported responses on identical questions, percentage agreement, ? statistics, and McNemar's test were used…
Does Social Labelling Encourage Child Schooling and Discourage Child Labour in Nepal?
ERIC Educational Resources Information Center
Chakrabarty, Sayan; Grote, Ulrike; Luchters, Guido
2011-01-01
This paper explores the determinants of child labour vis-a-vis child schooling. It further examines the influence of non-governmental organisations (NGOs) which are engaged in social labelling, on the incidence of child labour and schooling trade-off. The empirical results show that the probability of child schooling increases as well as child…
An Evaluation of Grades 9 and 10 Mathematics Textbooks vis-a-vis Fostering Problem Solving Skills
ERIC Educational Resources Information Center
Buishaw, Alemayehu; Ayalew, Assaye
2013-01-01
This study sought to evaluate the adequacy of integration of problematic situations and general problem-solving strategies (heuristics) in grades 9 and 10 mathematics textbooks. Grade 9 and grade 10 mathematics textbooks were used for analysis. Document analysis and interview were used as data gathering instruments. Document analysis was carried…
Colonial Museums in the Us (Un)translated
ERIC Educational Resources Information Center
Valdeón, Roberto A.
2015-01-01
This paper examines the role of museums in the creation of anglophone stories in the USA, and how the (non-)translation of signs contributes to create a narrative of exclusion vis-à-vis other groups, notably native Americans, the Spanish, and the French. Particular attention is paid to open-air museums that preserve old buildings and areas…
The Effectiveness of Title I: Synthesis of National-Level Evidence from 1966 to 2013
ERIC Educational Resources Information Center
Sousa, Sonia; Armor, David
2016-01-01
This paper reviews prior research to assess the effectiveness of Title I in closing the achievement gaps of disadvantaged students vis-à-vis their non-disadvantaged counterparts. A research synthesis approach is adopted to summarize national assessments of Title I conducted between 1966 and 2011. These analyses are supplemented by the authors'…
ERIC Educational Resources Information Center
Gyogi, Eiko
2015-01-01
This paper examines how children exercise their agency vis-à-vis their mother's beliefs and practices of bilingualism, especially code-switching, at home and elsewhere. The data were mainly collected through audio-recordings of family conversations both with and without the presence of the researcher and semi-structured interviews conducted during…
Cui Bono? On the Relative Merits of Technology-Enhanced Learning and Teaching in Higher Education
ERIC Educational Resources Information Center
Mykhnenko, Vlad
2016-01-01
This article provides evidence from a 4-year longitudinal study on the comparative use of illustrative video podcasts during Economic Geography lectures vis-à-vis traditional educational methods in order to guide pedagogic practice and future research on the relative merits of technology-enhanced learning in higher education. Key benefits derived…
ERIC Educational Resources Information Center
Gurney, Laura; Liyanage, Indika
2015-01-01
Under current Western neoliberal philosophy, promotion of efficiency and resolution of issues are typically expected to result from effective management. The education sector, too, has responded well to these expectations. Amongst such expectations, engagement in professional development activities (PDAs) by teachers of English as an additional…
ERIC Educational Resources Information Center
Gvion, Liora; Luzzatto, Diana
2008-01-01
This article focuses on the strategies that Israeli parents of children with high functioning communication disorders apply in their negotiations with municipal placement-committees, in order to realize their right to be fully involved in matters concerning their children's schooling. Our claim is that the parents introduce into the negotiation…
ERIC Educational Resources Information Center
French, Charles; Williams, Julie E.; Tang, Judy; Abrams, Eleanor; Townson, Lisa; Sabin, Mihaela; Sandmann, Lorilee R.; Wake, Cameron
2013-01-01
Over the last decade, the University of New Hampshire (UNH) has promoted mutually beneficial partnerships between faculty and community partners vis-à-vis the Engaged Scholars Academy (ESA), a faculty development program aimed at enhancing faculty understanding of the principles of partnership and engaged scholarship. This research seeks to…
ERIC Educational Resources Information Center
Alani, Ramoni Ayobami; Okunola, Phillips Olaide; Subair, Sikiru Omotayo
2010-01-01
Motivating learners in university depends largely on those services, processes and procedures whose primary purpose is to enhance and maintain learners' physical, social, intellectual and emotional well-being. This study examined the situation of welfare services in the context of university education vis-a-vis students' perceived motivation to…
"Obligatory Technologies": Explaining Why People Feel Compelled to Use Certain Technologies
ERIC Educational Resources Information Center
Chandler, Jennifer A.
