Diffusion or advection? Mass transfer and complex boundary layer landscapes of the brown alga Fucus vesiculosus.

PubMed

Lichtenberg, Mads; Nørregaard, Rasmus Dyrmose; Kühl, Michael

2017-03-01

The role of hyaline hairs on the thallus of brown algae in the genus Fucus is long debated and several functions have been proposed. We used a novel motorized set-up for two-dimensional and three-dimensional mapping with O 2 microsensors to investigate the spatial heterogeneity of the diffusive boundary layer (DBL) and O 2 flux around single and multiple tufts of hyaline hairs on the thallus of Fucus vesiculosus. Flow was a major determinant of DBL thickness, where higher flow decreased DBL thickness and increased O 2 flux between the algal thallus and the surrounding seawater. However, the topography of the DBL varied and did not directly follow the contour of the underlying thallus. Areas around single tufts of hyaline hairs exhibited a more complex mass-transfer boundary layer, showing both increased and decreased thickness when compared with areas over smooth thallus surfaces. Over thallus areas with several hyaline hair tufts, the overall effect was an apparent increase in the boundary layer thickness. We also found indications for advective O 2 transport driven by pressure gradients or vortex shedding downstream from dense tufts of hyaline hairs that could alleviate local mass-transfer resistances. Mass-transfer dynamics around hyaline hair tufts are thus more complex than hitherto assumed and may have important implications for algal physiology and plant-microbe interactions. © 2017 The Author(s).

Diffusion or advection? Mass transfer and complex boundary layer landscapes of the brown alga Fucus vesiculosus

PubMed Central

Nørregaard, Rasmus Dyrmose

2017-01-01

The role of hyaline hairs on the thallus of brown algae in the genus Fucus is long debated and several functions have been proposed. We used a novel motorized set-up for two-dimensional and three-dimensional mapping with O2 microsensors to investigate the spatial heterogeneity of the diffusive boundary layer (DBL) and O2 flux around single and multiple tufts of hyaline hairs on the thallus of Fucus vesiculosus. Flow was a major determinant of DBL thickness, where higher flow decreased DBL thickness and increased O2 flux between the algal thallus and the surrounding seawater. However, the topography of the DBL varied and did not directly follow the contour of the underlying thallus. Areas around single tufts of hyaline hairs exhibited a more complex mass-transfer boundary layer, showing both increased and decreased thickness when compared with areas over smooth thallus surfaces. Over thallus areas with several hyaline hair tufts, the overall effect was an apparent increase in the boundary layer thickness. We also found indications for advective O2 transport driven by pressure gradients or vortex shedding downstream from dense tufts of hyaline hairs that could alleviate local mass-transfer resistances. Mass-transfer dynamics around hyaline hair tufts are thus more complex than hitherto assumed and may have important implications for algal physiology and plant–microbe interactions. PMID:28330986

Effect of particle momentum transfer on an oblique-shock-wave/laminar-boundary-layer interaction

NASA Astrophysics Data System (ADS)

Teh, E.-J.; Johansen, C. T.

2016-11-01

Numerical simulations of solid particles seeded into a supersonic flow containing an oblique shock wave reflection were performed. The momentum transfer mechanism between solid and gas phases in the shock-wave/boundary-layer interaction was studied by varying the particle size and mass loading. It was discovered that solid particles were capable of significant modulation of the flow field, including suppression of flow separation. The particle size controlled the rate of momentum transfer while the particle mass loading controlled the magnitude of momentum transfer. The seeding of micro- and nano-sized particles upstream of a supersonic/hypersonic air-breathing propulsion system is proposed as a flow control concept.

An Entrance Region Mass Transfer Experiment.

ERIC Educational Resources Information Center

Youngquist, G. R.

1979-01-01

This paper describes an experiment designed to reveal the consequences of the development of a concentration boundary layer. The rate of a mass transfer limited electrochemical reaction is measured and used to obtain the dependence of average Sherwood number on Reynolds number and entrance length. (Author/BB)

Suitability of the first-order mass transfer concept for describing cyclic diffusive mass transfer in stagnant zones

NASA Astrophysics Data System (ADS)

Griffioen, Jasper

1998-10-01

The concept of first-order mass transfer between mobile and immobile regions, which mathematically simplifies the concept of Fickian diffusion in stagnant areas, has often been used to describe physical nonequilibrium transport of solutes into natural porous media. This study compares the two concepts, using analytical expressions describing cyclic mass transfer into and out of stagnant layers. The results show that the first-order mass transfer concept cannot describe continuous diffusion into the immobile zone during period of net outward diffusion if the immobile zone has not filled completely during the period of net inward diffusion. This sets phenomenological limitations to the first-order mass transfer concept when short periods of relative time are involved; these limitations have to be compared with the practical limitations to the Fickian diffusion concept.

Effects of mass transfer on MHD three dimensional flow of a Prandtl liquid over a flat plate in the presence of chemical reaction

NASA Astrophysics Data System (ADS)

Ganesh Kumar, K.; Rizwan-ul-Haq; Rudraswamy, N. G.; Gireesha, B. J.

The present study addresses the three-dimensional flow of a Prandtl fluid over a Riga plate in the presence of chemical reaction and convective condition. The converted set of boundary layer equations are solved numerically by RKF four-fifth method. Obtained numerical results for flow and mass transfer characteristics are discussed for various physical parameters. Additionally, the skin friction coefficient and Sherwood number are also presented. It is found that, the momentum boundary layer thickness is dominant for higher values of α and solutal boundary layer is low for higher Schmidt number and chemical reaction parameter.

THE PROCESS OF MASS TRANSFER ON THE SOLID-LIQUID BOUNDARY LAYER DURING THE RELEASE OF DICLOFENAC SODIUM AND PAPAVERINE HYDROCHLORIDE FROM TABLETS IN A PADDLE APPARATUS.

PubMed

Kasperek, Regina; Zimmer, Lukasz; Poleszak, Ewa

2016-01-01

The release study of diclofenac sodium (DIC) and papaverine hydrochloride (PAP) from two formulations of the tablets in the paddle apparatus using different rotation speeds to characterize the process of mass transfer on the solid-liquid boundary layer was carried out. The dissolution process of active substances was described by values of mass transfer coefficients, the diffusion boundary layer thickness and dimensionless numbers (Sh and Re). The values of calculated parameters showed that the release of DIC and PAP from tablets comprising potato starch proceeded faster than from tablets containing HPMC and microcrystalline cellulose. They were obtained by direct dependencies between Sh and Re in the range from 75 rpm to 125 rpm for both substances from all tablets. The description of the dissolution process with the dimensionless numbers make it possible to plan the drug with the required release profile under given in vitro conditions.

DETERMINATION OF THE MASS TRANSFER CHARACTERIZATION OF A CERAMIC-POLYMER COMPOSITE MEMBRANE IN THE PERVAPORATION MODE

EPA Science Inventory

The effect of the coating layer thickness on VOC extraction performance of a ceramic polymer composite membrane has been investigated. It was found, under experimental condiitons representing typical field operation, the overall mass transfer rates of feed components were control...

Correlation of laboratory and production freeze drying cycles.

PubMed

Kuu, Wei Y; Hardwick, Lisa M; Akers, Michael J

2005-09-30

The purpose of this study was to develop the correlation of cycle parameters between a laboratory and a production freeze-dryer. With the established correlation, key cycle parameters obtained using a laboratory dryer may be converted to those for a production dryer with minimal experimental efforts. In order to develop the correlation, it was important to consider the contributions from the following freeze-drying components: (1) the dryer, (2) the vial, and (3) the formulation. The critical parameters for the dryer are the shelf heat transfer coefficient and shelf surface radiation emissivity. The critical parameters for the vial are the vial bottom heat transfer coefficients (the contact parameter Kcs and separation distance lv), and vial top heat transfer coefficient. The critical parameter of the formulation is the dry layer mass transfer coefficient. The above heat and mass transfer coefficients were determined by freeze-drying experiments in conjunction with mathematical modeling. With the obtained heat and mass transfer coefficients, the maximum product temperature, Tbmax, during primary drying was simulated using a primary drying subroutine as a function of the shelf temperature and chamber pressure. The required shelf temperature and chamber pressure, in order to perform a successful cycle run without product collapse, were then simulated based on the resulting values of Tbmax. The established correlation approach was demonstrated by the primary drying of the model formulation 5% mannitol solution. The cycle runs were performed using a LyoStar dryer as the laboratory dryer and a BOC Edwards dryer as the production dryer. The determined normalized dried layer mass transfer resistance for 5% mannitol is expressed as RpN=0.7313+17.19l, where l is the receding dry layer thickness. After demonstrating the correlation approach using the model formulation 5% mannitol, a practical comparison study was performed for the actual product, the lactate dehydrogenase (LDH) formulation. The determined normalized dried layer mass transfer resistance for the LDH formulation is expressed as RpN=4.344+10.85l. The operational templates Tbmax and primary drying time were also generated by simulation. The cycle run for the LDH formulation using the Edwards production dryer verified that the cycle developed in a laboratory freeze-dryer was transferable at the production scale.

Calculation of turbulent boundary layers with heat transfer and pressure gradient utilizing a compressibility transformation. Part 3: Computer program manual

NASA Technical Reports Server (NTRS)

Schneider, J.; Boccio, J.

1972-01-01

A computer program is described capable of determining the properties of a compressible turbulent boundary layer with pressure gradient and heat transfer. The program treats the two-dimensional problem assuming perfect gas and Crocco integral energy solution. A compressibility transformation is applied to the equation for the conservation of mass and momentum, which relates this flow to a low speed constant property flow with simultaneous mass transfer and pressure gradient. The resulting system of describing equations consists of eight ordinary differential equations which are solved numerically. For Part 1, see N72-12226; for Part 2, see N72-15264.

An analysis of a charring ablator with thermal nonequilibrium, chemical kinetics, and mass transfer

NASA Technical Reports Server (NTRS)

Clark, R. K.

1973-01-01

The differential equations governing the transient response of a one-dimensional ablative thermal protection system are presented for thermal nonequilibrium between the pyrolysis gases and the char layer and with finite rate chemical reactions occurring. The system consists of three layers (the char layer, the uncharred layer, and an optical insulation layer) with concentrated heat sinks at the back surface and between the second and third layers. The equations are solved numerically by using a modified implicit finite difference scheme to obtain solutions for the thickness of the charred and uncharred layers, surface recession and pyrolysis rates, solid temperatures, porosity profiles, and profiles of pyrolysis-gas temperature, pressure, composition, and flow rate. Good agreement is obtained between numerical results and exact solutions for a number of simplified cases. The complete numerical analysis is used to obtain solutions for an ablative system subjected to a constant heating environment. Effects of thermal, chemical, and mass transfer processes are shown.

Mathematical Investigation of Fluid Flow, Mass Transfer, and Slag-steel Interfacial Behavior in Gas-stirred Ladles

NASA Astrophysics Data System (ADS)

Cao, Qing; Nastac, Laurentiu

2018-06-01

In this study, the Euler-Euler and Euler-Lagrange modeling approaches were applied to simulate the multiphase flow in the water model and gas-stirred ladle systems. Detailed comparisons of the computational and experimental results were performed to establish which approach is more accurate for predicting the gas-liquid multiphase flow phenomena. It was demonstrated that the Euler-Lagrange approach is more accurate than the Euler-Euler approach. The Euler-Lagrange approach was applied to study the effects of the free surface setup, injected bubble size, gas flow rate, and slag layer thickness on the slag-steel interaction and mass transfer behavior. Detailed discussions on the flat/non-flat free surface assumption were provided. Significant inaccuracies in the prediction of the surface fluid flow characteristics were found when the flat free surface was assumed. The variations in the main controlling parameters (bubble size, gas flow rate, and slag layer thickness) and their potential impact on the multiphase fluid flow and mass transfer characteristics (turbulent intensity, mass transfer rate, slag-steel interfacial area, flow patterns, etc.,) in gas-stirred ladles were quantitatively determined to ensure the proper increase in the ladle refining efficiency. It was revealed that by injecting finer bubbles as well as by properly increasing the gas flow rate and the slag layer thickness, the ladle refining efficiency can be enhanced significantly.

Experimental research of solid waste drying in the process of thermal processing

NASA Astrophysics Data System (ADS)

Bukhmirov, V. V.; Kolibaba, O. B.; Gabitov, R. N.

2015-10-01

The convective drying process of municipal solid waste layer as a polydispersed multicomponent porous structure is studied. On the base of the experimental data criterial equations for calculating heat transfer and mass transfer processes in the layer, depending on the humidity of the material, the speed of the drying agent and the layer height are obtained. These solutions are used in the thermal design of reactors for the thermal processing of multicomponent organic waste.

Numerical modelling of transient heat and moisture transport in protective clothing

NASA Astrophysics Data System (ADS)

Łapka, P.; Furmański, P.; Wisniewski, T. S.

2016-01-01

The paper presents a complex model of heat and mass transfer in a multi-layer protective clothing exposed to a flash fire and interacting with the human skin. The clothing was made of porous fabric layers separated by air gaps. The fabrics contained bound water in the fibres and moist air in the pores. The moist air was also present in the gaps between fabric layers or internal fabric layer and the skin. Three skin sublayers were considered. The model accounted for coupled heat transfer by conduction, thermal radiation and associated with diffusion of water vapour in the clothing layers and air gaps. Heat exchange due to phase transition of the bound water were also included in the model. Complex thermal and mass transfer conditions at internal or external boundaries between fabric layers and air gaps as well as air gap and skin were assumed. Special attention was paid to modelling of thermal radiation which was coming from the fire, penetrated through protective clothing and absorbed by the skin. For the first time non-grey properties as well as optical phenomena at internal or external boundaries between fabric layers and air gaps as well as air gap and skin were accounted for. A series of numerical simulations were carried out and the risk of heat injures was estimated.

Heat and mass transfer in a dissociated laminar boundary layer of air with consideration of the finite rate of chemical reaction

NASA Technical Reports Server (NTRS)

Oyegbesan, A. O.; Algermissen, J.

1986-01-01

A numerical investigation of heat and mass transfer in a dissociated laminar boundary layer of air on an isothermal flat plate is carried out for different degrees of cooling of the wall. A finite-difference chemical model is used to study elementary reactions involving NO2 and N2O. The analysis is based on equations of continuity, momentum, energy, conservation and state for the two-dimensional viscous flow of a reacting multicomponent mixtures. Attention is given to the effects of both catalyticity and noncatalyticity of the wall.

Determination of mass and heat transfer parameters during freeze-drying cycles of pharmaceutical products.

PubMed

Hottot, A; Vessot, S; Andrieu, J

2005-01-01

The principal aim of this study was to evaluate the water vapour mass transfer resistance of the dried layer and the vial heat transfer coefficient values of a pharmaceutical product during the primary drying period. First, overall vial heat transfer coefficient values, Kv, were determined by a gravimetric method based on pure ice sublimation experiments. Thus, it was possible to set up a map of the total heat flux received by each vial throughout the plate surface of our pilot scale freeze-dryer. Important heterogeneities were observed for the vials placed at the plate edges and for the vials placed at the center of the plate. As well, the same gravimetric method was also used to precisely determine the influence of main lyophilization operating parameters (shelf temperature and gas total pressure) or the vial types and sizes on these overall heat transfer coefficient values. A semi-empirical relationship as a function of total gas pressure was proposed. The transient method by pressure rise analysis (PRA method) after interrupting the water vapour flow between the sublimation chamber and the condenser, previously set up and validated in our laboratory, was then extensively used with an amorphous BSA-based formulation to identify the dried layer mass transfer resistance values, Rp, the ice front temperature, and the total heat transfer coefficient values, Kv, with or without annealing treatment. It was proved that this method gave accurate and coherent data only during the first half of the sublimation period when the totality of the vials of the set was still sublimating. Thus, this rapid method allowed estimation of, on line and in situ, the sublimation front temperature and the characterization of the morphology and structure of the freeze-dried layer, all along the first part of the sublimation period. The estimated sublimation temperatures shown by the PRA model were about 2 degrees C lower than the experimental values obtained using thermocouples inserted inside the vial, in accordance with previous data given by this method for similar freeze-drying conditions. As well, by using this method we could confirm the homogenization of the dried layer porous structure by annealing treatment after the freezing step. Furthermore, frozen matrix structure analysis (mean pore diameter) using optical microscopy and mass transfer modelling of water vapour by molecular diffusion (Knudsen regime) allowed, in some cases, to predict the experimental values of this overall mass transfer resistance directly related to the freeze-dried cake permeability.

Convective mass transfer around a dissolving bubble

NASA Astrophysics Data System (ADS)

Duplat, Jerome; Grandemange, Mathieu; Poulain, Cedric

2017-11-01

Heat or mass transfer around an evaporating drop or condensing vapor bubble is a complex issue due to the interplay between the substrate properties, diffusion- and convection-driven mass transfer, and Marangoni effects, to mention but a few. In order to disentangle these mechanisms, we focus here mainly on the convective mass transfer contribution in an isothermal mass transfer problem. For this, we study the case of a millimetric carbon dioxide bubble which is suspended under a substrate and dissolved into pure liquid water. The high solubility of CO2 in water makes the liquid denser and promotes a buoyant-driven flow at a high (solutal) Rayleigh number (Ra˜104 ). The alteration of p H allows the concentration field in the liquid to be imaged by laser fluorescence enabling us to measure both the global mass flux (bubble volume, contact angle) and local mass flux around the bubble along time. After a short period of mass diffusion, where the boundary layer thickens like the square root of time, convection starts and the CO2 is carried by a plume falling at constant velocity. The boundary layer thickness then reaches a plateau which depends on the bubble cross section. Meanwhile the plume velocity scales like (dV /d t )1 /2 with V being the volume of the bubble. As for the rate of volume loss, we recover a constant mass flux in the diffusion-driven regime followed by a decrease in the volume V like V2 /3 after convection has started. We present a model which agrees well with the bubble dynamics and discuss our results in the context of droplet evaporation, as well as high Rayleigh convection.

A model for allometric scaling of mammalian metabolism with ambient heat loss.

PubMed

Kwak, Ho Sang; Im, Hong G; Shim, Eun Bo

2016-03-01

Allometric scaling, which represents the dependence of biological traits or processes on body size, is a long-standing subject in biological science. However, there has been no study to consider heat loss to the ambient and an insulation layer representing mammalian skin and fur for the derivation of the scaling law of metabolism. A simple heat transfer model is proposed to analyze the allometry of mammalian metabolism. The present model extends existing studies by incorporating various external heat transfer parameters and additional insulation layers. The model equations were solved numerically and by an analytic heat balance approach. A general observation is that the present heat transfer model predicted the 2/3 surface scaling law, which is primarily attributed to the dependence of the surface area on the body mass. External heat transfer effects introduced deviations in the scaling law, mainly due to natural convection heat transfer, which becomes more prominent at smaller mass. These deviations resulted in a slight modification of the scaling exponent to a value < 2/3. The finding that additional radiative heat loss and the consideration of an outer insulation fur layer attenuate these deviation effects and render the scaling law closer to 2/3 provides in silico evidence for a functional impact of heat transfer mode on the allometric scaling law in mammalian metabolism.

Sorption-induced effects of humic substances on mass transfer of organic pollutants through aqueous diffusion boundary layers: the example of water/air exchange.

PubMed

Ramus, Ksenia; Kopinke, Frank-Dieter; Georgi, Anett

2012-02-21

This study examines the effect of dissolved humic substances (DHS) on the rate of water-gas exchange of organic compounds under conditions where diffusion through the aqueous boundary layer is rate-determining. A synthetic surfactant was applied for comparison. Mass-transfer coefficients were determined from the rate of depletion of the model compounds by means of an apparatus containing a stirred aqueous solution with continuous purging of the headspace above the solution. In addition, experiments with continuous passive dosing of analytes into the water phase were conducted to simulate a system where thermodynamic activity of the chemical in the aqueous phase is identical in the presence and absence of DHS. The experimental results show that DHS and surfactants can affect water-gas exchange rates by the superposition of two mechanisms: (1) hydrodynamic effects due to surface film formation ("surface smoothing"), and (2) sorption-induced effects. Whether sorption accelerates or retards mass transfer depends on its effect on the thermodynamic activity of the pollutant in the aqueous phase. Mass transfer will be retarded if the activity (or freely dissolved concentration) of the pollutant is decreased due to sorption. If it remains unchanged (e.g., due to fast equilibration with a sediment acting as a large source phase), then DHS and surfactant micelles can act as an additional shuttle for the pollutants, enhancing the flux through the boundary layer.

Impact of kinetic mass transfer on free convection in a porous medium

NASA Astrophysics Data System (ADS)

Lu, Chunhui; Shi, Liangsheng; Chen, Yiming; Xie, Yueqing; Simmons, Craig T.

2016-05-01

We investigate kinetic mass transfer effects on unstable density-driven flow and transport processes by numerical simulations of a modified Elder problem. The first-order dual-domain mass transfer model coupled with a variable-density-flow model is employed to describe transport behavior in porous media. Results show that in comparison to the no-mass-transfer case, a higher degree of instability and more unstable system is developed in the mass transfer case due to the reduced effective porosity and correspondingly a larger Rayleigh number (assuming permeability is independent on the mobile porosity). Given a constant total porosity, the magnitude of capacity ratio (i.e., immobile porosity/mobile porosity) controls the macroscopic plume profile in the mobile domain, while the magnitude of mass transfer timescale (i.e., the reciprocal of the mass transfer rate coefficient) dominates its evolution rate. The magnitude of capacity ratio plays an important role on the mechanism driving the mass flux into the aquifer system. Specifically, for a small capacity ratio, solute loading is dominated by the density-driven transport, while with increasing capacity ratio local mass transfer dominated solute loading may occur at later times. At significantly large times, however, both mechanisms contribute comparably to solute loading. Sherwood Number could be a nonmonotonic function of mass transfer timescale due to complicated interactions of solute between source zone, mobile zone and immobile zone in the top boundary layer, resulting in accordingly a similar behavior of the total mass. The initial assessment provides important insights into unstable density-driven flow and transport in the presence of kinetic mass transfer.

Product mass transfer resistance directly determined during freeze-drying cycle runs using tunable diode laser absorption spectroscopy (TDLAS) and pore diffusion model.

PubMed

Kuu, Wei Y; O'Bryan, Kevin R; Hardwick, Lisa M; Paul, Timothy W

2011-08-01

The pore diffusion model is used to express the dry layer mass transfer resistance, [Formula: see text], as a function of the ratio r(e)/?, where r(e) is the effective pore radius and ? is the tortuosity factor of the dry layer. Using this model, the effective pore radius of the dry layer can be estimated from the sublimation rate and product temperature profiles measured during primary drying. Freeze-drying cycle runs were performed using the LyoStar II dryer (FTS Systems), with real-time sublimation rate profiles during freeze drying continuously measured by tunable diode laser absorption spectroscopy (TDLAS). The formulations chosen for demonstration of the proposed approach include 5% mannitol, 5% sucrose, 5% lactose, 3% mannitol plus 2% sucrose, and a parenteral nutrition formulation denoted VitaM12. The three different methods used for determination of the product resistance are: (1) Using both the sublimation rate and product temperature profiles, (2) using the sublimation rate profile alone, and (3) using the product temperate profile alone. Unlike the second and third methods, the computation procedure of first method does not need solution of the complex heat and mass transfer equations.

Origin of Self-preservation Effect for Hydrate Decomposition: Coupling of Mass and Heat Transfer Resistances

PubMed Central

Bai, Dongsheng; Zhang, Diwei; Zhang, Xianren; Chen, Guangjin

2015-01-01

Gas hydrates could show an unexpected high stability at conditions out of thermodynamic equilibrium, which is called the self-preservation effect. The mechanism of the effect for methane hydrates is here investigated via molecular dynamics simulations, in which an NVT/E method is introduced to represent different levels of heat transfer resistance. Our simulations suggest a coupling between the mass transfer resistance and heat transfer resistance as the driving mechanism for self-preservation effect. We found that the hydrate is initially melted from the interface, and then a solid-like water layer with temperature-dependent structures is formed next to the hydrate interface that exhibits fractal feature, followed by an increase of mass transfer resistance for the diffusion of methane from hydrate region. Furthermore, our results indicate that heat transfer resistance is a more fundamental factor, since it facilitates the formation of the solid-like layer and hence inhibits the further dissociation of the hydrates. The self-preservation effect is found to be enhanced with the increase of pressure and particularly the decrease of temperature. Kinetic equations based on heat balance calculations is also developed to describe the self-preservation effect, which reproduces our simulation results well and provides an association between microscopic and macroscopic properties. PMID:26423519

Origin of Self-preservation Effect for Hydrate Decomposition: Coupling of Mass and Heat Transfer Resistances.

PubMed

Bai, Dongsheng; Zhang, Diwei; Zhang, Xianren; Chen, Guangjin

2015-10-01

Gas hydrates could show an unexpected high stability at conditions out of thermodynamic equilibrium, which is called the self-preservation effect. The mechanism of the effect for methane hydrates is here investigated via molecular dynamics simulations, in which an NVT/E method is introduced to represent different levels of heat transfer resistance. Our simulations suggest a coupling between the mass transfer resistance and heat transfer resistance as the driving mechanism for self-preservation effect. We found that the hydrate is initially melted from the interface, and then a solid-like water layer with temperature-dependent structures is formed next to the hydrate interface that exhibits fractal feature, followed by an increase of mass transfer resistance for the diffusion of methane from hydrate region. Furthermore, our results indicate that heat transfer resistance is a more fundamental factor, since it facilitates the formation of the solid-like layer and hence inhibits the further dissociation of the hydrates. The self-preservation effect is found to be enhanced with the increase of pressure and particularly the decrease of temperature. Kinetic equations based on heat balance calculations is also developed to describe the self-preservation effect, which reproduces our simulation results well and provides an association between microscopic and macroscopic properties.

Solutal separation in a binary nanofluid due to thermodiffusion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saghir, M.Z.; Yousefi, T.; Farahbakhsh, B.

2015-03-10

Transport phenomena in porous media have received considerable attention due to an increasing interest in geothermal processes, chemical catalytic reactors, waste storage (especially geological or ocean storage of carbon dioxide), etc. Among others, oil industry has shown an increasing interest in studying diffusion phenomenon. Nanofluid is a term used to describe the suspension of low concentration of metallic and non-metallic nanoparticles in a base fluid. The size of a nanoparticle ranges from 10 to 100nm, and the conventional fluids used are water, ethylene glycol (C{sub 2}H{sub 6}O{sub 2}) or engine oil. Various studies have proven that nanoparticles improve the heatmore » transfer of a base fluid. However, using various nanofluids it has been shown that the results could vary depending on different initial concentrations. The main objective of this paper is to study the diffusion and the thermodiffusion effect in a nanofluid for different fluid/porous media configurations. In this configuration, a liquid layer surrounds a porous layer. The full Brinkman equation coupled with the heat and mass transfer equations have been solved numerically for the porous layer using the finite element technique. The full Navier stokes equation coupled with heat and mass transfer equations have been solved for the liquid layer using the finite element method. A constraint between the liquid and porous layer has been applied to ensure heat flow and mass transfer continuity is maintained. A square cavity filled with hydrocarbon nanofluid of a mixture of fullerene-toluene with varying concentration of fullerene has been subject to different heating conditions. The entire cavity has been considered to be fully wetted with nanofluid. Results have confirmed that in the presence of a nanofluid a heat transfer enhancement is present up to certain initial concentration of the fullerene. The heat convection coefficient has been found to be 16% higher when a nanofluid is used as the working fluid.« less

Mass detection in digital breast tomosynthesis: Deep convolutional neural network with transfer learning from mammography.

PubMed

Samala, Ravi K; Chan, Heang-Ping; Hadjiiski, Lubomir; Helvie, Mark A; Wei, Jun; Cha, Kenny

2016-12-01

Develop a computer-aided detection (CAD) system for masses in digital breast tomosynthesis (DBT) volume using a deep convolutional neural network (DCNN) with transfer learning from mammograms. A data set containing 2282 digitized film and digital mammograms and 324 DBT volumes were collected with IRB approval. The mass of interest on the images was marked by an experienced breast radiologist as reference standard. The data set was partitioned into a training set (2282 mammograms with 2461 masses and 230 DBT views with 228 masses) and an independent test set (94 DBT views with 89 masses). For DCNN training, the region of interest (ROI) containing the mass (true positive) was extracted from each image. False positive (FP) ROIs were identified at prescreening by their previously developed CAD systems. After data augmentation, a total of 45 072 mammographic ROIs and 37 450 DBT ROIs were obtained. Data normalization and reduction of non-uniformity in the ROIs across heterogeneous data was achieved using a background correction method applied to each ROI. A DCNN with four convolutional layers and three fully connected (FC) layers was first trained on the mammography data. Jittering and dropout techniques were used to reduce overfitting. After training with the mammographic ROIs, all weights in the first three convolutional layers were frozen, and only the last convolution layer and the FC layers were randomly initialized again and trained using the DBT training ROIs. The authors compared the performances of two CAD systems for mass detection in DBT: one used the DCNN-based approach and the other used their previously developed feature-based approach for FP reduction. The prescreening stage was identical in both systems, passing the same set of mass candidates to the FP reduction stage. For the feature-based CAD system, 3D clustering and active contour method was used for segmentation; morphological, gray level, and texture features were extracted and merged with a linear discriminant classifier to score the detected masses. For the DCNN-based CAD system, ROIs from five consecutive slices centered at each candidate were passed through the trained DCNN and a mass likelihood score was generated. The performances of the CAD systems were evaluated using free-response ROC curves and the performance difference was analyzed using a non-parametric method. Before transfer learning, the DCNN trained only on mammograms with an AUC of 0.99 classified DBT masses with an AUC of 0.81 in the DBT training set. After transfer learning with DBT, the AUC improved to 0.90. For breast-based CAD detection in the test set, the sensitivity for the feature-based and the DCNN-based CAD systems was 83% and 91%, respectively, at 1 FP/DBT volume. The difference between the performances for the two systems was statistically significant (p-value < 0.05). The image patterns learned from the mammograms were transferred to the mass detection on DBT slices through the DCNN. This study demonstrated that large data sets collected from mammography are useful for developing new CAD systems for DBT, alleviating the problem and effort of collecting entirely new large data sets for the new modality.

Development of a Distributed Source Contaminant Transport Model for ARAMS

DTIC Science & Technology

2005-09-01

runoff as a result of rainfall. The transfer of dissolved chemicals from the soil solution to overland flow is a rate-limited process ERDC/EL TN-ECMI...boundary layer that separates the stagnant soil solution and the moving overland flow (Wallach et al. 1988, 1989). Dissolution. Some chemicals may...layer (L/T) The mass transfer coefficient relates solute flux across the soil surface interface to the difference in concentration between the soil

A Numerical Analysis of the Transient Response of an Ablation System Including Effects of Thermal Nonequilibrium, Mass Transfer and Chemical Kinetics. Ph.D Thesis - Virginia Polytechnic Inst. and State Univ.

NASA Technical Reports Server (NTRS)

Clark, R. K.

1972-01-01

The differential equations governing the transient response of a one-dimensional ablative thermal protection system undergoing stagnation ablation are derived. These equations are for thermal nonequilibrium effects between the pyrolysis gases and the char layer and kinetically controlled chemical reactions and mass transfer between the pyrolysis gases and the char layer. The boundary conditions are written for the particular case of stagnation heating with surface removal by oxidation or sublimation and pyrolysis of the uncharred layer occurring in a plane. The governing equations and boundary conditions are solved numerically using the modified implicit method (Crank-Nicolson method). Numerical results are compared with exact solutions for a number of simplified cases. The comparison is favorable in each instance.

Effects of convergent diffusion and charge transfer kinetics on the diffusion layer thickness of spherical micro- and nanoelectrodes.

PubMed

Molina, A; Laborda, E; González, J; Compton, R G

2013-05-21

Nuances of the linear diffusion layer approximation are examined for slow charge transfer reactions at (hemi)spherical micro- and nanoelectrodes. This approximation is widely employed in Electrochemistry to evaluate the extent of electrolyte solution perturbed by the electrode process, which is essential to the understanding of the effects arising from thin-layer diffusion, convergent diffusion, convection, coupled chemical reactions and the double layer. The concept was well established for fast charge transfer processes at macroelectrodes, but remains unclear under other conditions such that a thorough assessment of its meaning was necessary. In a previous publication [A. Molina, J. González, E. Laborda and R. G. Compton, Phys. Chem. Chem. Phys., 2013, 15, 2381-2388] we shed some light on the influence of the reversibility degree. In the present work, the meaning of the diffusion layer thickness is investigated when very small electrodes are employed and so the contribution of convergent diffusion to the mass transport is very important. An analytical expression is given to calculate the linear diffusion layer thickness at (hemi)spherical electrodes and its behaviour is studied for a wide range of conditions of reversibility (from reversible to fully-irreversible processes) and electrode size (from macro- to nano-electrodes). Rigorous analytical solutions are deduced for true concentration profiles, surface concentrations, linear diffusion layer thickness and current densities when a potential pulse is applied at (hemi)spherical electrodes. The expressions for the magnitudes mentioned above are valid for electrodes of any size (including (hemi)spherical nanoelectrodes) and for any degree of reversibility, provided that mass transport occurs exclusively via diffusion. The variation of the above with the electrode size, applied potential and charge transfer kinetics is studied.

Mathematical model of mass transfer at electron beam treatment

NASA Astrophysics Data System (ADS)

Konovalov, Sergey V.; Sarychev, Vladimir D.; Nevskii, Sergey A.; Kobzareva, Tatyana Yu.; Gromov, Victor E.; Semin, Alexander P.

2017-01-01

The paper proposes a model of convective mass transfer at electron beam treatment with beams in titanium alloys subjected to electro-explosion alloying by titanium diboride powder. The proposed model is based on the concept that treatment with concentrated flows of energy results in the initiation of vortices in the melted layer. The formation mechanism of these vortices rooted in the idea that the availability of temperature drop leads to the initiation of the thermo-capillary convection. For the melted layer of metal the equations of the convective heat transfer and boundary conditions in terms of the evaporated material are written. The finite element solution of these equations showed that electron-beam treatment results in the formation of multi-vortex structure that in developing captures all new areas of material. It leads to the fact that the strengthening particles are observed at the depth increasing many times the depth of their penetration according to the diffusion mechanism. The distribution of micro-hardness at depth and the thickness of strengthening zone determined from these data supported the view that proposed model of the convective mass transfer describes adequately the processes going on in the treatment with low-energy high-current electron beam.

ASDA - Advanced Suit Design Analyzer computer program

NASA Technical Reports Server (NTRS)

Bue, Grant C.; Conger, Bruce C.; Iovine, John V.; Chang, Chi-Min

1992-01-01

An ASDA model developed to evaluate the heat and mass transfer characteristics of advanced pressurized suit design concepts for low pressure or vacuum planetary applications is presented. The model is based on a generalized 3-layer suit that uses the Systems Integrated Numerical Differencing Analyzer '85 in conjunction with a 41-node FORTRAN routine. The latter simulates the transient heat transfer and respiratory processes of a human body in a suited environment. The user options for the suit encompass a liquid cooled garment, a removable jacket, a CO2/H2O permeable layer, and a phase change layer.

On two special values of temperature factor in hypersonic flow stagnation point

NASA Astrophysics Data System (ADS)

Bilchenko, G. G.; Bilchenko, N. G.

2018-03-01

The hypersonic aircraft permeable cylindrical and spherical surfaces laminar boundary layer heat and mass transfer control mathematical model properties are investigated. The nonlinear algebraic equations systems are obtained for two special values of temperature factor in the hypersonic flow stagnation point. The mappings bijectivity between heat and mass transfer local parameters and controls is established. The computation experiments results are presented: the domains of allowed values “heat-friction” are obtained.

Mass detection in digital breast tomosynthesis: Deep convolutional neural network with transfer learning from mammography

PubMed Central

Chan, Heang-Ping; Hadjiiski, Lubomir; Helvie, Mark A.; Wei, Jun; Cha, Kenny

2016-01-01

Purpose: Develop a computer-aided detection (CAD) system for masses in digital breast tomosynthesis (DBT) volume using a deep convolutional neural network (DCNN) with transfer learning from mammograms. Methods: A data set containing 2282 digitized film and digital mammograms and 324 DBT volumes were collected with IRB approval. The mass of interest on the images was marked by an experienced breast radiologist as reference standard. The data set was partitioned into a training set (2282 mammograms with 2461 masses and 230 DBT views with 228 masses) and an independent test set (94 DBT views with 89 masses). For DCNN training, the region of interest (ROI) containing the mass (true positive) was extracted from each image. False positive (FP) ROIs were identified at prescreening by their previously developed CAD systems. After data augmentation, a total of 45 072 mammographic ROIs and 37 450 DBT ROIs were obtained. Data normalization and reduction of non-uniformity in the ROIs across heterogeneous data was achieved using a background correction method applied to each ROI. A DCNN with four convolutional layers and three fully connected (FC) layers was first trained on the mammography data. Jittering and dropout techniques were used to reduce overfitting. After training with the mammographic ROIs, all weights in the first three convolutional layers were frozen, and only the last convolution layer and the FC layers were randomly initialized again and trained using the DBT training ROIs. The authors compared the performances of two CAD systems for mass detection in DBT: one used the DCNN-based approach and the other used their previously developed feature-based approach for FP reduction. The prescreening stage was identical in both systems, passing the same set of mass candidates to the FP reduction stage. For the feature-based CAD system, 3D clustering and active contour method was used for segmentation; morphological, gray level, and texture features were extracted and merged with a linear discriminant classifier to score the detected masses. For the DCNN-based CAD system, ROIs from five consecutive slices centered at each candidate were passed through the trained DCNN and a mass likelihood score was generated. The performances of the CAD systems were evaluated using free-response ROC curves and the performance difference was analyzed using a non-parametric method. Results: Before transfer learning, the DCNN trained only on mammograms with an AUC of 0.99 classified DBT masses with an AUC of 0.81 in the DBT training set. After transfer learning with DBT, the AUC improved to 0.90. For breast-based CAD detection in the test set, the sensitivity for the feature-based and the DCNN-based CAD systems was 83% and 91%, respectively, at 1 FP/DBT volume. The difference between the performances for the two systems was statistically significant (p-value < 0.05). Conclusions: The image patterns learned from the mammograms were transferred to the mass detection on DBT slices through the DCNN. This study demonstrated that large data sets collected from mammography are useful for developing new CAD systems for DBT, alleviating the problem and effort of collecting entirely new large data sets for the new modality. PMID:27908154

Mass Transfer Process by Magneto-convection at a Solid-liquid Interface in a Heterogeneous Vertical Magnetic Field

NASA Astrophysics Data System (ADS)

Sugiyama, Atsushi; Morisaki, Shigeyoshi; Aogaki, Ryoichi

2003-08-01

When an external magnetic field is vertically imposed on a solid-liquid interface, the mass transfer process of a solute dissolving from or depositing on the interface was theoretically examined. In a heterogeneous vertical magnetic field, a material receives a magnetic force in proportion to the product of the magnetic susceptibility, the magnetic flux density B and its gradient (dB/dz). As the reaction proceeds, a diffusion layer of the solute with changing susceptibility is formed at the interface because of the difference of the the magnetic susceptibility on the concentration of the solute. In the case of an unstable condition where the dimensionless number of magneto-convection S takes a positive value, the magnetic force is applied to the layer and induces numerous minute convection cells. The mass transfer of the solute is thus accelerated, so that it is predicted that the mass flux increases with the 1/3rd order of B(dB/dz) and the 4/3rd order of the concentration. The experiment was then performed by measuring the rate of the dissolution of copper sulfate pentahydrate crystal in water.

Shift in Mass Transfer of Wastewater Contaminants from Microplastics in the Presence of Dissolved Substances.

PubMed

Seidensticker, Sven; Zarfl, Christiane; Cirpka, Olaf A; Fellenberg, Greta; Grathwohl, Peter

2017-11-07

In aqueous environments, hydrophobic organic contaminants are often associated with particles. Besides natural particles, microplastics have raised public concern. The release of pollutants from such particles depends on mass transfer, either in an aqueous boundary layer or by intraparticle diffusion. Which of these mechanisms controls the mass-transfer kinetics depends on partition coefficients, particle size, boundary conditions, and time. We have developed a semianalytical model accounting for both processes and performed batch experiments on the desorption kinetics of typical wastewater pollutants (phenanthrene, tonalide, and benzophenone) at different dissolved-organic-matter concentrations, which change the overall partitioning between microplastics and water. Initially, mass transfer is externally dominated, while finally, intraparticle diffusion controls release kinetics. Under boundary conditions typical for batch experiments (finite bath), desorption accelerates with increasing partition coefficients for intraparticle diffusion, while it becomes independent of partition coefficients if film diffusion prevails. On the contrary, under field conditions (infinite bath), the pollutant release controlled by intraparticle diffusion is not affected by partitioning of the compound while external mass transfer slows down with increasing sorption. Our results clearly demonstrate that sorption/desorption time scales observed in batch experiments may not be transferred to field conditions without an appropriate model accounting for both the mass-transfer mechanisms and the specific boundary conditions at hand.

Experimental investigation of 20 K two-stage layered active magnetic regenerative refrigerator

NASA Astrophysics Data System (ADS)

Park, Inmyong; Jeong, Sangkwon

2015-12-01

The performance of a two-stage layered AMRR is experimentally investigated. The test apparatus includes two-stage layered AMRs, low temperature superconducting (LTS) magnet which generates maximum magnetic field of 4 T, and the helium gas flow system. The helium compressor with the tandem rotary valve is employed to generate the oscillating flow of the helium gas minimizing the pressure swing effect. The mass flow rate of working fluid is controlled separately at the first and second stages of the AMR by solenoid valves. The mass flow rate of the AMRs is measured by the mass flow meter and the cryogenic hot-film sensor which is calibrated at cryogenic temperature range from 20 K to 77 K. In order to reduce the heat leak by shuttle heat transfer of the working fluid, void volumes have been implemented and connected to the cold ends of the AMR1 and AMR2. The temperature span of the AMR is recorded as 52 K and the performance of the AMR with the variation of the mass flow rate is analysed. The results show that the mass flow rate and the heat leak due to the shuttle heat transfer by oscillating working fluid are crucial factors in the AMR performance.

Comments on Hypersonic Boundary-Layer Transition

DTIC Science & Technology

1990-09-01

mechanism by which boundary-layer disturbance growth is generally initiated and establishes the initial distur- banca amplitude at the onset of disturbance...Patankar, S. V., and Spalding, P. B., Heat and Mass Transfer in Boundary Lavers, CRC Press , Cleveland, Ohio, 1968. 87. Neumann, R. D., and Patterson, .J. 1

Impact of current speed on mass flux to a model flexible seagrass blade

NASA Astrophysics Data System (ADS)

Lei, Jiarui; Nepf, Heidi

2016-07-01

Seagrass and other freshwater macrophytes can acquire nutrients from surrounding water through their blades. This flux may depend on the current speed (U), which can influence both the posture of flexible blades (reconfiguration) and the thickness of the flux-limiting diffusive layer. The impact of current speed (U) on mass flux to flexible blades of model seagrass was studied through a combination of laboratory flume experiments, numerical modeling and theory. Model seagrass blades were constructed from low-density polyethylene (LDPE), and 1, 2-dichlorobenzene was used as a tracer chemical. The tracer mass accumulation in the blades was measured at different unidirectional current speeds. A numerical model was used to estimate the transfer velocity (K) by fitting the measured mass uptake to a one-dimensional diffusion model. The measured transfer velocity was compared to predictions based on laminar and turbulent boundary layers developing over a flat plate parallel to flow, for which K∝U0.5 and ∝U, respectively. The degree of blade reconfiguration depended on the dimensionless Cauchy number, Ca, which is a function of both the blade stiffness and flow velocity. For large Ca, the majority of the blade was parallel to the flow, and the measured transfer velocity agreed with laminar boundary layer theory, K∝U0.5. For small Ca, the model blades remained upright, and the flux to the blade was diminished relative to the flat-plate model. A meadow-scale analysis suggests that the mass exchange at the blade scale may control the uptake at the meadow scale.

On computational experiments in some inverse problems of heat and mass transfer

NASA Astrophysics Data System (ADS)

Bilchenko, G. G.; Bilchenko, N. G.

2016-11-01

The results of mathematical modeling of effective heat and mass transfer on hypersonic aircraft permeable surfaces are considered. The physic-chemical processes (the dissociation and the ionization) in laminar boundary layer of compressible gas are appreciated. Some algorithms of control restoration are suggested for the interpolation and approximation statements of heat and mass transfer inverse problems. The differences between the methods applied for the problem solutions search for these statements are discussed. Both the algorithms are realized as programs. Many computational experiments were accomplished with the use of these programs. The parameters of boundary layer obtained by means of the A.A.Dorodnicyn's generalized integral relations method from solving the direct problems have been used to obtain the inverse problems solutions. Two types of blowing laws restoration for the inverse problem in interpolation statement are presented as the examples. The influence of the temperature factor on the blowing restoration is investigated. The different character of sensitivity of controllable parameters (the local heat flow and local tangent friction) respectively to step (discrete) changing of control (the blowing) and the switching point position is studied.

Rate of precipitation of calcium phosphate on heated surfaces.

PubMed

Barton, K P; Chapman, T W; Lund, D

1985-03-01

Fouling of a heated stainless steel surface by calcium phosphate precipitation has been studied in an annular flow apparatus, instrumented to provide a constant heat flux while measuring local metal-surface temperatures. Models of the heat and mass-transfer boundary layers are used to estimate interfacial temperatures and concentrations, from which the heterogeneous reaction rate is inferred. The analysis indicates that the reaction rate is a function of both chemical kinetics and mass transfer limitations.

Momentum and buoyancy transfer in atmospheric turbulent boundary layer over wavy water surface - Part 1: Harmonic wave

NASA Astrophysics Data System (ADS)

Troitskaya, Yu. I.; Ezhova, E. V.; Zilitinkevich, S. S.

2013-10-01

The surface-drag and mass-transfer coefficients are determined within a self-consistent problem of wave-induced perturbations and mean fields of velocity and density in the air, using a quasi-linear model based on the Reynolds equations with down-gradient turbulence closure. Investigation of a harmonic wave propagating along the wind has disclosed that the surface drag is generally larger for shorter waves. This effect is more pronounced in the unstable and neutral stratification. The stable stratification suppresses turbulence, which leads to weakening of the momentum and mass transfer.

Cross-domain and multi-task transfer learning of deep convolutional neural network for breast cancer diagnosis in digital breast tomosynthesis

NASA Astrophysics Data System (ADS)

Samala, Ravi K.; Chan, Heang-Ping; Hadjiiski, Lubomir; Helvie, Mark A.; Richter, Caleb; Cha, Kenny

2018-02-01

We propose a cross-domain, multi-task transfer learning framework to transfer knowledge learned from non-medical images by a deep convolutional neural network (DCNN) to medical image recognition task while improving the generalization by multi-task learning of auxiliary tasks. A first stage cross-domain transfer learning was initiated from ImageNet trained DCNN to mammography trained DCNN. 19,632 regions-of-interest (ROI) from 2,454 mass lesions were collected from two imaging modalities: digitized-screen film mammography (SFM) and full-field digital mammography (DM), and split into training and test sets. In the multi-task transfer learning, the DCNN learned the mass classification task simultaneously from the training set of SFM and DM. The best transfer network for mammography was selected from three transfer networks with different number of convolutional layers frozen. The performance of single-task and multitask transfer learning on an independent SFM test set in terms of the area under the receiver operating characteristic curve (AUC) was 0.78+/-0.02 and 0.82+/-0.02, respectively. In the second stage cross-domain transfer learning, a set of 12,680 ROIs from 317 mass lesions on DBT were split into validation and independent test sets. We first studied the data requirements for the first stage mammography trained DCNN by varying the mammography training data from 1% to 100% and evaluated its learning on the DBT validation set in inference mode. We found that the entire available mammography set provided the best generalization. The DBT validation set was then used to train only the last four fully connected layers, resulting in an AUC of 0.90+/-0.04 on the independent DBT test set.

Nonstationary heat and mass transfer in the multilayer building construction with ventilation channels

NASA Astrophysics Data System (ADS)

Kharkov, N. S.

2017-11-01

Results of numerical modeling of the coupled nonstationary heat and mass transfer problem under conditions of a convective flow in facade system of a three-layer concrete panel for two different constructions (with ventilation channels and without) are presented. The positive effect of ventilation channels on the energy and humidity regime over a period of 12 months is shown. Used new method of replacement a solid zone (requiring specification of porosity and material structure, what complicates process of convergence of the solution) on quasi-solid in form of a multicomponent mixture (with restrictions on convection and mass fractions).

Model Implementation of Boron Removal Using CaCl2-CaO-SiO2 Slag System for Solar-Grade Silicon

NASA Astrophysics Data System (ADS)

Chen, Hui; Wang, Ye; Zheng, Wenjia; Li, Qincan; Yuan, Xizhi; Morita, Kazuki

2017-12-01

A new CaCl2-CaO-SiO2 slag system was recently proposed to remove boron from metallurgy-grade silicon by oxidized chlorination and evaporation. To further investigate the boron transformation process at a high temperature, a model implementation to present the transfer of boron from molten silicon to the gas phase via slag is introduced. Heat transfer, fluid flow, the chemical reactions at the interface and surface, the mass transfer and diffusion of boron in the molten silicon and slag, and the evaporation of BOCl and CaCl2 were coupled in this model. After the confirmation of the thermal field, other critical parameters, including the boron partition ratios ( L B) for this slag from 1723 K to 1823 K (1450 °C to 1550 °C), the thicknesses of the velocity boundary layer at the surface and interface, the mass transfer coefficients of the boundary layer at the surface and interface, and partial pressure of BOCl in the gas phase were analyzed to determine the rate-limiting step. To verify this model implementation, boron removal experiments were carried out at various temperatures and with various initial mass ratios of slag to silicon ( μ). The evaporation rate of CaCl2 was also measured by thermogravimetry analysis (TGA).

Determination of the dried product resistance variability and its influence on the product temperature in pharmaceutical freeze-drying.

PubMed

Scutellà, Bernadette; Trelea, Ioan Cristian; Bourlès, Erwan; Fonseca, Fernanda; Passot, Stephanie

2018-07-01

During the primary drying step of the freeze-drying process, mass transfer resistance strongly affects the product temperature, and consequently the final product quality. The main objective of this study was to evaluate the variability of the mass transfer resistance resulting from the dried product layer (R p ) in a manufacturing batch of vials, and its potential effect on the product temperature, from data obtained in a pilot scale freeze-dryer. Sublimation experiments were run at -25 °C and 10 Pa using two different freezing protocols: with spontaneous or controlled ice nucleation. Five repetitions of each condition were performed. Global (pressure rise test) and local (gravimetric) methods were applied as complementary approaches to estimate R p . The global method allowed to assess variability of the evolution of R p with the dried layer thickness between different experiments whereas the local method informed about R p variability at a fixed time within the vial batch. A product temperature variability of approximately ±4.4 °C was defined for a product dried layer thickness of 5 mm. The present approach can be used to estimate the risk of failure of the process due to mass transfer variability when designing freeze-drying cycle. Copyright © 2018 Elsevier B.V. All rights reserved.

Comparisons of rational engineering correlations of thermophoretically-augmented particle mass transfer with STAN5-predictions for developing boundary layers

NASA Technical Reports Server (NTRS)

Gokoglu, S. A.; Rosner, D. E.

1984-01-01

Modification of the code STAN5 to properly include thermophoretic mass transport, and examination of selected test cases developing boundary layers which include variable properties, viscous dissipation, transition to turbulence and transpiration cooling. Under conditions representative of current and projected GT operation, local application of St(M)/St(M),o correlations evidently provides accurate and economical engineering design predictions, especially for suspended particles characterized by Schmidt numbers outside of the heavy vapor range.

Thermal Convection in High-Pressure Ice Layers Beneath a Buried Ocean within Titan and Ganymede

NASA Astrophysics Data System (ADS)

Tobie, G.; Choblet, G.; Dumont, M.

2014-12-01

Deep interiors of large icy satellites such as Titan and Ganymede probably harbor a buried ocean sandwiched between low pressure ice and high-pressure ice layers. The nature and location of the lower interface of the ocean involves equilibration of heat and melt transfer in the HP ices and is ultimately controlled by the amount heat transferred through the surface ice Ih layer. Here, we perform 3D simulations of thermal convection, using the OEDIPUS numerical tool (Choblet et al. GJI 2007), to determine the efficiency of heat and mass transfer through these HP ice mantles. In a first series of simulations with no melting, we show that a significant fraction of the HP layer reaches the melting point. Using a simple description of water production and transport, our simulations demonstrate that the melt generation in the outermost part of the HP ice layer and its extraction to the overlying ocean increase the efficiency of heat transfer and reduce strongly the internal temperature. structure and the efficiency of the heat transfer. Scaling relationships are proposed to describe the cooling effect of melt production/extraction and used to investigate the consequences of internal melting on the thermal history of Titan and Ganymede's interior.

Effect of acoustic streaming on the mass transfer from a sublimating sphere

NASA Astrophysics Data System (ADS)

Kawahara, N.; Yarin, A. L.; Brenn, G.; Kastner, O.; Durst, F.

2000-04-01

The effect of the acoustic streaming on the mass transfer from the surface of a sphere positioned in an ultrasonic acoustic levitator is studied both experimentally and theoretically. Acoustic levitation using standing ultrasonic waves is an experimental tool for studying the heat and mass transfer from small solid or liquid samples, because it allows an almost steady positioning of a sample at a fixed location in space. However, the levitator introduces some difficulties. One of the main problems with acoustic levitation is that an acoustic streaming is induced near the sample surface, which affects the heat and mass transfer rates, as characterized by increased Nusselt and Sherwood numbers. The transfer rates are not uniform along the sample surface, and the aim of the present study is to quantify the spatial Sherwood number distribution over the surface of a sphere. The experiments are based on the measurement of the surface shape of a sphere layered with a solid substance as a function of time using a charge-coupled device (CCD) camera with backlighting. The sphere used in this research is a glass sphere layered with a volatile solid substance (naphthalene or camphor). The local mass transfer from the surface both with and without an ultrasonic acoustic field is investigated in order to evaluate the effect of the acoustic streaming. The experimental results are compared with predictions following from the theory outlined [A. L. Yarin, M. Pfaffenlehner, and C. Tropea, J. Fluid Mech. 356, 65 (1998); A. L. Yarin, G. Brenn, O. Kastner, D. Rensink, and C. Tropea, ibid. 399, 151 (1999)] which describes the acoustic field and the resulting acoustic streaming, and the mass transfer at the surface of particles and droplets located in an acoustic levitator. The results are also compared with the experimental data and with the theoretical predictions of Burdukov and Nakoryakov [J. Appl. Mech. Tech. Phys. 6, 51 (1965)], which are valid only in the case of spherical particles much smaller than the sound wavelength. Good agreement between experiment and the theory of Yarin et al. is demonstrated. The time-averaged heat and mass transfer rates over a sphere surface are greatest at the sphere's equator and least at its poles in the experiment as predicted by the theory (the ultrasonic standing wave spans the vertical axis passing through the poles). The measured distribution of the mass transfer rate over the sphere surface also agrees with the theoretical predictions, which shows that in strong acoustic fields sublimation (or evaporation) results from the acoustic streaming.

Evolutionary pruning of transfer learned deep convolutional neural network for breast cancer diagnosis in digital breast tomosynthesis.

PubMed

Samala, Ravi K; Chan, Heang-Ping; Hadjiiski, Lubomir M; Helvie, Mark A; Richter, Caleb; Cha, Kenny

2018-05-01

Deep learning models are highly parameterized, resulting in difficulty in inference and transfer learning for image recognition tasks. In this work, we propose a layered pathway evolution method to compress a deep convolutional neural network (DCNN) for classification of masses in digital breast tomosynthesis (DBT). The objective is to prune the number of tunable parameters while preserving the classification accuracy. In the first stage transfer learning, 19 632 augmented regions-of-interest (ROIs) from 2454 mass lesions on mammograms were used to train a pre-trained DCNN on ImageNet. In the second stage transfer learning, the DCNN was used as a feature extractor followed by feature selection and random forest classification. The pathway evolution was performed using genetic algorithm in an iterative approach with tournament selection driven by count-preserving crossover and mutation. The second stage was trained with 9120 DBT ROIs from 228 mass lesions using leave-one-case-out cross-validation. The DCNN was reduced by 87% in the number of neurons, 34% in the number of parameters, and 95% in the number of multiply-and-add operations required in the convolutional layers. The test AUC on 89 mass lesions from 94 independent DBT cases before and after pruning were 0.88 and 0.90, respectively, and the difference was not statistically significant (p  >  0.05). The proposed DCNN compression approach can reduce the number of required operations by 95% while maintaining the classification performance. The approach can be extended to other deep neural networks and imaging tasks where transfer learning is appropriate.

Evolutionary pruning of transfer learned deep convolutional neural network for breast cancer diagnosis in digital breast tomosynthesis

NASA Astrophysics Data System (ADS)

Samala, Ravi K.; Chan, Heang-Ping; Hadjiiski, Lubomir M.; Helvie, Mark A.; Richter, Caleb; Cha, Kenny

2018-05-01

Deep learning models are highly parameterized, resulting in difficulty in inference and transfer learning for image recognition tasks. In this work, we propose a layered pathway evolution method to compress a deep convolutional neural network (DCNN) for classification of masses in digital breast tomosynthesis (DBT). The objective is to prune the number of tunable parameters while preserving the classification accuracy. In the first stage transfer learning, 19 632 augmented regions-of-interest (ROIs) from 2454 mass lesions on mammograms were used to train a pre-trained DCNN on ImageNet. In the second stage transfer learning, the DCNN was used as a feature extractor followed by feature selection and random forest classification. The pathway evolution was performed using genetic algorithm in an iterative approach with tournament selection driven by count-preserving crossover and mutation. The second stage was trained with 9120 DBT ROIs from 228 mass lesions using leave-one-case-out cross-validation. The DCNN was reduced by 87% in the number of neurons, 34% in the number of parameters, and 95% in the number of multiply-and-add operations required in the convolutional layers. The test AUC on 89 mass lesions from 94 independent DBT cases before and after pruning were 0.88 and 0.90, respectively, and the difference was not statistically significant (p  >  0.05). The proposed DCNN compression approach can reduce the number of required operations by 95% while maintaining the classification performance. The approach can be extended to other deep neural networks and imaging tasks where transfer learning is appropriate.

Stress-sensitive tissue regeneration in viscoelastic biomaterials subjected to modulated tensile strain.

PubMed

Belfiore, Laurence A; Floren, Michael L; Paulino, Alexandre T; Belfiore, Carol J

2011-09-01

This research contribution addresses the mechanochemistry of intra-tissue mass transfer for nutrients, oxygen, growth factors, and other essential ingredients that anchorage-dependent cells require for successful proliferation on biocompatible surfaces. The unsteady state reaction-diffusion equation (i.e., modified diffusion equation) is solved according to the von Kármán-Pohlhausen integral method of boundary layer analysis when nutrient consumption and tissue regeneration are stimulated by harmonically imposed stress. The mass balance with diffusion and stress-sensitive kinetics represents a rare example where the Damköhler and Deborah numbers appear together in an effort to simulate the development of mass transfer boundary layers in porous viscoelastic biomaterials. The Boltzmann superposition integral is employed to calculate time-dependent strain in terms of the real and imaginary components of dynamic compliance for viscoelastic solids that transmit harmonic excitation to anchorage-dependent cells. Rates of nutrient consumption under stress-free conditions are described by third-order kinetics which include local mass densities of nutrients, oxygen, and attached cells that maintain dynamic equilibrium with active protein sites in the porous matrix. Thinner nutrient mass transfer boundary layers are stabilized at shorter dimensionless diffusion times when the stress-free intra-tissue Damköhler number increases above its initial-condition-sensitive critical value. The critical stress-sensitive intra-tissue Damköhler number, above which it is necessary to consider the effect of harmonic strain on nutrient consumption and tissue regeneration, is proportional to the Deborah number and corresponds to a larger fraction of the stress-free intra-tissue Damköhler number in rigid biomaterials. Copyright © 2011 Elsevier B.V. All rights reserved.

Small particle transport across turbulent nonisothermal boundary layers

NASA Technical Reports Server (NTRS)

Rosner, D. E.; Fernandez De La Mora, J.

1982-01-01

The interaction between turbulent diffusion, Brownian diffusion, and particle thermophoresis in the limit of vanishing particle inertial effects is quantitatively modeled for applications in gas turbines. The model is initiated with consideration of the particle phase mass conservation equation for a two-dimensional boundary layer, including the thermophoretic flux term directed toward the cold wall. A formalism of a turbulent flow near a flat plate in a heat transfer problem is adopted, and variable property effects are neglected. Attention is given to the limit of very large Schmidt numbers and the particle concentration depletion outside of the Brownian sublayer. It is concluded that, in the parameter range of interest, thermophoresis augments the high Schmidt number mass-transfer coefficient by a factor equal to the product of the outer sink and the thermophoretic suction.

Thermal boundary layer due to sudden heating of fluid

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kurkal, K.R.; Munukutla, S.

This paper proposes to solve computationally the heat-transfer problems (introduced by Munukutla and Venkataraman, 1988) related to a closed-cycle pulsed high-power laser flow loop. The continuity and the momentum equations as well as the unsteady energy equation are solved using the Keller-Box method. The solutions were compared with the steady-state solutions at large times, and the comparison was found to be excellent. Empirical formulas are proposed for calculating the time-dependent boundary-layer thickness and mass-heat transfer, that can be used by laser flow loop designers. 6 refs.

Thermal boundary layer due to sudden heating of fluid

NASA Astrophysics Data System (ADS)

Kurkal, K. R.; Munukutla, S.

1989-10-01

This paper proposes to solve computationally the heat-transfer problems (introduced by Munukutla and Venkataraman, 1988) related to a closed-cycle pulsed high-power laser flow loop. The continuity and the momentum equations as well as the unsteady energy equation are solved using the Keller-Box method. The solutions were compared with the steady-state solutions at large times, and the comparison was found to be excellent. Empirical formulas are proposed for calculating the time-dependent boundary-layer thickness and mass-heat transfer, that can be used by laser flow loop designers.

Heat and mass transfer analysis of unsteady MHD nanofluid flow through a channel with moving porous walls and medium

NASA Astrophysics Data System (ADS)

Zubair Akbar, Muhammad; Ashraf, Muhammad; Farooq Iqbal, Muhammad; Ali, Kashif

2016-04-01

The paper presents the numerical study of heat and mass transfer analysis in a viscous unsteady MHD nanofluid flow through a channel with porous walls and medium in the presence of metallic nanoparticles. The two cases for effective thermal conductivity are discussed in the analysis through H-C model. The impacts of the governing parameters on the flow, heat and mass transfer aspects of the issue are talked about. Under the patronage of small values of permeable Reynolds number and relaxation/contraction parameter, we locate that, when wall contraction is together with suction, flow turning is encouraged close to the wall where the boundary layer is shaped. On the other hand, when the wall relaxation is coupled with injection, the flow adjacent to the porous walls decreased. The outcome of the exploration may be beneficial for applications of biotechnology. Numerical solutions for the velocity, heat and mass transfer rate at the boundary are obtained and analyzed.

Dynamic Mass Transfer of Hemoglobin at the Aqueous/Ionic-Liquid Interface Monitored with Liquid Core Optical Waveguide.

PubMed

Chen, Xuwei; Yang, Xu; Zeng, Wanying; Wang, Jianhua

2015-08-04

Protein transfer from aqueous medium into ionic liquid is an important approach for the isolation of proteins of interest from complex biological samples. We hereby report a solid-cladding/liquid-core/liquid-cladding sandwich optical waveguide system for the purpose of monitoring the dynamic mass-transfer behaviors of hemoglobin (Hb) at the aqueous/ionic liquid interface. The optical waveguide system is fabricated by using a hydrophobic IL (1,3-dibutylimidazolium hexafluorophosphate, BBimPF6) as the core, and protein solution as one of the cladding layer. UV-vis spectra are recorded with a CCD spectrophotometer via optical fibers. The recorded spectra suggest that the mass transfer of Hb molecules between the aqueous and ionic liquid media involve accumulation of Hb on the aqueous/IL interface followed by dynamic extraction/transfer of Hb into the ionic liquid phase. A part of Hb molecules remain at the interface even after the accomplishment of the extraction/transfer process. Further investigations indicate that the mass transfer of Hb from aqueous medium into the ionic liquid phase is mainly driven by the coordination interaction between heme group of Hb and the cationic moiety of ionic liquid, for example, imidazolium cation in this particular case. In addition, hydrophobic interactions also contribute to the transfer of Hb.

Thermocapillary convection of melts and its role in laser-plasma synthesis and laser-induced amorphism

NASA Astrophysics Data System (ADS)

Uglov, A. A.; Smurov, I. Iu.; Gus'kov, A. G.; Semakhin, S. A.

1987-06-01

The role of thermocapillary convection in mass transfer processes in melts is investigated analytically and experimentally using vacuum-arc melted Ni63-Ta37 and Cu50-Zr50 alloys. It is shown that thermocapillary convection not only leads to the transfer of alloying components to the deeper layers of the melt but also may produce, in certain cases, a significant temperature redistribution in the liquid phase. Convective transfer dominates over conduction when the product of Re and Pr is greater than 1. In the experiments, the structure of the amorphous and crystalline layers in the solidified alloys is found to be in qualitative agreement with the structure of a thermocapillary vortex.

Stripping analysis of nanomolar perchlorate in drinking water with a voltammetric ion-selective electrode based on thin-layer liquid membrane.

PubMed

Kim, Yushin; Amemiya, Shigeru

2008-08-01

A highly sensitive analytical method is required for the assessment of nanomolar perchlorate contamination in drinking water as an emerging environmental problem. We developed the novel approach based on a voltammetric ion-selective electrode to enable the electrochemical detection of "redox-inactive" perchlorate at a nanomolar level without its electrolysis. The perchlorate-selective electrode is based on the submicrometer-thick plasticized poly(vinyl chloride) membrane spin-coated on the poly(3-octylthiophene)-modified gold electrode. The liquid membrane serves as the first thin-layer cell for ion-transfer stripping voltammetry to give low detection limits of 0.2-0.5 nM perchlorate in deionized water, commercial bottled water, and tap water under a rotating electrode configuration. The detection limits are not only much lower than the action limit (approximately 246 nM) set by the U.S. Environmental Protection Agency but also are comparable to the detection limits of the most sensitive analytical methods for detecting perchlorate, that is, ion chromatography coupled with a suppressed conductivity detector (0.55 nM) or electrospray ionization mass spectrometry (0.20-0.25 nM). The mass transfer of perchlorate in the thin-layer liquid membrane and aqueous sample as well as its transfer at the interface between the two phases were studied experimentally and theoretically to achieve the low detection limits. The advantages of ion-transfer stripping voltammetry with a thin-layer liquid membrane against traditional ion-selective potentiometry are demonstrated in terms of a detection limit, a response time, and selectivity.

MHD Forced Convective Laminar Boundary Layer Flow from a Convectively Heated Moving Vertical Plate with Radiation and Transpiration Effect

PubMed Central

Uddin, Md. Jashim; Khan, Waqar A.; Ismail, A. I. Md.

2013-01-01

A two-dimensional steady forced convective flow of a Newtonian fluid past a convectively heated permeable vertically moving plate in the presence of a variable magnetic field and radiation effect has been investigated numerically. The plate moves either in assisting or opposing direction to the free stream. The plate and free stream velocities are considered to be proportional to whilst the magnetic field and mass transfer velocity are taken to be proportional to where is the distance along the plate from the leading edge of the plate. Instead of using existing similarity transformations, we use a linear group of transformations to transform the governing equations into similarity equations with relevant boundary conditions. Numerical solutions of the similarity equations are presented to show the effects of the controlling parameters on the dimensionless velocity, temperature and concentration profiles as well as on the friction factor, rate of heat and mass transfer. It is found that the rate of heat transfer elevates with the mass transfer velocity, convective heat transfer, Prandtl number, velocity ratio and the magnetic field parameters. It is also found that the rate of mass transfer enhances with the mass transfer velocity, velocity ratio, power law index and the Schmidt number, whilst it suppresses with the magnetic field parameter. Our results are compared with the results existing in the open literature. The comparisons are satisfactory. PMID:23741295

Dissolution of Si in Molten Al with Gas Injection

NASA Astrophysics Data System (ADS)

Seyed Ahmadi, Mehran

Silicon is an essential component of many aluminum alloys, as it imparts a range of desirable characteristics. However, there are considerable practical difficulties in dissolving solid Si in molten Al, because the dissolution process is slow, resulting in material and energy losses. It is thus essential to examine Si dissolution in molten Al, to identify means of accelerating the process. This thesis presents an experimental study of the effect of Si purity, bath temperature, fluid flow conditions, and gas stirring on the dissolution of Si in molten Al, plus the results of physical and numerical modeling of the flow to corroborate the experimental results. The dissolution experiments were conducted in a revolving liquid metal tank to generate a bulk velocity, and gas was introduced into the melt using top lance injection. Cylindrical Si specimens were immersed into molten Al for fixed durations, and upon removal the dissolved Si was measured. The shape and trajectory of injected bubbles were examined by means of auxiliary water experiments and video recordings of the molten Al free surface. The gas-agitated liquid was simulated using the commercial software FLOW-3D. The simulation results provide insights into bubble dynamics and offer estimates of the fluctuating velocities within the Al bath. The experimental results indicate that the dissolution rate of Si increases in tandem with the melt temperature and bulk velocity. A higher bath temperature increases the solubility of Si at the solid/liquid interface, resulting in a greater driving force for mass transfer, and a higher liquid velocity decreases the resistance to mass transfer via a thinner mass boundary layer. Impurities (with lower diffusion coefficients) in the form of inclusions obstruct the dissolution of the Si main matrix. Finally, dissolution rate enhancement was observed by gas agitation. It is postulated that the bubble-induced fluctuating velocities disturb the mass boundary layer, which increases the mass transfer rate. Correlations derived for mass transfer from solids in liquids under various operating conditions were applied to the Al--Si system. A new correlation for combined natural and forced convection mass transfer from vertical cylinders in cross flow is presented, and a modification is proposed to take into account free stream turbulence in a correlation for forced convection mass transfer from vertical cylinders in cross flow.

RECOVERY FROM GIANT ERUPTIONS IN VERY MASSIVE STARS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kashi, Amit; Davidson, Kris; Humphreys, Roberta M., E-mail: kashi@astro.umn.edu

2016-01-20

We use a hydro-and-radiative-transfer code to explore the behavior of a very massive star (VMS) after a giant eruption—i.e., following a supernova impostor event. Beginning with reasonable models for evolved VMSs with masses of 80 M{sub ⊙} and 120 M{sub ⊙}, we simulate the change of state caused by a giant eruption via two methods that explicitly conserve total energy. (1) Synthetically removing outer layers of mass of a few M{sub ⊙} while reducing the energy of the inner layers. (2) Synthetically transferring energy from the core to the outer layers, an operation that automatically causes mass ejection. Our focus is onmore » the aftermath, not the poorly understood eruption itself. Then, using a radiation-hydrodynamic code in 1D with realistic opacities and convection, the interior disequilibrium state is followed for about 200 years. Typically the star develops a ∼400 km s{sup −1} wind with a mass loss rate that begins around 0.1 M{sub ⊙} yr{sup −1} and gradually decreases. This outflow is driven by κ-mechanism radial pulsations. The 1D models have regular pulsations but 3D models will probably be more chaotic. In some cases a plateau in the mass-loss rate may persist about 200 years, while other cases are more like η Car which lost >10 M{sub ⊙} and then had an abnormal mass loss rate for more than a century after its eruption. In our model, the post-eruption outflow carried more mass than the initial eruption. These simulations constitute a useful preliminary reconnaissance for 3D models which will be far more difficult.« less

Conditions for shock revival by neutrino heating in core-collapse supernovae

NASA Astrophysics Data System (ADS)

Janka, H.-Th.

2001-03-01

Energy deposition by neutrinos can rejuvenate the stalled bounce shock and can provide the energy for the supernova explosion of a massive star. This neutrino-heating mechanism, though investigated by numerical simulations and analytic studies, is not finally accepted or proven as the trigger of the explosion. Part of the problem is that different groups have obtained seemingly discrepant results, and the complexity of the hydrodynamic models often hampers a clear and simple interpretation of the results. This demands a deeper theoretical understanding of the requirements of a successful shock revival. A toy model is developed here for discussing the neutrino heating phase analytically. The neutron star atmosphere between the neutrinosphere and the supernova shock can well be considered to be in hydrostatic equilibrium, with a layer of net neutrino cooling below the gain radius and a layer of net neutrino heating above. Since the mass infall rate to the shock is in general different from the rate at which gas is advected into the neutron star, the mass in the gain layer varies with time. Moreover, the gain layer receives additional energy input by neutrinos emitted from the neutrinosphere and the cooling layer. Therefore the determination of the shock evolution requires a time-dependent treatment. To this end the hydrodynamical equations of continuity and energy are integrated over the volume of the gain layer to obtain conservation laws for the total mass and energy in this layer. The radius and velocity of the supernova shock can then be calculated from global properties of the gain layer as solutions of an initial value problem, which expresses the fact that the behavior of the shock is controlled by the cumulative effects of neutrino heating and mass accumulation in the gain layer. The described toy model produces steady-state accretion and mass outflow from the nascent neutron star as special cases. The approach is useful to illuminate the conditions that can lead to delayed explosions and in this sense supplements detailed numerical simulations. On grounds of the model developed here, a criterion is derived for the requirements of shock revival. It confirms the existence of a minimum neutrino luminosity that is needed for shock expansion, but also demonstrates the importance of a sufficiently large mass infall rate to the shock. If the neutrinospheric luminosity or accretion rate by the shock are too low, the shock is weakened because the gain layer loses more mass than is resupplied by inflow. On the other hand, very high infall rates damp the shock expansion and above some threshold, the development of positive total energy in the neutrino-heating layer is prevented. Time-dependent solutions for the evolution of the gain layer show that the total specific energy transferred to nucleons by neutrinos is limited by about 1052 erg Msun-1 ( ~ 5 MeV per nucleon). This excludes the possibility of very energetic explosions by the neutrino-heating mechanism, because the typical mass in the gain layer is about 0.1 Msun and does not exceed a few tenths of a solar mass. The toy model also allows for a crude discussion of the global effects of convective energy transport in the neutrino-heating layer. Transfer of energy from the region of maximum heating to radii closer behind the shock mainly reduces the loss of energy by the inward flow of neutrino-heated matter through the gain radius.

