Preparation of polymeric diacetylene thin films for nonlinear optical applications

NASA Technical Reports Server (NTRS)

Frazier, Donald O. (Inventor); Mcmanus, Samuel P. (Inventor); Paley, Mark S. (Inventor); Donovan, David N. (Inventor)

1995-01-01

A method for producing polymeric diacetylene thin films having desirable nonlinear optical characteristics has been achieved by producing amorphous diacetylene polymeric films by simultaneous polymerization of diacetylene monomers in solution and deposition of polymerized diacetylenes on to the surface of a transparent substrate through which ultraviolet light has been transmitted. These amorphous polydiacetylene films produced by photo-deposition from solution possess very high optical quality and exhibit large third order nonlinear optical susceptibilities, such properties being suitable for nonlinear optical devices such as waveguides and integrated optics.

Sixth-order wave aberration theory of ultrawide-angle optical systems.

PubMed

Lu, Lijun; Cao, Yiqing

2017-10-20

In this paper, we develop sixth-order wave aberration theory of ultrawide-angle optical systems like fisheye lenses. Based on the concept and approach to develop wave aberration theory of plane-symmetric optical systems, we first derive the sixth-order intrinsic wave aberrations and the fifth-order ray aberrations; second, we present a method to calculate the pupil aberration of such kind of optical systems to develop the extrinsic aberrations; third, the relation of aperture-ray coordinates between adjacent optical surfaces is fitted with the second-order polynomial to improve the calculation accuracy of the wave aberrations of a fisheye lens with a large acceptance aperture. Finally, the resultant aberration expressions are applied to calculate the aberrations of two design examples of fisheye lenses; the calculation results are compared with the ray-tracing ones with Zemax software to validate the aberration expressions.

Anomalous nonlinear absorption in epsilon-near-zero materials: optical limiting and all-optical control.

PubMed

Vincenti, M A; de Ceglia, D; Scalora, Michael

2016-08-01

We investigate nonlinear absorption in films of epsilon-near-zero materials. The combination of large local electric fields at the fundamental frequency and material losses at the harmonic frequencies induce unusual intensity-dependent phenomena. We predict that the second-order nonlinearity of a low-damping, epsilon-near-zero slab produces an optical limiting effect that mimics a two-photon absorption process. Anomalous absorption profiles that depend on low permittivity values at the pump frequency are also predicted for third-order nonlinearities. These findings suggest new opportunities for all-optical light control and novel ways to design reconfigurable and tunable nonlinear devices.

Reverse saturable absorption studies in polymerized indole - Effect of polymerization in the phenomenal enhancement of third order optical nonlinearity

NASA Astrophysics Data System (ADS)

Jayakrishnan, K.; Joseph, Antony; Bhattathiripad, Jayakrishnan; Ramesan, M. T.; Chandrasekharan, K.; Siji Narendran, N. K.

2016-04-01

We report our results on the identification of large order enhancement in nonlinear optical coefficients of polymerized indole and its comparative study with reference to its monomer counterpart. Indole monomer shows virtually little third order effects whereas its polymerized version exhibits phenomenal increase in its third order nonlinear optical parameters such as nonlinear refractive index and nonlinear absorption. Open aperture Z-scan trace of polyindole done with Q-switched Nd:YAG laser source (532 nm, 7 ns), shows β value as high as 89 cm/GW at a beam energy of 0.83 GW/cm2. Closed aperture Z-scan done at identical energies reveals nonlinear refractive index of the order of -3.55 × 10-17 m2/W. Band gap measurement of polyindole was done with UV-Vis absorption spectra and compared with that of Indole. FTIR spectra of the monomer and polymerized versions were recorded and relevant bond formations were confirmed from the characteristic peaks. Photo luminescent spectra were investigated to know the emission features of both molecules. Beam energy (I0) versus nonlinear absorption coefficient (β) plot indicates reverse saturable type of absorption behaviour in polyindole molecules. Degenerate Four Wave Mixing (DFWM) plot of polyindole reveals quite a cubic dependence between probe and phase conjugate signal and the resulting χ(3) is comparable with Z-scan results. Optical limiting efficiency of polyindole is comparable with certain derivatives of porphyrins, phthalocyanines and graphene oxides.

Transmission Measurement of the Third-Order Susceptibility of Gold

NASA Technical Reports Server (NTRS)

Smith, David D.; Yoon, Youngkwon; Boyd, Robert W.; Crooks, Richard M.; George, Michael

1999-01-01

Gold nanoparticle composites are known to display large optical nonlinearities. In order to assess the validity of generalized effective medium theories (EMT's) for describing the linear and nonlinear optical properties of metal nanoparticle composites, knowledge of the linear and nonlinear susceptibilities of the constituent materials is a prerequisite. In this study the inherent nonlinearity of the metal is measured directly (rather than deduced from a suitable EMT) using a very thin gold film. Specifically, we have used the z-scan technique at a wavelength near the transmission window of bulk gold to measure the third-order susceptibility of a continuous thin gold film deposited on a quartz substrate surface-modified with a self-assembled monolayer to promote adhesion and uniformity without affecting the optical properties. We compare our results with predictions which ascribe the nonlinear response to a Fermi-smearing mechanism. Further, we note that the sign of the nonlinear susceptibility is reversed from that of gold nanoparticle composites.

Large electronic third-order optical nonlinearities of cyanine dyes measured by resonant femtosecond degenerate four-wave mixing

NASA Astrophysics Data System (ADS)

Kasatani, Kazuo

2003-01-01

Third-order optical nonlinearities of several cyanine dyes were measured under resonant conditions by the femtosecond degenerate four-wave mixing (DFWM) technique. Temporal profiles of the DFWM signal were measured with a time resolution of 0.3 ps, and were found to consist of at least two components, the coherent instantaneous nonlinear response and the delayed response with a decay time constant of several hundred picoseconds. The latter can be attributed to molecular rotational relaxation of these dyes. The values of electronic component of the optical nonlinear susceptibility, χ e xxxx (3), for these dyes were ≈2×10 -12 esu at the very low concentration of 1×10 -5 mol dm -3. The electronic component of molecular hyperpolarizability, γe, was calculated to be ≈1×10 -28 esu for each dye.

Decrease and enhancement of third-order optical nonlinearity in metal-dielectric composite films

NASA Astrophysics Data System (ADS)

Ning, Tingyin; Lu, Heng; Zhou, Yueliang; Man, Baoyuan

2018-04-01

We investigate third-order optical nonlinearity in gold nanoparticles embedded in CaCu3Ti4O12 (CCTO) films using the Z-scan method. We observe that the effective third-order nonlinear optical susceptibilities in such composite films can not only be enhanced, in line with the conventional behavior, but also be decreased, depending on the volume concentration of gold. In particular, the nonlinear absorption behavior can be changed from saturable absorption in pure CCTO films to reversed saturable absorption in composite films, and theoretically, even zero nonlinear absorption could be obtained. These results indicate that it should be possible to tune the third-order optical nonlinearity in Au:CCTO composite films by altering the gold concentration, thus making them suitable for applications in photonic devices.

Ultralow-power and ultrafast all-optical tunable plasmon-induced transparency in metamaterials at optical communication range.

PubMed

Zhu, Yu; Hu, Xiaoyong; Fu, Yulan; Yang, Hong; Gong, Qihuang

2013-01-01

Actively all-optical tunable plasmon-induced transparency in metamaterials paves the way for achieving ultrahigh-speed quantum information processing chips. Unfortunately, up to now, very small experimental progress has been made for all-optical tunable plasmon-induced transparency in metamaterials in the visible and near-infrared range because of small third-order optical nonlinearity of conventional materials. The achieved operating pump intensity was as high as several GW/cm(2) order. Here, we report an ultralow-power and ultrafast all-optical tunable plasmon-induced transparency in metamaterials coated on polycrystalline indium-tin oxide layer at the optical communication range. Compared with previous reports, the threshold pump intensity is reduced by four orders of magnitude, while an ultrafast response time of picoseconds order is maintained. This work not only offers a way to constructing photonic materials with large nonlinearity and ultrafast response, but also opens up the possibility for realizing quantum solid chips and ultrafast integrated photonic devices based on metamaterials.

Ultralow-power and ultrafast all-optical tunable plasmon-induced transparency in metamaterials at optical communication range

PubMed Central

Zhu, Yu; Hu, Xiaoyong; Fu, Yulan; Yang, Hong; Gong, Qihuang

2013-01-01

Actively all-optical tunable plasmon-induced transparency in metamaterials paves the way for achieving ultrahigh-speed quantum information processing chips. Unfortunately, up to now, very small experimental progress has been made for all-optical tunable plasmon-induced transparency in metamaterials in the visible and near-infrared range because of small third-order optical nonlinearity of conventional materials. The achieved operating pump intensity was as high as several GW/cm2 order. Here, we report an ultralow-power and ultrafast all-optical tunable plasmon-induced transparency in metamaterials coated on polycrystalline indium-tin oxide layer at the optical communication range. Compared with previous reports, the threshold pump intensity is reduced by four orders of magnitude, while an ultrafast response time of picoseconds order is maintained. This work not only offers a way to constructing photonic materials with large nonlinearity and ultrafast response, but also opens up the possibility for realizing quantum solid chips and ultrafast integrated photonic devices based on metamaterials. PMID:23903825

Evaluating the component contribution to nonlinear optical performances using stable [Ni4O4] cuboidal clusters as models.

PubMed

Hao, Zhi-Min; Chao, Meng-Yao; Liu, Yan; Song, Ying-Lin; Yang, Jun-Yi; Ding, Lifeng; Zhang, Wen-Hua; Lang, Jian-Ping

2018-06-19

Five stable clusters sharing the cuboidal [Ni4O4] skeleton are subjected to third-order nonlinear optical (NLO) property measurements. Preliminary results suggest that the NLO property is largely defined by the cluster core skeleton and the directly coordinated atoms, with limited contribution from the heavy atoms peripherally attached to the aromatic ligands.

Probing optically silent superfluid stripes in cuprates

NASA Astrophysics Data System (ADS)

Rajasekaran, S.; Okamoto, J.; Mathey, L.; Fechner, M.; Thampy, V.; Gu, G. D.; Cavalleri, A.

2018-02-01

Unconventional superconductivity in the cuprates coexists with other types of electronic order. However, some of these orders are invisible to most experimental probes because of their symmetry. For example, the possible existence of superfluid stripes is not easily validated with linear optics, because the stripe alignment causes interlayer superconducting tunneling to vanish on average. Here we show that this frustration is removed in the nonlinear optical response. A giant terahertz third harmonic, characteristic of nonlinear Josephson tunneling, is observed in La1.885Ba0.115CuO4 above the transition temperature Tc = 13 kelvin and up to the charge-ordering temperature Tco = 55 kelvin. We model these results by hypothesizing the presence of a pair density wave condensate, in which nonlinear mixing of optically silent tunneling modes drives large dipole-carrying supercurrents.

Photodeposition of Thin Polydiacetylene Films from Solution that Exhibit Large Third-Order Optical Nonlinearities

NASA Technical Reports Server (NTRS)

Paley, M. S.; Frazier, D. O.; Abdeldayem, H.; McManus, S. P.

1994-01-01

One promising class of organic compounds for applications in the field of nonlinear optics (NLO) are polydiacetylenes, which are of interest because they are highly conjugated polymers capable of exhibiting very large optical nonlinearities with fast response times. During the course of crystal growth studies in anticipation of a space experiment, we discovered a novel, simple method for the formation of polydiacetylene thin films by photodeposition from monomer solutions onto quartz or glass substrates. Characterization of these PDAMNA films is not trivial; they are not soluble in common organic solvents, which makes the standard solution-based methods of polymer analysis useless.

Third-order nonlinear optical properties of thin sputtered gold films

NASA Astrophysics Data System (ADS)

Xenogiannopoulou, E.; Aloukos, P.; Couris, S.; Kaminska, E.; Piotrowska, A.; Dynowska, E.

2007-07-01

Au films of thickness ranging between 5 and 52 nm were prepared by sputtering on quartz substrates and their third-order nonlinear optical response was investigated by Optical Kerr effect (OKE) and Z-scan techniques using 532 nm, 35 ps laser pulses. All prepared films were characterized by XRD, AFM and UV-VIS-NIR spectrophotometry while their third-order susceptibility χ(3) was measured and found to be of the order of 10 -9 esu. The real and imaginary parts of the third-order susceptibility were found in very good agreement with experimental results and theoretical predictions reported by Smith et al. [D.D. Smith, Y. Yoon, R.W. Boyd, Y.K. Cambell, L.A. Baker, R.M. Crooks, M. George, J. Appl. Phys. 86 (1999) 6200].

Characterization of second and third order optical nonlinearities of ZnO sputtered films

NASA Astrophysics Data System (ADS)

Larciprete, M. C.; Haertle, D.; Belardini, A.; Bertolotti, M.; Sarto, F.; Günter, P.

2006-03-01

We measured the second and third order optical nonlinearity of zinc oxide, grown on glass substrates by the ion beam sputtering technique. Second and third harmonic generation measurements were performed by means of the rotational Maker fringes technique for different polarization configurations, thus allowing the determination of all non-zero components of the second order susceptibility at three different fundamental beam wavelengths, i.e., 1064 nm, 1542 nm and 1907 nm. The dispersion of the nonlinear optical coefficients has been evaluated, while the nonlinear optical coefficients were found to range between 0.9 pm/V and 0.16 pm/V for d33, 0.53 pm/V and 0.08 pm/V for |d15|, 0.31 and 0.08 pm/V for |d31|, with increasing wavelength. Finally, one third order susceptibility, χijkl (3), has been determined by third harmonic generation measurements at a fundamental wavelength λ=1907 nm and a value for χ3333 (3) of 185×10-20 m2/V2 has been found.

Optical nonlinearities of excitons in monolayer MoS2

NASA Astrophysics Data System (ADS)

Soh, Daniel B. S.; Rogers, Christopher; Gray, Dodd J.; Chatterjee, Eric; Mabuchi, Hideo

2018-04-01

We calculate linear and nonlinear optical susceptibilities arising from the excitonic states of monolayer MoS2 for in-plane light polarizations, using second-quantized bound and unbound exciton operators. Optical selection rules are critical for obtaining the susceptibilities. We derive the valley-chirality rule for the second-order harmonic generation in monolayer MoS2 and find that the third-order harmonic process is efficient only for linearly polarized input light while the third-order two-photon process (optical Kerr effect) is efficient for circularly polarized light using a higher order exciton state. The absence of linear absorption due to the band gap and the unusually strong two-photon third-order nonlinearity make the monolayer MoS2 excitonic structure a promising resource for coherent nonlinear photonics.

Substituent Dependence of Third-Order Optical Nonlinearity in Chalcone Derivatives

NASA Astrophysics Data System (ADS)

Kiran, Anthony John; Satheesh Rai, Nooji; Chandrasekharan, Keloth; Kalluraya, Balakrishna; Rotermund, Fabian

2008-08-01

The third-order nonlinear optical properties of derivatives of dibenzylideneacetone were investigated using the single beam z-scan technique at 532 nm. A strong dependence of third-order optical nonlinearity on electron donor and acceptor type of substituents was observed. An enhancement in χ(3)-value of one order of magnitude was achieved upon the substitution of strong electron donors compared to that of the molecule substituted with an electron acceptor. The magnitude of nonlinear refractive index of these chalcones is as high as of 10-11 esu. Their nonlinear optical coefficients are larger than those of widely used thiophene oligomers and trans-1-[p-(p-dimethylaminobenzyl-azo)-benzyl]-2-(N-methyl-4-pyridinium)-ethene iodide (DABA-PEI) organic compounds.

Rigorous theory of molecular orientational nonlinear optics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kwak, Chong Hoon, E-mail: chkwak@ynu.ac.kr; Kim, Gun Yeup

2015-01-15

Classical statistical mechanics of the molecular optics theory proposed by Buckingham [A. D. Buckingham and J. A. Pople, Proc. Phys. Soc. A 68, 905 (1955)] has been extended to describe the field induced molecular orientational polarization effects on nonlinear optics. In this paper, we present the generalized molecular orientational nonlinear optical processes (MONLO) through the calculation of the classical orientational averaging using the Boltzmann type time-averaged orientational interaction energy in the randomly oriented molecular system under the influence of applied electric fields. The focal points of the calculation are (1) the derivation of rigorous tensorial components of the effective molecularmore » hyperpolarizabilities, (2) the molecular orientational polarizations and the electronic polarizations including the well-known third-order dc polarization, dc electric field induced Kerr effect (dc Kerr effect), optical Kerr effect (OKE), dc electric field induced second harmonic generation (EFISH), degenerate four wave mixing (DFWM) and third harmonic generation (THG). We also present some of the new predictive MONLO processes. For second-order MONLO, second-order optical rectification (SOR), Pockels effect and difference frequency generation (DFG) are described in terms of the anisotropic coefficients of first hyperpolarizability. And, for third-order MONLO, third-order optical rectification (TOR), dc electric field induced difference frequency generation (EFIDFG) and pump-probe transmission are presented.« less

Third-order nonlinear optical property of a polyphenylene oligomer: poly(2,5-dialkozyphenylene)

NASA Astrophysics Data System (ADS)

Wu, Jianyao; Yan, Jun; Sun, Diechi; Li, Fuming; Zhou, Luwei; Sun, Meng

1997-02-01

The third-order nonlinear optical (NLO) property of a soluble, π-backbone conjugated polymer poly(2,5-dialkozyphenylene) (for abbreviation called dialkozy-PP) is studied at the picosecond time region. The near resonance third-order hyperpolarizability γxxxx at 532 nm is 8.2×10 -30 esu, and the corresponding macroscopic third-order susceptibility χ(3)(- ω, ω, ω, - ω) and nonlinear refractive index n2 are estimated to be 6.3×10 -10 esu and 1.4×10 -8 esu, respectively. The half-width of the laser pulse is 35 ps.

Design considerations for multi component molecular-polymeric nonlinear optical materials

NASA Astrophysics Data System (ADS)

Singer, K. D.; Kuzyk, M. G.; Fang, T.; Holland, W. R.; Cahill, P. A.

1990-08-01

We review our work on multi component polymeric nonlinear optical materials. These materials consist of nonlinear optical molecules incorporated in a polymeric host. A cross-linked triazine polymer incorporating a dicyanovinyl terminated azo dye was found to be relatively stable at 85 deg and possess an electro-optic coefficient of 11pm/V. We have also observed the zero dispersion condition in a new anomalous dispersion dye for phase matched second harmonic generation, and expect efficient conversion to the blue. A squarylium dye, ISQ, has been found to possess a large third order nonlinearity, and may display two-level behavior.

Optical design with Wood lenses

NASA Astrophysics Data System (ADS)

Caldwell, J. Brian

1991-01-01

Spherical aberration in a flat surfaced radial gradient-index lens (a Wood lens) with a parabolic index profile can be corrected by altering the profile to Include higher order terms. However this results in a large amowfl of third order coma. This paper presents an alternative method of aberration correction similar to that used in the catadiopthc Schmidtsystem. A Wood lens with a parabolic profile is used to provide all or most of the optical power. Coma is corrected by stop shifting and Spherical aberration is corrected by placing a powerless Wood lens corrector plate at the stop. 1.

Non-critically phase-matched second harmonic generation and third order nonlinearity in organic crystal glucuronic acid γ-lactone

NASA Astrophysics Data System (ADS)

Saripalli, Ravi Kiran; Katturi, Naga Krishnakanth; Soma, Venugopal Rao; Bhat, H. L.; Elizabeth, Suja

2017-12-01

The linear, second order, and third order nonlinear optical properties of glucuronic acid γ-lactone single crystals were investigated. The optic axes and principal dielectric axes were identified through optical conoscopy and the principal refractive indices were obtained using the Brewster's angle method. Conic sections were observed which is perceived to be due to spontaneous non-collinear phase matching. The direction of collinear phase matching was determined and the deff evaluated in this direction was 0.71 pm/V. Open and closed aperture Z-scan measurements with femtosecond pulses revealed high third order nonlinearity in the form of self-defocusing, two-photon absorption, as well as saturable absorption.

Nonlinear optical behavior of DNA-functionalized gold nanoparticles

NASA Astrophysics Data System (ADS)

Kulyk, B.; Krupka, O.; Smokal, V.; Figà, V.; Czaplicki, R.; Sahraoui, B.

2018-03-01

The third-order nonlinear optical properties of gold nanoparticles embedded in the DNA-based composites were investigated by means of the third harmonic generation. With this purpose, the thin films comprising DNA-based complexes and Au nanoparticles were spin-deposited on glass substrate and their optical and nonlinear optical features were studied using the Maker-fringe technique at a laser fundamental wavelength of 1064 nm. The values of the third-order susceptibility χ (3)(- 3ω; ω, ω, ω) of the composite films based on DNA complex doped with 5 wt% of N-ethyl-N-(2-hydroxyethyl)-4-(4-nitrophenylazo)aniline were found to be significantly higher than those for pure composite films. Meanwhile, the presence of Au nanoparticles noticeable decreases the third-order nonlinear response of DNA-based composite mainly due to the enhanced absorption and scattering of laser and generated beam, respectively.

Chi 3 dispersion in planar tantalum pentoxide waveguides in the telecommunications window.

PubMed

Chen, Ruiqi Y; Charlton, Martin D B; Lagoudakis, Pavlos G

2009-04-01

We report on the dispersion of the third-order nonlinear susceptibility (chi(3) or "Chi 3") in planar Ta2O5 waveguides in the telecommunications spectral window. We utilize the observation of third-harmonic generation under ultrashort pulsed excitation as a reference-free characterization method of chi(3) and obtain a large nonlinear coefficient, 2x10(-13) esu, at 1550 nm. Our observation of efficient third-harmonic generation in Ta2O5 waveguides in the telecoms window reveals the potential of this material system in high-speed integrated nonlinear optical switches.

Synthesis, crystal structure and third-order non-linear optical property of heterobimetallic cluster compound [MoOICu 3S 3(2,2'-bipy) 2

NASA Astrophysics Data System (ADS)

Li, Yong; Lu, Jing; Xu, Jiqing; Cui, Xiaobing; Sun, Yinghua; Yang, Qingxin; Pan, Lingyun

2004-03-01

Nest-shaped cluster [MoOICu 3S 3(2,2'-bipy) 2] ( 1) was synthesized by the treatment of (NH 4) 2MoS 4, CuI, ( n-Bu) 4NI, and 2,2'-bipyridine (2,2'-bipy) through a solid-state reaction. It crystallizes in monoclinic space group P2 1/ n, a=9.591(2) Å, b=14.820(3) Å, c=17.951(4) Å, β=91.98(2)°, V=2549.9(10) Å3, and Z=4. The nest-shaped cluster was obtained for the first time with a neutral skeleton containing 2,2'-bipy ligand. The non-linear optical (NLO) property of [MoOICu 3S 3(2,2'-bipy) 2] in DMF solution was measured by using a Z-scan technique with 15 ns and 532 nm laser pulses. The cluster has large third-order NLO absorption and the third-order NLO refraction, its α2 and n2 values were calculated as 6.2×10 -10 and -3.8×10 -17 m 2 W -1 in a 3.7×10 -4 M DMF solution.

Near resonant and nonresonant third-order optical nonlinearities of colloidal InP/ZnS quantum dots

NASA Astrophysics Data System (ADS)

Wang, Y.; Yang, X.; He, T. C.; Gao, Y.; Demir, H. V.; Sun, X. W.; Sun, H. D.

2013-01-01

We have investigated the third-order optical nonlinearities of high-quality colloidal InP/ZnS core-shell quantum dots (QDs) using Z-scan technique with femtosecond pulses. The two-photon absorption cross-sections as high as 6.2 × 103 GM are observed at 800 nm (non-resonant regime) in InP/ZnS QDs with diameter of 2.8 nm, which is even larger than those of CdSe, CdS, and CdTe QDs at similar sizes. Furthermore, both of the 2.2 nm and 2.8 nm-sized InP/ZnS QDs exhibit strong saturable absorption in near resonant regime, which is attributed to large exciton Bohr radius in this material. These results strongly suggest the promising potential of InP/ZnS QDs for widespread applications, especially in two-photon excited bio-imaging and saturable absorbing.

The third-order optical nonlinearities of Ge-Ga-Sb(In)-S chalcogenide glasses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guo, Haitao, E-mail: guoht_001@opt.ac.cn; Chen, Hongyan; Hou, Chaoqi

2011-05-15

Research highlights: {yields} It is firstly demonstrated that the nonlinear refractive index n{sub 2} is dependent on the covalency of bonds in chalcogenide glass. {yields} Homopolar metallic bonds in chalcogenide glass have positive contribution to large nonlinear refractive index n{sub 2} also. {yields} The 80GeS{sub 2}.20Sb{sub 2}S{sub 3} glass would be expected to be used in the all-optical switches working at 1330 nm and 1550 nm telecommunication wavelengths. -- Abstract: The third-order optical nonlinearities of 80GeS{sub 2}.(20 - x)Ga{sub 2}S{sub 3}.xY{sub 2}S{sub 3} (x = 0, 5, 10, 15, 20 and Y = Sb or In) chalcogenide glasses were investigatedmore » utilizing the Z-scan method at the wavelength of 800 nm and their linear optical properties and structure were also studied. By analyzing the compositional dependences and possible influencing factors including the linear refractive index, the concentration of lone electron pairs, the optical bandgap and the amount of weak covalent/homopolar bonds, it indicates that the electronic contribution in weak heteropolar covalent and homopolar metallic bonds is responsible for large nonlinear refractive index n{sub 2} in the chalcogenide glasses. These chalcogenide glasses have characteristics of environmentally friendship, wide transparency in the visible region, high nonlinear refractive index n{sub 2} and low nonlinear absorption coefficient {beta}, and would be expected to be used in the all-optical switches working at 1330 nm and 1550 nm telecommunication wavelengths.« less

A time correlation function theory describing static field enhanced third order optical effects at interfaces.

PubMed

Neipert, Christine; Space, Brian

2006-12-14

Sum vibrational frequency spectroscopy, a second order optical process, is interface specific in the dipole approximation. At charged interfaces, there exists a static field, and as a direct consequence, the experimentally detected signal is a combination of enhanced second and static field induced third order contributions. There is significant evidence in the literature of the importance/relative magnitude of this third order contribution, but no previous molecularly detailed approach existed to separately calculate the second and third order contributions. Thus, for the first time, a molecularly detailed time correlation function theory is derived here that allows for the second and third order contributions to sum frequency vibrational spectra to be individually determined. Further, a practical, molecular dynamics based, implementation procedure for the derived correlation functions that describe the third order phenomenon is also presented. This approach includes a novel generalization of point atomic polarizability models to calculate the hyperpolarizability of a molecular system. The full system hyperpolarizability appears in the time correlation functions responsible for third order contributions in the presence of a static field.

Probing optically silent superfluid stripes in cuprates

DOE PAGES

Rajasekaran, S.; Okamoto, J.; Mathey, L.; ...

2018-02-02

Unconventional superconductivity in the cuprates coexists with other types of electronic order. However, some of these orders are invisible to most experimental probes because of their symmetry. For example, the possible existence of superfluid stripes is not easily validated with linear optics, because the stripe alignment causes interlayer superconducting tunneling to vanish on average. In this paper, we show that this frustration is removed in the nonlinear optical response. A giant terahertz third harmonic, characteristic of nonlinear Josephson tunneling, is observed in La 1.885Ba 0.115CuO 4 above the transition temperature T c = 13 kelvin and up to the charge-orderingmore » temperature T co = 55 kelvin. We model these results by hypothesizing the presence of a pair density wave condensate, in which nonlinear mixing of optically silent tunneling modes drives large dipole-carrying supercurrents.« less

Probing optically silent superfluid stripes in cuprates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rajasekaran, S.; Okamoto, J.; Mathey, L.

Unconventional superconductivity in the cuprates coexists with other types of electronic order. However, some of these orders are invisible to most experimental probes because of their symmetry. For example, the possible existence of superfluid stripes is not easily validated with linear optics, because the stripe alignment causes interlayer superconducting tunneling to vanish on average. In this paper, we show that this frustration is removed in the nonlinear optical response. A giant terahertz third harmonic, characteristic of nonlinear Josephson tunneling, is observed in La 1.885Ba 0.115CuO 4 above the transition temperature T c = 13 kelvin and up to the charge-orderingmore » temperature T co = 55 kelvin. We model these results by hypothesizing the presence of a pair density wave condensate, in which nonlinear mixing of optically silent tunneling modes drives large dipole-carrying supercurrents.« less

Resonant and Nonresonant Nonlinear Optical Spectroscopy of CDSE Quantum Dots for Nonlinear Photonic Applications

DTIC Science & Technology

2006-11-01

Temple D., Yoo K. P., Kim S. Y., Mott A., Namkung M., and Jung S. S., 2003: Large and pure refractive nonlinearity of nanostructure silica ... aerogel , Appl. Phys. Lett., 82(25), 4444-4446. [18] Sun W., Patton T., Stultz L., andClaude J. P., 2003: Resonant third-order nonlinearities of tetrakis

Layer-Dependent Third-Harmonic Generation in Graphene

NASA Astrophysics Data System (ADS)

Yang, Hao; Guan, Honghua; Dadap, Jerry; Osgood, Richard; Richard Osgood Team

Graphene has become a subject of intense interest and study because of its remarkable 2D electronic properties. Multilayer graphene also offers an array of properties that are also of interest for optical physics and devices. Despite its second-order-nonlinear optical response is intrinsically weak, third-order nonlinear optical effects in graphene are symmetry-allowed thus leading to studies of several third-order process in few-layer graphene. In this work, we report third-harmonic generation in multilayer graphene mounted on fused silica and with thicknesses which approach the bulk continuum. THG signals show cubic power dependence with respect to the intensity of fundamental beam. Third-harmonic generation spectroscopy enables a good fit using linear optical detection, which shows strong contrast for different layer number graphene. The maximum THG efficiency appears at layer number around 30. Two models are used for describing this layer dependent phenomenon and shows absorption plays a key role in THG of multilayer graphene. This work also provides a new imaging technology for graphene detection and identification with better contrast and resolution. U.S. Department of Energy under Contract No. DE-FG 02-04-ER-46157.

Studies on third-order nonlinear optical properties of chalcone derivatives in polymer host

NASA Astrophysics Data System (ADS)

Shettigar, Seetharam; Umesh, G.; Chandrasekharan, K.; Sarojini, B. K.; Narayana, B.

2008-04-01

In this paper we present the experimental study of the third-order nonlinear optical properties of two chalcone derivatives, viz., 1-(4-methoxyphenyl)-3-(4-butyloxyphenyl)-prop-2-en-1-one and 1-(4-methoxyphenyl)-3-(4-propyloxyphenyl)-prop-2-en-1-one in PMMA host, with the prospective of reaching a compromise between good processability and high nonlinear optical properties. The nonlinear optical properties have been investigated by Z-scan technique using 7 ns laser pulses at 532 nm. The nonlinear refractive index, nonlinear absorption coefficient, magnitude of third-order susceptibility and the coupling factor have been determined. The values obtained are of the order of 10 -14 cm 2/W, 1 cm/GW, 10 -13 esu and 0.2, respectively. The molecular second hyperpolarizability for the chalcone derivatives in polymer is of the order of 10 -31 esu. Different guest/host concentrations have also been studied. The results suggest that the nonlinear properties of the chalcones have been improved when they are used as dopants in polymer matrix. The nonlinear parameters obtained are comparable with the reported values of II-VI compound semiconductors. Hence, these chalcons are a promising class of nonlinear optical dopant materials for optical device applications.

Study of third order nonlinearity of chalcogenide thin films using third harmonic generation measurements

NASA Astrophysics Data System (ADS)

Rani, Sunita; Mohan, Devendra; Kumar, Manish; Sanjay

2018-05-01

Third order nonlinear susceptibility of (GeSe3.5)100-xBix (x = 0, 10, 14) and ZnxSySe100-x-y (x = 2, y = 28; x = 4, y = 20; x = 6, y = 12; x = 8, y = 4) amorphous chalcogenide thin films prepared using thermal evaporation technique is estimated. The dielectric constant at incident and third harmonic wavelength is calculated using "PARAV" computer program. 1064 nm wavelength of Nd: YAG laser is incident on thin film and third harmonic signal at 355 nm wavelength alongwith fundamental light is obtained in reflection that is separated from 1064 nm using suitable optical filter. Reflected third harmonic signal is measured to trace the influence of Bi and Zn on third order nonlinear susceptibility and is found to increase with increase in Bi and Zn content in (GeSe3.5)100-xBix, and ZnxSySe100-x-y chalcogenide thin films respectively. The excellent optical nonlinear property shows the use of chalcogenide thin films in photonics for wavelength conversion and optical data processing.

Modified two-photon absorption and dispersion of ultrafast third-order polarization beats via twin noisy driving fields

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang Yanpeng; Department of Electronic Science and Technology, Xi'an Jiaotong University, Xi'an 710049; Gan Chenli

2006-05-15

We investigate the color-locked twin-noisy-field correlation effects in third-order nonlinear absorption and dispersion of ultrafast polarization beats. We demonstrate a phase-sensitive method for studying the two-photon nondegenerate four-wave mixing (NDFWM) due to atomic coherence in a multilevel system. The reference signal is another one-photon degenerate four-wave-mixing signal, which propagates along the same optical path as the NDFWM signal. This method is used for studying the phase dispersion of the third-order susceptibility and for the optical heterodyne detection of the NDFWM signal. The third-order nonlinear response can be controlled and modified through the color-locked correlation of twin noisy fields.

DOE Office of Scientific and Technical Information (OSTI.GOV)

D'silva, E.D., E-mail: deepak.dsilva@gmail.com; Podagatlapalli, G. Krishna; Venugopal Rao, S., E-mail: soma_venu@yahoo.com

Graphical abstract: Photograph and schematic representation of Z-scan experimental setup used to investigate third order nonlinear properties of the chalcone materials. Highlights: ► Br and NO{sub 2} substituted chalcone derivatives were exposed to picosecond laser pulses. ► Third-order nonlinear optical (NLO) properties were investigated. ► Compounds show promising third-order and optical limiting properties. ► These materials found suitable for electrical and optical applications. -- Abstract: In this paper we present results from the experimental study of third-order nonlinear optical (NLO) properties of three molecules of Br and NO{sub 2} substituted chalcone derivatives namely (2E)-1-(4-bromophenyl)-3-[4(methylsulfanyl)phenyl]prop-2-en-1-one (4Br4MSP), (2E)-1-(3-bromophenyl)-3-[4-(methylsulfanyl) phenyl]prop-2-en-1-one (3Br4MSP) and (2E)-3[4(methylsulfanyl)more » phenyl]-1-(4-nitrophenyl)prop-2-en-1-one (4N4MSP). The NLO properties have been investigated by Z-scan technique using 2 ps laser pulses at 800 nm. The nonlinear refractive indices, nonlinear absorption coefficient, and the magnitude of third-order susceptibility have been determined. The values obtained are of the order of 10{sup −7} cm{sup 2}/GW, 10{sup −3} cm/GW and 10{sup −14} esu respectively. The molecular second hyperpolarizability for the chalcone derivatives is of the order of 10{sup −32} esu. The coupling factor, excited state cross section, ground state cross section etc. were determined. The optical limiting (OL) property was studied. The results suggest that the nonlinear properties investigated for present chalcones are comparable with some of the reported chalcone derivatives and can be desirable for NLO applications.« less

Third-order optical conductivity of an electron fluid

NASA Astrophysics Data System (ADS)

Sun, Zhiyuan; Basov, D. N.; Fogler, M. M.

2018-02-01

We derive the nonlinear optical conductivity of an isotropic electron fluid at frequencies below the interparticle collision rate. In this regime, governed by hydrodynamics, the conductivity acquires a universal form at any temperature, chemical potential, and spatial dimension. We show that the nonlinear response of the fluid to a uniform field is dominated by the third-order conductivity tensor σ(3 ) whose magnitude and temperature dependence differ qualitatively from those in the conventional kinetic regime of higher frequencies. We obtain explicit formulas for σ(3 ) for Dirac materials such as graphene and Weyl semimetals. We make predictions for the third-harmonic generation, renormalization of the collective-mode spectrum, and the third-order circular magnetic birefringence experiments.

Incorporation of Keplerate-type Mo-O based macroanions into Zn2Al-LDH results in the formation of all-inorganic composite films with remarkable third-order optical nonlinearity.

PubMed

Ren, Haizhou; Shehzad, Farooq Khurum; Zhou, Yunshan; Zhang, Lijuan; Iqbal, Arshad; Long, Yi

2018-05-01

Herein, new all-inorganic transparent composite films with the formula (Zn2Al-LDH/{Mo132-Ac})n have been fabricated by a layer-by-layer method using the exfoliated Zn2Al-LDH monolayer nanosheets and Keplerate-type macroanion {Mo132-Ac}. They were characterized by UV-vis absorption spectroscopy, SEM, AFM, and XPS techniques. The Z-scan measurements, which were conducted under laser irradiation at a wavelength of 532 nm, a pulse width of 6 ns, a repetition rate of 10 Hz, and the light intensity at a focus E0 of 10 μJ, revealed that all the films had notable saturated absorption and self-defocusing effect with a large third-order optical nonlinear susceptibility χ(3). With an increase in the number of layers (i.e., n) corresponding to the increase in the thickness of the films, the third-order nonlinear absorption β and refractive effects of the films were improved (i.e., the χ(3) value was up to 1.99 × 10-11 esu when n = 24); this implied that the NLO responses could be modified by fine-tuning the thickness of the composite films to meet the demands of different devices.

Circularly polarized few-cycle optical rogue waves: rotating reduced Maxwell-Bloch equations.

PubMed

Xu, Shuwei; Porsezian, K; He, Jingsong; Cheng, Yi

2013-12-01

The rotating reduced Maxwell-Bloch (RMB) equations, which describe the propagation of few-cycle optical pulses in a transparent media with two isotropic polarized electronic field components, are derived from a system of complete Maxwell-Bloch equations without using the slowly varying envelope approximations. Two hierarchies of the obtained rational solutions, including rogue waves, which are also called few-cycle optical rogue waves, of the rotating RMB equations are constructed explicitly through degenerate Darboux transformation. In addition to the above, the dynamical evolution of the first-, second-, and third-order few-cycle optical rogue waves are constructed with different patterns. For an electric field E in the three lower-order rogue waves, we find that rogue waves correspond to localized large amplitude oscillations of the polarized electric fields. Further a complementary relationship of two electric field components of rogue waves is discussed in terms of analytical formulas as well as numerical figures.

Performance evaluation and optimization of multiband phase-modulated radio over IsOWC link with balanced coherent homodyne detection

NASA Astrophysics Data System (ADS)

Zong, Kang; Zhu, Jiang

2018-04-01

In this paper, we present a multiband phase-modulated (PM) radio over intersatellite optical wireless communication (IsOWC) link with balanced coherent homodyne detection. The proposed system can provide the transparent transport of multiband radio frequency (RF) signals with higher linearity and better receiver sensitivity than intensity modulated with direct detection (IM/DD) system. The expressions of RF gain, noise figure (NF) and third-order spurious-free dynamic range (SFDR) are derived considering the third-order intermodulation product and amplifier spontaneous emission (ASE) noise. The optimal power of local oscillator (LO) optical signal is also derived theoretically. Numerical results for RF gain, NF and third-order SFDR are given for demonstration. Results indicate that the gain of the optical preamplifier and the power of LO optical signal should be optimized to obtain the satisfactory performance.

Low threshold optical bistability in one-dimensional gratings based on graphene plasmonics.

PubMed

Guo, Jun; Jiang, Leyong; Jia, Yue; Dai, Xiaoyu; Xiang, Yuanjiang; Fan, Dianyuan

2017-03-20

Optical bistability of graphene surface plasmon is investigated numerically, using grating coupling method at normal light incidence. The linear surface plasmon resonance is strongly dependent on Femi-level of graphene, hence it can be tuned in a large wavelength range. Due to the field enhancement of graphene surface plasmon resonance and large third-order nonlinear response of graphene, a low-threshold optical hysteresis has been observed. The threshold value with 20MW/cm² and response time with 1.7ps have been verified. Especially, it is found that this optical bistability phenomenon is angular insensitivity for near 15° incident angle. The threshold of optical bistability can be further lowered to 0.5MW/cm² by using graphene nanoribbons, and the response time is also shorten to 800fs. We believe that our results will find potential applications in bistable devices and all-optical switching from mid-IR to THz range.

Nonlinear optical behavior of two tetrathiafulvalene derivatives in the picosecond regime

NASA Astrophysics Data System (ADS)

Marcovicz, Crislaine; Ferreira, Rudson C.; Santos, Arthur B. S.; Reyna, Albert S.; de Araújo, Cid B.; Malvestiti, Ivani; Falcão, Eduardo H. L.

2018-06-01

We report the microwave-assisted synthesis of two symmetrical tetrathiafulvalene (TTF) derivatives via trialkyl phosphite-promoted coupling of a DMIT precursor. The microwave irradiation led to an increase in the reaction yield and significantly reduced the reaction time, affording the 2,3,6,7-tetrakis(2‧-methylacetatethio)tetrathiafulvalene (4) in 74% isolated yield. Hydrolysis of 4 yielded the tetraacid 5 in excellent yield. The nonlinear optical properties of both TTF compounds at 532 nm were studied by using the Z-scan technique in the picosecond regime exhibiting large third-order refractive index and saturated nonlinear absorption with promising applications in optical limiting devices.

The Charles F. Prentice Award Lecture 2005: optics of the human eye: progress and problems.

PubMed

Charman, W Neil

2006-06-01

The history of measurements of ocular aberration is briefly reviewed and recent work using much-improved aberrometers and large samples of eyes is summarized. When on-axis, higher-order, monochromatic aberrations are averaged, undercorrected, positive, fourth-order spherical aberration dominates; other Zernike wavefront aberration coefficients have average values near zero. Individually, however, many eyes show substantial amounts of third-order and other fourth-order aberrations; the value of these varies idiosyncratically about zero. Most normal eyes show only small amounts of axial monochromatic aberration for photopic pupils up to around 3 mm; the limits to retinal image quality are then usually set by diffraction, uncorrected or imperfectly corrected spherocylindrical refractive error, accommodation error, and chromatic aberration. Longitudinal chromatic aberration varies very little across the population. With larger mesopic and scotopic pupils, monochromatic aberration plays a more important optical role, but overall visual performance is increasingly dominated by neural factors. Some remaining problems in measuring and modeling the eye's optical performance are discussed.

Spectroscopic, DFT and Z-scan supported investigation of dicyanoisophorone based push-pull NLOphoric styryl dyes

NASA Astrophysics Data System (ADS)

Erande, Yogesh; Sreenath, Mavila C.; Chitrambalam, Subramaniyan; Joe, Isaac H.; Sekar, Nagaiyan

2017-04-01

The dicyanoisophorone acceptor based NLOphores with Intramolecular Charge Transfer (ICT) character are newly synthesised, characterised and explored for linear and non linear optical (NLO) property investigation. Strong ICT character of these D-π-A styryl NLOphores is established with support of emission solvatochromism, polarity functions and Generalised Mulliken Hush (GMH) analysis. First, second and third order polarizability of these NLOphores is investigated by spectroscopic and TDDFT computational approach using CAM/B3LYP-6-311 + g (d, p) method. BLA and BOA values of these chromophores are evaluated from ground and excited state optimized geometries and found that the respective structures are approaching towards cyanine limit. Third order nonlinear susceptibility (X(3)) along with nonlinear absorption coefficient (β) and nonlinear refraction (n2) are evaluated for these NLOphores using Z-scan experiment. All four chromophores exhibit large polarization anisotropy (Δα), first order hyperpolarizability (β0), second order hyperpolarizability (γ) and third order nonlinear susceptibility (X(3)). TGA analysis proved these NLOphores are stable up to 320 °C and hence can be used in device fabrication.

Vapor deposition and characterization of supramolecular assemblies for integrated nonlinear optics

NASA Astrophysics Data System (ADS)

Esembeson, Bweh

Very recently, some organic molecules have been developed that are very compact and have exceptionally high molecular polarizabilities which approach the fundamental quantum limit. Supramolecular assemblies created from such highly nonlinear molecules could find applications in integrated nonlinear optics such as all-optical signal processing, electro-optic modulators and frequency conversion. In this work, we have constructed a versatile vacuum deposition system for the creation of organic thin films from these molecules that can be sublimated without decomposition. We have used deposition temperatures of the order of 100--200°C in a high vacuum of 10-6--10 -7 Torrs. While some molecules showed a tendency to form polycrystalline films, others led to very high optical quality films, with a roughness of less than 10 nm over tens of micrometers and no grains detected down to a size of 2 nm, as seen in Atomic Force and Scanning Electron Microscopy studies. The best material we developed has a linear refractive index of 1.8 +/- 0.1 at 1.5 mum and an off-resonant third order susceptibility, chi (3), measured through Degenerate Four Wave Mixing, of 2 +/- 1 x 10-19 m2V-2 at 1.5 mum, a value three orders of magnitude larger than fused silica. This vapor deposited thin film may represent one of the best materials demonstrated to date whereby a large third order susceptibility, high optical quality, and simplicity of fabrication and integration are in perfect harmony for integrated nonlinear optical applications. We have used this novel organic material to create a hybrid organic/silicon-on-insulator waveguide that showed a record high nonlinearity coefficient of 10 5 W-1m-1 and has been used as an all-optical switch for demultiplexing a 120 Gbit/s data stream to 10 Gbit/s on a 6 mm long device.

Microgravity Processing and Photonic Applications of Organic and Polymeric Materials

NASA Technical Reports Server (NTRS)

Frazier, Donald O.; Penn, Benjamin G.; Smith, David D.; Witherow, William K.; Paley, Mark S.; Abdeldayem, Hossin A.

1997-01-01

In recent years, a great deal of interest has been directed toward the use of organic materials in the development of high-efficiency optoelectronic and photonic devices. There is a myriad of possibilities among organics which allow flexibility in the design of unique structures with a variety of functional groups. The use of nonlinear optical (NLO) organic materials such as thin-film waveguides allows full exploitation of their desirable qualities by permitting long interaction lengths and large susceptibilities allowing modest power input. There are several methods in use to prepare thin films, such as Langmuir-Blodgett (LB) and self-assembly techniques, vapor deposition, growth from sheared solution or melt, and melt growth between glass plates. Organics have many features that make them desirable for use in optical devices such as high second- and third-order nonlinearities, flexibility of molecular design, and damage resistance to optical radiation. However, their use in devices has been hindered by processing difficulties for crystals and thin films. In this chapter, we discuss photonic and optoelectronic applications of a few organic materials and the potential role of microgravity on processing these materials. It is of interest to note how materials with second- and third-order nonlinear optical behavior may be improved in a diffusion-limited environment and ways in which convection may be detrimental to these materials.

Large χ(3) of squarylium dye J aggregates measured using the Z-scan technique

NASA Astrophysics Data System (ADS)

Tatsuura, Satoshi; Wada, Osamu; Tian, Minquan; Furuki, Makoto; Sato, Yasuhiro; Iwasa, Izumi; Pu, Lyong Sun; Kawashima, Hitoshi

2001-10-01

Third-order nonlinear optical coefficients χ(3) were measured for the J aggregates of two types of squarylium dye derivatives at resonant and near-resonant wavelengths by using the Z-scan technique. The maximum χ(3) value evaluated at one-photon resonance was 2.9×10-6 e.s.u., which was greater than that of phthalocyanines by 4 orders of magnitude. χ(3) for one squarylium derivative was approximately two times as large as that of the other. This can be attributed to the difference of the number of molecules contributing to a coherent state in each J aggregate.

Syntheses of Octasubstituted Metal Phthalocyanines for Nonlinear Optics

NASA Technical Reports Server (NTRS)

Guo, Huaisong; Townsend, Cheryl; Sanghadasa, Mohan; Amai, Robert L. S.; Clark, Ronald D.; Penn, Benjamin

1998-01-01

Many organic materials can be used as nonlinear optical media. Phthalocyanines are of special interest because they show an unusually large third order nonlinear response, they are thermally and photochemically stable and they can be formed into oriented thin films (Langmuir-Blodgett films). They also can be easily complexed by a large variety of metals, which place them at the interface between organics and organometallics, and allows for fine tuning of the macro cycle electronic properties by the coordinated metal and substituent groups. A series of 1,4,8,11,15,18,22,25-octaalkoxy metal-free and metal phthalocyanines and 2,3,9,10,16,17,23,24-octaalkoxy metal phthalocyanines has been synthesized. Their nonlinear optical properties have been measured. The physical properties of all the phthalocyanines synthesized in this work are subject to both acid and solvent effects.

Optical nonlinearity of D-A-π-D and D-A-π-A type of new chalcones for potential applications in optical limiting and density functional theory studies

NASA Astrophysics Data System (ADS)

Chandra Shekhara Shetty, T.; Chidan Kumar, C. S.; Gagan Patel, K. N.; Chia, Tze Shyang; Dharmaprakash, S. M.; Ramasami, Ponnadurai; Umar, Yunusa; Chandraju, Siddegowda; Quah, Ching Kheng

2017-09-01

Two new chalcones namely, (2E)-1-(3-fluoro-4-methoxyphenyl)-3-(4-methoxyphenyl) prop-2-en-1-one and (2E)-3-(4-chlorophenyl)-1-(3-fluoro-4-methoxyphenyl)prop-2-en-1-one were synthesized and grown as single crystals by slow evaporation technique in methanol. The FTIR spectrum recorded confirms the presence of functional groups in these materials. The molecular conformation of the compounds was achieved by single crystal X-ray diffraction studies. The thermal stability of the crystals was determined from TGA/DSC curve. The third order optical nonlinearity of the chalcone compounds in DMF solution has been carried out using an Nd:YAG laser at 532 nm as the source of excitation. The nonlinear optical response was characterized by measuring the intensity dependent refractive index n2 of the medium using Z-scan technique. It is seen that the molecules exhibit a negative (defocusing) nonlinearity and large nonlinear refractive index of the order of -1.8 × 10-11 esu. The third-order nonlinearity of the studied chalcones is dominated by nonlinear refraction, which leads to strong optical limiting of laser. The result reveals that these two new chalcone molecules would be a promising material for optical limiting applications. In addition, the optimized molecular geometry, vibrational frequencies in gas, and the Molecular Electrostatic Potential (MEP) surface parameters of the two molecules were calculated using DFT/B3LYP method with 6-311++G(d,p) basis set in ground state. All the theoretical calculations were found in good agreement with experimental data.

Investigations on nucleation, HRXRD, optical, piezoelectric, polarizability and Z-scan analysis of L-arginine maleate dihydrate single crystals

NASA Astrophysics Data System (ADS)

Sakthy Priya, S.; Alexandar, A.; Surendran, P.; Lakshmanan, A.; Rameshkumar, P.; Sagayaraj, P.

2017-04-01

An efficient organic nonlinear optical single crystal of L-arginine maleate dihydrate (LAMD) has been grown by slow evaporation solution technique (SEST) and slow cooling technique (SCT). The crystalline perfection of the crystal was examined using high-resolution X-ray diffractometry (HRXRD) analysis. Photoluminescence study confirmed the optical properties and defects level in the crystal lattice. Electromechanical behaviour was observed using piezoelectric co-efficient (d33) analysis. The photoconductivity analysis confirmed the negative photoconducting nature of the material. The dielectric constant and loss were measured as a function of frequency with varying temperature and vice-versa. The laser damage threshold (LDT) measurement was carried out using Nd:YAG Laser with a wavelength of 1064 nm (Focal length is 35 cm) and the obtained results showed that LDT value of the crystal is high compared to KDP crystal. The high laser damage threshold of the grown crystal makes it a potential candidate for second and higher order nonlinear optical device application. The third order nonlinear optical parameters of LAMD crystal is determined by open-aperture and closed-aperture studies using Z-scan technique. The third order linear and nonlinear optical parameters such as the nonlinear refractive index (n2), two photon absorption coefficient (β), Real part (Reχ3) and imaginary part (Imχ3) of third-order nonlinear optical susceptibility are calculated.

The influence of aggregation on the third-order nonlinear optical property of π-conjugated chromophores: the case of cyanine dyes.

PubMed

Wang, Chao; Yuan, Yizhong

2018-06-20

The external molecular environment like the aggregation of molecules can significantly change the intrinsic third-order nonlinear optical (NLO) property of π-conjugated chromophores. A combined experimental and theoretical study was performed to understand the influence of the aggregation of cyanines on the third-order NLO property in spin-coated thin films. Our result indicates that the H and J type cyanine dimers prefer the polyene-like structures and the P type dimer displays a comparatively smaller bond length alternation (BLA). The polarizable continuum model (PCM)-tuned, range-separated (RSE) density functional approach was used to describe the screening effect of the cyanine aggregation. In the thin film, the P aggregate has very small positive isotropic averaged second hyperpolarizability γ, while the J aggregate has the largest positive γ due to the most polarized face-to-tail cyanine-cyanine interaction. Hence, the γ of the isolated cyanines (negative γ) may get cancelled against that of the cyanine aggregates (positive γ) in the thin film. The forward degenerate four-wave mixing technique also confirms a decrease in the magnitude of γ with an increase in the aggregation degree of cyanines. Since the large positive γ of the cyanine also implies strong two-photon absorption (TPA), the J aggregation of cyanines can be used as a potential fabrication method for applications involving TPA.

Nonlinear optical studies on 1,3-disubstituent chalcones doped polymer films

NASA Astrophysics Data System (ADS)

Poornesh, P.; Shettigar, Seetharam; Umesh, G.; Manjunatha, K. B.; Prakash Kamath, K.; Sarojini, B. K.; Narayana, B.

2009-04-01

We report the measurements of the third-order nonlinear optical properties of recently synthesized and characterized two different 1,3-disubstituent chalcones doped PMMA films, with the prospective of reaching a good compromise between processability and high nonlinear optical properties. The measurements were done using nanosecond Z-scan at 532 nm. The Z-scan spectra reveal a large negative nonlinear refraction coefficient n2 of the order 10 -11 esu and the molecular two photon absorption cross section is 10 -46 cm 4 s/photon. The doped films exhibit good optical power limiting property under nanosecond regime and the two photon absorption (TPA) is the dominating process leading to the nonlinear behavior. The improvement in the nonlinear properties has been observed when methylenedioxy group is replaced by dimethoxy group due to increase in conjugation length. The observed nonlinear parameters of chalcone derivatives doped PMMA film is comparable with stilbazolieum derivatives, a well-known class of optical materials for photonics and biophotonics applications, which suggests that, these moieties have potential for the application of all-optical limiting and switching devices.

Recent developments in high speed lens design at the NPRL

NASA Astrophysics Data System (ADS)

McDowell, M. W.; Klee, H. W.

An account is given of recent South African developments in large aperture lens design for high speed photography that are based on the novel zero-power corrector concept. Complex multiple-element lens configurations based on such conventional optical layouts as the Petzval and double-Gauss can by the means presented be replaced with greatly simplified lens configurations employing as few as four basic elements. A tabulation is made of third-order monochromatic and first-order chromatic aberrations of the basic four-element zero-power corrector design.

Second and third order nonlinear optical properties of conjugated molecules and polymers

NASA Technical Reports Server (NTRS)

Perry, Joseph W.; Stiegman, Albert E.; Marder, Seth R.; Coulter, Daniel R.; Beratan, David N.; Brinza, David E.

1988-01-01

Second- and third-order nonlinear optical properties of some newly synthesized organic molecules and polymers are reported. Powder second-harmonic-generation efficiencies of up to 200 times urea have been realized for asymmetric donor-acceptor acetylenes. Third harmonic generation chi(3)s have been determined for a series of small conjugated molecules in solution. THG chi(3)s have also been determined for a series of soluble conjugated copolymers prepared using ring-opening metathesis polymerization. The results are discussed in terms of relevant molecular and/or macroscopic structural features of these conjugated organic materials.

Enhanced nonlinear optical properties of L-arginine stabilized gold nanoparticles embedded in PVP polymer

NASA Astrophysics Data System (ADS)

Sunatkari, A. L.; Talwatkar, S. S.; Tamgadge, Y. S.; Muley, G. G.

2018-05-01

Highly stable colloidal gold nanoparticles (GNPs) stabilised in l-arginine were synthesized and embedded in polyvinyl pyrrolidone (PVP) polymer matrix to fabricate thin films by spin coating method. Nonlinear optical response of GNP-PVP nanocomposite were investigated using single beam Z-scan technique using He-Ne laser beam in CW regime operated at 632.8 nm as an excitation source. The sign of nonlinear refractive index was found negative, which is of self-defocusing nature. The nonlinear optical parameters estimated for GNP-PVP nanocomposite and found values as large as n2≈(1.7 -3.1 ) ×10-4c m2W-1, β ≈(2.40 -4.69 ) ×10-5c m W-1 and χef f (3 )≈(2.30 -4.34 ) ×10-4e s u . The nonlinear refractive index, absorption coefficient and third order nonlinear susceptibility have found decreasing with the increase in the concentration of l-arginine. Localized surface plasmon resonance (LSPR) peaks show the blue shift. The average size of the GNPs is found reducing from 11 nm to 7.5 nm with the increase in the stabilizer concentration, as analysed by transmission electron microscopy. The XRD study reveals face-centred cubic (fcc) structure of GNPs. The huge nonlinearity is attributed to the thermo-optic phenomenon. The huge enhancement in third order nonlinear susceptibility and nonlinear refractive index indicates that this optical material possess a high potential for various optoelectronic devices applications.

Dispersion dependence of second-order refractive index and complex third-order optical susceptibility in oxide glasses

NASA Astrophysics Data System (ADS)

Abdel Wahab, F. A.; El-Diasty, Fouad; Abdel-Baki, Manal

2009-10-01

A method correlates Fresnel-based spectrophotometric measurements and Lorentz dispersion theory is presented to study the dispersion of nonlinear optical parameters in particularly oxide glasses in a very wide range of angular frequency. The second-order refractive index and third-order optical susceptibility of Cr-doped glasses are determined from linear refractive index. Furthermore, both real and imaginary components of the complex susceptibility are carried out. The study reveals the importance of determining the dispersion of nonlinear absorption (two-photon absorption coefficient) to find the maximum resonant and nonresonant susceptibilities of investigated glasses. The present method is applied on Cr-doped lithium aluminum silicate (LAS) glasses due to their semiconductor-like behavior and also to their application in laser industry.

Green synthesis and third-order nonlinear optical properties of 6-(9H-carbazol-9-yl) hexyl acetate

NASA Astrophysics Data System (ADS)

Chen, Baili; Geng, Feng; Luo, Xuan; Zhong, Quanjie; Zhang, Qingjun; Fang, Yu; Huang, Chuanqun; Yang, Ruizhuang; Shao, Ting; Chen, Shufan

2016-10-01

An extremely simple and green approach for the synthesis of photoelectric material 6-(9H-carbazol-9-yl) hexy-acetate (CHA) has been described in detail. The molecular structure of CHA was identified with Fourier transform infrared (FT-IR) spectra and 1H Nuclear Magnetic Resonance (1H NMR) spectroscopy. The optical absorption of CHA was recorded using ultraviolet-visible (UV-vis) spectrum. Notably, the reaction was accomplished in water medium instead of traditional toxic solvents (e.g., benzene and chloroform). The yield of CHA is up to 99%, which is increased by 13% compared with the traditional method. The approach developed by us makes it possible to achieve commercial production of CHA. Moreover, the thermal stability of CHA was studied with thermogravimetric (TG) and derivative thermogravimetric (DTG) method. The third-order nonlinear optical (NLO) properties of CHAn (obtained by new method) and CHAt (obtained by traditional method) have been studied by a Z-scan technique at 440 nm. The thermal decomposition temperature is above 200 °C. The third-order NLO of CHAn and CHAt are the same. The third-order NLO susceptibility χ (3) and two photon Figures of Merit (FOMs) of CHA are 1.58 × 10-8 (esu) and 4.55, respectively. The results reveal that CHA may be a promising candidate for all-optical switching application.

Studies on third-order optical nonlinearity and power limiting of conducting polymers using the z-scan technique for nonlinear optical applications

NASA Astrophysics Data System (ADS)

Pramodini, S.; Sudhakar, Y. N.; SelvaKumar, M.; Poornesh, P.

2014-04-01

We present the synthesis and characterization of third-order optical nonlinearity and optical limiting of the conducting polymers poly (aniline-co-o-anisidine) and poly (aniline-co-pyrrole). Nonlinear optical studies were carried out by employing the z-scan technique using a He-Ne laser operating in continuous wave mode at 633 nm. The copolymers exhibited a reverse saturable absorption process and self-defocusing properties under the experimental conditions. The estimated values of βeff, n2 and χ(3) were found to be of the order of 10-2 cm W-1, 10-5 esu and 10-7 esu respectively. Self-diffraction rings were observed due to refractive index change when exposed to the laser beam. The copolymers possess a lower limiting threshold and clamping level, which is essential to a great extent for power limiting devices. Therefore, copolymers of aniline emerge as a potential candidate for nonlinear optical device applications.

Efficient optical nonlinear Langmuir-Blodgett films: roles of matrix molecules

NASA Astrophysics Data System (ADS)

Ma, Shihong; Lu, Xingze; Liu, Liying; Han, Kui; Wang, Wencheng; Zhang, Zhi-Ming

1996-10-01

A novel bifat-chain amphiphilic molecule nitrogencrown (NC) was adopted as an inert material for fabrication of optical nonlinear Langmuir-Blodgett (LB) multilayers. Structural improvement in the Z-type mixed fullerene derivative (C60-Be)/NC LB multilayers samples was realized by insertion of the C60-Be molecules between two hydrophobic chains of the NC molecules. The relatively large third-order susceptibility (chi) (3)xxxx(- 3(omega) ;(omega) ,(omega) ,(omega) ) equals 2.9 multiplied by 10-19 M2V-2 (or 2.1 multiplied by 10-11 esu) was deduced by measuring third harmonic generation (THG) from the C60-Be samples. The second harmonic generation (SHG) intensity increased quadratically with the bilayer number (up to 116 bilayers) in Y-type hemicyanine (HEM)/NC interleaving LB multilayers due to improvement of the structural properties by insertion of the long hydrophobic tail of HEM molecules between two chains of NC molecules. The second-order susceptibility (chi) (2)zxx(-2(omega) ;(omega) ,(omega) ) equals 18 pM V-1 (or 4.35 multiplied by 10-8 esu) was obtained by measuring SHG from the HEM samples. The NC molecule has attractive features as a matrix material in fabrications of LB multilayers made from optically nonlinear materials with hydrophobic long tails or ball-like molecules.

Enhanced third-order nonlinear optical properties determined in thin films using the Z-scan technique: bis(μ-4,4'-oxydibenzoato)bis[(4'-phenyl-2,2':6',2''-terpyridine)cobalt(II)].

PubMed

Liu, Runqiang; Zhao, Ning; Liu, Ping; An, Caixia; Lian, Zhaoxun

2016-05-01

π-Conjugated organic materials exhibit high and tunable nonlinear optical (NLO) properties, and fast response times. 4'-Phenyl-2,2':6',2''-terpyridine (PTP) is an important N-heterocyclic ligand involving π-conjugated systems, however, studies concerning the third-order NLO properties of terpyridine transition metal complexes are limited. The title binuclear terpyridine Co(II) complex, bis(μ-4,4'-oxydibenzoato)-κ(3)O,O':O'';κ(3)O'':O,O'-bis[(4'-phenyl-2,2':6',2''-terpyridine-κ(3)N,N',N'')cobalt(II)], [Co2(C14H8O5)2(C21H15N3)2], (1), has been synthesized under hydrothermal conditions. In the crystal structure, each Co(II) cation is surrounded by three N atoms of a PTP ligand and three O atoms, two from a bidentate and one from a symmetry-related monodentate 4,4'-oxydibenzoate (ODA(2-)) ligand, completing a distorted octahedral coordination geometry. Neighbouring [Co(PTP)](2+) units are bridged by ODA(2-) ligands to form a ring-like structure. The third-order nonlinear optical (NLO) properties of (1) and PTP were determined in thin films using the Z-scan technique. The title compound shows a strong third-order NLO saturable absorption (SA), while PTP exhibits a third-order NLO reverse saturable absorption (RSA). The absorptive coefficient β of (1) is -37.3 × 10(-7) m W(-1), which is larger than that (8.96 × 10(-7) m W(-1)) of PTP. The third-order NLO susceptibility χ((3)) values are calculated as 6.01 × 10(-8) e.s.u. for (1) and 1.44 × 10(-8) e.s.u. for PTP.

Computer program for optical systems ray tracing

NASA Technical Reports Server (NTRS)

Ferguson, T. J.; Konn, H.

1967-01-01

Program traces rays of light through optical systems consisting of up to 65 different optical surfaces and computes the aberrations. For design purposes, paraxial tracings with astigmation and third order tracings are provided.

Structure Effect of Squarylium Cyanine Dyes on Third-Order Optical Nonlinearities in Ground and Excited States

NASA Astrophysics Data System (ADS)

Liu, Xu-chun; Xu, Gang; Si, Jin-hai; Ye, Pei-xian; Lin, Tong; Peng, Bi-xian

1999-08-01

A series of squarylium cyanine dyes with different substituents were synthesized and the third-order optical nonlinearities of their ground and excited states were investigated by backward degenerate four-wave-mixing. For the ground state, the molecular hyperpolarizability γg increases with the red-shift of the absorption peak λmaxab of the squaraine with different substituents, whereas for the excited-state molecular hyperpolarizability γe, the nonlinear enhancement γe/γg decreases, which may indicate that in the excited state the electron accepting-donating ability of different substituents changes in the reverse order compared with the order in the ground state.

Detecting a pronounced delocalized state in third-harmonic generation phenomenon; a quantum chaos approach

NASA Astrophysics Data System (ADS)

Behnia, S.; Ziaei, J.; Khodavirdizadeh, M.

2018-06-01

Nonlinear optics (NLO) deserves special attention in new optical devices, making it possible to generate coherent light more efficiently. Among the various NLO phenomena the third-harmonic generation (THG) is at the core of the effective operating mechanism of broadband wavelength conversion, in all-optical devices. Here, we aim to understand how the third-order susceptibility and the electric field may be effectively effect on the localization properties of the light in the THG process when included in a two-mode cavity coherently perturbed by a classical field. We address a stable-unstable transition due to the combination effect of the aforementioned factors. We report a reliable evidence confirming the appearance of chaos in THG under suitable conditions. By tracing the signatures of adjacent-spectral-spacing-ratio (ASSR) distribution and participation ratio, we also find a critical point (ɛc ,κc) =(3 . 1 , 0 . 35) for which a pronounced delocalized response is seen. This study may have profound findings for practical devices, and ushers in new opportunities for practical exploitation of the electric field and the third-order susceptibility effect in nonlinear optical devices.

Synthesis of stable ZnO nanocolloids with enhanced optical limiting properties via simple solution method

NASA Astrophysics Data System (ADS)

Ramya, M.; Nideep, T. K.; Vijesh, K. R.; Nampoori, V. P. N.; Kailasnath, M.

2018-07-01

In present work, we report the synthesis of stable ZnO nanocolloids through a simple solution method which exhibit enhanced optical limiting threshold. The influences of reaction temperature on the crystal structure as well as linear and nonlinear optical properties of prepared ZnO nanoparticles were carried out. The XRD and Raman analysis reveal that the prepared ZnO nanoparticles retain the hexagonal wurtzite crystal structure. HRTEM analysis confirms the effect of reaction temperature, solvent effect on crystallinity as well as nanostructure of ZnO nanoparticles. It has been found that crystallinity and average diameter increase with reaction temperature where ethylene glycol act as both solvent and growth inhibiter. EDS spectra shows formation of pure ZnO nanoparticles. The direct energy band gap of the nanoparticles increases with decrease in particle size due to quantum confinement effect. The third order nonlinear optical properties of ZnO nanoparticles were investigated by z scan technique using a frequency doubled Nd-YAG nanosecond laser at 532 nm wavelength. The z-scan result reveals that the prepared ZnO nanoparticles exhibit self - defocusing nonlinearity. The two photon absorption coefficient and third - order nonlinear optical susceptibility increases with increasing particle size. The third-order susceptibility of the ZnO nanoparticles is found to be in the order of 10-10 esu, which is at least three order magnitude greater than the bulk ZnO. The optical limiting threshold of the nanoparticles varies in the range of 54 to 17 MW/cm2. The results suggest that ZnO nanoparticles considered as a promising candidates for the future photonic devices.

Third order nonlinearity in pulsed laser deposited LiNbO{sub 3} thin films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tumuluri, Anil; Rapolu, Mounika; Rao, S. Venugopal, E-mail: kcjrsp@uohyd.ernet.in, E-mail: svrsp@uohyd.ernet.in

2016-05-06

Lithium niobate (LiNbO{sub 3}) thin films were prepared using pulsed laser deposition technique. Structural properties of the same were examined from XRD and optical band gap of the thin films were measured from transmittance spectra recorded using UV-Visible spectrophotometer. Nonlinear optical properties of the thin films were recorded using Z-Scan technique. The films were exhibiting third order nonlinearity and their corresponding two photon absorption, nonlinear refractive index, real and imaginary part of nonlinear susceptibility were calculated from open aperture and closed aperture transmission curves. From these studies, it suggests that these films have potential applications in nonlinear optical devices.

Ultrafast frequency-selective optical switching based on thin self-assembled organic chromophoric films with a large second-order nonlinear response

NASA Astrophysics Data System (ADS)

Wang, Gang; Zhu, Peiwang; Marks, Tobin J.; Ketterson, J. B.

2002-09-01

Thin films consisting of self-assembled chromophoric superlattices exhibit very large second-order nonlinear responses [chi](2). Using such films, a "static" diffraction grating is created by the interference of two coherent infrared beams from a pulsed yttritium-aluminum-garnet laser. This grating is used to switch the second-harmonic and third-harmonic "signal" beams (generated from the fundamental "pump" beam or mixed within the chromophoric superlattice) into different channels (directions). Ultrafast switching response as a function of the time overlap of the pumping beams is demonstrated. It is suggested that such devices can be used to spatially and temporally separate signal trains consisting of pulses having different frequencies and arrival times.

Characterization of the third-order optical nonlinearity spectrum of barium borate glasses

NASA Astrophysics Data System (ADS)

Santos, S. N. C.; Almeida, J. M. P.; Paula, K. T.; Tomazio, N. B.; Mastelaro, V. R.; Mendonça, C. R.

2017-11-01

Borate glasses have proven to be an important material for applications ranging from radiation dosimetry to nonlinear optics. In particular, B2O3-BaO based glasses are attractive to frequency generation since their barium metaborate phase (β-BaB2O4 or β-BBO) may be crystallized under proper heat treatment. Despite the vast literature covering their linear and second-order optical nonlinear properties, their third-order nonlinearities remain overlooked. This paper thus reports a study on the nonlinear refraction (n2) of BBO and BBS-DyEu glasses through femtosecond Z-scan technique. The results were modeled using the BGO approach, which showed that oxygen ions are playing a role in the nonlinear optical properties of the glasses studied here. In addition, the barium borate glasses containing rare-earths ions were found to exhibit larger nonlinearities, which is in agreement with previous studies.

