Late Quaternary distal tephra-fall deposits in lacustrine sediments, Kenai Peninsula, Alaska

USGS Publications Warehouse

de Fontaine, C.S.; Kaufman, D.S.; Scott, Anderson R.; Werner, A.; Waythomas, C.F.; Brown, T.A.

2007-01-01

Tephra-fall deposits from Cook Inlet volcanoes were detected in sediment cores from Tustumena and Paradox Lakes, Kenai Peninsula, Alaska, using magnetic susceptibility and petrography. The ages of tephra layers were estimated using 21 14C ages on macrofossils. Tephras layers are typically fine, gray ash, 1-5??mm thick, and composed of varying proportions of glass shards, pumice, and glass-coated phenocrysts. Of the two lakes, Paradox Lake contained a higher frequency of tephra (0.8 tephra/100 yr; 109 over the 13,200-yr record). The unusually large number of tephra in this lake relative to others previously studied in the area is attributed to the lake's physiography, sedimentology, and limnology. The frequency of ash fall was not constant through the Holocene. In Paradox Lake, tephra layers are absent between ca. 800-2200, 3800-4800, and 9000-10,300??cal yr BP, despite continuously layered lacustrine sediment. In contrast, between 5000 and 9000??cal yr BP, an average of 1.7 tephra layers are present per 100 yr. The peak period of tephra fall (7000-9000??cal yr BP; 2.6 tephra/100 yr) in Paradox Lake is consistent with the increase in volcanism between 7000 and 9000 yr ago recorded in the Greenland ice cores. ?? 2007 Elsevier Inc. All rights reserved.

Extraction and speciation of arsenic in lacustrine sediments

USGS Publications Warehouse

Ficklin, W.H.

1990-01-01

Arsenic was partially extracted with 4.OM hydrochloric acid, from samples collected at 25-cm intervals in a 350-cm column of sediment at Milltown Reservoir, Montana and from a 60-cm core of sediment collected at the Cheyenne River Embayment of Lake Oahe, South Dakota. The sediment in both reservoirs is highly contaminated with arsenic. The extracted arsenic was separated into As(III) and As(V) on acetate form Dowex 1-X8 ion-exchange resin with 0.12M HCl eluent. Residual arsenic was sequentially extracted with KClO3 and HCl. Arsenic was determined by graphite-furnace atomic-absorption spectrometry. The analytical results define oxidized and reduced zones in the sediment columns. ?? 1990.

Trace fossil analysis of lacustrine facies and basins

USGS Publications Warehouse

Buatois, L.A.; Mangano, M.G.

1998-01-01

Two ichnofacies are typical of lacustrine depositional systems. The Scoyenia ichnofacies characterizes transitional terrestrial/nonmarine aquatic substrates, periodically inundated or desiccated, and therefore is commonly present in lake margin facies. The Mermia ichnofacies is associated with well oxygenated, permanent subaqueous, fine-grained substrates of hydrologically open, perennial lakes. Bathymetric zonations within the Mermia ichnofacies are complicated by the wide variability of lacustrine systems. Detected proximal-distal trends are useful within particular lake basins, but commonly difficult to extrapolate to other lakes. Other potential ichnofacies include the typically marine Skolithos ichnofacies for high-energy zones of lakes and substrate-controlled, still unnamed ichnofacies, associated to lake margin deposits. Trace fossils are useful for sedimentologic analysis of event beds. Lacustrine turbidites are characterized by low-diversity suites, reflecting colonization by opportunistic organisms after the turbidite event. Underflow current beds record animal activity contemporaneous with nearly continuous sedimentation. Ichnologic studies may also help to distinguish between marine and lacustrine turbidites. Deep-marine turbidites host the Nereites ichnofacies that consists of high diversity of ornate grazing traces and graphoglyptids, recording highly specialized feeding strategies developed to solve the problem of the scarcity of food in the deep sea. Deep lacustrine environments contain the Mermia ichnofacies, which is dominated by unspecialized grazing and feeding traces probably related to the abundance and accessibility of food in lacustrine systems. The lower diversity of lacustrine ichnofaunas in comparison with deep-sea assemblages more likely reflects lower species diversity as a consequence of less stable conditions. Increase of depth and extent of bioturbation through geologic time produced a clear signature in the ichnofabric record of

Geophysical imaging of the lacustrine sediments deposited in the La Calderilla Volcanic Caldera (Gran Canaria Island, Spain) for paleoclimate research

NASA Astrophysics Data System (ADS)

Himi, Mahjoub; Rodríguez-González, Alejandro; Criado, Constantino; Tapias, Josefina C.; Ravazzi, Cesare; Pérez-Torrado, Francisco; Casas, Albert

2016-04-01

The discovery of well-preserved maar structures is important not only for studying the eruptive activity and formation of volcanoes, but also for paleoclimate research, since laminated maar lake sediments may contain very detailed archives of climate and environmental history. Maars are a singular type of volcanic structure generated by explosive phreatomagmatic eruptions as a result of interaction between rising magma and groundwater. This kind of structures are characterised by circular craters, often filled with water and/or lacustrine sediments and surrounded by a ring of pyroclastic deposits.Recently a borehole was drilled at the bottom of La Calderilla volcanic complex which penetrated about 8.7 m in its sedimentary sequence and paleobotanical study has supplied the first evidence of paleoenvironmental evolution during the Holocene on the Gran Canaria Island. This survey, however, did not penetrate into the substrate because the total thickness of the sedimentary fill was unknown. Since the age of formation of La Calderilla volcanic complex based on K/Ar dating is about 85,000 years (Upper Pleistocene), the possibility of its sedimentary fill extends beyond of the Holocene is extremely attractive, since, for example, there are few paleoenvironmental data regarding how much the last glaciation that affected the Canary Islands. In these circumstances, the knowledge of the total thickness of the lacustrine sediments is crucial to design a deeper borehole in the next future. Therefore, the subsurface characterisation provided by geophysics is essential for determining thickness and geometry of the sedimentary filling. Multielectrode ERT method was used to obtain five 2-D resistivity cross-sections into La Calderilla volcanic caldera. An Iris Syscal Pro resistivity system with 48 electrodes connected to a 94 m long cable (2m electrode spacing) in Wenner-Schlumberger configuration for an investigation depth of about 20 m. Data quality (q <2 %).was assessed by

Geochemical characteristics of organic compounds in a permafrost sediment core sample from northeast Siberia, Russia

NASA Technical Reports Server (NTRS)

Matsumoto, G. I.; Friedmann, E. I.; Gilichinsky, D. A.

1995-01-01

We studied total organic carbon (TOC), hydrocarbons and fatty acids in a permafrost sediment core sample (well 6-90, length 32.0 m, 1.5-2.5 Ma BP) from northeast Siberia (approximately 70 degrees N, 158 degrees E), Russia, to elucidate their geochemical features in relation to source organisms and paleoenvironmental conditions. Long-chain n-alkanes and n-alkanoic acids (>C19) were most predominant hydrocarbons and fatty acids, respectively, so organic matter in the sediment core was derived mainly from vascular plants and, to a much smaller extent, from bacteria. Low concentrations of unsaturated fatty acids revealed that organic matter in the sediment core was considerably degraded during and/or after sedimentation. The predominance of vascular plant components, the major ionic components of nonmarine sources, and geological data strongly implied that the sediment layers were formed in shallow lacustrine environments, such as swamp with large influences of tundra or forest-tundra vegetation. Also, no drastic changes in paleoenvironmental conditions for biological activity or geological events, such as sea transgressions or ice-sheet influences, occurred at the sampling site approximately 100 km from the coast of the East Siberian Sea during the late Pliocene an early Pleistocene periods.

Holocene glacier fluctuations inferred from lacustrine sediment, Emerald Lake, Kenai Peninsula, Alaska

NASA Astrophysics Data System (ADS)

LaBrecque, Taylor S.; Kaufman, Darrell S.

2016-01-01

Physical and biological characteristics of lacustrine sediment from Emerald Lake were used to reconstruct the Holocene glacier history of Grewingk Glacier, southern Alaska. Emerald Lake is an ice-marginal threshold lake, receiving glaciofluvial sediment when Grewingk Glacier overtops the topographic divide that separates it from the lake. Sub-bottom acoustical profiles were used to locate core sites to maximize both the length and resolution of the sedimentary sequence recovered in the 4-m-long cores. The age model for the composite sequence is based on 13 14C ages and a 210Pb profile. A sharp transition from the basal inorganic mud to organic-rich mud at 11.4 ± 0.2 ka marks the initial retreat of Grewingk Glacier below the divide of Emerald Lake. The overlaying organic-rich mud is interrupted by stony mud that records a re-advance between 10.7 ± 0.2 and 9.8 ± 0.2 ka. The glacier did not spill meltwater into the lake again until the Little Ice Age, consistent with previously documented Little Ice Ages advances on the Kenai Peninsula. The retreat of Grewingk Glacier at 11.4 ka took place as temperature increased following the Younger Dryas, and the subsequent re-advance corresponds with a climate reversal beginning around 11 ka across southern Alaska.

Earthquake-induced soft-sediment deformation structures in Late Pleistocene lacustrine deposits of Issyk-Kul lake (Kyrgyzstan)

NASA Astrophysics Data System (ADS)

Gladkov, A. S.; Lobova, E. U.; Deev, E. V.; Korzhenkov, A. M.; Mazeika, J. V.; Abdieva, S. V.; Rogozhin, E. A.; Rodkin, M. V.; Fortuna, A. B.; Charimov, T. A.; Yudakhin, A. S.

2016-10-01

This paper discusses the composition and distribution of soft-sediment deformation structures induced by liquefaction in Late Pleistocene lacustrine terrace deposits on the southern shore of Issyk-Kul Lake in the northern Tien Shan mountains of Kyrgyzstan. The section contains seven deformed beds grouped in two intervals. Five deformed beds in the upper interval contain load structures (load casts and flame structures), convolute lamination, ball-and-pillow structures, folds and slumps. Deformation patterns indicate that a seismic trigger generated a multiple slump on a gentle slope. The dating of overlying subaerial deposits suggests correlation between the deformation features and strong earthquakes in the Late Pleistocene.

The Index to Marine and Lacustrine Geological Samples: Improving Sample Accessibility and Enabling Current and Future Research

NASA Astrophysics Data System (ADS)

Moore, C.

2011-12-01

included in anticipation of opportunities for interconnectivity with Integrated Earth Data Applications (IEDA) systems. To promote interoperability and broaden exposure via the semantic web, NGDC is publishing lithologic classification schemes and terminology used in the Index as Simple Knowledge Organization System (SKOS) vocabularies, coordinating with R2R and the Consortium for Ocean Leadership for consistency. Availability in SKOS form will also facilitate use of the vocabularies in International Standards Organization (ISO) 19115-2 compliant metadata records. NGDC provides stewardship for the Index on behalf of U.S. repositories as the NSF designated "appropriate National Data Center" for data and metadata pertaining to sea floor samples as specified in the 2011 Division of Ocean Sciences Sample and Data Policy, and on behalf of international partners via a collocated World Data Center. NGDC operates on the Open Archival Information System (OAIS) reference model. Active Partners: Antarctic Marine Geology Research Facility, Florida State University; British Ocean Sediment Core Research Facility; Geological Survey of Canada; Integrated Ocean Drilling Program; Lamont-Doherty Earth Observatory; National Lacustrine Core Repository, University of Minnesota; Oregon State University; Scripps Institution of Oceanography; University of Rhode Island; U.S. Geological Survey; Woods Hole Oceanographic Institution.

Palaeoenvironmental implications of a Holocene sequence of lacustrine-peat sediments from the desert-loess transitional zone in Northern China

NASA Astrophysics Data System (ADS)

Jia, Feifei; Lu, Ruijie; Liu, Xiaokang; Zhao, Chao; Lv, Zhiqiang; Gao, Shangyu

2018-05-01

A high-resolution lacustrine-peat record from the desert-loess transitional zone in Northern China was obtained to reconstruct Holocene environmental change in the region. AMS 14C dates are used to provide a chronology. The results indicate that the site was a desert environment before 12.2 cal kyr BP, and was then occupied by a paleolake which started to shrink, with a wetland occurring from 6.2 to 3.0 cal kyr BP. Subsequently, the site became a seasonally water-filled depression. Based on the lithology and measurements of grain size and total organic carbon content, the climate changed from arid to humid at 12.2 cal kyr BP, and became more humid after 8.3 cal kyr BP. From 6.2 to 3.0 cal kyr BP, precipitation decreased but the climate remained at an optimum. After 3.0 cal kyr BP, the climate was dry overall but with several humid intervals. A comparison of paleoclimatic records from lacustrine and aeolian deposits from the region reveals a discrepancy about the nature of the early Holocene climate, and we conclude that this is because lacustrine sediments responded more sensitively to precipitation than aeolian deposits when the temperature was low. The environmental evolution of the region was synchronous with changes in the Asian summer monsoon (ASM), but temperature also played a key role in the early Holocene.

Summer temperatures inferred from varved lacustrine sediment at Iceberg Lake in southcentral Alaska

NASA Astrophysics Data System (ADS)

Diedrich, K.; Loso, M. G.

2010-12-01

Iceberg Lake, a glacier-dammed lake in southcentral Alaska, has been previously shown to record over 1,500 years of continuous laminated lacustrine sediment deposition. Because previous work was based on examination of subaerial outcrops exposed by stream incision in the bed of the jökulhlaup-drained lake, the length of the record was limited by the extent of the outcrops. In August of 2010, we returned to core the remote lake; our goal was recovery of the complete sedimentary record in the lake, extending perhaps back to the onset of late Holocene glaciation—around 3-5 ka in this region. We used a Vibarcorer system to recover sediment cores from two locations, one near the site of previous work and another at the distal end of the lake. The longest cores recovered were 5.2 meters and 6.2 meters at the proximal and distal sites, respectively. Based on the average lamination thickness established previously at the proximal site (4.7 mm), these cores should each represent over 1000 years of sediment accumulation, and likely much longer at the distal site, where laminations are expected to be thinner. Having established previously that the lake’s laminations are annual varves and that they are positively correlated with summer (melt-season) temperatures, our analysis is focused on documenting a long time-series of annual sediment accumulation and summer-layer particle size. Both measurements will be used to interpret the history of summer temperatures. The cores may also provide sedimentary evidence of the timing of advances/retreats of nearby glaciers, including the Tana Glacier and Bagley Icefield, helping to clarify the poorly-constrained timing of neoglaciation in Southern Alaska. The paleoclimate record produced at Iceberg Lake will be included in the Arctic System Science 8ka project

Impacts of flamingos on saline lake margin and shallow lacustrine sediments in the Kenya Rift Valley

NASA Astrophysics Data System (ADS)

Scott, Jennifer J.; Renaut, Robin W.; Owen, R. Bernhart

2012-11-01

Studies of modern, Holocene, and Pleistocene sediments around saline to hypersaline, alkaline Lake Bogoria and Lake Magadi show that evidence of flamingo activity in marginal areas of these lakes is nearly ubiquitous. Flamingos produce discrete structures such as webbed footprints (~ 9 cm long, ~ 11 cm wide) and nest mounds (~ 30 cm wide, ~ 20 cm high), and they also extensively rework sediments in delta front, delta plain, and shoreline areas. Large (~ 0.5-2 cm in diameter), pinched, 'bubble pores' and ped-like mud clumps are formed by the trampling and churning of wet clay-rich sediments in these settings. Flamingo nest mounds, although superficially similar to some thrombolite mounds, are typically internally structureless, unless formed on pre-existing sediments that preserve internal structures. The flamingo mounds consist of a dense, packed oval-shaped core, a surrounding 'body' of packed sediment, and an external layer with a ped-like texture of clumped mud. The nests may contain open holes from roots or feather shafts incorporated into the nest, and (or) burrows produced once the nests are abandoned. In areas with high densities of flamingos, lake margin sediments may be preferentially compacted, particularly at breeding sites, and become resistant to subaerial erosion and the effects of transgressive ravinement on time scales ranging from seasons to tens of thousands of years. The relatively well-compacted nest mounds and associated sediments also contribute to the stability of delta distributary channels during regressive-transgressive cycles, and can lead to the minor channelization of unconfined flows where currents are diverted around nest mounds. Pleistocene exhumed surfaces of relatively well-indurated lake margin sediments at Lake Bogoria and Lake Magadi that are interpreted as combined regressive and transgressive surfaces (flooding surface/sequence boundary) preserve evidence of flamingo activities, and are overlain by younger, porous lacustrine

An isotopic study of a fluvial-lacustrine sequence: The Plio-Pleistocene koobi fora sequence, East Africa

USGS Publications Warehouse

Cerling, T.E.; Bowman, J.R.; O'Neil, J.R.

1988-01-01

Stable isotopic analyses of Plio-Pleistocene and modern sediments in the fluvial-lacustrine system occupying the Turkana Basin, East Africa provide constraints on the paleoenvironmental and diagenetic histories of the Pliocene through the Recent sediments in the basin. The ??13C values for carbonates in lacustrine sediments range from -15 to +22??? relative to PDB, depending on the varying proportions of CO2 from the atmospheric reservoir and from various metabolic sources. The ??18O values of carbonates in lacustrine sediments indicate that the isotopic composition of paleolake water varied by over 10??? from the Pliocene to the present. The ??13C values for pedogenic carbonates record paleoccologic variations and suggest that C4 plants did not become well established in the preserved depositional parts of the basin until about 1.8 myr ago. The ??18O values pedogenic carbonates suggest a range of over 10??? for the isotopic composition of soil water during this interval. They also suggest a period of major climatic instability from about 3.4 to 3.1 myr and at about 1.8 myr. Together, the ??13C and ??18O values of pedogenic carbonates indicate that the present conditions are as arid and hot as any that had prevailed during deposition of these Plio-Pleistocene sediments. ?? 1988.

Relationships among charcoal particles from modern lacustrine sediments and remotely sensed fire events

NASA Astrophysics Data System (ADS)

López-Pérez, M.; Correa-Metrio, A.

2013-05-01

Analysis of charcoal particles from lacustrine sediments is a useful tool to understand fire regimes through time, and their relationships with climate and vegetation. However, the extent of the relationship between charcoal particles and their origin in terms of the spatial and temporal extent of the fire events is poorly known in the tropics. Modern sediments were collected from lakes in the Yucatan Peninsula and Central Mexico, 51 and 22 lakes respectively, to analyze their charcoal concentration and its relationships with modern fire events. Number of modern fire events was derived from the public source Fire Information for Resource Management System (FIRMS) for concentric spatial rings that ranged from 1 to 30 km of radius. The association between charcoal and fires was evaluated through the construction of linear models to explain charcoal concentration as a function of the number of fires recorded. Additionally, charcoal particles were stratified according to size to determine the association between fire distance and charcoal size classes. The relationship between total charcoal concentration and fire events was stronger for central Mexico than for the Yucatan Peninsula, which is probably the result of differences in vegetation cover. The highest determination coefficients were obtained for charcoal particle sizes ranging between 0.2 and 0.8 mm2, and for fire event distances of between 0 and 15 km from the lake. Overall, the analyses presented here offer useful tools to quantitatively and spatially reconstruct past regional fire dynamics in Central Mexico and the Yucatan Peninsula.

Improving age-depth models using sedimentary proxies for accumulation rates in fluvio-lacustrine deposits

NASA Astrophysics Data System (ADS)

Minderhoud, Philip S. J.; Cohen, Kim M.; Toonen, Willem. H. J.; Erkens, Gilles; Hoek, Wim Z.

2017-04-01

Lacustrine fills, including those of oxbow lakes in river floodplains, often hold valuable sedimentary and biological proxy records of palaeo-environmental change. Precise dating of accumulated sediments at levels throughout these records is crucial for interpretation and correlation of (proxy) data existing within the fills. Typically, dates are gathered from multiple sampled levels and their results are combined in age-depth models to estimate the ages of events identified between the datings. In this paper, a method of age-depth modelling is presented that varies the vertical accumulation rate of the lake fill based on continuous sedimentary data. In between Bayesian calibrated radiocarbon dates, this produces a modified non-linear age-depth relation based on sedimentology rather than linear or spline interpolation. The method is showcased on a core of an infilled palaeomeander at the floodplain edge of the river Rhine near Rheinberg (Germany). The sequence spans from 4.7 to 2.9 ka cal BP and consists of 5.5 meters of laminated lacustrine, organo-clastic mud, covered by 1 meter of peaty clay. Four radiocarbon dates provide direct dating control, mapping and dating in the wider surroundings provide additional control. The laminated, organo-clastic facies of the oxbow fill contains a record of nearby fluvial-geomorphological activity, including meander reconfiguration events and passage of rare large floods, recognized as fluctuations in coarseness and amount of allochthonous clastic sediment input. Continuous along-core sampling and measurement of loss-on-ignition (LOI) provided a fast way of expressing the variation in clastic sedimentation influx from the nearby river versus autochthonous organic deposition derived from biogenic production in the lake itself. This low-cost sedimentary proxy data feeds into the age-depth modelling. The sedimentology-modelled age-depth relation (re)produces the distinct lithological boundaries in the fill as marked changes in

Seismic Triggers of Lacustrine Subaqueous Landslides in Lake Champlain, USA

NASA Astrophysics Data System (ADS)

Manley, P.; Manley, T.; Ghosh, S. J.; Rosales-Underbrink, P.; Silverhart, P.

2017-12-01

Lacustrine slumps and debris flows (landslides) have been identified in Lake Champlain via Multibeam and CHIRP (compressed high intensity radar pulse) seismic profile data. Numerous large landslides studied by Ghosh (2012), Rosales-Underbrink (2015), and Silverhart (2016) have shown that many of these landslides are coeval. All landslides failed on a specific interface between marine Champlain Sea and modern lacustrine Lake Champlain sediments. Utilizing radionuclide dating on sediment from the unfailed slopes or undisturbed sediment above failed deposits, sedimentation rates were determined and used to calculate the approximate failure ages for each of the landslides studied. The northernmost failure, south of the Bouquet River, occurred about 950-1200 cal yr BP and is the first mass wasting event of this age to be recorded on Lake Champlain. The remaining landslides failed about 4500-5200 cal yr BP and agree with nearby Western Quebec Seismic Zone (WQSZ) with clusters of terrestrial landslides occurring at 1000 and 5000 cal yr BP triggered by large earthquakes (Brooks, 2015) along the same interface. The 5000 cal yr BP event has been attributed to a M 6.4 or greater earthquake within the WQSZ. The coeval landslides observed in Lake Champlain were likely triggered by this same earthquake. Lake tsunami models show that these simultaneous landslide failures can generate surface waves wave that can impact the Lake Champlain shoreline within 3-10 minutes after the earthquake.

Copper smelting and sediment pollution in Bronze Age China.

NASA Astrophysics Data System (ADS)

Zhang, S.; Dong, G.

2017-12-01

The emergence and diffusion of metallurgical technology had tremendous environmental consequence, however, the spatial-temporal consequences of the metallurgy during Bronze Age are not clear in China. Here, Xray fluorescence (XRF) measurement and principal component analysis (PCA) were conducted on heavy metal element (Cu, Ni, Pb, Zn, Cr and As) concentrations (HMEC) of natural and anthropogenic sediment samples systematically collected from 22 late Neolithic-Bronze Age sites in Hexi corridor to explore the potential for subcontinental-wide changes in soil geochemistry. We place this data within the context of the Cu concentrations in lacustrine sediments located near smelting and mining centers in Bronze Age China. Our results show that variation of HMEC in anthropogenic sediment in Hexi corridor is contemporaneous with the increases of the Cu concentrations in lacustrine sediment around 4000 BP. Comparative data suggests the metallurgical production diffused from the Hexi corridor to central and southwestern China around 3600 BP. We argue that sediment pollution is not an isolated phenomenon during the Bronze Age China, but rather occurred on regional scales and is closely related to the intensity of smelting activities.

Abundance and δ13C values of fatty acids in lacustrine surface sediments: Relationships with in-lake methane concentrations

NASA Astrophysics Data System (ADS)

Stötter, Tabea; Bastviken, David; Bodelier, Paul L. E.; van Hardenbroek, Maarten; Rinta, Päivi; Schilder, Jos; Schubert, Carsten J.; Heiri, Oliver

2018-07-01

Proxy-indicators in lake sediments provide the only approach by which the dynamics of in-lake methane cycling can be examined on multi-decadal to centennial time scales. This information is necessary to constrain how lacustrine methane production, oxidation and emissions are expected to respond to global change drivers. Several of the available proxies for reconstructing methane cycle changes of lakes rely on interpreting past changes in the abundance or relevance of methane oxidizing bacteria (MOB), either directly (e.g. via analysis of bacterial lipids) or indirectly (e.g. via reconstructions of the past relevance of MOB in invertebrate diet). However, only limited information is available about the extent to which, at the ecosystem scale, variations in abundance and availability of MOB reflect past changes in in-lake methane concentrations. We present a study examining the abundances of fatty acids (FAs), particularly of 13C-depleted FAs known to be produced by MOB, relative to methane concentrations in 29 small European lakes. 39 surface sediment samples were obtained from these lakes and FA abundances were compared with methane concentrations measured at the lake surface, 10 cm above the sediments and 10 cm within the sediments. Three of the FAs in the surface sediment samples, C16:1ω7c, C16:1ω5c/t, and C18:1ω7c were characterized by lower δ13C values than the remaining FAs. We show that abundances of these FAs, relative to other short-chain FAs produced in lake ecosystems, are related with sedimentary MOB concentrations assessed by quantitative polymerase chain reaction (qPCR). We observed positive relationships between methane concentrations and relative abundances of C16:1ω7c, C16:1ω5c/t, and C18:1ω7c and the sum of these FAs. For the full dataset these relationships were relatively weak (Spearman's rank correlation (rs) of 0.34-0.43) and not significant if corrected for multiple testing. However, noticeably stronger and statistically significant

Holocene environmental changes in northern Lebanon as inferred from a multiproxy study on lacustrine-palustrine sediment

NASA Astrophysics Data System (ADS)

Vidal, Laurence; Jenna, Hage-Hassen; Demory, François; Develle, Anne-Lise; van Campo, Elise; Elias, Ata

2016-04-01

The reconstruction of the Levantine post-glacial environmental evolution is essential to understand the interactions between variability of regional water cycle, dynamics of the global climate, and cultural evolution. We present a paleolacustrine record from the karstic Yammouneh basin (34.06N-34.09N; 36.0E-36.03E, 1360 m a.s.l.), located on the eastern flank of Mount Lebanon (northern Levant). Holocene sediments (retrieved from gully and a trenbch) (1.5 to 3.6 m thick) consist of pale lacustrine chalk interrupted by an ash layer and remarkable centimetric beds of ocher to dark brown silty clays used, in addition to 14C ages, as stratigraphical markers. Lacustrine biogenic remains are diversified and abundant (ostracods, gastropods, charophytes, chlorophyceae, plant debris…) all reflecting a freswater, generally shallow waterbody. We analysed the sediment mineralogy and geochemistry, TOM contents, magnetic properties, pollen and calcite oxygen isotope composition derived from ostracod shells. These sequences are compared to former data from 2 trenches and 1 core collected in different points of the basin (Daeron et al., 2007; Develle et al., 2009, 2010). A total of 42 AMS 14C dating (partly carbonized wood) provide a solid chronology from the YD to present. Results reveal the following main features : 1- intervals dominated by authigenic calcite suggest that the major water supply was the karstic springs, which still deliver Ca-rich water and low surface runoff; 2- the lake oxygen isotope composition has been impacted by the source isotope composition throughout the Holocene and by increased inland rainfall during the early Holocene; 3- a decideous oak forest, implying much more soil water availability than today, was developed around the lake from ca. 11.5 to 9.5 kyr (the very bad pollen preservation after 8.3 kyr reflects oxidation or frequent oscillations of the water level); 4- four paleosols evidenced from lithofacies and magnetic properties are identified

Dating lacustrine episodes in the eastern Sahara by the epimerization of isoleucine in ostrich eggshells

USGS Publications Warehouse

Miller, G.H.; Wendorf, F.; Ernst, R.; Schild, R.; Close, A.E.; Friedman, I.; Schwarcz, H.P.

1991-01-01

The eggshell of the African ostrich, Struthio camelus, closely approximates a closed system for the retention of indigenous proteinaceous residues. Epimerization of the protein amino acid isoleucine follows linear first-order kinetics in laboratory simulations nearly to racemic equilibrium, and the variation in D/L ratio within a single fragment, or between fragments of the same age, is significantly less than in other carbonate systems. These observations suggest that the extent of isoleucine epimerization (aIle/Ile ratio) in ostrich eggshell offers the potential for high-resolution geochronology of Quaternary deposits. From the simulation experiments, and dated early Holocene samples for which we have in situ mean annual sediment temperature measurements, Arrhenius parameters have been calculated; the activation energy is 30.33 kcal mol-1, similar to that of other carbonate systems. We have measured the aIle/Ile ratio in ostrich eggshell associated with lacustrine episodes at Bir Tarfawi and Bir Sahara East, two depressions in what is currently the hyperarid eastern Sahara. The ratios can be used directly to indicate qualitatively the time represented by each series of lake sediment, and to correlate disjunct lacustrine deposits within and between the basins. Uranium-series disequilibrium dating of algal mats contained within some of the lake beds indicate that a major wet interval occurred about 130 ka ago. Using the U-series date for calibration, the amino acid ratios are used to date the most recent lacustrine interval to about 100 ka B.P., and two older intervals, one about 200 ?? 25 ka B.P., and an older interval that occurred prior to 250 ka ago. ?? 1991.

Alluvial to lacustrine sedimentation in an endorheic basin during the Mio-Pliocene: The Toro Negro Formation, Central Andes of Argentina

NASA Astrophysics Data System (ADS)

Ciccioli, Patricia L.; Marenssi, Sergio A.; Amidon, William H.; Limarino, Carlos O.; Kylander-Clark, Andrew

2018-07-01

A 2400 m-thick sedimentary column belonging to the Toro Negro Formation was recorded along the Quebrada del Yeso, Sierra de Los Colorados (Vinchina Basin), La Rioja province, NW Argentina. The Vinchina basin is a good example of a closed basin surrounded by the Precordillera fold and thrust belt to the west and basement-cored blocks to the north, south (Western Sierras Pampeanas) and east (Sierra de Famatina). Seven facies associations (FA) are described and interpreted to represent fluvial, lacustrine and alluvial environments developed in the southern part of the Vinchina basin from the Late Miocene until the earliest Pleistocene. The depositional evolution of the formation was divided in four phases. Phase I (∼7-6.6 Ma) represents sedimentation in medial (FA I) to distal (FA II) parts of a southward directed distributive fluvial system with a retrogradational pattern. During phase II (6.6-6.1Ma), the distributive fluvial system was replaced by a mixed clastic-evaporitic shallow lake (FA III) in a high aggradational basin. In phase III (∼6.1-5 Ma) the eastward progradation of a fluvial system (FA IV) was recorded as a distal clastic wedge. Finally, phase IV (∼5-2.4Ma) records two depositional cycles of proximal clastic wedge progradation of fluvial-dominated piedmonts (FAV, FAVII) from the southwest (Sierra de Umango) and/or the west (Precordillera) with an intervening playa lake (FA VI). Two new U-Pb ages obtained from zircons in volcanic ash layers confirm the Late Miocene age of the lower member of the Toro Negro Formation and permit a tight correlation with the central part of the basin (Quebrada de La Troya section). The sedimentation rate calculated for the dated lacustrine-fluvial interval is higher than the corresponding one in La Troya area suggesting a higher subsidence in the southern part of the basin. During the Late Miocene (∼7-6.6Ma) the ephemeral drainage was controlled by an arid to semiarid climate and initially dissipated mostly

Nanometer-Scale Pore Characteristics of Lacustrine Shale, Songliao Basin, NE China

PubMed Central

Wang, Min; Yang, Jinxiu; Wang, Zhiwei; Lu, Shuangfang

2015-01-01

In shale, liquid hydrocarbons are accumulated mainly in nanometer-scale pores or fractures, so the pore types and PSDs (pore size distributions) play a major role in the shale oil occurrence (free or absorbed state), amount of oil, and flow features. The pore types and PSDs of marine shale have been well studied; however, research on lacustrine shale is rare, especially for shale in the oil generation window, although lacustrine shale is deposited widely around the world. To investigate the relationship between nanometer-scale pores and oil occurrence in the lacustrine shale, 10 lacustrine shale core samples from Songliao Basin, NE China were analyzed. Analyses of these samples included geochemical measurements, SEM (scanning electron microscope) observations, low pressure CO2 and N2 adsorption, and high-pressure mercury injection experiments. Analysis results indicate that: (1) Pore types in the lacustrine shale include inter-matrix pores, intergranular pores, organic matter pores, and dissolution pores, and these pores are dominated by mesopores and micropores; (2) There is no apparent correlation between pore volumes and clay content, however, a weak negative correlation is present between total pore volume and carbonate content; (3) Pores in lacustrine shale are well developed when the organic matter maturity (Ro) is >1.0% and the pore volume is positively correlated with the TOC (total organic carbon) content. The statistical results suggest that oil in lacustrine shale mainly occurs in pores with diameters larger than 40 nm. However, more research is needed to determine whether this minimum pore diameter for oil occurrence in lacustrine shale is widely applicable. PMID:26285123

Nanometer-Scale Pore Characteristics of Lacustrine Shale, Songliao Basin, NE China.

PubMed

Wang, Min; Yang, Jinxiu; Wang, Zhiwei; Lu, Shuangfang

2015-01-01

In shale, liquid hydrocarbons are accumulated mainly in nanometer-scale pores or fractures, so the pore types and PSDs (pore size distributions) play a major role in the shale oil occurrence (free or absorbed state), amount of oil, and flow features. The pore types and PSDs of marine shale have been well studied; however, research on lacustrine shale is rare, especially for shale in the oil generation window, although lacustrine shale is deposited widely around the world. To investigate the relationship between nanometer-scale pores and oil occurrence in the lacustrine shale, 10 lacustrine shale core samples from Songliao Basin, NE China were analyzed. Analyses of these samples included geochemical measurements, SEM (scanning electron microscope) observations, low pressure CO2 and N2 adsorption, and high-pressure mercury injection experiments. Analysis results indicate that: (1) Pore types in the lacustrine shale include inter-matrix pores, intergranular pores, organic matter pores, and dissolution pores, and these pores are dominated by mesopores and micropores; (2) There is no apparent correlation between pore volumes and clay content, however, a weak negative correlation is present between total pore volume and carbonate content; (3) Pores in lacustrine shale are well developed when the organic matter maturity (Ro) is >1.0% and the pore volume is positively correlated with the TOC (total organic carbon) content. The statistical results suggest that oil in lacustrine shale mainly occurs in pores with diameters larger than 40 nm. However, more research is needed to determine whether this minimum pore diameter for oil occurrence in lacustrine shale is widely applicable.

Volcanic influence of Mt. Fuji on the watershed of Lake Motosu and its impact on the lacustrine sedimentary record

NASA Astrophysics Data System (ADS)

Lamair, Laura; Hubert-Ferrari, Aurélia; Yamamoto, Shinya; El Ouahabi, Meriam; Vander Auwera, Jacqueline; Obrochta, Stephen; Boes, Evelien; Nakamura, Atsunori; Fujiwara, Osamu; Shishikura, Masanobu; Schmidt, Sabine; Siani, Giuseppe; Miyairi, Yosuke; Yokoyama, Yusuke; De Batist, Marc; Heyvaert, Vanessa M. A.; QuakeRecNankai Team

2018-01-01

Lacustrine sediments are particularly sensitive to modifications within the lake catchment. In a volcanic area, sedimentation rates are directly affected by the history of the volcano and its eruptions. Here, we investigate the impact of Mt. Fuji Volcano (Japan) on Lake Motosu and its watershed. The lacustrine infill is studied by combining seismic reflection profiles and sediment cores. We show evidence of changes in sedimentation patterns during the depositional history of Lake Motosu. The frequency of large mass-transport deposits recorded within the lake decreases over the Holocene. Before 8000 cal yr BP, large sublacustrine landslides and turbidites were filling the lacustrine depression. After 8000 cal yr BP, only one large sublacustrine landslide was recorded. The change in sedimentation pattern coincides with a change in sediment accumulation rate. Over the last 8000 cal yr BP, the sediment accumulation rate was not sufficient enough to produce large sublacustrine slope failures. Consequently, the frequency of large mass-transport deposits decreased and only turbidites resulting from surficial slope reworking occurred. These constitute the main sedimentary infill of the deep basin. We link the change in sediment accumulation rate with (i) climate and vegetation changes; and (ii) the Mt. Fuji eruptions which affected the Lake Motosu watershed by reducing its size and strongly modified its topography. Moreover, this study highlights that the deposition of turbidites in the deep basin of Lake Motosu is mainly controlled by the paleobathymetry of the lakefloor. Two large mass-transport deposits, occurring around 8000 cal yr BP and 2000 cal yr BP respectively, modified the paleobathymetry of the lakefloor and therefore changed the turbidite depositional pattern of Lake Motosu.

Late Holocene monsoon climate as evidenced by proxy records from a lacustrine sediment sequence in western Guangdong, South China

NASA Astrophysics Data System (ADS)

Zhong, Wei; Cao, jiayuan; Xue, Jibin; Ouyang, Jun; Tang, Xiaohong; Yin, Huanling; Liao, Congyun; Long, Kun

2014-02-01

The study of a 300-cm-thick exposed lacustrine sediment section in the Hedong village in Zhaoqing area which is located in sub-tropical west Guangdong Province in South China, demonstrates that the lacustrine sedimentary sequence possibly contains evidence for exploring variation of Asian monsoon climate. Multi-proxy records, including the humification intensity, total organic carbon, and grain size fractions, reveal a general trend towards dry and cold conditions in the late Holocene that this is because of a decrease in solar insolation on an orbital scale. Three intensified Asian summer monsoon (ASM) intervals (˜3300-3000 cal yr BP, ˜2600-1600 cal yr BP, and ˜900-600 cal yr BP), and three weakened ASM intervals (˜4000-3300 cal yr BP, ˜3000-2600 cal yr BP, and ˜1600-900 cal yr BP) are identified. Our humification record (HDcal) shows a good correlation on multi-centennial scale with the tree ring Δ14C record, a proxy of solar activity. A spectral analysis of HDcal reveals four significant cycles, i.e., ˜1250 yr, 300 yr, 110 yr, and 70 yr, and most of these cycles are related to the solar activity. Our findings indicate that solar output and oceanic-atmospheric circulation probably have influenced the late Holocene climate variability in the study region.

Lacustrine-fluvial interactions in Australia's Riverine Plains

NASA Astrophysics Data System (ADS)

Kemp, Justine; Pietsch, Timothy; Gontz, Allen; Olley, Jon

2017-06-01

Climatic forcing of fluvial systems has been a pre-occupation of geomorphological studies in Australia since the 1940s. In the Riverine Plain, southeastern Australia, the stable tectonic setting and absence of glaciation have combined to produce sediment loads that are amongst the lowest in the world. Surficial sediments and landforms exceed 140,000 yr in age, and geomorphological change recorded in the fluvial, fluvio-lacustrine and aeolian features have provided a well-studied record of Quaternary environmental change over the last glacial cycle. The region includes the Willandra Lakes, whose distinctive lunette lakes preserve a history of water-level variations and ecological change that is the cornerstone of Australian Quaternary chronostratigraphy. The lunette sediments also contain an ancient record of human occupation that includes the earliest human fossils yet found on the Australian continent. To date, the lake-level and palaeochannel records in the Lachlan-Willandra system have not been fully integrated, making it difficult to establish the regional significance of hydrological change. Here, we compare the Willandra Lakes environmental record with the morphology and location of fluvial systems in the lower Lachlan. An ancient channel belt of the Lachlan, Willandra Creek, acted as the main feeder channel to Willandra Lakes before channel avulsion caused the lakes to dry out in the late Pleistocene. Electromagnetic surveys, geomorphological and sedimentary evidence are used to reconstruct the evolution of the first new channel belt following the avulsion. Single grain optical dating of floodplain sediments indicates that sedimentation in the new Middle Billabong Palaeochannel had commenced before 18.4 ± 1.1 ka. A second avulsion shifted its upper reaches to the location of the present Lachlan River by 16.2 ± 0.9 ka. The timing of these events is consistent with palaeohydrological records reconstructed from Willandra Lakes and with the record of

Holocene environmental changes in northern Lebanon as inferred from a multiproxy study on lacustrine-palustrine sediment

NASA Astrophysics Data System (ADS)

Vidal, L.; Hage-Hassan, J.; Gasse, F. A.; Demory, F.; van Campo, E.; Develle, A.; Elias, A.

2013-12-01

The reconstruction of the Levantine post-glacial environmental evolution is essential to understand the interactions between variability of regional water cycle, dynamics of the global climate, and cultural evolution. Here, we present an Holocene record from the karstic Yammouneh basin (34.06N-34.09N; 36.0E-36.03E, 1360 m a.s.l.), located on the eastern flank of Mount Lebanon (northern Levant). Two new sedimentary profiles (from 1 gully and 1 trench) complement former data from 2 trenches and 1 core collected in different points of the basin (Daeron et al., 2007; Develle et al., 2009, 2010). A total of 42 AMS 14C dating (partly carbonized wood) provide a solid chronology from the YD to present. Holocene sediments (1.5 to 3.6 m thick) consist of pale lacustrine chalk interrupted by an ash layer and remarkable centimetric beds of ocher to dark brown silty clays used, in addition to 14C ages, as stratigraphical markers. Lacustrine biogenic remains are diversified and abundant (ostracods, gastropods, charophytes, chlorophyceae, plant debris...) all reflecting a freswater, generally shallow waterbody. We analysed the sediment mineralogy, TOM contents, magnetic properties (magnetic susceptibility and its frequency dependence), pollen and calcite oxygen isotope composition derived from ostracod shells. Results reveal the following main features : 1- intervals dominated by authigenic calcite suggest that the major water supply was the karstic springs, which still deliver Ca-rich water and low surface runoff; 2- the lake oxygen isotope composition has been impacted by the source isotope composition throughout the Holocene and by increased inland rainfall during the early Holocene; 3- a decideous oak forest, implying much more soil water availability than today, was developed around the lake from ca. 11.5 to 9.5 kyr (the very bad pollen preservation after 8.3 kyr reflects oxidation or frequent oscillations of the water level); 4- four paleosols evidenced from lithofacies and

Using Seismic Reflection Analysis of Lacustrine Sediment Stratigraphy to Reconstruct 40,000 Years of Northern Hemisphere Andean Hydroclimate

NASA Astrophysics Data System (ADS)

Gibson, D. K.; Bird, B. W.; Wattrus, N. J.; Escobar, J.; Fonseca, H.; Velasco, F.; Polissar, P. J.

2017-12-01

Geophysical analysis of lacustrine seismic stratigraphy at Laguna de Tota (hereafter "Tota"), Boyaca, Colombia, provides a record of lake level fluctuations that ranges from the Late Quaternary to the present. Changes in Tota's volume indicated by off-lap and on-lap sequences show that regional hydroclimate varied considerably during at least the last 40 Ka. Modern lake level variability at Tota has been directly linked to the El Niño-Southern Oscillation (ENSO) and Pacific Decadal Oscillation (PDO), suggesting that past lake level changes identified in CHIRP seismic data may provide insight into past Pacific atmosphere-ocean dynamics. Here, we use high-resolution CHIRP data spanning the top 15 meters of sediment column and a preliminary age model based on Holocene sedimentation rates to investigate lake level variability over the past 40 Ka. Our data demonstrates that lake levels at Tota were generally lower between 40 and 30 Ka, experienced rapid and extreme fluctuations between 30 and 20 Ka (including the lowest recorded lake level at Tota during the LGM at 22 Ka), and gradually rose to the present day high stand between 20 and 0 Ka. Although the CHIRP data indicate significant late Quaternary lake level fluctuations, the timing and duration of these events needs to be more firmly constrained with additional investigations combining sediment core collection and analysis, geochronology, and other lake level proxies. Future work combining these methods holds tremendous potential in terms of reconstructing Late Quaternary atmosphere-ocean cycles.

Using a network of core samples to explore hydroclimatic proxy relationships within the sediments of an alpine, glacier-fed lake

NASA Astrophysics Data System (ADS)

Hodder, Kyle; Suchan, Jared

2015-04-01

Spatial and temporal variability of recent lacustrine sedimentation rates are examined for glacier-fed Mud Lake, in the Monashee Mountains of British Columbia. Clastic varve sequences in alpine, glacier-fed environments have been linked elsewhere with temperature (summer, annual), precipitation (autumn, total snowpack), and runoff (glacial, floods), and the use of varved sediments as hydroclimatic proxies is well-developed from single, but rarely multiple, core samples. In this study, a network of sediment cores (n=63) were extracted using a dense grid-sampling scheme within the 2.5 km2 distal lake basin to assess varve thickness spatially, and through time. A radioisotope profile, sediment traps and repeated coring among multiple years were used to calibrate varve-years with calendar years. Measurements of varve thickness, and sub-annual laminae thickness, were collated among cores and spanned the period 1919 - 2013 AD. The resulting five-dimensional dataset (easting, northing, depth, varve/sub-laminae thickness, time) provides a unique opportunity to explore lacustrine sedimentation. Two clear trends emerge: a general down-lake trend in thickness among most years, which is punctuated by atypical years in which thicker varves appeared in only specific portions of the lake. In the latter case, thick varves appeared either (a) along the north (right-hand) side of the lake where inflow 'hugs' the shoreline, or (b) in the deepest, distal portion of the basin. In both cases, however, atypical varves of type (a) or (b) only punctuate the general down-lake trend in thickness that develops during most years. The clear implication is that sedimentation patterns, and rates, can (but do not always) differ between years and between points in Mud Lake: there is no 'single optimum' site for a core sample. To illustrate the potential consequences on hydroclimate proxy/inference, we show how the statistical relationships between hydroclimatic records and varve thickness vary

Mineralogy of Mudstone at Gale Crater, Mars: Evidence for Dynamic Lacustrine Environments

NASA Technical Reports Server (NTRS)

Rampe, E. B.; Ming, D. W.; Grotzinger, J. P.; Morris, R. V.; Blake, D. F.; Vaniman, D. T.; Bristow, T. F.; Yen, A. S.; Chipera, S. J.; Morrison, S. M.;

Stratigraphy, sedimentology, and volume of sediments behind a dam relic on the Muskegon River, Big Rapids, Michigan

USGS Publications Warehouse

Westjohn, David B.

1997-01-01

The proposed removal of the remnants of a hydroelectric dam in the Muskegon River at Big Rapids, Michigan, will potentially affect flow of the river at the city's water intake system. Fifteen boreholes were augered in bottom sediments in the river just upstream from the dam relic, and streambottom profiles were made using ground-penetrating radar. Data from boreholes show that sediments captured by the dam foundation were deposited in two distinctly different sedimentary environments. Sediments that overlie the pre-dam channel surface consist of lacustrine clay, wood chips, silt, and sand. These lacustrine sediments are interbedded in a cyclical fashion, and they were deposited under low flow to stagnant water conditions during 1916-66, when a 17-foot-tall hydroelectric dam was in place. Demolition of the upper 13 feet of this dam in 1966 resulted in erosion of most of the lacustrine sediments, and subsequent deposition of coarser alluvium in the impoundment behind the remaining dam foundation. Lacustrine sediments are present in the active part of the stream channel and extend from the dam foundation to about 1,300 feet upstream. The composite thickness of lacustrine sediments and overlying coarser alluvium was determined from sediment cores collected from the boreholes. The volume of these sediments is estimated to be about 19,000 cubic yards.

Deposition and deformation of fluvial-lacustrine sediments of the Upper Triassic-Lower Jurassic Whitmore Point Member, Moenave Formation, northern Arizona

NASA Astrophysics Data System (ADS)

Tanner, Lawrence H.; Lucas, Spencer G.

2010-01-01

The stratigraphic section of the Upper Triassic-Lower Jurassic Whitmore Point Member of the Moenave Formation at Potter Canyon, Arizona, comprises c. 26 m of gray to black shales and red mudstones interbedded with mainly sheet-like siltstones and sandstones. These strata represent deposition from suspension and sheetflow processes in shallow, perennial meromictic to ephemeral lakes, and on dry mudflats of the terminal floodout of the northward-flowing Moenave stream system. The lakes were small, as indicated by the lack of shoreline features and limited evidence for deltas. Changes in base level, likely forced by climate change, drove the variations between mudflat and perennial lacustrine conditions. Lenticular sandstones that occur across the outcrop face in the same stratigraphic interval in the lower part of the sequence represent the bedload fill of channels incised into a coarsening-upward lacustrine sequence following a fall in base level. These sandstones are distinctive for the common presence of over-steepened bedding, dewatering structures, and less commonly, folding. Deformation of these sandstones is interpreted as aseismic due to the lack of features typically associated with seismicity, such as fault-graded bedding, diapirs, brecciated fabrics and clastic dikes. Rapid deposition of the sands on a fluid-rich substrate produced a reverse density gradient that destabilized, and potentially fluidized the underlying, finer-grained sediments. This destabilization allowed synsedimentary subsidence of most of the channel sands, accompanied by longitudinal rotation and/or ductile deformation of the sand bodies.

Compositional classification and sedimentological interpretation of the laminated lacustrine sediments at Baumkrichen (Western Austria) using XRF core scanning data

NASA Astrophysics Data System (ADS)

Barrett, Samuel; Tjallingii, Rik; Bloemsma, Menno; Brauer, Achim; Starnberger, Reinhard; Spötl, Christoph; Dulski, Peter

2015-04-01

The outcrop at Baumkirchen (Austria) encloses part of a unique sequence of laminated lacustrine sediments deposited during the last glacial cycle. A ~250m long composite sediment record recovered at this location now continuously covers the periods ~33 to ~45 ka BP (MIS 3) and ~59 to ~73 ka BP (MIS 4), which are separated by a hiatus. The well-laminated (mm-cm scale) and almost entirely clastic sediments reveal alternations of clayey silt and medium silt to very-fine sand layers. Although radiocarbon and optically stimulated luminescence (OSL) dating provide a robust chronology, accurate dating of the sediment laminations appears to be problematic due to very high sedimentation rates (3-8 cm/yr). X-ray fluorescence (XRF) core scanning provided a detailed ~150m long record of compositional changes of the sediments at Baumkirchen. Changes in the sediments are subtle and classification into different facies based on individual elements is therefore subjective. We applied a statistically robust clustering analysis to provide an objective compositional classification without prior knowledge, based on XRF measurements for 15 analysed elements (all those with an acceptable signal-noise ratio: Zr, Sr, Ca, Mn, Cu, Zn, Rb, Ni, Fe, K, Cr, V, Si, Ba, T). The clustering analysis indicates a distinct compositional change between sediments deposited below and above the stratigraphic hiatus, but also differentiates between individual different laminae. Preliminary results suggest variations in the sequence are largely controlled by the relative occurrence of different kinds of sediment represented by different clusters. Three clusters identify well-laminated sediments, visually similar in appearance, each dominated by an anti-correlation between Ca and one or more of the detrital elements K, Zr, Ti, Si and Fe. Two of these clusters occur throughout the entire sequence, one frequently and the other restricted to short sections, while the third occurs almost exclusively below the

The occurrence and transformation of lacustrine sediment gravity flow related to depositional variation and paleoclimate in the Lower Cretaceous Prosopis Formation of the Bongor Basin, Chad

NASA Astrophysics Data System (ADS)

Tan, Mingxuan; Zhu, Xiaomin; Geng, Mingyang; Zhu, Shifa; Liu, Wei

2017-10-01

Bed variability of sediment-gravity-flow deposits is quite prevalent in deep-marine settings, but it has not been well investigated in lacustrine settings. The depositional characteristics of various event beds are characterized in the North Slope Belt of the Bongor Basin (Chad), using detailed sedimentological, petrographic, geochemical as well as palynological analysis. Four bed types including classical turbidite bed, debrite bed, hybrid event bed, and hyperpycnite bed were distinguished based on their interpreted depositional processes. Variable mud contents of debrite beds and classic turbidite beds show distinct genetic characteristics in four core wells, whilst the high mud content of cohesive debrite interval and the low mud content of turbidite interval in hybrid event bed demonstrate the existence of flow transformation. Generally, several trace element and rare earth element proxy parameters show that these gravity-flow deposits of BS1-1 and D-3 cores are formed in more distal depositional settings than them of BN8 and BNE3 cores, which is also well consistent with sedimentological understandings achieved by seismic facies analysis. Although palynological results show a general hot arid climate during the deposition of the Prosopis Formation, but the climate-sensitive Sr/Cu ratio demonstrates that most sampled turbidite beds are postulated to be formed within a short humid pulse. The multi-approach analysis has illustrated that two potential forming mechanisms (delta-front-failure and flood-related origin) can be derived in different cored wells of such a small lacustrine rift basin. Differentiated flow transformation plays a significant role in the depositional characteristics and heterogenetic distribution of these event deposits.

Analysis of soft-sediment deformation structures in Neogene fluvio-lacustrine deposits of Çaybağı Formation, Eastern Turkey

NASA Astrophysics Data System (ADS)

Koç Taşgin, Calibe; Türkmen, İbrahim

2009-06-01

During the Neogene, both strike-slip and extensional regimes coexisted in eastern Turkey and, a number of fault-bounded basins associated with the East Anatolian Fault System developed. The Çaybağı Formation (Late Miocene-Early Pliocene) deposited in one of these basins consists of fluvio-lacustrine deposits. Numerous soft-sediment deformation structures are encountered in this formation, particularly in conglomerates, medium- to coarse-grained tuffaceous sandstones and claystones: folded structures (slumps, convolute laminations, and simple recumbent folds), water-escape structures (intruded sands, internal cusps, interpenetrative cusps and sand volcanoes), and load structures (load casts, pseudonodules, flame structures, and pillow structures). These structures are produced by liquefaction and/or fluidization of the unconsolidated sediments during a seismic shock. Consequently, the existence of seismically-induced deformation structures in the Çaybağı Formation and the association with a Neogene intraformational unconformity, growth faults, and reverse faults in the Çaybağı basin attest to the tectonic activity in this area during the Late Miocene and Early Pliocene. The East Anatolian Fault System, in particular the Uluova fault zone, is the most probable seismogenic source. Earthquakes with a magnitude of over 5 in the Richter scale can be postulated.

Process interpretation of laminated lacustrine sediments from the valley of the river Alf, Quaternary West Eifel Volcanic Field, Germany

NASA Astrophysics Data System (ADS)

Eichhorn, Luise; Pirrung, Michael; Zolitschka, Bernd; Büchel, Georg

2016-04-01

(1): 83-88. Pirrung, M., et al. (2007). Hochauflösende fluviolakustrine Sedimente des jüngeren Pleistozän aus dem Alfbachtal bei Gillenfeld (Westeifel) - erste Ergebnisse. Mainzer geowissenschaftliche Mitteilungen 35: 51-80. Zolitschka, B. (1991). Absolute dating of late-Quaternary lacustrine sediments by high resolution varve chronology. Hydrobiologia 214: 59-61.

Sedimentation rates in eastern North America reveal strong links between regional climate, depositional environments, and sediment accumulation

NASA Astrophysics Data System (ADS)

Goring, S. J.; McLachlan, J. S.; Jackson, S. T.; Blaauw, M.; Christen, J.; Marlon, J.; Blois, J.; Williams, J. W.

2011-12-01

PalEON is a multidisciplinary project that combines paleo and modern ecological data with state-of-the-art statistical and modelling tools to examine the interactions between climate, fire and vegetation during the past two millennia in the northeastern United States. A fundamental challenge for PalEON (and paleo research more broadly) is to improve age modelling to yield more accurate sediment-core chronologies. To address this challenge, we assessed sedimentation rates and their controls for 218 lakes and mires in the northeastern U.S. Sedimentation rates (yr/cm) were calculated from age-depth models, which were obtained from the Neotoma database (www.neotomadb.org) and other contributed pollen records. The age models were recalibrated to IntCal09 and augmented in some cases using biostratigraphic markers (Picea decline, 16 kcal BP - 10.5 kcal BP; Quercus rise, 12 - 9.1 kcal BP; and Alnus decline, 11.5 - 10.6 kcal BP) as described in Blois et al. (2011). Relationships between sedimentation rates and sediment age, site longitude, and depositional environment (lacustrine or mire) are significant but weak. There are clear and significant links between variations in the NGRIP record of δ18O and sedimentation in mires across the PalEON region, but no links to lacustrine sedimentation rates. This result indicates that super-regional climatic control of primary productivity, and thus autochthonic sediment deposition, dominates in mires while deposition in lacustrine basins may be driven primarily by local and regional factors including watershed size, surficial materials,and regional vegetation. The shape of the gamma probability functions that best describe sedimentation rate distributions are calculated and presented here for use as priors in Bayesian age modelling applications such as BACON (Blaauw and Christen, in press). Future applications of this research are also discussed.

Lacustrine Records of Holocene Mountain Glacier Fluctuations from Western Greenland

NASA Astrophysics Data System (ADS)

Schweinsberg, A.; Briner, J. P.; Bennike, O.

2014-12-01

Recent studies have focused on documenting fluctuations of the Greenland Ice Sheet margin throughout the Holocene but few data exist that constrain past changes of local glaciers independent of the ice sheet. Our research combines proglacial lake sediment analysis with cosmogenic 10Be dating of Holocene moraines and radiocarbon dating of ice-cap-killed vegetation with an overall objective to use this multi-proxy approach to generate a detailed record of the coupled climate-glacier system through the Holocene. Here, we present lacustrine records of mountain glacier variability from continuous pro-glacial lake sediment sequences recovered from two glaciated catchments in northeastern Nuussuaq, western Greenland. We use radiocarbon-dated sediments from Sikuiui and Pauiaivik lakes to reconstruct the timing of advance and retreat of local glaciers. Sediments were characterized with magnetic susceptibility (MS), gamma density, Itrax XRF and visible reflectance spectroscopy at 0.2 cm intervals and sediment organic matter at 0.5 cm intervals. Basal radiocarbon ages provide minimum-age constraints on deglaciation from Sikuiui and Pauiaivik lakes of ~9.6 and 8.7 ka, respectively. Organic-rich gyttja from deglaciation until ~5.0 ka in Pauiaivik Lake suggests minimal glacial extent there while slightly elevated MS values from ~9.0 - 7.0 ka in Sikuiui Lake may reflect early Holocene glacial advances. Minerogenic sediment input gradually increases starting at ~5.0 ka in Pauiaivik Lake, which we interpret as the onset of Neoglaciation in the catchment. Furthermore, a distinct episode of enhanced glacial activity from ~4.0 - 2.2 ka in Sikuiui Lake may be correlative to a period of persistent snowline lowering evidenced by radiocarbon dates of ice-killed vegetation from nearby ice cap margins. Results from these lacustrine records and our ice-killed vegetation dataset suggest a middle Holocene onset of Neoglaciation ~5.0 - 4.0 ka in this region. We are supplementing these records

The effect of tectonic evolution on lacustrine syn-rift sediment patters in Qikou Sag, Bohaiwan Basin, eastern China

NASA Astrophysics Data System (ADS)

Liao, Y.; Wang, H.; Xu, W.

2013-12-01

Normal fault arrays and associated relay ramps between two overlapping en-echelon normal faults are well known to control the deposition and distribution of sediments in alluvial, fluvial and deltaic systems in rift settings. The influence of transfer zones or relay ramps on sediment routes and dispersal patterns in subaqueous (deeper marine/lacustrine), however, is barely studied and hence less clear. Previous experimental studies indicate that subaqueous relay ramps may act as sediment transportation pathways if certain conditions are available. In this study, we integrate detailed structural and stratigraphic analysis with three-dimensional seismic data and limited well log data from the Qikou Sag to examine the tectonic evolution and the syn-rift sediment patterns response to fault growth and linkage in an active rift setting. Qikou Sag is located at the center of Huanghua Depression, Bohaiwan Basin of eastern China. Structurally, it is a typical continental rift basin characterized by a linked system of two NEE-SWW-striking half-grabens and one E-W-striking graben. Qikou sag is filled with Eocene-Oligocene syn-rift sediments and Miocene to Quaternary post-rift sediments. The Eocene-Oligocene rifting stage can be divided into early rifting period (43-36.5 Ma, the third member and second member of Shahejie Formation, Es3 and Es2), stable rifting period (36.5-29Ma, the first member of Shaehejie Formation, Es1) and fault-depressed diversionary period (29-24.6Ma, the Dongying Formation, Ed). This study focus on the early syn-rift, the third and second member of Shehejie Formation, which is mostly dark-grey mudstone interbedded with fine to coarse-grained sandstone deposited by large-scale turbidity currents in deep-lake. In particular, we use a combination of thickness variability and facies distributions, onlap patterns within a high-resolution sequence stratigraphic framework, integrated with structural geometry, fault activity and subsidence history analysis to

Molecular biomarkers for sources of organic matter in lacustrine sediments in a subtropical lake in China.

PubMed

Wang, Yan-Hua; Yang, Hao; Chen, Xia; Zhang, Ji-Xiang; Ou, Jie; Xie, Biao; Huang, Chang-Chun

2013-05-01

N-alkanes distributions and stable isotopic compositions (δ(13)C and δ(15)N) in the lacustrine sediments of Shijiu lake were measured to assess whether biological source information was recorded in the molecular biomarker. Results showed regular unimodal n-alkanes distribution in range of C16-C33 with strong predominance of odd-numbered n-alkanes, maximizing at C29. The δ(15)N for SON were uniformly low, ranging from -6.7‰ to 3.8‰ and C/N ratios ranged from 6.6 to 10.0, suggesting that most of organic matter was influenced by terrestrial characteristics of the watershed. The δ(13)C for C27 to C31n-alkanes and for SOC varied from -32.9‰ to -26.6‰ and -23.4‰ to -21.6‰, respectively, falling within the range of corresponding n-alkanes in leaves mainly from C3 land plants. The values of C/N, CPI, OEP, ACL and C27/C31 exhibit similar temporal changes with the primary production, showing enhanced eutrophication resulted from increased anthropogenic activities in Shijiu lake from 1852 to 2010. Copyright © 2013 Elsevier Ltd. All rights reserved.

Small-scale lacustrine drifts in Lake Champlain, Vermont

USGS Publications Warehouse

Manley, Patricia L.; Manley, T.O.; Hayo, Kathryn; Cronin, Thomas

2012-01-01

High resolution CHIRP (Compressed High Intensity Radar Pulse) seismic profiles reveal the presence of two lacustrine sediment drifts located in Lake Champlain's Juniper Deep. Both drifts are positive features composed of highly laminated sediments. Drift B sits on a basement high while Drift A is built on a trough-filling acoustically-transparent sediment unit inferred to be a mass-transport event. These drifts are oriented approximately north–south and are parallel to a steep ridge along the eastern shore of the basin. Drift A, located at the bottom of a structural trough, is classified as a confined, elongate drift that transitions northward to become a system of upslope asymmetric mudwaves. Drift B is perched atop a structural high to the west of Drift A and is classified as a detached elongate drift. Bottom current depositional control was investigated using Acoustic Doppler Current Profilers (ADCPs) located across Drift A. Sediment cores were taken at the crest and at the edges of the Drift A and were dated. Drift source, deposition, and evolution show that these drifts are formed by a water column shear with the highest deposition occurring along its crest and western flank and began developing circa 8700–8800 year BP.

The distribution and adsorption behavior of aliphatic amines in marine and lacustrine sediments

NASA Astrophysics Data System (ADS)

Wang, Xu-chen; Lee, Cindy

1990-10-01

The methylated amines—monomethyl-, dimethyl-, and trimethyl amine (MMA, DMA, TMA)—are commonly found in aquatic environments, apparently as a result of decomposition processes. Adsorption of these amines to clay minerals and organic matter significantly influences their distribution in sediments. Laboratory measurements using 14C-radiolabelled amines and application of a linear partitioning model resulted in calculated adsorption coefficients of 2.4-4.7 (MMA), 3.3 (DMA), and 3.3-4.1 (TMA). Further studies showed that adsorption of amines is influenced by salinity of the porewaters, and clay mineral and organic matter content of the sediment solid phase. Concentrations of monomethyl- and dimethyl amine were measured in the porewaters and the solid phase of sediment samples collected from Flax Pond and Lake Ronkonkoma (NY), Long Island Sound, and the coastal Peru upwelling area. These two amines were present in all sediments investigated. A clear seasonal increase in the solid-phase concentration of MMA and DMA in Flax Pond sediments was likely related to the annual senescence of salt marsh grasses, either directly as a source of these compounds or indirectly by providing additional exchange capacity to the sediments. The distribution of amines in the solid and dissolved phases observed in all sediments investigated suggests that the distribution of these compounds results from a balance among production, decomposition, and adsorption processes.

Deposition and chemistry of bottom sediments in Cochiti Lake, north-central New Mexico

USGS Publications Warehouse

Wilson, Jennifer T.; Van Metre, Peter C.

2000-01-01

Bottom sediments were sampled at seven sites in Cochiti Lake in September 1996. Sediment cores penetrating the entire lacustrine sediment sequence were collected at one site near the dam. Surficial sediments were sampled at the near-dam site and six other sites located along the length of the reservoir. Analyses included grain size, major and trace elements, organochlorine compounds, polycyclic aromatic hydrocarbons (PAH's), and radionuclides. Concentrations of trace elements, organic compounds, and radionuclides are similar to those in other Rio Grande reservoirs and are low compared to published sediment-quality guidelines. Most elements and compounds that were detected did not show trends in the age estimated sediment cores with the exception of a decreasing trend in total DDT concentrations from about 1980 to 1992. The mixture of PAH's suggests that the increase is caused by inputs of fuel-related PAH and not combustion- related PAH.

Search for continuous paleoclimatic record in Holocene lacustrine sediments from Lake District, Chile (40°S)

NASA Astrophysics Data System (ADS)

Bertrand, S.; Fagel, N.

2003-04-01

preliminary study emphasizes the influence of geodynamic conditions on sedimentology of lacustrine deposits in a geodynamically active region. The contribution of the punctual tectonic and volcanic-derived layers to sediment thickness must be taken into account before calculation of the age-depth model.

Palaeogeographic, palaeoclimatic, palaeohydrological and chemical/biochemical controls on accumulation of late Eocene coastal lacustrine-palustrine limestones, Southern England

NASA Astrophysics Data System (ADS)

Armenteros, Ildefonso; Edwards, Nicholas

2012-12-01

The shallow-lacustrine to palustrine Hatherwood Limestone Member of the late Eocene Headon Hill Formation, Southern England, is in a succession of fluvio-estuarine and laguno-lacustrine siliciclastic sediments. It is up to 8.0 m thick and is subdivided by metric-scale palaeotopographic erosion surfaces, one of which underlies lenticular humic siliciclastic mudstones. The limestone lithologies are (1) biocalcilutites/biocalcisiltites, (2) biocalcarenites, (3) calcirudites, and (4) laterally-discontinuous laminar and fenestral crusts. Lithology (1) accumulated in a low-energy shallow-lacustrine depositional environment, indicated by the predominance of pulmonate pond-snails in the mollusc assemblage. In contrast, lithologies (2) and (3) are the coarse-grained fills of shallow palaeotopographic lows, and also form basal lags and palaeokarst-fills. Lithology (3) comprises remnant autochthonous lags that resulted from selective erosion during lacustrine transgressions. Brecciation and proto-intraclast to nodular differentiation in lithology (2) suggests derivation of the intraclasts from subaerially- and pedogenically-modified shallow-lacustrine muds. Laminar crusts (4), 0.5-6.0 cm in thickness, display irregularly undulose and anastamosing laminations 150-400 μm thick, that display differential staining by iron oxide. The abundance of rootlet traces and calcitised parenchymatic root tissues in the fenestral crusts suggests a palustrine depositional environment for these lithologies. The siliciclastic mudstone lithologies are (1) black humic muds and (2) blue-green silty muds and marls. The high C/N molar ratio of the black muds suggests derivation of the humic content mainly from vascular plants in local wetlands. The mollusc assemblage of the blue-green siliciclastic muds resembles floodplain lake assemblages from the regional Palaeogene succession. Mean stable isotopic values for limestone samples, of - 4.75 ± 1.53 for δ13C and - 2.77 ± 1.47 for δ18O, indicate a

The influence of authigenic clay formation on the mineralogy and stable isotopic record of lacustrine carbonates

NASA Astrophysics Data System (ADS)

Bristow, Thomas F.; Kennedy, Martin J.; Morrison, Keith D.; Mrofka, David D.

2012-08-01

The mineralogical, compositional and stable isotopic variability of lacustrine carbonates are frequently used as proxies for ancient paleoenvironmental change in continental settings, under the assumption that precipitated carbonates reflect conditions and chemistry of ancient lake waters. In some saline and alkaline lake systems, however, authigenic clay minerals, forming at or near the sediment water interface, are a major sedimentary component. Often these clays are rich in Mg, influencing the geochemical budget of lake waters, and are therefore expected to influence the properties of contemporaneous authigenic carbonate precipitates (which may also contain Mg). This paper documents evidence for a systematic feedback between clay mineral and carbonate authigenesis through multiple precessionally driven, m-scale sedimentary cycles in lacustrine oil-shale deposits of the Eocene Green River Formation from the Uinta Basin (NE Utah). In the studied section, authigenic, Mg-rich, trioctahedral smectite content varies cyclically between 9 and 39 wt.%. The highest concentrations occur in oil-shales and calcareous mudstones deposited during high lake level intervals that favored sedimentary condensation, lengthening the time available for clay diagenesis and reducing dilution by other siliciclastic phases. An inverse relation between dolomite percentage of carbonate and trioctahedral smectite abundance suggests the Mg uptake during clay authigenesis provides a first order control on carbonate mineralogy that better explains carbonate mineralogical trends than the possible alternative controls of (1) variable Mg/Ca ratios in lake water and (2) degree of microbial activity in sediments. We also observe that cyclical change in carbonate mineralogy, believed to be induced by clay authigenesis, also causes isotopic covariation between δ13CPDB and δ18OPDB of bulk sediments because of differences in the equilibrium fractionation factors of dolomite and calcite (˜2‰ and ˜2

Paleontological analysis of a lacustrine carbonaceous uranium deposit at the Anderson mine, Date Creek basin, west-central Arizona (U.S.A.)

USGS Publications Warehouse

Otton, J.K.; Bradbury, J.P.; Forester, R.M.; Hanley, J.H.

1990-01-01

The Tertiary sedimentary sequence of the Date Creek basin area of Arizona is composed principally of intertonguing alluvial-fan and lacustrine deposits. The lacustrine rocks contain large intermediate- to, locally, high-grade uranium deposits that form one of the largest uranium resources in the United States (an estimated 670,000 tons of U3O8 at an average grade of 0.023% is indicated by drilling to date). At the Anderson mine, about 50,000 tons of U3O8 occurs in lacustrine carbonaceous siltstones and mudstones (using a cutoff grade of 0.01%). The Anderson mine constitutes a new class of ore deposit, a lacustrine carbonaceous uranium deposit. Floral and faunal remains at the Anderson mine played a critical role in creating and documenting conditions necessary for uranium mineralization. Organic-rich, uraniferous rocks at the Anderson mine contain plant remains and ostracodes having remarkably detailed preservation of internal features because of infilling by opaline silica. This preservation suggests that the alkaline lake waters in the mine area contained high concentrations of dissolved silica and that silicification occurred rapidly, before compaction or cementation of the enclosing sediment. Uranium coprecipitated with the silica. Thinly laminated, dark-colored, siliceous beds contain centric diatoms preserved with carbonaceous material suggesting that lake waters at the mine were locally deep and anoxic. These alkaline, silica-charged waters and a stagnant, anoxic environment in parts of the lake were necessary conditions for the precipitation of large amounts of uranium in the lake-bottom sediments. Sediments at the Anderson mine contain plant remains and pollen that were derived from diverse vegetative zones suggesting about 1500 m of relief in the area at the time of deposition. The pollen suggests that the valley floor was semiarid and subtropical, whereas nearby mountains supported temperate deciduous forests. ?? 1990.

Record of late Pleistocene glaciation and deglaciation in the southern Cascade Range. I. Petrological evidence from lacustrine sediment in Upper Klamath Lake, southern Oregon

USGS Publications Warehouse

Reynolds, R.L.; Rosenbaum, J.G.; Rapp, J.; Kerwin, M.W.; Bradbury, J.P.; Colman, S.; Adam, D.

2004-01-01

Petrological and textural properties of lacustrine sediments from Upper Klamath Lake, Oregon, reflect changing input volumes of glacial flour and thus reveal a detailed glacial history for the southern Cascade Range between about 37 and 15 ka. Magnetic properties vary as a result of mixing different amounts of the highly magnetic, glacially generated detritus with less magnetic, more weathered detritus derived from unglaciated parts of the large catchment. Evidence that the magnetic properties record glacial flour input is based mainly on the strong correlation between bulk sediment particle size and parameters that measure the magnetite content and magnetic mineral freshness. High magnetization corresponds to relatively fine particle size and lower magnetization to coarser particle size. This relation is not found in the Buck Lake core in a nearby, unglaciated catchment. Angular silt-sized volcanic rock fragments containing unaltered magnetite dominate the magnetic fraction in the late Pleistocene sediments but are absent in younger, low magnetization sediments. The finer grained, highly magnetic sediments contain high proportions of planktic diatoms indicative of cold, oligotrophic limnic conditions. Sediment with lower magnetite content contains populations of diatoms indicative of warmer, eutrophic limnic conditions. During the latter part of oxygen isotope stage 3 (about 37-25 ka), the magnetic properties record millennial-scale variations in glacial-flour content. The input of glacial flour was uniformly high during the Last Glacial Maximum, between about 21 and 16 ka. At about 16 ka, magnetite input, both absolute and relative to hematite, decreased abruptly, reflecting a rapid decline in glacially derived detritus. The decrease in magnetite transport into the lake preceded declines in pollen from both grass and sagebrush. A more gradual decrease in heavy mineral content over this interval records sediment starvation with the growth of marshes at the margins

Hydrological responses of the Chihuahua Desert of Mexico to possible Heinrich Stadials: A study inferred from geochemistry and stable isotopes of lacustrine sediments

NASA Astrophysics Data System (ADS)

Quiroz-Jiménez, J. D.; Roy, P. D.; Lozano-SantaCruz, R.; López Balbiaux, N.; Girón-García, P.

