Study of Chromium Oxide Activities in EAF Slags

NASA Astrophysics Data System (ADS)

Yan, Baijun; Li, Fan; Wang, Hui; Sichen, Du

2016-02-01

The activity coefficients of chromium in Cu-Cr melts were determined by equilibrating liquid copper with solid Cr2O3 in CO-CO2 atmosphere. The temperature dependence of the activity coefficients of chromium in Cu-Cr melts could be expressed as lg γ_{Cr}(s)^{0} = { 3 2 5 9( ± 1 8 6} )/T - 0. 5 9( { ± 0. 1} ). Based on the above results, the activities of bivalent and trivalent chromium oxide in some slags at 1873 K (1600 °C) were measured. The slags were equilibrated with Cu-Cr melts under two oxygen partial pressures ( {p_{O}_{ 2} }} } = 6.9 × 10-4 and 1.8 × 10-6 Pa, respectively). The morphology of the quenched slags and the solubility of chromium oxide in the melts were investigated by EPMA, SEM, and XRD. Under both oxygen partial pressures, the slags were saturated by the solid solution MgAl2- x Cr x O4- δ . At the low oxygen partial pressure (1.8 × 10-6 Pa), the content of Cr in the liquid phase varied from 0.4 to 1.6 mass pct with the total Cr content in the slags increasing from 1.3 to 10.8 mass pct. At the high oxygen partial pressure (6.9 × 10-4 Pa), the content of Cr in the liquid phase decreased to the level of 0.2 to 0.6 mass pct. Both the activities of CrO and Cr2O3 in slag were found to increase approximately linearly with the increase of the total Cr content in slag. While the oxygen partial pressure had minor effect on the activity of Cr2O3 in the slag, it had significant effect on the activity of CrO.

Microscopic Study of Carbon Surfaces Interacting with High Carbon Ferromanganese Slag

NASA Astrophysics Data System (ADS)

Safarian, Jafar; Kolbeinsen, Leiv

2015-02-01

The interaction of carbon materials with molten slags occurs in many pyro-metallurgical processes. In the production of high carbon ferromanganese in submerged arc furnace, the carbothermic reduction of MnO-containing silicate slags yields the metal product. In order to study the interaction of carbon with MnO-containing slags, sessile drop wettability technique is employed in this study to reduce MnO from a molten slag drop by carbon substrates. The interfacial area on the carbon substrate before and after reaction with slag is studied by scanning electron microscope. It is indicated that no Mn metal particles are found at the interface through the reduction of the MnO slag. Moreover, the reduction of MnO occurs through the contribution of Boudouard reaction and it causes carbon consumption in particular active sites at the interface, which generate carbon degradation and open pore growth at the interface. It is shown that the slag is fragmented to many micro-droplets at the reaction interface, potentially due to the effect on the interfacial energies of a provisional liquid Mn thin film. The rapid reduction of these slag micro-droplets affects the carbon surface with making deep micro-pores. A mechanism for the formation of slag micro-droplets is proposed, which is based on the formation of provisional micro thin films of liquid Mn at the interface.

Effect of Rice Husk Ash Insulation Powder on the Reoxidation Behavior of Molten Steel in Continuous Casting Tundish

NASA Astrophysics Data System (ADS)

Kim, Tae Sung; Chung, Yongsug; Holappa, Lauri; Park, Joo Hyun

2017-06-01

Rice husk ash (RHA) has been widely used as an insulation powder in steel casting tundish. Its effect on the reoxidation of molten steel in tundish as well as on the corrosion of magnesia refractory was investigated. The reoxidation of the steel, indicated by an oxygen pickup, was progressed by increasing the ratio of RHA to the sum of RHA and carryover ladle slag ( R ratio) greater than about 0.2. The increase of the silica activity in the slag layer promoted the self-dissociation of SiO2 from the slag layer into the molten steel, resulting in the silicon and oxygen pickup as the R ratio increased. The total number of reoxidation inclusions dramatically increased and the relative fraction of Al2O3-rich inclusions increased by increasing the R ratio. Hence, the reoxidation of molten steel in tundish might become more serious due to the formation of alumina-rich inclusions as the casting sequence increases. MgO in the refractory directly dissolved into the molten slag layer without forming any intermediate compound layer ( e.g., spinel), which is a completely different situation from the general slag-refractory interfacial reaction. A flow was possibly induced by the bursting of gas bubbles at the ash-slag (-refractory) interface, since the silica in the RHA powder continuously dissolved into the molten slag pool. Thus, the RHA insulation powder has a negative effect on the corrosion of MgO refractory.

Phosphorus Control in DRI-EAF Steelmaking: Thermodynamics, Effect of Alumina, and Process Modeling

NASA Astrophysics Data System (ADS)

Tayeb, Mohammed A.

Flexibility in raw materials, the lower natural gas prices, and the increased use of nonconventional Electric Arc Furnace (EAF) steelmaking using up to 100% Direct Reduced Iron (DRI) have prompted a renewed interest in better control of phosphorus. Iron ore and DRI have higher phosphorus and silica compared to scrap. Although significant work has been done on understanding the partitioning of phosphorus between slag and metal for slags with chemistries relevant to those used in the Basic Oxygen Furnace (BOF), there is little reported work on slag chemistries corresponding to that in the EAF when DRI is used (EAF-DRI). In the current research, phosphorus equilibria between molten Fe-P alloys and CaO-SiO2-Al2O3-P 2O5-FeO-MgOsaturated slag system were investigated. An equilibrium correlation for phosphorus partition as a function of slag composition and temperature has been developed and resulted in better predictions compared with those proposed by earlier workers. As well, it is suitable for both BOF and EAF slags and includes coefficients for silica and alumina, unlike previous correlations. Low amounts of Al2O3 are present in EAF and BOF slags, but no appreciable work has been carried out to study the effect of alumina on the phosphorus partition. When DRI is used, the Al2O 3 contents can also be much higher. The data from this work indicates that there is significant reduction in Lp as the alumina fraction in the slag increases. The observed effect of alumina is attributed to its acidity, which contributes to the reduction of the phosphorus capacity of the slag by lowering the activities of iron oxide and calcium oxide. This in turn lowers the activity of oxygen and oxygen ions needed for phosphorus partition to the slag phase. Alumina in such situation is believed to elongate the silicate slag structure by forming [AlO45-]-tetrahedra. However, it is apparent that for higher alumina, lower silica slags the behavior of alumina changes and dephosphorization would improve. Alumina becomes less acidic acting as a diluting agent and probably forming [AlO6 9-]-octahedra according to which alumina is hypothesized to behave amphoterically. While understanding the equilibrium and kinetics of the phosphorus reaction is important in order to improve the ability to remove phosphorus from the melt, practical use of this understanding in industry is limited. Modeling the phosphorus reaction in steelmaking, however, would result in a better and easier use of conceptual understanding by operators and engineers in plants. This work describes dynamic process models for phosphorus and sulfur reactions when using DRI, scrap, and pig iron in EAF steelmaking. The present models are based on the assumption that thermodynamic equilibrium is locally established at the steel-slag interface, the bulk liquid steel and slag remain homogeneous throughout the reaction, and the rate is predominantly controlled by the mass transfer of phosphorus in the metal and slag boundary layers. The models, which consist of a series of rate and mass balance equations, were converted into a Python code and are capable of predicting trajectories of steel and slag phosphorus and sulfur levels as well as slag chemistry and slag liquid and solid phases. The effect of operating variables on the final phosphorus and sulfur contents, for instance the effect of DRI and pig iron P and S concentrations, oxygen use, temperature, melting rates, and flux addition were tested. The results imply that dephosphorization could be improved by maintaining lower bath temperatures for period of time. Additionally, dephosphorization and desulfurization were improved by higher flux addition.

Electroslag Treatment of Liquid Cast Iron

NASA Astrophysics Data System (ADS)

Grachev, V. A.

2018-01-01

The processes that occur in the liquid metal-slag system during electroslag treatment of cast iron are studied from an electrochemical standpoint. The role of electrolysis in the electroslag process is shown, and a method for producing high-strength cast iron with globular graphite using electrolysis of a slag containing magnesium oxides and fluorides is proposed and tested.

Bubbling at high flow rates in inviscid and viscous liquids (slags)

NASA Astrophysics Data System (ADS)

Engh, T. Abel; Nilmani, M.

1988-02-01

The behavior of gas discharging into melts at high velocities but still in the bubbling regime has been investigated in a laboratory modeling study for constant flow conditions. Air or helium was injected through a vertical tuyere into water, zinc-chloride, and aqueous glycerol solutions. High speed cinematography and pressure measurements in the tuyere have been carried out simultaneously. Pressure fluctuations at the injection point were monitored and correlated to the mode of bubble formation. The effects of high gas flow rates and high liquid viscosities have been examined in particular. Flow rates were employed up to 10-3 m3/s and viscosity to 0.5 Ns/m2. In order to attain a high gas momentum, the tuyere diameter was only 3 x 10-3 m. The experimental conditions and modeling liquids were chosen with special reference to the established practice of submerged gas injection to treat nonferrous slags. Such slags can be highly viscous. Bubble volume is smaller than that calculated from existing models such as those given by Davidson and Schüler10,11 due to the effect of gas momentum elongating the bubbles. On the other hand, viscosity tends to retard the bubble rise velocity, thus increasing volumes. To take elongation into account, a mathematical model is presented that assumes a prolate ellipsoidal shape of the bubbles. The unsteady potential flow equations for the liquid are solved for this case. Viscous effects are taken into account by noting that flow deviates from irrotational motion only in a thin boundary layer along the surface of the bubble. Thus, drag on the bubble can be obtained by calculating the viscous energy dissipation for potential flow past an ellipse. The time-dependent inertia coefficient for the ellipsoid is found by equating the vertical pressure increase inside and outside the bubble. This pressure change in the bubble is obtained by assuming that gas enters as a homogeneous jet and then calculating the stagnation pressure at the apex of the bubble.

Fuel and oxygen addition for metal smelting or refining process

DOEpatents

Schlichting, Mark R.

1994-01-01

A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

Fuel and oxygen addition for metal smelting or refining process

DOEpatents

Schlichting, M.R.

1994-11-22

A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figs.

Lance for fuel and oxygen injection into smelting or refining furnace

DOEpatents

Schlichting, Mark R.

1994-01-01

A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

Lance for fuel and oxygen injection into smelting or refining furnace

DOEpatents

Schlichting, M.R.

1994-12-20

A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figures.

Refractory lining system for high wear area of high temperature reaction vessel

DOEpatents

Hubble, David H.; Ulrich, Klaus H.

1998-01-01

A refractory-lined high temperature reaction vessel comprises a refractory ring lining constructed of refractory brick, a cooler, and a heat transfer medium disposed between the refractory ring lining and the cooler. The refractory brick comprises magnesia (MgO) and graphite. The heat transfer medium contacts the refractory brick and a cooling surface of the cooler, and is composed of a material that accommodates relative movement between the refractory brick and the cooler. The brick is manufactured such that the graphite has an orientation providing a high thermal conductivity in the lengthwise direction through the brick that is higher than the thermal conductivity in directions perpendicular to the lengthwise direction. The graphite preferably is flake graphite, in the range of about 10 to 20 wt %, and has a size distribution selected to provide maximum brick density. The reaction vessel may be used for performing a reaction process including the steps of forming a layer of slag on a melt in the vessel, the slag having a softening point temperature range, and forming a protective frozen layer of slag on the interior-facing surface of the refractory lining in at least a portion of a zone where the surface contacts the layer of slag, the protective frozen layer being maintained at or about the softening point of the slag.

Chromium Distribution between Liquid Slag and Matte Phases

NASA Astrophysics Data System (ADS)

Eric, R. Hurman

The distribution of chromium between liquid silicate slags and copper-iron-nickel matte phases encountered in electric smelting of PGM containing South African sulphide concentrates were experimentally studied under controlled partial pressures of oxygen and sulphur. The reported experiments were conducted under silica saturation through the use of silica crucibles. Seven representative slag compositions were equilibrated with a typical sulphur deficient matte containing 18% Ni, 11% Cu, 42% Fe and 29% S. The slag constituents varied in the following ranges: SiO2: 42-58%, Al2O3: 3.5-9.0%, Fe2O3: 13-21%, MgO: 15.6-25%, CaO: 2-15%, Cr2O3: 0.2-3.5%. The slag and matte samples were synthetically prepared from pure components. The chromium content of the two phases was analysed chemically. According to the present available results of this ongoing research it was found that the partition of chromium to the matte phase decreased with an increase in the partial pressures of both oxygen and sulphur where the value of the distribution coefficient of chromium between the matte and the slag phase varied from as low as 0.07 to as high as 5.5.

The Influence of Sulfur on Dephosphorization Kinetics Between Bloated Metal Droplets and Slag Containing FeO

NASA Astrophysics Data System (ADS)

Gu, Kezhuan; Dogan, Neslihan; Coley, Kenneth S.

2017-10-01

The bloating behavior of metal droplets and the dephosphorization behavior of bloated droplets at 1853 K (1580 °C) were investigated using X-ray fluoroscopy coupled with constant volume pressure change measurements and chemical analysis of quenched samples. The effect of sulfur content on dephosphorization kinetics was studied during the decarburization period. The slag foamed during the reaction forming a foamy layer over a dense layer. After a short incubation period, the droplets became bloated due to internal decarburization. The bloated droplets floated from the dense slag into the foamy slag. The behavioral changes are directly related to the effect of sulfur on the incubation time for swelling. The dephosphorization reaction was very fast; droplets with low sulfur contents experienced phosphorus reversion shortly after entering the foamy slag, while those with higher sulfur content took a longer time to swell and went through reversion before they entered the foam. The dephosphorization rate and maximum phosphorus partition were higher at lower CO evolution rates because the dynamic interfacial oxygen potential increased with the decreasing oxygen consumption rate. The rate controlling step for dephosphorization was initially a combination of mass transport in both the metal and the slag. As the iron oxide in the slag was depleted, the rate control shifted to mass transport in slag.

Experimental Investigation on Reduction Kinetics of Stainless Steel-Making Slag in Iron Bath Smelting Reduction

NASA Astrophysics Data System (ADS)

Zhang, Bo; Liu, Jienan; Yang, Yanfeng; Liu, Luming; Liu, Jiechao; Luo, Lijian; Ma, Yubao; Hong, Xin

Reduction kinetics of stainless steel slag in iron bath smelting reduction was studied at the temperature of 1500°C ˜ 1650°C. It was concluded that the reduction process consisted of two parts. That is to say smelting reduction was controlled by stainless steel slag melting initially and by interface reaction later. In order to increase smelting reaction rate, the melting point of slag should be decreased at the first stage and adjust the liquidity of slag at later stage. Smelting reaction rate will be accelerated by means of optimize the slag content. The optimal reduction result that all most all of the chromium in slag been recovered was obtained in temperature was 1500°C, basicity of slag was 1.0˜1.2, the value of Al2O3+MgO was 25%.

An Investigation into the Mechanics of Windblown Dust Entrainment from Nickel Slag Surfaces Resembling Armoured Desert Pavements

NASA Astrophysics Data System (ADS)

Sanderson, Robert Steven

The purpose of this thesis is to investigate the dynamics of PM 10 emission from a nickel slag stockpile that closely resembles a desert pavement in physical characteristics. In the field, it was observed that slag surfaces develop by natural processes into a well-armoured surface over some period of time. The surface then consists of two distinct layers; a surficial armour layer containing only non-erodible gravel and cobble-sized clasts, and an underlying dust-laden layer, which contains a wide size range of slag particles, from clay-sized to cobble-sized. This surficial armour layer protects the underlying fines from wind entrainment, at least under typical wind conditions; however, particle emissions still do occur under high wind speeds. The dynamics of particle entrainment from within these surfaces are investigated herein. It is shown that the dynamics of the boundary layer flow over these lag surfaces are influenced by the inherent roughness and permeability of the surficial armour layer, such that the flow resembles those observed over and within vegetation canopies, and those associated with permeable gravel-bed river channels. Restriction of air flow within the permeable surface produces a high-pressure zone within the pore spaces, resulting in a Kelvin-Helmholtz shear instability, which triggers coherent motions in the form of repeating burst-sweep cycles. Using Laser Doppler Anemometry (LDA), it is demonstrated that the lower boundary layer is characterized by both Q4 sweeping motions and Q2 bursting motions, while the upper boundary layer is dominated by Q2 bursts. Pore air motions within the slag material were measured using buried pressure ports. It is shown that the mean pressure gradient which forms within the slag material results in net upward displacement of air, or wind pumping. However, this net upward motion is a result of rapid oscillatory motions which are directly driven by coherent boundary layer motions. It is also demonstrated that these coherent motions are able to penetrate at least 4 cm through the surficial armour layer, thereby transporting turbulent kinetic energy (TKE) downward to the dust-laden sub-surface layer. This represents a mechanism of momentum transfer that is able to reach the erodible material, while the wind pumping effect represents a mechanism for particle exhaustion.