Direct dry transfer of CVD graphene to an optical substrate by in situ photo-polymerization

NASA Astrophysics Data System (ADS)

Kessler, Felipe; Muñoz, Pablo A. R.; Phelan, Ciaran; Romani, Eric C.; Larrudé, Dunieskys R. G.; Freire, Fernando L.; Thoroh de Souza, Eunézio A.; de Matos, Christiano J. S.; Fechine, Guilhermino J. M.

2018-05-01

Here, we report on a method that allows graphene produced by chemical vapor deposition (CVD) to be directly transferred to an optically transparent photo resin, by in situ photo-polymerization of the latter, with high efficiency and low contamination. Two photocurable resins, A and B, with different viscosities but essentially the same chemical structure, were used. Raman spectroscopy and surface energy results show that large continuous areas of graphene were transferred with minimal defects to the lower viscosity resin (B), due to the better contact between the resin and graphene. As a proof-of-principle optical experiment, graphene on the polymeric substrate was subjected to high-intensity femtosecond infrared pulses and third-harmonic generation was observed with no noticeable degradation of the sample. A sheet third-order susceptibility χ (3) = 0.71 ×10-28m3V-2 was obtained, matching that of graphene on a glass substrate. These results indicate the suitability of the proposed transfer method, and of the photo resin, for the production of nonlinear photonic components and devices.

All-optical tunable dual Fano resonance in nonlinear metamaterials in optical communication range

NASA Astrophysics Data System (ADS)

Zhou, Yi; Hu, Xiaoyong; Li, Chong; Yang, Hong; Gong, Qihuang

2018-01-01

Low-power, ultra-fast all-optical tunable dual Fano resonance was realized in a metamaterial coated with a non-linear nanocomposite layer composed of gold nanoparticle-doped polycrystalline barium strontium titanate and multilayer tungsten disulphide microsheets. A high non-linear refractive index of -2.148 × 10-11 m2/W was achieved in the nanocomposite material that originated in the non-linearity enhancement associated with the quantum confinement effect, the local-field enhancement effect, and reinforced interactions between photons and the multilayer tungsten disulphide microsheets. An ultra-low threshold pump intensity of 600 kW/cm2 was obtained. An ultra-fast response time of 25.4 ps was maintained because of the fast relaxation dynamics of the bound electrons in the nanoscale polycrystalline barium strontium titanate grains. The large third-order non-linear responses of the metamaterial were confirmed with a high third harmonic generation conversion efficiency of 5.4 × 10-5. This work may help to pave the way towards realization of ultra-high-speed information processing chips and multifunctional integrated photonic devices based on metamaterials.

Enabling the detection of UV signal in multimodal nonlinear microscopy with catalogue lens components.

PubMed

Vogel, Martin; Wingert, Axel; Fink, Rainer H A; Hagl, Christian; Ganikhanov, Feruz; Pfeffer, Christian P

2015-10-01

Using an optical system made from fused silica catalogue optical components, third-order nonlinear microscopy has been enabled on conventional Ti:sapphire laser-based multiphoton microscopy setups. The optical system is designed using two lens groups with straightforward adaptation to other microscope stands when one of the lens groups is exchanged. Within the theoretical design, the optical system collects and transmits light with wavelengths between the near ultraviolet and the near infrared from an object field of at least 1 mm in diameter within a resulting numerical aperture of up to 0.56. The numerical aperture can be controlled with a variable aperture stop between the two lens groups of the condenser. We demonstrate this new detection capability in third harmonic generation imaging experiments at the harmonic wavelength of ∼300 nm and in multimodal nonlinear optical imaging experiments using third-order sum frequency generation and coherent anti-Stokes Raman scattering microscopy so that the wavelengths of the detected signals range from ∼300 nm to ∼660 nm. © 2015 The Authors Journal of Microscopy © 2015 Royal Microscopical Society.

Silicon optical modulators for optical digital and analog communications (Conference Presentation)

NASA Astrophysics Data System (ADS)

Yang, Lin; Ding, Jianfeng; Zhang, Lei; Shao, Sizu

2017-02-01

Silicon photonics is considered as a promising technology to overcome the difficulties of the existing digital and analog optical communication systems, such as low integration, high cost, and high power consumption. Silicon optical modulator, as a component to transfer data from electronic domain to optical one, has attracted extensive attentions in the past decade. In this paper, we review the statuses of the silicon optical modulators for digital and analog optical communications and introduce our efforts on these topics. We analyze the relationship between the performance and the structural parameters of the silicon optical modulator and present how to optimize its performance including electro-optical bandwidth, modulation efficiency, optical bandwidth and insertion loss. The fabricated silicon optical modulator has an electro-optical bandwidth of 30 GHz. Its extinction ratios are 14.0 dB, 11.2 dB and 9.0 dB at the speeds of 40 Gbps, 50 Gbps and 64 Gbps for OOK modulation. The high extinction ratio of the silicon optical modulator at the high speed makes it very appropriate for the application of optical coherent modulation, such as QPSK and 16-QAM. The fabricated silicon optical modulator also can be utilized for analog optical communication. With respect to a noise floor of -165 dBc, the dynamic ranges for the second-order harmonic and the third-order intermodulation distortion are 90.8 dB and 110.5 dB respectively. By adopting a differential driving structure, the dynamic range for the second-order harmonic can be further improved to 100.0 dB while the third-order intermodulation distortion remains the same level.

Nonlinear silicon photonics

NASA Astrophysics Data System (ADS)

Tsia, Kevin K.; Jalali, Bahram

2010-05-01

An intriguing optical property of silicon is that it exhibits a large third-order optical nonlinearity, with orders-ofmagnitude larger than that of silica glass in the telecommunication band. This allows efficient nonlinear optical interaction at relatively low power levels in a small footprint. Indeed, we have witnessed a stunning progress in harnessing the Raman and Kerr effects in silicon as the mechanisms for enabling chip-scale optical amplification, lasing, and wavelength conversion - functions that until recently were perceived to be beyond the reach of silicon. With all the continuous efforts developing novel techniques, nonlinear silicon photonics is expected to be able to reach even beyond the prior achievements. Instead of providing a comprehensive overview of this field, this manuscript highlights a number of new branches of nonlinear silicon photonics, which have not been fully recognized in the past. In particular, they are two-photon photovoltaic effect, mid-wave infrared (MWIR) silicon photonics, broadband Raman effects, inverse Raman scattering, and periodically-poled silicon (PePSi). These novel effects and techniques could create a new paradigm for silicon photonics and extend its utility beyond the traditionally anticipated applications.

Soliton's eigenvalue based analysis on the generation mechanism of rogue wave phenomenon in optical fibers exhibiting weak third order dispersion.

PubMed

Weerasekara, Gihan; Tokunaga, Akihiro; Terauchi, Hiroki; Eberhard, Marc; Maruta, Akihiro

2015-01-12

One of the extraordinary aspects of nonlinear wave evolution which has been observed as the spontaneous occurrence of astonishing and statistically extraordinary amplitude wave is called rogue wave. We show that the eigenvalues of the associated equation of nonlinear Schrödinger equation are almost constant in the vicinity of rogue wave and we validate that optical rogue waves are formed by the collision between quasi-solitons in anomalous dispersion fiber exhibiting weak third order dispersion.

Advanced Instrumentation for Aero Engine Components: Conference Proceedings of the Propulsion and Energetics Panel Symposium (67th) Held in Philadelphia, Pennsylvania on 19-23 May 1986.

DTIC Science & Technology

1986-11-01

optical wave-mixing am., interact via the third order non linear susceptibility of the medium to produce a coherent laser-like signal beam at the higher...is the third order non- linear susceptibility of the medium and determines the shape of the CARS spectrum. It is the sum of a resonant contribution and...simultaneously using an appropriate spectrograph/optical multichannel detector; intensified linear diode array detectors are now used in most systems. The two

Studies on the growth aspects, structural, thermal, dielectric and third order nonlinear optical properties of solution grown 4-methylpyridinium p-nitrophenolate single crystal

NASA Astrophysics Data System (ADS)

Devi, S. Reena; Kalaiyarasi, S.; Zahid, I. MD.; Kumar, R. Mohan

2016-11-01

An ionic organic optical crystal of 4-methylpyridinium p-nitrophenolate was grown from methanol by slow evaporation method at ambient temperature. Powder and single crystal X-ray diffraction studies revealed the crystal system and its crystalline perfection. The rocking curve recorded from HRXRD study confirmed the crystal quality. FTIR spectral analysis confirmed the functional groups present in the title compound. UV-visible spectral study revealed the optical window and band gap of grown crystal. The thermal, electrical and surface laser damage threshold properties of harvested crystal were examined by using TGA/DTA, LCR/Impedance Analyzer and Nd:YAG laser system respectively. The third order nonlinear optical property of grown crystal was elucidated by Z-scan technique.

Theoretical study on the spectroscopic and third-order nonlinear optical properties of two-dimensional charge-transfer pyrazine derivatives

NASA Astrophysics Data System (ADS)

Li, Haipeng; Zhang, Yi; Bi, Zetong; Xu, Runfeng; Li, Mingxue; Shen, Xiaopeng; Tang, Gang; Han, Kui

2017-12-01

In this paper, density functional theory method was employed to study the electronic absorption spectrum and electronic static second hyperpolarisability of X-shaped pyrazine derivatives with two-dimensional charge-transfer structures. Computational results show that the push-pull electron abilities of the substituent groups and the length of the conjugated chains affect the electronic spectrum and static second hyperpolarisability of the pyrazine derivatives. As the push-pull electron abilities of the substituent groups or the length of the conjugated chains increases, the frontier molecular orbital energy gap decreases, resulting in increased second hyperpolarisability and redshift of the electronic absorption bands. The electronic absorption spectra of the pyrazine derivatives maintain good transparency in the blue light band. The electronic static second hyperpolarisability exhibits a linear relationship to the frontier molecular orbital energy gap. Particularly, increasing/decreasing the push-pull electron abilities of the substituent groups considerably affect the static second hyperpolarisability in long conjugated systems, which is important to the modulation of molecular organic nonlinear optical (NLO) properties. The studied pyrazine derivatives show large third-order NLO response and good transparency in the blue light band and are thus promising candidates as NLO materials for photonics applications.

Influence of electron beam irradiation on nonlinear optical properties of Al doped ZnO thin films for optoelectronic device applications in the cw laser regime

NASA Astrophysics Data System (ADS)

Antony, Albin; Pramodini, S.; Poornesh, P.; Kityk, I. V.; Fedorchuk, A. O.; Sanjeev, Ganesh

2016-12-01

We present the studies on third-order nonlinear optical properties of Al doped ZnO thin films irradiated with electron beam at different dose rate. Al doped ZnO thin films were deposited on a glass substrate by spray pyrolysis deposition technique. The thin films were irradiated using the 8 MeV electron beam from microtron ranging from 1 kG y to 5 kG y. Nonlinear optical studies were carried out by employing the single beam Z-scan technique to determine the sign and magnitude of absorptive and refractive nonlinearities of the irradiated thin films. Continuous wave He-Ne laser operating at 633 nm was used as source of excitation. The open aperture Z-scan measurements indicated the sample displays reverse saturable absorption (RSA) process. The negative sign of the nonlinear refractive index n2 was noted from the closed aperture Z-scan measurements indicates, the films exhibit self-defocusing property due to thermal nonlinearity. The third-order nonlinear optical susceptibility χ(3) varies from 8.17 × 10-5 esu to 1.39 × 10-3 esu with increase in electron beam irradiation. The present study reveals that the irradiation of electron beam leads to significant changes in the third-order optical nonlinearity. Al doped ZnO displays good optical power handling capability with optical clamping of about ∼5 mW. The irradiation study endorses that the Al doped ZnO under investigation is a promising candidate photonic device applications such as all-optical power limiting.

Optical Kerr effect in graphene: Theoretical analysis of the optical heterodyne detection technique

NASA Astrophysics Data System (ADS)

Savostianova, N. A.; Mikhailov, S. A.

2018-04-01

Graphene is an atomically thin two-dimensional material demonstrating strong optical nonlinearities, including harmonics generation, four-wave mixing, Kerr, and other nonlinear effects. In this paper we theoretically analyze the optical heterodyne detection (OHD) technique of measuring the optical Kerr effect (OKE) in two-dimensional crystals and show how to relate the quantities measured in such experiments with components of the third-order conductivity tensor σαβ γ δ (3 )(ω1,ω2,ω3) of the two-dimensional crystal. Using results of a recently developed quantum theory of the third-order nonlinear electrodynamic response of graphene, we analyze the frequency, charge carrier density, temperature, and other dependencies of the OHD-OKE response of this material. We compare our results with a recent OHD-OKE experiment in graphene and find good agreement between the theory and experiment.

Third order nonlinear optical properties of Mn doped CeO2 nanostructures

NASA Astrophysics Data System (ADS)

Mani Rahulan, K.; Angeline Little Flower, N.; Annie Sujatha, R.; Mohana Priya, P.; Gopalakrishnan, C.

2018-05-01

Mn doped CeO2 nanoparticles with different ratios of Mn were synthesized by hydrothermal method and their structural properties were characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and Scanning electron microscopy (SEM). XRD patterns revealed that the peaks are highly crystalline structure with no segregation of Mn. The surface morphology from SEM reveals that particle size decreases with increase in Mn concentration. Nonlinear optical studies of the samples were measured by single-beam open aperture Z-scan technique using 5 ns laser pulses at 532 nm. The measured optical nonlinearity of all the samples exhibit typical third order nonlinear optical behavior including two-photon absorption (2 PA) and reverse saturable absorption (RSA). The experimental results show that the presence of RSA in these nanoparticles makes them a promising material for the fabrication of optical limiting devices. .

Resonant third-order optical nonlinearities of thin films containing J-aggregates of a cyanine dye or a squarylium dye

NASA Astrophysics Data System (ADS)

Li, Zhongyu; Jin, Zhaohui; Kasatani, Kazuo

2005-01-01

The third-order optical nonlinearities and responses of thin films containing the J-aggregates of a cyanine dye or a squarylium dye were measured using the degenerate four-wave mixing (DFWM) technique under resonant conditions. The sol-gel silica coating films containing the J-aggregates of the cyanine dye, NK-3261, are stable at room temperature and durable against laser beam irradiation. The temporal profiles of the DFWM signal were measured with a time resolution of 0.3 ps, and were found to consist of at least three components, i.e., the coherent instantaneous nonlinear response and the two slow responses with delay time constants of ca. 1.0 ps and ca. 5.6 ps. The contribution of the later was small. The electronic component of the effective third-order optical nonlinear susceptibility of the film had value of as high as ca. 3.0 x 10-7 esu. We also studied the neat film of a squarylium dye J-aggregates. The temporal profile of the DFWM signal of the neat film of squarylium dye was also found to consist of at least three components, the coherent instantaneous nonlinear response and the delayed response with decay time constants of ca. 0.6 ps and ca. 6.5 ps. The contribution of the slow tail was also very small. The electronic component of effective third-order optical nonlinear susceptibility of the neat film of squarylium dye had value of as high as ca. 3.6 x 10-8 esu.

Nonlinear Optical Spectroscopy of Two-Dimensional Materials

NASA Astrophysics Data System (ADS)

Cui, Qiannan

Nonlinear optical properties of two-dimensional (2D) materials, such as transition metal dichalcogenides (TMDs), graphene, black phosphorus, and so on, play a key role of understanding nanoscale light-matter interactions, as well as developing nanophotonics applications from solar cells to quantum computation. With ultrafast lasers, we experimentally study nonlinear optical properties of 2D materials. Employing transient absorption microscopy, we study several members of 2D materials, such as WSe2, TiS3 and ReS2. The dynamical saturable absorption process of 2D excitons is spatiotemporally resolved. Intrinsic parameters of these 2D materials, such as exciton lifetime, exciton diffusion coefficient, and exciton mobility, are effectively measured. Especially, in-plane anisotropy of transient absorption and diffusive transport is observed for 2D excitons in monolayer ReS2, demonstrating the in-plane degree of freedom. Furthermore, with quantum interference and control nanoscopy, we all-optically inject, detect and manipulate nanoscale ballistic charge currents in a ReS2 thin film. By tuning the phase difference between one photon absorption and two photon absorption transition paths, sub-picosecond timescale of ballistic currents is coherently controlled for the first time in TMDs. In addition, the spatial resolution is two-order of magnitude smaller than optical diffraction limit. The second-order optical nonlinearity of 2D monolayers is resolved by second harmonic generation (SHG) microscopy. We measure the second-order susceptibility of monolayer MoS 2. The angular dependence of SHG in monolayer MoS2 shows strong symmetry dependence on its crystal lattice structure. Hence, second harmonic generation microscopy can serve as a powerful tool to noninvasively determine the crystalline directions of 2D monolayers. The real and imaginary parts of third-order optical nonlinearity of 2D monolayers are resolved by third harmonic generation (THG) microscopy and two-photon transient absorption microscopy, respectively. With third harmonic generation microscopy, we observe strong and anisotropic THG in monolayer and multilayer ReS2. Comparing with 2D materials with hexagonal lattice, such as MoS2, the third-order susceptibility is higher by one order of magnitude in ReS2 with a distorted 1T structure. The in-plane anisotropy of THG is attributed to the lattice distortion in ReS2 after comparing with a symmetry analysis. With two-photon transient absorption microscopy, we observe a giant two-photon absorption coefficient of monolayer WS2.

Optical, structural and nonlinear optical properties of laser ablation synthesized Ag nanoparticles and photopolymer nanocomposites based on them

NASA Astrophysics Data System (ADS)

Zulina, Natalia A.; Pavlovetc, Ilia M.; Baranov, Mikhail A.; Denisyuk, Igor Yu.

2017-03-01

In this work Ag nanoparticles (NPs) stable colloid solution were prepared by laser ablation of chemically pure silver rod in liquid monomer isodecyl acrylate (IDA). Sizes of obtained nanoparticles were determined by scanning electron microscope and vary from 27 to 120 nm. Nanocomposites films were prepared from obtained stable colloid solution of AgNPs by photocuring. For aliphatic polymer IDA long molecules cross-linking Diurethane dimethacrylate, 1,6-Hexandiol diacrylate and Tetra (ethylene glycol) diacrylate were used. Prepared nanomaterials exhibit strong third-order nonlinear optical responses, which was estimated by using z-scan technique. The third-order nonlinear optical coefficients of the studied nanocomposites were found to be up to Reχ(3)=1.31×10-5 (esu) and Imχ(3)=7.64×10-5 (esu).

Preserving Simplecticity in the Numerical Integration of Linear Beam Optics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Allen, Christopher K.

2017-07-01

Presented are mathematical tools and methods for the development of numerical integration techniques that preserve the symplectic condition inherent to mechanics. The intended audience is for beam physicists with backgrounds in numerical modeling and simulation with particular attention to beam optics applications. The paper focuses on Lie methods that are inherently symplectic regardless of the integration accuracy order. Section 2 provides the mathematically tools used in the sequel and necessary for the reader to extend the covered techniques. Section 3 places those tools in the context of charged-particle beam optics; in particular linear beam optics is presented in terms ofmore » a Lie algebraic matrix representation. Section 4 presents numerical stepping techniques with particular emphasis on a third-order leapfrog method. Section 5 discusses the modeling of field imperfections with particular attention to the fringe fields of quadrupole focusing magnets. The direct computation of a third order transfer matrix for a fringe field is shown.« less

Optical nonlinearity in gelatin layer film containing Au nanoparticles

NASA Astrophysics Data System (ADS)

Hirose, Tomohiro; Arisawa, Michiko; Omatsu, Takashige; Kuge, Ken'ichi; Hasegawa, Akira; Tateda, Mitsuhiro

2002-09-01

We demonstrate a novel technique to fabricate a gelatin film containing Au-nano-particles. The technique is based on silver halide photographic development. We investigated third-order non-linearity of the film by forward-four-wave-mixing technique. Peak absorption appeared at the wavelength of 560nm. Self-diffraction by the use of third order nonlinear grating formed by intense pico-second pulses was observed. Experimental diffraction efficiency was proportional to the square of the pump intensity. Third-order susceptibility c(3) of the film was estimated to be 1.8?~10^-7esu.

Cavity-dumped femtosecond optical parametric oscillator based on periodically poled stoichiometric lithium tantalate

NASA Astrophysics Data System (ADS)

Yoon, E.; Joo, T.

2016-03-01

A synchronously pumped cavity-dumped femtosecond optical parametric oscillator (OPO) based on a periodically poled stoichiometric lithium tantalate (PPSLT) crystal is reported. The OPO runs in positive group velocity dispersion (GVD) mode to deliver high pulse energy at high repetition rate. It delivers pulse energy over 130 nJ up to 500 kHz and 70 nJ at 1 MHz of repetition rate at 1100 nm. Pulse duration is as short as 42 fs, and the OPO is tunable in the near infrared region from 1050 to 1200 nm. Dispersion property of the OPO was also explored. The cavity-dumped output carries a positive GVD, which can be compensated easily by an external prism pair, and large negative third order dispersion (TOD), which results in a pedestal in the pulse shape. Approaches to obtain clean pulse shape by reducing the large TOD are proposed.

Investigation of third-order nonlinear and optical power limiting properties of terphenyl derivatives

NASA Astrophysics Data System (ADS)

Kamath, Laxminarayana; Manjunatha, K. B.; Shettigar, Seetharam; Umesh, G.; Narayana, B.; Samshuddin, S.; Sarojini, B. K.

2014-03-01

A series of new chalcones containing terphenyl as a core and with different functional groups has been successfully synthesized by Claisen-Schmidt condensation method in search of new nonlinear optical (NLO) materials. Molecular structural characterization for the compounds was achieved by FTIR and single crystal X-ray diffraction. The third-order NLO absorption and refraction coefficients were simultaneously determined by Z-scan technique. The measurements were performed at 532 nm with 7 ns laser pulses using a Nd:YAG laser in solution form. The Z-scan experiments reveal that the compounds exhibit strong nonlinear refraction coefficient of the order 10-11 esu and the molecular two photon absorption cross section is 10-46 cm4 s/photon. The results also show that the structures of the compounds have great impact on NLO properties. The compounds show optical power limiting behavior due to two-photon absorption (TPA).

Synthesis, Hirshfeld surface analysis, laser damage threshold, third-order nonlinear optical property and DFT computation studies of Dichlorobis(DL-valine)zinc(II): A spectroscopic approach

NASA Astrophysics Data System (ADS)

Chitrambalam, S.; Manimaran, D.; Hubert Joe, I.; Rastogi, V. K.; Ul Hassan, Israr

2018-01-01

The organometallic crystal of Dichlorobis(DL-valine)zinc(II) was grown by solution growth method. The computed structural geometry, vibrational wavenumbers and UV-visible spectra were compared with experimental results. Hirshfeld surface map was used to locate electron density and the fingerprint plots percentages are responsible for the stabilization of intermolecular interactions in molecular crystal. The second-order hyperpolarizability value of the molecule was also calculated at density functional theory method. The surface resistance and third-order nonlinear optical property of the crystal were studied by laser induced surface damage threshold and Z-scan techniques, respectively using Nd:YAG laser with wavelength 532 nm. The open aperture result exhibits the reverse saturation absorption, which indicate that this material has potential candidate for optical limiting and optoelectronic applications.

A physical optics/equivalent currents model for the RCS of trihedral corner reflectors

NASA Technical Reports Server (NTRS)

Balanis, Constantine A.; Polycarpou, Anastasis C.

1993-01-01

The scattering in the interior regions of both square and triangular trihedral corner reflectors is examined. The theoretical model presented combines geometrical and physical optics (GO and PO), used to account for reflection terms, with equivalent edge currents (EEC), used to account for first-order diffractions from the edges. First-order, second-order, and third-order reflection terms are included. Calculating the first-order reflection terms involves integrating over the entire surface of the illuminated plate. Calculating the second- and third-order reflection terms, however, is much more difficult because the illuminated area is an arbitrary polygon whose shape is dependent upon the incident angles. The method for determining the area of integration is detailed. Extensive comparisons between the high-frequency model, Finite-Difference Time-Domain (FDTD) and experimental data are used for validation of the radar cross section (RCS) of both square and triangular trihedral reflectors.

Solitonic dynamics and excitations of the nonlinear Schrödinger equation with third-order dispersion in non-Hermitian PT-symmetric potentials.

PubMed

Chen, Yong; Yan, Zhenya

2016-03-22

Solitons are of the important significant in many fields of nonlinear science such as nonlinear optics, Bose-Einstein condensates, plamas physics, biology, fluid mechanics, and etc. The stable solitons have been captured not only theoretically and experimentally in both linear and nonlinear Schrödinger (NLS) equations in the presence of non-Hermitian potentials since the concept of the parity-time -symmetry was introduced in 1998. In this paper, we present novel bright solitons of the NLS equation with third-order dispersion in some complex -symmetric potentials (e.g., physically relevant -symmetric Scarff-II-like and harmonic-Gaussian potentials). We find stable nonlinear modes even if the respective linear -symmetric phases are broken. Moreover, we also use the adiabatic changes of the control parameters to excite the initial modes related to exact solitons to reach stable nonlinear modes. The elastic interactions of two solitons are exhibited in the third-order NLS equation with -symmetric potentials. Our results predict the dynamical phenomena of soliton equations in the presence of third-order dispersion and -symmetric potentials arising in nonlinear fiber optics and other physically relevant fields.

Solitonic dynamics and excitations of the nonlinear Schrödinger equation with third-order dispersion in non-Hermitian PT-symmetric potentials

PubMed Central

Chen, Yong; Yan, Zhenya

2016-01-01

Solitons are of the important significant in many fields of nonlinear science such as nonlinear optics, Bose-Einstein condensates, plamas physics, biology, fluid mechanics, and etc. The stable solitons have been captured not only theoretically and experimentally in both linear and nonlinear Schrödinger (NLS) equations in the presence of non-Hermitian potentials since the concept of the parity-time -symmetry was introduced in 1998. In this paper, we present novel bright solitons of the NLS equation with third-order dispersion in some complex -symmetric potentials (e.g., physically relevant -symmetric Scarff-II-like and harmonic-Gaussian potentials). We find stable nonlinear modes even if the respective linear -symmetric phases are broken. Moreover, we also use the adiabatic changes of the control parameters to excite the initial modes related to exact solitons to reach stable nonlinear modes. The elastic interactions of two solitons are exhibited in the third-order NLS equation with -symmetric potentials. Our results predict the dynamical phenomena of soliton equations in the presence of third-order dispersion and -symmetric potentials arising in nonlinear fiber optics and other physically relevant fields. PMID:27002543

Quadratic electroabsorption studies of molecular motion in dye-doped polymers

NASA Astrophysics Data System (ADS)

Poga, Constantina; Kuzyk, Mark G.; Dirk, Carl W.

1993-02-01

This paper reports on quadratic electroabsorption studies of thin-film solid solutions of squarylium dye molecules in poly(methylmethacrylate) polymer with the aim of understanding the role of electronic and reorientational mechanisms in the third-order nonlinear-optical susceptibility. We present a generalized theory of the quadratic electrooptic response that includes both electronic mechanisms and molecular reorientation and show that the ratio of two independent third-order susceptibility tensor components, namely (chi) (3)3333/(chi) (3)1133, determines the relative contribution of each mechanism. Based on these theoretical results, we have designed and built an experiment that determines this ratio as a function of temperature and wavelength. Results show that at room temperature and near the first electronic transition wavelength, the response is dominated by the electronic mechanism, and that the reorientational contribution dominates when the sample is heated above its glass transition temperature. Furthermore, results show that, off-resonance, the sign of the imaginary part of the third-order susceptibility is positive. Quadratic electroabsorption is thus shown to be a versatile tool for measuring the imaginary part of the third-order nonlinear-optical susceptibility which yields information about the interaction of polymer and dopant molecule.

Third order nonlinear optical properties of graphene quantum dots under continuous wavelength regime at 532 nm

NASA Astrophysics Data System (ADS)

Kumara, K.; Shetty, T. C. S.; Patil, P. S.; Maidur, Shivaraj R.; Dharmaprakash, S. M.

2018-04-01

Graphene quantum dots (GQDs) have drawn more attention due to their multifunctional characteristics which can be used for various applications. However, literature on nonlinear optical (NLO) properties of GQDs is scarcely available. Therefore more investigations are required on NLO properties of GQDs. We report preparation of GQDs from pyrolysis method using citric acid as starting material. Third order nonlinear optical (TNLO) properties are studied using Z-scan technique employing continuous wavelength laser. Study reveals that GQD's show self defocusing effect. This is due to thermal heating of solvent which leads to negative nonlinear refractive index of the material. Open aperture (OA) Z-scan reveals reverse saturation absorption (RSA) nature of the material indicating optical limiting (OL) property. A broad UV absorbance spectrum reveals photoluminescence (PL) emission of the material which is independent of excitation wavelength.

Synthesis, spectral and third-order nonlinear optical properties of terpyridine Zn(II) complexes based on carbazole derivative with polyether group

NASA Astrophysics Data System (ADS)

Kong, Ming; Liu, Yanqiu; Wang, Hui; Luo, Junshan; Li, Dandan; Zhang, Shengyi; Li, Shengli; Wu, Jieying; Tian, Yupeng

2015-01-01

Four novel Zn(II) terpyridine complexes (ZnLCl2, ZnLBr2, ZnLI2, ZnL(SCN)2) based on carbazole derivative group were designed, synthesized and fully characterized. Their photophysical properties including absorption and one-photon excited fluorescence, two-photon absorption (TPA) and optical power limiting (OPL) were further investigated systematically and interpreted on the basis of theoretical calculations (TD-DFT). The influences of different solvents on the absorption and One-Photon Excited Fluorescence (OPEF) spectral behavior, quantum yields and the lifetime of the chromophores have been investigated in detail. The third-order nonlinear optical (NLO) properties were investigated by open/closed aperture Z-scan measurements using femtosecond pulse laser in the range from 680 to 1080 nm. These results revealed that ZnLCl2 and ZnLBr2 exhibited strong two-photon absorption and ZnLCl2 showed superior optical power limiting property.

Third-order optical nonlinearities of sol-gel silica coating films containing metal porphyrin derivatives measured by resonant femtosecond degenerate four-wave mixing technique

NASA Astrophysics Data System (ADS)

Kasatani, Kazuo; Okamoto, Hiroaki; Takenaka, Shunsuke

2003-11-01

Third-order optical nonlinearities of sol-gel silica coating films containing metal porphyrin derivatives were measured under resonant conditions by the femtosecond degenerate four-wave mixing (DFWM) technique. Temporal profiles of the DFWM signal were measured with a time resolution of 0.3 ps, and were found to consist of two components, the coherent instantaneous nonlinear response and the delayed response with a decay time constant of several to several hundred ps. The latter can be attributed to population grating of an excited state, and contribution of slow component was very little for a zinc porphyrin derivative. The values of electronic component of the optical nonlinear susceptibility, χ(3) xxxx, for these films were ca. 2 x 10-10 esu.

Tuning the third-order nonlinear optical properties of In:ZnO thin films by 8 MeV electron beam irradiation

NASA Astrophysics Data System (ADS)

Shettigar, Nayana; Pramodini, S.; Kityk, I. V.; Abd-Lefdil, M.; Eljald, E. M.; Regragui, M.; Antony, Albin; Rao, Ashok; Sanjeev, Ganesh; Ajeyakashi, K. C.; Poornesh, P.

2017-11-01

We report the third-order nonlinear optical properties of electron beam treated Indium doped ZnO (Zn1-xInxO (x = 0.03) thin films at different dose rate. Zn1-xInxO (x = 0.03) thin films prepared by spray pyrolysis deposition technique were irradiated using 8 MeV electron beam at dose rates ranging from 1 kGy to 4 kGy. X-ray diffraction patterns were obtained to examine the structural changes, The transformation from sphalerite to wurtzite structure of ZnO was observed which indicates occurrence of structural changes due to irradiation. Morphology of irradiated thin films examined using atomic force microscopy (AFM) technique indicates the surface roughness varying with irradiation dose rate. The switching over from Saturable Absorption (SA) to Reverse Saturable Absorption (RSA) behaviour was noted when the irradiation dose rate was increased from 1 kGy to 4 kGy. The significant changes observed in the third-order nonlinear optical susceptibility χ(3) of the Zn1-xInxO (x = 0.03) thin films is attributed mainly due to electron beam irradiation. The study indicates that nonlinear optical parameters can be controlled by electron beam irradiation by choosing appropriate dose rate which is very much essential for device applications. Hence Zn1-xInxO (x = 0.03) materialize as a promising material for use in nonlinear optical device applications.

Third-order nonlinear optical properties of acid green 25 dye by Z-scan method

NASA Astrophysics Data System (ADS)

Jeyaram, S.; Geethakrishnan, T.

2017-03-01

Third-order nonlinear optical (NLO) properties of aqueous solutions of an anthraquinone dye (Acid green 25 dye, color index: 61570) have been studied by Z-scan method with a 5 mW continuous wave (CW) diode laser operating at 635 nm. The nonlinear refractive index (n2) and the absorption coefficient (β) have been evaluated respectively from the closed and open aperture Z-scan data and the values of these parameters are found to increase with increase in concentration of the dye solution. The negative sign of the observed nonlinear refractive index (n2) indicates that the aqueous solution of acid green 25 dye exhibits self-defocusing type optical nonlinearity. The mechanism of the observed nonlinear absorption (NLA) and nonlinear refraction (NLR) is attributed respectively to reverse saturable absorption (RSA) and thermal nonlinear effects. The magnitudes of n2 and β are found to be of the order of 10-7 cm2/W and 10-3 cm/W respectively. With these experimental results, the authors suggest that acid green 25 dye may have potential applications in nonlinear optics.

Explicit formulation of second and third order optical nonlinearity in the FDTD framework

NASA Astrophysics Data System (ADS)

Varin, Charles; Emms, Rhys; Bart, Graeme; Fennel, Thomas; Brabec, Thomas

2018-01-01

The finite-difference time-domain (FDTD) method is a flexible and powerful technique for rigorously solving Maxwell's equations. However, three-dimensional optical nonlinearity in current commercial and research FDTD softwares requires solving iteratively an implicit form of Maxwell's equations over the entire numerical space and at each time step. Reaching numerical convergence demands significant computational resources and practical implementation often requires major modifications to the core FDTD engine. In this paper, we present an explicit method to include second and third order optical nonlinearity in the FDTD framework based on a nonlinear generalization of the Lorentz dispersion model. A formal derivation of the nonlinear Lorentz dispersion equation is equally provided, starting from the quantum mechanical equations describing nonlinear optics in the two-level approximation. With the proposed approach, numerical integration of optical nonlinearity and dispersion in FDTD is intuitive, transparent, and fully explicit. A strong-field formulation is also proposed, which opens an interesting avenue for FDTD-based modelling of the extreme nonlinear optics phenomena involved in laser filamentation and femtosecond micromachining of dielectrics.

Dynamics of Peregrine combs and Peregrine walls in an inhomogeneous Hirota and Maxwell-Bloch system

NASA Astrophysics Data System (ADS)

Wang, Lei; Wang, Zi-Qi; Sun, Wen-Rong; Shi, Yu-Ying; Li, Min; Xu, Min

2017-06-01

Under investigation in this paper is an inhomogeneous Hirota-Maxwell-Bloch (IHMB) system which can describe the propagation of optical solitons in an erbium-doped optical fiber. The breather multiple births (BMBs) are derived with periodically varying group velocity dispersion (GVD) coefficients. Under large periodic modulations in the GVD coefficient of IHMB system, the Peregrine comb (PC) solution is produced, which can be viewed as the limiting case of the BMBs. When the amplitude of the modulation satisfies a special condition, the Peregrine wall (PW) that can be regarded as an intermediate state between rogue wave and PC is obtained. The effects of the third-order dispersion on the spatiotemporal characteristics of PCs and PWs are studied. Our results may be useful for the experimental control and manipulation of the formation of generalized Peregrine rogue waves in inhomogeneous erbium-doped optical fiber.

The second– and third– order nonlinear optical properties and electronic transition of a NLO chromophore: A DFT study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Altürk, Sümeyye, E-mail: sumeyye-alturk@hotmail.com; Avci, Davut, E-mail: davci@sakarya.edu.tr; Tamer, Ömer, E-mail: omertamer@sakarya.edu.tr

2016-03-25

It is well known that the practical applications of second-order and third-order nonlinear optical (NLO) materials have been reported in modern technology, such as optical data processing, transmission and storage, etc. In this respect, the linear and nonlinear optical parameters (the molecular static polarizability (α), and the first–order static hyperpolarizability (β{sub 0}), the second–order static hyperpolarizability (γ)), UV-vis spectra and HOMO and LUMO energies of 2-(1′-(4’’’-Methoxyphenyl)-5′-(thien-2″-yl)pyrrol-2′-yl)-1,3-benzothiazole were investigated by using the HSEh1PBE/6–311G(d,p) level of density functional theory. The UV–vis spectra were simulated using TD/HSEh1PBE/6– 311G(d,p) level, and the major contributions to the electronic transitions were obtained. The molecular hardness (η)more » and electronegativity (χ) parameters were also obtained by using molecular frontier orbital energies. The NLO parameters of the title compound were calculated, and obtained data were compared with that of para-Nitroaniline (pNA) which is a typical NLO material and the corresponding experimental data. Obtained data of the chromosphere display significant molecular second-and third-nonlinearity.« less

Third-order nonlinear electro-optic measurements in the smectic-? phase

NASA Astrophysics Data System (ADS)

Nowicka, Kamila; Bielejewska, Natalia

2018-02-01

The chiral smectic subphase with three-layer structure, ?, is now of great interest from the point of view of device technologies such as multistate or symmetric switching. We report that the unique nonlinear electro-optic response can serve as precise mark of the phase transition into three-layer structure. The problem is illustrated with the first and third harmonic electro-optic spectra. Furthermore, the characteristic response of the helical liquid crystal phases correlated with particular collective modes using the Debye-type relaxation method for the well-known prototype liquid crystal material (MHPOBC) are presented.

Twistacene contained molecule for optical nonlinearity: Excited-state based negative refraction and optical limiting

NASA Astrophysics Data System (ADS)

Wu, Xingzhi; Xiao, Jinchong; Sun, Ru; Jia, Jidong; Yang, Junyi; Ao, Guanghong; Shi, Guang; Wang, Yuxiao; Zhang, Xueru; Song, Yinglin

2018-06-01

Spindle-type molecules containing twisted acenes (PyBTA-1 &PyBTA-2) are designed, synthesized characterized. Picosecond Z-scan experiments under 532 nm show reverse saturable absorption and negative nonlinear refraction, indicating large third-order optical nonlinearity in PyBTA-1. The mechanism of the optical nonlinearity is investigated and the results show that the nonlinear absorption and refraction in PyBTA-1 originates from a charge transfer (CT) state. Furthermore, relatively long lifetime and absorptive cross section of the CT state are measured. Based on the excited state absorption in PyBTA-1, strong optical limiting with ∼0.3 J/cm2 thresholds are obtained when excited by picoseconds and nanoseconds pulses. The findings on nonlinear optics suggest PyBTA-1 a promising material of all optical modulation and laser protection, which enrich the potential applications of these spindle-type molecules. Comparing to the previously reported spindle-type molecules with analogous structures, the introduction of ICT in PyBTA-1 &PyBTA-2 dramatically decreases the two-photon absorption while enhances the nonlinear refraction. The results could be used to selectively tailor the optical nonlinearity in such kind of compounds.

Third-order nonlinear optical properties of phthalocyanines in solution and in polystyrene films

NASA Astrophysics Data System (ADS)

Reeves, Roger J.; Powell, Richard C.; Chang, Young H.; Ford, Warren T.; Zhu, Weiming

1996-01-01

Degenerate four-wave mixing (DFWM) measurements of third-order nonlinear optical (NLO) coefficients of metal-free, Cu, Pt, Pb and Bi octa(2-ethylhexyloxy) phthalocyanines (MPc's) were done with 20 ps duration laser pulses under resonant conditions at 532 nm in polystyrene films and under nonresonant conditions at 1064 nm in chloroform solutions. The NLO coefficients ξxxxx(3) show saturation with increasing incident intensity and no strong dependence on the central metal atom of the MPc below the saturation intensity. Optical delays of the probe-pulse up to 3 ns show an acoustic phonon response in both the polystyrene films and the chloroform solutions. An intensity-dependent absorption coefficient was measured by a pump/probe experiment and used in a simple model to qualitatively account for the saturation of ξ(3) measured by DFWM.

Synthetic magnetism for photon fluids

NASA Astrophysics Data System (ADS)

Westerberg, N.; Maitland, C.; Faccio, D.; Wilson, K.; Öhberg, P.; Wright, E. M.

2016-08-01

We develop a theory of artificial gauge fields in photon fluids for the cases of both second-order and third-order optical nonlinearities. This applies to weak excitations in the presence of pump fields carrying orbital angular momentum and is thus a type of Bogoliubov theory. The resulting artificial gauge fields experienced by the weak excitations are an interesting generalization of previous cases and reflect the PT-symmetry properties of the underlying non-Hermitian Hamiltonian. We illustrate the observable consequences of the resulting synthetic magnetic fields for examples involving both second-order and third-order nonlinearities.

Preparation, linear and NLO properties of DNA-CTMA-SBE complexes

NASA Astrophysics Data System (ADS)

Manea, Ana-Maria; Rau, Ileana; Kajzar, Francois; Meghea, Aurelia

2013-10-01

Synthesis of deoxyribonucleic acid (DNA) - was cetyltrimethylammonium (CTMA) - sea buckthorn extract (SBE) at different concentrations is decribed. The complexes were processed into good optical quality thin films by spin coating on different substrates such as: glass, silica and ITO covered glass substrates. SBE contains many bioactive substances that can be used in the treatment of several diseases, such as cardiovascular disease, cancer, and acute mountain sickness. The obtained thin films were characterized for their spectroscopic, fluorescent, linear and nonlinear optical properties as function of SBE concentration. The third-order nonlinear optical (NLO) properties of thin films were determined by the optical third-harmonic generation technique at 1 064.2 nm fundamental wavelength.

Fourth near-infrared optical window for assessment of bone and other tissues

NASA Astrophysics Data System (ADS)

Sordillo, Diana C.; Sordillo, Laura A.; Sordillo, Peter P.; Alfano, Robert R.

2016-02-01

Recently, additional near-infrared (NIR) optical windows beyond the conventional first therapeutic window have been utilized for deep tissue imaging through scattering media. Biomedical applications using a second optical window (1100 to 1300 nm) and a third (1600 to 1870 nm) are emerging. A fourth window (2100 to 2300 nm) has been largely ignored due to high water absorption and a lack of high sensitivity imaging detectors and ultrafast laser sources. In this study, optical properties of bone in this fourth NIR optical window, were investigated. Results were compared to those seen at the first, second and third windows, and are consistent with our previous work on malignant and benign breast and prostate tissues. Bone and malignant tissues showed highest uptake in the third and fourth windows. As collagen is a major chromophore with prominent spectral peaks between 2100 and 2300 nm, it may be that the fourth optical window is particularly useful for studying tissues with a higher collagen content, such as bone or malignant tumors.

Conservation laws and rogue waves for a higher-order nonlinear Schrödinger equation with variable coefficients in the inhomogeneous fiber

NASA Astrophysics Data System (ADS)

Du, Zhong; Tian, Bo; Wu, Xiao-Yu; Liu, Lei; Sun, Yan

2017-07-01

Subpicosecond or femtosecond optical pulse propagation in the inhomogeneous fiber can be described by a higher-order nonlinear Schrödinger equation with variable coefficients, which is investigated in the paper. Via the Ablowitz-Kaup-Newell-Segur system and symbolic computation, the Lax pair and infinitely-many conservation laws are deduced. Based on the Lax pair and a modified Darboux transformation technique, the first- and second-order rogue wave solutions are constructed. Effects of the groupvelocity dispersion and third-order dispersion on the properties of the first- and second-order rouge waves are graphically presented and analyzed: The groupvelocity dispersion and third-order dispersion both affect the ranges and shapes of the first- and second-order rogue waves: The third-order dispersion can produce a skew angle of the first-order rogue wave and the skew angle rotates counterclockwise with the increase of the groupvelocity dispersion, when the groupvelocity dispersion and third-order dispersion are chosen as the constants; When the groupvelocity dispersion and third-order dispersion are taken as the functions of the propagation distance, the linear, X-shaped and parabolic trajectories of the rogue waves are obtained.

Growth of single crystals of organic salts with large second-order optical nonlinearities by solution processes for devices

NASA Technical Reports Server (NTRS)

Leslie, Thomas M.

1995-01-01

Data obtained from the electric field induced second harmonic generation (EFISH) and Kurtz Powder Methods will be provided to MSFC for further refinement of their method. A theoretical model for predicting the second-order nonlinearities of organic salts is being worked on. Another task is the synthesis of a number of salts with various counterions. Several salts with promising SHG activities and new salts will be tested for the presence of two crystalline forms. The materials will be recrystallized from dry and wet solvents and compared for SHG efficiency. Salts that have a high SHG efficiency and no tendency to form hydrates will be documented. The synthesis of these materials are included in this report. A third task involves method to aid in the growth of large, high quality single crystals by solution processes. These crystals will be characterized for their applicability in the fabrication of devices that will be incorporated into optical computers in future programs. Single crystals of optimum quality may be obtained by crystal growth in low-gravity. The final task is the design of a temperature lowering single crystal growth apparatus for ground based work. At least one prototype will be built.

Effect of the internal optics on the outcome of custom-LASIK in an eye model

NASA Astrophysics Data System (ADS)

Manns, Fabrice; Ho, Arthur; Parel, Jean-Marie

2004-07-01

Purpose. The purpose of this study was to evaluate if changes in the aberration-contribution of the internal optics of the eye have a significant effect on the outcome of wavefront-guided corneal reshaping. Methods. The Navarro-Escudero eye model was simulated using optical analysis software. The eye was rendered myopic by shifting the plane of the retina. Custom-LASIK was simulated by changing the radius of curvature and asphericity of the anterior corneal surface of the eye model. The radius of curvature was adjusted to provide a retinal conjugate at infinity. Three approaches were used to determine the postoperative corneal asphericity: minimizing third-order spherical aberration, minimizing third-order coma, and maximizing the Strehl ratio. The aberration contribution of the anterior corneal surface and internal optics was calculated before and after each simulated customized correction. Results. For a 5.2mm diameter pupil, the contribution of the anterior corneal surface to third-order spherical aberration and coma (in micrometers) was 2.22 and 2.49 preop, -0.36 and 2.83 postop when spherical aberration is minimized, 5.88 and 1.10 postop when coma is minimized, and -0.63 and 2.91 postop when Strehl ratio is maximized. The contribution of the internal optics of the eye to spherical aberration and coma for the same four conditions was: 0.43 and -1.13, 0.37 and -1.10, 0.37 and -1.10 and 0.37 and -1.10, respectively. Conclusion. In the model eye, the contribution of the internal optics of the eye to the change in the ocular aberration state is negligible.

Third-order nonlinear optical properties of organic azo dyes by using strength of nonlinearity parameter and Z-scan technique

NASA Astrophysics Data System (ADS)

Motiei, H.; Jafari, A.; Naderali, R.

2017-02-01

In this paper, two chemically synthesized organic azo dyes, 2-(2,5-Dichloro-phenyazo)-5,5-dimethyl-cyclohexane-1,3-dione (azo dye (i)) and 5,5-Dimethyl-2-tolylazo-cyclohexane-1,3-dione (azo dye (ii)), have been studied from optical Kerr nonlinearity point of view. These materials were characterized by Ultraviolet-visible spectroscopy. Experiments were performed using a continous wave diode-pumped laser at 532 nm wavelength in three intensities of the laser beam. Nonlinear absorption (β), refractive index (n2) and third-order susceptibility (χ (3)) of dyes, were calculated. Nonlinear absorption coefficient of dyes have been calculated from two methods; 1) using theoretical fits and experimental data in the Z-scan technique, 2) using the strength of nonlinearity curves. The values of β obtained from both of the methods were approximately the same. The results demonstrated that azo dye (ii) displays better nonlinearity and has a lower two-photon absorption threshold than azo dye (i). Calculated parameter related to strength of nonlinearity for azo dye (ii) was higher than azo dye (i), It may be due to presence of methyl in azo dye (ii) instead of chlorine in azo dye (i). Furthermore, The measured values of third order susceptibility of azo dyes were from the order of 10-9 esu . These azo dyes can be suitable candidate for optical switching devices.

Validity Using Pump-Probe Pulses to Determine the Optical Response of Niobate Crystals

NASA Technical Reports Server (NTRS)

Liu, Huimin; Jia, Weiyi

1997-01-01

A variety of niobate crystals have found their places in nonlinear optical applications as well as in laser devices. In recent years much attention has been paid to study the ultrafast optical response in a variety of photorefractive crystals such as KTa(1-x)Nb(x)O3 and KNbO3 crystals, glasses, semiconductors and polymers for applications in optical switching, information processing, optical computing, and all-optical device systems. Third-order optical nonlinearity is the most important property for realization of all-optical switching. Therefore experiments have been performed on the third order susceptibility using a variety of techniques such as the third-order harmonic generation, EFISH and degenerate four-wave mixing(DFWM). The latter has been conducted with a variety of pump wavelengths and with nanosecond, picosecond and femtosecond pulses. Niobate crystals, such as potassium niobate KNbO3, potassium tantalate niobate KTN family (KTa(1-x)Nb(x)O3), strontium barium niobate SBN (Sr(x)Ba(1-x)Nb2O6) and potassium-sodium niobate SBN (KNSBN) are attractive due to their photorefractive properties for application in optical storage and processing. The pulsed probe experiments performed on theses materials have suggested two types of time responses. These responses have been associated with an coherent response due to Chi(sup 3), and a long lived component due to excited state population. Recent study of DFWM on KNbO3 and KTN family reveals that the long lived component of those crystals depends on the crystal orientation. A slowly decaying signal is observable when the grating vector K(sub g) is not perpendicular to the C-axis of those photorefractive crystals', otherwise the optical response signal would be only a narrow coherent peak with FWHM equal to the cross-correlation width of the write beam pulses. Based on this understanding, we study the photodynamical process of a variety of niobate crystals using DFWM in a Kg perpindicular to C geometry with a ps-YAG: Nd laser operating at 532nm. However, the discrepancies in numerical estimations of Chi(sup 3) in these materials and other nonlinear optical media have resulted in a number of discussions. In order to better understand the photodynamical process of niobate crystals after an short pulse excitation we analyze the factors governing the coherent signal and present the DFWM spectra of niobate crystals.

Synthesis, optical, experimental and theoretical investigation of third order nonlinear optical properties of 8-hydroxyquinolinium 2-carboxy-6-nitrophthalate monohydrate single crystal

NASA Astrophysics Data System (ADS)

Bharathi, M. Divya; Bhuvaneswari, R.; Srividya, J.; Vinitha, G.; Prithiviraajan, R. N.; Anbalagan, G.

2018-02-01

Single crystals of 8-hydroxyquinolinium 2-carboxy-6-nitrophthalate monohydrate (8HQNP) were obtained from slow evaporation solution growth method using methanol-water (1:1) as a solvent. Powder X-ray diffraction was utilized to compute the unit cell parameters and dislocation density of 8HQNP crystal. The crystalline perfection of the as-grown crystal was investigated by high-resolution X-ray diffraction at room temperature. The molecular structure was analyzed by identifying the functional groups from FT-IR and FT-Raman spectra. The cut-off wavelength and the corresponding optical band gap obtained from an optical spectrum were 376 nm and 3.29 eV respectively. The dispersion nature of refractive index was investigated by the single-oscillator Wemple and Di-Domenico model. Red emission was observed in the photoluminescence spectrum when excited with 376 nm. The low birefringence and high laser damage threshold (8.538 GW/cm2) values dictate the suitability of the crystal for optical devices. Z-scan studies revealed the third order nonlinear absorption coefficient (β) and refractive index (n2) of the 8HQNP crystal. The theoretical value of third order nonlinear susceptibility obtained from density function theory is good accordance with the experimental value. The frontier molecular orbital energy gap decreases with increasing external electric field in different directions which attributed to the enhancement of the second hyperpolarizability. The grown title crystal is thermally stable up to 102 °C which was identified using thermal analysis. Mechanical strength of 8HQNP was estimated by using Vicker's microhardness studies.

Linear and nonlinear optical properties of Sb-doped GeSe2 thin films

NASA Astrophysics Data System (ADS)

Zhang, Zhen-Ying; Chen, Fen; Lu, Shun-Bin; Wang, Yong-Hui; Shen, Xiang; Dai, Shi-Xun; Nie, Qiu-Hua

2015-06-01

Sb-doped GeSe2 chalcogenide thin films are prepared by the magnetron co-sputtering method. The linear optical properties of as-deposited films are derived by analyzing transmission spectra. The refractive index rises and the optical band gap decreases from 2.08 eV to 1.41 eV with increasing the Sb content. X-ray photoelectron spectra further confirm the formation of a covalent Sb-Se bond. The third-order nonlinear optical properties of thin films are investigated under femtosecond laser excitation at 800 nm. The results show that the third-order nonlinear optical properties are enhanced with increasing the concentration of Sb. The nonlinear refraction indices of these thin films are measured to be on the order of 10-18 m2/W with a positive sign and the nonlinear absorption coefficients are obtained to be on the order of 10-10 m/W. These excellent properties indicate that Sb-doped Ge-Se films have a good prospect in the applications of nonlinear optical devices. Project supported by the National Key Basic Research Program of China (Grant No. 2012CB722703), the National Natural Science Foundation of China (Grant No. 61377061), the Young Leaders of Academic Climbing Project of the Education Department of Zhejiang Province, China (Grant No. pd2013092), the Program for Innovative Research Team of Ningbo City, China (Grant No. 2009B217), and the K. C. Wong Magna Fund in Ningbo University, China.

Pushing the limits of CMOS optical parametric amplifiers with USRN:Si7N3 above the two-photon absorption edge

PubMed Central

Ooi, K. J. A.; Ng, D. K. T.; Wang, T.; Chee, A. K. L.; Ng, S. K.; Wang, Q.; Ang, L. K.; Agarwal, A. M.; Kimerling, L. C.; Tan, D. T. H.

2017-01-01

CMOS platforms operating at the telecommunications wavelength either reside within the highly dissipative two-photon regime in silicon-based optical devices, or possess small nonlinearities. Bandgap engineering of non-stoichiometric silicon nitride using state-of-the-art fabrication techniques has led to our development of USRN (ultra-silicon-rich nitride) in the form of Si7N3, that possesses a high Kerr nonlinearity (2.8 × 10−13 cm2 W−1), an order of magnitude larger than that in stoichiometric silicon nitride. Here we experimentally demonstrate high-gain optical parametric amplification using USRN, which is compositionally tailored such that the 1,550 nm wavelength resides above the two-photon absorption edge, while still possessing large nonlinearities. Optical parametric gain of 42.5 dB, as well as cascaded four-wave mixing with gain down to the third idler is observed and attributed to the high photon efficiency achieved through operating above the two-photon absorption edge, representing one of the largest optical parametric gains to date on a CMOS platform. PMID:28051064

Microscopic cascading of second-order molecular nonlinearity: New design principles for enhancing third-order nonlinearity.

PubMed

Baev, Alexander; Autschbach, Jochen; Boyd, Robert W; Prasad, Paras N

2010-04-12

Herein, we develop a phenomenological model for microscopic cascading and substantiate it with ab initio calculations. It is shown that the concept of local microscopic cascading of a second-order nonlinearity can lead to a third-order nonlinearity, without introducing any new loss mechanisms that could limit the usefulness of our approach. This approach provides a new molecular design protocol, in which the current great successes achieved in producing molecules with extremely large second-order nonlinearity can be used in a supra molecular organization in a preferred orientation to generate very large third-order response magnitudes. The results of density functional calculations for a well-known second-order molecule, (para)nitroaniline, show that a head-to-tail dimer configuration exhibits enhanced third-order nonlinearity, in agreement with the phenomenological model which suggests that such an arrangement will produce cascading due to local field effects.

Nonlinear Optical Properties of Organic and Polymeric Thin Film Materials of Potential for Microgravity Processing Studies

NASA Technical Reports Server (NTRS)

Abdeldayem, Hossin; Frazier, Donald O.; Paley, Mark S.; Penn, Benjamin; Witherow, William K.; Bank, Curtis; Shields, Angela; Hicks, Rosline; Ashley, Paul R.

1996-01-01

In this paper, we will take a closer look at the state of the art of polydiacetylene, and metal-free phthalocyanine films, in view of the microgravity impact on their optical properties, their nonlinear optical properties and their potential advantages for integrated optics. These materials have many attractive features with regard to their use in integrated optical circuits and optical switching. Thin films of these materials processed in microgravity environment show enhanced optical quality and better molecular alignment than those processed in unit gravity. Our studies of these materials indicate that microgravity can play a major role in integrated optics technology. Polydiacetylene films are produced by UV irradiation of monomer solution through an optical window. This novel technique of forming polydiacetylene thin films has been modified for constructing sophisticated micro-structure integrated optical patterns using a pre-programmed UV-Laser beam. Wave guiding through these thin films by the prism coupler technique has been demonstrated. The third order nonlinear parameters of these films have been evaluated. Metal-free phthalocyanine films of good optical quality are processed in our laboratories by vapor deposition technique. Initial studies on these films indicate that they have excellent chemical, laser, and environmental stability. They have large nonlinear optical parameters and show intrinsic optical bistability. This bistability is essential for optical logic gates and optical switching applications. Waveguiding and device making investigations of these materials are underway.

Growth, optical, thermal, mechanical and dielectric studies of sodium succinate hexahydrate (β phase) single crystal: A promising third order NLO material

NASA Astrophysics Data System (ADS)

Mageshwari, P. S. Latha; Priya, R.; Krishnan, S.; Joseph, V.; Das, S. Jerome

2016-11-01

A third order nonlinear optical (NLO)single crystals of sodium succinate hexahydrate (SSH) (β phase) has been grown by a slow evaporation growth technique using aqueous solution at ambient temperature. The lattice parameters and morphology of SSH were determined by single crystal X-ray diffraction analysis. SSH crystallizes in centrosymmetric monoclinic system with space group P 21 / c and the crystalline purity was analyzed by powder X-ray diffraction analysis. The UV-vis-NIR spectrum reveals that the crystal is transparent in the entire visible region. The recorded FT-IR spectrum verified the presence of various functional groups in the material. NMR analysis of the grown crystal confirms the structural elucidation and detects the major and minor functional groups present in the title compound. ICP-OES analysis proved the presence of sodium in SSH. TG-DTA/DSCanalysis was used to investigate the thermal stability of the material. The dielectric permittivity and dielectric loss of SSH were carried out as a function of frequency for different temperatures and the results were discussed. The mechanical stability was evaluated from Vicker's microhardness test. The third order nonlinear optical properties of SSH has been investigated employing Z-scan technique with He-Ne laser operating at 632.8 nm wavelength.

Observation of Third-order Nonlinearities in Graphene Oxide Film at Telecommunication Wavelengths

DOE PAGES

Xu, Xiaochuan; Zheng, Xiaorui; He, Feng; ...

2017-08-29

All-optical switches have been considered as a promising solution to overcome the fundamental speed limit of the current electronic switches. However, the lack of a suitable third-order nonlinear material greatly hinders the development of this technology. Here in this paper we report the observation of ultrahigh third-order nonlinearity about 0.45 cm 2/GW in graphene oxide thin films at the telecommunication wavelength region, which is four orders of magnitude higher than that of single crystalline silicon. Besides, graphene oxide is water soluble and thus easy to process due to the existence of oxygen containing groups. These unique properties can potentially significantlymore » advance the performance of alloptical switches.« less

Observation of Third-order Nonlinearities in Graphene Oxide Film at Telecommunication Wavelengths

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, Xiaochuan; Zheng, Xiaorui; He, Feng

All-optical switches have been considered as a promising solution to overcome the fundamental speed limit of the current electronic switches. However, the lack of a suitable third-order nonlinear material greatly hinders the development of this technology. Here in this paper we report the observation of ultrahigh third-order nonlinearity about 0.45 cm 2/GW in graphene oxide thin films at the telecommunication wavelength region, which is four orders of magnitude higher than that of single crystalline silicon. Besides, graphene oxide is water soluble and thus easy to process due to the existence of oxygen containing groups. These unique properties can potentially significantlymore » advance the performance of alloptical switches.« less

Triphenylamine Derived 3-Acetyl and 3-Benzothiazolyl Bis and Tris Coumarins: Synthesis, Photophysical and DFT Assisted Hyperpolarizability Study

NASA Astrophysics Data System (ADS)

Erande, Yogesh; Kothavale, Shantaram; Sreenath, Mavila C.; Chitrambalam, Subramaniyan; Joe, Isaac H.; Sekar, Nagaiyan

2018-02-01

Triphenylamine derived bis- and tris-branched donor-pi-acceptor coumarins with acetyl and benzothiazolyl acceptors are studied for their linear and nonlinear optical properties that originate from their photophysical and molecular structure. Plots of solvent polarities versus the Stokes shift, frontier molecular orbital analysis and Generalised Mulliken Hush analysis have established their strong charge transfer character supported by the strong emission solvatochromism of these chromophores. On the basis of excited state intramolecular charge transfer, the first-, second- and third-order polarizability of these dyes are determined by a solvatochromic method and supported by density functional theory calculations using CAM-B3LYP/6-31g(d). Compared to the acetyl group, the benzothiazolyl group is a strong acceptor, and its corresponding derivatives show enhanced absorption, emission maxima and non-linear optical response. Bond length alternation and bond order alternation analysis reveals that these chromophores approach the cyanine-like framework which is responsible for maximum perturbation to produce high nonlinear optical response. Third order nonlinear susceptibility for dyes 1 and 2 is determined by Z-scan measurement. All of these methods are used to determine the nonlinear optical properties, and thermogravimetric analysis suggests that these chromophores are thermally robust and efficient nonlinear optical materials.

Afocal three-mirror anastigmat with zigzag optical axis for widened field of view and enlarged aperture

NASA Astrophysics Data System (ADS)

Li, Qi; Han, Lin; Jin, Yangming; Shen, Weimin

2016-10-01

In order to improve the detection accuracy and range of new generation of Forward Looking Infra-Red (FLIR) system for distant targets, its optical system, which usually consists of a fore afocal telescope and rear imaging lenses, is required to has wide spectral range, large entrance pupil aperture, and wide field of view (FOV). In this paper, a new afocal Three-Mirror Anastigmat (TMA) with widened field of view and high demagnification is suggested. Its mechanical structure remains coaxial, but it has zigzag optical axis through properly and slightly decentering and tilting of the three mirrors to avoid its secondary obscuration due to the third mirror as FOV increase. Compared with conventional off-axis TMA, the suggested zigzag-axis TMA is compact, easy-alignment and low-cost. The design method and optimum result of the suggested afocal TMA is presented. Its initial structural parameters are determined with its first-order relationship and primary aberration theory. Slight and proper decentration and tilt of each mirror is leaded in optimization so that its coaxial mechanical structure is held but attainable FOV and demagnification are respectively as wide and as high as possible. As an example, a 5.5-demagnification zigzag-axis afocal TMA with a wavelength range, an entrance pupil diameter, and FOV respectively from 3μm to 12μm, of 320mm, and 2×3.2 degrees and with a real exit pupil, is designed. Its imaging quality is diffraction limited. It is suitable for fore afocal telescope of the so-called third generation FLIR.

Studies on 2-amino-5-nitropyridinium nitrate (2A5NPN): A semi-organic third order nonlinear optical single crystal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sivasubramani, V.; Pandian, Muthu Senthil, E-mail: senthilpandianm@ssn.edu.in; Ramasamy, P.

2016-05-23

2-amino-5-nitropyridinium nitrate (2A5NPN) is a semi-organic nonlinear optical crystal and optically good quality 2A5NPN single crystals were successfully grown by slow evaporation solution growth technique (SEST) at ambient temperature. The crystallographic structure of the grown crystal was determined by single crystal X-Ray diffraction analysis and it belongs to Monoclinic crystal system with centro symmetric crystalline nature. The crystallinity of the grown crystal was confirmed by powder X-ray diffraction analysis. The other physical properties of grown crystals are also characterized using TG-DTA, UV-Visible NIR, chemical etching, photoconductivity and Z-scan measurements. The Z-scan method reveals that the 2A5NPN crystal possesses multi photonmore » absorption behaviour and the significantly higher third order susceptibility and it is a promising potential NLO material.« less

High-order rogue wave solutions of the classical massive Thirring model equations

NASA Astrophysics Data System (ADS)

Guo, Lijuan; Wang, Lihong; Cheng, Yi; He, Jingsong

2017-11-01

The nth-order solutions of the classical massive Thirring model (MTM) equations are derived by using the n-fold Darboux transformation. These solutions are expressed by the ratios of the two determinants consisted of 2n eigenfunctions under the reduction conditions. Using this method, rogue waves are constructed explicitly up to the third-order. Three patterns, i.e., fundamental, triangular and circular patterns, of the rogue waves are discussed. The parameter μ in the MTM model plays the role of the mass in the relativistic field theory while in optics it is related to the medium periodic constant, which also results in a significant rotation and a remarkable lengthening of the first-order rogue wave. These results provide new opportunities to observe rouge waves by using a combination of electromagnetically induced transparency and the Bragg scattering four-wave mixing because of large amplitudes.

Third-order optical nonlinearity of N-doped graphene oxide nanocomposites at different GO ratios

NASA Astrophysics Data System (ADS)

Kimiagar, Salimeh; Abrinaei, Fahimeh

2018-05-01

In the present work, the influence of GO ratios on the structural, linear and nonlinear optical properties of nitrogen-doped graphene oxide nanocomposites (N-GO NCs) has been studied. N-GO NCs were synthesized by hydrothermal method. The XRD, FTIR, SEM, and TEM results confirmed the reduction of GO by nitrogen doping. The energy band gaps of N-GO NCs calculated from UV-Vis analyzed by using Tauc plot. To obtain further insight into potential optical changes in the N-GO NCs by increasing GO contents, Z-scan analysis was performed with nanosecond Nd-YAG laser at 532 nm. The nonlinear absorption coefficient, β, and nonlinear refractive index, n2, for N-GO NCs at the laser intensity of 113 MW/cm were measured and an increase was observed in both parameters after addition of nitrogen to GO. The third-order nonlinear optical susceptibilities of N-GO NCs were measured in the order of 10-9 esu. The results showed that N-GO NCs have negative nonlinearity which can be controlled by GO contents to obtain the highest values for nonlinear optical parameters. The nonlinear optical results not only imply that N-GO NCs can serve as an important material in the advancing of optoelectronics but also open new possibilities for the design of new graphene-based materials by variation of N and GO ratios as well as manufacturing conditions.

Continuous-Variable Triple-Photon States Quantum Entanglement

NASA Astrophysics Data System (ADS)

González, E. A. Rojas; Borne, A.; Boulanger, B.; Levenson, J. A.; Bencheikh, K.

2018-01-01

We investigate the quantum entanglement of the three modes associated with the three-photon states obtained by triple-photon generation in a phase-matched third-order nonlinear optical interaction. Although the second-order processes have been extensively dealt with, there is no direct analogy between the second and third-order mechanisms. We show, for example, the absence of quantum entanglement between the quadratures of the three modes in the case of spontaneous parametric triple-photon generation. However, we show robust, seeding-dependent, genuine triple-photon entanglement in the fully seeded case.

Continuous-Variable Triple-Photon States Quantum Entanglement.

PubMed

González, E A Rojas; Borne, A; Boulanger, B; Levenson, J A; Bencheikh, K

2018-01-26

We investigate the quantum entanglement of the three modes associated with the three-photon states obtained by triple-photon generation in a phase-matched third-order nonlinear optical interaction. Although the second-order processes have been extensively dealt with, there is no direct analogy between the second and third-order mechanisms. We show, for example, the absence of quantum entanglement between the quadratures of the three modes in the case of spontaneous parametric triple-photon generation. However, we show robust, seeding-dependent, genuine triple-photon entanglement in the fully seeded case.

Nonlinear optical properties of rigid-rod polymers

NASA Technical Reports Server (NTRS)

Trimmer, Mark S.; Wang, Ying

1992-01-01

The purpose of this research project was to integrate enhanced third order nonlinear optical (NLO) properties, especially high x(exp (3)) (greater than 10(exp -8) esu), into Maxdem's novel conjugated rigid-rod polymers while retaining their desirable processing, mechanical, and thermal properties. This work primarily involved synthetic approaches to optimized materials.

Enhanced optical nonlinearity and fiber-optical frequency comb controlled by a single atom in a whispering-gallery-mode microtoroid resonator

NASA Astrophysics Data System (ADS)

Li, Jiahua; Zhang, Suzhen; Yu, Rong; Zhang, Duo; Wu, Ying

2014-11-01

Based on a single atom coupled to a fiber-coupled, chip-based microresonator [B. Dayan et al., Science 319, 1062 (2008), 10.1126/science.1152261], we put forward a scheme to generate optical frequency combs at driving laser powers as low as a few nanowatts. Using state-of-the-art experimental parameters, we investigate in detail the influences of different atomic positions and taper-resonator coupling regimes on optical-frequency-comb generation. In addition to numerical simulations demonstrating this effect, a physical explanation of the underlying mechanism is presented. We find that the combination of the atom and the resonator can induce a large third-order nonlinearity which is significantly stronger than Kerr nonlinearity in Kerr frequency combs. Such enhanced nonlinearity can be used to generate optical frequency combs if driven with two continuous-wave control and probe lasers and significantly reduce the threshold of nonlinear optical processes. The comb spacing can be well tuned by changing the frequency beating between the driving control and probe lasers. The proposed method is versatile and can be adopted to different types of resonators, such as microdisks, microspheres, microtoroids or microrings.

Coherent source interaction, third-order nonlinear response of synthesized PEG coated magnetite nanoparticles in polyethylene glycol and its application

NASA Astrophysics Data System (ADS)

Gopal, S. Veena; Chitrambalam, S.; Joe, I. Hubert

2018-01-01

Third-order nonlinear response of synthesized polyethylene glycol coated Fe3O4 nanoparticles dispersed in a suitable solvent, polyethylene glycol has been studied. The structural characterization of the synthesized magnetite nanoparticles were carried out. The linear optical property of the synthesized magnetite nanoparticles was investigated using UV-visible technique. Both closed and open aperture Z-scan techniques have been performed at 532 nm with pulse width 5 ns and repetition rate 10 Hz. It was found that polyethylene glycol coated magnetite exhibits reverse saturable absorption, with significant nonlinear absorption coefficient. Two-photon absorption intensity dependent positive nonlinear refraction coefficients indicate self focusing phenomena. Results show that higher concentration gives better nonlinear and optical limiting properties.