2016-12-01

The Heinrich Stadials (H6-H1) were cooler intervals of different duration characterized by massive discharge of icebergs from the Laurentide Ice Sheet mainly through the Hudson Straight into the Atlantic Ocean. In this paper, we present a proxy record to infer hydrological responses of the Chihuahua Desert of Mexico to all the Heinrich Stadials (HS) from element ratios, CO3 abundance, and oxygen and carbon isotope compositions of lacustrine calcite of the sediments deposited between depths of 560-78 cm ( 66-8 ka) of a new core collected from the Santiaguillo Basin. Sediments deposited during different HS were identified by radiocarbon dating up to 27.3 ka, extrapolation of an average sediment rate and tuning the CO3 abundance record with insolation in rest of the sequence, and oxygen isotope composition of authigenic CO3. Proxies suggest that hydroclimate of the Chihuahua Desert of Mexico responded differently to different HS. The overall runoff and hence precipitation remained below average during H6, H4, H2 and H1. Both of them were above average during H5 and H3. Similarly, runoff during H4 showed the least variability and it was the most variable during H5. Except for H2, negative excursions in δ18O values suggest cooler conditions during all other HS. In general, dissolved HCO3- was mainly sourced from the atmospheric CO2 during arid intervals. Both the lake productivity and atmospheric CO2 influenced the carbon isotope composition of dissolved HCO3- during humid intervals. During the H2, δ13C values indicate dominant influence of lacustrine productivity. Similar to Chihuahua Desert of Mexico, speleothem records from Fort Stanton and Cave of the Bells (Asmerom et al., 2010; Wagner et al., 2010) showed that hydroclimate of southwest USA also experienced millennial-scale variability and some intervals were more homogeneous compared to others. We did not observe concurrency in proxy records of the Chihuahua Desert of Mexico and southwest USA. Instead, we

Accumulation and diagenesis of chlorinated hydrocarbons in lacustrine sediments

USGS Publications Warehouse

Elsenreich, S.J.; Capel, P.D.; Robbins, J.A.; Bourbonniere, R.

1989-01-01

Two sediment cores were taken from the Rochester Basin of eastern Lake Ontario and analyzed for the radionuclides 210Pb and 137Cs and several high molecular weight chlorinated hydrocarbons (CHs). The two sites are geographically proximate but differ in sedimentation rate, permitting sedimentation-dependent processes to be factored out. The 210Pb chronology showed a mixed depth of 3-5 cm and an intrinsic time resolution of 11-14 years. Vertically integrated numbers of deposit-feeding oligochaete worms and burrowing organisms are insufficient to homogenize the sediment on the time scale of CH inputs, which are non steady state. U.S. production and sales of polychlorinated biphenyls (PCBs), DDT, Mirex, and hexachlorobenzene (HCB), as determinants of the shape of the input function, adequately predict the overall shape and, in many cases, details in the sedimentary profile. Sediment focusing factors (FF) inferred from 137Cs and 210Pb inventories averaged 1.17 and 1.74 for cores E-30 and G-32, respectively. This permitted CH accumulation rates to be corrected for focusing. Apparent molecular diffusion coefficients modeled for many of the CHs were about (1-3) ?? 10-9 cm2/s.

Lacustrine records of Holocene climate and environmental change from the Lofoten Islands, Norway

NASA Astrophysics Data System (ADS)

Balascio, Nicholas L.

Lakes sediments from the Lofoten Islands, Norway, can be used to generate well resolved records of past climate and environmental change. This dissertation presents three lacustrine paleoenvironmental reconstructions that show evidence for Holocene climate changes associated with North Atlantic climate dynamics and relative sea-level variations driven by glacio-isostatic adjustment. This study also uses distal tephra deposits (cryptotephra) from Icelandic volcanic eruptions to improve the chronologies of these reconstructions and explores new approaches to crypto-tephrochronology. Past and present conditions at Vikjordvatnet, Fiskebolvatnet, and Heimerdalsvatnet were studied during four field seasons conducted from 2007--2010. Initially, each lake was characterized by measuring water column chemistry, logging annual temperature fluctuations, and conducting bathymetric and seismic surveys. Sediment cores were then collected and analyzed using multiple techniques, including: sediment density, magnetic susceptibility, loss-on-ignition, total carbon and nitrogen, delta13C and delta 15N of organic matter, and elemental compositions acquired by scanning X-ray fluorescence. Chronologies were established using radiocarbon dating and tephrochronology. A 13.8 cal ka BP record from Vikjordvatnet provides evidence for glacial activity during the Younger Dryas cold interval and exhibits trends in Ti, Fe, and organic content during the Holocene that correlate with regional millennial-scale climate trends and provide evidence for more rapid events. A 9.7 cal ka BP record from Fiskebolvatnet shows a strong signal of sediment inwashing likely driven by local geomorphic conditions, although there is evidence that increased inwashing at the onset of the Neoglacial could have been associated with increased precipitation. Heimerdalsvatnet provides a record of relative sea-level change. A 7.8 cal ka BP sedimentary record reflects changes in salinity and water column conditions as the

Sediment characteristics and configuration within the Otsego City Dam impoundment on the Kalamazoo River, Michigan, 2001-02

USGS Publications Warehouse

Rheaume, S.J.; Hubbell, D.L.; Rachol, C.M.; Simard, A.; Fuller, L.M.

2004-01-01

The removal of the Otsego City Dam on the Kalamazoo River at Otsego, Mich., is under consideration by the Michigan Department of Environmental Quality and the city of Otsego. The historical discharge of papermill waste containing polychlorinated biphenyls from sources upstream from the dam has led the U.S. Environmental Protection Agency to designate the Kalamazoo River from Morrow Dam near Comstock to its mouth near Saugatuck as a Federal Superfund site. The papermill waste is concentrated in organic sediment and kaolinite clay, with the sediment containing as much as 94 milligrams per kilogram polychlorinated biphenyls. This contaminated sediment could move if the dam is removed; therefore, it is necessary to estimate the characteristics and configuration of the sediment before removal plans begin. Data from augered sections and sediment cores show that the current Otsego City impoundment sediments were deposited in two distinctly different sedimentary environments: (1) lacustrine sediments consisting of organic-rich silt and clay, fine to medium sand, and some gravel deposited in a repetitive, cyclic fashion related to former stream velocities when the Otsego City impoundment water levels were 2-4 feet higher (1880s-1960s), and from downstream movement of lacustrine sediments during the removal of the upstream Plainwell Dam superstructure in the 1980s; and (2) more recent (1980s-2002) coarse-grained alluvium deposited on top of the lacustrine sediments. The volume of instream sediment contained within the Otsego City impoundment is estimated to be about 457,270 cubic yards. This estimate is based on the composite thicknesses of the lacustrine deposits and overlying alluvium, which were determined to contain PCBs, and does not include bank or flood-plain deposits.

Geochemical characteristics of Holocene laminated sapropel (unit II) and underlying lacustrine unit III in the Black Sea

USGS Publications Warehouse

Dean, Walter E.; Arthur, Michael A.

2011-01-01

eg 1 of the 1988 R/V Knorr expeditions to the Black Sea recovered 90 gravity and box cores. The longest recovery by gravity cores was about 3 meters, with an average of about 2.5 meters, recovering all of the Holocene and upper Pleistocene sections in the Black Sea. During the latest Pleistocene glaciation, sea level dropped below the 35-meters-deep Bosporus outlet sill of the Black Sea. Therefore throughout most of its history the Black Sea was a lake, and most of its sediments are lacustrine. The oldest sediments recovered (older than 8,000 calendar years) consist of massive to coarsely banded lacustrine calcareous clay designated as lithologic Unit III, generally containing less than 1 percent organic carbon (OC). The base of overlying Unit II marks the first incursion of Mediterranean seawater into the Black Sea, and the onset of bottom-water anoxia about 7,900 calendar years. Unit II contains as much as 15 percent OC in cores from the deepest part of the Black Sea (2,200 meters). The calcium carbonate (CaCO3) remains of the coccolith Emiliania huxleyi form the distinctive white laminae of overlying Unit I. The composition of Unit III and Unit II sediments are quite different, reflecting different terrigenous clastic sources and increased contributions from hydrogenous and biogenic components in anoxic Unit II sapropel. In Unit II, positive covariance between OC and three trace elements commonly concentrated in OC-rich sediments where sulfate reduction has occurred (molybdenum, nickel, and vanadium) and a nutrient (phosphorus) suggest a large marine source for these elements although nickel and vanadium also have a large terrigenous clastic source. The marine sources may be biogenic or hydrogenous. A large biogenic source is also suggested for copper and cobalt. Because abundant pyrite forms in the water column and sediments of the Black Sea, we expected to find a large hydrogenous iron component, but a strong covariance of iron with aluminum suggests that the

Isotopic identification of the source of methane in subsurface sediments of an area surrounded by waste disposal facilities

USGS Publications Warehouse

Hackley, Keith C.; Liu, Chao-Li; Trainor, D.

1999-01-01

The major source of methane (CH4) in subsurface sediments on the property of a former hazardous waste treatment facility was determined using isotopic analyses measured on CH4 and associated groundwater. The site, located on an earthen pier built into a shallow wetland lake, has had a history of waste disposal practices and is surrounded by landfills and other waste management facilities. Concentrations of CH4 up to 70% were found in the headspace gases of several piezometers screened at 3 different depths (ranging from 8 to 17 m) in lacustrine and glacial till deposits. Possible sources of the CH4 included a nearby landfill, organic wastes from previous impoundments and microbial gas derived from natural organic matter in the sediments. Isotopic analyses included ??13C, ??D, 14C, and 3H on select CH4 samples and ??D and ??18O on groundwater samples. Methane from the deepest glacial till and intermediate lacustrine deposits had ??13C values from -79 to -82???, typical of natural 'drift gas' generated by microbial CO2-reduction. The CH4 from the shallow lacustrine deposits had ??13C values from -63 to -76???, interpreted as a mixture between CH4 generated by microbial fermentation and the CO2-reduction processes within the subsurface sediments. The ??D values of all the CH4 samples were quite negative ranging from -272 to -299???. Groundwater sampled from the deeper zones also showed quite negative ??D values that explained the light ??D observed for the CH4. Radiocarbon analyses of the CH4 showed decreasing 14C activity with depth, from a high of 58 pMC in the shallow sediments to 2 pMC in the deeper glacial till. The isotopic data indicated the majority of CH4 detected in the fill deposits of this site was microbial CH4 generated from naturally buried organic matter within the subsurface sediments. However, the isotopic data of CH4 from the shallow piezometers was more variable and the possibility of some mixing with oxidized landfill CH4 could not be completely

Sediment Sampling Operating Procedure

EPA Pesticide Factsheets

EPA Region 4 Science and Ecosystem Support Division (SESD) document that describes general and specific procedures, methods, and considerations when collecting sediment samples for field screening or laboratory analysis.

Lipid-based palaeotemperature reconstruction in lakes: New insights on the applicability of branched GDGTs in lacustrine sedimentary archives

NASA Astrophysics Data System (ADS)

Weber, Yuki; De Jonge, Cindy; Hopmans, Ellen C.; Sinninghe Damsté, Jaap S.; Gilli, Adrian; Lehmann, Moritz F.; Niemann, Helge

2014-05-01

Branched glycerol dialkyl glycerol tetraethers (brGDGTs) are bacterial membrane lipids that occur ubiquitously in soils worldwide. The relative abundances of nine structurally related brGDGTs (used in the MBT and CBT indices) have been shown to correlate with mean annual air temperature (MAAT) and soil pH, making them potential proxies in sediments that receive soil organic matter from terrestrial environments. The brGDGT distributions in lake deposits, however, mostly follow a different correlation with air temperature and (to a minor extent) lake water pH. This points to a substantial contribution of brGDGTs from in situ production within the lake water column and/or -sediments. It is also quite likely that the fractions of soil- and lake-derived brGDGTs vary considerably between sampling sites and with time, due to spatial and temporal changes in sediment input rates. Paleoclimate reconstructions using lacustrine brGDGT records thus remain challenging, especially because little is known about the environmental variables that control bacterial brGDGT production within aquatic environments. In order to decipher the impact of in situ production, we compared the brGDGT composition of surface sediments and corresponding catchment soils of 35 lakes from the Swiss alpine region, spanning an altitudinal gradient from 200 - 2000 m above mean sea level. We used an improved HPLC method to additionally quantify six recently discovered isomers, which vary in the position of their methyl branches. These 6-methyl compounds previously co-eluted with those brGDGTs used to calculate the MBT and CBT indices, obscuring any paleoenvironmental information they potentially yield. A principal component analysis suggests that the fractional abundances of the 6-methyl brGDGTs are primarily controlled by the surface water pH of the lakes. Notably, and in contrast to soils, the fractional abundance of the 5-methyl pentamethylated brGDGT in lake sediments does not show a correlation with

Estimating total suspended sediment yield with probability sampling

Treesearch

Robert B. Thomas

1985-01-01

The ""Selection At List Time"" (SALT) scheme controls sampling of concentration for estimating total suspended sediment yield. The probability of taking a sample is proportional to its estimated contribution to total suspended sediment discharge. This procedure gives unbiased estimates of total suspended sediment yield and the variance of the...

Evidences of melting of terrestrial sediments and paleoenvironment changes during the Younger Dryas in tectonic lacustrine basins of Transmexican Volcanic Belt, Mexico.

NASA Astrophysics Data System (ADS)

Israde-Alcantara, I.

2017-12-01

It is well known in the sedimentary record of several parts of the world that during the Younger Dryas interval (YD) ocurred an abrupt environmental change between 12,900 and 11,700 cal yr BP (10,900 to 10,000 14C BP). In the lacustrine basins this changes are often preserved and in some Mexican lakes this is a distinctive stratigraphic marker for the YD. We analized the proxies of this event in cores of two lakes (Chapala, Cuitzeo) and three trenches of ex-lakes (Acambay,Texcoco and El Cedral). Deposits consist of fine detrital material with often Pleistocene fossil vertebrate assemblages. At the Chapala, Cuitzeo, Acambay, and Tocuila lacustrine environments are found in association with a distinctive dark organic layer showing sharp changes in the diatom, pollen, mineralogical and geochemical record. Includes also microscopic magnetic, Fe-rich spherules, silica melted droplets with aerodynamic shapes (tektites), followed by large amounts of charcoal, and sometimes nanodiamonds (Cuitzeo), that were deposited at the onset of the YD or in the limit Pleistocene-Holocene. These unusual materials are buried more than 2.50 meters and were not observed above or below the Younger Dryas sediments at these sites. The geochemistry of the microspherules indicates that they are not volcanic, anthropogenic or authigenic origin. A very distinctive feature is the shape of the spherules, ovoid, polygonal, filigreed or dendritic indicating melting and quenching infering that are product of an impact event. Their morphologies includes hollow shells caused by de-gassing of elements at very high temperatures causing a flattened side with a "skirt" structure by a high-velocity collision.Our results are consistent with the Firestone hypothesis.

Fluvial and Lacustrine Processes in Meridiani Planum and the Origin of the Hematite by Aqueous Alteration

NASA Technical Reports Server (NTRS)

Newsom, H. E.; Barber, C. A.; Schelble, R. T.; Hare, T. M.; Feldman, W. C.; Sutherland, V.; Livingston, A.; Lewis, K.

2003-01-01

The prime MER landing site in Meridiani Planum is located on layered materials, including hematite, whose origin as lacustrine or aeolian sediments, or volcanic materials is uncertain. Our detailed mapping of the region provides important constraints on the history of the region. Our mapping of the location of fluvial and lacustrine land forms in the region relative to the layered deposits provides new evidence of a long history of erosion and deposition as has long been noted . In addition, our detailed mapping of the southern boundary of the hematite deposit strongly supports an association between longlived fluvial channels and lacustrine basins and the strongest hematite signatures. This evidence supports an origin of the hematite deposits by interaction with water under ambient conditions in contrast to suggestions of hydrothermal processes due to volcanic or impact crater processes. An important part of the story is the evidence for the localization of the layered deposits due to topographic control induce by the presence of a large early basin we have identified that extends to the north-east of the landing site. Distribution of current channel networks, drainages,

δ 13C and δD identification of sources of lipid biomarkers in sediments of Lake Haruna (Japan)

NASA Astrophysics Data System (ADS)

Chikaraishi, Yoshito; Naraoka, Hiroshi

2005-07-01

Organic materials in lacustrine sediments are from multiple terrestrial and aquatic sources. In this study, carbon (δ 13C) and hydrogen isotopic compositions (δD) of phytol, various sterols, and major n-fatty acids in sediments at Lake Haruna, Japan, were determined in their solvent-extractable (free) and saponification-released forms (bound). The δ 13C-δD distributions of these lipid molecules in sediments are compared with those of terrestrial C3 and C4 plants, aquatic C3 plants, and plankton to evaluate their relative contributions. δ 13C-δD of free phytol in sediments is very close to that of phytol in plankton samples, whereas δ 13C-δD of bound phytol in sediments is on a mixing line between terrestrial C3 plant and plankton material. Unlike phytol, no significant δ 13C-δD difference between free and bound forms was found in sterols and n-fatty acids. δ 13C-δD values of algal sterols such as 24-methylcholesta-5,22-dien-3β-ol in sediments are close to those of plankton, whereas δ 13C-δD of multiple-source sterols such as 24-ethylcholest-5-en-3β-ol and of major n-fatty acids such as n-hexadecanoic acid in sediments are between those of terrestrial C3 plants and plankton samples. Thus, δ 13C-δD distributions clearly indicate the specific source contributions of biomarkers preserved in a lacustrine environment. Free phytol and algal sterols can be attributed to phytoplankton, and bound phytol, multiple source sterols, and major n-fatty acids are contributed by both terrestrial C3 plants and phytoplankton.

High-resolution δ13C record of fossil wood and bulk organic matter from a deep Oligocene lacustrine succession, Bach Long Vi Island, Vietnam

NASA Astrophysics Data System (ADS)

Rizzi, M.; Schovsbo, N. H.; Fyhn, M. B. W.; Korte, C.

2017-12-01

We present a high-resolution stable isotope record based on bulk organic matter (δ13Corg) and fossil wood (δ13Cwood) originating from Oligocene deep lacustrine sediments cored on the Bach Long Vi Island, northern Gulf of Tonkin, offshore Vietnam. The sediments are exceptionally well preserved. They are thus excellently suited for a detailed stratigraphical analysis of the stable isotope record and as proxy for environmental and climatic changes within this period. The sediments were deposited in rapid subsiding, narrow and elongated fault-bound graben (Fyhn and Phach, 2015) and are represented by deep pelagic lacustrine organic-rich mud interrupted by numerous density-flow deposits (Hovikoski et al., 2016). The density-flow deposits contain abundant fragments of fossil wood. Therefore it was possible to obtain 262 coalified wood fragments together with 1063 bulk organic samples throughout the span of the core. This allowed to establish a high resolution stable C isotope record (δ13Corg and δ13Cwood). In addition 2464 handheld XRF determinations were carried out to further characterize the depositional environment (Rizzi et al., 2017). The organic carbon isotope trend from the 500 m core succession provides insight into the palaeoenvironmental changes of the lake during the Oligocene. Both, global and local factors control the δ13C variations. The aim of the study is to obtain pure global δ13Corg and δ13Cwood signals that would allow comparison of the studied sediments with coeval syn-rift successions in the South China Sea region and other parts of the world. [1] Fyhn and Phach (2015) Tectonics, 34(2): 290-312. [2] Hovikoski et al. (2016) Journal of Sedimentary Research, 86(8): 982-1007. [3] Rizzi et al. (2017) EGU General Assembly Abstract EGU 2017-17584.

Chapter D: With or Without Salt-a Comparison of Marine and Continental-Lacustrine Diatomite Deposits

USGS Publications Warehouse

Moyle, Phillip R.; Dolley, Thomas P.

2003-01-01

Diatoms in sedimentary deposits of marine and continental, especially lacustrine, origin have similar nutrient (for example, phosphate, nitrate, and silica) and light requirements; however, their geologic ranges and physiographic environments vary. Marine diatoms range in age from Early Cretaceous to Holocene, and continental diatoms range in age from Eocene to Holocene; however, most commercial diatomites, both marine and lacustrine, were deposited during the Miocene. Marine deposits of commercial value generally accumulated along continental margins with submerged coastal basins and shelves where wind-driven boundary currents provided the nutrient-rich upwelling conditions capable of supporting a productive diatom habitat. Commercial freshwater diatomite deposits occur in volcanic terrains associated with events that formed sediment-starved drainage basins, such as the Basin and Range Province, particularly in Nevada. Marine habitats generally are characterized by stable conditions of temperature, salinity, pH, nutrients, and water currents, in contrast to lacustrine habitats, which are characterized by wide variations in these conditions. Marine deposits generally are of higher quality and contain larger resources, owing to their greater areal extent and thickness, whereas most of the world's known diatomites are of lacustrine origin. Both types of deposit are commonly mined by open-pit methods and subjected to processing designed to remove organic matter, CO2, pore water, and inorganic contaminants in order to produce purified products. The highest quality diatomites, predominantly from marine sources, are used in filtration, although both types of deposit produce filter grades, and additional end uses include fillers, additives, absorbents, and abrasives.

Piecewise SALT sampling for estimating suspended sediment yields

Treesearch

Robert B. Thomas

1989-01-01

A probability sampling method called SALT (Selection At List Time) has been developed for collecting and summarizing data on delivery of suspended sediment in rivers. It is based on sampling and estimating yield using a suspended-sediment rating curve for high discharges and simple random sampling for low flows. The method gives unbiased estimates of total yield and...

100 Area Columbia River sediment sampling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weiss, S.G.

1993-09-08

Forty-four sediment samples were collected from 28 locations in the Hanford Reach of the Columbia River to assess the presence of metals and man-made radionuclides in the near shore and shoreline settings of the Hanford Site. Three locations were sampled upriver of the Hanford Site plutonium production reactors. Twenty-two locations were sampled near the reactors. Three locations were sampled downstream of the reactors near the Hanford Townsite. Sediment was collected from depths of 0 to 6 in. and between 12 to 24 in. below the surface. Samples containing concentrations of metals exceeding the 95 % upper threshold limit values (DOE-RLmore » 1993b) are considered contaminated. Contamination by arsenic, chromium, copper, lead, and zinc was found. Man-made radionuclides occur in all samples except four collected opposite the Hanford Townsite. Man-made radionuclide concentrations were generally less than 1 pCi/g.« less

Sedimentology and geochemistry of lacustrine sequences of the upper Pleistocene and holocene in intertropical area (Lake Magadi and Green crater lake): paleoclimatic implications

NASA Astrophysics Data System (ADS)

Damnati, B.

1993-05-01

Sedimentological and geochemical analyses have been carried out on lacustrine deposits of East Africa, at Lake Magadi (2°S, 36°E, Kenya) and at Green Crater Lake (0°S, 36°E, Kenya), to determine the parameters controlling climatic and environmental dynamics during late Pleistocene and Holocene. These sedimentary sequences were collected with a stationary piston corer. At Lake Magadi (Fig. 1), sedimentary and geochemical control show three phases of lake level variation which corresponds to climatic change occurring during the last 40 thousand years. These phases were defined by three lithostratigraphic units. Laminated deposits of Lake Magadi were formed during a wet period. Analysis of these laminae define two microfacies: a dark lamina, characterised by lacustrine organic matter and a light lamina enriched in detritus, carbonates (CaCO 3) and magadiite (NaSi 7O 13(OH) 3, 3H 2O). The formation and preservation of each couplet was favoured by climatic contrast, lake stratification and various origin of the sediments (autochthon and allochthon) in the drainage basin. Therefore a relative chronology can be derived from laminae counting and the duration of deposition of each couplet. Spectral analysis applied on variation of the laminae thickness, shows the existence of three main periods, 4-7 years, 8-14 years and 18-30 years, respectively (Fig. 2). These cyclicites of the lacustrine environment precise former determinations established on more recent lacustrine sequences from East Africa. They are related to the global climatic cycle (quasi-biannual oscillations, El Nino Southern Oscillations and the sun spot cycles). At Green Crater Lake, the study of the sedimentary sequence was completed by physico-chemical analysis of the waters and interface sediments which demonstrate the carbonate, sodium, bicarbonate composition and the thermal and chemical stratification of the modern lake. The sedimentary sequence is characterized by volcanic deposits overlain by

Turbidity-controlled sampling for suspended sediment load estimation

Treesearch

Jack Lewis

2003-01-01

Abstract - Automated data collection is essential to effectively measure suspended sediment loads in storm events, particularly in small basins. Continuous turbidity measurements can be used, along with discharge, in an automated system that makes real-time sampling decisions to facilitate sediment load estimation. The Turbidity Threshold Sampling method distributes...

Lithostratigraphy and physical properties of lacustrine sediments of the last ca. 150 kyr from Chalco basin, central México

NASA Astrophysics Data System (ADS)

Ortega-Guerrero, Beatriz; Lozano-García, Socorro; Herrera-Hernández, Dimitris; Caballero, Margarita; Beramendi-Orosco, Laura; Bernal, Juan Pablo; Torres-Rodríguez, Esperanza; Avendaño-Villeda, Diana

2017-11-01

The recognition of past climatic fluctuations in sedimentary sequences in central Mexico is relevant for understanding the forcing mechanisms and responses of climatic system in the northern American tropic. Moreover, in this active volcanic setting the sedimentary record preserves the history of past volcanic activity. Climatic and environmental variability has been documented for the last tenths of thousands of years from the upper lacustrine sediments in Chalco basin. A series of cores drilled down to 122 m depth in this basin offer a long, continuous and high resolution record of past climatic changes of the last ca. 150 kyr in this region. Here we present the detailed lithostratigraphy and some physical properties (magnetic susceptibility and density) of the master sequence. Sedimentary components and their abundance were identified and quantified in smear slides and direct core observations. Age model is based on 13 14C and one 230Th/U dates. Based on their facies association seven lithostratigraphic units were defined, which reflect the main stages of lake Chalco evolution. These phases closely match the marine isotopic stages. The data reveal that at the end of MIS6 Chalco was a relatively deep and stratified freshwater lake. During MIS5 the depositional environment fluctuated between low lake stands to marshy and marginal playa settings with sporadic flooding events, and severe arid periods resulted in aerial exposure of lake sediments. Low lake stands persisted during MIS4 and MIS3, with minor fluctuations towards slightly deeper phases. The Last Glacial Maximum (LGM) and the deglacial period (21-13 kyr) are characterized by intense volcanism. The early and mid-Holocene high calcareous content and alkaline-subsaline lake suggest dry conditions. The fluctuations of lake levels inferred provide the basis for future paleoclimatic works.

Prehistoric earthquake history revealed by lacustrine slump deposits

NASA Astrophysics Data System (ADS)

Schnellmann, Michael; Anselmetti, Flavio S.; Giardini, Domenico; McKenzie, Judith A.; Ward, Steven N.

2002-12-01

Five strong paleoseismic events were recorded in the past 15 k.y. in a series of slump deposits in the subsurface of Lake Lucerne, central Switzerland, revealing for the first time the paleoseismic history of one of the most seismically active areas in central Europe. Although many slump deposits in marine and lacustrine environments were previously attributed to historic earthquakes, the lack of detailed three-dimensional stratigraphic correlation in combination with accurate dating hampered the use of multiple slump deposits as paleoseismic indicators. This study investigated the fingerprint of the well-described A.D. 1601 earthquake (I = VII VIII, Mw ˜ 6.2) in the sediments of Lake Lucerne. The earthquake triggered numerous synchronous slumps and megaturbidites within different subbasins of the lake, producing a characteristic pattern that can be used to assign a seismic triggering mechanism to prehistoric slump events. For each seismic event horizon, the slump synchronicity was established by seismic-stratigraphic correlation between individual slump deposits through a quasi-three-dimensional high-resolution seismic survey grid. Four prehistoric events, dated by accelerator mass spectrometry, 14C measurements, and tephrochronology on a series of long gravity cores, occurred at 2420, 9770, 13,910, and 14,560 calendar yr ago. These recurrence times are essential factors for assessing seismic hazard in the area. The seismic hazard for lakeshore communities is additionally amplified by slump-induced tsunami and seiche waves. Numerical modeling of such tsunami waves revealed wave heights to 3 m, indicating tsunami risk in lacustrine environments.

Soft-sediment deformation in New Zealand: Structures resulting from the 2010/11 Christchurch earthquakes and comparison with Pleistocene sediments of the Taupo Volcanic Zone (TVZ)

NASA Astrophysics Data System (ADS)

Scholz, C.; Downs, D. T.; Gravley, D.; Quigley, M.; Rowland, J. V.

2011-12-01

The distinction between seismites and other event-related soft-sediment deformation is a challenging problem. Recognition and interpretation is aided by comparison of recent examples produced during known seismic events and those generated experimentally. Seismites are important features, once recognized in a rock, for interpretations of paleotectonic environment, tectonic relationships of sediments in basins, sedimentary facies analysis, evaluation of earthquake frequency and hazard and consequent land managment. Two examples of soft-sediment deformation, potentially generated through ground shaking and associated liquefaction, are described from within the TVZ: 1) Near Matata on the western margin of the Whakatane Graben. This location has a complicated en-echelon fault history and large earthquakes occur from time to time (e.g., 1987 ML6.3 Edgecumbe event). The structures occur in ~550 ka volcanic sediments, and represent soft-sediment deformation within stratigraphically-bounded layers. Based on paleoenvironment, appearance, and diagnostic criteria described by other authors (Sims 1975; Hempton and Dewey 1983), we interpret these features to have formed by ground shaking related to an earthquake and/or possibly accompanying large volcanic eruptions, rather than by slope failure. 2) Near Taupo, 3 km from the active Kaiapo fault. Lakeward dipping, nearly horizontal lacustrine sediments overlay Taupo Ignimbrite (1.8 ka). At one outcrop the lake beds have subsided into the underlying substrate resulting in kidney-shaped features. These structures formed as a result of liquefaction of the underlying substrate, which may have been caused by ground shaking related to either seismic or volcanic activity. However, inferred time relationships are more consistent with seismic-induced ground shaking. We compare and contrast the form and geometry of the above structures with seismites generated during the recent Christchurch earthquakes (Sep. 2010 and Feb. 2011). Hempton, M

Ground Penetrating Radar, Magnetic and Compositional Analysis of Sediment Cores and Surface Samples: The Relationships Between Lacustrine Sediments and Holocene Lake- Level and Climate Change at Deming Lake, Minnesota, USA

NASA Astrophysics Data System (ADS)

Murray, R.; Lascu, I.; Plank, C.

2007-12-01

Deming Lake is a small (<1 square km), deep (about 17m), meromictic kettle lake situated near the prairie- forest boundary, in Itasca State Park, MN. Because of the lake's location and morphology, the accumulated sediments comprise a high-resolution record of limnological and ecological changes in response to Holocene climate variations. We used a shore perpendicular transect of three cores (located in littoral, mid-slope, and profundal settings) and ground penetrating radar (GPR) profiles to investigate Holocene lake-level variability at Deming. Cores were sampled continuously at a 1-2 cm resolution and sediment composition (in terms of percent organic matter, carbonate material, and minerogenic residue) was determined via loss on ignition (LOI). Isothermal remanent magnetization (IRM) and anhysteretic remanent magnetization (ARM) were used as proxies of magnetic mineral concentration and grain size. Four lithostratigraphic units were identified and correlated between cores based on these analyses. Changes in GPR facies corroborate the correlation between the two shallow cores. In order to inform our interpretation of down-core variations in magnetic properties and LOI values in terms of variations in lake depth, a suite of over 70 modern sediment samples were collected from the basin and analyzed. LOI compositional variability across the basin was high, with no clear trends related to depth or distance from shore. A sharp decrease in minerogenic content was observed at depths consistent with a predicted wave-base of 0.5 m, but aside from this trend it appears the steep slopes of much of the basin promote gravity driven slumping and mixing of sediments at depth. In the profundal sediments IRM values are routinely 5% higher than in the slope and littoral environments, while ARM/IRM ratios indicate an increase in magnetic grain size with water depth. We infer that an increase in coarse organic material in the shallow-water cores of Deming records a period of aridity

Sediment characteristics and configuration within three dam impoundments on the Kalamazoo River, Michigan, 2000

USGS Publications Warehouse

Rheaume, S.J.; Rachol, C.M.; Hubbell, D.L.; Simard, Andreanne

2002-01-01

The removal of the remnants of three hydroelectric dams on the Kalamazoo River near Plainwell, Otsego, and Allegan, Michigan, has been proposed. The benefits of this removal include returning the Kalamazoo River to its pre-dam flow, increasing recreational use and safety on the river, and improving aquatic habitat. The U.S. Environmental Protection Agency has designated this reach of the Kalamazoo River as a Federal Superfund site because of the historical discharge of papermill waste containing polychlorinated biphenyls. Much of this waste material remains concentrated in organic sediment and kaolinite clay deposited upstream from the three dam foundations. Sediment containing up to 150 milligrams per kilogram polychlorinated biphenyls could move if dam foundations are removed; therefore, it is necessary to estimate the characteristic and configuration of the sediment before work begins. Data collected from augered sections and sediment cores show that impoundment sediments were deposited in two distinctly different sedimentary environments. Interbedded lacustrine sediments that overlie the pre-dam channel surface consist of organic-rich silt and clay, fine to medium sand, and some gravel. These materials were deposited in a repetitive, cyclic fashion related to former stream velocities when the impoundment water levels were 5-10 feet higher. Lowering of these water levels and demolition of the superstructures of these dams resulted in erosion of much of these instream lacustrine sediments and subsequent deposition of coarse-grained alluvium in the impounded channel behind the remaining dam foundations. The composite thicknesses of the lacustrine deposits and overlying alluvium was determined from sediment cores collected from each impoundment. The volume of instream sediment contained in each impoundment is estimated to be about 77,600 cubic yards at the Plainwell impoundment; 268,900 cubic yards at the Otsego impoundment; and 1,192,600 cubic yards at the

Recent Developments in Facies Models for Siliciclastic Sediments.

ERIC Educational Resources Information Center

Miall, Andrew D.

1982-01-01

Discusses theory of facies models (attempts to synthesize/generalize information about depositional environments), strengths/weaknesses of facies modelling, recent advances in facies models for siliciclastic sediments (focusing on fluvial, lacustrine, eolian and glacial environments, clastic shorelines and continental shelves, and clastic…

Regional paleohydrologic and paleoclimatic settings of wetland/lacustrine depositional systems in the Morrison Formation (Upper Jurassic), Western Interior, USA

USGS Publications Warehouse

Dunagan, S.P.; Turner, C.E.

2004-01-01

and shoreline deposits. Marginal lacustrine deposits include ooid and skeletal packstone-grainstone, siltstone, and sandstone. Distal lacustrine units are skeletal mudstone-wackestone, microbialites, and laminated (siliciclastic) mudstone. Differentiation between wetlands and distal lacustrine units is not always possible. Palustrine features, Magadi-type chert (MTC), and evaporites record episodes of increased aridity and exposure. Farther upstream, during deposition of the upper part of the Brushy Basin Member, the ancestral Uncompahgre Uplift imposed a barrier to shallow, eastward-flowing groundwater that discharged into the San Juan/Paradox Basin on the upstream side of the uplift. This created the closed hydrologic setting necessary for development of an alkaline-saline wetland/lacustrine complex ("Lake" T'oo'dichi'). Silicic volcanic ash, delivered by prevailing winds from calderas west and southwest of the basin, contributed to the pore-water evolution in the sediments. A distinctive lateral hydrogeochemical gradient, reflecting increasing salinity and alkalinity in the pore waters, altered the ash to a variety of authigenic minerals that define concentric zones within the basin. The basinward progression of diagenetic mineral zones is smectite???clinoptilolite???analcime ??potassium feldspar???albite. The groundwater-fed wetlands were shallow and frequently evaporated to dryness. Scarce laminated gray mudstone beds record distinct episodes of freshwater lacustrine deposition that resulted from intermittent streams that carried detritus well out into the basin. ?? 2004 Elsevier B.V. All rights reserved.

The combined effects of sediment accretion (burial) and nutrient enrichment on the growth and propagation of Phalaris arundinacea

PubMed Central

Chen, Xinsheng; Liao, Yulin; Xie, Yonghong; Wu, Chao; Li, Feng; Deng, Zhengmiao; Li, Xu

2017-01-01

Sediment accretion (burial) and nutrient enrichment occur concurrently in lacustrine wetlands, but the role of these two aspects of sedimentation on macrophyte performance has rarely been examined. Here, we investigated the concurrent effects of sediment accretion and nutrient enrichment on the growth and propagation of Phalaris arundinacea L. using a factorial sediment burial by nutrient addition experimental design. Regardless of burial depth, nutrient addition increased biomass accumulation, shoot mass ratio, the number of rhizomes, and the length of ramets and rhizomes. While burial had little effect on plant growth and propagation, it had an interactive effect with nutrient addition on belowground growth and ramet production. These results indicate that P. arundinacea is tolerant to burial, which allows it to grow in habitats with high sedimentation rates. However, the enhanced growth and propagation of P. arundinacea following sedimentation were primarily related to nutrient enrichment. This suggests that nutrient enrichment of sediments, which occurs in many lacustrine wetlands, increases the risk of invasion by P. arundinacea. PMID:28054590

Late Cenozoic geology and lacustrine history of Searles Valley, Inyo and San Bernardino Counties, California

USGS Publications Warehouse

Smith, George I.

2009-01-01

Searles Valley is an arid, closed basin lying 70 km east of the south end of the Sierra Nevada, California. It is bounded on the east and northeast by the Slate Range, on the west by the Argus Range and Spangler Hills, and on the south by the Lava Mountains; Searles (dry) Lake occupies the north-central part of the valley. During those parts of late Pliocene and Pleistocene time when precipitation and runoff from the east side of the Sierra Nevada into the Owens River were much greater than at present, a chain of as many as five large lakes was created, of which Searles Lake was third. The stratigraphic record left in Searles Valley when that lake expanded, contracted, or desiccated, is fully revealed by cores from beneath the surface of Searles (dry) Lake and partly recorded by sediments cropping out around the edge of the valley. The subsurface record is described elsewhere. This volume includes six geologic maps (scales: 1:50,000 and 1:10,000) and a text that describes the outcrop record, most of which represents sedimentation since 150 ka. Although this outcrop record is discontinuous, it provides evidence indicating the lake's water depths during each expansion, which the subsurface record does not. Maximum-depth lakes rose to the 2,280-ft (695 m) contour, the level of the spillway that led overflowing waters to Panamint Valley; that spillway is about 660 ft (200 m) above the present dry-lake surface. Several rock units of Tertiary and early Quaternary ages crop out in Searles Valley. Siltstone and sandstone of Tertiary age, mostly lacustrine in nature and locally deformed to near-vertical dips, are exposed in the southern part of the valley, as is the younger(?) upper Miocene Bedrock Spring Formation. Unnamed, mostly mafic volcanic rocks of probable Miocene or Pliocene age are exposed along the north and south edges of the basin. Slightly deformed lacustrine sandstones are mapped in the central-southwestern and southern parts of the study area. The Christmas

Trace fossils from Jurassic lacustrine turbidites of the Anyao Formation (Central China) and their environmental and evolutionary significance

USGS Publications Warehouse

Buatois, Luis A.; Mángano, M. Gabriela; Wu, Xiantao; Zhang, Guocheng

1996-01-01

The Lower Jurassic Anyao Formation crops out near Jiyuan city, western Henan Province, central China. It is part of the infill of the nonmarine early Mesozoic Jiyuan‐Yima Basin. In the Jiyuan section, this unit is about 100 m thick and consists of laterally persistent, thin and thick‐bedded turbidite sandstones and mudstones displaying complete and base‐or top‐absent Bouma sequences, and thick‐bedded massive sandstones. The Anyao Formation records sedimentation within a lacustrine turbidite system developed in a pull‐apart basin. Processes involved include high and low density turbidity currents, sometimes affected by liquefaction or fluidization. Facies analysis suggests that this succession is formed by stacked aggradational turbidite lobes. The absence of thick mudstone packages indicates that background sedimentation was subordinate to high frequency turbidite deposition.The Anyao Formation hosts a moderately diverse ichnofauna preserved as hypichnial casts on the soles of thin‐bedded turbidite sandstones. The ichnofauna consists of Cochlichnus anguineus, Hel‐minthoidichnites tenuis, Helminthopsis abeli, H. hieroglyphica, Mono‐morphichnus lineatus, Paracanthorhaphe togwunia, Tuberculichnus vagans, Vagorichnus anyao, tiny grazing trails, and irregularly branching burrows. Vagorichnus anyao occurs not only as a discrete trace, but also as a compound ichnotaxon intergrading with Gordia marina and Tuberculichnus vagans. Both predepositional and post‐depositional traces are present on the soles of turbidites.This ichnofauna comprises both feeding and grazing traces produced by a deposit‐feeding lacustrine benthic biota. Crawling traces are rare. Although certain ichnofossils (e.g. V. anyao, P. togwunia) show overall similarities with deep‐sea agrichnia, they differ in reflecting remarkably less specialized feeding strategies, displaying overcrossing between specimens (and to a lesser extent, self‐crossing), and in the case of V�

Sediment sampling and processing methods in Hungary, and possible improvements

NASA Astrophysics Data System (ADS)

Tamas, Eniko Anna; Koch, Daniel; Varga, Gyorgy

2016-04-01

The importance of the monitoring of sediment processes is unquestionable: sediment balance of regulated rivers suffered substantial alterations in the past century, affecting navigation, energy production, fish habitats and floodplain ecosystems alike; infiltration times to our drinking water wells have shortened, exposing them to an eventual pollution event and making them vulnerable; and sediment-attached contaminants accumulate in floodplains and reservoirs, threatening our healthy environment. The changes in flood characteristics and rating curves of our rivers are regularly being researched and described, involving state-of-the-art measurement methods, modeling tools and traditional statistics. Sediment processes however, are much less known. Unlike the investigation of flow processes, sediment-related research is scarce, which is partly due to the outdated methodology and poor database background in the specific field. Sediment-related data, information and analyses form an important and integral part of Civil engineering in relation to rivers all over the world. In relation to the second largest river of Europe, the Danube, it is widely known in expert community and for long discussed at different expert forums that the sediment balance of the river Danube has changed drastically over the past century. Sediment monitoring on the river Danube started as early as the end of the 19th century, with scattered measurements carried out. Regular sediment sampling was developed in the first half of the 20th century all along the river, with different station density and monitoring frequencies in different countries. After the first few decades of regular sampling, the concept of (mainly industrial) development changed along the river and data needs changed as well, furthermore the complicated and inexact methods of sampling bed load on the alluvial reach of the river were not developed further. Frequency of suspended sediment sampling is very low along the river

Underwater Sediment Sampling Research

DTIC Science & Technology

2017-01-01

resolved through further experimentation . Underwater Sediment Sampling Research vi UNCLAS//Public | CG-926 RDC | A. Hanson, et al. Public...Chemical Oceanographer, and In situ Chemical Analysis Subject Matter Expert (SME). 2 LABORATORY TEST SET UP The experimental research and laboratory... methodology involved using a fluorescence oil sensor (Turner Designs Cyclops-7) to measure the TPH contained in the interstitial waters (i.e., pore

Miocene to recent history of the western Altiplano in northern Chile revealed by lacustrine sediments of the Lauca basin (18°15' 18°40' S/69°30' 69°05'W)

NASA Astrophysics Data System (ADS)

Kött, A.; Gaupp, R.; Wörner, G.

1995-12-01

The intramontane Lauca Basin at the western margin of the northern Chilean Altiplano lies to the west of and is topographically isolated from the well-known Plio-Pleistocene lake system of fluvio-lacustrine origin that covers the Bolivian Altiplano from Lake Titicaca to the north for more than 800 km to the Salar de Uyuni in the south. The Lauca Basin is filled by a sequence of some 120 m of mainly upper Miocene to Pliocene elastic and volcaniclastic sediments of lacustrine and alluvial origin. Volcanic rocks, partly pyroelastic, provide useful marker horizons. In the first period (6 4 Ma) of its evolution, the ‘Lago Lauca’ was a shallow ephemeral lake. Evaporites indicate temporarily closed conditions. After 4 Ma the lake changed to a perennial water body surrounded by alluvial plains. In the late Pleistocene and Holocene (2-0 Ma) there was only marginal deposition of alluvial and glacial sediments. The basin formed as a half-graben or by pull-apart between 10 and 15 Ma (tectonic displacement of the basal ignimbrite sequence during the ‘Quechua Phase’) and 6.2 Ma (maximum K/Ar ages of biotites of tuff horizons in the deepest part of the basin). Apart from this early basin formation, there has been surprisingly little displacement during the past 6 Ma close to the Western Cordillera of the Altiplano. Also, climate indicators (pollen, evaporites, sedimentary facies) suggest that an arid climate has existed for the past 6 Ma on the Altiplano. Together, these pieces of evidence indicate the absence of large scale block-faulting, tilt and major uplift during the past 5 6 Ma in this area.

Miocene to Recent history of the western Altiplano in northern Chile revealed by lacustrine sediments of the Lauca Basin (18°15'-18°40'S/69°30'-69°05'W)

NASA Astrophysics Data System (ADS)

Kött, A.; Gaupp, R.; Wörner, G.

The intramontane Lauca Basin at the western margin of the northern Chilean Altiplano lies to the west of and is topographically isolated from the well-known Plio-Pleistocene lake system of fluvio-lacustrine origin that covers the Bolivian Altiplano from Lake Titicaca to the north for more than 800km to the Salar de Uyuni in the south. The Lauca Basin is filled by a sequence of some 120m of mainly upper Miocene to Pliocene clastic and volcaniclastic sediments of lacustrine and alluvial origin. Volcanic rocks, partly pyroclastic, provide useful marker horizons. In the first period (6-4Ma) of its evolution, the 'Lago Lauca' was a shallow ephemeral lake. Evaporites indicate temporarily closed conditions. After 4Ma the lake changed to a perennial water body surrounded by alluvial plains. In the late Pleistocene and Holocene (2-0Ma) there was only marginal deposition of alluvial and glacial sediments. The basin formed as a half-graben or by pull-apart between 10 and 15Ma (tectonic displacement of the basal ignimbrite sequence during the 'Quechua Phase') and 6.2Ma (maximum K/Ar ages of biotites of tuff horizons in the deepest part of the basin). Apart from this early basin formation, there has been surprisingly little displacement during the past 6Ma close to the Western Cordillera of the Altiplano. Also, climate indicators (pollen, evaporites, sedimentary facies) suggest that an arid climate has existed for the past 6Ma on the Altiplano. Together, these pieces of evidence indicate the absence of large scale block-faulting, tilt and major uplift during the past 5-6Ma in this area.

Disentangling natural and anthropogenic signals in lacustrine records: An example from the Ilan Plain, NE Taiwan

NASA Astrophysics Data System (ADS)

Huang, Jyh-Jaan; Huh, Chih-An; Wei, Kuo-Yen; Löwemark, Ludvig; Lin, Shu-Fen; Liao, Wen-Hsuan; Yang, Tien-Nan; Song, Sheng-Rong; Lee, Meng-Yang; Su, Chih-Chieh; Lee, Teh-Quei

2016-11-01

The impact of human activities has been increasing to a degree where humans now outcompete many natural processes. When interpreting environmental and climatic changes recorded in natural archives on historical time scales, it is therefore important to be able to disentangle the relative contribution of natural and anthropogenic processes. Lake Meihua on the Ilan Plain in northeastern Taiwan offers a particularly suitable opportunity to test how human activities known from historical records can be recorded in lacustrine sediment. For this purpose, three cores from Lake Meihua have been studied by a multiproxy approach, providing the first decadal-resolution lacustrine records covering the past 150 years in Taiwan. Profiles of excess 210Pb, 137Cs and 239,240Pu from two short cores (MHL-09-01 and MHL-11-02) allowed a precise chronology to be established. The presence of a yellow, earthy layer with lower levels of organic material coincide with the record of land development associated with the construction of the San-Chin-Gong Temple during AD 1970-1982. Furthermore, in the lower part of the cores, the upwards increasing trend of inc/coh, TOC, TOC/TN, and grain size, coupled with the palynological data (increase of Alnus, Mallotus, Trema and herbs) from the nearby core MHL-5A with radiocarbon chronology, suggest that the area surrounding the lake has been significantly affected by agricultural activities since the arrival of Chinese settlers around AD 1874. In sum, this study demonstrates that this suite of lacustrine sediments in northeastern Taiwan has recorded human activities in agreement with historical documents, and that different human activities will leave distinct sedimentological, geochemical, and palynological signatures in the sedimentary archives. Therefore, multiproxy reconstructions are important to capture the complex nature of human-environmental interactions. A better understanding of the weathering and erosion response to human activities can

Fluorescence spectroscopy reveals accompanying occurrence of ammonium with fulvic acid-like organic matter in a fluvio-lacustrine aquifer of Jianhan Plain.

PubMed

Huang, Shuangbing; Wang, Yanxin; Ma, Teng; Wang, Yanyan; Zhao, Long

2016-05-01

This study is the first to investigate the simultaneous presence of NH4 (+) and fluorescent organic matter components (FOCs) from a fluvio-lacustrine aquifer in Central Jianghan Plain. Sediment, groundwater, and surface water samples were collected for the sediment organic matter extraction, 3D fluorescence spectroscopy characterization, and/or hydrochemical analysis. NH4 (+) and dissolved organic carbon was ubiquitous in the groundwater. The fluorescence spectroscopy revealed good relationships between NH4 (+) and fulvic acid-like components (FALCs) in the groundwater and sediment-extracted organic matter (SEOM) solutions. NH4 (+) also exhibited significant positive correlation with protein-like component (PLC) (p < 0.001), with the stronger in the SEOM solutions than that in groundwater. Comparisons of spectroscopic indices [e.g., humification index (HIX), biological index (BIX), spectra slope (S275-295), and specific UV absorbance (SUVA254)] between the groundwater and SEOM solutions revealed more labile properties of SEOM. This result indicates that the decreasing NH4 (+)-FOCs correlations of groundwater relative to sediments may be attributed to microbial degradation. Factor analysis identifies important factors that cause NH4 (+) occurrence in the groundwater. The accompanying increase of FALC (C1) and NH4-N with the mole concentration of the normalized HCO3 (-)/(Ca(2+)+Mg(2+)) and [H(+)] suggests that couple effects of various biodegradations simultaneously occur in the aquifer, promoting the occurrence of NH4-DOMs.

Pleniglacial sedimentation process reconstruction on laminated lacustrine sediments from lava-dammed Paleolake Alf, West Eifel Volcanic Field (Germany)

NASA Astrophysics Data System (ADS)

Eichhorn, Luise; Pirrung, Michael; Zolitschka, Bernd; Büchel, Georg

2017-09-01

Differentiating between regularly seasonal, irregular and event-based clastic sedimentation is difficult if sedimentation structures resemble and dating methods are imprecise. In this study - clastic light and dark laminae from lava-dammed Paleolake Alf in the Late Pleistocene in the Quaternary West Eifel Volcanic Field are analyzed to clarify how they formed and if they are of annual origin and comparable to assumed periglacial varves from neighboring Lake Holzmaar. Therefore, a multiproxy approach is applied combining sediment thin section analysis which focuses on composition and structure with 14C dates. The results are compared to recently-formed annually-laminated clastic sediments of, e.g., the High Canadian Arctic. Observed sedimentation structures reveal sediment delivery by over- and interflows and deposition from suspension forming two characteristic microfacies: Type I graded laminae and Type II laminae with graded sublayers. Additionally, erosional bases and event deposits indicate episodic underflows. Thus, lamination is potentially seasonal but is significantly veiled by extreme runoff causing erosion and resuspension processes or a mixed water body preventing sediment delivery into the lake basin. However, sedimentation processes between watershed and lake could be reconstructed by comparing recent and paleosediment structures.

Environmental Change recorded in Lacustrine Sediments from Tangra Yumco, Tibetan Plateau, at 16.5 ka cal BP and during the Younger Dryas Chronozone

NASA Astrophysics Data System (ADS)

Henkel, K.; Ahlborn, M.; Haberzettl, T.; Kasper, T.; Daut, G.; Ju, J.; Ma, Q.; Wang, J.; Zhu, L.; Maeusbacher, R.

2013-12-01

In the purpose of understanding the recent climate change on the Tibetan Plateau (TP) and beyond and to allow predictions for future climate scenarios it is imperative to investigate past climate changes. The numerous lake systems on the TP serve as ideal archives for past hydrological changes, which are assumed to be caused by variations in strength and extent of monsoonal air masses. By now, the spatial and temporal monsoonal evolution on the TP is intensively discussed. With the focus on a W-E lake transect on the southern TP we investigate lakes with a multi-dating and multi-proxy analyses approach, which has already been successfully carried out on Nam Co, the easternmost lake of the transect. In this study, we present results from a ~11.5 m long lacustrine sediment record from the terminal lake Tangra Yumco (4,540 m a.s.l., 31°13'N, 86°43'E), representing the center of the transect. Tangra Yumco is the deepest lake recorded on the TP so far. Via a hydro-acoustic survey observed submerged beach berms (45 m below recent lake level) and exposed lake level terraces up to ~205 m above lake level indicate large lake level fluctuations in the past. The record consists of an interbedding of fine grained silty sediments with a lamination of different thicknesses (sub-mm to cm) and partly intercalated blackish sandy layers. Homogeneous areas, which occur especially in the upper two thirds of the profile, represent turbidite deposits. Until now, color- and greyscale-, magnetic susceptibility- and XRF-scanning were applied. For age control 22 14C AMS-radiocarbon measurements were carried out on bulk organic matter. To determine a possible carbon reservoir effect, additional surface sediment samples were measured as well as one modern aquatic plant. The results indicate a reservoir effect of ~2,120 +110/-90 years. Assuming a constant reservoir effect, the base of the record reveals a corrected radiocarbon age of 17,270 +325/-310 cal BP. The sediment accumulation rate is

Sedimentary architecture of a sub-lacustrine debris fan: Eocene Dongying Depression, Bohai Bay Basin, east China

NASA Astrophysics Data System (ADS)

Liu, Jianping; Xian, Benzhong; Wang, Junhui; Ji, Youliang; Lu, Zhiyong; Liu, Saijun

2017-12-01

The sedimentary architectures of submarine/sublacustrine fans are controlled by sedimentary processes, geomorphology and sediment composition in sediment gravity flows. To advance understanding of sedimentary architecture of debris fans formed predominantly by debris flows in deep-water environments, a sub-lacustrine fan (Y11 fan) within a lacustrine succession has been identified and studied through the integration of core data, well logging data and 3D seismic data in the Eocene Dongying Depression, Bohai Bay Basin, east China. Six types of resedimented lithofacies can be recognized, which are further grouped into five broad lithofacies associations. Quantification of gravity flow processes on the Y11 fan is suggested by quantitative lithofacies analysis, which demonstrates that the fan is dominated by debris flows, while turbidity currents and sandy slumps are less important. The distribution, geometry and sedimentary architecture are documented using well data and 3D seismic data. A well-developed depositional lobe with a high aspect ratio is identified based on a sandstone isopach map. Canyons and/or channels are absent, which is probably due to the unsteady sediment supply from delta-front collapse. Distributary tongue-shaped debris flow deposits can be observed at different stages of fan growth, suggesting a lobe constructed by debrite tongue complexes. Within each stage of the tongue complexes, architectural elements are interpreted by wireline log motifs showing amalgamated debrite tongues, which constitute the primary fan elements. Based on lateral lithofacies distribution and vertical sequence analysis, it is proposed that lakefloor erosion, entrainment and dilution in the flow direction lead to an organized distribution of sandy debrites, muddy debrites and turbidites on individual debrite tongues. Plastic rheology of debris flows combined with fault-related topography are considered the major factors that control sediment distribution and fan

Sulfur Geochemistry of a Lacustrine Record from Taiwan Reveals Enhanced Marine Aerosol Input during the Early Holocene

PubMed Central

Ding, Xiaodong; Li, Dawei; Zheng, Liwei; Bao, Hongyan; Chen, Huei-Fen; Kao, Shuh-Ji

2016-01-01

Lacustrine record of marine aerosol input has rarely been documented. Here, we present the sulfur geochemistry during the last deglaciation and early Holocene of a sediment core retrieved from the Dongyuan Lake in southern Taiwan. An unusually high sulfur peak accompanying pyrite presence is observed at 10.5 ka BP. Such high sulfur content in lacustrine record is unusual. The δ34S of sulfur varied from +9.5 to + 17.1‰ with two significant positive shifts at 10.5 and 9.4 ka BP. The sources of sulfur and potential processes involving the sulfur isotope variation including bacterial sulfate reduction, volcanic emissions, in-catchment sulfide oxidation and marine aerosol input are discussed. Enhanced marine aerosol input is the most likely explanation for such sulfur peaks and δ34S shifts. The positive δ34S shifts appeared concurrently with the maximum landslide events over Taiwan resulted from enhanced typhoon activities. The synchronicity among records suggests that increased typhoon activities promoted sea spray, and consequently enhanced the marine aerosol input with 34S-enriched sulfate. Our sulfur geochemistry data revealed sea spray history and marine influence onto terrestrial environment at coastal regions. Wider coverage of spatial-temporal lacustrine sulfur geochemistry record is needed to validate the applicability of sulfur proxy in paleoenvironmental research. PMID:27941864

Identifying, characterizing and predicting spatial patterns of lacustrine groundwater discharge

NASA Astrophysics Data System (ADS)

Tecklenburg, Christina; Blume, Theresa

2017-10-01

Lacustrine groundwater discharge (LGD) can significantly affect lake water balances and lake water quality. However, quantifying LGD and its spatial patterns is challenging because of the large spatial extent of the aquifer-lake interface and pronounced spatial variability. This is the first experimental study to specifically study these larger-scale patterns with sufficient spatial resolution to systematically investigate how landscape and local characteristics affect the spatial variability in LGD. We measured vertical temperature profiles around a 0.49 km2 lake in northeastern Germany with a needle thermistor, which has the advantage of allowing for rapid (manual) measurements and thus, when used in a survey, high spatial coverage and resolution. Groundwater inflow rates were then estimated using the heat transport equation. These near-shore temperature profiles were complemented with sediment temperature measurements with a fibre-optic cable along six transects from shoreline to shoreline and radon measurements of lake water samples to qualitatively identify LGD patterns in the offshore part of the lake. As the hydrogeology of the catchment is sufficiently homogeneous (sandy sediments of a glacial outwash plain; no bedrock control) to avoid patterns being dominated by geological discontinuities, we were able to test the common assumptions that spatial patterns of LGD are mainly controlled by sediment characteristics and the groundwater flow field. We also tested the assumption that topographic gradients can be used as a proxy for gradients of the groundwater flow field. Thanks to the extensive data set, these tests could be carried out in a nested design, considering both small- and large-scale variability in LGD. We found that LGD was concentrated in the near-shore area, but alongshore variability was high, with specific regions of higher rates and higher spatial variability. Median inflow rates were 44 L m-2 d-1 with maximum rates in certain locations going

The lacustrine carbon cycle as illuminated by the waters and sediments of two hydrologically distinct headwater lakes in North-Central Minnesota, U.S.A

USGS Publications Warehouse

Dean, W.E.; Schwalb, A.

2002-01-01

concentrations of Fe and Mn do not build up in the hypolimnion. The concentration of CaCO3 is about 80 wt. % in lower Holocene sediments of both lakes. The lower Holocene sediments in both lakes also contain high concentrations of Fe and Mn, and the lower Holocene sediments of Shingobee are laminated. The waters of both lakes had identical values of ??13C and ??18O during the early Holocene, but the waters of Williams Lake "evolved" during the early Holocene, increasing about 10??? in both ??13C and ??18O. Deposits of lacustrine marl occur as much as seven meters above the present elevation of Williams Lake, the highest of the two lakes. Taken together, these observations suggest that the lakes were once connected to form a larger lake called Lake Willobee with a hypolimnion that was anoxic, at least seasonally.

Lacustrine flow (divers, side scan sonar, hydrogeology, water penetrating radar) used to understand the location of a drowned person

NASA Astrophysics Data System (ADS)

Ruffell, Alastair

2014-05-01

An unusual application of hydrological understanding to a police search is described. The lacustrine search for a missing person provided reports of bottom-water currents in the lake and contradictory indications from cadaver dogs. A hydrological model of the area was developed using pre-existing information from side scan sonar, a desktop hydrogeological study and deployment of water penetrating radar (WPR). These provided a hydrological theory for the initial search involving subaqueous groundwater flow, focused on an area of bedrock surrounded by sediment, on the lake floor. The work shows the value a hydrological explanation has to a police search operation (equally to search and rescue). With hindsight, the desktop study should have preceded the search, allowing better understanding of water conditions. The ultimate reason for lacustrine flow in this location is still not proven, but the hydrological model explained the problems encountered in the initial search.

Equilibrium sampling of polychlorinated biphenyls in River Elbe sediments--Linking bioaccumulation in fish to sediment contamination.

PubMed

Schäfer, Sabine; Antoni, Catherine; Möhlenkamp, Christel; Claus, Evelyn; Reifferscheid, Georg; Heininger, Peter; Mayer, Philipp

2015-11-01

Equilibrium sampling can be applied to measure freely dissolved concentrations (cfree) of hydrophobic organic chemicals (HOCs) that are considered effective concentrations for diffusive uptake and partitioning. It can also yield concentrations in lipids at thermodynamic equilibrium with the sediment (clip⇌sed) by multiplying concentrations in the equilibrium sampling polymer with lipid to polymer partition coefficients. We have applied silicone coated glass jars for equilibrium sampling of seven 'indicator' polychlorinated biphenyls (PCBs) in sediment samples from ten locations along the River Elbe to measure cfree of PCBs and their clip⇌sed. For three sites, we then related clip⇌sed to lipid-normalized PCB concentrations (cbio,lip) that were determined independently by the German Environmental Specimen Bank in common bream, a fish species living in close contact with the sediment: (1) In all cases, cbio,lip were below clip⇌sed, (2) there was proportionality between the two parameters with high R(2) values (0.92-1.00) and (3) the slopes of the linear regressions were very similar between the three stations (0.297; 0.327; 0.390). These results confirm the close link between PCB bioaccumulation and the thermodynamic potential of sediment-associated HOCs for partitioning into lipids. This novel approach gives clearer and more consistent results compared to conventional approaches that are based on total concentrations in sediment and biota-sediment accumulation factors. We propose to apply equilibrium sampling for determining bioavailability and bioaccumulation potential of HOCs, since this technique can provide a thermodynamic basis for the risk assessment and management of contaminated sediments. Copyright © 2015 The Authors. Published by Elsevier Ltd.. All rights reserved.

Fluvial to Lacustrine Facies Transitions in Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Sumner, Dawn Y.; Williams, Rebecca M. E.; Schieber, Juergen; Palucis, Marisa C.; Oehler, Dorothy Z.; Mangold, Nicolas; Kah, Linda C.; Gupta, Sanjeev; Grotzinger, John P.; Grant, John A., III;

Minimum and Maximum Times Required to Obtain Representative Suspended Sediment Samples

NASA Astrophysics Data System (ADS)

Gitto, A.; Venditti, J. G.; Kostaschuk, R.; Church, M. A.

2014-12-01

Bottle sampling is a convenient method of obtaining suspended sediment measurements for the development of sediment budgets. While these methods are generally considered to be reliable, recent analysis of depth-integrated sampling has identified considerable uncertainty in measurements of grain-size concentration between grain-size classes of multiple samples. Point-integrated bottle sampling is assumed to represent the mean concentration of suspended sediment but the uncertainty surrounding this method is not well understood. Here we examine at-a-point variability in velocity, suspended sediment concentration, grain-size distribution, and grain-size moments to determine if traditional point-integrated methods provide a representative sample of suspended sediment. We present continuous hour-long observations of suspended sediment from the sand-bedded portion of the Fraser River at Mission, British Columbia, Canada, using a LISST laser-diffraction instrument. Spectral analysis suggests that there are no statistically significant peak in energy density, suggesting the absence of periodic fluctuations in flow and suspended sediment. However, a slope break in the spectra at 0.003 Hz corresponds to a period of 5.5 minutes. This coincides with the threshold between large-scale turbulent eddies that scale with channel width/mean velocity and hydraulic phenomena related to channel dynamics. This suggests that suspended sediment samples taken over a period longer than 5.5 minutes incorporate variability that is larger scale than turbulent phenomena in this channel. Examination of 5.5-minute periods of our time series indicate that ~20% of the time a stable mean value of volumetric concentration is reached within 30 seconds, a typical bottle sample duration. In ~12% of measurements a stable mean was not reached over the 5.5 minute sample duration. The remaining measurements achieve a stable mean in an even distribution over the intervening interval.

Earthquake imprints on a lacustrine deltaic system: the Kürk Delta along the East Anatolian Fault (Turkey)

NASA Astrophysics Data System (ADS)

Hubert-Ferrari, Aurélia; El-Ouahabi, Meriam; Garcia-Moreno, David; Avsar, Ulas; Altinok, Sevgi; Schmidt, Sabine; Cagatay, Namik

2016-04-01

Delta contains a sedimentary record primarily indicative of water level changes, but particularly sensitive to earthquake shaking, which results generally in soft-sediment-deformation structures. The Kürk Delta adjacent to a major strike-slip fault displays this type of deformation (Hempton and Dewey, 1983) as well as other types of earthquake fingerprints that are specifically investigated. This lacustrine delta stands at the south-western extremity of the Hazar Lake and is bound by the East Anatolian Fault (EAF), which generated earthquakes of magnitude 7 in eastern Turkey. Water level changes and earthquake shaking affecting the Kurk Delta have been reevaluated combining geophysical data (seismic-reflection profiles and side-scan sonar), remote sensing images, historical data, onland outcrops and offshore coring. The history of water level changes provides a temporal framework regarding the sedimentological record. In addition to the commonly soft-sediment-deformation previously documented, the onland outcrops reveal a record of deformation (faults and clastic dykes) linked to large earthquake-induced liquefactions. The recurrent liquefaction structures can be used to obtain a paleoseismological record. Five event horizons were identified that could be linked to historical earthquakes occurring in the last 1000 years along the EAF. Sedimentary cores sampling the most recent subaqueous sedimentation revealed the occurrence of another type of earthquake fingerprint. Based on radionuclide dating (137Cs and 210Pb), two major sedimentary events were attributed to the 1874-1875 earthquake sequence along the EAF. Their sedimentological characteristics were inferred based X-ray imagery, XRD, LOI, grain-size distribution, geophysical measurements. The events are interpreted to be hyperpycnal deposits linked to post-seismic sediment reworking of earthquake-triggered landslides. A time constraint regarding this sediment remobilization process could be achieved thanks to

Organochlorine pesticides in lacustrine sediments and tilapias of Metztitlan, Hidalgo, Mexico.

PubMed

Fernández-Bringas, Laura M; Ponce-Vélez, Guadalupe; Calva, Laura G; Salgado-Ugarte, Isaías Hazamamberth; Botello, Alfonso V; Díaz González, Gilberto

2008-09-01

The organochlorine pesticides (OP) are very stable molecules, due to this stability; they are very resistant in the environment and highly related to fat tissues with a wide diffusion property and an average time life higher then 10 years. We studied sediments (November 2001, April and June 2002) and organisms collected in April and July (2002) from the lacustric zone of Metzitlán, Hidalgo, Mexico. The analysis was performed according to UNEP/IAEA (1982) (sediments) and UNEP/FAO/IOC/IAEA (1986) (organisms) methods. Three chemical families of organochlorine pesticides were identified and analyzed to determine posible toxicological risk. The principal organochlorine compounds found in sediments were gamma-HCH, delta-HCH, p,p'-DDT and the endosulfan sulfate; these xenobiotics come from agriculture lands near the river and lake, used intensively, and most probably carried by the rain and rain flows into the main water body. In the tilapias tissue, p,p'-DDD y delta-HCH were detected. The average concentrations of organochlorine pesticides in sediments were within the internacional limits for freshwater benthonic fauna, although lindane (gamma-HCH) was near the limit. The fish were above the criteria established in the local legislation (NOM-027-SSA1-1993 y NOM-028-SSA1-1993).

Unique phenomenon of the accumulation of terrestrial metal iron particles in lacustrine deposits: Zhombolok volcanic region, East Sayan

NASA Astrophysics Data System (ADS)

Pechersky, D. M.; Kazanskii, A. Yu.; Markov, G. P.; Tselmovich, V. A.; Shchetnikov, A. A.

2018-01-01

The native iron particles that were previously detected by thermomagnetic and microprobe analyses in the sediments of different age in many regions of the world are of extraterrestrial origin. The similarity in the compositions, grain shapes, and sizes observed in the extraterrestrial and terrestrial particles of native iron testifies to the common production conditions of iron particles during the formation of planets. In this paper, the single finding of terrestrial iron in the lacustrine sediments of the Zhombolok volcanic region, East Sayan, is discussed. The uniqueness of the results indicates that the spatial distribution of the particles of native iron is limited to a fairly narrow area around their source—volcanic eruption or/and the fall of a large meteorite.

A 27cal ka biomarker-based record of ecosystem changes from lacustrine sediments of the Chihuahua Desert of Mexico

NASA Astrophysics Data System (ADS)

Chávez-Lara, C. M.; Holtvoeth, J.; Roy, P. D.; Pancost, R. D.

2018-07-01

Hydroclimate variation of the northwest Mexico during the late Pleistocene and Holocene is an active area of debate, with uncertainty in the nature and sources of precipitation. Previous research has inferred the influences of winter storms, summer monsoonal rain and autumn tropical cyclones. The impacts on regional and local ecosystems, however, are not well constrained. Here, we investigate the response of lacustrine and terrestrial habitats of the Santiaguillo Basin in the Chihuahua Desert (Mexico) to hydrological changes occurring since the late last glacial. Biomarkers from the sediments reflect variable input of organic matter (OM) from algal and bacterial biomass, aquatic microfauna and surrounding vegetation, revealing distinct stages of ecosystem adaption over the last 27 cal ka. Based on previously published and new data, we show that a perennial productive lake was present during the late glacial and it persisted until 17.5 cal ka BP. Coinciding with Heinrich event 1, OM supply from deteriorating wetland soils may have been caused by early dry conditions. Further phases of increasing aridity and a shrinking water body drove changing OM quality and biomarker composition during the early and mid-Holocene. A pronounced shift in biomarker distributions at 4 cal ka BP suggests that the supply of plant litter from resinous trees and grasses increased, likely reflecting the establishment of modern vegetation. Our results illustrate the potential of biomarker applications in the area, adding to the evidence of hydroclimate variability and enabling reconstructions of local ecosystem dynamics.

The effects of sample scheduling and sample numbers on estimates of the annual fluxes of suspended sediment in fluvial systems

USGS Publications Warehouse

Horowitz, Arthur J.; Clarke, Robin T.; Merten, Gustavo Henrique

2015-01-01

Since the 1970s, there has been both continuing and growing interest in developing accurate estimates of the annual fluvial transport (fluxes and loads) of suspended sediment and sediment-associated chemical constituents. This study provides an evaluation of the effects of manual sample numbers (from 4 to 12 year−1) and sample scheduling (random-based, calendar-based and hydrology-based) on the precision, bias and accuracy of annual suspended sediment flux estimates. The evaluation is based on data from selected US Geological Survey daily suspended sediment stations in the USA and covers basins ranging in area from just over 900 km2 to nearly 2 million km2 and annual suspended sediment fluxes ranging from about 4 Kt year−1 to about 200 Mt year−1. The results appear to indicate that there is a scale effect for random-based and calendar-based sampling schemes, with larger sample numbers required as basin size decreases. All the sampling schemes evaluated display some level of positive (overestimates) or negative (underestimates) bias. The study further indicates that hydrology-based sampling schemes are likely to generate the most accurate annual suspended sediment flux estimates with the fewest number of samples, regardless of basin size. This type of scheme seems most appropriate when the determination of suspended sediment concentrations, sediment-associated chemical concentrations, annual suspended sediment and annual suspended sediment-associated chemical fluxes only represent a few of the parameters of interest in multidisciplinary, multiparameter monitoring programmes. The results are just as applicable to the calibration of autosamplers/suspended sediment surrogates currently used to measure/estimate suspended sediment concentrations and ultimately, annual suspended sediment fluxes, because manual samples are required to adjust the sample data/measurements generated by these techniques so that they provide depth-integrated and cross

[Sediment-water flux and processes of nutrients and gaseous nitrogen release in a China River Reservoir].

PubMed

Chen, Zhu-hong; Chen, Neng-wang; Wu, Yin-qi; Mo, Qiong-li; Zhou, Xing-peng; Lu, Ting; Tian, Yun

2014-09-01

The key processes and fluxes of nutrients (N and P) and gaseous N (N2 and N2O) across the sediment-water interface in a river reservoir (Xipi) of the Jiulong River watershed in southeast China were studied. Intact core sediment incubation of nutrients exchange, in-situ observation and lab incubation of excess dissolved N2 and N2O (products of nitrification, denitrification and Anammox), and determination of physiochemical and microbe parameters were carried out in 2013 for three representative sites along the lacustrine zone of the reservoir. Results showed that ammonium and phosphate were generally released from sediment to overlying water [with averaged fluxes of N (479.8 ± 675.4) mg. (m2. d)-1 and P (4. 56 ± 0.54) mg. (m2 d) -1] , while nitrate and nitrite diffused into the sediment. Flood events in the wet season could introduce a large amount of particulate organic matter that would be trapped by the dam reservoir, resulting in the high release fluxes of ammonium and phosphate observed in the following low-flow season. No clear spatial variation of sediment nutrient release was found in the lacustrine zone of the reservoir. Gaseous N release was dominated by excess dissolved N2 (98% of total), and the N2 flux from sediment was (15.8 ± 12. 5) mg (m2. d) -1. There was a longitudinal and vertical variation of excess dissolved N2, reflecting the combined results of denitrification and Anammox occurring in anoxic sediment and fluvial transport. Nitrification mainly occurred in the lower lacustrine zone, and the enrichment of N2O was likely regulated by the ratio of ammonium to DIN in water.

High-resolution seismic stratigraphy of an Holocene lacustrine delta in western Lake Geneva (Switzerland)

USGS Publications Warehouse

Baster, I.; Girardclos, S.; Pugin, A.; Wildi, W.

2003-01-01

A high-resolution seismic survey was conducted in western Lake Geneva on a small delta formed by the Promenthouse, the Asse and the Boiron rivers. This dataset provides information on changes in the geometry and sedimentation patterns of this delta from Late-glacial to Present. The geometry of the deposits of the lacustrine delta has been mapped using 300-m spaced grid lines acquired with a 12 kHz Echosounder subbottom profiler. A complete three dimensional image of the sediment architecture was reconstructed through seismic stratigraphic analysis. Six different delta lobes have been recognized in the prodelta area. Depositional centers and lateral extension of the delta have changed through time, indicating migration and fluctuation of river input as well as changes in lake currents and wind regime from the time of glacier retreat to the Present. The delta slope is characterized by a high instability causing stumps developing and by the accumulation of biogenic gas that prevents seismic penetration.