Refractory lining system for high wear area of high temperature reaction vessel

DOEpatents

Hubble, D.H.; Ulrich, K.H.

1998-04-21

A refractory-lined high temperature reaction vessel comprises a refractory ring lining constructed of refractory brick, a cooler, and a heat transfer medium disposed between the refractory ring lining and the cooler. The refractory brick comprises magnesia (MgO) and graphite. The heat transfer medium contacts the refractory brick and a cooling surface of the cooler, and is composed of a material that accommodates relative movement between the refractory brick and the cooler. The brick is manufactured such that the graphite has an orientation providing a high thermal conductivity in the lengthwise direction through the brick that is higher than the thermal conductivity in directions perpendicular to the lengthwise direction. The graphite preferably is flake graphite, in the range of about 10 to 20 wt %, and has a size distribution selected to provide maximum brick density. The reaction vessel may be used for performing a reaction process including the steps of forming a layer of slag on a melt in the vessel, the slag having a softening point temperature range, and forming a protective frozen layer of slag on the interior-facing surface of the refractory lining in at least a portion of a zone where the surface contacts the layer of slag, the protective frozen layer being maintained at or about the softening point of the slag. 10 figs.

Refractory lining system for high wear area of high temperature reaction vessel

DOEpatents

Hubble, D.H.; Ulrich, K.H.

1998-09-22

A refractory-lined high temperature reaction vessel comprises a refractory ring lining constructed of refractory brick, a cooler, and a heat transfer medium disposed between the refractory ring lining and the cooler. The refractory brick comprises magnesia (MgO) and graphite. The heat transfer medium contacts the refractory brick and a cooling surface of the cooler, and is composed of a material that accommodates relative movement between the refractory brick and the cooler. The brick is manufactured such that the graphite has an orientation providing a high thermal conductivity in the lengthwise direction through the brick that is higher than the thermal conductivity in directions perpendicular to the lengthwise direction. The graphite preferably is flake graphite, in the range of about 10 to 20 wt %, and has a size distribution selected to provide maximum brick density. The reaction vessel may be used for performing a reaction process including the steps of forming a layer of slag on a melt in the vessel, the slag having a softening point temperature range, and forming a protective frozen layer of slag on the interior-facing surface of the refractory lining in at least a portion of a zone where the surface contacts the layer of slag, the protective frozen layer being maintained at or about the softening point of the slag. 10 figs.

Investigation of the kinetic mechanism of the demanganization reaction between carbon-saturated liquid iron and CaF2-CaO-SiO2-based slags

NASA Astrophysics Data System (ADS)

Duan, Sheng-chao; Li, Chuang; Guo, Han-jie; Guo, Jing; Han, Shao-wei; Yang, Wen-sheng

2018-04-01

The demanganization reaction kinetics of carbon-saturated liquid iron with an eight-component slag consisting of CaO-SiO2-MgO-FeO-MnO-Al2O3-TiO2-CaF2 was investigated at 1553, 1623, and 1673 K in this study. The rate-controlling step (RCS) for the demanganization reaction with regard to the hot metal pretreatment conditions was studied via kinetics analysis based on the fundamental equation of heterogeneous reaction kinetics. From the temperature dependence of the mass transfer coefficient of a transition-metal oxide (MnO), the apparent activation energy of the demanganization reaction was estimated to be 189.46 kJ·mol-1 in the current study, which indicated that the mass transfer of MnO in the molten slag controlled the overall rate of the demanganization reaction. The calculated apparent activation energy was slightly lower than the values reported in the literature for mass transfer in a slag phase. This difference was attributed to an increase in the "specific reaction interface" (SRI) value, either as a result of turbulence at the reaction interface or a decrease of the absolute amount of slag phase during sampling, and to the addition of calcium fluoride to the slag.

Preparation of glass-ceramics from molten steel slag using liquid-liquid mixing method.

PubMed

Zhang, Kai; Liu, Jianwen; Liu, Wanchao; Yang, Jiakuan

2011-10-01

A novel approach to prepare glass-ceramics from molten steel slag (MSS) was proposed. In laboratory, the water-quenched steel slag was melted at 1350 °C to simulate the MSS. A mixture of additive powders in wt.% (55 quartz powder, 5 Na2O, 16 emery powder, 15 CaO, 8 MgO, 1 TiO2) were melted into liquid at 1350 °C separately. Then the MSS and the molten additives were mixed homogeneously in order to obtain parent glass melt. The proportion of MSS in the melt was 50 wt.%. The melt was subsequently cast, annealed, heat-treated and transformed into glass-ceramics. Their microstructure and crystallization behavior were analyzed. The samples exhibited excellent properties and displayed bulk crystallization. The major crystallized phase was diopside ((Fe0.35Al0.20Mg0.44)Ca0.96(Fe0.08Si0.70Al0.20)2O6.12), which was uniformly distributed in the microstructure. The novel approach may help iron and steel industry achieve zero disposal of steel slag with utilization of the heat energy of the MSS. Copyright © 2011 Elsevier Ltd. All rights reserved.

Design of a continuous process setup for precipitated calcium carbonate production from steel converter slag.

PubMed

Mattila, Hannu-Petteri; Zevenhoven, Ron

2014-03-01

A mineral carbonation process "slag2PCC" for carbon capture, utilization, and storage is discussed. Ca is extracted from steel slag by an ammonium salt solvent and carbonated with gaseous CO2 after the separation of the residual slag. The solvent is reused after regeneration. The effects of slag properties such as the content of free lime, fractions of Ca, Si, Fe, and V, particle size, and slag storage on the Ca extraction efficiency are studied. Small particles with a high free-lime content and minor fractions of Si and V are the most suitable. To limit the amount of impurities in the process, the slag-to-liquid ratio should remain below a certain value, which depends on the slag composition. Also, the design of a continuous test setup (total volume ∼75 L) is described, which enables quick process variations needed to adapt the system to the varying slag quality. Different precipitated calcium carbonate crystals (calcite and vaterite) are generated in different parts of the setup. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Study of Shell-Mold Thermal Resistance: Laboratory Measurements, Estimation from Compact Strip Production Plant Data, and Observation of Simulated Flux-Mold Interface

NASA Astrophysics Data System (ADS)

González de la C., J. Manuel; Flores F., Tania M.; Castillejos E., A. Humberto

2016-08-01

The slag film that forms between the shell and mold in steel continuous casting is key in regulating the heat transfer between them. Generally, the mechanisms proposed are related to the phenomena associated with the formation of crystals in the solid layer of the film, such as the appearance of internal pores and surface roughness, which decrease phononic conduction through the layer and interfacial gap with the mold, respectively, and the emergence of crystals themselves, which reduce the transmissivity of infrared radiation across the layer. Due to the importance of the solid layer, this study investigates experimentally the effective thermal resistance, R T, between a hot Inconel surface and a cold Cu surface separated by an initially glassy slag disk, made from powders for casting low and medium-carbon steels, denoted as A and B, respectively. In the tests, an initially mirror-polished disk is sandwiched for 10,800 seconds while the Inconel temperature, away from the disk face, is maintained steady at a value, T c, between 973 K and 1423 K (700 °C and 1150 °C)-below the liquidus temperature of the slags. The disks have a thickness, d t, between ~0.7 and 3.2 mm. Over the range of conditions studied, mold slag B shows R T 33 pct larger than slag A, and microscopic observation of disks hints that the greater resistance arises from the larger porosity developed in B. This finding is supported by high-temperature confocal laser scanning microscope observations of the evolution of the surface of slag parallelepipeds encased between Pt sheets, which reveal that during devitrification the film surface moves outward not inward, contrary with what is widely claimed. This behavior would favor contact of the slag with the mold for both kinds of powders. However, in the case of slag A, the crystalline grains growing at or near the surface pack closely together, leaving only few and small empty spaces. In slag B, crystalline grains pack loosely and many and large empty spaces arise in and below the surface. Estimation from plant data shows R T values smaller than measured ones, suggesting that the process film slag thickness must be considerably thinner than those of laboratory disks. However, the difference in thermal resistance of both powders, averaged over the mold length, is close to the dissimilarity found in laboratory.

Static Holdup of Liquid Slag in Simulated Packed Coke Bed Under Oxygen Blast Furnace Ironmaking Conditions

NASA Astrophysics Data System (ADS)

Wang, Guang; Liu, Yingli; Zhou, Zhenfeng; Wang, Jingsong; Xue, Qingguo

2018-01-01

The liquid-phase flow behavior of slag in the lower zone of a blast furnace affects the furnace permeability, performance, and productivity. The effects of pulverized coal injection (PCI) on the behavior of simulated primary slag flow were investigated by quantifying the effect of key variables including Al/Si ratio [Al2O3 (wt.%) to SiO2 (wt.%)] and the amount of unburnt pulverized coal (UPC) at 1500°C. Viscosity analysis demonstrated that the slag fluidity decreased as the Al/Si ratio was increased (from 0.35 to 0.50), resulting in gradual increase of the static holdup. Increasing the amount of UPC resulted in a significant increase of the static holdup. Flooding analysis was applied to determine the maximum static holdup, which was found to be 11.5%. It was inferred that the burnout rates of pulverized coal should exceed 78.6% and 83.9% in traditional and oxygen blast furnaces, respectively.

Experimental Determination of Sulfur Partition Ratio in the CaO-Al2O3-SiO2-CaF2-MgO Slag and Liquid Iron

NASA Astrophysics Data System (ADS)

Jinzhu, Z.; Yunsheng, Y.; Wei, F.; Jialiang, Z.; Yi, Z.

2017-09-01

The external desulphurization of molten iron has become an important step in the production of steel and iron. The desulfurization degree of the high calcium slag, which was mainly taken from Shougang Shuicheng Iron and Steel (Group) Co. Limited, was investigated on basis of the fundamental theory of slag metal equilibrium reaction. The initial content of sulfur in the slag was adjusted to 2.60% mass perdent by adding analytical reagent CaS. The results show that the desulfurization degree of the high calcium slag increases obviously with the increase of temperature in the range 1593-1743K, and so the sulfur partition ratio. When the holding time of the hot metal and slag at controlled temperature was extended from 120 min to 180 min in the furnace, both the sulfur partition ratio and the desulfurization degree increased markedly.

Model Implementation of Boron Removal Using CaCl2-CaO-SiO2 Slag System for Solar-Grade Silicon

NASA Astrophysics Data System (ADS)

Chen, Hui; Wang, Ye; Zheng, Wenjia; Li, Qincan; Yuan, Xizhi; Morita, Kazuki

2017-12-01

A new CaCl2-CaO-SiO2 slag system was recently proposed to remove boron from metallurgy-grade silicon by oxidized chlorination and evaporation. To further investigate the boron transformation process at a high temperature, a model implementation to present the transfer of boron from molten silicon to the gas phase via slag is introduced. Heat transfer, fluid flow, the chemical reactions at the interface and surface, the mass transfer and diffusion of boron in the molten silicon and slag, and the evaporation of BOCl and CaCl2 were coupled in this model. After the confirmation of the thermal field, other critical parameters, including the boron partition ratios ( L B) for this slag from 1723 K to 1823 K (1450 °C to 1550 °C), the thicknesses of the velocity boundary layer at the surface and interface, the mass transfer coefficients of the boundary layer at the surface and interface, and partial pressure of BOCl in the gas phase were analyzed to determine the rate-limiting step. To verify this model implementation, boron removal experiments were carried out at various temperatures and with various initial mass ratios of slag to silicon ( μ). The evaporation rate of CaCl2 was also measured by thermogravimetry analysis (TGA).

DOE Office of Scientific and Technical Information (OSTI.GOV)

Matyas, Josef; Cooley, Scott K.; Sundaram, S. K.

Slags of low viscosity readily penetrate the refractory lining in slagging gasifiers, causing rapid and severe corrosion called spalling. In addition, a low-viscosity slag that flows down the gasifier wall forms a relatively thin layer of slag on the refractory surface, allowing the corrosive gases in the gasifier to participate in the chemical reactions between the refractory and the slag. In contrast, a slag viscosity of <25 Pa•s at 1400°C is necessary to minimize the possibility of plugging the slag tap. There is a need to predict and optimize slag viscosity so slagging gasifiers can operate continuously at temperatures rangingmore » from 1300 to 1650°C. The approach adopted in this work was to statistically design and prepare simulated slags, measure the viscosity as a function of temperature, and develop a model to predict slag viscosity based on slag composition and temperature. Statistical design software was used to select compositions from a candidate set of all possible vertices that will optimally represent the composition space for 10 main components. A total of 21 slag compositions were generated, including 5 actual coal slag compositions. The Arrhenius equation was applied to measured viscosity versus temperature data of tested slags, and the Arrhenius coefficients (A and B in ln(vis) = A + B/T) were expressed as linear functions of the slag composition. The viscosity model was validated using 1) data splitting approach, and 2) viscosity/temperature data of selected slag compositions from the literature that were formulated and melted at Pacific Northwest National Laboratory. The capability of the model to predict the viscosity of coal slags was compared with the model developed by Browning et al. because this model can predict the viscosity of slags from coal ash better than the most commonly used empirical models found in the literature.« less

Research on the Characteristics and Mechanism of the Cumulative Release of Antimony from an Antimony Smelting Slag Stacking Area under Rainfall Leaching

PubMed Central

Zhou, Yingying; Deng, Renjian

2017-01-01

We aimed to study the characteristics and the mechanism of the cumulative release of antimony at an antimony smelting slag stacking area in southern China. A series of dynamic and static leaching experiments to simulate the effects of rainfall were carried out. The results showed that the release of antimony from smelting slag increased with a decrease in the solid-liquid ratio, and the maximum accumulated release was found to be 42.13 mg Sb/kg waste and 34.26 mg Sb/kg waste with a solid/liquid ratio of 1 : 20; the maximum amount of antimony was released within 149–420 μm size fraction with 7.09 mg/L of the cumulative leaching. Also, the antimony release was the greatest and most rapid at pH 7.0 with the minimum release found at pH 4.0. With an increase in rainfall duration, the antimony release increased. The influence of variation in rainfall intensity on the release of antimony from smelting slag was small. PMID:28804669

Dissolution Behaviour of Hazardous Materials from Steel Slag with Wet Grinding Method

NASA Astrophysics Data System (ADS)

Hisyamudin Muhd Nor, Nik; Norhana Selamat, Siti; Hanif Abd Rashid, Muhammad; Fauzi Ahmad, Mohd; Jamian, Saifulnizan; Chee Kiong, Sia; Fahrul Hassan, Mohd; Mohamad, Fariza; Yokoyama, Seiji

2016-06-01

Steel slag is a by-product from steel industry and it contains variety of hazardous materials. In this study, the dissolution behaviour and removal potential of hazardous materials from steel slag with the wet grinding method was investigated. The slag was wet ground in the CO2 atmosphere and the slurry produced was filtered using centrifugal separator to separate the liquid and solid sediments. Then, the concentrations of dissolved metal elements in the liquid sediment were analyzed by ICP-MS. The changes of pH during the grinding were also investigated. It was found that the pHs were decreased immediately after the CO2 gas introduced into the vessel. The pHs were ranging from 6.8 to 7.6 at the end of grinding. The dissolved concentration of Zn and Cr were ranging from 5~45 [mg/dm3] and 0.2~2.5 [mg/dm3] respectively. The ratios of Zn removal for stainless steel oxidizing and reducing slag were very high, but those from normal steel oxidizing and reducing slag were very low. It is assumed that the Zn dissolved as ZnOH+ from Zn(OH)2 that formed due to the reaction between ZnO and water. Dissolution of Cr also occurred but in very low quantity compared to the dissolution of Zn. The dissolution of Cr occurred due to the grinding process and small amount of Cr(OH)3 was formed during the grinding. This small formation of Cr(OH)3 resulted to the low dissolved concentration of Cr in the form of Cr(OH)2+. According to the XRD analysis, the Cr mostly existed in the slags as Cr(IIl) in the form of MgCr2O4 and FeCr2O4.

Stabilization of Black Cotton Soil Using Micro-fine Slag

NASA Astrophysics Data System (ADS)

Shukla, Rajesh Prasad; Parihar, Niraj Singh

2016-09-01

This work presents the results of laboratory tests conducted on black cotton soil mixed with micro-fine slag. Different proportions of micro-fine slag, i.e., 3, 6, 9, 12 and 15 % were mixed with the black cotton soil to improve soil characteristics. The improvement in the characteristics of stabilized soil was assessed by evaluating the changes in the physical and strength parameters of the soil, namely, the Atterberg limits, free swell, the California Bearing Ratio (CBR), compaction parameters and Unconfined Compressive Strength (UCS). The mixing of micro-fine slag decreases the liquid limit, plasticity index and Optimum Moisture Contents (OMC) of the soil. Micro-fine slag significantly increases the plastic limit, UCS and CBR of the soil up to 6-7 % mixing, but mixing of more slag led to decrease in the UCS and CBR of the soil. The unsoaked CBR increased by a substantial amount unlike soaked CBR value. The swell potential of the soil is reduced from medium to very low. The optimum amount of micro-fine slag is found to be approximately 6-7 % by the weight of the soil.