Radio-frequency low-coherence interferometry.

PubMed

Fernández-Pousa, Carlos R; Mora, José; Maestre, Haroldo; Corral, Pablo

2014-06-15

A method for retrieving low-coherence interferograms, based on the use of a microwave photonics filter, is proposed and demonstrated. The method is equivalent to the double-interferometer technique, with the scanning interferometer replaced by an analog fiber-optics link and the visibility recorded as the amplitude of its radio-frequency (RF) response. As a low-coherence interferometry system, it shows a decrease of resolution induced by the fiber's third-order dispersion (β3). As a displacement sensor, it provides highly linear and slope-scalable readouts of the interferometer's optical path difference in terms of RF, even in the presence of third-order dispersion. In a proof-of-concept experiment, we demonstrate 20-μm displacement readouts using C-band EDFA sources and standard single-mode fiber.

Investigations on structural, optical, electrical, mechanical and third-order nonlinear behaviour of 3-aminopyridinium 2,4-dinitrophenolate single crystal

NASA Astrophysics Data System (ADS)

Mohanbabu, B.; Bharathikannan, R.; Siva, G.

2017-10-01

The single crystals of 3-aminopyridinium 2,4-dinitrophenolate (APDP) have been synthesized and grown by slow evaporation technique at room temperature. The crystal system was identified and lattice dimensions were measured from the single-crystal X-ray diffraction (SXRD) analysis. UV-visible absorption and transmittance spectra have been recorded in the region between 250 and 1100 nm. The different vibrational modes of the molecule were studied by Fourier transform infrared (FTIR) spectroscopic analysis. The decreasing tendency of dielectric constant with increasing frequency was analysed in dielectric study. The polarizability value calculated using Penn analysis well agrees with the value calculated using Clausius-Mossotti equation. The photoconductivity and photoluminescence behaviour were also studied on grown APDP crystal. The mechanical strength of the crystal has been studied using a Vickers' microhardness test. The stiffness constant and yield strength of the crystal were also calculated from the microhardness test. The third-order nonlinear optical parameters such as refractive index, absorption coefficient and third-order susceptibility were estimated by Z-scan studies.

Transfer function of radio over fiber multimode fiber optic links considering third-order dispersion.

PubMed

Capmany, J; Gasulla, Ivana

2007-08-20

Although a considerable number of multimode fiber (MMF) links operate in a wavelength region around 850 nm where chromatic dispersion of a given modal group mu is described adequately by the second derivative beta(mu) (2) of the propagation constant beta(mu)(omega), there is also an increasing interest in MMF links transmitting in the second spectral window (@1300nm) where this second derivative vanishes being thus necessary to consider the third derivative beta(mu) (3) in the evaluation of the transfer function of the multimode fiber link. We present in this paper, for the first time to our knowledge, an analytical model for the transfer function of a multimode fiber (MMF) optic link taken into account the impact of third-order dispersion. The model extends the operation of a previously reported one for second-order dispersion. Our results show that the performance of broadband radio over fiber transmission through middle-reach distances can be improved by working at the minimum-dispersion wavelength as long as low-linewidth lasers are employed.

Single nano-hole as a new effective nonlinear element for third-harmonic generation

NASA Astrophysics Data System (ADS)

Melentiev, P. N.; Konstantinova, T. V.; Afanasiev, A. E.; Kuzin, A. A.; Baturin, A. S.; Tausenev, A. V.; Konyaschenko, A. V.; Balykin, V. I.

2013-07-01

In this letter, we report on a particularly strong optical nonlinearity at the nanometer scale in aluminum. A strong optical nonlinearity of the third order was demonstrated on a single nanoslit. Single nanoslits of different aspect ratio were excited by a laser pulse (120 fs) at the wavelength 1.5 μm, leading predominantly to third-harmonic generation (THG). It has been shown that strong surface plasmon resonance in a nanoslit allows the realization of an effective nanolocalized source of third-harmonic radiation. We show also that a nanoslit in a metal film has a significant advantage in nonlinear processes over its Babinet complementary nanostructure (nanorod): the effective abstraction of heat in a film with a slit makes it possible to use much higher laser radiation intensities.

Enhancing light-atom interactions via atomic bunching

NASA Astrophysics Data System (ADS)

Schmittberger, Bonnie L.; Gauthier, Daniel J.

2014-07-01

There is a broad interest in enhancing the strength of light-atom interactions to the point where injecting a single photon induces a nonlinear material response. Here we show theoretically that sub-Doppler-cooled two-level atoms that are spatially organized by weak optical fields give rise to a nonlinear material response that is greatly enhanced beyond that attainable in a homogeneous gas. Specifically, in the regime where the intensity of the applied optical fields is much less than the off-resonance saturation intensity, we show that the third-order nonlinear susceptibility scales inversely with atomic temperature and, due to this scaling, can be two orders of magnitude larger than that of a homogeneous gas for typical experimental parameters. As a result, we predict that spatially bunched two-level atoms can exhibit single-photon nonlinearities. Our model is valid for all regimes of atomic bunching and simultaneously accounts for the backaction of the atoms on the optical fields. Our results agree with previous theoretical and experimental results for light-atom interactions that have considered only limited regimes of atomic bunching. For lattice beams tuned to the low-frequency side of the atomic transition, we find that the nonlinearity transitions from a self-focusing type to a self-defocusing type at a critical intensity. We also show that higher than third-order nonlinear optical susceptibilities are significant in the regime where the dipole potential energy is on the order of the atomic thermal energy. We therefore find that it is crucial to retain high-order nonlinearities to accurately predict interactions of laser fields with spatially organized ultracold atoms. The model presented here is a foundation for modeling low-light-level nonlinear optical processes for ultracold atoms in optical lattices.

Zn doped CdO thin films with enhanced linear and third order nonlinear optical properties for optoelectronic applications

NASA Astrophysics Data System (ADS)

Bairy, Raghavendra; Jayarama, A.; Shivakumar, G. K.; Patil, P. S.; Bhat, K. Udaya

2018-04-01

Thin films of undoped and zinc doped CdO have been deposited on glass substrate using spray pyrolysis technique with various dopant concentrations of Zn such as 1, 5 and 10%. Influence of Zn doping on CdO thin films for the structural, morphological, optical and nonlinear optical properties are reported. XRD analysis reveals that as prepared pure and Zn doped CdO films show polycrystalline nature with face centered cubic structure. Also, Zn doping does not significantly modify the crystallinity and not much increase in the crystallite size of the film. SEM images shows grains which are uniform and grain size with increase in dopant concentration. The transmittance of the prepared CdO films recorded in the UV visible spectra and it shows 50 to 60% in the visible region. The estimated optical band gap increases from 2.60 to 2.70 eV for various dopant concentrations. The nonlinear optical absorption of Zn-doped CdO films have been measured used the Z-scan technique at a wavelength 532 nm. The nonlinear optical absorption coefficient (β), nonlinear refractive index (n2) and the third order nonlinear optical susceptibility (χ(3)) of the pure and Zn doped films were determined.

Structural characterizations, Hirshfeld surface analyses, and third-order nonlinear optical properties of two novel chalcone derivatives

NASA Astrophysics Data System (ADS)

Maidur, Shivaraj R.; Jahagirdar, Jitendra R.; Patil, Parutagouda Shankaragouda; Chia, Tze Shyang; Quah, Ching Kheng

2018-01-01

We report synthesis, characterizations, structure-property relationships, and third-order nonlinear optical studies for two new chalcone derivatives, (2E)-1-(anthracen-9-yl)-3-(4-bromophenyl)prop-2-en-1-one (Br-ANC) and (2E)-1-(anthracen-9-yl)-3-(4-chlorophenyl)prop-2-en-1-one (Cl-ANC). These derivatives were crystallized in the centrosymmetric monoclinic P21/c crystal structure. The intermolecular interactions of both the crystals were visualized by Hirshfeld surface analyses (HSA). The crystals are thermally stable up to their melting points (180.82 and 191.16 °C for Cl-ANC and Br-ANC, respectively). The geometry optimizations, FT-IR spectra, 1H and 13C NMR spectra, electronic absorption spectra, electronic transitions, and HOMO-LUMO energy gaps were studied by Density Functional Theory (DFT) at B3LYP/6-311+G(d, p) level. The theoretical results provide excellent agreement with experimental findings. The electric dipole moments, static polarizabilities, molecular electrostatic potentials (MEP) and global chemical reactivity descriptors (GCRD) were also theoretically computed. The materials exhibited good nonlinear absorption (NLA), nonlinear refraction (NLR) and optical limiting (OL) behavior under diode-pumped solid-state (DPSS) continuous wave (CW) laser excitation (532 nm and 200 mW). The NLO parameters such as NLA coefficient (β∼10-5 cmW-1), NLR index (n2∼10-10 cm2 W-1) and third-order NLO susceptibilities (χ(3) ∼10-7 esu) were measured. Further, we estimated one-photon and two-photon figures of merit, which satisfy the demands (W > 1 and T < 1) for all-optical switching. Thus, the present chalcone derivatives with anthracene moiety are potential materials for OL and optical switching applications.

Third-order-harmonic generation in coherently spinning molecules

NASA Astrophysics Data System (ADS)

Prost, E.; Zhang, H.; Hertz, E.; Billard, F.; Lavorel, B.; Bejot, P.; Zyss, Joseph; Averbukh, Ilya Sh.; Faucher, O.

2017-10-01

The rotational Doppler effect occurs when circularly polarized light interacts with a rotating anisotropic material. It is manifested by the appearance of a spectral shift ensuing from the transfer of angular momentum and energy between radiation and matter. Recently, we reported terahertz-range rotational Doppler shifts produced in third-order nonlinear optical conversion [O. Faucher et al., Phys. Rev. A 94, 051402(R) (2016), 10.1103/PhysRevA.94.051402]. The experiment was performed in an ensemble of coherently spinning molecules prepared by a short laser pulse exhibiting a twisted linear polarization. The present work provides an extensive analysis of the rotational Doppler effect in third-order-harmonic generation from spinning linear molecules. The underlying physics is investigated both experimentally and theoretically. The implication of the rotational Doppler effect in higher-order processes like high-order-harmonic generation is discussed.

Enhanced third-harmonic generation in silicon nanoparticles driven by magnetic response.

PubMed

Shcherbakov, Maxim R; Neshev, Dragomir N; Hopkins, Ben; Shorokhov, Alexander S; Staude, Isabelle; Melik-Gaykazyan, Elizaveta V; Decker, Manuel; Ezhov, Alexander A; Miroshnichenko, Andrey E; Brener, Igal; Fedyanin, Andrey A; Kivshar, Yuri S

2014-11-12

We observe enhanced third-harmonic generation from silicon nanodisks exhibiting both electric and magnetic dipolar resonances. Experimental characterization of the nonlinear optical response through third-harmonic microscopy and spectroscopy reveals that the third-harmonic generation is significantly enhanced in the vicinity of the magnetic dipole resonances. The field localization at the magnetic resonance results in two orders of magnitude enhancement of the harmonic intensity with respect to unstructured bulk silicon with the conversion efficiency limited only by the two-photon absorption in the substrate.

Nonlinear optics and crystalline whispering gallery mode resonators

NASA Technical Reports Server (NTRS)

Matsko, Andrey B.; Savchenkov, Anatoliy A.; Ilchenko, Vladimir S.; Maleki, Lute

2004-01-01

We report on our recent results concerning fabrication of high-Q whispering gallery mode (WGM) crystalline resonators, and discuss some possible applications of lithium niobate WGM resonators in nonlinear optics and photonics. In particular, we demonstrate experimentally a tunable third-order optical filter fabricated from the three metalized resonators; and report observation of parametric frequency dobuling in a WGM resonator made of periodically poled lithium niobate (PPLN).

Theoretical and experimental evaluation of a new organic proton transfer crystal aminoguanidinium p-nitrobenzoate monohydrate for optical limiting applications

NASA Astrophysics Data System (ADS)

Shanmugavadivu, T.; Senthilkumar, K.; Dhandapani, M.; Muthuraja, P.; Balachandar, S.; Sethu Raman, M.

2017-12-01

Aminoguanidinium p-nitrobenzoate monohydrate (AGPNB), an organic third order nonlinear crystal, was successfully grown by the slow evaporation technique. Single crystal XRD analysis reveals that the grown crystal belongs to monoclinic system with P21/n space group. FT-IR, 1H and 13C NMR spectroscopic studies were carried out to confirm the proton transfer. Optical and thermal suitability were assessed by UV-NIR and TG-DTA studies. Hirshfeld surface analysis predicts that the O⋯H/H⋯O interactions dominated over the crystal structure. Third order nonlinearity was studied by Z-scan analysis and it is found that AGPNB can be used as a reverse satuarble absorption (RSA) based optical limiter at 632.8 nm. Computational studies, such as geometry optimization, Natural bond orbital (NBO) analysis, Mulliken population analysis and Molecular electrostatic potential (MEP) were performed at B3LYP/6-311G(d,p) level of theory. The calculated first order hyperpolarizability of AGPNB is found to be 35 times that of urea.

Third-order nonlinear optical properties of methylammonium lead halide perovskite films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, Justin C.; Li, Zhen; Ndione, Paul F.

2016-01-01

We report third-order nonlinear coefficient values and decay time kinetics vs. halide composition (CH3NH3PbBr3 and CH3NH3PbBr2I), temperature, and excitation wavelength. The maximum values of the third-order nonlinear susceptibility X(3) (-1.6 x 10-6 esu) are similar to or larger than many common third-order materials. The source of the nonlinearity is shown to be primarily excitonic in the tribromide film by virtue of its strong enhancement near the exciton resonance. Nonresonant excitation reduces the nonlinearity significantly, as does increasing the temperature. Substitution of one I for one Br also reduces the nonlinearity by at least one order of magnitude, presumably due tomore » the lack of strong exciton resonance in the substituted form. The thin films are stable, highly homogenous (lacking significant light scattering), and simple and inexpensive to fabricate, making them potentially useful in a variety of optoelectronic applications in which wavelength selectivity is important.« less

Contribution to the development of low frequency terahertz coherent Raman micro-spectroscopy and microscopy

NASA Astrophysics Data System (ADS)

Ujj, Laszlo

2018-06-01

We report the construction and characterization of a coherent Raman tabletop system utilizing a novel astigmatic optical focusing geometry, a broadband nanosecond optical parametric oscillator and volumetric Bragg filters assisting 3CBCRS measuring system for the first time. In order to illustrate the versatility of the measurements and reveal the molecular information obtainable, two well-characterized chemicals were selected. Polarization sensitive epi-detected 3CBCRS spectra of liquid CCl4 and calcite crystal were recorded and analyzed. An unexpected polarization dependence of the signals of the lowest frequency modes of CCl4 was observed. The 1122 third order susceptibility component was phase flipped. The non-resonant susceptibility normalized 1122 component was found to be larger than the 1111 component for the lowest vibrational modes. This anomalous comportment was attributable to the anisotropy Raman tensor invariant in the third order nonlinear susceptibility tensor.

Key functions analysis of a novel nonlinear optical D-π-A bridge type (2E)-3-(4-Methylphenyl)-1-(3-nitrophenyl) prop-2-en-1-one chalcone: An experimental and theoretical approach

NASA Astrophysics Data System (ADS)

Patil, Parutagouda Shankaragouda; Shkir, Mohd; Maidur, Shivaraj R.; AlFaify, S.; Arora, M.; Rao, S. Venugopal; Abbas, Haider; Ganesh, V.

2017-10-01

In the current work a new third-order nonlinear optical organic single crystal of (2E)-3-(4-Methylphenyl)-1-(3-nitrophenyl) prop-2-en-1-one (ML3NC) has been grown with well-defined morphology using the slow evaporation solution growth technique. X-ray diffraction technique was used to confirm the crystal system. The presence of functional groups in the molecular structure was identified by robust FT-IR and FT-Raman spectra by experimental and theoretical analysis. The ultraviolet-visible-near infrared and photoluminescence studies shows that the grown crystals possess excellent transparency window and green emission band (∼560 nm) confirms their use in green OLEDs. The third-order nonlinear and optical limiting studies have been performed using femtosecond (fs) Z-scan technique. The third-order nonlinear optical susceptibility (χ(3)), second-order hyperpolarizability (γ), nonlinear refractive index (n2) and limiting threshold values are found to be 4.03 × 10-12 esu, 14.2 × 10-32 esu, -4.33 × 10-14 cm2/W and 2.41 mJ/cm2, respectively. Furthermore, the quantum chemical studies were carried out to achieve the ground state molecular geometry and correlate with experimental results. The experimental value of absorption wavelength (λabs = 328 nm) is found to be in excellent accord with the theoretical value (λabs = 328 nm) at TD-DFT/B3LYP/6-31G* level of theory. To understand the static and dynamic NLO behavior, the polarizability (α) and second hyperpolarizability (γ) values were determined using TD-HF method. The computed second hyperpolarizability γ(-3ω; ω,ω,ω) at 800 nm wavelength was found to be 0.499 × 10-32 esu which is in good agreement with experimental value at the same wavelength. These results confirms the applied nature of title molecule in optoelectronic and nonlinear optical devices.

Effect of halogenation on the nonlinear optical properties of porthyrin and substituted porphyrins

NASA Technical Reports Server (NTRS)

Cardelino, Beatriz H.; Moore, Craig E.; Benloss, Angela; Thompson, Albert N., Jr.; Richards, Rosalie A.; Roney, Celeste A.; Sanghadasa, Mohan

1998-01-01

The effect that fluorine and chlorine substitution has on the nonlinear optical properties of porphyrin, tetramethylporphyrin and tetraphenylporphyrin has been theoretically studied. The calculations of nonlinear optical properties have been obtained by performing finite-field calculations on structures determined by semiempirical methods. In addition, tetra(p-chlorophenyl)porphyrin and tetra(p-bromophenyl)porphyrin were synthesized by the condensation of pyrrol and the appropriate aldehyde. Thin films of polymethylmethacrylate were obtained containing these materials, by spin coating onto glass substrates. The films were characterized by third-harmonic generation. It was determined that the experimental conditions enhance the third-order polarizability of the tetraphenylporphyrins by a factor of about 1.6.

Growth and characterization of a third order nonlinear optical single crystal: Ethylenediamine-4-nitrophenolate monohydrate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dhanalakshmi, B.; Ponnusamy, S., E-mail: suruponnus@gmail.com; Muthamizhchelvan, C.

2015-10-15

Highlights: • EDA4NPH crystal possesses negative nonlinear refractive index. • The crystal exhibits high third-order NLO susceptibility. • Wide transparency of the crystal makes it suitable for NLO applications. • Dielectric studies substantiate the suitability for electro-optic applications. • The crystal possesses suitable mechanical strength for device fabrication. - Abstract: Bulk crystals of the charge-transfer complex, ethylenediamine-4-nitrophenolate monohydrate, were grown by slow solvent evaporation method from aqueous solution at room temperature. The X-ray diffraction measurements showed that the crystal belongs to centrosymmetric space group C2/c of monoclinic system. The functional groups in the complex were identified using FTIR, FTRaman andmore » FTNMR analyses. The Z-scan measurements revealed the negative nonlinear refractive index of the crystal. The nonlinear absorption coefficient and third order nonlinear optical susceptibility calculated from the measurements were −3.5823 × 10{sup −3} cm/W and 2.3762 × 10{sup −6} esu respectively. The crystal was shown to be highly transparent above 366 nm by UV–vis spectroscopy and a yellow fluorescence was observed from PL spectrum. The TG–DTA and DSC analyses showed that the crystal is thermally stable up to 117.4 °C. The crystals were characterized by dielectric, etching and microhardness studies.« less

Third order nonlinear optical properties of bismuth zinc borate glasses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shanmugavelu, B.; Ravi Kanth Kumar, V. V., E-mail: ravi.phy@pondiuni.edu.in; Kuladeep, R.

2013-12-28

Third order nonlinear optical characterization of bismuth zinc borate glasses are reported here using different laser pulse durations. Bismuth zinc borate glasses with compositions xBi{sub 2}O{sub 3}-30ZnO-(70-x) B{sub 2}O{sub 3} (where x = 30, 35, 40, and 45 mol. %) have been prepared by melt quenching method. These glasses were characterized by Raman, UV-Vis absorption, and Z scan measurements. Raman and UV-Vis spectroscopic results indicate that non-bridging oxygens increase with increase of bismuth content in the glass. Nonlinear absorption and refraction behavior in the nanosecond (ns), picosecond (ps), and femtosecond (fs) time domains were studied in detail. Strong reverse saturable absorption due tomore » dominant two-photon absorption (TPA) was observed with both ps and fs excitations. In the case of ns pulse excitations, TPA and free-carrier absorption processes contribute for the nonlinear absorption. Two-photon absorption coefficient (β) and the absorption cross section due to free carriers (σ{sub e}) are estimated by theoretical fit of the open aperture Z-scan measurements and found to be dependent on the amount of bismuth oxide in the glass composition. In both ns and fs regimes the sign and magnitude of the third order nonlinearity are evaluated, and the optical limiting characteristics are also reported.« less

Ultrafast carrier dynamics and third-order nonlinear optical properties of AgInS2/ZnS nanocrystals

NASA Astrophysics Data System (ADS)

Yu, Kuai; Yang, Yang; Wang, Junzhong; Tang, Xiaosheng; Xu, Qing-Hua; Wang, Guo Ping

2018-06-01

Broad photoluminescence (PL) emission, a large Stokes shift and extremely long-lived radiative lifetimes are the characteristics of ternary I–III–VI semiconductor nanocrystals (NCs), such as CuInS2 and AgInS2. However, the lack of understanding regarding the intriguing PL mechanisms and photo-carrier dynamics limits their further applications. Here, AgInS2 and AgInS2/ZnS NCs were chemically synthesized and their carrier dynamics were studied by time-resolved PL spectroscopy. The results demonstrated that the surface defect state, which contributed dominantly to the non-radiative decay processes, was effectively passivated through ZnS alloying. Femtosecond transient absorption spectroscopy was also used to investigate the carrier dynamics, revealing the electron storage at the surface state and donor state. Furthermore, the two photon absorption properties of AgInS2 and AgInS2/ZnS NCs were measured using an open-aperture Z-scan technique. The improved third-order nonlinear susceptibility {χ }(3) of AgInS2 through ZnS alloying demonstrates potential application in two photon PL biological imaging.

Synthesis, growth, crystal structure, optical and third order nonlinear optical properties of quinolinium derivative single crystal: PNQI

NASA Astrophysics Data System (ADS)

Karthigha, S.; Krishnamoorthi, C.

2018-03-01

An organic quinolinium derivative nonlinear optical (NLO) crystal, 1-ethyl-2-[2-(4-nitro-phenyl)-vinyl]-quinolinium iodide (PNQI) was synthesized and successfully grown by slow evaporation solution growth technique. Formation of a crystalline compound was confirmed by single crystal X-ray diffraction. The quinolinium compound PNQI crystallizes in the triclinic crystal system with a centrosymmetric space group of P-1 symmetry. The molecular structure of PNQI was confirmed by 1H NMR and 13C NMR spectral studies. The thermal properties of the crystal have been investigated by thermogravimetric (TG) and differential scanning calorimetry (DSC) studies. The optical characteristics obtained from UV-Vis-NIR spectral data were described and the cut-off wavelength observed at 506 nm. The etching study was performed to analyse the growth features of PNQI single crystal. The third order NLO properties such as nonlinear refractive index (n2), nonlinear absorption coefficient (β) and nonlinear susceptibility (χ (3)) of the crystal were investigated using Z-scan technique at 632.8 nm of Hesbnd Ne laser.

Third order nonlinear optical properties of a paratellurite single crystal

NASA Astrophysics Data System (ADS)

Duclère, J.-R.; Hayakawa, T.; Roginskii, E. M.; Smirnov, M. B.; Mirgorodsky, A.; Couderc, V.; Masson, O.; Colas, M.; Noguera, O.; Rodriguez, V.; Thomas, P.

2018-05-01

The (a,b) plane angular dependence of the third-order nonlinear optical susceptibility, χ(3) , of a c-cut paratellurite (α-TeO2) single crystal was quantitatively evaluated here by the Z-scan technique, using a Ti:sapphire femtosecond laser operated at 800 nm. In particular, the mean value Re( ⟨χ(3)⟩a,b )(α-TeO2) of the optical tensor has been extracted from such experiments via a direct comparison with the data collected for a fused silica reference glass plate. A R e (⟨χ(3)⟩(a,b )(α-TeO2)):R e (χ(3))(SiO2 glass) ratio roughly equal to 49.1 is found, and our result compares thus very favourably with the unique experimental value (a ratio of ˜50) reported by Kim et al. [J. Am. Ceram. Soc. 76, 2486 (1993)] for a pure TeO2 glass. In addition, it is shown that the angular dependence of the phase modulation within the (a,b) plane can be fully understood in the light of the strong dextro-rotatory power known for TeO2 materials. Taking into account the optical activity, some analytical model serving to estimate the diagonal and non-diagonal components of the third order nonlinear susceptibility tensor has been thus developed. Finally, Re( χxxxx(3) ) and Re( χxxyy(3) ) values of 95.1 ×10-22 m 2/V2 and 42.0 ×10-22 m2/V2 , respectively, are then deduced for a paratellurite single crystal, considering fused silica as a reference.

Mid-infrared-to-mid-ultraviolet supercontinuum enhanced by third-to-fifteenth odd harmonics.

PubMed

Mitrofanov, A V; Voronin, A A; Mitryukovskiy, S I; Sidorov-Biryukov, D A; Pugžlys, A; Andriukaitis, G; Flöry, T; Stepanov, E A; Fedotov, A B; Baltuška, A; Zheltikov, A M

2015-05-01

A high-energy supercontinuum spanning 4.7 octaves, from 250 to 6500 nm, is generated using a 0.3-TW, 3.9-μm output of a mid-infrared optical parametric chirped-pulse amplifier as a driver inducing a laser filament in the air. The high-frequency wing of the supercontinuum spectrum is enhanced by odd-order optical harmonics of the mid-infrared driver. Optical harmonics up to the 15th order are observed in supercontinuum spectra as overlapping, yet well-resolved peaks broadened, as verified by numerical modeling, due to spatially nonuniform ionization-induced blue shift.

Large-scale quantum photonic circuits in silicon

NASA Astrophysics Data System (ADS)

Harris, Nicholas C.; Bunandar, Darius; Pant, Mihir; Steinbrecher, Greg R.; Mower, Jacob; Prabhu, Mihika; Baehr-Jones, Tom; Hochberg, Michael; Englund, Dirk

2016-08-01

Quantum information science offers inherently more powerful methods for communication, computation, and precision measurement that take advantage of quantum superposition and entanglement. In recent years, theoretical and experimental advances in quantum computing and simulation with photons have spurred great interest in developing large photonic entangled states that challenge today's classical computers. As experiments have increased in complexity, there has been an increasing need to transition bulk optics experiments to integrated photonics platforms to control more spatial modes with higher fidelity and phase stability. The silicon-on-insulator (SOI) nanophotonics platform offers new possibilities for quantum optics, including the integration of bright, nonclassical light sources, based on the large third-order nonlinearity (χ(3)) of silicon, alongside quantum state manipulation circuits with thousands of optical elements, all on a single phase-stable chip. How large do these photonic systems need to be? Recent theoretical work on Boson Sampling suggests that even the problem of sampling from e30 identical photons, having passed through an interferometer of hundreds of modes, becomes challenging for classical computers. While experiments of this size are still challenging, the SOI platform has the required component density to enable low-loss and programmable interferometers for manipulating hundreds of spatial modes. Here, we discuss the SOI nanophotonics platform for quantum photonic circuits with hundreds-to-thousands of optical elements and the associated challenges. We compare SOI to competing technologies in terms of requirements for quantum optical systems. We review recent results on large-scale quantum state evolution circuits and strategies for realizing high-fidelity heralded gates with imperfect, practical systems. Next, we review recent results on silicon photonics-based photon-pair sources and device architectures, and we discuss a path towards large-scale source integration. Finally, we review monolithic integration strategies for single-photon detectors and their essential role in on-chip feed forward operations.

Third-order nonlinear optical properties of ADP crystal

NASA Astrophysics Data System (ADS)

Wang, Mengxia; Wang, Zhengping; Chai, Xiangxu; Sun, Yuxiang; Sui, Tingting; Sun, Xun; Xu, Xinguang

2018-05-01

By using the Z-scan method, we investigated the third-order nonlinear optical (NLO) properties of ADP crystal at different wavelengths (355, 532, and 1064 nm) and different orientations ([001], [100], [110], I and II). The experimental data were fitted by NLO theory, to give out the two photon absorption (TPA) coefficient β 2 and the nonlinear refractive index n 2. When the light source changed from a 40 ps, 1064 nm fundamental laser to a 30 ps, 355 nm third-harmonic-generation (THG) laser, the β 2 value increased about 5 times (0.2 × 10‑2 → 1 × 10‑2 cm GW‑1), and the n 2 value increased about 1.5 times (1.5 × 10‑16 → 2.2 × 10‑16 cm2 W‑1). Among all of the orientations, the [110] sample exhibits the smallest β 2, and the second smallest n 2. It indicates that this orientation and its surroundings will be the preferred directions for high-power laser applications of ADP crystal.

Experimental observation of breathing solitons and a third harmonic in a tapered photonic crystal fiber

NASA Astrophysics Data System (ADS)

Wang, F.; Yao, C. F.; Li, C. Z.; Jia, Z. X.; Li, Q.; Wu, C. F.; Ohishi, Y.; Qin, W. P.; Qin, G. S.

2018-02-01

We report the experimental observation of breathing solitons and a third harmonic in a tapered fluorotellurite photonic crystal fiber (PCF) pumped by a 1560 nm femtosecond fiber laser. The PCF has a core diameter that varies continuously along its length, resulting in a zero-dispersion wavelength that moves from 1325 nm to 906 nm over the transition region. By finely controlling the dispersion map of the tapered PCF and increasing the order of the optical solitons, their breathing behavior is observed in the frequency domain and the number of breaths goes up to 9. Furthermore, the breathing behavior of the optical soliton is transferred to the third harmonic through inter-modal phase-matched processes in the tapered PCF, and the third harmonic also breathes with an increase in the pump power.

Second- and third-order nonlinear optical properties of unsubstituted and mono-substituted chalcones

NASA Astrophysics Data System (ADS)

Abegão, Luis M. G.; Fonseca, Ruben D.; Santos, Francisco A.; Souza, Gabriela B.; Barreiros, André Luis B. S.; Barreiros, Marizeth L.; Alencar, M. A. R. C.; Mendonça, Cleber R.; Silva, Daniel L.; De Boni, Leonardo; Rodrigues, J. J.

2016-03-01

This work describes the second and third orders of nonlinear optics properties of unsubstituted chalcone (C15H12O) and mono-substituted chalcone (C16H14O2) in solution, using hyper-Rayleigh scattering and Z-Scan techniques to determine the first molecular hyperpolarizability (β) and the two-photon absorption (2PA) cross section respectively. β Values of 25.4 × 10-30 esu and 31.6 × 10-30 esu, for unsubstituted and mono-substituted chalcone, respectively, dissolved in methanol have been obtained. The highest values of 2PA cross-sections obtained were 9 GM and 14 GM for unsubstituted and mono-substituted chalcone, respectively. The experimental 2PA cross sections obtained for each chalcone are in good agreement with theoretical results.

Third-order dissipative hydrodynamics from the entropy principle

NASA Astrophysics Data System (ADS)

El, Andrej; Xu, Zhe; Greiner, Carsten

2010-06-01

We review the entropy based derivation of third-order hydrodynamic equations and compare their solutions in one-dimensional boost-invariant geometry with calculations by the partonic cascade BAMPS. We demonstrate that Grad's approximation, which underlies the derivation of both Israel-Stewart and third-order equations, describes the transverse spectra from BAMPS with high accuracy. At the same time solutions of third-order equations are much closer to BAMPS results than solutions of Israel-Stewart equations. Introducing a resummation scheme for all higher-oder corrections to one-dimensional hydrodynamic equation we demonstrate the importance of higher-order terms if the Knudsen number is large.

Mechanisms of the Third-Order Nonlinear Optical Response in Dye-Doped Polymers.

NASA Astrophysics Data System (ADS)

Poga, Constantina

Quadratic Electroabsorption is applied to thin -film solid solutions of squarylium dye molecules in poly(methyl methacrylate) polymer to study the mechanisms in the third order nonlinear optical susceptibility. The data are interpreted with the help of a generalized quadratic electrooptic response theory that includes both electronic and hindered molecular motion mechanisms. This theory predicts the tensor ratio of two independent third order susceptibility tensor components, chi_sp{3333}{(3)}/ chi_sp{1133}{(3)}, whose value distinctly characterizes the relative contribution of each mechanism. Although thickness change mechanisms have not been included in this theory, their effect on the tensor ratio chi_sp{3333 }{(3)}/chi_sp{1133} {(3)} has been taken into account for both electrostriction and electrode attraction mechanisms. We measure the tensor ratio with quadratic electroabsorption spectroscopy as a function of temperature and wavelength and find that the response is predominantly electronic at temperatures below the glass transition temperature, but at temperatures higher than the glass transition temperature both reorientational and thickness changes effects play a dominant role. In particular, the contribution of each mechanism has been found for all wavelengths in the visible and the dominant thickness change mechanism has been identified to be electrode attraction. Additionally, the real part of the third-order nonlinear susceptibility can be found through a Kramers-Kronig transformation of the experimentally measured imaginary part. The knowledge of both the real and imaginary part in the visible allows the calculation of the two-photon figure of merit (defined as the real over the imaginary part of chi^{(3) }) which is necessary for determining a material's suitability for all-optical devices. Furthermore, quadratic electroabsorption can be used to characterize the nature of the excited states which in turn can be used to understand the source of the electronic response. For the ISQ chromophore, a one-photon state (at 657nm) and a two-photon state (at 596nm) have been found, and a three-level fit based on these states has been successful in predicting the low temperature chi^{(3)}^ectrum. Quadratic electroabsorption has been proven to be a versatile tool to study the mechanisms of the third -order nonlinear optical response, to measure the electronic gamma, to study the symmetry of the excited states of a molecule and to characterize the suitability of a material for all-optical devices. In this chapter, we start by calculating the change in the imaginary part of the refractive index under the application of an electric field and proceed with connecting this change with the quantities that are experimentally measured by the quadratic electroabsorption experiment. The sample preparation and the data collection are also described.

Studies on the growth, structural, spectral and third-order nonlinear optical properties of ammonium 3-carboxy-4-hydroxy benzenesulfonate monohydrate single crystal.

PubMed

Silambarasan, A; Krishna Kumar, M; Thirunavukkarasu, A; Mohan Kumar, R; Umarani, P R

2015-01-25

An organic nonlinear optical bulk single crystal, Ammonium 3-carboxy-4-hydroxy benzenesulfonate monohydrate (ACHBS) was successfully grown by solution growth technique. Single crystal X-ray diffraction study confirms that, the grown crystal belongs to P21/c space group. Powder X-ray diffraction and high resolution X-ray diffraction analyses revealed the crystallinity of the grown crystal. Infrared spectral analysis showed the vibrational behavior of chemical bonds and its functional groups. The thermal stability and decomposition stages of the grown crystal were studied by TG-DTA analysis. UV-Visible transmittance studies showed the transparency region and cut-off wavelength of the grown crystal. The third-order nonlinear optical susceptibility of the grown crystal was estimated by Z-scan technique using He-Ne laser source. The mechanical property of the grown crystal was studied by using Vicker's microhardness test. Copyright © 2014 Elsevier B.V. All rights reserved.

Anisotropy in Third-Order Nonlinear Optical Susceptibility of a Squarylium Dye in a Nematic Liquid Crystal

NASA Astrophysics Data System (ADS)

Jin, Zhao-Hui; Li, Zhong-Yu; Kasatani, Kazuo; Okamoto, Hiroaki

2006-03-01

A squarylium dye is dissolved in 4-cyano-4'-pentylbiphenyl (5CB) and oriented by sandwiching mixtures between two pieces of rubbed glass plates. The optical absorption spectra of the oriented squarylium dye-5CB layers exhibit high anisotropy. The third-order nonlinear optical responses and susceptibilities χ(3)e of squarylium dye in 5CB are measured with light polarizations parallel and perpendicular to the orientational direction by the resonant femtosecond degenerate four-wave mixing (DFWM) technique. Temporal profiles of the DFWM signal of the oriented squarylium dye-5CB layers with light polarizations parallel and perpendicular to the orientational direction are measured with a time resolution of 0.3 ps (FWHM), and are found to consist of two components, i.e., the coherent instantaneous nonlinear response and slow response due to the formation of excited molecules. A high anisotropic ratio of χ(3)e, 10.8±1.2, is observed for the oriented layers.

The Geometrical Optics PSF with Third Order Aberrations

NASA Astrophysics Data System (ADS)

Díaz-Uribe, Rufino; Campos-García, Manuel

2008-04-01

In this paper the calculation of the GPSF from the Geometrical Optics Irradiance Law (GOIL) is recalled, including some details not found in other references. Also it is explored an alternative solution based on the Irradiance Transport Equation (ITE). Some simulations of images of an extended object produced by an image forming instrument affected by spherical aberration are shown.

Measuring the molecular second hyperpolarizability in absorptive solutions by the third harmonic generation ratio technique.

PubMed

Tokarz, Danielle; Cisek, Richard; Prent, Nicole; Fekl, Ulrich; Barzda, Virginijus

2012-11-28

Measurement of the second hyperpolarizability (γ) values of compounds can provide insight into the molecular structural requirements for enhancement of third harmonic generation (THG) signal. A convenient method for measuring the γ of compounds in solutions was developed by implementing the THG ratio method which is based on measuring the THG intensity from two interfaces using a nonlinear optical microscope while accounting for the refractive index of solutions at the fundamental and third harmonic wavelengths. We demonstrated that the difference in refractive index at both wavelengths strongly influenced the calculation of γ values when compounds have absorption near the third harmonic or fundamental wavelength. To this end, a refractometer with the wavelength tuning range from UV to near IR was constructed, and the measured refractive indices were used to extract the γ values. The γ values of carotenoids and chlorophylls found in photosynthetic pigment-protein complexes were explored. Large differences in the refractive index at third harmonic and fundamental wavelengths for chlorophylls result in γ values that are more than two orders of magnitude larger than γ values for carotenoids as well as the sign of chlorophylls'γ values is negative while carotenoids have positive γ values. Copyright © 2012 Elsevier B.V. All rights reserved.

Precise and absolute measurements of complex third-order optical susceptibility

NASA Astrophysics Data System (ADS)

Santran, Stephane; Canioni, Lionel; Cardinal, Thierry; Fargin, Evelyne; Le Flem, Gilles; Rouyer, Claude; Sarger, Laurent

2000-11-01

We present precise and absolute measurements of full complex third order optical susceptibility on different fused silica and original glasses composed of tellurium, titanium, niobium erbium. These materials are designed to be the key point for applications ranging form high power laser systems to optoelectronics, their nonlinear index of refraction is a major property and thus must be accurately known. Due to the accuracy and sensitivity of our technique, we have been able to find a large dispersion (more than 30%) of the non linear index of fused silica glasses as a function of their processing mode. On the other hand, measurements on tellurium glasses have shown very strong nonlinearities (40 times higher than fused silica), to be linked to the configurations of their cations and anions. Although the titanium and niobium glasses are less nonlinear, they can be promising matrices for addition of luminescent entities like erbium leading to very interesting laser amplification materials. The experimental set-up is a collinear pump-probe (orthogonally polarized) experiment using transient absorption technique. It is built with around a 100 femtosecond laser oscillator. A fast oscillating delay between the pump and the probe allows us to measure the electronic nonlinearity in quasi real-time. This experiment has the following specifications: an absolute measurement accuracy below 10% mainly due to the laser parameters characterization, a relative measurement accuracy of 1% and a resolution less than 5.10-24m2/V2(50 times less than fused silica).

Creating a zero-order resonator using an optical surface transformation

PubMed Central

Sun, Fei; Ge, Xiaochen; He, Sailing

2016-01-01

A novel zero-order resonator has been designed by an optical surface transformation (OST) method. The resonator proposed here has many novel features. Firstly, the mode volume can be very small (e.g. in the subwavelength scale). Secondly, the resonator is open (no reflecting walls are utilized) and resonant effects can be found in a continuous spectrum (i.e. a continuum of eigenmodes). Thirdly, we only need one homogenous medium to realize the proposed resonator. The shape of the resonator can be a ring structure of arbitrary shape. In addition to the natural applications (e.g. optical storage) of an optical resonator, we also suggest some other applications of our novel optical open resonator (e.g. power combination, squeezing electromagnetic energy in the free space). PMID:26888359

Optical assembly of microparticles into highly ordered structures using Ince-Gaussian beams

NASA Astrophysics Data System (ADS)

Woerdemann, Mike; Alpmann, Christina; Denz, Cornelia

2011-03-01

Ince-Gaussian (IG) beams are a third complete family of solutions of the paraxial Helmholtz equation. While many applications of Hermite-Gaussian and Laguerre-Gaussian beams have been demonstrated for manipulation of microparticles, the potential of the more general class of IG beams has not yet been exploited at all. We describe the unique properties of IG beams with respect to optical trapping applications, demonstrate a flexible experimental realization of arbitrary IG beams and prove the concept by creating two- and three-dimensional, highly ordered assemblies of typical microparticles. The concept is universal and can easily be integrated into existing holographic optical tweezers setups.

Effets optiques et structurels de l'implantation ionique dans des couches minces polymeres

NASA Astrophysics Data System (ADS)

Cottin, Pierre

The main goal of this work is to highlight the effect of ion implantation---a widely spread technique to modify chemical, electrical or optical properties of materials---on the third order nonlinear optical properties (chi (3)) of polymers. This study was limited to four polymers (PMMA, PVK, PVA, CA) for which we developed a fabrication process to obtain high optical quality thin films and controlled thickness compatible with ion implantation depth. Moreover, these polymers show different chemical structures and have in common to have very low nonlinear optical properties. Two faces of the problem were studied. First, the chemical structure of these polymers was characterized using ultraviolet and infrared spectroscopy before and after ion implantation and then was compared with which of intrinsic nonlinear optical polymers. These analysis have clearly shown that from one hand, ion implantation leads to a great number of bond breaks but from the other hand, it creates a high concentration of conjugated bonds characteristic of nonlinear optical polymers. Second, the third order nonlinear optical properties of ion implanted polymers were measured by nonlinear waveguide coupling and by third harmonic generation. For the first method, the coupling function was performed by a diffraction grating etched in a glass substrate whose fabrication process was developed in this particular case. In both cases, the used laser wave-length was 1064 nm with pulse duration of 30 ps and 5 ns respectively. The corresponding modelization for each of these techniques was established and numerically implemented. Both techniques have shown an increase of chi(3) for these polymers after ion implantation but however, they can not reach the performance of chemically designed nonlinear optical polymers. The best results were obtained for 50 keV helium implanted PMMA given |chi(3)(-3o; o, o, o)| = 7.2 x 10-21 m2.V-2 which is six time greater than the pristine material.

Enhanced Third-Order Optical Nonlinearity Driven by Surface-Plasmon Field Gradients.

PubMed

Kravtsov, Vasily; AlMutairi, Sultan; Ulbricht, Ronald; Kutayiah, A Ryan; Belyanin, Alexey; Raschke, Markus B

2018-05-18

Efficient nonlinear optical frequency mixing in small volumes is key for future on-chip photonic devices. However, the generally low conversion efficiency severely limits miniaturization to nanoscale dimensions. Here we demonstrate that gradient-field effects can provide for an efficient, conventionally dipole-forbidden nonlinear response. We show that a longitudinal nonlinear source current can dominate the third-order optical nonlinearity of the free electron response in gold in the technologically important near-IR frequency range where the nonlinearities due to other mechanisms are particularly small. Using adiabatic nanofocusing to spatially confine the excitation fields, from measurements of the 2ω_{1}-ω_{2} four-wave mixing response as a function of detuning ω_{1}-ω_{2}, we find up to 10^{-5} conversion efficiency with a gradient-field contribution to χ_{Au}^{(3)} of up to 10^{-19}  m^{2}/V^{2}. The results are in good agreement with the theory based on plasma hydrodynamics and underlying electron dynamics. The associated increase in the nonlinear conversion efficiency with a decreasing sample size, which can even overcompensate the volume decrease, offers a new approach for enhanced nonlinear nano-optics. This will enable more efficient nonlinear optical devices and the extension of coherent multidimensional spectroscopies to the nanoscale.

Enhanced Third-Order Optical Nonlinearity Driven by Surface-Plasmon Field Gradients

NASA Astrophysics Data System (ADS)

Kravtsov, Vasily; AlMutairi, Sultan; Ulbricht, Ronald; Kutayiah, A. Ryan; Belyanin, Alexey; Raschke, Markus B.

2018-05-01

Efficient nonlinear optical frequency mixing in small volumes is key for future on-chip photonic devices. However, the generally low conversion efficiency severely limits miniaturization to nanoscale dimensions. Here we demonstrate that gradient-field effects can provide for an efficient, conventionally dipole-forbidden nonlinear response. We show that a longitudinal nonlinear source current can dominate the third-order optical nonlinearity of the free electron response in gold in the technologically important near-IR frequency range where the nonlinearities due to other mechanisms are particularly small. Using adiabatic nanofocusing to spatially confine the excitation fields, from measurements of the 2 ω1-ω2 four-wave mixing response as a function of detuning ω1-ω2, we find up to 10-5 conversion efficiency with a gradient-field contribution to χAu(3 ) of up to 10-19 m2/V2 . The results are in good agreement with the theory based on plasma hydrodynamics and underlying electron dynamics. The associated increase in the nonlinear conversion efficiency with a decreasing sample size, which can even overcompensate the volume decrease, offers a new approach for enhanced nonlinear nano-optics. This will enable more efficient nonlinear optical devices and the extension of coherent multidimensional spectroscopies to the nanoscale.

Passive optical limiting studies of nanostructured Cu doped ZnO-PVA composite thin films

NASA Astrophysics Data System (ADS)

Tamgadge, Y. S.; Sunatkari, A. L.; Talwatkar, S. S.; Pahurkar, V. G.; Muley, G. G.

2016-01-01

We prepared undoped and Cu doped ZnO semiconducting nanoparticles (NPs) by chemical co-precipitation method and obtained Cu doped ZnO-polyvinyl alcohol (PVA) nanocomposite thin films by spin coating to investigate third order nonlinear optical and optical limiting properties under cw laser excitation. Powder samples of NPs were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), energy dispersive spectroscopy, transmission electron microscopy, ultraviolet-visible (UV-vis) and Fourier transform infrared spectroscopy. XRD pattern and FE-SEM micrograph revealed the presence of hexagonal wurtzite phase ZnO NPs having uniform morphology with average particle size of 20 nm. The presence of excitons and absorption peaks in the range 343-360 nm, revealed by UV-vis study, were attributed to excitons in n = 1 quantum state. Third order NLO properties of all composite thin films were investigated by He-Ne continuous wave (cw) laser of wavelength 632.8 nm using Z-scan technique. Thermally stimulated enhanced values of nonlinear refraction and absorption coefficients were obtained which may be attributed to self-defocusing effect, reverse saturable absorption, weak free carrier absorption and surface states properties originated from thermo optic effect. Optical limiting properties have been studied using cw diode laser of wavelength 808 nm and results are presented.

Gyroscopic behavior exhibited by the optical Kerr effect in bimetallic Au-Pt nanoparticles suspended in ethanol

NASA Astrophysics Data System (ADS)

Fernández-Valdés, D.; Torres-Torres, C.; Martínez-González, C. L.; Trejo-Valdez, M.; Hernández-Gómez, L. H.; Torres-Martínez, R.

2016-07-01

The modification in the third-order nonlinear optical response exhibited by rotating bimetallic Au-Pt nanoparticles in an ethanol solution was analyzed. The samples were prepared by a sol-gel processing route. The anisotropy associated to the elemental composition of the nanoparticles was confirmed by high-resolution transmission electron microscopy and energy-dispersive X-ray spectroscopy measurements. The size of the nanoparticles varies in the range from 9 to 13 nm, with an average size of 11 nm. Changes in the spatial orientation of the nanomaterials automatically generated a variation in their plasmonic response evaluated by UV-Vis spectroscopy. A two-wave mixing experiment was conducted to explore an induced birefringence at 532 nm wavelength with nanosecond pulses interacting with the samples. A strong optical Kerr effect was identified to be the main responsible effect for the third-order nonlinear optical phenomenon exhibited by the nanoparticles. It was estimated that the rotation of inhomogeneous nanostructures can provide a remarkable change in the participation of different surface plasmon resonances, if they correspond to multimetallic nanoparticles. Potential applications for developing low-dimensional gyroscopic systems can be contemplated.

Benzothiazolium Single Crystals: A New Class of Nonlinear Optical Crystals with Efficient THz Wave Generation.

PubMed

Lee, Seung-Heon; Lu, Jian; Lee, Seung-Jun; Han, Jae-Hyun; Jeong, Chan-Uk; Lee, Seung-Chul; Li, Xian; Jazbinšek, Mojca; Yoon, Woojin; Yun, Hoseop; Kang, Bong Joo; Rotermund, Fabian; Nelson, Keith A; Kwon, O-Pil

2017-08-01

Highly efficient nonlinear optical organic crystals are very attractive for various photonic applications including terahertz (THz) wave generation. Up to now, only two classes of ionic crystals based on either pyridinium or quinolinium with extremely large macroscopic optical nonlinearity have been developed. This study reports on a new class of organic nonlinear optical crystals introducing electron-accepting benzothiazolium, which exhibit higher electron-withdrawing strength than pyridinium and quinolinium in benchmark crystals. The benzothiazolium crystals consisting of new acentric core HMB (2-(4-hydroxy-3-methoxystyryl)-3-methylbenzo[d]thiazol-3-ium) exhibit extremely large macroscopic optical nonlinearity with optimal molecular ordering for maximizing the diagonal second-order nonlinearity. HMB-based single crystals prepared by simple cleaving method satisfy all required crystal characteristics for intense THz wave generation such as large crystal size with parallel surfaces, moderate thickness and high optical quality with large optical transparency range (580-1620 nm). Optical rectification of 35 fs pulses at the technologically very important wavelength of 800 nm in 0.26 mm thick HMB crystal leads to one order of magnitude higher THz wave generation efficiency with remarkably broader bandwidth compared to standard inorganic 0.5 mm thick ZnTe crystal. Therefore, newly developed HMB crystals introducing benzothiazolium with extremely large macroscopic optical nonlinearity are very promising materials for intense broadband THz wave generation and other nonlinear optical applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Stereomotion is processed by the third-order motion system: reply to comment on Three-systems theory of human visual motion perception: review and update

NASA Astrophysics Data System (ADS)

Lu, Zhong-Lin; Sperling, George

2002-10-01

Two theories are considered to account for the perception of motion of depth-defined objects in random-dot stereograms (stereomotion). In the LuSperling three-motion-systems theory J. Opt. Soc. Am. A 18 , 2331 (2001), stereomotion is perceived by the third-order motion system, which detects the motion of areas defined as figure (versus ground) in a salience map. Alternatively, in his comment J. Opt. Soc. Am. A 19 , 2142 (2002), Patterson proposes a low-level motion-energy system dedicated to stereo depth. The critical difference between these theories is the preprocessing (figureground based on depth and other cues versus simply stereo depth) rather than the motion-detection algorithm itself (because the motion-extraction algorithm for third-order motion is undetermined). Furthermore, the ability of observers to perceive motion in alternating feature displays in which stereo depth alternates with other features such as texture orientation indicates that the third-order motion system can perceive stereomotion. This reduces the stereomotion question to Is it third-order alone or third-order plus dedicated depth-motion processing? Two new experiments intended to support the dedicated depth-motion processing theory are shown here to be perfectly accounted for by third-order motion, as are many older experiments that have previously been shown to be consistent with third-order motion. Cyclopean and rivalry images are shown to be a likely confound in stereomotion studies, rivalry motion being as strong as stereomotion. The phase dependence of superimposed same-direction stereomotion stimuli, rivalry stimuli, and isoluminant color stimuli indicates that these stimuli are processed in the same (third-order) motion system. The phase-dependence paradigm Lu and Sperling, Vision Res. 35 , 2697 (1995) ultimately can resolve the question of which types of signals share a single motion detector. All the evidence accumulated so far is consistent with the three-motion-systems theory. 2002 Optical Society of America

Exact optics - III. Schwarzschild's spectrograph camera revised

NASA Astrophysics Data System (ADS)

Willstrop, R. V.

2004-03-01

Karl Schwarzschild identified a system of two mirrors, each defined by conic sections, free of third-order spherical aberration, coma and astigmatism, and with a flat focal surface. He considered it impractical, because the field was too restricted. This system was rediscovered as a quadratic approximation to one of Lynden-Bell's `exact optics' designs which have wider fields. Thus the `exact optics' version has a moderate but useful field, with excellent definition, suitable for a spectrograph camera. The mirrors are strongly aspheric in both the Schwarzschild design and the exact optics version.

Azimuthal-angle dependence of charged-pion-interferometry measurements with respect to second- and third-order event planes in Au+Au collisions at √[S(NN)]=200  GeV.

PubMed

Adare, A; Afanasiev, S; Aidala, C; Ajitanand, N N; Akiba, Y; Al-Bataineh, H; Alexander, J; Aoki, K; Aramaki, Y; Atomssa, E T; Averbeck, R; Awes, T C; Azmoun, B; Babintsev, V; Bai, M; Baksay, G; Baksay, L; Barish, K N; Bassalleck, B; Basye, A T; Bathe, S; Baublis, V; Baumann, C; Bazilevsky, A; Belikov, S; Belmont, R; Bennett, R; Berdnikov, A; Berdnikov, Y; Bickley, A A; Bok, J S; Boyle, K; Brooks, M L; Buesching, H; Bumazhnov, V; Bunce, G; Butsyk, S; Camacho, C M; Campbell, S; Chen, C-H; Chi, C Y; Chiu, M; Choi, I J; Choudhury, R K; Christiansen, P; Chujo, T; Chung, P; Chvala, O; Cianciolo, V; Citron, Z; Cole, B A; Connors, M; Constantin, P; Csanád, M; Csörgő, T; Dahms, T; Dairaku, S; Danchev, I; Das, K; Datta, A; David, G; Denisov, A; Deshpande, A; Desmond, E J; Dietzsch, O; Dion, A; Donadelli, M; Drapier, O; Drees, A; Drees, K A; Durham, J M; Durum, A; Dutta, D; Edwards, S; Efremenko, Y V; Ellinghaus, F; Engelmore, T; Enokizono, A; En'yo, H; Esumi, S; Fadem, B; Fields, D E; Finger, M; Finger, M; Fleuret, F; Fokin, S L; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fujiwara, K; Fukao, Y; Fusayasu, T; Garishvili, I; Glenn, A; Gong, H; Gonin, M; Goto, Y; Granier de Cassagnac, R; Grau, N; Greene, S V; Grosse Perdekamp, M; Gunji, T; Gustafsson, H-Å; Haggerty, J S; Hahn, K I; Hamagaki, H; Hamblen, J; Han, R; Hanks, J; Hartouni, E P; Haslum, E; Hayano, R; He, X; Heffner, M; Hemmick, T K; Hester, T; Hill, J C; Hohlmann, M; Holzmann, W; Homma, K; Hong, B; Horaguchi, T; Hornback, D; Huang, S; Ichihara, T; Ichimiya, R; Ide, J; Ikeda, Y; Imai, K; Inaba, M; Isenhower, D; Ishihara, M; Isobe, T; Issah, M; Isupov, A; Ivanischev, D; Jacak, B V; Jia, J; Jin, J; Johnson, B M; Joo, K S; Jouan, D; Jumper, D S; Kajihara, F; Kametani, S; Kamihara, N; Kamin, J; Kang, J H; Kapustinsky, J; Karatsu, K; Kawall, D; Kawashima, M; Kazantsev, A V; Kempel, T; Khanzadeev, A; Kijima, K M; Kim, B I; Kim, D H; Kim, D J; Kim, E; Kim, E-J; Kim, S H; Kim, Y-J; Kinney, E; Kiriluk, K; Kiss, A; Kistenev, E; Kochenda, L; Komkov, B; Konno, M; Koster, J; Kotchetkov, D; Kozlov, A; Král, A; Kravitz, A; Kunde, G J; Kurita, K; Kurosawa, M; Kwon, Y; Kyle, G S; Lacey, R; Lai, Y S; Lajoie, J G; Lebedev, A; Lee, D M; Lee, J; Lee, K; Lee, K B; Lee, K S; Leitch, M J; Leite, M A L; Leitner, E; Lenzi, B; Li, X; Liebing, P; Linden Levy, L A; Liška, T; Litvinenko, A; Liu, H; Liu, M X; Love, B; Luechtenborg, R; Lynch, D; Maguire, C F; Makdisi, Y I; Malakhov, A; Malik, M D; Manko, V I; Mannel, E; Mao, Y; Masui, H; Matathias, F; McCumber, M; McGaughey, P L; Means, N; Meredith, B; Miake, Y; Mignerey, A C; Mikeš, P; Miki, K; Milov, A; Mishra, M; Mitchell, J T; Mohanty, A K; Morino, Y; Morreale, A; Morrison, D P; Moukhanova, T V; Murata, J; Nagamiya, S; Nagle, J L; Naglis, M; Nagy, M I; Nakagawa, I; Nakamiya, Y; Nakamura, T; Nakano, K; Newby, J; Nguyen, M; Niida, T; Nouicer, R; Nyanin, A S; O'Brien, E; Oda, S X; Ogilvie, C A; Oka, M; Okada, K; Onuki, Y; Oskarsson, A; Ouchida, M; Ozawa, K; Pak, R; Pantuev, V; Papavassiliou, V; Park, I H; Park, J; Park, S K; Park, W J; Pate, S F; Pei, H; Peng, J-C; Pereira, H; Peresedov, V; Peressounko, D Yu; Pinkenburg, C; Pisani, R P; Proissl, M; Purschke, M L; Purwar, A K; Qu, H; Rak, J; Rakotozafindrabe, A; Ravinovich, I; Read, K F; Reygers, K; Riabov, V; Riabov, Y; Richardson, E; Roach, D; Roche, G; Rolnick, S D; Rosati, M; Rosen, C A; Rosendahl, S S E; Rosnet, P; Rukoyatkin, P; Ružička, P; Sahlmueller, B; Saito, N; Sakaguchi, T; Sakashita, K; Samsonov, V; Sano, S; Sato, T; Sawada, S; Sedgwick, K; Seele, J; Seidl, R; Semenov, A Yu; Seto, R; Sharma, D; Shein, I; Shibata, T-A; Shigaki, K; Shimomura, M; Shoji, K; Shukla, P; Sickles, A; Silva, C L; Silvermyr, D; Silvestre, C; Sim, K S; Singh, B K; Singh, C P; Singh, V; Slunečka, M; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Sparks, N A; Stankus, P W; Stenlund, E; Stoll, S P; Sugitate, T; Sukhanov, A; Sziklai, J; Takagui, E M; Taketani, A; Tanabe, R; Tanaka, Y; Tanida, K; Tannenbaum, M J; Tarafdar, S; Taranenko, A; Tarján, P; Themann, H; Thomas, T L; Todoroki, T; Togawa, M; Toia, A; Tomášek, L; Torii, H; Towell, R S; Tserruya, I; Tsuchimoto, Y; Vale, C; Valle, H; van Hecke, H W; Vazquez-Zambrano, E; Veicht, A; Velkovska, J; Vértesi, R; Vinogradov, A A; Virius, M; Vrba, V; Vznuzdaev, E; Wang, X R; Watanabe, D; Watanabe, K; Watanabe, Y; Wei, F; Wei, R; Wessels, J; White, S N; Winter, D; Wood, J P; Woody, C L; Wright, R M; Wysocki, M; Xie, W; Yamaguchi, Y L; Yamaura, K; Yang, R; Yanovich, A; Ying, J; Yokkaichi, S; You, Z; Young, G R; Younus, I; Yushmanov, I E; Zajc, W A; Zhang, C; Zhou, S; Zolin, L

2014-06-06

Charged-pion-interferometry measurements were made with respect to the second- and third-order event plane for Au+Au collisions at sqrt[s_{NN}]=200  GeV. A strong azimuthal-angle dependence of the extracted Gaussian-source radii was observed with respect to both the second- and third-order event planes. The results for the second-order dependence indicate that the initial eccentricity is reduced during the medium evolution, which is consistent with previous results. In contrast, the results for the third-order dependence indicate that the initial triangular shape is significantly reduced and potentially reversed by the end of the medium evolution, and that the third-order oscillations are largely dominated by the dynamical effects from triangular flow.

Investigation on the growth, spectral, lifetime, mechanical analysis and third-order nonlinear optical studies of L-methionine admixtured D-mandelic acid single crystal: A promising material for nonlinear optical applications

NASA Astrophysics Data System (ADS)

Jayaprakash, P.; Sangeetha, P.; Kumari, C. Rathika Thaya; Caroline, M. Lydia

2017-08-01

A nonlinear optical bulk single crystal of L-methionine admixtured D-mandelic acid (LMDMA) has been grown by slow solvent evaporation technique using water as solvent at ambient temperature. The crystallized LMDMA single crystal subjected to single crystal X-ray diffraction study confirmed monoclinic system with the acentric space group P21. The FTIR analysis gives information about the modes of vibration in the various functional groups present in LMDMA. The UV-visible spectral analysis assessed the optical quality and linear optical properties such as extinction coefficient, reflectance, refractive index and from which optical conductivity and electric susceptibility were also evaluated. The frequency doubling efficiency was observed using Kurtz Perry powder technique. A multiple shot laser was utilized to evaluate the laser damage threshold energy of the crystal. Discrete thermodynamic properties were carried out by TG-DTA studies. The hardness, Meyer's index, yield strength, elastic stiffness constant, Knoop hardness, fracture toughness and brittleness index were analyzed using Vickers microhardness tester. Layer growth pattern and the surface defect were examined by chemical etching studies using optical microscope. Fluorescence emission spectrum was recorded and lifetime was also studied. The electric field response of crystal was investigated from the dielectric studies at various temperatures at different frequencies. The third-order nonlinear optical response in LMDMA has been investigated using Z-scan technique with He-Ne laser at 632.8 nm and nonlinear parameters such as refractive index (n2), absorption coefficient (β) and susceptibility (χ3) investigated extensively for they are in optical phase conjucation, high-speed optical switches and optical dielectric devices.

Nodal aberration theory for wild-filed asymmetric optical systems

NASA Astrophysics Data System (ADS)

Chen, Yang; Cheng, Xuemin; Hao, Qun

2016-10-01

Nodal Aberration Theory (NAT) was used to calculate the zero field position in Full Field Display (FFD) for the given aberration term. Aiming at wide-filed non-rotational symmetric decentered optical systems, we have presented the nodal geography behavior of the family of third-order and fifth-order aberrations. Meanwhile, we have calculated the wavefront aberration expressions when one optical element in the system is tilted, which was not at the entrance pupil. By using a three-piece-cellphone lens example in optical design software CodeV, the nodal geography is testified under several situations; and the wavefront aberrations are calculated when the optical element is tilted. The properties of the nodal aberrations are analyzed by using Fringe Zernike coefficients, which are directly related with the wavefront aberration terms and usually obtained by real ray trace and wavefront surface fitting.

Probing the nuclear susceptibility of mesoionic compounds using two-beam coupling with chirp-controlled pulses

NASA Astrophysics Data System (ADS)

Bosco, Carlos A. C.; Maciel, Glauco S.; Rakov, Nikifor; de Araújo, Cid B.; Acioli, Lúcio H.; Simas, Alfredo M.; Athayde-Filho, Petrônio F.; Miller, Joseph

2007-11-01

The third-order non-linear optical response of mesoionic compounds (MIC) in dimethylsulfoxide (DMSO) and methanol solutions was investigated by use of collinear pump and probe technique with chirp-controlled femtosecond pulses. The experiments allowed the investigation of non-instantaneous nuclear processes and thermal effects induced by two-photon absorption (TPA). We found that the nuclear non-linearity of MIC in DMSO is ˜1/5 the benzene, which was used as a reference material. This result is attributed to the large inertia of MIC to rotation, compared to benzene. The results for MIC in methanol indicate the influence of thermal effects due to TPA.

Two Photon Absorption in a Novel Nano-optical Material Based on the Nonconjugated Conductive Polymer, Poly(beta-pinene)

NASA Astrophysics Data System (ADS)

Titus, Jitto; Thakur, Mrinal

2006-03-01

As recently reported, the electrical conductivity of the nonconjugated polymer, poly(beta-pinene) increases by more than ten orders of magnitude upon doping with iodine [1]. The FTIR, optical absorption and EPR measurements have shown that radical cations are formed upon doping and charge-transfer involving the isolated double-bond in poly(beta-pinene). In this report, exceptionally large two-photon absorption in iodine-doped poly(beta-pinene) will be discussed. The linear absorption spectrum of medium-doped poly(beta-pinene) have peaks at about 4 eV and 3.1 eV. The first peak is due to the radical cation and the second due to the charge-transfer between the double bond and the dopant. The two-photon absorption of the medium-doped polymer has been measured at 730-860 nm using open-aperture z-scan with 150 femtosecond pulses from a Ti:Sapphire laser. A two-photon peak at about 1.5 eV with a magnitude of more than 1 cm/MW has been observed. The large magnitude of the two-photon absorption coefficient which is proportional to the imaginary part of the third order susceptibility has been attributed to the special structure of the radical cation and the confinement within a sub-nanometer dimension. [1] Vippa, Rajagopalan and Thakur, J. Poly. Sci. Part B: Poly. Phys., 43, 3695 (2005).

Cavity enhanced third harmonic generation in graphene

NASA Astrophysics Data System (ADS)

Beckerleg, Chris; Constant, Thomas J.; Zeimpekis, Ioannis; Hornett, Samuel M.; Craig, Chris; Hewak, Daniel W.; Hendry, Euan

2018-01-01

Graphene displays a surprisingly large third order nonlinearity. Here, we report that conversion efficiencies approaching 10-4 are possible for third harmonic generation (THG). Moreover, the atomically thin nature of graphene allows for simple integration in cavity designs to increase this even further. We demonstrate a 117-fold enhancement, of resonant vs non-resonant wavelengths in the THG from graphene due to the integration of a graphene layer with a resonant cavity. This large enhancement occurs as the cavity is resonant for both the fundamental field and the third harmonic. We model this effect using the finite difference time domain approach. By comparing our model with experiment, we are able to deduce the value of a bulk third order susceptibility of graphene of |χ(3)|=4 ×10-17(m/V ) 2 .

Influence of image charge effect on impurity-related optical absorption coefficients and refractive index changes in a spherical quantum dot

NASA Astrophysics Data System (ADS)

Vartanian, A. L.; Asatryan, A. L.; Vardanyan, L. A.

2017-03-01

We have investigated the influence of an image charge effect (ICE) on the energies of the ground and first few excited states of a hydrogen-like impurity in a spherical quantum dot (QD) in the presence of an external electric field. The oscillator strengths of transitions from the 1 s -like state to excited states of 2px and 2pz symmetries are calculated as the functions of the strengths of the confinement potential and the electric field. Also, we have studied the effect of image charges on linear and third-order nonlinear optical absorption coefficients and refractive index changes (RICs). The results show that image charges lead to the decrease of energies for all the hydrogen-like states, to the significant enhancement of the oscillator strengths of transitions between the impurity states, and to comparatively large blue shifts in linear, nonlinear, and total absorption coefficients and refractive index changes. Our results indicate that the total optical characteristics can be controlled by the strength of the confinement and the electric field.

Ultrafast carrier dynamics and third-order nonlinear optical properties of AgInS2/ZnS nanocrystals.

PubMed

Yu, Kuai; Yang, Yang; Wang, Junzhong; Tang, Xiaosheng; Xu, Qing-Hua; Wang, Guo Ping

2018-06-22

Broad photoluminescence (PL) emission, a large Stokes shift and extremely long-lived radiative lifetimes are the characteristics of ternary I-III-VI semiconductor nanocrystals (NCs), such as CuInS 2 and AgInS 2 . However, the lack of understanding regarding the intriguing PL mechanisms and photo-carrier dynamics limits their further applications. Here, AgInS 2 and AgInS 2 /ZnS NCs were chemically synthesized and their carrier dynamics were studied by time-resolved PL spectroscopy. The results demonstrated that the surface defect state, which contributed dominantly to the non-radiative decay processes, was effectively passivated through ZnS alloying. Femtosecond transient absorption spectroscopy was also used to investigate the carrier dynamics, revealing the electron storage at the surface state and donor state. Furthermore, the two photon absorption properties of AgInS 2 and AgInS 2 /ZnS NCs were measured using an open-aperture Z-scan technique. The improved third-order nonlinear susceptibility [Formula: see text] of AgInS 2 through ZnS alloying demonstrates potential application in two photon PL biological imaging.

Measurements of the CMB Polarization with POLARBEAR and the Optical Performance of the Simons Array

NASA Astrophysics Data System (ADS)

Takayuki Matsuda, Frederick; POLARBEAR Collaboration

2017-06-01

POLARBEAR is a ground-based polarization sensitive Cosmic Microwave Background (CMB) experiment installed on the 2.5 m aperture Gregorian-Dragone type Huan Tran Telescope located in the Atacama desert in Chile. POLARBEAR is designed to conduct broad surveys at 150 GHz to measure the CMB B-mode polarization signal from inflationary gravitational waves at large angular scales and from gravitational lensing at small angular scales. POLARBEAR started observations in 2012. First season results on gravitational lensing B-mode measurements were published in 2014, and the data analysis of further seasons is in progress. In order to further increase measurement sensitivity, in 2018 the experiment will be upgraded to the Simons Array comprising of three telescopes, each with improved receiver optics using alumina lenses. In order to further expand the observational range, the second and third receiver optics designs were further modified for improved optical performance across the frequencies of 95, 150, 220, and 280 GHz. The diffraction limited field of view was increased especially for the higher frequencies to span a full 4.5 degrees diameter field of view of the telescope. The Simons Array will have a total of 22,764 detectors within this field of view. The Simons Array is projected to put strong constraints on both the measurements of the tensor-to-scalar ratio for inflationary cosmology and the sum of the neutrino masses. I will report on the status of current observations and analysis of the first two observation seasons of POLARBEAR as well as the optics design development of the Simons Array receivers.