Oligocene lacustrine tuff facies, Abu Treifeya, Cairo-Suez Road, Egypt

NASA Astrophysics Data System (ADS)

Abdel-Motelib, Ali; Kabesh, Mona; El Manawi, Abdel Hamid; Said, Amir

2015-02-01

Field investigations in the Abu Treifeya area, Cairo-Suez District, revealed the presence of Oligocene lacustrine volcaniclastic deposits of lacustrine sequences associated with an Oligocene rift regime. The present study represents a new record of lacustrine zeolite deposits associated with saponite clay minerals contained within reworked clastic vitric tuffs. The different lithofacies associations of these clastic sequences are identified and described: volcaniclastic sedimentary facies represent episodic volcaniclastic reworking, redistribution and redeposition in a lacustrine environment and these deposits are subdivided into proximal and medial facies. Zeolite and smectite minerals are mainly found as authigenic crystals formed in vugs or crusts due to the reaction of volcanic glasses with saline-alkaline water or as alteration products of feldspars. The presence of abundant smectite (saponite) may be attributed to a warm climate, with alternating humid and dry conditions characterised by the existence of kaolinite. Reddish iron-rich paleosols record periods of non-deposition intercalated with the volcaniclastic tuff sequence.

Early cretaceous rift sediments of the Gabon-Congo margin: lithology and organic matter; tectonic and paleogeothermal evolution

NASA Astrophysics Data System (ADS)

Robert, P.; Yapaudjian, L.

The active troughs of the western Gabon-Congo margin which are part of the South Atlantic rift contain a Neocomian to barremian-aged fluvial-lacustrine series. The lithological sequence of interbedded clastic and pelitic formations constitutes a well-defined cycle. This cycle is divided into: a fluvial or piedmont stage, a lacustrine turbidite-stage corresponding to the distension paroxysm of the basin, and finally, a lacustrine deltaic stage of infilling and tectonic quiescence. The organic matter included in the shale layers is abundant and originates mainly from lacustrine Botryococcus algae and their alteration and secretion products. The geothermal history of the basin, demonstrated by the evolution of the organic matter indicates a strong hyperthermy located in the active, more subsiding part of the basin, and contemporaneous with sedimentation.

The Index to Marine and Lacustrine Geological Samples (IMLGS): Linking Digital Data to Physical Samples for the Marine Community

NASA Astrophysics Data System (ADS)

Stroker, K. J.; Jencks, J. H.; Eakins, B.

2016-12-01

The Index to Marine and Lacustrine Geological Samples (IMLGS) is a community designed and maintained resource enabling researchers to locate and request seafloor and lakebed geologic samples curated by partner institutions. The Index was conceived in the dawn of the digital age by representatives from U.S. academic and government marine core repositories and the NOAA National Geophysical Data Center, now the National Centers for Environmental Information (NCEI), at a 1977 meeting convened by the National Science Foundation (NSF). The Index is based on core concepts of community oversight, common vocabularies, consistent metadata and a shared interface. The Curators Consortium, international in scope, meets biennially to share ideas and discuss best practices. NCEI serves the group by providing database access and maintenance, a list server, digitizing support and long-term archival of sample metadata, data and imagery. Over three decades, participating curators have performed the laborious task of creating and contributing metadata for over 205,000 sea floor and lake-bed cores, grabs, and dredges archived in their collections. Some partners use the Index for primary web access to their collections while others use it to increase exposure of more in-depth institutional systems. The IMLGS has a persistent URL/Digital Object Identifier (DOI), as well as DOIs assigned to partner collections for citation and to provide a persistent link to curator collections. The Index is currently a geospatially-enabled relational database, publicly accessible via Web Feature and Web Map Services, and text- and ArcGIS map-based web interfaces. To provide as much knowledge as possible about each sample, the Index includes curatorial contact information and links to related data, information and images : 1) at participating institutions, 2) in the NCEI archive, and 3) through a Linked Data interface maintained by the Rolling Deck to Repository R2R. Over 43,000 International GeoSample

Secular and environmental constraints on the occurrence of dinosterane in sediments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Summons, R.E.; Boreham, C.J.; Thomas, J.

1992-06-01

The distribution patterns of sedimentary A-ring methylated steranes have changed markedly over geological time. Although dinosterane and its isomer 24-ethyl-4{alpha}-methylcholestane have been tentatively identified in three Proterozoic rock units, they are either not detectable or occur in low abundance relative to 3-methyl steranes throughout most of the Palaeozoic. Between Permian and middle Triassic times (260-220 Ma ago), 4-methyl sterane abundances in marine sediments increased markedly. The presence of dinosterane in some middle Triassic marine sediments is contemporaneous with the appearance of fossil cysts of uncontested dinoflagellate affinity. 4-Methyl steranes, including dinosterane or their precursor sterenes and sterols, then show amore » continuous presence, often in high abundance, in marine sediments from the late Triassic through to the present day. Assemblages of 4-methyl steranes and their precursors, but with dinosterane absent or in low relative abundance, are often the predominant steroids in lacustrine sediments in the Cainozoic. Dinosterane appears to arise predominantly from marine dinoflagellates and, as a consequence, is a useful biological marker for Mesozoic and Cainozoic marine organic matter. The isomer 24-ethyl-4{alpha}-methylcholestane is likely to have multiple origins although its very high abundance in Tertiary lacustrine sediments and oils, compared to older materials, suggests that dinoflagellates could also be the source in these cases.« less

Rock-magnetic proxies of wind intensity and dust since 51,200 cal BP from lacustrine sediments of Laguna Potrok Aike, southeastern Patagonia

NASA Astrophysics Data System (ADS)

Lisé-Pronovost, Agathe; St-Onge, Guillaume; Gogorza, Claudia; Haberzettl, Torsten; Jouve, Guillaume; Francus, Pierre; Ohlendorf, Christian; Gebhardt, Catalina; Zolitschka, Bernd

2015-02-01

The sedimentary archive from Laguna Potrok Aike is the only continuous record reaching back to the last Glacial period in continental southeastern Patagonia. Located in the path of the Southern Hemisphere westerly winds and in the source region of dust deposited in Antarctica during Glacial periods, southern Patagonia is a vantage point to reconstruct past changes in aeolian activity. Here we use high-resolution rock-magnetic and physical grain size data from site 2 of the International Continental scientific Drilling Program (ICDP) Potrok Aike maar lake Sediment Archive Drilling prOject (PASADO) in order to develop magnetic proxies of dust and wind intensity at 52°S since 51,200 cal BP. Rock-magnetic analysis indicates the magnetic mineral assemblage is dominated by detrital magnetite. Based on the estimated flux of magnetite to the lake and comparison with distal dust records from the Southern Ocean and Antarctica, kLF is interpreted as a dust indicator in the dust source of southern Patagonia at the millennial time scale, when ferrimagnetic grain size and coercivity influence are minimal. Comparison to physical grain-size data indicates that the median destructive field of isothermal remanent magnetization (MDFIRM) mostly reflects medium to coarse magnetite bearing silts typically transported by winds for short-term suspension. Comparison with wind-intensity proxies from the Southern Hemisphere during the last Glacial period and with regional records from Patagonia since the last deglaciation including marine, lacustrine and peat bog sediments as well as speleothems reveals similar variability with MDFIRM up to the centennial time scale. MDFIRM is interpreted as a wind-intensity proxy independent of moisture changes for southeastern Patagonia, with stronger winds capable of transporting coarser magnetite bearing silts to the lake.

In-situ monitoring of deformation of clayey and volcanic sequences in the lacustrine plain of Iztapalapa, Mexico City

NASA Astrophysics Data System (ADS)

Carreon-Freyre, D.; Cerca, M.; Barrientos, B.; Gutierrez, R.; Blancas, D.

2012-12-01

Major cities of Central Mexico with lowering of land elevation problems are located in inter-volcanic and fault bounded basins within the central Trans-Mexican Volcanic Belt (TMVB). The most representative and studied case of ground deformation is Mexico City, where the Iztapalapa Municipality presents the highest population density. This area is located over the geological contact between the "Sierra de Santa Catarina" volcanic range and a lacustrine plain. Filling of lacustrine basins includes silty and clayey sediments as well as pyroclastic deposits (coarse and fine grained) and volcanic rocks layers. We used Ground Penetrating Radar (GPR) and MASW prospection to evaluate contrasts in the physical properties of fine grained soils and identify geometry of the deformational features and implemented a mechanical system for in situ monitoring in fractured sites. Deformational features in this basin reflect an interplay between the geological history (depositional conditions), load history, seismic activity, and faulting. Plastic mechanical behaviour predominates in these clayey sediments and differential deformation locally triggers brittle fracturing and/or subsidence of the surface. In this work we present the results of monitoring and characterization of ground deformation and fracturing in different sequences, our results show a dynamic interplay between the mechanisms of ground fracturing and the stress history of sedimentary sequences. Relating the mechanical behaviour of the studied sequences with variations of physical and geological properties should be taken into account to estimate land level lowering and risk of fracturing for urban development planning.

Mesozoic lacustrine system in the Parnaíba Basin, northeastern Brazil: Paleogeographic implications for west Gondwana

NASA Astrophysics Data System (ADS)

Cardoso, Alexandre Ribeiro; Nogueira, Afonso César Rodrigues; Abrantes, Francisco Romério; Rabelo, Cleber Eduardo Neri

2017-03-01

The fragmentation of the West Gondwana during Early Triassic to Cretaceous was marked by intense climatic changes, concomitant with the establishment of extensive desertic/lacustrine systems. These deposits succeeded the emplacement and extrusion of lava flows, related to the pre-rift phase and initial opening of the Equatorial Atlantic Ocean. The thermal phase is recorded in the Upper Jurassic-Lower Cretaceous Pastos Bons Formation, exposed mainly in southeast parts of the Parnaíba Basin, Northeastern Brazil. The sedimentary facies of this unit were grouped in two facies associations (FA), representative of a shallow lacustrine system, influenced by episodic hyperpycnal and oscillatory flows. Central lake facies association (FA1) is composed by laminated mudstone (Ml), sandstone/mudstone rhythmite (S/Mr) and sandstone with even-parallel lamination (Sel). Flysch-like delta front (FA2) consists in sandstones with wave structures (Sw), sandstones with even-parallel stratification (Ses), massive sandstones (Sm), sandstones with soft-sediment deformation structures (Sd) and laminated mudstones (Ml). FA1 was deposited in the deepest portions of the lake, characterized by low energy, episodically disturbed by siliciclastic influx. FA2 presents sandy deposits generated by unconfined flow, probably fed by ephemeral stream flows that generated thickening upward of tabular sandstone beds. The progressive filling of the lake resulted in recurrent shoaling up of the water level and reworking by wave action. The installation of Pastos Bons lakes was controlled by thermal subsidence, mainly in restricted depocenters. The siliciclastic fluvial inflow can be related to the adjacent humid desertic facies, formed under climatic attenuation, typical of post-Triassic period, with reduced biological activity. Smectite and abundant feldspars, in lacustrine facies, corroborate an arid climate, with incipient chemical weathering. The new facies and stratigraphic data present in this

Sources of core and intact branched tetraether membrane lipids in the lacustrine environment: Anatomy of Lake Challa and its catchment, equatorial East Africa

NASA Astrophysics Data System (ADS)

Buckles, Laura K.; Weijers, Johan W. H.; Verschuren, Dirk; Sinninghe Damsté, Jaap S.

2014-09-01

The MBT/CBT palaeotemperature proxy uses the distribution of branched glycerol dialkyl glycerol tetraethers (brGDGTs), membrane lipids that are supposed to derive from soil bacteria, to reconstruct mean annual air temperature (MAAT). Applied successfully in coastal marine sediments, its extension to lake-sediment records with potentially high time resolution would greatly expand its utility. Over the last years, however, studies have indicated the presence of additional sources of brGDGTs within lake systems. To constrain the factors influencing the MBT/CBT palaeotemperature proxy in lakes, detailed investigation of brGDGT fluxes in a modern lake system is necessary to identify their potential sources. This study concentrates on Lake Challa, a permanently stratified crater lake in equatorial East Africa with limited catchment area. An almost 3-year time series of approximately monthly samples of settling particles, supplemented with a depth profile of suspended particulate matter (SPM) and sets of profundal surface-sediment and catchment soil samples, were analysed for both the 'living' intact polar lipids (IPLs) and 'fossil' core lipids (CLs) of GDGTs. We found that brGDGTs are produced in oxic, suboxic and anoxic zones of the water column, and in substantial amounts compared to influxes from catchment soils. Additional in situ production within the lake sediments is most probable, but cannot be definitely confirmed at this time. These lacustrine brGDGTs display a different response to temperature variation than soil-derived brGDGTs, signifying either a different physiological adaptation to changing conditions within the water column and/or a different composition of the respective bacterial communities. Using this specific relationship with temperature, a local calibration based on brGDGT distributions in SPM generates relatively accurate water temperature estimates from settling particles but fails for surface sediments.

Culturing of the first 37:4 predominant lacustrine haptophyte: Geochemical, biochemical, and genetic implications

NASA Astrophysics Data System (ADS)

Toney, Jaime L.; Theroux, Susanna; Andersen, Robert A.; Coleman, Annette; Amaral-Zettler, Linda; Huang, Yongsong

2012-02-01

Long chain alkenones (LCAs) are potential biomarkers for quantitative paleotemperature reconstructions from lacustrine environments. However, progress in this area has been hindered, because the conditions necessary for the growth of haptophytes responsible for alkenone distributions in lake sediments: the predominance of C 37:4 LCA are not known. Here we report the first enrichment culturing of a novel haptophyte phylotype (Hap-A) from Lake George, ND that produces predominantly C 37:4-LCA. Hap-A was enriched from its resting phase collected from deep sediments rather than from water column samples. In contrast, enrichments from near surface water yielded a different haptophyte phylotype (Hap-B), closely related to Chrysotila lamellosa and Pseudoisochrysis paradoxa, which does not display C 37:4-LCA predominance (similar enrichments have been reported previously). The LCA profile in sediments resembles that of enrichments containing Hap-A, suggesting that Hap-A is the dominant alkenone producer of the sedimentary LCAs. In enrichments, increased lighting appeared to be crucial for triggering alkenone production. Both U37K and U38K indices show a promising, positive relationship with temperature for Hap-A in enrichments, but the offset from the environmental calibration suggests that other factors (e.g., the growth stage or nutrients) may influence the absolute U37K value. Based on 18S rRNA gene analyses, several lakes from the Northern Great Plains, as well as Pyramid Lake, NV and Tso Ur, Tibetan Plateau, China contain the same two haptophyte phylotypes. Analysis of surface sediment from the Great Plains lakes show the Hap-A-type LCA distribution, whereas Pyramid and Tso Ur show the Hap-B type distribution. Waters of the Great Plain lakes are dominated by sulfate ions, whereas those Pyramid and Tso Ur are dominated by carbonate ions, suggesting that the sulfate to carbonate ratio may be a determining factor for the dominance of the Hap-A and Hap-B phylotypes in

Lake Qinghai sediment geochemistry linked to hydroclimate variability since the last glacial

NASA Astrophysics Data System (ADS)

Jin, Zhangdong; An, Zhisheng; Yu, Jimin; Li, Fuchun; Zhang, Fei

2015-08-01

Geochemistry of basin sediments from semi-arid regions is valuable to understand past hydroclimatic changes. Here, we investigate the links of sedimentary geochemistry (Rb, Sr, Ca/Zr, TOC, and %CaCO3), carbonate mineralogy and ostracod shell δ18O of Lake Qinghai, a basin proximal to major dust production centers at mid-latitudes of the Northern Hemisphere, to changes in depositional conditions and hydroclimate during the past 32 ka. Surface lacustrine sediments are characterized by low-Rb, high-Sr, low-Rb/Sr, high-%CaCO3 and high-Ca/Zr values, in contrast to the chemical compositions of eolian loess (high-Rb, low-Sr, high-Rb/Sr, low-%CaCO3, and low-Ca/Zr). A direct comparison of soluble Ca and Sr in two short cores with instrumental water discharge data suggests that lacustrine precipitates in Lake Qinghai are dominated by authigenic aragonite formed under Ca2+-limited water conditions, and that the accumulation rate of aragonite dominantly depends on solute fluxes into the lake during the rainy seasons (late May to September). Our high-resolution down-core records show that sediments during the last glacial (∼32-19.8 ka) had high-Rb, low-Sr, low-%CaCO3, and low-Ca/Zr, indicating eolian dust (loess) accumulation in a desiccated basin under dry glacial conditions, further supported by grain size and pollen results. This type of sedimentation was maintained during the last deglacial (∼19.8-11.5 ka), but interrupted by episodic lacustrine precipitates with high-Sr, high-%CaCO3, high-Ca/Zr, and low-Rb. At ∼11.5 ka, sedimentary Rb/Sr, Ca/Zr, %CaCO3 and TOC show dramatic and permanent changes, implying an abrupt shift in the atmospheric circulation at the onset of the Holocene in the Lake Qinghai region. Lacustrine precipitates have persisted throughout the Holocene with a maximum during the early to mid-Holocene (∼10.5-8.0 ka). Since ∼8.0 ka, the gradual and significant decreases in aragonite and Sr accumulations in tandem with increasing dust deposit and

Time-integrated sampling of fluvial suspended sediment: a simple methodology for small catchments

NASA Astrophysics Data System (ADS)

Phillips, J. M.; Russell, M. A.; Walling, D. E.

2000-10-01

Fine-grained (<62·5 µm) suspended sediment transport is a key component of the geochemical flux in most fluvial systems. The highly episodic nature of suspended sediment transport imposes a significant constraint on the design of sampling strategies aimed at characterizing the biogeochemical properties of such sediment. A simple sediment sampler, utilizing ambient flow to induce sedimentation by settling, is described. The sampler can be deployed unattended in small streams to collect time-integrated suspended sediment samples. In laboratory tests involving chemically dispersed sediment, the sampler collected a maximum of 71% of the input sample mass. However, under natural conditions, the existence of composite particles or flocs can be expected to increase significantly the trapping efficiency. Field trials confirmed that the particle size composition and total carbon content of the sediment collected by the sampler were representative statistically of the ambient suspended sediment.

Fluvial/lacustrine diagenesis: Significance for hydrocarbon production and entrapment in the carboniferous Albert Fm, Moncton basin, NB

DOE Office of Scientific and Technical Information (OSTI.GOV)

Noble, J.P.A.; Chowdhury, A.H.; Yu, H.

1996-12-31

The Carboniferous Horton Group Albert Formation sediments include lacustrine source-rock oil shales and fluvial porous reservoir sandstones. The petrography, stable isotopes, fluid inclusions, cathodoluminescence and mirror/trace element chemistry of these sandstones are used to establish the diagenetic history and controlling factors. Early diagenetic calcite, quartz and albite cements with minor chlorite and kaolinite are variably present and related to depositional mineralogy and lake levels winch controlled the porewater chemistry. Antitaxial veins occurring preferentially in shales are shown, from heavy {delta}C{sup 13} values and fluid inclusions, to be related to methanogenesis in overpressured zones at shallow depths. Later burial calcite andmore » extensive albitisation are related to mineral reactions during the phase of rapid subsidence at temperatures of 80{degrees} to 150{degrees} in the deepest segment of the basin, together with significant dissolution of carbonates and feldspars related mainly to organic acids generated by organic maturation processes. Mass balance calculations indicate that not enough organic matter was present to account for all the estimated secondary porosity and some evidence suggests that reactions between kaolinite and calcite/ankerite to produce chlorite, and mixed layer illite-smectite ordering reactions, produced significant secondary porosity. Burial history reconstructions and thermal modelling of the Albert Fm. sediments using Arrhenius type maturity models and reflectance and rock-eval data suggest locally variable maturation and reservoir production related to the locally different fault tectonic histories characteristic of strike-slip lacustrine segmented basins. The Horton depositional cycle was followed by major dextral transpression with local faulting and inversion and vein cementation.« less

Fluvial/lacustrine diagenesis: Significance for hydrocarbon production and entrapment in the carboniferous Albert Fm, Moncton basin, NB

DOE Office of Scientific and Technical Information (OSTI.GOV)

Noble, J.P.A.; Chowdhury, A.H.; Yu, H.

1996-01-01

The Carboniferous Horton Group Albert Formation sediments include lacustrine source-rock oil shales and fluvial porous reservoir sandstones. The petrography, stable isotopes, fluid inclusions, cathodoluminescence and mirror/trace element chemistry of these sandstones are used to establish the diagenetic history and controlling factors. Early diagenetic calcite, quartz and albite cements with minor chlorite and kaolinite are variably present and related to depositional mineralogy and lake levels winch controlled the porewater chemistry. Antitaxial veins occurring preferentially in shales are shown, from heavy [delta]C[sup 13] values and fluid inclusions, to be related to methanogenesis in overpressured zones at shallow depths. Later burial calcite andmore » extensive albitisation are related to mineral reactions during the phase of rapid subsidence at temperatures of 80[degrees] to 150[degrees] in the deepest segment of the basin, together with significant dissolution of carbonates and feldspars related mainly to organic acids generated by organic maturation processes. Mass balance calculations indicate that not enough organic matter was present to account for all the estimated secondary porosity and some evidence suggests that reactions between kaolinite and calcite/ankerite to produce chlorite, and mixed layer illite-smectite ordering reactions, produced significant secondary porosity. Burial history reconstructions and thermal modelling of the Albert Fm. sediments using Arrhenius type maturity models and reflectance and rock-eval data suggest locally variable maturation and reservoir production related to the locally different fault tectonic histories characteristic of strike-slip lacustrine segmented basins. The Horton depositional cycle was followed by major dextral transpression with local faulting and inversion and vein cementation.« less

Direct sampling during multiple sediment density flows reveals dynamic sediment transport and depositional environment in Monterey submarine canyon

NASA Astrophysics Data System (ADS)

Maier, K. L.; Gales, J. A.; Paull, C. K.; Gwiazda, R.; Rosenberger, K. J.; McGann, M.; Lundsten, E. M.; Anderson, K.; Talling, P.; Xu, J.; Parsons, D. R.; Barry, J.; Simmons, S.; Clare, M. A.; Carvajal, C.; Wolfson-Schwehr, M.; Sumner, E.; Cartigny, M.

2017-12-01

Sediment density flows were directly sampled with a coupled sediment trap-ADCP-instrument mooring array to evaluate the character and frequency of turbidity current events through Monterey Canyon, offshore California. This novel experiment aimed to provide links between globally significant sediment density flow processes and their resulting deposits. Eight to ten Anderson sediment traps were repeatedly deployed at 10 to 300 meters above the seafloor on six moorings anchored at 290 to 1850 meters water depth in the Monterey Canyon axial channel during 6-month deployments (October 2015 - April 2017). Anderson sediment traps include a funnel and intervalometer (discs released at set time intervals) above a meter-long tube, which preserves fine-scale stratigraphy and chronology. Photographs, multi-sensor logs, CT scans, and grain size analyses reveal layers from multiple sediment density flow events that carried sediment ranging from fine sand to granules. More sediment accumulation from sediment density flows, and from between flows, occurred in the upper canyon ( 300 - 800 m water depth) compared to the lower canyon ( 1300 - 1850 m water depth). Sediment accumulated in the traps during sediment density flows is sandy and becomes finer down-canyon. In the lower canyon where sediment directly sampled from density flows are clearly distinguished within the trap tubes, sands have sharp basal contacts, normal grading, and muddy tops that exhibit late-stage pulses. In at least two of the sediment density flows, the simultaneous low velocity and high backscatter measured by the ADCPs suggest that the trap only captured the collapsing end of a sediment density flow event. In the upper canyon, accumulation between sediment density flow events is twice as fast compared to the lower canyon; it is characterized by sub-cm-scale layers in muddy sediment that appear to have accumulated with daily to sub-daily frequency, likely related to known internal tidal dynamics also measured

Reconstruction of a saline, lacustrine carbonate system (Priabonian, St-Chaptes Basin, SE France): Depositional models, paleogeographic and paleoclimatic implications

NASA Astrophysics Data System (ADS)

Lettéron, Alexandre; Hamon, Youri; Fournier, François; Séranne, Michel; Pellenard, Pierre; Joseph, Philippe

2018-05-01

A 220-m thick carbonate-dominated succession has been deposited in shallow-water, saline lake environments during the early to middle Priabonian (MP17A-MP18 mammal zones) in the Saint-Chaptes Basin (south-east France). The palaeoenvironmental, paleoclimatic and palaeogeographic significance of such saline lake carbonates has been deciphered on the basis of a multi-proxy analyses including: 1) depositional and diagenetic features; 2) biological components (molluscs, benthic foraminifera, characean gyrogonites, spores and pollens); 3) carbon and oxygen stable isotopes; 4) trace elements; and 5) clay mineralogy. Five stages of lacustrine system evolution have been identified: 1) fresh-water closed lake under dry climate (unit U1); 2) fresh to brackish water lacustrine deltaic system with a mixed carbonate-siliciclastic sedimentation under relatively wet climatic conditions (unit U2); 3) salt-water lacustrine carbonate system under humid climatic setting (unit U3); 4) evaporitic lake (unit U4); and 5) closed lake with shallow-water carbonate sedimentation under subtropical to Mediterranean climate with dry seasons (unit U5). Upper Eocene aridification is evidenced to have started as early as the earliest Priabonian (unit U1: MP17A mammal zone). A change from humid to dryer climatic conditions is recorded between units U3 and U4. The early to middle Priabonian saline lake is interpreted as an athalassic (inland) lake that have been transiently connected with neighboring salt lakes influenced by seawater and/or fed with sulfates deriving from recycling of evaporites. Maximum of connection with neighboring saline lakes (Mormoiron Basin, Camargue and Central grabens, Hérault Basin) likely occurred during unit U3 and at the base of unit U5. The most likely sources of salts of these adjacent basins are: 1) Triassic evaporites derived from salt-diapirs (Rhône valley) or from paleo-outcrops located east of the Durance fault or offshore in the Gulf of Lion; or 2) marine

Procedures for Handling and Chemical Analysis of Sediment and Water Samples,

DTIC Science & Technology

1981-05-01

silts. Particularly suitable for studies of the sediment/ water interface, for studies on depositonal sediment structures. Al pi ne- ravity Cores of 2 m...adverse water quality impacts would occur. Elemental partitioning or sedimentation fractionation studies are the most complex of the tests considered...8217 water %nd blend the core or dredge sample. Place a{js roximalel-i 00 cc of’ the blended sample in an oxygen-free, poly - ca rbor’~ [ ’-l centrifuge bottle

Comparability of river suspended-sediment sampling and laboratory analysis methods

USGS Publications Warehouse

Groten, Joel T.; Johnson, Gregory D.

2018-03-06

Accurate measurements of suspended sediment, a leading water-quality impairment in many Minnesota rivers, are important for managing and protecting water resources; however, water-quality standards for suspended sediment in Minnesota are based on grab field sampling and total suspended solids (TSS) laboratory analysis methods that have underrepresented concentrations of suspended sediment in rivers compared to U.S. Geological Survey equal-width-increment or equal-discharge-increment (EWDI) field sampling and suspended sediment concentration (SSC) laboratory analysis methods. Because of this underrepresentation, the U.S. Geological Survey, in collaboration with the Minnesota Pollution Control Agency, collected concurrent grab and EWDI samples at eight sites to compare results obtained using different combinations of field sampling and laboratory analysis methods.Study results determined that grab field sampling and TSS laboratory analysis results were biased substantially low compared to EWDI sampling and SSC laboratory analysis results, respectively. Differences in both field sampling and laboratory analysis methods caused grab and TSS methods to be biased substantially low. The difference in laboratory analysis methods was slightly greater than field sampling methods.Sand-sized particles had a strong effect on the comparability of the field sampling and laboratory analysis methods. These results indicated that grab field sampling and TSS laboratory analysis methods fail to capture most of the sand being transported by the stream. The results indicate there is less of a difference among samples collected with grab field sampling and analyzed for TSS and concentration of fines in SSC. Even though differences are present, the presence of strong correlations between SSC and TSS concentrations provides the opportunity to develop site specific relations to address transport processes not captured by grab field sampling and TSS laboratory analysis methods.

Multidisciplinary distinction of mass-movement and flood-induced deposits in lacustrine environments: implications for Holocene palaeohydrology and natural hazards (Lake Ledro, Southern Alps, Italy)

NASA Astrophysics Data System (ADS)

Simonneau, A.; Chapron, E.; Vannière, B.; Wirth, S. B.; Gilli, A.; Di Giovanni, C.; Anselmetti, F. S.; Desmet, M.; Magny, M.

2012-08-01

High-resolution seismic profiles and sediment cores from Lake Ledro combined with soil and river-bed samples from the lake's catchment area are used to assess the recurrence of natural hazards (earthquakes and flood events) in the southern Italian Alps during the Holocene. Two well-developed deltas and a flat central basin are identified on seismic profiles in Lake Ledro. Lake sediments are finely laminated in the basin since 9000 cal. yr BP and frequently interrupted by two types of sedimentary events: light-coloured massive layers and dark-coloured graded beds. Optical analysis (quantitative organic petrography) of the organic matter occurring in soils, river beds and lacustrine samples together with lake-sediment bulk density and grain-size analysis illustrate that light-coloured layers consist of a mixture of lacustrine sediments and mainly contain algal particles similar to the ones observed in background sediments. Light-coloured layers thicker than 1.5 cm in the main basin of Lake Ledro are dense and synchronous to numerous coeval mass-wasting deposits remoulding the slopes of the basin. They are interpreted as subaquatic mass movements triggered by historical and pre-historical regional earthquakes dated to 2005 AD, 1891 AD, 1045 AD and 1260, 2545, 2595, 3350, 3815, 4740, 7190, 9185 and 11495 cal. yr BP. Dark-coloured sedimentary event are dense and develop high-amplitude reflections in front of the deltas and in the deep central basin. These beds are mainly made of terrestrial organic matter (soils and ligno-cellulosic debris) and are interpreted as resulting from intense hyperpycnal flood events. Mapping and quantifying the amount of soil material accumulated in the Holocene hyperpycnal flood deposits of the sequence and applying the De Ploey erosion model allow estimating that the equivalent soil thickness eroded over the catchment area reached up to 4 mm during the largest Holocene flood events. Such significant soil erosion is interpreted as resulting

Neotectonic Activity from Karewa Sediments, Kashmir Himalaya, India

NASA Astrophysics Data System (ADS)

Agarwal, K. K.; Shah, R. A.; Achyuthan, H.; Singh, D. S.; Srivastava, S.; Khan, I.

2018-01-01

Intermontane basin sedimentation occurred during Pliocene-Pleistocene in the Karewa Basin which formed after the continent-continent collision resulting in the formation of Himalayan orogenic belt around Eocene. These are elongated, narrow, thrust bounded basins which have formed during the late stages of orogeny. Situated at a height of 1700-1800 m above sea level, the Karewa basin received sediments because of ponding of a pre-existing river system and the tectonic movements along the Great Himalayan Ranges in the north and the Pir-Panjal ranges in the south along active faults. About 1300 m thick sediments of largely fluvio-lacustrine, glacio-fluvio-lacustrine and eolian origin are exposed having evidences of neotectonically formed structural features such as folds and faults. Folds are more prominent in the Lower Karewa formation (Hirpur Formation) while faults (mostly normal faults) are abundant in the Upper Karewas (Nagum Formation). Drainage in the area varies from dendritic to anastomosing to parallel. Anastomosing drainage suggests sudden decrease in gradient while presence of linear features such as faults and ridges is evident by parallel drainage. Study of morphometric parameters such as stream length (Lsm) and stream length ratios (RL), bifurcation ratio (Rb), drainage density (D), form factor (Rf), circularity ratio (Rc), and elongation ratio (Re) also indicate intense tectonic activity in the recent past.

The Upper Laacher See Tephra in Lake Geneva sediments: Paleoenvironmental and paleoclimatological implications

USGS Publications Warehouse

Moscariello, A.; Costa, F.

1997-01-01

Microstratigraphical analysis of Late glacial lacustrine sediments from Geneva Bay provided evidence of a tephra layer within the upper Aller??d biozone. The layer consists of alkali feldspar, quartz, plagioclase. amphibole, pyroxene, opaques, titanite and glass shards. Electron microprobe analyses and morphological study of glass shards allowed correlation with the upper part of the Laacher See Tephra of the Laacher See volcano (Eifel Mountains, Germany). Sedimentological features of enclosing lacustrine sediments suggest that a momentary decrease in precipitation occurred in the catchment area and consequent reduction in detrital supply in the lake, after the ash fall-out. This has been interpreted as the environmental response to a momentary cooling following the Laacher See Tephra aerosols emission. Comparison with Sedimentological features characterizing the Aller??d-Younger Dryas transition highlights the sensitivity of Lake Geneva system in recording both short and long-terms climate-induced environmental changes.

Water column and bed-sediment core samples collected from Brownlee Reservoir near Oxbow, Oregon, 2012

USGS Publications Warehouse

Fosness, Ryan L.; Naymik, Jesse; Hopkins, Candice B.; DeWild, John F.

2013-01-01

The U.S. Geological Survey, in cooperation with Idaho Power Company, collected water-column and bed-sediment core samples from eight sites in Brownlee Reservoir near Oxbow, Oregon, during May 5–7, 2012. Water-column and bed-sediment core samples were collected at each of the eight sites and analyzed for total mercury and methylmercury. Additional bed-sediment core samples, collected from three of the eight sites, were analyzed for pesticides and other organic compounds, trace metals, and physical characteristics, such as particle size. Total mercury and methylmercury were detected in each of the water column and bed-sediment core samples. Only 17 of the 417 unique pesticide and organic compounds were detected in bed-sediment core samples. Concentrations of most organic wastewater compounds detected in bed sediment were less than the reporting level. Trace metals detected were greater than the reporting level in all the bed-sediment core samples submitted for analysis. The particle size distribution of bed-sediment core samples was predominantly clay mixed with silt.

Calibrating SALT: a sampling scheme to improve estimates of suspended sediment yield

Treesearch

Robert B. Thomas

1986-01-01

Abstract - SALT (Selection At List Time) is a variable probability sampling scheme that provides unbiased estimates of suspended sediment yield and its variance. SALT performs better than standard schemes which are estimate variance. Sampling probabilities are based on a sediment rating function which promotes greater sampling intensity during periods of high...

Classification and sedimentary characteristics of lacustrine hyperpycnal channels: Triassic outcrops in the south Ordos Basin, central China

NASA Astrophysics Data System (ADS)

Xian, Benzhong; Wang, Junhui; Gong, Chenglin; Yin, Yu; Chao, Chuzhi; Liu, Jianping; Zhang, Guodong; Yan, Qi

2018-06-01

Subaquatic channels are known as active conduits for the delivery of terrigenous sediments into related marine and lacustrine basins, as well as important targets for hydrocarbon exploration. Compared to submarine channels, lacustrine subaqueous channels created by hyperpycnal flows are understudied. Using well-exposed outcrops collected from three different locations in the southern Ordos Basin, central China, morphologies and architecture of a channelized hyperpycnal system were studied and classified. Six facies associations represent sedimentary processes from strong erosion by bedload dominated hyperpycnal flows, to transitional deposition jointly controlled by bedload and suspended-load dominated hyperpycnal flows, finally to deposition from suspended-load dominated hyperpycnal flows. On the basis of channel morphologies, infilling sediments and sedimentary processes, the documented channels can be classified into four main categories, which are erosional, bedload dominated, suspended-load dominated, and depositional channels. In very proximal and very distal locations, erosional channels and depositional channels serve as two end-members, while in middle areas, bedload-dominated channels and suspended-load dominated channels are transitional types. Erosional channels, as a response to strong erosion from bedload dominated hyperpycnal flows on upper slope, were mainly filled by mud interbedded with thin sand beds. As flow energy decreases, bedload dominated channels develop on middle slopes, which are characterized mainly by under- to balanced sediment infillings with cross-bedded sandstones and/or minor massive sandstones. Compared to bedload dominated channels, suspended-load dominated channels mainly develop in deeper water, and were filled mainly by massive or planar-laminated sandstones. Depositional channels, as a response to suspended-load dominated hyperpycnal flows in deep-water areas, are characterized by thin-medium bed classical turbidites with

Characterization of Gas-Hydrate Sediment: In Situ Evaluation of Hydrate Saturation in Pores of Pressured Sedimental Samples

NASA Astrophysics Data System (ADS)

Jin, Y.; Konno, Y.; Kida, M.; Nagao, J.

2014-12-01

Hydrate saturation of gas-hydrate bearing sediment is a key of gas production from natural gas-hydrate reservoir. Developable natural gas-hydrates by conventional gas/oil production apparatus almost exist in unconsolidated sedimental layer. Generally, hydrate saturations of sedimental samples are directly estimated by volume of gas generated from dissociation of gas hydrates in pore spaces, porosity data and volume of the sediments. Furthermore, hydrate saturation can be also assessed using velocity of P-wave through sedimental samples. Nevertheless, hydrate saturation would be changed by morphological variations (grain-coating, cementing and pore-filling model) of gas hydrates in pore spaces. Jin et al.[1,2] recently observed the O-H stretching bands of H2O molecules of methane hydrate in porous media using an attenuated total reflection IR (ATR-IR) spectra. They observed in situ hydrate formation/dissociation process in sandy samples (Tohoku Keisya number 8, grain size of ca. 110 μm). In this presentation, we present IR spectroscopy approach to in situ evaluation of hydrate saturation of pressured gas-hydrate sediments. This work was supported by funding from the Research Consortium for Methane Hydrate Resources in Japan (MH21 Research Consortium) planned by the Ministry of Economy, Trade and Industry (METI), Japan. [1] Jin, Y.; Konno, Y.; Nagao, J. Energy Fules, 2012, 26, 2242-2247. [2] Jin, Y.; Oyama, H.; Nagao, J. Jpn. J. Appl. Phys. 2009, 48, No. 108001.

Passive sampling methods for contaminated sediments: Risk assessment and management

PubMed Central

Greenberg, Marc S; Chapman, Peter M; Allan, Ian J; Anderson, Kim A; Apitz, Sabine E; Beegan, Chris; Bridges, Todd S; Brown, Steve S; Cargill, John G; McCulloch, Megan C; Menzie, Charles A; Shine, James P; Parkerton, Thomas F

2014-01-01

This paper details how activity-based passive sampling methods (PSMs), which provide information on bioavailability in terms of freely dissolved contaminant concentrations (Cfree), can be used to better inform risk management decision making at multiple points in the process of assessing and managing contaminated sediment sites. PSMs can increase certainty in site investigation and management, because Cfree is a better predictor of bioavailability than total bulk sediment concentration (Ctotal) for 4 key endpoints included in conceptual site models (benthic organism toxicity, bioaccumulation, sediment flux, and water column exposures). The use of passive sampling devices (PSDs) presents challenges with respect to representative sampling for estimating average concentrations and other metrics relevant for exposure and risk assessment. These challenges can be addressed by designing studies that account for sources of variation associated with PSMs and considering appropriate spatial scales to meet study objectives. Possible applications of PSMs include: quantifying spatial and temporal trends in bioavailable contaminants, identifying and evaluating contaminant source contributions, calibrating site-specific models, and, improving weight-of-evidence based decision frameworks. PSM data can be used to assist in delineating sediment management zones based on likelihood of exposure effects, monitor remedy effectiveness, and, evaluate risk reduction after sediment treatment, disposal, or beneficial reuse after management actions. Examples are provided illustrating why PSMs and freely dissolved contaminant concentrations (Cfree) should be incorporated into contaminated sediment investigations and study designs to better focus on and understand contaminant bioavailability, more accurately estimate exposure to sediment-associated contaminants, and better inform risk management decisions. Research and communication needs for encouraging broader use are discussed. Integr

Turbidity threshold sampling for suspended sediment load estimation

Treesearch

Jack Lewis; Rand Eads

2001-01-01

Abstract - The paper discusses an automated procedure for measuring turbidity and sampling suspended sediment. The basic equipment consists of a programmable data logger, an in situ turbidimeter, a pumping sampler, and a stage-measuring device. The data logger program employs turbidity to govern sample collection during each transport event. Mounting configurations and...

Lacustrine records of continental climate in northwest Greenland through the Holocene and Last Interglacial

NASA Astrophysics Data System (ADS)

McFarlin, J. M.; Axford, Y.; Osburn, M. R.; Lasher, G. E.; Francis, D. R.; Kelly, M. A.; Osterberg, E. C.

2015-12-01

Lake sediment records provide opportunities for high-resolution observations of paleoclimate that help to place modern climate change in geologic context. Here we present a terrestrial record of July air temperature for northwest Greenland (Nunatarssuaq, ~25 km east of the Thule Air Base) through the Holocene and a prior warm period, inferred from subfossil insect remains (Chironomidae) preserved in lacustrine sediments. In addition, we discuss ongoing work in characterizing the sources and isotopic composition of leaf waxes preserved in the same sediments. Multiple parallel sediment cores were collected in the summers of 2012 and 2014 from Wax Lips Lake (informal name), a non-glacial lake situated <2 km from the current margin of the Greenland Ice Sheet. Radiocarbon ages were obtained on aquatic mosses from intact laminae, and indicate that the record spans the Holocene, beginning at ~10.4 ka, as well as an interval beyond the range of 14C (>44 ka) and thus predates the Last Glacial Maximum (LGM). Our results demonstrate temperatures warmer than present through the early and mid Holocene followed by cooling in the late Holocene. Material that pre-dates the LGM contains insect assemblages indicating temperatures warmer than the warmest millennia of the Holocene. We interpret this material as most likely dating to the Last Interglacial Period (MIS 5). Along with assemblages of Chironomidae, we find subfossil Chaoboridae in one section of the pre-LGM sediments, suggesting exceptionally warm conditions based upon the distribution of modern-day Chaoborus. We find abundant n-alkanes and n-acids are preserved in the Holocene and pre-LGM sediments, allowing for complementary compound-specific δD analyses and identification of organic matter source in addition to chironomid derived temperature records.

Re–Os geochronology of the lacustrine Green River Formation: Insights into direct depositional dating of lacustrine successions, Re–Os systematics and paleocontinental weathering

USGS Publications Warehouse

Cumming, Vivien M.; Selby, David; Lillis, Paul G.

2012-01-01

Lacustrine sedimentary successions provide exceptionally high-resolution records of continental geological processes, responding to tectonic, climatic and magmatic influences. These successions are therefore essential for correlating geological and climatic phenomena across continents and furthermore the globe. Producing accurate geochronological frameworks within lacustrine strata is challenging because the stratigraphy is often bereft of biostratigraphy and directly dateable tuff horizons. The rhenium–osmium (Re–Os) geochronometer is a well-established tool for determining precise and accurate depositional ages of marine organic-rich rocks. Lake systems with stratified water columns are predisposed to the preservation of organic-rich rocks and thus should permit direct Re–Os geochronology of lacustrine strata. We present Re–Os systematics from one of the world's best documented lacustrine systems, the Eocene Green River Formation, providing accurate Re–Os depositional dates that are supported by Ar–Ar and U–Pb ages of intercalated tuff horizons. Precision of the Green River Formation Re–Os dates is controlled by the variation in initial 187Os/188Os and the range of 187Re/188Os ratios, as also documented in marine systems. Controls on uptake and fractionation of Re and Os are considered to relate mainly to depositional setting and the type of organic matter deposited, with the need to further understand the chelating precursors of Re and Os in organic matter highlighted. In addition to geochronology, the Re–Os data records the 187Os/188Os composition of lake water (1.41–1.54) at the time of deposition, giving an insight into continental runoff derived from weathering of the geological hinterland of the Green River Formation. Such insights enable us to evaluate fluctuations in continental climatic, tectonic and magmatic processes and provide the ability for chemostratigraphic correlation combined with direct depositional dates. Furthermore

Paleotopographic control of landslides in lacustrine deposits (Trièves plateau, French western Alps)

NASA Astrophysics Data System (ADS)

Bièvre, Grégory; Kniess, Ulrich; Jongmans, Denis; Pathier, Erwan; Schwartz, Stéphane; van Westen, Cees J.; Villemin, Thierry; Zumbo, Vilma

2011-01-01

Paleotopography in Quaternary sedimentary environments can be an important factor that controls landslide movement. This study investigates the relation between paleotopography and landslide activity in two adjacent landslides in glaciolacustrine sediments located in the Trièves area (French western Alps). Although both are in slopes underlain by the same lacustrine deposits, the Avignonet and Harmalière landslides exhibit major differences in morphology and displacement rates. Through a combination of geological mapping, airborne light detection and ranging (LiDAR) data, aerial photographs, global positioning system (GPS), and seismic noise measurements, a three-dimensional impression was made of both landslides. The analysis reveals that the difference in kinematics between the two mass movements can be traced back to at least 50 years ago. The results show that the Harmalière slide, which failed catastrophically in 1981, is still much more active than the Avignonet landslide. The fear was that the Avignonet landslide might develop in a similar catastrophic manner, threatening a number of houses constructed on the landslide. A geophysical survey based on ambient noise measurements allowed us to map the base of the lacustrine clays, and the results indicate the presence of a N-S ridge of hard sediments (Jurassic bedrock and/or compact alluvial layers) on the eastern side of the Avignonet landslide. This ridge disappears when approaching the Harmalière landslide and makes a place to what can be interpreted as a NW-SE oriented paleovalley of the river Drac. We proposed that the ridge acts as a buttress that could mechanically prevent the Avignonet landslide from evolving as fast as the Harmalière. Furthermore, the NW-SE paleovalley located under the Harmalière landslide corresponds to the motion direction of the slide. Therefore, the different behaviour of the two landslides is partly controlled by the paleotopographic setting of Lake Trièves during the last

Monitoring baseline suspended sediment in forested basins: the effects of sampling on suspended sediment rating curves

Treesearch

Robert B. Thomas

1988-01-01

Abstract - Rating curves are widely used for directly assessing changes in the suspended sediment delivery process and indirectly for estimating total yields. Four sampling methods were simulated-over a 31-day record of suspended sediment from the North Fork of the Mad River near Korbel, California. The position and size of the four groups of plotted slope/intercept...

Ecotoxicological evaluation of industrial port of Venice (Italy) sediment samples after a decontamination treatment.

PubMed

Libralato, Giovanni; Losso, Chiara; Arizzi Novelli, Alessandra; Citron, Marta; Della Sala, Stefano; Zanotto, Emanuele; Cepak, Franka; Volpi Ghirardini, Annamaria

2008-12-01

This work assesses the ecotoxicological effects of polluted sediment after a decontamination treatment process using a new sediment washing technique. Sediment samples were collected from four sites in Marghera Port industrial channels (Venice, Italy). Ecotoxicological evaluations were performed with Vibrio fischeri and Crassostrea gigas bioassays. Whole sediment and elutriate were deemed as the most suitable environmental matrices for this study. Toxicity scores developed in the Lagoon of Venice for V. fischeri on whole sediment and for C. gigas on elutriate were considered for the final ranking of samples. Ecotoxicological results showed that the treated sediment samples presented both acute and sub-chronic toxicities, which were mainly attributed to the presence of some remaining chemicals such as metals and polyaromatic hydrocarbons. The acute toxicity ranged from low to medium, while the sub-chronic one from absent to very high, suggesting that treated sediments could not be reused in direct contact with seawater.

Turbidity-controlled suspended sediment sampling for runoff-event load estimation

Treesearch

Jack Lewis

1996-01-01

Abstract - For estimating suspended sediment concentration (SSC) in rivers, turbidity is generally a much better predictor than water discharge. Although it is now possible to collect continuous turbidity data even at remote sites, sediment sampling and load estimation are still conventionally based on discharge. With frequent calibration the relation of turbidity to...

Analysis of elements in lake sediment samples by PIXE spectrometry

NASA Astrophysics Data System (ADS)

Chelarescu, E. D.; Radulescu, C.; Stihi, C.; Bretcan, P.; Tanislav, D.; Dulama, I. D.; Stirbescu, R. M.; Teodorescu, S.; Bucurica, I. A.; Andrei, R.; Morarescu, C.

2017-09-01

This work aims to determine the concentrations of several elements (e.g. Pb, Ni, Zn, Mn, Cr, and Fe) from lake sediments, in order to characterize their origin and evolution. Particle Induced X-ray Emission (PIXE) technique using the 3 MV Tandetron™ particle accelerator from National Institute for R&D in Physics and Nuclear Engineering "Horia Hulubei" (IFIN-HH), Magurele-Bucharest, Romania, was applied. Sediment cores from different salt lakes from Romania (i.e. Amara Lake, Caineni Lake, and Movila Miresii Lake) were collected, in August 2015. The content of Pb, Cr, Mn, Fe, and Ni from sediment samples show similarities with other data presented in literature and international regulation. The Zn was the only element with a higher content in all samples (e.g. maximum 401.7-517.3 mg/kg d.w.).

Characteristics of arsenic in humic substances extracted from natural organic sediments.

PubMed

Hara, Junko; Norota, Susumu; Kawebe, Yoshishige; Sugita, Hajime; Zhang, Ming

2018-06-01

The stability and dispersion of naturally occurring As have been receiving increasing attention, because As is toxic and its contamination is a widespread problem in many countries. This study investigated As fractionation and speciation in organic sediments collected from different depositional settings to elucidate the existence of stable As in humic substances. Eleven organic sediment samples were collected from marine and terrestrial alluvial regions in Hokkaido prefecture, Japan, and the chemical fraction of As and species of humic substances were identified by sequential extraction. In addition, stable As bound in organic matter was evaluated by FT-IR spectroscopy. The As fraction mainly comprised inorganic substances, especially sulfur, iron, and manganese, and terrestrial sediments (lacustrine and inland deposits) were rich in sulfides and Fe and Al (hydr)oxides. When the residual fraction was excluded, the organic fraction of As was higher in seawater sediments than in terrestrial sediments. Among humic substances, cellulose, humic acid, and hydrophilic fulvic acid were clearly associated with As accumulation, and As speciation showed that the As was of organic origin. Cellulose, an organic compound of plant origin, was abundant in As=S and As (III)=O bonds, and As accumulation was higher in sulfur-rich peat sediments, corresponding with the physiological activities of As in plants. Hydrophilic fulvic acid and humic acid in these sediments, originating from small animals and microorganisms in addition to plants, denote higher As contents and abound in As (III, V)=C and C-H, CH 3 bonds even in sulfur-rich sediments. The methylated As bonds reflect the ecological transition of organisms.

Luminescence dating of the lacustrine record of Vršac (Carpathian Basin, Serbia) - implications for a palaeoenvironmetal reconstruction

NASA Astrophysics Data System (ADS)

Klasen, N.; Zeeden, C.; Markovic, S.; Fischer, P.; Lehmkuhl, F.; Schulte, P.; Bösken, J.; Hambach, U.; Vött, A.

2017-12-01

The Carpathian Basin is one of the key areas to investigate the influence of the continental, Mediterranean and Atlantic climate interaction over Europe. The available Upper Pleistocene and Holocene geoarchives in the region are mainly loess-paleosol records. Long lacustrine records are sparse and do not always span the whole last glacial cycle. In the area around Vršac, we drilled a 10 m core to contribute to the palaeoenvironmental reconstruction of the Carpathian Basin. Electrical Resistivity Tomography (ERT) was used to find the best-suited drilling location. We applied luminescence and radiocarbon dating, because a robust chronology is important for the interpretation of the sedimentary record. Pulsed OSL measurements were carried out to identify the best sampling positions. We expect runoff from the catchment being the main source of the lacustrine sediments, because coarse fluvial input is absent. Knowledge about the depositional conditions is important in luminescence dating to evaluate partial bleaching prior to deposition, which may cause age overestimation. Therefore, we compared infrared stimulated luminescence (IRSL) signals with post infrared infrared stimulated luminescence (pIRIR) signals, which bleach at different rates. Estimation of a representative water content has major influence on the age estimate, but remains challenging in luminescence dating. We measured the present day water content as well as the saturation water content, to account for variations over time. Luminescence and radiocarbon ages differ greatly from each other. According to the laboratory experiments, luminescence dating was reliable and we conclude that radiocarbon ages were underestimated because of an intrusion of younger organic material. The initial results demonstrated the potential of the drill core. Integrating more proxy data will be useful to enhance the importance of the geoarchive at Vršac for a better understanding of the last glacial cycle in the Carpathian

Pre-aged plant waxes in tropical lake sediments and their influence on the chronology of molecular paleoclimate proxy records

NASA Astrophysics Data System (ADS)

Douglas, Peter M. J.; Pagani, Mark; Eglinton, Timothy I.; Brenner, Mark; Hodell, David A.; Curtis, Jason H.; Ma, Keith F.; Breckenridge, Andy

2014-09-01

Sedimentary records of plant-wax hydrogen (δDwax) and carbon (δ13Cwax) stable isotopes are increasingly applied to infer past climate change. Compound-specific radiocarbon analyses, however, indicate that long time lags can occur between the synthesis of plant waxes and their subsequent deposition in marginal marine sediments. The influence of these time lags on interpretations of plant-wax stable isotope records is presently unconstrained, and it is unclear whether such time lags also affect lacustrine sediments. We present compound-specific radiocarbon (14Cwax) data for n-alkanoic acid plant waxes (n-C26 to n-C32) from: (1) a sediment core from Lake Chichancanab, Yucatan Peninsula, Mexico, (2) soils in the Lake Chichancanab catchment, and (3) surface sediments from three other lakes in southeastern Mexico and northern Guatemala. 14Cwax ages in the surface sediments are consistently older than modern, and may be negatively correlated with mean annual precipitation and positively correlated with lake catchment area. 14Cwax ages in soils surrounding Lake Chichancanab increase with soil depth, consistent with deep, subsoil horizons being the primary source of lacustrine aged plant waxes, which are likely delivered to lake sediments through subsurface transport. Plant waxes in the Lake Chichancanab core are 350-1200 years older than corresponding ages of bulk sediment deposition, determined by 14C dates on terrestrial plant macrofossils in the core. A δDwax time series is in closer agreement with other regional proxy hydroclimate records when a plant-wax 14C age model is applied, as opposed to the macrofossil-based core chronology. Inverse modeling of plant-wax age distribution parameters suggests that plant waxes in the Lake Chichancanab sediment core derive predominantly from millennial-age soil carbon pools that exhibit relatively little age variance (<200 years). Our findings demonstrate that high-temporal-resolution climate records inferred from stable isotope

Sedimentological, mineralogical, and geochemical results from surface sediments and the sediment record from Site 2 of the ICDP drilling project at Lake Towuti, Indonesia

NASA Astrophysics Data System (ADS)

Hasberg, A. K.; Melles, M.; Wennrich, V.; Vogel, H.; Just, J.; Russell, J. M.; Bijaksana, S.; Morlock, M.; Opitz, S.

2017-12-01

More than 1000 m of sediment core were recovered in spring 2015 from three different drill sites in tropical Lake Towuti (2.5°S, 121°E), Indonesia, during the Towuti Drilling Project (TDP) of the International Continental Scientific Drilling Program (ICDP). Furthermore, a set of 84 lake surface sediment samples, distributed over the entire lake, was collected in order to better understand modern sedimentary processes. The surface samples were investigated for physical, chemical, mineralogical, and biological properties at the University of Cologne (UoC), Germany. On the sediment cores macro- and microscopical lithological descriptions, line-scan imaging, logging of physical properties (MSCL), and subsampling was conducted at the National Lacustrine Core Facility of the University of Minnesota, USA, in November 2015 and January 2016. Afterwards, the archive core halves and 672 subsamples of TDP Site 2 were shipped to the UoC for X-Ray Fluorescence (XRF) scanning and sedimentological, geochemical, and mineralogical analyses, respectively, supplemented by visible to near-infrared spectroscopy (VNIR) at Brown University, USA. The data from the surface samples evidence that allochthonous sedimentation in Lake Towuti today is dominated by fluvial supply from five distinguishable source areas: (i) the Mahalona River to the north, which drains lakes Mahalona and Matano, (ii) inlets around the village of Timampu to the northwest, (iii) the Loeha River to the east, (iv) the Lengke River to the south, and (v) the Lemo-Lemo River to the northeast of Lake Towuti. Of these, source areas (ii) and (iii) as well as (iv) and (v) have similar geochemical compositions, respectively. In addition, the lake sedimentation is significantly influenced by gravitational sediment supply from steep slopes as well as lake-internal gravitational and density-driven processes. The uppermost 41 m of sediment core 2A consist of pelagic sediments (totaling 11 m) and event layers from mass movement

Unusual folding and rolling of Glacio-Lacustrine sediments, Upper Fraser Canyon, British Columbia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baxter, S.

1987-05-01

Folding and rolling of graded but unconsolidated sediments by at least 720/sup 0/ produced a structure resembling a large Swiss roll about 6 ft wide and 4 ft high. The sediments were initially horizontal and well sorted, grading from coarse sands to fine silts. About 50 ft away, at the same level, the sediments include irregular layers of poorly sorted, ice-rafted pebbles and boulders. The sequence is unconformably overlain by till. The axis of folding appears to be parallel to the eastern wall of the Fraser Canyon. The outcrop is in the Stevens Pit (sand and gravel) immediately east ofmore » the Trans-Canada Highway, 2 mi south of Lytton, B.C., at an elevation of 1000 ft, approximately 600 ft above the present level of the Fraser River. The sands and silts accumulated in a lake adjacent to the east margin of a stagnant and relatively small glacier occupying the upper part of the Frazer Canyon. Partial or complete melting of small icebergs caused deposition of coarser material. A subsequent cooling trend led to an advance of the glacier, an advance which at this location caused some of the adjacent and by now frozen sediments to be rolled up like an old carpet. Further advance of the glacier caused it to override and thus preserve the deformed sequence.« less

The Upper Jurassic Stanleyville Group of the eastern Congo Basin: An example of perennial lacustrine system

NASA Astrophysics Data System (ADS)

Caillaud, Alexis; Blanpied, Christian; Delvaux, Damien

2017-08-01

The intracratonic Congo Basin, located in the Democratic Republic of Congo (DRC), is the largest sedimentary basin of Africa. The Jurassic strata outcrop along its eastern margin, south of Kisangani (formerly Stanleyville). In the last century, the Upper Jurassic Stanleyville Group was described as a lacustrine series containing a thin basal marine limestone designed as the ;Lime Fine; beds. Since the proposal of this early model, the depositional environment of the Stanleyville Group, and especially the possible marine incursion, has been debated, but without re-examining the existing cores, outcrop samples and historical fossils from the type location near Kisangani that are available at the Royal Museum for Central Africa (MRAC/KMMA, Tervuren, Belgium). In order to refine the former sedimentology, a series of nine exploration cores drilled in the Kisangani sub-basin have been described. This study aims at integrating sedimentary facies in existing sedimentary models and to discuss the hypothesis of the presence of Kimmeridgian marine deposits along the Congo River near Kisangani, a region which lies in the middle of the African continent. Eight facies have been identified, which permit a reinterpretation of the depositional environment and paleogeography of the Stanleyville Group. The base of the Stanleyville Group is interpreted to represent a conglomeratic fluvial succession, which filled an inherited Triassic paleotopography. Above these conglomerates, a transition to a typically lacustrine system is interpreted, which includes: (1) a basal profundal, sublittoral (brown to dark fine-grained siltstones with microbial carbonates, i.e., the ;Lime Fine; beds) and littoral lacustrine series; covered by (2) a sublittoral to profundal interval (brown to dark organic-rich, fine-grained siltstones), which corresponds to the maximum extent of the paleo-lake; and, finally (3) a shallow lacustrine series (greenish calcareous siltstones and sandstones with red siltstones

The use of nuclear muprobe techniques to study the chemistry of lacustrine sediments and particles

NASA Astrophysics Data System (ADS)

Grime, G. W.; Davison, W.

1993-05-01

The Oxford SPM has been used in two novel studies of lake chemistry: (a) The distribution of dissolved iron in sediment pore waters close to the sediment/water interface has been measured using the novel technique of diffusive equilibration in a thin film (DET). In this technique, which has a spatial resolution of < 1 mm, much less than that of competing techniques (1 cm), a thin layer of polyacrylamide gel is inserted into the sediment and after the rapid equilibration with the pore water, the gel is dried and fixed. The distribution of trace elements can then be measured using mubeam PIXE. Preliminary results have shown for the first time a subsurface maximum of Fe consistent with current theories of Fe dynamics. This paper presents some results obtained using the technique and discusses the limits on resolution and sensitivity, (b) Individual suspended lake particles (predominantly iron oxides and sulphides) have been analysed using point mubeam RBS and PIXE. Of particular interest in this study is the oxidation state of iron rich particles, so RBS with a 1 μm beam was used to determine the Fe: O stoichiometry of single particles. The particles were filtered from a depth of 14 m in Esthwaite Water in the English Lake District and handled in anoxic conditions until evacuation in the SPM sample chamber. Two distinct compositions of iron oxide were determined in clusters of about 5 μm diameter. Analysis by PIXE revealed that FeS was uniformly distributed in the particulate material and that it also contained elevated levels of Cu and Zn. This study was the first to demonstrate directly that discrete clusters of iron oxides are present in black particulate material which is commonly considered to comprise iron sulphides.

Passive sampling methods for contaminated sediments: State of the science for metals

PubMed Central

Peijnenburg, Willie JGM; Teasdale, Peter R; Reible, Danny; Mondon, Julie; Bennett, William W; Campbell, Peter GC

2014-01-01

“Dissolved” concentrations of contaminants in sediment porewater (Cfree) provide a more relevant exposure metric for risk assessment than do total concentrations. Passive sampling methods (PSMs) for estimating Cfree offer the potential for cost-efficient and accurate in situ characterization of Cfree for inorganic sediment contaminants. In contrast to the PSMs validated and applied for organic contaminants, the various passive sampling devices developed for metals, metalloids, and some nonmetals (collectively termed “metals”) have been exploited to a limited extent, despite recognized advantages that include low detection limits, detection of time-averaged trends, high spatial resolution, information about dissolved metal speciation, and the ability to capture episodic events and cyclic changes that may be missed by occasional grab sampling. We summarize the PSM approaches for assessing metal toxicity to, and bioaccumulation by, sediment-dwelling biota, including the recognized advantages and limitations of each approach, the need for standardization, and further work needed to facilitate broader acceptance and application of PSM-derived information by decision makers. Integr Environ Assess Manag 2014;10:179–196. © 2014 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of SETAC. Key Points Passive sampling methods (PSMs) offer the potential for cost-efficient and accurate in situ characterization of the dissolved concentrations for inorganic sediment contaminants. PSMs are useful for evaluating the geochemical behavior of metals in surficial sediments, including determination of fluxes across the sediment-water interface, and post-depositional changes in metal speciation. Few studies have tried to link PSM responses in sediments to metal uptake and toxicity responses in benthic organisms. There is a clear need for further studies. Future PSMs could be designed to mimic saturable kinetics, which

Development of an Integrated Suspended Sediment Sampling System - Prototype Results

NASA Astrophysics Data System (ADS)

Nerantzaki, Sofia; Moirogiorgou, Konstantia; Efstathiou, Dionissis; Giannakis, George; Voutsadaki, Stella; Zervakis, Michalis; Sibetheros, Ioannis A.; Zacharias, Ierotheos; Karatzas, George P.; Nikolaidis, Nikolaos P.

2015-04-01

The Mediterranean region is characterized by a unique micro-climate and a complex geologic and geomorphologic environment caused by its position in the Alpine orogenesis belt. Unique features of the region are the temporary rivers that are dry streams or streams with very low flow for most of the time over decadal time scales. One of their key characteristics is that they present flashy hydrographs with response times ranging from minutes to hours. It is crucial to monitor flash-flood events and observe their behavior since they can cause environmental degradation of the river's wider location area. The majority of sediment load is transferred during these flash events. Quantification of these fluxes through the development of new measuring devices is of outmost importance as it is the first step for a comprehensive understanding of the water quality, the soil erosion and erosion sources, and the sediment and nutrient transport routes. This work proposes an integrated suspended sediment sampling system which is implemented in a complex semi-arid Mediterranean watershed (i.e. the Koiliaris River Basin of Crete) with temporary flow tributaries and karstic springs. The system consists of sensors monitoring water stage and turbidity, an automated suspended sediment sampler, and an online camera recording video sequence of the river flow. Water stage and turbidity are continuously monitored and stage is converted to flow with the use of a rating curve; when either of these variables exceeds certain thresholds, the pump of the sediment sampler initiates sampling with a rotation proportional to the stage (flow weighted sampling). The water passes through a filter that captures the sediment, the solids are weighted after each storm and the data are converted to a total sediment flux. At the same time, the online camera derives optical measurements for the determination of the two-dimensional river flow velocity and the spatial sediment distribution by analyzing the Hue

Mineralogy of Fluvio-Lacustrine Sediments Investigated by Curiosity during the Prime Mission: Implications for Diagenesis

NASA Astrophysics Data System (ADS)

Rampe, E. B.; Morris, R. V.; Bish, D. L.; Vaniman, D. T.; Bristow, T.; Chipera, S.; Blake, D. F.; Ming, D. W.; Farmer, J.; Morrison, S. M.; Treiman, A. H.; Achilles, C.; Crisp, J.; Des Marais, D. J.; Downs, R. T.; Morookian, J. M.; Sarrazin, P.; Spanovich, N.; Yen, A.

2014-12-01

The Mars Science Laboratory rover Curiosity investigated sedimentary rocks that were deposited in a diversity of fluvio-lacustrine settings. The entire science payload was employed to characterize the mineralogy and chemistry of the Sheepbed mudstone at Yellowknife Bay and the Windjana sandstone at the Kimberley. Data from the CheMin instrument, a transmission X-ray diffractometer, were used to determine the quantitative mineralogy of both samples. The Sheepbed mudstone contains detrital basaltic minerals, calcium sulfates, iron oxides or hydroxides, iron sulfides, trioctahedral smectite, and amorphous material. The mineral assemblage and chemical data from APXS suggest that the trioctahedral smectite and magnetite formed authigenically as a result of alteration of olivine. The apparent lack of higher-grade phyllosilicates (e.g., illite and chlorite) and the presence of anhydrite indicate diagenesis at ~50-80 ºC. The mineralogy of the Windjana sandstone is different than the Sheepbed mudstone. Windjana contains significant abundances of K-feldspar, low- and high-Ca pyroxenes, magnetite, phyllosilicates, and amorphous material. At least two distinct phyllosilicate phases exist: a 10 Å phase and a component that is expanded with a peak at ~11.8 Å. The identity of the expanded phase is currently unknown, but could be a smectite with interlayer H2O, and the 10 Å phase could be illite or collapsed smectite. Further work is necessary to characterize the phyllosilicates, but the presence of illite could suggest that Windjana experienced burial diagenesis. Candidates for the cementing agents include fine-grained phyllosilicates, Fe-oxides, and/or amorphous material. Interpretations of CheMin data from the Windjana sandstone are ongoing at the time of writing, but we will present an estimate of the composition of the amorphous material from mass balance calculations using the APXS bulk chemistry and quantitative mineralogy from CheMin.

Mineralogy of Fluvio-Lacustrine Sediments Investigated by Curiosity During the Prime Mission: Implications for Diagenesis

NASA Technical Reports Server (NTRS)

Rampe, Elizabeth B.; Morris, R. V.; Bish, D. L.; Vaniman, D. T.; Bristow, T. F.; Chipera, S. J.; Blake, D. F.; Ming, D. W.; Farmer, J. D.; Morrison, S. M.;

Standard operating procedures for collection of soil and sediment samples for the Sediment-bound Contaminant Resiliency and Response (SCoRR) strategy pilot study

USGS Publications Warehouse

Fisher, Shawn C.; Reilly, Timothy J.; Jones, Daniel K.; Benzel, William M.; Griffin, Dale W.; Loftin, Keith A.; Iwanowicz, Luke R.; Cohl, Jonathan A.

2015-12-17

An understanding of the effects on human and ecological health brought by major coastal storms or flooding events is typically limited because of a lack of regionally consistent baseline and trends data in locations proximal to potential contaminant sources and mitigation activities, sensitive ecosystems, and recreational facilities where exposures are probable. In an attempt to close this gap, the U.S. Geological Survey (USGS) has implemented the Sediment-bound Contaminant Resiliency and Response (SCoRR) strategy pilot study to collect regional sediment-quality data prior to and in response to future coastal storms. The standard operating procedure (SOP) detailed in this document serves as the sample-collection protocol for the SCoRR strategy by providing step-by-step instructions for site preparation, sample collection and processing, and shipping of soil and surficial sediment (for example, bed sediment, marsh sediment, or beach material). The objectives of the SCoRR strategy pilot study are (1) to create a baseline of soil-, sand-, marsh sediment-, and bed-sediment-quality data from sites located in the coastal counties from Maine to Virginia based on their potential risk of being contaminated in the event of a major coastal storm or flooding (defined as Resiliency mode); and (2) respond to major coastal storms and flooding by reoccupying select baseline sites and sampling within days of the event (defined as Response mode). For both modes, samples are collected in a consistent manner to minimize bias and maximize quality control by ensuring that all sampling personnel across the region collect, document, and process soil and sediment samples following the procedures outlined in this SOP. Samples are analyzed using four USGS-developed screening methods—inorganic geochemistry, organic geochemistry, pathogens, and biological assays—which are also outlined in this SOP. Because the SCoRR strategy employs a multi-metric approach for sample analyses, this

Hollow Nodules Gas Escape Sedimentary Structures in Lacustrine Deposits on Earth and Gale Crater

NASA Astrophysics Data System (ADS)

Bonaccorsi, R.; Willson, D.; Fairen, A. G.; Baker, L.; McKay, C.; Zent, A.; Mahaffy, P. R.

2015-12-01

Curiosity's Mastcam and MAHLI instruments in Gale Crater (GC) imaged mm-sized circular rimmed hollow nodules (HNs) (Figure 1A), pitting the Sheepbed mudstone of Yellowknife Bay Formation [1,2]. HNs are significantly smaller than the solid nodules within the outcrop, with an external mean diameter of 1.2 mm and an interior one of 0.7 mm [2] Several formation mechanisms of HNs have been discussed, such as: (1) Diagenetic dissolution of soluble mineral phases; or, (2) Gas bubbles released shortly after sediment deposition [1-3]. In an ephemeral pond in Ubehebe Crater (Death Valley, CA) we observed the formation of hollow nodule sedimentary structures produced by gas bubbles (Figure 1C) preserved in smectite-rich mud that are strikingly similar to those imaged in GC (Figure 1A). This finding supports the gas bubble hypothesis [2]. Ubehebe Crater (UC) surface sediment hollow nodules were sampled, imaged, and their internal diameter measured (200 hollow structures) showing similar shape, distribution, and composition to those imaged by Curiosity in GC. UC in-situ observations suggest the gas bubbles were generated within the slightly reducing ephemerally submerged mud. These intra-crater deposits remain otherwise extremely dry year round, i.e., Air_rH ~2-5%; ground H2O wt%: 1-2%; Summer air/ground T: 45-48ºC/67-70ºC [4-5]. Data from the Sample Analysis at Mars (SAM), CheMin, and ChemCam instruments onboard the rover revealed that HNs-bearing mudstone are rich in smectite clay e.g., ~18-20% [6,7] deposited in a neutral to mildly alkaline environment, capturing a period when the surface was potentially habitable [1]. The UC HNs-hosting deposits are also rich in smectite clays (~30%) and occur in an ephemeral shallow freshwater setting [4-5]. If present, surface hollow nodules are easy to find in dry clay-rich mud in lacustrine sediments, so they could represent a new indicator of ephemeral but habitable/inhabited environments on both Earth and early Mars. References: [1

Possible Climatic Signal Recorded by Alkenone Distributions in Sediments from Freshwater and Saline Lakes on the Skarvsnes and Skallen Areas, Antarctica

NASA Astrophysics Data System (ADS)

Sawada, K.; Takeda, M.; Takano, Y.

2014-12-01

The distribution of long-chain (C37 - C39) alkenones in marine sediment has been well documented to record paleo-sea surface temperatures. The alkenones were also found in sediments of terrestrial saline lakes, and recently the calibrations of alkenone unsaturation indices - temperature have been established in continental areas. Furthermore, these biomarkers have been identified in lacustrine sediments on high-latitudinal terrestrial areas such as Greenland and Antarctica. In the present study, the alkenones were identified in the lacustrine sediment cores in freshwater (Lake Naga-ike) and saline lakes (Lake Suribati and Lake Funazoko) on the Skarvsnes, and a saline lake (Lake Skallen Oh-ike) on the Skallen, Antarctica. Here, we report that the alkenone distribution in the Antarctic lakes was examined as paleotemperature proxy. C37-C38 Tetra- and tri-unsaturated alkenones and C37 tetra- and tri-unsaturated alkenoates are identified in all sediment samples. The C37 di-unsaturated (C37:2) alkenones can be identified in sediments of surface layers (0-15 cm) of Lake Naga-ike and layers of 160-190 cm depth, in which age is ca. 3000 years BP by 14C dating, in Lake Skallen Ohike, and alkenone unsaturation index (UK37) is analyzed from these sediments. By using a calibration obtained from a culture strain Chrysotila lamellosa as reported by Nakamura et al. (2014), paleotemperatures are calculated to be 9.2-15ºC in surface sediments of Lake Naga-ike and 6.8-8.6ºC in Lake Skallen Oh-ike, respectively. The estimated temperatures are concordant with summer temperature of lake waters observed in Lake Naga-ike. Also, the highest concentrations of the alkenones and alkenoates are observed in deeper (older) sediment layers from Lake Naga-ikes, which has not been connected the ocean and intruded sea water. This implies that the alkenones are originated from indigenous biological organism(s) in Antarctic lake water. The class distributions (unsaturation ratios) of alkenones

Development and testing of a sampling device for the analyses of suspended sediment concentrations

NASA Astrophysics Data System (ADS)

Schletterer, Martin; Reindl, Robert; Unterlercher, Franz; Hauer, Christoph

2017-04-01

Suspended sediment concentrations are not equal in time as well as within a cross section. For calibration, sampling is needed within a cross profile (using e.g. sampler US P-61-A1) or nearby of a SSC sensor. However, due to insufficient hydraulic efficiency, uncontrolled handling under water as well as lack in accuracy in starting and closing the suspended sediment sampling, the well-established extracting of water samples by hand (dip or grab sample) lacks reproducibility. Due to these shortcomings a novel measuring device has been developed for suspended sediment sampling in rivers. For the design of the presented sampler the experiences of previous technical concepts of direct suspended sediment sampling in rivers have been considered. The sampling device consists of 2 tubes: a filling pipe (8x1 mm = 6 mm inner diameter) and an exhaust pipe (6x1 mm = 4 mm inner diameter). The filling pipe is equipped thread (M8x1 mm) to attach the "measuring nozzle" made of brass. We compared three different nozzles (D4, D5, D6) in order to investigate possible effects of different filling times. Both tubes are connected (TIG -Tungsten Inert-Gaswelding) by a flat steel. All parts (despite the nozzles) are made from stainless steel. On the tubes a plastic screw cap is mounted which allows to attach (and quickly change) standard sampling bottles. A mount enables that the device can be attached to a commercially available "GARDENA aluminium handle", thus using this rod samples can be taken at certain localities. The measurement device has been designed to improve the accuracy of suspended sediment sampling in rivers. The target was to achieve an optimum in hydraulic efficiency without disturbing the natural transport dynamics. Thus, the water sample gained from this sampling device supports the calibration and validation of indirect suspended sediment sampling devices (e.g. SSC sensor). We present the design of the sampler as well as field data in comparison with conventional dip

Soft-sediment deformation structures in the late Miocene Şelmo Formation around Adıyaman area, Southeastern Turkey

NASA Astrophysics Data System (ADS)

Koç Taşgın, Calibe; Orhan, Hükmü; Türkmen, İbrahim; Aksoy, Ercan

2011-04-01

The Şelmo Formation was deposited in the basins associated with the Southeastern Anatolian Thrust Belt and East Anatolian Fault Zone in SE Turkey. These structures developed as a result of compressional stresses created by the movement of the Arabian plate to the north and the Eurasian plate to the west from early Miocene to late Pliocene. The outcrops of the Şelmo Formation in the Adýyaman area (SE Turkey) comprise braided river deposits (lower alluvial unit) at the base, lacustrine and deltaic deposits in the middle (lacustrine unit) and low sinuousity river and alluvial deposits at the top (upper alluvial unit). Soft-sediment deformation structures were developed in sandstone, siltstone and marl of the deltaic and lacustrine unit of the Şelmo Formation. These are slumps, recumbent folds, load casts, ball-and-pillow structures, flame structures, neptunian dykes, chaotically associated structures and synsedimentary faults. The tectonic setting of the basin, the lateral extent of the soft-sediment deformation structures over tens of kilometers, their similarities to deformation structures interpreted as being induced seismically in other regions worldwide or in a laboratory setting, and being confined by undeformed layers suggest that the main trigger system was related to seismic activity in the area.