Effect of flowing sodium on corrosion and tensile properties of AISI type 316LN stainless steel at 823 K

NASA Astrophysics Data System (ADS)

Sivai Bharasi, N.; Thyagarajan, K.; Shaikh, H.; Balamurugan, A. K.; Bera, Santanu; Kalavathy, S.; Gurumurthy, K.; Tyagi, A. K.; Dayal, R. K.; Rajan, K. K.; Khatak, H. S.

2008-07-01

AISI type 316LN stainless steel was exposed to flowing sodium in mass transfer loop (MTL) at 823 K for 16 000 h and then examined for changes in the tensile properties due to the mass transfer and corrosion effects. Comparisons in microstructural and mechanical properties were made between annealed, thermally aged and sodium exposed materials. Microstructural examination of thermally aged and sodium exposed materials revealed precipitation of carbides at the grain boundaries. The sodium exposed samples contained a degraded layer at the surface up to a depth of around 10 μm and a surface carburized layer of about 30 μm. There was about 15% increase in yield strength and a decrease of about 20% in ductility for the sodium exposed material vis-a-vis thermally aged material and this was attributed to carburization effects and microstructural changes.

Determination of the external mass transfer coefficient and influence of mixing intensity in moving bed biofilm reactors for wastewater treatment.

PubMed

Nogueira, Bruno L; Pérez, Julio; van Loosdrecht, Mark C M; Secchi, Argimiro R; Dezotti, Márcia; Biscaia, Evaristo C

2015-09-01

In moving bed biofilm reactors (MBBR), the removal of pollutants from wastewater is due to the substrate consumption by bacteria attached on suspended carriers. As a biofilm process, the substrates are transported from the bulk phase to the biofilm passing through a mass transfer resistance layer. This study proposes a methodology to determine the external mass transfer coefficient and identify the influence of the mixing intensity on the conversion process in-situ in MBBR systems. The method allows the determination of the external mass transfer coefficient in the reactor, which is a major advantage when compared to the previous methods that require mimicking hydrodynamics of the reactor in a flow chamber or in a separate vessel. The proposed methodology was evaluated in an aerobic lab-scale system operating with COD removal and nitrification. The impact of the mixing intensity on the conversion rates for ammonium and COD was tested individually. When comparing the effect of mixing intensity on the removal rates of COD and ammonium, a higher apparent external mass transfer resistance was found for ammonium. For the used aeration intensities, the external mass transfer coefficient for ammonium oxidation was ranging from 0.68 to 13.50 m d(-1) and for COD removal 2.9 to 22.4 m d(-1). The lower coefficient range for ammonium oxidation is likely related to the location of nitrifiers deeper in the biofilm. The measurement of external mass transfer rates in MBBR will help in better design and evaluation of MBBR system-based technologies. Copyright © 2015 Elsevier Ltd. All rights reserved.

On the possibility of control restoration in some inverse problems of heat and mass transfer

NASA Astrophysics Data System (ADS)

Bilchenko, G. G.; Bilchenko, N. G.

2016-11-01

The hypersonic aircraft permeable surfaces effective heat protection problems are considered. The physic-chemical processes (the dissociation and the ionization) in laminar boundary layer of compressible gas are appreciated in mathematical model. The statements of direct problems of heat and mass transfer are given: according to preset given controls it is necessary to compute the boundary layer mathematical model parameters and determinate the local and total heat flows and friction forces and the power of blowing system. The A.A.Dorodnicyn's generalized integral relations method has been used as calculation basis. The optimal control - the blowing into boundary layer (for continuous functions) was constructed as the solution of direct problem in extreme statement with the use of this approach. The statement of inverse problems are given: the control laws ensuring the preset given local heat flow and local tangent friction are restored. The differences between the interpolation and the approximation statements are discussed. The possibility of unique control restoration is established and proved (in the stagnation point). The computational experiments results are presented.

Sequential cryogen spraying for heat flux control at the skin surface

NASA Astrophysics Data System (ADS)

Majaron, Boris; Aguilar, Guillermo; Basinger, Brooke; Randeberg, Lise L.; Svaasand, Lars O.; Lavernia, Enrique J.; Nelson, J. Stuart

2001-05-01

Heat transfer rate at the skin-air interface is of critical importance for the benefits of cryogen spray cooling in combination with laser therapy of shallow subsurface skin lesions, such as port-wine stain birthmarks. With some cryogen spray devices, a layer of liquid cryogen builds up on the skin surface during the spurt, which may impair heat transfer across the skin surface due to relatively low thermal conductivity and potentially higher temperature of the liquid cryogen layer as compared to the spray droplets. While the mass flux of cryogen delivery can be adjusted by varying the atomizing nozzle geometry, this may strongly affect other spray properties, such as lateral spread (cone), droplet size, velocity, and temperature distribution. We present here first experiments with sequential cryogen spraying, which may enable accurate mass flux control through variation of spray duty cycle, while minimally affecting other spray characteristics. The observed increase of cooling rate and efficiency at moderate duty cycle levels supports the above described hypothesis of isolating liquid layer, and demonstrates a novel approach to optimization of cryogen spray devices for individual laser dermatological applications.

The stability of the boundary layer compressible gas with heat and mass transfer from the surface

NASA Astrophysics Data System (ADS)

Gaponov, S. A.; Terekhova, N. M.

2016-10-01

This work continues the research on modeling of the flow regime control in the compressible boundary layer. The effect of the distributed heat and mass transfer on the stability characteristics of the supersonic boundary layer at Mach number M = 5.35 is considered. The main attention is paid to modeling of acoustic disturbances both in conditions of a normal injection, when only the component of the average velocity V is nonzero, and the injection of other direction, including tangential one, when only the component U is nonzero at the wall. It is assumed that the effect of an injection of a homogeneous gas of the different temperature is similar to blowing of the gas of a different density, namely, blowing of the cold gas simulates blowing of the heavy gas and vice versa. Therefore in the present work this modeling is achieved by the change of a temperature factor (heating or cooling of the walls). There are the variant when the so-called locking regime when the velocity perturbations on the porous surface can be taken as zero.

Crossing turbulent boundaries: interfacial flux in environmental flows.

PubMed

Grant, Stanley B; Marusic, Ivan

2011-09-01

Advances in the visualization and prediction of turbulence are shedding new light on mass transfer in the turbulent boundary layer. These discoveries have important implications for many topics in environmental science and engineering, from the transport of earth-warming CO2 across the sea-air interface, to nutrient processing and sediment erosion in rivers, lakes, and the ocean, to pollutant removal in water and wastewater treatment systems. In this article we outline current understanding of turbulent boundary layer flows, with particular focus on coherent turbulence and its impact on mass transport across the sediment-water interface in marine and freshwater systems.

An Advection-Diffusion Concept for Solute Transport in Heterogeneous Unconsolidated Geological Deposits

NASA Astrophysics Data System (ADS)

Gillham, R. W.; Sudicky, E. A.; Cherry, J. A.; Frind, E. O.

1984-03-01

In layered permeable deposits with flow predominately parallel to the bedding, advection causes rapid solute transport in the more permeable layers. As the solute advances more rapidly in these layers, solute mass is continually transferred to the less permeable layers as a result of molecular diffusion due to the concentration gradient between the layers. The interlayer solute transfer causes the concentration to decline along the permeable layers at the expense of increasing the concentration in the less permeable layers, which produces strongly dispersed concentration profiles in the direction of flow. The key parameters affecting the dispersive capability of the layered system are the diffusion coefficients for the less permeable layers, the thicknesses of the layers, and the hydraulic conductivity contrasts between the layers. Because interlayer solute transfer by transverse molecular diffusion is a time-dependent process, the advection-diffusion concept predicts a rate of longitudinal spreading during the development of the dispersion process that is inconsistent with the classical Fickian dispersion model. A second consequence of the solute-storage effect offered by transverse diffusion into low-permeability layers is a rate of migration of the frontal portion of a contaminant in the permeable layers that is less than the groundwater velocity. Although various lines of evidence are presented in support of the advection-diffusion concept, more work is required to determine the range of geological materials for which it is applicable and to develop mathematical expressions that will make it useful as a predictive tool for application to field cases of contaminant migration.

Energy transfer through a multi-layer liner for shaped charges

DOEpatents

Skolnick, Saul; Goodman, Albert

1985-01-01

This invention relates to the determination of parameters for selecting materials for use as liners in shaped charges to transfer the greatest amount of energy to the explosive jet. Multi-layer liners constructed of metal in shaped charges for oil well perforators or other applications are selected in accordance with the invention to maximize the penetrating effect of the explosive jet by reference to four parameters: (1) Adjusting the explosive charge to liner mass ratio to achieve a balance between the amount of explosive used in a shaped charge and the areal density of the liner material; (2) Adjusting the ductility of each layer of a multi-layer liner to enhance the formation of a longer energy jet; (3) Buffering the intermediate layers of a multi-layer liner by varying the properties of each layer, e.g., composition, thickness, ductility, acoustic impedance and areal density, to protect the final inside layer of high density material from shattering upon impact of the explosive force and, instead, flow smoothly into a jet; and (4) Adjusting the impedance of the layers in a liner to enhance the transmission and reduce the reflection of explosive energy across the interface between layers.

Magneto-hydrodynamics of coupled fluid-sheet interface with mass suction and blowing

NASA Astrophysics Data System (ADS)

Ahmad, R.

2016-01-01

There are large number of studies which prescribe the kinematics of the sheet and ignore the sheet's mechanics. However, the current boundary layer analysis investigates the mechanics of both the electrically conducting fluid and a permeable sheet, which makes it distinct from the other studies in the literature. One of the objectives of the current study is to (i) examine the behaviour of magnetic field effect for both the surface and the electrically conducting fluid (ii) investigate the heat and mass transfer between a permeable sheet and the surrounding electrically conducting fluid across the hydro, thermal and mass boundary layers. Self-similar solutions are obtained by considering the RK45 technique. Analytical solution is also found for the stretching sheet case. The skin friction dual solutions are presented for various types of sheet. The influence of pertinent parameters on the dimensionless velocity, shear stress, temperature, mass concentration, heat and mass transfer rates on the fluid-sheet interface is presented graphically as well as numerically. The obtained results are of potential benefit for studying the electrically conducting flow over various soft surfaces such as synthetic plastics, soft silicone sheet and soft synthetic rubber sheet. These surfaces are easily deformed by thermal fluctuations or thermal stresses.

Hot steam transfer through heat protective clothing layers.

PubMed

Rossi, René; Indelicato, Eric; Bolli, Walter

2004-01-01

The aim of this study was to analyse the transfer of steam through different types of textile layers as a function of sample parameters such as thickness and permeability. In order to simulate the human body, a cylinder releasing defined amounts of moisture was also used. The influence of sweating on heat and mass transfer was assessed. The results show that in general impermeable materials offer better protection against hot steam than semi-permeable ones. The transfer of steam depended on the water vapour permeability of the samples, but also on their thermal insulation and their thickness. Increasing the thickness of the samples with a spacer gave a larger increase in protection with the impermeable samples compared to semi-permeable materials. Measurements with pre-wetted samples showed a reduction in steam protection in any case. On the other hand, the measurements with a sweating cylinder showed a beneficial effect of sweating.

The mechanism and theoretical basis of the management of intensity of the heat transfer control through periodic influences on the turbulent boundary layer

NASA Astrophysics Data System (ADS)

Kovalnogov, Vladislav N.; Fedorov, Ruslan V.; Khakhaleva, Larisa V.; Chukalin, Andrey V.; Bondarenko, Aleksandr A.; Kovrizhnykh, Evgeny N.

2017-07-01

Generalization of classical model of a displacement way on the transfer of heat exchange and mass exchange of a stream in the boundary layer, confirmed by the control action of the different nature, is undertaken. Here are given the results of numerical research which have allowed explaining the mechanism, to reveal efficiency and limits of various ways of management of intensity in exchange processes. The possibility of management of intensity in processes of a thermolysis and friction by use of the perforated surface with the damping cavities is analyzed.

Heat and mass transfer analysis for paraffin/nitrous oxide burning rate in hybrid propulsion

NASA Astrophysics Data System (ADS)

Ben-Basat (Sisi), Shani; Gany, Alon

2016-03-01

This research presents a physical-mathematical model for the combustion of liquefying fuels in hybrid combustors, accounting for blowing effect on the heat transfer. A particular attention is given to a paraffin/nitrous oxide hybrid system. The use of a paraffin fuel in hybrid propulsion has been considered because of its much higher regression rate enabling significantly higher thrust compared to that of common polymeric fuels. The model predicts the overall regression rate (melting rate) of the fuel and the different mechanisms involved, including evaporation, entrainment of droplets of molten material, and mass loss due to melt flow on the condensed fuel surface. Prediction of the thickness and velocity of the liquid (melt) layer formed at the surface during combustion was done as well. Applying the model for an oxidizer mass flux of 45 kg/(s m2) as an example representing experimental range, it was found that 21% of the molten liquid undergoes evaporation, 30% enters the gas flow by the entrainment mechanism, and 49% reaches the end of the combustion chamber as a flowing liquid layer. When increasing the oxidizer mass flux in the port, the effect of entrainment increases while that of the flowing liquid layer along the surface shows a relatively lower contribution. Yet, the latter is predicted to have a significant contribution to the overall mass loss. In practical applications it may cause reduced combustion efficiency and should be taken into account in the motor design, e.g., by reinforcing the paraffin fuel with different additives. The model predictions have been compared to experimental results revealing good agreement.

Three dimensional rotating flow of Powell-Eyring nanofluid with non-Fourier's heat flux and non-Fick's mass flux theory

NASA Astrophysics Data System (ADS)

Ibrahim, Wubshet

2018-03-01

This article numerically examines three dimensional boundary layer flow of a rotating Powell-Eyring nanofluid. In modeling heat transfer processes, non-Fourier heat flux theory and for mass transfer non-Fick's mass flux theory are employed. This theory is recently re-initiated and it becomes the active research area to resolves some drawback associated with the famous Fourier heat flux and mass flux theory. The mathematical model of the flow problem is a system of non-linear partial differential equations which are obtained using the boundary layer analysis. The non-linear partial differential equations have been transformed into non-linear high order ordinary differential equations using similarity transformation. Employing bvp4c algorithm from matlab software routine, the numerical solution of the transformed ordinary differential equations is obtained. The governing equations are constrained by parameters such as rotation parameter λ , the non-Newtonian parameter N, dimensionless thermal relaxation and concentration relaxation parameters δt and δc . The impacts of these parameters have been discussed thoroughly and illustrated using graphs and tables. The findings show that thermal relaxation time δt reduces the thermal and concentration boundary layer thickness. Further, the results reveal that the rotational parameter λ has the effect of decreasing the velocity boundary layer thickness in both x and y directions. Further examination pinpoints that the skin friction coefficient along x-axis is an increasing and skin friction coefficient along y-axis is a decreasing function of rotation parameter λ . Furthermore, the non-Newtonian fluid parameter N has the characteristic of reducing the amount of local Nusselt numbers -f″ (0) and -g″ (0) both in x and y -directions.

Steady boundary layer slip flow along with heat and mass transfer over a flat porous plate embedded in a porous medium.

PubMed

Aziz, Asim; Siddique, J I; Aziz, Taha

2014-01-01

In this paper, a simplified model of an incompressible fluid flow along with heat and mass transfer past a porous flat plate embedded in a Darcy type porous medium is investigated. The velocity, thermal and mass slip conditions are utilized that has not been discussed in the literature before. The similarity transformations are used to transform the governing partial differential equations (PDEs) into a nonlinear ordinary differential equations (ODEs). The resulting system of ODEs is then reduced to a system of first order differential equations which was solved numerically by using Matlab bvp4c code. The effects of permeability, suction/injection parameter, velocity parameter and slip parameter on the structure of velocity, temperature and mass transfer rates are examined with the aid of several graphs. Moreover, observations based on Schmidt number and Soret number are also presented. The result shows, the increase in permeability of the porous medium increase the velocity and decrease the temperature profile. This happens due to a decrease in drag of the fluid flow. In the case of heat transfer, the increase in permeability and slip parameter causes an increase in heat transfer. However for the case of increase in thermal slip parameter there is a decrease in heat transfer. An increase in the mass slip parameter causes a decrease in the concentration field. The suction and injection parameter has similar effect on concentration profile as for the case of velocity profile.

Steady Boundary Layer Slip Flow along with Heat and Mass Transfer over a Flat Porous Plate Embedded in a Porous Medium

PubMed Central

Aziz, Asim; Siddique, J. I.; Aziz, Taha

2014-01-01

In this paper, a simplified model of an incompressible fluid flow along with heat and mass transfer past a porous flat plate embedded in a Darcy type porous medium is investigated. The velocity, thermal and mass slip conditions are utilized that has not been discussed in the literature before. The similarity transformations are used to transform the governing partial differential equations (PDEs) into a nonlinear ordinary differential equations (ODEs). The resulting system of ODEs is then reduced to a system of first order differential equations which was solved numerically by using Matlab bvp4c code. The effects of permeability, suction/injection parameter, velocity parameter and slip parameter on the structure of velocity, temperature and mass transfer rates are examined with the aid of several graphs. Moreover, observations based on Schmidt number and Soret number are also presented. The result shows, the increase in permeability of the porous medium increase the velocity and decrease the temperature profile. This happens due to a decrease in drag of the fluid flow. In the case of heat transfer, the increase in permeability and slip parameter causes an increase in heat transfer. However for the case of increase in thermal slip parameter there is a decrease in heat transfer. An increase in the mass slip parameter causes a decrease in the concentration field. The suction and injection parameter has similar effect on concentration profile as for the case of velocity profile. PMID:25531301

Thermal evolution of the high-pressure ice layers beneath a buried ocean within Titan and Ganymede

NASA Astrophysics Data System (ADS)

Choblet, G.; Tobie, G.

2015-12-01

Deep interiors of massive icy satellites such as Titan and Ganymede probably harbor a buried ocean above high-pressure (HP) ice layers. The nature and location of the lower interface of the ocean is ultimately controlled by the amount of heat transferred through the surface ice Ih layer but it also involves equilibration of heat and melt transfer in the HP ices. While the Rayleigh number associated to such HP ice layers is most probably supercritical, classical subsolidus convection might not be a viable mechanism as the radial temperature gradient in the cold boundary layer is likely to exceed the slope of the melting curve. A significant part of the heat transfer could be achieved via the mass flux of warm liquid through this cold boundary layer up to the global phase boundary, a phenomenon sometimes referred to as heat-pipe mechanism. We present 3D spherical simulations of thermal convection in these HP ice layers that address for the first time this complex interplay. First, scaling relationships are proposed to describe this configuration for a large range of Rayleigh numbers and solidus curves. We then focus on a more realistic set-up where a prescribed basal heat flux is considered in a plausible range for the thermal history of Ganymede or Titan together with the expected viscosity law for HP ices.

Stability analysis on the flow and heat transfer of nanofluid past a stretching/shrinking cylinder with suction effect

NASA Astrophysics Data System (ADS)

Bakar, Nor Ashikin Abu; Bachok, Norfifah; Arifin, Norihan Md.; Pop, Ioan

2018-06-01

The steady boundary layer flow over a stretching/shrinking cylinder with suction effect is numerically studied. Using a similarity transformations, the governing partial differential equations are transformed into a set of nonlinear differential equations and have been solved numerically using a bvp4c code in Matlab software. The nanofluid model used is taking into account the effects of Brownian motion and thermophoresis. The influences of the governing parameters namely the curvature parameter γ, mass suction parameter S, Brownian motion parameter Nb and thermophoresis parameter Nt on the flow, heat and mass transfers characteristics are presented graphically. The numerical results obtained for the skin friction coefficient, local Nusselt number and local Sherwood number are thoroughly determined and presented graphically for several values of the governing parameters. From our investigation, it is found that the non-unique (dual) solutions exist for a certain range of mass suction parameter. It is observed that as curvature parameter increases, the skin friction coefficient and heat transfer rate decrease, meanwhile the mass transfer rates increase. Moreover, the stability analysis showed that the first solution is linearly stable, while the second solution is linearly unstable.

Biofilms in 3D porous media: Delineating the influence of the pore network geometry, flow and mass transfer on biofilm development.

PubMed

Carrel, Maxence; Morales, Verónica L; Beltran, Mario A; Derlon, Nicolas; Kaufmann, Rolf; Morgenroth, Eberhard; Holzner, Markus

2018-05-01

This study investigates the functional correspondence between porescale hydrodynamics, mass transfer, pore structure and biofilm morphology during progressive biofilm colonization of a porous medium. Hydrodynamics and the structure of both the porous medium and the biofilm are experimentally measured with 3D particle tracking velocimetry and micro X-ray Computed Tomography, respectively. The analysis focuses on data obtained in a clean porous medium after 36 h of biofilm growth. Registration of the particle tracking and X-ray data sets allows to delineate the interplay between porous medium geometry, hydrodynamic and mass transfer processes on the morphology of the developing biofilm. A local analysis revealed wide distributions of wall shear stresses and concentration boundary layer thicknesses. The spatial distribution of the biofilm patches uncovered that the wall shear stresses controlled the biofilm development. Neither external nor internal mass transfer limitations were noticeable in the considered system, consistent with the excess supply of nutrient and electron acceptors. The wall shear stress remained constant in the vicinity of the biofilm but increased substantially elsewhere. Copyright © 2018 Elsevier Ltd. All rights reserved.

Effect of the universal acid-base indicator on the formation of the concentration-dependent diffusion instability

NASA Astrophysics Data System (ADS)

Mosheva, E. A.; Shmyrov, A. V.

2017-06-01

The effect of the universal acid-base indicator on the pattern formation and mass transfer in a two-layer system composed of two reactive miscible liquids in a vertical Hele-Shaw cell is studied experimentally. The reaction we study is a neutralization one. It turns out that the presence of the indicator leads to a change in the spatio-temporal characteristics of the system and even in the mass transfer mechanism near the reaction front—from diffusive to convective. The conditions, where the universal indicator does not affect the reaction and can be used as a visualizing mean, are reported.

Mass Transfer from Gas Bubbles to Impinging Flow of Biological Fluids with Chemical Reaction

PubMed Central

Yang, Wen-Jei; Echigo, R.; Wotton, D. R.; Ou, J. W.; Hwang, J. B.

1972-01-01

The rates of mass transfer from a gas bubble to an impinging flow of a biological fluid such as whole blood and plasma are investigated analytically and experimentally. Gases commonly found dissolved in body fluids are included. Consideration is given to the effects of the chemical reaction between the dissolved gas and the liquid on the rate of mass transfer. Through the application of boundary layer theory the over-all transfer is found to be Sh/(Re)1/2 = 0.845 Sc1/3 in the absence of chemical reaction, and Sh/(Re) 1/2 = F′ (0) in the presence of chemical reaction, where Sh, Re, and Sc are the Sherwood, Reynolds, and Schmidt numbers, respectively, and F′ (0) is a function of Sc and the dimensionless reaction rate constant. Analytical results are also obtained for the bubble lifetime and the bubble radius-time history. These results, which are not incompatible with experimental results, can be applied to predict the dissolution of the entrapped gas emboli in the circulatory system of the human body. PMID:4642218

Criteria for significance of simultaneous presence of both condensible vapors and aerosol particles on mass transfer (deposition) rates

NASA Technical Reports Server (NTRS)

Gokoglu, S. A.

1987-01-01

The simultaneous presence of aerosol particles and condensible vapors in a saturated boundary layer which may affect deposition rates to subcooled surfaces because of vapor-particle interactions is discussed. Scavenging of condensible vapors by aerosol particles may lead to increased particle size and decreased vapor mass fraction, which alters both vapor and particle deposition rates. Particles, if sufficiently concentrated, may also coagulate. Criteria are provided to assess the significance of such phenomena when particles are already present in the mainstream and are not created inside the boundary layer via homogeneous nucleation. It is determined that there is direct proportionality with: (1) the mass concentration of both condensible vapors and aerosol particles; and (2) the square of the boundary layer thickness to particle diameter ratio (delta d sub p) square. Inverse proportionality was found for mainstream to surface temperature difference if thermophoresis dominates particle transport. It is concluded that the square of the boundary layer thickness to particle diameter ratio is the most critical factor to consider in deciding when to neglect vapor-particle interactions.

Criteria for significance of simultaneous presence of both condensible vapors and aerosol particles on mass transfer (deposition) rates

NASA Technical Reports Server (NTRS)

Gokoglu, S. A.

1986-01-01

The simultaneous presence of aerosol particles and condensible vapors in a saturated boundary layer which may affect deposition rates to subcooled surfaces because of vapor-particle interactions is discussed. Scavenging of condensible vapors by aerosol particles may lead to increased particle size and decreased vapor mass fraction, which alters both vapor and particle deposition rates. Particles, if sufficiently concentrated, may also coagulate. Criteria are provided to assess the significance of such phenomena when particles are already present in the mainstream and are not created inside the boundary layer via homogeneous nucleation. It is determined that there is direct proportionality with: (1) the mass concentration of both condensible vapors and aerosol particles; and (2) the square of the boundary layer thickness to particle diameter ratio (delta d sub p) square. Inverse proportionality was found for mainstream to surface temperature difference if thermophoresis dominates particle transport. It is concluded that the square of the boundary layer thickness to particle diameter ratio is the most critical factor to consider in deciding when to neglect vapor-particle interactions.

Numerical study of entropy generation and melting heat transfer on MHD generalised non-Newtonian fluid (GNF): Application to optimal energy

NASA Astrophysics Data System (ADS)

Iqbal, Z.; Mehmood, Zaffar; Ahmad, Bilal

2018-05-01

This paper concerns an application to optimal energy by incorporating thermal equilibrium on MHD-generalised non-Newtonian fluid model with melting heat effect. Highly nonlinear system of partial differential equations is simplified to a nonlinear system using boundary layer approach and similarity transformations. Numerical solutions of velocity and temperature profile are obtained by using shooting method. The contribution of entropy generation is appraised on thermal and fluid velocities. Physical features of relevant parameters have been discussed by plotting graphs and tables. Some noteworthy findings are: Prandtl number, power law index and Weissenberg number contribute in lowering mass boundary layer thickness and entropy effect and enlarging thermal boundary layer thickness. However, an increasing mass boundary layer effect is only due to melting heat parameter. Moreover, thermal boundary layers have same trend for all parameters, i.e., temperature enhances with increase in values of significant parameters. Similarly, Hartman and Weissenberg numbers enhance Bejan number.

Turbine Vane External Heat Transfer. Volume 1: Analytical and Experimental Evaluation of Surface Heat Transfer Distributions with Leading Edge Showerhead Film Cooling

NASA Technical Reports Server (NTRS)

Turner, E. R.; Wilson, M. D.; Hylton, L. D.; Kaufman, R. M.

1985-01-01

Progress in predictive design capabilities for external heat transfer to turbine vanes was summarized. A two dimensional linear cascade (previously used to obtain vane surface heat transfer distributions on nonfilm cooled airfoils) was used to examine the effect of leading edge shower head film cooling on downstream heat transfer. The data were used to develop and evaluate analytical models. Modifications to the two dimensional boundary layer model are described. The results were used to formulate and test an effective viscosity model capable of predicting heat transfer phenomena downstream of the leading edge film cooling array on both the suction and pressure surfaces, with and without mass injection.

Novel synthesis of highly durable and active Pt catalyst encapsulated in nitrogen containing carbon for polymer electrolyte membrane fuel cell

NASA Astrophysics Data System (ADS)

Lee, Hyunjoon; Sung, Yung-Eun; Choi, Insoo; Lim, Taeho; Kwon, Oh Joong

2017-09-01

Novel synthesis of a Pt catalyst encapsulated in a N-containing carbon layer for use in a polymer electrolyte membrane fuel cell is described in this study. A Pt-aniline complex, formed by mixing Pt precursor and aniline monomer, was used as the source of Pt, C, and N. Heat treatment of the Pt-aniline complex with carbon black yielded 5 nm Pt nanoparticles encapsulated by a N-containing carbon layer originating from aniline carbonization. The synthesized Pt catalyst exhibited higher mass specific activity to oxygen reduction reaction than that shown by conventional Pt/C catalyst because pyridinic N with graphitic carbon in the carbon layer provided active sites for oxygen reduction reaction in addition to those provided by Pt. In single cell testing, initial performance of the synthesized catalyst was limited because the thick catalyst layer increased resistance related to mass transfer. However, it was observed that the carbon layer successfully prevented Pt nanoparticles from growing via agglomeration and Ostwald ripening under fuel cell operation, thereby improving durability. Furthermore, a mass specific performance of the synthesized catalyst higher than that of a conventional Pt/C catalyst was achieved by modifying the synthesized catalyst's layer thickness.

A brief description of the simple biosphere model (SiB)

NASA Technical Reports Server (NTRS)

Sellers, P. J.; Mintz, Y.; Sud, Y. C.

1986-01-01

A biosphere model for calculating the transfer of energy, mass, and momentum between the atmosphere and the vegetated surface of the Earth was designed for atmospheric general circulation models. An upper vegetation layer represents the perennial canopy of trees or shrubs, a lower layer represents the annual ground cover of grasses and other herbacious species. The local coverage of each vegetation layer may be fractional or complete but as the individual vegetation elements are considered to be evenly spaced, their root systems are assumed to extend uniformly throughout the entire grid-area. The biosphere has seven prognostic physical-state variables: two temperatures (one for the canopy and one for the ground cover and soil surface); two interception water stores (one for the canopy and one for the ground cover); and three soil moisture stores (two of which can be reached by the vegetation root systems and one underlying recharge layer into and out of which moisture is transferred only by hydraulic diffusion).

Freeze-drying in novel container system: Characterization of heat and mass transfer in glass syringes.

PubMed

Patel, Sajal M; Pikal, Michael J

2010-07-01

This study is aimed at characterizing and understanding different modes of heat and mass transfer in glass syringes to develop a robust freeze-drying process. Two different holder systems were used to freeze-dry in syringes: an aluminum (Al) block and a plexiglass holder. The syringe heat transfer coefficient was characterized by a sublimation test using pure water. Mannitol and sucrose (5% w/v) were also freeze-dried, as model systems, in both the assemblies. Dry layer resistance was determined from manometric temperature measurement (MTM) and product temperature was measured using thermocouples, and was also determined from MTM. Further, freeze-drying process was also designed using Smart freeze-dryer to assess its application for freeze-drying in novel container systems. Heat and mass transfer in syringes were compared against the traditional container system (i.e., glass tubing vial). In the Al block, the heat transfer was via three modes: contact conduction, gas conduction, and radiation with gas conduction being the dominant mode of heat transfer. In the plexiglass holder, the heat transfer was mostly via radiation; convection was not involved. Also, MTM/Smart freeze-drying did work reasonably well for freeze-drying in syringes. When compared to tubing vials, product temperature decreases and hence drying time increases in syringes. (c) 2010 Wiley-Liss, Inc. and the American Pharmacists Association

A comparative study on heat and mass transfer of the Blasius and Falkner-Skan flow of a bio-convective Casson fluid past a wedge

NASA Astrophysics Data System (ADS)

Raju, C. S. K.; Sandeep, N.

2016-11-01

Nowadays, many theoretical models are available for analyzing the heat and mass transfer of flows through different geometries. Nevertheless, it is challenging for researchers to choose among these models, the most suitable for a particular geometry. In addition to this, the extrinsic magnetic field is capable to set the thermal and physical properties of magnetic fluids and regulate the flow and heat transfer characteristics. The strength of the applied magnetic field affects the thermal conductivity of the fluids and makes it anisotropic. With this incentive, we attempt to study the thermophoresis and Brownian motion effects on the magnetohydrodynamic radiative Casson fluid flow over a wedge filled with gyrotactic microorganisms by considering the Blasius and Falkner-Skan models. Numerical solutions are offered graphically as well as in tabular form with the aid of Runge-Kutta and Newton's methods. Results for Blasius and Falkner-Skan flow cases are exhibited through plots for the parameters of concern. For real life applications, we also calculated the heat and mass transfer rates. It is observed that thermal and concentration boundary layers are not uniform for Falkner-Skan and Blasius flow cases. It is also observed that the heat and mass transfer rate is high in Falkner-Skan flow when compared with Blasius flow.

Diffusive boundary layers at the bottom of gaps and cracks

NASA Astrophysics Data System (ADS)

Etzold, Merlin A.; Landel, Julien R.; Dalziel, Stuart B.

2017-11-01

This work is motivated by the chemical decontamination of droplets of chemical warfare agents trapped in the gaps and cracks found in most man-made objects. We consider axial laminar flow within gaps with both straight and angled walls. We study the diffusive mass transfer from a source (e.g. a droplet surface) located at the bottom of the gap. This problem is similar to boundary layers and Graetz-type problems (heat transfer in pipe flow) with the added complication of a non-uniform lateral concentration profile due to the lateral variation of the velocity profile. We present 3D solutions for the diffusive boundary layer and demonstrate that a 2D mean-field model, for which we calculate series and similarity solutions, captures the essential physics. We demonstrate the immediate practical relevance of our findings by comparing decontamination of a droplet located in a gap and on an exposed surface.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reshetenko, T. V.; Bender, G.; Bethune, K.

The overall current density that is measured in a proton exchange membrane fuel cell (PEMFC) represents the average of the local reaction rates. The overall and local PEMFC performances are determined by several primary loss mechanisms, namely activation, ohmic, and mass transfer. Spatial performance and loss variabilities are significant and depend on the cell design and operating conditions. A segmented cell system was used to quantify different loss distributions along the gas channel to understand the effects of gas humidification. A reduction in the reactant stream humidification decreased cell performance and resulted in non-uniform distributions of overpotentials and performance alongmore » the flow field. Activation and ohmic overpotentials increased with a relative humidity decrease due to insufficient membrane and catalyst layer hydration. The relative humidity of the cathode had a strong impact on the mass transfer overpotential due to a lower oxygen permeability through the dry Nafion film covering the catalyst surface. The mass transfer loss distribution was non-uniform, and the mass transfer overpotential increased for the outlet segments due to the oxygen consumption at the inlet segments, which reduced the oxygen concentration downstream, and a progressive water accumulation from upstream segments. Electrochemical impedance spectroscopy (EIS) and an equivalent electric circuit (EEC) facilitated the analysis and interpretation of the segmented cell data.« less

Instability of fluid flow over saturated porous medium

NASA Astrophysics Data System (ADS)

Lyubimova, Tatyana; Kolchanova, Ekaterina; Lyubimov, Dmitry

2013-04-01

We investigate the stability of a fluid flow over a saturated porous medium. The problem is of importance due to the applications to washing out of contaminants from the bottom layer of vegetation, whose properties are similar to the properties of porous medium. In the case of porous medium with the relatively high permeability and porosity the flow involves a part of the fluid saturating the porous medium, with the tangential fluid velocity drop occurring because of the resistance of the solid matrix. The drop leads to the instability analogous to Kelvin-Helmholtz one accompanied by the formation of travelling waves. In the present paper we consider a two-layer system consisting of a pure fluid layer and a porous layer saturated by the fluid located underneath. The system is bounded by a rigid surface at the bottom and a non-deformable free surface at the top. It is under the gravity and inclined at a slight angle to the horizontal axis. The boundary conditions at the interface between the fluid and porous layers are the continuity of fluid velocities and the balance of normal and tangential stresses taking into account the resistance of the solid matrix with respect to the fluid flow near the interface [1-2]. The problem is solved in the framework of the Brinkman model applying the classical shooting algorithm with orthogonalization. The stability boundaries of the stationary fluid flow over the saturated porous medium with respect to the small oscillatory perturbations are obtained for the various values of the Darcy number and the ratio of the porous layer thickness to the full thickness of the system d. It was shown that at the d > 0.5 with increasing the porous layer thickness (or with decreasing of the fluid layer thickness) the stability threshold rises. This is because of the fact that the instability is primarily caused by perturbations located in the fluid layer. At the d < 0.5 the reduction of the porous layer thickness leads to the stability threshold growth. The numerical calculations were also conducted for nonlinear regimes of the flow applying the finite-element method. Flow characteristics are determined at supercritical values of parameters. The work was made under the financial support of Russian Foundation for Basic Research (Grant 12-01-00795). 1. Ochoa-Tapia J. A. and Whitaker S. Momentum transfer at the boundary between a porous medium and a homogeneous fluid-I. Theoretical development. Int. J. Heat Mass Transfer. 1995. N 38. P. 2635-2646. 2. Ochoa-Tapia J. A. and Whitaker S. Momentum transfer at the boundary between a porous medium and a homogeneous fluid-II. Comparison with experiment. Int. J. Heat Mass Transfer. 1995. N 38. P. 2647-2655.

Transfer Kinetics at the Aqueous/Non-Aqueous Phase Liquid Interface. A Statistical Mechanic Approach

NASA Astrophysics Data System (ADS)

Doss, S. K.; Ezzedine, S.; Ezzedine, S.; Ziagos, J. P.; Hoffman, F.; Gelinas, R. J.

2001-05-01

Many modeling efforts in the literature use a first-order, linear-driving-force model to represent the chemical dissolution process at the non-aqueous/aqueous phase liquid (NAPL/APL) interface. In other words, NAPL to APL phase flux is assumed to be equal to the difference between the solubility limit and the "bulk aqueous solution" concentrations times a mass transfer coefficient. Under such assumptions, a few questions are raised: where, in relation to a region of pure NAPL, does the "bulk aqueous solution" regime begin and how does it behave? The answers are assumed to be associated with an arbitrary, predetermined boundary layer, which separates the NAPL from the surrounding solution. The mass transfer rate is considered to be, primarily, limited by diffusion of the component through the boundary layer. In fact, compositional models of interphase mass transfer usually assume that a local equilibrium is reached between phases. Representing mass flux as a rate-limiting process is equivalent to assuming diffusion through a stationary boundary layer with an instantaneous local equilibrium and linear concentration profile. Some environmental researchers have enjoyed success explaining their data using chemical engineering-based correlations. Correlations are strongly dependent on the experimental conditions employed. A universally applicable theory for NAPL dissolution in natural systems does not exist. These correlations are usually expressed in terms of the modified Sherwood number as a function of Reynolds, Peclet, and Schmidt numbers. The Sherwood number may be interpreted as the ratio between the grain size and the thickness of the Nernst stagnant film. In the present study, we show that transfer kinetics at the NAPL/APL interface under equilibrium conditions disagree with approaches based on the Nernst stagnant film concept. It is unclear whether local equilibrium assumptions used in current models are suitable for all situations.A statistical mechanic framework has been chosen to study the transfer kinetic processes at the microscale level. The rationale for our approach is based on both the activation energy of transfer of an ion and its velocity across the NAPL/APL interface. There are four major energies controlling the interfacial NAPL dissolution kinetics: (de)solvation energy, interfacial tension energy, electrostatic energy, and thermal fluctuation energy. Transfer of an ion across the NAPL/APL interface is accelerated by the viscous forces which can be described using the averaged Langevin master equation. The resulting energies and viscous forces were combined using the Boltzmann probability distribution. Asymptotic time limits of the resulting kinetics lead to instantaneous local equilibrium conditions that contradict the Nernst equilibrium equation. The NAPL/APL interface is not an ideal one: it does not conserve energy and heat. In our case the interface is treated as a thin film or slush zone that alters the thermodynamic variables. Such added zone, between the two phases, is itself a phase, and, therefore, the equilibrium does not occur between two phases but rather three. All these findings led us to develop a new non-linearly coupled flow and transport system of equations which is able to account for specific chemical dissolution processes and precludes the need for empirical mass-transfer parameters. Work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract W-7405-Eng-48.

Analysis of heat and mass transfer during condensation over a porous substrate.

PubMed

Balasubramaniam, R; Nayagam, V; Hasan, M M; Khan, L

2006-09-01

Condensing heat exchangers are important in many space applications for thermal and humidity control systems. The International Space Station uses a cooled fin surface to condense moisture from humid air that is blown over it. The condensate and the air are "slurped" into a system that separates air and water by centrifugal forces. The use of a cooled porous substrate is an attractive alternative to the fin where condensation and liquid/gas separation can be achieved in a single step. We analyze the heat and mass transfer during condensation of moisture from flowing air over such a cooled, flat, porous substrate. A fully developed regime is investigated for coupled mass, momentum and energy transport in the gas phase, and momentum and energy transport in the condensate layer on the porous substrate and through the porous medium.

Mechanisms of heat and mass transfer across a double-diffusive interface

NASA Astrophysics Data System (ADS)

Ko, B. H.; Smith, K. A.

1984-06-01

Flux measurements in an aqueous two-layer double-diffusive system using heat and NaCl confirmed the existence of a regime in which the ratio of the buoyancy fluxes (BFR) of salt and heat is independent of the stability ratio (R = beta(delta C)/alpha(delta T)). Linear analysis showed that the quiescent system can become unstable to small perturbations even when the lower layer is denser than the upper. If R is large, the most unstable mode presents as an oscillatory, antisymmetric pattern.

Heat and mass transfer in MHD free convection from a moving permeable vertical surface by a perturbation technique

NASA Astrophysics Data System (ADS)

Abdelkhalek, M. M.

2009-05-01

Numerical results are presented for heat and mass transfer effect on hydromagnetic flow of a moving permeable vertical surface. An analysis is performed to study the momentum, heat and mass transfer characteristics of MHD natural convection flow over a moving permeable surface. The surface is maintained at linear temperature and concentration variations. The non-linear coupled boundary layer equations were transformed and the resulting ordinary differential equations were solved by perturbation technique [Aziz A, Na TY. Perturbation methods in heat transfer. Berlin: Springer-Verlag; 1984. p. 1-184; Kennet Cramer R, Shih-I Pai. Magneto fluid dynamics for engineers and applied physicists 1973;166-7]. The solution is found to be dependent on several governing parameter, including the magnetic field strength parameter, Prandtl number, Schmidt number, buoyancy ratio and suction/blowing parameter, a parametric study of all the governing parameters is carried out and representative results are illustrated to reveal a typical tendency of the solutions. Numerical results for the dimensionless velocity profiles, the temperature profiles, the concentration profiles, the local friction coefficient and the local Nusselt number are presented for various combinations of parameters.

Transpiration and film cooling boundary layer computer program. Volume 2: Computer program and user's manual

NASA Technical Reports Server (NTRS)

Gloss, R. J.

1971-01-01

A finite difference turbulent boundary layer computer program which allows for mass transfer wall cooling and equilibrium chemistry effects is presented. The program is capable of calculating laminar or turbulent boundary layer solutions for an arbitrary ideal gas or an equilibrium hydrogen oxygen system. Either two dimensional or axisymmetric geometric configurations may be considered. The equations are solved, in nondimension-alized physical coordinates, using the implicit Crank-Nicolson technique. The finite difference forms of the conservation of mass, momentum, total enthalpy and elements equations are linearized and uncoupled, thereby generating easily solvable tridiagonal sets of algebraic equations. A detailed description of the computer program, as well as a program user's manual is provided. Detailed descriptions of all boundary layer subroutines are included, as well as a section defining all program symbols of principal importance. Instructions are then given for preparing card input to the program and for interpreting the printed output. Finally, two sample cases are included to illustrate the use of the program.

Analytical and numerical solutions for mass diffusion in a composite cylindrical body

NASA Astrophysics Data System (ADS)

Kumar, A.

1980-12-01

The analytical and numerical solution techniques were investigated to study moisture diffusion problems in cylindrical bodies that are assumed to be composed of a finite number of layers of different materials. A generalized diffusion model for an n-layer cylindrical body with discontinuous moisture content at the interfaces was developed and the formal solutions were obtained. The model is to be used for describing mass transfer rates of any composite body, such as an ear of corn which could be assumed of consisting two different layers: the inner core represents the woody cob and the outer cylinder represents the kernel layer. Data describing the fully exposed drying characteristics of ear corn at high air velocity were obtained under different drying conditions. Ear corns were modeled as homogeneous bodies since composite model did not improve the fit substantially. A computer program using multidimensional optimization technique showed that diffusivity was an exponential function of moisture content and an arrhenius function of temperature of drying air.

A simple 2D biofilm model yields a variety of morphological features.

PubMed

Hermanowicz, S W

2001-01-01

A two-dimensional biofilm model was developed based on the concept of cellular automata. Three simple, generic processes were included in the model: cell growth, internal and external mass transport and cell detachment (erosion). The model generated a diverse range of biofilm morphologies (from dense layers to open, mushroom-like forms) similar to those observed in real biofilm systems. Bulk nutrient concentration and external mass transfer resistance had a large influence on the biofilm structure.

Programmable Electrochemical Rectifier Based on a Thin-Layer Cell.

PubMed

Park, Seungjin; Park, Jun Hui; Hwang, Seongpil; Kwak, Juhyoun

2017-06-21

A programmable electrochemical rectifier based on thin-layer electrochemistry is described here. Both the rectification ratio and the response time of the device are programmable by controlling the gap distance of the thin-layer electrochemical cell, which is easily controlled using commercially available beads. One of the electrodes was modified using a ferrocene-terminated self-assembled monolayer to offer unidirectional charge transfers via soluble redox species. The thin-layer configuration provided enhanced mass transport, which was determined by the gap thickness. The device with the smallest gap thickness (∼4 μm) showed an unprecedented, high rectification ratio (up to 160) with a fast response time in a two-terminal configuration using conventional electronics.

A Water Model Study on Mixing Behavior of the Two-Layered Bath in Bottom Blown Copper Smelting Furnace

NASA Astrophysics Data System (ADS)

Shui, Lang; Cui, Zhixiang; Ma, Xiaodong; Jiang, Xu; Chen, Mao; Xiang, Yong; Zhao, Baojun

2018-05-01

The bottom-blown copper smelting furnace is a novel copper smelter developed in recent years. Many advantages of this furnace have been found, related to bath mixing behavior under its specific gas injection scheme. This study aims to use an oil-water double-phased laboratory-scale model to investigate the impact of industry-adjustable variables on bath mixing time, including lower layer thickness, gas flow rate, upper layer thickness and upper layer viscosity. Based on experimental results, an overall empirical relationship of mixing time in terms of these variables has been correlated, which provides the methodology for industry to optimize mass transfer in the furnace.

Vacuum drying of apples (cv. Golden Delicious): drying characteristics, thermodynamic properties, and mass transfer parameters

NASA Astrophysics Data System (ADS)

Nadi, Fatemeh; Tzempelikos, Dimitrios

2018-01-01

In this work, apples of cv. Golden Delicious were cut into slices that were 5 and 7 mm thick and then vacuum dried at 50, 60 and 70 °C and pressure of 0.02 bar. The thin layer model drying kinetics was studied, and mass transfer properties, specifically effective moisture diffusivity and convective mass transfer coefficient, were evaluated using the Fick's equation of diffusion. Also, thermodynamic parameters of the process, i.e. enthalpy (ΔH), entropy (ΔS) and Gibbs free energy (ΔG), were determined. Colour properties were evaluated as one of the important indicators of food quality and marketability. Determination of mass transfer parameters and thermodynamic properties of vacuum dried apple slices has not been discussed much in the literature. In conclusion, the Nadi's model fitted best the observed data that represent the drying process. Thermodynamic properties were determined based on the dependence of the drying constant of the Henderson and Pabis model on temperature, and it was concluded that the variation in drying kinetics depends on the energy contribution of the surrounding environment. The enthalpy and entropy diminished, while the Gibbs free energy increased with the increase of the temperature of drying; therefore, it was possible to verify that variation in the diffusion process in the apple during drying depends on energetic contributions of the environment. The obtained results showed that diffusivity increased for 69%, while the mass transfer coefficient increase was even higher, 75%, at the variation of temperature of 20 °C. The increase in the dimensionless Biot number was 20%.

Vacuum drying of apples (cv. Golden Delicious): drying characteristics, thermodynamic properties, and mass transfer parameters

NASA Astrophysics Data System (ADS)

Nadi, Fatemeh; Tzempelikos, Dimitrios

2018-07-01

In this work, apples of cv. Golden Delicious were cut into slices that were 5 and 7 mm thick and then vacuum dried at 50, 60 and 70 °C and pressure of 0.02 bar. The thin layer model drying kinetics was studied, and mass transfer properties, specifically effective moisture diffusivity and convective mass transfer coefficient, were evaluated using the Fick's equation of diffusion. Also, thermodynamic parameters of the process, i.e. enthalpy ( ΔH), entropy ( ΔS) and Gibbs free energy ( ΔG), were determined. Colour properties were evaluated as one of the important indicators of food quality and marketability. Determination of mass transfer parameters and thermodynamic properties of vacuum dried apple slices has not been discussed much in the literature. In conclusion, the Nadi's model fitted best the observed data that represent the drying process. Thermodynamic properties were determined based on the dependence of the drying constant of the Henderson and Pabis model on temperature, and it was concluded that the variation in drying kinetics depends on the energy contribution of the surrounding environment. The enthalpy and entropy diminished, while the Gibbs free energy increased with the increase of the temperature of drying; therefore, it was possible to verify that variation in the diffusion process in the apple during drying depends on energetic contributions of the environment. The obtained results showed that diffusivity increased for 69%, while the mass transfer coefficient increase was even higher, 75%, at the variation of temperature of 20 °C. The increase in the dimensionless Biot number was 20%.

Pore channel surface modification for enhancing anti-fouling membrane distillation

NASA Astrophysics Data System (ADS)

Qiu, Haoran; Peng, Yuelian; Ge, Lei; Villacorta Hernandez, Byron; Zhu, Zhonghua

2018-06-01

Membrane surface modification by forming a functional layer is an effective way to improve the anti-fouling properties of membranes; however, the additional layer and the potential blockage of bulk pores may increase the mass transfer resistance and reduce the permeability. In this study, we applied a novel method of preparing anti-fouling membranes for membrane distillation by dispersing graphene oxide (GO) on the channel surface of polyvinylidene fluoride membranes. The surface morphology and properties were characterized by scanning electron microscopy, atomic force microscope, and Fourier transform infrared spectrometry. Compared to the membrane surface modification by nanoparticles (e.g. SiO2), GO was mainly located on the pore surface of the membrane bulk, rather than being formed as an individual layer onto the membrane surface. The performance was evaluated via a direct-contact membrane distillation process with anionic and cationic surfactants as the foulants, separately. Compared to the pristine PVDF membrane, the anti-fouling behavior and distillate flux of the GO-modified membranes were improved, especially when using the anionic surfactant as the foulant. The enhanced anti-fouling performance can be attributed to the oxygen containing functional groups in GO and the healing of the membrane pore defects. This method may provide an effective route to manipulate membrane pore surface properties for anti-fouling separation without increasing mass transfer resistance.

Laboratory evaluation of thermal protective clothing performance upon hot liquid splash.

PubMed

Gholamreza, Farzan; Song, Guowen

2013-07-01

This study provides an understanding of heat and mass transfer through materials exposed to hot liquid splash, a relatively unexplored hazard in the safety clothing industry. Selected fabrics and layered systems were exposed to three hot liquids to study the effects of hot liquids and configuration. To explore the energy transfer mechanisms, a modified apparatus (based on ASTM F 2701-08) was developed to assess the protection performance provided by a fabric when exposed to a hot liquid. The modified test method allows measurement of the energy absorbed by the sensor, and with the use of a skin model, the time required to produce a second-degree burn injury was predicted. The preliminary testing demonstrated that mass transfer of the hot liquid through the fabric is the main factor contributing to burn injury. Key factors that determine the level of protection that a fabric system provides are summarized.

The fluid dynamics of a basaltic magma chamber replenished by influx of hot, dense ultrabasic magma

NASA Astrophysics Data System (ADS)

Huppert, Herbert E.; Sparks, R. Stephen J.

1981-09-01

This paper describes a fluid dynamical investigation of the influx of hot, dense ultrabasic magma into a reservoir containing lighter, fractionated basaltic magma. This situation is compared with that which develops when hot salty water is introduced under cold fresh water. Theoretical and empirical models for salt/water systems are adapted to develop a model for magmatic systems. A feature of the model is that the ultrabasic melt does not immediately mix with the basalt, but spreads out over the floor of the chamber, forming an independent layer. A non-turbulent interface forms between this layer and the overlying magma layer across which heat and mass are transferred by the process of molecular diffusion. Both layers convect vigorously as heat is transferred to the upper layer at a rate which greatly exceeds the heat lost to the surrounding country rock. The convection continues until the two layers have almost the same temperature. The compositions of the layers remain distinct due to the low diffusivity of mass compared to heat. The temperatures of the layers as functions of time and their cooling rate depend on their viscosities, their thermal properties, the density difference between the layers and their thicknesses. For a layer of ultrabasic melt (18% MgO) a few tens of metres thick at the base of a basaltic (10% MgO) magma chamber a few kilometres thick, the temperature of the layers will become nearly identical over a period of between a few months and a few years. During this time the turbulent convective velocities in the ultrabasic layer are far larger than the settling velocity of olivines which crystallise within the layer during cooling. Olivines only settle after the two layers have nearly reached thermal equilibrium. At this stage residual basaltic melt segregates as the olivines sediment in the lower layer. Depending on its density, the released basalt can either mix convectively with the overlying basalt layer, or can continue as a separate layer. The model provides an explanation for large-scale cyclic layering in basic and ultrabasic intrusions. The model also suggests reasons for the restriction of erupted basaltic liquids to compositions with MgO<10% and the formation of some quench textures in layered igneous rocks.

Boundary layers at a dynamic interface: Air-sea exchange of heat and mass

NASA Astrophysics Data System (ADS)

Szeri, Andrew J.

2017-04-01

Exchange of mass or heat across a turbulent liquid-gas interface is a problem of critical interest, especially in air-sea transfer of natural and anthropogenic gases involved in the study of climate. The goal in this research area is to determine the gas flux from air to sea or vice versa. For sparingly soluble nonreactive gases, this is controlled by liquid phase turbulent velocity fluctuations that act on the thin species concentration boundary layer on the liquid side of the interface. If the fluctuations in surface-normal velocity w' and gas concentration c' are known, then it is possible to determine the turbulent contribution to the gas flux. However, there is no suitable fundamental direct approach in the general case where neither w' nor c' can be easily measured. A new approach is presented to deduce key aspects about the near-surface turbulent motions from measurements that can be taken by an infrared (IR) camera. An equation is derived with inputs being the surface temperature and heat flux, and a solution method developed for the surface-normal strain experienced over time by boundary layers at the interface. Because the thermal and concentration boundary layers experience the same near-surface fluid motions, the solution for the surface-normal strain determines the gas flux or gas transfer velocity. Examples illustrate the approach in the cases of complete surface renewal, partial surface renewal, and insolation. The prospects for use of the approach in flows characterized by sheared interfaces or rapid boundary layer straining are explored.

Influence of Soret-Dufour and thermophoresis on hydromagnetic mixed convection heat and mass transfer over an inclined flat plate with non-uniform heat source/sink and chemical reaction

NASA Astrophysics Data System (ADS)

Pal, Dulal; Mondal, Hiranmoy

2018-03-01

The paper is devoted to the study of thermophoresis and Soret-Dufour effects on magnetohydrodynamic mixed convective heat and mass transfer over an inclined flat plate with non-uniform heat source/sink. Governing non-linear coupled ordinary differential equations are solved numerically using Runge-Kutta Fehlberg technique with shooting scheme. The effects of various physical parameters on the velocity, temperature, and concentration profiles are depicted graphically. The values of skin-friction coefficient, Nusselt number and Sherwood number are presented in a tabular form. It is found that increase in thermophoretic and chemical reaction parameters retard the velocity and concentration distributions in the boundary layer.

A mass transfer model of ethanol emission from thin layers of corn silage

USDA-ARS?s Scientific Manuscript database

Dairies may be important emission sources for volatile organic compounds (VOCs). Reactive organic gases (ROG) emissions from dairy farms are the second largest source responsible for ozone formation in the California’s San Joaquin Valley. Animal feed was found to be a major ROG emission source on da...

Accounting for Mass Transfer Kinetics when Modeling the Impact of Low Permeability Layers in a Groundwater Source Zone on Dissolved Contaminant Fate and Transport

DTIC Science & Technology

2014-03-27

Clay Interface) ...................................................................................................... 40 Figure 9: Time-Dependent...vs Constant Dissolution Rate BTCs (Monitoring Well in Clay ...pits, poured down sanitary sewer systems, and partially burned in fire training pits. Poor handling and disposal of chlorinated solvents have

Mathematical modeling of forest fire initiation in three dimensional setting

Treesearch

Valeriy Perminov

2007-01-01

In this study, the assignment and theoretical investigations of the problems of forest fire initiation were carried out, including development of a mathematical model for description of heat and mass transfer processes in overterrestrial layer of atmosphere at crown forest fire initiation, taking into account their mutual influence. Mathematical model of forest fire...

MERCURY REMOVAL FROM STACK GAS BY AQUEOUS SCRUBBING

EPA Science Inventory

Fundamental results will be obtained on the reaction kinetics in mass transfer boundary layers for the following systems:

Hg(g)/Cl2(g)/SO2(g)/sulfite
Hg(g)/ClO2(g)/SO2...

• Boundary layers at a dynamic interface: air-sea exchange of heat and mass

  NASA Astrophysics Data System (ADS)

  Szeri, Andrew

  2017-11-01

  Exchange of mass or heat across a turbulent liquid-gas interface is a problem of critical interest, especially in air-sea transfer of natural and man-made gases involved in climate change. The goal in this research area is to determine the gas flux from air to sea or vice versa. For sparingly soluble non-reactive gases, this is controlled by liquid phase turbulent velocity fluctuations that act on the thin species concentration boundary layer on the liquid side of the interface. If the fluctuations in surface-normal velocity and gas concentration differences are known, then it is possible to determine the turbulent contribution to the gas flux. However, there is no suitable fundamental direct approach in the general case where neither of these quantities can be easily measured. A new approach is presented to deduce key aspects about the near-surface turbulent motions from remote measurements, which allows one to determine the gas transfer velocity, or gas flux per unit area if overall concentration differences are known. The approach is illustrated with conceptual examples.

• Heat and mass transfer in combustion - Fundamental concepts and analytical techniques

  NASA Technical Reports Server (NTRS)

  Law, C. K.

  1984-01-01

  Fundamental combustion phenomena and the associated flame structures in laminar gaseous flows are discussed on physical bases within the framework of the three nondimensional parameters of interest to heat and mass transfer in chemically-reacting flows, namely the Damkoehler number, the Lewis number, and the Arrhenius number which is the ratio of the reaction activation energy to the characteristic thermal energy. The model problems selected for illustration are droplet combustion, boundary layer combustion, and the propagation, flammability, and stability of premixed flames. Fundamental concepts discussed include the flame structures for large activation energy reactions, S-curve interpretation of the ignition and extinctin states, reaction-induced local-similarity and non-similarity in boundary layer flows, the origin and removal of the cold boundary difficulty in modeling flame propagation, and effects of flame stretch and preferential diffusion on flame extinction and stability. Analytical techniques introduced include the Shvab-Zeldovich formulation, the local Shvab-Zeldovich formulation, flame-sheet approximation and the associated jump formulation, and large activation energy matched asymptotic analysis. Potentially promising research areas are suggested.

• Numerical model for a watering plan to wash out organic matter from the municipal solid waste incinerator bottom ash layer in closed system disposal facilities.

  PubMed

  Ishii, Kazuei; Furuichi, Toru; Tanikawa, Noboru

  2009-02-01

  Bottom ash from municipal solid waste incineration (MSWI) is a main type of waste that is landfilled in Japan. The long-term elution of organic matter from the MSWI bottom ash layers is a concern because maintenance and operational costs of leachate treatment facilities are high. In closed system disposal facilities (CSDFs), which have a roof to prevent rainfall from infiltrating into the waste layers, water must be supplied artificially and its quantity can be controlled. However, the quantity of water needed and how to apply it (the intensity, period and frequency) have not been clearly defined. In order to discuss an effective watering plan, this study proposes a new washout model to clarify a fundamental mechanism of total organic carbon (TOC) elution behavior from MSWI bottom ash layers. The washout model considers three phases: solid, immobile water and mobile water. The parameters, including two mass transfer coefficients of the solid-immobile water phases and immobile-mobile water phases, were determined by one-dimensional column experiments for about 2 years. The intensity, period and frequency of watering and other factors were discussed based on a numerical analysis using the above parameters. As a result, our washout model explained adequately the elution behavior of TOC from the MSWI bottom ash layer before carbonation occurred (pH approximately 8.3). The determined parameters and numerical analysis suggested that there is a possibility that the minimum amount of water needed for washing out TOC per unit weight of MSWI bottom ash layer could be determined, which depends on the two mass transfer coefficients and the depth of the MSWI bottom ash layer. Knowledge about the fundamental mechanism of the elution behavior of TOC from the MSWI bottom ash layer before carbonation occurs, clarified by this study, will help an effective watering plan in CSDFs.

• Mathematical modeling heat and mass transfer processes in porous media

  NASA Astrophysics Data System (ADS)

  Akhmed-Zaki, Darkhan

  2013-11-01

  On late development stages of oil-fields appears a complex problem of oil-recovery reduction. One of solution approaches is injecting of surfactant together with water in the form of active impurities into the productive layer - for decreasing oil viscosity and capillary forces between ``oil-water'' phases system. In fluids flow the surfactant can be in three states: dissolved in water, dissolved in oil and adsorbed on pore channels' walls. The surfactant's invasion into the reservoir is tracked by its diffusion with reservoir liquid and mass-exchange with two phase (liquid and solid) components of porous structure. Additionally, in this case heat exchange between fluids (injected, residual) and framework of porous medium has practical importance for evaluating of temperature influences on enhancing oil recovery. Now, the problem of designing an adequate mathematical model for describing a simultaneous flowing heat and mass transfer processes in anisotropic heterogeneous porous medium -surfactant injection during at various temperature regimes has not been fully researched. In this work is presents a 2D mathematical model of surfactant injections into the oil reservoir. Description of heat- and mass transfer processes in a porous media is done through differential and kinetic equations. For designing a computational algorithm is used modify version of IMPES method. The sequential and parallel computational algorithms are developed using an adaptive curvilinear meshes which into account heterogeneous porous structures. In this case we can evaluate the boundaries of our process flows - fronts (``invasion'', ``heat'' and ``mass'' transfers), according to the pressure, temperature, and concentration gradient changes.

• Radiative flow of Carreau liquid in presence of Newtonian heating and chemical reaction

  NASA Astrophysics Data System (ADS)

  Hayat, T.; Ullah, Ikram; Ahmad, B.; Alsaedi, A.

  Objective of this article is to investigate the magnetohydrodynamic (MHD) boundary layer stretched flow of Carreau fluid in the presence of Newtonian heating. Sheet is presumed permeable. Analysis is studied in the presence of chemical reaction and thermal radiation. Mathematical formulation is established by using the boundary layer approximations. The resultant nonlinear flow analysis is computed for the convergent solutions. Interval of convergence via numerical data and plots are obtained and verified. Impact of numerous pertinent variables on the velocity, temperature and concentration is outlined. Numerical data for surface drag coefficient, surface heat transfer (local Nusselt number) and mass transfer (local Sherwood number) is executed and inspected. Comparison of skin friction coefficient in limiting case is made for the verification of current derived solutions.

• Calculation of heat transfer on shuttle type configurations including the effects of variable entropy at boundary layer edge

  NASA Technical Reports Server (NTRS)

  Dejarnette, F. R.

  1972-01-01

  A relatively simple method is presented for including the effect of variable entropy at the boundary-layer edge in a heat transfer method developed previously. For each inviscid surface streamline an approximate shockwave shape is calculated using a modified form of Maslen's method for inviscid axisymmetric flows. The entropy for the streamline at the edge of the boundary layer is determined by equating the mass flux through the shock wave to that inside the boundary layer. Approximations used in this technique allow the heating rates along each inviscid surface streamline to be calculated independent of the other streamlines. The shock standoff distances computed by the present method are found to compare well with those computed by Maslen's asymmetric method. Heating rates are presented for blunted circular and elliptical cones and a typical space shuttle orbiter at angles of attack. Variable entropy effects are found to increase heating rates downstream of the nose significantly higher than those computed using normal-shock entropy, and turbulent heating rates increased more than laminar rates. Effects of Reynolds number and angles of attack are also shown.

• Combined liquid chromatography-mass spectrometry for trace analysis of pharmaceuticals

  NASA Astrophysics Data System (ADS)

  Schmidt, Lothar; Danigel, Harald; Jungclas, Hartmut

  1982-07-01

  A 252Cf-plasma desorption mass spectrometer (PDMS) for the analysis of thin layers from nonvolatile organic samples has been set up to be combined with a liquid chromatograph. A novel interface performs the direct inlet of the liquid sample through a capillary into the vacuum system of the spectrometer. Samples of drugs are periodically collected, transferred to the ion source and analysed using a rotating disk. This on-line sample preparation has been tested for three antiarrhythmic drugs using various solvents and mixtures.

• Non-conventional Pt-Cu alloy/carbon paper electrochemical catalyst formed by electrodeposition using hydrogen bubble as template

  NASA Astrophysics Data System (ADS)

  Kim, Youngkwang; Lee, Hyunjoon; Lim, Taeho; Kim, Hyun-Jong; Kwon, Oh Joong

  2017-10-01

  With emerging stability issues in fuel cell technology, a non-conventional catalyst not supported on carbon materials has been highlighted because it can avoid negative influences of carbon support materials on the stability, such as carbon corrosion. The nanostructured thin film catalyst is representative of non-conventional catalysts, which shows improved stability, enhanced mass specific activity, and fast mass transfer at high current densities. However, the nanostructured thin film catalyst usually requires multi-step processes for fabrication, making its mass production complex and irreproducible. We introduce a Pt-Cu alloy nanostructured thin film catalyst, which can be simply prepared by electrodeposition. By using hydrogen bubbles as a template, a three-dimensional free-standing foam of Cu was electrodeposited directly on the micro-porous layer/carbon paper and it was then displaced with Pt by simple immersion. The structure characterization revealed that a porous thin Pt-Cu alloy catalyst layer was successfully formed on the micro-porous layer/carbon paper. The synthesized Pt-Cu alloy catalyst exhibited superior durability compared to a conventional Pt/C in single cell test.

The origin and structure of streak-like instabilities in laminar boundary layer flames

NASA Astrophysics Data System (ADS)

Gollner, Michael; Miller, Colin; Tang, Wei; Finney, Mark

2017-11-01

Streamwise streaks are consistently observed in wildland fires, at the base of pool fires, and in other heated flows within a boundary layer. This study examines both the origin of these structures and their role in influencing some of the macroscopic properties of the flow. Streaks were reproduced and characterized via experiments on stationary heated strips and liquid and gas-fueled burners in laminar boundary layer flows, providing a framework to develop theory based on both observed and measured physical phenomena. The incoming boundary layer was established as the controlling mechanism in forming streaks, which are generated by pre-existing coherent structures, while the amplification of streaks was determined to be compatible with quadratic growth of Rayleigh-Taylor Instabilities, providing credence to the idea that the downstream growth of streaks is strongly tied to buoyancy. These local instabilities were also found to affect macroscopic properties of the flow, including heat transfer to the surface, indicating that a two-dimensional assumption may fail to adequately describe heat and mass transfer during flame spread and other reacting boundary layer flows. This work was supported by NSF (CBET-1554026) and the USDA-FS (13-CS-11221637-124).

Nonequilibrium electrokinetic effects in beds of ion-permselective particles.

PubMed

Leinweber, Felix C; Tallarek, Ulrich

2004-12-21

Electrokinetic transport of fluorescent tracer molecules in a bed of porous glass beads was investigated by confocal laser scanning microscopy. Refractive index matching between beads and the saturating fluid enabled a quantitative analysis of intraparticle and extraparticle fluid-side concentration profiles. Kinetic data were acquired for the uptake and release of electroneutral and counterionic tracer under devised conditions with respect to constant pressure-driven flow through the device and the effect of superimposed electrical fields. Transport of neutral tracer is controlled by intraparticle mass transfer resistance which can be strongly reduced by electroosmotic flow, while steady-state distributions and bead-averaged concentrations are unaffected by the externally applied fields. Electrolytes of low ionic strength caused the transport through the charged (mesoporous) beads to become highly ion-permselective, and concentration polarization is induced in the bulk solution due to the superimposed fields. The depleted concentration polarization zone comprises extraparticle fluid-side mass transfer resistance. Ionic concentrations in this diffusion boundary layer decrease at increasing field strength, and the flux densities approach an upper limit. Meanwhile, intraparticle transport of counterions by electromigration and electroosmosis continues to increase and finally exceeds the transport from bulk solution into the beads. A nonequilibrium electrical double layer is induced which consists of mobile and immobile space charge regions in the extraparticle bulk solution and inside a bead, respectively. These electrical field-induced space charges form the basis for nonequilibrium electrokinetic phenomena. Caused by the underlying transport discrimination (intraparticle electrokinetic vs extraparticle boundary-layer mass transfer), the dynamic adsorption capacity for counterions can be drastically reduced. Further, the extraparticle mobile space charge region leads to nonlinear electroosmosis. Flow patterns can become highly chaotic, and electrokinetic instability mixing is shown to increase lateral dispersion. Under these conditions, the overall axial dispersion of counterionic tracer can be reduced by more than 2 orders of magnitude, as demonstrated by pulse injections.

A Chemical-Adsorption Strategy to Enhance the Reaction Kinetics of Lithium-Rich Layered Cathodes via Double-Shell Surface Modification.

PubMed

Guo, Lichao; Li, Jiajun; Cao, Tingting; Wang, Huayu; Zhao, Naiqin; He, Fang; Shi, Chunsheng; He, Chunnian; Liu, Enzuo

2016-09-21

Sluggish surface reaction kinetics hinders the power density of Li-ion battery. Thus, various surface modification techniques have been applied to enhance the electronic/ionic transfer kinetics. However, it is challenging to obtain a continuous and uniform surface modification layer on the prime particles with structure integration at the interface. Instead of classic physical-adsorption/deposition techniques, we propose a novel chemical-adsorption strategy to synthesize double-shell modified lithium-rich layered cathodes with enhanced mass transfer kinetics. On the basis of experimental measurement and first-principles calculation, MoO2S2 ions are proved to joint the layered phase via chemical bonding. Specifically, the Mo-O or Mo-S bonds can flexibly rotate to bond with the cations in the layered phase, leading to the good compatibility between the thiomolybdate adsorption layer and layered cathode. Followed by annealing treatment, the lithium-excess-spinel inner shell forms under the thiomolybdate adsorption layer and functions as favorable pathways for lithium and electron. Meanwhile, the nanothick MoO3-x(SO4)x outer shell protects the transition metal from dissolution and restrains electrolyte decomposition. The double-shell modified sample delivers an enhanced discharge capacity almost twice as much as that of the unmodified one at 1 A g(-1) after 100 cycles, demonstrating the superiority of the surface modification based on chemical adsorption.

Modeling solute clustering in the diffusion layer around a growing crystal.

PubMed

Shiau, Lie-Ding; Lu, Yung-Fang

2009-03-07

The mechanism of crystal growth from solution is often thought to consist of a mass transfer diffusion step followed by a surface reaction step. Solute molecules might form clusters in the diffusion step before incorporating into the crystal lattice. A model is proposed in this work to simulate the evolution of the cluster size distribution due to the simultaneous aggregation and breakage of solute molecules in the diffusion layer around a growing crystal in the stirred solution. The crystallization of KAl(SO(4))(2)12H(2)O from aqueous solution is studied to illustrate the effect of supersaturation and diffusion layer thickness on the number-average degree of clustering and the size distribution of solute clusters in the diffusion layer.

Local measurement and numerical modeling of mass/heat transfer from a turbine blade in a linear cascade with tip clearance

NASA Astrophysics Data System (ADS)

Jin, Peitong

2000-11-01

Local mass/heat transfer measurements from the turbine blade near-tip and the tip surfaces are performed using the naphthalene sublimation technique. The experiments are conducted in a linear cascade consisting of five high-pressure blades with a central test-blade configuration. The incoming flow conditions are close to those of the gas turbine engine environment (boundary layer displacement thickness is about 0.01 of chord) with an exit Reynolds number of 6.2 x 105. The effects of tip clearance level (0.86%--6.90% of chord), mainstream Reynolds number and turbulence intensity (0.2 and 12.0%) are investigated. Two methods of flow visualization---oil and lampblack, laser light sheet smoke wire---as well as static pressure measurement on the blade surface are used to study the tip leakage flow and vortex in the cascade. In addition, numerical modeling of the flow and heat transfer processes in the linear cascade with different tip clearances is conducted using commercial software incorporating advanced turbulence models. The present study confirms many important results on the tip leakage flow and vortex from the literature, contributes to the current understanding in the effects of tip leakage flow and vortex on local heat transfer from the blade near-tip and the tip surfaces, and provides detailed local and average heat/mass transfer data applicable to turbine blade tip cooling design.

Operational parameters and their influence on particle-side mass transfer resistance in a packed bed bioreactor.