Dissolved organic matter removal during coal slag additive soil aquifer treatment for secondary effluent recharging: Contribution of aerobic biodegradation.

PubMed

Wei, Liangliang; Li, Siliang; Noguera, Daniel R; Qin, Kena; Jiang, Junqiu; Zhao, Qingliang; Kong, Xiangjuan; Cui, Fuyi

2015-06-01

Recycling wastewater treatment plant (WWTP) effluent at low cost via the soil aquifer treatment (SAT), which has been considered as a renewable approach in regenerating potable and non-potable water, is welcome in arid and semi-arid regions throughout the world. In this study, the effect of a coal slag additive on the bulk removal of the dissolved organic matter (DOM) in WWTP effluent during SAT operation was explored via the matrix configurations of both coal slag layer and natural soil layer. Azide inhibition and XAD-resins fractionation experiments indicated that the appropriate configuration designing of an upper soil layer (25 cm) and a mixture of soil/coal slag underneath would enhance the removal efficiency of adsorption and anaerobic biodegradation to the same level as that of aerobic biodegradation (31.7% vs 32.2%), while it was only 29.4% compared with the aerobic biodegradation during traditional 50 cm soil column operation. The added coal slag would preferentially adsorb the hydrophobic DOM, and those adsorbed organics could be partially biodegraded by the biomass within the SAT systems. Compared with the relatively lower dissolved organic carbon (DOC), ultraviolet light adsorption at 254 nm (UV-254) and trihalomethane formation potential (THMFP) removal rate of the original soil column (42.0%, 32.9%, and 28.0%, respectively), SSL2 and SSL4 columns would enhance the bulk removal efficiency to more than 60%. Moreover, a coal slag additive in the SAT columns could decline the aromatic components (fulvic-like organics and tryptophan-like proteins) significantly. Copyright © 2015 Elsevier Ltd. All rights reserved.

Physical Modelling of the Effect of Slag and Top-Blowing on Mixing in the AOD Process

NASA Astrophysics Data System (ADS)

Haas, Tim; Visuri, Ville-Valtteri; Kärnä, Aki; Isohookana, Erik; Sulasalmi, Petri; Eriç, Rauf Hürman; Pfeifer, Herbert; Fabritius, Timo

The argon-oxygen decarburization (AOD) process is the most common process for refining stainless steel. High blowing rates and the resulting efficient mixing of the steel bath are characteristic of the AOD process. In this work, a 1:9-scale physical model was used to study mixing in a 150 t AOD vessel. Water, air and rapeseed oil were used to represent steel, argon and slag, respectively, while the dynamic similarity with the actual converter was maintained using the modified Froude number and the momentum number. Employing sulfuric acid as a tracer, the mixing times were determined on the basis of pH measurements according to the 97.5% criterion. The gas blowing rate and slag-steel volume ratio were varied in order to study their effect on the mixing time. The effect of top-blowing was also investigated. The results suggest that mixing time decreases as the modified Froude number of the tuyères increases and that the presence of a slag layer increases the mixing time. Furthermore, top-blowing was found to increase the mixing time both with and without the slag layer.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Su, Zhiqi; He, Qing, E-mail: heqing@ise.neu.edu.cn; Xie, Zhi

For real-time and precise measurement of molten steel level in tundish during continuous casting, slag level and slag thickness are needed. Among which, the problem of slag thickness measurement has been solved in our previous work. In this paper, a systematic solution for slag level measurement based on laser triangulation is proposed. Being different from traditional laser triangulation, several aspects for measuring precision and robustness have been done. First, laser line is adopted for multi-position measurement to overcome the deficiency of single point laser range finder caused by the uneven surface of the slag. Second, the key parameters, such asmore » installing angle and minimum requirement of the laser power, are analyzed and determined based on the gray-body radiation theory to fulfill the rigorous requirement of measurement accuracy. Third, two kinds of severe noises in the acquired images, which are, respectively, caused by heat radiation and Electro-Magnetic Interference (EMI), are cleaned via morphological characteristic of the liquid slag and color difference between EMI and the laser signals, respectively. Fourth, as false target created by stationary slag usually disorders the measurement, valid signals of the slag are distinguished from the false ones to calculate the slag level. Then, molten steel level is obtained by the slag level minus the slag thickness. The measuring error of this solution is verified by the applications in steel plants, which is ±2.5 mm during steady casting and ±3.2 mm at the end of casting.« less

METHOD OF PURIFYING URANIUM METAL

DOEpatents

Blanco, R.E.; Morrison, B.H.

1958-12-23

The removal of lmpurities from uranlum metal can be done by a process conslstlng of contacting the metal with liquid mercury at 300 icient laborato C, separating the impunitycontalnlng slag formed, cooling the slag-free liquld substantlally below the point at which uranlum mercurlde sollds form, removlng the mercury from the solids, and recovering metallic uranium by heating the solids.

Synthetic Coal Slag Infiltration into Varying Refractory Materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaneko, Tetsuya K; Thomas, Hugh; Bennett, James P

The infiltrations of synthetic coal slag into 99%Al{sub 2}O{sub 3}, 85%Al{sub 2}O{sub 3}–15%SiO{sub 2}, and 90%Cr{sub 2}O{sub 3}–10%Al{sub 2}O{sub 3} refractories with a temperature gradient induced along the penetration direction were compared to one another. The infiltrating slag was synthesized with a composition that is representative of an average of the ash contents from U S coal feedstock. Experiments were conducted with a hot-face temperature of 1450°C in a CO/CO{sub 2} atmosphere. Minimal penetration was observed in the 90%Cr{sub 2}O{sub 3}–10%Al{sub 2}O{sub 3} material because interactions between the refractory and the slag produced a protective layer of FeCr{sub 2}O{sub 4},more » which impeded slag flow into the bulk of the refractory. After 5 h, the 99%Al{sub 2}O{sub 3} sample exhibited an average penetration of 12.7 mm whereas the 85%Al{sub 2}O{sub 3}–15%SiO{sub 2} sample showed 3.8 mm. Slag infiltrated into the 99%Al{sub 2}O{sub 3} and 85%Al{sub 2}O{sub 3}–15%SiO{sub 2} refractory systems by dissolving the respective refractories' matrix materials, which consist of fine Al{sub 2}O{sub 3} particles and an amorphous alumino-silicate phase. Due to enrichment in SiO{sub 2}, a network-former, infiltration into the 85%Al{sub 2}O{sub 3}–15%SiO{sub 2} system yielded a higher viscosity slag and hence, a shallower penetration depth. The results suggest that slag infiltration can be limited by interactions with the refractory through the formation of either a solid layer that physically impedes fluid flow or a more viscous slag that retards infiltration.« less

Method for magnesium sulfate recovery

DOEpatents

Gay, Richard L.; Grantham, LeRoy F.

1987-01-01

A method of obtaining magnesium sulfate substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is then contacted with a concentrated sulfuric acid under certain prescribed conditions to produce a liquid product and a solid product. The particulate solid product and a minor amount of the liquid is then treated to produce a solid residue consisting essentially of magnesium sulfate substantially free of uranium and having a residual radioactivity level of less than 1000 pCi/gm. In accordance with the preferred embodiment of the invention, a catalyst and an oxidizing agent are used during the initial acid treatment and a final solid residue has a radioactivity level of less than about 50 pCi/gm.

Magnesium fluoride recovery method

DOEpatents

Gay, Richard L.; McKenzie, Donald E.

1989-01-01

A method of obtaining magnesium fluoride substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is contacted with an acid under certain prescribed conditions to produce a liquid product and a particulate solid product. The particulate solid product is separated from the liquid and treated at least two more times with acid to produce a solid residue consisting essentially of magnesium fluoride substantially free of uranium and having a residual radioactivity level of less than about 1000 pCi/gm. In accordance with a particularly preferred embodiment of the invention a catalyst and an oxidizing agent are used during the acid treatment and preferably the acid is sulfuric acid having a strength of about 1.0 Normal.

Method for magnesium sulfate recovery

DOEpatents

Gay, R.L.; Grantham, L.F.

1987-08-25

A method is described for obtaining magnesium sulfate substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7,000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is then contacted with a concentrated sulfuric acid under certain prescribed conditions to produce a liquid product and a solid product. The particulate solid product and a minor amount of the liquid is then treated to produce a solid residue consisting essentially of magnesium sulfate substantially free of uranium and having a residual radioactivity level of less than 1,000 pCi/gm. In accordance with the preferred embodiment of the invention, a catalyst and an oxidizing agent are used during the initial acid treatment and a final solid residue has a radioactivity level of less than about 50 pCi/gm.

Processing industrial wastes with the liquid-phase reduction romelt process

NASA Astrophysics Data System (ADS)

Romenets, V.; Valavin, V.; Pokhvisnev, Yu.; Vandariev, S.

1999-08-01

The Romelt technology for liquid-phase reduction has been developed for processing metallurgical wastes containing nonferrousmetal components. Thermodynamic calculations were made to investigate the behavior of silver, copper, zinc, manganese, vanadium, chrome, and silicon when reduced from the slag melt into the metallic solution containing iron. The process can be applied to all types of iron-bearing wastes, including electric arc furnace dust. The distribution of elements between the phases can be controlled by adjusting the slag bath temperature. Experiments at a pilot Romelt plant proved the possibility of recovering the metallurgical wastes and obtaining iron.

Effects of Reoxidation of Liquid Steel and Slag Composition on the Chemistry Evolution of Inclusions During Electroslag Remelting

NASA Astrophysics Data System (ADS)

Shi, Chengbin; Wang, Hui; Li, Jing

2018-06-01

Electroslag remelting (ESR) is increasingly used to produce some varieties of special steels and alloys, mainly because of its ability to provide extreme cleanliness and an excellent solidification structure simultaneously. In the present study, the combined effects of varying SiO2 contents in slag and reoxidation of liquid steel on the chemistry evolution of inclusions and the alloying element content in steel during ESR were investigated. The inclusions in the steel before ESR refining were found to be oxysulfides of patch-type (Ca,Mn)S adhering to a CaO-Al2O3-SiO2-MgO inclusion. The oxide inclusions in both the liquid metal pool and remelted ingots are CaO-Al2O3-MgO and MgAl2O4 together with CaO-Al2O3-SiO2-MgO inclusions (slightly less than 30 pct of the total inclusions), which were confirmed to originate from the reduction of SiO2 from the original oxide inclusions by dissolved Al in liquid steel during ESR. CaO-Al2O3-MgO and MgAl2O4 are newly formed inclusions resulting from the reactions taking place inside liquid steel in the liquid metal pool caused by reoxidation of liquid steel during ESR. Increasing the SiO2 content in slag not only considerably reduced aluminum pickup in parallel with silicon loss during ESR, but also suppressed the decrease in SiO2 content in oxide inclusions. (Ca,Mn)S inclusions were fully removed before liquid metal droplets collected in the liquid metal pool.

Correlation between the critical viscosity and ash fusion temperatures of coal gasifier ashes

DOE PAGES

Hsieh, Peter Y.; Kwong, Kyei-Sing; Bennett, James

2015-09-27

Coal gasification yields synthesis gas, an important intermediate in chemical manufacturing. It is also vital to the production of liquid fuels through the Fischer-Tropsch process and electricity in Integrated Gasification Combined Cycle power generation. Minerals naturally present in coal become molten in entrained-flow slagging gasifiers. Molten coal ash slag penetrates and dissolves refractory bricks, leading to costly plant shutdowns. The extent of coal ash slag penetration and refractory brick dissolution depends on the slag viscosity, the gasification temperature, and the composition of slag and bricks. We measured the viscosity of several synthetic coal ash slags with a high-temperature rotary viscometermore » and their ash fusion temperatures through optical image analysis. All measurements were made in a carbon monoxide-carbon dioxide reducing atmosphere that approximates coal gasification conditions. Empirical correlation models based on ash fusion temperatures were used to calculate critical viscosity temperatures based on the coal ash compositions. These values were then compared with those obtained from thermodynamic phase-transition models. An understanding of slag viscosity as a function of ash composition is important to reducing refractory wear in slagging coal gasifiers, which would help to reduce the cost and environmental impact of coal for chemical and electricity production.« less

Correlation between the critical viscosity and ash fusion temperatures of coal gasifier ashes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hsieh, Peter Y.; Kwong, Kyei-Sing; Bennett, James

Coal gasification yields synthesis gas, an important intermediate in chemical manufacturing. It is also vital to the production of liquid fuels through the Fischer-Tropsch process and electricity in Integrated Gasification Combined Cycle power generation. Minerals naturally present in coal become molten in entrained-flow slagging gasifiers. Molten coal ash slag penetrates and dissolves refractory bricks, leading to costly plant shutdowns. The extent of coal ash slag penetration and refractory brick dissolution depends on the slag viscosity, the gasification temperature, and the composition of slag and bricks. We measured the viscosity of several synthetic coal ash slags with a high-temperature rotary viscometermore » and their ash fusion temperatures through optical image analysis. All measurements were made in a carbon monoxide-carbon dioxide reducing atmosphere that approximates coal gasification conditions. Empirical correlation models based on ash fusion temperatures were used to calculate critical viscosity temperatures based on the coal ash compositions. These values were then compared with those obtained from thermodynamic phase-transition models. An understanding of slag viscosity as a function of ash composition is important to reducing refractory wear in slagging coal gasifiers, which would help to reduce the cost and environmental impact of coal for chemical and electricity production.« less

Dissolution of steel slags in aqueous media.

PubMed

Yadav, Shashikant; Mehra, Anurag

2017-07-01

Steel slag is a major industrial waste in steel industries, and its dissolution behavior in water needs to be characterized in the larger context of its potential use as an agent for sequestering CO 2 . For this purpose, a small closed system batch reactor was used to conduct the dissolution of steel slags in an aqueous medium under various dissolution conditions. In this study, two different types of steel slags were procured from steel plants in India, having diverse structural features, mineralogical compositions, and particle sizes. The experiment was performed at different temperatures for 240 h of dissolution at atmospheric pressure. The dissolution rates of major and minor slag elements were quantified through liquid-phase elemental analysis using an inductively coupled plasma atomic emission spectroscopy at different time intervals. Advanced analytical techniques such as field emission gun-scanning electron microscope, energy-dispersive X-ray, BET, and XRD were also used to analyze mineralogical and structural changes in the slag particles. High dissolution of slags was observed irrespective of the particle size distribution, which suggests high carbonation potential. Concentrations of toxic heavy metals in the leachate were far below maximum acceptable limits. Thus, the present study investigates the dissolution behavior of different mineral ions of steel slag in aqueous media in light of its potential application in CO 2 sequestration.

Microscopic and Metallurgical Aspects of the Space Shuttle Columbia Accident Investigation and Reconstruction

NASA Technical Reports Server (NTRS)

McDaniels, Steven J.