Impacts of heterogeneous organic matter on phenanthrene sorption--Different soil and sediment samples

USGS Publications Warehouse

Karapanagioti, Hrissi K.; Childs, Jeffrey; Sabatini, David A.

2001-01-01

Organic petrography has been proposed as a tool for characterizing the heterogeneous organic matter present in soil and sediment samples. A new simplified method is proposed as a quantitative means of interpreting observed sorption behavior for phenanthrene and different soils and sediments based on their organic petrographical characterization. This method is tested under singe solute conditions and at phenanthrene concentration of 1 μg/L. Since the opaque organic matter fraction dominates the sorption process, we propose that by quantifying this fraction one can interpret organic content normalized sorption distribution coefficient (Koc) values for a sample. While this method was developed and tested for various samples within the same aquifer, in the current study the method is validated for soil and sediment samples from different sites that cover a wide range of organic matter origin, age, and organic content. All 10 soil and sediment samples studied had log Koc values for the opaque particles between 5.6 and 6.8. This range of Koc values illustrates the heterogeneity of opaque particles between sites and geological formations and thus the need to characterize the opaque fraction of materials on a site-by-site basis.

Characteristics of hydrocarbons in sediment core samples from the northern Okinawa Trough.

PubMed

Huang, Xin; Chen, Shuai; Zeng, Zhigang; Pu, Xiaoqiang; Hou, Qinghua

2017-02-15

Sediment core samples from the northern Okinawa Trough (OT) were analyzed to determine abundances and distributions of hydrocarbons by gas chromatography-mass spectrometer (GC-MS). The results show that the n-alkanes in this sediment core conform to a bimodal distribution, and exhibit an odd-to-even predominance of high molecular weights compared to an even-to-odd predominance in low molecular weight n-alkanes with maxima at C 16 and C 18 . The concentrations of bitumen, alkanes and polyaromatic hydrocarbons (PAHs) were higher in samples S10-07 than all others. Three maturity parameters as well as the ratios between parent phenanthrenes (Ps) and methylphenanthrenes (MPs) in samples S10-07 and S10-17 were higher. The distribution and composition of hydrocarbons in sample S10-07 suggest that one, or several, undetected hydrothermal fields may be present in the region of this sediment core. Results also suggest that volcanism may be the main reason for the observed distribution and composition of hydrocarbons in S10-17 sample. Copyright © 2016 Elsevier Ltd. All rights reserved.

The relationship between humans and climate across the North Atlantic: what can lacustrine biomarkers tell us?

NASA Astrophysics Data System (ADS)

de Wet, G.; Castañeda, I. S.; Bradley, R. S.; Small, G.; Barrasso, T.

2016-12-01

While climate change has been implicated in the colonization/population dynamics of the North Atlantic region, researchers in many cases are forced to compare archaeological data with distant paleoclimate records, making these linkages tenuous. Our research utilizes novel organic biomarkers in lacustrine sediments to produce paired paleoclimate and human occupancy reconstructions to better address questions surrounding human migration and climate change. Here we present preliminary results from two prominent locations in the history of the European colonization of the North Atlantic. The first, carried out on the Norse "Eastern Settlement" in Southern Greenland, attempts to answer the long-standing question of whether climate change caused the demise of the colony in the 1400s C.E. Second, we use similar techniques to search for evidence of the first peopling of the Faroe Islands, a highly debated topic. The use of lacustrine biomarkers allows for numerous aspects of both paleoclimate and human presence in a catchment to be reconstructed. We reconstruct paleotemperatures using branched glycerol dialkyl glycerol tetraethers (brGDGTs) and alkenones (the UK37 Index), when present. Additionally, will analyze the difference in the hydrogen isotopic composition of long and short-chain plant leaf waxes as a proxy for lake water balance. Human occupancy in the region is investigated using fecal sterols and stanols, primarily created by the breakdown of cholesterol. Some of these compounds, such as coprostanol (the dominant sterol in human waste), provide strong evidence of human settlements and have been identified in some of our lake records. Our preliminary results suggest that temperatures were increasing in SW Greenland during the period when the Norse are thought to have died out, potentially challenging the long-standing view of climate deterioration being the primary cause of their demise. Primary productivity biomarkers from lake Eidisvatnet, in the Faroe Islands

Introduction to suspended-sediment sampling

USGS Publications Warehouse

Nolan, K. Michael; Gray, John R.; Glysson, G. Douglas

2005-01-01

Knowledge of the amount and timing of sediment transport in streams is important to those directly or indirectly responsible for developing and managing water and land resources. Such data are often used to judge the health of watershed and the success or failure of activities designed to mitigate adverse impacts of sediment on streams and stream habitats. This training class presents an introduction to methods currently used by the U.S. Geological Survey (USGS) to sample suspended-sediment concentrations in streams. The presentation is narrated, but you control the pace of the presentation. If the computer you are using can view 'MPEG' videos you will be able to take advantage of videos interspersed in the presentation. A test, found at the end of the presentation, can be taken to assess how well you understood the training material. The class, which is registered as class SW4416 with the National Training Center of the USGS, should take two or three hours to complete. In order to use the presentation provided via this Web page, you will need to download a large disc images (linked below) and 'burn' it to a blank CD-ROM using a CD-ROM recorder on your computer. The presentation will only run on a Windows-based personal computer (PC). The presentation was developed using Macromedia Director MX 20041 and is contained in the file 'SIR05-5077.exe' which should autolaunch. If it does not, the presentation can be started by double-clicking on the file name. A sound card and speakers are necessary to take advantage of narrations that accompany the presentation. Text of narrations is provided, if you are unable to listen to narrations. Instructions for installing and running the presentation are included in the file 'Tutorial.htm', which is on the CD. 1 Registered Trademark: Macromedia Incorporated

Age model for a continuous, ca 250-ka Quaternary lacustrine record from Bear Lake, Utah-Idaho

USGS Publications Warehouse

Colman, Steven M.; Kaufman, D.S.; Bright, Jordon; Heil, C.; King, J.W.; Dean, W.E.; Rosenbaum, J.G.; Forester, R.M.; Bischoff, J.L.; Perkins, Marie; McGeehin, J.P.

2006-01-01

The Quaternary sediments sampled by continuous 120-m-long drill cores from Bear Lake (Utah-Idaho) comprise one of the longest lacustrine sequences recovered from an extant lake. The cores serve as a good case study for the construction of an age model for sequences that extend beyond the range of radiocarbon dating. From a variety of potential age indicators, we selected a combination of radiocarbon ages, one magnetic excursion (correlated to a standard sequence), and a single Uranium-series age to develop an initial data set. The reliability of the excursion and U-series data require consideration of their position with respect to sediments of inferred interglacial character, but not direct correlation with other paleoclimate records. Data omitted from the age model include amino acid age estimates, which have a large amount of scatter, and tephrochronology correlations, which have relatively large uncertainties. Because the initial data set was restricted to the upper half of the BL00-1 core, we inferred additional ages by direct correlation to the independently dated paleoclimate record from Devils Hole. We developed an age model for the entire core using statistical methods that consider both the uncertainties of the original data and that of the curve-fitting process, with a combination of our initial data set and the climate correlations as control points. This age model represents our best estimate of the chronology of deposition in Bear Lake. Because the age model contains assumptions about the correlation of Bear Lake to other climate records, the model cannot be used to address some paleoclimate questions, such as phase relationships with other areas.

Results of sampling and analysis : preliminary sediment quality assessment Martha Lake Snohomish County Washington

DOT National Transportation Integrated Search

1995-10-18

This report presents the results of sediment sampling and analysis conducted in support of proposed dredging activities of Martha Lake Sediments. The characterization of the sediments will be used in support of permitting applications and exploring v...

A novel method for sampling the suspended sediment load in the tidal environment using bi-directional time-integrated mass-flux sediment (TIMS) samplers

NASA Astrophysics Data System (ADS)

Elliott, Emily A.; Monbureau, Elaine; Walters, Glenn W.; Elliott, Mark A.; McKee, Brent A.; Rodriguez, Antonio B.

2017-12-01

Identifying the source and abundance of sediment transported within tidal creeks is essential for studying the connectivity between coastal watersheds and estuaries. The fine-grained suspended sediment load (SSL) makes up a substantial portion of the total sediment load carried within an estuarine system and efficient sampling of the SSL is critical to our understanding of nutrient and contaminant transport, anthropogenic influence, and the effects of climate. Unfortunately, traditional methods of sampling the SSL, including instantaneous measurements and automatic samplers, can be labor intensive, expensive and often yield insufficient mass for comprehensive geochemical analysis. In estuaries this issue is even more pronounced due to bi-directional tidal flow. This study tests the efficacy of a time-integrated mass sediment sampler (TIMS) design, originally developed for uni-directional flow within the fluvial environment, modified in this work for implementation the tidal environment under bi-directional flow conditions. Our new TIMS design utilizes an 'L' shaped outflow tube to prevent backflow, and when deployed in mirrored pairs, each sampler collects sediment uniquely in one direction of tidal flow. Laboratory flume experiments using dye and particle image velocimetry (PIV) were used to characterize the flow within the sampler, specifically, to quantify the settling velocities and identify stagnation points. Further laboratory tests of sediment indicate that bidirectional TIMS capture up to 96% of incoming SSL across a range of flow velocities (0.3-0.6 m s-1). The modified TIMS design was tested in the field at two distinct sampling locations within the tidal zone. Single-time point suspended sediment samples were collected at high and low tide and compared to time-integrated suspended sediment samples collected by the bi-directional TIMS over the same four-day period. Particle-size composition from the bi-directional TIMS were representative of the array of

The last millennia climate dynamics in Central Asia as a function of recent geochemical response of lacustrine sedimentation

NASA Astrophysics Data System (ADS)

Kalugin, I.; Darin, A.; Ovchinnikov, D.; Myglan, V.; Babich, V.

2010-09-01

Our knowledge of climate change with associated forcing during the last thousand-years remains limited because that cannot be studied thoroughly by instrumental data. So it is an actual task to find high resolution paleoclimate records and to compare it with recent patterns of short-period oscillations. Combination of lake sediments and tree rings appears to be effective for understanding of regional climate forcings. There are several dendrochronologies (up to 1700 years long) and comparable annual reconstructions by Teletskoye Lake sediments (1500 years) in Altai region. They are calibrated by data from 14 local weather stations (time series up to 80 years) and Barnaul station (170 years) as well. We used tree-ring series together with element contents in sediments as an additional proxy for calculation of transfer function, considering that tree-ring series are responded to summer temperature in this climatic zone. Such combined version allows taking one more independent environmental indication for objective reconstructions. Element content in sediments is provided by X-ray Fluorescence on Synchrotron Radiation microanalysis with scanning step up to 0.1mm. Age model is based on three strong dates: AD 1963 by 137Cs, and AD 897 and 1540 by radiocarbon. Time series of both annual temperature and precipitation from AD 450 to 2000 are obtained from Teletskoye Lake sediments by multiple regression and artificial neural network methods using transfer function trained by meteodata. Revealed climatic proxies (Br, U and Ti content, Sr/Rb ratio and X-ray density) appear to be fundamental for silt-clay organic-bearing sediments because the same correlation is determined in standard samples from European as well as from Siberian, Chinese and Mongolian cores. The characteristic periods for northern hemisphere such as medieval warming and Little Ice Age known in the Europe and in other Asian areas (China) are revealed in Siberian region. The spectral analysis of temperatures

Sedimentary processes in High Arctic lakes (Cape Bounty, Melville Island, Canada): What do sediments really record?

NASA Astrophysics Data System (ADS)

Normandeau, Alexandre; Lamoureux, Scott; Lajeunesse, Patrick; Francus, Pierre

2016-04-01

Lacustrine sedimentary sequences can hold a substantial amount of information regarding paleoenvironments, hydroclimate variability and extreme events, providing critical insights into past climate change. The study of lacustrine sediments is often limited to the analysis of sediment cores from which past changes are inferred. However, studies have provided evidence that the accumulation of sediments in lacustrine basins and their distribution can be affected by a wide range of internal and external forcing mechanisms. It is therefore crucial to have a good knowledge of the factors controlling the transport and distribution of sediments in lakes prior to investigating paleoenvironmental archives. To address this knowledge gap, the Cape Bounty Arctic Watershed Observatory (CBAWO), located on southern Melville Island in the Canadian High Arctic, was initiated in 2003 as a long term monitoring site with the aim of understanding the controls over sediment transport within similar paired watersheds and lakes. The East and West lakes have been monitored each year since 2003 to document the role of hydro-climate variability on water column processes and sediment deposition. Moorings recording water electrical conductivity, temperature, density, dissolved oxygen and turbidity, as well as sediment traps were deployed during the active hydrological period (generally May-July). These data were analyzed in combination with hydrological and climatic data from the watersheds. Additionally, a high-resolution bathymetric and sub-bottom survey was completed in 2015 and allowed imaging the lake floor and sub-surface in great detail. This combination of process and lake morphological data are unique in the Arctic. The morphostratigraphic analysis reveals two highly disturbed lake floors, being widely affected by subaqueous mass movements that were triggered during the last 2000 years. Backscatter intensity maps and the presence of bedforms on each delta foresets indicate that

Identification of a novel lipid biomarker in lake sediments: Implications for the aquatic production of branched GDGTs

NASA Astrophysics Data System (ADS)

Weber, Yuki; De Jonge, Cindy; Rijpstra, W. Irene C.; Hopmans, Ellen C.; Stadnitskaia, Alina; Schubert, Carsten J.; Lehmann, Moritz F.; Sinninghe Damsté, Jaap S.; Niemann, Helge

2014-05-01

Branched dialkyl glycerol tetraethers (brGDGTs) are bacterial membrane lipids that occur ubiquitously in soils worldwide. Their relative abundances (which form the MBT and CBT indices) correlate with mean annual air temperature (MAAT) and pH, making them potential proxies for paleoenvironmental reconstructions in sedimentary archives with organic matter input of from terrestrial environments. In lake sediments, however, brGDGT distributions mostly relate differently to MAAT compared to soils. A likely cause for this discrepancy is in situ production of brGDGTs within the lake water column and/or -sediments by microorganisms possessing a membrane physiology that is different from soil bacteria. Until to date, existing analytical methods did not allow the distinction between soil-and lake-derived brGDGTs, complicating paleoclimate reconstructions in lacustrine settings. In order to decipher differences in the structure and the relative distribution of brGDGTs in lake deposits versus soils, we analysed samples from 35 Swiss alpine lakes and their catchments using an improved HPLC protocol. Our data revealed a novel isomer of the hexamethylated, non-cyclic brGDGT, which was previously co-eluting with the recently described 5- and 6-methyl isomers. About half of the 35 investigated lakes contained this compound where it accounted for 1 - 11 % of total brGDGTs. We were able to isolate the previously unknown isomer by multi-step preparative HPLC. The structure of the molecule was assessed by determining the identity of its alkyl chains by ether cleavage with HI and subsequent analysis with gas chromatography quadrupole mass spectrometry (GC-MS). In addition, the carbon isotopic composition of the fragments was determined to trace their biological source. In contrast to lake sediments, soil samples analysed from the watersheds of the studied lakes did not contain the newly discovered GDGT, providing evidence for in situ production in aquatic systems. This novel isomer is

Characterizing spatial structure of sediment E. coli populations to inform sampling design.

PubMed

Piorkowski, Gregory S; Jamieson, Rob C; Hansen, Lisbeth Truelstrup; Bezanson, Greg S; Yost, Chris K

2014-01-01

Escherichia coli can persist in streambed sediments and influence water quality monitoring programs through their resuspension into overlying waters. This study examined the spatial patterns in E. coli concentration and population structure within streambed morphological features during baseflow and following stormflow to inform sampling strategies for representative characterization of E. coli populations within a stream reach. E. coli concentrations in bed sediments were significantly different (p = 0.002) among monitoring sites during baseflow, and significant interactive effects (p = 0.002) occurred among monitoring sites and morphological features following stormflow. Least absolute shrinkage and selection operator (LASSO) regression revealed that water velocity and effective particle size (D 10) explained E. coli concentration during baseflow, whereas sediment organic carbon, water velocity and median particle diameter (D 50) were important explanatory variables following stormflow. Principle Coordinate Analysis illustrated the site-scale differences in sediment E. coli populations between disconnected stream segments. Also, E. coli populations were similar among depositional features within a reach, but differed in relation to high velocity features (e.g., riffles). Canonical correspondence analysis resolved that E. coli population structure was primarily explained by spatial (26.9–31.7 %) over environmental variables (9.2–13.1 %). Spatial autocorrelation existed among monitoring sites and morphological features for both sampling events, and gradients in mean particle diameter and water velocity influenced E. coli population structure for the baseflow and stormflow sampling events, respectively. Representative characterization of streambed E. coli requires sampling of depositional and high velocity environments to accommodate strain selectivity among these features owing to sediment and water velocity heterogeneity.

Mineralogy of Rocks and Sediments at Gale Crater, Mars

NASA Astrophysics Data System (ADS)

Achilles, Cherie; Downs, Robert; Blake, David; Vaniman, David; Ming, Doug; Rampe, Elizabeth; Morris, Dick; Morrison, Shaunna; Treiman, Allan; Chipera, Steve; Yen, Albert; Bristow, Thomas; Craig, Patricia; Hazen, Robert; Crisp, Joy; Grotzinger, John; Des Marias, David; Farmer, Jack; Sarrazin, Philippe; Morookian, John Michael

2017-04-01

The Mars Science Laboratory rover, Curiosity, is providing in situ mineralogical, geochemical, and sedimentological assessments of rocks and soils in Gale crater. Since landing in 2012, Curiosity has traveled over 15 km, providing analyses of mudstones and sandstones to build a stratigraphic history of the region. The CheMin X-ray diffraction (XRD) instrument is the first instrument on Mars to provide quantitative mineralogical analyses of drilled powders and scooped sediment based on X-ray crystallography. CheMin identifies and determines mineral abundances and unit-cell parameters of major crystalline phases, and identifies minor phases at abundances >1 wt%. In conjunction with elemental analyses, CheMin-derived crystal chemistry allows for the first calculations of crystalline and amorphous material compositions. These mineralogy, crystal chemistry, and amorphous chemistry datasets are playing central roles in the characterization of Gale crater paleoenvironments. CheMin has analyzed 17 rock and sediment samples. In the first phase of the mission, Curiosity explored the sedimentary units of Aeolis Palus (Bradbury group), including two mudstones from Yellowknife Bay. CheMin analyses of the Yellowknife Bay mudstones identified clay minerals among an overall basaltic mineral assemblage. These mineralogical results, along with imaging and geochemical analyses, were used to characterize an ancient lacustrine setting that is thought to have once been a habitable environment. Following the investigations of the Bradbury group, Curiosity arrived at the lower reaches of Aeolis Mons, commonly called Mt. Sharp. A strategic sample campaign was initiated, drilling bedrock at <25 m elevation intervals in order to compile a comprehensive stratigraphic column of Mt. Sharp sedimentary units. Two formations have been sampled thus far, the lower-most Murray formation and the Stimson formation, which lies unconformably over the Murray. The Stimson formation is a cross

Thermokarst lake dynamics and its influence on biogeochemical sediment characteristics: A case study from the discontinuous permafrost zone in Interior Alaska

NASA Astrophysics Data System (ADS)

Lenz, J.; Walter Anthony, K. M.; Maio, C. V.; Matuszewski, F.; Grosse, G.

2017-12-01

Under currently projected scenarios of climate warming, discontinuous warm permafrost in Interior Alaska is expected to experience widespread disappearance. Thermokarst ponds and lakes are evidence for rapid permafrost thaw and amplify deep thaw by talik development. During the thawing process, previously preserved organic matter is made available for decomposition and former permafrost carbon is potentially released as greenhouse gases carbon dioxide and methane. In the course of lake development and shoreline expansion, both, younger near-surface and older organic matter from slumping shores are potentially deposited in the lake basin. Lake internal bioproductivity is complementing carbon accumulation in lacustrine deposits and provides an additional source of young carbon. This study presents results of two intersecting, limnolithological transects of 5 sediment cores from Goldstream Lake, a typical small, boreal thermokarst lake in Interior Alaska. We here distinguish external terrestrial and internal aquatic carbon contributions to sediments based on sediment samples that were analyzed for the total organic carbon/total nitrogen ratio (C/N) as well as stable carbon isotopes. The littoral zone with actively eroding shorelines is characterized by methane seeps produced from anaerobic microbial decomposition; however, near-shore sediments have surprisingly low total organic carbon contents with a mean of 1.5 wt%; the low C/N ratio of 8.7 indicate a dominance of lacustrine plant material. Very similar results were found for sediments in the central basin, but here a clear shift to a terrestrial carbon signal (C/N of 22) with total organic carbon content of almost 30 wt% is presumably indicating the presence of a trash layer featuring largely terrestrial plants submerged during the initial lake phase. The talik sediments have carbon storage similar to the lake sediments but in contrast are not layered. Subarctic aquatic environments such as Goldstream Lake

An evaluation of flow-stratified sampling for estimating suspended sediment loads

Treesearch

Robert B. Thomas; Jack Lewis

1995-01-01

Abstract - Flow-stratified sampling is a new method for sampling water quality constituents such as suspended sediment to estimate loads. As with selection-at-list-time (SALT) and time-stratified sampling, flow-stratified sampling is a statistical method requiring random sampling, and yielding unbiased estimates of load and variance. It can be used to estimate event...

Millennial-scale climate variations recorded in Early Pliocene colour reflectance time series from the lacustrine Ptolemais Basin (NW Greece)

NASA Astrophysics Data System (ADS)

Steenbrink, J.; Kloosterboer-van Hoeve, M. L.; Hilgen, F. J.

2003-03-01

Quaternary climate proxy records show compelling evidence for climate variability on time scales of a few thousand years. The causes for these millennial-scale or sub-Milankovitch cycles are still poorly understood, not least due to the complex feedback mechanisms of large ice sheets during the Quaternary. We present evidence of millennial-scale climate variability in Early Pliocene lacustrine sediments from the intramontane Ptolemais Basin in northwestern Greece. The sediments are well exposed in a series of open-pit lignite mines and exhibit a distinct millennial-scale sedimentary cyclicity of alternating lignites and lacustrine marl beds that resulted from precession-induced variations in climate. The higher-frequency, millennial-scale cyclicity is particularly prominent within the grey-coloured marl segment of individual cycles. A stratigraphic interval of ˜115 ka, covering five precession-induced sedimentary cycles, was studied in nine parallel sections from two open-pit lignite mines located several km apart. High-resolution colour reflectance records were used to quantify the within-cycle variability and to determine its lateral continuity. Much of the within-cycle variability could be correlated between the parallel sections, even in fine detail, which suggests that these changes reflect basin-wide variations in environmental conditions related to (regional) climate fluctuations. Interbedded volcanic ash beds demonstrate the synchronicity of these fluctuations and spectral analysis of the reflectance time series shows a significant concentration of within-cycle variability at periods of ˜11, ˜5.5 and ˜2 ka. The occurrence of variability at such time scales at times before the intensification of the Northern Hemisphere glaciation suggests that they cannot solely have resulted from internal ice-sheet dynamics. Possible candidates include harmonics or combination tones of the main orbital cycles, variations in solar output or periodic motions of the Earth

Effect of lixiviated sediments affected with treated water on Selenastrum capricornutum, Printz and Origanum vulgare L.

PubMed

Ramos, Guadalupe E; Lopez, Martin H; Flores, Antonio M; Figueroa, Guadalupe T; De Leon, Fernando G

2010-01-01

Xochimilco is an area of Mexico City fulfilling important ecological functions. However, the water of the canal network in the lacustrine zone of Xochimilco is supplied by the water treatment plants of the city, implying a risk of accumulated contaminants in the sediments. This study reports the effect of lixiviates obtained from sediments collected in the canals of Xochimilco on the growth of the alga Selenastrum capricornutum and the angiosperm Origanum vulgare. Three factors were tested: (a) water source in terms of the effluent from the two water treatment plants (urban waste-water, located at Cerro de la Estrella (CE) and urban-rural waters at San Luis Tlaxialtemalco (SLT); (b) sampling season (January, dry season; May and September, rainy season; and (c) distances from the water discharge point in the Xochimilco's main canal (5200 and 1000 m for CE, and 0, 200 m for SLT). The chemical water properties analyzed were: pH, electrical conductivity, N-NO(3), N-NH(3), N(Total), P-PO(4) and P(Total). The alga was more sensitive to the contaminants than O. vulgare, showing growth inhibition of 93-100%. The effect of sampling season on the inhibition of algal growth was ordered as follows: September > May > January. Lixiviates obtained from sediment samples 200 and 1000 m from the main point of water discharge caused a higher algal growth inhibition than the samples obtained at the source point. Lixiviate promoted the growth of seedlings of O. vulgare.

Impacts of shore expansion and catchment characteristics on lacustrine thermokarst records in permafrost lowlands, Alaska Arctic Coastal Plain

USGS Publications Warehouse

Lenz, Josefine; Jones, Benjamin M.; Wetterich, Sebastian; Tjallingii, Rik; Fritz, Michael; Arp, Christopher D.; Rudaya, Natalia; Grosse, Guido

2016-01-01

Arctic lowland landscapes have been modified by thermokarst lake processes throughout the Holocene. Thermokarst lakes form as a result of ice-rich permafrost degradation, and they may expand over time through thermal and mechanical shoreline erosion. We studied proximal and distal sedimentary records from a thermokarst lake located on the Arctic Coastal Plain of northern Alaska to reconstruct the impact of catchment dynamics and morphology on the lacustrine depositional environment and to quantify carbon accumulation in thermokarst lake sediments. Short cores were collected for analysis of pollen, sedimentological, and geochemical proxies. Radiocarbon and 210Pb/137Cs dating, as well as extrapolation of measured historic lake expansion rates, were applied to estimate a minimum lake age of ~1400 calendar years BP. The pollen record is in agreement with the young lake age as it does not include evidence of the “alder high” that occurred in the region ~4000 cal yr BP. The lake most likely initiated from a remnant pond in a drained thermokarst lake basin (DTLB) and deepened rapidly as evidenced by accumulation of laminated sediments. Increasing oxygenation of the water column as shown by higher Fe/Ti and Fe/S ratios in the sediment indicate shifts in ice regime with increasing water depth. More recently, the sediment source changed as the thermokarst lake expanded through lateral permafrost degradation, alternating from redeposited DTLB sediments, to increased amounts of sediment from eroding, older upland deposits, followed by a more balanced combination of both DTLB and upland sources. The characterizing shifts in sediment sources and depositional regimes in expanding thermokarst lakes were, therefore, archived in the thermokarst lake sedimentary record. This study also highlights the potential for Arctic lakes to recycle old carbon from thawing permafrost and thermokarst processes.

Are watershed and lacustrine controls on planktonic N2 fixation hierarchically structured?

PubMed

Scott, J Thad; Doyle, Robert D; Prochnow, Shane J; White, Joseph D

2008-04-01

N2 fixation can be an important source of N to limnetic ecosystems and can influence the structure of phytoplankton communities. However, watershed-scale conditions that favor N2 fixation in lakes and reservoirs have not been well studied. We measured N2 fixation and lacustrine variables monthly over a 19-month period in Waco Reservoir, Texas, USA, and linked these data with nutrient-loading estimates from a physically based watershed model. Readily available topographic, soil, land cover, effluent discharge, and climate data were used in the Soil and Water Assessment Tool (SWAT) to derive watershed nutrient-loading estimates. Categorical and regression tree (CART) analysis revealed that lacustrine and watershed correlates of N2 fixation were hierarchically structured. Lacustrine conditions showed greater predictive capability temporally. For instance, low NO3(-) concentration (<25 microg N/L) and high water temperatures (>27 degrees C) in the reservoir were correlated with the initiation of N2 fixation seasonally. When lacustrine conditions were favorable for N2 fixation, watershed conditions appeared to influence spatial patterns of N2 fixation within the reservoir. For example, spatially explicit patterns of N2 fixation were correlated with the ratio of N:P in nutrient loadings and the N loading rate, which were driven by anthropogenic activity in the watershed and periods of low stream flow, respectively. Although N2 fixation contributed <5% of the annual N load to the reservoir, 37% of the N load was derived from atmospheric N2 fixation during summertime when stream flow in the watershed was low. This study provides evidence that watershed anthropogenic activity can exert control on planktonic N2 fixation, but that temporality is controlled by lacustrine conditions. Furthermore, this study also supports suggestions that reduced inflows may increase the propensity of N2-fixing cyanobacterial blooms in receiving waters of anthropogenically modified landscapes.

Assessment of selected contaminants in streambed- and suspended-sediment samples collected in Bexar County, Texas, 2007-09

USGS Publications Warehouse

Wilson, Jennifer T.

2011-01-01

Elevated concentrations of sediment-associated contaminants are typically associated with urban areas such as San Antonio, Texas, in Bexar County, the seventh most populous city in the United States. This report describes an assessment of selected sediment-associated contaminants in samples collected in Bexar County from sites on the following streams: Medio Creek, Medina River, Elm Creek, Martinez Creek, Chupaderas Creek, Leon Creek, Salado Creek, and San Antonio River. During 2007-09, the U.S. Geological Survey periodically collected surficial streambed-sediment samples during base flow and suspended-sediment (large-volume suspended-sediment) samples from selected streams during stormwater runoff. All sediment samples were analyzed for major and trace elements and for organic compounds including halogenated organic compounds and polycyclic aromatic hydrocarbons (PAHs). Selected contaminants in streambed and suspended sediments in watersheds of the eight major streams in Bexar County were assessed by using a variety of methods—observations of occurrence and distribution, comparison to sediment-quality guidelines and data from previous studies, statistical analyses, and source indicators. Trace elements concentrations were low compared to the consensus-based sediment-quality guidelines threshold effect concentration (TEC) and probable effect concentration (PEC). Trace element concentrations were greater than the TEC in 28 percent of the samples and greater than the PEC in 1.5 percent of the samples. Chromium concentrations exceeded sediment-quality guidelines more frequently than concentrations of any other constituents analyzed in this study (greater than the TEC in 69 percent of samples and greater than the PEC in 8 percent of samples). Mean trace element concentrations generally are lower in Bexar County samples compared to concentrations in samples collected during previous studies in the Austin and Fort Worth, Texas, areas, but considering the relatively

Fluidized-sediment pipes in Gale crater, Mars, and possible Earth analogs

USGS Publications Warehouse

Rubin, David M.; Fairen, A.G.; Frydenvang, J.; Gasnault, O.; Gelfenbaum, Guy R.; Goetz, W.; Grotzinger, J.P.; Le Mouélic, S.; Mangold, N.; Newsom, H.; Oehler, D. Z.; Rapin, W.; Schieber, J.; Wiens, R.C.

2017-01-01

Since landing in Gale crater, the Mars Science Laboratory rover Curiosity has traversed fluvial, lacustrine, and eolian sedimentary rocks that were deposited within the crater ∼3.6 to 3.2 b.y. ago. Here we describe structures interpreted to be pipes formed by vertical movement of fluidized sediment. Like many pipes on Earth, those in Gale crater are more resistant to erosion than the host rock; they form near other pipes, dikes, or deformed sediment; and some contain internal concentric or eccentric layering. These structures provide new evidence of the importance of subsurface aqueous processes in shaping the near-surface geology of Mars.

Geomorphic Drainage Capture Recorded by Oxygen Isotopes of Green River Formation Lacustrine Mudstone, Eocene, Wyoming

NASA Astrophysics Data System (ADS)

Doebbert, A. C.; Booth, A. L.; Carroll, A.; Chamberlain, C.; Rhodes, M.

2005-12-01

The isotopic composition of cement and other meteoric precipitates are increasingly being used to interpret orogenic uplift histories, based on the relationship between altitude and rainwater δ18O. However, other variables such as changing regional drainage patterns may also affect the downstream composition of surface waters, especially when multiple drainages commingle in a lake. The Green River Formation contains some of the best documented lacustrine deposits in the world, making it ideal for examining such issues. Carbonate mudstone in balanced-fill facies of the lower LaClede Bed averages 3.41‰ (PDB), and records a deep, saline to brackish lake that fluctuated near its sill. In contrast, overfilled facies of the upper LaClede Bed record a freshwater lake, and δ18O reaches values as low as -9.72‰. This transition occurred shortly after deposition of the Analcite Tuff at 48.94 ± 0.12 Ma (Smith et al., 2003), and was geologically abrupt. Based on 40Ar/39Ar-calibrated sediment accumulation rates it required no more than 200-300 ky. An almost identical transition occurs in two cores separated by about 30 km, making local diagenesis an unlikely cause. The magnitude of δ18O change is similar to that in some uplift studies, but its rapidity virtually excludes uplift as a controlling mechanism. Instead, we propose that both the change in sedimentation and the sharp decrease in δ18O are the result of a drainage capture event. The addition of a new drainage to the basin may have adjusted isotopic values in two ways: by introducing runoff with relatively low δ18O, and by decreasing residence time (and therefore evaporation) of lake water. Decreasing 87Sr/86Sr across the same transition suggests that the newly added waters may have been sourced from rising volcanic topography to the north in the Absaroka province. Although this rising topography allows for the possibility of some uplift component, the rate of change in lacustrine δ18O is consistent with

SOIL AND SEDIMENT SAMPLING METHODS | Science ...

EPA Pesticide Factsheets

The EPA Office of Solid Waste and Emergency Response's (OSWER) Office of Superfund Remediation and Technology Innovation (OSRTI) needs innovative methods and techniques to solve new and difficult sampling and analytical problems found at the numerous Superfund sites throughout the United States. Inadequate site characterization and a lack of knowledge of surface and subsurface contaminant distributions hinders EPA's ability to make the best decisions on remediation options and to conduct the most effective cleanup efforts. To assist OSWER, NERL conducts research to improve their capability to more accurately, precisely, and efficiently characterize Superfund, RCRA, LUST, oil spills, and brownfield sites and to improve their risk-based decision making capabilities, research is being conducted on improving soil and sediment sampling techniques and improving the sampling and handling of volatile organic compound (VOC) contaminated soils, among the many research programs and tasks being performed at ESD-LV.Under this task, improved sampling approaches and devices will be developed for characterizing the concentration of VOCs in soils. Current approaches and devices used today can lose up to 99% of the VOCs present in the sample due inherent weaknesses in the device and improper/inadequate collection techniques. This error generally causes decision makers to markedly underestimate the soil VOC concentrations and, therefore, to greatly underestimate the ecological

Documentation of particle-size analyzer time series, and discrete suspended-sediment and bed-sediment sample data collection, Niobrara River near Spencer, Nebraska, October 2014

USGS Publications Warehouse

Schaepe, Nathaniel J.; Coleman, Anthony M.; Zelt, Ronald B.

2018-04-06

The U.S. Geological Survey (USGS), in cooperation with the U.S. Army Corps of Engineers, monitored a sediment release by Nebraska Public Power District from Spencer Dam located on the Niobrara River near Spencer, Nebraska, during the fall of 2014. The accumulated sediment behind Spencer Dam ordinarily is released semiannually; however, the spring 2014 release was postponed until the fall. Because of the postponement, the scheduled fall sediment release would consist of a larger volume of sediment. The larger than normal sediment release expected in fall 2014 provided an opportunity for the USGS and U.S. Army Corps of Engineers to improve the understanding of sediment transport during reservoir sediment releases. A primary objective was to collect continuous suspended-sediment data during the first days of the sediment release to document rapid changes in sediment concentrations. For this purpose, the USGS installed a laser-diffraction particle-size analyzer at a site near the outflow of the dam to collect continuous suspended-sediment data. The laser-diffraction particle-size analyzer measured volumetric particle concentration and particle-size distribution from October 1 to 2 (pre-sediment release) and October 5 to 9 (during sediment release). Additionally, the USGS manually collected discrete suspended-sediment and bed-sediment samples before, during, and after the sediment release. Samples were collected at two sites upstream from Spencer Dam and at three bridges downstream from Spencer Dam. The resulting datasets and basic metadata associated with the datasets were published as a data release; this report provides additional documentation about the data collection methods and the quality of the data.

Passive PE Sampling in Support of In Situ Remediation of Contaminated Sediments

DTIC Science & Technology

2015-08-01

elements: • Expendable items: including materials such as stainless steel mixing bowls/spoons, decontamination supplies (buckets, brushes, distilled...PE samplers. Traditional sediment sampling equipment would include items such as decontamination fluids, stainless steel mixing bowls and spoons...hazardous/hazardous wastes (excess sediment, decontamination fluids). There is not expected to be a big difference in solid waste disposal costs

Preservation and Significance of Extracellular DNA in Ferruginous Sediments from Lake Towuti, Indonesia

PubMed Central

Vuillemin, Aurèle; Horn, Fabian; Alawi, Mashal; Henny, Cynthia; Wagner, Dirk; Crowe, Sean A.; Kallmeyer, Jens

2017-01-01

Extracellular DNA is ubiquitous in soil and sediment and constitutes a dominant fraction of environmental DNA in aquatic systems. In theory, extracellular DNA is composed of genomic elements persisting at different degrees of preservation produced by processes occurring on land, in the water column and sediment. Extracellular DNA can be taken up as a nutrient source, excreted or degraded by microorganisms, or adsorbed onto mineral matrices, thus potentially preserving information from past environments. To test whether extracellular DNA records lacustrine conditions, we sequentially extracted extracellular and intracellular DNA from anoxic sediments of ferruginous Lake Towuti, Indonesia. We applied 16S rRNA gene Illumina sequencing on both fractions to discriminate exogenous from endogenous sources of extracellular DNA in the sediment. Environmental sequences exclusively found as extracellular DNA in the sediment originated from multiple sources. For instance, Actinobacteria, Verrucomicrobia, and Acidobacteria derived from soils in the catchment. Limited primary productivity in the water column resulted in few sequences of Cyanobacteria in the oxic photic zone, whereas stratification of the water body mainly led to secondary production by aerobic and anaerobic heterotrophs. Chloroflexi and Planctomycetes, the main degraders of sinking organic matter and planktonic sequences at the water-sediment interface, were preferentially preserved during the initial phase of burial. To trace endogenous sources of extracellular DNA, we used relative abundances of taxa in the intracellular DNA to define which microbial populations grow, decline or persist at low density with sediment depth. Cell lysis became an important additional source of extracellular DNA, gradually covering previous genetic assemblages as other microbial genera became more abundant with depth. The use of extracellular DNA as nutrient by active microorganisms led to selective removal of sequences with lowest

Diagenetic effects on magnetic minerals in a Holocene lacustrine sediment core from Huguangyan maar lake, southeast China

NASA Astrophysics Data System (ADS)

Wu, Xudong; Wang, Yong; Bian, Liu; Shen, Ji

2016-09-01

Post-depositional reductive diagenesis usually results in partial or entire cleansing of the pristine palaeomagnetic signal, therefore, its intensity is important to be assessed for sediments that are in the purpose of retrieving palaeomagnetic information. Grain size, rock magnetic and geochemical studies on the entire core, along with scanning electron microscope observations and X-ray diffraction analyses for representative samples were carried out on a Holocene sediment core retrieved from the deep water part of Huguangyan maar lake (HGY), southeast China. The pristine magnetic mineral assemblage of the studied core is domianted by superparamagnetic (SP) and stable single domain titanomagnetite, and high coercivity minerals are not detectable. Based on down-core variations of the average grain size (MZ), total organic carbon (TOC), detrital elements (Al, Ti, Fe and Mn) and the concentration and mineralogy of magnetic minerals, the studied core could be divided into three subsections. The uppermost subsection is the least affected by diagenesis, with detrital titanomagnetite as the dominant magnetic mineral. This is owing to low TOC contents, but high detrital input generated by weak Asian summer monsoon intensity during the late Holocene. The intermediate subsection shows down-core progressively enhanced dissolution of detrital titanomagnetite, and concomitant formation of authigenic pyrite and siderite, which indicates down-core progressively enhanced diagenesis generated by down-core progressive increasing TOC content, but decreasing detrital input as the result of down-core progressively strengthened Asian summer monsoon intensity. The pristine magnetic mineral assemblage has been profoundly modified in the lowermost subsection. At certain positions of the lowermost subsection, detrital titanomagnetite has been even completely dissolved via diagenesis, giving place to authigenic pyrite and siderite. High TOC content, but low detrital input generated from

Sediment Transforms Lake Michigan

NASA Image and Video Library

2011-01-11

NASA image acquired December 17, 2010 In mid-December 2010, suspended sediments transformed the southern end of Lake Michigan. Ranging in color from brown to green, the sediment filled the surface waters along the southern coastline and formed a long, curving tendril extending toward the middle of the lake. The Moderate Resolution Imaging Spectroradiometer (MODIS) on NASA’s Aqua satellite captured these natural-color images on December 17, 2010 (top), and December 10, 2010 (bottom). Such sediment clouds are not uncommon in Lake Michigan, where winds influence lake circulation patterns. A scientificpaper published in 2007 described a model of the circulation, noting that while the suspended particles mostly arise from lake-bottom sediments along the western shoreline, they tend to accumulate on the eastern side. When northerly winds blow, two circulation gyres, rotating in opposite directions, transport sediment along the southern shoreline. As the northerly winds die down, the counterclockwise gyre predominates, and the smaller, clockwise gyre dissipates. Clear water—an apparent remnant of the small clockwise gyre—continues to interrupt the sediment plume. George Leshkevich, a researcher with the U.S. National Oceanic and Atmospheric Administration, explains that the wind-driven gyres erode lacustrine clay (very fine lakebed sediment) on the western shore before transporting it, along with re-suspended lake sediments, to the eastern shore. On the eastern side, the gyre encounters a shoreline bulge that pushes it toward the lake’s central southern basin, where it deposits the sediments. The sediment plume on December 17 followed a windy weather front in the region on December 16. NASA image courtesy MODIS Rapid Response Team at NASA GSFC. Caption by Michon Scott. Instrument: Aqua - MODIS NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard

Taphonomy and paleoecology of nonmarine mollusca: indicators of alluvial plain lacustrine sedimentation, upper part of the Tongue River Member, Fort Union Formation ( Paleocene), Northern Powder River Basin, Wyoming and Montana ( USA).

USGS Publications Warehouse

Hanley, J.H.; Flores, R.M.

1987-01-01

The composition, species abundances, and spatial and temporal distributions of mollusc assemblages were controlled by the environments in which they lived and the depositional processes that affected the molluscs after death and before final burial. Post-mortem transport, reworking and concentration of shells, and mixing of faunal elements from discrete habitats produced a taphonomic 'overprint' on assemblage characteristics that directly reflects the processes of alluvial plain and floodbasin lacustrine sedimentation. The 'overprint' can be interpreted from outcrop analysis of molluscan biofabric, which consists of: 1) orientation, fragmentation, size-sorting, abrasion, density, and dispersion of shells, 2) the nature and extent of shell-infilling, and 3) ratio of articulated to disarticulated bivalves. Taphonomic characteristics were used with sedimentological properties to differentiate in-place, reworked, transported, and ecologically mixed mollusc assemblages. This study also defines the paleoecology of habitat preferences of mollusc species as a basis for recognition of the environments in which these assemblages were deposited: 1) large floodbasin lakes, 2) small floodbasin lakes, and 3) crevasse deltas and splays. Integration of sedimentology and paleoecology provides an interdisciplinary approach to the interpretation of alluvial environments through time in the Tongue River Member. -Authors

Random field theory to interpret the spatial variability of lacustrine soils

NASA Astrophysics Data System (ADS)

Russo, Savino; Vessia, Giovanna

2015-04-01

The lacustrine soils are quaternary soils, dated from Pleistocene to Holocene periods, generated in low-energy depositional environments and characterized by soil mixture of clays, sands and silts with alternations of finer and coarser grain size layers. They are often met at shallow depth filling several tens of meters of tectonic or erosive basins typically placed in internal Appenine areas. The lacustrine deposits are often locally interbedded by detritic soils resulting from the failure of surrounding reliefs. Their heterogeneous lithology is associated with high spatial variability of physical and mechanical properties both along horizontal and vertical directions. The deterministic approach is still commonly adopted to accomplish the mechanical characterization of these heterogeneous soils where undisturbed sampling is practically not feasible (if the incoherent fraction is prevalent) or not spatially representative (if the cohesive fraction prevails). The deterministic approach consists on performing in situ tests, like Standard Penetration Tests (SPT) or Cone Penetration Tests (CPT) and deriving design parameters through "expert judgment" interpretation of the measure profiles. These readings of tip and lateral resistances (Rp and RL respectively) are almost continuous but highly variable in soil classification according to Schmertmann (1978). Thus, neglecting the spatial variability cannot be the best strategy to estimated spatial representative values of physical and mechanical parameters of lacustrine soils to be used for engineering applications. Hereafter, a method to draw the spatial variability structure of the aforementioned measure profiles is presented. It is based on the theory of the Random Fields (Vanmarcke 1984) applied to vertical readings of Rp measures from mechanical CPTs. The proposed method relies on the application of the regression analysis, by which the spatial mean trend and fluctuations about this trend are derived. Moreover, the

Holocene and late glacial palaeoceanography and palaeolimnology of the Black Sea: Changing sediment provenance and basin hydrography over the past 20,000 years

USGS Publications Warehouse

Piper, David Z.; Calvert, S.E.

2011-01-01

The elemental geochemistry of Late Pleistocene and Holocene sediments of the Black Sea, recovered in box cores from the basin margins and a 5-m gravity core from the central abyssal region of the basin, identifies two terrigenous sediment sources over the last 20 kyrs. One source region includes Anatolia and the southern Caucasus; the second region is the area drained by rivers entering the Black Sea from Eastern Europe. Alkali metal:Al and heavy:light rare-earth element ratios reveal that the relative contribution of the two sources shifted abruptly every few thousand years during the late glacial and early Holocene lacustrine phase of the basin. The shifts in source were coeval with changes in the lake level as determined from the distribution of quartz and the heavy mineral-hosted trace elements Ti and Zr.The geochemistry of the abyssal sediments further recorded a sequence of changes to the geochemistry of the water column following the lacustrine phase, when high salinity Mediterranean water entered the basin beginning 9.3 kyrs BP. Bottom water that had been oxic throughout the lake phase became anoxic at approximately 8.4 kyrs BP, as recorded by the accumulation from the water column of several redox-sensitive trace metals (Mo, Re, U). The accumulation of organic carbon and several trace nutrients (Cd, Cu, Ni, Zn) increased sharply ca. 0.4 kyrs later, at 8.0 kyrs BP, reflecting an increase of primary productivity. Its increase was coeval with a shift in the dinoflagellate ecology from stenohaline to euryhaline assemblages. During this profound environmental change from the lacustrine to the marine phase, the accumulation rate of the lithogenous sediment fraction decreased as much as 10-fold in response to the rise of the water level in the basin from a low stand ca. 9.3 ka to its current level.

Holocene and late glacial palaeoceanography and palaeolimnology of the Black Sea: Changing sediment provenance and basin hydrography over the past 20,000 years

USGS Publications Warehouse

Piper, D.Z.; Calvert, S.E.

2011-01-01

The elemental geochemistry of Late Pleistocene and Holocene sediments of the Black Sea, recovered in box cores from the basin margins and a 5-m gravity core from the central abyssal region of the basin, identifies two terrigenous sediment sources over the last 20. kyrs. One source region includes Anatolia and the southern Caucasus; the second region is the area drained by rivers entering the Black Sea from Eastern Europe. Alkali metal:Al and heavy:light rare-earth element ratios reveal that the relative contribution of the two sources shifted abruptly every few thousand years during the late glacial and early Holocene lacustrine phase of the basin. The shifts in source were coeval with changes in the lake level as determined from the distribution of quartz and the heavy mineral-hosted trace elements Ti and Zr. The geochemistry of the abyssal sediments further recorded a sequence of changes to the geochemistry of the water column following the lacustrine phase, when high salinity Mediterranean water entered the basin beginning 9.3. kyrs BP. Bottom water that had been oxic throughout the lake phase became anoxic at approximately 8.4. kyrs BP, as recorded by the accumulation from the water column of several redox-sensitive trace metals (Mo, Re, U). The accumulation of organic carbon and several trace nutrients (Cd, Cu, Ni, Zn) increased sharply ca. 0.4. kyrs later, at 8.0. kyrs BP, reflecting an increase of primary productivity. Its increase was coeval with a shift in the dinoflagellate ecology from stenohaline to euryhaline assemblages. During this profound environmental change from the lacustrine to the marine phase, the accumulation rate of the lithogenous sediment fraction decreased as much as 10-fold in response to the rise of the water level in the basin from a low stand ca. 9.3. ka to its current level.

Late Holocene Hydrologic Variability in the southeast Mojave Desert using sediments from Ford Lake, California

NASA Astrophysics Data System (ADS)

Leidelmeijer, J.; Kirby, M.; Anderson, W. T., Jr.; Mayer, S. A.; Palermo, J. A.; Stout, C.; Shellhorn, A.; Weisberg, G.; Rangel, H.; Hess, B.

2017-12-01

Most published lacustrine studies located in the Mojave Desert focus on lakes that receive the majority of their water from the Mojave River (e.g., Silver Lake, Cronese Lakes, Soda Lake, etc). Consequently, these Mojave River-fed lake sites record coastal hydroclimatic signals rather than a solely Mojave-only signal. The reason for this signal-disconnect is that the Mojave River is sourced in the San Bernardino Mountains, where annual precipitation is dictated by coastal hydroclimates. Therefore, much remains unknown about how the Mojave Desert changed during the Holocene at sub-millennial time scales. To address this problem and fill in an important geographical gap, we focus on Ford Lake in the southeastern Mojave Desert. Ford Lake is an internally drained, closed basin, and it is completely disconnected from the Mojave River. As a result, it represents one of the first lakes studied in the Mojave Desert with a climate signal that is 100% Mojave. Sediments from Ford Lake provide valuable context for understanding hydroclimatic variability exclusive to the Mojave Desert. To date, two hand-dug 1.5 m trenches (depocenter and littoral zone) and 3 overlapping sediments cores from the lake's depocenter have been sampled. The total core length is 3.55 m and bottomed in coarse alluvium, suggesting we captured the complete lacustrine sediment package. Initial results by Mayer (2016) focused on the most recent 1200 calendar years before present, or the upper 2.16 m. Mayer (2016) found evidence for increased run-off (wetter climate) during the Little Ice Age and reduced run-off (drier climate) during the Medieval Climatic Anomaly. Here, we complete the study, improving age control using sediment charcoal. Grain size, magnetic susceptibility, percent total organic matter, percent total carbonate content, C:N ratios and C and N isotopic analyses are (will be) measured at 1 cm contiguous intervals. The Ford Lake record has been (will be) compared to pre-existing regional

Semi-automatic surface sediment sampling system - A prototype to be implemented in bivalve fishing surveys

NASA Astrophysics Data System (ADS)

Rufino, Marta M.; Baptista, Paulo; Pereira, Fábio; Gaspar, Miguel B.

2018-01-01

In the current work we propose a new method to sample surface sediment during bivalve fishing surveys. Fishing institutes all around the word carry out regular surveys with the aim of monitoring the stocks of commercial species. These surveys comprise often more than one hundred of sampling stations and cover large geographical areas. Although superficial sediment grain sizes are among the main drivers of benthic communities and provide crucial information for studies on coastal dynamics, overall there is a strong lack of this type of data, possibly, because traditional surface sediment sampling methods use grabs, that require considerable time and effort to be carried out on regular basis or on large areas. In face of these aspects, we developed an easy and un-expensive method to sample superficial sediments, during bivalve fisheries monitoring surveys, without increasing survey time or human resources. The method was successfully evaluated and validated during a typical bivalve survey carried out on the Northwest coast of Portugal, confirming that it had any interference with the survey objectives. Furthermore, the method was validated by collecting samples using a traditional Van Veen grabs (traditional method), which showed a similar grain size composition to the ones collected by the new method, on the same localities. We recommend that the procedure is implemented on regular bivalve fishing surveys, together with an image analysis system to analyse the collected samples. The new method will provide substantial quantity of data on surface sediment in coastal areas, using a non-expensive and efficient manner, with a high potential application in different fields of research.

Quantifying the influence of sediment source area sampling on detrital thermochronometer data

NASA Astrophysics Data System (ADS)

Whipp, D. M., Jr.; Ehlers, T. A.; Coutand, I.; Bookhagen, B.

2014-12-01

Detrital thermochronology offers a unique advantage over traditional bedrock thermochronology because of its sensitivity to sediment production and transportation to sample sites. In mountainous regions, modern fluvial sediment is often collected and dated to determine the past (105 to >107 year) exhumation history of the upstream drainage area. Though potentially powerful, the interpretation of detrital thermochronometer data derived from modern fluvial sediment is challenging because of spatial and temporal variations in sediment production and transport, and target mineral concentrations. Thermochronometer age prediction models provide a quantitative basis for data interpretation, but it can be difficult to separate variations in catchment bedrock ages from the effects of variable basin denudation and sediment transport. We present two examples of quantitative data interpretation using detrital thermochronometer data from the Himalaya, focusing on the influence of spatial and temporal variations in basin denudation on predicted age distributions. We combine age predictions from the 3D thermokinematic numerical model Pecube with simple models for sediment sampling in the upstream drainage basin area to assess the influence of variations in sediment production by different geomorphic processes or scaled by topographic metrics. We first consider a small catchment from the central Himalaya where bedrock landsliding appears to have affected the observed muscovite 40Ar/39Ar age distributions. Using a simple model of random landsliding with a power-law landslide frequency-area relationship we find that the sediment residence time in the catchment has a major influence on predicted age distributions. In the second case, we compare observed detrital apatite fission-track age distributions from 16 catchments in the Bhutan Himalaya to ages predicted using Pecube and scaled by various topographic metrics. Preliminary results suggest that predicted age distributions scaled

A multi-proxy palaeoecological and palaeoclimatic record within full glacial lacustrine deposits, western Tennessee, USA

USGS Publications Warehouse

Grimley, D.A.; Daniel, L.; Kaplan, S.W.; Yansa, C.H.; Curry, B. Brandon; Oches, E.A.

2009-01-01

The Fulton Section, along the Mississippi River in western Tennessee, USA, is a 1km continuous exposure (~20m vertically) of Quaternary fluvial and lacustrine deposits, inset within Eocene sediments and buried by thick loess. Fossiliferous slackwater lake sediments record maximum aggradation during the last two major glaciations, with deposition between ca. 190-140 ka and 24-1814C ka BP, based on amino acid and radiocarbon chronology, respectively. During the onset of full glacial conditions (ca. 24-22 14C ka BP), a relatively permanent shallow lake environment is indicated by ostracods, aquatic molluscs, and both pollen and macrofossils of aquatic plants. By 21.8 14C ka BP, increasing emergent plants, amphibious gastropods (Pomatiopsis) and heavier ??18O compositions suggest marsh-like conditions in a periodically drying lake. The surrounding uplands consisted of Picea-Pinus woodlands mixed with cool-temperate hardwoods (e.g. Quercus, Populus, Carya), grasses and herbs. More open conditions ensued ca. 20 14C ka BP, with loess and slopewash gradually infilling the former lake by 18 14C ka BP. Modern analogue analyses of ostracods and palaeontological evidence imply a full glacial climate similar to today's mixed-boreal zone in central Minnesota, USA, about 98C cooler in mean annual temperature than present-day western Tennessee. Copyright ?? 2009 John Wiley & Sons, Ltd.

Thickness of surficial sediment at and near the Idaho National Engineering Laboratory, Idaho

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anderson, S.R.; Liszewski, M.J.; Ackerman, D.J.

1996-06-01

Thickness of surficial sediment was determined from natural-gamma logs in 333 wells at and near the Idaho National Engineering Laboratory in eastern Idaho to provide reconnaissance data for future site-characterization studies. Surficial sediment, which is defined as the unconsolidated clay, silt, sand, and gravel that overlie the uppermost basalt flow at each well, ranges in thickness from 0 feet in seven wells drilled through basalt outcrops east of the Idaho Chemical Processing Plant to 313 feet in well Site 14 southeast of the Big Lost River sinks. Surficial sediment includes alluvial, lacustrine, eolian, and colluvial deposits that generally accumulated duringmore » the past 200 thousand years. Additional thickness data, not included in this report, are available from numerous auger holes and foundation borings at and near most facilities.« less

Quantifying recent erosion and sediment delivery using probability sampling: A case study

Treesearch

Jack Lewis

2002-01-01

Abstract - Estimates of erosion and sediment delivery have often relied on measurements from locations that were selected to be representative of particular terrain types. Such judgement samples are likely to overestimate or underestimate the mean of the quantity of interest. Probability sampling can eliminate the bias due to sample selection, and it permits the...

Past Holocene detritism quantification and modeling from lacustrine archives in order to deconvoluate human-climate interactions on natural ecosystem over long time-scale

NASA Astrophysics Data System (ADS)

Simonneau, Anaëlle; Chapron, Emmanuel; Di Giovanni, Christian; Galop, Didier; Darboux, Frédéric

2014-05-01

Water budget is one of the main challenges to paleoclimate researchers in relation to present-day global warming and its consequences for human societies. Associated soil degradation and erosion are thereby becoming a major concern in many parts of the world and more particularly in the Alps. Moreover, humans are considered as geomorphologic agents since few thousand years and it is now recognized that such an impact on natural ecosystem profoundly modified soils properties as well as aquatic ecosystems dynamics over long-term periods. The quantification of such inference over long time-scale is therefore essential to establish new policies to reduce mechanic soil erosion, which is one of the dominant processes in Europe, and anticipate the potential consequences of future climate change on hydric erosion. The mechanical erosion of continental surfaces results from climatic forcing, but can be amplified by the anthropogenic one. We therefore suggest that quantifying and modelling soil erosion processes within comparable Holocene lacustrine archives, allows to estimate and date which and when past human activities have had an impact on soil fluxes over the last 10000 years. Based on the present-day geomorphology of the surrounding watershed and the evolution of the vegetation cover during the Holocene, we develop an interdisciplinary approach combining quantitative organic petrography (i.e. optical characterization and quantification of soil particles within lake sediments) with high-resolution seismic profiling, age-depth models on lacustrine sediment cores and soil erosional susceptibility modeling, in order to estimate the annual volume of soil eroded over the last 10000 years, and in fine to quantify the volume of human-induced soil erosion during the Holocene period. This method is applied to close but contrasted mountainous lacustrine environments from the western French Alps: lakes Blanc Huez and Paladru, sensitive to same climatic influences but where past

Geochemical results from stream-water and stream-sediment samples collected in Colorado and New Mexico

USGS Publications Warehouse

Hageman, Philip L.; Todd, Andrew S.; Smith, Kathleen S.; DeWitt, Ed; Zeigler, Mathew P.

2013-01-01

Scientists from the U.S. Geological Survey are studying the relationship between watershed lithology and stream-water chemistry. As part of this effort, 60 stream-water samples and 43 corresponding stream-sediment samples were collected in 2010 and 2011 from locations in Colorado and New Mexico. Sample sites were selected from small to midsize watersheds composed of a high percentage of one rock type or geologic unit. Stream-water and stream-sediment samples were collected, processed, preserved, and analyzed in a consistent manner. This report releases geochemical data for this phase of the study.

Climatic and lacustrine morphometric controls of diatom paleoproductivity in a tropical Andean lake

NASA Astrophysics Data System (ADS)

Bao, R.; Hernández, A.; Sáez, A.; Giralt, S.; Prego, R.; Pueyo, J. J.; Moreno, A.; Valero-Garcés, B. L.

2015-12-01

. The subsequent net increase in lake level introduced modifications in the area of the epilimnion sediments versus the total volume of the epilimnion, preventing complete overturn. Surpassing a certain depth threshold at approx. 8300 cal yr BP caused cessation of the morphometric eutrophy conditions associated with Cyclostephanos cf. andinus superblooms. After 7300 cal yr BP, the lake experienced a decrease in biosiliceous productivity and a change of state that involved a stronger dependence on precipitation variability, with a lesser contribution of diatoms to the total primary productivity. Our results show that the interpretation of lacustrine paleoproductivity records as paleoclimatic archives needs to take into account the effects of changes in the epilimnion sediment area to epilimnion volume ratio in association with lake ontogeny.

A geochemical record of the link between chemical weathering and the East Asian summer monsoon during the late Holocene preserved in lacustrine sediments from Poyang Lake, central China

NASA Astrophysics Data System (ADS)

Huang, Chao; Wei, Gangjian; Li, Wuxian; Liu, Ying

2018-04-01

This paper presents relatively high-resolution geochemical records spanning the past 4000 cal yr BP obtained from the lacustrine sediments of Poyang Lake in central China. The variations in the intensity of the East Asian summer monsoon (EASM) are traced using the K/Na, Ti/Na, Al/K, kaolinite/illite and clay/feldspar ratios, together with the chemical index of alteration (CIA), as indicators of chemical weathering. During the last 4000 years, the proxy records of chemical weathering from Poyang Lake exhibit an overall enhanced trend, consistent with regional hydrological changes in previous independent records. Further comparisons and analyses demonstrate that regional moisture variations in central China is inversely correlated with the EASM intensity, with weak EASM generating high precipitation in central China. Our data reveal three intervals of dramatically dry climatic conditions (i.e., ca. 4000-3200 cal yr BP, ca. 2800-2400 cal yr BP, and ca. 500-200 cal yr BP). A period of weak chemical weathering, related to cold and dry climatic conditions, occurred during the Little Ice Age (LIA), whereas more intense chemical weathering, reflecting warm and humid climatic conditions, was recorded during the Medieval Warm Period (MWP). Besides, an intensification of chemical weathering in Poyang Lake during the late Holocene agrees well with strong ENSO activity, suggesting that moisture variations in central China may be predominantly driven by ENSO variability.

SedCT: MATLAB™ tools for standardized and quantitative processing of sediment core computed tomography (CT) data collected using a medical CT scanner

NASA Astrophysics Data System (ADS)

Reilly, B. T.; Stoner, J. S.; Wiest, J.

2017-08-01

Computed tomography (CT) of sediment cores allows for high-resolution images, three-dimensional volumes, and down core profiles. These quantitative data are generated through the attenuation of X-rays, which are sensitive to sediment density and atomic number, and are stored in pixels as relative gray scale values or Hounsfield units (HU). We present a suite of MATLAB™ tools specifically designed for routine sediment core analysis as a means to standardize and better quantify the products of CT data collected on medical CT scanners. SedCT uses a graphical interface to process Digital Imaging and Communications in Medicine (DICOM) files, stitch overlapping scanned intervals, and create down core HU profiles in a manner robust to normal coring imperfections. Utilizing a random sampling technique, SedCT reduces data size and allows for quick processing on typical laptop computers. SedCTimage uses a graphical interface to create quality tiff files of CT slices that are scaled to a user-defined HU range, preserving the quantitative nature of CT images and easily allowing for comparison between sediment cores with different HU means and variance. These tools are presented along with examples from lacustrine and marine sediment cores to highlight the robustness and quantitative nature of this method.

Large sulfur isotope fractionations in Martian sediments at Gale crater

NASA Astrophysics Data System (ADS)

Franz, H. B.; McAdam, A. C.; Ming, D. W.; Freissinet, C.; Mahaffy, P. R.; Eldridge, D. L.; Fischer, W. W.; Grotzinger, J. P.; House, C. H.; Hurowitz, J. A.; McLennan, S. M.; Schwenzer, S. P.; Vaniman, D. T.; Archer, P. D., Jr.; Atreya, S. K.; Conrad, P. G.; Dottin, J. W., III; Eigenbrode, J. L.; Farley, K. A.; Glavin, D. P.; Johnson, S. S.; Knudson, C. A.; Morris, R. V.; Navarro-González, R.; Pavlov, A. A.; Plummer, R.; Rampe, E. B.; Stern, J. C.; Steele, A.; Summons, R. E.; Sutter, B.

2017-09-01

Variability in the sulfur isotopic composition in sediments can reflect atmospheric, geologic and biological processes. Evidence for ancient fluvio-lacustrine environments at Gale crater on Mars and a lack of efficient crustal recycling mechanisms on the planet suggests a surface environment that was once warm enough to allow the presence of liquid water, at least for discrete periods of time, and implies a greenhouse effect that may have been influenced by sulfur-bearing volcanic gases. Here we report in situ analyses of the sulfur isotopic compositions of SO2 volatilized from ten sediment samples acquired by NASA’s Curiosity rover along a 13 km traverse of Gale crater. We find large variations in sulfur isotopic composition that exceed those measured for Martian meteorites and show both depletion and enrichment in 34S. Measured values of δ34S range from -47 +/- 14‰ to 28 +/- 7‰, similar to the range typical of terrestrial environments. Although limited geochronological constraints on the stratigraphy traversed by Curiosity are available, we propose that the observed sulfur isotopic signatures at Gale crater can be explained by equilibrium fractionation between sulfate and sulfide in an impact-driven hydrothermal system and atmospheric processing of sulfur-bearing gases during transient warm periods.

Change in Sediment Provenance Near the Current Estuary of Yellow River Since the Holocene Transgression

NASA Astrophysics Data System (ADS)

Song, Sheng; Feng, Xiuli; Li, Guogang; Liu, Xiao; Xiao, Xiao; Feng, Li

2018-06-01

Sedimentary sequence and sediment provenance are important factors when it comes to the studies on marine sedimentation. This paper studies grain size distribution, lithological characteristics, major and rare earth elemental compositions, micropaleontological features and 14C ages in order to examine sedimentary sequence and sediment provenance of the core BH6 drilled at the mouth of the Yellow River in Bohai Sea. According to the grain size and the micropaleontological compositions, 4 sedimentary units have been identified. Unit 1 (0-8.08 mbsf) is of the delta sedimentary facies, Unit 2 (8.08-12.08 mbsf) is of the neritic shelf facies, Unit 3 (12.08-23.85 mbsf) is of near-estuary beach-tidal facies, and Unit 4 (23.85 mbsf-) is of the continental lake facies. The deposits from Unit 1 to Unit 3 have been found to be marine strata formed after the Holocene transgression at about 10 ka BP, while Unit 4 is continental lacustrine deposit formed before 10 ka BP. The provenances of core BH6 sediments show properties of the continental crust and vary in different sedimentary periods. For Unit 4 sediments, the source regions are dispersed while the main provenance is not clear, although the parent rock characteristics of a few samples are similar to the Luanhe River sediments. For Unit 3, sediments at 21.1-23.85 mbsf have been mainly transported from the Liaohe River, while sediments above 21.1 mbsf are mainly from the Yellow River and partially from the Liaohe River. For Unit 2, the sediments have been mainly transported from the Yellow River, with a small amount from other rivers. For Unit 1, the provenance is mainly the Yellow River catchment. These results help in better understanding the evolution of the Yellow River Delta.

Sediment Sampling Data for BP Spill/Deepwater Horizon

EPA Pesticide Factsheets

The Deepwater Horizon oil spill (also referred to as the BP oil spill) began on 20 April 2010 in the Gulf of Mexico on the BP-operated Macondo Prospect. Following the explosion and sinking of the Deepwater Horizon oil rig, a sea-floor oil gusher flowed for 87 days, until it was capped on 15 July 2010.In response to the BP oil spill, EPA sampled air, water, sediment, and waste generated by the cleanup operations.

Application of Lacustrine Biomarkers to Reconstruct Late Holocene Temperature Change in the Saskatchewan Prairies.

NASA Astrophysics Data System (ADS)

Cavazzin, B.; Toney, J. L.; Pearson, E. J.; Schouten, S.; Leavitt, P.; Haig, H.

2016-12-01

Extreme hydrological events such as prolonged droughts are among Canada's costliest natural calamities resulting in disastrous impacts on agriculture, forestry, industry, and ecosystems. Investigations into climate variations prior to significant anthropogenic modification are essential to build effective projection models and adaptation strategies needed to reduce economic, social and environmental vulnerability within the prairies eco-region. In this study we use organic geochemical analysis of lipids produced by bacteria, archaea and algae in lake and catchment sediments. These organic compounds are highly resistant to degradation and accumulate in the sediments as geochemical fossils or biomarkers. In particular we focus on Glycerol Dialkyl Glycerol Tetraethers (GDGT) biomarkers which are ubiquitous in soils and lacustrine environments and can be applied as quantitative temperature proxies in regions of the world where other proxies cannot be used. The aim of this study is to examine the relationship between GDGT distribution and temperature and assess the potential for establishing a GDGT-based paleothermometer for the Canadian prairies lakes. Our training set includes GDGT data from core-top sediments from 105 lakes across spanning a 5° latitudinal gradient and spring surface water temperature gradient of about 9°C. We identified 30 known bacterial and archaeal GDGTs, including the novel archaeal tetraether lipids with a cyclohexyl ring. These compounds are present in varying proportions in all the lakes investigated, suggesting a broad range of GDGT inputs and also potential in-situ production. We analysed the relationships between individual GDGT compounds against temperature, pH, conductivity, water depth and other environmental variables. We also examined previously published GDGT-environment indices in order to test the applicability of previously developed GDGT-based paleotemperature calibrations to the prairies lakes and assess whether a new

The impact of urban expansion and agricultural legacies on trace metal accumulation in fluvial and lacustrine sediments of the lower Chesapeake Bay basin, USA.

PubMed

Coxon, T M; Odhiambo, B K; Giancarlo, L C

2016-10-15

The progressively declining ecological condition of the Chesapeake Bay is attributed to the influx of contaminants associated with sediment loads supplied by its largest tributaries. The continued urban expansion in the suburbs of Virginia cities, modern agricultural activities in the Shenandoah Valley, the anthropogenic and climate driven changes in fluvial system hydrodynamics and their potential associated impacts on trace metals enrichment in the bay's tributaries necessitate constant environmental monitoring of these important water bodies. Eight (210)Pb and (137)Cs dated sediment cores and seventy two sediment grab samples were used to analyze the spatial and temporal distributions of Al, Ca, Mg, Cr, Cd, As, Se, Pb, Cu, Zn, Mn, and Fe in the waterways of the Virginia portion of the Chesapeake Bay basin. The sediment cores for trace metal historical fluctuation analysis were obtained in lower fluvial-estuarine environments and reservoirs in the upper reaches of the basin. The trace metal profiles revealed high basal enrichment factors (EF) of between 0.05 and 40.24, which are interpreted to represent early nineteenth century agricultural activity and primary resource extraction. Surficial enrichment factors on both cores and surface grab samples ranged from 0.01 (Cu) to 1421 (Cd), with Pb, Cu, Zn, and Cd enrichments a plausible consequence of modern urban expansion and industrial development along major transportation corridors. Contemporary surficial enrichments of As, Se, and Cr also ranged between 0 and 137, with the higher values likely influenced by lithological and atmospheric sources. Pearson correlation analyses suggest mining and agricultural legacies, coupled with aerosol deposition, are responsible for high metal concentrations in western lakes and headwater reaches of fluvial systems, while metal accumulation in estuarine reaches of the major rivers can be attributed to urban effluence and the remobilization of legacy sediments. Copyright © 2016

Abiotically-formed, primary dolomite in the mid-Eocene lacustrine succession at Gebel El-Goza El-Hamra, NE Egypt: An approach to the role of smectitic clays

NASA Astrophysics Data System (ADS)

Wanas, H. A.; Sallam, E.

2016-08-01

This study discusses the role of smectitic clays in the formation of an abiotic (physio-chemical) primary dolomite within an evaporative alkaline-saline marginal lake system, in the absence of carbonate precursor and microbes. The present work has been achieved in terms of textural, mineralogical, and geochemical characteristics of dolostones in the Mid-Eocene (Bartonian) lacustrine succession cropping out at Gebel El-Goza El-Hamra (Shabrawet area, NE Egypt). This lacustrine succession is 15-16 m thick, and made up of alternating horizontal beds of dolostone, marlstone and mudrock that show some pedogenic and subaerial exposure features. The dolostones are composed mainly of dolomite (60-90%), smectite (20-30%) and quartz grains (5-10%). The dolomite comprises fine-crystalline rhombs to micro-spherical crystals with no obvious relics of microbial activity and/or carbonate precursor. It is, ordered, nearly stoichiometric (with 46-50% mole of MgCO3) and has δ18O and δ13C values ranging from + 0.44 to + 2.96 VPDB ‰, and 0.93 to - 8.95 VPDB ‰, respectively. The smectite occurs as thin mats that are commonly intergrown and associated with dolomite. Mineralogical, textural and stable isotopic results of the dolomite indicated that the dolomite was formed as an abiotic primary precipitate in alkaline saline lacustrine systems. In this respect, the gel-like highly viscous smectitic medium plus progressive CO2 degassing, elevated evaporation, low sedimentation rate, low sulphates level and alkaline soil solution lowered the kinetic barriers of dolomite precipitation from solution and promoted the incorporation of Mg2 + in the structure of dolomite. Consequently, the presence of smectitic clays in evaporative saline lakes is significant for dolomite formation because they can generate a gel-like highly viscous medium and provide Mg2 + that can facilitate the physcio-chemical precipitation of primary dolomite from solution at ambient temperatures. However, more work is

Marine and Lacustrine Organic-rich Sedimentary Unit Time Markers: Implications from Rhenium-Osmium Geochronology

NASA Astrophysics Data System (ADS)

Selby, D.

