Development of multiple unconformities during the Devonian-Carboniferous transition on parts of Laurussia

USGS Publications Warehouse

Ettensohn, F.R.; Pashin, J.C.

1997-01-01

The Devonian-Carboniferous transition on Laurussia was a time of diverse geologic activity associated with the assembly of Pangea, including episodes of Late Devonian glacial-eustatic lowstand and active orogeny on four margins. Six widespread unconformities are present in the Devonian-Carboniferous (Mississippian) interval on southern parts of Laurussia. We suggest that attention to the timing and plan of the unconformities may provide ways of discerning tectonic and climatic controls on their respective origins. Indeed, unconformities generated by pure eustasy are ideally of interregional extent, whereas unconformities generated by tectonism reflect more local factors associated with the evolution of sedimentary basins. Each of the six unconformities analyzed provides evidence for concurrent eustasy and tectonism. Glaciation was apparently the dominant factor driving the development of unconformities during the latest Devonian. During the Early Carboniferous, however, the volume of glacial ice available to drive eustasy was limited and, at times, tectonism may have been the source of a subordinate eustatic signal. Development of unconformities in southern Laurussia appear to be local manifestations of tectonic and climatic processes associated with supercontinent assembly. Thus, the time may be at hand for construction of a new global stratigraphic paradigm that is based on the plate tectonic supercycle affecting continentality and climate.

Environmental conditions as the cause of the great mass extinction of marine organisms in the Late Devonian

NASA Astrophysics Data System (ADS)

Barash, M. S.

2017-08-01

During the Late Devonian extinction, 70-82% of all marine species disappeared. The main causes of this mass extinction include tectonic activity, climate and sea-level fluctuations, volcanism, and the collision of the Earth with cosmic bodies (impact events). The major causes are considered to be volcanism accompanying formation of the Viluy traps and, probably, basaltic magmatism in the Southern Urals, alkaline magmatism within the East European platform, and volcanism in northern Iran and northern and southern China. Several large impact craters of Late Devonian age have been documented in different parts of the world. The available data indicate that this time period on the Earth was marked by two major sequences of events: terrestrial events that resulted in extensive volcanism and cosmic (or impact) events. They produced similar effects such as emissions of harmful chemical compounds and aerosols to cause greenhouse warming and the darkening of the atmosphere, which prevented photosynthesis and cause ocean stagnation and anoxia. This disrupted the food chain and reduced ecosystem productivity. As a result, all vital processes were disturbed and a large part of the marine biota became extinct.

Causes of the great mass extinction of marine organisms in the Late Devonian

NASA Astrophysics Data System (ADS)

Barash, M. S.

2016-11-01

The second of the five great mass extinctions of the Phanerozoic occurred in the Late Devonian. The number of species decreased by 70-82%. Major crises occurred at the Frasnian-Famennian and Devonian-Carboniferous boundary. The lithological and geochemical compositions of sediments, volcanic deposits, impactites, carbon and oxygen isotope ratios, evidence of climate variability, and sea level changes reflect the processes that led the critical conditions. Critical intervals are marked by layers of black shales, which were deposited in euxinic or anoxic environments. These conditions were the main direct causes of the extinctions. The Late Devonian mass extinction was determined by a combination of impact events and extensive volcanism. They produced similar effects: emissions of harmful chemical compounds and aerosols to cause greenhouse warming; darkening of the atmosphere, which prevented photosynthesis; and stagnation of oceans and development of anoxia. Food chains collapsed and biological productivity decreased. As a result, all vital processes were disturbed and a large portion of the biota became extinct.

Paleozoic and Lower Mesozoic magmas from the eastern Klamath Mountains (North California) and the geodynamic evolution of northwestern America

NASA Astrophysics Data System (ADS)

Lapierre, H.; Brouxel, M.; Albarede, F.; Coulin, C.; Lecuyer, C.; Martin, P.; Mascle, G.; Rouer, O.

1987-09-01

The Paleozoic to Early Mesozoic geology of the eastern Klamath Mountains (N California) is characterized by three major magmatic events of Ordovician, Late Ordovician to Early Devonian, and Permo-Triassic ages. The Ordovician event is represented by a calc-alkalic island-arc sequence (Lovers Leap Butte sequence) developed in the vicinity of a continental margin. The Late Ordovician to Early Devonian event consists of the 430-480 Ma old Trinity ophiolite formed during the early development of a marginal basin, and a series of low-K tholeiitic volcanic suites (Lovers Leap Basalt—Keratophyre unit, Copley and Balaklala Formations) belonging to intraoceanic island-arcs. Finally, the Permo-Triassic event gave rise to three successives phases of volcanic activity (Nosoni, Dekkas and Bully Hill) represented by the highly differentiated basalt-to-rhyolite low-K tholeiitic series of mature island-arcs. The Permo-Triassic sediments are indicative of shallow to moderate depth in an open, warm sea. The geodynamic evolution of the eastern Klamath Mountains during Paleozoic to Early Mesozoic times is therefore constrained by the geological, petrological and geochemical features of its island-arcs and related marginal basin. A consistent plate-tectonic model is proposed for the area, consisting of six main stages: (1) development during Ordovician times of a calc-alkalic island-arc in the vicinity of a continental margin; (2) extrusion during Late Ordovician to Silurian times of a primitive basalt-andesite intraoceanic island-arc suite, which terminated with boninites, the latter suggest rifting in the fore-arc, followed by the breakup of the arc; (3) opening and development of the Trinity back-arc basin around 430-480 Ma ago; (4) eruption of the Balaklala Rhyolite either in the arc or in the fore-arc, ending in Early Devonian time with intrusion of the 400 Ma Mule Mountain stock; (5) break in volcanic activity from the Early Devonian to the Early Permian; and (6) development of a mature island-arc from the Early Permian to the Late Triassic. The eastern Klamath Mountains island-arc formations and ophiolitic suite are part of the "Cordilleran suspect terranes", considered to be Gondwana margin fragments, that have undergone large northward translations before final collision with the North American craton during Late Mesozoic or Cenozoic times. These eastern Klamath Mountains island-arcs could be associated with the paleo-Pacific oceanic plate that led to accretion of these allochthonous terranes to the American margin.

Devonian-Carboniferous unconformity in Argentina and its relation to the Eo-Hercynian orogeny in southern South America

NASA Astrophysics Data System (ADS)

López-Gamundí, O. R.; Rossello, E. A.

1993-04-01

The Devonian-Carboniferous contact in southern South America, characterized by a sharp unconformity, has been related to the Late Devonian-Early Carboniferous Eo-Hercynian orogeny. The Calingasta-Uspallata basin of western Argentina and the Sauce-Grande basin (Ventana Foldbelt) of eastern Argentina have been selected to characterize this unconformity. The Eo-Hercynian movements were accompanied in western Argentina by igneous activity related to a Late Devonian—Early Carboniferous magmatic arc mainly exposed today along the Andean Cordillera. This magmatic activity is partly reflected also in eastern Argentina (Ventana Foldbelt), where isotopic dates suggest a thermal event also related to the intrusions present to the west in the North Patagonian Massif and Sierras Pampeanas. The scarcity of Lower Carboniferous deposits in the stratigraphic record of southern South America suggests that the Early Carboniferous was a time interval dominated by uplift and erosion followed by widespread subsidence during the Middle and Late Carboniferous. The origin of the Eo-Hercynian orogeny can be linked with the convergence between the Arequipa Massif, and its southern extension, and the South American continent. Its effects are best represented along the ‘Palaeo-Pacific’ margin, although distant effects are discernible in the cratonic areas of eastern South America.

New Insights into Arctic Tectonics: Uranium-Lead, (Uranium-Thorium)/Helium, and Hafnium Isotopic Data from the Franklinian Basin, Canadian Arctic Islands

NASA Astrophysics Data System (ADS)

Anfinson, Owen Anthony

More than 2300 detrital zircon uranium-lead (U-Pb) ages, 32 176Hf/177Hf (eHf) isotopic values, 37 apatite helium (AHe) ages, and 72 zircon helium (ZHe) ages represent the first in-depth geochronologic and thermochronologic study of Franklinian Basin strata in the Canadian Arctic and provide new insight on >500 M.y. of geologic history along the northern Laurentian margin (modern orientation). Detrital zircon U-Pb age data demonstrate that the Franklinian Basin succession is composed of strata with three distinctly different provenance signatures. Neoproterozoic and Lower Cambrian formations contain detrital zircon populations consistent with derivation from Archean to Paleoproterozoic gneisses and granites of the west Greenland--northeast Canadian Shield. Lower Silurian to Middle Devonian strata are primarily derived from foreland basin strata of the East Greenland Caledonides (Caledonian orogen). Middle Devonian to Upper Devonian strata also contain detrital zircon populations interpreted as being primarily northerly derived from the continental landmass responsible for the Ellesmerian Orogen (often referred to as Crockerland). U-Pb age data from basal turbidites of the Middle to Upper Devonian clastic succession suggest Crockerland contributed sediment to the northern Laurentian margin by early-Middle Devonian time and that prior to the Ellesmerian Orogeny Crockerland had a comparable geologic history to the northern Baltica Craton. Detrital zircon U-Pb ages in Upper Devonian strata suggest Crockerland became the dominant source by the end of Franklinian Basin sedimentation. Mean eHf values from Paleozoic detrital zircon derived from Crockerland suggest the zircons were primarily formed in either an island arc or continental arc built on accreted oceanic crust setting. ZHe cooling ages from Middle and Upper Devonian strata were not buried deeper than 7 km since deposition and suggest Crockerland was partially exhumed during the Caledonian Orogen. AHe cooling ages are partially reset since deposition and experienced varying burial histories depending on stratigraphic and geographic location within the basin. AHe ages from Middle Devonian strata from the western margin of the basin indicate episodes of exhumation associated with clastic influxes of sediment into the Sverdrup Basin during the Late Jurassic-Early Cretaceous and Late Cretaceous.

Late Devonian glacial deposits from the eastern United States signal an end of the mid-Paleozoic warm period

USGS Publications Warehouse

Brezinski, D.K.; Cecil, C.B.; Skema, V.W.; Stamm, R.

2008-01-01

A Late Devonian polymictic diamictite extends for more than 400??km from northeastern Pennsylvania across western Maryland and into east-central West Virginia. The matrix-supported, unbedded, locally sheared diamictite contains subangular to rounded clasts up to 2??m in diameter. The mostly rounded clasts are both locally derived and exotic; some exhibit striations, faceting, and polish. The diamictite commonly is overlain by laminated siltstone/mudstone facies associations (laminites). The laminites contain isolated clasts ranging in size from sand and pebbles to boulders, some of which are striated. The diamictite/laminite sequence is capped by massive, coarse-grained, pebbly sandstone that is trough cross-bedded. A stratigraphic change from red, calcic paleo-Vertisols in strata below the diamictite to non-calcic paleo-Spodosols and coal beds at and above the diamictite interval suggests that the climate became much wetter during deposition of the diamictite. The diamictite deposit is contemporaneous with regressive facies that reflect fluvial incision during the Late Devonian of the Appalachian basin. These deposits record a Late Devonian episode of climatic cooling so extreme that it produced glaciation in the Appalachian basin. Evidence for this episode of climatic cooling is preserved as the interpreted glacial deposits of diamictite, overlain by glaciolacustrine varves containing dropstones, and capped by sandstone interpreted as braided stream outwash. The Appalachian glacigenic deposits are contemporaneous with glacial deposits in South America, and suggest that Late Devonian climatic cooling was global. This period of dramatic global cooling may represent the end of the mid-Paleozoic warm interval that began in the Middle Silurian. ?? 2008 Elsevier B.V. All rights reserved.

Contrasting tectonothermal domains and faulting in the Potomac terrane, Virginia-Maryland - Discrimination by 40Ar/39Ar and fission-track thermochronology

USGS Publications Warehouse

Kunk, Michael J.; Wintsch, R.P.; Naeser, C.W.; Naeser, N.D.; Southworth, C.S.; Drake, Avery A.; Becker, J.L.

2005-01-01

New 40Ar/39Ar data reveal ages and thermal discontinuities that identify mapped and unmapped fault boundaries in the Potomac terrane in northern Virginia, thus confirming previous interpretations that it is a composite terrane. The rocks of the Potomac terrane were examined along the Potomac River, where it has been previously subdivided into three units: the Mather Gorge, Sykesville, and Laurel Formations. In the Mather Gorge Formation, at least two metamorphic thermal domains were identified, the Blockhouse Point and Bear Island domains, separated by a fault active in the late Devonian. Early Ordovician (ca. 475 Ma) cooling ages of amphibole in the Bear Island domain reflect cooling from Taconic metamorphism, whereas the Blockhouse Point domain was first metamorphosed in the Devonian. The 40Ar/39Ar data from muscovites in a third (eastern) domain within the Mather Gorge Formation, the Stubblefield Falls domain, record thrusting of the Sykesville Formation over the Mather Gorge Formation on the Plummers Island fault in the Devonian. The existence of two distinctly different thermal domains separated by a tectonic boundary within the Mather Gorge argues against its status as a formation. Hornblende cooling ages in the Sykesville Formation are Early Devonian (ca. 400 Ma), reflecting cooling from Taconic and Acadian metamorphism. The ages of retrograde and overprinting muscovite in phyllonites from domain-bounding faults are late Devonian (Acadian) and late Pennsylvanian (Alleghanian), marking the time of assembly of these domains and subsequent movement on the Plummers Island fault. Our data indicate that net vertical motion between the Bear Island domain of the Mather Gorge complex and the Sykesville Formation across the Plummers Island fault is east-side-up. Zircon fission-track cooling ages demonstrate thermal equillbrium across the Potomac terrane in the early Permian, and apatite fission-track cooling ages record tilting of the Potomac terrane in the Cretaceous or later with the west side up at least 1 km. ?? 2005 Geological Society of America.

Peeking out of the basins: looking for the Late Devonian Kellwasser Event in the open ocean in the Central Asian Orogenic Belt, southwestern Mongolia

NASA Astrophysics Data System (ADS)

Thomas, R. M., Jr.; Carmichael, S. K.; Waters, J. A.; Batchelor, C. J.

2017-12-01

Two of the top five most devastating mass extinctions in Earth's history occurred during the Late Devonian (419.2 Ma - 358.9 Ma), and are commonly associated with the black shale deposits of the Kellwasser and Hangenberg ocean anoxia events. Our understanding of these extinction events is incomplete partly due to sample bias, as 95% of the field sites studying the Late Devonian are limited to continental shelves and continental marine basins, and 77% of these sites are derived from the Euramerican paleocontinent. The Samnuuruul Formation at the Hoshoot Shiveetiin Gol locality (HSG), located in southwestern Mongolia, offers a unique opportunity to better understand global oceanic conditions during the Late Devonian. The HSG locality shows a continuous sequence of terrestrial to marine sediments on the East Junggar arc; an isolated, open-ocean island arc within the Central Asian Orogenic Belt (CAOB). Samples from this near shore locality consist of volcanogenic silts, sands and immature conglomerates as well as calc-alkalic basalt lava flows. Offshore sections contain numerous limestones with Late Devonian fossil assemblages. Preliminary biostratigraphy of the associated marine and terrestrial sequences can only constrain the section to a general Late Devonian age, but TIMS analysis of detrital zircons from volcanogenic sediments from the Samnuuruul Formation in localities 8-50 km from the site suggests a late Frasnian age (375, 376 Ma). To provide a more precise radiometric age of the HSG locality, zircon geochronology using laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) will be performed at UNC-Chapel Hill. If the HSG section crosses the Frasnian-Famennian boundary, geochemical, mineralogical, and ichnological signatures of the Kellwasser Event are expected to be preserved, if the Kellwasser Event was indeed global in scope (as suggested by Carmichael et al. (2014) for analogous sites on the West Junggar arc in the CAOB). Black shale accumulation anywhere in the CAOB would be unlikely due to the paleoenvironment and arc topography, so additional multiproxy techniques are required for recognition of the Kellwasser Event in regions such as the HSG, which are outside of the basins where they have historically been studied. Carmichael et al. (2014) Paleo3 399, 394-403.

Late Devonian Anoxia Events in the Central Asian Orogenic Belt: a Global Phenomenon

NASA Astrophysics Data System (ADS)

Carmichael, S. K.; Waters, J. A.; Suttner, T. J.; Kido, E.; DeReuil, A. A.; Moore, L. M.; Batchelor, C. J.

2013-12-01

Atmospheric CO2 values decreased dramatically during the Middle Devonian due to the rapid rise of land plants. These changing environmental conditions resulted in widespread anoxia and extinction events throughout the Late Devonian, including the critical Kellwasser and Hangenberg anoxia events, which are associated with major mass extinctions at both the beginning and end of the Famennian Stage of the Late Devonian. Fammenian sediments in northwestern Xinjiang Province, China, represent a highly fossiliferous shallow marine setting associated with a Devonian oceanic island arc complex. Analysis of multiple geochemical proxies (such as U/Th, Ba, normalized P2O5, V/Cr, Zr), magnetic susceptibility, and mineralogical data (biogenic apatite and pyrite framboids) indicates that these Famennian sequences record not only the Upper Kellwasser Anoxic Event at the Frasnian/Famennian (F/F) boundary but also the rebound from the F/F extinction event. Preliminary evidence suggests that the Hangenberg Anoxic Event can also be recognized in the same sequence, although our biostratigraphic control is less precise. Previous studies of the Kellwasser and Hangenberg Events have been performed on continental shelf environments of Laurussia, Gondwana, Siberia, and South China. The Devonian formations of northwest Xinjiang in this study, however, are part of the Central Asian Orogenic Belt (CAOB), which is thought to have formed as part of a complex amalgamation of intra-oceanic island arcs and continental fragments prior to the end of the latest Carboniferous. These results allow us to confirm the presence of the Kellwasser and Hangenberg Events in the open oceanic part of Paleotethys, indicating that both events were global in scope. The presence of an abundant diverse Famennian fauna between these anoxia/extinction events suggests that the shallow marine ecosystems in the CAOB were somewhat protected due to their tectonic location and relative isolation within an open ocean system. Our new data puts the Late Devonian anoxic events recognized in the CAOB into a global rather than regional context, and helps constrain the nature of ocean anoxia during this period by analysis of locations outside subequatorial North America and Europe.

Middle to Late Devonian-Carboniferous collapse basins on the Finnmark Platform and in the southwesternmost Nordkapp basin, SW Barents Sea

NASA Astrophysics Data System (ADS)

Koehl, Jean-Baptiste P.; Bergh, Steffen G.; Henningsen, Tormod; Faleide, Jan Inge

2018-03-01

The SW Barents Sea margin experienced a pulse of extensional deformation in the Middle-Late Devonian through the Carboniferous, after the Caledonian Orogeny terminated. These events marked the initial stages of formation of major offshore basins such as the Hammerfest and Nordkapp basins. We mapped and analyzed three major fault complexes, (i) the Måsøy Fault Complex, (ii) the Rolvsøya fault, and (iii) the Troms-Finnmark Fault Complex. We discuss the formation of the Måsøy Fault Complex as a possible extensional splay of an overall NE-SW-trending, NW-dipping, basement-seated Caledonian shear zone, the Sørøya-Ingøya shear zone, which was partly inverted during the collapse of the Caledonides and accommodated top-NW normal displacement in Middle to Late Devonian-Carboniferous times. The Troms-Finnmark Fault Complex displays a zigzag-shaped pattern of NNE-SSW- and ENE-WSW-trending extensional faults before it terminates to the north as a WNW-ESE-trending, NE-dipping normal fault that separates the southwesternmost Nordkapp basin in the northeast from the western Finnmark Platform and the Gjesvær Low in the southwest. The WNW-ESE-trending, margin-oblique segment of the Troms-Finnmark Fault Complex is considered to represent the offshore prolongation of a major Neoproterozoic fault complex, the Trollfjorden-Komagelva Fault Zone, which is made of WNW-ESE-trending, subvertical faults that crop out on the island of Magerøya in NW Finnmark. Our results suggest that the Trollfjorden-Komagelva Fault Zone dies out to the northwest before reaching the western Finnmark Platform. We propose an alternative model for the origin of the WNW-ESE-trending segment of the Troms-Finnmark Fault Complex as a possible hard-linked, accommodation cross fault that developed along the Sørøy-Ingøya shear zone. This brittle fault decoupled the western Finnmark Platform from the southwesternmost Nordkapp basin and merged with the Måsøy Fault Complex in Carboniferous times. Seismic data over the Gjesvær Low and southwesternmost Nordkapp basin show that the low-gravity anomaly observed in these areas may result from the presence of Middle to Upper Devonian sedimentary units resembling those in Middle Devonian, spoon-shaped, late- to post-orogenic collapse basins in western and mid-Norway. We propose a model for the formation of the southwesternmost Nordkapp basin and its counterpart Devonian basin in the Gjesvær Low by exhumation of narrow, ENE-WSW- to NE-SW-trending basement ridges along a bowed portion of the Sørøya-Ingøya shear zone in the Middle to Late Devonian-early Carboniferous. Exhumation may have involved part of a large-scale metamorphic core complex that potentially included the Lofoten Ridge, the West Troms Basement Complex and the Norsel High. Finally, we argue that the Sørøya-Ingøya shear zone truncated and decapitated the Trollfjorden-Komagelva Fault Zone during the Caledonian Orogeny and that the western continuation of the Trollfjorden-Komagelva Fault Zone was mostly eroded and potentially partly preserved in basement highs in the SW Barents Sea.

Middle Devonian to Late Mississippian event stratigraphy of Overthrust belt region, western United States.

USGS Publications Warehouse

Sandberg, C.A.; Gutschick, R.C.; Johnson, J.G.; Poole, F.G.; Sando, W.J.

1986-01-01

Twenty eustatic and epeirogenic events mainly dated by conodonts are distinguished between the Middle Devonian and the lower Upper Mississippian in Great Basin, in Rocky Mountains and in the Overthrust belt regions.-Journal Editors

The Cannery Formation--Devonian to Early Permian arc-marginal deposits within the Alexander Terrane, Southeastern Alaska

USGS Publications Warehouse

Karl, Susan M.; Layer, Paul W.; Harris, Anita G.; Haeussler, Peter J.; Murchey, Benita L.

2011-01-01

The Cannery Formation consists of green, red, and gray ribbon chert, siliceous siltstone, graywacke-chert turbidites, and volcaniclastic sandstone. Because it contains early Permian fossils at and near its type area in Cannery Cove, on Admiralty Island in southeastern Alaska, the formation was originally defined as a Permian stratigraphic unit. Similar rocks exposed in Windfall Harbor on Admiralty Island contain early Permian bryozoans and brachiopods, as well as Mississippian through Permian radiolarians. Black and green bedded chert with subordinate lenses of limestone, basalt, and graywacke near Kake on Kupreanof Island was initially correlated with the Cannery Formation on the basis of similar lithology but was later determined to contain Late Devonian conodonts. Permian conglomerate in Keku Strait contains chert cobbles inferred to be derived from the Cannery Formation that yielded Devonian and Mississippian radiolarians. On the basis of fossils recovered from a limestone lens near Kake and chert cobbles in the Keku Strait area, the age of the Cannery Formation was revised to Devonian and Mississippian, but this revision excludes rocks in the type locality, in addition to excluding bedded chert on Kupreanof Island east of Kake that contains radiolarians of Late Pennsylvanian and early Permian age. The black chert near Kake that yielded Late Devonian conodonts is nearly contemporaneous with black chert interbedded with limestone that also contains Late Devonian conodonts in the Saginaw Bay Formation on Kuiu Island. The chert cobbles in the conglomerate in Keku Strait may be derived from either the Cannery Formation or the Saginaw Bay Formation and need not restrict the age of the Cannery Formation, regardless of their source. The minimum age of the Cannery Formation on both Admiralty Island and Kupreanof Island is constrained by the stratigraphically overlying fossiliferous Pybus Formation, of late early and early late Permian age. Because bedded radiolarian cherts on both Admiralty and Kupreanof Islands contain radiolarians as young as Permian, the age of the Cannery Formation is herein extended to Late Devonian through early Permian, to include the early Permian rocks exposed in its type locality. The Cannery Formation is folded and faulted, and its stratigraphic thickness is unknown but inferred to be several hundred meters. The Cannery Formation represents an extended period of marine deposition in moderately deep water, with slow rates of deposition and limited clastic input during Devonian through Pennsylvanian time and increasing argillaceous, volcaniclastic, and bioclastic input during the Permian. The Cannery Formation comprises upper Paleozoic rocks in the Alexander terrane of southeastern Alaska. In the pre-Permian upper Paleozoic, the tectonic setting of the Alexander terrane consisted of two or more evolved oceanic arcs. The lower Permian section is represented by a distinctive suite of rocks in the Alexander terrane, which includes sedimentary and volcanic rocks containing early Permian fossils, metamorphosed rocks with early Permian cooling ages, and intrusive rocks with early Permian cooling ages, that form discrete northwest-trending belts. After restoration of 180 km of dextral displacement of the Chilkat-Chichagof block on the Chatham Strait Fault, these belts consist, from northeast to southwest, of (1) bedded chert, siliceous argillite, volcaniclastic turbidites, pillow basalt, and limestone of the Cannery Formation and the Porcupine Slate of Gilbert and others (1987); (2) greenschist-facies Paleozoic metasedimentary and metavolcanic rocks that have Permian cooling ages; (3) silty limestone and calcareous argillite interbedded with pillow basalt and volcaniclastic rocks of the Halleck Formation and the William Henry Bay area; and (4) intermediate-composition and syenitic plutons. These belts correspond to components of an accretionary complex, contemporary metamorphic rocks, forearc-basin deposits,

Bedrock geology of the Mount Carmel and Southington quadrangles, Connecticut

USGS Publications Warehouse

Fritts, Crawford Ellswroth

1962-01-01

New data concerning the geologic structure, stratigraphy, petrography, origin, and ages of bedrock formations in an area of approximately 111 square miles in south-central Connecticut were obtained in the course of detailed geologic mapping from 1957 to 1960. Mapping was done at a scale of 1:24,000 on topographic base maps having a 10-foot contour interval. Bedrock formations are classified in two principal categories. The first includes metasedimentary, meta-igneous, and igneous rocks of Precambrian to Devonian age, which crop out in the western parts of both quadrangles. The second includes sedimentary and igneous rocks of the Newark Group of Late Triassic age, which crop out in the eastern parts of the quadrangles. Diabase dikes, which are Late Triassic or younger in age, intruded rocks in both the western and eastern parts of the map area. Rocks in the western part of the area underwent progressive regional metamorphism in Middle to Late Devonian time. The arrangement of the chlorite, garnet, biotite, staurolite, and kyanite zones here is approximately the mirror-image of metamorphic zones in Dutchess County, New York. However, garnet appeared before biotite in politic rocks in the map area, because the ration MgO/FeO is low. Waterbury Gneiss and the intrusive Woodtick Gneiss are parts of a basement complex of Precambrian age, which forms the core of the Waterbury dome. This structure is near the southern end of a line of similar domes that lie along the crest of a geanticline east of the Green Mountain anticlinorium. The Waterbury Gneiss is believed to have been metamorphosed in Precambrian time as well as in Paleozoic time. The Woodtick Gneiss also may have been metamorphosed more than once. In Paleozoic time, sediments were deposited in geosynclines during two main cycles of sedimentation. The Straits, Southington Mountain, and Derby Hill Schists, which range in age from Cambrian to Ordovician, reflect a transition from relatively clean politic sediments to thinly layered sediments that contained rather high percentages of fine-grained volcanic debris. Metadiabase and metabasalt extrusives above Derby Hill Schist south of the map area represent more intense volcanic activity before or during the early stages of the Taconic disturbance in Late Ordovician time. Impure argillaceous, siliceous, and minor calcareous sediments of the Wepawaug Schist, which is Silurian and Devonian in age, were deposited unconformably on older rocks during renewed subsidence of a geosyncline. The Wepawaug now occupies the trough of a tight syncline, which formed before and during progressive regional metamorphism at the time of the Acadian orogeny in middle to Late Devonian time. Felsic igneous rocks were intruded into the metasedimentary formations of Paleozoic age before the climax of the latest progressive regional metamorphism. Intrusives that gave rise to the Prospect and Ansonia Gneisses were emplaced mainly in the Southington Mountain Schist, and the igneous rocks as well as the host rocks were metamorphosed in the staurolite zone. Although it is possible that these two intrusives were emplaced during the Taconic disturbance, the writer believes it more likely that the igneous rocks from which the Prospect and Ansonia Gneisses formed were emplaced during the Acadian orogeny. Woodbridge Granite, which intruded the Wepawaug Schist, is Devonian in age and undoubtedly was emplaced during the Acadian orogeny. In this area the granite is essentially unmetamorphosed, because it is in the chlorite, garnet, and biotite zones. Southwest of the map area, however, metamorphic equivalents of the Woodbridge are found in Wepawaug Schist in the staurolite zone. The Ansonia Gneiss, therefore, may be a metamorphic equivalent of the Woodbridge Granite. Rocks of Late Triassic age formerly covered the entire map area, but were eroded from the western part after tilting and faulting in Late Triassic time. The New Haven Arkose of the Newark

Plate tectonic history of the Arctic

NASA Technical Reports Server (NTRS)

Burke, K.

1984-01-01

Tectonic development of the Arctic Ocean is outlined, and geological maps are provided for the Arctic during the mid-Cenozoic, later Cretaceous, late Jurassic, early Cretaceous, early Jurassic and late Devonian. It is concluded that Arctic basin history is moulded by the events of the following intervals: (1) continental collision and immediately subsequent rifting and ocean formation in the Devonian, and continental rifting ocean formation, rapid rotation of microcontinents, and another episode of collision in the latest Jurassic and Cretaceous. It is noted that Cenozoic Arctic basin formation is a smaller scale event superimposed on the late Mesozoic ocean basin.

Ichnology applied to sequence stratigraphic analysis of Siluro-Devonian mud-dominated shelf deposits, Paraná Basin, Brazil

NASA Astrophysics Data System (ADS)

Sedorko, Daniel; Netto, Renata G.; Savrda, Charles E.

2018-04-01

Previous studies of the Paraná Supersequence (Furnas and Ponta Grossa formations) of the Paraná Basin in southern Brazil have yielded disparate sequence stratigraphic interpretations. An integrated sedimentological, paleontological, and ichnological model was created to establish a refined sequence stratigraphic framework for this succession, focusing on the Ponta Grossa Formation. Twenty-nine ichnotaxa are recognized in the Ponta Grossa Formation, recurring assemblages of which define five trace fossil suites that represent various expressions of the Skolithos, Glossifungites and Cruziana ichnofacies. Physical sedimentologic characteristics and associated softground ichnofacies provide the basis for recognizing seven facies that reflect a passive relationship to bathymetric gradients from shallow marine (shoreface) to offshore deposition. The vertical distribution of facies provides the basis for dividing the Ponta Grossa Formation into three major (3rd-order) depositional sequences- Siluro-Devonian and Devonian I and II-each containing a record of three to seven higher-order relative sea-level cycles. Major sequence boundaries, commonly coinciding with hiatuses recognized from previously published biostratigraphic data, are locally marked by firmground Glossifungites Ichnofacies associated with submarine erosion. Maximum transgressive horizons are prominently marked by unbioturbated or weakly bioturbated black shales. By integrating observations of the Ponta Grossa Formation with those recently made on the underlying marginal- to shallow-marine Furnas Formation, the entire Paraná Supersequence can be divided into four disconformity-bound sequences: a Lower Silurian (Llandovery-Wenlock) sequence, corresponding to lower and middle units of the Furnas; a Siluro-Devonian sequence (?Pridoli-Early Emsian), and Devonian sequences I (Late Emsian-Late Eifelian) and II (Late Eifelian-Early Givetian). Stratigraphic positions of sequence boundaries generally coincide with regressive phases on established global sea-level curves for the Silurian-Devonian.

Late Devonian shale deposition based on known and predicted occurrence of Foerstia in Michigan basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Matthews, R.D.

The fossil Foerstia (Protosalvinia) marks a time zone within Late Devonian shale sequences in the eastern US. Its recent discovery in Michigan has led to more accurate correlations among the three large eastern basins. Subdivisions of the Devonian-Mississippi shale sequence in Michigan based on gamma-ray correlations reveal an idealized black shale geometry common to other eastern black shales, such as the Sunbury of Michigan and Ohio, the Clegg Creek of Indiana, the Dunkirk of Pennsylvania and New York, and the lower Huron of Ohio and West Virginia. In Michigan, Foerstia occurs at a stratigraphic position postulated to mark a majormore » change in depositional conditions and source areas. This position strengthens the physical and paleontologic evidence for a formal division of the Antrim. Isopach maps of the shale sequence above and below Foerstia show a relatively uniform and continuous black shale deposit (units 1A, 1B, and 1C) below Foerstia. This deposit is unlike the wedge of sediment found above Foerstia, which is composed of a western facies (Ellsworth) and an eastern facies (upper Antrim) that should be combined in a single stratigraphic unit conforming to Forgotson's concept of a format.« less

From success to persistence: Identifying an evolutionary regime shift in the diverse Paleozoic aquatic arthropod group Eurypterida, driven by the Devonian biotic crisis.

PubMed

Lamsdell, James C; Selden, Paul A

2017-01-01

Mass extinctions have altered the trajectory of evolution a number of times over the Phanerozoic. During these periods of biotic upheaval a different selective regime appears to operate, although it is still unclear whether consistent survivorship rules apply across different extinction events. We compare variations in diversity and disparity across the evolutionary history of a major Paleozoic arthropod group, the Eurypterida. Using these data, we explore the group's transition from a successful, dynamic clade to a stagnant persistent lineage, pinpointing the Devonian as the period during which this evolutionary regime shift occurred. The late Devonian biotic crisis is potentially unique among the "Big Five" mass extinctions in exhibiting a drop in speciation rates rather than an increase in extinction. Our study reveals eurypterids show depressed speciation rates throughout the Devonian but no abnormal peaks in extinction. Loss of morphospace occupation is random across all Paleozoic extinction events; however, differential origination during the Devonian results in a migration and subsequent stagnation of occupied morphospace. This shift appears linked to an ecological transition from euryhaline taxa to freshwater species with low morphological diversity alongside a decrease in endemism. These results demonstrate the importance of the Devonian biotic crisis in reshaping Paleozoic ecosystems. © 2016 The Author(s). Evolution © 2016 The Society for the Study of Evolution.

Geometry, kinematics and tectonic models of the Kazakhstan Orocline, Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Li, Pengfei; Sun, Min; Rosenbaum, Gideon; Yuan, Chao; Safonova, Inna; Cai, Keda; Jiang, Yingde; Zhang, Yunying

2018-03-01

The Central Asian Orogenic Belt (CAOB) is one of the largest accretionary orogens on Earth and is characterized by the occurrence of tight oroclines (Kazakhstan and Tuva-Mongolian oroclines). The origin of these large-scale orogenic curvatures is not quite understood, but is fundamentally important for understanding crustal growth and tectonic evolution of the CAOB. Here we provide an outline of available geological and paleomagnetic data around the Kazakhstan Orocline, with an aim of clarifying the geometry, kinematics and geodynamic origin of the orocline. The Kazakhstan Orocline is evident in a total magmatic image, and can be traced by the continuation of high magnetic anomalies associated with the Devonian Volcanic Belt and the Late Devonian to Carboniferous Balkhash-Yili arc. Paleomagnetic data show ∼112-126° clockwise rotation of the northern limb relative to the southern limb in the Late Devonian to Early Carboniferous, as well as ∼15-28° clockwise rotation of the northern limb and ∼39-40° anticlockwise rotation of the southern limb relative to the hinge of the orocline during the Late Carboniferous to Permian. We argue that the Kazakhstan Orocline experienced two-stage bending with the early stage of bending (Late Devonian to Early Carboniferous; ∼112-126°) driven by slab rollback, and the later stage (Late Carboniferous to Permian; 54-68°) possibly associated with the amalgamation of the Siberian, Tarim and Baltic cratons. This new tectonic model is compatible with the occurrence of rift basins, the spatial migration of magmatic arc, and the development of large-scale strike-slip fault systems during oroclinal bending.

Rotational and accretionary evolution of the Klamath Mountains, California and Oregon, from Devonian to present time

USGS Publications Warehouse

Irwin, William P.; Mankinen, Edward A.

1998-01-01

The purpose of this report is to show graphically how the Klamath Mountains grew from a relatively small nucleus in Early Devonian time to its present size while rotating clockwise approximately 110°. This growth occurred by the addition of large tectonic slices of oceanic lithosphere, volcanic arcs, and melange during a sequence of accretionary episodes. The Klamath Mountains province consists of eight lithotectonoic units called terranes, some of which are divided into subterranes. The Eastern Klamath terrane, which was the early Paleozoic nucleus of the province, is divided into the Yreka, Trinity, and Redding subterranes. Through tectonic plate motion, usually involving subduction, the other terranes joined the early Paleozoic nucleus during seven accretionary episodes ranging in age from Early Devonian to Late Jurassic. The active terrane suture is shown for each episode by a bold black line. Much of the western boundary of the Klamath Mountains is marked by the South Fork and correlative faults along which the Klamath terranes overrode the Coast Range rocks during an eighth accretionary episode, forming the South Fork Mountain Schist in Early Cretaceous time.

Timing of terrane accretion in eastern and east-central Maine

NASA Astrophysics Data System (ADS)

Ludman, Allan

1986-05-01

The Norumbega fault zone is often cited as a post-Acadian suture between exotic blocks, even though stratigraphic, structural, and metamorphic data indicate that there is little offset of the Silurian-Devonian strata that the zone cuts in eastern Maine. Similarly, the Kingman fault zone has been shown by gravity and geochemical studies to separate distinct crustal blocks, whereas mapping shows that it lies entirely within a Silurian turbidite package. These conflicts are resolved if the two fault zones represent boundaries between Ordovician or older crustal blocks that had accreted to form a composite terrane prior to deposition of the cover sequences. The faults now mapped within these younger rocks formed by reactivation of the pre-Silurian boundaries during late Acadian time; movement continued until the late Carboniferous. Most of the accretionary history of Maine had thus ended before the Silurian. A complex composite terrane may have formed during Cambrian-Ordovician time that (1) interacted with cratonic North America during the Taconian orogeny and (2) became the “basement” upon which the Silurian and Lower Devonian strata of eastern Maine were deposited.

The first direct evidence of a Late Devonian coelacanth fish feeding on conodont animals

NASA Astrophysics Data System (ADS)

Zatoń, Michał; Broda, Krzysztof; Qvarnström, Martin; Niedźwiedzki, Grzegorz; Ahlberg, Per Erik

2017-04-01

We describe the first known occurrence of a Devonian coelacanth specimen from the lower Famennian of the Holy Cross Mountains, Poland, with a conodont element preserved in its digestive tract. A small spiral and phosphatic coprolite (fossil excrement) containing numerous conodont elements and other unrecognized remains was also found in the same deposits. The coprolite is tentatively attributed to the coelacanth. Although it is unclear whether the Late Devonian coelacanth from Poland was an active predator or a scavenger, these finds provide the first direct evidence of feeding on conodont animals by early coelacanth fish, and one of the few evidences of feeding on these animals known to date. It also expands our knowledge about the diet and trophic relations between the Paleozoic marine animals in general.

Air-breathing adaptation in a marine Devonian lungfish.

PubMed

Clement, Alice M; Long, John A

2010-08-23

Recent discoveries of tetrapod trackways in 395 Myr old tidal zone deposits of Poland (Niedźwiedzki et al. 2010 Nature 463, 43-48 (doi:10.1038/nature.08623)) indicate that vertebrates had already ventured out of the water and might already have developed some air-breathing capacity by the Middle Devonian. Air-breathing in lungfishes is not considered to be a shared specialization with tetrapods, but evolved independently. Air-breathing in lungfishes has been postulated as starting in Middle Devonian times (ca 385 Ma) in freshwater habitats, based on a set of skeletal characters involved in air-breathing in extant lungfishes. New discoveries described herein of the lungfish Rhinodipterus from marine limestones of Australia identifies the node in dipnoan phylogeny where air-breathing begins, and confirms that lungfishes living in marine habitats had also developed specializations to breathe air by the start of the Late Devonian (ca 375 Ma). While invasion of freshwater habitats from the marine realm was previously suggested to be the prime cause of aerial respiration developing in lungfishes, we believe that global decline in oxygen levels during the Middle Devonian combined with higher metabolic costs is a more likely driver of air-breathing ability, which developed in both marine and freshwater lungfishes and tetrapodomorph fishes such as Gogonasus.

Air-breathing adaptation in a marine Devonian lungfish

PubMed Central

Clement, Alice M.; Long, John A.

2010-01-01

Recent discoveries of tetrapod trackways in 395 Myr old tidal zone deposits of Poland (Niedźwiedzki et al. 2010 Nature 463, 43–48 (doi:10.1038/nature.08623)) indicate that vertebrates had already ventured out of the water and might already have developed some air-breathing capacity by the Middle Devonian. Air-breathing in lungfishes is not considered to be a shared specialization with tetrapods, but evolved independently. Air-breathing in lungfishes has been postulated as starting in Middle Devonian times (ca 385 Ma) in freshwater habitats, based on a set of skeletal characters involved in air-breathing in extant lungfishes. New discoveries described herein of the lungfish Rhinodipterus from marine limestones of Australia identifies the node in dipnoan phylogeny where air-breathing begins, and confirms that lungfishes living in marine habitats had also developed specializations to breathe air by the start of the Late Devonian (ca 375 Ma). While invasion of freshwater habitats from the marine realm was previously suggested to be the prime cause of aerial respiration developing in lungfishes, we believe that global decline in oxygen levels during the Middle Devonian combined with higher metabolic costs is a more likely driver of air-breathing ability, which developed in both marine and freshwater lungfishes and tetrapodomorph fishes such as Gogonasus. PMID:20147310

Birth and demise of the Rheic Ocean magmatic arc(s): Combined U-Pb and Hf isotope analyses in detrital zircon from SW Iberia siliciclastic strata

NASA Astrophysics Data System (ADS)

Pereira, M. F.; Gutíerrez-Alonso, G.; Murphy, J. B.; Drost, K.; Gama, C.; Silva, J. B.

2017-05-01

Paleozoic continental reconstructions indicate that subduction of Rheic oceanic lithosphere led to collision between Laurussia and Gondwana which was a major event in the formation of the Ouachita-Appalachian-Variscan orogenic belt and the amalgamation of Pangea. However, arc systems which record Rheic Ocean subduction are poorly preserved. The preservation of Devonian detrital zircon in Late Devonian-Early Carboniferous siliciclastic rocks of SW Iberia, rather than arc-related igneous rocks indicates that direct evidence of the arc system may have been largely destroyed by erosion. Here we report in-situ detrital zircon U-Pb isotopic analyses of Late Devonian-Early Carboniferous siliciclastic rocks from the Pulo do Lobo Zone, which is a reworked Late Paleozoic suture zone located between Laurussia and Gondwana. Detrital zircon age spectra from the Pulo do Lobo Zone Frasnian formations show striking similarities, revealing a wide range of ages dominated by Neoproterozoic and Paleoproterozoic grains sourced from rocks typical of peri-Gondwanan terranes, such as Avalonia, the Meguma terrane and the Ossa-Morena Zone. Pulo do Lobo rocks also include representative populations of Mesoproterozoic and Early Silurian zircons that are typical of Avalonia and the Meguma terrane which are absent in the Ossa-Morena Zone. The Famennian-Tournaisian formations from the Pulo do Lobo Zone, however, contain more abundant Middle-Late Devonian zircon indicating the contribution from a previously unrecognized source probably related to the Rheic Ocean magmatic arc(s). The Middle-Late Devonian to Early Carboniferous zircon ages from the siliciclastic rocks of SW Iberia (South Portuguese, Pulo do Lobo and Ossa-Morena zones) have a wide range in εHfT values (- 8.2 to + 8.3) indicating the likely crystallization from magmas formed in a convergent setting. The missing Rheic Ocean arc was probably built on a Meguma/Avalonia type basement. We propose for the Pulo do Lobo Zone that the Frasnian sedimentation occurred through the opening of a back-arc basin formed along the Laurussian active margin during Rheic Ocean subduction, as has been recently proposed for the Rhenohercynian Zone in Central Europe. Detrital zircon ages in the Frasnian siliciclastic rocks indicate provenance in the Meguma terrane, Avalonia and Devonian Rheic Ocean arc(s). As a result of back-arc basin inversion, the Frasnian formations underwent deformation, metamorphism and denudation and were unconformably overlain by Famennian to Visean siliciclastic strata (including the Phyllite-Quartzite Formation of the South Portuguese Zone). The Latest Devonian-Early Carboniferous detritus were probably shed to the Pulo do Lobo Zone (Represa and Santa Iria formations) by recycling of Devonian siliciclastic rocks, from the South Portuguese Zone (Meguma terrane) and from a new distinct source with Baltica/Laurentia derivation (preserved in the Horta da Torre Formation and Alajar Mélange).

The north-subducting Rheic Ocean during the Devonian: consequences for the Rhenohercynian ore sites

NASA Astrophysics Data System (ADS)

von Raumer, Jürgen F.; Nesbor, Heinz-Dieter; Stampfli, Gérard M.

2017-10-01

Base metal mining in the Rhenohercynian Zone has a long history. Middle-Upper Devonian to Lower Carboniferous sediment-hosted massive sulfide deposits (SHMS), volcanic-hosted massive sulfide deposits (VHMS) and Lahn-Dill-type iron, and base metal ores occur at several sites in the Rhenohercynian Zone that stretches from the South Portuguese Zone, through the Lizard area, the Rhenish Massif and the Harz Mountain to the Moravo-Silesian Zone of SW Bohemia. During Devonian to Early Carboniferous times, the Rhenohercynian Zone is seen as an evolving rift system developed on subsiding shelf areas of the Old Red continent. A reappraisal of the geotectonic setting of these ore deposits is proposed. The Middle-Upper Devonian to Early Carboniferous time period was characterized by detrital sedimentation, continental intraplate and subduction-related volcanism. The large shelf of the Devonian Old Red continent was the place of thermal subsidence with contemporaneous mobilization of rising thermal fluids along activated Early Devonian growth faults. Hydrothermal brines equilibrated with the basement and overlying Middle-Upper Devonian detrital deposits forming the SHMS deposits in the southern part of the Pyrite Belt, in the Rhenish Massif and in the Harz areas. Volcanic-hosted massive sulfide deposits (VHMS) formed in the more eastern localities of the Rhenohercynian domain. In contrast, since the Tournaisian period of ore formation, dominant pull-apart triggered magmatic emplacement of acidic rocks, and their metasomatic replacement in the apical zones of felsic domes and sediments in the northern part of the Iberian Pyrite belt, thus changing the general conditions of ore precipitation. This two-step evolution is thought to be controlled by syn- to post-tectonic phases in the Variscan framework, specifically by the transition of geotectonic setting dominated by crustal extension to a one characterized by the subduction of the supposed northern slab of the Rheic Ocean preceding the general Late Variscan crustal shortening and oroclinal bending.

Devonian and Mississippian rocks of the northern Antelope Range, Eureka County, Nevada

USGS Publications Warehouse

Hose, Richard Kenneth; Armstrong, A.K.; Harris, A.G.; Mamet, B.L.

1982-01-01

Lower through Upper Devonian rocks of the northern Antelope Range, Nev., consist of four formational rank units more than 800 m thick, separated from Mississippian units by an unconformity. The lower three Devonian units, the Beacon Peak Dolomite, McColley Canyon Formation, and Denay Limestone are known in other areas; the top unit, the Fenstermaker Wash Formation, is new. The Mississippian units, more than 280 m thick, are divisible into three units which are unlike coeval units elsewhere, and are herein named the Davis Spring Formation, Kinkead Spring Limestone, and Antelope Range Formation. Systematic sampling of the Devonian sequence has yielded relatively abundant conodonts containing several biostratigraphic ally significant taxa. The Mississippian units contain redeposited conodonts of chiefly Late Devonian and Early Mississippian (Kinderhookian) age together with indigenous Osagean foraminifers and algae in the Kinkead Spring Limestone.

First recognition of the genus Verneuilia Hall and Clarke (Brachiopoda, Spiriferida) from North America (west-central Alaska)

USGS Publications Warehouse

Blodgett, R.B.; Johnson, J.G.

1994-01-01

The brachiopod genus Verneuilia Hall and Clarke, 1893, is recognized for the first time in North America, where it is represented by a new species described here. V. langenstrasseni. This occurrence extends not only the geographic range of the genus, but also the lower age and stratigraphic limit into the Eifelian (early Middle Devonian). Previously, the oldest known species was the type, V. cheiropteryx d'Archiac and de Verneuil, 1842, from the Givetian (late Middle Devonian) of Germany. Internal structures of V. langenstrasseni n.sp. are similar to those of genera in the ambocoeliid subfamily Rhynchospiriferinae, providing the first good evidence of a systematic relationship. -Authors

The diversification of Paleozoic fire systems and fluctuations in atmospheric oxygen concentration

PubMed Central

Scott, Andrew C.; Glasspool, Ian J.

2006-01-01

By comparing Silurian through end Permian [≈250 million years (Myr)] charcoal abundance with contemporaneous macroecological changes in vegetation and climate we aim to demonstrate that long-term variations in fire occurrence and fire system diversification are related to fluctuations in Late Paleozoic atmospheric oxygen concentration. Charcoal, a proxy for fire, occurs in the fossil record from the Late Silurian (≈420 Myr) to the present. Its presence at any interval in the fossil record is already taken to constrain atmospheric oxygen within the range of 13% to 35% (the “fire window”). Herein, we observe that, as predicted, atmospheric oxygen levels rise from ≈13% in the Late Devonian to ≈30% in the Late Permian so, too, fires progressively occur in an increasing diversity of ecosystems. Sequentially, data of note include: the occurrence of charcoal in the Late Silurian/Early Devonian, indicating the burning of a diminutive, dominantly rhyniophytoid vegetation; an apparent paucity of charcoal in the Middle to Late Devonian that coincides with a predicted atmospheric oxygen low; and the subsequent diversification of fire systems throughout the remainder of the Late Paleozoic. First, fires become widespread during the Early Mississippian, they then become commonplace in mire systems in the Middle Mississippian; in the Pennsylvanian they are first recorded in upland settings and finally, based on coal petrology, become extremely important in many Permian mire settings. These trends conform well to changes in atmospheric oxygen concentration, as predicted by modeling, and indicate oxygen levels are a significant control on long-term fire occurrence. PMID:16832054

Sequences, stratigraphy and scenarios: what can we say about the fossil record of the earliest tetrapods?

PubMed

Friedman, Matt; Brazeau, Martin D

2011-02-07

Past research on the emergence of digit-bearing tetrapods has led to the widely accepted premise that this important evolutionary event occurred during the Late Devonian. The discovery of convincing digit-bearing tetrapod trackways of early Middle Devonian age in Poland has upset this orthodoxy, indicating that current scenarios which link the timing of the origin of digited tetrapods to specific events in Earth history are likely to be in error. Inspired by this find, we examine the fossil record of early digit-bearing tetrapods and their closest fish-like relatives from a statistical standpoint. We find that the Polish trackways force a substantial reconsideration of the nature of the early tetrapod record when only body fossils are considered. However, the effect is less drastic (and often not statistically significant) when other reliably dated trackways that were previously considered anachronistic are taken into account. Using two approaches, we find that 95 per cent credible and confidence intervals for the origin of digit-bearing tetrapods extend into the Early Devonian and beyond, spanning late Emsian to mid Ludlow. For biologically realistic diversity models, estimated genus-level preservation rates for Devonian digited tetrapods and their relatives range from 0.025 to 0.073 per lineage-million years, an order of magnitude lower than species-level rates for groups typically considered to have dense records. Available fossils of early digited tetrapods and their immediate relatives are adequate for documenting large-scale patterns of character acquisition associated with the origin of terrestriality, but low preservation rates coupled with clear geographical and stratigraphic sampling biases caution against building scenarios for the origin of digits and terrestrialization tied to the provenance of particular specimens or faunas.

Unsuspected functional disparity in Devonian fishes revealed by tooth morphometrics?

NASA Astrophysics Data System (ADS)

Gauchey, Samuel; Girard, Catherine; Adnet, Sylvain; Renaud, Sabrina

2014-09-01

The shape of features involved in key biological functions, such as teeth in nutrition, can provide insights into ecological processes even in ancient time, by linking the occupation of the morphological space (disparity) to the occupation of the ecological space. Investigating disparity in radiating groups may provide insights into the ecological diversification underlying evolution of morphological diversity. Actinopterygian fishes initiated their radiation in the Devonian, a period characterized by the diversification of marine ecosystem. Although a former morpho-functional analysis of jaw shape concluded to conservative and poorly diversified morphologies in this early part of their history, fish tooth disparity evidenced here an unsuspected diversity of possible functional significance in the pivotal period of the Late Devonian (Famennian). All teeth being caniniforms, some were stocky and robust, in agreement with expectations for active generalist predators. More surprisingly, elongated teeth also occurred at the beginning of Famennian. Their needle-like shape challenges morpho-functional interpretations by making them fragile in response to bending or torsion. The occurrence of both types of fish teeth during the beginning of the Famennian points to a discrete but real increase in disparity, thus testifying a first burst of feeding specialization despite overall conservative jaw morphology. The disappearance of these needle-like teeth in the Late Famennian might have been related to a relay in dental diversity with abundant co-occurring groups, namely conodonts and chondrichthyans (sharks).

Late Devonian conodonts and event stratigraphy in northwestern Algerian Sahara

NASA Astrophysics Data System (ADS)

Mahboubi, Abdessamed; Gatovsky, Yury

2015-01-01

Conodonts recovered from the Late Devonian South Marhouma section comprise 5 genera with 31 species (3 undetermined). The fauna establishes the presence of MN Zones 5, undifferentiated 6/7, 8/10 for the Middle Frasnian, the MN Zones 11, 12, 13 for the Upper Frasnian as well as the Early through Late triangularis Zones in the basal Famennian. The outcropping lithological succession is one of mostly nodular calcilutites alternating with numerous marly and shaly deposits, which, in the lower and upper part, comprise several dysoxic dark shale intervals. Among these the Upper Kellwasser horizon can be precisely dated and as such the presence of the terminal Frasnian Kellwasser Event is recognized for the first time in Algeria. Both the Middlesex and Rhinestreet Events cannot yet be precisely located, but supposedly occur among the dark shale horizons in the lower part of the section. However, their assignment to a precise level has so far not been established. Though poor in conodont abundance the South Marhouma section provides first evidence of the presence of several Montagne Noire conodont zones within the so far widely unstudied Frasnian of the Ougarta Chain. As such it is considered representative for the northwestern Algerian Saoura region.

Global climatic changes during the Devonian-Mississippian: Stable isotope biogeochemistry of brachiopods

NASA Astrophysics Data System (ADS)

Brand, Uwe

1989-12-01

A progressive trend towards heavier δ 13C values of Devonian-Mississippian brachiopods from North America, Europe, Afghanistan and Algeria probably reflects expansion of the terrestrestrial and/or marine biomass and/or burial of carbon in soils/sediments. Oceanic Productivity crises, based on perturbations in the overall δ 13C trend, are recognized for the Mid Givetian, Early Famennian, Late Kinderhookian, Late Osagean and Early and Late Meramecian. The Givetian productivity crisis was probably accompanied by massive overturn of biologically toxic deep-ocean water. Temperature data, adjusted for the possible secular variation of seawater, support the hypothesis of global greenhouse conditions for the Devonian (mean of 30°C, mean of 26°C if extrinsic data are deleted) and icehouse conditions for the Mississippian (mean of 17°C). During the Mid Givetian, Frasnian and Early Famennian calculated water temperatures for tropical epeiric seas were generally above the thermal threshold limit (˜ 38°C) of most marine invertebrates or epeiric seawater was characterized by unusually low salinities (˜ pp ppt) or a combination of the two. These elevated water temperatures and/or low salinities, in conjunction with the postulated productivity crises and overturning of toxic deep waters are considered prime causes for the biotic crisis of the Late Devonian. In addition, a presumed expanding oxygen-minimum zone and general anoxia in the oceans prevented shallow-water organisms from escaping these inhospitable conditions. Re-population of the tropical seas occurred, after either water temperatures had dropped below the thermal threshold limit and/or salinities were back to normal, and oceanic productivity had increased due to more vigorous oceanic circulation, sometime during the Mid-Late Famennian. Migration of eurythermal, shallow- and deeper-water organisms into the vacant niches of the shallow seas was possible because of, generally, slightly lower sea levels, but, more importantly of more restricted oxygen-minimum zone and generally reduced oceanic anoxia.

The carpenter fork bed, a new - and older - Black-shale unit at the base of the New Albany shale in central Kentucky: Characterization and significance

USGS Publications Warehouse

Barnett, S.F.; Ettensohn, F.R.; Norby, R.D.

1996-01-01

Black shales previously interpreted to be Late Devonian cave-fill or slide deposits are shown to be much older Middle Devonian black shales only preserved locally in Middle Devonian grabens and structural lows in central Kentucky. This newly recognized - and older -black-shale unit occurs at the base of the New Albany Shale and is named the Carpenter Fork Bed of the Portwood Member of the New Albany Shale after its only known exposure on Carpenter Fork in Boyle County, central Kentucky; two other occurrences are known from core holes in east-central Kentucky. Based on stratigraphic position and conodont biostratigraphy, the unit is Middle Devonian (Givetian: probably Middle to Upper P. varcus Zone) in age and occurs at a position represented by an unconformity atop the Middle Devonian Boyle Dolostone and its equivalents elsewhere on the outcrop belt. Based on its presence as isolated clasts in the overlying Duffin Bed of the Portwood Member, the former distribution of the unit was probably much more widespread - perhaps occurring throughout western parts of the Rome trough. Carpenter Fork black shales apparently represent an episode of subsidence or sea-level rise coincident with inception of the third tectophase of the Acadian orogeny. Deposition, however, was soon interrupted by reactivation of several fault zones in central Kentucky, perhaps in response to bulge migration accompanying start of the tectophase. As a result, much of central Kentucky was uplifted and tilted, and the Carpenter Fork Bed was largely eroded from the top of the Boyle, except in a few structural lows like the Carpenter Fork graben where a nearly complete record of Middle to early Late Devonian deposition is preserved.

An exceptionally preserved Late Devonian actinopterygian provides a new model for primitive cranial anatomy in ray-finned fishes

PubMed Central

Giles, Sam; Darras, Laurent; Clément, Gaël; Blieck, Alain; Friedman, Matt

2015-01-01

Actinopterygians (ray-finned fishes) are the most diverse living osteichthyan (bony vertebrate) group, with a rich fossil record. However, details of their earliest history during the middle Palaeozoic (Devonian) ‘Age of Fishes' remains sketchy. This stems from an uneven understanding of anatomy in early actinopterygians, with a few well-known species dominating perceptions of primitive conditions. Here we present an exceptionally preserved ray-finned fish from the Late Devonian (Middle Frasnian, ca 373 Ma) of Pas-de-Calais, northern France. This new genus is represented by a single, three-dimensionally preserved skull. CT scanning reveals the presence of an almost complete braincase along with near-fully articulated mandibular, hyoid and gill arches. The neurocranium differs from the coeval Mimipiscis in displaying a short aortic canal with a distinct posterior notch, long grooves for the lateral dorsal aortae, large vestibular fontanelles and a broad postorbital process. Identification of similar but previously unrecognized features in other Devonian actinopterygians suggests that aspects of braincase anatomy in Mimipiscis are apomorphic, questioning its ubiquity as stand-in for generalized actinopterygian conditions. However, the gill skeleton of the new form broadly corresponds to that of Mimipiscis, and adds to an emerging picture of primitive branchial architecture in crown gnathostomes. The new genus is recovered in a polytomy with Mimiidae and a subset of Devonian and stratigraphically younger actinopterygians, with no support found for a monophyletic grouping of Moythomasia with Mimiidae. PMID:26423841

Record of the Late Devonian Hangenberg global positive carbon-isotope excursion in an epeiric sea setting: Carbonate production, organic-carbon burial and paleoceanography during the late Famennian

USGS Publications Warehouse

Cramer, Bradley D.; Saltzman, Matthew R.; Day, J.E.; Witzke, B.J.

2008-01-01

Latest Famennian marine carbonates from the mid-continent of North America were examined to investigate the Late Devonian (very late Famennian) Hangenberg positive carbon-isotope (??13 Ccarb) excursion. This global shift in the ?? 13C of marine waters began during the late Famennian Hangenberg Extinction Event that occurred during the Middle Siphonodella praesulcata conodont zone. The post-extinction recovery interval spans the Upper S. praesulcata Zone immediately below the Devonian-Carboniferous boundary. Positive excursions in ?? 13 Ccarb are often attributed to the widespread deposition of organic-rich black shales in epeiric sea settings. The Hangenberg ??13 Ccarb excursion documented in the Louisiana Limestone in this study shows the opposite trend, with peak ??13 Ccarb values corresponding to carbonate production in the U.S. mid-continent during the highstand phase of the very late Famennian post-glacial sea level rise. Our data indicate that the interval of widespread black shale deposition (Hangenberg Black Shale) predates the peak isotope values of the Hangenberg ??13 Ccarb excursion and that peak values of the Hangenberg excursion in Missouri are not coincident with and cannot be accounted for by high Corg burial in epeiric seas. We suggest instead that sequestration and burial of Corg in the deep oceans drove the peak interval of the ??13Ccarb excursion, as a result of a change in the site of deep water formation to low-latitude epeiric seas as the global climate shifted between cold and warm states.

Provenance and petrofacies, Upper Devonian sandstones, Philip Smith Mountains and Arctic quandrangles, Brooks Range, Alaska: Final report, Project No. 3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anderson, A.V.; Coney, P.J.

1987-11-01

Late Devonian sandstone beds are exposed as allochthonous sequences that extend for over 1000 km along the east-west strike of the Brooks Range in northern Alaska. These horizons, at least in part, record Late Devonian tectonism and deposition along the southern margin of the Arctic Alaska block. This study identifies clastic petrofacies in the western Philip Smith Mountains and southern Arctic quadrangles and infers the composition of the source terrane. The paleogeography is not known and the original distribution of lithofacies is uncertain, owing to the extensive post-depositional tectonism. In the study area the sandstones are exposed along rugged mountainmore » tops and high ridges. Although exposures are excellent, access is often difficult. Samples were collected from exposures near the western end of the Chandalar Shelf, Atigun Pass, and the Atigun River valley in the Philip Smith Mountains quadrangle and from the Crow Nest Creek and Ottertail Creek areas in the Arctic quadrangle. 34 refs., 17 figs.« less

Devonian post-orogenic extension-related volcano-sedimentary rocks in the northern margin of the Tibetan Plateau, NW China: Implications for the Paleozoic tectonic transition in the North Qaidam Orogen

NASA Astrophysics Data System (ADS)

Qin, Yu; Feng, Qiao; Chen, Gang; Chen, Yan; Zou, Kaizhen; Liu, Qian; Jiao, Qianqian; Zhou, Dingwu; Pan, Lihui; Gao, Jindong

2018-05-01

The Maoniushan Formation in the northern part of the North Qaidam Orogen (NQO), NW China, contains key information on a Paleozoic change in tectonic setting of the NQO from compression to extension. Here, new zircon U-Pb, petrological, and sedimentological data for the lower molasse sequence of the Maoniushan Formation are used to constrain the timing of this tectonic transition. Detrital zircons yield U-Pb ages of 3.3-0.4 Ga with major populations at 0.53-0.4, 1.0-0.56, 2.5-1.0, and 3.3-2.5 Ga. The maximum depositional age of the Maoniushan Formation is well constrained by a youngest detrital zircon age of ∼409 Ma. Comparing these dates with geochronological data for the region indicates that Proterozoic-Paleozoic zircons were derived mainly from the NQO as well as the Oulongbuluk and Qaidam blocks, whereas Archean zircons were probably derived from the Oulongbuluk Block and the Tarim Craton. The ∼924, ∼463, and ∼439 Ma tectonothermal events recorded in this region indicate that the NQO was involved in the early Neoproterozoic assembly of Rodinia and early Paleozoic microcontinental convergence. A regional angular unconformity between Devonian and pre-Devonian strata within the NQO suggests a period of strong mountain building between the Oulongbuluk and Qaidam blocks during the Silurian, whereas an Early Devonian post-orogenic molasse, evidence of extensional collapse, and Middle to Late Devonian bimodal volcanic rocks and Carboniferous marine carbonate rocks clearly reflect long-lived tectonic extension. Based on these results and the regional geology, we suggest that the Devonian volcano-sedimentary rocks within the NQO were formed in a post-orogenic extensional setting similar to that of the East Kunlun Orogen, indicating that a major tectonic transition from compression to extension in these two orogens probably commenced in the Early Devonian.

Late Paleozoic SEDEX deposits in South China formed in a carbonate platform at the northern margin of Gondwana

NASA Astrophysics Data System (ADS)

Qiu, Wenhong Johnson; Zhou, Mei-Fu; Liu, Zerui Ray

2018-05-01

SEDEX sulfide deposits hosted in black shale and carbonate are common in the South China Block. The Dajiangping pyrite deposit is the largest of these deposits and is made up of stratiform orebodies hosted in black shales. Sandstone interlayered with stratiform orebodies contains detrital zircon grains with the youngest ages of 429 Ma. Pyrite from the orebodies has a Re-Os isochron age of 389 ± 62 Ma, indicative of formation of the hosting strata and syngenetic pyrite ores in the mid-late Devonian. The hosting strata is a transgression sequence in a passive margin and composed of carbonaceous limestone in the lower part and black shales in the upper part. The ore-hosting black shales have high TOC (total organic carbon), Mo, As, Pb, Zn and Cd, indicating an anoxic-euxinic deep basin origin. The high redox proxies, V/(V + Ni) > 0.6 and V/Cr > 1, and the positive correlations of TOC with Mo and V in black shales are also consistent with an anoxic depositional environment. The Dajiangping deposit is located close to the NE-trending Wuchuan-Sihui fault, which was active during the Devonian. The mid-late Devonian mineralization age and the anoxic-euxinic deep basinal condition of this deposit thus imply that the formation of this deposit was causally linked to hydrothermal fluid exhalation in an anoxic fault-bounded basin that developed in a carbonate platform of the South China Block. The regional distribution of many Devonian, stratiform, carbonaceous sediment-hosted sulfide deposits along the NE-trending fault-bounded basins in South China, similar to the Dajiangping deposit, indicates that these deposits formed at a basin developed in the passive margin setting of the South China Block during the Devonian. This environment was caused by the break-up and northward migration of the South China Block from Gandwana.

Leaf evolution in early-diverging ferns: insights from a new fern-like plant from the Late Devonian of China

PubMed Central

Wang, De-Ming; Xu, Hong-He; Xue, Jin-Zhuang; Wang, Qi; Liu, Le

2015-01-01

Background and Aims With the exception of angiosperms, the main euphyllophyte lineages (i.e. ferns sensu lato, progymnosperms and gymnosperms) had evolved laminate leaves by the Late Devonian. The evolution of laminate leaves, however, remains unclear for early-diverging ferns, largely represented by fern-like plants. This study presents a novel fern-like taxon with pinnules, which provides new insights into the early evolution of laminate leaves in early-diverging ferns. Methods Macrofossil specimens were collected from the Upper Devonian (Famennian) Wutong Formation of Anhui and Jiangsu Provinces, South China. A standard degagement technique was employed to uncover compressed plant portions within the rock matrix. Key Results A new fern-like taxon, Shougangia bella gen. et sp. nov., is described and represents an early-diverging fern with highly derived features. It has a partially creeping stem with adventitious roots only on one side, upright primary and secondary branches arranged in helices, tertiary branches borne alternately or (sub)oppositely, laminate and usually lobed leaves with divergent veins, and complex fertile organs terminating tertiary branches and possessing multiple divisions and numerous terminal sporangia. Conclusions Shougangia bella provides unequivocal fossil evidence for laminate leaves in early-diverging ferns. It suggests that fern-like plants, along with other euphyllophyte lineages, had independently evolved megaphylls by the Late Devonian, possibly in response to a significant decline in atmospheric CO2 concentration. Among fern-like plants, planate ultimate appendages are homologous with laminate pinnules, and in the evolution of megaphylls, fertile organs tend to become complex. PMID:25979918

Geological Structure of the Basement of Western and Eastern Parts of the West-Siberian Plain

ERIC Educational Resources Information Center

Ivanov, Kirill S.; Erokhin, Yuriy V.; Ponomarev, Vladimir S.; Pogromskaya, Olga E.; Berzin, Stepan V.

2016-01-01

The U-Pb dating (SHRIMP-II on zircon) was obtained for the first time from the basement of the West Siberian Plain in the Western half of the region. It is established that a large part of the protolith of the metamorphic depth in the Shaim-Kuznetsov meganticlinorium contained sedimentary late- and middle-Devonian rocks (395-358 million years).…

No geochemical evidence for an asteroidal impact at late Devonian mass extinction horizon

NASA Astrophysics Data System (ADS)

McGhee, G. R., Jr.; Gilmore, J. S.; Orth, C. J.; Olsen, E.

1984-04-01

Three sedimentary sequences in New York State (Dunkirk Beach, Walnut Creek Gorge, and Mills Mills) and one sedimentary sequence in Belgium (Sinsin), that cross the Devonian Frasnian-Famennian boundary, were examined for an iridium (Ir) anomaly to determine whether the biotic extinctions at the end of the Cretaceous could have been caused by an asteroidal impact. The sampling at three of the four areas was on 2-cm center points, and 15 to 20 g of sample were collected. The instrumental neutron activation method required 5 g samples, and consequently the distance between samples was less than 1 cm. Though the Devonian samples studied had a high probability of locating an Ir anomaly, none was found. The highest Ir values were between 0.2 and 2 percent of those reported for the marine and terrestrial Ir analyses at the Cretaceous-Tertiary boundary, and Devonian pyrite-rich sediments did not exhibit high Ir concentrations.

Linking the southern West Junggar terrane to the Yili Block: Insights from the oldest accretionary complexes in West Junggar, NW China

NASA Astrophysics Data System (ADS)

Ren, Rong; Han, Bao-Fu; Guan, Shu-Wei; Liu, Bo; Wang, Zeng-Zhen

2018-06-01

West Junggar is known to tectonically correlate with East Kazakhstan; however, the tectonic link of the southern West Junggar terrane to adjacent regions still remains uncertain. Here, we examined the oldest accretionary complexes, thus constraining its tectonic evolution and link during the Early-Middle Paleozoic. They have contrasting lithologic, geochemical, and geochronological features and thus, provenances and tectonic settings. The Laba Unit was derived from the Late Ordovician-Early Devonian continental arc system (peaking at 450-420 Ma) with Precambrian substrate, which formed as early as the Early Devonian and metamorphosed during the Permian; however, the Kekeshayi Unit was accumulated in an intra-oceanic arc setting, and includes the pre-Late Silurian and Late Silurian subunits with or without Precambrian sources. Integrated with the regional data, the southern West Junggar terrane revealed a tectonic link to the northern Yili Block during the Late Silurian to Early Devonian, as suggested by the comparable Precambrian zircon age spectra between the southern West Junggar terrane and the micro-continents in the southern Kazakhstan Orocline, the proximal accumulation of the Laba Unit in the continental arc atop the Yili Block, and the sudden appearance of Precambrian zircons in the Kekeshayi Unit during the Late Silurian. This link rejects the proposals of the southern West Junggar terrane as an extension of the northern Kazakhstan Orocline and the Middle Paleozoic amalgamation of West Junggar. A new linking model is thus proposed, in which the southern West Junggar terrane first evolved individually, and then collided with the Yili Block to constitute the Kazakhstan continent during the Late Silurian. The independent and contrasting intra-oceanic and continental arcs also support the Paleozoic archipelago-type evolution of the Central Asian Orogenic Belt.

New U-Pb zircon ages and the duration and division of Devonian time

USGS Publications Warehouse

Tucker, R.D.; Bradley, D.C.; Ver Straeten, C.A.; Harris, A.G.; Ebert, J.R.; McCutcheon, S.R.

1998-01-01

Newly determined U-Pb zircon ages of volcanic ashes closely tied to biostratigraphic zones are used to revise the Devonian time-scale. They are: 1) 417.6 ?? 1.0 Ma for an ash within the conodont zone of Icriodus woschmidti/I. w. hesperius Lochkovian); 2) 408.3 ?? 1.9 Ma for an ash of early Emsian age correlated with the conodont zones of Po. dehiscens--Lower Po. inversus; 3) 391.4 ?? 1.8 Ma for an ash within the Po. c. costatus Zone and probably within the upper half of the zone (Eifelian); and 4) 381.1 ?? 1.3 Ma for an ash within the range of the Frasnian conodont Palmatolepis punctata (Pa. punctata Zone to Upper Pa. hassi Zone). U-Pb zircon ages for two rhyolites bracketing a palyniferous bed of the pusillites-lepidophyta spore zone, are dated at 363.8 ?? 2.2 Ma and 363 ?? 2.2 Ma and 363.4 ?? 1.8 Ma, respectively, suggesting an age of ~363 Ma for a level within the late Famennian Pa. g. expansa Zone. These data, together with other published zircon ages, suggest that the base and top of the Devonian lie close to 418 Ma and 362 Ma, respectively, thus lengthening the period of ~20% over current estimates. We suggest that the duration of the Middle Devonian (Eifelian and Givitian) is rather brief, perhaps no longer than 11.5 Myr (394 Ma-382.5 Ma), and that the Emsian and Famennian are the longest stages in the period with estimated durations of ~15.5 Myr and 14.5 Myr, respectively.

Leaf evolution in early-diverging ferns: insights from a new fern-like plant from the Late Devonian of China.

PubMed

Wang, De-Ming; Xu, Hong-He; Xue, Jin-Zhuang; Wang, Qi; Liu, Le

2015-06-01

With the exception of angiosperms, the main euphyllophyte lineages (i.e. ferns sensu lato, progymnosperms and gymnosperms) had evolved laminate leaves by the Late Devonian. The evolution of laminate leaves, however, remains unclear for early-diverging ferns, largely represented by fern-like plants. This study presents a novel fern-like taxon with pinnules, which provides new insights into the early evolution of laminate leaves in early-diverging ferns. Macrofossil specimens were collected from the Upper Devonian (Famennian) Wutong Formation of Anhui and Jiangsu Provinces, South China. A standard degagement technique was employed to uncover compressed plant portions within the rock matrix. A new fern-like taxon, SHOUGANGIA BELLA GEN ET SP NOV: , is described and represents an early-diverging fern with highly derived features. It has a partially creeping stem with adventitious roots only on one side, upright primary and secondary branches arranged in helices, tertiary branches borne alternately or (sub)oppositely, laminate and usually lobed leaves with divergent veins, and complex fertile organs terminating tertiary branches and possessing multiple divisions and numerous terminal sporangia. Shougangia bella provides unequivocal fossil evidence for laminate leaves in early-diverging ferns. It suggests that fern-like plants, along with other euphyllophyte lineages, had independently evolved megaphylls by the Late Devonian, possibly in response to a significant decline in atmospheric CO2 concentration. Among fern-like plants, planate ultimate appendages are homologous with laminate pinnules, and in the evolution of megaphylls, fertile organs tend to become complex. © The Author 2015. Published by Oxford University Press on behalf of the Annals of Botany Company. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Ontogenetic and intraspecific variation in the late Emsian - Eifelian (Devonian) conodonts Polygnathus serotinus and P. bultyncki in the Prague Basin (Czech Republic) and Nevada (western U.S.)

NASA Astrophysics Data System (ADS)

Klapper, Gilbert; Vodrážková, Stanislava

2013-06-01

Klapper, G. and Vodražkova, S. 2013. Ontogenetic and intraspecific variation in the late Emsian - Eifelian (Devonian) conodonts Polygnathus serotinus and P. bultyncki in the Prague Basin (Czech Republic) and Nevada (western U.S.). Acta Geologica Polonica, 63 (2), 153-174, Warszawa. Samples from populations of Polygnathus serotinus Telford 1975 and P. bultyncki Weddige 1977 from the Prague Basin and Nevada display normal variation for Devonian conodont species. A considerable number of previous authors, however, have proposed unnecessary synonyms of these two species, primarily because they have not recognized ontogenetic variation. In contrast, we interpret the variation as ontogenetic as well as intraspecific and present detailed synonymies as a result. A third species, P. praetrigonicus Bardashev 1992, which has been carried in open nomenclature for many years, is an important indicator of the basal costatus Zone in the Prague Basin, New York, and Nevada. We review the stratigraphic distribution of these three species and the conodont zonation across the Emsian-Eifelian (Lower-Middle Devonian) boundary. Polygnathus pseudocostatus sp. nov. (partitus-costatus zones, central Nevada) is described herein. We have observed a decrease in the pit size during ontogeny in P. bultyncki although we have not measured enough specimens to rule out intraspecific versus ontogenetic variation.

Paracontinuous boundaries within the Devonian Columbus Limestone and Delaware Formation of central Ohio

DOE Office of Scientific and Technical Information (OSTI.GOV)

Conkin, J.E.; Conkin, B.M.

1994-04-01

Internal units within the Columbus Limestone (Early Devonian Emsian [Schoharie] to Middle Devonian Eifelian [late Onesquethawan]) and the Delaware Formation (Middle Devonian early Givetian [Cazenovian]) of central Ohio are separated by disconformities of the magnitude of paracontinuities. Stauffer (1909) divided the Columbus Limestone into zones A--H and the Delaware Formation into zones I--M. Within the Columbus, the A Zone (conglomerate at the base of Bellepoint Member) disconformably overlies Late Silurian beds. The D zone at top of the Bellepoint Member (bearing the Kawkawlin Metabentonite horizon) is overlain paracontinuously by the Marblehead Member (Lower Paraspirifer acuminatus-Spirifer macrothyris to Brevispirifer gregarius-Moellerina greeneimore » zones [= E--G zones]), with the Onondagan Indian Nation Metabentonite in the top of the G Zone. The Marblehead Member is overlain paracontinuously by a bone bed at base of the Venice Member (H zone = Upper Paraspirifer acuminatus- Spirifer duodenarius'' Zone). I Zone (Dublin Shale=Marcellus) of the Delaware Formation overlies the Columbus and has two bone beds at its base; Tioga Metabentonite (restricted) overlies the I Zone bone beds and is a few tenths to 1.85 feet above the base of the I Zone. Paracontinuities and bone beds occur at the bases of J, K, and L zones. Conkin and Conkin (1975) have shown Stauffer's (1909) M Zone is an extension of his L Zone. The Olentangy paracontinuously overlies the L Zone.« less

A new Trimerocephalus species (Trilobita, Phacopidae) from the Late Devonian (Early Famennian) of Poland.

PubMed

Kin, Adrian; Błażejowski, Błażej

2013-01-01

This study presents a detailed morphological analysis of a new species belonging to the blind trilobite Trimerocephalus McCoy, 1849, T. chopini n. sp., based on exceptionally well preserved articulated specimens from the Late Devonian (Early Famennian) of the Holy Cross Mountains in central Poland. The occurrence of this taxon in Kowala Quarry near Kielce has been reported previously, with specimens often found in single-file queues representing migratory behaviour that was followed by a mass mortality event that preserved these assemblages. The new taxon is compared with other species of Trimerocephalus and is interpreted as being most closely related to a clade consisting of T. caecus, T. lelievrei, T, inimbi, T. shotoriensis and T. tardispinosus.

Devonian (Emsian-Eifelian) fish from the Lower Bokkeveld Group (Ceres Subgroup), South Africa

NASA Astrophysics Data System (ADS)

Anderson, M. E.; Almond, J. E.; Evans, F. J.; Long, J. A.

1999-07-01

Four major groups of fish are represented by fragmentary remains from South Africa's Lower Bokkeveld Group of Early to Middle Devonian age: the Acanthodii, Chondrichthyes, Placodermi and Osteichthyes. These represent the oldest known occurrences of these groups in southern Africa, as well as an important addition to the very meagre record of earlier Devonian fish from the Malvinokaffric Province of southwestern Gondwana. Bokkeveld fish material comes from the Gydo (Late Emsian) and Tra Tra (Middle Eifelian) Formations of the Western Cape and Eastern Cape Provinces. The cosmopolitan marine acanthodian Machæracanthus is represented only by isolated fin spines which may belong to two different species on the basis of their external ornamentation, cross-sectional outline and internal histology. The elasmobranchs are represented by four elements: (1) a flattened chondrocranium which bears affinity to the Late Devonian-Carboniferous symmoriid (protacrodont) 'cladodont' sharks. It is probably the earliest known (Emsian) shark chondrocranium; (2) an isolated, primitive scapulocoracoid with a very short coracoidal ridge; (3) ankylosed and isolated radials, interpreted as parts of pterygial plates of a paired fin of an unknown chondrichthyan bearing affinity to the Middle Devonian Zamponiopteron from Bolivia; and (4) isolated barlike structures, perhaps gill arch or a jaw elements, thought to be from the same taxon as (3). The placoderms are represented by an incomplete trunk armour and fragmentary, finely ornamented plates of a primitive antiarch. The Osteichthyes are represented by a single large scale of an unidentified dipnoan from the Eifelian of the Cedarberg range, as well as a probable sarcopterygian dermal plate from the Emsian of the Prince Albert area. These are among the earliest sarcopterygian remains recorded from the Malvinokaffric Province.

Rock-inhabiting fungi originated during periods of dry climate in the late Devonian and middle Triassic.

PubMed

Gueidan, Cécile; Ruibal, Constantino; de Hoog, G S; Schneider, Harald

2011-10-01

Non-lichenized rock-inhabiting fungi (RIF) are slow-growing melanized ascomycetes colonizing rock surfaces in arid environments. They possess adaptations, which allow them to tolerate extreme abiotic conditions, such as high UV radiations and extreme temperatures. They belong to two separate lineages, one consisting in the sister classes Dothideomycetes and Arthoniomycetes (Dothideomyceta), and the other consisting in the order Chaetothyriales (Eurotiomycetes). Because RIF often form early diverging groups in Chaetothyriales and Dothideomyceta, the ancestors of these two lineages were suggested to most likely be rock-inhabitants. The lineage of RIF related to the Chaetothyriales shows a much narrower phylogenetic spectrum than the lineage of RIF related to Dothideomyceta, suggesting a much more ancient origin for the latter. Our study aims at investigating the times of origin of RIF using a relaxed clock model and several fossil and secondary calibrations. Our results show that the RIF in Dothideomyceta evolved in the late Devonian, much earlier than the RIF in Chaetothyriales, which originated in the middle Triassic. The origin of the chaetothyrialean RIF correlates well with a period of recovery after the Permian-Triassic mass extinction and an expansion of arid landmasses. The period preceding the diversification of the RIF related to Dothideomyceta (Silurian--Devonian) is also characterized by large arid landmasses, but temperatures were much cooler than during the Triassic. The paleoclimate record provides a good explanation for the diversification of fungi subjected to abiotic stresses and adapted to life on rock surfaces in nutrient-poor habitats. Copyright © 2011 British Mycological Society. Published by Elsevier Ltd. All rights reserved.

Fossil record of stem groups employed in evaluating the chronogram of insects (Arthropoda: Hexapoda)

PubMed Central

Wang, Yan-hui; Engel, Michael S.; Rafael, José A.; Wu, Hao-yang; Rédei, Dávid; Xie, Qiang; Wang, Gang; Liu, Xiao-guang; Bu, Wen-jun

2016-01-01

Insecta s. str. (=Ectognatha), comprise the largest and most diversified group of living organisms, accounting for roughly half of the biodiversity on Earth. Understanding insect relationships and the specific time intervals for their episodes of radiation and extinction are critical to any comprehensive perspective on evolutionary events. Although some deeper nodes have been resolved congruently, the complete evolution of insects has remained obscure due to the lack of direct fossil evidence. Besides, various evolutionary phases of insects and the corresponding driving forces of diversification remain to be recognized. In this study, a comprehensive sample of all insect orders was used to reconstruct their phylogenetic relationships and estimate deep divergences. The phylogenetic relationships of insect orders were congruently recovered by Bayesian inference and maximum likelihood analyses. A complete timescale of divergences based on an uncorrelated log-normal relaxed clock model was established among all lineages of winged insects. The inferred timescale for various nodes are congruent with major historical events including the increase of atmospheric oxygen in the Late Silurian and earliest Devonian, the radiation of vascular plants in the Devonian, and with the available fossil record of the stem groups to various insect lineages in the Devonian and Carboniferous. PMID:27958352

Stratigraphy and facies development of the marine Late Devonian near the Boulongour Reservoir, northwest Xinjiang, China

NASA Astrophysics Data System (ADS)

Suttner, Thomas J.; Kido, Erika; Chen, Xiuqin; Mawson, Ruth; Waters, Johnny A.; Frýda, Jiří; Mathieson, David; Molloy, Peter D.; Pickett, John; Webster, Gary D.; Frýdová, Barbora

2014-02-01

Late Devonian to Early Carboniferous stratigraphic units within the 'Zhulumute' Formation, Hongguleleng Formation (stratotype), 'Hebukehe' Formation and the Heishantou Formation near the Boulongour Reservoir in northwestern Xinjiang are fossil-rich. The Hongguleleng and 'Hebukehe' formations are biostratigraphically well constrained by microfossils from the latest Frasnian linguiformis to mid-Famennian trachytera conodont biozones. The Hongguleleng Formation (96.8 m) is characterized by bioclastic argillaceous limestones and marls (the dominant facies) intercalated with green spiculitic calcareous shales. It yields abundant and highly diverse faunas of bryozoans, brachiopods and crinoids with subordinate solitary rugose corals, ostracods, trilobites, conodonts and other fish teeth. The succeeding 'Hebukehe' Formation (95.7 m) consists of siltstones, mudstones, arenites and intervals of bioclastic limestone (e.g. 'Blastoid Hill') and cherts with radiolarians. A diverse ichnofauna, phacopid trilobites, echinoderms (crinoids and blastoids) together with brachiopods, ostracods, bryozoans and rare cephalopods have been collected from this interval. Analysis of geochemical data, microfacies and especially the distribution of marine organisms, which are not described in detail here, but used for facies analysis, indicate a deepening of the depositional environment at the Boulongour Reservoir section. Results presented here concern mainly the sedimentological and stratigraphical context of the investigated section. Additionally, one Late Devonian palaeo-oceanic and biotic event, the Upper Kellwasser Event is recognized near the section base.

An outline of the palaeogeographic evolution of the Australasian region since the beginning of the Neoproterozoic

NASA Astrophysics Data System (ADS)

Li, Z. X.; Powell, C. McA.

2001-04-01

In the last 1000 million years, Australia has been part of two supercontinents: Palaeozoic Gondwanaland and Neoproterozoic Rodinia. Neoproterozoic Australia was covered by shallow epicontinental seas, and, in the late Neoproterozoic, by low-latitude glaciers. The breakup of Rodinia along the Tasman Line occurred at the end of the Sturtian glaciation (760 Ma) giving rise to the Palaeo-Pacific Ocean. Gondwanaland formed in the Early Cambrian, at the same time as the Tarim block broke away from northwestern Australia. Westward subduction of the Palaeo-Pacific Ocean along the eastern margin of Australia-Antarctica commenced during the Early Cambrian in northern Victoria Land and in the Middle Cambrian in South Australia, and culminated to the Late Cambrian-Early Ordovician Ross-Delamerian Mountains. In the Ordovician, the magmatic arc retreated from Australia's then-eastern continental margin, forming a marginal sea and offshore island arc. A shallow seaway across Australia in the Late Cambrian and Ordovician gradually gave way to desert-like conditions in Central Australia and the adjacent Canning Basin by Silurian time. The Silurian to mid-Devonian was an interval of rapidly changing palaeogeography in eastern Australia with deep volcanogenic troughs formed in a dextral transtensional tectonic setting. Widespread deformation in the Tasman orogenic zone in the Middle Devonian to Early Carboniferous, was accompanied by the development of an Andean-style magmatic arc along the Pacific continental margin of Australia. The most widespread Phanerozoic mountain-building stage in Central Australia occurred in the Late Devonian to mid-Carboniferous, as part of a world-wide Variscan orogenic episode associated with the collision of Gondwanaland with Laurussia to form Pangea. In the late Visean, Australia drifted rapidly southward from previous low latitudes to a near-polar position. Glacial conditions dominated the Late Carboniferous and earliest Permian. Transtensional basins associated with dextral oroclinal shear along the Panthalassan eastern margin of Australia developed in the Late Carboniferous and persisted until the Late Permian, when an Andean-style magmatic arc was re-established. Large foreland basins inboard of the Late Permian to Early Triassic magmatic arc accumulated major coal deposits during Late Permian volcanic phases, but drastic climatic changes at the end of the Permian, possibly caused by global greenhouse conditions, led to red-bed deposition in the Early Triassic. Pangea began to rift in the mid-Triassic, and by the Late Triassic, the Cimmerian blocks, which lay off northwestern Australia throughout the Palaeozoic, had departed the northern margin of Gondwanaland. A new Andean-style continental magmatic arc became established along the Pacific Ocean margin of Australia. Breakup between Australia-Antarctica and the northern part of Greater India commenced ca. 130 Ma, and between Australia and Antarctica around 96 Ma. At the beginning of the Palaeogene, Australia commenced its northward drift towards its present position. Seafloor spreading between Australia and Antarctica was at first slow, but increased to ca. 5 cm per year around 45 Ma. By 35 Ma, the circum-Antarctic current became established, thereby triggering glaciation in Antarctica. Northern Australia reached the tropics by the beginning of the Miocene, and Australia has progressively moved northwards at 7 to 8 cm per year since.

Palaeomagnetism and geochemistry of Early Palaeozoic rocks of the Barrandian (Teplé-Barrandian Unit, Bohemian Massif): palaeotectonic implications

NASA Astrophysics Data System (ADS)

Patočka, F.; Pruner, P.; Štorch, P.

The Barrandian area (the Teplá-Barrandian unit, Bohemian Massif) provided palaeomagnetic results on Early Palaeozoic rocks and chemical data on siliciclastic sediments of both Middle Cambrian and Early Ordovician to Middle Devonian sedimentary sequences; an outcoming interpretation defined source areas of clastic material and palaeotectonic settings of the siliciclastic rock deposition. The siliciclastic rocks of the earliest Palaeozoic sedimentation cycle, deposited in the Cambrian Příbram-Jince Basin of the Barrandian, were derived from an early Cadomian volcanic island arc developed on Neoproterozoic oceanic lithosphere and accreted to a Cadomian active margin of northwestern Gondwana. Inversion of relief terminated the Cambrian sedimentation, and a successory Prague Basin subsided nearby since Tremadocian. Source area of the Ordovician and Early Silurian shallow-marine siliciclastic sediments corresponded to progressively dissected crust of continental arc/active continental margin type of Cadomian age. Since Late Ordovician onwards both synsedimentary within-plate basic volcanics and older sediments had been contributing in recognizable proportions to the siliciclastic rocks. The siliciclastic sedimentation was replaced by deposition of carbonate rocks throughout late Early Silurian to Early Devonian period of withdrawal of the Cadomian clastic material source. Above the carbonates an early Givetian flysch-like siliciclastic suite completed sedimentation in the Barrandian. In times between Middle Cambrian and Early/Middle Devonian boundary interval an extensional tectonic setting prevailed in the Teplá-Barrandian unit. The extensional regime was related to Early Palaeozoic large-scale fragmentation of the Cadomian belt of northwestern Gondwana and origin of Armorican microcontinent assemblage. The Teplá-Barrandian unit was also engaged in a peri-equatorially oriented drift of Armorican microcontinent assemblage throughout the Early Palaeozoic: respective palaeolatitudes of 58°S (Middle Cambrian) and 17°S (Middle Devonian) were inferred for the Barrandian rocks. The Middle Devonian flysch-like siliciclastics of the Prague Basin suggest a reappearance of the deeply dissected Cadomian source area in a proximity of the Barrandian due to early Variscan convergences and collisions of the Armorican microcontinents. Significant palaeotectonic rotations are palaeomagnetically evidenced to take place during oblique convergence and final docking of the Teplá-Barrandian microplate within the Variscan terrane mosaic of the Bohemian Massif.

Devonian volcanic rocks of the southern Chinese Altai, NW China: Petrogenesis and implication for a propagating slab-window magmatism induced by ridge subduction during accretionary orogenesis

NASA Astrophysics Data System (ADS)

Ma, Xiaomei; Cai, Keda; Zhao, Taiping; Bao, Zihe; Wang, Xiangsong; Chen, Ming; Buslov, M. M.

2018-07-01

Ridge-trench interaction is a common tectonic process of the present-day Pacific Rim accretionary orogenic belts, and this process may facilitate "slab-window" magmatism that can produce significant thermal anomalies and geochemically unusual magmatic events. However, ridge-trench interaction has rarely been well-documented in the ancient geologic record, leading to grossly underestimation of this process in tectonic syntheses of plate margins. The Chinese Altai was inferred to have undergone ridge subduction in the Devonian and a slab-window model is proposed to interpret its high-temperature metamorphism and geochemically unique magmatic rocks, which can serve as an excellent and unique place to refine the tectonic evolution associated with ridge subduction in an ancient accretionary orogeny. For this purpose, we carried out geochemical and geochronological studies on Devonian basaltic rocks in this region. Secondary ion mass spectrometry (SIMS) zircon U-Pb dating results yield an age of 376.2 ± 2.4 Ma, suggesting an eruption at the time of Late Devonian. Geochemically, the samples in this study have variable SiO2 (43.3-58.3 wt%), low K2O (0.02-0.07 wt%) and total alkaline contents (2.16-5.41 wt%), as well as Fe2O3T/MgO ratios, showing typical tholeiitic affinity. On the other hand, the basaltic rocks display MORB-like REE patterns ((La/Yb)N = 0.90-2.57) and (Ga/Yb)N = 0.97-1.28), and have moderate positive εNd(t) values (+4.4 to +5.4), which collectively suggest a derivation from a mixing source comprising MORB-like mantle of a mature back-arc basin and subordinate arc mantle wedge. These basaltic rocks are characterized by Low La/Yb (1.26-3.69), Dy/Yb (1.51-1.77) and Sm/Yb (0.83-1.32) ratios, consistent with magmas derived from low degree (∼10%) partial melting of the spinel lherzolite source at a quite shallow mantle depth. Considering the distinctive petrogenesis of the basaltic rocks in this region, the Late Devonian basalts in the southern Chinese Altai is suggested to have witnessed the propagating process of slab-window magmatism that was induced by ridge subduction in a nascent rifting stage of a back-arc basin.

Lithostratigraphic, conodont, and other faunal links between lower Paleozoic strata in northern and central Alaska and northeastern Russia

USGS Publications Warehouse

Dumoulin, Julie A.; Harris, Anita G.; Gagiev, Mussa; Bradley, Dwight C.; Repetski, John E.

2002-01-01

Lower Paleozoic platform carbonate strata in northern Alaska (parts of the Arctic Alaska, York, and Seward terranes; herein called the North Alaska carbonate platform) and central Alaska (Farewell terrane) share distinctive lithologic and faunal features, and may have formed on a single continental fragment situated between Siberia and Laurentia. Sedimentary successions in northern and central Alaska overlie Late Proterozoic metamorphosed basement; contain Late Proterozoic ooid-rich dolostones, Middle Cambrian outer shelf deposits, and Ordovician, Silurian, and Devonian shallow-water platform facies, and include fossils of both Siberian and Laurentian biotic provinces. The presence in the Alaskan terranes of Siberian forms not seen in wellstudied cratonal margin sequences of western Laurentia implies that the Alaskan rocks were not attached to Laurentia during the early Paleozoic.The Siberian cratonal succession includes Archean basement, Ordovician shallow-water siliciclastic rocks, and Upper Silurian–Devonian evaporites, none of which have counterparts in the Alaskan successions, and contains only a few of the Laurentian conodonts that occur in Alaska. Thus we conclude that the lower Paleozoic platform successions of northern and central Alaska were not part of the Siberian craton during their deposition, but may have formed on a crustal fragment rifted away from Siberia during the Late Proterozoic. The Alaskan strata have more similarities to coeval rocks in some peri-Siberian terranes of northeastern Russia (Kotelny, Chukotka, and Omulevka). Lithologic ties between northern Alaska, the Farewell terrane, and the peri-Siberian terranes diminish after the Middle Devonian, but Siberian afµnities in northern and central Alaskan biotas persist into the late Paleozoic.

The Late Devonian Gogo Formation Lägerstatte of Western Australia: Exceptional Early Vertebrate Preservation and Diversity

NASA Astrophysics Data System (ADS)

Long, John A.; Trinajstic, Kate

2010-05-01

The Gogo Formation of Western Australia preserves a unique Late Devonian (Frasnian) reef fauna. The exceptional three-dimensional preservation of macrofossils combined with unprecedented soft-tissue preservation (including muscle bundles, nerve cells, and umbilical structures) has yielded a particularly rich assemblage with almost 50 species of fishes described. The most significant discoveries have contributed to resolving placoderm phylogeny and elucidating their reproductive physiology. Specifically, these discoveries have produced data on the oldest known vertebrate embryos; the anatomy of the primitive actinopterygian neurocranium and phylogeny of the earliest actinopterygians; the histology, radiation, and plasticity of dipnoan (lungfish) dental and cranial structures; the anatomy and functional morphology of the extinct onychodonts; and the anatomy of the primitive tetrapodomorph head and pectoral fin.

Further study of Late Devonian seed plant Cosmosperma polyloba: its reconstruction and evolutionary significance.

PubMed

Liu, Le; Wang, Deming; Meng, Meicen; Xue, Jinzhuang

2017-06-26

The earliest seed plants in the Late Devonian (Famennian) are abundant and well known. However, most of them lack information regarding the frond system and reconstruction. Cosmosperma polyloba represents the first Devonian ovule in China and East Asia, and its cupules, isolated synangiate pollen organs and pinnules have been studied in the preceding years. New fossils of Cosmosperma were obtained from the type locality, i.e. the Leigutai Member of the Wutong Formation in Fanwan Village, Changxing County, Zhejiang Province, South China. The collection illustrates stems and fronds extensively covered in prickles, as well as fertile portions including uniovulate cupules and anisotomous branches bearing synangiate pollen organs. The stems are unbranched and bear fronds helically. Fronds are dimorphic, displaying bifurcate and trifurcate types, with the latter possibly connected to fertile rachises terminated by pollen organs. Tertiary and quaternary rachises possessing pinnules are arranged alternately (pinnately). The cupule is uniovulate and the ovule has four linear integumentary lobes fused in basal 1/3. The striations on the stems and rachises may indicate a Sparganum-type cortex. Cosmosperma further demonstrates diversification of frond branching patterns in the earliest seed plants. The less-fused cupule and integument of this plant are considered primitive among Devonian spermatophytes with uniovulate cupules. We tentatively reconstructed Cosmosperma with an upright, semi-self-supporting habit, and the prickles along stems and frond rachises were interpreted as characteristics facilitating supporting rather than defensive structures.

Cope's Rule and Romer's theory: patterns of diversity and gigantism in eurypterids and Palaeozoic vertebrates

PubMed Central

Lamsdell, James C.; Braddy, Simon J.

2010-01-01

Gigantism is widespread among Palaeozoic arthropods, yet causal mechanisms, particularly the role of (abiotic) environmental factors versus (biotic) competition, remain unknown. The eurypterids (Arthropoda: Chelicerata) include the largest arthropods; gigantic predatory pterygotids (Eurypterina) during the Siluro-Devonian and bizarre sweep-feeding hibbertopterids (Stylonurina) from the Carboniferous to end-Permian. Analysis of family-level originations and extinctions among eurypterids and Palaeozoic vertebrates show that the diversity of Eurypterina waned during the Devonian, while the Placodermi radiated, yet Stylonurina remained relatively unaffected; adopting a sweep-feeding strategy they maintained their large body size by avoiding competition, and persisted throughout the Late Palaeozoic while the predatory nektonic Eurypterina (including the giant pterygotids) declined during the Devonian, possibly out-competed by other predators including jawed vertebrates. PMID:19828493

The anatomy of a major late-stage thrust and implications for models of late-stage collisional orogenesis in the Caledonian crust of northern Scandinavia

NASA Astrophysics Data System (ADS)

Anderson, Mark; Hames, Willis; Stokes, Alison

2010-05-01

Within the stack of Caledonian crystalline thrust sheets of northern Scandinavia, a single amphibolite facies lithotectonic unit, the Småtinden nappe, is identified as a major, basement-coupled ("stretching") shear zone. This dominantly pelitic unit achieved peak metamorphic conditions of 535-550°C and 8-9kbars, and the stretching geometry suggests that this most likely occurred in response to overthrusting of a hot, pre-assembled Caledonian thrust stack. Along-strike variations in microstructural geometries and patterns of mineral zoning in widely developed porphyroblast phases suggest, however, subsequent strain partitioning within the zone during late-stage decoupling of the thrust stack from the basement along major out-of-sequence thrusts. Large parts of the nappe are characterised by relatively late, static growth preserving concordant Si-Se relationships, and typically symmetrical external fabrics consistent with formation under dominantly pure shear conditions. In the Salangen area, however, the nappe is characterised by early garnet growth, with discordant Si-Se relationships and asymmetric external fabric geometries consistent with formation during ESE-directed simple shear. Remarkably consistent thermometric estimates from chlorites in both regimes (post- and syn-shearing) suggest that out-of-sequence ramping occurred at temperatures in the range 370-400 ̊C, within the typical range of blocking temperatures for argon retention in muscovite. 40Ar-39Ar dating of muscovites from S-C fabrics in the out-of-sequence shear zone suggest that late-stage thrusting occurred during the middle-late Devonian (ca. 395-375 Ma). Hanging-wall and footwall geometries coupled with these radiometric dates indicate that the development of these late thrusts closely relates to reactivation of pre-Caledonian Baltic basement during the Devonian (400-370 Ma). East-west contraction during the upper end of this time frame is peculiar considering that this was the period of large magnitude and rapid extension in western Norway.

A new Late Devonian genus with seed plant affinities.

PubMed

Wang, Deming; Liu, Le

2015-02-26

Many ovules of Late Devonian (Famennian) seed plants have been well studied. However, because few taxa occur with anatomically preserved stems and/or petioles, the vascular system of these earliest spermatophytes is little understood and available data come mostly from Euramerica. There remains great controversy over the anatomical differentiation of Late Devonian and Carboniferous seed plant groups of Buteoxylonales, Calamopityales and Lyginopteridales. Protostele evolution of these early spermatophytes needs more research. A new taxon Yiduxylon trilobum gen. et sp. nov. with seed plant affinities has been discovered in the Upper Devonian (Famennian) Tizikou Formation of Hubei Province, China. It is represented by stems, helically arranged and bifurcate fronds with two orders of pinnae and planate pinnules. Both secondary pinnae and pinnules are borne alternately. Stems contain a small protostele with three primary xylem ribs possessing a single peripheral protoxylem strand. Thick secondary xylem displays multiseriate bordered pitting on the tangential and radial walls of the tracheids, and has biseriate to multiseriate and high rays. A narrow cortex consists of inner cortex without sclerotic nests and sparganum-type outer cortex with peripheral bands of vertically aligned sclerenchyma cells. Two leaf traces successively arise tangentially from each primary xylem rib and they divide once to produce four circular-oval traces in the stem cortex. Four vascular bundles occur in two C-shaped groups at each petiole base with ground tissue and peripheral bands of sclerenchyma cells. Yiduxylon justifies the assignment to a new genus mainly because of the protostele with protoxylem strands only near the periphery of primary xylem ribs, leaf trace origination and petiolar vascular supply structure. It shares many definitive characters with Calamopityales and Lyginopteridales, further underscoring the anatomical similarities among early seed plants. The primary vascular system, pycnoxylic-manoxylic secondary xylem with bordered pits on both tangential and radial walls of a tracheid and leaf trace divergence of Yiduxylon suggest transitional features between the early spermatophytes and ancestral aneurophyte progymnosperms.

Late Devonian glacigenic and associated facies from the central Appalachian Basin, eastern United States

USGS Publications Warehouse

Brezinski, D.K.; Cecil, C.B.; Skema, V.W.

2010-01-01

Late Devonian strata in the eastern United States are generally considered as having been deposited under warm tropical conditions. However, a stratigraphically restricted Late Devonian succession of diamictite- mudstonesandstone within the Spechty Kopf and Rockwell Formations that extends for more than 400 km along depositional strike within the central Appalachian Basin may indicate other wise. This lithologic association unconformably overlies the Catskill Formation, where a 3- to 5-m-thick interval of deformed strata occurs immediately below the diamictite strata. The diamictite facies consists of several subfacies that are interpreted to be subglacial, englacial, supraglacial meltout, and resedimented deposits. The mudstone facies that overlies the diamictite consists of subfacies of chaotically bedded, clast-poor mudstone, and laminated mudstone sub facies that represent subaqueous proximal debris flows and distal glaciolacustrine rhythmites or varvites, respectively. The pebbly sandstone facies is interpreted as proglacial braided outwash deposits that both preceded glacial advance and followed glacial retreat. Both the tectonic and depositional frameworks suggest that the facies were deposited in a terrestrial setting within the Appalachian foreland basin during a single glacial advance and retreat. Regionally, areas that were not covered by ice were subject to increased rainfall as indicated by wet-climate paleosols. River systems eroded deeper channels in response to sea-level drop during glacial advance. Marine facies to the west contain iceborne dropstone boulders preserved within contemporaneous units of the Cleveland Shale Member of the Ohio Shale.The stratigraphic interval correlative with sea-level drop, climate change, and glacigenic succession represents one of the Appalachian Basin's most prolific oil-and gas-producing intervals and is contemporaneous with a global episode of sea-level drop responsible for the deposition of the Hangenberg Shale/Sandstone of Europe. This interval records the Hangenberg biotic crisis near the Devonian-Carboniferous boundary. ?? 2009 Geological Society of America.

The earliest seeds

USGS Publications Warehouse

Gillespie, W.H.; Rothwell, G.W.; Scheckler, S.E.

1981-01-01

Lagenostomalean-type seeds in bifurcating cupule systems have been discovered in the late Devonian Hampshire Formation of Randolph County, West Virginia, USA (Fig. 1). The associated megaflora, plants from coal balls, and vertebrate and invertebrate faunas demonstrate that the material is Famennian; the microflora indicates a more specific Fa2c age. Consequently, these seeds predate Archaeosperma arnoldii1 from the Fa2d of northeastern Pennsylvania, the oldest previously reported seed. By applying precision fracture, transfer, de??gagement, and thin-section techniques to selected cupules from the more than 100 specimens on hand, we have determined the three-dimensional morphology and histology of the seeds (Fig. 2a-h, k) and cupule systems. A comparison with known late Devonian to early Carboniferous seeds reveals that ours are more primitively organized than all except Genomosperma2,3. ?? 1981 Nature Publishing Group.

Euryhaline ecology of early tetrapods revealed by stable isotopes.

PubMed

Goedert, Jean; Lécuyer, Christophe; Amiot, Romain; Arnaud-Godet, Florent; Wang, Xu; Cui, Linlin; Cuny, Gilles; Douay, Guillaume; Fourel, François; Panczer, Gérard; Simon, Laurent; Steyer, J-Sébastien; Zhu, Min

2018-06-01

The fish-to-tetrapod transition-followed later by terrestrialization-represented a major step in vertebrate evolution that gave rise to a successful clade that today contains more than 30,000 tetrapod species. The early tetrapod Ichthyostega was discovered in 1929 in the Devonian Old Red Sandstone sediments of East Greenland (dated to approximately 365 million years ago). Since then, our understanding of the fish-to-tetrapod transition has increased considerably, owing to the discovery of additional Devonian taxa that represent early tetrapods or groups evolutionarily close to them. However, the aquatic environment of early tetrapods and the vertebrate fauna associated with them has remained elusive and highly debated. Here we use a multi-stable isotope approach (δ 13 C, δ 18 O and δ 34 S) to show that some Devonian vertebrates, including early tetrapods, were euryhaline and inhabited transitional aquatic environments subject to high-magnitude, rapid changes in salinity, such as estuaries or deltas. Euryhalinity may have predisposed the early tetrapod clade to be able to survive Late Devonian biotic crises and then successfully colonize terrestrial environments.

Oxygenation history of the Neoproterozoic to early Phanerozoic and the rise of land plants

NASA Astrophysics Data System (ADS)

Wallace, Malcolm W.; Hood, Ashleigh vS.; Shuster, Alice; Greig, Alan; Planavsky, Noah J.; Reed, Christopher P.

2017-05-01

There has been extensive debate about the history of Earth's oxygenation and the role that land plant evolution played in shaping Earth's ocean-atmosphere system. Here we use the rare earth element patterns in marine carbonates to monitor the structure of the marine redox landscape through the rise and diversification of animals and early land plants. In particular, we use the relative abundance of cerium (Ceanom), the only redox-sensitive rare earth element, in well-preserved marine cements and other marine precipitates to track seawater oxygen levels. Our results indicate that there was only a moderate increase in oceanic oxygenation during the Ediacaran (average Cryogenian Ceanom = 1.1, average Ediacaran Ceanom = 0.62), followed by a decrease in oxygen levels during the early Cambrian (average Cryogenian Ceanom = 0.90), with significant ocean anoxia persisting through the early and mid Paleozoic (average Early Cambrian-Early Devonian Ceanom = 0.84). It was not until the Late Devonian that oxygenation levels are comparable to the modern (average of all post-middle Devonian Ceanom = 0.55). Therefore, this work confirms growing evidence that the oxygenation of the Earth was neither unidirectional nor a simple two-stage process. Further, we provide evidence that it was not until the Late Devonian, when large land plants and forests first evolved, that oxygen levels reached those comparable to the modern world. This is recorded with the first modern-like negative Ceanom (values <0.6) occurring at around 380 Ma (Frasnian). This suggests that land plants, rather than animals, are the 'engineers' responsible for the modern fully oxygenated Earth system.

A new osteichthyan from the late Silurian of Yunnan, China.

PubMed

Choo, Brian; Zhu, Min; Qu, Qingming; Yu, Xiaobo; Jia, Liantao; Zhao, Wenjin

2017-01-01

Our understanding of early gnathostome evolution has been hampered by a generally scant fossil record beyond the Devonian. Recent discoveries from the late Silurian Xiaoxiang Fauna of Yunnan, China, have yielded significant new information, including the earliest articulated osteichthyan fossils from the Ludlow-aged Kuanti Formation. Here we describe the partial postcranium of a new primitive bony fish from the Kuanti Formation that represents the second known taxon of pre-Devonian osteichthyan revealing articulated remains. The new form, Sparalepis tingi gen. et sp. nov., displays similarities with Guiyu and Psarolepis, including a spine-bearing pectoral girdle and a placoderm-like dermal pelvic girdle, a structure only recently identified in early osteichthyans. The squamation with particularly thick rhombic scales shares an overall morphological similarity to that of Psarolepis. However, the anterior flank scales of Sparalepis possess an unusual interlocking system of ventral bulges embraced by dorsal concavities on the outer surfaces. A phylogenetic analysis resolves Sparalepis within a previously recovered cluster of stem-sarcopterygians including Guiyu, Psarolepis and Achoania. The high diversity of osteichthyans from the Ludlow of Yunnan strongly contrasts with other Silurian vertebrate assemblages, suggesting that the South China block may have been an early center of diversification for early gnathostomes, well before the advent of the Devonian "Age of Fishes".

The Middle to Late Devonian Eden-Comerong-Yalwal Volcanic Zone of Southeastern Australia: An ancient analogue of the Yellowstone-Snake River Plain region of the USA

NASA Astrophysics Data System (ADS)

Dadd, K. A.

1992-11-01

The Middle to Late Devonian Yalwal Volcanics, Comerong Volcanics, Boyd Volcanic Complex and associated gabbroic and A-type granitic plutons form part of a continental volcano-tectonic belt, the Eden-Comerong-Yalwal Volcanic Zone (EVZ), located parallel to the coast of southeastern Australia. The EVZ is characterised by an elongate outcrop pattern, bimodal basalt-rhyolite volcanism, and a paucity of sedimentary rocks. Volcanic centres were located along the length of the volcanic zone at positions indicated by subvolcanic plutons, dykes, rhyolite lavas and other proximal vent indicators including surge bedforms in tuff rings, and hydrothermal alteration. Previous interpretations that suggested the volcanic zone was a fault bounded rift are rejected in favour of a volcano-tectonic belt. The Yellowstone-Snake River Plain region (Y-SRP) in the USA is an appropriate analogue. Both regions have basalt lavas which range in composition from olivine tholeiite to ferrobasalt, alkalic rhyolitic rocks enriched in Y, Zr and Th, large rhyolite lava flows, plains-type basalt lava flows, and a paucity of sedimentary rocks. The Y-SRP is inferred to have developed by migration of the American plate over a fixed hot spot leading to a northeast temporal progression of the focus of volcanic activity. Application of a similar hot spot model to the EVZ (using a length of 300 km and a time range for volcanic activity of 5-10 Ma), suggests that during the Middle to Late Devonian the Australian plate was moving at a rate of between 3 and 6 cm/yr relative to the hot spot and that the northern extent of the volcanic zone at any time was a topographically high region with rhyolitic activity, similar to present day Yellowstone. As the focus of activity moved northward, the high region subsided and the depression was flooded by basalt. The EVZ was much wider (up to 70 km) and much longer than the belt defined by present-day outcrop and was of comparable scale to the Y-SRP. The main difference between the two volcanic belts is the lack of large pyroclastic flows and identifiable caldera complexes in the EVZ.

Middle Devonian to Early Carboniferous event stratigraphy of Devils Gate and Northern Antelope Range sections, Nevada, U.S.A

USGS Publications Warehouse

Sandberg, C.A.; Morrow, J.R.; Poole, F.G.; Ziegler, W.

2003-01-01

The classic type section of the Devils Gate Limestone at Devils Gate Pass is situated on the eastern slope of a proto-Antler forebulge that resulted from convergence of the west side of the North American continent with an ocean plate. The original Late Devonian forebulge, the site of which is now located between Devils Gate Pass and the Northern Antelope Range, separated the continental-rise to deep-slope Woodruff basin on the west from the backbulge Pilot basin on the east. Two connections between these basins are recorded by deeper water siltstone beds at Devils Gate; the older one is the lower tongue of the Woodruff Formation, which forms the basal unit of the upper member of the type Devils Gate, and the upper one is the overlying, thin lower member of the Pilot Shale. The forebulge and the backbulge Pilot basin originated during the middle Frasnian (early Late Devonian) Early hassi Zone, shortly following the Alamo Impact within the punctata Zone in southern Nevada. Evidence of this impact is recorded by coeval and reworked shocked quartz grains in the Northern Antelope Range and possibly by a unique bypass-channel or megatsunami-uprush sandy diamictite within carbonate-platform rocks of the lower member of the type Devils Gate Limestone. Besides the Alamo Impact and three regional events, two other important global events are recorded in the Devils Gate section. The semichatovae eustatic rise, the maximum Late Devonian flooding event, coincides with the sharp lithogenetic change at the discordant boundary above the lower member of the Devils Gate Limestone. Most significantly, the Devils Gate section contains the thickest and most complete rock record in North America across the late Frasnian linguiformis Zone mass extinction event. Excellent exposures include not only the extinction shale, but also a younger. Early triangularis Zone tsunamite breccia, produced by global collapse of carbonate platforms during a shallowing event that continued into the next younger Famennian Stage. The Northern Antelope Range section is located near the top of the west side of the proto-Antler forebulge. Because of its unusual, tectonically active location, unmatched at any other Nevada localities, this section records only four regional and global events during a timespan slightly longer than that of the Devils Gate section. The global semichatovae rise and late Frasnian mass extinction event are largely masked because of the depositional complexities resulting from this location.