2004-01-01

The Space Shuttle Columbia was descending for a landing at the Kennedy Space Center (KSC) on February 1, 2003. Approximately 20 minutes prior to touchdown, the Columbia began disintegrating over the western United States; the majority of debris eventually impacted in eastern Texas and western Louisiana. A monumental effort eventually recovered approximately 84,000 pieces of debris, approximately 38% of the Orbiter's original dry weight. The debris was transported to KSC, where the items were catalogued and evaluated. Critical areas of interest, such as the left and right leading edge surfaces and the underside of the ship, were placed upon a grid to aid in the reconstruction. Items of interest included metallic structures, reinforced carbon-carbon composites, and ceramic heat insulation tiles. Many of the leading edge elements had re-solidified metallic deposits spattered on them. These deposits became known as slag and were one of the main focuses of the investigation. In order to help determine the sequence of events inside the left wing during the accident, the slag's composition, layering order, and directionality of deposition were studied. A myriad of analytical tests were performed in an attempt to ascertain the compositional and depositional characteristics of selected slag deposits, including the ordering of deposited layers within each individual slag deposit harvested. Initially, Scanning Electron Microscopy and Energy Dispersive X-Ray Spectroscopy (SEM/EDX) were performed to quickly characterize the overall composition of individual slag deposits: SEM utilizes a narrowlyfocused high-energy electron beam impinging upon a specimen. The incident beam excites and liberates lower energy secondary electrons, which are detected and analyzed, providing a visual representation of the sample's surface topography. EDX also relies on an incident electron beam, except an EDX unit measures X-ray energies generated by the impinging beam. Each element generates a unique X-ray signature; the EDX detector measures these discreet energies. EDX actually penetrates approximately 2 microns into the bulk of the sample. However, random examination of various portions of slag, coupled with the semiquantitative nature of the SEM/EDX analysis, did not yield convincingly pertinent data. Therefore, X-ray dot mapping was conducted, which provided more understandable data, both in terms of slag layering and composition. An X-ray dot map is generated by performing numerous EDX scans for individual elements, then compiling the scans in a visual representation. Eventually, specimens consisting of not only the slag, but of the adjacent RCC substrate as well were cross-sectioned. X-Ray dot mapping of the materialographicallymounted and -polished cross- sections provided a visual representation of both the layering sequence and compositional characteristics of the slag. Contemporaneously, Electron Spectroscopy for Chemical Analysis/X-Ray Photoelectron Spectroscopy (ESCA/XPS) and powdered X-Ray Diffraction (XRD) were performed to further characterize the deposits and to attempt to identify what, if any, compounds were present. The ESCA/XPS analysis allowed the analyst to "sputter" into the sample with an electron gun, aiding in the identification of the layering sequence. XPS uses photons, rather than electrons, which impinge upon the surface of the sample. XPS measures the electrons emitted from within the first 5 nm of the sample's surface. The XRD measures the scatter angles of incident X-rays; the angle and intensity of scatter depend upon the crystalline structure of the pulverized sample. XRD is considered a qualitative rather than quantitative technique. ESCA/XPS revealed that the final layer to deposit was predominantly carbonaceous. XRD was successful in identifying specific compounds, such as Al 2O3, Al and/or Al3 21SiO47, mullite (3(Al2)O3 -SiO2), and nickel-aluminides. Eventually, Electron MicroProbe Analysis (EMPA) was conducted on the marialographically-prepared cross- sections of selected slag deposits. Microprobe combines SEM and Wavelength Dispersive X-Ray Spectroscopy (WDS), and, like EDX, uses a narrowly-focused high-energy electron beam impinging upon a specimen to elicit, in the case of EPMA, characteristic X-rays with specific wavelengths. This quantitative, analytical tool proved the most useful in determining depositional layering and composition of the slag deposits. This information was utilized in verifying the location of the breach in the left leading edge of the wing of the Columbia.

Effect of Temperature and Graphite Immersion Method on Carbothermic Reduction of Fayalite Slag

NASA Astrophysics Data System (ADS)

Mitrašinović, Aleksandar

2017-09-01

In this work, graphite flakes were used to reduce fayalite slag originated from the pyrometallurgical copper extraction process. Experiments were conducted with a significantly different contact area between graphite and slag at two temperatures, 1300°C and 1400°C. The process was continuously monitored via the concentration change of CO and CO2 in off-gas. Reduction rate values in experiments where 150-micron-diameter graphite flakes were submerged into the slag and left to float slowly to the top are about four times higher compared with when graphite flakes were dispersed at the top surface of liquid slag. The activation energy for instigating reduction was 302.61 kJ mol-1 and 306.67 kJ mol-1 in the case where graphite flakes were submerged into the slag and dispersed at the surface, respectively. The reduction process is characterized by two distinctive periods: an initial steep increase in the concentration of CO and CO2 controlled by the Boudouard reaction and a subsequent slow decrease of CO and CO2 concentrations in the off-gas controlled by mass transfer of reducible oxides from bulk to the gas-slag interface.

Uranium distribution in pseudowollastonite slag from a phosphorus furnace

USGS Publications Warehouse

Young, Edward; Altschuler, Zalman S.

1956-01-01

Silicate slag from the Victor Chemical Company phosphorus furnace at Tarpon Springs, Fla., has been found to consist essentially of pseudowollastonite, α-CaSiO3. The first-formed crystals are euhedral laths which form a mesh making up most of the slag. As the slag continues to solidify, its composition changes slightly and more equant, subhedral crystals of pseudowollastonite are deposited within the framework of the earlier material. Finally, anherdral masses of fibrous, poorly crystallized material are deposited in the remaining pore spaces which are not always completely filled. Spherules of iron phosphide, Fe2P, occur very sparsely in the slag as inclusions from the immiscible iron phosphide melt. Uranium content increases in the later crystal products of the slag, and by heavy-liquid fractionation it has been possible to segregate partially the phases and to obtain a fourfold concentration of uranium in 5 percent of the material and a twofold concentration in 30 percent of the material. Nuclear-emulsion studies indicate that the last phases of the silicate slag are actually eight times as radioactive as the early phases. In addition, the iron phosphide spherules are comparably enriches in uranium.

Open-cycle magnetohydrodynamic power plant based upon direct-contact closed-loop high-temperature heat exchanger

DOEpatents

Berry, G.F.; Minkov, V.; Petrick, M.

1981-11-02

A magnetohydrodynamic (MHD) power generating system is described in which ionized combustion gases with slag and seed are discharged from an MHD combustor and pressurized high temperature inlet air is introduced into the combustor for supporting fuel combustion at high temperatures necessary to ionize the combustion gases, and including a heat exchanger in the form of a continuous loop with a circulating heat transfer liquid such as copper oxide. The heat exchanger has an upper horizontal channel for providing direct contact between the heat transfer liquid and the combustion gases to cool the gases and condense the slag which thereupon floats on the heat transfer liquid and can be removed from the channel, and a lower horizontal channel for providing direct contact between the heat transfer liquid and pressurized air for preheating the inlet air. The system further includes a seed separator downstream of the heat exchanger.

Open-cycle magnetohydrodynamic power plant based upon direct-contact closed-loop high-temperature heat exchanger

DOEpatents

Berry, Gregory F.; Minkov, Vladimir; Petrick, Michael

1988-01-05

A magnetohydrodynamic (MHD) power generating system in which ionized combustion gases with slag and seed are discharged from an MHD combustor and pressurized high temperature inlet air is introduced into the combustor for supporting fuel combustion at high temperatures necessary to ionize the combustion gases, and including a heat exchanger in the form of a continuous loop with a circulating heat transfer liquid such as copper oxide. The heat exchanger has an upper horizontal channel for providing direct contact between the heat transfer liquid and the combustion gases to cool the gases and condense the slag which thereupon floats on the heat transfer liquid and can be removed from the channel, and a lower horizontal channel for providing direct contact between the heat transfer liquid and pressurized air for preheating the inlet air. The system further includes a seed separator downstream of the heat exchanger.

Open-cycle magnetohydrodynamic power plant based upon direct-contact closed-loop high-temperature heat exchanger

DOEpatents

Berry, Gregory F.; Minkov, Vladimir; Petrick, Michael

1988-01-01

A magnetohydrodynamic (MHD) power generating system in which ionized combustion gases with slag and seed are discharged from an MHD combustor and pressurized high temperature inlet air is introduced into the combustor for supporting fuel combustion at high temperatures necessary to ionize the combustion gases, and including a heat exchanger in the form of a continuous loop with a circulating heat transfer liquid such as copper oxide. The heat exchanger has an upper horizontal channel for providing direct contact between the heat transfer liquid and the combustion gases to cool the gases and condense the slag which thereupon floats on the heat transfer liquid and can be removed from the channel, and a lower horizontal channel for providing direct contact between the heat transfer liquid and pressurized air for preheating the inlet air. The system further includes a seed separator downstream of the heat exchanger.

Infiltration of Slag Film into the Grooves on a Continuous Casting Mold

NASA Astrophysics Data System (ADS)

Cho, Jung-Wook; Jeong, Hee-Tae

2013-02-01

An analytical model is developed to clarify the slag film infiltration into grooves on a copper mold during the continuous casting of steel slabs. A grooved-type casting mold was applied to investigate the infiltration of slag film into the grooves of a pitch of 0.8 mm, width of 0.7 mm, and depth of 0.6 mm at the vicinity of a meniscus. The plant trial tests were carried out at a casting speed of 5.5 m min-1. The slag film captured at a commercial thin slab casting plant showed that both the overall and the liquid film thickness were decreased exponentially as the distance from the meniscus increases. In contrast, the infiltration of slag film into the grooves had been increased with increasing distance from the meniscus. A theoretic model has been derived based on the measured profile of slag film thickness to calculate the infiltration of slag film into the grooves. It successfully reproduces the empirical observation that infiltration ratio increased sharply along casting direction, about 80 pct at 50 mm and 95 pct at 150 mm below the meniscus. In the model calculation, the infiltration of slag film increases with increasing groove width and/or surface tension of the slag. The effect of groove depth is negligible when the width to depth ratio of the groove is larger than unity. It is expected that the developed model for slag film infiltration in this study will be widely utilized to optimize the design of groove dimensions in continuous casting molds.

Perspectives regarding the use of metallurgical slags as secondary metal resources - A review of bioleaching approaches.

PubMed

Potysz, Anna; van Hullebusch, Eric D; Kierczak, Jakub

2018-05-05

Smelting activity by its very nature produces large amounts of metal-bearing waste, often called metallurgical slag(s). In the past, industry used to dispose of these waste products at dumping sites without the appropriate environmental oversight. Once there, ongoing biogeochemical processes affect the stability of the slags and cause the release of metallic contaminants. Rather than viewing metallurgical slags as waste, however, such deposits should be viewed as secondary metal resources. Metal bioleaching is a "green" treatment route for metallurgical slags, currently being studied under laboratory conditions. Metal-laden leachates obtained at the bioleaching stage have to be subjected to further recovery operations in order to obtain metal(s) of interest to achieve the highest levels of purity possible. This perspective paper considers the feasibility of the reuse of base-metal slags as secondary metal resources. Special focus is given to current laboratory bioleaching approaches and associated processing obstacles. Further directions of research for development of more efficient methods for waste slag treatment are also highlighted. The optimized procedure for slag treatment is defined as the result of this review and should include following steps: i) slag characterization (chemical and phase composition and buffering capacity) following the choice of initial pH, ii) the choice of particle size, iii) the choice of the liquid-to-solid ratio, iv) the choice of microorganisms, v) the choice of optimal nutrient supply (growth medium composition). An optimal combination of all these parameters will lead to efficient extraction and generation of metal-free solid residue. Copyright © 2018 Elsevier Ltd. All rights reserved.

Gasification Slag and the Mechanisms by Which Phosphorous Additions Reduce Slag Wear and Corrosion in High Cr2O3 Refractories

NASA Astrophysics Data System (ADS)

Bennett, James; Nakano, Anna; Nakano, Jinichiro; Thomas, Hugh

Gasification is a high-temperature/high-pressure process that converts carbonaceous materials such as coal and/or petcoke into CO and H2, feedstock materials used in power generation and chemical production. Gasification is considered an important technology because of its high process efficiency and the ability to capture environmental pollutants such as CO2, SO3 and Hg. Ash impurities in the carbon feedstock materials melt and coalesce during gasification (1325-1575 °C), becoming slag that attaches to and flows down the gasifier sidewall, corroding and eroding the high Cr2O3 refractory liner used to protect the gasification chamber. Phosphate additions to high Cr2O3 refractory have been found to alter slag/refractory interactions and dramatically reduce refractory wear by the following mechanisms: a) spinel formation, b) slag chemistry changes, c) two phase liquid formation, and d) oxidation state changes. The mechanisms and how they work together to impact material wear/corrosion will be discussed.

The solidification behavior of calcium oxide-aluminum oxide slags

NASA Astrophysics Data System (ADS)

Prapakorn, Kritsada

The binary CaO-Al2O3 based slag and the ternary CaO-Al2O3-MgO based slag are common slags covering and inclusions that are found in calcium treated Al-killed, continuously cast steels. However, the effect of cooling conditions and chemistry on the solidification behavior of these slags is not well characterized. To better understand this phenomena, the solidification behavior of these slags was studied by using double hot thermocouple technique. TTT and CCT diagrams of these slags were determined to quantify the solidification behavior in both dry and humid atmospheres. In this work, these slag samples were easily undercooled and the solidification behavior of these slags was found to be a strong function of cooling conditions. The crystallization tendency of these slags follows the trends suggested by the phase diagram. In CaO-Al2O3 based slags, The eutectic composition (50%CaO) give the lowest crystallization tendency due to the lowest liquidus temperature. In a eutectic CaO-Al2O3 slag sample, dissolved water in the sample increases crystallization tendency and enhances the growth. It was also found that the crystalline phase that formed during cooling in both the dry and humid conditions is the mixture between 3CaO.Al2O 3 and CaO.Al2O3 phases. In CaO-Al2O3-MgO based slags, the crystallization tendency increases with MgO content because the high MgO content leads to the high liquidus temperature. The effect of dissolved of water on the crystallization of CaO-Al2O3-MgO based slags is not as prominent as in the eutectic CaO-Al2O3 slag. Thus, the addition of MgO to CaO-Al2O3 slags was seen to minimize or eliminate the effect of humidity on the solidification of CaO-Al2O3 based slags. In this work, Uhlmann's method was used to estimate the solid-liquid interfacial energy of CaO-Al2O3 based slag for the temperature between 1100--1250°C. The result is between 0.25--0.4 Joules/m 2.

Recycling of red muds with the extraction of metals and special additions to cement

NASA Astrophysics Data System (ADS)

Zinoveev, D. V.; Diubanov, V. G.; Shutova, A. V.; Ziniaeva, M. V.

2015-01-01

The liquid-phase reduction of iron oxides from red mud is experimentally studied. It is shown that, in addition to a metal, a slag suitable for utilization in the construction industry can be produced as a result of pyrometallurgical processing of red mud. Portland cement is shown to be produced from this slag with mineral additions and a high-aluminate expansion addition to cement.

Co-reduction of Copper Smelting Slag and Nickel Laterite to Prepare Fe-Ni-Cu Alloy for Weathering Steel

NASA Astrophysics Data System (ADS)

Guo, Zhengqi; Pan, Jian; Zhu, Deqing; Zhang, Feng

2018-02-01

In this study, a new technique was proposed for the economical and environmentally friendly recovery of valuable metals from copper smelting slag while simultaneously upgrading nickel laterite through a co-reduction followed by wet magnetic separation process. Copper slag with a high FeO content can decrease the liquidus temperature of the SiO2-Al2O3-CaO-MgO system and facilitate formation of liquid phase in a co-reduction process with nickel laterite, which is beneficial for metallic particle growth. As a result, the recovery of Ni, Cu, and Fe was notably increased. A crude Fe-Ni-Cu alloy with 2.5% Ni, 1.1% Cu, and 87.9% Fe was produced, which can replace part of scrap steel, electrolytic copper, and nickel as the burden in the production of weathering steel by an electric arc furnace. The study further found that an appropriate proportion of copper slag and nickel laterite in the mixture is essential to enhance the reduction, acquire appropriate amounts of the liquid phase, and improve the growth of the metallic alloy grains. As a result, the liberation of alloy particles in the grinding process was effectively promoted and the metal recovery was increased significantly in the subsequent magnetic separation process.

Preparation of Al-Ti Master Alloy by Electrochemical Recovery of Titanium-Reducing Slag in Molten Salts

NASA Astrophysics Data System (ADS)

Zhao, Kun; Wang, Yaowu; Feng, Naixiang

2018-02-01

An electrochemical method for the preparation of an Al-Ti master alloy in Al electrolysis melts of Na3AlF6-Al2O3-LiF at 980°C was investigated. The Ti-reducing slag (5.24 wt.% Ti in the Ti-reducing slag) was obtained from the aluminothermic reduction of Na2TiF6. The cold test (i.e., the aluminothermic reduction process without applying any voltages) result revealed the capability of the Al cathode to reduce the Ti slag, and the recovery rate could reach 45.8% at 980°C over 3.5 h with the addition of 10 wt.% Ti-reducing slag. In contrast, the recovery rate of Ti after electrolysis at 3.0 V could reach 99.2%. Thus, the electrochemical treatment for Ti-reducing slag is a cooperative process involving aluminothermic and electrochemical reduction reactions. Electrochemical analysis indicated that the Ti ions are reduced to metallic Ti according to Ti4+ → Ti3+ → Ti. An Al-Ti alloy layer could be prepared on the external surface of the Mo electrode after electrolysis with the addition of 12 wt.% Ti-reducing slag.

Effect of Cr2O3 Pickup on Dissolution of Lime in Converter Slag

NASA Astrophysics Data System (ADS)

Yan, Wei; Chen, Weiqing; Zhao, Xiaobo; Yang, Yindong; McLean, Alex

2017-09-01

Application of low-nickel laterite ore containing chromium as charging material for ironmaking can reduce raw material costs, but result in an increase of chromium content in the hot metal and hence, Cr2O3 content in the steelmaking slag, which subsequently causes many problems related to lime dissolution for the steelmaking operation. In this work, a rotating cylinder method was employed to study the effect of Cr2O3 on lime dissolution in steelmaking slag. The lime dissolution mechanism, rate control step and affecting factors, including slag basicity, FeOx and B2O3 content, and the formation of phases at reacted layer, were discussed. It was found that mass transfer was the rate control step in slag phase, increase of Cr2O3 and slag basicity delayed lime dissolution due to the formation of high-melting temperature phases of FeO · Cr2O3 spinel and 2CaO · SiO2 at the slag/lime reacted interface. Addition of B2O3 promoted lime dissolution and suppressed formation of FeO · Cr2O3 spinel.