2011-12-01

addition to these examples, several studies have presented precise dates for Phanerozoic marine organic-rich units that are in excellent agreement with biostratigraphic determinations. A recent Re-Os study of the Woodford Shale (that was deposited throughout the Frasnian and Famennian) has provided important time markers as well as suggesting that the sedimentation rate of the Formation was relatively constant for ~20 Ma. To date only marine organic-rich sedimentary rocks have been utilized for Re-Os geochronology. However, lacustrine sedimentary rocks provide an invaluable archive of continental geological processes responding to tectonic, climatic and magmatic influences. Correlating these rocks to global geological phenomena requires accurate geochronological frameworks. The organic-rich lacustrine sedimentary units of the Eocene Green River Formation are enriched is Re and Os comparable to that of marine units. The Re-Os dates for the Green River Formation from the Uinta basin are 48.5 ± 0.6 Ma and 49.2 ± 1.0 Ma. These dates are in excellent agreement with Ar/Ar and U/Pb dates of interbedded tuffs in the GRF, therefore demonstrating that lacustrine units can be used for Re-Os geochronology in addition to marine organic-rich units.

Sampling method, storage and pretreatment of sediment affect AVS concentrations with consequences for bioassay responses.

PubMed

De Lange, H J; Van Griethuysen, C; Koelmans, A A

2008-01-01

Sediment treatment and sediment storage may alter sediment toxicity, and consequently biotic response. Purpose of our study was to combine these three aspects (treatment-toxicity-biotic response) in one integrated approach. We used Acid Volatile Sulfide (AVS) concentrations as a proxy of the disturbance of the sediment. AVS and Simultaneously Extracted Metal (SEM) concentrations were compared to bioassay responses with the freshwater benthic macroinvertebrate Asellus aquaticus. Storage conditions and sediment treatment affected AVS but not SEM levels. AVS can be used as a proxy for sediment disturbance. The best way to pretreat the sediment for use in a bioassay in order to maintain initial AVS conditions was to sample the sediment with an Ekman grab, immediately store it in a jar without headspace, and freeze it as soon as possible. In a survey using seven different sediments, bioassay responses of A. aquaticus were correlated with SEM and AVS characteristics.

Occurrence, distribution, and concentrations of selected contaminants in streambed- and suspended-sediment samples collected in Bexar County, Texas, 2007-09

USGS Publications Warehouse

Wilson, Jennifer T.

2011-01-01

High concentrations of sediment-associated contaminants are typically associated with urban areas such as San Antonio, Texas, in Bexar County, the seventh most populous city in the United States. U.S. Geological Survey personnel periodically collected surficial streambed-sediment samples during 2007-09 and collected suspended-sediment samples from selected streams after storms during 2008 and 2009. All sediment samples were analyzed for major and trace elements, pesticides, polychlorinated biphenyls, and polycyclic aromatic hydrocarbons.

A comparison of selection at list time and time-stratified sampling for estimating suspended sediment loads

Treesearch

Robert B. Thomas; Jack Lewis

1993-01-01

Time-stratified sampling of sediment for estimating suspended load is introduced and compared to selection at list time (SALT) sampling. Both methods provide unbiased estimates of load and variance. The magnitude of the variance of the two methods is compared using five storm populations of suspended sediment flux derived from turbidity data. Under like conditions,...

Diatom Assemblages on Lacustrine Sediments from the Tropical Andes, Southern Peru: Modern Analogs for Ancient Environments

NASA Astrophysics Data System (ADS)

Tapia, P. M.; Vargas, J.; Beal, S. A.; Stroup, J. S.; Kelly, M. A.

2012-12-01

Diatom analysis of surface sediments from 17 high-altitude lakes (~3,100-5,000 m asl) in the Cuzco area, Peru, reveals several potential environmental settings that have been observed in biostratigraphy records from lakes in the tropical Andes. The sedimentation rates in several lakes from this area range between 1 and 1.6 mm yr-1 during the late Quaternary, thus we assume our surface samples represent conditions spanning from 6 to 10 years for the top 1cm. Physical and chemical analysis show a high variability in water depth (0.5-12.3 m), pH (7.5-9.7), temperature (4.6-16.5 °C) and conductivity (5.6-3205 μS cm -1), as well as cationic (Na+, K+, Mg2+, Ca2+, Al3+, Mn3+, Fe3+) and anionic (F-, Cl-, Br-, SO42-) composition. Most of the lakes were oligotrophic (PO43-and NO32- below limit of detection) with the exception of nitrite. Principle Component Analysis suggests that the sites follows a strong gradient in conductivity + anions & cations (Axis 1, explaining 51.61 % of variance), and pH + water depth (Axis 2, 17.36 %). Diatoms are quite abundant (108-1010 valves g dry sed-1) in these samples, indicating oligotrophic to mesotrophic conditions and fresh to brackish waters, sometimes forming almost monospecific associations. Applications of these assemblages may be found in the Lake Junin, Central Peruvian Andes. The high abundance (92%) of the pennate diatom Denticula elegans from Site PLS-9 is similar at the Junin Biozone JU-3 that covers most of the Holocene. This species prospers in shallow (1.3-m), high conductivity (3205 μS cm-1) and alkaline (pH 9.39) waters with high values in Ca, Mg and sulfate. Similarly, the dominance (95%) of the centric diatom Discotella stelligera at Site PLS-8 resemble Biozone JU-2, ~17,000 cal yr BP, with deeper (10.9 m), lower conductivity (48.8 μS cm-1) and slightly-alkaline (pH 7.82) waters, with at least 2 orders of magnitude lower in chemical parameters than Site PLS-9. These findings encourage the survey of additional modern

Sediment Sampling in Estuarine Mudflats with an Aerial-Ground Robotic Team

PubMed Central

Deusdado, Pedro; Guedes, Magno; Silva, André; Marques, Francisco; Pinto, Eduardo; Rodrigues, Paulo; Lourenço, André; Mendonça, Ricardo; Santana, Pedro; Corisco, José; Almeida, Susana Marta; Portugal, Luís; Caldeira, Raquel; Barata, José; Flores, Luis

2016-01-01

This paper presents a robotic team suited for bottom sediment sampling and retrieval in mudflats, targeting environmental monitoring tasks. The robotic team encompasses a four-wheel-steering ground vehicle, equipped with a drilling tool designed to be able to retain wet soil, and a multi-rotor aerial vehicle for dynamic aerial imagery acquisition. On-demand aerial imagery, properly fused on an aerial mosaic, is used by remote human operators for specifying the robotic mission and supervising its execution. This is crucial for the success of an environmental monitoring study, as often it depends on human expertise to ensure the statistical significance and accuracy of the sampling procedures. Although the literature is rich on environmental monitoring sampling procedures, in mudflats, there is a gap as regards including robotic elements. This paper closes this gap by also proposing a preliminary experimental protocol tailored to exploit the capabilities offered by the robotic system. Field trials in the south bank of the river Tagus’ estuary show the ability of the robotic system to successfully extract and transport bottom sediment samples for offline analysis. The results also show the efficiency of the extraction and the benefits when compared to (conventional) human-based sampling. PMID:27618060

Net atmospheric mercury deposition to Svalbard: Estimates from lacustrine sediments

NASA Astrophysics Data System (ADS)

Drevnick, Paul E.; Yang, Handong; Lamborg, Carl H.; Rose, Neil L.

2012-11-01

In this study we used lake sediments, which faithfully record Hg inputs, to derive estimates of net atmospheric Hg deposition to Svalbard, Norwegian Arctic. With the exception of one site affected by local pollution, the study lakes show twofold to fivefold increases in sedimentary Hg accumulation since 1850, likely due to long-range atmospheric transport and deposition of anthropogenic Hg. Sedimentary Hg accumulation in these lakes is a linear function of the ratio of catchment area to lake area, and we used this relationship to model net atmospheric Hg flux: preindustrial and modern estimates are 2.5 ± 3.3 μg m-2 y-1 and 7.0 ± 3.0 μg m-2 y-1, respectively. The modern estimate, by comparison with data for Hg wet deposition, indicates that atmospheric mercury depletion events (AMDEs) or other dry deposition processes contribute approximately half (range 0-70%) of the net flux. Hg from AMDEs may be moving in significant quantities into aquatic ecosystems, where it is a concern because of contamination of aquatic food webs.

Determining the Influence of Dust on Post-Glacial Lacustrine Sedimentation in Bald Lake, Uinta Mountains, Utah

NASA Astrophysics Data System (ADS)

O'Keefe, S. S.; McElroy, R.; Munroe, J. S.

2016-12-01

Dust is increasingly recognized as an important component of biogeochemical cycling and ecosystem function in mountain environments. Previous work has shown that delivery of dust to the Uinta Mountains of northeastern Utah has influenced pedogenesis, soil nutrient status, and surface water chemistry. An array of passive and active samplers in the alpine zone of the Uintas provides detailed information about contemporary dust fluxes, along with physical and geochemical properties of modern dust. Reconstruction of changes in the dust system over time, however, requires continuous sedimentary archives sensitive to dust inputs. A radiocarbon-dated 3.5-m core (spanning 12.7 kyr) collected from subalpine Bald Lake may provide such a record. Passive dust collectors in the vicinity of the lake constrain the geochemical properties of modern dust, whereas samples of regolith constrain properties of the local surficial material within the watershed. Together, these represent two end member sources of clastic sediment to Bald Lake basin: allochthonous dust and autochthonous regolith. Ba and Eu are found in higher abundances in the dust than in the watershed regolith. Zr and Th are found to be lower in the dust than in the watershed. Geochemical analysis of the sediment core allows the relative contribution of exotic and local material to the lake to be considered as a time series covering the post-glacial interval when indicator elements are plotted. Findings suggest Bald Lake's dust record tracks regional aridity and corresponds to low-stands of large lakes in the southwestern United States. Spatial variability of elemental abundances in the watershed suggests there are more than two input sources contributing to the lake over time.

Matuyama/Brunhes Polarity Transition in Owens Lake, CA, Sediment

NASA Astrophysics Data System (ADS)

Liddicoat, Joseph; Kravchinsky, Vadim

2014-05-01

The complexity of the Matuyama/Brunhes (M/B) polarity transition is becoming better understood from investigations of volcanic rocks (Coe et al., 2004), loess (Jin et al., 2012; Evans et al., 2011; Kravchinsky, 2013), and marine (Clement and Opdyke, 1982; Hartl and Tauxe, 1996; Macri et al., 2010) and lacustrine (Valet et al., 1988; Sagnotti et al., 2013) sediments. The transition appears to include a brief interval of normal polarity prior to the entry into the Brunhes Normal Chron (Coe et al., 2004; Jin et al., 2012; Evans et al., 2011), and the transition has Virtual Geomagnetic Poles rapidly moving from the Southern Hemisphere to the Northern Hemisphere (Coe et al., 2004; Jin et al., 2012; Evans et al., 2011; Sagnotti et al., 2013). The M/B polarity transition is recorded in exposed Pleistocene lake sediments near Bishop, CA, where the brief interval of normal polarity noted above is present and the change from full reverse to full normal polarity occurs rapidly. The brief interval of normal polarity is recorded at two sites separated laterally by about 150 m and is in single hand samples measured at vertical spacing of 2.0-2.5 cm using six samples per measured level and alternating field demagnetization at 20 mT (Liddicoat, 1993, Table 1 and Fig. 8). The siltstone is unweathered glacial flour from the Sierra Nevada that borders the western side of Owens Valley where the sediments were deposited in Owens Lake. In the siltstone, the majority of the samples have a percentage of about 60 percent where the grain diameter is less than 63 micrometres, and in those samples there is about a five percent fraction when the diameter is two micrometres or less. The Total Inorganic Carbon in most samples is about 0.25 percent (Bergeron, 2013), and magnetite is the dominant carrier of the magnetization (Liddicoat, 1993). The palaeomagnetic directions recording the terminus of the full M/B transition, which occurs before the field intensity is completely recovered, spans no

Lacustrine turbidites as a tool for quantitative earthquake reconstruction: New evidence for a variable rupture mode in south central Chile

NASA Astrophysics Data System (ADS)

Moernaut, Jasper; Daele, Maarten Van; Heirman, Katrien; Fontijn, Karen; Strasser, Michael; Pino, Mario; Urrutia, Roberto; De Batist, Marc

2014-03-01

Understanding the long-term earthquake recurrence pattern at subduction zones requires continuous paleoseismic records with excellent temporal and spatial resolution and stable threshold conditions. South central Chilean lakes are typically characterized by laminated sediments providing a quasi-annual resolution. Our sedimentary data show that lacustrine turbidite sequences accurately reflect the historical record of large interplate earthquakes (among others the 2010 and 1960 events). Furthermore, we found that a turbidite's spatial extent and thickness are a function of the local seismic intensity and can be used for reconstructing paleo-intensities. Consequently, our multilake turbidite record aids in pinpointing magnitudes, rupture locations, and extent of past subduction earthquakes in south central Chile. Comparison of the lacustrine turbidite records with historical reports, a paleotsunami/subsidence record, and a marine megaturbidite record demonstrates that the Valdivia Segment is characterized by a variable rupture mode over the last 900 years including (i) full ruptures (Mw ~9.5: 1960, 1575, 1319 ± 9, 1127 ± 44), (ii) ruptures covering half of the Valdivia Segment (Mw ~9: 1837), and (iii) partial ruptures of much smaller coseismic slip and extent (Mw ~7.5-8: 1737, 1466 ± 4). Also, distant or smaller local earthquakes can leave a specific sedimentary imprint which may resolve subtle differences in seismic intensity values. For instance, the 2010 event at the Maule Segment produced higher seismic intensities toward southeastern localities compared to previous megathrust ruptures of similar size and extent near Concepción.

Passive Sampling of Nonpolar Compounds in Sediments

DTIC Science & Technology

2010-12-02

Example 1: pore water sniffing PAHs/PCBs/HCB in harbor sediments ES&T 37: 4213-4220,2003 LDPE strips in sediment slurries and stagnant sediments...slurry stagnant ~160 g sediment (1-4% oc) ~120 mL water 0.5 g LDPE (30x2.5 cm) 50 d exposure chrysene msed Kd ≈1000 L ms Ksw ≈ 300 L ( or ) Koc from...silicone ! SPME! POG! LDPE ! Chemcatcher ! SPMD! POCIS! Mesco I 300 200 100 2 3 4 5 6 7 8 N ( n g ) log Kow Cw = 1 ng / L week 123456 Evolution of peak pattern

Advancing the Use of Passive Sampling in Risk Assessment and Management of Sediments Contaminated with Hydrophobic Organic Chemicals: Results of an International Ex Situ Passive Sampling Interlaboratory Comparison

PubMed Central

2018-01-01

This work presents the results of an international interlaboratory comparison on ex situ passive sampling in sediments. The main objectives were to map the state of the science in passively sampling sediments, identify sources of variability, provide recommendations and practical guidance for standardized passive sampling, and advance the use of passive sampling in regulatory decision making by increasing confidence in the use of the technique. The study was performed by a consortium of 11 laboratories and included experiments with 14 passive sampling formats on 3 sediments for 25 target chemicals (PAHs and PCBs). The resulting overall interlaboratory variability was large (a factor of ∼10), but standardization of methods halved this variability. The remaining variability was primarily due to factors not related to passive sampling itself, i.e., sediment heterogeneity and analytical chemistry. Excluding the latter source of variability, by performing all analyses in one laboratory, showed that passive sampling results can have a high precision and a very low intermethod variability (sampling, irrespective of the specific method used, is fit for implementation in risk assessment and management of contaminated sediments, provided that method setup and performance, as well as chemical analyses are quality-controlled. PMID:29488382

Sample preparation for the determination of 241Am in sediments utilizing gamma-spectroscopy.

PubMed

Ristic, M; Degetto, S; Ast, T; Cantallupi, C

2002-01-01

This paper describes a procedure developed to separate americium-241 from the bulk of a sample by coprecipitation followed by high sensitivity gamma-counting of the concentrate in a well-type detector. It enables the measurement of 241Am at low concentrations, e.g. fallout levels in soils and sediments, or where large sample sizes are not available. The method is much faster and more reliable than those involving separation from other alpha-emitters, electroplating and alpha-spectrometry. A number of tracer experiments was performed in order to optimize the conditions for coprecipitation of 241Am from sediment leachates. The general outline of the determination of americium is also given.

Evidence for sub-lacustrine volcanic activity in Lake Bolsena (central Italy) revealed by high resolution seismic data sets

NASA Astrophysics Data System (ADS)

Lindhorst, Katja; Krastel, Sebastian; Wagner, Bernd; Schuerer, Anke

2017-06-01

The Bolsena caldera that formed between 0.6 and 0.2 Ma has a well preserved structural rim, which makes it an ideal site to study the tectonic and volcanic evolution of calderas. However, the main area is covered by a 150 m deep lake which makes it rather difficult to investigate the subsurface structure directly. To overcome this problem new high resolution hydro-acoustic surveys using a multichannel reflection seismic system and a sediment echo-sounder system were conducted in September 2012. As space was limited we used a rowing boat towed by a rubber boat to handle a 36 m long and 24 channel streamer to receive seismic reflections produced using a Mini GI-Gun (0.25 l). The subsurface structure of Lake Bolsena was imaged up to a sediment depth of 190 m, which is estimated to have filled over a period of 333 kyrs. However, massive pyroclastic flow deposits found in the deeper parts of the basin indicate an initial infill of volcanic deposits from two adjacent younger calderas, the Latera (W) and Montefiascone (SE) calderas. Our data suggest that the caldera has a long history of active volcanism, because the lacustrine sediments show post-sedimentary influences of geothermal fluids. We mapped several mound structures at various stratigraphic depths. Two volcanic structures outcrop at the modern lake surface implying recent activity. One of these structures is hardly covered by sediments and has a crater-like feature in its summit. The other structure shows a pockmark-like depression on top. Another observable feature is a partially sediment filled crater located in the western part of the lake which further implies the existence of a magma chamber located beneath the Bolsena caldera. Since the late Pleistocene and Holocene, the sedimentation was mainly hemipelagic evidenced by a sediment drape of up to 10 m thick sediment drape on the uppermost sediments. Beneath the drape we found evidence for a distal tephra layer likely related to an explosive eruption from

Carbon Cycle Dynamics through the Early Eocene Climatic Optimum: Orbital Couplings to Lacustrine Cycling

NASA Astrophysics Data System (ADS)

Rosengard, S. Z.; Grogan, D. S.; Whiteside, J. H.; van Keuren, M.; Musher, D.

2010-12-01

The early Eocene represents the most recent hothouse climate state of Earth history, a period during which Earth’s surface temperatures warmed and reached a steady peak at the Early Eocene Climatic Optimum (EECO), 53.5-50 Ma. Interspersed through the primary warming interval were several hyperthermals, or rapid peaks in surface temperature and pulses of carbon dioxide into the atmosphere, followed by rapid declines, lasting 10^4 to 10^5 years. Various hypotheses have been offered to explain the climatic triggers during the hothouse interval, including changes in ocean circulation, methane release from hydrates, volcanism, and turnover of terrestrial organic matter, implicating various couplings and feedbacks in the global carbon cycle. The present study investigates the prevailing changes in carbon cycle dynamics that occurred during a specific subinterval of the Early Eocene Climatic Optimum. We sampled a carbon-rich 300-ft ( 1100 kyr) section of lacustrine Green River Formation sediments from the TOSCO core in the Uinta Basin at a one-foot resolution for organic carbon content and δ^{13}C. The compiled data comprise a high-resolution profile of total organic carbon and isotopic organic carbon composition through the section, showing cyclic patterns that we hypothesize reflect orbital signals. Bulk isotopic carbon and shale oil measurements from an earlier Fischer Assay across TOSCO’s entire 1030-ft core were then filtered using the expected frequency of a 23-kyr precession cycle. The overlaid cycles reveal δ^{13}C and oil content to be anti-phase through the 300-ft section, except for an interval of 50 feet (180 kyr) from the Mahogany Zone to the B-groove of the core, where the two measurements are in-phase. Given that shale oil, a proxy for lake primary productivity and carbon burial, and δ^{13}C typically correlate inversely, this short, 180-kyr interval of in-phase variation suggests a significant alteration in the local carbon cycle. These preliminary

Spawning migration of lacustrine-adfluvial bull trout in a natural area

USGS Publications Warehouse

Brenkman, Samuel J.; Larson, Gary L.; Gresswell, Robert E.

2001-01-01

We investigated the spawning migration of lacustrine-adfluvial bull trout Salvelinus confluentus in the North Fork Skokomish River in Olympic National Park (Washington State) during 1996. Day-snorkeling and electrofishing were conducted to determine timing and duration of the migration and the distribution and abundance of bull trout. The primary spawning migration began in early October and was waning by December. Bull trout migrated 6 km or less up the river from Lake Cushman. Increased river discharge and decreased water temperature appeared to be the primary environmental variables corresponding to the initiation of the migration. Mean length of migratory bull trout increased from June to December. Comparisons with other lacustrine-adfluvial bull trout populations in Oregon, Montana, Idaho, and British Columbia suggested that these populations exhibit specific migratory strategies related to local environmental conditions.

Sources and proxy potential of long chain alkyl diols in lacustrine environments

NASA Astrophysics Data System (ADS)

Rampen, Sebastiaan W.; Datema, Mariska; Rodrigo-Gámiz, Marta; Schouten, Stefan; Reichart, Gert-Jan; Sinninghe Damsté, Jaap S.

2014-11-01

Long chain 1,13- and 1,15-alkyl diols form the base of a number of recently proposed proxies used for climate reconstruction. However, the sources of these lipids and environmental controls on their distribution are still poorly constrained. We have analyzed the long chain alkyl diol (LCD) composition of cultures of ten eustigmatophyte species, with three species from different families grown at various temperatures, to identify the effect of species composition and growth temperature on the LCD distribution. The results were compared with the LCD distribution of sixty-two lake surface sediments, and with previously reported LCD distributions from marine environments. The different families within the Eustigmatophyceae show distinct LCD patterns, with the freshwater family Eustigmataceae most closely resembling LCD distributions in both marine and lake environments. Unlike the other two eustigmatophyte families analyzed (Monodopsidaceae and Goniochloridaceae), C28 and C30 1,13-alkyl diols and C30 and C32 1,15-alkyl diols are all relatively abundant in the family Eustigmataceae, while the mono-unsaturated C32 1,15-alkyl diol was below detection limit. In contrast to the marine environment, LCD distributions in lakes did not show a clear relationship with temperature. The Long chain Diol Index (LDI), a proxy previously proposed for sea surface temperature reconstruction, showed a relatively weak correlation (R2 = 0.33) with mean annual air temperature used as an approximation for annual mean surface temperature of the lakes. A much-improved correlation (R2 = 0.74, p-value <0.001) was observed applying a multiple linear regression analysis between LCD distributions and lake temperatures reconstructed using branched tetraether lipid distributions. The obtained regression model provides good estimates of temperatures for cultures of the family Eustigmataceae, suggesting that algae belonging to this family have an important role as a source for LCDs in lacustrine

Ecological state of the Romanian Black Sea littoral lacustrine ecosystems

NASA Astrophysics Data System (ADS)

Gomoiu, M.-T.

2009-04-01

The author uses the results of his own researches as well as data from specialty literature to assess the ecological state of some typical lacustrine ecosystems considered, about 50 years ago, of major importance by their functions, services and researches, for the human populations in the settlements nearby. Based on this assessment the author recommends a few criteria which can be taken into account when programs of integrated management of these coastal ecosystems are initiated. The paper focuses on the study cases regarding the following major ecosystems: 1. Razelm-Sinoie Lagoon Complex - tightly linked to the Danube River and Delta systems, 2. Taşaul Lake - interfered in the last two decades by a branch of the DanubeRiver - Black Sea Canal and 3. Techirghiol Lake - for a long time under the sea level, a hyperhaline lake with therapeutic, sapropelic mud, disturbed by huge quantities of freshwaters infiltrated from the irrigation system. At present, the state of the lacustrine ecosystems at the Romanian Black Sea Coast can be characterized, mainly, by the following aspects: · Increase in the quantities of nutrients and chemical toxicants; · Rise in the level and frequency of eutrophication and pollution phenomena; · Drastic reduction of specific diversity; · Simplification of communities' structure - biocoenosis homogeneity; · Decrease in numerical abundance and biomass of benthic populations and consequently, low biofilter power by the decrease of the filter-feeder populations; · Worsening of the qualitative and the quantitative state of the biological benthic resources; · Thriving opportunistic forms (e.g. the worms causing sediment bioturbation); · Invasion by some exotic species, with harmful, unexpected consequences; · All populations undergo quantitative fluctuations; · Decrease in the fish population and in the use values of lacustrine assets, with strong impact on the welfare of the human society. Almost all pressure forms associated with the

Fine Increment Soil Collector (FISC): A new device to support high resolution soil and sediment sampling for agri-environmental assessments

NASA Astrophysics Data System (ADS)

Mabit, Lionel; Meusburger, Katrin; Iurian, Andra-Rada; Owens, Philip N.; Toloza, Arsenio; Alewell, Christine

2014-05-01

Soil and sediment related research for terrestrial agri-environmental assessments requires accurate depth incremental sampling of soil and exposed sediment profiles. Existing coring equipment does not allow collecting soil/sediment increments at millimetre resolution. Therefore, the authors have designed an economic, portable, hand-operated surface soil/sediment sampler - the Fine Increment Soil Collector (FISC) - which allows extensive control of soil/sediment sampling process and easy recovery of the material collected by using a simple screw-thread extraction system. In comparison with existing sampling tools, the FISC has the following advantages and benefits: (i) it permits sampling of soil/sediment samples at the top of the profile; (ii) it is easy to adjust so as to collect soil/sediment at mm resolution; (iii) it is simple to operate by one single person; (iv) incremental samples can be performed in the field or at the laboratory; (v) it permits precise evaluation of bulk density at millimetre vertical resolution; and (vi) sample size can be tailored to analytical requirements. To illustrate the usefulness of the FISC in sampling soil and sediments for 7Be - a well-known cosmogenic soil tracer and fingerprinting tool - measurements, the sampler was tested in a forested soil located 45 km southeast of Vienna in Austria. The fine resolution increments of 7Be (i.e. 2.5 mm) affects directly the measurement of the 7Be total inventory but above all impacts the shape of the 7Be exponential profile which is needed to assess soil movement rates. The FISC can improve the determination of the depth distributions of other Fallout Radionuclides (FRN) - such as 137Cs, 210Pbexand239+240Pu - which are frequently used for soil erosion and sediment transport studies and/or sediment fingerprinting. Such a device also offers great potential to investigate FRN depth distributions associated with fallout events such as that associated with nuclear emergencies. Furthermore, prior

Passive sampling methods for contaminated sediments: Scientific rationale supporting use of freely dissolved concentrations

PubMed Central

Mayer, Philipp; Parkerton, Thomas F; Adams, Rachel G; Cargill, John G; Gan, Jay; Gouin, Todd; Gschwend, Philip M; Hawthorne, Steven B; Helm, Paul; Witt, Gesine; You, Jing; Escher, Beate I

2014-01-01

Passive sampling methods (PSMs) allow the quantification of the freely dissolved concentration (Cfree) of an organic contaminant even in complex matrices such as sediments. Cfree is directly related to a contaminant's chemical activity, which drives spontaneous processes including diffusive uptake into benthic organisms and exchange with the overlying water column. Consequently, Cfree provides a more relevant dose metric than total sediment concentration. Recent developments in PSMs have significantly improved our ability to reliably measure even very low levels of Cfree. Application of PSMs in sediments is preferably conducted in the equilibrium regime, where freely dissolved concentrations in the sediment are well-linked to the measured concentration in the sampler via analyte-specific partition ratios. The equilibrium condition can then be assured by measuring a time series or a single time point using passive samplers with different surface to volume ratios. Sampling in the kinetic regime is also possible and generally involves the application of performance reference compounds for the calibration. Based on previous research on hydrophobic organic contaminants, it is concluded that Cfree allows a direct assessment of 1) contaminant exchange and equilibrium status between sediment and overlying water, 2) benthic bioaccumulation, and 3) potential toxicity to benthic organisms. Thus, the use of PSMs to measure Cfree provides an improved basis for the mechanistic understanding of fate and transport processes in sediments and has the potential to significantly improve risk assessment and management of contaminated sediments. Integr Environ Assess Manag 2014;10:197–209. © 2014 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of SETAC. PMID:24288295

Molecular Detection of Avian Influenza Virus from Sediment Samples in Waterfowl Habitats on the Delmarva Peninsula, United States.

PubMed

Densmore, C L; Iwanowicz, D D; Ottinger, C A; Hindman, L J; Bessler, A M; Iwanowicz, L R; Prosser, D J; Whitbeck, M; Driscoll, C P

2017-12-01

Avian influenza viruses (AIV) affect many species of birds including waterfowl and may persist in sediment in aquatic habitats. Sediment samples were collected from two areas representative of prime migration and overwintering waterfowl habitat in Dorchester County, Maryland in the fall and winter of 2013-2014. Samples were screened for the presence of AIV via reverse transcriptase-quantitative PCR targeting the matrix gene. Although 13.6% of sediment samples were positive for the AIV matrix gene across all collection dates and locations, differences in detection were noted with location and collection season. Percentage of AIV-positive sediment samples recovered corresponded to trends in waterfowl abundance at collection sites both temporally and spatially. These findings provide further support for the assertion that the presence of AIV in the aquatic environment is likely affected by the total number, site-specific density, and array of waterfowl species.

Feast to famine: Sediment supply control on Laramide basin fill

NASA Astrophysics Data System (ADS)

Carroll, Alan R.; Chetel, Lauren M.; Elliot Smith, M.

2006-03-01

Erosion of Laramide-style uplifts in the western United States exerted an important first-order influence on Paleogene sedimentation by controlling sediment supply rates to adjacent closed basins. During the latest Cretaceous through Paleocene, these uplifts exposed thick intervals of mud-rich Upper Cretaceous foreland basin fill, which was quickly eroded and redeposited. Cretaceous sedimentary lithologies dominate Paleocene conglomerate clast compositions, and the volume of eroded foreland basin strata is approximately twice the volume of preserved Paleocene basin fill. As a result of this sediment oversupply, clastic alluvial and paludal facies dominate Paleocene strata, and are associated with relatively shallow and ephemeral freshwater lake facies. In contrast, large, long-lived, carbonate-producing lakes occupied several of the basins during the Eocene. Basement-derived clasts (granite, quartzite, and other metamorphic rocks) simultaneously became abundant in lower Eocene conglomerate. We propose that Eocene lakes developed primarily due to exposure of erosion-resistant lithologies within cores of Laramide uplifts. The resultant decrease in erosion rate starved adjacent basins of sediment, allowing the widespread and prolonged deposition of organic-rich lacustrine mudstone. These observations suggest that geomorphic evolution of the surrounding landscape should be considered as a potentially important influence on sedimentation in many other interior basins, in addition to more conventionally interpreted tectonic and climatic controls.

Seismic wave velocity of hydrate-bearing fine-grained sediments sampled from the Ulleung basin in East Sea, Korea

NASA Astrophysics Data System (ADS)

Kim, H.; Kwon, T.; Cho, G.

2012-12-01

Synthesizing gas hydrate in a fine-grained natural seabed sediment sample, mainly composed of silty-to-clayey soils, has been hardly attempted due to the low permeability. It has been known that hydrate loci in pore spaces and heterogeneity of hydrate growth in core-scale play a critical role in determining physical properties of hydrate-bearing sediments. In the presented study, we attempted to identify the effect of hydrate growth morphology on seismic velocities in natural fine-grained sediments sampled from the Ulleung Basin in East Sea. We synthesized CO2 hydrate in clayey silt sediments in an instrumented oedometric cell and measured seismic velocities during hydrate formation and loading processes. Herein, we present the experiment results on P-wave and S-wave velocities of gas hydrate-bearing fine-grained sediments. It is found that the geophysical properties of gas hydrate-bearing sediments are governed by hydrate saturation and effective stress as well as morphological feature of hydrate formation in sediments.

Bed-Sediment Sampling and Analysis for Physical and Chemical Properties of the Lower Mississippi River near Memphis, Tennessee

USGS Publications Warehouse

Blanchard, Robert A.; Wagner, Daniel M.; Evans, Dennis A.

2010-01-01

In February 2010, the U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers, Memphis District, investigated the presence of inorganic elements and organic compounds in bed sediments of the lower Mississippi River. Selected sites were located in the navigation channel near river miles 737, 773, and 790 near Memphis, Tennessee. Bed-sediment samples were collected using a Shipek grab sampler mounted to a boom crane with a motorized winch. Samples then were processed and shipped to the U.S. Geological Survey Sediment Laboratory in Rolla, Missouri, the USGS National Water Quality Laboratory in Denver, Colorado, and to TestAmerica Laboratory, Inc. in West Sacramento, California. Samples were analyzed for grain size, inorganic elements (including mercury), and organic compounds. Chemical results were tabulated and listed with sediment-quality guidelines and presented with the physical property results. All of the bed material samples collected during this investigation yielded concentrations that were less than the Consensus-Based Probable Effect Concentration guidelines. The physical properties were tabulated and listed using a standard U.S. Geological Survey scale of sizes by class for sediment analysis. All of the samples collected during this investigation indicated a percent composition mostly comprised of sand, ranging from less than 0.125 millimeters to less than 2 millimeters.

Marine sediment sample preparation for analysis for low concentrations of fine detrital gold

USGS Publications Warehouse

Clifton, H. Edward; Hubert, Arthur; Phillips, R. Lawrence

1967-01-01

Analyses by atomic absorption for detrital gold in more than 2,000 beach, offshore, marine-terrace, and alluvial sands from southern Oregon have shown that the values determined from raw or unconcentrated sediment containing small amounts of gold are neither reproducible nor representative of the initial sample. This difficulty results from a 'particle sparsity effect', whereby the analysis for gold in a given sample depends more upon the occurrence of random flakes of gold in the analyzed portion than upon the actual gold content of the sample. The particle sparsity effect can largely be eliminated by preparing a gold concentrate prior to analysis. A combination of sieve, gravimetric, and magnetic separation produces a satisfactory concentrate that yields accurate and reproducible analyses. In concentrates of nearly every marine and beach sand studied, the gold occurs in the nonmagnetic fraction smaller than 0.124 mm and with a specific gravity greater than 3.3. The grain size of gold in stream sediments is somewhat more variable. Analysis of concentrates provides a means of greatly increasing the sensitivity of the analytical technique in relation to the initial sample. Gold rarely exceeds 1 part per million in even the richest black sand analyzed; to establish the distribution of gold (and platinum) in marine sediments and its relationship to source and environmental factors, one commonly needs to know their content to the part per billion range. Analysis of a concentrate and recalculation to the value in the initial sample permits this degree of sensitivity.

Lacustrine Environment Reservoir Properties on Sandstone Minerals and Hydrocarbon Content: A Case Study on Doba Basin, Southern Chad

NASA Astrophysics Data System (ADS)

Sumery, N. F. Mohd; Lo, S. Z.; Salim, A. M. A.

2017-10-01

The contribution of lacustrine environment as the hydrocarbon reservoir has been widely known. However, despite its growing importance, the lacustrine petroleum geology has received far less attention than marine due to its sedimentological complexity. This study therefore aims in developing an understanding of the unique aspects of lacustrine reservoirs which eventually impacts the future exploration decisions. Hydrocarbon production in Doba Basin, particularly the northern boundary, for instance, has not yet succeeded due to the unawareness of its depositional environment. The drilling results show that the problems were due to the: radioactive sand and waxy oil/formation damage, which all are related to the lacustrine depositional environment. Detailed study of geological and petrophysical integration on wireline logs and petrographic thin sections analysis of this environment helps in distinguishing reservoir and non-reservoir areas and determining the possible mechanism causing the failed DST results. The interpretations show that the correlation of all types> of logs and rho matrix analysis are capable in identifying sand and shale bed despite of the radioactive sand present. The failure of DST results were due to the presence of arkose in sand and waxy oil in reservoir bed. This had been confirmed by the petrographic thin section analysis where the arkose has mineral twinning effect indicate feldspar and waxy oil showing bright colour under fluorescent light. Understanding these special lacustrine environment characteristics and features will lead to a better interpretation of hydrocarbon prospectivity for future exploration.

Advancing the Use of Passive Sampling in Risk Assessment and Management of Sediments Contaminated with Hydrophobic Organic Chemicals: Results of an International Ex Situ Passive Sampling Interlaboratory Comparison

EPA Science Inventory

This work presents the results of an international interlaboratory comparison on ex situ passive sampling in sediments. The main objectives were to map the state of the science in passively sampling sediments, identify sources of variability, provide recommendations and practical...

Advancing the Use of Passive Sampling in Risk Assessment and Management of Sediments Contaminated with Hydrophobic Organic Chemicals: Results of an International Ex Situ Passive Sampling Interlaboratory Comparison

EPA Science Inventory

This work presents the results of an international interlaboratory comparison on ex situ passive sampling in sediments. The main objectives were to map the state of the science in passively sampling sediments, identify sources of variability, provide recommendations and practica...

Sedimentary Basin Structure of the Hadar Formation's Lacustrine-Dominated Depocenter (Ledi-Geraru, Afar, Ethiopia) and its Relevance for Investigating Hominin Paleoenvironments

NASA Astrophysics Data System (ADS)

Dimaggio, E. N.; Campisano, C. J.; Arrowsmith, J. R.; Dupont-Nivet, G.; Johnson, R. A.; Warren, M. B.

2008-12-01

Sedimentary sequences preserved in East African rift basins record the long-term response of past depositional environments to climatic and tectonic forcing. Motivations for recent field investigations at the Ledi-Geraru site, part of the greater Hadar sedimentary basin in the Afar region of Ethiopia, stem from a need to characterize local basin structure and expand and refine interpretations of the complex mid-late Pliocene history of local and regional-scale landscape change during a time of critical importance for understanding hominin evolution. Detailed geologic mapping (1:7,000), measured stratigraphic sections, and seismic reflection surveys provide the datasets necessary for basin evaluation. The Ledi-Geraru sedimentary sequence (>250m thick) exposes nearly the entirety of the hominin-bearing Hadar Formation of west- central Afar. Both primary unmodified lake deposits and intervals modified by subsequent subaerial exposure and pedogenesis are well-exposed. The lacustrine-dominated signature is indicated by the prevalence of laminated silty clays that contain leaf impressions, fish scales, and gastropod shells, undisturbed laminated diatomite and clays, and pedogenically modified diatomaceous silts. The sequence is generally flat lying, with low bedding dips ranging from 0-2° NNW to <1° NNE and minor NNW trending faults with <5 m vertical offset. Whereas coeval fluvio-lacustrine sediments associated with hominin and archaeological sites west of Ledi-Geraru (e.g., Hadar and Gona) are marked by comparatively slow and episodic sedimentation, sedimentation rates in the Ledi-Geraru sequence are extremely high and consistent, on the order of ~0.9-1.0mm/yr. Laterally extensive tephra marker beds and paleomagnetic records provide excellent age control for sedimentation rate estimates and correlation to nearby fossil-rich sequences. As the Hadar basin sediments preserve a rich paleoanthropologic and archaeological record, this work provides the geologic framework

Cenozoic record of aeolian sediment accumulation and aridification from Lanzhou, China, driven by Tibetan Plateau uplift and global climate

NASA Astrophysics Data System (ADS)

Zhang, Yuebao; Sun, Donghuai; Li, Zaijun; Wang, Fei; Wang, Xin; Li, Baofeng; Guo, Feng; Wu, Sheng

2014-09-01

Previous work has shown that aeolian Red Clay first appears at around 8 Ma in the main Chinese Loess Plateau and at 25-22 Ma in the western Loess Plateau; however, records of aeolian deposition in the North Pacific suggest that aeolian accumulation occurred throughout the Cenozoic, and that changes in aeolian flux occurred in distinct stages. Tracing the Cenozoic aeolian history of the interior of the Asian continent may help us to understand the history of Asian aridification and its driving forces. In the Lanzhou area on the western margin of the Loess Plateau and the northeastern edge of the Tibetan Plateau, the Cenozoic stratigraphic sequence consists of fluvial-lacustrine sediments in the lower part, aeolian Red Clay with intercalated fluvial layers in the middle part, and predominantly aeolian loess in the upper part. We use high resolution paleomagnetic measurements of this sequence to construct a time scale, and measurements of sediment rock magnetic properties, grain-size, and color reflectance and sedimentary facies analysis to reconstruct the paleoenvironment. The results show that prior to 33 Ma the area was dominantly a fluvial-lacustrine environment, and that subsequently an aridification trend commenced, as indicated by the appearance of aeolian sediment. This change coincided with, and is thus explained as the environmental response to global cooling. A significant increase in aeolian sediments occurred at ~ 26 Ma, suggesting that a large scale arid environment had formed in the Asian interior since the late Oligocene. Stepwise increases of aeolian sediment, and decreases in sediments of hydraulic origin, occurred at ~ 22, ~ 14, ~ 8 and 2.6 Ma and represent important stages in the aridification process. This long-term trend was interrupted by intervals dominated by fluvial sedimentation at 23.6-22 Ma and 17.1-14.1 Ma and which were probably associated with warming of the global climate and the tectonic uplift of the northeastern Tibetan Plateau

Comparative sequence stratigraphy of low-latitude versus high-latitude lacustrine rift basins: Seismic data examples from the East African and Baikal rifts

USGS Publications Warehouse

Scholz, C.A.; Moore, T.C.; Hutchinson, D.R.; Golmshtok, A. Ja; Klitgord, Kim D.; Kurotchkin, A.G.

1998-01-01

Lakes Baikal, Malawi and Tanganyika are the world's three largest rift valley lakes and are the classic modem examples of lacustrine rift basins. All the rift lakes are segmented into half-graben basins, and seismic reflection datasets reveal how this segmentation controls the filling of the rift basins through time. In the early stages of rifting, basins are fed primarily by flexural margin and axial margin drainage systems. At the climax of syn-rift sedimentation, however, when the basins are deeply subsided, almost all the margins are walled off by rift shoulder uplifts, and sediment flux into the basins is concentrated at accommodation zone and axial margin river deltas. Flexural margin unconformities are commonplace in the tropical lakes but less so in high-latitude Lake Baikal. Lake levels are extremely dynamic in the tropical lakes and in low-latitude systems in general because of the predominance of evaporation in the hydrologic cycle in those systems. Evaporation is minimized in relation to inflow in the high-latitude Lake Baikal and in most high-latitude systems, and consequently, major sequence boundaries tend to be tectonically controlled in that type of system. The acoustic stratigraphies of the tropical lakes are dominated by high-frequency and high-amplitude lake level shifts, whereas in high-latitude Lake Baikal, stratigraphic cycles are dominated by tectonism and sediment-supply variations.

Organic contaminants, trace and major elements, and nutrients in water and sediment sampled in response to the Deepwater Horizon oil spill

USGS Publications Warehouse

Nowell, Lisa H.; Ludtke, Amy S.; Mueller, David K.; Scott, Jonathon C.

2012-01-01

Beach water and sediment samples were collected along the Gulf of Mexico coast to assess differences in contaminant concentrations before and after landfall of Macondo-1 well oil released into the Gulf of Mexico from the sinking of the British Petroleum Corporation's Deepwater Horizon drilling platform. Samples were collected at 70 coastal sites between May 7 and July 7, 2010, to document baseline, or "pre-landfall" conditions. A subset of 48 sites was resampled during October 4 to 14, 2010, after oil had made landfall on the Gulf of Mexico coast, called the "post-landfall" sampling period, to determine if actionable concentrations of oil were present along shorelines. Few organic contaminants were detected in water; their detection frequencies generally were low and similar in pre-landfall and post-landfall samples. Only one organic contaminant--toluene--had significantly higher concentrations in post-landfall than pre-landfall water samples. No water samples exceeded any human-health benchmarks, and only one post-landfall water sample exceeded an aquatic-life benchmark--the toxic-unit benchmark for polycyclic aromatic hydrocarbons (PAH) mixtures. In sediment, concentrations of 3 parent PAHs and 17 alkylated PAH groups were significantly higher in post-landfall samples than pre-landfall samples. One pre-landfall sample from Texas exceeded the sediment toxic-unit benchmark for PAH mixtures; this site was not sampled during the post-landfall period. Empirical upper screening-value benchmarks for PAHs in sediment were exceeded at 37 percent of post-landfall samples and 22 percent of pre-landfall samples, but there was no significant difference in the proportion of samples exceeding benchmarks between paired pre-landfall and post-landfall samples. Seven sites had the largest concentration differences between post-landfall and pre-landfall samples for 15 alkylated PAHs. Five of these seven sites, located in Louisiana, Mississippi, and Alabama, had diagnostic

Facies analysis, palaeoenvironmental reconstruction and stratigraphic development of the Early Cretaceous sediments (Lower Bima Member) in the Yola Sub-basin, Northern Benue Trough, NE Nigeria

NASA Astrophysics Data System (ADS)

Sarki Yandoka, Babangida M.; Abubakar, M. B.; Abdullah, Wan Hasiah; Amir Hassan, M. H.; Adamu, Bappah U.; Jitong, John S.; Aliyu, Abdulkarim H.; Adegoke, Adebanji Kayode

2014-08-01

The Benue Trough of Nigeria is a major rift basin formed from the tension generated by the separation of African and South American plates in the Early Cretaceous. It is geographically sub-divided into Southern, Central and Northern Benue portions. The Northern Benue Trough comprises two sub-basins; the N-S trending Gongola Sub-basin and the E-W trending Yola Sub-basin. The Bima Formation is the oldest lithogenetic unit occupying the base of the Cretaceous successions in the Northern Benue Trough. It is differentiated into three members; the Lower Bima (B1), the Middle Bima (B2) and the Upper Bima (B3). Facies and their stratigraphical distribution analyses were conducted on the Lower Bima Member exposed mainly at the core of the NE-SW axially trending Lamurde Anticline in the Yola Sub-basin, with an objective to interpret the paleodepositional environments, and to reconstruct the depositional model and the stratigraphical architecture. Ten (10) lithofacies were identified on the basis of lithology, grain size, sedimentary structures and paleocurrent analysis. The facies constitute three (3) major facies associations; the gravelly dominated, the sandy dominated and the fine grain dominated. These facies and facies associations were interpreted and three facies successions were recognized; the alluvial-proximal braided river, the braided river and the lacustrine-marginal lacustrine. The stratigraphic architecture indicates a rifted (?pull-apart) origin as the facies distribution shows a progradational succession from a shallow lacustrine/marginal lacustrine (at the axial part of the basin) to alluvial fan (sediment gravity flow)-proximal braided river (gravel bed braided river) and braided river (channel and overbank) depositional systems. The facies stacking patterns depict sedimentation mainly controlled by allogenic factors of climate and tectonism.

Paleogeographic implications of Late Miocene lacustrine and nonmarine evaporite deposits in the Lake Mead region: Immediate precursors to the Colorado River

USGS Publications Warehouse

Faulds, James E.; Schreiber, Charlotte; Langenheim, Victoria; Hinz, Nicholas H.; Shaw, Tom; Heizler, Matthew T.; Perkins, Michael E; El Tabakh, Mohammed; Kunk, Michael J.

2016-01-01

Thick late Miocene nonmarine evaporite (mainly halite and gypsum) and related lacustrine limestone deposits compose the upper basin fill in half grabens within the Lake Mead region of the Basin and Range Province directly west of the Colorado Plateau in southern Nevada and northwestern Arizona. Regional relations and geochronologic data indicate that these deposits are late synextensional to postextensional (ca. 12–5 Ma), with major extension bracketed between ca. 16 and 9 Ma and the abrupt western margin of the Colorado Plateau established by ca. 9 Ma. Significant accommodation space in the half grabens allowed for deposition of late Miocene lacustrine and evaporite sediments. Concurrently, waning extension promoted integration of initially isolated basins, progressive enlargement of drainage nets, and development of broad, low gradient plains and shallow water bodies with extensive clastic, carbonate, and/or evaporite sedimentation. The continued subsidence of basins under restricted conditions also allowed for the preservation of particularly thick, localized evaporite sequences prior to development of the through-going Colorado River.The spatial and temporal patterns of deposition indicate increasing amounts of freshwater input during the late Miocene (ca. 12–6 Ma) immediately preceding arrival of the Colorado River between ca. 5.6 and 4.9 Ma. In axial basins along and proximal to the present course of the Colorado River, evaporite deposition (mainly gypsum) transitioned to lacustrine limestone progressively from east to west, beginning ca. 12–11 Ma in the Grand Wash Trough in the east and shortly after ca. 5.6 Ma in the western Lake Mead region. In several satellite basins to both the north and south of the axial basins, evaporite deposition was more extensive, with thick halite (>200 m to 2.5 km thick) accumulating in the Hualapai, Overton Arm, and northern Detrital basins. Gravity and magnetic lows suggest that thick halite may also lie within the

Mineralogy of an ancient lacustrine mudstone succession from the Murray formation, Gale crater, Mars

NASA Astrophysics Data System (ADS)

Rampe, E. B.; Ming, D. W.; Blake, D. F.; Bristow, T. F.; Chipera, S. J.; Grotzinger, J. P.; Morris, R. V.; Morrison, S. M.; Vaniman, D. T.; Yen, A. S.; Achilles, C. N.; Craig, P. I.; Des Marais, D. J.; Downs, R. T.; Farmer, J. D.; Fendrich, K. V.; Gellert, R.; Hazen, R. M.; Kah, L. C.; Morookian, J. M.; Peretyazhko, T. S.; Sarrazin, P.; Treiman, A. H.; Berger, J. A.; Eigenbrode, J.; Fairén, A. G.; Forni, O.; Gupta, S.; Hurowitz, J. A.; Lanza, N. L.; Schmidt, M. E.; Siebach, K.; Sutter, B.; Thompson, L. M.

2017-08-01

The Mars Science Laboratory Curiosity rover has been traversing strata at the base of Aeolis Mons (informally known as Mount Sharp) since September 2014. The Murray formation makes up the lowest exposed strata of the Mount Sharp group and is composed primarily of finely laminated lacustrine mudstone intercalated with rare crossbedded sandstone that is prodeltaic or fluvial in origin. We report on the first three drilled samples from the Murray formation, measured in the Pahrump Hills section. Rietveld refinements and FULLPAT full pattern fitting analyses of X-ray diffraction patterns measured by the MSL CheMin instrument provide mineral abundances, refined unit-cell parameters for major phases giving crystal chemistry, and abundances of X-ray amorphous materials. Our results from the samples measured at the Pahrump Hills and previously published results on the Buckskin sample measured from the Marias Pass section stratigraphically above Pahrump Hills show stratigraphic variations in the mineralogy; phyllosilicates, hematite, jarosite, and pyroxene are most abundant at the base of the Pahrump Hills, and crystalline and amorphous silica and magnetite become prevalent higher in the succession. Some trace element abundances measured by APXS also show stratigraphic trends; Zn and Ni are highly enriched with respect to average Mars crust at the base of the Pahrump Hills (by 7.7 and 3.7 times, respectively), and gradually decrease in abundance in stratigraphically higher regions near Marias Pass, where they are depleted with respect to average Mars crust (by more than an order of magnitude in some targets). The Mn stratigraphic trend is analogous to Zn and Ni, however, Mn abundances are close to those of average Mars crust at the base of Pahrump Hills, rather than being enriched, and Mn becomes increasingly depleted moving upsection. Minerals at the base of the Pahrump Hills, in particular jarosite and hematite, as well as enrichments in Zn, Ni, and Mn, are products of

Investigations of the Origin of the Magnetic Remanence in Late Pleistocene Lacustrine Sediments in the Mono Basin, CA

NASA Astrophysics Data System (ADS)

Vasquez, N.; Corley, A. D.

2015-12-01

In the Mono Basin, CA, fine sand, silt, and volcanic ash deposited in Pleistocene Lake Russell is exposed on the margin of Mono Lake, and on Paoha Island in the lake. The silt records the Mono Lake Excursion (MLE: Denham and Cox, 1971) and several tens of thousands of years of paleomagnetic secular variation (PSV: Denham and Cox, 1971; Liddicoat, 1976; Lund et al., 1988). The sediment is believed to be an accurate recorder of PSV because the MLE has the same signal at widely separated localities in the basin (Denham, 1974; Liddicoat and Coe, 1979; Liddicoat, 1992) with the exception at wave-cut cliffs on the southeast side of the lake (Coe and Liddicoat, 1994). Magnetite, titanomagnetite, and titanomaghemite are present in the sediment (Denham and Cox, 1971; Liddicoat, 1976; Liddicoat and Coe, 1979), which is glacial flour from the adjacent Sierra Nevada (Lajoie, 1968). X-rays of the sediment and lineation measurements show patterns of normal bedding with layers aligned such that the minimum axes are within 5-10 degrees of normal bedding, with 10 percent foliation and 1 percent lineation (Coe and Liddicoat, 1994). We explore reasons for the difference in part of the PSV record at the wave-cut cliffs beyond the interpretation of Coe and Liddicoat (1994) that paleomagnetic field strength is a controlling factor. Possibilities include the sedimentation rate - at localities on the margin of Mono Lake the rate is about 60 percent less than at the wave-cut cliffs - and lithology of the sediment. At Mill Creek on the northwest side of Mono Lake, the non-magnetic sediment fraction is coarser-grained than at the wave-cut cliffs by a factor of about two, and there is a similar difference in the total inorganic carbon (TIC) percentage by weight for the two localities. (Spokowski et al., 2011) Studies of the sediment at two localities in the basin where the Hilina Pali Excursion (Teanby et al., 2002) might be recorded (Wilson Creek and South Shore Cliffs; Liddicoat and Coe

Deltaic sedimentation and stratigraphic sequences in post-orogenic basins, Western Greece

NASA Astrophysics Data System (ADS)

Piper, David J. W.; Kontopoulos, N.; Panagos, A. G.

1988-03-01

Post-orogenic basin sediments in the gulfs of Corinth, Patras and Amvrakia, on the western coast of Greece, occur in four tectonic settings: (1) true graben; (2) simple and complex half graben; (3) shallow half graben associated with the high-angel surface traces of thrust faults; and (4) marginal depressions adjacent to graben in which sediment loading has occurred. Late Quaternary facies distribution has been mapped in all three basins. Sea level changes, interacting with the apparently fortuitous elevation of horsts at basin margins, result in a complex alternation of well-mixed marine, stratified marine, brackish and lacustrine facies. Organic carbon contents of muds are high in all but the well-mixed marine facies. Basin margin slope is the most important determinant of facies distribution. The steep slopes of the Gulf of Corinth half graben result in fan-deltas which deliver coarse sediments in turbidity currents to the deep basin floor. Where gradients are reduced by marginal downwarping (Gulf of Patras) or on the gentle slopes of thrust-related half graben (Gulf of Amvrakia) coarse sediments are trapped on the subaerial delta or the coastal zone, and the fine sediment reaching the basin floor appears derived mainly from muddy plumes during winter floods.

Diversity of methanogenic archaea in freshwater sediments of lacustrine ecosystems.

PubMed

Laskar, Folguni; Das Purkayastha, Sumi; Sen, Aniruddha; Bhattacharya, Mrinal K; Misra, Biswapriya B

2018-02-01

About half of the global methane (CH 4 ) emission is contributed by the methanogenic archaeal communities leading to a significant increase in global warming. This unprecedented situation has increased the ever growing necessity of evaluating the control measures for limiting CH 4 emission to the atmosphere. Unfortunately, research endeavors on the diversity and functional interactions of methanogens are not extensive till date. We anticipate that the study of the diversity of methanogenic community is paramount for understanding the metabolic processes in freshwater lake ecosystems. Although there are several disadvantages of conventional culture-based methods for determining the diversity of methanogenic archaeal communities, in order to understand their ecological roles in natural environments it is required to culture the microbes. Recently different molecular techniques have been developed for determining the structure of methanogenic archaeal communities thriving in freshwater lake ecosystem. The two gene based cloning techniques required for this purpose are 16S rRNA and methyl coenzyme M reductase (mcrA) in addition to the recently developed metagenomics approaches and high throughput next generation sequencing efforts. This review discusses the various methods of culture-dependent and -independent measures of determining the diversity of methanogen communities in lake sediments in lieu of the different molecular approaches and inter-relationships of diversity of methanogenic archaea. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Carbon and nitrogen isotope composition of core catcher samples from the ICDP deep drilling at Laguna Potrok Aike (Patagonia, Argentina)

NASA Astrophysics Data System (ADS)

Luecke, Andreas; Wissel, Holger; Mayr*, Christoph; Oehlerich, Markus; Ohlendorf, Christian; Zolitschka, Bernd; Pasado Science Team

2010-05-01

Glacial (up to 22.0 per mil) are only sporadically reached down core. Compared to this, separated moss debris is remarkably 13C depleted with a minimum at 31.5 per mil. The nitrogen isotope ratios of glacial Laguna Potrok Aike sediments are lower (2.5 per mil) than those of the younger part of the record. The core catcher samples indicate several oscillations between 0.5 and 3.5 per mil. Data suggest a correlation between nitrogen isotopes and C/N ratios, but no linear relation between carbon isotopes and carbon content and an only weak relationship between carbon and nitrogen isotopes. Increasing nitrogen isotope values from 8000 cm downwards could probably be related to changed environmental conditions of Marine Isotope Stage 3 (MIS 3) compared to Marine Isotope Stage 2 (MIS 2). This will be further evaluated with higher resolution from the composite profile including a detailed study of discrete plant debris layers. References Haberzettl, T. et al. (2007). Lateglacial and Holocene wet-dry cycles in southern Patagonia: chronology, sedimentology and geochemistry of a lacustrine record from Laguna Potrok Aike, Argentina. The Holocene, 17: 297-310. Mayr, C. et al. (2009). Isotopic and geochemical fingerprints of environmental changes during the last 16,000 years on lacustrine organic matter from Laguna Potrok Aike (southern Patagonia, Argentina). Journal of Paleolimnology, 42: 81-102.

The formation of lacustrine dolomites: an example from the Tortonian-Messinian sequence at the East Mediterranean margins (northern Israel)

NASA Astrophysics Data System (ADS)

Shaked Gelband, Dotan; Starinsky, Abraham; Stein, Mordechai

2017-04-01

Lacustrine water bodies that filled the tectonic depressions in the Lower Galilee area of Israel during the Tortonian-Messinian periods deposited Bira and Gesher Formations, which comprise marly limestones and dolomites, basalts, and varying amounts of mollusc fossils. Most fossils are gastropods of fresh to brackish water origin, while marine representation is minor and comprise monospecific assemblages of euryhaline bivalves. During the deposition of the Tortonian Bira formation the lakes were mostly influenced by meteoric waters while during the deposition of the Messinian Gesher Formation they became more swampy. Here, we set to establish the deposition conditions of the dolomites in the lacustrine formations. The following petrographic characteristics indicate dolomitization of precursor carbonate sediment during early diagenesis stage: (1) Dolomitized fossils with similar texture as the surrounding dolomite matrix; (2) Common euhedral inner zone crystals, representing original growth in solution or plastic environment; (3) Subhedral outer shape derived from neighboring crystals collisions. More information is given by the δ18O and δ13C values of the dolomites. The δ18O of the inter-layered limestones and dolomites fluctuates between -3‰ to -4‰ (VPDB) in the limestones and +5‰ to -1.5‰ (VPDB) in the adjacent dolomites. These fluctuations are prominent in the Bira formation and become smaller along the sequence with the decrease in the dolomite values. δ13C values of both limestones and dolomites gradually decrease along the stratigraphic section, from -3.5‰ to -10‰ (VPDB) in the limestones, and from 0‰ to -8‰ (VPDB) in the dolomites. The data suggest a dolomitization process controlled by the following events: 1. Evaporation of fresh lake waters originated from the surrounding environment as runoff. It should be emphasized that significant evaporation could take place only in terminal lakes, during periods of relatively dry climate with low

Estimation of the tectonic slip-rate from Quaternary lacustrine facies within the intraplate Albacete province (SE of Spain)

USGS Publications Warehouse

Rodriguez-Pascua, M. A.; Bischoff, J.; Garduno-Monroy, Victor H.; Pérez-López, R.; Giner-Robles, J.L.; Israde-Alcántara, I.; Calvo, J.P.; Williams, Ross W.

2009-01-01

The Quaternary lacustrine basin of Cordovilla (CB) represents one of the most active tectonic areas of the Prebetic Zone (Albacete, SE of Spain). The Quaternary sedimentary deposits of this basin are mainly endoreic lacustrine carbonate and alluvial deposits, developed in a semi-arid climate (Pleistocene-present). The basin is a NW-SE-elongated graben bounded by a major right-lateral oblique-fault, the Pozohondo Fault. This fault trends NW-SE, with an approximate trace of 55 km, and is composed of various segments which are identified by fault scarps. In order to establish the slip-rate of the most active segment of the Pozohondo Fault, called the Cordovilla segment, we carried out a detailed study of the affected Quaternary lacustrine deposits. We found that the lacustrine facies could be related to episodic moderate paleoearthquakes. The slip-rate is calculated to be 0.05 and 0.09 mm/yr, using radiometric dating for the vertical offsets of the lacustrine facies. A trenching study at the northern part of the Cordovilla segment revealed two events caused by paleoearthquakes, with the most recent expressed as an oblique-fault off-setting a poorly-developed soil. The magnitude of the last event was greater than 6, using various empirical relationships for the fault displacement and the surface-length rupture. We estimate episodic activity across the Cordovilla segment, to be characterized by moderate-sized paleoearthquakes (M6), which is in agreement with the tectonic context of an intraplate zone of the Iberian plate. ?? 2009 Elsevier B.V.

Late Cenozoic lacustrine and climatic environments at Tule Lake, northern Great Basin, USA

USGS Publications Warehouse

Platt, Bradbury J.

1992-01-01

Cores of lake sediment to a depth of 334 m in the town of Tulelake, Siskiyou County, northern California, document the late Cenozoic paleolimnologic and paleoclimatic history of the northwestern edge of the Great Basin. The cores have been dated by radiometric, tephrochronologic and paleomagnetic analyses. Lacustrine diatoms are abundant throughout the record and document a nearly continuous paleolimnologic history of the Tule Lake basin for the last 3 Myr. During most of this time, this basin (Tule Lake) was a relatively deep, extensive lake. Except for a drier (and cooler?) interval recorded by Fragilaria species about 2.4 Ma, the Pliocene is characterized by a dominance of planktonic Aulacoseira solida implying a warm monomictic lake under a climatic regime of low seasonality. Much of the Pleistocene is dominated by Stephanodiscus and Fragilaria species suggesting a cooler, often drier, and highly variable climate. Benthic diatoms typical of alkaline-enriched saline waters commonly appear after 1.0 Ma, and tephrochronology indicates slow deposition and possible hiatuses between about 0.6 and 0.2 Ma. The chronology of even-numbered oxygen isotope stages approximately matches fluctuations in the abundance of Fragilaria since 800 ka indicating that glacial periods were expressed as drier environments at Tule Lake. Glacial and interglacial environments since 150 ka were distinct from, and more variable than, those occurring earlier. The last full glacial period was very dry, but shortly thereafter Tule Lake became a deep, cool lacustrine system indicating a substantial increase in precipitation. Aulacoseira ambigua characterized the latest glacial and Holocene record of Tule Lake. Its distribution indicates that warmer and wetter climates began about 15 ka in this part of the Great Basin. Diatom concentration fluctuates at 41 000 year intervals between 3.0 and 2.5 Ma and at approximately 100 000 year intervals after 1.0 Ma. In the late Pliocene and early Pleistocene

Physicochemical Drivers of Microbial Community Structure in Sediments of Lake Hazen, Nunavut, Canada.

PubMed

Ruuskanen, Matti O; St Pierre, Kyra A; St Louis, Vincent L; Aris-Brosou, Stéphane; Poulain, Alexandre J

2018-01-01

The Arctic is undergoing rapid environmental change, potentially affecting the physicochemical constraints of microbial communities that play a large role in both carbon and nutrient cycling in lacustrine environments. However, the microbial communities in such Arctic environments have seldom been studied, and the drivers of their composition are poorly characterized. To address these gaps, we surveyed the biologically active surface sediments in Lake Hazen, the largest lake by volume north of the Arctic Circle, and a small lake and shoreline pond in its watershed. High-throughput amplicon sequencing of the 16S rRNA gene uncovered a community dominated by Proteobacteria, Bacteroidetes, and Chloroflexi, similar to those found in other cold and oligotrophic lake sediments. We also show that the microbial community structure in this Arctic polar desert is shaped by pH and redox gradients. This study lays the groundwork for predicting how sediment microbial communities in the Arctic could respond as climate change proceeds to alter their physicochemical constraints.

High-resolution multi-proxy reconstruction of Lake Ighiel (Western Carpathians, Romania): processes and controlling factors of lacustrine dynamics during the mid and late Holocene

NASA Astrophysics Data System (ADS)

Haliuc, Aritina; Veres, Daniel; Hubay, Katalin; Begy, Robert; Brauer, Achim; Hutchinson, Simon; Braun, Mihaly

2016-04-01

Concerns about current and prospective environmental change have increased the interest in past climate variability and its impact on the bio-hydro-atmosphere and human society. Acting as high-resolution terrestrial archives, lacustrine sediments are the result of the complex interaction between internal and external forcing and an important tool in efforts to resolve questions related to the palaeoclimatic and palaeoenvironmental conditions of the recent past. Here we discuss a new, high-resolution sedimentary record from the Romanian Carpathians (central-eastern Europe). Lake Ighiel (46° 10'50"N, 23° 22'00"E) is a small lake located in a mid-altitude mountain belt (Trascau Mountains) at an altitude of 924 m ( lake maximum depth 9 m; catchment area 487 ha). We employ detailed 210Pb and 14C dating coupled with high-resolution X-ray fluorescence scanning (μ-XRF) measurements, long-core sedimentary logging, environmental magnetic proxies (susceptibility, natural and induced remanences) in an attempt to trace the 6000 years evolution of lake-catchment system. More specifically, we discuss: i) the temporal evolution of the main sedimentation phases of the lake based on sedimentological, geochemical and magnetic proxies; ii) the amplitude and interplay of processes (natural and/or anthropogenic) controlling the depositional environment through time; iii) assess the contribution of each controlling factors and reconstruct the evolution of lacustrine system and palaeoclimate forcing using multivariate statistics. The sedimentary record can be divided into six phases based on alternating high and low detrital fluxes, oscillating lacustrine productivity and redox conditions. A series of detrital events (5200; 4800; 5400; 5250; 4500; 4050; 3800; 3500; 3250; 3050; 2650; 2350; 2250; 1400; 1100; 500; 100 cal yr BP) were identified by microfacies analyses and X-ray fluorescence scanning (μ-XRF) analysis. These events are reflected in most of the parameters and appear

Final report for 105-N Basin sediment disposition task, phase 2 -- samples BOMPC8 and BOMPC9

DOE Office of Scientific and Technical Information (OSTI.GOV)

Esch, R.A.

1998-02-05

This document is the final report deliverable for Phase 2 analytical work for the 105-N Basin Sediment Disposition Task. On December 23, 1997, ten samples were received at the 222-S Laboratory as follows: two (2) bottles of potable water, six (6) samples for process control testing and two (2) samples for characterization. Analyses were performed in accordance with the Letter of Instruction for Phase 2 Analytical Work for the 105-N Basin Sediment Disposition Task (Logan and Kessner, 1997) (Attachment 7) and 105-N Basin Sediment Disposition Phase-Two Sampling and Analysis Plan (SAP) (Smith, 1997). The analytical results are included in Tablemore » 1. This document provides the values of X/Qs for the onsite and offsite receptors, taking into account the building wake and the atmospheric stability effects. X/Qs values for the potential fire accident were also calculated. In addition, the unit dose were calculated for the mixtures of isotopes.« less

Estimating the biological value of soft-bottom sediments with sediment profile imaging and grab sampling

NASA Astrophysics Data System (ADS)

Van Hoey, Gert; Birchenough, Silvana N. R.; Hostens, Kris

2014-02-01

Biological value estimation is based on a set of assessment questions and several thresholds to delineate areas of ecological importance (e.g. biodiversity). An existing framework, that was specifically designed to assess the ecosystem biodiversity, was expanded by adding new questions on the productivity, functionality and biogeochemical status of benthic habitats. The additional ecological and sedimentological information was collected by using sediment profile imagery (SPI) and grab sampling. Additionally, information on the performance and comparability of both techniques is provided in this study. The research idea was tested at a site near the harbor of Zeebrugge, an area under consideration as a new disposal site for dredged material from the harbor entrance. The sedimentology of the area can be adequately described based on the information from both SPI and Van Veen grab samples, but only the SPI revealed structural information on the physical habitat (layering, a-RPD). The latter information represented the current status of the benthic habitat, which was confirmed by the Van Veen grab samples. All information was summarized through the biological valuation framework, and provided clear evidence of the differences in biological value for the different sediment types within the area. We concluded that the installation of a new dredged material disposal site in this area was not in conflict with the benthic ecology. This area has a low biological value and the benthic system is adapted to changing conditions, which was signaled by the dominance of mobile, short living and opportunistic species. This study showed that suitable sedimentological and ecological information can be gathered by these traditional and complementary techniques, to estimate the biological value of an area in the light of marine spatial planning and environmental impact assessments.

Sedimentation and tectonics in the southern Bida Basin, Nigeria: depositional response to varying tectonic context

DOE Office of Scientific and Technical Information (OSTI.GOV)

Braide, S.P.

1990-05-01

The Upper Cretaceous Bida basin of central Nigeria is sandwiched between the Precambrian schist belts of the Northern Nigerian massif and the West African craton. Of interest is the southern part of the basin, which developed in continental settings, because the facies architecture of the sedimentary fill suggests a close relation between sedimentation dynamics and basin margin tectonics. This relationship is significant to an understanding of the basin's origin, which has been controversial. A simple sag and rift origin has been suggested, and consequently dominated the negative thinking on the hydrocarbon prospects of the basin which were considered poor. Thismore » detailed study of the facies indicates rapid basin-wide changes from various alluvial fan facies through flood-basin and deltaic facies to lacustrine facies. Paleogeographic reconstruction suggests lacustrine environments were widespread and elongate. Lacustrine environments occurred at the basin's axis and close to the margins. This suggests the depocenter must have migrated during the basin's depositional history and subsided rapidly to accommodate the 3.5-km-thick sedimentary fill. Although distinguishing pull-apart basins from rift basins, based solely on sedimentologic grounds, may be difficult, the temporal migration of the depocenter, as well as the basin architecture of upward coarsening cyclicity, show a strong tectonic and structural overprint that suggests a tectonic framework for the Southern Bida basin similar in origin to a pull-apart basin.« less

Benzene and MTBE Sorption in Fine Grain Sediments

NASA Astrophysics Data System (ADS)

Leal-Bautista, R. M.; Lenczewski, M. E.

2003-12-01

The practice of adding methyl tert-butyl ether (MTBE) to gasoline started in the late 1970s and increased dramatically in the 1990s. MTBE first was added as a substitute for tetra-ethyl lead then later as a fuel oxygenate. Although the use of MTBE has resulted in significant reduction in air pollution, it has become a significant groundwater contaminant due to its high solubility in water, high environmental mobility, and low potential for biodegradation. A recent report (1999-2001) by the Metropolitan Water District of Southern California in collaboration with United State Geological Survey and the Oregon Health and Science University found that MTBE was the second most frequent detected volatile organic compound in groundwater. In Illinois, MTBE has been found in 26 of the 1,800 public water supplies. MTBE has also been blended in Mexico into two types of gasoline sold in the country by the state oil company (PEMEX) but is not monitored in groundwater at this time. Early research on MTBE considered it unable to adsorb to soils and sediments, however, by increasing the organic matter and decreasing the size of the grains (silts or clays) this may increase sorption. The objective of this study is to determine if fine grained materials have the potential for sorption of MTBE due to its high specific surface area (10-700 m 2/g) and potentially high organic matter (0.5-3.8%). The experiment consisted of sorption isotherms to glacial tills from DeKalb, Illinois and lacustrine clays from Chalco, Mexico. Experiments were performed with various concentrations of MTBE and benzene (10, 50, 100, 500 and 1000 ug/L) at 10° C and 25° C. Results showed a range of values for the distribution coefficient (Kd, linear model). At 10° C the Kd value for MTBE was 0.187 mL/g for lacustrine clay while the glacial loess had a value of 0.009 mL/g. The highest Kd values with MTBE were 0.2859 mL/g for organic rich lacustrine clays and 0.014 mL/g for glacial loess at 25° C. The highest

Method of evaluation of process of red blood cell sedimentation based on photometry of droplet samples.

PubMed

Aristov, Alexander; Nosova, Ekaterina

2017-04-01

The paper focuses on research aimed at creating and testing a new approach to evaluate the processes of aggregation and sedimentation of red blood cells for purpose of its use in clinical laboratory diagnostics. The proposed method is based on photometric analysis of blood sample formed as a sessile drop. The results of clinical approbation of this method are given in the paper. Analysis of the processes occurring in the sample in the form of sessile drop during the process of blood cells sedimentation is described. The results of experimental studies to evaluate the effect of the droplet sample focusing properties on light radiation transmittance are presented. It is shown that this method significantly reduces the sample volume and provides sufficiently high sensitivity to the studied processes.

Volcanogenic Fluvial-Lacustrine Environments in Iceland and Their Utility for Identifying Past Habitability on Mars

PubMed Central

Cousins, Claire

2015-01-01

The search for once-habitable locations on Mars is increasingly focused on environments dominated by fluvial and lacustrine processes, such as those investigated by the Mars Science Laboratory Curiosity rover. The availability of liquid water coupled with the potential longevity of such systems renders these localities prime targets for the future exploration of Martian biosignatures. Fluvial-lacustrine environments associated with basaltic volcanism are highly relevant to Mars, but their terrestrial counterparts have been largely overlooked as a field analogue. Such environments are common in Iceland, where basaltic volcanism interacts with glacial ice and surface snow to produce large volumes of meltwater within an otherwise cold and dry environment. This meltwater can be stored to create subglacial, englacial, and proglacial lakes, or be released as catastrophic floods and proglacial fluvial systems. Sedimentary deposits produced by the resulting fluvial-lacustrine activity are extensive, with lithologies dominated by basaltic minerals, low-temperature alteration assemblages (e.g., smectite clays, calcite), and amorphous, poorly crystalline phases (basaltic glass, palagonite, nanophase iron oxides). This paper reviews examples of these environments, including their sedimentary deposits and microbiology, within the context of utilising these localities for future Mars analogue studies and instrument testing. PMID:25692905

Volcanogenic fluvial-lacustrine environments in iceland and their utility for identifying past habitability on Mars.