The potential of paleozoic nonmarine trace fossils for paleoecological interpretations

USGS Publications Warehouse

Maples, C.G.; Archer, A.W.

1989-01-01

Many Late Paleozoic environments have been interpreted as marine because of the co-occurrence of supposedly exclusively marine trace fossils. Beginning in the Late Ordovician, however, nonmarine trace-fossil diversity increased throughout the Paleozoic. This diversification of nonmarine organisms and nonmarine trace fossils was especially prevalent in Devonian and later times. Diversification of freshwater organisms is indicated by the large number of freshwater fish, arthropods, annelids and molluscs that had developed by the Carboniferous. In addition to diverse freshwater assemblages, entirely terrestrial vertebrate and invertebrate ecosystems had developed by the Devonian. This rapid diversification of freshwater and terrestrial organisms is inherently linked to development and diversification of land plants and subsequent shedding of large quantities of organic detritus in nonmarine and marginal-marine areas. Nearshore marine organisms and their larvae that are able to tolerate relatively short periods of lowered salinities will follow salt-water wedges inland during times of reduced freshwater discharge. Similarly, amphidromous marine organisms will migrate periodically inland into nonmarine environments. Undoubtedly, both of these processes were active in the Paleozoic. However, both processes are restricted to stream/distributary channels, interdistributary bays, or estuaries. Therefore, the presence of diverse trace-fossil assemblages in association with floodplain deposits is interpreted to reflect true nonmarine adaptation and diversity. Conversely, diverse trace-fossil assemblages in association with stream/distributary channel deposits, interdistributary-bay deposits, or estuarine deposits may reflect migration of salt-water wedges inland, or migration of marine organisms into freshwater environments (amphidromy), or both. ?? 1989.

Biostratigraphy and structure of paleozoic host rocks and their relationship to Carlin-type gold deposits in the Jerritt Canyon mining district, Nevada

USGS Publications Warehouse

Peters, S.G.; Armstrong, A.K.; Harris, A.G.; Oscarson, R.L.; Noble, P.J.

2003-01-01

The Jerritt Canyon mining district in the northern Independence Range, northern Nevada, contains multiple, nearly horizontal, thrust masses of platform carbonate rocks that are exposed in a series of north- to northeast-elongated, tectonic windows through rocks of the Roberts Mountains allochthon. The Roberts Mountains allochthon was emplaced during the Late Devonian to Early Mississippian Antler orogeny. These thrust masses contain structurally and stratigraphically controlled Carlin-type gold deposits. The gold deposits are hosted in tectonically truncated units of the Silurian to Devonian Hanson Creek and Roberts Mountains Formations that lie within structural slices of an Eastern assemblage of Cambrian to Devonian carbonate rocks. In addition, these multiply thrust-faulted and folded host rocks are structurally interleaved with Mississippian siliciclastic rocks and are overlain structurally by Cambrian to Devonian siliciclastic units of the Roberts Mountains allochthon. All sedimentary rocks were involved in thrusting, high-angle faulting, and folding, and some of these events indicate substantial late Paleozoic and/or Mesozoic regional shortening. Early Pennsylvanian and late Eocene dikes also intrude the sedimentary rocks. These rocks all were uplifted into a northeast-trending range by subsequent late Cenozoic Basin and Range faulting. Eocene sedimentary and volcanic rocks flank part of the range. Pathways of hydrothermal fluid flow and locations of Carlin-type gold orebodies in the Jerritt Canyon mining district were controlled by structural and host-rock geometries within specific lithologies of the stacked thrust masses of Eastern assemblage rocks. The gold deposits are most common proximal to intersections of northeast-striking faults, northwest-striking dikes, and thrust planes that lie adjacent to permeable stratigraphic horizons. The host stratigraphic units include carbonate sequences that contained primary intercrystalline permeability, which provided initial pathways for fluid flow and later served as precipitation sites for ore minerals. Alteration, during, and perhaps prior to mineralization, enhanced primary permeability by dissolution, by removal of calcite, and by formation of dolomite. Ore-stage sulfide minerals and alteration minerals commonly precipitated in pore spaces among dolomite grains. Microveinlets and microbrecciation in zones of intense alteration also provided networks of secondary permeability that further enhanced fluid flux and produced additional sites for ore deposition.

The Timan-Pechora Basin province of northwest Arctic Russia; Domanik, Paleozoic total petroleum system

USGS Publications Warehouse

Lindquist, Sandra J.

1999-01-01

The Domanik-Paleozoic oil-prone total petroleum system covers most of the Timan-Pechora Basin Province of northwestern Arctic Russia. It contains nearly 20 BBOE ultimate recoverable reserves (66% oil). West of the province is the early Precambrian Eastern European craton margin. The province itself was the site of periodic Paleozoic tectonic events, culminating with the Hercynian Uralian orogeny along its eastern border. The stratigraphic record is dominated by Paleozoic platform and shelf-edge carbonates succeeded by Upper Permian to Triassic molasse siliciclastics that are locally present in depressions. Upper Devonian (Frasnian), deep marine shale and limestone source rocks ? with typically 5 wt % total organic carbon ? by middle Mesozoic time had generated hydrocarbons that migrated into reservoirs ranging in age from Ordovician to Triassic but most focused in Devonian and Permian rocks. Carboniferous structural inversions of old aulacogen borders, and Hercynian (Permian) to Early Cimmerian (Late Triassic to Early Jurassic) orogenic compression not only impacted depositional patterns, but also created and subsequently modified numerous structural traps within the province.

Paleomagnetism of Devonian dykes in the northern Kola Peninsula and its bearing on the apparent polar wander path of Baltica in the Precambrian

NASA Astrophysics Data System (ADS)

Veselovskiy, Roman V.; Bazhenov, Mikhail L.; Arzamastsev, Andrey A.

2016-04-01

Mafic dykes and large alkaline and carbonatite intrusions of Middle-Late Devonian age are widespread on the Kola Peninsula in NE Fennoscandia. These magmatic rocks are well characterized with petrographic, geochemical and geochronological data but no paleomagnetic results have been reported yet. We studied dolerite dykes from the northern part of the Peninsula and isolated three paleomagnetic components in these rocks. A low-temperature component is aligned along the present-day field, while a major constituent of natural remanent magnetization is an intermediate-temperature component (Decl. = 79.6°, Inc. = 78.5°, α95 = 5,9°, N = 17 sites) that is present in most Devonian dykes but is found in some baked metamorphic rocks and Proterozoic dykes too. Finally, a primary Devonian component could be reliably isolated from two dykes only. Rock-magnetic studies point to presumably primary low-Ti titanomagnetite and/or pure magnetite as the main remanence carriers but also reveal alteration of the primary minerals and the formation of new magnetic phases. The directions of a major component differ from the Middle Paleozoic reference data for Baltica but closely match those for the 190 ± 10 Ma interval recalculated from the apparent polar wander path of the craton. We assume that this Early Jurassic component is a low-temperature overprint of chemical origin. The main impact of the new results is not to mid-Paleozoic or Early Mesozoic times but to much older epochs. Analysis of paleomagnetic data shows that the directionally similar remanences are present in objects with the ages ranging from 500 Ma to 2 Ga over entire Fennoscandia. Hence we argue that an Early Jurassic remagnetization is of regional extent but cannot link it to a certain process and a certain tectonic event. If true, this hypothesis necessitates a major revision of the APWP for Baltica over a wide time interval.

Climate effects caused by land plant invasion in the Devonian

NASA Astrophysics Data System (ADS)

Hir guillaume, Le; yannick, Donnadieu; yves, Goddéris; brigitte, Meyer-Berthaud; gilles, Ramstein

2017-04-01

Land plants invaded continents during the Mid-Paleozoic. Their spreading and diversification have been compared to the Cambrian explosion in terms of intensity and impact on the diversification of life on Earth. Whereas prior studies were focused on the evolution of the root system and its weathering contribution, here we investigated the biophysical impacts of plant colonization on the surface climate through changes in continental albedo, roughness, thermal properties, and potential evaporation using a 3D-climate model coupled to a global biogeochemical cycles associated to a simple model for vegetation dynamics adapted to Devonian conditions. From the Early to the Late Devonian, we show that continental surface changes induced by land plants and tectonic drift have produced a large CO2 drawdown without being associated to a global cooling, because the cooling trend is counteracted by a warming trend resulting from the surface albedo reduction. If CO2 is consensually assumed as the main driver of the Phanerozoic climate, during land-plant invasion, the modifications of soil properties could have played in the opposite direction of the carbon dioxide fall, hence maintaining warm temperatures during part of the Devonian.

Controls of late Palaeozoic and Mesozoic extension in the British Isles: evidence from seismic reflection data in the Central North Sea

NASA Astrophysics Data System (ADS)

Smith, K.; Cameron, T. D. J.

2009-04-01

Controls of late Palaeozoic and Mesozoic extension in the British Isles: evidence from seismic reflection data in the Central North Sea. Kevin Smith (1) and Don Cameron (2) (1) British Geological Survey, Murchison House, West Mains Road, Edinburgh, EH9 3LA. (ksm@bgs.ac.uk). (2) British Geological Survey, 376 Gilmerton Road, Edinburgh, EH17 7QS. In the area of the British Isles during the late Devonian and early Carboniferous, the oblique convergence of Laurentia and Gondwana imposed a torque on the adjoining terranes of Baltica and Avalonia. Their resulting clockwise rotation was accommodated by widely distributed N-S extension in the intervening zones previously formed by Caledonian and Acadian convergence. South of Laurentia and Baltica, late Palaeozoic extension was focused (1) at terrane margins, (2) in areas of limited Caledonian-Acadian plutonism, and (3) in places where the western (Iapetus) and eastern (Tornquist) convergence zones intersect at a high angle. One of these latter areas lies in Central England immediately north of the Midland Microcraton (part of Eastern Avalonia), where thermal subsidence associated with early Carboniferous extension gave rise to the late Carboniferous Pennine Basin. Interpretation of an extensive set of 3D and 2D long-offset seismic reflection data suggests that a similar area of enhanced extension at a fold belt intersection lies to north of the Mid North Sea High in the middle of the Central North Sea. Variscan uplift and inversion of the late Palaeozoic basins began to predominate in mid-Carboniferous times as final amalgamation of all the different terranes to form Pangaea curtailed the initial episode of extension and thermal subsidence. This change in the tectonic regime was associated with the onset of tholeiitic volcanism within the convergence zones, and was followed by localised extension during the earliest Permian. Evidence obtained from seismic interpretation of the deep structure of the UK sector of the Central North Sea, suggests that late Carboniferous uplift and inversion along a northerly-trending axis analogous to the Pennine anticline controlled rift orientation during the episode of late Jurassic and early Cretaceous extension that formed the Central Graben. Other evidence indicates that subsequent local inversion of the Mesozoic basins in the same area can be spatially linked to the previous framework of late Devonian and early Carboniferous extension. In Scotland, north of the Southern Uplands, the pattern of late Palaeozoic extension in the Midland Valley is similar to that in England and the Central North Sea. Minor differences can be attributed to the greater effect of Laurentian tectonics in Scotland, including the development of Lower Devonian basins and volcanic rocks, and the influence of strike-slip faults of the NNE-trending Great Glen set, which originated between Laurentia and Baltica, largely to the north of the terranes of southern, Gondwanan, affinity. Published regional interpretations of variation in depth to the Moho in the UK can be used to examine the relative contribution of crustal stretching and magmatic underplating across the area.

Magnetostratigraphy of late Devonian carbonates of Western Australia: Integrating reversal history with biostratigraphic and 13C records

NASA Astrophysics Data System (ADS)

Tohver, E.; Playton, T.; Hillbun, K.; Yan, M.; Pisarevsky, S.; Hansma, J.; Roelofs, B.; Trinajstic, K.; Kirschvink, J. L.; Haines, P.

2016-12-01

The Global Polarity Timescale presents a useful basis for chronostratigraphic correlations, but pre-Jurassic records depend on records from sedimentary basins preserved on the continents. At present, the record for the late Devonian is poorly established. Here we present an integrated magnetostratigraphic, biostratigraphic and C-isotope study of the Canning Basin of Western Australia, located on the northern margin of eastern Gondwana. The study region is part of the classic "Devonian Great Barrier Reef", and preserves an outstanding marine record of a prominent mass extinction event (i.e., the Frasnian-Fammenian event, the fifth of the "Big Five" mass extinctions). We present magnetostratigraphic profiles from six different sections (2200 m total) from four separate localities that record different paleowater depths, i.e., lowermost slope to reef/platform deposits of the basin. Correlations between localities are based on conodont assemblages that can be correlated to global records. Paleomagnetic sampling was carried out at the meter-scale for magnetostratigraphic analysis, with duplicate specimens used for carbon isotope stratigraphy. Most samples record a magnetic overprint parallel to the modern geomagnetic direction, but this remanence was removed by laboratory heating to ca. 180°C. Approximately forty percent of samples retain a high temperature characteristic remanent magnetization (ChRM), typically carried by magnetite or hematite. Before using these ChRMs to assign a magnetic polarity, we filtered paleomagnetic directions to eliminate directions >45 degrees from the Fisherian mean direction, avoiding spurious directions and low latitude virtual geomagnetic poles (VGPs) from transitional field directions. The resulting magnetostratigraphic profiles were used to correlate different sections on the basis of matching reversal records, yielding a composite record of the Middle to Late Devonian geomagnetic reversal record. We recognized seventeen major magnetozones, although the total number of individual reversals is much higher. We examine the distribution of both VGPs and ChRMs to assess whether non-Fisherian statistics should be applied to magnetostratigraphic datasets, and we assess the factors that might cause ellipticity of both datasets.

The Neoacadian orogenic core of the souther Appalachians: a Geo-traverse through the migmatitic inner Piedmont from the Brushy Mountains to Lincolnton, North Carolina

USGS Publications Warehouse

Merschat, Arthur J.; Hatcher, Robert D.; Byars, Heather E.; Gilliam, William G.; Eppes, Martha Cary; Bartholomew, Mervin J.

2012-01-01

The Inner Piedmont extends from North Carolina to Alabama and comprises the Neoacadian (360–345 Ma) orogenic core of the southern Appalachian orogen. Bordered to west by the Blue Ridge and the exotic Carolina superterrane to the east, the Inner Piedmont is cored by an extensive region of migmatitic, sillimanite-grade rocks. It is a composite of the peri-Laurentian Tugaloo terrane and mixed Laurentian and peri-Gondwanan affinity Cat Square terrane, which are exposed in several gentle-dipping thrust sheets (nappes). The Cat Square terrane consists of Late Silurian to Early Devonian pelitic schist and metagraywacke intruded by several Devonian to Mississippian peraluminous granitoids, and juxtaposed against the Tugaloo terrane by the Brindle Creek fault. This field trip through the North Carolina Inner Piedmont will examine the lithostratigraphies of the Tugaloo and Cat Square terranes, deformation associated with Brindle Creek fault, Devonian-Mississippian granitoids and charnockite of the Cat Square terrane, pervasive amphibolite-grade Devonian-Mississippian (Neoacadian) deformation and metamorphism throughout the Inner Piedmont, and existence of large crystalline thrust sheets in the Inner Piedmont. Consistent with field observations, geochronology and other data, we have hypothesized that the Carolina superterrane collided obliquely with Laurentia near the Pennsylvania embayment during the Devonian, overrode the Cat Square terrane and Laurentian margin, and squeezed the Inner Piedmont out to the west and southwest as an orogenic channel buttressed against the footwall of the Brevard fault zone.

Paleozoic strata of the Dyckman Mountain area, northeastern Medfra quadrangle, Alaska: A section in Geologic studies in Alaska by the U.S. Geological Survey, 1998

USGS Publications Warehouse

Dumoulin, Julie A.; Bradley, Dwight C.; Harris, Anita G.

2000-01-01

Paleozoic rocks in the Dyckman Mountain area (northeastern Medfra quadrangle; Farewell terrane) include both shallowand deep-water lithologies deposited on and adjacent to a carbonate platform. Shallow-water strata, which were recognized by earlier workers but not previously studied in detail, consist of algal-laminated micrite and skeletal-peloidal wackestone, packstone, and lesser grainstone. These rocks are, at least in part, of Early and (or) Middle Devonian age but locally could be as old as Silurian; they accumulated in shallow subtidal to intertidal settings with periodically restricted water circulation. Deepwater facies, reported here for the first time, are thin, locally graded beds of micrite and calcisiltite and subordinate thick to massive beds of lime grainstone and conglomerate. Conodonts indicate an age of Silurian to Middle Devonian; the most tightly dated intervals are early Late Silurian (early to middle Ludlow). These strata formed as hemipelagic deposits, turbidites, and debris flows derived from shallow-water lithologies of the Nixon Fork subterrane. Rocks in the Dyckman Mountain area are part of a broader facies belt that is transitional between the Nixon Fork carbonate platform to the west and deeper water, basinal lithologies (Minchumina “terrane”) to the east. Transitional facies patterns are complex because of Paleozoic shifts in the position of the platform margin, Mesozoic shortening, and Late Cretaceous-Tertiary disruption by strike-slip faulting.

Palaeomagnetic results from the Palaeozoic of Istanbul: A hypothesis for Remagnetization

NASA Astrophysics Data System (ADS)

Lom, Nalan; Domeier, Mathew; Ülgen, Semih Can; İşseven, Turgay; Celal Şengör, Ali Mehmet

2016-04-01

The Istanbul Zone in northwestern Turkey is a part of a larger continental fragment called the Rhodope-Pontide Fragment. The Istanbul Zone differs from its surroundings by its continuous, well-developed sedimentary sequence extending from the early-medial Ordovician to the early Carboniferous. The İstanbul Zone has a complicated deformation history related to the Hercynide (or Scythide), Cimmeride and Alpide orogenies. Although the region of Istanbul shows essentially no metamorphism and only a weak cleavage development, constraining the entire history of the deformation in the İstanbul Zone marginal fold and thrust belt is a difficult task, primarily due to the multiple deformation phases. But yet it is not impossible. The Palaeozoic sequence is cut by late Cretaceous plutonics together with dacitic and andesitic dykes. This arc magmatism is ascribed to the north-dipping subduction of the Neo-Tethyan ocean along the İzmir-Ankara-Erzincan suture. The Palaeozoic sequence is unconformably overlain by Permian and younger sedimentary strata. In this study a total of 523 samples were obtained from 48 sites around İstanbul and Kocaeli. 465 samples collected from Palaeozoic sedimentary rocks and 58 samples belong to the dykes that cut these sediments. Specimens were demagnetized in the laboratory by using both AF and thermal treatments depending on their effectiveness. After demagnetization treatments, 290 specimens showed stable demagnetization patterns and majority of these samples have a characteristic remanent magnetization component close to the present day geomagnetic field. Demagnetization studies demonstrate variable degrees of overprinting in a large number of samples. After the application of the tilt correction, %70 of the specimens failed the fold test at site level (early Ordovician siltstones; late Silurian-early Devonian limestones; late Devonian limestones; early Carboniferous turbidites). Rest of them clearly got scattered with increasing α95 and decreasing k values (mid Ordovician conglomerates; mid-late Devonian shales; late Ordovician-early Silurian sandstone and siltstones). This secondary magnetization, acquired during or after the folding event, constitutes evidence of pervasive remagnetization that can be caused by regional re-heating related to the Cretaceous arc magmatism. This suggestion contradicts the previous palaeomagnetic studies and requires further and detailed investigation on Palaeozoic sequence.

Wangshangkia, a new Devonian ostracod genus from Dushan of Guizhou, South China

NASA Astrophysics Data System (ADS)

Song, Junjun; Gong, Yiming

2018-02-01

Wangshangkia, a new genus of Ostracoda, from the Late Devonian in Dushan of Guizhou, South China, is described. This genus belongs to the family Bairdiocyprididae Shaver, 1961 and includes two new species, i.e. Wangshangkia dushaniensis and W. bailouiensis. The new genus is characterized by a wide ventral carina with radial striae. It is reported from the Famennian of South China and disappeared just below the Devonian-Carboniferous boundary. Wangshangkia is essentially a benthic crawler and is restricted to the shallow-marine depositional environment with a low hydrodynamic condition. Wangshangkia: urn:lsid:zoobank.org:act:34BF01D4-D202-492D-8E27-BC508EF7EFFB W. dushaniensis: urn:lsid:zoobank.org:act:D267C362-7510-4D19-996B-EA1848D7D025 W. bailouiensis: urn:lsid:zoobank.org:act:FE988AA0-7363-4D9E-A5AB-1526C8DBCDD9

Mid and Late Devonian arenites deposited by sheet-flood, braided streams and rivers in the northern Barrier Ranges, far western New South Wales, Australia

NASA Astrophysics Data System (ADS)

Neef, G.; Bottrill, R. S.; Cohen, D. R.

1996-05-01

Extensive and well exposed, fine-grained fluvial sandstone and less common pebbly coarse-grained fluvial sandstone of Devonian age, crop out in the northern Barrier Ranges of far west New South Wales, Australia. These strata were deposited largely on low-gradient alluvial fans in a basin and range landscape and contain common sedimentary structures (especially streaming lineations and tabular cross-beds). Around 400 of these sedimentary structures were measured to determine the palaeoflow trends of the sheet floods, streams or rivers which deposited the sandstone. The strata are mapped as the Mid Devonian Coco Range Sandstone and the Late Devonian Nundooka Sandstone, which together are around 2.7 km thick. They were deposited at the western margin of the large Emsian to Early Carboniferous Darling Basin. The Coco Range Sandstone is Emsian to Eifelian in age (based on fragments) of fossil fish) and it is separated from the Frasnian-Famennian (Late Devonian) Nundooka Sandstone by the north-trending Nundooka Creek Fault. The eastern boundary of the Nundooka Sandstone is formed by the Western Boundary Fault. Eastward of this fault is the north-trending and 40 km wide Bancannia Trough, which contains gently folded Late Silurian to Early Carboniferous strata up to 7.5 km thick. Most of the Coco Range Sandstone and all of the Nundooka Sandstone are non-graded, fine and very fine-grained, light brown sub-litharenites which are considered to have been deposited mainly on low-gradient alluvial fans. Sedimentary successions of 1.75 to 5.25 m thickness in the fine-grained arenite usually commence with Sm (massive or slumped) → Sh (laminated arenite) or St (trough cross-beds) → Sp (tabular cross-bedded sandstone). An erosional surface commonly underlies the sedimentary successions and they are interpreted to be the result of deposition from decelerating sheet floods. Units composed of tabular cross-bedded strata several metres thick are rarely channelised and are interpreted to represent deposition within braided streams flowing upon the fans or deposited at the margin of sheet floods. In the Coco Range Sandstone there are two sheet-like coarse pebbly arenite units (The Valley Tank and Copi Dam Members) which together total 200 m in thickness. Unimodal palaeocurrent trends and heavy mineral suites from within the coarse-grained arenite indicate a derivation from the south near Broken Hill. Sedimentary structures within the coarse-grained arenite indicate a Platte River style of deposition upon distal braid plains, whereas local interdigitation of coarse-grained arenite with fine arenite strata shows that deposition was essentially continuous (i.e. the coarse arenite do not overlie unconformities) and the two lithotypes represent interdigitation of alluvial fans and braid plain deposition. The northward progradation of the coarse arenite units was probably due to a sudden retardation of basement downwarping.

The hyper-enrichment of V and Zn in black shales of the Late Devonian-Early Mississippian Bakken Formation (USA)

USGS Publications Warehouse

Scott, Clinton T.; Slack, John F.; Kelley, Karen Duttweiler

2017-01-01

Black shales of the Late Devonian to Early Mississippian Bakken Formation are characterized by high concentrations of organic carbon and the hyper-enrichment (> 500 to 1000s of mg/kg) of V and Zn. Deposition of black shales resulted from shallow seafloor depths that promoted rapid development of euxinic conditions. Vanadium hyper-enrichments, which are unknown in modern environments, are likely the result of very high levels of dissolved H2S (~ 10 mM) in bottom waters or sediments. Because modern hyper-enrichments of Zn are documented only in Framvaren Fjord (Norway), it is likely that the biogeochemical trigger responsible for Zn hyper-enrichment in Framvaren Fjord was also present in the Bakken basin. With Framvaren Fjord as an analogue, we propose a causal link between the activity of phototrophic sulfide oxidizing bacteria, related to the development of photic-zone euxinia, and the hyper-enrichment of Zn in black shales of the Bakken Formation.

Early Forest Soils and Their Role in Devonian Global Change

PubMed

Retallack

1997-04-25

A paleosol in the Middle Devonian Aztec Siltstone of Victoria Land, Antarctica, is the most ancient known soil of well-drained forest ecosystems. Clay enrichment and chemical weathering of subsurface horizons in this and other Devonian forested paleosols culminate a long-term increase initiated during the Silurian. From Silurian into Devonian time, red clayey calcareous paleosols show a greater volume of roots and a concomitant decline in the density of animal burrows. These trends parallel the decline in atmospheric carbon dioxide determined from isotopic records of pedogenic carbonate in these same paleosols. The drawdown of carbon dioxide began well before the Devonian appearance of coals, large logs, and diverse terrestrial plants and animals, and it did not correlate with temporal variation in volcanic or metamorphic activity. The early Paleozoic greenhouse may have been curbed by the evolution of rhizospheres with an increased ratio of primary to secondary production and by more effective silicate weathering during Silurian time.

Paleozoic Assemblage of the Northern Sierra Terrane: New Geochronology And Geochemical Data From the Stitching Late Devonian - Early Carboniferous Bowman Lake Batholith, and Associated Rocks

NASA Astrophysics Data System (ADS)

Powerman, V.; Hanson, R. E.; Girty, G.; Tretiakov, A.

2016-12-01

Previous study (Grove et al., 2008) of detrital zircon ages and the timing of magmatism within the Northern Sierra terrane (NST) suggest that it is exotic relative to western Laurentia, and link it to the Paleozoic Arctic Realm, Baltica and Caledonides. NST is a composite terrane in the North America Cordillera, consisting of four distinct allochthons, thrusted upon each other. As a first step towards the understanding of the origin and tectonic development of the NST we have undertaken the SHRIMP-RG U-Pb zircon dating of the rocks from granites, granodiorites, trondhjemites, tonalites and hypabyssal intrusions, composing the Bowman Lake batholith. The batholith stitches the allochthons of the NST and its crystallization age signifies the timing of juxtaposition SHRIMP-RG analyses from 14 samples yielded an age range of ca. 352-369 Ma, which overlaps the Devonian-Mississipian boundary and constrains the minimum age for amalgamation. Additionally, we have acquired multiple XRF data, favoring the island arc provenance of the Bowman Lake batholith Batholith. Previously proposed ties between NST and Robert Mountains allochthon seem unlikely because the latter was accreted onto the western miogeocline of Laurentia during the Late Dev.-Early Miss. while the NST was most probably still situated within the Arctic Realm. This work has been supported by the grant #14.Z50.31.0017 of the Government of the Russian Federation and by the Russian Foundation for Basic Research grant #15-55-10055. We are grateful to Stanford-USGS SHRIMP-RG center, and personally to Marty Grove and Elizabeth Miller.

Tectonics of Antarctica

USGS Publications Warehouse

Hamilton, W.

1967-01-01

Antarctica consists of large and wholly continental east Antarctica and smaller west Antarctica which would form large and small islands, even after isostatic rebound, if its ice cap were melted. Most of east Antarctica is a Precambrian Shield, in much of which charnockites are characteristic. The high Transantarctic Mountains, along the Ross and Weddell Seas, largely follow a geosyncline of Upper Precambrian sedimentary rocks that were deformed, metamorphosed and intruded by granitic rocks during Late Cambrian or Early Ordovician time. The rocks of the orogen were peneplained, then covered by thin and mostly continental Devonian-Jurassic sediments, which were intruded by Jurassic diabase sheets and overlain by plateau-forming tholeiites. Late Cenozoic doming and block-faulting have raised the present high mountains. Northeastern Victoria Land, the end of the Transantarctic Mountains south of New Zealand, preserves part of a Middle Paleozoic orogen. Clastic strata laid unconformably upon the Lower Paleozoic plutonic complex were metamorphosed at low grade, highly deformed and intruded by Late Devonian or Early Carboniferous granodiorites. The overlying Triassic continental sedimentary rocks have been broadly folded and normal-faulted. Interior west Antarctica is composed of miogeosynclinal clastic and subordinate carbonate rocks which span the Paleozoic Era and which were deformed, metamorphosed at generally low grade, and intruded by granitic rocks during Early Mesozoic time and possibly during other times also. Patterns of orogenic belts, if systematic, cannot yet be defined; but fragmentation and rotation of crustal blocks by oroclinal folding and strike-slip faulting can be suggested. The Ellsworth Mountains, for example, consist of Cambrian-Permian metasedimentary rocks that strike northward toward the noncorrelative and latitudinally striking Mesozoic terrane of the Antarctic Peninsula in one direction and southward toward that of the Lower Paleozoic: terrane of the Transantarctic Mountains in the other; the three regions may be separated by great strike-slip faults. The Antarctic Peninsula in west Antarctica, south of South America, consists of metavolcanic and metasedimentary rocks intruded by Late Cretaceous quartz diorite. The pre-granitic rocks are of Jurassic and Early Cretaceous ages wherever they have been dated by fossils, although some crystalline complexes may be older. The S-shape of the peninsula may represent oroclinal bending within Cenozoic time as part of a motion system in which a narrow continental bridge between South America and Antarctica was deformed and ruptured. Perhaps this bridge lagged behind as the larger continental plates drifted into the Pacific Ocean Basin. ?? 1967.

Evidence for long-term climate change in Upper Devonian strata of the central Appalachians

USGS Publications Warehouse

Brezinski, D.K.; Cecil, C.B.; Skema, V.W.; Kertis, C.A.

2009-01-01

The highest 1 to 200 m of the Upper Devonian (Famennian) Catskill and equivalent Hampshire formations exhibit a noticeable vertical or stratigraphic change in color and a shift in lithologic character. The lower part of the unit is characterized by typically red, channel-phase sandstones and overbank siltstone and mudstone containing thin calcareous paleosols. These lithologies give way to greenish gray sandstone containing abundant coaly plant fragments, coalified logs, and pyrite, interbedded with thick intervals of non-calcareous paleo-vertisols. The increase in the prominence of preserved terrestrial organic matter suggests that there was a corresponding increase in the abundance of plants in terrestrial ecosystems. The stratigraphic change in lithology within the upper part of the Catskill-Hampshire succession suggests the onset of environmental conditions that became increasingly wet in response to elevated humid climatic conditions during the final stages of Catskill alluvial plain deposition. The sedimentological signature suggesting increased climatic wetness within the uppermost Catskill and Hampshire formations is nearly contemporaneous with the initiation of Late Devonian Gondwanan glaciation in the paleo-high-latitudes. The Appalachian climate record indicates that this change began during the Fa2c and continued through the latest Famennian, reaching its peak during the Fa2d when glacial deposits are recorded in the paleo-mid-latitudes of the Appalachian basin. Evidence of this late Famennian increase in precipitation also is recorded in the adjacent marine environments. Equivalent-age marine units in Ohio and Kentucky record progressive increases in both total organic carbon and the percentage of terrestrially-derived organic carbon. This suggests that there was a late Famennian increase in terrestrial organic matter productivity, and that during the late Famennian, there were elevated levels of runoff produced by the interpreted increase in precipitation that washed progressively higher amounts of terrestrial organic matter into the local marine environments. The late Famennian climate changes identified within the Appalachian basin strata have been recognizable globally, and appear to have had both positive and negative effects on the Earth's biota. Some marine groups exhibit sharp diversity drops or even extinction coincident with the maximum development of the late Famennian ice age. Conversely, terrestrial biota appears to have been more positively affected by the late Famennian increased wetness that accompanied this progressive climate change. Marked diversification and evolutionary innovation, which appear to coincide with this climatic deviation, can be recognized within terrestrial plant communities and early tetrapod amphibians. ?? 2009 Elsevier B.V. All rights reserved.

Bedrock geologic map of the Nashua South quadrangle, Hillsborough County, New Hampshire, and Middlesex County, Massachusetts

USGS Publications Warehouse

Walsh, Gregory J.; Jahns, Richard H.; Aleinikoff, John N.

2013-01-01

The bedrock geology of the 7.5-minute Nashua South quadrangle consists primarily of deformed Silurian metasedimentary rocks of the Berwick Formation. The metasedimentary rocks are intruded by a Late Silurian to Early Devonian diorite-gabbro suite, Devonian rocks of the Ayer Granodiorite, Devonian granitic rocks of the New Hampshire Plutonic Suite including pegmatite and the Chelmsford Granite, and Jurassic diabase dikes. The bedrock geology was mapped to study the tectonic history of the area and to provide a framework for ongoing hydrogeologic characterization of the fractured bedrock of Massachusetts and New Hampshire. This report presents mapping by G.J. Walsh and R.H. Jahns and zircon U-Pb geochronology by J.N. Aleinikoff. The complete report consists of a map, text pamphlet, and GIS database. The map and text pamphlet are only available as downloadable files (see frame at right). The GIS database is available for download in ESRITM shapefile and Google EarthTM formats, and includes contacts of bedrock geologic units, faults, outcrops, structural geologic information, photographs, and a three-dimensional model.

The Valley and Ridge Province of eastern Pennsylvania - stratigraphic and sedimentologic contributions and problems ( USA).

USGS Publications Warehouse

Epstein, J.B.

1986-01-01

The rocks in the area, which range from Middle Ordovician to Late Devonian in age, are more than 7620 m thick. This diversified group of sedimentary rocks was deposited in many different environments, ranging from deep sea, through neritic and tidal, to alluvial. In general, the Middle Ordovician through Lower Devonian strata are a sedimentary cycle related to the waxing and waning of Taconic tectonism. The sequence began with a greywacke-argillite suite (Martinsburg Formation) representing synorogenic basin deepening. This was followed by basin filling and progradation of a sandstone-shale clastic wedge (Shawangunk Formation and Bloomsburg Red Beds) derived from the erosion of the mountains that were uplifted during the Taconic orogeny. The sequence ended with deposition of many thin units of carbonate, sandstone, and shale on a shelf marginal to a land area of low relief. Another tectonic-sedimentary cycle, related to the Acadian orogeny, began with deposition of Middle Devonian rocks. Deep-water shales (Marcellus Shale) preceded shoaling (Mahantango Formation) and turbidite sedimentation (Trimmers Rock Formation) followed by another molasse (Catskill Formation). -from Author

A late Frasnian (Late Devonian) radiolarian, sponge spicule, and conodont fauna from the Slaven Chert, northern Shoshone Range, Roberts Mountains allochthon, Nevada

USGS Publications Warehouse

Boundy-Sanders, S. Q.; Sandberg, C.A.; Murchey, B.L.; Harris, A.G.

1999-01-01

Co-occuring conodonts, radiolarians, and sponge spicules from the type locality of the Slaven Chert, northern Shoshone Range, Nevada, indicate that the radiolarian and sponge spicule assemblage described herein correlates with the Late rhenana conodont Zone (late Frasnian). The moderately well preserved radiolarians are the first Frasnian-age fauna described from the Western Hemisphere. They include spumellarians, Ceratoikiscum, and Paleoscenidium, and a radiolarian which we have assigned to a new genus, Durahelenifore Boundy-Sanders and Murchey, with its type species, Durahelenifore robustum Boundy-Sanders and Murchey. Sponge spicules include umbellate microscleres of the Subclass Amphidiscophora, Order Hemidiscosa, previously documented only in Pennsylvanian and younger rocks.

Retrospective Case Study in Killdeer, North Dakota, Study of the Potential Impacts of Hydraulic Fracturing on Drinking Water Resources.

EPA Science Inventory

This report describes the retrospective case study conducted near Killdeer, Dunn County, North Dakota. The Killdeer study area is the location of historical oil and gas production, with current unconventional oil and gas production occurring in the late Devonian/early Mississipp...

Provenance of upper Triassic sandstone, southwest Iberia (Alentejo and Algarve basins): tracing variability in the sources

NASA Astrophysics Data System (ADS)

Pereira, M. F.; Ribeiro, C.; Gama, C.; Drost, K.; Chichorro, M.; Vilallonga, F.; Hofmann, M.; Linnemann, U.

2017-01-01

Laser ablation ICP-MS U-Pb analyses have been conducted on detrital zircon of Upper Triassic sandstone from the Alentejo and Algarve basins in southwest Iberia. The predominance of Neoproterozoic, Devonian, Paleoproterozoic and Carboniferous detrital zircon ages confirms previous studies that indicate the locus of the sediment source of the late Triassic Alentejo Basin in the pre-Mesozoic basement of the South Portuguese and Ossa-Morena zones. Suitable sources for the Upper Triassic Algarve sandstone are the Upper Devonian-Lower Carboniferous of the South Portuguese Zone (Phyllite-Quartzite and Tercenas formations) and the Meguma Terrane (present-day in Nova Scotia). Spatial variations of the sediment sources of both Upper Triassic basins suggest a more complex history of drainage than previously documented involving other source rocks located outside present-day Iberia. The two Triassic basins were isolated from each other with the detrital transport being controlled by two independent drainage systems. This study is important for the reconstruction of the late Triassic paleogeography in a place where, later, the opening of the Central Atlantic Ocean took place separating Europe from North America.

Early Carboniferous adakite-like and I-type granites in central Qiangtang, northern Tibet: Implications for intra-oceanic subduction and back-arc basin formation within the Paleo-Tethys Ocean

NASA Astrophysics Data System (ADS)

Liu, Jin-Heng; Xie, Chao-Ming; Li, Cai; Wang, Ming; Wu, Hao; Li, Xing-Kui; Liu, Yi-Ming; Zhang, Tian-Yu

2018-01-01

Recent studies have proposed that the Late Devonian ophiolites in the central Qiangtang region of northern Tibet were formed in an oceanic back-arc basin setting, which has led to controversy over the subduction setting of the Longmucuo-Shuanghu-Lancangjiang Suture Zone (LSLSZ) during the Late Devonian to Early Carboniferous. In this paper we present new data about a suite of granite plutons that intrude into ophiolite in central Qiangtang. Our aim was to identify the type of subduction and to clarify the existence of an intra-oceanic back-arc basin in the LSLSZ during the Late Devonian to Early Carboniferous. The suite of granites consists of monzogranites, syenogranites, and granodiorites. Our laser ablation-inductively coupled plasma-mass spectrometry zircon U-Pb data yielded Early Carboniferous crystallization ages of 357.2 Ma, 357.4 Ma and 351.1 Ma. We subsequently investigated the petrogenesis and tectonic setting of these granites based on their geochemical and Hf isotopic characteristics. First, we divided the granites into high Sr/Y (HSG) and low Sr/Y granites (LSG). The HSG group contains monzogranites and granodiorites that have similar geochemical characteristics to adakites (i.e., high Sr/Y and La/Yb ratios, low MgO, Y, and Yb contents, and no pronounced negative Eu anomaly), although they have slightly lower Sr and Al2O3 contents, caused by crystal fractionation during late magmatic evolution. Therefore, we define the HSG group as adakite-like granites. The study of the HSG shows that they are adakite-like granites formed by partial melting of oceanic crust and experience fractional crystallization process during late evolution. However, some differences between the monzogranites and granodiorites indicate that there are varying degree contributions of subducted sediments during diagenesis. The LSG group contains syenogranites that have distinct negative correlations between their P2O5 and SiO2 contents, and Y and Th contents have significant positive correlations with Rb. The above characteristics indicate that the syenogranites are typical I-type granites. The results of this study also show that the LSG were produced by magma mixing between the mantle and juvenile oceanic crust. The field study found that the Early Carboniferous suite of granites intruded into contemporaneous ophiolites that formed in an intra-oceanic back-arc basin, and were associated with coeval A-type granites in this region. Based on the geochemical and isotopic data presented in this paper and regional geological data, we consider that the HSG were formed during intra-oceanic subduction of the Paleo-Tethys Ocean in the Early Carboniferous. The LSG and A-type granites were formed in an intra-oceanic back-arc basin setting caused by roll-back of the Paleo-Tethys Ocean slab. This confirms that the subduction of the Paleo-Tethys Ocean in the Early Carboniferous was intra-oceanic subduction, and provides important evidence for the existence of an intra-oceanic back-arc basin during the Late Devonian to Early Carboniferous.

Chemostratigraphic and U-Pb geochronologic constraints on carbon cycling across the Silurian-Devonian boundary

NASA Astrophysics Data System (ADS)

Husson, Jon M.; Schoene, Blair; Bluher, Sarah; Maloof, Adam C.

2016-02-01

The Devonian Period hosts extraordinary changes to Earth's biosphere. Land plants began their rise to prominence, with early vascular vegetation beginning its colonization of near-shore environments in the latest Silurian. Across the Silurian-Devonian (Pridoli-Lochkovian) transition, carbon isotope analyses of bulk marine carbonates (δC13carb) from Laurentian and Baltic successions reveal a positive δC13carb shift. Known as the Klonk Event, values reach + 5.8 ‰, making it one of the largest carbon isotope excursions in the Phanerozoic. Assigning rates and durations to these significant events requires a robust, precise Devonian time scale. Here we present 675 micritic matrix and 357 fossil-specific δC13carb analyses from the lower Devonian Helderberg Group of New York and West Virginia that exhibit the very positive δC13carb values observed in other Silurian-Devonian basins. This chemostratigraphic dataset is coupled with 66 ID-TIMS U-Pb dates on single zircons from six ash falls intercalated within Helderberg sediments, including dates on the stratigraphically lowest Devonian ashes yet developed. In this work, we (a) demonstrate that matrix and fossil-specific δC13carb values track one another closely in the Helderberg Group, (b) estimate the Silurian-Devonian boundary age in New York to be 421.3 ± 1.2 Ma (2σ; including decay constant uncertainties), and (c) calculate the time required to evolve from baseline to peak δC13carb values at the onset of the Klonk event to be 1.00 ± 0.25 Myr. Under these constraints, a steady-state perturbation to the global carbon cycle can explain the observed excursion with modern fluxes, as long as DIC concentration in the Devonian ocean remained below ∼2× the modern value. Therefore, potential drivers, such as enhanced burial of organic carbon, need not rely on anomalously high total fluxes of carbon to explain the Klonk Event.

Devonian paleomagnetism of the North Tien Shan: Implications for the middle-Late Paleozoic paleogeography of Eurasia

NASA Astrophysics Data System (ADS)

Levashova, Natalia M.; Mikolaichuk, Alexander V.; McCausland, Philip J. A.; Bazhenov, Mikhail L.; Van der Voo, Rob

2007-05-01

The Ural-Mongol belt (UMB), between Siberia, Baltica and Tarim, is widely recognized as the locus of Asia's main growth during the Paleozoic, but its evolution remains highly controversial, as illustrated by the disparate paleogeographic models published in the last decade. One of the largest tectonic units of the UMB is the Kokchetav-North Tien Shan Domain (KNTD) that stretches from Tarim in the south nearly to the West Siberian Basin. The KNTD comprises several Precambrian microcontinents and numerous remnants of Early Paleozoic island arcs, marginal basins and accretionary complexes. In Late Ordovician time, all these structures had amalgamated into a single contiguous domain. Its paleogeographic position is of crucial importance for elucidating the Paleozoic evolution of the UMB in general and of the Urals in particular. The Aral Formation, located in Kyrgyzstan in the southern part of the KNTD, consists of a thick Upper Devonian (Frasnian) basalt-andesite sequence. Paleomagnetic data show a dual-polarity characteristic component (Dec/Inc = 286° / + 56°, α95 = 9°, k = 21, N = 15 sites). The primary origin of this magnetization is confirmed by a positive test on intraformational conglomerates. We combine this result with other Paleozoic data from the KNTD and show its latitudinal motion from the Late Ordovician to the end of the Paleozoic. The observed paleolatitudes are found to agree well with the values extrapolated from Baltica to a common reference point (42.5°N, 73°E) in our sampling area for the entire interval; hence coherent motion of the KNTD and Baltica is strongly indicated for most of the Paleozoic. This finding contradicts most published models of the UMB evolution, where the KNTD is separated from Baltica by a rather wide Ural Ocean containing one or more major plate boundaries. An exception is the model of Şengör and Natal'in [A.M.C. Şengör, B.A. Natal'in, Paleotectonics of Asia: fragments of a synthesis, in: A. Yin and M. Harrison (eds.), The tectonic evolution of Asia, Cambridge University Press, Cambridge (1996) 486-640], in which coherent paleolatitudinal motion of Baltica and the KNTD is hypothesized — the latter as part of the Kipchak Arc. We suggest a parallel hypothesis, which explains coherent motion of the KNTD and Baltica. In particular, we argue that if a basin with oceanic crust ever existed between the KNTD and Baltica, it was a narrow one without (significant) active spreading in Middle to Late Paleozoic time. Notably, the paleogeographic position of Siberia during the Middle Paleozoic and hence, the width of the Khanty-Mansi Ocean between Siberia, on the one hand, and Baltica-KNTD, on the other hand, remains largely unconstrained, because of the paucity of high-quality Silurian, Devonian and Carboniferous paleomagnetic results from Siberia.

Utility of palmatolepids and icriodontids in recognizing Upper Devonian Series, Stage, and possible substage boundaries

USGS Publications Warehouse

Ziegler, W.; Sandberg, C.A.

2000-01-01

Conodonts are accepted internationally to define Devonian Series and Stage boundaries. Hence, the evolution and taxonomy of pelagic palmatolepids, primarily Palmatolepis and its direct ancestor Mesotaxis, and shallow-water icriodontids, Icriodus, Pelekysgnathus, and "Icriodus", are the major tools for recognizing subdivisions of the Upper Devonian. Palmatolepids are the basis for the Late Devonian Standard Conodont Zonation (ZIEGLER & SANDBERG 1990), whereas icriodontids are the basis for the alternative, integrated shallow-water zonation (SANDBERG & DREESEN 1984). However, an alternative palmatolepid taxonomy for some Frasnian species has been employed recently by some conodont workers using the Montagne Noire (M.N.) zonation, shape analyses of Pa elements, and multielement reconstructions of KLAPPER (1989), KLAPPER & FOSTER (1993); and KLAPPER et al. (1996). Herein, the evolution of palmatolepids and icriodontids is summarized in terms of our zonation and some of the taxonomic differences with the alternative M.N. zonation are exemplified. One of the problems in relating the Standard and M.N. zonations arises from previous errors of interpretation and drafting of the Martenberg section in Germany. This section was designated the reference section for the Frasnian transitans through jamieae Zones by ZIEGLER & SANDBERG (1990). Herein, the early and middle Frasnian zonal boundaries at Martenberg are improved by re-study of our old and recent collections from three profiles, spaced only 4 m apart. Serious problems exist with the Global Stratotype Sections and Points (GSSP's), selected by the Subcommission on Devonian Stratigraphy, following the paleontologic definition of the bases of the Frasnian, Famennian, and Tournaisian Stages, because of the difficulty in making global correlations from these GSSP's. Our summary of these problems should be helpful if future workers decide to relocate these GSSP's.

Terrestrial-marine teleconnections in the Devonian: links between the evolution of land plants, weathering processes, and marine anoxic events

PubMed Central

Algeo, T. J.

1998-01-01

The Devonian Period was characterized by major changes in both the terrestrial biosphere, e.g. the evolution of trees and seed plants and the appearance of multi-storied forests, and in the marine biosphere, e.g. an extended biotic crisis that decimated tropical marine benthos, especially the stromatoporoid-tabulate coral reef community. Teleconnections between these terrestrial and marine events are poorly understood, but a key may lie in the role of soils as a geochemical interface between the lithosphere and atmosphere/hydrosphere, and the role of land plants in mediating weathering processes at this interface. The effectiveness of terrestrial floras in weathering was significantly enhanced as a consequence of increases in the size and geographic extent of vascular land plants during the Devonian. In this regard, the most important palaeobotanical innovations were (1) arborescence (tree stature), which increased maximum depths of root penetration and rhizoturbation, and (2) the seed habit, which freed land plants from reproductive dependence on moist lowland habitats and allowed colonization of drier upland and primary successional areas. These developments resulted in a transient intensification of pedogenesis (soil formation) and to large increases in the thickness and areal extent of soils. Enhanced chemical weathering may have led to increased riverine nutrient fluxes that promoted development of eutrophic conditions in epicontinental seaways, resulting in algal blooms, widespread bottomwater anoxia, and high sedimentary organic carbon fluxes. Long-term effects included drawdown of atmospheric pCO2 and global cooling, leading to a brief Late Devonian glaciation, which set the stage for icehouse conditions during the Permo-Carboniferous. This model provides a framework for understanding links between early land plant evolution and coeval marine anoxic and biotic events, but further testing of Devonian terrestrial-marine teleconnections is needed.

Confirmation of the southwest continuation of the Cat Square terrane, southern Appalachian Inner Piedmont, with implications for middle Paleozoic collisional orogenesis

USGS Publications Warehouse

Huebner, Matthew T.; Hatcher, Robert D.; Merschat, Arthur J.

2017-01-01

Detailed geologic mapping, U-Pb zircon geochronology and whole-rock geochemical analyses were conducted to test the hypothesis that the southwestern extent of the Cat Square terrane continues from the northern Inner Piedmont (western Carolinas) into central Georgia. Geologic mapping revealed the Jackson Lake fault, a ∼15 m-thick, steeply dipping sillimanite-grade fault zone that truncates lithologically distinct granitoids and metasedimentary units, and roughly corresponds with a prominent aeromagnetic lineament hypothesized to represent the southern continuation of the terrane-bounding Brindle Creek fault. Results of U-Pb SHRIMP geochronology indicate Late Ordovician to Silurian granitoids (444–439 Ma) occur exclusively northwest of the fault, whereas Devonian (404–371 Ma) granitoids only occur southeast of the fault. The relatively undeformed Indian Springs granodiorite (three individual bodies dated 317–298 Ma) crosscuts the fault and occurs on both sides, which indicates the Jackson Lake fault is a pre-Alleghanian structure. However, detrital zircon signatures from samples southeast of the Jackson Lake fault reveal dominant Grenville provenance, in contrast to Cat Square terrane detrital zircon samples from the northern Inner Piedmont, which include peri-Gondwanan (600–500 Ma) and a prominent Ordovician-Silurian (∼430 Ma) signature. We interpret the rocks southeast of the Jackson Lake fault to represent the southwestern extension of the Cat Square terrane primarily based on the partitioning of granitoid ages and lithologic distinctions similar to the northern Inner Piedmont.Data suggest Cat Square terrane metasedimentary rocks were initially deposited in a remnant ocean basin setting and developed into an accretionary prism in front of the approaching Carolina superterrane, ultimately overridden by it in Late Devonian to Early Mississippian time. Burial to >20 km resulted in migmatization of lower plate rocks, forming an infrastructure beneath the Carolina superterrane suprastructure. Provenance patterns support ∼250 km of Devonian dextral translation of the composite Inner Piedmont, which places the northern portion of the Inner Piedmont adjacent to a suite of ∼430 Ma plutons in the Virginia Blue Ridge during deposition. The megascopic thrust-nappe structural style of the northern Inner Piedmont, combined with southwest-directed lateral extrusion at mid-crustal depths, may reconcile differences in timing of metamorphism between the Carolina and central Georgia Inner Piedmont and structural contrasts between the Brindle Creek and Jackson Lake faults.

Unique growth strategy in the Earth's first trees revealed in silicified fossil trunks from China.

PubMed

Xu, Hong-He; Berry, Christopher M; Stein, William E; Wang, Yi; Tang, Peng; Fu, Qiang

2017-11-07

Cladoxylopsida included the earliest large trees that formed critical components of globally transformative pioneering forest ecosystems in the Mid- and early Late Devonian (ca. 393-372 Ma). Well-known cladoxylopsid fossils include the up to ∼1-m-diameter sandstone casts known as Eospermatopteris from Middle Devonian strata of New York State. Cladoxylopsid trunk structure comprised a more-or-less distinct cylinder of numerous separate cauline xylem strands connected internally with a network of medullary xylem strands and, near the base, externally with downward-growing roots, all embedded within parenchyma. However, the means by which this complex vascular system was able to grow to a large diameter is unknown. We demonstrate-based on exceptional, up to ∼70-cm-diameter silicified fossil trunks with extensive preservation of cellular anatomy from the early Late Devonian (Frasnian, ca. 374 Ma) of Xinjiang, China-that trunk expansion is associated with a cylindrical zone of diffuse secondary growth within ground and cortical parenchyma and with production of a large amount of wood containing both rays and growth increments concentrically around individual xylem strands by normal cambia. The xylem system accommodates expansion by tearing of individual strand interconnections during secondary development. This mode of growth seems indeterminate, capable of producing trees of large size and, despite some unique features, invites comparison with secondary development in some living monocots. Understanding the structure and growth of cladoxylopsids informs analysis of canopy competition within early forests with the potential to drive global processes. Published under the PNAS license.

Geochronology and geochemistry of late Paleozoic-early Mesozoic igneous rocks of the Erguna Massif, NE China: Implications for the early evolution of the Mongol-Okhotsk tectonic regime

NASA Astrophysics Data System (ADS)

Li, Yu; Xu, Wen-Liang; Wang, Feng; Tang, Jie; Zhao, Shuo; Guo, Peng

2017-08-01

We undertook geochemical and geochronological studies on late Paleozoic-early Mesozoic igneous rocks from the Erguna Massif with the aim of constraining the early evolution of the Mongol-Okhotsk tectonic regime. Zircon crystals from nine representative samples are euhedral-subhedral, display oscillatory growth zoning, and have Th/U values of 0.14-6.48, indicating a magmatic origin. U-Pb dating of zircon using SIMS and LA-ICP-MS indicates that these igneous rocks formed during the Late Devonian (∼365 Ma), late Carboniferous (∼303 Ma), late Permian (∼256 Ma), and Early-Middle Triassic (246-238 Ma). The Late Devonian rhyolites, together with coeval A-type granites, formed in an extensional environment related to the northwestwards subduction of the Heihe-Nenjiang oceanic plate. Their positive εHf(t) values (+8.4 to +14.4) and Hf two-stage model ages (TDM2 = 444-827 Ma) indicate they were derived from a newly accreted continental crustal source. The late Carboniferous granodiorites are geochemically similar to adakites, and their εHf(t) values (+10.4 to +12.3) and Hf two-stage model ages (TDM2 = 500-607 Ma) suggest they were sourced from thickened juvenile lower crustal material, this thickening may be related to the amalgamation of the Erguna-Xing'an and Songnen-Zhangguangcai Range massifs. Rocks of the late Permian to Middle Triassic suite comprise high-K calc-alkaline monzonites, quartz monzonites, granodiorites, and monzogranites. These rocks are relatively enriched in light rare earth elements and large ion lithophile elements, and depleted in heavy rare earth elements and high field strength elements. They were emplaced, together with coeval porphyry-type ore deposits, along an active continental margin where the Mongol-Okhotsk oceanic plate was subducting beneath the Erguna Massif.

Ten Windows Into the Meteorite Flux to Earth During the Past 500 Million Years

NASA Astrophysics Data System (ADS)

Schmitz, B.

2017-12-01

Almost nothing is known about the variations through deep time in the types of meteorites arriving at Earth. In an ongoing project we are searching ancient sediments from ten different time periods through the Phanerozoic for relict extraterrestrial spinel grains from micrometeorites (Schmitz, 2013). Samples, 300-1500 kg large, of slowly formed pelagic limestone are dissolved in acids leaving a residue of extraterrestrial spinels. The time periods studied include the middle Cambrian, Ordovician before and after the breakup of the L-chondrite parent body, late Silurian, late Devonian, middle Jurassic, early and late Cretaceous, early Paleocene and late Eocene. The approach builds on complex methodological considerations and a thorough understanding also of the spinel fraction in recent meteorites is necessary. In order to obtain some insights into the changes in the meteorite flux carefully calibrated analyses of the isotopic and elemental composition of the recovered spinel grains as well as consistent data treatment is required for the different time windows. Our results indicate that the background meteorite flux has changed significantly through the Phanerozoic. The results so far suggest that there may have been a gradual long-term (on the order of hundred million years) turnover in the meteorite flux from dominance of achondrites in the early Phanerozoic to ordinary chondrites in the late Phanerozoic interrupted by short-term (a few million years) meteorite cascades from single asteroid breakup events. This scenario may change, however, as results from additional time windows emerge. B. Schmitz (2013) Extraterrestrial spinels and the astronomical perspective on Earth's geological record and evolution of life: Chemie der Erde 73:117-145.

Tectonic setting of synorogenic gold deposits of the Pacific Rim

USGS Publications Warehouse

Goldfarb, R.J.; Phillips, G.N.; Nokleberg, W.J.

1998-01-01

More than 420 million oz of gold were concentrated in circum-Pacific synorogenic quartz loades mainly during two periods of continental growth, one along the Gondwanan margin in the Palaeozoic and the other in the northern Pacific basin between 170 and 50 Ma. These ores have many features in common and can be grouped into a single type of lode gold deposit widespread throughout clastic sedimentary-rock dominant terranes. The auriferous veins contain only a few percent sulphide minerals, have gold:silver ratios typically greater than 1:1, show a distinct association with medium grade metamorphic rocks, and may be associated with large-scale fault zone. Ore fluids are consistently of low salinity and are CO2-rich. In the early and middle Palaeozoic in the southern Pacific basin, a single immense turbidite sequence was added to the eastern margin of Gondwanaland. Deformation of these rocks in southeastern Australia was accompanied by deposition of at least 80 million oz of gold in the Victorian sector of the Lachlan fold belt mainly during the Middle and Late Devonian. Lesser Devonian gold accumulations characterized the more northerly parts of the Gondwanan margin within the Hodgkinson-Broken River and Thomson fold belts. Additional lodes were emplaced in this flyschoid sequence in Devonian or earlier Palaeozoic times in what is now the Buller Terrane, Westland, New Zealand. Minor post-Devonian growth of Gondwanaland included terrane collision and formation of gold-bearing veins in the Permian in Australia's New England fold belt and in the Jurassic-Early Cretaceous in New Zealand's Otago schists. Collision and accretion of dozens of terranes for a 100-m.y.-long period against the western margin of North America and eastern margin of Eurasia led to widespread, lattest Jurassic to Eocene gold veining in the northern Pacific basin. In the former location, Late Jurassic and Early Cretaceous veins and related placer deposits along the western margin of the Sierra Nevada batholith have yielded more than 100 million oz of gold. Additional significant ore-forming events during the development of North America's Cordilleran orogen included those in the Klamath Mountains region, California in the Late Jurassic and Early Cretaceous; the Klondike district, Yukon by the Early Cretaceous; the Nome and Fairbanks districts, Alaska, and the Bridge River district, British Columbia in the middle Cretaceous; and the Juneau gold belt, Alaska in the Eocene. Gold-bearing veins deposited during the Late Jurassic and Early Cretaceous terrane collision that formed the present-day Russian Far East have been the source for more than 130 million oz of placer gold. The abundance of gold-bearing quartz-carbonate veins throughout the Gondwanan, North American and Eurasian continental margins suggests the migration and concentration of large fluid volumes during continental growth. Such volumes could be released during orogenic heating of hydrous silicate mineral phases within accreted marine strata. The common temporal association between gold veining and magmatism around the Pacific Rim reflects these thermal episodes. Melting of the lower thickened crust during arc formation, slab rollback and extensional tectonism, and subduction of a slab window beneath the seaward part of the forearc region can all provide the required heat for initation of the ore-forming processes.

A new model for the provenance of the Upper Devonian Old Red Sandstone (UORS) of southern Ireland

NASA Astrophysics Data System (ADS)

Ennis, Meg; Meere, Pat; Timmerman, Martin

2010-05-01

The geology of Southern Ireland is dominated by the influence of both the Caledonian and Variscan orogenies which have shaped the landscape of today. The Old Red Sandstone (ORS) sequences of the Middle - Upper Devonian Munster Basin have traditionally been viewed as a post-orogenic molasse deposit sourced from the Caledonides (Friend et al. 2000 & references therein), which were subsequently deformed by the Late Carboniferous Variscan Orogeny. This model does not take into account the potential impact of the Acadian Orogeny, an Early to Mid Devonian transpressional tectonic event which culminated in Mid Emsian times and resulted in the deformation and inversion of Lower ORS (LORS) basins across Britain and Ireland (Soper & Woodcock 2003; Meere & Mulchrone 2006). Evidence of Acadian deformation in Southern Ireland is recorded in the LORS sequence of the Lower-Middle Devonian basin, the Dingle Basin. Meere & Mulchrone (2006) show that penetrative deformation visible in the LORS of the Dingle Basin has an Acadian signature and is not associated with Late Carboniferous Variscan compression (Parkin 1976; Todd 2000). The role of the Acadian Orogeny in the tectono-sedimentary evolution of Southern Ireland has been analyzed in this study using a multidisciplinary approach. Petrographic analysis of both the LORS and Upper ORS (UORS) of southern Ireland suggests an alternative provenance model in which there is a direct genetic link between the two Devonian deposits. There is a fining-up relationship between the two basins and the volcanic lithic fragments - while extremely limited in occurrence in the Munster Basin - are strikingly similar in both units. The absence of conglomeratic units at the base of the Munster Basin provide further evidence that the UORS does not represent a classic molasse deposit. This is supported by EMPA data from both basins which indicates identical mica chemistries in both the LORS and UORS. A comparison with the white mica chemistries from a variety of source areas suggests that the mica chemistry is similar to both the Irish Caledonides and also to the Scandian micas; therefore the ultimate source area of the ORS detritus remains ambiguous. This relationship is confirmed by the 40Ar/39Ar step-heating and total fusion age dating which yields Acadian apparent ages for the detrital white mica component in both basins; apparent ages for the Munster Basin micas are in the range 403 to 388 Ma. The Dingle Basin micas yield ages in the range 405 to 385 Ma. The presence of Acadian age micas in both basins and the similarity in mica chemistry suggest an alternative provenance model in which the LORS deposits of the Dingle Basin are inverted and recycled southwards into the UORS Munster Basin. References: Friend, P.F., Williams, B.P.J. and Williams, E.A. 2000. Kinematics and dynamics of Old Red Sandstone basins. In: Friend, P.F., and Williams, B.P.J. (eds.). New Perspectives on the Old Red Sandstone. Geological Society of London Special Publications, 180, 29-60. Meere, P.A. and Mulchrone, K.F. 2006. Timing of deformation within the Old Red Sandstone lithologies from the Dingle Peninsula, SW Ireland. Journal of the Geological Society of London, 163, 461-469. Parkin, J. 1976. Silurian rocks of the Bull's Head, Annascaul and Derrymore Glen inliers, Co. Kerry. Proceedings of the Royal Irish Academy 76B, 577-606. Soper, N.J., and Woodcock, N.H., 2003, The lost Lower Old Red Sandstone of England and Wales: a record of post-Iapetan flexure or Early Devonian transtension? Geological Magazine, 140, 627-647. Todd, S.P., Connery, C., Higgs, K.T. and Murphy, F.C. 2000. An Early Ordovician age for the Annascaul Formation of the SE Dingle Peninsula, SW Ireland. Journal of the Geological Society of London, 157, 823-833.

Late Paleozoic to Cenozoic reconstruction of the Arctic

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, D.G.

1985-04-01

The plate tectonic evolution of the Arctic is reassessed in the context of the known histories of the North Atlantic and North Pacific Oceans, and of the tectono-stratigraphic development of the lands around the Arctic Ocean. Computer map-drawing facilities were used to provide geometrical constraints on the reconstructions, which are presented to in the form of eight palinispatic maps. Stratigraphic similarities among presently dispersed continental areas identify fragments of a former Barents plate. Collision of this plate with the Euramerican plate was the cause of the Late Devonian Ellesmerian orogeny. In later Paleozoic time, the Siberian continent also joined Pangeamore » by collision with the combined Barents and Euramerican plates along the Ural-Taymyr suture. The Mesozoic-Cenozoic history of the Arctic is concerned with the fragmentation and dispersal of the former Barents plate, as well as the accretion of new continental fragments from the Pacific.« less

Changing CO2 and the evolution of terrestrial and marine photosynthetic organisms during the terrestrialization process in the Palaeozoic.

NASA Astrophysics Data System (ADS)

Vecoli, M.; Strother, P. K.; Servais, T.

2009-04-01

The comparative analysis, at the scale of the entire Phanerozoic, of the curves of modelled variation in atmospheric CO2, of global phytoplankton diversity, and of the major steps in land plant evolution, shows interesting and somewhat unexpected correlations that can be explained in a coherent conceptual model linking the terrestrialization process, the global carbon cycle, and the evolution of the large oceanic phytoplankton. A simple model for the evolution of land plants can be proposed which subdivides the terrestrialization process into a sequence of four successive terrestrial autotrophic biomes: a cyanobacterial-dominated microbial landscape (microbial mats: 2.2 Gy), a bryophyte-dominated subaerial biome similar to posterlands, sensu Retallack (1993) (thalloid bryophytes: 523-513 My), a polysporangiophytic biome that includes both rhyniophytoids and tracheophytes which do not possess secondary xylem (tracheophyes: 426-423 My), and a forested biome composed of plants that possessed secondary xylem (lignophytes: 385-375 My). These stages represent successive incremental increases levels of biomass (thus of sequestration of carbon), and of weathering of parent rock (depth of the rhizosphere). Apart from the microbial mats biome, each of the three successive stages corresponds to a subsequent drop in paleo-CO2 levels as established in the GEOCARB III model. This was not an expected result of our analysis, because the primary effect of terrestrialization should not have been felt until the rise of the forested (Lignophyte) biome during the Late Devonian. Nevertheless, it seems a remarkable coincidence that each of three periods of the most significant drops in the CO2 model begins exactly at the time of the origin of each successive vegetative biome. It is therefore proposed that the cumulative increase in biomass retention (which corresponds to the successive establishment of terrestrial biomes) contributed significantly to a drawdown of pCO2 due to the sequestration of Corg in organic matter trapped in plant biomass, litter, soils, and buried in sediments, adding up to the better known effect of increased weathering due to the evolution of deep rooting systems during late Devonian time onwards. In this study, we also examined the potential perturbations to the phytoplankton of the mid-Palaeozoic marine realm as CO2(aq) declined and as POM and DOM delivery to the shallow shelf increased nutrient flux to the oceans. We used the fossil record of acritarchs as a proxy for the large phytoplankton of the Palaeozoic. Our data show that the standing diversity of acritarchs (genus-level taxon richness) is highly correlated with the decline in Palaeozoic pCO2 as modelled by Berner and Kothavala (2001); the two curves show the same trends, the acritarch diversity curve being offset, on average, by a -10 my time lag. We propose that the gradual (and not catastrophic as previously assumed) decline in acritarch diversity observed during late Silurian - late Devonian times was causally linked to the decline in dissolved CO2 in the oceans and the associated increase in oceanic pH, which were in turn caused by the falling pCO2 in the atmosphere. These observations appear to link the decline of the acritarchs to the rise of the terrestrial biota through the effect of terrestrialization on pCO2.

Microbes and mass extinctions: paleoenvironmental distribution of microbialites during times of biotic crisis.

PubMed

Mata, S A; Bottjer, D J

2012-01-01

Widespread development of microbialites characterizes the substrate and ecological response during the aftermath of two of the 'big five' mass extinctions of the Phanerozoic. This study reviews the microbial response recorded by macroscopic microbial structures to these events to examine how extinction mechanism may be linked to the style of microbialite development. Two main styles of response are recognized: (i) the expansion of microbialites into environments not previously occupied during the pre-extinction interval and (ii) increases in microbialite abundance and attainment of ecological dominance within environments occupied prior to the extinction. The Late Devonian biotic crisis contributed toward the decimation of platform margin reef taxa and was followed by increases in microbialite abundance in Famennian and earliest Carboniferous platform interior, margin, and slope settings. The end-Permian event records the suppression of infaunal activity and an elimination of metazoan-dominated reefs. The aftermath of this mass extinction is characterized by the expansion of microbialites into new environments including offshore and nearshore ramp, platform interior, and slope settings. The mass extinctions at the end of the Triassic and Cretaceous have not yet been associated with a macroscopic microbial response, although one has been suggested for the end-Ordovician event. The case for microbialites behaving as 'disaster forms' in the aftermath of mass extinctions accurately describes the response following the Late Devonian and end-Permian events, and this may be because each is marked by the reduction of reef communities in addition to a suppression of bioturbation related to the development of shallow-water anoxia. © 2011 Blackwell Publishing Ltd.

Productivity Contribution of Paleozoic Woodlands to the Formation of Shale-Hosted Massive Sulfide Deposits in the Iberian Pyrite Belt (Tharsis, Spain)

NASA Astrophysics Data System (ADS)

Fernández-Remolar, David C.; Harir, Mourad; Carrizo, Daniel; Schmitt-Kopplin, Philippe; Amils, Ricardo

2018-03-01

The geological materials produced during catastrophic and destructive events are an essential source of paleobiological knowledge. The paleobiological information recorded by such events can be rich in information on the size, diversity, and structure of paleocommunities. In this regard, the geobiological study of late Devonian organic matter sampled in Tharsis (Iberian Pyrite Belt) provided some new insights into a Paleozoic woodland community, which was recorded as massive sulfides and black shale deposits affected by a catastrophic event. Sample analysis using TOF-SIMS (Time of Flight Secondary Ion Mass Spectrometer), and complemented by GC/MS (Gas Chromatrograph/Mass Spectrometer) identified organic compounds showing a very distinct distribution in the rock. While phytochemical compounds occur homogeneously in the sample matrix that is composed of black shale, the microbial-derived organics are more abundant in the sulfide nodules. The cooccurrence of sulfur bacteria compounds and the overwhelming presence of phytochemicals provide support for the hypothesis that the formation of the massive sulfides resulted from a high rate of vegetal debris production and its oxidation through sulfate reduction under suboxic to anoxic conditions. A continuous supply of iron from hydrothermal activity coupled with microbial activity was strictly necessary to produce this massive orebody. A rough estimate of the woodland biomass was made possible by accounting for the microbial sulfur production activity recorded in the metallic sulfide. As a result, the biomass size of the late Devonian woodland community was comparable to modern woodlands like the Amazon or Congo rainforests.

Formation and inversion of transtensional basins in the western part of the Lachlan Fold Belt, Australia, with emphasis on the Cobar Basin

NASA Astrophysics Data System (ADS)

Glen, R. A.

The Palaeozoic history of the western part of the Lachlan Fold Belt in New South Wales was dominated by strike-slip tectonics. In the latest Silurian to late Early Devonian, an area of crust >25,000 km 2 lying west of the Gilmore Suture underwent regional sinistral transtension, leading to the development of intracratonic successor basins, troughs and flanking shelves. The volcaniclastic deep-water Mount Hope Trough and Rast Trough, the siliciclastic Cobar Basin and the volcanic-rich Canbelego-Mineral Hill Belt of the Kopyje Shelf all were initiated around the Siluro-Devonian boundary. They all show clear evidence of having evolved by both active syn-rift processes and passive later post-rift (sag-phase) processes. Active syn-rift faulting is best documented for the Cobar Basin and Mount Hope Trough. In the former case, the synchronous activity on several fault sets suggests that the basin formed by sinistral transtension in response to a direction of maximum extension oriented NE-SW. Structures formed during inversion of the Cobar Basin and Canbelego-Mineral Hill Belt indicate closure under a dextral transpressive strain regime, with a far-field direction of maximum shortening oriented NE-SW. In the Cobar Basin, shortening was partitioned into two structural zones. A high-strain zone in the east was developed into a positive half-flower structure by re-activation of early faults and by formation of short-cut thrusts, some with strike-slip movement, above an inferred steep strike-slip fault. Intense subvertical cleavage, a steep extension lineation and variably plunging folds are also present. A lower-strain zone to the west developed by syn-depositional faults being activated as thrusts soling into a gently dipping detachment. A subvertical cleavage and steep extension lineation are locally present, and variably plunging folds are common. Whereas Siluro-Devonian basin-opening appeared to be synchronous in the western part of the fold belt, the different period of basin inversion in the Cobar region (late Early Devonian and Carboniferous) may reflect different movement histories on the master strike-slip faults in this part of the fold belt, the Gilmore Suture and Kiewa Fault.

Sea-level changes vs. organic productivity as controls on Early and Middle Devonian bioevents: Facies- and gamma-ray based sequence-stratigraphic correlation of the Prague Basin, Czech Republic

NASA Astrophysics Data System (ADS)

Bábek, Ondřej; Faměra, Martin; Šimíček, Daniel; Weinerová, Hedvika; Hladil, Jindřich; Kalvoda, Jiří

2018-01-01

The Devonian marine stratigraphic record is characterized by a number of bioevents - overturns in pelagic and benthic faunal assemblages, which are associated with distinct changes in lithology. The coincidence of lithologic and biotic changes can be explained by the causal link between biotic evolution, carbonate production and relative sea-level changes. To gain insight into the sea-level history of Early and Middle Devonian bioevents (the Lochkovian/Pragian Event, Basal Zlíchovian E., Daleje E., and Choteč E.) we carried out a sequence-stratigraphic analysis of carbonate-dominated successions in the Prague Basin (peri-Gondwana), a classic area of Devonian bioevents. The study is based on a basin-wide correlation of facies and field gamma-ray spectrometry (GRS) logs from 18 sections (Lochkovian to Eifelian), supported by element geochemistry and published biostratigraphic and carbon isotope data. Devonian carbonate deposition in the Prague Basin alternated between two end-member modes: an oligotrophic, homoclinal ramp (Praha and Daleje-Třebotov Formations) and a mesotrophic, distally steepened ramp (Lochkov, Zlíchov, and Choteč Formations). They show contrasting facies, particularly the absence/presence of gravity-flow deposits, allochem composition, U/Th ratios, and geochemical composition (productivity proxies such as P/Al, Si/Al, Zn/Al, TOC and stable carbon isotopes). The mesotrophic systems reflect an increased availability of nutrients on the shelf during the late Lochkovian, early Emsian (Zlíchovian), and Eifelian periods when sea surface temperature, pCO2, and silicate weathering rates were higher. The oligotrophic systems deposited during the Pragian-to-earliest Emsian and late Emsian (Dalejan) periods reflect reversed palaeoclimatic trends. We identified three depositional sequences (DS), DS1 (base of Pragian to early Emsian); DS2 (early Emsian to mid Emsian); and DS3 (mid Emsian to mid Eifelian). These sequences were integrated into a peri-Gondwana relative sea-level curve, which was then compared with the Euramerican sea-level curve of Johnson et al. (1985). The bioevents coincided with several sequence stratigraphic surfaces, representing variable limbs of the relative sea-level curve. On the other hand, their conspicuous coincidence with the switching intervals between the colder oligotrophic and warmer mesotrophic modes suggests that organic production linked to global climate was the primary control on biotic overturns, while sea-level fluctuations may have only amplified its effects.

The Anarak, Jandaq and Posht-e-Badam metamorphic complexes in central Iran: New geological data, relationships and tectonic implications

NASA Astrophysics Data System (ADS)

Bagheri, Sasan; Stampfli, Gérard M.

2008-04-01

The Anarak, Jandaq and Posht-e-Badam metamorphic complexes occupy the NW part of the Central-East Iranian Microcontinent and are juxtaposed with the Great Kavir block and Sanandaj-Sirjan zone. Our recent findings redefine the origin of these complexes, so far attributed to the Precambrian-Early Paleozoic orogenic episodes, and now directly related to the tectonic evolution of the Paleo-Tethys Ocean. This tectonic evolution was initiated by Late Ordovician-Early Devonian rifting events and terminated in the Triassic by the Eocimmerian collision event due to the docking of the Cimmerian blocks with the Asiatic Turan block. The "Variscan accretionary complex" is a new name we proposed for the most widely distributed metamorphic rocks connected to the Anarak and Jandaq complexes. This accretionary complex exposed from SW of Jandaq to the Anarak and Kabudan areas is a thick and fine grain siliciclastic sequence accompanied by marginal-sea ophiolitic remnants, including gabbro-basalts with a supra-subduction-geochemical signature. New 40Ar/ 39Ar ages are obtained as 333-320 Ma for the metamorphism of this sequence under greenschist to amphibolite facies. Moreover, the limy intercalations in the volcano-sedimentary part of this complex in Godar-e-Siah yielded Upper Devonian-Tournaisian conodonts. The northeastern part of this complex in the Jandaq area was intruded by 215 ± 15 Ma arc to collisional granite and pegmatites dated by ID-TIMS and its metamorphic rocks are characterized by some 40Ar/ 39Ar radiometric ages of 163-156 Ma. The "Variscan" accretionary complex was northwardly accreted to the Airekan granitic terrane dated at 549 ± 15 Ma. Later, from the Late Carboniferous to Triassic, huge amounts of oceanic material were accreted to its southern side and penetrated by several seamounts such as the Anarak and Kabudan. This new period of accretion is supported by the 280-230 Ma 40Ar/ 39Ar ages for the Anarak mild high-pressure metamorphic rocks and a 262 Ma U-Pb age for the trondhjemite-rhyolite association of that area. The Triassic Bayazeh flysch filled the foreland basin during the final closure of the Paleo-Tethys Ocean and was partly deposited and/or thrusted onto the Cimmerian Yazd block. The Paleo-Tethys magmatic arc products have been well-preserved in the Late Devonian-Carboniferous Godar-e-Siah intra-arc deposits and the Triassic Nakhlak fore-arc succession. On the passive margin of the Cimmerian block, in the Yazd region, the nearly continuous Upper Paleozoic platform-type deposition was totally interrupted during the Middle to Late Triassic. Local erosion, down to Lower Paleozoic levels, may be related to flexural bulge erosion. The platform was finally unconformably covered by Liassic continental molassic deposits of the Shemshak. One of the extensional periods related to Neo-Tethyan back-arc rifting in Late Cretaceous time finally separated parts of the Eocimmerian collisional domain from the Eurasian Turan domain. The opening and closing of this new ocean, characterized by the Nain and Sabzevar ophiolitic mélanges, finally transported the Anarak-Jandaq composite terrane to Central Iran, accompanied by large scale rotation of the Central-East Iranian Microcontinent (CEIM). Due to many similarities between the Posht-e-Badam metamorphic complex and the Anarak-Jandaq composite terrane, the former could be part of the latter, if it was transported further south during Tertiary time.

Paleocurrent analysis of a deformed Devonian foreland basin in the northern Appalachians, Maine, USA

USGS Publications Warehouse

Bradley, D.C.; Hanson, L.S.

2002-01-01

New paleocurrent data indicate that the widespread Late Silurian and Devonian flysch and molasse succession in Maine was deposited in an ancestral, migrating foreland basin adjacent to an advancing Acadian orogenic belt. The foreland-basin sequence spread across a varied Silurian paleogeography of deep basins and small islands-the vestiges of an intraoceanic arc complex that not long before had collided with the Laurentian passive margin during the Ordovician Taconic Orogeny. We report paleocurrents from 43 sites representing 12 stratigraphic units, the most robust and consistent results coming from three units: Madrid Formation (southwesterly paleoflow), Carrabassett Formation (northerly paleoflow), and Seboomook Group (westerly paleoflow). Deformation and regional metamorphism are sufficiently intense to test the limits of paleocurrent analysis requiring particular care in retrodeformation. ?? 2002 Elsevier Science B.V. All rights reserved.

Sedimentology and stratigraphy of the Kanayut Conglomerate, central and western Brooks Range, Alaska; report of 1981 field season

USGS Publications Warehouse

Nilsen, T.H.; Moore, T.E.

1982-01-01

The Upper Devonian and Lower Mississippian(?) Kanayut Conglomerate forms a major stratigraphic unit along the crest of the Brooks Range of northern Alaska. It crops out for an east-west distance of about 900 km and a north-south distance of about 65 km. The Kanayut is wholly allochthonous and has probably been transported northward on a series of thrust plates. The Kanayut is as thick as 2,600 m in the east-central Brooks Range. It thins and fines to the south and west. The Kanayut forms the middle part of the allochthonous sequence of the Endicott Group, an Upper Devonian and Mississippian clastic sequence underlain by platform limestones of the Baird Group and overlain by platform limestone, carbonaceous shale, and black chert of the Lisburne Group. The Kanayut overlies the marine Upper Devonian Noatak Sandstone or, where it is missing, the marine Upper Devonian Hunt Fork Shale. It is overlain by the marine Mississippian Kayak Shale. The Kanayut Conglomerate forms the fluvial part of a large, coarse-grained delta that prograded to the southwest in Late Devonian time and retreated in Early Mississippian time. Four sections of the Kanayut Conglomerate in the central Brooks Range and five in the western Brooks Range were measured in 1981. The sections from the western Brooks Range document the presence of fluvial cycles in the Kanayut as far west as the shores of the Chukchi Sea. The Kanayut in this area is generally finer grained than it is in the central and eastern Brooks Range, having a maximum clast size of 3 cm. It is probably about 300 m thick. The upper and lower contacts of the Kanayut are gradational. The lower Kanayut contains calcareous, marine-influenced sandstone within channel deposits, and the upper Kanayut contains probable marine interdistributary-bay shale sequences. The members of the Kanayut Conglomerate cannot be differentiated in this region. In the central Brooks Range, sections of the Kanayut Conglomerate at Siavlat Mountain and Kakivilak Creek are typically organized into fining-upward fluvial cycles. The maximum clast size is about 3 cm in this area. The Kanayut in this region is 200-500 m thick and can be divided into the Ear Peak, Shainin Lake, and Stuver Members. The upper contact of the Kanayut with the Kayak Shale is very gradational at Kakivilak Creek and very abrupt at Siavlat Mountain. Paleocurrents from fluvial strata of the Kanayut indicate sediment transport toward the west and south in both the western and central Brooks Range. The maximum clast size distribution generally indicates westward fining from the Shainin Lake region.

Mid to late Devonian back-arc rift basins in the Brooks Range, AK, and across the Arctic: a possible paleogeographic piercing point for Arctic reconstructions

NASA Astrophysics Data System (ADS)

Hoiland, C. W.; Miller, E. L.; Hourigan, J. K.

2013-12-01

The westernmost Brooks Range, Alaska, is underlain by basement of probable Baltic or Timanian affinity (e.g. Miller et al., 2011; Amato et al., 2009), while the eastern Brooks Range is underlain by Laurentian affinity basement (e.g. Strauss et al., 2013). A post-Timanian and pre-Mississippian suture or contact is thus required based on continuity of late Devonian and younger strata across the Brooks Range (e.g. Dumoulin et al., 2002). This inferred juxtaposition has been proposed as the distal and diachronous (though possibly non-collisional) continuation of the Caledonian orogen (e.g. Moore et al., 2012) but the actual location and character of this suture within basement rocks of the Brooks Range remain speculative. New laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb single grain detrital zircon (DZ) geochronology of basement rocks from the Cosmos Hills, Slate Creek, and Wiseman regions suggest that metamorphic rocks in these regions are Devonian, not pre-Devonian. New SHRIMP-RG analyses of the Kogoluktuk orthogneiss (Cosmos) (zircon: 383 Ma × 5 Ma, 2-sigma errors, consistent with Dillon et al. 1980) revealed no inherited cores from which to infer basement affinity. DZ spectra from metasedimentary and metavolcanic wall rock contain youngest detrital zircon populations with ages (390 Ma) just barely older than the cross-cutting intrusive age, providing tight bracketing of depositional age. These zircon ages are noticeably younger than Caledonian magmatic ages (430-420 Ma) suggesting deposition in a volcanically and tectonically active setting (likely extensional) as originally suggested by Hitzman et al (1986). Zircon spectra (Cosmos) contain notable amounts of "Timanian" age zircons (c. 700-550 Ma), and a spread of zircons from 1-2 Ga (including 1.5-1.6 Ga ages of the Laurentian "magmatic gap', e.g. Grove et al. 2008) more typical of derivation from Baltic rather than Laurentian sources. East in the Wiseman and Slate Creek localities, the detrital signature becomes characteristically Laurentian, with a notable absence of Timanian and "magmatic gap" ages. A youngest age population of 390 Ma still provides a maximum depositional age, but minimum age is poorly constrained. The coarse and feldspathic nature of many of these intercalated volcanic and clastic sequences suggests a proximal provenance, thus serving as a proxy for local pre-Devonian basement ages and affinity. We might, therefore, infer a non-Laurentian basement for the AACM at least as far east as the Cosmos Hills but not further east than the Wiseman region. These Devonian-age volcanic/rift basins may be related to slab roll-back and induced backarc rifting that occurred obliquely across a 'Caledonian' suture, possibly in response to global plate re-organization. Rifting, accompanied by bimodal volcanism (the Ambler Sequence), may have aided the removal and translation of peri-Baltic terranes to a position outboard of the proto-Cordilleran margin ('Northwestern Passage' of Colpron & Nelson, 2009). Further correlations might be drawn with the Sakmarian-Magnitogorsk arcs of the pre-Uralian margin of Europe. These Devonian backarc rift sequences - more widespread than previously thought - may serve as critical additional tie-points for paleogeographic reconstructions of the Arctic.

Geochronology and geochemistry of basaltic rocks from the Sartuohai ophiolitic mélange, NW China: Implications for a Devonian mantle plume within the Junggar Ocean

NASA Astrophysics Data System (ADS)

Yang, Gaoxue; Li, Yongjun; Santosh, M.; Yang, Baokai; Yan, Jing; Zhang, Bing; Tong, Lili

2012-10-01

The West Junggar domain in NW China is a distinct tectonic unit of the Central Asian Orogenic Belt (CAOB). It is composed of Paleozoic ophiolitic mélanges, arcs and accretionary complexes. The Sartuohai ophiolitic mélange in the eastern West Junggar forms the northeastern part of the Darbut ophiolitic mélange, which contains serpentinized harzburgite, pyroxenite, dunite, cumulate, pillow lava, abyssal radiolarian chert and podiform chromite, overlain by the Early Carboniferous volcano-sedimentary rocks. In this paper we report new geochronological and geochemical data from basaltic and gabbroic blocks embedded within the Sartuohai ophiolitic mélange, to assess the possible presence of a Devonian mantle plume in the West Junggar, and evaluate the petrogenesis and implications for understanding of the Paleozoic continental accretion of CAOB. Zircon U-Pb analyses from the alkali basalt and gabbro by laser ablation inductively coupled plasma mass spectrometry yielded weighted mean ages of 375 ± 2 Ma and 368 ± 11 Ma. Geochemically, the Sartuohai ophiolitic mélange includes at least two distinct magmatic units: (1) a Late Devonian fragmented ophiolite, which were produced by ca. 2-10% spinel lherzolite partial melting in arc-related setting, and (2) contemporary alkali lavas, which were derived from 5% to 10% garnet + minor spinel lherzolite partial melting in an oceanic plateau or a seamount. Based on detailed zircon U-Pb dating and geochemical data for basalts and gabbros from the Sartuohai ophiolitic mélange, in combination with previous work, indicate a complex evolution by subduction-accretion processes from the Devonian to the Carboniferous. Furthermore, the alkali basalts from the Sartuohai ophiolitic mélange might be correlated to a Devonian mantle plume-related magmatism within the Junggar Ocean. If the plume model as proposed here is correct, it would suggest that mantle plume activity significantly contributed to the crustal growth in the CAOB.

Paleozoic Hydrocarbon-Seep Limestones

NASA Astrophysics Data System (ADS)

Peckmann, J.

2007-12-01

To date, five Paleozoic hydrocarbon-seep limestones have been recognized based on carbonate fabrics, associated fauna, and stable carbon isotopes. These are the Middle Devonian Hollard Mound from the Antiatlas of Morocco [1], Late Devonian limestone lenses with the dimerelloid brachiopod Dzieduszyckia from the Western Meseta of Morocco [2], Middle Mississippian limestones with the dimerelloid brachiopod Ibergirhynchia from the Harz Mountains of Germany [3], Early Pennsylvanian limestones from the Tantes Mound in the High Pyrenees of France [4], and Late Pennsylvanian limestone lenses from the Ganigobis Shale Member of southern Namibia [5]. Among these examples, the composition of seepage fluids varied substantially as inferred from delta C-13 values of early diagenetic carbonate phases. Delta C-13 values as low as -50 per mil from the Tantes Mound and -51 per mil from the Ganigobis limestones reveal seepage of biogenic methane, whereas values of -12 per mil from limestones with Dzieduszyckia associated with abundant pyrobitumen agree with oil seepage. Intermediate delta C-13 values of carbonate cements from the Hollard Mound and Ibergirhynchia deposits probably reflect seepage of thermogenic methane. It is presently very difficult to assess the faunal evolution at seeps in the Paleozoic based on the limited number of examples. Two of the known seeps were typified by extremely abundant rhynchonellide brachiopods of the superfamily Dimerelloidea. Bivalve mollusks and tubeworms were abundant at two of the known Paleozoic seep sites; one was dominated by bivalve mollusks (Hollard Mound, Middle Devonian), another was dominated by tubeworms (Ganigobis Shale Member, Late Pennsylvanian). The tubeworms from these two deposits are interpreted to represent vestimentiferan worms, based on studies of the taphonomy of modern vestimentiferans. However, this interpretation is in conflict with the estimated evolutionary age of vestimentiferans based on molecular clock methods, which suggest a maximal age of 126 million years for this group. 1. Peckmann et al. (1999) Facies 40, 281. 2. Peckmann et al. (2007) Palaios 22, 114. 3. Peckmann et al. (2001) Geology 29, 271. 4. Buggisch and Krumm (2005) Facies 51, 566. 5. Himmler et al. (submitted) Palaeogeogr., Palaeoclimatol., Palaeoecol.

Petroleum geology and resources of the Dnieper-Donets Basin, Ukraine and Russia

USGS Publications Warehouse

Ulmishek, Gregory F.

2001-01-01

The Dnieper-Donets basin is almost entirely in Ukraine, and it is the principal producer of hydrocarbons in that country. A small southeastern part of the basin is in Russia. The basin is bounded by the Voronezh high of the Russian craton to the northeast and by the Ukrainian shield to the southwest. The basin is principally a Late Devonian rift that is overlain by a Carboniferous to Early Permian postrift sag. The Devonian rift structure extends northwestward into the Pripyat basin of Belarus; the two basins are separated by the Bragin-Loev uplift, which is a Devonian volcanic center. Southeastward, the Dnieper-Donets basin has a gradational boundary with the Donbas foldbelt, which is a structurally inverted and deformed part of the basin. The sedimentary succession of the basin consists of four tectono-stratigraphic sequences. The prerift platform sequence includes Middle Devonian to lower Frasnian, mainly clastic, rocks that were deposited in an extensive intracratonic basin. 1 The Upper Devonian synrift sequence probably is as thick as 4?5 kilometers. It is composed of marine carbonate, clastic, and volcanic rocks and two salt formations, of Frasnian and Famennian age, that are deformed into salt domes and plugs. The postrift sag sequence consists of Carboniferous and Lower Permian clastic marine and alluvial deltaic rocks that are as thick as 11 kilometers in the southeastern part of the basin. The Lower Permian interval includes a salt formation that is an important regional seal for oil and gas fields. The basin was affected by strong compression in Artinskian (Early Permian) time, when southeastern basin areas were uplifted and deeply eroded and the Donbas foldbelt was formed. The postrift platform sequence includes Triassic through Tertiary rocks that were deposited in a shallow platform depression that extended far beyond the Dnieper-Donets basin boundaries. A single total petroleum system encompassing the entire sedimentary succession is identified in the Dnieper-Donets basin. Discovered reserves of the system are 1.6 billion barrels of oil and 59 trillion cubic feet of gas. More than one-half of the reserves are in Lower Permian rocks below the salt seal. Most of remaining reserves are in upper Visean-Serpukhovian (Lower Carboniferous) strata. The majority of discovered fields are in salt-cored anticlines or in drapes over Devonian horst blocks; little exploration has been conducted for stratigraphic traps. Synrift Upper Devonian carbonate reservoirs are almost unexplored. Two identified source-rock intervals are the black anoxic shales and carbonates in the lower Visean and Devonian sections. However, additional source rocks possibly are present in the deep central area of the basin. The role of Carboniferous coals as a source rock for gas is uncertain; no coal-related gas has been identified by the limited geochemical studies. The source rocks are in the gas-generation window over most of the basin area; consequently gas dominates over oil in the reserves. Three assessment units were identified in the Dnieper-Donets Paleozoic total petroleum system. The assessment unit that contains all discovered reserves embraces postrift Carboniferous and younger rocks. This unit also contains the largest portion of undiscovered resources, especially gas. Stratigraphic and combination structural and stratigraphic traps probably will be the prime targets for future exploration. The second assessment unit includes poorly known synrift Devonian rocks. Carbonate reef reservoirs along the basin margins probably will contain most of the undiscovered resources. The third assessment unit is an unconventional, continuous, basin-centered gas accumulation in Carboniferous low-permeability clastic rocks. The entire extent of this accumulation is unknown, but it occupies much of the basin area. Resources of this assessment unit were not estimated quantitatively.

Gold Veins near Great Falls, Maryland

USGS Publications Warehouse

Reed, John Calvin; Reed, John C.

1969-01-01

Small deposits of native gold are present along an anastomosing system of quartz veins and shear zones just east of Great Falls, Montgomery County, Md. The deposits were discovered in 1861 and were worked sporadically until 1951, yielding more than 5,000 ounces of gold. The vein system and the principal veins within it strike a few degrees west of north, at an appreciable angle to foliation and fold axial planes in enclosing rocks of the Wissahickon Formation of late Precambrian (?) age. The veins cut granitic rocks of Devonian or pre-Devonian age and may be as young as Triassic. Further development of the deposits is unlikely under present economic conditions because of their generally low gold content and because much of the vein system lies on park property, but study of the Great Falls vein system may be useful in the search for similar deposits elsewhere in the Appalachian Piedmont.

The largest Silurian vertebrate and its palaeoecological implications

PubMed Central

Choo, Brian; Zhu, Min; Zhao, Wenjin; Jia, Liaotao; Zhu, You'an

2014-01-01

An apparent absence of Silurian fishes more than half-a-metre in length has been viewed as evidence that gnathostomes were restricted in size and diversity prior to the Devonian. Here we describe the largest pre-Devonian vertebrate (Megamastax amblyodus gen. et sp. nov.), a predatory marine osteichthyan from the Silurian Kuanti Formation (late Ludlow, ~423 million years ago) of Yunnan, China, with an estimated length of about 1 meter. The unusual dentition of the new form suggests a durophagous diet which, combined with its large size, indicates a considerable degree of trophic specialisation among early osteichthyans. The lack of large Silurian vertebrates has recently been used as constraint in palaeoatmospheric modelling, with purported lower oxygen levels imposing a physiological size limit. Regardless of the exact causal relationship between oxygen availability and evolutionary success, this finding refutes the assumption that pre-Emsian vertebrates were restricted to small body sizes. PMID:24921626

DOE Office of Scientific and Technical Information (OSTI.GOV)

McCollum, L.B.; Buchanan, J.P.; McCollum, M.B.

The Antler orogeny is a textbook example of a Paleozoic mountain building and crustal shortening event in western North America. A relatively complex geologic history of the type Antler at Battle Mountain, Nevada, is interpreted as distinct thrust plates of Lower Cambrian Scott Canyon Formation, Upper Cambrian Harmony Sandstone, and Ordovician Valmy Formation, overlain unconformably by the Middle Pennsylvanian Battle Formation. Mississippian crustal deformation and emplacement of the Roberts Mountain thrust have previously been thought to characterize the Antler orogen. Detailed sedimentology studies of the Scott Canyon and Harmony, and the relationship with the overlying Battle Formation at the typemore » section of the Antler orogeny, cast doubt on the previously accepted geologic history. The Scott Canyon is an interbedded sequence of pillow basalts, Late Devonian radiolarian cherts, and mudstone debris flows with numerous limestone olistoliths, many containing undescribed archaeocyathid fauna. The contact of the Harmony with the Battle Formation appears channeled, but otherwise conformable, and the Battle has been interpreted as an alluvial fan facies. The paleoenvironmental interpretation of these sediments is that the Scott Canyon was deposited upon a Late Devonian active continental margin setting, with prograding fan deposits of the Harmony Sandstone, overlain by Middle Pennsylvanian fanglomerates of the Battle Formation. This conformable sequence appears to preclude any major uplift within the type Antler orogen.« less

Lithologies of the basement complex (Devonian and older) in the National Petroleum Reserve - Alaska

USGS Publications Warehouse

Dumoulin, Julie A.; Houseknecht, David W.

2001-01-01

Rocks of the basement complex (Devonian and older) were encountered in at least 30 exploratory wells in the northern part of the NPRA. Fine-grained, variably deformed sedimentary rocks deposited in a slope or basinal setting predominate and include varicolored (mainly red and green) argillite in the Simpson area, dark argillite and chert near Barrow, and widespread gray argillite. Chitinozoans of Middle-Late Ordovician and Silurian age occur in the dark argillite and chert unit. Sponge spicules and radiolarians establish a Phanerozoic age for the varicolored and gray argillite units, both of which contain local interbeds of chert-rich sandstone and silt-stone. Conglomerate and sandstone, also chert-rich but interbedded with mudstone and coal and of Early-Middle Devonian age, occur in the Topagoruk area; these strata formed in a fluvial environment. At East Teshekpuk, granite of probable Devonian age was penetrated. Brecciated, quartz-veined rock of uncertain protolith that may be part of the basement complex was encountered in the Ikpikpuk well. Seismic data indicate that angular unconformities truncate all sedimentary units of the basement complex in NPRA. Rocks correlative in age and lithofacies with the dark argillite and chert unit occur in the subsurface near Prudhoe Bay. Other argillite units in NPRA have similarities to basement rocks in the subsurface adjacent to ANWR and the Ordovician-Silurian Iviagik Group at Cape Lisburne, but lack the interbedded limestones found in the ANWR strata, and are less metamorphosed than, and compositionally distinct from, the Iviagik. The Topagoruk conglomerate and the East Teshekpuk granite resemble the Ulungarat formation and the Okpilak batholith, respectively, in the northeastern Brooks Range.

Widespread effects of middle Mississippian deformation in the Great Basin of western North America

USGS Publications Warehouse

Trexler, J.H.; Cashman, P.H.; Cole, J.C.; Snyder, W.S.; Tosdal, R.M.; Davydov, V.I.

2003-01-01

Stratigraphic analyses in central and eastern Nevada reveal the importance of a deformation event in middle Mississippian time that caused widespread deformation, uplift, and erosion. It occurred between middle Osagean and late Meramecian time and resulted in deposition of both synorogenic and postorogenic sediments. The deformation resulted in east-west shortening, expressed as east-vergent folding and east-directed thrusting; it involved sedimentary rocks of the Antler foredeep as well as strata associated with the Roberts Mountains allochthon. A latest Meramecian to early Chesterian unconformity, with correlative conformable lithofacies changes, postdates this deformation and occurs throughout Nevada. A tectonic highland-created in the middle Mississippian and lasting into the Pennsylvanian and centered in the area west and southwest of Carlin, Nevada- shed sediments eastward across the Antler foreland, burying the unconformity. Postorogenic strata are late Meramecian to early Chesterian at the base and are widespread throughout the Great Basin. The tectonism therefore occurred 20 to 30 m.y. after inception of the Late Devonian Antler orogeny, significantly extending the time span of this orogeny or representing a generally unrecognized orogenic event in the Paleozoic evolution of western North America. We propose a revised stratigraphic nomenclature for Mississippian strata in Nevada, based on detailed age control and the recognition of unconformities. This approach resolves the ambiguity of some stratigraphic names and emphasizes genetic relationships within the upper Paleozoic section. We take advantage of better stratigraphic understanding to propose two new stratigraphic units for southern and eastern Nevada: the middle Mississippian Gap Wash and Late Mississippian Captain Jack Formations.

Paleozoic intrusive rocks from the Dunhuang tectonic belt, NW China: Constraints on the tectonic evolution of the southernmost Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Zhao, Yan; Sun, Yong; Diwu, Chunrong; Zhu, Tao; Ao, Wenhao; Zhang, Hong; Yan, Jianghao

2017-05-01

The Dunhuang tectonic belt (DTB) is of great importance for understanding the tectonic evolution of the southernmost Central Asian Orogenic Belt (CAOB). In this study, the temporal-spatial distribution, petrogenesis and tectonic setting of the Paleozoic representative intrusive rocks from the DTB were systematically investigated to discuss crustal evolution history and tectonic regime of the DTB during Paleozoic. Our results reveal that the Paleozoic magmatism within the DTB can be broadly divided into two distinct episodes of early Paleozoic and late Paleozoic. The early Paleozoic intrusive rocks, represented by a suite metaluminous-slight peraluminous and medium- to high-K calc-alkaline I-type granitoids crystallized at Silurian (ca. 430-410 Ma), are predominantly distributed along the northern part of the DTB. They were probably produced with mineral assemblage of eclogite or garnet + amphibole + rutile in the residue, and were derived from magma mixing source of depleted mantle materials with various proportions of Archean-Mesoproterozoic continental crust. The late Paleozoic intrusive rocks can be further subdivided into two stages of late Devonian stage (ca. 370-360 Ma) and middle Carboniferous stage (ca. 335-315 Ma). The former stage is predominated by metaluminous to slight peraluminous and low-K tholeiite to high-K calc-alkaline I-type granitic rocks distributed in the central part of the DTB. They were also generated with mineral assemblage of amphibolite- to eclogite-facies in the residue, and originated from magma source of depleted mantle materials mixed with different degrees of old continental crust. The later stage is represented by adakite and alkali-rich granite exposed in the southern part of the DTB. The alkali-rich granites studied in this paper were possibly produced with mineral assemblage of granulite-facies in the residue and were generated by partial melting of thickened lower continental crust. Zircon Hf isotopes and field distribution of those Paleozoic intrusive rocks reveal that both the Silurian and the late Devonian magmatic activities predominantly represent crustal growth processes in the DTB, accompanied by different degrees of reworking of pre-existing continental crust. However, the middle Carboniferous (ca. 335-315 Ma) magmatic activity reflects a crustal reworking process. The Silurian and late Devonian intrusive rocks were most likely formed in the arc-related subduction zones, whereas, the middle Carboniferous intrusive rocks were possibly formed in a transitional tectonic setting from compression to extension, representing the final stage of Paleozoic orogeny in the DTB. These Paleozoic magmatic rocks further suggest that the DTB has reactivated from a stable block to an orogen and undergone two episodes (the early Paleozoic and the late Paleozoic) of orogeny during Paleozoic. It represents a Paleozoic accretionary orogen of the southernmost margin of the CAOB between the Tarim Craton and North China Craton, and tectonically extends northward to the Beishan orogen and westward to the eastern South Tianshan Belt.

Unusual central Nevada geologic terranes produced by Late Devonian Antler orogeny and Alamo impact

USGS Publications Warehouse

Poole, Forrest G.; Sandberg, Charles

2015-01-01

Detailed geologic maps at scales of 1:8,000 and 1:10,000 document the conclusions, interpretations, and hypotheses presented in Chapters 1 and 2, respectively. Identification and dating of Paleozoic rock units are accomplished by means of nearly a hundred acid-dissolved carbonate conodont samples and at least 50 collections of conodonts on siltstone bedding planes that were identified either in the field or later in the office.

Similarities between several major extinctions and preservation of life - biomolecules to geomolecules: an interdisciplinary approach

NASA Astrophysics Data System (ADS)

Grice, Kliti; Melendez, Ines; Tulipani, Svenja

2015-04-01

WA Organic and Isotope Geochemistry Centre, The Institute for Geoscience Research, Department of Chemistry, Curtin University, GPO Box U1987 Perth, WA 6845, Australia Photic zone euxinia in ancient seas has proven signficant for elucidating biogeochemical changes that occurred during three of the five Phanerozoic mass extinctions, viz. the Permian/Triassic [1], Triassic/Jurassic [2] and Late Givetian (Devonian) [3] events, including the conditions associated with exceptional fossil preservation [4,5]. The series of events preceding, during and post the Triassic/Jurassic event, is remarkably similar to that reported for the Permian/Triassic extinction, the largest of the Phanerozoic Era. For the Late Givetian event, the first forests evolved and reef-building communities and associated fauna in tropical, marine settings were largely affected [6]. Sedimentary rocks on the margins of the Devonian reef slope in the Canning Basin, WA, contain novel biomarker, isotopic and palynological evidence for the existence of a persistently stratified water-column (comprising a freshwater lens overlying a more saline hypolimnion), with prevailing anoxia and PZE [7]. Also from the Canning Basin, the exceptional preservation of a suite of biomarkers in a Devonian invertebrate fossil within a carbonate concretion supports rapid encasement of the crustacean (identified by % of C27 steroids) enhanced by sulfate reducing bacteria under PZE conditions. PZE plays a critical role in fossil (including soft tissue) and biomarker preservation. In the same sample, the oldest occurrence of intact sterols shows that they have been preserved for ca. 380 Ma [5]. The exceptional preservation of this biomass is attributed to microbially induced carbonate encapsulation, preventing full decomposition and transformation, thus extending the record of sterol occurrences in the geosphere by 250 Ma. A suite of ca. 50 diagenetic transformation products of sterols is also reported, showing the unique coexistence of biomolecules and geomolecules in the same sample, previously assumed unfeasible. The coexistence of steroids in a diagenetic continuum, ranging from stenols to triaromatic steroids, is attributed to microbially mediated eogenetic processes. Under exceptional conditions concretions preserve biomolecules at extraordinary levels, providing a new opportunity to study the distributions of biomolecules in deep time and thereby improving our understanding of the evolution of life where fossils are rarely preserved. References [1] Grice K., Cao C., Love G.D., Bottcher M.E., Twitchett R,, Grosjean E., Summons R.E., Turgeon S., Dunning W.J. & Jin Y., 2005. Photic zone euxinia during the Permian-Triassic superanoxic event. Science. 307, 706-709. [2] Jaraula C.M.B, Grice K., Twitchett R.,J., Böttcher M.E., Le Metayer P., Dastidar A.G. & Opazo L.F., 2013. Elevated pCO2 leading to Late triassic extinction, persistent photic zone euxinia, and rising sea levels. Geology 41, 955-958. [3] Tulipani S., Grice K., Greenwood P.F, Haines P., Sauer P., Schimmelmann A., Summons R.E., Foster C.B., Böttcher M.E., Playton, T. & Schwark L., 2014a. Changes in palaeoenvironmental conditions in Late Devonian Reef systems from the Canning Basin, WA: A biomarker and stable isotope approach. Gondwana Research, in press. [4] Melendez I., Grice K., Trinajstic K., Ladjavardi M., Thompson K. & Greenwood P.F., 2013a. Biomarkers reveal the role of photic zone euxinia in exceptional fossil preservation: An organic geochemical perspective. Geology 41, 123-126. [5] Melendez I., Grice K. & Schwark L., 2013b. Exceptional preservation of palaeozoic steroids in a diagenetic continuum. Nature Scientific Reports. 3. [6] Grice K., Lu H., Atahan P., Hallmann, C., Asif M., Greenwood P.F., Tulipani S., Maslen E., Williford W.H. & Dodson J. 2009. New insights into the origin of perlyene in geological samples Geochimica et Cosmochimica Acta, 73, 6531-6543. [7] Tulipani S., Grice K., Greenwood P.F., Schwark L., Summons R.E., Böttcher M.E. & Foster C.B., 2014b. Molecular proxies as indicators of freshwater incursion-driven salinity stratification. Geochemistry, Geophysics, Geosystems, accepted.

Cambrian to Devonian evolution of alluvial systems: The sedimentological impact of the earliest land plants

NASA Astrophysics Data System (ADS)

Davies, Neil S.; Gibling, Martin R.

2010-02-01

In present-day alluvial environments, the impact of vegetation on sedimentological processes and deposits is well known. A vegetated catchment may decrease sediment yield, sediment erodibility, Hortonian overland flow, aeolian winnowing of fines, the proportion of sediment transported as bedload, and may increase bank stability, infiltration into substrates, and bed roughness. Vegetation also promotes the production of chemically-weathered clays and soils and the adoption of a meandering style. It is generally understood that, prior to the evolution of terrestrial vegetation during the Early Palaeozoic, ancient alluvial systems were markedly different from modern systems, with many systems adopting a "sheet-braided" style. This understanding has previously informed the interpretations of many Precambrian pre-vegetation alluvial successions, but there has been relatively little work regarding Early Palaeozoic alluvial successions laid down prior to and during the initial colonization of the Earth's surface by plants. A comprehensive review of 144 Cambrian to Devonian alluvial successions documented in published literature was combined with original field data from 34 alluvial successions across Europe and North America. The study was designed to identify changes in alluvial style during the period that vegetation was evolving and first colonizing alluvial environments. An increase in mudrock proportion and sandstone maturity is apparent, along with a decrease in overall sand grain size through the Early Palaeozoic. These trends suggest that primitive vegetation cover promoted the production and preservation of muds from the mid Ordovician onwards and increased the residence time of sand-grade sediment in alluvial systems. The compilation also enables the first stratigraphic occurrence of certain vegetation-dependent sedimentary features to be pinpointed and related to the evolution of specific palaeobotanical adaptations. The first markedly heterolithic alluvial sequences appeared at about the same time as the most primitive terrestrial vegetation in the Ordovician, and prolific pedogenic calcite, charcoal and bioturbated floodplain fines first appeared in the rock record at about the same time as vascular-plant macrofossils became abundant in the late Silurian. Lateral accretion sets in channel deposits appeared near the Silurian-Devonian boundary, at or shortly before the appearance of underground rooting systems, and become progressively more abundant in the record during the Devonian, implying a major expansion of meandering rivers as rooted plants stabilized river banks. Coals become abundant after the development of plant arborescence. The analysis suggests that the evolution of embryophytes had a profound effect on fluvial processes and deposits, and this period of landscape evolution must be considered amongst the most significant environmental and geomorphological changes in Earth history, with profound consequences for all aspects of the Earth system.

Detrital zircon age distribution from Devonian and Carboniferous sandstone in the Southern Variscan Fold-and-Thrust belt (Montagne Noire, French Massif Central), and their bearings on the Variscan belt evolution

NASA Astrophysics Data System (ADS)

Lin, Wei; Faure, Michel; Li, Xian-hua; Chu, Yang; Ji, Wenbin; Xue, Zhenhua

2016-05-01

In the Southern French Massif Central, the Late Paleozoic sedimentary sequences of the Montagne Noire area provide clues to decipher the successive tectonic events that occurred during the evolution of the Variscan belt. Previous sedimentological studies already demonstrated that the siliciclastic deposits were supplied from the northern part of the Massif Central. In this study, detrital zircon provenance analysis has been investigated in Early Devonian (Lochkovian) conglomerate and sandstone, and in Carboniferous (Visean to Early Serpukhovian) sandstone from the recumbent folds and the foreland basin of the Variscan Southern Massif Central in Montagne Noire. The zircon grains from all of the samples yielded U-Pb age spectra ranging from Neoarchean to Late Paleozoic with several age population peaks at 2700 Ma, 2000 Ma, 980 Ma, 750 Ma, 620 Ma, 590 Ma, 560 Ma, 480 Ma, 450 Ma, and 350 Ma. The dominant age populations concentrate on the Neoproterozoic and Paleozoic. The dominant concordant detrital zircon age populations in the Lochkovian samples, the 480-445 Ma with a statistical peak around 450 Ma, are interpreted as reflecting the rifting event that separated several continental stripes, such as Armorica, Mid-German Crystalline Rise, and Avalonia from the northern part of Gondwana. However, Ediacaran and Cambrian secondary peaks are also observed. The detrital zircons with ages at 352 - 340 Ma, with a statistical peak around 350 Ma, came from the Early Carboniferous volcanic and plutonic rocks similar to those exposed in the NE part of the French Massif Central. Moreover, some Precambrian grains recorded a more complex itinerary and may have experienced a multi-recycling history: the Archean and Proterozoic grains have been firstly deposited in Cambrian or Ordovician terrigenous rocks, and secondly re-sedimented in Devonian and/or Carboniferous formations. Another possibility is that ancient grains would be inherited grains, scavenged from an underlying but not exposed Precambrian basement.

Devonian magmatism in the Timan Range, Arctic Russia - subduction, post-orogenic extension, or rifting?

NASA Astrophysics Data System (ADS)

Pease, V.; Scarrow, J. H.; Silva, I. G. Nobre; Cambeses, A.

2016-11-01

Devonian mafic magmatism of the northern East European Craton (EEC) has been variously linked to Uralian subduction, post-orogenic extension associated with Caledonian collision, and rifting. New elemental and isotopic analyses of Devonian basalts from the Timan Range and Kanin Peninsula, Russia, in the northern EEC constrain magma genesis, mantle source(s) and the tectonic process(es) associated with this Devonian volcanism to a rift-related context. Two compositional groups of low-K2O tholeiitic basalts are recognized. On the basis of Th concentrations, LREE concentrations, and (LREE/HREE)N, the data suggest two distinct magma batches. Incompatible trace elements ratios (e.g., Th/Yb, Nb/Th, Nb/La) together with Nd and Pb isotopes indicate involvement of an NMORB to EMORB 'transitional' mantle component mixed with variable amounts of a continental component. The magmas were derived from a source that developed high (U,Th)/Pb, U/Th and Sm/Nd over time. The geochemistry of Timan-Kanin basalts supports the hypothesis that the genesis of Devonian basaltic magmatism in the region resulted from local melting of transitional mantle and lower crust during rifting of a mainly non-volcanic continental rifted margin.

Repeated kimberlite magmatism beneath Yakutia and its relationship to Siberian flood volcanism: Insights from in situ U-Pb and Sr-Nd perovskite isotope analysis

NASA Astrophysics Data System (ADS)

Sun, Jing; Liu, Chuan-Zhou; Tappe, Sebastian; Kostrovitsky, Sergey I.; Wu, Fu-Yuan; Yakovlev, Dmitry; Yang, Yue-Heng; Yang, Jin-Hui

2014-10-01

We report combined U-Pb ages and Sr-Nd isotope compositions of perovskites from 50 kimberlite occurrences, sampled from 9 fields across the Yakutian kimberlite province on the Siberian craton. The new U-Pb ages, together with previously reported geochronological constraints, suggest that kimberlite magmas formed repeatedly during at least 4 episodes: Late Silurian-Early Devonian (419-410 Ma), Late Devonian-Early Carboniferous (376-347 Ma), Late Triassic (231-215 Ma), and Middle/Late Jurassic (171-156 Ma). Recurrent kimberlite melt production beneath the Siberian craton - before and after flood basalt volcanism at 250 Ma - provides a unique opportunity to test existing models for the origin of global kimberlite magmatism. The internally consistent Sr and Nd isotope dataset for perovskites reveals that the Paleozoic and Mesozoic kimberlites of Yakutia have distinctly different initial radiogenic isotope compositions. There exists a notable increase in the initial 143Nd/144Nd ratios through time, with an apparent isotopic evolution that is intermediate between that of Bulk Earth and Depleted MORB Mantle. While the Paleozoic samples range between initial 87Sr/86Sr of 0.7028-0.7034 and 143Nd/144Nd of 0.51229-0.51241, the Mesozoic samples show values between 0.7032-0.7038 and 0.51245-0.51271, respectively. Importantly, perovskites from all studied Yakutian kimberlite fields and age groups have moderately depleted initial εNd values that fall within a relatively narrow range between +1.8 and +5.5. The perovskite isotope systematics of the Yakutian kimberlites are interpreted to reflect magma derivation from the convecting upper mantle, which appears to have a record of continuous melt depletion and crustal recycling throughout the Phanerozoic. The analyzed perovskites neither record highly depleted nor highly enriched isotopic components, which had been previously identified in likely plume-related Siberian Trap basalts. The Siberian craton has frequently been suggested to represent a type example of an association between kimberlite eruptions and flood basaltic volcanism within a single large igneous province (LIP), but our new extensive age and isotopic tracer constraints do not support a genetic link between these contrasting types of mantle-derived magmatism.