2012-01-01
The ideas of technological determinism and the autonomy of technology are long-standing and widespread. This article explores why the use of certain technologies is perceived to be obligatory, thus fueling the fatalism of technological determinism and undermining our sense of freedom vis-a-vis the use of technologies. Three main mechanisms that…
1980-01-01
purpose of exporting cash crops but which generally did not cross colonial frontiers, and preferential trading systems and banking arrange- ments which...divide through cooperation in specific functional organisations--the Cocoa Producers Alliance (founded 1962), the African Groundnut Council (1964), the...arrangements essentially allowed EEC exports privileged access to Associates’ markets vis-a-vis the exports of all other countries, including the neighboring
NASA Astrophysics Data System (ADS)
Shew, A. M.; Ghosh, A.
2017-10-01
Remote sensing in the optical domain is widely used in agricultural monitoring; however, such initiatives pose a challenge for developing countries due to a lack of high quality in situ information. Our proposed methodology could help developing countries bridge this gap by demonstrating the potential to quantify patterns of dry season rice production in Bangladesh. To analyze approximately 90,000 km2 of cultivated land in Bangladesh at 30 m spatial resolution, we used two decades of remote sensing data from the Landsat archive and Google Earth Engine (GEE), a cloud-based geospatial data analysis platform built on Google infrastructure and capable of processing petabyte-scale remote sensing data. We reconstructed the seasonal patterns of vegetation indices (VIs) for each pixel using a harmonic time series (HTS) model, which minimizes the effects of missing observations and noise. Next, we combined the seasonality information of VIs with our knowledge of rice cultivation systems in Bangladesh to delineate rice areas in the dry season, which are predominantly hybrid and High Yielding Varieties (HYV). Based on historical Landsat imagery, the harmonic time series of vegetation indices (HTS-VIs) model estimated 4.605 million ha, 3.519 million ha, and 4.021 million ha of rice production for Bangladesh in 2005, 2010, and 2015 respectively. Fine spatial scale information on HYV rice over the last 20 years will greatly improve our understanding of double-cropped rice systems, current status of production, and potential for HYV rice adoption in Bangladesh during the dry season.
Weber, E; Doppelmayr, M
2016-12-01
Motor imagery (MI) is a frequently used and effective method for motor learning in sports as well as in other domains. Electroencephalography (EEG) and functional magnetic resonance imaging (fMRI) studies indicated that experts within a certain sport exhibit a more pronounced brain activity during MI as compared to novices. Similar to the execution, during MI the motor sequence has to be planned. Thus, the frontal attentional system, in part represented by the frontal midline theta (4-7Hz), is closely related to these processes and presumably plays a major role in MI as well. In this study, a MI dart training and its impact on frontal midline theta activity (fmt) during MI are examined. 53 healthy subjects with no prior dart experience were randomly allocated to a kinesthetic training group (KinVis) or to a control group (Control). Both groups performed 15 training sessions. While in the KinVis group dart throwing was accompanied by MI, the Control group trained without MI. Dart performance and fmt activity during MI within the first and the 15th session were compared. As expected, the performance increase was more pronounced in the KinVis group. Furthermore, frontal theta amplitude was significantly increased in the KinVis group during MI in the 15th training session as compared to the baseline. These results confirm the effectivity of MI. The enhanced fmt activity in the KinVis group can be interpreted as a better allocation of the requested resources in the frontal attentional network after MI. Copyright © 2016 Elsevier B.V. All rights reserved.
Self-Organizing-Map Program for Analyzing Multivariate Data
NASA Technical Reports Server (NTRS)
Li, P. Peggy; Jacob, Joseph C.; Block, Gary L.; Braverman, Amy J.