PubMed

Cousins, Claire

2015-02-16

The search for once-habitable locations on Mars is increasingly focused on environments dominated by fluvial and lacustrine processes, such as those investigated by the Mars Science Laboratory Curiosity rover. The availability of liquid water coupled with the potential longevity of such systems renders these localities prime targets for the future exploration of Martian biosignatures. Fluvial-lacustrine environments associated with basaltic volcanism are highly relevant to Mars, but their terrestrial counterparts have been largely overlooked as a field analogue. Such environments are common in Iceland, where basaltic volcanism interacts with glacial ice and surface snow to produce large volumes of meltwater within an otherwise cold and dry environment. This meltwater can be stored to create subglacial, englacial, and proglacial lakes, or be released as catastrophic floods and proglacial fluvial systems. Sedimentary deposits produced by the resulting fluvial-lacustrine activity are extensive, with lithologies dominated by basaltic minerals, low-temperature alteration assemblages (e.g., smectite clays, calcite), and amorphous, poorly crystalline phases (basaltic glass, palagonite, nanophase iron oxides). This paper reviews examples of these environments, including their sedimentary deposits and microbiology, within the context of utilising these localities for future Mars analogue studies and instrument testing.

From the North American Great Basin to the planet Mars: Taking Lacustrine Geomorphology into the 21st Century

NASA Astrophysics Data System (ADS)

Edgett, Kenneth S.; Parker, Timothy J.

1997-09-01

Introduction. The entire planet Mars is presently a desert more arid than any on Earth. The planet appears to have had more water in the past, and some of this water affected the surface geology and geomorphology by carving a variety of channels. Despite the evidence for running water in the martian past, the presence of sanding bodies of water (lakes, oceans) has been a topic of considerable controversy in the past two decades. The issue is still not settled, but evidence has mounted to suggest that lakes and oceans were indeed a major factor in shaping the present geomorphology of the martian surface. Although there remains uncertainty as to whether lakes were present on Mars, major efforts to seek evidence for fossil martian organisms are focused on the search for lake sediments and tufa deposits [1]. In 2001 and 2003, the NASA Mars Surveyor Program will launch mobile rovers designed to explore the surface and collect samples for return to Earth. The first set of samples will reach Earth in 2008. The types of landing sites being considered for the '01 and '03 missions include areas interpreted as ancient lacustrine deposits. Knowledge and experience with the geomorphology of lacustrine features in the North American Great Basin is crucial for identifying lake features on Mars. Martian Lakes and Oceans: Prior to spacecraft exploration of Mars, many early astronomers though that the low-albedo surfaces of Mars could be seas or lakes, others considered these to be vast tracts of vegetation [2]. The low-albedo surfaces are now known to be the result of aeolian action on the distribution of sand and dust. The Mariner 4, 6, and 7 spacecraft in 1965 and 1969 stunned the world by showing a cratered, lunar-like martian surface. In 1972, Mariner 9 showed a more Earth-like surface - indeed, there were numerous channels, some carved by massive floods, others perhaps by fluvial run-off or sapping. The Viking orbiters (1976-1980) provided additional images; these formed the

2010 Maule (Chile) and AD 1755 (Portugal) tsunami sediment samples: limitations of microtextural analysis

NASA Astrophysics Data System (ADS)

Costa, Pedro; Silva, Diogo; Figueirinhas, Leonor; Lario, Javier

2017-04-01

The innovative application of microtextural analysis to the study of sandy tsunamigenic sediments has been sparsely attempted over recent years. Despite having demonstrated potential as a provenance tool, its reliability as a discriminant proxy for these deposits is still a matter under discussion. This is mainly due to the subjectivity of the analysis that heavily relies on operator proficiency but also to specificities of the data set (e.g. post-depositional dissolution masking other microtextures). To address these issues, a double-blind simplified microtextural classification was tested by 3 independent observers, using more than 600 Scanning Electron Microscope images of sandy samples retrieved after the February 2010 Chilean tsunami. These were compared with approximately 15 AD 1755 tsunamigenic samples (app. 250 SEM images) retrieved from south Portugal. Comparison with a limited number of potential tsunami source sediment (beach and dune) was attempted to establish provenance relationships. Grains were classified into four main microtextural families (A-fresh surfaces, B- percussion marks, C- dissolution and D- adhering particles) according to its most recent microtextural imprint (A to D) thus indicating the last event responsible for microtextural imprints. In the Chilean samples the dominance of chemical marks (dissolution and adhering particles) was obvious. Combining these two microtextures, all samples presented results >69%. On the other hand, the Portuguese samples presented a much stronger presence of mechanical marks (e.g. percussion marks present up to 59%). Reasons behind different results in the Chilean and Portuguese samples raise serious questions regarding the application of microtextural analysis to the study of tsunami deposits. Nevertheless, the discrepancies observed can also be explain by a one or a combination of the following factors: different geomorphological setting (with the presence of dunes in the Portuguese case), higher

Passive Sampling Methods for Contaminated Sediments: Practical Guidance for Selection, Calibration, and Implementation

EPA Science Inventory

This article provides practical guidance on the use of passive sampling methods(PSMs) that target the freely dissolved concentration (Cfree) for improved exposure assessment of hydrophobic organic chemicals in sediments. Primary considerations for selecting a PSM for a specific a...

Search for Martian fossil communities: Science strategies, sediment sites, and sample handling

NASA Technical Reports Server (NTRS)

Desmarais, David J.

1988-01-01

The strategy for locating and sampling possible fossilized Martian organisms benefits from our experience with fossil microbial ecosystems on Earth. Evidence of early life is typically preserved as stromatolites in carbonates and cherts, and as microfossils in cherts, carbonates and shales. Stromatolites, which are laminated flat or domal structures built by microbial communities, are very likely the oldest and most widespread relics of early life. These communities flourished in supratidal to subtidal coastal benthic environments, wherever sunlight was available and where incoming sediments were insufficient to bury the communities before they became established. A logical site for such communities on Mars might be those areas in an ancient lake bed which were furthest from sediment input, but were still sufficiently shallow to have received sunlight. Therefore, although some sites within Valles Marineris might have contained ponded water, the possibly abundant sediment inputs might have overwhelmed stromatolite-like communities. Localized depressions which acted as catchment basins for ancient branched valley systems might be superior sites. Perhaps such depressions received drainage which, because of the relatively modest water discharges implied for these streams, was relatively low in transported sediment. Multiple streams converging on a single basin might have been able to maintain a shallow water environment for extended periods of time.

Soft sediment deformation structures in a lacustrine sedimentary succession induced by volcano-tectonic activities: An example from the Cretaceous Beolgeumri Formation, Wido Volcanics, Korea

NASA Astrophysics Data System (ADS)

Ko, Kyoungtae; Kim, Sung Won; Lee, Hong-Jin; Hwang, In Gul; Kim, Bok Chul; Kee, Won-Seo; Kim, Young-Seog; Gihm, Yong Sik

2017-08-01

The Cretaceous Beolgeumri Formation is composed of laminated mudstones intercalated with sandstones, chert, and a bed of lapilli tuff that were deposited in a lacustrine environment at the terminal part of a regional strike-slip fault systems on the southwestern Korean Peninsula. The Beolgeumri Formation contains various types of soft sediment deformation (SSD) structures that are characterized by a wide extent (< 4 km), lateral continuity (< 200 m), and vertical repetition. The SSD structures can be classified into six categories based on their morphological features and deformation styles: 1) fold structures, 2) load structures, 3) water-escape structures, 4) rip-down structures, 5) boudin structures, and 6) synsedimentary fault structures. Field examination of SSD structures together with an analysis of the sedimentological records of the Beolgeumri Formation indicate that the SSD structures formed largely by liquefaction and/or fluidization triggered by ground shaking during earthquakes. To constrain the timing of the development of SSD structures in the Beolgeumri Formation, we conducted sensitive high-resolution ion microprobe (SHRIMP) U-Pb zircon age dating of block sized lithic clasts bearing volcaniclastic deposits that conformably underlie (the Mangryeongbong Tuff) and overlie (the Ttandallae Tuff) the Beolgeumri Formation. The Mangryeongbong and Ttandallae Tuffs have ages of 86.63 ± 0.83 Ma and 87.24 ± 0.36 Ma, respectively, indicating that the Beolgeumri Formation was deposited during a short interval between major volcanic eruptions. The large lithic clasts of volcaniclastic deposits suggest that the Beolgeumri Formation was deposited adjacent to an active volcanic edifice(s). Syndepositional magmatic activities are suggested by the occurrence of a lapilli tuff bed in the Beolgeumri Formation and an igneous intrusion (intermediate sill) that is crosscut by a sand dike, as well as the similar age results of the underlying and overlying volcaniclastic

Vivianite formation and distribution in Lake Baikal sediments

NASA Astrophysics Data System (ADS)

Fagel, N.; Alleman, L. Y.; Granina, L.; Hatert, F.; Thamo-Bozso, E.; Cloots, R.; André, L.

2005-04-01

In an effort to better understand vivianite formation processes, four Lake Baikal sediment cores spanning two to four interglacial stages in the northern, central and southern basins and under various biogeochemical environments are scrutinized. The vivianite-rich layers were detected by anomalous P-enrichments in bulk geochemistry and visually by observations on X-radiographs. The millimetric concretions of vivianite were isolated by sieving and analysed by X-ray diffraction, scanning electron microscope (SEM), microprobe, infrared spectroscopy, inductively coupled plasma atomic emission spectrometry and mass spectrometry (ICP-AES, ICP-MS). All the vivianites display similar morphological, mineralogical and geochemical signature, suggesting a common diagenetic origin. Their geochemical signature is sensitive to secondary alteration where vivianite concretions are gradually transformed from the rim to the center into an amorphous santabarbaraite phase with a decreasing Mn content. We analysed the spatial and temporal distribution of the concretions in order to determine the primary parameters controlling the vivianite formation, e.g., lithology, sedimentation rates, and porewater chemistry. We conclude that vivianite formation in Lake Baikal is mainly controlled by porewater chemistry and sedimentation rates, and it is not a proxy for lacustrine paleoproductivity. Vivianite accumulation is not restricted to areas of slow sedimentation rates (e.g., Academician and Continent ridges). At the site of relatively fast sedimentation rate, i.e., the Posolsky Bank near the Selenga Delta, vivianite production may be more or less related to the Selenga River inputs. It could be also indirectly related to the past intensive methane escapes from the sediments. While reflecting an early diagenetic signal, the source of P and Fe porewater for vivianites genesis is still unclear.

A Novel Selective Deep Eutectic Solvent Extraction Method for Versatile Determination of Copper in Sediment Samples by ICP-OES.

PubMed

Bağda, Esra; Altundağ, Huseyin; Tüzen, Mustafa; Soylak, Mustafa

2017-08-01

In the present study, a simple, mono step deep eutectic solvent (DES) extraction was developed for selective extraction of copper from sediment samples. The optimization of all experimental parameters, e.g. DES type, sample/DES ratio, contact time and temperature were performed with using BCR-280 R (lake sediment certified reference material). The limit of detection (LOD) and the limit of quantification (LOQ) were found as 1.2 and 3.97 µg L -1 , respectively. The RSD of the procedure was 7.5%. The proposed extraction method was applied to river and lake sediments sampled from Serpincik, Çeltek, Kızılırmak (Fadl and Tecer region of the river), Sivas-Turkey.

Stereochemistry of amino acids in surface samples of a marine sediment

NASA Technical Reports Server (NTRS)

Pollock, G. E.; Kvenvolden, K. A.

1978-01-01

In two surface samples of marine sediment, the percentages of D-alanine and D-aspartic acid are significantly higher than the other D-amino acids and are similar to the range found in soils. The percentage of D-glutamic acid is also higher than the other amino acids but less than D-alanine and D-aspartic acid. These D-amino acids may come mainly from bacteria.

Stereochemistry of amino acids in surface samples of a marine sediment

USGS Publications Warehouse

Pollock, G.E.; Kvenvolden, K.A.

1978-01-01

In two surface samples of marine sediment, the percentages of d-alanine and d-aspartic acid are significantly higher than the other d-amino acids and are similar to the range found in soils. The percentage of d-glutamic acid is also higher than the other amino acids but less than d-alanine and d-aspartic acid. These d-amino acids may come mainly from bacteria. ?? 1978.

A Buoy for Continuous Monitoring of Suspended Sediment Dynamics

PubMed Central

Mueller, Philip; Thoss, Heiko; Kaempf, Lucas; Güntner, Andreas

2013-01-01

Knowledge of Suspended Sediments Dynamics (SSD) across spatial scales is relevant for several fields of hydrology, such as eco-hydrological processes, the operation of hydrotechnical facilities and research on varved lake sediments as geoarchives. Understanding the connectivity of sediment flux between source areas in a catchment and sink areas in lakes or reservoirs is of primary importance to these fields. Lacustrine sediments may serve as a valuable expansion of instrumental hydrological records for flood frequencies and magnitudes, but depositional processes and detrital layer formation in lakes are not yet fully understood. This study presents a novel buoy system designed to continuously measure suspended sediment concentration and relevant boundary conditions at a high spatial and temporal resolution in surface water bodies. The buoy sensors continuously record turbidity as an indirect measure of suspended sediment concentrations, water temperature and electrical conductivity at up to nine different water depths. Acoustic Doppler current meters and profilers measure current velocities along a vertical profile from the water surface to the lake bottom. Meteorological sensors capture the atmospheric boundary conditions as main drivers of lake dynamics. It is the high spatial resolution of multi-point turbidity measurements, the dual-sensor velocity measurements and the temporally synchronous recording of all sensors along the water column that sets the system apart from existing buoy systems. Buoy data collected during a 4-month field campaign in Lake Mondsee demonstrate the potential and effectiveness of the system in monitoring suspended sediment dynamics. Observations were related to stratification and mixing processes in the lake and increased turbidity close to a catchment outlet during flood events. The rugged buoy design assures continuous operation in terms of stability, energy management and sensor logging throughout the study period. We conclude that

Marine-to-lacustrine transition, mud volcanism, and slope instability in an active tectonic setting: the MIS 5 to 4 transition in the Sea of Marmara, Turkey

NASA Astrophysics Data System (ADS)

Grall, Céline; Henry, Pierre; Kendé, Julia; Namık Çaǧatay, M.; Kadir Eriş, K.; Paillès, Christine; Sorlien, Christopher; Shillington, Donna; McHugh, Cecilia; Steckler, Michael; Çifçi, Günay; Géli, Louis

2016-04-01

In the Sea of Marmara, glacio-eustatic cycles set the tempo of a complex history of disconnection and reconnection with the Black Sea and with the global ocean through the Mediterranean Sea. As a result, the sedimentary record consists of alternating high stand marine sediments and lowstand sea or lake sediments. The Sea of Marmara is also an active transtensional basin along the Northern branch of the North Anatolian Fault (NNAF), which accommodates most (~3/4) of the 21-27 mm/a dextral slip between Eurasia and Anatolia. This peculiar setting makes the Sea of Marmara an exceptional site to study the interplay of paleo-environmental factors and seismotectonic processes. Notably, Mass Transport Deposits (MTDs) crossing the faults provide offset markers although their age remains uncertain. A high resolution seismic stratigraphic model has been proposed for 100 ka glacial cycles, based on onlap sequences within basins, and paleo-deltas at shorelines. The sedimentation rate in basins decreases during episodes of sea-level rise and reach maximum values during low stands. Remarkably, seismic reflector sequences display nearly identical character for locations with similar sedimentation rate. The uppermost sequence boundary reflector (Red-H1) has been recently cored at several locations during MARSITECRUISE (Ifremer R/V Pourquoi Pas?, Oct-Nov. 2014), enabled us to correlate high resolution seismic data with core data. The Red-H1 reflector is regionally characterized by a high amplitude and a reverse polarity. Correlations between seismic data and piston core logs indicate that the reverse polarity of this reflector may be explained by a negative density contrast between lacustrine sediments above and a greenish sapropellic layer of several meters thickness below. On shelves, Red-H1 is on top of the low stand wedge. On slopes and topographic highs, Red-H1 appears as an erosional surface laterally correlative with an onlapping unit in basins and is frequently overlain by

Optimizing sample pretreatment for compound-specific stable carbon isotopic analysis of amino sugars in marine sediment

NASA Astrophysics Data System (ADS)

Zhu, R.; Lin, Y.-S.; Lipp, J. S.; Meador, T. B.; Hinrichs, K.-U.

2014-01-01

Amino sugars are quantitatively significant constituents of soil and marine sediment, but their sources and turnover in environmental samples remain poorly understood. The stable carbon isotopic composition of amino sugars can provide information on the lifestyles of their source organisms and can be monitored during incubations with labeled substrates to estimate the turnover rates of microbial populations. However, until now, such investigation has been carried out only with soil samples, partly because of the much lower abundance of amino sugars in marine environments. We therefore optimized a procedure for compound-specific isotopic analysis of amino sugars in marine sediment employing gas chromatography-isotope ratio mass spectrometry. The whole procedure consisted of hydrolysis, neutralization, enrichment, and derivatization of amino sugars. Except for the derivatization step, the protocol introduced negligible isotopic fractionation, and the minimum requirement of amino sugar for isotopic analysis was 20 ng, i.e. equivalent to ~ 8 ng of amino sugar carbon. Our results obtained from δ13C analysis of amino sugars in selected marine sediment samples showed that muramic acid had isotopic imprints from indigenous bacterial activities, whereas glucosamine and galactosamine were mainly derived from organic detritus. The analysis of stable carbon isotopic compositions of amino sugars opens a promising window for the investigation of microbial metabolisms in marine sediments and the deep marine biosphere.

Landslide-dammed paleolake perturbs marine sedimentation and drives genetic change in anadromous fish.

PubMed

Mackey, Benjamin H; Roering, Joshua J; Lamb, Michael P

2011-11-22

Large bedrock landslides have been shown to modulate rates and processes of river activity by forming dams, forcing upstream aggradation of water and sediment, and generating catastrophic outburst floods. Less apparent is the effect of large landslide dams on river ecosystems and marine sedimentation. Combining analyses of 1-m resolution topographic data (acquired via airborne laser mapping) and field investigation, we present evidence for a large, landslide-dammed paleolake along the Eel River, CA. The landslide mass initiated from a high-relief, resistant outcrop which failed catastrophically, blocking the Eel River with an approximately 130-m-tall dam. Support for the resulting 55-km-long, 1.3-km(3) lake includes subtle shorelines cut into bounding terrain, deltas, and lacustrine sediments radiocarbon dated to 22.5 ka. The landslide provides an explanation for the recent genetic divergence of local anadromous (ocean-run) steelhead trout (Oncorhynchus mykiss) by blocking their migration route and causing gene flow between summer run and winter run reproductive ecotypes. Further, the dam arrested the prodigious flux of sediment down the Eel River; this cessation is recorded in marine sedimentary deposits as a 10-fold reduction in deposition rates of Eel-derived sediment and constitutes a rare example of a terrestrial event transmitted through the dispersal system and recorded offshore.

A note on coarse-grained gravity-flow deposits within proterozoic lacustrine sedimentary rocks, Transvaal sequence, South Africa

NASA Astrophysics Data System (ADS)

Eriksson, P. G.

A widely developed, thin, coarse-matrix conglomerate occurs within early Proterozoic lacustrine mudrocks in the Transvaal Sequence, South Africa. The poorly sorted tabular chert clasts, alternation of a planar clast fabric with disorientated zones, plus normal and inverse grading in the former rock type suggest deposition by density-modified grain-flow and high density turbidity currents. The lower fan-delta slope palæenvironment inferred for the conglomerate is consistent with the lacustrine interpretation for the enclosing mudrock facies. This intracratonic setting contrasts with the marine environment generally associated with density-modified grain-flow deposits.

Liquefaction features interpreted as seismites in the Pleistocene fluvio-lacustrine deposits of the Neuquén Basin (Northern Patagonia)

NASA Astrophysics Data System (ADS)

Moretti, M.; Ronchi, A.

2011-04-01

Superbly exposed soft-sediment deformation structures in Pleistocene fluvio-lacustrine deposits along the southern border of the depression area called Bajo de Añelo (Departamento de Añelo, Neuquén Basin) have been analysed. In the study area, five stratigraphic sections were measured in detail: facies distributions and stacking patterns show that these sediments result from the interaction between fluvial and lacustrine systems, represented by cross-bedded and rippled strata, and varved deposits. The lateral extent of the deformation is some hundred metres and the deformed bed involves the lower-mid part of the 30-metre-thick succession. Deformation affects about 1.5 m of coarse-grained sand, fine-grained sand and rare gravel alternations. The base and top of the deformed layer are defined by planar surfaces: undeformed beds of similar thickness, lithology and facies to the deformed layer occur above and below. Deformation is represented by a complex vertical succession of disturbed layers: each layer shows a general load-structure morphology. It can be described as a multilayered unstable density gradient system: in each bed a partial gravitational re-adjustment occurred after liquefaction. Unequal loading related to lateral variation of both bed thickness and grain packing and porosity is a probable additional driving force that can be described in the undeformed beds. Trigger mechanism recognition for the observed liquefaction features can be based on the study of the geometry of deformed beds and on facies analysis results. Two key factors drive our interpretation: (1) the occurrence of undeformed beds below and above the deformed bed; (2) deformed and undeformed beds showing the same sedimentological features. These field data allow us to exclude the action of internal erosive and/or sedimentary processes (such as overloading, wave action, etc.) as possible trigger agents for liquefaction since deformation is totally absent in beds with similar sedimentary

Geochemical data for core and bottom-sediment samples collected in 2007 from Grand Lake O' the Cherokees, northeast Oklahoma

USGS Publications Warehouse

Fey, David L.; Becker, Mark F.; Smith, Kathleen S.

2010-01-01

Grand Lake O' the Cherokees is a large reservoir in northeast Oklahoma, below the confluence of the Neosho and Spring Rivers, both of which drain the Tri-State Mining District to the north. The Tri-State district covers an area of 1,200 mi2 (3,100 km2) and comprises Mississippi Valley-type lead-zinc deposits. A result of 120 years of mining activity is an estimated 75 million tons of processed mine tailings (chat) remaining in the district. Concerns of sediment quality and the possibility of human exposure to cadmium and lead through eating fish have led to several studies of the sediments in the Tri-State district. In order to record the transport and deposition of metals from the Tri-State district by the Spring and Neosho Rivers into Grand Lake O' the Cherokees, the U.S. Geological Survey collected 11 sediment cores and 15 bottom-sediment samples in September 2007. Subsamples from five selected cores and the bottom-sediment samples were analyzed for major and trace elements and forms of carbon. The sediment samples collected from the sediment-water interface had larger average concentrations of zinc, cadmium, and lead than local background. The core collected from the Spring River had the largest concentrations of mining-related elements. A core collected just south of Twin Bridges State Park, at the confluence of the Spring and Neosho Rivers, showed a mixing zone with more mining-related elements coming from the Spring River side. The element zinc showed the most definitive patterns in graphs depicting concentration-versus-depth profiles. A core collected from the main body of the reservoir showed affected sediment down to a depth of 85 cm (33 in). This core and two others appear to have penetrated to below mining-affected sediment.

Lake-level history of Lake Michigan for the past 12,000 years: the record from deep lacustrine sediments

USGS Publications Warehouse

Colman, Steven M.; Forester, Richard M.; Reynolds, Richard L.; Sweetkind, Donald S.; King, John W.; Gangemi, Paul; Jones, Glenn A.; Keigwin, Loyd D.; Foster, David S.

1994-01-01

Collection and analysis of an extensive set of seismic-reflection profiles and cores from southern Lake Michigan have provided new data that document the history of the lake basin for the past 12,000 years. Analyses of the seismic data, together with radiocarbon dating, magnetic, sedimentologic, isotopic, and paleontologic studies of core samples, have allowed us to reconstruct lake-level changes during this recent part of the lake's history.The post-glacial history of lake-level changes in the Lake Michigan basin begins about 11.2 ka with the fall from the high Calumet level, caused by the retreat of the Two Rivers glacier, which had blocked the northern outlet of the lake. This lake-level fall was temporarily reversed by a major influx of water from glacial Lake Agassiz (about 10.6 ka), during which deposition of the distinctive gray Wilmette Bed of the Lake Michigan Formation interrupted deposition of red glaciolacustrine sediment. Lake level then continued to fall, culminating in the opening of the North Bay outlet at about 10.3 ka. During the resulting Chippewa low phase, lake level was about 80 m lower than it is today in the southern basin of Lake Michigan.The rise of the early Holocene lake level, controlled primarily by isostatic rebound of the North Bay outlet, resulted in a prominent, planar, transgressive unconformity that eroded most of the shoreline features below present lake level. Superimposed on this overall rise in lake level, a second influx of water from Lake Agassiz temporarily raised lake levels an unknown amount about 9.1 ka. At about 7 ka, lake level may have fallen below the level of the outlet because of sharply drier climate. Sometime between 6 and 5 ka, the character of the lake changed dramatically, probably due mostly to climatic causes, becoming highly undersaturated with respect to calcium carbonate and returning primary control of lake level to the isostatically rising North Bay outlet. Post-Nipissing (about 5 ka) lake level has

Cross Validation of Two Partitioning-Based Sampling Approaches in Mesocosms Containing PCB Contaminated Field Sediment, Biota, and Activated Carbon Amendment.

PubMed

Schmidt, Stine N; Wang, Alice P; Gidley, Philip T; Wooley, Allyson H; Lotufo, Guilherme R; Burgess, Robert M; Ghosh, Upal; Fernandez, Loretta A; Mayer, Philipp

2017-09-05

The Gold Standard for determining freely dissolved concentrations (C free ) of hydrophobic organic compounds in sediment interstitial water would be in situ deployment combined with equilibrium sampling, which is generally difficult to achieve. In the present study, ex situ equilibrium sampling with multiple thicknesses of silicone and in situ pre-equilibrium sampling with low density polyethylene (LDPE) loaded with performance reference compounds were applied independently to measure polychlorinated biphenyls (PCBs) in mesocosms with (1) New Bedford Harbor sediment (MA, U.S.A.), (2) sediment and biota, and (3) activated carbon amended sediment and biota. The aim was to cross validate the two different sampling approaches. Around 100 PCB congeners were quantified in the two sampling polymers, and the results confirmed the good precision of both methods and were in overall good agreement with recently published LDPE to silicone partition ratios. Further, the methods yielded C free in good agreement for all three experiments. The average ratio between C free determined by the two methods was factor 1.4 ± 0.3 (range: 0.6-2.0), and the results thus cross-validated the two sampling approaches. For future investigations, specific aims and requirements in terms of application, data treatment, and data quality requirements should dictate the selection of the most appropriate partitioning-based sampling approach.

Bottom-current and wind-pattern changes as indicated by Late Glacial and Holocene sediments from western Lake Geneva (Switzerland)

USGS Publications Warehouse

Girardclos, S.; Baster, I.; Wildi, W.; Pugin, A.; Rachoud-Schneider, A. -M.

2003-01-01

The Late-Glacial and Holocene sedimentary history of the Hauts-Monts area (western Lake Geneva, Switzerland) is reconstructed combining high resolution seismic stratigraphy and well-dated sedimentary cores. Six reflections and seismic units are defined and represented by individual isopach maps, which are further combined to obtain a three-dimensional age-depth model. Slumps, blank areas and various geometries are identified using these seismic data. The sediment depositional areas have substantially changed throughout the lake during the end of the Late-Glacial and the Holocene. These changes are interpreted as the result of variations in the intensity of deep lake currents and the frequency of strong winds determining the distribution of sediment input from the Versoix River and from reworking of previously deposited sediments within the lacustrine basin. The identified changes in sediment distribution allowed us to reconstruct the lake's deep-current history and the evolution of dominant strong wind regimes from the Preboreal to present times.

Organic contaminants, trace and major elements, and nutrients in water and sediment sampled in response to the Deepwater Horizon oil spill

USGS Publications Warehouse

Nowell, Lisa H.; Ludtke, Amy S.; Mueller, David K.; Scott, Jonathon C.

2011-01-01

Considering all the information evaluated in this report, there were significant differences between pre-landfall and post-landfall samples for PAH concentrations in sediment. Pre-landfall and post-landfall samples did not differ significantly in concentrations or benchmark exceedances for most organics in water or trace elements in sediment. For trace elements in water, aquatic-life benchmarks were exceeded in almost 50 percent of samples, but the high and variable analytical reporting levels precluded statistical comparison of benchmark exceedances between sampling periods. Concentrations of several PAH compounds in sediment were significantly higher in post-landfall samples than pre-landfall samples, and five of seven sites with the largest differences in PAH concentrations also had diagnostic geochemical evidence of Deepwater Horizon Macondo-1 oil from Rosenbauer and others (2010).

Archival policies and collections database for the Woods Hole Science Center's marine sediment samples

USGS Publications Warehouse

Buczkowski, Brian J.; Kelsey, Sarah A.

2007-01-01

The Woods Hole Science Center of the U.S. Geological Survey (USGS) has been an active member of the Woods Hole research community, Woods Hole, Massachusetts, for over 40 years. In that time there have been many projects that involved the collection of sediment samples conducted by USGS scientists and technicians for the research and study of seabed environments and processes. These samples were collected at sea or near shore and then brought back to the Woods Hole Science Center (WHSC) for analysis. While at the center, samples are stored in ambient temperature, refrigerated and freezing conditions ranging from +2º Celsius to -18º Celsius, depending on the best mode of preparation for the study being conducted or the duration of storage planned for the samples. Recently, storage methods and available storage space have become a major concern at the WHSC. The core and sediment archive program described herein has been initiated to set standards for the management, methods, and duration of sample storage. A need has arisen to maintain organizational consistency and define storage protocol. This handbook serves as a reference and guide to all parties interested in using and accessing the WHSC's sample archive and also defines all the steps necessary to construct and maintain an organized collection of geological samples. It answers many questions as to the way in which the archive functions.

Summary geochemical maps for samples of rock, stream sediment, and nonmagnetic heavy-mineral concentrate, Sweetwater Roadless Area, Mono County, California and Lyon and Douglas Counties, Nevada

USGS Publications Warehouse

Chaffee, Maurice A.

1986-01-01

Map A shows the locations of all sites where rock samples were collected for this report and the distributions of anomalous concentrations for 12 elements in the 127 rock samples collected. In a similar manner, map B shows the collection sites for 59 samples of minus-60-mesh stream sediment, and 59 samples of nonmagnetic heavy-mineral concentrate derived from stream sediment and also shows the distributions of anomalous concentrations for 13 elements in the stream-sediment samples and 17 elements in the concentrate samples. Map C shows outlines of those drainage basins containing samples of stream sediment and concentrate with anomalous element concentrations and also shows weighted values for each outlined basin based on the number of elements with anomalous concentrations in each stream-sediment and concentrate sample and on the degree to which these concentrations are anomalous in each sample.

Equilibrium sampling informs tissue residue and sediment remediation for pyrethroid insecticides in mariculture: A laboratory demonstration.

PubMed

Li, Juan-Ying; Shi, Wenxuan; Li, Zhenhua; Chen, Yiqin; Shao, Liu; Jin, Ling

2018-03-01

Mariculture product safety in relation to sediment quality has attracted increasing attention because of the accumulation of potentially hazardous chemicals, including pyrethroid insecticides, in sediment. Passive sampling has been widely used to assess the bioavailability of sediment-associated hydrophobic organic contaminants and predict their body residue in benthic organisms. Therefore, in this study, we introduced polydimethylsiloxane (PDMS) polymer as a biomimetic "chemometer" for freely-dissolved concentrations (C free ) to assess the efficacy of different carbon sorbents in reducing the bioavailability of pyrethroids in the process of sediment remediation. Black carbon (BC)-based materials (e.g., charcoal, biochar, and activated carbon) showed the advantageous sorption capacity over humic substance-based peat soil based on both C free and tissue residue in exposed clams. Of the tested BC-type materials, biochar appeared to be an ideal one in the remediation of pyrethroid-contaminated sediment. The predictive value of the PDMS chemometer approach to informing tissue residue was confirmed by a good agreement between the measured lipid-normalized concentrations of pyrethroids in clams and the lipid-based equilibrium concentrations calculated from C free via lipid-water partition coefficients. The quantitative inter-compartmental relationship underlying the laboratory system of sediment-pore water-PDMS-biota was also cross-validated by a mechanistically-based bioaccumulation model, thus confirming the validity of C free as a predictive intermediate to alert for tissue residue and guide sediment remediation. The present study revealed a great promise of sensing C free by polymer-based equilibrium sampling in predicting tissue residue of chemicals applied in mariculture against regulatory guidelines, and, in turn, informing remediation measures when needs arise. In situ demonstration is warranted in the future to ascertain the field applicability of this approach

In situ passive sampling of sediments in the Lower Duwamish Waterway Superfund site: Replicability, comparison with ex situ measurements, and use of data.

PubMed

Apell, Jennifer N; Gschwend, Philip M

2016-11-01

Superfund sites with sediments contaminated by hydrophobic organic compounds (HOCs) can be difficult to characterize because of the complex nature of sorption to sediments. Porewater concentrations, which are often used to model transport of HOCs from the sediment bed into overlying water, benthic organisms, and the larger food web, are traditionally estimated using sediment concentrations and sorption coefficients estimated using equilibrium partitioning (EqP) theory. However, researchers have begun using polymeric samplers to determine porewater concentrations since this method does not require knowledge of the sediment's sorption properties. In this work, polyethylene passive samplers were deployed into sediments in the field (in situ passive sampling) and mixed with sediments in the laboratory (ex situ active sampling) that were contaminated with polychlorinated biphenyls (PCBs). The results show that porewater concentrations based on in situ and ex situ sampling generally agreed within a factor of two, but in situ concentrations were consistently lower than ex situ porewater concentrations. Imprecision arising from in situ passive sampling procedures does not explain this bias suggesting that field processes like bioirrigation may cause the differences observed between in situ and ex situ polymeric samplers. Copyright © 2016 Elsevier Ltd. All rights reserved.

Middle Pleistocene infill of Hinkley Valley by Mojave River sediment and associated lake sediment: Depositional architecture and deformation by strike-slip faults

USGS Publications Warehouse

Miller, David; Haddon, Elizabeth; Langenheim, Victoria; Cyr, Andrew J.; Wan, Elmira; Walkup, Laura; Starratt, Scott W.

2018-01-01

Hinkley Valley in the Mojave Desert, near Barstow about 140 km northeast of Los Angeles and midway between Victorville Valley and the Lake Manix basin, contains a thick sedimentary sequence delivered by the Mojave River. Our study of sediment cores drilled in the valley indicates that Hinkley Valley was probably a closed playa basin with stream inflow from four directions prior to Mojave River inflow. The Mojave River deposited thick and laterally extensive clastic wedges originating from the southern valley that rapidly filled much of Hinkley Valley. Sedimentary facies representing braided stream, wetland, delta, and lacustrine depositional environments all are found in the basin fill; in some places, the sequence is greater than 74 m (245 ft) thick. The sediment is dated in part by the presence of the ~631 ka Lava Creek B ash bed low in the section, and thus represents sediment deposition after Victorville basin was overtopped by sediment and before the Manix basin began to be filled. Evidently, upstream Victorville basin filled with sediment by about 650 ka, causing the ancestral Mojave River to spill to the Harper and Hinkley basins, and later to Manix basin.Initial river sediment overran wetland deposits in many places in southern Hinkley Valley, indicating a rapidly encroaching river system. These sediments were succeeded by a widespread lake (“blue” clay) that includes the Lava Creek B ash bed. Above the lake sediment lies a thick section of interlayered stream sediment, delta and nearshore lake sediment, mudflat and/or playa sediment, and minor lake sediment. This stratigraphic architecture is found throughout the valley, and positions of lake sediment layers indicate a successive northward progression in the closed basin. A thin overlapping sequence at the north end of the valley contains evidence for a younger late Pleistocene lake episode. This late lake episode, and bracketing braided stream deposits of the Mojave River, indicate that the river

Equilibrium sampling to determine the thermodynamic potential for bioaccumulation of persistent organic pollutants from sediment.

PubMed

Jahnke, Annika; MacLeod, Matthew; Wickström, Håkan; Mayer, Philipp

2014-10-07

Equilibrium partitioning (EqP) theory is currently the most widely used approach for linking sediment pollution by persistent hydrophobic organic chemicals to bioaccumulation. Most applications of the EqP approach assume (I) a generic relationship between organic carbon-normalized chemical concentrations in sediments and lipid-normalized concentrations in biota and (II) that bioaccumulation does not induce levels exceeding those expected from equilibrium partitioning. Here, we demonstrate that assumption I can be obviated by equilibrating a silicone sampler with chemicals in sediment, measuring chemical concentrations in the silicone, and applying lipid/silicone partition ratios to yield concentrations in lipid at thermodynamic equilibrium with the sediment (CLip⇌Sed). Furthermore, we evaluated the validity of assumption II by comparing CLip⇌Sed of selected persistent, bioaccumulative and toxic pollutants (polychlorinated biphenyls (PCBs) and hexachlorobenzene (HCB)) to lipid-normalized concentrations for a range of biota from a Swedish background lake. PCBs in duck mussels, roach, eel, pikeperch, perch and pike were mostly below the equilibrium partitioning level relative to the sediment, i.e., lipid-normalized concentrations were ≤CLip⇌Sed, whereas HCB was near equilibrium between biota and sediment. Equilibrium sampling allows straightforward, sensitive and precise measurement of CLip⇌Sed. We propose CLip⇌Sed as a metric of the thermodynamic potential for bioaccumulation of persistent organic chemicals from sediment useful to prioritize management actions to remediate contaminated sites.

Spatial and Temporal Patterns of Mercury Accumulation in Lacustrine Sediments Across the Laurentian Great Lakes Region

EPA Science Inventory

Data from 103 sediment cores from the Great Lakes and inland lakes of the Great Lakes airshed were compiled to examine and provide a synthesis of patterns of historical and recent changes in mercury (Hg) deposition. Limited data from the lower Laurentian Great Lakes shows a lega...

Geomorphological map and preliminary analysis of Quaternary sediments in the Planica-Tamar valley (Julian Alps, NW Slovenia)

NASA Astrophysics Data System (ADS)

Novak, Andrej; Šmuc, Andrej

2016-04-01

The Planica-Tamar valley is located in the Julian Alps in north-west Slovenia. The Planica-Tamar valley represents typical mountain glacial valley bounded by steep, mainly carbonate cliffs with some glacial deposits still preserved. The valley is currently being filled with numerous Holocene sediments deposited by rock falls, landslides, mass gravity flows and fluvial flows. These deposits are forming active or inactive interfingering talus slopes, alluvial and debris-flow fans, all of them with a complex history of sedimentation and erosion forming unconformity bounded sedimentary units. In order to make a thorough analysis of these deposits a detailed geomorphological map in a scale of 1:10 000 has been made. Six different types of sedimentary deposits were defined and mapped. These are moraines, lacustrine sediments, fluvio-glacial deposits, talus slopes, debris fans and alluvial fans. Other mapped features also include shape of ravines, their depths, ridges and direction of sedimentary flow. Additionally areas of active, semi-active and inactive sedimentation were marked. Moraines forms a ridge in the bottom of the valleys and are composed of unconsolidated, poorly sorted, subangular grains ranging from clay size to a few cubic meters big blocks. Lacustrine sediments are represented by laminated well sorted sand and silt, while fluvio-glacial deposits are composed of washed out subrounded sands and gravels. Talus slope deposits are characterised by clast-supported poorly sorted very angular gravel. Debris flow fans are represented by extremely poorly sorted matrix-supported gravels with grain size ranging from clay to few cubic meters big blocks. Alluvial fans are composed by variety of sedimentary textures. Sediments at the fan apex are clast-supported poorly sorted very angular gravels with up to a few cubic meters big block. In the middle part of the fan the sieve deposits are common, while in the distal parts a few centimeters thick layers of sand and

Concentration of Antifouling Biocides and Metals in Sediment Core Samples in the Northern Part of Hiroshima Bay

PubMed Central

Tsunemasa, Noritaka; Yamazaki, Hideo

2014-01-01

Accumulation of Ot alternative antifoulants in sediment is the focus of this research. Much research had been done on surface sediment, but in this report, the accumulation in the sediment core was studied. The Ot alternative antifoulants, Diuron, Sea-Nine211, and Irgarol 1051, and the latter’s degradation product, M1, were investigated in five samples from the northern part of Hiroshima Bay. Ot compounds (tributyltin (TBT) and triphenyltin (TPT)) were also investigated for comparison. In addition, metal (Pb, Cu, Zn, Fe and Mn) levels and chronology were measured to better understand what happens after accumulation on the sea floor. It was discovered that Ot alternative antifoulant accumulation characteristics in sediment were like Ot compounds, with the concentration in the sediment core being much higher than surface sediment. The concentration in sediment seems to have been affected by the regulation of Ot compounds in 1990, due to the concentration of Ot alternative antifoulants and Ot compounds at the survey point in front of the dock, showing an increase from almost the same layer after the regulation. PMID:24901529

Eruptive and environmental processes recorded by diatoms in volcanically-dispersed lake sediments from the Taupo Volcanic Zone, New Zealand

USGS Publications Warehouse

Harper, Margaret A.; Pledger, Shirley A.; Smith, Euan G. C.; Van Eaton, Alexa; Wilson, Colin J. N.

2015-01-01

Late Pleistocene diatomaceous sediment was widely dispersed along with volcanic ash (tephra) across and beyond New Zealand by the 25.4 ka Oruanui supereruption from Taupo volcano. We present a detailed analysis of the diatom populations in the Oruanui tephra and the newly discovered floras in two other eruptions from the same volcano: the 28.6 ka Okaia and 1.8 ka Taupo eruptions. For comparison, the diatoms were also examined in Late Pleistocene and Holocene lake sediments from the Taupo Volcanic Zone (TVZ). Our study demonstrates how these microfossils provide insights into the lake history of the TVZ since the Last Glacial Maximum. Morphometric analysis of Aulacoseira valve dimensions provides a useful quantitative tool to distinguish environmental and eruptive processes within and between individual tephras. The Oruanui and Okaia diatom species and valve dimensions are highly consistent with a shared volcanic source, paleolake and eruption style (involving large-scale magma-water interaction). They are distinct from lacustrine sediments sourced elsewhere in the TVZ. Correspondence analysis shows that small, intact samples of erupted lake sediment (i.e., lithic clasts in ignimbrite) contain heterogeneous diatom populations, reflecting local variability in species composition of the paleolake and its shallowly-buried sediments. Our analysis also shows a dramatic post-Oruanui supereruption decline in Cyclostephanos novaezelandiae, which likely reflects a combination of (1) reorganisation of the watershed in the aftermath of the eruption, and (2) overall climate warming following the Last Glacial Maximum. This decline is reflected in substantially lower proportions of C. novaezelandiae in the 1.8 ka Taupo eruption deposits, and even fewer in post-1.8 ka sediments from modern (Holocene) Lake Taupo. Our analysis highlights how the excellent preservation of siliceous microfossils in volcanic tephra may fingerprint the volcanic source region and retain a valuable record

Surge Block Method for Controlling Well Clogging and Sampling Sediment during Bioremediation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, Wei-min; Watson, David B; Luo, Jian

2013-01-01

A surge block treatment method (i.e. inserting a solid rod plunger with a flat seal that closely fits the casing interior into a well and stocking it up and down) was performed for the rehabilitation of wells clogged with biomass and for the collection of time series sediment samples during in situ bioremediation tests for U(VI) immobilization at a the U.S. Department of Energy site in Oak Ridge, TN. The clogging caused by biomass growth had been controlled by using routine surge block treatment for18 times over a nearly four year test period. The treatment frequency was dependent of themore » dosage of electron donor injection and microbial community developed in the subsurface. Hydraulic tests showed that the apparent aquifer transmissivity at a clogged well with an inner diameter (ID) of 10.16 cm was increased by 8 13 times after the rehabilitation, indicating the effectiveness of the rehabilitation. Simultaneously with the rehabilitation, the surge block method was successfully used for collecting time series sediment samples composed of fine particles (clay and silt) from wells with ID 1.9 10.16 cm for the analysis of mineralogical and geochemical composition and microbial community during the same period. Our results demonstrated that the surge block method provided a cost-effective approach for both well rehabilitation and frequent solid sampling at the same location.« less

Distinguishing megathrust from intraplate earthquakes using lacustrine turbidites (Laguna Lo Encañado, Central Chile)

NASA Astrophysics Data System (ADS)

Van Daele, Maarten; Araya-Cornejo, Cristian; Pille, Thomas; Meyer, Inka; Kempf, Philipp; Moernaut, Jasper; Cisternas, Marco

2017-04-01

triggered by megathrust earthquakes. These findings are an important step forward in the interpretation of lacustrine turbidites in subduction settings, and will eventually improve hazard assessments based on such paleoseismic records in the study area, and in other subduction zones. References Howarth et al., 2014. Lake sediments record high intensity shaking that provides insight into the location and rupture length of large earthquakes on the Alpine Fault, New Zealand. Earth and Planetary Science Letters 403, 340-351. Lomnitz, 1960. A study of the Maipo Valley earthquakes of September 4, 1958, Second World Conference on Earthquake Engineering, Tokyo and Kyoto, Japan, pp. 501-520. Sepulveda et al., 2008. New Findings on the 1958 Las Melosas Earthquake Sequence, Central Chile: Implications for Seismic Hazard Related to Shallow Crustal Earthquakes in Subduction Zones. Journal of Earthquake Engineering 12, 432-455. Van Daele et al., 2015. A comparison of the sedimentary records of the 1960 and 2010 great Chilean earthquakes in 17 lakes: Implications for quantitative lacustrine palaeoseismology. Sedimentology 62, 1466-1496.

Hydrothermal alteration and diagenesis of terrestrial lacustrine pillow basalts: Coordination of hyperspectral imaging with laboratory measurements

NASA Astrophysics Data System (ADS)

Greenberger, Rebecca N.; Mustard, John F.; Cloutis, Edward A.; Mann, Paul; Wilson, Janette H.; Flemming, Roberta L.; Robertson, Kevin M.; Salvatore, Mark R.; Edwards, Christopher S.

2015-12-01

We investigate an outcrop of ∼187 Ma lacustrine pillow basalts of the Talcott Formation exposed in Meriden, Connecticut, USA, focusing on coordinated analyses of one pillow lava to characterize the aqueous history of these basalts in the Hartford Basin. This work uses a suite of multidisciplinary measurements, including hyperspectral imaging, other spectroscopic techniques, and chemical and mineralogical analyses, from the microscopic scale up to the scale of an outcrop. The phases identified in the sample are albite, large iron oxides, and titanite throughout; calcite in vesicles; calcic clinopyroxene, aegirine, and Fe/Mg-bearing clay in the rind; and fine-grained hematite and pyroxenes in the interior. Using imaging spectroscopy, the chemistry and mineralogy results extend to the hand sample and larger outcrop. From all of the analyses, we suggest that the pillow basalts were altered initially after emplacement, either by heated lake water or magmatic fluids, at temperatures of at least 400-600 °C, and the calcic clinopyroxenes and aegirine identified in the rind are a preserved record of that alteration. As the hydrothermal system cooled to slightly lower temperatures, clays formed in the rind, and, during this alteration, the sample oxidized to form hematite in the matrix of the interior and Fe3+ in the pyroxenes in the rind. During the waning stages of the hydrothermal system, calcite precipitated in vesicles within the rind. Later, diagenetic processes albitized the sample, with albite replacing plagioclase, lining vesicles, and accreting onto the exterior of the sample. This albitization or Na-metasomatism occurred when the lake within the Hartford Basin evaporated during a drier past climatic era, resulting in Na-rich brines. As Ca-rich plagioclase altered to albite, Ca was released into solution, eventually precipitating as calcite in previously-unfilled vesicles, dominantly in the interior of the pillow. Coordinated analyses of this sample permit

The Alleret Maar lacustrine sequence (French Massif Central): a 150 ka long early-middle Pleistocene continental paleoenvironmental record.

NASA Astrophysics Data System (ADS)

Nomade, S.; Pastre, J.; Guillou, H.; Gauthier, A.; Scaillet, S.

2008-12-01

Lacustrine maar sequences of the French Massif Central are of great interest for paleoclimatic and paleoenvironmental reconstructions of mid-latitudes Quaternary continental environments. In particular, the western Velay region yields exceptional sequences spanning the last 450 ka (Reille et al., J. Quat. Sci. 2000). However, older sequences remain largely unknown despite the presence of interbedded alkaline tephras allowing precise absolute radiochronological control of many lacustrine squences. The Alleret maar is a 1500 m wide phreatomagmatic crater that provides a long lacustrine sequence (41 m). The upper part of this sequence (AL2 core, 14.6 m) was studied between 2005 and 2006 (Pastre et al., C. R. Acad Sci, 2007). A 39Ar/40Ar date (557 ± 5ka) obtained from an interbedded tephra layer located at 7m as well as the associated pollen data attribute the beginning of this sequence to the MIS 15. Thanks to the AL3 core recovered in 2005 (40.6 m, CNRS Meudon) several new tephra layers were discovered in the bottom part of this lacustrine sequence. Three new 39Ar/40Ar ages (single crystal analyses) from trachytic tephra layers were obtained at the LSCE Argon Laboratory (France). These layers are located at -30.2, -36.2 and -39.2m. Ages obtained relative to the ACR-2 flux standard (1,201Ma, Kuiper et al., Science, 2008) range from 692 ± 6 ka (MSWD: 2.3, n=18) for the youngest (-30.2m) to 726 ± 9Ka Ka (MSWD: 2.2, n=12) for the lowest tephra located at -39.2m. These new dates indicate a relatively homogeneous deposition rate of 3.5cm/ka and that the last 10 meters cover the MIS 17-MIS18 period. According to these current radiochronological data the complete lacustrine sequence last more than 150ka. Ongoing sedimentary and pollen studies will allow to extend the paleoenvironmental and paleoclimatic records of the French Massif Central towards the beginning of the early middle Pleistocene.

[Postspawning survival in lacustrine sock-eyed salmon Oncorhynchus nerka Walb].

PubMed

Markevich, G N; Ivashkin, E G; Pavlov, E D

2011-01-01

The state of gonads, age, structure of scales, and size of specimens of the resident lacustrine form of sock-eyed salmon--kokanee Onchorhynchus nerka--are analyzed. In stocked, previously fishless, lakes, there are specimens that have survived spawning and have remained active for a year or several years. No evidence was found of the possibility of repeated spawning. Thus, such fish do not belong to the spawning stock of the population, and their ecological function is not clear.

Pleistocene lake outburst floods and fan formation along the eastern Sierra Nevada, California: implications for the interpretation of intermontane lacustrine records

NASA Astrophysics Data System (ADS)

Benn, Douglas I.; Owen, Lewis A.; Finkel, Robert C.; Clemmens, Samuel

2006-11-01

Variations in the rock flour fraction in intermontane lacustrine sediments have the potential to provide more complete records of glacier fluctuations than moraine sequences, which are subject to erosional censoring. Construction of glacial chronologies from such records relies on the assumption that rock flour concentration is a simple function of glacier extent. However, other factors may influence the delivery of glacigenic sediments to intermontane lakes, including paraglacial adjustment of slope and fluvial systems to deglaciation, variations in precipitation and snowmelt, and lake outburst floods. We have investigated the processes and chronology of sediment transport on the Tuttle and Lone Pine alluvial fans in the eastern Sierra Nevada, California, USA, to elucidate the links between former glacier systems located upstream and the long sedimentary record from Owens Lake located downstream. Aggradation of both fans reflects sedimentation by three contrasting process regimes: (1) high magnitude, catastrophic floods, (2) fluvial or glacifluvial river systems, and (3) debris flows and other slope processes. Flood deposits are represented by multiple boulder beds exposed in section, and extensive networks of large palaeochannels and boulder deposits on both fan surfaces. Palaeohydrological analysis implies peak discharges in the order of 10 3-10 4 m 3 s -1, most probably as the result of catastrophic drainage of ice-, moraine-, and landslide-dammed lakes. Cosmogenic radionuclide surface exposure dating shows that at least three flood events are represented on each fan, at 9-13, 16-18 and 32-44 ka (Tuttle Fan); and at ˜23-32, ˜80-86 ka, and a poorly constrained older event (Lone Pine Fan). Gravels and sands exposed in both fans represent fluvial and/or glacifluvial sediment transport from the Sierra Nevada into Owens Valley, and show that river systems incised and reworked older sediment stored in the fans. We argue that millennial-scale peaks in rock flour

Impact of sorption processes on PCE concentrations in organohalide-respiring aquifer sediment samples.

PubMed

Leitner, Simon; Reichenauer, Thomas G; Watzinger, Andrea

2018-02-15

The evaluation of groundwater contaminant e.g. tetrachloroethene (PCE) degradation processes requires complete quantification of and pathway analysis of the groundwater contaminant under investigation. For example the reduction of PCE concentrations in the groundwater by unknown dissolution and/or sorption processes will impede interpretation of the fate and behaviour of such contaminants. In the present study PCE dissolution and sorption processes during anaerobic microbial degradation of chlorinated ethenes were investigated. For this purpose, microcosms were prepared using sediment samples from a PCE-contaminated aquifer, which in previous studies had demonstrated anaerobic organohalide respiration of PCE. Solid/water distribution coefficients (k d ) of PCE were determined and validated by loss-on-ignition (LOI) and PCE sorption experiments. The determined k d magnitudes indicated methodological congruency, yielding values for sediment samples within a range of 1.15±0.02 to 5.93±0.34L·kg -1 . The microcosm experiment showed lower PCE concentrations than expected, based on spiked PCE and observed anaerobic microbial degradation processes. Nevertheless the amount of PCE spike added was completely recovered albeit in the form of lower chlorinated metabolites. A delay due to dissolution processes was not responsible for this phenomenon. Sorption to sediments could only partially explain the reduction of PCE in the water phase. Accordingly, the results point to reversible sorption processes of PCE, possibly onto bacterial cell compartments and/or exopolymeric substances. Copyright © 2017 Elsevier B.V. All rights reserved.

Non-steady state diagenesis of organic and inorganic sulfur in lake sediments

NASA Astrophysics Data System (ADS)

Couture, Raoul-Marie; Fischer, Rachele; Van Cappellen, Philippe; Gobeil, Charles

2016-12-01

Sulfur controls the fate of many geochemical elements in lake sediments, including iron, phosphorus and environmentally important trace elements. We measured the speciation of pore-water and sediment-bound sulfur (aqueous sulfate and sulfides, elemental sulfur, iron monosulfide, pyrite, organic sulfur) and supporting geochemical variables (carbon, oxygen, iron) in the sediments of a perennially oxygenated and a seasonally anoxic basin of an oligotrophic lake in Québec, using a combination of pore-water analyses, sequential extractions and X-ray absorption near edge structure. A non-steady state early diagenetic model was developed and calibrated against this extensive dataset to help unravel the pathways and quantify the rates of S transformations. Results suggest that the main source of S to the sediments is the settling of organic ester-sulfate (R-O-SO3-H). Hydrolysis of these compounds provides an additional source of sulfate for anaerobic microbial oxidation of sedimentary organic matter, releasing sulfide to the pore-water. Reduced solid-bound S species accumulate as thiols (R-SH) and iron sulfides in the perennially oxygenated and seasonally anoxic basin, respectively. The model-estimated rate constant for R-SH formation is lower than previously estimated for this particular lacustrine site, but similar to that proposed for marine shelf sediments. The solid sediment S profiles, however, carry the imprint of the time-dependent sulfate input to the lake. Iron sulfide enrichments formed during past decades of elevated atmospheric SO4 deposition are presently dissolving. In the sediments of the perennially oxygenated basin this reaction hampers the build-up of Fe(III) (oxy)hydroxide near the sediment-water interface.

Using palynology to re-assess the Dead Sea laminated sediments - Indeed varves?

NASA Astrophysics Data System (ADS)

Bookman, Revital; Lopez-Merino, Lourdes; Belmaker, Reuven; Eshel, Amram; Epshtein Epshtein, Valentina; Leroy, Suzanne

2017-04-01

Lacustrine laminated sediments are often varves representing annual rhythmic deposition. The Dead Sea high-stand laminated sections consist of mm-scale alternating detrital and authigenic aragonite laminae. Previous studies assumed these laminae were varves; detritus deposition during the winter and aragonite in the summer. These sequences were used for varve counting and chronology, however this assumption has never been robustly validated. Here, we report an examination of the seasonal deposition of detrital and aragonite couplets from two well-known Late Holocene laminated sections at the Ze'elim fan-delta using palynology and grain-size distribution analyses. These analyses are complemented by the study of contemporary flash-flood samples and multivariate statistical analysis. Because transport affects the pollen preservation state, well-preserved (mostly) air-borne transported pollen was analysed separately from badly-preserved pollen and fungal spores, which are more indicative of water transport and reworking from soils. Our results indicate that (i) both detrital and aragonite laminae were deposited during the rainy season; (ii) aragonite laminae have significantly lower reworked pollen and fungal spore concentrations than detrital and flash-flood samples; and (iii) detrital laminae are composed of recycling of local and distal sources, with coarser particles that were initially deposited in the Dead Sea watershed and later transported via run-off to the lake. The conclusions suggest that detrital and aragonite couplets in the Dead Sea laminated sediments are most likely not varves and that the laminae deposition is related to the occurrence of flash-flood events. Consequently, at least for the Holocene sequences, laminated sediments cannot be considered as varves and Quaternary laminated sequences should be re-evaluated. The Dead Sea Basin laminated sequences (as the ICDP Dead Sea Deep Drilling Project record) should be used for the reconstruction of

Landslide-dammed paleolake perturbs marine sedimentation and drives genetic change in anadromous fish

PubMed Central

Mackey, Benjamin H.; Roering, Joshua J.; Lamb, Michael P.

2011-01-01

Large bedrock landslides have been shown to modulate rates and processes of river activity by forming dams, forcing upstream aggradation of water and sediment, and generating catastrophic outburst floods. Less apparent is the effect of large landslide dams on river ecosystems and marine sedimentation. Combining analyses of 1-m resolution topographic data (acquired via airborne laser mapping) and field investigation, we present evidence for a large, landslide-dammed paleolake along the Eel River, CA. The landslide mass initiated from a high-relief, resistant outcrop which failed catastrophically, blocking the Eel River with an approximately 130-m-tall dam. Support for the resulting 55-km-long, 1.3-km3 lake includes subtle shorelines cut into bounding terrain, deltas, and lacustrine sediments radiocarbon dated to 22.5 ka. The landslide provides an explanation for the recent genetic divergence of local anadromous (ocean-run) steelhead trout (Oncorhynchus mykiss) by blocking their migration route and causing gene flow between summer run and winter run reproductive ecotypes. Further, the dam arrested the prodigious flux of sediment down the Eel River; this cessation is recorded in marine sedimentary deposits as a 10-fold reduction in deposition rates of Eel-derived sediment and constitutes a rare example of a terrestrial event transmitted through the dispersal system and recorded offshore. PMID:22084068

Sensitive trace enrichment of environmental andiandrogen vinclozolin from natural waters and sediment samples using hollow-fiber liquid-phase microextraction.

PubMed

Lambropoulou, Dimitra A; Albanis, Triantafyllos A

2004-12-17

The presence of vinclozolin in the environment as far as the endocrine disruption effects in biota are concerned has raised interest in the environmental fate of this compound. In this respect, the present study attempts to investigate the feasibility of applying a novel quantitative method, liquid-phase microextraction (LPME), so as to determine this environmental andiandrogen in environmental samples such as water and sediment samples. The technique involved the use of a small amount (3 microL) of organic solvent impregnated in a hollow fiber membrane, which was attached to the needle of a conventional GC syringe. The extracted samples were analyzed by gas chromatography coupled with electron-capture detection. Experimental LPME conditions such as extraction solvent, stirring rate, content of NaCl and pH were tested. Once LPME was optimized, the performance of the proposed technique was evaluated for the determination of vinclozolin in different types of natural water samples. The recovery of spiked water samples was from 80 to 99%. The procedure was adequate for quantification of vinclozolin in waters at levels of 0.010 to 50 microg/L (r> 0.994) with a detection limit of 0.001 microg/L (S/N= 3). Natural sediment samples from the Aliakmonas River area (Macedonia, Greece) spiked with the target andiandrogen compound were liquid-liquid extracted and analyzed by the methodology developed in this work. No significant interferences from the samples matrix were noticed, indicating that the reported methodology is an innovative tactic for sample preparation in sediment analysis, with a considerable improvement in the achieved detection limits. The results demonstrated that apart from analyte enrichment, the proposed LPME procedure also serves as clean-up method and could be successfully performed to determine trace amounts of vinclozolin in water and sediment samples.

Hydroecology of Amazonian lacustrine Arcellinida (testate amoebae): A case study from Lake Quistococha, Peru.

PubMed

Patterson, R Timothy; Huckerby, Gail; Kelly, Thomas J; Swindles, Graeme T; Nasser, Nawaf A

2015-10-01

Organic rich sediments were obtained from seven core tops taken in Lake Quistococha, near the city of Iquitos in the Peruvian Amazon. Subsamples from 0 to 4cm depth in each core were analyzed under dissecting light microscopy to carry out the first investigation of Arcellinida (testate lobose amoebae) from a lacustrine environment in this ecologically important region. The fauna was characterized by a low diversity, low abundance community dominated by centropyxids. This fauna is similar to 'stressed' assemblages reported from temperate latitudes, except that test concentrations were two orders of magnitude lower than typical in temperate lakes. Principle arcellinidan stressors in Lake Quistococha likely include the low pH 4 conditions in the lake, and a general lack of suitable minerogenic material to construct tests in the organic rich lake substrate. The low pH conditions are the result of runoff and seepage of water high in dissolved organic carbon from the adjacent similarly low pH 4 terrestrial peatland. The dearth of minerogenic material is the result of the lake being isolated from riverine input for the past ∼2000 years, even during flooding events. Other limiting factors contributing to depressed arcellinidan populations may include nutrient supply, predation pressure, competition, and post-mortem taphonomic factors. Copyright © 2015 Elsevier GmbH. All rights reserved.

Improving understanding of mixed-land-use watershed suspended sediment regimes: Mechanistic progress through high-frequency sampling.

PubMed

Kellner, Elliott; Hubbart, Jason A

2017-11-15

Given the importance of suspended sediment to biogeochemical functioning of aquatic ecosystems, and the increasing concern of mixed-land-use effects on pollutant loading, there is an urgent need for research that quantitatively characterizes spatiotemporal variation of suspended sediment dynamics in contemporary watersheds. A study was conducted in a representative watershed of the central United States utilizing a nested-scale experimental watershed design, including five gauging sites (n=5) partitioning the catchment into five sub-watersheds. Hydroclimate stations at gauging sites were used to monitor air temperature, precipitation, and stream stage at 30-min intervals during the study (Oct. 2009-Feb. 2014). Streamwater grab samples were collected four times per week, at each site, for the duration of the study (Oct. 2009-Feb. 2014). Water samples were analyzed for suspended sediment using laser particle diffraction. Results showed significant differences (p<0.05) between monitoring sites for total suspended sediment concentration, mean particle size, and silt volume. Total concentration and silt volume showed a decreasing trend from the primarily agricultural upper watershed to the urban mid-watershed, and a subsequent increasing trend to the more suburban lower watershed. Conversely, mean particle size showed an opposite spatial trend. Results are explained by a combination of land use (e.g. urban stormwater dilution) and surficial geology (e.g. supply-controlled spatial variation of particle size). Correlation analyses indicated weak relationships with both hydroclimate and land use, indicating non-linear sediment dynamics. Suspended sediment parameters displayed consistent seasonality during the study, with total concentration decreasing through the growing season and mean particle size inversely tracking air temperature. Likely explanations include vegetation influences and climate-driven weathering cycles. Results reflect unique observations of

Conditions for Land Subsidence and Ground Failure in Lacustrine Sediments, the Case of West Chapala Basin.

NASA Astrophysics Data System (ADS)

Hernandez-Marin, M.; Pacheco, J.; Ortiz-Lozano, J. A.; Ramirez-Cortes, A.; Araiza, G.

2014-12-01

Surface deformation in the form of land subsidence and ground failure in the Chapala Basin has caused serious damage to structures, mostly homes. In this work, the conditions for the occurrence of deformation particularly regarding the physical and mechanical properties of the soil are discussed. In 2012 a maximum land subsidence of 7.16 cm in a short period of 8 months was recorded with maximum velocities of deformation close to 0.89 centimeters per month. Natural conditions of the zone of study include a lacustrine low land with the perennial Chapala Lake, surrounded by ranges formed by volcanic extrusive rocks, mostly basalts and andesites. Two soil cores of 11 meters depth show the predominance of fine soil but with the incrustation of several sandy lenses of volcanic ash. In the first core closer to the piedmont, the volcanic ash presents an accumulated thickness close to three meters, starting at 4.5 meters depth; on the contrary, this thickness in the second core closer to the lake is critically reduced to no more than 50 centimeters. Even though the predominance of fine soil is significant, water-content averages 100 % and the liquid limit is low, suggesting amongst other possibilities, low content of clay or at least low content of smectites or allophanes in the clayey portion. Other properties of the soil are being determined for analyses. The occurrence of three alignments of ground failures in the community of Jocotepec at the west, mostly faults, suggests highly heterogeneous subsoil. The high volumes of groundwater withdrawn from the local aquifers mainly for agriculture are directly contributing to the increase of the effective stress and surface deformation, however, the relationship between level descents and surficial deformation is still not clear.

User Friendly Processing of Sediment CT Data: Software and Application in High Resolution Non-Destructive Sediment Core Data Sets

NASA Astrophysics Data System (ADS)

Reilly, B. T.; Stoner, J. S.; Wiest, J.; Abbott, M. B.; Francus, P.; Lapointe, F.

2015-12-01

Computed Tomography (CT) of sediment cores allow for high resolution images, three dimensional volumes, and down core profiles, generated through the attenuation of X-rays as a function of density and atomic number. When using a medical CT-Scanner, these quantitative data are stored in pixels using the Hounsfield scale, which are relative to the attenuation of X-rays in water and air at standard temperature and pressure. Here we present MATLAB based software specifically designed for sedimentary applications with a user friendly graphical interface to process DICOM files and stitch overlapping CT scans. For visualization, the software allows easy generation of core slice images with grayscale and false color relative to a user defined Hounsfield number range. For comparison to other high resolution non-destructive methods, down core Hounsfield number profiles are extracted using a method robust to coring imperfections, like deformation, bowing, gaps, and gas expansion. We demonstrate the usefulness of this technique with lacustrine sediment cores from the Western United States and Canadian High Arctic, including Fish Lake, Oregon, and Sawtooth Lake, Ellesmere Island. These sites represent two different depositional environments and provide examples for a variety of common coring defects and lithologies. The Hounsfield profiles and images can be used in combination with other high resolution data sets, including sediment magnetic parameters, XRF core scans and many other types of data, to provide unique insights into how lithology influences paleoenvironmental and paleomagnetic records and their interpretations.

Quantitative estimates of Mid- to late Holocene Climate Variability in northeastern Siberia inferred from chironomids in lake sediments

NASA Astrophysics Data System (ADS)

Nazarova, Larisa; Diekmann, Bernhard; Pestrjakova, Ludmila; Herzschuh, Ulrike; Subetto, Dmitry

2010-05-01

Yakutia (Russia, northeastern part of Eurasia) represents one of Earths most extreme climatic settings in the world with deep-reaching frozen ground and a semiarid continental climate with highest seasonal temperature contrasts in the northern hemisphere. The amplitude of temperature variations around the year sometimes exceeds 100oC. There are few examples of quantitative palaeoecological studies in Siberia and these data have to be tested by quantitative studies from other sites in this region, inferred from different proxies and using regional calibration datasets and temperature models that are still lacking. Chironomid midges (Insecta, Diptera, Chironomidae) have been widely used to reconstruct past climate variability in many areas of Western Europe and North America. A chironomid-mean July air temperature inference model has been developed, based on a modern calibration set of 200 lakes sampled along a transect from 110° to 159° E and 61° to73° N in northern Russia. The inference model was applied to sediment cores from 2 lakes in the Central Yakutia in order to reconstruct past July air temperatures. The lacustrine records span mid- to late Holocene. The downcore variability in the chironomid assemblages and the composition of organic matter give evidence of climate-driven and interrelated changes in biological productivity, lacustrine trophic states, and lake-level fluctuations. Three phases of the climate development in Central Yakutia can be derived from the geochemical composition of the lake cores and according to the inferred from chironomid assemblages mean July air ToC. Content of organic matters reached maximal values in the period between 7000-4500 yBP. Sedimentation rate is especially high, numerous molluscs shells are found in sediments. All this along with the reconstructed air temperature confirmed that Mid Holocene optimum in Central Yakutia took place in this period with the maximal temperatures up to 4oC above present day ToC. Strong

Analytical Results for 42 Fluvial Tailings Cores and 7 Stream Sediment Samples from High Ore Creek, Northern Jefferson County, Montana

USGS Publications Warehouse

Fey, David L.; Church, Stan E.

1998-01-01

Metal-mining related wastes in the Boulder River basin study area in northern Jefferson County, Montana have been implicated in their detrimental effects on water quality with regard to acid-generation and toxic-metal solubility. Sediments, fluvial tailings and water from High Ore Creek have been identified as significant contributors to water quality degradation of the Boulder River below Basin, Montana. A study of 42 fluvial tailings cores and 7 stream sediments from High Ore Creek was undertaken to determine the concentrations of environmentally sensitive elements (i.e. Ag, As, Cd, Cu, Pb, Zn) present in these materials, and the mineral phases containing those elements. Two sites of fluvial deposition of mine-waste contaminated sediment on upper High Ore Creek were sampled using a one-inch soil probe. Forty-two core samples were taken producing 247 subsamples. The samples were analyzed by ICP-AES (inductively coupled-plasma atomic emission spectroscopy) using a total mixed-acid digestion. Results of the core analyses show that the elements described above are present at very high concentrations (to 22,000 ppm As, to 460 ppm Ag, to 900 ppm Cd, 4,300 ppm Cu, 46,000ppm Pb, and 50,000 ppm Zn). Seven stream-sediment samples were also analyzed by ICP-AES for total element content and for leachable element content. Results show that the sediment of High Ore Creek has elevated levels of ore-related metals throughout its length, down to the confluence with the Boulder River, and that the metals are, to a significant degree, contained in the leachable phase, namely the hydrous amorphous iron- and manganese-hydroxide coatings on detrital sediment particles.

Geomicrobiological Features of Ferruginous Sediments from Lake Towuti, Indonesia

PubMed Central

Vuillemin, Aurèle; Friese, André; Alawi, Mashal; Henny, Cynthia; Nomosatryo, Sulung; Wagner, Dirk; Crowe, Sean A.; Kallmeyer, Jens

2016-01-01

Lake Towuti is a tectonic basin, surrounded by ultramafic rocks. Lateritic soils form through weathering and deliver abundant iron (oxy)hydroxides but very little sulfate to the lake and its sediment. To characterize the sediment biogeochemistry, we collected cores at three sites with increasing water depth and decreasing bottom water oxygen concentrations. Microbial cell densities were highest at the shallow site—a feature we attribute to the availability of labile organic matter (OM) and the higher abundance of electron acceptors due to oxic bottom water conditions. At the two other sites, OM degradation and reduction processes below the oxycline led to partial electron acceptor depletion. Genetic information preserved in the sediment as extracellular DNA (eDNA) provided information on aerobic and anaerobic heterotrophs related to Nitrospirae, Chloroflexi, and Thermoplasmatales. These taxa apparently played a significant role in the degradation of sinking OM. However, eDNA concentrations rapidly decreased with core depth. Despite very low sulfate concentrations, sulfate-reducing bacteria were present and viable in sediments at all three sites, as confirmed by measurement of potential sulfate reduction rates. Microbial community fingerprinting supported the presence of taxa related to Deltaproteobacteria and Firmicutes with demonstrated capacity for iron and sulfate reduction. Concomitantly, sequences of Ruminococcaceae, Clostridiales, and Methanomicrobiales indicated potential for fermentative hydrogen and methane production. Such first insights into ferruginous sediments showed that microbial populations perform successive metabolisms related to sulfur, iron, and methane. In theory, iron reduction could reoxidize reduced sulfur compounds and desorb OM from iron minerals to allow remineralization to methane. Overall, we found that biogeochemical processes in the sediments can be linked to redox differences in the bottom waters of the three sites, like oxidant

Assessment of Density Variations of Marine Sediments with Ocean and Sediment Depths

PubMed Central

Tenzer, R.; Gladkikh, V.

2014-01-01

We analyze the density distribution of marine sediments using density samples taken from 716 drill sites of the Deep Sea Drilling Project (DSDP). The samples taken within the upper stratigraphic layer exhibit a prevailing trend of the decreasing density with the increasing ocean depth (at a rate of −0.05 g/cm3 per 1 km). Our results confirm findings of published studies that the density nonlinearly increases with the increasing sediment depth due to compaction. We further establish a 3D density model of marine sediments and propose theoretical models of the ocean-sediment and sediment-bedrock density contrasts. The sediment density-depth equation approximates density samples with an average uncertainty of about 10% and better represents the density distribution especially at deeper sections of basin sediments than a uniform density model. The analysis of DSDP density data also reveals that the average density of marine sediments is 1.70 g/cm3 and the average density of the ocean bedrock is 2.9 g/cm3. PMID:24744686

Method to determine 226Ra in small sediment samples by ultralow background liquid scintillation.

PubMed

Sanchez-Cabeza, Joan-Albert; Kwong, Laval Liong Wee; Betti, Maria

2010-08-15

(210)Pb dating of sediment cores is a widely used tool to reconstruct ecosystem evolution and historical pollution during the last century. Although (226)Ra can be determined by gamma spectrometry, this method shows severe limitations which are, among others, sample size requirements and counting times. In this work, we propose a new strategy based on the analysis of (210)Pb through (210)Po in equilibrium by alpha spectrometry, followed by the determination of (226)Ra (base or supported (210)Pb) without any further chemical purification by liquid scintillation and with a higher sample throughput. Although gamma spectrometry might still be required to determine (137)Cs as an independent tracer, the effort can then be focused only on those sections dated around 1963, when maximum activities are expected. In this work, we optimized the counting conditions, calibrated the system for changing quenching, and described the new method to determine (226)Ra in small sediment samples, after (210)Po determination, allowing a more precise determination of excess (210)Pb ((210)Pb(ex)). The method was validated with reference materials IAEA-384, IAEA-385, and IAEA-313.