A Gibbs Energy Minimization Approach for Modeling of Chemical Reactions in a Basic Oxygen Furnace

NASA Astrophysics Data System (ADS)

Kruskopf, Ari; Visuri, Ville-Valtteri

2017-12-01

In modern steelmaking, the decarburization of hot metal is converted into steel primarily in converter processes, such as the basic oxygen furnace. The objective of this work was to develop a new mathematical model for top blown steel converter, which accounts for the complex reaction equilibria in the impact zone, also known as the hot spot, as well as the associated mass and heat transport. An in-house computer code of the model has been developed in Matlab. The main assumption of the model is that all reactions take place in a specified reaction zone. The mass transfer between the reaction volume, bulk slag, and metal determine the reaction rates for the species. The thermodynamic equilibrium is calculated using the partitioning of Gibbs energy (PGE) method. The activity model for the liquid metal is the unified interaction parameter model and for the liquid slag the modified quasichemical model (MQM). The MQM was validated by calculating iso-activity lines for the liquid slag components. The PGE method together with the MQM was validated by calculating liquidus lines for solid components. The results were compared with measurements from literature. The full chemical reaction model was validated by comparing the metal and slag compositions to measurements from industrial scale converter. The predictions were found to be in good agreement with the measured values. Furthermore, the accuracy of the model was found to compare favorably with the models proposed in the literature. The real-time capability of the proposed model was confirmed in test calculations.

Investigation of Reaction Mechanism on the Lime-Free Roasting of Chromium-Containing Slag

NASA Astrophysics Data System (ADS)

Yu, Kai-ping; Zhang, Hong-ling; Chen, Bo; Xu, Hong-bin; Zhang, Yi

2015-12-01

The lime-free roasting process of trivalent chromium-containing slag was investigated. The effect of Fe and liquid phase on the conversion reaction of chromium was discussed. The oxidation of trivalent chromium depends greatly on the diffusion of Na+ and O2. Both the raw material Na2CO3 and the intermediate product NaFeO2 serve as the carriers of Na+. The Na+ diffusion is improved by the binary liquid phase of Na2CrO4-Na2CO3, whereas excess liquid phase results in a low conversion rate of chromium by hindering the diffusion of oxygen towards the reaction interface. With the increasing of liquid volume, the controlled step of chromium oxidation changes from Na+ diffusion to oxygen diffusion. The mechanism study showed that the volume of liquid phase increased while raising the reaction temperature or prolonging the reaction time. Based on the role of both liquid phase and Fe, the oxidation process of chromium was summarized as a three-stage model: the Na+ diffusion-controlled stage, the O2 diffusion-controlled stage, and the oxidation reaction halted stage.

Experimental Study on the Behavior of TiN and Ti2O3 Inclusions in Contact with CaO‐Al2O3‐SiO2‐MgO Slags

PubMed Central

Bernhard, C.

2017-01-01

TiN and Ti2O3 are the predominant inclusion types in Ti-alloyed ferritic chromium stainless steels. In order to ensure the required steel cleanness level, an effective removal of such inclusions in the slag during secondary metallurgy is essential. This inclusion removal predominantly takes place via dissolution of the inclusion in the slag. The dissolution behavior of TiN and Ti2O3 in CaO-SiO2-Al2O3-MgO slags as well as their agglomeration behavior in the liquid steel is investigated using High Temperature Laser Scanning Confocal Microscopy and Tammann Furnace experiments. Thermodynamic calculations are performed using FactSage 7.0. The behavior of TiN is observed to be completely different to that of oxides. Ti2O3 dissolves quickly in slags, and its dissolution behavior is comparable to that of other already well examined oxides. In contrast, TiN shows a very intense gas reaction which is attributed to the release of nitrogen during contact with slag. Slags with higher SiO2 content show a significantly higher ability for the dissolution of TiN as compared to Al2O3-rich slags. The gas reaction is found to also significantly influence the final steel cleanness. Despite the easy absorption of TiN in the slag, the formed nitrogen supports the formation of pinholes in the steel. PMID:29109805

Leaching of silicon from ferronickel (FeNi) smelting slag with sodium hydroxide solution at atmospheric pressure

NASA Astrophysics Data System (ADS)

Mufakhir, F. R.; Mubarok, M. Z.; Ichlas, Z. T.

2018-01-01

The present paper reports the leaching behavior of silicon from ferronickel slag under atmospheric pressure using sodium hydroxide solution. The effect of several experimental variables, namely concentration of leaching agent, operating temperature, stirring speed, and slurry density was investigated. The leaching kinetic was also investigated by using shrinking core model. It was determined that leaching of silicon from the slag was controlled by diffusion through product layer, although the activation energy was found to be 85.84 kJ/mol, which was unusually high for such a diffusion-controlled process.

Vertical distribution of trace-element concentrations and occurrence of metallurgical slag particles in accumulated bed sediments of Lake Roosevelt, Washington, September 2002

USGS Publications Warehouse

Cox, S.E.; Bell, P.R.; Lowther, J.S.; Van Metre, P.C.

2005-01-01

Sediment cores were collected from six locations in Lake Roosevelt to determine the vertical distributions of trace-element concentrations in the accumulated sediments of Lake Roosevelt. Elevated concentrations of arsenic, cadmium, copper, lead, mercury, and zinc occurred throughout much of the accumulated sediments. Concentrations varied greatly within the sediment core profiles, often covering a range of 5 to 10 fold. Trace-element concentrations typically were largest below the surficial sediments in the lower one-half of each profile, with generally decreasing concentrations from the 1964 horizon to the surface of the core. The trace-element profiles reflect changes in historical discharges of trace elements to the Columbia River by an upstream smelter. All samples analyzed exceeded clean-up guidelines adopted by the Confederated Tribes of the Colville Reservation for cadmium, lead, and zinc and more than 70 percent of the samples exceeded cleanup guidelines for mercury, arsenic, and copper. Although 100 percent of the samples exceeded sediment guidelines for cadmium, lead, and zinc, surficial concentrations of arsenic, copper, and mercury in some cores were less than the sediment-quality guidelines. With the exception of copper, the trace-element profiles of the five cores collected along the pre-reservoir Columbia River channel typically showed trends of decreasing concentrations in sediments deposited after the 1964 time horizon. The decreasing concentrations of trace elements in the upper half of cores from along the pre-reservoir Columbia River showed a pattern of decreasing concentrations similar to reductions in trace-element loading in liquid effluent from an upstream smelter. Except for arsenic, trace-element concentrations typically were smaller at downstream reservoir locations along the pre-reservoir Columbia River. Trace-element concentration in sediments from the Spokane Arm of the reservoir showed distinct differences compared to the similarities observed in cores from along the pre-reservoir Columbia River. Particles of slag, which have physical and chemical characteristics of slag discharged to the Columbia River by a lead-zinc smelter upstream of the reservoir at Trail, British Columbia, were found in sediments of Lake Roosevelt. Slag particles are more common in the upstream reaches of the reservoir. The chemical composition of the interior matrix of slag collected from Lake Roosevelt closely approximated the reported elemental concentrations of fresh smelter slag, although evidence of slag weathering was observed. Exfoliation flakes were observed on the surface of weathered slag particles isolated from the core sediments. The concentrations of zinc on the exposed surface of slag grains were smaller than concentrations on interior surfaces. Weathering rinds also were observed in the cross section of weathered slag grains, indicating that the glassy slag material was undergoing hydration and chemical weathering. Trace elements observed in accumulated sediments in the middle and lower reaches of the reservoir are more likely due to the input from liquid effluent discharges compared to slag discharges from the upstream smelter.

Use of steel slag as a new material for roads

NASA Astrophysics Data System (ADS)

Ochoa Díaz, R.; Romero Farfán, M.; Cardenas, J.; Forero, J.

2017-12-01

This research paper aims to analyse the behaviour of MDC-19 hot dense asphalt mixtures with steel slag as coarse aggregate, by using asphalt 80-100, in order to verify if this residue has suitable characteristics that allow its use. The physical and mechanical characterization was accomplished using phosphorous slag from the company Acerías Paz del Río S.A. The working formula was then determined for each mixture using the RAMCODES methodology, the briquettes were produced in the laboratory and then, the design verification was performed. Taking into account the results obtained, it is concluded that the use of phosphorous slag as coarse aggregate in asphalt mixtures is workable, since acceptable design parameters and verification are obtained that meet the specifications for use as a rolling layer.

Kinetics of Reduction of CaO-FeO x -MgO-PbO-SiO2 Slags by CO-CO2 Gas Mixtures

NASA Astrophysics Data System (ADS)

Jahanshahi, Sharif; Wright, Steven

2017-08-01

Kinetics of the reaction of lead slags (PbO-CaO-SiO2-FeO x -MgO) with CO-CO2 gas mixtures was studied by monitoring the changes in the slag composition when a stream of CO-CO2 gas mixture was blown on the surface of thin layers of slags (3 to 10 mm) at temperatures in the range of 1453 K to 1593 K (1180 °C to 1320 °C). These measurements were carried out under conditions where mass transfer in the gas phase was not the rate-limiting step and the reduction rates were insensitive to factors affecting mass transfer in the slag phase. The results show simultaneous reduction of PbO and Fe2O3 in the slag. The measured specific rate of oxygen removal from the melts varied from about 1 × 10-6 to 4 × 10-5 mol O cm-2 s-1 and was strongly dependent on the slag chemistry and its oxidation state, partial pressure of CO in the reaction gas mixture, and temperature. The deduced apparent first-order rate constant increased with increasing iron oxide content, oxidation state of the slag, and temperature. The results indicate that under the employed experimental conditions, the rate of formation of CO2 at the gas-slag interface is likely to be the rate-limiting step.

Effects of Slag-Based Silicon Fertilizer on Rice Growth and Brown-Spot Resistance

PubMed Central

Ning, Dongfeng; Song, Alin; Fan, Fenliang; Li, Zhaojun; Liang, Yongchao

2014-01-01

It is well documented that slag-based silicon fertilizers have beneficial effects on the growth and disease resistance of rice. However, their effects vary greatly with sources of slag and are closely related to availability of silicon (Si) in these materials. To date, few researches have been done to compare the differences in plant performance and disease resistance between different slag-based silicon fertilizers applied at the same rate of plant-available Si. In the present study both steel and iron slags were chosen to investigate their effects on rice growth and disease resistance under greenhouse conditions. Both scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to examine the effects of slags on ultrastructural changes in leaves of rice naturally infected by Bipolaris oryaze, the causal agent of brown spot. The results showed that both slag-based Si fertilizers tested significantly increased rice growth and yield, but decreased brown spot incidence, with steel slag showing a stronger effect than iron slag. The results of SEM analysis showed that application of slags led to more pronounced cell silicification in rice leaves, more silica cells, and more pronounced and larger papilla as well. The results of TEM analysis showed that mesophyll cells of slag-untreated rice leaf were disorganized, with colonization of the fungus (Bipolaris oryzae), including chloroplast degradation and cell wall alterations. The application of slag maintained mesophyll cells relatively intact and increased the thickness of silicon layer. It can be concluded that applying slag-based fertilizer to Si-deficient paddy soil is necessary for improving both rice productivity and brown spot resistance. The immobile silicon deposited in host cell walls and papillae sites is the first physical barrier for fungal penetration, while the soluble Si in the cytoplasm enhances physiological or induced resistance to fungal colonization. PMID:25036893

Reduction of CaO and MgO Slag Components by Al in Liquid Fe

NASA Astrophysics Data System (ADS)

Mu, Haoyuan; Zhang, Tongsheng; Fruehan, Richard J.; Webler, Bryan A.

2018-05-01

This study documents laboratory-scale observations of reactions between Fe-Al alloys (0.1 to 2 wt pct Al) with slags and refractories. Al in steels is known to reduce oxide components in slag and refractory. With continued development of Al-containing Advanced High-Strength Steel (AHSS) grade, the effects of higher Al must be examined because reduction of components such as CaO and MgO could lead to uncontrolled modification of non-metallic inclusions. This may lead to castability or in-service performance problems. In this work, Fe-Al alloys and CaO-MgO-Al2O3 slags were melted in an MgO crucible and samples were taken at various times up to 60 minutes. Inclusions from these samples were characterized using an automated scanning electron microscope equipped with energy dispersive x-ray analysis (SEM/EDS). Initially Al2O3 inclusions were modified to MgAl2O4, then MgO, then MgO + CaO-Al2O3-MgO liquid inclusions. Modification of the inclusions was faster at higher Al levels. Very little Ca modification was observed except at 2 wt pct Al level. The thermodynamic feasibility of inclusion modification and some of the mass transfer considerations that may have led to the differences in the Mg and Ca modification behavior were discussed.

An Assessment of the General Applicability of the Relationship Between Nucleation of CO Bubbles and Mass Transfer of Phosphorus in Liquid Iron Alloys

NASA Astrophysics Data System (ADS)

Gu, Kezhuan; Dogan, Neslihan; Coley, Kenneth S.

2018-06-01

The current paper seeks to demonstrate the general applicability of the authors' recently developed treatment of surface renewal during decarburization of Fe-C-S alloys and its effect on the mass transport of phosphorus in the metal phase. The proposed model employs a quantitative model of CO bubble nucleation in the metal to predict the rate of surface renewal, which can then in turn be used to predict the mass-transfer coefficient for phosphorus. A model of mixed transport control in the slag and metal phases was employed to investigate the dephosphorization kinetics between a liquid iron alloy and oxidizing slag. Based on previous studies of the mass-transfer coefficient of FeO in the slag, it was possible to separate the mass transfer coefficient of phosphorus in metal phase, km , from the overall mass-transfer coefficient k_{{o}} . Using this approach, km was investigated under a wide range of conditions and shown to be represented reasonably by the mechanism proposed. The mass-transfer model was tested against results from the literature over a wide range of conditions. The analysis showed that the FeO content in the slag, silicon in the metal and the experimental temperature have strong impact on, km , almost entirely because of their effect on decarburization behavior.

An Assessment of the General Applicability of the Relationship Between Nucleation of CO Bubbles and Mass Transfer of Phosphorus in Liquid Iron Alloys

NASA Astrophysics Data System (ADS)

Gu, Kezhuan; Dogan, Neslihan; Coley, Kenneth S.

2018-02-01

The current paper seeks to demonstrate the general applicability of the authors' recently developed treatment of surface renewal during decarburization of Fe-C-S alloys and its effect on the mass transport of phosphorus in the metal phase. The proposed model employs a quantitative model of CO bubble nucleation in the metal to predict the rate of surface renewal, which can then in turn be used to predict the mass-transfer coefficient for phosphorus. A model of mixed transport control in the slag and metal phases was employed to investigate the dephosphorization kinetics between a liquid iron alloy and oxidizing slag. Based on previous studies of the mass-transfer coefficient of FeO in the slag, it was possible to separate the mass transfer coefficient of phosphorus in metal phase, km , from the overall mass-transfer coefficient k_{{o}} . Using this approach, km was investigated under a wide range of conditions and shown to be represented reasonably by the mechanism proposed. The mass-transfer model was tested against results from the literature over a wide range of conditions. The analysis showed that the FeO content in the slag, silicon in the metal and the experimental temperature have strong impact on, km , almost entirely because of their effect on decarburization behavior.

Protective sheath for a continuous measurement thermocouple

DOEpatents

Phillippi, R.M.

1991-12-03

Disclosed is a protective thermocouple sheath of a magnesia graphite refractory material for use in continuous temperature measurements of molten metal in a metallurgical ladle and having a basic slag layer thereon. The sheath includes an elongated torpedo-shaped sheath body formed of a refractory composition and having an interior borehole extending axially therethrough and adapted to receive a thermocouple. The sheath body includes a lower end which is closed about the borehole and forms a narrow, tapered tip. The sheath body also includes a first body portion integral with the tapered tip and having a relatively constant cross section and providing a thin wall around the borehole. The sheath body also includes a second body portion having a relatively constant cross section larger than the cross section of the first body portion and providing a thicker wall around the borehole. The borehole terminates in an open end at the second body portion. The tapered tip is adapted to penetrate the slag layer and the thicker second body portion and its magnesia constituent material are adapted to withstand chemical attack thereon from the slag layer. The graphite constituent improves thermal conductivity of the refractory material and, thus, enhances the thermal responsiveness of the device. 4 figures.