2005-01-01
SOM_VIS is a computer program for analysis and display of multidimensional sets of Earth-image data typified by the data acquired by the Multi-angle Imaging Spectro-Radiometer [MISR (a spaceborne instrument)]. In SOM_VIS, an enhanced self-organizing-map (SOM) algorithm is first used to project a multidimensional set of data into a nonuniform three-dimensional lattice structure. The lattice structure is mapped to a color space to obtain a color map for an image. The Voronoi cell-refinement algorithm is used to map the SOM lattice structure to various levels of color resolution. The final result is a false-color image in which similar colors represent similar characteristics across all its data dimensions. SOM_VIS provides a control panel for selection of a subset of suitably preprocessed MISR radiance data, and a control panel for choosing parameters to run SOM training. SOM_VIS also includes a component for displaying the false-color SOM image, a color map for the trained SOM lattice, a plot showing an original input vector in 36 dimensions of a selected pixel from the SOM image, the SOM vector that represents the input vector, and the Euclidean distance between the two vectors.
Koeppe, Benjamin; Tolstoy, Peter M; Limbach, Hans-Heinrich
2011-05-25
Combined low-temperature NMR/UV-vis spectroscopy (UVNMR), where optical and NMR spectra are measured in the NMR spectrometer under the same conditions, has been set up and applied to the study of H-bonded anions A··H··X(-) (AH = 1-(13)C-2-chloro-4-nitrophenol, X(-) = 15 carboxylic acid anions, 5 phenolates, Cl(-), Br(-), I(-), and BF(4)(-)). In this series, H is shifted from A to X, modeling the proton-transfer pathway. The (1)H and (13)C chemical shifts and the H/D isotope effects on the latter provide information about averaged H-bond geometries. At the same time, red shifts of the π-π* UV-vis absorption bands are observed which correlate with the averaged H-bond geometries. However, on the UV-vis time scale, different tautomeric states and solvent configurations are in slow exchange. The combined data sets indicate that the proton transfer starts with a H-bond compression and a displacement of the proton toward the H-bond center, involving single-well configurations A-H···X(-). In the strong H-bond regime, coexisting tautomers A··H···X(-) and A(-)···H··X are observed by UV. Their geometries and statistical weights change continuously when the basicity of X(-) is increased. Finally, again a series of single-well structures of the type A(-)···H-X is observed. Interestingly, the UV-vis absorption bands are broadened inhomogeneously because of a distribution of H-bond geometries arising from different solvent configurations.
ERIC Educational Resources Information Center
Roizen, Merle A.
A study of students' self-expressed test-taking strategies for reading comprehension tests in English as a second language (ESL) had as subjects 86 Hebrew-speaking university students in Israel. The students were given a reading comprehension test, half with open-ended questions and half with multiple choice. Half the responses were anonymous and…
NASA Astrophysics Data System (ADS)
Nocita, M.; Stevens, A.; Toth, G.; van Wesemael, B.; Montanarella, L.