Hydrothermal activity and its paleoecological implications in the latest Miocene to Middle Pleistocene lacustrine environments of the Baza Basin (Betic Cordillera, SE Spain)

NASA Astrophysics Data System (ADS)

García-Aguilar, José Manuel; Guerra-Merchán, Antonio; Serrano, Francisco; Palmqvist, Paul; Flores-Moya, Antonio; Martínez-Navarro, Bienvenido

2014-07-01

The continental sedimentary record of the Baza Basin (Guadix-Baza Depression, Betic Cordillera, SE Spain) shows six sedimentary units of lacustrine origin deposited from the latest Miocene to the Middle Pleistocene. Depending on the interval considered, the lacustrine deposits are mainly composed of marls, carbonates or gypsiferous evaporites, showing lithological, mineralogical and geochemical features (i.e., magnesium, strontium and sulfur contents, celestine deposits and travertine growths) that are evidence of intense, tectonically-induced hydrothermal activity. According to the high concentrations of strontium and sulfur as well as the abundance of travertines and magnesium clays, the supply of hot waters was greater during the Zanclean, the Gelasian and the Calabrian, as a result of tectonic activity. Hydrothermal activity has continued until the present time and is responsible of the hot springs that are nowadays active in the Guadix-Baza Depression. The paleoenvironmental consequences of these sublacustrine hot springs were that during some intervals the lakes maintained a relatively permanent water table, not subject to periodic desiccations in the dry season, and warmer temperatures throughout the year. This resulted in a high level of organic productivity, especially for the Calabrian, which allowed the development of a rich and well diversified mammalian community, similar to those of modern African savannas with tree patches. In this mild environment, the permanent water sheet favored the presence of drought intolerant megaherbivores such as the giant extinct hippo Hippopotamus antiquus. The high standing crop biomass of ungulates resulted in the availability of abundant carcasses for scavengers such as hyenas and hominins, which explains the very high densities of skeletal remains preserved in the sediments distributed along the lake surroundings.

Coupled geophysical characterization of shallow fluvio-clastic sediments in Agwagune, southeastern Nigeria

NASA Astrophysics Data System (ADS)

Akpan, Anthony E.; Ekwok, Stephen E.; Ebong, Ebong D.; George, Anthony M.; Okwueze, Emeka E.

2018-07-01

Geophysical investigation performed using electrical resistivity tomography (ERT), vertical electrical sounding (VES), seismic refraction (SRF) and ground penetrating radar (GPR) techniques were used to constrain and characterize shallow lithologic units in the Cross River bank (CRB) in southeastern Nigeria. Results show that the upper layer sediments comprise a 3-5-layered lithostratigraphic sequence with high clayey content. Around the Cross River bank (CRB), the top sediments consist of loose, silty and clayey sands with low resistivities (<150 Ωm) and low P-wave velocities (300-1000 m/s). These attenuating sediments have no reasonable continuity beyond the vicinity of the CRB. The low attenuating indurated silts/sands characterized by low resistivities (<25 Ωm) and high P-wave velocities (1000-2400 m/s) underlie the first layer around in the CRB. Localized microstructures (e.g., fractures) trending east-west, and saturated sand-filled channels truncate their lateral continuities. The lacustrine clays characterized by low resistivities (<15 Ωm) and high P-wave velocities (>2400 m/s) make up the third layer. The clayey sediments impede vertical percolation of groundwater forcing it to accumulate at the bottom of the second layer resulting in high static water levels of <3 m within the CRB and >5 m elsewhere. Hydraulic gradient in the Cross River bed (CRBD) and in the coastal groundwater drives groundwater flow into the CRBD through macropores. The sediments become unstable when these macropores become enlarged as more materials are continuously transmitted through them.

Spatial and temporal variations in the sediment state of North American dune fields

NASA Astrophysics Data System (ADS)

Halfen, Alan F.; Lancaster, Nicholas; Wolfe, Stephen

2015-04-01

This research evaluates geomorphic and chronologic data from the INQUA Dune Atlas for three areas of North America: 1) the Prairie, Parkland and Boreal ecozones of the northern Great Plains in Canada; 2) the Central Great Plains of the USA; and 3) the deserts of southwestern USA and northern Mexico. Chronometric data for periods of dune activity and stability are compared with palaeoenvironment reconstructions to assess dune system response to changes in sediment supply, availability, and mobility. Dune fields in the northern Great Plains were formed from glaciofluvial or glaciolacustrine sediments deposited during deglaciation 16-11 ka. Subsequent aeolian deposition occurred in Parkland and Prairie dune fields as a result of mid-Holocene (8-5 ka) and late-Holocene (< 3.5 ka) activity related to drought conditions. In the Central Great Plains, many dune fields are closely linked to fluvial sediment sources. Sediment supply was high in these dune fields during deglaciation of the Rocky Mountains and resulted in widespread dune construction 16-10 ka. Multiple periods of Holocene reactivation are recorded and reflect increased sediment availability during drought episodes. Dune fields in the southwestern deserts experienced periods of construction as a result of enhanced supply of sediment from fluvial and lacustrine sources during the period 11.8 - 8 ka and at short but repeated intervals during the late Holocene. Despite spatial and temporal gaps in chronometric data, the record from North American dune fields indicates the strong influence of sediment supply on dune construction, with changes in sediment availability, as a result of drought, being the primary driver of dune activity during the Holocene.

Determining the sources of fine-grained sediment using the Sediment Source Assessment Tool (Sed_SAT)

USGS Publications Warehouse

Gorman Sanisaca, Lillian E.; Gellis, Allen C.; Lorenz, David L.

2017-07-27

A sound understanding of sources contributing to instream sediment flux in a watershed is important when developing total maximum daily load (TMDL) management strategies designed to reduce suspended sediment in streams. Sediment fingerprinting and sediment budget approaches are two techniques that, when used jointly, can qualify and quantify the major sources of sediment in a given watershed. The sediment fingerprinting approach uses trace element concentrations from samples in known potential source areas to determine a clear signature of each potential source. A mixing model is then used to determine the relative source contribution to the target suspended sediment samples.The computational steps required to apportion sediment for each target sample are quite involved and time intensive, a problem the Sediment Source Assessment Tool (Sed_SAT) addresses. Sed_SAT is a user-friendly statistical model that guides the user through the necessary steps in order to quantify the relative contributions of sediment sources in a given watershed. The model is written using the statistical software R (R Core Team, 2016b) and utilizes Microsoft Access® as a user interface but requires no prior knowledge of R or Microsoft Access® to successfully run the model successfully. Sed_SAT identifies outliers, corrects for differences in size and organic content in the source samples relative to the target samples, evaluates the conservative behavior of tracers used in fingerprinting by applying a “Bracket Test,” identifies tracers with the highest discriminatory power, and provides robust error analysis through a Monte Carlo simulation following the mixing model. Quantifying sediment source contributions using the sediment fingerprinting approach provides local, State, and Federal land management agencies with important information needed to implement effective strategies to reduce sediment. Sed_SAT is designed to assist these agencies in applying the sediment fingerprinting

A comparison of four porewater sampling methods for metal mixtures and dissolved organic carbon and the implications for sediment toxicity evaluations

USGS Publications Warehouse

Cleveland, Danielle; Brumbaugh, William G.; MacDonald, Donald D.

2017-01-01

Evaluations of sediment quality conditions are commonly conducted using whole-sediment chemistry analyses but can be enhanced by evaluating multiple lines of evidence, including measures of the bioavailable forms of contaminants. In particular, porewater chemistry data provide information that is directly relevant for interpreting sediment toxicity data. Various methods for sampling porewater for trace metals and dissolved organic carbon (DOC), which is an important moderator of metal bioavailability, have been employed. The present study compares the peeper, push point, centrifugation, and diffusive gradients in thin films (DGT) methods for the quantification of 6 metals and DOC. The methods were evaluated at low and high concentrations of metals in 3 sediments having different concentrations of total organic carbon and acid volatile sulfide and different particle-size distributions. At low metal concentrations, centrifugation and push point sampling resulted in up to 100 times higher concentrations of metals and DOC in porewater compared with peepers and DGTs. At elevated metal levels, the measured concentrations were in better agreement among the 4 sampling techniques. The results indicate that there can be marked differences among operationally different porewater sampling methods, and it is unclear if there is a definitive best method for sampling metals and DOC in porewater.

Understanding bioavailability and toxicity of sediment-associated contaminants by combining passive sampling with in vitro bioassays in an urban river catchment.

PubMed

Li, Juan-Ying; Tang, Janet Yat Man; Jin, Ling; Escher, Beate I

2013-12-01

Bioavailable and bioaccessible fractions of sediment-associated contaminants are considered as better dose metrics for sediment-quality assessment than total concentrations. The authors applied exhaustive solvent extraction and nondepletive equilibrium sampling techniques to sediment samples collected along the Brisbane River in South East Queensland, Australia, which range from pristine environments to urban and industry-impacted areas. The wide range of chemicals expected prevents comprehensive chemical analysis, but a battery of cell-based bioassays sheds light on mixture effects of chemicals in relation to various modes of toxic action. Toxic effects were expressed as bioanalytical equivalent concentrations (BEQs) normalized to the organic carbon content of each sediment sample. Bioanalytical equivalent concentrations from exhaustive extraction agreed fairly well with values estimated from polydimethylsiloxane passive sampling extracts via the constant organic carbon to polydimethylsiloxane partition coefficient. Agreement was best for bioassays indicative of photosynthesis inhibition and oxidative stress response and discrepancy within a factor of 3 for the induction of the aryl hydrocarbon receptor. For nonspecific cytotoxicity, BEQ from exhaustive extraction were 1 order of magnitude higher than values from equilibrium sampling, possibly because of coextraction of bioactive natural organic matter that led to an overestimation of toxicity in the exhaustive extracts, which suggests that passive sampling is better suited in combination with bioanalytical assessment than exhaustive extraction. © 2013 SETAC.

Relationships of sedimentation and benthic macroinvertebrate assemblages in headwater streams using systematic longitudinal sampling at the reach scale.

PubMed

Longing, S D; Voshell, J R; Dolloff, C A; Roghair, C N

2010-02-01

Investigating relationships of benthic invertebrates and sedimentation is challenging because fine sediments act as both natural habitat and potential pollutant at excessive levels. Determining benthic invertebrate sensitivity to sedimentation in forested headwater streams comprised of extreme spatial heterogeneity is even more challenging, especially when associated with a background of historical and intense watershed disturbances that contributed unknown amounts of fine sediments to stream channels. This scenario exists in the Chattahoochee National Forest where such historical timber harvests and contemporary land-uses associated with recreation have potentially affected the biological integrity of headwater streams. In this study, we investigated relationships of sedimentation and the macroinvertebrate assemblages among 14 headwater streams in the forest by assigning 30, 100-m reaches to low, medium, or high sedimentation categories. Only one of 17 assemblage metrics (percent clingers) varied significantly across these categories. This finding has important implications for biological assessments by showing streams impaired physically by sedimentation may not be impaired biologically, at least using traditional approaches. A subsequent multivariate cluster analysis and indicator species analysis were used to further investigate biological patterns independent of sedimentation categories. Evaluating the distribution of sedimentation categories among biological reach clusters showed both within-stream variability in reach-scale sedimentation and sedimentation categories generally variable within clusters, reflecting the overall physical heterogeneity of these headwater environments. Furthermore, relationships of individual sedimentation variables and metrics across the biological cluster groups were weak, suggesting these measures of sedimentation are poor predictors of macroinvertebrate assemblage structure when using a systematic longitudinal sampling design

Mt. Fuji Holocene eruption history reconstructed from proximal lake sediments and high-density radiocarbon dating

NASA Astrophysics Data System (ADS)

Obrochta, S.; Yokoyama, Y.; Yoshimoto, M.; Yamamoto, S.; Miyairi, Y.; Nagano, G.; Nakamura, A.; Tsunematsu, K.; Lamair, L.; Hubert-Ferrari, A.; Heyvaert, V.; De Batist, M. A. O.; Fujiwara, O.

2017-12-01

Understanding the eruption history of volcanos located near large population centers is of direct societal relevance. Here we present a 8,000-year lacustrine record that includes previously unreported eruptions of the active Mt. Fuji volcano, which receives approximately 47 million annual visitors with another 40 million living in the adjacent Kanto Plain. A high-fidelity age model is constructed from a number of terrestrial macrofossil and bulk organic radiocarbon measurements and is extremely consistent with the independently determined age of diagnostic tephra layers. In addition to reporting new eruptions, we also present more accurate ages for known eruptions and detect a wider distribution of ejecta for the most recent summit eruption, that latter of which will alter modeled prevailing wind vector during eruption. Furthermore, closely spaced fall-scoria layers, unlikely to be differentiated as separate events in land-based surveys, will lower the estimated mass of ejecta erupted and in turn reduce calculated magnitude. These results, the first of their kind from a highly populated region, demonstrate the utility of lacustrine sediments as powerful tools for understanding characteristics of volcanic eruptions and will improve disaster mitigation plans for the region.

Seeking Signs of Life on Mars: The Importance of Sedimentary Suites as Part of Mars Sample Return

NASA Astrophysics Data System (ADS)

iMOST Team; Mangold, N.; McLennan, S. M.; Czaja, A. D.; Ori, G. G.; Tosca, N. J.; Altieri, F.; Amelin, Y.; Ammannito, E.; Anand, M.; Beaty, D. W.; Benning, L. G.; Bishop, J. L.; Borg, L. E.; Boucher, D.; Brucato, J. R.; Busemann, H.; Campbell, K. A.; Carrier, B. L.; Debaille, V.; Des Marais, D. J.; Dixon, M.; Ehlmann, B. L.; Farmer, J. D.; Fernandez-Remolar, D. C.; Fogarty, J.; Glavin, D. P.; Goreva, Y. S.; Grady, M. M.; Hallis, L. J.; Harrington, A. D.; Hausrath, E. M.; Herd, C. D. K.; Horgan, B.; Humayun, M.; Kleine, T.; Kleinhenz, J.; Mackelprang, R.; Mayhew, L. E.; McCubbin, F. M.; McCoy, J. T.; McSween, H. Y.; Moser, D. E.; Moynier, F.; Mustard, J. F.; Niles, P. B.; Raulin, F.; Rettberg, P.; Rucker, M. A.; Schmitz, N.; Sefton-Nash, E.; Sephton, M. A.; Shaheen, R.; Shuster, D. L.; Siljestrom, S.; Smith, C. L.; Spry, J. A.; Steele, A.; Swindle, T. D.; ten Kate, I. L.; Usui, T.; Van Kranendonk, M. J.; Wadhwa, M.; Weiss, B. P.; Werner, S. C.; Westall, F.; Wheeler, R. M.; Zipfel, J.; Zorzano, M. P.

2018-04-01

Sedimentary, and especially lacustrine, depositional environments are high-priority geological/astrobiological settings for Mars Sample Return. We review the detailed investigations, measurements, and sample types required to evaluate such settings.

Using bioavailability to assess contaminated sediment risk: Passive sampling and Pore Water Remedial Guidelines (PWRGs)

EPA Science Inventory

Hosted by the Contaminated Sediment Forum, this half-day course will introduce the RPM to the use of passive samplers to assess bioavailability and in ecological risk assessment. Passive sampling devices (PSD) are a technology with growing acceptance for measuring porewater conce...

Mechanosensory based orienting behaviors in fluvial and lacustrine populations of mottled sculpin (Cottus bairdi)

Treesearch

Sheryl Coombs; Gary D. Grossman

2006-01-01

We compared prey-orienting and rheotactic behaviors in a fluvial (Coweeta Creek) and lacustrine (Lake Michigan) population of mottled sculpin. Blinded sculpin from both populations exhibited unconditioned, mechanosensory based rheotaxis to low velocity flows. Whereas Lake Michigan sculpin generally showed increasing levels of positive rheotaxis to increasing velocities...

Passive sampling methods for contaminated sediments: Practical guidance for selection, calibration, and implementation

PubMed Central

Ghosh, Upal; Driscoll, Susan Kane; Burgess, Robert M; Jonker, Michiel To; Reible, Danny; Gobas, Frank; Choi, Yongju; Apitz, Sabine E; Maruya, Keith A; Gala, William R; Mortimer, Munro; Beegan, Chris

2014-01-01

This article provides practical guidance on the use of passive sampling methods (PSMs) that target the freely dissolved concentration (Cfree) for improved exposure assessment of hydrophobic organic chemicals in sediments. Primary considerations for selecting a PSM for a specific application include clear delineation of measurement goals for Cfree, whether laboratory-based “ex situ” and/or field-based “in situ” application is desired, and ultimately which PSM is best-suited to fulfill the measurement objectives. Guidelines for proper calibration and validation of PSMs, including use of provisional values for polymer–water partition coefficients, determination of equilibrium status, and confirmation of nondepletive measurement conditions are defined. A hypothetical example is described to illustrate how the measurement of Cfree afforded by PSMs reduces uncertainty in assessing narcotic toxicity for sediments contaminated with polycyclic aromatic hydrocarbons. The article concludes with a discussion of future research that will improve the quality and robustness of Cfree measurements using PSMs, providing a sound scientific basis to support risk assessment and contaminated sediment management decisions. Integr Environ Assess Manag 2014;10:210–223. © 2014 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of SETAC. PMID:24288273

Analytical results and sample locality map for rock, stream-sediment, and soil samples, Northern and Eastern Coloado Desert BLM Resource Area, Imperial, Riverside, and San Bernardino Counties, California

USGS Publications Warehouse

King, Harley D.; Chaffee, Maurice A.

2000-01-01

INTRODUCTION In 1996-1998 the U.S. Geological Survey (USGS) conducted a geochemical study of the Bureau of Land Management's (BLM) 5.5 million-acre Northern and Eastern Colorado Desert Resource Area (usually referred to as the NECD in this report), Imperial, Riverside, and San Bernardino Counties, southeastern California (figure 1). This study was done in support of the BLM's Coordinated Management Plan for the area. This report presents analytical data from this study. To provide comprehensive coverage of the NECD, we compiled and examined all available geochemical data, in digital form, from previous studies in the area, and made sample-site plots to aid in determining where sample-site coverage and analyses were sufficient, which samples should be re-analyzed, and where additional sampling was needed. Previous investigations conducted in parts of the current study area included the National Uranium Resource Evaluation (NURE) program studies of the Needles and Salton Sea 1? x 2? quadrangles; USGS studies of 12 BLM Wilderness Study Areas (WSAs) (Big Maria Mountains, Chemehuevi Mountains, Chuckwalla Mountains, Coxcomb Mountains, Mecca Hills, Orocopia Mountains, Palen-McCoy, Picacho Peak, Riverside Mountains, Sheephole Valley (also known as Sheep Hole/Cadiz), Turtle Mountains, and Whipple Mountains); and USGS studies in the Needles and El Centro 1? x 2? quadrangles done during the early 1990s as part of a project to identify the regional geochemistry of southern California. Areas where we did new sampling of rocks and stream sediments are mainly in the Chocolate Mountain Aerial Gunnery Range and in Joshua Tree National Park, which extends into the west-central part of the NECD, as shown in figure 1 and figure 2. This report contains analytical data for 132 rock samples and 1,245 stream-sediment samples collected by the USGS, and 362 stream-sediment samples and 189 soil samples collected during the NURE program. All samples are from the Northern and Eastern Colorado

Magnetic and gravity studies of Mono Lake, east-central, California

USGS Publications Warehouse

Athens, Noah D.; Ponce, David A.; Jayko, Angela S.; Miller, Matt; McEvoy, Bobby; Marcaida, Mae; Mangan, Margaret T.; Wilkinson, Stuart K.; McClain, James S.; Chuchel, Bruce A.; Denton, Kevin M.

2014-01-01

From August 26 to September 5, 2011, the U.S. Geological Survey (USGS) collected more than 600 line-kilometers of shipborne magnetic data on Mono Lake, 20 line-kilometers of ground magnetic data on Paoha Island, 50 gravity stations on Paoha and Negit Islands, and 28 rock samples on Paoha and Negit Islands, in east-central California. Magnetic and gravity investigations were undertaken in Mono Lake to study regional crustal structures and to aid in understanding the geologic framework, in particular regarding potential geothermal resources and volcanic hazards throughout Mono Basin. Furthermore, shipborne magnetic data illuminate local structures in the upper crust beneath Mono Lake where geologic exposure is absent. Magnetic and gravity methods, which sense contrasting physical properties of the subsurface, are ideal for studying Mono Lake. Exposed rock units surrounding Mono Lake consist mainly of Quaternary alluvium, lacustrine sediment, aeolian deposits, basalt, and Paleozoic granitic and metasedimentary rocks (Bailey, 1989). At Black Point, on the northwest shore of Mono Lake, there is a mafic cinder cone that was produced by a subaqueous eruption around 13.3 ka. Within Mono Lake there are several small dacite cinder cones and flows, forming Negit Island and part of Paoha Island, which also host deposits of Quaternary lacustrine sediments. The typical density and magnetic properties of young volcanic rocks contrast with those of the lacustrine sediment, enabling us to map their subsurface extent.

The quantification of short-chain chlorinated paraffins in sediment samples using comprehensive two-dimensional gas chromatography with μECD detection.

PubMed

Muscalu, Alina M; Morse, Dave; Reiner, Eric J; Górecki, Tadeusz

2017-03-01

The analysis of persistent organic pollutants in environmental samples is a challenge due to the very large number of compounds with varying chemical and physical properties. Chlorinated paraffins (CPs) are complex mixtures of chlorinated n-alkanes with varying chain lengths (C 10 to C 30 ) and degree of chlorination (30 to 70% by weight). Their physical-chemical properties make these compounds persistent in the environment and able to bioaccumulate in living organisms. Comprehensive two-dimensional gas chromatography (GC × GC) coupled with micro-electron capture detection (μECD) was used to separate and quantify short-chain chlorinated paraffins (SCCP) in sediment samples. Distinct ordered bands were observed in the GC × GC chromatograms pointing to group separation. Using the Classification function of the ChromaTOF software, summary tables were generated to determine total area counts to set up multilevel-calibration curves for different technical mixes. Fortified sediment samples were analyzed by GC × GC-μECD with minimal extraction and cleanup. Recoveries ranged from 120 to 130%. To further validate the proposed method for the analysis of SCCPs, the laboratory participated in interlaboratory studies for the analysis of standards and sediment samples. The results showed recoveries between 75 and 95% and z-score values <2, demonstrating that the method is suitable for the analysis of SCCPs in soil/sediment samples. Graphical abstract Quantification of SCCPs by 2D-GC-μECD.

Circulation and sedimentation in a tidal-influenced fjord lake: Lake McKerrow, New Zealand

NASA Astrophysics Data System (ADS)

Pickrill, R. A.; Irwin, J.; Shakespeare, B. S.

1981-01-01

Lake McKerrow is a tide-influenced fjord lake, separated from the open sea by a Holocene barrier spit. Fresh, oxygenated waters of the epilimnion overlie saline, deoxygenated waters of the hypolimnion. During winter, water from the Upper Hollyford River interflows along the pycnocline, depositing coarse silt on the steep delta and transporting finer sediment down-lake. An extensive sub-lacustrine channel system on the foreset delta slope is possibly maintained by turbidity currents. Saline waters of the hypolimnion are periodically replenished. During high tides and low lake levels saline water flows into the lake and downslope into the lake basin as a density current in a well defined channel.

Dioxin-like biological activity of organic extracts from sediments and fish livers sampled along the Israeli Mediterranean and Red Sea coasts.

PubMed

Yudkovski, Yana; Herut, Barak; Shefer, Edna; Tom, Moshe

2015-09-15

This study provides, for the first time, a baseline evaluation of dioxin-like biological activity in sediments and fish sampled in- and adjacent to anchorages along the Mediterranean and Red Sea coasts of Israel. It indicates the effect of past pollution, still present in the sediments of older Israeli harbors, with putative contribution of still existing sources of pollution. A commercial reporter gene bioassay was used to evaluate the biological activity of dioxin-like compounds extracted from the samples. HRGC/HRMS analysis of several samples contributed a profile of dioxin-like compounds in sediments and fish. The results point out 1,2,3,4,6,7,8-HeptaCDD, 2,3,4,6,7,8-HexaCDF, 1,2,3,4,6,7,8-HeptaCDF, РСВ-126 and РСВ-118 as major contributors to the dioxin-like activity in sediments. It indicates polychlorinated biphenyls non-selective absorption in fish livers, in contrary to a biased accumulation of poorly chlorinated and more potent dibenzodioxins and dibenzofurans. Copyright © 2015 Elsevier Ltd. All rights reserved.

Combination of LC/TOF-MS and LC/Ion Trap MS/MS for the Identification of Diphenhydramine in Sediment Samples

USGS Publications Warehouse

Ferrer, I.; Heine, C.E.; Thurman, E.M.

2004-01-01

Diphenhydramine (Benadryl) is a popular over-the-counter antihistaminic medication used for the treatment of allergies. After consumption, excretion, and subsequent discharge from wastewater treatment plants, it is possible that diphenhydramine will be found in environmental sediments due to its hydrophobicity (log P = 3.27). This work describes a methodology for the first unequivocal determination of diphenhydramine bound to environmental sediments. The drug is removed from the sediments by accelerated solvent extraction and then analyzed by liquid chromatography with a time-of-flight mass spectrometer and an ion trap mass spectrometer. This combination of techniques provided unequivocal identification and confirmation of diphenhydramine in two sediment samples. The accurate mass measurements of the protonated molecules were m/z 256.1703 and 256.1696 compared to the calculated mass of m/z 256.1701, resulting in errors of 0.8 and 2.3 ppm. This mass accuracy was sufficient to verify the elemental composition of diphenhydramine in each sample. Furthermore, accurate mass measurements of the primary fragment ion were obtained. This work is the first application of time-of-flight mass spectrometry for the identification of diphenhydramine and shows the accumulation of an over-the-counter medication in aquatic sediments at five different locations.

Passive sampling methods for contaminated sediments: State of the science for organic contaminants

PubMed Central

Lydy, Michael J; Landrum, Peter F; Oen, Amy MP; Allinson, Mayumi; Smedes, Foppe; Harwood, Amanda D; Li, Huizhen; Maruya, Keith A; Liu, Jingfu

2014-01-01

This manuscript surveys the literature on passive sampler methods (PSMs) used in contaminated sediments to assess the chemical activity of organic contaminants. The chemical activity in turn dictates the reactivity and bioavailability of contaminants in sediment. Approaches to measure specific binding of compounds to sediment components, for example, amorphous carbon or specific types of reduced carbon, and the associated partition coefficients are difficult to determine, particularly for native sediment. Thus, the development of PSMs that represent the chemical activity of complex compound–sediment interactions, expressed as the freely dissolved contaminant concentration in porewater (Cfree), offer a better proxy for endpoints of concern, such as reactivity, bioaccumulation, and toxicity. Passive sampling methods have estimated Cfree using both kinetic and equilibrium operating modes and used various polymers as the sorbing phase, for example, polydimethylsiloxane, polyethylene, and polyoxymethylene in various configurations, such as sheets, coated fibers, or vials containing thin films. These PSMs have been applied in laboratory exposures and field deployments covering a variety of spatial and temporal scales. A wide range of calibration conditions exist in the literature to estimate Cfree, but consensus values have not been established. The most critical criteria are the partition coefficient between water and the polymer phase and the equilibrium status of the sampler. In addition, the PSM must not appreciably deplete Cfree in the porewater. Some of the future challenges include establishing a standard approach for PSM measurements, correcting for nonequilibrium conditions, establishing guidance for selection and implementation of PSMs, and translating and applying data collected by PSMs. Integr Environ Assess Manag 2014;10:167–178. © 2014 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of

Fate of polychlorinated biphenyls in a contaminated lake ecosystem: combining equilibrium passive sampling of sediment and water with total concentration measurements of biota.

PubMed

Mäenpää, Kimmo; Leppänen, Matti T; Figueiredo, Kaisa; Mayer, Philipp; Gilbert, Dorothea; Jahnke, Annika; Gil-Allué, Carmen; Akkanen, Jarkko; Nybom, Inna; Herve, Sirpa

2015-11-01

Equilibrium sampling devices can be applied to study and monitor the exposure and fate of hydrophobic organic chemicals on a thermodynamic basis. They can be used to determine freely dissolved concentrations and chemical activity ratios and to predict equilibrium partitioning concentrations of hydrophobic organic chemicals in biota lipids. The authors' aim was to assess the equilibrium status of polychlorinated biphenyls (PCBs) in a contaminated lake ecosystem and along its discharge course using equilibrium sampling devices for measurements in sediment and water and by also analyzing biota. The authors used equilibrium sampling devices (silicone rubber and polyethylene [PE]) to determine freely dissolved concentrations and chemical activities of PCBs in the water column and sediment porewater and calculated for both phases the corresponding equilibrium concentrations and chemical activities in model lipids. Overall, the studied ecosystem appeared to be in disequilibrium for the studied phases: sediment, water, and biota. Chemical activities of PCBs were higher in sediment than in water, which implies that the sediment functioned as a partitioning source of PCBs and that net diffusion occurred from the sediment to the water column. Measured lipid-normalized PCB concentrations in biota were generally below equilibrium lipid concentrations relative to the sediment (CLip ⇌Sed ) or water (CLip ⇌W ), indicating that PCB levels in the organisms were below the maximum partitioning levels. The present study shows the application versatility of equilibrium sampling devices in the field and facilitates a thermodynamic understanding of exposure and fate of PCBs in a contaminated lake and its discharge course. © 2015 SETAC.

Distribution and environmental impacts of heavy metals and radioactivity in sediment and seawater samples of the Marmara Sea.

PubMed

Otansev, Pelin; Taşkın, Halim; Başsarı, Asiye; Varinlioğlu, Ahmet

2016-07-01

In this study, the natural and anthropogenic radioactivity levels in the sediment samples collected from the Marmara Sea in Turkey were determined. The average activity concentrations (range) of (226)Ra, (238)U, (232)Th, (40)K and (137)Cs were found to be 23.8 (13.8-34.2) Bq kg(-1), 18.8 (6.4-25.9) Bq kg(-1), 23.02 (6.3-31.1) Bq kg(-1), 558.6 (378.8-693.6) Bq kg(-1) and 9.14 (4.8-16.3) Bq kg(-1), respectively. Our results showed that the average activity concentrations of (226)Ra, (238)U and (232)Th in the sediment samples were within the acceptable limits; whereas the average activity concentration of (40)K in the sediment samples was higher than the worldwide average concentration. The average radium equivalent activity, the average absorbed dose rate and the average external hazard index were calculated as 100.01 Bq kg(-1), 48.32 nGy h(-1) and 0.27, respectively. The average gross alpha and beta activity in the seawater samples were found to be 0.042 Bq L(-1) and 13.402 Bq L(-1), respectively. The gross alpha and beta activity concentrations increased with water depth in the same stations. The average heavy metal concentrations (range) in the sediment samples were 114.6 (21.6-201.7) μg g(-1) for Cr, 568.2 (190.8-1625.1) μg g(-1) for Mn, 39.3 (4.9-83.4) μg g(-1) for Cu, 85.5 (11.0-171.8) μg g(-1) for Zn, 32.9 (9.1-73.1) μg g(-1) for Pb and 49.1 (6.8-103.0) μg g(-1) for Ni. S5 station was heavily polluted by Cr, Cu, Ni and Pb. The results showed that heavy metal enrichment in sediments of the Marmara Sea was widespread. Copyright © 2016 Elsevier Ltd. All rights reserved.

An innovative piston corer for large‐volume sediment samples

PubMed Central

Haselmair, Alexandra; Stachowitsch, Michael; Zuschin, Martin

2016-01-01

Abstract Coring is one of several standard procedures to extract sediments and their faunas from open marine, estuarine, and limnic environments. Achieving sufficiently deep penetration, obtaining large sediment volumes in single deployments, and avoiding sediment loss upon retrieval remain problematic. We developed a piston corer with a diameter of 16 cm that enables penetration down to 1.5 m in a broad range of soft bottom types, yields sufficient material for multiple analyses, and prevents sediment loss due to a specially designed hydraulic core catcher. A novel extrusion system enables very precise slicing and preserves the original sediment stratification by keeping the liners upright. The corer has moderate purchase costs and a robust and simple design that allows for a deployment from relatively small vessels as available at most marine science institutions. It can easily be operated by two to three researchers rather than by specially trained technicians. In the northern Adriatic Sea, the corer successfully extracted more than 50 cores from a range of fine mud to coarse sand, at water depths from three to 45 m. The initial evaluation of the cores demonstrated their usefulness for fauna sequences along with heavy metal, nutrient and pollutant analyses. Their length is particularly suited for historical ecological work requiring sedimentary and faunal sequences to reconstruct benthic communities over the last millennia. PMID:28111529

Sediment acoustic index method for computing continuous suspended-sediment concentrations

USGS Publications Warehouse

Landers, Mark N.; Straub, Timothy D.; Wood, Molly S.; Domanski, Marian M.

2016-07-11

Once developed, sediment acoustic index ratings must be validated with additional suspended-sediment samples, beyond the period of record used in the rating development, to verify that the regression model continues to adequately represent sediment conditions within the stream. Changes in ADVM configuration or installation, or replacement with another ADVM, may require development of a new rating. The best practices described in this report can be used to develop continuous estimates of suspended-sediment concentration and load using sediment acoustic surrogates to enable more informed and accurate responses to diverse sedimentation issues.

Central Colorado Assessment Project (CCAP)-Geochemical data for rock, sediment, soil, and concentrate sample media

USGS Publications Warehouse

Granitto, Matthew; DeWitt, Ed H.; Klein, Terry L.

2010-01-01

This database was initiated, designed, and populated to collect and integrate geochemical data from central Colorado in order to facilitate geologic mapping, petrologic studies, mineral resource assessment, definition of geochemical baseline values and statistics, environmental impact assessment, and medical geology. The Microsoft Access database serves as a geochemical data warehouse in support of the Central Colorado Assessment Project (CCAP) and contains data tables describing historical and new quantitative and qualitative geochemical analyses determined by 70 analytical laboratory and field methods for 47,478 rock, sediment, soil, and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed either in the analytical laboratories of the USGS or by contract with commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects. In addition, geochemical data from 7,470 sediment and soil samples collected and analyzed under the Atomic Energy Commission National Uranium Resource Evaluation (NURE) Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) program (henceforth called NURE) have been included in this database. In addition to data from 2,377 samples collected and analyzed under CCAP, this dataset includes archived geochemical data originally entered into the in-house Rock Analysis Storage System (RASS) database (used by the USGS from the mid-1960s through the late 1980s) and the in-house PLUTO database (used by the USGS from the mid-1970s through the mid-1990s). All of these data are maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB and from the NURE database were used to generate most of this dataset. In addition, USGS data that have been excluded previously from the NGDB because the data predate earliest USGS geochemical databases, or were once excluded for programmatic reasons

Flashy Water and Sediment Delivery to Fluvial Megafan andFan Delta Systems on Opposing Shorelines of an Early Eocene Lake

NASA Astrophysics Data System (ADS)

Jones, E. R.; Plink-Bjorklund, P.

2015-12-01

Flashy delivery of water and sediment had distinct effects on the process of deposition in coeval fluvial megafan and fan delta deposits on opposing shorelines of a paleolake that occupied the Uinta Basin throughout the Eocene. The Tertiary Uinta Basin was an asymmetric continental interior basin with a steep northern margin, adjacent to the block uplift controlling basin subsidence, and a low gradient southern margin. A ~140 km wide fluvial megafan with catchments as far as ~750 km away occupied the southern margin of the lacustrine basin. Within this megafan system, fluvial deposits contain within-channel continental bioturbation and paleosol development on bar accretion surfaces that are evidence of prolonged periods of groundwater flow or channel abandonment. These are punctuated by channel fills exhibiting a suite of both high-deposition rate and upper flow regime sedimentary structures that were deposited by very rapid suspension-fallout during seasonal to episodic river flooding events. A series of small (~8 km wide) and proximally sourced fan deltas fed sediment into the steeper northern margin of the lacustrine basin. 35-50% of the deposits in the delta plain environment of these fan deltas are very sandy debris flows with as low as 5% clay and silt sized material. Detrital zircon geochronology shows that these fan deltas were tapping catchments where mostly unconsolidated Cretaceous sedimentary cover and thick Jurassic eolianites were being eroded. A combination of flashy precipitation, arid climate, catchments mantled by abundant loose sand-sized colluvium, and steep depositional gradients promoted generation of abundant very sandy (5-10% clay and silt sized material) debris flows. In this way, the Wasatch and Green River Formations in the Uinta Basin, Utah, U.S.A. gives us two very different examples of how routing flashy water and sediment delivery (associated with pulses of hyperthermal climate change during the Early Eocene) through different

Heavy metal and trace elements in riparian vegetation and macrophytes associated with lacustrine systems in Northern Patagonia Andean Range.

PubMed

Juárez, Andrea; Arribére, María A; Arcagni, Marina; Williams, Natalia; Rizzo, Andrea; Ribeiro Guevara, Sergio

2016-09-01

Vegetation associated with lacustrine systems in Northern Patagonia was studied for heavy metal and trace element contents, regarding their elemental contribution to these aquatic ecosystems. The research focused on native species and exotic vascular plant Salix spp. potential for absorbing heavy metals and trace elements. The native species studied were riparian Amomyrtus luma, Austrocedrus chilensis, Chusquea culeou, Desfontainia fulgens, Escallonia rubra, Gaultheria mucronata, Lomatia hirsuta, Luma apiculata, Maytenus boaria, Myrceugenia exsucca, Nothofagus antarctica, Nothofagus dombeyi, Schinus patagonicus, and Weinmannia trichosperma, and macrophytes Hydrocotyle chamaemorus, Isöetes chubutiana, Galium sp., Myriophyllum quitense, Nitella sp. (algae), Potamogeton linguatus, Ranunculus sp., and Schoenoplectus californicus. Fresh leaves were analyzed as well as leaves decomposing within the aquatic bodies, collected from lakes Futalaufquen and Rivadavia (Los Alerces National Park), and lakes Moreno and Nahuel Huapi (Nahuel Huapi National Park). The elements studied were heavy metals Ag, As, Cd, Hg, and U, major elements Ca, K, and Fe, and trace elements Ba, Br, Co, Cr, Cs, Hf, Na, Rb, Se, Sr, and Zn. Geochemical tracers La and Sm were also determined to evaluate contamination of the biological tissues by geological particulate (sediment, soil, dust) and to implement concentration corrections.

Petroleum Hydrocarbon Fingerprints of Water and Sediment Samples of Buffalo River Estuary in the Eastern Cape Province, South Africa

PubMed Central

Okoh, A. I.

2017-01-01

Petroleum hydrocarbon status of the Buffalo River Estuary in East London, South Africa, was evaluated from January to May, 2016. Surface water and sediment samples were collected from five points in the estuary and extracted using standard methods. The extracts were subsequently analyzed by gas chromatography-flame ionization detection. Results showed that total petroleum hydrocarbon (TPH) varied from 7.65 to 477 μg/L in the water and 12.59 to 1,100 mg/kg in the sediments, with mean values of 146.50 ± 27.96 μg/L and 209.81 ± 63.82 mg/kg, respectively. Concentrations of TPH in the sediments correlated significantly with organic carbon (OC) in both seasons. TPH and OC levels were slightly lower in summer than in autumn in the two environmental matrices, and the average amount of TPH in the water samples collected from all the sampling stations was generally lower than the EU standard limit of 300 μg/L. However, the levels in the sediments exceeded the EGASPIN target value (50 mg/kg) for mineral oil but were below the intervention value (5,000 mg/kg), indicating a serious impact of industrial growth and urbanization on the area, although the n-alkane ratios and indexes used for source tracking revealed excessive flow from both natural and anthropogenic sources. PMID:28638675

Sediment records of Yellow River channel migration and Holocene environmental evolution of the Hetao Plain, northern China

NASA Astrophysics Data System (ADS)

Wang, Jingzhong; Wu, Jinglu; Pan, Baotian; Jia, Hongjuan; Li, Xiao; Wei, Hao

2018-05-01

The origin and evolution of lakes in the Hetao Plain, northern China, were influenced by climate variation, channel migration, and human activity. We analyzed a suite of sediment cores from the region to investigate Yellow River channel migration and environmental change in this region over the Holocene. Short sediment cores show that environmental indicators changed markedly around CE 1850, a time that corresponds to flood events, when large amounts of river water accumulated in the western part of the Hetao Plain, giving rise to abundant small lakes. Multiple sediment variables (environmental proxies) from two long cores collected in the Tushenze Paleolake area show that sediments deposited between 12.0 and 9.0 cal ka BP were yellow clay, indicative of fluvial deposition and channel migration. From 9.0 to 7.5 cal ka BP, sand was deposited, reflecting a desert environment. From 7.5 to 2.2 cal ka BP, however, the sediments were blue-gray clay that represents lacustrine facies of Lake Tushenze, which owes its origin to an increase in strength of the East Asian monsoon. At about 2.2 cal ka BP, the north branch of the Yellow River was flooded, and the Tushenze Paleolake developed further. Around 2.0 cal ka BP, the paleolake shrank and eolian sedimentation was recorded. The analyzed sediment records are consistent with the written history from the region, which documents channel migration and environmental changes in the Hetao Plain over the Holocene.

Distal alluvial fan sediments in early Proterozoic red beds of the Wilgerivier formation, Waterberg Group, South Africa

NASA Astrophysics Data System (ADS)

Van Der Neut, M.; Eriksson, P. G.; Callaghan, C. C.

The 1900 - 1700 M.a. Waterberg Group belongs to a series of southern African cratonic cover sequences of roughly equivalent age. Red beds of the Wilgerivier Formation comprise sandstones, interbedded with subordinate conglomerates and minor mudrocks. These immature sedimentary rocks exhibit lenticular bedding, radial palaeocurrent patterns and features indicative of both streamflow and gravity-flow deposition. A distal wet alluvial fan palaeoenvironmental setting is envisaged, with fan-deltas forming where alluvial lobes prograded into a lacustrine basin. Intrastratal, diagenetic alteration of ferromagnesian detrital grains and ferruginous grain coatings led to the red colouration of the Wilgerivier sediments.

Linking groundwater dissolved organic matter to sedimentary organic matter from a fluvio-lacustrine aquifer at Jianghan Plain, China by EEM-PARAFAC and hydrochemical analyses.

PubMed

Huang, Shuang-bing; Wang, Yan-xin; Ma, Teng; Tong, Lei; Wang, Yan-yan; Liu, Chang-rong; Zhao, Long

2015-10-01

The sources of dissolved organic matter (DOM) in groundwater are important to groundwater chemistry and quality. This study examined similarities in the nature of DOM and investigated the link between groundwater DOM (GDOM) and sedimentary organic matter (SOM) from a lacustrine-alluvial aquifer at Jianghan Plain. Sediment, groundwater and surface water samples were employed for SOM extraction, optical and/or chemical characterization, and subsequent fluorescence excitation-emission matrix (EEM) and parallel factor analyses (PARAFAC). Spectroscopic properties of bulk DOM pools showed that indices indicative of GDOM (e.g., biological source properties, humification level, aromaticity and molecule mobility) varied within the ranges of those of two extracted end-members of SOM: humic-like materials and microbe-associated materials. The coexistence of PARAFAC compositions and the sustaining internal relationship between GDOM and extracted SOM indicate a similar source. The results from principal component analyses with selected spectroscopic indices showed that GDOM exhibited a transition trend regarding its nature: from refractory high-humification DOM to intermediate humification DOM and then to microbe-associated DOM, with decreasing molecular weight. Correlations of spectroscopic indices with physicochemical parameters of the groundwater suggested that GDOM was released from SOM and was modified by microbial diagenetic processes. The current study demonstrated the associations of GDOM with SOM from a spectroscopic viewpoint and provided new evidence supporting SOM as the source of GDOM. Copyright © 2015 Elsevier B.V. All rights reserved.

Linking microbial assemblages to paleoenvironmental conditions from the Holocene and Last Glacial Maximum times in Laguna Potrok Aike sediments, Argentina

NASA Astrophysics Data System (ADS)

Vuillemin, Aurele; Ariztegui, Daniel; Leavitt, Peter R.; Bunting, Lynda

2014-05-01

Laguna Potrok Aike is a closed basin located in the southern hemisphere's mid-latitudes (52°S) where paleoenvironmental conditions were recorded as temporal sedimentary sequences resulting from variations in the regional hydrological regime and geology of the catchment. The interpretation of the limnogeological multiproxy record developed during the ICDP-PASADO project allowed the identification of contrasting time windows associated with the fluctuations of Southern Westerly Winds. In the framework of this project, a 100-m-long core was also dedicated to a detailed geomicrobiological study which aimed at a thorough investigation of the lacustrine subsurface biosphere. Indeed, aquatic sediments do not only record past climatic conditions, but also provide a wide range of ecological niches for microbes. In this context, the influence of environmental features upon microbial development and survival remained still unexplored for the deep lacustrine realm. Therefore, we investigated living microbes throughout the sedimentary sequence using in situ ATP assays and DAPI cell count. These results, compiled with pore water analysis, SEM microscopy of authigenic concretions and methane and fatty acid biogeochemistry, provided evidence for a sustained microbial activity in deep sediments and pinpointed the substantial role of microbial processes in modifying initial organic and mineral fractions. Finally, because the genetic material associated with microorganisms can be preserved in sediments over millennia, we extracted environmental DNA from Laguna Potrok Aike sediments and established 16S rRNA bacterial and archaeal clone libraries to better define the use of DNA-based techniques in reconstructing past environments. We focused on two sedimentary horizons both displaying in situ microbial activity, respectively corresponding to the Holocene and Last Glacial Maximum periods. Sequences recovered from the productive Holocene record revealed a microbial community adapted to

Evaluation of zirconium as a permanent chemical modifier using synchrotron radiation and imaging techniques for lithium determination in sediment slurry samples by ET AAS.

PubMed

Flores, Araceli V; Pérez, Carlos A; Arruda, Marco A Z

2004-02-27

In the present paper, lithium was determined in river sediment using slurry sampling and electrothermal atomic absorption spectrometry (ET AAS) after L'vov platform coating with zirconium (as a permanent chemical modifier). The performance of this modifier and its distribution on the L'vov platform after different heating cycles were evaluated using synchrotron radiation X-ray fluorescence (SRXRF) and imaging scanning electron microscopy (SEM) techniques. The analytical conditions for lithium determination in river sediment slurries were also investigated and the best conditions were obtained employing 1300 and 2300 degrees C for pyrolysis and atomization temperatures, respectively. In addition, 100mg of sediment samples were prepared using 4.0moll(-1) HNO(3). The Zr-coating permitted lithium determination with good precision and accuracy after 480 heating cycles using the same platform for slurry samples. The sediment samples were collected from five different points of the Cachoeira river, São Paulo, Brazil. The detection and quantification limits were, respectively, 0.07 and 0.23mugl(-1).

dSED: A database tool for modeling sediment early diagenesis

NASA Astrophysics Data System (ADS)

Katsev, S.; Rancourt, D. G.; L'Heureux, I.

2003-04-01

Sediment early diagenesis reaction transport models (RTMs) are becoming powerful tools in providing kinetic descriptions of the metal and nutrient diagenetic cycling in marine, lacustrine, estuarine, and other aquatic sediments, as well as of exchanges with the water column. Whereas there exist several good database/program combinations for thermodynamic equilibrium calculations in aqueous systems, at present there exist no database tools for classification and analysis of the kinetic data essential to RTM development. We present a database tool that is intended to serve as an online resource for information about chemical reactions, solid phase and solute reactants, sorption reactions, transport mechanisms, and kinetic and equilibrium parameters that are relevant to sediment diagenesis processes. The list of reactive substances includes but is not limited to organic matter, Fe and Mn oxides and oxyhydroxides, sulfides and sulfates, calcium, iron, and manganese carbonates, phosphorus-bearing minerals, and silicates. Aqueous phases include dissolved carbon dioxide, oxygen, methane, hydrogen sulfide, sulfate, nitrate, phosphate, some organic compounds, and dissolved metal species. A number of filters allow extracting information according to user-specified criteria, e.g., about a class of substances contributing to the cycling of iron. The database also includes bibliographic information about published diagenetic models and the reactions and processes that they consider. At the time of preparing this abstract, dSED contained 128 reactions and 12 pre-defined filters. dSED is maintained by the Lake Sediment Structure and Evolution (LSSE) group at the University of Ottawa (www.science.uottawa.ca/LSSE/dSED) and we invite input from the geochemical community.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cregg, A.K.

Kenya basins have evolved primarily through extension related to episodic continental rifting. In eastern Kenya, thick accumulations of sediments formed within grabens during the prerift phase (Precambrian to Carboniferous) of the Gondwana breakup. Synrift sedimentation (Late Carboniferous to Middle Jurassic) occurred within a north-south rift system, which included the Mandera basin, South Anza basin, and Lamu embayment. During the Early Jurassic, a marine transgression invaded the margins of the eastern Kenya rift basins, resulting in the deposition of platform carbonates and shales. A Callovian-aged salt basin formed in the offshore regions of the Lamu embayment. Intermittent tectonic activity and eustaticmore » sea-level changes controlled sedimentation, which produced marine shales, carbonates or evaporites, and fluvio-deltaic to lacustrine sandstones. From the Early Cretaceous to recent, continental sediments were deposited within the North Anza and Turkana basins. These fluvial-lacustrine sediments are similar to the Lower Cretaceous sequences that have produced oil in the Mesozoic Sudanese Abu Gabra rift. Although exploration activities began in the early 1950s, significant occurrences of potential reservoir, source, and seal lithologies as well as trapping configurations remain in many areas. Favorable structures and sequences of reservoir sandstones and carbonates overlain by potentially sealing lacustrine or marine shales, evaporites, or volcanics have been noted. Potential source beds are believed to be present within shales of the lacustrine or marine depositional environments.« less

From submarine to lacustrine groundwater discharge

USGS Publications Warehouse

Lewandowski, Jörg; Meinikmann, Karin; Pöschke, Franziska; Nützmann, Gunnar; Rosenberry, Donald O.

2017-01-01

Submarine groundwater discharge (SGD) and its role in marine nutrient cycling are well known since the last decade. The freshwater equivalent, lacustrine groundwater discharge (LGD), is often still disregarded, although first reports of LGD are more than 50 years old. We identify nine different reasons why groundwater has long been disregarded in both freshwater and marine environments such as invisibility of groundwater discharge, the size of the interface and its difficult accessibility. Although there are some fundamental differences in the hydrology of SGD and LGD, caused primarily by seawater recirculation that occurs only in cases of SGD, there are also a lot of similarities such as a focusing of discharge to near-shore areas. Nutrient concentrations in groundwater near the groundwater–surface water interface might be anthropogenically enriched. Due to spatial heterogeneity of aquifer characteristics and biogeochemical processes, the quantification of groundwater-borne nutrient loads is challenging. Both nitrogen and phosphorus might be mobile in near-shore aquifers and in a lot of case studies large groundwater-borne nutrient loads have been reported.

Sediment Coring of the Proglacial Lake Donguz-Orun (northern Caucasus, Russia)

NASA Astrophysics Data System (ADS)

Alexandrin, Mikhail; Solomina, Olga; Kalugin, Ivan; Darin, Andrey; Nesje, Atle

2014-05-01

So far, no high-resolution reconstructions of climate and glacier variations based on lake sediment properties are available in Caucasus Mountains. In other presently glaciated regions this approach is proved to be very useful for this purpose (e.g. Nesje et al., 2001, 2011; Bakke, 2005, Nesje, 2009) In this paper we report the first results of the sediment coring of Donguz-Orun Lake (N 43°13'26", E 42°29'35") situated in the upper reaches of Donguz-Orun-Kyol, a tributary of Baksan river in the Elbrus region of Northern Caucasus, a typical proglacial lake dammed by a lateral moraine deposited by the Donguz-Orun Glacier. It is a drainage lake with several inflowing glacial streams and effluent river Donguz-Orun. The surface area is around 105 000 m2 with a water volume of 465 000m3. The average water depth is around 4.5 m, with a maximum water depth of 14 m. The deepest part is found close to the moraine dam in the narrow northern part of the lake. This is normally consistent with this type of glacial lake systems. An intensive gravitational drift of the moraine material towards the lake is observed. These non-rounded moraine boulders constitute a significant part of the lakebed. Lacustrine sediments are present though. The coring campaign from Institute of Geography, Russian Academy of Sciences (August 2012) used a modified piston corer with a 110 mm-diameter plastic tube (Nesje, 1992) mounted on the inflatable catamaran to obtain lake sediments from Lake Donguz-Orun. A 28-cm long core was retrieved from a water depth of around 7 m. The sediments consist of regularly laminated, fine beige clay, with several interlayers of sand. The coring process appeared to be challenging due to the stiffness of clay, which led to extreme bending of the sediment layers in the basal part of the core. The original thickness of the sediments was obviously higher than observed in the core. In order to clarify the recent history of the Donguz-Orun glacier, we used lichenometry and

Late Holocene Climate Change Inferred From Varved Proglacial Lake Sediments on Northeastern Baffin Island, Arctic Canada

NASA Astrophysics Data System (ADS)

Thomas, E. K.; Briner, J. P.; Axford, Y.

2007-12-01

The Arctic has a disproportionately large response to changes in radiative forcing of climate, and glaciers and arctic lacustrine ecosystems respond sensitively to these changes. Lacustrine ecosystems throughout the Arctic are undergoing rapid regime shifts, including dramatically increased primary productivity and changing aquatic floral and faunal assemblages. Our work on organic lake sediments from northeast Baffin Island shows a large increase in primary productivity, changes in insect (Chironomidae) assemblages including the disappearance of cold stenotherms, and a rise in chironomid-inferred summer water temperatures of at least 1.5°C over the past 50 years, reaching temperatures that were unprecedented in the past 5000 years. Here, we pursue the use of varve thickness, an abiotic temperature proxy, to expand our understanding of late Holocene temperature changes on northeast Baffin Island. We obtained a 14C- and 239+240Pu-dated surface core/percussion core pair from a proglacial lake. Together these cores span > 8000 years and the sediments are varved, as verified by the 239+240Pu analysis, for at least the past 700 years. Magnetic susceptibility was high during the early Holocene, decreased to near-zero values during the mid-Holocene and increased during the past 2500 years to reach the highest values seen in the record around 1000 years ago. Loss-on- ignition had an opposite trend, with the highest values in the mid-Holocene. Sedimentation rate was constant during most of the Holocene (0.03 cm yr -1) and increased during the past 1000 years to 0.05 cm yr -1. These parameters indicate that following the absence of an active glacier during the middle Holocene, glacier activity initiated ~2500 years ago and reached peak activity over the last 1000 years. Our ongoing work to obtain a varve-thickness record for at least the last 700 years, and its calibration to a nearby weather station, will be presented.

Cyclic Sediment Trading Between Channel and River Bed Sediments

NASA Astrophysics Data System (ADS)

Haddadchi, A.

2015-12-01

Much of the previous work on sediment tracing has focused on determining either the initial sources of the sediment (soils derive from a particular rock type) or the erosion processes generating the sediment. However, alluvial stores can be both a source and sink for sediment transported by streams. Here geochemical and fallout radionuclide tracing of river-bed and alluvial sediments are used to determine the role of secondary sources, sediment stores, as potential sources of sediment leaving Emu Creek catchment, southeastern Queensland, Australia. Activity concentrations of 137Cs on the river sediments are consistent with channel erosion being the dominant source at all sites sampled along the river. To characterise the deposition and remobilisation cycles in the catchment, a novel geochemical tracing approach was used. Successive pockets of alluvium were treated as discrete sink terms within geochemical mixing models and their source contributions compared with those of river bed sediments collected adjacent to each alluvial pocket. Three different size fractions were examined; silts and clays (<10 μm), silts (10-63 μm), and fine sands (63-212 μm). The contribution of the initial soil/rock type sources to river bed and alluvial sediments at each sampling site was identical for all three different size fractions, but varied along the stream. Combining these findings it is concluded that proximal alluvial stores dominated the supply of sediment to the river at each location, with this being particularly evident at the catchment outlet. Identical contribution of rock type sources to both river bed and alluvial pockets together with the dominant erosion being from channel banks indicates a high degree of 'trading' between the fluvial space and the alluvial space. Hence, management works aimed at primarily reducing the supply of sediments to the outlet of Emu Creek should focus on rehabilitation of channel banks in the lower catchment.

Basin evolution during Cretaceous-Oligocene changes in sediment routing in the Eastern Precordillera, Argentina

NASA Astrophysics Data System (ADS)

Reat, Ellen J.; Fosdick, Julie C.

2018-07-01

The response of sedimentary basins to earliest onset of Andean contraction and lithospheric flexure in the southern Central Andes is debated and not well-resolved. The Upper Cretaceous to Oligocene strata of the Cuesta de Huaco anticline in the Argentine Precordillera record sedimentation, regional deformation, and climate patterns prior to the highly studied Oligocene-Miocene foreland basin phase. These deposits have recently been recognized as Cretaceous and Paleogene in age, prompting a re-evaluation of this depocenter as part of the early Andean system, prior to deposition of the aeolian foredeep sediments of the Oligocene Vallecito Formation. This work presents new data from the Argentine Precordillera fold-and-thrust belt at 30°S that sheds light on new reinterpretations of the timing of sedimentation for an important interval in Andean retroarc foreland basin history. We report the first Paleocene detrital radiometric ages from the Cuesta de Huaco 'red strata' of the pre-Oligocene Bermejo Basin. Detailed sedimentology and provenance data from the Cenomanian-Turonian Ciénaga del Río Huaco and Danian-Priabonian Puesto La Flecha formations reveal a Cenomanian-Turonian braided stream system that transitioned into a shallow freshwater lacustrine depocenter in Paleocene-Eocene time. During Late Cretaceous time, sediment in the braided river system was derived primarily from northeastern cratonic sources; during the Paleocene-Eocene, uplift and unroofing of the Andean arc and Frontal Cordillera resulted in an influx of western-derived sediment. We therefore suggest a revised timing of sedimentation for the transition to Andean retroarc foreland basin deposition.

Targeting sediment management strategies using sediment quantification and fingerprinting methods

NASA Astrophysics Data System (ADS)

Sherriff, Sophie; Rowan, John; Fenton, Owen; Jordan, Phil; hUallacháin, Daire Ó.

2016-04-01

Cost-effective sediment management is required to reduce excessive delivery of fine sediment due to intensive land uses such as agriculture, resulting in the degradation of aquatic ecosystems. Prioritising measures to mitigate dominant sediment sources is, however, challenging, as sediment loss risk is spatially and temporally variable between and within catchments. Fluctuations in sediment supply from potential sources result from variations in land uses resulting in increased erodibility where ground cover is low (e.g., cultivated, poached and compacted soils), and physical catchment characteristics controlling hydrological connectivity and transport pathways (surface and/or sub-surface). Sediment fingerprinting is an evidence-based management tool to identify sources of in-stream sediments at the catchment scale. Potential sediment sources are related to a river sediment sample, comprising a mixture of source sediments, using natural physico-chemical characteristics (or 'tracers'), and contributions are statistically un-mixed. Suspended sediment data were collected over two years at the outlet of three intensive agricultural catchments (approximately 10 km2) in Ireland. Dominant catchment characteristics were grassland on poorly-drained soils, arable on well-drained soils and arable on moderately-drained soils. High-resolution (10-min) calibrated turbidity-based suspended sediment and discharge data were combined to quantify yield. In-stream sediment samples (for fingerprinting analysis) were collected at six to twelve week intervals, using time-integrated sediment samplers. Potential sources, including stream channel banks, ditches, arable and grassland field topsoils, damaged road verges and tracks were sampled, oven-dried (<40oC) and sieved (125 microns). Soil and sediment samples were analysed for mineral magnetics, geochemistry and radionuclide tracers, particle size distribution and soil organic carbon. Tracer data were corrected to account for particle

Concentrations of Elements in Sediments and Selective Fractions of Sediments, and in Natural Waters in Contact with Sediments from Lake Roosevelt, Washington, September 2004

USGS Publications Warehouse

Paulson, Anthony J.; Wagner, Richard J.; Sanzolone, Richard F.; Cox, Steven E.

2006-01-01

Twenty-eight composite and replicate sediment samples from 8 Lake Roosevelt sites were collected and analyzed for 10 alkali and alkaline earth elements, 2 non-metals, 20 metals, and 4 lanthanide and actinide elements. All elements were detected in all sediment samples except for silver (95 percent of the elements detected for 1,008 analyses), which was detected only in 4 samples. Sequential selective extraction procedures were performed on single composite samples from the eight sites. The percentage of detections for the 31 elements analyzed ranged from 76 percent for the first extraction fraction using a weak extractant to 93 percent for the four-acid dissolution of the sediments remaining after the third sequential selective extraction. Water samples in various degrees of contact with the sediment were analyzed for 10 alkali and alkaline earth elements, 5 non-metals, 25 metals, and 16 lanthanide and actinide elements. The filtered water samples included 10 samples from the reservoir water column at 8 sites, 32 samples of porewater, 55 samples from reservoir water overlying sediments in 8 cores from the site incubated in a field laboratory, and 24 water samples that were filtered after being tumbled with sediments from 8 sites. Overall, the concentrations of only 37 percent of the 6,776 analyses of the 121 water samples were greater than the reporting limit. Selenium, bismuth, chromium, niobium, silver, and zirconium were not detected in any water samples. The percentage of concentrations for the water samples that were above the reporting limit ranged from 14 percent for the lanthanide and actinide elements to 77 percent for the alkali and alkaline earth elements. Concentrations were greater than reporting limits in only 23 percent of the analyses of reservoir water and 29 percent of the analyses of reservoir water overlying incubation cores. In contrast, 47 and 48 percent of the concentrations of porewater and water samples tumbled with sediments, respectively

Fluvial sediments a summary of source, transportation, deposition, and measurement of sediment discharge

USGS Publications Warehouse

Colby, B.R.

1963-01-01

continuously at about the velocity of the flow, and even low flows can transport large amounts of fine sediment. Hence, the discharge of fine sediments, being largely dependent on the availability of fine sediment upstream rather than on the properties of the sediment and of the flow at a cross section, can seldom be computed from properties, other than concentrations based directly on samples, that can be observed at the cross section. Sediment particles continually change their positions in the flow; some fall to the streambed, and others are removed from the bed. Sediment deposits form locally or over large areas if the volume rate at which particles settle to the bed exceeds the volume rate at which particles are removed from the bed. In general, large particles are deposited more readily than small particles, whether the point of deposition is behind a rock, on a flood plain, within a stream channel, or at the entrance to a reservoir, a lake, or the ocean. Most samplers used for sediment observations collect a water-sediment mixture from the water surface to within a few tenths of a foot of the streambed. They thus sample most of the suspended sediment, especially if the flow is deep or if the sediment is mostly fine; but they exclude the bedload and some of the suspended sediment in a layer near the streambed where the suspended-sediment concentrations are highest. Measured sediment discharges are usually based on concentrations that are averages of several individual sediment samples for a cross section. If enough average concentrations for a cross section have been determined, the measured sediment discharge can be computed by interpolating sediment concentrations between sampling times. If only occasional samples were collected, an average relation between sediment discharge and flow can be used with a flow-duration curve to compute roughly the average or the total sediment discharges for any periods of time for which the flow-duration c

The Lacustrine Upper Brushy Basin Member of the Morrison Formation, Four Corners Region, Usa: a Lithological and Mineralogical Terrestrial Analog for Gale Crater, Mars

NASA Astrophysics Data System (ADS)

Potter-McIntyre, S. L.; Chan, M. A.; McPherson, B. J.

2013-12-01

The upper part of the Jurassic Brushy Basin Member of the Morrison Formation is an iron- and clay-rich volcaniclastic shale deposited in an ephemeral alkaline saline lake system. Sedimentary rocks exposed in Gale Crater consist of similar non-acidic clays, possibly of lacustrine origin. Three primary clastic lithofacies are present in both the Brushy Basin Member and at Gale Crater: silt-/claystone, sandstone, and conglomerate. Both the terrestrial and martian silt-/claystone lithofacies are interpreted as lacustrine depositional environments due to features such as parallel laminated and massive sedimentary structures. Vugs are present in the siltstone/claystone facies on both the Colorado Plateau and at Gale Crater. Fluvial features are also observed in both examples such as cross-bedded sandstones and imbricated conglomerates. Concretions are present in both the Colorado Plateau and Gale Crater units. The vugs in the Brushy Basin Member preserve algal forms with cellular elaboration and are interpreted as charophyte molds. Two distinct suites of elements (1. C, Fe, As, P and, 2. C, S, Se, P) are associated with the microbial fossils and may be potential markers for biosignatures. Vugs at Gale Crater are a potential target to investigate the possibility of preserved microbial (algal) life where early analyses show the presence of the elements capable of supporting life. The Brushy Basin Member is composed predominately of quartz, feldspars, zeolites and altered volcanic ash. The abundant clay minerals in both the terrestrial and martian examples are hypothesized to have formed due to partial alteration of volcanic minerals in alkaline fluid. Similarly, concretions present in the terrestrial unit exhibit a diverse range of mineralogies likely due to alkaline fluid chemistries interacting with reactive volcaniclastic sediments. Terrestrial concretion mineralogy is diverse even within an outcrop or stratigraphic horizon which suggests reactants to precipitate

Radiocarbon ages of lacustrine deposits in volcanic sequences of the Lomas Coloradas area, Socorro Island, Mexico

NASA Technical Reports Server (NTRS)

Farmer, J. D.; Farmer, M. C.; Berger, R.

1993-01-01

Extensive eruptions of alkalic basalt from low-elevation fissures and vents on the southern flank of the dormant volcano, Cerro Evermann, accompanied the most recent phase of volcanic activity on Socorro Island, and created the Lomas Coloradas, a broad, gently sloping terrain comprising the southern part of the island. We obtained 14C ages of 4690 +/- 270 BP (5000-5700 cal BP) and 5040 +/- 460 BP (5300-6300 cal BP) from lacustrine deposits that occur within volcanic sequences of the lower Lomas Coloradas. Apparently, the sediments accumulated within a topographic depression between two scoria cones shortly after they formed. The lacrustine environment was destroyed when the cones were breached by headward erosion of adjacent stream drainages. This was followed by the eruption of a thin basaltic flow from fissures near the base of the northernmost cone. The flow moved downslope for a short distance and into the drainages that presently bound the study area on the east and west. The flow postdates development of the present drainage system and may be very recent. Our 14C data, along with historical accounts of volcanic activity over the last century, including submarine eruptions that occurred a few km west of Socorro in early 1993, underscore the high risk for explosive volcanism in this region and the need for a detailed volcanic hazards plan and seismic monitoring.

Unusual Holocene and late Pleistocene carbonate sedimentation in Bear Lake, Utah and Idaho, USA

USGS Publications Warehouse

Dean, W.; Rosenbaum, J.; Skipp, G.; Colman, S.; Forester, R.; Liu, A.; Simmons, K.; Bischoff, J.

2006-01-01

Bear Lake (Utah-Idaho, USA) has been producing large quantities of carbonate minerals of varying mineralogy for the past 17,000 years. The history of sedimentation in Bear Lake is documented through the study of isotopic ratios of oxygen, carbon, and strontium, percent organic carbon, percent CaCO3, X-ray diffraction mineralogy, HCl-leach inorganic geochemistry, and magnetic properties on samples from three piston cores. Historically, the Bear River, the main source of water for Great Salt Lake, did not enter Bear Lake until it was artificially diverted into the lake at the beginning of the 20th century. However, during the last glacial interval, the Bear River did enter Bear Lake depositing red, calcareous, silty clay. About 18,000 years ago, the Bear River became disconnected from Bear Lake. A combination of warmer water, increased evaporation, and increased organic productivity triggered the precipitation of calcium carbonate, first as calcite. As the salinity of the lake increased due to evaporation, aragonite began to precipitate about 11,000 years ago. Aragonite is the dominant mineral that accumulated in bottom sediments of the lake during the Holocene, comprising an average of about 70 wt.% of the sediments. Aragonite formation in a large, cold, oligotrophic, high latitude lake is highly unusual. Lacustrine aragonite usually is found in small, saline lakes in which the salinity varies considerably over time. However, Bear Lake contains endemic ostracodes and fish, which indicate that the chemistry of the lake has remained fairly constant for a long time. Stable isotope data from Holocene aragonite show that the salinity of Bear Lake increased throughout the Holocene, but never reached highly evolved values of ??18O in spite of an evaporation-dominated water balance. Bear Lake hydrology combined with evaporation created an unusual situation that produced large amounts of aragonite, but no evaporite minerals.

Surface-sediment grain-size distribution and sediment transport in the subaqueous Mekong Delta, Vietnam

NASA Astrophysics Data System (ADS)

Nguyen, T. T.; Stattegger, K.; Nittrouer, C.; Phung, P. V.; Liu, P.; DeMaster, D. J.; Bui, D. V.; Le, A. D.; Nguyen, T. N.

2016-02-01

Collected surface-sediment samples in coastal water around Mekong Delta (from distributary channels to Ca Mau Peninsula) were analyzed to determine surface-sediment grain-size distribution and sediment-transport trend in the subaqueous Mekong Delta. The grain-size data set of 238 samples was obtained by using the laser instrument Mastersizer 2000 and LS Particle Size Analyzer. Fourteen samples were selected for geochemical analysis (total-organic and carbonate content). These geochemical results were used to assist in interpreting variations of granulometricparamenters along the cross-shore transects. Nine transects were examined from CungHau river mouth to Ca Mau Peninsula and six thematic maps on the whole study area were made. The research results indicate that: (1) generally, the sediment becomes finer from the delta front downwards to prodelta and becomes coarser again and poorer sorted on the adjacent inner shelf due to different sources of sediment; (2) sediment-granulometry parameters vary among sedimentary sub-environments of the underwater part of Mekong Delta, the distance from sediment source and hydrodynamic regime controlling each region; (3) the net sediment transport is southwest toward the Ca Mau Peninsula.

K1-95-HW, cruise report 1995: preliminary results. Phase III: sediment chemistry and biological sampling survey

USGS Publications Warehouse

Torresan, M.E.; Hampton, M.A.; Barber, J.H.; Wong, F.L.

1995-01-01

Mamala Bay, off the south shore of the island of Oahu, has been used as a repository of dredged material primarily from Pearl and Honolulu Harbors for over a century. The U.S. Geological Survey, U.S. Army Corps of Engineers, and the U.S. Environmental Protection Agency are conducting an integrated study on the distribution and character of dredged materials as well as the effects of dredged material on the marine environment. A three phase study is providing information to evaluate the effects on seafloor substrate and the benthic fauna. The studies include geophysical profiling and imaging, bottom photography, sampling, chemical and physical analyses of sediment, and evaluations of the benthic population, population density, and adverse impacts to the benthic fauna. Phase 1, conducted in 1993, inventoried the seafloor via remote sensing. Sidescan sonar and subbottom profilers characterized the seafloor in and around the disposal sites, and the resulting products reveal the character and extent of the dredged material. These data were used to plan Phase 2 in 1994, a sampling program that employed subbottom profilers, video and still photography, and seafloor sampling to ground truth the sonar mosaic and identify the seafloor substrates responsible for the various acoustic signatures on the sonar images and subbottom profiles. Box coring provided the samples necessary to distinguish dredged material from native sediment, and for the chemical analyses used to determine contaminant concentrations. Phase 3 studies conducted in June of 1995 consisted of box core sampling for chemical and biological analyses. Specific studies include: infaunal taxonomy and population density, bioassay/bioaccumulation, sediment chemistry, and post-disposal resuspension and transport. The 1995 survey, conducted June 14 through 17, resulted in the collection of 39 box cores from 20 different stations. Multiple box cores were composited at 7 different locations occupied in 1994, to provide

Seismically-triggered soft-sediment deformation structures close to a major strike-slip fault system in the Eastern Alps (Hirlatz cave, Austria)

NASA Astrophysics Data System (ADS)

Salomon, Martina Lan; Grasemann, Bernhard; Plan, Lukas; Gier, Susanne; Schöpfer, Martin P. J.

2018-05-01

We investigate episodic soft-sediment deformation structures cross-cut by normal faults preserved in unlithified finely laminated calcite rich sediments in the Hirlatz cave in the Northern Calcareous Alps (Austria). These sediments comprise varve-like alternations of brighter carbonate/quartz rich layers, and darker clay mineral rich layers. The deformed sediments contain abundant millimeter to centimeter-scale soft-sediment structures (load casts, ball-and-pillow structures), sheet slumps (thrust faults and folds), erosive channels filled with slides and chaotic slumps. After deposition and soft-sediment deformation normal faults developed within the entire sedimentary succession, an event that probably correlates with an offset of c. 10 cm of the passage wall above the outcrop. Our major conclusions are: (i) The sediments have a glacial origin and were deposited in the Hirlatz cave under phreatic fluvio-lacustrine conditions. The deposition and the soft-sediment deformation occurred most likely during the last glaciation (i.e. around 25 ka ago); (ii) The liquefaction and formation of the soft-sediment structures in water-saturated stratified layers was triggered by episodic seismic events; (iii) The internally deformed sediments were later displaced by normal faults; (iv) A possible source for the seismic events is the active sinistral Salzach-Ennstal-Mariazeller-Puchberger (SEMP) strike-slip fault which is located about 10 km south of the outcrop and plays a major role in accommodating the extrusion of the Eastern Alps towards the Pannonian Basin. To our knowledge, the described structures are the first report of liquefaction and seismically induced soft-sediment deformations in Quaternary sediments in the Eastern Alps.

Sedimentation and provenance of the Antofagasta region of the southern Puna Plateau, central Andes

NASA Astrophysics Data System (ADS)

Zhou, Renjie; Schoenbohm, Lindsay M.; Sobel, Edward R.; Carrapa, Barbara; Davis, Donald W.