The Calvin impact crater and its associated oil production, Cass County, Michigan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Milstein, R.L.

1996-01-01

The Calvin impact crater is an isolated, nearly circular subsurface structure of Late Ordovician age in southwestern Michigan. The crater is defined by 110 oil and gas test wells, has a diameter of 6.2 km, and consists of a central dome exhibiting 415 m of structural uplift, an annular depression, and an encircling anticlinal rim. Exploration and development of three Devonian oil fields associated wit this structure provide all available subsurface data. All oil production is from the Middle Devonian Traverse Limestone, with the exception of one well producing from the Middle Devonian Sylvania Sandstone. This study models the grossmore » morphology of the Calvin structure using multiple tools and compares the results to known impact craters. Combined results of reflection seismic, gravity, magnetic, and resistivity data, as well as organized relationships between stratigraphic displacement and structural diameters observed in complex impact craters, suggest the Calvin structure is morphologically similar to recognized complex impact craters in sedimentary targets. In addition, individual quartz grains recovered from the Calvin structure exhibit decorated shock lamellae, Boehm lamellae, rhombohederal cleavage, and radiating concussion fractures. Based on the available data, I conclude the Calvin structure is a buried complex impact crater and that the trapping and reservoir characteristics of the associated Calvin 20, Juno Lake, and Calvin 28 oil fields are resultant of the craters morphology.« less

The Calvin impact crater and its associated oil production, Cass County, Michigan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Milstein, R.L.

1996-12-31

The Calvin impact crater is an isolated, nearly circular subsurface structure of Late Ordovician age in southwestern Michigan. The crater is defined by 110 oil and gas test wells, has a diameter of 6.2 km, and consists of a central dome exhibiting 415 m of structural uplift, an annular depression, and an encircling anticlinal rim. Exploration and development of three Devonian oil fields associated wit this structure provide all available subsurface data. All oil production is from the Middle Devonian Traverse Limestone, with the exception of one well producing from the Middle Devonian Sylvania Sandstone. This study models the grossmore » morphology of the Calvin structure using multiple tools and compares the results to known impact craters. Combined results of reflection seismic, gravity, magnetic, and resistivity data, as well as organized relationships between stratigraphic displacement and structural diameters observed in complex impact craters, suggest the Calvin structure is morphologically similar to recognized complex impact craters in sedimentary targets. In addition, individual quartz grains recovered from the Calvin structure exhibit decorated shock lamellae, Boehm lamellae, rhombohederal cleavage, and radiating concussion fractures. Based on the available data, I conclude the Calvin structure is a buried complex impact crater and that the trapping and reservoir characteristics of the associated Calvin 20, Juno Lake, and Calvin 28 oil fields are resultant of the craters morphology.« less

Syngenetic Au on the Carlin trend: Implications for Carlin-type deposits

USGS Publications Warehouse

Emsbo, P.; Hutchinson, R.W.; Hofstra, A.H.; Volk, J.A.; Bettles, K.H.; Baschuk, G.J.; Johnson, C.A.

1999-01-01

A new type of gold occurrence recently discovered in the Carlin trend, north-central Nevada, is clearly distinct from classic Carlin-type gold ore. These occurrences are interpreted to be of sedimentary exhalative (sedex) origin because they are stratiform and predate compaction and lithification of their unaltered Devonian host rocks. They contain barite that exhibits ??34S and ??18O values identical to sulfate in Late Devonian seawater and sedex-type barite deposits. Abrupt facies changes in the host rocks strongly suggest synsedimentary faulting and foundering of the carbonate shelf during mineralization, as is characteristic of sedex deposits. Gold occurs both as native inclusions in synsedimentary base-metal sulfides and barite, and as chemical enrichments in sulfide minerals. The absence of alteration and lack of ??13C and ??18O isotopic shift of primary carbonates in these rocks is strong evidence that this gold was not introduced with classic Carlin-type mineralization. Collectively, these features show that the Devonian strata were significantly enriched in gold some 300 m.y. prior to generation of the mid-Tertiary Carlin-type deposits. These strata may have been an important, perhaps even vital, source of gold for the latter. Although gold is typically low in most Zn-Pb-rich sedex deposits, our evidence suggests that transport of gold in basinal fluids, and its subsequent deposition in the sedex environment, can be significant.

Two hundred years of palaeontological discovery: Review of research on the Early to Middle Devonian Bokkeveld Group (Cape Supergroup) of South Africa

NASA Astrophysics Data System (ADS)

Penn-Clarke, C. R.; Rubidge, B. S.; Jinnah, Z. A.

2018-01-01

Documentation of the palaeontological heritage of the Early to Middle Devonian Bokkeveld Group of South Africa has been recorded as far back as the early nineteenth century with the arrival of the first European settlers, merchants and explorers to the Cape region. Anecdotal evidence suggests that indigenous peoples had knowledge of fossils in the Bokkeveld Group from as early as the Middle-to-Late Stone Age. Within the first hundred years of the expansion of the Cape Colony the first geological maps of the Bokkeveld Group were produced alongside the first description of fossils as well as their Devonian age and marine origin. These early investigations provided a foundation for establishing faunal endemism common to South Africa, South America and the Falkland Islands. During the early twentieth century considerable progress was made in the description of fossil fauna of the Bokkeveld Group, most notably of invertebrates and plants. This research demonstrated that invertebrate fossils from the Bokkeveld Group, as well as those from time equivalents in South America and the Falkland Islands, were distinct from the Devonian Period elsewhere (e.g. Europe and North America). The role of fossils from the Bokkeveld Group proved critical in the formal designation and delineation of a broad region of endemism, the Malvinokaffric Realm that persisted at high subpolar-to-polar palaeolatitudes in southwestern Gondwana and extended from South Africa, Bolivia, Brazil, Argentina, Antarctica and the Falkland Islands with possible elements in Guinea-Bissau, Senegal and Ghana during the Emsian-Eifelian Stages. In the latter half of the twentieth century developments in understanding the sedimentology and stratigraphy of the Bokkeveld Group lead to the premise that the succession accumulated in a storm-and-wave dominated deltaic palaeoenvironment, and enabled inferences on the palaeoecology of the fossil taxa. During this period detailed revisions of numerous invertebrate and plant taxa were undertaken as well as the first descriptions of fossil fish. Research in the twenty-first century has shown a general decline in palaeontological interest, but developments are currently underway in refining the taxonomy of fossil echinoderms and fish from the Bokkeveld Group as well as understanding the Group's palaeoenvironmental history, geochronology and understanding the decline of the Malvinokaffric Realm in South Africa and its causation.

Continental crust melting induced by subduction initiation of the South Tianshan Ocean: Insight from the Latest Devonian granitic magmatism in the southern Yili Block, NW China

NASA Astrophysics Data System (ADS)

Bao, Zihe; Cai, Keda; Sun, Min; Xiao, Wenjiao; Wan, Bo; Wang, Yannan; Wang, Xiangsong; Xia, Xiaoping

2018-03-01

The Tianshan belt of the southwestern Central Asian Orogenic Belt was generated by Paleozoic multi-stage subduction and final closure of several extinct oceans, including the South Tianshan Ocean between the Kazakhstan-Yili and Tarim blocks. However, the subduction initiation and polarity of the South Tianshan Ocean remain issues of highly debated. This study presents new zircon U-Pb ages, geochemical compositions and Sr-Nd isotopes, as well as zircon Hf isotopic data of the Latest Devonian to Early Carboniferous granitic rocks in the Wusun Mountain of the Yili Paleozoic convergent margin, which, together with the spatial-temporal distributions of regional magmatic rocks, are applied to elucidate their petrogenesis and tectonic linkage to the northward subduction initiation of the South Tianshan Ocean. Our zircon U-Pb dating results reveal that these granites were emplaced at the time interval of 362.0 ± 1.2-360.3 ± 1.9 Ma, suggesting a marked partial melting event of the continental crust in the Latest Devonian to Early Carboniferous. These granites, based on their mineral compositions and textures, can be categorized as monzogranites and K-feldspar granites. Geochemically, both monzogranites and K-feldspar granites have characters of I-type granites with high K2O contents (4.64-4.83 wt.%), and the K-feldspar granites are highly fractionated I-type granites, while the monzogranites have features of unfractionated I-type granites. Whole-rock Sr-Nd isotopic modeling results suggest that ca. 20-40% mantle-derived magmas may be involved in magma mixing with continental crust partial melts to generate the parental magmas of the granites. The mantle-derived basaltic magmas was inferred not only to be a major component of magma mixture but also as an important heat source to fuse the continental crust in an extensional setting, which is evidenced by the high zircon saturation temperatures (713-727 °C and 760-782 °C) of the studied granites. The Latest Devonian to Early Carboniferous extensional setting in the Wusun Mountain region of the Yili Paleozoic convergent margin is addressed by the subduction initiation of the South Tianshan Ocean and constituted a late Paleozoic nascent arc- back-arc system in the southwestern CAOB.

Sequence stratigraphy and a revised sea-level curve for the Middle Devonian of eastern North America

USGS Publications Warehouse

Brett, Carlton E.; Baird, G.C.; Bartholomew, A.J.; DeSantis, M.K.; Ver Straeten, C.A.

2011-01-01

The well-exposed Middle Devonian rocks of the Appalachian foreland basin (Onondaga Formation; Hamilton Group, Tully Formation, and the Genesee Group of New York State) preserve one of the most detailed records of high-order sea-level oscillation cycles for this time period in the world. Detailed examination of coeval units in distal areas of the Appalachian Basin, as well as portions of the Michigan and Illinois basins, has revealed that the pattern of high-order sea-level oscillations documented in the New York-Pennsylvania section can be positively identified in all areas of eastern North America where coeval units are preserved. The persistence of the pattern of high-order sea-level cycles across such a wide geographic area suggests that these cycles are allocyclic in nature with primary control on deposition being eustatic sea-level oscillation, as opposed to autocylic controls, such as sediment supply, which would be more local in their manifestation. There is strong evidence from studies of cyclicity and spectral analysis that these cycles are also related to Milankovitch orbital variations, with the short and long-term eccentricity cycles (100. kyr and 405. kyr) being the dominant oscillations in many settings. Relative sea-level oscillations of tens of meters are likely and raise considerable issues about the driving mechanism, given that the Middle Devonian appears to record a greenhouse phase of Phanerozoic history. These new correlations lend strong support to a revised high-resolution sea-level oscillation curve for the Middle Devonian for the eastern portion of North America. Recognized third-order sequences are: Eif-1 lower Onondaga Formation, Eif-2: upper Onondaga and Union Springs formations; Eif-Giv: Oatka Creek Formation; Giv-1: Skaneateles, Giv-2: Ludlowville, Giv-3: lower Moscow, Giv-4: upper Moscow-lower Tully, and Giv-5: middle Tully-Geneseo formations. Thus, in contrast with the widely cited eustatic curve of Johnson et al. (1985), which recognizes just one major transgressive-regressive (T-R) cycle in the early-mid Givetian (If) prior to the major late Givetian Taghanic unconformity (IIa, upper Tully-Geneseo Shale), we recognize four T-R cycles: If (restricted), Ig, Ih, and Ii. We surmise that third-order sequences record eustatic sea-level fluctuations of tens of meters with periodicities of 0.8-2. myr, while their medial-scale (fourth-order) subdivisions record lesser variations primarily of 405. kyr duration (long-term eccentricity). This high-resolution record of sea-level change provides strong evidence for high-order eustatic cycles with probable Milankovitch periodicities, despite the fact that no direct evidence for Middle Devonian glacial sediments has been found to date. ?? 2010.

Tectono-thermal Evolution of the Lower Paleozoic Petroleum Source Rocks in the Southern Lublin Trough: Implications for Shale Gas Exploration from Maturity Modelling

NASA Astrophysics Data System (ADS)

Botor, Dariusz

2018-03-01

The Lower Paleozoic basins of eastern Poland have recently been the focus of intensive exploration for shale gas. In the Lublin Basin potential unconventional play is related to Lower Silurian source rocks. In order to assess petroleum charge history of these shale gas reservoirs, 1-D maturity modeling has been performed. In the Łopiennik IG-1 well, which is the only well that penetrated Lower Paleozoic strata in the study area, the uniform vitrinite reflectance values within the Paleozoic section are interpreted as being mainly the result of higher heat flow in the Late Carboniferous to Early Permian times and 3500 m thick overburden eroded due to the Variscan inversion. Moreover, our model has been supported by zircon helium and apatite fission track dating. The Lower Paleozoic strata in the study area reached maximum temperature in the Late Carboniferous time. Accomplished tectono-thermal model allowed establishing that petroleum generation in the Lower Silurian source rocks developed mainly in the Devonian - Carboniferous period. Whereas, during Mesozoic burial, hydrocarbon generation processes did not develop again. This has negative influence on potential durability of shale gas reservoirs.

Textural and Rb-Sr isotopic evidence for late Paleozoic mylonitization within the Honey Hill fault zone southeastern Connecticut

DOE Office of Scientific and Technical Information (OSTI.GOV)

O'Hara, K.D.; Gromet, L.P.

A petrographic and Rb-Sr isotopic study of rocks within and near the Honey Hill fault zone places important constraints on its history of movement. Rb-Sr apparent ages for micas and plagioclase from these rocks have been reset and range from Permian to Triassic, considerably younger than the minimum stratigraphic age (Ordovician) of the rocks studied or of Acadian (Devonian) regional metamorphism. Permian Rb-Sr ages of dynamically recrystallized muscovite date the development of mylonite fabric. An older age is precluded by the excellent preservation of unrecovered quartz, which indicates that these rocks did not experience temperatures high enough to anneal quartzmore » or thermally reset Rb-Sr isotopic systems in muscovite since the time of mylonitization. Metamorphic mineral assemblages and mineral apparent ages in rocks north of the fault zone indicate recrystallization under similar upper greenschist-lower amphibolite grade conditions during Permian to Triassic time. Collectively these results indicate that the Honey Hill fault zone was active during the Late Paleozoic and that ductile deformation and metamorphism associated with the Alleghanian orogeny extend well into southern Connecticut. An Alleghanian age for mylonitization within the Honey Hill fault zone suggests it should be considered as a possible site for the major Late Paleozoic strike-slip displacements inferred from paleomagnetic studies for parts of coastal New England and maritime Canada.« less

Phanerozoic geological evolution of Northern and Central Africa: An overview

NASA Astrophysics Data System (ADS)

Guiraud, R.; Bosworth, W.; Thierry, J.; Delplanque, A.

2005-10-01

The principal paleogeographic characteristics of North and Central Africa during the Paleozoic were the permanency of large exposed lands over central Africa, surrounded by northerly and northwesterly dipping pediplanes episodically flooded by epicontinental seas related to the Paleotethys Ocean. The intra-continental Congo-Zaire Basin was also a long-lived feature, as well as the Somali Basin from Late Carboniferous times, in conjunction with the development of the Karoo basins of southern Africa. This configuration, in combination with eustatic sea-level fluctuations, had a strong influence on facies distributions. Significant transgressions occurred during the Early Cambrian, Tremadocian, Llandovery, Middle to Late Devonian, Early Carboniferous, and Moscovian. The Paleozoic tectonic history shows an alternation of long periods of predominantly gentle basin subsidence and short periods of gentle folding and occasionally basin inversion. Some local rift basins developed episodically, located mainly along the northern African-Arabian plate margin and near the West African Craton/Pan-African Belt suture. Several arches or spurs, mainly N-S to NE-SW trending and inherited from late Pan-African fault swarms, played an important role. The Nubia Province was the site of numerous alkaline anorogenic intrusions, starting in Ordovician times, and subsequently formed a large swell. Paleozoic compressional events occurred in the latest Early Cambrian ("Iskelian"), Medial Ordovician to earliest Silurian ("pre-Caradoc" and "Taconian"), the end Silurian ("Early Acadian" or "Ardennian"), mid-Devonian ("Mid-Acadian"), the end Devonian ("Late Acadian" or "Bretonnian"), the earliest Serpukhovian ("Sudetic"), and the latest Carboniferous-earliest Permian ("Alleghanian" or "Asturian"). The strongest deformations, including folding, thrusting, and active strike-slip faulting, were registered in Northwestern Africa during the last stage of the Pan-African Belt development around the West African Craton (end Early Cambrian) and during the polyphased Hercynian-Variscan Orogeny that extended the final closure of the Paleotethys Ocean and resulted in the formation of the Maghrebian and Mauritanides belts. Only gentle deformation affected central and northeastern African during the Paleozoic, the latter remaining a passive margin of the Paleotethys Ocean up to the Early Permian when the development of the Neotethys initiated along the Eastern Mediterranean Basins. The Mesozoic-Cenozoic sedimentary sequence similarly consists of a succession of eustatically and tectonically controlled depositional cycles. Through time, progressive southwards shift of the basin margins occurred, related to the opening of the Neotethys Ocean and to the transgressions resulting from warming of the global climate and associated rise of the global sea level. The Guinean-Nigerian Shield, the Hoggar, Tibesti-Central Cyrenaica, Nubia, western Saudi Arabia, Central African Republic, and other long-lived arches delimited the principal basins. The main tectonic events were the polyphased extension, inversion, and folding of the northern African-Arabian shelf margin resulting in the development of the Alpine Maghrebian and Syrian Arc belts, rifting and drifting along the Central Atlantic, Somali Basins, and Gulf of Aden-Red Sea domains, inversion of the Murzuq-Djado Basin, and rifting and partial inversion along the Central African Rift System. Two major compressional events occurred in the Late Santonian and early Late Eocene. The former entailed folding and strike-slip faulting along the northeastern African-northern Arabian margin (Syrian Arc) and the Central African Fold Belt System (from Benue to Ogaden), and thrusting in Oman. The latter ("Pyrenean-Atlasic") resulted in folding, thrusting, and local metamorphism of the northern African-Arabian plate margin, and rejuvenation of intra-plate fault zones. Minor or more localized compressional deformations took place in the end Cretaceous, the Burdigalian, the Tortonian and Early Quaternary. Recent tectonic activity is mainly concentrated along the Maghrebian Alpine Belt, the offshore Nile Delta, the Red Sea-East African Rifts Province, the Aqaba-Dead Sea-Bekaa sinistral strike-slip fault zone, and some major intra-plate fault zones including the Guinean-Nubian, Aswa, and central Sinai lineaments. Large, long-lived magmatic provinces developed in the Egypt-Sudan confines (Nubia), in the Hoggar-Air massifs, along the Cameroon Line and Nigerian Jos Plateau, and along the Levant margin, resulting in uplifts that influenced the paleogeography. Extensive tholeiitic basaltic magmatism at ˜200 Ma preceded continental break-up in the Central Atlantic domain, while extensive alkaline to transitional basaltic magmatism accompanied the Oligocene to Recent rifting along the Red Sea-Gulf of Aden-East African rift province.

New porcellioidean gastropods from early Devonian of Royal Creek area, Yukon Territory, Canada, with notes on their early phylogeny

USGS Publications Warehouse

Fryda, J.; Blodgett, R.B.; Lenz, A.C.; Manda, S.

2008-01-01

This paper presents a description of new gastropods belonging to the superfamily Porcellioidea (Vetigastropoda) from the richly diverse Lower Devonian gastropod fauna of the Road River Formation in the Royal Creek area, Yukon Territory. This fauna belongs to Western Canada Province of the Old World Realm. The Pragian species Porcellia (Porcellia) yukonensis n. sp. and Porcellia (Paraporcellia) sp. represent the oldest presently known members of subgenera Porcellia (Porcellia) and Porcellia (Paraporcellia). Their simple shell ornamentation fits well with an earlier described evolutionary trend in shell morphology of the Porcellinae. Late Pragian to early Emsian Perryconcha pulchra n. gen. and n. sp. is the first member of the Porcellioidea bearing a row of tremata on adult teleoconch whorls. The occurrence of this shell feature in the Porcellioidea is additional evidence that the evolution of the apertural slit was much more complicated than has been proposed in classical models of Paleozoic gastropod evolution. Copyright ?? 2008, The Paleontological Society.

The Oldest Actinopterygian Highlights the Cryptic Early History of the Hyperdiverse Ray-Finned Fishes.

PubMed

Lu, Jing; Giles, Sam; Friedman, Matt; den Blaauwen, Jan L; Zhu, Min

2016-06-20

Osteichthyans comprise two divisions, each containing over 32,000 living species [1]: Sarcopterygii (lobe-finned fishes and tetrapods) and Actinopterygii (ray-finned fishes). Recent discoveries from China highlight the morphological disparity of early sarcopterygians and extend their origin into the late Silurian [2-4]. By contrast, the oldest unambiguous actinopterygians are roughly 30 million years younger, leaving a long temporal gap populated by fragments and rare body fossils of controversial phylogenetic placement [5-10]. Here we reinvestigate the enigmatic osteichthyan Meemannia from the Early Devonian (∼415 million years ago) of China, previously identified as an exceptionally primitive lobe-finned fish [3, 7, 11, 12]. Meemannia combines "cosmine"-like tissues taken as evidence of sarcopterygian affinity with actinopterygian-like skull roof and braincase geometry, including endoskeletal enclosure of the spiracle and a lateral cranial canal. We report comparable histological structures in undoubted ray-finned fishes and conclude that they are general osteichthyan features. Phylogenetic analysis places Meemannia as an early-diverging ray-finned fish, resolving it as the sister lineage of Cheirolepis [13] plus all younger actinopterygians. This brings the first appearance of ray-fins more in line with that of lobe-fins and fills a conspicuous faunal gap in the otherwise diverse late Silurian-earliest Devonian vertebrate faunas of the South China Block [4]. Copyright © 2016 The Author(s). Published by Elsevier Ltd.. All rights reserved.

Devonian rocks and Lower and Middle Devonian pelecypods of Guangxi, China, and the Traverse Group of Michigan

USGS Publications Warehouse

Pojeta, John

1986-01-01

A state-of-the-art summary of the Devonian rocks of China, correlation of the Lower and Middle Devonian of the Guangxi Autonomous Region with the European Standards, and detailed lithologic descriptions of the major Lower and Middle Devonian sections in Guangxi from which pelecypods were collected. Systematic descriptions are given for the Lower and Middle Devonian pelecypods of Guangxi. The Chinese pelecypods are principally compared with the previously little studied Givetian pelecypods of Michigan, which are also described.

Gondwana dispersion and Asian accretion: Tectonic and palaeogeographic evolution of eastern Tethys

NASA Astrophysics Data System (ADS)

Metcalfe, I.

2013-04-01

Present-day Asia comprises a heterogeneous collage of continental blocks, derived from the Indian-west Australian margin of eastern Gondwana, and subduction related volcanic arcs assembled by the closure of multiple Tethyan and back-arc ocean basins now represented by suture zones containing ophiolites, accretionary complexes and remnants of ocean island arcs. The Phanerozoic evolution of the region is the result of more than 400 million years of continental dispersion from Gondwana and plate tectonic convergence, collision and accretion. This involved successive dispersion of continental blocks, the northwards translation of these, and their amalgamation and accretion to form present-day Asia. Separation and northwards migration of the various continental terranes/blocks from Gondwana occurred in three phases linked with the successive opening and closure of three intervening Tethyan oceans, the Palaeo-Tethys (Devonian-Triassic), Meso-Tethys (late Early Permian-Late Cretaceous) and Ceno-Tethys (Late Triassic-Late Cretaceous). The first group of continental blocks dispersed from Gondwana in the Devonian, opening the Palaeo-Tethys behind them, and included the North China, Tarim, South China and Indochina blocks (including West Sumatra and West Burma). Remnants of the main Palaeo-Tethys ocean are now preserved within the Longmu Co-Shuanghu, Changning-Menglian, Chiang Mai/Inthanon and Bentong-Raub Suture Zones. During northwards subduction of the Palaeo-Tethys, the Sukhothai Arc was constructed on the margin of South China-Indochina and separated from those terranes by a short-lived back-arc basin now represented by the Jinghong, Nan-Uttaradit and Sra Kaeo Sutures. Concurrently, a second continental sliver or collage of blocks (Cimmerian continent) rifted and separated from northern Gondwana and the Meso-Tethys opened in the late Early Permian between these separating blocks and Gondwana. The eastern Cimmerian continent, including the South Qiangtang block and Sibumasu Terrane (including the Baoshan and Tengchong blocks of Yunnan) collided with the Sukhothai Arc and South China/Indochina in the Triassic, closing the Palaeo-Tethys. A third collage of continental blocks, including the Lhasa block, South West Borneo and East Java-West Sulawesi (now identified as the missing "Banda" and "Argoland" blocks) separated from NW Australia in the Late Triassic-Late Jurassic by opening of the Ceno-Tethys and accreted to SE Sundaland by subduction of the Meso-Tethys in the Cretaceous.

Characteristics of the Late Devonian Tsagaan Suvarga Cu-Mo deposit, Southern Mongolia

NASA Astrophysics Data System (ADS)

Tungalag, Naidansuren; Jargalan, Sereenen; Khashgerel, Bat-Erdene; Mijiddorj, Chuluunbaatar; Kavalieris, Imants

2018-05-01

The Late Devonian Tsagaan Suvarga deposit (255 Mt at 0.55% Cu, 0.02% Mo) is located on the NW margin of the Tsagaan Suvarga Complex (TSC), which extends ENE over 15 × 10 km and comprises mainly medium-grained equigranular hornblende-biotite quartz monzonite and monzodiorite. Distinct mineralized intrusions are inferred from distribution of Cu-Mo mineralization but are not clearly discernible. The Tsagaan Suvarga Complex is a window within Carboniferous volcanic and sedimentary rocks, and wall rocks to the TSC are not known or exposed in the nearby district. Whole-rock analyses and Sr-Nd isotopes, 87Sr/86Sr0 = 0.7027 to 0.7038 (n = 12) and ɛNd0 = + 4.26 to + 2.77 (n = 12), show that the granitoids are subduction-related I-type, high K-calc-alkaline to shoshonitic series and derived from a mantle source. They exhibit fractionated light rare earth elements, without depleted Eu and depleted middle heavy rare earth elements and Y, typical of oxidized, fertile porphyry magmatic suites. Early porphyry-style quartz veins include A- and B-type. Molybdenite occurs in monomineralic veins (1-5 mm) or A veins. Copper mineralization occurs mainly as chalcopyrite and subordinate bornite, disseminated and associated with quartz-muscovite veins. Pyrite (vol%) content is less than chalcopyrite and bornite combined. Deep oxidation to about 50 m depth has formed zones of malachite and covellite in late fractures. The most important alteration is actinolite-biotite-chlorite-magnetite replacing hornblende and primary biotite. Quartz-K-feldspar alteration is minor. Late albite replaces primary K-feldspar and enhances sodic rims on plagioclase crystals. Quartz-muscovite (or sericitic alteration) overprints actinolite-biotite and porphyry-type quartz veins. Field observations and petrographic studies suggest that the bulk of the chalcopyrite-bornite mineralization at the Tsagaan Suvarga formed together with coarse muscovite alteration.

Reconstruction of an early Paleozoic continental margin based on the nature of protoliths in the Nome Complex, Seward Peninsula, Alaska

USGS Publications Warehouse

Till, Alison B.; Dumoulin, Julie A.; Ayuso, Robert A.; Aleinikoff, John N.; Amato, Jeffrey M.; Slack, John F.; Shanks, W.C. Pat

2014-01-01

The Nome Complex is a large metamorphic unit that sits along the southern boundary of the Arctic Alaska–Chukotka terrane, the largest of several micro continental fragments of uncertain origin located between the Siberian and Laurentian cratons. The Arctic Alaska–Chukotka terrane moved into its present position during the Mesozoic; its Mesozoic and older movements are central to reconstruction of Arctic tectonic history. Accurate representation of the Arctic Alaska–Chukotka terrane in reconstructions of Late Proterozoic and early Paleozoic paleogeography is hampered by the paucity of information available. Most of the Late Proterozoic to Paleozoic rocks in the Alaska–Chukotka terrane were penetratively deformed and recrystallized during the Mesozoic deformational events; primary features and relationships have been obliterated, and age control is sparse. We use a variety of geochemical, geochronologic, paleontologic, and geologic tools to read through penetrative deformation and reconstruct the protolith sequence of part of the Arctic Alaska–Chukotka terrane, the Nome Complex. We confirm that the protoliths of the Nome Complex were part of the same Late Proterozoic to Devonian continental margin as weakly deformed rocks in the southern and central part of the terrane, the Brooks Range. We show that the protoliths of the Nome Complex represent a carbonate platform (and related rocks) that underwent incipient rifting, probably during the Ordovician, and that the carbonate platform was overrun by an influx of siliciclastic detritus during the Devonian. During early phases of the transition to siliciclastic deposition, restricted basins formed that were the site of sedimentary exhalative base-metal sulfide deposition. Finally, we propose that most of the basement on which the largely Paleozoic sedimentary protolith was deposited was subducted during the Mesozoic.

Late Paleozoic closure of the Ob-Zaisan Ocean along the Irtysh/Chara shear zone and implications for arc amalgamation and oroclinal bending in the western Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Li, Pengfei; Sun, Min; Rosenbaum, Gideon

2016-04-01

The Irtysh/Chara Shear Zone is one of the largest strike-slip systems in the Central Asian Orogenic Belt (CAOB). It records collisional processes of the peri-Siberian orogenic system with the West Junggar-Kazakhstan-Tianshan orogenic system following the closure of the Ob-Zaisan Ocean, but the exact timing of these events remains enigmatic. We conducted detailed structural analysis along the Irtysh Shear Zone (NW China), which together with new geochronological data allows us to reconstruct the tectonic evolution during the final closure of the Ob-Zaisan Ocean. Our results showed that subduction-accretion processes lasted at least until the Late Carboniferous in the Chinese Altai and the East/West Junggar. The subsequent arc amalgamation is characterized by a cycle of crustal thickening, orogenic collapse and transpressional thickening. On a larger scale, the West Junggar- Kazakhstan -Tianshan orogenic system defines a U-shape oroclinal structure (e.g. Xiao et al., 2010). A major phase of oroclinal bending that involved ~110° rotation may have occurred during the Late Devonian to Early Carboniferous (Levashova et al., 2012). Previous authors have linked oroclinal bending with the late Paleozoic amalgamation of the western CAOB, and proposed that a quasi-linear West Junggar- Kazakhstan -Tianshan orogenic system was buckled during the convergence of the Siberian and Tarim cratons following the closure of the Ob-Zaisan Ocean (in the north) and the South Tianshan Ocean (in the south) (e.g. Abrajevitch et al., 2008). This model, however, is not supported by our new data that constrain the closure of the Ob-Zaisan Ocean to the Late Carboniferous. Alternatively, we propose that oroclinal bending may have involved two phases of bending, with the ~110° rotation in the Late Devonian to Early Carboniferous possibly associated with trench retreat. Further tightening may have occurred in response to the convergence of the Siberian and Tarim cratons during the Late Carboniferous to Permian. References: Abrajevitch, A., Van der Voo, R., Bazhenov, M.L., Levashova, N.M., McCausland, P.J.A., 2008. The role of the Kazakhstan orocline in the late Paleozoic amalgamation of Eurasia. Tectonophysics 455, 61-76. Levashova, N., Degtyarev, K., Bazhenov, M., 2012. Oroclinal bending of the Middle and Late Paleozoic volcanic belts in Kazakhstan: Paleomagnetic evidence and geological implications. Geotectonics 46, 285-302. Xiao, W., Huang, B., Han, C., Sun, S., Li, J., 2010. A review of the western part of the Altaids: A key to understanding the architecture of accretionary orogens. Gondwana Research 18, 253-273. Acknowledgements: This study was financially supported by the Major Basic Research Project of the Ministry of Science and Technology of China (Grant: 2014CB448000 and 2014CB440801), Hong Kong Research Grant Council (HKU705311P, HKU704712P and HKU17303415), National Science Foundation of China (41273048), HKU seed funding (201111159137) and HKU CRCG grants. This work is a contribution of the Joint Laboratory of Chemical Geodynamics between HKU and CAS (Guangzhou Institute of Geochemistry), IGCP 592 and PROCORE France/Hong Kong Joint Research Scheme.

Do fossil plants signal palaeoatmospheric carbon dioxide concentration in the geological past?

PubMed Central

McElwain, J. C.

1998-01-01

Fossil, subfossil, and herbarium leaves have been shown to provide a morphological signal of the atmospheric carbon dioxide environment in which they developed by means of their stomatal density and index. An inverse relationship between stomatal density/index and atmospheric carbon dioxide concentration has been documented for all the studies to date concerning fossil and subfossil material. Furthermore, this relationship has been demonstrated experimentally by growing plants under elevated and reducedcarbon dioxide concentrations. To date, the mechanism that controls the stomatal density response to atmospheric carbon dioxide concentration remains unknown. However, stomatal parameters of fossil plants have been successfully used as a proxy indicator of palaeo-carbon dioxide levels. This paper presents new estimates of palaeo-atmospheric carbon dioxide concentrations for the Middle Eocene (Lutetian), based on the stomatal ratios of fossil Lauraceae species from Bournemouth in England. Estimates of atmospheric carbon dioxide concentrations derived from stomatal data from plants of the Early Devonian, Late Carboniferous, Early Permian and Middle Jurassic ages are reviewed in the light of new data. Semi-quantitative palaeo-carbon dioxide estimates based on the stomatal ratio (a ratio of the stomatal index of a fossil plant to that of a selected nearest living equivalent) have in the past relied on the use of a Carboniferous standard. The application of a new standard based on the present-day carbon dioxide level is reported here for comparison. The resultant ranges of palaeo-carbon dioxide estimates made from standardized fossil stomatal ratio data are in good agreement with both carbon isotopic data from terrestrial and marine sources and long-term carbon cycle modelling estimates for all the time periods studied. These data indicate elevated atmospheric carbon dioxide concentrations during the Early Devonian, Middle Jurassic and Middle Eocene, and reduced concentrations during the Late Carboniferous and Early Permian. Such data are important in demonstrating the long-term responses of plants to changing carbon dioxide concentrations and in contributing to the database needed for general circulation model climatic analogues.

18 CFR 270.306 - Devonian shale wells in Michigan.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Devonian shale wells in... PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.306 Devonian shale wells in Michigan. A person seeking a determination that natural gas is being produced from the Devonian Age Antrim...

18 CFR 270.306 - Devonian shale wells in Michigan.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 18 Conservation of Power and Water Resources 1 2014-04-01 2014-04-01 false Devonian shale wells in... PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.306 Devonian shale wells in Michigan. A person seeking a determination that natural gas is being produced from the Devonian Age Antrim...

18 CFR 270.306 - Devonian shale wells in Michigan.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 18 Conservation of Power and Water Resources 1 2013-04-01 2013-04-01 false Devonian shale wells in... PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.306 Devonian shale wells in Michigan. A person seeking a determination that natural gas is being produced from the Devonian Age Antrim...

18 CFR 270.306 - Devonian shale wells in Michigan.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 18 Conservation of Power and Water Resources 1 2012-04-01 2012-04-01 false Devonian shale wells in... PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.306 Devonian shale wells in Michigan. A person seeking a determination that natural gas is being produced from the Devonian Age Antrim...

Late Frasnian-Famennian climates based on palynomorph analyses and the question of the Late Devonian glaciations

NASA Astrophysics Data System (ADS)

Streel, Maurice; Caputo, Mário V.; Loboziak, Stanislas; Melo, José Henrique G.

2000-11-01

Palynomorph distribution in Euramerica and western Gondwana, from the Latest Givetian to the Latest Famennian, may be explained, to some extent, by climatic changes. Detailed miospore stratigraphy dates accurately the successive steps of these changes. Interpretation is built on three postulates which are discussed: Euramerica at slightly lower latitudes than generally accepted by most paleomagnetic reconstructions; a conodont time-scale accepted as the most used available subdivision of time; and Late Devonian sea-level fluctuations mainly governed by glacio-eustasy. The Frasnian-Famennian timescale is also evaluated. The comparison, based on conodont correlations, between Givetian and most of the Frasnian miospore assemblages from, respectively, northern and southern Euramerica demonstrates a high taxonomic diversity in the equatorial belt and much difference between supposed equatorial and (sub) tropical vegetations. On the contrary, a similar vegetation pattern and therefore probably compatible climatic conditions were present from tropical to subpolar areas. A rather hot climate culminated during the Latest Frasnian when equatorial miospore assemblages reached their maximum width. The miospore diversity shows also a rather clear global Late Frasnian minimum which is also recorded during the Early and Middle Famennian but only in low latitude regions while, in high latitude, very cold climates without perennial snow may explain the scarcity of miospores and so, of vegetation. The Early and Middle Famennian conspicuous latitudinal gradient of the vegetation seems to attenuate towards the Late and Latest Famennian but this might be above all the result of the development, of cosmopolitan coastal lowland vegetations (downstream swamps) depending more on the moisture and equable local microclimates than on the probably adverse climates of distant hinterland areas. During that time, periods of cold climate without perennial snow cover and with rare vegetation may have alternated with less cold but wetter climates, thus giving rise to the development of mountain glaciers in high latitudes and explaining the jerking character of the global major marine regression. In high latitude regions, the development of an ice cap reaching sea level is only recorded by the end of the Latest Famennian, immediately below the DCB but, even if glacial evidences are not known at near the FFB, a short (0.1 Ma?) glaciation seems the best reasonable explanation of the major eustatic fall following the Kellwasser Event. The sudden growth and decay of a hypothetical Earliest Famennian ice sheet can be explained by the reduction and, later, increase in greenhouse capacity of the atmosphere. These changes in the atmospheric CO 2 might have provoked changes in the mode of ocean-atmosphere operation. It may also be partly controlled by a volcanic paroxysm and/or bolide impacts. The Hony microtektites represent the best known evidence of the impact of extraterrestrial bodies on Earth corresponding to the UKW, and they are immediately followed by a regression, suggested by the quantitative analysis of acritarch assemblages. In the paleo-tropical Late Famennian, a peat-forming vascular plant community occurs for the first time and makes possible quantitative palynology of autochthonous sediments allowing the recognition of different swamp and near-swamp characteristic miospores. The early Latest Famennian starts with a widespread transgression which could correspond to the melting phases of the hypothetical Late Famennian mountain glaciers. During the end-Famennian, the coastal lowland vegetation has a worldwide distribution from sub-polar to equatorial regions. The climate has become less cold in high latitudes but wetter than before probably because the midlatitude cyclonic activity allows sufficient polar transportation of moisture to form large snow cover. Extensive coastal glaciers developed in different Bolivian and Brazilian basins, well dated by miospores. Rapid climatic changes characterize the onset of glaciation. The cyclic nature of climate allowed even intertropical marine faunas to reach occasionally the subpolar regions. For the plant kingdom, the crisis which follows the Hangenberg Event was more severe than the Late Frasnian Crisis.

18 CFR 270.303 - Natural gas produced from Devonian shale.

Code of Federal Regulations, 2013 CFR

2013-04-01

... from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale... 18 Conservation of Power and Water Resources 1 2013-04-01 2013-04-01 false Natural gas produced from Devonian shale. 270.303 Section 270.303 Conservation of Power and Water Resources FEDERAL ENERGY...

18 CFR 270.303 - Natural gas produced from Devonian shale.

Code of Federal Regulations, 2012 CFR

2012-04-01

... from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale... 18 Conservation of Power and Water Resources 1 2012-04-01 2012-04-01 false Natural gas produced from Devonian shale. 270.303 Section 270.303 Conservation of Power and Water Resources FEDERAL ENERGY...

18 CFR 270.303 - Natural gas produced from Devonian shale.

Code of Federal Regulations, 2014 CFR

2014-04-01

... from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale... 18 Conservation of Power and Water Resources 1 2014-04-01 2014-04-01 false Natural gas produced from Devonian shale. 270.303 Section 270.303 Conservation of Power and Water Resources FEDERAL ENERGY...

Revisions to the original extent of the Devonian Shale-Middle and Upper Paleozoic Total Petroleum System

USGS Publications Warehouse

Enomoto, Catherine B.; Rouse, William A.; Trippi, Michael H.; Higley, Debra K.

2016-04-11

Technically recoverable undiscovered hydrocarbon resources in continuous accumulations are present in Upper Devonian and Lower Mississippian strata in the Appalachian Basin Petroleum Province. The province includes parts of New York, Pennsylvania, Ohio, Maryland, West Virginia, Virginia, Kentucky, Tennessee, Georgia, and Alabama. The Upper Devonian and Lower Mississippian strata are part of the previously defined Devonian Shale-Middle and Upper Paleozoic Total Petroleum System (TPS) that extends from New York to Tennessee. This publication presents a revision to the extent of the Devonian Shale-Middle and Upper Paleozoic TPS. The most significant modification to the maximum extent of the Devonian Shale-Middle and Upper Paleozoic TPS is to the south and southwest, adding areas in Tennessee, Georgia, Alabama, and Mississippi where Devonian strata, including potential petroleum source rocks, are present in the subsurface up to the outcrop. The Middle to Upper Devonian Chattanooga Shale extends from southeastern Kentucky to Alabama and eastern Mississippi. Production from Devonian shale has been established in the Appalachian fold and thrust belt of northeastern Alabama. Exploratory drilling has encountered Middle to Upper Devonian strata containing organic-rich shale in west-central Alabama. The areas added to the TPS are located in the Valley and Ridge, Interior Low Plateaus, and Appalachian Plateaus physiographic provinces, including the portion of the Appalachian fold and thrust belt buried beneath Cretaceous and younger sediments that were deposited on the U.S. Gulf Coastal Plain.

Magmatic record of Late Devonian arc-continent collision in the northern Qiangtang, Tibet: Implications for the early evolution of East Paleo-Tethys Ocean

NASA Astrophysics Data System (ADS)

Dan, Wei; Wang, Qiang; Zhang, Xiu-Zheng; Zhang, Chunfu; Tang, Gong-Jian; Wang, Jun; Ou, Quan; Hao, Lu-Lu; Qi, Yue

2018-05-01

Recognizing the early-developed intra-oceanic arc is important in revealing the early evolution of East Paleo-Tethys Ocean. In this study, new SIMS zircon U-Pb dating, O-Hf isotopes, and whole-rock geochemical data are reported for the newly-discovered Late Devonian-Early Carboniferous arc in Qiangtang, central Tibet. New dating results reveal that the eastern Riwanchaka volcanic rocks were formed at 370-365 Ma and were intruded by the 360 Ma Gangma Co alkali feldspar granites. The volcanic rocks consist of basalts, andesites, dacites, and rhyodacites, whose geochemistry is similar to that typical of subduction-related volcanism. The basalts and andesites were generated by partial melting of the fluid and sediment-melt metasomatized mantle, respectively. The rhyodacites and dacites were probably derived from the fractional crystallization of andesites and from partial melting of the juvenile underplated mafic rocks, respectively. The Gangma Co alkali feldspar granites are A-type granites, and were possibly derived by partial melting of juvenile underplated mafic rocks in a post-collisional setting. The 370-365 Ma volcanic arc was characterized by basalts with oceanic arc-like Ce/Yb ratios and by rhyodacites with mantle-like or slightly higher zircon δ18O values, and it was associated with the contemporary ophiolites. Thus, we propose that it is the earliest intra-oceanic arc in the East Paleo-Tethys Ocean, and was accreted to the Northern Qiangtang Terrane during 365-360 Ma.

500 Myr of thermal history elucidated by multi-method detrital thermochronology of North Gondwana Cambrian sandstone (Eilat area, Israel)

NASA Astrophysics Data System (ADS)

Vermeesch, P.; Avigad, D.

2009-04-01

Following the Neoproterozoic Pan-African orogeny, the Arabian-Nubian Shield (ANS) of North Africa and Arabia was eroded and then covered by Cambrian sandstones that record the onset of platform sedimentation. We applied K-feldspar 40Ar/39Ar, zircon and apatite fission track and apatite (U-Th)/He thermochronology to detritus from Cambrian sandstones of southern Israel deposited at about 500 Ma. U-Pb detrital zircon ages from these sandstones predate deposition and record the earlier Neoproterozoic crustal evolution of the Pan-African orogens. 40Ar/39Ar ages from 50 single grains of K-feldspar yield a Cambrian mean of approximately 535 Ma. The 40Ar/39Ar age spectrum of a multi-grain K-feldspar aliquot displays diffusion behaviour compatible with >560 Ma cooling later affected by a heating event. Assuming that the high temperature domains of the K-feldspars have not been affected by subsequent (hydro)thermal events, and taking previously published K-Ar and Rb-Sr ages from other parts of the East African Orogen at face value, these ages apparently record Pan-African thermal resetting below a thick volcano-sedimentary pile similar to the Saramuj conglomerate in Jordan and/or the Hammamat in Egypt. Detrital zircon fission track (ZFT) ages cluster around 380 Ma, consistent with previous ZFT results from Neoproterozoic basement and sediments of the region, revealing that the Cambrian platform sequence experienced a middle Devonian thermal event and low-grade metamorphism. Regional correlation indicates that during Devonian time the sedimentary cover atop the Cambrian in Israel was never in excess of 2.5 km, requiring an abnormally steep geothermal gradient to explain the complete ZFT annealing. A basal Carboniferous unconformity can be traced from Syria to southern Saudi Arabia, suggesting that the observed Devonian ZFT ages represent a regional tectonothermal event. Similar Devonian ZFT ages were reported from ANS basement outcrops in the Eastern Desert, 500 km south of Eilat. The detrital apatites we studied all have extremely rounded cores suggestive of a distant provenance, but some grains also feature distinct euhedral U-rich apatite overgrowth rims. Authigenic apatite may have grown during the late Devonian thermal event we dated by ZFT, coinciding with existing Rb-Sr ages from authigenic clays in the same deposits and leading to the conclusion that the Devonian event was probably hydrothermal. Like the ZFT ages, the detrital apatite fission track (AFT) ages were also completely reset after deposition. Sixty single grain detrital apatite fission track (AFT) ages group at ~270 Ma with significant dispersion. Inverse modeling of the AFT data indicate extended and/or repeated residence in the AFT partial annealing zone, in turn suggesting an episodic burial-erosion history during the Mesozoic caused by low-amplitude vertical motions. Seven detrital apatite (U-Th)/He ages scatter between 33 and 77 Ma, possibly resulting from extreme compositional zonation associated with the authigenic U-rich overgrowths. The ~70 Ma (U-Th)/He ages are more likely to be accurate, setting 1-2 km as an upper limit (depending on the geothermal gradient) on the post-Cretaceous exhumation of the Cambrian sandstone and showing no evidence for substantial denudation related to Tertiary rifting of the Red Sea.

Bedrock geologic map of the Miles Pond and Concord quadrangles, Essex and Caledonia Counties, Vermont, and Grafton County, New Hampshire

USGS Publications Warehouse

Rankin, Douglas W.

2018-04-20

The bedrock geologic map of the Miles Pond and Concord quadrangles covers an area of approximately 107 square miles (276 square kilometers) in east-central Vermont and adjacent New Hampshire, north of and along the Connecticut River. This map was created as part of a larger effort to produce a new bedrock geologic map of Vermont through the collection of field data at a scale of 1:24,000. The majority of the map area consists of the Bronson Hill anticlinorium, a post-Early Devonian structure that is cored by metamorphosed Cambrian to Silurian sedimentary, volcanic, and plutonic rocks. A major feature on the map is the Monroe fault, interpreted to be a west-directed, steeply dipping Late Devonian (Acadian) thrust fault. To the west of the Monroe fault, rocks of the Connecticut Valley-Gaspé trough dominate and consist primarily of metamorphosed Silurian and Devonian sedimentary rocks. To the north, the Victory pluton intrudes the Bronson Hill anticlinorium. The Bronson Hill anticlinorium consists of the metamorphosed Albee Formation, the Ammonoosuc Volcanics, the Comerford Intrusive Complex, the Highlandcroft Granodiorite, and the Joselin Turn tonalite. The Albee Formation is an interlayered, feldspathic metasandstone and pelite that is locally sulfidic. Much of the deformed metasandstone is tectonically pinstriped. In places, one can see compositional layering that was transposed by a steeply southeast-dipping foliation. The Ammonoosuc Volcanics are lithologically complex and predominantly include interlayered and interfingered rhyolitic to basaltic volcanic and volcaniclastic rocks, as well as lesser amounts of siltstone, phyllite, graywacke, and grit. The Comerford Intrusive Complex crops out east of the Monroe fault and consists of metamorphosed gabbro, diorite, tonalite, aplitic tonalite, and crosscutting diabase dikes. Abundant mafic dikes from the Comerford Intrusive Complex intruded the Albee Formation and Ammonoosuc Volcanics east of the Monroe fault. The Highlandcroft Granodiorite and Joslin Turn tonalite plutons intruded during the Middle to Late Ordovician.West of the Monroe fault, the Connecticut Valley-Gaspé trough consists of the Silurian and Devonian Waits River and Gile Mountain Formations. The Waits River Formation is a carbonaceous muscovite-biotite-quartz (±garnet) phyllite containing abundant beds of micaceous quartz-rich limestone. The Gile Mountain Formation consists of interlayered metasandstone and graphitic (and commonly sulfidic) slate, along with minor calcareous metasandstone and ironstone. Graded bedding is common in the Gile Mountain Formation. Rocks of the Devonian New Hampshire Plutonic Suite intruded as plutons, dikes, and sills. The largest of these is the Victory pluton, which consists of weakly foliated, biotite granite and granodiorite. The Victory pluton also intruded a large part of the Albee Formation to the north.This report consists of a geologic map and an online geographic information systems database that includes contacts of bedrock geologic units, faults, outcrops, and structural geologic information. The geologic map is intended to serve as a foundation for applying geologic information to problems involving land use decisions, groundwater availability and quality, earth resources such as natural aggregate for construction, assessment of natural hazards, and engineering and environmental studies for waste disposal sites and construction projects.

Geometry of the neoproterozoic and paleozoic rift margin of western Laurentia: Implications for mineral deposit settings

USGS Publications Warehouse

Lund, K.

2008-01-01

The U.S. and Canadian Cordilleran miogeocline evolved during several phases of Cryogenian-Devonian intracontinental rifting that formed the western mangin of Laurentia. Recent field and dating studies across central Idaho and northern Nevada result in identification of two segments of the rift margin. Resulting interpretations of rift geometry in the northern U.S. Cordillera are compatible with interpretations of northwest- striking asymmetric extensional segments subdivided by northeast-striking transform and transfer segments. The new interpretation permits integration of miogeoclinal segments along the length of the western North American Cordillera. For the U.S. Cordillera, miogeoclinal segments include the St. Mary-Moyie transform, eastern Washington- eastern Idaho upper-plate margin, Snake River transfer, Nevada-Utah lower-plate margin, and Mina transfer. The rift is orthogonal to most older basement domains, but the location of the transform-transfer zones suggests control of them by basement domain boundaries. The zigzag geometry of reentrants and promontories along the rift is paralleled by salients and recesses in younger thrust belts and by segmentation of younger extensional domains. Likewise, transform transfer zones localized subsequent transcurrent structures and igneous activity. Sediment-hosted mineral deposits trace the same zigzag geometry along the margin. Sedimentary exhalative (sedex) Zn-Pb-Ag ??Au and barite mineral deposits formed in continental-slope rocks during the Late Devonian-Mississippian and to a lesser degree, during the Cambrian-Early Ordovician. Such deposits formed during episodes of renewed extension along miogeoclinal segments. Carbonate-hosted Mississippi Valley- type (MVT) Zn-Pb deposits formed in structurally reactivated continental shelf rocks during the Late Devonian-Mississippian and Mesozoic due to reactivation of preexisting structures. The distribution and abundance of sedex and MVT deposits are controlled by the polarity and kinematics of the rift segment. Locally, discrete mineral belts parallel secondary structures such as rotated crustal blocks at depth that produced sedimentary subbasins and conduits for hydrothermal fluids. Where the miogeocline was overprinted by Mesozoic and Cenozoic deformation and magmatism, igneous rock-related mineral deposits are common. ??2008 Geological Society of America.

Upper Devonian outcrop stratigraphy, southwestern Virginia and southeastern West Virginia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dennison, J.M.; Filer, J.K.; Rossbach, T.J.

Ongoing outcrop studies are resulting in the extension of existing formal lithostratigraphic units and revision of previously less refined subdivisions of Upper Devonian strata in southwestern Virginia and southeastern West Virginia. A 425 km (263 mi) long stratigraphic cross-section has been constructed primarily from the outcrop belt along the Allegheny Structural Front, supplemented by sections from nearby outcrop belts. This NE-SW striking cross-section is oblique to the nearly due N-S depositional strike of the Upper Devonian Acadian orogenic wedge. To the southwest, the Upper Devonian section thins from 2,100 meters (6,900 feet) to 230 meters (756 feet) as progressively moremore » distal deposits are encountered. An integrated approach has been taken to establish chronostratigraphic control within the cross-section. The best time markers include particularly regressive parasequences which can be identified across facies boundaries (especially the Pound and Briery Gap Sandstones and their equivalents), volcanic ashes, and an organic-rich shale zone marking the base of a major transgression (equivalent to the base of the Huron Shale in Ohio and the Dunkirk Shale of New York). These tools provide chronostratigraphic correlation through the undivided Brallier Formation. Supplemental control includes biostratigraphic markers as well as marine dull redbeds within the Foreknobs which parallel other time lines and may represent partially reduced influxes of oxidized coastal plain sediments during minor parasequence scale regressions.« less

Lead in the Getchell-Turquoise ridge Carlin-type gold deposits from the perspective of potential igneous and sedimentary rock sources in Northern Nevada: Implications for fluid and metal sources

USGS Publications Warehouse

Tosdal, R.M.; Cline, J.S.; Fanning, C.M.; Wooden, J.L.

2003-01-01

Lead isotope compositions of bulk mineral samples (fluorite, orpiment, and realgar) determined using conventional techniques and of ore-stage arsenian pyrite using the Sensitive High Resolution Ion-Microprobe (SHRIMP) in the Getchell and Turquoise Ridge Carlin-type gold deposits (Osgood Mountains) require contribution from two different Pb sources. One Pb source dominates the ore stage. It has a limited Pb isotope range characterized by 208Pb/206Pb values of 2.000 to 2.005 and 207Pb/206Pb values of 0.8031 to 0.8075, as recorded by 10-??m-diameter spot SHRIMP analyses of ore-stage arsenian pyrite. These values approximately correspond to 206Pb/204Pb of 19.3 to 19.6, 207Pb/204Pb of 15.65 to 15.75, and 208Pb/204Pb of 39.2 to 39.5. This Pb source is isotopically similar to that in average Neoproterozoic and Cambrian elastic rocks but not to any potential magmatic sources. Whether those clastic rocks provided Pb to the ore fluid cannot be unequivocally proven because their Pb isotope compositions over the same range as in ore-stage arsenian pyrite are similar to those of Ordovician to Devonian siliciclastic and calcareous rocks. The Pb source in the calcareous rocks most likely is largely detrital minerals, since that detritus was derived from the same sources as the detritus in the Neoproterozoic and Cambrian clastic rocks. The second Pb source is characterized by a large range of 206Pb/204Pb values (18-34) with a limited range of 208Pb/204Pb values (38.1-39.5), indicating low but variable Th/U and high and variable U/Pb values. The second Pb source dominates late and postore-stage minerals but is also found in preore sulfide minerals. These Pb isotope characteristics typify Ordovician to Devonian siliciclastic and calcareous rocks around the Carlin trend in northeast Nevada. Petrologically similar rocks host the Getchell and Turquoise Ridge deposits. Lead from the second source was either contributed from the host sedimentary rock sequences or brought into the hydrothermal system by oxidized ground water as the system collapsed. Late ore- and postore-stage sulfide minerals (pyrite, orpiment, and stibnite) from the Betze-Post and Meikle deposits in the Carlin trend and from the Jerritt Canyon mining district have Pb isotope characteristics similar to those determined in Getchell and Turquoise Ridge. This observation suggests that the Pb isotope compositions of their ore fluids may be similar to those at Getchell and Turquoise Ridge. Two models can explain the Pb isotope compositions of the ore-stage arsenian pyrite versus the late ore or postore sulfide minerals. In either model, Pb from the Ordovician to Devonian siliciclastic and calcareous rock source enters the hydrothermal system late in the ore stage but not to any extent during the main stage of ore deposition. In one model, ore-stage Pb was derived from a source with Pb isotope compositions similar to those of the Neoproterozoic and Cambrian clastic sequence, transported as part of the ore fluid and then deposited in the ore-stage arsenian pyrite and fluorite. The second model is based on the observation that the Pb isotope characteristics of the ore-stage minerals also are found in some Ordovician to Devonian calcareous and siliciclastic rocks. Hence, ore-stage Pb could have been derived locally and simply concentrated during the ore stage. Critical to the second model is the removal of all high 206Pb/204Pb (>20) material during alteration. It Also requires the retention of only the low 206Pb/204Pb component of the Ordovician to Devonian sedimentary rocks. This critical step is possible only if the high 206Pb/204Pb values are contained in readily dissolvable mineral phases, whereas the low 206Pb/204Pb values are found only in refractory minerals that released Pb during a final alteration stage just prior deposition of auriferous arsenian pyrite. Distinguishing between Pb transported with the ore fluid or inherited from the site of mineral deposition is not straightforward

Ancient plate kinematics derived from the deformation pattern of continental crust: Paleo- and Neo-Tethys opening coeval with prolonged Gondwana-Laurussia convergence

NASA Astrophysics Data System (ADS)

Kroner, Uwe; Roscher, Marco; Romer, Rolf L.

2016-06-01

The formation and destruction of supercontinents requires prolonged convergent tectonics between particular plates, followed by intra-continental extension during subsequent breakup stages. A specific feature of the Late Paleozoic supercontinent Pangea is the prolonged and diachronous formation of the collisional belts of the Rheic suture zone coeval with recurrent continental breakup and subsequent formation of the mid-ocean ridge systems of the Paleo- and Neo-Tethys oceans at the Devonian and Permian margins of the Gondwana plate, respectively. To decide whether these processes are causally related or not, it is necessary to accurately reconstruct the plate motion of Gondwana relative to Laurussia. Here we propose that the strain pattern preserved in the continental crust can be used for the reconstruction of ancient plate kinematics. We present Euler pole locations for the three fundamental stages of the Late Paleozoic assembly of Pangea and closure of the Rheic Ocean: (I) Early Devonian (ca. 400 Ma) collisional tectonics affected Gondwana at the Armorican Spur north of western Africa and at the promontory of the South China block/Australia of eastern Gondwana, resulting in the Variscan and the Qinling orogenies, respectively. The Euler pole of the rotational axis between Gondwana and Laurussia is positioned east of Gondwana close to Australia. (II) Continued subduction of the western Rheic Ocean initiates the clockwise rotation of Gondwana that is responsible for the separation of the South China block from Gondwana and the opening of Paleo-Tethys during the Late Devonian. The position of the rotational axis north of Africa reveals a shift of the Euler pole to the west. (III) The terminal closure of the Rheic Ocean resulted in the final tectonics of the Alleghanides, the Mauritanides and the Ouachita-Sonora-Marathon belt, occurred after the cessation of the Variscan orogeny in Central Europe, and is coeval with the formation of the Central European Extensional Province and the opening of Neo-Tethys at ca. 300 Ma. The Euler pole for the final closure of the Rheic Ocean is positioned near Oslo (Laurussia). Thus, the concomitant formation of convergent and divergent plate boundaries during the assembly of Pangea is due to the relocation of the particular rotational axis. From a geodynamic point of view, coupled collisional (western Pangea) and extensional tectonics (eastern Pangea) due to plate tectonic reorganization is fully explained by slab pull and ridge push forces.

A Devonian tetrapod-like fish reveals substantial parallelism in stem tetrapod evolution.

PubMed

Zhu, Min; Ahlberg, Per E; Zhao, Wen-Jin; Jia, Lian-Tao

2017-10-01

The fossils assigned to the tetrapod stem group document the evolution of terrestrial vertebrates from lobe-finned fishes. During the past 18 years the phylogenetic structure of this stem group has remained remarkably stable, even when accommodating new discoveries such as the earliest known stem tetrapod Tungsenia and the elpistostegid (fish-tetrapod intermediate) Tiktaalik. Here we present a large lobe-finned fish from the Late Devonian period of China that disrupts this stability. It combines characteristics of rhizodont fishes (supposedly a basal branch in the stem group, distant from tetrapods) with derived elpistostegid-like and tetrapod-like characters. This mélange of characters may reflect either detailed convergence between rhizodonts and elpistostegids plus tetrapods, under a phylogenetic scenario deduced from Bayesian inference analysis, or a previously unrecognized close relationship between these groups, as supported by maximum parsimony analysis. In either case, the overall result reveals a substantial increase in homoplasy in the tetrapod stem group. It also suggests that ecological diversity and biogeographical provinciality in the tetrapod stem group have been underestimated.

Variability over time in the sources of South Portuguese Zone turbidites: evidence of denudation of different crustal blocks during the assembly of Pangaea

NASA Astrophysics Data System (ADS)

Pereira, M. F.; Ribeiro, C.; Vilallonga, F.; Chichorro, M.; Drost, K.; Silva, J. B.; Albardeiro, L.; Hofmann, M.; Linnemann, U.

2014-07-01

This study combines geochemical and geochronological data in order to decipher the provenance of Carboniferous turbidites from the South Portuguese Zone (SW Iberia). Major and trace elements of 25 samples of graywackes and mudstones from the Mértola (Visean), Mira (Serpukhovian), and Brejeira (Moscovian) Formations were analyzed, and 363 U-Pb ages were obtained on detrital zircons from five samples of graywackes from the Mira and Brejeira Formations using LA-ICPMS. The results indicate that turbiditic sedimentation during the Carboniferous was marked by variability in the sources, involving the denudation of different crustal blocks and a break in synorogenic volcanism. The Visean is characterized by the accumulation of immature turbidites (Mértola Formation and the base of the Mira Formation) inherited from a terrane with intermediate to mafic source rocks. These source rocks were probably formed in relation to Devonian magmatic arcs poorly influenced by sedimentary recycling, as indicated by the almost total absence of pre-Devonian zircons typical of the Gondwana and/or Laurussia basements. The presence of Carboniferous grains in Visean turbidites indicates that volcanism was active at this time. Later, Serpukhovian to Moscovian turbiditic sedimentation (Mira and Brejeira Formations) included sedimentary detritus derived from felsic mature source rocks situated far from active magmatism. The abundance of Precambrian and Paleozoic zircons reveals strong recycling of the Gondwana and/or Laurussia basements. A peri-Gondwanan provenance is indicated by zircon populations with Neoproterozoic (Cadomian-Avalonian and Pan-African zircon-forming events), Paleoproterozoic, and Archean ages. The presence of late Ordovician and Silurian detrital zircons in Brejeira turbidites, which have no correspondence in the Gondwana basement of SW Iberia, indicates Laurussia as their most probable source.

Trace-element budgets in the Ohio/Sunbury shales of Kentucky: Constraints on ocean circulation and primary productivity in the Devonian-Mississippian Appalachian Basin

USGS Publications Warehouse

Perkins, R.B.; Piper, D.Z.; Mason, C.E.

2008-01-01

The hydrography of the Appalachian Basin in late Devonian-early Mississippian time is modeled based on the geochemistry of black shales and constrained by others' paleogeographic reconstructions. The model supports a robust exchange of basin bottom water with the open ocean, with residence times of less than forty years during deposition of the Cleveland Shale Member of the Ohio Shale. This is counter to previous interpretations of these carbon-rich units having accumulated under a stratified and stagnant water column, i.e., with a strongly restricted bottom bottom-water circulation. A robust circulation of bottom waters is further consistent with the palaeoclimatology, whereby eastern trade-winds drove upwelling and arid conditions limited terrestrial inputs of siliciclastic sediment, fresh waters, and riverine nutrients. The model suggests that primary productivity was high (~ 2??g C m- 2 d- 1), although no higher than in select locations in the ocean today. The flux of organic carbon settling through the water column and its deposition on the sea floor was similar to fluxes found in modern marine environments. Calculations based on the average accumulation rate of the marine fraction of Ni suggest the flux of organic carbon settling out of the water column was approximately 9% of primary productivity, versus an accumulation rate (burial) of organic carbon of 0.5% of primary productivity. Trace-element ratios of V:Mo and Cr:Mo in the marine sediment fraction indicate that bottom waters shifted from predominantly anoxic (sulfate reducing) during deposition of the Huron Shale Member of the Ohio Shale to predominantly suboxic (nitrate reducing) during deposition of the Cleveland Shale Member and the Sunbury Shale, but with anoxic conditions occurring intermittently throughout this period. ?? 2008 Elsevier B.V.

Paleoclimatic and paleomagnetic constraints on the Paleozoic reconstructions of south China, north China and Tarim

NASA Astrophysics Data System (ADS)

Shangyou, Nie

1991-10-01

Paleomagnetic and paleoclimatic data provide the most useful latitudinal constraints for plate reconstructions. Distributions through the Paleozoic of five types of climatically sensitive sediments (coals, evaporites, reefs, dolomites and limestones) for south China, north China and Tarim are shown on 15 maps that include 1578 reliable data points. These paleoclimatic data agree reasonably well with available paleomagnetic directions, although significant divergence between the two exists for the Early Paleozoic. These data indicate the following: (1) South China was in low latitudes during the entire Paleozoic, with a subtropical position in the Cambrian. (2) North China also remained near the equator in the Early and Late Paleozoic, except for the Ordovian and the Late Permian when extensive evaporites suggest slightly higher latitudinal positions, while its Middle Paleozoic position is uncertain due to the missing stratigraphie record. (3) In south China, local tectonics appears to have played a dominant role in determining paleogeography and therefore marine sedimentation, especially after the Late Ordovician-Early Silurian, because the areal coverage of marine sediments through time is distinctly different from what would be expected from published global sea-level curves. (4) Paleoclimatic and paleomagnetic data are compatible with biogeographic data which suggest that south China was part of eastern Gondwana in the Early Paleozoic, but was widely separated from Gondwana in the Late Paleozoic, and the split between the two probably happened in the Devonian, giving rise to a major break-up unconformity in central south China.

The ichnologic record of the continental invertebrate invasion: evolutionary trends in environmental expansion, ecospace utilization, and behavioral complexity

USGS Publications Warehouse

Buatois, L.A.; Mangano, M.G.; Genise, Jorge F.; Taylor, T.N.

1998-01-01

The combined study of continental trace fossils and associated sedimentary facies provides valuable evidence of colonization trends and events throughout the Phanerozoic. Colonization of continental environments was linked to the exploitation of empty or under-utilized ecospace. Although the nonmarine trace fossil record probably begins during the Late Ordovician, significant invasion of nonmarine biotopes began close to the Silurian-Devonian transition with the establishment of a mobile arthropod epifauna (Diplichnites ichnoguild) in coastal marine to alluvial plain settings. Additionally, the presence of vertical burrows in Devonian high-energy fluvial deposits reflects the establishment of a stationary, deep suspension-feeding infauna of the Skolithos ichnoguild. The earliest evidence of plant-arthropod interaction occurred close to the Silurian-Devonian boundary, but widespread and varied feeding patterns are known from the Carboniferous. During the Carboniferous, permanent subaqueous lacustrine settings were colonized by a diverse, mobile detritus-feeding epifauna of the Mermia ichnoguild, which reflects a significant palaeoenvironmental expansion of trace fossils. Paleozoic ichnologic evidence supports direct routes to the land from marginal marine environments, and migration to lakes from land settings. All nonmarine sedimentary environments were colonized by the Carboniferous, and subsequent patterns indicate an increase in ecospace utilization within already colonized depositional settings. During the Permian, back-filled traces of the Scoyenia ichnoguild record the establishment of a mobile, intermediate-depth, deposit-feeding in-fauna in alluvial and transitional alluvial-lacustrine sediment. Diversification of land plants and the establishment of ecologically diverse plant communities through time provided new niches to be exploited by arthropods. Nevertheless, most ot the evolutionary feeding innovations took place relatively early, during the Late Palaeozoic or early Mesozoic. A stationary deep unfauna, the Camborygma ichnoguild, was developed in Triassic transitional alluvial-lacustrinbe deposits. Terrestrial environments hosted the rise of complex social behavioral patterns, as suggested by the probable presence of hymenopteran and isopteran nests in Triassic paleosols. An increase in diversity of trace fossils is detected in Triassic-Jurassic eolian deposits, where the ichnofauna displays more varied behavioral patterns than their Paleozoic counterparts. Also, a mobile, intermediate-depth, deposit-feeding infauna, the Vagorichnus ichnoguild, was established in deep lake environments during the Jurassic. In contrast to Paleozoic permanent subaqueous assemblages typified by surface trails, Jurassic ichnocoenoses are dominated by infaunal burrows. High density of infaunal deposit-feeding traces of the Planolites ichnoguild caused major disruption of lacustrine sedimentary fabrics during the Cretaceous. Most insect mouthpart classes, functional feeding groups, and dietary guilds were established by the end of the Cretaceous. Diversification of modern insects is recorded by the abundance and complexity of structures produced by wasps, bees, dung-beetles, and termites in Cretaceous-Tertiary paleosols. The increase in bioturbation migrated from fluvial and lake-margin settings to permanent subaqueous lacustrine environments through time.

The Bowland Basin, NW England: Base metal mineralisation and its relationship to basin evolution

NASA Astrophysics Data System (ADS)

Gaunt, Jonathan Mark

The Bowland Basin of NW England is a Carboniferous half graben. The Basin was initiated in the Devonian and actively extended during the Carboniferous until the late Westphalian. From the late Westphalian to the early Permian the Bowland Basin underwent inversion in response to Hercynian collision tectonics. Renewed subsidence commenced in the Permian and continued until inversion in the Cenozoic. The sedimentary succession of the Bowland Basin is dominated by Carboniferous strata, but some Permo-Triassic strata are present. The basal sedimentary succession may be comprised of Devonian to early Dinantian syn-rift clastics. The main Dinantian succession is comprised of interbedded limestones, calcareous mudstones and clastic strata. The Dinantian strata include the Waulsortian-facies Clitheroe Limestone and the Limekiln Wood Limestone, both of which host mineralisation. The overlying Namurian is comprised of shales and sandstones. The diagenetic history of the Limekiln Wood Limestone and Waulsortian-facies Clitheroe Limestone in the Cow Ark-Marl Hill Moor district is a function of changes in the burial environment during the Carboniferous. Both exhibit a pre-basin inversion diagenetic sequence that changes with time from shallow to moderate burial depth cements. Late Carbonifeous basin inversion resulted in the formation of tectonic stylolites. Tectonic stylolitisation was postdated by dolomitisation and silicification. Dolomitisation and silicification are suggested to have taken place in the deep burial environment. The base metal mineralisation studied in this work comes from the Cow Ark- Marl Hill Moor district, which is sited on the present basin inversion axis. Mineralisation occurs as four distinct episodes (Period 1, Period 2, Period 3 and Post-Period 3) within a complex multigeneration vein suite. The vein suite, which postdates tectonic stylolitisation and hence end-Carboniferous basin inversion, is comprised of calcite, baroque dolomite, baroque ankerite and siderite. The veins, which are often spatially associated with faults, exhibit a variety of morphologies, and are largely hosted by hydraulic shear fractures. Compositional variations between the different vein carbonates occur with time and the calcites, baroque dolomites, baroque ankerites and siderites are interpreted to have had several different fluid sources. Fluids precipitating siderite, baroque dolomite and baroque ankerite may have been produced by clay mineral transformations and decarboxylation of organic matter within the calcareous strata. The multiple vein calcite generations belong to three MnO:FeO compositional classes, each occupying a specific paragenetic position. The trend from ferroan to manganoan calcite with time may be a consequence of calcite-forming fluids being derived from successively shallower depths within the sedimentary succession, or of increased permeation by meteoric fluids. (Abstract shortened by ProQuest.).

Hunton Group core workshop and field trip

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, K.S.

The Late Ordovician-Silurian-Devonian Hunton Group is a moderately thick sequence of shallow-marine carbonates deposited on the south edge of the North American craton. This rock unit is a major target for petroleum exploration and reservoir development in the southern Midcontinent. The workshop described here was held to display cores, outcrop samples, and other reservoir-characterization studies of the Hunton Group and equivalent strata throughout the region. A field trip was organized to complement the workshop by allowing examination of excellent outcrops of the Hunton Group of the Arbuckle Mountains.

The Devonian Marcellus Shale and Millboro Shale

USGS Publications Warehouse

Soeder, Daniel J.; Enomoto, Catherine B.; Chermak, John A.

2014-01-01

The recent development of unconventional oil and natural gas resources in the United States builds upon many decades of research, which included resource assessment and the development of well completion and extraction technology. The Eastern Gas Shales Project, funded by the U.S. Department of Energy in the 1980s, investigated the gas potential of organic-rich, Devonian black shales in the Appalachian, Michigan, and Illinois basins. One of these eastern shales is the Middle Devonian Marcellus Shale, which has been extensively developed for natural gas and natural gas liquids since 2007. The Marcellus is one of the basal units in a thick Devonian shale sedimentary sequence in the Appalachian basin. The Marcellus rests on the Onondaga Limestone throughout most of the basin, or on the time-equivalent Needmore Shale in the southeastern parts of the basin. Another basal unit, the Huntersville Chert, underlies the Marcellus in the southern part of the basin. The Devonian section is compressed to the south, and the Marcellus Shale, along with several overlying units, grades into the age-equivalent Millboro Shale in Virginia. The Marcellus-Millboro interval is far from a uniform slab of black rock. This field trip will examine a number of natural and engineered exposures in the vicinity of the West Virginia–Virginia state line, where participants will have the opportunity to view a variety of sedimentary facies within the shale itself, sedimentary structures, tectonic structures, fossils, overlying and underlying formations, volcaniclastic ash beds, and to view a basaltic intrusion.

Bedrock geologic map of the Lisbon quadrangle, and parts of the Sugar Hill and East Haverhill quadrangles, Grafton County, New Hampshire

USGS Publications Warehouse

Rankin, Douglas W.

2018-04-20

The bedrock geologic map of the Lisbon quadrangle, and parts of the Sugar Hill and East Haverhill quadrangles, Grafton County, New Hampshire, covers an area of approximately 73 square miles (189 square kilometers) in west-central New Hampshire. This map was created as part of a larger effort to produce a new bedrock geologic map of Vermont through the collection of field data at a scale of 1:24,000. A large part of the map area consists of the Bronson Hill anticlinorium, a post-Early Devonian structure that is cored by metamorphosed Cambrian to Devonian sedimentary, volcanic, and plutonic rocks.The Bronson Hill anticlinorium is the apex of the Middle Ordovician to earliest-Silurian Bronson Hill magmatic arc that contains the Ammonoosuc Volcanics, Partridge Formation, and Oliverian Plutonic Suite, and extends from Maine, through western New Hampshire (down the eastern side of the Connecticut River), through southern New England to Long Island Sound. The deformed and partially eroded arc is locally overlain by a relatively thin Silurian section of metasedimentary rocks (Clough Quartzite and Fitch Formation) that thickens to the east. The Silurian section near Littleton is disconformably overlain by a thicker, Lower Devonian section that includes mostly metasedimentary and minor metavolcanic rocks of the Littleton Formation. The Bronson Hill anticlinorium is bisected by a series of northeast-southwest trending Mesozoic normal faults. Primarily among them is the steeply northwest-dipping Ammonoosuc fault that divides older and younger units (lower and upper sections) of the Ammonoosuc Volcanics. The Ammonoosuc Volcanics are lithologically complex and predominantly include interlayered and interfingered rhyolitic to basaltic volcanic and volcaniclastic rocks, as well as lesser amounts of slate, phyllite, ironstone, chert, sandstone, and pelite. The Albee Formation underlies the Ammonoosuc Volcanics and is predominantly composed of interbedded metamorphosed sandstone, siltstone, and phyllite.During the Late Ordovician, a series of arc-related plutons intruded the Ammonoosuc Volcanics including the Moody Ledge pluton and the Scrag granite of Billings (1937). Subsequent plutonism related to the Acadian orogeny occurred after volcanism and deposition resulted in the Littleton Formation during the Late Devonian, including the intrusion of the Haverhill pluton and French Pond Granite found in the southern part of the map.This report consists of a geologic map and an online geographic information systems database that includes contacts of bedrock geologic units, faults, outcrops, and structural geologic information. The geologic map is intended to serve as a foundation for applying geologic information to problems involving land use decisions, groundwater availability and quality, earth resources such as natural aggregate for construction, assessment of natural hazards, and engineering and environmental studies for waste disposal sites and construction projects.

Evaporite karst of northern lower Michigan

USGS Publications Warehouse

Black, T.J.

1997-01-01

Michigan has three main zones of evaporite karst: collapse breccia in Late Silurian deposits of the Mackinac Straits region; breccia, collapse sinks, and mega-block collapse in Middle Devonian deposits of Northern Lower Michigan, which overlaps the preceding area; and areas of soil swallows in sinks of Mississippian deposits between Turner and Alabaster in Arenac and Iosco counties, and near Grand Rapids in Kent County. The author has focused his study on evaporite karst of the Middle Devonian deposits. The Middle Devonian depos its are the Detroit River Group: a series consisting of limestone, dolomite, shale, salt, gypsum, and anhydrite. The group occurs from subcrop, near the surface, to nearly 1400 feet deep from the northern tip of the Southern Peninsula to the south edge of the "solution front" Glacial drift is from zero to 350 feet thick. Oil and gas exploration has encountered some significant lost-circulation zones throughout the area. Drilling without fluid returns, casing-seal failures, and lost holes are strong risks in some parts of the region. Lost fluid returns near the top of the group in nearby areas indicate some karst development shortly after deposition. Large and irregular lost-circulation zones, linear and patch trends of large sink holes, and 0.25 mile wide blocks of down-dropped land in the northern Lower Peninsula of Michigan were caused by surface- and ground-water movement along faults into the Detroit River Group. Glaciation has removed some evidence of the karst area at the surface. Sinkhole development, collapse valleys, and swallows developed since retreat of the glacier reveal an active solution front in the Detroit River Group.

Precambrian Continent Arctida: A New Kinematic Reconstruction of Late Precambrian - Early Paleozoic Arctida U Europe (baltia) Collision

NASA Astrophysics Data System (ADS)

Borisova, T. P.; Guertseva, M. V.; Egorov, A. Ju.; Kononov, M. V.; Kouznetsov, N. B.

In according to L.P.Zonenshain and L.M.Natapov (1988, 1990), different size conti- nental blocks locating at the margins and inside of present-day Arctic ocean composed the hypothetical early Paleozoic paleocontinent Arctida. The blocks are Kara block (north part of Taymir peninsula, Severnaja Zemlja archipelago and Franz Joseph Land archipelago), north part of Alaska (northward Bruks ridge), Chukchi block, Novosi- birsky block (Novosibirskiye islands together their shelves), several fragments north- ward to the Innuitian orogen (north parts of Peary Land and Ellesmere Island), and Lomonosov ridgeSs block. In the previous kinematic reconstruction it was believed that Arctida as a whole collided with north flanks of Laurentia (Innuitian margin) and Europe (Baltia, Barentsia margin) in middle Paleozoic time. Later, the Arctida (been a fragment of supercontinent Pangea) was fragmented due to a spreading in the Arctic ocean and north part of Atlantic ocean in late Mesozoic and Cenozoic times. Then ArctidaSs fragments were accreted to the Eurasia and North America conti- nents. During the last decade "AEROGEOLOGIA" company has been gathered new data (geologic, stratigraphical, paleomagnetic, and others) of Russian Arctic sector and Svalbard. The data were summarized into "Paleogeographical Atlas for the Rus- sian Arctic sector and Svalbard from Vendian to Jurassic times" (see Abstact SE1.04, ID-NR: EGS02-A-02453). An analyzing of the maps for Vend and Cambrian times allows us to reconsider a few stages of kinematic scenario of late Precambrian - early Paleozoic Arctida U Europe collision. 1) Old interpretation: Arctida was considered as an isolated paleocontinent during early Paleozoic time. New interpretation: during the early Paleozoic Arctida together Europe (Baltia) were assembled into a paleo- continent named us Arcteurope. This conclusion is based on excellent coincidence of Paleozoic paleomagnetic poles of the Kara block (which is a part of Arctida) and Europe (Baltia). 2) Old interpretation: the dextral Kara-Barents shear zone was con- sidered as Europe (Baltia) U Arctida late Devonian suture zone. New interpretation: A collision of Europe (Baltia) and Arctida occurred about the time boundary between Vend and Cambrian times on the Timan suture zone. Time of the collision marked 1 by the Cambrian granitoids of the Timan ridge and west slope of North Urals. 3). Old interpretation: During late Precambrian times Barentsia sialic block was believed as an isolated microcontinent, been accreted to the Europe (Baltia) in the latest Ven- dian time. New interpretation: Barentsia sialic block was a part of Arctida during late Precambrian time. 2

Ste. Genevieve Fault Zone, Missouri and Illinois. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nelson, W.J.; Lumm, D.K.

1985-07-01

The Ste. Genevieve Fault Zone is a major structural feature which strikes NW-SE for about 190 km on the NE flank of the Ozark Dome. There is up to 900 m of vertical displacement on high angle normal and reverse faults in the fault zone. At both ends the Ste. Genevieve Fault Zone dies out into a monocline. Two periods of faulting occurred. The first was in late Middle Devonian time and the second from latest Mississippian through early Pennsylvanian time, with possible minor post-Pennsylvanian movement. No evidence was found to support the hypothesis that the Ste. Genevieve Fault Zonemore » is part of a northwestward extension of the late Precambrian-early Cambrian Reelfoot Rift. The magnetic and gravity anomalies cited in support of the ''St. Louis arm'' of the Reelfoot Rift possible reflect deep crystal features underlying and older than the volcanic terrain of the St. Francois Mountains (1.2 to 1.5 billion years old). In regard to neotectonics no displacements of Quaternary sediments have been detected, but small earthquakes occur from time to time along the Ste. Genevieve Fault Zone. Many faults in the zone appear capable of slipping under the current stress regime of east-northeast to west-southwest horizontal compression. We conclude that the zone may continue to experience small earth movements, but catastrophic quakes similar to those at New Madrid in 1811-12 are unlikely. 32 figs., 1 tab.« less

Ordovician magmatism in the Lévézou massif (French Massif Central): tectonic and geodynamic implications

NASA Astrophysics Data System (ADS)

Lotout, Caroline; Pitra, Pavel; Poujol, Marc; Van Den Driessche, Jean

2017-03-01

New U-Pb dating on zircon yielded ca. 470 Ma ages for the granitoids from the Lévézou massif in the southern French Massif Central. These new ages do not support the previous interpretation of these granitoids as syn-tectonic intrusions emplaced during the Late Devonian-Early Carboniferous thrusting. The geochemical and isotopic nature of this magmatism is linked to a major magmatic Ordovician event recorded throughout the European Variscan belt and related to extreme thinning of continental margins during a rifting event or a back-arc extension. The comparable isotopic signatures of these granitoids on each side of the eclogite-bearing leptyno-amphibolitic complex in the Lévézou massif, together with the fact that they were emplaced at the same time, strongly suggest that these granitoids were originally part of a single unit, tectonically duplicated by either isoclinal folding or thrusting during the Variscan tectonics.

Geological duration of ammonoids controlled their geographical range of fossil distribution.

PubMed

Wani, Ryoji

2017-01-01

The latitudinal distributions in Devonian-Cretaceous ammonoids were analyzed at the genus level, and were compared with the hatchling sizes (i.e., ammonitella diameters) and the geological durations. The results show that (1) length of temporal ranges of ammonoids effected broader ranges of fossil distribution and paleobiogeography of ammonoids, and (2) the hatchling size was not related to the geographical range of fossil distribution of ammonoids. Reducing the influence of geological duration in this analysis implies that hatchling size was one of the controlling factors that determined the distribution of ammonoid habitats at any given period in time: ammonoids with smaller hatchling sizes tended to have broader ammonoid habitat ranges. These relationships were somewhat blurred in the Devonian, Carboniferous, Triassic, and Jurassic, which is possibly due to (1) the course of development of a reproductive strategy with smaller hatchling sizes in the Devonian and (2) the high origination rates after the mass extinction events.

Thermal maturity map of Devonian shale in the Illinois, Michigan, and Appalachian basins of North America

USGS Publications Warehouse

East, Joseph A.; Swezey, Christopher S.; Repetski, John E.; Hayba, Daniel O.

2012-01-01

Much of the oil and gas in the Illinois, Michigan, and Appalachian basins of eastern North America is thought to be derived from Devonian shale that is within these basins (for example, Milici and others, 2003; Swezey, 2002, 2008, 2009; Swezey and others, 2005, 2007). As the Devonian strata were buried by younger sediments, the Devonian shale was subjected to great temperature and pressure, and in some areas the shale crossed a thermal maturity threshold and began to generate oil. With increasing burial (increasing temperature and pressure), some of this oil-generating shale crossed another thermal maturity threshold and began to generate natural gas. Knowledge of the thermal maturity of the Devonian shale is therefore useful for predicting the occurrence and the spatial distribution of oil and gas within these three basins. This publication presents a thermal maturity map of Devonian shale in the Illinois, Michigan, and Appalachian basins. The map shows outlines of the three basins (dashed black lines) and an outline of Devonian shale (solid black lines). The basin outlines are compiled from Thomas and others (1989) and Swezey (2008, 2009). The outline of Devonian shale is a compilation from Freeman (1978), Thomas and others (1989), de Witt and others (1993), Dart (1995), Nicholson and others (2004), Dicken and others (2005a,b), and Stoeser and others (2005).

Strike-slip faulting at Thebes Gap, Missouri and Illinois; implications for New Madrid tectonism

USGS Publications Warehouse

Harrison, Richard W.; Schultz, Art

1994-01-01

Numerous NNE and NE striking strike-slip faults and associated normal faults, folds, and transtensional grabens occur in the Thebes Gap area of Missouri and Illinois. These structures developed along the northwestern margin of the buried Reelfoot rift of Precambrian-Cambrian age at the northern edge of the Mississippi embayment. They have had a long-lived and complex structural history. This is an area of recent moderate seismicity, approximately 45 km north of the New Madrid seismic zone. Stratigraphic evidence suggests that these faults were active during the Middle Ordovician. They were subsequently reactivated between the Early Devonian and Late Cretaceous, probably in response to both the Acadian and Ouachita orogenies. Deformation during this period was characterized by strongly faulted and folded Ordovician through Devonian rocks. In places, these deformed rocks are overlain with angular unconformity by undeformed Cretaceous strata. Fault motion is interpreted as dominantly strike slip. A still younger period of reactivation involved Late Cretaceous and Cenozoic formations as young as the Miocene or Pliocene Mounds Gravel. These formations have experienced both minor high-angle normal faulting and subsequent major, right-lateral strike-slip faulting. En echelon north-south folds, ENE striking normal faults, regional fracture patterns, and drag folds indicate the right-lateral motion for this major episode of faulting which predates deposition of Quaternary loess. Several nondefinitive lines of evidence suggest Quaternary faulting. Similar fault orientations and kinematics, as well as recent seismicity and proximity, clearly suggest a structural relationship between deformation at Thebes Gap and tectonism associated with the New Madrid area.

Evidence for prolonged mid-Paleozoic plutonism and ages of crustal sources in east-central Alaska from SHRIMP U-Pb dating of syn-magmatic, inherited, and detrital zircon

USGS Publications Warehouse

Dusel-Bacon, C.; Williams, I.S.

2009-01-01

Sensitive high-resolution ion microprobe (SHRIMP) U-Pb analyses of igneous zircons from the Lake George assemblage in the eastern Yukon-Tanana Upland (Tanacross quadrangle) indicate both Late Devonian (???370 Ma) and Early Mississippian (???350 Ma) magmatic pulses. The zircons occur in four textural variants of granitic orthogneiss from a large area of muscovite-biotite augen gneiss. Granitic orthogneiss from the nearby Fiftymile batholith, which straddles the Alaska-Yukon border, yielded a similar range in zircon U-Pb ages, suggesting that both the Fiftymile batholith and the Tanacross orthogneiss body consist of multiple intrusions. We interpret the overall tectonic setting for the Late Devonian and Early Mississippian magmatism as an extending continental margin (broad back-arc region) inboard of a northeast-dipping (present coordinates) subduction zone. New SHRIMP U-Pb ages of inherited zircon cores in the Tanacross orthogneisses and of detrital zircons from quartzite from the Jarvis belt in the Alaska Range (Mount Hayes quadrangle) include major 2.0-1.7 Ga clusters and lesser 2.7-2.3 Ga clusters, with subordinate 3.2, 1.4, and 1.1 Ga clusters in some orthogneiss samples. For the most part, these inherited and core U-Pb ages match those of basement provinces of the western Canadian Shield and indicate widespread potential sources within western Laurentia for most grain populations; these ages also match the detrital zircon reference for the northern North American miogeocline and support a correlation between the two areas.

Late Carboniferous paleoichnology reveals the oldest full-body impression of a flying insect.

PubMed

Knecht, Richard J; Engel, Michael S; Benner, Jacob S

2011-04-19

Insects were the first animals to evolve powered flight and did so perhaps 90 million years before the first flight among vertebrates. However, the earliest fossil record of flying insect lineages (Pterygota) is poor, with scant indirect evidence from the Devonian and a nearly complete dearth of material from the Early Carboniferous. By the Late Carboniferous a diversity of flying lineages is known, mostly from isolated wings but without true insights into the paleoethology of these taxa. Here, we report evidence of a full-body impression of a flying insect from the Late Carboniferous Wamsutta Formation of Massachusetts, representing the oldest trace fossil of Pterygota. Through ethological and morphological analysis, the trace fossil provides evidence that its maker was a flying insect and probably was representative of a stem-group lineage of mayflies. The nature of this current full-body impression somewhat blurs distinctions between the systematics of traces and trace makers, thus adding to the debate surrounding ichnotaxonomy for traces with well-associated trace makers.

The Inskip Formation, the Harmony Formation, and the Havallah Sequence of Northwestern Nevada - An Interrelated Paleozoic Assemblage in the Home of the Sonoma Orogeny

USGS Publications Warehouse

Ketner, Keith B.

2008-01-01

An area between the towns of Winnemucca and Battle Mountain in northwestern Nevada, termed the arkosic triangle, includes the type areas of the middle to upper Paleozoic Inskip Formation and Havallah sequence, the Upper Devonian to Mississippian Harmony Formation, the Sonoma orogeny, and the Golconda thrust. According to an extensive body of scientific literature, the Havallah sequence, a diverse assemblage of oceanic rocks, was obducted onto the continent during the latest Permian or earliest Triassic Sonoma orogeny by way of the Golconda thrust. This has been the most commonly accepted theory for half a century, often cited but rarely challenged. The tectonic roles of the Inskip and Harmony Formations have remained uncertain, and they have never been fully integrated into the accepted theory. New, and newly interpreted, data are incompatible with the accepted theory and force comprehensive stratigraphic and tectonic concepts that include the Inskip and Harmony Formations as follows: middle to upper Paleozoic strata, including the Inskip, Harmony, and Havallah, form an interrelated assemblage that was deposited in a single basin on an autochthonous sequence of Cambrian, Ordovician, and lowest Silurian strata of the outer miogeocline. Sediments composing the Upper Devonian to Permian sequence entered the basin from both sides, arkosic sands, gravel, limestone olistoliths, and other detrital components entered from the west, and quartz, quartzite, chert, and other clasts from the east. Tectonic activity was expressed as: (1) Devonian uplift and erosion of part of the outer miogeocline; (2) Late Devonian depression of the same area, forming a trough, probably fault-bounded, in which the Inskip, Harmony, and Havallah were deposited; (3) production of intraformational and extrabasinal conglomerates derived from the basinal rocks; and (4) folding or tilting of the east side of the depositional basin in the Pennsylvanian. These middle to upper Paleozoic deposits were compressed in the Jurassic, causing east-verging thrusts in the eastern part of the depositional basin (Golconda thrust) and west-verging thrusts and folds in the western part. Hypotheses involving a far-traveled allochthon that was obducted from an ocean or back-arc basin are incompatible with modern observations and concepts.

The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation

USGS Publications Warehouse

Claypool, George E.; Holser, William T.; Kaplan, Isaac R.; Sakai, Hitoshi; Zak, Israel

1980-01-01

Three hundred new samples of marine evaporite sulfate, of world-wide distribution, were analyzed for δ34S, and 60 of these also for δ18O in the sulfate ion. Detailed δ34S age curves for Tertiary—Cretaceous, Permian—Pennsylvanian, Devonian, Cambrian and Proterozoic times document large variations in δ34S. A summary curve forδ18O also shows definite variations, some at different times than δ34S, and always smaller. The measured δ34S and δ18O correspond to variations in these isotopes in sulfate of the world ocean surface. The variations of δ18O are controlled by input and output fluxes of sulfur in the ocean, three of which are the same that control δ34S: deposition and erosion of sulfate, and deposition of sulfide. Erosion of sulfide differs in its effect on the S and O systems. δ18O in the sulfate does not seem to be measurably affected by equilibration with either seawater or with subsurface waters after crystallization. In principle, the simultaneous application of both δ34S and δ18O age curves should help reduce the number of assumptions in calculations of the cycles of sulfur and oxygen through geological time, and a new model involving symmetrical fluxes is introduced here to take advantage of the oxygen data. However, all previously published models as well as this one lead to anomalies, such as unreasonable calcium or oxygen depletions in the ocean—atmosphere system. In addition, most models are incapable of reproducing the sharp rises of the δ34S curve in the late Proterozoic, the Devonian and the Triassic which would be the result of unreasonably fast net sulfide deposition. This fast depletion could result from an ocean that has not always been mixed (as previously assumed in all model calculations).

Towards a High-resolution Time Scale for the Early Devonian

NASA Astrophysics Data System (ADS)

Dekkers, M. J.; da Silva, A. C.

2017-12-01

High-resolution time scales are crucial to understand Earth's history in detail. The construction of a robust geological time scale, however, inevitably becomes increasingly harder further back in time. Uncertainties associated with anchor radiometric ages increase in size, not speaking of the mere presence of suitable datable strata. However, durations of stages can be tightly constrained by making use of cyclic expressions in sediments, an approach that revolutionized the Cenozoic time scale. When precisely determined durations are stitched together, ultimately, a very precise time scale is the result. For the Mesozoic and Paleozoic an astronomical solution as a tuning target is not available but the dominant periods of eccentricity, obliquity and precession are reasonably well constrained for the entire Phanerozoic which enables their detection by means of spectral analysis. Eccentricity is time-invariant and is used as the prime building block. Here we focus on the Early Devonian, on its lowermost three stages: the Lochkovian, Pragian and Emsian. The uncertainties on the Devonian stage boundaries are currently in the order of several millions of years. The preservation of climatic cycles in diagenetically or even anchimetamorphically affected successions, however, is essential. The fit of spectral peak ratios with those calculated for orbital cycles, is classically used as a strong argument for a preserved climatic signal. Here we use primarily the low field magnetic susceptibility (MS) as proxy parameter, supported by gamma-ray spectrometry to test for consistency. Continuous Wavelet Transform, Evolutive Harmonic Analysis, Multitaper Method, and Average Spectral Misfit are used to reach an optimal astronomical interpretation. We report on classic Early Devonian sections from the Czech Republic: the Pozar-CS (Lochkovian and Pragian), Pod Barrandovem (Pragian and Lower Emsian), and Zlichov (Middle-Upper Emsian). Also a Middle-Upper Emsian section from the US (Road 199 section, Kingston, New York) will be targeted. Strata display Milankovitch cycles to a varying visible degree but spectral analysis of MS with supporting magnetic property tests enables to constrain durations up to an order of magnitude more precise than in the current (2012) Geological Time Scale.

Rhenium and osmium isotopes in black shales and Ni-Mo-PGE-rich sulfide layers, Yukon Territory, Canada, and Hunan and Guizhou provinces, China

USGS Publications Warehouse

Horan, M.F.; Morgan, J.W.; Grauch, R.I.; Coveney, R.M.; Murowchick, J.B.; Hulbert, L.J.

1994-01-01

Rhenium and osmium abundances and osmium isotopic compositions were determined by negative thermal ionization mass spectrometry for samples of Devonian black shale and an associated Ni-enriched sulfide layer from the Yukon Territory, Canada. The same composition information was also obtained for samples of early Cambrian Ni-Mo-rich sulfide layers hosted in black shale in Guizhou and Hunan provinces, China. This study was undertaken to constrain the origin of the PGE enrichment in the sulfide layers. Samples of the Ni sulfide layer from the Yukon Territory are highly enriched in Re, Os, and other PGE, with distinctly higher Re/192Os but similar Pt/Re, compared to the black shale host. Re-Os isotopic data of the black shale and the sulfide layer are approximately isochronous, and the data plot close to reference isochrons which bracket the depositional age of the enclosing shales. Samples of the Chinese sulfide layers are also highly enriched in Re, Os, and the other PGE. Re/192Os are lower than in the Yukon sulfide layer. Re-Os isotopic data for the sulfide layers lie near a reference isochron with an age of 560 Ma, similar to the depositional age of the black shale host. The osmium isotopic data suggest that Re and PGE enrichment of the brecciated sulfide layers in both the Yukon Territory and in southern China may have occurred near the time of sediment deposition or during early diagenesis, during the middle to late Devonian and early Cambrian, respectively. ?? 1994.

Devonian alkaline magmatic belt along the northern margin of the North China Block: Petrogenesis and tectonic implications

NASA Astrophysics Data System (ADS)

Zhang, Qi-Qi; Zhang, Shuan-Hong; Zhao, Yue; Liu, Jian-Min

2018-03-01

Some Devonian magmatic rocks have been identified from the northern margin of the North China Block (NCB) in recent years. However, their petrogenesis and tectonic setting are still highly controversial. Here we present new geochronological, Sr-Nd-Hf isotopic and whole-rock chemical data on several newly identified and previously reported Devonian alkaline complexes, including mafic-ultramafic rocks (pyroxenites and gabbros), alkaline rocks (syenites, monzonites) and alkaline granites in the northern NCB. We firstly identified some mafic-ultramafic rocks coeval with monzonite and quartz monzonite in the Sandaogou and Wulanhada alkaline intrusions. New zircon U-Pb dating of 16 samples from the Baicaigou, Gaojiacun, Sandaogou, Wulanhada and Chifeng alkaline intrusions combined with previous geochronological results indicate that the Devonian alkaline rocks emplaced during the early-middle Devonian at around 400-380 Ma and constitute an E-W-trending alkaline magmatic belt that extend ca. 900 km long along the northern margin of the NCB. Whole-rock geochemical and Sr-Nd-Hf isotopic data reveal that the Devonian alkaline rocks were mainly originated from partial melting of a variably enriched lithospheric mantle with different involvement of ancient lower crustal component and fractional crystallization. The Devonian alkaline magmatic belt rocks in the northern NCB are characterized by very weak or no deformations and were most likely related to post-collision extension after arc-continent collision between the Bainaimiao island arc and the northern margin of North China Craton during the latest Silurian. Partial melting of subcontinental lithospheric mantle to produce the Devonian alkaline magmatic rocks suggests that the northern North China Craton has an inhomogeneous, variably enriched subcontinental lithospheric mantle and was characterized by significant vertical crustal growth during the Devonian period.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Negus-De Wys, J.; Dixon, J. M.; Evans, M. A.

This document consists of the following papers: inorganic geochemistry studies of the Eastern Kentucky Gas Field; lithology studies of upper Devonian well cuttings in the Eastern Kentucky Gas Field; possible effects of plate tectonics on the Appalachian Devonian black shale production in eastern Kentucky; preliminary depositional model for upper Devonian Huron age organic black shale in the Eastern Kentucky Gas Field; the anatomy of a large Devonian black shale gas field; the Cottageville (Mount Alto) Gas Field, Jackson County, West Virginia: a case study of Devonian shale gas production; the Eastern Kentucky Gas Field: a geological study of the relationshipsmore » of Ohio Shale gas occurrences to structure, stratigraphy, lithology, and inorganic geochemical parameters; and a statistical analysis of geochemical data for the Eastern Kentucky Gas Field.« less

Nd Isotopic Provenance of Sedimentary Rocks Along Margins of North America: ten Years of Study

NASA Astrophysics Data System (ADS)

Patchett, J.; Ross, G. M.

2001-12-01

Ten years of effort, principally employing Nd isotopes, have resulted in substantial advances in understanding of the movements of sedimentary material around North America from Cambrian to Cretaceous time. This synthesis has depended upon work of current and former students S. Samson, J. Gleason, N. Boghossian, C. Garzione, M. Roth, B. Canale and E. Rosenberg, as well as collaborators W. Dickinson and A. Embry, among others. Nd isotopes are particularly good at documenting movements of sedimentary material on the largest (continental) scale and over extended times. What has emerged is a picture of a largely exposed North America-Greenland craton from Neoproterozoic to Ordovician time, a partial to complete burial by detritus from Caledonian-Appalachian mountains starting in the Ordovician, a gradual exhumation during Late Paleozoic and Mesozoic time, followed by a partial burial with Cordilleran detritus during Late Jurassic to Tertiary time. One current question is the nature of the Mesozoic and Tertiary sedimentary material eroded from the North American Cordillera, and its relevance for Cordilleran orogenesis. Another current question is the extent to which Caledonian-Appalachian detritus covered the craton in Devonian-Carboniferous time, and the timing and manner of its removal during Mesozoic time. At first glance, available Nd isotopic data appear to suggest that the Canada-Greenland Shield was largely covered during most of Mesozoic time, a conclusion that would have profound effects on models of dynamic topography. However, this conclusion is also very dependent on the relationship between topography and erosion, because in certain situations a geographically-restricted cover sequence could dominate over low-relief cratonic terrain as a sediment source.

Petroleum geology and resources of the North Caspian Basin, Kazakhstan and Russia

USGS Publications Warehouse

Ulmishek, Gregory F.

2001-01-01

The North Caspian basin is a petroleum-rich but lightly explored basin located in Kazakhstan and Russia. It occupies the shallow northern portion of the Caspian Sea and a large plain to the north of the sea between the Volga and Ural Rivers and farther east to the Mugodzhary Highland, which is the southern continuation of the Ural foldbelt. The basin is bounded by the Paleozoic carbonate platform of the Volga-Ural province to the north and west and by the Ural, South Emba, and Karpinsky Hercynian foldbelts to the east and south. The basin was originated by pre-Late Devonian rifting and subsequent spreading that opened the oceanic crust, but the precise time of these tectonic events is not known. The sedimentary succession of the basin is more than 20 km thick in the central areas. The drilled Upper Devonian to Tertiary part of this succession includes a prominent thick Kungurian (uppermost Lower Permian) salt formation that separates strata into the subsalt and suprasalt sequences and played an important role in the formation of oil and gas fields. Shallow-shelf carbonate formations that contain various reefs and alternate with clastic wedges compose the subsalt sequence on the 1 basin margins. Basinward, these rocks grade into deep-water anoxic black shales and turbidites. The Kungurian salt formation is strongly deformed into domes and intervening depressions. The most active halokinesis occurred during Late Permian?Triassic time, but growth of salt domes continued later and some of them are exposed on the present-day surface. The suprasalt sequence is mostly composed of clastic rocks that are several kilometers thick in depressions between salt domes. A single total petroleum system is defined in the North Caspian basin. Discovered reserves are about 19.7 billion barrels of oil and natural gas liquids and 157 trillion cubic feet of gas. Much of the reserves are concentrated in the supergiant Tengiz, Karachaganak, and Astrakhan fields. A recent new oil discovery on the Kashagan structure offshore in the Caspian Sea is probably also of the supergiant status. Major oil and gas reserves are located in carbonate reservoirs in reefs and structural traps of the subsalt sequence. Substantially smaller reserves are located in numerous fields in the suprasalt sequence. These suprasalt fields are largely in shallow Jurassic and Cretaceous clastic reservoirs in salt dome-related traps. Petroleum source rocks are poorly identified by geochemical methods. However, geologic data indicate that the principal source rocks are Upper Devonian to Lower Permian deep-water black-shale facies stratigraphically correlative to shallow-shelf carbonate platforms on the basin margins. The main stage of hydrocarbon generation was probably in Late Permian and Triassic time, during deposition of thick orogenic clastics. Generated hydrocarbons migrated laterally into adjacent subsalt reservoirs and vertically, through depressions between Kungurian salt domes where the salt is thin or absent, into suprasalt clastic reservoirs. Six assessment units have been identified in the North Caspian basin. Four of them include Paleozoic subsalt rocks of the basin margins, and a fifth unit, which encompasses the entire total petroleum system area, includes the suprasalt sequence. All five of these assessment units are underexplored and have significant potential for new discoveries. Most undiscovered petroleum resources are expected in Paleozoic subsalt carbonate rocks. The assessment unit in subsalt rocks with the greatest undiscovered potential occupies the south basin margin. Petroleum potential of suprasalt rocks is lower; however, discoveries of many small to medium size fields are expected. The sixth identified assessment unit embraces subsalt rocks of the central basin areas. The top of subsalt rocks in these areas occurs at depths ranging from 7 to 10 kilometers and has not been reached by wells. Undiscovered resources of this unit did not rec

Geology of quadrangles H-12, H-13, and parts of I-12 and I-13, (zone III) in northeastern Santander Department, Colombia

USGS Publications Warehouse

Ward, Dwight Edward; Goldsmith, Richard; Cruz, Jaime B.; Restrepo, Hernan A.

1974-01-01

A program of geologic mapping and mineral investigation in Colombia was undertaken cooperatively by the Colombian Instituto Nacional de Investigaciones Geologico-Mineras (formerly known as the Inventario Minero Nacional), and the U. S. Geological Survey; by the Government of Colombia and the Agency for International Development, U. S. Department of State. The purpose was to study, and evaluate mineral resources (excluding of petroleum, coal, emeralds, and alluvial gold) of four selected areas, designated Zones I to IV, that total about 70,000 km2. The work in Zone III, in the Cordillera Oriental, was done from 1965 to 1968. The northeast trend of the Cordillera Oriental of Colombia swings abruptly to north-northwest in the area of this report, and divides around the southern end of the Maracaibo Basin. This section of the Cordillera Oriental is referred to as the Santander Massif. Radiometric age determinations indicate that the oldest rocks of the Santander massif are Precambrian and include high-grade gneiss, schist, and migmatite of the Bucaramanga Formation. These rocks were probably part of the Precambrian Guayana Shield. Low- to medium-grade metamorphic rocks of late Precambrian to Ordovician age .include phyllite, schist, metasiltstone, metasandstone, and marble of the Silgara Formation, a geosynclinal series of considerable extent in the Cordillera Oriental and possibly the Cordillera de Merida of Venezuela. Orthogneiss ranging from granite to tonalite is widely distributed in the high- and medium-grade metamorphic rocks of the central core of the massif and probably represents rocks of two ages, Precambrian and Ordovician to Early Devonian. Younger orthogneiss and the Silgara are overlain by Middle Devonian beds of the Floresta Formation which show a generally low but varying degree of metamorphism. Phyllite and argillite are common, and infrequent marble and other calcareous beds are fossiliferous. Except for recrystallization in limestones of !the Permian-Carboniferous Diamante Formation, sedimentary rocks younger than Devonian are unmetamorphosed. The effects of Precambrian regional dynamothermal metamorphism and plutonism on Precambrian geosynclinal deposits reached the upper amphibolite facies in the Bucaramanga Gneiss. The geosynclinal Silgara Formation was subjected to similar conditions in Late Ordovician and Early Silurian time but reached only the greenschist or lower amphibolite facies. Orthogneisses generally show a concordance of foliation and lineation with the neighboring Silgara Formation and the Bucaramanga Gneiss as well as similarities in grade of metamorphism. Regional dynamothermal metamorphism in Late Permian and Triassic time reached, low grade in the Floresta Formation and caused recrystallization of limestone of the Diamante Formation. The Bucaramanga and Silgara metamorphic rocks show evidence of metrogressive metamorphism accompanied by high activity or potassium and water, but whether this occurred at the time the Floresta was metamorphosed or later is not clear. Batholiths, plutons, and stocks of igneous rocks in the Santander massif range from diorite to granite. Radioactive age data indicate that most belong to a single plutonic interval. These are referred to as the Santander Plutoniq Group and are Jurassic and Jurassic-Triassic- Two suites of this group are pink granite and quartz monzonite, and gray quartz monzonite and granodiorite. Contact relations indicate that the pink and more granitic rocks are younger than the gray and more mafic rocks, but radioactive age data are in conflict with this. Undated plutonic rocks that are not clearly related to the group are assigned to relatively older or younger age positions. West of the Bucanamanga fault rhyolite makes up a small body at one locality and forms an intrusive sheet with granophyre and intrusive breccias in Triassic sedimentary rocks at another locality. Its age is unknown, but it probably is younger than the

Geochemistry, palynology, and regional geology of worldclass Upper Devonian source rocks in the Madre de Dios basin, Bolivia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, K.E.; Conrad, K.T.; Carpenter, D.G.

Recent exploration drilling indicates the existence of world-class source rock in the Madre de Dios basin, Bolivia. In the Pando-1 X and -2X wells, over 200 m of poorly bioturbated, organic-rich (TOC = 3-16 wt.%) prodelta to shelf mudstones in the Frasnian-Famennian Tomachi Formation contain oil-prone organic matter (hydrogen index = 400-600 mg HC/g TOC). Our calculated source prolificity indices for this interval in these wells (SPI = 15-18 tons of hydrocarbons per square meter of source rock) exceed that for the Upper Jurassic in Central Saudi Arabia. The Tomachi interval is lithologically equivalent to the Colpacucho Formation in themore » northern Altiplano, the Iquiri Formation in the Cordillera Oriental, and is coeval with other excellent source rocks in North America, Africa, and Eurasia. All of these rocks were deposited under conditions favorable for accumulation of organic matter, including a global highstand and high productivity. However, the Madre de Dios basin was situated at high latitude during the Late Devonian and some of the deposits are interpreted to be of glacial origin, indicating conditions not generally associated with organic-rich deposition. A biomarker and palynological study of Upper Devonian rocks in the Pando-1X well suggests deposition under conditions similar to certain modern fjords. High productivity resulted in preservation of abundant organic matter in the bottom sediments despite a cold, toxic water column. Low-sulfur crude oil produced from the Pando-1X well is geochemically similar to, but more mature than, extracts from associated organic-rich Tomachi samples, and was generated from deeper equivalents of these rocks.« less

Modeling Variable Phanerozoic Oxygen Effects on Physiology and Evolution.

PubMed

Graham, Jeffrey B; Jew, Corey J; Wegner, Nicholas C

2016-01-01

Geochemical approximation of Earth's atmospheric O2 level over geologic time prompts hypotheses linking hyper- and hypoxic atmospheres to transformative events in the evolutionary history of the biosphere. Such correlations, however, remain problematic due to the relative imprecision of the timing and scope of oxygen change and the looseness of its overlay on the chronology of key biotic events such as radiations, evolutionary innovation, and extinctions. There are nevertheless general attributions of atmospheric oxygen concentration to key evolutionary changes among groups having a primary dependence upon oxygen diffusion for respiration. These include the occurrence of Devonian hypoxia and the accentuation of air-breathing dependence leading to the origin of vertebrate terrestriality, the occurrence of Carboniferous-Permian hyperoxia and the major radiation of early tetrapods and the origins of insect flight and gigantism, and the Mid-Late Permian oxygen decline accompanying the Permian extinction. However, because of variability between and error within different atmospheric models, there is little basis for postulating correlations outside the Late Paleozoic. Other problems arising in the correlation of paleo-oxygen with significant biological events include tendencies to ignore the role of blood pigment affinity modulation in maintaining homeostasis, the slow rates of O2 change that would have allowed for adaptation, and significant respiratory and circulatory modifications that can and do occur without changes in atmospheric oxygen. The purpose of this paper is thus to refocus thinking about basic questions central to the biological and physiological implications of O2 change over geological time.

A pyritized lepidocoleid machaeridian (Annelida) from the Lower Devonian Hunsrück Slate, Germany

PubMed Central

Högström, Anette E.S.; Briggs, Derek E.G.; Bartels, Christoph

2009-01-01

A machaeridian, Lepidocoleus hohensteini sp. nov., is described from the Hunsrück Slate (Lower Emsian) of Germany. The available material includes a unique example preserving evidence of the soft tissues, only the second machaeridian specimen to do so and the first lepidocoleid. This specimen shows that the plates are attached to alternate segments in the trunk. The morphology is consistent with an annelid affinity of the Lepidocoleidae and confirms the unity of the Machaeridia. This discovery adds an important group to the known diversity of this famous late Palaeozoic marine Konservat-Lagerstätte. PMID:19324782

Assessment of water and proppant quantities associated with petroleum production from the Bakken and Three Forks Formations, Williston Basin Province, Montana and North Dakota, 2016

USGS Publications Warehouse

Haines, Seth S.; Varela, Brian A.; Hawkins, Sarah J.; Gianoutsos, Nicholas J.; Thamke, Joanna N.; Engle, Mark A.; Tennyson, Marilyn E.; Schenk, Christopher J.; Gaswirth, Stephanie B.; Marra, Kristen R.; Kinney, Scott A.; Mercier, Tracey J.; Martinez, Cericia D.

2017-06-23

The U.S. Geological Survey (USGS) has completed an assessment of water and proppant requirements and water production associated with the possible future production of undiscovered oil and gas resources in the Three Forks and Bakken Formations (Late Devonian to Early Mississippian) of the Williston Basin Province in Montana and North Dakota. This water and proppant assessment is directly linked to the geology-based assessment of the undiscovered, technically recoverable continuous oil and gas resources that is described in USGS Fact Sheet 2013–3013.

Emsian (late Early Devonian) sponges from west-central and south-central Alaska

USGS Publications Warehouse

Rigby, J.K.; Blodgett, R.B.; Anderson, N.K.

2009-01-01

Relatively common specimens of the hypercalcified agelasiid sponge Hormospongia labyrinthica Rigby and Blodgett, 1983 and specimens of associated species of Hormospongia have been previously reported from Emsian and Eifelian stratigraphic units at several localities in south-central and southeastern Alaska (Rigby and Blodgett, 1983). Those sponges were first described from the type section of the Eifelian Cheeneetnuk Limestone in the McGrath A-5 quadrangle. Since then several additional specimens of Hormospongia labyrinthica have also been collected from a new locality in the Talkeetna C-6 quadrangle in southcentral Alaska (Figs. 1, 2.1), and are documented here.