PubMed

Hussain, Amir; Kangwa, Martin; Yumnam, Nivedita; Fernandez-Lahore, Marcelo

2015-12-01

The influence of internal mass transfer on productivity as well as the performance of packed bed bioreactor was determined by varying a number of parameters; chitosan coating, flow rate, glucose concentration and particle size. Saccharomyces cerevisiae cells were immobilized in chitosan and non-chitosan coated alginate beads to demonstrate the effect on particle side mass transfer on substrate consumption time, lag phase and ethanol production. The results indicate that chitosan coating, beads size, glucose concentration and flow rate have a significant effect on lag phase duration. The duration of lag phase for different size of beads (0.8, 2 and 4 mm) decreases by increasing flow rate and by decreasing the size of beads. Moreover, longer lag phase were found at higher glucose medium concentration and also with chitosan coated beads. It was observed that by increasing flow rates; lag phase and glucose consumption time decreased. The reason is due to the reduction of external (fluid side) mass transfer as a result of increase in flow rate as glucose is easily transported to the surface of the beads. Varying the size of beads is an additional factor: as it reduces the internal (particle side) mass transfer by reducing the size of beads. The reason behind this is the distance for reactants to reach active site of catalyst (cells) and the thickness of fluid created layer around alginate beads is reduced. The optimum combination of parameters consisting of smaller beads size (0.8 mm), higher flow rate of 90 ml/min and glucose concentration of 10 g/l were found to be the maximum condition for ethanol production.

Temperature Rise in a Two-Layer Structure Induced by a Rotating or Dithering Laser Beam

DTIC Science & Technology

2012-01-01

References [1] G. Araya and G. Gutierrez, Analytical solution for a transient, three-dimensional temperature dis- tribution due to a moving laser...beam, Int. J. Heat and Mass Transfer 49 ( 2006 ), 4124-4131. [2] R. Bellman, R.E. Marshak, and G.M. Wing, Laplace transform solution of two-medium neutron

Mixing in wicking structures and the use of enhanced mixing within wicks in microchannel devices

DOEpatents

Stenkamp, Victoria S [Richland, WA; TeGrotenhuis, Ward E [Kennewick, WA; Wegeng, Robert S [Alexandria, VA

2009-06-02

Advanced wicking structures and methods utilizing these structures are described. The use of advanced wicking structures can promote rapid mass transfer while maintaining high capillary pressure through the use of small pores. Particularly improved results in fluid contacting processes can be achieved by enhanced mixing within a wicking layer within a microchannel.

Mixing in wicking structures and the use of enhanced mixing within wicks in microchannel devices

DOEpatents

Stenkamp, Victoria S [Richland, WA; TeGrotenhuis, Ward E [Kennewick, WA; Wegeng, Robert S [Richland, WA

2011-04-19

Advanced wicking structures and methods utilizing these structures are described. The use of advanced wicking structures can promote rapid mass transfer while maintaining high capillary pressure through the use of small pores. Particularly improved results in fluid contacting processes can be achieved by enhanced mixing within a wicking layer within a microchannel.

An advanced model of heat and mass transfer in the protective clothing - verification

NASA Astrophysics Data System (ADS)

Łapka, P.; Furmański, P.

2016-09-01

The paper presents an advanced mathematical and numerical models of heat and mass transfer in the multi-layers protective clothing and in elements of the experimental stand subjected to either high surroundings temperature or high radiative heat flux emitted by hot objects. The model included conductive-radiative heat transfer in the hygroscopic porous fabrics and air gaps as well as conductive heat transfer in components of the stand. Additionally, water vapour diffusion in the pores and air spaces as well as phase transition of the bound water in the fabric fibres (sorption and desorption) were accounted for. The thermal radiation was treated in the rigorous way e.g.: semi-transparent absorbing, emitting and scattering fabrics were assumed a non-grey and all optical phenomena at internal or external walls were modelled. The air was assumed transparent. Complex energy and mass balance as well as optical conditions at internal or external interfaces were formulated in order to find exact values of temperatures, vapour densities and radiation intensities at these interfaces. The obtained highly non-linear coupled system of discrete equation was solve by the in-house iterative algorithm which was based on the Finite Volume Method. The model was then successfully partially verified against the results obtained from commercial software for simplified cases.

Dusty gas influences on transport in turbulent erosive propellant flow

NASA Astrophysics Data System (ADS)

Buckingham, A. C.

1980-01-01

A theoretical-numerical model is introduced which relates the influences of particles on erosive transport in a turbulent reactive boundary layer. Specifically, this discussion concerns additive particles used to suppress wall erosion in gun barrel turbulent propellant combustion. The turbulent-particle interactions are modeled with random particulate motion computations. These produce particulate trajectories, distributions and momenta. The interaction model includes effects of particle size, mass, and rotation as well as two-particle hard sphere collisions. The main purpose of this work is to evaluate the effects of the particles on the energy, mass, and momentum transport in the erosive wall boundary layer region. Neglecting thermal relaxation, the heat transfer rates are found to be substantially reduced when smaller diameter (0.2 micron) particles are introduced as compared to larger diameter particles (5 microns).

Dynamics of internal waves on the Southeast Florida shelf: Implications for cross-shelf exchange and turbulent mixing on a barrier reef system

NASA Astrophysics Data System (ADS)

Davis, Kristen Alexis

The dynamics of internal waves shoaling on the Southeast Florida shelf and the resulting stratified turbulence in the shelf bottom boundary layer are investigated using observational studies completed during the summers of 2003-2005. This work is driven by a desire to understand the effects of internal wave-driven flow and the shoreward transport of cool, nutrient-rich water masses on cross-shelf exchange, vertical mixing, and mass transfer to benthic reef organisms. Shelf sea internal wave fields are typically highly variable and dominated by wind and tidal forces. However, this is not necessarily true for outer shelf regions or very narrow shelves where remote physical processes originating over the slope or deep ocean may exert a strong influence on the internal wave climate. During the summers of 2003 and 2004 observational studies were conducted to examine the effects of a western boundary current (the Florida Current), tides, and wind on the mean currents and internal wave field on the outer Southeast Florida shelf. We present evidence that suggests that the Florida Current plays as large a role in the determination of the high frequency internal wave field as tidal forces. These observations and analyses show that it is necessary to include the forcing from the Florida Current meanders and instabilities in order to predict accurately the episodic nature of the internal wave field on the Southeast Florida shelf. Deep ocean and continental shelf processes intersect at the shelf edge and influence the exchange of water masses and their associated characteristics including heat, nutrients, sediment, and larvae across the shelf. Thus, the dynamics of cross-shelf circulation have important consequences for organisms living on the shelf. In the second phase of this work, we investigate physical mechanisms controlling the exchange of water masses during the summer season across the Southeast Florida shelf. A time series of cross-shelf transport from May to August 2003 suggests that, during the summer months, instabilities in the Florida Current and nonlinear internal waves are the primary mechanisms driving cross-shelf transport on the outer shelf Surface tide, wind, and wave-driven transport were found to be small in comparison. Additionally, this data set highlights the importance of baroclinic processes to cross-shelf transport in this region. In the last phase of my research, I sought to investigate how boundary layer dynamics over a rough coral bed were modified by shoaling internal waves and to understand the implications for mixing and mass transfer to the bed. Results are presented from an observational study of the turbulent bottom boundary layer on the outer Southeast Florida shelf in July and August 2005. Turbulence in the reef bottom boundary layer is highly variable in time and is modified by near bed flow, shear, and stratification driven by shoaling internal waves. We examined turbulence in the bottom boundary layer during a typical internal wave event and found that in addition to the episodic onshore transport of cool, subthermocline water masses, with elevated nutrient concentrations, bottom-intensified currents from shoaling internal waves can increase turbulent dissipation and mixing in the reef bottom boundary layer. Additionally, we show that estimates of flux Richardson number, calculated directly from measurements of dissipation and buoyancy flux, support the dependence of R f on turbulent intensity, epsilon/nuN 2, a relationship that has only been previously shown in laboratory and numerical work. While the importance of surface gravity waves in generating turbulent mixing and controlling mass transfer on coral reefs has been well documented in the literature, this work represents the first time the appropriate field data have been collected for a detailed dynamic analysis of the physical effects and biological implications of internal waves on reef ecosystems. Results from these studies suggest that for reef communities exposed to continental shelf and slope processes, internal waves may play an important role in cross-shelf transport and mass transfer to benthic organisms and may be essential to modeling key biological processes, the connectivity of coral populations, or designing and managing marine reserves and fisheries.

Modeling and measurement of the performance of a branched conduit sampling system in a mass spectrometer leak detector

NASA Technical Reports Server (NTRS)

Russell, John M.

1994-01-01

In the leak testing of a large engineering system, one may distinguish three stages, namely leakage measurement by an overall enclosure, leak location, and leakage measurement by a local enclosure. Sniffer probes attached to helium mass spectrometer leak detectors are normally designed for leak location, a qualitative inspection technique intended to pinpoint where a leak is but not to quantify its rate of discharge. The main conclusion of the present effort is that local leakage measurement by a leak detector with a sniffer probe is feasible provided one has: (1) quantitative data on the performance of the mass separator cell (a device interior to the unit where the stream of fluid in the sample line branches); and (2) a means of stabilizing the mass transfer boundary layer that is created near a local leak site when a sniffer probe is placed in its immediate vicinity. Theoretical models of the mass separator cell are provided and measurements of the machine-specific parameters in the formulas are presented. A theoretical model of a porous probe end for stabilizing the mass transfer boundary is also presented.

Modeling and measurement of the performance of a branched conduit sampling system in a mass spectrometer leak detector

NASA Astrophysics Data System (ADS)

Russell, John M.

1994-10-01

In the leak testing of a large engineering system, one may distinguish three stages, namely leakage measurement by an overall enclosure, leak location, and leakage measurement by a local enclosure. Sniffer probes attached to helium mass spectrometer leak detectors are normally designed for leak location, a qualitative inspection technique intended to pinpoint where a leak is but not to quantify its rate of discharge. The main conclusion of the present effort is that local leakage measurement by a leak detector with a sniffer probe is feasible provided one has: (1) quantitative data on the performance of the mass separator cell (a device interior to the unit where the stream of fluid in the sample line branches); and (2) a means of stabilizing the mass transfer boundary layer that is created near a local leak site when a sniffer probe is placed in its immediate vicinity. Theoretical models of the mass separator cell are provided and measurements of the machine-specific parameters in the formulas are presented. A theoretical model of a porous probe end for stabilizing the mass transfer boundary is also presented.

Interaction of solar wind with the magnetopause-boundary layer and generation of magnetic impulse events

NASA Technical Reports Server (NTRS)

Lee, L. C.; Wei, C. Q.

1993-01-01

The transport of mass, momentum, energy and waves from the solar wind to the Earth's magnetosphere takes place in the magnetopause-boundary layer region. Various plasma processes that may occur in this region have been proposed and studied. In this paper, we present a brief review of the plasma processes in the dayside magnetopause-boundary layer. These processes include (1) flux transfer events at the dayside magnetopause, (2) formation of plasma vortices in the low-latitude boundary layer by the Kelvin-Helmholtz instability and coupling to the polar ionosphere, (3) the response of the magnetopause to the solar wind dynamic pressure pulses, and (4) the impulsive penetration of solar wind plasma filaments through the dayside magnetopause into the magnetospheric boundary layer. Through the coupling of the magnetopause-boundary layer to the polar ionosphere, those above processes may lead to occurrence of magnetic impulse events observed in the high-latitude stations.

Vortical ciliary flows actively enhance mass transport in reef corals.

PubMed

Shapiro, Orr H; Fernandez, Vicente I; Garren, Melissa; Guasto, Jeffrey S; Debaillon-Vesque, François P; Kramarsky-Winter, Esti; Vardi, Assaf; Stocker, Roman

2014-09-16

The exchange of nutrients and dissolved gasses between corals and their environment is a critical determinant of the growth of coral colonies and the productivity of coral reefs. To date, this exchange has been assumed to be limited by molecular diffusion through an unstirred boundary layer extending 1-2 mm from the coral surface, with corals relying solely on external flow to overcome this limitation. Here, we present direct microscopic evidence that, instead, corals can actively enhance mass transport through strong vortical flows driven by motile epidermal cilia covering their entire surface. Ciliary beating produces quasi-steady arrays of counterrotating vortices that vigorously stir a layer of water extending up to 2 mm from the coral surface. We show that, under low ambient flow velocities, these vortices, rather than molecular diffusion, control the exchange of nutrients and oxygen between the coral and its environment, enhancing mass transfer rates by up to 400%. This ability of corals to stir their boundary layer changes the way that we perceive the microenvironment of coral surfaces, revealing an active mechanism complementing the passive enhancement of transport by ambient flow. These findings extend our understanding of mass transport processes in reef corals and may shed new light on the evolutionary success of corals and coral reefs.

Transfer, loss and physical processing of water in hit-and-run collisions of planetary embryos

NASA Astrophysics Data System (ADS)

Burger, C.; Maindl, T. I.; Schäfer, C. M.

2018-01-01

Collisions between large, similar-sized bodies are believed to shape the final characteristics and composition of terrestrial planets. Their inventories of volatiles such as water are either delivered or at least significantly modified by such events. Besides the transition from accretion to erosion with increasing impact velocity, similar-sized collisions can also result in hit-and-run outcomes for sufficiently oblique impact angles and large enough projectile-to-target mass ratios. We study volatile transfer and loss focusing on hit-and-run encounters by means of smooth particle hydrodynamics simulations, including all main parameters: impact velocity, impact angle, mass ratio and also the total colliding mass. We find a broad range of overall water losses, up to 75% in the most energetic hit-and-run events, and confirm the much more severe consequences for the smaller body also for stripping of volatile layers. Transfer of water between projectile and target inventories is found to be mostly rather inefficient, and final water contents are dominated by pre-collision inventories reduced by impact losses, for similar pre-collision water mass fractions. Comparison with our numerical results shows that current collision outcome models are not accurate enough to reliably predict these composition changes in hit-and-run events. To also account for non-mechanical losses, we estimate the amount of collisionally vaporized water over a broad range of masses and find that these contributions are particularly important in collisions of ˜ Mars-sized bodies, with sufficiently high impact energies, but still relatively low gravity. Our results clearly indicate that the cumulative effect of several (hit-and-run) collisions can efficiently strip protoplanets of their volatile layers, especially the smaller body, as it might be common, e.g., for Earth-mass planets in systems with Super-Earths. An accurate model for stripping of volatiles that can be included in future planet formation simulations has to account for the peculiarities of hit-and-run events and track compositional changes in both large post-collision fragments.

Verification and validation of an advanced model of heat and mass transfer in the protective clothing

NASA Astrophysics Data System (ADS)

Łapka, Piotr; Furmański, Piotr

2018-04-01

The paper presents verification and validation of an advanced numerical model of heat and moisture transfer in the multi-layer protective clothing and in components of the experimental stand subjected to either high surroundings temperature or high radiative heat flux emitted by hot objects. The developed model included conductive-radiative heat transfer in the hygroscopic porous fabrics and air gaps as well as conductive heat transfer in components of the stand. Additionally, water vapour diffusion in the pores and air spaces as well as phase transition of the bound water in the fabric fibres (sorption and desorption) were accounted for. All optical phenomena at internal or external walls were modelled and the thermal radiation was treated in the rigorous way, i.e., semi-transparent absorbing, emitting and scattering fabrics with the non-grey properties were assumed. The air was treated as transparent. Complex energy and mass balances as well as optical conditions at internal or external interfaces were formulated in order to find values of temperatures, vapour densities and radiation intensities at these interfaces. The obtained highly non-linear coupled system of discrete equations was solved by the Finite Volume based in-house iterative algorithm. The developed model passed discretisation convergence tests and was successfully verified against the results obtained applying commercial software for simplified cases. Then validation was carried out using experimental measurements collected during exposure of the protective clothing to high radiative heat flux emitted by the IR lamp. Satisfactory agreement of simulated and measured temporal variation of temperature at external and internal surfaces of the multi-layer clothing was attained.

Modeling condensation with a noncondensable gas for mixed convection flow

NASA Astrophysics Data System (ADS)

Liao, Yehong

2007-05-01

This research theoretically developed a novel mixed convection model for condensation with a noncondensable gas. The model developed herein is comprised of three components: a convection regime map; a mixed convection correlation; and a generalized diffusion layer model. These components were developed in a way to be consistent with the three-level methodology in MELCOR. The overall mixed convection model was implemented into MELCOR and satisfactorily validated with data covering a wide variety of test conditions. In the development of the convection regime map, two analyses with approximations of the local similarity method were performed to solve the multi-component two-phase boundary layer equations. The first analysis studied effects of the bulk velocity on a basic natural convection condensation process and setup conditions to distinguish natural convection from mixed convection. It was found that the superimposed velocity increases condensation heat transfer by sweeping away the noncondensable gas accumulated at the condensation boundary. The second analysis studied effects of the buoyancy force on a basic forced convection condensation process and setup conditions to distinguish forced convection from mixed convection. It was found that the superimposed buoyancy force increases condensation heat transfer by thinning the liquid film thickness and creating a steeper noncondensable gas concentration profile near the condensation interface. In the development of the mixed convection correlation accounting for suction effects, numerical data were obtained from boundary layer analysis for the three convection regimes and used to fit a curve for the Nusselt number of the mixed convection regime as a function of the Nusselt numbers of the natural and forced convection regimes. In the development of the generalized diffusion layer model, the driving potential for mass transfer was expressed as the temperature difference between the bulk and the liquid-gas interface using the Clausius-Clapeyron equation. The model was developed on a mass basis instead of a molar basis to be consistent with general conservation equations. It was found that vapor diffusion is not only driven by a gradient of the molar fraction but also a gradient of the mixture molecular weight at the diffusion layer.

A critical review on liquid-gas mass transfer models for estimating gaseous emissions from passive liquid surfaces in wastewater treatment plants.

PubMed

Prata, Ademir A; Santos, Jane M; Timchenko, Victoria; Stuetz, Richard M

2018-03-01

Emission models are useful tools for the study and management of atmospheric emissions from passive liquid surfaces in wastewater treatment plants (WWTPs), which are potential sources of odour nuisance and other environmental impacts. In this work, different theoretical and empirical models for the gas-side (k G ) and liquid-side (k L ) mass transfer coefficients in passive surfaces in WWTPs were critically reviewed and evaluated against experimental data. Wind forcing and the development of the wind-wave field, especially the occurrence of microscale wave breaking, were identified as the most important physical factors affecting mass transfer in these situations. Two approaches performed well in describing the available data for k G for water vapour. One is an empirical correlation whilst the other consists of theoretical models based on the description of the inner part of the turbulent boundary layer over a smooth flat plate. We also fit to the experimental data set a new, alternate equation for k G , whose performance was comparable to existing ones. However, these three approaches do not agree with each other in the whole range of Schmidt numbers typical for compounds found in emissions from WWTPs. As to k L , no model was able to satisfactorily explain the behaviour and the scatter observed in the whole experimental data set. Excluding two suspected biased sources, the WATER9 (US EPA, 1994. Air Emission Models for Waste and Wastewater. North Carolina, USA. EPA-453/R-94-080A) approach produced the best results among the most commonly used k L models, although still with considerably high relative errors. For this same sub-set, we propose a new, alternate approach for estimating k L , which resulted in improved performance, particularly for longer fetches. Two main gaps were found in the literature, the understanding of the evolution of the mass transfer boundary layer over liquid surfaces, and the behaviour of k L for larger fetches, especially in the range from 40 to 60 m. Copyright © 2017 Elsevier Ltd. All rights reserved.

The influence of mass transfer on solute transport in column experiments with an aggregated soil

NASA Astrophysics Data System (ADS)

Roberts, Paul V.; Goltz, Mark N.; Summers, R. Scott; Crittenden, John C.; Nkedi-Kizza, Peter

1987-06-01

The spreading of concentration fronts in dynamic column experiments conducted with a porous, aggregated soil is analyzed by means of a previously documented transport model (DFPSDM) that accounts for longitudinal dispersion, external mass transfer in the boundary layer surrounding the aggregate particles, and diffusion in the intra-aggregate pores. The data are drawn from a previous report on the transport of tritiated water, chloride, and calcium ion in a column filled with Ione soil having an average aggregate particle diameter of 0.34 cm, at pore water velocities from 3 to 143 cm/h. The parameters for dispersion, external mass transfer, and internal diffusion were predicted for the experimental conditions by means of generalized correlations, independent of the column data. The predicted degree of solute front-spreading agreed well with the experimental observations. Consistent with the aggregate porosity of 45%, the tortuosity factor for internal pore diffusion was approximately equal to 2. Quantitative criteria for the spreading influence of the three mechanisms are evaluated with respect to the column data. Hydrodynamic dispersion is thought to have governed the front shape in the experiments at low velocity, and internal pore diffusion is believed to have dominated at high velocity; the external mass transfer resistance played a minor role under all conditions. A transport model such as DFPSDM is useful for interpreting column data with regard to the mechanisms controlling concentration front dynamics, but care must be exercised to avoid confounding the effects of the relevant processes.

Radiated chemical reaction impacts on natural convective MHD mass transfer flow induced by a vertical cone

NASA Astrophysics Data System (ADS)

Sambath, P.; Pullepu, Bapuji; Hussain, T.; Ali Shehzad, Sabir

2018-03-01

The consequence of thermal radiation in laminar natural convective hydromagnetic flow of viscous incompressible fluid past a vertical cone with mass transfer under the influence of chemical reaction with heat source/sink is presented here. The surface of the cone is focused to a variable wall temperature (VWT) and wall concentration (VWC). The fluid considered here is a gray absorbing and emitting, but non-scattering medium. The boundary layer dimensionless equations governing the flow are solved by an implicit finite-difference scheme of Crank-Nicolson which has speedy convergence and stable. This method converts the dimensionless equations into a system of tri-diagonal equations and which are then solved by using well known Thomas algorithm. Numerical solutions are obtained for momentum, temperature, concentration, local and average shear stress, heat and mass transfer rates for various values of parameters Pr, Sc, λ, Δ, Rd are established with graphical representations. We observed that the liquid velocity decreased for higher values of Prandtl and Schmidt numbers. The temperature is boost up for decreasing values of Schimdt and Prandtl numbers. The enhancement in radiative parameter gives more heat to liquid due to which temperature is enhanced significantly.

Acoustic explorations of the upper ocean boundary layer

NASA Astrophysics Data System (ADS)

Vagle, Svein

2005-04-01

The upper ocean boundary layer is an important but difficult to probe part of the ocean. A better understanding of small scale processes at the air-sea interface, including the vertical transfer of gases, heat, mass and momentum, are crucial to improving our understanding of the coupling between atmosphere and ocean. Also, this part of the ocean contains a significant part of the total biomass at all trophic levels and is therefore of great interest to researchers in a range of different fields. Innovative measurement plays a critical role in developing our understanding of the processes involved in the boundary layer, and the availability of low-cost, compact, digital signal processors and sonar technology in self-contained and cabled configurations has led to a number of exciting developments. This talk summarizes some recent explorations of this dynamic boundary layer using both active and passive acoustics. The resonant behavior of upper ocean bubbles combined with single and multi-frequency broad band active and passive devices are now giving us invaluable information on air-sea gas transfer, estimation of biological production, marine mammal behavior, wind speed and precipitation, surface and internal waves, turbulence, and acoustic communication in the surf zone.

Characterization of Polyester Cloth as an Alternative Separator to Nafion Membrane in Microbial Fuel Cells for Bioelectricity Generation Using Swine Wastewater.

PubMed

Kim, Taeyoung; Kang, Sukwon; Sung, Je Hoon; Kang, Youn Koo; Kim, Young Hwa; Jang, Jae Kyung

2016-12-28

Polyester cloth (PC) was selected as a prospective inexpensive substitute separator material for microbial fuel cells (MFCs). PC was compared with a traditional Nafion proton exchange membrane (PEM) as an MFC separator by analyzing its physical and electrochemical properties. A single layer of PC showed higher mass transfer ( e.g ., for O₂/H⁺/ions) than the Nafion PEM; in the case of oxygen mass transfer coefficient (k o ), a rate of 50.0 × 10⁻⁵ cm·s⁻¹ was observed compared with a rate of 20.8 × 10⁻⁵ cm/s in the Nafion PEM. Increased numbers of PC layers were found to reduce the oxygen mass transfer coefficient. In addition, the diffusion coefficient of oxygen (D O ) for PC (2.0-3.3 × 10⁻⁶ cm²/s) was lower than that of the Nafion PEM (3.8 × 10⁻⁶ cm²/s). The PC was found to have a low ohmic resistance (0.29-0.38 Ω) in the MFC, which was similar to that of Nafion PEM (0.31 Ω); this resulted in comparable maximum power density and maximum current density in MFCs with PC and those with Nafion PEMs. Moreover, a higher average current generation was observed in MFCs with PC (104.3 ± 15.3 A/m³) compared with MFCs with Nafion PEM (100.4 ± 17.7 A/m³), as well as showing insignificant degradation of the PC surface, during 177 days of use in swine wastewater. These results suggest that PC separators could serve as a low-cost alternative to Nafion PEMs for construction of cost-effective MFCs.

Experimental study on the heat transfer characteristics of waste printed circuit boards pyrolysis.

PubMed

Ma, Hongting; Du, Na; Lin, Xueyin; Li, Chen; Lai, Junwen; Li, Zihao

2018-08-15

In order to study the appropriate and advanced technology for recycling waste printed circuit boards (PCBs), a fixed bed pyrolysis device with stirring function has been designed and developed. The effect of rotating speed on the temperature distribution and mass change in the pyrolysis process of FR-4 PCB has been analyzed. The heat transfer and pyrolysis characteristics of different granular layers with and without stirring have been investigated. The results indicate that the stirring can change the main way of heat transfer from conduction to convection in the PCB layers. As the increase of rotating speed, the temperature rising rate of material at the bottom of the pyrolysis furnace gradually decreases, while the heating rate is increasing at the upper layer, and the temperature difference between the upper and bottom layers is gradually reduced. When the rotating speed varies from 0r/min to 18r/min, the weight loss of the material increases from 3.97% to 6.76%, and the overall pyrolysis degree is improved. During the pyrolysis process, the material layer can be divided into three zones along the vertical direction, namely complete pyrolysis zone, partial pyrolysis zone and non-pyrolysis zone. As the rotating speed is 0r/min, the thickness of each zones is 6cm, 6cm and 3cm, respectively. However, when the rotating speed is increased to 18r/min, the non-pyrolysis zone disappears, and the thickness of complete pyrolysis zone and partial pyrolysis zone increase to 9cm and 6cm, respectively. Copyright © 2018 Elsevier B.V. All rights reserved.

Radon and radium in the ice-covered Arctic Ocean, and what they reveal about gas exchange in the sea ice zone.

NASA Astrophysics Data System (ADS)

Loose, B.; Kelly, R. P.; Bigdeli, A.; Moran, S. B.

2014-12-01

The polar sea ice zones are regions of high primary productivity and interior water mass formation. Consequently, the seasonal sea ice cycle appears important to both the solubility and biological carbon pumps. To estimate net CO2 transfer in the sea ice zone, we require accurate estimates of the air-sea gas transfer velocity. In the open ocean, the gas transfer velocity is driven by wind, waves and bubbles - all of which are strongly altered by the presence of sea ice, making it difficult to translate open ocean estimates of gas transfer to the ice zone. In this study, we present profiles of 222Rn and 226Ra throughout the mixed-layer and euphotic zone. Profiles were collected spanning a range of sea ice cover conditions from 40 to 100%. The profiles of Rn/Ra can be used to estimate the gas transfer velocity, but the 3.8 day half-life of 222Rn implies that mixed layer radon will have a memory of the past ~20 days of gas exchange forcing, which may include a range of sea ice cover conditions. Here, we compare individual estimates of the gas transfer velocity to the turbulent forcing conditions constrained from shipboard and regional reanalysis data to more appropriately capture the time history upper ocean Rn/Ra.

The relationship between inadvertent ingestion and dermal exposure pathways: a new integrated conceptual model and a database of dermal and oral transfer efficiencies.

PubMed

Gorman Ng, Melanie; Semple, Sean; Cherrie, John W; Christopher, Yvette; Northage, Christine; Tielemans, Erik; Veroughstraete, Violaine; Van Tongeren, Martie

2012-11-01

Occupational inadvertent ingestion exposure is ingestion exposure due to contact between the mouth and contaminated hands or objects. Although individuals are typically oblivious to their exposure by this route, it is a potentially significant source of occupational exposure for some substances. Due to the continual flux of saliva through the oral cavity and the non-specificity of biological monitoring to routes of exposure, direct measurement of exposure by the inadvertent ingestion route is challenging; predictive models may be required to assess exposure. The work described in this manuscript has been carried out as part of a project to develop a predictive model for estimating inadvertent ingestion exposure in the workplace. As inadvertent ingestion exposure mainly arises from hand-to-mouth contact, it is closely linked to dermal exposure. We present a new integrated conceptual model for dermal and inadvertent ingestion exposure that should help to increase our understanding of ingestion exposure and our ability to simultaneously estimate exposure by the dermal and ingestion routes. The conceptual model consists of eight compartments (source, air, surface contaminant layer, outer clothing contaminant layer, inner clothing contaminant layer, hands and arms layer, perioral layer, and oral cavity) and nine mass transport processes (emission, deposition, resuspension or evaporation, transfer, removal, redistribution, decontamination, penetration and/or permeation, and swallowing) that describe event-based movement of substances between compartments (e.g. emission, deposition, etc.). This conceptual model is intended to guide the development of predictive exposure models that estimate exposure from both the dermal and the inadvertent ingestion pathways. For exposure by these pathways the efficiency of transfer of materials between compartments (for example from surfaces to hands, or from hands to the mouth) are important determinants of exposure. A database of transfer efficiency data relevant for dermal and inadvertent ingestion exposure was developed, containing 534 empirically measured transfer efficiencies measured between 1980 and 2010 and reported in the peer-reviewed and grey literature. The majority of the reported transfer efficiencies (84%) relate to transfer between surfaces and hands, but the database also includes efficiencies for other transfer scenarios, including surface-to-glove, hand-to-mouth, and skin-to-skin. While the conceptual model can provide a framework for a predictive exposure assessment model, the database provides detailed information on transfer efficiencies between the various compartments. Together, the conceptual model and the database provide a basis for the development of a quantitative tool to estimate inadvertent ingestion exposure in the workplace.

Wafer-scale layer transfer of GaAs and Ge onto Si wafers using patterned epitaxial lift-off

NASA Astrophysics Data System (ADS)

Mieda, Eiko; Maeda, Tatsuro; Miyata, Noriyuki; Yasuda, Tetsuji; Kurashima, Yuichi; Maeda, Atsuhiko; Takagi, Hideki; Aoki, Takeshi; Yamamoto, Taketsugu; Ichikawa, Osamu; Osada, Takenori; Hata, Masahiko; Ogawa, Arito; Kikuchi, Toshiyuki; Kunii, Yasuo

2015-03-01

We have developed a wafer-scale layer-transfer technique for transferring GaAs and Ge onto Si wafers of up to 300 mm in diameter. Lattice-matched GaAs or Ge layers were epitaxially grown on GaAs wafers using an AlAs release layer, which can subsequently be transferred onto a Si handle wafer via direct wafer bonding and patterned epitaxial lift-off (ELO). The crystal properties of the transferred GaAs layers were characterized by X-ray diffraction (XRD), photoluminescence, and the quality of the transferred Ge layers was characterized using Raman spectroscopy. We find that, after bonding and the wet ELO processes, the quality of the transferred GaAs and Ge layers remained the same compared to that of the as-grown epitaxial layers. Furthermore, we realized Ge-on-insulator and GaAs-on-insulator wafers by wafer-scale pattern ELO technique.

Two-Phase Solid/Fluid Simulation of Dense Granular Flows With Dilatancy Effects

NASA Astrophysics Data System (ADS)

Mangeney, A.; Bouchut, F.; Fernández-Nieto, E. D.; Kone, E. H.; Narbona-Reina, G.

2016-12-01

Describing grain/fluid interaction in debris flows models is still an open and challenging issue with key impact on hazard assessment [1]. We present here a two-phase two-thin-layer model for fluidized debris flows that takes into account dilatancy effects. It describes the velocity of both the solid and the fluid phases, the compression/ dilatation of the granular media and its interaction with the pore fluid pressure [2]. The model is derived from a 3D two-phase model proposed by Jackson [3] and the mixture equations are closed by a weak compressibility relation. This relation implies that the occurrence of dilation or contraction of the granular material in the model depends on whether the solid volume fraction is respectively higher or lower than a critical value. When dilation occurs, the fluid is sucked into the granular material, the pore pressure decreases and the friction force on the granular phase increases. On the contrary, in the case of contraction, the fluid is expelled from the mixture, the pore pressure increases and the friction force diminishes. To account for this transfer of fluid into and out of the mixture, a two-layer model is proposed with a fluid or a solid layer on top of the two-phase mixture layer. Mass and momentum conservation are satisfied for the two phases, and mass and momentum are transferred between the two layers. A thin-layer approximation is used to derive average equations. Special attention is paid to the drag friction terms that are responsible for the transfer of momentum between the two phases and for the appearance of an excess pore pressure with respect to the hydrostatic pressure. By comparing quantitatively the results of simulation and laboratory experiments on submerged granular flows, we show that our model contains the basic ingredients making it possible to reproduce the interaction between the granular and fluid phases through the change in pore fluid pressure. In particular, we analyse the different time scales in the model and their role in granular/fluid flow dynamics. References[1] R. Delannay, A. Valance, A. Mangeney, O. Roche, P. Richard, J. Phys. D: Appl. Phys., in press (2016). [2] F. Bouchut, E. D. Fernández-Nieto, A. Mangeney, G. Narbona-Reina, J. Fluid Mech., 801, 166-221 (2016). [3] R. Jackson, Cambridges Monographs on Mechanics (2000).

Numerical and experimental investigation of DNAPL removal mechanisms in a layered porous medium by means of soil vapor extraction.

PubMed

Yoon, Hongkyu; Oostrom, Mart; Wietsma, Thomas W; Werth, Charles J; Valocchi, Albert J

2009-10-13

The purpose of this work is to identify the mechanisms that govern the removal of carbon tetrachloride (CT) during soil vapor extraction (SVE) by comparing numerical and analytical model simulations with a detailed data set from a well-defined intermediate-scale flow cell experiment. The flow cell was packed with a fine-grained sand layer embedded in a coarse-grained sand matrix. A total of 499 mL CT was injected at the top of the flow cell and allowed to redistribute in the variably saturated system. A dual-energy gamma radiation system was used to determine the initial NAPL saturation profile in the fine-grained sand layer. Gas concentrations at the outlet of the flow cell and 15 sampling ports inside the flow cell were measured during subsequent CT removal using SVE. Results show that CT mass was removed quickly in coarse-grained sand, followed by a slow removal from the fine-grained sand layer. Consequently, effluent gas concentrations decreased quickly at first, and then started to decrease gradually, resulting in long-term tailing. The long-term tailing was mainly due to diffusion from the fine-grained sand layer to the coarse-grained sand zone. An analytical solution for a one-dimensional advection and a first-order mass transfer model matched the tailing well with two fitting parameters. Given detailed knowledge of the permeability field and initial CT distribution, we were also able to predict the effluent concentration tailing and gas concentration profiles at sampling ports using a numerical simulator assuming equilibrium CT evaporation. The numerical model predictions were accurate within the uncertainty of independently measured or literature derived parameters. This study demonstrates that proper numerical modeling of CT removal through SVE can be achieved using equilibrium evaporation of NAPL if detailed fine-scale knowledge of the CT distribution and physical heterogeneity is incorporated into the model. However, CT removal could also be fit by a first-order mass transfer analytical model, potentially leading to an erroneous conclusion that the long-term tailing in the experiment was kinetically controlled due to rate-limited NAPL evaporation.

Application of Low Melting Point Thermoplastics to Hybrid Rocket Fuel

NASA Astrophysics Data System (ADS)

Wada, Yutaka; Jikei, Mitsutoshi; Kato, Ryuichi; Kato, Nobuji; Hori, Keiichi

This paper introduces the application of low melting point thermoplastics (LT) to hybrid rocket fuel. LT made by Katazen Corporation has an excellent mechanical property comparing with other thermoplastics and prospect of high surface regression rate because it has a similar physical property with low melting point of paraffin fuel which has high regression rate probably due to the entrainment mass transfer mechanism that droplets continuously depart out of the surface melt layer. Several different types of LT developed by Katazen Corporation for this use have been evaluated in the measurements of regression rate, mechanical properties These results show the LTs have the higher regression rate and better mechanical properties comparing with conventional hybrid rocket fuels. Observation was also made using a small 2D combustor, and the entrainment mass transfer mechanism is confirmed with the LT fuels.

Effects of magnetic, radiation and chemical reaction on unsteady heat and mass transfer flow of an oscillating cylinder

NASA Astrophysics Data System (ADS)

Ahmed, Rubel; Rana, B. M. Jewel; Ahmmed, S. F.

2017-06-01

The effects of magnetic, radiation and chemical reaction parameters on the unsteady heat and mass transfer boundary layer flow past an oscillating cylinder is considered. The dimensionless momentum, energy and concentration equations are solved numerically by using explicit finite difference method with the help of a computer programming language Compaq visual FORTRAN 6.6a. The obtained results of this study have been discussed for different values of well-known parameters with different time steps. The effect of these parameters on the velocity field, temperature field and concentration field, skin-friction, Nusselt number, streamlines and isotherms has been studied and results are presented by graphically represented by the tabular form quantitatively. The stability and convergence analysis of the solution parameters that have been used in the mathematical model have been tested.

Full-wafer fabrication by nanostencil lithography of micro/nanomechanical mass sensors monolithically integrated with CMOS.

PubMed

Arcamone, J; van den Boogaart, M A F; Serra-Graells, F; Fraxedas, J; Brugger, J; Pérez-Murano, F

2008-07-30

Wafer-scale nanostencil lithography (nSL) is used to define several types of silicon mechanical resonators, whose dimensions range from 20 µm down to 200 nm, monolithically integrated with CMOS circuits. We demonstrate the simultaneous patterning by nSL of ∼2000 nanodevices per wafer by post-processing standard CMOS substrates using one single metal evaporation, pattern transfer to silicon and subsequent etch of the sacrificial layer. Resonance frequencies in the MHz range were measured in air and vacuum. As proof-of-concept towards an application as high performance sensors, CMOS integrated nano/micromechanical resonators are successfully implemented as ultra-sensitive areal mass sensors. These devices demonstrate the ability to monitor the deposition of gold layers whose average thickness is smaller than a monolayer. Their areal mass sensitivity is in the range of 10(-11) g cm(-2) Hz(-1), and their thickness resolution corresponds to approximately a thousandth of a monolayer.

Solutions for Reacting and Nonreacting Viscous Shock Layers with Multicomponent Diffusion and Mass Injection. Ph.D. Thesis - Virginia Polytechnic Inst. and State Univ.

NASA Technical Reports Server (NTRS)

Moss, J. N.

1971-01-01

Numerical solutions are presented for the viscous shocklayer equations where the chemistry is treated as being either frozen, equilibrium, or nonequilibrium. Also the effects of the diffusion model, surface catalyticity, and mass injection on surface transport and flow parameters are considered. The equilibrium calculations for air species using multicomponent: diffusion provide solutions previously unavailable. The viscous shock-layer equations are solved by using an implicit finite-difference scheme. The flow is treated as a mixture of inert and thermally perfect species. Also the flow is assumed to be in vibrational equilibrium. All calculations are for a 45 deg hyperboloid. The flight conditions are those for various altitudes and velocities in the earth's atmosphere. Data are presented showing the effects of the chemical models; diffusion models; surface catalyticity; and mass injection of air, water, and ablation products on heat transfer; skin friction; shock stand-off distance; wall pressure distribution; and tangential velocity, temperature, and species profiles.

Application of graphene oxide in water treatment

NASA Astrophysics Data System (ADS)

Liu, Yongchen

2017-11-01

Graphene oxide has good hydrophilicity and has been tried to use it into thin films for water treatment in recent years. In this paper, the preparation methods of graphene oxide membrane are reviewed, including vacuum suction filtration, spray coating, spin coating, dip coating and the layer by layer method. Secondly, the mechanism of mass transfer of graphene membrane is introduced in detail. The application of the graphene oxide membrane, modified graphene oxide membrane and graphene hybrid membranes were discussed in RO, vaporization, nanofiltration and other aspects. Finally, the development and application of graphene membrane in water treatment were discussed.

Multi-scale modeling of urban air pollution: development of a Street-in-Grid model

NASA Astrophysics Data System (ADS)

Kim, Youngseob; Wu, You; Seigneur, Christian; Roustan, Yelva

2016-04-01

A new multi-scale model of urban air pollution is presented. This model combines a chemical-transport model (CTM) that includes a comprehensive treatment of atmospheric chemistry and transport at spatial scales greater than 1 km and a street-network model that describes the atmospheric concentrations of pollutants in an urban street network. The street-network model is based on the general formulation of the SIRANE model and consists of two main components: a street-canyon component and a street-intersection component. The street-canyon component calculates the mass transfer velocity at the top of the street canyon (roof top) and the mean wind velocity within the street canyon. The estimation of the mass transfer velocity depends on the intensity of the standard deviation of the vertical velocity at roof top. The effect of various formulations of this mass transfer velocity on the pollutant transport at roof-top level is examined. The street-intersection component calculates the mass transfer from a given street to other streets across the intersection. These mass transfer rates among the streets are calculated using the mean wind velocity calculated for each street and are balanced so that the total incoming flow rate is equal to the total outgoing flow rate from the intersection including the flow between the intersection and the overlying atmosphere at roof top. In the default option, the Leighton photostationary cycle among ozone (O3) and nitrogen oxides (NO and NO2) is used to represent the chemical reactions within the street network. However, the influence of volatile organic compounds (VOC) on the pollutant concentrations increases when the nitrogen oxides (NOx) concentrations are low. To account for the possible VOC influence on street-canyon chemistry, the CB05 chemical kinetic mechanism, which includes 35 VOC model species, is implemented in this street-network model. A sensitivity study is conducted to assess the uncertainties associated with the use of the Leighton cycle chemistry. The street-network model is coupled to the CTM Polair3D of the Polyphemus air quality modeling platform to constitute a Street-in-Grid (SinG) model. The street-network model is used to simulate the concentrations of the chemical species in the lowest layer in the urban area and the simulation for the upper layers is then performed by Polair3D. Interactions between the street-network model and the host CTM occur at roof-top and depend on the vertical mass transfer described above. The SinG model is used to simulate the concentrations of gas-phase pollutants (O3 and NOx) in a Paris suburb. The emission data for each street that are needed for the street-network model were obtained from a dynamic traffic model. Topographic data, such as street length/width and building height, were obtained from a geographic database (BD TOPO). Simulated concentrations are compared to concentrations measured at two monitoring stations that were located on each side of a large avenue.

Convective response of a wall-mounted hot-film sensor in a shock tube

NASA Technical Reports Server (NTRS)

Roberts, A. Sidney, Jr.; Ortgies, Kelly R.; Gartenberg, Ehud; Carraway, Debra L.

1991-01-01

Shock tube experiments were performed in order to determine the response of a single hot-film element of a sensor array to transiently induced flow behind weak normal shock waves. The experiments attempt to isolate the response due only to the change in convective heat transfer at the hot-film surface mounted on the wall of the shock tube. The experiments are described, the results being correlated with transient boundary layer theory and compared with an independent set of experimental results. One of the findings indicates that the change in the air properties (temperature and pressure) precedes the air mass transport, causing an ambiguity in the sensor response to the development of the velocity boundary layer. Also, a transient, local heat transfer coefficient is formulated to be used as a forcing function in an hot-film instrument model and simulation which remains under investigation.

Turbulent boundary layer on a full-coverage film-cooled surface: An experimental heat transfer study with normal injection

NASA Technical Reports Server (NTRS)

Choe, H.; Kays, W. M.; Moffat, R. J.

1976-01-01

Heat transfer behavior was studied in a turbulent boundary layer with full-coverage film cooling through an array of discrete holes and with injection normal to the wall surface. Stanton numbers were measured for a staggered hole pattern with pitch-to-diameter ratios of 5 and 10, an injection mass flux ratio range of 0.1 to 1.0, and a range of Reynolds number 170 thousand to 5 million. Air was used as the working fluid with the mainstream velocity varied from .14 to 33.5 m/sec (30 to 110 ft/sec). The data were taken for secondary injection temperatures equal to the wall temperature and also equal to the mainstream temperature. By use of linear superposition theory, the data may be used to obtain Stanton number as a continuous function of the injectant temperature. The heat transfer coefficient is defined on the basis of a mainstream-to-wall temperature difference. This difinition permits direct comparison of performance between film cooling and transpiration cooling.

Theory of deposition of condensible impurities on surfaces immersed in combustion gases

NASA Technical Reports Server (NTRS)

Rosner, D. E.

1979-01-01

The components resulting from the deposition of inorganic salts (e.g., Na2S04) and oxides present in the combustion products from gas turbine engines were investigated. Emphasis was placed on the effects of multicomponent vapor transport, thermophoretic transport of vapor and small particles to actively cooled surfaces, variable fluid properties within mass transfer boundary layers, and free stream turbulence.

JPRS report: Science and technology. Central Eurasia

NASA Astrophysics Data System (ADS)

1995-02-01

Translated articles cover the following topics: laser-controlled rotary microwave waveguide junction; optical pulse-phase modulation of semiconductor laser; amplitude-phase distortions of light beam obliquely propagating through ground layer of troposphere; antenna arrays with ultrafast beam scanning; materials for a walk on moon; textile-wood-coal briquette path to capitalism; and development of automated system for scientific research and design of heat and mass transfer processes.

Discussion of flight experiments with an entry research vehicle

NASA Technical Reports Server (NTRS)

Potter, J. L.

1985-01-01

The focus of interest is the maneuvering flight of advanced entry vehicles operating at altitudes above 50 km and at velocities of 5 to 8 km/s. Information resulting in more accurate aerodynamic analysis is sought and measurement techniques that appear to be applicable are identified. Measurements discussed include: shock layer or boundary layer profiles of velocity, temperature, species mass fractions, and other gas properties associated with aerodynamic heating; surface energy transfer process; nonequilibrium flow processes and pressure distribution; separated, vortic leeside flow of nonequilibrium fluid; boundary layer transition on highly swept configurations; and shock and surface slip and gas/surface interaction. Further study should focus on evolving measurement techniques, installation requirements, and on identification of the portions of flights where successful results seem probable.

Low tritium partial pressure permeation system for mass transport measurement in lead lithium eutectic

DOE PAGES

Pawelko, R. J.; Shimada, M.; Katayama, K.; ...

2015-11-28

This paper describes a new experimental system designed to investigate tritium mass transfer properties in materials important to fusion technology. Experimental activities were carried out at the Safety and Tritium Applied Research (STAR) facility located at the Idaho National Laboratory (INL). The tritium permeation measurement system was developed as part of the Japan/US TITAN collaboration to investigate tritium mass transfer properties in liquid lead lithium eutectic (LLE) alloy. The experimental system is configured to measure tritium mass transfer properties at low tritium partial pressures. Initial tritium permeation scoping tests were conducted on a 1 mm thick α-Fe plate to determinemore » operating parameters and to validate the experimental technique. A second series of permeation tests was then conducted with the α-Fe plate covered with an approximately 8.5 mm layer of liquid lead lithium eutectic alloy (α-Fe/LLE). We present preliminary tritium permeation data for α-Fe and α-Fe/LLE at temperatures between 400 and 600°C and at tritium partial pressures between 1.7E-3 and 2.5 Pa in helium. Preliminary results for the α-Fe plate and α-Fe/LLE indicate that the data spans a transition region between the diffusion-limited regime and the surface-limited regime. In conclusion, additional data is required to determine the existence and range of a surface-limited regime.« less

Probing Interfacial Processes on Graphene Surface by Mass Detection

NASA Astrophysics Data System (ADS)

Kakenov, Nurbek; Kocabas, Coskun

2013-03-01

In this work we studied the mass density of graphene, probed interfacial processes on graphene surface and examined the formation of graphene oxide by mass detection. The graphene layers were synthesized by chemical vapor deposition method on copper foils and transfer-printed on a quartz crystal microbalance (QCM). The mass density of single layer graphene was measured by investigating the mechanical resonance of the QCM. Moreover, we extended the developed technique to probe the binding dynamics of proteins on the surface of graphene, were able to obtain nonspecific binding constant of BSA protein of graphene surface in aqueous solution. The time trace of resonance signal showed that the BSA molecules rapidly saturated by filling the available binding sites on graphene surface. Furthermore, we monitored oxidation of graphene surface under oxygen plasma by tracing the changes of interfacial mass of the graphene controlled by the shifts in Raman spectra. Three regimes were observed the formation of graphene oxide which increases the interfacial mass, the release of carbon dioxide and the removal of small graphene/graphene oxide flakes. Scientific and Technological Research Council of Turkey (TUBITAK) grant no. 110T304, 109T209, Marie Curie International Reintegration Grant (IRG) grant no 256458, Turkish Academy of Science (TUBA-Gebip).

Effects of variable properties on MHD heat and mass transfer flow near a stagnation point towards a stretching sheet in a porous medium with thermal radiation

NASA Astrophysics Data System (ADS)

M. Salem, A.; Rania, Fathy

2012-05-01

The effect of variable viscosity and thermal conductivity on steady magnetohydrodynamic (MHD) heat and mass transfer flow of viscous and incompressible fluid near a stagnation point towards a permeable stretching sheet embedded in a porous medium are presented, taking into account thermal radiation and internal heat genberation/absorbtion. The stretching velocity and the ambient fluid velocity are assumed to vary linearly with the distance from the stagnation point. The Rosseland approximation is used to describe the radiative heat flux in the energy equation. The governing fundamental equations are first transformed into a system of ordinary differential equations using a scaling group of transformations and are solved numerically by using the fourth-order Rung—Kutta method with the shooting technique. A comparison with previously published work has been carried out and the results are found to be in good agreement. The results are analyzed for the effect of different physical parameters, such as the variable viscosity and thermal conductivity, the ratio of free stream velocity to stretching velocity, the magnetic field, the porosity, the radiation and suction/injection on the flow, and the heat and mass transfer characteristics. The results indicate that the inclusion of variable viscosity and thermal conductivity into the fluids of light and medium molecular weight is able to change the boundary-layer behavior for all values of the velocity ratio parameter λ except for λ = 1. In addition, the imposition of fluid suction increases both the rate of heat and mass transfer, whereas fluid injection shows the opposite effect.

The impact of viscosity on the combined heat, mass and momentum transfer in laminar liquid falling films

NASA Astrophysics Data System (ADS)

Mittermaier, M.; Ziegler, F.

2018-04-01

In this article we present a model describing a laminar film flow over a vertical isothermal plate whilst heat and mass transfer is occurring. We focus on a formulation where most common assumptions, such as constant property data and constant film thickness, have been cancelled. The hydrodynamic model results in longitudinal and transversal velocity components and their evolution in the entrance region. Heat and mass transfer occurs simultaneously and is modelled with respect to release of differential heat of solution as well as heat flow due to interdiffusion. The numerical solution is obtained by utilising a Newton-Raphson method to solve the finite difference formulation of the governing equations. Mass transfer across the film affects the development of both longitudinal and transversal velocity components. The hydrodynamics are modelled using a boundary layer approximation of the Navier-Stokes equations. The significance of simplifications on the hydrodynamic model are illustrated and discussed using a fully developed velocity profile (Nusselt flow) and a plug flow at the inlet for comparison. Even if a Nusselt profile is assumed, it develops further since mass is absorbed or desorbed. It is found that the onset of absorption occurs at shorter flow length when applying a plug flow at the inlet. If the film is initially in equilibrium, this results in a 9.3% increase in absorbed mass over a length of 0.03 m as compared with the Nusselt flow. A fluid with a viscosity five times the one of lithium bromide solution but sharing comparable properties apart from that, leads to lower overall heat and mass transfer rates. If the respective fluids are saturated at the inlet, the accumulated mass flux absorbed by lithium bromide solution is 2.2 times higher than the one absorbed by a high viscous fluid. However, when a plug flow is applied and the fluid is sub-cooled, ab initio the absorbed mass flux is slightly higher for a high viscous fluid. Assuming a sub-cooling of 3 K at the inlet, lithium bromide solution now only performs around 11% better as compared with a high viscous fluid over the considered length of 0.03 m. The code may be downloaded from: https://github.com/mittermaier/hmt.

Ordered macroporous platinum electrode and enhanced mass transfer in fuel cells using inverse opal structure.

PubMed

Kim, Ok-Hee; Cho, Yong-Hun; Kang, Soon Hyung; Park, Hee-Young; Kim, Minhyoung; Lim, Ju Wan; Chung, Dong Young; Lee, Myeong Jae; Choe, Heeman; Sung, Yung-Eun

2013-01-01

Three-dimensional, ordered macroporous materials such as inverse opal structures are attractive materials for various applications in electrochemical devices because of the benefits derived from their periodic structures: relatively large surface areas, large voidage, low tortuosity and interconnected macropores. However, a direct application of an inverse opal structure in membrane electrode assemblies has been considered impractical because of the limitations in fabrication routes including an unsuitable substrate. Here we report the demonstration of a single cell that maintains an inverse opal structure entirely within a membrane electrode assembly. Compared with the conventional catalyst slurry, an ink-based assembly, this modified assembly has a robust and integrated configuration of catalyst layers; therefore, the loss of catalyst particles can be minimized. Furthermore, the inverse-opal-structure electrode maintains an effective porosity, an enhanced performance, as well as an improved mass transfer and more effective water management, owing to its morphological advantages.

On Two-Scale Modelling of Heat and Mass Transfer

NASA Astrophysics Data System (ADS)

Vala, J.; Št'astník, S.

2008-09-01

Modelling of macroscopic behaviour of materials, consisting of several layers or components, whose microscopic (at least stochastic) analysis is available, as well as (more general) simulation of non-local phenomena, complicated coupled processes, etc., requires both deeper understanding of physical principles and development of mathematical theories and software algorithms. Starting from the (relatively simple) example of phase transformation in substitutional alloys, this paper sketches the general formulation of a nonlinear system of partial differential equations of evolution for the heat and mass transfer (useful in mechanical and civil engineering, etc.), corresponding to conservation principles of thermodynamics, both at the micro- and at the macroscopic level, and suggests an algorithm for scale-bridging, based on the robust finite element techniques. Some existence and convergence questions, namely those based on the construction of sequences of Rothe and on the mathematical theory of two-scale convergence, are discussed together with references to useful generalizations, required by new technologies.

Extremely high efficient nanoreactor with Au@ZnO catalyst for photocatalysis

NASA Astrophysics Data System (ADS)

Su, Chung-Yi; Yang, Tung-Han; Gurylev, Vitaly; Huang, Sheng-Hsin; Wu, Jenn-Ming; Perng, Tsong-Pyng

2015-10-01

We fabricated a photocatalytic Au@ZnO@PC (polycarbonate) nanoreactor composed of monolayered Au nanoparticles chemisorbed on conformal ZnO nanochannel arrays within the PC membrane. A commercial PC membrane was used as the template for deposition of a ZnO shell into the pores by atomic layer deposition (ALD). Thioctic acid (TA) with sufficient steric stabilization was used as a molecular linker for functionalization of Au nanoparticles in a diameter of 10 nm. High coverage of Au nanoparticles anchored on the inner wall of ZnO nanochannels greatly improved the photocatalytic activity for degradation of Rhodamine B. The membrane nanoreactor achieved 63% degradation of Rhodamine B within only 26.88 ms of effective reaction time owing to its superior mass transfer efficiency based on Damköhler number analysis. Mass transfer limitation can be eliminated in the present study due to extremely large surface-to-volume ratio of the membrane nanoreactor.

Characterization of vibrissa germinative cells: transition of cell types.

PubMed

Osada, A; Kobayashi, K

2001-12-01

Germinative cells, small cell masses attached to the stalks of dermal papillae that are able to differentiate into the hair shaft and inner root sheath, form follicular bulb-like structures when co-cultured with dermal papilla cells. We studied the growth characteristics of germinative cells to determine the cell types in the vibrissa germinative tissue. Germinative tissues, attaching to dermal papillae, were cultured on 3T3 feeder layers. The cultured keratinocytes were harvested and transferred, equally and for two passages, onto lined dermal papilla cells (LDPC) and/or 3T3 feeder layers. The resulting germinative cells were classified into three types in the present experimental condition. Type 1 cells grow very well on either feeder layer, whereas Type 3 cells scarcely grow on either feeder layer. Type 2 cells are very conspicuous and are reversible. They grow well on 3T3 but growth is suppressed on LDPC feeder layers. The Type 2 cells that grow well on 3T3 feeder layers, however, are suppressed when transferred onto LDPC and the Type 2 cells that are suppressed on LDPC begin to grow again on 3T3. The transition of one cell type to another in vitro and the cell types that these germinative cell types correspond to in vivo is discussed. It was concluded that stem cells or their close progenitors reside in the germinative tissues of the vibrissa bulb except at late anagen-early catagen.

Modeling the Secondary Drying Stage of Freeze Drying: Development and Validation of an Excel-Based Model.

PubMed

Sahni, Ekneet K; Pikal, Michael J

2017-03-01

Although several mathematical models of primary drying have been developed over the years, with significant impact on the efficiency of process design, models of secondary drying have been confined to highly complex models. The simple-to-use Excel-based model developed here is, in essence, a series of steady state calculations of heat and mass transfer in the 2 halves of the dry layer where drying time is divided into a large number of time steps, where in each time step steady state conditions prevail. Water desorption isotherm and mass transfer coefficient data are required. We use the Excel "Solver" to estimate the parameters that define the mass transfer coefficient by minimizing the deviations in water content between calculation and a calibration drying experiment. This tool allows the user to input the parameters specific to the product, process, container, and equipment. Temporal variations in average moisture contents and product temperatures are outputs and are compared with experiment. We observe good agreement between experiments and calculations, generally well within experimental error, for sucrose at various concentrations, temperatures, and ice nucleation temperatures. We conclude that this model can serve as an important process development tool for process design and manufacturing problem-solving. Copyright © 2017 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

Fluid Flow and Mass Transfer in Micro/Nano-Channels

NASA Astrophysics Data System (ADS)

Conlisk, A. T.; McFerran, Jennifer; Hansford, Derek; Zheng, Zhi

2001-11-01

In this work the fluid flow and mass transfer due to the presence of an electric field in a rectangular channel is examined. We consider a mixture of water or other neutral solvent and a salt compound such as sodium chloride for which the ionic species are entirely dissociated. Results are produced for the case where the channel height is much greater than the electric double layer(EDL)(microchannel) and for the case where the channel height is of the order or somewhat greater than the width of the EDL(nanochannel). For the electroosmotic flow so induced, the velocity field and the potential are similar. The fluid is assumed to behave as a continuum and the Boltzmann distribution for the mole fractions of the ions emerges from the classical dilute mass transfer equation in the limiting case where the EDL thickness is much less than the channel height. Depending on the relative magnitude of the mole fractions at the walls of the channel, both forward and reversed flow may occur. The volume flow rate is observed to vary linearly with channel height for electrically driven flow in contrast to pressure driven flow which varies as height cubed. This means that power requirements for small channels are much greater for pressure driven flow. Supported by DARPA

High Static Stability in the Mixed Layer Above the Extratropical Tropopause

NASA Astrophysics Data System (ADS)

Kunz, A.; Konopka, P.; Müller, R.; Pan, L. L.; Schiller, C.

2009-04-01

A strong relationship between the static stability N2 in the tropopause inversion layer (TIL) and the intensity of mixing is evident from in-situ observations during SPURT. With a new simple measure of mixing intensity based on O3/CO tracer correlations, a very high mixing intensity connected to a high N2 is found in the extratropical mixing layer. Using radiative transfer calculations we simulate the influence of trace gases such as O3 and H2O on the temperature gradient and thus on the static stability above the tropopause in an idealized (L-shaped) non-mixed and reference mixed atmosphere. N2 enhances due to an intensifying mixing in the LS. At the same time the temperature decreases together with a development of an inversion and the TIL. Hereby H2O plays the dominant role in maintenance the temperature inversion and the TIL structure. In case of non mixed profiles the TIL vanishes. The results motivate a link between the mixing layer and the TIL. The mixing layer contains on the one hand older air masses, with high values of N2 due to radiative adjustment. This part of the mixing layer is spatial identically to the TIL. On the other hand, there are younger air masses with somehow lower N2 values within the mixing layer, because of fast intrusion processes from the troposphere due to the permeability or so-called mid-latitude-breaks associated with the jet.

Modifications to MacCormack’s 2-D Navier-Stokes Compression Ramp Code for Application to Flows with Axes of Symmetry and Wall Mass Transfer

DTIC Science & Technology

1981-01-01

in two dimensions have been studied experimentally by Gray and Rhudy (Ref. 3) and theoretically by Bloy and Georgeff (Ref. 4) and Carter (Ref. 5...Layer Separation at Supersonic and Hypersonic Speeds." AEDC-TR-70-235, March 1971. 4. Bloy , A. W. and Georgeff, M. P. "The Hypersonic Laminar

Double-layered cell transfer technology for bone regeneration

PubMed Central

Akazawa, Keiko; Iwasaki, Kengo; Nagata, Mizuki; Yokoyama, Naoki; Ayame, Hirohito; Yamaki, Kazumasa; Tanaka, Yuichi; Honda, Izumi; Morioka, Chikako; Kimura, Tsuyoshi; Komaki, Motohiro; Kishida, Akio; Izumi, Yuichi; Morita, Ikuo

2016-01-01

For cell-based medicine, to mimic in vivo cellular localization, various tissue engineering approaches have been studied to obtain a desirable arrangement of cells on scaffold materials. We have developed a novel method of cell manipulation called “cell transfer technology”, enabling the transfer of cultured cells onto scaffold materials, and controlling cell topology. Here we show that using this technique, two different cell types can be transferred onto a scaffold surface as stable double layers or in patterned arrangements. Various combinations of adherent cells were transferred to a scaffold, amniotic membrane, in overlapping bilayers (double-layered cell transfer), and transferred cells showed stability upon deformations of the material including folding and trimming. Transplantation of mesenchymal stem cells from periodontal ligaments (PDLSC) and osteoblasts, using double-layered cell transfer significantly enhanced bone formation, when compared to single cell type transplantation. Our findings suggest that this double-layer cell transfer is useful to produce a cell transplantation material that can bear two cell layers. Moreover, the transplantation of an amniotic membrane with PDLSCs/osteoblasts by cell transfer technology has therapeutic potential for bone defects. We conclude that cell transfer technology provides a novel and unique cell transplantation method for bone regeneration. PMID:27624174

Atomic layer deposited oxide films as protective interface layers for integrated graphene transfer

NASA Astrophysics Data System (ADS)

Cabrero-Vilatela, A.; Alexander-Webber, J. A.; Sagade, A. A.; Aria, A. I.; Braeuninger-Weimer, P.; Martin, M.-B.; Weatherup, R. S.; Hofmann, S.

2017-12-01

The transfer of chemical vapour deposited graphene from its parent growth catalyst has become a bottleneck for many of its emerging applications. The sacrificial polymer layers that are typically deposited onto graphene for mechanical support during transfer are challenging to remove completely and hence leave graphene and subsequent device interfaces contaminated. Here, we report on the use of atomic layer deposited (ALD) oxide films as protective interface and support layers during graphene transfer. The method avoids any direct contact of the graphene with polymers and through the use of thicker ALD layers (≥100 nm), polymers can be eliminated from the transfer-process altogether. The ALD film can be kept as a functional device layer, facilitating integrated device manufacturing. We demonstrate back-gated field effect devices based on single-layer graphene transferred with a protective Al2O3 film onto SiO2 that show significantly reduced charge trap and residual carrier densities. We critically discuss the advantages and challenges of processing graphene/ALD bilayer structures.

Towards nanoprinting with metals on graphene.

PubMed

Melinte, G; Moldovan, S; Hirlimann, C; Liu, X; Bégin-Colin, S; Bégin, D; Banhart, F; Pham-Huu, C; Ersen, O

2015-08-28

Graphene and carbon nanotubes are envisaged as suitable materials for the fabrication of the new generation of nanoelectronics. The controlled patterning of such nanostructures with metal nanoparticles is conditioned by the transfer between a recipient and the surface to pattern. Electromigration under the impact of an applied voltage stands at the base of printing discrete digits at the nanoscale. Here we report the use of carbon nanotubes as nanoreservoirs for iron nanoparticles transfer on few-layer graphene. An initial Joule-induced annealing is required to ensure the control of the mass transfer with the nanotube acting as a 'pen' for the writing process. By applying a voltage, the tube filled with metal nanoparticles can deposit metal on the surface of the graphene sheet at precise locations. The reverse transfer of nanoparticles from the graphene surface to the nanotube when changing the voltage polarity opens the way for error corrections.

Towards nanoprinting with metals on graphene

NASA Astrophysics Data System (ADS)

Melinte, G.; Moldovan, S.; Hirlimann, C.; Liu, X.; Bégin-Colin, S.; Bégin, D.; Banhart, F.; Pham-Huu, C.; Ersen, O.

2015-08-01

Graphene and carbon nanotubes are envisaged as suitable materials for the fabrication of the new generation of nanoelectronics. The controlled patterning of such nanostructures with metal nanoparticles is conditioned by the transfer between a recipient and the surface to pattern. Electromigration under the impact of an applied voltage stands at the base of printing discrete digits at the nanoscale. Here we report the use of carbon nanotubes as nanoreservoirs for iron nanoparticles transfer on few-layer graphene. An initial Joule-induced annealing is required to ensure the control of the mass transfer with the nanotube acting as a `pen' for the writing process. By applying a voltage, the tube filled with metal nanoparticles can deposit metal on the surface of the graphene sheet at precise locations. The reverse transfer of nanoparticles from the graphene surface to the nanotube when changing the voltage polarity opens the way for error corrections.

Bioturbation and dissolved organic matter enhance contaminant fluxes from sediment treated with powdered and granular activated carbon.

PubMed

Kupryianchyk, D; Noori, A; Rakowska, M I; Grotenhuis, J T C; Koelmans, A A

2013-05-21

Sediment amendment with activated carbon (AC) is a promising technique for in situ sediment remediation. To date it is not clear whether this technique sufficiently reduces sediment-to-water fluxes of sediment-bound hydrophobic organic chemicals (HOCs) in the presence of bioturbators. Here, we report polychlorobiphenyl (PCB) pore water concentrations, fluxes, mass transfer coefficients, and survival data of two benthic species, for four treatments: no AC addition (control), powdered AC addition, granular AC addition and addition and subsequent removal of GAC (sediment stripping). AC addition decreased mass fluxes but increased apparent mass transfer coefficients because of dissolved organic carbon (DOC) facilitated transport across the benthic boundary layer (BBL). In turn, DOC concentrations depended on bioturbator activity which was high for the PAC tolerant species Asellus aquaticus and low for AC sensitive species Lumbriculus variegatus. A dual BBL resistance model combining AC effects on gradients, DOC facilitated transport and biodiffusion was evaluated against the data and showed how the type of resistance differs with treatment and chemical hydrophobicity. Data and simulations illustrate the complex interplay between AC and contaminant toxicity to benthic organisms and how differences in species tolerance affect mass fluxes from sediment to the water column.

Thermal Analysis and Design of Multi-layer Insulation for Re-entry Aerodynamic Heating

NASA Technical Reports Server (NTRS)

Daryabeigi, Kamran

2001-01-01

The combined radiation/conduction heat transfer in high-temperature multi-layer insulations was modeled using a finite volume numerical model. The numerical model was validated by comparison with steady-state effective thermal conductivity measurements, and by transient thermal tests simulating re-entry aerodynamic heating conditions. A design of experiments technique was used to investigate optimum design of multi-layer insulations for re-entry aerodynamic heating. It was found that use of 2 mm foil spacing and locating the foils near the hot boundary with the top foil 2 mm away from the hot boundary resulted in the most effective insulation design. A 76.2 mm thick multi-layer insulation using 1, 4, or 16 foils resulted in 2.9, 7.2, or 22.2 percent mass per unit area savings compared to a fibrous insulation sample at the same thickness, respectively.

Electrosorption capacitance of nanostructured carbon-based materials.

PubMed

Hou, Chia-Hung; Liang, Chengdu; Yiacoumi, Sotira; Dai, Sheng; Tsouris, Costas

2006-10-01

The fundamental mechanism of electrosorption of ions developing a double layer inside nanopores was studied via a combination of experimental and theoretical studies. A novel graphitized-carbon monolithic material has proven to be a good electrical double-layer capacitor that can be applied in the separation of ions from aqueous solutions. An extended electrical double-layer model indicated that the pore size distribution plays a key role in determining the double-layer capacitance in an electrosorption process. Because of the occurrence of double-layer overlapping in narrow pores, mesopores and micropores make significantly different contributions to the double-layer capacitance. Mesopores show good electrochemical accessibility. Micropores present a slow mass transfer of ions and a considerable loss of double-layer capacitance, associated with a shallow potential distribution inside pores. The formation of the diffuse layer inside the micropores determines the magnitude of the double-layer capacitance at low electrolyte concentrations and at conditions close to the point of zero charge of the material. The effect of the double-layer overlapping on the electrosorption capacitance can be reduced by increasing the pore size, electrolyte concentration, and applied potential. The results are relevant to water deionization.

On total turbulent energy and the passive and active role of buoyancy in turbulent momentum and mass transfer.

PubMed

de Nijs, Michel A J; Pietrzak, Julie D

Measurements of turbulent fluctuations of horizontal and vertical components of velocity, salinity and suspended particulate matter are presented. Turbulent Prandtl numbers are found to increase with stratification and to become larger than 1. Consequently, the vertical turbulent mass transport is suppressed by buoyancy forces, before the turbulent kinetic energy (TKE) and vertical turbulent momentum exchange are inhibited. With increasing stratification, the buoyancy fluxes do not cease, instead they become countergradient. We find that buoyantly driven motions play an active role in the transfer of mass. This is in agreement with trends derived from Monin-Obukhov scaling. For positive Richardson flux numbers (Ri f ), the log velocity profile in the near-bed layer requires correction with a drag reduction. For negative Ri f , the log velocity profile should be corrected with a drag increase, with increasing |Ri f |. This highlights the active role played by buoyancy in momentum transfer and the production of TKE. However, the data do not appear to entirely follow Monin-Obukhov scaling. This is consistent with the notion that the turbulence field is not in equilibrium. The large stratification results in the decay of turbulence and countergradient buoyancy fluxes act to restore equilibrium in the energy budget. This implies that there is a finite adjustment timescale of the turbulence field to changes in velocity shear and density stratification. The energy transfers associated with the source and sink function of the buoyancy flux can be modeled with the concept of total turbulent energy.

A simple approach for the sonochemical loading of Au, Ag and Pd nanoparticle on functionalized MWCNT and subsequent dispersion studies for removal of organic dyes: Artificial neural network and response surface methodology studies.

PubMed

Moghaddari, Mitra; Yousefi, Fakhri; Ghaedi, Mehrorang; Dashtian, Kheibar

2018-04-01

In this study, the artificial neural network (ANN) and response surface methodology (RSM) based on central composite design (CCD) were applied for modeling and optimization of the simultaneous ultrasound-assisted removal of quinoline yellow (QY) and eosin B (EB). The MWCNT-NH 2 and its composites were prepared by sonochemistry method and characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS) analysis's. Initial dyes concentrations, adsorbent mass, sonication time and pH contribution on QY and EB removal percentage were investigated by CCD and replication of experiments at conditions suggested by model has results which statistically are close to experimented data. The ultrasound irradiation is associated with raising mass transfer of process so that small amount of the adsorbent (0.025 g) is able to remove high percentage (88.00% and 91.00%) of QY and EB, respectively in short time (6.0 min) at pH = 6. Analysis of experimental data by conventional models is good indication of Langmuir efficiency for fitting and explanation of experimented data. The ANN based on the Levenberg-Marquardt algorithm (LMA) combined of linear transfer function at output layer and tangent sigmoid transfer function at hidden layer with 20 hidden neurons supply best operation conditions for good prediction of adsorption data. Accurate and efficient artificial neural network was obtained by changing the number of neurons in the hidden layer, while data was divided into training, test and validation sets which contained 70, 15 and 15% of data points respectively. The Average absolute deviation (AAD)% of a collection of 128 data points for MWCNT-NH 2 and composites is 0.58%.for EB and 0.55 for YQ. Copyright © 2017 Elsevier B.V. All rights reserved.

Methanol steam reforming promoted by molten salt-modified platinum on alumina catalysts.