2014-05-01

Stratigraphic and provenance studies of Cenozoic non-marine sedimentary basins in the Central Andean Puna Plateau provide insight into the regional development and dynamics. The southern plateau hosts several poorly exposed intramontane basins bounded by basement-involved ~N-S striking thrust faults; their origin is explained differently by contrasting geodynamic models. This study focuses on the Antofagasta region (NW Argentina). The top of the studied basin was over-thrust by basement rocks along a west-dipping thrust fault, which was likely active during exhumation of the Calalaste range to the west (25-29 Ma, Carrapa et al., 2005). We studied three sections SW of Antofagasta de la Sierra. S3 (552 m) is the lowest section and is composed of mud playa to sandflat sediments, with at least two paleosol horizons. Lower S2 (1,263 m) contains ~300 meters of proximal alluvial fan sediments. Upper S2 is composed of fluvial to shallow lacustrine sediments. The separation between the top of S2 and the bottom of S1 (1,062 m) is ~540 m. The lower ~600 m of S1 is composed of thick, distal alluvial fan and braided river sediments. In the upper S1, the depositional environment changes to fluvial-alluvial, with a paleosol developed at the top of S1. Imbricated pebbles suggest prevailing eastward paleoflow. Modal compositions of 18 sandstones plot in the mixed zone on a Qm-F-Lt plot, and the transitional continental and recycled orogenic zones on a Qt-F-L plot (Dickinson, 1985). Their compositions cluster and do not show any evolutionary trends, despite being sampled from a ~3000 m-thick sedimentary column. However, when combined with data from the Quinoas Formation (Late Eocene to Late Oligocene) and the Chacras Formation (Late Oligocene to Early Miocene), outcropped west of the study site (Carrapa et al., 2005), the Antofagasta samples mark the beginning of an evolving trend towards the dissected arc and transitional arc zones. We analyzed U-Pb ages of detrital zircons from

Assessing contamination in Great Lakes sediments using benthic invertebrate communities and the sediment quality triad approach

USGS Publications Warehouse

Canfield, Timothy J.; Dwyer, F. James; Fairchild, James F.; Haverland, Pamela S.; Ingersoll, Christopher G.; Kemble, Nile E.; Mount, David R.; La Point, Thomas W.; Burton, G. Allen; Swift, M. C.

1996-01-01

Sediments in many Great Lakes harbors and tributary rivers are contaminated. As part of the USEPA's Assessment and Remediation of Contaminated Sediment (ARCS) program, a number of studies were conducted to determine the nature and extent of sediment contamination in Great Lakes Areas of Concern (AOC). This paper describes the composition of benthic invertebrate communities in contaminated sediments and is one in a series of papers describing studies conducted to evaluate sediment toxicity from three AOC's (Buffalo River, NY; Indiana Harbor, IN; Saginaw River, MI), as part of the ARCS Program. Oligochaeta (worms) and Chironomidae (midge) comprised over 90% of the benthic invertebrate numbers in samples collected from depositional areas. Worms and midge consisted of taxa identified as primarily contaminant tolerant organisms. Structural deformities of mouthparts in midge larvae were pronounced in many of the samples. Good concurrence was evident between measures of laboratory toxicity, sediment contaminant concentration, and benthic invertebrate community composition in extremely contaminated samples. However, in moderately contaminated samples, less concordance was observed between the benthos community composition and either laboratory toxicity test results or sediment contaminant concentration. Laboratory sediment toxicity tests may better identify chemical contamination in sediments than many commonly used measures of benthic invertebrate community composition. Benthic measures may also reflect other factors such as habitat alteration. Evaluation of non-contaminant factors are needed to better interpret the response of benthic invertebrates to sediment contamination.

Stratigraphic architecture of a fluvial-lacustrine basin-fill succession at Desolation Canyon, Uinta Basin, Utah: Reference to Walthers’ Law and implications for the petroleum industry

USGS Publications Warehouse

Ford, Grace L.; David R. Pyles,; Dechesne, Marieke

2016-01-01

Two large-scale (member-scale) upward patterns are noted: Waltherian, and non-Waltherian. The upward successions in Waltherian progressions record progradation or retrogradation of a linked fluvial-lacustrine system across the area; whereas the upward successions in non-Waltherian progressions record large-scale changes in the depositional system that are not related to progradation or retrogradation of the ancient lacustrine shoreline. Four Waltherian progressions are noted: 1) the Flagstaff Limestone to lower Wasatch Formation member records the upward transition from lacustrine to fluvial—or shallowing-upward succession; 2) the upper Wasatch to Uteland Butte records the upward transition from fluvial to lacustrine—or a deepening upward succession; 3) the Uteland Butte to Renegade Tongue records the upward transition from lacustrine to fluvial—a shallowing-upward succession; and 4) the Renegade Tongue to Mahogany oil shale interval records the upward transition from fluvial to lacustrine—a deepening upward succession. The two non-Waltherian progressions in the study area are: 1) the lower to middle Wasatch, which records the abrupt shift from low to high net-sand content fluvial system, and 2) the middle to upper Wasatch, which records the abrupt shift from high to intermediate net-sand content fluvial system.

Sediment source fingerprinting to quantify fine sediment sources in forested catchments, Chile.

NASA Astrophysics Data System (ADS)

Schuller, P.; Walling, D. E.; Iroume, A.; Castillo, A.; Quilodran, C.

2012-04-01

A study to improve the understanding of the primary sediment sources and transfer pathways in catchments disturbed following forest plantation harvesting is being undertaken in South-Central Chile. The study focuses on two sets of paired experimental catchments (treatment and control), located about 400 km apart, with similar soil type but contrasting mean annual rainfall: Nacimiento (1,200 mm year-1) and Los Ulmos (2,500 mm year-1). Sediment source fingerprinting techniques are being used to document the primary fine sediment sources. In each catchment, three potential sediment sources were defined: clearcut slopes (Z1), forest roads (Z2) and the stream channel (Z3). In each catchment, multiple representative composite samples of the different potential source materials were collected before harvest operations from the upper 1 cm layer in Z1, Z2, and from the channel bank and bed for Z3. A time-integrating trap sampler installed in the discharge monitoring station constructed at the outlet of each catchment has been used to collect samples of the suspended sediment and these have been supplemented by sediment collected from the weir pools. Total suspended sediment load is been quantified in the monitoring stations using discharge records and integrated water sampling. Caesium-137 (137Cs), excess lead-210 (210Pbex) and other sediment properties are being used as fingerprints. After air-drying, oven-drying at 40°C and disaggregation, both the source material samples and the sediment samples collected in the discharge monitoring stations were sieved through a 63-μm sieve and the <63-μm fractions were used for subsequent analyses. For radionuclide assay, the samples were sealed in Petri dishes and after 4 weeks the mass activity density (activity concentration) of 137Cs and 210Pbex was determined by gamma analysis, using an ORTEC extended range Ge detector of 53% relative efficiency. The 137Cs and 210Pbex activity and organic carbon (Corg) concentration associated

Extracting paleo-climate signals from sediment laminae: A new, automated image processing method

NASA Astrophysics Data System (ADS)

Gan, S. Q.; Scholz, C. A.

2010-12-01

Lake sediment laminations commonly represent depositional seasonality in lacustrine environments. Their occurrence and quantitative attributes contain various signals of their depositional environment, limnological conditions and climate. However, the identification and measurement of laminae remains a mainly manual process that is not only tedious and labor intensive, but also subjective and error prone. We present a batch method to identify laminae and extract lamina properties automatically and accurately from sediment core images. Our algorithm is focused on image enhancement that improves the signal-to-noise ratio and maximizes and normalizes image contrast. The unique feature of these algorithms is that they are all direction-sensitive, i.e., the algorithms treat images in the horizontal direction and vertical direction differently and independently. The core process of lamina identification is to use a one-dimensional (1-D) lamina identification algorithm to produce a lamina map, and to use image blob analyses and lamina connectivity analyses to aggregate and smash two-dimensional (2-D) lamina data for the best representation of fine-scale stratigraphy in the sediment profile. The primary output datasets of the system are definitions of laminae and primary color values for each pixel and each lamina in the depth direction; other derived datasets can be retrieved at users’ discretion. Sediment core images from Lake Hitchcock , USA and Lake Bosumtwi, Ghana, were used for algorithm development and testing. As a demonstration of the utility of the software, we processed sediment core images from the top of 50 meters of drill core (representing the past ~100 ky) from Lake Bosumtwi, Ghana.

Analytical results and sample locations of reanalyzed NURE stream-sediment and soil samples for the Humboldt River basin mineral-environmental assessment, northern Nevada

USGS Publications Warehouse

Folger, H. W.

2000-01-01

The U.S. Geological Survey (USGS), in cooperation with the Bureau of Land Management (BLM), began a study in 1996 to describe to the geochemistry of the Humboldt River Basin. The principal sample media evaluated are stream-sediment and soil samples retrieved from the National Uranium Resource Evaluation (NURE) archives located in Denver, Colorado. Samples were retrieved from the Wells, McDermitt, Vya, Lovelock, Winnemucca, Elko, Ely, Millett, Reno, and Tonopah 1? x 2? quadrangles in northern Nevada. The data are appropriate for large-scale reconnaissance resource evaluations and landscape geochemical-geoenvironmental evaluations. The analytical results are presented in this report.

Ostracods and sediment geochemistry as indicators of hydrologic and climatic variability in the central part of the Mexican Chihuahuan Desert over the last 27 ka cal BP

NASA Astrophysics Data System (ADS)

Chávez Lara, C. M.; Roy, P. D.; Lozano Santa Cruz, R.; López Balbiaux, N.

2013-12-01

The paleolake Santiaguillo (Durango State) is located in the central part of the Chihuahuan Desert (Mexico). The lacustrine basin covers an area of approximately 1,964 km2 and is surrounded by mountains up to ca. 2,700 masl. This basin was formed by tectonic processes and the basement is formed by volcanic felsic rocks of Tertiary age. Four sediment cores were obtained from central and western part of the basin to reconstruct hydrologic and climate variability during the late Pleistocene and Holocene. In this work, we present paleo-ecology of ostracods and sedimentary geochemistry from two sediment cores (300 cm and 200 cm long) collected from the western basin margin. The age model was constructed from 8 AMS radiocarbon dates and the longest profile represents the last 27 cal ka BP. The ostracode faunal content consists of 4 different species: Limnocythere bradburyi, Cadona patzcuaro, Cypridopsis vidua and Limnocythere ceriotuberosa (listed from highest to lowest abundance) and total abundance varies between 0 and 125 valves/g. Paleo-environmental conditions were reconstructed from the Total Organic Carbon (TOC), Total Inorganic Carbon (TIC), Carbon/Nitrogen ratios (C/N), Chemical Index of Alteration (CIA) and concentrations of Ti, Ca, Si and Al. The results were divided into two zones for interpretation. Zone 1 covers ca. 27-17 cal ka BP (300-191 cm) and is characterized by higher Ti concentrations and above average CIA values. This suggests greater interaction between water and sediment, lower evaporation and relatively higher lake level in the basin. During this interval of higher lakestand, the deposited organic matter was autochthonous (lacustrine origin) and ostracodes suggest presence of a warm and dilute water column (>13 °C and >100 ppm). Sediments of the last 17 cal ka BP (191-0 cm) (Zone 2) are characterized by below average water-sediment interaction, higher carbonate precipitation and deposition of allochthonous organic matter (terrestrial origin

Liver histological changes and lipid peroxidation in the amphibian Ambystoma mexicanum induced by sediment elutriates from the Lake Xochimilco.

PubMed

Ortiz-Ordoñez, Esperanza; López-López, Eugenia; Sedeño-Díaz, Jacinto Elías; Uría, Esther; Morales, Ignacio Andrés; Pérez, María Estela; Shibayama, Mineko

2016-08-01

Lacustrine sediments accumulate pollutants that input from the lake watershed and can be released to the water column by sediment resuspension; thus, pollutants can change their bioavailability and exert adverse effects to aquatic biota. Shallow-urban lakes are particularly susceptible to receive pollutants from urban discharges and sediment resuspension. Lake Xochimilco, in Mexico City, an urban-shallow lake, faces multiple problems: urban sprawl, overexploitation of aquifers, drying of springs, discharge of wastewater from treatment plants, and sediment resuspension. The aquatic biota living in this ecosystem is continuously exposed to the release of pollutants from the sediments. We assessed the risk that pollutants released from sediments from Lake Xochimilco, Touristic (TZ) and Agriculture zone (AZ), can exert on a native amphibian species of the lake (Ambystoma mexicanum) through exposure bioassays to sediment elutriates. We evaluate alterations in the amphibian by three approaches: biochemical (level of lipid peroxidation, LPO), cellular (ultrastructure) and the liver histology of A. mexicanum and we compare them with a batch control. Additionally, we assessed heavy metals (Pb, Cd and Hg) in elutriates. Elutriates from TZ showed the highest concentrations of the metals assessed. Organisms exposed to sediment elutriates from either study sites showed higher LPO values than control organisms (p<0.05). Organisms exposed to elutriates from the TZ showed the most conspicuous damages: hepatic vasodilation of sinusoids, capillaries with erythrocytes, leukocyte infiltration and cytoplasmic vacuolation in hepatocytes. The biological responses assessed reflected the risk that faces A. mexicanum when is exposed for prolonged periods to sediment resuspension in Lake Xochimilco. Copyright © 2016. Published by Elsevier B.V.

Concentrations of antifouling biocides in sediment and mussel samples collected from Otsuchi bay, Japan.

PubMed

Harino, Hiroya; Yamamoto, Yoshikazu; Eguchi, Sayaka; Kawai, Shini'chiro; Kurokawa, Yuko; Arai, Takaomi; Ohji, Madoka; Okamura, Hideo; Miyazaki, Nobuyuki

2007-02-01

Organotin compounds (OTs) and representative booster biocides were measured in sediment and mussels from Otsuchi Bay, Japan. The mean amounts of tributyltin (TBT) and triphenyltin (TPT) compounds in sediment were 13 microg kg(-1) dry and 3 microg kg(-1) dry, respectively. Representative booster biocides (Sea-Nine 211, Diuron, Dichlofluanid, Irgarol 1501, M1, which is a degradation compound of Irgarol 1051, and Copper pyrithione) were also detected in sediment from Otsuchi Bay. OT concentrations were higher than those of the measured booster biocides. Otsuchi Bay was divided into four parts by cluster analysis based on OT concentrations in sediment sampled from the bay. These areas included the vicinity of a shipyard, a small fishing port, the closed inner area of the bay, and the mouth of the bay. Higher concentrations of TBT and TPT and a higher ratio of TBT to total BTs were observed in the vicinity of the shipyard. A higher concentration of TPT in comparison with TBT was detected in a small fishing port. Furthermore, OT concentrations in the mouth of the bay were higher than those in the closed-off section. OT concentrations in mussels decreased with distance from the shipyard. Otsuchi Bay was then divided into three parts by cluster analysis based on the concentrations of representative booster biocides found in the bay's sediment. These areas included the vicinity of a shipyard, a small fishing port, and other sites. Concentrations of Diuron and Irgarol 1051 in the vicinity of a shipyard and a small fishing port were dramatically high in comparison with the other sites. Copper pyrithione and Dichlofluanid in addition to Diuron and Irgarol 1051 were also detected in the area of a small fishing port. The concentrations of antifouling biocides were highest in the water in front of the shipyard and showed a marked decrease with distance from the shipyard.

Diagenetic changes of lignin compounds in a more than 0.6 million-year-old lacustrine sediment (Lake Biwa, Japan)

NASA Astrophysics Data System (ADS)

Ishiwatari, Ryoshi; Uzaki, Minoru

1987-02-01

A vertical profile of lignin in the upper 700 m layer of a 1400 m sediment core of Lake Biwa, an oligotrophic freshwater lake in Japan, was determined using a CuO oxidative degradation method. The results indicated that lignin is found throughout the core, demonstrating lignin to be very stable for over 0.6 million years. Moreover, the upper 250 m (approximately 0.6 million years old) segment of the sediment core was investigated to determine the apparent long term degradation rate of lignin. A downward lignin concentration decrease is observed over the upper 250 m of the core which corresponds to a calculated half life of at least approximately 40 × 10 4 years, assuming that lignin decrease is due to its in situ degradation (diagenesis).

Iron and nutrient content of wind-erodible sediment in the ephemeral river valleys of Namibia

NASA Astrophysics Data System (ADS)

Dansie, A. P.; Wiggs, G. F. S.; Thomas, D. S. G.

2017-08-01

Research concerning the global distribution of aeolian dust sources has principally focussed on salt/clay pan and desiccated lacustrine emission areas. In southern Africa such sources are identified as Etosha Pan in northern Namibia and Makgadikgadi Pans in northern Botswana. Dust emitting from ephemeral river valleys, however, has been largely overlooked. Rivers are known nutrient transport pathways and the flooding regimes of ephemeral river valleys frequently replenish stores of fine sediment which, on drying, can become susceptible to aeolian erosion. Such airborne sediment may be nutrient rich and thus be significant for the fertilisation of marine waters once deposited. This study investigates the dust source sediments from three ephemeral river valleys in Namibia in terms of their particle size distribution and their concentrations of bioavailable N, P and Fe. We compare the nutrient content of these sediments from the ephemeral river valleys to those collected from Etosha and Makgadikgadi Pans and consider their relative ocean fertilising potential. Our results show that the ephemeral river valleys contain fine grained sediment similar in physical character to Etosha and Makgadikgadi Pans yet they have up to 43 times greater concentrations of bioavailable iron and enriched N and P macronutrients that are each important for ocean fertilisation. The known dust-emitting river valleys of Namibia may therefore be contributing a greater fertilisation role in the adjacent marine system than previously considered, and not-yet investigated. Given this finding a re-assessment of the potential role of ephemeral river valleys in providing nutrient-rich sediment into the aeolian and marine systems in other dryland areas is necessary.

The middle Holocene climatic records from Arabia: Reassessing lacustrine environments, shift of ITCZ in Arabian Sea, and impacts of the southwest Indian and African monsoons

NASA Astrophysics Data System (ADS)

Enzel, Yehouda; Kushnir, Yochanan; Quade, Jay

2015-06-01

A dramatic increase in regional summer rainfall amount has been proposed for the Arabian Peninsula during the middle Holocene (ca. 9-5 ka BP) based on lacustrine sediments, inferred lake levels, speleothems, and pollen. This rainfall increase is considered primarily the result of an intensified Indian summer monsoon as part of the insolation-driven, northward shift of the boreal summer position of the Inter-Tropical Convergence Zone (ITCZ) to over the deserts of North Africa, Arabia, and northwest India. We examine the basis for the proposed drastic climate change in Arabia and the shifts in the summer monsoon rains, by reviewing paleohydrologic lacustrine records from Arabia. We evaluate and reinterpret individual lake-basin status regarding their lacustrine-like deposits, physiography, shorelines, fauna and flora, and conclude that these basins were not occupied by lakes, but by shallow marsh environments. Rainfall increase required to support such restricted wetlands is much smaller than needed to form and maintain highly evaporating lakes and we suggest that rainfall changes occurred primarily at the elevated edges of southwestern, southern, and southeastern Arabian Peninsula. These relatively small changes in rainfall amounts and local are also supported by pollen and speleothems from the region. The changes do not require a northward shift of the Northern Hemisphere summer ITCZ and intensification of the Indian monsoon rainfall. We propose that (a) latitudinal and slight inland expansion of the North African summer monsoon rains across the Red Sea, and (b) uplifted moist air of this monsoon to southwestern Arabia highlands, rather than rains associated with intensification of Indian summer monsoon, as proposed before, increased rains in that region; these African monsoon rains produced the modest paleo-wetlands in downstream hyperarid basins. Furthermore, we postulate that as in present-day, the ITCZ in the Indian Ocean remained at or near the equator all

Results of soil, ground-water, surface-water, and streambed-sediment sampling at Air Force Plane 85, Columbus, Ohio, 1996

USGS Publications Warehouse

Parnell, J.M.

1997-01-01

The U.S. Geological Survey (USGS), in cooperation with Aeronautical Systems Center, Environmental Management Directorate, Restoration Division, prepared the Surface- and Ground- Water Monitoring Work Plan for Air Force Plant 85 (AFP 85 or Plant), Columbus, Ohio, under the Air Force Installation Restoration Program to characterize any ground-water, surface-water, and soil contamination that may exist at AFP 85. The USGS began the study in November 1996. The Plant was divided into nine sampling areas, which included some previously investi gated study sites. The investigation activities included the collection and presentation of data taken during drilling and water-quality sampling. Data collection focused on the saturated and unsatur ated zones and surface water. Twenty-three soil borings were completed. Ten monitoring wells (six existing wells and four newly constructed monitoring wells) were selected for water-quality sam pling. Surface-water and streambed-sediment sampling locations were chosen to monitor flow onto and off of the Plant. Seven sites were sampled for both surface-water and streambed-sediment quality. This report presents data on the selected inorganic and organic constituents in soil, ground water, surface water, and streambed sediments at AFP 85. The methods of data collection and anal ysis also are included. Knowledge of the geologic and hydrologic setting could aid Aeronautical Systems Center, Environmental Management Directorate, Restoration Division, and its governing regulatory agencies in future remediation studies.

Mixed biogenic and hydrothermal quartz in Permian lacustrine shale of Santanghu Basin, NW China: implications for penecontemporaneous transformation of silica minerals

NASA Astrophysics Data System (ADS)

Jiao, Xin; Liu, Yiqun; Yang, Wan; Zhou, Dingwu; Wang, Shuangshuang; Jin, Mengqi; Sun, Bin; Fan, Tingting

2018-01-01

The cycling of various isomorphs of authigenic silica minerals is a complex and long-term process. A special type of composite quartz (Qc) grains in tuffaceous shale of Permian Lucaogou Formation in the sediment-starved volcanically and hydrothermally active intracontinental lacustrine Santanghu rift basin (NW China) is studied in detail to demonstrate such processes. Samples from one well in the central basin were subject to petrographic, elemental chemical, and fluid inclusion analyses. About 200 Qc-bearing laminae are 0.1-2 mm and mainly 1 mm thick and intercalated within tuffaceous shale laminae. The Qc grains occur as framework grains and are dispersed in igneous feldspar-dominated matrix, suggesting episodic accumulation. The Qc grains are bedding-parallel, uniform in size (100 s µm), elongate, and radial in crystal pattern, suggesting a biogenic origin. Qc grains are composed of a core of anhedral microcrystalline quartz and an outer part of subhedral mega-quartz grains, whose edges are composed of small euhedral quartz crystals, indicating multiple episodic processes of recrystallization and overgrowth. Abundance of Al and Ti in quartz crystals and estimated temperature from fluid inclusions in Qc grains indicate that processes are related to hydrothermal fluids. Finally, the Qc grains are interpreted as original silica precipitation in microorganism (algae?) cysts, which were reworked by bottom currents and altered by hydrothermal fluids to recrystalize and overgrow during penecontemporaneous shallow burial. It is postulated that episodic volcanic and hydrothermal activities had changed lake water chemistry, temperature, and nutrient supply, resulting in variations in microorganic productivities and silica cycling. The transformation of authigenic silica from amorphous to well crystallized had occurred in a short time span during shallow burial.

Optimizing sample pretreatment for compound-specific stable carbon isotopic analysis of amino sugars in marine sediment

NASA Astrophysics Data System (ADS)

Zhu, R.; Lin, Y.-S.; Lipp, J. S.; Meador, T. B.; Hinrichs, K.-U.

2014-09-01

Amino sugars are quantitatively significant constituents of soil and marine sediment, but their sources and turnover in environmental samples remain poorly understood. The stable carbon isotopic composition of amino sugars can provide information on the lifestyles of their source organisms and can be monitored during incubations with labeled substrates to estimate the turnover rates of microbial populations. However, until now, such investigation has been carried out only with soil samples, partly because of the much lower abundance of amino sugars in marine environments. We therefore optimized a procedure for compound-specific isotopic analysis of amino sugars in marine sediment, employing gas chromatography-isotope ratio mass spectrometry. The whole procedure consisted of hydrolysis, neutralization, enrichment, and derivatization of amino sugars. Except for the derivatization step, the protocol introduced negligible isotopic fractionation, and the minimum requirement of amino sugar for isotopic analysis was 20 ng, i.e., equivalent to ~8 ng of amino sugar carbon. Compound-specific stable carbon isotopic analysis of amino sugars obtained from marine sediment extracts indicated that glucosamine and galactosamine were mainly derived from organic detritus, whereas muramic acid showed isotopic imprints from indigenous bacterial activities. The δ13C analysis of amino sugars provides a valuable addition to the biomarker-based characterization of microbial metabolism in the deep marine biosphere, which so far has been lipid oriented and biased towards the detection of archaeal signals.

Minero-chemical composition as environmental quality assessment tool of an artificial water reservoir: the case of the "Pietra del Pertusillo" lake (Basilicata, Italia)

NASA Astrophysics Data System (ADS)

fortunato, elisabetta; mongelli, giovanni; paternoster, michele; sinisi, rosa

2016-04-01

The Pietra del Pertusillo fresh-water reservoir is an artificial lake located in the High Agri River Valley (Basilicata); its dam was completed in 1963 for producing hydroelectric energy and providing water for human use to Puglia and Basilicata southern Italian regions (approximately 2 million people). Pertusillo lake lies within a national park because of the presence of many special protected areas. This reservoir is a natural laboratory for assessing the sediment pollution from human activities, including: waste-water treatment plants, landfills, farms, treatment oil plant, plastics and other industrial activities. In addition, the Pertusillo reservoir is located in the area of the largest oil field of continental Europe. This anthropogenic pressure may thus represent an impact factor on the environmental equilibrium and consequently the knowledge and control on their quality represents a relevant environmental challenge. This study reports the preliminary results of a multidisciplinary (sedimentological, mineralogical, geochemical) PhD research focused on the analysis of the lacustrine sediments filling the Pietra del Pertusillo fresh-water reservoir. The lakes and its sediments represent the natural sink for nutrients and possible pollutants which tend to accumulate in relation to the nature and composition of the solid matrix but also the concentration and characteristics of the substances themselves. Moreover the deeper sediments, deposited under undisturbed condition, represent the "historical memory" of the ecosystem. Sub-aqueous lake sediments were investigated in May 2014, sampled using a small platform and a gravity corer (UWITEC, Austria) of 90 mm diameter which allowed to drill 19 cores up to 2 m long from the sediment/water interface. Successively cores were studied and described by using facies analysis techniques; a large number of core samples (147) were collected from the working half of each core, stored in HPDE containers, and frozen at -20�

Denaturing gradient gel electrophoresis and barcoded pyrosequencing reveal unprecedented archaeal diversity in mangrove sediment and rhizosphere samples.

PubMed

Pires, Ana C C; Cleary, Daniel F R; Almeida, Adelaide; Cunha, Angela; Dealtry, Simone; Mendonça-Hagler, Leda C S; Smalla, Kornelia; Gomes, Newton C M

2012-08-01

Mangroves are complex ecosystems that regulate nutrient and sediment fluxes to the open sea. The importance of bacteria and fungi in regulating nutrient cycles has led to an interest in their diversity and composition in mangroves. However, very few studies have assessed Archaea in mangroves, and virtually nothing is known about whether mangrove rhizospheres affect archaeal diversity and composition. Here, we studied the diversity and composition of Archaea in mangrove bulk sediment and the rhizospheres of two mangrove trees, Rhizophora mangle and Laguncularia racemosa, using denaturing gradient gel electrophoresis (DGGE) and pyrosequencing of archaeal 16S rRNA genes with a nested-amplification approach. DGGE profiles revealed significant structural differences between bulk sediment and rhizosphere samples, suggesting that roots of both mangrove species influence the sediment archaeal community. Nearly all of the detected sequences obtained with pyrosequencing were identified as Archaea, but most were unclassified at the level of phylum or below. Archaeal richness was, furthermore, the highest in the L. racemosa rhizosphere, intermediate in bulk sediment, and the lowest in the R. mangle rhizosphere. This study shows that rhizosphere microhabitats of R. mangle and L. racemosa, common plants in subtropical mangroves located in Rio de Janeiro, Brazil, hosted distinct archaeal assemblages.

Denaturing Gradient Gel Electrophoresis and Barcoded Pyrosequencing Reveal Unprecedented Archaeal Diversity in Mangrove Sediment and Rhizosphere Samples

PubMed Central

Pires, Ana C. C.; Cleary, Daniel F. R.; Almeida, Adelaide; Cunha, Ângela; Dealtry, Simone; Mendonça-Hagler, Leda C. S.; Smalla, Kornelia

2012-01-01

Mangroves are complex ecosystems that regulate nutrient and sediment fluxes to the open sea. The importance of bacteria and fungi in regulating nutrient cycles has led to an interest in their diversity and composition in mangroves. However, very few studies have assessed Archaea in mangroves, and virtually nothing is known about whether mangrove rhizospheres affect archaeal diversity and composition. Here, we studied the diversity and composition of Archaea in mangrove bulk sediment and the rhizospheres of two mangrove trees, Rhizophora mangle and Laguncularia racemosa, using denaturing gradient gel electrophoresis (DGGE) and pyrosequencing of archaeal 16S rRNA genes with a nested-amplification approach. DGGE profiles revealed significant structural differences between bulk sediment and rhizosphere samples, suggesting that roots of both mangrove species influence the sediment archaeal community. Nearly all of the detected sequences obtained with pyrosequencing were identified as Archaea, but most were unclassified at the level of phylum or below. Archaeal richness was, furthermore, the highest in the L. racemosa rhizosphere, intermediate in bulk sediment, and the lowest in the R. mangle rhizosphere. This study shows that rhizosphere microhabitats of R. mangle and L. racemosa, common plants in subtropical mangroves located in Rio de Janeiro, Brazil, hosted distinct archaeal assemblages. PMID:22660713

Improved marine reservoir age estimation and palaeoclimate synchronisation of the early Holocene Levantine/NW-Arabian region based on identification of the S1 tephra in Dead Sea and Tayma palaeolake sediments

NASA Astrophysics Data System (ADS)

Neugebauer, Ina; Wulf, Sabine; Schwab, Markus J.; Serb, Johanna; Plessen, Birgit; Appelt, Oona; Brauer, Achim

2017-04-01

Due to a lack of tephras identified in marine and terrestrial palaeoclimate records from the Levantine-Arabian area, this region is still not sufficiently connected to the eastern Mediterranean tephrostratigraphical lattice. Here we report on the first finding of cryptotephra in the Holocene lacustrine sediment records of the Dead Sea and the Tayma palaeolake (NW Arabian Peninsula). The major elemental chemistry of the rhyolitic glass shards proves this tephra identical to the distal 'S1 tephra' identified in the Yammoûneh palaeolake, Lebanon (Develle et al, 2009), in a marine sediment record from the SE Levantine basin (Hamann et al., 2010) and in the Sodmein Cave archaeological site in Egypt (Barton et al., 2015). The 'S1 tephra', most likely corresponding to the early Holocene 'Dikkartın' dome eruption of the Erciyes Daǧ volcano in central Anatolia, Turkey, has been dated in the marine record at 8830 ± 140 cal yr BP. We present new age estimates of the 'S1 tephra' based on radiocarbon dating of terrestrial plant remains (Migowski et al., 2004) and pollen concentrates (Dinies et al., 2015), which reveal modelled ages of 8939 ± 83 cal yr BP in the Dead Sea sediments and 9041 ± 254 cal yr BP in Tayma. This allows the estimation of an early Holocene marine reservoir age of ca. 320 years in the SE Levantine Sea. The timing of the volcanic eruption during the early Holocene humid period, which led to the formation of sapropel S1 in the Mediterranean Sea, and the identification of the 'S1 tephra' more than 1200 km to the south are crucial for the synchronisation of marine and terrestrial palaeoclimate records in the eastern Mediterranean region. References: Barton et al., 2015. The role of cryptotephra in refining the chronology of Late Pleistocene human evolution and cultural change in North Africa. Quaternary Sci. Rev. 118, 151-169. Develle et al., 2009. Early Holocene volcanic ash fallout in the Yammoûneh lacustrine basin (Lebanon): Tephrochronological

Quality-assurance plan for the analysis of fluvial sediment by the U.S. Geological Survey Kentucky Water Science Center Sediment Laboratory

USGS Publications Warehouse

Shreve, Elizabeth A.; Downs, Aimee C.

2005-01-01

This report describes laboratory procedures used by the U.S. Geological Survey Kentucky Water Science Center Sediment Laboratory for the processing and analysis of fluvial-sediment samples for concentration of sand and finer material. The report details the processing of a sediment sample through the laboratory from receiving the sediment sample, through the analytical process, to compiling results of the requested analysis. Procedures for preserving sample integrity, calibrating and maintaining of laboratory and field instruments and equipment, analyzing samples, internal quality assurance and quality control, and validity of the sediment-analysis results also are described. The report includes a list of references cited and a glossary of sediment and quality-assurance terms.

Chemical and physical properties affecting strontium distribution coefficients of surficial-sediment samples at the Idaho National Engineering and Environmental Laboratory, Idaho

USGS Publications Warehouse

Liszewski, M.J.; Rosentreter, J.J.; Miller, Karl E.; Bartholomay, R.C.

2000-01-01

The U.S. Geological Survey and Idaho State University, in cooperation with the U.S. Department of Energy, conducted a study to determine strontium distribution coefficients (K(d)s) of surficial sediments at the Idaho National Engineering and Environmental Laboratory (INEEL). Batch experiments using synthesized aqueous solutions were used to determine K(d)s, which describe the distribution of a solute between the solution and solid phase, of 20 surficial-sediment samples from the INEEL. The K(d)s for the 20 surficial-sediment samples ranged from 36 to 275 ml/g. Many properties of both the synthesized aqueous solutions and sediments used in the experiments also were determined. Solution properties determined were initial and equilibrium concentrations of calcium, magnesium, and strontium, pH and specific conductance, and initial concentrations of potassium and sodium. Sediment properties determined were grain-size distribution, bulk mineralogy, whole-rock major-oxide and strontium and barium concentrations, and Brunauer-Emmett-Teller (BET) surface area. Solution and sediment properties were correlated with strontium K(d)s of the 20 surficial sediments using Pearson correlation coefficients. Solution properties with the strongest correlations with strontium K(d)s were equilibrium pH and equilibrium calcium concentration correlation coefficients, 0.6598 and -0.6518, respectively. Sediment properties with the strongest correlations with strontium K(d)s were manganese oxide (MnO), BET surface area, and the >4.75-mm-grain-size fraction correlation coefficients, 0.7054, 0.7022, and -0.6660, respectively. Effects of solution properties on strontium K(d)s were interpreted as being due to competition among similarly charged and sized cations in solution for strontium-sorption sites; effects of sediment properties on strontium K(d)s were interpreted as being surface-area related. Multivariate analyses of these solution and sediment properties resulted in r2 values of 0

Data precision of X-ray fluorescence (XRF) scanning of discrete samples with the ITRAX XRF core-scanner exemplified on loess-paleosol samples

NASA Astrophysics Data System (ADS)

Profe, Jörn; Ohlendorf, Christian

2017-04-01

XRF-scanning is the state-of-the-art technique for geochemical analyses in marine and lacustrine sedimentology for more than a decade. However, little attention has been paid to data precision and technical limitations so far. Using homogenized, dried and powdered samples (certified geochemical reference standards and samples from a lithologically-contrasting loess-paleosol sequence) minimizes many adverse effects that influence the XRF-signal when analyzing wet sediment cores. This allows the investigation of data precision under ideal conditions and documents a new application of the XRF core-scanner technology at the same time. Reliable interpretations of XRF results require data precision evaluation of single elements as a function of X-ray tube, measurement time, sample compaction and quality of peak fitting. Ten-fold measurement of each sample constitutes data precision. Data precision of XRF measurements theoretically obeys Poisson statistics. Fe and Ca exhibit largest deviations from Poisson statistics. The same elements show the least mean relative standard deviations in the range from 0.5% to 1%. This represents the technical limit of data precision achievable by the installed detector. Measurement times ≥ 30 s reveal mean relative standard deviations below 4% for most elements. The quality of peak fitting is only relevant for elements with overlapping fluorescence lines such as Ba, Ti and Mn or for elements with low concentrations such as Y, for example. Differences in sample compaction are marginal and do not change mean relative standard deviation considerably. Data precision is in the range reported for geochemical reference standards measured by conventional techniques. Therefore, XRF scanning of discrete samples provide a cost- and time-efficient alternative to conventional multi-element analyses. As best trade-off between economical operation and data quality, we recommend a measurement time of 30 s resulting in a total scan time of 30 minutes

Laboratory theory and methods for sediment analysis

USGS Publications Warehouse

Guy, Harold P.

1969-01-01

The diverse character of fluvial sediments makes the choice of laboratory analysis somewhat arbitrary and the pressing of sediment samples difficult. This report presents some theories and methods used by the Water Resources Division for analysis of fluvial sediments to determine the concentration of suspended-sediment samples and the particle-size distribution of both suspended-sediment and bed-material samples. Other analyses related to these determinations may include particle shape, mineral content, and specific gravity, the organic matter and dissolved solids of samples, and the specific weight of soils. The merits and techniques of both the evaporation and filtration methods for concentration analysis are discussed. Methods used for particle-size analysis of suspended-sediment samples may include the sieve pipet, the VA tube-pipet, or the BW tube-VA tube depending on the equipment available, the concentration and approximate size of sediment in the sample, and the settling medium used. The choice of method for most bed-material samples is usually limited to procedures suitable for sand or to some type of visual analysis for large sizes. Several tested forms are presented to help insure a well-ordered system in the laboratory to handle the samples, to help determine the kind of analysis required for each, to conduct the required processes, and to assist in the required computations. Use of the manual should further 'standardize' methods of fluvial sediment analysis among the many laboratories and thereby help to achieve uniformity and precision of the data.

Unconventional maar diatreme and associated intrusions in the soft sediment-hosted Mardoux structure (Gergovie, France)

NASA Astrophysics Data System (ADS)

Valentine, Greg A.; van Wyk de Vries, Benjamin

2014-03-01

A Miocene age volcanic-hypabyssal structure comprising volcaniclastic deposits and mafic intrusions is exposed with vertical relief of ˜110 m on the side of Gergovie Plateau (Auvergne, France). Three main volcaniclastic facies are: (1) Fluidal tuff breccia composed of juvenile basalt and sediment clasts with dominantly fluidal shapes, with several combinations of basalt and sediment within individual clasts. (2) Thickly bedded lapilli tuff composed of varying proportions of fine-grained sediment derived from Oligocene-Miocene lacustrine marls and mudstones and basaltic lapilli, blocks, and bombs. (3) Planar-bedded tuff forming thin beds of fine to coarse ash-size sedimentary material and basalt clasts. Intrusive bodies in the thickly bedded lapilli tuff range from irregularly shaped and anastomosing dikes and sills of meters to tens of meters in length, to a main feeder dike that is up to ˜20 m wide, and that flares into a spoon-shaped sill at ˜100 m in diameter and 10-20 m thick in the eastern part of the structure. Volcaniclastic deposits and structural features suggest that ascending magma entrained soft, saturated sediment host material into the feeder dike and erupted fluidal magma and wet sediment via weak, Strombolian-like explosions. Host sediment and erupted material subsided to replace the extracted sediments, producing the growth subsidence structure that is similar to upper diatreme facies in typical maar diatremes but lacks evidence for explosive disruption of diatreme fill. Irregularly shaped small intrusions extended from the main feeder dike into the diatreme, and many were disaggregated due to shifting and subsidence of diatreme fill and recycled via eruption. The Mardoux structure is an "unconventional" maar diatreme in that it was produced mainly by weak explosive activity rather than by violent phreatomagmatic explosions and is an example of complex coupling between soft sediment and ascending magma.

Diagenetic silica enrichment and late-stage groundwater activity in Gale crater, Mars

USGS Publications Warehouse

Frydenvang, Jens; Gasda, Patrick J.; Hurowitz, Joel A.; Grotzinger, John P.; Wiens, Roger C.; Newsom, Horton E.; Edgett, Ken S.; Watkins, Jessica; Bridges, John C.; Maurice, Sylvestre; Fisk, Martin R.; Johnson, Jeffrey R.; Rapin, William; Stein, Nathan; Clegg, Sam M.; Schwenzer, S. P.; Bedford, C.; Edwards, P.; Mangold, Nicolas; Cousin, Agnes; Anderson, Ryan; Payre, Valerie; Vaniman, David; Blake, David; Lanza, Nina L.; Gupta, Sanjeev; Van Beek, Jason; Sautter, Violaine; Meslin, Pierre-Yves; Rice, Melissa; Milliken, Ralf; Gellert, Ralf; Thompson, Lucy; Clark, Ben C.; Sumner, Dawn Y.; Fraeman, Abigail A.; Kinch, Kjartan M; Madsen, Morten B.; Mitofranov, Igor; Jun, Insoo; Calef, Fred J.; Vasavada, Ashwin R.

2017-01-01

Diagenetic silica enrichment in fracture-associated halos that crosscut lacustrine and unconformably overlying aeolian sedimentary bedrock is observed on the lower north slope of Aeolis Mons in Gale crater, Mars. The diagenetic silica enrichment is colocated with detrital silica enrichment observed in the lacustrine bedrock yet extends into a considerably younger, unconformably draping aeolian sandstone, implying that diagenetic silica enrichment postdates the detrital silica enrichment. A causal connection between the detrital and diagenetic silica enrichment implies that water was present in the subsurface of Gale crater long after deposition of the lacustrine sediments and that it mobilized detrital amorphous silica and precipitated it along fractures in the overlying bedrock. Although absolute timing is uncertain, the observed diagenesis likely represents some of the most recent groundwater activity in Gale crater and suggests that the timescale of potential habitability extended considerably beyond the time that the lacustrine sediments of Aeolis Mons were deposited.

Sedimentology and palaeontology of the Upper Jurassic Puesto Almada Member (Cañadón Asfalto Formation, Fossati sub-basin), Patagonia Argentina: Palaeoenvironmental and climatic significance

NASA Astrophysics Data System (ADS)

Cabaleri, Nora G.; Benavente, Cecilia A.; Monferran, Mateo D.; Narváez, Paula L.; Volkheimer, Wolfgang; Gallego, Oscar F.; Do Campo, Margarita D.

2013-10-01

Six facies associations are described for the Puesto Almada Member at the Cerro Bandera locality (Fossati sub-basin). They correspond to lacustrine, palustrine, and pedogenic deposits (limestones); and subordinated alluvial fan, fluvial, aeolian, and pyroclastic deposits. The lacustrine-palustrine depositional setting consisted of carbonate alkaline shallow lakes surrounded by flooded areas in a low-lying topography. The facies associations constitute four shallowing upward successions defined by local exposure surfaces: 1) a Lacustrine-Palustrine-pedogenic facies association with a 'conchostracan'-ostracod association; 2) a Palustrine facies association representing a wetland subenvironment, and yielding 'conchostracans', body remains of insects, fish scales, ichnofossils, and palynomorphs (cheirolepidiacean species and ferns growing around water bodies, and other gymnosperms in more elevated areas); 3) an Alluvial fan facies association indicating the source of sediment supply; and 4) a Lacustrine facies association representing a second wetland episode, and yielding 'conchostracans', insect ichnofossils, and a palynoflora mainly consisting of planktonic green algae associated with hygrophile elements. The invertebrate fossil assemblage found contains the first record of fossil insect bodies (Insecta-Hemiptera and Coleoptera) for the Cañadón Asfalto Formation. The succession reflects a mainly climatic control over sedimentation. The sedimentary features of the Puesto Almada Member are in accordance with an arid climatic scenario across the Upper Jurassic, and they reflect a strong seasonality with periods of higher humidity represented by wetlands and lacustrine sediments.

Determination of selected quaternary ammonium compounds by liquid chromatography with mass spectrometry. Part II. Application to sediment and sludge samples in Austria.

PubMed

Martínez-Carballo, Elena; González-Barreiro, Carmen; Sitka, Andrea; Kreuzinger, Norbert; Scharf, Sigrid; Gans, Oliver

2007-03-01

Soxhlet extraction and high-performance liquid chromatography (HPLC) coupled to tandem mass spectrometry detection (MS/MS) was used for the determination of selected quaternary ammonium compounds (QACs) in solid samples. The method was applied for the determination of alkyl benzyl, dialkyl and trialkyl quaternary ammonium compounds in sediment and sludge samples in Austria. The overall method quantification limits range from 0.6 to 3 microg/kg for sediments and from 2 to 5 microg/kg for sewage sludges. Mean recoveries between 67% and 95% are achieved. In general sediments were especially contaminated by C12 chain benzalkonium chloride (BAC-C12) as well as by the long C-chain dialkyldimethylammonium chloride (DDAC-C18) with a maximum concentration of 3.6 mg/kg and 2.1mg/kg, respectively. Maxima of 27 mg/kg for DDAC-C10, 25 mg/kg for BAC-C12 and 23 mg/kg for BAC-C14 were determined for sludge samples. The sums of the 12 selected target compounds range from 22 mg/kg to 103 mg/kg in the sludge samples.

Selective trace enrichment of chlorotriazine pesticides from natural waters and sediment samples using terbuthylazine molecularly imprinted polymers

USGS Publications Warehouse

Ferrer, I.; Lanza, F.; Tolokan, A.; Horvath, V.; Sellergren, B.; Horvai, G.; Barcelo, D.

2000-01-01

Two molecularly imprinted polymers were synthesized using either dichloromethane or toluene as the porogen and terbuthylazine as the template and were used as solid-phase extraction cartridges for the enrichment of six chlorotriazines (deisopropylatrazine, deethylatrazine, simazine, atrazine, propazine, and terbuthylazine) in natural water and sediment samples. The extracted samples were analyzed by liquid chromatography/diode array detection (LC/DAD). Several washing solvents, as well as different volumes, were tested for their ability to remove the matrix components nonspecifically adsorbed on the sorbents. This cleanup step was shown to be of prime importance to the successful extraction of the pesticides from the aqueous samples. The optimal analytical conditions were obtained when the MIP imprinted using dichloromethane was the sorbent, 2 mL of dichloromethane was used in the washing step, and the preconcentrated analytes were eluted with 8 mL of methanol. The recoveries were higher than 80% for all the chlorotriazines except for propazine (53%) when 50- or 100-mL groundwater samples, spiked at 1 ??g/L level, were analyzed. The limits of detection varied from 0.05 to 0.2 ??g/L when preconcentrating a 100-mL groundwater sample. Natural sediment samples from the Ebre Delta area (Tarragona, Spain) containing atrazine and deethylatrazine were Soxhlet extracted and analyzed by the methodology developed in this work. No significant interferences from the sample matrix were noticed, thus indicating good selectivity of the MIP sorbents used.

Polychlorinated Biphenyls in suspended-sediment samples from outfalls to Meandering Road Creek at Air Force Plant 4, Fort Worth, Texas, 2003-08

USGS Publications Warehouse

Braun, Christopher L.; Wilson, Jennifer T.

2010-01-01

Meandering Road Creek is an intermittent stream and tributary to Lake Worth, a reservoir on the West Fork Trinity River on the western edge of Fort Worth, Texas. U.S. Air Force Plant 4 (AFP4) is on the eastern shore of Woods Inlet, an arm of Lake Worth. Meandering Road Creek gains inflow from several stormwater outfalls as it flows across AFP4. Several studies have characterized polychlorinated biphenyls (PCBs) in the water and sediments of Lake Worth and Meandering Road Creek; sources of PCBs are believed to originate primarily from AFP4. Two previous U.S. Geological Survey (USGS) reports documented elevated PCB concentrations in surficial sediment samples from Woods Inlet relative to concentrations in surficial sediment samples from other parts of Lake Worth. The second of these two previous reports also identified some of the sources of PCBs to Lake Worth. These reports were followed by a third USGS report that documented the extent of PCB contamination in Meandering Road Creek and Woods Inlet and identified runoff from outfalls 4 and 5 at AFP4 as prominent sources of these PCBs. This report describes the results of a fourth study by the USGS, in cooperation with the Lockheed Martin Corporation, to investigate PCBs in suspended-sediment samples in storm runoff from outfalls 4 and 5 at AFP4 following the implementation of engineering controls designed to potentially alleviate PCB contamination in the drainage areas of these outfalls. Suspended-sediment samples collected from outfalls 4 and 5 during storms on March 2 and November 10, 2008, were analyzed for selected PCBs. Sums of concentrations of 18 reported PCB congeners (Sigma PCBc) in suspended-sediment samples collected before and after implementation of engineering controls are compared. At both outfalls, the Sigma PCBc before engineering controls was higher than the Sigma PCBc after engineering controls. The Sigma PCBc in suspended-sediment samples collected at AFP4 before and after implementation of

Relationship of sediment discharge to streamflow

USGS Publications Warehouse

Colby, B.R.

1956-01-01

The relationship between rate of sediment discharge and rate of water discharge at a cross section of a stream is frequently expressed by an average curve. This curve is the sediment rating curve. It has been widely used in the computation of average sediment discharge from water discharge for periods when sediment samples were not collected. This report discusses primarily the applications of sediment rating curves for periods during which at least occasional sediment samples were collected. Because sediment rating curves are of many kinds, the selection of the correct kind for each use is important. Each curve should be carefully prepared. In particular, the correct dependent variable must be used or the slope of the sediment rating curve may be incorrect for computing sediment discharges. Sediment rating curves and their applications were studied for the following gaging stations: 1. Niobrara River near Cody, Nebr. 2. Colorado River near Grand Canyon, Ariz. 3. Rio Grande at San Martial, N. Mex. 4. Rio Puerto near Bernardo, N. Mex. 5. White River near Kadoka, S. Dak. 6. Sandusky River near Fremont, Ohio Except for the Sandusky River and the Rio Puerco, which transport mostly fine sediment, one instantaneous sediment rating curve was prepared for the discharge of suspended sands, at each station, and another for the discharge of sediment finer than 0.082 millimeter. Each curve was studied separately, and by trial-end-error multiple correlation some of the factors that cause scatter from the sediment rating curves were determined. Average velocity at the cross section, Water temperature, and erratic fluctuations in concentration seemed to be the three major factors that caused departures from the sediment rating curves for suspended sands. The concentration of suspended sands varied with about the 2.8 power of the mean velocity for the four sediment, rating curves for suspended sands. The effect of water temperature was not so consistent as that of velocity and

Quantitative enzyme-linked immunosorbent assay for determination of polychlorinated biphenyls in environmental soil and sediment samples.

PubMed

Johnson, J C; Van Emon, J M

1996-01-01

An enzyme-linked immunosorbent assay (ELISA) for the quantitative determination of Aroclors 1242, 1248, 1254, and 1260 in soil and sediments was developed and its performance compared with that of gas chromatography (GC). The detection limits for Aroclors 1242 and 1248 in soil are 10.5 and 9 ng/g, respectively. The assay linear dynamic range is 50-1333 ng/g. Cross-reactivity of the assay with 37 structurally related potential cocontaminants in environmental soil samples was examined; none of the chlorinated anisoles, benzenes, or phenols exhibited >3% cross-reactivity, with <0.1% cross-reactivity being the norm. Soil spike recoveries of 107% and 104% were obtained for Aroclors 1242 and 1248, respectively, for a spike level of 5 mg/kg, with corresponding relative standard deviations of 14% and 17%. One hundred forty-eight environmental soil, sediment, and paper pulp samples, obtained from two EPA listed Superfund sites, were analyzed by ELISA and standard GC methods. Samples were extracted for ELISA analysis by shaking with methanol. Additional extractions of the same samples were performed either with supercritical carbon dioxide or by Soxhlet extraction with methanol. ELISA results for both the supercritical fluid and the Soxhlet extracts were in close agreement with the GC results, while the ELISA results for the methanol shake extracts were not. The data for the environmental samples demonstrated the capability of the ELISA to provide accurate results and reinforced the dependence of any detection method, including ELISA, on appropriate extraction procedures.

A comparison of four porewater sampling methods for metal mixtures and dissolved organic carbon and the implications for sediment toxicity evaluations.

PubMed

Cleveland, Danielle; Brumbaugh, William G; MacDonald, Donald D

2017-11-01

Evaluations of sediment quality conditions are commonly conducted using whole-sediment chemistry analyses but can be enhanced by evaluating multiple lines of evidence, including measures of the bioavailable forms of contaminants. In particular, porewater chemistry data provide information that is directly relevant for interpreting sediment toxicity data. Various methods for sampling porewater for trace metals and dissolved organic carbon (DOC), which is an important moderator of metal bioavailability, have been employed. The present study compares the peeper, push point, centrifugation, and diffusive gradients in thin films (DGT) methods for the quantification of 6 metals and DOC. The methods were evaluated at low and high concentrations of metals in 3 sediments having different concentrations of total organic carbon and acid volatile sulfide and different particle-size distributions. At low metal concentrations, centrifugation and push point sampling resulted in up to 100 times higher concentrations of metals and DOC in porewater compared with peepers and DGTs. At elevated metal levels, the measured concentrations were in better agreement among the 4 sampling techniques. The results indicate that there can be marked differences among operationally different porewater sampling methods, and it is unclear if there is a definitive best method for sampling metals and DOC in porewater. Environ Toxicol Chem 2017;36:2906-2915. Published 2017 Wiley Periodicals Inc. on behalf of SETAC. This article is a US government work and, as such, is in the public domain in the United States of America. Published 2017 Wiley Periodicals Inc. on behalf of SETAC. This article is a US government work and, as such, is in the public domain in the United States of America.

Aquatic sediments

DOE Office of Scientific and Technical Information (OSTI.GOV)

DePinto, J.V.; Young, T.C.; Booty, W.G.

1984-06-01

This literature review includes conference proceedings on the interactions of PCBs. Papers range from the adsorption/desorption behavior of PCBs to the influence of suspended and benthic sediments on fate and transport modeling of PCBs in the Great Lakes. Other papers are included in the review which involve analytical and sampling methods, paleolimnology, and modeling and sediment transport. Two papers presented the results of using radionuclides (Pb-210, Ru-106, Cs-137) in the study of lake-sediment dynamics. 111 references.

Map showing abundance and distribution of copper in oxide residues of stream-sediment samples, Medford 1 degree by 2 degrees Quadrangle, Oregon-California

USGS Publications Warehouse

Whittington, Charles L.; Grimes, David J.; Leinz, Reinhard W.

1985-01-01

Stream-sediment sampling in the Medford 1o x 2o quadrangle was undertaken to provide to aid in assessment of the mineral resource potential of the quadrangle. This map presents data on the abundance and distribution of copper in the oxide residues (oxalic-acid leachates) of stream sediments and in the minus-0.18-mm sieve fraction of selected stream sediments collected in the quadrangle. 

Map showing abundance and distribution of arsenic in oxide residues of stream-sediment samples, Medford 1 degree by 2 degrees Quadrangle, Oregon-California

USGS Publications Warehouse

Whittington, Charles L.; Leinz, Reinhard W.; Grimes, David J.

1985-01-01

Stream-sediment sampling in the Medford 1o x 2o quadrangle was undertaken to provide to aid in assessment of the mineral resource potential of the quadrangle. This map presents data on the abundance and distribution of copper in the oxide residues (oxalic-acid leachates) of stream sediments and in the minus-0.18-mm sieve fraction of selected stream sediments collected in the quadrangle. 

Verifying Sediment Fingerprinting Results with Known Mixtures

NASA Astrophysics Data System (ADS)

Gellis, A.; Gorman-Sanisaca, L.; Cashman, M. J.

2017-12-01

Sediment fingerprinting is a widely used approach to determine the specific sources of fluvial sediment within a watershed. It relies on the principle that potential sediment sources can be identified using a set of chemical tracers (or fingerprints), and comparison of these source fingerprints with fluvial (target) sediment allows for source apportionment of the fluvial sediment. There are numerous source classifications, fingerprints, and statistical approaches used in the literature to apportion sources of sediment. However, few of these studies have sought to test the method by creating controls on the ratio of sources in the target sediment. Without a controlled environment for inputs and outputs, such verification of results is ambiguous. Here, we generated artificial mixtures of source sediment from an agricultural/forested watershed in Virginia, USA (Smith Creek, 246 km2) to verify the apportionment results. Target samples were established from known mixtures of the four major sediment sources in the watershed (forest, pasture, cropland, and streambanks). The target samples were sieved to less than 63 microns and analyzed for elemental and isotopic chemistry. The target samples and source samples were run through the Sediment Source Assessment Tool (Sed_SAT) to verify if the statistical operations provided the correct apportionment. Sed_SAT uses a multivariate parametric approach to identify the minimum suite of fingerprints that discriminate the source areas and applies these fingerprints through an unmixng model to apportion sediment. The results of this sediment fingerprinting verification experiment will be presented in this session.

Climate and lake-level history of the northern altiplano, Bolivia, as recorded in holocene sediments of the Rio Desaguadero

USGS Publications Warehouse

Baucom, P.C.; Rigsby, C.A.

1999-01-01

Strata exposed in terraces and modern cutbanks along the Rio Desaguadero contain a variety of lithofacies that were deposited in four distinct facie??s associations. These facie??s associations document a history of aggradation and downcutting that is linked to Holocene climate change on the Altiplano. Braided-stream, meandering-stream, deltaic and shoreline, and lacustrine sediments preserved in multi-level terraces in the northern Rio Desaguadero valley record two high-water intervals: one between 4500 and 3900 yr BP and another between 2000 and 2200 yr BP. These wet periods were interrupted by three periods of fluvial downcutting, centered at approximately 4000 yr BP, 3600 yr BP, and after 2000 yr BP. Braided-river sediments preserved in a single terrace level in the southern Rio Desaguadero valley record a history of nearly continuous fluvial sedimentation from at least 7000 yr BP until approximately 3200 yr BP that was followed by a single episode (post-3210 yr BP) of downcutting and lateral migration. The deposition and subsequent fluvial downcutting of the northern strata was controlled by changes in effective moisture that can be correlated to Holocene water-level fluctuations of Lake Titicaca. The deposition and dissection of braided-stream sediments to the south are more likely controlled by a combination of base-level change and sediment input from the Rio Mauri. Copyright ??1999, SEPM (Society for Sedimentar)- Geology).

Soft-sediment deformation in a tectonically active area: The Plio-Pleistocene Zarzal Formation in the Cauca Valley (Western Colombia)

NASA Astrophysics Data System (ADS)

Neuwerth, Ralph; Suter, Fiore; Guzman, Carlos A.; Gorin, Georges E.

2006-04-01

The Plio-Pleistocene Zarzal Formation corresponds to fluvio-lacustrine sediments deposited in an intramontane depression within the Colombian Andes, associated with the Cauca-Romeral Fault System. It crops out mainly in the Cauca Valley where numerous field sections have permitted the mapping of the vertical and lateral lithological variations. Lacustrine deposits of sands, silts, clays and diatomites are interbedded with fluvial sand and gravel beds and fluvio-volcanic mass flows derived from the volcanic Central Cordillera. Numerous soft-sediment deformation structures are encountered in this formation, particularly in fine- to medium-grained sands, silts and clays: load structures (load casts, flame structures, pseudonodules), water escape structures (water escape cusps, dish-and-pillar and pocket-and-pillar structures), soft-sediment intrusions (clastic sills and dykes), disturbed laminites, convolute laminations, slumps and synsedimentary faulting. Deformation mechanisms and driving forces are related essentially to gravitational instabilities, dewatering, liquidization and brittle deformations. Field and regional geological data show that most of these deformations are related to seismicity and can be interpreted as seismites. This area has a geological and recent seismic history and outcrops show both syn- and post-depositional faulting related to the transpressional regime of this part of the Colombian Andes, which generates strike-slip faults and associated local normal faults. The drainage pattern within the Zarzal Formation shows the signature of neotectonics. Moreover, the fine to coarse-grained sands of the Zarzal Formation are lithologies prone to liquefaction when affected by seismic waves. The intercalation of the deformed intervals within undisturbed strata confirms the catastrophic nature of the events. Finally, the large areal extent of the deformations and the type of structures are compatible with seismites. Consequently, the existence of

Combining sediment fingerprinting and a conceptual model for erosion and sediment transfer to explore sediment sources in an Alpine catchment

NASA Astrophysics Data System (ADS)

Costa, A.; Stutenbecker, L.; Anghileri, D.; Bakker, M.; Lane, S. N.; Molnar, P.; Schlunegger, F.

2017-12-01

In Alpine basins, sediment production and transfer is increasingly affected by climate change and human activities, specifically hydropower exploitation. Changes in sediment sources and pathways significantly influence basin management, biodiversity and landscape evolution. We explore the dynamics of sediment sources in a partially glaciated and highly regulated Alpine basin, the Borgne basin, by combining geochemical fingerprinting with the modelling of erosion and sediment transfer. The Borgne basin in southwest Switzerland is composed of three main litho-tectonic units, which we characterised following a tributary-sampling approach from lithologically characteristic sub-basins. We analysed bulk geochemistry using lithium borate fusion coupled with ICP-ES, and we used it to discriminate the three lithologic sources using statistical methods. Finally, we applied a mixing model to estimate the relative contributions of the three sources to the sediment sampled at the outlet. We combine results of the sediment fingerprinting with simulations of a spatially distributed conceptual model for erosion and transport of fine sediment. The model expresses sediment erosion by differentiating the contributions of erosional processes driven by erosive rainfall, snowmelt, and icemelt. Soil erodibility is accounted for as function of land-use and sediment fluxes are linearly convoluted to the outlet by sediment transfer rates for hillslope and river cells, which are a function of sediment connectivity. Sediment connectivity is estimated on the basis of topographic-hydraulic connectivity, flow duration associated with hydropower flow abstraction and permanent storage in hydropower reservoirs. Sediment fingerprinting at the outlet of the Borgne shows a consistent dominance (68-89%) of material derived from the uppermost, highly glaciated reaches, while contributions of the lower part (10-25%) and middle part (1-16%), where rainfall erosion is predominant, are minor. This result is

Magnetic Mineralogy as Indicator of dry Conditions in Lacustrine Sediments From Santa María del Oro, Nayarit, Central Mexico

NASA Astrophysics Data System (ADS)

Ortega, B.; Vazquez, G.; Rodriguez, A.

2007-05-01

Combined magnetic and geochemical analysis were conducted on laminated sediments from Santa Maria del Oro, a crater lake in Nayarit (Mexico), to build up a model of paleoenvironmental conditions for the late Holocene. The occurrence of a severe drought at the end of the archeological Classic period (100 - 900 AD) has been documented in sites of central Mexico (Zirahuen lake and Lerma basin), the Gulf of Mexico coast (Los Tuxtlas) and the Yucatan peninsula. The effects of this climatic event are considered to have stressed the social and political situation in the Yucatan area and other sites in Mesoamerica, and resulted in the "collapse" of the Maya civilization. Santa Maria del Oro sediments between ca. 600 - 1140 AD are characterized by repeated sequences of ocher silt laminae with high inorganic carbon content, authigenic siderite, and low concentration of SD magnetic minerals, followed upward by an increase of concentrations of fine grained SD and SP ferrimagnetic minerals in brown silt laminae. This sequence is considered to represent dissolution-precipitation cycles of magnetic minerals in low erosion, concentrated waters and anoxic water-sediment interface environments. Dissolution of magnetite occurs in reductive conditions, which are considered as warmer and dryer periods. Above the ocher silt, precipitation of fine grained magnetite occurs when conditions change to oxic environments. Ostracode C and O isotopy document a negative precipitation/evaporation balance during this time period.

Anatomy of major coal successions: Facies analysis and sequence architecture of a brown coal-bearing valley fill to lacustrine tract (Upper Valdarno Basin, Northern Apennines, Italy)

NASA Astrophysics Data System (ADS)

Ielpi, Alessandro

2012-07-01

A late Pliocene incised valley fill to lacustrine succession, which contains an interbedded brown coal seam (< 20 m thick), is examined in terms of facies analysis, physical stratigraphy and sequence architecture. The succession (< 50 m thick) constitutes the first depositional event of the Castelnuovo Synthem, which is the oldest unconformity bounded stratigraphic unit of the nonmarine Upper Valdarno Basin, Northern Apennines (Italy). The integration of field surveys and borehole logs identified the following event sequence: first valley filling stages by coarse alluvial fan and channelised streams; the progressive setting of low gradient floodbasins with shallow floodplain lakes; subsequent major waterlogging and extensive peat mire development; and system drowning and establishment of permanent lacustrine conditions. The deposits are grouped in a set of nested valley fills and are arranged as high-frequency depositional sequences. The sequences are bounded by minor erosive truncations and have distinctive upward trends: lowstand system tract thinning; transgressive system tract thickening; highstand system tract thinning and eventual non-deposition; and the smoothing of along-sequence boundary sub-aerial incisions. Such features fit in with the notion of an idealised model where second-order (high-frequency) fluctuations, modulated by first-order (low-frequency) base-level rising, have short-lived standing + falling phases and prolonged transgressions, respectively. Furthermore, the general sequence architecture reveals how a mixed palustrine-siliciclastic system differs substantially from a purely siliciclastic one. In the transgressive phases, terrigenous starvation induces prevailing peat accumulation, generating abnormally thick transgressive system tracts that eventually come to occupy much of the same transgression-generated accommodation space. In the highstand phases, the development of thick highstand system tracts is then prevented by sediment upstream

Using sediment particle size distribution to evaluate sediment sources in the Tobacco Creek Watershed

NASA Astrophysics Data System (ADS)

Liu, Cenwei; Lobb, David; Li, Sheng; Owens, Philip; Kuzyk, ZouZou

2014-05-01

Lake Winnipeg has recently brought attention to the deteriorated water quality due to in part to nutrient and sediment input from agricultural land. Improving water quality in Lake Winnipeg requires the knowledge of the sediment sources within this ecosystem. There are a variety of environmental fingerprinting techniques have been successfully used in the assessment of sediment sources. In this study, we used particle size distribution to evaluate spatial and temporal variations of suspended sediment and potential sediment sources collected in the Tobacco Creek Watershed in Manitoba, Canada. The particle size distribution of suspended sediment can reflect the origin of sediment and processes during sediment transport, deposition and remobilization within the watershed. The objectives of this study were to quantify visually observed spatial and temporal changes in sediment particles, and to assess the sediment source using a rapid and cost-effective fingerprinting technique based on particle size distribution. The suspended sediment was collected by sediment traps twice a year during rainfall and snowmelt periods from 2009 to 2012. The potential sediment sources included the top soil of cultivated field, riparian area and entire profile from stream banks. Suspended sediment and soil samples were pre-wet with RO water and sieved through 600 μm sieve before analyzing. Particle size distribution of all samples was determined using a Malvern Mastersizer 2000S laser diffraction with the measurement range up to 600μm. Comparison of the results for different fractions of sediment showed significant difference in particle size distribution of suspended sediment between snowmelt and rainfall events. An important difference of particle size distribution also found between the cultivated soil and forest soil. This difference can be explained by different land uses which provided a distinct fingerprint of sediment. An overall improvement in water quality can be achieved by

Holocene intramontane lake development: A new model in the Jáchal River Valley, Andean Precordillera, San Juan, Argentina

NASA Astrophysics Data System (ADS)

Colombo, Ferran; Busquets, Pere; Sole de Porta, Nuria; Limarino, Carlos Oscar; Heredia, Nemesio; Rodriguez-Fernandez, Luis Roberto; Alvarez-Marron, Joaquina

2009-10-01

The Jáchal River Valley displays a number of significant Holocene sedimentary accumulations made up of fine-grained materials. These deposits are interpreted as the sedimentary infill of shallow temporary lakes that were generated by slow growing episodes of alluvial fans that obstructed the Jáchal River Valley. The association of fossil remains through the Holocene sedimentary sequence suggests that the accumulation of lacustrine sediments was affected by climate variations. The predominant aridity was punctuated by very few humid episodes characterised by fresh-water gastropoda and the intercalations of muddy sediments. The high proportion of charcoal particles in some samples indicates periodic forest fires. Abundant non-pollen forest remains suggest that an open zone dominated by several types of grasses underwent a dry season during part of the year. The palynomorph associations found in the Jáchal River Valley Holocene lacustrine sediments suggest that the humid conditions were less intense than those in the San Juan River Valley located more than one hundred kilometres southwards. Our study suggests that lake formation could have been controlled by climate oscillation probably related to the ENSO variation at 30° south latitude.

Accelerated solvent extraction followed by on-line solid-phase extraction coupled to ion trap LC/MS/MS for analysis of benzalkonium chlorides in sediment samples

USGS Publications Warehouse

Ferrer, I.; Furlong, E.T.

2002-01-01

Benzalkonium chlorides (BACs) were successfully extracted from sediment samples using a new methodology based on accelerated solvent extraction (ASE) followed by an on-line cleanup step. The BACs were detected by liquid chromatography/ion trap mass spectrometry (LC/MS) or tandem mass spectrometry (MS/MS) using an electrospray interface operated in the positive ion mode. This methodology combines the high efficiency of extraction provided by a pressurized fluid and the high sensitivity offered by the ion trap MS/MS. The effects of solvent type and ASE operational variables, such as temperature and pressure, were evaluated. After optimization, a mixture of acetonitrile/water (6:4 or 7:3) was found to be most efficient for extracting BACs from the sediment samples. Extraction recoveries ranged from 95 to 105% for C12 and C14 homologues, respectively. Total method recoveries from fortified sediment samples, using a cleanup step followed by ASE, were 85% for C12BAC and 79% for C14-BAC. The methodology developed in this work provides detection limits in the subnanogram per gram range. Concentrations of BAC homologues ranged from 22 to 206 ??g/kg in sediment samples from different river sites downstream from wastewater treatment plants. The high affinity of BACs for soil suggests that BACs preferentially concentrate in sediment rather than in water.

Examination of factors dominating the sediment-water diffusion flux of DDT-related compounds measured by passive sampling in an urbanized estuarine bay.

PubMed

Feng, Yan; Wu, Chen-Chou; Bao, Lian-Jun; Shi, Lei; Song, Lin; Zeng, Eddy Y

2016-12-01

The fate of hydrophobic organic compounds in aquatic environment are largely determined by their exchange at sediment-water interface, which is highly dynamic and subject to rapidly evolving environmental conditions. In turn, environmental conditions may be governed by both physicochemical parameters and anthropogenic events. To examine the importance of various impact factors, passive sampling devices were deployed at the seafloor of Hailing Bay, an urbanized estuarine bay in Guangdong Province of South China to measure the sediment-water diffusion fluxes of several metabolites of dichlorodiphenyltrichloroethane (DDT), p,p'-DDE, p,p'-DDD and o,p'-DDD. The physicochemical properties of water (temperature, pH, salinity and dissolved oxygen) and surface sediment (sediment organic matter, physical composition, pH, water content, colony forming unit and catalase activity) were also measured. The results showed that the diffusion fluxes of o,p'-DDD, p,p'-DDD and p,p'-DDE at sites A1 and A2 near a fishing boat maintenance facility ranged from 0.42 to 4.73 ng m -2 d -1 (from sediment to overlying water), whereas those at offshore sites varied between -0.03 and -3.02 ng m -2 d -1 (from overlying water to sediment), implicating A1 and A2 as the sources of the target compounds. The distribution patterns of the diffusion fluxes of the target compounds were different from those of water and sediment parameters (water temperature, salinity, sediment texture, pH, colony forming unit and catalase activity) at six sampling sites. This finding suggested that none of these parameters were critical in dictating the sediment-water diffusion fluxes. Besides, decreases in the contents of kerogen and black carbon by 6.7% and 11% would enhance the diffusion fluxes of the target compounds by 11-14% and 12-23%, respectively, at site A1, indicating that kerogen and black carbon were the key factors in mediating the sediment-water diffusion fluxes of DDT-related compounds in field

Enrichment and identification of polycyclic aromatic compound-degrading bacteria enriched from sediment samples.

PubMed

Long, Rachel M; Lappin-Scott, Hilary M; Stevens, Jamie R

2009-07-01

The degradation of polycyclic aromatic compounds (PACs) has been widely studied. Knowledge of the degradation of PACs by microbial populations can be utilized in the remediation of contaminated sites. To isolate and identify PAC-degrading bacteria for potential use in future bioremediation programmes, we established a series of PAC enrichments under the same experimental conditions from a single sediment sample taken from a highly polluted estuarine site. Enrichment cultures were established using the pollutants: anthracene, phenanthrene and dibenzothiophene as a sole carbon source. The shift in microbial community structure on each of these carbon sources was monitored by analysis of a time series of samples from each culture using 16S rRNA polymerase chain reaction-denaturing gradient gel electrophoresis (PCR-DGGE). Significantly, our findings demonstrate that shifts in the constituent species within each degradative community are directly attributable to enrichment with different PACs. Subsequently, we characterized the microorganisms comprising the degradative communities within each enrichment using 16S rRNA sequence data. Our findings demonstrate that the ability to degrade PACs is present in five divisions of the Proteobacteria and Actinobacteria. By determining the precise identity of the PAC-degrading bacterial species isolated from a single sediment sample, and by comparing our findings with previously published research, we demonstrate how bacteria with similar PAC degrading capabilities and 16S rRNA signatures are found in similarly polluted environments in geographically very distant locations, e.g., China, Italy, Japan and Hawaii. Such a finding suggests that geographical barriers do not limit the distribution of key PAC-degrading bacteria; this finding is in accordance with the Baas-Becking hypothesis "everything is everywhere; the environment selects" and may have significant consequences for the global distribution of PAC-degrading bacteria and

Optimization of sample preparation and chromatography for the determination of perfluoroalkyl acids in sediments from the Yangtze Estuary and East China Sea.

PubMed

Wang, Qian-Wen; Yang, Gui-Peng; Zhang, Ze-Ming; Zhang, Jing

2018-08-01

Perfluoroalkyl acids (PFAAs) are ubiquitous pollutants present in various environmental media, including marine sediments. A method was proposed for the determination of 17 target PFAA analytes in marine sediment samples (n = 49) collected from the Yangtze Estuary and East China Sea. The proposed method involves the use of an optimized pretreatment procedure and ultrahigh-performance liquid chromatography electrospray ionization-tandem mass spectrometry in dynamic multiple reaction monitoring mode. The method relied on extraction cycles using methanol followed by concentration, filtration, and small volume injection to UHPLC-MS/MS. The recovery, time efficiency, and detection limit of the proposed method are improved relative to those of traditional methods. Limits of detection varied from 0.003 to 0.045 ng/g, and spike recoveries to sediment ranged from 90% to 110% with suitable precisions (1.7%-14.6%). PFAAs were widely present in the samples, and ΣPFAAs ranged from 0.67 ng/g dw to 36.75 ng/g dw. Results indicated that terrigenous input strongly influences PFAA distribution in sediments from the study areas. Perfluorooctanoic acid (PFOA) and perfluorooctanesulfonate (PFOS) were identified as the dominant perfluorocarboxylic acid (PFCA) and perfluoroalkylsulfonate (PFSA) in sediment samples from the Yangtze Estuary and the East China Sea. Preliminary environmental risk assessment indicated that PFOS may pose a higher environmental risk than PFOA. Furthermore, risk quotient values indicated that PFOS poses a significant risk to the aquatic ecosystem of the study areas. Copyright © 2018 Elsevier Ltd. All rights reserved.

Determination of plutonium and its isotopic ratio in marine sediment samples using quadrupole ICP-MS with the shield torch system under normal plasma conditions.