Detrital zircon ages in Korean mid-Paleozoic meta-sandstones (Imjingang Belt and Taean Formation): Constraints on tectonic and depositional setting, source regions and possible affinity with Chinese terranes

NASA Astrophysics Data System (ADS)

Han, Seokyoung; de Jong, Koen; Yi, Keewook

2017-08-01

Sensitive High-Resolution Ion Microprobe (SHRIMP) U-Th-Pb isotopic data of detrital zircons from mature, quartz-rich meta-sandstones are used to constrain possible tectonic affinities and source regions of the rhythmically layered and graded-bedded series in the Yeoncheon Complex (Imjingang Belt) and the correlative Taean Formation. These metamorphic marine turbidite sequences presently occur along the Paleoproterozoic (1.93-1.83 Ga) Gyeonggi Massif, central Korea's main high-grade metamorphic gneiss terrane. Yet, detrital zircons yielded highly similar multimodal age spectra with peaks that do not match the age repartition in these basement rocks, as late (1.9-1.8 Ga) and earliest (∼ 2.5 Ga) Paleoproterozoic detrital modes are subordinate but, in contrast, Paleozoic (440-425 Ma) and Neoproterozoic (980-920 Ma) spikes are prominent, yet the basement essentially lacks lithologies with such ages. The youngest concordant zircon ages in each sample are: 378, 394 and 423 Ma. The maturity of the meta-sandstones and the general roundness of zircons of magmatic signature, irrespective of their age, suggest that sediments underwent considerable transport from source to sink, and possibly important weathering and recycling, which may have filtered out irradiation-weakened metamorphic zircon grains. In combination with these isotopic data, presence of a low-angle ductile fault contact between the Yeoncheon Complex and the Taean Formation and the underlying mylonitized Precambrian basement implies that they are in tectonic contact and do not have a stratigraphic relationship, as often assumed. Consequently, in all likelihood, both meta-sedimentary formations: (1) are at least of early Late Devonian age, (2) received much of their detritus from distant (reworked) Silurian-Devonian and Early Neoproterozoic magmatic sources, not present in the Gyeonggi Massif, (3) and not from Paleoproterozoic crystalline rocks of this massif, or other Korean Precambrian basement terranes, and (4) should be viewed as independent tectonic units that had sources not exposed in Korea. A thorough literature review reveals that the Yeoncheon Complex and the Taean Formation were potentially sourced from the Liuling, Nanwan and Foziling groups in the Qinling-Dabie Belt, which all show very similar detrital zircon age spectra. These immature middle-late Devonian sandstones were deposited in a pro-foreland basin formed as a result of the aborted subduction of the South Qinling Terrane below the North Qinling Terrane, which was uplifted and eroded during post-collision isostatic rebound. The submarine fans where the mature distal turbiditic Yeoncheon and Taean sandstones were deposited may have constituted the eastern terminal part of a routing system originating in the uplifted and eroded middle Paleozoic Qinling Belt and adjacent part of the foreland basin.

18 CFR 270.303 - Natural gas produced from Devonian shale.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Natural gas produced... DETERMINATION PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.303 Natural gas produced from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale...

18 CFR 270.303 - Natural gas produced from Devonian shale.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Natural gas produced... DETERMINATION PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.303 Natural gas produced from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale...

Unroofing history of Late Paleozoic magmatic arcs within the ``Turan Plate'' (Tuarkyr, Turkmenistan)

NASA Astrophysics Data System (ADS)

Garzanti, E.; Gaetani, M.

2002-07-01

Stratigraphic, sedimentologic and petrographic data collected on the Kizilkaya sedimentary succession (Western Turkmenistan) demonstrate that the "Turan Plate" consists in fact of an amalgamation of Late Paleozoic to Triassic continental microblocks separated by ocean sutures. In the Kizilkaya area, an ophiolitic sequence including pyroxenite, gabbro, pillow basalt and chert, interpreted as the oceanic crust of a back-arc or intra-arc basin, is tectonically juxtaposed against volcaniclastic redbeds documenting penecontemporaneous felsic arc magmatism (Amanbulak Group). A collisional event took place around ?mid-Carboniferous times, when oceanic rocks underwent greenschist-facies metamorphism and a thick volcaniclastic wedge, with pyroclastic rocks interbedded in the lower part, accumulated (Kizilkaya Formation). The climax of orogenic activity is testified by arid fanglomerates shed from the rapid unroofing of a continental arc sequence, including Middle-Upper Devonian back-reef carbonates and cherts, and the underlying metamorphic and granitoid basement rocks (Yashmu Formation). After a short period of relative quiescence, renewed tectonic activity is indicated by a conglomeratic sequence documenting erosion of a sedimentary and metasedimentary succession including chert, sandstone, slate and a few carbonates. A final stage of rhyolitic magmatism took place during rapid unroofing of granitoid basement rocks (Kizildag Formation). Such a complex sequence of events recorded by the Kizilkaya episutural basin succession documents the stepwise assemblage of magmatic arcs and continental fragments to form the Turan microblock collage during the Late Paleozoic. Evolution of detrital modes is compatible with that predicted for juvenile to accreted and unroofed crustal blocks. The deposition of braidplain lithic arkoses in earliest Triassic time indicates that strong subsidence continued after the end of the volcanic activity, possibly in retroarc foreland basin settings. The occurrence of transgressive coquinas yielding endemic ammonoids ( Dorikranites) characteristic of the whole Caspian area suggests proximity to the southern margin of the newly formed Eurasian continent in the late Early Triassic. The Late Triassic Eo-Cimmerian Orogeny caused only mild tilting and rejuvenation of the underlying succession in the study area. Only at this time were the Turan blocks, a series of Indonesian-type terranes comprised between the Mashad Paleo-Tethys Suture in the south and the Mangyshlak belt in the north, finally incorporated into the Eurasian landmass.

The pre-Mesozoic tectonic unit division of the Xing-Meng orogenic belt (XMOB)

NASA Astrophysics Data System (ADS)

Xu, Bei; Zhao, Pan

2014-05-01

According to the viewpoint that the paleo-Asian ocean closed by the end of early Paleozoic and extended during the late Paleozoic, a pre-Mesozoic tectonic unit division has been suggested. Five blocks and four sutures have been recognized in the pre-Devonia stage, the five blocks are called Erguna (EB), Xing'an (XB), Airgin Sum-Xilinhot (AXB), Songliao-Hunshandak (SHB) and Jiamusi (JB) blocks and four sutures, Xinlin-Xiguitu (XXS), Airgin Sum-Xilinhot-Heihe (AXHS), Ondor Sum-Jizhong-Yanji (OJYS) and Mudanjiang (MS) sutures. The EB contains the Precambrian base with the ages of 720-850Ma and ɛHf(T)=+2.5to +8.1. The XB is characterized by the Paleoproterozoic granitic gneiss with ɛHf(T)=-3.9 to -8.9. Several ages from 1150 to 1500 Ma bave been acquired in the AXB, proving presence of old block that links with Hutag Uul block in Mongolia to the west. The Paleoproterozoic (1.8-1.9Ga) and Neoproterozoic (750-850Ma) ages have been reported from southern and eastern parts of the SHB, respectively. As a small block in east margin of the XMOB, the JB outcrops magmatite and granitic gneiss bases with ages of 800-1000Ma. The XXS is marked by blueschists with zircon ages of 490-500Ma in Toudaoqiao village, ophiolites in Xiguitu County and granite with ages of about 500Ma along the northern segment of XXS. The AXHS is characterized by the early Paleozoic arc magmatic rocks with ages from 430Ma to 490Ma, mélange and the late Devonia molass basins, which indicates a northward subduction of the SHB beneath the AXB during the early-middle Paleozoic. The OJYS is composed of the early Paleozoic volcanic rocks, diorites and granites with ages of 425-475Ma, blueschists, ophiolitic mélange, the late Silurian flysch and Early-Middle Devonian molasses in western segment, granites (420-450Ma) in middle segment, and plagiogranites (443Ma) and the late Silurian molasses in eastern segment. This suture was caused by a southward subduction of the SHB beneath the North China block. The MS is between the SHB and JB, marked by the three phase granites of 485, 450 and 425Ma in the SHB. Tectonic units of the middle Devonian-Carboniferous tectonic stage include the middle-late Devonian continental basin, Carboniferious continental and epeiric sea basin, intrusive and irruptive igneous rock belt with ages from 300Ma to 330Ma containing granites, diorites, gabbros and biomodal volcanic rocks, and early Carboniferious ophiolites of 330-350Ma in Hegenshan and Erenhot. The Permian tectonic units can be divided into continental rift belt, ophiolite belt, alkaline rock belt and "red sea"-like ocean basin, which indicates an continuous extension environment during the Permian. The continental rift belt is composed of thick continental sedimentary rocks containing plant fossils, biomodal volcanic rocks (270-290Ma). The alkaline rocks can be divided into north and south belts by their distribution. The Solonker ophiolite is a thrust sheet that is inserted in a thrust stack containing the Upper Carboniferious epeiric sea clastic rocks and carbornates. The "red sea"-like ocean basin is characterized by basalt sequences with ages of 246-260Ma, which shows an affinity to E-MORB and a tendency towards OIB.

Bedrock geologic map of the Littleton and Lower Waterford quadrangles, Essex and Caledonia Counties, Vermont, and Grafton County, New Hampshire

USGS Publications Warehouse

Rankin, Douglas W.

2018-06-13

The bedrock geologic map of the Littleton and Lower Waterford quadrangles covers an area of approximately 107 square miles (277 square kilometers) north and south of the Connecticut River in east-central Vermont and adjacent New Hampshire. This map was created as part of a larger effort to produce a new bedrock geologic map of Vermont through the collection of field data at a scale of 1:24,000. A large part of the map area consists of the Bronson Hill anticlinorium, a post-Early Devonian structure that is cored by metamorphosed Cambrian to Devonian sedimentary, volcanic, and plutonic rocks. The northwestern part of the map is divided by the Monroe fault which separates Early Devonian rocks of the Connecticut Valley-Gaspé trough from rocks of the Bronson Hill anticlinorium.The Bronson Hill anticlinorium is the apex of the Middle Ordovician to earliest-Silurian Bronson Hill magmatic arc that contains the Ammonoosuc Volcanics, Partridge Formation, and Oliverian Plutonic suite, and extends from Maine, down the eastern side of the Connecticut River in New Hampshire, to Long Island Sound. The deformed and partially eroded arc is locally overlain by a relatively thin Silurian section of metasedimentary rocks (Clough Quartzite and Fitch Formation) that thickens to the east. The Silurian section near Littleton is disconformably overlain by a thicker, Lower Devonian section that includes mostly metasedimentary rocks and minor metavolcanic rocks of the Littleton Formation. The Bronson Hill anticlinorium is bisected by a series of northeast-southwest trending Mesozoic normal faults. Primarily among them is the steeply northwest-dipping Ammonoosuc fault that divides older and younger units (upper and lower sections) of the Ammonoosuc Volcanics. The Ammonoosuc Volcanics are lithologically complex and predominantly include interlayered and interfingered rhyolitic to basaltic volcanic and volcaniclastic rocks, as well as lesser amounts of metamorphic and metasedimentary rocks. The Ammonoosuc Volcanics overlies the Albee Formation that consists of interlayered feldspathic sandstone, siltstone, pelite, and slate.During the Late Ordovician, a series of arc-related plutons intruded the Ammonoosuc Volcanics, including the Whitefield pluton to the east, the Scrag granite of Billing (1937) in the far southeastern corner of the map, the Highlandcroft Granodiorite just to the west of the Ammonoosuc fault, and the Joslin Turn tonalite (just north of the Connecticut River). To the east of the Monroe fault lies the late Silurian Comerford Intrusive Complex, which consists of metamorphosed gabbro, diorite, tonalite, aplitic tonalite, and crosscutting diabase dikes. Abundant mafic dikes of the Comerford Intrusive Complex intruded the Albee Formation and Ammonoosuc Volcanics well east of the Monroe fault.This report consists of a single geologic map sheet and an online geographic information systems database that includes contacts of bedrock geologic units, faults, outcrops, and structural geologic information.

Sedimentology of gas-bearing Devonian shales of the Appalachian Basin

NASA Astrophysics Data System (ADS)

Potter, P. E.; Maynard, J. B.; Pryor, W. A.

1981-01-01

Sedimentology of the Devonian shales and its relationship to gas, oil, and uranium are reported. Information about the gas bearing Devonian shales of the Appalachian Basin is organized in the following sections: paleogeography and basin analysis; lithology and internal stratigraphy; paleontology; mineralogy, petrology, and chemistry; and gas oil, and uranium.

Emsian synorogenic paleogeography of the Maine Applachians

USGS Publications Warehouse

Bradley, D.; Tucker, R.

2002-01-01

The Acadian deformation front in the northern Appalachians of Maine and New Hampshire can now be closely located during the early Emsian (Early Devonian; 408-406 Ma). Tight correlations between paleontologically and isotopically dated rocks are possible only because of a new 408-Ma time scale tie point for the early Emsian. The deformation front lay between a belt of Lower Devonian flysch and molasse that were deposited in an Acadian foreland basin and had not yet been folded and a belt of early Emsian plutons that intruded folded Lower Devonian rocks. This plutonic belt includes the newly dated Ore Mountain gabbro (U/Pb; 406 Ma), which hosts magmatic-sulfide mineralization. Along the deformation front, a 407-Ma pluton that locally truncates Acadian folds (Katahdin) was the feeder to volcanic rocks (Traveler Rhyolite; 406-407 Ma) that are part of the foreland-basin succession involved in these same folds. The Emsian igneous rocks thus define a syncollisional magmatic province that straddled the deformation front. These findings bear on three alternative subduction geometries for the Acadian collision.

Thermal maturity patterns (conodont color alteration index and vitrinite reflectance) in Upper Ordovician and Devonian rocks of the Appalachian basin: a major revision of USGS Map I-917-E using new subsurface collections: Chapter F.1 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Repetski, John E.; Ryder, Robert T.; Weary, David J.; Harris, Anita G.; Trippi, Michael H.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

The conodont color alteration index (CAI) introduced by Epstein and others (1977) and Harris and others (1978) is an important criterion for estimating the thermal maturity of Ordovician to Mississippian rocks in the Appalachian basin. Consequently, the CAI isograd maps of Harris and others (1978) are commonly used by geologists to characterize the thermal and burial history of the Appalachian basin and to better understand the origin and distribution of oil and gas resources in the basin. The main objectives of this report are to present revised CAI isograd maps for Ordovician and Devonian rocks in the Appalachian basin and to interpret the geologic and petroleum resource implications of these maps. The CAI isograd maps presented herein complement, and in some areas replace, the CAI-based isograd maps of Harris and others (1978) for the Appalachian basin. The CAI data presented in this report were derived almost entirely from subsurface samples, whereas the CAI data used by Harris and others (1978) were derived almost entirely from outcrop samples. Because of the different sampling methods, there is little geographic overlap of the two data sets. The new data set is mostly from the Allegheny Plateau structural province and most of the data set of Harris and others (1978) is from the Valley and Ridge structural province, east of the Allegheny structural front (fig. 1). Vitrinite reflectance, based on dispersed vitrinite in Devonian black shale, is another important parameter for estimating the thermal maturity in pre-Pennsylvanian-age rocks of the Appalachian basin (Streib, 1981; Cole and others, 1987; Gerlach and Cercone, 1993; Rimmer and others, 1993; Curtis and Faure, 1997). This chapter also presents a revised percent vitrinite reflectance (%R0) isograd map based on dispersed vitrinite recovered from selected Devonian black shales. The Devonian black shales used for the vitrinite studies reported herein also were analyzed by RockEval pyrolysis and total organic carbon (TOC) content in weight percent. Although the RockEval and TOC data are included in this chapter (table 1), they are not shown on the maps. The revised CAI isograd and percent vitrinite reflectance isograd maps cover all or parts of Kentucky, New York, Ohio, Pennsylvania, Virginia, and West Virginia (fig. 1), and the following three stratigraphic intervals: Upper Ordovician carbonate rocks, Lower and Middle Devonian carbonate rocks, and Middle and Upper Devonian black shales. These stratigraphic intervals were chosen for the following reasons: (1) they represent target reservoirs for much of the oil and gas exploration in the Appalachian basin; (2) they are stratigraphically near probable source rocks for most of the oil and gas; (3) they include geologic formations that are nearly continuous across the basin; (4) they contain abundant carbonate grainstone-packstone intervals, which give a reasonable to good probability of recovery of conodont elements from small samples of drill cuttings; and (5) the Middle and Upper Devonian black shale contains large amounts of organic matter for RockEval, TOC, and dispersed vitrinite analyses. Thermal maturity patterns of the Upper Ordovician Trenton Limestone are of particular interest here, because they closely approximate the thermal maturity patterns in the overlying Upper Ordovician Utica Shale, which is the probable source rock for oil and gas in the Upper Cambrian Rose Run Sandstone (sandstone), Upper Cambrian and Lower Ordovician Knox Group (Dolomite), Lower and Middle Ordovician Beekmantown Group (dolomite or Dolomite), Upper Ordovician Trenton and Black River Limestones, and Lower Silurian Clinton/Medina sandstone (Cole and others, 1987; Jenden and others, 1993; Laughrey and Baldassare, 1998; Ryder and others, 1998; Ryder and Zagorski, 2003). The thermal maturity patterns of the Lower Devonian Helderberg Limestone (Group), Middle Devonian Onondaga Limestone, and Middle Devonian Marcellus Shale-Upper Devonian Rhine street Shale Member-Upper Devonian Ohio Shale are of interest, because they closely approximate the thermal maturity patterns in the Marcellus Shale, Upper Devonian Rhinestreet Shale Member, and Upper Devonian Huron Member of the Ohio Shale, which are the most important source rocks for oil and gas in the Appalachian basin (de Witt and Milici, 1989; Klemme and Ulmishek, 1991). The Marcellus, Rhinestreet, and Huron units are black-shale source rocks for oil and (or) gas in the Lower Devonian Oriskany Sandstone, the Upper Devonian sandstones, the Middle and Upper Devonian black shales, and the Upper Devonian-Lower Mississippian(?) Berea Sandstone (Patchen and others, 1992; Roen and Kepferle, 1993; Laughrey and Baldassare, 1998).

Precise U/Pb zircons dates of bentonites in Upper Ordovician and Lower Silurian reference sections in North America and Britain.

NASA Astrophysics Data System (ADS)

Suarez, S. E.; Brookfield, M. E.; Catlos, E. J.; Stockli, D. F.; Batchelor, R. A.

2016-12-01

The end of the Ordovician marks one of the greatest of the Earth's mass extinctions. One hypothesis explains this mass extinction as the result of a short-lived, major glaciation preceded by episodes of increased volcanism brought on by the Taconic orogeny. K-bentonites, weathered volcanic ash, provide evidence for increased volcanism. However, there is a lack of modern precise U-Pb dating of these ashes and some confusion in the biostratigraphy. The aim of this study is to obtain more precise U-Pb zircon ages from biostratigraphically constrained bentonites which will lead to better correlation of the Upper Ordovician and Lower Silurian relative time scales, as well as time the pulses of eruption. Zircon grains were extracted from the samples by heavy mineral separation and U-Pb dated using the Laser Ablation-Inductively Coupled Plasma-Mass Spectrometer at the University of Texas-Austin. We report here 3 precise U-Pb zircon ages from the Trenton Group, Ontario, Canada, and Dob's Linn, Scotland. The youngest age from the top of the Kirkfield Formation in Ontario is 448.0 +/- 18 Ma, which fits with existing late Ordovician stratigraphic ages. At Dob's Linn, Scotland, the site of the Ordovician/Silurian Global Boundary Stratigraphic Section and Point (GSSP), the youngest age for DL7, a bentonite 5 meters below the GSSP is 402.0 +/- 12.0 Ma, and for DL24L, a bentonite 8 meters above the GSSP is 358.2 +/- 7.9 Ma. These are Devonian ages in current timescales - the current age for the GSSP is 443.8 +/- 1.8 Ma, based on an U/Pb dates from a bentonite 1.6 meters above the GSSP at Dob's Linn. We are confident that our techniques rule out contamination and the most likely explanation is that the small zircons we analyzed either suffered Pb loss, or grew overgrowths during low grade hydrothermal metamorphism of the sediments during the intrusion of the Southern Upland Devonian granites during the Caledonian orogeny. These Devonian ages suggest that the 443.8 +/- 1.8 Ma age may also be suspect. The Dob's Linn site is therefore unsuitable for calibrating the biostratigraphic horizons. Work in progress will provide more U-Pb dating of bentonites from around the Ordovician-Silurian boundary in Canada, United States, Britain and Scandinavia with the aim of calibrating the local series and stages in order to help in International correlations.

The Grand St Bernard-Briançonnais Nappe System and the Paleozoic Inheritance of the Western Alps Unraveled by Zircon U-Pb Dating

NASA Astrophysics Data System (ADS)

Bergomi, M. A.; Dal Piaz, G. V.; Malusà, M. G.; Monopoli, B.; Tunesi, A.

2017-12-01

The continental crust involved in the Alpine orogeny was largely shaped by Paleozoic tectono-metamorphic and igneous events during oblique collision between Gondwana and Laurussia. In order to shed light on the pre-Alpine basement puzzle disrupted and reamalgamated during the Tethyan rifting and the Alpine orogeny, we provide sensitive high-resolution ion microprobe U-Pb zircon and geochemical whole rock data from selected basement units of the Grand St Bernard-Briançonnais nappe system in the Western Alps and from the Penninic and Lower Austroalpine units in the Central Alps. Zircon U-Pb ages, ranging from 459.0 ± 2.3 Ma to 279.1 ± 1.1 Ma, provide evidence of a complex evolution along the northern margin of Gondwana including Ordovician transtension, Devonian subduction, and Carboniferous-to-Permian tectonic reorganization. Original zircon U-Pb ages of 371 ± 0.9 Ma and 369.3 ± 1.5 Ma, from calc-alkaline granitoids of the Grand Nomenon and Gneiss del Monte Canale units, provide the first compelling evidence of Late Devonian orogenic magmatism in the Alps. We propose that rocks belonging to these units were originally part of the Moldanubian domain and were displaced toward the SW by Late Carboniferous strike-slip faulting. The resulting assemblage of basement units was disrupted by Permian tectonics and by Mesozoic opening of the Alpine Tethys. Remnants of the Moldanubian domain became either part of the European paleomargin (Grand Nomenon unit) or part of the Adriatic paleomargin (Gneiss del Monte Canale unit), to be finally accreted into the Alpine orogenic wedge during the Cenozoic.

Reported middle Paleozoic fossils and new geochronological data from the southern and central Appalachians: Disposable outrageous hypothesis or justification for major revision of tectonic history

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hatcher, R.D. Jr.

Recently published interpretations of fossil fragments from the Walden Creek Group (Ocoee Supergroup) suggesting that these rocks are middle Paleozoic (Devonian to Early Carboniferous), and new geochronological data that yield late Paleozoic age dates on rocks and major faults in the Blue Ridge and piedmont, if taken alone, would permit speculation that most of the deformation and metamorphism affecting this part of the orogen is Alleghanian. The two Ordovician clastic wedges (Sevier, Llanvirn, and Martinsburg, Caradoc-Ashgill) and the Carboniferous-Permian wedge(s), along with many radiometric ages on plutons, indicate uplift and sediment dispersal from the interior of the southern and centralmore » Appalachians (SCA) that may have resulted from Taconian and Alleghanian deformation. Combining the reproducible fossil evidence, including that from Alabama and a recently discovered crinoid fragment from the upper part of the Murphy belt sequence, with the most current geochronological data requires that peak metamorphism and penetrative deformation be at least Devonian or younger at the southwestern end of the orogen, and Late Ordovician or younger in the Carolinas and northern Georgia. Zircon ages reported from large thrust and dextral strike-slip faults bounding the Pine Mountain window indicate all of the faults there may be Alleghanian, except the younger sinistral Mesozoic faults, and requires that both metamorphism and penetrative deformation there also be Alleghanian. As in New England, the southern Appalachian Alleghanian metamorphic core is now known to be much more extensive. The older data require that the Taconian and perhaps the Acadian orogenies were significant events in the SCA, but these new data reconfirm the dominance of Alleghanian continent-continent collision processes here.« less

Geochemistry and tectonostratigraphy of the basal allochthonous units of SW Iberia (Évora Massif, Portugal): Keys to the reconstruction of pre-Pangean paleogeography in southern Europe

NASA Astrophysics Data System (ADS)

Fernández, Rubén Díez; Fuenlabrada, José Manuel; Chichorro, Martim; Pereira, M. Francisco; Sánchez-Martínez, Sonia; Silva, José B.; Arenas, Ricardo

2017-01-01

The basal allochthonous units of NW and SW Iberia are members of an intra-Gondwana suture zone that spreads across the Iberian Massif and was formed during the collision of Gondwana and Laurussia in the late Paleozoic. This suture zone is made of allochthonous terranes and is currently preserved as a tectonically dismembered ensemble. A multi-proxy analysis is applied to the basal allochthonous units of Iberia to test their affinity and potential usage for tracing a suture zone. A comparison of the lithostratigraphy, tectonometamorphic evolution, geochronology, and geochemical characteristics of the Ediacaran series of these units reveals striking affinities. They derive from rather similar immature sedimentary successions, deposited along the same continental margin, and in relation to a Cadomian magmatic arc. Sm-Nd systematics indicates that the isotopic sources are among the oldest of the Iberian Massif (ca. 2.15-1.5 Ga), suggesting a very strong contribution from the West African Craton. These Ediacaran series were affected by high-P and low- to medium-T metamorphism (blueschist to eclogite facies) during the Late Devonian (ca. 370 Ma). They occur below allochthonous ophiolitic sequences, and on top of autochthonous or parautochthonous domains lacking of high-P and low- to medium-T Devonian metamorphism, i.e., tectonically sandwiched between lithosphere-scale thrusts. The combination of all these characteristics makes these particular Ediacaran series different from the rest of the terranes of the Iberian Massif. Such singularity could be useful for tracing more occurrences of the same suture zone along the Variscan orogen, particularly in cases where its preservation and recognition may be cryptic. It also contributes to improve the paleogeographic reconstruction of the margin of Gondwana during the Ediacaran.

Reconstructing multiple arc-basin systems in the Altai-Junggar area (NW China): Implications for the architecture and evolution of the western Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Li, Di; He, Dengfa; Tang, Yong

2016-05-01

The Altai-Junggar area in northwestern China is a critical region to gain insights on the tectonic framework and geological evolution of the western Central Asian Orogenic Belt (CAOB). In this study, we report results from integrated geological, geochemical and geophysical investigations on the Wulungu Depression of the Junggar Basin to determine the basement nature of the basin and understand its amalgamation history with the Chinese Altai, within the broad tectonic evolution of the Altai-Junggar area. Based on borehole and seismic data, the Wulungu Depression is subdivided into two NW-trending tectonic units (Suosuoquan Sag and Hongyan High) by southward-vergent thrust faults. The Suosuoquan Sag consists of the Middle-Late Devonian basaltic andesite, andesite, dacite, tuff, tuffaceous sandstone and tuffite, and the overlying Early Carboniferous volcano-sedimentary sequence with lava flows and shallow marine sediments from a proximal juvenile provenance (zircon εHf(t) = 6.0-14.9), compared to the Late Carboniferous andesite and rhyolite in the Hongyan High. Zircon SIMS U-Pb ages for dacites and andesites indicate that these volcanics in the Suosuoquan Sag and Hongyan High erupted at 376.3 Ma and 313.4 Ma, respectively. The Middle-Late Devonian basaltic andesites from well LC1 are calc-alkaline and exhibit primitive magma-like MgO contents (7.9-8.6%) and Mg# values (66-68), with low initial 87Sr/86Sr (0.703269-0.704808) and positive εNd(t) values (6.6-7.6), and relatively high Zr abundance (98.2-116.0 ppm) and Zr/Y ratios (5.1-5.4), enrichment in LREEs and LILEs (e.g., Th and U) and depletion in Nb, Ta and Ti, suggesting that they were probably derived from a metasomatized depleted mantle in a retro-arc extensional setting. The well LC1 andesitic tuffs, well L8 dacites, well WL1 dacitic tuffs and well L5 andesites belong to calc-alkaline and metaluminous to peraluminous (A/CNK = 0.8-1.7) series, and display low Mg# values (35-46) and variably positive εNd(t) (4.5-8.5) and εHf(t) (10.2-16.8) values, as well as young isotopic model ages. These Devonian-Carboniferous intermediate-felsic volcanics are interpreted as the products of partial melting of a juvenile lower crust with some contributions from mantle components in an evolved island arc setting from immature to mature island arc. The basin filling pattern and the distribution of arc volcanics and their zircon Hf model ages with the eruptive time suggest that the Wulungu Depression represents an island arc-basin system with the development of a Carboniferous retro-arc basin. In combination with previous work, we propose that the northern Junggar area comprises three arc-basin belts from south to north: the Darbut-Luliang-Karamaili, Wulungu-Yemaquan, and Saur-Fuhai-Dulate. Such tectonic subdivisions are consistent with the regional gravity and magnetic anomaly data. The recognition of the Wulungu arc-basin system demonstrates that the Junggar Basin is likely underlain by juvenile continental crust rather than ancient Precambrian basement, and also implies that the CAOB was built by amalgamation of multiple linear arcs and accretionary complexes.

A Remaining Open Paleogeography of Paleo-Asian Ocean by Early Permian, Paleomagnetic Constraints from Eastern CAOB

NASA Astrophysics Data System (ADS)

Zhang, Donghai; Huang, Baochun; Zhao, Jie; Meert, Joseph; Zhang, Ye; Liang, Yalun; Bai, Qianhui; Zhao, Qian; Zhou, Tinghong

2017-04-01

We carry out a combined paleomagnetic and U-Pb geochronologic study on Paleozoic strata ranging from Lower Devonian to Upper Permian in mid-eastern Inner Mongolia, NE China with the purpose of puzzling out the timing and location of the final closure of Paleo-Asian Ocean (PAO), and thus provides further implications for the evolution of eastern Central Asian Orogenic Belt (CAOB). Inside North Margin of North China Block (NMNCB), 20 sites from Middle Permian Elitu formation and 9 sites from Lower Permian Sanmianjing formation yields a high temperature Characteristic Remanent Magnetism (ChRM) of Dg=330.9, Ig=54.3, Kg=4.9, a95g=14.9 N= 24 before and Ds=347.4, Is=38.1, Ks=28.6, a95s=5.6, N=24 after tilt correction. 13 sites from Songliao-Xilinhot Block (SXB) isolate a ChRM of Dg=196.6, Ig=36.4, Kg=18.0, a95g=11.1, N=13; Ds=222.9, Is=20.5, Ks=15.7 a95s=11.9, N=13 with a positive fold test, which suggests a likely primary magnetization. Inside of Khingan-Airgin Sum Block (KAB), 2 different component is extracted from Lower Devonian Niqiuhe formation, Upper Carboniferous Baoligaomiao formation and Lower Permian Dashizhai formation. A high temperature Component A (Dg=28.3, Ig=29.7, Kg=24.4, a95g=6.6, N= 21; Ds=49.8, Is=62.1, Ks=57.4, a95s=4.2, N=21) with a synfolding origin is derived from 21 sites of Baoligaomiao formation in west KAB, which is traditionally named as Uliastai passive continental margin, whilst 11 sites from Lower Devonian Niqiuhe formation in east KAB generate a post-folding Component B (Dg=196.6, Ig=36.4, Kg=18.0, a95g=11.1, N=11; Ds=222.9, Is=20.5, Ks=15.7, a95s=11.9, N=11) with a possible remagnetization in early Permian suggested by widely exposed granitic intrusion of 299 Ma in adjacent areas. Accordingly, 4 paleomagnetic poles are calculated as early-middle Permian of NMNCB (Plat=67.9°N, Plong=326.7°E, A95=4.2°), early Permian of SXB (Plat=45.3°N, Plong=250.3°E, A95=5.8°), late Carboniferous of west KAB (Plat=55.1°N, Plong=187.8°E, A95=6.2°) and early Permian of (Plat=-16.3°N, Plong=109.1°E, A95=8.4°). The early Permian paleomagnetic pole of SXB and NMNCB are located at a common small circle centered around the reference site (43° N, 114° E), whilst late Carboniferous pole of west KAB and early Permian pole of east KAB share a similar paleolatitude, about 17.8° higher than that of SXB and NMNCB, with a huge 85° longitudinal difference in between. These data indicate the final closure of PAO happened at the northern Hegenshan-Heihe Suture Zone (HHSZ) after early Permian instead of the pre-assumed southern Solonker-Xar Moron Suture Zone (SXMSZ) with a remaining open paleogeography of Paleo-Asian Ocean between SXB and KAB by early Permian. Keywords: Paleo-Asian Ocean, Central Asian Orogenic Belt, Paleomagnetism, Paleolatitude, Late Paleozoic, XMOB.

Late Paleozoic deformation and exhumation in the Sierras Pampeanas (Argentina): 40Ar/39Ar-feldspar dating constraints

NASA Astrophysics Data System (ADS)

Löbens, Stefan; Oriolo, Sebastián; Benowitz, Jeff; Wemmer, Klaus; Layer, Paul; Siegesmund, Siegfried

2017-09-01

Systematic 40Ar/39Ar feldspar data obtained from the Sierras Pampeanas are presented, filling the gap between available high- (> 300 °C) and low-temperature (< 150 °C) thermochronological data. Results show Silurian-Devonian exhumation related to the late stages of the Famatinian/Ocloyic Orogeny for the Sierra de Pocho and the Sierra de Pie de Palo regions, whereas the Sierras de San Luis and the Sierra de Comechingones regions record exhumation during the Carboniferous. Comparison between new and available data points to a Carboniferous tectonic event in the Sierras Pampeanas, which represents a key period to constrain the early evolution of the proto-Andean margin of Gondwana. This event was probably transtensional and played a major role during the evolution of the Paganzo Basin as well as during the emplacement of alkaline magmatism in the retroarc.

Carboniferous paleogeographic, phytogeographic, and paleoclimatic reconstructions

USGS Publications Warehouse

Rowley, D.B.; Raymond, A.; Parrish, Judith T.; Lottes, A.L.; Scotese, C.R.; Ziegler, A.M.

1985-01-01

Two revised paleogeographic reconstructions of the Visean and Westphalian C-D stages are presented based on recent paleomagnetic, phytogeographic, stratigraphic, and tectonic data. These data change the positions of some continental blocks, and allow the definition of several new ones. The most important modifications that have been incorporated in these reconstructions are: (1) a proposed isthmus linking North America and Siberia across the Bering Strait; and (2) the separation of China and Southeast Asia in six major blocks, including South China, North China, Shan Thai-Malaya, Indochina, Qangtang, and Tarim blocks. Evidence is presented that suggests that at least the South China, Shan Thai-Malaya, and Qangtang blocks were derived from the northern margin of Gondwana. Multivariate statistical analysis of phytogeographic data from the middle and late Paleozoic allow definition of a number of different phytogeographic units for four time intervals: (1) the Early Devonian, (2) Tournaisian-early Visean, (3) Visean, and (4) late Visean-early Namurian A. Pre-late Visean-early Namurian A floral assemblages from South China show affinities with northern Gondwana floras suggesting a southerly position and provides additional support for our reconstruction of South China against the northern margin of Gondwana. There is a marked decrease in the diversity of phytogeographic units in the Namurian and younger Carboniferous. This correlates closely with the time of assembly of most of Pangaea. The general pattern of Carboniferous phytogeographic units corresponds well with global distribution of continents shown on our paleogeographic reconstructions. In addition, we have constructed paleoclimatic maps for the two Carboniferous time intervals. These maps stress the distribution of rainfall, as this should be strongly correlated with the floras. There is marked change in the rainfall patterns between the Visean and Westphalian C-D. This change corresponds with the closing of the Appalachian-Ouachita ocean between Laurussia and Gondwana, and reflects the removal of a low-latitude moisture source that probably gave rise to monsoonal conditions along the northern margin of Gondwana in the Visean and earlier times. As well, the presence of a substantial heat source at high elevation in the Late Carboniferous significantly influenced the distribution of climatic belts. ?? 1986.

Patterns of Gondwana plant colonisation anddiversification

NASA Astrophysics Data System (ADS)

Anderson, J. M.; Anderson, H. M.; Archangelsky, S.; Bamford, M.; Chandra, S.; Dettmann, M.; Hill, R.; McLoughlin, S.; Rösler, O.

Charting the broad patterns of vascular plant evolution for Gondwana againstthe major global environmental shifts and events is attempted here for the first time. This is based on the analysis of the major vascular plant-bearing formations of the southern continents (plus India) correlated against the standard geological time-scale. Australia, followed closely by South America, are shown to yield by far the most complete sequences of productive strata. Ten seminal turnover pulses in the unfolding evolutionary picture are identified and seen to be linked to continental drift, climate change and mass global extinctions. The rise of vascular plants along the tropical belt, for instance, followed closely after the end-Ordovician warming and extinction. Equally remarkable is that the Late Devonian extinction may have caused both the terrestrialisation of the vertebrates and the origin of the true gymnosperms. The end-Permian extinction, closure of Iapetus, together with warming, appears to have set in motion an unparalleled, explosive, gymnosperm radiation; whilst the Late Triassic extinction dramatically curtailed it. It is suggested that the latitudinal diversity gradient clearly recognised today, where species richness increases towards the tropics, may have been partly reversed during phases of Hot House climate. Evidence hints at this being particularly so at the heyday of the gymnosperms in the Late Triassic super-Hot House world. As for the origin of terrestrial, vascular, plant life, the angiosperms seem closely linked to a phase of marked shift from Ice House to Hot House. Insect and tetrapod evolutionary patterns are discussed in the context of the plants providing the base of the ever-changing ecosystems. Intimate co-evolution is often evident. This isn't always the case, for example the non-linkage between the dominant, giant, long-necked, herbivorous sauropod dinosaurs and the dramatic radiation of the flowering plants in the Mid Cretaceous.

Zircon U-Pb geochronology, Sr-Nd isotope analyses, and petrogenetic study of the Dehnow diorite and Kuhsangi granodiorite (Paleo-Tethys), NE Iran

NASA Astrophysics Data System (ADS)

Karimpour, M. H.; Stern, C. R.; Farmer, G. L.

2010-03-01

The Paleo-Tethys ocean opened in Silurian time, and its subduction under the Turan plate started in the Late Devonian. By Late Triassic time (225 Ma), no Paleo-Tethys crust remained on the surface of the Iranian plate. Subsequently, however, obduction of the Turan plate over the Iranian plate emplaced allochthonous sheets in what is now northeastern Iran. The sheets contain meta-ophiolites, which have been dated at 281.4 and 277.4 Ma by the 40Ar- 39Ar method. These remnant Paleo-Tethys meta-ophiolites and associated metaflysch sequences were intruded by the Dehnow diorite and Kuhsangi granodiorite. Zircon U-Pb dating indicates that the age of the Kuhsangi granodiorite is 217 ± 4 Ma and that of the Dehnow diorite is 215 ± 4 Ma (Late Triassic, Norian). The granodiorite and diorite have magnetic susceptibilities of between 5 × 10 -5 and 20 × 10 -5 (SI units) and therefore are classified as belonging to the ilmenite series of reduced-type granitoids. Chemically, the Dehnow diorite and Kuhsangi granodiorite are moderately peraluminous S-type plutons with (La/Yb) N = 7-22 and no, or only small, negative Eu anomalies (Eu/Eu* = 0.55-1.1). Their initial 87Sr/ 86Sr ratios range from 0.707949 to 0.708589, and their initial ɛNd values range from -6.63 to -5.90 when recalculated to an age of 216 Ma. These values could be considered to represent continental crust-derived magmas, and metagreywacke to metapelite with initial ɛNd values of -15.01 may have been involved in their genesis, but these were not the sole parent material.

The problem of the age and structural position of the Blyb metamorphic complex (Fore Range zone, Great Caucasus) granitoids.

NASA Astrophysics Data System (ADS)

Kamzolkin, Vladimir; Latyshev, Anton; Ivanov, Stanislav

2016-04-01

The Blyb metamorphic complex (BMC) of the Fore Range zone is one of the most high-grade metamorphosed element of the Great Caucasus fold belt. Determination of the timing and the mechanism of formation of the Fore Range fold-thrust structures are not possible without investigation of the BMC located at the basement of its section. At the same time, the conceptions about its structure and age are outdated and need revision. Somin (2011) determined the age of the protolith and metamorphism of the Blyb complex as the Late Devonian - Early Carboniferous. We have recently shown that the BMC has not the dome, as previously thought, but nappe structure (Vidjapin, Kamzolkin, 2015), and is metamorphically coherent with the peak metamorphism pressures up to 22 kbar (Kamzolkin et al., 2015; Konilov et al., 2013). Considering the age and structure of the Blyb complex it is necessary to revise the age of granitoid intrusions and their relations with gneisses and schists, which constitute the main part of the section of the complex. Most authors (Gamkrelidze, Shengelia, 2007; Lavrischev, 2002; Baranov, 1967) adheres to Early Paleozoic age of intrusives, which is doubtful, considering the younger age of metamorphic rocks. We suppose, that the intrusive bodies broke through a BMC nappe structure during the exhumation of the complex (Perchuk, 1991) at the Devonian - Carboniferous boundary. Seemingly, the massive monzodiorites body (Lavrischev, 2002), intruding garnet-muscovite schists and amphibolite gneisses of the Blyb complex and cut by the Main Caucasian fault (MCF), are younger. Given the timing of termination of the MCF movement activity as the Middle Jurassic (Greater Caucasus..., 2005), their age should be in the Early Carboniferous - Middle Jurassic interval. At the same time, on the modern geological map (Lavrischev, 2002) monzodiorites body is assigned to the Middle Paleozoic. The study of the BMC granitoids and monzodiorites will help in determining of the mechanism and age of exhumation of the Blyb metamorphic complex high-pressure rocks. The reported study was partially supported by RFBR, research projects No. 16-35-00571mol_a; 16-05-01012a

Stage boundary recognition in the Eastern Americas realm based on rugose corals

USGS Publications Warehouse

Oliver, W.A.

2000-01-01

Most Devonian stages contain characteristic coral assemblages but these tend to be geographically and facies limited and may or may not be useful for recognising stage boundaries. Within eastern North America, corals contribute to the recognition of two boundaries: the base of the Lochkovian (Silurian-Devonian boundary) and the base of the Eifelian (Lower-Middle Devonian Series boundary).

Late paleozoic base and precious metal deposits, East Tianshan, Xinjiang, China: Characteristics and geodynamic setting

USGS Publications Warehouse

Mao, J.; Goldfarb, R.J.; Wang, Y.; Hart, C.J.; Wang, Z.; Yang, J.

2005-01-01

The East Tianshan is a remote Gobi area located in eastern Xinjiang, northwestern China. In the past several years, a number of gold, porphyry copper, and Fe(-Cu) and Cu-Ag-Pb-Zn skarn deposits have been discovered there and are attracting exploration interest. The East Tianshan is located between the Junggar block to the north and early Paleozoic terranes of the Middle Tianshan to the south. It is part of a Hercynian orogen with three distinct E-W-trending tectonic belts: the Devonian-Early Carboniferous Tousuquan-Dananhu island arc on the north and the Carboniferous Aqishan - Yamansu rift basin to the south, which are separated by rocks of the Kanggurtag shear zone. The porphyry deposits, dated at 322 Ma, are related to the late evolutionary stages of a subduction-related oceanic or continental margin arc. In contrast, the skarn, gold, and magmatic Ni-Cu deposits are associated with post-collisional tectonics at ca. 290-270 Ma. These Late Carboniferous - Early Permian deposits are associated with large-scale emplacement and eruption of magmas possibly caused by lithosphere delamination and rifting within the East Tianshan.

Palaeoecology and sedimentology of the dysaerobic Bedford fauna (late Devonian), Ohio and Kentucky (USA)

USGS Publications Warehouse

Pashin, J.C.; Ettensohn, F.R.

1992-01-01

Oxygen-deficient biofacies models rely on lithologic and paleontologic attributes to identify distinctive biofacies interpreted to reflect levels of oxygenation in anaerobic, dysaerobic, and aerobic parts of a stratified water column. This study of the Bedford fauna from the Bedford Shale of Ohio and Kentucky and from adjacent black-shale units reports faunal distributions different from those predicted by the accepted models. This study suggests that, although oxygenation was an important factor that determined the taxonomic makeup of the fauna, bacterially mediated nutrient recycling and substrate characteristics were more important than oxygenation in determining faunal distribution in the dysaerobic zone. ?? 1992.

Geologic map of the Bateman Spring Quadrangle, Lander County, Nevada

USGS Publications Warehouse

Ramelli, Alan R.; Wrucke, Chester T.; House, P. Kyle

2017-01-01

This 1:24,000-scale geologic map of the Bateman Spring 7.5-minute quadrangle in Lander County, Nevada contains descriptions of 24 geologic units and one cross section. Accompanying text includes full unit descriptions and references. This quadrangle includes lower Paleozoic siliciclastic sedimentary rocks of the Roberts Mountain allochthon, Miocene intrusive dikes, alluvial deposits of the northern Shoshone Range piedmont, and riverine deposits of the Reese and Humboldt rivers.Significant findings include: refined age estimates for the Ordovician-Cambrian Valmy Formation and Devonian Slaven Chert, based on new fossil information; and detailed mapping of late Quaternary fault traces along the Shoshone Range fault system.

Early Devonian (late Emsian) Brachiopods from Zhongping, Xiangzhou, central Guangxi, China

USGS Publications Warehouse

Chen, X.-Q.; Yao, Z.-G.

1999-01-01

The brachiopod fauna (20 species in 6 genera) from the Ma'anshan section of the Emsian Dale Formation at Zhongping, Xiangzhou county, central Guangxi is described. The fauna is dominated by spire-bearing brachiopods. One new genus and 4 new species are proposed: the smooth-shelled, septalium-bearing Lubricospirifer gumoensis gen. et sp. nov., Parathyrisina transitoria sp. nov., Acrospirifer shipengensis sp. nov. and Barbarothyris? luhuiensis sp. nov. Athyrisinoidea Chen and Wan 1980 is regarded as equating partly with Athyrisina partly with Parathyrisina. Excellence of preservation has provided an opportunity to present internal structure - obtained from serial sections - for 12 of the 20 species represented.

Climate signals in Palaeozoic land plants

PubMed Central

Edwards, D.

1998-01-01

The Palaeozoic is regarded as a period in which it is difficult to recognize climate signals in land plants because they have few or no close extant relatives. In addition early, predominantly axial, representatives lack the features, e.g. leaf laminae, secondary growth, used later as qualitative and quantitive measures of past climates. Exceptions are stomata, and the preliminary results of a case study of a single taxon present throughout the Devonian, and analysis of stomatal complex anatomy attempt to disentangle evolutionary, taxonomic, habitat and atmospheric effects on stomatal frequencies. Ordovician-Silurian vegetation is represented mainly by spores whose widespread global distribution on palaeocontinental reconstructions with inferred climates suggest that the producers were independent of major climate variables, probably employing the physiology and behavioural strategies of extant bryophytes, further characterized by small size. Growth-ring studies, first possible on Mid-Devonian plants, have proved most informative in elucidating the climate at high palaeolatitudes in Late Permian Gondwana. Changes in the composition of Carboniferous-Permian low-latitude wetland vegetation are discussed in relation to tectonic activity and glaciation, with most confidence placed on the conclusion that major extinctions at the Westphalian-Stephanian boundary in Euramerica resulted from increased seasonality created by changes in circulation patterns at low latitudes imposed by the decrease of glaciations in most parts of Gondwana.

New morphological information on, and species of placoderm fish Africanaspis (Arthrodira, Placodermi) from the Late Devonian of South Africa.

PubMed

Gess, Robert W; Trinajstic, Kate M

2017-01-01

Here we present a new species of placoderm fish, Africanaspis edmountaini sp. nov., and redescribe Africanaspis doryssa on the basis of new material collected from the type locality of Africanaspis. The new material includes the first head shields of Africanaspis doryssa in addition to soft anatomy for both taxa. Hitherto Africanaspis was entirely described from trunk armour and no record of body and fin outlines had been recorded. In addition the first record of embryonic and juvenile specimens of Africanaspis doryssa is presented and provides a growth series from presumed hatchlings to presumed adults. The presence of a greater number of juveniles compared to adults indicates that the Waterloo Farm fossil site in South Africa represents the first nursery site of arthrodire placoderms known from a cold water environment. The preservation of an ontogenetic series demonstrates that variation within the earlier known sample, initially considered to have resulted from ontogenetic change, instead indicates the presence of a second, less common species Africanaspis edmountaini sp. nov. There is some faunal overlap between the Waterloo Farm fossil site and faunas described from Strud in Belgium and Red Hill, Pennsylvania, in north America, supporting the concept of a more cosmopolitan vertebrate fauna in the Famennian than earlier in the Devonian.

New morphological information on, and species of placoderm fish Africanaspis (Arthrodira, Placodermi) from the Late Devonian of South Africa

PubMed Central

2017-01-01

Here we present a new species of placoderm fish, Africanaspis edmountaini sp. nov., and redescribe Africanaspis doryssa on the basis of new material collected from the type locality of Africanaspis. The new material includes the first head shields of Africanaspis doryssa in addition to soft anatomy for both taxa. Hitherto Africanaspis was entirely described from trunk armour and no record of body and fin outlines had been recorded. In addition the first record of embryonic and juvenile specimens of Africanaspis doryssa is presented and provides a growth series from presumed hatchlings to presumed adults. The presence of a greater number of juveniles compared to adults indicates that the Waterloo Farm fossil site in South Africa represents the first nursery site of arthrodire placoderms known from a cold water environment. The preservation of an ontogenetic series demonstrates that variation within the earlier known sample, initially considered to have resulted from ontogenetic change, instead indicates the presence of a second, less common species Africanaspis edmountaini sp. nov. There is some faunal overlap between the Waterloo Farm fossil site and faunas described from Strud in Belgium and Red Hill, Pennsylvania, in north America, supporting the concept of a more cosmopolitan vertebrate fauna in the Famennian than earlier in the Devonian. PMID:28379973

Late Ordovician (post-Sardic) rifting branches in the North Gondwanan Montagne Noire and Mouthoumet massifs of southern France

NASA Astrophysics Data System (ADS)

Javier Álvaro, J.; Colmenar, Jorge; Monceret, Eric; Pouclet, André; Vizcaïno, Daniel

2016-06-01

Upper Ordovician-Lower Devonian rocks of the Cabrières klippes (southern Montagne Noire) and the Mouthoumet massif in southern France rest paraconformably or with angular discordance on Cambrian-Lower Ordovician strata. Neither Middle-Ordovician volcanism nor associated metamorphism is recorded, and the subsequent Middle-Ordovician stratigraphic gap is related to the Sardic phase. Upper Ordovician sedimentation started in the rifting branches of Cabrières and Mouthoumet with deposition of basaltic lava flows and lahar deposits (Roque de Bandies and Villerouge formations) of continental tholeiite signature (CT), indicative of continental fracturing. The infill of both rifting branches followed with the onset of (1) Katian (Ka1-Ka2) conglomerates and sandstones (Glauzy and Gascagne formations), which have yielded a new brachiopod assemblage representative of the Svobodaina havliceki Community; (2) Katian (Ka2-Ka4) limestones, marlstones, and shales with carbonate nodules, reflecting development of bryozoan-echinoderm meadows with elements of the Nicolella Community (Gabian and Montjoi formations); and (3) the Hirnantian Marmairane Formation in the Mouthoumet massif that has yielded a rich and diverse fossil association representative of the pandemic Hirnantia Fauna. The sealing of the subaerial palaeorelief generated during the Sardic phase is related to Silurian and Early Devonian transgressions leading to onlapping patterns and the record of high-angle discordances.

Geologic map of the White Hall quadrangle, Frederick County, Virginia, and Berkeley County, West Virginia

USGS Publications Warehouse

Doctor, Daniel H.; Orndorff, Randall C.; Parker, Ronald A.; Weary, David J.; Repetski, John E.

2010-01-01

The White Hall 7.5-minute quadrangle is located within the Valley and Ridge province of northern Virginia and the eastern panhandle of West Virginia. The quadrangle is one of several being mapped to investigate the geologic framework and groundwater resources of Frederick County, Va., as well as other areas in the northern Shenandoah Valley of Virginia and West Virginia. All exposed bedrock outcrops are clastic and carbonate strata of Paleozoic age ranging from Middle Cambrian to Late Devonian. Surficial materials include unconsolidated alluvium, colluvium, and terrace deposits of Quaternary age, and local paleo-terrace deposits possibly of Tertiary age. The quadrangle lies across the northeast plunge of the Great North Mountain anticlinorium and includes several other regional folds. The North Mountain fault zone cuts through the eastern part of the quadrangle; it is a series of thrust faults generally oriented northeast-southwest that separate the Silurian and Devonian clastic rocks from the Cambrian and Ordovician carbonate rocks and shales. Karst development in the quadrangle occurs in all of the carbonate rocks. Springs occur mainly near or on faults. Sinkholes occur within all of the carbonate rock units, especially where the rocks have undergone locally intensified deformation through folding, faulting, or some combination.

Devonian-Carboniferous boundary succession in Eastern Taurides, Turkey

NASA Astrophysics Data System (ADS)

Atakul-Özdemir, Ayşe; Altıner, Demir; Özkan-Altıner, Sevinç

2015-04-01

The succession covering the Devonian-Carboniferous boundary in Eastern Taurides comprises mainly limestones, shales and siltstones. The studied section starts at the base with bioturbated limestones alternating with shales and is followed upwards by platy limestones, and continues with the alternations of bioturbated and platy limestones. Towards the upper part of the succession the alternations of limestone, shales and siltstones reappear again and the top of the section is capped by quartz arenitic sandstone. The studied section spanning the Uppermost Devonian-Lower Carboniferous interval yields a not very abundant, but quite important assemblage of conodont taxa including species of Bispathodus, Polygnathus, Palmatolepis, Spathognathodus and Vogelgnathus. The uppermost Devonian part of the succession is characterized by the presence of Bispathodus costatus, Bispathodus aculeatus aculeatus, Polygnathus communis communis, Palmatolepis gracilis gracilis and Spathognathodus sp.. The Lower Carboniferous in the studied section is represented by the appearance of Polygnathus inornatus and Polygnathus communis communis. Based on the recovered conodont assemblages, Devonian-Carboniferous boundary in Eastern Turides has been determined by the appearance and disappearance of major conodont species.

Linking Fossil Fish Cyclicity and Paleoenvironmental Proxies in the mid-Devonian

NASA Astrophysics Data System (ADS)

Grogan, D.; Whiteside, J. H.; Trewin, N. H.; Johnson, J. E.

2009-12-01

The significant radiation of fishes throughout the Devonian, combined with the abundance of well-preserved fossil fish assemblages from this period, provides for a high-resolution record of prevalent fish taxa in the Orcadian basin of North Scotland. In addition to their ability to serve as a lake-level and lake-chemistry proxy, the waxing and waning of dominant fish taxa exhibit a pronounced cyclicity, suggesting they respond to broader climate rhythms. Recent studies of mid-Devonian lacustrine sedimentary sequences have quantitatively demonstrated the presence of Milankovitch cyclicity in geochemical and gamma ray proxy records. Spectral analysis of gamma ray data show a strong obliquity peak usually associated with ice-house conditions; this obliquity signal is unexpected as tropical latitudes in the mid-Devonian are traditionally thought to have been in a greenhouse climate. Geochemical data include the measurement of bulk carbon and nitrogen stable isotopes, molecule-specific carbon isotopes of plant biomarkers, and depth ranks from eight sections of the Caithness Flagstone Group of the Orcadian Basin. Evidence for orbital forcing of climate change paired with the fossil fish record provides a unique opportunity to establish an astronomically calibrated timescale for the mid-Devonian, as well as to make a quantitative assessment of the validity of a greenhouse climate existing in the mid-Devonian.

Root evolution at the base of the lycophyte clade: insights from an Early Devonian lycophyte

PubMed Central

Matsunaga, Kelly K. S.; Tomescu, Alexandru M. F.

2016-01-01

Background and Aims The evolution of complex rooting systems during the Devonian had significant impacts on global terrestrial ecosystems and the evolution of plant body plans. However, detailed understanding of the pathways of root evolution and the architecture of early rooting systems is currently lacking. We describe the architecture and resolve the structural homology of the rooting system of an Early Devonian basal lycophyte. Insights gained from these fossils are used to address lycophyte root evolution and homology. Methods Plant fossils are preserved as carbonaceous compressions at Cottonwood Canyon (Wyoming), in the Lochkovian–Pragian (∼411 Ma; Early Devonian) Beartooth Butte Formation. We analysed 177 rock specimens and documented morphology, cuticular anatomy and structural relationships, as well as stratigraphic position and taphonomic conditions. Key Results The rooting system of the Cottonwood Canyon lycophyte is composed of modified stems that bear fine, dichotomously branching lateral roots. These modified stems, referred to as root-bearing axes, are produced at branching points of the above-ground shoot system. Root-bearing axes preserved in growth position exhibit evidence of positive gravitropism, whereas the lateral roots extend horizontally. Consistent recurrence of these features in successive populations of the plant preserved in situ demonstrates that they represent constitutive structural traits and not opportunistic responses of a flexible developmental programme. Conclusions This is the oldest direct evidence for a rooting system preserved in growth position. These rooting systems, which can be traced to a parent plant, include some of the earliest roots known to date and demonstrate that substantial plant–substrate interactions were under way by Early Devonian time. The morphological relationships between stems, root-bearing axes and roots corroborate evidence that positive gravitropism and root identity were evolutionarily uncoupled in lycophytes, and challenge the hypothesis that roots evolved from branches of the above-ground axial system, suggesting instead that lycophyte roots arose as a novel organ. PMID:26921730

Identification of remagnetization processes in Paleozoic sedimentary rocks of the northeast Rhenish Massif in Germany by K-Ar dating and REE tracing of authigenic illite and Fe oxides

NASA Astrophysics Data System (ADS)

Zwing, A.; Clauer, N.; Liewig, N.; Bachtadse, V.

2009-06-01

This study combines mineralogical, chemical (rare earth elemental (REE)) and isotopic (K-Ar) data of clay minerals as well as chemical compositions (major and REE) of Fe oxide leachates from remagnetized Palaeozoic sedimentary rocks from NE Rhenish Massif in Germany, for which the causes of remagnetization are not yet clear. The dominant carrier of the syntectonic, pervasive Carboniferous magnetization is magnetite. The Middle Devonian clastic rocks record an illitization event at 348 ± 7 Ma probably connected to a major magmatic event in the Mid-German Crystalline Rise, whereas a second illitization episode at 324 ± 3 Ma is coeval to the northward migrating deformation through the Rhenish Massif, being only detected in Upper Devonian and Lower Carboniferous rocks. The age of that younger illitization is not significantly different from that of the remagnetization, which, however, is not restricted to the upper part of the orogenic belt, but affects also the Middle Devonian strata. The REE patterns of the Fe-enriched leachates support two mineralization episodes with varied oxidation-reduction conditions outlined by varied Eu and Ce anomalies. This is not compatible with a unique, pervasive migration of orogenic fluids on a regional scale to explain the remagnetization in the studied region. While clay diagenesis and remagnetization are time-equivalent in Upper Devonian and Lower Carboniferous rocks, they are not so in Middle Devonian rocks. Transformation of smectite into illite cannot, therefore, account for the growth of associated authigenic magnetite, which must have been triggered by a different process. Since remagnetization and deformation ages are similar, the mechanism could relate to local physical conditions such as pressure solution and changing pore fluid pressure due to tectonic stress as well as to chemical conditions such as changing composition of the pore fluids.

Plate collision and mounting building separated by long periods of time. Possible causes

NASA Astrophysics Data System (ADS)

Artyushkov, Eugene; Chekhovich, Peter; Massonne, Hans-Joachim

2017-04-01

According to a popular scheme of orogenesis, superposition of thick nappe on continental crust results in concomitant mountain building. In many cases plate collision was not accompanied by mountain building which actually occurred 10-100 Myr later. Thus in East Carpathians 12 Ma ago thick nappe was superimposed on the western margin of the East European Craton. The nappe remained near to sea level and mountain building began only 3 myr ago. In the Middle Urals collision developed in a number of phases during 70 Myr since the Late Devonian and until the earliest Permian; however, this produced no high topography. The formation of orogenic granitoids took place at the main stage of collision 306-300 Ma ago. High mountains were formed in the earliest Permian 10 Myr after the end of collision. In the Northern Tien Shan collision with intrusion of large granitic plutons occurred in the Late Ordovician-Middle Devonian. In the Southern Tien Shan these phenomena refer to the Late Carboniferous and Late Jurassic. In both regions collision was not accompanied by mountain building. High mountains were formed in the Tien Shan quite recently. Shortening of strong lithospheric layer becomes possible only at short epochs of its softening under infiltration of fluids from the mantle. The absence of large uplift during shortening and thickening of the crust indicates a concomitant density increase in this layer. As follows from the analysis of typical phase diagrams of crustal rocks this can be explained by metamorphic reactions taking place in a presence of fluids under the pressure increase due to the nappe emplacement. As follows from the absence of large crustal uplift in shortened regions mantle lithosphere remains preserved in them after plate collision. At the epochs of infiltration from the mantle of large volumes of fluids it becomes softened. This ensures a possibility of convective replacement by the asthenosphere of fertile and dense mantle lithosphere of the Phanerozoic age which should result in a strong isostatic crustal uplift. Pronounced asthenospheric upwelling is indeed observed under high mountains in many Phanerozoic fold belts. New temperature distribution arises in the thickened crust after its shortening. As a result retrograde metamorphism with expansion became possible in dense rocks which underwent deep metamorphism at the preceding epochs of collision. This is another mechanism of mountain building. Analysis of the data on the Tien Shan shows that both these mechanisms are responsible for its uplift by 2 km and more during the last 2 Myr. In the gravity field the force acting along the lithospheric layer that necessary to shorten the crust increases with the altitude of topography. Termination of shortening after reaching only a very low altitude indicates that the forces which ensure collision are not large. They can be estimated as 3 × 1012 N m which is comparable with the plate driving force of ridge push.

A Systems Approach to Identifying Exploration and Development Opportunities in the Illinois Basin: Digital Portifolio of Plays in Underexplored Lower Paleozoic Rocks [Part 1 of 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seyler, Beverly; Harris, David; Keith, Brian

2008-06-30

This study examined petroleum occurrence in Ordovician, Silurian and Devonian reservoirs in the Illinois Basin. Results from this project show that there is excellent potential for additional discovery of petroleum reservoirs in these formations. Numerous exploration targets and exploration strategies were identified that can be used to increase production from these underexplored strata. Some of the challenges to exploration of deeper strata include the lack of subsurface data, lack of understanding of regional facies changes, lack of understanding the role of diagenetic alteration in developing reservoir porosity and permeability, the shifting of structural closures with depth, overlooking potential producing horizons,more » and under utilization of 3D seismic techniques. This study has shown many areas are prospective for additional discoveries in lower Paleozoic strata in the Illinois Basin. This project implemented a systematic basin analysis approach that is expected to encourage exploration for petroleum in lower Paleozoic rocks of the Illinois Basin. The study has compiled and presented a broad base of information and knowledge needed by independent oil companies to pursue the development of exploration prospects in overlooked, deeper play horizons in the Illinois Basin. Available geologic data relevant for the exploration and development of petroleum reservoirs in the Illinois Basin was analyzed and assimilated into a coherent, easily accessible digital play portfolio. The primary focus of this project was on case studies of existing reservoirs in Devonian, Silurian, and Ordovician strata and the application of knowledge gained to future exploration and development in these underexplored strata of the Illinois Basin. In addition, a review of published reports and exploration in the New Albany Shale Group, a Devonian black shale source rock, in Illinois was completed due to the recent increased interest in Devonian black shales across the United States. The New Albany Shale is regarded as the source rock for petroleum in Silurian and younger strata in the Illinois Basin and has potential as a petroleum reservoir. Field studies of reservoirs in Devonian strata such as the Geneva Dolomite, Dutch Creek Sandstone and Grassy knob Chert suggest that there is much additional potential for expanding these plays beyond their current limits. These studies also suggest the potential for the discovery of additional plays using stratigraphic concepts to develop a subcrop play on the subkaskaskia unconformity boundary that separates lower Devonian strata from middle Devonian strata in portions of the basin. The lateral transition from Geneva Dolomite to Dutch Creek Sandstone also offers an avenue for developing exploration strategies in middle Devonian strata. Study of lower Devonian strata in the Sesser Oil Field and the region surrounding the field shows opportunities for development of a subcrop play where lower Devonian strata unconformably overlie Silurian strata. Field studies of Silurian reservoirs along the Sangamon Arch show that opportunities exist for overlooked pays in areas where wells do not penetrate deep enough to test all reservoir intervals in Niagaran rocks. Mapping of Silurian reservoirs in the Mt. Auburn trend along the Sangamon Arch shows that porous reservoir rock grades laterally to non-reservoir facies and several reservoir intervals may be encountered in the Silurian with numerous exploration wells testing only the uppermost reservoir intervals. Mapping of the Ordovician Trenton and shallower strata at Centralia Field show that the crest of the anticline shifted through geologic time. This study illustrates that the axes of anticlines may shift with depth and shallow structure maps may not accurately predict structurally favorable reservoir locations at depth.« less

187Re - 187Os nuclear geochronometry: age dating with permil precision

NASA Astrophysics Data System (ADS)

Roller, Goetz

2016-04-01

Recently, 187Re - 187Os nuclear geochronometry, a new dating method combining ideas of nuclear astrophysics with geochronology, has successfully been used to calculate two-point-isochron (TPI) ages for Devonian black gas shales using the isotopic signature of an r-process geochronometer as one data point in a TPI diagram [1]. Based upon a nuclear production ratio 187Re/188Os = 5.873, TPI ages were calculated for 12 SDO-1 (Devonian Ohio Shale, Appalachian Basin) aliquants, for which repeated Re-Os measurements are reported in the literature [2]. TPI ages range from 384.5 ± 2.7 Ma (187Os/188Osi = 0.29413 ± 0.00023) to 387.7 ± 2.1 Ma (187Os/188Osi = 0.29407 ± 0.00019) with a mean of 386.67 ± 1.79 Ma). The result is consistent with the isochronous age from the 12 aliquants alone (386 ± 16 Ma, 187Os/188Osi = 0.31±0.31), which is bracketed by U-Pb ages for the Belpre Ash (381.1 ± 3.3 Ma) and the Tioga Ash bed (390.0 ± 2.5 Ma) [3] from the Appalachian Basin. Hence, SDO-1 can be assigned to the Givetian stage (varcus-zone) of the Middle Devonian, close to the Eifelian/Givetian boundary (using the time-scale of [3] or [4]). If an age is calculated from an isochron diagram for the 12 aliquants including the nuclear geochronometer, a permil precision can be achieved, an interesting feature with respect to any effort towards calibrating the Geologic Timescale. Additionally, a Th/U evolution (or: Th/U-time) diagram can be plotted using U-Pb zircon age data and Th/U ratios from volcanic rocks and ashes reported in the literature [3] for specific Devonian samples from the Appalachian Basin. Since the Re-Os age obtained for SDO-1 can also be connected to its Th/U ratio, it turns out, that Th/U ratios might be helpful age indicators, as demonstrated for the Devonian using the U-Pb and Re-Os datasets. [1] Roller (2015), GSA Abstr. with Programs 47, #248-14. [2] Du Vivier et al. (2014), Earth Planet. Sci. Lett. 389, 23 - 33. [3] Tucker et al. (1998), Earth Planet. Sci. Lett. 158, 175 - 186. [4] Kaufmann (2006), Earth-Sci. Revs. 76, 175 - 190.

Carbonate rocks of the Seward Peninsula, Alaska: Their correlation and paleogeographic significance

USGS Publications Warehouse

Dumoulin, Julie A.; Harris, Alta; Repetski, John E.

2014-01-01

Paleozoic carbonate strata deposited in shallow platform to off-platform settings occur across the Seward Peninsula and range from unmetamorphosed Ordovician–Devonian(?) rocks of the York succession in the west to highly deformed and metamorphosed Cambrian–Devonian units of the Nome Complex in the east. Faunal and lithologic correlations indicate that early Paleozoic strata in the two areas formed as part of a single carbonate platform. The York succession makes up part of the York terrane and consists of Ordovician, lesser Silurian, and limited, possibly Devonian rocks. Shallow-water facies predominate, but subordinate graptolitic shale and calcareous turbidites accumulated in deeper water, intraplatform basin environments, chiefly during the Middle Ordovician. Lower Ordovician strata are mainly lime mudstone and peloid-intraclast grainstone deposited in a deepening upward regime; noncarbonate detritus is abundant in lower parts of the section. Upper Ordovician and Silurian rocks include carbonate mudstone, skeletal wackestone, and coral-stromatoporoid biostromes that are commonly dolomitic and accumulated in warm, shallow to very shallow settings with locally restricted circulation. The rest of the York terrane is mainly Ordovician and older, variously deformed and metamorphosed carbonate and siliciclastic rocks intruded by early Cambrian (and younger?) metagabbros. Older (Neoproterozoic–Cambrian) parts of these units are chiefly turbidites and may have been basement for the carbonate platform facies of the York succession; younger, shallow- and deep-water strata likely represent previously unrecognized parts of the York succession and its offshore equivalents. Intensely deformed and altered Mississippian carbonate strata crop out in a small area at the western edge of the terrane. Metacarbonate rocks form all or part of several units within the blueschist- and greenschist-facies Nome Complex. The Layered sequence includes mafic meta¬igneous rocks and associated calcareous metaturbidites of Ordovician age as well as shallow-water Silurian dolostones. Scattered metacarbonate rocks are chiefly Cambrian, Ordovician, Silurian, and Devonian dolostones that formed in shallow, warm-water settings with locally restricted circulation and marbles of less constrained Paleozoic age. Carbonate metaturbidites occur on the northeast and southeast coasts and yield mainly Silurian and lesser Ordovician and Devonian conodonts; the northern succession also includes debris flows with meter-scale clasts and an argillite interval with Late Ordovician graptolites and lenses of radiolarian chert. Mafic igneous rocks at least partly of Early Devonian age are common in the southern succession. Carbonate rocks on Seward Peninsula experienced a range of deformational and thermal histories equivalent to those documented in the Brooks Range. Conodont color alteration indices (CAIs) from Seward Peninsula, like those from the Brooks Range, define distinct thermal provinces that likely reflect structural burial. Penetratively deformed high-pressure metamorphic rocks of the Nome Complex (CAIs ≥5) correspond to rocks of the Schist belt in the southern Brooks Range; both record subduction during early stages of the Jurassic–Cretaceous Brooks Range orogeny. Weakly metamorphosed to unmetamorphosed strata of the York terrane (CAIs mainly 2–5), like Brooks Range rocks in the Central belt and structural allochthons to the north, experienced moderate to shallow burial during the main phase of the Brooks Range orogeny. The nature of the contact between the York terrane and the Nome Complex is uncertain; it may be a thrust fault, an extensional surface, or a thrust fault later reactivated as an extensional fault. Lithofacies and biofacies data indicate that, in spite of their divergent Mesozoic histories, rocks of the York terrane and protoliths of the Nome Complex formed as part of the same lower Paleozoic carbonate platform. Stratigraphies in both

Reevaluating the age of the Walden Creek Group and the kinematic evolution of the western Blue Ridge, southern Appalachians

USGS Publications Warehouse

Thigpen, J. Ryan; Hatcher, Robert D.; Kah, Linda C.; Repetski, John E.

2016-01-01

An integrated synthesis of existing datasets (detailed geologic mapping, geochronologic, paleontologic, geophysical) with new paleontologic and geochemical investigations of rocks previously interpreted as part of the Neoproterozoic Walden Creek Group in southeastern Tennessee suggest a necessary reevaluation of the kinematics and structural architecture of the Blue Ridge Foothills. The western Blue Ridge of Tennessee, North Carolina, and Georgia is composed of numerous northwest-directed early and late Paleozoic thrust sheets, which record pronounced variation in stratigraphic/structural architecture and timing of metamorphism. The detailed spatial, temporal, and kinematic relationships of these rocks have remained controversial. Two fault blocks that are structurally isolated between the Great Smoky and Miller Cove-Greenbrier thrust sheets, here designated the Maggies Mill and Citico thrust sheets, contain Late Ordovician-Devonian conodonts and stable isotope chemostratigraphic signatures consistent with a mid-Paleozoic age. Geochemical and paleontological analyses of Walden Creek Group rocks northwest and southeast of these two thrust sheets, however, are more consistent with a Late Neoproterozoic (550–545 Ma) depositional age. Consequently, the structural juxtaposition of mid-Paleozoic rocks within a demonstrably Neoproterozoic-Cambrian succession between the Great Smoky and Miller Cove-Greenbrier thrust sheets suggests that a simple foreland-propagating thrust sequence model is not applicable in the Blue Ridge Foothills. We propose that these younger rocks were deposited landward of the Ocoee Supergroup, and were subsequently plucked from the Great Smoky fault footwall as a horse, and breached through the Great Smoky thrust sheet during Alleghanian emplacement of that structure.

Geology of the Cupsuptic quadrangle, Maine

USGS Publications Warehouse

Harwood, David S.

1966-01-01

The Cupsuptic quadrangle, in west-central Maine, lies in a relatively narrow belt of pre-Silurian rocks extending from the Connecticut River valley across northern New Hampshire to north-central Maine. The Albee Formation, composed of green, purple, and black phyllite with interbedded-quartzite, is exposed in the core of a regional anticlinorium overlain to the southeast by greenstone of the Oquossoc Formation which in turn is overlain by black slate of the Kamankeag Formation. In the northern part of the quadrangle the Albee Formation is overlain by black slate, feldspathic graywacke, and minor greenstone of the Dixville Formation. The Kamankeag Formation is dated as 1-ate Middle Ordovician by graptolites (zone 12) found near the base of the unit. The Dixville Formation is correlated with the Kamankeag Formation and Oquossoc Formation and is considered to be Middle Ordovician. The Albee Formation is considered to be Middle to Lower Ordovician from correlations with similar rocks in northeastern and southwestern Vermont. The Oquossoc and Kamankeag Formations are correlated with the Amonoosuc and Partridge Formations of northern New Hampshire. The pre-Silurian rocks are unconformably overlain by unnamed rocks of Silurian age in the southeast, west-central, and northwest ninths of the quadrangle. The basal Silurian units are boulder to cobble polymict conglomerate and quartz-pebble conglomerate of late Lower Silurian (Upper Llandovery) age. The overlying rocks are either well-bedded slate and quartzite, silty limestone, or arenaceous limestone. Thearenaceous limestone contains Upper Silurian (Lower Ludlow) brachiopods. The stratified rocks have been intruded by three stocks of biotite-muscovite quartz monzonite, a large body of metadiorite and associated serpentinite, smaller bodies of gabbro, granodiorite, and intrusive felsite, as well as numerous diabase and quartz monzonite dikes. The metadiorite and serpentinite, and possibly the gabbro and granodiorite are Late Ordovician in age. The quartz monzonite is considered to be Late Devonian. Five tectonic events are inferred from the structural features in the area. The earliest was a period of folding producing tightly-appressed, northeast-trending folds in the rocks of pre-Silurian age. In the second stage the folded pre-Silurian rocks were uplifted, eroded, and truncated to produce a major unconformity between the Middle Ordovician and Lower Silurian rocks. These events constitute the Taconic orogeny. The third tectonic event was a period of folding, probably of Middle Devonian age, that warped the unconformity and overlying rocks into open, gently-plunging, east-trending folds. This period of folding undoubtedly changed the attitude of the early folds in the pre-Silurian units but it did not produce any recognizable, cross-cutting planar features in the older rocks. The fourth tectonic event was a period of igneous intrusion that locally deformed the northeast-trending folds in the pre-Silurian rocks into a macroscopic drag fold plunging at 80 degrees in a direction S.10?w. A north-trending, subvertical slip cleavage was produced locally during this period of Late Devonian (?) deformation. A period of faulting, possibly of Triassic age, dislocated some of the earlier features. The rocks are in the chlorite zone of regional metamorphism, but have been contact metamorphosed to sillimanite-bearing hornfels adjacent to the quartz monzonite stocks. The chemical changes in chlorite, biotite, garnet, cordierite, and muscovite in the chlorite, biotite, andalusite, and sillimanite zones have been-studied by optical and x-ray methods and by partial chemical analyses. The progressive changes in mineral assemblages have been graphically portrayed on quaternary diagrams and ternary projections.

Geology and hydrocarbon potential of the Oued Mya Basin, Algeria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Benamrane, O.; Messaoudi, M.; Messelles, H.

1992-01-01

The hydrocarbon System Ourd Mya is located in the Sahara Basin. It is one of the producing basin in Algeria. The stratigraphic section consists of Paleozoic and Mesosoic, it is about 5000m thick. In the eastern part, the basin is limited by the Hassi-Messaoud high zone which is a giant oil field producing from the Cambrian sands. The western part is limited by Hassi R'mel which is one of the biggest gas field in the world, it is producing from the triassic sands. The Mesozoic section is laying on the lower Devonian and in the eastern part, on the Cambrian.more » The main source rock is the Silurian shale with an average thickness of 50m and a total organic matter of 6% (14% in some cases). Results of maturation modeling indicate that the lower Silurian source is in the oil window. The Ordovician shales are also a source rock, but in a second order. Clastic reservoirs are in the Triassic sequence which is mainly fluvial deposits with complex alluvial channels, it is the main target in the basin. Clastic reservoirs within the lower Devonian section have a good hydrocarbon potential in the east of the basin through a southwest-northeast orientation. The late Triassic-Early Jurassic evaporites overlie the Triassic clastic interval and extend over the entire Oued Mya Basin. This is considered as a super-seal evaporate package, which consists predominantly of anhydrite and halite. For Paleozoic targets, a large number of potential seals exist within the stratigraphic column. The authors infer that a large amount of the oil volume generated by the Silurian source rock from the beginning of Cretaceous until now, still not discovered could be trapped within structure closures and mixed or stratigraphic traps related to the fluvial Triassic sandstones, marine Devonian sands and Cambro-Ordovician reservoirs.« less

A newly discovered K-bentonite zone in the Lower Devonian of the Appalachian Basin; Basal Esopus and Needmore Formations (Late Pragian-Emsian)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ver Straeten, C.A.

1992-01-01

The K-bentonite-rich interval of the Esopus Formation (eastern New York and northeastern Pennsylvania) overlies the coeval Oriskany/Glenerie/Ridgely Formations and ranges from 1 to 6.3 m in thickness. Six to seventeen soapy-feeling, yellow, tan, green, or gray clay to claystone beds (0.001 to 0.5 m-thick) interbedded with thin siltstone and chert beds (0.02--1 m-thick) characterize outcrops in eastern New York. Heavy mineral separates from these layers yield abundant uncorraded euhedral zircons and apatites, indicating that these are K-bentonites. In eastern Pennsylvania, the westernmost outcrop of the Esopus Formation displays a 2.3 m-thick massive, soapy-feeling clay to claystone-dominated interval. The presence ofmore » both coarse, highly abraded and small, fragile, pristine-appearing zircons and apatites from a 20 cm sampled interval may indicate a complex amalgamation/reworking history to the relatively thick, clay-dominated strata. Similar clay/claystone-rich strata have been found in the lower 0.15 to 1 m of the Beaverdam Member (Needmore Formation) in central Pennsylvania. Interbedded clays and claystones with or without minor siltstone beds characterize some outcrops. Other localities are clay-dominated, with minor amounts of quartz sand present in strata immediately overlying the Ridgely Sandstone. These newly discovered K-bentonite-rich strata mark a transition from shelfal orthoquartzites and carbonates to basinal black/dark gray shales similar to the overlying Middle Devonian Tioga ash interval. Deposition of ash-rich strata, associated with increased volcanic activity, coincided with subsidence of the foreland basin/relative sea level rise. These events were concurrent with a flush of siliciclastic sediments into the basin and are indicative of the onset of an early tectophase of the Devonian Acadian Orogeny.« less

The formation of Pangea

NASA Astrophysics Data System (ADS)

Stampfli, G. M.; Hochard, C.; Vérard, C.; Wilhem, C.; vonRaumer, J.

2013-05-01

The making of Pangea is the result of large-scale amalgamation of continents and micro-continents, which started at the end of the Neoproterozoic with the formation of Gondwana. As pieces were added to Gondwana on its South-American, Antarctica and Australia side, ribbon-like micro-continents were detached from its African and South-Chinese side: Cadomia in the late Neoproterozoic, Avalonia and Hunia in the Ordovician, Galatia in the Devonian and Cimmeria in the Permian. Cadomia was re-accreted to Gondwana, but the other ribbon-continents were accreted to Baltica, North-China, Laurussia or Laurasia. Finding the origin of these numerous terranes is a major geological challenge. Recently, a global plate tectonic model was developed together with a large geological/geodynamic database, at the Lausanne University, covering the last 600 Ma of the Earth's history. Special attention was given to the placing of Gondwana derived terranes in their original position, using all possible constraints. We propose here a solution for the Variscan terranes, another paper deals with the Altaids. The Galatian super-terrane was detached from Gondwana in the Devonian, during the opening of Paleotethys, and was quickly separated into four sub-terranes that started to by-pass each other. The leading terranes collided at the end of the Devonian with the Hanseatic terrane detached from Laurussia. In the Carboniferous, Gondwana started to impinge onto the amalgamated terranes, creating the Variscan chain and the Pangean super-continent. East of Spain Paleotethys remained opened until the Triassic, subducting northward under Laurasia. Roll-back of the Paleotethyan slab triggered the collapse of most of the European Variscan orogen, which was replaced by series of Permian rifts, some of them becoming oceanized back-arc basins during the Triassic. Major force changes at the Pangean plate limits at the end of the Triassic provoked its break-up, through the opening of the proto-Caribbean, central-Atlantic, Alpine-Tethys oceanic seaways.

Assessment of Appalachian basin oil and gas resources: Devonian gas shales of the Devonian Shale-Middle and Upper Paleozoic Total Petroleum System: Chapter G.9 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Milici, Robert C.; Swezey, Christopher S.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

This report presents the results of a U.S. Geological Survey (USGS) assessment of the technically recoverable undiscovered natural gas resources in Devonian shale in the Appalachian Basin Petroleum Province of the eastern United States. These results are part of the USGS assessment in 2002 of the technically recoverable undiscovered oil and gas resources of the province. This report does not use the results of a 2011 USGS assessment of the Devonian Marcellus Shale because the area considered in the 2011 assessment is much greater than the area of the Marcellus Shale described in this report. The USGS assessment in 2002 was based on the identification of six total petroleum systems, which include strata that range in age from Cambrian to Pennsylvanian. The Devonian gas shales described in this report are within the Devonian Shale-Middle and Upper Paleozoic Total Petroleum System, which extends generally from New York to Tennessee. This total petroleum system is divided into ten assessment units (plays), four of which are classified as conventional and six as continuous. The Devonian shales described in this report make up four of these continuous assessment units. The assessment results are reported as fully risked fractiles (F95, F50, F5, and the mean); the fractiles indicate the probability of recovery of the assessment amount. The products reported are oil, gas, and natural gas liquids. The mean estimates for technically recoverable undiscovered hydrocarbons in the four gas shale assessment units are 12,195.53 billion cubic feet (12.20 trillion cubic feet) of gas and 158.91 million barrels of natural gas liquids

Study of hydrocarbon production from the Devonian shale in Letcher, Knott, Floyd, Martin, and Pike Counties, eastern Kentucky annual technical report, July 1, 1984-June 30, 1985

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frankie, W.T.

The Kentucky Geological Survey (KGS) at the University of Kentucky is conducting a 2-year research project funded by the Gas Research Institute (GRI) to study hydrocarbon production from the Devonian shale in eastern Kentucky. Objectives are to develop an understanding of relationships between stratigraphy and hydrocarbon production, create a data base, and prepare geologic reports for each county in the study area. Data were compiled from the KGS, GRI Eastern Gas Data System (EGDS), U. S. Department of Energy (DOE), and industry. Research for Letcher County was completed and 270 Devonian wells were entered into the KGS computer data base.more » Devonian black-shale units were correlated using gamma-ray logs. Structure and isopach maps, and stratigraphic cross sections have been constructed. An isopotential map defining areas of equal initial gas production has been prepared. Statistics for Letcher County have been run on the data base using Datatrieve software package. Statistical analyses focused on different types of formation treatments and the resulting production. Temperature logs were used to detect gas-producing intervals within the Mississippian-Devonian black-shale sequence. The results of the research provide the petroleum industry with a valuable tool for gas exploration in the Devonian shales.« less

Deep in shadows, deep in time: the oldest mesophotic coral ecosystems from the Devonian of the Holy Cross Mountains (Poland)

NASA Astrophysics Data System (ADS)

Zapalski, Mikołaj K.; Wrzołek, Tomasz; Skompski, Stanisław; Berkowski, Błażej

2017-09-01

Recent mesophotic coral ecosystems (MCE) occur at depths between 30 and 150 m and are characterized by dominance of platy corals. Such morphology is an effect of specific adaptation to efficient light harvesting. Here, we describe and analyze platy coral assemblages from two Middle Devonian localities in the Holy Cross Mountains (Poland) that during this time were located on the southern shelf of Laurussia at tropical latitudes. The Eifelian argillaceous sediments of Skały are dominated by platy and encrusting tabulate corals ( Roseoporella, Platyaxum and Alveolites). Coeval faunas from the shallow-water parts of the Holy Cross Mountains basin display bulbous and branching morphology, thus indicating a Paleozoic coral zonation similar to that known in the Recent. Hence, the Skały site seems to be the oldest known MCE (ca. 390 Ma). A Givetian biostrome from Laskowa Quarry is a second example dominated by platy corals, with abundant branching forms; this site can be recognized as another Devonian MCE. Frondescent Platyaxum, common at both sites, had a growth habit similar to that of Recent Leptoseris, Mycedium or Pavona. Platy morphology is photoadaptive and may evidence photosymbiosis in tabulate ( Alveolites, Roseoporella, Platyaxum) and rugose corals ( Phillipsastrea). Furthermore, it may serve as a tool for recognition of the lower euphotic zone in the fossil record.

Radon-222 content of natural gas samples from Upper and Middle Devonian sandstone and shale reservoirs in Pennsylvania—preliminary data

USGS Publications Warehouse

Rowan, E.L.; Kraemer, T.F.

2012-01-01

Samples of natural gas were collected as part of a study of formation water chemistry in oil and gas reservoirs in the Appalachian Basin. Nineteen samples (plus two duplicates) were collected from 11 wells producing gas from Upper Devonian sandstones and the Middle Devonian Marcellus Shale in Pennsylvania. The samples were collected from valves located between the wellhead and the gas-water separator. Analyses of the radon content of the gas indicated 222Rn (radon-222) activities ranging from 1 to 79 picocuries per liter (pCi/L) with an overall median of 37 pCi/L. The radon activities of the Upper Devonian sandstone samples overlap to a large degree with the activities of the Marcellus Shale samples.

Reevaluation of the Piermont-Frontenac allochthon in the Upper Connecticut Valley: Restoration of a coherent Boundary Mountains–Bronson Hill stratigraphic sequence

USGS Publications Warehouse

Rankin, Douglas W.; Tucker, Robert D.; Amelin, Yuri

2013-01-01

The regional extent and mode and time of emplacement of the Piermont-Frontenac allochthon in the Boundary Mountains–Bronson Hill anticlinorium of the Upper Connecticut Valley, New Hampshire–Vermont, are controversial. Moench and coworkers beginning in the 1980s proposed that much of the autochthonous pre–Middle Ordovician section of the anticlinorium was a large allochthon of Silurian to Early Devonian rocks correlated to those near Rangeley, Maine. This ∼200-km-long allochthon was postulated to have been transported westward in the latest Silurian to Early Devonian as a soft-sediment gravity slide on a hypothesized Foster Hill fault. New mapping and U-Pb geochronology do not support this interpretation. The undisputed Rangeley sequence in the Bean Brook slice is different from the disputed sequence in the proposed larger Piermont-Frontenac allochthon, and field evidence for the Foster Hill fault is lacking. At the type locality on Foster Hill, the postulated “fault” is a stratigraphic contact within the Ordovician Ammonoosuc Volcanics. The proposed Foster Hill fault would place the Piermont-Frontenac allochthon over the inverted limb of the Cornish(?) nappe, which includes the Emsian Littleton Formation, thus limiting the alleged submarine slide to post-Emsian time. Mafic dikes of the 419 Ma Comerford Intrusive Complex intrude previously folded strata attributed to the larger Piermont-Frontenac allochthon as well as the autochthonous Albee Formation and Ammonoosuc Volcanics. The Lost Nation pluton intruded and produced hornfels in previously deformed Albee strata. Zircons from an apophysis of the pluton in the hornfels have a thermal ionization mass spectrometry 207Pb/206Pb age of 444.1 ± 2.1 Ma. Tonalite near Bath, New Hampshire, has a zircon sensitive high-resolution ion microprobe 206Pb/238U age of 492.5 ± 7.8 Ma. The tonalite intrudes the Albee Formation, formerly interpreted as the Silurian Perry Mountain Formation of the proposed allochthon. Collectively, these features indicate that the large Piermont-Frontenac allochthon gravity slide of Silurian-Devonian strata, as previously proposed, cannot exist. Allochthonous rocks are restricted to a 25 km2 klippe, the Bean Brook slice, emplaced by hard-rock thrusting in the post-Emsian Devonian. The Albee Formation, the oldest unit in the study area, is older than the Late Cambrian tonalite at Bath. The correlation and apparent continuity along strike to the northeast of the Albee Formation with the Dead River Formation suggest that the Albee Formation, like the Dead River Formation, is of Ganderian affinity and that the Bronson Hill magmatic arc in the Upper Connecticut Valley was built on Ganderian crust. The Dead River Formation is unconformably overlain by Middle and Upper Ordovician volcanic units; the unconformity is attributed to the pre-Arenig Penobscottian orogeny. Some of the pre-Silurian deformation in the Upper Connecticut Valley may be Penobscottian rather than Taconian. New stratigraphic units defined herein include the pelitic Scarritt Member of the Albee Formation, the Ordovician Washburn Brook Formation consisting of synsedimentary breccia and coticule, chert, and ironstone, and the Devonian–Silurian Sawyer Mountain Formation, probably correlative with the Frontenac Formation. The Partridge Formation is partially coeval with the Ammonoosuc Volcanics.

Mineral and whole-rock compositions of seawater-dominated hydrothermal alteration at the Arctic volcanogenic massive sulfide prospect, Alaska

USGS Publications Warehouse

Schmidt, J.M.

1988-01-01

The Arctic volcanogenic massive sulfide prospect, located in the Ambler mineral district of northwestern Alaska, includes three types of hydrothermally altered rocks overlying, underlying, and interlayered with semimassive sulfide mineralization. Hydrothermal alteration of wall rocks and deposition of sulfide and gangue minerals were contemporaneous with Late Devonian of Early Mississippian basalt-rhyolite volcanism. Alteration developed asymmetrically around a linear fissure, suggesting fracture control of ore fluids rather than a point source. Microprobe analyses of phyllosilicates from the Arctic area indicate two discrete mineral populations. These differences in mineral chemistry are the result of differences in protolith composition caused by hydrothermal alteration-metasomatism. -from Author

Paleozoic and mesozoic evolution of East-Central California

USGS Publications Warehouse

Stevens, C.H.; Stone, P.; Dunne, G.C.; Greene, D.C.; Walker, J.D.; Swanson, B.J.

1997-01-01

East-central California, which encompasses an area located on the westernmost part of sialic North America, contains a well-preserved record of Paleozoic and Mesozoic tectonic events that reflect the evolving nature of the Cordilleran plate margin to the west. After the plate margin was formed by continental rifting in the Neoproterozoic, sediments comprising the Cordilleran miogeocline began to accumulate on the subsiding passive margin. In east-central California, sedimentation did not keep pace with subsidence, resulting in backstepping of a series of successive carbonate platforms throughout the early and middle Paleozoic. This phase of miogeoclinal development was brought to a close by the Late Devonian-Early Mississippian Antler orogeny, during the final phase of which oceanic rocks were emplaced onto the continental margin. Subsequent Late Mississippian-Pennsylvanian faulting and apparent reorientation of the carbonate platform margin are interpreted to have been associated with truncation of the continental plate on a sinistral transform fault zone. In the Early Permian, contractional deformation in east-central California led to the development of a narrow, uplifted thrust belt flanked by marine basins in which thick sequences of deep-water strata accumulated. A second episode of contractional deformation in late Early Permian to earliest Triassic time widened and further uplifted the thrust belt and produced the recently identified Inyo Crest thrust, which here is correlated with the regionally significant Last Chance thrust. In the Late Permian, about the time of the second contractional episode, extensional faulting created shallow sedimentary basins in the southern Inyo Mountains. In the El Paso Mountains to the south, deformation and plutonism record the onset of subduction and arc magmatism in late Early Permian to earliest Triassic time along this part of the margin. Tectonism had ceased in most of east-central California by middle to late Early Triassic time, and marine sediment deposited on the subsiding continental shelf overlapped the previously deformed Permian rocks. Renewed contractional deformation, probably in the Middle Triassic, is interpreted to be associated with emplacement of the Golconda allochthon onto the margin of the continent. This event, which is identified with certainty in the Sierra Nevada, also may have significantly affected rocks in the White and Inyo Mountains to the east. Subduction and arc magmatism that created most of the Sierra Nevada batholith began in the Late Triassic and lasted through the remainder of the Mesozoic. During this time, the East Sierran thrust system (ESTS) developed as a narrow zone of intense, predominantly E-vergent contractional deformation along the eastern margin of the growing batholith. Activity on the ESTS took place over an extended part of Mesozoic time, both before and after intrusion of voluminous Middle Jurassic plutons, and is interpreted to have been mechanically linked to emplacement of the batholith. Deformation on the ESTS and magmatism in the Sierra Nevada both ended prior to the close of the Cretaceous.

Late Proterozoic-Paleozoic evolution of the Arctic Alaska-Chukotka terrane based on U-Pb igneous and detrital zircon ages: Implications for Neoproterozoic paleogeographic reconstructions

USGS Publications Warehouse

Amato, J.M.; Toro, J.; Miller, E.L.; Gehrels, G.E.; Farmer, G.L.; Gottlieb, E.S.; Till, A.B.

2009-01-01

The Seward Peninsula of northwestern Alaska is part of the Arctic Alaska-Chukotka terrane, a crustal fragment exotic to western Laurentia with an uncertain origin and pre-Mesozoic evolution. U-Pb zircon geochronology on deformed igneous rocks reveals a previously unknown intermediate-felsic volcanic event at 870 Ma, coeval with rift-related magmatism associated with early breakup of eastern Rodinia. Orthogneiss bodies on Seward Peninsula yielded numerous 680 Ma U-Pb ages. The Arctic Alaska-Chukotka terrane has pre-Neoproterozoic basement based on Mesoproterozoic Nd model ages from both 870 Ma and 680 Ma igneous rocks, and detrital zircon ages between 2.0 and 1.0 Ga in overlying cover rocks. Small-volume magmatism occurred in Devonian time, based on U-Pb dating of granitic rocks. U-Pb dating of detrital zircons in 12 samples of metamorphosed Paleozoic siliciclastic cover rocks to this basement indicates that the dominant zircon age populations in the 934 zircons analyzed are found in the range 700-540 Ma, with prominent peaks at 720-660 Ma, 620-590 Ma, 560-510 Ma, 485 Ma, and 440-400 Ma. Devonian- and Pennsylvanian-age peaks are present in the samples with the youngest detrital zircons. These data show that the Seward Peninsula is exotic to western Laurentia because of the abundance of Neoproterozoic detrital zircons, which are rare or absent in Lower Paleozoic Cordilleran continental shelf rocks. Maximum depositional ages inferred from the youngest detrital age peaks include latest Proterozoic-Early Cambrian, Cambrian, Ordovician, Silurian, Devonian, and Pennsylvanian. These maximum depositional ages overlap with conodont ages reported from fossiliferous carbonate rocks on Seward Peninsula. The distinctive features of the Arctic Alaska-Chukotka terrane include Neoproterozoic felsic magmatic rocks intruding 2.0-1.1 Ga crust overlain by Paleozoic carbonate rocks and Paleozoic siliciclastic rocks with Neoproterozoic detrital zircons. The Neoproterozoic ages are similar to those in the peri-Gondwanan Avalonian-Cadomian arc system, the Timanide orogen of Baltica, and other circum-Arctic terranes that were proximal to Arctic Alaska prior to the opening of the Amerasian basin in the Early Cretaceous. Our Neoproterozoic reconstruction places the Arctic Alaska-Chukotka terrane in a position near Baltica, northeast of Laurentia, in an arc system along strike with the Avalonian-Cadomian arc terranes. Previously published faunal data indicate that Seward Peninsula had Siberian and Laurentian links by Early Ordovician time. The geologic links between the Arctic Alaska-Chukotka terrane and eastern Laurentia, Baltica, peri-Gondwanan arc terranes, and Siberia from the Paleoproterozoic to the Paleozoic help to constrain paleogeographic models from the Neoproterozoic history of Rodinia to the Mesozoic opening of the Arctic basin. ?? 2009 Geological Society of America.

Tectonic transition associated with Kazakhstan Orocline in the Late Paleozoic: magmatic archives of western Chinese Tianshan

NASA Astrophysics Data System (ADS)

Cai, Keda

2016-04-01

Kazakhstan accretionary system was a principle component of the Central Asian Orogenic Belt (CAOB) that is one of the largest accretionary orogens on earth. The Kazakhstan composite continent could have been established in the Early Paleozoic by the Kazakhstan accretionary system in the form of progressively amalgamations of diverse tectonic units, such as continental ribbon, accretionary prim, oceanic remnant and arc material. Subsequently, the composite continent was bended to form a spectacular U-shaped architecture that probably occurred in the Late Paleozoic. The western Chinese Tianshan is situated on the south wing of the Kazakhstan Orocline, featured by extensive magmatim, intense deformation and voluminous mineralization. Our new geochronological and geochemical data suggest a noticeable magmatic gap between Late Devonian and Early carboniferous and contrasting magma sources of these magmatic rocks. The significant shifts correspond to the tectonic transition from terrane amalgamation to mountain bending in the Early Paleozoic. This study was financially supported by the Major Basic Research Project of the Ministry of Science and Technology of China (2014CB448000), Xinjiang outstanding youth scientific grant (2013711003) and the Talent Awards to KDC from the China Government under the 1000 Talent Plan.

Concordant paleolatitudes for Neoproterozoic ophiolitic rocks of the Trinity Complex, Klamath Mountains, California

USGS Publications Warehouse

Mankinen, E.A.; Lindsley-Griffin, N.; Griffin, J.R.

2002-01-01

New paleomagnetic results from the eastern Klamath Mountains of northern California show that Neoproterozoic rocks of the Trinity ophiolitic complex and overlying Middle Devonian volcanic rocks are latitudinally concordant with cratonal North America. Combining paleomagnetic data with regional geologic and faunal evidence suggests that the Trinity Complex and related terranes of the eastern Klamath plate were linked in some fashion to the North American craton throughout that time, but that distance between them may have varied considerably. A possible model that is consistent with our paleomagnetic results and the geologic evidence is that the Trinity Complex formed and migrated parallel to paleolatitude in the basin between Laurasia and Australia-East Antarctica as the Rodinian supercontinent began to break up. It then continued to move parallel to paleolatitude at least through Middle Devonian time. Although the eastern Klamath plate served as a nucleus against which more western components of the Klamath Mountains province amalgamated, the Klamath superterrane was not accreted to North America until Early Cretaceous time.

Belowground rhizomes in paleosols: The hidden half of an Early Devonian vascular plant

NASA Astrophysics Data System (ADS)

Xue, Jinzhuang; Deng, Zhenzhen; Huang, Pu; Huang, Kangjun; Benton, Michael J.; Cui, Ying; Wang, Deming; Liu, Jianbo; Shen, Bing; Basinger, James F.; Hao, Shougang

2016-08-01

The colonization of terrestrial environments by rooted vascular plants had far-reaching impacts on the Earth system. However, the belowground structures of early vascular plants are rarely documented, and thus the plant-soil interactions in early terrestrial ecosystems are poorly understood. Here we report the earliest rooted paleosols (fossil soils) in Asia from Early Devonian deposits of Yunnan, China. Plant traces are extensive within the soil and occur as complex network-like structures, which are interpreted as representing long-lived, belowground rhizomes of the basal lycopsid Drepanophycus. The rhizomes produced large clones and helped the plant survive frequent sediment burial in well-drained soils within a seasonal wet-dry climate zone. Rhizome networks contributed to the accumulation and pedogenesis of floodplain sediments and increased the soil stabilizing effects of early plants. Predating the appearance of trees with deep roots in the Middle Devonian, plant rhizomes have long functioned in the belowground soil ecosystem. This study presents strong, direct evidence for plant-soil interactions at an early stage of vascular plant radiation. Soil stabilization by complex rhizome systems was apparently widespread, and contributed to landscape modification at an earlier time than had been appreciated.

Belowground rhizomes in paleosols: The hidden half of an Early Devonian vascular plant.

PubMed

Xue, Jinzhuang; Deng, Zhenzhen; Huang, Pu; Huang, Kangjun; Benton, Michael J; Cui, Ying; Wang, Deming; Liu, Jianbo; Shen, Bing; Basinger, James F; Hao, Shougang

2016-08-23

The colonization of terrestrial environments by rooted vascular plants had far-reaching impacts on the Earth system. However, the belowground structures of early vascular plants are rarely documented, and thus the plant-soil interactions in early terrestrial ecosystems are poorly understood. Here we report the earliest rooted paleosols (fossil soils) in Asia from Early Devonian deposits of Yunnan, China. Plant traces are extensive within the soil and occur as complex network-like structures, which are interpreted as representing long-lived, belowground rhizomes of the basal lycopsid Drepanophycus The rhizomes produced large clones and helped the plant survive frequent sediment burial in well-drained soils within a seasonal wet-dry climate zone. Rhizome networks contributed to the accumulation and pedogenesis of floodplain sediments and increased the soil stabilizing effects of early plants. Predating the appearance of trees with deep roots in the Middle Devonian, plant rhizomes have long functioned in the belowground soil ecosystem. This study presents strong, direct evidence for plant-soil interactions at an early stage of vascular plant radiation. Soil stabilization by complex rhizome systems was apparently widespread, and contributed to landscape modification at an earlier time than had been appreciated.

Belowground rhizomes in paleosols: The hidden half of an Early Devonian vascular plant

PubMed Central

Xue, Jinzhuang; Deng, Zhenzhen; Huang, Pu; Huang, Kangjun; Benton, Michael J.; Cui, Ying; Wang, Deming; Liu, Jianbo; Shen, Bing; Basinger, James F.; Hao, Shougang

2016-01-01

The colonization of terrestrial environments by rooted vascular plants had far-reaching impacts on the Earth system. However, the belowground structures of early vascular plants are rarely documented, and thus the plant−soil interactions in early terrestrial ecosystems are poorly understood. Here we report the earliest rooted paleosols (fossil soils) in Asia from Early Devonian deposits of Yunnan, China. Plant traces are extensive within the soil and occur as complex network-like structures, which are interpreted as representing long-lived, belowground rhizomes of the basal lycopsid Drepanophycus. The rhizomes produced large clones and helped the plant survive frequent sediment burial in well-drained soils within a seasonal wet−dry climate zone. Rhizome networks contributed to the accumulation and pedogenesis of floodplain sediments and increased the soil stabilizing effects of early plants. Predating the appearance of trees with deep roots in the Middle Devonian, plant rhizomes have long functioned in the belowground soil ecosystem. This study presents strong, direct evidence for plant−soil interactions at an early stage of vascular plant radiation. Soil stabilization by complex rhizome systems was apparently widespread, and contributed to landscape modification at an earlier time than had been appreciated. PMID:27503883

Geologic summary of the Appalachian Basin, with reference to the subsurface disposal of radioactive waste solutions

USGS Publications Warehouse

Colton, G.W.

1962-01-01

The Appalachian basin is an elongate depression in the crystalline basement complex< which contains a great volume of predominantly sedimentary stratified rocks. As defined in this paper it extends from the Adirondack Mountains in New York to central Alabama. From east to west it extends from the west flank of the Blue Ridge Mountains to the crest of the Findlay and Cincinnati arches and the Nashville dome. It encompasses an area of about 207,000 square miles, including all of West Virginia and parts of New York, New Jersey, Pennsylvania, Ohio, Maryland, Virginia, Kentucky, Tennessee, North Carolina, Georgia, and Alabama. The stratified rocks that occupy the basin constitute a wedge-shaped mass whose axis of greatest thickness lies close to and parallel to the east edge of the basin. The maximum thickness of stratified rocks preserved in any one part of the basin today is between 35,000 and 40,000 feet. The volume of the sedimentary rocks is approximately 510,000 cubic miles and of volcanic rocks is a few thousand cubic miles. The sedimentary rocks are predominantly Paleozoic in age, whereas the volcanic rocks are predominantly Late Precambrian. On the basis of gross lithology the stratified rocks overlying the crystalline basement complex can be divided into nine vertically sequential units, which are designated 'sequences' in this report. The boundaries between contiguous sequences do not necessarily coincide with the commonly recognized boundaries between systems or series. All sequences are grossly wedge shaped, being thickest along the eastern margin of the basin and thinnest along the western margin. The lowermost unit--the Late Precambrian stratified sequence--is present only along part of the eastern margin of the basin, where it lies unconformably on the basement complex. It consists largely of volcanic tuffs and flows but contains some interbedded sedimentary rocks. The Late Precambrian sequence is overlain by the Early Cambrian clastic sequence. Where the older sequence is absent, the Early Cambrian sequence rests on the basement complex. Interbedded fine- to coarse-grained noncarbonate detrital rocks comprise the bulk of the sequence, but some volcanic and carbonate rocks are included. Next above is the Cambrian-Ordovician carbonate sequence which consists largely of limestone and dolomite. Some quartzose sandstone is present in the lower part in the western half of the basin, and much shale is present in the upper part in the southeast part of the basin. The next higher sequence is the Late Ordovician clastic sequence, which consists largely of shale, siltstone, and sandstone. Coarse-grained light-gray to red rocks are common in the sequence along the eastern side of the basin, whereas fine-grained dark-gray to black calcareous rocks are common along the west side. The Late Ordovician clastic sequence is overlain--unconformably in many places--by the Early Silurian clastic sequence. The latter comprises a relatively thin wedge of coarse-grained clastic rocks. Some of the most prolific oil- and gas-producing sandstones in the Appalachian basin are included. Among these are the 'Clinton' sands of Ohio, the Medina Sandstones of New York and Pennsylvania, and the Keefer or 'Big Six' Sandstone of West Virginia and Kentucky. Conformably overlying the Early Silurian clastic sequence is the Silurian-Devonian carbonate sequence, which consists predominantly of limestone and dolomite. It also contains a salt-bearing unit in the north-central part of the basin and a thick wedge of coarse-grained red beds in the northeastern part. The sequence is absent in much of the southern part of the basin. Large volumes of gas and much oil are obtained from some of its rocks, especially from the Oriskany Sandstone and the Huntersville Chert. The Silurian-Devonian carbonate sequence is abruptly overlain by the Devonian clastic sequence--a thick succession of interbedded shale, mudrock, siltstone, and sandstone. Colors range f

Armorican provenance for the mélange deposits below the Lizard ophiolite (Cornwall, UK): evidence for Devonian obduction of Cadomian and Lower Palaeozoic crust onto the southern margin of Avalonia

NASA Astrophysics Data System (ADS)

Strachan, Rob A.; Linnemann, Ulf; Jeffries, Teresa; Drost, Kerstin; Ulrich, Jens

2014-07-01

Devonian sedimentary rocks of the Meneage Formation within the footwall of the Lizard ophiolite complex in SW England are thought to have been derived from erosion of the over-riding Armorican microplate during collision with Avalonia and the closure of the Rheic Ocean. We further test this hypothesis by comparison of their detrital zircon suites with those of autochthonous Armorican strata. Five samples analysed from SW England (Avalonia) and NW France (Armorica) have a bimodal U-Pb zircon age distribution dominated by late Neoproterozoic to middle Cambrian (c. 710-518 Ma) and Palaeoproterozoic (c. 1,800-2,200 Ma) groupings. Both can be linked with lithologies exposed within the Cadomian belt as well as the West African craton, which is characterized by major tectonothermal events at 2.0-2.4 Ga. The detrital zircon signature of Avalonia is distinct from that of Armorica in that there is a much larger proportion of Mesoproterozoic detritus. The common provenance of the samples is therefore consistent with: (a) derivation of the Meneage Formation mélange deposits from the Armorican plate during Rheic Ocean closure and obduction of the Lizard Complex and (b) previous correlation of quartzite blocks within the Meneage Formation with the Ordovician Grès Armoricain Formation of NW France.

Phanerozoic stratigraphy of Northwind Ridge, magnetic anomalies in the Canada Basin, and the geometry and timing of rifting in the Amerasia Basin, Arctic Ocean

USGS Publications Warehouse

Grantz, A.; Clark, D.L.; Phillips, R.L.; Srivastava, S.P.; Blome, C.D.; Gray, L.-B.; Haga, H.; Mamet, B.L.; McIntyre, D.J.; McNeil, D.H.; Mickey, M.B.; Mullen, M.W.; Murchey, B.I.; Ross, C.A.; Stevens, C.H.; Silberling, Norman J.; Wall, J.H.; Willard, D.A.

1998-01-01

Cores from Northwind Ridge, a high-standing continental fragment in the Chukchi borderland of the oceanic Amerasia basin, Arctic Ocean, contain representatives of every Phanerozoic system except the Silurian and Devonian systems. Cambrian and Ordovician shallow-water marine carbonates in Northwind Ridge are similar to basement rocks beneath the Sverdrup basin of the Canadian Arctic Archipelago. Upper Mississippian(?) to Permian shelf carbonate and spicularite and Triassic turbidite and shelf lutite resemble coeval strata in the Sverdrup basin and the western Arctic Alaska basin (Hanna trough). These resemblances indicate that Triassic and older strata in southern Northwind Ridge were attached to both Arctic Canada and Arctic Alaska prior to the rifting that created the Amerasia basin. Late Jurassic marine lutite in Northwind Ridge was structurally isolated from coeval strata in the Sverdrup and Arctic Alaska basins by rift shoulder and grabens, and is interpreted to be a riftogenic deposit. This lutite may be the oldest deposit in the Canada basin. A cape of late Cenomanian or Turonian rhyodacite air-fall ash that lacks terrigenous material shows that Northwind Ridge was structurally isolated from the adjacent continental margins by earliest Late Cretaceous time. Closing Amerasia basin by conjoining seafloor magnetic anomalies beneath the Canada basin or by uniting the pre-Jurassic strata of Northwind Ridge with kindred sections in the Sverdrup basin and Hanna trough yield simular tectonic reconstructions. Together with the orientation and age of rift-marine structures, these data suggest that: 1) prior to opening of the Amerasia basin, both northern Alaska and continental ridges of the Chukchi borderland were part of North America, 2) the extension that created the Amerasia basin formed rift-margin graben beginning in Early Jurassic time and new oceanic crust probably beginning in Late Jurassic or early Neocomian time. Reconstruction of the Amerasia basin on the basis of the stratigraphy of Northwind Ridge and sea-floor magnetic anomalies in the Canada basin accounts in a general way for the major crustal elements of the Americasia basin, including the highstanding ridges of the Chukchi borderland, and supports S.W. Carye's hypothesis that the Amerasia basin is the product of anticlockwise rotational rifting of Arctic Alaska from North America.

Devonian of the Northern Rocky Mountains and plains

USGS Publications Warehouse

Sandberg, Charles A.; Mapel, William J.

1967-01-01

5. Undivided uppermost Devonian (Famennian, to V-VI) and lowermost Mississippian (Tournaisian, cuI-lower cuIIα) carbonaceous and clastic rocks deposited in six shallow basins interspersed among areas uplifted during the penecontemporaneous Antler orogeny.

The Evolution of Land Plants and the Silicate Weathering Feedback

NASA Astrophysics Data System (ADS)

Ibarra, D. E.; Caves Rugenstein, J. K.; Bachan, A.; Baresch, A.; Lau, K. V.; Thomas, D.; Lee, J. E.; Boyce, C. K.; Chamberlain, C. P.

2017-12-01

It has long been recognized that the advent of vascular plants in the Paleozoic must have changed silicate weathering and fundamentally altered the long-term carbon cycle. Efforts to quantify these effects have been formulated in carbon cycle models that are, in part, calibrated by weathering studies of modern plant communities. In models of the long-term carbon cycle, plants play a key role in controlling atmospheric CO2, particularly in the late Paleozoic. We test the impact of some established and recent theories regarding plant-enhanced weathering by coupling a one-dimensional vapor transport model to a reactive transport model of silicate weathering. In this coupled model, we evaluate consequences of plant evolutionary innovation that have not been mechanistically incorporated into most existing models: 1) the role of evolutionary shifts in plant transpiration in enhancing silicate weathering by increasing downwind transport and recycling of water vapor to continental interiors; 2) the importance of deeply-rooted plants and their associated microbial communities in increasing soil CO2 and weathering zone length scales; and, 3) the cumulative effect of these processes. Our modeling approach is framed by energy/supply constraints calibrated for minimally vegetated-, vascular plant forested-, and angiosperm-worlds. We find that the emergence of widespread transpiration and associated inland vapor recycling approximately doubles weathering solute concentrations when deep-rooted vascular plants (Devonian-Carboniferous) fully replace a minimally vegetated (pre-Devonian) world. The later evolution of angiosperms (Cretaceous and Cenozoic) and subsequent increase in transpiration fluxes increase weathering solute concentrations by approximately an additional 20%. Our estimates of the changes in weatherability caused by land plant evolution are of a similar magnitude, but explained with new process-based mechanisms, than those used in existing carbon cycle models. We suggest a feedback where the increase in solute concentrations is compensated by a decrease in runoff and temperature, permitting lower steady-state atmospheric pCO2. Consequently, plants have increased the strength of the climatic feedback on silicate weathering since the late Paleozoic.