PubMed

Kusche, Matthias; Agel, Friederike; Ní Bhriain, Nollaig; Kaftan, Andre; Laurin, Mathias; Libuda, Jörg; Wasserscheid, Peter

2014-09-01

We herein describe a straight forward procedure to increase the performance of platinum-on-alumina catalysts in methanol steam reforming by applying an alkali hydroxide coating according to the "solid catalyst with ionic liquid layer" (SCILL) approach. We demonstrate by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and temperature-programmed desorption (TPD) studies that potassium doping plays an important role in the catalyst activation. Moreover, the hygroscopic nature and the basicity of the salt modification contribute to the considerable enhancement in catalytic performance. During reaction, a partly liquid film of alkali hydroxides/carbonates forms on the catalyst/alumina surface, thus significantly enhancing the availability of water at the catalytically active sites. Too high catalyst pore fillings with salt introduce a considerable mass transfer barrier into the system as indicated by kinetic studies. Thus, the optimum interplay between beneficial catalyst modification and detrimental mass transfer effects had to be identified and was found on the applied platinum-on-alumina catalyst at KOH loadings around 7.5 mass%. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Hydrodynamic structure of the boundary layers in a rotating cylindrical cavity with radial inflow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Herrmann-Priesnitz, Benjamín, E-mail: bherrman@ing.uchile.cl; Torres, Diego A.; Advanced Mining Technology Center, Universidad de Chile, Av. Tupper 2007, Santiago

A flow model is formulated to investigate the hydrodynamic structure of the boundary layers of incompressible fluid in a rotating cylindrical cavity with steady radial inflow. The model considers mass and momentum transfer coupled between boundary layers and an inviscid core region. Dimensionless equations of motion are solved using integral methods and a space-marching technique. As the fluid moves radially inward, entraining boundary layers develop which can either meet or become non-entraining. Pressure and wall shear stress distributions, as well as velocity profiles predicted by the model, are compared to numerical simulations using the software OpenFOAM. Hydrodynamic structure of themore » boundary layers is governed by a Reynolds number, Re, a Rossby number, Ro, and the dimensionless radial velocity component at the periphery of the cavity, U{sub o}. Results show that boundary layers merge for Re < < 10 and Ro > > 0.1, and boundary layers become predominantly non-entraining for low Ro, low Re, and high U{sub o}. Results may contribute to improve the design of technology, such as heat exchange devices, and turbomachinery.« less

Two-Phase Solid/Fluid Simulation of Dense Granular Flows With Dilatancy Effects

NASA Astrophysics Data System (ADS)

Mangeney, Anne; Bouchut, Francois; Fernandez-Nieto, Enrique; Narbona-Reina, Gladys; Kone, El Hadj

2017-04-01

Describing grain/fluid interaction in debris flows models is still an open and challenging issue with key impact on hazard assessment [1]. We present here a two-phase two-thin-layer model for fluidized debris flows that takes into account dilatancy effects. It describes the velocity of both the solid and the fluid phases, the compression/ dilatation of the granular media and its interaction with the pore fluid pressure [2]. The model is derived from a 3D two-phase model proposed by Jackson [3] and the mixture equations are closed by a weak compressibility relation. This relation implies that the occurrence of dilation or contraction of the granular material in the model depends on whether the solid volume fraction is respectively higher or lower than a critical value. When dilation occurs, the fluid is sucked into the granular material, the pore pressure decreases and the friction force on the granular phase increases. On the contrary, in the case of contraction, the fluid is expelled from the mixture, the pore pressure increases and the friction force diminishes. To account for this transfer of fluid into and out of the mixture, a two-layer model is proposed with a fluid or a solid layer on top of the two-phase mixture layer. Mass and momentum conservation are satisfied for the two phases, and mass and momentum are transferred between the two layers. A thin-layer approximation is used to derive average equations. Special attention is paid to the drag friction terms that are responsible for the transfer of momentum between the two phases and for the appearance of an excess pore pressure with respect to the hydrostatic pressure. Interestingly, when removing the role of water, our model reduces to a dry granular flow model including dilatancy. We first compare experimental and numerical results of dilatant dry granular flows. Then, by quantitatively comparing the results of simulation and laboratory experiments on submerged granular flows, we show that our model contains the basic ingredients making it possible to reproduce the interaction between the granular and fluid phases through the change in pore fluid pressure. In particular, we analyse the different time scales in the model and their role in granular/fluid flow dynamics. References [1] R. Delannay, A. Valance, A. Mangeney, O. Roche, P. Richard, J. Phys. D: Appl. Phys., in press (2016). [2] F. Bouchut, E. D. Fernández-Nieto, A. Mangeney, G. Narbona-Reina, J. Fluid Mech., 801, 166-221 (2016). [3] R. Jackson, Cambridges Monographs on Mechanics (2000).

Transient heat transfer to a forced flow of supercritical helium at 4.2 K

NASA Astrophysics Data System (ADS)

Bloem, W. B.

The transient heat transfer coefficient of supercritical helium flowing through a rectangular copper tube with a hydraulic diameter of 5 mm has been measured. The conditions of the flow were: inlet bulk temperature of the fluid was 4.2 K pressures from 3 to 10 bar and Reynolds numbers between 1.5 × 10 4 and 2 × 10 5. The tube was heated on four sides with heat fluxes up to 9800 W m -2. From the experiments it followed that during the first tens of milliseconds the heat transfer is determined by the heat conduction in the boundary layer of the supercritical helium flow. The heat transfer coefficient can be described by h = 0.5(Π λ p C p/t) 1/2. Although the helium properties λ p and Cp are a strong function of pressure and temperature, it was remarkable that the temperature increase during a heat pulse was almost the same at different flow pressures. After analysing the data an empirical relation, h =b ṁ0.75 (t t/t) case1/n, was derived, which predicts the heat transfer coefficient at a given mass flow, ṁ, to within 10% during 0.1 s. The constants b, n and tt are related to the mass flow, ṁ, and the pressure of the fluid.

The optical properties of transferred graphene and the dielectrics grown on it obtained by ellipsometry

NASA Astrophysics Data System (ADS)

Kasikov, Aarne; Kahro, Tauno; Matisen, Leonard; Kodu, Margus; Tarre, Aivar; Seemen, Helina; Alles, Harry

2018-04-01

Graphene layers grown by chemical vapour deposition (CVD) method and transferred from Cu-foils to the oxidized Si-substrates were investigated by spectroscopic ellipsometry (SE), Raman and X-Ray Photoelectron Spectroscopy (XPS) methods. The optical properties of transferred CVD graphene layers do not always correspond to the ones of the exfoliated graphene due to the contamination from the chemicals used in the transfer process. However, the real thickness and the mean properties of the transferred CVD graphene layers can be found using ellipsometry if a real thickness of the SiO2 layer is taken into account. The pulsed laser deposition (PLD) and atomic layer deposition (ALD) methods were used to grow dielectric layers on the transferred graphene and the obtained structures were characterized using optical methods. The approach demonstrated in this work could be useful for the characterization of various materials grown on graphene.

A near-wall turbulence model and its application to fully developed turbulent channel and pipe flows

NASA Technical Reports Server (NTRS)

Kim, S.-W.

1988-01-01

A near wall turbulence model and its incorporation into a multiple-time-scale turbulence model are presented. In the method, the conservation of mass, momentum, and the turbulent kinetic energy equations are integrated up to the wall; and the energy transfer rate and the dissipation rate inside the near wall layer are obtained from algebraic equations. The algebraic equations for the energy transfer rate and the dissipation rate inside the near wall layer were obtained from a k-equation turbulence model and the near wall analysis. A fully developed turbulent channel flow and fully developed turbulent pipe flows were solved using a finite element method to test the predictive capability of the turbulence model. The computational results compared favorably with experimental data. It is also shown that the present turbulence model could resolve the over shoot phenomena of the turbulent kinetic energy and the dissipation rate in the region very close to the wall.

Core-shell microstructured nanocomposites for synergistic adjustment of environmental temperature and humidity

NASA Astrophysics Data System (ADS)

Zhang, Haiquan; Yuan, Yanping; Zhang, Nan; Sun, Qingrong; Cao, Xiaoling

2016-11-01

The adjustment of temperature and humidity is of great importance in a variety of fields. Composites that can perform both functions are prepared by mixing phase change materials (PCMs) with hygroscopic materials. However, the contact area between the adsorbent and humid air is inevitably decreased in such structures, which reduces the number of mass transfer channels for water vapor. An approach entailing the increase in the mass ratio of the adsorbent is presented here to improve the adsorption capacity. A core-shell CuSO4/polyethylene glycol (PEG) nanomaterial was developed to satisfy the conflicting requirements of temperature control and dehumidification. The results show that the equilibrium adsorption capacity of the PEG coating layer was enhanced by a factor of 188 compared with that of the pure PEG powder. The coating layer easily concentrates vapor, providing better adsorption properties for the composite. Furthermore, the volume modification of the CuSO4 matrix was reduced by 80% by the PEG coated layer, a factor that increases the stability of the composite. For the phase change process, the crystallization temperature of the coating layer was adjusted between 37.2 and 46.3 °C by interfacial tension. The core-shell CuSO4/PEG composite reported here provides a new general approach for the simultaneous control of temperature and humidity.

Method of transferring a thin crystalline semiconductor layer

DOEpatents

Nastasi, Michael A [Sante Fe, NM; Shao, Lin [Los Alamos, NM; Theodore, N David [Mesa, AZ

2006-12-26

A method for transferring a thin semiconductor layer from one substrate to another substrate involves depositing a thin epitaxial monocrystalline semiconductor layer on a substrate having surface contaminants. An interface that includes the contaminants is formed in between the deposited layer and the substrate. Hydrogen atoms are introduced into the structure and allowed to diffuse to the interface. Afterward, the thin semiconductor layer is bonded to a second substrate and the thin layer is separated away at the interface, which results in transferring the thin epitaxial semiconductor layer from one substrate to the other substrate.

Modelling the mid-infrared drying of sweet potato: kinetics, mass and heat transfer parameters, and energy consumption

NASA Astrophysics Data System (ADS)

Onwude, Daniel I.; Hashim, Norhashila; Abdan, Khalina; Janius, Rimfiel; Chen, Guangnan

2018-04-01

This study investigated the drying kinetics, mass and heat transfer characteristics of sweet potato slices (0.4-0.6 cm thickness) during drying based on mid-infrared experimental set-up (intensity of 1100-1400 W/m2). Thin layer drying models were used to evaluate the drying kinetics of sweet potato slices. Two analytical models (Fick's diffusion model, and Dincer and Dost model) were used to study the mass transfer behaviour of sweet potato slices with and without shrinkage during mid-infrared drying. The heat transfer flux between the emitter and sweet potato slices was also investigated. Results demonstrated that an increase in infrared intensity from 1100 W/m2 to 1400 W/m2 resulted in increased in average radiation heat flux by 3.4 times and a 15% reduction in the overall drying time. The two-term exponential model was found to be the best in predicting the drying kinetics of sweet potato slices during mid-infrared drying. The specific heat consumption varied from 0.91-4.82 kWh/kg. The effective moisture diffusivity with and without shrinkage using the Fick's diffusion model varied from 2.632 × 10-9 to 1.596 × 10-8 m2/s, and 1.24 × 10-8 to 2.4 × 10-8 m2/s using Dincer and Dost model, respectively. The obtained values of mass transfer coefficient, Biot number and activation energy varied from 5.99 × 10-6 to 1.17 × 10-5 m/s, 0.53 to 2.62, and 12.83 kJ/mol to 34.64 kJ/mol, respectively. The values obtained for Biot number implied the existence of simultaneous internal and external resistances. The findings further explained that mid-infrared intensity of 1100 W/m2 did not significantly affect the quality of sweet potato during drying, demonstrating a great potential of applying low intensity mid-infrared radiation in the drying of agricultural crops.

Mass and heat transfer between evaporation and condensation surfaces: Atomistic simulation and solution of Boltzmann kinetic equation.

PubMed

Zhakhovsky, Vasily V; Kryukov, Alexei P; Levashov, Vladimir Yu; Shishkova, Irina N; Anisimov, Sergey I

2018-04-16

Boundary conditions required for numerical solution of the Boltzmann kinetic equation (BKE) for mass/heat transfer between evaporation and condensation surfaces are analyzed by comparison of BKE results with molecular dynamics (MD) simulations. Lennard-Jones potential with parameters corresponding to solid argon is used to simulate evaporation from the hot side, nonequilibrium vapor flow with a Knudsen number of about 0.02, and condensation on the cold side of the condensed phase. The equilibrium density of vapor obtained in MD simulation of phase coexistence is used in BKE calculations for consistency of BKE results with MD data. The collision cross-section is also adjusted to provide a thermal flux in vapor identical to that in MD. Our MD simulations of evaporation toward a nonreflective absorbing boundary show that the velocity distribution function (VDF) of evaporated atoms has the nearly semi-Maxwellian shape because the binding energy of atoms evaporated from the interphase layer between bulk phase and vapor is much smaller than the cohesive energy in the condensed phase. Indeed, the calculated temperature and density profiles within the interphase layer indicate that the averaged kinetic energy of atoms remains near-constant with decreasing density almost until the interphase edge. Using consistent BKE and MD methods, the profiles of gas density, mass velocity, and temperatures together with VDFs in a gap of many mean free paths between the evaporation and condensation surfaces are obtained and compared. We demonstrate that the best fit of BKE results with MD simulations can be achieved with the evaporation and condensation coefficients both close to unity.

Second principle approach to the analysis of unsteady flow and heat transfer in a tube with arc-shaped corrugation

NASA Astrophysics Data System (ADS)

Pagliarini, G.; Vocale, P.; Mocerino, A.; Rainieri, S.

2017-01-01

Passive convective heat transfer enhancement techniques are well known and widespread tool for increasing the efficiency of heat transfer equipment. In spite of the ability of the first principle approach to forecast the macroscopic effects of the passive techniques for heat transfer enhancement, namely the increase of both the overall heat exchanged and the head losses, a first principle analysis based on energy, momentum and mass local conservation equations is hardly able to give a comprehensive explanation of how local modifications in the boundary layers contribute to the overall effect. A deeper insight on the heat transfer enhancement mechanisms can be instead obtained within a second principle approach, through the analysis of the local exergy dissipation phenomena which are related to heat transfer and fluid flow. To this aim, the analysis based on the second principle approach implemented through a careful consideration of the local entropy generation rate seems the most suitable, since it allows to identify more precisely the cause of the loss of efficiency in the heat transfer process, thus providing a useful guide in the choice of the most suitable heat transfer enhancement techniques.

Influence of metal bonding layer on strain transfer performance of FBG

NASA Astrophysics Data System (ADS)

Liu, Hao; Chen, Weimin; Zhang, Peng; Liu, Li; Shu, Yuejie; Wu, Jun

2013-01-01

Metal bonding layer seriously affects the strain transfer performance of Fiber Bragg Grating (FBG). Based on the mode of FBG strain transfer, the influence of the length, the thickness, Poisson's ratio, elasticity modulus of metal bonding layer on the strain transfer coefficient of FBG is analyzed by numerical simulation. FBG is packaged to steel wire using metal bonding technology of FBG. The tensile tests of different bonding lengths and elasticity modulus are carried out. The result shows the strain transfer coefficient of FBGs are 0.9848,0.962 and their average strain sensitivities are 1.076 pm/μɛ,1.099 pm/μɛ when the metal bonding layer is zinc, whose lengths are 15mm, 20mm, respectively. The strain transfer coefficient of FBG packaged by metal bonding layer raises 8.9 percent compared to epoxy glue package. The preliminary experimental results show that the strain transfer coefficient increases with the length of metal bonding layer, decreases with the thickness of metal bonding layer and the influence of Poisson's ratio can be ignored. The experiment result is general agreement with the analysis and provides guidance for metal package of FBG.

Release strategies for making transferable semiconductor structures, devices and device components

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rogers, John A.; Nuzzo, Ralph G.; Meitl, Matthew

2016-05-24

Provided are methods for making a device or device component by providing a multi layer structure having a plurality of functional layers and a plurality of release layers and releasing the functional layers from the multilayer structure by separating one or more of the release layers to generate a plurality of transferable structures. The transferable structures are printed onto a device substrate or device component supported by a device substrate. The methods and systems provide means for making high-quality and low-cost photovoltaic devices, transferable semiconductor structures, (opto-)electronic devices and device components.

Studying interfacial reactions of cholesterol sulfate in an unsaturated phosphatidylglycerol layer with ozone using field induced droplet ionization mass spectrometry.

PubMed

Ko, Jae Yoon; Choi, Sun Mi; Rhee, Young Min; Beauchamp, J L; Kim, Hugh I

2012-01-01

Field-induced droplet ionization (FIDI) is a recently developed ionization technique that can transfer ions from the surface of microliter droplets to the gas phase intact. The air-liquid interfacial reactions of cholesterol sulfate (CholSO(4)) in a 1-palmitoyl-2-oleoyl-sn-phosphatidylglycerol (POPG) surfactant layer with ozone (O(3)) are investigated using field-induced droplet ionization mass spectrometry (FIDI-MS). Time-resolved studies of interfacial ozonolysis of CholSO(4) reveal that water plays an important role in forming oxygenated products. An epoxide derivative is observed as a major product of CholSO(4) oxidation in the FIDI-MS spectrum after exposure of the droplet to O(3) for 5 s. The abundance of the epoxide product then decreases with continued O(3) exposure as the finite number of water molecules at the air-liquid interface becomes exhausted. Competitive oxidation of CholSO(4) and POPG is observed when they are present together in a lipid surfactant layer at the air-liquid interface. Competitive reactions of CholSO(4) and POPG with O(3) suggest that CholSO(4) is present with POPG as a well-mixed interfacial layer. Compared with CholSO(4) and POPG alone, the overall ozonolysis rates of both CholSO(4) and POPG are reduced in a mixed layer, suggesting the double bonds of both molecules are shielded by additional hydrocarbons from one another. Molecular dynamics simulations of a monolayer comprising POPG and CholSO(4) correlate well with experimental observations and provide a detailed picture of the interactions between CholSO(4), lipids, and water molecules in the interfacial region. © American Society for Mass Spectrometry, 2011

Similar solutions of double-diffusive dissipative layers along free surfaces

NASA Astrophysics Data System (ADS)

Napolitano, L. G.; Viviani, A.; Savino, R.

1990-10-01

Free convection due to buoyant forces (natural convection) and surface tension gradients (Marangoni convection) generated by temperature and concentration gradients is discussed together with the formation of double-diffusive boundary layers along liquid-gas interfaces. Similarity solutions for each class of free convection are derived and the resulting nonlinear two-point problems are solved numerically using the quasi-linearization method. Velocity, temperature, concentration profiles, interfacial velocity, heat and mass transfer bulk coefficients for various Prandtl and Schmidt numbers, and different values of the similarity parameters are determined. The convective flows are of particular interest because they are considered to influence the processes of crystal growth, both on earth and in a microgravity environment.

Flow-induced corrosion of absorbable magnesium alloy: In-situ and real-time electrochemical study

PubMed Central

Wang, Juan; Jang, Yongseok; Wan, Guojiang; Giridharan, Venkataraman; Song, Guang-Ling; Xu, Zhigang; Koo, Youngmi; Qi, Pengkai; Sankar, Jagannathan; Huang, Nan; Yun, Yeoheung

2016-01-01

An in-situ and real-time electrochemical study in a vascular bioreactor was designed to analyze corrosion mechanism of magnesium alloy (MgZnCa) under mimetic hydrodynamic conditions. Effect of hydrodynamics on corrosion kinetics, types, rates and products was analyzed. Flow-induced shear stress (FISS) accelerated mass and electron transfer, leading to an increase in uniform and localized corrosions. FISS increased the thickness of uniform corrosion layer, but filiform corrosion decreased this layer resistance at high FISS conditions. FISS also increased the removal rate of localized corrosion products. Impedance-estimated and linear polarization-measured polarization resistances provided a consistent correlation to corrosion rate calculated by computed tomography. PMID:28626241

Flow-induced corrosion of absorbable magnesium alloy: In-situ and real-time electrochemical study.

PubMed

Wang, Juan; Jang, Yongseok; Wan, Guojiang; Giridharan, Venkataraman; Song, Guang-Ling; Xu, Zhigang; Koo, Youngmi; Qi, Pengkai; Sankar, Jagannathan; Huang, Nan; Yun, Yeoheung

2016-03-01

An in-situ and real-time electrochemical study in a vascular bioreactor was designed to analyze corrosion mechanism of magnesium alloy (MgZnCa) under mimetic hydrodynamic conditions. Effect of hydrodynamics on corrosion kinetics, types, rates and products was analyzed. Flow-induced shear stress (FISS) accelerated mass and electron transfer, leading to an increase in uniform and localized corrosions. FISS increased the thickness of uniform corrosion layer, but filiform corrosion decreased this layer resistance at high FISS conditions. FISS also increased the removal rate of localized corrosion products. Impedance-estimated and linear polarization-measured polarization resistances provided a consistent correlation to corrosion rate calculated by computed tomography.

Object recognition using deep convolutional neural networks with complete transfer and partial frozen layers

NASA Astrophysics Data System (ADS)

Kruithof, Maarten C.; Bouma, Henri; Fischer, Noëlle M.; Schutte, Klamer

2016-10-01

Object recognition is important to understand the content of video and allow flexible querying in a large number of cameras, especially for security applications. Recent benchmarks show that deep convolutional neural networks are excellent approaches for object recognition. This paper describes an approach of domain transfer, where features learned from a large annotated dataset are transferred to a target domain where less annotated examples are available as is typical for the security and defense domain. Many of these networks trained on natural images appear to learn features similar to Gabor filters and color blobs in the first layer. These first-layer features appear to be generic for many datasets and tasks while the last layer is specific. In this paper, we study the effect of copying all layers and fine-tuning a variable number. We performed an experiment with a Caffe-based network on 1000 ImageNet classes that are randomly divided in two equal subgroups for the transfer from one to the other. We copy all layers and vary the number of layers that is fine-tuned and the size of the target dataset. We performed additional experiments with the Keras platform on CIFAR-10 dataset to validate general applicability. We show with both platforms and both datasets that the accuracy on the target dataset improves when more target data is used. When the target dataset is large, it is beneficial to freeze only a few layers. For a large target dataset, the network without transfer learning performs better than the transfer network, especially if many layers are frozen. When the target dataset is small, it is beneficial to transfer (and freeze) many layers. For a small target dataset, the transfer network boosts generalization and it performs much better than the network without transfer learning. Learning time can be reduced by freezing many layers in a network.

Additive erosion reduction influences in the turbulent boundary layer

NASA Astrophysics Data System (ADS)

Buckingham, A. C.

1981-05-01

Results of a sequence of flow, heat and mass transfer calculations are presented which theoretically characterize the erosive environment at the wall surface of refractory metal coated and uncoated gun barrels. The theoretical results include analysis of the wall surface temperature, heat flux, and shear stress time histories on thin (10 mil.) Cr, Mo, Nb, and Ta plated steel barrel walls as uncoated steel walls. The calculations combine effects of a number of separate processes which were previously (and purposely) studied individually. These include solid particle additive concentrations, gas wall thermochemical influences, and transient turbulent wall boundary layer flow with multicomponent molecular diffusion and reactions from interaction of propellant combustion and the eroding surface. The boundary layer model includes particulate additive concentrations as well as propellant combustion products, considered for the present to be in the local thermochemical equilibrium.

Method of transferring strained semiconductor structure

DOEpatents

Nastasi, Michael A [Santa Fe, NM; Shao, Lin [College Station, TX

2009-12-29

The transfer of strained semiconductor layers from one substrate to another substrate involves depositing a multilayer structure on a substrate having surface contaminants. An interface that includes the contaminants is formed in between the deposited layer and the substrate. Hydrogen atoms are introduced into the structure and allowed to diffuse to the interface. Afterward, the deposited multilayer structure is bonded to a second substrate and is separated away at the interface, which results in transferring a multilayer structure from one substrate to the other substrate. The multilayer structure includes at least one strained semiconductor layer and at least one strain-induced seed layer. The strain-induced seed layer can be optionally etched away after the layer transfer.

Epitaxial growth of silicon for layer transfer

DOEpatents

Teplin, Charles; Branz, Howard M

2015-03-24

Methods of preparing a thin crystalline silicon film for transfer and devices utilizing a transferred crystalline silicon film are disclosed. The methods include preparing a silicon growth substrate which has an interface defining substance associated with an exterior surface. The methods further include depositing an epitaxial layer of silicon on the silicon growth substrate at the surface and separating the epitaxial layer from the substrate substantially along the plane or other surface defined by the interface defining substance. The epitaxial layer may be utilized as a thin film of crystalline silicon in any type of semiconductor device which requires a crystalline silicon layer. In use, the epitaxial transfer layer may be associated with a secondary substrate.

Experimental evaluation of heat transfer efficiency of nanofluid in a double pipe heat exchanger and prediction of experimental results using artificial neural networks

NASA Astrophysics Data System (ADS)

Maddah, Heydar; Ghasemi, Nahid

2017-12-01

In this study, heat transfer efficiency of water and iron oxide nanofluid in a double pipe heat exchanger equipped with a typical twisted tape is experimentally investigated and impacts of the concentration of nanofluid and twisted tape on the heat transfer efficiency are also studied. Experiments were conducted under the laminar and turbulent flow for Reynolds numbers in the range of 1000 to 6000 and the concentration of nanofluid was 0.01, 0.02 and 0.03 wt%. In order to model and predict the heat transfer efficiency, an artificial neural network was used. The temperature of the hot fluid (nanofluid), the temperature of the cold fluid (water), mass flow rate of hot fluid (nanofluid), mass flow rate of cold fluid (water), the concentration of nanofluid and twist ratio are input data in artificial neural network and heat transfer is output or target. Heat transfer efficiency in the presence of 0.03 wt% nanofluid increases by 30% while using both the 0.03 wt% nanofluid and twisted tape with twist ratio 2 increases the heat transfer efficiency by 60%. Implementation of various structures of neural network with different number of neurons in the middle layer showed that 1-10-6 arrangement with the correlation coefficient 0.99181 and normal root mean square error 0.001621 is suggested as a desirable arrangement. The above structure has been successful in predicting 72% to 97%of variation in heat transfer efficiency characteristics based on the independent variables changes. In total, comparing the predicted results in this study with other studies and also the statistical measures shows the efficiency of artificial neural network.

Heat Transfer to Surfaces of Finite Catalytic Activity in Frozen Dissociated Hypersonic Flow

NASA Technical Reports Server (NTRS)

Chung, Paul M.; Anderson, Aemer D.

1961-01-01

The heat transfer due to catalytic recombination of a partially dissociated diatomic gas along the surfaces of two-dimensional and axisymmetric bodies with finite catalytic efficiencies is studied analytically. An integral method is employed resulting in simple yet relatively complete solutions for the particular configurations considered. A closed form solution is derived which enables one to calculate atom mass-fraction distribution, therefore catalytic heat transfer distribution, along the surface of a flat plate in frozen compressible flow with and without transpiration. Numerical calculations are made to determine the atom mass-fraction distribution along an axisymmetric conical body with spherical nose in frozen hypersonic compressible flow. A simple solution based on a local similarity concept is found to be in good agreement with these numerical calculations. The conditions are given for which the local similarity solution is expected to be satisfactory. The limitations on the practical application of the analysis to the flight of the blunt bodies in the atmosphere are discussed. The use of boundary-layer theory and the assumption of frozen flow restrict application of the analysis to altitudes between about 150,000 and 250,000 feet.

HEAT TRANSFER FROM SURFACES OF NON-UNIFORM TEMPERATURE DISTRIBUTION. PART II. TURBULENT TRANSFER FROM ISOTHERMAL SPANWISE STRIPS ON A FLAT PLATE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sogin, H.H.; Goldstein, R.J.

1960-02-01

Experiments were performed on mass transfer by forced convection from naphthalene strips on a flat plate to an air stream at ordinary temperature and pressure. Turbulence was induced in the boundary layer by means of a wire strip. In all cases there was a hydrodynamic starting length upstream of the strips. The ratio of this inert length to the total length was varied from about 0.80 to 0.96. The flow was practically incompressible with Reynolds number, based on the total length, varying from 175,000 to 486,000. The Schmidt number was 2.5. The experimental results fell in proximity to the Sebanmore » step function factor when they were reduced after the massmomentum analysis of Deissler and Loeffler for a surface of uniform vapor pressure. When Karman's formulation of the mass- momentum analogy was assumed, the data fell between the values predicted by the Seban and by the Rubesin expression for the step function factor. The results were well correlated by the Colburn analogy in conjunction with the Rubesin step function factor. (auth)« less

Numerical modeling of heat transfer during hydrogen absorption in thin double-layered annular ZrCo beds

NASA Astrophysics Data System (ADS)

Cui, Yehui; Zeng, Xiangguo; Kou, Huaqin; Ding, Jun; Wang, Fang

2018-06-01

In this work a three-dimensional (3D) hydrogen absorption model was proposed to study the heat transfer behavior in thin double-layered annular ZrCo beds. Numerical simulations were performed to investigate the effects of conversion layer thickness, thermal conductivity, cooling medium and its flow velocity on the efficiency of heat transfer. Results reveal that decreasing the layer thickness and improving the thermal conductivity enhance the ability of heat transfer. Compared with nitrogen and helium, water appears to be a better medium for cooling. In order to achieve the best efficiency of heat transfer, the flow velocity needs to be maximized.

A model for soft X-ray transients

NASA Astrophysics Data System (ADS)

Hameury, J. M.; King, A. R.; Lasota, J. P.

1986-07-01

The existing database on the physical characteristics of stellar soft and ultrasoft transient X-ray bursts is summarized in order to form a generic model for the sources. The bursts have come from binary systems which repeat the bursts with a frequency of about a year. Bursts possess energies of about 10 to the 44th ergs emitted for months and reaching maximum luminosities of 10 to the 37th to 10 to the 38th ergs, levels associated with an accretion rate of 10 billion grams/sec. The transients are shown to arise because of a mass loss instability in the secondary star, believed to be red dwarf. Analysis of the structure of the envelope of a dwarf heated by X-rays shows that subphotospheric layers can expand during the quiescent phase and enter into a mass transfer instability condition near the Roche lobe. The accretion disk eventually blocks the X-ray input and the transfer to the primary, a neutron star, abates.

Thermophoresis on boundary layer heat and mass transfer flow of Walters-B fluid past a radiate plate with heat sink/source

NASA Astrophysics Data System (ADS)

Vasu, B.; Gorla, Rama Subba Reddy; Murthy, P. V. S. N.

2017-05-01

The Walters-B liquid model is employed to simulate medical creams and other rheological liquids encountered in biotechnology and chemical engineering. This rheological model introduces supplementary terms into the momentum conservation equation. The combined effects of thermal radiation and heat sink/source on transient free convective, laminar flow and mass transfer in a viscoelastic fluid past a vertical plate are presented by taking thermophoresis effect into account. The transformed conservation equations are solved using a stable, robust finite difference method. A parametric study illustrating the influence of viscoelasticity parameter ( Γ), thermophoretic parameter ( τ), thermal radiation parameter ( F), heat sink/source ( ϕ), Prandtl number ( Pr), Schmidt number ( Sc), thermal Grashof number ( Gr), solutal Grashof number ( Gm), temperature and concentration profiles as well as local skin-friction, Nusselt and Sherwood number is conducted. The results of this parametric study are shown graphically and inform of table. The study has applications in polymer materials processing.

Thermal conductivity of microporous layers: Analytical modeling and experimental validation

NASA Astrophysics Data System (ADS)

Andisheh-Tadbir, Mehdi; Kjeang, Erik; Bahrami, Majid

2015-11-01

A new compact relationship is developed for the thermal conductivity of the microporous layer (MPL) used in polymer electrolyte fuel cells as a function of pore size distribution, porosity, and compression pressure. The proposed model is successfully validated against experimental data obtained from a transient plane source thermal constants analyzer. The thermal conductivities of carbon paper samples with and without MPL were measured as a function of load (1-6 bars) and the MPL thermal conductivity was found between 0.13 and 0.17 W m-1 K-1. The proposed analytical model predicts the experimental thermal conductivities within 5%. A correlation generated from the analytical model was used in a multi objective genetic algorithm to predict the pore size distribution and porosity for an MPL with optimized thermal conductivity and mass diffusivity. The results suggest that an optimized MPL, in terms of heat and mass transfer coefficients, has an average pore size of 122 nm and 63% porosity.

Electrochemically Produced Graphene for Microporous Layers in Fuel Cells.

PubMed

Najafabadi, Amin Taheri; Leeuwner, Magrieta J; Wilkinson, David P; Gyenge, Előd L

2016-07-07

The microporous layer (MPL) is a key cathodic component in proton exchange membrane fuel cells owing to its beneficial influence on two-phase mass transfer. However, its performance is highly dependent on material properties such as morphology, porous structure, and electrical resistance. To improve water management and performance, electrochemically exfoliated graphene (EGN) microsheets are considered as an alternative to the conventional carbon black (CB) MPLs. The EGN-based MPLs decrease the kinetic overpotential and the Ohmic potential loss, whereas the addition of CB to form a composite EGN+CB MPL improves the mass-transport limiting current density drastically. This is reflected by increases of approximately 30 and 70 % in peak power densities at 100 % relative humidity (RH) compared with those for CB- and EGN-only MPLs, respectively. The composite EGN+CB MPL also retains the superior performance at a cathode RH of 20 %, whereas the CB MPL shows significant performance loss. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Development of a model and computer code to describe solar grade silicon production processes

NASA Technical Reports Server (NTRS)

Gould, R. K.; Srivastava, R.

1979-01-01

Two computer codes were developed for describing flow reactors in which high purity, solar grade silicon is produced via reduction of gaseous silicon halides. The first is the CHEMPART code, an axisymmetric, marching code which treats two phase flows with models describing detailed gas-phase chemical kinetics, particle formation, and particle growth. It can be used to described flow reactors in which reactants, mix, react, and form a particulate phase. Detailed radial gas-phase composition, temperature, velocity, and particle size distribution profiles are computed. Also, deposition of heat, momentum, and mass (either particulate or vapor) on reactor walls is described. The second code is a modified version of the GENMIX boundary layer code which is used to compute rates of heat, momentum, and mass transfer to the reactor walls. This code lacks the detailed chemical kinetics and particle handling features of the CHEMPART code but has the virtue of running much more rapidly than CHEMPART, while treating the phenomena occurring in the boundary layer in more detail.

The behavior of a compressible turbulent boundary layer in a shock-wave-induced adverse pressure gradient. Ph.D. Thesis - Washington Univ., Seattle, Aug. 1972

NASA Technical Reports Server (NTRS)

Rose, W. C.

1973-01-01

The results of an experimental investigation of the mean- and fluctuating-flow properties of a compressible turbulent boundary layer in a shock-wave-induced adverse pressure gradient are presented. The turbulent boundary layer developed on the wall of an axially symmetric nozzle and test section whose nominal free-stream Mach number and boundary-layer thickness Reynolds number were 4 and 100,000, respectively. The adverse pressure gradient was induced by an externally generated conical shock wave. Mean and time-averaged fluctuating-flow data, including the complete experimental Reynolds stress tensor and experimental turbulent mass- and heat-transfer rates are presented for the boundary layer and external flow, upstream, within and downstream of the pressure gradient. The mean-flow data include distributions of total temperature throughout the region of interest. The turbulent mixing properties of the flow were determined experimentally with a hot-wire anemometer. The calibration of the wires and the interpretation of the data are discussed. From the results of the investigation, it is concluded that the shock-wave - boundary-layer interaction significantly alters the turbulent mixing characteristics of the boundary layer.

Development of a thermal-hydraulics experimental system for high Tc superconductors cooled by liquid hydrogen

NASA Astrophysics Data System (ADS)

Tatsumoto, H.; Shirai, Y.; Shiotsu, M.; Hata, K.; Kobayashi, H.; Naruo, Y.; Inatani, Y.; Kato, T.; Futakawa, M.; Kinoshita, K.

2010-06-01

A thermal-hydraulics experimental system of liquid hydrogen was developed in order to investigate the forced flow heat transfer characteristics in the various cooling channels for wide ranges of subcoolings, flow velocities, and pressures up to supercritical. A main tank is connected to a sub tank through a hydrogen transfer line with a control valve. A channel heater is located at one end of the transfer line in the main tank. Forced flow through the channel is produced by adjusting the pressure difference between the tanks and the valve opening. The mass flow rate is measured from the weight change of the main tank. For the explosion protection, electrical equipments are covered with a nitrogen gas blanket layer and a remote control system was established. The first cryogenic performance tests confirmed that the experimental system had satisfied with the required performances. The forced convection heat transfer characteristics was successfully measured at the pressure of 0.7 MPa for various flow velocities.

Model for heat and mass transfer in freeze-drying of pellets.

PubMed

Trelea, Ioan Cristian; Passot, Stéphanie; Marin, Michèle; Fonseca, Fernanda

2009-07-01

Lyophilizing frozen pellets, and especially spray freeze-drying, have been receiving growing interest. To design efficient and safe freeze-drying cycles, local temperature and moisture content in the product bed have to be known, but both are difficult to measure in the industry. Mathematical modeling of heat and mass transfer helps to determine local freeze-drying conditions and predict effects of operation policy, and equipment and recipe changes on drying time and product quality. Representative pellets situated at different positions in the product slab were considered. One-dimensional transfer in the slab and radial transfer in the pellets were assumed. Coupled heat and vapor transfer equations between the temperature-controlled shelf, the product bulk, the sublimation front inside the pellets, and the chamber were established and solved numerically. The model was validated based on bulk temperature measurement performed at two different locations in the product slab and on partial vapor pressure measurement in the freeze-drying chamber. Fair agreement between measured and calculated values was found. In contrast, a previously developed model for compact product layer was found inadequate in describing freeze-drying of pellets. The developed model represents a good starting basis for studying freeze-drying of pellets. It has to be further improved and validated for a variety of product types and freeze-drying conditions (shelf temperature, total chamber pressure, pellet size, slab thickness, etc.). It could be used to develop freeze-drying cycles based on product quality criteria such as local moisture content and glass transition temperature.

Formation of Au nano-patterns on various substrates using simplified nano-transfer printing method

NASA Astrophysics Data System (ADS)

Kim, Jong-Woo; Yang, Ki-Yeon; Hong, Sung-Hoon; Lee, Heon

2008-06-01

For future device applications, fabrication of the metal nano-patterns on various substrates, such as Si wafer, non-planar glass lens and flexible plastic films become important. Among various nano-patterning technologies, nano-transfer print method is one of the simplest techniques to fabricate metal nano-patterns. In nano-transfer printing process, thin Au layer is deposited on flexible PDMS mold, containing surface protrusion patterns, and the Au layer is transferred from PDMS mold to various substrates due to the difference of bonding strength of Au layer to PDMS mold and to the substrate. For effective transfer of Au layer, self-assembled monolayer, which has strong bonding to Au, is deposited on the substrate as a glue layer. In this study, complicated SAM layer coating process was replaced to simple UV/ozone treatment, which can activates the surface and form the -OH radicals. Using simple UV/ozone treatments on both Au and substrate, Au nano-pattern can be successfully transferred to as large as 6 in. diameter Si wafer, without SAM coating process. High fidelity transfer of Au nano-patterns to non-planar glass lens and flexible PET film was also demonstrated.

Effect of atmospheric-pressure plasma treatment on the adhesion properties of a thin adhesive layer in a selective transfer process

NASA Astrophysics Data System (ADS)

Yoon, Min-Ah; Kim, Chan; Hur, Min; Kang, Woo Seok; Kim, Jaegu; Kim, Jae-Hyun; Lee, Hak-Joo; Kim, Kwang-Seop

2018-01-01

The adhesion between a stamp and thin film devices is crucial for their transfer on a flexible substrate. In this paper, a thin adhesive silicone layer on the stamp was treated by atmospheric pressure plasma to locally control the adhesion strength for the selective transfer. The adhesion strength of the silicone layer was significantly reduced after the plasma treatment, while its surface energy was increased. To understand the inconsistency between the adhesion strength and surface energy changes, the surface properties of the silicone layer were characterized using nanoindentation and X-ray photoelectron spectroscopy. These techniques revealed that a thin, hard, silica-like layer had formed on the surface from plasma-enhanced oxidation. This layer played an important role in decreasing the contact area and increasing the interfacial slippage, resulting in decreased adhesion. As a practical application, the transfer process was demonstrated on GaN LEDs that had been previously delaminated by a laser lift-off (LLO) process. Although the LEDs were not transferred onto the treated adhesive layer due to the reduced adhesion, the untreated adhesive layer could readily pick up the LEDs. It is expected that this simple method of controlling the adhesion of a stamp with a thin adhesive layer would enable a continuous, selective and large-scale roll-to-roll selective transfer process and thereby advance the development of flexible, stretchable and wearable electronics.

Formation and investigation of ultrathin layers of Co2FeSi ferromagnetic alloy synthesized on silicon covered with a CaF2 barrier layer

NASA Astrophysics Data System (ADS)

Grebenyuk, G. S.; Gomoyunova, M. V.; Pronin, I. I.; Vyalikh, D. V.; Molodtsov, S. L.

2016-03-01

Ultrathin (∼2 nm) films of Co2FeSi ferromagnetic alloy were formed on silicon by solid-phase epitaxy and studied in situ. Experiments were carried out in an ultrahigh vacuum (UHV) using substrates of Si(1 1 1) single crystals covered with a 5 nm thick CaF2 barrier layer. The elemental and phase composition as well as the magnetic properties of the synthesized films were analyzed by photoelectron spectroscopy using synchrotron radiation and by magnetic linear dichroism in photoemission of Fe 3p and Co 3p electrons. The study shows that the synthesis of the Co2FeSi ferromagnetic alloy occurs in the temperature range of 200-400 °C. At higher temperatures, the films become island-like and lose their ferromagnetic properties, as the CaF2 barrier layer is unable to prevent a mass transfer between the film and the Si substrate, which violates the stoichiometry of the alloy.

A review of high-speed, convective, heat-transfer computation methods

NASA Technical Reports Server (NTRS)

Tauber, Michael E.

1989-01-01

The objective of this report is to provide useful engineering formulations and to instill a modest degree of physical understanding of the phenomena governing convective aerodynamic heating at high flight speeds. Some physical insight is not only essential to the application of the information presented here, but also to the effective use of computer codes which may be available to the reader. A discussion is given of cold-wall, laminar boundary layer heating. A brief presentation of the complex boundary layer transition phenomenon follows. Next, cold-wall turbulent boundary layer heating is discussed. This topic is followed by a brief coverage of separated flow-region and shock-interaction heating. A review of heat protection methods follows, including the influence of mass addition on laminar and turbulent boundary layers. Also discussed are a discussion of finite-difference computer codes and a comparison of some results from these codes. An extensive list of references is also provided from sources such as the various AIAA journals and NASA reports which are available in the open literature.

A review of high-speed, convective, heat-transfer computation methods

NASA Technical Reports Server (NTRS)

Tauber, Michael E.

1989-01-01

The objective is to provide useful engineering formulations and to instill a modest degree of physical understanding of the phenomena governing convective aerodynamic heating at high flight speeds. Some physical insight is not only essential to the application of the information presented here, but also to the effective use of computer codes which may be available to the reader. Given first is a discussion of cold-wall, laminar boundary layer heating. A brief presentation of the complex boundary layer transition phenomenon follows. Next, cold-wall turbulent boundary layer heating is discussed. This topic is followed by a brief coverage of separated flow-region and shock-interaction heating. A review of heat protection methods follows, including the influence of mass addition on laminar and turbulent boundary layers. Next is a discussion of finite-difference computer codes and a comparison of some results from these codes. An extensive list of references is also provided from sources such as the various AIAA journals and NASA reports which are available in the open literature.

Airfoil deposition model

NASA Technical Reports Server (NTRS)

Kohl, F. J.

1982-01-01

The methodology to predict deposit evolution (deposition rate and subsequent flow of liquid deposits) as a function of fuel and air impurity content and relevant aerodynamic parameters for turbine airfoils is developed in this research. The spectrum of deposition conditions encountered in gas turbine operations includes the mechanisms of vapor deposition, small particle deposition with thermophoresis, and larger particle deposition with inertial effects. The focus is on using a simplified version of the comprehensive multicomponent vapor diffusion formalism to make deposition predictions for: (1) simple geometry collectors; and (2) gas turbine blade shapes, including both developing laminar and turbulent boundary layers. For the gas turbine blade the insights developed in previous programs are being combined with heat and mass transfer coefficient calculations using the STAN 5 boundary layer code to predict vapor deposition rates and corresponding liquid layer thicknesses on turbine blades. A computer program is being written which utilizes the local values of the calculated deposition rate and skin friction to calculate the increment in liquid condensate layer growth along a collector surface.

Subsurface Characterization using Geophysical Seismic Refraction Survey for Slope Stabilization Design with Soil Nailing

NASA Astrophysics Data System (ADS)

Ashraf Mohamad Ismail, Mohd; Ng, Soon Min; Hazreek Zainal Abidin, Mohd; Madun, Aziman

2018-04-01

The application of geophysical seismic refraction for slope stabilization design using soil nailing method was demonstrated in this study. The potential weak layer of the study area is first identify prior to determining the appropriate length and location of the soil nail. A total of 7 seismic refraction survey lines were conducted at the study area with standard procedures. The refraction data were then analyzed by using the Pickwin and Plotrefa computer software package to obtain the seismic velocity profiles distribution. These results were correlated with the complementary borehole data to interpret the subsurface profile of the study area. It has been identified that layer 1 to 3 is the potential weak zone susceptible to slope failure. Hence, soil nails should be installed to transfer the tensile load from the less stable layer 3 to the more stable layer 4. The soil-nail interaction will provide a reinforcing action to the soil mass thereby increasing the stability of the slope.

Laser induced forward transfer of graphene

NASA Astrophysics Data System (ADS)

Smits, Edsger C. P.; Walter, Arnaud; de Leeuw, Dago M.; Asadi, Kamal

2017-10-01

Transfer of graphene and other two-dimensional materials is still a technical challenge. The 2D-materials are typically patterned after transfer, which leads to a major loss of material. Here, we present laser induced forward transfer of chemical vapor deposition grown graphene layers with well-defined shapes and geometries. The transfer is based on photo-decomposition of a triazene-based transfer layer that produces N2 gas, which propels a graphene layer from the donor to the acceptor substrate. The functionality of the graphene-metal junction was verified by realizing functional bottom contact bottom gate field-effect transistors.

Comparison of the key mechanisms leading to rollovers in Liquefied Natural Gas using Computational Fluid Dynamics

NASA Astrophysics Data System (ADS)

Hubert, Antoine; Dadonau, Maksim; Dembele, Siaka; Denissenko, Petr; Wen, Jennifer

2017-11-01

Growing demand for the LNG fosters growth of the number of production sites with varying composition and density. Combining different sources of LNG may result in a stably stratified system, in which heat and mass transfer between the layers is limited. Heating of the LNG due to wall thermal conductivity leads to formation of convection cells confined within the layers. While the upper layer can release the extra energy via preferential methane boil-off, the bottom layer cannot and hence becomes superheated. Gradual density equilibration reduces stratification and may eventually lead to a sudden mixing event called ``rollover'', accompanied by violent evaporation of the superheated LNG. Three phenomena are potentially responsible for density equilibration. The first is the growing difference in thermal expansion of the layers due to the reduced ability of the bottom layer to reject heat. The second is the penetration of the heated near-wall boundary layer into the upper layer. The third is the ``entrainment mixing'' occurring at the contact surface between the two layers. The present study uses CFD to compare these mechanisms. Boussinesq approximation and an extended version of the k- ɛ model is used. The code is validated by comparison with a large-scale LNG rollover experiment.

Discrete element simulation of charging and mixed layer formation in the ironmaking blast furnace

NASA Astrophysics Data System (ADS)

Mitra, Tamoghna; Saxén, Henrik

2016-11-01

The burden distribution in the ironmaking blast furnace plays an important role for the operation as it affects the gas flow distribution, heat and mass transfer, and chemical reactions in the shaft. This work studies certain aspects of burden distribution by small-scale experiments and numerical simulation by the discrete element method (DEM). Particular attention is focused on the complex layer-formation process and the problems associated with estimating the burden layer distribution by burden profile measurements. The formation of mixed layers is studied, and a computational method for estimating the extent of the mixed layer, as well as its voidage, is proposed and applied on the results of the DEM simulations. In studying a charging program and its resulting burden distribution, the mixed layers of coke and pellets were found to show lower voidage than the individual burden layers. The dynamic evolution of the mixed layer during the charging process is also analyzed. The results of the study can be used to gain deeper insight into the complex charging process of the blast furnace, which is useful in the design of new charging programs and for mathematical models that do not consider the full behavior of the particles in the burden layers.

Fabrication of complex nanoscale structures on various substrates

NASA Astrophysics Data System (ADS)

Han, Kang-Soo; Hong, Sung-Hoon; Lee, Heon

2007-09-01

Polymer based complex nanoscale structures were fabricated and transferred to various substrates using reverse nanoimprint lithography. To facilitate the fabrication and transference of the large area of the nanostructured layer to the substrates, a water-soluble polyvinyl alcohol mold was used. After generation and transference of the nanostructured layer, the polyvinyl alcohol mold was removed by dissolving in water. A residue-free, UV-curable, glue layer was formulated and used to bond the nanostructured layer onto the substrates. As a result, nanometer scale patterned polymer layers were bonded to various substrates and three-dimensional nanostructures were also fabricated by stacking of the layers.

Comparison of Theoretical and Experimental Heat-Transfer Characteristics of Bodies of Revolution at Supersonic Speeds

NASA Technical Reports Server (NTRS)

Scherrer, Richard

1951-01-01

An investigation of the three important factors that determine convective heat-transfer characteristics at supersonic speeds, location boundary-layer transition, recovery factor, and heat-transfer parameter has been performed at Mach numbers from 1.49 to 1.18. The bodies of revolution that were tested had, in most cases, laminar boundary layers, and the test results have been compared with available theory. Boundary-layer transition was found to be affected by heat transfer. Adding heat to a laminar boundary layer caused transition to move forward on the test body, while removing heat caused transition to move rearward. These experimental results and the implications of boundary-layer-stability theory are in qualitative agreement.

An experimental investigation of heat transfer to reusable surface insulation tile array gaps in a turbulent boundary layer with pressure gradient. M.S. Thesis

NASA Technical Reports Server (NTRS)

Throckmorton, D. A.

1975-01-01

An experimental investigation was performed to determine the effect of pressure gradient on the heat transfer to space shuttle reusable surface insulation (RSI) tile array gaps under thick, turbulent boundary layer conditions. Heat transfer and pressure measurements were obtained on a curved array of full-scale simulated RSI tiles in a tunnel wall boundary layer at a nominal freestream Mach number of 10.3 and freestream unit Reynolds numbers of 1.6, 3.3, and and 6.1 million per meter. Transverse pressure gradients were induced over the model surface by rotating the curved array with respect to the flow. Definition of the tunnel wall boundary layer flow was obtained by measurement of boundary layer pitot pressure profiles, and flat plate wall pressure and heat transfer. Flat plate wall heat transfer data were correlated and a method was derived for prediction of smooth, curved array heat transfer in the highly three-dimensional tunnel wall boundary layer flow and simulation of full-scale space shuttle vehicle pressure gradient levels was assessed.

Contamination-free Ge-based graphene as revealed by graphene enhanced secondary ion mass spectrometry (GESIMS)

NASA Astrophysics Data System (ADS)

Michałowski, P. P.; Pasternak, I.; Strupiński, W.

2018-01-01

In this study, we demonstrate that graphene grown on Ge does not contain any copper contamination, and identify some of the errors affecting the accuracy of commonly used measurement methods. Indeed, one of these, the secondary ion mass spectrometry (SIMS) technique, reveals copper contamination in Ge-based graphene but does not take into account the effect of the presence of the graphene layer. We have shown that this layer increases negative ionization significantly, and thus yields false results, but also that the graphene enhances, by an order of two, the magnitude of the intensity of SIMS signals when compared with a similar graphene-free sample, enabling much better detection limits. This forms the basis of a new measurement procedure, graphene enhanced SIMS (GESIMS) (pending European patent application no. EP 16461554.4), which allows for the precise estimation of the realistic distribution of dopants and contamination in graphene. In addition, we present evidence that the GESIMS effect leads to unexpected mass interferences with double-ionized species, and that these interferences are negligible in samples without graphene. The GESIMS method also shows that graphene transferred from Cu results in increased copper contamination.

Experimental study of CO2 dissolution a convection phenomenon at high pressure

NASA Astrophysics Data System (ADS)

Ben Salem, Imen; Chevalier, Sylvie; Faisal, Titly Farhana; Abderrahmane, Hamid; Sassi, Mohamed

2016-05-01

The density driven convection phenomenon has a significant role in enhancing the CO2 geological storage capacity. Deep saline aquifers are targeted for large scale geological sequestration. Once the CO2 is injected in saline aquifer, the supercritical CO2 rises up, forms a thin layer of free phase CO2, and the dissolution and molecular diffusion of the dissolved CO2 in brine begins. The CO2 saturated brine is denser than the original brine leading to gravitational convection of CO2 saturated brine. Convection accelerates the dissolution process and thus improves the safety and the efficiency of the sequestration. Laboratory experiments have been previously performed with experimental set-ups allowing the visualization of the phenomenon (1) eventually combined to the measurements of the dissolved CO2 mass transfer (2) as a function of the permeability of the medium. The visualization of the process was possible as Hele-Shaw cells at atmospheric pressure were used. Pressurized cylindrical vessel containing porous media allows measuring mass transfer of CO2 using the pressure decay concept (3) but visualization of the convection/dissolution was not possible for these setups. In this work, we performed experiments in a pressurized transparent cell similar to a Hele-Shaw cell but with bigger aperture. Permeability was varied by changing the size of the glass beads filling the cell. Bromocrysol green was used as a dye to track the pH change due to the presence of dissolved CO2 (1). The phenomenon is captured by a high resolution camera. We studied the effect of the pressure and of the permeability on the fingering pattern, the onset and the timescale of the phenomenon and the quantitative mass transfer of dissolved CO2. Experiments were validated on numerical simulations performed using STOMP (Subsurface Transport Over Multiple Phases) developed by the PNNL (Pacific Northwest National Laboratory) Hydrology group of the Department of Energy, USA. (1) Kneafsey, T.J., Pruess, K., 2010. Laboratory flow experiments for visualizing carbon dioxide-induced density-driven brine convection, Transport in Porous Media 82, 123-139. (2) Faisal, T. F., Chevalier, S., Bernabé, Y., Juanes, R. and M. Sassi. 2015. Quantitative and qualitative study of density driven CO2 mass transfer in a vertical Hele-Shaw cell. International Journal of Heat and Mass Transfer. Vol. 81, 901-914. (3) Farajzadeh, R.; Barati, A.; Delil, H. A.; Bruining, J.; Zitha, P. L. J., Mass transfer of CO2 into water and surfactant solutions, Petroleum Science and Technology 25 (12) (2007) 1493-1511.

How changing the particle structure can speed up protein mass transfer kinetics in liquid chromatography.

PubMed

Gritti, Fabrice; Horvath, Krisztian; Guiochon, Georges

2012-11-09

The mass transfer kinetics of a few compounds (uracil, 112 Da), insulin (5.5 kDa), lysozyme (13.4 kDa), and bovine serum albumin (BSA, 67 kDa) in columns packed with several types of spherical particles was investigated under non-retained conditions, in order to eliminate the poorly known contribution of surface diffusion to overall sample diffusivity across the porous particles in RPLC. Diffusivity across particles is then minimum. Based on the porosity of the particles accessible to analytes, it was accurately estimated from the elution times, the internal obstruction factor (using Pismen correlation), and the hindrance diffusion factor (using Renkin correlation). The columns used were packed with fully porous particles 2.5 μm Luna-C(18) 100 Å, core-shell particles 2.6 μm Kinetex-C(18) 100 Å, 3.6 μm Aeris Widepore-C(18) 200 Å, and prototype 2.7 μm core-shell particles (made of two concentric porous shells with 100 and 300 Å average pore size, respectively), and with 3.3 μm non-porous silica particles. The results demonstrate that the porous particle structure and the solid-liquid mass transfer resistance have practically no effect on the column efficiency for small molecules. For them, the column performance depends principally on eddy dispersion (packing homogeneity), to a lesser degree on longitudinal diffusion (effective sample diffusivity along the packed bed), and only slightly on the solid-liquid mass transfer resistance (sample diffusivity across the particle). In contrast, for proteins, this third HETP contribution, hence the porous particle structure, together with eddy dispersion govern the kinetic performance of columns. Mass transfer kinetics of proteins was observed to be fastest for columns packed with core-shell particles having either a large core-to-particle ratio or having a second, external, shell made of a thin porous layer with large mesopores (200-300 Å) and a high porosity (~/=0.5-0.7). The structure of this external shell seems to speed up the penetration of proteins into the particles. A stochastic model of the penetration of bulky proteins driven by a concentration gradient across an infinitely thin membrane of known porosity and pore size is suggested to explain this mechanism. Yet, under retained conditions, surface diffusion speeds up the mass transfer into the mesopores and levels the kinetic performance of particles built with either one or two porous shells. Copyright © 2012 Elsevier B.V. All rights reserved.

A numerical analysis for non-linear radiation in MHD flow around a cylindrical surface with chemically reactive species

NASA Astrophysics Data System (ADS)

Khan, Junaid Ahmad; Mustafa, M.

2018-03-01

Boundary layer flow around a stretchable rough cylinder is modeled by taking into account boundary slip and transverse magnetic field effects. The main concern is to resolve heat/mass transfer problem considering non-linear radiative heat transfer and temperature/concentration jump aspects. Using conventional similarity approach, the equations of motion and heat transfer are converted into a boundary value problem whose solution is computed by shooting method for broad range of slip coefficients. The proposed numerical scheme appears to improve as the strengths of magnetic field and slip coefficients are enhanced. Axial velocity and temperature are considerably influenced by a parameter M which is inversely proportional to the radius of cylinder. A significant change in temperature profile is depicted for growing wall to ambient temperature ratio. Relevant physical quantities such as wall shear stress, local Nusselt number and local Sherwood number are elucidated in detail.

The effect of velocity slip and multiple convective boundary conditions in a Darcian porous media with microorganism past a vertical stretching/shrinking sheet

NASA Astrophysics Data System (ADS)

Latiff, Nur Amalina Abdul; Yahya, Elisa; Ismail, Ahmad Izani Md.; Amirsom, Ardiana; Basir, Faisal

2017-08-01

An analysis is carried out to study the steady mixed convective boundary layer flow of a nanofluid in a Darcian porous media with microorganisms past a vertical stretching/shrinking sheet. Heat generation/absorption and chemical reaction effects are incorporated in the model. The partial differential equations are transformed into a system of ordinary differential equations by using similarity transformations generated by scaling group transformations. The transformed equations with boundary conditions are solved numerically. The effects of controlling parameters such as velocity slip, Darcy number, heat generation/absorption and chemical reaction on the skin friction factor, heat transfer, mass transfer and microorganism transfer are shown and discuss through graphs. Comparison of numerical solutions in the present study with the previous existing results in literature are made and comparison results are in very good agreement.

Turbulent heat transfer as a control of platelet ice growth in supercooled under-ice ocean boundary layers

NASA Astrophysics Data System (ADS)

McPhee, Miles G.; Stevens, Craig L.; Smith, Inga J.; Robinson, Natalie J.

2016-04-01

Late winter measurements of turbulent quantities in tidally modulated flow under land-fast sea ice near the Erebus Glacier Tongue, McMurdo Sound, Antarctica, identified processes that influence growth at the interface of an ice surface in contact with supercooled seawater. The data show that turbulent heat exchange at the ocean-ice boundary is characterized by the product of friction velocity and (negative) water temperature departure from freezing, analogous to similar results for moderate melting rates in seawater above freezing. Platelet ice growth appears to increase the hydraulic roughness (drag) of fast ice compared with undeformed fast ice without platelets. Platelet growth in supercooled water under thick ice appears to be rate-limited by turbulent heat transfer and that this is a significant factor to be considered in mass transfer at the underside of ice shelves and sea ice in the vicinity of ice shelves.

Laser deposition and direct-writing of thermoelectric misfit cobaltite thin films

NASA Astrophysics Data System (ADS)

Chen, Jikun; Palla-Papavlu, Alexandra; Li, Yulong; Chen, Lidong; Shi, Xun; Döbeli, Max; Stender, Dieter; Populoh, Sascha; Xie, Wenjie; Weidenkaff, Anke; Schneider, Christof W.; Wokaun, Alexander; Lippert, Thomas

2014-06-01

A two-step process combining pulsed laser deposition of calcium cobaltite thin films and a subsequent laser induced forward transfer as micro-pixel is demonstrated as a direct writing approach of micro-scale thin film structures for potential applications in thermoelectric micro-devices. To achieve the desired thermo-electric properties of the cobaltite thin film, the laser induced plasma properties have been characterized utilizing plasma mass spectrometry establishing a direct correlation to the corresponding film composition and structure. The introduction of a platinum sacrificial layer when growing the oxide thin film enables a damage-free laser transfer of calcium cobaltite thereby preserving the film composition and crystallinity as well as the shape integrity of the as-transferred pixels. The demonstrated direct writing approach simplifies the fabrication of micro-devices and provides a large degree of flexibility in designing and fabricating fully functional thermoelectric micro-devices.

A general stagnation-point convective heating equation for arbitrary gas mixtures

NASA Technical Reports Server (NTRS)

Sutton, K.; Graves, R. A., Jr.

1971-01-01

The stagnation-point convective heat transfer to an axisymmetric blunt body for arbitrary gases in chemical equilibrium was investigated. The gases considered were base gases of nitrogen, oxygen, hydrogen, helium, neon, argon, carbon dioxide, ammonia, and methane and 22 gas mixtures composed of the base gases. Enthalpies ranged from 2.3 to 116.2 MJ/kg, pressures ranged from 0.001 to 100 atmospheres, and the wall temperatures were 300 and 1111 K. A general equation for the stagnation-point convective heat transfer in base gases and gas mixtures was derived and is a function of the mass fraction, the molecular weight, and a transport parameter of the base gases. The relation compares well with present boundary-layer computer results and with other analytical and experimental results. In addition, the analysis verified that the convective heat transfer in gas mixtures can be determined from a summation relation involving the heat transfer coefficients of the base gases. The basic technique developed for the prediction of stagnation-point convective heating to an axisymmetric blunt body could be applied to other heat transfer problems.

A mathematical analysis of drug dissolution in the USP flow through apparatus

NASA Astrophysics Data System (ADS)

McDonnell, David; D'Arcy, D. M.; Crane, L. J.; Redmond, Brendan

2018-03-01

This paper applies boundary layer theory to the process of drug dissolution in the USP (United States Pharmacopeia) Flow Through Apparatus. The mass transfer rate from the vertical planar surface of a compact within the device is examined. The theoretical results obtained are then compared with those of experiment. The paper also examines the effect on the dissolution process caused by the interaction between natural and forced convection within the apparatus and the introduction of additional boundaries.

Parameter Estimation for a Thin Layer by Measuring Temperature Induced by a Heat Source

DTIC Science & Technology

2013-01-01

Abdelrazaq, The solution of heat conduction equation with mixed boundary conditions, J. Math. Stat. 2 ( 2006 ) 346-350. [2] R. T. Al-Khairy and Z. M. Al-Ofey...Appl. Math. 2009 (2009) Article ID 604695. [3] G. Araya and G. Gutierrez, Analytical solution for a transient, three-dimensional temperature...distribution due to a moving laser beam, Int. J. Heat and Mass Transfer 49 ( 2006 ) 4124-4131. [4] M. Bertolotti and C. Sibilia, Depth and velocity of the

Fabrication of porous matrix membrane (PMM) using metal-organic framework as green template for water treatment.

PubMed

Lee, Jian-Yuan; Tang, Chuyang Y; Huo, Fengwei

2014-01-17

Pressure-driven membranes with high porosity can potentially be fabricated by removing template, such as low water stability metal-organic frameworks (MOFs) or other nanoparticles, in polymeric matrix. We report on the use of benign MOFs as green template to enhance porosity and interconnectivity of the water treatment membranes. Significantly enhanced separation performance was observed which might be attributed to the mass transfer coefficient of the substrate layer increased in ultrafiltration (UF) application.

Physical modelling of LNG rollover in a depressurized container filled with water

NASA Astrophysics Data System (ADS)

Maksim, Dadonau; Denissenko, Petr; Hubert, Antoine; Dembele, Siaka; Wen, Jennifer

2015-11-01

Stable density stratification of multi-component Liquefied Natural Gas causes it to form distinct layers, with upper layer having a higher fraction of the lighter components. Heat flux through the walls and base of the container results in buoyancy-driven convection accompanied by heat and mass transfer between the layers. The equilibration of densities of the top and bottom layers, normally caused by the preferential evaporation of Nitrogen, may induce an imbalance in the system and trigger a rapid mixing process, so-called rollover. Numerical simulation of the rollover is complicated and codes require validation. Physical modelling of the phenomenon has been performed in a water-filled depressurized vessel. Reducing gas pressure in the container to levels comparable to the hydrostatic pressure in the water column allows modelling of tens of meters industrial reservoirs using a 20 cm laboratory setup. Additionally, it allows to model superheating of the base fluid layer at temperatures close the room temperature. Flow visualizations and parametric studies are presented. Results are related to outcomes of numerical modelling.

Sound transmission through finite lightweight multilayered structures with thin air layers.

PubMed

Dijckmans, A; Vermeir, G; Lauriks, W

2010-12-01

The sound transmission loss (STL) of finite lightweight multilayered structures with thin air layers is studied in this paper. Two types of models are used to describe the vibro-acoustic behavior of these structures. Standard transfer matrix method assumes infinite layers and represents the plane wave propagation in the layers. A wave based model describes the direct sound transmission through a rectangular structure placed between two reverberant rooms. Full vibro-acoustic coupling between rooms, plates, and air cavities is taken into account. Comparison with double glazing measurements shows that this effect of vibro-acoustic coupling is important in lightweight double walls. For infinite structures, structural damping has no significant influence on STL below the coincidence frequency. In this frequency region, the non-resonant transmission or so-called mass-law behavior dominates sound transmission. Modal simulations suggest a large influence of structural damping on STL. This is confirmed by experiments with double fiberboard partitions and sandwich structures. The results show that for thin air layers, the damping induced by friction and viscous effects at the air gap surfaces can largely influence and improve the sound transmission characteristics.

Heat transfer within a flat micro heat pipe with extra liquid

NASA Astrophysics Data System (ADS)

Sprinceana, Silviu; Mihai, Ioan

2016-12-01

In the real functioning of flat micro heat pipe (FMHP), there can appear cases when the temperature from the vaporization zone can exceed a critical value caused by a sudden increase of the thermal flow. The heat transfer which is completed conductively through the copper wall of a FMHP vaporizer causes the vaporization of the work fluid. On the condenser, the condensation of the fluid vapors and the transfer of the condenser to the vaporizer can no longer be achieved. The solution proposed for enhancing heat transfer in the event of blockage phenomenon FMHP, it is the injection of a certain amount of working fluid in the vaporization zone. By this process the working fluid injected into the evaporator passes suddenly in the vapor, producing a cooling zone. The new product additional mass of vapor will leave the vaporization zone and will condense in condensation zone, thereby supplementing the amount of condensation. Thus resumes normal operating cycle of FMHP. For the experimental measurements made for the transfer of heat through the FMHP working fluid demineralized water, they were made two micro-capillary tubes of sintered copper layer. The first was filled with 1ml of demineralized water was dropped under vacuum until the internal pressure has reached a level of 1•104Pa. The second FMHP was filled with the same amount of working fluid was used and the same capillary inner layer over which was laid a polysynthetic material that will accrue an additional amount of fluid. In this case, the internal pressure was reduced to 1•104Pa.

Release strategies for making transferable semiconductor structures, devices and device components

DOEpatents

Rogers, John A; Nuzzo, Ralph G; Meitl, Matthew; Ko, Heung Cho; Yoon, Jongseung; Menard, Etienne; Baca, Alfred J

2014-11-25

Provided are methods for making a device or device component by providing a multilayer structure having a plurality of functional layers and a plurality of release layers and releasing the functional layers from the multilayer structure by separating one or more of the release layers to generate a plurality of transferable structures. The transferable structures are printed onto a device substrate or device component supported by a device substrate. The methods and systems provide means for making high-quality and low-cost photovoltaic devices, transferable semiconductor structures, (opto-)electronic devices and device components.

Release strategies for making transferable semiconductor structures, devices and device components

DOEpatents

Rogers, John A [Champaign, IL; Nuzzo, Ralph G [Champaign, IL; Meitl, Matthew [Raleigh, NC; Ko, Heung Cho [Urbana, IL; Yoon, Jongseung [Urbana, IL; Menard, Etienne [Durham, NC; Baca, Alfred J [Urbana, IL

2011-04-26

Provided are methods for making a device or device component by providing a multilayer structure having a plurality of functional layers and a plurality of release layers and releasing the functional layers from the multilayer structure by separating one or more of the release layers to generate a plurality of transferable structures. The transferable structures are printed onto a device substrate or device component supported by a device substrate. The methods and systems provide means for making high-quality and low-cost photovoltaic devices, transferable semiconductor structures, (opto-)electronic devices and device components.

Analysis of turbulent free-convection boundary layer on flat plate

NASA Technical Reports Server (NTRS)

Eckert, E R G; Jackson, Thomas W

1950-01-01

A calculation was made for the flow and heat transfer in the turbulent free-convection boundary layer on a vertical flat plate. Formulas for the heat-transfer coefficient, boundary layer thickness, and the maximum velocity in the boundary layer were obtained.

Simulation of reduction of iron-oxide-carbon composite pellets in a rotary hearth furnace

NASA Astrophysics Data System (ADS)

Halder, Sabuj

The primary motivation of this work is to evaluate a new alternative ironmaking process which involves the combination of a Rotary Hearth Furnace (RHF) with an iron bath smelter. This work is concerned primarily, with the productivity of the RHF. It is known that the reduction in the RHF is controlled by chemical kinetics of the carbon oxidation and wustite reduction reactions as well as by heat transfer to the pellet surface and within the pellet. It is heat transfer to the pellet which limits the number of layers of pellets in the pellet bed in the RHF and thus, the overall productivity. Different types of carbon like graphite, coal-char and wood charcoal were examined. Part of the research was to investigate the chemical kinetics by de-coupling it from the influence of heat and mass transfer. This was accomplished by carrying out reduction experiments using small iron-oxide-carbon powder composite mixtures. The reaction rate constants were determined by fitting the experimental mass loss with a mixed reaction model. This model accounts for the carbon oxidation by CO2 and wustite reduction by CO, which are the primary rate controlling surface-chemical reactions in the composite system. The reaction rate constants have been obtained using wustite-coal-char powder mixtures and wustite-wood-charcoal mixtures. The wustite for these mixtures was obtained from two iron-oxide sources: artificial porous analytical hematite (PAH) and hematite ore tailings. In the next phase of this study, larger scale experiments were conducted in a RHF simulator using spherical composite pellets. Measurement of the reaction rates was accomplished using off-gas analysis. Different combinations of raw materials for the pellets were investigated. These included artificial ferric oxide as well as naturally existing hematite and taconite ores. Graphite, coal-char and wood-charcoal were the reductants. Experiments were conducted using a single layer, a double layer and a triple layer of composite pellets to look into the different aspects associated with multi-layer reduction in the RHF. The reduced pellets were examined for morphology and phase distribution using Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) analysis. Efforts were made to interpret the differences in the observed rates from one kind of pellet to the other on the grounds of chemical kinetics of the carbon oxidation and wustite reduction reactions and the issues of external and internal heat transport to and within the pellets. It was concluded from the experiments that in the ore containing pellets, wood-charcoal appeared to be a faster reductant than coal-char. However, in the PAH containing pellets, the reverse was found to be true. This is because of the internal heat transport limitations imposed by two factors (a) lower thermal conductivity of wood-charcoal in comparison to coal-char and (b) swelling of the PAH-Wood-Charcoal pellets during the initial heat-up stage. For the same type of reductant, hematite containing pellets were observed to reduce faster than taconite containing pellets. This is in accordance with the higher reducibility of hematite because of development of internal porosity due to cracking and fissure formation during the Fe2O3 to Fe 3O4 transformation stage. This is however, absent during the reduction of taconite, which is primarily Fe3O4. The PAH-Wood-Charcoal pellets were found to undergo significant amounts of swelling under low temperature conditions. This behavior of the PAH-Wood-Charcoal pellets of a certain layer impeded the external heat transport to the lower layer and consequently, resulted in a relatively lower reduction rate for a multi-layer bed. The volume change phenomena associated with the reduction of composites were also studied. Volume changes influence the external heat transport, especially to the lower layers of a multi-layer bed. The volume change of the different kinds of composite pellets was studied as a function of reduction temperature and time. Empirical correlations were developed associating the volume shrinkage to the fractional mass loss of the pellets. The estimation of the change in the amount of external heat transport with varying pellet sizes for a particular layer of a multi-layer bed was obtained by conducting heat transport tests using inert low carbon steel spheres. The experimental temperature data for the spheres of different layers was interpreted using a simple mathematical model. It was found through this exercise, that if the spheres of the top layer of the bed shrink by 30%, the external heat transfer to the second layer increases by almost 6 times. This is because of the decrease in the shielded area of the second layer due to the decreasing size of the top layer spheres. If the average degree of reduction targeted in a RHF is reduced from 95% to about 70% by coupling the RHF with a bath smelter, the productivity of the RHF can be enhanced by 1.5 to 2 times. The use of a 2 or 3 layer bed was found to be far superior to that of a single layer for higher productivities under the current experimental conditions. Sometimes, a 2 layer bed is more advantageous than a 3 layer bed, as was found to be the case with hematite-wood-charcoal pellets. The choice of the optimal number of layers depends upon several factors like pellet size, kind of pellet and shrinking characteristics of the pellet.

Core-shell microstructured nanocomposites for synergistic adjustment of environmental temperature and humidity

PubMed Central

Zhang, Haiquan; Yuan, Yanping; Zhang, Nan; Sun, Qingrong; Cao, Xiaoling

2016-01-01

The adjustment of temperature and humidity is of great importance in a variety of fields. Composites that can perform both functions are prepared by mixing phase change materials (PCMs) with hygroscopic materials. However, the contact area between the adsorbent and humid air is inevitably decreased in such structures, which reduces the number of mass transfer channels for water vapor. An approach entailing the increase in the mass ratio of the adsorbent is presented here to improve the adsorption capacity. A core-shell CuSO4/polyethylene glycol (PEG) nanomaterial was developed to satisfy the conflicting requirements of temperature control and dehumidification. The results show that the equilibrium adsorption capacity of the PEG coating layer was enhanced by a factor of 188 compared with that of the pure PEG powder. The coating layer easily concentrates vapor, providing better adsorption properties for the composite. Furthermore, the volume modification of the CuSO4 matrix was reduced by 80% by the PEG coated layer, a factor that increases the stability of the composite. For the phase change process, the crystallization temperature of the coating layer was adjusted between 37.2 and 46.3 °C by interfacial tension. The core-shell CuSO4/PEG composite reported here provides a new general approach for the simultaneous control of temperature and humidity. PMID:27845371

On the nature of the symbiotic binary AX Persei

NASA Technical Reports Server (NTRS)

Mikolajewska, Joanna; Kenyon, Scott J.