Optical and Nonlinear Optical Response of Light Sensor Thin Films

PubMed Central

Liu, Huimin; Rua, Armando; Vasquez, Omar; Vikhnin, Valentin S.; Fernandez, Felix E.; Fonseca, Luis F.; Resto, Oscar; Weisz, Svi Z.

2005-01-01

For potential ultrafast optical sensor application, both VO2 thin films and nanocomposite crystal-Si enriched SiO2 thin films grown on fused quartz substrates were successfully prepared using pulsed laser deposition (PLD) and RF co-sputtering techniques. In photoluminescence (PL) measurement c-Si/SiO2 film contains nanoparticles of crystal Si exhibits strong red emission with the band maximum ranging from 580 to 750 nm. With ultrashort pulsed laser excitation all films show extremely intense and ultrafast nonlinear optical (NLO) response. The recorded holography from all these thin films in a degenerate-four-wave-mixing configuration shows extremely large third-order response. For VO2 thin films, an optically induced semiconductor-to-metal phase transition (PT) immediately occurred upon laser excitation. it accompanied. It turns out that the fast excited state dynamics was responsible to the induced PT. For c-Si/SiO2 film, its NLO response comes from the contribution of charge carriers created by laser excitation in conduction band of the c-Si nanoparticles. It was verified by introducing Eu3+ which is often used as a probe sensing the environment variations. It turns out that the entire excited state dynamical process associated with the creation, movement and trapping of the charge carriers has a characteristic 500 ps duration.

Ultrafast third-order nonlinear optical response of pyrene derivatives

NASA Astrophysics Data System (ADS)

Shi, Yufang; Li, Zhongguo; Fang, Yu; Sun, Jinyu; Zhao, Minggen; Song, Yinglin

2017-05-01

Two mono-substituted pyrene derivatives with delocalized electron system 1-(pyren-1-yl)-3-(4-Methyl thiophene-2-yl) acrylic ketone (13#) and 1-(pyren-1-yl)-3-(4-bromo thiophene-2-yl) acrylic ketone (15#) were successfully synthesized. The resultant compounds were characterized by nuclear magnetic resonance (NMR), infrared spectroscopy (IR), high resolution mass spectrum (HR-MS), and UV-vis spectra. The third-order nonlinear optical properties of the compounds were investigated using Z-scan technique with femtosecond laser pulses at 500 nm and 700 nm, respectively. Both of the compounds showed a decrease in transmittance about the focus, which are typical of two-photon absorption. It was found that the two-photon absorption behavior of the pyrene derivatives were modified by substituents on thiophene ring. These results indicate that both compounds can be promising candidates for future optoelectronic and bio-imaging applications.

The Longwave Silicon Chip - Integrated Plasma-Photonics in Group IV And III-V Semiconductors

DTIC Science & Technology

2013-10-01

infrared applications; SiGeSn heterostructure photonics; group IV plasmonics with silicides , germanicides, doped Si, Ge or GeSn; Franz-Keldysh...SPP waveguide in which localized silicide or germanicide “conductors” are introduced to give local plasmonic confinement. Therefore, guided-wave...reconfigurable integrated optoelectronics, electro-optical logic in silicon, silicides for group IV plasmonics, reviews of third-order nonlinear optical

Towards a unifying theory for the first-, second-, and third-order molecular (non)linear optical response

NASA Astrophysics Data System (ADS)

Pérez-Moreno, Javier; Clays, Koen; Kuzyk, Mark G.

2010-05-01

We present a procedure for the modeling of the dispersion of the nonlinear optical response of complex molecular structures that is based strictly on the results from experimental characterization. We show how under some general conditions, the use of the Thomas-Kuhn sum-rules leads to a successful modeling of the nonlinear response of complex molecular structures.

Photodeposition of amorphous polydiacetylene films from monomer solutions onto transparent substrates

NASA Technical Reports Server (NTRS)

Paley, M. S.; Frazier, D. O.; Abdeldeyem, H.; Armstrong, S.; McManus, S. P.

1995-01-01

Polydiacetylenes are a very promising class of polymers for both photonic and electronic applications because of their highly conjugated structures. For these applications, high-quality thin polydiacetylene films are required. We have discovered a novel technique for obtaining such films of a polydiacetylene derivative of 2-methyl-4-nitroaniline using photodeposition from monomer solutions onto UV transparent substrates. This heretofore unreported process yields amorphous polydiacetylene films with thicknesses on the order of I micron that have optical quality superior to that of films grown by standard crystal growth techniques. Furthermore, these films exhibit good third-order nonlinear optical susceptibilities; degenerate four-wave mixing experiments give x(3) values on the order of 10(exp -8) - 10(exp -7) esu. We have conducted masking experiments which demonstrate that photodeposition occurs only where the substrate is directly irradiated, clearly indicating that the reaction occurs at the surface. Additionally, we have also been able to carry out photodeposition using lasers to form thin polymer circuits. In this work, we discuss the photodeposition of polydiacetylene thin films from solution, perform chemical characterization of these films, investigate the role of the substrate, speculate on the mechanism of the reaction, and make a preliminary determination of the third-order optical nonlinearity of the films. This simple, straightforward technique may ultimately make feasible the production of polydiacetylene thin films for technological applications.

Advanced space optics development in freeform optics design, ceramic polishing, rapid and extreme freeform polishing

NASA Astrophysics Data System (ADS)

Geyl, R.; Leplan, H.; Ruch, E.

2017-09-01

In this paper Safran-Reosc wants to share with the space community its recent work performed in the domain of space optics. Our main topic is a study about the advantages that freeform optical surfaces can offer to advanced space optics in term of compactness or performances. We have separated smart and extreme freeform in our design exploration work. Our second topic is to answer about the immediate question following: can we manufacture and test these freeform optics? We will therefore present our freeform optics capability, report recent achievement in extreme aspheric optics polishing and introduce to the industrialisation process of large off axis optics polishing for the ESO Extremely Large Telescope primary mirror segments. Thirdly we present our R-SiC polishing layer technology for SiC material. This technique has been developed to reduce costs, risks and schedule in the manufacturing of advanced SiC optics for Vis and IR applications.

The Posterior Transpetrosal Approach in a Case of Large Retrochiasmatic Craniopharyngioma: Operative Video and Technical Nuances.

PubMed

Labidi, Moujahed; Watanabe, Kentaro; Loit, Marie-Pier; Hanakita, Shunya; Froelich, Sébastien

2018-02-01

Objectives  To discuss the use of the posterior petrosal approach for the resection of a retrochiasmatic craniopharyngioma. Design  Operative video. Results  In this case video, the authors discuss the surgical management of a large craniopharyngioma, presenting with mass effect on the third ventricle and optic apparatus. A first surgical stage, through an endoscopic endonasal transtubercular approach, allowed satisfactory decompression of the optic chiasma and nerves in preparation for adjuvant therapy. However, accelerated growth of the tumor, with renewed visual deficits and mass effect on the hypothalamus and third ventricle, warranted a supplementary resection. A posterior transpetrosal 1 2 (also called "retrolabyrinthine transtentorial") was performed to obtain a better exposure of the tumor and the surrounding anatomy (floor and walls of the third ventricle, perforating vessels, optic nerves, etc.) 3 . Nuances of technique and surgical pearls related to the posterior transpetrosal are discussed and illustrated in this operative video, including the posterior mobilization of the transverse-sigmoid sinuses junction, preservation of the venous anatomy during the tentorial incision, identification and preservation of the floor of the third ventricle during tumor resection, and a careful multilayer closure. Conclusion  Retrochiasmatic craniopharyngiomas are difficult to reach tumors that often require skull base approaches, either endoscopic endonasal or transcranial. The posterior transpetrosal approach is an important part of the surgical armamentarium to safely resect these complex tumors. The link to the video can be found at: https://youtu.be/2MyGLJ_v1kI .

Thermally stimulated nonlinear refraction in gelatin stabilized Cu-PVP nanocomposite thin films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tamgadge, Y. S., E-mail: ystamgadge@gmail.com; Atkare, D. V.; Pahurkar, V. G.

2016-05-06

This article illustrates investigations on thermally stimulated third order nonlinear refraction of Cu-PVP nanocomposite thin films. Cu nanoparticles have been synthesized using chemical reduction method and thin films in PVP matrix have been obtained using spin coating technique. Thin films have been characterized by X-ray diffraction (XRD) and Ultraviolet-visible (UV-vis) spectroscopyfor structural and linear optical studies. Third order nonlinear refraction studies have been performed using closed aperture z-scan technique under continuous wave (CW) He-Ne laser. Cu-PVP nanocomposites are found to exhibit strong nonlinear refractive index stimulated by thermal lensing effect.

Bismuth ferrite dielectric nanoparticles excited at telecom wavelengths as multicolor sources by second, third, and fourth harmonic generation.

PubMed

Riporto, Jérémy; Demierre, Alexis; Kilin, Vasyl; Balciunas, Tadas; Schmidt, Cédric; Campargue, Gabriel; Urbain, Mathias; Baltuska, Andrius; Le Dantec, Ronan; Wolf, Jean-Pierre; Mugnier, Yannick; Bonacina, Luigi

2018-05-03

We demonstrate the simultaneous generation of second, third, and fourth harmonics from a single dielectric bismuth ferrite nanoparticle excited using a telecom fiber laser at 1560 nm. We first characterize the signals associated with different nonlinear orders in terms of spectrum, excitation intensity dependence, and relative signal strengths. Successively, on the basis of the polarization-resolved emission curves of the three harmonics, we discuss the interplay of susceptibility tensor components at different orders and show how polarization can be used as an optical handle to control the relative frequency conversion properties.

Regional Recovery of the Disturbing Gravitational Potential from Satellite Observations of First-, Second- and Third-order Radial Derivatives of the Disturbing Gravitational Potential

NASA Astrophysics Data System (ADS)

Novak, P.; Pitonak, M.; Sprlak, M.

2015-12-01

Recently realized gravity-dedicated satellite missions allow for measuring values of scalar, vectorial (Gravity Recovery And Climate Experiment - GRACE) and second-order tensorial (Gravity field and steady-state Ocean Circulation Explorer - GOCE) parameters of the Earth's gravitational potential. Theoretical aspects related to using moving sensors for measuring elements of a third-order gravitational tensor are currently under investigation, e.g. the gravity-dedicated satellite mission OPTIMA (OPTical Interferometry for global Mass change detection from space) should measure third-order derivatives of the Earth's gravitational potential. This contribution investigates regional recovery of the disturbing gravitational potential on the Earth's surface from satellite observations of first-, second- and third-order radial derivatives of the disturbing gravitational potential. Synthetic measurements along a satellite orbit at the altitude of 250 km are synthetized from the global gravitational model EGM2008 and polluted by the Gaussian noise. The process of downward continuation is stabilized by the Tikhonov regularization. Estimated values of the disturbing gravitational potential are compared with the same quantity synthesized directly from EGM2008. Finally, this contribution also discusses merging a regional solution into a global field as a patchwork.

Possibilities of the regional gravity field recovery from first-, second- and third-order radial derivatives of the disturbing gravitational potential measured on moving platforms

NASA Astrophysics Data System (ADS)

Pitonak, Martin; Sprlak, Michal; Novak, Pavel; Tenzer, Robert

2016-04-01

Recently realized gravity-dedicated satellite missions allow for measuring values of scalar, vectorial (Gravity Recovery And Climate Experiment - GRACE) and second-order tensorial (Gravity field and steady-state Ocean Circulation Explorer - GOCE) parameters of the Earth's gravitational potential. Theoretical aspects related to using moving sensors for measuring elements of the third-order gravitational tensor are currently under investigation, e.g., the gravity field-dedicated satellite mission OPTIMA (OPTical Interferometry for global Mass change detection from space) should measure third-order derivatives of the Earth's gravitational potential. This contribution investigates regional recovery of the disturbing gravitational potential on the Earth's surface from satellite and aerial observations of the first-, second- and third-order radial derivatives of the disturbing gravitational potential. Synthetic measurements along a satellite orbit at the altitude of 250 km and along an aircraft track at the altitude of 10 km are synthetized from the global gravitational model EGM2008 and polluted by the Gaussian noise. The process of downward continuation is stabilized by the Tikhonov regularization. Estimated values of the disturbing gravitational potential are compared with the same quantity synthesized directly from EGM2008.

One-pot synthesis of silica-hybridized Ag{sub 2}S–CuS nanocomposites with tunable nonlinear optical properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ann Mary, K.A.; Unnikrishnan, N.V., E-mail: nvu100@yahoo.com; Philip, Reji

2015-10-15

Highlights: • Silica modified QDs of CuS and Ag{sub 2}S is developed at room temperature. • Formation of Ag{sub 2}S/CuS nanocomposites is confirmed from XRD and FFT of HRTEM images. • The concentration dependent growth of silica modified QDs is discussed. • Nonlinear absorption observed in ns excitations is dominated by SA and ESA. • Tuning of optical limiting efficiency is achieved with relative Ag{sub 2}S content. - Abstract: In the present work we report a simple, facile route developed for preparing silica hybridized copper sulfide and silver sulfide quantum dots at room temperature. By adjusting the concentration of themore » precursors, Ag{sub 2}S can form Ag{sub 2}S–CuS nanocomposites which are self regulated in one pot. Their crystalline, structural and optical properties have been investigated in detail, and the optical limiting nature is studied from fluence-dependent transmittance measurements employing short (5 ns) laser pulses at 532 nm. Ag{sub 2}S nanoparticles are found to have large third order nonlinear optical coefficients with a relatively lower optical limiting threshold of 1.7 J cm{sup −2}, while the nonlinearity of the nanocomposites is found to lie in between that of Ag{sub 2}S and CuS nanoparticles. These results suggest pathways for designing good quality optical limiters with tunable optical limiting efficiencies by varying the constituent nanocrystal compositions.« less

Synthesis, growth, structure, mechanical and optical properties of a new semi-organic 2-methyl imidazolium dihydrogen phosphate single crystal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nagapandiselvi, P., E-mail: nagapandiselvip@ssn.edu.in; Baby, C.; Gopalakrishnan, R.

2016-09-15

Highlights: • 2MIDP crystals were grown by slow evaporation solution growth technique. • Single crystal XRD revealed self-assembled supramolecular framework. • Z scan technique is employed for third order nonlinear optical susceptibility. • Structure-property correlation is established. - Abstract: A new semi-organic compound, 2-methyl imidazolium dihydrogen phosphate (2MIDP), was prepared and good quality single crystals of 2MIDP were grown by slow evaporation solution growth technique. Crystal structure elucidated using Single crystal XRD showed that 2MIDP crystallizes in monoclinic system with P2{sub 1}/c space group. FT-IR, UV-Vis-NIR, Fluorescence and FT-NMR spectra confirm the molecular structure of 2MIDP. The UV-Vis-NIR spectra establishedmore » the suitability of the compound for NLO applications. TG-DSC showed that 2MIDP is thermally stable up to 200 °C. Mechanical characteristics like hardness number (H{sub v}), stiffness constant (C{sub 11}), yield strength (σ{sub v}), fracture toughness (K{sub c}) and brittleness index (B{sub i}) were assessed using Vicker’s microhardness tester. Third order nonlinear optical properties determined from Z-scan measurement using femto and picosecond lasers showed two photon reverse saturable absorption. The enhancement of nonlinear optical properties in femto second laser, revealed the suitability of 2MIDP for optical limiting applications.« less

Nonlinear optical measurements of conducting copolymers of aniline under CW laser excitation

NASA Astrophysics Data System (ADS)

Pramodini, S.; Poornesh, P.

2015-08-01

Synthesis and measurements of third-order optical nonlinearity and optical limiting of conducting copolymers of aniline are presented. Single beam z-scan technique was employed for the nonlinear optical studies. Continuous wave He-Ne laser operating at 633 nm was used as the source of excitation. Copolymer samples exhibited reverse saturable absorption (RSA) process. The nonlinear refraction studies depict that the copolymers exhibit self-defocusing property. The estimated values of βeff, n2 and χ(3) were found to be of the order of 10-2 cm/W, 10-5 esu and 10-7 esu respectively. Self-diffraction rings were observed due to refractive index change when exposed to the laser beam. A good optical limiting and clamping of power of ∼0.9 mW and ∼0.05 mW was observed. Therefore, copolymers of aniline emerge as a potential candidate for photonic device applications.

Optical design and simulation of a new coherence beamline at NSLS-II

NASA Astrophysics Data System (ADS)

Williams, Garth J.; Chubar, Oleg; Berman, Lonny; Chu, Yong S.; Robinson, Ian K.

2017-08-01

We will discuss the optical design for a proposed beamline at NSLS-II, a late-third generation storage ring source, designed to exploit the spatial coherence of the X-rays to extract high-resolution spatial information from ordered and disordered materials through Coherent Diffractive Imaging, executed in the Bragg- and forward-scattering geometries. This technique offers a powerful tool to image sub-10 nm spatial features and, within ordered materials, sub-Angstrom mapping of deformation fields. Driven by the opportunity to apply CDI to a wide range of samples, with sizes ranging from sub-micron to tens-of-microns, two optical designs have been proposed and simulated under a wide variety of optical configurations using the software package Synchrotron Radiation Workshop. The designs, their goals, and the results of the simulation, including NSLS-II ring and undulator source parameters, of the beamline performance as a function of its variable optical components is described.

A Third-Order Item Response Theory Model for Modeling the Effects of Domains and Subdomains in Large-Scale Educational Assessment Surveys

ERIC Educational Resources Information Center

Rijmen, Frank; Jeon, Minjeong; von Davier, Matthias; Rabe-Hesketh, Sophia

2014-01-01

Second-order item response theory models have been used for assessments consisting of several domains, such as content areas. We extend the second-order model to a third-order model for assessments that include subdomains nested in domains. Using a graphical model framework, it is shown how the model does not suffer from the curse of…

Few-cycle optical rogue waves: complex modified Korteweg-de Vries equation.

PubMed

He, Jingsong; Wang, Lihong; Li, Linjing; Porsezian, K; Erdélyi, R

2014-06-01

In this paper, we consider the complex modified Korteweg-de Vries (mKdV) equation as a model of few-cycle optical pulses. Using the Lax pair, we construct a generalized Darboux transformation and systematically generate the first-, second-, and third-order rogue wave solutions and analyze the nature of evolution of higher-order rogue waves in detail. Based on detailed numerical and analytical investigations, we classify the higher-order rogue waves with respect to their intrinsic structure, namely, fundamental pattern, triangular pattern, and ring pattern. We also present several new patterns of the rogue wave according to the standard and nonstandard decomposition. The results of this paper explain the generalization of higher-order rogue waves in terms of rational solutions. We apply the contour line method to obtain the analytical formulas of the length and width of the first-order rogue wave of the complex mKdV and the nonlinear Schrödinger equations. In nonlinear optics, the higher-order rogue wave solutions found here will be very useful to generate high-power few-cycle optical pulses which will be applicable in the area of ultrashort pulse technology.

Even-order harmonic cancellation for off-quadrature biased Mach-Zehnder modulator with improved RF metrics using dual wavelength inputs and dual outputs.

PubMed

Devgan, Preetpaul S; Diehl, John F; Urick, Vincent J; Sunderman, Christopher E; Williams, Keith J

2009-05-25

We present a technique using a dual-output Mach-Zehnder modulator (MZM) with two wavelength inputs, one operating at low-bias and the other operating at high-bias, in order to cancel unwanted even-order harmonics in analog optical links. By using a dual-output MZM, this technique allows for two suppressed optical carriers to be transmitted to the receiver. Combined with optical amplification and balanced differential detection, the RF power of the fundamental is increased by 2 dB while the even-order harmonic is reduced by 47 dB, simultaneously. The RF noise figure and third-order spurious-free dynamic range (SFDR(3)) are improved by 5.4 dB and 3.6 dB, respectively. Using a wavelength sensitive, low V(pi) MZM allows the two wavelengths to be within 5.5 nm of each other for a frequency band from 10 MHz to 100 MHz and 10 nm for 1 GHz.

A Evaluation of Optical Aberrations in Underwater Hologrammetry

NASA Astrophysics Data System (ADS)

Kilpatrick, J. M.

Available from UMI in association with The British Library. An iterative ray-trace procedure is developed in conjunction with semi-analytic expressions for spherical aberration, coma, and astigmatism in the reconstructed holographic images of underwater objects. An exact expression for the astigmatic difference is obtained, based on the geometry of the caustic for refraction. The geometrical characteristics of the aberrated images associated with axial and non-axial field positions are represented by ray intersection diagrams. A third order expression for the wavefront aberration introduced at a planar air/water boundary is given. The associated third order aberration coefficients are used to obtain analytic expressions for the aberrations observed in underwater hologrammetry. The results of the third order treatment are shown to give good agreement with the results obtained by geometrical ray tracing and by direct measurement on the reconstructed real image. The third order aberration coefficients are employed to estimate the limit of resolution in the presence of the aberrations associated with reconstruction in air. In concurrence with practical observations it is found that the estimated resolution is primarily limited by astigmatism. The limitations of the planar window in underwater imaging applications are outlined and various schemes are considered to effect a reduction in the extent of aberration. The analogous problems encountered in underwater photography are examined in order to establish the grounds for a common solution based on a conventional optical corrector. The performance of one such system, the Ivanoff Corrector, is investigated. The spherical aberration associated with axial image formation is evaluated. The equivalence of the third order wavefront aberration introduced at a planar air/water boundary to that introduced upon reconstruction by an appropriate wavelength change is shown to provide a basis for the compensation of aberrations in underwater hologrammetry. The results of experimental trials which demonstrate the correction of astigmatism and field curvature are presented. Exact expressions are obtained for the aberrations in wavelength compensated holograms and are employed to determine the conditions for optimum compensation and the degree of residual aberration. (Abstract shortened by UMI.).

Eye/Sensor Protection against Laser Irradiation Organic Nonlinear Optical Materials

DTIC Science & Technology

1989-06-12

the dipole. When the electric field is small compared to the internal fields due to the electron!, the molecular polarizability (p), which is...polarizability tensors, respectively, the linear polarizability and the second and third-order hyperpolarizability. At lower field intensities ( small E’s) only...nonlinear optical effect: the bonding electrons are well localized so only small changes in charge distribution with changes in local field environments

Enhancement of nonlinear optical susceptibility of CuPc films by ITO layer

NASA Astrophysics Data System (ADS)

Ganesh, V.; Zahran, H. Y.; Yahia, I. S.; Shkir, Mohd; AlFaify, S.

2016-12-01

In the present study, the Copper Phthalocyanine (CuPc)/ITO thin film was fabricated using thermal evaporation method. The structural property was analyzed by X-ray diffraction study and confirms that the thin film has been preferentially grown along (200) plane. The atomic force microscope study was carried out on deposited film and quality of thin films is assessed by calculating the roughness of the films. The direct and indirect band gap, linear and nonlinear optical characteristics of grown films were calculated by using UV-Vis-NIR spectrometer studies. The calculated values of the first direct and indirect band gaps (Eg1(d) &Eg1(ind)) are 1.879 and 1.644 eV as a fundamental gap, while the values of second direct and indirect band gap (Eg2(d) &Eg2(ind)) are 1.660 and 1.498 eV as an onset gap for CuPc. The values of nonlinear refractive index (n2) and third order nonlinear optical susceptibility (χ3) are found to be 5 × 10-8 and 8 × 10-9 (theoretical) and 5.2 × 10-8 and 1.56 × 10-7 (experimental) respectively. The optical band and third order nonlinear properties suggest that the as-prepared films are may be applied in optoelectronic and nonlinear applications.

Fabrication and notable optical nonlinearities of ultrathin composite films derived from water-soluble Keggin-type polyoxometalates and water-insoluble phthalocyanine.

PubMed

Shehzad, Farooq Khurum; Qu, Ningning; Zhou, Yunshan; Zhang, Lijuan; Ji, Huanyao; Shi, Zonghai; Li, Jiaqi; Hassan, Sadaf Ul

2016-11-28

Composite films with the general formula (POM/CuTAPc) n derived from water-soluble Keggin-type polyoxometalates (POMs = H 5 PMo 10 V 2 O 40 , H 4 SiW 12 O 40 , H 3 PMo 12 O 40 and H 3 PW 12 O 40 ) and water-insoluble 4,9,16,23-copper tetraaminophthalocyanine (denoted CuTAPc) are successfully fabricated by a layer-by-layer self-assembly technique and systematically characterized. The structure of the polyoxometalate anions in the multilayers is kept intact; the deposition amounts of POM and CuTAPc remain constant in every adsorption cycle of the composite film assembly process. The nonlinear optical properties of the composite films were studied by a Z-scan technique at a wavelength of 532 nm and a pulse width of 7 ns. The results not only show that the composite films exhibit notable optical nonlinear self-defocusing behavior and a saturated absorption effect with the nonlinear optical absorption co-efficient β, refractive index n 2 , and third-order NLO susceptibility χ (3) of the films increasing with the increase in number of layers of the films, but also reveal importantly that the discrepancy of LUMO levels between CuTAPc and POMs is proportional to their third-order NLO response.

Optical nonlinearities of excitonic states in atomically thin 2D transition metal dichalcogenides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Soh, Daniel Beom Soo

We calculated the optical nonlinearities of the atomically thin monolayer transition metal dichalcogenide material (particularly MoS 2), particularly for those linear and nonlinear transition processes that utilize the bound exciton states. We adopted the bound and the unbound exciton states as the basis for the Hilbert space, and derived all the dynamical density matrices that provides the induced current density, from which the nonlinear susceptibilities can be drawn order-by-order via perturbative calculations. We provide the nonlinear susceptibilities for the linear, the second-harmonic, the third-harmonic, and the kerr-type two-photon processes.

Transparent electrode for optical switch

DOEpatents

Goldhar, J.; Henesian, M.A.

1984-10-19

The invention relates generally to optical switches and techniques for applying a voltage to an electro-optical crystal, and more particularly, to transparent electodes for an optical switch. System architectures for very large inertial confinement fusion (ICF) lasers require active optical elements with apertures on the order of one meter. Large aperture optical switches are needed for isolation of stages, switch-out from regenerative amplifier cavities and protection from target retroreflections.

Vectorial control of nonlinear emission via chiral butterfly nanoantennas: generation of pure high order nonlinear vortex beams.

PubMed

Lesina, Antonino Cala'; Berini, Pierre; Ramunno, Lora

2017-02-06

We report on a chiral gap-nanostructure, which we term a "butterfly nanoantenna," that offers full vectorial control over nonlinear emission. The field enhancement in its gap occurs for only one circular polarization but for every incident linear polarization. As the polarization, phase and amplitude of the linear field in the gap are highly controlled, the linear field can drive nonlinear emitters within the gap, which behave as an idealized Huygens source. A general framework is thereby proposed wherein the butterfly nanoantennas can be arranged in a metasurface, and the nonlinear Huygens sources exploited to produce a highly structured far-field optical beam. Nonlinearity allows us to shape the light at shorter wavelengths, not accessible by linear plasmonics, and resulting in high purity beams. The chirality of the butterfly allows us to create orbital angular momentum states using a linearly polarized excitation. A third harmonic Laguerre-Gauss beam carrying an optical orbital angular momentum of 41 is demonstrated as an example, through large-scale simulations on a high-performance computing platform of the full plasmonic metasurface with an area large enough to contain up to 3600 nanoantennas.

Synthesis and characterization of d10 metal complexes of 3-Me-5-FcPz: Structural, theoretical and third order nonlinear optical properties

NASA Astrophysics Data System (ADS)

Senthilkumar, Kabali; Thirumoorthy, Krishnan; Vinitha, G.; Soni, Kiran; Bhuvanesh, Nattamai S. P.; Palanisami, Nallasamy

2017-01-01

The d10 metal complexes based on 3-methyl-5-ferrocenyl-1H-pyrazole (L = 3-Me-5-FcPz) ligand [M(L)4(NO3)2] Zn=(1) and Cd=(2), [Hg(L)4(NO3)2].dmf (3) have been synthesized and characterized by FT-IR, NMR, UV-Vis and elemental analysis. The molecular structure of compound 2 and its crystal packing were determined by single crystal X-ray diffraction. The nitrate anions are also involved in intermolecular hydrogen bonding with adjacent ferrocene units and it forms zig-zag one-dimensional polymeric structure. UV-Vis investigations on the positive solvatochromic behavior of 1-3 revealed that the solvation of the push-pull character increases with increasing polarity. The third-order nonlinear optical (NLO) properties of 1-3 have been determined by Z-scan technique and the results indicate that compounds 1-3 exhibits the strong self-defocusing effect. The nonlinear susceptibility χ(3) values are calculated in the order of 10-6 esu.

Generalized nonlinear Schrödinger equation and ultraslow optical solitons in a cold four-state atomic system.

PubMed

Hang, Chao; Huang, Guoxiang; Deng, L

2006-03-01

We investigate the influence of high-order dispersion and nonlinearity on the propagation of ultraslow optical solitons in a lifetime broadened four-state atomic system under a Raman excitation. Using a standard method of multiple-scales we derive a generalized nonlinear Schrödinger equation and show that for realistic physical parameters and at the pulse duration of 10(-6)s, the effects of third-order linear dispersion, nonlinear dispersion, and delay in nonlinear refractive index can be significant and may not be considered as perturbations. We provide exact soliton solutions for the generalized nonlinear Schrödinger equation and demonstrate that optical solitons obtained may still have ultraslow propagating velocity. Numerical simulations on the stability and interaction of these ultraslow optical solitons in the presence of linear and differential absorptions are also presented.

Enhanced nonlinear optical response of an endohedral metallofullerene through metal-to-cage charge transfer

NASA Astrophysics Data System (ADS)

Heflin, J. R.; Marciu, D.; Figura, C.; Wang, S.; Burbank, P.; Stevenson, S.; Dorn, H. C.

1998-06-01

A new mechanism for increasing the third-order nonlinear optical susceptibility, χ(3), is described for endohedral metallofullerenes. A two to three orders of magnitude increase in the nonlinear response is reported for degenerate four-wave mixing experiments conducted with solutions of Er2@C82 (isomer III) relative to empty-cage fullerenes. A value of -8.7×10-32esu is found for the molecular susceptibility, γxyyx, of Er2@C82 compared to previously reported values of γxxxx=3×10-34 esu and γxyyx=4×10-35 esu for C60. The results confirm the importance of the metal-to-cage charge-transfer mechanism for enhancing the nonlinear optical response in endohedral metallofullerenes.

Quasi-phase-matched χ(3 )-parametric interactions in sinusoidally tapered waveguides

NASA Astrophysics Data System (ADS)

Saleh, Mohammed F.

2018-01-01

In this article, I show how periodically tapered waveguides can be employed as efficient quasi-phase-matching schemes for four-wave mixing parametric processes in third-order nonlinear materials. As an example, a thorough study of enhancing third-harmonic generation in sinusoidally tapered fibers has been conducted. The quasi-phase-matching condition has been obtained for nonlinear parametric interactions in these structures using Fourier-series analysis. The dependencies of the conversion efficiency of the third harmonic on the modulation amplitude, tapering period, longitudinal-propagation direction, and pump wavelength have been studied. In comparison to uniform waveguides, the conversion efficiency has been enhanced by orders of magnitudes. I envisage that this work will have a great impact in the field of guided nonlinear optics using centrosymmetric materials.

On marginally resolved objects in optical interferometry

NASA Astrophysics Data System (ADS)

Lachaume, R.

2003-03-01

With the present and soon-to-be breakthrough of optical interferometry, countless objects shall be within reach of interferometers; yet, most of them are expected to remain only marginally resolved with hectometric baselines. In this paper, we tackle the problem of deriving the properties of a marginally resolved object from its optical visibilities. We show that they depend on the moments of flux distribution of the object: centre, mean angular size, asymmetry, and curtosis. We also point out that the visibility amplitude is a second-order phenomenon, whereas the phase is a combination of a first-order term, giving the location of the photocentre, and a third-order term, more difficult to detect than the visibility amplitude, giving an asymmetry coefficient of the object. We then demonstrate that optical visibilities are not a good model constraint while the object stays marginally resolved, unless observations are carried out at different wavelengths. Finally, we show an application of this formalism to circumstellar discs.

Combined effects of nonparaxiality, optical activity, and walk-off on rogue wave propagation in optical fibers filled with chiral materials.

PubMed

Temgoua, D D Estelle; Tchokonte, M B Tchoula; Kofane, T C

2018-04-01

The generalized nonparaxial nonlinear Schrödinger (NLS) equation in optical fibers filled with chiral materials is reduced to the higher-order integrable Hirota equation. Based on the modified Darboux transformation method, the nonparaxial chiral optical rogue waves are constructed from the scalar model with modulated coefficients. We show that the parameters of nonparaxiality, third-order dispersion, and differential gain or loss term are the main keys to control the amplitude, linear, and nonlinear effects in the model. Moreover, the influence of nonparaxiality, optical activity, and walk-off effect are also evidenced under the defocusing and focusing regimes of the vector nonparaxial NLS equations with constant and modulated coefficients. Through an algorithm scheme of wider applicability on nonparaxial beam propagation methods, the most influential effect and the simultaneous controllability of combined effects are underlined, showing their properties and their potential applications in optical fibers and in a variety of complex dynamical systems.

Combined effects of nonparaxiality, optical activity, and walk-off on rogue wave propagation in optical fibers filled with chiral materials

NASA Astrophysics Data System (ADS)

Temgoua, D. D. Estelle; Tchokonte, M. B. Tchoula; Kofane, T. C.

2018-04-01

The generalized nonparaxial nonlinear Schrödinger (NLS) equation in optical fibers filled with chiral materials is reduced to the higher-order integrable Hirota equation. Based on the modified Darboux transformation method, the nonparaxial chiral optical rogue waves are constructed from the scalar model with modulated coefficients. We show that the parameters of nonparaxiality, third-order dispersion, and differential gain or loss term are the main keys to control the amplitude, linear, and nonlinear effects in the model. Moreover, the influence of nonparaxiality, optical activity, and walk-off effect are also evidenced under the defocusing and focusing regimes of the vector nonparaxial NLS equations with constant and modulated coefficients. Through an algorithm scheme of wider applicability on nonparaxial beam propagation methods, the most influential effect and the simultaneous controllability of combined effects are underlined, showing their properties and their potential applications in optical fibers and in a variety of complex dynamical systems.

Heterogeneous integration of lithium niobate and silicon nitride waveguides for wafer-scale photonic integrated circuits on silicon.

PubMed

Chang, Lin; Pfeiffer, Martin H P; Volet, Nicolas; Zervas, Michael; Peters, Jon D; Manganelli, Costanza L; Stanton, Eric J; Li, Yifei; Kippenberg, Tobias J; Bowers, John E

2017-02-15

An ideal photonic integrated circuit for nonlinear photonic applications requires high optical nonlinearities and low loss. This work demonstrates a heterogeneous platform by bonding lithium niobate (LN) thin films onto a silicon nitride (Si₃N₄) waveguide layer on silicon. It not only provides large second- and third-order nonlinear coefficients, but also shows low propagation loss in both the Si₃N₄ and the LN-Si₃N₄ waveguides. The tapers enable low-loss-mode transitions between these two waveguides. This platform is essential for various on-chip applications, e.g., modulators, frequency conversions, and quantum communications.

Z-scan and optical limiting properties of Hibiscus Sabdariffa dye

NASA Astrophysics Data System (ADS)

Diallo, A.; Zongo, S.; Mthunzi, P.; Rehman, S.; Alqaradawi, S. Y.; Soboyejo, W.; Maaza, M.

2014-12-01

The intensity-dependent refractive index n 2 and the nonlinear susceptibility χ (3) of Hibiscus Sabdariffa dye solutions in the nanosecond regime at 532 nm are reported. More presicely, the variation of n 2, β, and real and imaginary parts of χ (3) versus the natural dye extract concentration has been carried out by z-scan and optical limiting techniques. The third-order nonlinearity of the Hibiscus Sabdariffa dye solutions was found to be dominated by nonlinear refraction, which leads to strong optical limiting of laser.

Structural, optical and nonlinear optical studies of AZO thin film prepared by SILAR method for electro-optic applications

NASA Astrophysics Data System (ADS)

Edison, D. Joseph; Nirmala, W.; Kumar, K. Deva Arun; Valanarasu, S.; Ganesh, V.; Shkir, Mohd.; AlFaify, S.

2017-10-01

Aluminium doped (i.e. 3 at%) zinc oxide (AZO) thin films were prepared by simple successive ionic layer adsorption and reaction (SILAR) method with different dipping cycles. The structural and surface morphology of AZO thin films were studied by using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The optical parameters such as, transmittance, band gap, refractive index, extinction coefficient, dielectric constant and nonlinear optical properties of AZO films were investigated. XRD pattern revealed the formation of hexagonal phase ZnO and the intensity of the film was found to increase with increasing dipping cycle. The crystallite size was found to be in the range of 29-37 nm. Scanning Electron Microscope (SEM) images show the presence of small sized grains, revealing that the smoothest surface was obtained at all the films. The EDAX spectrum of AZO conforms the presence of Zn, O and Al. The optical transmittance in the visible region is high 87% and the band gap value is 3.23 eV. The optical transmittance is decreased with respect to dipping cycles. The room temperature PL studies revealed that the AZO films prepared at (30 cycles) has good film quality with lesser defect density. The third order nonlinear optical parameters were also studied using Z-scan technique to know the applications of deposited films in nonlinear devices. The third order nonlinear susceptibility value is found to be 1.69 × 10-7, 3.34 × 10-8, 1.33 × 10-7and 2.52 × 10-7 for AZO films deposited after 15, 20, 25 and 30 dipping cycles.

Characteristics of an Optical Delay Line for Radar Testing

DTIC Science & Technology

2016-04-12

MANUFACTURER PERFORMANCE MEASUREMENT ....................................... 2 3 NRL PERFORMANCE MEASUREMENT ...Third-Order-Intercept (TOI) ................... 7 3.4 Phase Noise Measurement ...MANUFACTURER PERFORMANCE MEASUREMENT Figures 3 to 5 are the Miteq’s FODL performance measured by the manufacturer prior to shipping the system to NRL

Third order nonlinear phenomena in silica solid and hollow whispering gallery mode resonators

NASA Astrophysics Data System (ADS)

Farnesi, D.; Barucci, A.; Berneschi, S.; Cosi, F.; Righini, G. C.; Nunzi Conti, G.; Soria, Silvia

2016-03-01

We report efficient generation of nonlinear phenomena related to third order optical non-linear susceptibility χ(3) interactions in resonant silica microspheres and microbubbles in the regime of normal dispersion. The interactions here reported are: Stimulated Raman Scattering (SRS), and four wave mixing processes comprising Stimulated Anti-stokes Raman Scattering (SARS) and comb generation. Unusually strong anti-Stokes components and extraordinarily symmetric spectra have been observed. Resonant SARS and SRS corresponding to different Raman bands were also observed. The lack of correlation between stimulated anti-stokes and stokes scattering spectra indicates that the signal has to be resonant with the cavity.

Phase-dependent ultrafast third-order optical nonlinearities in metallophthalocyanine thin films

NASA Astrophysics Data System (ADS)

Kumar, Samir; Anil Kumar, K. V.; Dharmaprakash, S. M.; Das, Ritwick

2016-09-01

We present a comprehensive study on the impact of phase transformations of metallophthalocyanine thin films on their third-order nonlinear optical (NLO) properties. The metallophthalocyanine thin films are prepared by thermally evaporating the commercially available Copper(II)2,9,16,23-Tetra-tert-butyl-29H,31H-phthalocyanine (CuPc) and Zinc(II) 2,9,16,23-Tetra-tert-butyl-29H,31H-phthalocyanine (ZnPc) powder on glass substrate. Thermal annealing causes a phase transformation which has a distinct signature in powder X-ray diffraction and UV-Vis-NIR spectroscopy. The NLO characteristics which include nonlinear refractive index n2, as well as nonlinear absorption coefficient (βeff), were measured by using a single beam Z-scan technique. An ultrashort pulsed fiber laser emitting femtosecond pulses (Δτ ≈ 250 fs) at 1064 nm central wavelength is used as a source for the Z-scan experiment. The βeff values in as prepared thin films were ascertained to be smaller as compared to the annealed one due to the smaller value of saturation intensity (Is) which, in turn, is a consequence of ground-state bleaching in the thermally unstable amorphous state of the molecule. Interestingly, the nonlinear refractive indices bear opposite sign for CuPc and ZnPc. The variations in the third-order nonlinearity in CuPc and ZnPc are discussed in terms of molecular packing and geometries of metallophthalocyanine molecules.

Bulk crystal growth and their effective third order nonlinear optical properties of 2-(4-fluorobenzylidene) malononitrile (FBM) single crystal

NASA Astrophysics Data System (ADS)

Priyadharshini, A.; Kalainathan, S.

2018-04-01

2-(4-fluorobenzylidene) malononitrile (FBM), an organic third order nonlinear (TONLO) single crystal with the dimensions of 32 × 7 × 11 mm3, has been successfully grown in acetone solution by slow evaporation technique at 35 °C. The crystal system (triclinic), space group (P-1) and crystalline purity of the titular crystal were measured by single crystal and powder X-ray diffraction, respectively. The molecular weight and the multiple functional groups of the FBM material were confirmed through the mass and FT-IR spectral analysis. UV-Vis-NIR spectral study enroles that the FBM crystal exhibits excellent transparency (83%) in the entire visible and near infra-red region with a wide bandgap 2.90 eV. The low dielectric constant (εr) value of FBM crystal is appreciable for microelectronics industry applications. Thermal stability and melting point (130.09 °C) were ascertained by TGA-DSC analysis. The laser-induced surface damage threshold (LDT) value of FBM specimen is found to be 2.14 GW/cm2, it is fairly good compared to other reported NLO crystals. The third - order nonlinear optical character of the FBM crystal was confirmed through the typical single beam Z-scan technique. All these finding authorized that the organic crystal of FBM is favorably suitable for NLO applications.

A design study for a compact two stage in-flight separator with a high mass resolution and large acceptance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hwang, Ji-Gwang; Kim, Eun-San, E-mail: eskim1@knu.ac.kr; Hatanaka, Kichiji

2015-03-15

The rare isotope beam separator with a large angular acceptance and energy acceptance is essential for examining the characteristics of unstable nuclei and exotic nuclear reactions. Careful design, however, is required to compensate for the effects of high order aberrations induced by large aperture magnets, which are used to collect rare isotopes obtained from a high energy primary heavy-ion beam hitting a target. In order to minimize the effect of the high order aberration, the optics was based on the mirror symmetry optics, which provides smaller high order aberrations, for the separation of {sup 132}Sn produced by a fission reactionmore » between the primary beam of {sup 238}U and a relatively thick Pb target. The designed optics provides energy acceptance (full), horizontal angular acceptance, and vertical acceptance of approximately 8%, 60 mrad, and 130 mrad, respectively.« less

A design study for a compact two stage in-flight separator with a high mass resolution and large acceptance.

PubMed

Hwang, Ji-Gwang; Kim, Eun-San; Hatanaka, Kichiji

2015-03-01

The rare isotope beam separator with a large angular acceptance and energy acceptance is essential for examining the characteristics of unstable nuclei and exotic nuclear reactions. Careful design, however, is required to compensate for the effects of high order aberrations induced by large aperture magnets, which are used to collect rare isotopes obtained from a high energy primary heavy-ion beam hitting a target. In order to minimize the effect of the high order aberration, the optics was based on the mirror symmetry optics, which provides smaller high order aberrations, for the separation of (132)Sn produced by a fission reaction between the primary beam of (238)U and a relatively thick Pb target. The designed optics provides energy acceptance (full), horizontal angular acceptance, and vertical acceptance of approximately 8%, 60 mrad, and 130 mrad, respectively.

A design study for a compact two stage in-flight separator with a high mass resolution and large acceptance

NASA Astrophysics Data System (ADS)

Hwang, Ji-Gwang; Kim, Eun-San; Hatanaka, Kichiji

2015-03-01

The rare isotope beam separator with a large angular acceptance and energy acceptance is essential for examining the characteristics of unstable nuclei and exotic nuclear reactions. Careful design, however, is required to compensate for the effects of high order aberrations induced by large aperture magnets, which are used to collect rare isotopes obtained from a high energy primary heavy-ion beam hitting a target. In order to minimize the effect of the high order aberration, the optics was based on the mirror symmetry optics, which provides smaller high order aberrations, for the separation of 132Sn produced by a fission reaction between the primary beam of 238U and a relatively thick Pb target. The designed optics provides energy acceptance (full), horizontal angular acceptance, and vertical acceptance of approximately 8%, 60 mrad, and 130 mrad, respectively.

Thiophene-based terpyridine and its zinc halide complexes: third-order nonlinear optical properties in the near-infrared region.

PubMed

Tan, Jingyun; Li, Rui; Li, Dandan; Zhang, Qiong; Li, Shengli; Zhou, Hongping; Yang, Jiaxiang; Wu, Jieying; Tian, Yupeng

2015-01-21

A novel 4'-(4-(diphenylamino)thienyl)-2,2':6',2''-terpyridine ligand () based on thiophene and its complexes (X = Cl, Br, I, SCN) was designed, synthesized and characterized by elemental analysis, far-IR, MALDI-TOF-MS, and single crystal X-ray diffraction analysis. Structural studies revealed that the central zinc(ii) atom adopted a distorted trigonal bipyramidal coordination model. However, there were different hydrogen bonds and stacking models with different counter anions in the crystals. The absorption properties of the compounds were investigated with the aid of TD-DFT computational methods. Furthermore, the third-order nonlinear optical (NLO) properties were systematically studied via open-aperture Z-scan methods using a tunable wavelength femtosecond laser. The results from photophysical property investigations suggested that the complexation of the thiophene-based terpyridine ligand with zinc halides resulted in strong ICT/LLCT bands of about 450 nm, and the complexes exhibited strong nonlinear optical response in the near-infrared range around 850 nm. Above all, the two-photon absorption (2PA) cross-section values (σ) were enhanced by coordination with zinc and influenced by halide ions, reaching up to 2583 GM (X = Br).

Characterization of the excited states of a squaraine molecule with quadratic electroabsorption spectroscopy

NASA Astrophysics Data System (ADS)

Poga, C.; Brown, T. M.; Kuzyk, M. G.; Dirk, Carl W.

1995-04-01

We apply quadratic electroabsorption spectroscopy (QES) to thin-film solid solutions of squarylium dye molecules in poly(methyl methacrylate) polymer to study the dye's electronic excited states and to investigate the importance of these states with regard to their contribution to the third-order nonlinear-optical susceptibility. We first show that the room-temperature tensor ratio a= chi (3)3333/ chi (3)1133 \\approximately 3 throughout most of the visible region to establish that the electronic mechanism dominates. Because QES is a third-order nonlinear-optical susceptibility measurement, it can be used to identify two photon states. By obtaining good agreement between the quadratic electroabsorption spectrum and a three level model, we conclude that there are two dominant states that contribute to the near-resonant and a two-photon state that are separated by less than 0.2 eV in energy. QES is thus shown to be a versatile tool for measuring the nature of excited states in a molecule. Furthermore, by applying a Kramers-Kronig transformation to determine the real part of the response, we are able to assess the two-photon all-optical device figure of merit of these materials. Such an

Third-order optical nonlinearity studies of bilayer Au/Ag metallic films

NASA Astrophysics Data System (ADS)

Mezher, M. H.; Chong, W. Y.; Zakaria, R.

2016-05-01

This paper presents nonlinear optical studies of bilayer metallic films of gold (Au) and silver (Ag) on glass substrate prepared using electron beam evaporation. The preparation of Au and Ag nanoparticles (NPs) on the substrate involved the use of electron beam deposition, then thermal annealing at 600 °C and 270 °C, respectively, to produce a randomly distributed layer of Au and a layer of Ag NPs. Observation of field-effect scanning electron microscope images indicated the size of the NPs. Details of the optical properties related to peak absorption of surface plasmon resonance of the nanoparticle were revealed by use of UV-Vis spectroscopy. The Z-scan technique was used to measure the nonlinear absorption and nonlinear refraction of the fabricated NP layers. The third-order nonlinear refractive index coefficients for Au and Ag are (-9.34 and  -1.61)  ×  10-11 cm2 W-1 given lower n 2, in comparison with bilayer (Au and Ag) NPs at  -1.24  ×  10-10 cm2 W-1. The results show bilayer NPs have higher refractive index coefficients thus enhance the nonlinearity effects.

Possible higher order phase transition in large-N gauge theory at finite temperature

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nishimura, Hiromichi

2017-08-07

We analyze the phase structure of SU(¥) gauge theory at finite temperature using matrix models. Our basic assumption is that the effective potential is dominated by double-trace terms for the Polyakov loops. As a function of the temperature, a background field for the Polyakov loop, and a quartic coupling, it exhibits a universal structure: in the large portion of the parameter space, there is a continuous phase transition analogous to the third-order phase transition of Gross,Witten and Wadia, but the order of phase transition can be higher than third. We show that different confining potentials give rise to drastically differentmore » behavior of the eigenvalue density and the free energy. Therefore lattice simulations at large N could probe the order of phase transition and test our results. Critical« less

Coherent Femtosecond Spectroscopy and Nonlinear Optical Imaging on the Nanoscale

NASA Astrophysics Data System (ADS)

Kravtsov, Vasily

Optical properties of many materials and macroscopic systems are defined by ultrafast dynamics of electronic, vibrational, and spin excitations localized on the nanoscale. Harnessing these excitations for material engineering, optical computing, and control of chemical reactions has been a long-standing goal in science and technology. However, it is challenging due to the lack of spectroscopic techniques that can resolve processes simultaneously on the nanometer spatial and femtosecond temporal scales. This thesis describes the fundamental principles, implementation, and experimental demonstration of a novel type of ultrafast microscopy based on the concept of adiabatic plasmonic nanofocusing. Simultaneous spatio-temporal resolution on a nanometer-femtosecond scale is achieved by using a near-field nonlinear optical response induced by ultrafast surface plasmon polaritons nanofocused on a metal tip. First, we study the surface plasmon response in metallic structures and evaluate its prospects and limitations for ultrafast near-field microscopy. Through plasmon emission-based spectroscopy, we investigate dephasing times and interplay between radiative and non-radiative decay rates of localized plasmons and their modification due to coupling. We identify a new regime of quantum plasmonic coupling, which limits the achievable spatial resolution to several angstroms but at the same time provides a potential channel for generating ultrafast electron currents at optical frequencies. Next, we study propagation of femtosecond wavepackets of surface plasmon polaritons on a metal tip. In time-domain interferometric measurements we detect group delays that correspond to slowing of the plasmon polaritons down to 20% of the speed of light at the tip apex. This provides direct experimental verification of the plasmonic nanofocusing mechanism and suggests enhanced nonlinear optical interactions at the tip apex. We then measure a plasmon-generated third-order nonlinear optical four-wave mixing response from the tip apex and investigate its microscopic mechanism. Our results reveal a significant contribution to the third order nonlinearity of plasmonic structures due to large near-field gradients associated with nanofocused plasmons. In combination with scanning probe imaging and femtosecond pulse shaping, the nanofocused four-wave mixing response provides a basis for a novel type of ultrafast optical microscopy on the nanoscale. We demonstrate its capabilities by nano-imaging the coherent dynamics of localized plasmonic modes in a rough gold film edge with simultaneous sub-50 nm spatial and sub-5 fs temporal resolution. We capture the coherent decay and extract the dephasing times of individual plasmonic modes. Lastly, we apply our technique to study nanoscale spatial heterogeneity of the nonlinear optical response in novel two-dimensional materials: monolayer and few-layer graphene. An enhanced four-wave mixing signal is revealed on the edges of graphene flakes. We investigate the mechanism of this enhancement by performing nano-imaging on a graphene field-effect transistor with the variable carrier density controlled by electrostatic gating.

MEMS-tunable dielectric metasurface lens.

PubMed

Arbabi, Ehsan; Arbabi, Amir; Kamali, Seyedeh Mahsa; Horie, Yu; Faraji-Dana, MohammadSadegh; Faraon, Andrei

2018-02-23

Varifocal lenses, conventionally implemented by changing the axial distance between multiple optical elements, have a wide range of applications in imaging and optical beam scanning. The use of conventional bulky refractive elements makes these varifocal lenses large, slow, and limits their tunability. Metasurfaces, a new category of lithographically defined diffractive devices, enable thin and lightweight optical elements with precisely engineered phase profiles. Here we demonstrate tunable metasurface doublets, based on microelectromechanical systems (MEMS), with more than 60 diopters (about 4%) change in the optical power upon a 1-μm movement of one metasurface, and a scanning frequency that can potentially reach a few kHz. They can also be integrated with a third metasurface to make compact microscopes (~1 mm thick) with a large corrected field of view (~500 μm or 40 degrees) and fast axial scanning for 3D imaging. This paves the way towards MEMS-integrated metasurfaces as a platform for tunable and reconfigurable optics.

Extended depth of focus adaptive optics spectral domain optical coherence tomography

PubMed Central

Sasaki, Kazuhiro; Kurokawa, Kazuhiro; Makita, Shuichi; Yasuno, Yoshiaki

2012-01-01

We present an adaptive optics spectral domain optical coherence tomography (AO-SDOCT) with a long focal range by active phase modulation of the pupil. A long focal range is achieved by introducing AO-controlled third-order spherical aberration (SA). The property of SA and its effects on focal range are investigated in detail using the Huygens-Fresnel principle, beam profile measurement and OCT imaging of a phantom. The results indicate that the focal range is extended by applying SA, and the direction of extension can be controlled by the sign of applied SA. Finally, we demonstrated in vivo human retinal imaging by altering the applied SA. PMID:23082278

Extended depth of focus adaptive optics spectral domain optical coherence tomography.

PubMed

Sasaki, Kazuhiro; Kurokawa, Kazuhiro; Makita, Shuichi; Yasuno, Yoshiaki

2012-10-01

We present an adaptive optics spectral domain optical coherence tomography (AO-SDOCT) with a long focal range by active phase modulation of the pupil. A long focal range is achieved by introducing AO-controlled third-order spherical aberration (SA). The property of SA and its effects on focal range are investigated in detail using the Huygens-Fresnel principle, beam profile measurement and OCT imaging of a phantom. The results indicate that the focal range is extended by applying SA, and the direction of extension can be controlled by the sign of applied SA. Finally, we demonstrated in vivo human retinal imaging by altering the applied SA.

Effects of higher order aberrations on beam shape in an optical recording system

NASA Technical Reports Server (NTRS)

Wang, Mark S.; Milster, Tom D.

1992-01-01

An unexpected irradiance pattern in the detector plane of an optical data storage system was observed. Through wavefront measurement and scalar diffraction modeling, it was discovered that the energy redistribution is due to residual third-order and fifth-order spherical aberration of the objective lens and cover-plate assembly. The amount of residual aberration is small, and the beam focused on the disk would be considered diffraction limited by several criteria. Since the detector is not in the focal plane, even this small amount of aberration has a significant effect on the energy distribution. We show that the energy redistribution can adversely affect focus error signals, which are responsible for maintaining sub-micron spot diameters on the spinning disk.

A photonic chip based frequency discriminator for a high performance microwave photonic link.

PubMed

Marpaung, David; Roeloffzen, Chris; Leinse, Arne; Hoekman, Marcel

2010-12-20

We report a high performance phase modulation direct detection microwave photonic link employing a photonic chip as a frequency discriminator. The photonic chip consists of five optical ring resonators (ORRs) which are fully programmable using thermo-optical tuning. In this discriminator a drop-port response of an ORR is cascaded with a through response of another ORR to yield a linear phase modulation (PM) to intensity modulation (IM) conversion. The balanced photonic link employing the PM to IM conversion exhibits high second-order and third-order input intercept points of + 46 dBm and + 36 dBm, respectively, which are simultaneously achieved at one bias point.

All-optical 1st- and 2nd-order differential equation solvers with large tuning ranges using Fabry-Pérot semiconductor optical amplifiers.

PubMed

Chen, Kaisheng; Hou, Jie; Huang, Zhuyang; Cao, Tong; Zhang, Jihua; Yu, Yuan; Zhang, Xinliang

2015-02-09

We experimentally demonstrate an all-optical temporal computation scheme for solving 1st- and 2nd-order linear ordinary differential equations (ODEs) with tunable constant coefficients by using Fabry-Pérot semiconductor optical amplifiers (FP-SOAs). By changing the injection currents of FP-SOAs, the constant coefficients of the differential equations are practically tuned. A quite large constant coefficient tunable range from 0.0026/ps to 0.085/ps is achieved for the 1st-order differential equation. Moreover, the constant coefficient p of the 2nd-order ODE solver can be continuously tuned from 0.0216/ps to 0.158/ps, correspondingly with the constant coefficient q varying from 0.0000494/ps(2) to 0.006205/ps(2). Additionally, a theoretical model that combining the carrier density rate equation of the semiconductor optical amplifier (SOA) with the transfer function of the Fabry-Pérot (FP) cavity is exploited to analyze the solving processes. For both 1st- and 2nd-order solvers, excellent agreements between the numerical simulations and the experimental results are obtained. The FP-SOAs based all-optical differential-equation solvers can be easily integrated with other optical components based on InP/InGaAsP materials, such as laser, modulator, photodetector and waveguide, which can motivate the realization of the complicated optical computing on a single integrated chip.

Synthesis, growth, structural and optical studies of a new organic three dimensional framework: 4-(aminocarbonyl)pyridine 4-(aminocarbonyl)pyridinium hydrogen L-malate

NASA Astrophysics Data System (ADS)

Vijayalakshmi, A.; Vidyavathy, B.; Peramaiyan, G.; Vinitha, G.

2017-02-01

4-(aminocarbonyl)pyridine 4-(aminocarbonyl)pyridinium hydrogen L-malate [(4ACP)(4ACP).(LM)] a new organic nonlinear optical (NLO) crystal was grown by the slow evaporation method. Single crystal X-ray diffraction analysis revealed that the [(4ACP)(4ACP).(LM)] crystal belongs to monoclinic crystal system, space group P21/n, with a three dimensional network. Thermogravimetry (TG) and differential thermal (DT) analyses showed that [(4ACP)(4ACP).(LM)] is thermally stable up to 165 °C. The optical transmittance window and the lower cut-off wavelength of [(4ACP)(4ACP).(LM)] were found out by UV-vis-NIR spectral study. The molecular structure of [(4ACP)(4ACP).(LM)] was further confirmed by FTIR spectral studies. The relative dielectric permittivity and dielectric loss were determined as function of frequency and temperature. The third order nonlinear optical property of [(4ACP)(4ACP).(LM)] was studied by the Z-scan technique using a 532 nm diode pumped CW Nd:YAG laser. Nonlinear refractive index, nonlinear absorption coefficient and third order nonlinear susceptibility of the grown crystal were found to be 7.38×10-8 cm2/W, 0.08×10-4 cm/W and 5.36×10-6 esu, respectively. The laser damage threshold value is found to be 1.75 GW/cm2

Coherent nonlinear optical response of single-layer black phosphorus: third-harmonic generation

NASA Astrophysics Data System (ADS)

Margulis, Vladimir A.; Muryumin, Evgeny E.; Gaiduk, Evgeny A.

2017-10-01

We theoretically calculate the nonlinear optical (NLO) response of phosphorene (a black phosphorus monolayer) to a normally incident and linearly polarized coherent laser radiation of frequency ω, resulting in the generation of radiation at frequency 3ω. We derive explicit analytic expressions for four independent nonvanishing elements of the third-order NLO susceptibility tensor, describing the third-harmonic generation (THG) from phosphorene. The final formulas are numerically evaluated for typical values of the system's parameters to explore how the efficiency of the THG varies with both the frequency and the polarization direction of the incident radiation. The results obtained show a resonant enhancement of the THG efficiency when the pump photon energy ℏω approaches a value of one third of the bandgap energy Eg (≈1.5 eV) of phosphorene. It is also shown that the THG efficiency exhibits a specific polarization dependence, allowing the THG to be used for determining the orientation of phosphorene's crystallographic axes. Our findings highlight the material's potential for practical application in nanoscale photonic devices such as frequency convertors operating in the near-infrared spectral range.

Study of nonlinear refraction of organic dye by Z-scan technique using He-Ne laser

DOE Office of Scientific and Technical Information (OSTI.GOV)

Medhekar, S.; Kumar, R.; Mukherjee, S.

2013-02-05

Laser induced third-order nonlinear optical responses of Brilliant Green solution has been investigated by utilizing single beam Z-scan technique with a continuous-wave He-Ne laser radiation at 632.8 nm. It was observed that the material exhibits self-defocusing type optical nonlinearity. The measurements of nonlinear refraction were carried out at different dye concentrations and found that the increase in solution concentration leads to the linear increase of the nonlinear refractive index. The experimental results confirm great potential of the Brilliant Green for the application in nonlinear optical devices.

The Japanese containerless experiments

NASA Technical Reports Server (NTRS)

Azuma, Hisao

1990-01-01

There are three sets of Japanese containerless experiments. The first is Drop dynamics research. It consists of acoustic levitation and large amplitude drop oscillation. The second is Optical materials processing in an acoustic levitation furnace. And the third is Electrostatic levitator development by two different Japanese companies.

Experimental study of the third-order nonlinearity of atomic and molecular gases using 10-μm laser pulses

NASA Astrophysics Data System (ADS)

Pigeon, J. J.; Tochitsky, S. Ya.; Welch, E. C.; Joshi, C.

2018-04-01

We present measurements of the third-order optical nonlinearity of Kr, Xe, N2, O2, and air at a wavelength near 10 µm by using four-wave mixing of ˜15 -GW /c m2 , 200-ps (full width at half maximum) C O2 laser pulses. Measurements in molecular gases resulted in an asymmetric four-wave mixing spectrum indicating that the nonlinear response is strongly affected by the delayed, rotational contribution to the effective nonlinear refractive index. Within the uncertainty of our measurements, we have found that the long-wavelength nonlinear refractive indices of these gases are consistent with measurements performed in the near IR.

Estimating the Volterra Series Transfer Function over coherent optical OFDM for efficient monitoring of the fiber channel nonlinearity.

PubMed

Shulkind, Gal; Nazarathy, Moshe

2012-12-17

We present an efficient method for system identification (nonlinear channel estimation) of third order nonlinear Volterra Series Transfer Function (VSTF) characterizing the four-wave-mixing nonlinear process over a coherent OFDM fiber link. Despite the seemingly large number of degrees of freedom in the VSTF (cubic in the number of frequency points) we identified a compressed VSTF representation which does not entail loss of information. Additional slightly lossy compression may be obtained by discarding very low power VSTF coefficients associated with regions of destructive interference in the FWM phased array effect. Based on this two-staged VSTF compressed representation, we develop a robust and efficient algorithm of nonlinear system identification (optical performance monitoring) estimating the VSTF by transmission of an extended training sequence over the OFDM link, performing just a matrix-vector multiplication at the receiver by a pseudo-inverse matrix which is pre-evaluated offline. For 512 (1024) frequency samples per channel, the VSTF measurement takes less than 1 (10) msec to complete with computational complexity of one real-valued multiply-add operation per time sample. Relative to a naïve exhaustive three-tone-test, our algorithm is far more tolerant of ASE additive noise and its acquisition time is orders of magnitude faster.

Synthesis, characterization and theoretical investigations of the structure, electronic properties and third-order nonlinearity optics (NLO) of M(DPIP)2

NASA Astrophysics Data System (ADS)

Li, Kang; Tang, Guodong; Kou, ShanShan; Culnane, Lance F.; Zhang, Yu; Song, Yinglin; Li, Rongqing; Wei, Changmei

2015-03-01

Three complexes of M(DPIP)2 (M = Cu, Co, Zn as 1, 2, 3) were synthesized and characterized by elemental analysis, IR, UV-Vis, thermogravimetry, and X-ray diffraction. Their nonlinear optical properties were measured by the Z-scan technique and yielded a normalized transmittance of about 70% for complex 1 (45 μJ pulse), and 93% for complex 3 (68 μJ pulse at the focus point). The nonlinear absorption coefficient, β, is 1.4 × 10-11 m/W for 1 and 5.6 × 10-13 m/W for 3, and the third-order nonlinear refraction index, n2, is 1.0 × 10-18 m2/W for 3. Complex 1 shows self-defocusing property, while complex 3 exhibits self-focusing property. The thermogravimetric results show that the frame structure of compounds 1-3 begin to collapse at 400, 250 and 280 °C, respectively, which suggests that they elicit excellent thermal stability. This research aims to provide better understanding of these compounds, and offer preliminary explanations for the significant differences between compounds 1-3, in order to potentially help in the designing of future novel materials with NLO properties.

Control of optical bistability and third-order nonlinearity via tunneling induced quantum interference in triangular quantum dot molecules

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tian, Si-Cong, E-mail: tiansicong@ciomp.ac.cn; Tong, Cun-Zhu, E-mail: tongcz@ciomp.ac.cn; Zhang, Jin-Long

The optical bistability of a triangular quantum dot molecules embedded inside a unidirectional ring cavity is studied. The type, the threshold and the hysteresis loop of the optical bistability curves can be modified by the tunneling parameters, as well as the probe laser field. The linear and nonlinear susceptibilities of the medium are also studied to interpret the corresponding results. The physical interpretation is that the tunneling can induce the quantum interference, which modifies the linear and the nonlinear response of the medium. As a consequence, the characteristics of the optical bistability are changed. The scheme proposed here can bemore » utilized for optimizing and controlling the optical switching process.« less

Parallel Optical Random Access Memory (PORAM)

NASA Technical Reports Server (NTRS)

Alphonse, G. A.

1989-01-01

It is shown that the need to minimize component count, power and size, and to maximize packing density require a parallel optical random access memory to be designed in a two-level hierarchy: a modular level and an interconnect level. Three module designs are proposed, in the order of research and development requirements. The first uses state-of-the-art components, including individually addressed laser diode arrays, acousto-optic (AO) deflectors and magneto-optic (MO) storage medium, aimed at moderate size, moderate power, and high packing density. The next design level uses an electron-trapping (ET) medium to reduce optical power requirements. The third design uses a beam-steering grating surface emitter (GSE) array to reduce size further and minimize the number of components.

[Zn(C 7H 3O 5N)] n · nH 2O: A third-order NLO Zn coordination polymer with spiroconjugated structure

NASA Astrophysics Data System (ADS)

Zhou, Guo-Wei; Lan, You-Zhao; Zheng, Fa-Kun; Zhang, Xin; Lin, Meng-Hai; Guo, Guo-Cong; Huang, Jin-Shun

2006-08-01

[Zn(C 7H 3O 5N)] n · nH 2O ( 1) possesses an anticlockwise windmill-like framework structure and formats spiroconjugation over the infinite molecular layer that is predicted to have large static third-order polarizability and the convergence value of γxxxx reaches 6.86 × 10 -33 esu in the case of zero input photon energy. The third-order NLO properties of 1 were investigated via Z-scan techniques at wavelength of 532 nm. It showed strong third-order NLO absorptive properties, and its n2 value was calculated to be 4.15 × 10 -11 esu. The relationship between the spiroconjugated structure and the NLO property has been discussed, which supposed to be more valuable for the NLO research.

Stimulated Brillouin scattering materials, experimental design and applications: A review

NASA Astrophysics Data System (ADS)

Bai, Zhenxu; Yuan, Hang; Liu, Zhaohong; Xu, Pengbai; Gao, Qilin; Williams, Robert J.; Kitzler, Ondrej; Mildren, Richard P.; Wang, Yulei; Lu, Zhiwei

2018-01-01

Stimulated Brillouin scattering (SBS), as one type of third-order nonlinear optics effect, is extensively exploited and rapidly developed in the field of lasers and optoelectronics. A large number of theoretical and experimental studies on SBS have been carried out in the past decades. Especially, the exploration of new SBS materials and new types of SBS modulation methods have been engaged simultaneously, as the properties of different materials have great influence on the SBS performance such as generation threshold, Brillouin amplification efficiency, frequency shift, breakdown threshold, etc. This article provides a comprehensive review of the characteristics of different types of SBS materials, SBS applications, experimental design methods, as well as the parameter optimization method, which is expected to provide reference and guidance to SBS related experiments.

High-dynamic-range cross-correlator for shot-to-shot measurement of temporal contrast

NASA Astrophysics Data System (ADS)

Kon, Akira; Nishiuchi, Mamiko; Kiriyama, Hiromitsu; Ogura, Koichi; Mori, Michiaki; Sakaki, Hironao; Kando, Masaki; Kondo, Kiminori

2017-01-01

The temporal contrast of an ultrahigh-intensity laser is a crucial parameter for laser plasma experiments. We have developed a multichannel cross-correlator (MCCC) for single-shot measurements of the temporal contrast in a high-power laser system. The MCCC is based on third-order cross-correlation, and has four channels and independent optical delay lines. We have experimentally demonstrated that the MCCC system achieves a high dynamic range of ˜1012 and a large temporal window of ˜1 ns. Moreover, we were able to measure the shot-to-shot fluctuations of a short-prepulse intensity at -26 ps and long-pulse (amplified spontaneous emission, ASE) intensities at -30, -450, and -950 ps before the arrival of the main pulse at the interaction point.

Whole-angle spherical retroreflector using concentric layers of homogeneous optical media.

PubMed

Oakley, John P

2007-03-01

Spherical retroreflectors have a much greater acceptance angle than conventional retroreflectors such as corner cubes. However, the optical performance of known spherical reflectors is limited by spherical aberration. It is shown that third-order spherical aberration may be corrected by using two or more layers of homogeneous optical media of different refractive indices. The performance of the retroreflector is characterized by the scattering (or radar) cross section, which is calculated by using optical design software. A practical spherical reflector is described that offers a significant increase in optical performance over existing devices. No gradient index components are required, and the device is constructed by using conventional optical materials and fabrication techniques. The experimental results confirm that the device operates correctly at the design wavelength of 690 nm.

Nonlinear optical response in graphene nanoribbons: The critical role of electron scattering

NASA Astrophysics Data System (ADS)

Karimi, F.; Davoody, A. H.; Knezevic, I.

2018-06-01

Nonlinear nanophotonics has many potential applications, such as in mode locking, frequency-comb generation, and all-optical switching. The development of materials with large nonlinear susceptibility is key to realizing nonlinear nanophotonics. Nanostructured graphene systems, such as graphene nanoribbons and nanoislands, have been predicted to have a strong plasmon-enhanced nonlinear optical behavior in the nonretarded regime. Plasmons concentrate the light field down to subwavelength scales and can enhance the nonlinear optical effects; however, plasmon resonances are narrowband and sensitive to the nanostructure geometry. Here we show that graphene nanoribbons, particularly armchair graphene nanoribbons, have a remarkably strong nonlinear optical response in the long-wavelength regime and over a broad frequency range, from terahertz to the near infrared. We use a quantum-mechanical master equation with a detailed treatment of scattering and show that, in the retarded regime, electron scattering has a critical effect on the optical nonlinearity of graphene nanoribbons, which cannot be captured via the commonly used relaxation-time approximation. At terahertz frequencies, where intraband optical transitions dominate, the strong nonlinearity (in particular, third-order Kerr nonlinearity) stems from the jagged shape of the electron energy distribution, caused by the interband electron scattering mechanisms along with the intraband inelastic scattering mechanisms. We show that the relaxation-time approximation fails to capture this quantum-mechanical phenomenon and results in a significant underestimation of the intraband nonlinearity. At the midinfrared to near infrared frequencies, where interband optical transitions dominate, the Kerr nonlinearity is significantly overestimated within the relaxation-time approximation. These findings unveil the critical effect of electron scattering on the optical nonlinearity of nanostructured graphene, and also underscore the capability of this class of materials for nonlinear nanophotonic applications.