2012-12-01
In the context of global environmental change, the estimation of carbon fluxes between soils and the atmosphere has been the object of a growing number of studies. This has been motivated notably by the possibility to sequester CO2 into soils by increasing the soil organic carbon (SOC) stocks and by the role of SOC in maintaining soil quality. Spatial variability of SOC masks its slow accumulation or depletion, and the sampling density required to detect a change in SOC content is often very high and thus very expensive and labour intensive. Visible near infrared diffuse reflectance spectroscopy (Vis-NIR DRS) has been shown to be a fast, cheap and efficient tool for the prediction of SOC at fine scales. However, when applied to regional or country scales, Vis-NIR DRS did not provide sufficient accuracy as an alternative to standard laboratory soil analysis for SOC monitoring. Under the framework of Land Use/Cover Area Frame Statistical Survey (LUCAS) project of the European Commission's Joint Research Centre (JRC), about 20,000 samples were collected all over European Union. Soil samples were analyzed for several physical and chemical parameters, and scanned with a Vis-NIR spectrometer in the same laboratory. The scope of our research was to predict SOC content at European scale using LUCAS spectral library. We implemented a modified local partial least square regression (l-PLS) including, in addition to spectral distance, other potentially useful covariates (geography, texture, etc.) to select for each unknown sample a group of predicting neighbours. The dataset was split in mineral soils under cropland, mineral soils under grassland, mineral soils under woodland, and organic soils due to the extremely diverse spectral response of the four classes. Four every class training (70%) and test (30%) sets were created to calibrate and validate the SOC prediction models. The results showed very good prediction ability for mineral soils under cropland and mineral soils under grassland, with a root mean square error (RMSE) of 3.6 and 7.2 g C kg-1 respectively, while mineral soils under woodland and organic soils predictions were less accurate (RMSE of 11.9 and 51.1 g C kg-1). The RMSE was lower (except for organic soils) when sand content was used as covariate in the selection of the l-PLS predicting neighbours. The obtained results proved that: (i) Although the enormous spatial variability of European soils, the developed modified l-PLS algorithm was able to produce stable calibrations and accurate predictions. (ii) It is essential to invest in spectral libraries built according to sampling strategies, based on soil types, and a standardized laboratory protocol. (iii) Vis-NIR DRS spectroscopy is a powerful and cost effective tool to predict SOC content at regional/continental scales, and should be converted from a pure research discipline into a reference operational method decreasing the uncertainties of SOC monitoring and terrestrial ecosystems carbon fluxes at all scales.
Power system modeling and optimization methods vis-a-vis integrated resource planning (IRP)
NASA Astrophysics Data System (ADS)
Arsali, Mohammad H.
1998-12-01
The state-of-the-art restructuring of power industries is changing the fundamental nature of retail electricity business. As a result, the so-called Integrated Resource Planning (IRP) strategies implemented on electric utilities are also undergoing modifications. Such modifications evolve from the imminent considerations to minimize the revenue requirements and maximize electrical system reliability vis-a-vis capacity-additions (viewed as potential investments). IRP modifications also provide service-design bases to meet the customer needs towards profitability. The purpose of this research as deliberated in this dissertation is to propose procedures for optimal IRP intended to expand generation facilities of a power system over a stretched period of time. Relevant topics addressed in this research towards IRP optimization are as follows: (1) Historical prospective and evolutionary aspects of power system production-costing models and optimization techniques; (2) A survey of major U.S. electric utilities adopting IRP under changing socioeconomic environment; (3) A new technique designated as the Segmentation Method for production-costing via IRP optimization; (4) Construction of a fuzzy relational database of a typical electric power utility system for IRP purposes; (5) A genetic algorithm based approach for IRP optimization using the fuzzy relational database.
49 CFR 826.6 - Allowable fees and expenses.
Code of Federal Regulations, 2011 CFR
2011-10-01
... these rules may exceed $75 indexed as follows: ER14JN94.001 The CPI to be used is the annual average CPI, All Urban Consumers, U.S. City Average, All Items, except where a local, All Item index is available. Where a local index is available, but results in a manifest inequity vis-a-vis the U.S. City Average...
49 CFR 826.6 - Allowable fees and expenses.
Code of Federal Regulations, 2010 CFR
2010-10-01
... these rules may exceed $75 indexed as follows: ER14JN94.001 The CPI to be used is the annual average CPI, All Urban Consumers, U.S. City Average, All Items, except where a local, All Item index is available. Where a local index is available, but results in a manifest inequity vis-a-vis the U.S. City Average...