From body scale ontogeny to species ontogeny: Histological and morphological assessment of the Late Devonian acanthodian Triazeugacanthus affinis from Miguasha, Canada

PubMed Central

2017-01-01

Growth series of Palaeozoic fishes are rare because of the fragility of larval and juvenile specimens owing to their weak mineralisation and the scarcity of articulated specimens. This rarity makes it difficult to describe early vertebrate growth patterns and processes in extinct taxa. Indeed, only a few growth series of complete Palaeozoic fishes are available; however, they allow the growth of isolated elements to be described and individual growth from these isolated elements to be inferred. In addition, isolated and in situ scales are generally abundant and well-preserved, and bring information on (1) their morphology and structure relevant to phylogenetic relationships and (2) individual growth patterns and processes relative to species ontogeny. The Late Devonian acanthodian Triazeugacanthus affinis from the Miguasha Fossil-Lagerstätte preserves one of the best known fossilised ontogenies of early vertebrates because of the exceptional preservation, the large size range, and the abundance of complete specimens. Here, we present morphological, histological, and chemical data on scales from juvenile and adult specimens (scales not being formed in larvae). Histologically, Triazeugacanthus scales are composed of a basal layer of acellular bone housing Sharpey’s fibers, a mid-layer of mesodentine, and a superficial layer of ganoine. Developmentally, scales grow first through concentric addition of mesodentine and bone around a central primordium and then through superposition of ganoine layers. Ontogenetically, scales form first in the region below the dorsal fin spine, then squamation spreads anteriorly and posteriorly, and on fin webs. Phylogenetically, Triazeugacanthus scales show similarities with acanthodians (e.g. “box-in-box” growth), chondrichthyans (e.g. squamation pattern), and actinopterygians (e.g. ganoine). Scale histology and growth are interpreted in the light of a new phylogenetic analysis of gnathostomes supporting acanthodians as stem chondrichthyans. PMID:28403168

Sedimentology, conodonts and ostracods of the Devonian - Carboniferous strata of the Anseremme railway bridge section, Dinant Basin, Belgium

USGS Publications Warehouse

Casier, J.-G.; Mamet, B.; Preat, A.; Sandberg, C.A.

2004-01-01

Seven major carbonate microfacies are defined in the Devonian - Carboniferous (D/C) strata (50 m) of the Anseremme railway bridge section, south of Dinant. They permit recognition of several levels encompassing the Etroeungt and Hastie??re formations. "Bathymetric" sequences range from open marine, below the storm wave base, to semi-restricted lagoon. This sequence records a shallowing-upward trend of the relative sea level, from environments below the storm wave base to strongly eroded supraticial pre-evaporitic environments. Faunal components (echinoderms, brachiopods...) indicate open-marine domain for the first six microfacies located within the dysphoticeuphotic zone in relatively shallow waters. The textures of the rocks (mudstones to rudstones) associated with lamination characteristics indicate the position of the storm (SWB) and the fair-weather (FWWB) wave bases. Microfacies seven suggests a semi-restricted platform with salinity fluctuations from hypersaline brines to brackish waters. Thus, the boundary of the Etroeungt/Hastie??re formations is marked by an abrupt drop in sea level. Carbonate micro-conglomerates recording an important erosive phase and a sedimentary hiatus. The environment is again open marine in the upper part of the Hastie??re Formation. Our conclusion is that the Anseremme section is not a reliable continuous succession for the study of the D/C boundary. This confirms the VAN STEENWINKEL (1988, 1993 hypothesis based on other arguments. Conodont faunas demonstrate that the Devonian sequence spans the five youngest conodont zones, but that two of these zones are not represented. The Epinette Formation is dated as the youngest part of the Middle expansa Zone. Thus, the boundary with the Late praesulcata Zone probably coincides with the sharp sedimentological change at the base of the Etroeungt Formation, which is interpreted to belong entirely to this zone. The disconformably overlying basal bed 159 of the Hastie??re Formation is dated as Late praesulcata Zone, with the Early and Middle praesulcata Zones unrepresented because of an hiatus or unconformity. Sparse conodont faunas suggest that only the two next-to-oldest Carboniferous duplicata and sandbergi Zones are represented in the higher part of the Hastie??re Formation. The oldest Carboniferous sulcata Zone and possibly part ofthe duplicata Zone are unrepresented because of an hiatus or unconformity above bed 159. Ostracods are abundant and diversified at most levels in the Anseremme railway bridge section and sixty taxa, the majority in open nomenclature, have been identified and nearly all of them are figured. The ostracod fauna is indicative of shallow-marine environments between fair-weather and storm wave bases in the Etroeungt Formation, and to shallower water conditions periodically subjected to minor salinity variations in the base of the Hastie??re Formation. The upper part of the Hastie??re Formation is marked by a sea-level rise associated with a moderate decrease of the oxygenation of bottom waters. The intra-Devonian hiatus at the Etroeungt-Hastie??re boundary shows no abnormal extinctions and no appearance of new taxa. Thus, the Hangenberg Event is not recognizable in the studied section. Neither the sedimentological analysis nor the palaeontological study of the Bocahut quarry in the Avesnois and of the Anseremme railway bridge section confirm the hypothesis of a highstand for the Hastie??re Formation.

Root evolution at the base of the lycophyte clade: insights from an Early Devonian lycophyte.

PubMed

Matsunaga, Kelly K S; Tomescu, Alexandru M F

2016-04-01

The evolution of complex rooting systems during the Devonian had significant impacts on global terrestrial ecosystems and the evolution of plant body plans. However, detailed understanding of the pathways of root evolution and the architecture of early rooting systems is currently lacking. We describe the architecture and resolve the structural homology of the rooting system of an Early Devonian basal lycophyte. Insights gained from these fossils are used to address lycophyte root evolution and homology. Plant fossils are preserved as carbonaceous compressions at Cottonwood Canyon (Wyoming), in the Lochkovian-Pragian (∼411 Ma; Early Devonian) Beartooth Butte Formation. We analysed 177 rock specimens and documented morphology, cuticular anatomy and structural relationships, as well as stratigraphic position and taphonomic conditions. The rooting system of the Cottonwood Canyon lycophyte is composed of modified stems that bear fine, dichotomously branching lateral roots. These modified stems, referred to as root-bearing axes, are produced at branching points of the above-ground shoot system. Root-bearing axes preserved in growth position exhibit evidence of positive gravitropism, whereas the lateral roots extend horizontally. Consistent recurrence of these features in successive populations of the plant preserved in situ demonstrates that they represent constitutive structural traits and not opportunistic responses of a flexible developmental programme. This is the oldest direct evidence for a rooting system preserved in growth position. These rooting systems, which can be traced to a parent plant, include some of the earliest roots known to date and demonstrate that substantial plant-substrate interactions were under way by Early Devonian time. The morphological relationships between stems, root-bearing axes and roots corroborate evidence that positive gravitropism and root identity were evolutionarily uncoupled in lycophytes, and challenge the hypothesis that roots evolved from branches of the above-ground axial system, suggesting instead that lycophyte roots arose as a novel organ. © The Author 2016. Published by Oxford University Press on behalf of the Annals of Botany Company. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Early Paleozoic magmatic events in the eastern Klamath Mountains, northern California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wallin, E.T.; Mattinson, J.M.; Potter, A.W.

1988-02-01

New U-Pb zircon ages for nine samples of tonalite and pegmatitic trondhjemite from the Trinity ophiolite and associated melange reveal a complex history of magmatic activity extending back into the earliest Cambrian, much older than previously believed. Earlier investigations, based on limited data, recognized lower Paleozoic crustal elements in the eastern Klamath terrane (EKT) ranging in age from Middle Ordovician to Early to Middle Devonian. The new work in the Yreka-Callahan area of the EKT confirms the Ordovician (440-475 Ma) and younger ages, but reveals for the first time the presence of tonalitic rocks that crystallized during a narrow timemore » interval at about 565-570 Ma. The authors also recognize younger, Late Silurian magmatism at 412 Ma. In the context of available mapping, these ages indicate that the Trinity ophiolite is broadly polygenetic because parts of it yield crystallization ages that span approximately 150 m.y. Superjacent dismembered units of probable early Paleozoic age may be tectonostratigraphically equivalent to the Sierra City melange in the northern Sierra Nevada.« less

Improving global paleogeography since the late Paleozoic using paleobiology

NASA Astrophysics Data System (ADS)

Cao, Wenchao; Zahirovic, Sabin; Flament, Nicolas; Williams, Simon; Golonka, Jan; Dietmar Müller, R.

2017-12-01

Paleogeographic reconstructions are important to understand Earth's tectonic evolution, past eustatic and regional sea level change, paleoclimate and ocean circulation, deep Earth resources and to constrain and interpret the dynamic topography predicted by mantle convection models. Global paleogeographic maps have been compiled and published, but they are generally presented as static maps with varying map projections, different time intervals represented by the maps and different plate motion models that underlie the paleogeographic reconstructions. This makes it difficult to convert the maps into a digital form and link them to alternative digital plate tectonic reconstructions. To address this limitation, we develop a workflow to restore global paleogeographic maps to their present-day coordinates and enable them to be linked to a different tectonic reconstruction. We use marine fossil collections from the Paleobiology Database to identify inconsistencies between their indicative paleoenvironments and published paleogeographic maps, and revise the locations of inferred paleo-coastlines that represent the estimated maximum transgression surfaces by resolving these inconsistencies. As a result, the consistency ratio between the paleogeography and the paleoenvironments indicated by the marine fossil collections is increased from an average of 75 % to nearly full consistency (100 %). The paleogeography in the main regions of North America, South America, Europe and Africa is significantly revised, especially in the Late Carboniferous, Middle Permian, Triassic, Jurassic, Late Cretaceous and most of the Cenozoic. The global flooded continental areas since the Early Devonian calculated from the revised paleogeography in this study are generally consistent with results derived from other paleoenvironment and paleo-lithofacies data and with the strontium isotope record in marine carbonates. We also estimate the terrestrial areal change over time associated with transferring reconstruction, filling gaps and modifying the paleogeographic geometries based on the paleobiology test. This indicates that the variation of the underlying plate reconstruction is the main factor that contributes to the terrestrial areal change, and the effect of revising paleogeographic geometries based on paleobiology is secondary.

The astronomical rhythm of Late-Devonian climate change (Kowala section, Holy Cross Mountains, Poland)

NASA Astrophysics Data System (ADS)

De Vleeschouwer, David; Rakociński, Michał; Racki, Grzegorz; Bond, David P. G.; Sobień, Katarzyna; Claeys, Philippe

2013-03-01

Rhythmical alternations between limestone and shales or marls characterize the famous Kowala section, Holy Cross Mountains, Poland. Two intervals of this section were studied for evidence of orbital cyclostratigraphy. The oldest interval spans the Frasnian-Famennian boundary, deposited under one of the hottest greenhouse climates of the Phanerozoic. The youngest interval encompasses the Devonian-Carboniferous (D-C) boundary, a pivotal moment in Earth's climatic history that saw a transition from greenhouse to icehouse. For the Frasnian-Famennian sequence, lithological variations are consistent with 405-kyr and 100-kyr eccentricity forcing and a cyclostratigraphic floating time-scale is presented. The interpretation of observed lithological rhythms as eccentricity cycles is confirmed by amplitude modulation patterns in agreement with astronomical theory and by the recognition of precession cycles in high-resolution stable isotope records. The resulting relative time-scale suggests that ˜800 kyr separate the Lower and Upper Kellwasser Events (LKE and UKE, respectively), two periods of anoxia that culminated in massive biodiversity loss at the end of the Frasnian. Th/U and pyrite framboid analyses indicate that during the UKE, oxygen levels remained low for 400 kyr and δ13Corg measurements demonstrate that more than 600 kyr elapsed before the carbon cycle reached a steady state after a +3‰ UKE excursion. The Famennian-Tournaisian (D-C) interval also reveals eccentricity and precession-related lithological variations. Precession-related alternations clearly demonstrate grouping into 100-kyr bundles. The Famennian part of this interval is characterized by several distinctive anoxic black shales, including the Annulata, Dasberg and Hangenberg shales. Our high-resolution cyclostratigraphic framework indicates that those shales were deposited at 2.2 and 2.4 Myr intervals respectively. These durations strongly suggest a link between the long-period (˜2.4 Myr) eccentricity cycle and the development of the Annulata, Dasberg and Hangenberg anoxic shales. It is assumed that these black shales form under transgressive conditions, when extremely high eccentricity promoted the collapse of small continental ice-sheets at the most austral latitudes of western Gondwana.

Pennsylvanian history of the Chautauqua Arch

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bennison, A.P.

1993-03-01

Westward extension of the Ozark Uplift known as the Chautauqua Arch is concealed by a Pennsylvanian cover. This cover provides an insight into its later tectonic history subsequent to its major Late Devonian uplift and truncation. Part of this arch was episodically uplifted during Pennsylvanian time in an area extending west from southwestern Missouri along the Kansas-Oklahoma border to western Montgomery County. Recent stratigraphic mapping in that county indicates moderate Late Desmoinesian to Missourian tectonism. Some strata present on both flanks of the arch are either comparatively thin or missing owing to unconformity truncation or non-deposition. Stratal loss involves themore » Lenapah Limestone, the Hepler and Lost Branch formations, the Cherryvale Shale and the Hertha, Drum, Dewey, Stanton and Wyandotte Limestones. Earlier movements also account for the truncation of Morrowan, Atokan and possibly some Early Desmoinesian beds over the arch. Between tectonic episodes along the arch there were periods of relative tectonic quiescence accompanied by shelf-edge carbonate banks, condensed sequences and siliciclastic sedimentation. West of Montgomery County in Chautauqua County, the widespread Late Pennsylvanian Virgilian outcrops show practically no tectonism. Therefore, the name Chautauqua Arch seems inappropriate for this Pennsylvanian arch, and the name Tri-State Arch is proposed. This arch is bounded on the north by the Cherokee Basin and on the south by the northern rise of the Arkoma Basin. Although this arch is commonly omitted on many tectonic maps, it is a stronger gravity feature than the Bourbon Arch about 50 miles northward. Both tectonic and sedimentary structures have produced much oil and gas entrapment along this arch. For example, an east-west fault south of Independence, aligned with buried Proterozoic hills, has been specially productive.« less

Bimodal Silurian and Lower Devonian volcanic rock assemblages in the Machias-Eastport area, Maine

USGS Publications Warehouse

Gates, Olcott; Moench, R.H.

1981-01-01

Exposed in the Machias-Eastport area of southeastern Maine is the thickest (at least 8,000 m), best exposed, best dated, and most nearly complete succession of Silurian and Lower Devonian volcanic strata in the coastal volcanic belt, remnants of which crop out along the coasts of southern New Brunswick, Canada, and southeastern New England in the United States. The volcanics were erupted through the 600-700-million-year-old Avalonian sialic basement. To test the possibility that this volcanic belt was a magmatic arc above a subduction zone prior to presumed Acadian continental collision, samples representing the entire section in the Machias-Eastport area of Maine were chemically analyzed. Three strongly bimodal assemblages of volcanic rocks and associated intrusives are recognized, herein called the Silurian, older Devonian, and younger Devonian assemblages. The Silurian assemblage contains typically nonporphyritic high-alumina tholeiitic basalts, basaltic andesites, and diabase of continental characterand calc-alkalic rhyolites, silicic dacites, and one known dike of andesite. These rocks are associated with fossiliferous, predominantly marine strata of the Quoddy, Dennys, and Edmunds Formations, and the Leighton Formation of the Pembroke Group (the stratigraphic rank of both is revised herein for the Machias-Eastport area), all of Silurian age. The shallow marine Hersey Formation (stratigraphic rank also revised herein) of the Pembroke Group, of latest Silurian age (and possibly earliest Devonian, as suggested by an ostracode fauna), contains no known volcanics; and it evidently was deposited during a volcanic hiatus that immediately preceded emergence of the coastal volcanic belt and the eruption of the older Devonian assemblage. The older Devonian assemblage, in the lagoonal to subaerial Lower Devonian Eastport Formation, contains tholeiitic basalts and basaltic andesites, typically with abundant plagioclase phenocrysts and typically richer in iron and titanium and poorer in magnesium and nickel than the Silurian basalts; and the Eastport Formation has rhyolites and silicic dacites that have higher average SiO2 and K2O contents and higher ratios of FeO* to MgO than the Silurian ones. The younger Devonian assemblage is represented by one sample of basalt from a flow in red beds of the post-Acadian Upper Devonian Perry Formation, and by three samples from pre-Acadian diabases that intrude the Leighton and Hersey Formations. These rocks are even richer in titanium and iron and poorer in magnesium and nickel than the older Devonian basalts. Post-Acadian granitic plutons exposed along the coastal belt for which analyses are available are tentatively included in the younger Devonian assemblage. The most conspicuous features of the coastal volcanics and associated intrusives are the preponderance of rocks of basaltic composition ( < 52 percent SiO2 ) in the Silurian assemblage, and the near absence in all assemblages of intermediate rocks having 57-67 percent SiO2 (calculated without volatiles). All the rocks are variably altered spilites and keratophyres. The basaltic types are adequately defined, however, by eight samples of least altered basalts having calcic plagioclase, clinopyroxene, and 0.5 percent or less CO2 , The more altered basalts are variably enriched or depleted in Na2O, K2O, and CaO relative to the least altered ones. In the silicic rocks no primary ferromagnesian minerals are preserved. The Na2O and K2O contents of the silicic rocks are erratic; they are approximately reciprocal, possibly owing to alkali exchange while the rocks were still glassy. We propose that the coastal volcanic belt extended along an axis of thermal swelling in the Earth's mantle and upward intrusion of partially melted mantle into the sialic Avalonian crust. These processes were accompanied by shoaling and emergence of the belt, and they produced the bimodal volcanism. Tholeiitic basaltic melts segregated from mantle material

Bedrock Geology and Asbestos Deposits of the Upper Missisquoi Valley and Vicinity, Vermont

USGS Publications Warehouse

Cady, Wallace Martin; Albee, Arden Leroy; Chidester, A.H.

1963-01-01

The upper Missisquoi Valley and vicinity as described in this report covers an area of about 250 square miles at the headwaters of the Missisquoi River in north-central Vermont. About 90 percent of the area is forested and the remainder is chiefly farm land. The topography reflects the geologic structure and varied resistance of the bedrock to erosion. Most of the area is on the east limb of the Green Mountain anticlinorium, which is the principal structural feature of Vermont. The bedrock is predominantly sedimentary and volcanic rock that has been regionally metamorphosed. It was intruded before metamorphism by mafic and ultramafic igneous rocks, and after metamorphism by felsic and mafic igneous rocks. The metamorphosed sedimentary and volcanic rocks range in age from Cambrian(?) to Middle Silurian, the intrusive igneous rocks from probably Late Ordovician to probably late Permian. Metamorphism and principal folding in the region occurred in Middle Devonian time. The metamorphosed sedimentary and volcanic rocks make up a section at least 25,000 feet thick and can be divided into nine formations. The Hazens Notch formation of Cambrian(?) and Early Cambrian age is characterized by carbonaceous schist. It is succeeded in western parts of the area by the Jay Peak formation of Early Cambrian age, which is chiefly a schist that is distinguished by the general absence of carbonaceous zones; in central parts of the area the Hazens Notch formation is followed by the Belvidere Mountain amphibolite, probably the youngest of the formations of Early Cambrian age. The Ottauquechee formation, composed of carbonaceous phyllite and quartzite, and phyllitic graywacke, is of Middle Cambrian age. The Stowe formation of Late Cambrian(?) and Early(?) Ordovician age overlies the Ottauquechee and is predominantly noncarbonaceous schist, though it also contains greenstone and carbonaceous schist and phyllite. The Umbrella Hill formation of Middle Ordovician age is characteristically a conglomerate in which the mineral chloritoid is common. The overlying Moretown formation, also of Middle Ordovician age, contains granulite and slate, also greenstone and amphibolite of the Coburn Hill volcanic member. The Shaw Mountain formation, made up of conglomerate, phyllite, and limestone, is the oldest Silurian unit. The Shaw Mountain formation is succeeded by the Northfield slate of Middle Silurian age. The igneous rocks of the region include various ultramafic plutonic rocks, such as dunite, peridotite, and serpentinite, probably of Late Ordovician age; sills and nearly concordant dikes of metagabbro of Late Ordovician age; biotite granite plutons or Middle or Late Devonian age, most notably on Eltey Mountain; and hypabyssallamprophyre, probably of late Permian age. Metamorphic zoning is shown by the distribution of rocks of the epidote-amphibolite facies and the greenschist facies in and near the Green Mountains, and near Coburn Hill and Eltey Mountain. Metasomatism related to regional metamorphism has produced porphyroblasts and quartz segregations in the sedimentary and volcanic rocks, and steatitization and carbonatization of serpentinite. Contact metamorphism has formed rocks of the epidote-amphibolite facies near granite plutons, and probably calc-silicate rock at the contacts of ultramafic plutons. The axial anticline of the Green Mountain anticlinorium and other anticlines and synclines to the east are the major longitudinal structural features of the area. These structures are complicated by transverse folds, particularly a syncline in the vicinity of Tillotson Peak. Early minor cross folds that are best developed in the Hazens Notch formation are believed to be genetically related to the transverse folds. The axial planes of the cross folds are folded about the axes of the later longitudinal folds of the Green Mountain anticlinorium. The longitudinal and transverse fold systems probably formed in the same episode of defor

Geometry of an outcrop-scale duplex in Devonian flysch, Maine

USGS Publications Warehouse

Bradley, D.C.; Bradley, L.M.

1994-01-01

We describe an outcrop-scale duplex consisting of 211 exposed repetitions of a single bed. The duplex marks an early Acadian (Middle Devonian) oblique thrust zone in the Lower Devonian flysch of northern Maine. Detailed mapping at a scale of 1:8 has enabled us to measure accurately parameters such as horse length and thickness, ramp angles and displacements; we compare these and derivative values with those of published descriptions of duplexes, and with theoretical models. Shortening estimates based on line balancing are consistently smaller than two methods of area balancing, suggesting that layer-parallel shortening preceded thrusting. ?? 1994.

Eastern Devonian shales: Organic geochemical studies, past and present

USGS Publications Warehouse

Breger, I.A.; Hatcher, P.G.; Romankiw, L.A.; Miknis, F.P.

1983-01-01

The Eastern Devonian shales are represented by a sequence of sediments extending from New York state, south to the northern regions of Georgia and Alabama, and west into Ohio and to the Michigan and Ilinois Basins. Correlatives are known in Texas. The shale is regionally known by a number of names: Chattanooga, Dunkirk, Rhinestreet, Huron, Antrim, Ohio, Woodford, etc. These shales, other than those in Texas, have elicited much interest because they have been a source of unassociated natural gas. It is of particular interest, however, that most of these shales have no associated crude oil, in spite of the fact that they have some of the characteristics normally attributed to source beds. This paper addresses some of the organic geochemical aspects of the kerogen in these shales, in relation to their oil generating potential. Past organic geochemical studies on Eastern Devonian shales will be reviewed. Recent solid state 13C NMR studies on the nature of the organic matter in Eastern Devonian shales show that Eastern Devonian shales contain a larger fraction of aromatic carbon in their chemical composition. Thus, despite their high organic matter contents, their potential as a petroleum source rock is low, because the kerogen in these shales is of a "coaly" nature and hence more prone to producing natural gas.

Eastern Devonian shales: Organic geochemical studies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berger, I.A.; Hatchner, P.G.; Miknis, F.P.

The Eastern Devonian shales are represented by a sequence of sediments extending from New York state, south to the northern regions of Georgia and Alabama, and west into Ohio and to the Michigan and Illinois Basins. Correlatives are known in Texas. The shale is regionally known by a number of names: Chattanooga, Dunkirk, Rhinestreet, Huron, Antrim, Ohio, Woodford, etc. These shales, other than those in Texas, have elicited much interest because they have been a source of unassociated natural gas. It is of particular interest, however, that most of these shales have no associated crude oil, in spite of themore » fact that they have some of the characteristics normally attributed to source beds. This paper addresses some of the organic geochemical aspects of the kerogen in these shales, in relation to their oil generating potential. Past organic geochemical studies on Eastern Devonian shales are reviewed. Recent solid state /sup 13/C NMR studies on the nature of the organic matter in Eastern Devonian shales show that Eastern Devonian shales contain a larger fraction of aromatic carbon in their chemical composition. Thus, despite their high organic matter contents, their potential as a petroleum source rock is low, because the kerogen in these shales is of a ''coaly'' nature and hence more prone to producing natural gas.« less

Eastern Madre de Dios Devonian generated large volumes of oil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, K.E.; Wagner, J.B.; Carpenter, D.G.

This is the second part of an article giving details of a Mobil Corp. regional geological, geophysical, and geochemical study of the Madre de Dios basin. The assessment covered the distribution, richness, depositional environment, and thermal maturity of Devonian source rocks.

Assessment of undiscovered oil and gas resources of the Devonian Marcellus Shale of the Appalachian Basin Province

USGS Publications Warehouse

Coleman, James L.; Milici, Robert C.; Cook, Troy A.; Charpentier, Ronald R.; Kirshbaum, Mark; Klett, Timothy R.; Pollastro, Richard M.; Schenk, Christopher J.

2011-01-01

Using a geology-based assessment methodology, the U.S. Geological Survey (USGS) estimated a mean undiscovered natural gas resource of 84,198 billion cubic feet and a mean undiscovered natural gas liquids resource of 3,379 million barrels in the Devonian Marcellus Shale within the Appalachian Basin Province. All this resource occurs in continuous accumulations. In 2011, the USGS completed an assessment of the undiscovered oil and gas potential of the Devonian Marcellus Shale within the Appalachian Basin Province of the eastern United States. The Appalachian Basin Province includes parts of Alabama, Georgia, Kentucky, Maryland, New York, Ohio, Pennsylvania, Tennessee, Virginia, and West Virginia. The assessment of the Marcellus Shale is based on the geologic elements of this formation's total petroleum system (TPS) as recognized in the characteristics of the TPS as a petroleum source rock (source rock richness, thermal maturation, petroleum generation, and migration) as well as a reservoir rock (stratigraphic position and content and petrophysical properties). Together, these components confirm the Marcellus Shale as a continuous petroleum accumulation. Using the geologic framework, the USGS defined one TPS and three assessment units (AUs) within this TPS and quantitatively estimated the undiscovered oil and gas resources within the three AUs. For the purposes of this assessment, the Marcellus Shale is considered to be that Middle Devonian interval that consists primarily of shale and lesser amounts of bentonite, limestone, and siltstone occurring between the underlying Middle Devonian Onondaga Limestone (or its stratigraphic equivalents, the Needmore Shale and Huntersville Chert) and the overlying Middle Devonian Mahantango Formation (or its stratigraphic equivalents, the upper Millboro Shale and middle Hamilton Group).

Assessment of undiscovered continuous gas resources in Upper Devonian Shales of the Appalachian Basin Province, 2017

USGS Publications Warehouse

Enomoto, Catherine B.; Trippi, Michael H.; Higley, Debra K.; Rouse, William A.; Dulong, Frank T.; Klett, Timothy R.; Mercier, Tracey J.; Brownfield, Michael E.; Leathers-Miller, Heidi M.; Finn, Thomas M.; Marra, Kristen R.; Le, Phuong A.; Woodall, Cheryl A.; Schenk, Christopher J.

2018-04-19

Using a geology-based assessment methodology, the U.S. Geological Survey estimated mean undiscovered, technically recoverable continuous resources of 10.7 trillion cubic feet of natural gas in Upper Devonian shales of the Appalachian Basin Province.

Detrital zircon age patterns and provenance of the metamorphic complexes of southern Chile

NASA Astrophysics Data System (ADS)

Hervé, F.; Fanning, C. M.; Pankhurst, R. J.

2003-05-01

Zircon SHRIMP U-Pb age patterns are reported for 13 metasedimentary rocks from the low grade metamorphic complexes of the Patagonian Andes. Combined with four recently published patterns, these provide the first detailed survey of the provenance of these complexes. The youngest dated zircons, corresponding to maximum sedimentation ages, are Devonian-Late Triassic in the eastern Andes metamorphic complex, Carboniferous in the main range metamorphic complex, Permian in the Duque de York complex, and Late Triassic in the Chonos metamorphic complex. In the last two cases, these ages are in agreement with their respective fossil ages. Older components in the eastern Andes metamorphic complex include a large proportion of Proterozoic (predominantly 1000-1200 Ma) zircons, which may indicate distribution, probably by rivers, of detrital material from regions currently in northern South America, Africa, or east Antarctica. The abundance of Proterozoic zircons is very much less in the Duque de York complex, possibly because of the rise of an inferred Permian magmatic arc related to the Gondwanan orogeny and consequent westward migration of the watershed. A Late Triassic magmatic episode is registered in the Chonos metamorphic complex, where reappearance of significant Proterozoic zircons indicates exhumation of the cratonic areas or of recycled sedimentary material.

The geology of Burnsville Cove, Bath and Highland Counties, Virginia

USGS Publications Warehouse

Swezey, Christopher; Haynes, John T.; Lambert, Richard A.; White, William B.; Lucas, Philip C.; Garrity, Christopher P.

2015-01-01

Burnsville Cove is a karst region in Bath and Highland Counties of Virginia. A new geologic map of the area reveals various units of limestone, sandstone, and siliciclastic mudstone (shale) of Silurian through Devonian age, as well as structural features such as northeast-trending anticlines and synclines, minor thrust faults, and prominent joints. Quaternary features include erosional (strath) terraces and accumulations of mud, sand, and gravel. The caves of Burnsville Cove are located within predominantly carbonate strata above the Silurian Williamsport Sandstone and below the Devonian Oriskany Sandstone. Most of the caves are located within the Silurian Tonoloway Limestone, rather than the Silurian-Devonian Keyser Limestone as reported previously.

Petroleum geology and resources of the Nepa-Botuoba High, Angara-Lena Terrace, and Cis-Patom Foredeep, southeastern Siberian Craton, Russia

USGS Publications Warehouse

Ulmishek, Gregory F.

2001-01-01

Three structural provinces of this report, the Nepa-Botuoba High, the Angara-Lena Terrace, and the Cis-Patom Foredeep, occupy the southeastern part of the Siberian craton northwest of the Baikal-Patom folded region (fig. 1). The provinces are similar in many aspects of their history of development, stratigraphic composition, and petroleum geology characteristics. The sedimentary cover of the provinces overlies the Archean?Lower Proterozoic basement of the Siberian craton. Over most of the area of the provinces, the basement is covered by Vendian (uppermost Proterozoic, 650?570 Ma) clastic and carbonate rocks. Unlike the case in the more northwestern areas of the craton, older Riphean sedimentary rocks here are largely absent and they appear in the stratigraphic sequence only in parts of the Cis-Patom Foredeep province. Most of the overlying sedimentary section consists of Cambrian and Ordovician carbonate and clastic rocks, and it includes a thick Lower Cambrian salt-bearing formation. Younger rocks are thin and are present only in marginal areas. 1 A single total petroleum system (TPS) embraces all three provinces. The TPS is unique in two aspects: (1) its rich hydro-carbon reserves are derived from Precambrian source rocks and (2) preservation of oil and gas fields is extremely long owing to the presence of the Lower Cambrian undeformed salt seal. Discovered reserves of the TPS are about 2 billion barrels of oil and more than 30 trillion cubic feet of gas. The stratigraphic distribution of oil and gas reserves is narrow; all fields are in Vendian to lowermost Cambrian clastic and carbonate reservoirs that occur below Lower Cambrian salt. Both structural and stratigraphic traps are known. Source rocks are absent in the sedimentary cover of the provinces, with the possible exception of a narrow zone on the margin of the Cis-Patom Foredeep province. Source rocks are interpreted here to be Riphean and Vendian organic-rich shales of the Baikal-Patom folded region. These rocks presently are deformed and metamorphosed, but they generated oil and gas before the deformation occurred in Late Silurian and Devonian time. Generated hydrocarbons migrated updip onto the craton margin. The time of migration and formation of fields is constrained by the deposition of Lower Cambrian salt and by the Late Silurian or Devonian metamorphism of source rocks. This time frame indicates that the TPS is one of the oldest petroleum systems in the world. All three provinces are exploration frontiers, and available geologic data are limited; therefore, only one assessment unit has been identified. The largest undiscovered hydrocarbon resources are expected to be in Vendian clastic reservoirs in both structural and stratigraphic traps of the Nepa-Botuoba High province. The petroleum potential of Vendian?lowermost Cambrian carbonate reservoirs is smaller. Nevertheless, these reservoirs may contain significant resources. Gas is expected to dominate over oil in the resource base.

Time-slice maps showing age, distribution, and style of deformation in Alaska north of 60° N.

USGS Publications Warehouse

Moore, Thomas E.; Box, Stephen E.

2016-08-29

The structural architecture of Alaska is the product of a complex history of tectonism that occurred along the Cordilleran and Arctic margins of North America through interactions with ancient and modern ocean plates and with continental elements derived from Laurentia, Siberia, and Baltica. To unravel the tectonic history of Alaska, we constructed maps showing the age, distribution, structural style, and kinematics of contractional and penetrative extensional deformation in Alaska north of latitude 60° N. at a scale of 1:5,000,000. These maps use the Geologic Map of the Arctic (Harrison and others, 2011) as a base map and follow the guidelines in the Tectonic Map of the Arctic project (Petrov and others, 2013) for construction, including use of the International Commission on Stratigraphy time scale (Cohen and others, 2013) divided into 20 time intervals. We find evidence for deformation in 14 of the 20 time intervals and present maps showing the known or probable extent of deformation for each time interval. Maps and descriptions of deformational style, age constraints, kinematics, and information sources for each deformational episode are discussed in the text and are reported in tabular form. This report also contains maps showing the lithologies and structural geology of Alaska, a terrane map, and the distribution of tectonically important units including post-tectonic sedimentary basins, accretionary complexes, ophiolites, metamorphic rocks.These new maps show that most deformational belts in Alaska are relatively young features, having developed during the late Mesozoic and Cenozoic. The oldest episode of deformation recognized anywhere in Alaska is found in the basement of the Farewell terrane (~1.75 Ga). Paleozoic and early Mesozoic deformational events, including Devonian deformation in the Arctic Alaska terrane, Pennsylvanian deformation in the Alexander terrane, Permian deformation in the Yukon Composite (Klondike orogeny) and Farewell terranes (Browns Fork orogeny), Early and Late Jurassic deformation in the Peninsular-Wrangellia terranes, and Early Cretaceous deformation in northern Alaska (early Brookian orogeny) show that within-terrane amalgamation events occurred prior to assembly of Alaska. Widespread episodes of deformation in the Late Cretaceous and early Cenozoic, in contrast, affected multiple terranes, indicating they occurred during or following the time of assembly of most of Alaska.The primary deformational event in northern Alaska was the Late Jurassic and Early Cretaceous (early) Brookian orogeny, which affected most terranes north and west of the early Cenozoic Tintina, Victoria Creek, Kaltag, and Poorman dextral-slip faults in central Alaska. In southern Alaska, formation of the southern Alaska accretionary complex (Chugach, Prince William, Yakutat terranes) and associated magmatism in the Peninsular-Wrangellia terrane began near the Triassic-Jurassic boundary and continued episodically throughout the remainder of the Mesozoic and the Cenozoic. The collision of these terranes with the Farewell and Yukon Composite terranes in central Alaska is recorded by contractional deformation that emanated from the intervening basins in the Late Cretaceous. The boundary between northern and central Alaska is constrained to late Early Cretaceous but is enigmatic and not obviously marked by contractional deformation. Early Cenozoic shortening and transpressional deformation is the most widespread event recorded in Alaska and produced the widespread late Brookian orogenic event in northern Alaska. Middle and late Cenozoic shortening and transpression is significant in southern Alaska inboard of the underthrusting Yakutat terrane at the Pacific margin subduction zone as well as in northeastern Alaska.

Hydrocarbon potential of Upper Devonian black shale, eastern Kentucky

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnston, I.M.; Frankie, W.T.; Moody, J.R.

The gas-producing Upper Devonian black shales of eastern Kentucky represent cycles of organic units alternating with less-organic units that were dominated by an influx of clastics from a northeastern source. This pattern of sedimentation is typical throughout the southern Appalachian basin in areas basinal to, yet still influenced by, the Catskill delta to the northwest. These black shales, which thin westward onto the Cincinnati arch, dip eastward into the Appalachian basin. To evaluate the future gas potential of Devonian shale, a data base has been compiled, consisting of specific geologic and engineering information from 5920 Devonian shale wells in Letcher,more » Knott, Floyd, Martin, and Pike Counties, Kentucky. The first successful gas completion in eastern Kentucky was drilled in Martin County in 1901. Comparison of initial open-flow potential (IP) and long-term production data for these wells demonstrates that higher IP values generally indicate wells of higher production potential. Areas of higher IP are aligned linearly, and these lineaments are interpreted to be related to fracture systems within the Devonian shale. These fractures may be basement influenced. Temperature log analyses indicate that the greatest number of natural gas shows occur in the lower Huron Member of the Ohio Shale. Using both the temperature log to indicate gas shows and the gamma-ray log to determine the producing unit is a workable method for selecting the interval for treatment.« less

Suprasubduction volcanic rocks of the Char ophiolite belt, East Kazakhstan: new geochemical and first geochronological data

NASA Astrophysics Data System (ADS)

Safonova, Inna; Simonov, Vladimir; Seltmann, Reimar; Yamamoto, Shinji; Xiao, Wenjiao

2016-04-01

The Char ophiolite belt is located in the western Central Asian Orogenic Belt, a world largest accretionary orogen, which has evolved during more than 800 Ma. The Char belt formed during Kazakhstan - Siberia collision. It has been known for hosting fragments of Late Devonian-Early Carboniferous oceanic crust, MORB, OPB and OIB, of the Paleo-Asian Ocean (Safonova et al., 2012). The Char is surrounded by two Paleozoic island-arc terranes: Zharma-Saur in the west and Rudny Altai in the east, however, until recent times, no island-arc units have been found within it. We were the first to find island-arc units as tectonic sheets occurring adjacent to those consisting of oceanic rocks. In places, island-arc andesites cut oceanic basalts. The Char volcanic and subvolcanic rocks of a probable suprasubduction origin are basalt, microgabbro, dolerite, andesite, tonalite and dacite. The mafic to andesitic volcanics possessing low TiO2 (0.85 wt.%av.) and show MgO vs. major elements crystallization trends suggesting two magma series: tholeiitic and calc-alkaline. The tholeiitic varieties are less enriched in incompatible elements then the calc-alkaline ones. Two samples are high-Mg and low-Ti andesibasalts similar to boninites. The rocks possess moderately LREE enriched rare-earth element patterns and are characterized by negative Nb anomalies present on the multi-element spectra (Nb/Lapm = 0.14-0.47; Nb/Thpm = 0.7-1.6).The distribution of rare-earth elements (La/Smn = 0.8-2.3, Gd/Ybn = 0.7-1.9) and the results of geochemical modeling in the Nb-Yb system suggest high degrees of melting of a depleted harzburgite-bearing mantle source at spinel facies depths. Fractional crystallization of clinopyroxene, plagioclase and opaque minerals also affected the final composition of the volcanic rocks. Clinopyroxene monomineral thermometry indicates crystallization of melts at 1020-1180°C. Melt inclusion composition based numerical calculations show that primary melts were derived at 1350-1530°C and 14-26 kbar and crystallized at 1150-1190°C (Simonov et al., 2010). All these features are indicative of a supra-subduction origin of rocks. The age of gabbro, dolerite, andesite and tonalite was determined by LA ICP MS U-Pb zircon dating performed in the University of Kyoto, Japan. The andesites and tonalites yielded Carboniferous ages of ca. 322-336 Ma and the gabbro and dolerite appeared Devonian (387-395 Ma). Thus, the Char volcanic rocks possess geochemical signatures of supra-subduction magmas and could be derived at high degree melting of relatively shallow mantle sources. The volcanic units probably formed at one or two island-arcs or at an intra-oceanic arc and continental margin arc during the Middle Devonian - Mississippian. Later, the island-arc units were probably accreted to the active margin of the Kazakhstan continent. The work was supported by RFBR Project no. 16-05-00313. Contribution to IGCP#592 of UNESCO-IUGS. Safonova, I.Yu., Simonov V.A., Kurganskaya E.V., Obut O.T., Romer R.L., Seltmann R., 2012. Late Paleozoic oceanic basalts hosted by the Char suture-shear zone, East Kazakhstan: geological position, geochemistry, petrogenesis and tectonic setting. Journal of Asian Earth Sciences 49, 20-39. Simonov V.A., Safonova I.Yu., Kovyazin S.V., 2010. Petrogenesis of island-arc complexes of the Char zone, East Kazakhstan. Petrology 18, 59-72.

"Belgian black and red marbles" as potential candidates for Global Heritage Stone Resource

NASA Astrophysics Data System (ADS)

Tourneur, Francis; Pereira, Dolores

2016-04-01

The Paleozoic substrate of South Belgium is rich in compact limestones, able to take a good polished finishing and to be used as "marbles". Among them, the black and red varieties were and still are of special importance, intensively exploited and largely exported, almost worldwide. The pure black marbles were extracted mostly from Frasnian (Upper Devonian) and Viséan (Lower Carboniferous) strata, in many localities like Namur, Dinant, Theux and Basècles. Today only the Frasnian variety is still exploited in a spectacular underground quarry in Golzinne, close to the town of Gembloux. These black marbles, already known in Antiquity, were exported since the Middle Age, first in Western Europe, then, from the 19th c., at a larger scale, almost worldwide. Among their most frequent uses figured of course funeral objects, like the epitaph of the Pope Adrian the 1st, offered by Charlemagne and preserved in the St-Pieter basilica in Rom. Another famous reference is the tombs of the Dukes of Burgundy in Dijon, with white crystalline marble and alabaster. The red marbles are limestones from reefal origin, forming mudmounds more or less rich in fossils of Late Frasnian (Late Devonian) age. They show a strong variability in colors, from dark red to light pinkish grey, and in texture, with many sedimentary structures and/or tectonic veins. The outcrops are non-stratified, which allows extraction of large blocks, for example for high columns. Known in the Roman time, they were intensively exploited since at least the 16th c. During the 19th and beginning of 20th c., more than hundred quarries were active in South Belgium, from Rance at West to Chaudfontaine at East, around Philippeville and Rochefort. They were largely used both in civil and religious buildings, mostly for inside decoration, for examples as altars or fireplaces. Among the most symbolic places, the Belgian red marbles were massively employed in Versailles, like in the famous "Galerie des Glaces". But many examples of historical buildings are known around the world, for examples the decoration of the harem of Topkapi in Istanbul in the 19th c. or in the floors of the St-Pieter basilica in Rom. Today, only one quarry is active, in Vodelée, a village close to Philippeville but all the varieties of colors and textures can be obtained from this unique source. Both referred materials present the characteristics needed to be candidates to the Global Heritage Stone Resource designation.

Silurian and Devonian in Vietnam—Stratigraphy and facies

NASA Astrophysics Data System (ADS)

Thanh, Tống Duy; Phương, Tạ Hoàng; Janvier, Philippe; Hùng, Nguyễn Hữu; Cúc, Nguyễn Thị Thu; Dương, Nguyễn Thùy

2013-09-01

Silurian and Devonian deposits in Viet Nam are present in several zones and regions, including Quang Ninh, East Bac Bo, and West Bac Bo Zones of the Bac Bo Region, the Dien Bien-Nghe An and Binh Tri Thien Zones of the Viet-Lao Region, and the South Trung Bo, and Western Nam Bo Zones of the South Viet Nam Region (Fig. 1). The main lithological features and faunal composition of the Silurian and Devonian Units in all these zones are briefly described. The Silurian consists of deep-water deposits of the upper parts of the Co To and Tan Mai Formations in the Quang Ninh Zone, the upper parts of the Phu Ngu Formation in the East Bac Bo Zone and the upper parts of the Long Dai and Song Ca Formations in the Viet-Lao Region. Shallow water facies Silurian units containing benthic faunas are more widely distributed, including the upper part of the Sinh Vinh and Bo Hieng Formations in the West Bac Bo Zone, the Kien An Formation in the Quang Ninh Zone, and, in the Viet-Lao Region, the Dai Giang Formation and the upper part of the Tay Trang Formation. No Lower and Middle Devonian deposits indicate deep water facies, but they are characterized by different shallow water facies. Continental to near shore, deltaic facies characterize the Lower Devonian Song Cau Group in the East Bac Bo Zone, the Van Canh Formation in the Quang Ninh Zone, and the A Choc Formation in the Binh Tri Thien Zone. Similar facies also occur in the Givetian Do Son Formation of the Quang Ninh Zone, and the Tan Lap Formation in the East Bac Bo Zone, and consist of coarse terrigenous deposits—cross-bedded conglomerates, sandstone, etc. Most Devonian units are characterized by shallow marine shelf facies. Carbonate and terrigenous-carbonate facies dominate, and terrigenous facies occur in the Lower and Middle Devonian sections in some areas only. The deep-water-like facies is characteriztic for some Upper Devonian formations in the Bac Bo (Bang Ca and Toc Tat Formations) and Viet-Lao Regions (Thien Nhan and Xom Nha Formations). These formations contain cherty shale or siliceous limestone, and fossils consist of conodonts, but there are also brachiopods and other benthos. They were possibly deposited in a deep water environment on the slope of the continental shelf. Most Devonian units distributed in the North and the Central Viet Nam consist of self shallow water sediments, and apparently they were deposited in a passive marginal marine environment. The coarse clastic continental or subcontinental deposits are distributed only in some areas of the East Bac Bo and of the Quang Ninh zones of the Bac Bo Region, and in the south of the Binh Tri Thien Zone. This situation suggests the influence of the Caledonian movement at the end of the Silurian period that called the Guangxi movement in South China.

18 CFR 270.306 - Devonian shale wells in Michigan.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Devonian shale wells in Michigan. 270.306 Section 270.306 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY...) Attesting the applicant has no knowledge of any information not described in the application which is...

The major-ion composition of Carboniferous seawater

NASA Astrophysics Data System (ADS)

Holt, Nora M.; García-Veigas, Javier; Lowenstein, Tim K.; Giles, Peter S.; Williams-Stroud, Sherilyn

2014-06-01

The major-ion chemistry (Na+, Mg2+, Ca2+, K+, SO42-, and Cl-) of Carboniferous seawater was determined from chemical analyses of fluid inclusions in marine halites, using the cryo scanning electron microscopy (Cryo-SEM) X-ray energy-dispersive spectrometry (EDS) technique. Fluid inclusions in halite from the Mississippian Windsor and Mabou Groups, Shubenacadie Basin, Nova Scotia, Canada (Asbian and Pendleian Substages, 335.5-330 Ma), and from the Pennsylvanian Paradox Formation, Utah, USA, (Desmoinesian Stage 309-305 Ma) contain Na+-Mg2+-K+-Ca2+-Cl- brines, with no measurable SO42-, which shows that the Carboniferous ocean was a “CaCl2 sea”, relatively enriched in Ca2+ and low in SO42- with equivalents Ca2+ > SO42- + HCO3-. δ34S values from anhydrite in the Mississippian Shubenacadie Basin (13.2-14.0 ‰) and the Pennsylvanian Paradox Formation (11.2-12.6 ‰) support seawater sources. Br in halite from the Shubenacadie Basin (53-111 ppm) and the Paradox Basin (68-147 ppm) also indicate seawater parentages. Carboniferous seawater, modeled from fluid inclusions, contained ∼22 mmol Ca2+/kg H2O (Mississippian) and ∼24 mmol Ca2+/kg H2O (Pennsylvanian). Estimated sulfate concentrations are ∼14 mmol SO42-/kg H2O (Mississippian), and ∼12 mmol SO42-/kg H2O (Pennsylvanian). Calculated Mg2+/Ca2+ ratios are 2.5 (Mississippian) and 2.3 (Pennsylvanian), with an estimated range of 2.0-3.2. The fluid inclusion record of seawater chemistry shows a long period of CaCl2 seas in the Paleozoic, from the Early Cambrian through the Carboniferous, when seawater was enriched in Ca2+ and relatively depleted in SO42-. During this ∼200 Myr interval, Ca2+ decreased and SO42- increased, but did not cross the Ca2+-SO42- chemical divide to become a MgSO4 sea (when SO42- in seawater became greater than Ca2+) until the latest Pennsylvanian or earliest Permian (∼309-295 Ma). Seawater remained a MgSO4 sea during the Permian and Triassic, for ∼100 Myr. Fluid inclusions also record a long interval, from the Early Cambrian to the Middle Devonian, when seawater had low Mg2+/Ca2+ ratios (<2) that coincide with calcite seas. The Mg2+/Ca2+ ratio of seawater rose from 0.9 in the Middle Devonian, to 2.5 in the Middle/Late Mississippian, 2.3 in the Middle Pennsylvanian, and 3.5 in the Early Permian. The transition from calcite seas to aragonite seas, established from the mineralogy of oölites and early marine cements, occurred in the Late Mississippian. Fluid inclusions show that seawater Mg2+/Ca2+ ratios rose above 2 by the Middle to Late Mississippian coinciding exactly with the shift to aragonite seas. Aragonite seas existed for ∼100 Myr, from the Late Mississippian until the Late Triassic/Early Jurassic.

Land plants, weathering, and Paleozoic climatic evolution

NASA Astrophysics Data System (ADS)

Goddéris, Yves; Maffre, Pierre; Donnadieu, Yannick; Carretier, Sébastien

2017-04-01

At the end of the Paleozoic, the Earth plunged into the longest and most severe glaciation of the Phanerozoic eon (Montanez et al., 2013). The triggers for this event (called the Late Paleozoic Ice Age, LPIA) are still debated. Based on field observations and laboratory experiments showing that CO2 consumption by rock weathering is enhanced by the presence of plants, the onset of the LPIA has been related to the colonization of the continents by vascular plants in the latest Devonian. By releasing organic acids, concentrating respired CO2 in the soil, and by mechanically breaking rocks with their roots, land plants may have increased the weatherability of the continental surfaces. The "greening" of the continents may also have contributed to an enhanced burial of organic carbon in continental sedimentary basins, assuming that lignin decomposers have not yet evolved (Berner, 2004). As a consequence, CO2 went down, setting the conditions for the onset of the LPIA. This scenario is now widely accepted in the scientific community, and reinforces the feeling that biotic evolutionary steps are main drivers of the long-term climatic evolution. Although appealing, this scenario suffers from some weaknesses. The timing of the continent colonization by vascular plants was achieved in the late Devonian, several tens of million years before the onset of the LPIA (Davies and Gibling, 2013). Second, lignin decomposer fungi were present at the beginning of the Carboniferous, 360 million years ago while the LPIA started around 340-330 Ma (Nelsen et al., 2016). Land plants have also decreased the continental albedo, warming the Earth surface and promoting runoff. Weathering was thus facilitated and CO2 went down. Yet, temperature may have stayed constant, the albedo change compensating for the CO2 fall (Le Hir et al., 2010). From a modelling point of view, the effect of land plants on CO2 consumption by rock weathering is accounted for by forcing the weatherability of the continents to rise by a factor of 6 (Berner, 2004). This factor has been inferred from studies of the weathering rate of rocks in young environments, such as recent lava flows colonized by the vegetation (e.g. Moulton et al., 2001). Nevertheless, present-day continental areas displaying a dense vegetal cover (equatorial forests) are characterized by low weathering rates (West, 2012). Indeed, the development of thick and depleted weathering profiles has shifted those systems into a supply-limited regime. The arising questions are thus: is the land plant effect on CO2 consumption by weathering only transient, and if yes, how long does it last? Thousand, million, or tens of million years? Is a world fully vegetated weathering faster than a naked world? Those questions will be investigated through a modelling study simulating the colonization of the continents by land plants in the late Paleozoic using a simple cellular automata algorithm, coupled to a weathering model accounting for the role of the regolith thickness on the weathering regime.

Paleozoic evolution of active margin basins in the southern Central Andes (northwestern Argentina and northern Chile)

NASA Astrophysics Data System (ADS)

Bahlburg, H.; Breitkreuz, C.

The geodynamic evolution of the Paleozoic continental margin of Gondwana in the region of the southern Central Andes is characterized by the westward progression of orogenic basin formation through time. The Ordovician basin in the northwest Argentinian Cordillera Oriental and Puna originated as an Early Ordovician back-arc basin. The contemporaneous magmatic arc of an east-dipping subduction zone was presumably located in northern Chile. In the back-arc basin, a ca. 3500 meter, fining-up volcaniclastic apron connected to the arc formed during the Arenigian. Increased subsidence in the late Arenigian allowed for the accomodation of large volumes of volcaniclastic turbidites during the Middle Ordovician. Subsidence and sedimentation were caused by the onset of collision between the para-autochthonous Arequipa Massif Terrane (AMT) and the South American margin at the Arenigian-Llanvirnian transition. This led to eastward thrusting of the arc complex over its back-arc basin and, consequently, to its transformation into a marine foreland basin. As a result of thrusting in the west, a flexural bulge formed in the east, leading to uplift and emergence of the Cordillera Oriental shelf during the Guandacol Event at the Arenigian-Llanvirnian transition. The basin fill was folded during the terminal collision of the AMT during the Oclóyic Orogeny (Ashgillian). The folded strata were intruded post-tectonically by the presumably Silurian granitoids of the "Faja Eruptiva de la Puna Oriental." The orogeny led to the formation of the positive area of the Arco Puneño. West of the Arco Puneño, a further marine basin developed during the Early Devonian, the eastern shelf of which occupied the area of the Cordillera Occidental, Depresión Preandina, and Precordillera. The corresponding deep marine turbidite basin was located in the region of the Cordillera de la Costa. Deposition continued until the basin fill was folded in the early Late Carboniferous Toco Orogeny. The basin originated as an extensional structure at the continental margin of Gondwana. Independent lines of evidence imply that basin evolution was not connected to subduction. Thus, the basin could not have been in a fore-arc position as previously postulated. Above the folded Devonian-Early Carboniferous strata, a continental volcanic arc developed from the Late Carboniferous to the Middle Triassic. It represents the link between the Choiyoi Province in central Chile and Argentina, and the Mitu Group rift in southern Peru. The volcanic arc succession is characterized by the prevalence of silicic lavas and tuffs and volcaniclastic sedimentary rocks. During the latest Carboniferous, a thick ostracod-bearing lacustrine unit formed in an extended lake in the area of the Depresión Preandina. This lake basin originated in an intra-arc tensional setting. During the Early Permian, marine limestones were deposited on a marine platform west and east of the volcanic arc, connected to the depositional area of the Copacabana Formation in southern Peru.

Open system sulphate reduction in a diagenetic environment - Isotopic analysis of barite (δ34S and δ18O) and pyrite (δ34S) from the Tom and Jason Late Devonian Zn-Pb-Ba deposits, Selwyn Basin, Canada

NASA Astrophysics Data System (ADS)

Magnall, J. M.; Gleeson, S. A.; Stern, R. A.; Newton, R. J.; Poulton, S. W.; Paradis, S.

2016-05-01

Highly positive δ34S values in sulphide minerals are a common feature of shale hosted massive sulphide deposits (SHMS). Often this is attributed to near quantitative consumption of seawater sulphate, and for Paleozoic strata of the Selwyn Basin (Canada), this is thought to occur during bacterial sulphate reduction (BSR) in a restricted, euxinic water column. In this study, we focus on drill-core samples of sulphide and barite mineralisation from two Late Devonian SHMS deposits (Tom and Jason, Macmillan Pass, Selwyn Basin), to evaluate this euxinic basin model. The paragenetic relationship between barite, pyrite and hydrothermal base metal sulphides has been determined using transmitted and reflected light microscopy, and backscatter electron imaging. This petrographic framework provides the context for in-situ isotopic microanalysis (secondary ion mass spectrometry; SIMS) of barite and pyrite. These data are supplemented by analyses of δ34S values for bulk rock pyrite (n = 37) from drill-core samples of un-mineralised (barren), siliceous mudstone, to provide a means by which to evaluate the mass balance of sulphur in the host rock. Three generations of barite have been identified, all of which pre-date hydrothermal input. Isotopically, the three generations of barite have overlapping distributions of δ34S and δ18O values (+22.5‰ to +33.0‰ and +16.4‰ to +18.3‰, respectively) and are consistent with an origin from modified Late Devonian seawater. Radiolarian tests, enriched in barium, are abundant within the siliceous mudstones, providing evidence that primary barium enrichment was associated with biologic activity. We therefore propose that barite formed following remobilisation of productivity-derived barium within the sediment, and precipitated within diagenetic pore fluids close to the sediment water interface. Two generations of pyrite are texturally associated with barite: framboidal pyrite (py-I), which has negative δ34S values (-23‰ to -28‰; n = 9), and euhedral pyrite (py-II), which has markedly more positive δ34S values (+8‰ to +26‰; n = 86). We argue that stratiform pyrite and barite developed along diagenetic redox fronts, where the isotopic relationships (δ34Spyrite ≈ δ34Sbarite) are explained by anaerobic oxidation of methane coupled to sulphate reduction (AOM-SR). Furthermore, the relatively narrow distribution of δ34Sbarite values is consistent with an open system model of sulphate reduction, in which reduced sulphur generation occurred with a reduced isotopic fractionation (ε34S = <15‰) linked to higher rates of sulphate reduction and AOM-SR. Importantly, hydrothermal sulphides (pyrite, sphalerite and galena) all post-date this diagenetic barite-pyrite assemblage, and textural and mineralogical evidence indicates barite replacement to be an important process during hydrothermal mineralisation. Neither the textures nor the documented isotopic relationships can be produced by processes operating in a euxinic water column, which represents a major departure from the conventional model for SHMS formation at Macmillan Pass. We suggest that positive δ34S values in sulphides, a common feature of SHMS systems both in the Selwyn Basin and throughout the geologic record, could be linked to AOM-SR. At Macmillan Pass, positive δ34Spyrite values developed during open system diagenesis, which was critical for rapid sulphur cycling and the development of an effective metal trap.

Geologic map of the Nelson quadrangle, Lewis and Clark County, Montana

USGS Publications Warehouse

Reynolds, Mitchell W.; Hays, William H.

2003-01-01

The geologic map of the Nelson quadrangle, scale 1:24,000, was prepared as part of the Montana Investigations Project to provide new information on the stratigraphy, structure, and geologic history of an area in the geologically complex southern part of the Montana disturbed belt. In the Nelson area, rocks ranging in age from Middle Proterozoic through Cretaceous are exposed on three major thrust plates in which rocks have been telescoped eastward. Rocks within the thrust plates are folded and broken by thrust faults of smaller displacement than the major bounding thrust faults. Middle and Late Tertiary sedimentary and volcaniclastic rocks unconformably overlie the pre-Tertiary rocks. A major normal fault displaces rocks of the western half of the quadrangle down on the west with respect to strata of the eastern part. Alluvial and terrace gravels and local landslide deposits are present in valley bottoms and on canyon walls in the deeply dissected terrain. Different stratigraphic successions are exposed at different structural levels across the quadrangle. In the northeastern part, strata of the Middle Cambrian Flathead Sandstone, Wolsey Shale, and Meagher Limestone, the Middle and Upper Cambrian Pilgrim Formation and Park Shale undivided, the Devonian Maywood, Jefferson, and lower part of the Three Forks Formation, and Lower and Upper Mississippian rocks assigned to the upper part of the Three Forks Formation and the overlying Lodgepole and Mission Canyon Limestones are complexly folded and faulted. These deformed strata are overlain structurally in the east-central part of the quadrangle by a succession of strata including the Middle Proterozoic Greyson Formation and the Paleozoic succession from the Flathead Sandstone upward through the Lodgepole Limestone. In the east-central area, the Flathead Sandstone rests unconformably on the middle part of the Greyson Formation. The north edge, northwest quarter, and south half of the quadrangle are underlain by a succession of rocks that includes not only strata equivalent to those of the remainder of the quadrangle, but also the Middle Proterozoic Newland, Greyson, and Spokane Formations, Pennsylvanian and Upper Mississippian Amsden Formation and Big Snowy Group undivided, the Permian and Pennsylvanian Phosphoria and Quadrant Formations undivided, the Jurassic Ellis Group and Lower Cretaceous Kootenai Formation. Hornblende diorite sills and irregular bodies of probable Late Cretaceous age intrude Middle Proterozoic, Cambrian and Devonian strata. No equivalent intrusive rocks are present in structurally underlying successions of strata. In this main part of the quadrangle, the Flathead Sandstone cuts unconformably downward from south to north across the Spokane Formation into the upper middle part of the Greyson Formation. Tertiary (Miocene?) strata including sandstone, pebble and cobble conglomerate, and vitric crystal tuff underlie, but are poorly exposed, in the southeastern part of the quadrangle where they are overlain by late Tertiary and Quaternary gravel. The structural complexity of the quadrangle decreases from northeast to southwest across the quadrangle. At the lowest structural level (Avalanche Butte thrust plate) exposed in the canyon of Beaver Creek, lower and middle Paleozoic rocks are folded in northwest-trending east-inclined disharmonic anticlines and synclines that are overlain by recumbently folded and thrust faulted Devonian and Mississippian rocks. The Mississippian strata are imbricated adjacent to the recumbent folds. In the east-central part of the quadrangle, a structurally overlying thrust plate, likely equivalent to the Hogback Mountain thrust plate of the Hogback Mountain quadrangle adjacent to the east (Reynolds, 20xx), juxtaposes recumbently folded Middle Proterozoic and unconformably overlying lower Paleozoic rocks on the complexly folded and faulted rocks of the Avalanche Butte thrust plate. The highest structural plate, bounded below

Metals in Devonian kerogenous marine strata at Gibellini and Bisoni properties in southern Fish Creek Range, Eureka County, Nevada

USGS Publications Warehouse

Desborough, George A.; Poole, F.G.; Hose, R.K.; Radtke, A.S.

1979-01-01

A kerogen-rich sequence of siliceous mudstone, siltstone, and chert as much as 60 m thick on ridge 7129 in the southern Fish Creek Range, referred to as Gibellini facies of the Woodruff Formation, has been evaluated on the surface and in drill holes principally for its potential resources of vanadium, zinc, selenium, molybdenum, and syncrude oil content. The strata are part of a strongly deformed allochthonous mass of eugeosynclinal Devonian marine rocks that overlie deformed allochthonous Mississippian siliceous rocks and relatively undeformed autochthonous Mississippian Antler flysch at this locality. The vanadium in fresh black rocks obtained from drill holes and fresh exposures in trenches and roadcuts occurs chiefly in organic matter. Concentrations of vanadium oxide (V2O5) in unoxidized samples range from 3,000 to 7,000 ppm. In oxidized and bleached rock that is prevalent at the surface, concentrations of vanadium oxide range from 6,000 to 8,000 ppm, suggesting a tendency toward enrichment due to surficial weathering and ground-water movement. Zinc occurs in sphalerite, and selenium occurs in organic matter; molybdenum appears to occur both in molybdenite and in organic matter. Concentrations of zinc in unoxidized rock range from 4,000 to 18,000 ppm, whereas in oxidized rock they range from 30 to 100 ppm, showing strong depletion due to weathering. Concentrations of selenium in unoxidized rock range from 30 to 200 ppm, whereas in oxidized rock they range from 200 to 400 ppm, indicating some enrichment upon weathering. Concentrations of molybdenum in unoxidized rock range from 70 to 960 ppm, whereas in oxidized rock they range from 30 to 80 ppm, indicating strong depletion upon weathering. Most fresh black rock is low-grade oil shale, and yields as much as 12 gallons/short ton of syncrude oil. Metahewettite is the principal vanadium mineral in the oxidized zone, but it also occurs sparsely as small nodules and fillings of microfractures in unweathered strata. In fresh rock, bluish-white opaline-like silica (chalcedonic quartz) fills microfractures, and is believed to have originated by diagenetic mobilization of opaline silica from radiolarian tests and sponge spicules. As revealed by microscopic study, the Gibellini facies originally consisted of siliceous muds, slimes, and oozes high in organic constituents. The organic matter is amorphous flaky and stringy sapropel, and probably includes remains of bacteria, phytoplankton, zooplankton, and minor higher plants. Recognizable organic remnants include radiolarian tests, sponge spicules, conodonts, brachiopod shells, algae, and humic debris. Diagnostic radiolarians indicate a Late Devonian age for the Gibellini facies of the Woodruff Formation. Some pyrite is disseminated through the rock and may be primary (syngenetic) but significant pyrite and marcasite occur in chalcedonic quartz veinlets and appear to be diagenetic. In fresh rock, black solid bitumen and liquid oil fill voids and microfractures. These early phase hydrocarbons probably were released during diagenesis from complex nonhydrocarbon molecular structures originating from living organisms, and formed without any major thermal degradation of the kerogen. Gas chromatographic analysis of the saturated hydrocarbon fraction indicates a very complex mixture dominated by branched and cyclic compounds. Conodont and palynomorph color alteration, vitrinite reflectance, and other organic geochemical data suggest that the organic matter in the rock is thermally immature and has not been subjected to temperatures greater than 60?C since deposition in Devonian time. All of these characteristics are consistent with the interpretation of a relatively low temperature and a shallow-burial history for the Gibellini facies on ridge 7129.

Porphyry-Style Petropavlovskoe Gold Deposit, the Polar Urals: Geological Position, Mineralogy, and Formation Conditions

NASA Astrophysics Data System (ADS)

Vikentyev, I. V.; Mansurov, R. Kh.; Ivanova, Yu. N.; Tyukova, E. E.; Sobolev, I. D.; Abramova, V. D.; Vykhristenko, R. I.; Trofimov, A. P.; Khubanov, V. B.; Groznova, E. O.; Dvurechenskaya, S. S.; Kryazhev, S. G.

2017-11-01

Geological and structural conditions of localization, hydrothermal metasomatic alteration, and mineralization of the Petropavlovskoe gold deposit (Novogodnenskoe ore field) situated in the northern part of the Lesser Ural volcanic-plutonic belt, which is a constituent of the Middle Paleozoic island-arc system of the Polar Urals, are discussed. The porphyritic diorite bodies pertaining to the late phase of the intrusive Sob Complex play an ore-controlling role. The large-volume orebodies are related to the upper parts of these intrusions. Two types of stringer-disseminated ores have been revealed: (1) predominant gold-sulfide and (2) superimposed low-sulfide-gold-quartz ore markedly enriched in Au. Taken together, they make up complicated flattened isometric orebodies transitory to linear stockworks. The gold potential of the deposit is controlled by pyrite-(chlorite)-albite metasomatic rock of the main productive stage, which mainly develops in a volcanic-sedimentary sequence especially close to the contacts with porphyritic diorite. The relationships between intrusive and subvolcanic bodies and dating of individual zircon crystals corroborate a multistage evolution of the ore field, which predetermines its complex hydrothermal history. Magmatic activity of mature island-arc plagiogranite of the Sob Complex and monzonite of the Kongor Complex initiated development of skarn and beresite alterations accompanied by crystallization of hydrothermal sulfides. In the Early Devonian, due to emplacement of the Sob Complex at a depth of approximately 2 km, skarn magnetite ore with subordinate sulfides was formed. At the onset of the Middle Devonian, the large-volume gold porphyry Au-Ag-Te-W ± Mo,Cu stockworks related to quartz diorite porphyry—the final phase of the Sob Complex— were formed. In the Late Devonian, a part of sulfide mineralization was redistributed with the formation of linear low-sulfide quartz vein zones. Isotopic geochemical study has shown that the ore is deposited from reduced, substantially magmatic fluid, which is characterized by close to mantle values δ34S = 0 ± 1‰, δ13C =-6 to-7‰, and δ18O = +5‰ as the temperature decreases from 420-300°C (gold-sulfide ore) to 250-130°C (gold-(sulfide)-quartz ore) and pressure decreases from 0.8 to 0.3 kbar. According to the data of microanalysis (EPMA and LA-ICP-MS), the main trace elements in pyrite of gold orebodies are represented by Co (up to 2.52 wt %), As (up to 0.70 wt %), and Ni (up to 0.38 wt %); Te, Se, Ag, Au, Bi, Sb, and Sn also occur. Pyrite of the early assemblages is characterized by high Co, Te, Au, and Bi contents, whereas the late pyrite is distinguished by elevated concentrations of As (up to 0.7 wt %), Ni (up to 0.38 wt %), Se (223 ppm), Ag (up to 111 ppm), and Sn (4.4 ppm). The minimal Au content in pyrite of the late quartz-carbonate assemblage is up to 1.7 ppm and geometric average is 0.3 ppm. The significant correlation between Au and As (furthermore, negative-0.6) in pyrite from ore of the Petropavlovskoe deposit is recorded only for the gold-sulfide assemblage, whereas it is not established for other assemblages. Pyrite with higher As concentration (up to 0.7 wt %) is distinguished only for the Au-Te mineral assemblage. Taking into account structural-morphological and mineralogical-geochemical features, the ore-magmatic system of the Petropavlovskoe deposit is referred to as gold porphyry style. Among the main criteria of such typification are the spatial association of orebodies with bodies of subvolcanic porphyry-like intrusive phases at the roof of large multiphase pluton; the stockwork-like morphology of gold orebodies; 3D character of ore-alteration zoning and distribution of ore components; geochemical association of gold with Ag, W, Mo, Cu, As, Te, and Bi; and predominant finely dispersed submicroscopic gold in ore.

Thermal maturity of northern Appalachian Basin Devonian shales: Insights from sterane and terpane biomarkers

USGS Publications Warehouse

Hackley, Paul C.; Ryder, Robert T.; Trippi, Michael H.; Alimi, Hossein

2013-01-01

To better estimate thermal maturity of Devonian shales in the northern Appalachian Basin, eleven samples of Marcellus and Huron Shale were characterized via multiple analytical techniques. Vitrinite reflectance, Rock–Eval pyrolysis, gas chromatography (GC) of whole rock extracts, and GC–mass spectrometry (GCMS) of extract saturate fractions were evaluated on three transects that lie across previously documented regional thermal maturity isolines. Results from vitrinite reflectance suggest that most samples are immature with respect to hydrocarbon generation. However, bulk geochemical data and sterane and terpane biomarker ratios from GCMS suggest that almost all samples are in the oil window. This observation is consistent with the presence of thermogenic gas in the study area and higher vitrinite reflectance values recorded from overlying Pennsylvanian coals. These results suggest that vitrinite reflectance is a poor predictor of thermal maturity in early mature areas of Devonian shale, perhaps because reported measurements often include determinations of solid bitumen reflectance. Vitrinite reflectance interpretations in areas of early mature Devonian shale should be supplanted by evaluation of thermal maturity information from biomarker ratios and bulk geochemical data.

Geology of the Devonian Marcellus Shale--Valley and Ridge province, Virginia and West Virginia--a field trip guidebook for the American Association of Petroleum Geologists Eastern Section Meeting, September 28-29, 2011

USGS Publications Warehouse

Enomoto, Catherine B.; Coleman, James L.; Haynes, John T.; Whitmeyer, Steven J.; McDowell, Ronald R.; Lewis, J. Eric; Spear, Tyler P.; Swezey, Christopher S.

2012-01-01

Detailed and reconnaissance field mapping and the results of geochemical and mineralogical analyses of outcrop samples indicate that the Devonian shales of the Broadtop Synclinorium from central Virginia to southern Pennsylvania have an organic content sufficiently high and a thermal maturity sufficiently moderate to be considered for a shale gas play. The organically rich Middle Devonian Marcellus Shale is present throughout most of the synclinorium, being absent only where it has been eroded from the crests of anticlines. Geochemical analyses of outcrop and well samples indicate that hydrocarbons have been generated and expelled from the kerogen originally in place in the shale. The mineralogical characteristics of the Marcellus Shale samples from the Broadtop Synclinorium are slightly different from the averages of samples from New York, Pennsylvania, northeast Ohio, and northern West Virginia. The Middle Devonian shale interval is moderately to heavily fractured in all areas, but in some areas substantial fault shearing has removed a regular "cleat" system of fractures. Conventional anticlinal gas fields in the study area that are productive from the Lower Devonian Oriskany Sandstone suggest that a continuous shale gas system may be in place within the Marcellus Shale interval at least in a portion of the synclinorium. Third-order intraformational deformation is evident within the Marcellus shale exposures. Correlations between outcrops and geophysical logs from exploration wells nearby will be examined by field trip attendees.

Unusual anal fin in a Devonian jawless vertebrate reveals complex origins of paired appendages

PubMed Central

Sansom, Robert S.; Gabbott, Sarah E.; Purnell, M. A.

2013-01-01

Jawed vertebrates (gnathostomes) have undergone radical anatomical and developmental changes in comparison with their jawless cousins (cyclostomes). Key among these is paired appendages (fins, legs and wings), which first evolved at some point on the gnathostome stem. The anatomy of fossil stem gnathostomes is, therefore, fundamental to our understanding of the nature and timing of the origin of this complex innovation. Here, we show that Euphanerops, a fossil jawless fish from the Devonian, possessed paired anal-fin radials, but no pectoral or pelvic fins. This unique condition occurs at an early stage on the stem-gnathostome lineage. This condition, and comparison with the varied condition of paired fins in other ostracoderms, indicates that there was a large amount of developmental plasticity during this episode—rather than a gradual evolution of this complex feature. Apparently, a number of different clades were exploring morphospace or undergoing multiple losses. PMID:23576777

Origin and geodynamic significance of the early Mesozoic Weiya LP and HT granulites from the Chinese Eastern Tianshan

NASA Astrophysics Data System (ADS)

Mao, Ling-Juan; He, Zhen-Yu; Zhang, Ze-Ming; Klemd, Reiner; Xiang, Hua; Tian, Zuo-Lin; Zong, Ke-Qing

2015-12-01

The Chinese Tianshan in the southwestern part of the Central Asian Orogenic Belt (CAOB) is characterized by a variety of high-grade metamorphic rocks, which provide critical constraints for understanding the geodynamic evolution of the CAOB. In this paper, we present detailed petrological and zircon U-Pb geochronological studies of the Weiya low-pressure and high-temperature (LP-HT) granulites of the Chinese Eastern Tianshan. These granulites were previously considered to be a product of a regional metamorphic orogenic event. Due to different bulk-rock chemistries the Weiya granulites, which occur as lenses within the contact metamorphic aureole of the Weiya granitic ring complex, have a variety of felsic-pelitic and mafic granulites with different textural equilibrium mineral assemblages including garnet-cordierite-sillimanite-bearing granulites, cordierite-sillimanite-bearing granulites, cordierite-orthopyroxene-bearing granulites, and orthopyroxene-clinopyroxene-bearing granulites. Average P-T thermobarometric calculations and conventional geothermobarometry indicates that the Weiya granulites underwent early prograde metamorphism under conditions of 600-650 °C at 3.2-4.2 kbar and peak metamorphism of 750-840 °C at 2.9-6.3 kbar, indicating a rather high geothermal gradient of ca. 60 °C/km. Zircon U-Pb LA-ICP-MS dating revealed metamorphic ages between 244 ± 1 to 237 ± 3 Ma, which are in accordance with the crystallization age of the Weiya granitic ring complex. We suggest that the formation of the Weiya granulites was related to contemporaneous granitic magmatism instead of a regional metamorphic orogenic event. In addition, a Late Devonian metamorphic age of ca. 380 Ma was recorded in zircon mantle domains from two pelitic samples which is consistent with the metamorphic age of the Xingxingxia metamorphic complex in the Chinese Eastern Tianshan. This suggests that the mantle domains of the zircon grains of the Weiya granulites probably formed during the Late Devonian regional metamorphism and were overprinted by the Early Triassic contact metamorphism. Therefore, Early Triassic geodynamic models for the southwestern part of the CAOB, which are based on a previously suggested regional metamorphic orogenic event of the Weiya granulites, need to be viewed with caution.

Geochronology, stratigraphy and geochemistry of Cambro-Ordovician, Silurian and Devonian volcanic rocks of the Saxothuringian Zone in NE Bavaria (Germany)—new constraints for Gondwana break up and ocean-island magmatism

NASA Astrophysics Data System (ADS)

Höhn, Stefan; Koglin, Nikola; Klopf, Lisa; Schüssler, Ulrich; Tragelehn, Harald; Frimmel, Hartwig E.; Zeh, Armin; Brätz, Helene

2018-01-01

Stratigraphically well-defined volcanic rocks in Palaeozoic volcano-sedimentary units of the Frankenwald area (Saxothuringian Zone, Variscan Orogen) were sampled for geochemical characterisation and U-Pb zircon dating. The oldest rock suite comprises quartz keratophyre, brecciated keratophyre, quartz keratophyre tuff and basalt, formed in Upper Cambrian to Tremadocian time (c. 497-478 Ma). Basaltic volcanism continued until the Silurian. Quartz keratophyre shows post-collisional calc-alkaline signature, the Ordovician-Silurian basalt has alkaline signature typical of continental rift environments. The combined datasets provide evidence of Cambro-Ordovician bimodal volcanism and successive rifting until the Silurian. This evolution very likely resulted from break-up of the northern Gondwana margin, as recorded in many terranes throughout Europe. The position at the northern Gondwana margin is supported by detrital zircon grains in some tuffs, with typical Gondwana-derived age spectra mostly recording ages of 550-750 Ma and minor age populations of 950-1100 and 1700-2700 Ma. The absence of N-MORB basalt in the Frankenwald area points to a retarded break-off of the Saxothuringian terrane along a continental rift system from Uppermost Cambrian to Middle Silurian time. Geochemical data for a second suite of Upper Devonian basalt provide evidence of emplacement in a hot spot-related ocean-island setting south of the Rheic Ocean. Our results also require partial revision of the lithostratigraphy of the Frankenwald area. The basal volcanic unit of the Randschiefer Formation yielded a Tremadocian age and, therefore, should be attributed to the Vogtendorf Formation. Keratophyre of the Vogtendorf Formation, previously assigned to the Tremadoc, is most likely of Upper Devonian age.

Exceptionally preserved crustaceans from western Canada reveal a cryptic Cambrian radiation

NASA Astrophysics Data System (ADS)

Harvey, Thomas H. P.; Vélez, Maria I.; Butterfield, Nicholas J.

2012-01-01

The early history of crustaceans is obscured by strong biases in fossil preservation, but a previously overlooked taphonomic mode yields important complementary insights. Here we describe diverse crustacean appendages of Middle and Late Cambrian age from shallow-marine mudstones of the Deadwood Formation in western Canada. The fossils occur as flattened and fragmentary carbonaceous cuticles but provide a suite of phylogenetic and ecological data by virtue of their detailed preservation. In addition to an unprecedented range of complex, largely articulated filtering limbs, we identify at least four distinct types of mandible. Together, these fossils provide the earliest evidence for crown-group branchiopods and total-group copepods and ostracods, extending the respective ranges of these clades back from the Devonian, Pennsylvanian, and Ordovician. Detailed similarities with living forms demonstrate the early origins and subsequent conservation of various complex food-handling adaptations, including a directional mandibular asymmetry that has persisted through half a billion years of evolution. At the same time, the Deadwood fossils indicate profound secular changes in crustacean ecology in terms of body size and environmental distribution. The earliest radiation of crustaceans is largely cryptic in the fossil record, but "small carbonaceous fossils" reveal organisms of surprisingly modern aspect operating in an unfamiliar biosphere.

Early jointing in coal and black shale: Evidence for an Appalachian-wide stress field as a prelude to the Alleghanian orogeny

DOE Office of Scientific and Technical Information (OSTI.GOV)

Engelder, T.; Whitaker, A.

2006-07-15

Early ENE-striking joints (present coordinates) within both Pennsylvanian coal and Devonian black shale of the Central and Southern Appalachians reflect an approximately rectilinear stress field with a dimension > 1500 km. This Appalachian-wide stress field (AWSF) dates from the time of joint propagation, when both the coal and shale were buried to the oil window during the 10-15 m.y. period straddling the Pennsylvanian-Permian boundary. The AWSF was generated during the final assembly of Pangea as a consequence of plate-boundary tractions arising from late-stage oblique convergence, where maximum horizontal stress, S-H, of the AWSF was parallel to the direction of closuremore » between Gondwana and Laurentia. After closure, the AWSF persisted during dextral slip of peri-Gondwanan microcontinents, when SH appears to have crosscut plate-scale trans-current faults at around 30{sup o}. Following > 10 m.y. of dextral slip during tightening of Gondwana against Laurentia, the AWSF was disrupted by local stress fields associated with thrusting on master basement decollements to produce the local orocline-shaped Alleghanian map pattern seen today.« less

Geological fieldwork in the Libyan Sahara: A multidisciplinary approach

NASA Astrophysics Data System (ADS)

Meinhold, Guido; Whitham, Andrew; Howard, James P.; Morton, Andrew; Abutarruma, Yousef; Bergig, Khaled; Elgadry, Mohamed; Le Heron, Daniel P.; Paris, Florentin; Thusu, Bindra

2010-05-01

Libya is one of the most hydrocarbon-rich countries in the world. Its large oil and gas reserves make it attractive to international oil and gas companies, which provide the impetus for field-based research in the Libyan Sahara. North Africa is made up of several enormous intracratonic basins, two of which are found in southern Libya: the Murzuq Basin, in the southwest, and the Kufra Basin, in the southeast, separated by the Tibesti Massif. Both basins are filled with Palaeozoic and Mesozoic clastic sedimentary rocks reaching up to 5 km in thickness. These basins developed from the Cambrian onwards following an earlier period of orogenesis (the Panafrican Orogeny) in the Neoproterozoic. Precambrian metasediments and granitoids are unconformably overlain by Cambrian and Ordovician conglomerates and sandstones. They show a transitional environment from continental to shallow marine. Skolithos-bearing sandstone is common in Ordovician strata. By the Late Ordovician, ice masses had developed across West Gondwana. Upon melting of the ice sheets in the latest Hirnantian, large volumes of melt water and sediment were released that were transported to the periphery of Gondwana. In Libya, these sediments are predominantly highly mature sandstones, which, in many places, are excellent hydrocarbon reservoirs. Polished and striated surfaces in these sandstones clearly point to their glaciogenic origin. Following Late Ordovician deglaciation, black shale deposition occurred in the Silurian. Some of the shales are characterised by high values of total organic carbon (TOC). These shales are commonly referred to as ‘hot shales' due to their associated high uranium content, and are the major source rock for Early Palaeozoic-sourced hydrocarbons in North Africa. Late Ordovician glaciogenic sediments and the Early Silurian ‘hot shales' are therefore the main focus of geological research in the Libyan Sahara. Fluvial conglomerates and sandstones of Devonian age unconformably overlie these strata. Marine intervals occur in the Late Devonian, and the Carboniferous is characterised by shallow marine clastic sediments with carbonate horizons. Permian rocks are only known from subsurface drill cores and comprise continental and deltaic facies. The centre of the Murzuq Basin has been relatively well investigated by drilling and seismic profiles. The basin margins, however, lack detailed geological investigation. In comparison, the Kufra Basin is underexplored with few boreholes drilled. Our studies have focused on the eastern and northern margins of the Murzuq Basin and the northern, eastern and western margins of the Kufra Basin. The main objective of fieldwork has been to characterise the Infracambrian-Lower Palaeozoic stratigraphy, deduce the structural evolution of each study area, and to collect samples for follow-up analyses including provenance studies and biostratigraphy. In addition to outcrop-based fieldwork shallow boreholes up to 70 m depth were successfully drilled in the Early Silurian shales. The unweathered samples retrieved from two of the boreholes have been used for biostratigraphical and whole-rock geochemical investigations. The provenance study of the sandstone succession with conventional heavy mineral analysis together with U-Pb zircon dating provides, for the first time, an understanding of the ancient source areas. Because most of the Early Palaeozoic succession in southern Libya is barren of fossils, heavy mineral chemostratigraphy is moreover used as a correlation test on surface outcrops in the Kufra and Murzuq basins.

Unconventional shallow biogenic gas systems

USGS Publications Warehouse

Shurr, G.W.; Ridgley, J.L.

2002-01-01

Unconventional shallow biogenic gas falls into two distinct systems that have different attributes. Early-generation systems have blanketlike geometries, and gas generation begins soon after deposition of reservoir and source rocks. Late-generation systems have ringlike geometries, and long time intervals separate deposition of reservoir and source rocks from gas generation. For both types of systems, the gas is dominantly methane and is associated with source rocks that are not thermally mature. Early-generation biogenic gas systems are typified by production from low-permeability Cretaceous rocks in the northern Great Plains of Alberta, Saskatchewan, and Montana. The main area of production is on the southeastern margin of the Alberta basin and the northwestern margin of the Williston basin. The huge volume of Cretaceous rocks has a generalized regional pattern of thick, non-marine, coarse clastics to the west and thinner, finer grained marine lithologies to the east. Reservoir rocks in the lower part tend to be finer grained and have lower porosity and permeability than those in the upper part. Similarly, source beds in the units have higher values of total organic carbon. Patterns of erosion, deposition, deformation, and production in both the upper and lower units are related to the geometry of lineament-bounded basement blocks. Geochemical studies show that gas and coproduced water are in equilibrium and that the fluids are relatively old, namely, as much as 66 Ma. Other examples of early-generation systems include Cretaceous clastic reservoirs on the southwestern margin of Williston basin and chalks on the eastern margin of the Denver basin. Late-generation biogenic gas systems have as an archetype the Devonian Antrim Shale on the northern margin of the Michigan basin. Reservoir rocks are fractured, organic-rich black shales that also serve as source rocks. Although fractures are important for production, the relationships to specific geologic structures are not clear. Large quantities of water are coproduced with the gas, and geochemical data indicate that the water is fairly fresh and relatively young. Current thinking holds that biogenic gas was generated, and perhaps continues to be, when glacial meltwater descended into the plumbing system provided by fractures. Other examples of late-generation systems include the Devonian New Albany Shale on the eastern margin of the Illinois basin and the Tertiary coalbed methane production on the northwestern margin of the Powder River basin. Both types of biogenic gas systems have a similar resource development history. Initially, little technology is used, and gas is consumed locally; eventually, sweet spots are exploited, widespread unconventional reservoirs are developed, and transport of gas is interstate or international. However, drilling and completion techniques are very different between the two types of systems. Early-generation systems have water-sensitive reservoir rocks, and consequently water is avoided or minimized in drilling and completion. In contrast, water is an important constituent of late-generation systems; gas production is closely tied to dewatering the system during production. Existing production and resource estimates generally range from 10 to 100 tcf for both types of biogenic gas systems. Although both system types are examples of relatively continuous accumulations, the geologic frameworks constrain most-economic production to large geologic structures on the margins of basins. Shallow biogenic gas systems hold important resources to meet the increased domestic and international demands for natural gas.

Refining the Early Devonian time scale using Milankovitch cyclicity in Lochkovian-Pragian sediments (Prague Synform, Czech Republic)

NASA Astrophysics Data System (ADS)

Da Silva, A. C.; Hladil, J.; Chadimová, L.; Slavík, L.; Hilgen, F. J.; Bábek, O.; Dekkers, M. J.

2016-12-01

The Early Devonian geological time scale (base of the Devonian at 418.8 ± 2.9 Myr, Becker et al., 2012) suffers from poor age control, with associated large uncertainties between 2.5 and 4.2 Myr on the stage boundaries. Identifying orbital cycles from sedimentary successions can serve as a very powerful chronometer to test and, where appropriate, improve age models. Here, we focus on the Lochkovian and Pragian, the two lowermost Devonian stages. High-resolution magnetic susceptibility (χin - 5 to 10 cm sampling interval) and gamma ray spectrometry (GRS - 25 to 50 cm sampling interval) records were gathered from two main limestone sections, Požár-CS (118 m, spanning the Lochkov and Praha Formations) and Pod Barrandovem (174 m; Praha Formation), both in the Czech Republic. An additional section (Branžovy, 65 m, Praha Formation) was sampled for GRS (every 50 cm). The χin and GRS records are very similar, so χin variations are driven by variations in the samples' paramagnetic clay mineral content, reflecting changes in detrital input. Therefore, climatic variations are very likely captured in our records. Multiple spectral analysis and statistical techniques such as: Continuous Wavelet Transform, Evolutive Harmonic Analysis, Multi-taper method and Average Spectral Misfit, were used in concert to reach an optimal astronomical interpretation. The Požár-CS section shows distinctly varying sediment accumulation rates. The Lochkovian (essentially equivalent to the Lochkov Formation (Fm.)) is interpreted to include a total of nineteen 405 kyr eccentricity cycles, constraining its duration to 7.7 ± 2.8 Myr. The Praha Fm. includes fourteen 405 kyr eccentricity cycles in the three sampled sections, while the Pragian Stage only includes about four 405 kyr eccentricity cycles, thus exhibiting durations of 5.7 ± 0.6 Myr and 1.7 ± 0.7 Myr respectively. Because the Lochkov Fm. contains an interval with very low sediment accumulation rate and because the Praha Fm. was cross-validated in three different sections, the uncertainty in the duration of the Lochkov Fm. and the Lochkovian is larger than that of the Praha Fm. and Pragian. The new floating time scales for the Lochkovian and Pragian stages have an unprecedented precision, with reduction in the uncertainty by a factor of 1.7 for the Lochkovian and of ∼6 for the Pragian. Furthermore, longer orbital modulation cycles are also identified with periodicities of ∼1000 kyr and 2000-2500 kyr.

S-type rhyolites from the Tolmie Igneous Complex, Australia: deep crust origins and shallow crustal evolution

NASA Astrophysics Data System (ADS)

Clemens, J. D.; Birch, W. D.

2010-05-01

The Late Devonian Tolmie Igneous Complex, in Central Victoria, Australia, is composed mainly of Ba-rich (up to 3000 ppm) S-type rhyolite ignimbrites with SiO2 varying from 69 to 79 wt% and low Mg#s (1 to 43). Two main ignimbrite flows fill the Wabonga Caldera, the Ryans Creek and the overlying Toombullup Ignimbrites, totalling 750 to 1000 km3 in volume. The tectonic environment is late post-tectonic continental extension, with rifting and normal faulting. However, the volcanism was unimodal, without associated mafic lavas or pyroclastic rocks. Devonian red-beds underlie the Complex, Carboniferous, red-bed basins overlie the volcanic rocks, and some mafic lavas are present in the overlying red-bed sequences. The presence of almandine-rich garnet phenocrysts with rutile, in the Ryans Creek, implies minimum pressures of magma generation of 0.9 - 1.0 GPa. The Toombullup Ignimbrite contains two generations of garnet phenocrysts and three of orthopyroxene. Grt+Opx assemblages in the Toombullup imply early magmatic temperatures near 1000 ° C. The early phenocryst assemblage of Grt+Opx+Pl+Qtz constrains early magmatic crystallisation to around 0.4 GPa. Later Grt+Opx+Crd+Pl+Bt+Qtz assemblages suggest crystallisation at around 0.3 GPa and 750 to 800 ° C. The presence of ferroan Opx+Fa as late microphenocrysts suggest continued crystallisation at around 0.15 GPa and 800 ° C. Thus the magmas may were generated by high-T contact anatectic partial melting of Ba-enriched quartzofeldspathic metasediments near the base of the continental crust, during extension and mantle upwelling. There is then a record of partial crystallisation during ascent to shallow crustal pressures, where the felsic magmas evolved and interacted prior to eruption. Geochemical variations in the Complex suggest that there are at least 3 separate magma groups. Mafic-felsic magma mixing and restite unmixing can be ruled out as processes responsible for the variation. The chemistry of the magmas is interpreted to be the result of a complex interplay between partial melting of heterogeneous source rocks, variable entrainment of peritectic phases formed during the melting reactions and some crystal fractionation involving garnet, orthopyroxene, plagioclase and accessory minerals (Ap, Mon, Ilm, Zrn). The implication of these rocks for the local geology is that pre-Palaeozoic supracrustal rocks must have been carried to the base of the crust but escaped high-grade metamorphism and partial melting for 100s of millions of years after the orogenic events that brought them to those depths.

The potential source of lead in the Permian Kupferschiefer bed of Europe and some selected Paleozoic mineral deposits in the Federal Republic of Germany

USGS Publications Warehouse

Wedepohl, K.H.; Delevaux, M.H.; Doe, B.R.

1978-01-01

New lead isotopic compositions have been measured for Paleozoic bedded and vein ore deposits of Europe by the high precision thermal emission (triple filament) technique. Eleven samples have been analyzed from the Upper Permian Kupferschiefer bed with representatives from Poland to England, three samples from the Middle Devonian Rammelsberg deposit and one from the Middle Devonian Meggen deposit, both of which are conformable ore lenses and are in the Federal Republic of Germany (FRG); and also two vein deposits from the FRG were analyzed, from Ramsbeck in Devonian host rocks and from Grund in Carboniferous host rocks. For Kupferschiefer bed samples from Germany, the mineralization is of variable lead isotopic composition and appears to have been derived about 250 m.y. ago from 1700 m.y. old sources, or detritus of this age, in Paleozoic sedimentary rocks. Samples from England, Holland, and Poland have different isotopic characteristics from the German samples, indicative of significantly different source material (perhaps older). The isotopic variability of the samples from the Kupferschiefer bed in Germany probably favors the lead containing waters coming from shoreward (where poor mixing is to be expected) rather than basinward (where better mixing is likely) directions. The data thus support the interpretation of the metal source already given by Wedepohl in 1964. Data on samples from Rammelsberg and Meggen tend to be slightly less radiogenic than for the Kupferschiefer, about the amount expected if the leads were all derived from the same source material but 100 to 150 m.y. apart in time. The vein galena from Ramsbeck is similar to that from Rammelsberg conformable ore lenses, both in rocks of Devonian age; vein galena from Grund in Upper Carboniferous country rocks is similar to some bedded Kupferschiefer mineralization in Permian rocks, as if the lead composition was formed at about the same time and from similar source material as the bedded deposits. Although heat has played a more significant role in the formation of some of these deposits (veins and Rammelsberg-Meggen) than in others (Kupferschiefer), there is no indication of radically different sources for the lead, all apparently coming from sedimentary source material containing Precambrian detritus. One feldspar lead sample from the Brocken-Oker Granite is not the same in isotopic composition as any of the ores analyzed. ?? 1978 Springer-Verlag.

Newly identified "Tunnunik" impact structure, Prince Albert Peninsula, northwestern Victoria Island, Arctic Canada

NASA Astrophysics Data System (ADS)

Dewing, Keith; Pratt, Brian R.; Hadlari, Thomas; Brent, Tom; BÉDard, Jean; Rainbird, Robert H.

2013-02-01

Regional geological mapping of the glaciated surface of northwestern Victoria Island in the western Canadian Arctic revealed an anomalous structure in otherwise flat-lying Neoproterozoic and lower Paleozoic carbonate rocks, located south of Richard Collinson Inlet. The feature is roughly circular in plan view, approximately 25 km in diameter, and characterized by quaquaversal dips of approximately 45°, decreasing laterally. The core of the feature also exhibits local vertical dips, low-angle reverse faults, and drag folds. Although brecciation was not observed, shatter cones are pervasive in all lithologies in the central area, including 723 Ma old dikes that penetrate Neoproterozoic limestones. Their abundance decreases distally, and none was observed in surrounding, horizontally bedded strata. This circular structure is interpreted as a deeply eroded meteorite impact crater of the complex type, and the dipping strata as the remnants of the central uplift. The variation in orientation and shape of shatter cones point to variably oriented stresses with the passage of the shock wave, possibly related to the presence of pore water in the target strata as well as rock type and lithological heterogeneities, especially bed thickness. Timing of impact is poorly constrained. The youngest rocks affected are Late Ordovician (approximately 450 Ma) and the impact structure is mantled by undisturbed postglacial sediments. Regional, hydrothermal dolomitization of the Ordovician limestones, possibly in the Late Devonian (approximately 360 Ma), took place before the impact, and widespread WSW-ENE-trending normal faults of probable Early Cretaceous age (approximately 130 Ma) apparently cross-cut the impact structure.

The Bolivian source rocks: Sub Andean Zone-Madre de Dios-Chaco

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moretti, I.; Montemurro, G.; Aguilera, E.

A complete study of source rocks has been carried out in the Bolivian foothills and foreland (Sub Andean Zone, Chaco and Madre de Dios) in order to quantify the petroleum potential of the area. Besides the classical mid-Devonian source rocks (Tequeje Formation in the north, Limoncito Formation in the center and Los Monos Formation in the south), others are important: the Tomachi Formation (late Devonian) in the north and the Copacabana Formation (Upper Carboniferous-lower Permian) in the northern Sub Andean Zone. Both show an excellent potential with S{sub 2} over 50 mg HC/g and average values higher than 10 mgmore » HC/g over few hundred meters. The Latest Cretaceous Flora Formation present locally a high potential but is very thin. Almost all the source rocks matured during the Neogene due to the subsidence in the Andean foreland and in the piggyback basins, and are thus involved on the current petroleum system. Silurian and Lower Paleozoic units also contain thick shale beds, but these source rocks were mature before the Jurassic in the south of the country. In the center, the Silurian is not nowadays overmature and may play an important role. The different zones are compared based on their Source Potential Index which indicates that the richest areas are the northern Sub Andean Zone and the Madre de Dios basin with SPI greater than 10 t/m{sup 2}. Since these two areas remain almost unexplored, these results allow us to be optimistic about the possibilities for future exploration.« less

The Mesozoic and Palaeozoic granitoids of north-western New Guinea

NASA Astrophysics Data System (ADS)

Jost, Benjamin M.; Webb, Max; White, Lloyd T.

2018-07-01

A large portion of the Bird's Head Peninsula of NW New Guinea is an inlier that reveals the pre-Cenozoic geological history of the northern margin of eastern Gondwana. The peninsula is dominated by a regional basement high exposing Gondwanan ('Australian') Palaeozoic metasediments intruded by Palaeozoic and Mesozoic granitoids. Here, we present the first comprehensive study of these granitoids, including field and petrographic descriptions, bulk rock geochemistry, and U-Pb zircon age data. We further revise and update previous subdivisions of granitoids in the area. Most granitoids were emplaced as small to medium-scale intrusions during two episodes in the Devonian-Carboniferous and the Late Permian-Triassic, separated by a period of apparent magmatic quiescence. The oldest rocks went unrecognised until this study, likely due to the younger intrusive events resetting the K-Ar isotopic system used in previous studies. Most of the Palaeozoic and Mesozoic granitoids are peraluminous and in large parts derived from partial melts of the country rock. This is corroborated by local migmatites and country rock xenoliths. Although rare, metaluminous and mafic rocks show that partial melts of mantle-derived material played a minor role in granitoid petrogenesis, especially during the Permian-Triassic. The Devonian-Carboniferous granitoids and associated volcanics are locally restricted, whereas the Permian-Triassic intrusions are found across NW New Guinea and further afield. The latter were likely part of an extensive active continental margin above a subduction system spanning the length of what is now New Guinea and potentially extending southward through eastern Australia and Antarctica.

Cyclic and secular variation in microfossil biomineralization: clues to the biogeochemical evolution of Phanerozoic oceans

NASA Astrophysics Data System (ADS)

Martin, Ronald E.

1995-06-01

The stratigraphic occurrence and mineralogy of major protistan microfossil taxa tend to reflect evolutionary innovation in response to ocean chemistry and fertility. In foraminefera, the characteristic test composition—and, in some cases, ultrastructure—of each suborder is indicative of the degree of surface ocean CaCO 3 saturation, which varied in a cyclic manner through the Phanerozoic, at the time of origin of the suborder. High dissolved phosphate and low CaCO 3 saturation in late Precambrian-Early Cambrian surface waters may have prevented calcification in primitive non-calcareous (organic, agglutinated) foraminiferal stocks. Scattered reports of coccolithophorid-like microfossils from the Paleozoic are indicative of a secular trend in rising nutrient levels and marine productivity that controlled the initiation of calcareous oozes. Based on acritarch, carbon isotope, and phosphorite records, extremely low nutrient levels ("superligotrophic" conditions) in Cambrian-to-Devonian seas typically limited population densities of calcareous nannoplankton and prevented the formation of calcareous oozes. The overall "superoligotrophic" surface conditions of the Paleozoic were punctuated, though, by episodes of "catastrophic" eutrophication in the Late Ordovician, Late Devonia, and Late Carboniferous (Worsley et al., 1986). Following each episode, CaCO 3 rain rates were presumably enhanced because Marine C:P (MCP) burial ratios increased permanently above previous levels (Worsley et al., 1986). Nevertheless, it was not until the Carboniferous that the CCD had deepened sufficiently (via erosion of cratonic limestones) to allow pelagic calcareous oozes to begin to accumulate. Prior to this time, surface waters appear to have been sufficiently corrosive (high atmospheric pCO 2 and low CaCO 3 saturation), and the CCD sufficiently shallow, to dissolve virtually all incipient calcareous nannofossils. Following Late Permian extinctions, plankton re-expanded in response to both eustatic sea level rise (increased habitat availability) and increased nutrient levels ("mesotrophic" conditions). As organic matter (C org) and CaCO 3 rain rates increased, bioturbation rates also increased, thereby recycling nutrients back to the surface and accentuating productivity and calcareous ooze formation. MCP episodes further accelerated nutrient cycling and productivity in the Neogene, as indicated by the expansion of diatoms, which prefer nutrient-rich ("eutrophic") conditions. Ironically, while permanently increasing C:P burial ratios and productivity through the Phanerozoic, catastrophic fluctuations in nutrient levels may have also exacerbated mass extinctions via shortening of pelagic food chains. Nevertheless, re-expansion of the marine biosphere following each extinction episode resulted in a secular trend of increasing biomass and biotic diversity that may have contributed to the decline in background extinction rates through the Phanerozoic.

Discovery of the fossiliferous Cu Brei Formation (Lower Devonian) in the Kon Tum Block (South Viet Nam)

NASA Astrophysics Data System (ADS)

Thanh, Tong-Dzuy; Duyen, Than Duc; Hung, Nguyen Huu; My, Bui Phu

2007-01-01

Lower Devonian corals and stromatoporoids have recently been discovered in limestones among low grade metamorphic rocks on the western margin of the Kon Tum Block (South Viet Nam). This unit has been identified as the Cu Brei Formation. Coral and stromatoporoid species have been described including Squameofavosites aff. spongiosus, Parallelostroma cf. multicolumnum, Amphipora cf. rasilis, A. cf. raritalis, Simplexodictyon cf. artyschtense, Stromatopora cf. boriarchinovi and Stromatopora sp. indet. The Cu Brei Formation is exposed in a small area 6 km in length and 3 km wide at the foot of Cu Brei Mountain (Sa Thay District, Kon Tum Province). As this formation is in marine shelf facies it is probable that further exposures of Lower Devonian sediments may be discovered in the Kon Tum Block. This discovery raises the question of the tectonic history of the metamorphic Kon Tum Block. It is possible that the block was not an area of positive uplift from the beginning of Paleozoic as has been supposed, but was submerged in a marine environment, at least on its outer margins, in the Devonian, and possibly even earlier, in Early Paleozoic.

Late Devonian (Frasnian) phyllopod and phyllocarid crustacean shields from Belgium reinterpreted as ammonoid anaptychi

NASA Astrophysics Data System (ADS)

Goolaerts, Stijn; Denayer, Julien; Mottequin, Bernard

2017-12-01

The taxonomic affinities of fossils from the Frasnian succession of Belgium previously described as phyllopod and phyllocarid crustacean shields are discussed. The rediscovery of the holotype of Ellipsocaris dewalquei, the type species of the genus Ellipsocaris Woodward in Dewalque, 1882, allows to end the discussion on the taxonomic assignation of the genus Ellipsocaris. It is removed from the phyllopod crustaceans as interpreted originally and considered here as an ammonoid anaptychus. Furthermore, it is considered to be a junior synonym of the genus Sidetes Giebel, 1847. Similarly, Van Straelen's (1933) lower to middle Frasnian record Spathiocaris chagrinensis Ruedemann, 1916, is also an ammonoid anaptychus. Although ammonoids can be relatively frequent in some Frasnian horizons of Belgium, anaptychi remain particularly scarce and the attribution to the present material to peculiar ammonoid species is not possible.

Hydrology, water quality, and effects of drought in Monroe County, Michigan

USGS Publications Warehouse

Nicholas, J.R.; Rowe, Gary L.; Brannen, J.R.

1996-01-01

Monroe County relies heavily on its aquifers and streams for drinking water, irrigation, and other ~ses; however, increased water use, high concentrations of certain constituents in ground water, and droughts may limit the availability of water resources. Although the most densely populated parts of the county use water from the Great Lakes, large amounts of ground water are withdrawn for quarry dewatering, domestic supply, and irrigation.Unconsolidated deposits and bedrock of Silurian and Devonian age underlie Mon_roe County. The unconsolidated deposits are mostly clayey and less than 50 feet thick. Usable amounts of ground water generally are obtained from thin, discontinuous surficial sand deposits or, in the northwestern part of the county, from deep glaciofluvial deposits. In most of the county, however, ground water in unconsolidated deposits is highly susceptible to effects of droughts and to contamination.The bedrock is mostly carbonate rock, and usable quantities of ground water can be obtained from fractures and other secondary openings throughout the county. Transmissivities of the Silurian-Devonian aquifer range from 10 to 6,600 feet squared per day. Aquifer tests and historical informati.on indicate that the Silurian-Devonian aquifer is confmed throughout most of the county. The major recharge area for the Silurian-Devonian aquifer in Monroe County is in the southwest, and groundwater flow is mostly southeastward toward Lake Erie. In the northeastern and southeastern parts of the county, the potentiometric surface of the SilurianDevonian aquifers has been lowered by pumpage to below the elevation of Lake Erie.Streams and artificial drains in Monroe County are tributary to Lake Erie. Most streams are perennial because of sustained discharge from the sand aquifer and the Silurian-Devonian aquifer; however, the lower reaches of River Raisin and Plum Creek lost water to the Silurian-Devonian aquifer in July 1990.The quality of ground water and of streamwater at low flow is suitable for most domestic u~es, irrigation, and recreation. In ground water, dissolved solids and hydrogen sulfide are present at concentrations objectionable to some users. Indicators of ground-water contamination from agricultural activities-pesticides and nitrates-were not present at detectable concentrations or were below U.S. Environmental Protection Agency (USEPA) limits. In streamwater, some treatment to remove bacteria may be necessary in summer months; nitrate concentrations, however, were found to be below USEPA limits.Tritium concentrations indicative of recent recharge to the Silurian-Devonian aquifer are present in a southwest-to-northeast-trending band from Whiteford to Berlin Townships. Generally, where glacial deposits are thicker than 30 feet, rech~rge.takes more than 40 years. Carbon isotope data md1cate that some of the ground water in the Silurian-Devonian aquifer is more than 14,000 years old.Mild droughts are common in Michigan, but long severe droughts, such as those during 1930-37 and 1960-67, are infrequent. The most recent drought, during 1988, was severe but short. Ground-water levels declined throughout the county; the largest declines were probably in the southwest. Shallow bedrock wells completed in only the upper part of the Silurian-Devonian aquifer and near large uses of ground water were especially susceptible to the effects of drought. Deep bedrock wells continued to produce water through the drought of 1988.During droughts, streamflow is reduced because of low ground-water levels and high consumptive uses of surface water. In 1988, annual discharge on the River Raisin was near normal, but monthly averages were below normal from March through August. The quality of surface water during droughts is similar to that during normal lowflow conditions.

Discovery of a Devonian mafic magmatism on the western border of the Murzuq basin (Saharan metacraton): Paleomagnetic dating and geodynamical implications

NASA Astrophysics Data System (ADS)

Derder, M. E. M.; Maouche, S.; Liégeois, J. P.; Henry, B.; Amenna, M.; Ouabadi, A.; Bellon, H.; Bruguier, O.; Bayou, B.; Bestandji, R.; Nouar, O.; Bouabdallah, H.; Ayache, M.; Beddiaf, M.

2016-03-01

Intraplate deformation is most often linked to major stress applied on plate margins. When such intraplate events are accompanied by magmatism, the use of several dating methods integrated within a multidisciplinary approach can bring constraints on the age, nature and source mobilized for generating the magma and in turn on the nature of the intraplate deformation. This study focuses on the large gabbro Arrikine sill (35 km in extension) emplaced within the Silurian sediments of the western margin of the Murzuq cratonic basin in southeastern Algeria. Its emplacement is dated during the early Devonian (415-400 Ma) through the determination of a reliable paleomagnetic pole by comparison with the Gondwana Apparent Polar Wander Path (APWP). This age can be correlated with deep phreatic eruptions before Pragian time thought to be at the origin of sand injections and associated circular structures in Algeria and Libya. For the sill, the K-Ar age of 325.6 ± 7.7 Ma is related to a K-rich aplitic phase that has K-enriched by more than 20% the Devonian gabbro. Laser-ICP-MS U-Pb method dates only inherited zircons mostly at c. 2030 Ma with additional ages at c. 2700 Ma and younger ones in the 766-598 Ma age range. The Arrikine sill is a high-Ti alkaline gabbro having the geochemical composition of a hawaiite akin to several intraplate continental and oceanic provinces, including the contemporaneous Aïr ring complexes province in Niger, but also to the Mauna Loa volcano in Hawaii. This peculiar composition akin to that of the contemporaneous Aïr province is in agreement with a lower Devonian age for the Arrikine sill. The lower Devonian Arrikine sill emplacement is related to a "Caledonian" transtensive reactivation of the western metacratonic boundary of the Murzuq craton. This event also generated in the Saharan platform the so-called "Caledonian unconformity" of regional extension, the Aïr ring complexes and magmatic rocks that produced sand injections. It could be related to rifting of the Hun terranes that occurred at the plate margin to the north (Stampfli and Borel, 2002, Blackey, 2008 and references therein). The mid-Carboniferous (c. 326 Ma) reactivation corresponds to Variscan compression on NW Africa generating aplitic fluids, but also to the major "Hercynian unconformity" of regional extension. The generation of the Arrikine magma is attributed to partial melting through adiabatic pressure release of uprising asthenosphere along tectonically reactivated mega-shear zones, here bordering the relictual Murzuq craton enclosed in the Saharan metacraton.

The composition of fluid inclusions in ore and gangue minerals from the Silesian-Cracow Mississippi Valley-type Zn-Pb deposits Poland: Genetic and environmental implications

USGS Publications Warehouse

Viets, J.G.; Hofstra, A.H.; Emsbo, P.; Kozlowski, A.

1996-01-01

The composition of fluids extracted from ore and gangue sulfide minerals that span most of the paragenesis of the Silesian-Cracow district was determined using a newly developed ion chromatographic (IC) technique. Ionic species determined were Na+, NH+4, Ca2+, Mg2+, K+, Rb+, Sr2+, Ba2+, Cl-, Br-, F-, I-, PO3-4, CO2-3, HS-, S2O2-3, SO2-4, NO-3, and acetate. Mineral samples included six from the Pomorzany mine and one from the Trzebionka mine which are hosted in the Triassic Muschelkalk Formation, and two samples of drill core from mineralized Upper Devonian strata. Nine paragenetically identifiable sulfide minerals occur throughout the Silesian-Cracow district. These include from earliest to latest: early iron sulfides, granular sphalerite, early galena, light-banded sphalerite, galena, dark-banded sphalerite, iron sulfides, late dark-banded sphalerite with late galena, and late iron sulfides. Seven of the minerals were sampled for fluid inclusion analysis in this study. Only the early iron sulfides and the last galena stage were not sampled. Although the number of analyses are limited to nine samples and two replicates and there is uncertainty about the characteristics of the fluid inclusions analyzed, the data show clear temporal trends in the composition of the fluids that deposited these minerals. Fluid inclusions in minerals deposited later in the paragenesis have significantly more K+, Br-, NH+4, and acetate but less Sr2+ than those deposited earlier in the paragenesis. The later minerals are also characterized by isotopically lighter sulfur and significantly more Tl and As in the solid minerals. The change in ore-fluid chemistry is interpreted to reflect a major change in the hydrologic regime of the district. Apparently, the migrational paths of ore fluids from the Upper Silesian basin changed during ore deposition and the fluids which deposited early minerals reacted with aquifers with very different geochemical characteristics than those that deposited late minerals. The early fluids may have reacted primarily with Devonian and Lower Carboniferous carbonate aquifers deeper in the basin, whereas the later fluids appear to have had extensive contact with organic-rich rocks, probably the shallower Middle and Upper Carboniferous flysch associated with coal measures. High concentrations of toxic Tl and As occur in the readily oxidized marcasite and pyrite minerals deposited by the later fluids. In general, the geochemistry of both the early and late fluids may be explained by an evaporite related origin or by water-rock modification of a saline basinal brine. When compared to the composition of fluid inclusions in Mississippi Valley-type (MVT) ore minerals from the Ozark region of the United States, fluid inclusions in minerals from Silesian-Cracow are fundamentally different, containing more Ca2+, Mg2+, NH+4, Br-, Sr2+ and acetate in all mineral stages with significantly more K+ in later stage minerals. The differences in ore fluid chemistry between the two regions are consistent with the lithologic differences of the respective basins thought to be the source of the mineralizing brines.

The evolution of Phanerozoic seawater - Isotope paleothermometry finds consensus on Early Paleozoic warmth and constant seawater δ18O

NASA Astrophysics Data System (ADS)

Grossman, E. L.; Henkes, G. A.; Passey, B. H.; Shenton, B.; Yancey, T. E.; Perez-Huerta, A.

2015-12-01

Evolution of metazoan life is closely linked to the Phanerozoic evolution of ocean temperatures and chemistry. Oxygen isotopic evidence for early Phanerozoic paleotemperatures has been equivocal, with decreasing δ18O values with age being interpreted as warmer early oceans, decreasing seawater δ18O with age, or increasing diagenetic alteration in older samples. Here we compare an updated compilation of oxygen isotope data for carbonate and phosphate fossils and microfossils (Grossman, 2012, Geol. Time Scale, Elsevier, 195-220) with a compilation of new and existing clumped isotope data. Importantly, these data are curated based on sample preservation with special consideration given to screening techniques, and tectonic and burial history. Burial history is critical in the preservation of carbonate clumped isotope temperatures in particular, which can undergo reordering in the solid state. We use a model derived for reordering kinetics (Henkes et al., 2014, Geochim. Cosmochim. Acta 139:362-382) to screen clumped isotope data for the effects of solid-state burial alteration. With minor but significant exceptions (Late Cretaceous, Early Triassic), average δ18O values (4 m.y. window, 2 m.y. steps) for post-Devonian brachiopods, belemnites, and foraminifera, representing tropical-subtropical surface ocean conditions, yield average isotopic temperatures below 30°C (assuming a seawater δ18O value [ -1‰ VSMOW] of an "ice-free" world). In contrast, Ordovician to Devonian data show sustained temperatures of 35-40°C. Likewise, isotopic paleotemperatures from conodont apatite, known to be resistant to isotopic exchange, follow the same pattern. Clumped isotope data derived from Paleozoic brachiopod shells that experienced minimal burial (< 100 °C) and <1% reordering according to the taxon-specific clumped isotope reordering model yield typical temperatures of 25-30°C for the Carboniferous, and 35-40°C for the Ordovician-Silurian. Inserting clumped temperatures and δ18O values into the oxygen isotopic paleotemperature equation yields a mean seawater δ18O of -0.7 ± 1.4‰ for the Phanerozoic. Collectively, these findings argue for extremely warm early Paleozoic oceans, and constant seawater δ18O throughout the last ~450 million years.

Alligator ridge district, East-Central Nevada: Carlin-type gold mineralization at shallow depths

USGS Publications Warehouse

Nutt, C.J.; Hofstra, A.H.