Optical rogue waves generation in a nonlinear metamaterial

NASA Astrophysics Data System (ADS)

Onana Essama, Bedel Giscard; Atangana, Jacques; Biya-Motto, Frederick; Mokhtari, Bouchra; Cherkaoui Eddeqaqi, Noureddine; Kofane, Timoleon Crepin

2014-11-01

We investigate the behavior of electromagnetic wave which propagates in a metamaterial for negative index regime. The optical pulse propagation is described by the nonlinear Schrödinger equation with cubic-quintic nonlinearities, second- and third-order dispersion effects. The behavior obtained for negative index regime is compared to that observed for positive index regime. The characterization of electromagnetic wave uses some pulse parameters obtained analytically and called collective coordinates such as amplitude, temporal position, width, chirp, frequency shift and phase. Six frequency ranges have been pointed out where a numerical evolution of collective coordinates and their stability are studied under a typical example to verify our analysis. It appears that a robust soliton due to a perfect compensation process between second-order dispersion and cubic-nonlinearity is presented at each frequency range for both negative and positive index regimes. Thereafter, the stability of the soliton pulse and physical conditions leading to optical rogue waves generation are discussed at each frequency range for both regimes, when third-order dispersion and quintic-nonlinearity come into play. We have demonstrated that collective coordinates give much useful information on external and internal behavior of rogue events. Firstly, we determine at what distance begins the internal excitation leading to rogue waves. Secondly, what kind of internal modification and how it modifies the system in order to build-up rogue events. These results lead to a best comprehension of the mechanism of rogue waves generation. So, it clearly appears that the rogue wave behavior strongly depends on nonlinearity strength of distortion, frequency and regime considered.

Large dynamic range optical vector analyzer based on optical single-sideband modulation and Hilbert transform

NASA Astrophysics Data System (ADS)

Xue, Min; Pan, Shilong; Zhao, Yongjiu

2016-07-01

A large dynamic range optical vector analyzer (OVA) based on optical single-sideband modulation is proposed and demonstrated. By dividing the optical signal after optical device under test into two paths, reversing the phase of one swept sideband using a Hilbert transformer in one path, and detecting the two signals from the two paths with a balanced photodetector, the measurement errors induced by the residual -1st-order sideband and the high-order sidebands can be eliminated and the dynamic range of the measurement is increased. In a proof-of-concept experiment, the stimulated Brillouin scattering and a fiber Bragg grating are measured by OVAs with and without the Hilbert transform and balanced photodetection. Results show that about 40-dB improvement in the measurement dynamic range is realized by the proposed OVA.

FOUR DUAL AGN CANDIDATES OBSERVED WITH THE VLBA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gabányi, K. É.; Frey, S.; An, T.

According to hierarchical structure formation models, merging galaxies are expected to be seen in different stages of coalescence. However, there are currently no straightforward observational methods to either select or to confirm a large number of dual active galactic nucleus (AGN) candidates. Most attempts involve obtaining a better understanding of double-peaked narrow emission line sources, in order to distinguish the objects for which the emission lines originate from narrow-line kinematics or jet-driven outflows, from those which might harbor dual AGNs. We observed four such candidate sources with the Very Long Baseline Array (VLBA), at 1.5 GHz with a ∼10 masmore » angular resolution, for which the spectral profiles of AGN optical emission suggested the existence of dual AGNs. In SDSS J210449.13–000919.1 and SDSS J23044.82–093345.3 the radio structures are aligned with the optical emission features, thus the double-peaked emission lines might be the results of jet-driven outflows. In the third detected source SDSS J115523.74+150756.9, the radio structure is less extended and is oriented nearly perpendicular to the position angle derived from optical spectroscopy. The fourth source remained undetected with the VLBA, but it was imaged with the Very Large Array at arcsec resolution a few months before our observations, suggesting the existence of an extended radio structure. We did not detect two radio-emitting cores in any of the four sources, a convincing signature of duality.« less

Cross-quadrature modulation with the Raman-induced Kerr effect

NASA Astrophysics Data System (ADS)

Levenson, M. D.; Holland, M. J.; Walls, D. F.; Manson, P. J.; Fisk, P. T. H.; Bachor, H. A.

1991-08-01

The Raman-enhanced third-order optical nonlinearity of calcite potentially can support resonant back-action-evading measurement of the optical-field amplitude. In a preliminary experiment, we have observed cross-quadrature modulation transfer between an amplitude-modulated pump beam and an unmodulated probe beam tuned near the Stokes frequency. The theory of Holland et al. [Phys. Rev. A 42, 2995 (1990)] is extended to the case for which intracavity losses are significant in an attempt to account for the observations.

Femtosecond nonlinear optical properties of laser ablated gold nanoparticles in water

NASA Astrophysics Data System (ADS)

Krishnakanth, K. N.; Bharathi, M. S. S.; Hamad, S.; Rao, S. Venugopal

2018-04-01

Femtosecond third order nonlinear optical (NLO) properties of ultrafast laser ablated gold (Au) colloidsin distilled waterare investigatedusing degenerate four wave mixing technique with 50fs pulses at 800nm wavelength. The estimated value of χ(3) obtained for Au nanoparticles is 1.93×10-14 e.s.u. The characterization of the NPs was achieved done using TEM and HR-TEM techniques. We also present the time resolved studies of Au colloids by using DFWM technique in the forward BOXCAR phase matching geometry.

Chaos-assisted broadband momentum transformation in optical microresonators

NASA Astrophysics Data System (ADS)

Jiang, Xuefeng; Shao, Linbo; Zhang, Shu-Xin; Yi, Xu; Wiersig, Jan; Wang, Li; Gong, Qihuang; Lončar, Marko; Yang, Lan; Xiao, Yun-Feng

2017-10-01

The law of momentum conservation rules out many desired processes in optical microresonators. We report broadband momentum transformations of light in asymmetric whispering gallery microresonators. Assisted by chaotic motions, broadband light can travel between optical modes with different angular momenta within a few picoseconds. Efficient coupling from visible to near-infrared bands is demonstrated between a nanowaveguide and whispering gallery modes with quality factors exceeding 10 million. The broadband momentum transformation enhances the device conversion efficiency of the third-harmonic generation by greater than three orders of magnitude over the conventional evanescent-wave coupling. The observed broadband and fast momentum transformation could promote applications such as multicolor lasers, broadband memories, and multiwavelength optical networks.

Heterodyne detection using spectral line pairing for spectral phase encoding optical code division multiple access and dynamic dispersion compensation.

PubMed

Yang, Yi; Foster, Mark; Khurgin, Jacob B; Cooper, A Brinton

2012-07-30

A novel coherent optical code-division multiple access (OCDMA) scheme is proposed that uses spectral line pairing to generate signals suitable for heterodyne decoding. Both signal and local reference are transmitted via a single optical fiber and a simple balanced receiver performs sourceless heterodyne detection, canceling speckle noise and multiple-access interference (MAI). To validate the idea, a 16 user fully loaded phase encoded system is simulated. Effects of fiber dispersion on system performance are studied as well. Both second and third order dispersion management is achieved by using a spectral phase encoder to adjust phase shifts of spectral components at the optical network unit (ONU).

Mach-Zehnder interferometer implementation for thermo-optical and Kerr effect study

NASA Astrophysics Data System (ADS)

Bundulis, Arturs; Nitiss, Edgars; Busenbergs, Janis; Rutkis, Martins

2018-04-01

In this paper, we propose the Mach-Zehnder interferometric method for third-order nonlinear optical and thermo-optical studies. Both effects manifest themselves as refractive index dependence on the incident light intensity and are widely employed for multiple opto-optical and thermo-optical applications. With the implemented method, we have measured the Kerr and thermo-optical coefficients of chloroform under CW, ns and ps laser irradiance. The application of lasers with different light wavelengths, pulse duration and energy allowed us to distinguish the processes responsible for refractive index changes in the investigated solution. Presented setup was also used for demonstration of opto-optical switching. Results from Mach-Zehnder experiment were compared to Z-scan data obtained in our previous studies. Based on this, a quality comparison of both methods was assessed and advantages and disadvantages of each method were analyzed.

Low-cost Large Aperture Telescopes for Optical Communications

NASA Technical Reports Server (NTRS)

Hemmati, Hamid

2006-01-01

Low-cost, large-aperture optical receivers are required to form an affordable optical ground receiver network for laser communications. Among the ground receiver station's multiple subsystems, here, we only discuss the ongoing research activities aimed at reducing the cost of the large-size optics on the receiver. Experimental results of two different approaches for fabricating low-cost mirrors of wavefront quality on the order of 100-200X the diffraction limit are described. Laboratory-level effort are underway to improve the surface figure to better than 20X the diffraction limit.

Cost-effective accurate coarse-grid method for highly convective multidimensional unsteady flows

NASA Technical Reports Server (NTRS)

Leonard, B. P.; Niknafs, H. S.

1991-01-01

A fundamentally multidimensional convection scheme is described based on vector transient interpolation modeling rewritten in conservative control-volume form. Vector third-order upwinding is used as the basis of the algorithm; this automatically introduces important cross-difference terms that are absent from schemes using component-wise one-dimensional formulas. Third-order phase accuracy is good; this is important for coarse-grid large-eddy or full simulation. Potential overshoots or undershoots are avoided by using a recently developed universal limiter. Higher order accuracy is obtained locally, where needed, by the cost-effective strategy of adaptive stencil expansion in a direction normal to each control-volume face; this is controlled by monitoring the absolute normal gradient and curvature across the face. Higher (than third) order cross-terms do not appear to be needed. Since the wider stencil is used only in isolated narrow regions (near discontinuities), extremely high (in this case, seventh) order accuracy can be achieved for little more than the cost of a globally third-order scheme.

Optical waveguides having flattened high order modes

DOEpatents

Messerly, Michael Joseph; Beach, Raymond John; Heebner, John Edward; Dawson, Jay Walter; Pax, Paul Henry

2014-08-05

A deterministic methodology is provided for designing optical fibers that support field-flattened, ring-like higher order modes. The effective and group indices of its modes can be tuned by adjusting the widths of the guide's field-flattened layers or the average index of certain groups of layers. The approach outlined here provides a path to designing fibers that simultaneously have large mode areas and large separations between the propagation constants of its modes.

Crystal growth and characterization of semi-organic 2-amino-5-nitropyridinium bromide (2A5NPBr) single crystals for third-order nonlinear optical (NLO) applications

NASA Astrophysics Data System (ADS)

Vediyappan, Sivasubramani; Arumugam, Raja; Pichan, Karuppasamy; Kasthuri, Ramachandran; Muthu, Senthil Pandian; Perumal, Ramasamy

2017-12-01

Semi-organic nonlinear optical (NLO) 2-amino-5-nitropyridinium bromide (2A5NPBr) single crystals have been grown by slow evaporation solution technique (SEST) with the growth period of 60 days. The single-crystal XRD analysis confirms the unit cell parameters of the grown crystal. The crystallinity of grown 2A5NPBr was analyzed by powder X-ray diffraction (PXRD) measurement. The presence of functional groups of 2A5NPBr crystal was confirmed by Fourier transform infrared (FTIR) spectrum analysis. The optical transmittance of the grown crystal was analyzed by UV-Vis-NIR analysis. It shows good transparency in the visible and NIR region and it is favorable for nonlinear optical (NLO) device applications. The chemical etching study was carried out and it reveals that the grown crystal has less dislocation density. The photoconductivity study reveals that the grown crystal possesses positive photoconductive nature. The thermal stability of the crystal has been investigated by thermogravimetric (TG) and differential thermal analysis (DTA). The dielectric constant and dielectric loss as a function of frequency were measured. The electronic polarizability (α) of 2A5NPBr molecule has been calculated theoretically by different ways such as Penn analysis, Clausius-Mossotti relation, Lorentz-Lorenz equation, optical bandgap, and coupled dipole method (CDM). The obtained values of electronic polarizability (α) are in good agreement with each other. Laser damage threshold (LDT) of 2A5NPBr crystal has been measured using Nd:YAG laser with the wavelength of 1064 nm. Third-order nonlinear optical property of the grown crystal was studied by Z-scan technique using He-Ne laser of wavelength 632.8 nm.

Dielectric resonator: cavity-enhanced optical manipulation in the near field

NASA Astrophysics Data System (ADS)

Reece, Peter J.; Wright, Ewan; Garcés-Chávez, Veneranda; Dholakia, Kishan

2006-08-01

In the following paper we explore the dynamics of single colloidal particles and particle aggregates in a counterpropagating cavity-enhanced evanescent wave optical trap. For this study we make use of Fabry-Perot like cavity modes generated in a prism-coupled resonant dielectric waveguide. The advantage of using this type of optical structure is that there is an enhancement in the electric field of the evanescent at the sample surface that may be used to achieve greater coupling to colloidal particles for the purposes of optical micromanipulation. We demonstrate an order of magnitude increase in the optical forces acting on micrometer sized colloidal particles using cavity enhanced evanescent waves, compared with evanescent wave produced by conventional prism-coupling techniques. The combination of the enhanced optical interaction and the wide area illumination provided by the prism coupler makes it an ideal geometry for studying the collective dynamics of many particles over a large area. We study the different type of ordering observed when particles of different sizes are accumulated at the centre of this novel optical trap. We find that for large particles sizes (greater than 2μm), colloid dynamics are primarily driven by thermodynamics, whilst for smaller particles, in the range of 200-600nm, particles ordering is dictated by optical-matter interactions. We suggest a qualitative model for the observed optically induced ordering occurs and discuss how these results tie in with existing demonstrations of twodimensional optical binding.

Nonlinear optical switching and optical limiting in colloidal CdSe quantum dots investigated by nanosecond Z-scan measurement

NASA Astrophysics Data System (ADS)

Valligatla, Sreeramulu; Haldar, Krishna Kanta; Patra, Amitava; Desai, Narayana Rao

2016-10-01

The semiconductor nanocrystals are found to be promising class of third order nonlinear optical materials because of quantum confinement effects. Here, we highlight the nonlinear optical switching and optical limiting of cadmium selenide (CdSe) quantum dots (QDs) using nanosecond Z-scan measurement. The intensity dependent nonlinear absorption and nonlinear refraction of CdSe QDs were investigated by applying the Z-scan technique with 532 nm, nanosecond laser pulses. At lower intensities, the nonlinear process is dominated by saturable absorption (SA) and it is changed to reverse saturable absorption (RSA) at higher intensities. The SA behaviour is attributed to the ground state bleaching and the RSA is ascribed to free carrier absorption (FCA) of CdSe QDs. The nonlinear optical switching behaviour and reverse saturable absorption makes CdSe QDs are good candidate for all-optical device and optical limiting applications.

A new fiber optic sensor for inner surface roughness measurement

NASA Astrophysics Data System (ADS)

Xu, Xiaomei; Liu, Shoubin; Hu, Hong

2009-11-01

In order to measure inner surface roughness of small holes nondestructively, a new fiber optic sensor is researched and developed. Firstly, a new model for surface roughness measurement is proposed, which is based on intensity-modulated fiber optic sensors and scattering modeling of rough surfaces. Secondly, a fiber optical measurement system is designed and set up. Under the help of new techniques, the fiber optic sensor can be miniaturized. Furthermore, the use of micro prism makes the light turn 90 degree, so the inner side surface roughness of small holes can be measured. Thirdly, the fiber optic sensor is gauged by standard surface roughness specimens, and a series of measurement experiments have been done. The measurement results are compared with those obtained by TR220 Surface Roughness Instrument and Form Talysurf Laser 635, and validity of the developed fiber optic sensor is verified. Finally, precision and influence factors of the fiber optic sensor are analyzed.

Piezoelectric Field Enhanced Second-Order Nonlinear Optical Susceptibilities in Wurtzite GaN/AlGaN Quantum Wells

NASA Technical Reports Server (NTRS)

Liu, Ansheng; Chuang, S.-L.; Ning, C. Z.; Woo, Alex (Technical Monitor)

1999-01-01

Second-order nonlinear optical processes including second-harmonic generation, optical rectification, and difference-frequency generation associated with intersubband transitions in wurtzite GaN/AlGaN quantum well (QW) are investigated theoretically. Taking into account the strain-induced piezoelectric (PZ) effects, we solve the electronic structure of the QW from coupled effective-mass Schrodinger equation and Poisson equation including the exchange-correlation effect under the local-density approximation. We show that the large PZ field in the QW breaks the symmetry of the confinement potential profile and leads to large second-order susceptibilities. We also show that the interband optical pump-induced electron-hole plasma results in an enhancement in the maximum value of the nonlinear coefficients and a redshift of the peak position in the nonlinear optical spectrum. By use of the difference-frequency generation, THz radiation can be generated from a GaN/Al(0.75)Ga(0.25)N with a pump laser of 1.55 micron.

Gauss-Legendre quadrature method used to evaluate the spatio-temporal intensity of ultrashort pulses in the focal region of lenses.

PubMed

García-Martínez, L; Rosete-Aguilar, M; Garduño-Mejia, J

2012-01-20

We analyze the spatio-temporal intensity of sub-20 femtosecond pulses with a carrier wavelength of 810 nm along the optical axis of low numerical aperture achromatic and apochromatic doublets designed in the IR region by using the scalar diffraction theory. The diffraction integral is solved by expanding the wave number around the carrier frequency of the pulse in a Taylor series up to third order, and then the integral over the frequencies is solved by using the Gauss-Legendre quadrature method. The numerical errors in this method are negligible by taking 96 nodes and the computational time is reduced by 95% compared to the integration method by rectangles. We will show that the third-order group velocity dispersion (GVD) is not negligible for 10 fs pulses at 810 nm propagating through the low numerical aperture doublets, and its effect is more important than the propagation time difference (PTD). This last effect, however, is also significant. For sub-20 femtosecond pulses, these two effects make the use of a pulse shaper necessary to correct for second and higher-order GVD terms and also the use of apochromatic optics to correct the PTD effect. The design of an apochromatic doublet is presented in this paper and the spatio-temporal intensity of the pulse at the focal region of this doublet is compared to that given by the achromatic doublet. © 2012 Optical Society of America

High-performance axicon lenses based on high-contrast, multilayer gratings

NASA Astrophysics Data System (ADS)

Doshay, Sage; Sell, David; Yang, Jianji; Yang, Rui; Fan, Jonathan A.

2018-01-01

Axicon lenses are versatile optical elements that can convert Gaussian beams to Bessel-like beams. In this letter, we demonstrate that axicons operating with high efficiencies and at large angles can be produced using high-contrast, multilayer gratings made from silicon. Efficient beam deflection of incident monochromatic light is enabled by higher-order optical modes in the silicon structure. Compared to diffractive devices made from low-contrast materials such as silicon dioxide, our multilayer devices have a relatively low spatial profile, reducing shadowing effects and enabling high efficiencies at large deflection angles. In addition, the feature sizes of these structures are relatively large, making the fabrication of near-infrared devices accessible with conventional optical lithography. Experimental lenses with deflection angles as large as 40° display field profiles that agree well with theory. Our concept can be used to design optical elements that produce higher-order Bessel-like beams, and the combination of high-contrast materials with multilayer architectures will more generally enable new classes of diffractive photonic structures.

Interface inequivalence of the InP/InAlAs/InP staggered double heterostructure grown by metalorganic chemical vapor deposition

NASA Astrophysics Data System (ADS)

Böhrer, J.; Krost, A.; Heitz, R.; Heinrichsdorff, F.; Eckey, L.; Bimberg, D.; Cerva, H.

1996-02-01

The optical and structural properties of the normal InAlAs on InP and the inverted InP on the InAlAs staggered band lineup interface grown by metalorganic chemical vapor deposition (MOCVD) are compared by use of transmission electron microscopy (TEM), time integrated, and time resolved photoluminescence. TEM images show that both interfaces are dissimilar. The normal interface is very abrupt. The inverted interface shows an additional graded layer of about 2.5 nm in width of In1-xAlxAsyP1-y with x (0.48-0) and y (1.0-0.0). A large optical anisotropy exists because of the inequivalence of the two interfaces. The larger spatial separation of the carriers at the inverted interface is responsible for a smaller overlap of the electron and hole wave functions and for that reason a one order of magnitude longer e-h luminescence decay time of 45 ns is observed. The normal interface transition shifts approximately to the third root of excitation while the inverted interface transition shifts logarithmically.

Dark solitons for a variable-coefficient higher-order nonlinear Schrödinger equation in the inhomogeneous optical fiber

NASA Astrophysics Data System (ADS)

Sun, Yan; Tian, Bo; Wu, Xiao-Yu; Liu, Lei; Yuan, Yu-Qiang

2017-04-01

Under investigation in this paper is a variable-coefficient higher-order nonlinear Schrödinger equation, which has certain applications in the inhomogeneous optical fiber communication. Through the Hirota method, bilinear forms, dark one- and two-soliton solutions for such an equation are obtained. We graphically study the solitons with d1(z), d2(z) and d3(z), which represent the variable coefficients of the group-velocity dispersion, third-order dispersion and fourth-order dispersion, respectively. With the different choices of the variable coefficients, we obtain the parabolic, periodic and V-shaped dark solitons. Head-on and overtaking collisions are depicted via the dark two soliton solutions. Velocities of the dark solitons are linearly related to d1(z), d2(z) and d3(z), respectively, while the amplitudes of the dark solitons are not related to such variable coefficients.

High quality adaptive optics zoom with adaptive lenses

NASA Astrophysics Data System (ADS)

Quintavalla, M.; Santiago, F.; Bonora, S.; Restaino, S.

2018-02-01

We present the combined use of large aperture adaptive lens with large optical power modulation with a multi actuator adaptive lens. The Multi-actuator Adaptive Lens (M-AL) can correct up to the 4th radial order of Zernike polynomials, without any obstructions (electrodes and actuators) placed inside its clear aperture. We demonstrated that the use of both lenses together can lead to better image quality and to the correction of aberrations of adaptive optics optical systems.

Nonlinear optical properties of TeO2-P2 O5- ZnO-LiNbO3 glass doped with Er3+ ions

NASA Astrophysics Data System (ADS)

Miedzinski, R.; Fuks-Janczarek, I.; El Sayed Said, Y.

2016-10-01

A series of lithium niobate LiNbO3 (LN) single crystals doped with Er3+ were grown under the same conditions by melt-quenching method. The distribution coefficients of rare-earth (RE) elements in the "crystal-melt" system of LN were determined at the beginning of the crystal growth. Their dependence on the dopant concentration in melt for 0.4 and 0.8 wt % was investigated. The procedure is applied to RE-doped lithium niobate (LiNbO3), a material of great interest for optoelectronic applications. We have obtained the real χR(3) and imaginary parts χI(3) of the third-order, nonlinear optical susceptibility to the nonlinear refractive index n2 and the nonlinear absorption coefficient β that are valid for absorbing systems. We show that nonlinear refractive or absorptive effects are the consequence of the interplay between the real and imaginary parts of the third-order susceptibilities of the materials. The method for measuring non-linear absorption coefficients and nonlinear refractive index based on well-known Z-scan is presented.

Nonlinear-optical studies of organic liquids and polymer optical fibers

NASA Astrophysics Data System (ADS)

Vigil, Steven Richard

We present the results of non-resonant optical Kerr effect measurements of the neat organic liquids nitrobenzene, carbon disulfide, carbon tetrachloride, and methyl-methacrylate. We also present the results of one- photon resonant optical Kerr effect measurements of solutions of the organic dyes indole squarylium and silicon-phthalocyanine:methylmethacrylate (separately) in carbon tetrachloride. Fits of the molecular third-order susceptibility theory to the one-photon resonant data indicate the presence of high-lying two-photon states for each of the dye molecules studied. We also present results concerning light coupling in dye- doped dual-core polymer optical fibers. Measurements of the coupling length at low intensity are in agreement with linear coupling length calculations. Intensity- dependent coupling is observed as the intensity launched into the fiber is increased.

Material characterisation with methods of nonlinear optics

NASA Astrophysics Data System (ADS)

Prylepa, A.; Reitböck, C.; Cobet, M.; Jesacher, A.; Jin, X.; Adelung, R.; Schatzl-Linder, M.; Luckeneder, G.; Stellnberger, K.-H.; Steck, T.; Faderl, J.; Stehrer, T.; Stifter, D.

2018-01-01

In this review, we present nonlinear optical methods, based on the second and third order nonlinear polarization, especially in the context of material characterization tasks outside the area of life sciences—for which these techniques are mostly designed. An overview of application studies reported to date is given, together with a discussion on the advantages and limits of the individual methods. Furthermore, new ways of experimentally combining different optical concepts are introduced, and their potential for characterisation and inspection tasks is evaluated in the context of various case studies, including the investigation of semiconductor surfaces, metals and related corrosion products, as well as of organic materials.

All-Optical Control of Linear and Nonlinear Energy Transfer via the Zeno Effect

NASA Astrophysics Data System (ADS)

Guo, Xiang; Zou, Chang-Ling; Jiang, Liang; Tang, Hong X.

2018-05-01

Microresonator-based nonlinear processes are fundamental to applications including microcomb generation, parametric frequency conversion, and harmonics generation. While nonlinear processes involving either second- (χ(2 )) or third- (χ(3 )) order nonlinearity have been extensively studied, the interaction between these two basic nonlinear processes has seldom been reported. In this paper we demonstrate a coherent interplay between second- and third- order nonlinear processes. The parametric (χ(2 ) ) coupling to a lossy ancillary mode shortens the lifetime of the target photonic mode and suppresses its density of states, preventing the photon emissions into the target photonic mode via the Zeno effect. Such an effect is then used to control the stimulated four-wave mixing process and realize a suppression ratio of 34.5.

Nonlinear optical properties and excited state dynamics of sandwich-type mixed (phthalocyaninato)(Schiff-base) triple-decker complexes: Effect of rare earth atom

NASA Astrophysics Data System (ADS)

Li, Zhongguo; Gao, Feng; Xiao, Zhengguo; Wu, Xingzhi; Zuo, Jinglin; Song, Yinglin

2018-07-01

The third-order nonlinear optical properties of two di-lanthanide (Ln = Tb and Dy) sandwich complexes with mixed phthalocyanine and Schiff-base ligands were studied using Z-scan technique at 532 nm with 20 ps and 4 ns pulses. Both complexes exhibit reverse saturable absorption and self-focusing effect in ps regime, while the second-order hyperpolarizability decreases from Dy to Tb. Interestingly, the Tb triple-decker complexes show larger nonlinear absorption than Dy complexes on ns timescale. The time-resolved pump-probe measurements demonstrate that the nonlinear optical response was caused by excited-state mechanism related to the five-level model, while the singlet state lifetime of Dy complexes is 3 times shorter than that of Tb complexes. Our results indicate the lanthanide ions play a critical role in the photo-physical properties of triple-decker phthalocyanine complexes for their application as optical limiting materials.

Study of Third-Order Optical Nonlinearities of Se-Sn (Bi,Te) Quaternary Chalcogenide Thin Films Using Ti: Sapphire Laser in Femtosecond Regime

NASA Astrophysics Data System (ADS)

Yadav, Preeti; Sharma, Ambika

2017-01-01

The objective of the present research work is to study the nonlinear optical properties of quaternary Se-Sn (Bi,Te) chalcogenide thin films. A Z-scan technique utilizing 800 nm femtosecond laser source has been used for the determination of the nonlinear refractive index ( n 2), two-photon absorption coefficient ( β 2) and third-order susceptibility ( χ (3)). In the measurement of n 2, an aperture is placed in the far field before the detector (closed aperture), while for the measurement of β 2, entire transmitted light is collected by the detector without an aperture (open aperture). Self-focusing has been observed in closed aperture transmission spectra. The appearance of the peak after the valley in this spectrum reflects the positive nonlinear refractive index. The calculated value of n 2 of the studied thin films varies from 1.06 × 10-12 cm2/W to 0.88 × 10-12 cm2/W. The compound-dependent behavior of n 2 is explained in this paper. We have also compared the experimental values of n 2 with the theoretically determined values, other compounds of chalcogenide glass and pure silica. The n 2 of the investigated thin films is found to be 3200 times higher than pure silica. The results of the open aperture Z-scan revealed that the value of β 2 of the studied compound is in the order of 10-8 cm/W. The behavior of two-photon absorption is described by means of the optical band gap ( E g) of the studied compound. The variation in the figure-of-merit from 0.32 to 1.4 with varying Sn content is also reported in this paper. The higher value of nonlinearity makes this material advantageous for optical fibers, waveguides and optical limiting devices.

Optically induced metal-to-dielectric transition in Epsilon-Near-Zero metamaterials

PubMed Central

Kaipurath, R. M.; Pietrzyk, M.; Caspani, L.; Roger, T.; Clerici, M.; Rizza, C.; Ciattoni, A.; Di Falco, A.; Faccio, D.

2016-01-01

Epsilon-Near-Zero materials exhibit a transition in the real part of the dielectric permittivity from positive to negative value as a function of wavelength. Here we study metal-dielectric layered metamaterials in the homogenised regime (each layer has strongly subwavelength thickness) with zero real part of the permittivity in the near-infrared region. By optically pumping the metamaterial we experimentally show that close to the Epsilon-Near-Zero (ENZ) wavelength the permittivity exhibits a marked transition from metallic (negative permittivity) to dielectric (positive permittivity) as a function of the optical power. Remarkably, this transition is linear as a function of pump power and occurs on time scales of the order of the 100 fs pump pulse that need not be tuned to a specific wavelength. The linearity of the permittivity increase allows us to express the response of the metamaterial in terms of a standard third order optical nonlinearity: this shows a clear inversion of the roles of the real and imaginary parts in crossing the ENZ wavelength, further supporting an optically induced change in the physical behaviour of the metamaterial. PMID:27292270

Nonlinear Optics and Applications

NASA Technical Reports Server (NTRS)

Abdeldayem, Hossin A. (Editor); Frazier, Donald O. (Editor)

2007-01-01

Nonlinear optics is the result of laser beam interaction with materials and started with the advent of lasers in the early 1960s. The field is growing daily and plays a major role in emerging photonic technology. Nonlinear optics play a major role in many of the optical applications such as optical signal processing, optical computers, ultrafast switches, ultra-short pulsed lasers, sensors, laser amplifiers, and many others. This special review volume on Nonlinear Optics and Applications is intended for those who want to be aware of the most recent technology. This book presents a survey of the recent advances of nonlinear optical applications. Emphasis will be on novel devices and materials, switching technology, optical computing, and important experimental results. Recent developments in topics which are of historical interest to researchers, and in the same time of potential use in the fields of all-optical communication and computing technologies, are also included. Additionally, a few new related topics which might provoke discussion are presented. The book includes chapters on nonlinear optics and applications; the nonlinear Schrodinger and associated equations that model spatio-temporal propagation; the supercontinuum light source; wideband ultrashort pulse fiber laser sources; lattice fabrication as well as their linear and nonlinear light guiding properties; the second-order EO effect (Pockels), the third-order (Kerr) and thermo-optical effects in optical waveguides and their applications in optical communication; and, the effect of magnetic field and its role in nonlinear optics, among other chapters.

Investigation of quadratic electro-optic effects and electro-absorption process in GaN/AlGaN spherical quantum dot

PubMed Central

2014-01-01

Quadratic electro-optic effects (QEOEs) and electro-absorption (EA) process in a GaN/AlGaN spherical quantum dot are theoretically investigated. It is found that the magnitude and resonant position of third-order nonlinear optical susceptibility depend on the nanostructure size and aluminum mole fraction. With increase of the well width and barrier potential, quadratic electro-optic effect and electro-absorption process nonlinear susceptibilities are decreased and blueshifted. The results show that the DC Kerr effect in this case is much larger than that in the bulk case. Finally, it is observed that QEOEs and EA susceptibilities decrease and broaden with the decrease of relaxation time. PMID:24646318

Crystal growth and characterization of semi organic nonlinear optical (NLO) piperazinium tetrachlorozincate monohydrate (PTCZ) single crystal

NASA Astrophysics Data System (ADS)

Karuppasamy, P.; Pandian, Muthu Senthil; Ramasamy, P.

2018-04-01

The semi-organic single crystal of piperazinium tetrachlorozincate monohydrate (PTCZ) was successfully grown by slow evaporation solution technique (SEST). The grown crystal was subjected to the single crystal XRD studies for confirming the unit cell parameters. The optical quality of the grown crystal was identified by the UV-Vis NIR spectrum analysis and the optical band gap energy was calculated. The photoconductivity study reveals that the grown crystal has positive photoconductive nature. The mechanical stability of the grown crystal was analyzed using Vickers microhardness analyzer. The third-order nonlinear optical properties such as nonlinear refractive index (n2), absorption co-efficient (β) and susceptibility (χ(3)) were studied by Z-scan technique at 640 nm using solid state laser.

Microstructure of squarylium dye J aggregate films examined on the basis of optical behavior at low temperature

NASA Astrophysics Data System (ADS)

Tatsuura, Satoshi; Tian, Minquan; Furuki, Makoto; Sato, Yasuhiro; Iwasa, Izumi; Pu, Lyong Sun; Kawashima, Hitoshi; Ishikawa, Hiroshi

2002-10-01

The microstructure of a spin-coated film of squarylium dye J aggregates is examined on the basis of the measurement of the optical properties and the third-order nonlinear optical susceptibility χ(3) at low temperature. The absorption maximum of J aggregates shifted to lower energies as the film temperature decreased, while χ(3) was independent of the temperature. The latter finding indicates that the coherent length of J aggregates is confined by a structural boundary rather than by phonons; consequently, the observed peak energy shift can be due to temperature-dependent conformational change of the aggregates. The small aggregation size may contribute to the ultrahigh-speed optical response of squarylium dye J aggregates.

Optical recording materials

NASA Astrophysics Data System (ADS)

Savant, Gajendra D.; Jannson, Joanna L.

1991-07-01

The increased emphasis on speed of operation, wavelength selectivity, compactness, and ruggedization has focused a great deal of attention on the solutions offered by all-optic devices and by hybrid electro-optic systems. In fact, many photonic devices are being considered for use as partial replacements for electronic systems. Optical components, which include modulators, switches, 3-D memory storage devices, wavelength division multiplexers, holographic optical elements, and others, are examples of such devices. The success or failure of these modern optical devices depends, to a great extent, on the performance and survivability of the optical materials used. This is particularly true for volume holographic filters, organic memory media, second- and third-order nonlinear material-based processors and neural networks. Due to the critical importance of these materials and their lack of availability, Physical Optics Corporation (POC) undertook a global advanced optical materials program which has enabled it to introduce several optical devices, based on the new and improved materials which will be described in this article.

Thermal transport and anharmonic phonons in strained monolayer hexagonal boron nitride

NASA Astrophysics Data System (ADS)

Li, Shasha; Chen, Yue

2017-03-01

Thermal transport and phonon-phonon coupling in monolayer hexagonal boron nitride (h-BN) under equibiaxial strains are investigated from first principles. Phonon spectra at elevated temperatures have been calculated from perturbation theory using the third-order anharmonic force constants. The stiffening of the out-of-plane transverse acoustic mode (ZA) near the Brillouin zone center and the increase of acoustic phonon lifetimes are found to contribute to the dramatic increase of thermal transport in strained h-BN. The transverse optical mode (TO) at the K point, which was predicted to lead to mechanical failure of h-BN, is found to shift to lower frequencies at elevated temperatures under equibiaxial strains. The longitudinal and transverse acoustic modes exhibit broad phonon spectra under large strains in sharp contrast to the ZA mode, indicating strong in-plane phonon-phonon coupling.

NGC 4438: Ram pressure sweeping of a tidally disrupted galaxy

NASA Technical Reports Server (NTRS)

Hibbard, J. E.; Vangorkom, Jacqueline H.

1990-01-01

NGC 4438 is the highly HI deficient peculiar spiral in the center of the Virgo cluster. Observations are given of the neutral hydrogen emission obtained with the Very Large Array (VLA) in the D-array configuration. These observations map out the total HI as determined from single dish measurements, and show the hydrogen to be confined to a region about one third the size of the optical disk and displaced to the side of the galaxy opposite M87. The hydrogen content of the galaxy is over an order of magnitude less than that expected for a galaxy of its type. The data suggest that the HI deficiency is a result of ram pressure stripping of the gas in the outer regions of the galaxy by the hot intracluster medium after being tidally perturbed.

Directed-Assembly of Block Copolymers for Large-Scale, Three-Dimensional, Optical Metamaterials at Visible Wavelengths. Final LDRD Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hiszpanski, Anna M.

Metamaterials are composites with patterned subwavelength features where the choice of materials and subwavelength structuring bestows upon the metamaterials unique optical properties not found in nature, thereby enabling optical applications previously considered impossible. However, because the structure of optical metamaterials must be subwavelength, metamaterials operating at visible wavelengths require features on the order of 100 nm or smaller, and such resolution typically requires top-down lithographic fabrication techniques that are not easily scaled to device-relevant areas that are square centimeters in size. In this project, we developed a new fabrication route using block copolymers to make over large device-relevant areas opticalmore » metamaterials that operate at visible wavelengths. Our structures are smaller in size (sub-100 nm) and cover a larger area (cm 2) than what has been achieved with traditional nanofabrication routes. To guide our experimental efforts, we developed an algorithm to calculate the expected optical properties (specifically the index of refraction) of such metamaterials that predicts that we can achieve surprisingly large changes in optical properties with small changes in metamaterials’ structure. In the course of our work, we also found that the ordered metal nanowires meshes produced by our scalable fabrication route for making optical metamaterials may also possibly act as transparent electrodes, which are needed in electrical displays and solar cells. We explored the ordered metal nanowires meshes’ utility for this application and developed design guidelines to aide our experimental efforts.« less

Crystal growth and DFT insight on sodium para-nitrophenolate para-nitrophenol dihydrate single crystal for NLO applications

NASA Astrophysics Data System (ADS)

Selvakumar, S.; Boobalan, Maria Susai; Anthuvan Babu, S.; Ramalingam, S.; Leo Rajesh, A.

2016-12-01

Single crystals of sodium para-nitrophenolate para-nitrophenol dihydrate (SPPD) were grown by slow evaporation technique and its structure has been studied by FT-IR, FT-Raman and single crystal X-ray diffraction techniques. The optical and electrical properties were characterized by UV-Vis spectrum, and dielectric studies respectively. SPPD was thermally stable up to 128 °C as determined by TG-DTA curves. Using the Kurtz-Perry powder method, the second-harmonic generation efficiency was found to be five times to that of KDP. Third-order nonlinear response was studied using Z-scan technique with a He-Ne laser (632.8 nm) and NLO parameters such as intensity dependent refractive index, nonlinear absorption coefficient and third-order susceptibility were also estimated. The molecular geometry from X-ray experiment in the ground state has been compared using density functional theory (DFT) with appropriate basis set. The first-order hyperpolarizability also calculated using DFT approaches. Stability of the molecule arising from hyperconjugative interactions leading to its nonlinear optical activity and charge delocalization were analyzed using natural bond orbital technique. HOMO-LUMO energy gap value suggests the possibility of charge transfer within the molecule. Based on optimized ground state geometries, Natural bond orbital (NBO) analysis was performed to study donor-acceptor interactions.

Synthesis, characterization and theoretical investigations of the structure, electronic properties and third-order nonlinearity optics (NLO) of M(DPIP)₂.

PubMed

Li, Kang; Tang, Guodong; Kou, ShanShan; Culnane, Lance F; Zhang, Yu; Song, Yinglin; Li, Rongqing; Wei, Changmei

2015-03-15

Three complexes of M(DPIP)2 (M=Cu, Co, Zn as 1, 2, 3) were synthesized and characterized by elemental analysis, IR, UV-Vis, thermogravimetry, and X-ray diffraction. Their nonlinear optical properties were measured by the Z-scan technique and yielded a normalized transmittance of about 70% for complex 1 (45 μJ pulse), and 93% for complex 3 (68 μJ pulse at the focus point). The nonlinear absorption coefficient, β, is 1.4×10(-11) m/W for 1 and 5.6×10(-13) m/W for 3, and the third-order nonlinear refraction index, n2, is 1.0×10(-18) m(2)/W for 3. Complex 1 shows self-defocusing property, while complex 3 exhibits self-focusing property. The thermogravimetric results show that the frame structure of compounds 1-3 begin to collapse at 400, 250 and 280°C, respectively, which suggests that they elicit excellent thermal stability. This research aims to provide better understanding of these compounds, and offer preliminary explanations for the significant differences between compounds 1-3, in order to potentially help in the designing of future novel materials with NLO properties. Copyright © 2014 Elsevier B.V. All rights reserved.

Ab-initio and DFT methodologies for computing hyperpolarizabilities and susceptibilities of highly conjugated organic compounds for nonlinear optical applications

NASA Astrophysics Data System (ADS)

Karakas, A.; Karakaya, M.; Ceylan, Y.; El Kouari, Y.; Taboukhat, S.; Boughaleb, Y.; Sofiani, Z.

2016-06-01

In this talk, after a short introduction on the methodologies used for computing dipole polarizability (α), second and third-order hyperpolarizability and susceptibility; the results of theoretical studies performed on density functional theory (DFT) and ab-initio quantum mechanical calculations of nonlinear optical (NLO) properties for a few selected organic compounds and polymers will be explained. The electric dipole moments (μ) and dispersion-free first hyperpolarizabilities (β) for a family of azo-azulenes and a styrylquinolinium dye have been determined by DFT at B3LYP level. To reveal the frequency-dependent NLO behavior, the dynamic α, second hyperpolarizabilities (γ), second (χ(2)) and third-order (χ(3)) susceptibilites have been evaluated using time-dependent HartreeFock (TDHF) procedure. To provide an insight into the third-order NLO phenomena of a series of pyrrolo-tetrathiafulvalene-based molecules and pushpull azobenzene polymers, two-photon absorption (TPA) characterizations have been also investigated by means of TDHF. All computed results of the examined compounds are compared with their previous experimental findings and the measured data for similar structures in the literature. The one-photon absorption (OPA) characterizations of the title molecules have been theoretically obtained by configuration interaction (CI) method. The highest occupied molecular orbitals (HOMO), the lowest unoccupied molecular orbitals (LUMO) and the HOMO-LUMO band gaps have been revealed by DFT at B3LYP level for azo-azulenes, styrylquinolinium dye, push-pull azobenzene polymers and by parametrization method 6 (PM6) for pyrrolo-tetrathiafulvalene-based molecules.

Design of an imaging microscope for soft X-ray applications

NASA Astrophysics Data System (ADS)

Hoover, Richard B.; Shealy, David L.; Gabardi, David R.; Walker, Arthur B. C., Jr.; Lindblom, Joakim F.

1988-01-01

An imaging soft X-ray microscope with a spatial resolution of 0.1 micron and normal incidence multilayer optics is discussed. The microscope has a Schwarzschild configuration, which consists of two concentric spherical mirrors with radii of curvature which minimize third-order spherical aberration, coma, and astigmatism. The performance of the Stanford/MSFC Cassegrain X-ray telescope and its relevance to the present microscope are addressed. A ray tracing analysis of the optical system indicates that diffraction-limited performance can be expected for an object height of 0.2 mm.

Spectral splitting of optical pulses inside a dispersive medium at a temporal boundary

DOE PAGES

Plansinis, Brent W.; Donaldson, William R.; Agrawal, Govind P.

2016-11-07

We show numerically that the spectrum of an optical pulse splits into multiple, widely separated, spectral bands when it arrives at a temporal boundary across which refractive index changes suddenly. At the same time, the pulse breaks into several temporally separated pulses traveling at different speeds. The number of such pulses depends on the dispersive properties of the medium. We study the effect of second- and third-order dispersion in detail but also consider briefly the impact of other higher-order terms. As a result, a temporal waveguide formed with two temporal boundaries can reflect the temporally separated pulses again and again,more » increasing the number of pulses trapped within the temporal waveguide.« less

Nonlinear intermodulation distortion suppression in coherent analog fiber optic link using electro-optic polymeric dual parallel Mach-Zehnder modulator.

PubMed

Kim, Seong-Ku; Liu, Wei; Pei, Qibing; Dalton, Larry R; Fetterman, Harold R

2011-04-11

A linearized dual parallel Mach-Zehnder modulator (DPMZM) based on electro-optic (EO) polymer was both fabricated, and experimentally used to suppress the third-order intermodulation distortion (IMD3) in a coherent analog fiber optic link. This optical transmitter design was based on a new EO chromophore called B10, which was synthesized for applications dealing with the fiber-optic communication systems. The chromophore was mixed with amorphous polycarbonate (APC) to form the waveguide's core material. The DPMZM was configured with two MZMs, of different lengths in parallel, with unbalanced input and output couplers and a phase shifter in one arm. In this configuration each of the MZMs carried a different optical power, and imposed a different depth of optical modulation. When the two optical beams from the MZMs were combined to generate the transmitted signal it was possible to set the IMD3 produced by each modulator to be equal in amplitude but 180° out of phase from the other. Therefore, the resulting IMD3 of the DPMZM transmitter was effectively canceled out during two-tone experiments. A reduction of the IMD3 below the noise floor was observed while leaving fifth-order distortion (IMD5) as the dominant IMD product. This configuration has the capability of broadband operation and shot-noise limited operation simultaneously. © 2011 Optical Society of America

Access to long-term optical memories using photon echoes retrieved from electron spins in semiconductor quantum wells

NASA Astrophysics Data System (ADS)

Poltavtsev, S. V.; Langer, L.; Yugova, I. A.; Salewski, M.; Kapitonov, Y. V.; Yakovlev, D. R.; Karczewski, G.; Wojtowicz, T.; Akimov, I. A.; Bayer, M.

2016-10-01

We use spontaneous (two-pulse) and stimulated (three-pulse) photon echoes for studying the coherent evolution of optically excited ensemble of trions which are localized in semiconductor CdTe/CdMgTe quantum well. Application of transverse magnetic field leads to the Larmor precession of the resident electron spins, which shuffles optically induced polarization between optically accessible and inaccessible states. This results in several spectacular phenomena. First, magnetic field induces oscillations of spontaneous photon echo amplitude. Second, in three-pulse excitation scheme, the photon echo decay is extended by several orders of magnitude. In this study, short-lived optical excitation which is created by the first pulse is coherently transferred into a long-lived electron spin state using the second optical pulse. This coherent spin state of electron ensemble persists much longer than any optical excitation in the system, preserving information on initial optical field, which can be retrieved as a photon echo by means of third optical pulse.

Nonlinear dispersion-based incoherent photonic processing for microwave pulse generation with full reconfigurability.

PubMed

Bolea, Mario; Mora, José; Ortega, Beatriz; Capmany, José

2012-03-12

A novel all-optical technique based on the incoherent processing of optical signals using high-order dispersive elements is analyzed for microwave arbitrary pulse generation. We show an approach which allows a full reconfigurability of a pulse in terms of chirp, envelope and central frequency by the proper control of the second-order dispersion and the incoherent optical source power distribution, achieving large values of time-bandwidth product.

Third-order linearization for self-beating filtered microwave photonic systems using a dual parallel Mach-Zehnder modulator.

PubMed

Pérez, Daniel; Gasulla, Ivana; Capmany, José; Fandiño, Javier S; Muñoz, Pascual; Alavi, Hossein

2016-09-05

We develop, analyze and apply a linearization technique based on dual parallel Mach-Zehnder modulator to self-beating microwave photonics systems. The approach enables broadband low-distortion transmission and reception at expense of a moderate electrical power penalty yielding a small optical power penalty (<1 dB).

Computation of turbulent pipe and duct flow using third order upwind scheme

NASA Technical Reports Server (NTRS)

Kawamura, T.

1986-01-01

The fully developed turbulence in a circular pipe and in a square duct is simulated directly without using turbulence models in the Navier-Stokes equations. The utilized method employs a third-order upwind scheme for the approximation to the nonlinear term and the second-order Adams-Bashforth method for the time derivative in the Navier-Stokes equation. The computational results appear to capture the large-scale turbulent structures at least qualitatively. The significance of the artificial viscosity inherent in the present scheme is discussed.

Perturbative two- and three-loop coefficients from large β Monte Carlo

NASA Astrophysics Data System (ADS)

Lepage, G. P.; Mackenzie, P. B.; Shakespeare, N. H.; Trottier, H. D.

Perturbative coefficients for Wilson loops and the static quark self-energy are extracted from Monte Carlo simulations at large β on finite volumes, where all the lattice momenta are large. The Monte Carlo results are in excellent agreement with perturbation theory through second order. New results for third order coefficients are reported. Twisted boundary conditions are used to eliminate zero modes and to suppress Z3 tunneling.

Perturbative two- and three-loop coefficients from large b Monte Carlo

DOE Office of Scientific and Technical Information (OSTI.GOV)

G.P. Lepage; P.B. Mackenzie; N.H. Shakespeare

1999-10-18

Perturbative coefficients for Wilson loops and the static quark self-energy are extracted from Monte Carlo simulations at large {beta} on finite volumes, where all the lattice momenta are large. The Monte Carlo results are in excellent agreement with perturbation theory through second order. New results for third order coefficients are reported. Twisted boundary conditions are used to eliminate zero modes and to suppress Z{sub 3} tunneling.

Tuning the nonlinear optical absorption in Au/BaTiO3 nanocomposites with gold nanoparticle concentration

NASA Astrophysics Data System (ADS)

Bijeesh, M. M.; Shakhi, P. K.; Varier, Geetha K.; Nandakumar, P.

2018-06-01

We report on the nonlinear optical absorption coefficient of Au/BaTiO3 nanocomposite films and its dependence on gold nanoparticle concentration. Au/BaTiO3 nanocomposite films with different molar ratio of Au/Ba are prepared by sol-gel technique and characterized by X-ray diffraction, UV Visible absorption spectroscopy and high resolution transmission electron microscopy. An open aperture Z-scan technique is employed to study the third order nonlinear optical properties of Au/BaTiO3 thin films. An Nd:YAG laser operating at 532 nm wavelength having a pulse width of 5 ns is used for the measurements. The two-photon absorption coefficient of the films increases linearly with gold nanoparticle concentration and significant enhancement of nonlinear optical absorption is observed. This ability to fine tune the nonlinear optical coefficients of Au/BaTiO3 films would be handy in optical device applications.

Nonlinear Optical Properties of Aluminum Doped Zinc Oxide

NASA Astrophysics Data System (ADS)

Otieno, Calford O.

Nonlinear optical (NLO) materials are crucial to future progress in industrial and technological applications that involve intense light-matter interaction. While ZnO-related materials are known to possess good NLO properties, existing results on ZnO and AZO (Al-doped ZnO) are mostly available at a single wavelength or limited ranges. Therefore, NLO dispersions (wavelength dependences) are not entirely studied, especially at longer wavelengths far below the bandgap. It is important to explore wavelength dependences since doping can induce a drastic change in the NLO responses at varied spectral ranges via doping-induced subgap-state contributions. We present results of our studies on nonlinear harmonic generation from our samples, which include 1) second harmonic generation and 2) third harmonic generation precisely characterized by Maker fringes as a function of both Al doping and wavelength. We exhaustively discuss the possible cause for the modified optical nonlinearities observed in our AZO thin films and give detailed comparisons of our observations with the previous studies. We also present the results of open- and close-aperture Z-scans to characterize the two-photon absorption coefficient (TPA) and the nonlinear refractive index (NLR), respectively, of the AZO films. There was no clearcut evidence of monotonic dependence of TPA and NLR on doping. This presumably indicates that the overall effect is nontrivial and should be understood in terms of combined effects of bandgap shift and crystallinity upon varying the doping level. Most intriguingly, we found that NLR values from the closed-aperture Z-scan are very large by orders of magnitude when compared with the bulk counterparts. Similar observation was made for TPA values from the open-aperture Z-scan. To countercheck very large NLO absorption, we conducted simple intensity scan by varying the incident photon number on each sample but fixing the beam area to eliminate any possible errors related to optical damage at the Z-scan focus. However, we confirmed that the TPA values are also very large and comparable to those obtained by the open-aperture Z-scan. We try to explain this very large nonlinearity by seriously considering the previously proposed models.

Non linear optical studies on semiorganic single crystal: L-arginine 4-nitrophenalate 4-nitrophenol dihydrate (LAPP)

NASA Astrophysics Data System (ADS)

Mahadevan, M.; Sankar, P. K.; Vinitha, G.; Arivanandhan, M.; Ramachandran, K.; Anandan, P.

2017-07-01

L-arginine 4-nitrophenalate 4-nitrophenol dihydrate (LAPP) has been synthesized and grown by solution growth at room temperature using deionized water as a solvent. The various functional groups of the sample were identified by Fourier transform infra-red and Fourier transforms - Raman spectroscopic analyses. The Laser damage threshold of LAPP has been studied. Refractive index of LAPP single crystal was measured using Metricon prism coupler Instrument. The etching studies were carried out to study the quality of the grown crystals. The third order nonlinear optical properties of LAPP sample was analyzed by the Z-scan technique using 532 nm diode pumped CW Nd: YAG laser. The LAPP material exhibits negative optical nonlinearity. The results show that LAPP sample has potential applications in nonlinear optics and it can be exploited for optical limiting or switching.

Ultra-large nonlinear parameter in graphene-silicon waveguide structures.

PubMed

Donnelly, Christine; Tan, Dawn T H

2014-09-22

Mono-layer graphene integrated with optical waveguides is studied for the purpose of maximizing E-field interaction with the graphene layer, for the generation of ultra-large nonlinear parameters. It is shown that the common approach used to minimize the waveguide effective modal area does not accurately predict the configuration with the maximum nonlinear parameter. Both photonic and plasmonic waveguide configurations and graphene integration techniques realizable with today's fabrication tools are studied. Importantly, nonlinear parameters exceeding 10(4) W(-1)/m, two orders of magnitude larger than that in silicon on insulator waveguides without graphene, are obtained for the quasi-TE mode in silicon waveguides incorporating mono-layer graphene in the evanescent part of the optical field. Dielectric loaded surface plasmon polariton waveguides incorporating mono-layer graphene are observed to generate nonlinear parameters as large as 10(5) W(-1)/m, three orders of magnitude larger than that in silicon on insulator waveguides without graphene. The ultra-large nonlinear parameters make such waveguides promising platforms for nonlinear integrated optics at ultra-low powers, and for previously unobserved nonlinear optical effects to be studied in a waveguide platform.

WGM-Resonator/Tapered-Waveguide White-Light Sensor Optics

NASA Technical Reports Server (NTRS)

Stekalov, Dmitry; Maleki, Lute; Matsko, Andrey; Savchenkov, Anatoliy; Iltchenko, Vladimir

2007-01-01

Theoretical and experimental investigations have demonstrated the feasibility of compact white-light sensor optics consisting of unitary combinations of (1) low-profile whispering-gallery-mode (WGM) resonators and (2) tapered rod optical waveguides. These sensors are highly wavelength-dispersive and are expected to be especially useful in biochemical applications for measuring absorption spectra of liquids. These sensor optics exploit the properties of a special class of non-diffracting light beams that are denoted Bessel beams because their amplitudes are proportional to Bessel functions of the radii from their central axes. High-order Bessel beams can have large values of angular momentum. In a sensor optic of this type, a low-profile WGM resonator that supports modes having large angular momenta is used to generate high-order Bessel beams. As used here, "low-profile" signifies that the WGM resonator is an integral part of the rod optical waveguide but has a radius slightly different from that of the adjacent part(s).

Nasmyth Telescope

NASA Astrophysics Data System (ADS)

Murdin, P.

2000-11-01

An altazimuth reflecting telescope with relatively stable platforms for mounting heavy, large, delicate or developmental equipment which cannot be, or has not been, engineered to cope with attitude changes during the tracking of a star. The optical configuration is the Cassegrain type, with a primary and secondary mirror, and an additional third flat mirror mounted at the intersection of the alti...

Enhanced Optical Transmission Mediated by Localized Plasmons in Anisotropic, 3D Nanohole Arrays

PubMed Central

Yang, Jiun-Chan; Gao, Hanwei; Suh, Jae Yong; Zhou, Wei; Lee, Min Hyung; Odom, Teri W.

2010-01-01

This paper describes 3D nanohole arrays whose high optical transmission is mediated more by localized surface plasmon (LSP) excitations than by surface plasmon polaritons (SPPs). First, LSPs on 3D hole arrays lead to optical transmission an order of magnitude higher than 2D planar hole arrays. Second, LSP-mediated transmission is broadband and more tunable than SPP-enhanced transmission which is restricted by Bragg coupling. Third, for the first time, two types of surface plasmons can be selectively excited and manipulated on the same plasmonic substrate. This new plasmonic substrate fabricated by high-throughput nanolithography techniques paves the way for cutting-edge optoelectronic and biomedical applications. PMID:20698633

Growth and characterization of new nonlinear optical 1-phenyl-3-(4-dimethylamino phenyl) prop-2-en-1-one (PDAC) single crystals

NASA Astrophysics Data System (ADS)

Ravindraswami, K.; Janardhana, K.; Gowda, Jayaprakash; Moolya, B. Narayana

2018-04-01

Non linear optical 1-phenyl-3-(4-dimethylamino phenyl) prop-2-en-1-one (PDAC) was synthesized using Claisen - Schmidt condensation method and studied for optical nonlinearity with an emphasis on structure-property relationship. The structural confirmation studies were carried out using 1H-NMR, FT-IR and single crystal XRD techniques. The nonlinear absorption and nonlinear refraction parameters in z-scan with nano second laser pulses were obtained by measuring the profile of propagated beam through the samples. The real and imaginary parts of third-order bulk susceptibility χ(3) were evaluated. Thermo gravimetric analysis is carried out to investigate the thermal stability.

Predicting the nonlinear optical response in the resonant region from the linear characterization: a self-consistent theory for the first-, second-, and third-order (non)linear optical response

NASA Astrophysics Data System (ADS)

Pérez-Moreno, Javier; Clays, Koen; Kuzyk, Mark G.

2010-08-01

We introduce a self-consistent theory for the description of the optical linear and nonlinear response of molecules that is based strictly on the results of the experimental characterization. We show how the Thomas-Kuhn sum-rules can be used to eliminate the dependence of the nonlinear response on parameters that are not directly measurable. Our approach leads to the successful modeling of the dispersion of the nonlinear response of complex molecular structures with different geometries (dipolar and octupolar), and can be used as a guide towards the modeling in terms of fundamental physical parameters.

Optical micro-cavities on silicon

NASA Astrophysics Data System (ADS)

Dai, Daoxin; Liu, Erhu; Tan, Ying

2018-01-01

Silicon-based optical microcavities are very popular for many applications because of the ultra-compact footprint, easy scalability, and functional versatility. In this paper we give a discussion about the challenges of the optical microcavities on silicon and also give a review of our recent work, including the following parts. First, a near-"perfect" high-order MRR optical filter with a box-like filtering response is realized by introducing bent directional couplers to have sufficient coupling between the access waveguide and the microrings. Second, an efficient thermally-tunable MRR-based optical filter with graphene transparent nano-heater is realized by introducing transparent graphene nanoheaters. Thirdly, a polarization-selective microring-based optical filter is realized to work with resonances for only one of TE and TM polarizations for the first time. Finally, a on-chip reconfigurable optical add-drop multiplexer for hybrid mode- /wavelength-division-multiplexing systems is realized for the first time by monolithically integrating a mode demultiplexer, four MRR optical switches, and a mode multiplexer.

Tunable Filter Made From Three Coupled WGM Resonators

NASA Technical Reports Server (NTRS)

Savchenkov, Anatoliy; Iltchenko, Vladimir; Maleki, Lute; Matsko, Andrey

2006-01-01

A tunable third-order band-pass optical filter has been constructed as an assembly of three coupled, tunable, whispering-gallery-mode resonators similar to the one described in Whispering-Gallery-Mode Tunable Narrow-Band-Pass Filter (NPO-30896), NASA Tech Briefs, Vol. 28, No. 4 (April 2004), page 5a. This filter offers a combination of four characteristics that are desirable for potential applications in photonics: (1) wide real-time tunability accompanied by a high-order filter function, (2) narrowness of the passband, (3) relatively low loss between input and output coupling optical fibers, and (4) a sparse spectrum. In contrast, prior tunable band-pass optical filters have exhibited, at most, two of these four characteristics. As described in several prior NASA Tech Briefs articles, a whispering-gallery-mode (WGM) resonator is a spheroidal, disklike, or toroidal body made of a highly transparent material. It is so named because it is designed to exploit whispering-gallery electromagnetic modes, which are waveguide modes that propagate circumferentially and are concentrated in a narrow toroidal region centered on the equatorial plane and located near the outermost edge. Figure 1 depicts the optical layout of the present filter comprising an assembly of three coupled, tunable WGM resonators. Each WGM resonator is made from a disk of Z-cut LiNbO3 of 3.3-mm diameter and 50-m thickness. The perimeter of the disk is polished and rounded to a radius of curvature of 40 microns. The free spectral range of each WGM resonator is about 13.3 GHz. Gold coats on the flat faces of the disk serve as electrodes for exploiting the electro-optical effect in LiNbO3 for tuning. There is no metal coat on the rounded perimeter region, where the whispering-gallery modes propagate. Light is coupled from an input optical fiber into the whispering-gallery-modes of the first WGM resonator by means of a diamond prism. Another diamond prism is used to couple light from the whispering-gallery-modes of the third WGM resonator to an output optical fiber. The filter operates at a nominal wavelength of 1,550 nm and can be tuned over a frequency range of plus or minus 12 GHz by applying a potential in the range of plus or minus 150 V to the electrodes. The insertion loss (the loss between the input and output coupling optical fibers) was found to be repeatable at 6 dB. The resonance quality factor (Q) of the main sequence of resonator modes was found to be 5 x 10(exp 6), which corresponds to a bandwidth of 30 MHz. The filter can be shifted from one operating frequency to another within a tuning time less than or equal to 30 micro seconds. The transmission curve of the filter at frequencies near the middle of the passband closely approximates a theoretical third-order Butterworth filter profile, as shown in Figure 2.

Third harmonic from air breakdown plasma induced by nanosecond laser pulses

NASA Astrophysics Data System (ADS)

Stafe, M.; Negutu, C.; Puscas, N. N.

2018-06-01

Harmonic generation is a nonlinear optical effect consisting in frequency up-conversion of intense laser radiation when phase-matching conditions are fulfilled. Here, we study the mechanisms involved in the third harmonic (TH) generation process, the conversion efficiency, and the properties of TH radiation generated in air by focusing infrared linearly polarized nanosecond laser pulses at intensities of the order of TW/cm2. By analyzing the emission from the air breakdown plasma, we demonstrate that filamentary breakdown plasma containing molecular nitrogen ions acts as an optical nonlinear medium enabling generation of TH radiation in the axial direction. The data reveal important properties of the TH radiation: maximum conversion efficiency of 0.04%, sinc2 dependence of the TH intensity on the square root of the pump intensity, and three times smaller divergence and pulse duration of TH as compared to the pump radiation.

Study of coherence effects in a four-level Ξ‑Λ type system

NASA Astrophysics Data System (ADS)

Yadav, Kavita; Wasan, Ajay

2018-05-01

We theoretically study the two- and three-photon coherence in a Ξ‑Λ type four-level system for stationary as well moving atoms at the room temperature using density matrix formalism. We discuss the role of dressed states to elucidate the electromagnetically induced transparency and electromagnetically induced absorption phenomena. The presence of the third field induces absorption at the line centre. A negative dispersion slope owing to the enhanced absorption results in super-luminal light propagation and the group index variation with the coupling field is switched from sub- to super-luminal. Group index with probe detuning shows super-luminal light propagation behaviour at the dressed state positions. The three optical fields trigger four-wave mixing as a result of the third order nonlinearity. The transient evolution is also discussed for optimum strengths of the coupling and drive fields to realize the optical switching in the system.

Crystal growth and characterization of third order nonlinear optical piperazinium bis(4-hydroxybenzenesulphonate) (P4HBS) single crystal

NASA Astrophysics Data System (ADS)

Pichan, Karuppasamy; Muthu, Senthil Pandian; Perumalsamy, Ramasamy

2017-09-01

The organic single crystal of piperazinium bis(4-hydroxybenzenesulphonate) (P4HBS) was grown by slow evaporation solution technique (SEST) at room temperature. The lattice parameters of the grown crystal were confirmed by single crystal X-ray diffraction analysis. Functional groups of P4HBS crystal were confirmed by FTIR spectrum analysis. The optical quality of the grown crystal was identified by the UV-Vis NIR spectrum analysis. The grown crystal has good optical transmittance in the range of 410-1100 nm. In photoluminescence spectrum, sharp emission peaks are observed, which indicates the ultraviolet (UV) emission. The photoconductivity study reveals that the grown crystal has negative photoconductive nature. The thermal behaviour of the P4HBS crystal was investigated by thermogravimetric and differential thermal analysis (TG-DTA). The mechanical stability of grown crystal was analyzed and the indentation size effect (ISE) was explained by Hays-Kendall's (HK) approach and proportional specimen resistance model (PSRM). Chemical etching study was carried out and the etch pit density (EPD) was calculated. The dielectric constant (ε‧) and dielectric loss (tan δ) as a function of frequency were measured for the grown crystal. The solid state parameters such as valence electron, plasma energy, Penn gap and Fermi energy were evaluated theoretically for the P4HBS using the empirical relation. The estimated values are used to calculate the electronic polarizability. The third-order nonlinear optical properties such as nonlinear refractive index (n2), absorption co-efficient (β) and susceptibility (χ(3)) were studied by Z-scan technique at 632.8 nm using He-Ne laser.

Investigation on the behavioral difference in third order nonlinearity and optical limiting of Mn0.55Cu0.45Fe2O4 nanoparticles annealed at different temperatures

NASA Astrophysics Data System (ADS)

Yuvaraj, S.; Manikandan, N.; Vinitha, G.

2017-11-01

Mn0.55Cu0.45Fe2O4 nanoparticles were synthesized by wet chemical co-precipitation method. The obtained samples were annealed at different temperatures (500 °C to 1250 °C). All annealed samples were characterized for their structural, magnetic, linear and non-linear optical properties. XRD results confirm single phase cubic spinel structure only for samples annealed at 800 °C and 1250 °C. The average crystallite sizes of the samples are in the range of 11-37 nm. HR-SEM image of the sample annealed at 800 °C exposed spherical morphology. The quantitative analysis of EDX results is close to the expected values. Bandgaps were evaluated from UV-DRS. The FTIR spectrum showing the essential peaks around 452.1 and 567.2 cm-1 prove the formation of spinel nanoparticles. In PL spectrum, a broad emission peak is attained in visible region at 485 nm. The saturation magnetization (M s), coercivity (H c) and remanence magnetization (M r) are obtained from the hysteresis curve. Nonlinear absorption coefficients (10-4 cm W-1), nonlinear indices of refraction (10-8 cm2 W-1) and the third order nonlinear susceptibilities (10-6 esu) are determined using Z-scan experiment. CW laser beam is utilized to study the optical limiting characteristics and the results prove these materials to be a potential candidate for device applications like optical switches and power limiters.

LDR structural experiment definition

NASA Technical Reports Server (NTRS)

Russell, Richard A.; Gates, Richard M.

1988-01-01

A study was performed to develop the definition of a structural flight experiment for a large precision segmented reflector that would utilize the Space Station. The objective of the study was to use the Large Deployable Reflector (LDR) baseline configuration for focusing on experiment definition activity which would identify the Space Station accommodation requirements and interface constraints. Results of the study defined three Space Station based experiments to demonstrate the technologies needed for an LDR type structure. The basic experiment configurations are the same as the JPL baseline except that the primary mirror truss is 10 meters in diameter instead of 20. The primary objectives of the first experiment are to construct the primary mirror support truss and to determine its structural and thermal characteristics. Addition of the optical bench, thermal shield and primary mirror segments and alignment of the optical components occur on the second experiment. The structure will then be moved to the payload pointing system for pointing, optical control and scientific optical measurement for the third experiment.

Linear and nonlinear magneto-optical properties of monolayer phosphorene

NASA Astrophysics Data System (ADS)

Nguyen, Chuong V.; Ngoc Hieu, Nguyen; Duque, C. A.; Quoc Khoa, Doan; Van Hieu, Nguyen; Van Tung, Luong; Vinh Phuc, Huynh

2017-01-01

We theoretically study the magneto-optical properties of monolayer phosphorene under a perpendicular magnetic field. We evaluate linear, third-order nonlinear, and total absorption coefficients and relative refractive index changes as functions of the photon energy and the magnetic field, and show that they are strongly influenced by the magnetic field. The magneto-optical absorption coefficients and relative refractive index changes appear in two different regimes: the microwave to THz and the visible frequency. The amplitude of intra-band transition peaks is larger than that of the inter-band transitions. The resonant peaks are blue-shifted with the magnetic field. Our results demonstrate the potential of monolayer phosphorene as a new two-dimensional material for applications in nano-electronic and optical devices as a promising alternative to graphene.

Plasmon-enhanced versatile optical nonlinearities in a Au-Ag-Au multi-segmental hybrid structure.

PubMed

Yao, Lin-Hua; Zhang, Jun-Pei; Dai, Hong-Wei; Wang, Ming-Shan; Zhang, Lu-Man; Wang, Xia; Han, Jun-Bo

2018-06-27

A Au-Ag-Au multi-segmental hybrid structure has been synthesized by using an electrodeposition method based on an anodic aluminum oxide (AAO) membrane. The third-order optical nonlinearities, second harmonic generation (SHG) and photoluminescence (PL) properties containing ultrafast supercontinuum generation and plasmon mediated thermal emission have been investigated. Significant optical enhancements have been obtained near surface plasmon resonance wavelength in all the abovementioned nonlinear processes. Comparative studies between the Au-Ag-Au multi-segmental hybrid structure and the corresponding single-component Au and Ag hybrid structures demonstrate that the Au-Ag-Au multi-segmental hybrid structure has much larger optical nonlinearities than its counterparts. These results demonstrate that the Au-Ag-Au hybrid structure is a promising candidate for applications in plasmonic devices and enhancement substrates.