Benito-Lopez, Fernando; Verboom, Willem; Kakuta, Masaya; Gardeniers, J Han G E; Egberink, Richard J M; Oosterbroek, Edwin R; van den Berg, Albert; Reinhoudt, David N
2005-06-14
With a miniaturized (3 microL volume) fiber-optics based system for on-line measurement by UV/Vis spectroscopy, the reaction rate constants (at different pressures) and the activation volumes (deltaV(not =)) were determined for a nucleophilic aromatic substitution and an aza Diels-Alder reaction in a capillary microreactor.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jones, Brant M.; Kaiser, Ralf I.; Strazzulla, Giovanni
2014-02-01
Ozone has been detected on the surface of Ganymede via observation of the Hartley band through the use of ultraviolet spectroscopy and is largely agreed upon to be formed by radiolytic processing via interaction of magnetospheric energetic ions and/or electrons with oxygen-bearing ices on Ganymede's surface. Interestingly, a clearly distinct band near 300 nm within the shoulder of the UV-Vis spectrum of Ganymede was also observed, but currently lacks an acceptable physical or chemical explanation. Consequently, the primary motivation behind this work was the collection of UV-Vis absorption spectroscopy of ozone formation by energetic electron bombardment of a variety ofmore » oxygen-bearing ices (oxygen, carbon dioxide, water) relevant to this moon as well as other solar system. Ozone was indeed synthesized in pure ices of molecular oxygen, carbon dioxide and a mixture of water and oxygen, in agreement with previous studies. The Hartley band of the ozone synthesized in these ice mixtures was observed in the UV-Vis spectra and compared with the spectrum of Ganymede. In addition, a solid state ozone absorption cross section of 6.0 ± 0.6 × 10{sup –17} cm{sup 2} molecule{sup –1} was obtained from the UV-Vis spectral data. Ozone was not produced in the irradiated carbon dioxide-water mixtures; however, a spectrally 'red' UV continuum is observed and appears to reproduce well what is observed in a large number of icy moons such as Europa.« less
Alimi, Olubukola S; Farner Budarz, Jeffrey; Hernandez, Laura M; Tufenkji, Nathalie
2018-02-20
Plastic litter is widely acknowledged as a global environmental threat, and poor management and disposal lead to increasing levels in the environment. Of recent concern is the degradation of plastics from macro- to micro- and even to nanosized particles smaller than 100 nm in size. At the nanoscale, plastics are difficult to detect and can be transported in air, soil, and water compartments. While the impact of plastic debris on marine and fresh waters and organisms has been studied, the loads, transformations, transport, and fate of plastics in terrestrial and subsurface environments are largely overlooked. In this Critical Review, we first present estimated loads of plastics in different environmental compartments. We also provide a critical review of the current knowledge vis-à-vis nanoplastic (NP) and microplastic (MP) aggregation, deposition, and contaminant cotransport in the environment. Important factors that affect aggregation and deposition in natural subsurface environments are identified and critically analyzed. Factors affecting contaminant sorption onto plastic debris are discussed, and we show how polyethylene generally exhibits a greater sorption capacity than other plastic types. Finally, we highlight key knowledge gaps that need to be addressed to improve our ability to predict the risks associated with these ubiquitous contaminants in the environment by understanding their mobility, aggregation behavior and their potential to enhance the transport of other pollutants.
The Role of E-learning in Science Education vis-a-vis Teacher Training Institutes in Middle East
ERIC Educational Resources Information Center
Deshmukh, Veena; Forawi, Sufian; Jaiswal, Anuradha
2012-01-01
This paper describes the effect of "online science teaching" in teacher education institutes in the UAE (United Arab Emirates). The study was undertaken to understand the mindset and perceptions of educators with respect to online education with a sample comprising of 20 pre-service teachers in the second semester of a one-year post…
ERIC Educational Resources Information Center
Tan, Yao Sua; Goh, Soo Khoon
2014-01-01
This paper examines the responses of a Malaysian public university, namely Universiti Sains Malaysia, to the impact of globalisation vis-à-vis three key issues: international students, academic publications and world university rankings. There are concerted efforts put in place by the university to recruit more international students. But a global…
Outcomes of Curricular Enhancement in a Health Program: LPU CAMP Experience
ERIC Educational Resources Information Center
Valdez, Anacleta P.; Panganiban, Citadel A.; Alday, Mark H.