2003-01-01

Carlin-type deposits in the Alligator Ridge mining district are present sporadically for 40 km along the north-striking Mooney Basin fault system but are restricted to a 250-m interval of Devonian to Mississippian strata. Their age is bracketed between silicified ca. 45 Ma sedimentary rocks and unaltered 36.5 to 34 Ma volcanic rocks. The silicification is linked to the deposits by its continuity with ore-grade silicification in Devonian-Mississippian strata and by its similar ??18O values (_e1???17???) and trace element signature (As, Sb, Tl, Hg). Eocene reconstruction indicates that the deposits formed at depths of ???300 to 800 m. In comparison to most Carlin-type gold deposits, they have lower Au/Ag, Au grades, and contained Au, more abundant jasperoid, and textural evidence from deposition of an amorphous silica precursor in jasperoid. These differences most likely result from their shallow depth of formation. The peak fluid temperature (_e1???230??C) and large ??18OH2O value shift from the meteroric water line (_e1???20???) suggest that ore fluids were derived from depths of 8 km or more. A magnetotelluric survey indicates that the Mooney Basin fault system penetrates to mid-crustal depths. Deep circulation of meteoric water along the Mooney Basin fault system may have been in response to initial uplift of the East Humboldt-Ruby Mountains metamorphic core complex; convection also may have been promoted by increased heat flow associated with large magnitude extension in the core complex and regional magmatism. Ore fluids ascended along the fault system until they encountered impermeable Devonian and Mississippian shales, at which point they moved laterally through permeable strata in the Devonian Guilmette Formation, Devonian-Mississippian Pilot Shale, Mississippian Joana Limestone, and Mississippian Chainman Shale toward erosional windows where they ascended into Eocene fluvial conglomerates and lake sediments. Most gold precipitated by sulfidation of host-rock Fe and mixing with local ground water in zones of lateral fluid flow in reactive strata, such as the Lower Devonian-Mississippian Pilot Shale.

Rifting along the northern Gondwana margin and the evolution of the Rheic Ocean: A Devonian age for the El Castillo volcanic rocks (Salamanca, Central Iberian Zone)

NASA Astrophysics Data System (ADS)

Gutiérrez-Alonso, G.; Murphy, J. B.; Fernández-Suárez, J.; Hamilton, M. A.

2008-12-01

Exposures of volcanic rocks (El Castillo) in the Central Iberian Zone near Salamanca, Spain, are representative of Paleozoic volcanic activity along the northern Gondwanan passive margin. Alkaline basalts and mafic volcaniclastic rocks of this sequence are structurally preserved in the core of the Variscan-Tamames Syncline. On the basis of the occurrence of graptolite fossils in immediately underlying strata, the El Castillo volcanics traditionally have been regarded as Lower Silurian in age. In contrast, most Paleozoic volcanic units in western Iberia are rift-related mafic to felsic rocks emplaced during the Late Cambrian-Early Ordovician, and are attributed to the opening of the Rheic Ocean. We present new zircon U-Pb TIMS data from a mafic volcaniclastic rock within the El Castillo unit. These data yield a near-concordant, upper intercept age of 394.7 ± 1.4 Ma that is interpreted to reflect a Middle Devonian (Emsian-Eifelian) age for the magmatism, demonstrating that the El Castillo volcanic rocks are separated from underlying lower Silurian strata by an unconformity. The U-Pb age is coeval with a widespread extensional event in Iberia preserved in the form of a generalized paraconformity surface described in most of the Iberian Variscan realm. However, in the inner part of the Gondwanan platform, the Cantabrian Zone underwent a major, coeval increase in subsidence and the generation of sedimentary troughs. From this perspective, the eruption age reported here probably represents a discrete phase of incipient rifting along the southern flank of the Rheic Ocean. Paleogeographic reconstructions indicate that this rifting event was coeval with widespread orogeny and ridge subduction along the conjugate northern flank of the Rheic Ocean, the so called Acadian "orogeny". We speculate that ridge subduction resulted in geodynamic coupling of the northern and southern flanks of the Rheic Ocean, and that the extension along the southern flank of the Rheic Ocean is a manifestation of slab pull along the northern flank. This scenario provides a uniform explanation for many features that form at ca. 395 Ma along the Gondwanan margin and has implications for the origin of the coeval oceanic Devonian mafic rocks currently exposed in the Variscan suture of NW Iberia.

Tracing source terranes using U-Pb-Hf isotopic analysis of detrital zircons: provenance of the Orhanlar Unit of the Palaeotethyan Karakaya subduction-accretion complex, NW Turkey

NASA Astrophysics Data System (ADS)

Ustaömer, Timur; Ayda Ustaömer, Petek; Robertson, Alastair; Gerdes, Axel

2016-04-01

Sandstones of the Late Palaeozoic-Early Mesozoic Karakaya Complex are interpreted to have accumulated along an active continental margin related to northward subduction of Palaeotethys. The age of deposition and provenance of the sandstones are currently being determined using radiometric dating of detrital zircons, coupled with dating of potential source terranes. Our previous work shows that the U-Pb-Hf isotopic characteristics of the sandstones of all but one of the main tectonostratigraphic units of the Karakaya Complex are compatible with a provenance that was dominated by Triassic and Permo-Carboniferous magmatic arc-type rocks, together with a minor contribution from Lower to Mid-Devonian igneous rocks (Ustaömer et al. 2015). However, one of the tectono-stratigraphic units, the Orhanlar Unit, which occurs in a structurally high position, differs in sedimentary facies and composition from the other units of the Karakaya Complex. Here, we report new isotopic age data for the sandstones of the Orhanlar Unit and also from an extensive, associated tectonic slice of continental metamorphic rocks (part of the regional Sakarya Terrane). Our main aim is to assess the provenance of the Orhanlar Unit sandstones in relation to the tectonic development of the Karakaya Complex as a whole. The Orhanlar Unit is composed of shales, sandstone turbidites and debris-flow deposits, which include blocks of Devonian radiolarian chert and Carboniferous and Permian neritic limestones. The sandstones are dominated by rock fragments, principally volcanic and plutonic rocks of basic-to-intermediate composition, metamorphic rocks and chert, together with common quartz, feldspar and mica. This modal composition contrasts significantly with the dominantly arkosic composition of the other Karakaya Complex sandstones. The detrital zircons were dated by the U-Pb method, coupled with determination of Lu-Hf isotopic compositions using a laser ablation microprobe attached to a multicollector-inductively coupled plasma-mass spectrometer (LA-MC-ICP-MS) at Goethe University, Frankfurt. A total of 399 U-Pb spot analyses were carried out on zircons from the sandstones of the Orhanlar Unit. 84% of the data yielded Precambrian ages, which is in marked contrast with the typical arkosic sandstones of the Karakaya Complex in which Precambrian zircons form only 10% of the population. Three zircon grains of Ladinian age suggest a maximum depositional age for the Orhanlar Unit. The most prominent zircon population is of Ediacaran-Cryogenian age (31%). The second largest population is Tonian-Stenian (22%), the third largest Cryogenian-Tonian (9%) and the fourth Devonian-Carboniferous (7%). There are also minor zircon populations of Palaeoproterozoic and Neo-Archean ages. The Precambrian zircon populations in the Orhanlar Unit sandstones are identical to those in the schists of the Sakarya continental crust (P.A. Ustaömer et al. 2012; this study). Their Hf isotope compositions also overlap, suggesting that the Sakarya continental crust could be a source for the sandstones of the Orhanlar Unit. On the other hand, the Hf(t) values of most of the Devonian and Carboniferous detrital zircons differ from those of the Devonian and Carboniferous granites that intrude the Sakarya continental crust. The Karakaya Complex as a whole appears to have been derived from two different source terranes, of which the Orhanlar Unit sandstones represent a minor, but significant component. Possible explanations are that two different source terranes already existed in the same region but that these were not exposed to erosion at the same time or, if exposed simultaneously, experienced different depositional pathways (without mixing); alternatively, the Orhanar Unit represents part of a different tectono-stratigraphic terrane from the other Karakaya Complex units, with which it was tectonically amalgamated prior to Early Jurassic deposition of a common sedimentary cover. Ustaömer PA, Ustaömer T, Robertson AHF (2012), Turkish Journal of Earth Sciences, doi:10.3906/yer-1103-1 Ustaömer T, Ustaömer PA, Robertson AHF, Gerdes A (2015), International Journal of Earth Sciences, DOI 10.1007/s00531-015-1225-8. This work was supported by TUBITAK, Project no 111R015

Geology of the Devonian black shales of the Appalachian basin

USGS Publications Warehouse

Roen, J.B.

1983-01-01

Black shales of Devonian age in the Appalachian basin are a unique rock sequence. The high content of organic matter, which imparts the characteristic lithology, has for years attracted considerable interest in the shales as a possible source of energy. Concurrent with periodic and varied economic exploitations of the black shales are geologic studies. The recent energy shortage prompted the U.S. Department of Energy through the Eastern Gas Shales Project of the Morgantown Energy Technology Center to underwrite a research program to determine the geologic, geochemical, and structural characteristics of the Devonian black shales in order to enhance the recovery of gas from the shales. Geologic studies produced a regional stratigraphic network that correlates the 15-foot sequence in Tennessee with 3,000 feet of interbedded black and gray shales in central New York. The classic Devonian black-shale sequence in New York has been correlated with the Ohio Shale of Ohio and Kentucky and the Chattanooga Shale of Tennessee and southwestern Virginia. Biostratigraphic and lithostratigraphic markers in conjunction with gamma-ray logs facilitated long range correlations within the Appalachian basin and provided a basis for correlations with the black shales of the Illinois and Michigan basins. Areal distribution of selected shale units along with paleocurrent studies, clay mineralogy, and geochemistry suggests variations in the sediment source and transport directions. Current structures, faunal evidence, lithologic variations, and geochemical studies provide evidence to support interpretation of depositional environments. In addition, organic geochemical data combined with stratigraphic and structural characteristics of the shale within the basin allow an evaluation of the resource potential of natural gas in the Devonian shale sequence.

The pre-Devonian tectonic framework of Xing'an-Mongolia orogenic belt (XMOB) in north China

NASA Astrophysics Data System (ADS)

Xu, Bei; Zhao, Pan; Wang, Yanyang; Liao, Wen; Luo, Zhiwen; Bao, Qingzhong; Zhou, Yongheng

2015-01-01

A new tectonic division of the Xing'an-Mongolia orogenic belt (XMOB) in north China has been presented according to our research and a lot of new data of tectonics, geochronology and geochemistry. Four blocks and four sutures have been recognized in the XMOB, including the Erguna (EB), Xing'an-Airgin Sum (XAB), Songliao-Hunshandake (SHB), and Jiamusi (JB), and Xinlin-Xiguitu (XXS), Xilinhot-Heihe (XHS), Mudanjiang (MS) and Ondor Sum-Yongji sutures (OYS). The framework of the XMOB is characterized by a tectonic collage of the blocks and orogenic belts between them. Different Precambrian basements have been found in the blocks, including the Neoproterozoic metamorphic rocks and plutons in the EB, the Neoproterozoic metamorphic rocks in western and eastern of segments of the XAB, Mesoproterozoic and Neoproterozoic metamorphic rocks in middle segments of the XAB, respectively, the Neoproterozoic metamorphic rocks and Mesoproterozoic volcanic rocks and plutons in the SHB, and Neoproterozoic metamorphic rocks in the JB. The XXS resulted from a northwestward subduction of the XAB beneath the EB during the Cambrian, which was followed by the forming of the XHS and OYS in the northwest and south margins of the SHB in the Silurian, respectively. The MS was caused by a westward subduction of the JB beneath the east margin of the SHB during the middle Devonian. The three Cambrian, Silurian and middle Devonian events indicate that the XMOB belongs to a pre-middle Devonian multiple orogenic belt in the Central Asian Orogenic Belt (CAOB). Forming of the XMOB suggests that the southeast part of the Paleo Asian Ocean closed before the middle Devonian.

Stable isotope analysis of Dacryoconarid carbonate microfossils: a new tool for Devonian oxygen and carbon isotope stratigraphy.

PubMed

Frappier, Amy Benoit; Lindemann, Richard H; Frappier, Brian R

2015-04-30

Dacryoconarids are extinct marine zooplankton known from abundant, globally distributed calcite microfossils in the Devonian, but their shell stable isotope composition has not been previously explored. Devonian stable isotope stratigraphy is currently limited to less common invertebrates or bulk rock analyses of uncertain provenance. As with Cenozoic planktonic foraminifera, isotopic analysis of dacryoconarid shells could facilitate higher-resolution, geographically widespread stable isotope records of paleoenvironmental change, including marine hypoxia events, climate changes, and biocrises. We explored the use of Dacryoconarid isotope stratigraphy as a viable method in interpreting paleoenvironments. We applied an established method for determining stable isotope ratios (δ(13) C, δ(18) O values) of small carbonate microfossils to very well-preserved dacryoconarid shells. We analyzed individual calcite shells representing five common genera using a Kiel carbonate device coupled to a MAT 253 isotope ratio mass spectrometer. Calcite shell δ(13) C and δ(18) O values were compared by taxonomic group, rock unit, and locality. Single dacryoconarid calcite shells are suitable for stable isotope analysis using a Kiel-IRMS setup. The dacryoconarid shell δ(13) C values (-4.7 to 2.3‰) and δ(18) O values (-10.3 to -4.8‰) were consistent across taxa, independent of shell size or part, but varied systematically through time. Lower fossil δ(18) O values were associated with warmer water temperature and more variable δ(13) C values were associated with major bioevents. Dacryoconarid δ(13) C and δ(18) O values differed from bulk rock carbonate values. Dacryoconarid individual microfossil δ(13) C and δ(18) O values are highly sensitive to paleoenvironmental changes, thus providing a promising avenue for stable isotope chemostratigraphy to better resolve regional to global paleoceanographic changes throughout the upper Silurian to the upper Devonian. Our results warrant further exploration of dacryoconarid stable isotope proxy sensitivity, the isotopic contrast among dacryoconarids, other taxa, and bulk rock, as well as other potential dacryoconarid proxies (Mg/Ca, Sr/Ca, (87) Sr/(86) Sr, microlaser and ion microprobe isotope techniques, and clumped isotopes) for stratigraphic research. Copyright © 2015 John Wiley & Sons, Ltd.

Sulfur-, oxygen-, and carbon-isotope studies of Ag-Pb-Zn vein-breccia occurrences, sulfide-bearing concretions, and barite deposits in the north-central Brooks Range, with comparisons to shale-hosted stratiform massive sulfide deposits: A section in Geologic studies in Alaska by the U.S. Geological Survey, 1998

USGS Publications Warehouse

Kelley, Karen D.; Leach, David L.; Johnson, Craig A.

2000-01-01

Stratiform shale-hosted massive sulfide deposits, sulfidebearing concretions and vein breccias, and barite deposits are widespread in sedimentary rocks of Late Devonian to Permian age in the northern Brooks Range. All of the sulfide-bearing concretions and vein breccias are hosted in mixed continental-marine clastic rocks of the Upper Devonian to Lower Mississippian Endicott Group. The clastic rocks and associated sulfide occurrences underlie chert and shale of Mississippian-Pennsylvanian(?) age that contain large stratiform massive sulfide deposits like that at Red Dog. The relative stratigraphic position of the vein breccias, as well as previously published mineralogical, geochemical, and lead-isotope data, suggest that the vein breccias formed coevally with overlying shale-hosted massive sulfide deposits and that they may represent pathways of oreforming hydrothermal fluids. Barite deposits are hosted either in Mississippian chert and limestone (at essentially the same stratigraphic position as the shale-hosted massive sulfide deposits) or Permian chert and shale. Although most barite deposits have no associated base-metal mineralization, barite occurs with massive sulfide deposits at the Red Dog deposit.Galena and sphalerite from most vein breccias have δ34S values from –7.3 to –0.7‰ (per mil) and –5.1 to 3.6‰, respectively; sphalerite from sulfide-bearing concretions have δ34S values of 0.7 and 4.7‰. This overall range in δ34S values largely overlaps with the range previously determined for galena and sphalerite from shale-hosted massive sulfide deposits at Red Dog and Drenchwater. The Kady vein-breccia occurrence is unusual in having higher δ34S values for sphalerite (12.1 to 12.9‰) and pyrite (11.3‰), consistent with previously published values for the shale-hosted Lik deposit. The correspondence in sulfur isotopic compositions between the stratiform and vein-breccia deposits suggests that they share a common source of reduced sulfur, or derived reduced sulfur by similar geochemical processes. Most likely, the reduced sulfur was derived by biogenic sulfate reduction (BSR) or thermochemical sulfate reduction (TSR) of seawater sulfate during Devonian-Mississippian time.The δ18O values of quartz from the vein breccias are between 16.6 and 19.9‰. Using the sphalerite-galena sulfur isotopic temperature of 188°±25°C, the calulated hydrothermal fluids had δ18O values of 4.2 to 7.5‰. The calculated range of δ18O values of the fluids is similar to that of pore fluids in equilibrium with sedimentary rocks during diagenesis at 100°– 190°C.

Stratigraphy, depositional environments, and carbonate petrology of the Toroweap and Kaibab Formations (lower Permian), Grand Canyon region, Arizona

NASA Astrophysics Data System (ADS)

Clark, R. A.

Sediments deposited in northwestern Arizona during Late Leonardian and Early Guadalupian (Permian) were controlled chiefly by an arid climate and the tectonic setting. Eastward thrusting of eugeosynclinal rocks onto miogeosynclinal deposits during Middle Devonian to Early Mississippian had a major influence on shelf sedimentation. The Toroweap and Kaibab formations represent two such platform sequences of northwestern Arizona and southern Utah deposited during this phase of sedimentation. The Toroweap Formation is subdivided into three members and represents sediments deposited during initial transgression, maximum extent of the sea, and regression (Seligman, Brady Canyon, and Woods Ranch members respectively). The Fossil Mountain Member of the Kaibab Formation documents the most extensive phase of sedimentation for all members of the Toroweap and Kaibab formations. The Harrisburg Member documents the final phase of sedimentation at the close of the Paleozoic Era.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Potter, P.E.; Maynard, J.B.; Pryor, W.A.

Studies of shales in the Appalachian area are reported (mainly in the form of abstracts of reports or manuscripts). They discuss the geology, lithology, stratigraphy, radioactivity, organic matter, the isotopic abundance of carbon and sulfur isotopes, etc. of shales in this area with maps. One report discusses Devonian paliocurrents in the central and northern Appalachian basin. Another discusses sedimentology of the Brallier Formation. The stratigraphy of upper Devonian shales along the southern shore of Lake Erie was also studied. (LTN)

Subsurface stratigraphy of upper Devonian clastics in southern West Virginia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Neal, D.W.; Patchen, D.G.

Studies of upper Devonian shales and siltstones in southern West Virginia have resulted in a refinement of the stratigraphic framework used in characterizing the gas-producing Devonian shales. Gamma-ray log correlation around the periphery of the Appalachian Basin has extended the usage of New York stratigraphic nomenclature for the interval between the base of the Dunkirk shale and the top of the Tully limestone to southern West Virginia. Equivalents of the Dunkirk shale and younger rocks of New York are recognized in southwestern West Virginia and are named according to Ohio usage. Gas production is primarily from the basal black shalemore » member of the Ohio shale. Gas shows from older black shale units (Rhinestreet and Marcellus shales) are recorded from wells east of the major producing trend. Provided suitable stimulation techniques can be developed, these older and deeper black shales may prove to be another potential gas resource.« less

World class Devonian potential seen in eastern Madre de Dios basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, K.E.; Wagner, J.B.; Carpenter, D.G.

The Madre de Dios basin in northern Bolivia contains thick, laterally extensive, organic-rich Upper Devonian source rocks that reached the oil-generative stage of thermal maturity after trap and seal formation. Despite these facts, less than one dozen exploration wells have been drilled in the Madre de Dios basin, and no significant reserves have been discovered. Mobil geoscientists conducted a regional geological, geophysical, and geochemical study of the Madre de Dios basin. The work reported here was designed to assess the distribution, richness, depositional environment, and thermal maturity of Devonian source rocks. It is supported by data from over 3,000 mmore » of continuous slimhole core in two of the five Mobil wells in the basin. Source potential also exists in Cretaceous, Mississippian, and Permian intervals. The results of this study have important implications for future exploration in Bolivia and Peru.« less

Benefits of applying technology to Devonian shale wells. Topical report, July-December 1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

Voneiff, G.W.; Gatens, J.M.

1993-01-01

The report summarizes the benefits of applying technology to Devonian Shales wells in the Appalachian Basin. The results of the work suggest that an intermediate level of technology application, with an incremental cost of $6,700/well, is best for routine application in the Devonian Shales. The technology level uses conventional well tests, rock mechanical properties logs, a borehole camera, and a moderate logging suite. Most of these tools and technologies should be used on only a portion of the wells in multi-well projects, reducing the per well cost of the technology. Determining the correct reservoir description is critical to optimizing themore » stimulation treatment. The most critical reservoir properties are bulk and matrix permeabilities, net pay, stress profile, and natural fracture spacing in the direction perpendicular to induced hydraulic fractures. Applying technology to improve the accuracy of the reservoir description can significantly increase well profitability.« less

Secular distribution of highly metalliferous black shales corresponds with peaks in past atmosphere oxygenation

NASA Astrophysics Data System (ADS)

Johnson, Sean C.; Large, Ross R.; Coveney, Raymond M.; Kelley, Karen D.; Slack, John F.; Steadman, Jeffrey A.; Gregory, Daniel D.; Sack, Patrick J.; Meffre, Sebastien

2017-08-01

Highly metalliferous black shales (HMBS) are enriched in organic carbon and a suite of metals, including Ni, Se, Mo, Ag, Au, Zn, Cu, Pb, V, As, Sb, Se, P, Cr, and U ± PGE, compared to common black shales, and are distributed at particular times through Earth history. They constitute an important future source of metals. HMBS are relatively thin units within thicker packages of regionally extensive, continental margin or intra-continental marine shales that are rich in organic matter and bio-essential trace elements. Accumulation and preservation of black shales, and the metals contained within them, usually require low-oxygen or euxinic bottom waters. However, whole-rock redox proxies, particularly Mo, suggest that HMBS may have formed during periods of elevated atmosphere pO2. This interpretation is supported by high levels of nutrient trace elements within these rocks and secular patterns of Se and Se/Co ratios in sedimentary pyrite through Earth history, with peaks occurring in the middle Paleoproterozoic, Early Cambrian to Early Ordovician, Middle Devonian, Middle to late Carboniferous, Middle Permian, and Middle to Late Cretaceous, all corresponding with time periods of HMBS deposition. This counter-intuitive relationship of strongly anoxic to euxinic, localized seafloor conditions forming under an atmosphere of peak oxygen concentrations is proposed as key to the genesis of HMBS. The secular peaks and shoulders of enriched Se in sedimentary pyrite through time correlate with periods of tectonic plate collision, which resulted in high nutrient supply to the oceans and consequently maximum productivity accompanying severe drawdown into seafloor muds of C, S, P, and nutrient trace metals. The focused burial of C and S over extensive areas of the seafloor, during these anoxic to euxinic periods, likely resulted in an O2 increase in the atmosphere, causing short-lived peaks in pO2 that coincide with the deposition of HMBS. As metals become scarce, particularly Mo, Ni, Se, Ag, and U, the geological times of these narrow HMBS horizons will become a future focus for exploration.

Infiltration-driven metamorphism, New England, USA: Regional CO2 fluxes and implications for Devonian climate and extinctions

NASA Astrophysics Data System (ADS)

Stewart, E. M.; Ague, Jay J.

2018-05-01

We undertake thermodynamic pseudosection modeling of metacarbonate rocks in the Wepawaug Schist, Connecticut, USA, and examine the implications for CO2 outgassing from collisional orogenic belts. Two broad types of pseudosections are calculated: (1) a fully closed-system model with no fluid infiltration and (2) a fluid-buffered model including an H2O-CO2 fluid of a fixed composition. This fluid-buffered model is used to approximate a system open to infiltration by a water-bearing fluid. In all cases the fully closed-system model fails to reproduce the observed major mineral zones, mineral compositions, reaction temperatures, and fluid compositions. The fluid-infiltrated models, on the other hand, successfully reproduce these observations when the XCO2 of the fluid is in the range ∼0.05 to ∼0.15. Fluid-infiltrated models predict significant progressive CO2 loss, peaking at ∼50% decarbonation at amphibolite facies. The closed-system models dramatically underestimate the degree of decarbonation, predicting only ∼15% CO2 loss at peak conditions, and, remarkably, <1% CO2 loss below ∼600 °C. We propagate the results of fluid-infiltrated pseudosections to determine an areal CO2 flux for the Wepawaug Schist. This yields ∼1012 mol CO2 km-2 Myr-1, consistent with multiple independent estimates of the metamorphic CO2 flux, and comparable in magnitude to fluxes from mid-ocean ridges and volcanic arcs. Extrapolating to the area of the Acadian orogenic belt, we suggest that metamorphic CO2 degassing is a plausible driver of global warming, sea level rise, and, perhaps, extinction in the mid- to late-Devonian.

Stable isotopic compositions of early calcite cements in the Middle Devonian Coralville Formation (Cedar Valley Group), eastern Iowa

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ludvigson, G.A.; Gonzalez, L.S.; Witzke, B.J.

1993-03-01

The Middle-Upper Devonian Cedar Valley Gp in Iowa is subdivided into four formations each representing a broad transgressive-regressive (T-R) cycle of deposition. Cycles consist of basal open marine facies that shallow upward into capping peritidal facies. Results from ongoing diagenetic studies of the Coralville Fm (late Givetian), the second T-R cycle of the Cedar Valley Gp, have focused attention on the origins of early cements. Early calcite cements in the Coralville Fm of Johnson County, Iowa, include blocky equant spars filling fenestral voids in birdseye limestones of the Iowa City Mbr and isopachous bladed spars that occur throughout the Coralville.more » Bladed spars fill stromatactis and microkarstic voids in the Iowa City Mbr, and sheltered voids in underlying open-marine skeletal packstones of the Cou Falls Mbr (lower Coralville cycle). The bladed spars include nonluminescent inclusion-free domains that contain up to 4,000 ppm Mg, and luminescent inclusion-rich domains that contain less than 2,000 ppm Mg. Birdseye spars have a constructive oscillatory luminescent-nonluminescent zonation controlled by Mn contents and contain less than 1,000 ppm Mg. Nonluminescent domains in bladed spars have the heaviest oxygen isotopic compositions of all components in the Coralville, similar to the isotopically heaviest nonluminescent brachiopods but have [delta][sup 13]C values ranging from [minus]3 to [minus]5 [per thousand]. They are interpreted to have precipitated from marine fluids saturated by CO[sub 2] produced from bacterial oxidation of organic matter. Altered luminescent domains in the bladed spars have the same [delta][sup 13]C compositions, but have widely varying [delta][sup 18]O compositions, ranging to [minus]9 [per thousand].« less

Composition, Age, and Origin of Cretaceous Granitic Magmatism on the Eastern Chukchi Peninsula

NASA Astrophysics Data System (ADS)

Luchitskaya, M. V.; Sokolov, S. D.; Pease, V.; Miller, E.; Belyatsky, B. V.

2018-05-01

New geochronological and isotopic geochemical data are given, which make it possible to recognize two types of granitic rocks on the eastern Chukchi Peninsula. Early Cretaceous Tkachen and Dolina granitic plutons with zircon ages (U-Pb SIMS) of 119-122 and 131-136 Ma are related to the first type. They cut through Devonian-Lower Carboniferous basement rocks and are overlain by the Aptian-Albian Etelkuyum Formation. Basal units of the latter contain fragments of granitic rocks. Late Cretaceous Provideniya and Rumilet granitic plutons, which contain zircons with ages of 94 and 85 Ma (U-Pb SIMS), respectively, belong to the second type. They cut through volcanic-sedimentary rocks of the Etelkuyum and Leurvaam formations pertaining to the Okhotsk-Chukotka Volcanic Belt. In petrographic and geochemical features, the Early Cretaceous granitic rocks of the Tkachen Pluton are commensurable with I-type granites, while Late Cretaceous granite of the Rumilet Pluton is comparable to A2-type granite. The Sr-Nd isotopic data provide evidence that from the Early Cretaceous Tkachen and Dolina plutons to the Late Cretaceous Provideniya and Rumilet plutons, the degree of crustal assimilation of suprasubduction mantle-derived melts increases up to partial melting of heterogeneous continental crust enriched in rubidium. An unconformity and various degrees of secondary alteration of volcanic-sedimentary rocks have been established in the Okhotsk-Chukotka Volcanic Belt, and this was apparently caused by transition of the tectonic setting from suprasubduction to a transform margin with local extension.

Tectonics and hydrocarbon potential of the Barents Megatrough

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baturin, D.; Vinogradov, A.; Yunov, A.

1991-08-01

Interpretation of geophysical data shows that the geological structure of the Eastern Barents Shelf, named Barents Megatrough (BM), extends sublongitudinally almost from the Baltic shield to the Franz Josef Land archipelago. The earth crust within the axis part of the BM is attenuated up to 28-30 km, whereas in adjacent areas its thickness exceeds 35 km. The depression is filled with of more than 15 km of Upper Paleozoic, Mesozoic, and Cenozoic sediments overlying a folded basement of probable Caledonian age. Paleozoic sediments, with exception of the Upper Permian, are composed mainly of carbonates and evaporites. Mesozoic-Cenozoic sediments are mostlymore » terrigenous. The major force in the development of the BM was due to extensional tectonics. Three rifting phases are recognizable: Late Devonian-Early Carboniferous, Early Triassic, and Jurassic-Early Cretaceous. The principal features of the geologic structure and evolution of the BM during the late Paleozoic-Mesozoic correlate well with those of the Sverdup basin, Canadian Arctic. Significant quantity of Late Jurassic-Early Cretaceous basaltic dikes and sills were intruded within Triassic sequence during the third rifting phase. This was probably the main reason for trap disruption and hydrocarbon loss from Triassic structures. Lower Jurassic and Lower Cretaceous reservoir sandstones are most probably the main future objects for oil and gas discoveries within the BM. Upper Jurassic black shales are probably the main source rocks of the BM basin, as well as excellent structural traps for hydrocarbon fluids from the underlying sediments.« less

Disparity changes in 370 Ma Devonian fossils: the signature of ecological dynamics?

PubMed

Girard, Catherine; Renaud, Sabrina

2012-01-01

Early periods in Earth's history have seen a progressive increase in complexity of the ecosystems, but also dramatic crises decimating the biosphere. Such patterns are usually considered as large-scale changes among supra-specific groups, including morphological novelties, radiation, and extinctions. Nevertheless, in the same time, each species evolved by the way of micro-evolutionary processes, extended over millions of years into the evolution of lineages. How these two evolutionary scales interacted is a challenging issue because this requires bridging a gap between scales of observation and processes. The present study aims at transferring a typical macro-evolutionary approach, namely disparity analysis, to the study of fine-scale evolutionary variations in order to decipher what processes actually drove the dynamics of diversity at a micro-evolutionary level. The Late Frasnian to Late Famennian period was selected because it is punctuated by two major macro-evolutionary crises, as well as a progressive diversification of marine ecosystem. Disparity was estimated through this period on conodonts, tooth-like fossil remains of small eel-like predators that were part of the nektonic fauna. The study was focused on the emblematic genus of the period, Palmatolepis. Strikingly, both crises affected an already impoverished Palmatolepis disparity, increasing risks of random extinction. The major disparity signal rather emerged as a cycle of increase and decrease in disparity during the inter-crises period. The diversification shortly followed the first crisis and might correspond to an opportunistic occupation of empty ecological niche. The subsequent oriented shrinking in the morphospace occupation suggests that the ecological space available to Palmatolepis decreased through time, due to a combination of factors: deteriorating climate, expansion of competitors and predators. Disparity changes of Palmatolepis thus reflect changes in the structure of the ecological space itself, which was prone to evolve during this ancient period where modern ecosystems were progressively shaped.

Early Paleozoic tectonic reconstruction of Iran: Tales from detrital zircon geochronology

NASA Astrophysics Data System (ADS)

Moghadam, Hadi Shafaii; Li, Xian-Hua; Griffin, William L.; Stern, Robert J.; Thomsen, Tonny B.; Meinhold, Guido; Aharipour, Reza; O'Reilly, Suzanne Y.

2017-01-01

In this study we use detrital zircons to probe the Early Paleozoic history of NE Iran and evaluate the link between sediment sources and Gondwanan pre-Cadomian, Cadomian and younger events. U-Pb zircon ages and Hf isotopic compositions are reported for detrital zircons from Ordovician and Early Devonian sedimentary rocks from NE Iran. These clastic rocks are dominated by zircons with major age populations at 2.5 Ga, 0.8-0.6 Ga, 0.5 Ga and 0.5-0.4 Ga as well as a minor broad peak at 1.0 Ga. The source of 2.5 Ga detrital zircons is enigmatic; they may have been supplied from the Saharan Metacraton (or West African Craton) to the southwest or Afghanistan-Tarim to the east. The detrital zircons with age populations at 0.8-0.6 Ga probably originated from Cryogenian-Ediacaran juvenile igneous rocks of the Arabian-Nubian Shield; this inference is supported by their juvenile Hf isotopes, although some negative εHf (t) values suggest that other sources (such as the West African Craton) were also involved. The age peak at ca 0.5 Ga correlates with Cadomian magmatism reported from Iranian basement and elsewhere in north Gondwana. The variable εHf (t) values of Cadomian detrital zircons, resembling the εHf (t) values of zircons in magmatic Cadomian rocks from Iran and Taurides (Turkey), suggest an Andean-type margin and the involvement of reworked older crust in the generation of the magmatic rocks. The youngest age population at 0.5-0.4 Ga is interpreted to represent Gondwana rifting and the opening of Paleotethys, which probably started in Late Cambrian-Ordovician time. A combination of U-Pb dating and Hf-isotope data from Iran, Turkey and North Gondwana confirms that Iran and Turkey were parts of Gondwana at least until late Paleozoic time.

Disparity Changes in 370 Ma Devonian Fossils: The Signature of Ecological Dynamics?

PubMed Central

Girard, Catherine; Renaud, Sabrina

2012-01-01

Early periods in Earth's history have seen a progressive increase in complexity of the ecosystems, but also dramatic crises decimating the biosphere. Such patterns are usually considered as large-scale changes among supra-specific groups, including morphological novelties, radiation, and extinctions. Nevertheless, in the same time, each species evolved by the way of micro-evolutionary processes, extended over millions of years into the evolution of lineages. How these two evolutionary scales interacted is a challenging issue because this requires bridging a gap between scales of observation and processes. The present study aims at transferring a typical macro-evolutionary approach, namely disparity analysis, to the study of fine-scale evolutionary variations in order to decipher what processes actually drove the dynamics of diversity at a micro-evolutionary level. The Late Frasnian to Late Famennian period was selected because it is punctuated by two major macro-evolutionary crises, as well as a progressive diversification of marine ecosystem. Disparity was estimated through this period on conodonts, tooth-like fossil remains of small eel-like predators that were part of the nektonic fauna. The study was focused on the emblematic genus of the period, Palmatolepis. Strikingly, both crises affected an already impoverished Palmatolepis disparity, increasing risks of random extinction. The major disparity signal rather emerged as a cycle of increase and decrease in disparity during the inter-crises period. The diversification shortly followed the first crisis and might correspond to an opportunistic occupation of empty ecological niche. The subsequent oriented shrinking in the morphospace occupation suggests that the ecological space available to Palmatolepis decreased through time, due to a combination of factors: deteriorating climate, expansion of competitors and predators. Disparity changes of Palmatolepis thus reflect changes in the structure of the ecological space itself, which was prone to evolve during this ancient period where modern ecosystems were progressively shaped. PMID:22558396

Constraints on Earth degassing history from the argon isotope composition of Devonian atmosphere

NASA Astrophysics Data System (ADS)

Stuart, F. M.; Mark, D.

2012-04-01

The primordial and radiogenic isotopes of the noble gases combine to make them a powerful tool for determining the time and tempo of the outgassing of the Earth's interior. The outgassing history of the Earth is largely constrained from measurements of the isotopic composition of He, Ne, Ar and Xe in samples of modern mantle, crust and atmosphere. There have been few unequivocal measurement of the isotopic composition of noble gases in ancient atmosphere. We have re-visited whether ancient Ar is trapped in the ~400 Ma Rhynie chert [1]. We have analysed samples of pristine Rhynie chert using the ARGUS multi-collector mass spectrometer calibrated against the new determination of atmospheric Ar isotope ratios [2]. 40Ar/36Ar ratios are low, with many lower than the modern air value (298.8). Importantly these are accompanied by atmospheric 38Ar/36Ar ratios indicating that the low 40Ar/36Ar are not due to mass fractionation. We conclude that the Rhynie chert has captured Devonian atmosphere-derived Ar. The data indicate that the Devonian atmosphere 40Ar/36Ar was at least 3 % lower than the modern air value. Thus the Earth's atmosphere has accumulated at least 5 ± 0.2 x 1016 moles of 40Ar in the last 400 million years, at an average rate of 1.24 ± 0.06 x 108 mol 40Ar/year. This overlaps the rate determined from ice cores for the last 800,000 years [3] and implies that there has been no resolvable temporal change in Earth outgassing rate since mid-Palaeozoic times. The new data require the Earth outgassed early, and suggests that pristine samples of Archaean and Proterozoic chert may prove useful as palaeo-atmosphere tracers. [1] G. Turner, J. Geol. Soc. London 146, 147-154 (1989) [2] D. Mark, F.M. Stuart, M. de Podesta, Geochim. Cosmochim. Acta 75, 7494-7501 [3] M. Bender et al., Proc. Nat. Acad. Sci. 105, 8232-8237 (2008)

Phanerozoic polyphase orogenies recorded in the northeastern Okcheon Belt, Korea from SHRIMP U-Pb detrital zircon and K-Ar illite geochronologies

NASA Astrophysics Data System (ADS)

Jang, Yirang; Kwon, Sanghoon; Song, Yungoo; Kim, Sung Won; Kwon, Yi Kyun; Yi, Keewook

2018-05-01

We present the SHRIMP U-Pb detrital zircon and K-Ar illite 1Md/1M and 2M1 ages, suggesting new insight into the Phanerozoic polyphase orogenies preserved in the northeastern Okcheon Belt, Korea since the initial basin formation during Neoproterozoic rifting through several successive contractional orogens. The U-Pb detrital zircon ages from the Early Paleozoic strata of the Taebaeksan Zone suggest a Cambrian maximum deposition age, and are supported by trilobite and conodont biostratigraphy. Although the age spectra from two sedimentary groups, the Yeongwol and Taebaek Groups, show similar continuous distributions from the Late Paleoproterozoic to Early Paleozoic ages, a Grenville-age hiatus (1.3-0.9 Ga) in the continuous stratigraphic sequence from the Taebaek Group suggests the existence of different peripheral clastic sources along rifted continental margin(s). In addition, we present the K-Ar illite 1Md/1M ages of the fault gouges, which confirm fault formation/reactivation during the Late Cretaceous to Early Paleogene (ca. 82-62 Ma) and the Early Miocene (ca. 20-18 Ma). The 2M1 illite ages, at least those younger than the host rock ages, provide episodes of deformation, metamorphism and hydrothermal effects related to the tectonic events during the Devonian (ca.410 Ma) and Permo-Triassic (ca. 285-240 Ma). These results indicate that the northeastern Okcheon Belt experienced polyphase orogenic events, namely the Okcheon (Middle Paleozoic), Songrim (Late Paleozoic to Early Mesozoic), Daebo (Middle Mesozoic) and Bulguksa (Late Mesozoic to Early Cenozoic) Orogenies, reflecting the Phanerozoic tectonic evolution of the Korean Peninsula along the East Asian continental margin.

U-Pb detrital zircon dates and provenance data from the Beaufort Group (Karoo Supergroup) reflect sedimentary recycling and air-fall tuff deposition in the Permo-Triassic Karoo foreland basin

NASA Astrophysics Data System (ADS)

Viglietti, Pia A.; Frei, Dirk; Rubidge, Bruce S.; Smith, Roger M. H.

2018-07-01

Detrital zircon U-Pb age dating was used for provenance determination and maximum age of deposition for the Upper Permian (upper Teekloof and Balfour formations) and Lower Triassic (Katberg Formation) lithostratigraphic subdivisions of the Beaufort Group of South Africa's Karoo Basin. Ten samples were analysed using laser ablation - single collector - magnetic sectorfield - inductively coupled plasma - mass spectrometry (LA-SF-ICP-MS). The results reveal a dominant Late Carboniferous-Late Permian population (250 ± 5 Ma - 339 ± 5 Ma), a secondary Cambrian-Neoproterozoic (489 ± 5 Ma to 878 ± 24 Ma) population, a minor Mesoproterozoic (908 ± 24 Ma to 1308 ± 23) population, and minor occurrences of Devonian, Ordovician, Proterozoic and Archean zircon grains. Multiple lines of evidence (e.g. roundness and fragmentary nature of zircons, palaeo-current directions, and previous work), suggest the older zircon populations are related to sedimentary recycling in the Gondwanide Orogeny. The youngest and dominant population contain elongate euhedral grains interpreted to be directly derived from their protolith. Since zircons form in felsic igneous rocks, and no igneous rocks of Late Permian age occur in the Karoo Basin, these findings suggest significant input of volcanic material by ash falls. These results support sedimentological and palaeontological data for a Lopingian (Late Permian) age for the upper Beaufort Group, but contradict previous workers who retrieved Early Triassic dates from zircons in ashes for the Beaufort and Ecca Groups. Pb-loss not revealed by resolvable discordance on the concordia diagram, and metamictization of natural zircons are not factored into the conclusions of earlier workers.

Looking for the Kellwasser Event in all the wrong places: a multiproxy study of island arc paleoenvironments in the Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Carmichael, S. K.; Wang, Z.; Waters, J. A.; Dombrowski, A. D.; Batchelor, C. J.; Coleman, D. S.; Suttner, T.; Kido, E.

2017-12-01

The Late Devonian Frasnian-Famennian (F-F) boundary at 372 Ma is associated with the Kellwasser Event, an ocean anoxia event that is often associated with positive δ13C excursions and commonly represented by black shales. However, approximately 88% of the studies of the Kellwasser Event are based on sites from deep epicontinental basins and epeiric seas, and most of these sites are located on the Euramerican paleocontinent. In contrast to the positive δ13C excursions found in most basinal study sites, the δ13C signatures in three separate shallow water, island-arc F-F sections in the Junggar Basin in northwestern China (Wulankeshun, Boulongour Reservoir, and Genare) all show negative excursions in the stratigraphic location of the Kellwasser Event [1-3]. The δ18O values in both carbonates and/or conodont apatite likewise show negative excursions within the shallow water facies at each site, but have relatively constant signatures within the deeper water facies. 87Sr/86Sr values range from 0.70636-0.70906 at the base of the Boulongour Reservoir section and 0.70746-0.71383 at the base of the Wulankeshun section but both Sr signaures stabilize with relatively constant values closer to modeled Late Devonian seawater in deeper water and/or offshore facies. The fossil assemblages at the base of the Boulongour and Wulankeshun sections each correspond to euryhaline/brackish conditions, while microtextures in Ti-bearing phases within clastic sediments as well as isotope mixing models suggest submarine groundwater discharge signatures rather than diagenetic alteration. Preliminary framboidal pyrite distributions in these sections also show evidence for sub/dysoxic (rather than euxinic or anoxic) conditions that correspond to the stratigraphic Kellwasser interval. Positive δ13C excursions and the presence of black shales are thus not prerequisites for recognition of the Kellwasser Event, particularly in shallow water paleoenvironments that are not topographically favorable to shale accumulation and may have significant coastal groundwater or surface water inputs. [1] Suttner et al. (2014) J. of Asian Earth Sci. 80, 101-118. [2] Carmichael et al. (2014) Paleo3 399, 394-403. [3] Wang et al. (2016) Paleo3 448, 279-297.

Sandstone provenance and U-Pb ages of detrital zircons from Permian-Triassic forearc sediments within the Sukhothai Arc, northern Thailand: Record of volcanic-arc evolution in response to Paleo-Tethys subduction

NASA Astrophysics Data System (ADS)

Hara, Hidetoshi; Kunii, Miyuki; Miyake, Yoshihiro; Hisada, Ken-ichiro; Kamata, Yoshihito; Ueno, Katsumi; Kon, Yoshiaki; Kurihara, Toshiyuki; Ueda, Hayato; Assavapatchara, San; Treerotchananon, Anuwat; Charoentitirat, Thasinee; Charusiri, Punya

2017-09-01

Provenance analysis and U-Pb dating of detrital zircons in Permian-Triassic forearc sediments from the Sukhothai Arc in northern Thailand clarify the evolution of a missing arc system associated with Paleo-Tethys subduction. The turbidite-dominant formations within the forearc sediments include the Permian Ngao Group (Kiu Lom, Pha Huat, and Huai Thak formations), the Early to earliest Late Triassic Lampang Group (Phra That and Hong Hoi formations), and the Late Triassic Song Group (Pha Daeng and Wang Chin formations). The sandstones are quartzose in the Pha Huat, Huai Thak, and Wang Chin formations, and lithic wacke in the Kiu Lom, Phra That, Hong Hoi and Pha Daeng formations. The quartzose sandstones contain abundant quartz, felsic volcanic and plutonic fragments, whereas the lithic sandstones contain mainly basaltic to felsic volcanic fragments. The youngest single-grain (YSG) zircon U-Pb age generally approximates the depositional age in the study area, but in the case of the limestone-dominant Pha Huat Formation the YSG age is clearly older. On the other hand, the youngest cluster U-Pb age (YC1σ) represents the peak of igneous activity in the source area. Geological evidence, geochemical signatures, and the YC1σ ages of the sandstones have allowed us to reconstruct the Sukhothai arc evolution. The initial Sukhothai Arc (Late Carboniferous-Early Permian) developed as a continental island arc. Subsequently, there was general magmatic quiescence with minor I-type granitic activity during the Middle to early Late Permian. In the latest Permian to early Late Triassic, the Sukhothai Arc developed in tandem with Early to Middle Triassic I-type granitic activity, Middle to Late Triassic volcanism, evolution of an accretionary complex, and an abundant supply of sediments from the volcanic rocks to the trench through a forearc basin. Subsequently, the Sukhothai Arc became quiescent as the Paleo-Tethys closed after the Late Triassic. In addition, parts of sediments of supposed Devonian-Carboniferous age within the Sukhothai Arc were revised as the Triassic Lampang Group, and the Early Cretaceous Khorat Group.

Devonian salt dissolution-collapse breccias flooring the Cretaceous Athabasca oil sands deposit and development of lower McMurray Formation sinkholes, northern Alberta Basin, Western Canada

NASA Astrophysics Data System (ADS)

Broughton, Paul L.

2013-01-01

The sub-Cretaceous paleotopography underlying giant Lower Cretaceous Athabasca oil sands, northern Alberta, has an orthogonal lattice pattern of troughs up to 50 km long and 100 m deep between pairs of cross-cutting lineaments. These structures are interpreted to have been inherited from a similar pattern of dissolution collapse-subsidence troughs in the underlying Middle Devonian salt beds. Removal of more than 100 m of halite salt fragmented the overlying Upper Devonian strata into fault blocks and collapse breccias that subsided into the underlying dissolution troughs. The unusually low 1:2 to 1:3 thickness ratios of halite salts to the overlying strata resulted in the Upper Devonian strata collapse-subsidence into underlying salt dissolution troughs being more cataclysmic during the first phase of salt removal. The second phase of slower but complete salt removal between the earlier troughs resulted in a more gradual subsidence of the overlying strata. This obliterated the earlier pattern of giant cross-cutting dissolution troughs bounded by major lineaments. The collapse breccia fabrics underlying the earlier troughs differ from those from areas between the troughs. Collapse breccias underlying the large troughs often have crushed fabrics distributed in zones that rapidly pinched out between fault blocks. Breccias between troughs developed as giant mosaics of detached carbonate blocks that formed breccia pipe complexes. Multiple sinkholes up to 100 m deep aligned along multi-km linear valley trends that dissected the sub-Cretaceous paleotopography. These sinkhole trends formed orthogonal patterns inherited from underlying lattice of NW-SE and NE-SW salt structured lineaments. These cross-cutting sinkhole trends have a smaller 5 km scale reticulate pattern similar to the giant 50 km scale pattern of collapse-subsidence troughs. Other sinkholes developed as lower McMurray strata sagged when underlying Devonian fault blocks and breccia pipes differentially subsided.

Fluid evolution during burial and Variscan deformation in the Lower Devonian rocks of the High-Ardenne slate belt (Belgium): sources and causes of high-salinity and C-O-H-N fluids

NASA Astrophysics Data System (ADS)

Kenis, I.; Muchez, Ph.; Verhaert, G.; Boyce, A.; Sintubin, M.

2005-08-01

Fluid inclusions in quartz veins of the High-Ardenne slate belt have preserved remnants of prograde and retrograde metamorphic fluids. These fluids were examined by petrography, microthermometry and Raman analysis to define the chemical and spatial evolution of the fluids that circulated through the metamorphic area of the High-Ardenne slate belt. The earliest fluid type was a mixed aqueous/gaseous fluid (H2O-NaCl-CO2-(CH4-N2)) occurring in growth zones and as isolated fluid inclusions in both the epizonal and anchizonal part of the metamorphic area. In the central part of the metamorphic area (epizone), in addition to this mixed aqueous/gaseous fluid, primary and isolated fluid inclusions are also filled with a purely gaseous fluid (CO2-N2-CH4). During the Variscan orogeny, the chemical composition of gaseous fluids circulating through the Lower Devonian rocks in the epizonal part of the slate belt, evolved from an earlier CO2-CH4-N2 composition to a later composition enriched in N2. Finally, a late, Variscan aqueous fluid system with a H2O-NaCl composition migrated through the Lower Devonian rocks. This latest type of fluid can be observed in and outside the epizonal metamorphic part of the High-Ardenne slate belt. The chemical composition of the fluids throughout the metamorphic area, shows a direct correlation with the metamorphic grade of the host rock. In general, the proportion of non-polar species (i.e. CO2, CH4, N2) with respect to water and the proportion of non-polar species other than CO2 increase with increasing metamorphic grade within the slate belt. In addition to this spatial evolution of the fluids, the temporal evolution of the gaseous fluids is indicative for a gradual maturation due to metamorphism in the central part of the basin. In addition to the maturity of the metamorphic fluids, the salinity of the aqueous fluids also shows a link with the metamorphic grade of the host-rock. For the earliest and latest fluid inclusions in the anchizonal part of the High-Ardenne slate belt the salinity varies respectively between 0 and 3.5 eq.wt% NaCl and between 0 and 2.7 eq.wt% NaCl, while in the epizonal part the salinity varies between 0.6 and 17 eq.wt% NaCl and between 3 and 10.6 eq.wt% for the earliest and latest aqueous fluid inclusions, respectively. Although high salinity fluids are often attributed to the original sedimentary setting, the increasing salinity of the fluids that circulated through the Lower Devonian rocks in the High-Ardenne slate belt can be directly attributed to regional metamorphism. More specifically the salinity of the primary fluid inclusions is related to hydrolysis reactions of Cl-bearing minerals during prograde metamorphism, while the salinity of the secondary fluid inclusions is rather related to hydration reactions during retrograde metamorphism. The temporal and spatial distribution of the fluids in the High-Ardenne slate belt are indicative for a closed fluid flow system present in the Lower Devonian rocks during burial and Variscan deformation, where fluids were in thermal and chemical equilibrium with the host rock. Such a closed fluid flow system is confirmed by stable isotope study of the veins and their adjacent host rock for which uniform δ180 values of both the veins and their host rock demonstrate a rock-buffered fluid flow system.

300 million years of basin evolution - the thermotectonic history of the Ukrainian Donbas Foldbelt

NASA Astrophysics Data System (ADS)

Spiegel, C.; Danisik, M.; Sachsenhofer, R.; Frisch, W.; Privalov, V.

2009-04-01

The Ukrainian-Russian Pripyat-Dniepr-Donets Basin is a large intracratonic rift structure formed during the Late Devonian. It is situated at the southern margin of the Precambrian East European Craton, adjacent to the Hercynian Tethyan belt in the Black Sea area and the Alpine Caucasus orogen. With a sediment thickness of more than 20 km, it is one of the deepest sedimentary basins on earth. The eastern part of the Pripyat-Dniepr-Donets Basin - called Donbas foldbelt - is strongly folded and inverted. Proposed models of basin evolution are often controversial and numerous issues are still a matter of speculation, particularly the erosion history and the timing of basin inversion. Basin inversion may have taken place during the Permian related to the Uralian orogeny, or in response to Alpine tectonics during the Late Cretaceous to Early Tertiary. We investigated the low-temperature thermal history of the Donbas Foldbelt and the adjacent Ukrainian shield by a combination of zircon fission track, apatite fission track and apatite (U-Th)/He thermochronology. Although apatite fission track ages of all sedimentary samples were reset shortly after deposition during the Carboniferous, we took advantage of the fact that samples contained kinetically variable apatites, which are sensitive to different temperatures. By using statistic-based component analysis incorporating physical properties of individual grains we identified several distinct age population, ranging from late Permian (~265 Ma) to the Late Cretaceous (70 Ma). We could thus constrain the thermal history of the Donbas Foldbelt and the adjacent basement during a ~300 Myr long time period. The Precambrian crystalline basement of the Ukrainian shield was affected by a Permo-Triassic thermal event associated with magmatic activity, which also strongly heated the sediments of the Donbas Foldbelt. The basement rocks cooled to near-surface conditions during the Early to Middle Triassic and since then was thermally stable. The basin margins started to cool during the Permo-Triassic whereas the central parts were residing or slowly cooling through the apatite partial annealing zone during the Jurassic and most of the Cretaceous and eventually cooled to near-surface conditions around the Cretaceous-Paleogene boundary. Our data show that Permian erosion was lower and Mesozoic erosion larger than generally assumed. Inversion and pop-up of the Donbas Foldbelt occurred in the Cretaceous and not in the Permian as previously thought. This is indicated by overall Cretaceous apatite fission track ages in the central parts of the basin.

Phanerozoic continental growth and gold metallogeny of Asia

USGS Publications Warehouse

Goldfarb, Richard J.; Taylor, Ryan D.; Collins, Gregory S.; Goryachev, Nicolay A.; Orlandini, Omero Felipe

2014-01-01

The Asian continent formed during the past 800 m.y. during late Neoproterozoic through Jurassic closure of the Tethyan ocean basins, followed by late Mesozoic circum-Pacific and Cenozoic Himalayan orogenies. The oldest gold deposits in Asia reflect accretionary events along the margins of the Siberia, Kazakhstan, North China, Tarim–Karakum, South China, and Indochina Precambrian blocks while they were isolated within the Paleotethys and surrounding Panthalassa Oceans. Orogenic gold deposits are associated with large-scale, terrane-bounding fault systems and broad areas of deformation that existed along many of the active margins of the Precambrian blocks. Deposits typically formed during regional transpressional to transtensional events immediately after to as much as 100 m.y. subsequent to the onset of accretion or collision. Major orogenic gold provinces associated with this growth of the Asian continental mass include: (1) the ca. 750 Ma Yenisei Ridge, ca. 500 Ma East Sayan, and ca. 450–350 Ma Patom provinces along the southern margins of the Siberia craton; (2) the 450 Ma Charsk belt of north-central Kazakhstan; (3) the 310–280 Ma Kalba belt of NE Kazakhstan, extending into adjacent NW Xinjiang, along the Siberia–Kazakhstan suture; (4) the ca. 300–280 Ma deposits within the Central Asian southern and middle Tien Shan (e.g., Kumtor, Zarmitan, Muruntau), marking the closure of the Turkestan Ocean between Kazakhstan and the Tarim–Karakum block; (5) the ca. 190–125 Ma Transbaikal deposits along the site of Permian to Late Jurassic diachronous closure of the Mongol–Okhotsk Ocean between Siberia and Mongolia/North China; (6) the probable Late Silurian–Early Devonian Jiagnan belt formed along the margin of Gondwana at the site of collision between the Yangtze and Cathaysia blocks; (7) Triassic deposits of the Paleozoic Qilian Shan and West Qinling orogens along the SW margin of the North China block developed during collision of South China; and (8) Jurassic(?) ores on the margins of the Subumusu block in Myanmar and Malaysia. Circum-Pacific tectonism led to major orogenic gold province formation along the length of the eastern side of Asia between ca. 135 and 120 Ma, although such deposits are slightly older in South Korea and slightly younger in the Amur region of the Russian Southeast. Deformation related to collision of the Kolyma–Omolon microcontinent with the Pacific margin of the Siberia craton led to formation of 136–125 Ma ores of the Yana–Kolyma belt (Natalka, Sarylakh) and 125–119 Ma ores of the South Verkhoyansk synclinorium (Nezhdaninskoe). Giant ca. 125 Ma gold provinces developed in the Late Archean uplifted basement of the decratonized North China block, within its NE edge and into adjacent North Korea, in the Jiaodong Peninsula, and in the Qinling Mountains. The oldest gold-bearing magmatic–hydrothermal deposits of Asia include the ca. 485 Ma Duobaoshan porphyry within a part of the Tuva–Mongol arc, ca. 355 Ma low-sulfidation epithermal deposits (Kubaka) of the Omolon terrane accreted to eastern Russia, and porphyries (Bozshakol, Taldy Bulak) within Ordovican to Early Devonian oceanic arcs formed off the Kazakhstan microcontinent. The Late Devonian to Carboniferous was marked by widespread gold-rich porphyry development along the margins of the closing Ob–Zaisan, Junggar–Balkhash, and Turkestan basins (Amalyk, Oyu Tolgoi); most were formed in continental arcs, although the giant Oyu Tolgoi porphyry was part of a near-shore oceanic arc. Permian subduction-related deformation along the east side of the Indochina block led to ca. 300 Ma gold-bearing skarn and disseminated gold ore formation in the Truong Son fold belt of Laos, and along the west side to ca. 250 Ma gold-bearing skarns and epithermal deposits in the Loei fold belt of Laos and Thailand. In the Mesozoic Transbaikal region, extension along the basin margins subsequent to Mongol–Okhotsk closure was associated with ca. 150–125 Ma formation of important auriferous epithermal (Balei), skarn (Bystray), and porphyry (Kultuminskoe) deposits. In northeastern Russia, Early Cretaceous Pacific margin subduction and Late Cretaceous extension were associated with epithermal gold-deposit formation in the Uda–Murgal (Julietta) and Okhotsk–Chukotka (Dukat, Kupol) volcanic belts, respectively. In southeastern Russia, latest Cretaceous to Oligocene extension correlates with other low-sulfidation epithermal ores that formed in the East Sikhote–Alin volcanic belt. Other extensional events, likely related to changing plate dynamics along the Pacific margin of Asia, relate to epithermal–skarn–porphyry districts that formed at ca. 125–85 Ma in northeastmost China and ca. 105–90 Ma in the Coast Volcanic belt of SE China. The onset of strike slip along a part of the southeastern Pacific margin appears to correlate with the giant 148–135 Ma gold-rich porphyry–skarn province of the lower and middle Yangtze River. It is still controversial as to whether true Carlin-like gold deposits exist in Asia. Those deposits that most closely resemble the Nevada (USA) ores are those in the Permo-Triassic Youjiang basin of SW China and NE Vietnam, and are probably Late Triassic in age, although this is not certain. Other Carlin-like deposits have been suggested to exist in the Sepon basin of Laos and in the Mongol–Okhotsk region (Kuranakh) of Transbaikal.

Timing of crust formation and recycling in accretionary orogens: Insights learned from the western margin of South America

NASA Astrophysics Data System (ADS)

Bahlburg, Heinrich; Vervoort, Jeffrey D.; Du Frane, S. Andrew; Bock, Barbara; Augustsson, Carita; Reimann, Cornelia

2009-12-01

Accretionary orogens are considered major sites of formation of juvenile continental crust. In the central and southern Andes this is contradicted by two observations: siliciclastic fills of Paleozoic basins in the central Andean segment of the accretionary Terra Australis Orogen consist almost exclusively of shales and mature sandstones; and magmatic rocks connected to the Famatinian (Ordovician) and Late Paleozoic magmatic arcs are predominantly felsic and characterized by significant crustal contamination and strongly unradiogenic Nd isotope compositions. Evidence of juvenile crustal additions is scarce. We present laser ablation (LA)-ICPMS U-Pb ages and LA-MC-ICPMS Hf isotope data of detrital zircons from seven Devonian to Permian turbidite sandstones incorporated into a Late Paleozoic accretionary wedge at the western margin of Gondwana in northern Chile. The combination with Nd whole-rock isotope data permits us to trace the evolution of the South American continental crust through several Proterozoic and Paleozoic orogenic cycles. The analyzed detrital zircon spectra reflect all Proterozoic orogenic cycles representing the step-wise evolution of the accretionary SW Amazonia Orogenic System between 2.0 and 0.9 Ga, followed by the Terra Australis Orogen between 0.9 and 0.25 Ga. The zircon populations are characterized by two prominent maxima reflecting input from Sunsas (Grenville) age magmatic rocks (1.2-0.9 Ga) and from the Ordovician to Silurian Famatinian magmatic arc (0.52-0.42 Ga). Grains of Devonian age are scarce or absent from the analyzed zircon populations. The Hf isotopic compositions of selected dated zircons at the time of their crystallization ( ɛHf ( T) ; T = 3.3-0.25 Ga) vary between - 18 and + 11. All sandstones have a significant juvenile component; between 20 and 50% of the zircons from each sedimentary rock have positive ɛHf ( T) and can be considered juvenile. The majority of the juvenile grains have Hf-depleted mantle model ages (Hf TDM) between 1.55 and 0.8 Ga, the time of the Rondonia-San Ignacio and Sunsas orogenic events on the Amazonia craton. The corresponding whole-rock ɛNd ( T) values fot these same rocks are between - 8 and - 3 indicating a mixture of older evolved and juvenile sources. Nd-depleted mantle model ages (Nd TDM*) are between 1.5 and 1.2 Ga and coincide broadly with the zircon Hf model ages. Our data indicate that the Paleo- and Mesoproterozoic SW Amazonia Orogenic System, and the subsequent Neoproterozoic and Paleozoic Terra Australis Orogen in the region of the central and southern Andes, developed following two markedly different patterns of accretionary orogenic crustal evolution. The SW Amazonia Orogenic System developed by southwestward growth over approximately 1.1 Ga through a combination of accretion of juvenile material and crustal recycling typical of the extensional or retreating mode of accretionary orogens. In contrast, the central Andean segment of the Terra Australis Orogen evolved from 0.9 to 0.25 Ga in the compressional or advancing mode in a relatively fixed position without the accretion of oceanic crustal units or large scale input of juvenile material to the orogenic crust. Here, recycling mainly of Mesoproterozoic continental crust has been the dominant process of crustal evolution.

Phanerozoic burial and unroofing history of the western Slave craton and Wopmay orogen from apatite (U-Th)/He thermochronometry

NASA Astrophysics Data System (ADS)

Ault, Alexis K.; Flowers, Rebecca M.; Bowring, Samuel A.

2009-06-01

Low temperature thermochronometry of cratonic regions can illuminate relationships among burial and unroofing patterns, surface subsidence and uplift, and lithosphere-asthenosphere interactions. The Slave craton, initially stabilized by the development of a thick lithospheric mantle root in late Archean time, is an excellent location in which to examine these connections. Although the Slave craton currently lacks Phanerozoic cover, Phanerozoic sedimentary xenoliths entrained in ca. 610 to 45 Ma kimberlites indicate that the region underwent a more dynamic history of burial and unroofing than widely recognized. We report new apatite (U-Th)/He thermochronometry data along a southeast to northwest transect from the interior of the Slave craton into the adjacent Paleoproterozoic Wopmay orogen to resolve the region's depositional and denudational history. Six samples from the western Slave craton and three samples from Wopmay orogen yield mean dates from 296 ± 41 Ma to 212 ± 39 Ma. Individual apatite dates are broadly uniform over a wide span of apatite [eU], and this pattern can be used to more tightly restrict the spectrum of viable temperature-time paths that can explain the dataset. When coupled with geologic and stratigraphic information, temperature-time simulations of the thermochronometry results suggest complete He loss from the apatites at minimum peak temperatures of ~ 88 °C in Devonian-Pennsylvanian time, cooling to near-surface conditions by the Early Cretaceous, followed by reheating to ≤ 72 °C during Cretaceous-Early Tertiary time. Consideration of modern and ancient geotherm constraints implies ≥ 3.3 km of burial during the first Phanerozoic heating phase, with an ancillary phase of reburial in late Mesozoic-Cenozoic time. The uniformity of the apatite (U-Th)/He dates indicates that the rocks encompassed by our > 250 km-long sample transect experienced similar Phanerozoic thermal histories. Despite the distinctly different lithospheric architecture on either side of the Paleoproterozoic suture between the Slave craton and Wopmay orogen, the region behaved as a single, broadly coherent cratonic unit since at least ca. 250 Ma. The Phanerozoic burial and unroofing patterns across the craton may be a response to far-field convergent activity at the northern and western margins of North America and processes associated with episodic kimberlite emplacement.

Combined Detrital U/Pb Zircon and 40Ar/39Ar Mica Geoochronology to Test Structural Models for a Devonian Orogenic Collapse Basin in the Norwegian Caledonides

NASA Astrophysics Data System (ADS)

Templeton, J.; Anders, M.; Fossen, H.

2014-12-01

The Hornelen basin is the largest of the Devonian 'Old Red' sandstone basins in Norway, comprising 25 km of alluvial-fluvial deposits which are organized into basin-wide, coarsening-upward megacycles. Hornelen sits with several smaller basins in the hanging wall a major extensional shear zone along which the ultra-high pressure metamorphic core of subducted Baltican crust was rapidly exhumed during the extensional collapse of the Caledonian orogeny. The timing of orogenic collapse corresponds closely to the timing of the basins, which are loosely constrained by sparse trace-fossil assemblages to a mid-Devonian age. Further, the basins are now in brittle fault contact with the underlying mylonitic shear zone and the metamorphic core, implying that they are the upper-crustal expression of large-scale extension and deep-crustal exhumation. Two distinct structural models have been proposed for Hornelen to account for these observations. The strike-slip model juxtaposes different source terranes across the basin-controlling fault and predicts spatially changing provenance within chronostratigraphic units. The supradetachment model links the filling of the basin directly to unroofing of the metamorphic core on a low-angle detachment fault, and predicts basin-wide changes in provenance through time with progressive exhumation of the metamorphic hinterland. We present an extensive new provenance dataset, spanning the Hornelen basin strata through space and time. Detrital zircon U/Pb ages from 18 new samples comprise three distinct populations (1.6, 1.0, and 0.43 Ga) with the Caledonian-aged zircons (ca 0.43 Ga) present mainly along the northern margin of the basin, representing an Upper Allochthon source not found on the southern or eastern margins of the basin. Juxtaposition of different source terranes across the basin supports the strike-slip model. 40Ar/39Ar detrital white mica from the same sample set documents a younging of the dominant age peak from 432 Ma in the oldest sediments to 401 Ma in the youngest units, but does not document any difference between northern and southern mica sources. This trend supports the supradetachment model, but may also be explained by passive, isostatically-driven erosional unroofing of the overthickened orogenic crust.

The effect of long-term regional pumping on hydrochemistry and dissolved gas content in an undeveloped shale-gas-bearing aquifer in southwestern Ontario, Canada

NASA Astrophysics Data System (ADS)

Hamilton, Stewart M.; Grasby, Stephen E.; McIntosh, Jennifer C.; Osborn, Stephen G.

2015-02-01

Baseline groundwater geochemical mapping of inorganic and isotopic parameters across 44,000 km2 of southwestern Ontario (Canada) has delineated a discreet zone of natural gas in the bedrock aquifer coincident with an 8,000-km2 exposure of Middle Devonian shale. This study describes the ambient geochemical conditions in these shales in the context of other strata, including Ordovician shales, and discusses shale-related natural and anthropogenic processes contributing to hydrogeochemical conditions in the aquifer. The three Devonian shales—the Kettle Point Formation (Antrim equivalent), Hamilton Group and Marcellus Formation—have higher DOC, DIC, HCO3, CO2(aq), pH and iodide, and much higher CH4(aq). The two Ordovician shales—the Queenston and Georgian-Bay/Blue Mountain Formations—are higher in Ca, Mg, SO4 and H2S. In the Devonian shale region, isotopic zones of Pleistocene-aged groundwater have halved in size since first identified in the 1980s; potentiometric data implicate regional groundwater extraction in the shrinkage. Isotopically younger waters invading the aquifer show rapid increases in CH4(aq), pH and iodide with depth and rapid decrease in oxidized carbon species including CO2, HCO3 and DIC, suggesting contemporary methanogenesis. Pumping in the Devonian shale contact aquifer may stimulate methanogenesis by lowering TDS, removing products and replacing reactants, including bicarbonate, derived from overlying glacial sedimentary aquifers.

Pre-lithification tectonic foliation development in a clastic sedimentary sequence

NASA Astrophysics Data System (ADS)

Meere, Patrick; Mulchrone, Kieran; McCarthy, David; Timmermann, Martin; Dewey, John

2016-04-01

The current view regarding the timing of regionally developed penetrative tectonic fabrics in sedimentary rocks is that their development postdates lithification of those rocks. In this case fabric development is achieved by a number of deformation mechanisms including grain rigid body rotation, crystal-plastic deformation and pressure solution (wet diffusion). The latter is believed to be the primary mechanism responsible for shortening and the domainal structure of cleavage development commonly observed in low grade metamorphic rocks. In this study we combine field observations with strain analysis and modelling to fully characterise considerable (>50%) mid-Devonian Acadian crustal shortening in a Devonian clastic sedimentary sequence from south west Ireland. Despite these high levels of shortening and associated penetrative tectonic fabric there is a marked absence of the expected domainal cleavage structure and intra-clast deformation, which are expected with this level of deformation. In contrast to the expected deformation processes associated with conventional cleavage development, fabrics in these rocks are a product of translation, rigid body rotation and repacking of extra-formational clasts during deformation of an un-lithified clastic sedimentary sequence.

First Record of Soft Tissue Preservation in the Upper Devonian of Poland

PubMed Central

Zatoń, Michał; Broda, Krzysztof

2015-01-01

Soft tissue preservation is reported from Upper Devonian deposits of the Holy Cross Mountains, central Poland, for the first time. The preserved soft tissues are muscles associated with arthropod cuticle fragments. The muscles are phosphatized with variable states of preservation. Well-preserved specimens display the typical banding of striated muscles. Other muscle fragments are highly degraded and/or recrystallized such that their microstructure is barely visible. The phosphatized muscles and associated cuticle are fragmented, occur in patches and some are scattered on the bedding plane. Due to the state of preservation and the lack of diagnostic features, the cuticle identification is problematic; however, it may have belonged to a phyllocarid crustacean. Taphonomic features of the remains indicate that they do not represent fossilized fecal matter (coprolite) but may represent a regurgitate, but the hypothesis is difficult to test. Most probably they represent the leftover remains after arthropod or fish scavenging. The present study shows that soft tissues, which even earlier were manipulated by scavenger, may be preserved if only special microenvironmental conditions within and around the animal remains are established. PMID:26559060

First Record of Soft Tissue Preservation in the Upper Devonian of Poland.

PubMed

Zatoń, Michał; Broda, Krzysztof

2015-01-01

Soft tissue preservation is reported from Upper Devonian deposits of the Holy Cross Mountains, central Poland, for the first time. The preserved soft tissues are muscles associated with arthropod cuticle fragments. The muscles are phosphatized with variable states of preservation. Well-preserved specimens display the typical banding of striated muscles. Other muscle fragments are highly degraded and/or recrystallized such that their microstructure is barely visible. The phosphatized muscles and associated cuticle are fragmented, occur in patches and some are scattered on the bedding plane. Due to the state of preservation and the lack of diagnostic features, the cuticle identification is problematic; however, it may have belonged to a phyllocarid crustacean. Taphonomic features of the remains indicate that they do not represent fossilized fecal matter (coprolite) but may represent a regurgitate, but the hypothesis is difficult to test. Most probably they represent the leftover remains after arthropod or fish scavenging. The present study shows that soft tissues, which even earlier were manipulated by scavenger, may be preserved if only special microenvironmental conditions within and around the animal remains are established.

Late Carboniferous remagnetisation of Palaeozoic rocks in the NE Rhenish Massif, Germany

NASA Astrophysics Data System (ADS)

Zwing, A.; Bachtadse, V.; Soffel, H. C.

During stepwise thermal and alternating field demagnetisation experiments on Devonian and Lower Carboniferous carbonate and clastic rocks from the north-eastern part of the Rhenish Massif, Germany, three components of magnetisation (A, B, C) are identified. Component A is a recent viscous overprint that parallels the local present day geomagnetic field. Component B is mainly observed from 260 up to 550 °C during thermal demagnetisation and is carried by magnetite. In two localities, where red siltstones and red carbonate rocks were sampled, component B is stable up to 670 °C, indicating the presence of hematite. Three clusters of in situ B directions can be identified, which are controlled by the tectonic position of the sampling areas. These are from NW to SE: the Remscheid anticline (RA), the Lüdenscheid syncline (LS) and the Attendorn and Wittgenstein synclines (AS/WS). Standard and inclination-only fold tests, using parametric resampling, yield optimal statistical parameters at increasing amounts of untilting ranging from 0% in the South up to 57% in the North of the NE Rhenish Massif. Despite the variations in optimal untilting, the resulting site mean directions of component B do not differ significantly in inclination. These results are interpreted to reflect the acquisition of magnetisation during progressive northward migration of the deformation front in Late Carboniferous times. The resulting palaeolatitudes (RA: 1°S +2°-3°; LS: 2°S +3°-2°; AS/WS: 1°S +3°-4°) are in good agreement with the predicted position of the sampling area in the Late Carboniferous, as derived from a published Apparent Polar Wander Path for Baltica and Laurentia. The unblocking temperature spectra and the synfolding nature of B yield strong evidence that chemical processes, possibly driven by fluid migration during orogenesis, caused this remagnetisation. A third component C was observed in zones of tight folding with steeply dipping to overturned bedding planes and is dominantly carried by hematite. The resulting palaeolatitude (27°N +10°-8°) suggest a Late Triassic to Early Jurassic age of component C, which is interpreted to be caused by either hematite-bearing post-Variscan mineralisation or oxidising fluids percolating from the weathering surface and penetrating zones of enhanced permeability in the Mesozoic.

Hydrogeology and simulation of ground-water flow in the Silurian-Devonian aquifer system, Johnson County, Iowa

USGS Publications Warehouse

Tucci, Patrick; McKay, Robert M.

2006-01-01

The greatest limitation to the model is the lack of measured or estimated water-budget components for comparison to simulated water-budget components. Because the model is only calibrated to measured water levels, and not to water-budget components, the model results are nonunique. Other model limitations include the relatively coarse grid scale, lack of detailed information on pumpage from the quarry and from private developments and domestic wells, and the lack of separate water-level data for the Silurian- and Devonian-age rocks.

Basin-mountain structures and hydrocarbon exploration potential of west Junggar orogen in China

NASA Astrophysics Data System (ADS)

Wu, Xiaozhi; He, Dengfa; Qi, Xuefeng

2016-04-01

Situated in northern Xinjiang, China, in NE-SW trend, West Junggar Orogen is adjacent to Altai fold belt on the north with the Ertix Fault as the boundary, North Tianshan fold belt on the south with the Ebinur Lake Strike-slip Fault as the boundary, and the Junggar Basin on the southeast with Zaire-Genghis Khan-Hala'alat fold belt as the boundary. Covering an area of about 10×104 km2 in China, there are medium and small intermontane basins, Burqin-Fuhai, Tacheng, Hefeng and Hoxtolgay, distributing inside the orogen. Tectonically West Junggar Orogen lies in the middle section of the Palaeo-Asian tectonic domain where the Siberia, Kazakhstan and Tarim Plates converge, and is the only orogen trending NE-SW in the Palaeo-Asian tectonic domain. Since the Paleozoic, the orogen experienced pre-Permian plate tectonic evolution and post-Permian intra-plate basin evolution. Complex tectonic evolution and multi-stage structural superimposition not only give rise to long term controversial over the basin basement property but also complex basin-mountain coupling relations, structures and basin superimposition modes. According to analysis of several kinds of geological and geophysical data, the orogen was dominated by compressive folding and thrust napping from the Siberia plate in the north since the Late Paleozoic. Compressive stress weakened from north to south, corresponding to subdued vertical movement and enhanced horizontal movement of crustal surface from north to south, and finally faded in the overthrust-nappe belt at the northwest margin of the Junggar Basin. The variation in compressive stress is consistent with the surface relief of the orogen, which is high in the north and low in the south. There are two kinds of basin-mountain coupling relationships, i.e. high angle thrusting and overthrusting and napping, and two kinds of basin superimposition modes, i.e. inherited and progressive, and migrating and convulsionary modes. West Junggar orogen has rich oil and gas shows, and oil and gas fields have also been discovered in the Zaysan Basin in adjacent Kazakhstan and in adjacent Junggar, Tuha and Santanghu Basins. Drilling data, geochemical analysis of outcrop data, and the disection of ancient Bulongguoer oil reservoir at the south margin of the Hefeng Basin show there developed two sets of good transitional source rocks, the lower Hujierste Formation in the Middle Devonian (D2h1) and the Hebukehe Formation in the Upper Devonian and Lower Carboniferous (D3-C1h) in this area, which, 10 to 300 m thick, mainly distribute in the shoal water zone along Tacheng-Ertai Late Paleozoic island arc belt. Reservoirs were mainly formed in the Jurassic and then adjusted in two periods, one from the end of the Jurassic to middle Cretaceous and the other in early Paleogene. Those early oil reservoirs might be destroyed in areas such as Bulongguoer with poor preservation conditions, but in an area with good geologic and preserving conditions, oil and gas might accumulate again to form new reservoirs. Therefore, a potential Middle Devonian-Lower Carboniferous petroleum system may exist in Tacheng-Ertai island arc belt, which may become a new domain for exploration, north faulted fold belt in the Heshituoluogai basin, and Hongyan fault bench zone in north Ulungur Depression in the Junggar Basin are promising areas for hydrocarbon exploration.

Telescoping metamorphic isograds: Evidence from 40Ar/39A dating in the Orange-Milford belt, southern Connecticut

USGS Publications Warehouse

Kunk, Michael J.; Walsh, Gregory J.; Growdon, Martha L.; Wintsch, Robert P.

2013-01-01

New 40Ar/39Ar ages for hornblende and muscovite from the Orange-Milford belt in southern Connecticut reflect cooling from Acadian amphibolite facies metamorphism between ∼380 to 360 Ma followed by retrograde recrystallization of fabric-forming muscovite and chlorite during lower greenschist facies Alleghanian transpression at ∼280 Ma. Reported field temperature and pressure gradients are improbably high for these rocks and a NW metamorphic field gradient climbing from chlorite-grade to staurolite-grade occurs over less than 5 km. Simple tilting cannot account for this compressed isograd spacing given the geothermal gradient of ∼20 °C/km present at the time of regional metamorphism. However, post-metamorphic transpression could effectively telescope the isograds by stretching the belt at an oblique angle to the isograd traces. Textures in the field and in thin section reveal several older prograde schistosities overprinted by lower greenschist facies fabrics. The late cleavages commonly occur at the scale of ∼100 μm and these samples contain multiple age populations of white mica. 40Ar/39Ar analysis of these poly-metamorphic samples with mixed muscovite populations yield climbing or U-shaped age spectra. The ages of the low temperature steps are late Paleozoic, while the ages of the older steps are late Devonian. These results support our petrologic interpretation that the younger cleavage developed under metamorphic conditions below the closure temperature for Ar diffusion in muscovite, that is, in the lower greenschist facies. The correlation of a younger regionally reproducible age population with a pervasive retrograde muscovite ± chlorite cleavage reveals an Alleghanian (∼280 Ma) overprint on the Acadian metamorphic gradient (∼380 Ma). Outcrop-scale structures including drag folds and imbricate boudins suggest that Alleghanian deformation and cleavage development occurred in response to dextral transpression along a northeast striking boundary. Alleghanian oblique collision of accreting terranes from the northeast would have resulted in northeast-southwest dextral transpression against the New York promontory. This deformation was responsible for crystallization of pervasive retrograde muscovite + chlorite cleavages and associated telescoping of the Acadian metamorphic isograds in southern Connecticut at ∼280 Ma.

Using Paleomagnetic, Geochemical and Structural Data to Recognize Post-metamorphic Tectonic Events in the Caledonide Terranes of Western Svalbard.

NASA Astrophysics Data System (ADS)

Michalski, K.; Manby, G.; Nejbert, K.; Domańska Siuda, J.; Burzyński, M.

2015-12-01

A total of 170 oriented palaeomagnetic samples of Proterozoic-Lower Palaeozoic metacarbonates and metabasites from 28 sites in Hornsund and Oscar II Land, Western Spitsbergen (Fig. 1A) were investigated at the Polish Academy of Sciences Institute of Geophysics . Petrographic and rock-magnetic analyses revealed that the ferromagnetic carriers are dominated by metamorphic pyrrhotite and Low-Ti magnetite. Simultaneous in situ laser ablation 40Ar/39Ar age determination of the samples indicate that a 426-380 Ma Caledonian sensu lato thermal overprint was followed by younger events in the 377-326 Ma and ca. 300 Ma intervals (Fig. 1B). The latter two ages appear to coincide with recently published seismic data indicating that Late Devonian - Carboniferous rifting was followed by similar crustal extension in the SW Barents shelf area in Late Carboniferous time. Published in situ palaeomagnetic directions from Hornsund area in SW Svalbard fit the Silurian sector of the Baltica reference path suggesting that the geometry of the sampled Caledonian Sofekammen Syncline was not modified during following Svalbardian or Eurekan deformation events (Fig. 1C). In contrast, palaeomagnetic directions obtained from Oscar II Land are distant from Caledonian sector of Baltica reference path (Fig. 1C). It is suggested here, that the most significant mechanism responsible for the rotation of the palaeomagnetic directions and modification of geometry of Caledonian tectonic structures of Oscar II Land was listric normal faulting related to the opening of the North Atlantic -Arctic Ocean Basins. Late Cretaceous- Early Tertiary Eurekan folding and thrust faulting appear to have had minor influence on the palaeomagnetic directions obtained. This study is part of the Polish National Science Centre - DEC 2011/03/D/ST10/05193 PALMAG 2012-2016 funded project . Fig. 1. A. Geological sketch map of Western Spitsbergen. B. Probability diagrams derived from insitu 40Ar/39Ar laser ablation age determinations for Oscar II/Haakon VII Land. C. The most stable palaeomagnetic components from Hornsund (squares) and Oscar II Land (ovals) against the reference path for the Batica paleomagnetic directions recalculated for the area of Western Spitsbergen; equal area; open/ full symbols -upper/lower hemisphere.

Hydrothermal zebra dolomite in the Great Basin, Nevada--attributes and relation to Paleozoic stratigraphy, tectonics, and ore deposits

USGS Publications Warehouse

Diehl, S.F.; Hofstra, A.H.; Koenig, A.E.; Emsbo, P.; Christiansen, W.; Johnson, Chad

2010-01-01

In other parts of the world, previous workers have shown that sparry dolomite in carbonate rocks may be produced by the generation and movement of hot basinal brines in response to arid paleoclimates and tectonism, and that some of these brines served as the transport medium for metals fixed in Mississippi Valley-type (MVT) and sedimentary exhalative (Sedex) deposits of Zn, Pb, Ag, Au, or barite. Numerous occurrences of hydrothermal zebra dolomite (HZD), comprised of alternating layers of dark replacement and light void-filling sparry or saddle dolomite, are present in Paleozoic platform and slope carbonate rocks on the eastern side of the Great Basin physiographic province. Locally, it is associated with mineral deposits of barite, Ag-Pb-Zn, and Au. In this paper the spatial distribution of HZD occurrences, their stratigraphic position, morphological characteristics, textures and zoning, and chemical and stable isotopic compositions were determined to improve understanding of their age, origin, and relation to dolostone, ore deposits, and the tectonic evolution of the Great Basin. In northern and central Nevada, HZD is coeval and cogenetic with Late Devonian and Early Mississippian Sedex Au, Zn, and barite deposits and may be related to Late Ordovician Sedex barite deposits. In southern Nevada and southwest California, it is cogenetic with small MVT Ag-Pb-Zn deposits in rocks as young as Early Mississippian. Over Paleozoic time, the Great Basin was at equatorial paleolatitudes with episodes of arid paleoclimates. Several occurrences of HZD are crosscut by Mesozoic or Cenozoic intrusions, and some host younger pluton-related polymetallic replacement and Carlin-type gold deposits. The distribution of HZD in space (carbonate platform, margin, and slope) and stratigraphy (Late Neoproterozoic Ediacaran-Mississippian) roughly parallels that of dolostone and both are prevalent in Devonian strata. Stratabound HZD is best developed in Ediacaran and Cambrian units, whereas discordant HZD is proximal to high-angle structures at the carbonate platform margin, such as strike-slip and growth faults and dilational jogs. Fabric-selective replacement and dissolution features (e.g., collapse breccias, voids with geopetal textures) are common, with remaining void space lined with light-colored dolomite crystals that exhibit zoning under cathodoluminescence. Zoned crystals usually contain tiny ( ~70 degrees C. The oxygen isotopic compositions of HZD are consistent with formation temperatures of 50-150 degrees C requiring brine circulation to depths of 2-5 km, or more. The few HZD occurrences with the highest concentrations of metals (especially Fe, Mn, and Zn) and the largest isotopic shifts are closely associated with Sedex or MVT deposits known to have formed from hotter brines (e.g., Th > 150-250 degrees C). These relationships permit that HZD formed at about the same time as dolostone, from brines produced by the evaporation of seawater during arid paleoclimates at equatorial paleolatitudes. Both dolostone and HZD may have formed as basinal brines, which migrated seaward from evaporative pans on the platform, with dolostone forming at low temperatures along shallow migration pathways through permeable limestones, and HZD forming at high temperatures along deeper migration pathways through basal aquifers and dilatant high-angle faults. The small MVT deposits were chemical traps where hot brines encountered rocks or fluids containing reduced sulfur. The abundant Sedex deposits mark sites where hot brine discharged at the seafloor in adjacent basins. Thus the distribution of HZD may map deep migration pathways and upflow zones between eastern shallow marine facies, where evaporative brine could have been generated, and western Sedex deposits, where heated brines discharged along faults into platform margin, slope, and basin facies. The small size and scarcity of Pb-Zn depos

Geology of the Devonian black shales of the Appalachian Basin

USGS Publications Warehouse

Roen, J.B.

1984-01-01

Black shales of Devonian age in the Appalachian Basin are a unique rock sequence. The high content of organic matter, which imparts the characteristic lithology, has for years attracted considerable interest in the shales as a possible source of energy. The recent energy shortage prompted the U.S. Department of Energy through the Eastern Gas Shales Project of the Morgantown Energy Technology Center to underwrite a research program to determine the geologic, geochemical, and structural characteristics of the Devonian black shales in order to enhance the recovery of gas from the shales. Geologic studies by Federal and State agencies and academic institutions produced a regional stratigraphic network that correlates the 15 ft black shale sequence in Tennessee with 3000 ft of interbedded black and gray shales in central New York. These studies correlate the classic Devonian black shale sequence in New York with the Ohio Shale of Ohio and Kentucky and the Chattanooga Shale of Tennessee and southwestern Virginia. Biostratigraphic and lithostratigraphic markers in conjunction with gamma-ray logs facilitated long-range correlations within the Appalachian Basin. Basinwide correlations, including the subsurface rocks, provided a basis for determining the areal distribution and thickness of the important black shale units. The organic carbon content of the dark shales generally increases from east to west across the basin and is sufficient to qualify as a hydrocarbon source rock. Significant structural features that involve the black shale and their hydrocarbon potential are the Rome trough, Kentucky River and Irvine-Paint Creek fault zone, and regional decollements and ramp zones. ?? 1984.

Siberia, the wandering northern terrane, and its changing geography through the Palaeozoic

NASA Astrophysics Data System (ADS)

Cocks, L. Robin M.; Torsvik, Trond H.

2007-05-01

The old terrane of Siberia occupied a very substantial area in the centre of today's political Siberia and also adjacent areas of Mongolia, eastern Kazakhstan, and northwestern China. Siberia's location within the Early Neoproterozoic Rodinia Superterrane is contentious (since few if any reliable palaeomagnetic data exist between about 1.0 Ga and 540 Ma), but Siberia probably became independent during the breakup of Rodinia soon after 800 Ma and continued to be so until very near the end of the Palaeozoic, when it became an integral part of the Pangea Supercontinent. The boundaries of the cratonic core of the Siberian Terrane (including the Patom area) are briefly described, together with summaries of some of the geologically complex surrounding areas, and it is concluded that all of the Palaeozoic underlying the West Siberian Basin (including the Ob-Saisan Surgut area), Tomsk Terrane, Altai-Sayan Terranes (including Salair, Kuznetsk Alatau, Batenov, Kobdin and West Sayan), Ertix Terrane, Barguzin Terrane, Tuva-Mongol Terrane, Central Mongolia Terrane Assemblage, Gobi Altai and Mandalovoo Terranes, Okhotsk Terrane and much of the Verkhoyansk-Kolyma region all formed parts of peri-Siberia, and thus rotated with the main Siberian Craton as those areas were progressively accreted to the main Siberian Terrane at various times during the latest Neoproterozoic and Palaeozoic. The Ertix Terrane is a new term combining what has been termed the "Altay Terrane" or "NE Xinjiang" area of China, and the Baytag, Baaran and Bidz terranes of Mongolia. The Silurian Tuvaella brachiopod fauna is restricted only to today's southern parts of peri-Siberia. Thus, allowing for subsequent rotation, the fauna occurs only in the N of the Siberian Terrane, and, as well as being a helpful indicator of what marginal terranes made up peri-Siberia, is distinctive as being the only Silurian fauna known from northern higher latitudes globally. In contrast, the other terranes adjacent to peri-Siberia, the North China Terrane, the Manchurides terranes (including the Khingan-Bureya Massif area), the Gurvanshayan Terrane, the Ala Shan Terrane, the Qaidam-Qilian Terrane, the Tarim Terrane, the Junggar Terrane, the Tien Shan terranes and the various Kazakh terranes, did not become part of the Siberian Terrane assemblage until they accreted to it in the Upper Palaeozoic or later during the formation of Pangea. The Farewell Terrane of Alaska includes typical Lower and Middle Palaeozoic Siberian endemic faunas, but its Palaeozoic position is unknown. Cambrian to Early Silurian palaeomagnetic poles from the southern and northern parts of the Siberian Craton differ, but can be matched with an Euler pole of 60°N, 120°E and a rotation angle of 13°. We link this observation with Devonian rifting in the Viljuy Basin near the centre of the craton and also postulate that this rifting rejuvenated an older Precambrian rift zone, since 1-1.1 Ga poles from southern and northern Siberia differ as much as 23° around the same Euler pole. A revised Palaeozoic apparent polar wander (APW) path is presented for the Siberian Craton in which pre-Devonian poles are corrected for Viljuy Basin rifting. There is also much Late Devonian tectonic activity in the Altai-Sayan area, which may be linked. The APW path implies that Siberia was located at low southerly latitudes at the dawn of the Palaeozoic and slowly drifted northward (< 4 cm/yr.). A velocity burst is noted near the Ordovician-Silurian boundary (ca. 13 cm/yr between 450 and 440 Ma), whilst the Mid-Silurian and younger history is characterized by steady clockwise rotation (totalling about 75°) until the Late Permian. The Late Palaeozoic convergence history between Siberia and Baltica (Pangea) is hard to quantify from palaeomagnetic data because there are only two reliable poles (at 360 and 275 Ma) between the Early Silurian and the Permo-Triassic boundary. The Mid and Late Palaeozoic APW path for Siberia is therefore strongly interpolated and we discuss two different APW path alternatives that result in two very different convergence scenarios between Siberia and Baltica/Kazakh terranes. There are a newly-constructed succession of palaeogeographic maps of Siberia and its nearby areas at various times from the Cambrian to the Permian as, firstly, the peri-Siberian terranes and, secondly, the remainder of the Central Asian terranes accreted to it. Prior to the Early Ordovician, Siberia was in the southern hemisphere, but after that it drifted northwards and for most of the Phanerozoic it has been one of the few larger terranes in the northern hemisphere. The Cambrian and Ordovician maps are provisional for the Altai-Sayan and Mongolian areas, whose geology is highly complex and whose detailed palaeogeography is unresolved. The terms "Altaids" and "Paleo-Asian Ocean" have been used in so many different ways by so many different authors over so many geological periods that we reject their use. Wider issues considered include the possible links between the Cambrian Radiation (often wrongly termed "Explosion"), when metazoan animals first gained hard parts, and True Polar Wander (TPW). New Early Cambrian palaeomagnetic data from Siberia do not show rapid APW (< 10 cm/yr.) or dramatic velocity changes (< 4 cm/yr). It is concluded that the Cambrian Radiation occurred over a period approaching 20 Myr, and that rapid and large-scale TPW did not take place in the Cambrian. In addition, there are no traces of glaciogenic deposits in the very large area of Siberia during the Neoproterozoic, casting some doubt on the "Snowball Earth" hypothesis.

Combining shock barometry with numerical modeling: Insights into complex crater formation—The example of the Siljan impact structure (Sweden)

NASA Astrophysics Data System (ADS)

Holm-Alwmark, Sanna; Rae, Auriol S. P.; Ferrière, Ludovic; Alwmark, Carl; Collins, Gareth S.

2017-12-01

Siljan, central Sweden, is the largest known impact structure in Europe. It was formed at about 380 Ma, in the late Devonian period. The structure has been heavily eroded to a level originally located underneath the crater floor, and to date, important questions about the original size and morphology of Siljan remain unanswered. Here we present the results of a shock barometry study of quartz-bearing surface and drill core samples combined with numerical modeling using iSALE. The investigated 13 bedrock granitoid samples show that the recorded shock pressure decreases with increasing depth from 15 to 20 GPa near the (present) surface, to 10-15 GPa at 600 m depth. A best-fit model that is consistent with observational constraints relating to the present size of the structure, the location of the downfaulted sediments, and the observed surface and vertical shock barometry profiles is presented. The best-fit model results in a final crater (rim-to-rim) diameter of 65 km. According to our simulations, the original Siljan impact structure would have been a peak-ring crater. Siljan was formed in a mixed target of Paleozoic sedimentary rocks overlaying crystalline basement. Our modeling suggests that, at the time of impact, the sedimentary sequence was approximately 3 km thick. Since then, there has been around 4 km of erosion of the structure.

Eutrophication, microbial-sulfate reduction and mass extinctions

PubMed Central

Schobben, Martin; Stebbins, Alan; Ghaderi, Abbas; Strauss, Harald; Korn, Dieter; Korte, Christoph

2016-01-01

ABSTRACT In post-Cambrian time, life on Earth experienced 5 major extinction events, likely instigated by adverse environmental conditions. Biodiversity loss among marine taxa, for at least 3 of these mass extinction events (Late Devonian, end-Permian and end-Triassic), has been connected with widespread oxygen-depleted and sulfide-bearing marine water. Furthermore, geochemical and sedimentary evidence suggest that these events correlate with rather abrupt climate warming and possibly increased terrestrial weathering. This suggests that biodiversity loss may be triggered by mechanisms intrinsic to the Earth system, notably, the biogeochemical sulfur and carbon cycle. This climate warming feedback produces large-scale eutrophication on the continental shelf, which, in turn, expands oxygen minimum zones by increased respiration, which can turn to a sulfidic state by increased microbial-sulfate reduction due to increased availability of organic matter. A plankton community turnover from a high-diversity eukaryote to high-biomass bacterial dominated food web is the catalyst proposed in this anoxia-extinction scenario and stands in stark contrast to the postulated productivity collapse suggested for the end-Cretaceous mass extinction. This cascade of events is relevant for the future ocean under predicted greenhouse driven climate change. The exacerbation of anoxic “dead” zones is already progressing in modern oceanic environments, and this is likely to increase due to climate induced continental weathering and resulting eutrophication of the oceans. PMID:27066181

A new reconstruction of the Paleozoic continental margin of southwestern North America: Implications for the nature and timing of continental truncation and the possible role of the Mojave-Sonora megashear

USGS Publications Warehouse

Stevens, C.H.; Stone, P.; Miller, J.S.

2005-01-01

Data bearing on interpretations of the Paleozoic and Mesozoic paleogeography of southwestern North America are important for testing the hypothesis that the Paleozoic miogeocline in this region has been tectonically truncated, and if so, for ascertaining the time of the event and the possible role of the Mojave-Sonora megashear. Here, we present an analysis of existing and new data permitting reconstruction of the Paleozoic continental margin of southwestern North America. Significant new and recent information incorporated into this reconstruction includes (1) spatial distribution of Middle to Upper Devonian continental-margin facies belts, (2) positions of other paleogeographically significant sedimentary boundaries on the Paleozoic continental shelf, (3) distribution of Upper Permian through Upper Triassic plutonic rocks, and (4) evidence that the southern Sierra Nevada and western Mojave Desert are underlain by continental crust. After restoring the geology of western Nevada and California along known and inferred strike-slip faults, we find that the Devonian facies belts and pre-Pennsylvanian sedimentary boundaries define an arcuate, generally south-trending continental margin that appears to be truncated on the southwest. A Pennsylvanian basin, a Permian coral belt, and a belt of Upper Permian to Upper Triassic plutons stretching from Sonora, Mexico, into westernmost central Nevada, cut across the older facies belts, suggesting that truncation of the continental margin occurred in the Pennsylvanian. We postulate that the main truncating structure was a left-lateral transform fault zone that extended from the Mojave-Sonora megashear in northwestern Mexico to the Foothills Suture in California. The Caborca block of northwestern Mexico, where Devonian facies belts and pre-Pennsylvanian sedimentary boundaries like those in California have been identified, is interpreted to represent a missing fragment of the continental margin that underwent ???400 km of left-lateral displacement along this fault zone. If this model is correct, the Mojave-Sonora megashear played a direct role in the Pennsylvanian truncation of the continental margin, and any younger displacement on this fault has been relatively small. ?? 2005 Geological Society of America.

Stratigraphic, regional unconformity analysis and potential petroleum plays of East Siberian Sea Basin

NASA Astrophysics Data System (ADS)

Karpov, Yury; Stoupakova, Antonina; Suslova, Anna; Agasheva, Mariia

2017-04-01

The East Siberian Sea basin (ESSB) one of the most unexplored part of the Russian Arctic shelf, extending for over 1000 km from New Siberian Islands archipelago to Wrangel Island. This region is considered as a region with probable high petroleum potential. Within the ESSB several phases of orogeny are recognized [1]: Elsmerian orogeny in Early Devonian, Early Brooks orogeny in Early Cretaceous, Late Brooks orogeny in Late Cretaceous. Two generations of the basins could be outlined. Both of these generations are controlled by the basement domains [1]: Paleozoic (post-Devonian) to Mesozoic basins preserved north of the Late Mesozoic frontal thrusts; Aptian-Albian to Quaternary basins, postdating the Verkhoyansk-Brookian orogeny, and evolving mainly over the New-Siberian-Chukchi Fold Belt. Basin is filled with siliclastic sediments and in the deepest depocentres sediments thickness exceeds 8-10 km in average. Seismic data was interpreted using methods of seismic stratigraphy. Finally, main seismic horizons were indicated and each horizon follows regional stratigraphic unconformities: mBU - in base of Cenozoic, BU - in base of Upper Cretaceous, LCU - in base of Cretaceous, JU - in middle of Jurassic, F - in top of Basement. In ESSB, we can identify Permian, Triassic, Jurassic, Cretaceous, Paleogene and Neogene seismic stratigraphy complexes. Perspective structures, investigated in ESSB were founded out by comparing seismogeological cross-sections with explored analogs in other onshore and offshore basins [2, 3, 4]. The majority of structures could be connected with stratigraphic and fault traps. The most perspective prospects are probably connected with grabens and depressions, where thickness of sediments exceed 10 km. Reservoirs in ESSB are proposed by regional geological explorations on New Siberian Islands Archipelago and Wrangel Island. Potential seals are predominantly assigned to Jurassic and Cretaceous periods. Thick clinoform units of various geometry and trajectories were found in Southern part of ESSB. These clinoform sequences could be formed as a result of significant subsidence followed by rapid sedimentary influx. All possible perspective structures were mapped on tectonic scheme of basin. References: [1] Drachev S.S., Malyshev N.A. and Nikishin A.M., 2010 Tectonic history and petroleum geology of the Russian Arctic Shelves: an overview. Petroleum Geology Conference series, 7, 591-619. [2] Spencer A.M., Embry A.F., Gautier D.L., Stoupakova A.V. and Sorensen K., 2011 An overview of the petroleum geology of the Arctic, Geological Society Memoirs, 35, 1-15. [3] Stoupakova A., Kirykhina T., Suslova A., Kirykhina N., Sautkin R. and Bordunov S., 2012 Structure, hydrocarbon prospects of the Russian Western arctic shelf. AAPG Arctic technology conference. Manuscript. Electronic version. AAPG Houston, USA. [4] Verzhbitsky V.E., Sokolov, S.D., Tuchkova M.I., Frantzen E.M., Little A., Lobkovsky L.I., 2012 The South Chukchi Sedimentary Basin (Chukchi Sea, Russian Arctic): Age, Structural Pattern, and Hydrocarbon Potential in D. Gao, ed., Tectonics and sedimentation: Implications for petroleum systems: AAPG Memoir, 100, 267-290.

Algoma-, Superior-, and oolitic-type iron deposits of the Islamic Republic of Mauritania (phase V, deliverable 83): Chapter O in Second projet de renforcement institutionnel du secteur minier de la République Islamique de Mauritanie (PRISM-II)

USGS Publications Warehouse

Taylor, Cliff D.; Finn, Carol A.; Anderson, Eric D.; Joud, M. Y.; Taleb, M. A.; Horton, John D.

2015-01-01

Phanerozoic oolitic ironstones are hosted in the upper Silurian and lower Devonian rocks of the Gara Bouya Ali Group and the Zemmour Group in the Tindouf Basin in northern Mauritania and in the end Ordovician Tichit Group, the Silurian Oued Chig Group, and the lower Devonian Tenemouj Group in the Taoudeni Basin near Tidjikja. These rock groups define 11 permissive tracts for Algoma-, Superior-, and oolitic-type iron deposits in Mauritania.

Petrology and sedimentology of the Horlick Formation (Lower Devonian), Ohio Range, Transantarctic Mountains

USGS Publications Warehouse

McCartan, Lucy; Bradshaw, Margaret A.

1987-01-01

The Horlick Formation of Early Devonian age is as thick as 50 m and consists of subhorizontal, interbedded subarkosic sandstone and chloritic shale and mudstone. The Horlick overlies an erosion surface cut into Ordovician granitic rocks and is, in turn, overlain by Carboniferous and Permian glacial and periglacial deposits. Textures, sedimentary structures, and ubiquitous marine body fossils and animal traces suggest that the Horlick was deposited on a shallow shelf having moderate wave energy and a moderate tidal range. The source terrane probably lay to the north, and longshore transport was toward the west.

The stratigraphic utility of the trace fossil Pteridichnites biseriatus in the Upper Devonian of eastern West Virginia and western Virginia, USA

USGS Publications Warehouse

McDowell, R.R.; Avary, K.L.; Matchen, D.L.; Britton, J.Q.

2007-01-01

Similar lithologies and lithofacies are present in two Upper Devonian siliciclastic units, the Brallier and Foreknobs formations, in eastern West Virginia and western Virginia, USA. Specimens of an unusual trace fossil, Pteridichnites biseriatus, occur in variable numbers throughout both stratigraphic units. P. biseriatus is present in abundance in the lowermost Brallier and this abundance-zone serves as a local stratigraphic marker for the Brallier. The trace fossil, originally suggested as an indication of polychaete or arthropod locomotion, is herein proposed as the locomotion trace of an unidentified ophiuroid.

Evidence of land plant affinity for the Devonian fossil Protosalvinia (Foerstia)

USGS Publications Warehouse

Romankiw, L.A.; Hatcher, P.G.; Roen, J.B.

1988-01-01

The Devonian plant fossil Protosalvinia (Foerstia) has been examined by solid-state 13C nuclear magnetic resonance spectroscopy (NMR) and pyrolysis-gas chromatography-mass spectrometry (PY-GC-MS). Results of these studies reveal that the chemical structure of Protosalvinia is remarkably similar to that of coalified wood. A well-defined phenolic carbon peak in the NMR spectra and the appearance of phenol and alkylated phenols in pyrolysis products are clearly indicative of lignin-like compounds. These data represent significant new information on the chemical nature of Protosalvinia and provide the first substantial organic geochemical evidence for land plant affinity. -Authors

The Lower Devonian marginal-marine ecosystems of the Holy Cross Mountains, Poland - new discoveries and observations

NASA Astrophysics Data System (ADS)

Szrek, P.; Niedźwiedzki, G.; Dec, M.

2012-04-01

Despite of more than 100 years of study, the Lower Devonian deposits of the Holy Cross Mountains (central Poland) are still not well understood from the biostratigraphical, environmental and also paleontological point of views. During field works and excavations conducted in 2011 numerous fossils (body and trace fossils) were discovered in a few Lower Devonian outcrops of the region. The siliciclastic sequence of the Lower Devonian of the southern part of the Holy Cross Mountains, is renowned for abundant vertebrate fossils, including mainly the jawless fish and placoderm remains. During the first detailed taphonomic study of the vertebrate assemblage from the so-called "Placoderm Sandstones" cropping out at the Podłazie near Daleszyce, abundant vertebrate remains have been collected (more than 600 specimens). Their analysis (that is in progress) will be the first description of so rich and numerous vertebrates association from the Central Europe that contains placoderms, sharks, acathodians and sarcopterygians. The degree of fragmentation of the bones and disarticulation of the skeletons suggest that the carcasses were reworked and transported before burial. Sedimentological data suggest deposition in a shallow marine environment. Numerous invertebrate ichnofossils (Phycodes isp. Skolithos isp., Diplichnites isp., Monomorphichnus isp., Lockeia cf. siliquaria, Corophioides isp. and Teichinus isp.) particularly well preserved were ascertained in another Lower Devonian site near Iwaniska. Moreover a very interesting assemblage of trace fossils corresponding to traces of feeding fishes were discovered. They are very similar to those found in much younger deposits (e.g. from the Eocene of Turkey). Its interpretation found them as made by placoderms is taken into consideration recently, because of its fiting to whole morphology of small coccosteids. They are also important that they could be the first imprints of soft body of the placoderm as a life animal according to good preservation of particular specimens. The occurrence of characteristic trace fossils is taken as strong evidence of marine influences of the studied section, where sedimentological features are not so clear, with exceptions of very few surfaces covered with symmetrical wave marks. The distribution of the most common trace fossils recognized in the field allowed for different interpretation than was proposed in the past which set up the river influence in the Lower Dewonian of the eastern part of the Holy Cross Mountains, but it is not confirmed by mentioned above invertebrate ichnofossils. Instead of this the development of Skolithos and Cruziana ichnofacies in Iwaniska profile, indicate high energy conditions in foreshore zone, respectively. All the Lower Devonian sites with trace fossils and vertebrate bonebeds from the Holy Cross Mountains are associated with sandy deposits and have been formed in a sea-coastal zone during rather rapid sedimentation episodes, but differ in fossil abundance and degree of preservation.

Assessing the composition of fragmented agglutinated foraminiferal assemblages in ancient sediments: comparison of counting and area-based methods in Famennian samples (Late Devonian)

NASA Astrophysics Data System (ADS)

Girard, Catherine; Dufour, Anne-Béatrice; Charruault, Anne-Lise; Renaud, Sabrina

2018-01-01

Benthic foraminifera have been used as proxies for various paleoenvironmental variables such as food availability, carbon flux from surface waters, microhabitats, and indirectly water depth. Estimating assemblage composition based on morphotypes, as opposed to genus- or species-level identification, potentially loses important ecological information but opens the way to the study of ancient time periods. However, the ability to accurately constrain benthic foraminiferal assemblages has been questioned when the most abundant foraminifera are fragile agglutinated forms, particularly prone to fragmentation. Here we test an alternate method for accurately estimating the composition of fragmented assemblages. The cumulated area per morphotype method is assessed, i.e., the sum of the area of all tests or fragments of a given morphotype in a sample. The percentage of each morphotype is calculated as a portion of the total cumulated area. Percentages of different morphotypes based on counting and cumulated area methods are compared one by one and analyzed using principal component analyses, a co-inertia analysis, and Shannon diversity indices. Morphotype percentages are further compared to an estimate of water depth based on microfacies description. Percentages of the morphotypes are not related to water depth. In all cases, counting and cumulated area methods deliver highly similar results, suggesting that the less time-consuming traditional counting method may provide robust estimates of assemblages. The size of each morphotype may deliver paleobiological information, for instance regarding biomass, but should be considered carefully due to the pervasive issue of fragmentation.

A synthesis of mineralization styles and geodynamic settings of the Paleozoic and Mesozoic metallic ore deposits in the Altay Mountains, NW China

NASA Astrophysics Data System (ADS)

Yang, Fuquan; Geng, Xinxia; Wang, Rui; Zhang, Zhixin; Guo, Xuji

2018-06-01

The Altay Mountains within the Xinjiang region of northwestern China hosts major metallic ore deposits. Here we review the geological characteristics, metallogenic features and tectonic settings of these deposits. The metallic ore deposits in the Altay Mountains occur mainly within four regions: North Altay, Central Altay, South Altay and Erqis. We recognize seven types of metallic ore deposits in the Altay Mountains: VMS, submarine volcanogenic iron, magmatic, skarn, pegmatite, hydrothermal vein (Cu-Zn, Fe) and orogenic gold. Among these types, the VMS, pegmatite, orogenic gold and skarn deposits are the most common. Most of the rare metal pegmatite deposits are distributed in Central Altay, with only a few in South Altay. The VMS, submarine volcanogenic type iron and skarn-type deposits are distributed in South Altay, whereas the orogenic-type gold deposits are distributed in the Erqis Fault belt. The hydrothermal vein-type deposits occur in the Erqis Fault belt and Chonghu'er Basin in South Altay. Magmatic-type deposits are mostly in the Erqis Fault belt and Central Altay. Based on isotopic age data, the VMS, submarine volcanogenic-type Fe and skarn-type Cu, Pb, Zn, Fe mineralization occurred during Early-Middle Devonian (∼410-377 Ma), orogenic-type Au, magmatic-type Cu-Ni, and a small number of skarn-type Fe, hydrothermal vein-type Cu-Zn, pegmatite-type rare-metal deposits in Early-Middle Permian (293-261 Ma), pegmatite-type rare-metal deposits, few skarn-type Fe deposit in Early-Middle Triassic (248-232 Ma), and dominantly represented by pegmatite-type rare-metal deposits in Late Triassic-Early Jurassic (223-180 Ma). The metallic ore deposits in the Altay Mountains formed in various tectonic settings, such as the Early-Middle Devonian continental arc and oceanic island arc, Early-Middle Permian post-collisional extensional setting, and Triassic-Early Jurassic intracontinental setting.

Geology and hydrocarbon potential of the Oued Mya basin, Algeria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Benamrane, O.; Messaoudi, M.; Messelles, H.

1993-09-01

The Oued Mya hydrocarbon system is located in the Sahara basin. It is one of the best producing basins in Algeria, along with the Ghadames and Illizi basins. The stratigraphic section consists of Paleozoic and Mesozoic, and is about 5000 m thick. This intracratonic basin is limited to the north by the Toughourt saddle, and to the west and east it is flanked by regional arches, Allal-Tilghemt and Amguid-Hassi Messaoud, which culminate in the super giant Hassi Messaoud and Hassi R'mel hydrocarbon accumulations, respectively, producing oil from the Cambrian sands and gas from the Trissic sands. The primary source rockmore » in this basin is lower Silurian shale, with an average thickness of 50 m and a total organic carbon of 6% (14% in some cases). Results of maturation modeling indicate that the lower Silurian source is in the oil window. The Ordovician shales are also source rocks, but in a second order. Clastic reservoirs are in the Trissic sequence, which is mainly fluvial deposits with complex alluvial channels, and the main target in the basin. Clastic reservoirs in the lower Devonian section have a good hydrocarbon potential east of the basin through a southwest-northwest orientation. The Late Trissic-Early Jurassic evaporites that overlie the Triassic clastic interval and extend over the entire Oued Mya basin, are considered to be a super-seal evaporite package, which consists predominantly of anhydrite and halite. For paleozoic targets, a large number of potential seals exist within the stratigraphic column. This super seal does not present oil dismigration possibilities. We can infer that a large amount of the oil generated by the Silurian source rock from the beginning of Cretaceous until now still is not discovered and significantly greater volumes could be trapped within structure closures and mixed or stratigraphic traps related to the fluvial Triassic sandstones, marine Devonian sands, and Cambrian-Ordovician reservoirs.« less

Metallogeny of the Mont-de-l'Aigle IOCG deposit, Gaspé Peninsula, Québec, Canada

NASA Astrophysics Data System (ADS)

Simard, M.; Beaudoin, G.; Bernard, J.; Hupé, A.

2006-09-01

The Mont-de-l’Aigle deposit is located in the northern part of Dome Lemieux, in the Connecticut Valley-Gaspé Synclinorium, Gaspé Peninsula, Québec. The Dome Lemieux is a subcircular antiform of Siluro-Devonian sedimentary rocks that is cut by numerous mafic and felsic sills and dikes of Silurian to Late Devonian age. Plutonism occurred in a continental within-plate extensional setting typical of orogenic collapse. The Cu-Fe (± Au) mineralization of Mont-de-l’Aigle occurs in veins, stockworks, and breccias. Mineralization is located near or within N-S and NW-SE faults cutting sedimentary rocks. IOCG mineralization postdates intrusions, skarns, hornfels, and epithermal mineralization typical of the southern part of the Dome Lemieux. The paragenetic sequence comprises: (1) pervasive sodic, potassic, chlorite, and silica alteration, (2) hematite, quartz, pyrite, magnetite, and chalcopyrite veins, stockworks and breccias and, (3) dolomite ± hematite veins and veinlets cutting the earlier mineralization. Intrusions display proximal sodic and potassic alteration, whereas sedimentary rocks have proximal decalcification, silicification, and potassic alteration. Both intrusive and sedimentary rocks are affected by a pervasive distal chlorite (± silica) alteration. The sulfur isotope composition of pyrite and chalcopyrite (δ34S=-1.5 to 4.8‰) suggests that sulfur was derived mainly from igneous rocks. Fluid δ18O (-0.4 to 2.65‰) indicates meteoric or seawater that reacted with the country rocks. Mixing of hot magmatic fluids with a cooler fluid, perhaps meteoric or seawater is suggested for mineral deposition and alteration of the Mont-de-l’Aigle deposit. The mineralogy, alteration, and sulfur isotope composition of the Mont-de-l’Aigle deposit compare well with IOCG deposits worldwide, making the Mont-de-l’Aigle deposit a rare example of Paleozoic IOCG mineralization, formed at shallow depth, within a low metamorphic grade sedimentary rock sequence.