1992-01-01

Photometric and spectroscopic observations of the symbiotic binary AX Persei are presented. This system contains a red giant that fills its tidal lobe and transfers material into an accretion disk surrounding a low-mass main-sequence star. The stellar masses - 1 solar mass for the red giant and about 0.4 solar mass for the companion - suggest AX Per is poised to enter a common envelope phase of evolution. The disk luminosity increases from L(disk) about 100 solar luminosity in quiescence to L(disk) about 5700 solar luminosity in outburst for a distance of d = 2.5 kpc. Except for visual maximum, high ionization permitted emission lines - such as He II - imply an EUV luminosity comparable to the disk luminosity. High-energy photons emitted by a hot boundary layer between the disk and central star ionize a surrounding nebula to produce this permitted line emission. High ionization forbidden lines form in an extended, shock-excited region well out of the binary's orbital plane and may be associated with mass loss from the disk.

Drying process optimization for an API solvate using heat transfer model of an agitated filter dryer.

PubMed

Nere, Nandkishor K; Allen, Kimberley C; Marek, James C; Bordawekar, Shailendra V

2012-10-01

Drying an early stage active pharmaceutical ingredient candidate required excessively long cycle times in a pilot plant agitated filter dryer. The key to faster drying is to ensure sufficient heat transfer and minimize mass transfer limitations. Designing the right mixing protocol is of utmost importance to achieve efficient heat transfer. To this order, a composite model was developed for the removal of bound solvent that incorporates models for heat transfer and desolvation kinetics. The proposed heat transfer model differs from previously reported models in two respects: it accounts for the effects of a gas gap between the vessel wall and solids on the overall heat transfer coefficient, and headspace pressure on the mean free path length of the inert gas and thereby on the heat transfer between the vessel wall and the first layer of solids. A computational methodology was developed incorporating the effects of mixing and headspace pressure to simulate the drying profile using a modified model framework within the Dynochem software. A dryer operational protocol was designed based on the desolvation kinetics, thermal stability studies of wet and dry cake, and the understanding gained through model simulations, resulting in a multifold reduction in drying time. Copyright © 2012 Wiley-Liss, Inc.

Heat transfer during condensation of steam from steam-gas mixtures in the passive safety systems of nuclear power plants

NASA Astrophysics Data System (ADS)

Portnova, N. M.; Smirnov, Yu B.

2017-11-01

A theoretical model for calculation of heat transfer during condensation of multicomponent vapor-gas mixtures on vertical surfaces, based on film theory and heat and mass transfer analogy is proposed. Calculations were performed for the conditions implemented in experimental studies of heat transfer during condensation of steam-gas mixtures in the passive safety systems of PWR-type reactors of different designs. Calculated values of heat transfer coefficients for condensation of steam-air, steam-air-helium and steam-air-hydrogen mixtures at pressures of 0.2 to 0.6 MPa and of steam-nitrogen mixture at the pressures of 0.4 to 2.6 MPa were obtained. The composition of mixtures and vapor-to-surface temperature difference were varied within wide limits. Tube length ranged from 0.65 to 9.79m. The condensation of all steam-gas mixtures took place in a laminar-wave flow mode of condensate film and turbulent free convection in the diffusion boundary layer. The heat transfer coefficients obtained by calculation using the proposed model are in good agreement with the considered experimental data for both the binary and ternary mixtures.

Conductive polymer layers to limit transfer of fuel reactants to catalysts of fuel cells to reduce reactant crossover

DOEpatents

Stanis, Ronald J.; Lambert, Timothy N.

2016-12-06

An apparatus of an aspect includes a fuel cell catalyst layer. The fuel cell catalyst layer is operable to catalyze a reaction involving a fuel reactant. A fuel cell gas diffusion layer is coupled with the fuel cell catalyst layer. The fuel cell gas diffusion layer includes a porous electrically conductive material. The porous electrically conductive material is operable to allow the fuel reactant to transfer through the fuel cell gas diffusion layer to reach the fuel cell catalyst layer. The porous electrically conductive material is also operable to conduct electrons associated with the reaction through the fuel cell gas diffusion layer. An electrically conductive polymer material is coupled with the fuel cell gas diffusion layer. The electrically conductive polymer material is operable to limit transfer of the fuel reactant to the fuel cell catalyst layer.

Heat transfer to a full-coverage film-cooled surface with 30 degree slant-hole injection

NASA Technical Reports Server (NTRS)

Crawford, M. E.; Kays, W. M.; Moffat, R. J.

1976-01-01

Heat transfer behavior was studied in a turbulent boundary layer with full coverage film cooling through an array of discrete holes and with injection 30 deg to the wall surface in the downstream direction. Stanton numbers were measured for a staggered hole pattern with pitch-to-diameter ratios of 5 and 10, an injection mass flux ratio range of 0.1 to 1.3, and a range of Reynolds number Re sub x of 150,000 to 5 million. Air was used as the working fluid, and the mainstream velocity varied from 9.8 to 34.2 m/sec (32 to 112 ft/sec). The data were taken for secondary injection temperature equal to the wall temperature and also equal to the mainstream temperature. The data may be used to obtain Stanton number as a continuous function of the injectant temperature by use of linear superposition theory. The heat transfer coefficient is defined on the basis of a mainstream-to-wall temperature difference. This definition permits direct comparison of performance between film cooling and transpiration cooling. A differential prediction method was developed to predict the film cooling data base. The method utilizes a two-dimensional boundary layer program with routines to model the injection process and turbulence augmentation. The program marches in the streamwise direction, and when a row of holes is encountered, it stops and injects fluid into the boundary layer. The turbulence level is modeled by algebraically augmenting the mixing length, with the augmentation keyed to a penetration distance for the injected fluid.

Investigation of Deposits in Channels of Panels of a Heat-Transfer Agent

NASA Astrophysics Data System (ADS)

Koshoridze, S. I.; Levin, Yu. K.; Rabinskiy, L. N.; Babaytsev, A. V.

2017-12-01

An analysis of the behavior of nanosized colloidal particles in a supersaturated solution made it possible to substantiate the possibility of increasing the heat-transfer efficiency in a heat exchanger during magnetic treatment of a heat-transfer agent. A model is proposed to weaken the scale during magnetic treatment of a water stream. A colloidal solution is shown to decrease its stability—the coagulation of colloidal particles begins—because of the deformation of the double electrical layer. As a result of increasing the effective radius of curvature of nanoparticles, the solution becomes strongly supersaturated with respect to forming aggregates, which accelerates the solidification of dissolved salts on them. The influence of the interfacial layer of nanoobjects decreases the energy of formation of critical nuclei (size effect) and their sizes. Since coagulation tends to decrease the concentration of critical nuclei in the solution, their loss should be compensated via the homogeneous generation of new nuclei. As a result, the concentration of suspended particles increases additionally and the antiscale effect is enhanced. The solidification flux of dissolved salts is shown to deposit mainly on suspended nanoparticles due to an increase in their total surface area and to the fact that the coefficient of mass transfer to suspension is higher than that to the wall by four orders of magnitude. The mathematical model constructed on the basis of the detected set of physical processes can be used to perform quantitative estimates of the antiscale effect in real power plants.

Using White Dwarf Companions of Blue Stragglers to Constrain Mass Transfer Physics

NASA Astrophysics Data System (ADS)

Gosnell, Natalie M.; Leiner, Emily; Geller, Aaron M.; Knigge, Christian; Mathieu, Robert D.; Sills, Alison; Leigh, Nathan

2018-06-01

Complete membership studies of old open clusters reveal that 25% of the evolved stars follow pathways in stellar evolution that are impacted by binary evolution. Recent studies show that the majority of blue straggler stars, traditionally defined to be stars brighter and bluer than the corresponding main sequence turnoff, are formed through mass transfer from a giant star onto a main sequence companion, resulting in a white dwarf in a binary system with a blue straggler. We will present constraints on the histories and mass transfer efficiencies for two blue straggler-white dwarf binaries in open cluster NGC 188. The constraints are a result of measuring white dwarf cooling temperatures and surface gravities with HST COS far-ultraviolet spectroscopy. This information sets both the timeline for mass transfer and the stellar masses in the pre-mass transfer binary, allowing us to constrain aspects of the mass transfer physics. One system is formed through Case C mass transfer, leaving a CO-core white dwarf, and provides an interesting test case for mass transfer from an asymptotic giant branch star in an eccentric system. The other system formed through Case B mass transfer, leaving a He-core white dwarf, and challenges our current understanding of the expected regimes for stable mass transfer from red giant branch stars.

The Influence of Oscillatory Fractions on Mass Transfer of Non-Newtonian Fluid in Wavy-Walled Tubes for Pulsatile Flow

NASA Astrophysics Data System (ADS)

Zhu, Donghui; Bian, Yongning

2018-03-01

The shape of pipeline structure, fluid medium and flow state have important influence on the heat transfer and mass effect of fluid. In this paper, we investigated the mass transfer behavior of Non-Newtonian fluid CMC solution with 700ppm concentration in five different-sized axisymmetric wave-walled tubes for pulsatile flow. It is revealed that the effect of mass transfer is enhanced with the increase of oscillatory fractions P based on the PIV measurements. Besides, mass transfer rate was measured by the electrochemical method in the larger oscillatory points rate range. It is observed that mass transfer rate increases with the increase in P and reached the maximum mass transfer rate at the most optimal oscillatory fractions P opt. After reaching the optimal oscillatory fractions P opt, the mass transfer rate decreases with increasing P.

The influence of polarization on box air mass factors for UV/vis nadir satellite observations

NASA Astrophysics Data System (ADS)

Hilboll, Andreas; Richter, Andreas; Rozanov, Vladimir V.; Burrows, John P.

2015-04-01

Tropospheric abundances of pollutant trace gases like, e.g., NO2, are often derived by applying the differential optical absorption spectroscopy (DOAS) method to space-borne measurements of back-scattered and reflected solar radiation. The resulting quantity, the slant column density (SCD), subsequently has to be converted to more easily interpretable vertical column densities by means of the so-called box air mass factor (BAMF). The BAMF describes the ratio of SCD and VCD within one atmospheric layer and is calculated by a radiative transfer model. Current operational and scientific data products of satellite-derived trace gas VCDs do not include the effect of polarization in their radiative transfer models. However, the various scattering processes in the atmosphere do lead to a distinctive polarization pattern of the observed Earthshine spectra. This study investigates the influence of these polarization patterns on box air mass factors for satellite nadir DOAS measurements of NO2 in the UV/vis wavelength region. NO2 BAMFs have been simulated for a multitude of viewing geometries, surface albedos, and surface altitudes, using the radiative transfer model SCIATRAN. The results show a potentially large influence of polarization on the BAMF, which can reach 10% and more close to the surface. A simple correction for this effect seems not to be feasible, as it strongly depends on the specific measurement scenario and can lead to both high and low biases of the resulting NO2 VCD. We therefore conclude that all data products of NO2 VCDs derived from space-borne DOAS measurements should include polarization effects in their radiative transfer model calculations, or at least include the errors introduced by using linear models in their uncertainty estimates.

Effects of natural organic matter on PCB-activated carbon sorption kinetics: implications for sediment capping applications.

PubMed

Fairey, Julian L; Wahman, David G; Lowry, Gregory V

2010-01-01

In situ capping of polychlorinated biphenyl (PCB)-contaminated sediments with a layer of activated carbon has been proposed, but several questions remain regarding the long-term effectiveness of this remediation strategy. Here, we assess the degree to which kinetic limitations, size exclusion effects, and electrostatic repulsions impaired PCB sorption to activated carbon. Sorption of 11 PCB congeners with activated carbon was studied in fixed bed reactors with organic-free water (OFW) and Suwannee River natural organic matter (SR-NOM), made by reconstituting freeze-dried SR-NOM at a concentration of 10 mg L(-1) as carbon. In the OFW test, no PCBs were detected in the column effluent over the 390-d study, indicating that PCB-activated carbon equilibrium sorption capacities may be achieved before breakthrough even at the relatively high hydraulic loading rate (HLR) of 3.1 m h(-1). However, in the SR-NOM fixed-bed test, partial PCB breakthrough occurred over the entire 320-d test (HLRs of 3.1-, 1.5-, and 0.8 m h(-1)). Simulations from a modified pore and surface diffusion model indicated that external (film diffusion) mass transfer was the dominant rate-limiting step but that internal (pore diffusion) mass transfer limitations were also present. The external mass transfer limitation was likely caused by formation of PCB-NOM complexes that reduced PCB sorption through a combination of (i) increased film diffusion resistance; (ii) size exclusion effects; and (iii) electrostatic repulsive forces between the PCBs and the NOM-coated activated carbon. However, the seepage velocities in the SR-NOM fixed bed test were about 1000 times higher than would be expected in a sediment cap. Therefore, additional studies are needed to assess whether the mass transfer limitations described here would be likely to manifest themselves at the lower seepage velocities observed in practice.

Study of the influence of surfactants on the activity coefficients and mass transfer coefficients of methanol in aqueous mixtures by reversed-flow gas chromatography.

PubMed

Kotsalos, Efthimios; Brezovska, Boryana; Sevastos, Dimitrios; Vagena, Artemis; Koliadima, Athanasia; Kapolos, John; Karaiskakis, George

2017-11-17

This work focuses on the influences of surfactants on the activity coefficients, γ, of methanol in binary mixtures with water, as well as on the mass transfer coefficients, k c , for the evaporation of methanol, which is a ubiquitous component in the troposphere, from mixtures of methanol with water at various surfactant's and methanol's concentrations. The technique used is the Reversed-Flow Gas Chromatography (R.F.G.C.), a version of Inverse Gas Chromatography, which allows determining both parameters by performing only one experiment for the k c parameter and two experiments for the γ parameter. The k c and γ values decrease in the presence of the three surfactants used (CTAB, SDS, TRITON X-100) at all methanol's and surfactant's concentrations. The decrease in the methanol's molar fraction, at constant number of surfactant films leads to a decrease in the k c and γ values, while the decrease in the surfactant's concentration, at constant methanol's molar fraction leads to an increase in both the k c and γ parameters. Mass transfer coefficients for the evaporation of methanol at the surfactant films, are also calculated which are approximately between 4 and 5 orders of magnitude larger than the corresponding mass transfer coefficients at the liquid films. Finally, thicknesses of the boundary layer of methanol in the mixtures of methanol with water were determined. The quantities found are compared with those given in the literature or calculated theoretically using various empirical equations. The precision of the R.F.G.C. method for measuring γ and k c parameters is approximately high (94.3-98.0%), showing that R.F.G.C. can be used with success not only for the thermodynamic study of solutions, but also for the interphase transport. Copyright © 2017 Elsevier B.V. All rights reserved.

Heat transfer through turbulent boundary layers - The effects of introduction of and recovery from convex curvature

NASA Technical Reports Server (NTRS)

Simon, T. W.; Moffat, R. J.

1979-01-01

Measurements have been made of the heat transfer through a turbulent boundary layer on a convexly curved isothermal wall and on a flat plate following the curved section. Data were taken for one free-stream velocity and two different ratios of boundary layer thickness to radius of curvature delta/R = 0.051 and delta/R = 0.077. Only small differences were observed in the distribution of heat transfer rates for the two boundary layer thicknesses tested, although differences were noted in the temperature distributions within the boundary layer

The heat source of Ruapehu crater lake; deductions from the energy and mass balances

NASA Astrophysics Data System (ADS)

Hurst, A. W.; Bibby, H. M.; Scott, B. J.; McGuinness, M. J.

1991-05-01

Regular observations of temperature, outflow rates and water chemistry of Crater Lake, Mt. Ruapehu, New Zealand have been made for the last 25 years. These data have been used to derive a model of the dynamics of the lake, and determine the input of energy, mass, and chloride from the volcano to the Crater Lake. The recent, relatively quiescent state of the volcano, when virtually no heat has been input to the lake, has also enabled an assessment to be made of the surface heat loss characteristics, which play an important role in the model of the lake. The modelling suggests that since about 1982 the ratio of the volcanic heat to mass added to the base of the lake is about 6 MJ/kg, which is not compatible with heating of the lake by magmatic steam alone. Thus, only about 50% of the heating has been by magmatic steam. It is suggested that heat could be transferred from a magmatic source to the region below the lake by a heat-pipe mechanism, commonly associated with geothermal systems. The simultaneous upward movement of vapour phase, and downward movement of liquid phase from condensed vapour allows efficient heat transfer without overall mass transfer. The permeability necessary to supply the required heat is of the order of 10 darcy, and is consistent with a rubble filled vent. For at least the last five years, there has been a characteristic pattern in the Crater Lake temperature record, with alternate heating and cooling phases. The heating phase generally lasts for one or two months, while the cooling phase lasts for six months to a year. A possible explanation for this cyclic behaviour is the presence of a layer of liquid sulphur under Crater Lake, acting as a partial barrier between the heat-pipe and the lake. The unusual variations of the viscosity of liquid sulphur with temperature will mean that at temperatures greater than 160°C, the layer of sulphur becomes highly viscous and would block any upwards steam flow and hence stop the heat input to Crater Lake, so producing a cooling phase. This blockage would last until the heating from below raised the temperature of the sulphur beyond the high-viscosity region, so gases could again pass through the sulphur.

Efficient Yttrium(III) Chloride-Treated TiO2 Electron Transfer Layers for Performance-Improved and Hysteresis-Less Perovskite Solar Cells.

PubMed

Li, Minghua; Huan, Yahuan; Yan, Xiaoqin; Kang, Zhuo; Guo, Yan; Li, Yong; Liao, Xinqin; Zhang, Ruxiao; Zhang, Yue

2018-01-10

Hybrid organic-inorganic metal halide perovskite solar cells have attracted widespread attention, owing to their high performance, and have undergone rapid development. In perovskite solar cells, the charge transfer layer plays an important role for separating and transferring photogenerated carriers. In this work, an efficient YCl 3 -treated TiO 2 electron transfer layer (ETL) is used to fabricate perovskite solar cells with enhanced photovoltaic performance and less hysteresis. The YCl 3 -treated TiO 2 layers bring about an upward shift of the conduction band minimum (E CBM ), which results in a better energy level alignment for photogenerated electron transfer and extraction from the perovskite into the TiO 2 layer. After optimization, perovskite solar cells based on the YCl 3 -treated TiO 2 layers achieve a maximum power conversion efficiency of about 19.99 % (19.29 % at forward scan) and a steady-state power output of about 19.6 %. Steady-state and time-resolved photoluminescence measurements and impedance spectroscopy are carried out to investigate the charge transfer and recombination dynamics between the perovskite and the TiO 2 electron transfer layer interface. The improved perovskite/TiO 2 ETL interface with YCl 3 treatment is found to separate and extract photogenerated charge rapidly and suppress recombination effectively, which leads to the improved performance. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Electrochemical performance of BaZr0.1Ce0.7Y0.1Yb0.1O3-δ electrolyte based proton-conducting SOFC solid oxide fuel cell with layered perovskite PrBaCo2O5+δ cathode

NASA Astrophysics Data System (ADS)

Ding, Hanping; Xie, Yuanyuan; Xue, Xingjian

2011-03-01

BaZr0.1Ce0.7Y0.1Yb0.1O3-δ (BZCYYb) exhibits adequate protonic conductivity as well as sufficient chemical and thermal stability over a wide range of SOFC operating conditions, while layered perovskite PrBaCo2O5+δ (PBCO) has advanced electrochemical properties. This research fully takes advantage of these advanced properties and develops a novel protonic ceramic membrane fuel cell (PCMFC) of Ni-BZCYYb|BZCYYb|PBCO. The performance of the button cell was tested under intermediate-temperature range from 600 to 700 °C with humified H2 (∼3% H2O) as fuel and ambient air as oxidant. The results show that the open circuit potential of 0.983 V and the maximal power density of 490 mW cm-2 were achieved at 700 °C. By co-doping barium zirconate-cerate with Y and Yb, the conductivity of electrolyte was significantly improved. The polarization processes of the button cell were characterized using the complicated electrochemical impedance spectroscopy technique. The results indicate that the polarization resistances contributed from both charge migration processes and mass transfer processes increase with decreasing cell voltage loads. However the polarization resistance induced by mass transfer processes is negligible in the studied button cell.

Film transfer enabled by nanosheet seed layers on arbitrary sacrificial substrates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dral, A. P.; Nijland, M.; Koster, G.

An approach for film transfer is demonstrated that makes use of seed layers of nanosheets on arbitrary sacrificial substrates. Epitaxial SrTiO{sub 3}, SrRuO{sub 3}, and BiFeO{sub 3} films were grown on Ca{sub 2}Nb{sub 3}O{sub 10} nanosheet seed layers on phlogopite mica substrates. Cleavage of the mica substrates enabled film transfer to flexible polyethylene terephthalate substrates. Electron backscatter diffraction, X-ray diffraction, and atomic force microscopy confirmed that crystal orientation and film morphology remained intact during transfer. The generic nature of this approach is illustrated by growing films on zinc oxide substrates with a nanosheet seed layer. Film transfer to a flexiblemore » substrate was accomplished via acid etching.« less

Heat Transfer Through Dipolar Coupling: Sympathetic cooling without contact

NASA Astrophysics Data System (ADS)

Oktel, Mehmet; Renklioglu, Basak; Tanatar, Bilal

We consider two parallel layers of dipolar ultracold gases at different temperatures and calculate the heat transfer through dipolar coupling. As the simplest model we consider a system in which both of the layers contain two-dimensional spin-polarized Fermi gases. The effective interactions describing the correlation effects and screening between the dipoles are obtained by the Euler-Lagrange Fermi-hypernetted-chain approximation in a single layer. We use the random-phase approximation (RPA) for the interactions across the layers. We find that heat transfer through dipolar coupling becomes efficient when the layer separation is comparable to dipolar interaction length scale. We characterize the heat transfer by calculating the time constant for temperature equilibration between the layers and find that for the typical experimental parameter regime of dipolar molecules this is on the order of milliseconds. We generalize the initial model to Boson-Boson and Fermion-Boson layers and suggest that contactless sympathetic cooling may be used for ultracold dipolar molecules. Supported by TUBITAK 1002-116F030.

Low-temperature fabrication of dye-sensitized solar cells by transfer of composite porous layers

NASA Astrophysics Data System (ADS)

Dürr, Michael; Schmid, Andreas; Obermaier, Markus; Rosselli, Silvia; Yasuda, Akio; Nelles, Gabriele

2005-08-01

Dye-sensitized solar cells have established themselves as a potential low-cost alternative to conventional solar cells owing to their remarkably high power-conversion efficiency combined with `low-tech' fabrication processes. As a further advantage, the active layers consisting of nanoporous TiO2 are only some tens of micrometres thick and are therefore in principle suited for flexible applications. However, typical flexible plastic substrates cannot withstand the process temperatures of up to 500 ∘C commonly used for sintering the TiO2 nanoparticles together. Even though some promising routes for low-temperature sintering have been proposed, those layers cannot compete as regards electrical properties with layers obtained with the standard high-temperature process. Here we show that by a lift-off technique, presintered porous layers can be transferred to an arbitrary second substrate, and the original electrical properties of the transferred porous layers are maintained. The transfer process is greatly assisted by the application of composite layers comprising nanoparticles and nanorods.

Interfacial heat transfer in multiphase molten pools with gas injection

NASA Astrophysics Data System (ADS)

Bilbao Y Leon, Rosa Marina

1998-12-01

In the very unlikely event of a severe reactor accident involving core meltdown and pressure vessel failure, it is vital to identify the circumstances that would allow the molten core material to cool down and resolidify, bringing core debris to a safe and stable state. In this type of accident, the molten material which escapes from the reactor pressure vessel will accumulate as a molten pool in the reactor cavity below. To achieve coolability of the corium in this configuration it has been proposed to flood the cavity with water from above forming a layered structure where upward heat loss from the molten pool to the water will cause the core material to quench and solidify. The effectiveness of this procedure depends largely on the rate of upward heat loss as well as on the formation and stability of an upper crust. In this situation the molten pool becomes a three phase mixture: the solid and liquid slurry formed by the molten pool cooled to a temperature below the temperature of liquidus, agitated by the gases formed in the concrete ablation process. The present work quantifies the partition of the heat losses upward and downward considering the influence of the solid fraction in the pool and the viscosity effects, and the rate of heat loss through a solid layer. To complete this task a intermediate scale experimental test section has been designed and built at the University of Wisconsin - Madison, in which simulant materials are used to model the process of heat and mass transfer which involves the molten pool, the solid layer atop and the coolant layer above. The design includes volumetric heating, gas injection from the bottom and solids within the pool. New experimental results showing the heat transfer behavior for pools with different viscosities and various solid fractions are presented. The current results indicate a power split which favors heat transfer upward to the coolant simulant above by a 2:1 or 3:1 ratio. In addition, the power split is unaffected by the viscosity of the pool, the solid fractions in the pool and the superficial velocity.

Mass Transfer with Chemical Reaction.

ERIC Educational Resources Information Center

DeCoursey, W. J.

1987-01-01

Describes the organization of a graduate course dealing with mass transfer, particularly as it relates to chemical reactions. Discusses the course outline, including mathematics models of mass transfer, enhancement of mass transfer rates by homogeneous chemical reaction, and gas-liquid systems with chemical reaction. (TW)

Spectral collocation method with a flexible angular discretization scheme for radiative transfer in multi-layer graded index medium

NASA Astrophysics Data System (ADS)

Wei, Linyang; Qi, Hong; Sun, Jianping; Ren, Yatao; Ruan, Liming

2017-05-01

The spectral collocation method (SCM) is employed to solve the radiative transfer in multi-layer semitransparent medium with graded index. A new flexible angular discretization scheme is employed to discretize the solid angle domain freely to overcome the limit of the number of discrete radiative direction when adopting traditional SN discrete ordinate scheme. Three radial basis function interpolation approaches, named as multi-quadric (MQ), inverse multi-quadric (IMQ) and inverse quadratic (IQ) interpolation, are employed to couple the radiative intensity at the interface between two adjacent layers and numerical experiments show that MQ interpolation has the highest accuracy and best stability. Variable radiative transfer problems in double-layer semitransparent media with different thermophysical properties are investigated and the influence of these thermophysical properties on the radiative transfer procedure in double-layer semitransparent media is also analyzed. All the simulated results show that the present SCM with the new angular discretization scheme can predict the radiative transfer in multi-layer semitransparent medium with graded index efficiently and accurately.

Polymer-coated compliant receivers for intact laser-induced forward transfer of thin films: experimental results and modelling

NASA Astrophysics Data System (ADS)

Feinaeugle, Matthias; Horak, Peter; Sones, Collin L.; Lippert, Thomas; Eason, Rob W.

2014-09-01

In this study, we investigate both experimentally and numerically laser-induced forward transfer (LIFT) of thin films to determine the role of a thin polymer layer coating the receiver with the aim of modifying the rate of deceleration and reduction of material stress preventing intact material transfer. A numerical model of the impact phase during LIFT shows that such a layer reduces the modelled stress. The evolution of stress within the transferred deposit and the substrate as a function of the thickness of the polymer layer, the transfer velocity and the elastic properties of the polymer are evaluated. The functionality of the polymer layer is verified experimentally by LIFT printing intact 1- m-thick bismuth telluride films and polymeric light-emitting diode pads onto a layer of 12-m-thick polydimethylsiloxane and 50-nm-thick poly(3,4-ethylenedioxythiophene) blended with poly(styrenesulfonate) (PEDOT:PSS), respectively. Furthermore, it is demonstrated experimentally that the introduction of such a compliant layer improves adhesion between the deposit and its substrate.

Modification of graphene by ion beam

NASA Astrophysics Data System (ADS)

Gawlik, G.; Ciepielewski, P.; Jagielski, J.; Baranowski, J.

2017-09-01

Ion induced defect generation in graphene was analyzed using Raman spectroscopy. A single layer graphene membrane produced by chemical vapor deposition (CVD) on copper foil and then transferred on glass substrate was subjected to helium, carbon, nitrogen, argon and krypton ions bombardment at energies from the range 25 keV to 100 keV. A density of ion induced defects and theirs mean size were estimated by using Raman measurements. Increasing number of defects generated by ion with increase of ion mass and decrease of ion energy was observed. Dependence of ion defect efficiency (defects/ion) on ion mass end energy was proportional to nuclear stopping power simulated by SRIM. No correlation between ion defect efficiency and electronic stopping power was observed.

Synthesis of superhydrophobic alumina membrane: Effects of sol-gel coating, steam impingement and water treatment

NASA Astrophysics Data System (ADS)

Ahmad, N. A.; Leo, C. P.; Ahmad, A. L.

2013-11-01

Ceramic membranes possess natural hydrophilicity thus tending to absorb water droplets. The absorption of water molecules on membrane surface reduces their application in filtration, membrane distillation, osmotic evaporation and membrane gas absorption. Fluoroalkylsilane (FAS) grafting allows the conversion of hydrophilic ceramic membranes into superhydrophobic thin layer, but it usually introduces a great increment of mass transfer resistance. In this study, superhydrophobic alumina membranes were synthesized by dip coating alumina support into sol-gel and grafted with the fluoroalkylsilane (FAS) named (heptadecafluoro-1,1,2,2-tetra hydrodecyl) triethoxysilane. Steam impingement and water treatment acted as additional steps to generate surface roughness on sol-gel and most importantly to reduce mass transfer resistance. Superhydrophobic alumina membrane with high water contact angle (158.4°) and low resistance (139.5 ± 24.9 G m-1) was successfully formed when the alumina membrane was dip coated into sol-gel for 7 s, treated with steam impingement for 1 min and immersed in hot water at 100 °C. However, the mass transfer resistance was greatly induced to 535.6 ± 23.5 G m-1 when the dip coating time was increased to 60 s. Long dip coating time contributes more on the blockage of porous structure rather than creates a thin film on the top of membrane surface. Reducing the pore size and porosity significantly due to increase of coating molecules deposited on the membrane. Steam impingement for 1 min promoted the formation of cones and valleys on the sol-gel, but the macro-roughness was destroyed when the steam impingement duration was extended to more than 3 min. The immersions of membranes into hot water at temperatures higher than 60 °C encouraged the formation of boehmite which enhances the formation of additional roughness and enlarges pore size greatly. Thus, this work showed that the formation of superhydrophobic alumina membrane with low resistance is influenced by three factors; sol-gel dip coating time, steam impingement time and temperature of water treatment. The optimum dip coating time could promote appropriate thickness of the sol-gel layer on the membrane support. The highest surface roughness and porosity could be created when the sol-gel layer was further treated with optimum steam impingement duration and immersed in hot water at 100 °C. The presence of appropriate sol-gel thickness can reduce the penetration of FAS during the grafting and reduce the membrane resistance.

Optimized plasma etch window of block copolymers and neutral brush layers for enhanced direct self-assembly pattern transfer into a hardmask layer

NASA Astrophysics Data System (ADS)

Brakensiek, Nickolas; Xu, Kui; Sweat, Daniel; Hockey, Mary Ann

2018-03-01

Directed self-assembly (DSA) of block copolymers (BCPs) is one of the most promising patterning technologies for future lithography nodes. However, one of the biggest challenges to DSA is the pattern transfer by plasma etching from BCP to hardmask (HM) because the etch selectivity between BCP and neutral brush layer underneath is usually not high enough to enable robust pattern transfer. This paper will explore the plasma etch conditions of both BCPs and neutral brush layers that may improve selectivity and allow a more robust pattern transfer of DSA patterns into the hardmask layer. The plasma etching parameters that are under investigation include the selection of oxidative or reductive etch chemistries, as well as plasma gas pressure, power, and gas mixture fractions. Investigation into the relationship between BCP/neutral brush layer materials with varying chemical compositions and the plasma etching conditions will be highlighted. The culmination of this work will demonstrate important etch parameters that allow BCPs and neutral brush layers to be etched into the underlying hardmask layer with a large process window.

Magnetic Coupling in the Disks around Young Gas Giant Planets

NASA Astrophysics Data System (ADS)

Turner, N. J.; Lee, Man Hoi; Sano, T.

2014-03-01

We examine the conditions under which the disks of gas and dust orbiting young gas giant planets are sufficiently conducting to experience turbulence driven by the magneto-rotational instability. By modeling the ionization and conductivity in the disk around proto-Jupiter, we find that turbulence is possible if the X-rays emitted near the Sun reach the planet's vicinity and either (1) the gas surface densities are in the range of the minimum-mass models constructed by augmenting Jupiter's satellites to solar composition, while dust is depleted from the disk atmosphere, or (2) the surface densities are much less, and in the range of gas-starved models fed with material from the solar nebula, but not so low that ambipolar diffusion decouples the neutral gas from the plasma. The results lend support to both minimum-mass and gas-starved models of the protojovian disk. (1) The dusty minimum-mass models have internal conductivities low enough to prevent angular momentum transfer by magnetic forces, as required for the material to remain in place while the satellites form. (2) The gas-starved models have magnetically active surface layers and a decoupled interior "dead zone." Similar active layers in the solar nebula yield accretion stresses in the range assumed in constructing the circumjovian gas-starved models. Our results also point to aspects of both classes of models that can be further developed. Non-turbulent minimum-mass models will lose dust from their atmospheres by settling, enabling gas to accrete through a thin surface layer. For the gas-starved models it is crucial to learn whether enough stellar X-ray and ultraviolet photons reach the circumjovian disk. Additionally, the stress-to-pressure ratio ought to increase with distance from the planet, likely leading to episodic accretion outbursts.

Lightweight acoustic treatments for aerospace applications

NASA Astrophysics Data System (ADS)

Naify, Christina Jeanne

2011-12-01

Increase in the use of composites for aerospace applications has the benefit of decreased structural weight, but at the cost of decreased acoustic performance. Stiff, lightweight structures (such as composites) are traditionally not ideal for acoustic insulation applications because of high transmission loss at low frequencies. A need has thus arisen for effective sound insulation materials for aerospace and automotive applications with low weight addition. Current approaches, such as the addition of mass law dominated materials (foams) also perform poorly when scaled to small thickness and low density. In this dissertation, methods which reduce sound transmission without adding significant weight are investigated. The methods presented are intended to be integrated into currently used lightweight structures such as honeycomb sandwich panels and to cover a wide range of frequencies. Layering gasses of differing acoustic impedances on a panel substantially reduced the amount of sound energy transmitted through the panel with respect to the panel alone or an equivalent-thickness single species gas layer. The additional transmission loss derives from successive impedance mismatches at the interfaces between gas layers and the resulting inefficient energy transfer. Attachment of additional gas layers increased the transmission loss (TL) by as much as 17 dB at high (>1 kHz) frequencies. The location and ordering of the gasses with respect to the panel were important factors in determining the magnitude of the total TL. Theoretical analysis using a transfer matrix method was used to calculate the frequency dependence of sound transmission for the different configurations tested. The method accurately predicted the relative increases in TL observed with the addition of different gas layer configurations. To address low-frequency sound insulation, membrane-type locally resonant acoustic materials (LRAM) were fabricated, characterized, and analyzed to understand their acoustic response. Acoustic metamaterials with negative dynamic mass density have been shown to demonstrate a significant (5x) increase in TL over mass law predictions for a narrow band (100Hz) at low frequencies (100--1000Hz). The peak TL frequency can be tuned to specific values by varying the membrane and mass properties. TL magnitude as a function of frequency was measured for variations of the mass magnitude and membrane tension using an impedance tube setup. The dynamic properties of membranes constructed from different materials and thicknesses were measured and compared to the results of coupled field acoustic-structural finite element analysis (FEA) modeling to understand the role of tension and element quality factor. To better comprehend the mechanism(s) responsible for the TL peak, a laser vibrometer was used to map the out-of-plane dynamic response of the structure under acoustic loading at discrete frequencies. Negative dynamic mass was experimentally demonstrated at the peak TL frequency. The scale-up of the acoustic metamaterial structure was explored by examining the behavior of multiple elements arranged in arrays. Single membranes were stretched over rigid frame supports and masses were attached to the center of each divided cell. TL behavior was measured for multiple configurations with different magnitudes of mass distributed across each of the cell membranes in the array resulting in a multi-peak TL profile. To better understand scale-up issues, the effect of the frame structure compliance was evaluated, and more compliant frames resulted in a reduction in TL peak frequency bandwidth. In addition, displacement measurements of frames and membranes were performed using a laser vibrometer. The measured TL of the multi-celled structure was compared with TL behavior predicted by FEA to understand the role of non-uniform mass distribution and frame compliance. TL of membrane-type LRAM with added ring masses was analyzed using both finite element analysis and experimental techniques. The addition of a ring mass to the structure either increased the bandwidth of the TL peak, or introduced multiple peaks, depending on the number of rings, the distribution of mass between the center and ring masses, and radii of the rings. FEA was used to predict TL behavior of several ring configurations, and TL for these configurations was measured to validate the model predictions. Finally, FEA was used to predict the mode shapes of the structure under single-frequency excitation to understand the mechanisms responsible for the TL peaks.

43 CFR 3106.4-3 - Mass transfers.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 43 Public Lands: Interior 2 2011-10-01 2011-10-01 false Mass transfers. 3106.4-3 Section 3106.4-3... or Otherwise § 3106.4-3 Mass transfers. (a) A mass transfer may be utilized in lieu of the provisions... large number of Federal leases to the same transferee. (b) Three originally executed copies of the mass...

A Comparison of Active and Passive Methods for Control of Hypersonic Boundary Layers on Airbreathing Configurations

NASA Technical Reports Server (NTRS)

Berry, Scott A.; Nowak, Robert J.

2003-01-01

Active and passive methods for control of hypersonic boundary layers have been experimentally examined in NASA Langley Research Center wind tunnels on a Hyper-X model. Several configurations for forcing transition using passive discrete roughness elements and active mass addition, or blowing, methods were compared in two hypersonic facilities, the 20-Inch Mach 6 Air and the 31-Inch Mach 10 Air tunnels. Heat transfer distributions, obtained via phosphor thermography, shock system details, and surface streamline patterns were measured on a 0.333-scale model of the Hyper-X forebody. The comparisons between the active and passive methods for boundary layer control were conducted at test conditions that nearly match the nominal Mach 7 flight trajectory of an angle-of-attack of 2-deg and length Reynolds number of 5.6 million. For the passive roughness examination, the primary parametric variation was a range of trip heights within the calculated boundary layer thickness for several trip concepts. The prior passive roughness study resulted in a swept ramp configuration being selected for the Mach 7 flight vehicle that was scaled to be roughly 0.6 of the calculated boundary layer thickness. For the active jet blowing study, the blowing manifold pressure was systematically varied for each configuration, while monitoring the mass flow, to determine the jet penetration height with schlieren and transition movement with the phosphor system for comparison to the passive results. All the blowing concepts tested were adequate for providing transition onset near the trip location with manifold stagnation pressures on the order of 40 times the model static pressure or higher.

Scalable alignment and transfer of nanowires in a Spinning Langmuir Film.

PubMed

Zhu, Ren; Lai, Yicong; Nguyen, Vu; Yang, Rusen

2014-10-21

Many nanomaterial-based integrated nanosystems require the assembly of nanowires and nanotubes into ordered arrays. A generic alignment method should be simple and fast for the proof-of-concept study by a researcher, and low-cost and scalable for mass production in industries. Here we have developed a novel Spinning-Langmuir-Film technique to fulfill both requirements. We used surfactant-enhanced shear flow to align inorganic and organic nanowires, which could be easily transferred to other substrates and ready for device fabrication in less than 20 minutes. The aligned nanowire areal density can be controlled in a wide range from 16/mm(-2) to 258/mm(-2), through the compression of the film. The surface surfactant layer significantly influences the quality of alignment and has been investigated in detail.

Chemical reaction fouling model for single-phase heat transfer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Panchal, C.B.; Watkinson, A.P.

1993-08-01

A fouling model was developed on the premise that the chemical reaction for generation of precursor can take place in the bulk fluid, in the thermalboundary layer, or at the fluid/wall interface, depending upon the interactive effects of flu id dynamics, heat and mass transfer, and the controlling chemical reaction. The analysis was used to examine the experimental data for fouling deposition of polyperoxides produced by autoxidation of indene in kerosene. The effects of fluid and wall temperatures for two flow geometries were analyzed. The results showed that the relative effects of physical parameters on the fouling rate would differmore » for the three fouling mechanisms; therefore, it is important to identify the controlling mechanism in applying the closed-flow-loop data to industrial conditions.« less

Turbulent boundary layer heat transfer experiments: Convex curvature effects including introduction and recovery

NASA Technical Reports Server (NTRS)

Simon, T. W.; Moffat, R. J.; Johnston, J. P.; Kays, W. M.

1982-01-01

Measurements were made of the heat transfer rate through turbulent and transitional boundary layers on an isothermal, convexly curved wall and downstream flat plate. The effect of convex curvature on the fully turbulent boundary layer was a reduction of the local Stanton numbers 20% to 50% below those predicted for a flat wall under the same circumstances. The recovery of the heat transfer rates on the downstream flat wall was extremely slow. After 60 cm of recovery length, the Stanton number was still typically 15% to 20% below the flat wall predicted value. Various effects important in the modeling of curved flows were studied separately. These are: the effect of initial boundary layer thickness, the effect of freestream velocity, the effect of freestream acceleration, the effect of unheated starting length, and the effect of the maturity of the boundary layer. An existing curvature prediction model was tested against this broad heat transfer data base to determine where it could appropriately be used for heat transfer predictions.

Fuel Reforming Technologies (BRIEFING SLIDES)

DTIC Science & Technology

2009-09-01

Heat and Mass Transfer , Catalysis...Gallons Of Fuel/Day/1100men Deployment  To Reduce Noise/Thermal Signature And 4 Environmental Emissions Advanced Heat and Mass Transfer 5 Advanced... Heat and Mass & Transfer Technologies Objective Identify And Develop New Technologies To Enhance Heat And Mass Transfer In Deployed Energy

Advanced germanium layer transfer for ultra thin body on insulator structure

NASA Astrophysics Data System (ADS)

Maeda, Tatsuro; Chang, Wen-Hsin; Irisawa, Toshifumi; Ishii, Hiroyuki; Hattori, Hiroyuki; Poborchii, Vladimir; Kurashima, Yuuichi; Takagi, Hideki; Uchida, Noriyuki

2016-12-01

We present the HEtero-Layer Lift-Off (HELLO) technique to obtain ultra thin body (UTB) Ge on insulator (GeOI) substrates. The transferred ultra thin Ge layers are characterized by the Raman spectroscopy measurements down to the thickness of ˜1 nm, observing a strong Raman intensity enhancement for high quality GeOI structure in ultra thin regime due to quantum size effect. This advanced Ge layer transfer technique enabled us to demonstrate UTB-GeOI nMOSFETs with the body thickness of only 4 nm.

Tunable photoelectric response in NiO-based heterostructures by various orientations

NASA Astrophysics Data System (ADS)

Luo, Yidong; Qiao, Lina; Zhang, Qinghua; Xu, Haomin; Shen, Yang; Lin, Yuanhua; Nan, Cewen

2018-02-01

We engineered various orientations of NiO layers for NiO-based heterostructures (NiO/Au/STO) to investigate their effects on the generation of hot electrons and holes. Our calculation and experimental results suggested that bandgap engineering and the orientation of the hole transport layer (NiO) were crucial elements for the optimization of photoelectric responses. The (100)-orientated NiO/Au/STO achieved the highest photo-current density (˜30 μA/cm2) compared with (111) and (110)-orientated NiO films, which was attributed to the (100) films's lowest effective mass of photogenerated holes (˜1.82 m0) and the highest efficiency of separating and transferring electron-holes of the (100)-orientated sample. Our results opened a direction to design a high efficiency photoelectric solar cell.

Microporous layer based on SiC for high temperature proton exchange membrane fuel cells

NASA Astrophysics Data System (ADS)

Lobato, Justo; Zamora, Héctor; Cañizares, Pablo; Plaza, Jorge; Rodrigo, Manuel Andrés

2015-08-01

This work reports the evaluation of Silicon Carbide (SiC) for its application in microporous layers (MPL) of HT-PEMFC electrodes and compares results with those obtained using conventional MPL based on Vulcan XC72. Influence of the support load on the MPL prepared with SiC was evaluated, and the MPL were characterized by XRD, Hg porosimetry and cyclic voltammetries. In addition, a short lifetest was carried out to evaluate performance in accelerated stress conditions. Results demonstrate that SiC is a promising alternative to carbonaceous materials because of its higher electrochemical and thermal stability and the positive effect on mass transfer associated to its different pore size distribution. Ohmic resistance is the most significant challenge to be overcome in further studies.

Formation of atomically smooth epitaxial metal films on a chemically reactive interface: Mg on Si(111)

NASA Astrophysics Data System (ADS)

Özer, Mustafa M.; Weitering, Hanno H.

2013-07-01

Deposition of Mg on Si(111)7 × 7 produces an epitaxial magnesium silicide layer. Under identical annealing conditions, the thickness of this Mg2Si(111) layer increases with deposition amount, reaching a maximum of 4 monolayer (ML) and decreasing to ˜3 ML at higher Mg coverage. Excess Mg coalesces into atomically flat, crystalline Mg(0001) films. This surprising growth mode can be attributed to the accidental commensurability of the Mg(0001), Si(111), and Mg2Si(111) interlayer spacing and the concurrent minimization of in-plane Si mass transfer and domain-wall energies. The commensurability of the interlayer spacing defines a highly unique solid-phase epitaxial growth process capable of producing trilayer structures with atomically abrupt interfaces and atomically smooth surface morphologies.

Exploring the Effects of Atmospheric Forcings on Evaporation: Experimental Integration of the Atmospheric Boundary Layer and Shallow Subsurface

PubMed Central

Smits, Kathleen; Eagen, Victoria; Trautz, Andrew

2015-01-01

Evaporation is directly influenced by the interactions between the atmosphere, land surface and soil subsurface. This work aims to experimentally study evaporation under various surface boundary conditions to improve our current understanding and characterization of this multiphase phenomenon as well as to validate numerical heat and mass transfer theories that couple Navier-Stokes flow in the atmosphere and Darcian flow in the porous media. Experimental data were collected using a unique soil tank apparatus interfaced with a small climate controlled wind tunnel. The experimental apparatus was instrumented with a suite of state of the art sensor technologies for the continuous and autonomous collection of soil moisture, soil thermal properties, soil and air temperature, relative humidity, and wind speed. This experimental apparatus can be used to generate data under well controlled boundary conditions, allowing for better control and gathering of accurate data at scales of interest not feasible in the field. Induced airflow at several distinct wind speeds over the soil surface resulted in unique behavior of heat and mass transfer during the different evaporative stages. PMID:26131928

A new type of high energy asymmetric capacitor with nanoporous carbon electrodes in aqueous electrolyte

NASA Astrophysics Data System (ADS)

Khomenko, V.; Raymundo-Piñero, E.; Béguin, F.

A new type of low cost and high energy asymmetric capacitor based on only activated carbons for both electrodes has been developed in a safe and environment friendly aqueous electrolyte. In such electrolyte, the charges are stored in the electrical double-layer and through fast faradaic charge transfer processes. By taking profit of different redox reactions occurring in the positive and negative ranges of potential, it is possible to optimize the capacitor either by balancing the mass of the electrodes or by using different optimized carbons for the positive and negative electrodes. The best results are obtained in the latter case, by utilizing different pseudo-faradaic properties of carbons in order to increase the capacitance and to shift the potentials of water decomposition and destructive oxidation of activated carbon to more negative and positive values, respectively. After an additional adjustment of potentials by mass-balancing the two electrodes, the electrochemical capacitor can be reversibly charged/discharged at 1.6 V in aqueous medium, with energy densities close to the values obtained with electrical double-layer capacitors working in organic electrolytes, while avoiding their disadvantages.

Quantitative determination of tilmicosin in canine serum by high performance liquid chromatography-tandem mass spectrometry.

PubMed

Herrera, Michael; Ding, Haiqing; McClanahan, Robert; Owens, Jane G; Hunter, Robert P

2007-09-15

A highly sensitive and quantitative LC/MS/MS assay for the determination of tilmicosin in serum has been developed and validated. For sample preparation, 0.2 mL of canine serum was extracted with 3 mL of methyl tert-butyl ether. The organic layer was transferred to a new vessel and dried under nitrogen. The sample was then reconstituted for analysis by high performance liquid chromatography-tandem mass spectrometry. A Phenomenex Luna C8(2) analytical column was used for the chromatographic separation. The eluent was subsequently introduced to the mass spectrometer by electrospray ionization. A single range was validated for 50-5000 ng/mL for support of toxicokinetic studies. The inter-day relative error (inaccuracy) for the LLOQ samples ranged from -5.5% to 0.3%. The inter-day relative standard deviations (imprecision) at the respective LLOQ levels were < or =10.1%.

Tropical storm redistribution of Saharan dust to the upper troposphere and ocean surface

NASA Astrophysics Data System (ADS)

Herbener, Stephen R.; Saleeby, Stephen M.; Heever, Susan C.; Twohy, Cynthia H.

2016-10-01

As a tropical cyclone traverses the Saharan Air Layer (SAL), the storm will spatially redistribute the dust from the SAL. Dust deposited on the surface may affect ocean fertilization, and dust transported to the upper levels of the troposphere may impact radiative forcing. This study explores the relative amounts of dust that are vertically redistributed when a tropical cyclone crosses the SAL. The Regional Atmospheric Modeling System (RAMS) was configured to simulate the passage of Tropical Storm Debby (2006) through the SAL. A dust mass budget approach has been applied, enabled by a novel dust mass tracking capability of the model, to determine the amounts of dust deposited on the ocean surface and transferred aloft. The mass of dust removed to the ocean surface was predicted to be nearly 2 orders of magnitude greater than the amount of dust transported to the upper troposphere.

Investigation the evaporation-condensation problem by means of the joint numerical solution of the Boltzmann kinetic equation and interface modelling

NASA Astrophysics Data System (ADS)

Shiskova, I. N.; Kryukov, A. P.; Levashov, V. Yu

2017-11-01

The paper is devoted to research of the heat and mass transfer processes in liquid and vapor phase on the basis of the uniform approach assuming the through description of liquid, interface and vapor. Multiparticles interactions in liquid will be taken into account. The problem is studied when temperature in the depth of liquid differs from temperature in the vapor region. In this case there are both mass flux and heat flux. The study of influence of the correlations resulting from interactions of molecules set in thin near-surface liquid layers and an interface on intensity of evaporation is made. As a result of calculations the equilibrium line of the liquid-vapor saturation is obtained, which corresponds good enough with experimental data. Distributions of density, temperature, pressure, heat and mass fluxes, both in a liquid and in vapor are also presented.

Development of a compact freeze vacuum drying for jelly fish (Schypomedusae)

NASA Astrophysics Data System (ADS)

Alhamid, M. Idrus; Yulianto, M.; Nasruddin

2012-06-01

A new design of a freeze vacuum drying with internal cooling and heater from condenser's heat loss was built and tested. The dryer was used to dry jelly fish (schypomedusae), to study the effect of drying parameters such as the temperature within the drying chamber on mass losses (evaporation) during the freezing stage and the moisture ratio at the end of the drying process. The midili thin layer mathematical drying model was used to estimate and predict the moisture ratio curve based on different drying chamber temperatures. This experiment shows that decreasing the drying chamber temperature with constant pressure results in less mass loss during the freezing stage Drying time was reduced with an increase in drying temperature. Decreasing the drying chamber temperature results in lower pressure saturation of the material has no effect of drying chamber pressure on mass transfer.

Application of Hoffman modulation contrast microscopy coupled with three-wavelength two-beam interferometry to the in situ direct observation of the growth process of a crystal in microgravity

NASA Technical Reports Server (NTRS)

Tsukamoto, Katsuo

1988-01-01

Direct visualization of three dimensional transfer process of both heat and mass around a growing crystal and mono-molecular growth layers on the surface is possible in situ by means of high resolution Hoffman modulation contrast microscopy coupled with three wavelength two beam Mach-Zehnder interferometry. This in situ observation is very suitable for the verification of the growth mechanism of a crystal in a solution or a melt in microgravity.

Prediction of mass transfer coefficient in rotating bed contactor (Higee) using artificial neural network

NASA Astrophysics Data System (ADS)

Saha, Dipendu

2009-02-01

The feasibility of drastically reducing the contactor size in mass transfer processes utilizing centrifugal field has generated a lot of interest in rotating packed bed (Higee). Various investigators have proposed correlations to predict mass transfer coefficients in Higee, but, none of the correlations was more than 20-30% accurate. In this work, artificial neural network (ANN) is employed for predicting mass transfer coefficient data. Results show that ANN provides better estimation of mass transfer coefficient with accuracy 5-15%.

Insulation Testing Using Cryostat Apparatus with Sleeve

NASA Technical Reports Server (NTRS)

Fesmire, J. E.; Augustynowicz, S. D.

1999-01-01

The method and equipment of testing continuously rolled insulation materials is presented in this paper. Testing of blanket and molded products is also facilitated. Materials are installed around a cylindrical copper sleeve using a wrapping machine. The sleeve is slid onto the vertical cold mass of the cryostat. The gap between the cold mass and the sleeve measures less than 1 mm. The cryostat apparatus is a liquid nitrogen boiloff calorimeter system that enables direct measurement of the apparent thermal conductivity (k-value) of the insulation system at any vacuum level between 5 x 10(exp -5) and 760 torr. Sensors are placed between layers of the insulation to provide complete temperature-thickness profiles. The temperatures of the cold mass (maintained at 77.8 kelvin (K)), the sleeve (cold boundary temperature (CBT)), the insulation outer surface (warm boundary temperature (WBT)), and the vacuum can (maintained at 313 K by a thermal shroud) are measured. Plots of CBT, WBT, and layer temperature profiles as functions of vacuum level show the transitions between the three dominant heat transfer modes. For this cryostat apparatus, the measureable heat gain is from 0.2 to 20 watts. The steady-state measurement of k-value is made when all temperatures and the boiloff rate are stable.

MHD Free Convective Boundary Layer Flow of a Nanofluid past a Flat Vertical Plate with Newtonian Heating Boundary Condition

PubMed Central

Uddin, Mohammed J.; Khan, Waqar A.; Ismail, Ahmed I.

2012-01-01

Steady two dimensional MHD laminar free convective boundary layer flows of an electrically conducting Newtonian nanofluid over a solid stationary vertical plate in a quiescent fluid taking into account the Newtonian heating boundary condition is investigated numerically. A magnetic field can be used to control the motion of an electrically conducting fluid in micro/nano scale systems used for transportation of fluid. The transport equations along with the boundary conditions are first converted into dimensionless form and then using linear group of transformations, the similarity governing equations are developed. The transformed equations are solved numerically using the Runge-Kutta-Fehlberg fourth-fifth order method with shooting technique. The effects of different controlling parameters, namely, Lewis number, Prandtl number, buoyancy ratio, thermophoresis, Brownian motion, magnetic field and Newtonian heating on the flow and heat transfer are investigated. The numerical results for the dimensionless axial velocity, temperature and nanoparticle volume fraction as well as the reduced Nusselt and Sherwood number have been presented graphically and discussed. It is found that the rate of heat and mass transfer increase as Newtonian heating parameter increases. The dimensionless velocity and temperature distributions increase with the increase of Newtonian heating parameter. The results of the reduced heat transfer rate is compared for convective heating boundary condition and found an excellent agreement. PMID:23166688

Effective characterization of polymer residues on two-dimensional materials by Raman spectroscopy

NASA Astrophysics Data System (ADS)

Park, Ji-Hoon; Choi, Soo Ho; Chae, Won Uk; Stephen, Boandoh; Park, Hyeon Ki; Yang, Woochul; Kim, Soo Min; Lee, Joo Song; Kim, Ki Kang

2015-12-01

Large-area two-dimensional (2D) materials grown by chemical vapor deposition need to be transferred onto a target substrate for real applications. Poly(methyl methacrylate) as a supporting layer is widely used during the transfer process and removed after finishing it. However, it is a challenge to diminish the polymer layer completely. It is necessary to readily characterize the polymer residues on 2D materials to facilitate the removal process. Here, we report a method that characterizes the polymer residues on 2D materials by tracking the presence of G-band of amorphous carbons (a-Cs) in the Raman spectrum after forming carbonized a-Cs through thermal annealing. The 13C-graphene is employed to separate the Raman signal G-band between 12C-a-Cs and 13C-graphene in the Raman spectrum. The residence of the polymer residues is clearly confirmed by the different Raman signals of two different isotopes (12C and 13C) due to differences in mass. Our effective method recognizes that while the polymer residue is not easily removed on graphene, those on hexagonal boron nitride and molybdenum disulfide are almost diminished under optimum thermal annealing conditions. Our method will not only contribute to the development of a new transfer process, but also help to achieve a clean surface of 2D materials.

Devices with extended area structures for mass transfer processing of fluids

DOEpatents

TeGrotenhuis, Ward E.; Wegeng, Robert S.; Whyatt, Greg A.; King, David L.; Brooks, Kriston P.; Stenkamp, Victoria S.

2009-04-21

A microchannel device includes several mass transfer microchannels to receive a fluid media for processing at least one heat transfer microchannel in fluid communication with a heat transfer fluid defined by a thermally conductive wall, and at several thermally conductive fins each connected to the wall and extending therefrom to separate the mass transfer microchannels from one another. In one form, the device may optionally include another heat transfer microchannel and corresponding wall that is positioned opposite the first wall and has the fins and the mass transfer microchannels extending therebetween.

Dimensionless numbers and correlating equations for the analysis of the membrane-gas diffusion electrode assembly in polymer electrolyte fuel cells

NASA Astrophysics Data System (ADS)

Gyenge, E. L.

The Quraishi-Fahidy method [Can. J. Chem. Eng. 59 (1981) 563] was employed to derive characteristic dimensionless numbers for the membrane-electrolyte, cathode catalyst layer and gas diffuser, respectively, based on the model presented by Bernardi and Verbrugge for polymer electrolyte fuel cells [AIChE J. 37 (1991) 1151]. Monomial correlations among dimensionless numbers were developed and tested against experimental and mathematical modeling results. Dimensionless numbers comparing the bulk and surface-convective ionic conductivities, the electric and viscous forces and the current density and the fixed surface charges, were employed to describe the membrane ohmic drop and its non-linear dependence on current density due to membrane dehydration. The analysis of the catalyst layer yielded electrode kinetic equivalents of the second Damköhler number and Thiele modulus, influencing the penetration depth of the oxygen reduction front based on the pseudohomogeneous film model. The correlating equations for the catalyst layer could describe in a general analytical form, all the possible electrode polarization scenarios such as electrode kinetic control coupled or not with ionic and/or oxygen mass transport limitation. For the gas diffusion-backing layer correlations are presented in terms of the Nusselt number for mass transfer in electrochemical systems. The dimensionless number-based correlating equations for the membrane electrode assembly (MEA) could provide a practical approach to quantify single-cell polarization results obtained under a variety of experimental conditions and to implement them in models of the fuel cell stack.

Control of iron nitride layers growth kinetics in the binary Fe-N system

NASA Astrophysics Data System (ADS)

Torchane, L.; Bilger, P.; Dulcy, J.; Gantois, M.

1996-07-01

This study is within the framework of a research program dedicated to defining the optimal conditions for the nitriding of iron and steels at atmospheric pressure by using various mixtures, NH3-N2-H2 and NH3-Ar. After studying the mechanisms of phase formation and mass transfer at the gas-solid interface, a mathematical model is developed in order to predict the nitrogen transfer rate in the solid, the nitride layer growth rate, and the nitrogen concentration profiles. In order to validate the model and to show its possibilities, it is compared with thermogravimetric experiments, analyses, and metallurgical observations (X-ray diffraction, optical microscopy, and electron microprobe anal-ysis). The results obtained allow us to demonstrate the sound correlation between the experimental results and the theoretical predictions. By applying the model to the iron-nitrogen binary system, when the ɛ/γ/α configuration referred to the Fe-N phase diagram is formed, we have experimentally determined the effective diffusion coefficient of nitrogen in the ɛ phase. The latter is constant for a composition of the ɛ nitride between 8 and 9.5 wt pct nitrogen. All the results obtained show that it is possible, by means of dynamic gas flow regulation, to eliminate the incubation period and to control the thickness, composition, and structure of the compound layer at the beginning of the treatment.

Construction of surface HA/TiO2 coating on porous titanium scaffolds and its preliminary biological evaluation.

PubMed

Chen, Hongjie; Wang, Chunli; Yang, Xiao; Xiao, Zhanwen; Zhu, Xiangdong; Zhang, Kai; Fan, Yujiang; Zhang, Xingdong

2017-01-01

A simple approach to fabricating hydroxyxapatite/titanium dioxide (HA/TiO 2 ) coating on porous titanium (Ti) scaffolds was developed in the present study. Surface TiO 2 layer was firstly formed on porous Ti scaffolds with multi-scale pores by acid-alkali (AA) treatment. The outer HA layer was then formed on the TiO 2 layer by subsequent pulse electrochemical deposition (ED) technique. All the three main process parameters, i.e. deposition times, current density and mass transfer mode affected the properties of the HA coating notably. Under the conditions of 90 deposition cycles, -10mA/cm 2 of pulse current density and stirring, a thin layer of homogeneous and nanorod-like HA sediments was formed on the substrate surface of porous Ti scaffolds. The results of protein adsorption and cellular experiments showed that compared to the single TiO 2 surface, the HA/TiO 2 surface allowed more adsorption of serum proteins and further enhanced the alkaline phosphatase (ALP) activity of MC3T3-E1 osteoblasts. Copyright © 2016 Elsevier B.V. All rights reserved.

Pressure gradient effects on heat transfer to reusable surface insulation tile-array gaps

NASA Technical Reports Server (NTRS)

Throckmorton, D. A.

1975-01-01

An experimental investigation was performed to determine the effect of pressure gradient on the heat transfer within space shuttle reusable surface insulation (RSI) tile-array gaps under thick, turbulent boundary-layer conditions. Heat-transfer and pressure measurements were obtained on a curved array of full-scale simulated RSI tiles in a tunnel-wall boundary layer at a nominal free-stream Mach number and free-stream Reynolds numbers. Transverse pressure gradients of varying degree were induced over the model surface by rotating the curved array with respect to the flow. Definition of the tunnel-wall boundary-layer flow was obtained by measurement of boundary-layer pitot pressure profiles, wall pressure, and heat transfer. Flat-plate heat-transfer data were correlated and a method was derived for prediction of heat transfer to a smooth curved surface in the highly three-dimensional tunnel-wall boundary-layer flow. Pressure on the floor of the RSI tile-array gap followed the trends of the external surface pressure. Heat transfer to the surface immediately downstream of a transverse gap is higher than that for a smooth surface at the same location. Heating to the wall of a transverse gap, and immediately downstream of it, at its intersection with a longitudinal gap is significantly greater than that for the simple transverse gap.

Transfer of micro and nano-photonic silicon nanomembrane waveguide devices on flexible substrates.

PubMed

Ghaffari, Afshin; Hosseini, Amir; Xu, Xiaochuan; Kwong, David; Subbaraman, Harish; Chen, Ray T

2010-09-13

This paper demonstrates transfer of optical devices without extra un-patterned silicon onto low-cost, flexible plastic substrates using single-crystal silicon nanomembranes. Employing this transfer technique, stacking two layers of silicon nanomembranes with photonic crystal waveguide in the first layer and multi mode interference couplers in the second layer is shown, respectively. This technique is promising to realize high density integration of multilayer hybrid structures on flexible substrates.

Long-term mass transfer and mixing-controlled reactions of a DNAPL plume from persistent residuals

NASA Astrophysics Data System (ADS)

Liu, Yuan; Illangasekare, Tissa H.; Kitanidis, Peter K.

2014-02-01

Understanding and being able to predict the long-term behavior of DNAPL (i.e., PCE and TCE) residuals after active remediation has ceased have become increasingly important as attention at many sites turns from aggressive remediation to monitored natural attenuation and long-term stewardship. However, plume behavior due to mass loading and reactions during these later phases is less studied as they involve large spatial and temporal scales. We apply both theoretical analysis and pore-scale simulations to investigate mass transfer from DNAPL residuals and subsequent reactions within the generated plume, and, in particular, to show the differences between early- and late-time behaviors of the plume. In the zone of entry of the DNAPL entrapment zone where the concentration boundary layer in the flowing groundwater has not fully developed, the pore-scale simulations confirm the past findings based on laboratory studies that the mass transfer increases as a power-law function of the Peclét number, and is enhanced due to reactions in the plume. Away from the entry zone and further down gradient, the long-term reactions are limited by the available additive and mixing in the porous medium, thereby behave considerably differently from the entry zone. For the reaction between the contaminant and an additive with intrinsic second-order bimolecular kinetics, the late-time reaction demonstrates a first-order decay macroscopically with respect to the mass of the limiting additive, not with respect to that of the contaminant. The late-time decay rate only depends on the intrinsic reaction rate and the solubility of the entrapped DNAPL. At the intermediate time, the additive decays exponentially with the square of time (t2), instead of time (t). Moreover, the intermediate decay rate also depends on the initial conditions, the spatial distribution of DNAPL residuals, and the effective dispersion coefficient.

Organic doping of rotated double layer graphene

DOE Office of Scientific and Technical Information (OSTI.GOV)

George, Lijin; Jaiswal, Manu, E-mail: manu.jaiswal@iitm.ac.in

2016-05-06

Charge transfer techniques have been extensively used as knobs to tune electronic properties of two- dimensional systems, such as, for the modulation of conductivity \\ mobility of single layer graphene and for opening the bandgap in bilayer graphene. The charge injected into the graphene layer shifts the Fermi level away from the minimum density of states point (Dirac point). In this work, we study charge transfer in rotated double-layer graphene achieved by the use of organic dopant, Tetracyanoquinodimethane. Naturally occurring bilayer graphene has a well-defined A-B stacking whereas in rotated double-layer the two graphene layers are randomly stacked with differentmore » rotational angles. This rotation is expected to significantly alter the interlayer interaction. Double-layer samples are prepared using layer-by-layer assembly of chemical vapor deposited single-layer graphene and they are identified by characteristic resonance in the Raman spectrum. The charge transfer and distribution of charges between the two graphene layers is studied using Raman spectroscopy and the results are compared with that for single-layer and A-B stacked bilayer graphene doped under identical conditions.« less

Heat and mass transfer at gas-phase ignition of grinded coal layer by several metal particles heated to a high temperature

NASA Astrophysics Data System (ADS)

Glushkov, D. O.; Kuznetsov, G. V.; Strizhak, P. A.

2017-07-01

Characteristics of gas-phase ignition of grinded brown coal (brand 2B, Shive-Ovoos deposit in Mongolia) layer by single and several metal particles heated to a high temperature (above 1000 K) have been investigated numerically. The developed mathematical model of the process takes into account the heating and thermal decomposition of coal at the expense of the heat supplied from local heat sources, release of volatiles, formation and heating of gas mixture and its ignition. The conditions of the joint effect of several hot particles on the main characteristic of the process-ignition delay time are determined. The relation of the ignition zone position in the vicinity of local heat sources and the intensity of combustible gas mixture warming has been elucidated. It has been found that when the distance between neighboring particles exceeds 1.5 hot particle size, an analysis of characteristics and regularities of coal ignition by several local heat sources can be carried out within the framework of the model of "single metal particle / grinded coal / air". Besides, it has been shown with the use of this model that the increase in the hot particle height leads, along with the ignition delay time reduction, to a reduction of the source initial temperatures required for solid fuel ignition. At an imperfect thermal contact at the interface hot particle / grinded coal due to the natural porosity of the solid fuel structure, the intensity of ignition reduces due to a less significant effect of radiation in the area of pores on the heat transfer conditions compared to heat transfer by conduction in the near-surface coal layer without regard to its heterogeneous structure.

Receptivity of the compressible mixing layer

NASA Astrophysics Data System (ADS)

Barone, Matthew F.; Lele, Sanjiva K.

2005-09-01

Receptivity of compressible mixing layers to general source distributions is examined by a combined theoretical/computational approach. The properties of solutions to the adjoint Navier Stokes equations are exploited to derive expressions for receptivity in terms of the local value of the adjoint solution. The result is a description of receptivity for arbitrary small-amplitude mass, momentum, and heat sources in the vicinity of a mixing-layer flow, including the edge-scattering effects due to the presence of a splitter plate of finite width. The adjoint solutions are examined in detail for a Mach 1.2 mixing-layer flow. The near field of the adjoint solution reveals regions of relatively high receptivity to direct forcing within the mixing layer, with receptivity to nearby acoustic sources depending on the source type and position. Receptivity ‘nodes’ are present at certain locations near the splitter plate edge where the flow is not sensitive to forcing. The presence of the nodes is explained by interpretation of the adjoint solution as the superposition of incident and scattered fields. The adjoint solution within the boundary layer upstream of the splitter-plate trailing edge reveals a mechanism for transfer of energy from boundary-layer stability modes to Kelvin Helmholtz modes. Extension of the adjoint solution to the far field using a Kirchhoff surface gives the receptivity of the mixing layer to incident sound from distant sources.

Charge transfer at organic-inorganic interfaces—Indoline layers on semiconductor substrates

NASA Astrophysics Data System (ADS)

Meyenburg, I.; Falgenhauer, J.; Rosemann, N. W.; Chatterjee, S.; Schlettwein, D.; Heimbrodt, W.

2016-12-01

We studied the electron transfer from excitons in adsorbed indoline dye layers across the organic-inorganic interface. The hybrids consist of indoline derivatives on the one hand and different inorganic substrates (TiO2, ZnO, SiO2(0001), fused silica) on the other. We reveal the electron transfer times from excitons in dye layers to the organic-inorganic interface by analyzing the photoluminescence transients of the dye layers after femtosecond excitation and applying kinetic model calculations. A correlation between the transfer times and four parameters have been found: (i) the number of anchoring groups, (ii) the distance between the dye and the organic-inorganic interface, which was varied by the alkyl-chain lengths between the carboxylate anchoring group and the dye, (iii) the thickness of the adsorbed dye layer, and (iv) the level alignment between the excited dye ( π* -level) and the conduction band minimum of the inorganic semiconductor.

Dynamics and mitigation of six pesticides in a "Wet" forest buffer zone.

PubMed

Passeport, Elodie; Richard, Benjamin; Chaumont, Cédric; Margoum, Christelle; Liger, Lucie; Gril, Jean-Joël; Tournebize, Julien

2014-04-01

Pesticide pollution is one of the main current threats on water quality. This paper presents the potential and functioning principles of a "Wet" forest buffer zone for reducing concentrations and loads of glyphosate, isoproturon, metazachlor, azoxystrobin, epoxiconazole, and cyproconazole. A tracer injection experiment was conducted in the field in a forest buffer zone at Bray (France). A fine time-scale sampling enabled to illustrate that interactions between pesticides and forest buffer substrates (soil and organic-rich litter layer), had a retarding effect on molecule transfer. Low concentrations were observed for all pesticides at the forest buffer outlet thus demonstrating the efficiency of "Wet" forest buffer zone for pesticide dissipation. Pesticide masses injected in the forest buffer inlet directly determined concentration peaks observed at the outlet. Rapid and partially reversible adsorption was likely the major process affecting pesticide transfer for short retention times (a few hours to a few days). Remobilization of metazachlor, isoproturon, desmethylisoproturon, and AMPA was observed when non-contaminated water flows passed through the forest buffer. Our data suggest that pesticide sorption properties alone could not explain the complex reaction mechanisms that affected pesticide transfer in the forest buffer. Nevertheless, the thick layer of organic matter litter on the top of the forest soil was a key parameter, which enhanced partially reversible sorption of pesticide, thus retarded their transfer, decreased concentration peaks, and likely increased degradation of the pesticides. Consequently, to limit pesticide pollution transported by surface water, the use of already existing forest areas as buffer zones should be equally considered as the most commonly implemented grass buffer strips.

Intensification of heat transfer across falling liquid films

NASA Astrophysics Data System (ADS)

Ruyer-Quil, Christian; Cellier, Nicolas; Stutz, Benoit; Caney, Nadia; Bandelier, Philippe; Locie Team; Legi Team

2017-11-01

The wavy motion of a liquid film is well known to intensify heat or mass transfers. Yet, if film thinning and wave merging are generally invoked, the physical mechanisms which enable this intensification are still unclear. We propose a systematic investigation of the impact of wavy motions on the heat transfer across 2D falling films on hot plates as a function of the inlet frequency and flow parameters. Computations over extended domains and for sufficient durations to achieve statistically established flows have been made possible by low-dimensional modeling and the development of a fast temporal solver based on graph optimizations. Heat transfer has been modeled using the weighted residual technique as a set of two evolution equations for the free-surface temperature and the wall heat flux. This new model solves the shortcomings of previous attempts, namely their inability to capture the onset of thermal boundary layers in large-amplitude waves and their limitation to low Prandtl numbers. Our study reveals that heat transfer is enhanced at the crests of the waves and that heat transfer intensification is maximum at the maximum of density of wave crests, which does not correspond to the natural wavy regime (no inlet forcing). Supports from Institut Universitaire de France and Région Auvergne-Rhones-Alpes are warmly acknowledged.

Migration, Knowledge Transfer, and the Emergence of Australian Post-War Skiing: The Story of Charles William Anton

PubMed Central

Strobl, Philipp

2016-01-01

Abstract Skiing underwent substantial changes during the post-war years when the sport turned into a multi-billion dollar industry and a leisure activity for the masses. Despite its global nature and popularity, skiing in academic writing has not gained much recognition. This paper explores the role of knowledge transfer during the pioneering phase of post-war skiing in Australia. It describes the life of Charles William Anton, an Austrian refugee from the Anschluss who migrated to Sydney and subsequently became one of the founding fathers of Australian post-war skiing. The following pages show the multi-layered nature of skiing as a global sport by exemplifying how ideas spread from pre-war Europe to post-war Australia. The paper will also provide a case study about refugee knowledge transfer and the ‘productive process of absorption, adoption or rejection of knowledge’ that takes place once an idea has been introduced into a new environment. PMID:29170603

Migration, Knowledge Transfer, and the Emergence of Australian Post-War Skiing: The Story of Charles William Anton.