Protective sheath for a continuous measurement thermocouple

DOEpatents

Phillippi, R. Michael

1991-01-01

Disclosed is a protective thermocouple sheath of a magnesia graphite refractory material for use in continuous temperature measurements of molten metal in a metallurgical ladle and having a basic slag layer thereon. The sheath includes an elongated torpedo-shaped sheath body formed of a refractory composition and having an interior borehole extending axially therethrough and adapted to receive a thermocouple. The sheath body includes a lower end which is closed about the borehole and forms a narrow, tapered tip. The sheath body also includes a first body portion integral with the tapered tip and having a relatively constant cross section and providing a thin wall around the borehole. The sheath body also includes a second body portion having a relatively constant cross section larger than the cross section of the first body portion and providing a thicker wall around the borehole. The borehole terminates in an open end at the second body portion. The tapered tip is adapted to penetrate the slag layer and the thicker second body portion and its magnesia constituent material are adapted to withstand chemical attack thereon from the slag layer. The graphite constituent improves thermal conductivity of the refractory material and, thus, enhances the thermal responsiveness of the device.

Formation mechanism of the protective layer in a blast furnace hearth

NASA Astrophysics Data System (ADS)

Jiao, Ke-xin; Zhang, Jian-liang; Liu, Zheng-jian; Xu, Meng; Liu, Feng

2015-10-01

A variety of techniques, such as chemical analysis, scanning electron microscopy-energy dispersive spectroscopy, and X-ray diffraction, were applied to characterize the adhesion protective layer formed below the blast furnace taphole level when a certain amount of titanium- bearing burden was used. Samples of the protective layer were extracted to identify the chemical composition, phase assemblage, and distribution. Furthermore, the formation mechanism of the protective layer was determined after clarifying the source of each component. Finally, a technical strategy was proposed for achieving a stable protective layer in the hearth. The results show that the protective layer mainly exists in a bilayer form in the sidewall, namely, a titanium-bearing layer and a graphite layer. Both the layers contain the slag phase whose major crystalline phase is magnesium melilite (Ca2MgSi2O7) and the main source of the slag phase is coke ash. It is clearly determined that solid particles such as graphite, Ti(C,N) and MgAl2O4 play an important role in the formation of the protective layer, and the key factor for promoting the formation of a stable protective layer is reasonable control of the evolution behavior of coke.

Effects of Slag Ejection on Solid Rocket Motor Performance

NASA Technical Reports Server (NTRS)

Whitesides, R. Harold; Purinton, David C.; Hengel, John E.; Skelley, Stephen E.

1995-01-01

In past firings of the Reusable Solid Rocket Motor (RSRM) both static test and flight motors have shown small pressure perturbations occurring primarily between 65 and 80 seconds. A joint NASA/Thiokol team investigation concluded that the cause of the pressure perturbations was the periodic ingestion and ejection of molten aluminum oxide slag from the cavity around the submerged nozzle nose which tends to trap and collect individual aluminum oxide droplets from the approach flow. The conclusions of the team were supported by numerous data and observations from special tests including high speed photographic films, real time radiography, plume calorimeters, accelerometers, strain gauges, nozzle TVC system force gauges, and motor pressure and thrust data. A simplistic slag ballistics model was formulated to relate a given pressure perturbation to a required slag quantity. Also, a cold flow model using air and water was developed to provide data on the relationship between the slag flow rate and the chamber pressure increase. Both the motor and the cold flow model exhibited low frequency oscillations in conjunction with periods of slag ejection. Motor and model frequencies were related to scaling parameters. The data indicate that there is a periodicity to the slag entrainment and ejection phenomena which is possibly related to organized oscillations from instabilities in the dividing streamline shear layer which impinges on the underneath surface of the nozzle.

New welding fluxes based on silicomanganese slag for deposition and welding of canopies and crib bed of mine support

NASA Astrophysics Data System (ADS)

Kryukov, R. E.; Kozyrev, N. A.; Usoltsev, A. A.; Kozyreva, O. E.

2017-09-01

The paper considers the possibility of efficient use of silicomanganese slag for the production of welding fluxes. The results of studying the use of metallurgical wastes as components of welding fluxes are given. Analysis of the results of mechanical properties of the samples made it possible to determine the optimum content of the pulverized fraction less than 0.45 mm in the flux. The composition and technology of manufacturing a new welding flux using slag of silicomanganese production was developed. The effect of fractional composition on the welding-technological properties of fluxes was studied. The optimal content of liquid glass in the flux, which allows a favorable complex of mechanical properties to be obtained, is 20-30%. To reduce the level of contamination of the weld metal with non-metallic oxide inclusions and to increase the mechanical properties of the welded joint, it is proposed to introduce a carbon-fluorine-containing additive FD-UFS into fluxes based on the slag.

High temperature desulfurization of synthesis gas

DOEpatents

Najjar, Mitri S.; Robin, Allen M.

1989-01-01

The hot process gas stream from the partial oxidation of sulfur-containing heavy liquid hydrocarbonaceous fuel and/or sulfur-containing solid carbonaceous fuel comprising gaseous mixtures of H.sub.2 +CO, sulfur-containing gases, entrained particulate carbon, and molten slag is passed through the unobstructed central passage of a radiant cooler where the temperature is reduced to a temperature in the range of about 1800.degree. F. to 1200.degree. F. From about 0 to 95 wt. % of the molten slag and/or entrained material may be removed from the hot process gas stream prior to the radiant cooler with substantially no reduction in temperature of the process gas stream. In the radiant cooler, after substantially all of the molten slag has solidified, the sulfur-containing gases are contacted with a calcium-containing material to produce calcium sulfide. A partially cooled stream of synthesis gas, reducing gas, or fuel gas containing entrained calcium sulfide particulate matter, particulate carbon, and solidified slag leaves the radiant cooler containing a greatly reduced amount of sulfur-containing gases.

Selective Sulfidation of Lead Smelter Slag with Sulfur

NASA Astrophysics Data System (ADS)

Han, Junwei; Liu, Wei; Wang, Dawei; Jiao, Fen; Qin, Wenqing

2016-02-01

The selective sulfidation of lead smelter slag with sulfur was studied. The effects of temperature, sulfur dosage, carbon, and Na salts additions were investigated based on thermodynamic calculation. The results indicated that more than 96 pct of zinc in the slag could be converted into sulfides. Increasing temperature, sulfur dosage, or Na salts dosage was conducive to the sulfidation of the zinc oxides in the slag. High temperature and excess Na salts would result in the more consumption of carbon and sulfur. Carbon addition not only promoted the selective sulfidation but reduced the sulfur dosage and eliminated the generation of SO2. Iron oxides had a buffering role on the sulfur efficient utilization. The transformation of sphalerite to wurtzite was feasible under reducing condition at high temperature, especially above 1273 K (1000 °C). The growth of ZnS particles largely depended upon the roasting temperature. They were significantly increased when the temperature was above 1273 K (1000 °C), which was attributed to the formation of a liquid phase.

Kinetics of steel slag leaching: Batch tests and modeling

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Windt, Laurent, E-mail: laurent.dewindt@mines-paristech.fr; Chaurand, Perrine; Rose, Jerome

2011-02-15

Reusing steel slag as an aggregate for road construction requires to characterize the leaching kinetics and metal releases. In this study, basic oxygen furnace (BOF) steel slag were subjected to batch leaching tests at liquid to solid ratios (L/S) of 10 and 100 over 30 days; the leachate chemistry being regularly sampled in time. A geochemical model of the steel slag is developed and validated from experimental data, particularly the evolution with leaching of mineralogical composition of the slag and trace element speciation. Kinetics is necessary for modeling the primary phase leaching, whereas a simple thermodynamic equilibrium approach can bemore » used for secondary phase precipitation. The proposed model simulates the kinetically-controlled dissolution (hydrolysis) of primary phases, the precipitation of secondary phases (C-S-H, hydroxide and spinel), the pH and redox conditions, and the progressive release of major elements as well as the metals Cr and V. Modeling indicates that the dilution effect of the L/S ratio is often coupled to solubility-controlled processes, which are sensitive to both the pH and the redox potential. A sensitivity analysis of kinetic uncertainties on the modeling of element releases is performed.« less

Fundamental Researches on the High-speed and High-efficiency Steelmaking Reaction

NASA Astrophysics Data System (ADS)

Kitamura, Shin-ya; Shibata, Hiroyuki; Maruoka, Nobuhiro

2012-06-01

Traditionally, steelmaking reactions have been analyzed by thermodynamics. Recently, software packages that can be used to calculate the equilibrium conditions have improved greatly. In some cases, information obtained in this software is useful for analyzing the steelmaking reaction. On the other hand, in industrial operation, steelmaking reactions, i.e., decarburization, dephosphorization, desulfurization or nitrogen removal, do not reach the equilibrium condition. Therefore, the kinetic model is very important for gaining a theoretical understanding of the steelmaking reaction. In this paper, the following recent research activities were shown; 1) mass transfer of impurities between solid oxide and liquid slag, 2) simulation model of hot metal dephosphorization by multiphase slag, 3) evaluation of reaction rate at bath surface in gas-liquid reaction system and 4) condition for forming of metal emulsion by bottom bubbling.

Thin-film versus slurry-phase carbonation of steel slag: CO₂ uptake and effects on mineralogy.

PubMed

Baciocchi, R; Costa, G; Di Gianfilippo, M; Polettini, A; Pomi, R; Stramazzo, A

2015-01-01

The results of direct aqueous accelerated carbonation of three types of steel manufacturing residues, including an electric arc furnace (EAF) slag and two basic oxygen furnace (BOF) slags, are reported. Batch accelerated carbonation tests were conducted at different temperatures and CO2 pressures applying the thin-film route (liquid to solid, L/S, ratio=0.3L/kg) or the slurry-phase route (L/S ratio=5L/kg). The CO2 uptake strongly depended on both the slag characteristics and the process route; maximum yields of 280 (EAF), 325 (BOF1) and 403 (BOF2) gCO2/kg slag were achieved in slurry phase at T=100°C and pCO2=10 bar. Differently from previous studies, additional carbonates (other than Ca-based phases) were retrieved in the carbonated BOF slags, indicating that also Mg-, Fe- and Mn-containing phases partially reacted with CO2 under the tested conditions. The results hence show that the effects of accelerated carbonation in terms of CO2 uptake capacity, yield of mineral conversion into carbonates and mineralogy of the treated product, strongly rely on several factors. These include, above all, the mineralogy of the original material and the operating conditions adopted, which thus need specific case-by-case optimization to maximize the CO2 sequestration yield. Copyright © 2014 Elsevier B.V. All rights reserved.

SRM Internal Flow Tests and Computational Fluid Dynamic Analysis. Volume 2; RSRM Full Scale Motor Analyses

NASA Technical Reports Server (NTRS)

1995-01-01

The purpose of the RSRM Nozzle Slag Ejection Precursor Test is to investigate the effect that slag ejection from the RSRM nozzle has on the chamber pressure and trust of the SRB's. In past firings of the Reusable Solid Rocket Motor (RSRM) both static test and flight motors have shown small pressure perturbations occurring primarily between 65 and 80 seconds. A joint NASA/Thiokol team investigation concluded that the cause of the pressure perturbations was the periodic ingestion and ejection of molten aluminum oxide slag from the cavity around the submerged nozzle nose which tends to trap and collect individual aluminum oxide droplets from the approach flow. The conclusions of the team were supported by numerous data and observations from special tests including high speed photographic films, real time radiography, plume calorimeters, accelerometers, strain gauges, nozzle TVC system force gauges, and motor pressure and thrust data. A simplistic slag ballistics model was formulated to relate a given pressure perturbation to a required slag quantity. Also, a cold flow model using air and water was developed to provide data on the relationship between the slag flow rate and the chamber pressure increase. Both the motor and the cold flow model exhibited low frequency oscillations in conjunction with periods of slag ejection. Motor and model frequencies were related to scaling parameters. The data indicate that there is a periodicity to the slag entrainment and ejection phenomena which is possibly related to organized oscillations from instabilities in the dividing streamline shear layer which impinges on the underneath surface of the nozzle.

Experimental Liquidus Studies of the Pb-Cu-Si-O System in Equilibrium with Metallic Pb-Cu Alloys

NASA Astrophysics Data System (ADS)

Shevchenko, M.; Nicol, S.; Hayes, P. C.; Jak, E.

2018-03-01

Phase equilibria of the Pb-Cu-Si-O system have been investigated in the temperature range from 1073 K to 1673 K (800 °C to 1400 °C) for oxide liquid (slag) in equilibrium with solid Cu metal and/or liquid Pb-Cu alloy, and solid oxide phases: (a) quartz or tridymite (SiO2) and (b) cuprite (Cu2O). High-temperature equilibration on silica or copper substrates was performed, followed by quenching, and direct measurement of Pb, Cu, and Si concentrations in the liquid and solid phases using the electron probe X-ray microanalysis has been employed to accurately characterize the system in equilibrium with Cu or Pb-Cu metal. All results are projected onto the PbO-"CuO0.5"-SiO2 plane for presentation purposes. The present study is the first-ever systematic investigation of this system to describe the slag liquidus temperatures in the silica and cuprite primary phase fields.

Comparison of Ultrasound-Assisted and Regular Leaching of Vanadium and Chromium from Roasted High Chromium Vanadium Slag

NASA Astrophysics Data System (ADS)

Wen, Jing; Jiang, Tao; Gao, Huiyang; Liu, Yajing; Zheng, Xiaole; Xue, Xiangxin

2018-02-01

Ultrasound-assisted leaching (UAL) was used for vanadium and chromium leaching from roasted material obtained by the calcification roasting of high-chromium-vanadium slag. UAL was compared with regular leaching. The effect of the leaching time and temperature, acid concentration, and liquid-solid ratio on the vanadium and chromium leaching behaviors was investigated. The UAL mechanism was determined from particle-size-distribution and microstructure analyses. UAL decreased the reaction time and leaching temperature significantly. Furthermore, 96.67% vanadium and less than 1% chromium were leached at 60°C for 60 min with 20% H2SO4 at a liquid-solid ratio of 8, which was higher than the maximum vanadium leaching rate of 90.89% obtained using regular leaching at 80°C for 120 min. Ultrasonic waves broke and dispersed the solid sample because of ultrasonic cavitation, which increased the contact area of the roasted sample and the leaching medium, the solid-liquid mass transfer, and the vanadium leaching rate.

Application of Dredged Materials and Steelmaking Slag as Basal Media to Restore and Create Seagrass Beds: Mesocosm and Core Incubation Experiments

NASA Astrophysics Data System (ADS)

Tsukasaki, A.; Suzumura, M.; Tsurushima, N.; Nakazato, T.; Huang, Y.; Tanimoto, T.; Yamada, N.; Nishijima, W.

2016-02-01

Seagrass beds stabilize bottom sediments, improve water quality and light conditions, enhance species diversity, and provide habitat complexity in coastal marine environments. Seagrass beds are now experiencing worldwide decline by rapid environmental changes. Possible options of seagrass bed restoration are civil engineering works including mounding to raise the bottom to elevations with suitable light for seagrass growth. Reuse or recycling of dredged materials (DM) and various industrial by-products including steelmaking slags is a beneficial option to restore and create seagrass beds. To evaluate the applicability of DM and dephosphorization slag (Slag) as basal media of seagrass beds, we carried out mesocosm experiments and core incubation experiments in a land-based flow-through seawater tank over a year. During the mesocosm experiment, no difference was found in growth of eelgrass (Zostera marina L.) and macrobenthic community structures between Slag-based sediments and sand-based control experiments, even though Slag-based sediments exhibited substantially higher pH than sand-based sediments. During the core incubation experiment, we investigated detailed variation and distributions of pH and nutrients, and diffusion fluxes of nutrients between the sediment/seawater interface. Though addition of Slag induced high pH up to 10.7 in deep layers (< 5 cm), the surface pH decreased rapidly within 10 days. Concentrations of dissolved inorganic nitrogen were comparable between Slag- and sand-based sediments, whereas dissolved phosphate concentration was substantially reduced by the addition of Slag. The low concentrations of phosphate was likely due to precipitation with calcium under high pH condition. Diffusion fluxes of nutrients from the cores were comparable with those reported in natural coastal systems. It was suggested that the mixture of Slag and DM is applicable as basal media for construction of artificial seagrass beds.