A paleolatitude reconstruction of the South Armenian Block (Lesser Caucasus) for the Late Cretaceous: Constraints on the Tethyan realm

NASA Astrophysics Data System (ADS)

Meijers, Maud J. M.; Smith, Brigitte; Kirscher, Uwe; Mensink, Marily; Sosson, Marc; Rolland, Yann; Grigoryan, Araik; Sahakyan, Lilit; Avagyan, Ara; Langereis, Cor; Müller, Carla

2015-03-01

The continental South Armenian Block - part of the Anatolide-Tauride South Armenian microplate - of Gondwana origin rifted from the African margin after the Triassic and collided with the Eurasian margin after the Late Cretaceous. During the Late Cretaceous, two northward dipping subduction zones were simultaneously active in the northern Neo-Tethys between the South Armenian Block in the south and the Eurasian margin in the north: oceanic subduction took place below the continental Eurasian margin and intra-oceanic subduction resulted in ophiolite obduction onto the South Armenian Block in the Late Cretaceous. The paleolatitude position of the South Armenian Block before its collision with Eurasia within paleogeographic reconstructions is poorly determined and limited to one study. This earlier study places the South Armenian Block at the African margin in the Early Jurassic. To reconstruct the paleolatitude history of the South Armenian Block, we sampled Upper Devonian-Permian and Cretaceous sedimentary rocks in Armenia. The sampled Paleozoic rocks have likely been remagnetized. Results from two out of three sites sampled in Upper Cretaceous strata pass fold tests and probably all three carry a primary paleomagnetic signal. The sampled sedimentary rocks were potentially affected by inclination shallowing. Therefore, two sites that consist of a large number of samples (> 100) were corrected for inclination shallowing using the elongation/inclination method. These are the first paleomagnetic data that quantify the South Armenian Block's position in the Tethys ocean between post-Triassic rifting from the African margin and post-Cretaceous collision with Eurasia. A locality sampled in Lower Campanian Eurasian margin sedimentary rocks and corrected for inclination shallowing, confirms that the corresponding paleolatitude falls on the Eurasian paleolatitude curve. The north-south distance between the South Armenian Block and the Eurasian margin just after Coniacian-Santonian ophiolite obduction was at most 1000 km.

Burial, Uplift and Exhumation History of the Atlantic Margin of NE Brazil

NASA Astrophysics Data System (ADS)

Japsen, Peter; Bonow, Johan M.; Green, Paul F.; Cobbold, Peter R.; Chiossi, Dario; Lilletveit, Ragnhild

2010-05-01

We have undertaken a regional study of landscape development and thermo-tectonic evo-lution of NE Brazil. Our results reveal a long history of post-Devonian burial and exhuma-tion across NE Brazil. Uplift movements just prior to and during Early Cretaceous rifting led to further regional denudation, to filling of rift basins and finally to formation of the Atlantic margin. The rifted margin was buried by a km-thick post-rift section, but exhumation began in the Late Cretaceous as a result of plate-scale forces. The Cretaceous cover probably extended over much of NE Brazil where it is still preserved over extensive areas. The Late Cretaceous exhumation event was followed by events in the Paleogene and Neogene. The results of these events of uplift and exhumation are two regional peneplains that form steps in the landscape. The plateaux in the interior highlands are defined by the Higher Surface at c. 1 km above sea level. This surface formed by fluvial erosion after the Late Cretaceous event - and most likely after the Paleogene event - and thus formed as a Paleogene pene-plain near sea level. This surface was reburied prior to the Neogene event, in the interior by continental deposits and along the Atlantic margin by marine and coastal deposits. Neo-gene uplift led to reexposure of the Palaeogene peneplain and to formation of the Lower Surface by incision along rivers below the uplifted Higher Surface that characterise the pre-sent landscape. Our results show that the elevated landscapes along the Brazilian margin formed during the Neogene, c. 100 Myr after break-up. Studies in West Greenland have demonstrated that similar landscapes formed during the late Neogene, c. 50 Myr after break-up. Many passive continental margins around the world are characterised by such elevated plateaus and it thus seems possible, even likely, that they may also post-date rifting and continental separation by many Myr.

The Rhynie hot-spring system: implications for the Devonian timescale, development of Devonian biota, gold mineralization, evolution of the atmosphere and Earth outgassing

NASA Astrophysics Data System (ADS)

Mark, D.; Rice, C.; Stuart, F.; Trewin, N.

2011-12-01

The Rhynie cherts are hot spring sinters that contain world-renowned plant and animal remains and anomalously high quantities of heavy metals, including gold. The biota in several beds is preserved undeformed with plants in life positions thus establishing that they and the indurating hydrothermal fluids were coeval. Despite the international importance of the Rhynie cherts their age has been poorly constrained for three reasons: (1) lack of a precise radio-isotopic age, (2) low resolution of spore biostratigraphic schemes for Devonian terrestrial deposits, with only one to a few zones per stage, and (3) poor resolution of the early Devonian timescale. Wellman (2004) assigned a Pragian-?earliest Emsian age to the Rhynie cherts on the basis of the spore assemblage. An 40Ar/39Ar dating study targeting Rhynie chert yielded an age of 395 ± 12 Ma (1σ) (Rice et al., 1995). This contribution discusses a new high-precision 40Ar/39Ar age (407.1 ± 2.2 Ma, 2σ) for the Devonian hot-spring system at Rhynie (Mark et al., 2011) and demonstrates that a proposed U-Pb age (411.5 ± 1.1 Ma, 2σ) for the Rhynie cherts (Parry et al., 2011) is inconsistent with both field evidence and our interpretation of the U-Pb data. The 40Ar/39Ar age provides a robust marker for the polygonalis-emsiensis Spore Assemblage Biozone within the Pragian-?earliest Emsian. It also constrains the age of a wealth of flora and fauna preserved in life positions as well as dating gold mineralization. Furthermore, we have now determined the Ar isotope composition of pristine samples of the Rhynie chert using an ARGUS multi-collector mass spectrometer and a low blank laser extraction technique. 40Ar/36Ar are systematically lower than the modern air value (Lee et al., 2006), and are not accompanied by non-atmospheric 38Ar/36Ar ratios. We conclude that the Rhynie chert captured and has preserved Devonian atmosphere-derived Ar. The data indicate that the 40Ar/36Ar of Devonian atmosphere was at least 3 % lower than the modern air value (Lee et al., 2006). Thus the Earth's atmosphere has accumulated at least 5 ± 0.2 x 1016 moles of 40Ar in the last c. 407 Ma, at an average rate of 1.24 ± 0.06 x 108 mol 40Ar/year. This overlaps the 40Ar accumulation rate determined from ice cores for the last 800,000 years (Bender et al. 2008) and implies that there has been no resolvable temporal change in outgassing rate since the mid-Palaeozoic. The new chronological and Ar isotope data provide a unique tie point and dictate outgassing of the Earth's interior early in Earth history. [1] Bender, M. et al. (2008) Proceedings of the National Academy of Sciences, 105, 8232-8237. [2] Wellman, C.H., 2004. Proceedings of the Royal Society of London. Biological Sciences, 271, 985-992. [3] Lee, J.Y. et al. (2006) Geochimica et Cosmochimica Acta, 70, 4507-4512. [4] Mark, D.F. et al. (2011) Geochimica et Cosmochimica Acta, 75, 555-569. [5] Parry, S.F. et al. (2011) Journal of the Geological Society, London, 168, 863-872. [6] Rice, C.M. et al. (1995) Journal of the Geological Society, London, 152, 229-2250.

Regional stratigraphy and petroleum potential, Ghadames basin, Algeria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Emme, J.J.; Sunderland, B.L.

1991-03-01

The Ghadames basin in east-central Algeria extends over 65,000 km{sup 2} (25,000 mi{sup 2}), of which 90% is covered by dunes of the eastern Erg. This intracratonic basin consists of up to 6000 m (20,000 ft) of dominantly clastic Paleozoic through Mesozoic strata. The Ghadames basin is part of a larger, composite basin complex (Ilizzi-Ghadames-Triassic basins) where Paleozoic strata have been truncated during a Hercynian erosional event and subsequently overlain by a northward-thickening wedge of Mesozoic sediments. Major reservoir rocks include Triassic sandstones that produce oil, gas, and condensate in the western Ghadames basin, Siluro-Devonian sandstones that produce mostly oilmore » in the shallower Ilizzi basin to the south, and Cambro-Ordovician orthoquartzites that produce oil at Hassi Messaoud to the northwest. Organic shales of the Silurian and Middle-Upper Devonian are considered primary source rocks. Paleozoic shales and Triassic evaporite/red bed sequences act as seals for hydrocarbon accumulations. The central Ghadames basin is underexplored, with less than one wildcat well/1700 km{sup 2} (one well/420,000 ac). Recent Devonian and Triassic oil discoveries below 3500 m (11,500 ft) indicate that deep oil potential exists. Exploration to date has concentrated on structural traps. Subcrop and facies trends indicate that potential for giant stratigraphic or combination traps exists for both Siluro-Devonian and Triassic intervals. Modern seismic acquisition and processing techniques in high dune areas can be used to successfully identify critical unconformity-bound sequences with significant stratigraphic trap potential. Advances in seismic and drilling technology combined with creative exploration should result in major petroleum discoveries in the Ghadames basin.« less

The tectonographic development of Patagonia and its relevance to hydrocarbon exploration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Light, M.P.R.; Urien, C.M.; Maslanyj, M.P.

1993-02-01

Patagonia accreted successively from the southwest onto the southern margin of the Proterozoic Plata Craton and Brazilian Guapore Shield between the Late Proterozoic and Early Devonian. The thrust-like stacking of terranes onto the southern termination of the Pelotas Terrane is considered to have developed a pervasive northwest to north-trending fabric. During the Permo-Triassic the northwest to north-trending fabric of the Patagonian Plate was re-activated by dextral strike-slip movement causing extension. The deformation was caused by oblique subduction and accretion of the madre Dos Dios to Pichidangui Terranes along its western margin. To the northeast the more competent shield underwent compressionmore » (Ventania-Gond-wanide Folding) and extension occurred parallel to the axis of the embryo South Atlantic, where a shallow sea transgressed. Ridge on its western side, now preserved on the facing shelf margins of Argentina and Namibia. In the Late Triassic-Lower Jurassic, the Malvinas and Microplate was situated south of the Transkei (South Africa) and an intracratonic basin separated it from two sutures formed at the margin of the Argentine Shelf and along the axis of the West Malvinas Basin. Subduction/arc activity on the west flank of this intracratonic basin, in association with trench pull is believed to have initiated Late Triassic-Early Jurassic strike slip extension and volcanicity in Patagonia. This exploited the pervasive northwest and north-trending Paleozoic fabric. By the Mid-Jurassic the Malvinas Microplate had docked with the eastern margin of the Patagonian Shelf and was undergoing clockwise rotation between the Malvinas-Agulhas and Burwood Bank-Scotia Ridge dextral strike-slip systems. Rifting had now progressed southwestwards to the Pacific and north eastwards to the Colorado and Outeniqua Basins.« less

A carbon isotopic and sedimentological record of the latest Devonian (Famennian) from the Western U.S. and Germany

USGS Publications Warehouse

Myrow, P.M.; Strauss, J.V.; Creveling, J.R.; Sicard, K.R.; Ripperdan, R.; Sandberg, C.A.; Hartenfels, S.

2011-01-01

New carbon isotopic data from upper Famennian deposits in the western United States reveal two previously unrecognized major positive isotopic excursions. The first is an abrupt ~. 3??? positive excursion, herein referred to as ALFIE (A Late Famennian Isotopic Excursion), recorded in two sections of the Pinyon Peak Limestone of north-central Utah. Integration of detailed chemostratigraphic and biostratigraphic data suggests that ALFIE is the Laurentian record of the Dasberg Event, which has been linked to transgression in Europe and Morocco. Sedimentological data from the Chaffee Group of western Colorado also record transgression at a similar biostratigraphic position, with a shift from restricted to open-marine lithofacies. ALFIE is not evident in chemostratigraphic data from age-equivalent strata in Germany studied herein and in southern Europe, either because it is a uniquely North American phenomenon, or because the German sections are too condensed relative to those in Laurentia. A second positive carbon isotopic excursion from the upper Chaffee Group of Colorado is recorded in transgressive strata deposited directly above a previously unrecognized paleokarst interval. The age of this excursion, and the duration of the associated paleokarst hiatus, are not well constrained, although the events occurred sometime after the Late Famennian Middle expansa Zone. The high positive values recorded in this excursion are consistent with those associated with the youngest Famennian Middle to Late praesulcata Hangenberg Isotopic Excursion in Europe, the isotopic expression of the Hangenberg Event, which included mass extinction, widespread black shale deposition, and a glacio-eustatic fall and rise. If correct, this would considerably revise the age of the Upper Chaffee Group strata of western Colorado. ?? 2011 Elsevier B.V.

Multiple crust reworking in the French Armorican Variscan belt: implication for the genesis of uranium-fertile leucogranites

NASA Astrophysics Data System (ADS)

Ballouard, C.; Poujol, M.; Zeh, A.

2018-03-01

Muscovite peraluminous granites (MPGs) form by partial melting of the continental crust and can be related to metalliferous deposits such as tin, tungsten, and uranium (U). Metal enrichment in MPGs commonly results from fractional crystallization, but the metal contents of the source play a major role for their fertility. Between ca. 320 and 300 Ma (Late Carboniferous), the French Armorican Variscan belt was intruded by numerous U-fertile MPGs that contain inherited zircon grains with a wide range of ages from Archean-to-Carboniferous. U-Pb and Hf isotopic data of zircon grains from Brioverian-to-Carboniferous sediments, Cambrian-to-Early Carboniferous granitoids, and Late Carboniferous MPGs indicate that the crust of the Armorican Massif is made up by detritus mainly derived from the West African craton (3500-1600 Ma; T DM = 3.8-2.3 Ga), Grenvillian belt (1200-900 Ma; T DM = 2.7-1.2 Ga), and Avalonian-Cadomian belt (800-550 Ma; T DM = 2.5-0.8 Ga) and that the crust was affected by magmatic events at 510-470 Ma (T DM = 1.6-0.6 Ga), 410-330 Ma (T DM = 1.6-1 Ga), and 320-300 Ma. Furthermore, they reveal that the Late Carboniferous MPGs were mainly formed by partial melting of Brioverian sediments with Cambro-Ordovician and Devonian-Carboniferous granitoids, which are all genetically linked with each other and characterized by Th/U < 4. The new data suggest that the U-fertile MPGs result from multiple reworking of U-rich Brioverian sediments, deposited ca. 550 Ma ago on the northern margin of Gondwana, and partially molten during several Paleozoic events, causing a successive increase in U content in the middle-upper crust.

Geochemical Aspects of Formation of Large Oil Deposits in the Volga-Ural Sedimentary Basin

NASA Astrophysics Data System (ADS)

Plotnikova, I.; Nosova, F.; Pronin, N.; Nosova, J.; Budkevich, T.

2012-04-01

The study of the rocks domanikoid type in the territory of the Ural-Volga region has an almost century-long history, beginning with the first studies of A.D. Archangelsky in the late 20's of last century. But nevertheless the question of the source of oil that formed the industrial deposits of Volga-Ural oil and gas province (OGP), where Romashkinskoye oil field occupies a special place, remains unresolved and topical. According to the sedimentary-migration theory of origin of oil and gas, it is supposed that the primary source of hydrocarbons in this area are the deposits of domanikoid type that contain a large ammount of sapropel organic matter (OM). Semiluki (domanik) horizon of srednefranski substage of the Upper Devonian is considered to be a typical domanikoid stratum. Investigation of the OM of the rocks and oils of the sedimentary cover on the basis of chromato-mass spectrometry method allows us to study the correlations between rock and oil and to assess the location (or absence) of the sources of hydrocarbons in the Paleozoic sedimentary cover. The results of geochemical study of dispersed organic matter (DOM) of rocks from Semiluksky horizon of the Upper Devonian and of the oil from Pashiysky horizon of the Middle Devonian form the basis of this paper. The objectives of this study were the following: to determine the original organic matter of the rocks, which would indicate the conditions of sedimentation of the supposed rock-oil sources; the study of chemofossils (biomarkers) in oil from Pashiyskiy horizon; and the identification of genetic association of DOM rocks from Semiluksky horizon with this oil on the basis of the oil-DOM correlation. The study of biomarkers was carried out with the help of chromato-mass spectrometry in the Laboratory of Geochemistry of Fossil Fuels (Kazan Federal University). In this study we used several informative parameters characterizing the depositional environment, the type of source OM and its maturity: STER / PENT, hC35/hC34, GAM / HOP, S27/S28/S29 (steranes), DIA / REG, Ts / Tm, MOR / HOP, NOR / HOP, TET / TRI, C29SSR, C29BBAA, C31HSR, S30STER, TRI / PENT, TRI / HOP. Comparison in the rock-oil system was performed primarily according to the parameters indicating the depositional environment of the source rock that contains syngenetic DOM - according to the coefficients that determine lithological conditions for the formation of the supposed oil-source bed strata (DIA / REG, Ts / Tm, NOR / HOP, TRI / HOP and STER / PENT). Biomarker ratios indicate a different type of sedimentation basins. Sediments, which accumulated DOM from Semilukskiy horizon, can be characterized by low clay content, or its absence, that is consistent with the carbonate type of cut of the horizon. The bacterial material that was accumulated under reducing conditions of sedimentation appeared to be the source of syngenetic OM. Chemofossils found in oils from Pashiyskiy horizon are typical of sedimentary strata that contain clay - for clastic rocks, which in the study area are mainly represented by deposits and Eyfel Givetian layers of the Middle Devonian and lowfransk substage of the Upper Devonian. The study of correlations obtained for the different coefficients of OM and oils showed that only the relationships between Ts/Tm and DIA/REG and between NOR/HOP and TRI/HOP are characteristic of close, almost similar values of correlation both for the dispersed organic matter and for oil. In all other cases, the character of the correlation of OM is significantly different from that of oil. The differences in values and ranges of biomarker ratios as well as the character of their correlation indicates the absence of genetic connection between the oil from Pashiyskiy horizon for the dispersed organic matter from Semilukskiy horizon. This conclusion is based on the study of five biomarker parameters (DIA/REG, Ts/Tm, NOR/HOP, TRI/HOP and STER/PENT). The research results described in the article clearly indicate the need for further studies of geochemical features of the organic matter of the Paleozoic mantle rocks and the underlying sedimentary and crystalline complexes of Precambrian.

Stratigraphy and Mesozoic–Cenozoic tectonic history of northern Sierra Los Ajos and adjacent areas, Sonora, Mexico

USGS Publications Warehouse

Page, William R.; Gray, Floyd; Iriondo, Alexander; Miggins, Daniel P.; Blodgett, Robert B.; Maldonado, Florian; Miller, Robert J.

2010-01-01

Geologic mapping in the northern Sierra Los Ajos reveals new stratigraphic and structural data relevant to deciphering the Mesozoic–Cenozoic tectonic evolution of the range. The northern Sierra Los Ajos is cored by Proterozoic, Cambrian, Devonian, Mississippian, and Pennsylvanian strata, equivalent respectively to the Pinal Schist, Bolsa Quartzite and Abrigo Limestone, Martin Formation, Escabrosa Limestone, and Horquilla Limestone. The Proterozoic–Paleozoic sequence is mantled by Upper Cretaceous rocks partly equivalent to the Fort Crittenden and Salero Formations in Arizona, and the Cabullona Group in Sonora, Mexico.Absence of the Upper Jurassic–Lower Cretaceous Bisbee Group below the Upper Cretaceous rocks and above the Proterozoic–Paleozoic rocks indicates that the Sierra Los Ajos was part of the Cananea high, a topographic highland during the Late Jurassic and Early Cretaceous. Deposition of Upper Cretaceous rocks directly on Paleozoic and Proterozoic rocks indicates that the Sierra Los Ajos area had subsided as part of the Laramide Cabullona basin during Late Cretaceous time. Basal beds of the Upper Cretaceous sequence are clast-supported conglomerate composed locally of basement (Paleozoic) clasts. The conglomerate represents erosion of Paleozoic basement in the Sierra Los Ajos area coincident with development of the Cabullona basin.The present-day Sierra Los Ajos reaches elevations of greater than 2600 m, and was uplifted during Tertiary basin-and-range extension. Upper Cretaceous rocks are exposed at higher elevations in the northern Sierra Los Ajos and represent an uplifted part of the inverted Cabullona basin. Tertiary uplift of the Sierra Los Ajos was largely accommodated by vertical movement along the north-to-northwest-striking Sierra Los Ajos fault zone flanking the west side of the range. This fault zone structurally controls the configuration of the headwaters of the San Pedro River basin, an important bi-national water resource in the US-Mexico border region.

Deformation of the Roberts Mountains Allochthon in north-central Nevada

USGS Publications Warehouse

Evans, James George; Theodore, Ted G.

1978-01-01

During the Antler orogeny in Late Devonian and Early Mississippian time, early and middle Paleozoic siliceous rocks, largely chert and sha1e, were thrust eastward for 90 to 160 km over coexisting carbonate rocks. Minor and major structures of two small areas of the allochthon at Battle Mountain and in the southern Tuscarora Mountains were studied in order to characterize the deformation and test the consistency of the movement plan with respect to the large eastward displacement. In the Battle Mountain area, the lower Paleozoic Scott Canyon and Valmy Formations were deformed in the Antler orogeny but were unaffected by later tectonism during late Paleozoic or early Mesozoic. In the southern Tuscarora Mountains area, the Ordovician and Silurian siliceous rocks deformed in the Antler Orogeny were deformed by later, possibly Mesozoic, folding and thrusting. Most of the minor folding visible in the allochthon is in the cheret, but proportionally more of the strain was taken up in the shale and argillite, both poorly exposed but predominant rock types. Most minor folds, concentric in form, plunge at small angles to the north-northeast and south-southwest with steeply dipping or vertical axial planes. The b-fabric axis, parallel to these folds, is identical apparently to the B-kinematic axis. The horizontal component of tectonic shortening of the allochthon, N. 70?-75? W. both in the Battle Mountain area and in the southern Tuscarora Mountains area, is therefore consistent with an eastward direction of movement of the allochthon. Folds with west- northwest trends locally present in the allochthon, may have formed in the direction of tectonic transport. In the southern Tuscarora Mountains, local strain in and below the allochthon was different from the prevailing strain in the allochthon, and tectonic shortening was locally at large angles to the accepted direction of movement of the allochthon.

The Carboniferous of the Western Karakoram (Pakistan)

NASA Astrophysics Data System (ADS)

Gaetani, M.; Zanchi, A.; Angiolini, L.; Olivini, G.; Sciunnach, D.; Brunton, H.; Nicora, A.; Mawson, R.

2004-05-01

The results of the study of the Carboniferous successions in the western part of the Northern Karakoram during three geological expeditions are summarized here. Rocks of that period are not uniformly preserved in the several thrust sheets forming the Northern Karakoram. In most of them only the basal part of the Carboniferous, up to the Visean, is preserved, whilst in the Karambar thrust sheet a more complete section—previously almost unknown—is preserved. Four new lithostratigraphic units, time-constrained by brachiopod and conodont biostratigraphy, are described, from bottom to top: (1) the Margach Formation: prevailing dark shales with subordinate fine subarkoses and quartzarenites, up to 300 m thick (mid-Famennian to middle Tournaisian); (2) the Ribat Formation: grey crinoidal limestones passing upwards to dark marly limestones and marls, at least 300 m thick (middle Tournaisian to Serpukhovian); (3) the Lupsuk Formation: subarkoses to feldspathic quartzarenites in thick beds, alternating with dark shales and siltstones, up to 400 m thick (Serpukhovian to uppermost Carboniferous); (4) within the Lupsuk Formation a local member, the Twin Valleys Member, up to 100 m thick, a bioclastic limestone intercalation of post-Moscovian age, is distinguished. The Carboniferous successions are invariably sealed by the arkoses to quartzarenites of the Gircha Formation, 133 m above the base of which, in the Karambar area, an Asselian brachiopod fauna was recovered. The Carboniferous succession is interpreted as recording the evolution of the passive margin of the Northern Karakoram Terrane, from early rifting stage in the Late Devonian to syn-rift events during the Late Carboniferous. The basal part of the Gircha Formation, of latest Carboniferous-earliest Permian age, is considered to have been deposited above a break-up unconformity, linked to the early drifting in the seaway bordering the Karakoram. In the palaeontological appendix the most significant brachiopod taxa (19 species, one new) are described.

The Thermal Evolution of the Southeast Baffin Island Continental Margin: An Integrated Apatite Fission Track and Apatite (U-Th)/He Study

NASA Astrophysics Data System (ADS)

Jess, S.; Stephenson, R.; Brown, R. W.

2017-12-01

The elevated continental margins of the North Atlantic continue to be a focus of considerable geological and geomorphological debate, as the timing of major tectonic events and the age of topographic relief remain controversial. The West Greenland margin, on the eastern flank of Baffin Bay, is believed by some authors to have experienced tectonic rejuvenation and uplift during the Neogene. However, the opposing flank, Baffin Island, is considered to have experienced a protracted erosional regime with little tectonic activity since the Cretaceous. This work examines the thermal evolution of the Cumberland Peninsula, SE Baffin Island, using published apatite fission track (AFT) data with the addition of 103 apatite (U-Th)/He (AHe) ages. This expansion of available thermochronological data introduces a higher resolution of thermal modelling, whilst the application of the newly developed `Broken Crystals' technique provides a greater number of thermal constraints for an area dominated by AHe age dispersion. Results of joint thermal modelling of the AFT and AHe data exhibit two significant periods of cooling across the Cumberland Peninsula: Devonian/Carboniferous to the Triassic and Late Cretaceous to present. The earliest phase of cooling is interpreted as the result of major fluvial systems present throughout the Paleozoic that flowed across the Canadian Shield to basins in the north and south. The later stage of cooling is believed to result from rift controlled fluvial systems that flowed into Baffin Bay during the Mesozoic and Cenozoic during the early stages and culmination of rifting along the Labrador-Baffin margins. Glaciation in the Late Cenozoic has likely overprinted these later river systems creating a complex fjordal distribution that has shaped the modern elevated topography. This work demonstrates how surface processes, and not tectonism, can explain the formation of elevated continental margins and that recent methodological developments in the field of low temperature thermochronology are improving our understanding of onshore passive margin development.

Thermal history and differential exhumation across the Eastern Musgrave Province, South Australia: Insights from low-temperature thermochronology

NASA Astrophysics Data System (ADS)

Glorie, Stijn; Agostino, Kate; Dutch, Rian; Pawley, Mark; Hall, James; Danišík, Martin; Evans, Noreen J.; Collins, Alan S.

2017-04-01

Multi-method geo- and thermochronological data obtained for Palaeo- and Mesoproterozoic granitoids traversing the main structural architecture of the eastern Musgrave Province within South Australia reveal multiphase cooling histories. Apatite U-Pb dating on six samples yield consistent ages of 1075-1025 Ma, suggesting a thermal reset coinciding with mantle-derived magmatism of the greater Warakurna Large Igneous Province ( 1080-1040 Ma). Apatite fission track (AFT) analysis indicate that four discrete thermal events affected the study area, inducing cooling through the AFT partial annealing zone ( 60-120 °C), supported by apatite and zircon (U-Th-Sm)/He data. Late Neoproterozoic cooling from deep crustal levels to temperatures < 200 °C was discerned, which is thought to be related to exhumation and denudation during the Petermann Orogeny. Subsequent cooling events at 450-400 Ma (Silurian-Devonian) and 310-290 Ma (Late Carboniferous) are interpreted to represent exhumation associated with the Alice Springs Orogeny. The latter event exhumed the sampled plutons to shallow crustal depths. An additional Triassic - early Jurassic thermal event, likely recording elevated geothermal gradients at that time, was observed throughout the study area, however, more data is needed to further support this interpretation. The high sample density across the structural architecture of the study area furthermore reveals patterns of fault reactivation and resulting differential exhumation, indicating shallower exhumation levels in the centre and deeper exhumation towards the margins of the sampled transect. The observed differential exhumation patterns match with existing seismic data and fit a model of an inverted graben system for the Phanerozoic evolution of the eastern Musgraves. The results highlight a complex Phanerozoic thermal history for the eastern Musgraves and help to elucidate the poorly appreciated tectonic evolution of inland Australia. This study further demonstrates how high-density sample transects across structural architecture can assess the relative crustal level and associated preservation of the thermal history record within fault-reactivated terranes.

The Paleoecology, Habitats, and Stratigraphic Range of the Enigmatic Cretaceous Brachiopod Peregrinella

PubMed Central

Kiel, Steffen; Glodny, Johannes; Birgel, Daniel; Bulot, Luc G.; Campbell, Kathleen A.; Gaillard, Christian; Graziano, Roberto; Kaim, Andrzej; Lazăr, Iuliana; Sandy, Michael R.; Peckmann, Jörn

2014-01-01

Modern and Cenozoic deep-sea hydrothermal-vent and methane-seep communities are dominated by large tubeworms, bivalves and gastropods. In contrast, many Early Cretaceous seep communities were dominated by the largest Mesozoic rhynchonellid brachiopod, the dimerelloid Peregrinella, the paleoecologic and evolutionary traits of which are still poorly understood. We investigated the nature of Peregrinella based on 11 occurrences world wide and a literature survey. All in situ occurrences of Peregrinella were confirmed as methane-seep deposits, supporting the view that Peregrinella lived exclusively at methane seeps. Strontium isotope stratigraphy indicates that Peregrinella originated in the late Berriasian and disappeared after the early Hauterivian, giving it a geologic range of ca. 9.0 (+1.45/–0.85) million years. This range is similar to that of rhynchonellid brachiopod genera in general, and in this respect Peregrinella differs from seep-inhabiting mollusks, which have, on average, longer geologic ranges than marine mollusks in general. Furthermore, we found that (1) Peregrinella grew to larger sizes at passive continental margins than at active margins; (2) it grew to larger sizes at sites with diffusive seepage than at sites with advective fluid flow; (3) despite its commonly huge numerical abundance, its presence had no discernible impact on the diversity of other taxa at seep sites, including infaunal chemosymbiotic bivalves; and (4) neither its appearance nor its extinction coincides with those of other seep-restricted taxa or with global extinction events during the late Mesozoic. A preference of Peregrinella for diffusive seepage is inferred from the larger average sizes of Peregrinella at sites with more microcrystalline carbonate (micrite) and less seep cements. Because other seep-inhabiting brachiopods occur at sites where such cements are very abundant, we speculate that the various vent- and seep-inhabiting dimerelloid brachiopods since Devonian time may have adapted to these environments in more than one way. PMID:25296341

Dutrochus, a new microdomatid (Gastropoda) genus from the Middle Devonian (Eifelian) of west-central Alaska

USGS Publications Warehouse

Blodgett, R.B.

1993-01-01

A new gastropod genus, Dutrochus, is established for members of the family Microdomatidae that are characterized by a reticulate ornament of spiral cords and intersecting, finer collabral threads, with all but one spiral cord being of nearly equal strength, and the single remaining cord being of stronger (nearly twice the order) magnitude and being situated at the periphery. It is represented by the type and only known species, Dutrochus alaskensis n. gen. and sp., from the upper part (lower Eifelian) of the Lower? and Middle Devonian Cheeneetnuk Limestone. The genus is very close and nearly homeomorphic to the Permian microdomatid genus Glyptospira. -from Author

Impact ejecta layer from the mid-Devonian: possible connection to global mass extinctions.

PubMed

Ellwood, Brooks B; Benoist, Stephen L; El Hassani, Ahmed; Wheeler, Christopher; Crick, Rex E

2003-06-13

We have found evidence for a bolide impacting Earth in the mid-Devonian ( approximately 380 million years ago), including high concentrations of shocked quartz, Ni, Cr, As, V, and Co anomalies; a large negative carbon isotope shift (-9 per mil); and microspherules and microcrysts at Jebel Mech Irdane in the Anti Atlas desert near Rissani, Morocco. This impact is important because it is coincident with a major global extinction event (Kacák/otomari event), suggesting a possible cause-and-effect relation between the impact and the extinction. The result may represent the extinction of as many as 40% of all living marine animal genera.

Input-form data for the U.S. Geological Survey assessment of the Devonian and Mississippian Bakken and Devonian Three Forks Formations of the U.S. Williston Basin Province, 2013

USGS Publications Warehouse

,; Gaswirth, Stephanie B.; Marra, Kristen R.; Cook, Troy A.; Charpentier, Ronald R.; Gautier, Donald L.; Higley, Debra K.; Klett, Timothy R.; Lewan, Michael D.; Lillis, Paul G.; Schenk, Christopher J.; Tennyson, Marilyn E.; Whidden, Katherine J.

2013-01-01

In 2013, the U.S. Geological Survey assessed the technically recoverable oil and gas resources of the Bakken and Three Forks Formations of the U.S. portion of the Williston Basin. The Bakken and Three Forks Formations were assessed as continuous and hypothetical conventional oil accumulations using a methodology similar to that used in the assessment of other continuous- and conventional-type assessment units throughout the United States. The purpose of this report is to provide supplemental documentation and information used in the Bakken-Three Forks assessment.

Origins and relationships of colonial Heliophyllum in the upper Middle Devonian (Givetian) of New York

USGS Publications Warehouse

Oliver, W.A.

1997-01-01

Heliophyllum halli Milne-Edwards and Haime is common to abundant in many Lower and Middle Devonian stratigraphic units in New York. Most Heliophyllum are solitary, but both branching and massive colonies are known. Four 'populations' of colonial Heliophyllum in the Givetian part of the sequence are distinct, as is a fifth form that occurs through the section. Each of the colonial forms is interpreted as an independent derivative of solitary forms of H. halli. The relationships appear to range from infrasubspecific to specific, and it is suggested that the complex should be recognized as the Heliophyllum halli species group.

Impact Ejecta Layer from the Mid-Devonian: Possible Connection to Global Mass Extinctions

NASA Astrophysics Data System (ADS)

Ellwood, Brooks B.; Benoist, Stephen L.; Hassani, Ahmed El; Wheeler, Christopher; Crick, Rex E.

2003-06-01

We have found evidence for a bolide impacting Earth in the mid-Devonian (~380 million years ago), including high concentrations of shocked quartz, Ni, Cr, As, V, and Co anomalies; a large negative carbon isotope shift (-9 per mil); and microspherules and microcrysts at Jebel Mech Irdane in the Anti Atlas desert near Rissani, Morocco. This impact is important because it is coincident with a major global extinction event (Kacák/otomari event), suggesting a possible cause-and-effect relation between the impact and the extinction. The result may represent the extinction of as many as 40% of all living marine animal genera.

Affinities and architecture of Devonian trunks of Prototaxites loganii.

PubMed

Retallack, G J; Landing, Ed

2014-01-01

Devonian fossil logs of Prototaxites loganii have been considered kelp-like aquatic algae, rolled up carpets of liverworts, enormous saprophytic fungal fruiting bodies or giant lichens. Algae and rolled liverwort models cannot explain the proportions and branching described here of a complete fossil of Prototaxites loganii from the Middle Devonian (386 Ma) Bellvale Sandstone on Schunnemunk Mountain, eastern New York. The "Schunnemunk tree" was 8.83 m long and had six branches, each about 1 m long and 9 cm diam, on the upper 1.2 m of the main axis. The coalified outermost layer of the Schunnemunk trunk and branches have isotopic compositions (δ(13)CPDB) of -25.03 ± 0.13‰ and -26.17 ± 0.69‰, respectively. The outermost part of the trunk has poorly preserved invaginations above cortical nests of coccoid cells embraced by much-branched tubular cells. This histology is unlike algae, liverworts or vascular plants and most like lichen with coccoid chlorophyte phycobionts. Prototaxites has been placed within Basidiomycota but lacks clear dikaryan features. Prototaxites and its extinct order Nematophytales may belong within Mucoromycotina or Glomeromycota. © 2014 by The Mycological Society of America.

Thermal maturity patterns in New York State using CAI and %Ro

USGS Publications Warehouse

Weary, D.J.; Ryder, R.T.; Nyahay, R.E.

2001-01-01

New conodont alteration index (CAI) and vitrinite reflectance (%Ro) data collected from drill holes in the Appalachian basin of New York State allow refinement of thermal maturity maps for Ordovician and Devonian rocks. CAI isotherms on the new maps show a pattern that approximates that published by Harris et al. (1978) in eastern and western New York, but it differs in central New York, where the isotherms are shifted markedly westward by more than 100 km and are more tightly grouped. This close grouping of isograds reflects a steeper thermal gradient than previously noted by Harris et al. (1978) and agrees closely with the abrupt west-to-east increase in thermal maturity across New York noted by Johnsson (1986). These data show, in concordance with previous studies, that thermal maturity levels in these rocks are higher than can be explained by simple burial heating beneath the present thickness of overburden. The Ordovician and Devonian rocks of the Appalachian Basin in New York must have been buried by very thick post-Devonian sediments (4-6 km suggested by Sarwar and Friedman 1995) or were exposed to a higher-than-normal geothermal flux caused by crustal extension, or a combination of the two.

Devonian Terrestrial Revolution: the palaeoenvironment of the oldest known tetrapod tracks, Zachełmie Quarry, Poland

NASA Astrophysics Data System (ADS)

Niedźwiedzki, G.

2012-04-01

Numerous trackways and isolated prints with digit impressions, which are similar to the foot anatomy of early tetrapods such as Ichthyostega, were found on the three dolomite bed-surfaces in the lower part of the Wojciechowice Formation exposed in the Zachełmie Quarry in the Holy Cross Mountains (south-central Poland), (Niedźwiedzki et al., 2010). The age of the tetrapod track-bearing strata is well-constrained, but the detailed sedimentology of the lower section with tetrapod ichnites is still under study. The Wojciechowice Formation represent one of the first carbonate stages of a transgressive succession that begins with Early Devonian continental to marginal marine clastics and culminates in the development of a Givetian coral-stromatoporoid carbonate platform. The tetrapod track-bearing complex is composed of grey to reddish, thin- to medium-bedded dolomitic shales and marly dolomite mudstones. These deposits from the tetrapod track-bearing horizon lack definitive marine body fossils, and may have formed in a marginal marine environment, e.g. around a coastal lagoon. Mudcracks, columnar peds, root traces, and microbially induced sedimentary structures were found in three distinct pedotypes of very weakly to weakly developed paleosols (Retallack, 2011). Conodonts of the costatus zone (mid-Eifelian) were found 20 m above the uppermost surface with tetrapod tracks in limestones of the upper Wojciechowice Formation, which contain also brachiopod and crinoidal debris. The overlying Kowala Formation is a marine coral limestone and dolostone. The parts of profile with tetrapod ichnites and invertebrate and conodont fossils contain also records of invertebrate traces. Seven ichnotaxa are distributed among four recognized ichnoassemblages. The recognized ichnocoenoses are typical for the shallow-marine (Cruziana ichnofacies) and land-water transitional (Skolithos/Psilonichnus ichnofacies) carbonate depositional environments. The ichnocoenoses are dominated by trace fossils produced by arthropods (probably crustaceans), a group that can create large and distinctive burrows. The palaeoecological information from the Zachełmie section has direct bearing on the interpretation of environmental aspects of tetrapod emergence and terrestrialization. It should be fully integrated with data from other Devonian tetrapod tracksites. Niedźwiedzki, G., Szrek P., Narkiewicz K., Narkiewicz M. and Ahlberg P.E. 2010. Tetrapod trackways from the early Middle Devonian period of Poland. Nature, 463: 43-48. Retallack, G.J. 2011. Woodland Hypothesis for Devonian Tetrapod Evolution. The Journal of Geology, 119, 3: 235-258

Assessment of Paleozoic terrane accretion along the southern central Andes using detrital zircon geochronology

NASA Astrophysics Data System (ADS)

McKenzie, R.; Horton, B. K.; Fuentes, F.; Fosdick, J. C.; Capaldi, T.; Stockli, D. F.; Alvarado, P. M.

2015-12-01

Two distinct Paleozoic terranes known as Cuyania and Chilenia occupy the southern central Andes of Argentina and Chile. Because the proposed terrane boundaries coincide with major structural elements of the modern Andean system at 30-36°S, it is important to understand their origins and potential role in guiding later Andean deformation. The Cuyania terrane of western Argentina encompasses the Precordillera (PC) and a thick-skinned thrust block of the western Sierras Pampeanas, persisting southward to the San Rafael Basin (SRB). Although recently challenged, Cuyania has been long considered a piece of southern Laurentia that rifted away during the early Cambrian and collided with the Argentine margin during the Ordovician. Chilenia is situated west of Cuyania and includes the Frontal Cordillera (FC) and Andean magmatic arc. This less-studied terrane was potentially accreted during an enigmatic Devonian orogenic event. We present new detrital zircon U-Pb age data from siliciclastic sedimentary rocks that span the entire Paleozoic to Triassic from the FC, PC, and SRB. Cambrian rocks of the PC exhibit similar zircon age distributions with prominent ~1.4 and subordinate ~1.1 Ga populations, which are distinct from other Paleozoic strata. Plutonic rocks with these ages are common in southern Laurentia, whereas ~1.4 Ga zircons are uncommon in South American age distributions. This supports a Laurentian origin for Cuyania in isolation from Argentina during the Cambrian. Upper Paleozoic strata from the PC, FC, and SRB all yield similar age data suggesting shared provenance across the proposed Cuyania-Chilenia suture. Age distributions also notably lack Devonian-age grains. The regional paucity of Devonian plutonic rocks and detrital zircon casts doubt on a possible arc system between these terranes at this time, a key requisite for the mid-Paleozoic transfer and accretion of Chilenia to the Argentine margin. Collectively, these data question the precise boundaries of the Chilenia terrane.

Provenance and paleogeography of the Devonian Durazno Group, southern Parana Basin in Uruguay

NASA Astrophysics Data System (ADS)

Uriz, N. J.; Cingolani, C. A.; Basei, M. A. S.; Blanco, G.; Abre, P.; Portillo, N. S.; Siccardi, A.

2016-03-01

A succession of Devonian cover rocks occurs in outcrop and in the subsurface of central-northern Uruguay where they were deposited in an intracratonic basin. This Durazno Group comprises three distinct stratigraphic units, namely the Cerrezuelo, Cordobés and La Paloma formations. The Durazno Group does not exceed 300 m of average thickness and preserves a transgressive-regressive cycle within a shallow-marine siliciclastic shelf platform, and is characterized by an assemblage of invertebrate fossils of Malvinokaffric affinity especially within the Lower Devonian Cordobés shales. The sedimentary provenance of the Durazno Group was determined using petrography, geochemistry, and morphological studies of detrital zircons as well as their U-Pb ages. Sandstone petrography of Cerrezuelo and La Paloma sequences shows that they have a dominantly quartz-feldspathic composition with a minor contribution of other minerals. Whole-rock geochemical data indicate that alteration was strong in each of the three formations studied; chondritic-normalized REE patterns essentially parallel to PAAS, the presence of a negative Eu-anomaly, and Th/Sc and La/Hf ratios point to an average source composition similar to UCC or slightly more felsic. Within the Cerrezuelo Formation, recycling of older volcano-metasedimentary sources is interpreted from Zr/Sc ratios and high Hf, Zr, and REE concentrations. U-Pb detrital zircon age populations of the Cerrezuelo and La Paloma formations indicate that the principal source terranes are of Neoproterozoic age, but include also minor populations derived from Mesoproterozoic and Archean-Paleoproterozoic rocks. A provenance from the Cuchilla Dionisio-Dom Feliciano, Nico Pérez and Piedra Alta terranes of Uruguay and southern Brazil is likely. This study establishes an intracratonic extensional tectonic setting during Durazno time. Considering provenance age sources, regional paleocurrent distributions and the established orogenic history recorded in SW Gondwana, we suggest that the basin fill was derived from paleohighs located in what is currently SE Uruguay.

The giant Carlin gold province: A protracted interplay of orogenic, basinal, and hydrothermal processes above a lithospheric boundary

USGS Publications Warehouse

Emsbo, P.; Groves, D.I.; Hofstra, A.H.; Bierlein, F.P.

2006-01-01

Northern Nevada hosts the only province that contains multiple world-class Carlin-type gold deposits. The first-order control on the uniqueness of this province is its anomalous far back-arc tectonic setting over the rifted North American paleocontinental margin that separates Precambrian from Phanerozoic subcontinental lithospheric mantle. Globally, most other significant gold provinces form in volcanic arcs and accreted terranes proximal to convergent margins. In northern Nevada, periodic reactivation of basement faults along this margin focused and amplified subsequent geological events. Early basement faults localized Devonian synsedimentary extension and normal faulting. These controlled the geometry of the Devonian sedimentary basin architecture and focused the discharge of basinal brines that deposited syngenetic gold along the basin margins. Inversion of these basins and faults during subsequent contraction produced the complex elongate structural culminations that characterize the anomalous mineral deposit "trends." Subsequently, these features localized repeated episodes of shallow magmatic and hydrothermal activity that also deposited some gold. During a pulse of Eocene extension, these faults focused advection of Carlin-type fluids, which had the opportunity to leach gold from gold-enriched sequences and deposit it in reactive miogeoclinal host rocks below the hydrologic seal at the Roberts Mountain thrust contact. Hence, the vast endowment of the Carlin province resulted from the conjunction of spatially superposed events localized by long-lived basement structures in a highly anomalous tectonic setting, rather than by the sole operation of special magmatic or fluid-related processes. An important indicator of the longevity of this basement control is the superposition of different gold deposit types (e.g., Sedex, porphyry, Carlin-type, epithermal, and hot spring deposits) that formed repeatedly between the Devonian and Miocene time along the trends. Interestingly, the large Cretaceous Alaska-Yukon intrusion-related gold deposits (e.g., Fort Knox) are associated with the northern extension of the same lithospheric margin in the Selwyn basin, which experienced an analogous series of geologic events. ?? Springer-Verlag 2006.

The blueschits from the Kopina Mt., West Sudetes, Poland - what do they tell us about accretion of the Variscides?

NASA Astrophysics Data System (ADS)

Majka, Jarosław; Mazur, Stanisław; Kośmińska, Karolina; Dudek, Krzysztof

2015-04-01

Blueschists are tracers of sutures, thus marking fossil subduction zones at convergent plate boundaries and providing important constraints on plate tectonic reconstructions. Their occurrences are scarce in the Variscan belt owing to a strong collisional overprint but just because of that each locality deserves particular attention. The Variscan blueschists must have formed during the early stage of the Variscan Orogeny and may represent a vestige of missing marginal basins fringing the Rheic Ocean at the onset of subduction. The studied rocks from the Kopina Mt. consist mainly of garnet, glaucophane, clinozoisite-epidote, chlorite-I, titanite, hematite and quartz. The original high-pressure assemblage is overprinted by later, lower pressure paragenesis, which comprises mostly Ca-amphiboles, chlorite-II, albite and K-feldspar. The latter occurs in polymineral inclusions in other phases together with albite and chlorite that are interpreted as phengite breakdown products. Garnet shows chemical compositional variation from Alm54Prp3Grs30Sps13 in the cores to Alm66Prp4Grs29Sps1 in the rims. The almandine zoning is bowl-shaped, whereas spessartine profiles show bell-shaped trends. The grossular and pyrope contents are generally constant throughout the grain. Rather gradual changes in the chemical zoning suggest a progressive, one-step garnet growth pattern. Glaucophane, although commonly well preserved, in some cases disintegrates to the albite-chlorite assemblage. The pressure-temperature (P-T) conditions were estimated using the phase equilibrium modelling in the NCKFMMnASHTO system using the PerpleX software. The compositional isopleths cross cut in the stability field of Grt+Gln+Ep+Chl+Pheng+Ttn+Hem+Q. P-T estimates indicate that the peak conditions occur at c. 14-17 kbar and 470-500°C, which corresponds to quite a low geothermal gradient in the range of 8-10°C/km. The P-T conditions estimated lie on a low temperature geotherm that is typical for a relatively cool subduction of the oceanic crust. Therefore, the origin of the studied rocks dates back to the time preceding accretion of the eastern Variscides and defines one of the key tectonic boundaries in the Bohemian Massif. A mechanism for syn-collisional emplacement and exhumation of the Kopina blueschists can be tentatively explained through activation of the double subduction system operating towards the east. First subduction commenced already in the Early Devonian and operated beneath an island arc located in proximity to the Saxothuringian margin, within the Rheic Ocean. After the mid-Devonian exhumation of the Central Sudetes allochthon, another subduction system was initiated along the eastern margin of the Rheic Ocean, beneath the Brunia microplate. Subducted oceanic crust of the Rheic Ocean (including the Kopina Mt. blueschists) reached peak metamorphic conditions in the Late Devonian, the event pronounced by a continental arc volcanism along the Brunian margin. Exhumation of the subducted oceanic crust was accommodated by the slab roll-back, which is inferred from the bimodal age and spatial distribution of the volcanic activity within the Brunian active margin. Shortly after the Kopina Mt. blueschists exhumation this eastern subduction system became probably inactive. In contrast, the western one involving the Saxothuringian margin was still operating leading to the subsequent collision with Brunia in the Early Carboniferous that produced a widespread high temperature overprint mostly wiping up the earlier metamorphic history.

Geodynamic interpretation of the 40Ar/39Ar dating of ophiolitic and arc-related mafics and metamafics of the northern part of the Anadyr-Koryak region

USGS Publications Warehouse

Palandzhyan, S.A.; Layer, P.W.; Patton, W.W.; Khanchuk, A.I.

2011-01-01

Isotope datings of amphibole-bearing mafics and metamafics in the northern part of the Anadyr-Koryak region allow clarification of the time of magmatic and metamorphic processes, which are synchronous with certain stages of the geodynamic development of the northwest segment of the Pacific mobile belt in the Phanerozoic. To define the 40Ar/39Ar age of amphiboles, eight samples of amphibole gabbroids and metamafics were selected during field work from five massifs representing ophiolites and mafic plutons of the island arc. Rocks from terranes of three foldbelts: 1) Pekulnei (Chukotka region), 2) Ust-Belaya (West Koryak region), and 3) the Tamvatnei and El'gevayam subterranes of the Mainits terrane (Koryak-Kamchatka region), were studied. The isotope investigations enabled us to divide the studied amphiboles into two groups varying in rock petrographic features. The first was represented by gabbroids of the Svetlorechensk massif of the Pekulnei Range and by ophiolites of the Tamvatnei Mts.; their magmatic amphiboles show the distribution of argon isotopes in the form of clearly distinguished plateau with an age ranging within 120-129 Ma. The second group includes metamorphic amphiboles of metagabbroids and apogabbro amphibolites of the Ust-Belaya Mts., Pekulnei and Kenkeren ranges (El'gevayam subterranes). Their age spectra show loss of argon and do not provide well defined plateaus the datings obtained for them are interpreted as minimum ages. Dates of amphiboles from the metagabbro of the upper tectonic plate of the Ust-Belaya allochthon points to metamorphism in the suprasubduction environment in the fragment of Late Neoproterozoic oceanic lithosphere in Middle-Late Devonian time, long before the Uda-Murgal island arc system was formed. The amphibolite metamorphism in the dunite-clinopyroxenite-metagabbro Pekulnei sequence was dated to occur at the Permian-Triassic boundary. The age of amphiboles from gabbrodiorites of the Kenkeren Range was dated to be Early Jurassic that confirmed their assignment to the El'gevayam volcanic-plutonic assemblage. These data are consistent with geological concepts and make more precise the available age dates. Neocomian-Aptian 40Ar/39Ar age of amphibolites from the Pekulnei and Tamvatnei gabbroids make evident that mafics of these terranes (varying in geodynamic formation settings and in petrogenesis) were generated in later stages of the development of the West Pekulnei and Mainits-Algan Middle-Late Jurassic-Early Cretaceous island arc systems, presumably due to breakup of island arcs in the Neocomian. ?? 2011 Pleiades Publishing, Ltd.

Plume type ophiolites in Japan, East Russia and Mongolia: Peculiarity of the Late Jurassic examples

NASA Astrophysics Data System (ADS)

Ishiwatari, Akira; Ichiyama, Yuji; Ganbat, Erdenesaikhan

2013-04-01

Dilek and Furnes (2011; GSAB) provided a new comprehensive classification of ophiolites. In addition to the mid-ocean ridge (MOR) and supra-subduction zone (SSZ) types that are known for decades, they introduced rift-zone (passive margin) type, volcanic arc (active margin) type, and plume type. The last type is thought to be originated in oceanic large igneous provinces (LIPs; oceanic plateaus), and is preserved in the subduction-accretion complexes in the Pacific margins. The LIP-origin greenstones occur in the Middle Paleozoic (Devonian) accretionary complex (AC) in central Mongolia (Ganbat et al. 2012; AGU abst.). The Late Paleozoic and Mesozoic plume-type ophiolites are abundant in Japan. They are Carboniferous greenstones covered by thick limestone in the Akiyoshi belt (Permian AC, SW Japan; Tatsumi et al., 2000; Geology), Permian greenstones in the Mino-Tamba belt (Jurassic AC, SW Japan; Ichiyama et al. 2008; Lithos), and Late Jurassic-Early Cretaceous greenstone in the Sorachi (Hokkaido; Ichiyama et al, 2012; Geology) and Mikabu (SW Japan; this study) belts. The LIP origin of these greenstones is indicated by abundance of picrite (partly komatiite and meimechite), geochemical features resembling HIMU basalts (e.g. high Nb/Y and Zr/Y) and Mg-rich (up to Fo93) picritic olivines following the "mantle array", suggesting very high (>1600oC) temperature of the source mantle plume. The Sorachi-Mikabu greenstones are characterized by the shorter time interval between magmatism and accretion than the previous ones, and are coeval with the meimechite lavas and Alaskan-type ultramafic intrusions in the Jurassic AC in Sikhote-Alin Mountains of Primorye (E. Russia), that suggest a superplume activity in the subduction zone (Ishiwatari and Ichiyama, 2004; IGR). The Mikabu greenstones extend for 800 km along the Pacific coast of SW Japan, and are characterized by the fragmented "olistostrome" occurrence of the basalts, gabbros and ultramafic cumulate rocks (but no mantle peridotite), suggesting tectonism in a sediment-starved subduction zone or a transform fault zone that transected the thick oceanic LIP crust. The Sorachi greenstones are associated with depleted mantle peridotite, and are covered by the thick Cretaceous turbidite formation (Yezo Group), and Takashima et al. (2002; JAES) concluded the marginal basin origin for the "Sorachi ophiolite". We know that some oceanic LIPs were developed into marginal basins (e.g. Caribbean basin). The Late Jurassic-Early Cretaceous greenstone belts of Japan and eastern Russia may represent relics of a 2000 km-size superplume activity that hit the subduction zone and the adjacent ocean floor in NW Pacific.

Zirconology of lherzolites in the Nurali Massif

NASA Astrophysics Data System (ADS)

Krasnobaev, A. A.; Rusin, A. I.; Anfilogov, V. N.; Valizer, P. M.; Busharina, S. V.; Medvedeva, E. V.

2017-06-01

The age trend (SHRIMP U/Pb) of the evolution of zircon is obtained for the first time in lherzolites of the Nurali Massif. Zircons are subdivided into groups by the crystallomorphological and geochemical features. These specific features in zircon development are confirmed by the age dates. Precambrian dates (no younger than 1190 Ma) correspond to mantle sources of the lherzolite block. The Early Silurian (445-448 and 439-440 Ma) wass the time of lherzolite magmatism of 10-15 Ma in duration. The Middle Devonian (382.9 ± 8.7 Ma) corresponded to postmagmatic processes related to the effect of gabbro-diorite intrusions crowning in the Nurali Massif.

The Human Centrifuge

NASA Astrophysics Data System (ADS)

van Loon, Jack J. W. A.

2009-01-01

Life on Earth has developed at unit gravity, 9.81 m/s2, which was a major factor especially when vertebrates emerged from water onto land in the late Devonian, some 375 million years ago. But how would nature have evolved on a larger planet? We are able to address this question simply in experiments using centrifuges. Based on these studies we have gained valuable insights in the physiological process in plants and animals. They adapt to a new steady state suitable for the high-g environments applied. Information on mammalian adaptations to hyper-g is interesting or may be even vital for human space exploration programs. It has been shown in long duration animal hypergravity studies, ranging from snails, rats to primates, that various structures like muscles, bones, neuro-vestibular, or the cardio-vascular system are affected. However, humans have never been exposed to a hyper-g environment for long durations. Centrifuge studies involving humans are mostly in the order of hours. The current work on human centrifuges are all focused on short arm systems to apply short periods of artificial gravity in support of long duration space missions in ISS or to Mars. In this paper we will address the possible usefulness of a large human centrifuge on Earth. In such a centrifuge a group of humans can be exposed to hypergravity for, in principle, an unlimited period of time like living on a larger planet. The input from a survey under scientists working in the field of gravitational physiology, but also other disciplines, will be discussed.

Geochemical and mineralogical sampling of the Devonian shales in the Broadtop synclinorium, Appalachian basin, in Virginia, West Virginia, Maryland, and Pennsylvania

USGS Publications Warehouse

Enomoto, Catherine B.; Coleman, James L.; Swezey, Christopher S.; Niemeyer, Patrick W.; Dulong, Frank T.

2015-01-01

The presence of conventional anticlinal gas fields in the study area that are productive from the underlying Lower Devonian Oriskany Sandstone suggests that an unconventional (or continuous) shale gas system may be in place within the Marcellus Shale in the study area. Results of this study indicate that the Marcellus Shale in the Broadtop synclinorium generally is similar in organic geochemical nature throughout its extent, and based on the sample analyses, there are no clearly identifiable high potential areas (or “sweet spots”) in the study area. This report contains analyses of 132 outcrop and well drill-cuttings samples.

Tabulate Corals after the Frasnian/Famennian Crisis: A Unique Fauna from the Holy Cross Mountains, Poland

PubMed Central

Zapalski, Mikołaj K.; Berkowski, Błażej; Wrzołek, Tomasz

2016-01-01

Famennian tabulate corals were very rare worldwide, and their biodiversity was relatively low. Here we report a unique tabulate fauna from the mid- and late Famennian of the western part of the Holy Cross Mountains (Kowala and Ostrówka), Poland. We describe eight species (four of them new, namely ?Michelinia vinni sp. nov., Thamnoptychia mistiaeni sp. nov., Syringopora kowalensis sp. nov. and Syringopora hilarowiczi sp. nov.); the whole fauna consists of ten species (two others described in previous papers). These corals form two assemblages—the lower, mid-Famennian with Thamnoptychia and the upper, late Famennian with representatives of genera ?Michelinia, Favosites, Syringopora and ?Yavorskia. The Famennian tabulates from Kowala represent the richest Famennian assemblage appearing after the F/F crisis (these faunas appear some 10 Ma after the extinction event). Corals described here most probably inhabited deeper water settings, near the limit between euphotic and disphotic zones or slightly above. At generic level, these faunas show similarities to other Devonian and Carboniferous faunas, which might suggest their ancestry to at least several Carboniferous lineages. Tabulate faunas described here represent new recruits (the basin of the Holy Cross mountains was not a refuge during the F/F crisis) and have no direct evolutionary linkage to Frasnian faunas from Kowala. The colonization of the seafloor took place in two separate steps: first was monospecific assemblage of Thamnoptychia, and later came the diversified Favosites-Syringopora-Michelinia fauna. PMID:27007689

Tabulate Corals after the Frasnian/Famennian Crisis: A Unique Fauna from the Holy Cross Mountains, Poland.

PubMed

Zapalski, Mikołaj K; Berkowski, Błażej; Wrzołek, Tomasz

2016-01-01

Famennian tabulate corals were very rare worldwide, and their biodiversity was relatively low. Here we report a unique tabulate fauna from the mid- and late Famennian of the western part of the Holy Cross Mountains (Kowala and Ostrówka), Poland. We describe eight species (four of them new, namely ?Michelinia vinni sp. nov., Thamnoptychia mistiaeni sp. nov., Syringopora kowalensis sp. nov. and Syringopora hilarowiczi sp. nov.); the whole fauna consists of ten species (two others described in previous papers). These corals form two assemblages-the lower, mid-Famennian with Thamnoptychia and the upper, late Famennian with representatives of genera ?Michelinia, Favosites, Syringopora and ?Yavorskia. The Famennian tabulates from Kowala represent the richest Famennian assemblage appearing after the F/F crisis (these faunas appear some 10 Ma after the extinction event). Corals described here most probably inhabited deeper water settings, near the limit between euphotic and disphotic zones or slightly above. At generic level, these faunas show similarities to other Devonian and Carboniferous faunas, which might suggest their ancestry to at least several Carboniferous lineages. Tabulate faunas described here represent new recruits (the basin of the Holy Cross mountains was not a refuge during the F/F crisis) and have no direct evolutionary linkage to Frasnian faunas from Kowala. The colonization of the seafloor took place in two separate steps: first was monospecific assemblage of Thamnoptychia, and later came the diversified Favosites-Syringopora-Michelinia fauna.

Arsenic in rocks and stream sediments of the central Appalachian Basin, Kentucky

USGS Publications Warehouse

Tuttle, Michele L.W.; Goldhaber, Martin B.; Ruppert, Leslie F.; Hower, James C.

2002-01-01

Arsenic (As) enrichment in coal and stream sediments has been documented in the southern Appalachian basin (see Goldhaber and others, submitted) and is attributed to interaction of rocks and coal with metamorphic fluids generated during the Allegheny Orogeny (late Paleozoic). Similarly derived fluids are expected to affect the coal and in the Kentucky Appalachian Basin to the north as well. In addition, similar processes may have influenced the Devonian oil shale on the western margin of the basin. The major goals of this study are to determine the effect such fluids had on rocks in the Kentucky Appalachian basin (fig. 1), and to understand the geochemical processes that control trace-metal source, residence, and mobility within the basin. This report includes data presented in a poster at the USGS workshop on arsenic (February 21 and 22, 2001), new NURE stream sediment data3 , and field data from a trip in April 2001. Although data for major and minor elements and all detectable trace metals are reported in the Appendices, the narrative of this report primarily focuses on arsenic.

Spatial and temporal correlation of water quality parameters of produced waters from devonian-age shale following hydraulic fracturing.

PubMed

Barbot, Elise; Vidic, Natasa S; Gregory, Kelvin B; Vidic, Radisav D

2013-03-19

The exponential increase in fossil energy production from Devonian-age shale in the Northeastern United States has highlighted the management challenges for produced waters from hydraulically fractured wells. Confounding these challenges is a scant availability of critical water quality parameters for this wastewater. Chemical analyses of 160 flowback and produced water samples collected from hydraulically fractured Marcellus Shale gas wells in Pennsylvania were correlated with spatial and temporal information to reveal underlying trends. Chloride was used as a reference for the comparison as its concentration varies with time of contact with the shale. Most major cations (i.e., Ca, Mg, Sr) were well-correlated with chloride concentration while barium exhibited strong influence of geographic location (i.e., higher levels in the northeast than in southwest). Comparisons against brines from adjacent formations provide insight into the origin of salinity in produced waters from Marcellus Shale. Major cations exhibited variations that cannot be explained by simple dilution of existing formation brine with the fracturing fluid, especially during the early flowback water production when the composition of the fracturing fluid and solid-liquid interactions influence the quality of the produced water. Water quality analysis in this study may help guide water management strategies for development of unconventional gas resources.

Aquifer Characteristics Data Report for the Weldon Spring Site chemical plant/raffinate pits and vicinity properties for the Weldon Spring Site Remedial Action Project, Weldon Spring, Missouri

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1990-11-01

This report describes the procedures and methods used, and presents the results of physical testing performed, to characterize the hydraulic properties of the shallow Mississippian-Devonian aquifer beneath the Weldon Spring chemical plant, raffinate pits, and vicinity properties. The aquifer of concern is composed of saturated rocks of the Burlington-Keokuk Limestone which constitutes the upper portion of the Mississippian-Devonian aquifer. This aquifer is a heterogeneous anisotropic medium which can be described in terms of diffuse Darcian flow overlain by high porosity discrete flow zones and conduits. Average hydraulic conductivity for all wells tested is 9.6E-02 meters/day (3.1E-01 feet/day). High hydraulic conductivitymore » values are representative of discrete flow in the fractured and weathered zones in the upper Burlington-Keokuk Limestone. They indicate heterogeneities within the Mississippian-Devonian aquifer. Aquifer heterogeneity in the horizontal plane is believed to be randomly distributed and is a function of fracture spacing, solution voids, and preglacial weathering phenomena. Relatively high hydraulic conductivities in deeper portions of the aquifer are though to be due to the presence of widely spaced fractures. 44 refs., 27 figs., 9 tabs.« less

Global microbial carbonate proliferation after the end-Devonian mass extinction: Mainly controlled by demise of skeletal bioconstructors

PubMed Central

Yao, Le; Aretz, Markus; Chen, Jitao; Webb, Gregory E.; Wang, Xiangdong

2016-01-01

Microbial carbonates commonly flourished following mass extinction events. The end-Devonian (Hangenberg) mass extinction event is a first-order mass extinction on the scale of the ‘Big Five’ extinctions. However, to date, it is still unclear whether global microbial carbonate proliferation occurred after the Hangenberg event. The earliest known Carboniferous stromatolites on tidal flats are described from intertidal environments of the lowermost Tournaisian (Qianheishan Formation) in northwestern China. With other early Tournaisian microbe-dominated bioconstructions extensively distributed on shelves, the Qianheishan stromatolites support microbial carbonate proliferation after the Hangenberg extinction. Additional support comes from quantitative analysis of the abundance of microbe-dominated bioconstructions through the Famennian and early Tournaisian, which shows that they were globally distributed (between 40° latitude on both sides of the palaeoequator) and that their abundance increased distinctly in the early Tournaisian compared to the latest Devonian (Strunian). Comparison of variations in the relative abundance of skeleton- versus microbe-dominated bioconstructions across the Hangenberg and ‘Big Five’ extinctions suggests that changes in abundance of skeletal bioconstructors may play a first-order control on microbial carbonate proliferation during extinction transitions but that microbial proliferation is not a general necessary feature after mass extinctions. PMID:28009013

Modern methods rediscover deep gas. [Texas

DOE Office of Scientific and Technical Information (OSTI.GOV)

McDonald, J.S.

1979-03-01

In 1973, Northern Natural Gas (NNG) Co.'s Midland exploration and production district acquired a 7-section lease block on a Devonian-Montoya prospect suggested by trend geology and limited seismic data. This acreage block was 2 miles west of the abandoned Hershey field, and included acreage on which the Devonian was tested at noncommercial rates in 1962. Additional seismic data confirmed the presence of a drillable prospect on NNG's acreage block. Engineering analyses of the reservoir characteristics suggested that modern completion and treatment techniques would result in a commercial producer. NNG's management approved the expenditure and the first well was spudded inmore » April, 1977. This well, the No. 1 Hershenson, was completed in Sept., 1977 as the discovery well in the Hershey West (Devonian-Montoya) field for a calculated open flow potential (CAOFP) of 20.5 mmcfd dry gas from perforations at 15,445 to 16,017 ft. The confirmation well, No. 1 Hershenson 6, was spudded in May, 1978, and completed in Oct., 1978, for a CAOFP of 86.3 mmcfd from perforations at 16,000 to 16,624 ft. A third well, No. 1 Maddox-Willbanks 15, was spudded in Nov., 1978. Rediscovered field potential justified construction of a gas processing plant and a 16-mile pipeline.« less

Drilling of a deviated well: E. C. Newell 10056-D Meigs County, Ohio

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rodgers, J.A.

1982-09-30

The Department of Energy's (DOE) Eastern Gas Shales Program (EGSP) has focused primarily on the resource characterization of the Devonian shales in the Appalachian, Michigan and Illinois Basins, where the collective volume of gas in place is estimated to be on the order of 280 Tcf. From an early assessment of the petrophysical properties of these shales, attention now has turned to an understanding of the mechanisms controlling production of this unconventional-gas source. However, present knowledge of the production history of the Devonian shales is inadequate for an accurate estimation of the gas reserves, the optimum well spacing for gasmore » extraction, and the preferred stimulation techniques to be used. As part of this program, a Deviated Well Test was designed to evaluate the spacing of natural fractures in the Devonian shale in Meigs County, Ohio as a follow-on test to further define shale production characteristics and to assess the benefit of additional section gained by drilling through the producing interval at the approximate angle for dip of 60/sup 0/ from vertical. The Columbia Gas Transmission Company, E.C. Newell 10056-D well, on the same site as a previous Off-Set Well Test, was selected for this investigation. This report summarizes drilling operations on this Deviated Well Test.« less

Preliminary investigation of two areas in New York State in terms of possible potential for hot dry rock geothermal energy. [Adirondack Mountains and Catskill Mountains

DOE Office of Scientific and Technical Information (OSTI.GOV)

Isachsen, Y.W.

1978-09-27

Two areas in New York State were studied in terms of possible long range potential for geothermal energy: the Adirondack Mountains which are undergoing contemporary doming, and an anomalous circular feature centered on Panther Mountain in the Catskill Mountains. The Adirondack Mountains constitute an anomalously large, domical uplift on the Appalachian foreland. The domical configuration of the area undergoing uplift, combined with subsidence at the northeastern perimeter of the dome, argues for a geothermal rather than glacioisostatic origin. A contemporary hot spot near the crust-mantle boundary is proposed as the mechanism of doming, based on analogy with uplifts of similarmore » dimensions elsewhere in the world, some of which have associated Tertiary volcanics. The lack of thermal springs in the area, or high heat flow in drill holes up to 370 m deep, indicates that the front of the inferred thermal pulse must be at some depth greater than 1 km. From isopach maps by Rickard (1969, 1973), it is clear that the present Adirondack dome did not come into existence until sometime after Late Devonian time. Strata younger than this are not present to provide further time stratigraphic refinement of this lower limit. However, the consequent radial drainage pattern in the Adirondacks suggests that the dome is a relatively young tectonic feature. Using arguments based on fixed hot spots in central Africa, and the movement of North American plate, Kevin Burke (Appendix I) suggests that the uplift may be less than 4 m.y. old.The other area of interest, the Panther Mountain circular feature in the Catskill Mountains, was studied using photogeology, gravity and magnetic profiling, gravity modeling, conventional field methods, and local shallow seismic refraction profiling.« less

Improving global paleogeographic reconstructions since the Devonian using paleobiology

NASA Astrophysics Data System (ADS)

Cao, Wenchao; Zahirovic, Sabin; Williams, Simon; Flament, Nicolas; Müller, Dietmar

2017-04-01

Paleogeographic reconstructions are important to understand past eustatic and regional sea level change, the tectonic evolution of the planet, hydrocarbon genesis, and to constrain and interpret the dynamic topography predicted by time-dependent global mantle convection models. Several global paleogeographic compilations have been published, generally presented as static snapshots with varying temporal resolution and fixed spatial resolution. Published paleogeographic compilations are tied to a particular plate motion model, making it difficult to link them to alternative digital plate tectonic reconstructions. In order to address this issue, we developed a workflow to reverse-engineer reconstructed paleogeographies to their present-day coordinates and link them to any reconstruction model. Published paleogeographic compilations are also tied to a given dataset. We used fossil data from the Paleobiology Database to identify inconsistencies between fossils paleoenvironments and paleogeographic reconstructions, and to improve reconstructed terrestrial-marine boundaries by resolving these inconsistencies. We used the improved reconstructed paleogeographies to estimate the surface areas of global paleogeographic features (shallow marine environments, landmasses, mountains and ice sheets), to investigate the global continental flooding history since the late Paleozoic, which has inherent links to global eustasy as well as dynamic topography. Finally, we discuss the relationships between our modeled emerged land area and total continental area through time, continental growth models, and strontium isotope (87Sr/86Sr) signatures in ocean water. Our study highlights the flexibility of digital paleogeographic models linked to state-of-the-art plate tectonic reconstructions in order to better understand the interplay of continental growth and eustasy, with wider implications for understanding Earth's paleotopography, ocean circulation, and the role of mantle convection in shaping long-wavelength topography.

New Plants from the Lower Devonian Pingyipu Group, Jiangyou County, Sichuan Province, China

PubMed Central

Edwards, Dianne; Geng, Bao-Yin; Li, Cheng-Sen

2016-01-01

Descriptions of Lower Devonian plants from Yunnan, South China, have revolutionized concepts of diversity and disparity in tracheophytes soon after they became established on land. Sichuan assemblages have received little attention since their discovery almost 25 years ago and require revision. With this objective, fieldwork involving detailed logging and collection of fossils was undertaken in the Longmenshan Mountain Region, Jiangyou County and yielded the two new taxa described here. They are preserved as coalified compressions and impressions that allowed morphological but not anatomical analyses. Yanmenia (Zosterophyllum) longa comb nov is based on numerous rarely branching shoots with enations resembling lycophyte microphylls, without evidence for vasculature. The presence of sporangia is equivocal making assignation to the Lycopsida conjectural. The plant was recently described as a zosterophyll, but lacks strobili. These are present in the second plant and comprise bivalved sporangia. The strobili terminate aerial stems which arise from a basal axial complex displaying diversity in branching including H- and K- forms. These features characterise the Zosterophyllopsida, although the plant differs from Zosterophyllum in valve shape. Comparisons indicate greatest similarities to the Lower Devonian Guangnania cuneata, from Yunnan, but differences, particularly in the nature of the sporangium border, require the erection of a new species, G. minor. Superficial examination of specimens already published indicate a high degree of endemism at both species and generic level, while this study shows that Yanmenia is confined to Sichuan and Guangnania is one of the very few genera shared with Yunnan, where assemblages also show a high proportion of further endemic genera. Such provincialism noted in the Chinese Lower Devonian is explained by the palaeogeographic isolation of the South China plate, but this cannot account for differences/endemism between the Sichuan and Yunnan floras. Such an enigma demands further integrated geological, palaeobotanical and palynological studies. PMID:27851760

The GEORIFT 2013 wide-angle seismic profile, along Pripyat-Dnieper-Donets Basin

NASA Astrophysics Data System (ADS)

Starostenko, Vitaliy; Janik, Tomasz; Yegorova, Tamara; Czuba, Wojciech; Sroda, Piotr; Lysynchuk, Dmytro; Aizberg, Roman; Garetsky, Radim; Karataev, German; Gribik, Yaroslav; Farfuliak, Lliudmyla; Kolomiyets, Katerina; Omelchenko, Victor; Gryn, Dmytro; Guterch, Aleksander; Komminaho, Kari; Legostaeva, Olga; Thybo, Hans; Tiira, Timo; Tolkunov, Anatoly

2017-04-01

The GEORIFT 2013 deep seismic sounding (DSS) experiment was carried in August 2013 on territory of Belarus and Ukraine in wide international co-operation. The aim of the work is to study basin architecture and the deep structure of the Pripyat-Dnieper-Donets Basin (PDDB), which is the deepest and best studied Palaeozoic rift basin in Europe. The PDDB locates in the southern part of the East European Craton (EEC) and crosses in NW direction the Sarmatia, the southernmost of three major segments forming the EEC. The long PDDB was formed by Late Devonian rifting in the arch of the ancient Sarmatian shield. During the Late Devonian, rifting, associated with domal basement uplift and magmatism, was widespread in the EEC from the PDDB rift basin in the south to Eastern Barents Sea in the north. The GEORIFT 2013 runs in NW-SE direction along the PDDB and crosses the Pripyat Trough and Dnieper Graben separated by Bragin uplift of the basement. The total profile length was 675 km: 315 km on the Belarusian territory and 360 km in Ukraine. The field acquisition included 14 shot points (charge 600-1000 kg of TNT), and 309 recording stations every 2.2 km. The data quality of the data was good, with visible first arrivals even up to 670 km. We present final model of the structure to the depth of 80 km. Ray-tracing forward modelling (SEIS83 package) was used for the modelling of the seismic data. The thickness of the sedimentary layer (Vp < 6.0 km/s) changes along the profile from 1-4 km in the NW, through 5 km in the central part, to 10-13 km in the SE part of the profile. In 330-530 km distance range, an updoming of the lower crust (with Vp of 7.1 km/s) to 25 km depth is observed. Large variations in the internal structure of the crust and the Moho topography were detected. The depth of the Moho varies from 47 km in the northwestern part of the model, to 40 km in central part, and to 38 km in the southeastern part of the profile. The sub-Moho velocities are 8.25 km/s. Second, near-horizontal mantle discontinuity was found in the northwestern part of the profile at the depth of 50-47 km. It dips to the depth of 60 km at distances of 360-405 km, similarly as on crossing EUROBRIDGE'97 profile (Thybo et al., 2003). In the central part of the profile (distances 180-330 km and 300-480 km) two reflectors were found in the lower lithosphere at depths of about 62 km and 75 km, respectively.

Evidences of Silurian dextral transpression in the Scandinavian Caledonides

NASA Astrophysics Data System (ADS)

Torgersen, Espen; Viola, Giulio

2017-04-01

The Scandinavian Caledonides are classically interpreted as a fold and thrust belt resulting from the collision between Laurentia and Baltica during the Silurian, which involved the up-to-400 km ESE-wards translation of nappes onto the Baltoscandian platform. It has been suggested that the Caledonian fold and thrust belt formed through several distinct orogenic episodes, from early shortening in the Late Ordovician to orogenic collapse in the Devonian. The classic Caledonian, orogen-perpendicular ESE-ward nappe transport is constrained by abundant and consistently oriented stretching lineations across the entire orogen and unambiguous kinematic indicators. However, there is also a large number of NW-SE-trending and roughly orogen-parallel lineations, particularly in the upper ophiolite- and eclogite-bearing nappes, which are more challenging to interpret with the traditional orogeny evolution model. The analysis of the areal extent, spatial distribution and geometrical relationships of the Caledonian nappes in southern and central Norway, however, offers new insights and allows for new constraints on the bulk kinematic framework of the shortening history of the belt. Here we present new, first-order geological observations that demonstrate a two-fold compressional history and associated strain partitioning during Caledonian convergence. More specifically, we propose that Late Ordovician NNW-SSE shortening caused early compression, followed by WNW-ESE Early Silurian shortening, which resulted in strain partitioning along the planar fabrics and discontinuities from the earlier event. In detail, orogen-parallel dextral wrench tectonics caused significant lateral displacement along at least three, orogen-scale NE-SW striking corridors, wherein the nappes appear to be consistently displaced in a dextral fashion. We propose that the Møre-Trøndelag Fault Complex, which accommodated significant sinistral displacements during the later Devonian orogenic collapse, localized on one of these early dextral shear corridor. This is expressed by the asymptotic dragging of the nappes along it and also the significant morphological asymmetry of the central Norwegian coast line, which is not compatible with sinistral shearing. Along a southern corridor, which extends from the Hardangerfjord to the east of Folldal, the Caledonian foliation is asymptotically bent into the ENE-WSW orientation of the shear corridor, also consistent with an overall dextral kinematics. This is also confirmed by the gradual reorientation and increased strain toward these shear corridors of Ordovician to Silurian intrusive bodies, indicating that the dextral displacement is of Silurian age. Similar dextral displacements along NE-SW faults have previously been interpreted from potential field data offshore southern Norway. Large-scale dextral transpression in the Scandinavian Caledonides readily accounts for numerous geological features that are not as easily reconciled with the more classical model of only ESE-ward translation and/or sinistral transpression.

Water resources of the Clarion River and Redbank Creek basins, northwestern Pennsylvania

USGS Publications Warehouse

Buckwalter, Theodore F.; Dodge, C.H.; Schiner, G.R.; Koester, H.F.

1981-01-01

The Clarion River and Redbank Creek basin occupy 1,280 and 545 square miles, respectively, in northwatern Pennsylvania. The area is mostly in Clerion, Elk, and Jefferson Counties and is approximately 70 miles long and 30 miles wide. All drainage is to the Allegheny River. Sedimentary rocks of Late Devionian Early Mississippian, and Pennsylvanian age underlie the area. Rocks of Late Devonian age underlie the entire area and crop out in the deep stream valleys in the north. Lower Mississippian rocks generally crop out in strips along major stream valleys; the strips are narrow in the south and broaden northward. Pennsylvanian rocks cover most of the interfluvial areas between major streams. The Upper Devonian and Lower Mississippian rocks are composed mostly of alternating sandstone and shale. Sandstone may intertongue laterally with shale. The Pennsylvanian rocks are most heterogeneous and contain many commercial coal beds. The major mineral resources are bituminous coal, petroleum, and natural gas. Narly all coal production is from strip mining in Clarion, Elk, and Jefferson Counties. Total coal production exceeded 8 million short tons in 1976. The basins are south and east of the major oil-producing regions in Pennsylvania, but more than 50,000 barrels of crude oil were produced here in 1975. Commercial quantities of natural gas are also obtained. Thirty-three public water-supply systems furnish about two-thirds of the water for domestic use. Surface water is the source of about 90 percent of public-supply water. The remainder is from wells and springs. In an average year, 64 percent of the precipitation in the Clarion River basin and 60 percent in the Redbank Creek basin leave the area as streamflow. The percentage of annuual discharge from each basin that is base runoff averaged 53 and 51 percent, respectively, during 1972-75. Only 4 of 10 stream-gaging stations recorded an average 10-year, 7-consecutive day low flow of at least 0.15 cubic feet per second per square mile. Most wells are completed on bedrock. Yields of bedrock wells are affected mostly by rock type, type of overburden, topography, depth of water-bearing zones, and by the rate and duration of pumping. Water in the bedrock occurs chiefly along fractures and bedding planes. Most wells get water from several zones. Yielding zones occur less frequently as depth increases, but are reported as much as 400 feet below land surface. Optimum well depth is about 350 feet. Well yields range from less than 1 to more than 550 gallons per minute. The best bedrock aquifers are the Lower Mississippian rocks, which have a median specific capacity of 4.3 gallons per minute per foot of drawdown compared to median between 0.38 and 0.67 in the Conemaugh, Allegheny, and Pottsville Groups. The major water-qualitty problems are due to high concentrations of iron, manganese, hardness, and acidity. Some of these problems are related to coal mining that has degraded water quality in parts of Clarion, Clearfield, Elk, and Jefferson Counties. Water-quality problems result from the rock composition. Many streams have low alkalinity concentrations and, consequently, have little capacity to neutralize the acid water from coal mines. Large forested areas, with little development, in Elk, Forest, and Jefferson Counties, have good quality water. The water from over three-quarters of the bedrock wells sampled has dissolved-solids concentratins less than 250 milligrams per liter. Water from aqufers of Pennsylvanian age is generally lower in dissolved solids than that from Lower Mississippian aquifers. Salt water is not a problem, except locally in Devonian rocks. Water from wells on hilltops is generally of better quality than that from wells in valleys (median dissolved solids 140 versus 340 millgrams per liter). In many valleys in Clarion and Jefferson Counties, old abandoned flowing oil and gas wells contribute high

Geology of the Volga-Ural petroleum province and detailed description of the Ramashkino and Arlan oil fields

USGS Publications Warehouse

Peterson, James A.; Clarke, James W.

1983-01-01

The Volga-Ural petroleum province is in general coincident with the Volga-Ural regional high, a broad upwarp of the east-central part of the Russian (East European) platform. The central part of the province is occupied by the Tatar arch, which contains the major share of the oil fields of the province. The Perm-Bashkir arch forms the northeastern part of the regional high, and the Zhigulevsko-Orenburg arch makes up the southern part. These arches are separated from one another by elongate downwarps. The platform cover overlies an Archean crystalline basement and consists of seven main sedimentation cycles as follows: 1) Riphean (lower Bavly) continental sandstone, shale, and conglomerate beds from 500 to 5,000 m thick deposited in aulacogens. 2) Vendian (upper Bavly) continental and marine shale and sandstone up to 3,000 m thick. 3) Middle Devonian-Tournaisian transgressive deposits, which are sandstone, siltstone, and shale in the lower part and carbonates with abundant reefs in the upper; thickness is 300-1,000 m. In the upper carbonate part is the Kamsko-Kinel trough system, which consists of narrow interconnected deep-water troughs. 4) The Visean-Namurian-Bashkirian cycle, which began with deposition of Visean clastics that draped over reefs of the previous cycle and filled in an erosional relief that had formed in some places on the sediments of the previous cycle. The Visean clastics are overlain by marine carbonates. Thickness of the cycle is 50-800 m. 5) Early Moscovian-Early Permian terrigenous clastic deposits and marine carbonate beds 1,000-3,000 m thick. 6) The late Early Permian-Late Permian cycle, which reflects maximum growth of the Ural Mountains and associated Ural foredeep. Evaporites were first deposited, then marine limestones and dolomites, which intertongue eastward with clastic sediments from the Ural Mountains. 7) Continental redbeds of Triassic age and mixed continental and marine elastic beds of Jurassic and Cretaceous age, which were deposited on the southern, southwestern, and northern margins of the Russian platform; they are generally absent in the Volga-Ural province, however. The Volga-Ural oil and gas basin is a single artesian system that contains seven aquifers separated by seals. The areas of greatest hydraulic head are in the eastern parts of the basin near areas where the aquifers crop out on the western slopes of the Ural Mountains. The Peri-Caspian basin is the principal drainage area of the artesian system. Approximately 600 oil and gas fields and 2,000 pools have been found in the Volga-Ural province. Nine productive sequences are recognized as follows: 1) Upper Proterozoic (Bavly beds), which are promising but not yet commercial. 2) Clastic Devonian, which contains the major reserves and includes the main pays of the super-giant Romashkino field. 3) Carbonate Upper Devonian and lowermost Carboniferous, which is one of the main reef-bearing intervals. 4) Visean (Lower Carboniferous) elastics, which are the main pays in the super-giant Arian field. 5) Carbonate Lower and Middle Carboniferous. 6) Clastic Middle Carboniferous Moscovian. 7) Carbonate Middle and Upper Carboniferous. 8) Carbonate-evaporite Lower Permian, which contains the major gas reserves and the lower part of the Melekess tar deposits. 9) Clastic-carbonate Upper Permian, which contains the major part of the Melekess tar deposits. The Volga-Ural province is divided into several productive regions on a basis of differences in structure, distribution of reservoir and source-rock facies, and general composition of the petroleum accumulations. These regions are the Tatar arch, Birsk saddle, Upper Kama depression, Perm-Bashkir arch, Ufa-Orenburg monocline, Melekess-Sernovodsko-Abdulino basin, Zhligulevsko-Orenburg arch, Ural foredeep, and north borders of the Peri-Casplan depression. Exploration activity has declined in recent years; however, interest remains high in several parts of the province, particula

Geology of the Stroudsburg quadrangle and Adjacent areas, Pennsylvania--New Jersey

USGS Publications Warehouse

Epstein, Jack Burton

1971-01-01

The Stroudsburg area is within the Valley and Ridge and Great Valley physiographic provinces, Northampton and Monroe Counties, Pennsylvania, and Warren County, New Jersey. The northeast-trending subparallel valleys and ridges resulted from erosion of folded heterogeneous sedimentary rocks. These are Middle Ordovician to Middle Devonian in age and are more than 17,000 feet thick. Deposition of a thick flysch sequence (Martinsburg Formation of Ordovician age) accompanied onset of Taconic orogenesis. It was followed by deposition of a thick molasse sequence of Silurian and Early Devonian age (continental and marginal-marine clastics--Shawangunk Formation and Bloomsburg Red Beds--overlain by predominantly marginal-marine and subtidal limestone, dolomite, shale, and sandstone--Poxono Island Formation through Oriskany Group). Basin deepening and gradual shallowing occurred during Esopus through Mahantango deposition, heralding the Acadian clastic wedge exposed north of the Stroudsburg area. Interpretation of sedimentary structures and regional stratigraphic relations suggest that the Silurian and Devonian rocks were deposited in the following environments: A1luviated coastal plain (meandering and braided streams), tidal flats (supratidal and intertidal), barrier zone, and neritic zone (upper and lower). The rock stratigraphic units have been grouped into four lithotectonic units, each having a different style of deformation. Folds produced in these rocks are disharmonic, and it is believed that each rock sequence is set off from units above and below by decollements, or zones of detachment. Movement was northwest into the Appalachian basin, primarily by gravitational sliding. The contact between the Shawangunk Formation of Silurian age and Martinsburg Formation of Ordovician age, is one zone of detachment as well as an angular unconformity. Deformational effects of the Middle to Late Ordovician Taconic orogeny are elusive, but it appears that the folds and most minor structures, including the prominent regional cleavage, were produced during the late Paleozoic Appalachian orogeny and are superimposed upon larger Taconic folds and faults. Field relations and microscopic study suggest that the regional cleavage in the Stroudsburg area is due to laminar flow of pelitic material along cleavage folia accompanied by mechanical reorientation of platy and elongate minerals and neocrystallization of mica, quartz, chlorite, and probably albite. Numerous lines of evidence point to the conclusion that cleavage developed after the rock was indurated and formed at, and Just below, conditions of low-grade metamorphism. Intensity of cleavage development increases to the southeast across the area. Second-generation slip cleavage, also believed to be Appalachian in age, formed by mechanical reorientation of minerals as well as by limited new mineral growth. The topography had a profound effect on the direction of movement of the Wisconsin glacier, as well as the manner of its retreat and the deposits that were formed. Till and stratified drift of Wisconsin age and till of Illinoian(?) age are common in the area. Wisconsin deglaciation occurred by northeastward retreat and by stagnation. A conspicuous terminal moraine marks the limit of Wisconsin ice movement. Lake Sciota was dammed between the retreating ice, the moraine, and the surrounding ridges north of Godfrey Ridge. Several deltas mark ice stand positions during the retreat of the ice. Lake-bottom and kame deposits are locally common in Cherry Valley. South of Kittatinny Mountain, on the other hand, melt water was freely discharged to the south. The wind and water gaps in the Stroudsburg area (including Delaware Water Gap and Wind Gap) are structurally controlled; specifically they are located where folds die out in short distances, where folding is locally more intense, or where resistant rocks dip steeply and have a narrow width of outcrop. This conclusion is contrary to

On the origin of a phosphate enriched interval in the Chattanooga Shale (Upper Devonian) of Tennessee-A combined sedimentologic, petrographic, and geochemical study

NASA Astrophysics Data System (ADS)

Li, Yifan; Schieber, Juergen

2015-11-01

The Devonian Chattanooga Shale contains an uppermost black shale interval with dispersed phosphate nodules. This interval extends from Tennessee to correlative strata in Kentucky, Indiana, and Ohio and represents a significant period of marine phosphate fixation during the Late Devonian of North America. It overlies black shales that lack phosphate nodules but otherwise look very similar in outcrop. The purpose of this study is to examine what sets these two shales apart and what this difference tells us about the sedimentary history of the uppermost Chattanooga Shale. In thin section, the lower black shales (PBS) show pyrite enriched laminae and compositional banding. The overlying phosphatic black shales (PhBS) are characterized by phosbioclasts, have a general banded to homogenized texture with reworked layers, and show well defined horizons of phosphate nodules that are reworked and transported. In the PhBS, up to 8000 particles of P-debris per cm2 occur in reworked beds, whereas the background black shale shows between 37-88 particles per cm2. In the PBS, the shale matrix contains between 8-16 phosphatic particles per cm2. The shale matrix in the PhBS contains 5.6% inertinite, whereas just 1% inertinite occurs in the PBS. The shale matrix in both units is characterized by flat REE patterns (shale-normalized), whereas Phosbioclast-rich layers in the PhBS show high concentrations of REEs and enrichment of MREEs. Negative Ce-anomalies are common to all samples, but are best developed in association with Phosbioclasts. Redox-sensitive elements (Co, U, Mo) are more strongly enriched in the PBS when compared to the PhBS. Trace elements associated with organic matter (Cu, Zn, Cd, Ni) show an inverse trend of enrichment. Deposited atop a sequence boundary that separates the two shale units, the PhBS unit represents a transgressive systems tract and probably was deposited in shallower water than the underlying PBS interval. The higher phosphate content in the PhBS is interpreted as the result of a combination of lower sedimentation rates with reworking/winnowing episodes. Three types of phosphatic beds that reflect different degrees of reworking intensity are observed. Strong negative Ce anomalies and abundant secondary marcasite formation in the PhBS suggests improved aeration of the water column, and improved downward diffusion of oxygen into the sediment. The associated oxidation of previously formed pyrite resulted in a lowering of pore water pH and forced dissolution of biogenic phosphate. Phosphate dissolution was followed by formation of secondary marcasite and phosphate. Repeated, episodic reworking caused repetitive cycles of phosphatic dissolution and reprecipitation, enriching MREEs in reprecipitated apatite. A generally "deeper" seated redox boundary favored P-remineralization within the sediment matrix, and multiple repeats of this process in combination with wave and current reworking at the seabed led to the formation of larger phosphatic aggregates and concentration of phosphate nodules in discrete horizons.

Sedimentary records on the subduction-accretion history of the Russian Altai, northwestern Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Chen, Ming; Sun, Min

2017-04-01

The Russian Altai, comprising the northern segment of the Altai-Mongolian terrane (AM) in the south, the Gorny Altai terrane (GA) in the north and the intervening Charysh-Terekta-Ulagan-Sayan suture zone, is a key area of the northwestern Central Asian Orogenic Belt (CAOB). A combined geochemical and detrital zircon study was conducted on the (meta-)sedimentary sequences from the Russian Altai to reveal the tectono-magmatic history of these two terranes and their amalgamation history, which in turn place constraints on the accretionary orogenesis and crustal growth in the CAOB. The Cambrian-Ordovician meta-sedimentary rocks from the northern AM are dominated by immature sediments possibly sourced from intermediate-felsic igneous rocks. Geochemical data show that the sediments were likely deposited in a continental arc-related setting. Zircons separated from these rocks are mainly 566-475 Ma and 1015-600 Ma old, comparable to the magmatic records of the Tuva-Mongolian terrane and surrounding island arcs in the western Mongolia. The similar source nature, provenance and depositional setting of these rocks to the counterparts from the Chinese Altai (i.e., the southern AM) imply that the whole AM possibly represents a coherent accretionary prism of the western Mongolia in the early Paleozoic rather than a Precambrian continental block with passive marginal deposition as previously thought. In contrast, the Cambrian to Silurian (meta-)sedimentary rocks from the GA are characterized by a unitary zircon population with ages of 640-470 Ma, which were potentially sourced from the Kuznetsk-Altai intra-oceanic island arc in the east of this terrane. The low abundance of 640-540 Ma zircons (5%) may attest that this arc was under a primitive stage in the late Neoproterozoic, when mafic igneous rocks dominated. However, the voluminous 530-470 Ma zircons (95%) suggest that this arc possibly evolved toward a mature one in the Cambrian to early Ordovician with increasing amount of intermediate-felsic igneous rocks, highlighting both crustal growth and recycling. Importantly, a significant amount of additional 2431-772 Ma zircons occur in the early Devonian sedimentary sequence of the GA. These detrital zircons possibly have the same source as their counterpart from the AM. This implies that the two terranes with countrary evolutionary history, i.e. the GA and AM, amalgamated before the early Devonian. To summary, the AM and GA represented two separated subduction-accretion systems in the early Paleozoic and subsequently amalgamated prior to the early Devonian, documenting complicated accretionary orogenesis and significant lateral crustal growth in the CAOB. Acknowledgement This study is financially supported by the Major Research Project of the Ministry of Science and Technology of China (2014CB44801 and 2014CB448000), Hong Kong Research Grant Council (HKU705313P and HKU17303415), National Science Foundation of China (41273048) and the Fundamental Research Funds for the Central Universities, China University of Geosciences (Wuhan) (162301132731).

Structure of the Red Dog District, western Brooks Range, Alaska

USGS Publications Warehouse

de Vera, Jean-Pierre P.; McClay, K. R.

2004-01-01

The Red Dog district of the western Brooks Range of northern Alaska, which includes the sediment-hosted Zn-Pb-Ag ± Ba deposits at Red Dog, Su-Lik, and Anarraaq, contains one of the world's largest reserves of zinc. This paper presents a new model for the structural development of the area and shows that understanding the structure is crucial for future exploration efforts and new mineral discoveries in the district. In the Red Dog district, a telescoped Late Devonian through Jurassic continental passive margin is exposed in a series of subhorizontally stacked, internally imbricated, and regionally folded thrust sheets. These sheets were emplaced during the Middle Jurassic to Late Cretaceous Brookian orogeny and subsequently were uplifted by late tectonic activity in the Tertiary. The thrust sheet stack comprises seven tectonostratigraphically distinct allochthonous sheets, three of which have been subject to regional and detailed structural analysis. The lowermost of these is the Endicott Mountains allochthon, which is overlain by the structurally higher Picnic Creek and Kelly River allochthons. Each individual allochthon is itself internally imbricated into a series of tectonostratigraphically coherent and distinct thrust plates and subplates. This structural style gives rise to duplex development and imbrication at a range of scales, from a few meters to tens of kilometers. The variable mechanical properties of the lithologic units of the ancient passive margin resulted in changes in structural styles and scales of structures across allochthon boundaries. Structural mapping and analysis of the district indicate a dominant northwest to west-northwest direction of regional tectonic transport. Local north to north-northeast transport of thrust sheets is interpreted to reflect the influence of underlying lateral and/or oblique ramps, which may have been controlled by inherited basin margin structures. Some thrust-sheet stacking patterns suggest out-of-sequence thrusting. The west-northwest-east-southeast-trending Wrench Creek and Sivukat Mountain faults were previously interpreted to be strike-slip faults, but this study shows that they are Tertiary (Eocene?) late extensional faults with little or no lateral displacement.

Geochemistry and metamorphism of the Paleozoic metasedimentary basement of the Sierra Madre Oriental, NE Mexico. Possible paths from their depositional environment?

NASA Astrophysics Data System (ADS)

Torres Sanchez, Sonia Alejandra; Augustsson, Carita; Alonso Ramirez Fernandez, Juan; Rafael Barboza Gudiño, Jose; Jenchen, Uwe; Abratis, Michael

2013-04-01

We present depositional conditions and possible protholits for Late Paleozoic metasediment in Mexico that were related to the Laurentia-Gondwana collision in Carboniferous time, during Pangea amalgamation. The study aims to reconstruct the depositional and metamorphic evolution of the Granjeno Schist in northeastern Mexico to get a better control on the timing of subduction and collision processes involving the two supercontinents. Remnants of the Mexican Paleozoic continental configuration are present in the Granjeno Schist, the metamorphic basement of the Sierra Madre Oriental in northeastern Mexico. We apply field mapping, petrographic investigations, whole-rock and mineral chemical analysis, as well as U-Pb zircon dating of both metasedimentary and metavolcanic rocks. Field work and petrographic analysis reveal that the Granjeno Schist comprises intercalations of metamorphic rocks with both sedimentary (psammite, pelite, turbidite, conglomerate, black shale) and volcanic (tuff, lava flows, pillow lava and ultramafic bodies) protoliths. The chlorite geothermometer and the presence of phengite in the metasedimentary units as well as U-Pb zircon ages on metapsammite indicate that the Granjeno Schist was metamorphosed under sub-greenschist to greenschist facies with temperatures ranging from 250-345°C during the Carboniferous time (330±30 Ma). The geochemical composition of the metasedimentary rocks is in accordance with iron shale, wacke and quartz arenite protoliths. Some of the variations can be explained by the grain sizes (e. g., 69-74% and 78-96% SiO2 and 10-15% and 3-9% Al2O3 in metapelite and metapsammite, respectively). Our data suggest that the Granjeno Schist metasedimentary units represent a wide variety of clastic sediments derived from mixed felsic basic sources compositions (e. g., Ti/Nb 200-400). Furthermore, the trace element characteristics point to a continental island arc or active continental margin setting due to e. g., Th/Sc and Zr/Sc ratios of 5-8 and 0.3-0.5, respectively, both for metapelite and metapsammite. The metavolcanic rocks are associated with ocean-island basalt (OIB) or mid-ocean ridge basalts (MORB) due to the immobile trace element ratios Zr/Nb and Y/Nb in the ranges 4.91-8.06 and 0.74-1 for the IOB and >9.2 and >1.25 for the MORB, respectively. Detrital zircon ages for three metapsammites reveal that the major sources mainly are Grenvillian (1250-920 Ma) rocks. Such rocks can be found in the ca. 1 Ga Oaxaquia Complex in NE Mexico (Novillo Gneiss). Hence, short transport can be assumed. Maximum depositional ages are Neoproterozoic, Silurian and Devonian. They indicate that the volcanosedimentary deposition probably took place during Devonian time. Based on our results we suggest a plate-tectonic frame for Oaxaquia which is a modification of accepted models. Most models suggest that Oaxaquia was situated between Laurentia and Gondwana during collision in Carboniferous time. The zircon data indicate that the Granjeno Schist was deposited before the collision of Laurentia and Gondwana. The presence of ocean basalt floor, lava flows and serpentinite lenses intercalated with tuff and active continental margin sedimentary rocks necessitates a near-continental environment, such as a back-arc basin. Hence, we present the first evidence of a subduction zone predating the collision of Laurentia and Gondwana.

Assessment of Factors Influencing Effective CO 2 Storage Capacity and Injectivity in Eastern Gas Shales

DOE Office of Scientific and Technical Information (OSTI.GOV)

Godec, Michael

Building upon advances in technology, production of natural gas from organic-rich shales is rapidly developing as a major hydrocarbon supply option in North America and around the world. The same technology advances that have facilitated this revolution - dense well spacing, horizontal drilling, and hydraulic fracturing - may help to facilitate enhanced gas recovery (EGR) and carbon dioxide (CO 2) storage in these formations. The potential storage of CO 2 in shales is attracting increasing interest, especially in Appalachian Basin states that have extensive shale deposits, but limited CO 2 storage capacity in conventional reservoirs. The goal of this cooperativemore » research project was to build upon previous and on-going work to assess key factors that could influence effective EGR, CO 2 storage capacity, and injectivity in selected Eastern gas shales, including the Devonian Marcellus Shale, the Devonian Ohio Shale, the Ordovician Utica and Point Pleasant shale and equivalent formations, and the late Devonian-age Antrim Shale. The project had the following objectives: (1) Analyze and synthesize geologic information and reservoir data through collaboration with selected State geological surveys, universities, and oil and gas operators; (2) improve reservoir models to perform reservoir simulations to better understand the shale characteristics that impact EGR, storage capacity and CO 2 injectivity in the targeted shales; (3) Analyze results of a targeted, highly monitored, small-scale CO 2 injection test and incorporate into ongoing characterization and simulation work; (4) Test and model a smart particle early warning concept that can potentially be used to inject water with uniquely labeled particles before the start of CO 2 injection; (5) Identify and evaluate potential constraints to economic CO 2 storage in gas shales, and propose development approaches that overcome these constraints; and (6) Complete new basin-level characterizations for the CO 2 storage capacity and injectivity potential of the targeted eastern shales. In total, these Eastern gas shales cover an area of over 116 million acres, may contain an estimated 6,000 trillion cubic feet (Tcf) of gas in place, and have a maximum theoretical storage capacity of over 600 million metric tons. Not all of this gas in-place will be recoverable, and economics will further limit how much will be economic to produce using EGR techniques with CO 2 injection. Reservoir models were developed and simulations were conducted to characterize the potential for both CO 2 storage and EGR for the target gas shale formations. Based on that, engineering costing and cash flow analyses were used to estimate economic potential based on future natural gas prices and possible financial incentives. The objective was to assume that EGR and CO 2 storage activities would commence consistent with the historical development practices. Alternative CO 2 injection/EGR scenarios were considered and compared to well production without CO 2 injection. These simulations were conducted for specific, defined model areas in each shale gas play. The resulting outputs were estimated recovery per typical well (per 80 acres), and the estimated CO 2 that would be injected and remain in the reservoir (i.e., not produced), and thus ultimately assumed to be stored. The application of this approach aggregated to the entire area of the four shale gas plays concluded that they contain nearly 1,300 Tcf of both primary production and EGR potential, of which an estimated 460 Tcf could be economic to produce with reasonable gas prices and/or modest incentives. This could facilitate the storage of nearly 50 Gt of CO 2 in the Marcellus, Utica, Antrim, and Devonian Ohio shales.« less

Ocean acidification and the δ15N record of Paleozoic epeiric seas

NASA Astrophysics Data System (ADS)

Tuite, M. L., Jr.; Williford, K. H.

2017-12-01

In addition to its role as a primary driver of global climate, atmospheric CO2 influences the pH of seawater which is an important factor in mediating biogeochemical cycles. Variations in the pH of seawater on geological timescales have been correlated with broad impacts on marine ecosystems and biogeochemical processes including evolutionary turnover and mass extinction. Atmospheric CO2 declined dramatically during the mid-Paleozoic, coincident with the emergence of terrestrial forests and concomitant development of a substantial soil carbon reservoir and increased silicate weathering. Global greenhouse conditions that prevailed at the Late Devonian Frasnian/Famennian boundary gave way to temperate latitude glaciation at the end of the Famennian. In a recent review of icehouse-greenhouse variations in marine nitrogen biogeochemistry through the Phanerozoic (Algeo et al. 2014), the authors observed a strong correlation between sediment δ15N and first order climate cycles with a trend toward lower values during greenhouse periods and higher values during icehouse periods. Based upon modeling results, the shift in sediment δ15N was ascribed to a change in the locus of denitrification from sediments in warm climates to the water column during cooler periods driven primarily by eustatic sea level change as glacial ice mass waxed and waned. Sediment δ15N is a useful proxy for interpreting N biogeochemistry in marine systems because it provides an integrated record of the microbially-mediated redox reactions that led to that δ15N value. We propose that the elevated CO2 that drove the greenhouse climate in the early Famennian also resulted in the acidification of seawater that precluded nitrification, yielding an ammonium-dominated surface ocean and low sediment δ15N. As O2 climbed and seawater pH responded to diminished CO2, we propose that nitrification rates increased resulting in a nitrate-dominated system and sediment δ15N values that approach modern values. In support of our argument, we present stable isotope, redox, and compositional data from a core that spans the transition from the high CO2 greenhouse climate near the F/F boundary to the lower CO2 climate in the latest Devonian.

REE enrichment due to fenitization of Devonian granites, Rodeo de Los Molles, Central Argentina

NASA Astrophysics Data System (ADS)

Lorenz, M.; Altenberger, U.; Trumbull, R. B.; Lira, R.; Lopez De Luchi, M. G.; Viñas, N.

2017-12-01

The Rodeo de Los Molles rare earth element (REE) mineralization is characterized by an uncommon REE-bearing assemblage located within a fenitized biotite-monzogranite. The fenitization is found in a NNE-SSW trending, possibly fault related elliptical body in the northern margin of the Devonian Las Chacras-Piedras Coloradas Batholith, San Luis province, Central Argentina. The fenite was produced by the metasomatic addition of K and Na, as well as the loss of Ca and Sr, leading to the transformation of monzogranite to (quartz) alkali-feldspar syenite composition. Whole-rock geochemistry revealed a local enrichment in light rare earth elements within the fenitized zone. Drill-core samples from a mineral exploration campaign (Lira et al., 1999) and new surface samples are the basis for the present investigation, which aims to decipher the fluid evolution and REE-mineralization. REE-bearing minerals are located in irregularly patches and nodules ranging from a few millimeters to more than one meter in diameter. The REE-rich assemblage comprises an intergrowth of primary britholite (Ce,Ca)5(SiO4, PO4)3(OH,F), allanite and apatite with aegirine-augite, titanite, fluorite, bastnaesite and, quartz as well as complex thorium-rich accessory minerals. In more intensely altered areas clinochlore, spherolitic quartz, calcite, kaolinite, hematite and phlogopite also occur. Britholite is an extraordinary mineral belonging to the apatite group, usually described as an accessory mineral. Aside from being one of only three localites in the world where it occurs in ore quantities, Rodeo de Los Molles further contains atypical huge aggregates of the rare mineral. In general, britholite is thought to form by late-magmatic crystallization or alteration of primary minerals in alkali-rich granites (Uher et al., 2015). Its origin as an abundant phase in the Rodeo de Los Molles mineralization is one focus of this study. Lira, R., Barbieri, M., Ripley, E.M., Viñas, N.A. (1999) Actas II South American Symposium on Isotope Geology, p.219-222. Uher, P., Ondrejka, M., Bačík, P., Broska, I., & Konečný, P. (2015) Lithos, 236, p.212-225.

Low-Temperature Thermochronology Investigation in Uruguay and Southernmost Brazil: Apatite (U-Th)/He Results

NASA Astrophysics Data System (ADS)

Machado, J. P.; Bicca, M. M.

2017-12-01

Low-temperature thermochronology has successfully allowed one to reveal exhumation histories of many orogenic belts across the Earth, and lately these techniques have been applied in cratonic regions. The present study aims to constrain thermal history and exhumation of the South Atlantic Passive Margin, between Uruguay and Southernmost Brazil, a region scarce of thermochronological data. This location has become relatively stable after the Neoproterozoic Brasiliano Orogeny, being more intensely disturbed by tectonics during the Gondwana Breakup and consequent opening of the Atlantic Ocean (Jurassic - Cretaceous). Both apatite and zircon (U-Th)/He methods are being applied on basement rocks, and since those have a long cooling history, radiation damage is expected to play an important role in crystal ages. A total of 25 samples were analyzed, and preliminary apatite (U-Th)/He results reveals unweighted sample ages ranging from Permian to Lower-Cretaceous in Southernmost Brazil, with a couple of outliers with Devonian - Carboniferous ages. In Uruguay results can be grouped in two different clusters: one of samples with Jurassic to Lower-Cretaceous ages, and another of Devonian to Permian ages. This wide range of results can be assign to variations in the uranium content of the grains, due the presence of inclusions, compositional zonation or substantial radiation damage of the crystalline lattice. In most cases, ages tend to increase with crystal eU content. No clear relationship between ages and tectonic terranes has been found so far, neither between ages and elevation, since the region does not have significant topographic variations. Younger ages are commonly found closer to the coastal region, possibly in response to the rift shoulders uplift during Gondwana breakup and further exhumation and denudation at higher rates. An anomalous concentration of older ages in the southern region of the Pelotas Batholith, close to the Brazil - Uruguay border, suggests a geotectonic stable area near the margin. A NW-trend of younger ages throughout southernmost Brazilian Shield may reflect cooling triggered by the structural reactivation of Precambrian basement fabrics. Hopefully, future work will permit a better comprehension of the regional exhumation patterns during the Phanerozoic.

Breathing air in air: in what ways might extant amphibious fish biology relate to prevailing concepts about early tetrapods, the evolution of vertebrate air breathing, and the vertebrate land transition?

PubMed

Graham, Jeffrey B; Lee, Heather J

2004-01-01

The air-breathing fishes have heuristic importance as possible models for the Paleozoic evolution of vertebrate air breathing and the transition to land. A recent hypothesis about this transition suggests that the diverse assemblage of marine amphibious fishes occurring primarily in tropical, high intertidal zone habitats are analogs of early tetrapods and that the intertidal zone, not tropical freshwater lowlands, was the springboard habitat for the Devonian land transition by vertebrates. Here we argue that selection pressures imposed by life in the intertidal zone are insufficient to have resulted in the requisite aerial respiratory capacity or the degree of separation from water required for the vertebrate land transition. The extant marine amphibious fishes, which occur mainly on rocky shores or mudflats, have reached the limit of their niche expansion onto land and remain tied to water by respiratory structures that are less efficient in air and more vulnerable to desiccation than lungs. We further argue that evolutionary contingencies actuated by the Devonian origin of the tetrapods marked a critical point of divergence for a way of life in which selection pressures would operate on the physiology, morphology, and natural history of the different vertebrate groups. While chronically hypoxic and shallow water conditions in the habitats of some primitive bony fishes and some amphibians appear similar to the conditions that prevailed in the Devonian, markedly different selection pressures have operated on other amphibians and bony fishes over the 300 million years since the vertebrate land transition. For example, both egg development and larval metamorphosis in extant amphibians are geared mainly toward compensating for the uncertainty of habitat water quality or even the absence of water by minimizing the time required to develop there. In contrast, reproduction by most intertidal (and amphibious) fishes, all of which are teleosts, remains dependent on a planktonic larval phase and is characterized by specializations (brooding) that minimize overdispersal and maximize recruitment back to the littoral habitat.

An organismal concept for Sengelia radicans gen. et sp. nov. – morphology and natural history of an Early Devonian lycophyte

PubMed Central

Tomescu, Alexandru M. F.

2017-01-01

Abstract Background and Aims Fossil plants are found as fragmentary remains and understanding them as natural species requires assembly of whole-organism concepts that integrate different plant parts. Such concepts are essential for incorporating fossils in hypotheses of plant evolution and phylogeny. Plants of the Early Devonian are crucial to reconstructing the initial radiation of tracheophytes, yet few are understood as whole organisms. Methods This study assembles a whole-plant concept for the Early Devonian lycophyte Sengelia radicans gen. et sp. nov., based on morphometric data and taphonomic observations from >1000 specimens collected in the Beartooth Butte Formation (Wyoming, USA). Key Results Sengelia radicans occupies a key position between stem-group and derived lycophyte lineages. Sengelia had a rooting system of downward-growing root-bearing stems, formed dense monotypic mats of prostrate shoots in areas that experienced periodic flooding, and was characterized by a life-history strategy adapted for survival after floods, dominated by clonality, and featuring infrequent sexual reproduction. Conclusions Sengelia radicans is the oldest among the very few early tracheophytes for which a detailed, rigorous whole-plant concept integrates morphology, growth habit, life history and growth environment. This plant adds to the diversity of body plans documented among lycophytes and may help elucidate patterns of morphological evolution in the clade. PMID:28334100

Geochemical and strontium isotope characterization of produced waters from Marcellus Shale natural gas extraction.

PubMed

Chapman, Elizabeth C; Capo, Rosemary C; Stewart, Brian W; Kirby, Carl S; Hammack, Richard W; Schroeder, Karl T; Edenborn, Harry M

2012-03-20

Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ~375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (ε(Sr)(SW) = +13.8 to +41.6, where ε(Sr) (SW) is the deviation of the (87)Sr/(86)Sr ratio from that of seawater in parts per 10(4)); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.

The Geochemistry of Mass Extinction

NASA Astrophysics Data System (ADS)

Kump, L. R.