PubMed

Strobl, Philipp

2016-11-01

Skiing underwent substantial changes during the post-war years when the sport turned into a multi-billion dollar industry and a leisure activity for the masses. Despite its global nature and popularity, skiing in academic writing has not gained much recognition. This paper explores the role of knowledge transfer during the pioneering phase of post-war skiing in Australia. It describes the life of Charles William Anton, an Austrian refugee from the Anschluss who migrated to Sydney and subsequently became one of the founding fathers of Australian post-war skiing. The following pages show the multi-layered nature of skiing as a global sport by exemplifying how ideas spread from pre-war Europe to post-war Australia. The paper will also provide a case study about refugee knowledge transfer and the 'productive process of absorption, adoption or rejection of knowledge' that takes place once an idea has been introduced into a new environment.

Notes on Earth Atmospheric Entry for Mars Sample Return Missions

NASA Technical Reports Server (NTRS)

Rivell, Thomas

2006-01-01

The entry of sample return vehicles (SRVs) into the Earth's atmosphere is the subject of this document. The Earth entry environment for vehicles, or capsules, returning from the planet Mars is discussed along with the subjects of dynamics, aerodynamics, and heat transfer. The material presented is intended for engineers and scientists who do not have strong backgrounds in aerodynamics, aerothermodynamics and flight mechanics. The document is not intended to be comprehensive and some important topics are omitted. The topics considered in this document include basic principles of physics (fluid mechanics, dynamics and heat transfer), chemistry and engineering mechanics. These subjects include: a) fluid mechanics (aerodynamics, aerothermodynamics, compressible fluids, shock waves, boundary layers, and flow regimes from subsonic to hypervelocity; b) the Earth s atmosphere and gravity; c) thermal protection system design considerations; d) heat and mass transfer (convection, radiation, and ablation); e) flight mechanics (basic rigid body dynamics and stability); and f) flight- and ground-test requirements; and g) trajectory and flow simulation methods.

Heat and mass transfer rates during flow of dissociated hydrogen gas over graphite surface

NASA Technical Reports Server (NTRS)

Nema, V. K.; Sharma, O. P.

1986-01-01

To improve upon the performance of chemical rockets, the nuclear reactor has been applied to a rocket propulsion system using hydrogen gas as working fluid and a graphite-composite forming a part of the structure. Under the boundary layer approximation, theoretical predictions of skin friction coefficient, surface heat transfer rate and surface regression rate have been made for laminar/turbulent dissociated hydrogen gas flowing over a flat graphite surface. The external stream is assumed to be frozen. The analysis is restricted to Mach numbers low enough to deal with the situation of only surface-reaction between hydrogen and graphite. Empirical correlations of displacement thickness, local skin friction coefficient, local Nusselt number and local non-dimensional heat transfer rate have been obtained. The magnitude of the surface regression rate is found low enough to ensure the use of graphite as a linear or a component of the system over an extended period without loss of performance.

Ultraviolet Radiative Transfer Modeling of Nearby Galaxies with Extraplanar Dusts

NASA Astrophysics Data System (ADS)

Shinn, Jong-Ho; Seon, Kwang-Il

2015-12-01

In order to examine their relation to the host galaxy, the extraplanar dusts of six nearby galaxies are modeled, employing a three-dimensional Monte Carlo radiative transfer code. The targets are from the highly inclined galaxies that show dust-scattered ultraviolet halos, and the archival Galaxy Evolution Explorer FUV band images were fitted with the model. The observed images are generally well-reproduced by two dust layers and one light source layer, whose vertical and radial distributions have exponential profiles. We obtained several important physical parameters, such as star formation rate (SFRUV), face-on optical depth, and scale-heights. Three galaxies (NGC 891, NGC 3628, and UGC 11794) show clear evidence for the existence of an extraplanar dust layer. However, it is found that the remaining three targets (IC 5249, NGC 24, and NGC 4173) do not necessarily need a thick dust disk to model the ultraviolet (UV) halo, because its contribution is too small and the UV halo may be caused by the wing part of the GALEX point spread function. This indicates that the galaxy samples reported to have UV halos may be contaminated by galaxies with negligible extraplanar (halo) dust. The galaxies showing evidence of an extraplanar dust layer fall within a narrow range on the scatter plots between physical parameters such as SFRUV and extraplanar dust mass. Several mechanisms that could possibly produce the extraplanar dust are discussed. We also found a hint that the extraplanar dust scale-height might not be much different from the polycyclic aromatic hydrocarbon emission characteristic height.

Conversion of Nuclear Waste into Nuclear Waste Glass: Experimental Investigation and Mathematical Modeling

DOE PAGES

Hrma, Pavel

2014-12-18

The melter feed, slurry, or calcine charged on the top of a pool of molten glass forms a floating layer of reacting material called the cold cap. Between the cold-cap top, which is covered with boiling slurry, and its bottom, where bubbles separate it from molten glass, the temperature changes by up to 1000 K. The processes that occur over this temperature interval within the cold cap include liberation of gases, conduction and consumption of heat, dissolution of quartz particles, formation and dissolution of intermediate crystalline phases, and generation of foam and gas cavities. These processes have been investigated usingmore » thermal analyses, optical and electronic microscopies, x-ray diffraction, as well as other techniques. Properties of the reacting feed, such as heat conductivity and density, were measured as functions of temperature. Investigating the structure of quenched cold caps produced in a laboratory-scale melter complemented the crucible studies. The cold cap consists of two main layers. The top layer contains solid particles dissolving in the glass-forming melt and open pores through which gases are escaping. The bottom layer contains bubbly melt or foam where bubbles coalesce into larger cavities that move sideways and release the gas to the atmosphere. The feed-to-glass conversion became sufficiently understood for representing the cold-cap processes via mathematical models. These models, which comprise heat transfer, mass transfer, and reaction kinetics models, have been developed with the final goal to relate feed parameters to the rate of glass melting.« less

Influence of Evaporating Droplets in the Turbulent Marine Atmospheric Boundary Layer

NASA Astrophysics Data System (ADS)

Peng, Tianze; Richter, David

2017-12-01

Sea-spray droplets ejected into the marine atmospheric boundary layer take part in a series of complex transport processes. By capturing the air-droplet coupling and feedback, we focus on how droplets modify the total heat transfer across a turbulent boundary layer. We implement a high-resolution Eulerian-Lagrangian algorithm with varied droplet size and mass loading in a turbulent open-channel flow, revealing that the influence from evaporating droplets varies for different dynamic and thermodynamic characteristics of droplets. Droplets that both respond rapidly to the ambient environment and have long suspension times are able to modify the latent and sensible heat fluxes individually, however the competing signs of this modification lead to an overall weak effect on the total heat flux. On the other hand, droplets with a slower thermodynamic response to the environment are less subjected to this compensating effect. This indicates a potential to enhance the total heat flux, but the enhancement is highly dependent on the concentration and suspension time.

Evaluation of analytical procedures for prediction of turbulent boundary layers on a porous wall

NASA Technical Reports Server (NTRS)

Towne, C. E.

1974-01-01

An analytical study has been made to determine how well current boundary layer prediction techniques work when there is mass transfer normal to the wall. The data that were considered in this investigation were for two-dimensional, incompressible, turbulent boundary layers with suction and blowing. Some of the bleed data were taken in an adverse pressure gradient. An integral prediction method was used three different porous wall skin friction relations, in addition to a solid-surface relation for the suction cases. A numerical prediction method was also used. Comparisons were made between theoretical and experimental skin friction coefficients, displacement and momentum thicknesses, and velocity profiles. The integral method with one of the porous wall skin friction laws gave very good agreement with data for most of the cases considered. The use of the solid-surface skin friction law caused the integral to overpredict the effectiveness of the bleed. The numerical techniques also worked well for most of the cases.

Study of Strength Characteristics of Steel Specimens after Selective Laser Melting of Powder Materials 17-4PH, 316L, 321

NASA Astrophysics Data System (ADS)

Zhukov, Anton; Barakhtin, Boris; Kuznetsov, Pavel

By the method of selective laser melting of powder materials nanostructured stainless steels 17-4PH, 316L, 321 were obtained. In all experiments the recorded hardness increase depending on the construction parameters. Obtained relationship of hardness increase with the carbon ratio, which explained by the chemical composition of the metal in the melting zone. It is suggested that the effect of hardness increase is associated with structural changes as to the formation and dissolution of hardening nanophases. Methods of metallography were performed in structural studies. Traces of interlayer segregation were detected inside the grains as turbulent eddies in the bands of different saturation tone caused by the migration of convective (mass transfer) metal atoms. It was visible signs of crystallization through the grain places the image (dendrite crystals). These facts revealed structural features suggest that the adhesion layers of melted powder was initiated by the colder layers and going mechanism epitaxy by coherently oriented groups of atoms from layers of melting.

Photovoltaic cells with a graded active region achieved using stamp transfer printing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Forrest, Stephen R.; Lee, Jun Yeob; Cho, Yong Joo

Disclosed herein are processes for fabricating organic photosensitive optoelectronic devices with a vertical compositionally graded organic active layer. The processes use either a single-stamp or double-stamp printing technique to transfer the vertical compositionally graded organic active layer from a starting substrate to a device layer.

Plasma nitriding induced growth of Pt-nanowire arrays as high performance electrocatalysts for fuel cells

NASA Astrophysics Data System (ADS)

Du, Shangfeng; Lin, Kaijie; Malladi, Sairam K.; Lu, Yaxiang; Sun, Shuhui; Xu, Qiang; Steinberger-Wilckens, Robert; Dong, Hanshan

2014-09-01

In this work, we demonstrate an innovative approach, combing a novel active screen plasma (ASP) technique with green chemical synthesis, for a direct fabrication of uniform Pt nanowire arrays on large-area supports. The ASP treatment enables in-situ N-doping and surface modification to the support surface, significantly promoting the uniform growth of tiny Pt nuclei which directs the growth of ultrathin single-crystal Pt nanowire (2.5-3 nm in diameter) arrays, forming a three-dimensional (3D) nano-architecture. Pt nanowire arrays in-situ grown on the large-area gas diffusion layer (GDL) (5 cm2) can be directly used as the catalyst electrode in fuel cells. The unique design brings in an extremely thin electrocatalyst layer, facilitating the charge transfer and mass transfer properties, leading to over two times higher power density than the conventional Pt nanoparticle catalyst electrode in real fuel cell environment. Due to the similar challenges faced with other nanostructures and the high availability of ASP for other material surfaces, this work will provide valuable insights and guidance towards the development of other new nano-architectures for various practical applications.

Three-dimensional flow of Prandtl fluid with Cattaneo-Christov double diffusion

NASA Astrophysics Data System (ADS)

Hayat, Tasawar; Aziz, Arsalan; Muhammad, Taseer; Alsaedi, Ahmed

2018-06-01

This research paper intends to investigate the 3D flow of Prandtl liquid in the existence of improved heat conduction and mass diffusion models. Flow is created by considering linearly bidirectional stretchable sheet. Thermal and concentration diffusions are considered by employing Cattaneo-Christov double diffusion models. Boundary layer approach has been used to simplify the governing PDEs. Suitable nondimensional similarity variables correspond to strong nonlinear ODEs. Optimal homotopy analysis method (OHAM) is employed for solutions development. The role of various pertinent variables on temperature and concentration are analyzed through graphs. The physical quantities such as surface drag coefficients and heat and mass transfer rates at the wall are also plotted and discussed. Our results indicate that the temperature and concentration are decreasing functions of thermal and concentration relaxation parameters respectively.

Quantification of bulk solution limits for liquid and interfacial transport in nanoconfinements.

PubMed

Kelly, Shaina; Balhoff, Matthew T; Torres-Verdín, Carlos

2015-02-24

Liquid imbibition, the capillary-pressure-driven flow of a liquid into a gas, provides a mechanism for studying the effects of solid-liquid and solid-liquid-gas interfaces on nanoscale transport. Deviations from the classic Washburn equation for imbibition are generally observed for nanoscale imbibition, but the identification of the origin of these irregularities in terms of transport variables varies greatly among investigators. We present an experimental method and corresponding image and data analysis scheme that enable the determination of independent effective values of nanoscale capillary pressure, liquid viscosity, and interfacial gas partitioning coefficients, all critical transport variables, from imbibition within nanochannels. Experiments documented herein are performed within two-dimensional siliceous nanochannels of varying size and as small as 30 nm × 60 nm in cross section. The wetting fluid used is the organic solvent isopropanol and the nonwetting fluid is air, but investigations are not limited to these fluids. Optical data of dynamic flow are rare in geometries that are nanoscale in two dimensions due to the limited resolution of optical microscopy. We are able to capture tracer-free liquid imbibition with reflected differential interference contrast microscopy. Results with isopropanol show a significant departure from bulk transport values in the nanochannels: reduced capillary pressures, increased liquid viscosity, and nonconstant interfacial mass-transfer coefficients. The findings equate to the nucleation of structured, quasi-crystalline boundary layers consistently ∼10-25 nm in extent. This length is far thicker than the boundary layer range prescribed by long-range intermolecular force interactions. Slower but linear imbibition in some experimental cases suggests that structured boundary layers may inhibit viscous drag at confinement walls for critical nanochannel dimensions. Probing the effects of nanoconfinement on the definitions of capillary pressure, viscosity, and interfacial mass transfer is critical in determining and improving the functionality and fluid transport efficacy of geological, biological, and synthetic nanoporous media and materials.

Mass transfer in white dwarf-neutron star binaries

NASA Astrophysics Data System (ADS)

Bobrick, Alexey; Davies, Melvyn B.; Church, Ross P.

2017-05-01

We perform hydrodynamic simulations of mass transfer in binaries that contain a white dwarf and a neutron star (WD-NS binaries), and measure the specific angular momentum of material lost from the binary in disc winds. By incorporating our results within a long-term evolution model, we measure the long-term stability of mass transfer in these binaries. We find that only binaries containing helium white dwarfs (WDs) with masses less than a critical mass of MWD, crit = 0.2 M⊙ undergo stable mass transfer and evolve into ultracompact X-ray binaries. Systems with higher mass WDs experience unstable mass transfer, which leads to tidal disruption of the WD. Our low critical mass compared to the standard jet-only model of mass-loss arises from the efficient removal of angular momentum in the mechanical disc winds, which develop at highly super-Eddington mass-transfer rates. We find that the eccentricities expected for WD-NS binaries when they come into contact do not affect the loss of angular momentum, and can only affect the long-term evolution if they change on shorter time-scales than the mass-transfer rate. Our results are broadly consistent with the observed numbers of both ultracompact X-ray binaries and radio pulsars with WD companions. The observed calcium-rich gap transients are consistent with the merger rate of unstable systems with higher mass WDs.

The effects of dual-domain mass transfer on the tritium-helium-3 dating method.

PubMed

Neumann, Rebecca B; Labolle, Eric M; Harvey, Charles F

2008-07-01

Diffusion of tritiated water (referred to as tritium) and helium-3 between mobile and immobile regions in aquifers (mass transfer) can affect tritium and helium-3 concentrations and hence tritium-helium-3 (3H/3He) ages that are used to estimate aquifer recharge and groundwater residence times. Tritium and helium-3 chromatographically separate during transport because their molecular diffusion coefficients differ. Simulations of tritium and helium-3 transport and diffusive mass transfer along stream tubes show that mass transfer can shift the 3H/3He age of the tritium and helium-3 concentration ([3H + 3He]) peak to dates much younger than the 1963 peak in atmospheric tritium. Furthermore, diffusive mass-transfer can cause the 3H/3He age to become younger downstream along a stream tube, even as the mean water-age must increase. Simulated patterns of [3H + 3He] versus 3H/3He age using a mass transfer model appear consistent with a variety of field data. These results suggest that diffusive mass transfer should be considered, especially when the [3H + 3He] peak is not well defined or appears younger than the atmospheric peak. 3H/3He data provide information about upstream mass-transfer processes that could be used to constrain mass-transfer models; however, uncritical acceptance of 3H/3He dates from aquifers with immobile regions could be misleading.

Optimization of the freeze-drying cycle: adaptation of the pressure rise analysis model to non-instantaneous isolation valves.

PubMed

Chouvenc, P; Vessot, S; Andrieu, J; Vacus, P

2005-01-01

The principal aim of this study is to extend to a pilot freeze-dryer equipped with a non-instantaneous isolation valve the previously presented pressure rise analysis (PRA) model for monitoring the product temperature and the resistance to mass transfer of the dried layer during primary drying. This method, derived from the original MTM method previously published, consists of interrupting rapidly (a few seconds) the water vapour flow from the sublimation chamber to the condenser and analysing the resulting dynamics of the total chamber pressure increase. The valve effect on the pressure rise profile observed during the isolation valve closing period was corrected by introducing in the initial PRA model a valve characteristic function factor which turned out to be independent of the operating conditions. This new extended PRA model was validated by implementing successively the two types of valves and by analysing the pressure rise kinetics data with the corresponding PRA models in the same operating conditions. The coherence and consistency shown on the identified parameter values (sublimation front temperature, dried layer mass transfer resistance) allowed validation of this extended PRA model with a non-instantaneous isolation valve. These results confirm that the PRA method, with or without an instantaneous isolation valve, is appropriate for on-line monitoring of product characteristics during freeze-drying. The advantages of PRA are that the method is rapid, non-invasive, and global. Consequently, PRA might become a powerful and promising tool not only for the control of pilot freeze-dryers but also for industrial freeze-dryers equipped with external condensers.

Influence of acoustic impedance of multilayer acoustic systems on the transfer function of ultrasonic airborne transducers.

PubMed

Gudra, Tadeusz; Opieliński, Krzysztof J

2002-05-01

In different solutions of ultrasonic transducers radiating acoustic energy into the air there occurs the problem of the proper selection of the acoustic impedance of one or more matching layers. The goal of this work was a computer analysis of the influence of acoustic impedance on the transfer function of piezoceramic transducers equipped with matching layers. Cases of resonance and non-resonance matching impedance in relation to the transfer function and the energy transmission coefficient for solid state-air systems were analysed. With stable thickness of matching layers the required shape of the transfer function can be obtained through proper choice of acoustic impedance were built (e.g. maximal flat function). The proper choice of acoustic impedance requires an elaboration of precise methods of synthesis of matching systems. Using the known matching criteria (Chebyshev's, DeSilets', Souquet's), the transfer function characteristics of transducers equipped with one, two, and three matching layers as well as the optimisation methods of the energy transmission coefficient were presented. The influence of the backside load of the transducer on the shape of transfer function was also analysed. The calculation results of this function for different loads of the transducer backside without and with the different matching layers were presented. The proper load selection allows us to obtain the desired shape of the transfer function, which determines the pulse shape generated by the transducer.

Heat transfer optimization for air-mist cooling between a stack of parallel plates

NASA Astrophysics Data System (ADS)

Issa, Roy J.

2010-06-01

A theoretical model is developed to predict the upper limit heat transfer between a stack of parallel plates subject to multiphase cooling by air-mist flow. The model predicts the optimal separation distance between the plates based on the development of the boundary layers for small and large separation distances, and for dilute mist conditions. Simulation results show the optimal separation distance to be strongly dependent on the liquid-to-air mass flow rate loading ratio, and reach a limit for a critical loading. For these dilute spray conditions, complete evaporation of the droplets takes place. Simulation results also show the optimal separation distance decreases with the increase in the mist flow rate. The proposed theoretical model shall lead to a better understanding of the design of fins spacing in heat exchangers where multiphase spray cooling is used.

Influence of the boundary conditions on heat and mass transfer in spacer-filled channels

NASA Astrophysics Data System (ADS)

Ciofalo, M.; La Cerva, M. F.; Di Liberto, M.; Tamburini, A.

2017-11-01

The purpose of this study is to discuss some problems which arise in heat or mass transfer in complex channels, with special reference to the spacer-filled channels adopted in membrane processes. Among the issues addressed are the consistent definition of local and mean heat or mass transfer coefficients; the influence of the wall boundary conditions; the influence of one-side versus two-side heat/mass transfer. Most of the results discussed were obtained by finite volume CFD simulations concerning heat transfer in Membrane Distillation or mass transfer in Electrodialysis and Reverse Electrodialysis, but many of the conclusions apply also to different processes involving geometrically complex channels

A Structurally Specialized Uniform Wall Layer is Essential for Constructing Wall Ingrowth Papillae in Transfer Cells

PubMed Central

Xia, Xue; Zhang, Hui-Ming; Offler, Christina E.; Patrick, John W.

2017-01-01

Transfer cells are characterized by wall labyrinths with either a flange or reticulate architecture. A literature survey established that reticulate wall ingrowth papillae ubiquitously arise from a modified component of their wall labyrinth, termed the uniform wall layer; a structure absent from flange transfer cells. This finding sparked an investigation of the deposition characteristics and role of the uniform wall layer using a Vicia faba cotyledon culture system. On transfer of cotyledons to culture, their adaxial epidermal cells spontaneously trans-differentiate to a reticulate architecture comparable to their abaxial epidermal transfer cell counterparts formed in planta. Uniform wall layer construction commenced once adaxial epidermal cell expansion had ceased to overlay the original outer periclinal wall on its inner surface. In contrast to the dense ring-like lattice of cellulose microfibrils in the original primary wall, the uniform wall layer was characterized by a sparsely dispersed array of linear cellulose microfibrils. A re-modeled cortical microtubule array exerted no influence on uniform wall layer formation or on its cellulose microfibril organization. Surprisingly, formation of the uniform wall layer was not dependent upon depositing a cellulose scaffold. In contrast, uniform wall cellulose microfibrils were essential precursors for constructing wall ingrowth papillae. On converging to form wall ingrowth papillae, the cellulose microfibril diameters increased 3-fold. This event correlated with up-regulated differential, and transfer-cell specific, expression of VfCesA3B while transcript levels of other cellulose biosynthetic-related genes linked with primary wall construction were substantially down-regulated. PMID:29259611

A Structurally Specialized Uniform Wall Layer is Essential for Constructing Wall Ingrowth Papillae in Transfer Cells.

PubMed

Xia, Xue; Zhang, Hui-Ming; Offler, Christina E; Patrick, John W

2017-01-01

Transfer cells are characterized by wall labyrinths with either a flange or reticulate architecture. A literature survey established that reticulate wall ingrowth papillae ubiquitously arise from a modified component of their wall labyrinth, termed the uniform wall layer; a structure absent from flange transfer cells. This finding sparked an investigation of the deposition characteristics and role of the uniform wall layer using a Vicia faba cotyledon culture system. On transfer of cotyledons to culture, their adaxial epidermal cells spontaneously trans -differentiate to a reticulate architecture comparable to their abaxial epidermal transfer cell counterparts formed in planta . Uniform wall layer construction commenced once adaxial epidermal cell expansion had ceased to overlay the original outer periclinal wall on its inner surface. In contrast to the dense ring-like lattice of cellulose microfibrils in the original primary wall, the uniform wall layer was characterized by a sparsely dispersed array of linear cellulose microfibrils. A re-modeled cortical microtubule array exerted no influence on uniform wall layer formation or on its cellulose microfibril organization. Surprisingly, formation of the uniform wall layer was not dependent upon depositing a cellulose scaffold. In contrast, uniform wall cellulose microfibrils were essential precursors for constructing wall ingrowth papillae. On converging to form wall ingrowth papillae, the cellulose microfibril diameters increased 3-fold. This event correlated with up-regulated differential, and transfer-cell specific, expression of VfCesA3B while transcript levels of other cellulose biosynthetic-related genes linked with primary wall construction were substantially down-regulated.

Boundary Layer Control for Hypersonic Airbreathing Vehicles

NASA Technical Reports Server (NTRS)

Berry, Scott A.; Nowak, Robert J.; Horvath, Thomas J.

2004-01-01

Active and passive methods for tripping hypersonic boundary layers have been examined in NASA Langley Research Center wind tunnels using a Hyper-X model. This investigation assessed several concepts for forcing transition, including passive discrete roughness elements and active mass addition (or blowing), in the 20-Inch Mach 6 Air and the 31-Inch Mach 10 Air Tunnels. Heat transfer distributions obtained via phosphor thermography, shock system details, and surface streamline patterns were measured on a 0.333-scale model of the Hyper-X forebody. The comparisons between the active and passive methods for boundary layer control were conducted at test conditions that nearly match the Hyper-X nominal Mach 7 flight test-point of an angle-of-attack of 2-deg and length Reynolds number of 5.6 million. For passive roughness, the primary parametric variation was a range of trip heights within the calculated boundary layer thickness for several trip concepts. The passive roughness study resulted in a swept ramp configuration, scaled to be roughly 0.6 of the calculated boundary layer thickness, being selected for the Mach 7 flight vehicle. For the active blowing study, the manifold pressure was systematically varied (while monitoring the mass flow) for each configuration to determine the jet penetration height, with schlieren, and transition movement, with the phosphor system, for comparison to the passive results. All the blowing concepts tested, which included various rows of sonic orifices (holes), two- and three-dimensional slots, and random porosity, provided transition onset near the trip location with manifold stagnation pressures on the order of 40 times the model surface static pressure, which is adequate to ensure sonic jets. The present results indicate that the jet penetration height for blowing was roughly half the height required with passive roughness elements for an equivalent amount of transition movement.

Similar solutions for viscous hypersonic flow over a slender three-fourths-power body of revolution

NASA Technical Reports Server (NTRS)

Lin, Chin-Shun

1987-01-01

For hypersonic flow with a shock wave, there is a similar solution consistent throughout the viscous and inviscid layers along a very slender three-fourths-power body of revolution The strong pressure interaction problem can then be treated by the method of similarity. Numerical calculations are performed in the viscous region with the edge pressure distribution known from the inviscid similar solutions. The compressible laminar boundary-layer equations are transformed into a system of ordinary differential equations. The resulting two-point boundary value problem is then solved by the Runge-Kutta method with a modified Newton's method for the corresponding boundary conditions. The effects of wall temperature, mass bleeding, and body transverse curvature are investigated. The induced pressure, displacement thickness, skin friction, and heat transfer due to the previously mentioned parameters are estimated and analyzed.

Mass-spring matching layers for high-frequency ultrasound transducers: a new technique using vacuum deposition.

PubMed

Brown, Jeremy; Sharma, Srikanta; Leadbetter, Jeff; Cochran, Sandy; Adamson, Rob

2014-11-01

We have developed a technique of applying multiple matching layers to high-frequency (>30 MHz) imaging transducers, by using carefully controlled vacuum deposition alone. This technique uses a thin mass-spring matching layer approach that was previously described in a low-frequency (1 to 10 MHz) transducer design with epoxied layers. This mass- spring approach is more suitable to vacuum deposition in highfrequency transducers over the conventional quarter-wavelength resonant cavity approach, because thinner layers and more versatile material selection can be used, the difficulty in precisely lapping quarter-wavelength matching layers is avoided, the layers are less attenuating, and the layers can be applied to a curved surface. Two different 3-mm-diameter 45-MHz planar lithium niobate transducers and one geometrically curved 3-mm lithium niobate transducer were designed and fabricated using this matching layer approach with copper as the mass layer and parylene as the spring layer. The first planar lithium niobate transducer used a single mass-spring matching network, and the second planar lithium niobate transducer used a single mass-spring network to approximate the first layer in a dual quarter-wavelength matching layer system in addition to a conventional quarter-wavelength layer as the second matching layer. The curved lithium niobate transducer was press focused and used a similar mass-spring plus quarter-wavelength matching layer network. These transducers were then compared with identical transducers with no matching layers and the performance improvement was quantified. The bandwidth of the lithium niobate transducer with the single mass-spring layer was measured to be 46% and the insertion loss was measured to be -21.9 dB. The bandwidth and insertion loss of the lithium niobate transducer with the mass-spring network plus quarter-wavelength matching were measured to be 59% and -18.2 dB, respectively. These values were compared with the unmatched transducer, which had a bandwidth of 28% and insertion loss of -34.1 dB. The bandwidth and insertion loss of the curved lithium niobate transducer with the mass-spring plus quarter-wavelength matching layer combination were measured to be 68% and -26 dB, respectively; this compared with the measured unmatched bandwidth and insertion loss of 35% and -37 dB. All experimentally measured values were in excellent agreement with theoretical Krimholtz-Leedom-Matthaei (KLM) model predictions.

Transfer Printing Method to Obtain Polarized Light Emission in Organic Light-Emitting Device

NASA Astrophysics Data System (ADS)

Noh, Hee Yeon; Park, Chang-sub; Park, Ji-Sub; Kang, Shin-Won; Kim, Hak-Rin

2012-06-01

We demonstrate a transfer printing method to obtain polarized light emission in organic light-emitting devices (OLEDs). On a rubbed self-assembled monolayer (SAM), a spin-coated liquid crystalline light-emissive polymer is aligned along the rubbing direction because of the anisotropic interfacial intermolecular interaction. Owing to the low surface energy of the SAM surface, the light-emissive layer was easily transferred to a patterned poly(dimethylsiloxane) (PDMS) stamp surface without degrading the ordering. Finally, a polarized light-emissive OLED device was prepared by transferring the patterned light-emissive layer to the charge transport layer of the OLED structure.

Effect of Mass Proportion of Municipal Solid Waste Incinerator Bottom Ash Layer to Municipal Solid Waste Layer on the Cu and Zn Discharge from Landfill.

PubMed

Kong, Qingna; Yao, Jun; Qiu, Zhanhong; Shen, Dongsheng

2016-01-01

Municipal solid waste incinerator (MSWI) bottom ash is often used as the protection layer for the geomembrane and intermediate layer in the landfill. In this study, three sets of simulated landfills with different mass proportion of MSWI bottom ash layer to municipal solid waste (MSW) layer were operated. Cu and Zn concentrations in the leachates and MSW were monitored to investigate the effect of MSWI bottom ash layer on the Cu and Zn discharge from the landfill. The results showed that the Zn discharge was dependent on the mass proportion of MSWI bottom ash layer. The pH of landfill was not notably increased when the mass proportion of MSWI bottom ash layer to MSW layer was 1 : 9, resulting in the enhancement of the Zn discharge. However, Zn discharge was mitigated when the mass proportion was 2 : 8, as the pH of landfill was notably promoted. The discharge of Cu was not dependent on the mass proportion, due to the great affinity of Cu to organic matter. Moreover, Cu and Zn contents of the sub-MSW layer increased due to the MSWI bottom ash layer. Therefore, the MSWI bottom ash layer can increase the potential environmental threat of the landfill.

Modeling and sensitivity analysis of mass transfer in active multilayer polymeric film for food applications

NASA Astrophysics Data System (ADS)

Bedane, T.; Di Maio, L.; Scarfato, P.; Incarnato, L.; Marra, F.

2015-12-01

The barrier performance of multilayer polymeric films for food applications has been significantly improved by incorporating oxygen scavenging materials. The scavenging activity depends on parameters such as diffusion coefficient, solubility, concentration of scavenger loaded and the number of available reactive sites. These parameters influence the barrier performance of the film in different ways. Virtualization of the process is useful to characterize, design and optimize the barrier performance based on physical configuration of the films. Also, the knowledge of values of parameters is important to predict the performances. Inverse modeling and sensitivity analysis are sole way to find reasonable values of poorly defined, unmeasured parameters and to analyze the most influencing parameters. Thus, the objective of this work was to develop a model to predict barrier properties of multilayer film incorporated with reactive layers and to analyze and characterize their performances. Polymeric film based on three layers of Polyethylene terephthalate (PET), with a core reactive layer, at different thickness configurations was considered in the model. A one dimensional diffusion equation with reaction was solved numerically to predict the concentration of oxygen diffused into the polymer taking into account the reactive ability of the core layer. The model was solved using commercial software for different film layer configurations and sensitivity analysis based on inverse modeling was carried out to understand the effect of physical parameters. The results have shown that the use of sensitivity analysis can provide physical understanding of the parameters which highly affect the gas permeation into the film. Solubility and the number of available reactive sites were the factors mainly influencing the barrier performance of three layered polymeric film. Multilayer films slightly modified the steady transport properties in comparison to net PET, giving a small reduction in the permeability and oxygen transfer rate values. Scavenging capacity of the multilayer film increased linearly with the increase of the reactive layer thickness and the oxygen absorption reaction at short times decreased proportionally with the thickness of the external PET layer.

Modeling and sensitivity analysis of mass transfer in active multilayer polymeric film for food applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bedane, T.; Di Maio, L.; Scarfato, P.

The barrier performance of multilayer polymeric films for food applications has been significantly improved by incorporating oxygen scavenging materials. The scavenging activity depends on parameters such as diffusion coefficient, solubility, concentration of scavenger loaded and the number of available reactive sites. These parameters influence the barrier performance of the film in different ways. Virtualization of the process is useful to characterize, design and optimize the barrier performance based on physical configuration of the films. Also, the knowledge of values of parameters is important to predict the performances. Inverse modeling and sensitivity analysis are sole way to find reasonable values ofmore » poorly defined, unmeasured parameters and to analyze the most influencing parameters. Thus, the objective of this work was to develop a model to predict barrier properties of multilayer film incorporated with reactive layers and to analyze and characterize their performances. Polymeric film based on three layers of Polyethylene terephthalate (PET), with a core reactive layer, at different thickness configurations was considered in the model. A one dimensional diffusion equation with reaction was solved numerically to predict the concentration of oxygen diffused into the polymer taking into account the reactive ability of the core layer. The model was solved using commercial software for different film layer configurations and sensitivity analysis based on inverse modeling was carried out to understand the effect of physical parameters. The results have shown that the use of sensitivity analysis can provide physical understanding of the parameters which highly affect the gas permeation into the film. Solubility and the number of available reactive sites were the factors mainly influencing the barrier performance of three layered polymeric film. Multilayer films slightly modified the steady transport properties in comparison to net PET, giving a small reduction in the permeability and oxygen transfer rate values. Scavenging capacity of the multilayer film increased linearly with the increase of the reactive layer thickness and the oxygen absorption reaction at short times decreased proportionally with the thickness of the external PET layer.« less

L2-LBMT: A Layered Load Balance Routing Protocol for underwater multimedia data transmission

NASA Astrophysics Data System (ADS)

Lv, Ze; Tang, Ruichun; Tao, Ye; Sun, Xin; Xu, Xiaowei

2017-12-01

Providing highly efficient underwater transmission of mass multimedia data is challenging due to the particularities of the underwater environment. Although there are many schemes proposed to optimize the underwater acoustic network communication protocols, from physical layer, data link layer, network layer to transport layer, the existing routing protocols for underwater wireless sensor network (UWSN) still cannot well deal with the problems in transmitting multimedia data because of the difficulties involved in high energy consumption, low transmission reliability or high transmission delay. It prevents us from applying underwater multimedia data to real-time monitoring of marine environment in practical application, especially in emergency search, rescue operation and military field. Therefore, the inefficient transmission of marine multimedia data has become a serious problem that needs to be solved urgently. In this paper, A Layered Load Balance Routing Protocol (L2-LBMT) is proposed for underwater multimedia data transmission. In L2-LBMT, we use layered and load-balance Ad Hoc Network to transmit data, and adopt segmented data reliable transfer (SDRT) protocol to improve the data transport reliability. And a 3-node variant of tornado (3-VT) code is also combined with the Ad Hoc Network to transmit little emergency data more quickly. The simulation results show that the proposed protocol can balance energy consumption of each node, effectively prolong the network lifetime and reduce transmission delay of marine multimedia data.

Investigation of the Influence of Heat Balance Shifts on the Freeze Microstructure and Composition in Aluminum Smelting Bath System: Cryolite-CaF2-AlF3-Al2O3

NASA Astrophysics Data System (ADS)

Liu, Jingjing; Fallah-Mehrjardi, Ata; Shishin, Denis; Jak, Evgueni; Dorreen, Mark; Taylor, Mark

2017-12-01

In an aluminum electrolysis cell, the side ledge forms on side walls to protect it from the corrosive cryolitic bath. In this study, a series of laboratory analogue experiments have been carried out to investigate the microstructure and composition of side ledge (freeze linings) at different heat balance steady states. Three distinct layers are found in the freeze linings formed in the designed Cryolite-CaF2-AlF3-Al2O3 electrolyte system: a closed (columnar) crystalline layer, an open crystalline layer, and a sealing layer. This layered structure changes when the heat balance is shifted between different steady states, by melting or freezing the open crystalline layer. Phase chemistry of the freeze lining is studied in this paper to understand the side ledge formation process upon heat balance shifts. Electron probe X-ray microanalysis (EPMA) is used to characterize the microstructure and compositions of distinct phases existing in the freeze linings, which are identified as cryolite, chiolite, Ca-cryolite, and alumina. A freeze formation mechanism is further developed based on these microstructural/compositional investigations and also thermodynamic calculations through the software—FactSage. It is found that entrapped liquid channels exist in the open crystalline layer, assisting with the mass transfer between solidified crystals and bulk molten bath.

Fabrication and improved photoelectrochemical properties of a transferred GaN-based thin film with InGaN/GaN layers.

PubMed

Cao, Dezhong; Xiao, Hongdi; Gao, Qingxue; Yang, Xiaokun; Luan, Caina; Mao, Hongzhi; Liu, Jianqiang; Liu, Xiangdong

2017-08-17

Herein, a lift-off mesoporous GaN-based thin film, which consisted of a strong phase-separated InGaN/GaN layer and an n-GaN layer, was fabricated via an electrochemical etching method in a hydrofluoric acid (HF) solution for the first time and then transferred onto quartz or n-Si substrates, acting as photoanodes during photoelectrochemical (PEC) water splitting in a 1 M NaCl aqueous solution. Compared to the as-grown GaN-based film, the transferred GaN-based thin films possess higher and blue-shifted light emission, presumably resulting from an increase in the surface area and stress relaxation in the InGaN/GaN layer embedded on the mesoporous n-GaN. The properties such as (i) high photoconversion efficiency, (ii) low turn-on voltage (-0.79 V versus Ag/AgCl), and (iii) outstanding stability enable the transferred films to have excellent PEC water splitting ability. Furthermore, as compared to the film transferred onto the quartz substrate, the film transferred onto the n-Si substrate exhibits higher photoconversion efficiency (2.99% at -0.10 V) due to holes (h + ) in the mesoporous n-GaN layer that originate from the n-Si substrate.

Modeling of the heat transfer in bypass transitional boundary-layer flows

NASA Technical Reports Server (NTRS)

Simon, Frederick F.; Stephens, Craig A.

1991-01-01

A low Reynolds number k-epsilon turbulence model and conditioned momentum, energy and turbulence equations were used to predict bypass transition heat transfer on a flat plate in a high-disturbance environment with zero pressure gradient. The use of conditioned equations was demonstrated to be an improvement over the use of the global-time-averaged equations for the calculation of velocity profiles and turbulence intensity profiles in the transition region of a boundary layer. The approach of conditioned equations is extended to include heat transfer and a modeling of transition events is used to predict transition onset and the extent of transition on a flat plate. The events, which describe the boundary layer at the leading edge, result in boundary-layer regions consisting of: (1) the laminar, (2) pseudolaminar, (3) transitional, and (4) turbulent boundary layers. The modeled transition events were incorporated into the TEXSTAN 2-D boundary-layer code which is used to numerically predict the heat transfer. The numerical predictions in general compared well with the experimental data and revealed areas where additional experimental information is needed.

"Self-Peel-Off" Transfer Produces Ultrathin Polyvinylidene-Fluoride-Based Flexible Nanodevices.

PubMed

Tai, Yanlong; Lubineau, Gilles

2017-04-01

Here, a new strategy, self-peel-off transfer, for the preparation of ultrathin flexible nanodevices made from polyvinylidene-fluoride (PVDF) is reported. In this process, a functional pattern of nanoparticles is transferred via peeling from a temporary substrate to the final PVDF film. This peeling process takes advantage of the differences in the work of adhesion between the various layers (the PVDF layer, the nanoparticle-pattern layer and the substrate layer) and of the high stresses generated by the differential thermal expansion of the layers. The work of adhesion is mainly guided by the basic physical/chemical properties of these layers and is highly sensitive to variations in temperature and moisture in the environment. The peeling technique is tested on a variety of PVDF-based functional films using gold/palladium nanoparticles, carbon nanotubes, graphene oxide, and lithium iron phosphate. Several PVDF-based flexible nanodevices are prepared, including a single-sided wireless flexible humidity sensor in which PVDF is used as the substrate and a double-sided flexible capacitor in which PVDF is used as the ferroelectric layer and the carrier layer. Results show that the nanodevices perform with high repeatability and stability. Self-peel-off transfer is a viable preparation strategy for the design and fabrication of flexible, ultrathin, and light-weight nanodevices.

Interfacial nonequilibrium and Bénard-Marangoni instability of a liquid-vapor system

NASA Astrophysics Data System (ADS)

Margerit, J.; Colinet, P.; Lebon, G.; Iorio, C. S.; Legros, J. C.

2003-10-01

We study Bénard-Marangoni instability in a system formed by a horizontal liquid layer and its overlying vapor. The liquid is lying on a hot rigid plate and the vapor is bounded by a cold parallel plate. A pump maintains a reduced pressure in the vapor layer and evacuates the vapor. This investigation is undertaken within the classical quasisteady approximation for both the vapor and the liquid phases. The two layers are separated by a deformable interface. Temporarily frozen temperature and velocity distributions are employed at each instant for the stability analysis, limited to infinitesimal disturbances (linear regime). We use irreversible thermodynamics to model the phase change under interfacial nonequilibrium. Within this description, the interface appears as a barrier for transport of both heat and mass. Hence, in contrast with previous studies, we consider the possibility of a temperature jump across the interface, as recently measured experimentally. The stability analysis shows that the interfacial resistances to heat and mass transfer have a destabilizing influence compared to an interface that is in thermodynamic equilibrium. The role of the fluctuations in the vapor phase on the onset of instability is discussed. The conditions to reduce the system to a one phase model are also established. Finally, the influence of the evaporation parameters and of the presence of an inert gas on the marginal stability curves is discussed.

Laser-fired contact formation on metallized and passivated silicon wafers under short pulse durations

NASA Astrophysics Data System (ADS)

Raghavan, Ashwin S.

The objective of this work is to develop a comprehensive understanding of the physical processes governing laser-fired contact (LFC) formation under microsecond pulse durations. Primary emphasis is placed on understanding how processing parameters influence contact morphology, passivation layer quality, alloying of Al and Si, and contact resistance. In addition, the research seeks to develop a quantitative method to accurately predict the contact geometry, thermal cycles, heat and mass transfer phenomena, and the influence of contact pitch distance on substrate temperatures in order to improve the physical understanding of the underlying processes. Finally, the work seeks to predict how geometry for LFCs produced with microsecond pulses will influence fabrication and performance factors, such as the rear side contacting scheme, rear surface series resistance and effective rear surface recombination rates. The characterization of LFC cross-sections reveals that the use of microsecond pulse durations results in the formation of three-dimensional hemispherical or half-ellipsoidal contact geometries. The LFC is heavily alloyed with Al and Si and is composed of a two-phase Al-Si microstructure that grows from the Si wafer during resolidification. As a result of forming a large three-dimensional contact geometry, the total contact resistance is governed by the interfacial contact area between the LFC and the wafer rather than the planar contact area at the original Al-Si interface within an opening in the passivation layer. By forming three-dimensional LFCs, the total contact resistance is significantly reduced in comparison to that predicted for planar contacts. In addition, despite the high energy densities associated with microsecond pulse durations, the passivation layer is well preserved outside of the immediate contact region. Therefore, the use of microsecond pulse durations can be used to improve device performance by leading to lower total contact resistances while preserving the passivation layer. A mathematical model was developed to accurately predict LFC geometry over a wide range of processing parameters by accounting for transient changes in Al and Si alloy composition within the LFC. Since LFC geometry plays a critical role in device performance, an accurate method to predict contact geometry is an important tool that can facilitate further process development. Dimensionless analysis was also conducted to evaluate the relative importance of heat and mass transfer mechanisms. It is shown that convection plays a dominant role in the heat and mass transfer within the molten pool. Due to convective mass transfer, the contacts are heavily doped with Al and Si within 10 is after contact formation, which contributes to the entire resolidified region behaving as the electrically active LFC. The validated model is also used to determine safe operating regimes during laser processing to avoid excessively high operating temperatures. By maintaining processing temperatures below a critical temperature threshold, the onset of liquid metal expulsion and loss of alloying elements can be avoided. The process maps provide a framework that can be used to tailor LFC geometry for device fabrication. Finally, using various geometric relationships for the rear side contacting scheme for photovoltaic devices, it is shown that by employing hemispherical contacts, the number of LFCs required on the rear side can be reduced 75% while doubling the pitch distance and increasing the passivation fraction. Reducing the number of backside contacts required can have a noteworthy impact of manufacturing throughput. In addition, the analytical models suggest that device performance can be maintained at levels comparable to those achieved for planar contacts when producing three-dimensional contacts. The materials and electrical characterization results, device simulations, and design considerations presented in this thesis indicate that by forming three-dimensional LFCs, performance levels of Si-based photovoltaic devices can be maintained while greatly enhancing manufacturing efficiency. The research lays a solid foundation for future development of the LFC process with microsecond pulse durations and indicates that device fabrication employing this method is a critical step moving forward.

Investigation of mass transfer intensification under power ultrasound irradiation using 3D computational simulation: A comparative analysis.

PubMed

Sajjadi, Baharak; Asgharzadehahmadi, Seyedali; Asaithambi, Perumal; Raman, Abdul Aziz Abdul; Parthasarathy, Rajarathinam

2017-01-01

This paper aims at investigating the influence of acoustic streaming induced by low-frequency (24kHz) ultrasound irradiation on mass transfer in a two-phase system. The main objective is to discuss the possible mass transfer improvements under ultrasound irradiation. Three analyses were conducted: i) experimental analysis of mass transfer under ultrasound irradiation; ii) comparative analysis between the results of the ultrasound assisted mass transfer with that obtained from mechanically stirring; and iii) computational analysis of the systems using 3D CFD simulation. In the experimental part, the interactive effects of liquid rheological properties, ultrasound power and superficial gas velocity on mass transfer were investigated in two different sonicators. The results were then compared with that of mechanical stirring. In the computational part, the results were illustrated as a function of acoustic streaming behaviour, fluid flow pattern, gas/liquid volume fraction and turbulence in the two-phase system and finally the mass transfer coefficient was specified. It was found that additional turbulence created by ultrasound played the most important role on intensifying the mass transfer phenomena compared to that in stirred vessel. Furthermore, long residence time which depends on geometrical parameters is another key for mass transfer. The results obtained in the present study would help researchers understand the role of ultrasound as an energy source and acoustic streaming as one of the most important of ultrasound waves on intensifying gas-liquid mass transfer in a two-phase system and can be a breakthrough in the design procedure as no similar studies were found in the existing literature. Copyright © 2016. Published by Elsevier B.V.

Cooling without contact in bilayer dipolar Fermi gases

NASA Astrophysics Data System (ADS)

Tanatar, Bilal; Renklioglu, Basak; Oktel, M. Ozgur

2016-05-01

We consider two parallel layers of dipolar ultracold Fermi gases at different temperatures and calculate the heat transfer between them. The effective interactions describing screening and correlation effects between the dipoles in a single layer are modelled within the Euler-Lagrange Fermi-hypernetted chain approximation. The random-phase approximation is employed for the interactions across the layers. We investigate the amount of transferred power between the layers as a function of the temperature difference. Energy transfer proceeds via the long-range dipole-dipole interactions. A simple thermal model is developed to investigate the feasibility of using the contactless sympathetic cooling of the ultracold polar atoms/molecules. Our calculations indicate that dipolar heat transfer is effective for typical polar molecule experiments and may be utilized as a cooling process. Supported by TUBA and TUBITAK (112T974).

Spin-Transfer Studies in Magnetic Multilayer Nanostructures

NASA Astrophysics Data System (ADS)

Emley, N. C.; Albert, F. J.; Ryan, E. M.; Krivorotov, I. N.; Ralph, D. C.; Buhrman, R. A.

2003-03-01

Numerous experiments have demonstrated current-induced magnetization reversal in ferromagnet/paramagnet/ferromagnet nanostructures with the current in the CPP geometry. The primary mechanism for this reversal is the transfer of angular momentum from the spin-polarized conduction electrons to the nanomagnet moment the spin transfer effect. This phenomenon has potential application in nanoscale, current-controlled non-volatile memory elements, but several challenges must be overcome for realistic device implementation. Typical Co/Cu/Co nanopillar devices, although effective for fundamental studies, are not advantageous for technological applications because of their large switching currents Ic ( 3-10 mA) and small R·A (< 1 mΩ·µm^2). Here we report initial results testing some possible approaches for enhancing spin-transfer device performance which involve the addition of more layers, and hence, more complexity, to the simple Co/Cu/Co trilayer structure. These additions include synthetic antiferromagnet layers (SAF), exchange biased layers, nano-oxide layers (NOL), and additional magnetic layers. Research supported by NSF and DARPA

Freeze-drying process design by manometric temperature measurement: design of a smart freeze-dryer.

PubMed

Tang, Xiaolin Charlie; Nail, Steven L; Pikal, Michael J

2005-04-01

To develop a procedure based on manometric temperature measurement (MTM) and an expert system for good practices in freeze drying that will allow development of an optimized freeze-drying process during a single laboratory freeze-drying experiment. Freeze drying was performed with a FTS Dura-Stop/Dura-Top freeze dryer with the manometric temperature measurement software installed. Five percent solutions of glycine, sucrose, or mannitol with 2 ml to 4 ml fill in 5 ml vials were used, with all vials loaded on one shelf. Details of freezing, optimization of chamber pressure, target product temperature, and some aspects of secondary drying are determined by the expert system algorithms. MTM measurements were used to select the optimum shelf temperature, to determine drying end points, and to evaluate residual moisture content in real-time. MTM measurements were made at 1 hour or half-hour intervals during primary drying and secondary drying, with a data collection frequency of 4 points per second. The improved MTM equations were fit to pressure-time data generated by the MTM procedure using Microcal Origin software to obtain product temperature and dry layer resistance. Using heat and mass transfer theory, the MTM results were used to evaluate mass and heat transfer rates and to estimate the shelf temperature required to maintain the target product temperature. MTM product dry layer resistance is accurate until about two-thirds of total primary drying time is over, and the MTM product temperature is normally accurate almost to the end of primary drying provided that effective thermal shielding is used in the freeze-drying process. The primary drying times can be accurately estimated from mass transfer rates calculated very early in the run, and we find the target product temperature can be achieved and maintained with only a few adjustments of shelf temperature. The freeze-dryer overload conditions can be estimated by calculation of heat/mass flow at the target product temperature. It was found that the MTM results serve as an excellent indicator of the end point of primary drying. Further, we find that the rate of water desorption during secondary drying may be accurately measured by a variation of the basic MTM procedure. Thus, both the end point of secondary drying and real-time residual moisture may be obtained during secondary drying. Manometric temperature measurement and the expert system for good practices in freeze drying does allow development of an optimized freeze-drying process during a single laboratory freeze-drying experiment.

A two-phase solid/fluid model for dense granular flows including dilatancy effects

NASA Astrophysics Data System (ADS)

Mangeney, Anne; Bouchut, Francois; Fernandez-Nieto, Enrique; Koné, El-Hadj; Narbona-Reina, Gladys

2016-04-01

Describing grain/fluid interaction in debris flows models is still an open and challenging issue with key impact on hazard assessment [{Iverson et al.}, 2010]. We present here a two-phase two-thin-layer model for fluidized debris flows that takes into account dilatancy effects. It describes the velocity of both the solid and the fluid phases, the compression/dilatation of the granular media and its interaction with the pore fluid pressure [{Bouchut et al.}, 2016]. The model is derived from a 3D two-phase model proposed by {Jackson} [2000] based on the 4 equations of mass and momentum conservation within the two phases. This system has 5 unknowns: the solid and fluid velocities, the solid and fluid pressures and the solid volume fraction. As a result, an additional equation inside the mixture is necessary to close the system. Surprisingly, this issue is inadequately accounted for in the models that have been developed on the basis of Jackson's work [{Bouchut et al.}, 2015]. In particular, {Pitman and Le} [2005] replaced this closure simply by imposing an extra boundary condition at the surface of the flow. When making a shallow expansion, this condition can be considered as a closure condition. However, the corresponding model cannot account for a dissipative energy balance. We propose here an approach to correctly deal with the thermodynamics of Jackson's model by closing the mixture equations by a weak compressibility relation following {Roux and Radjai} [1998]. This relation implies that the occurrence of dilation or contraction of the granular material in the model depends on whether the solid volume fraction is respectively higher or lower than a critical value. When dilation occurs, the fluid is sucked into the granular material, the pore pressure decreases and the friction force on the granular phase increases. On the contrary, in the case of contraction, the fluid is expelled from the mixture, the pore pressure increases and the friction force diminishes. To account for this transfer of fluid into and out of the mixture, a two-layer model is proposed with a fluid layer on top of the two-phase mixture layer. Mass and momentum conservation are satisfied for the two phases, and mass and momentum are transferred between the two layers. A thin-layer approximation is used to derive average equations. Special attention is paid to the drag friction terms that are responsible for the transfer of momentum between the two phases and for the appearance of an excess pore pressure with respect to the hydrostatic pressure. We present several numerical tests of two-phase granular flows over sloping topography that are compared to the results of the model proposed by {Pitman and Le} [2005]. In particular, we quantify the role of the fluid and compression/dilatation processes on granular flow velocity field and runout distance. F. Bouchut, E.D. Fernandez-Nieto, A. Mangeney, G. Narbona-Reina, A two-phase shallow debris flow model with energy balance, {ESAIM: Math. Modelling Num. Anal.}, 49, 101-140 (2015). F. Bouchut, E. D. Fernandez-Nieto, A. Mangeney, G. Narbona-Reina, A two-phase two-layer model for fluidized granular flows with dilatancy effects, {J. Fluid Mech.}, submitted (2016). R.M. Iverson, M. Logan, R.G. LaHusen, M. Berti, The perfect debris flow? Aggregated results from 28 large-scale experiments, {J. Geophys. Res.}, 115, F03005 (2010). R. Jackson, The Dynamics of Fluidized Particles, {Cambridges Monographs on Mechanics} (2000). E.B. Pitman, L. Le, A two-fluid model for avalanche and debris flows, {Phil.Trans. R. Soc. A}, 363, 1573-1601 (2005). S. Roux, F. Radjai, Texture-dependent rigid plastic behaviour, {Proceedings: Physics of Dry Granular Media}, September 1997. (eds. H. J. Herrmann et al.). Kluwer. Cargèse, France, 305-311 (1998).

Ultrafast Interlayer Electron Transfer in Incommensurate Transition Metal Dichalcogenide Homobilayers.

PubMed

Li, Yuanyuan; Cui, Qiannan; Ceballos, Frank; Lane, Samuel D; Qi, Zeming; Zhao, Hui

2017-11-08

Two-dimensional materials, such as graphene, transition metal dichalcogenides, and phosphorene, can be used to construct van der Waals multilayer structures. This approach has shown potentials to produce new materials that combine novel properties of the participating individual layers. One key requirement for effectively harnessing emergent properties of these materials is electronic connection of the involved atomic layers through efficient interlayer charge or energy transfer. Recently, ultrafast charge transfer on a time scale shorter than 100 fs has been observed in several van der Waals bilayer heterostructures formed by two different materials. However, information on the transfer between two atomic layers of the same type is rare. Because these homobilayers are essential elements in constructing multilayer structures with desired optoelectronic properties, efficient interlayer transfer is highly desired. Here we show that electron transfer between two monolayers of MoSe 2 occurs on a picosecond time scale. Even faster transfer was observed in homobilayers of WS 2 and WSe 2 . The samples were fabricated by manually stacking two exfoliated monolayer flakes. By adding a graphene layer as a fast carrier recombination channel for one of the two monolayers, the transfer of the photoexcited carriers from the populated to the drained monolayers was time-resolved by femtosecond transient absorption measurements. The observed efficient interlayer carrier transfer indicates that such homobilayers can be used in van der Waals multilayers to enhance their optical absorption without significantly compromising the interlayer transport performance. Our results also provide valuable information for understanding interlayer charge transfer in heterostructures.

Tunable Interfacial Thermal Conductance by Molecular Dynamics

NASA Astrophysics Data System (ADS)

Shen, Meng

We study the mechanism of tunable heat transfer through interfaces between solids using a combination of non-equilibrium molecular dynamics simulation (NEMD), vibrational mode analysis and wave packet simulation. We investigate how heat transfer through interfaces is affected by factors including pressure, interfacial modulus, contact area and interfacial layer thickness, with an overreaching goal of developing fundamental knowledge that will allow one to tailor thermal properties of interfacial materials. The role of pressure and interfacial stiffness is unraveled by our studies on an epitaxial interface between two Lennard-Jones (LJ) crystals. The interfacial stiffness is varied by two different methods: (i) indirectly by applying pressure which due to anharmonic nature of bonding, increases interfacial stiffness, and (ii) directly by changing the interfacial bonding strength by varying the depth of the potential well of the LJ potential. When the interfacial bonding strength is low, quantitatively similar behavior to pressure tuning is observed when the interfacial thermal conductance is increased by directly varying the potential-well depth parameter of the LJ potential. By contrast, when the interfacial bonding strength is high, thermal conductance is almost pressure independent, and even slightly decreases with increasing pressure. This decrease can be explained by the change in overlap between the vibrational densities of states of the two crystalline materials. The role of contact area is studied by modeling structures comprised of Van der Waals junctions between single-walled nanotubes (SWCNT). Interfacial thermal conductance between SWCNTs is obtained from NEMD simulation as a function of crossing angle. In this case the junction conductance per unit area is essentially a constant. By contrast, interfacial thermal conductance between multiwalled carbon nanotubes (MWCNTs) is shown to increase with diameter of the nanotubes by recent experimental studies [1]. To elucidate this behavior we studied a simplified model comprised of an interface between two stacks of graphene ribbons to mimic the contact between multiwalled nanotubes. Our results, in agreement with experiment, show that the interfacial thermal conductance indeed increases with the number of graphene layers, corresponding to larger diameter and larger number of walls in MWCNT. The role of interfacial layer thickness is investigated by modeling a system of a few layers of graphene sandwiched between two silicon slabs. We show, by wave packet simulation and by theoretical calculation of a spring-mass model, that the transmission coefficient of individual vibrational modes is strongly dependent on the frequency and the number of graphene layers due to coherent interference effects; by contrast, the interfacial thermal conductance obtained in NEMD simulation, which represents an integral over all phonons, is essentially independent of the number of graphene layers, in agreement with recent experiments. Furthermore, when we heat one atomic layer of graphene directly, the effective interfacial conductance associated with heat dissipation to the silicon substrate is very small. We attribute this to the resistance associated with heat transfer between high and low frequency phonon modes within graphene. Finally, we also replaced graphene layers by a few WSe2 sheets and observed that interfacial thermal resistance of a Si/n-WSe2/Si structure increases linearly with interface thickness at least for 1 < n <= 20, indicating diffusive heat transfer mechanism, in contrast to ballistic behavior of a few graphene layers. The corresponding thermal conductivity (0.048 W m-1 K-1) of a few WSe2 layers is rather small. By comparing phonon dispersion of graphene layers and WSe2 sheets, we attribute the diffusive behavior of a few WSe2 sheets to abundant optical phonons at low and medium frequencies leading to very short mean free path. Our computational studies of effects of pressure and structural properties on interfacial thermal conductance provide fundamental insights for tunable heat transfer in nanostructures. [1] Professor D. Y. Li from University of Vanderbilt, private communication (Nov. 14, 2011).

Field-Scale Hydraulic Conductivity (K) and Mass Transfer at the MADE Site in Columbus, Mississippi: A Review and Continuing Studies

NASA Astrophysics Data System (ADS)

Molz, F. J.; Guan, J.; Liu, H.; Zheng, C.

2005-12-01

During the late eighties and early nineties, several natural gradient tracer tests were conducted in a shallow unconfined fluvial aquifer at Columbus Air Force Base in Mississippi. The aquifer matrix was highly heterogeneous (natural log(K) variance of about 4.5) and consisted of poorly-sorted to well-sorted layered sandy gravel to gravely sand, with variable silt and clay content (Boggs et al., 1993). Prior to performing the tracer tests, the aquifer was characterized extensively using a borehole flow-meter. The resulting tracer plumes were highly elongated with dilute leading edges in the down-gradient direction, and transport appeared to be advection-dominated. Although there is still some controversy, reasonably successful simulations of the MADE tracer data have settled on an approximate dual porosity conceptualization of the aquifer matrix. Throughout the aquifer, high K zones (mobile porosity) are visualized as being in contact with low K zones (immobile porosity), with mass transfer between the zones governed by an effective mass transfer coefficient B. Such a transfer coefficient is analogous to the matrix diffusion coefficient Dm used to simulate transport in fractured rock with diffusion into the rock matrix (Foster, 1975). Recently, experiments and geometrically-based reasoning have been presented, implying that the effective Dm, like dispersivity, increases with travel distance (Liu et al., 2004; Zhou et al., 2005). Conversely, other studies based on multiple rate mass transfer between mobile and immobile porosities in granular media (Haggerty et al., 2004) have indicated that B will decrease with travel distance. Thus in geometrically complex granular media, like those at the MADE site, two opposing effects may be present. To further study this question, new 3-D simulations of tritium transport are being performed using flow-meter K data and the measured tritium concentrations at selected times. Results to date indicate that B generally decreases with scale, but changes will depend on the details of how the flow and mass transfer process at the MADE site is conceptualized. For example, did the tritium tracer injected initially all enter the mobile porosity, as commonly assumed, or was a significant portion of it forced into the immobile porosity? Was fluid in the immobile porosity essentially non-moving relative to mobile fluid, or did both fluid classes move significantly down-gradient. Alternatively, was tracer simply injected into an overall low K region, from which it slowly leaked out during the course of the 328 day experiment? Simulation results from different scenarios will be presented and implications discussed concerning the detailed scale-dependence of B at the MADE Site.

Performance of the cometary experiment MUPUS on the body Earth

NASA Astrophysics Data System (ADS)

Marczewski, W.; Usowicz, B.; Schröer, K.; Seiferlin, K.; Spohn, T.

2003-04-01

Thermal experiment MUPUS for the Rosetta mission was extensively experience in field and laboratory conditions to predict its performance under physical processes available on the Earth. The goal was not guessing a cometary material in the ground but available behavior of thermal sensor responses monitoring mass and energy transfer. The processes expected on a comet are different in composition and environmental from those met on the Earth but basically similar in physics. Nature of energy powering the processes is also essentially the same - solar radiation. Several simple laboratory experiments with freezing and thawing with water ice, with mixture of water and oil and water layers strongly diverged by salinity revealed capability of recognition layered structure of the medium under test. More over effects of slow convection and latent heat related to the layers are also observed well. Cometary environment without atmosphere makes process of sublimation dominant. Open air conditions on the Earth may also offer a change of state in matter but between different phases. Learning temperature gradient in snow layers under thawing show that effects stimulated by a cause of daily cycling may be detected thermally. Results from investigations in snow made on Spitzbergen are good proofs on capability of the method. Relevance of thermal effects to heat powered processes of mass transport in the matter of ground is meaningful for the cometary experiment of MUPUS and for Earth sciences much concerned on water, gas and solid matter transport in the terrestrial ground. Results leading to energy balance studied on the Earth surface may be interesting also for the experiment on the comet and are to be discussed.

Heat Transfer at the Reattachment Zone of Separated Laminar Boundary Layers

NASA Technical Reports Server (NTRS)

Chung, Paul M.; Viegas, John R.

1961-01-01

The flow and heat transfer are analyzed at the reattachment zone of two-dimensional separated laminar boundary layers. The fluid is considered to be flowing normal to the wall at reattachment. An approximate expression is derived for the heat transfer in the reattachment region and a calculated value is compared with an experimental measurement.

Predictive capabilities of series solutions for laminar free convection boundary layer heat transfer

NASA Technical Reports Server (NTRS)

Lin, F. N.; Chao, B. T.

1978-01-01

Various types of series solutions for predicting laminar, free-convection boundary-layer heat transfer over both isothermal and nonisothermal boundaries are reviewed. The methods include finite difference, Merk series, Blasius series, and Goertler series. Comparative results are presented for heat transfer over an isothermal, horizontal, elliptical cylinder in both slender and blunt configurations.

Photoinduced charge-transfer materials for nonlinear optical applications

DOEpatents

McBranch, Duncan W.

2006-10-24

A method using polyelectrolyte self-assembly for preparing multi-layered organic molecular materials having individual layers which exhibit ultrafast electron and/or energy transfer in a controlled direction occurring over the entire structure. Using a high molecular weight, water-soluble, anionic form of poly-phenylene vinylene, self-assembled films can be formed which show high photoluminescence quantum efficiency (QE). The highest emission QE is achieved using poly(propylene-imine) (PPI) dendrimers as cationic binders. Self-quenching of the luminescence is observed as the solid polymer film thickness is increased and can be reversed by inserting additional spacer layers of transparent polyelectrolytes between each active conjugated layer, such that the QE grows with thickness. A red shift of the luminescence is also observed as additional PPV layers are added. This effect persists as self-quenching is eliminated. Charge transfer superlattices can be formed by additionally incorporating C.sub.60 acceptor layers.

Diffusion of One-Dimensional Crystals in Channels of Single-Walled Carbon Nanotubes

NASA Astrophysics Data System (ADS)

Zhigalina, V. G.; Kumskov, A. S.; Falaleev, N. S.; Vasiliev, A. L.; Kiselev, N. A.

2018-05-01

The transport of one-dimensional CuI crystals in channels of single-walled carbon nanotubes (SWCNTs) has been studied by high resolution electron microscopy. The diffusion kinetics has been investigated by counting the number of CuI atoms escaping from the nanotube channel. The diffusivity is calculated to be 6.8 × 10-21 m2/s, which corresponds to an activation-barrier height of 1 eV/atom. A comparison with the theoretically estimated height of the energy barrier for molecular transport through a graphene layer is indicative of mass transfer through vacancy defects in graphene.

Numerical simulation of the alloying process during impulse induction heating of the metal substrate

NASA Astrophysics Data System (ADS)

Popov, V. N.

2017-10-01

2D numerical modeling of the processes during the alloying of the substrate surface metal layer is carried out. Heating, phase transition, heat and mass transfer in the molten metal, solidification of the melt are considered with the aid the proposed mathematical model. Under study is the applicability of the high-frequency electromagnetic field impulse for metal heating and melting. The distribution of the electromagnetic energy in the metal is described by empirical formulas. According to the results of numerical experiments, the flow structure in the melt and distribution of the alloying substances is evaluated.

A model for dispersion from area sources in convective turbulence. [for air pollution

NASA Technical Reports Server (NTRS)

Crane, G.; Panofsky, H. A.; Zeman, O.

1977-01-01

Four independent estimates of the vertical distribution of the eddy coefficient for dispersion of a passive contaminant from an extensive area source in a convective layer have been presented. The estimates were based on the following methods: (1) a second-order closure prediction, (2) field data of pollutant concentrations over Los Angeles, (3) lab measurements of particle dispersion, and (4) assumption of equality between momentum and mass transfer coefficients in the free convective limit. It is suggested that K-values estimated both from second-order closure theory and from Los Angeles measurements are systematically underestimated.

Effect of Mass Proportion of Municipal Solid Waste Incinerator Bottom Ash Layer to Municipal Solid Waste Layer on the Cu and Zn Discharge from Landfill

PubMed Central

Kong, Qingna; Qiu, Zhanhong; Shen, Dongsheng

2016-01-01

Municipal solid waste incinerator (MSWI) bottom ash is often used as the protection layer for the geomembrane and intermediate layer in the landfill. In this study, three sets of simulated landfills with different mass proportion of MSWI bottom ash layer to municipal solid waste (MSW) layer were operated. Cu and Zn concentrations in the leachates and MSW were monitored to investigate the effect of MSWI bottom ash layer on the Cu and Zn discharge from the landfill. The results showed that the Zn discharge was dependent on the mass proportion of MSWI bottom ash layer. The pH of landfill was not notably increased when the mass proportion of MSWI bottom ash layer to MSW layer was 1 : 9, resulting in the enhancement of the Zn discharge. However, Zn discharge was mitigated when the mass proportion was 2 : 8, as the pH of landfill was notably promoted. The discharge of Cu was not dependent on the mass proportion, due to the great affinity of Cu to organic matter. Moreover, Cu and Zn contents of the sub-MSW layer increased due to the MSWI bottom ash layer. Therefore, the MSWI bottom ash layer can increase the potential environmental threat of the landfill. PMID:28044139

Mass and heat transfer in crushed oil shale

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carley, J.F.; Straub, J.S.; Ott, L.L.

1984-04-01

Heat and mass transfer between gases and oil-shale particles are both important for all proposed retorting processes. Past studies of transfer in packed beds, which have disagreed substantially in their results, have nearly all been done with beds of regular particles of uniform size, whereas oil-shale retorting involves particles of diverse shapes and widely ranging sizes. To resolve these questions, we have made 349 runs in which we measured mass-transfer rates from naphthalene particles of diverse shapes buried in packed beds through which air was passed at room temperature. This technique permits calculation of the mass-transfer coefficient for each activemore » particle in the bed rather than, as in most past studies, for the bed as a whole. The data were analyzed in two ways: (1) by the traditional correlation of Colburn j/sub D/ vs Reynolds number and (2) by multiple regression of the mass-transfer coefficient on air rate, traditional correlation of Colburn j/sub D/ vs Reynolds number and (3) by multiple regression of the mass-transfer coefficient on air rate, sizes of active and inert particles, void fraction, and temperature. Principal findings are: (1) local Reynolds number should be based on active particle size rather than average size for the bed; (2) no appreciable differences were seen between shallow beds and deep ones; (3) mass transfer was 26% faster for spheres and lozenges buried in shale than for all-sphere beds; (4) orientation of lozenges in shale beds has little effect on mass-transfer rate; (5) a useful summarizing equation for either mass or heat transfer in shale beds is log j.epsilon = -.0747 - .6344 log Re + .0592 log/sup 2/Re where j = either j/sub D/ or j/sub H/, the Chilton-Colburn j-factors for mass and heat transfer, Re = the Reynolds number defined for packed beds, and epsilon = the void fraction in the bed. 12 references, 15 figures.« less

Electrochemical Impedance Spectroscopy for Real-Time Detection of Lipid Membrane Damage Based on a Porous Self-Assembly Monolayer Support.

PubMed

Zhang, Meng; Zhai, Qingyu; Wan, Liping; Chen, Li; Peng, Yu; Deng, Chunyan; Xiang, Juan; Yan, Jiawei

2018-06-19

Layer-by-layer dissolution and permeable pore formation are two typical membrane damage pathways, which induce membrane function disorder and result in serious disease, such as Alzheimer's disease, Keshan disease, Sickle-cell disease, and so on. To effectively distinguish and sensitively monitor these two typical membrane damage pathways, a facile electrochemical impedance strategy was developed on a porous self-assembly monolayer (pSAM) supported bilayer lipid membrane (BLM). The pSAM was prepared by selectively electrochemical reductive desorption of the mercaptopropionic acid in a mixed mercaptopropionic acid/11-mercaptoundecanoic acid self-assembled monolayer, which created plenty of nanopores with tens of nanometers in diameter and several nanometers in height (defined as inner-pores). The ultralow aspect ratio of the inner-pores was advantageous to the mass transfer of electrochemical probe [Fe(CN) 6 ] 3-/4- , simplifying the equivalent electric circuit for electrochemical impedance spectroscopy analysis at the electrode/membrane interface. [Fe(CN) 6 ] 3-/4- transferring from the bulk solution into the inner-pore induce significant changes of the interfacial impedance properties, improving the detection sensitivity. Based on these, the different membrane damage pathways were effectively distinguished and sensitively monitored with the normalized resistance-capacitance changes of inner-pore-related parameters including the electrolyte resistance within the pore length ( R pore ) and the metal/inner-pore interfacial capacitance ( C pore ) and the charge-transfer resistance ( R ct-in ) at the metal/inner-pore interface.

Using a hybrid model to predict solute transfer from initially saturated soil into surface runoff with controlled drainage water.

PubMed

Tong, Juxiu; Hu, Bill X; Yang, Jinzhong; Zhu, Yan

2016-06-01

The mixing layer theory is not suitable for predicting solute transfer from initially saturated soil to surface runoff water under controlled drainage conditions. By coupling the mixing layer theory model with the numerical model Hydrus-1D, a hybrid solute transfer model has been proposed to predict soil solute transfer from an initially saturated soil into surface water, under controlled drainage water conditions. The model can also consider the increasing ponding water conditions on soil surface before surface runoff. The data of solute concentration in surface runoff and drainage water from a sand experiment is used as the reference experiment. The parameters for the water flow and solute transfer model and mixing layer depth under controlled drainage water condition are identified. Based on these identified parameters, the model is applied to another initially saturated sand experiment with constant and time-increasing mixing layer depth after surface runoff, under the controlled drainage water condition with lower drainage height at the bottom. The simulation results agree well with the observed data. Study results suggest that the hybrid model can accurately simulate the solute transfer from initially saturated soil into surface runoff under controlled drainage water condition. And it has been found that the prediction with increasing mixing layer depth is better than that with the constant one in the experiment with lower drainage condition. Since lower drainage condition and deeper ponded water depth result in later runoff start time, more solute sources in the mixing layer are needed for the surface water, and larger change rate results in the increasing mixing layer depth.

Hybrid transfer-matrix FDTD method for layered periodic structures.