Modulating optical rectification, second and third harmonic generation of doped quantum dots: Interplay between hydrostatic pressure, temperature and noise

NASA Astrophysics Data System (ADS)

Ganguly, Jayanta; Saha, Surajit; Bera, Aindrila; Ghosh, Manas

2016-10-01

We examine the profiles of optical rectification (OR), second harmonic generation (SHG) and third harmonic generation (THG) of impurity doped QDs under the combined influence of hydrostatic pressure (HP) and temperature (T) in presence and absence of Gaussian white noise. Noise has been incorporated to the system additively and multiplicatively. In order to study the above nonlinear optical (NLO) properties the doped dot has been subjected to a polarized monochromatic electromagnetic field. Effect of application of noise is nicely reflected through alteration of peak shift (blue/red) and variation of peak height (increase/decrease) of above NLO properties as temperature and pressure are varied. All such changes again sensitively depends on mode of application (additive/multiplicative) of noise. The remarkable influence of interplay between noise strength and its mode of application on the said profiles has also been addressed. The findings illuminate fascinating role played by noise in tuning above NLO properties of doped QD system under the active presence of both hydrostatic pressure and temperature.

Correcting highly aberrated eyes using large-stroke adaptive optics.

PubMed

Sabesan, Ramkumar; Ahmad, Kamran; Yoon, Geunyoung

2007-11-01

To investigate the optical performance of a large-stroke deformable mirror in correcting large aberrations in highly aberrated eyes. A large-stroke deformable mirror (Mirao 52D; Imagine Eyes) and a Shack-Hartmann wavefront sensor were used in an adaptive optics system. Closed-loop correction of the static aberrations of a phase plate designed for an advanced keratoconic eye was performed for a 6-mm pupil. The same adaptive optics system was also used to correct the aberrations in one eye each of two moderate keratoconic and three normal human eyes for a 6-mm pupil. With closed-loop correction of the phase plate, the total root-mean-square (RMS) over a 6-mm pupil was reduced from 3.54 to 0.04 microm in 30 to 40 iterations, corresponding to 3 to 4 seconds. Adaptive optics closed-loop correction reduced an average total RMS of 1.73+/-0.998 to 0.10+/-0.017 microm (higher order RMS of 0.39+/-0.124 to 0.06+/-0.004 microm) in the three normal eyes and 2.73+/-1.754 to 0.10+/-0.001 microm (higher order RMS of 1.82+/-1.058 to 0.05+/-0.017 microm) in the two keratoconic eyes. Aberrations in both normal and highly aberrated eyes were successfully corrected using the large-stroke deformable mirror to provide almost perfect optical quality. This mirror can be a powerful tool to assess the limit of visual performance achievable after correcting the aberrations, especially in eyes with abnormal corneal profiles.

Optical resonance imaging: An optical analog to MRI with sub-diffraction-limited capabilities.

PubMed

Allodi, Marco A; Dahlberg, Peter D; Mazuski, Richard J; Davis, Hunter C; Otto, John P; Engel, Gregory S

2016-12-21

We propose here optical resonance imaging (ORI), a direct optical analog to magnetic resonance imaging (MRI). The proposed pulse sequence for ORI maps space to time and recovers an image from a heterodyne-detected third-order nonlinear photon echo measurement. As opposed to traditional photon echo measurements, the third pulse in the ORI pulse sequence has significant pulse-front tilt that acts as a temporal gradient. This gradient couples space to time by stimulating the emission of a photon echo signal from different lateral spatial locations of a sample at different times, providing a widefield ultrafast microscopy. We circumvent the diffraction limit of the optics by mapping the lateral spatial coordinate of the sample with the emission time of the signal, which can be measured to high precision using interferometric heterodyne detection. This technique is thus an optical analog of MRI, where magnetic-field gradients are used to localize the spin-echo emission to a point below the diffraction limit of the radio-frequency wave used. We calculate the expected ORI signal using 15 fs pulses and 87° of pulse-front tilt, collected using f /2 optics and find a two-point resolution 275 nm using 800 nm light that satisfies the Rayleigh criterion. We also derive a general equation for resolution in optical resonance imaging that indicates that there is a possibility of superresolution imaging using this technique. The photon echo sequence also enables spectroscopic determination of the input and output energy. The technique thus correlates the input energy with the final position and energy of the exciton.

Nanostructured optical fibre arrays for high-density biochemical sensing and remote imaging.

PubMed

Deiss, F; Sojic, N; White, D J; Stoddart, P R

2010-01-01

Optical fibre bundles usually comprise a few thousand to tens of thousands of individually clad glass optical fibres. The ordered arrangement of the fibres enables coherent transmission of an image through the bundle and therefore enables analysis and viewing in remote locations. In fused bundles, this architecture has also been used to fabricate arrays of various micro to nano-scale surface structures (micro/nanowells, nanotips, triangles, etc.) over relatively large areas. These surface structures have been used to obtain new optical and analytical capabilities. Indeed, the imaging bundle can be thought of as a "starting material" that can be sculpted by a combination of fibre drawing and selective wet-chemical etching processes. A large variety of bioanalytical applications have thus been developed, ranging from nano-optics to DNA nanoarrays. For instance, nanostructured optical surfaces with intrinsic light-guiding properties have been exploited as surface-enhanced Raman scattering (SERS) platforms and as near-field probe arrays. They have also been productively associated with electrochemistry to fabricate arrays of transparent nanoelectrodes with electrochemiluminescent imaging properties. The confined geometry of the wells has been loaded with biosensing materials and used as femtolitre-sized vessels to detect single molecules. This review describes the fabrication of high-density nanostructured optical fibre arrays and summarizes the large range of optical and bioanalytical applications that have been developed, reflecting the versatility of this ordered light-guiding platform.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Prakash, Deo; Shaaban, E.R., E-mail: esam_ramadan2008@yahoo.com; Shapaan, M.

Highlights: • Combined experimental and theoretical researches on ZnSe Thin Films. • The film thickness and refractive index were determined using envelope method. • The absorption coefficient and the energy gap were calculated. • Dispersion parameters were determined using Wemple-DiDomenico relation. • The third order susceptibility and nonlinear refractive index were calculated. - Abstract: Zinc selenide (ZnSe) thin films with different thicknesses were evaporated onto glass substrates using the thermal evaporation technique. X-ray diffraction analysis confirmed that both the film and powder have cubic zinc-blende structure. The fundamental optical parameters like absorption coefficient, extinction coefficient and band gap were evaluatedmore » in transparent region of transmittance and reflectance spectrum. The optical transition of the films was found to be allowed, where the energy gap increased from 2.576 to 2.702 eV with increasing film thickness. Also, the refractive index value increase with increasing film thickness. The refractive indices evaluated through envelope method were extrapolated by Cauchy dispersion relationship over the whole spectra range. Additionally, the dispersion of refractive index was determined in terms of Wemple-DiDomenico single oscillator model. Third order susceptibility and nonlinear refractive index were determined for different thickness of ZnSe thin films.« less

Investigation of inorganic nonlinear optical potassium penta borate tetra hydrate (PPBTH) single crystals grown by slow evaporation method

NASA Astrophysics Data System (ADS)

Arivuselvi, R.; Babu, P. Ramesh

2018-03-01

Borates family crystals were plays vital role in the field of non linear optics (NLO) due to needs of wide range of applications. In this report, NLO crystals (potassium penta borate tetra hydrate (KB5H8O12) are grown by slow evaporation method at room temperature (28° C) and studied their physical properties. The harvested single crystals are transparent with the dimension of 12 × 10 × 6 mm3 and colourless. X-ray diffraction of single crystals reveals that the grown crystal belongs to orthorhombic system with non-centrosymmetric space group Pba2. All the absorbed functional groups are present in the order of inorganic compounds expect 1688 cm-1 because of water (Osbnd H sbnd O blending) molecule present in the pristine. Crystals show transparent in the entire visible region with 5.9 eV optical band gap and also it shows excellence in both second and third order nonlinear optical properties. Crystals can withstand upto 154 °C without any phase changes which is observed using thermal (TGA/DTA) analysis.

Dielectric, optical and mechanical studies of phenolic polyene OH1 organic electrooptic crystal

NASA Astrophysics Data System (ADS)

Bharath, D.; Kalainathan, S.

2014-11-01

2-{3-[2-(4-Hydroxyphenyl) vinyl]-5, 5-dimethylcyclo-hex-2-en-1-ylidene}malononitrile (OH1) phenolic locked polyene organic material has been synthesized by the Knoevenagel condensation method. OH1 single crystals were grown in methanol by a slow evaporation method. In order to avoid the multinucleation and reduce the metastable zone width, phosphoric acid is added in different concentrations. The linear optical property of OH1 crystal has been studied using UV-vis-NIR spectroscopy in the wavelength range 190-1100 nm and optical constants are calculated theoretically. The magnitude of nonlinear refractive index (10-12 m2/W), nonlinear absorption (10-6 m/W) and third order nonlinear susceptibility (10-6 esu) has been studied using a Z-scan technique. Dielectric property of OH1 crystal has been studied in frequency range 50 Hz-5 MHz. Photoluminescence spectrum was recorded using a xenon lamp in the range of 450-700 nm. Laser optical damage threshold of OH1 crystal was obtained (0.62 GW/cm2) using a pulsed Nd-YAG laser (1064 nm) of repetition rate 10 ns.

Growth and characterization of benzaldehyde 4-nitro phenyl hydrazone (BPH) single crystal: A proficient second order nonlinear optical material

NASA Astrophysics Data System (ADS)

Saravanan, M.; Abraham Rajasekar, S.

2016-04-01

The crystals (benzaldehyde 4-nitro phenyl hydrazone (BPH)) appropriate for NLO appliance were grown by the slow cooling method. The solubility and metastable zone width measurement of BPH specimen was studied. The material crystallizes in the monoclinic crystal system with noncentrosymmetric space group of Cc. The optical precision in the whole visible region was found to be excellent for non-linear optical claim. Excellence of the grown crystal is ascertained by the HRXRD and etching studies. Laser Damage Threshold and Photoluminescence studies designate that the grown crystal contains less imperfection. The mechanical behaviour of BPH sample at different temperatures was investigated to determine the hardness stability of the grown specimen. The piezoelectric temperament and the relative Second Harmonic Generation (for diverse particle sizes) of the material were also studied. The dielectric studies were executed at varied temperatures and frequencies to investigate the electrical properties. Photoconductivity measurement enumerates consummate of inducing dipoles due to strong incident radiation and also divulge the nonlinear behaviour of the material. The third order nonlinear optical properties of BPH crystals were deliberate by Z-scan method.

Toward large-area roll-to-roll printed nanophotonic sensors

NASA Astrophysics Data System (ADS)

Karioja, Pentti; Hiltunen, Jussi; Aikio, Sanna M.; Alajoki, Teemu; Tuominen, Jarkko; Hiltunen, Marianne; Siitonen, Samuli; Kontturi, Ville; Böhlen, Karl; Hauser, Rene; Charlton, Martin; Boersma, Arjen; Lieberzeit, Peter; Felder, Thorsten; Eustace, David; Haskal, Eliav

2014-05-01

Polymers have become an important material group in fabricating discrete photonic components and integrated optical devices. This is due to their good properties: high optical transmittance, versatile processability at relative low temperatures and potential for low-cost production. Recently, nanoimprinting or nanoimprint lithography (NIL) has obtained a plenty of research interest. In NIL, a mould is pressed against a substrate coated with a moldable material. After deformation of the material, the mold is separated and a replica of the mold is formed. Compared with conventional lithographic methods, imprinting is simple to carry out, requires less-complicated equipment and can provide high-resolution with high throughput. Nanoimprint lithography has shown potential to become a method for low-cost and high-throughput fabrication of nanostructures. We show the development process of nano-structured, large-area multi-parameter sensors using Photonic Crystal (PC) and Surface Enhanced Raman Scattering (SERS) methodologies for environmental and pharmaceutical applications. We address these challenges by developing roll-to-roll (R2R) UV-nanoimprint fabrication methods. Our development steps are the following: Firstly, the proof of concept structures are fabricated by the use of wafer-level processes in Si-based materials. Secondly, the master molds of successful designs are fabricated, and they are used to transfer the nanophotonic structures into polymer materials using sheet-level UV-nanoimprinting. Thirdly, the sheet-level nanoimprinting processes are transferred to roll-to-roll fabrication. In order to enhance roll-to-roll manufacturing capabilities, silicone-based polymer material development was carried out. In the different development phases, Photonic Crystal and SERS sensor structures with increasing complexities were fabricated using polymer materials in order to enhance sheet-level and roll-to-roll manufacturing processes. In addition, chemical and molecular imprint (MIP) functionalization methods were applied in the sensor demonstrators. In this paper, the process flow in fabricating large-area nanophotonic structures by the use of sheet-level and roll-to-roll UV- nanoimprinting is reported.

Nonlinear optical properties of Nd3+-Li+ co-doped ZnS-PVP thin films

NASA Astrophysics Data System (ADS)

Talwatkar, S. S.; Sunatkari, A. L.; Tamgadge, Y. S.; Muley, G. G.

2018-04-01

The nonlinear optical properties of Nd3+-Li+ co-doped ZnS-PVP nanocomposite were studied using a continuous wave (CW) He-Ne laser (λ = 632.8 nm)by z-scan technique. The nonlinear refractive index (n2), absorption coefficient (β) and third order nonlinear susceptibility (χ(3)) of PVP thin films embedded with Nd3+-Li+ co-doped ZnS NPs was found in the order of 10-7 cm2/W, 10-6 cm/W and 10-7 esu respectively. The nonlinearity found increasing with Nd3+-Li+ co-dopant concentration. Based on the results, it is proposed that this material is a new class of luminescent material suitable in optoelectronics devices application, especially in light-emitting devices, electroluminescent devices, display devices, etc.

Perception of second- and third-order orientation signals and their interactions

PubMed Central

Victor, Jonathan D.; Thengone, Daniel J.; Conte, Mary M.

2013-01-01

Orientation signals, which are crucial to many aspects of visual function, are more complex and varied in the natural world than in the stimuli typically used for laboratory investigation. Gratings and lines have a single orientation, but in natural stimuli, local features have multiple orientations, and multiple orientations can occur even at the same location. Moreover, orientation cues can arise not only from pairwise spatial correlations, but from higher-order ones as well. To investigate these orientation cues and how they interact, we examined segmentation performance for visual textures in which the strengths of different kinds of orientation cues were varied independently, while controlling potential confounds such as differences in luminance statistics. Second-order cues (the kind present in gratings) at different orientations are largely processed independently: There is no cancellation of positive and negative signals at orientations that differ by 45°. Third-order orientation cues are readily detected and interact only minimally with second-order cues. However, they combine across orientations in a different way: Positive and negative signals largely cancel if the orientations differ by 90°. Two additional elements are superimposed on this picture. First, corners play a special role. When second-order orientation cues combine to produce corners, they provide a stronger signal for texture segregation than can be accounted for by their individual effects. Second, while the object versus background distinction does not influence processing of second-order orientation cues, this distinction influences the processing of third-order orientation cues. PMID:23532909

Euro50: Proposal for a 50 m Optical and Infrared Telescope

NASA Astrophysics Data System (ADS)

Ardeberg, Arne; Andersen, Torben; Rodriguez Espinosa, Jose Miguel

Staff from Instituto de Astrofisica de Canarias, Lund Observatory, Physics Department and Larmor Research Institute at Galway, and Tuorla Observatory is collaborating on studies for a 50 m optical and infrared telescope. The telescope concepts are based on the work on extremely large telescopes carried out during 1991-2000 at Lund Observatory, and on the experience from the 10.4 m segmented Grantecan telescope presently under construction. The proposed 50 m telescope is a fully adaptive Nasmyth telescope with a Ritchey Chretien configuration. It will have an aspherical, segmented primary mirror with 2 m large segments and a deformable secondary. Adaptive optics will be implemented in several steps. From the beginning, there will be single-conjugate adaptive optics for the K-band. Next, and within the first year of operation, the telescope will have single-conjugate adaptive optics for visible wavelengths. As a third step, and another year of operation, dual-conjugate adaptive optics will be made available for the K-band. The telescope will be housed in a co-rotating enclosure at the Roque de los Muchachos observatory on La Palma. Further studies are in progress aiming at preparation of a proposal during the first half of 2002.

Growth, spectral, linear and nonlinear optical characteristics of an efficient semiorganic acentric crystal: L-valinium L-valine chloride

NASA Astrophysics Data System (ADS)

Nageshwari, M.; Jayaprakash, P.; Kumari, C. Rathika Thaya; Vinitha, G.; Caroline, M. Lydia

2017-04-01

An efficient nonlinear optical semiorganic material L-valinium L-valine chloride (LVVCl) was synthesized and grown-up by means of slow evaporation process. Single crystal XRD evince that LVVCl corresponds to monoclinic system having acentric space group P21. The diverse functional groups existing in LVVCl were discovered with FTIR spectral investigation. The UV-Visible and photoluminescence spectrum discloses the optical and electronic properties respectively for the grown crystal. Several optical properties specifically extinction coefficient, reflectance, linear refractive index, electrical and optical conductivity were also determined. The SEM analysis was also carried out and it portrayed the surface morphology of LVVCl. The calculated value of laser damage threshold was 2.59 GW/cm2. The mechanical and dielectric property of LVVCl was investigated employing microhardness and dielectric studies. The second and third order nonlinear optical characteristics of LVVCl was characterized utilizing Kurtz Perry and Z scan technique respectively clearly suggest its suitability in the domain of optics and photonics.

The Optical Properties of Ion Implanted Silica

NASA Technical Reports Server (NTRS)

Smith, Cydale C.; Ila, D.; Sarkisov, S.; Williams, E. K.; Poker, D. B.; Hensley, D. K.

1997-01-01

We will present our investigation on the change in the optical properties of silica, 'suprasil', after keV through MeV implantation of copper, tin, silver and gold and after annealing. Suprasil-1, name brand of silica glass produced by Hereaus Amerisil, which is chemically pure with well known optical properties. Both linear nonlinear optical properties of the implanted silica were investigated before and after thermal annealing. All implants, except for Sn, showed strong optical absorption bands in agreement with Mie's theory. We have also used Z-scan to measure the strength of the third order nonlinear optical properties of the produced thin films, which is composed of the host material and the metallic nanoclusters. For implants with a measurable optical absorption band we used Doyle's theory and the full width half maximum of the absorption band to calculate the predicted size of the formed nanoclusters at various heat treatment temperatures. These results are compared with those obtained from direct observation using transmission electron microscopic techniques.

ARGOS wavefront sensing: from detection to correction

NASA Astrophysics Data System (ADS)

Orban de Xivry, Gilles; Bonaglia, M.; Borelli, J.; Busoni, L.; Connot, C.; Esposito, S.; Gaessler, W.; Kulas, M.; Mazzoni, T.; Puglisi, A.; Rabien, S.; Storm, J.; Ziegleder, J.

2014-08-01

Argos is the ground-layer adaptive optics system for the Large Binocular Telescope. In order to perform its wide-field correction, Argos uses three laser guide stars which sample the atmospheric turbulence. To perform the correction, Argos has at disposal three different wavefront sensing measurements : its three laser guide stars, a NGS tip-tilt, and a third wavefront sensor. We present the wavefront sensing architecture and its individual components, in particular: the finalized Argos pnCCD camera detecting the 3 laser guide stars at 1kHz, high quantum efficiency and 4e- noise; the Argos tip-tilt sensor based on a quad-cell avalanche photo-diodes; and the Argos wavefront computer. Being in the middle of the commissioning, we present the first wavefront sensing configurations and operations performed at LBT, and discuss further improvements in the measurements of the 3 laser guide star slopes as detected by the pnCCD.

Efficient Second-Harmonic Generation in Nanocrystalline Silicon Nanoparticles.

PubMed

Makarov, Sergey V; Petrov, Mihail I; Zywietz, Urs; Milichko, Valentin; Zuev, Dmitry; Lopanitsyna, Natalia; Kuksin, Alexey; Mukhin, Ivan; Zograf, George; Ubyivovk, Evgeniy; Smirnova, Daria A; Starikov, Sergey; Chichkov, Boris N; Kivshar, Yuri S

2017-05-10

Recent trends to employ high-index dielectric particles in nanophotonics are motivated by their reduced dissipative losses and large resonant enhancement of nonlinear effects at the nanoscale. Because silicon is a centrosymmetric material, the studies of nonlinear optical properties of silicon nanoparticles have been targeting primarily the third-harmonic generation effects. Here we demonstrate, both experimentally and theoretically, that resonantly excited nanocrystalline silicon nanoparticles fabricated by an optimized laser printing technique can exhibit strong second-harmonic generation (SHG) effects. We attribute an unexpectedly high yield of the nonlinear conversion to a nanocrystalline structure of nanoparticles supporting the Mie resonances. The demonstrated efficient SHG at green light from a single silicon nanoparticle is 2 orders of magnitude higher than that from unstructured silicon films. This efficiency is significantly higher than that of many plasmonic nanostructures and small silicon nanoparticles in the visible range, and it can be useful for a design of nonlinear nanoantennas and silicon-based integrated light sources.

Nonlinear Optical Properties of Carotenoid and Chlorophyll Harmonophores

NASA Astrophysics Data System (ADS)

Tokarz, Danielle Barbara

Information regarding the structure and function of living tissues and cells is instrumental to the advancement of cell biology and biophysics. Nonlinear optical microscopy can provide such information, but only certain biological structures generate nonlinear optical signals. Therefore, structural specificity can be achieved by introducing labels for nonlinear optical microscopy. Few studies exist in the literature about labels that facilitate harmonic generation, coined "harmonophores". This thesis consists of the first major investigation of harmonophores for third harmonic generation (THG) microscopy. Carotenoids and chlorophylls were investigated as potential harmonophores. Their nonlinear optical properties were studied by the THG ratio technique. In addition, a tunable refractometer was built in order to determine their second hyperpolarizability (gamma). At 830 nm excitation wavelength, carotenoids and chlorophylls were found to have large negative gamma values however, at 1028 nm, the sign of gamma reversed for carotenoids and remained negative for chlorophylls. Consequently, at 1028 nm wavelength, THG signal is canceled with mixtures of carotenoids and chlorophylls. Furthermore, when such molecules are covalently bonded as dyads or interact within photosynthetic pigment-protein complexes, it is found that additive effects with the gamma values still play a role, however, the overall gamma value is also influenced by the intra-pigment and inter-pigment interaction. The nonlinear optical properties of aggregates containing chlorophylls and carotenoids were the target of subsequent investigations. Carotenoid aggregates were imaged with polarization-dependent second harmonic generation and THG microscopy. Both techniques revealed crystallographic information pertaining to H and J aggregates and beta-carotene crystalline aggregates found in orange carrot. In order to demonstrate THG enhancement due to labeling, cultured cells were labeled with carotenoid incorporated liposomes. In addition, Drosophila melanogaster larvae muscle as well as keratin structures in the hair cortex were labeled with beta-carotene. Polarization-dependent THG studies may be particularly useful in understanding the structural organization that occurs within biological structures containing carotenoids and chlorophylls such as photosynthetic pigment-protein complexes and carotenoid aggregates in plants and alga. Further, artificial labeling with carotenoids and chlorophylls may be useful in clinical applications since they are nontoxic, nutritionally valuable, and they can aid in visualizing structural changes in cellular components.

Dynamic evolution of light-induced orientation of dye-doped liquid crystals in liquid phase studied by time-resolved optically heterodyned optical Kerr effect technique.

PubMed

Yang, Pei; Liu, Liying; Xu, Lei

2008-02-28

Transient evolution of light-induced molecular reorientation both in 1-amino-anthraquinone (1AAQ) dye and azobenzene doped isotropic liquid crystals (LCs) were studied by time-resolved optically heterodyned optical Kerr effect method. The results give clear direct experimental proof that under short pulse (30 ps) excitation, LC molecules orientate toward the excitation light polarization direction in the 1AAQ/LC system. However, LC molecular orientation becomes orthogonal to the light polarization in azobenzene/LC system. Time-resolved excited-state absorption of 1AAQ and wavelength dependent excited-state absorption of azobenzene were also observed and their contributions to the early dynamics of the third order optical responses of the two systems were confirmed. A simplified two-level mean-field theory was derived to reveal the intensity dependence of orientation enhancement factor in azobenzene/LC system considering the photoisomerization process.

Optical super-resolution effect induced by nonlinear characteristics of graphene oxide films

NASA Astrophysics Data System (ADS)

Zhao, Yong-chuang; Nie, Zhong-quan; Zhai, Ai-ping; Tian, Yan-ting; Liu, Chao; Shi, Chang-kun; Jia, Bao-hua

2018-01-01

In this work, we focus on the optical super-resolution effect induced by strong nonlinear saturation absorption (NSA) of graphene oxide (GO) membranes. The third-order optical nonlinearities are characterized by the canonical Z-scan technique under femtosecond laser (wavelength: 800 nm, pulse width: 100 fs) excitation. Through controlling the applied femtosecond laser energy, NSA of the GO films can be tuned continuously. The GO film is placed at the focal plane as a unique amplitude filter to improve the resolution of the focused field. A multi-layer system model is proposed to present the generation of a deep sub-wavelength spot associated with the nonlinearity of GO films. Moreover, the parameter conditions to achieve the best resolution (˜λ/6) are determined entirely. The demonstrated results here are useful for high density optical recoding and storage, nanolithography, and super-resolution optical imaging.

Enhancement of two photon absorption with Ni doping in the dilute magnetic semiconductor ZnO crystalline nanorods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rana, Amit Kumar; Kumar, Yogendra; Arjunan, M.S.

2015-12-07

In this letter, we have investigated the third-order optical nonlinearities of high-quality Ni doped ZnO nanorods crystallized in wurtzite lattice, prepared by the wet chemical method. In our experiments, we found that the two photon absorption coefficient (β) increases by as much as 14 times, i.e., 7.6 ± 0.4 to 112 ± 6 cm/GW, when the Ni doping is increased from 0% to 10%. The substantial enhancement in β is discussed in terms of the bandgap scaling and Ni doping. Furthermore, we also show that the optical bandgap measured by UV-Vis and photoluminescence spectroscopies, continuously redshift with increasing Ni doping concentration.more » We envision that the strong nonlinear optical properties together with their dilute magnetic effects, they form an important class of materials for potential applications in magneto-optical and integrated optical chips.« less

Enhancement of two photon absorption with Ni doping in the dilute magnetic semiconductor ZnO crystalline nanorods

NASA Astrophysics Data System (ADS)

Rana, Amit Kumar; J, Aneesh; Kumar, Yogendra; M. S, Arjunan; Adarsh, K. V.; Sen, Somaditya; Shirage, Parasharam M.

2015-12-01

In this letter, we have investigated the third-order optical nonlinearities of high-quality Ni doped ZnO nanorods crystallized in wurtzite lattice, prepared by the wet chemical method. In our experiments, we found that the two photon absorption coefficient (β) increases by as much as 14 times, i.e., 7.6 ± 0.4 to 112 ± 6 cm/GW, when the Ni doping is increased from 0% to 10%. The substantial enhancement in β is discussed in terms of the bandgap scaling and Ni doping. Furthermore, we also show that the optical bandgap measured by UV-Vis and photoluminescence spectroscopies, continuously redshift with increasing Ni doping concentration. We envision that the strong nonlinear optical properties together with their dilute magnetic effects, they form an important class of materials for potential applications in magneto-optical and integrated optical chips.

CAD Integration : new optical design possibilities

NASA Astrophysics Data System (ADS)

Haumonte, Jean-Baptiste; Venturino, Jean-Claude

2005-09-01

The development of optical design and analysis tools in a CAD software can help to optimise the design, size and performance of tomorrow's consumer products. While optics was still held back by software limitations, CAD programs were moving forward in leaps and bounds, improving manufacturing technologies and making it possible to design and produce highly innovative and sophisticated products. The problem was that in the past, 'traditional' optical design programs were only able to simulate spherical and aspherical lenses, meaning that the optical designers were limited to designing systems which were a series of imperfect lenses, each one correcting the last. That is why OPTIS has created the first optical design program to be fully integrated into a CAD program. The technology is available from OPTIS in an integrated SOLIDWORKS or CATIA V5 version. Users of this software can reduce the number of lenses needed in a system. Designers will now have access to complex surfaces such as NURBS meaning they will now be able to define free shape progressive lenses and even improve on optical performances using fewer lenses. This revolutionary technology will allow mechanical designers to work on optical systems and to share information with optical designers for the first time. Previously not possible in a CAD program you may now determine all the optical performances of any optical system, providing first order and third order performances, sequential and non-sequential ray-tracing, wavefront surfaces, point spread function, MTF, spot-diagram, using real optical surfaces and guaranteeing the mechanical precision necessary for an optical system.

Spherical mirror grazing incidence x-ray optics

NASA Technical Reports Server (NTRS)

Cash, Jr., Webster C. (Inventor)

1997-01-01

An optical system for x-rays combines at least two spherical or near spherical mirrors for each dimension in grazing incidence orientation to provide the functions of a lens in the x-ray region. To focus x-ray radiation in both the X and the Y dimensions, one of the mirrors focusses the X dimension, a second mirror focusses the Y direction, a third mirror corrects the X dimension by removing comatic aberration and a fourth mirror corrects the Y dimension. Spherical aberration may also be removed for an even better focus. The order of the mirrors is unimportant.

Enhanced Kerr nonlinearity in a quantized four-level graphene nanostructure

NASA Astrophysics Data System (ADS)

Ghahraman, Solookinejad; M, Panahi; E, Ahmadi; Seyyed, Hossein Asadpour

2016-07-01

In this paper, a new model is proposed for manipulating the Kerr nonlinearity of right-hand circular probe light in a monolayer of graphene nanostructure. By using the density matrix equations and quantum optical approach, the third-order susceptibility of probe light is explored numerically. It is realized that the enhanced Kerr nonlinearity with zero linear absorption can be provided by selecting the appropriate quantities of controllable parameters, such as Rabi frequency and elliptical parameter of elliptical polarized coupling field. Our results may be useful applications in future all-optical system devices in nanostructures.

Incorporation of New Benzofulvene Derivatives Into Polymers to Give New NLO Materials

NASA Technical Reports Server (NTRS)

Bowens, Andrea D.; Bu, Xiu; Mintz, Eric A.; Zhang, Yue

1996-01-01

The need for fast electro-optic switches and modulators for optical communication, and laser frequency conversion has created a demand for new second-order non-linear optical materials. One approach to produce such materials is to align chromophores with large molecular hyperpolarizabilities in polymers. Recently fulvenes and benzofulvenes which contain electron donating groups have been shown to exhibit large second-order non-linear optical properties. The resonance structures shown below suggest that intramolecular charge transfer (ICT) should be favorable in omega - (hydroxyphenyl)benzofulvenes and even more favorable in omega-omega - (phenoxy)benzofulvenes because of the enhanced donor properties of the O group. This ICT should lead to enormously enhanced second-order hyperpolarizability. We have prepared all three new omega - (hydroxyphenyl)benzofulvenes by the condensation of indene with the appropriate hydroxyaryl aldehyde in MeOH or MeOH/H2O under base catalysis. In a similar fashion we have prepared substituted benzofulvenes with multipal donor groups. Preliminary studies show that some of our benzofulvene derivatives exhibit second order harmonic generation (SHG). Measurements were carried out by preparing host-guest polymers. The results of our work on benzofulvene derivatives in host-guest polymers when covalently bonded in the polymer will be described.

Optical pulling and pushing forces exerted on silicon nanospheres with strong coherent interaction between electric and magnetic resonances.

PubMed

Liu, Hongfeng; Panmai, Mingcheng; Peng, Yuanyuan; Lan, Sheng

2017-05-29

We investigated theoretically and numerically the optical pulling and pushing forces acting on silicon (Si) nanospheres (NSs) with strong coherent interaction between electric and magnetic resonances. We examined the optical pulling and pushing forces exerted on Si NSs by two interfering waves and revealed the underlying physical mechanism from the viewpoint of electric- and magnetic-dipole manipulation. As compared with a polystyrene (PS) NS, it was found that the optical pulling force for a Si NS with the same size is enlarged by nearly two orders of magnitude. In addition to the optical pulling force appearing at the long-wavelength side of the magnetic dipole resonance, very large optical pushing force is observed at the magnetic quadrupole resonance. The correlation between the optical pulling/pushing force and the directional scattering characterized by the ratio of the forward to backward scattering was revealed. More interestingly, it was found that the high-order electric and magnetic resonances in large Si NSs play an important role in producing optical pulling force which can be generated by not only s-polarized wave but also p-polarized one. Our finding indicates that the strong coherent interaction between the electric and magnetic resonances existing in nanoparticles with large refractive indices can be exploited to manipulate the optical force acting on them and the correlation between the optical force and the directional scattering can be used as guidance. The engineering and manipulation of optical forces will find potential applications in the trapping, transport and sorting of nanoparticles.

Single MoO3 nanoribbon waveguides: good building blocks as elements and interconnects for nanophotonic applications

NASA Astrophysics Data System (ADS)

Zhang, Li; Wu, Guoqing; Gu, Fuxing; Zeng, Heping

2015-11-01

Exploring new nanowaveguide materials and structures is of great scientific interest and technological significance for optical and photonic applications. In this work, high-quality single-crystal MoO3 nanoribbons (NRs) are synthesized and used for optical guiding. External light sources are efficiently launched into the single MoO3 NRs using silica fiber tapers. It is found that single MoO3 NRs are as good nanowaveguides with loss optical losses (typically less than 0.1 dB/μm) and broadband optical guiding in the visible/near-infrared region. Single MoO3 NRs have good Raman gains that are comparable to those of semiconductor nanowaveguides, but the second harmonic generation efficiencies are about 4 orders less than those of semiconductor nanowaveguides. And also no any third-order nonlinear optical effects are observed at high pump power. A hybrid Fabry-Pérot cavity containing an active CdSe nanowire and a passive MoO3 NR is also demonstrated, and the ability of coupling light from other active nanostructures and fluorescent liquid solutions has been further demonstrated. These optical properties make single MoO3 NRs attractive building blocks as elements and interconnects in miniaturized photonic circuitries and devices.

Development of reaction-sintered SiC mirror for space-borne optics

NASA Astrophysics Data System (ADS)

Yui, Yukari Y.; Kimura, Toshiyoshi; Tange, Yoshio

2017-11-01

We are developing high-strength reaction-sintered silicon carbide (RS-SiC) mirror as one of the new promising candidates for large-diameter space-borne optics. In order to observe earth surface or atmosphere with high spatial resolution from geostationary orbit, larger diameter primary mirrors of 1-2 m are required. One of the difficult problems to be solved to realize such optical system is to obtain as flat mirror surface as possible that ensures imaging performance in infrared - visible - ultraviolet wavelength region. This means that homogeneous nano-order surface flatness/roughness is required for the mirror. The high-strength RS-SiC developed and manufactured by TOSHIBA is one of the most excellent and feasible candidates for such purpose. Small RS-SiC plane sample mirrors have been manufactured and basic physical parameters and optical performances of them have been measured. We show the current state of the art of the RS-SiC mirror and the feasibility of a large-diameter RS-SiC mirror for space-borne optics.

Relations Between Cloud Condensation Nuclei And Aerosol Optical Properties Relevant to Remote Sensing: Airborne Measurements in Biomass Burning, Pollution and Dust Aerosol Over North America

NASA Astrophysics Data System (ADS)

Shinozuka, Y.; Clarke, A.; Howell, S.; Kapustin, V.; McNaughton, C.; Zhou, J.; Decarlo, P.; Jimenez, J.; Roberts, G.; Tomlinson, J.; Collins, D.

2008-12-01

Remote sensing of the concentration of cloud condensation nuclei (CCN) would help investigate the indirect effect of tropospheric aerosols on clouds and climate. In order to assess its feasibility, this paper evaluates the spectral-based retrieval technique for aerosol number and seeks one for aerosol solubility, using in-situ aircraft measurements of aerosol size distribution, chemical composition, hygroscopicity, CCN activity and optical properties. Our statistical analysis reveals that the CCN concentration over Mexico can be optically determined to a relative error of <20%, smaller than that for the mainland US and the surrounding oceans (~a factor of 2). Mexico's advantage is four-fold. Firstly, many particles originating from the lightly regulated industrial combustion and biomass burning are large enough to significantly affect light extinction, elevating the correlation between extinction and CCN number in absence of substantial dust. Secondly, the generally low ambient humidity near the major aerosol sources limits the error in the estimated response of particle extinction to humidity changes. Thirdly, because many CCN contain black carbon, light absorption also provides a measure of the CCN concentration. Fourthly, the organic fraction of volatile mass of submicron particles (OMF) is anti-correlated with the wavelength dependence of extinction due to preferential anion uptake by coarse dust, which provides a potential tool for remote-sensing OMF and the particle solubility.

Low power continuous-wave nonlinear optical effects in MoS2 nanosheets synthesized by simple bath ultrasonication

NASA Astrophysics Data System (ADS)

Karmakar, S.; Biswas, S.; Kumbhakar, P.

2017-11-01

Here, we have unveiled low power continuous-wave nonlinear optical properties of a few layer (4-12L) Molybdenum disulfide (MoS2) dispersion in N, N-dimethylformamide (DMF) by using spatial self-phase modulation technique. The effective third-order nonlinear susceptibility of the monolayer has been estimated to be as high as ∼10-8 esu. Also a low power technique of syntheses of stable and a few-layer (4-12L) MoS2 dispersion in DMF has been demonstrated here by utilizing ultrasonication bath treatment combined with the natural gravitation sedimentation effect starting from the bulk MoS2 powder. The synthesized samples are exhibiting interesting linear optical absorption and photoluminescence (PL) after exfoliation to a few layer nanosheets (NSs) and the exciton binding energies have been determined from PL emission data in association with 2D hydrogenic Bohr-exciton model. The specific capacitances (Csp) of the electrode prepared with MoS2 NSs have been measured by electrochemical measurement and the highest value of Csp is 382 Fg-1 for 4L sample. The reported intensity driven change of Csp in the presence of light emitted from light emitting diodes of various colours is unprecedented. The demonstrated technique can be scaled up for large scale and easy synthesis of other 2D materials having applications in optoelectronics and energy devices.

I. The theory of aberrations of quadrupole focusing arrays. II. Ion optical design of high quality extracted synchrotron beams with application to the bevatron

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meads, Jr, Philip Francis

In Part One they formulate in a general way the problem of analyzing and evaluating the aberrations of quadrupole magnet beam systems, and of characterizing the shapes and other properties of the beam envelopes in the neighborhood of foci. They consider all aberrations, including those due to misalignments and faulty construction, through third order in small parameters, for quadrupole beam systems. One result of this study is the development of analytic and numerical techniques for treating these aberrations, yielding useful expressions for the comparison of the aberrations of different beam systems. A second result of this study is a comprehensivemore » digital computer program that determines the magnitude and nature of the aberrations of such beam systems. The code, using linear programming techniques, will adjust the parameters of a beam system to obtain specified optical properties and to reduce the magnitude of aberrations that limit the performance of that system. They examine numerically, in detail, the aberrations of two typical beam systems. In Part Two, they examine the problem of extracting the proton beam from a synchrotron of 'H' type magnet construction. They describe the optical studies that resulted in the design of an external beam from the Bevatron that is optimized with respect to linear, dispersive, and aberration properties and that uses beam elements of conservative design. The design of the beam is the result of the collaboration of many people representing several disciplines. They describe the digital computer programs developed to carry out detailed orbit studies which were required because of the existence of large second order aberrations in the beam.« less

Nonlinear optical studies and structure-activity relationship of chalcone derivatives with in silico insights

NASA Astrophysics Data System (ADS)

Kar, Swayamsiddha; Adithya, K. S.; Shankar, Pruthvik; Jagadeesh Babu, N.; Srivastava, Sailesh; Nageswara Rao, G.

2017-07-01

Nine chalcones were prepared via Claisen-Schmidt condensation, and characterized by UV-vis, IR, 1H NMR, 13C NMR and mass spectrometry. One of the representative member 4-NDM-TC has been studied via single crystal XRD and the TGA/DTA technique. SHG efficiency and NLO susceptibilities of the chalcones have been evaluated by the Kurtz and Perry method and Degenerate Four Wave Mixing techniques respectively. 3-Cl-4‧-HC was noted to possess SHG efficiency 1.37 times that of urea while 4-NDM-TC returned the highest third order NLO susceptibilities with respect to CS2. In silico studies help evaluate various physical parameters, in correlating the observed activities. In conclusion, the structure-activity relationship was derived based on the in silico and experimental results for the third order NLO susceptibilities.

Monolithically integrated quantum dot optical gain modulator with semiconductor optical amplifier for 10-Gb/s photonic transmission

NASA Astrophysics Data System (ADS)

Yamamoto, Naokatsu; Akahane, Kouichi; Umezawa, Toshimasa; Kawanishi, Tetsuya

2015-03-01

Short-range interconnection and/or data center networks require high capacity and a large number of channels in order to support numerous connections. Solutions employed to meet these requirements involve the use of alternative wavebands to increase the usable optical frequency range. We recently proposed the use of the T- and O-bands (Thousand band: 1000-1260 nm, Original band: 1260-1360 nm) as alternative wavebands because large optical frequency resources (>60 THz) can be easily employed. In addition, a simple and compact Gb/s-order high-speed optical modulator is a critical photonic device for short-range communications. Therefore, to develop an optical modulator that acts as a highfunctional photonic device, we focused on the use of self-assembled quantum dots (QDs) as a three-dimensional (3D) confined structure because QD structures are highly suitable for realizing broadband optical gain media in the T+O bands. In this study, we use the high-quality broadband QD optical gain to develop a monolithically integrated QD optical gain modulator (QD-OGM) device that has a semiconductor optical amplifier (QD-SOA) for Gb/s-order highspeed optical data generation in the 1.3-μm waveband. The insertion loss of the device can be compensated through the SOA, and we obtained an optical gain change of up to ~7 dB in the OGM section. Further, we successfully demonstrate a 10-Gb/s clear eye opening using the QD-OGM/SOA device with a clock-data recovery sequence at the receiver end. These results suggest that the monolithic QD-EOM/SOA is suitable for increasing the number of wavelength channels for smart short-range communications.

Theoretical limit of spatial resolution in diffuse optical tomography using a perturbation model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Konovalov, A B; Vlasov, V V

2014-03-28

We have assessed the limit of spatial resolution of timedomain diffuse optical tomography (DOT) based on a perturbation reconstruction model. From the viewpoint of the structure reconstruction accuracy, three different approaches to solving the inverse DOT problem are compared. The first approach involves reconstruction of diffuse tomograms from straight lines, the second – from average curvilinear trajectories of photons and the third – from total banana-shaped distributions of photon trajectories. In order to obtain estimates of resolution, we have derived analytical expressions for the point spread function and modulation transfer function, as well as have performed a numerical experiment onmore » reconstruction of rectangular scattering objects with circular absorbing inhomogeneities. It is shown that in passing from reconstruction from straight lines to reconstruction using distributions of photon trajectories we can improve resolution by almost an order of magnitude and exceed the accuracy of reconstruction of multi-step algorithms used in DOT. (optical tomography)« less

Non-linear non-local molecular electrodynamics with nano-optical fields.

PubMed

Chernyak, Vladimir Y; Saurabh, Prasoon; Mukamel, Shaul

2015-10-28

The interaction of optical fields sculpted on the nano-scale with matter may not be described by the dipole approximation since the fields may vary appreciably across the molecular length scale. Rather than incrementally adding higher multipoles, it is advantageous and more physically transparent to describe the optical process using non-local response functions that intrinsically include all multipoles. We present a semi-classical approach for calculating non-local response functions based on the minimal coupling Hamiltonian. The first, second, and third order response functions are expressed in terms of correlation functions of the charge and the current densities. This approach is based on the gauge invariant current rather than the polarization, and on the vector potential rather than the electric and magnetic fields.

Structural control of nonlinear optical absorption and refraction in dense metal nanoparticle arrays.

PubMed

Kohlgraf-Owens, Dana C; Kik, Pieter G

2009-08-17

The linear and nonlinear optical properties of a composite containing interacting spherical silver nanoparticles embedded in a dielectric host are studied as a function of interparticle separation using three dimensional frequency domain simulations. It is shown that for a fixed amount of metal, the effective third-order nonlinear susceptibility of the composite chi((3))(omega) can be significantly enhanced with respect to the linear optical properties, due to a combination of resonant surface plasmon excitation and local field redistribution. It is shown that this geometry-dependent susceptibility enhancement can lead to an improved figure of merit for nonlinear absorption. Enhancement factors for the nonlinear susceptibility of the composite are calculated, and the complex nature of the enhancement factors is discussed.

Fiber-optic epoxy composite cure sensor. II. Performance characteristics

NASA Astrophysics Data System (ADS)

Lam, Kai-Yuen; Afromowitz, Martin A.

1995-09-01

The performance of a fiber-optic epoxy composite cure sensor, as previously proposed, depends on the optical properties and the reaction kinetics of the epoxy. The reaction kinetics of a typical epoxy system are presented. It is a third-order autocatalytic reaction with a peak observed in each isothermal reaction-rate curve. A model is derived to describe the performance characteristics of the epoxy cure sensor. If a composite coupon is cured at an isothermal temperature, the sensor signal can be used to predict the time when the gel point occurs and to monitor the cure process. The sensor is also shown to perform well in nonstoichiometric epoxy matrices. In addition the sensor can detect the end of the cure without calibration.

Chaos-assisted broadband momentum transformation in optical microresonators.

PubMed

Jiang, Xuefeng; Shao, Linbo; Zhang, Shu-Xin; Yi, Xu; Wiersig, Jan; Wang, Li; Gong, Qihuang; Lončar, Marko; Yang, Lan; Xiao, Yun-Feng

2017-10-20

The law of momentum conservation rules out many desired processes in optical microresonators. We report broadband momentum transformations of light in asymmetric whispering gallery microresonators. Assisted by chaotic motions, broadband light can travel between optical modes with different angular momenta within a few picoseconds. Efficient coupling from visible to near-infrared bands is demonstrated between a nanowaveguide and whispering gallery modes with quality factors exceeding 10 million. The broadband momentum transformation enhances the device conversion efficiency of the third-harmonic generation by greater than three orders of magnitude over the conventional evanescent-wave coupling. The observed broadband and fast momentum transformation could promote applications such as multicolor lasers, broadband memories, and multiwavelength optical networks. Copyright © 2017 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.

Second-order closure PBL model with new third-order moments: Comparison with LES data

NASA Technical Reports Server (NTRS)

Canuto, V. M.; Minotti, F.; Ronchi, C.; Ypma, R. M.; Zeman, O.

1994-01-01

This paper contains two parts. In the first part, a new set of diagnostic equations is derived for the third-order moments for a buoyancy-driven flow, by exact inversion of the prognostic equations for the third-order moment equations in the stationary case. The third-order moments exhibit a universal structure: they all are a linear combination of the derivatives of all the second-order moments, bar-w(exp 2), bar-w theta, bar-theta(exp 2), and bar-q(exp 2). Each term of the sum contains a turbulent diffusivity D(sub t), which also exhibits a universal structure of the form D(sub t) = a nu(sub t) + b bar-w theta. Since the sign of the convective flux changes depending on stable or unstable stratification, D(sub t) varies according to the type of stratification. Here nu(sub t) approximately equal to wl (l is a mixing length and w is an rms velocity) represents the 'mechanical' part, while the 'buoyancy' part is represented by the convective flux bar-w theta. The quantities a and b are functions of the variable N(sub tau)(exp 2), where N(exp 2) = g alpha derivative of Theta with respect to z and tau is the turbulence time scale. The new expressions for the third-order moments generalize those of Zeman and Lumley, which were subsequently adopted by Sun and Ogura, Chen and Cotton, and Finger and Schmidt in their treatments of the convective boundary layer. In the second part, the new expressions for the third-order moments are used to solve the ensemble average equations describing a purely convective boundary laye r heated from below at a constant rate. The computed second- and third-order moments are then compared with the corresponding Large Eddy Simulation (LES) results, most of which are obtained by running a new LES code, and part of which are taken from published results. The ensemble average results compare favorably with the LES data.

Cascading second-order nonlinear processes in a lithium niobate-on-insulator microdisk.

PubMed

Liu, Shijie; Zheng, Yuanlin; Chen, Xianfeng

2017-09-15

Whispering-gallery-mode (WGM) microcavities are very important in both fundamental science and practical applications, among which on-chip second-order nonlinear microresonators play an important role in integrated photonic functionalities. Here we demonstrate resonant second-harmonic generation (SHG) and cascaded third-harmonic generation (THG) in a lithium niobate-on-insulator (LNOI) microdisk resonator. Efficient SHG in the visible range was obtained with only several mW input powers at telecom wavelengths. THG was also observed through a cascading process, which reveals simultaneous phase matching and strong mode coupling in the resonator. Cascading of second-order nonlinear processes gives rise to an effectively large third-order nonlinearity, which makes on-chip second-order nonlinear microresonators a promising frequency converter for integrated nonlinear photonics.

Contribution of the 2(1)Ag state to the third-order optical nonlinearity in a squaraine dye.

PubMed

Andrews, J H; Khaydarov, J D; Singer, K D

1994-07-01

We have measured the third-harmonic response, gamma, of a centrosymmetric squaraine dye (ISQ) in chloroform at a range of frequencies for which the third harmonic is above the strong, narrow peak in the dye's linear absorption spectrum but below the UV absorption band. By fitting the experimental dispersion of gamma using a four-level model, we determine the strength, location, and width of the lowest-lying two-photon transition. We find that the 2(1)Ag state appears just above the 1(1)Bu state in energy and that the 1(1)Bu-2(1)Ag transition moment is somewhat smaller than the transition moment between the ground state and the 1(1)Bu state but much larger than previously predicted for comparable squaraine dyes.

A Cross-Dispersed Medium-Resolution Spectrograph for Appalachian State Univeristy's 32-inch Telescope

NASA Astrophysics Data System (ADS)

Kluttz, K. A.; Gray, R. O.

2003-12-01

We have designed and constructed an economical medium-resolution spectrograph to be used on the 32-inch telescope of Appalachian State University's Dark Sky Observatory (DSO). The primary function of this instrument will be to study shell and emission-line stars. However, we will also use this instrument for chemical abundance studies and radial velocities. The basic design is that of an Ebert spectrograph with a single 6-inch mirror acting as both the collimator and camera. The primary dispersion is accomplished by a reflection grating, and order separation is accomplished by a grism. The spectrograph has been designed so that three wavelength regions are simultaneously imaged on the CCD camera. When the Hα line is centered in the third order, Hβ and lines of Fe II multiplet 42 -- often enhanced in shell and emission-line stars -- appear in the fourth order and the fifth order contains both the Ca II K & H lines. To facilitate abundance measurements, a telluric-free region near 6400Å is available in the third order by tilting the main diffraction grating. Preliminary tests have shown that the resolution of the new spectrograph is 0.42Å in the third order (R ≈ 15,000). This relatively high resolution will allow studies to be conducted at DSO which have not previously been possible with the instrumentation currently in use. Several optical components for this spectrograph were purchased with grants from the Fund for Astrophysical Research and the University Research Council.

Correlating Microstructure and Optoelectronic Performance of Carbon-Based Nanomaterials

NASA Astrophysics Data System (ADS)

Rochford, Caitlin

There is a great deal of interest in carbon nanostructures such as graphene and various forms of carbon nanotubes due to their exceptional physical, electronic, and optical properties. Many technological applications have been proposed for these nanostructures, but despite the promise many carbon nanostructure-based optoelectronic devices fail to compete with their conventional counterparts. This is often due in large part to a non-optimized material or device microstructure. Factors such as crystallinity, contact quality, defect structure, and device configuration can critically affect device performance due to the high sensitivity and extreme surface to volume ratio of carbon nanostructures. In order for the exceptional intrinsic properties of the nanostructures to be exploited, a clear understanding of the microstructure and its correlation with device-relevant optoelectronic properties is needed. This dissertation presents four projects which demonstrate this principle. First, a TiO 2-coated carbon nanofiber is studied in order to optimize its structure for use in a novel dye-sensitized solar cell. Second, the electrode configuration of an individual multiwall carbon nanotube infrared sensor is investigated in order to surpass the limitations of disordered nanotube film-based infrared sensors. Third, the properties of defect structures in large area transferred graphene films grown by chemical vapor deposition are correlated with carrier diffusion in order to understand the film's low mobility compared to exfoliated graphene. Fourth, the effect of deposition conditions on graphene-metal contact was studied with the goal of achieving sufficiently transparent contacts for investigation of the superconducting proximity effect. All four projects highlight the unique properties of carbon nanostructures as well as the need to correlate their optoelectronic properties with microstructural details in order to achieve the desired device performance.

Research on precision grinding technology of large scale and ultra thin optics

NASA Astrophysics Data System (ADS)

Zhou, Lian; Wei, Qiancai; Li, Jie; Chen, Xianhua; Zhang, Qinghua

2018-03-01

The flatness and parallelism error of large scale and ultra thin optics have an important influence on the subsequent polishing efficiency and accuracy. In order to realize the high precision grinding of those ductile elements, the low deformation vacuum chuck was designed first, which was used for clamping the optics with high supporting rigidity in the full aperture. Then the optics was planar grinded under vacuum adsorption. After machining, the vacuum system was turned off. The form error of optics was on-machine measured using displacement sensor after elastic restitution. The flatness would be convergenced with high accuracy by compensation machining, whose trajectories were integrated with the measurement result. For purpose of getting high parallelism, the optics was turned over and compensation grinded using the form error of vacuum chuck. Finally, the grinding experiment of large scale and ultra thin fused silica optics with aperture of 430mm×430mm×10mm was performed. The best P-V flatness of optics was below 3 μm, and parallelism was below 3 ″. This machining technique has applied in batch grinding of large scale and ultra thin optics.

MPDATA: Third-order accuracy for variable flows

NASA Astrophysics Data System (ADS)

Waruszewski, Maciej; Kühnlein, Christian; Pawlowska, Hanna; Smolarkiewicz, Piotr K.

2018-04-01

This paper extends the multidimensional positive definite advection transport algorithm (MPDATA) to third-order accuracy for temporally and spatially varying flows. This is accomplished by identifying the leading truncation error of the standard second-order MPDATA, performing the Cauchy-Kowalevski procedure to express it in a spatial form and compensating its discrete representation-much in the same way as the standard MPDATA corrects the first-order accurate upwind scheme. The procedure of deriving the spatial form of the truncation error was automated using a computer algebra system. This enables various options in MPDATA to be included straightforwardly in the third-order scheme, thereby minimising the implementation effort in existing code bases. Following the spirit of MPDATA, the error is compensated using the upwind scheme resulting in a sign-preserving algorithm, and the entire scheme can be formulated using only two upwind passes. Established MPDATA enhancements, such as formulation in generalised curvilinear coordinates, the nonoscillatory option or the infinite-gauge variant, carry over to the fully third-order accurate scheme. A manufactured 3D analytic solution is used to verify the theoretical development and its numerical implementation, whereas global tracer-transport benchmarks demonstrate benefits for chemistry-transport models fundamental to air quality monitoring, forecasting and control. A series of explicitly-inviscid implicit large-eddy simulations of a convective boundary layer and explicitly-viscid simulations of a double shear layer illustrate advantages of the fully third-order-accurate MPDATA for fluid dynamics applications.

Effects of electromagnetic fields on the nonlinear optical properties of asymmetric double quantum well under intense laser field

NASA Astrophysics Data System (ADS)

Yesilgul, U.; Sari, H.; Ungan, F.; Martínez-Orozco, J. C.; Restrepo, R. L.; Mora-Ramos, M. E.; Duque, C. A.; Sökmen, I.

2017-03-01

In this study, the effects of electric and magnetic fields on the optical rectification and second and third harmonic generation in asymmetric double quantum well under the intense non-resonant laser field is theoretically investigated. We calculate the optical rectification and second and third harmonic generation within the compact density-matrix approach. The theoretical findings show that the influence of electric, magnetic, and intense laser fields leads to significant changes in the coefficients of nonlinear optical rectification, second and third harmonic generation.

Synthesis, growth, structural and optical studies of a new organic three dimensional framework: 4-(aminocarbonyl)pyridine 4-(aminocarbonyl)pyridinium hydrogen L-malate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vijayalakshmi, A.; Vidyavathy, B., E-mail: vidyavathybalraj@gmail.com; Peramaiyan, G.

2017-02-15

4-(aminocarbonyl)pyridine 4-(aminocarbonyl)pyridinium hydrogen L-malate [(4ACP)(4ACP).(LM)] a new organic nonlinear optical (NLO) crystal was grown by the slow evaporation method. Single crystal X-ray diffraction analysis revealed that the [(4ACP)(4ACP).(LM)] crystal belongs to monoclinic crystal system, space group P2{sub 1}/n, with a three dimensional network. Thermogravimetry (TG) and differential thermal (DT) analyses showed that [(4ACP)(4ACP).(LM)] is thermally stable up to 165 °C. The optical transmittance window and the lower cut-off wavelength of [(4ACP)(4ACP).(LM)] were found out by UV–vis–NIR spectral study. The molecular structure of [(4ACP)(4ACP).(LM)] was further confirmed by FTIR spectral studies. The relative dielectric permittivity and dielectric loss were determined asmore » function of frequency and temperature. The third order nonlinear optical property of [(4ACP)(4ACP).(LM)] was studied by the Z-scan technique using a 532 nm diode pumped CW Nd:YAG laser. Nonlinear refractive index, nonlinear absorption coefficient and third order nonlinear susceptibility of the grown crystal were found to be 7.38×10{sup −8} cm{sup 2}/W, 0.08×10{sup −4} cm/W and 5.36×10{sup −6} esu, respectively. The laser damage threshold value is found to be 1.75 GW/cm{sup 2} - Graphical abstract: In the crystal structure of the title complex, the asymmetric unit contains one hydrogen L-malate anion, 4-(aminocarbonyl)pyridinium cation and a neutral isonicotinamide molecule. It is stabilized by intermolecular N-H…O, C-H…O and O-H…O hydrogen bonds which generate a three dimensional network.« less

Influence of bis-thiourea nickel nitrate on the structural, optical, electrical, thermal and mechanical behavior of a KDP single crystal for NLO applications

NASA Astrophysics Data System (ADS)

Rasal, Y. B.; Shaikh, R. N.; Shirsat, M. D.; Kalainathan, S.; Hussaini, S. S.

2017-03-01

A single crystal of bis-thiourea nickel nitrate (BTNN) doped potassium dihydrogen phosphate (KDP) has been grown from solution at room temperature by a slow evaporation technique. The cell parameters of the grown crystals were determined using single crystal x-ray diffraction analysis. The different functional groups of the grown crystal were confirmed using Fourier transform infrared analysis. The improved optical parameters of the grown crystal have been evaluated in the range of 200-900 nm using UV-visible spectral analysis. The grown crystal was transparent in the entire visible region and the band gap value was found to be 4.96 eV. The influence of BTNN on the third order nonlinear optical properties of KDP crystal has been investigated by means of the Z-scan technique. The second harmonic generation (SHG) efficiency of grown crystal measured using a Nd-YAG laser is 1.98 times higher than that of pure KDP. The third order nonlinear optical susceptibility (χ 3) and nonlinear absorption coefficient (β) of BTNN doped KDP crystal is found to be 1.77  ×  10-5 esu and 5.57  ×  10-6 cm W-1 respectively. The laser damage threshold (LDT) energy for the grown crystal has been measured by using a Q-switched Nd:YAG laser source. The bis-thiourea nickel nitrate shows authoritative impact on the dielectric properties of doped crystal. The influence of bis-thiourea nickel nitrate on the mechanical behavior of KDP crystal has been investigated using Vickers microhardness intender. The thermal behavior of BTNN doped KDP crystal has been analyzed by TGA/DTA analysis.

Strong anharmonicity in the phonon spectra of PbTe and SnTe from first principles

NASA Astrophysics Data System (ADS)

Ribeiro, Guilherme A. S.; Paulatto, Lorenzo; Bianco, Raffaello; Errea, Ion; Mauri, Francesco; Calandra, Matteo

2018-01-01

At room temperature, PbTe and SnTe are efficient thermoelectrics with a cubic structure. At low temperature, SnTe undergoes a ferroelectric transition with a critical temperature strongly dependent on the hole concentration, while PbTe is an incipient ferroelectric. By using the stochastic self-consistent harmonic approximation, we investigate the anharmonic phonon spectra and the occurrence of a ferroelectric transition in both systems. We find that vibrational spectra strongly depend on the approximation used for the exchange-correlation kernel in density-functional theory. If gradient corrections and the theoretical volume are employed, then the calculation of the phonon frequencies as obtained from the diagonalization of the free-energy Hessian leads to phonon spectra in good agreement with experimental data for both systems. In PbTe we evaluate the linear thermal expansion coefficient γ =2.3 ×10-5K-1 , finding it to be in good agreement with experimental value of γ =2.04 ×10-5K-1 . Furthermore, we study the phonon spectrum and we do reproduce the transverse optical mode phonon satellite detected in inelastic neutron scattering and the crossing between the transverse optical and the longitudinal acoustic modes along the Γ X direction. The phonon satellite becomes broader at high temperatures but its energy is essentially temperature independent, in agreement with experiments. We decompose the self-consistent harmonic free energy in second-, third-, and fourth-order anharmonic terms. We find that the third- and fourth-order terms are small. However, treating the third-order term perturbatively on top of the second-order self-consistent harmonic free energy overestimates the energy of the satellite associated with the transverse optical mode. On the contrary, a perturbative treatment on top of the harmonic Hamiltonian breaks down and leads to imaginary phonon frequencies already at 300 K. In the case of SnTe, we describe the occurrence of a ferroelectric transition from the high-temperature F m 3 ¯m structure to the low-temperature R 3 m one. The transition temperature is, however, underestimated with respect to the experimental one. No satellites are present in the SnTe phonon spectra despite a not negligible anharmonic broadening of the zone-center TO mode.

Linear and Nonlinear Optical Properties of Spherical Quantum Dots: Effects of Hydrogenic Impurity and Conduction Band Non-Parabolicity

NASA Astrophysics Data System (ADS)

Rezaei, G.; Vaseghi, B.; Doostimotlagh, N. A.

2012-03-01

Simultaneous effects of an on-center hydrogenic impurity and band edge non-parabolicity on intersubband optical absorption coefficients and refractive index changes of a typical GaAs/AlxGa1-x As spherical quantum dot are theoretically investigated, using the Luttinger—Kohn effective mass equation. So, electronic structure and optical properties of the system are studied by means of the matrix diagonalization technique and compact density matrix approach, respectively. Finally, effects of an impurity, band edge non-parabolicity, incident light intensity and the dot size on the linear, the third-order nonlinear and the total optical absorption coefficients and refractive index changes are investigated. Our results indicate that, the magnitudes of these optical quantities increase and their peaks shift to higher energies as the influences of the impurity and the band edge non-parabolicity are considered. Moreover, incident light intensity and the dot size have considerable effects on the optical absorption coefficients and refractive index changes.

Diffraction-limited imaging with very large telescopes; Proceedings of the NATO Advanced Study Institute, Cargese, France, Sept. 13-23, 1988

NASA Astrophysics Data System (ADS)

Alloin, D. M.; Mariotti, J.-M.

Recent advances in optics and observation techniques for very large astronomical telescopes are discussed in reviews and reports. Topics addressed include Fourier optics and coherence, optical propagation and image formation through a turbulent atmosphere, radio telescopes, continuously deformable telescopes for optical interferometry (I), amplitude estimation from speckle I, noise calibration of speckle imagery, and amplitude estimation from diluted-array I. Consideration is given to first-order imaging methods, speckle imaging with the PAPA detector and the Knox-Thompson algorithm, phase-closure imaging, real-time wavefront sensing and adaptive optics, differential I, astrophysical programs for high-angular-resolution optical I, cophasing telescope arrays, aperture synthesis for space observatories, and lunar occultations for marcsec resolution.