2003-12-01

The course of biological evolution is inextricably linked to that of the environment through an intricate network of feedbacks that span all scales of space and time. Disruptions to the environment have biological consequences, and vice versa. Fossils provide the prima facie evidence for biotic disruptions: catastrophic losses of global biodiversity at various times in the Phanerozoic. However, the forensic evidence for the causes and environmental consequences of these mass extinctions resides primarily in the geochemical composition of sedimentary rocks deposited during the extinction intervals. Thus, advancement in our understanding of mass extinctions requires detailed knowledge obtained from both paleontological and geochemical records.This chapter reviews the state of knowledge concerning the geochemistry of the "big five" extinctions of the Phanerozoic (e.g., Sepkoski, 1993): the Late Ordovician (Hirnantian; 440 Ma), the Late Devonian (an extended or multiple event with its apex at the Frasnian-Famennian (F-F) boundary; 367 Ma), the Permian-Triassic (P-Tr; 251 Ma), the Triassic-Jurassic (Tr-J; 200 Ma), and the Cretaceous-Tertiary (K-T; 65 Ma). The focus on the big five is a matter of convenience, as there is a continuum in extinction rates from "background" to "mass extinction." Although much of the literature on extinctions centers on the causes and extents of biodiversity loss, in recent years paleontologists have begun to focus on recoveries (see, e.g., Hart, 1996; Kirchner and Weil, 2000; Erwin, 2001 and references therein).To the extent that the duration of the recovery interval may reflect a slow relaxation of the environment from perturbation, analysis of the geochemical record of recovery is an integral part of this effort. In interpreting the geochemical and biological records of recovery, we need to maintain a clear distinction among the characteristics of the global biota: their biodiversity (affected by differences in origination and extinction rates) and ecosystem function (guild structure, complexity of interactions, productivity). Geochemical records reflect attributes of ecosystem function, not biodiversity; low-diversity recovery faunas and floras may support pre-event productivities. Thus, geochemical and biodiversity recovery intervals are interdependent but not equivalent, and may not be of equal duration.From the biological point of view, there is an inevitable lag between peak extinction rates and peak origination rates, and the durations and underlying causes of the lags are topics of debate. Both intrinsic (e.g., the fact that ecospace is created as biodiversity increases producing positive feedback) and external (environmental) constraints are possible. Kirchner and Weil (2000) performed a time-series analysis of extinction and origination-rate data, and concluded that the lag is ˜10 Myr and independent of the magnitude of the event. Erwin (2001) raised the possibility that the 10 Myr lag may be an artifact of the coarseness of the timescales utilized, and discussed possible environmental and ecological limits on rate of recovery from mass extinction.The comparison of the geochemical records of the five major mass extinctions of the Phanerozoic reveals few commonalities. Most, but not all, exhibit sharp drops in the carbon isotopic composition (δ13C) of the surface ocean, indicating substantial disruptions to the global carbon cycle. The P-Tr and F-F events are associated with indicators of widespread anoxia and enhanced pyrite burial (positive δ34S excursions), whereas the Late Ordovician extinction occurred during a brief interlude of oxic conditions from general anoxia. Some are associated with sea-level transgressions from previous lowstands (P-Tr, Tr-J, K-T), but the Late Ordovician and F-F occurred during sea-level falls. Long-term climates change across all events, but span major coolings (Late Ordovician, F-F) to prominent warmings (P-Tr, Tr-J, K-T).Evidence for extraterrestrial influence is strong for the K-T, suggestive for the Tr-J and Late Permian, and missing for the F-F and Late Ordovician. What these times have in common is that all were times of biotic and environmental change. Long-term trends toward extreme environmental conditions presaged the Late Ordovician, F-F, and P-Tr events, whereas the Tr-J and K-T seem to have been abrupt shocks to the Earth system, perhaps belying their extraterrestrial cause. However, even for the K-T extinction there is indication of environmental and biotic change before the known impact event and mass extinction (e.g., Keller et al., 1993; Barrera, 1994; Abramovich and Keller, 2002).

Thermal Transgressions and Phanerozoic Extinctions

NASA Astrophysics Data System (ADS)

Worsley, T. R.; Kidder, D. L.

2007-12-01

A number of significant Phanerozoic extinctions are associated with marine transgressions that were probably driven by rapid ocean warming. The conditions associated with what we call thermal transgressions are extremely stressful to life on Earth. The Earth system setting associated with end-Permian extinction exemplifies an end-member case of our model. The conditions favoring extreme warmth and sea-level increases driven by thermal expansion are also conducive to changes in ocean circulation that foster widespread anoxia and sulfidic subsurface ocean waters. Equable climates are characterized by reduced wind shear and weak surface ocean circulation. Late Permian and Early Triassic thermohaline circulation differs considerably from today's world, with minimal polar sinking and intensified mid-latitude sinking that delivers sulfate from shallow evaporative areas to deeper water where it is reduced to sulfide. Reduced nutrient input to oceans from land at many of the extinction intervals results from diminished silicate weathering and weakened delivery of iron via eolian dust. The falloff in iron-bearing dust leads to minimal nitrate production, weakening food webs and rendering faunas and floras more susceptible to extinction when stressed. Factors such as heat, anoxia, ocean acidification, hypercapnia, and hydrogen sulfide poisoning would significantly affect these biotas. Intervals of tectonic quiescence set up preconditions favoring extinctions. Reductions in chemical silicate weathering lead to carbon dioxide buildup, oxygen drawdown, nutrient depletion, wind and ocean current abatement, long-term global warming, and ocean acidification. The effects of extinction triggers such as large igneous provinces, bolide impacts, and episodes of sudden methane release are more potent against the backdrop of our proposed preconditions. Extinctions that have characteristics we call for in the thermal transgressions include the Early Cambrian Sinsk event, as well as extinction events at the Frasnian-Famennian, end-Devonian, end Permian, Early Toarcian, Cenomanian-Turonian, and end Cretaceous. The Late Paleocene and end Triassic extinctions are still under evaluation. The extinctions associated with the glacio-eustatic sea-level change in the Late Ordovician are not consistent with the conditions of our model.

Geologic Map of the Big Delta B-1 Quadrangle, East-Central Alaska

USGS Publications Warehouse

Day, Warren C.; O'Neill, J. Michael; Aleinikoff, John N.; Green, Gregory N.; Saltus, Richard W.; Gough, Larry P.

2007-01-01

Geologic mapping and U-Pb age dating of rocks from the Big Delta B-1 quadrangle, east-central Alaska, have yielded new insights into the geology and gold mineral resource for the headwater region of the Goodpaster River, northeast of Delta, Alaska. The area lies within the Yukon-Tanana Upland and is underlain by Paleozoic and Cretaceous crystalline bedrock and contains several gold mines and prospects. The Paleozoic units include biotite gneiss, quartzite interlayered with metapelite, and amphibolite gneiss. The Paleozoic units were intruded during the Devonian by tonalitic to granitic plutons, which, as a result of regional Mesozoic metamorphism and tectonism, are now augen gneiss and biotite orthogneiss. The Mesozoic regional metamorphism and ductile deformation of the entire Yukon-Tanana Upland culminated by the Late Cretaceous (about 116 Ma) as a result of northwest-directed regional transpression along the southern margin of the North American craton. This dynamothermal episode was followed by invasion of syn- to post-tectonic granodioritic to granitic batholiths during the Late Cretaceous (about 113-107 Ma), followed by a pulse of 100-95 Ma quartz feldspar porphyry intrusions. Gold mineralization is spatially associated with various post-tectonic Late Cretaceous granitic dikes and batholiths throughout the quadrangle. A northeast-trending structural corridor, described herein as the Black Mountain tectonic zone, both controlled the emplacement of some of the Cretaceous intrusive rocks, gold deposits, and prospects, as well as formed a deep-seated crustal conduit along which a subsequent rhyolite flow-dome complex erupted during the Paleocene. Tertiary uplift and erosion resulted in the development of extensive erosional pediments. Quaternary alpine glaciation carved beautiful, broad valleys in the eastern part of the quadrangle, leaving behind terminal moraines in the headwater region of the Goodpaster river drainage. Continued Holocene to Recent deformation along the Black Mountain tectonic zone has offset Tertiary terraces, as well as Quaternary fluvial and alluvial deposits, indicating that the area has a long, complex, and ongoing tectonic history.

History of displacement along Ste. Genevieve Fault Zone, Southwestern Illinois

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schwalb, H.R.

1983-09-01

The Ste. Genevieve fault zone extends eastward from Missouri across the Mississippi River into Jackson County, Illinois, about 75 mi (120 km) southeast of St. Louis. Outcrop studies have dated movement along portions of the zone as pre-Middle Devonian, post-Mississippian, and post-Pennsylvanian. Present displacement is down to the north and east with throw ranging up to 3,000 ft (915 m). However, pre-Middle Devonian movement was down to the south and west. The present upthrown block shows no evidence of vertical movement during the Cambrian and Ordovician. Nor is there any indication that the fault zone was part of the northernmore » border of the Reelfoot basin, where earliest Paleozoic sediments infilled an aulacogen at the northern end of the Mississippi embayment.« less

Lunar and Planetary Science XXXV: Impact-Related Deposits

NASA Technical Reports Server (NTRS)

2004-01-01

The session "Impact-Related Deposits" included:Evidence for a Lightning-Strike Origin of the Edeowie Glass; 57Fe M ssbauer Spectroscopy of Fulgurites: Implications for Chemical Reduction; Ca-Metasomatism in Crystalline Target Rocks from the Charlevoix Structure, Quebec, Canada: Evidence for Impact-related Hydrothermal Activity; Magnetic Investigations of Breccia Veins and Basement Rocks from Roter Kamm Crater and Surrounding Region, Namibia; Petrologic Complexities of the Manicouagan Melt Sheet: Implications for 40Ar-39Ar Geochronology; Laser Argon Dating of Melt Breccias from the Siljan Impact Structure, Sweden: Implications for Possible Relationship to Late Devonian Extinction Events; Lunar Impact Crater, India: Occurrence of a Basaltic Suevite?; Age of the Lunar Impact Crater, India: First Results from Fission Track Dating; The Fluidized Chicxulub Ejecta Blanket, Mexico: Implications for Mars; Low Velocity Ejection of Boulders from Small Lunar Craters: Ground Truth for Asteroid Surfaces; Ejecta and Secondary Crater Distributions of Tycho Crater: Effects of an Oblique Impact; Potassium Isotope Systematics of Crystalline Lunar Spherules from Apollo 16; Late Paleocene Spherules from the North Sea: Probable Sea Floor Precipitates: A Silverpit Provenance Unproven; A Lithological Investigation of Marine Strata from the Triassic-Jurassic Boundary Interval, Queen Charlotte Islands, British Columbia, Including a Search for Shocked Quartz; Triassic Cratered Cobbles: Shock Effects or Tectonic Pressure?; Regional Variations of Trace Element Composition Within the Australasian Tektite Strewn Field; Cretaceous-Tertiary Boundary Microtektite-bearing Sands and Tsunami Beds, Alabama Gulf Coastal Plain; Sand Lobes on Stewart Island as Probable Impact-Tsunami Deposits; Distal Impact Ejecta, Uppermost Eocene, Texas Coastal Plain; and Continental Impact Debris in the Eltanin Impact Layer.

Some contrasting biostratigraphic links between the Baker and Olds Ferry Terranes, eastern Oregon

USGS Publications Warehouse

Nestell, Merlynd K.; Blome, Charles D.

2016-01-01

New stratigraphic and paleontologic data indicate that ophiolitic melange windows in the Olds Ferry terrane of eastern Oregon contain limestone blocks and chert that are somewhat different in age than those present in the adjacent Baker terrane melange. The melange windows in the Olds Ferry terrane occur as inliers in the flyschoid Early and Middle Jurassic age Weatherby Formation, which depositionally overlies the contact between the melange-rich Devonian to Upper Triassic rocks of the Baker terrane on the north, and Upper Triassic and Early Jurassic volcanic arc rocks of the Huntington Formation on the south. The Baker terrane and Huntington Formation represent fragments of a subduction complex and related volcanic island arc, whereas the Weatherby Formation consists of forearc basin sedimentary deposits. The tectonic blocks in the melange windows of the Weatherby Formation (in the Olds Ferry terrane) are dated by scarce biostratigraphic evidence as Upper Pennsylvanian to Lower Permian and Upper Triassic. In contrast, tectonic blocks of limestone in theBaker terrane yield mostly fusulinids and small foraminifers of Middle Pennsylvanian Moscovian age at one locality.Middle Permian (Guadalupian) Tethyan fusulinids and smaller foraminifers (neoschwagerinids and other Middle Permian genera) are present at a few other localities. Late Triassic conodonts and bryozoans are also present in a few of the Baker terrane tectonic blocks. These limestone blocks are generally embedded in Permian and Triassic radiolarian bearing chert or argillite. Based on conodont, radiolarian and fusulinid data, the age limits of the meange blocks in the Weatherby Formation range from Pennsylvanian to Late Triassic.

Minimum age of the Neoproterozoic Seven Hundred Acre Island Formation and the tectonic setting of the Islesboro Formation, Islesboro block, Maine

USGS Publications Warehouse

Stewart, D.B.; Tucker, R.D.; Ayuso, R.A.; Lux, D.R.

2001-01-01

Two platformal stratigraphic sequences occur on Islesboro, Penobscot Bay, Maine. The older Seven Hundred Acre Island Formation is at least 200 m thick, its base is not exposed, and it makes up fault-bounded blocks of siliceous colour-banded dolomitic marble, muscovite-rich quartzite, coarse-grained splendent muscovite-garnet-staurolite-andalusite schist, and calcareous metapelite, with minor garnet amphibolite and amphibolite. It was initially metamorphosed to lower amphibolite facies and was later to lower greenschist facies. The lower amphibolite facies metamorphism is Neoproterozoic (670 to 650 Ma) as inferred from the 40Ar/39Ar high temperature release spectra of hornblende separates. A U-Pb zircon age of 646.7 ?? 2.7 Ma obtained for a pegmatite that intruded deformed rocks is taken to be the minimum age of the Formation. The platformal Islesboro Formation probably unconformably overlies the Seven Hundred Acre Island Formation. It is primarily turbiditic pelite with many beds of quartzite, impure dolomitic marble, some conglomerate, and a few feldsparrich volcaniclastic beds and is thought to be either Neoproterozoic or Cambrian. It was metamorphosed only to lower greenschist facies, possibly in the same event that retrograded the Seven Hundred Acre Island Formation. Geochemical interpretations of minor and trace element analyses of six amphibolite and four schist samples from the Seven Hundred Acre Island Formation show that the protoliths of the amphibolite samples were intermediate between tholeiitic and within-plate type basaltic flows or dikes that intruded attenuated continental crust, or were eroded from these basalts. Four amphibolite and three schist samples analyzed for Pb isotopes were found to be enriched in radiogenic Pb. The Pb isotopic compositions are similar to those in peri-Gondwanan basement rocks from Atlantic Canada. The peri-Gondwanan Islesboro block was placed against the peri-Gondwanan Middle and Late Cambrian Ellsworth terrane on the east by significant Late Silurian strike-slip faulting. The Late Silurian or Early Devonian Turtle Head dextral strike-slip fault separates the Islesboro block from the peri-Gondwanan St. Croix terrane to the west. The timing and nature of the movements of these faults are given from offsets of the isograds around the zircon-dated Late Silurian Sedgwick Granite (419.5 ?? 1.4 Ma) and South Penobscot Intrusive Suite (419.2 ?? 2.2 Ma). These terranes and others like them in Atlantic Canada make up a composite terrane that is different from the composite Avalonian terranes sensu stricto of southeastern New England and Atlantic Canada. The composite peri-Gondwanan terrane that included the Islesboro block was amalgamated with the margin of ancestral North America in the Silurian.

Petrology and diagenetic history of the upper shale member of the Late Devonian-Early Mississippian Bakken Formation, Williston Basin, North Dakota

USGS Publications Warehouse

Neil S. Fishman,; Sven O. Egenhoff,; Boehlke, Adam; Lowers, Heather A.

2015-01-01

The organic-rich upper shale member of the upper Devonian–lower Mississippian Bakken Formation (Williston Basin, North Dakota, USA) has undergone significant diagenetic alteration, irrespective of catagenesis related to hydrocarbon generation. Alteration includes precipitation of numerous cements, replacement of both detrital and authigenic minerals, multiple episodes of fracturing, and compaction. Quartz authigenesis occurred throughout much of the member, and is represented by multiple generations of microcrystalline quartz. Chalcedonic quartz fills radiolarian microfossils and is present in the matrix. Sulfide minerals include pyrite and sphalerite. Carbonate diagenesis is volumetrically minor and includes thin dolomite overgrowths and calcite cement. At least two generations of fractures are observed. Based on the authigenic minerals and their relative timing of formation, the evolution of pore waters can be postulated. Dolomite and calcite resulted from early postdepositional aerobic oxidation of some of the abundant organic material in the formation. Following aerobic oxidation, conditions became anoxic and sulfide minerals precipitated. Transformation of the originally opaline tests of radiolaria resulted in precipitation of quartz, and quartz authigenesis is most common in more distal parts of the depositional basin where radiolaria were abundant. Because quartz authigenesis is related to the distribution of radiolaria, there is a link between diagenesis and depositional environment. Furthermore, much of the diagenesis in the upper shale member preceded hydrocarbon generation, so early postdepositional processes were responsible for occlusion of significant original porosity in the member. Thus, diagenetic mineral precipitation was at least partly responsible for the limited ability of these mudstones to provide porosity for storage of hydrocarbons.

Extensional Late Paleozoic deformation on the western margin of Pangea, Patlanoaya area, Acatlán Complex, southern Mexico

NASA Astrophysics Data System (ADS)

Ramos-Arias, M. A.; Keppie, J. D.; Ortega-Rivera, A.; Lee, J. W. K.

2008-02-01

New mapping in the northern part of the Paleozoic Acatlán Complex (Patlanoaya area) records several ductile shear zones and brittle faults with normal kinematics (previously thought to be thrusts). These movement zones separate a variety of units that pass structurally upwards from: (i) blueschist-eclogitic metamorphic rocks (Piaxtla Suite) and mylonitic megacrystic granites (Columpio del Diablo granite ≡ Ordovician granites elsewhere in the complex); (ii) a gently E-dipping, listric, normal shear zone with top to the east kinematic indicators that formed under upper greenschist to lower amphibolite conditions; (iii) the Middle-Late Ordovician Las Minas quartzite (upper greenschist facies psammites with minor interbedded pelites intruded by mafic dikes and a leucogranite dike from the Columpio del Diablo granite) unconformably overlain by the Otate meta-arenite (lower greenschist facies psammites and pelites): roughly temporal equivalents are the Middle-Late Ordovician Mal Paso and Ojo de Agua units (interbedded metasandstone and slate, and metapelite and mafic minor intrusions, respectively) — some of these units are intruded by the massive, 461 ± 2 Ma, Palo Liso megacrystic granite: decussate, contact metamorphic muscovite yielded a 40Ar/ 39Ar plateau age of 440 ± 4 Ma; (iv) a steeply-moderately, E-dipping normal fault; (v) latest Devonian-Middle Permian sedimentary rocks (Patlanoaya Group: here elevated from formation status). The upward decrease in metamorphic grade is paralleled by a decrease in the number of penetrative fabrics, which varies from (i) three in the Piaxtla Suite, through (ii) two in the Las Minas unit (E-trending sheath folds deformed by NE-trending, subhorizontal folds with top to the southeast asymmetry, both associated with a solution cleavage), (iii) one in the Otate, Mal Paso, and Ojo de Agua units (steeply SE-dipping, NE-SW plunging, open-close folds), to (iv) none in the Patlanoaya Group. 40Ar/ 39Ar analyses of muscovite from the earliest cleavage in the Las Minas unit yielded a plateau age of 347 ± 3 Ma and show low temperature ages of ˜ 260 Ma. Post-dating all of these structures and the Patlanoaya Group are NE-plunging, subvertical folds and kink bands. An E-W, vertical normal fault juxtaposes the low-grade rocks against the Anacahuite amphibolite that is cut by megacrystic granite sheets, both of which were deformed by two penetrative fabrics. Amphibole from this unit has yielded a 40Ar/ 39Ar plateau age of 299 ± 6 Ma, which records cooling through ˜ 490 °C and is probably related to a Permo-Carboniferous reheating event during exhumation. The extensional deformation is inferred to have started in the latest Devonian (˜ 360 Ma) during deposition of the basal Patlanoaya Group, lasting through the rapid exhumation of the Piaxtla Suite at ˜ 350-340 Ma synchronous with cleavage development in the Las Minas unit, deposition of the Patlanoaya Group with active fault-related exhumation suggested by Mississippian and Early Permian conglomerates (˜ 340 and 300 Ma, respectively), and continuing at least into the Middle Permian (≡ 260 Ma muscovite ages). The continuity of Mid-Continent Mississippian fauna from the USA to southern Mexico suggests that this extensional deformation occurred on the western margin of Pangea after closure of the Rheic Ocean.

Lower Paleozoic deep-water facies of the Medfra area, central Alaska: A section in Geologic studies in Alaska by the U.S. Geological Survey, 1997

USGS Publications Warehouse

Dumoulin, Julie A.; Bradley, Dwight C.; Harris, Anita G.; Repetski, John E.

1999-01-01

Deep-water facies, chiefly hemipelagic deposits and turbidites, of Cambrian through Devonian age are widely exposed in the Medfra and Mt. McKinley quadrangles. These strata include the upper part of the Telsitna Formation (Middle-Upper Ordovician) and the Paradise Fork Formation (Lower Silurian-Lower Devonian) in the Nixon Fork terrane, the East Fork Hills Formation (Upper Cambrian-Lower Devonian) in the East Fork subterrane of the Minchumina terrane, and the chert and argillite unit (Ordovician) and the argillite and quartzite unit (Silurian- Devonian? and possibly older) in the Telida subterrane of the Minchumina terrane.In the western part of the study area (Medfra quadrangle), both hemipelagic deposits and turbidites are largely calcareous and were derived from the Nixon Fork carbonate platform. East- ern exposures (Mt. McKinley quadrangle; eastern part of the Telida subterrane) contain much less carbonate; hemipelagic strata are mostly chert, and turbidites contain abundant rounded quartz and lesser plagioclase and potassium feldspar. Deep-water facies in the Medfra quadrangle correlate well with rocks of the Dillinger terrane exposed to the south (McGrath quadrangle), but coeval strata in the Mt. McKinley quadrangle are compositionally similar to rocks to the northeast (Livengood quadrangle). Petrographic data thus suggest that the Telida subterranes presently defined is an artificial construct made up of two distinct sequences of disparate provenance.Restoration of 90 and 150 km of dextral strike-slip on the Iditarod and Farewell faults, respectively, aligns the deep-water strata of the Minchumina and Dillinger terranes in a position east of the Nixon Fork carbonate platform. This restoration supports the interpretation that lower Paleozoic rocks in the Nixon Fork and Dillinger terranes, and in the western part of the Minchumina terrane (East Fork subterrane and western part of the Telida subterrane), formed along a single continental margin. Rocks in the eastern part of the Telida subterrane are compositionally distinct from those to the west and may have had a different origin and history.

Juxtaposition of contrasting structural regimes across a portion of the Norumbega fault system in the northern Casco Bay region of Maine

NASA Astrophysics Data System (ADS)

West, D. P., Jr.; Hussey, A. M., II

2015-12-01

It has long been recognized that Paleozoic stratified rocks in some regions of central New England are dominated by relatively flat structural features (e.g., recumbent folds, shallow dipping foliation) while other areas are dominated by near vertical upright structures. The northern Casco Bay region of coastal Maine (Brunswick 7.5' quadrangle and adjacent areas) provides an excellent venue for studying the relationships between these two structural regimes as they are in close proximity due to juxtaposition by high angle faulting associated with the Norumbega fault system. Stratified rocks exposed west of the Flying Point fault in northern Casco Bay are dominated by moderately east dipping foliation (ave. = 025o, 37o), moderate northeast plunging mineral lineations, and recumbent to gently inclined minor folds. In stark contrast, immediately east of the Flying Point fault, stratified rocks are dominated by steep east dipping foliation (ave. = 014o, 73o), subhorizontal mineral lineations, and upright to steeply inclined minor folds. The structural differences correspond directly to differences in the thermal histories preserved in these rocks as revealed by earlier thermochronological studies. Rocks in the zone of upright structures east of the Flying Point fault were last subjected to high grade metamorphic conditions and granitic plutonism in the Late Devonian and were relatively cold (<300oC) by Late Carboniferous time. In contrast, flat lying rocks west of the Flying Point fault were over 500oC in the Early Permian and Permian pegmatites are common. Geochronological studies north of the study area have revealed that the two distinctly different structural styles are not the product of strain partitioning during the same deformational episode, but rather they represent two temporally and kinematically distinct deformational events. Swanson (1999), originally suggested flat structures west of the Flying Point fault are consistent with an episode of northwest directed thrusting and our findings are consistent with this interpretation. However, this flat phase of deformation significantly post-dates the older upright structures preserved to the east and thus models for the structural evolution of the region must integrate both the kinematic and temporal differences in this deformation.

U-Pb ages and metamorphic evolution of the La Pampa Gneisses: Implications for the evolution of the Chilenia Terrane and Permo-Triassic tectonics of north Central Chile

NASA Astrophysics Data System (ADS)

Álvarez, Javier; Mpodozis, Constantino; Blanco-Quintero, Idael; García-Casco, Antonio; Arriagada, César; Morata, Diego

2013-11-01

The La Pampa Gneisses are an enclave of orthogneisses emplaced within late Paleozoic to Triassic granitoids of the Chollay Batholith, in the Cordillera Frontal, to the east of Vallenar. Previous geochronological data (a Rb/Sr “errorchron” of 415 ± 4 Ma) allowed to some authors to suggest that these rocks were part of the Chilenia Terrane accreted to Gondwana during the Middle Devonian (ca. 390 Ma). New petrographic, chemical and geothermobarometric studies, together with U-Pb geochronological data show that the protolith of the La Pampa Gneisses derives from peraluminous tonalites emplaced during the Pennsylvanian at 306.5 ± 1.8 Ma, ruling out the hypothesis considering these rocks as remnant of the pre-collisional Chilenia basement. The tonalites were metamorphosed between 5.06 and 5.58 kbar and 709-779 °C during the middle Permian (267.6 ± 2.1 Ma), possibly in conjunction with the San Rafael tectonic event and the emplacement of the oldest granitoids of the Chollay Batholith. A new intrusive episode occurred at ca. 240 Ma, followed by exhumation and cooling during a regional Triassic extensional episode.

Bedrock geologic and joint trend map of the Pinardville quadrangle, Hillsborough County, New Hampshire

USGS Publications Warehouse

Burton, William C.; Armstrong, Thomas R.

2013-01-01

The bedrock geology of the Pinardville quadrangle includes the Massabesic Gneiss Complex, exposed in the core of a regional northeast-trending anticlinorium, and highly deformed metasedimentary rocks of the Rangeley Formation, exposed along the northwest limb of the anticlinorium. Both formations were subjected to high-grade metamorphism and partial melting: the Rangeley during the middle Paleozoic Acadian orogeny, and the Massabesic Gneiss Complex during both the Acadian and the late Paleozoic Alleghanian orogeny. Granitoids produced during these orogenies range in age from Devonian (Spaulding Tonalite) to Permian (granite at Damon Pond), each with associated pegmatite. In the latest Paleozoic the Massabesic Gneiss Complex was uplifted with respect to the Rangeley Formation along the ductile Powder Hill fault, which also had a left-lateral component. Uplift continued into the early Mesozoic, producing the 2-kilometer-wide Campbell Hill fault zone, which is marked by northwest-dipping normal faults and dilational map-scale quartz bodies. Rare, undeformed Jurassic diabase dikes cut all older lithologies and structures. A second map is a compilation of joint orientations measured at all outcrops in the quadrangle. There is a great diversity of strike trends, with northeast perhaps being the most predominant.

The evolutionary diversification of seed size: using the past to understand the present.

PubMed

Sims, Hallie J

2012-05-01

The Devonian origin of seed plants and subsequent morphological diversification of seeds during the late Paleozoic represents an adaptive radiation into unoccupied ecological niche space. A plant's seed size is correlated with its life-history strategy, growth form, and seed dispersal syndrome. The fossil record indicates that the oldest seed plants had relatively small seeds, but the Mississippian seed size envelope increased significantly with the diversification of larger seeded lineages. Fossil seeds equivalent to the largest extant gymnosperm seeds appeared by the Pennsylvanian, concurrent with morphological diversification of growth forms and dispersal syndromes as well as the clade's radiation into new environments. Wang's Analysis of Skewness indicates that the evolutionary trend of increasing seed size resulted from primarily passive processes in Pennsylvanian seed plants. The distributions of modern angiosperms indicate a more diverse system of active and some passive processes, unbounded by Paleozoic limits; multiple angiosperm lineages independently evolved though the upper and lower bounds. Quantitative measures of preservation suggest that, although our knowledge of Paleozoic seeds is far from complete, the evolutionary trend in seed size is unlikely to be an artifact of taphonomy. © 2012 The Author. Evolution© 2012 The Society for the Study of Evolution.

Petroleum geology of the major producing basins of Algeria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Attar, A.; Chaouch, A.

1988-08-01

The South Atlas flexure divides Algeria into two contrasting geologic provinces: (1) the Saharan Atlas and offshore region in the north, both of which are part of the Mediterranean basin, and (2) the Saharan platform on the south, part of the North African craton. The limits of the various sedimentary basins on the Saharan platform are tied to late Paleozoic (Hercynian) crustal reactivation. Comparable structurally controlled basins in northern Algeria are the products of Mesozoic-Recent tectonism. The spatial and temporal distribution of hydrocarbons in the Algerian Sahara can be understood in terms of the geologic evolution of the region. Analysismore » of areas of proven hydrocarbon reserves permits the following generalizations. (1) There is a concentration of oil and gas fields northeast of a northwest-southeast-trending line connecting Hassi R'Mel with In Amenas. Production is also established in the Sbaa basin and in northern Algeria, where recent discoveries have been made in, respectively, upper Paleozoic and Mesozoic reservoirs. (2) Hydrocarbon are present throughout the entire sedimentary column, but major production currently is restricted to the lower Paleozoic (Cambrian-Ordovician and Lower Devonian) and Triassic reservoirs.« less

Raman spectroscopic and microthermometric studies of authigenic quartz (the Pepper Mts., Central Poland) as an indicator of fluids circulation

NASA Astrophysics Data System (ADS)

Naglik, Beata; Toboła, Tomasz; Natkaniec-Nowak, Lucyna; Luptáková, Jarmila; Milovská, Stanislava

2017-02-01

Differently colored authigenic quartz crystals were found as the druses compound within mudstone heteroliths from the Pepper Mts. Shale Formation (Cambrian unit of the Holy Cross Mts., Central Poland). The genesis of this mineral was established on the basis of fluid inclusion study. Raman microspectroscopy was the key instrumental technique to identify the nature of the compounds trapped in the fluid inclusions. Methane (2917 cm- 1) or water vapor (broad band 2500-3000 cm- 1) occur within two-phased primary inclusion assemblages, while nitrogen (2329 cm- 1) associated with methane and trace amount of carbon dioxide (1285, 1388 cm- 1) occur within secondary fluid inclusion assemblage. Temperatures of homogenization of primary fluid inclusions was obtained on the basis of heating experiments and ranged from 171° to 266 °C. These values are much higher than expected for the diagenetic system without metamorphic changes what may imply hydrothermal origin of quartz crystals. The source of fluids is uncertain as in the Holy Cross Mts. there was no volcanic activity to the end of Late Devonian. However, fluids originated in metamorphic basin could use deep faults as the migration paths.

Oceanic Impact: Mechanisms and Environmental Perturbations

NASA Technical Reports Server (NTRS)

Gersonde, Rainer (Editor); Deutsch, Alex (Editor); Ivanov, Boris A. (Editor); Kyte, Frank T. (Editor)

2002-01-01

The contents include the following: Oceanic impacts-a growing field of fundamental geoscience. Shock metamorphism on the ocean floor (numerical simulations). Numerical modeling of impact-induced modifications of the deep-sea floor. Computer modelling of the water resurge at a marine impact: the Lockne crater, Sweden. Experimental investigation of the role of water in impact vaporization chemistry. Calcareous plankton stratigraphy around the Pliocene Eltanin asteroid impact area (SE Pacific): documentation and application for geological and paleoceanographic reconstruction. Composition of impact melt debris from the Eltanin impact strewn field, Bellingshausen Sea. Iridium concentrations and abundances of meteoritic ejecta from the Eltanin impact in sediment cores from Polarstern expedition ANT XII/4. Unmelted meteoritic debris collected from Eltanin ejecta in Polarstern cores from expedition ANT XII/4. Impact tsunami-Eltanin. Ancient impact structures on modern continental shelves: The Chesapeake Bay, Montagnais, and Toms Canyon craters, Atlantic margin of North America. The Mjolnir marine impact crater porosity anomaly. Kardla (Hiiu-maa Island, Estonia) - the buried and well-preserved Ordovician marine impact structure. Long-term effect of the Kardla crater (Hiiu-maa, Estonia) on Late Ordovician carbonate sedimentation. The middle Devonian Kaluga impact crater (Russia): new interpretation of marine setting.

Silurian pinnacle reefs of the Canadian Arctic

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Freitas, T.A.; Dixon, O.A.; Mayr, U.

1993-04-01

Pinnacle reefs are commonly an attractive target for oil exploration because they are usually porous carbonate bodies entombed in impervious, deep-water shales that provide both the source and the seal for hydrocarbons. Silurian pinnacle reefs, the first described in the Canadian Arctic Archipelago, are exposed on Ellesmere and Devon Islands. Two main reef trends occur, one of early middle Llandovery to middle Ludlow age and a second of middle Ludlow to Late Silurian or Early Devonian age. Reefs of both phases contain lime mudstone cores: some are stromatactoid-rich and others consist predominantly of microbialite-rich lime mudstone or microbial boundstone. Faciesmore » sequences of both reef phases show evidence of upward-shallowing overall, but, in the older reefs, isochronous capping facies are dominated either by coral-mirian or by stromatoporoid boundstone and floatstone. This difference perhaps reflects variation in wave stress and apparent ability of a few corals,thickly encrusted by or associated with microbial boundstone and skeletal algae, to withstand greater wave energy than a stromatoporoid-coral-rich reef community. These reefs constitute one of the bright prospects of hydrocarbon exploration in rocks of the Franklinian succession. 43 refs., 9 figs.« less

Potentiometric surface of the Ozark aquifer in northern Arkansas, 2004

USGS Publications Warehouse

Schrader, T.P.

2005-01-01

The Ozark aquifer in northern Arkansas comprises dolomites, limestones, sandstones, and shales of Late Cambrian to Middle Devonian age, and ranges in thickness from approximately 1,100 feet to more than 4,000 feet. Hydrologically, the aquifer is complex, characterized by discrete and discontinuous flow components with large variations in permeability. The potentiometric-surface map, based on 59 well and 5 spring water-level measurements collected in 2004 in Arkansas and Missouri, indicates maximum water-level altitudes of about 1,188 feet in Benton County and minimum water-level altitudes of about 116 feet in Randolph County. Regionally, the flow within the aquifer is to the south and southeast in the eastern and central part of the study area and to the northwest and north in the western part of the study area. Comparing the 2004 potentiometric- surface map with a predevelopment potentiometricsurface map indicates general agreement between the two surfaces. Potentiometric-surface differences could be attributed to differences in pumping related to changing population from 1990 to 2000, change in source for public supplies, processes or water use outside the study area, or differences in data-collection or map-construction methods.

Unravelling Orbital Climatic Cycles from Devonian Magnetic Susceptibility Signal - The Quest for a Better Age Model for the Lochkovian and Pragian Stages (Czech Republic)

NASA Astrophysics Data System (ADS)

da Silva, A. C.; Chadimova, L.; Hladil, J.; Slavik, L.; Hilgen, F. J.; Dekkers, M. J.

2015-12-01

The uncertainties on the Devonian stage boundaries are currently in the order of several millions of years. When shown to reflect a detrital signal, which is influenced by climatic variations, Magnetic Susceptibility (MS) has been proven as a useful tool for identifying climatic cycles; which can subsequently be used to improve the time scale. Here, we focus on two sections from the Prague Synform (Czech Republic) cutting through the Lochkovian, Pragian and the lower part of the Emsian. Sedimentation is rhythmic, dominated by slightly clayey offshore limestones, being mostly calciturbidites and hemipelagites. We provide hysteresis analysis in order to get insight into the nature and the origin of the magnetic minerals driving the variation in the MS signal. The results point to a MS signal mostly carried by clay minerals. Subsequently, to improve estimation of the duration of the stages, we apply different spectral analysis techniques on this MS signal. From the Continuous Wavelet Transform (CWT), Evolutive Harmonic Analysis (EHA) and field observations, we subdivide the section into portions with a steady sedimentation rate (a first estimate of this rate is also delivered by these analyzes). Then, we apply Multitaper Method (MTM) and Multitaper harmonic Analysis (F-test) and extract the frequencies reaching 95% Confidence Level. These frequencies are then implemented into the Average Spectral Misfit procedures (ASM) which enables comparison with orbital targets. By combining these different techniques, 405 kyr cyclicty is identifed, a powerful duration paleochronometer. These new results indicate a duration of 7.7 ± 2 Myr for the Lochkovian stage and of 1.7 Myr ± 1.4 for the Pragian stage (compared to respectively 8.4 ± 6 Myr and 3.2 ± 5.4 Myr in the 2012 Geological Time Scale).

Post-early cretaceous landform evolution along the western margin of the banca~nnia trough, western nsw

USGS Publications Warehouse

Gibson, D.L.

2000-01-01

Previously undated post-Devonian sediments outcropping north of Fowlers Gap station near the western margin of the Bancannia Trough are shown by plant macro- and microfossil determinations to be of Early Cretaceous (most likely Neocomian and/or Aptian) age, and thus part of the Eromanga Basin. They are assigned to the previously defined Telephone Creek Formation. Study of the structural configuration of this unit and the unconformably underlying Devonian rocks suggests that the gross landscape architecture of the area results from post-Early Cretaceous monoclinal folding along blind faults at the western margin of the trough, combined with the effects of differential erosion. This study shows that, while landscape evolution in the area has been dynamic, the major changes that have occurred are on a geological rather than human timescale.

Preliminary stratigraphic cross section showing radioactive zones in the Devonian dark shales in the eastern part of the Appalachian Basin

USGS Publications Warehouse

West, Mareta N.

1978-01-01

The U.S. Geological Survey (USGS), in a cooperative agreement with the U.S. Department of Energy (DOE), is participating in the Eastern Gas Shales Project. The purpose of the DOE project is to increase the production of natural gas from eastern United States shales in petroliferous basins through improved exploration and extraction techniques. The USGS participation includes stratigraphic studies which will contribute to the characterization and appraisal of the natural gas resources of Devonian shale in the Appalachian basin.This cross section differs from others in this series partly because many of the shales in the eastern part of the basin are less radioactive than those farther west and because in this area shales that may be gas-productive are not necessarily highly radioactive and black.

An organismal concept for Sengelia radicans gen. et sp. nov. - morphology and natural history of an Early Devonian lycophyte.

PubMed

Matsunaga, Kelly K S; Tomescu, Alexandru M F

2017-05-01

Fossil plants are found as fragmentary remains and understanding them as natural species requires assembly of whole-organism concepts that integrate different plant parts. Such concepts are essential for incorporating fossils in hypotheses of plant evolution and phylogeny. Plants of the Early Devonian are crucial to reconstructing the initial radiation of tracheophytes, yet few are understood as whole organisms. This study assembles a whole-plant concept for the Early Devonian lycophyte Sengelia radicans gen. et sp. nov., based on morphometric data and taphonomic observations from >1000 specimens collected in the Beartooth Butte Formation (Wyoming, USA). Sengelia radicans occupies a key position between stem-group and derived lycophyte lineages. Sengelia had a rooting system of downward-growing root-bearing stems, formed dense monotypic mats of prostrate shoots in areas that experienced periodic flooding, and was characterized by a life-history strategy adapted for survival after floods, dominated by clonality, and featuring infrequent sexual reproduction. Sengelia radicans is the oldest among the very few early tracheophytes for which a detailed, rigorous whole-plant concept integrates morphology, growth habit, life history and growth environment. This plant adds to the diversity of body plans documented among lycophytes and may help elucidate patterns of morphological evolution in the clade. © The Author 2017. Published by Oxford University Press on behalf of the Annals of Botany Company. All rights reserved. For Permissions, please email: journals.permissions@oup.com

Faulting at Thebes Gap, Mo. -Ill. : Implications for New Madrid tectonism

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harrison, R.W.; Schultz, A.P.

1992-01-01

Recent geologic mapping in the Thebes Gap area has identified numerous NNE- and NE-striking faults having a long-lived and complex structural history. The faults are located in an area of moderate recent seismicity at the northern margin of the Mississippi embayment, approximately 45 km north of the New Madrid seismic zone. Earliest deformation occurred along dextral strike-slip faults constrained as post-Devonian and pre-Cretaceous. Uplift and erosion of all Carboniferous strata suggest that this faulting is related to development of the Pascola arch (Ouachita orogeny). This early deformation is characterized by strongly faulted and folded Ordovician through Devonian rocks overlain inmore » places with angular unconformity by undeformed Cretaceous strata. Elsewhere, younger deformation involves Paleozoic, Cretaceous, Paleocene, and Eocene formations. These units have experienced both minor high-angle normal faulting and major, dextral strike-slip faulting. Quaternary-Tertiary Mounds Gravel is also involved in the latest episode of strike-slip deformation. Enechelon north-south folds, antithetic R[prime] shears, and drag folds indicate right-lateral motion. Characteristic positive and negative flower structures are commonly revealed in cross section. Right-stepping fault strands have produced pull-apart basins where Ordovician, Silurian, Devonian, Cretaceous, and Tertiary units are downdropped several hundreds of meters and occur in chaotic orientations. Similar fault orientations and kinematics, as well as recent seismicity and close proximity, clearly suggest a structural relationship between deformation at Thebes Gap and tectonism associated with the New Madrid area.« less

Bedrock geologic map of the Montpelier and Barre West quadrangles, Washington and Orange Counties, Vermont

USGS Publications Warehouse

Walsh, Gregory J.; Kim, Jonathan; Gale, Marjorie H.; King, Sarah M.

2010-01-01

The bedrock geology of the Montpelier and Barre West quadrangles consists of Silurian and Devonian metasedimentary rocks of the Connecticut Valley-Gaspe synclinorium (CVGS) and metasedimentary, metavolcanic, and metaintrusive rocks of the Cambrian and Ordovician Moretown and Cram Hill Formations. Devonian granite dikes occur throughout the two quadrangles but are more abundant in the Silurian and Devonian rocks. The pre-Silurian rocks are separated from the rocks of the CVGS by the informally named 'Richardson Memorial Contact,' historically interpreted as either an unconformity or a fault. The results of this report represent mapping by G.J. Walsh, Jonathan Kim, and M.H. Gale from 2002 to 2005. S.M. King assisted Kim and Gale from 2002 to 2003. A.M. Satkoski (Indiana University) assisted Walsh, and L.R. Pascale (University of Vermont) and C.M. Orsi (Middlebury College) assisted Kim and Gale as summer interns in 2003. This study was designed to map the bedrock geology in the area. This map supersedes a preliminary map of the Montpelier quadrangle (Kim, Gale, and others, 2003). A companion study in the Barre West quadrangle (Walsh and Satkoski, 2005) determined the levels of naturally occurring radioactivity in the bedrock from surface measurements at outcrops during the course of 1:24,000-scale geologic mapping to identify which rock types were potential sources of radionuclides. Results of that study indicate that the carbonaceous phyllites in the CVGS have the highest levels of natural radioactivity.

Representatives of the family Actinostromatidae (Stromatoporoidea) in the Devonian of southern Poland and their ecological significance

NASA Astrophysics Data System (ADS)

Wolniewicz, Paweł

2016-09-01

Stromatoporoids of the family Actinostromatidae are common constituents of Givetian to Frasnian (Devonian) organic buildups. The species-level structure of actinostromatid assemblages from the Devonian of southern Poland is described in the present paper, with special emphasis on ecological factors that influenced species composition of the communities. Nine species of the genera Actinostroma and Bifariostroma are distinguished. Members of the family Actinostromatidae predominated in stromatoporoid assemblages within lower Frasnian carbonate buildup margins. The most diverse actinostromatid faunas were found within the middle Givetian Stringocephalus Bank, in the upper Givetian-lower Frasnian biostromal complex and in the lower Frasnian organic buildups. Species-level biodiversity was lowest within detrital facies which surrounded the Frasnian carbonate buildups. Species of Actinostroma with well-developed colliculi are commonest within the middle Givetian to early Frasnian coral-stromatoporoid biostromal complexes, whereas species with strongly reduced colliculi predominate early-middle Frasnian organic buildups. The skeletal structure of actinostromatids reflects environmental changes, documenting a transition from species with thin, close-set pillars and widely spaced laminae (common in the middle Givetian) to those with long, thick pillars and megapillars (in Bifariostroma), which were predominant during the early and middle Frasnian. The distribution of growth forms among species reveals a significant intraspecific variation. Species of Actinostroma can be either tabular or low domical, depending on the palaeoenvironmental setting. Thus, the present study confirms that stromatoporoid morphology was influenced by environmental conditions.

Kimmeridgian Shales Total Petroleum System of the North Sea Graben Province

USGS Publications Warehouse

Gautier, Donald L.

2005-01-01

The North Sea Graben of northwestern Europe, World Energy Project Province 4025, is entirely offshore within the territorial waters of Denmark, Germany, the Netherlands, Norway, and the United Kingdom. Extensional tectonics and failed rifting are fundamental to the distribution of oil and gas in the province. Accordingly, the geologic history and reser-voir rocks of the province are considered in the context of their temporal relationship to the principal extension and rifting events. The oil and gas accumulations of the province are considered part of a single petroleum system: the Kimmeridg-ian Shales Total Petroleum System (TPS). Source rocks of the Kimmeridgian Shales TPS were deposited in Late Jurassic to earliest Cretaceous time during the period of intensive exten-sion and rifting. The Kimmeridgian Shales contain typical 'type II' mixed kerogen. Oil and gas generation began locally in the North Sea Graben Province by Cretaceous time and has continued in various places ever since. Reservoirs are found in strata with ages ranging from Devonian to Eocene. Pre-rift reservoirs are found in fault-block structures activated during rifting and can be of any age prior to the Late Jurassic. Syn-rift reservoirs are restricted to strata actually deposited during maximum extension and include rocks of Late Jurassic to earliest Cretaceous age. Post-rift reservoirs formed after rifting and range in age from Early Cretaceous to Eocene. Seals are diverse, depending upon the structural setting and reservoir age. Pre-rift reservoirs com-monly have seals formed by fine-grained, post-rift sedimentary sequences that drape the Late Jurassic to earliest Cretaceous structures. Contemporaneous shales such as the Kimmeridge Clay seal many syn-rift reservoirs. Fields with post-rift res-ervoirs generally require seals in fine-grained Tertiary rocks. In most of the North Sea Graben, source rocks have been continuously buried since deposition. Structural trap forma-tion has also taken place continuously since Mesozoic time. As a result, oil and gas are present in a wide variety of settings within Province 4025. Assessment units for the World Energy Project were defined geographically in order to capture regional differ-ences in exploration history, geography, and geological evolution. Three geographic areas were assessed. The Viking Graben, in the northern part of the province, includes both United Kingdom and Norwegian territorial areas. The Moray Firth/Witch Ground in the west-central part of the province is entirely in United Kingdom. waters. The Central Graben in the southern part of the province includes territorial areas of Denmark, Germany, the Netherlands, Norway, and the United Kingdom. The North Sea Graben is estimated to contain between 4.3 and 25.6 billion barrels (BBO) of undiscovered, conventionally recoverable oil. Of that total, the Viking Graben is believed to contain 2.2 to 14.8 BBO of undiscov-ered oil, the Moray Firth/Witch Ground may contain between 0.3 and 1.9 BBO, and the Central Graben was estimated to contain undiscovered oil resources of 1.7 to 8.8 BBO. Prov-ince 4025 was also estimated to hold between 11.8 and 75 trillion cubic feet (TCF) of undiscovered natural gas. Of this total, 6.8 to 44.5 TCF is thought to exist in the Viking Graben, 0.6 to 3.4 TCF is estimated to be in the Moray Firth/Witch Ground, and 4.5 to 27.1 TCF of undiscovered gas is estimated to be in the Central Graben.

K-Ar geochronology of basement rocks on the northern flank of the Huancabama deflection, Ecuador

USGS Publications Warehouse

Feininger, Tomas; Silberman, M.L.

1982-01-01

The Huancabamba deflection, a major Andean orocline located at the Ecuador-Peru border, constitutes an important geologic boundary on the Pacific coast of South America. Crust to the north of the deflection is oceanic and the basement is composed of basic igneous rocks of Cretaceous age, whereas crust to the south is continental and felsic rocks of Precambrian to Cretaceous age make up the basement. The northern flank of the Huancabamba Deflection in El Oro Province, Ecuador, is underlain by Precambrian polymetamorphic basic rocks of the Piedras Group; shale, siltstone, sandstone, and their metamorphosed equivalents in the Tahuin Group (in part of Devonian age); concordant syntectonic granitic rocks; quartz diorite and alaskite of the Maroabeli pluton; a protrusion of serpentinized harzburgite that contains a large inclusion of blueschist-facies metamorphic rocks, the Raspas Formation, and metamorphic rocks north of the La Palma fault. Biotite from gneiss of the Tahuin Group yields a Late Triassic K-Ar age (210 ? 8 m.y.). This is interpreted as an uplift age and is consistent with a regional metamorphism of Paleozoic age. A nearby sample from the Piedras Group that yielded a hornblende K-Ar age of 196 ? 8 m.y. was affected by the same metamorphic event. Biotite from quartz diorite of the mesozonal Maroabeli pluton yields a Late Triassic age (214 ? 6 m.y.) which is interpreted as an uplift age which may be only slightly younger than the age of magmatic crystallization. Emplacement of the pluton may postdate regional metamorphism of the Tahuin Group. Phengite from politic schist of the Raspas Formation yields an Early Cretaceous K-Ar age (132 ? 5 m.y.). This age is believed to date the isostatic rise of the encasing serpentinized harzburgite as movement along a subjacent subduction zone ceased, and it is synchronous with the age of the youngest lavas of a coeval volcanic arc in eastern Ecuador. A Late Cretaceous K-Ar age (74.4 ? 1.1 m.y.) from hornblende in amphibolite north of the La Palma fault shows that rocks there are distinct from the superficially similar rocks of the Tahuin Group to the south. Biotite from schist in the Eastern Andean Cordillera yields an Early Eocene age (56.6 ? 1.6 m.y.). Metamorphic rocks in the northern part of the Eastern Andean Cordillera are Cretaceous in age and were metamorphosed in part in early Tertiary time. They are unrelated to and were metamorphosed later than any of the diverse rocks exposed on the northern flank of the Huancabamba Deflection.

Identifying heterogeneity in rates of morphological evolution: discrete character change in the evolution of lungfish (Sarcopterygii; Dipnoi).

PubMed

Lloyd, Graeme T; Wang, Steve C; Brusatte, Stephen L

2012-02-01

Quantifying rates of morphological evolution is important in many macroevolutionary studies, and critical when assessing possible adaptive radiations and episodes of punctuated equilibrium in the fossil record. However, studies of morphological rates of change have lagged behind those on taxonomic diversification, and most authors have focused on continuous characters and quantifying patterns of morphological rates over time. Here, we provide a phylogenetic approach, using discrete characters and three statistical tests to determine points on a cladogram (branches or entire clades) that are characterized by significantly high or low rates of change. These methods include a randomization approach that identifies branches with significantly high rates and likelihood ratio tests that pinpoint either branches or clades that have significantly higher or lower rates than the pooled rate of the remainder of the tree. As a test case for these methods, we analyze a discrete character dataset of lungfish, which have long been regarded as "living fossils" due to an apparent slowdown in rates since the Devonian. We find that morphological rates are highly heterogeneous across the phylogeny and recover a general pattern of decreasing rates along the phylogenetic backbone toward living taxa, from the Devonian until the present. Compared with previous work, we are able to report a more nuanced picture of lungfish evolution using these new methods. © 2011 The Author(s). Evolution© 2011 The Society for the Study of Evolution.

Correlation of LANDSAT lineaments with Devonian gas fields in Lawrence County, Ohio

NASA Technical Reports Server (NTRS)

Johnson, G. O.

1981-01-01

In an effort to locate sources of natural gas in Ohio, the fractures and lineaments in Black Devonian shale were measured by: (1) field mapping of joints, swarms, and fractures; (2) stereophotointerpretation of geomorphic lineaments with precise photoquads; and (3) by interpreting the linear features on LANDSAT images. All results were compiled and graphically represented on 1:250,000 scale maps. The geologic setting of Lawrence County was defined and a field fracture map was generated and plotted as rose patterns at the exposure site. All maps were compared, contrasted, and correlated by superimposing each over the other as a transparency. The LANDSAT lineaments had significant correlation with the limits of oil and gas producing fields. These limits included termination of field production as well as extensions to other fields. The lineaments represent real rock fractures with zones of increased permeability in the near surface bedrock.

Indirect and direct tensile behavior of Devonian oil shales

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chong, K.P.; Chen, J.L.; Dana, G.F.

1984-03-01

Ultimate indirect tensile strengths of Devonian oil shales across the bedding planes is a mechanical property parameter important to predicting how oil shale will break. This is particularly important to in-situ fragmentation. The Split Cylinder Test was used to determine the indirect tensile strengths between the bedding planes. Test specimens, cored perpendicular to the bedding planes, representing oil shales of different oil yields taken from Silver Point Quad in DeKalb County, Tennessee and Friendship in Scioto County, Ohio, were subjected to the Split Cylinder Test. Linear regression equations relating ultimate tensile strength across the bedding planes to volume percent ofmore » organic matter in the rock were developed from the test data. In addition, direct tensile strengths were obtained between the bedding planes for the Tennessee oil shales. This property is important for the design of horizontal fractures in oil shales. Typical results were presented.« less

An enigmatic fossil fungus from the 410 Ma Rhynie chert that resembles Macrochytrium (Chytridiomycota) and Blastocladiella (Blastocladiomycota).

PubMed

Krings, Michael; Taylor, Thomas N; Martin, Helmut

2016-01-01

Litter layers in the Lower Devonian (~ 410 Ma) Rhynie chert were inhabited by a wide variety of saprotrophic fungi, however, only a few of these organisms have been described formally. A new microfungus, Trewinomyces annulifer gen. et sp. nov., occurs as tufts on decaying land plant axes from the Rhynie chert. The fungus consists of an intramatrical rhizoidal system and an erect extramatrical hypha (stalk) that bears a single, terminal sporangium. One or two successive rings often are present in the stalk immediately below the sporangium base. Overall morphology of T. annulifer resembles the extant genera Macrochytrium (Chytridiomycota) and Blastocladiella (Blastocladiomycota). However, the rhizoids are septate or pseudoseptate, a feature not known in extant zoosporic fungi, and thus render the systematic affinities of T. annulifer unresolved. Trewinomyces annulifer offers a rare view of the morphology of a distinctive Early Devonian saprotrophic microfungus. © 2016 by The Mycological Society of America.

Ornamentation of dermal bones of Placodermi from the Lower Devonian of Morocco as a measure of biodiversity

NASA Astrophysics Data System (ADS)

Antczak, Mateusz; Berkowski, Błażej

2017-06-01

Dermal bones are formed early during growth and thus constitute an important tool in studies of ontogenetic and evolutionary changes amongst early vertebrates. Ornamentation of dermal bones of terrestrial vertebrates is often used as a taxonomic tool, for instance in Aetosauria, extant lungfishes (Dipnoi) and ray-finned fishes (Actinopterygii), for which it have been proved to be of use in differentiating specimens to species level. However, it has not been utilised to the same extent in placoderms. Several features of the ornamentation of Early Devonian placoderms from Hamar Laghdad (Morocco) were examined using both optical and scanning electron microscopy to determine whether it is possible to distinguish armoured Palaeozoic fishes. Four distinct morphotypes, based on ornamentation of dermal bones, are differentiated. These distinct types of ornamentation may be the result of either different location of dermal plates on the body or of ontogenetic (intraspecific) and/or interspecific variation.

Geology of the southern Elkhorn Mountains, Jefferson and Broadwater Counties, Montana

USGS Publications Warehouse

Klepper, M.R.; Weeks, R.A.; Ruppel, E.T.

1957-01-01

The geology of an area of about 270 square miles in the southern Elkhorn Mountains, west of Townsend in west-central Montana, is described. The mountains in the southern part of the area comprise northward-trending alternating ridges and valleys underlain principally by folded sedimentary rocks. They merge northward into the higher and more rugged main mass of the mountains, which is underlain principally by upper Cretaceous volcanic rocks. The mountaintops are 1,000 to 4,500 feet above the major valleys. The sedimentary rocks range in age from Precambrian to Tertiary and the igneous rocks from late Cretaceous to probably middle Tertiary. The oldest rocks are varicolored mudstone, shale, and sandstone of the Belt series of late Precambrian age. They are overlain with slight unconformity by a moderately thick but incomplete section of Paleozoic rocks. The basal Paleozoic formation is the Flathead quartzite of Middle Cambrian age, which is overlain by alternating units of shale and carbonate rock : the Wolsey shale, the Meagher limestone, the Park shale, the Pilgrim dolomite, and the Red Lion formation, all of Cambrian age. A slight erosional unconformity between the Red Lion formation and the Maywood formation of late Devonian age marks a long interval of crustal stability in the area. The Maywood is overlain by the Jefferson dolomite and the Three Forks shale of Late Devonian and Mississippian age, and these in turn are conformably overlain by the Lodgepole and Mission Canyon limestones, a thick carbonate sequence of Mississippian age. A slight erosional unconformity separates the Mission Canyon limestone from the Amsden formation, which probably includes beds of both Mississippian and Pennsylvanian age. The Amsden is composed of a heterogeneous assemblage of arenaceous, argillaceous, dolomitic, and calcareous rocks and grades upward into the Quadrant formation of Pennsylvanian age, an alternation of quartzitic sandstone and dolomite. At the top of the Paleozoic section is the Phosphoria formation of Permian age, a thin unit of chert and quartzitic sandstone that contains a few thin phosphate beds. The basal Mesozoic unit is the Swift formation of late Jurassic age, a thin calcareous marine sandstone that overlies the Phosphoria with slight erosional unconformity. It is overlain by nonmarine shale and sandstone of the Morrison formation of late Jurassic age and the Kootenai formation of Early Cretaceous age. The Kootenai is overlain, possibly with slight erosional unconformity, by the Colorado formation an assemblage of marine dark shale and siliceous mudstone and nonmarine quartz-chert sandstone. The Colorado formation as here used includes beds of both Early and Late Cretaceous age. The Colorado in places grades upwards into a sequence of feldspathic sandstone and tuff beds here named the Slim Sam formation. Elsewhere within the area, the Slim Sam formation is absent, probably in part owing to erosion and in part nondeposition. Where present, the Slim Sam grades upward into a thick sequence of andesitic and quartz latitic volcanic rocks, comprising tuffs, lapilli tuffs, breccias, welded tuffs and flows, that are here named the Elkhorn Mountains volclinics and are probably entirely of Cretaceous age. Where the Slim Sam formation is absent, the Elkhorn Mountains volcanics rest with angular unconformity on beds as old as the Morrison. The pre-Tertiary layered rocks, aggregating more than 15,000 feet in thickness, were folded and intruded by igneous rocks of several types, and the area was uplifted and eroded to a terrain of mature relief, similar to that of the present. During the Oligocene epoch, volcanic sediments with interbreds of nonvolcanic gravel accumulated. These beds were in turn moderately eroded, and gravel of Miocene ( ?) age was deposited in channels within them. Subsequently, probably during the Pliocene epoch, the Tertiary beds were weakly deformed locally, and a pediment was cut across the Tertiary and older rocks in the southern part of the area. Fan gravel, in part of Recent origin and in part older, blankets parts of the pediment. Glacial deposits of at least two stages of Pleistocene glaciation are present in the higher mountains in the northern part of the area. The intrusive igneous rocks, except for a few felsite dikes of uncertain age, are divisible into two groups, primarily on the basis of structural relations and secondarily on the basis of composition and fabric. The older group of dioritic and andesitic rocks were intruded in part, if not wholly, prior to the main folding and are similar in chemical and mineralogical composition to the Elkhorn Mountains volcanics. They were probably emplaced throughout the period of volcanism that commenced in late Niobrara time and continued until late Cretaceous time. The younger group consists chiefly of quartzbearing phanerites but includes rocks ranging from gabbro to alaskitic granite and aplite. These rocks were emplaced after the main episode of folding and faulting. The Boulder batholith, composed dominantly of quartz monzonite, is the principal body of this younger group. The older igneous rocks metamorphosed the invaded rocks only slightly. In contrast, the younger intrusive bodies, and especially the batholith, altered and recrystallized the country rock in moderately broad belts, changing them to various types of hornfels, calcsilicate rock, marble, and vitreous quartzite. Concomitantly magnetite, garnet, axinite, and other high-temperature replacement minerals formed locally as products of additive metamorphism. The pre-Tertiary layered rocks of the southern Elkhorn Mountains are folded into northward-trending folds and are cut by many faults. The sedimentary rocks tend to be more tightly folded than the Elkhorn Mountains volcanics, although both were involved in the major folding. The principal folds of the area from east to west are : a major dome, a complex syncline with several second-order folds, and a remnant of a northward-plunging anticline, the major part of which was engulfed by the batholith. The folded rocks are cut by many faults of small to moderate displacement and by two faults of large displacement. Most of the faults were probably formed by the same forces that produced the folds. The origin of the two major faults, however, is uncertain, and may be related to igneous activity. The batholith crosscuts the folded structure and is in turn cut by small faults. Some parts of the area were elevated along steep normal faults in late Tertiary time. The southern part of the Elkhorn Mountains has been mountainous at least since early Oligocene time, and probably began to take form during the Cretaceous. As a consequence of long continued erosion, the modern topography reflects the structure and lithologic character of the underlying rocks except in a few areas blanketed by poorly consolidated Tertiary rocks and in the higher mountains where glaciation has been prominent. Silver, lead, zinc, and gold have been produced, either singly or, more typically, as a combination of metals from a number of types of ore deposits. Replacement deposits in carbonate rocks are the most common type, but veins, contact metamorphic deposits, and pipelike bodies of breccia cemented by ore and gangue minerals also are present. The Elkhorn mining district has the largest number of mines and the greatest variety of types of deposits. In the Tizer Basin several narrow goldbearing veins cut andesitic volcanic rocks, and in the southern part of the area sporadic small veins and replacement deposits occur in carbonate rocks. The mines and prospects of the area are described, and some suggestions for future prospecting are outlined. The application of geochemical prospecting techniques may prove of value, judging from the results of reconnaissance soil sampling in the vicinity of the Elkhorn mine.

Paleozoic to early Cenozoic cooling and exhumation of the basement underlying the eastern Puna plateau margin prior to plateau growth

NASA Astrophysics Data System (ADS)

Insel, N.; Grove, M.; Haschke, M.; Barnes, J. B.; Schmitt, A. K.; Strecker, M. R.

2012-12-01

Constraining the pre-Neogene history of the Puna plateau is crucial for establishing the initial conditions that attended the early stage evolution of the southern extent of the Andean plateau. We apply high- to low-temperature thermochronology data from plutonic rocks in northwestern Argentina to quantify the Paleozoic, Mesozoic and early Tertiary cooling history of the Andean crust. U-Pb crystallization ages of zircons indicate that pluton intrusion occurred during the early mid-Ordovician (490-470 Ma) and the late Jurassic (160-150 Ma). Lower-temperature cooling histories from 40Ar/39Ar analyses of K-feldspar vary substantially. Basement rocks underlying the western Puna resided at temperatures below 200°C (<6 km depth) since the Devonian (˜400 Ma). In contrast, basement rocks underlying the southeastern Puna were hotter (˜200-300°C) throughout the Paleozoic and Jurassic and cooled to temperatures of <200°C by ˜120 Ma. The southeastern Puna basement records a rapid cooling phase coeval with active extension of the Cretaceous Salta rift at ˜160-100 Ma that we associate with tectonic faulting and lithospheric thinning. The northeastern Puna experienced protracted cooling until the late Cretaceous with temperatures <200°C during the Paleocene. Higher cooling rates between 78 and 55 Ma are associated with thermal subsidence during the postrift stage of the Salta rift and/or shortening-related flexural subsidence. Accelerated cooling and deformation during the Eocene was focused within a narrow zone along the eastern Puna/Eastern Cordillera transition that coincides with Paleozoic/Mesozoic structural and thermal boundaries. Our results constrain regional erosion-induced cooling throughout the Cenozoic to have been less than ˜150°C, which implies total Cenozoic denudation of <6-4 km.

Geological Structure and History of the Arctic Ocean

NASA Astrophysics Data System (ADS)

Petrov, Oleg; Morozov, Andrey; Shokalsky, Sergey; Sobolev, Nikolay; Kashubin, Sergey; Pospelov, Igor; Tolmacheva, Tatiana; Petrov, Eugeny

2016-04-01

New data on geological structure of the deep-water part of the Arctic Basin have been integrated in the joint project of Arctic states - the Atlas of maps of the Circumpolar Arctic. Geological (CGS, 2009) and potential field (NGS, 2009) maps were published as part of the Atlas; tectonic (Russia) and mineral resources (Norway) maps are being completed. The Arctic basement map is one of supplements to the tectonic map. It shows the Eurasian basin with oceanic crust and submerged margins of adjacent continents: the Barents-Kara, Amerasian ("Amerasian basin") and the Canada-Greenland. These margins are characterized by strained and thinned crust with the upper crust layer, almost extinct in places (South Barents and Makarov basins). In the Central Arctic elevations, seismic studies and investigation of seabed rock samples resulted in the identification of a craton with the Early Precambrian crust (near-polar part of the Lomonosov Ridge - Alpha-Mendeleev Rise). Its basement presumably consists of gneiss granite (2.6-2.2 Ga), and the cover is composed of Proterozoic quartzite sandstone and dolomite overlain with unconformity and break in sedimentation by Devonian-Triassic limestone with fauna and terrigenous rocks. The old crust is surrounded by accretion belts of Timanides and Grenvillides. Folded belts with the Late Precambrian crust are reworked by Caledonian-Ellesmerian and the Late Mesozoic movements. Structures of the South Anuy - Angayucham ophiolite suture reworked in the Early Cretaceous are separated from Mesozoides proper of the Pacific - Verkhoyansk-Kolyma and Koryak-Kamchatka belts. The complicated modern ensemble of structures of the basement and the continental frame of the Arctic Ocean was formed as a result of the conjugate evolution and interaction of the three major oceans of the Earth: Paleoasian, Paleoatlantic and Paleopacific.

Almost a spider: a 305-million-year-old fossil arachnid and spider origins.

PubMed

Garwood, Russell J; Dunlop, Jason A; Selden, Paul A; Spencer, Alan R T; Atwood, Robert C; Vo, Nghia T; Drakopoulos, Michael

2016-03-30

Spiders are an important animal group, with a long history. Details of their origins remain limited, with little knowledge of their stem group, and no insights into the sequence of character acquisition during spider evolution. We describe a new fossil arachnid, Idmonarachne brasierigen. et sp. nov. from the Late Carboniferous (Stephanian,ca 305-299 Ma) of Montceau-les-Mines, France. It is three-dimensionally preserved within a siderite concretion, allowing both laboratory- and synchrotron-based phase-contrast computed tomography reconstruction. The latter is a first for siderite-hosted fossils and has allowed us to investigate fine anatomical details. Although distinctly spider-like in habitus, this remarkable fossil lacks a key diagnostic character of Araneae: spinnerets on the underside of the opisthosoma. It also lacks a flagelliform telson found in the recently recognized, spider-related, Devonian-Permian Uraraneida. Cladistic analysis resolves our new fossil as sister group to the spiders: the spider stem-group comprises the uraraneids and I. brasieri While we are unable to demonstrate the presence of spigots in this fossil, the recovered phylogeny suggests the earliest character to evolve on the spider stem-group is the secretion of silk. This would have been followed by the loss of a flagelliform telson, and then the ability to spin silk using spinnerets. This last innovation defines the true spiders, significantly post-dates the origins of silk, and may be a key to the group's success. The Montceau-les-Mines locality has previously yielded a mesothele spider (with spinnerets). Evidently, Late Palaeozoic spiders lived alongside Palaeozoic arachnid grades which approached the spider condition, but did not express the full suite of crown-group autapomorphies. © 2016 The Authors.

Palaeozoic gas charging in the Ahnet-Timimoun basin, Algeria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cawley, S.J.; Wilson, N.P.; Primmer, T.

1995-08-01

The Ahnet-Timimoun Basin, Southern Algeria, contains significant gas reserves expelled from originally oil prone Silurian and Frasnian shales. The gas is reservoired in Devonian and Carboniferous clastics in inversion anticlines formed, primarily, during the Hercynian orogeny. Integration of organic and inorganic geochemical techniques, such as AFTA, ZFTA, fluid inclusion analysis, vitrinite and chitinizoan reflectance, is entirely consistent with gas generation 300 +/- 30MY, immediately prior to or synchronous with the Hercynian orogeny. Data from gas fields has shown the remobilisation of gas during post Hercynian tectonics. A {open_quotes}two-event{close_quotes} heating/cooling history is proposed: (1) Maximum burial and palaeotemperature at ca. 300more » +/- 30MY prior to or synchronous with Hercynian uplift and cooling. (2) Cooling from a secondary peak (lower than maximum) palaeotemperature at ca. 30-60My following Creataceous burial. Calibrated thermal modelling indicates that Palaeozoic source rocks were heated above 200{degrees}C in the Late Carboniferous. Such high temperatures are consistent with the widespread occurrence of pyrophyllite in Silurian shales. Two end-member thermal models can account for the observed maturities. The first is a constant high Pre-Hercynian heat flow which rapidly decreases during Hercynian uplift to remain at Present day values of 50-75mW/m{sup 2}. Gas expulsion in this case commences much earlier than trap formation. The second is {open_quotes}normal{close_quotes} heat flow of ca. 50mW/m{sup 2} until ca. 310My with a rapid increase at ca. 290My followed by an equally rapid drop to constant present day values - in this model, petroleum generation and expulsion is late in relation to structuring.« less

New insight on petroleum system modeling of Ghadames basin, Libya

NASA Astrophysics Data System (ADS)

Bora, Deepender; Dubey, Siddharth

2015-12-01

Underdown and Redfern (2008) performed a detailed petroleum system modeling of the Ghadames basin along an E-W section. However, hydrocarbon generation, migration and accumulation changes significantly across the basin due to complex geological history. Therefore, a single section can't be considered representative for the whole basin. This study aims at bridging this gap by performing petroleum system modeling along a N-S section and provides new insights on source rock maturation, generation and migration of the hydrocarbons using 2D basin modeling. This study in conjunction with earlier work provides a 3D context of petroleum system modeling in the Ghadames basin. Hydrocarbon generation from the lower Silurian Tanezzuft formation and the Upper Devonian Aouinet Ouenine started during the late Carboniferous. However, high subsidence rate during middle to late Cretaceous and elevated heat flow in Cenozoic had maximum impact on source rock transformation and hydrocarbon generation whereas large-scale uplift and erosion during Alpine orogeny has significant impact on migration and accumulation. Visible migration observed along faults, which reactivated during Austrian unconformity. Peak hydrocarbon expulsion reached during Oligocene for both the Tanezzuft and the Aouinet Ouenine source rocks. Based on modeling results, capillary entry pressure driven downward expulsion of hydrocarbons from the lower Silurian Tanezzuft formation to the underlying Bir Tlacsin formation observed during middle Cretaceous. Kinetic modeling has helped to model hydrocarbon composition and distribution of generated hydrocarbons from both the source rocks. Application of source to reservoir tracking technology suggest some accumulations at shallow stratigraphic level has received hydrocarbons from both the Tanezzuft and Aouinet Ouenine source rocks, implying charge mixing. Five petroleum systems identified based on source to reservoir correlation technology in Petromod*. This Study builds upon the original work of Underdown and Redfern, 2008 and offers new insights and interpretation of the data.

New insights into Arctic paleogeography and tectonics from U-Pb detrital zircon geochronology

USGS Publications Warehouse

Miller, E.L.; Toro, J.; Gehrels, G.; Amato, J.M.; Prokopiev, A.; Tuchkova, M.I.; Akinin, V.V.; Dumitru, T.A.; Moore, Thomas E.; Cecile, M.P.

2006-01-01

To test existing models for the formation of the Amerasian Basin, detrital zircon suites from 12 samples of Triassic sandstone from the circum-Arctic region were dated by laser ablation-inductively coupled plasma-mass spectrometry (ICP-MS). The northern Verkhoyansk (NE Russia) has Permo-Carboniferous (265-320 Ma) and Cambro-Silurian (410-505 Ma) zircon populations derived via river systems from the active Baikal Mountain region along the southern Siberian craton. Chukotka, Wrangel Island (Russia), and the Lisburne Hills (western Alaska) also have Permo-Carboniferous (280-330 Ma) and late Precambrian-Silurian (420-580 Ma) zircons in addition to Permo-Triassic (235-265 Ma), Devonian (340-390 Ma), and late Precambrian (1000-1300 Ma) zircons. These ages suggest at least partial derivation from the Taimyr, Siberian Trap, and/ or east Urals regions of Arctic Russia. The northerly derived Ivishak Formation (Sadlerochit Mountains, Alaska) and Pat Bay Formation (Sverdrup Basin, Canada) are dominated by Cambrian-latest Precambrian (500-600 Ma) and 445-490 Ma zircons. Permo-Carboniferous and Permo-Triassic zircons are absent. The Bjorne Formation (Sverdrup Basin), derived from the south, differs from other samples studied with mostly 1130-1240 Ma and older Precambrian zircons in addition to 430-470 Ma zircons. The most popular tectonic model for the origin of the Amerasian Basin involves counterclockwise rotation of the Arctic Alaska-Chukotka microplate away from the Canadian Arctic margin. The detrital zircon data suggest that the Chukotka part of the microplate originated closer to the Taimyr and Verkhoyansk, east of the Polar Urals of Russia, and not from the Canadian Arctic. Copyright 2006 by the American Geophysical Union.

Upper Paleozoic Marine Shale Characteristics and Exploration Prospects in the Northwestern Guizhong Depression, South China

NASA Astrophysics Data System (ADS)

Zhu, Zhenhong; Yao, Genshun; Lou, Zhanghua; Jin, Aimin; Zhu, Rong; Jin, Chong; Chen, Chao

2018-05-01

Multiple sets of organic-rich shales developed in the Upper Paleozoic of the northwestern Guizhong Depression in South China. However, the exploration of these shales is presently at a relatively immature stage. The Upper Paleozoic shales in the northwestern Guizhong Depression, including the Middle Devonian Luofu shale, the Nabiao shale, and the Lower Carboniferous Yanguan shale, were investigated in this study. Mineral composition analysis, organic matter analysis (including total organic carbon (TOC) content, maceral of kerogen and the vitrinite reflection (Ro)), pore characteristic analysis (including porosity and permeability, pore type identification by SEM, and pore size distribution by nitrogen sorption), methane isothermal sorption test were conducted, and the distribution and thickness of the shales were determined, Then the characteristics of the two target shales were illustrated and compared. The results show that the Upper Paleozoic shales have favorable organic matter conditions (mainly moderate to high TOC content, type I and II1 kerogen and high to over maturity), good fracability potential (brittleness index (BI) > 40%), multiple pore types, stable distribution and effective thickness, and good methane sorption capacity. Therefore, the Upper Paleozoic shales in the northern Guizhong Depression have good shale gas potential and exploration prospects. Moreover, the average TOC content, average BI, thickness of the organic-rich shale (TOC > 2.0 wt%) and the shale gas resources of the Middle Devonian shales are better than those of the Lower Carboniferous shale. The Middle Devonian shales have better shale gas potential and exploration prospects than the Lower Carboniferous shales.

A search for stratiform massive-sulfide exploration targets in Appalachian Devonian rocks; a case study using computer-assisted attribute-coincidence mapping

USGS Publications Warehouse

Wedow, Helmuth

1983-01-01

The empirical model for sediment-associated, stratiform, exhalative, massive-sulfide deposits presented by D. Large in 1979 and 1980 has been redesigned to permit its use in a computer-assisted search for exploration-target areas in Devonian rocks of the Appalachian region using attribute-coincidence mapping (ACM). Some 36 gridded-data maps and selected maps derived therefrom were developed to show the orthogonal patterns, using the 7-1/2 minute quadrangle as an information cell, of geologic data patterns relevant to the empirical model. From these map and data files, six attribute-coincidence maps were prepared to illustrate both variation in the application of ACM techniques and the extent of possible significant exploration-target areas. As a result of this preliminary work in ACM, four major (and some lesser) exploration-target areas needing further study and analysis have been defined as follows: 1) in western and central New York in the outcrop area of lowermost Upper Devonian rocks straddling the Clarendon-Linden fault; 2) in western Virginia and eastern West Virginia in an area largely coincident with the well-known 'Oriskany' Mn-Fe ores; 3) an area in West Virginia, Maryland, and Virginia along and nearby the trend of the Alabama-New York lineament of King and Zietz approximately between 38- and 40-degrees N. latitude; and 4) an area in northeastern Ohio overlying an area coincident with a significant thickness of Silurian salt and high modern seismic activity. Some lesser, smaller areas suggested by relatively high coincidence may also be worthy of further study.

Edgecliff reefs - Devonian temperate water carbonate deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wolosz, T.H.

1991-03-01

The Middle Devonian Edgecliff Member of the Onondaga Formation in New York and Ontario, Canada, is a coral-rich, reefy,' crinoidal grainstone/packstone. The reefs contain only rare stromatoporoids and are devoid of algae, having been constructed by a fauna of mound and thicket-forming branching colonial rugosans, and large sheet favositids that populated grainstone/packstone flank beds and banks. Despite the restricted fauna, the reefs display a variety of growth patterns. Rugosan mounds range in size from 2-3 m diameter by 1 m thick, up to 230 m diameter by 15 m thick. Composite structures consist of interbedded rugosan buildups and packstone/grainstone flanks,more » ranging from shield-shaped reefs (240 m diameter by 6 m thick) in which the rugosans occur only as thickets, to pinnacle reefs (up to 3 km diameter by 60 m thick) in which rugosan mounds are interbedded with crinoidal flanks. Geographic distribution of these reef types and analysis of surrounding facies suggests that reef growth pattern was controlled by water depth and local rate of subsidence. Despite superfacial resemblance to modern deep water ahermatypic coral mounds and thickets, abundant coral breakage and overturning, and erosion of at least one reef core during an intermediate stage of reef growth supports a shallow water origin of these reefs. It is suggested that the Edgecliff and its reefs represent an example of Devonian cool water carbonate deposition, a hypothesis supported by a trend of increasing stromatoporoid abundance westwards across New York (in the direction of the paleo-equator).« less

Stratigraphy of lower to middle Paleozoic rocks of northern Nevada and the Antler orogeny

USGS Publications Warehouse

Ketner, Keith B.

2013-01-01

Commonly accepted concepts concerning the lower Paleozoic stratigraphy of northern Nevada are based on the assumption that the deep-water aspects of Ordovician to Devonian siliceous strata are due to their origin in a distant oceanic environment, and their presence where we find them is due to tectonic emplacement by the Roberts Mountains thrust. The concept adopted here is based on the assumption that their deep-water aspects are the result of sea-level rise in the Cambrian, and all of the Paleozoic strata in northern Nevada are indigenous to that area. The lower part of the Cambrian consists mainly of shallow-water cross-bedded sands derived from the craton. The upper part of the Cambrian, and part of the Ordovician, consists mainly of deep-water carbonate clastics carried by turbidity currents from the carbonate shelf in eastern Nevada, newly constructed as a result of sea-level rise. Ordovician to mid-Devonian strata are relatively deep-water siliceous deposits, which are the western facies assemblage. The basal contact of this assemblage on autochthonous Cambrian rocks is exposed in three mountain ranges and is clearly depositional in all three. The western facies assemblage can be divided into distinct stratigraphic units of regional extent. Many stratigraphic details can be explained simply by known changes in sea level. Upper Devonian to Mississippian strata are locally and westerly derived orogenic clastic beds deposited disconformably on the western facies assemblage. This disconformity, clearly exposed in 10 mountain ranges, indicates regional uplift and erosion of the western facies assemblage and absence of local deformation. The disconformity represents the Antler orogeny.

Geology of the Aspen 15-minute quadrangle, Pitkin and Gunnison counties, Colorado

USGS Publications Warehouse

Bryant, Bruce

1979-01-01

The Aspen area, located 170 km southwest of Denver, Colo., lies at the intersection of the northeast-trending Colorado mineral belt and the west margin of the north-trending Sawatch uplift of Laramide age; it is within the southwest part of the northwest-trending late Paleozoic Eagle basin. Precambrian shales and graywackes, perhaps as old as 2 billion years (b.y.), were converted to sillimanite-bearing gneiss and muscovite-biotite schist 1.65-1.70 b.y. ago. They were deformed into northeast-plunging folds and were migmatized, and they were intruded by quartz diorite, porphyritic quartz monzonite, and granite. Muscovite-biotite quartz monzonite intruded this older Precambrian terrane about 1.45 b.y. ago and is the predominant Precambrian rock near Aspen. Uplift, some faulting, and much erosion occurred during the 900-million year (m.y.) interval between emplacement of the plutonic rocks and deposition of Upper Cambrian sediments. From Late Cambrian through Mississippian the region was part of a broad area alternately covered by shallow seas or occupied by low-lying land. Quartzite, dolomite, and limestone 200-320 m thick, comprising the Sawatch Quartzite and Peerless Formation (Cambrian), Manitou Dolomite (Ordovician), Chaffee Group (Mississippian(?) and Devonian), and Leadville Limestone (Mississippian) were deposited during this interval. After an hiatus during which soil formation and solution of the Leadville Limestone took place in the Late Mississippian, a thick sequence of marine and nonmarine clastic rocks was deposited in the newly developing Eagle basin during the late Paleozoic and early Mesozoic. Deposition of about 300 m of carbonaceous shale, limestone, dolomite, and minor siltstone and evaporite of the Belden Formation began in a shallow sea in Early and Middle Pennsylvanian time. Facies relations indicate that the northwest-trending Uncompahgre uplift southwest of Aspen, if present at that time, had very low relief. The overlying Middle Pennsylvanian Gothic Formation of Langenheim (1952) contains calcareous sandstone, siltstone, shale, limestone, and evaporite. Its clastic debris, significantly coarser than that in the Belden, signals the initial rise of the Uncompahgre uplift bordering the Eagle basin on the southwest; the Gothic here lacks the conglomerates and fossiliferous marine limestones found closer to the uplift. Red terrigenous clastic rocks and minor limestone and evaporite of the Maroon Formation as much as 3,200 m thick, deposited mainly in a fluvial flood-plain environment during the rest of the Pennsylvanian and the Early Permian, indicate withdrawal of the sea caused by further uplift of the Uncompahgre highland. Following an hiatus accompanied by local folding, the red conglomerate, sandstone, and siltstone of the State Bridge Formation (Late Permian and Early Triassic) was deposited in a fluvial-lacustrine environment adjacent to a much-expanded Uncompahgre uplift; a significant part of the State Bridge is material recycled from the Maroon Formation exposed to erosion on the flank of the uplift. The State Bridge, absent towards the south, becomes thicker and finer grained towards the north. The Chinle Formation (Late Triassic) rests with angular unconformity on the State Bridge Formation. The Chinle contains a basal discontinuous quartz-pebble conglomerate (Gartra Member) and is chiefly calcareous siltstone and limestone, with some beds of sandstone and conglomerate composed of fragments derived from the limestone beds. The Chinle was deposited on flood plains and in lakes by streams. Storms may have disrupted the sediments in the lakes producing the limestone pebble conglomerates. The lack of feldspar in the Chinle indicates that the nearby part of the Uncompahgre uplift was not a sediment source, or was covered by a deeply weathered feldspar-free mantle. The formation, absent towards the south, thickens toward the north. Thicknesses of the Maroon, State Bridge, and Ch

On the fossil faunas of the Upper Devonian: The Genesee section, New York

USGS Publications Warehouse

Williams, Henry Shaler

1887-01-01

I have the honor to transmit herewith for publication as a bulletin a second contribution to the study of Devonian paleontology, Bulletin No. 3, "On the Fossil Faunas of the Upper Devonian," having been designed as the first of a series of papers on the comparative paleontology of the Devonian and Carboniferous.In that paper I gave the results of a study of the section along the meridian of Ithaca and Cayuga Lake, running southward, which may be called the Cayuga section.In 1883 examination was made south along the meridian running through Genesee County, New York, into McKean County, Pennsylvania, where the Alton coal beds were reached. The general results of this survey were communicated to the Director of the United States Geological Survey and an abstract of my communication was published in Science, Vol. II, pp. 836, 837, December 28, 1883. The present paper is a detailed report of the study of the materials of this Genesee section.Since the field work was done several additional sections have been examined: in 1884, sections through Western New York (and adjoining Pennsylvania) from Chautauqua County westward and into Ohio as far as the meridian of Cleveland; and in 1885 the region between the Cayuga section and those of Delaware and Otsego Counties, as far as Oneonta, were examined. The materials are under investigation and will be reported upon as soon as their study is completed.The sections are made along meridians, in order to make them more readily and simply comparable. Each long meridional section runs through the same stratigraphical series of deposits and is made up of a series of small local sections, such as the individual outcrop of the rocks renders possible.It is not supposed that in any case these sections are exhaustive, but it is intended that so far as they go the relative position of the faunas in the sections shall be precise and the association of species in each horizon shall be given as it is, so that the faunas can be identified, and thus, while they will leave much to be added, these studies, it is hoped, will give an outline of the geographical distribution and geological range of faunas and their species which will make a comparative study of the faunas possible.Respectfully yours, HENRY S. WILLIAMS.

Sea-level and environmental changes around the Devonian-Carboniferous boundary in the Namur-Dinant Basin (S Belgium, NE France): A multi-proxy stratigraphic analysis of carbonate ramp archives and its use in regional and interregional correlations

NASA Astrophysics Data System (ADS)

Kumpan, Tomáš; Bábek, Ondřej; Kalvoda, Jiří; Matys Grygar, Tomáš; Frýda, Jiří

2014-08-01

The paper focuses on high-resolution multidisciplinary research on three Devonian-Carboniferous boundary sections in shallow-water carbonate rocks in the Namur-Dinant Basin (Belgium, France). The aim of the study is to provide palaeo-environmental reconstructions and correlations supported by several independent quantitative proxies. We describe several correlative horizons and provide their sequence-stratigraphic interpretation based on facies analysis, spectral gamma-ray data, element concentrations (XRF) and δ13Ccarb, with foraminifer-biostratigraphy age control. The most prominent surface is a basal surface of forced regression, which is indicated by a sharp basinwards facies shift and a drop in clay-gamma-ray values and Al concentrations at the base of the Hastière and Avesnelles formations in more distal settings. In proximal settings, this surface merges with a hiatus at the Devonian-Carboniferous boundary inferred from foraminifer biostratigraphy. This hiatus can be correlated with the global Hangenberg sandstone event, which indicates a glacioeustatic sea-level fall. Increasing values of Zr/Al, K/Al, Sr/Al and Mn/Al coincide with the proximal facies of the falling stage system tract and lowstand system tract in the Hastière and Avesnelles formations as a consequence of the enhanced input of siliciclastics and nutrients during low sea levels. The top of the middle Hastière member is interpreted as the maximum regression surface, which is overlain by transgressive system tract of the upper Hastière member. The patterns of gamma-ray, δ13Ccarb, Th/K, Al and Zr/Al curves are well correlated between the studied sections. The δ13Ccarb excursions are correlated with the unnamed excursion in the Upper expansa conodont zone (Carnic Alps) and with the global Hangenberg event s.l. excursion in the kockeli conodont zone. This sequence-stratigraphic framework is used for correlations with deltaic successions from the Tafilalt Basin, Morocco. The basal surface of the forced regression equivalent to the Hangenberg sandstone event, which is typical for deeper-water settings, is easily recognisable and correlatable with gaps in more-shallow water settings. We suggest that it should be taken into account as a possible candidate for the “natural solution” of the Devonian-Carboniferous boundary in discussions concerning its redefinition.

Geologic controls on cave development in Burnsville Cove, Bath and Highland Counties, Virginia

USGS Publications Warehouse

Swezey, Christopher; Haynes, John T.; Lucas, Philip C.; Lambert, Richard A.

2017-01-01

Burnsville Cove in Bath and Highland Counties (Virginia, USA) is a karst region in the Valley and Ridge Province of the Appalachian Mountains. The region contains many caves in Silurian to Devonian limestone, and is well suited for examining geologic controls on cave location and cave passage morphology. In Burnsville Cove, many caves are located preferentially near the axes of synclines and anticlines. For example, Butler Cave is an elongate cave where the trunk channel follows the axis of Sinking Creek syncline and most of the side passages follow joints at right angles to the syncline axis. In contrast, the Water Sinks Subway Cave, Owl Cave, and Helictite Cave have abundant maze patterns, and are located near the axis of Chestnut Ridge anticline. The maze patterns may be related to fact that the anticline axis is the site of the greatest amount of flexure, leading to more joints and (or) greater enlargement of joints. Many of the larger caves of Burnsville Cove (e.g., Breathing Cave, Butler Cave–Sinking Creek Cave System, lower parts of the Water Sinks Cave System) are developed in the Silurian Tonoloway Limestone, the stratigraphic unit with the greatest surface exposure in the area. Other caves are developed in the Silurian to Devonian Keyser Limestone of the Helderberg Group (e.g., Owl Cave, upper parts of the Water Sinks Cave System) and in the Devonian Shriver Chert and (or) Licking Creek Limestone of the Helderberg Group (e.g., Helictite Cave). Within the Tonoloway Limestone, the larger caves are developed in the lower member of the Tonoloway Limestone immediately below a bed of silica-cemented sandstone. In contrast, the larger caves in the Keyser Limestone are located preferentially in limestone beds containing stromatoporoid reefs, and some of the larger caves in the Licking Creek Limestone are located in beds of cherty limestone below the Devonian Oriskany Sandstone. Geologic controls on cave passage morphology include joints, bedding planes, and folds. The influence of joints results in tall and narrow cave passages, whereas the influence of bedding planes results in cave passages with flat ceilings and (or) floors. The influence of folds is less common, but a few cave passages follow fold axes and have distinctive arched ceilings.

Nature and regional significance of unconformities associated with the Middle Ordovician Hagan K-bentonite complex in the North American midcontinent

USGS Publications Warehouse

Kolata, Dennis R.; Huff, W.D.; Bergstrom, Stig M.

1998-01-01

Stratal patterns of the Middle Ordovician Hagan K-bentonite complex and associated rocks show that the Black River-Trenton unconformity in the North American midcontinent formed through the complex interplay of eustasy, sediment accumulation rates, siliciclastic influx, bathymetry, seawater chemistry, and perhaps local tectonic uplift. The unconformity is diachronous and is an amalgamated surface that resulted from local late Turinian lowstand exposure followed by regional early Chatfieldian transgressive drowning and sediment starvation. The duration of the unconformity is greatest in southern Wisconsin, northern Illinois, and northern Indiana, where the Deicke and Millbrig K-bentonite Beds converge at the unconformity. On the basis of published isotopic ages for the Deicke and Millbrig beds, it is possible that in these regions erosion and non-deposition spanned a period of as much as 3.2 m.y. Two broad coeval depositional settings are recognized within the North American midcontinent during early Chatfieldian time. 1) An inner shelf, subtidal facies of fossiliferous shale (Spechts Ferry Shale Member and Ion Shale Member of the Decorah Formation) and argillaceous lime mudstone and skeletal wackestone (Guttenberg and Kings Lake Limestone Members) extended from the Canadian shield and Transcontinental arch southeastward through Minnesota, Wisconsin, Iowa, and Missouri. 2) A seaward, relatively deep subtidal, sediment-starved, middle shelf extended eastward from the Mississippi Valley region to the Taconian foreland basins in the central and southern Appalachians and southward through the pericratonic Arkoma and Black Warrior basins. In the inner shelf region, the Black River-Trenton unconformity is a composite of at least two prominent hardground omission surfaces, one at the top of the Castlewood and Carimona Limestone Members and the other at the top of the Guttenberg and Kings Lake Limestone Members, both merging to a single surface in the middle shelf region. The inner and middle shelves redeveloped later in approximately the same regions during Devonian and Mississippian time.

Geochronology of Zircon in Eclogite Reveals Imbrication of the Ultrahigh-Pressure Western Gneiss Region of Norway.

NASA Astrophysics Data System (ADS)

Young, D. J.; Kylander-Clark, A. R.; Root, D. B.

2014-12-01

Eclogite provides the only record of kinematic events at the deepest levels of orogens. Integrating the U-Pb geochronology and trace element chemistry of zircon in eclogite reveals the most complete view of the PTt history, yet low concentrations of uranium and zirconium and drier compositions that hinder zircon growth at peak conditions render it a challenging rocktype for this approach. The iconic Western Gneiss Region (WGR) in Norway is one of the largest terranes of deeply subducted continental rocks in the world, and contains many indicators of ultrahigh-pressure metamorphic conditions (P>2.8 GPa) that developed during the Siluro-Devonian Caledonian Orogeny. A metamorphic transition from amphibolite-facies to ultrahigh-pressure eclogite facies broadly coincides with a km-scale shear zone that underlies the majority of the WGR. A critical unknown is the timing of movement on this feature, which emplaced allochthonous units above the Baltica basement, but might also have accommodated late-orogenic exhumation of the WGR from mantle depths. We carried out laser ablation split-stream ICPMS (LASS) and selected multigrain TIMS analyses of zircons from eleven eclogites across the southern WGR, of which eight are located within or above the shear zone. LASS spots on polished grains mostly yield weakly discordant Proterozoic intrusive ages, and often minimal indication of a Caledonian (U)HP metamorphic overprint. Direct ablation into unpolished zircon reveals thin rims of Caledonian age in some cases. Overall, the dataset shows that all samples began zircon growth at approximately the same time (ca. 430-420 Ma). Eclogite from lower levels of the shear zone does not contain any dates younger than ca. 410 Ma, however, while eclogite from higher levels continued growth until ca. 400 Ma. We interpret this to result from thrusting of the WGR above cooler basement after 410 Ma, terminating new zircon crystallization within the shear zone but allowing limited further growth in rocks above.

Devonian to Carboniferous collision in the Greenland Caledonides: U-Pb zircon and Sm-Nd ages of high-pressure and ultrahigh-pressure metamorphism

NASA Astrophysics Data System (ADS)

Gilotti, Jane A.; Nutman, Allen P.; Brueckner, Hannes K.

2004-10-01

A variety of eclogites from an east-west transect across the North-East Greenland eclogite province have been studied to establish the timing of high pressure (HP) and ultrahigh-pressure (UHP) metamorphism in this northern segment of the Laurentian margin. Garnet + omphacite ± amphibole + whole rock Sm-Nd isochrons from a quartz eclogite, a garnet + omphacite + rutile eclogite and a partially melted zoisite eclogite in the western HP belt are 401±2, 402±9 and 414±18 Ma, respectively. Corresponding sensitive high-resolution ion microprobe (SHRIMP) 206Pb/238U ages of metamorphic zircon in the same samples are 401±7, 414±13, and 393 ±10 Ma. Metamorphic zircon domains were identified using morphology, cathodoluminescence (CL) imaging, U, Th, Th/U and trace element contents. Zircon from the quartz eclogite and the garnet + omphacite + rutile eclogite are typical of eclogite facies zircon with rounded to subhedral shapes, patchy to homogenous CL domains, low U, and very low Th and Th/U. The partially melted eclogite contains euhedral zircons with dark, sector-zoned, higher U, Th and Th/U inherited cores. Three cores give a Paleoproterozoic 207Pb/206Pb age of 1,962±27 Ma, interpreted as the age of the leucogabbroic protolith. CL images of the bright overgrowths show faint oscillatory zoning next to homogenous areas that indicate zircon growth in the presence of a HP melt and later recrystallization. Additional evidence that zircon grew during eclogite facies conditions is the lack of a Eu anomaly in the trace element data for all the samples. These results, combined with additional less precise Sm-Nd ages and our earlier work, point to a Devonian age of HP metamorphism in the western and central portions of the eclogite province. An UHP kyanite eclogite from the eastern part of the transect contains equant metamorphic zircon with homogeneous to patchy zoning in CL and HP inclusions of garnet, omphacite and kyanite. These zircons have slightly higher U, Th and Th/U values than the HP ones, no Eu anomaly, and are thus comparable to UHP zircons in the literature. The 206Pb/238U age of these zircons is 360±5 Ma, much younger than the HP eclogites. The same sample gives a Sm-Nd age of 342±6 Ma. Unlike the HP eclogites, the Sm-Nd age of the UHP rock is ca. 20 Ma younger than the U-Pb zircon age and most likely records slow cooling through the closure temperature, since peak temperatures were in excess of 900°C. Widespread HP metamorphism of both the Laurentian and Baltica continental margins marks the culmination of this continent continent collision in the Devonian. Carboniferous UHP conditions, though localized in the east, suggest a prolonged collisional history rather than a short-lived Scandian orogeny. The traditional Silurian Scandian orogeny should thus be extended through the Devonian.

An alternative hypothesis for the mid-Paleozoic Antler orogeny in Nevada

USGS Publications Warehouse

Ketner, Keith B.

2012-01-01

A great volume of Mississippian orogenic deposits supports the concept of a mid-Paleozoic orogeny in Nevada, and the existence and timing of that event are not questioned here. The nature of the orogeny is problematic, however, and new ideas are called for. The cause of the Antler orogeny, long ascribed to plate convergence, is here attributed to left-lateral north-south strike-slip faulting in northwestern Nevada. The stratigraphic evidence originally provided in support of an associated regional thrust fault, the Roberts Mountains thrust, is now known to be invalid, and abundant, detailed map evidence testifies to post-Antler ages of virtually all large folds and thrust faults in the region. The Antler orogeny was not characterized by obduction of the Roberts Mountains allochthon; rocks composing the "allochthon" essentially were deposited in situ. Instead, the orogeny was characterized by appearance of an elongate north-northeast-trending uplift through central Nevada and by two parallel flanking depressions. The eastern depression was the Antler foreland trough, into which sediments flowed from both east and west in the Mississippian. The western depression was the Antler hinterland trough into which sediments also flowed from both east and west during the Mississippian. West of the hinterland trough, across a left-lateral strike-slip fault, an exotic landmass originally attached to the northwestern part of the North American continent was moved southward 1700 km along a strike-slip fault. An array of isolated blocks of shelf carbonate rocks, long thought to be autochthonous exposures in windows of the Roberts Mountains allochthon, is proposed here as an array of gravity-driven slide blocks dislodged from the shelf, probably initiated by the Late Devonian Alamo impact event.

Uncoupled O and Hf isotopic systems in zircon from the contrasting granite suites of the New England Orogen, eastern Australia: Implications for studies of Phanerozoic magma genesis

NASA Astrophysics Data System (ADS)

Jeon, Heejin; Williams, Ian S.; Bennett, Vickie C.

2014-12-01

The Permo-Triassic granites of the New England Orogen, eastern Australia, were emplaced into a volcanic arc complex accreted to the eastern Gondwana margin in the Late Devonian or Early Carboniferous. Zircon U-Pb dating shows that the S-type Hillgrove (∼297 Ma) and Bundarra (∼287 Ma) Supersuites predated intrusion of the I-type Moonbi Supersuite (∼250 Ma) by up to 50 Ma. The high δ18Ozrn of the S-type granites (10.0-11.5‰), and range of U-Pb ages (∼370-300 Ma) and δ18Ozrn (∼5-10‰) of their inherited zircon cores, show that their source rocks were predominantly weathered Carboniferous volcaniclastics, the youngest deposited < 25 Ma before the granites were emplaced. In contrast, the lower δ18Ozrn (6.9-7.8‰) and lack of inheritance in the I-type granites is consistent with a zircon poor, more juvenile source, probably a mafic igneous underplate mixed with a small amount of volcanogenic and/or oceanic sediment. Despite the differences in source materials, the εHf(t) values of all granites, both S- and I-type, are similar (+5.0 ± 0.5 cf. +5.9 ± 0.5), consistent with both the mafic and sedimentary components in the granite sources being relatively young and similar in Hf isotopic composition at the time of granite genesis. In young, isotopically juvenile orogens, the O isotopic composition of well-dated igneous and inherited zircon can be a much more sensitive indicator of petrogenetic processes than the zircon Hf isotopic compositions alone.

Lunar and Planetary Science XXXVI, Part 18

NASA Technical Reports Server (NTRS)

2005-01-01

Topics discussed include: PoDS: A Powder Delivery System for Mars In-Situ Organic, Mineralogic and Isotopic Analysis Instruments Planetary Differentiation of Accreting Planetesimals with 26Al and 60Fe as the Heat Sources Ground-based Observation of Lunar Surface by Lunar VIS/NIR Spectral Imager Mt. Oikeyama Structure: First Impact Structure in Japan? Central Mounds in Martian Impact Craters: Assessment as Possible Perennial Permafrost Mounds (Pingos) A Further Analysis of Potential Photosynthetic Life on Mars New Insight into Valleys-Ocean Boundary on Mars Using 128 Pixels per Degree MOLA Data: Implication for Martian Ocean and Global Climate Change; Recursive Topography Based Surface Age Computations for Mars: New Insight into Surficial Processes That Influenced Craters Distribution as a Step Toward the Formal Proof of Martian Ocean Recession, Timing and Probability; Laser-induced Breakdown Spectroscopy: A New Method for Stand-Off Quantitative Analysis of Samples on Mars; Milk Spring Channels Provide Further Evidence of Oceanic, >1.7-km-Deep Late Devonian Alamo Crater, Southern Nevada; Exploration of Martian Polar Residual Caps from HEND/ODYSSEY Data; Outflow Channels Influencing Martian Climate: Global Circulation Model Simulations with Emplaced Water; Presence of Nonmethane Hydrocarbons on Pluto; Difference in Degree of Space Weathering on the Newborn Asteroid Karin; Circular Collapsed Features Related to the Chaotic Terrain Formation on Mars; A Search for Live (sup 244)Pu in Deep-Sea Sediments: Preliminary Results of Method Development; Some Peculiarities of Quartz, Biotite and Garnet Transformation in Conditions of Step-like Shock Compression of Crystal Slate; Error Analysis of Remotely-Acquired Mossbauer Spectra; Cloud Activity on Titan During the Cassini Mission; Solar Radiation Pressure and Transient Flows on Asteroid Surfaces; Landing Site Characteristics for Europa 1: Topography; and The Crop Circles of Europa.

Geology and mineral deposits of the Minnie Moore and Bullion mineralized areas, Blaine County, Idaho

USGS Publications Warehouse

Link, Paul Karl; Worl, Ronald G.

2001-01-01

In the early 1880?s the discovery of rich ores in the Minnie Moore and Bullion mineralized areas sparked a rush to settle and develop the Wood River valley. Silver and lead discoveries in these areas spurred the boom in mining after completion of the Oregon Short Line Railroad to Hailey in 1883. In both areas the ore comprises galena, sphalerite, and tetrahedrite in a gangue of siderite, calcite, or quartz. Minor goldbearing quartz veins are also present. The ore is in fissure and replacement veins along fracture systems that formed in Late Cretaceous time, after intrusion of nearby granodiorite or quartz diorite stocks. The ore formed under mesothermal conditions and heat was supplied by the nearby plutons. In the Minnie Moore area, the mineralized veins are cut by low-angle normal faults that are of probable Eocene age. In the Minnie Moore mineralized area, the host rock is the middle part of the Devonian Milligen Formation, (the informal Lucky Coin limestone and Triumph argillite), which is the same stratigraphic level as the host ore in the rich Triumph mine northeast of Hailey. In the Bullion mineralized area, the ore is hosted by the lower member of the Middle Pennsylvanian to Lower Permian Dollarhide Formation. Rich ore was mined in several tunnels that reached the Mayflower vein, a northwest-striking mineralized shear zone. The deposits are thought to be mainly mesothermal veins that formed in association with Cretaceous magmatism. The syngenetic stratiform model of ore formation has often been applied to these deposits, however, no evidence of syngenetic mineralization was found in this study. Faulting has displaced most of the major orebodies and thus has made mining these deposits a challenge.

Phylogeny of Selaginellaceae: There is value in morphology after all!

PubMed

Weststrand, Stina; Korall, Petra

2016-12-01

The cosmopolitan lycophyte family Selaginellaceae, dating back to the Late Devonian-Early Carboniferous, is notorious for its many species with a seemingly undifferentiated gross morphology. This morphological stasis has for a long time hampered our understanding of the evolutionary history of the single genus Selaginella. Here we present a large-scale phylogenetic analysis of Selaginella, and based on the resulting phylogeny, we discuss morphological evolution in the group. We sampled about one-third of the approximately 750 recognized Selaginella species. Evolutionary relationships were inferred from both chloroplast (rbcL) and single-copy nuclear gene data (pgiC and SQD1) using a Bayesian inference approach. The morphology of the group was studied and important features mapped onto the phylogeny. We present an overall well-supported phylogeny of Selaginella, and the phylogenetic positions of some previously problematic taxa (i.e., S. sinensis and allies) are now resolved with strong support. We show that even though the evolution of most morphological characters involves reversals and/or parallelisms, several characters are phylogenetically informative. Seven major clades are identified, which each can be uniquely diagnosed by a suite of morphological features. There is value in morphology after all! Our hypothesis of the evolutionary relationships of Selaginella is well founded based on DNA sequence data, as well as morphology, and is in line with previous findings. It will serve as a firm basis for further studies on Selaginella with respect to, e.g., the poorly known alpha taxonomy, as well as evolutionary questions such as historical biogeographic reconstructions. © 2016 Weststrand and Korall. Published by the Botanical Society of America. This work is licensed under a Creative Commons Attribution License (CC-BY 4.0).

Geochemistry of formation waters from the Wolfcamp and “Cline” shales: Insights into brine origin, reservoir connectivity, and fluid flow in the Permian Basin, USA

USGS Publications Warehouse

Engle, Mark A.; Reyes, Francisco R.; Varonka, Matthew S.; Orem, William H.; Lin, Ma; Ianno, Adam J.; Westphal, Tiffani M.; Xu, Pei; Carroll, Kenneth C.

2016-01-01

Despite being one of the most important oil producing provinces in the United States, information on basinal hydrogeology and fluid flow in the Permian Basin of Texas and New Mexico is lacking. The source and geochemistry of brines from the basin were investigated (Ordovician- to Guadalupian-age reservoirs) by combining previously published data from conventional reservoirs with geochemical results for 39 new produced water samples, with a focus on those from shales. Salinity of the Ca–Cl-type brines in the basin generally increases with depth reaching a maximum in Devonian (median = 154 g/L) reservoirs, followed by decreases in salinity in the Silurian (median = 77 g/L) and Ordovician (median = 70 g/L) reservoirs. Isotopic data for B, O, H, and Sr and ion chemistry indicate three major types of water. Lower salinity fluids (<70 g/L) of meteoric origin in the middle and upper Permian hydrocarbon reservoirs (1.2–2.5 km depth; Guadalupian and Leonardian age) likely represent meteoric waters that infiltrated through and dissolved halite and anhydrite in the overlying evaporite layer. Saline (>100 g/L), isotopically heavy (O and H) water in Leonardian [Permian] to Pennsylvanian reservoirs (2–3.2 km depth) is evaporated, Late Permian seawater. Water from the Permian Wolfcamp and Pennsylvanian “Cline” shales, which are isotopically similar but lower in salinity and enriched in alkalis, appear to have developed their composition due to post-illitization diffusion into the shales. Samples from the “Cline” shale are further enriched with NH4, Br, I and isotopically light B, sourced from the breakdown of marine kerogen in the unit. Lower salinity waters (<100 g/L) in Devonian and deeper reservoirs (>3 km depth), which plot near the modern local meteoric water line, are distinct from the water in overlying reservoirs. We propose that these deep meteoric waters are part of a newly identified hydrogeologic unit: the Deep Basin Meteoric Aquifer System. Chemical, isotopic, and pressure data suggest that despite over-pressuring in the Wolfcamp shale, there is little potential for vertical fluid migration to the surface environment via natural conduits.

Geology and undiscovered resource assessment of the potash-bearing Pripyat and Dnieper-Donets Basins, Belarus and Ukraine

USGS Publications Warehouse

Cocker, Mark D.; Orris, Greta J.; Dunlap, Pamela; Lipin, Bruce R.; Ludington, Steve; Ryan, Robert J.; Słowakiewicz, Mirosław; Spanski, Gregory T.; Wynn, Jeff; Yang, Chao

2017-08-03

Undiscovered potash resources in the Pripyat Basin, Belarus, and Dnieper-Donets Basin, Ukraine, were assessed as part of a global mineral resource assessment led by the U.S. Geological Survey (USGS). The Pripyat Basin (in Belarus) and the Dnieper-Donets Basin (in Ukraine and southern Belarus) host stratabound and halokinetic Upper Devonian (Frasnian and Famennian) and Permian (Cisuralian) potash-bearing salt. The evaporite basins formed in the Donbass-Pripyat Rift, a Neoproterozoic continental rift structure that was reactivated during the Late Devonian and was flooded by seawater. Though the rift was divided, in part by volcanic deposits, into the separate Pripyat and Dnieper-Donets Basins, both basins contain similar potash‑bearing evaporite sequences. An Early Permian (Cisuralian) sag basin formed over the rift structure and was also inundated by seawater resulting in another sequence of evaporite deposition. Halokinetic activity initiated by basement faulting during the Devonian continued at least into the Permian and influenced potash salt deposition and structural evolution of potash-bearing salt in both basins.Within these basins, four areas (permissive tracts) that permit the presence of undiscovered potash deposits were defined by using geological criteria. Three tracts are permissive for stratabound potash-bearing deposits and include Famennian (Upper Devonian) salt in the Pripyat Basin, and Famennian and Cisuralian (lower Permian) salt in the Dnieper-Donets Basin. In addition, a tract was delineated for halokinetic potash-bearing Famennian salt in the Dnieper-Donets Basin.The Pripyat Basin is the third largest source of potash in the world, producing 6.4 million metric tons of potassium chloride (KCl) (the equivalent of about 4.0 million metric tons of potassium oxide or K2O) in 2012. Potash production began in 1963 in the Starobin #1 mine, near the town of Starobin, Belarus, in the northwestern corner of the basin. Potash is currently produced from six potash mines in the Starobin area. Published reserves in the Pripyat Basin area are about 7.3 billion metric tons of potash ore (about 1.3 billion metric tons of K2O) mostly from potash-bearing salt horizons in the Starobin and Petrikov mine areas. The 15,160-square-kilometer area of the Pripyat Basin underlain by Famennian potash-bearing salt contains as many as 60 known potash-bearing salt horizons. Rough estimates of the total mineral endowment associated with stratabound Famennian salt horizons in the Pripyat Basin range from 80 to 200 billion metric tons of potash-bearing salt that could contain 15 to 30 billion metric tons of K2O.Parameters (including the number of economic potash horizons, grades, and depths) for these estimates are not published so the estimates are not easily confirmed. Historically, reserves have been estimated above a depth of 1,200 meters (m) (approximately the depths of conventional underground mining). Additional undiscovered K2O resources could be significantly greater in the remainder of the Fammenian salt depending on the extents and grades of the 60 identified potash horizons above the USGS assessment depth of 3,000 m in the remainder of the tract. Increasing ambient temperatures with increasing depths in the eastern parts of the Pripyat Basin may require a solution mining process which is aided by higher temperatures.No resource or reserve data have been published and little is known about stratabound Famennian and Frasnian salt in the Dnieper-Donets Basin. These Upper Devonian salt units dip to the southeast and extend to depths of 15–19 kilometers (km) or greater. The tract of stratabound Famennian salt that lies above a depth of 3 km, the depth above which potash is technically recoverable by solution mining, underlies an area of about 15,600 square kilometers (km2). If Upper Devonian salt units in the Dnieper-Donets Basin contain potash-bearing strata similar to salt of the same age in the Pripyat Basin, then the stratabound Famennian tract in the Dnieper-Donets Basin could contain significant undiscovered potash resources.The Cisuralian evaporite sequence in the Dnieper-Donets Basin consists of 10 evaporite cycles with the upper 3 cycles containing potash-bearing salt (mainly as sylvite and carnallite) in several subbasins and polyhalite in the sulfate bearing parts of the identified tract. The area of the Cisuralian tract is 62,700 km2. Potash-bearing cycles are as much as 40 m thick. One subbasin is reported to contain 794 million metric tons of “raw or crude” potash-bearing salt which could contain 50 to 150 million metric tons of K2O, depending on the grade. Undiscovered potash resources in the remainder of this permissive tract may be significantly greater. Depths to the Permian salt range from less than 100 to about 1,500 m.Undiscovered resources of halokinetic potash-bearing salt in the Dnieper-Donets Basin were assessed quantitatively for this study by using the standard USGS three-part form of mineral resource assessment (Singer, 2007a; Singer and Menzie, 2010). Delineation of the permissive tract was based on distributions of mapped halokinetic salt structures. This tract contains at least 248 diapiric salt structures with a total area of 7,840 km2 that occupies approximately 8 percent of the basin area. The vertical extent of these salt structures is hundreds of meters to several kilometers. This assessment estimated that a total mean of 11 undiscovered deposits contain an arithmetic mean estimate of about 840 million metric tons of K2O in the halokinetic salt structures of the Dnieper-Donets Basin for which the probabilistic estimate was made.

Geochronology and geochemistry of the Borohoro pluton in the northern Yili Block, NW China: Implication for the tectonic evolution of the northern West Tianshan orogen

NASA Astrophysics Data System (ADS)

Wang, Meng; Zhang, Jinjiang; Zhang, Bo; Liu, Kai; Chen, Youxin; Zheng, Yanrong

2018-03-01

The closure of the North Tianshan Ocean between the Junggar Terrane and the Yili Block is a longtime debated issue in literature, because of the different understanding of the Carboniferous volcanic rocks in the northern margin of the Yili Block. This study presents new geochronological and whole-rock geochemical data for the granitic rocks from the Borohoro pluton to provide constraints on the tectonic regime for the northern West Tianshan during the Carboniferous. LA-ICP-MS U-Pb dating results reveal two magmatic phases for the Borohoro pluton. The former magmatic activity in the Early Carboniferous formed the fine-grained granodiorite (332 Ma). The later magmatic activity occurred during the Late Carboniferous (305-300 Ma), forming a diversity of granitic rocks, involving quartz diorite, granodiorite and granite. Geochemical and mineralogical studies reveal that the studied granitic rocks from the Borohoro pluton all belong to metaluminous to weakly peraluminous, calc-alkaline I-type granites. They are characterized by enrichment in LILEs relative to HFSEs, and depletion of Nb, Ti and P, typical of continental arc-type granites. The intermediate SiO2, high Al2O3, and relatively low Fe2O3T, MgO and TiO2 contents reflect that these granitic rocks are mainly crust-derived. But the high Mg# values for most samples and the occurrence of microgranular mafic enclaves indicate that their magma sources were mixed by mantle-derived components. Especially, the Late Carboniferous rocks define an elegant mixing trend in both the Rb-Rb/V and the 1/V-Rb/V diagrams, consistent with mixing between magmas from subcontinental lithospheric mantle and mafic lower crust. Taking into consideration of the facts that all the Devonian to Carboniferous granitoids belong to calc-alkaline I-type granites, and granitoids of A-type didn't appear until the Early Permian, we suggest that the subduction of the North Tianshan Ocean continued to the Late Carboniferous, generating the granitic rocks of the Borohoro pluton.

Discovering Fossils--A Hands-on Lab.

ERIC Educational Resources Information Center

Goldstein, Alan

2002-01-01

Describes fossil investigations developed and provided by the Falls of the Ohio State Park near Louisville, Kentucky. The Devonian shale beds contain representatives of over 600 species including corals, sponges, brachiopods, mollusks, and echinoderms. Rather than focusing on identification, the activities emphasize the past ecological…