PubMed

Deinega, Alexei; Belousov, Sergei; Valuev, Ilya

2009-03-15

A hybrid transfer-matrix finite-difference time-domain (FDTD) method is proposed for modeling the optical properties of finite-width planar periodic structures. This method can also be applied for calculation of the photonic bands in infinite photonic crystals. We describe the procedure of evaluating the transfer-matrix elements by a special numerical FDTD simulation. The accuracy of the new method is tested by comparing computed transmission spectra of a 32-layered photonic crystal composed of spherical or ellipsoidal scatterers with the results of direct FDTD and layer-multiple-scattering calculations.

Digital Transfer Growth of Patterned 2D Metal Chalcogenides by Confined Nanoparticle Evaporation

DOE PAGES

Mahjouri-Samani, Masoud; Tian, Mengkun; Wang, Kai; ...

2014-10-19

Developing methods for the facile synthesis of two-dimensional (2D) metal chalcogenides and other layered materials is crucial for emerging applications in functional devices. Controlling the stoichiometry, number of the layers, crystallite size, growth location, and areal uniformity is challenging in conventional vapor phase synthesis. Here, we demonstrate a new route to control these parameters in the growth of metal chalcogenide (GaSe) and dichalcogenide (MoSe 2) 2D crystals by precisely defining the mass and location of the source materials in a confined transfer growth system. A uniform and precise amount of stoichiometric nanoparticles are first synthesized and deposited onto a substratemore » by pulsed laser deposition (PLD) at room temperature. This source substrate is then covered with a receiver substrate to form a confined vapor transport growth (VTG) system. By simply heating the source substrate in an inert background gas, a natural temperature gradient is formed that evaporates the confined nanoparticles to grow large, crystalline 2D nanosheets on the cooler receiver substrate, the temperature of which is controlled by the background gas pressure. Large monolayer crystalline domains (~ 100 m lateral sizes) of GaSe and MoSe 2 are demonstrated, as well as continuous monolayer films through the deposition of additional precursor materials. This novel PLD-VTG synthesis and processing method offers a unique approach for the controlled growth of large-area, metal chalcogenides with a controlled number of layers in patterned growth locations for optoelectronics and energy related applications.« less

Exercising Spatiotemporal Control of Cell Attachment with Optically Transparent Microelectrodes

PubMed Central

Shah, Sunny S.; Lee, Ji Youn; Verkhoturov, Stanislav; Tuleuova, Nazgul; Schweikert, Emile A.; Ramanculov, Erlan; Revzin, Alexander

2013-01-01

This paper describes a novel approach of controlling cell-surface interactions through an electrochemical “switching” of biointerfacial properties of optically transparent microelectrodes. The indium tin oxide (ITO) microelectrodes, fabricated on glass substrates, were modified with poly(ethylene glycol) (PEG) silane to make glass and ITO regions resistant to protein and cell adhesion. Cyclic voltammetry, with potassium ferricyanide serving as a redox reporter molecule, was used to monitor electron transfer across the electrolyte–ITO interface. PEG silane modification of ITO correlated with diminished electron transfer, judged by the disappearance of ferricyanide redox activity. Importantly, application of reductive potential (−1.4 V vs Ag/AgCl reference) corresponded with reappearance of typical ferricyanide redox peaks, thus pointing to desorption of an insulating PEG silane layer. Time-of-flight secondary ion mass spectrometry (ToF-SIMS) characterization of the silanized ITO surfaces after electrical stimulation indicated complete removal of the silane layer. Significantly, electrical stimulation allowed to “switch” chosen electrodes from nonfouling to protein-adhesive while leaving other ITO and glass regions protected by a nonfouling PEG silane layer. The spatial and temporal control of biointerfacial properties afforded by our approach was utilized to micropattern proteins and cells and to construct micropatterned co-cultures. In the future, control of the biointerfacial properties afforded by this novel approach may allow the organization of multiple cell types into precise geometric configurations in order to create better in vitro mimics of cellular complexity of the native tissues. PMID:18512875

Electric propulsion for geostationary orbit insertion

NASA Technical Reports Server (NTRS)

Oleson, Steven R.; Curran, Francis M.; Myers, Roger M.

1995-01-01

Solar electric propulsion (SEP) technology is already being used for geostationary satellite stationkeeping to increase payload mass. By using this same technology to perform part of the orbit transfer additional increases in payload mass can be achieved. Advanced chemical and N2H4 arcjet systems are used to increase the payload mass by performing stationkeeping and part of the orbit transfer. Four mission options are analyzed which show the impact of either sharing the orbit transfer between chemical and SEP systems or having either complete the transfer alone. Results show that for an Atlas 2AS payload increases in net mass (geostationary satellite mass less wet propulsion system mass) of up to 100 kg can be achieved using advanced chemical for the transfer and advanced N2H4 arcjets for stationkeeping. An additional 100 kg can be added using advanced N2H4 arcjets for part of a 40 day orbit transfer.

Remote direct memory access over datagrams

DOEpatents

Grant, Ryan Eric; Rashti, Mohammad Javad; Balaji, Pavan; Afsahi, Ahmad

2014-12-02

A communication stack for providing remote direct memory access (RDMA) over a datagram network is disclosed. The communication stack has a user level interface configured to accept datagram related input and communicate with an RDMA enabled network interface card (NIC) via an NIC driver. The communication stack also has an RDMA protocol layer configured to supply one or more data transfer primitives for the datagram related input of the user level. The communication stack further has a direct data placement (DDP) layer configured to transfer the datagram related input from a user storage to a transport layer based on the one or more data transfer primitives by way of a lower layer protocol (LLP) over the datagram network.

G-Jitter Induced Magnetohydrodynamics Flow of Nanofluid with Constant Convective Thermal and Solutal Boundary Conditions

PubMed Central

Uddin, Mohammed J.; Khan, Waqar A.; Ismail, Ahmad Izani Md.

2015-01-01

Taking into account the effect of constant convective thermal and mass boundary conditions, we present numerical solution of the 2-D laminar g-jitter mixed convective boundary layer flow of water-based nanofluids. The governing transport equations are converted into non-similar equations using suitable transformations, before being solved numerically by an implicit finite difference method with quasi-linearization technique. The skin friction decreases with time, buoyancy ratio, and thermophoresis parameters while it increases with frequency, mixed convection and Brownian motion parameters. Heat transfer rate decreases with time, Brownian motion, thermophoresis and diffusion-convection parameters while it increases with the Reynolds number, frequency, mixed convection, buoyancy ratio and conduction-convection parameters. Mass transfer rate decreases with time, frequency, thermophoresis, conduction-convection parameters while it increases with mixed convection, buoyancy ratio, diffusion-convection and Brownian motion parameters. To the best of our knowledge, this is the first paper on this topic and hence the results are new. We believe that the results will be useful in designing and operating thermal fluids systems for space materials processing. Special cases of the results have been compared with published results and an excellent agreement is found. PMID:25933066

Nonequilibrium adiabatic molecular dynamics simulations of methane clathrate hydrate decomposition

NASA Astrophysics Data System (ADS)

Alavi, Saman; Ripmeester, J. A.

2010-04-01

Nonequilibrium, constant energy, constant volume (NVE) molecular dynamics simulations are used to study the decomposition of methane clathrate hydrate in contact with water. Under adiabatic conditions, the rate of methane clathrate decomposition is affected by heat and mass transfer arising from the breakup of the clathrate hydrate framework and release of the methane gas at the solid-liquid interface and diffusion of methane through water. We observe that temperature gradients are established between the clathrate and solution phases as a result of the endothermic clathrate decomposition process and this factor must be considered when modeling the decomposition process. Additionally we observe that clathrate decomposition does not occur gradually with breakup of individual cages, but rather in a concerted fashion with rows of structure I cages parallel to the interface decomposing simultaneously. Due to the concerted breakup of layers of the hydrate, large amounts of methane gas are released near the surface which can form bubbles that will greatly affect the rate of mass transfer near the surface of the clathrate phase. The effects of these phenomena on the rate of methane hydrate decomposition are determined and implications on hydrate dissociation in natural methane hydrate reservoirs are discussed.

Scrap melting model for steel converter founded on interfacial solid/liquid phenomena

NASA Astrophysics Data System (ADS)

Kruskopf, Ari; Holappa, Lauri

2017-12-01

The primary goal in steel converter operation is the removal of carbon from the hot metal. This is achieved by blowing oxygen into the melt. The oxidation of carbon produces a lot of heat. To avoid too high temperatures in the melt cold scrap (recycled steel) is charged into the converter. The melting rate is affected by heat and carbon mass transfer. A process model for steel converter is in development. This model is divided into several modules, which are fluid dynamics, heat- and mass-transfer, scrap melting and chemical reactions. This article focuses on the development of the scrap melting module. A numerical model for calculating temperature and carbon concentration in the melt is presented. The melt model is connected with the solid scrap model via solid/liquid interface. The interface model can take into account solidification of iron melt, melting of solidified layer, a situation without such phase changes, and scrap melting. The aim is to predict the melting rate of the scrap including the properties of the hot metal. The model is tested by calculating the melting rates for different scrap thicknesses. All of the stages in the interface model were taking place in the test calculations.

Nonequilibrium adiabatic molecular dynamics simulations of methane clathrate hydrate decomposition.

PubMed

Alavi, Saman; Ripmeester, J A

2010-04-14

Nonequilibrium, constant energy, constant volume (NVE) molecular dynamics simulations are used to study the decomposition of methane clathrate hydrate in contact with water. Under adiabatic conditions, the rate of methane clathrate decomposition is affected by heat and mass transfer arising from the breakup of the clathrate hydrate framework and release of the methane gas at the solid-liquid interface and diffusion of methane through water. We observe that temperature gradients are established between the clathrate and solution phases as a result of the endothermic clathrate decomposition process and this factor must be considered when modeling the decomposition process. Additionally we observe that clathrate decomposition does not occur gradually with breakup of individual cages, but rather in a concerted fashion with rows of structure I cages parallel to the interface decomposing simultaneously. Due to the concerted breakup of layers of the hydrate, large amounts of methane gas are released near the surface which can form bubbles that will greatly affect the rate of mass transfer near the surface of the clathrate phase. The effects of these phenomena on the rate of methane hydrate decomposition are determined and implications on hydrate dissociation in natural methane hydrate reservoirs are discussed.

Condensation heat transfer and pressure drop of R-410A in a 7.0 mm O.D. microfin tube at low mass fluxes

NASA Astrophysics Data System (ADS)

Kim, Nae-Hyun

2016-12-01

R-410A condensation heat transfer and pressure drop data are provided for a 7.0 mm O.D. microfin tube at low mass fluxes (50-250 kg/m2 s). The heat transfer coefficient of the microfin tube shows a minimum behavior with the mass flux. At a low mass flux, where flow pattern is stratified, condensation induced by surface tension by microfins overwhelms condensation induced by shear, and the heat transfer coefficient decreases as mass flux increases. At a high mass flux, where flow pattern is annular, condensation induced by shear governs the heat transfer, and the heat transfer coefficient increases as mass flux increases. The pressure drop of the microfin tube is larger than that of the smooth tube at the annular flow regime. On the contrary, the pressure drop of the smooth tube is larger than that of the microfin tube at the stratified flow regime.

Extreme Events on a Low-Gradient River and Delta: Evidence for Sediment Mass Movements on the Subaqueous Delta and a Mechanism for Creating Hyperpycnal Flow onto the Shelf

NASA Astrophysics Data System (ADS)

Dellapenna, T. M.; Carlin, J. A.; Williams, J. R.

2016-02-01

The Brazos River empties into the Gulf of Mexico (GOM) forming a wave-influenced, muddy, subaqueous delta (SAD). Recent research in the estuarine reach of the river and on the SAD, however, found evidence for significant mass wasting of the delta-front and potential evidence of hyperpycnal flow, a processes typically associated with higher gradient and higher sediment yield rivers. The study used high-resolution geophysics on the SAD and water-column profiling in the lower river to investigate the transfer to and fate of fluvial sediment on the shelf. The SAD side scan mosaic combined with core data reveal that the eastern portion was dominated by exposed relict, consolidated sediment; an erosional scarp along the upper shoreface; and a thinning of the Holocene strata immediately downslope of the scarp. Holocene strata thickness increases into deeper water. These features suggest sediment mass wasting on the delta front. After rapidly prograding during the early and mid 20th century, reductions in sediment load due anthropogenic influences, and a shift in the primary depocenter lead to erosion on these abandoned portions of the delta. During an elevated fluvial discharge event, a >1 m thick fluid mud layer was found along a 6 km span of the river 2 km upstream from the mouth. The river's salt wedge was shown to inhibit sediment export from the river to the GOM, and facilitate deposition of mud in the lower river. We believe that the mud layer in the lower river builds during moderate and low discharge periods and remobilized during increased discharge, potentially resulting in hyperpyncnal flow to the shelf. We observed suspended sediment concentrations up to 100 g/l in the fluid mud layer during this event. While our observations did not capture the transition from fluid mud to hyperpycnal flow, we believe that with persistent increased discharge the fluid mud layer could transition to hyperpycnal flow.

Geochemical cycling, mass balance, and Earth’s dynamic structure (Invited)

NASA Astrophysics Data System (ADS)

Allegre, C. J.

2009-12-01

The use of radiogenic tracers is now established as one of the standard methods (together with seismic tomography) to constrain Earth models. One of the advantages of radiogenic tracers is that they constrain not only present day structures, but also their historical evolution since the earliest time. A mandatory condition is to use not only one but all of the available isotopic systems, with their diverse cycling properties and different radioactive half-lives. Mass balances calculations are the basic tool which allows one to use quantitatively the various tracers. However, the inverse method approach, when applied to mass balance, is strongly non-linear, particularly for tracers with intermediate to short half lives. 142Nd, 82W, and 129Xe allows one to define a consistent model for the Present and past evolutions. Results point to a 3-layer model for the present mantle: an upper mantle with two layers separated by the 450 km discontinuity, and a lower mantle below the 670 km discontinuity. These layers all convect independently though none of them is fully isolated. They exchange matter and energy, not necessarily through the same process. For instance, most hotspots (though not all of them!) are boundary layer instabilities generated at the 670 km discontinuity, but there is important heat transfer from the lower mantle through megablobs. Recent results on the Hadean period are in agreement with core-mantle- atmosphere differentiation at 4444 My. The early crust was mostly anorthositic but has been recycled into the upper mantle within the first billion years. Formation of granitic continents started at 4300 My. 80% of their material was already present on the surface as acidic rocks by 2500 My. The reworking process involved in continental development increased continuously with time and today is the dominant process. Continents are now in a stage of steady state, with general addition of mantle and subducted continental material.

In-Plane Channel-Structured Catalyst Layer for Polymer Electrolyte Membrane Fuel Cells.

PubMed

Lee, Dong-Hyun; Jo, Wonhee; Yuk, Seongmin; Choi, Jaeho; Choi, Sungyu; Doo, Gisu; Lee, Dong Wook; Kim, Hee-Tak

2018-02-07

In this study, we present a novel catalyst layer (CL) with in-plane flow channels to enhance the mass transports in polymer electrolyte membrane fuel cells. The CL with in-plane channels on its surface is fabricated by coating a CL slurry onto a surface-treated substrate with the inverse line pattern and transferring the dried CL from the substrate to a membrane. The membrane electrode assembly with the in-plane channel-patterned CL has superior power performances in high current densities compared with an unpatterned, flat CL, demonstrating a significant enhancement of the mass-transport property by the in-plane channels carved in the CL. The performance gain is more pronounced when the channel direction is perpendicular to the flow field direction, indicating that the in-plane channels increase the utilization of the CL under the rib area. An oxygen-transport resistance analysis shows that both molecular and Knudsen diffusion can be facilitated with the introduction of the in-plane channels. The direct CL patterning technique provides a platform for the fabrication of advanced CL structures with a high structural fidelity and design flexibility and a rational guideline for designing high-performance CLs.

Influence of indoor environmental factors on mass transfer parameters and concentrations of semi-volatile organic compounds.

PubMed

Wei, Wenjuan; Mandin, Corinne; Ramalho, Olivier

2018-03-01

Semi-volatile organic compounds (SVOCs) in indoor environments can partition among the gas phase, airborne particles, settled dust, and available surfaces. The mass transfer parameters of SVOCs, such as the mass transfer coefficient and the partition coefficient, are influenced by indoor environmental factors. Subsequently, indoor SVOC concentrations and thus occupant exposure can vary depending on environmental factors. In this review, the influence of six environmental factors, i.e., indoor temperature, humidity, ventilation, airborne particle concentration, source loading factor, and reactive chemistry, on the mass transfer parameters and indoor concentrations of SVOCs was analyzed and tentatively quantified. The results show that all mass transfer parameters vary depending on environmental factors. These variations are mostly characterized by empirical equations, particularly for humidity. Theoretical calculations of these parameters based on mass transfer mechanisms are available only for the emission of SVOCs from source surfaces when airborne particles are not present. All mass transfer parameters depend on the temperature. Humidity influences the partition of SVOCs among different phases and is associated with phthalate hydrolysis. Ventilation has a combined effect with the airborne particle concentration on SVOC emission and their mass transfer among different phases. Indoor chemical reactions can produce or eliminate SVOCs slowly. To better model the dynamic SVOC concentration indoors, the present review suggests studying the combined effect of environmental factors in real indoor environments. Moreover, interactions between indoor environmental factors and human activities and their influence on SVOC mass transfer processes should be considered. Copyright © 2017 Elsevier Ltd. All rights reserved.

Investigation of a broadband coherent perfect absorber in a multi-layer structure by using the transfer matrix method

NASA Astrophysics Data System (ADS)

Na, Jihoon; Noh, Heeso

2018-01-01

We investigated a multi-layer structure for a broadband coherent perfect absorber (CPA). The transfer matrix method (TMM) is useful for analyzing the optical properties of structures and optimizing multi-layer structures. The broadband CPA strongly depends on the phase of the light traveling in one direction and the light reflected within the structure. The TMM simulation shows that the absorption bandwidth is increased by 95% in a multi-layer CPA compared to that in a single-layer CPA.

Probabilistic migration modelling focused on functional barrier efficiency and low migration concepts in support of risk assessment.

PubMed

Brandsch, Rainer

2017-10-01

Migration modelling provides reliable migration estimates from food-contact materials (FCM) to food or food simulants based on mass-transfer parameters like diffusion and partition coefficients related to individual materials. In most cases, mass-transfer parameters are not readily available from the literature and for this reason are estimated with a given uncertainty. Historically, uncertainty was accounted for by introducing upper limit concepts first, turning out to be of limited applicability due to highly overestimated migration results. Probabilistic migration modelling gives the possibility to consider uncertainty of the mass-transfer parameters as well as other model inputs. With respect to a functional barrier, the most important parameters among others are the diffusion properties of the functional barrier and its thickness. A software tool that accepts distribution as inputs and is capable of applying Monte Carlo methods, i.e., random sampling from the input distributions of the relevant parameters (i.e., diffusion coefficient and layer thickness), predicts migration results with related uncertainty and confidence intervals. The capabilities of probabilistic migration modelling are presented in the view of three case studies (1) sensitivity analysis, (2) functional barrier efficiency and (3) validation by experimental testing. Based on the predicted migration by probabilistic migration modelling and related exposure estimates, safety evaluation of new materials in the context of existing or new packaging concepts is possible. Identifying associated migration risk and potential safety concerns in the early stage of packaging development is possible. Furthermore, dedicated material selection exhibiting required functional barrier efficiency under application conditions becomes feasible. Validation of the migration risk assessment by probabilistic migration modelling through a minimum of dedicated experimental testing is strongly recommended.

Study of cyanide wastewater treatment by dispersion supported liquid membrane using trioctylamine and kerosene as liquid membrane.

PubMed

Li, Guo Ping; Xue, Juan Qin; Yu, Li Hua; Liu, Ni Na

2015-01-01

A certain amount of cyanide is present in wastewater of various industrial processes, such as wet extraction of gold, coal processing, electroplating and other industries. In this work, an experimental study regarding transport of cyanide through a dispersion supported liquid membrane was performed. A model was established to describe the reaction and transport of CN(I) in the supported liquid membrane and the mass transfer kinetics equations were deduced. Through mass transfer kinetic equation it was derived that, when the carrier concentration was under certain conditions, there was a linear relationship between the reciprocal of the permeability coefficient of CN(I) (1/Pc) and n-th power of the concentration of H+ (cnH+), and the parameters Δa(δa/da) and Δo(δ0/d0) could be obtained from the slope and intercept of the straight line. Then the diffusion coefficient do and the diffusion layer thickness δo of the phase interface between the feed phase and membrane phase could be calculated. Factors affecting migration of CN(I) were analyzed, and the stable removal rate of CN(I) was more than 90% with carrier concentration (%TOA) of 2%, feed phase pH of 4, initial CN(I) concentration of 30 mg/L, stirring time of 1 hour, volume ratio of membrane solution to NaOH solution of 2:1, strip phase concentration of 2 mol/L. The results showed that the overall mass transfer rate increased first and then decreased with an increase of TOA concentration, organic-to-strip volume ratio, and strip concentration. Furthermore, the transport percentage of CN(I) was increased, the stability of membrane was enhanced, and the lifetime of the membrane was extended.

Why Pulse If You Live in Turbulent Flow? Studying the Benefits of Pulsing Behavior in Xeniid Corals

NASA Astrophysics Data System (ADS)

Samson, J. E.; Khatri, S.; Holzman, R.; Shavit, U.; Miller, L.

2016-02-01

Pulsing behavior in benthic cnidarians increases local water flows and thus mass transfer (i.e. nutrient exchange) between organisms and environment. This increased mass transfer plays an especially important role in photosynthetic organisms by increasing the exchange rate of oxygen and carbon dioxide, allowing for increased metabolic rates. For organisms living mostly in the boundary layer of quiet water bodies, the benefits of pulsing to create a (feeding) current seem to be straightforward; the benefit of increased flow around the organism is larger than the cost of sustaining an energetically expensive behavior. Xeniid corals, however, are often found in turbulent flows, and it is unclear what the benefits of pulsing behavior are in an already well-mixed environment. Using lab experiments (particle image velocimetry or PIV), computational fluid dynamics simulations (immersed boundary method), and field data, we explore the reason(s) behind this paradoxical observation. 3D video recordings from pulsing corals in the lab and in the field were used to extract the kinematics of the pulsing motion. These kinematics served as input to create computational fluid dynamics simulations that allow us to further explore and compare fluid flows resulting from different situations (presence or absence of background flow around a coral colony, for example). The PIV data collected in the lab will serve to validate these simulations. Developing our computational models further will allow us to study the potential benefit of pulsing on mass transfer and to explore the advantage of collective pulsing behavior. Xeniid corals form colonies in which collective pulsing patterns can be observed. These patterns, however, have not yet been quantified and it is unclear how they arise, since cnidarians lack a centralized nervous system.

Layer-by-Layer Assembly of Glucose Oxidase on Carbon Nanotube Modified Electrodes.

PubMed

Suroviec, Alice H

2017-01-01

The use of enzymatically modified electrodes for the detection of glucose or other non-electrochemically active analytes is becoming increasingly common. Direct heterogeneous electron transfer to glucose oxidase has been shown to be kinetically difficult, which is why electron transfer mediators or indirect detection is usually used for monitoring glucose with electrochemical sensors. It has been found, however, that electrodes modified with single or multi-walled carbon nanotubes (CNTs) demonstrate fast heterogeneous electron transfer kinetics as compared to that found for traditional electrodes. Incorporating CNTs into the assembly of electrochemical glucose sensors, therefore, affords the possibility of facile electron transfer to glucose oxidase, and a more direct determination of glucose. This chapter describes the methods used to use CNTs in a layer-by-layer structure along with glucose oxidase to produce an enzymatically modified electrode with high turnover rates, increased stability and shelf-life.

Fabricating metal-oxide-semiconductor field-effect transistors on a polyethylene terephthalate substrate by applying low-temperature layer transfer of a single-crystalline silicon layer by meniscus force

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sakaike, Kohei; Akazawa, Muneki; Nakamura, Shogo

2013-12-02

A low-temperature local-layer technique for transferring a single-crystalline silicon (c-Si) film by using a meniscus force was proposed, and an n-channel metal-oxide-semiconductor field-effect transistor (MOSFET) was fabricated on polyethylene terephthalate (PET) substrate. It was demonstrated that it is possible to transfer and form c-Si films in the required shape at the required position on PET substrates at extremely low temperatures by utilizing a meniscus force. The proposed technique for layer transfer was applied for fabricating high-performance c-Si MOSFETs on a PET substrate. The fabricated MOSFET showed a high on/off ratio of more than 10{sup 8} and a high field-effect mobilitymore » of 609 cm{sup 2} V{sup −1} s{sup −1}.« less

Strain transfer analysis of optical fiber based sensors embedded in an asphalt pavement structure

NASA Astrophysics Data System (ADS)

Wang, Huaping; Xiang, Ping

2016-07-01

Asphalt pavement is vulnerable to random damage, such as cracking and rutting, which can be proactively identified by distributed optical fiber sensing technology. However, due to the material nature of optical fibers, a bare fiber is apt to be damaged during the construction process of pavements. Thus, a protective layer is needed for this application. Unfortunately, part of the strain of the host material is absorbed by the protective layer when transferring the strain to the sensing fiber. To account for the strain transfer error, in this paper a theoretical analysis of the strain transfer of a three-layered general model has been carried out by introducing Goodman’s hypothesis to describe the interfacial shear stress relationship. The model considers the viscoelastic behavior of the host material and protective layer. The effects of one crack in the host material and the sensing length on strain transfer relationship are been discussed. To validate the effectiveness of the strain transfer analysis, a flexible asphalt-mastic packaged distributed optical fiber sensor was designed and tested in a laboratory environment to monitor the distributed strain and appearance of cracks in an asphalt concrete beam at two different temperatures. The experimental results indicated that the developed strain transfer formula can significantly reduce the strain transfer error, and that the asphalt-mastic packaged optical fiber sensor can successfully monitor the distributed strain and identify local cracks.

Confined methane-water interfacial layers and thickness measurements using in situ Raman spectroscopy.

PubMed

Pinho, Bruno; Liu, Yukun; Rizkin, Benjamin; Hartman, Ryan L

2017-11-07

Gas-liquid interfaces broadly impact our planet, yet confined interfaces behave differently than unconfined ones. We report the role of tangential fluid motion in confined methane-water interfaces. The interfaces are created using microfluidics and investigated by in situ 1D, 2D and 3D Raman spectroscopy. The apparent CH 4 and H 2 O concentrations are reported for Reynolds numbers (Re), ranging from 0.17 to 8.55. Remarkably, the interfaces are comprised of distinct layers of thicknesses varying from 23 to 57 μm. We found that rarefaction, mixture, thin film, and shockwave layers together form the interfaces. The results indicate that the mixture layer thickness (δ) increases with Re (δ ∝ Re), and traditional transport theory for unconfined interfaces does not explain the confined interfaces. A comparison of our results with thin film theory of air-water interfaces (from mass transfer experiments in capillary microfluidics) supports that the hydrophobicity of CH 4 could decrease the strength of water-water interactions, resulting in larger interfacial thicknesses. Our findings help explain molecular transport in confined gas-liquid interfaces, which are common in a broad range of societal applications.

Modeling of Blast Furnace with Layered Cohesive Zone

NASA Astrophysics Data System (ADS)

Dong, X. F.; Yu, A. B.; Chew, S. J.; Zulli, P.

2010-04-01

An ironmaking blast furnace (BF) is a moving bed reactor involving counter-, co-, and cross-current flows of gas, powder, liquids, and solids, coupled with heat exchange and chemical reactions. The behavior of multiple phases directly affects the stability and productivity of the furnace. In the present study, a mathematical model is proposed to describe the behavior of fluid flow, heat and mass transfer, as well as chemical reactions in a BF, in which gas, solid, and liquid phases affect each other through interaction forces, and their flows are competing for the space available. Process variables that characterize the internal furnace state, such as reduction degree, reducing gas and burden concentrations, as well as gas and condensed phase temperatures, have been described quantitatively. In particular, different treatments of the cohesive zone (CZ), i.e., layered, isotropic, and anisotropic nonlayered, are discussed, and their influence on simulation results is compared. The results show that predicted fluid flow and thermochemical phenomena within and around the CZ and in the lower part of the BF are different for different treatments. The layered CZ treatment corresponds to the layered charging of burden and naturally can predict the CZ as a gas distributor and liquid generator.

Cryogenic Boil-Off Reduction System

NASA Astrophysics Data System (ADS)

Plachta, David W.; Guzik, Monica C.

2014-03-01

A computational model of the cryogenic boil-off reduction system being developed by NASA as part of the Cryogenic Propellant Storage and Transfer technology maturation project has been applied to a range of propellant storage tanks sizes for high-performing in-space cryogenic propulsion applications. This effort focuses on the scaling of multi-layer insulation (MLI), cryocoolers, broad area cooling shields, radiators, solar arrays, and tanks for liquid hydrogen propellant storage tanks ranging from 2 to 10 m in diameter. Component scaling equations were incorporated into the Cryogenic Analysis Tool, a spreadsheet-based tool used to perform system-level parametric studies. The primary addition to the evolution of this updated tool is the integration of a scaling method for reverse turbo-Brayton cycle cryocoolers, as well as the development and inclusion of Self-Supporting Multi-Layer Insulation. Mass, power, and sizing relationships are traded parametrically to establish the appropriate loiter period beyond which this boil-off reduction system application reduces mass. The projected benefit compares passive thermal control to active thermal control, where active thermal control is evaluated for reduced boil-off with a 90 K shield, zero boil-off with a single heat interception stage at the tank wall, and zero boil-off with a second interception stage at a 90 K shield. Parametric studies show a benefit over passive storage at loiter durations under one month, in addition to showing a benefit for two-stage zero boil-off in terms of reducing power and mass as compared to single stage zero boil-off. Furthermore, active cooling reduces the effect of varied multi-layer insulation performance, which, historically, has been shown to be significant.

Electric-field-enhanced nutrient consumption in dielectric biomaterials that contain anchorage-dependent cells.

PubMed

Belfiore, Laurence A; Floren, Michael L; Belfiore, Carol J

2012-02-01

This research contribution addresses electric-field stimulation of intra-tissue mass transfer and cell proliferation in viscoelastic biomaterials. The unsteady state reaction-diffusion equation is solved according to the von Kármán-Pohlhausen integral method of boundary layer analysis when nutrient consumption and tissue regeneration occur in response to harmonic electric potential differences across a parallel-plate capacitor in a dielectric-sandwich configuration. The partial differential mass balance with diffusion and electro-kinetic consumption contains the Damköhler (Λ(2)) and Deborah (De) numbers. Zero-field and electric-field-sensitive Damköhler numbers affect nutrient boundary layer growth. Diagonal elements of the 2nd-rank diffusion tensor are enhanced in the presence of weak electric fields, in agreement with the formalism of equilibrium and nonequilibrium thermodynamics. Induced dipole polarization density within viscoelastic biomaterials is calculated via the real and imaginary components of the complex dielectric constant, according to the Debye equation, to quantify electro-kinetic stimulation. Rates of nutrient consumption under zero-field conditions are described by third-order kinetics that include local mass densities of nutrients, oxygen, and attached cells. Thinner nutrient boundary layers are stabilized at shorter dimensionless diffusion times when the zero-field intra-tissue Damköhler number increases above its initial-condition-sensitive critical value [i.e., {Λ(2)(zero-field)}(critical)≥53, see Eq. (23)], such that the biomaterial core is starved of essential ingredients required for successful proliferation. When tissue regeneration occurs above the critical electric-field-sensitive intra-tissue Damköhler number, the electro-kinetic contribution to nutrient consumption cannot be neglected. The critical electric-field-sensitive intra-tissue Damköhler number is proportional to the Deborah number. Copyright © 2011 Elsevier B.V. All rights reserved.

Probability theory for 3-layer remote sensing radiative transfer model: univariate case.

PubMed

Ben-David, Avishai; Davidson, Charles E

2012-04-23

A probability model for a 3-layer radiative transfer model (foreground layer, cloud layer, background layer, and an external source at the end of line of sight) has been developed. The 3-layer model is fundamentally important as the primary physical model in passive infrared remote sensing. The probability model is described by the Johnson family of distributions that are used as a fit for theoretically computed moments of the radiative transfer model. From the Johnson family we use the SU distribution that can address a wide range of skewness and kurtosis values (in addition to addressing the first two moments, mean and variance). In the limit, SU can also describe lognormal and normal distributions. With the probability model one can evaluate the potential for detecting a target (vapor cloud layer), the probability of observing thermal contrast, and evaluate performance (receiver operating characteristics curves) in clutter-noise limited scenarios. This is (to our knowledge) the first probability model for the 3-layer remote sensing geometry that treats all parameters as random variables and includes higher-order statistics. © 2012 Optical Society of America

Room temperature rubbing for few-layer two-dimensional thin flakes directly on flexible polymer substrates

PubMed Central

Yu, Yan; Jiang, Shenglin; Zhou, Wenli; Miao, Xiangshui; Zeng, Yike; Zhang, Guangzu; Liu, Sisi

2013-01-01

The functional layers of few-layer two-dimensional (2-D) thin flakes on flexible polymers for stretchable applications have attracted much interest. However, most fabrication methods are “indirect” processes that require transfer steps. Moreover, previously reported “transfer-free” methods are only suitable for graphene and not for other few-layer 2-D thin flakes. Here, a friction based room temperature rubbing method is proposed for fabricating different types of few-layer 2-D thin flakes (graphene, hexagonal boron nitride (h-BN), molybdenum disulphide (MoS2), and tungsten disulphide (WS2)) on flexible polymer substrates. Commercial 2-D raw materials (graphite, h-BN, MoS2, and WS2) that contain thousands of atom layers were used. After several minutes, different types of few-layer 2-D thin flakes were fabricated directly on the flexible polymer substrates by rubbing procedures at room temperature and without any transfer step. These few-layer 2-D thin flakes strongly adhere to the flexible polymer substrates. This strong adhesion is beneficial for future applications. PMID:24045289

Determination of the mass transfer limiting step of dye adsorption onto commercial adsorbent by using mathematical models.

PubMed

Marin, Pricila; Borba, Carlos Eduardo; Módenes, Aparecido Nivaldo; Espinoza-Quiñones, Fernando R; de Oliveira, Silvia Priscila Dias; Kroumov, Alexander Dimitrov

2014-01-01

Reactive blue 5G dye removal in a fixed-bed column packed with Dowex Optipore SD-2 adsorbent was modelled. Three mathematical models were tested in order to determine the limiting step of the mass transfer of the dye adsorption process onto the adsorbent. The mass transfer resistance was considered to be a criterion for the determination of the difference between models. The models contained information about the external, internal, or surface adsorption limiting step. In the model development procedure, two hypotheses were applied to describe the internal mass transfer resistance. First, the mass transfer coefficient constant was considered. Second, the mass transfer coefficient was considered as a function of the dye concentration in the adsorbent. The experimental breakthrough curves were obtained for different particle diameters of the adsorbent, flow rates, and feed dye concentrations in order to evaluate the predictive power of the models. The values of the mass transfer parameters of the mathematical models were estimated by using the downhill simplex optimization method. The results showed that the model that considered internal resistance with a variable mass transfer coefficient was more flexible than the other ones and this model described the dynamics of the adsorption process of the dye in the fixed-bed column better. Hence, this model can be used for optimization and column design purposes for the investigated systems and similar ones.

Carbon monoxide mass transfer for syngas fermentation in a stirred tank reactor with dual impeller configurations.

PubMed

Ungerman, Andrew J; Heindel, Theodore J

2007-01-01

This study compares the power demand and gas-liquid volumetric mass transfer coefficient, kLa, in a stirred tank reactor (STR) (T = 0.211 m) using different impeller designs and schemes in a carbon monoxide-water system, which is applicable to synthesis gas (syngas) fermentation. Eleven different impeller schemes were tested over a range of operating conditions typically associated with the "after large cavity" region (ALC) of a Rushton-type turbine (D/T = 0.35). It is found that the dual Rushton-type impeller scheme exhibits the highest volumetric mass transfer rates for all operating conditions; however, it also displays the lowest mass transfer performance (defined as the volumetric mass transfer coefficient per unit power input) for all conditions due to its high power consumption. Dual impeller schemes with an axial flow impeller as the top impeller show improved mass transfer rates without dramatic increases in power draw. At high gas flow rates, dual impeller schemes with a lower concave impeller have kLa values similar to those of the Rushton-type dual impeller schemes but show improved mass transfer performance. It is believed that the mass transfer performance can be further enhanced for the bottom concave impeller schemes by operating at conditions beyond the ALC region defined for Rushton-type impellers because the concave impeller can handle higher gas flow rates prior to flooding.

Spatial Molecular Architecture of the Microbial Community of a Peltigera Lichen.

PubMed

Garg, Neha; Zeng, Yi; Edlund, Anna; Melnik, Alexey V; Sanchez, Laura M; Mohimani, Hosein; Gurevich, Alexey; Miao, Vivian; Schiffler, Stefan; Lim, Yan Wei; Luzzatto-Knaan, Tal; Cai, Shengxin; Rohwer, Forest; Pevzner, Pavel A; Cichewicz, Robert H; Alexandrov, Theodore; Dorrestein, Pieter C

2016-01-01

Microbes are commonly studied as individual species, but they exist as mixed assemblages in nature. At present, we know very little about the spatial organization of the molecules, including natural products that are produced within these microbial networks. Lichens represent a particularly specialized type of symbiotic microbial assemblage in which the component microorganisms exist together. These composite microbial assemblages are typically comprised of several types of microorganisms representing phylogenetically diverse life forms, including fungi, photosymbionts, bacteria, and other microbes. Here, we employed matrix-assisted laser desorption ionization-time of flight (MALDI-TOF) imaging mass spectrometry to characterize the distributions of small molecules within a Peltigera lichen. In order to probe how small molecules are organized and localized within the microbial consortium, analytes were annotated and assigned to their respective producer microorganisms using mass spectrometry-based molecular networking and metagenome sequencing. The spatial analysis of the molecules not only reveals an ordered layering of molecules within the lichen but also supports the compartmentalization of unique functions attributed to various layers. These functions include chemical defense (e.g., antibiotics), light-harvesting functions associated with the cyanobacterial outer layer (e.g., chlorophyll), energy transfer (e.g., sugars) surrounding the sun-exposed cyanobacterial layer, and carbohydrates that may serve a structural or storage function and are observed with higher intensities in the non-sun-exposed areas (e.g., complex carbohydrates). IMPORTANCE Microbial communities have evolved over centuries to live symbiotically. The direct visualization of such communities at the chemical and functional level presents a challenge. Overcoming this challenge may allow one to visualize the spatial distributions of specific molecules involved in symbiosis and to define their functional roles in shaping the community structure. In this study, we examined the diversity of microbial genes and taxa and the presence of biosynthetic gene clusters by metagenomic sequencing and the compartmentalization of organic chemical components within a lichen using mass spectrometry. This approach allowed the identification of chemically distinct sections within this composite organism. Using our multipronged approach, various fungal natural products, not previously reported from lichens, were identified and two different fungal layers were visualized at the chemical level.

Spatial Molecular Architecture of the Microbial Community of a Peltigera Lichen

PubMed Central

Garg, Neha; Zeng, Yi; Edlund, Anna; Melnik, Alexey V.; Mohimani, Hosein; Gurevich, Alexey; Miao, Vivian; Schiffler, Stefan; Lim, Yan Wei; Luzzatto-Knaan, Tal; Cai, Shengxin; Rohwer, Forest; Pevzner, Pavel A.; Cichewicz, Robert H.; Alexandrov, Theodore

2016-01-01

ABSTRACT Microbes are commonly studied as individual species, but they exist as mixed assemblages in nature. At present, we know very little about the spatial organization of the molecules, including natural products that are produced within these microbial networks. Lichens represent a particularly specialized type of symbiotic microbial assemblage in which the component microorganisms exist together. These composite microbial assemblages are typically comprised of several types of microorganisms representing phylogenetically diverse life forms, including fungi, photosymbionts, bacteria, and other microbes. Here, we employed matrix-assisted laser desorption ionization–time of flight (MALDI-TOF) imaging mass spectrometry to characterize the distributions of small molecules within a Peltigera lichen. In order to probe how small molecules are organized and localized within the microbial consortium, analytes were annotated and assigned to their respective producer microorganisms using mass spectrometry-based molecular networking and metagenome sequencing. The spatial analysis of the molecules not only reveals an ordered layering of molecules within the lichen but also supports the compartmentalization of unique functions attributed to various layers. These functions include chemical defense (e.g., antibiotics), light-harvesting functions associated with the cyanobacterial outer layer (e.g., chlorophyll), energy transfer (e.g., sugars) surrounding the sun-exposed cyanobacterial layer, and carbohydrates that may serve a structural or storage function and are observed with higher intensities in the non-sun-exposed areas (e.g., complex carbohydrates). IMPORTANCE Microbial communities have evolved over centuries to live symbiotically. The direct visualization of such communities at the chemical and functional level presents a challenge. Overcoming this challenge may allow one to visualize the spatial distributions of specific molecules involved in symbiosis and to define their functional roles in shaping the community structure. In this study, we examined the diversity of microbial genes and taxa and the presence of biosynthetic gene clusters by metagenomic sequencing and the compartmentalization of organic chemical components within a lichen using mass spectrometry. This approach allowed the identification of chemically distinct sections within this composite organism. Using our multipronged approach, various fungal natural products, not previously reported from lichens, were identified and two different fungal layers were visualized at the chemical level. PMID:28028548

Simulation of the ozone pretreatment of wheat straw.

PubMed

Bhattarai, Sujala; Bottenus, Danny; Ivory, Cornelius F; Gao, Allan Haiming; Bule, Mahesh; Garcia-Perez, Manuel; Chen, Shulin

2015-11-01

Wheat straw is a potential feedstock in biorefinery for sugar production. However, the cellulose, which is the major source of sugar, is protected by lignin. Ozonolysis deconstructs the lignin and makes cellulose accessible to enzymatic digestion. In this study, the change in lignin concentration with different ozonolysis times (0, 1, 2, 3, 5, 7, 10, 15, 20, 30, 60min) was fit to two different kinetic models: one using the model developed by Garcia-Cubero et al. (2012) and another including an outer mass transfer barrier or "cuticle" region where ozone mass transport is reduced in proportion to the mass of unreacted insoluble lignin in the cuticle. The kinetic parameters of two mathematical models for predicting the soluble and insoluble lignin at different pretreatment time were determined. The results showed that parameters derived from the cuticle-based model provided a better fit to experimental results compared to a model without a cuticle layer. Copyright © 2015 Elsevier Ltd. All rights reserved.

The Coupled Boundary Layers and Air-Sea Transfer (CBLAST) Experiments at the Martha's Vineyard Coastal Observatory

NASA Astrophysics Data System (ADS)

Edson, J. B.

2001-12-01

The Woods Hole Oceanographic Institution (WHOI) completed the initial phase of the Martha's Vineyard Coastal Observatory (MVCO) in July of 2001. The MVCO is being using to monitor coastal atmospheric and oceanic processes. Specifically, the observatory is expected to: - Provide continuous long-term observations for climate studies. - Provide a reliable system and rugged sensors that allow opportunistic sampling of extreme events. - Provide a local climatology for intensive, short duration field campaigns. - Further facilitate regional studies of coastal processes by providing infrastructure that supports easy access to power and data. This talk provides an example of the last two objectives using the low wind component of the Office of Naval Research's (ONR) Coupled Boundary Layers and Air-Sea Transfer (CBLAST) program. CBLAST-LOW has been designed to investigate air-sea interaction and coupled atmospheric and oceanic boundary layer dynamics at low wind speeds where the dynamic processes are driven and/or strongly modulated by thermal forcing. This effort is being carried out by scientists at WHOI, NPS, NOAA, NRL, Rutgers, UW/APL, JH/APL, OSU, NCAR, and other institutions, and includes observational and modeling components. The MVCO is providing observations and infrastructure in support of several intensive operating periods in the summers of 2001, 2002, and possibly 2003. During these periods, the observational network around the observatory was and will be greatly expanded using traditional oceanographic moorings and bottom mounted instrumentation, innovative 2- and 3-D moored and drifting arrays, survey ships, AUVs, satellite remote sensing, and heavily instrumented aircraft. In addition, the MVCO cabled components will be extended out to the 20-m isobath where we plan to deploy a 35-m tower. The tower will be instrumented from 15-m above the ocean surface to the ocean bottom with instruments capable of directly measuring the momentum, heat, and radiative fluxes in the atmospheric, oceanic, and bottom boundary layers. This tower will be directly connected to shore via the existing node at the MVCO using an additional fiber-optic-power cable. All of these measurements will be combined to obtain direct measurements of vertical fluxes (transfer) of momentum, heat and mass across the coupled boundary layers (CBLs); to map the 3-D structure of the CBLs over a range of spatial and temporal scales; to identify the processes that drive the fluxes and CBL structure; to develop and evaluate parameterizations of the flux-producing processes; and to test the mean and variance budgets for momentum, heat, mass, and kinetic energy. These measurements will also be used to evaluate and improve mesoscale models, large eddy simulations (LES), and direct numerical simulations (DNS) that will, in-turn, provide nowcasts, forecasts, and simulations of these processes to help interpret the observations. >http://www.whoi.edu/science/AOPE/dept/CBLAST/lowwind.html

Water Transport in the Micro Porous Layer and Gas Diffusion Layer of a Polymer Electrolyte Fuel Cell

NASA Astrophysics Data System (ADS)

Qin, C.; Hassanizadeh, S. M.

2015-12-01

In this work, a recently developed dynamic pore-network model is presented [1]. The model explicitly solves for both water pressure and capillary pressure. A semi-implicit scheme is used in updating water saturation in each pore body, which considerably increases the numerical stability at low capillary number values. Furthermore, a multiple-time-step algorithm is introduced to reduce the computational effort. A number of case studies of water transport in the micro porous layer (MPL) and gas diffusion layer (GDL) are conducted. We illustrate the role of MPL in reducing water flooding in the GDL. Also, the dynamic water transport through the MPL-GDL interface is explored in detail. This information is essential to the reduced continua model (RCM), which was developed for multiphase flow through thin porous layers [2, 3]. C.Z. Qin, Water transport in the gas diffusion layer of a polymer electrolyte fuel cell: dynamic pore-network modeling, J Electrochimical. Soci., 162, F1036-F1046, 2015. C.Z. Qin and S.M. Hassanizadeh, Multiphase flow through multilayers of thin porous media: general balance equations and constitutive relationships for a solid-gas-liquid three-phase system, Int. J. Heat Mass Transfer, 70, 693-708, 2014. C.Z. Qin and S.M. Hassanizadeh, A new approach to modeling water flooding in a polymer electrolyte fuel cell, Int. J. Hydrogen Energy, 40, 3348-3358, 2015.

LH2 fuel tank design for SSTO

NASA Technical Reports Server (NTRS)

Wright, Geoff

1994-01-01

This report will discuss the design of a liquid hydrogen fuel tank constructed from composite materials. The focus of this report is to recommend a design for a fuel tank which will be able to withstand all static and dynamic forces during manned flight. Areas of study for the design include material selection, material structural analysis, heat transfer, thermal expansion, and liquid hydrogen diffusion. A structural analysis FORTRAN program was developed for analyzing the buckling and yield characteristics of the tank. A thermal analysis Excel spreadsheet was created to determine a specific material thickness which will minimize heat transfer through the wall of the tank. The total mass of the tank was determined by the combination of both structural and thermal analyses. The report concludes with the recommendation of a layered material tank construction. The designed system will include exterior insulation, combination of metal and organize composite matrices and honeycomb.

Electrical transport engineering of semiconductor superlattice structures

NASA Astrophysics Data System (ADS)

Shokri, Aliasghar

2014-04-01

We investigate the influence of doping concentration on band structures of electrons and electrical transmission in a typical aperiodic semiconductor superlattice consisting of quantum well and barrier layers, theoretically. For this purpose, we assume that each unit cell of the superlattice contains alternately two types of material GaAs (as a well) and GaAlAs (as a barrier) with six sublayers of two materials. Our calculations are based on the generalized Kronig-Penny (KP) model and the transfer matrix method within the framework of the parabolic conductance band effective mass approximation in the coherent regime. This model reduces the numerical calculation time and enables us to use the transfer matrix method to investigate transport in the superlattices. We show that by varying the doping concentration and geometrical parameters, one can easily block the transmission of the electrons. The numerical results may be useful in designing of nanoenergy filter devices.

Properties of six short-period massive binaries: A study of the effects of binarity on surface chemical abundances

NASA Astrophysics Data System (ADS)

Martins, F.; Mahy, L.; Hervé, A.

2017-11-01

Context. A significant percentage of massive stars are found in multiple systems. The effect of binarity on stellar evolution is poorly constrained. In particular, the role of tides and mass transfer on surface chemical abundances is not constrained observationally. Aims: The aim of this study is to investigate the effect of binarity on the stellar properties and surface abundances of massive binaries. Methods: We performed a spectroscopic analysis of six Galactic massive binaries. We obtained the spectra of individual components via a spectral disentangling method and subsequently analyzed these spectra by means of atmosphere models. The stellar parameters and CNO surface abundances were determined. Results: Most of these six systems are comprised of main-sequence stars. Three systems are detached, two are in contact, and no information is available for the sixth system. For 11 out of the 12 stars studied, the surface abundances are only mildly affected by stellar evolution and mixing. The surface abundances are not different from those of single stars within the uncertainties. The secondary of XZ Cep is strongly chemically enriched. Considering previous determinations of surface abundances in massive binary systems suggests that the effect of tides on chemical mixing is limited, whereas the mass transfer and removal of outer layers of the mass donor leads to the appearance of chemically processed material at the surface, although this is not systematic. The evolutionary masses of the components of our six systems are on average 16.5% higher than the dynamical masses. Some systems seem to have reached synchronization, while others may still be in a transitory phase. Based on observations made with the SOPHIE spectrograph on the 1.93 m telescope at Observatoire de Haute-Provence (OHP, CNRS/AMU), France.

The vertical structure of the boundary layer around compact objects

NASA Astrophysics Data System (ADS)

Hertfelder, Marius; Kley, Wilhelm

2017-09-01

Context. Mass transfer due to Roche lobe overflow leads to the formation of an accretion disk around a weakly magnetized white dwarf (WD) in cataclysmic variables. At the inner edge of the disk, the gas comes upon the surface of the WD and has to get rid of its excess kinetic energy in order to settle down on the more slowly rotating outer stellar layers. This region is known as the boundary layer (BL). Aims: In this work we investigate the vertical structure of the BL, which is still poorly understood. We shall provide details of the basic structure of the two-dimensional (2D) BL and how it depends on parameters such as stellar mass and rotation rate, as well as the mass-accretion rate. We further investigate the destination of the disk material and compare our results with previous one-dimensional (1D) simulations. Methods: We solve the 2D equations of radiation hydrodynamics in a spherical (r-ϑ) geometry using a parallel grid-based code that employs a Riemann solver. The radiation energy is considered in the two-temperature approach with a radiative flux given by the flux-limited diffusion approximation. Results: The BL around a non-rotating WD is characterized by a steep drop in angular velocity over a width of only 1% of the stellar radius, a heavy depletion of mass, and a high temperature ( 500 000 K) as a consequence of the strong shear. Variations in Ω∗,M∗, and Ṁ influence the extent of the changes of the variables in the BL but not the general structure. Depending on Ω∗, the disk material travels up to the poles or is halted at a certain latitude. The extent of mixing with the stellar material also depends on Ω∗. We find that the 1D approximation matches the 2D data well, apart from an underestimated temperature.

Mass and heat transfer in crushed oil shale

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carley, J.F.; Ott, L.L.; Swecker, J.L.

1995-03-01

Studies of heat and mass transfer in packed beds, which disagree substantially in their findings, have nearly all been done with beds of regular particles of uniform size, whereas oil-shale retorting involves particles of diverse irregular shapes and sizes. The authors, in 349 runs, measured mass-transfer rates front naphthalene particles buried in packed beds by passing through air at room temperature. An exact catalog between convection of heat and mass makes it possible to infer heat-transfer coefficients from measured mass-transfer coefficients and fluid properties. Some beds consisted of spheres, naphthalene and inert, of the same, contrasting or distributed sizes. Inmore » some runs, naphthalene spheres were buried in beds of crushed shale, some in narrow screen ranges and others with a wide size range. In others, naphthalene lozenges of different shapes were buried in beds of crushed shale in various bed axis orientations. This technique permits calculation of the mass-transfer coefficient for each active particle in the bed rather than, as in most past studies, for the bed as a whole. The data are analyzed by the traditional correlation of Colburn j{sub D} vs. Reynolds number and by multiple regression of the mass-transfer coefficient on air rate, sizes of active and inert particles, void fraction, and temperature. Principal findings are: local Reynolds number should be based on the active-particle size, not the average for the whole bed; differences between shallow and deep beds are not appreciable; mass transfer is 26% faster for spheres and lozenges buried in shale than in all-sphere beds; orientation of lozenges in shale beds has little or no effect on mass-transfer rate; and for mass or heat transfer in shale beds, log(j{center_dot}{epsilon}) = {minus}0.0747 - 0.6344 log N{sub Re} + 0. 0592 log {sup 2} N{sub Re}.« less

Marangoni convection in Casson liquid flow due to an infinite disk with exponential space dependent heat source and cross-diffusion effects

NASA Astrophysics Data System (ADS)

Mahanthesh, B.; Gireesha, B. J.; Shashikumar, N. S.; Hayat, T.; Alsaedi, A.

2018-06-01

Present work aims to investigate the features of the exponential space dependent heat source (ESHS) and cross-diffusion effects in Marangoni convective heat mass transfer flow due to an infinite disk. Flow analysis is comprised with magnetohydrodynamics (MHD). The effects of Joule heating, viscous dissipation and solar radiation are also utilized. The thermal and solute field on the disk surface varies in a quadratic manner. The ordinary differential equations have been obtained by utilizing Von Kármán transformations. The resulting problem under consideration is solved numerically via Runge-Kutta-Fehlberg based shooting scheme. The effects of involved pertinent flow parameters are explored by graphical illustrations. Results point out that the ESHS effect dominates thermal dependent heat source effect on thermal boundary layer growth. The concentration and temperature distributions and their associated layer thicknesses are enhanced by Marangoni effect.

Double-diffusive boundary layers along vertical free surfaces

NASA Astrophysics Data System (ADS)

Napolitano, L. G.; Viviani, A.; Savino, R.

1992-05-01

This paper deals with double-diffusive (or thermosolutal) combined free convection, i.e., free convection due to buoyant forces (natural convection) and surface tension gradients (Marangoni convection), which are generated by volume differences and surface gradients of temperature and solute concentration. Attention is focused on boundary layers that form along a vertical liquid-gas interface, when the appropriately defined nondimensional characteristic transport numbers are large enough, in problems of thermosolutal natural and Marangoni convection, such as buoyancy and surface tension driven flows in differentially heated open cavities and liquid bridges. Classes of similar solutions are derived for each class of convection on the basis of a rigorous order of magnitude analysis. Velocity, temperature and concentration profiles are reported in the similarity plane; flow and transport properties at the liquid-gas interface (interfacial velocity, heat and mass transfer bulk coefficients) are obtained for a wide range of Prandtl and Schmidt numbers and different values of the similarity parameter.

Mn concentration and quantum size effects on spin-polarized transport through CdMnTe based magnetic resonant tunneling diode.

PubMed

Mnasri, S; Abdi-Ben Nasrallahl, S; Sfina, N; Lazzari, J L; Saïd, M

2012-11-01

Theoretical studies on spin-dependent transport in magnetic tunneling diodes with giant Zeeman splitting of the valence band are carried out. The studied structure consists of two nonmagnetic layers CdMgTe separated by a diluted magnetic semiconductor barrier CdMnTe, the hole is surrounded by two p-doped CdTe layers. Based on the parabolic valence band effective mass approximation and the transfer matrix method, the magnetization and the current densities for holes with spin-up and spin-down are studied in terms of the Mn concentration, the well and barrier thicknesses as well as the voltage. It is found that, the current densities depend strongly on these parameters and by choosing suitable values; this structure can be a good spin filter. Such behaviors are originated from the enhancement and suppression in the spin-dependent resonant states.

Solar dynamic modules for Space Station Freedom: The relationship between fine-pointing control and thermal loading of the aperture plate

NASA Technical Reports Server (NTRS)

Quinn, Roger D.; Kerslake, Thomas W.

1992-01-01

Dynamic simulations of Space Station Freedom (SSF) configured with solar dynamic (SD) power modules were performed. The structure was subjected to Space Shuttle docking disturbances, while being controlled with a 'natural' vibration and tracking control approach. Three control cases were investigated for the purpose of investigating the relationship between actuator effort, SD pointing, and thermal loading on the receiver aperture plate. Transient, one-dimensional heat transfer analyses were performed to conservatively predict temperatures of the multi-layered receiver aperture plate assembly and thermal stresses in its shield layer. Results indicate that the proposed aperture plate is tolerant of concentrated flux impingement during short-lived structural disturbances. Pointing requirements may be loosened and the requirement control torques lessened from that previously specified. Downsizing and simplifying the joint drive system should result in a considerable savings mass.

Effect of operating temperature on styrene mass transfer characteristics in a biotrickling filter.

PubMed

Parnian, Parham; Zamir, Seyed Morteza; Shojaosadati, Seyed Abbas

2017-05-01

To study the effect of operating temperature on styrene mass transfer from gas to liquid phase in biotrickling filters (BTFs), overall mass transfer coefficient (K L a) was calculated through fitting test data to a general mass balance model under abiotic conditions. Styrene was used as the volatile organic compound and the BTF was packed with a mixture of pall rings and pumice. Operating temperature was set at 30°C and 50°C for mesophilic and thermophilic conditions, respectively. K L a values increased from 54 to 70 h -1 at 30°C and from 60 to 90 h -1 at 50°C, respectively, depending on the countercurrent gas to liquid flow ratio that varied in the range of 7.5-32. Evaluation of styrene mass transfer capacity (MTC) showed that liquid-phase mass transfer resistance decreased as the flow ratio increased at constant temperature. MTC also decreased with an increase in operating temperature. Both gas-liquid partition coefficient and K L a increased with increasing temperature; however the effect on gas-liquid partition coefficient was more significant and served to increase mass transfer limitations. Thermophilic biofiltration on the one hand increases mass transfer limitations, but on the other hand may enhance the biodegradation rate in favor of enhancing BTFs' performance.

Ozone mass transfer behaviors on physical and chemical absorption for hollow fiber membrane contactors.

PubMed

Zhang, Yong; Li, Kuiling; Wang, Jun; Hou, Deyin; Liu, Huijuan

2017-09-01

To understand the mass transfer behaviors in hollow fiber membrane contactors, ozone fluxes affected by various conditions and membranes were investigated. For physical absorption, mass transfer rate increased with liquid velocity and the ozone concentration in the gas. Gas flow rate was little affected when the velocity was larger than the critical value, which was 6.1 × 10 -3 m/s in this study. For chemical absorption, the flux was determined by the reaction rate between ozone and the absorbent. Therefore, concentration, species, and pH affected the mass transfer process markedly. For different absorbents, the order of mass transfer rate was the same as the reaction rate constant, which was phenol, sodium nitrite, hydrogen peroxide, and oxalate. Five hydrophobic membranes with various properties were employed and the mass transfer behavior can be described by the Graetz-Lévèque equation for the physical absorption process. The results showed the process was controlled by liquid film and the gas phase conditions, and membrane properties did not affect the ozone flux. For the chemical absorption, gas film, membrane and liquid film affected the mass transfer together, and none of them were negligible.

Local Mass and Heat Transfer on a Turbine Blade Tip

DOE PAGES

Jin, P.; Goldstein, R. J.

2003-01-01

Locmore » al mass and heat transfer measurements on a simulated high-pressure turbine blade-tip surface are conducted in a linear cascade with a nonmoving tip endwall, using a naphthalene sublimation technique. The effects of tip clearance (0.86–6.90% of chord) are investigated at various exit Reynolds numbers (4–7 × 10 5 ) and turbulence intensities (0.2 and 12.0%). The mass transfer on the tip surface is significant along its pressure edge at the smallest tip clearance. At the two largest tip clearances, the separation bubble on the tip surface can cover the whole width of the tip on the second half of the tip surface. The average mass-transfer rate is highest at a tip clearance of 1.72% of chord. The average mass-transfer rate on the tip surface is four and six times as high as on the suction and the pressure surface, respectively. A high mainstream turbulence level of 12.0% reduces average mass-transfer rates on the tip surface, while the higher mainstream Reynolds number generates higher local and average mass-transfer rates on the tip surface.« less

Meniscus-force-mediated layer transfer technique using single-crystalline silicon films with midair cavity: Application to fabrication of CMOS transistors on plastic substrates

NASA Astrophysics Data System (ADS)

Sakaike, Kohei; Akazawa, Muneki; Nakagawa, Akitoshi; Higashi, Seiichiro

2015-04-01

A novel low-temperature technique for transferring a silicon-on-insulator (SOI) layer with a midair cavity (supported by narrow SiO2 columns) by meniscus force has been proposed, and a single-crystalline Si (c-Si) film with a midair cavity formed in dog-bone shape was successfully transferred to a poly(ethylene terephthalate) (PET) substrate at its heatproof temperature or lower. By applying this proposed transfer technique, high-performance c-Si-based complementary metal-oxide-semiconductor (CMOS) transistors were successfully fabricated on the PET substrate. The key processes are the thermal oxidation and subsequent hydrogen annealing of the SOI layer on the midair cavity. These processes ensure a good MOS interface, and the SiO2 layer works as a “blocking” layer that blocks contamination from PET. The fabricated n- and p-channel c-Si thin-film transistors (TFTs) on the PET substrate showed field-effect mobilities of 568 and 103 cm2 V-1 s-1, respectively.

Development of dissipative elastic metamaterials based on the layered cantilever-in-mass structure for attenuating the broad spectrum vibrations

NASA Astrophysics Data System (ADS)

Wang, Jun; Zhou, Xiaoqin; Wang, Rongqi; Lin, Jieqiong

2018-05-01

In this paper, the layered cantilever-in-mass structures (LCIMs) will be theoretically investigated to reveal the effects of the layered structures on band gaps, which have great potential to bring in many useful material properties without much increasing the manufacturing difficulty by stacking the damped layers or other different component layers. Firstly, the negative effective mass model of LCIMs is derived based on the mass-in-mass model, which is applied to analyze the effective parameters of band gaps in terms of the geometrical features and material properties, the analytical results indicate the negative effective masses of LCIMs depend highly on the material parameter and thicknesses of each constituent layers. Then the LCIMs consist of the same thickness layers are further researched, which has found that their resonance frequency are independent on the layer thickness, and the numeric values of resonance frequencies are between the maximum and minimum local resonance frequency of their constituent layers. To validate the above analytical model, the three-dimensional model and the two-dimensional shell model of LCIMs are constructed in COMSOL Multiphysics. The obtained results show well agreement with the derived model in both the three-dimensional model and shell model. Finally, the dissipative LCIMs modeled by stacking the damped layers and metal layers are studied and discussed.

Heat transfer to the transpired turbulent boundary layer.

NASA Technical Reports Server (NTRS)

Kays, W. M.

1972-01-01

This paper contains a summarization of five years work on an investigation on heat transfer to the transpired turbulent boundary layer. Experimental results are presented for friction coefficient and Stanton number over a wide range of blowing and suction for the case of constant free-stream velocity, holding certain blowing parameters constant. The problem of the accelerated turbulent boundary layer with transpiration is considered, experimental data are presented and discussed, and theoretical models for solution of the momentum equation under these conditions are presented. Data on turbulent Prandtl number are presented so that solutions to the energy equation may be obtained. Some examples of boundary layer heat transfer and friction coefficient predictions are presented using one of the models discussed, employing a finite difference solution method.

Weak incident shock interactions with Mach 8 laminar boundary layers. [of flat plate

NASA Technical Reports Server (NTRS)

Kaufman, L. G., II; Johnson, C. B.

1974-01-01

Weak shock-wave interactions with boundary layers on a flat plate were investigated experimentally in Mach 8 variable-density tunnel for plate-length Reynolds numbers. The undisturbed boundary layers were laminar over the entire plate length. Pressure and heat-transfer distributions were obtained for wedge-generated incident shock waves that resulted in pressure rises ranging from 1.36 to 4.46 (both nonseparated and separated boundary-layer flows). The resulting heat-transfer amplifications ranged from 1.45 to 14. The distributions followed established trends for nonseparated flows, for incipient separation, and for laminar free-interaction pressure rises. The experimental results corroborated established trends for the extent of the pressure rise and for certain peak heat-transfer correlations.

Application of gas diffusion biocathode in microbial electrosynthesis from carbon dioxide.

PubMed

Bajracharya, Suman; Vanbroekhoven, Karolien; Buisman, Cees J N; Pant, Deepak; Strik, David P B T B

2016-11-01

Microbial catalysis of carbon dioxide (CO 2 ) reduction to multi-carbon compounds at the cathode is a highly attractive application of microbial electrosynthesis (MES). The microbes reduce CO 2 by either taking the electrons or reducing the equivalents produced at the cathode. While using gaseous CO 2 as the carbon source, the biological reduction process depends on the dissolution and mass transfer of CO 2 in the electrolyte. In order to deal with this issue, a gas diffusion electrode (GDE) was investigated by feeding CO 2 through the GDE into the MES reactor for its reduction at the biocathode. A combination of the catalyst layer (porous activated carbon and Teflon binder) and the hydrophobic gas diffusion layer (GDL) creates a three-phase interface at the electrode. So, CO 2 and reducing equivalents will be available to the biocatalyst on the cathode surface. An enriched inoculum consisting of acetogenic bacteria, prepared from an anaerobic sludge, was used as a biocatalyst. The cathode potential was maintained at -1.1 V vs Ag/AgCl to facilitate direct and/or hydrogen-mediated CO 2 reduction. Bioelectrochemical CO 2 reduction mainly produced acetate but also extended the products to ethanol and butyrate. Average acetate production rates of 32 and 61 mg/L/day, respectively, with 20 and 80 % CO 2 gas mixture feed were achieved with 10 cm 2 of GDE. The maximum acetate production rate remained 238 mg/L/day for 20 % CO 2 gas mixture. In conclusion, a gas diffusion biocathode supported bioelectrochemical CO 2 reduction with enhanced mass transfer rate at continuous supply of gaseous CO 2 . Graphical abstract ᅟ.

VizieR Online Data Catalog: Adiabatic mass loss in binary stars. II. (Ge+, 2015)

NASA Astrophysics Data System (ADS)

Ge, H.; Webbink, R. F.; Chen, X.; Han, Z.

2016-02-01

In the limit of extremely rapid mass transfer, the response of a donor star in an interacting binary becomes asymptotically one of adiabatic expansion. We survey here adiabatic mass loss from Population I stars (Z=0.02) of mass 0.10M⊙-100M⊙ from the zero-age main sequence to the base of the giant branch, or to central hydrogen exhaustion for lower main sequence stars. The logarithmic derivatives of radius with respect to mass along adiabatic mass-loss sequences translate into critical mass ratios for runaway (dynamical timescale) mass transfer, evaluated here under the assumption of conservative mass transfer. For intermediate- and high-mass stars, dynamical mass transfer is preceded by an extended phase of thermal timescale mass transfer as the star is stripped of most of its envelope mass. The critical mass ratio qad (throughout this paper, we follow the convention of defining the binary mass ratio as q{equiv}Mdonor/Maccretor) above which this delayed dynamical instability occurs increases with advancing evolutionary age of the donor star, by ever-increasing factors for more massive donors. Most intermediate- or high-mass binaries with nondegenerate accretors probably evolve into contact before manifesting this instability. As they approach the base of the giant branch, however, and begin developing a convective envelope, qad plummets dramatically among intermediate-mass stars, to values of order unity, and a prompt dynamical instability occurs. Among low-mass stars, the prompt instability prevails throughout main sequence evolution, with qad declining with decreasing mass, and asymptotically approaching qad=2/3, appropriate to a classical isentropic n=3/2 polytrope. Our calculated qad values agree well with the behavior of time-dependent models by Chen & Han (2003MNRAS.341..662C) of intermediate-mass stars initiating mass transfer in the Hertzsprung gap. Application of our results to cataclysmic variables, as systems that must be stable against rapid mass transfer, nicely circumscribes the range in qad as a function of the orbital period in which they are found. These results are intended to advance the verisimilitude of population synthesis models of close binary evolution. (3 data files).

Stagnation-point heat transfer correlation for ionized gases

NASA Technical Reports Server (NTRS)

Bade, W. L.

1975-01-01

Based on previous laminar boundary-layer solutions for argon, xenon, nitrogen, and air, it is shown that the effect of gas ionization on stagnation-point heat transfer can be correlated with the variation of the frozen Prandtl number across the boundary layer. A formula is obtained for stagnation-point heat transfer in a noble gas and is shown to be valid from the low-temperature range to the region of strong ionization. It is concluded that the considered effect can be well correlated by the 0.7 power of the Prandtl-number ratio across the boundary layer.

Mixing of secondary organic aerosols versus relative humidity

PubMed Central

Ye, Qing; Robinson, Ellis Shipley; Ding, Xiang; Ye, Penglin

2016-01-01

Atmospheric aerosols exert a substantial influence on climate, ecosystems, visibility, and human health. Although secondary organic aerosols (SOA) dominate fine-particle mass, they comprise myriad compounds with uncertain sources, chemistry, and interactions. SOA formation involves absorption of vapors into particles, either because gas-phase chemistry produces low-volatility or semivolatile products that partition into particles or because more-volatile organics enter particles and react to form lower-volatility products. Thus, SOA formation involves both production of low-volatility compounds and their diffusion into particles. Most chemical transport models assume a single well-mixed phase of condensing organics and an instantaneous equilibrium between bulk gas and particle phases; however, direct observations constraining diffusion of semivolatile organics into particles containing SOA are scarce. Here we perform unique mixing experiments between SOA populations including semivolatile constituents using quantitative, single-particle mass spectrometry to probe any mass-transfer limitations in particles containing SOA. We show that, for several hours, particles containing SOA from toluene oxidation resist exchange of semivolatile constituents at low relative humidity (RH) but start to lose that resistance above 20% RH. Above 40% RH, the exchange of material remains constant up to 90% RH. We also show that dry particles containing SOA from α-pinene ozonolysis do not appear to resist exchange of semivolatile compounds. Our interpretation is that in-particle diffusion is not rate-limiting to mass transfer in these systems above 40% RH. To the extent that these systems are representative of ambient SOA, we conclude that diffusion limitations are likely not common under typical ambient boundary layer conditions. PMID:27791066

Mixing of secondary organic aerosols versus relative humidity.

PubMed

Ye, Qing; Robinson, Ellis Shipley; Ding, Xiang; Ye, Penglin; Sullivan, Ryan C; Donahue, Neil M

2016-10-24

Atmospheric aerosols exert a substantial influence on climate, ecosystems, visibility, and human health. Although secondary organic aerosols (SOA) dominate fine-particle mass, they comprise myriad compounds with uncertain sources, chemistry, and interactions. SOA formation involves absorption of vapors into particles, either because gas-phase chemistry produces low-volatility or semivolatile products that partition into particles or because more-volatile organics enter particles and react to form lower-volatility products. Thus, SOA formation involves both production of low-volatility compounds and their diffusion into particles. Most chemical transport models assume a single well-mixed phase of condensing organics and an instantaneous equilibrium between bulk gas and particle phases; however, direct observations constraining diffusion of semivolatile organics into particles containing SOA are scarce. Here we perform unique mixing experiments between SOA populations including semivolatile constituents using quantitative, single-particle mass spectrometry to probe any mass-transfer limitations in particles containing SOA. We show that, for several hours, particles containing SOA from toluene oxidation resist exchange of semivolatile constituents at low relative humidity (RH) but start to lose that resistance above 20% RH. Above 40% RH, the exchange of material remains constant up to 90% RH. We also show that dry particles containing SOA from α-pinene ozonolysis do not appear to resist exchange of semivolatile compounds. Our interpretation is that in-particle diffusion is not rate-limiting to mass transfer in these systems above 40% RH. To the extent that these systems are representative of ambient SOA, we conclude that diffusion limitations are likely not common under typical ambient boundary layer conditions.

Irradiation-driven Mass Transfer Cycles in Compact Binaries

NASA Astrophysics Data System (ADS)

Büning, A.; Ritter, H.

2005-08-01

We elaborate on the analytical model of Ritter, Zhang, & Kolb (2000) which describes the basic physics of irradiation-driven mass transfer cycles in semi-detached compact binary systems. In particular, we take into account a contribution to the thermal relaxation of the donor star which is unrelated to irradiation and which was neglected in previous studies. We present results of simulations of the evolution of compact binaries undergoing mass transfer cycles, in particular also of systems with a nuclear evolved donor star. These computations have been carried out with a stellar evolution code which computes mass transfer implicitly and models irradiation of the donor star in a point source approximation, thereby allowing for much more realistic simulations than were hitherto possible. We find that low-mass X-ray binaries (LMXBs) and cataclysmic variables (CVs) with orbital periods ⪉ 6hr can undergo mass transfer cycles only for low angular momentum loss rates. CVs containing a giant donor or one near the terminal age main sequence are more stable than previously thought, but can possibly also undergo mass transfer cycles.

Nearly Perfect Triplet-Triplet Energy Transfer from Wannier Excitons to Naphthalene in Organic-Inorganic Hybrid Quantum-Well Materials

NASA Astrophysics Data System (ADS)

Ema, K.; Inomata, M.; Kato, Y.; Kunugita, H.; Era, M.

2008-06-01

We report the observation of extremely efficient energy transfer (greater than 99%) in an organic-inorganic hybrid quantum-well structure consisting of perovskite-type lead bromide well layers and naphthalene-linked ammonium barrier layers. Time-resolved photoluminescence measurements confirm that the transfer is triplet-triplet Dexter-type energy transfer from Wannier excitons in the inorganic well to the triplet state of naphthalene molecules in the organic barrier. Using measurements in the 10 300 K temperature range, we also investigated the temperature dependence of the energy transfer.