Effects of Temperature, Oxygen Partial Pressure, and Materials Selection on Slag Infiltration into Porous Refractories for Entrained-Flow Gasifiers

NASA Astrophysics Data System (ADS)

Kaneko, Tetsuya Kenneth

The penetration rate of molten mineral contents (slag) from spent carbonaceous feedstock into porous ceramic-oxide refractory linings is a critical parameter in determining the lifecycle of integrated gasification combined cycle energy production plants. Refractory linings that withstand longer operation without interruption are desirable because they can mitigate consumable and maintenance costs. Although refractory degradation has been extensively studied for many other high-temperature industrial processes, this work focuses on the mechanisms that are unique to entrained-flow gasification systems. The use of unique feedstock mixtures, temperatures from 1450 °C to 1600 °C, and oxygen partial pressures from 10-7 atm to 10-9 atm pose engineering challenges in designing an optimal refractory material. Experimentation, characterization, and modeling show that gasifier slag infiltration into porous refractory is determined by interactions between the slag and the refractory that either form a physical barrier that impedes fluid flow or induce an increased fluid viscosity that decelerates the velocity of the fluid body. The viscosity of the slag is modified by the thermal profile of the refractory along the penetration direction as well as reactions between the slag and refractory that alter the chemistry, and thereby the thermo-physical properties of the fluid. Infiltration experiments reveal that the temperature gradient inherently present along the refractory lining limits penetration. A refractory in near-isothermal conditions demonstrates deeper slag penetration as compared to one that experiences a steeper thermal profile. The decrease in the local temperatures of the slag as it travels deeper into the refractory increases the viscosity of the fluid, which in turn slows the infiltration velocity of fluid body into the pores of the refractory microstructure. With feedstock mixtures that exhibit high iron-oxide concentrations, a transition-metal-oxide, the oxygen partial pressure of the operating atmosphere regulates the penetration of slag into refractory. The viscosity of the slag, which dictates its penetration rate, is influenced by the oxidation state of the Fe cation. Slag penetrations are shallower in oxidizing conditions than they are in reducing conditions because the iron-oxide from the slag solutions into the corundum-structured refractory and the slag is depleted of iron-oxide, increasing the viscosity of slags. Equally, the chemistries of both the refractory and slag materials dictate the course of penetration. Cr2O3-Al2O3 refractory limits mixed feedstock slag penetration through formation of a chromium spinel layer that functions as a physical obstacle against fluid flow. Al2O 3-SiO2 refractory limits eastern coal feedstock slag penetration as a result of refractory dissolution of SiO2, which increases the viscosity of slags. A physical model, which considers unidirectional fluid flow of slag through each pore of the porous microstructure of the refractory, sufficiently approximates the penetration depth of the slag into the refractory. Agreement between experiments and the physical model demonstrates that the slag is driven into the refractory by capillary pressure. Since the viscosity of the slag continuously changes as the slag travels through the inherent temperature gradient of the refractory lining, the model incorporates dynamic viscosities that are dependent on both temperature and composition to project depths that are unique to the experimental parameters. The significantly different length scales of the radial and penetration directions of the pores allows for the application of a lubrication approximation onto the momentum equation. This process produces an analytical solution that effectively envelopes the variable viscosity into a single term.

Model of Inclusion Evolution During Calcium Treatment in the Ladle Furnace

NASA Astrophysics Data System (ADS)

Tabatabaei, Yousef; Coley, Kenneth S.; Irons, Gordon A.; Sun, Stanley

2018-04-01

Calcium treatment of steel is typically employed to modify alumina inclusions to liquid calcium aluminates. However, injected calcium also reacts with the dissolved sulfur to form calcium sulfide. The current work aims to develop a kinetic model for the evolution of oxide and sulfide inclusions in Al-killed alloyed steel during Ca treatment in the ladle refining process. The model considers dissolution of the calcium from the calcium bubbles into the steel and reduction of calcium oxide in the slag to dissolved calcium. A steel-inclusion kinetic model is used for mass transfer to the inclusion interface and diffusion within the calcium aluminate phases formed on the inclusion. The inclusion-steel kinetic model is then coupled with a previously developed steel-slag kinetic model. The coupled inclusion-steel-slag kinetic model is applied to the chemical composition changes in molten steel, slag, and evolution of inclusions in the ladle. The result of calculations is found to agree well with an industrial heat for species in the steel as well as inclusions during Ca treatment.

Numerical modeling of materials processes with fluid-fluid interfaces

NASA Astrophysics Data System (ADS)

Yanke, Jeffrey Michael

A numerical model has been developed to study material processes that depend on the interaction between fluids with a large discontinuity in thermophysical properties. A base model capable of solving equations of mass, momentum, energy conservation, and solidification has been altered to enable tracking of the interface between two immiscible fluids and correctly predict the interface deformation using a volume of fluid (VOF) method. Two materials processes investigated using this technique are Electroslag Remelting (ESR) and plasma spray deposition. ESR is a secondary melting technique that passes an AC current through an electrically resistive slag to provide the heat necessary to melt the alloy. The simulation tracks the interface between the slag and metal. The model was validated against industrial scale ESR ingots and was able to predict trends in melt rate, sump depth, macrosegregation, and liquid sump depth. In order to better understand the underlying physics of the process, several constant current ESR runs simulated the effects of freezing slag in the model. Including the solidifying slag in the imulations was found to have an effect on the melt rate and sump shape but there is too much uncertainty in ESR slag property data at this time for quantitative predictions. The second process investigated in this work is the deposition of ceramic coatings via plasma spray deposition. In plasma spray deposition, powderized coating material is injected into a plasma that melts and carries the powder towards the substrate were it impacts, flattening out and freezing. The impacting droplets pile up to form a porous coating. The model is used to simulate this rain of liquid ceramic particles impacting the substrate and forming a coating. Trends in local solidification time and porosity are calculated for various particle sizes and velocities. The predictions of decreasing porosity with increasing particle velocity matches previous experimental results. Also, a preliminary study was conducted to investigate the effects of substrate surface defects and droplet impact angle on the propensity to form columnar porosity.

Correlation of the Processing Parameters in the Formation of Granulated Ground Blast Furnace Slag Geopolymer

NASA Astrophysics Data System (ADS)

Aziz, I. H.; Abdullah, M. M. A. B.; Yong, H. C.; Ming, L. Y.; Panias, D.; Sakkas, K.

2017-06-01

Geopolymers are inorganic materials with huge potential applications including building material, fire resistant materials, and agricultural construction materials. Various parameters influenced the final properties of these geopolymer concretes. This study developed the effects of several factors such as solid-to-liquid ratio, NaOH concentration, and Na2SiO3/NaOH ratio on the compressive strength of granulated ground blast furnace slag (GGBFS) by statistical design of experiment (DOE) approach. Analysis of the experimental results through ANOVA exhibited that the specimen with NaOH concentration of 10M, Na2SiO3/NaOH ratio equals to 2.5, and solid-to-liquid ratio of 3.0 curing at room temperatures for 28 days was potential of highest strength (168.705 MPa) in the considered procedure. Besides, the relationship between compressive strength and influential factors could be suitably by fraction factorial design method.

In Situ Observation of Dissolution of Oxide Inclusions in Steelmaking Slags

NASA Astrophysics Data System (ADS)

Sharma, Mukesh; Mu, Wangzhong; Dogan, Neslihan

2018-05-01

Better understanding of removal of non-metallic inclusions is of importance in the steelmaking process to control the cleanliness of steel. In this study, the dissolution rate of Al2O3 and Al2TiO5 inclusions in a liquid CaO-SiO2-Al2O3 slag was measured using high-temperature confocal scanning laser microscopy (HT-CSLM) at 1550°C. The dissolution rate of inclusions is expressed as a function of the rate of decrease of the radius of solid particles with time. It is found that Al2O3 inclusions have a slower dissolution rate than that of Al2TiO5 inclusions at 1550°C. The rate-limiting steps are investigated in terms of a shrinking core model. It is shown that the rate-limiting step for dissolution of both inclusion types is mass transfer in the slag at 1550°C.

CO2 sequestration by carbonation of steelmaking slags in an autoclave reactor.

PubMed

Chang, E-E; Pan, Shu-Yuan; Chen, Yi-Hung; Chu, Hsiao-Wen; Wang, Chu-Fang; Chiang, Pen-Chi

2011-11-15

Carbon dioxide (CO(2)) sequestration experiments using the accelerated carbonation of three types of steelmaking slags, i.e., ultra-fine (UF) slag, fly-ash (FA) slag, and blended hydraulic slag cement (BHC), were performed in an autoclave reactor. The effects of reaction time, liquid-to-solid ratio (L/S), temperature, CO(2) pressure, and initial pH on CO(2) sequestration were evaluated. Two different CO(2) pressures were chosen: the normal condition (700 psig) and the supercritical condition (1300 psig). The carbonation conversion was determined quantitatively by using thermo-gravimetric analysis (TGA). The major factors that affected the conversion were reaction time (5 min to 12h) and temperature (40-160°C). The BHC was found to have the highest carbonation conversion of approximately 68%, corresponding to a capacity of 0.283 kg CO(2)/kg BHC, in 12h at 700 psig and 160°C. In addition, the carbonation products were confirmed to be mainly in CaCO(3), which was determined by using scanning electron microscopy (SEM) and X-ray powder diffraction (XRD) to analyze samples before and after carbonation. Furthermore, reaction kinetics were expressed with a surface coverage model, and the carbon footprint of the developed technology in this investigation was calculated by a life cycle assessment (LCA). Copyright © 2011 Elsevier B.V. All rights reserved.

An innovative wood-chip-framework substrate used as slow-release carbon source to treat high-strength nitrogen wastewater.

PubMed

Li, Huai; Chi, Zifang; Yan, Baixing; Cheng, Long; Li, Jianzheng

2017-01-01

Removal of nitrogen in wastewater before discharge into receiving water courses is an important consideration in treatment systems. However, nitrogen removal efficiency is usually limited due to the low carbon/nitrogen (C/N) ratio. A common solution is to add external carbon sources, but amount of liquid is difficult to determine. Therefore, a combined wood-chip-framework substrate (with wood, slag and gravel) as a slow-release carbon source was constructed in baffled subsurface-flow constructed wetlands to overcome the problem. Results show that the removal rate of ammonia nitrogen (NH 4 + -N), total nitrogen (TN) and chemical oxygen demand (COD) could reach 37.5%-85%, 57.4%-86%, 32.4%-78%, respectively, indicating the combined substrate could diffuse sufficient oxygen for the nitrification process (slag and gravel zone) and provide carbon source for denitrification process (wood-chip zone). The nitrification and denitrification were determined according to the location of slag/gravel and wood-chip, respectively. Nitrogen removal was efficient at the steady phase before a shock loading using slag-wood-gravel combined substrate because of nitrification-denitrification process, while nitrogen removal was efficient under a shock loading with wood-slag-gravel combined substrate because of ANAMMOX process. This study provides a new idea for wetland treatment of high-strength nitrogen wastewater. Copyright © 2016. Published by Elsevier B.V.

Removal of phosphorus-rich phase from high-phosphorous iron ore by melt separation at 1573 K in a super-gravity field

NASA Astrophysics Data System (ADS)

Gao, Jin-tao; Guo, Lei; Zhong, Yi-wei; Ren, Hong-ru; Guo, Zhan-cheng

2016-07-01

A new approach of removing the phosphorus-rich phase from high-phosphorous iron ore by melt separation at 1573 K in a super- gravity field was investigated. The iron-slag separation by super-gravity resulted in phosphorus being effectively removed from the iron-rich phase and concentrated as a phosphorus-rich phase at a temperature below the melting point of iron. The samples obtained by super-gravity exhibited obvious layered structures. All the iron grains concentrated at the bottom of the sample along the super-gravity direction, whereas the molten slag concentrated in the upper part of the sample along the opposite direction. Meanwhile, fine apatite crystals collided and grew into larger crystals and concentrated at the slag-iron interface. Consequently, in the case of centrifugation with a gravity coefficient of G = 900, the mass fractions of the slag phase and iron-rich phase were similar to their respective theoretical values. The mass fraction of MFe in the iron-rich phase was as high as 97.77wt% and that of P was decreased to 0.092wt%.

A Mathematical Model for the Multiphase Transport and Reaction Kinetics in a Ladle with Bottom Powder Injection

NASA Astrophysics Data System (ADS)

Lou, Wentao; Zhu, Miaoyong

2017-12-01

A computation fluid dynamics-population balance model-simultaneous reaction model (CFD-PBM-SRM) coupled model has been proposed to study the multiphase flow behavior and refining reaction kinetics in a ladle with bottom powder injection, and some new and important phenomena and mechanisms are presented. For the multiphase flow behavior, the effects of bubbly plume flow, powder particle motion, particle-particle collision and growth, particle-bubble collision and adhesion, and powder particle removal into top slag are considered. For the reaction kinetics, the mechanisms of multicomponent simultaneous reactions, including Al, S, Si, Mn, Fe, and O, at the multi-interface, including top slag-liquid steel interface, air-liquid steel interface, powder droplet-liquid steel interface, and bubble-liquid steel interface, are presented, and the effect of sulfur solubility in the powder droplet on the desulfurization is also taken into account. Model validation is carried out using hot tests in a 2-t induction furnace with bottom powder injection. The result shows that the powder particles gradually disperse in the entire furnace; in the vicinity of the bottom slot plugs, the desulfurization product CaS is liquid phase, while in the upper region of the furnace, the desulfurization product CaS is solid phase. The predicted sulfur contents by the present model agree well with the measured data in the 2-t furnace with bottom powder injection.

Process-time Optimization of Vacuum Degassing Using a Genetic Alloy Design Approach

PubMed Central

Dilner, David; Lu, Qi; Mao, Huahai; Xu, Wei; van der Zwaag, Sybrand; Selleby, Malin

2014-01-01

This paper demonstrates the use of a new model consisting of a genetic algorithm in combination with thermodynamic calculations and analytical process models to minimize the processing time during a vacuum degassing treatment of liquid steel. The model sets multiple simultaneous targets for final S, N, O, Si and Al levels and uses the total slag mass, the slag composition, the steel composition and the start temperature as optimization variables. The predicted optimal conditions agree well with industrial practice. For those conditions leading to the shortest process time the target compositions for S, N and O are reached almost simultaneously. PMID:28788286

Numerical Investigation of Desulfurization Kinetics in Gas-Stirred Ladles by a Quick Modeling Analysis Approach

NASA Astrophysics Data System (ADS)

Cao, Qing; Nastac, Laurentiu; Pitts-Baggett, April; Yu, Qiulin

2018-03-01

A quick modeling analysis approach for predicting the slag-steel reaction and desulfurization kinetics in argon gas-stirred ladles has been developed in this study. The model consists of two uncoupled components: (i) a computational fluid dynamics (CFD) model for predicting the fluid flow and the characteristics of slag-steel interface, and (ii) a multicomponent reaction kinetics model for calculating the desulfurization evolution. The steel-slag interfacial area and mass transfer coefficients predicted by the CFD simulation are used as the processing data for the reaction model. Since the desulfurization predictions are uncoupled from the CFD simulation, the computational time of this uncoupled predictive approach is decreased by at least 100 times for each case study when compared with the CFD-reaction kinetics fully coupled model. The uncoupled modeling approach was validated by comparing the evolution of steel and slag compositions with the experimentally measured data during ladle metallurgical furnace (LMF) processing at Nucor Steel Tuscaloosa, Inc. Then, the validated approach was applied to investigate the effects of the initial steel and slag compositions, as well as different types of additions during the refining process on the desulfurization efficiency. The results revealed that the sulfur distribution ratio and the desulfurization reaction can be promoted by making Al and CaO additions during the refining process. It was also shown that by increasing the initial Al content in liquid steel, both Al oxidation and desulfurization rates rapidly increase. In addition, it was found that the variation of the initial Si content in steel has no significant influence on the desulfurization rate. Lastly, if the initial CaO content in slag is increased or the initial Al2O3 content is decreased in the fluid-slag compositional range, the desulfurization rate can be improved significantly during the LMF process.

Numerical Investigation of Desulfurization Kinetics in Gas-Stirred Ladles by a Quick Modeling Analysis Approach

NASA Astrophysics Data System (ADS)

Cao, Qing; Nastac, Laurentiu; Pitts-Baggett, April; Yu, Qiulin

2018-06-01

A quick modeling analysis approach for predicting the slag-steel reaction and desulfurization kinetics in argon gas-stirred ladles has been developed in this study. The model consists of two uncoupled components: (i) a computational fluid dynamics (CFD) model for predicting the fluid flow and the characteristics of slag-steel interface, and (ii) a multicomponent reaction kinetics model for calculating the desulfurization evolution. The steel-slag interfacial area and mass transfer coefficients predicted by the CFD simulation are used as the processing data for the reaction model. Since the desulfurization predictions are uncoupled from the CFD simulation, the computational time of this uncoupled predictive approach is decreased by at least 100 times for each case study when compared with the CFD-reaction kinetics fully coupled model. The uncoupled modeling approach was validated by comparing the evolution of steel and slag compositions with the experimentally measured data during ladle metallurgical furnace (LMF) processing at Nucor Steel Tuscaloosa, Inc. Then, the validated approach was applied to investigate the effects of the initial steel and slag compositions, as well as different types of additions during the refining process on the desulfurization efficiency. The results revealed that the sulfur distribution ratio and the desulfurization reaction can be promoted by making Al and CaO additions during the refining process. It was also shown that by increasing the initial Al content in liquid steel, both Al oxidation and desulfurization rates rapidly increase. In addition, it was found that the variation of the initial Si content in steel has no significant influence on the desulfurization rate. Lastly, if the initial CaO content in slag is increased or the initial Al2O3 content is decreased in the fluid-slag compositional range, the desulfurization rate can be improved significantly during the LMF process.