Azimuthally anisotropic emission of low-momentum direct photons in Au + Au collisions at √{sN N}=200 GeV

NASA Astrophysics Data System (ADS)

Adare, A.; Afanasiev, S.; Aidala, C.; Ajitanand, N. N.; Akiba, Y.; Akimoto, R.; Al-Bataineh, H.; Alexander, J.; Alfred, M.; Al-Ta'Ani, H.; Angerami, A.; Aoki, K.; Apadula, N.; Aramaki, Y.; Asano, H.; Aschenauer, E. C.; Atomssa, E. T.; Averbeck, R.; Awes, T. C.; Azmoun, B.; Babintsev, V.; Bai, M.; Baksay, G.; Baksay, L.; Bandara, N. S.; Bannier, B.; Barish, K. N.; Bassalleck, B.; Basye, A. T.; Bathe, S.; Baublis, V.; Baumann, C.; Baumgart, S.; Bazilevsky, A.; Beaumier, M.; Beckman, S.; Belikov, S.; Belmont, R.; Bennett, R.; Berdnikov, A.; Berdnikov, Y.; Bickley, A. A.; Blau, D. S.; Bok, J. S.; Boyle, K.; Brooks, M. L.; Bryslawskyj, J.; Buesching, H.; Bumazhnov, V.; Bunce, G.; Butsyk, S.; Camacho, C. M.; Campbell, S.; Castera, P.; Chen, C.-H.; Chi, C. Y.; Chiu, M.; Choi, I. J.; Choi, J. B.; Choi, S.; Choudhury, R. K.; Christiansen, P.; Chujo, T.; Chung, P.; Chvala, O.; Cianciolo, V.; Citron, Z.; Cole, B. A.; Connors, M.; Constantin, P.; Csanád, M.; Csörgő, T.; Dahms, T.; Dairaku, S.; Danchev, I.; Danley, T. W.; Das, K.; Datta, A.; Daugherity, M. S.; David, G.; Deblasio, K.; Dehmelt, K.; Denisov, A.; Deshpande, A.; Desmond, E. J.; Dharmawardane, K. V.; Dietzsch, O.; Ding, L.; Dion, A.; Diss, P. B.; Do, J. H.; Donadelli, M.; D'Orazio, L.; Drapier, O.; Drees, A.; Drees, K. A.; Durham, J. M.; Durum, A.; Dutta, D.; Edwards, S.; Efremenko, Y. V.; Ellinghaus, F.; Engelmore, T.; Enokizono, A.; En'yo, H.; Esumi, S.; Eyser, K. O.; Fadem, B.; Feege, N.; Fields, D. E.; Finger, M.; Finger, M.; Fleuret, F.; Fokin, S. L.; Fraenkel, Z.; Frantz, J. E.; Franz, A.; Frawley, A. D.; Fujiwara, K.; Fukao, Y.; Fusayasu, T.; Gainey, K.; Gal, C.; Gallus, P.; Garg, P.; Garishvili, A.; Garishvili, I.; Ge, H.; Giordano, F.; Glenn, A.; Gong, H.; Gong, X.; Gonin, M.; Goto, Y.; Granier de Cassagnac, R.; Grau, N.; Greene, S. V.; Grosse Perdekamp, M.; Gunji, T.; Guo, L.; Gustafsson, H.-Å.; Hachiya, T.; Haggerty, J. S.; Hahn, K. I.; Hamagaki, H.; Hamblen, J.; Hamilton, H. F.; Han, R.; Han, S. Y.; Hanks, J.; Hartouni, E. P.; Hasegawa, S.; Haseler, T. O. S.; Hashimoto, K.; Haslum, E.; Hayano, R.; He, X.; Heffner, M.; Hemmick, T. K.; Hester, T.; Hill, J. C.; Hohlmann, M.; Hollis, R. S.; Holzmann, W.; Homma, K.; Hong, B.; Horaguchi, T.; Hori, Y.; Hornback, D.; Hoshino, T.; Hotvedt, N.; Huang, J.; Huang, S.; Ichihara, T.; Ichimiya, R.; Ide, J.; Iinuma, H.; Ikeda, Y.; Imai, K.; Imrek, J.; Inaba, M.; Iordanova, A.; Isenhower, D.; Ishihara, M.; Isobe, T.; Issah, M.; Isupov, A.; Ivanishchev, D.; Jacak, B. V.; Javani, M.; Jezghani, M.; Jia, J.; Jiang, X.; Jin, J.; Johnson, B. M.; Joo, K. S.; Jouan, D.; Jumper, D. S.; Kajihara, F.; Kametani, S.; Kamihara, N.; Kamin, J.; Kanda, S.; Kaneti, S.; Kang, B. H.; Kang, J. H.; Kang, J. S.; Kapustinsky, J.; Karatsu, K.; Kasai, M.; Kawall, D.; Kawashima, M.; Kazantsev, A. V.; Kempel, T.; Key, J. A.; Khachatryan, V.; Khanzadeev, A.; Kijima, K. M.; Kim, B. I.; Kim, C.; Kim, D. H.; Kim, D. J.; Kim, E.; Kim, E.-J.; Kim, G. W.; Kim, H. J.; Kim, K.-B.; Kim, M.; Kim, S. H.; Kim, Y.-J.; Kim, Y. K.; Kimelman, B.; Kinney, E.; Kiriluk, K.; Kiss, Á.; Kistenev, E.; Kitamura, R.; Klatsky, J.; Kleinjan, D.; Kline, P.; Koblesky, T.; Kochenda, L.; Komatsu, Y.; Komkov, B.; Konno, M.; Koster, J.; Kotchetkov, D.; Kotov, D.; Kozlov, A.; Král, A.; Kravitz, A.; Krizek, F.; Kunde, G. J.; Kurita, K.; Kurosawa, M.; Kwon, Y.; Kyle, G. S.; Lacey, R.; Lai, Y. S.; Lajoie, J. G.; Lebedev, A.; Lee, B.; Lee, D. M.; Lee, J.; Lee, K.; Lee, K. B.; Lee, K. S.; Lee, S.; Lee, S. H.; Lee, S. R.; Leitch, M. J.; Leite, M. A. L.; Leitgab, M.; Leitner, E.; Lenzi, B.; Lewis, B.; Li, X.; Liebing, P.; Lim, S. H.; Linden Levy, L. A.; Liška, T.; Litvinenko, A.; Liu, H.; Liu, M. X.; Love, B.; Luechtenborg, R.; Lynch, D.; Maguire, C. F.; Makdisi, Y. I.; Makek, M.; Malakhov, A.; Malik, M. D.; Manion, A.; Manko, V. I.; Mannel, E.; Mao, Y.; Masui, H.; Masumoto, S.; Matathias, F.; McCumber, M.; McGaughey, P. L.; McGlinchey, D.; McKinney, C.; Means, N.; Meles, A.; Mendoza, M.; Meredith, B.; Miake, Y.; Mibe, T.; Mignerey, A. C.; Mikeš, P.; Miki, K.; Milov, A.; Mishra, D. K.; Mishra, M.; Mitchell, J. T.; Miyachi, Y.; Miyasaka, S.; Mizuno, S.; Mohanty, A. K.; Mohapatra, S.; Montuenga, P.; Moon, H. J.; Moon, T.; Morino, Y.; Morreale, A.; Morrison, D. P.; Motschwiller, S.; Moukhanova, T. V.; Murakami, T.; Murata, J.; Mwai, A.; Nagae, T.; Nagamiya, S.; Nagashima, K.; Nagle, J. L.; Naglis, M.; Nagy, M. I.; Nakagawa, I.; Nakagomi, H.; Nakamiya, Y.; Nakamura, K. R.; Nakamura, T.; Nakano, K.; Nattrass, C.; Nederlof, A.; Netrakanti, P. K.; Newby, J.; Nguyen, M.; Nihashi, M.; Niida, T.; Nishimura, S.; Nouicer, R.; Novák, T.; Novitzky, N.; Nyanin, A. S.; O'Brien, E.; Oda, S. X.; Ogilvie, C. A.; Oka, M.; Okada, K.; Onuki, Y.; Orjuela Koop, J. D.; Osborn, J. D.; Oskarsson, A.; Ouchida, M.; Ozawa, K.; Pak, R.; Pantuev, V.; Papavassiliou, V.; Park, B. H.; Park, I. H.; Park, J.; Park, J. S.; Park, S.; Park, S. K.; Park, W. J.; Pate, S. F.; Patel, L.; Patel, M.; Pei, H.; Peng, J.-C.; Pereira, H.; Perepelitsa, D. V.; Perera, G. D. N.; Peresedov, V.; Peressounko, D. Yu.; Perry, J.; Petti, R.; Pinkenburg, C.; Pinson, R.; Pisani, R. P.; Proissl, M.; Purschke, M. L.; Purwar, A. K.; Qu, H.; Rak, J.; Rakotozafindrabe, A.; Ramson, B. J.; Ravinovich, I.; Read, K. F.; Reygers, K.; Reynolds, D.; Riabov, V.; Riabov, Y.; Richardson, E.; Rinn, T.; Roach, D.; Roche, G.; Rolnick, S. D.; Rosati, M.; Rosen, C. A.; Rosendahl, S. S. E.; Rosnet, P.; Rowan, Z.; Rubin, J. G.; Rukoyatkin, P.; Ružička, P.; Sahlmueller, B.; Saito, N.; Sakaguchi, T.; Sakashita, K.; Sako, H.; Samsonov, V.; Sano, M.; Sano, S.; Sarsour, M.; Sato, S.; Sato, T.; Sawada, S.; Schaefer, B.; Schmoll, B. K.; Sedgwick, K.; Seele, J.; Seidl, R.; Semenov, A. Yu.; Sen, A.; Seto, R.; Sett, P.; Sexton, A.; Sharma, D.; Shein, I.; Shibata, T.-A.; Shigaki, K.; Shimomura, M.; Shoji, K.; Shukla, P.; Sickles, A.; Silva, C. L.; Silvermyr, D.; Silvestre, C.; Sim, K. S.; Singh, B. K.; Singh, C. P.; Singh, V.; Slunečka, M.; Snowball, M.; Soltz, R. A.; Sondheim, W. E.; Sorensen, S. P.; Sourikova, I. V.; Sparks, N. A.; Stankus, P. W.; Stenlund, E.; Stepanov, M.; Ster, A.; Stoll, S. P.; Sugitate, T.; Sukhanov, A.; Sumita, T.; Sun, J.; Sziklai, J.; Takagui, E. M.; Takahara, A.; Taketani, A.; Tanabe, R.; Tanaka, Y.; Taneja, S.; Tanida, K.; Tannenbaum, M. J.; Tarafdar, S.; Taranenko, A.; Tarján, P.; Tennant, E.; Themann, H.; Thomas, T. L.; Tieulent, R.; Timilsina, A.; Todoroki, T.; Togawa, M.; Toia, A.; Tomášek, L.; Tomášek, M.; Torii, H.; Towell, C. L.; Towell, R.; Towell, R. S.; Tserruya, I.; Tsuchimoto, Y.; Tsuji, T.; Vale, C.; Valle, H.; van Hecke, H. W.; Vargyas, M.; Vazquez-Zambrano, E.; Veicht, A.; Velkovska, J.; Vértesi, R.; Vinogradov, A. A.; Virius, M.; Vossen, A.; Vrba, V.; Vznuzdaev, E.; Wang, X. R.; Watanabe, D.; Watanabe, K.; Watanabe, Y.; Watanabe, Y. S.; Wei, F.; Wei, R.; Wessels, J.; White, A. S.; White, S. N.; Winter, D.; Wolin, S.; Wood, J. P.; Woody, C. L.; Wright, R. M.; Wysocki, M.; Xia, B.; Xie, W.; Xue, L.; Yalcin, S.; Yamaguchi, Y. L.; Yamaura, K.; Yang, R.; Yanovich, A.; Ying, J.; Yokkaichi, S.; Yoo, J. H.; Yoon, I.; You, Z.; Young, G. R.; Younus, I.; Yu, H.; Yushmanov, I. E.; Zajc, W. A.; Zelenski, A.; Zhang, C.; Zhou, S.; Zolin, L.; Zou, L.; Phenix Collaboration

2016-12-01

The PHENIX experiment at the BNL Relativistic Heavy Ion Collider has measured second- and third-order Fourier coefficients of the azimuthal distributions of direct photons emitted at midrapidity in Au +Au collisions at √{sNN}=200 GeV for various collision centralities. Combining two different analysis techniques, results were obtained in the transverse momentum range of 0.4

Nonlinear propagation analysis of few-optical-cycle pulses for subfemtosecond compression and carrier envelope phase effect

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mizuta, Yo; Nagasawa, Minoru; Ohtani, Morimasa

2005-12-15

A numerical approach called Fourier direct method (FDM) is applied to nonlinear propagation of optical pulses with the central wavelength 800 nm, the width 2.67-12.00 fs, and the peak power 25-6870 kW in a fused-silica fiber. Bidirectional propagation, delayed Raman response, nonlinear dispersion (self-steepening, core dispersion), as well as correct linear dispersion are incorporated into 'bidirectional propagation equations' which are derived directly from Maxwell's equations. These equations are solved for forward and backward waves, instead of the electric-field envelope as in the nonlinear Schroedinger equation (NLSE). They are integrated as multidimensional simultaneous evolution equations evolved in space. We investigate, bothmore » theoretically and numerically, the validity and the limitation of assumptions and approximations used for deriving the NLSE. Also, the accuracy and the efficiency of the FDM are compared quantitatively with those of the finite-difference time-domain numerical approach. The time-domain size 500 fs and the number of grid points in time 2048 are chosen to investigate numerically intensity spectra, spectral phases, and temporal electric-field profiles up to the propagation distance 1.0 mm. On the intensity spectrum of a few-optical-cycle pulses, the self-steepening, core dispersion, and the delayed Raman response appear as dominant, middle, and slight effects, respectively. The delayed Raman response and the core dispersion reduce the effective nonlinearity. Correct linear dispersion is important since it affects the intensity spectrum sensitively. For the compression of femtosecond optical pulses by the complete phase compensation, the shortness and the pulse quality of compressed pulses are remarkably improved by the intense initial peak power rather than by the short initial pulse width or by the propagation distance longer than 0.1 mm. They will be compressed as short as 0.3 fs below the damage threshold of fused-silica fiber 6 MW. It is demonstrated that the carrier envelope phase (CEP) causes the difference on the temporal electric-field profile and the intensity spectrum for the initial peak power of the order of megawatts. At the propagation distance longer than the coherence length for third-order harmonics, the difference grows in the spectral components around the third-order and higher-order harmonics. The CEP can be a sensitive marker to monitor the evolution of nonlinear optical process by a few-optical-cycle electric-field wave-packet source.« less

Stability analysis solutions and optical solitons in extended nonlinear Schrödinger equation with higher-order odd and even terms

NASA Astrophysics Data System (ADS)

Peng, Wei-Qi; Tian, Shou-Fu; Zou, Li; Zhang, Tian-Tian

2018-01-01

In this paper, the extended nonlinear Schrödinger equation with higher-order odd (third order) and even (fourth order) terms is investigated, whose particular cases are the Hirota equation, the Sasa-Satsuma equation and Lakshmanan-Porsezian-Daniel equation by selecting some specific values on the parameters of higher-order terms. We first study the stability analysis of the equation. Then, using the ansatz method, we derive its bright, dark solitons and some constraint conditions which can guarantee the existence of solitons. Moreover, the Ricatti equation extension method is employed to derive some exact singular solutions. The outstanding characteristics of these solitons are analyzed via several diverting graphics.

Automatically assessing properties of dynamic cameras for camera selection and rapid deployment of video content analysis tasks in large-scale ad-hoc networks

NASA Astrophysics Data System (ADS)

den Hollander, Richard J. M.; Bouma, Henri; van Rest, Jeroen H. C.; ten Hove, Johan-Martijn; ter Haar, Frank B.; Burghouts, Gertjan J.

2017-10-01

Video analytics is essential for managing large quantities of raw data that are produced by video surveillance systems (VSS) for the prevention, repression and investigation of crime and terrorism. Analytics is highly sensitive to changes in the scene, and for changes in the optical chain so a VSS with analytics needs careful configuration and prompt maintenance to avoid false alarms. However, there is a trend from static VSS consisting of fixed CCTV cameras towards more dynamic VSS deployments over public/private multi-organization networks, consisting of a wider variety of visual sensors, including pan-tilt-zoom (PTZ) cameras, body-worn cameras and cameras on moving platforms. This trend will lead to more dynamic scenes and more frequent changes in the optical chain, creating structural problems for analytics. If these problems are not adequately addressed, analytics will not be able to continue to meet end users' developing needs. In this paper, we present a three-part solution for managing the performance of complex analytics deployments. The first part is a register containing meta data describing relevant properties of the optical chain, such as intrinsic and extrinsic calibration, and parameters of the scene such as lighting conditions or measures for scene complexity (e.g. number of people). A second part frequently assesses these parameters in the deployed VSS, stores changes in the register, and signals relevant changes in the setup to the VSS administrator. A third part uses the information in the register to dynamically configure analytics tasks based on VSS operator input. In order to support the feasibility of this solution, we give an overview of related state-of-the-art technologies for autocalibration (self-calibration), scene recognition and lighting estimation in relation to person detection. The presented solution allows for rapid and robust deployment of Video Content Analysis (VCA) tasks in large scale ad-hoc networks.

Rogue waves for a discrete (2+1)-dimensional Ablowitz-Ladik equation in the nonlinear optics and Bose-Einstein condensation

NASA Astrophysics Data System (ADS)

Wu, Xiao-Yu; Tian, Bo; Chai, Han-Peng; Du, Zhong

2018-03-01

Under investigation in this paper is a discrete (2+1)-dimensional Ablowitz-Ladik equation, which is used to model the nonlinear waves in the nonlinear optics and Bose-Einstein condensation. Employing the Kadomtsev-Petviashvili hierarchy reduction, we obtain the rogue wave solutions in terms of the Gramian. We graphically study the first-, second- and third-order rogue waves with the influence of the focusing coefficient and coupling strength. When the value of the focusing coefficient increases, both the peak of the rogue wave and background decrease. When the value of the coupling strength increases, the rogue wave raises and decays in a shorter time. High-order rogue waves are exhibited as one single highest peak and some lower humps, and such lower humps are shown as the triangular and circular patterns.

Investigation of local strain distribution and linear electro-optic effect in strained silicon waveguides.

PubMed

Chmielak, Bartos; Matheisen, Christopher; Ripperda, Christian; Bolten, Jens; Wahlbrink, Thorsten; Waldow, Michael; Kurz, Heinrich

2013-10-21

We present detailed investigations of the local strain distribution and the induced second-order optical nonlinearity within strained silicon waveguides cladded with a Si₃N₄ strain layer. Micro-Raman Spectroscopy mappings and electro-optic characterization of waveguides with varying width w(WG) show that strain gradients in the waveguide core and the effective second-order susceptibility χ(2)(yyz) increase with reduced w(WG). For 300 nm wide waveguides a mean effective χ(2)(yyz) of 190 pm/V is achieved, which is the highest value reported for silicon so far. To gain more insight into the origin of the extraordinary large optical second-order nonlinearity of strained silicon waveguides numerical simulations of edge induced strain gradients in these structures are presented and discussed.

Subtropical Cirrus Properties Derived from GSFC Scanning Raman Lidar Measurements during CAMEX 3

NASA Technical Reports Server (NTRS)

Whiteman, D. N.; Wang, Z.; Demoz, B.

2004-01-01

The NASA/GSFC Scanning Raman Lidar (SRL) was stationed on Andros Island, Bahamas for the third Convection and Moisture Experiment (CAMEX 3) held in August - September, 1998 and acquired an extensive set of water vapor and cirrus cloud measurements (Whiteman et al., 2001). The cirrus data studied here have been segmented by generating mechanism. Distinct differences in the optical properties of the clouds are found when the cirrus are hurricane-induced versus thunderstom-induced. Relationships of cirrus cloud optical depth, mean cloud temperature, and layer mean extinction-to-backscatter ratio (S) are presented and compared with mid-latitude and tropical results. Hurricane-induced cirrus clouds are found to generally possess lower values of S than thunderstorm induced clouds. Comparison of these measurements of S are made with other studies revealing at times large differences in the measurements. Given that S is a required parameter for spacebased retrievals of cloud optical depth using backscatter lidar, these large diffaences in S measurements present difficulties for space-based retrievals of cirrus cloud extinction and optical depth.

Effect of the magnetic field on the nonlinear optical rectification and second and third harmonic generation in double δ-doped GaAs quantum wells

NASA Astrophysics Data System (ADS)

Martínez-Orozco, J. C.; Rojas-Briseño, J. G.; Rodríguez-Magdaleno, K. A.; Rodríguez-Vargas, I.; Mora-Ramos, M. E.; Restrepo, R. L.; Ungan, F.; Kasapoglu, E.; Duque, C. A.

2017-11-01

In this paper we are reporting the computation for the Nonlinear Optical Rectification (NOR) and the Second and Third Harmonic Generation (SHG and THG) related with electronic states of asymmetric double Si-δ-doped quantum well in a GaAs matrix when this is subjected to an in-plane (x-oriented) constant magnetic field effect. The work is performed in the effective mass and parabolic band approximations in order to compute the electronic structure for the system by a diagonalization procedure. The expressions for the nonlinear optical susceptibilities, χ0(2), χ2ω(2), and χ3ω(3), are those arising from the compact matrix density formulation and stand for the NOR, SHG, and THG, respectively. This asymmetric double δ-doped quantum well potential profile actually exhibits nonzero NOR, SHG, and THG responses which can be easily controlled by the in-plane (x-direction) externally applied magnetic field. In particular we find that for the chosen configuration the harmonic generation is in the far-infrared/THz region, thus and becoming suitable building blocks for photodetectors in this range of the electromagnetic spectra.

Walk-off reduction, using an external optical plate and Bessel-Gaussian interaction

NASA Astrophysics Data System (ADS)

Masoume, Mansouri; Mohsen, Askarbioki; Saeed Ghavami, Sabouri; Alireza, Khorsandi

2015-02-01

To reduce the walk-off angle of the extraordinary third-harmonic ultraviolet wave at 355 nm generated by type II KTiOPO4 and type I β-BaB2O4 optical crystals, and the Gaussian output beam of a Q-switched Nd:YAG laser, a simple theoretical model was developed based on a rotatable BK7 plate of variable thickness. By rotating the plate up to 35° along the beam direction, we reduced the walk-off angle up to ˜ 13%. The same phenomenon is predicted by the model, confirming the performance of the model. It is found that, due to the walk-off effect, the intensity profile of the third-harmonic generation beam is slightly degraded. To compensate for the observed phenomena and further reduce the walk-off, we used a combination of a convex lens and an axicon to transform the beam profile of the interacting fundamental and second-harmonic generation waves to the zero-order Bessel-Gaussian form. As a result, the walk-off is decreased to ˜48.81 mrad, providing ˜30% relative reduction. By using the same BK7 plate rotated up to 35° along the third-harmonic beam direction, the walk-off angle is further reduced to 38.9 mrad. Moreover, it is observed that the beam profile of the emerged Bessel-Gaussian third-harmonic generation beam remains unchanged with no degradation.

Modeling of a Single-Notch Microfiber Coupler for High-Sensitivity and Low Detection-Limit Refractive Index Sensing.

PubMed

Zhang, Jiali; Shi, Lei; Zhu, Song; Xu, Xinbiao; Zhang, Xinliang

2016-05-11

A highly sensitive refractive index sensor with low detection limit based on an asymmetric optical microfiber coupler is proposed. It is composed of a silica optical microfiber and an As₂Se₃ optical microfiber. Due to the asymmetry of the microfiber materials, a single-notch transmission spectrum is demonstrated by the large refractive index difference between the two optical microfibers. Compared with the symmetric coupler, the bandwidth of the asymmetric structure is over one order of magnitude narrower than that of the former. Therefore, the asymmetric optical microfiber coupler based sensor can reach over one order of magnitude smaller detection limit, which is defined as the minimal detectable refractive index change caused by the surrounding analyte. With the advantage of large evanescent field, the results also show that a sensitivity of up to 3212 nm per refractive index unit with a bandwidth of 12 nm is achieved with the asymmetric optical microfiber coupler. Furthermore, a maximum sensitivity of 4549 nm per refractive index unit can be reached while the radii of the silica optical microfiber and As₂Se₃ optical microfiber are 0.5 μm and a 0.128 μm, respectively. This sensor component may have important potential for low detection-limit physical and biochemical sensing applications.

Efficient Third-Order Distributed Feedback Laser with Enhanced Beam Pattern

NASA Technical Reports Server (NTRS)

Hu, Qing (Inventor); Lee, Alan Wei Min (Inventor); Kao, Tsung-Yu (Inventor)

2015-01-01

A third-order distributed feedback laser has an active medium disposed on a substrate as a linear array of segments having a series of periodically spaced interstices therebetween and a first conductive layer disposed on a surface of the active medium on each of the segments and along a strip from each of the segments to a conductive electrical contact pad for application of current along a path including the active medium. Upon application of a current through the active medium, the active medium functions as an optical waveguide, and there is established an alternating electric field, at a THz frequency, both in the active medium and emerging from the interstices. Spacing of adjacent segments is approximately half of a wavelength of the THz frequency in free space or an odd integral multiple thereof, so that the linear array has a coherence length greater than the length of the linear array.

Backscattering from a Gaussian distributed, perfectly conducting, rough surface

NASA Technical Reports Server (NTRS)

Brown, G. S.

1977-01-01

The problem of scattering by random surfaces possessing many scales of roughness is analyzed. The approach is applicable to bistatic scattering from dielectric surfaces, however, this specific analysis is restricted to backscattering from a perfectly conducting surface in order to more clearly illustrate the method. The surface is assumed to be Gaussian distributed so that the surface height can be split into large and small scale components, relative to the electromagnetic wavelength. A first order perturbation approach is employed wherein the scattering solution for the large scale structure is perturbed by the small scale diffraction effects. The scattering from the large scale structure is treated via geometrical optics techniques. The effect of the large scale surface structure is shown to be equivalent to a convolution in k-space of the height spectrum with the following: the shadowing function, a polarization and surface slope dependent function, and a Gaussian factor resulting from the unperturbed geometrical optics solution. This solution provides a continuous transition between the near normal incidence geometrical optics and wide angle Bragg scattering results.

Nonlinear optics of astaxanthin thin films

NASA Astrophysics Data System (ADS)

Esser, A.; Fisch, Herbert; Haas, Karl-Heinz; Haedicke, E.; Paust, J.; Schrof, Wolfgang; Ticktin, Anton

1993-02-01

Carotinoids exhibit large nonlinear optical properties due to their extended (pi) -electron system. Compared to other polyenes which show a broad distribution of conjugation lengths, carotinoids exhibit a well defined molecular structure, i.e. a well defined conjugation length. Therefore the carotinoid molecules can serve as model compounds to study the relationship between structure and nonlinear optical properties. In this paper the synthesis of four astaxanthins with C-numbers ranging from 30 to 60, their preparation into thin films, wavelength dispersive Third Harmonic Generation (THG) measurements and some molecular modelling calculations will be presented. Resonant (chi) (3) values reach 1.2(DOT)10-10 esu for C60 astaxanthin. In the nonresonant regime a figure of merit (chi) (3)/(alpha) of several 10-13 esu-cm is demonstrated.

Effect of reduction time on third order optical nonlinearity of reduced graphene oxide

NASA Astrophysics Data System (ADS)

Sreeja, V. G.; Vinitha, G.; Reshmi, R.; Anila, E. I.; Jayaraj, M. K.

2017-04-01

We report the influence of reduction time on structural, linear and nonlinear optical properties of reduced graphene oxide (rGO) thin films synthesized by spin coating method. We observed that the structural, linear and nonlinear optical properties can be tuned with reduction time in GO is due to the increased structural ordering because of the restoration of sp2 carbon atoms with the time of reduction. The nonlinear absorption studies by open aperture Z-scan technique exhibited a saturable absorption. The nonlinear refraction studies showed the self de focusing nature of rGO by closed aperture Z scan technique. The nonlinear absorption coefficient and saturation intensity varies with the time for reduction of GO which is attributed to the depletion of valence band and the conduction band filling effect. Our results emphasize duration for reduction of GO dependent optical nonlinearity of rGO thin films to a great extent and explore its applications Q switched mode locking laser systems for generating ultra short laser pulses and in optical sensors. The rGO coated films were characterized by X-Ray diffraction method (XRD), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, UV-Vis absorption spectroscopy (UV-Vis), Photoluminescence (PL) and Scanning electron microscope (SEM) measurements.

Ultrabroadband direct detection of nonclassical photon statistics at telecom wavelength

PubMed Central

Wakui, Kentaro; Eto, Yujiro; Benichi, Hugo; Izumi, Shuro; Yanagida, Tetsufumi; Ema, Kazuhiro; Numata, Takayuki; Fukuda, Daiji; Takeoka, Masahiro; Sasaki, Masahide

2014-01-01

Broadband light sources play essential roles in diverse fields, such as high-capacity optical communications, optical coherence tomography, optical spectroscopy, and spectrograph calibration. Although a nonclassical state from spontaneous parametric down-conversion may serve as a quantum counterpart, its detection and characterization have been a challenging task. Here we demonstrate the direct detection of photon numbers of an ultrabroadband (110 nm FWHM) squeezed state in the telecom band centred at 1535 nm wavelength, using a superconducting transition-edge sensor. The observed photon-number distributions violate Klyshko's criterion for the nonclassicality. From the observed photon-number distribution, we evaluate the second- and third-order correlation functions, and characterize a multimode structure, which implies that several tens of orthonormal modes of squeezing exist in the single optical pulse. Our results and techniques open up a new possibility to generate and characterize frequency-multiplexed nonclassical light sources for quantum info-communications technology. PMID:24694515

Ultrabroadband direct detection of nonclassical photon statistics at telecom wavelength.

PubMed

Wakui, Kentaro; Eto, Yujiro; Benichi, Hugo; Izumi, Shuro; Yanagida, Tetsufumi; Ema, Kazuhiro; Numata, Takayuki; Fukuda, Daiji; Takeoka, Masahiro; Sasaki, Masahide

2014-04-03

Broadband light sources play essential roles in diverse fields, such as high-capacity optical communications, optical coherence tomography, optical spectroscopy, and spectrograph calibration. Although a nonclassical state from spontaneous parametric down-conversion may serve as a quantum counterpart, its detection and characterization have been a challenging task. Here we demonstrate the direct detection of photon numbers of an ultrabroadband (110 nm FWHM) squeezed state in the telecom band centred at 1535 nm wavelength, using a superconducting transition-edge sensor. The observed photon-number distributions violate Klyshko's criterion for the nonclassicality. From the observed photon-number distribution, we evaluate the second- and third-order correlation functions, and characterize a multimode structure, which implies that several tens of orthonormal modes of squeezing exist in the single optical pulse. Our results and techniques open up a new possibility to generate and characterize frequency-multiplexed nonclassical light sources for quantum info-communications technology.

Optical properties of the Tietz-Hua quantum well under the applied external fields

NASA Astrophysics Data System (ADS)

Kasapoglu, E.; Sakiroglu, S.; Ungan, F.; Yesilgul, U.; Duque, C. A.; Sökmen, I.

2017-12-01

In this study, the effects of the electric and magnetic fields as well as structure parameter- γ on the total absorption coefficient, including linear and third order nonlinear absorption coefficients for the optical transitions between any two subband in the Tietz-Hua quantum well have been investigated. The optical transitions were investigated by using the density matrix formalism and the perturbation expansion method. The Tietz-Hua quantum well becomes narrower (wider) when the γ - structure parameter increases (decreases) and so the energies of the bound states will be functions of this parameter. Therefore, we can provide the red or blue shift in the peak position of the absorption coefficient by changing the strength of the electric and magnetic fields as well as the structure parameters and these results can be used to adjust and control the optical properties of the Tietz-Hua quantum well.

Third-order nonlinear optical properties of soluble Cr(III)-dioxolene complexes

NASA Astrophysics Data System (ADS)

Noro, Shin-ichiro; Sassa, Takafumi; Aoyama, Tetsuya; Chang, Ho-Chol; Kitagawa, Susumu; Wada, Tatsuo

2004-10-01

We synthesized novel ligand-based mixed valence (LBMV) CrIII-dioxolene complexes, [Cr(X4SQ)(X4Cat)(4,4'-di-tert-butyl-2,2'-bpy)] (SQ = semiquinone, Cat = catecohol, 2,2'-bpy = 2,2'-bipyridine; X = Cl (2a) and Br (2b)) and [Cr(X4SQ)(X4Cat)(4,4'-dinonyl-2,2'-bpy)] (X = Cl (3a) and Br (3b)), and prepared thin films for investigating their third-order nonlinear optical (NLO) properties in terms of the mixed valence states. Electronic absorption spectra of these complexes in solution and solid states showed an intervalence charge-transfer (IVCT) band from Cat2- to SQ"- at the IR region, indicating of a coexistence of SQ and Cat ligands, namely, LBMV state of the complexes. These complexes were well soluble in nonpolar organic solvent, which allowed us to prepare thin films by spin coating. The obtained films showed the electronic absorption spectra similar to those in solution and were amorphous because of steric hindrance of halogen and alkyl substituents in o-dioxolene and 2,2'-bpy moieties, respectively. The x(3) values of the films of 3a and 3b with a thickness of 30 ~ 40 nm were determined for 1.0 × 10-12 esu at 1.907 μm.

Large-aperture space optical system testing based on the scanning Hartmann.

PubMed

Wei, Haisong; Yan, Feng; Chen, Xindong; Zhang, Hao; Cheng, Qiang; Xue, Donglin; Zeng, Xuefeng; Zhang, Xuejun

2017-03-10

Based on the Hartmann testing principle, this paper proposes a novel image quality testing technology which applies to a large-aperture space optical system. Compared with the traditional testing method through a large-aperture collimator, the scanning Hartmann testing technology has great advantages due to its simple structure, low cost, and ability to perform wavefront measurement of an optical system. The basic testing principle of the scanning Hartmann testing technology, data processing method, and simulation process are presented in this paper. Certain simulation results are also given to verify the feasibility of this technology. Furthermore, a measuring system is developed to conduct a wavefront measurement experiment for a 200 mm aperture optical system. The small deviation (6.3%) of root mean square (RMS) between experimental results and interferometric results indicates that the testing system can measure low-order aberration correctly, which means that the scanning Hartmann testing technology has the ability to test the imaging quality of a large-aperture space optical system.

Crystal growth of triphenylphosphine oxide 4-nitrophenol (TP4N) for nonlinear optical (NLO) applications

NASA Astrophysics Data System (ADS)

Pandian, Muthu Senthil; Karuppasamy, P.; Kamalesh, T.; Ramasamy, P.; Verma, Sunil

2018-04-01

The optically good quality organic single crystals of triphenylphosphine oxide 4-nitrophenol (TP4N) were successfully grown by slow evaporation solution technique (SEST) using methanol as solvent. The lattice parameters of the grown crystal were confirmed by single crystal X-ray diffraction analysis. The optical transmittance, cut-off wavelength and band gap of the TP4N crystal were obtained by UV-Vis NIR spectrum analysis. The photoluminescence studies were carried out to find out the luminesce properties of TP4N single crystal. The photoconductivity studies reveal that the TP4N crystal has negative photoconductive nature. The third order nonlinear susceptibility (χ(3)) of TP4N crystal was evaluated using the Z-scan technique at 640 nm.

Symplectic maps and chromatic optics in particle accelerators

DOE PAGES

Cai, Yunhai

2015-07-06

Here, we have applied the nonlinear map method to comprehensively characterize the chromatic optics in particle accelerators. Our approach is built on the foundation of symplectic transfer maps of magnetic elements. The chromatic lattice parameters can be transported from one element to another by the maps. We also introduce a Jacobian operator that provides an intrinsic linkage between the maps and the matrix with parameter dependence. The link allows us to directly apply the formulation of the linear optics to compute the chromatic lattice parameters. As an illustration, we analyze an alternating-gradient cell with nonlinear sextupoles, octupoles, and decapoles andmore » derive analytically their settings for the local chromatic compensation. Finally, the cell becomes nearly perfect up to the third-order of the momentum deviation.« less

Optical Asymmetry and Nonlinear Light Scattering from Colloidal Gold Nanorods.

PubMed

Lien, Miao-Bin; Kim, Ji-Young; Han, Myung-Geun; Chang, You-Chia; Chang, Yu-Chung; Ferguson, Heather J; Zhu, Yimei; Herzing, Andrew A; Schotland, John C; Kotov, Nicholas A; Norris, Theodore B

2017-06-27

A systematic study is presented of the intensity-dependent nonlinear light scattering spectra of gold nanorods under resonant excitation of the longitudinal surface plasmon resonance (SPR). The spectra exhibit features due to coherent second and third harmonic generation as well as a broadband feature that has been previously attributed to multiphoton photoluminescence arising primarily from interband optical transitions in the gold. A detailed study of the spectral dependence of the scaling of the scattered light with excitation intensity shows unexpected scaling behavior of the coherent signals, which is quantitatively accounted for by optically induced damping of the SPR mode through a Fermi liquid model of the electronic scattering. The broadband feature is shown to arise not from luminescence, but from scattering of the second-order longitudinal SPR mode with the electron gas, where efficient excitation of the second order mode arises from an optical asymmetry of the nanorod. The electronic-temperature-dependent plasmon damping and the Fermi-Dirac distribution together determine the intensity dependence of the broadband emission, and the structure-dependent absorption spectrum determines the spectral shape through the fluctuation-dissipation theorem. Hence a complete self-consistent picture of both coherent and incoherent light scattering is obtained with a single set of physical parameters.

Strong magneto-optical effects in A Cr2O4 (A =Fe,Co ) spinel oxides generated by tetrahedrally coordinated transition metal ions

NASA Astrophysics Data System (ADS)

Kocsis, V.; Bordács, S.; Deisenhofer, J.; Kiss, L. F.; Ohgushi, K.; Kaneko, Y.; Tokura, Y.; Kézsmárki, I.

2018-03-01

Magneto-optical effects have been investigated over the infrared visible spectral range in A Cr2O4 (A =Fe,Co ) spinel oxides with noncollinear spin orders in their ground states. We found large magneto-optical Kerr rotation and ellipticity at the on-site d -d transitions of the A2 + ions located within the charge gap. The magneto-optical Kerr rotation of ϑKerr≈12∘ observed in CoCr2O4 is unprecedentedly large among magnetic semiconductors and points toward the uniqueness of tetrahedrally coordinated Co2 + ions in generating strong magneto-optical response. Criteria of strong magneto-optical effects emerging at on-site d -d transitions of transition metal ions are discussed.

Third US T-G supplier: now or later

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lincicome, R.A.

The Utility Power Corporation (UPC) anticipates that a rush of new orders for turbines and generators will enable it to become the third domestic manufacturer of the large units. A joint venture of Allis-Chalmers and the West German firm Kraftwerk Union (KWU), UPC has waited 18 months without receiving a single order. A manufacturing site was acquired and negotiations with electric utility executives are expected to bring in bids. KWU, while disappointed, confirms its long-term goal of serving American utilities. UPC has revised its original schedule in the face of lagging electrical demand and a variety of economic and sitingmore » constraints, but sees a growing acceptance of large turbine-generators and for foreign technology. UPC will pursue a single-line of responsibility in its marketing strategy. (DCK)« less

fNL‑gNL mixing in the matter density field at higher orders

NASA Astrophysics Data System (ADS)

Gressel, Hedda A.; Bruni, Marco

2018-06-01

In this paper we examine how primordial non-Gaussianity contributes to nonlinear perturbative orders in the expansion of the density field at large scales in the matter dominated era. General Relativity is an intrinsically nonlinear theory, establishing a nonlinear relation between the metric and the density field. Representing the metric perturbations with the curvature perturbation ζ, it is known that nonlinearity produces effective non-Gaussian terms in the nonlinear perturbations of the matter density field δ, even if the primordial ζ is Gaussian. Here we generalise these results to the case of a non-Gaussian primordial ζ. Using a standard parametrization of primordial non-Gaussianity in ζ in terms of fNL, gNL, hNL\\ldots , we show how at higher order (from third and higher) nonlinearity also produces a mixing of these contributions to the density field at large scales, e.g. both fNL and gNL contribute to the third order in δ. This is the main result of this paper. Our analysis is based on the synergy between a gradient expansion (aka long-wavelength approximation) and standard perturbation theory at higher order. In essence, mathematically the equations for the gradient expansion are equivalent to those of first order perturbation theory, thus first-order results convert into gradient expansion results and, vice versa, the gradient expansion can be used to derive results in perturbation theory at higher order and large scales.

Enhanced visible light generation in an active microcavity via third-harmonic conversion beyond the non-depletion approximation

NASA Astrophysics Data System (ADS)

Yu, Rong; Ding, Chunling; Wang, Jiangpeng; Zhang, Duo

2017-12-01

We explore the possibility of using an active doubly resonant microtoroid resonator to produce high-efficiency third-harmonic generation (THG) by exploiting optical third-order nonlinearity. In a microresonator, the active fundamental mode is coherently driven with a continuous-wave input laser at the telecommunication wavelength (1550 nm), and then, the visible THG signal (517 nm) is monitored via an individual bus waveguide. We thoroughly compare our results with those obtained from the conventional passive (i.e., loss) microtoroid resonator by a systematic analysis and detailed numerical simulations based on the Heisenberg-Langevin equations of motion. It is shown that the achievable THG spectrum features an ultralow critical input power. The THG power transmission can be significantly enhanced by about three orders of magnitude at a low input power of 0.1 μ W as compared with the obtained results in the passive microtoroid resonator THG system. Moreover, the THG efficiency can reach up to 100% with optical critical input power as low as a few microwatts. In turn, the analytical expressions of the critical intracavity intensity of the light in the microcavity, the critical input pump power, and the maximum THG efficiency are obtained. The enhanced THG power transmission and high conversion efficiency are attributed to a gain-induced loss compensation in the microtoroid resonator, reducing the effective loss felt by the resonator photons. With state-of-the art technologies in the field of solid-state resonators, including but not limited to microtoroids, the proposed THG scheme is experimentally realizable.

Numerical analysis of a high-order unstructured overset grid method for compressible LES of turbomachinery

NASA Astrophysics Data System (ADS)

de Laborderie, J.; Duchaine, F.; Gicquel, L.; Vermorel, O.; Wang, G.; Moreau, S.

2018-06-01

Large-Eddy Simulation (LES) is recognized as a promising method for high-fidelity flow predictions in turbomachinery applications. The presented approach consists of the coupling of several instances of the same LES unstructured solver through an overset grid method. A high-order interpolation, implemented within this coupling method, is introduced and evaluated on several test cases. It is shown to be third order accurate, to preserve the accuracy of various second and third order convective schemes and to ensure the continuity of diffusive fluxes and subgrid scale tensors even in detrimental interface configurations. In this analysis, three types of spurious waves generated at the interface are identified. They are significantly reduced by the high-order interpolation at the interface. The latter having the same cost as the original lower order method, the high-order overset grid method appears as a promising alternative to be used in all the applications.

Where Does Wood Most Effectively Enhance Storage? Network-Scale Distribution of Sediment and Organic Matter Stored by Instream Wood

NASA Astrophysics Data System (ADS)

Pfeiffer, Andrew; Wohl, Ellen

2018-01-01

We used 48 reach-scale measurements of large wood and wood-associated sediment and coarse particulate organic matter (CPOM) storage within an 80 km2 catchment to examine spatial patterns of storage relative to stream order. Wood, sediment, and CPOM are not distributed uniformly across the drainage basin. Third- and fourth-order streams (23% of total stream length) disproportionately store wood and coarse and fine sediments: 55% of total wood volume, 78% of coarse sediment, and 49% of fine sediment, respectively. Fourth-order streams store 0.8 m3 of coarse sediment and 0.2 m3 of fine sediment per cubic meter of wood. CPOM storage is highest in first-order streams (60% of storage in 47% of total network stream length). First-order streams can store up to 0.3 m3 of CPOM for each cubic meter of wood. Logjams in third- and fourth-order reaches are primary sediment storage agents, whereas roots in small streams may be more important for storage of CPOM. We propose the large wood particulate storage index to quantify average volume of sediment or CPOM stored by a cubic meter of wood.

Fiber-optic annular detector array for large depth of field photoacoustic macroscopy.

PubMed

Bauer-Marschallinger, Johannes; Höllinger, Astrid; Jakoby, Bernhard; Burgholzer, Peter; Berer, Thomas

2017-03-01

We report on a novel imaging system for large depth of field photoacoustic scanning macroscopy. Instead of commonly used piezoelectric transducers, fiber-optic based ultrasound detection is applied. The optical fibers are shaped into rings and mainly receive ultrasonic signals stemming from the ring symmetry axes. Four concentric fiber-optic rings with varying diameters are used in order to increase the image quality. Imaging artifacts, originating from the off-axis sensitivity of the rings, are reduced by coherence weighting. We discuss the working principle of the system and present experimental results on tissue mimicking phantoms. The lateral resolution is estimated to be below 200 μm at a depth of 1.5 cm and below 230 μm at a depth of 4.5 cm. The minimum detectable pressure is in the order of 3 Pa. The introduced method has the potential to provide larger imaging depths than acoustic resolution photoacoustic microscopy and an imaging resolution similar to that of photoacoustic computed tomography.

Nonlinear optical effects in organic microstructures

NASA Astrophysics Data System (ADS)

Novikov, Vladimir B.; Mamonov, Evgeniy A.; Kopylov, Denis A.; Mitetelo, Nikolai V.; Venkatakrishnarao, D.; Narayana, YSLV; Chandrasekar, R.; Murzina, Tatiana V.

2017-05-01

Organic microstructures attract much attention due to their unique properties originating from the design of their shape and optical parameters. In this work we discuss the linear, second- and third-order nonlinear optical effects in arrays and in individual organic microstructures composed by self-assembling technique and formed randomly on top of a solid substrate. The structures under study consist of micro-spheres, -hemispheres or -frustums made of red laser dye and reveal an intense fluorescence (FL) in the visible spectral range. Importantly, that due to a high value of the refractive index and confined geometry, such micro-structures support the excitation of whispering gallery modes (WGM), which brings about strong and spectrally-selected light localization. We show that an amplification of the nonlinear optical effects is observed for these structures as compared to a homogeneous dye film of similar composition. The obtained data are in agreement with the results of the FDTD calculations performed for the structures of different dimensions. Perspectives of application of such type of organic nonlinear microresonators in optical devices are discussed.

Fabrication and Characterization of Thin Film Ion Implanted Composite Materials for Integrated Nonlinear Optical Devices

NASA Technical Reports Server (NTRS)

Sarkisov, S.; Curley, M.; Williams, E. K.; Wilkosz, A.; Ila, D.; Poker, D. B.; Hensley, D. K.; Smith, C.; Banks, C.; Penn, B.;

Design and analysis of large-core single-mode windmill single crystal sapphire optical fiber

DOE PAGES

Cheng, Yujie; Hill, Cary; Liu, Bo; ...

2016-06-01

We present a large-core single-mode “windmill” single crystal sapphire optical fiber (SCSF) design, which exhibits single-mode operation by stripping off the higher-order modes (HOMs) while maintaining the fundamental mode. The “windmill” SCSF design was analyzed using the finite element analysis method, in which all the HOMs are leaky. The numerical simulation results show single-mode operation in the spectral range from 0.4 to 2 μm in the windmill SCSF, with an effective core diameter as large as 14 μm. Such fiber is expected to improve the performance of many of the current sapphire fiber optic sensor structures.

Wavefront Analysis of Adaptive Telescope

NASA Technical Reports Server (NTRS)

Hadaway, James B.; Hillman, Lloyd

1997-01-01

The motivation for this work came from a NASA Headquarters interest in investigating design concepts for a large space telescope employing active optics technology. Current and foreseeable launch vehicles will be limited to carrying around 4-5 meter diameter objects. Thus, if a large, filled-aperture telescope (6-20 meters in diameter) is to be placed in space, it will be required to have a deployable primary mirror. Such a mirror may be an inflatable membrane or a segmented mirror consisting of many smaller pieces. In any case, it is expected that the deployed primary will not be of sufficient quality to achieve diffraction-limited performance for its aperture size. Thus, an active optics system will be needed to correct for initial as well as environmentally-produced primary figure errors. Marshall Space Flight Center has developed considerable expertise in the area of active optics with the PAMELA test-bed. The combination of this experience along with the Marshall optical shop's work in mirror fabrication made MSFC the logical choice to lead NASA's effort to develop active optics technology for large, space-based, astronomical telescopes. Furthermore, UAH's support of MSFC in the areas of optical design, fabrication, and testing of space-based optical systems placed us in a key position to play a major role in the development of this future-generation telescope. A careful study of the active optics components had to be carried out in order to determine control segment size, segment quality, and segment controllability required to achieve diffraction-limited resolution with a given primary mirror. With this in mind, UAH undertook the following effort to provide NASA/MSFC with optical design and analysis support for the large telescope study. All of the work performed under this contract has already been reported, as a team member with MSFC, to NASA Headquarters in a series of presentations given between May and December of 1995. As specified on the delivery order, this report simply summarizes the material with the various UAH-written presentation packages attached as appendices.

Analyses of Third Order Bose-Einstein Correlation by Means of Coulomb Wave Function

DOE Office of Scientific and Technical Information (OSTI.GOV)

Biyajima, Minoru; Mizoguchi, Takuya; Suzuki, Naomichi

2006-04-11

In order to include a correction by the Coulomb interaction in Bose-Einstein correlation (BEC), the wave function for the Coulomb scattering were introduced in the quantum optical approach to BEC in the previous work. If we formulate the amplitude written by Coulomb wave functions according to the diagram for BEC in the plane wave formulation, the formula for 3{pi} -BEC becomes simpler than that of our previous work. We re-analyze the raw data of 3{pi} -BEC by NA44 and STAR Collaborations by this formula. Results are compared with the previous ones.

Image storage in coumarin-based copolymer thin films by photoinduced dimerization.

PubMed

Gindre, Denis; Iliopoulos, Konstantinos; Krupka, Oksana; Champigny, Emilie; Morille, Yohann; Sallé, Marc

2013-11-15

We report a technique to encode grayscale digital images in thin films composed of copolymers containing coumarins. A nonlinear microscopy setup was implemented and two nonlinear optical processes were used to store and read information. A third-order process (two-photon absorption) was used to photoinduce a controlled dimer-to-monomer ratio within a defined tiny volume in the material, which corresponds to each recorded bit of data. Moreover, a second-order process (second-harmonic generation) was used to read the stored information, which has been found to be highly dependent upon the monomer-to-dimer ratio.

Issues to be addressed in the design and fabrication of ultralightweight meter-class optics

NASA Astrophysics Data System (ADS)

Krumweide, Gary C.

1998-08-01

There is a growing need for large aperture, ultralightweight, deployable optics for various science, military and commercial compact satellites. This paper will examine the engineering and manufacturing considerations that must be addressed in order to satisfy the requirements for these sought after optics. In order to limit the scope of this paper, only Graphite Fiber Reinforced/Polymer Matrix Composites (GFR/PMC) will be under consideration because of the potential to satisfy ultralightweight mirror requirements. The requirements associated with specular mirror concepts that Composite Optics, Incorporated (COI) has proposed to Air Force Research Laboratory and NASA Langley Research Center for visible range optics and LIDAR optics, respectively, will also be our interest. Moreover, it is the intent of this paper to illustrate how COI's proposed design/manufacturing concepts for visible and LIDAR optics have evolved based on overcoming, or working around, material constraints and/or undesirable characteristics associated with GFR/PMC.

Optical properties and progressive sterical hindering in pyridinium phenoxides

NASA Astrophysics Data System (ADS)

Boeglin, A.; Barsella, A.; Fort, A.; Mançois, F.; Rodriguez, V.; Diemer, V.; Chaumeil, H.; Defoin, A.; Jacques, P.; Carré, C.

2007-07-01

Pyridinium phenoxides are model compounds associating large dipole moments with high optical nonlinearities. A progression of sterically hindered forms of such zwitterions has been synthesized in order to investigate their structure/property relationships. Their UV-vis absorption in acetonitrile has been analyzed as a function of concentration in order to assess the presence of aggregates and the level of protonation. The quadratic optical properties have been measured by the EFISH and hyper-Rayleigh techniques and are interpreted via semi-empirical calculations. The solvation model used leads to results that agree with our experimental findings indicating an increased response for intermediate twist angles.

Remarkable Second-Order Optical Nonlinearity of Nano-Sized Au Cluster: A TDDFT Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, Kechen; Li, Jun; Lin, Chensheng

2004-04-21

The dipole polarizability, static first hyperpolarizability, and UV-vis spectrum of the recently identified nano-sized tetrahedral cluster of Au have been investigated by using time-dependent density functional response theory. We have discovered that the Au cluster possesses remarkably large molecular second-order optical nonlinearity with the first hyperpolarizabilty (xyz) calculated to be 14.3 x 10 electrostatic unit (esu). The analysis of the low-energy absorption band suggests that the charge transfer from the edged gold atoms to the vertex ones plays the key role in nonlinear optical (NLO) response of Au.

On a third-order shear deformation theory for laminated composite shells

NASA Technical Reports Server (NTRS)

Liu, C. F.; Reddy, J. N.

1986-01-01

A higher-order theory based on an assumed displacement field in which the surface displacements are expanded in powers of the thickness coordinate up to the third order is presented. The theory allows parabolic description of the transverse shear stresses, and therefore the shear correction factors of the usual shear deformation theory are not required in the present theory. The theory also accounts for small strains but moderately large displacements (i.e., von Karman strains). A finite-element model based on independent approximations of the displacements and bending moments (i.e., mixed formulation) is developed. The element is used to analyze cross-ply and angle-ply laminated shells for bending.

Rogue wave generation by inelastic quasi-soliton collisions in optical fibres

NASA Astrophysics Data System (ADS)

Eberhard, M.; Savojardo, A.; Maruta, A.; Römer, R. A.

2017-11-01

We demonstrate a simple cascade mechanism that drives the formation and emergence of rogue waves in the generalized non-linear Schr\\"{o}dinger equation with third-order dispersion. This conceptually novel generation mechanism is based on inelastic collisions of quasi-solitons and is well described by a resonant-like scattering behaviour for the energy transfer in pair-wise quasi-soliton collisions. Our results demonstrate a threshold for rogue wave emergence and the existence of a period of reduced amplitudes - a "calm before the storm" - preceding the arrival of a rogue wave event. Comparing with ultra-long time window simulations of $3.865\\times 10^{6}$ps we observe the statistics of rogue waves in optical fibres with an unprecedented level of detail and accuracy, unambiguously establishing the long-ranged character of the rogue wave power-distribution function over seven orders of magnitude.

Biomolecular Imaging with Coherent Nonlinear Vibrational Microscopy

PubMed Central

Chung, Chao-Yu; Boik, John; Potma, Eric O.

2014-01-01

Optical imaging with spectroscopic vibrational contrast is a label-free solution for visualizing, identifying, and quantifying a wide range of biomolecular compounds in biological materials. Both linear and nonlinear vibrational microscopy techniques derive their imaging contrast from infrared active or Raman allowed molecular transitions, which provide a rich palette for interrogating chemical and structural details of the sample. Yet nonlinear optical methods, which include both second-order sum-frequency generation (SFG) and third-order coherent Raman scattering (CRS) techniques, offer several improved imaging capabilities over their linear precursors. Nonlinear vibrational microscopy features unprecedented vibrational imaging speeds, provides strategies for higher spatial resolution, and gives access to additional molecular parameters. These advances have turned vibrational microscopy into a premier tool for chemically dissecting live cells and tissues. This review discusses the molecular contrast of SFG and CRS microscopy and highlights several of the advanced imaging capabilities that have impacted biological and biomedical research. PMID:23245525

High power continuous-wave titanium:sapphire laser

DOEpatents

Erbert, G.V.; Bass, I.L.; Hackel, R.P.; Jenkins, S.L.; Kanz, V.K.; Paisner, J.A.

1993-09-21

A high-power continuous-wave laser resonator is provided, wherein first, second, third, fourth, fifth and sixth mirrors form a double-Z optical cavity. A first Ti:sapphire rod is disposed between the second and third mirrors and at the mid-point of the length of the optical cavity, and a second Ti:sapphire rod is disposed between the fourth and fifth mirrors at a quarter-length point in the optical cavity. Each Ti:sapphire rod is pumped by two counter-propagating pump beams from a pair of argon-ion lasers. For narrow band operation, a 3-plate birefringent filter and an etalon are disposed in the optical cavity so that the spectral output of the laser consists of 5 adjacent cavity modes. For increased power, seventy and eighth mirrors are disposed between the first and second mirrors to form a triple-Z optical cavity. A third Ti:sapphire rod is disposed between the seventh and eighth mirrors at the other quarter-length point in the optical cavity, and is pumped by two counter-propagating pump beams from a third pair of argon-ion lasers. 5 figures.

Highly linear ring modulator from hybrid silicon and lithium niobate.

PubMed

Chen, Li; Chen, Jiahong; Nagy, Jonathan; Reano, Ronald M

2015-05-18

We present a highly linear ring modulator from the bonding of ion-sliced x-cut lithium niobate onto a silicon ring resonator. The third order intermodulation distortion spurious free dynamic range is measured to be 98.1 dB Hz(2/3) and 87.6 dB Hz(2/3) at 1 GHz and 10 GHz, respectively. The linearity is comparable to a reference lithium niobate Mach-Zehnder interferometer modulator operating at quadrature and over an order of magnitude greater than silicon ring modulators based on plasma dispersion effect. Compact modulators for analog optical links that exploit the second order susceptibility of lithium niobate on the silicon platform are envisioned.

Solid-state reversible quadratic nonlinear optical molecular switch with an exceptionally large contrast.

PubMed

Sun, Zhihua; Luo, Junhua; Zhang, Shuquan; Ji, Chengmin; Zhou, Lei; Li, Shenhui; Deng, Feng; Hong, Maochun

2013-08-14

Exceptional nonlinear optical (NLO) switching behavior, including an extremely large contrast (on/off) of ∼35 and high NLO coefficients, is displayed by a solid-state reversible quadratic NLO switch. The favorable results, induced by very fast molecular motion and anionic ordering, provides impetus for the design of a novel second-harmonic-generation switch involving molecular motion. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

P-REx: The Piston Reconstruction Experiment for infrared interferometry

NASA Astrophysics Data System (ADS)

Widmann, Felix; Pott, Jörg-Uwe; Velasco, Sergio

2018-03-01

For sensitive infrared interferometry, it is crucial to control the differential piston evolution between the used telescopes. This is classically done by the use of a fringe tracker. In this work, we develop a new method to reconstruct the temporal piston variation from the atmosphere, by using real-time data from adaptive optics (AO) wavefront sensing: the Piston Reconstruction Experiment (P-REx). In order to understand the principle performance of the system in a realistic multilayer atmosphere, it is first extensively tested in simulations. The gained insights are then used to apply P-REx to real data, in order to demonstrate the benefit of using P-REx as an auxiliary system in a real interferometer. All tests show positive results, which encourages further research and eventually a real implementation. Especially, the tests on on-sky data showed that the atmosphere is, under decent observing conditions, sufficiently well structured and stable, in order to apply P-REx. It was possible to conveniently reconstruct the piston evolution in two-thirds of the data sets from good observing conditions (r0 ˜ 30 cm). The main conclusion is that applying the piston reconstruction in a real system would reduce the piston variation from around 10 μm down to 1-2 μm over time-scales of up to two seconds. This suggests an application for mid-infrared interferometry, for example for MATISSE at the very large telescope interferometer or the large binocular telescope interferometer. P-REx therefore provides the possibility to improve interferometric measurements without the need for more complex AO systems than already in regular use at 8-m-class telescopes.

Model Hamiltonian Calculations of the Nonlinear Polarizabilities of Conjugated Molecules.

NASA Astrophysics Data System (ADS)

Risser, Steven Michael

This dissertation advances the theoretical knowledge of the nonlinear polarizabilities of conjugated molecules. The unifying feature of these molecules is an extended delocalized pi electron structure. The pi electrons dominate the electronic properties of the molecules, allowing prediction of molecular properties based on the treatment of just the pi electrons. Two separate pi electron Hamiltonians are used in the research. The principal Hamiltonian used is the non-interacting single-particle Huckel Hamiltonian, which replaces the Coulomb interaction among the pi electrons with a mean field interaction. The simplification allows for exact solution of the Hamiltonian for large molecules. The second Hamiltonian used for this research is the interacting multi-particle Pariser-Parr-Pople (PPP) Hamiltonian, which retains explicit Coulomb interactions. This limits exact solutions to molecules containing at most eight electrons. The molecular properties being investigated are the linear polarizability, and the second and third order hyperpolarizabilities. The hyperpolarizabilities determine the nonlinear optical response of materials. These molecular parameters are determined by two independent approaches. The results from the Huckel Hamiltonian are obtained through first, second and third order perturbation theory. The results from the PPP Hamiltonian are obtained by including the applied field directly in the Hamiltonian and determining the ground state energy at a series of field strengths. By fitting the energy to a polynomial in field strength, the polarizability and hyperpolarizabilities are determined. The Huckel Hamiltonian is used to calculate the third order hyperpolarizability of polyenes. These calculations were the first to show the average hyperpolarizability of the polyenes to be positive, and also to show the saturation of the hyperpolarizability. Comparison of these Huckel results to those from the PPP Hamiltonian shows the lack of explicit Coulomb interactions in the Huckel Hamiltonian results in calculated hyperpolarizabilities that are much larger than the experimentally determined values. Comparison of hyperpolarizabilities calculated for small benzene derivatives using both the Huckel and PPP Hamiltonians shows that inclusion of explicit Coulomb interactions is not as significant for aromatic molecules. This assertion is supported by comparison of the calculated results to the experimentally determined values. This allows for predictions of the hyperpolarizability of various liquid crystal molecules to be made.

Use of thermal sieve to allow optical testing of cryogenic optical systems.

PubMed

Kim, Dae Wook; Cai, Wenrui; Burge, James H

2012-05-21

Full aperture testing of large cryogenic optical systems has been impractical due to the difficulty of operating a large collimator at cryogenic temperatures. The Thermal Sieve solves this problem by acting as a thermal barrier between an ambient temperature collimator and the cryogenic system under test. The Thermal Sieve uses a set of thermally controlled baffles with array of holes that are lined up to pass the light from the collimator without degrading the wavefront, while attenuating the thermal background by nearly 4 orders of magnitude. This paper provides the theory behind the Thermal Sieve system, evaluates the optimization for its optical and thermal performance, and presents the design and analysis for a specific system.

Second-order optical effects in several pyrazolo-quinoline derivatives

NASA Astrophysics Data System (ADS)

Makowska-Janusik, M.; Gondek, E.; Kityk, I. V.; Wisła, J.; Sanetra, J.; Danel, A.

2004-11-01

Using optical poling of several pyazolo-quinoline (PAQ) derivatives we have found an existence of sufficiently high second order optical susceptibility at wavelength 1.76 μm varying in the range 0.9-2.8 pm/V. The performed quantum chemical simulations of the UV-absorption for isolated, solvated and incorporated into the polymethacrylate (PMMA) polymer films have shown that the PM3 method is the best among the semi-empirical ones to simulate the optical properties. The calculations of the hyperpolarizabilites have shown a good correlation with experimentally measured susceptibilities obtained from the optical poling. We have found that experimental susceptibility depends on linear molecular polarizability and photoinducing changes of the molecular dipole moment. It is clearly seen for the PAQ4-PAQ6 molecules possessing halogen atoms with relatively large polarizabilities.

Replicated Wolter-I X-ray Optics for Lightweight, High Angular Resolution, Large Collecting Area X-Ray Telescopes

NASA Technical Reports Server (NTRS)

Joy, M.; Bilbro, J.; Elsner, R.; Jones, W.; Kolodziejczak, J.; Petruzzo, J.; ODell, S.; Weisskopf, M.

1997-01-01

The next generation of orbiting x-ray observatories will require high angular resolution telescopes that have an order of magnitude greater collecting area in the 0.1-10 keV spectral region than those currently under construction, but with a much lower weight and cost per unit area. Replicated Wolter-I x-ray optics have the potential to meet this requirement. The currently demonstrated capabilities of replicated Wolter-I optics will be described, and a development plan for creating lightweight, high angular resolution, large effective area x-ray telescopes will be presented.

Kinoform optics applied to X-ray photon correlation spectroscopy.

PubMed

Sandy, A R; Narayanan, S; Sprung, M; Su, J-D; Evans-Lutterodt, K; Isakovic, A F; Stein, A

2010-05-01

Moderate-demagnification higher-order silicon kinoform focusing lenses have been fabricated to facilitate small-angle X-ray photon correlation spectroscopy (XPCS) experiments. The geometric properties of such lenses, their focusing performance and their applicability for XPCS measurements are described. It is concluded that one-dimensional vertical X-ray focusing via silicon kinoform lenses significantly increases the usable coherent flux from third-generation storage-ring light sources for small-angle XPCS experiments.

Flat-field anastigmatic mirror objective for high-magnification extreme ultraviolet microscopy

NASA Astrophysics Data System (ADS)

Toyoda, Mitsunori

2015-08-01

To apply high-definition microscopy to the extreme ultraviolet (EUV) region in practice, i.e. to enable in situ observation of living tissue and the at-wavelength inspection of lithography masks, we constructed a novel reflective objective made of three multilayer mirrors. This objective is configured as a two-stage imaging system made of a Schwarzschild two-mirror system as the primary objective and an additional magnifier with a single curved mirror. This two-stage configuration can provide a high magnification of 1500, which is suitable for real-time observation with an EUV charge coupled device (CCD) camera. Besides, since off-axis aberrations can be corrected by the magnifier, which provides field flattener optics, we are able to configure the objective as a flat-field anastigmatic system, in which we will have a diffraction-limited spatial resolution over a large field-of-view. This paper describes in detail the optical design of the present objective. After calculating the closed-form equations representing the third-order aberrations of the objective, we apply these equations to practical design examples with a numerical aperture of 0.25 and an operation wavelength of 13.5 nm. We also confirm the imaging performances of this novel design by using the numerical ray-tracing method.

High resolution telescope

DOEpatents

Massie, Norbert A.; Oster, Yale

1992-01-01

A large effective-aperture, low-cost optical telescope with diffraction-limited resolution enables ground-based observation of near-earth space objects. The telescope has a non-redundant, thinned-aperture array in a center-mount, single-structure space frame. It employs speckle interferometric imaging to achieve diffraction-limited resolution. The signal-to-noise ratio problem is mitigated by moving the wavelength of operation to the near-IR, and the image is sensed by a Silicon CCD. The steerable, single-structure array presents a constant pupil. The center-mount, radar-like mount enables low-earth orbit space objects to be tracked as well as increases stiffness of the space frame. In the preferred embodiment, the array has elemental telescopes with subaperture of 2.1 m in a circle-of-nine configuration. The telescope array has an effective aperture of 12 m which provides a diffraction-limited resolution of 0.02 arc seconds. Pathlength matching of the telescope array is maintained by an electro-optical system employing laser metrology. Speckle imaging relaxes pathlength matching tolerance by one order of magnitude as compared to phased arrays. Many features of the telescope contribute to substantial reduction in costs. These include eliminating the conventional protective dome and reducing on-site construction activites. The cost of the telescope scales with the first power of the aperture rather than its third power as in conventional telescopes.

Effets non-lineaires de second ordre dans les verres de silice

NASA Astrophysics Data System (ADS)

Godbout, Nicolas

Materials possessing inversion symmetry can not have a non-zero second-order susceptibility tensor. Since silica glasses are amorphous and isotropic, they possess this symmetry and therefore do not exhibit second-order nonlinear optical effects. However, the symmetry can be broken by several processes. The central question of this thesis is the determination of the mechanisms responsible for the second-order susceptibility in silica glasses after thermal poling. The presence of this nonlinearity arises through one of these mechanisms: the orientation of dipolar moieties possessing a second-order hyperpolarisability, or the build-up of a permanent electric field by charge motion which creates an apparent χ(2) through the already present χ (3). The dipole orientation model has a bigger potential of generating high optical nonlinearities than the built-in field model. This conclusion is based on a study of the crystalline structures of silica. The measurement of Maker fringes is the most informative technique for characterization of the optical properties of bulk poled samples. Measurements on Infrasil™ and Suprasil™ samples show an optically active layer of approximately 9 and 23 microns, with χ(2) susceptibilities of approximately 0.07 pm/V and 0.02 pm/V respectively. The analysis of Maker fringes in a similar sample suggests that the sign of the surface and bulk χ (2)-s is different, supporting the built-in field model as the origin of χ(2). Based on the results analyzed in this thesis, the second- order susceptibility of silica glasses after thermal poling results from the creation of a permanent built-in electric field caused by the movement of cations coupled to the pre-existing third-order nonlinearity. This claim is based on: the observed pump polarization dependence of Maker fringes, predictions of a steady-state ion migration model about the resulting optical properties and their confirmation by optical measurements; the presence of a bulk nonlinearity and its apparent opposite sign to the one of the surface; polarization and depolarization currents showing only signs of ion migration. (Abstract shortened by UMI.)

Bright, dark and W-shaped solitons with extended nonlinear Schrödinger's equation for odd and even higher-order terms

NASA Astrophysics Data System (ADS)

Bendahmane, Issam; Triki, Houria; Biswas, Anjan; Saleh Alshomrani, Ali; Zhou, Qin; Moshokoa, Seithuti P.; Belic, Milivoj

2018-02-01

We present solitary wave solutions of an extended nonlinear Schrödinger equation with higher-order odd (third-order) and even (fourth-order) terms by using an ansatz method. The including high-order dispersion terms have significant physical applications in fiber optics, the Heisenberg spin chain, and ocean waves. Exact envelope solutions comprise bright, dark and W-shaped solitary waves, illustrating the potentially rich set of solitary wave solutions of the extended model. Furthermore, we investigate the properties of these solitary waves in nonlinear and dispersive media. Moreover, specific constraints on the system parameters for the existence of these structures are discussed exactly. The results show that the higher-order dispersion and nonlinear effects play a crucial role for the formation and properties of propagating waves.

Plasmonic nanoparticle lithography: Fast resist-free laser technique for large-scale sub-50 nm hole array fabrication

NASA Astrophysics Data System (ADS)

Pan, Zhenying; Yu, Ye Feng; Valuckas, Vytautas; Yap, Sherry L. K.; Vienne, Guillaume G.; Kuznetsov, Arseniy I.

2018-05-01

Cheap large-scale fabrication of ordered nanostructures is important for multiple applications in photonics and biomedicine including optical filters, solar cells, plasmonic biosensors, and DNA sequencing. Existing methods are either expensive or have strict limitations on the feature size and fabrication complexity. Here, we present a laser-based technique, plasmonic nanoparticle lithography, which is capable of rapid fabrication of large-scale arrays of sub-50 nm holes on various substrates. It is based on near-field enhancement and melting induced under ordered arrays of plasmonic nanoparticles, which are brought into contact or in close proximity to a desired material and acting as optical near-field lenses. The nanoparticles are arranged in ordered patterns on a flexible substrate and can be attached and removed from the patterned sample surface. At optimized laser fluence, the nanohole patterning process does not create any observable changes to the nanoparticles and they have been applied multiple times as reusable near-field masks. This resist-free nanolithography technique provides a simple and cheap solution for large-scale nanofabrication.

Azimuthally anisotropic emission of low-momentum direct photons in Au + Au collisions at s N N = 200 GeV

DOE PAGES

Adare, A.; Afanasiev, S.; Aidala, C.; ...

2016-12-06

Inmore » this paper, the PHENIX experiment at the BNL Relativistic Heavy Ion Collider has measured second- and third-order Fourier coefficients of the azimuthal distributions of direct photons emitted at midrapidity in Au + Au collisions at s N N = 200 GeV for various collision centralities. Combining two different analysis techniques, results were obtained in the transverse momentum range of 0.4 < p T < 4.0 GeV/c. At low p T the second-order coefficients, v 2, are similar to the ones observed in hadrons. Third-order coefficients, v 3, are nonzero and almost independent of centrality. These new results on v 2 and v 3, combined with previously published results on yields, are compared to model calculations that provide yields and asymmetries in the same framework. Finally, those models are challenged to explain simultaneously the observed large yield and large azimuthal anisotropies.« less

Electro-Optic Coefficients of Guest-Host Poled Polymers Containing Chromophores with Large First Hyperpolarizabilities: A Test of the Two-State, Oriented-Gas Model

NASA Technical Reports Server (NTRS)

Skindhoj, J.; Bourhill, G.; Gilmour, S.; Tiemann, B.; Mansour, K.; Perry, K.; Heng, L-T.; Marder, S.; Perry, J.

1994-01-01

the electro-optic r33, coefficients of poled poly(methylmethacrylate) films containing dyes with first hyperpolarizabilities that span nearly two orders of magnitude have been determined at 820 and 1300 nm by modulated ellipsometry.

Optical switch

DOEpatents

Reedy, R.P.

1985-01-18

An optical switching device is provided whereby light from a first glass fiber or a second glass fiber may be selectively transmitted into a third glass fiber. Each glass fiber is provided with a focusing and collimating lens system. In one mode of operation, light from the first glass fiber is reflected by a planar mirror into the third glass fiber. In another mode of operation, light from the second glass fiber passes directly into the third glass fiber. The planar mirror is attached to a rotatable table which is rotated to provide the optical switching.

Optical switch

DOEpatents

Reedy, R.P.

1987-11-10

An optical switching device is provided whereby light from a first glass fiber or a second glass fiber may be selectively transmitted into a third glass fiber. Each glass fiber is provided with a focusing and collimating lens system. In one mode of operation, light from the first glass fiber is reflected by a planar mirror into the third glass fiber. In another mode of operation, light from the second glass fiber passes directly into the third glass fiber. The planar mirror is attached to a rotatable table which is rotated to provide the optical switching. 3 figs.

Efficient quantum microwave-to-optical conversion using electro-optic nanophotonic coupled resonators

NASA Astrophysics Data System (ADS)

Soltani, Mohammad; Zhang, Mian; Ryan, Colm; Ribeill, Guilhem J.; Wang, Cheng; Loncar, Marko

2017-10-01

We propose a low-noise, triply resonant, electro-optic (EO) scheme for quantum microwave-to-optical conversion based on coupled nanophotonics resonators integrated with a superconducting qubit. Our optical system features a split resonance—a doublet—with a tunable frequency splitting that matches the microwave resonance frequency of the superconducting qubit. This is in contrast to conventional approaches, where large optical resonators with free-spectral range comparable to the qubit microwave frequency are used. In our system, EO mixing between the optical pump coupled into the low-frequency doublet mode and a resonance microwave photon results in an up-converted optical photon on resonance with high-frequency doublet mode. Importantly, the down-conversion process, which is the source of noise, is suppressed in our scheme as the coupled-resonator system does not support modes at that frequency. Our device has at least an order of magnitude smaller footprint than conventional devices, resulting in large overlap between optical and microwave fields and a large photon conversion rate (g /2 π ) in the range of ˜5 -15 kHz. Owing to a large g factor and doubly resonant nature of our device, microwave-to-optical frequency conversion can be achieved with optical pump powers in the range of tens of microwatts, even with moderate values for optical Q (˜106 ) and microwave Q (˜104 ). The performance metrics of our device, with substantial improvement over the previous EO-based approaches, promise a scalable quantum microwave-to-optical conversion and networking of superconducting processors via optical fiber communication.

Average BER analysis of SCM-based free-space optical systems by considering the effect of IM3 with OSSB signals under turbulence channels.

PubMed

Lim, Wansu; Cho, Tae-Sik; Yun, Changho; Kim, Kiseon

2009-11-09

In this paper, we derive the average bit error rate (BER) of subcarrier multiplexing (SCM)-based free space optics (FSO) systems using a dual-drive Mach-Zehnder modulator (DD-MZM) for optical single-sideband (OSSB) signals under atmospheric turbulence channels. In particular, we consider the third-order intermodulation (IM3), a significant performance degradation factor, in the case of high input signal power systems. The derived average BER, as a function of the input signal power and the scintillation index, is employed to determine the optimum number of SCM users upon the designing FSO systems. For instance, when the user number doubles, the input signal power decreases by almost 2 dBm under the log-normal and exponential turbulence channels at a given average BER.

Molecular structure, second- and third-order nonlinear optical properties and DFT studies of a novel non-centrosymmetric chalcone derivative: (2E)-3-(4-fluorophenyl)-1-(4-{[(1E)-(4-fluorophenyl)methylene]amino}phenyl)prop-2-en-1-one

NASA Astrophysics Data System (ADS)

Maidur, Shivaraj R.; Patil, Parutagouda Shankaragouda; Ekbote, Anusha; Chia, Tze Shyang; Quah, Ching Kheng

2017-09-01

In the present work, the title chalcone, (2E)-3-(4-fluorophenyl)-1-(4-{[(1E)-(4-fluorophenyl) methylene]amino}phenyl)prop-2-en-1-one (abbreviated as FAMFC), was synthesized and structurally characterized by single-crystal X-ray diffraction. The compound is crystallized in the monoclinic system with non-centrosymmetric space group P21 and hence it satisfies the essential condition for materials to exhibit second-order nonlinear optical properties. The molecular structure was further confirmed by using FT-IR and 1H NMR spectroscopic techniques. The title crystal is transparent in the Vis-NIR region and has a direct band gap. The third-order nonlinear optical properties were investigated in solution (0.01 M) by Z-scan technique using a continuous wave (CW) DPSS laser at the wavelength of 532 nm. The title chalcone exhibited significant two-photon absorption (β = 35.8 × 10- 5 cm W- 1), negative nonlinear refraction (n2 = - 0.18 × 10- 8 cm2 W- 1) and optical limiting (OL threshold = 2.73 kJ cm- 2) under the CW regime. In support of the experimental results, a comprehensive theoretical study was carried out on the molecule of FAMFC using density functional theory (DFT). The optimized geometries and frontier molecular orbitals were calculated by employing B3LYP/6-31 + G level of theory. The optimized molecular structure was confirmed computationally by IR vibrational and 1H NMR spectral analysis. The experimental UV-Vis-NIR spectrum was interpreted using computational chemistry under time-dependent DFT. The static and dynamic NLO properties such as dipole moments (μ), polarizability (α), and first hyperpolarizabilities (β) were computed by using finite field method. The obtained dynamic first hyperpolarizability β(- 2ω;ω,ω) at input frequency ω = 0.04282 a.u. is predicted to be 161 times higher than urea standard. The electronic excitation energies and HOMO-LUMO band gap for FAMFC were also evaluated by DFT. The experimental and theoretical results are in good agreement, and the NLO study suggests that FAMFC molecule can be a potential candidate in the nonlinear optical applications.