2013-01-01
Higher educational system has gone through substantial reforms and changes vis-à-vis curriculum innovation over the past years. The evaluation of a revised program is one of the most relevant courses of action done when curriculum change is to be implemented. One of the main reasons is that it is a chance for practitioners to test for themselves…
The Decline and Fall of English in Hong Kong's Legislative Council
ERIC Educational Resources Information Center
Evans, Stephen
2014-01-01
This article presents the findings of a corpus-based study of the use of English vis-à-vis Cantonese and Putonghua in Hong Kong's Legislative Council in the past four decades. The objective of the study was to track the changing fortunes of the three languages in a key government institution during a period of unprecedented political, economic and…
What Might a Non-Confessional Theory of Catholic Education Look Like?
ERIC Educational Resources Information Center
Whittle, Sean
2016-01-01
This article emulates the new stance of Professor Michael Hand on faith schools. He illustrates how theological criteria could be used to inform and guide curriculum aims in a way that avoids indoctrination and the perils of faith-based education. This approach is adopted vis-à-vis Catholic education in order to sketch out what a non-confessional…
Advanced Theory of Mind in Children Using Augmentative and Alternative Communication
ERIC Educational Resources Information Center
Sundqvist, Anett; Ronnberg, Jerker
2010-01-01
This study focused on the attainment of Theory of Mind (ToM) in children (aged 6 to 13) with complex communication needs who used augmentative and alternative communication (AAC). The AAC group (n = 14) was matched to a younger group, without disabilities, vis-a-vis nonverbal mental age. A second comparison group consisting of children with mild…
Political Values in Educational Finance: A Comparative Study of Canada and the United States.
ERIC Educational Resources Information Center
Lawton, Stephen B.
Equality of educational opportunity is a social goal in both the United States and Canada; yet, the nations differ considerably in their approaches and progress toward this objective. Canada appears to have achieved greater equality of condition vis-a-vis education than has the United States, judged by variation in expenditure per student among…
Shishir, Sharmin; Tsuyuzaki, Shiro
2018-05-11
Detecting fine-scale spatiotemporal land use changes is a prerequisite for understanding and predicting the effects of urbanization and its related human impacts on the ecosystem. Land use changes are frequently examined using vegetation indices (VIs), although the validation of these indices has not been conducted at a high resolution. Therefore, a hierarchical classification was constructed to obtain accurate land use types at a fine scale. The characteristics of four popular VIs were investigated prior to examining the hierarchical classification by using Purbachal New Town, Bangladesh, which exhibits ongoing urbanization. These four VIs are the normalized difference VI (NDVI), green-red VI (GRVI), enhanced VI (EVI), and two-band EVI (EVI2). The reflectance data were obtained by the IKONOS (0.8-m resolution) and WorldView-2 sensor (0.5-m resolution) in 2001 and 2015, respectively. The hierarchical classification of land use types was constructed using a decision tree (DT) utilizing all four of the examined VIs. The accuracy of the classification was evaluated using ground truth data with multiple comparisons and kappa (κ) coefficients. The DT showed overall accuracies of 96.1 and 97.8% in 2001 and 2015, respectively, while the accuracies of the VIs were less than 91.2%. These results indicate that each VI exhibits unique advantages. In addition, the DT was the best classifier of land use types, particularly for native ecosystems represented by Shorea forests and homestead vegetation, at the fine scale. Since the conservation of these native ecosystems is of prime importance, DTs based on hierarchical classifications should be used more widely.
Method of predicting mechanical properties of decayed wood
Kelley, Stephen S.
2003-07-15
A method for determining the mechanical properties of decayed wood that has been exposed to wood decay microorganisms, comprising: a) illuminating a surface of decayed wood that has been exposed to wood decay microorganisms with wavelengths from visible and near infrared (VIS-NIR) spectra; b) analyzing the surface of the decayed wood using a spectrometric method, the method generating a first spectral data of wavelengths in VIS-NIR spectra region; and c) using a multivariate analysis to predict mechanical properties of decayed wood by comparing the first spectral data with a calibration model, the calibration model comprising a second spectrometric method of spectral data of wavelengths in VIS-NIR spectra obtained from a reference decay wood, the second spectral data being correlated with a known mechanical property analytical result obtained from the reference decayed wood.