Observations of metal concentrations in E-region sporadic thin layers using incoherent-scatter radar

NASA Astrophysics Data System (ADS)

Suzuki, Nobuhiro

This thesis has used incoherent-scatter radar data from the facility at Sondrestrom, Greenland to determine the ion mass values inside thin sporadic-E layers in the lower ionosphere. Metallic positively-charged ions of meteoric origin are deposited in the earth's upper atmosphere over a height range of about 85-120 km. Electric fields and neutral-gas (eg N2, O, O2) winds at high latitudes may produce convergent ion dynamics that results in the re-distribution of the background altitude distribution of the ions to form thin (1-3 km) high-density layers that are detectable with radar. A large database of experimental radar observations has been processed to determine ion mass values inside these thin ion layers. The range resolution of the radar was 600 meters that permitted mass determinations at several altitude steps within the layers. Near the lower edge of the layers the ion mass values were in the range 20-25 amu while at the top portion of the layers the mass values were generally in the range 30-40 amu. The numerical values are consistent with in-situ mass spectrometer data obtained by other researchers that suggest these layers are mainly composed of a mixture or Mg +, Si+, and Fe + ions. The small tendency for heavier ions to reside at the top portion of the layers is consistent with theory. The results have also found new evidence for the existence of complex-shaped multiple layers; the examples studied suggest similar ion mass values in different layers that in some cases are separated in altitude by several km.

Effect of Amount of Carbon on the Reduction Efficiency of Iron Ore-Coal Composite Pellets in Multi-layer Bed Rotary Hearth Furnace (RHF)

NASA Astrophysics Data System (ADS)

Mishra, Srinibash; Roy, Gour Gopal

2016-08-01

The effect of carbon-to-hematite molar ratio has been studied on the reduction efficiency of iron ore-coal composite pellet reduced at 1523 K (1250 °C) for 20 minutes in a laboratory scale multi-layer bed rotary hearth furnace (RHF). Reduced pellets have been characterized through weight loss measurement, estimation of porosity, shrinkage, qualitative and quantitative phase analysis by XRD. Performance parameters such as the degree of reduction, metallization, carbon efficiency, productivity, and compressive strength have been calculated to compare the process efficacy at different carbon levels in the pellets. Pellets with optimum carbon-to-hematite ratio (C/Fe2O3 molar ratio = 1.66) that is much below the stoichiometric carbon required for direct reduction of hematite yielded maximum reduction, better carbon utilization, and productivity for all three layers. Top layer exhibited maximum reduction at comparatively lower carbon level (C/Fe2O3 molar ratio <2.33) in the pellet, while bottom layer exceeded top layer reduction at higher carbon level (C/Fe2O3 molar ratio >2.33). Correlation between degree of reduction and metallization indicated non-isothermal kinetics influenced by heat and mass transfer in multi-layer bed RHF. Compressive strength of the partially reduced pellet with optimum carbon content (C/Fe2O3 molar ratio = 1.66) showed that they could be potentially used as an alternate feed in a blast furnace or any other smelting reactor.

Nanoscale pillar arrays for separations

DOE PAGES

Kirchner, Teresa; Strickhouser, Rachel; Hatab, Nahla; ...

2015-04-01

The work presented herein evaluates silicon nano-pillar arrays for use in planar chromatography. Electron beam lithography and metal thermal dewetting protocols were used to create nano-thin layer chromatography platforms. With these fabrication methods we are able to reduce the size of the characteristic features in a separation medium below that used in ultra-thin layer chromatography; i.e. pillar heights are 1-2μm and pillar diameters are typically in the 200- 400nm range. In addition to the intrinsic nanoscale aspects of the systems, it is shown they can be further functionalized with nanoporous layers and traditional stationary phases for chromatography; hence exhibit broad-rangingmore » lab-on-a-chip and point-of-care potential. Because of an inherent high permeability and very small effective mass transfer distance between pillars, chromatographic efficiency can be very high but is enhanced herein by stacking during development and focusing while drying, yielding plate heights in the nm range separated band volumes. Practical separations of fluorescent dyes, fluorescently derivatized amines, and anti-tumor drugs are illustrated.« less

A comprehensive review of thin-layer drying models used in agricultural products.

PubMed

Ertekin, Can; Firat, M Ziya

2017-03-04

Drying is one of the widely used methods of grain, fruit, and vegetable preservation. The important aim of drying is to reduce the moisture content and thereby increase the lifetime of products by limiting enzymatic and oxidative degradation. In addition, by reducing the amount of water, drying reduces the crop losses, improves the quality of dried products, and facilitates its transportation, handling, and storage requirements. Drying is a process comprising simultaneous heat and mass transfer within the material, and between the surface of the material and the surrounding media. Many models have been used to describe the drying process for different agricultural products. These models are used to estimate drying time of several products under different drying conditions, and how to increase the drying process efficiency and also to generalize drying curves, for the design and operation of dryers. Several investigators have proposed numerous mathematical models for thin-layer drying of many agricultural products. This study gives a comprehensive review of more than 100 different semitheoretical and empirical thin-layer drying models used in agricultural products and evaluates the statistical criteria for the determination of appropriate model.

Proteomics analysis of latex from Hevea brasiliensis (clone RRIM 600).

PubMed

Habib, Mohd Afiq Hazlami; Yuen, Gan Chee; Othman, Fazilah; Zainudin, Nurul Nabilah; Latiff, Aishah Abdul; Ismail, Mohd Nazri

2017-04-01

The natural rubber latex extracted from the bark of Hevea brasiliensis plays various important roles in today's modern society. Following ultracentrifugation, the latex can be separated into 3 layers: C-serum, lutoids, and rubber particles. Previous studies have shown that a large number of proteins are present in these 3 layers. However, a complete proteome for this important plant is still unavailable. Protein sequences have been recently translated from the completed draft genome database of H. brasiliensis, leading to the creation of annotated protein databases of the following H. brasiliensis biosynthetic pathways: photosynthesis, latex allergens, rubberwood formation, latex biosynthesis, and disease resistance. This research was conducted to identify the proteins contained within the latex by way of de novo sequencing from mass spectral data obtained from the 3 layers of the latex. Peptides from these proteins were fragmented using collision-induced dissociation, higher-energy collisional dissociation, and electron-transfer dissociation activation methods. A large percentage of proteins from the biosynthetic pathways (63% to 100%) were successfully identified. In addition, a total of 1839 unique proteins were identified from the whole translated draft genome database (AnnHBM).

Three-dimensional graphene as gas diffusion layer for micro direct methanol fuel cell

NASA Astrophysics Data System (ADS)

Zhu, Yingli; Zhang, Xiaojian; Li, Jianyu; Qi, Gary

2018-05-01

The gas diffusion layer (GDL), as an important structure of the membrane electrode assembly (MEA) of the direct methanol fuel cell (DMFC), provides a support layer for the catalyst and the fuel and the product channel. Traditionally, the material of GDL is generally carbon paper (CP). In this paper, a new material, namely three-dimensional graphene (3DG) is used as GDL for micro DMFC. The experimental results reveal that the performance of the DMFC has been improved significantly by application of 3DG. The peak powers increase from 25 mW to 31.2 mW and 32 mW by using 3DG as the anode and cathode GDL instead of CP, respectively. The reason may be the decrease of charge and mass transfer resistance of the cell. This means that the unique 3D porous architecture of the 3DG can provide lower contact resistance and sufficient fuel diffusion paths. The output performance of the cell will be further improved when porous metal current collectors is used.

Aqueous proton transfer across single-layer graphene

DOE PAGES

Achtyl, Jennifer L.; Unocic, Raymond R.; Xu, Lijun; ...

2015-03-17

Proton transfer across single-layer graphene proceeds with large computed energy barriers and is thought to be unfavourable at room temperature unless nanoscale holes or dopants are introduced, or a potential bias is applied. Here we subject single-layer graphene supported on fused ​silica to cycles of high and low pH, and show that protons transfer reversibly from the aqueous phase through the graphene to the other side where they undergo acid–base chemistry with the silica hydroxyl groups. After ruling out diffusion through macroscopic pinholes, the protons are found to transfer through rare, naturally occurring atomic defects. Computer simulations reveal low energymore » barriers of 0.61–0.75 eV for aqueous proton transfer across hydroxyl-terminated atomic defects that participate in a Grotthuss-type relay, while ​pyrylium-like ether terminations shut down proton exchange. In conclusion, unfavourable energy barriers to helium and ​hydrogen transfer indicate the process is selective for aqueous protons.« less

The effect of body postures on the distribution of air gap thickness and contact area.

PubMed

Mert, Emel; Psikuta, Agnes; Bueno, Marie-Ange; Rossi, René M

2017-02-01

The heat and mass transfer in clothing is predominantly dependent on the thickness of air layer and the magnitude of contact area between the body and the garment. The air gap thickness and magnitude of the contact area can be affected by the posture of the human body. Therefore, in this study, the distribution of the air gap and the contact area were investigated for different body postures of a flexible manikin. In addition, the effect of the garment fit (regular and loose) and style (t-shirts, sweatpants, jacket and trousers) were analysed for the interaction between the body postures and the garment properties. A flexible manikin was scanned using a three-dimensional (3D) body scanning technique, and the scans were post-processed in dedicated software. The body posture had a strong effect on the air gap thickness and the contact area for regions where the garment had a certain distance from the body. Furthermore, a mathematical model was proposed to estimate the possible heat transfer coefficient for the observed air layers and their change with posture. The outcome of this study can be used to improve the design of the protective and functional garments and predict their effect on the human body.

Noncontact Infrared-Mediated Heat Transfer During Continuous Freeze-Drying of Unit Doses.

PubMed

Van Bockstal, Pieter-Jan; De Meyer, Laurens; Corver, Jos; Vervaet, Chris; De Beer, Thomas

2017-01-01

Recently, an innovative continuous freeze-drying concept for unit doses was proposed, based on spinning the vials during freezing. An efficient heat transfer during drying is essential to continuously process these spin frozen vials. Therefore, the applicability of noncontact infrared (IR) radiation was examined. The impact of several process and formulation variables on the mass of sublimed ice after 15 min of primary drying (i.e., sublimation rate) and the total drying time was examined. Two experimental designs were performed in which electrical power to the IR heaters, distance between the IR heaters and the spin frozen vial, chamber pressure, product layer thickness, and 5 model formulations were included as factors. A near-infrared spectroscopy method was developed to determine the end point of primary and secondary drying. The sublimation rate was mainly influenced by the electrical power to the IR heaters and the distance between the IR heaters and the vial. The layer thickness had the largest effect on total drying time. The chamber pressure and the 5 model formulations had no significant impact on sublimation rate and total drying time, respectively. This study shows that IR radiation is suitable to provide the energy during the continuous processing of spin frozen vials. Copyright © 2016 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

Turbulent boundary layer heat transfer experiments: Convex curvature effects, including introduction and recovery

NASA Technical Reports Server (NTRS)

Simon, T. W.; Moffat, R. J.; Johnston, J. P.; Kays, W. M.

1980-01-01

Heat transfer rates were measured through turbulent and transitional boundary layers on an isothermal, convexly curved wall and downstream flat plate. The effect of convex curvature on the fully turbulent boundary layer was a reduction of the local Stanton numbers 20-50% below those predicted for a flat wall under the same circumstances. The recovery of the heat transfer rates on the downstream flat wall was extremely slow. After 60 cm of recovery length, the Stanton number was still typically 15-20% below the flat wall predicted value. Various effects important in the modeling of curved flows were studied separately. These are: (1) the effect of initial boundary layer thickness; (2) the effect of freestream velocity; (3) the effect of freestream acceleration; (4) the effect of unheated starting length; and (5) the effect of the maturity of the boundary layer. Regardless of the initial state, curvature eventually forced the boundary layer into an asymptotic curved condition. The slope, minus one, is believed to be significant.

Inter-layer and intra-layer heat transfer in bilayer/monolayer graphene van der Waals heterostructure: Is there a Kapitza resistance analogous?

NASA Astrophysics Data System (ADS)

Rajabpour, Ali; Fan, Zheyong; Vaez Allaei, S. Mehdi

2018-06-01

Van der Waals heterostructures have exhibited interesting physical properties. In this paper, heat transfer in hybrid coplanar bilayer/monolayer (BL-ML) graphene, as a model layered van der Waals heterostructure, was studied using non-equilibrium molecular dynamics (MD) simulations. The temperature profile and inter- and intra-layer heat fluxes of the BL-ML graphene indicated that, there is no fully developed thermal equilibrium between layers and the drop in the average temperature profile at the step-like BL-ML interface is not attributable to the effect of Kapitza resistance. By increasing the length of the system up to 1 μm in the studied MD simulations, the thermally non-equilibrium region was reduced to a small area near the step-like interface. All MD results were compared to a continuum model and a good match was observed between the two approaches. Our results provide a useful understanding of heat transfer in nano- and micro-scale layered materials and van der Waals heterostructures.

Enhanced interfacial electron transfer of inverted perovskite solar cells by introduction of CoSe into the electron-transporting-layer

NASA Astrophysics Data System (ADS)

Chen, Shanshan; Yang, Songwang; Sun, Hong; Zhang, Lu; Peng, Jiajun; Liang, Ziqi; Wang, Zhong-Sheng

2017-06-01

To improve the electron transfer at the interface between the perovskite film and the electron-transporting-material (ETM) layer, CoSe doped [6,6]-phenyl C61-butyric acid methyl ester (PCBM) is employed as the ETM layer for the inverted planar perovskite solar cell with NiO as the hole-transporting-material layer. Introduction of CoSe (5.8 wt%) into the PCBM layer improves the conductivity of the ETM layer and decreases the photoluminescence intensity, thus enhancing the interfacial electron extraction and reducing the electron transfer resistance at the perovskite/ETM interface. As a consequence, the power conversion efficiency is enhanced from 11.43% to 14.91% by 30% due to the noted increases in short-circuit current density from 17.95 mA cm-2 to 19.85 mA cm-2 and fill factor from 0.60 to 0.70. This work provides a new strategy to improve the performance of inverted perovskite solar cells.

The Compressible Laminar Boundary Layer with Heat Transfer and Arbitrary Pressure Gradient

NASA Technical Reports Server (NTRS)

Cohen, Clarence B; Reshotko, Eli

1956-01-01

An approximate method for the calculation of the compressible laminar boundary layer with heat transfer and arbitrary pressure gradient, based on Thwaites' correlation concept, is presented. With the definition of dimensionless shear and heat-transfer parameters and an assumed correlation of these parameters in terms of a momentum parameter, a complete system of relations for calculating skin friction and heat transfer results. Knowledge of velocity or temperature profiles is not necessary in using this calculation method. When the method is applied to a convergent-divergent, axially symmetric rocket nozzle, it shows that high rates of heat transfer are obtained at the initial stagnation point and at the throat of the nozzle. Also indicated are negative displacement thicknesses in the convergent portion of the nozzle; these occur because of the high density within the lower portions of the cooled boundary layer. (author)

Giant magneto-spin-Seebeck effect and magnon transfer torques in insulating spin valves

NASA Astrophysics Data System (ADS)

Cheng, Yihong; Chen, Kai; Zhang, Shufeng

2018-01-01

We theoretically study magnon transport in an insulating spin valve (ISV) made of an antiferromagnetic insulator sandwiched between two ferromagnetic insulator (FI) layers. In the conventional metal-based spin valve, the electron spins propagate between two metallic ferromagnetic layers, giving rise to giant magnetoresistance and spin transfer torque. Here, the incoherent magnons in the ISV serve as angular momentum carriers and are responsible for the angular momentum transport between two FI layers across the antiferromagnetic spacer. We predict two transport phenomena in the presence of the temperature gradient: a giant magneto-spin-Seebeck effect in which the output voltage signal is controlled by the relative orientation of the two FI layers and magnon transfer torque that can be used for switching the magnetization of the FI layers with a temperature gradient of the order of 0.1 Kelvin per nanometer.

Flux-transfer losses in helically wound superconducting power cables

DOE Office of Scientific and Technical Information (OSTI.GOV)

Clem, John R; Malozemoff, A P

2013-06-25

Minimization of ac losses is essential for economic operation of high-temperature superconductor (HTS) ac power cables. A favorable configuration for the phase conductor of such cables has two counter-wound layers of HTS tape-shaped wires lying next to each other and helically wound around a flexible cylindrical former. However, if magnetic materials such as magnetic substrates of the tapes lie between the two layers, or if the winding pitch angles are not opposite and essentially equal in magnitude to each other, current distributes unequally between the two layers. Then, if at some point in the ac cycle the current of eithermore » of the two layers exceeds its critical current, a large ac loss arises from the transfer of flux between the two layers. A detailed review of the formalism, and its application to the case of paramagnetic substrates including the calculation of this flux-transfer loss, is presented.« less

Simultaneous Heat and Mass Transfer Model for Convective Drying of Building Material

NASA Astrophysics Data System (ADS)

Upadhyay, Ashwani; Chandramohan, V. P.

2018-04-01

A mathematical model of simultaneous heat and moisture transfer is developed for convective drying of building material. A rectangular brick is considered for sample object. Finite-difference method with semi-implicit scheme is used for solving the transient governing heat and mass transfer equation. Convective boundary condition is used, as the product is exposed in hot air. The heat and mass transfer equations are coupled through diffusion coefficient which is assumed as the function of temperature of the product. Set of algebraic equations are generated through space and time discretization. The discretized algebraic equations are solved by Gauss-Siedel method via iteration. Grid and time independent studies are performed for finding the optimum number of nodal points and time steps respectively. A MATLAB computer code is developed to solve the heat and mass transfer equations simultaneously. Transient heat and mass transfer simulations are performed to find the temperature and moisture distribution inside the brick.

Jason Woods | NREL

Science.gov Websites

doctoral student since 2007. Jason's area of expertise is heat and mass transfer, including the design , analysis, and testing of heat and mass transfer devices and processes. Research Interests Membrane Thermal energy storage Heat and mass transfer enhancements Combined cooling, heat, and power (CCHP

Venting and High Vacuum Performance of Low Density Multilayer Insulation

NASA Astrophysics Data System (ADS)

Riesco, M. E.; McLean, C. H.; Mills, G. L.; Buerger, S.; Meyer, M. L.

2010-04-01

The NASA Exploration Program is currently studying the use liquid oxygen, liquid methane and liquid hydrogen for propulsion in future spacecraft for Exploration of the Moon and Mars. This will require the efficient long term, on-orbit storage of these cryogenic propellants. Multilayer Insulation (MLI) will be critical to achieving the required thermal performance since it has much lower heat transfer than any other insulation when used in a vacuum. MLI with a low density (⩽10 layers/cm) has been shown in previous work to be the most mass efficient. The size and mass constraints of these propulsion systems will not allow a structural shell to be used to provide vacuum for the MLI during ground hold and launch. The baseline approach is to purge the MLI during ground hold with an inert gas which is then vented during launch ascent and on-orbit. This paper presents the results on experimental tests and modeling performed by Ball Aerospace on low density, non-perforated MLI used to insulate a cryogenic tank simulating an Exploration cryogenic propellant storage vessel. These include measurements of the rate of venting and of the heat transfer of gas filled insulation, fully evacuated insulation and during the transition in between. Results of transient computer modeling of the MLI venting and heat transfer process are also presented. Previous work by some of the authors performed vent testing using MLI with perforations and slits and a slow pump down rate.

Modeling of trim panels in the energy finite element analysis

NASA Astrophysics Data System (ADS)

Moravaeji, Seyed-Javid

Modeling a trim panel is divided into finding the power exchange through two different paths: (i) the connection of the outer and inner panels (ii) through the layers directly. The vibrational power exchanged through the mounts is modeled as the connection of two parallel plates connected via a beam. Wave matrices representing plates and beams are derived separately; then a matrix method is proposed to solve for the wave amplitudes and hence the vibrational power exchange between the plates accordingly. A closed form formula for the case of connection of two identical plates is derived. For the power transmission loss directly through the layers, first transfer matrices representing layers made of different materials is considered. New matrices for a porous layer are derived. A method of finding the layered structure transfer matrix is proposed. It is concluded that in general a single isotropic layer cannot replace a structure accurately. Finally, on the basis of an equivalent transfer matrix, an optimization process for is proposed to replace the panel by a suitable set of layers.

Thermal stratification in LH2 tank of cryogenic propulsion stage tested in ISRO facility

NASA Astrophysics Data System (ADS)

Xavier, M.; Raj, R. Edwin; Narayanan, V.

2017-02-01

Liquid oxygen and hydrogen are used as oxidizer and fuel respectively in cryogenic propulsion system. These liquids are stored in foam insulated tanks of cryogenic propulsion system and are pressurized using warm pressurant gas supplied for tank pressure maintenance during cryogenic engine operation. Heat leak to cryogenic propellant tank causes buoyancy driven liquid stratification resulting in formation of warm liquid stratum at liquid free surface. This warm stratum is further heated by the admission of warm pressurant gas for tank pressurization during engine operation. Since stratified layer temperature has direct bearing on the cavitation free operation of turbo pumps integrated in cryogenic engine, it is necessary to model the thermal stratification for predicting stratified layer temperature and mass of stratified liquid in tank at the end of engine operation. These inputs are required for estimating the minimum pressure to be maintained by tank pressurization system. This paper describes configuration of cryogenic stage for ground qualification test, stage hot test sequence, a thermal model and its results for a foam insulated LH2 tank subjected to heat leak and pressurization with hydrogen gas at 200 K during liquid outflow at 38 lps for engine operation. The above model considers buoyancy flow in free convection boundary layer caused by heat flux from tank wall and energy transfer from warm pressurant gas etc. to predict temperature of liquid stratum and mass of stratified liquid in tank at the end of engine operation in stage qualification tests carried out in ISRO facility.

An Analytic Approach to Modeling Land-Atmosphere Interaction: 1. Construct and Equilibrium Behavior

NASA Astrophysics Data System (ADS)

Brubaker, Kaye L.; Entekhabi, Dara

1995-03-01

A four-variable land-atmosphere model is developed to investigate the coupled exchanges of water and energy between the land surface and atmosphere and the role of these exchanges in the statistical behavior of continental climates. The land-atmosphere system is substantially simplified and formulated as a set of ordinary differential equations that, with the addition of random noise, are suitable for analysis in the form of the multivariate Îto equation. The model treats the soil layer and the near-surface atmosphere as reservoirs with storage capacities for heat and water. The transfers between these reservoirs are regulated by four states: soil saturation, soil temperature, air specific humidity, and air potential temperature. The atmospheric reservoir is treated as a turbulently mixed boundary layer of fixed depth. Heat and moisture advection, precipitation, and layer-top air entrainment are parameterized. The system is forced externally by solar radiation and the lateral advection of air and water mass. The remaining energy and water mass exchanges are expressed in terms of the state variables. The model development and equilibrium solutions are presented. Although comparisons between observed data and steady state model results re inexact, the model appears to do a reasonable job of partitioning net radiation into sensible and latent heat flux in appropriate proportions for bare-soil midlatitude summer conditions. Subsequent work will introduce randomness into the forcing terms to investigate the effect of water-energy coupling and land-atmosphere interaction on variability and persistence in the climatic system.

Charge transfer efficiency improvement of 4T pixel for high speed CMOS image sensor

NASA Astrophysics Data System (ADS)

Jin, Xiangliang; Liu, Weihui; Yang, Hongjiao; Tang, Lizhen; Yang, Jia

2015-03-01

The charge transfer efficiency improvement method is proposed by optimizing the electrical potential distribution along the transfer path from the PPD to the FD. In this work, we present a non-uniform doped transfer transistor channel, with the adjustments to the overlap length between the CPIA layer and the transfer gate, and the overlap length between the SEN layer and transfer gate. Theory analysis and TCAD simulation results show that the density of the residual charge reduces from 1e11 /cm3 to 1e9 /cm3, and the transfer time reduces from 500 ns to 143 ns, and the charge transfer efficiency is about 77 e-/ns. This optimizing design effectively improves the charge transfer efficiency of 4T pixel and the performance of 4T high speed CMOS image sensor.

The role of intra-NAPL diffusion on mass transfer from MGP residuals

NASA Astrophysics Data System (ADS)

Shafieiyoun, Saeid; Thomson, Neil R.

2018-06-01

An experimental and computational study was performed to investigate the role of multi-component intra-NAPL diffusion on NAPL-water mass transfer. Molecular weight and the NAPL component concentrations were determined to be the most important parameters affecting intra-NAPL diffusion coefficients. Four NAPLs with different viscosities but the same quantified mass were simulated. For a spherical NAPL body, a combination of NAPL properties and interphase mass transfer rate can result in internal diffusion limitations. When the main intra-NAPL diffusion coefficients are in the range of self-diffusion coefficients (10-5 to 10-6 cm2/s), dissolution is not limited by internal diffusion except for high mass transfer rate coefficients (>180 cm/day). For a complex and relatively high viscous NAPL (>50 g/(cm s)), smaller intra-NAPL diffusion coefficients (<10-8) are expected and even low mass transfer rate coefficients ( 6 cm/day) can result in diffusion-limited dissolution.

International Space Station (ISS) Water Transfer Hardware Logistics

NASA Technical Reports Server (NTRS)

Shkedi, Brienne D.

2006-01-01

Water transferred from the Space Shuttle to the International Space Station (ISS) is generated as a by-product from the Shuttle fuel cells, and is generally preferred over the Progress which has to launch water from the ground. However, launch mass and volume are still required for the transfer and storage hardware. Some of these up-mass requirements have been reduced since ISS assembly began due to changes in the storage hardware (CWC). This paper analyzes the launch mass and volume required to transfer water from the Shuttle and analyzes the up-mass savings due to modifications in the CWC. Suggestions for improving the launch mass and volume are also provided.

Heat and Mass Transfer in an L Shaped Porous Medium

NASA Astrophysics Data System (ADS)

Salman Ahmed, N. J.; Azeem; Yunus Khan, T. M.

2017-08-01

This article is an extension to the heat transfer in L-shaped porous medium by including the mass diffusion. The heat and mass transfer in the porous domain is represented by three coupled partial differential equations representing the fluid movement, energy transport and mass transport. The equations are converted into algebraic form of equations by the application of finite element method that can be conveniently solved by matrix method. An iterative approach is adopted to solve the coupled equations by setting suitable convergence criterion. The results are discussed in terms of heat transfer characteristics influenced by physical parameters such as buoyancy ratio, Lewis number, Rayleigh number etc. It is found that these physical parameters have significant effect on heat and mass transfer behavior of L-shaped porous medium.

Electrical characterization of non‐Fickian transport in groundwater and hyporheic systems

USGS Publications Warehouse

Singha, Kamini; Pidlisecky, Adam; Day-Lewis, Frederick D.; Gooseff, Michael N.

2008-01-01

Recent work indicates that processes controlling solute mass transfer between mobile and less mobile domains in porous media may be quantified by combining electrical geophysical methods and electrically conductive tracers. Whereas direct geochemical measurements of solute preferentially sample the mobile domain, electrical geophysical methods are sensitive to changes in bulk electrical conductivity (bulk EC) and therefore sample EC in both the mobile and immobile domains. Consequently, the conductivity difference between direct geochemical samples and remotely sensed electrical geophysical measurements may provide an indication of mass transfer rates and mobile and immobile porosities in situ. Here we present (1) an overview of a theoretical framework for determining parameters controlling mass transfer with electrical resistivity in situ; (2) a review of a case study estimating mass transfer processes in a pilot‐scale aquifer storage recovery test; and (3) an example application of this method for estimating mass transfer in watershed settings between streams and the hyporheic corridor. We demonstrate that numerical simulations of electrical resistivity studies of the stream/hyporheic boundary can help constrain volumes and rates of mobile‐immobile mass transfer. We conclude with directions for future research applying electrical geophysics to understand field‐scale transport in aquifer and fluvial systems subject to rate‐limited mass transfer.

Air sparging: Air-water mass transfer coefficients

NASA Astrophysics Data System (ADS)

Braida, Washington J.; Ong, Say Kee

1998-12-01

Experiments investigating the mass transfer of several dissolved volatile organic compounds (VOCs) across the air-water interface were conducted using a single-air- channel air-sparging system. Three different porous media were used in the study. Air velocities ranged from 0.2 cm s-1 to 2.5 cm s-1. The tortuosity factor for each porous medium and the air-water mass transfer coefficients were estimated by fitting experimental data to a one-dimensional diffusion model. The estimated mass transfer coefficients KG ranged from 1.79 × 10-3 cm min-1 to 3.85 × 10-2 cm min-1. The estimated lumped gas phase mass transfer coefficients KGa were found to be directly related to the air diffusivity of the VOC, air velocity, and particle size, and inversely related to the Henry's law constant of the VOCs. Of the four parameters investigated, the parameter that controlled or had a dominant effect on the lumped gas phase mass transfer coefficient was the air diffusivity of the VOC. Two empirical models were developed by correlating the Damkohler and the modified air phase Sherwood numbers with the air phase Peclet number, Henry's law constant, and the reduced mean particle size of porous media. The correlation developed in this study may be used to obtain better predictions of mass transfer fluxes for field conditions.

Investigations of effect of phase change mass transfer rate on cavitation process with homogeneous relaxation model

DOE Office of Scientific and Technical Information (OSTI.GOV)

He, Zhixia; Zhang, Liang; Saha, Kaushik

The super high fuel injection pressure and micro size of nozzle orifice has been an important development trend for the fuel injection system. Accordingly, cavitation transient process, fuel compressibility, amount of noncondensable gas in the fuel and cavitation erosion have attracted more attention. Based on the fact of cavitation in itself is a kind of thermodynamic phase change process, this paper takes the perspective of the cavitation phase change mass transfer process to analyze above mentioned phenomenon. The two-phase cavitating turbulent flow simulations with VOF approach coupled with HRM cavitation model and U-RANS of standard k-ε turbulence model were performedmore » for investigations of cavitation phase change mass transfer process. It is concluded the mass transfer time scale coefficient in the Homogenous Relaxation Model (HRM) representing mass transfer rate should tend to be as small as possible in a condition that ensured the solver stable. At very fast mass transfer rate, the phase change occurs at very thin interface between liquid and vapor phase and condensation occurs more focused and then will contribute predictably to a more serious cavitation erosion. Both the initial non-condensable gas in fuel and the fuel compressibility can accelerate the cavitation mass transfer process.« less

Thermo-fluid-dynamics of turbulent boundary layer over a moving continuous flat sheet in a parallel free stream

NASA Astrophysics Data System (ADS)

Afzal, Bushra; Noor Afzal Team; Bushra Afzal Team

2014-11-01

The momentum and thermal turbulent boundary layers over a continuous moving sheet subjected to a free stream have been analyzed in two layers (inner wall and outer wake) theory at large Reynolds number. The present work is based on open Reynolds equations of momentum and heat transfer without any closure model say, like eddy viscosity or mixing length etc. The matching of inner and outer layers has been carried out by Izakson-Millikan-Kolmogorov hypothesis. The matching for velocity and temperature profiles yields the logarithmic laws and power laws in overlap region of inner and outer layers, along with friction factor and heat transfer laws. The uniformly valid solution for velocity, Reynolds shear stress, temperature and thermal Reynolds heat flux have been proposed by introducing the outer wake functions due to momentum and thermal boundary layers. The comparison with experimental data for velocity profile, temperature profile, skin friction and heat transfer are presented. In outer non-linear layers, the lowest order momentum and thermal boundary layer equations have also been analyses by using eddy viscosity closure model, and results are compared with experimental data. Retired Professor, Embassy Hotel, Rasal Ganj, Aligarh 202001 India.

Lag and light-transfer characteristics of amorphous selenium photoconductive film with tellurium-doped layer

NASA Astrophysics Data System (ADS)

Park, Wug-Dong; Tanioka, Kenkichi

2016-07-01

Amorphous selenium (a-Se) high-gain avalanche rushing amorphous photoconductor (HARP) films have been used for highly sensitive imaging devices. To study a-Se HARP films for a solid-state image sensor, current-voltage, lag, spectral response, and light-transfer characteristics of 0.4-µm-thick a-Se HARP films are investigated. Also, to clarify a suitable Te-doped a-Se layer thickness in the a-Se photoconductor, we considered the effects of Te-doped layer thickness on the lag, spectral response, and light-transfer characteristics of 0.4-µm-thick a-Se HARP films. The threshold field, at which avalanche multiplication occurs in the a-Se HARP targets, decreases when the Te-doped layer thickness increases. The lag of 0.4-µm-thick a-Se HARP targets with Te-doped layers is higher than that of the target without Te doping. The lag of the targets with Te-doped layers is caused by the electrons trapped in the Te-doped layers within the 0.4-µm-thick a-Se HARP films. From the results of the spectral response measurement of about 15 min, the 0.4-µm-thick a-Se HARP targets with Te-doped layers of 90 and 120 nm are observed to be unstable owing to the electrons trapped in the Te-doped a-Se layer. From the light-transfer characteristics of 0.4-µm-thick a-Se HARP targets, as the slope at the operating point of signal current-voltage characteristics in the avalanche mode increases, the γ of the a-Se HARP targets decreases. Considering the effects of dark current on the lag and spectral response characteristics, a Te-doped layer of 60 nm is suitable for 0.4-µm-thick a-Se HARP films.

Approximate Solution Methods for Spectral Radiative Transfer in High Refractive Index Layers

NASA Technical Reports Server (NTRS)

Siegel, R.; Spuckler, C. M.

1994-01-01

Some ceramic materials for high temperature applications are partially transparent for radiative transfer. The refractive indices of these materials can be substantially greater than one which influences internal radiative emission and reflections. Heat transfer behavior of single and laminated layers has been obtained in the literature by numerical solutions of the radiative transfer equations coupled with heat conduction and heating at the boundaries by convection and radiation. Two-flux and diffusion methods are investigated here to obtain approximate solutions using a simpler formulation than required for exact numerical solutions. Isotropic scattering is included. The two-flux method for a single layer yields excellent results for gray and two band spectral calculations. The diffusion method yields a good approximation for spectral behavior in laminated multiple layers if the overall optical thickness is larger than about ten. A hybrid spectral model is developed using the two-flux method in the optically thin bands, and radiative diffusion in bands that are optically thick.

Method of using a germanium layer transfer to Si for photovoltaic applications and heterostructure made thereby

DOEpatents

Atwater, Jr., Harry A.; Zahler, James M.

2006-11-28

Ge/Si and other nonsilicon film heterostructures are formed by hydrogen-induced exfoliation of the Ge film which is wafer bonded to a cheaper substrate, such as Si. A thin, single-crystal layer of Ge is transferred to Si substrate. The bond at the interface of the Ge/Si heterostructures is covalent to ensure good thermal contact, mechanical strength, and to enable the formation of an ohmic contact between the Si substrate and Ge layers. To accomplish this type of bond, hydrophobic wafer bonding is used, because as the invention demonstrates the hydrogen-surface-terminating species that facilitate van der Waals bonding evolves at temperatures above 600.degree. C. into covalent bonding in hydrophobically bound Ge/Si layer transferred systems.

Nonradiative Energy Transfer from Individual CdSe/ZnS Quantum Dots to Single-Layer and Few-Layer Tin Disulfide

DOE PAGES

Zang, Huidong; Routh, Prahlad K.; Huang, Yuan; ...

2016-03-31

We study the combination of zero-dimensional (0D) colloidal CdSe/ZnS quantum dots with tin disulfide (SnS 2), a two-dimensional (2D)-layered metal dichalcogenide, results in 0D–2D hybrids with enhanced light absorption properties. These 0D–2D hybrids, when exposed to light, exhibit intrahybrid nonradiative energy transfer from photoexcited CdSe/ZnS quantum dots to SnS 2. Using single nanocrystal spectroscopy, we find that the rate for energy transfer in 0D–2D hybrids increases with added number of SnS 2 layers, a positive manifestation toward the potential functionality of such 2D-based hybrids in applications such as photovoltaics and photon sensing.

Nonradiative Energy Transfer from Individual CdSe/ZnS Quantum Dots to Single-Layer and Few-Layer Tin Disulfide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zang, Huidong; Routh, Prahlad K.; Huang, Yuan

We study the combination of zero-dimensional (0D) colloidal CdSe/ZnS quantum dots with tin disulfide (SnS 2), a two-dimensional (2D)-layered metal dichalcogenide, results in 0D–2D hybrids with enhanced light absorption properties. These 0D–2D hybrids, when exposed to light, exhibit intrahybrid nonradiative energy transfer from photoexcited CdSe/ZnS quantum dots to SnS 2. Using single nanocrystal spectroscopy, we find that the rate for energy transfer in 0D–2D hybrids increases with added number of SnS 2 layers, a positive manifestation toward the potential functionality of such 2D-based hybrids in applications such as photovoltaics and photon sensing.

Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Frameworks- like Materials: Solar Energy Capture and Directional Energy Transfer

DOE PAGES

Park, Hea Jung; So, Monica C.; Gosztola, David J.

2016-09-28

We demonstrate that thin films of metal organic framework (MOF)-like materials, containing two perylenedlimides (PDICl4, PDIOPh2) and a squaraine dye (S1); can be fabricated by, layer-by-layer assembly (LbL). Interestingly, these LbL films absorb across the visible light region (400-750 nm) and facilitate directional energy transfer. Due to the high spectral overlap and oriented transition dipole moments of the donor (PDICl4 and PDIOPh2) and acceptor (S1) components, directional long-range energy transfer from the bluest to reddest absorber was successfully demonstrated in the multicomponent MOF-like films. These findings have significant implications for the development of solar energy conversion devices based on MOFs.

Mass Transfer Limited Enhanced Bioremediation at Dnapl Source Zones: a Numerical Study

NASA Astrophysics Data System (ADS)

Kokkinaki, A.; Sleep, B. E.

2011-12-01

The success of enhanced bioremediation of dense non-aqueous phase liquids (DNAPLs) relies on accelerating contaminant mass transfer from the organic to the aqueous phase, thus enhancing the depletion of DNAPL source zones compared to natural dissolution. This is achieved by promoting biological activity that reduces the contaminant's aqueous phase concentration. Although laboratory studies have demonstrated that high reaction rates are attainable by specialized microbial cultures in DNAPL source zones, field applications of the technology report lower reaction rates and prolonged remediation times. One possible explanation for this phenomenon is that the reaction rates are limited by the rate at which the contaminant partitions from the DNAPL to the aqueous phase. In such cases, slow mass transfer to the aqueous phase reduces the bioavailability of the contaminant and consequently decreases the potential source zone depletion enhancement. In this work, the effect of rate limited mass transfer on bio-enhanced dissolution of DNAPL chlorinated ethenes is investigated through a numerical study. A multi-phase, multi-component groundwater transport model is employed to simulate DNAPL mass depletion for a range of source zone scenarios. Rate limited mass transfer is modeled by a linear driving force model, employing a thermodynamic approach for the calculation of the DNAPL - water interfacial area. Metabolic reductive dechlorination is modeled by Monod kinetics, considering microbial growth and self-inhibition. The model was utilized to identify conditions in which mass transfer, rather than reaction, is the limiting process, as indicated by the bioavailability number. In such cases, reaction is slower than expected, and further increase in the reaction rate does not enhance mass depletion. Mass transfer rate limitations were shown to affect both dechlorination and microbial growth kinetics. The complex dynamics between mass transfer, DNAPL transport and distribution, and dechlorination kinetics were reflected in a transient, spatially heterogeneous bioavailability number and dissolution enhancement. In agreement with the literature, source zone architecture largely determined the impact of mass transfer on potential dissolution enhancement, with bioavailability decreasing the most at high ganglia to pool ratios. The results of this study suggest that if mass transfer rate limitations are not considered in designing bioremediation applications at DNAPL source zones, the enhancement of DNAPL depletion and the overall effectiveness of enhanced bioremediation may be significantly overestimated.

On optical imaging through aircraft turbulent boundary layers

NASA Technical Reports Server (NTRS)

Sutton, G. W.

1980-01-01

Optical resolution quality as affected by aircraft turbulent boundary layers is analyzed. Wind-tunnel data was analyzed to obtained the variation of boundary layer turbulence scale length and mass density rms fluctuations with Mach number. The data gave good agreement with a mass density fluctuation turbulence spectrum that is either isotropic of orthogonally anisotropic. The data did not match an isotropic turbulence velocity spectrum which causes an anisotropic non-orthogonal mass density fluctuation spectrum. The results indicate that the average mass density rms fluctuation is about 10% of the maximum mass density across the boundary layer and that the transverse turbulence scale size is about 10% of the boundary layer thickness. The results indicate that the effect of the turbulent boundary layer is large angle scattering which decreases contrast but not resolution. Using extinction as a criteria the range of acceptable aircraft operating conditions are given.

Shuttle Damage/Repair from the Perspective of Hypersonic Boundary Layer Transition - Experimental Results

NASA Technical Reports Server (NTRS)

Horvath, Thomas J.; Berry, Scott A.; Merski, N. Ronald; Berger, Karen T.; Buck, Gregory M.; Liechty, Derek S.; Schneider, Steven P.

2006-01-01

An overview is provided of the experimental wind tunnel program conducted at the NASA Langley Research Center Aerothermodynamics Laboratory in support of an agency-wide effort to prepare the Shuttle Orbiter for Return-to-Flight. The effect of an isolated protuberance and an isolated rectangular cavity on hypersonic boundary layer transition onset on the windward surface of the Shuttle Orbiter has been experimentally characterized. These experimental studies were initiated to provide a protuberance and cavity effects database for developing hypersonic transition criteria to support on-orbit disposition of thermal protection system damage or repair. In addition, a synergistic experimental investigation was undertaken to assess the impact of an isolated mass-flow entrainment source (simulating pyrolysis/outgassing from a proposed tile repair material) on boundary layer transition. A brief review of the relevant literature regarding hypersonic boundary layer transition induced from cavities and localized mass addition from ablation is presented. Boundary layer transition results were obtained using 0.0075-scale Orbiter models with simulated tile damage (rectangular cavities) of varying length, width, and depth and simulated tile damage or repair (protuberances) of varying height. Cavity and mass addition effects were assessed at a fixed location (x/L = 0.3) along the model centerline in a region of near zero pressure gradient. Cavity length-to-depth ratio was systematically varied from 2.5 to 17.7 and length-to-width ratio of 1 to 8.5. Cavity depth-to-local boundary layer thickness ranged from 0.5 to 4.8. Protuberances were located at several sites along the centerline and port/starboard attachment lines along the chine and wing leading edge. Protuberance height-to-boundary layer thickness was varied from approximately 0.2 to 1.1. Global heat transfer images and heating distributions of the Orbiter windward surface using phosphor thermography were used to infer the state of the boundary layer (laminar, transitional, or turbulent). Test parametrics include angles-of-attack of 30 deg and 40 deg, sideslip angle of 0 deg, freestream Reynolds numbers from 0.02x106 to 7.3x106 per foot, edge-to-wall temperature ratio from 0.4 to 0.8, and normal shock density ratios of approximately 5.3, 6.0, and 12 in Mach 6 air, Mach 10 air, and Mach 6 CF4, respectively. Testing to simulate the effects of ablation from a proposed tile repair concept indicated that transition was not a concern. The experimental protuberance and cavity databases highlighted in this report were used to formulate boundary layer transition correlations that were an integral part of an analytical process to disposition observed Orbiter TPS damage during STS- 114.

Capillary electrophoresis electrospray ionization mass spectrometry interface

DOEpatents

Smith, Richard D.; Severs, Joanne C.

1999-01-01

The present invention is an interface between a capillary electrophoresis separation capillary end and an electrospray ionization mass spectrometry emitter capillary end, for transporting an anolyte sample from a capillary electrophoresis separation capillary to a electrospray ionization mass spectrometry emitter capillary. The interface of the present invention has: (a) a charge transfer fitting enclosing both of the capillary electrophoresis capillary end and the electrospray ionization mass spectrometry emitter capillary end; (b) a reservoir containing an electrolyte surrounding the charge transfer fitting; and (c) an electrode immersed into the electrolyte, the electrode closing a capillary electrophoresis circuit and providing charge transfer across the charge transfer fitting while avoiding substantial bulk fluid transfer across the charge transfer fitting. Advantages of the present invention have been demonstrated as effective in providing high sensitivity and efficient analyses.

Murt user`s guide: A hybrid Lagrangian-Eulerian finite element model of multiple-pore-region solute transport through subsurface media

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gwo, J.P.; Jardine, P.M.; Yeh, G.T.

Matrix diffusion, a diffusive mass transfer process,in the structured soils and geologic units at ORNL, is believe to be an important subsurface mass transfer mechanism; it may affect off-site movement of radioactive wastes and remediation of waste disposal sites by locally exchanging wastes between soil/rock matrix and macropores/fractures. Advective mass transfer also contributes to waste movement but is largely neglected by researchers. This report presents the first documented 2-D multiregion solute transport code (MURT) that incorporates not only diffusive but also advective mass transfer and can be applied to heterogeneous porous media under transient flow conditions. In this report, theoreticalmore » background is reviewed and the derivation of multiregion solute transport equations is presented. Similar to MURF (Gwo et al. 1994), a multiregion subsurface flow code, multiplepore domains as suggested by previous investigators (eg, Wilson and Luxmoore 1988) can be implemented in MURT. Transient or steady-state flow fields of the pore domains can be either calculated by MURF or by modelers. The mass transfer process is briefly discussed through a three-pore-region multiregion solute transport mechanism. Mass transfer equations that describe mass flux across pore region interfaces are also presented and parameters needed to calculate mass transfer coefficients detailed. Three applications of MURT (tracer injection problem, sensitivity analysis of advective and diffusive mass transfer, hillslope ponding infiltration and secondary source problem) were simulated and results discussed. Program structure of MURT and functions of MURT subroutiness are discussed so that users can adapt the code; guides for input data preparation are provided in appendices.« less

Group solution for unsteady free-convection flow from a vertical moving plate subjected to constant heat flux

NASA Astrophysics Data System (ADS)

Kassem, M.

2006-03-01

The problem of heat and mass transfer in an unsteady free-convection flow over a continuous moving vertical sheet in an ambient fluid is investigated for constant heat flux using the group theoretical method. The nonlinear coupled partial differential equation governing the flow and the boundary conditions are transformed to a system of ordinary differential equations with appropriate boundary conditions. The obtained ordinary differential equations are solved numerically using the shooting method. The effect of Prandlt number on the velocity and temperature of the boundary-layer is plotted in curves. A comparison with previous work is presented.

Quantification of the Mass Transfer at Fluid Interfaces in Microfluidic Channels

NASA Astrophysics Data System (ADS)

Wismeth, Carina; Manhart, Michael; Niessner, Reinhard; Baumann, Thomas

2017-04-01

Mass transfer rates at interfaces in a complex porous media are relevant in many environmental applications and control the functions of natural filter systems in subsurface environments. The mass transfer at fluid interfaces is associated with interface convection caused by local inhomogeneities in interface tension and hydrodynamic instabilities at the interface. If there is a surface tension gradient along the surface a shear stress jump is generated that results in fluid motion along the surface that is called Marangoni effect. These spontaneous convection currents can lead to an increased mass transfer of the transition component at the phase boundary and to an increased mixing of the phases. Therefore compensatory currents at the interface can have a significant influence on the subsurface transport of contaminants in the groundwater area, especially in the vadose zone. Using microfluidic channels and advanced experimental techniques it is possible to measure the fluid flow and mass transfer rates directly and to quantify the effect of the Marangoni convection on the mass transfer at interfaces between a non-aqueous liquid and water with high temporal and spatial resolution. The use of fluorescent particles as well as the recording and analysis of their trajectories is intended to visualize interfacial processes and to quantify the mass transfer at fluid phase boundaries. Concentration gradients at the interface are analysed by spectroscopic methods and allow an assessment of the enrichment and depletion at the phase boundaries. Extensive test series provide the experimental basis for quantifying and analysing the impact of the Marangoni effect on the mass transfer rates at interfaces in porous media in subsurface aquatic environments. Within this research project we concentrate on the effect of Marangoni convection on the mass transfer near an 1-octanol-water interface, which serves as a well defined proxy for non-aqueous phase liquids in porous media. Experiments and a numerical simulation are closely coupled to provide a generic data set with high reproducibility and used to obtain highly resolved three-dimensional data of mass transfer in two- and three-phase systems to foster the understanding of subsurface transport, especially in the vadose zone.

Deposition of thin silicon layers on transferred large area graphene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lupina, Grzegorz, E-mail: lupina@ihp-microelectronics.com; Kitzmann, Julia; Lukosius, Mindaugas

2013-12-23

Physical vapor deposition of Si onto transferred graphene is investigated. At elevated temperatures, Si nucleates preferably on wrinkles and multilayer graphene islands. In some cases, however, Si can be quasi-selectively grown only on the monolayer graphene regions while the multilayer islands remain uncovered. Experimental insights and ab initio calculations show that variations in the removal efficiency of carbon residuals after the transfer process can be responsible for this behavior. Low-temperature Si seed layer results in improved wetting and enables homogeneous growth. This is an important step towards realization of electronic devices in which graphene is embedded between two Si layers.

Phthalates and alternative plasticizers and potential for contact exposure from children's backpacks and toys.

PubMed

Xie, Mingjie; Wu, Yaoxing; Little, John C; Marr, Linsey C

2016-01-01

This work focuses on the mass content of plasticizers in children's backpacks and toys, and their mass transfer from product surfaces to cotton wipes. The mass content of plasticizers in six backpacks and seven toys was measured by extracting them in tetrahydrofuran. Bis(2-ethylhexyl) terephthalate (DEHT) was the most common plasticizer, dominating the composition of plasticizers in four backpacks (average mass content in product polyvinyl chloride, 5.38 ± 1.98%-25.5 ± 3.54%) and six plastic toys (8.17 ± 1.85%-21.2 ± 1.11%). The surface of each product was wiped with three dry and three wet (by isopropanol) cotton wipes, so as to evaluate the mass transfer of plasticizers to clothing and human skin, respectively. DEHT was the most common plasticizer detected on wipe samples. There were strong correlations (backpacks r=0.90; plastic toys r=0.96) between average mass transfer of DEHT to wet wipes and its average mass content in the product. The mass transfers of the five dominant plasticizers in one backpack to both dry and wet wipes were also correlated (both r=1.00) with their mass contents. These results suggest that the mass transfer of plasticizers from products to clothing or human skin is strongly associated with their mass content.

Mass transfer effects in a gasification riser

DOE Office of Scientific and Technical Information (OSTI.GOV)

Breault, Ronald W.; Li, Tingwen; Nicoletti, Phillip

2013-07-01

In the development of multiphase reacting computational fluid dynamics (CFD) codes, a number of simplifications were incorporated into the codes and models. One of these simplifications was the use of a simplistic mass transfer correlation for the faster reactions and omission of mass transfer effects completely on the moderate speed and slow speed reactions such as those in a fluidized bed gasifier. Another problem that has propagated is that the mass transfer correlation used in the codes is not universal and is being used far from its developed bubbling fluidized bed regime when applied to circulating fluidized bed (CFB) risermore » reactors. These problems are true for the major CFD codes. To alleviate this problem, a mechanistic based mass transfer coefficient algorithm has been developed based upon an earlier work by Breault et al. This fundamental approach uses the local hydrodynamics to predict a local, time varying mass transfer coefficient. The predicted mass transfer coefficients and the corresponding Sherwood numbers agree well with literature data and are typically about an order of magnitude lower than the correlation noted above. The incorporation of the new mass transfer model gives the expected behavior for all the gasification reactions evaluated in the paper. At the expected and typical design values for the solid flow rate in a CFB riser gasifier an ANOVA analysis has shown the predictions from the new code to be significantly different from the original code predictions. The new algorithm should be used such that the conversions are not over predicted. Additionally, its behaviors with changes in solid flow rate are consistent with the changes in the hydrodynamics.« less

Controls and variability of solute and sedimentary fluxes in Arctic and sub-Arctic Environments

NASA Astrophysics Data System (ADS)

Dixon, John

2015-04-01

Six major factors consistently emerge as controls on the spatial and temporal variability in sediment and solute fluxes in cold climates. They are climatic, geologic, physiographic or relief, biologic, hydrologic, and regolith factors. The impact of these factors on sediment and solute mass transfer in Arctic and sub-Arctic environments is examined. Comparison of non-glacierized Arctic vs. subarctic drainage basins reveals the effects of these controls. All drainage basins exhibit considerable variability in rates of sediment and solute fluxes. For the non-glacierized drainage basins there is a consistent increase in sediment mass transfer by slope processes and fluvial processes as relief increases. Similarly, a consistent increase in sediment mass transfer by slope and fluvial processes is observed as total precipitation increases. Similar patterns are also observed with respect to solute transport and relief and precipitation. Lithologic factors are most strongly observed in the contrast between volcanic vs. plutonic igneous bedrock substrates. Basins underlain by volcanic rocks display greater mass transfers than those underlain by plutonic rocks. Biologic influences are most strongly expressed by variations in extent of vegetation cover and the degree of human interference, with human impacted basins generating greater fluxes. For glacierized basins the fundamental difference to non-glacierized basins is an overall increase in mean annual mass transfers of sediment and a generally smaller magnitude solute transfer. The principal role of geology is observed with respect to lithology. Catchments underlain by limestone demonstrate substantially greater solute mass transfers than sediment transfer. The influence of relief is seen in the contrast in mass transfers between upland and lowland drainage basins with upland basins generating greater sediment and solute transfers than lowland basins. For glacierized basins the effects of biology and regolith appear to be largely overridden by the hydrologic impacts of glacierization.

Beyond the standard two-film theory: Computational fluid dynamics simulations for carbon dioxide capture in a wetted wall column

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Chao; Xu, Zhijie; Lai, Canhai

The standard two-film theory (STFT) is a diffusion-based mechanism that can be used to describe gas mass transfer across liquid film. Fundamental assumptions of the STFT impose serious limitations on its ability to predict mass transfer coefficients. To better understand gas absorption across liquid film in practical situations, a multiphase computational fluid dynamics (CFD) model fully equipped with mass transport and chemistry capabilities has been developed for solvent-based carbon dioxide (CO 2) capture to predict the CO 2 mass transfer coefficient in a wetted wall column. The hydrodynamics is modeled using a volume of fluid method, and the diffusive andmore » reactive mass transfer between the two phases is modeled by adopting a one-fluid formulation. We demonstrate that the proposed CFD model can naturally account for the influence of many important factors on the overall mass transfer that cannot be quantitatively explained by the STFT, such as the local variation in fluid velocities and properties, flow instabilities, and complex geometries. The CFD model also can predict the local mass transfer coefficient variation along the column height, which the STFT typically does not consider.« less

Beyond the standard two-film theory: Computational fluid dynamics simulations for carbon dioxide capture in a wetted wall column

DOE PAGES

Wang, Chao; Xu, Zhijie; Lai, Canhai; ...

2018-03-27

The standard two-film theory (STFT) is a diffusion-based mechanism that can be used to describe gas mass transfer across liquid film. Fundamental assumptions of the STFT impose serious limitations on its ability to predict mass transfer coefficients. To better understand gas absorption across liquid film in practical situations, a multiphase computational fluid dynamics (CFD) model fully equipped with mass transport and chemistry capabilities has been developed for solvent-based carbon dioxide (CO 2) capture to predict the CO 2 mass transfer coefficient in a wetted wall column. The hydrodynamics is modeled using a volume of fluid method, and the diffusive andmore » reactive mass transfer between the two phases is modeled by adopting a one-fluid formulation. We demonstrate that the proposed CFD model can naturally account for the influence of many important factors on the overall mass transfer that cannot be quantitatively explained by the STFT, such as the local variation in fluid velocities and properties, flow instabilities, and complex geometries. The CFD model also can predict the local mass transfer coefficient variation along the column height, which the STFT typically does not consider.« less

The inducement of planetary boundary layer mass convergence associated with varying vorticity beneath tropospheric wind maximum

NASA Technical Reports Server (NTRS)

Johnson, D. R.

1984-01-01

The effects of the vorticity distribution are applied to study planetary boundary layer mass convergence beneath free tropospheric wind maximum. For given forcing by viscous and pressure gradient forces beneath a wind maximum, boundary layer cross stream mass transport is increased by anticyclonic vorticity on the right flank and decreased by cyclonic vorticity on the left flank. Such frictionally forced mass transport induces boundary layer mass convergence beneath the relative wind maximum. This result is related to the empirical rule that the most intense convection and severe weather frequently develop beneath the 500 mb zero relative vorticity isopleth.

2D modeling of direct laser metal deposition process using a finite particle method

NASA Astrophysics Data System (ADS)

Anedaf, T.; Abbès, B.; Abbès, F.; Li, Y. M.

2018-05-01

Direct laser metal deposition is one of the material additive manufacturing processes used to produce complex metallic parts. A thorough understanding of the underlying physical phenomena is required to obtain a high-quality parts. In this work, a mathematical model is presented to simulate the coaxial laser direct deposition process tacking into account of mass addition, heat transfer, and fluid flow with free surface and melting. The fluid flow in the melt pool together with mass and energy balances are solved using the Computational Fluid Dynamics (CFD) software NOGRID-points, based on the meshless Finite Pointset Method (FPM). The basis of the computations is a point cloud, which represents the continuum fluid domain. Each finite point carries all fluid information (density, velocity, pressure and temperature). The dynamic shape of the molten zone is explicitly described by the point cloud. The proposed model is used to simulate a single layer cladding.

Procedure for detecting and confirming pentobarbital residues in dog food by gas chromatography/mass spectrometry.

PubMed

Adam, L A; Reeves, V B

1998-01-01

The method described detects and confirms presence of pentobarbital residues in dry, extruded feeds at concentrations of 5-20 ppb. Dried feed is ground to a uniform powder and shaken overnight in methanol. A portion of the methanolic extract is evaporated, and the residue is reconstituted in phosphate-buffered saline. The aqueous extract is cleaned with a solid-phase extraction cartridge designed to extract barbiturate residues from biological matrixes. Dimethyl sulfoxide, tetramethylammonium hydroxide, and iodomethane are added to derivatize pentobarbital, 1,3-Dimethyl-pentobarbital is then acidified with dilute hydrochloric acid and extracted with isooctane. The organic layer is transferred and evaporated under a stream of nitrogen. The residue is reconstituted in a small volume of ethyl acetate for analysis by gas chromatography/mass spectrometry. The limit of detection is approximately 0.7 ppb. The method was validated with pentobarbital-fortified feed samples containing high concentrations of meat and bone meal.

Optical properties of sea ice doped with black carbon - an experimental and radiative-transfer modelling comparison

NASA Astrophysics Data System (ADS)

Marks, Amelia A.; Lamare, Maxim L.; King, Martin D.

2017-12-01

Radiative-transfer calculations of the light reflectivity and extinction coefficient in laboratory-generated sea ice doped with and without black carbon demonstrate that the radiative-transfer model TUV-snow can be used to predict the light reflectance and extinction coefficient as a function of wavelength. The sea ice is representative of first-year sea ice containing typical amounts of black carbon and other light-absorbing impurities. The experiments give confidence in the application of the model to predict albedo of other sea ice fabrics. Sea ices, ˜ 30 cm thick, were generated in the Royal Holloway Sea Ice Simulator ( ˜ 2000 L tanks) with scattering cross sections measured between 0.012 and 0.032 m2 kg-1 for four ices. Sea ices were generated with and without ˜ 5 cm upper layers containing particulate black carbon. Nadir reflectances between 0.60 and 0.78 were measured along with extinction coefficients of 0.1 to 0.03 cm-1 (e-folding depths of 10-30 cm) at a wavelength of 500 nm. Values were measured between light wavelengths of 350 and 650 nm. The sea ices generated in the Royal Holloway Sea Ice Simulator were found to be representative of natural sea ices. Particulate black carbon at mass ratios of ˜ 75, ˜ 150 and ˜ 300 ng g-1 in a 5 cm ice layer lowers the albedo to 97, 90 and 79 % of the reflectivity of an undoped clean sea ice (at a wavelength of 500 nm).

Advanced Liquid-Cooling Garment Using Highly Thermally Conductive Sheets

NASA Technical Reports Server (NTRS)

Ruemmele, Warren P.; Bue, Grant C.; Orndoff, Evelyne; Tang, Henry

2010-01-01

This design of the liquid-cooling garment for NASA spacesuits allows the suit to remove metabolic heat from the human body more effectively, thereby increasing comfort and performance while reducing system mass. The garment is also more flexible, with fewer restrictions on body motion, and more effectively transfers thermal energy from the crewmember s body to the external cooling unit. This improves the garment s performance in terms of the maximum environment temperature in which it can keep a crewmember comfortable. The garment uses flexible, highly thermally conductive sheet material (such as graphite), coupled with cooling water lines of improved thermal conductivity to transfer the thermal energy from the body to the liquid cooling lines more effectively. The conductive sheets can be layered differently, depending upon the heat loads, in order to provide flexibility, exceptional in-plane heat transfer, and good through-plane heat transfer. A metal foil, most likely aluminum, can be put between the graphite sheets and the external heat source/sink in order to both maximize through-plane heat transfer at the contact points, and to serve as a protection to the highly conductive sheets. Use of a wicking layer draws excess sweat away from the crewmember s skin and the use of an outer elastic fabric ensures good thermal contact of the highly conductive underlayers with the skin. This allows the current state of the art to be improved by having cooling lines that can be more widely spaced to improve suit flexibility and to reduce weight. Also, cooling liquid does not have to be as cold to achieve the same level of cooling. Specific areas on the human body can easily be targeted for greater or lesser cooling to match human physiology, a warmer external environment can be tolerated, and spatial uniformity of the cooling garment can be improved to reduce vasoconstriction limits. Elements of this innovation can be applied to other embodiments to provide effective heat transfer over a flexible and surface-conformable fashion without the limitation of fluid freeze points.

Determining Mass and Persistence of a Reactive Brominated-Solvent DNAPL Source Using Mass Depletion-Mass Flux Reduction Relationships During Pumping

NASA Astrophysics Data System (ADS)

Johnston, C. D.; Davis, G. B.; Bastow, T.; Annable, M. D.; Trefry, M. G.; Furness, A.; Geste, Y.; Woodbury, R.; Rhodes, S.

2011-12-01

Measures of the source mass and depletion characteristics of recalcitrant dense non-aqueous phase liquid (DNAPL) contaminants are critical elements for assessing performance of remediation efforts. This is in addition to understanding the relationships between source mass depletion and changes to dissolved contaminant concentration and mass flux in groundwater. Here we present results of applying analytical source-depletion concepts to pumping from within the DNAPL source zone of a 10-m thick heterogeneous layered aquifer to estimate the original source mass and characterise the time trajectory of source depletion and mass flux in groundwater. The multi-component, reactive DNAPL source consisted of the brominated solvent tetrabromoethane (TBA) and its transformation products (mostly tribromoethene - TriBE). Coring and multi-level groundwater sampling indicated the DNAPL to be mainly in lower-permeability layers, suggesting the source had already undergone appreciable depletion. Four simplified source dissolution models (exponential, power function, error function and rational mass) were able to describe the concentration history of the total molar concentration of brominated organics in extracted groundwater during 285 days of pumping. Approximately 152 kg of brominated compounds were extracted. The lack of significant kinetic mass transfer limitations in pumped concentrations was notable. This was despite the heterogeneous layering in the aquifer and distribution of DNAPL. There was little to choose between the model fits to pumped concentration time series. The variance of groundwater velocities in the aquifer determined during a partitioning inter-well tracer test (PITT) were used to parameterise the models. However, the models were found to be relatively insensitive to this parameter. All models indicated an initial source mass around 250 kg which compared favourably to an estimate of 220 kg derived from the PITT. The extrapolated concentrations from the dissolution models diverged, showing disparate approaches to possible remediation objectives. However, it also showed that an appreciable proportion of the source would need to be removed to discriminate between the models. This may limit the utility of such modelling early in the history of a DNAPL source. A further limitation is the simplified approach of analysing the combined parent/daughter compounds with different solubilities as a total molar concentration. Although the fitted results gave confidence to this approach, there were appreciable changes in relative abundance. The dissolution and partitioning processes are discussed in relation to the lower-solubility TBA becoming dominant in pumped groundwater over time, despite its known rapid transformation to TriBE. These processes are also related to the architecture of the depleting source as revealed by multi-level groundwater sampling under reversed pumping/injection conditions.

ADIABATIC MASS LOSS IN BINARY STARS. II. FROM ZERO-AGE MAIN SEQUENCE TO THE BASE OF THE GIANT BRANCH

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ge, Hongwei; Chen, Xuefei; Han, Zhanwen

2015-10-10

In the limit of extremely rapid mass transfer, the response of a donor star in an interacting binary becomes asymptotically one of adiabatic expansion. We survey here adiabatic mass loss from Population I stars (Z = 0.02) of mass 0.10 M{sub ⊙}–100 M{sub ⊙} from the zero-age main sequence to the base of the giant branch, or to central hydrogen exhaustion for lower main sequence stars. The logarithmic derivatives of radius with respect to mass along adiabatic mass-loss sequences translate into critical mass ratios for runaway (dynamical timescale) mass transfer, evaluated here under the assumption of conservative mass transfer. Formore » intermediate- and high-mass stars, dynamical mass transfer is preceded by an extended phase of thermal timescale mass transfer as the star is stripped of most of its envelope mass. The critical mass ratio q{sub ad} (throughout this paper, we follow the convention of defining the binary mass ratio as q ≡ M{sub donor}/M{sub accretor}) above which this delayed dynamical instability occurs increases with advancing evolutionary age of the donor star, by ever-increasing factors for more massive donors. Most intermediate- or high-mass binaries with nondegenerate accretors probably evolve into contact before manifesting this instability. As they approach the base of the giant branch, however, and begin developing a convective envelope, q{sub ad} plummets dramatically among intermediate-mass stars, to values of order unity, and a prompt dynamical instability occurs. Among low-mass stars, the prompt instability prevails throughout main sequence evolution, with q{sub ad} declining with decreasing mass, and asymptotically approaching q{sub ad} = 2/3, appropriate to a classical isentropic n = 3/2 polytrope. Our calculated q{sub ad} values agree well with the behavior of time-dependent models by Chen and Han of intermediate-mass stars initiating mass transfer in the Hertzsprung gap. Application of our results to cataclysmic variables, as systems that must be stable against rapid mass transfer, nicely circumscribes the range in q{sub ad} as a function of the orbital period in which they are found. These results are intended to advance the verisimilitude of population synthesis models of close binary evolution.« less

Stochastic backscatter modelling for the prediction of pollutant removal from an urban street canyon: A large-eddy simulation

NASA Astrophysics Data System (ADS)

O'Neill, J. J.; Cai, X.-M.; Kinnersley, R.

2016-10-01

The large-eddy simulation (LES) approach has recently exhibited its appealing capability of capturing turbulent processes inside street canyons and the urban boundary layer aloft, and its potential for deriving the bulk parameters adopted in low-cost operational urban dispersion models. However, the thin roof-level shear layer may be under-resolved in most LES set-ups and thus sophisticated subgrid-scale (SGS) parameterisations may be required. In this paper, we consider the important case of pollutant removal from an urban street canyon of unit aspect ratio (i.e. building height equal to street width) with the external flow perpendicular to the street. We show that by employing a stochastic SGS model that explicitly accounts for backscatter (energy transfer from unresolved to resolved scales), the pollutant removal process is better simulated compared with the use of a simpler (fully dissipative) but widely-used SGS model. The backscatter induces additional mixing within the shear layer which acts to increase the rate of pollutant removal from the street canyon, giving better agreement with a recent wind-tunnel experiment. The exchange velocity, an important parameter in many operational models that determines the mass transfer between the urban canopy and the external flow, is predicted to be around 15% larger with the backscatter SGS model; consequently, the steady-state mean pollutant concentration within the street canyon is around 15% lower. A database of exchange velocities for various other urban configurations could be generated and used as improved input for operational street canyon models.

A comparison of mass transfer coefficients between trickle-bed, hollow fiber membrane and stirred tank reactors.

PubMed

Orgill, James J; Atiyeh, Hasan K; Devarapalli, Mamatha; Phillips, John R; Lewis, Randy S; Huhnke, Raymond L

2013-04-01

Trickle-bed reactor (TBR), hollow fiber membrane reactor (HFR) and stirred tank reactor (STR) can be used in fermentation of sparingly soluble gasses such as CO and H2 to produce biofuels and bio-based chemicals. Gas fermenting reactors must provide high mass transfer capabilities that match the kinetic requirements of the microorganisms used. The present study compared the volumetric mass transfer coefficient (K(tot)A/V(L)) of three reactor types; the TBR with 3 mm and 6 mm beads, five different modules of HFRs, and the STR. The analysis was performed using O2 as the gaseous mass transfer agent. The non-porous polydimethylsiloxane (PDMS) HFR provided the highest K(tot)A/V(L) (1062 h(-1)), followed by the TBR with 6mm beads (421 h(-1)), and then the STR (114 h(-1)). The mass transfer characteristics in each reactor were affected by agitation speed, and gas and liquid flow rates. Furthermore, issues regarding the comparison of mass transfer coefficients are discussed. Copyright © 2013 Elsevier Ltd. All rights reserved.

[Correlation of molecular weight and nanofiltration mass transfer coefficient of phenolic acid composition from Salvia miltiorrhiza].

PubMed

Li, Cun-Yu; Wu, Xin; Gu, Jia-Mei; Li, Hong-Yang; Peng, Guo-Ping

2018-04-01

Based on the molecular sieving and solution-diffusion effect in nanofiltration separation, the correlation between initial concentration and mass transfer coefficient of three typical phenolic acids from Salvia miltiorrhiza was fitted to analyze the relationship among mass transfer coefficient, molecular weight and concentration. The experiment showed a linear relationship between operation pressure and membrane flux. Meanwhile, the membrane flux was gradually decayed with the increase of solute concentration. On the basis of the molecular sieving and solution-diffusion effect, the mass transfer coefficient and initial concentration of three phenolic acids showed a power function relationship, and the regression coefficients were all greater than 0.9. The mass transfer coefficient and molecular weight of three phenolic acids were negatively correlated with each other, and the order from high to low is protocatechualdehyde >rosmarinic acid> salvianolic acid B. The separation mechanism of nanofiltration for phenolic acids was further clarified through the analysis of the correlation of molecular weight and nanofiltration mass transfer coefficient. The findings provide references for nanofiltration separation, especially for traditional Chinese medicine with phenolic acids. Copyright© by the Chinese Pharmaceutical Association.

Theory of Excitation Transfer between Two-Dimensional Semiconductor and Molecular Layers

NASA Astrophysics Data System (ADS)

Specht, Judith F.; Verdenhalven, Eike; Bieniek, Björn; Rinke, Patrick; Knorr, Andreas; Richter, Marten

2018-04-01

The geometry-dependent energy transfer rate from an electrically pumped inorganic semiconductor quantum well into an organic molecular layer is studied theoretically. We focus on Förster-type nonradiative excitation transfer between the organic and inorganic layers and include quasimomentum conservation and intermolecular coupling between the molecules in the organic film. (Transition) partial charges calculated from density-functional theory are used to calculate the coupling elements. The partial charges describe the spatial charge distribution and go beyond the common dipole-dipole interaction. We find that the transfer rates are highly sensitive to variations in the geometry of the hybrid inorganic-organic system. For instance, the transfer efficiency is improved by up to 2 orders of magnitude by tuning the spatial arrangement of the molecules on the surface: Parameters of importance are the molecular packing density along the effective molecular dipole axis and the distance between the molecules and the surface. We also observe that the device performance strongly depends on the orientation of the molecular dipole moments relative to the substrate dipole moments determined by the inorganic crystal structure. Moreover, the operating regime is identified where inscattering dominates over unwanted backscattering from the molecular layer into the substrate.

Prediction and measurement of heat transfer rates for the shock-induced unsteady laminar boundary layer on a flat plate

NASA Technical Reports Server (NTRS)

Cook, W. J.

1972-01-01

The unsteady laminar boundary layer induced by the flow-initiating shock wave passing over a flat plate mounted in a shock tube was theoretically and experimentally studied in terms of heat transfer rates to the plate for shock speeds ranging from 1.695 to 7.34 km/sec. The theory presented by Cook and Chapman for the shock-induced unsteady boundary layer on a plate is reviewed with emphasis on unsteady heat transfer. A method of measuring time-dependent heat-transfer rates using thin-film heat-flux gages and an associated data reduction technique are outlined in detail. Particular consideration is given to heat-flux measurement in short-duration ionized shocktube flows. Experimental unsteady plate heat transfer rates obtained in both air and nitrogen using thin-film heat-flux gages generally agree well with theoretical predictions. The experimental results indicate that the theory continues to predict the unsteady boundary layer behavior after the shock wave leaves the trailing edge of the plate even though the theory is strictly applicable only for the time interval in which the shock remains on the plate.

Plume effects on the flow around a blunted cone at hypersonic speeds

NASA Technical Reports Server (NTRS)

Atcliffe, P.; Kumar, D.; Stollery, J. L.

1992-01-01

Tests at M = 8.2 show that a simulated rocket plume at the base of a blunted cone can cause large areas of separated flow, with dramatic effects on the heat transfer rate distribution. The plume was simulated by solid discs of varying sizes or by an annular jet of gas. Flow over the cone without a plume is fully laminar and attached. Using a large disc, the boundary layer is laminar at separation at the test Reynolds number. Transition occurs along the separated shear layer and the boundary layer quickly becomes turbulent. The reduction in heat transfer associated with a laminar separated region is followed by rising values as transition occurs and the heat transfer rates towards the rear of the cone substantially exceed the values obtained without a plume. With the annular jet or a small disc, separation occurs much further aft, so that heat transfer rates at the front of the cone are comparable with those found without a plume. Downstream of separation the shear layer now remains laminar and the heat transfer rates to the surface are significantly lower than the attached flow values.