Molecular structure, second- and third-order nonlinear optical properties and DFT studies of a novel non-centrosymmetric chalcone derivative: (2E)-3-(4-fluorophenyl)-1-(4-{[(1E)-(4-fluorophenyl)methylene]amino}phenyl)prop-2-en-1-one.

PubMed

Maidur, Shivaraj R; Patil, Parutagouda Shankaragouda; Ekbote, Anusha; Chia, Tze Shyang; Quah, Ching Kheng

2017-09-05

In the present work, the title chalcone, (2E)-3-(4-fluorophenyl)-1-(4-{[(1E)-(4-fluorophenyl) methylene]amino}phenyl)prop-2-en-1-one (abbreviated as FAMFC), was synthesized and structurally characterized by single-crystal X-ray diffraction. The compound is crystallized in the monoclinic system with non-centrosymmetric space group P2 1 and hence it satisfies the essential condition for materials to exhibit second-order nonlinear optical properties. The molecular structure was further confirmed by using FT-IR and 1 H NMR spectroscopic techniques. The title crystal is transparent in the Vis-NIR region and has a direct band gap. The third-order nonlinear optical properties were investigated in solution (0.01M) by Z-scan technique using a continuous wave (CW) DPSS laser at the wavelength of 532nm. The title chalcone exhibited significant two-photon absorption (β=35.8×10 -5 cmW -1 ), negative nonlinear refraction (n 2 =-0.18×10 -8 cm 2 W -1 ) and optical limiting (OL threshold=2.73kJcm -2 ) under the CW regime. In support of the experimental results, a comprehensive theoretical study was carried out on the molecule of FAMFC using density functional theory (DFT). The optimized geometries and frontier molecular orbitals were calculated by employing B3LYP/6-31+G level of theory. The optimized molecular structure was confirmed computationally by IR vibrational and 1 H NMR spectral analysis. The experimental UV-Vis-NIR spectrum was interpreted using computational chemistry under time-dependent DFT. The static and dynamic NLO properties such as dipole moments (μ), polarizability (α), and first hyperpolarizabilities (β) were computed by using finite field method. The obtained dynamic first hyperpolarizability β(-2ω;ω,ω) at input frequency ω=0.04282a.u. is predicted to be 161 times higher than urea standard. The electronic excitation energies and HOMO-LUMO band gap for FAMFC were also evaluated by DFT. The experimental and theoretical results are in good agreement, and the NLO study suggests that FAMFC molecule can be a potential candidate in the nonlinear optical applications. Copyright © 2017 Elsevier B.V. All rights reserved.

Miniature mechanical transfer optical coupler

DOEpatents

Abel, Philip [Overland Park, KS; Watterson, Carl [Kansas City, MO

2011-02-15

A miniature mechanical transfer (MT) optical coupler ("MMTOC") for optically connecting a first plurality of optical fibers with at least one other plurality of optical fibers. The MMTOC may comprise a beam splitting element, a plurality of collimating lenses, and a plurality of alignment elements. The MMTOC may optically couple a first plurality of fibers disposed in a plurality of ferrules of a first MT connector with a second plurality of fibers disposed in a plurality of ferrules of a second MT connector and a third plurality of fibers disposed in a plurality of ferrules of a third MT connector. The beam splitting element may allow a portion of each beam of light from the first plurality of fibers to pass through to the second plurality of fibers and simultaneously reflect another portion of each beam of light from the first plurality of fibers to the third plurality of fibers.

LDR structural experiment definition

NASA Technical Reports Server (NTRS)

Russell, R. A.

1988-01-01

A system study to develop the definition of a structural flight experiment for a large precision segmented reflector on the Space Station was accomplished by the Boeing Aerospace Company for NASA's Langley Research Center. The objective of the study was to use a Large Deployable Reflector (LDR) baseline configuration as the basis for focusing an experiment definition, so that the resulting accommodation requirements and interface constraints could be used as part of the mission requirements data base for Space Station. The primary objectives of the first experiment are to construct the primary mirror support truss and to determine its structural and thermal characteristics. Addition of an optical bench, thermal shield and primary mirror segments, and alignment of the optical components, would occur on a second experiment. The structure would then be moved to the payload point system for pointing, optical control, and scientific optical measurement for a third experiment. Experiment 1 will deploy the primary support truss while it is attached to the instrument module structure. The ability to adjust the mirror attachment points and to attach several dummy primary mirror segments with a robotic system will also be demonstrated. Experiment 2 will be achieved by adding new components and equipment to experiment one. Experiment 3 will demonstrate advanced control strategies, active adjustment of the primary mirror alignment, and technologies associated with optical sensing.

Synthesis, characterization and nonlinear optical properties of symmetrically substituted dibenzylideneacetone derivatives

NASA Astrophysics Data System (ADS)

Sunil Kumar Reddy, N.; Badam, Rajashekar; Sattibabu, Romala; Molli, Muralikrishna; Sai Muthukumar, V.; Siva Sankara Sai, S.; Rao, G. Nageswara

2014-11-01

We report here the nonlinear optical (NLO) properties of eight bis-chalcones of D-π-A-π-D type. These dibenzylideneacetone (DBA) derivatives are synthesized by Claisen-Schmidt reaction. The compounds are characterized by UV-vis, FTIR, 1H NMR, 13C NMR, mass spectroscopy and powder XRD. By substituting different groups (electron withdrawing and electron donating) at 'para' and 'meta' positions of the aromatic ring, we observed an enhancement in second harmonic generation with substitution at 'para' position. These compounds have also showed higher two-photon absorption compared to other chalcones reported in literature. These compounds, exhibiting both second and third order NLO effects, are plausible candidate materials in photonic devices.

Thermal, mechanical, optical and dielectric properties of piperazinium hydrogen phosphite monohydrate NLO single crystal

NASA Astrophysics Data System (ADS)

Rajkumar, R.; Praveen Kumar, P.

2018-05-01

Optical transparent crystal of piperazinium hydrogen phosphite monohydrate (PHPM) was grown by slow evaporation method. The grown crystal was characterized by single crystal X-ray diffraction analysis and the crystal belongs to monoclinic system. The functional groups present in PHPM crystal were confirmed by FTIR analysis. UV-Visible spectrum shows that the PHPM crystal is transparent in the visible region. The mechanical behavior of PHPM crystal was characterized by Vickers hardness test. Thermal stability of PHPM crystal was analyzed by thermogravimetric analysis. Dielectric studies were also carried out for the grown crystal. The third-order nonlinear parameters such as nonlinear refractive index and nonlinear absorption coefficient have been calculated using Z scan technique.

Effect of antimony (Sb) addition on the linear and non-linear optical properties of amorphous Ge-Te-Sb thin films

NASA Astrophysics Data System (ADS)

Kumar, P.; Kaur, J.; Tripathi, S. K.; Sharma, I.

2017-12-01

Non-crystalline thin films of Ge20Te80-xSbx (x = 0, 2, 4, 6, 10) systems were deposited on glass substrate using thermal evaporation technique. The optical coefficients were accurately determined by transmission spectra using Swanepoel envelope method in the spectral region of 400-1600 nm. The refractive index was found to increase from 2.38 to 2.62 with the corresponding increase in Sb content over the entire spectral range. The dispersion of refractive index was discussed in terms of the single oscillator Wemple-DiDomenico model. Tauc relation for the allowed indirect transition showed decrease in optical band gap. To explore non-linearity, the spectral dependence of third order susceptibility of a-Ge-Te-Sb thin films was evaluated from change of index of refraction using Miller's rule. Susceptibility values were found to enhance rapidly from 10-13 to 10-12 (esu), with the red shift in the absorption edge. Non-linear refractive index was calculated by Fourier and Snitzer formula. The values were of the order of 10-12 esu. At telecommunication wavelength, these non-linear refractive index values showed three orders higher than that of silica glass. Dielectric constant and optical conductivity were also reported. The prepared Sb doped thin films on glass substrate with observed improved functional properties have a noble prospect in the application of nonlinear optical devices and might be used for a high speed communication fiber. Non-linear parameters showed good agreement with the values given in the literature.

A third-order silicon racetrack add-drop filter with a moderate feature size

NASA Astrophysics Data System (ADS)

Wang, Ying; Zhou, Xin; Chen, Qian; Shao, Yue; Chen, Xiangning; Huang, Qingzhong; Jiang, Wei

2018-01-01

In this work, we design and fabricate a highly compact third-order racetrack add-drop filter consisting of silicon waveguides with modified widths on a silicon-on-insulator (SOI) wafer. Compared to the previous approach that requires an exceedingly narrow coupling gap less than 100nm, we propose a new approach that enlarges the minimum feature size of the whole device to be 300 nm to reduce the process requirement. The three-dimensional finite-difference time-domain (3D-FDTD) method is used for simulation. Experiment results show good agreement with simulation results in property. In the experiment, the filter shows a nearly box-like channel dropping response, which has a large flat 3-dB bandwidth ({3 nm), relatively large FSR ({13.3 nm) and out-of-band rejection larger than 14 dB at the drop port with a footprint of 0.0006 mm2 . The device is small and simple enough to have a wide range of applications in large scale on-chip photonic integration circuits.

Surface plasmon resonance and nonlinear optical behavior of pulsed laser-deposited semitransparent nanostructured copper thin films

NASA Astrophysics Data System (ADS)

Kesarwani, Rahul; Khare, Alika

2018-06-01

In this paper, surface plasmon resonance (SPR) and nonlinear optical properties of semitransparent nanostructured copper thin films fabricated on the glass substrate at 400 °C by pulsed laser deposition technique are reported. The thickness, linear absorption coefficient and linear refractive index of the films were measured by spectroscopic ellipsometer. The average particle size as measured via atomic force microscope was in the range of 12.84-26.02 nm for the deposition time ranging from 5 to 10 min, respectively. X-ray diffraction spectra revealed the formation of Cu (111) and Cu (200) planes. All these thin films exhibited broad SPR peak. The third-order optical nonlinearity of all the samples was investigated via modified z-scan technique using cw laser at a wavelength of 632.8 nm. The open aperture z-scan spectra of Cu thin film deposited for 5 min duration exhibited reverse saturation absorption whereas all the other samples displayed saturation absorption behavior. The nonlinear refractive index coefficient of these films showed a positive sign having the magnitude of the order of 10- 4 cm/W. The real and imaginary parts of susceptibilities were also calculated from the z-scan data and found to be of the order of 10- 6 esu.

Optical birefringence imaging of x-ray excited lithium tantalate

DOE PAGES

Durbin, S. M.; Landcastle, A.; DiChiara, A.; ...

2017-08-04

X-ray absorption in lithium tantalate induces large, long-lived (~10 -5 s) optical birefringence, visualized via scanning optical polarimetry, likely arising from electrooptic coupling to x-ray induced electric fields. Similar birefringence measured from glass, sapphire, and quartz was two orders of magnitude weaker. This suggests that x-ray excited charges preferentially create ordered, aligned dipoles within the noncentrosymmetric unit cell of ferroelectric LiTaO 3, enhancing the electric field compared to more isotropic charge distributions in the other materials. In conclusion, time-resolved measurements show a prompt response on a picosecond time scale, which along with the long decay time suggest novel approaches tomore » optical detection of x-rays using ferroelectric materials.« less

Large-scale frequency- and time-domain quantum entanglement over the optical frequency comb (Conference Presentation)

NASA Astrophysics Data System (ADS)

Pfister, Olivier

2017-05-01

When it comes to practical quantum computing, the two main challenges are circumventing decoherence (devastating quantum errors due to interactions with the environmental bath) and achieving scalability (as many qubits as needed for a real-life, game-changing computation). We show that using, in lieu of qubits, the "qumodes" represented by the resonant fields of the quantum optical frequency comb of an optical parametric oscillator allows one to create bona fide, large scale quantum computing processors, pre-entangled in a cluster state. We detail our recent demonstration of 60-qumode entanglement (out of an estimated 3000) and present an extension to combining this frequency-tagged with time-tagged entanglement, in order to generate an arbitrarily large, universal quantum computing processor.

Swing arm profilometer: high accuracy testing for large reaction-bonded silicon carbide optics with a capacitive probe

NASA Astrophysics Data System (ADS)

Xiong, Ling; Luo, Xiao; Hu, Hai-xiang; Zhang, Zhi-yu; Zhang, Feng; Zheng, Li-gong; Zhang, Xue-jun

2017-08-01

A feasible way to improve the manufacturing efficiency of large reaction-bonded silicon carbide optics is to increase the processing accuracy in the ground stage before polishing, which requires high accuracy metrology. A swing arm profilometer (SAP) has been used to measure large optics during the ground stage. A method has been developed for improving the measurement accuracy of SAP using a capacitive probe and implementing calibrations. The experimental result compared with the interferometer test shows the accuracy of 0.068 μm in root-mean-square (RMS) and maps in 37 low-order Zernike terms show accuracy of 0.048 μm RMS, which shows a powerful capability to provide a major input in high-precision grinding.

Using Polarized Spectroscopy to Investigate Order in Thin-Films of Ionic Self-Assembled Materials Based on Azo-Dyes

PubMed Central

Ahmad, Mariam; Andersen, Frederik; Brend Bech, Ári; Bendixen, H. Krestian L.; Nawrocki, Patrick R.; Bloch, Anders J.; Bora, Ilkay; Bukhari, Tahreem A.; Bærentsen, Nicolai V.; Carstensen, Jens; Chima, Smeeah; Colberg, Helene; Dahm, Rasmus T.; Daniels, Joshua A.; Dinckan, Nermin; El Idrissi, Mohamed; Erlandsen, Ricci; Førster, Marc; Ghauri, Yasmin; Gold, Mikkel; Hansen, Andreas; Hansen, Kenn; Helmsøe-Zinck, Mathias; Henriksen, Mathias; Hoffmann, Sophus V.; Hyllested, Louise O. H.; Jensen, Casper; Kallenbach, Amalie S.; Kaur, Kirandip; Khan, Suheb R.; Kjær, Emil T. S.; Kristiansen, Bjørn; Langvad, Sylvester; Lund, Philip M.; Munk, Chastine F.; Møller, Theis; Nehme, Ola M. Z.; Nejrup, Mathilde Rove; Nexø, Louise; Nielsen, Simon Skødt Holm; Niemeier, Nicolai; Nikolajsen, Lasse V.; Nøhr, Peter C. T.; Skaarup Ovesen, Jacob; Paustian, Lucas; Pedersen, Adam S.; Petersen, Mathias K.; Poulsen, Camilla M.; Praeger-Jahnsen, Louis; Qureshi, L. Sonia; Schiermacher, Louise S.; Simris, Martin B.; Smith, Gorm; Smith, Heidi N.; Sonne, Alexander K.; Zenulovic, Marko R.; Winther Sørensen, Alma; Vogt, Emil; Væring, Andreas; Westermann, Jonas; Özcan, Sevin B.

2018-01-01

Three series of ionic self-assembled materials based on anionic azo-dyes and cationic benzalkonium surfactants were synthesized and thin films were prepared by spin-casting. These thin films appear isotropic when investigated with polarized optical microscopy, although they are highly anisotropic. Here, three series of homologous materials were studied to rationalize this observation. Investigating thin films of ordered molecular materials relies to a large extent on advanced experimental methods and large research infrastructure. A statement that in particular is true for thin films with nanoscopic order, where X-ray reflectometry, X-ray and neutron scattering, electron microscopy and atom force microscopy (AFM) has to be used to elucidate film morphology and the underlying molecular structure. Here, the thin films were investigated using AFM, optical microscopy and polarized absorption spectroscopy. It was shown that by using numerical method for treating the polarized absorption spectroscopy data, the molecular structure can be elucidated. Further, it was shown that polarized optical spectroscopy is a general tool that allows determination of the molecular order in thin films. Finally, it was found that full control of thermal history and rigorous control of the ionic self-assembly conditions are required to reproducibly make these materials of high nanoscopic order. Similarly, the conditions for spin-casting are shown to be determining for the overall thin film morphology, while molecular order is maintained. PMID:29462883

Using Polarized Spectroscopy to Investigate Order in Thin-Films of Ionic Self-Assembled Materials Based on Azo-Dyes.

PubMed

Kühnel, Miguel R Carro-Temboury Martin; Ahmad, Mariam; Andersen, Frederik; Bech, Ári Brend; Bendixen, H Krestian L; Nawrocki, Patrick R; Bloch, Anders J; Bora, Ilkay; Bukhari, Tahreem A; Bærentsen, Nicolai V; Carstensen, Jens; Chima, Smeeah; Colberg, Helene; Dahm, Rasmus T; Daniels, Joshua A; Dinckan, Nermin; Idrissi, Mohamed El; Erlandsen, Ricci; Førster, Marc; Ghauri, Yasmin; Gold, Mikkel; Hansen, Andreas; Hansen, Kenn; Helmsøe-Zinck, Mathias; Henriksen, Mathias; Hoffmann, Sophus V; Hyllested, Louise O H; Jensen, Casper; Kallenbach, Amalie S; Kaur, Kirandip; Khan, Suheb R; Kjær, Emil T S; Kristiansen, Bjørn; Langvad, Sylvester; Lund, Philip M; Munk, Chastine F; Møller, Theis; Nehme, Ola M Z; Nejrup, Mathilde Rove; Nexø, Louise; Nielsen, Simon Skødt Holm; Niemeier, Nicolai; Nikolajsen, Lasse V; Nøhr, Peter C T; Orlowski, Dominik B; Overgaard, Marc; Ovesen, Jacob Skaarup; Paustian, Lucas; Pedersen, Adam S; Petersen, Mathias K; Poulsen, Camilla M; Praeger-Jahnsen, Louis; Qureshi, L Sonia; Ree, Nicolai; Schiermacher, Louise S; Simris, Martin B; Smith, Gorm; Smith, Heidi N; Sonne, Alexander K; Zenulovic, Marko R; Sørensen, Alma Winther; Sørensen, Karina; Vogt, Emil; Væring, Andreas; Westermann, Jonas; Özcan, Sevin B; Sørensen, Thomas Just

2018-02-15

Three series of ionic self-assembled materials based on anionic azo-dyes and cationic benzalkonium surfactants were synthesized and thin films were prepared by spin-casting. These thin films appear isotropic when investigated with polarized optical microscopy, although they are highly anisotropic. Here, three series of homologous materials were studied to rationalize this observation. Investigating thin films of ordered molecular materials relies to a large extent on advanced experimental methods and large research infrastructure. A statement that in particular is true for thin films with nanoscopic order, where X-ray reflectometry, X-ray and neutron scattering, electron microscopy and atom force microscopy (AFM) has to be used to elucidate film morphology and the underlying molecular structure. Here, the thin films were investigated using AFM, optical microscopy and polarized absorption spectroscopy. It was shown that by using numerical method for treating the polarized absorption spectroscopy data, the molecular structure can be elucidated. Further, it was shown that polarized optical spectroscopy is a general tool that allows determination of the molecular order in thin films. Finally, it was found that full control of thermal history and rigorous control of the ionic self-assembly conditions are required to reproducibly make these materials of high nanoscopic order. Similarly, the conditions for spin-casting are shown to be determining for the overall thin film morphology, while molecular order is maintained.

Free-space wavelength-multiplexed optical scanner.

PubMed

Yaqoob, Z; Rizvi, A A; Riza, N A

2001-12-10

A wavelength-multiplexed optical scanning scheme is proposed for deflecting a free-space optical beam by selection of the wavelength of the light incident on a wavelength-dispersive optical element. With fast tunable lasers or optical filters, this scanner features microsecond domain scan setting speeds and large- diameter apertures of several centimeters or more for subdegree angular scans. Analysis performed indicates an optimum scan range for a given diffraction order and grating period. Limitations include beam-spreading effects based on the varying scanner aperture sizes and the instantaneous information bandwidth of the data-carrying laser beam.

Artificial optical emissions in the thermosphere induced by powerful radio waves: A review

NASA Astrophysics Data System (ADS)

Kosch, M.; Senior, A.; Gustavsson, B.; Grach, S.; Pedersen, T.; Rietveld, M.

High-power high-frequency radio waves beamed into the ionosphere with O-mode polarization cause plasma turbulence which can accelerate electrons These electrons collide with the F-layer neutrals causing artificial optical emissions identical to natural aurora The brightest optical emissions are O 1D 630 nm with a threshold of 2 eV and O 1S 557 7 nm with a threshold of 4 2 eV The optical emissions give direct evidence of electron acceleration by plasma turbulence as well as their non-Maxwellian energy spectrum HF pumping of the ionosphere also causes electron temperature enhancements but these alone are not sufficient to explain the optical emissions EISCAT plasma-line measurements indicate that the enhanced electron temperatures are consistent with the bulk of the electrons having a Maxwellian energy spectrum Novel discoveries include 1 Very large electron temperature enhancements of several 1000 K which maximise along the magnetic field line direction 2 Ion temperature enhancements of a few 100 K 3 Large ion outflows exceeding 200 m s 4 The F-layer optical emission maximizes sharply near the magnetic zenith with clear evidence of self-focusing 5 The optical emission generally appears below the HF pump reflection altitude as well as the upper-hybrid resonance height 6 The optical emission and HF coherent radar backscatter generally minimize when pumping on the third or higher electron gyro-harmonic frequency suggesting upper-hybrid waves as the primary mechanism 7 The optical emissions and HF coherent backscatter are enhanced on the

SKA weak lensing - III. Added value of multiwavelength synergies for the mitigation of systematics

NASA Astrophysics Data System (ADS)

Camera, Stefano; Harrison, Ian; Bonaldi, Anna; Brown, Michael L.

2017-02-01

In this third paper of a series on radio weak lensing for cosmology with the Square Kilometre Array, we scrutinize synergies between cosmic shear measurements in the radio and optical/near-infrared (IR) bands for mitigating systematic effects. We focus on three main classes of systematics: (I) experimental systematic errors in the observed shear; (II) signal contamination by intrinsic alignments and (III) systematic effects due to an incorrect modelling of non-linear scales. First, we show that a comprehensive, multiwavelength analysis provides a self-calibration method for experimental systematic effects, only implying <50 per cent increment on the errors on cosmological parameters. We also illustrate how the cross-correlation between radio and optical/near-IR surveys alone is able to remove residual systematics with variance as large as 10-5, I.e. the same order of magnitude of the cosmological signal. This also opens the possibility of using such a cross-correlation as a means to detect unknown experimental systematics. Secondly, we demonstrate that, thanks to polarization information, radio weak lensing surveys will be able to mitigate contamination by intrinsic alignments, in a way similar but fully complementary to available self-calibration methods based on position-shear correlations. Lastly, we illustrate how radio weak lensing experiments, reaching higher redshifts than those accessible to optical surveys, will probe dark energy and the growth of cosmic structures in regimes less contaminated by non-linearities in the matter perturbations. For instance, the higher redshift bins of radio catalogues peak at z ≃ 0.8-1, whereas their optical/near-IR counterparts are limited to z ≲ 0.5-0.7. This translates into having a cosmological signal 2-5 times less contaminated by non-linear perturbations.

High-speed volume measurement system and method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lane, Michael H.; Doyle, Jr., James L.; Brinkman, Michael J.

2017-12-12

Disclosed is a volume sensor having first, second, and third laser sources emitting first, second, and third laser beams; first, second, and third beam splitters splitting the first, second, and third laser beams into first, second, and third beam pairs; first, second, and third optical assemblies expanding the first, second, and third beam pairs into first, second, and third pairs of parallel beam sheets; fourth, fifth, and sixth optical assemblies focusing the first, second, and third beam sheet pairs into fourth, fifth, and sixth beam pairs; and first, second, and third detector pairs receiving the fourth, fifth, and sixth beammore » pairs and converting a change in intensity of at least one of the beam pairs resulting from an object passing through at least one of the first, second, and third parallel beam sheets into at least one electrical signal proportional to a three-dimensional representation of the object.« less

Optical bandgap modelling from the structural arrangement of carbon nanotubes.

PubMed

Butler, Timothy P; Rashid, Ijaz; Montelongo, Yunuen; Amaratunga, Gehan A J; Butt, Haider

2018-06-14

The optical bandgap properties of vertically-aligned carbon nanotube (VACNT) arrays were probed through their interaction with white light, with the light reflected from the rotating arrays measured with a spectrometer. The precise deterministic control over the structure of vertically-aligned carbon nanotube arrays through electron beam lithography and well-controlled growth conditions brings with it the ability to produce exotic photonic crystals over a relatively large area. The characterisation of the behaviour of these materials in the presence of light is a necessary first step toward application. Relatively large area array structures of high-quality VACNTs were fabricated in square, hexagonal, circular and pseudorandom patterned arrays with length scales on the order of those of visible light for the purpose of investigating how they may be used to manipulate an impinging light beam. In order to investigate the optical properties of these arrays a set of measurement apparatus was designed which allowed the accurate measurement of their optical bandgap characteristics. The patterned samples were rotated under the illuminating white light beam, revealing interesting optical bandgap results caused by the changing patterns and relative positions of the scattering elements (VACNTs).

Optical diffraction by ordered 2D arrays of silica microspheres

NASA Astrophysics Data System (ADS)

Shcherbakov, A. A.; Shavdina, O.; Tishchenko, A. V.; Veillas, C.; Verrier, I.; Dellea, O.; Jourlin, Y.

2017-03-01

The article presents experimental and theoretical studies of angular dependent diffraction properties of 2D monolayer arrays of silica microspheres. High-quality large area defect-free monolayers of 1 μm diameter silica microspheres were deposited by the Langmuir-Blodgett technique under an accurate optical control. Measured angular dependencies of zeroth and one of the first order diffraction efficiencies produced by deposited samples were simulated by the rigorous Generalized Source Method taking into account particle size dispersion and lattice nonideality.

Ultralow power trapping and fluorescence detection of single particles on an optofluidic chip.

PubMed

Kühn, S; Phillips, B S; Lunt, E J; Hawkins, A R; Schmidt, H

2010-01-21

The development of on-chip methods to manipulate particles is receiving rapidly increasing attention. All-optical traps offer numerous advantages, but are plagued by large required power levels on the order of hundreds of milliwatts and the inability to act exclusively on individual particles. Here, we demonstrate a fully integrated electro-optical trap for single particles with optical excitation power levels that are five orders of magnitude lower than in conventional optical force traps. The trap is based on spatio-temporal light modulation that is implemented using networks of antiresonant reflecting optical waveguides. We demonstrate the combination of on-chip trapping and fluorescence detection of single microorganisms by studying the photobleaching dynamics of stained DNA in E. coli bacteria. The favorable size scaling facilitates the trapping of single nanoparticles on integrated optofluidic chips.

Comparative Study of Neural Network Frameworks for the Next Generation of Adaptive Optics Systems.

PubMed

González-Gutiérrez, Carlos; Santos, Jesús Daniel; Martínez-Zarzuela, Mario; Basden, Alistair G; Osborn, James; Díaz-Pernas, Francisco Javier; De Cos Juez, Francisco Javier

2017-06-02

Many of the next generation of adaptive optics systems on large and extremely large telescopes require tomographic techniques in order to correct for atmospheric turbulence over a large field of view. Multi-object adaptive optics is one such technique. In this paper, different implementations of a tomographic reconstructor based on a machine learning architecture named "CARMEN" are presented. Basic concepts of adaptive optics are introduced first, with a short explanation of three different control systems used on real telescopes and the sensors utilised. The operation of the reconstructor, along with the three neural network frameworks used, and the developed CUDA code are detailed. Changes to the size of the reconstructor influence the training and execution time of the neural network. The native CUDA code turns out to be the best choice for all the systems, although some of the other frameworks offer good performance under certain circumstances.

Comparative Study of Neural Network Frameworks for the Next Generation of Adaptive Optics Systems

PubMed Central

González-Gutiérrez, Carlos; Santos, Jesús Daniel; Martínez-Zarzuela, Mario; Basden, Alistair G.; Osborn, James; Díaz-Pernas, Francisco Javier; De Cos Juez, Francisco Javier

2017-01-01

Many of the next generation of adaptive optics systems on large and extremely large telescopes require tomographic techniques in order to correct for atmospheric turbulence over a large field of view. Multi-object adaptive optics is one such technique. In this paper, different implementations of a tomographic reconstructor based on a machine learning architecture named “CARMEN” are presented. Basic concepts of adaptive optics are introduced first, with a short explanation of three different control systems used on real telescopes and the sensors utilised. The operation of the reconstructor, along with the three neural network frameworks used, and the developed CUDA code are detailed. Changes to the size of the reconstructor influence the training and execution time of the neural network. The native CUDA code turns out to be the best choice for all the systems, although some of the other frameworks offer good performance under certain circumstances. PMID:28574426

Materials For Second and Third Order Nonlinear Optical Applications.

DTIC Science & Technology

1996-02-05

the ,Ieneral reaction scheme below in Fig. 1 is reminiscent of the synthetic method of Jutz, using Grignard reagents which were treated with N-methyl...N- phenylpropen-l-al (1[1]) or its higher vinylog, 1[2] in yields of 5-95%. In our procedure, we used a wide variety of organolithium reagents ...be synthesized from a facile high yield procedure for bromination of julolidine. Here we demonstrated that organolithium reagents add to known co-N,N

Generation of multicolor vacuum ultraviolet pulses through four-wave sum-frequency mixing in argon

NASA Astrophysics Data System (ADS)

Shi, Liping; Li, Wenxue; Zhou, Hui; Wang, Di; Ding, Liang'en; Zeng, Heping

2013-11-01

We demonstrate efficient generation of multicolor vacuum ultraviolet pulses with excellent mode quality through χ(3)-based four-wave sum-frequency mixing and third-order harmonic generation of 400- and 267-nm femtosecond laser pulses in argon gas. The χ(3)-based nonlinear optical processes were optimized with appropriate control of gas pressure and group velocity delay between the driving pulses. Furthermore, the pulse breakup effects were observed for tightly focused ultraviolet pulses.

Optical response of semiconductors in a dc-electric field

NASA Astrophysics Data System (ADS)

Prussel, Lucie; Veniard, Valerie

A deep understanding of the optical properties of solids is crucial for the improvement of nonlinear materials and devices. It offers the opportunity to search for new materials with specific properties. One way to tune some of those properties is to apply an electrostatic field. This gives rise to electro-optic effects. The most known among those is the Pockel or linear electro-optic effect (LEO), which is a second order response property described by the susceptibility χ (2) (- ω ω , 0) . An important nonlinear process is the second harmonic generation (SHG), where two photons are absorbed by the material. While this process is sensitive to the symmetry of the material, adding a static field would enable a nonlinear response from every material, including centrosymmetric ones. This happens through a third order process, named EFISH (Electric Field Induced Second Harmonic) for which the susceptibility of interest is χ (3) (- 2 ω ω , ω , 0) . We have developed a theoretical approach and a numerical tool to study these two nonlinear properties (LEO and EFISH) in the context of Time-dependent Density Functional Theory (TDDFT), and we have applied it to the case of bulk SiC and GaAs as well as layered systems such as Ge/SiGe.

Ultra-fast nonlinear optical properties and photophysical mechanism of a novel pyrene derivative

NASA Astrophysics Data System (ADS)

Zhang, Youwei; Yang, Junyi; Xiao, Zhengguo; Song, Yinglin

2016-10-01

The third-order nonlinear optical properties of 1-(pyrene-1-y1)-3-(3-methylthiophene) acrylic keton named PMTAK was investigated by using Z-scan technique. The light sources for picoseconds(ps) and femtosecond(fs) Z-scan were a mode-locked Nd: YAG laser (21 ps, 532 nm,10 Hz) and an Yb: KGW based fiber laser (190 fs, 515 nm,532 nm, 20 Hz), respectively. In the two cases, reverse saturation absorption(RSA) are observed. The dynamics of the sample's optical nonlinearity is discussed via the femtosecond time-resolved pump probe with phase object at 515nm. We believe that the molecules in excited state of particle population count is caused by two-photon absorption(TPA). The five-level theoretical model is used to analysis the optical nonlinear mechanism. Combining with the result of picosecond Z-scan experiment, a set of optical nonlinear parameters are calculated out. The femtosecond Z-scan experiment is taken to confirm these parameters. The obvious excited-state nonlinearity is found by the set of parameters. The result shows that the sample has good optical nonlinearity which indicates it has potential applications in nonlinear optics field.

Course for undergraduate students: analysis of the retinal image quality of a human eye model

NASA Astrophysics Data System (ADS)

del Mar Pérez, Maria; Yebra, Ana; Fernández-Oliveras, Alicia; Ghinea, Razvan; Ionescu, Ana M.; Cardona, Juan C.

2014-07-01

In teaching of Vision Physics or Physiological Optics, the knowledge and analysis of the aberration that the human eye presents are of great interest, since this information allows a proper evaluation of the quality of the retinal image. The objective of the present work is that the students acquire the required competencies which will allow them to evaluate the optical quality of the human visual system for emmetropic and ammetropic eye, both with and without the optical compensation. For this purpose, an optical system corresponding to the Navarro-Escudero eye model, which allows calculating and evaluating the aberration of this eye model in different ammetropic conditions, was developed employing the OSLO LT software. The optical quality of the visual system will be assessed through determinations of the third and fifth order aberration coefficients, the impact diagram, wavefront analysis, calculation of the Point Spread Function and the Modulation Transfer Function for ammetropic individuals, with myopia or hyperopia, both with or without the optical compensation. This course is expected to be of great interest for student of Optics and Optometry Sciences, last courses of Physics or medical sciences related with human vision.

Large Diffractive Optics for GEo-Based Earth Surveillance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hyde, R A

2003-09-11

The natural vantage point for performing Earth-centric operations from space is geosynchronous orbit (GEO); a platform there moves at the same rate as the Earth's surface, so appears to continually ''hover'' over a fixed site on the Earth. Unlike spacecraft in other orbits, which rapidly fly-over targets, a GEO-based platform remains in-position all the time. In order to insure continual access to sites using low earth orbit (LEO) platforms, one needs a large enough constellation ({approx} 50) of spacecraft so that one is always overhead; in contrast, a single GEO platform provides continuous coverage over sites throughout Euro-Asia. This permanentmore » coverage comes, unfortunately, with a stiff price-tag; geosynchronous orbit is 36,000 km high, so space platforms there must operate at ranges roughly 100 times greater than ones located in LEO. For optical-based applications, this extreme range is difficult to deal with; for surveillance the price is a 100-fold loss of resolution, for laser weapons it is a 10,000-fold loss in flux-on-target. These huge performance penalties are almost always unacceptable, preventing us from successfully using GEO-based platforms. In practice, we are forced to either settle for brief, infrequent access to targets, or, if we demand continuous coverage, to invest in large, many-satellite, constellations. There is, fortunately, a way to use GEO-based optical platforms without incurring the huge, range-dependent, performance penalties; one must simply use bigger optics. As long as the aperture of a platform's optics increases as much as its operating range, then its performance (resolution and/or flux) does not suffer; the price for operating from GEO is simply 100-fold larger optics. This is, of course, a very stiff price; while meter-class optics may suffice for many low-earth-orbit applications, 100 meter apertures are needed in order to achieve similar performance from GEO. Since even the largest Earth-based telescope is only 10 meters in diameter, building ten-fold larger ones for GEO applications (let alone delivering and operating them there) presents major difficulties. However, since the challenges of fielding large platforms in GEO are matched by the benefits of continuous coverage, we propose a program to develop such optical platforms. In this section, we will examine a particular form of large aperture optic, using a flat diffractive lens instead of the more conventional curved reflectors considered elsewhere in this report. We will discuss both the development of this type of large aperture optics, as well as the steps necessary to use it for GEO-based Earth surveillance. In a later section of this report we will discuss another use for large diffractive optics, their application for global-reach laser weapons.« less

A new third order finite volume weighted essentially non-oscillatory scheme on tetrahedral meshes

NASA Astrophysics Data System (ADS)

Zhu, Jun; Qiu, Jianxian

2017-11-01

In this paper a third order finite volume weighted essentially non-oscillatory scheme is designed for solving hyperbolic conservation laws on tetrahedral meshes. Comparing with other finite volume WENO schemes designed on tetrahedral meshes, the crucial advantages of such new WENO scheme are its simplicity and compactness with the application of only six unequal size spatial stencils for reconstructing unequal degree polynomials in the WENO type spatial procedures, and easy choice of the positive linear weights without considering the topology of the meshes. The original innovation of such scheme is to use a quadratic polynomial defined on a big central spatial stencil for obtaining third order numerical approximation at any points inside the target tetrahedral cell in smooth region and switch to at least one of five linear polynomials defined on small biased/central spatial stencils for sustaining sharp shock transitions and keeping essentially non-oscillatory property simultaneously. By performing such new procedures in spatial reconstructions and adopting a third order TVD Runge-Kutta time discretization method for solving the ordinary differential equation (ODE), the new scheme's memory occupancy is decreased and the computing efficiency is increased. So it is suitable for large scale engineering requirements on tetrahedral meshes. Some numerical results are provided to illustrate the good performance of such scheme.

Experiments and Theory of Induced Optical Magnetization

NASA Astrophysics Data System (ADS)

Fisher, Alexander A.

This thesis reports the results of light scattering experiments at moderate optical intensities (˜ 108 W/cm2) in which the magnetic component of light induces magnetic dipolar response of unprecedented intensity by a novel nonlinear mechanism. Both experimentally and theoretically the amplitude of induced magnetization is found to be as large as electric polarization (M = cP) at intensities above ~ 108 W/cm2 in different materials, greatly exceeding the conventional bounds of the multipole expansion. The transverse nature of the magnetization, its frequency, and its quadratic dependence on incident light intensity are in agreement with an exact theory which identifies the importance of magnetically-induced torque in achieving 2-photon resonance of this ultrafast process. In this work we report and compare the intensity dependence of cross-polarized scattering in the transparent molecular liquids CCl4, SiCl 4, SiBr4, SnCl4, C6H6, C 6D6, C6H5NH2, and C 6H5CN and the crystalline solid Gd3Ga5O 12. Complete radiation patterns of co-polarized and cross-polarized light scattering were recorded as a function of intensity in these homogeneous media and subsequently decomposed into polarized and unpolarized components to provide a more complete picture of scattering dynamics than has been possible in past experiments. The cross-polarized scattering observed from spherical-top molecules CCl4, SiCl4, SiBr4, and SnCl4 and crystalline GGG is argued to originate from magnetic dipoles induced by a second-order optical nonlinearity driven jointly by the E and B fields of light. Among the spherical top molecular liquids, SnCl4 developed more intense magnetic scattering at a fixed intensity than CCl4, in agreement with the predicted dependence on rotational frequency and damping. Cross-polarized scattering in anisotropic molecules C6H6, C6D6, C6 H5NH2, and C6H5CN, on the other hand, is known to originate from optical orientation of permanent electric dipole moments in first-order or differential polarizability in third-order. The importance of rotational dynamics to depolarization in all the liquids studied is outlined and confirmed through observation of an isotopic effect in the scattering from C6H6 vs. C6D 6. Finally, the new nonlinear optical process investigated here provides a method for generating oriented rotations of molecules.

Reduction of electro-optic half-wave voltage of 0.93Pb(Zn1/3Nb2/3)O3-0.07PbTiO3 single crystal through large piezoelectric strain

PubMed Central

Sun, Enwei; Wang, Zhu; Zhang, Rui; Cao, Wenwu

2011-01-01

The influence of converse piezoelectric effect on the electro-optic coefficient of single domain relaxor-based 0.93Pb(Zn1/3Nb2/3)O3-0.07PbTiO3 (PZN-0.07PT) has been quantified under ambient conditions. It was found that the large piezoelectric constants d31 and d33 have significant influence to the half-wave voltage of electro-optic modulators. For single domain PZN-0.07PT crystal, Vπ13T is reduced by a factor of 8 and Vπ13L can be decreased by more than an order of magnitude due to the large piezoelectric effect. Compared to commonly used electro-optic crystal LiNbO3 and BaTiO3, PZN-xPT single crystal is much superior for optic phase modulation applications because they have much higher linear electro-optic coefficients and much lower half-wave voltage when piezoelectric strain influence is considered. PMID:21308004

Applications of plastic optical fiber in communication

NASA Astrophysics Data System (ADS)

Tayahi, Moncef Ben

In this thesis, we report the results of our theoretical and experimental studies of large core polymer fibers. This relatively low loss and high bandwidth plastic optical fiber (POF) potentially have important applications in LAN. We measured the power penalty due to modal noise. We also developed a model to calculate the signal to noise ratio (SNR) and the bit error rate (BER) floor just by knowing the coupling coefficient in the mode selective loss being considered. The calculated bandwidth using the WKB approximation was found to be 0.44 GHz per 100 m, which is much lower than the measured bandwidth of 3 GHz per 100 m. This discrepancy was explained by the presence of strong mode coupling in POFs. We studied distortions products in CATV systems. Composite second order (CSO) and composite triple beat (CTB) for different channels were measured using a spectrum analyzer and adjustable band pass filter. Since the CSO and the CTB did not meet the CATV standard, a predistortion circuit was used to minimize CSO and CTB products produced by the laser. The predistortion circuit provides a signal comprising multiple subcarrier signals substantially equal in magnitude and opposite in phase to those associated with the nonlinear transfer function of the laser being deployed. The RF signal is split into a primary branch that has a time delayed portion (80% of the RF signal), the secondary branch (10% of the RF signal) is where the second order products are generated with a 180 °phase shift from the fundamental, and the last remaining 10% of the RF signal is where the third order distortion products are generated with a 180 °phase shift from the fundamental. The output signal is taken as the summation of three signals processed by the branch circuits and coupled to the directly to the laser to be linearized. Finally, using cyclic transparent optical polymer (CYTOP), a perfluorinated graded index fiber, different transmission characteristics were investigated. CYTOP fiber has many outstanding characteristics superior to any other polymer waveguide. It can support multi-Gb/s date rates from 800 run to 1300 nm.

Aberrated laser beams in terms of Zernike polynomials

NASA Astrophysics Data System (ADS)

Alda, Javier; Alonso, Jose; Bernabeu, Eusebio

1996-11-01

The characterization of light beams has devoted a lot of attention in the past decade. Several formalisms have been presented to treat the problem of parameter invariance and characterization in the propagation of light beam along ideal, ABCD, optical systems. The hard and soft apertured optical systems have been treated too. Also some aberrations have been analyzed, but it has not appeared a formalism able to treat the problem as a whole. In this contribution we use a classical approach to describe the problem of aberrated, and therefore apertured, light beams. The wavefront aberration is included in a pure phase term expanded in terms of the Zernike polynomials. Then, we can use the relation between the lower order Zernike polynomia and the Seidel or third order aberrations. We analyze the astigmatism, the spherical aberration and the coma, and we show how higher order aberrations can be taken into account. We have calculated the divergence, and the radius of curvature of such aberrated beams and the influence of these aberrations in the quality of the light beam. Some numerical simulations have been done to illustrate the method.

Nonlinear refraction of Nd3+-Li+ co-doped CdS-PVP nanostructure

NASA Astrophysics Data System (ADS)

Talwatkar, S. S.; Sunatkari, A. L.; Tamgadge, Y. S.; Muley, G. G.

2018-05-01

Third-order optical nonlinearity of the co-doped CdS nanoparticles embedded in polymer thin films is studied with the Z-scan technique with 632.8 nm excitation using a cw laser. The results show that the co-doped CdS nanocomposite film exhibits enhanced negative nonlinear refractive index in the order of n2 ≈ 10-5 cm2/W, as compared to the undoped CdS nanoparticles. Nonlinear refractive index of co-doped CdS-PVP thin film are found maximum for the sample doped with 5 wt% of Nd3+-Li+ concentration. The underlying mechanism is discussed.

Issues to be addressed in the design and fabrication of ultralightweight, meter class optics

NASA Astrophysics Data System (ADS)

Krumweide, Gary C.; Dyer, J.; Kasl, E. P.; Mehle, G. V.

1998-01-01

There is a growing need for large aperture, ultralightweight, deployable optics (mirrors) for various science, military and commercial compact satellites (Pleimann 1997). This paper will examine the engineering and manufacturing considerations that must be addressed in order to satisfy the requirements for these sought after optics. In order to limit the scope of this paper, only Graphite Fiber Reinforced/Polymer Matrix Composites (GFR/PMC) will be under consideration because of the potential to satisfy ultralightweight mirror requirements (5-10 Kg/m2) (Kasl 1997). The requirements associated with specular mirror concepts that Composite Optics, Incorporated (COI) has proposed to Air Force Research Laboratory (AFRL/VS) and NASA Langley Research Center for visible range optics and LIDAR (light bucket) optics, respectively, will also be our interest. Moreover, it is the intent of this paper to illustrate how COI's proposed design/manufacturing concepts for visible and LIDAR optics have evolved based on overcoming, or working around, material constraints and/or undesirable characteristics associated with GFR/PMC.

432- μm laser's beam-waist measurement for the polarimeter/interferometer on the EAST tokamak

NASA Astrophysics Data System (ADS)

Wang, Z. X.; Liu, H. Q.; Jie, Y. X.; Wu, M. Q.; Lan, T.; Zhu, X.; Zou, Z. Y.; Yang, Y.; Wei, X. C.; Zeng, L.; Li, G. S.; Gao, X.

2014-10-01

A far-infrared (FIR) polarimeter/interferometer (PI) system is under development for measurements of the current-density and the electron-density profiles in the EAST tokamak. The system will utilize three identical 432- μm CHCOOH lasers pumped by a CO2 laser. Measurements of the laser beam's waist size and position are basic works. This paper will introduce three methods with a beam profiler and several focusing optical elements. The beam profiler can be used to show the spatial energy distribution of the laser beam. The active area of the profiler is 12.4 × 12.4 mm2. Some focusing optical elements are needed to focus the beam in order for the beam profiler to receive the entire laser beam. Two principles and three methods are used in the measurement. The first and the third methods are based on the same principle, and the second method adopts an other principle. Due to the fast and convenient measurement, although the first method is a special form of the third and it can only give the size of beam waist, it is essential to the development of the experiment and it can provide guidance for the choices of the sizes of the optical elements in the next step. A concave mirror, a high-density polyethylene (HDPE) lens and a polymethylpentene (TPX) lens are each used in the measurement process. The results of these methods are close enough for the design of PI system's optical path.

Influence of electrode width of interdigital transducer on third-order nonlinearity of surface acoustic wave devices on 42°YX-LiTaO3 substrate

NASA Astrophysics Data System (ADS)

Nakagawa, Ryo; Hashimoto, Ken-ya

2018-07-01

In this paper, we discuss the influence of the electrode width of an interdigital transducer on the third-order nonlinearity of surface acoustic wave (SAW) devices. First, an estimation technique of third-order nonlinear signals based on the linear finite element method is proposed, and the variation of nonlinear signal level with electrode width is estimated. Then, several one-port SAW resonators with different electrode widths are fabricated, and measured nonlinear signal levels are compared with simulation. As predicted by the numerical simulation, nonlinear signal levels became large with electrode width. However, harmonics takes a minimum at a certain electrode width. This tendency disagrees with the simulation. The variation of nonlinear coefficients is evaluated by numerical fitting for the measured data using the nonlinear signal simulator proposed by the authors. As the result, it is concluded that the generation mechanism is not limited to the acoustic strain in electrodes.

Magnetic ordering induced giant optical property change in tetragonal BiFeO3

NASA Astrophysics Data System (ADS)

Tong, Wen-Yi; Ding, Hang-Chen; Gong, Shi Jing; Wan, Xiangang; Duan, Chun-Gang

2015-12-01

Magnetic ordering could have significant influence on band structures, spin-dependent transport, and other important properties of materials. Its measurement, especially for the case of antiferromagnetic (AFM) ordering, however, is generally difficult to be achieved. Here we demonstrate the feasibility of magnetic ordering detection using a noncontact and nondestructive optical method. Taking the tetragonal BiFeO3 (BFO) as an example and combining density functional theory calculations with tight-binding models, we find that when BFO changes from C1-type to G-type AFM phase, the top of valance band shifts from the Z point to Γ point, which makes the original direct band gap become indirect. This can be explained by Slater-Koster parameters using the Harrison approach. The impact of magnetic ordering on band dispersion dramatically changes the optical properties. For the linear ones, the energy shift of the optical band gap could be as large as 0.4 eV. As for the nonlinear ones, the change is even larger. The second-harmonic generation coefficient d33 of G-AFM becomes more than 13 times smaller than that of C1-AFM case. Finally, we propose a practical way to distinguish the two AFM phases of BFO using the optical method, which is of great importance in next-generation information storage technologies.

von Kármán-Howarth equation for three-dimensional two-fluid plasmas.

PubMed

Andrés, N; Mininni, P D; Dmitruk, P; Gómez, D O

2016-06-01

We derive the von Kármán-Howarth equation for a full three-dimensional incompressible two-fluid plasma. In the long-time limit and for very large Reynolds numbers we obtain the equivalent of the hydrodynamic "four-fifths" law. This exact law predicts the scaling of the third-order two-point correlation functions, and puts a strong constraint on the plasma turbulent dynamics. Finally, we derive a simple expression for the 4/5 law in terms of third-order structure functions, which is appropriate for comparison with in situ measurements in the solar wind at different spatial ranges.

Field localization and enhancement of phase-locked second- and third-order harmonic generation in absorbing semiconductor cavities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roppo, V.; Charles M. Bowden Research Facility, US Army RDECOM, Redstone Arsenal, Alabama 35803; Cojocaru, C.

We predict and experimentally observe the enhancement by three orders of magnitude of phase mismatched second and third harmonic generation in a GaAs cavity at 650 and 433 nm, respectively, well above the absorption edge. Phase locking between the pump and the harmonics changes the effective dispersion of the medium and inhibits absorption. Despite hostile conditions the harmonics resonate inside the cavity and become amplified leading to relatively large conversion efficiencies. Field localization thus plays a pivotal role despite the presence of absorption, and ushers in a new class of semiconductor-based devices in the visible and uv ranges.

MoS2 /Carbon Nanotube Core-Shell Nanocomposites for Enhanced Nonlinear Optical Performance.

PubMed

Zhang, Xiaoyan; Selkirk, Andrew; Zhang, Saifeng; Huang, Jiawei; Li, Yuanxin; Xie, Yafeng; Dong, Ningning; Cui, Yun; Zhang, Long; Blau, Werner J; Wang, Jun

2017-03-08

Nanocomposites of layered MoS 2 and multi-walled carbon nanotubes (CNTs) with core-shell structure were prepared by a simple solvothermal method. The formation of MoS 2 nanosheets on the surface of coaxial CNTs has been confirmed by scanning electron microscopy, transmission electron microscopy, absorption spectrum, Raman spectroscopy, and X-ray photoelectron spectroscopy. Enhanced third-order nonlinear optical performances were observed for both femtosecond and nanosecond laser pulses over a broad wavelength range from the visible to the near infrared, compared to those of MoS 2 and CNTs alone. The enhancement can be ascribed to the strong coupling effect and the photoinduced charge transfer between MoS 2 and CNTs. This work affords an efficient way to fabricate novel CNTs based nanocomposites for enhanced nonlinear light-matter interaction. The versatile nonlinear properties imply a huge potential of the nanocomposites in the development of nanophotonic devices, such as mode-lockers, optical limiters, or optical switches. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Effect of annealing on structural, electrical and optical properties of p-quaterphenyl thin films

NASA Astrophysics Data System (ADS)

Darwish, A. A. A.

2017-05-01

Thin films of p-quaterphenyl are deposited by an evaporation technique. IR spectra confirm that the thermal evaporation method is a decent one to acquire p-quaterphenyl films without dissociation. The X-ray diffraction studies demonstrate that the as-deposited and annealed films are polycrystalline with monoclinic structure. The electrical conductivity shows an activated behavior and indicating that p-quaterphenyl behaves as an organic semiconductor. The value of activation energy decreases by annealing, which explains due to the adjustment in the crystallite size. Optical properties of p-quaterphenyl films were performed to determine some optical constants. Dispersion of the refractive index is described utilizing the Wemple-DiDomenico model. In addition, the third order nonlinear susceptibility and the nonlinear refractive index are calculated. The analysis of the absorption coefficient for the as-deposited film showed an allowed direct optical band gap with a value of 2.35 eV, which decreased by annealing to 2.05 eV.

Linear and nonlinear optical characteristics of Te nanoparticles-doped germanate glasses

NASA Astrophysics Data System (ADS)

Xu, Zhousu; Guo, Qiangbing; Liu, Chang; Ma, Zhijun; Liu, Xiaofeng; Qiu, Jianrong

2016-10-01

Te nanoparticles (NPs)-doped GeO2-MgO-B2O3-Al2O3-TeO2 glasses were prepared by the conventional melt-quenching method. Based on X-ray photoelectron spectroscopy, Raman spectroscopy and transmission electron microscope observation, the coloration of the glass at high TeO2 concentration is ascribed to the precipitation of elemental Te NPs with a size of 5-10 nm in the germanate glass. Optical absorption spectra and nonlinear optical (NLO) properties of the glass samples were analyzed by UV-3600 spectrophotometry and Z-scan technique, respectively. The nonlinear absorption coefficient ( β) and the imaginary part of the third-order NLO susceptibility (Im χ (3)) were estimated to be 1.74 cm/GW and 1.142 × 10-12 esu for laser power of 95 μW, respectively. Due to the excellent NLO properties, the Te NPs-doped germanate glasses may have potential applications for ultrafast optical switch and photonics.

Reciprocal regulation between taurine and glutamate response via Ca2+- dependent pathways in retinal third-order neurons

PubMed Central

2010-01-01

Although taurine and glutamate are the most abundant amino acids conducting neural signals in the central nervous system, the communication between these two neurotransmitters is largely unknown. This study explores the interaction of taurine and glutamate in the retinal third-order neurons. Using specific antibodies, both taurine and taurine transporters were localized in photoreceptors and Off-bipolar cells, glutamatergic neurons in retinas. It is possible that Off-bipolar cells release juxtaposed glutamate and taurine to activate the third-order neurons in retina. The interaction of taurine and glutamate was studied in acutely dissociated third-order neurons in whole-cell patch-clamp recording and Ca2+ imaging. We find that taurine effectively reduces glutamate-induced Ca2+ influx via ionotropic glutamate receptors and voltage-dependent Ca2+ channels in the neurons, and the effect of taurine was selectively inhibited by strychnine and picrotoxin, but not GABA receptor antagonists, although GABA receptors are present in the neurons. A CaMKII inhibitor partially reversed the effect of taurine, suggesting that a Ca2+/calmodulin-dependent pathway is involved in taurine regulation. On the other hand, a rapid influx of Ca2+ through ionotropic glutamate receptors could inhibit the amplitude and kinetics of taurine-elicited currents in the third-order neurons, which could be controlled with intracellular application of BAPTA a fast Ca2+ chelator. This study indicates that taurine is a potential neuromodulator in glutamate transmission. The reciprocal inhibition between taurine and glutamate in the postsynaptic neurons contributes to computation of visual signals in the retinal neurons. PMID:20804625

Synthesis, growth, structural modeling and physio-chemical properties of a charge transfer molecule: Guanidinium tosylate

NASA Astrophysics Data System (ADS)

Era, Paavai; Jauhar, RO. MU.; Vinitha, G.; Murugakoothan, P.

2018-05-01

An organic nonlinear optical material, guanidinium tosylate was synthesized adopting slow evaporation method and the crystals were harvested from aqueous methanolic medium with dimensions 13 × 9 × 3 mm3. Constitution of crystalline material was confirmed by single crystal X-ray diffraction study. The title compound crystallizes in the monoclinic crystal system with space group P21/c. The UV-vis-NIR spectral study of the grown crystal exhibits high transparency of 80% in the entire visible region with lower cut-off wavelength at 282 nm. Optimized molecular geometry of the grown crystal was obtained using density functional theory (DFT) and the frontier energy gaps calculated from the DFT aids to understand the charge transfer taking place in the molecule. The dielectric properties were studied as a function of temperature and frequency to find the charge distribution within the crystal. The titular compound is thermally stable up to 230 °C assessed by thermogravimetric and differential thermal analysis. Anisotropy in the mechanical behavior was observed while measuring for individual planes. The laser induced surface damage threshold of the grown crystal was measured to be 0.344 GW/cm2 for 1064 nm Nd:YAG laser radiation. Z-scan technique confirms the third-order nonlinear optical property with the ascertained nonlinear refractive index (n2), nonlinear absorption coefficient (β) and third order nonlinear susceptibility (χ(3)). Optical limiting study divulges that the transmitted output power step-up linearly with the increase of the input power at lower power realms and saturates from the threshold 24.95 mW/cm2 and amplitude 0.23 mW/cm2.

Optical nonclassicality test based on third-order intensity correlations

NASA Astrophysics Data System (ADS)

Rigovacca, L.; Kolthammer, W. S.; Di Franco, C.; Kim, M. S.

2018-03-01

We develop a nonclassicality criterion for the interference of three delayed, but otherwise identical, light fields in a three-mode Bell interferometer. We do so by comparing the prediction of quantum mechanics with those of a classical framework in which independent sources emit electric fields with random phases. In particular, we evaluate third-order correlations among output intensities as a function of the delays, and show how the presence of a correlation revival for small delays cannot be explained by the classical model of light. The observation of a revival is thus a nonclassicality signature, which can be achieved only by sources with a photon-number statistics that is highly sub-Poissonian. Our analysis provides strong evidence for the nonclassicality of the experiment discussed by Menssen et al. [Phys. Rev. Lett. 118, 153603 (2017), 10.1103/PhysRevLett.118.153603], and shows how a collective "triad" phase affects the interference of any three or more light fields, irrespective of their quantum or classical character.

Optic nerve involvement in childhood onset systemic lupus erythematosus: Three cases and a review of the literature.

PubMed

Suri, D; Abujam, B; Gupta, A; Rawat, A; Saikia, B; Walker Minz, R; Gupta, V; Bansal, R; Kaushik, S; Singh, S

2016-01-01

The ocular system can be affected in systemic lupus erythematosus (SLE) in one third of patients. However, optic nerve involvement is relatively uncommon, but is more so in pediatric SLE patients, where it can occur in 1% of cases. We report three children with SLE who presented with optic nerve involvement. Two children had optic neuritis, with optic neuritis being the first manifestation in one child. The third child had ischaemic optic neuropathy secondary to antiphospholipid syndrome. A careful work up for SLE should be performed in every child with optic nerve disease. Prompt diagnosis and early treatment results in a better prognosis. © The Author(s) 2015.

First-order error budgeting for LUVOIR mission

NASA Astrophysics Data System (ADS)

Lightsey, Paul A.; Knight, J. Scott; Feinberg, Lee D.; Bolcar, Matthew R.; Shaklan, Stuart B.

2017-09-01

Future large astronomical telescopes in space will have architectures that will have complex and demanding requirements to meet the science goals. The Large UV/Optical/IR Surveyor (LUVOIR) mission concept being assessed by the NASA/Goddard Space Flight Center is expected to be 9 to 15 meters in diameter, have a segmented primary mirror and be diffraction limited at a wavelength of 500 nanometers. The optical stability is expected to be in the picometer range for minutes to hours. Architecture studies to support the NASA Science and Technology Definition teams (STDTs) are underway to evaluate systems performance improvements to meet the science goals. To help define the technology needs and assess performance, a first order error budget has been developed. Like the JWST error budget, the error budget includes the active, adaptive and passive elements in spatial and temporal domains. JWST performance is scaled using first order approximations where appropriate and includes technical advances in telescope control.

Large Aperture "Photon Bucket" Optical Receiver Performance in High Background Environments

NASA Technical Reports Server (NTRS)

Vilnrotter, Victor A.; Hoppe, D.

2011-01-01

The potential development of large aperture groundbased "photon bucket" optical receivers for deep space communications, with acceptable performance even when pointing close to the sun, is receiving considerable attention. Sunlight scattered by the atmosphere becomes significant at micron wavelengths when pointing to a few degrees from the sun, even with the narrowest bandwidth optical filters. In addition, high quality optical apertures in the 10-30 meter range are costly and difficult to build with accurate surfaces to ensure narrow fields-of-view (FOV). One approach currently under consideration is to polish the aluminum reflector panels of large 34-meter microwave antennas to high reflectance, and accept the relatively large FOV generated by state-of-the-art polished aluminum panels with rms surface accuracies on the order of a few microns, corresponding to several-hundred micro-radian FOV, hence generating centimeter-diameter focused spots at the Cassegrain focus of 34-meter antennas. Assuming pulse-position modulation (PPM) and Poisson-distributed photon-counting detection, a "polished panel" photon-bucket receiver with large FOV will collect hundreds of background photons per PPM slot, along with comparable signal photons due to its large aperture. It is demonstrated that communications performance in terms of PPM symbol-error probability in high-background high-signal environments depends more strongly on signal than on background photons, implying that large increases in background energy can be compensated by a disproportionally small increase in signal energy. This surprising result suggests that large optical apertures with relatively poor surface quality may nevertheless provide acceptable performance for deep-space optical communications, potentially enabling the construction of cost-effective hybrid RF/optical receivers in the future.

Metasurface Enabled Wide-Angle Fourier Lens.

PubMed

Liu, Wenwei; Li, Zhancheng; Cheng, Hua; Tang, Chengchun; Li, Junjie; Zhang, Shuang; Chen, Shuqi; Tian, Jianguo

2018-06-01

Fourier optics, the principle of using Fourier transformation to understand the functionalities of optical elements, lies at the heart of modern optics, and it has been widely applied to optical information processing, imaging, holography, etc. While a simple thin lens is capable of resolving Fourier components of an arbitrary optical wavefront, its operation is limited to near normal light incidence, i.e., the paraxial approximation, which puts a severe constraint on the resolvable Fourier domain. As a result, high-order Fourier components are lost, resulting in extinction of high-resolution information of an image. Other high numerical aperture Fourier lenses usually suffer from the bulky size and costly designs. Here, a dielectric metasurface consisting of high-aspect-ratio silicon waveguide array is demonstrated experimentally, which is capable of performing 1D Fourier transform for a large incident angle range and a broad operating bandwidth. Thus, the device significantly expands the operational Fourier space, benefitting from the large numerical aperture and negligible angular dispersion at large incident angles. The Fourier metasurface will not only facilitate efficient manipulation of spatial spectrum of free-space optical wavefront, but also be readily integrated into micro-optical platforms due to its compact size. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Growth, spectral, optical, laser damage threshold and DFT investigations on 2-amino 4-methyl pyridinium 4-methoxy benzoate (2A4MP4MB): A potential organic third order nonlinear optical material for optoelectronic applications

NASA Astrophysics Data System (ADS)

Krishnakumar, M.; Karthick, S.; Thirupugalmani, K.; Babu, B.; Vinitha, G.

2018-05-01

In present investigation, single crystals of organic charge transfer complex, 2-amino-4-methyl pyridinium-4-methoxy benzoate (2A4MP4MB) was grown by controlled slow evaporation solution growth technique using methanol as a solvent at room temperature. Single crystal XRD analysis confirmed the crystal system and lattice parameters of 2A4MP4MB. The crystalline nature, presence of various vibrational modes and other chemical bonds in the compound have been recognized and confirmed by powder X-ray diffraction, FT-IR and FT-Raman spectroscopic techniques respectively. The presence of various proton and carbon positions in title compound was confirmed using 1H NMR and 13C NMR spectral studies. The wide optical operating window and cut-off wavelength were identified and band gap value of the title compound was calculated using UV-vis-NIR study. The specific heat capacity (cp) values of the title compound, 1.712 J g-1·K-1 at 300 K and 13.6 J g-1 K-1 at 433 K (melting point) were measured using Modulated Differential Scanning Calorimetric studies (MDSC). From Z-scan study, nonlinear refractive index (n2), nonlinear absorption (β) and third order nonlinear susceptibility (χ(3)) values were determined. The self-defocusing effect and saturable absorption behavior of the material were utilized to exhibit the optical limiting action at λ = 532 nm by employing the same continuous wave (cw) Nd: YAG laser source. The laser damage threshold (LDT) study of title compound was carried out using Nd: YAG laser of 532 nm wavelength. The Vickers' micro hardness test was carried out at room temperature and obtained results were investigated using classical Meyer's law. In addition, DFT calculations were carried out for the first time for this compound. These characterization studies performed on the title compound planned to probe the valuable and safe region of optical, thermal and mechanical properties to improve efficacy of 2A4MP4MB single crystals in optoelectronic device applications.

CMOS-compatible 2-bit optical spectral quantization scheme using a silicon-nanocrystal-based horizontal slot waveguide

PubMed Central

Kang, Zhe; Yuan, Jinhui; Zhang, Xianting; Wu, Qiang; Sang, Xinzhu; Farrell, Gerald; Yu, Chongxiu; Li, Feng; Tam, Hwa Yaw; Wai, P. K. A.

2014-01-01

All-optical analog-to-digital converters based on the third-order nonlinear effects in silicon waveguide are a promising candidate to overcome the limitation of electronic devices and are suitable for photonic integration. In this paper, a 2-bit optical spectral quantization scheme for on-chip all-optical analog-to-digital conversion is proposed. The proposed scheme is realized by filtering the broadened and split spectrum induced by the self-phase modulation effect in a silicon horizontal slot waveguide filled with silicon-nanocrystal. Nonlinear coefficient as high as 8708 W−1/m is obtained because of the tight mode confinement of the horizontal slot waveguide and the high nonlinear refractive index of the silicon-nanocrystal, which provides the enhanced nonlinear interaction and accordingly low power threshold. The results show that a required input peak power level less than 0.4 W can be achieved, along with the 1.98-bit effective-number-of-bit and Gray code output. The proposed scheme can find important applications in on-chip all-optical digital signal processing systems. PMID:25417847

Synthesis, growth, structural characterization, Hirshfeld analysis and nonlinear optical studies of a methyl substituted chalcone

NASA Astrophysics Data System (ADS)

Prabhu, Shobha R.; Jayarama, A.; Chandrasekharan, K.; Upadhyaya, V.; Ng, Seik Weng

2017-05-01

A new chalcone compound (2E)-3-(3-methylphenyl)-1-(4-nitrophenyl)prop-2-en-1-one (3MPNP) with molecular formula C16H13NO3 has been synthesized and crystallized by slow solvent evaporation technique. The Fourier transform infrared, Fourier transform Raman and nuclear magnetic resonance techniques were used for structural characterization. UV-visible absorption studies were carried out to study the transparency of the crystal in the visible region. Differential scanning calorimetry study shows thermal stability of crystals up to temperature 122 °C. Single crystal X-ray diffraction and powder X-ray diffraction techniques were used to study crystal structure and cell parameters. The Hirshfeld surface and 2-D fingerprint analysis were performed to study the nature of interactions and their quantitative contributions towards the crystal packing. The third order non-linear optical properties have been studied using single beam Z-scan technique and the results show that the material is a potential candidate for optical device applications such as optical limiters and optical switches.

The Development of a Deflectometer for Accurate Surface Figure Metrology

NASA Technical Reports Server (NTRS)

Gubarev, Mikhail; Eberhardt, Andrew; Ramsey, Brian; Atkins, Carolyn

2015-01-01

Marshall Space Flight Center is developing the method of direct fabrication for high resolution full-shell x-ray optics. In this technique the x-ray optics axial profiles are figured and polished using a computer-controlled ZeekoIRP600X polishing machine. Based on the Chandra optics fabrication history about one third of the manufacturing time is spent on moving a mirror between fabrication and metrology sites, reinstallation and alignment with either the metrology or fabrication instruments. Also, the accuracy of the alignment significantly affects the ultimate accuracy of the resulting mirrors. In order to achieve higher convergence rate it is highly desirable to have a metrology technique capable of in situ surface figure measurements of the optics under fabrication, so the overall fabrication costs would be greatly reduced while removing the surface errors due to the re-alignment necessary after each metrology cycle during the fabrication. The goal of this feasibility study is to demonstrate if the Phase Measuring Deflectometry can be applied for in situ metrology of full shell x-ray optics. Examples of the full-shell mirror substrates suitable for the direct fabrication

CMOS-compatible 2-bit optical spectral quantization scheme using a silicon-nanocrystal-based horizontal slot waveguide.

PubMed

Kang, Zhe; Yuan, Jinhui; Zhang, Xianting; Wu, Qiang; Sang, Xinzhu; Farrell, Gerald; Yu, Chongxiu; Li, Feng; Tam, Hwa Yaw; Wai, P K A

2014-11-24

All-optical analog-to-digital converters based on the third-order nonlinear effects in silicon waveguide are a promising candidate to overcome the limitation of electronic devices and are suitable for photonic integration. In this paper, a 2-bit optical spectral quantization scheme for on-chip all-optical analog-to-digital conversion is proposed. The proposed scheme is realized by filtering the broadened and split spectrum induced by the self-phase modulation effect in a silicon horizontal slot waveguide filled with silicon-nanocrystal. Nonlinear coefficient as high as 8708 W(-1)/m is obtained because of the tight mode confinement of the horizontal slot waveguide and the high nonlinear refractive index of the silicon-nanocrystal, which provides the enhanced nonlinear interaction and accordingly low power threshold. The results show that a required input peak power level less than 0.4 W can be achieved, along with the 1.98-bit effective-number-of-bit and Gray code output. The proposed scheme can find important applications in on-chip all-optical digital signal processing systems.

Study on optical properties of L-valine doped ADP crystal

NASA Astrophysics Data System (ADS)

Shaikh, R. N.; Anis, Mohd.; Shirsat, M. D.; Hussaini, S. S.

2015-02-01

Single crystal of L-valine doped ammonium dihydrogen phosphate has been grown by slow evaporation method at room temperature. The crystalline nature of the grown crystal was confirmed using powder X-ray diffraction technique. The different functional groups of the grown crystal were identified using Fourier transform infrared analysis. The UV-visible studies were employed to examine the high optical transparency and influential optical constants for tailoring materials suitability for optoelectronics applications. The cutoff wavelength of the title crystal was found to be 280 nm with wide optical band gap of 4.7 eV. The dielectric measurements were carried to determine the dielectric constant and dielectric loss at room temperature. The grown crystal has been characterized by thermogravimetric analysis. The second harmonic generation efficiency of the grown crystal was determined by the classical Kurtz powder technique and it is found to be 1.92 times that of potassium dihydrogen phosphate. The grown crystal was identified as third order nonlinear optical material employing Z-scan technique using He-Ne laser operating at 632.8 nm.