Thermodynamics of Palladium (Pd) and Tantalum (Ta) Relevant to Secondary Copper Smelting

NASA Astrophysics Data System (ADS)

Shuva, M. A. H.; Rhamdhani, M. A.; Brooks, G. A.; Masood, S. H.; Reuter, M. A.

2017-02-01

The slag-to-metal distribution ratios of palladium (Pd), L_{{Pd}}^{s/m} , in the range of oxygen partial pressure ( pO2) from 10-10 to 10-7 atm at 1473 K to 1623 K (1200 °C to 1350 °C); distribution ratios of tantalum (Ta), L_{{Ta}}^{s/m} , in the range of pO2 from 10-16 to 10-12 atm at 1673 K and 1873 K (1400 °C and 1600 °C), have been determined in this study. The L_{{Pd}}^{s/m} in FeO x -CaO-SiO2-MgO and copper at 1573 K (1300 °C) and pO2 = 10-8 atm is dependant strongly on basicity of slag, i.e. (CaO + MgO)/SiO2 or optical basicity. The current results suggest that Pd presents in the FeO x -CaO-SiO2-MgO slag predominantly as Pd2+. The activity coefficient of PdO in the slag at 1573 K (1300 °C) and pO2 = 10-8 atm was calculated to be in the range of 3.89 × 10-3 to 2.63 × 10-2. The L_{{Pd}}^{s/m} was also found to increase with increasing of pO2 and with decreasing of temperature. It was observed that Ta mostly partition to slag phase and very small amount of Ta was found in liquid copper at the high temperature and reduced condition studied. It can be suggested that to promote recovery of palladium from Pd-containing e-waste, a slag with lower silica content and basic flux based, high temperature with reducing atmosphere, is highly desired particularly in secondary copper smelting.

Wetting Behavior of Calcium Ferrite Slags on Cristobalite Substrates

NASA Astrophysics Data System (ADS)

Yang, Mingrui; Lv, Xuewei; Wei, Ruirui; Xu, Jian; Bai, Chenguang

2018-03-01

Calcium ferrite (CF) is a significant intermediate adhesive phase in high-basicity sinters. The wettability between calcium ferrite (CF) and gangue plays an important role in the assimilation process. The wettability of CF-based slags, in which a constant amount (2 mass pct.) of Al2O3, MgO, SiO2, and TiO2 was added, on solid SiO2 (cristobalite) substrates at 1523 K (1250 °C) was investigated. The interfacial microstructure and spreading mechanisms were discussed for each sample. All the tested slag samples exhibited good wettability on the SiO2 substrate. The initial apparent contact angles were in the range of 20 to 50 deg, while the final apparent contact angles were 5 deg. The wetting process could be divided into three stages on the basis of the change in diameter, namely the "linear spreading" stage, "spreading rate reduction" stage, and "wetting equilibrium" stage. It was found that the CF-SiO2 wetting system exhibits dissolutive wetting and the dissolution of SiO2 into slag influences its spreading process. The spreading rate increases with a decrease in the ratio of viscosity to interfacial tension, which is a result of the addition of Al2O3, MgO, SiO2, and TiO2. After cooling, a deep corrosion pit was formed in the substrate and a diffusion layer was generated in front of the residual slag zone; further, some SiO2 and Fe2O3 solid solutions precipitated in the slag.

Geochemistry of extremely alkaline (pH>12) ground water in slag-fill aquifers.

PubMed

Roadcap, George S; Kelly, Walton R; Bethke, Craig M

2005-01-01

Extremely alkaline ground water has been found underneath many shuttered steel mills and slag dumps and has been an impediment to the cleanup and economic redevelopment of these sites because little is known about the geochemistry. A large number of these sites occur in the Lake Calumet region of Chicago, Illinois, where large-scale infilling of the wetlands with steel slag has created an aquifer with pH values as high as 12.8. To understand the geochemistry of the alkaline ground water system, we analyzed samples of ground water and the associated slag and weathering products from four sites. We also considered several potential remediation schemes to lower the pH and toxicity of the water. The principal cause of the alkaline conditions is the weathering of calcium silicates within the slag. The resulting ground water at most of the sites is dominated by Ca2+ and OH- in equilibrium with Ca(OH)2. Where the alkaline ground water discharges in springs, atmospheric CO2 dissolves into the water and thick layers of calcite form. Iron, manganese, and other metals in the metallic portion of the slag have corroded to form more stable low-temperature oxides and sulfides and have not accumulated in large concentrations in the ground water. Calcite precipitated at the springs is rich in a number of heavy metals, suggesting that metals can move through the system as particulate matter. Air sparging appears to be an effective remediation strategy for reducing the toxicity of discharging alkaline water.

Wetting Behavior of Calcium Ferrite Slags on Cristobalite Substrates

NASA Astrophysics Data System (ADS)

Yang, Mingrui; Lv, Xuewei; Wei, Ruirui; Xu, Jian; Bai, Chenguang

2018-06-01

Calcium ferrite (CF) is a significant intermediate adhesive phase in high-basicity sinters. The wettability between calcium ferrite (CF) and gangue plays an important role in the assimilation process. The wettability of CF-based slags, in which a constant amount (2 mass pct.) of Al2O3, MgO, SiO2, and TiO2 was added, on solid SiO2 (cristobalite) substrates at 1523 K (1250 °C) was investigated. The interfacial microstructure and spreading mechanisms were discussed for each sample. All the tested slag samples exhibited good wettability on the SiO2 substrate. The initial apparent contact angles were in the range of 20 to 50 deg, while the final apparent contact angles were 5 deg. The wetting process could be divided into three stages on the basis of the change in diameter, namely the "linear spreading" stage, "spreading rate reduction" stage, and "wetting equilibrium" stage. It was found that the CF-SiO2 wetting system exhibits dissolutive wetting and the dissolution of SiO2 into slag influences its spreading process. The spreading rate increases with a decrease in the ratio of viscosity to interfacial tension, which is a result of the addition of Al2O3, MgO, SiO2, and TiO2. After cooling, a deep corrosion pit was formed in the substrate and a diffusion layer was generated in front of the residual slag zone; further, some SiO2 and Fe2O3 solid solutions precipitated in the slag.

Construction demolition wastes, Waelz slag and MSWI bottom ash: a comparative technical analysis as material for road construction.

PubMed

Vegas, I; Ibañez, J A; San José, J T; Urzelai, A

2008-01-01

The objective of the study is to analyze the technical suitability of using secondary materials from three waste flows (construction and demolition waste (CDW), Waelz slag and municipal solid waste incineration (MSWI) bottom ash), under the regulations and standards governing the use of materials for road construction. A detailed technical characterization of the materials was carried out according to Spanish General Technical Specifications for Road Construction (PG3). The results show that Waelz slag can be adequate for using in granular structural layers, while CDW fits better as granular material in roadbeds. Likewise, fresh MSWI bottom ash can be used as roadbed material as long as it does not contain a high concentration of soluble salts. This paper also discusses the adequacy of using certain traditional test methods for natural soils when characterizing secondary materials for use as aggregates in road construction.

AISI/DOE Technology Roadmap Program: Removal of Residual Elements in The Steel Ladle by a Combination of Top Slag and Deep Injection Practice

DOE Office of Scientific and Technical Information (OSTI.GOV)

S. Street; K.S. Coley; G.A. Iron

2001-08-31

The objective of this work was to determine if tin could be removed from liquid steel by a combination of deep injection of calcium and a reducing top-slag practice. The work was carried out in three stages: injection of Ca wire into 35 Kg heats in an induction furnace under laboratory condition; a fundamental study of the solubility of Sn in the slag as a function of oxygen potential, temperature and slag composition; and, two full-scale plant trials. During the first stage, it was found that 7 to 50% of the Sn was removed from initial Sn contents of 0.1%,more » using 8 to 16 Kg of calcium per tonne of steel. The Sn solubility study suggested that low oxygen potential, high basicity of the slag and lower temperature would aid Sn removal by deep injection of Ca in the bath. However, two full-scale trials at the LMF station in Dofasco's plant showed virtually no Sn removal, mainly because of very low Ca consumption rates used (0.5 to 1.1 Kg/tonne vs. 8 to 16 Kg/tonne used during the induction furnace study in the laboratory). Based on the current price of Ca, addition of 8 to 16 Kg/tonne of steel to remove Sn is too cost prohibitive, and therefore, it is not worthwhile to pursue this process further, even though it may be technically feasible.« less

Thermal treatment and vitrification of boiler ash from a municipal solid waste incinerator.

PubMed

Yang, Y; Xiao, Y; Voncken, J H L; Wilson, N

2008-06-15

Boiler ash generated from municipal solid waste (MSW) incinerators is usually classified as hazardous materials and requires special disposal. In the present study, the boiler ash was characterized for the chemical compositions, morphology and microstructure. The thermal chemical behavior during ash heating was investigated with thermal balance. Vitrification of the ash was conducted at a temperature of 1400 degrees C in order to generate a stable silicate slag, and the formed slag was examined with chemical and mineralogical analyses. The effect of vitrification on the leaching characteristics of various elements in the ash was evaluated with acid leaching. The study shows that the boiler ash as a heterogeneous fine powder contains mainly silicate, carbonate, sulfates, chlorides, and residues of organic materials and heavy metal compounds. At elevated temperatures, the boiler ash goes through the initial moisture removal, volatilization, decomposition, sintering, melting, and slag formation. At 1400 degrees C a thin layer of salt melt and a homogeneous glassy slag was formed. The experimental results indicate that leaching values of the vitrified slag are significantly reduced compared to the original boiler ash, and the vitrification could be an interesting alternative for a safer disposal of the boiler ash. Ash compacting, e.g., pelletizing can reduce volatilization and weight loss by about 50%, and would be a good option for the feed preparation before vitrification.

Effect of Mechanical Activation Treatment on the Recovery of Vanadium from Converter Slag

NASA Astrophysics Data System (ADS)

Xiang, Junyi; Huang, Qingyun; Lv, Xuewei; Bai, Chenguang

2017-10-01

The high roasting temperature and low leaching efficiency of vanadium from vanadium-bearing converter slag are regarded as the main factors significantly influencing the application of calcification roasting-acid leaching processes in the cleaner production of vanadium. In this study, a mechanical activation treatment was performed to enhance the extraction of vanadium from converter slag. The enhancement effects obtained from mechanical activation were comprehensively evaluated through indices such as the roasting temperature and leaching efficiency. The effects of mechanical activation time, roasting temperature, leaching temperature, solid to liquid ratio, particle size, and acid concentration on the leaching efficiency were investigated. Microstructure morphology and elemental analyses of the raw materials and leaching residue were also investigated using scanning electron microscopy and energy-dispersive X-ray spectroscopy. The results demonstrated that the mechanical activation significantly decreased the optimum roasting temperature from 1173 K to 1073 K (900 °C to 800 °C) and increased the leaching efficiency from 86.0 to 90.9 pct.

Selective Sulfidation of Lead Smelter Slag with Pyrite and Flotation Behavior of Synthetic ZnS

NASA Astrophysics Data System (ADS)

Han, Junwei; Liu, Wei; Wang, Dawei; Jiao, Fen; Zhang, Tianfu; Qin, Wenqing

2016-08-01

The selective sulfidation of lead smelter slag with pyrite in the presence of carbon and Na salts, and the flotation behavior of synthetic ZnS were studied. The effects of temperature, time, pyrite dosage, Na salts, and carbon additions were investigated based on thermodynamic calculation, and correspondingly, the growth mechanism of ZnS particles was studied at high temperatures. The results indicated that the zinc in lead smelter slag was selectively converted into zinc sulfides by sulfidation roasting. The sulfidation degree of zinc was increased until the temperature, time, pyrite, and carbon dosages reached their optimum values, under which it was more than 95 pct. The growth of ZnS particles largely depended upon roasting temperature, and the ZnS grains were significantly increased above 1373 K (1100 °C) due to the formation of a liquid phase. After the roasting, the zinc sulfides generated had a good floatability, and 88.34 pct of zinc was recovered by conventional flotation.

Studies to overcome the manufacturing problems in blast furnace tap hole clay of Integrated Steel Plants: Experimental approach

NASA Astrophysics Data System (ADS)

Siva kumar, R.; Mohammed, Raffi; Srinivasa Rao, K.

2018-03-01

Integrated Steel Plants commonly uses Blast Furnace route for iron production which accounts for over 60 % of the world iron output. Blast Furnace runs for ten to twenty years without repairing hearth walls and Tap Hole (TH). Tap hole is an outlet for hot metal produced in a Blast Furnace and run from the shell of the furnace into the interior allowing access to the molten material. Tapping is the term used for drilling a hole through the tap hole which allows the molten iron and slag to flow out. In Iron making process, removal of liquid iron from furnace and sending it for steel making is known as cast house practice. For tapping liquid iron and operating the tap hole requires a special type of clay. Tap hole clay (THC) used to stop the flow of liquid iron and slag from the blast furnace. Present work deals with the study on manufacturing of THC at Visakhapatnam Steel Plant and problems related to manufacturing. Experiments were conducted to solve the identified problems and results are furnished in detail. The findings can improve the manufacturing process and improve the productivity of tap hole clay.

Numerical simulation of submicron particles formation by condensation at coals burning

NASA Astrophysics Data System (ADS)

Kortsenshteyn, N. M.; Petrov, L. V.

2017-11-01

The thermodynamic analysis of the composition of the combustion products of 15 types of coals was carried out with consideration for the formation of potassium and sodium aluminosilicates and solid and liquid slag removal. Based on the results of the analysis, the approximating temperature dependences of the concentrations of condensed components (potassium and sodium sulfates) were obtained for the cases of two-phase and single-phase equilibriums; conclusions on the comparative influence of solid and liquid slag removal on the probability of the formation of submicron particles on the combustion of coals were made. The found dependences was make it possible to perform a numerical simulation of the bulk condensation of potassium and sodium sulfate vapors upon the cooling of coal combustion products in a process flow. The number concentration and size distribution of the formed particles have been determined. Agreement with experimental data on the fraction composition of particles has been reached at a reasonable value of a free parameter of the model.

Method and system for producing metallic iron nuggets

DOEpatents

Iwasaki, Iwao; Kiesel, Richard F.; Englund, David J; Hendrickson, Dave

2012-12-18

A method and system for producing metallic iron nuggets may include providing multiple layers of agglomerates, such as briquettes, balls and extrusions, of a reducible mixture of reducing material (such as carbonaceous material) and of a reducible iron bearing material (such as iron oxide) on a hearth material layer (such as carbonaceous material) and providing a coarse overlayer of carbonaceous material over at least some of the agglomerates. Heating the agglomerates of reducible mixture to 1425.degree. C. or 1400.degree. C. or 1375.degree. C. results in formation of an intermediate product of one or more metallic iron nuggets, which may have a sulfur content of less than 0.03%, and slag, which may have less than 5% mass MgO, which may have a ratio of percent by weight sulfur in the slag over percent by weight sulfur in the metallic nuggets of at least about 12 or at least about 15.

Numerical Simulation of Desulfurization Behavior in Gas-Stirred Systems Based on Computation Fluid Dynamics-Simultaneous Reaction Model (CFD-SRM) Coupled Model

NASA Astrophysics Data System (ADS)

Lou, Wentao; Zhu, Miaoyong

2014-10-01

A computation fluid dynamics-simultaneous reaction model (CFD-SRM) coupled model has been proposed to describe the desulfurization behavior in a gas-stirred ladle. For the desulfurization thermodynamics, different models were investigated to determine sulfide capacity and oxygen activity. For the desulfurization kinetic, the effect of bubbly plume flow, as well as oxygen absorption and oxidation reactions in slag eyes are considered. The thermodynamic and kinetic modification coefficients are proposed to fit the measured data, respectively. Finally, the effects of slag basicity and gas flow rate on the desulfurization efficiency are investigated. The results show that as the interfacial reactions (Al2O3)-(FeO)-(SiO2)-(MnO)-[S]-[O] simultaneous kinetic equilibrium is adopted to determine the oxygen activity, and the Young's model with the modification coefficient R th of 1.5 is adopted to determine slag sulfide capacity, the predicted sulfur distribution ratio LS agrees well with the measured data. With an increase of the gas blowing time, the predicted desulfurization rate gradually decreased, and when the modification parameter R k is 0.8, the predicted sulfur content changing with time in ladle agrees well with the measured data. If the oxygen absorption and oxidation reactions in slag eyes are not considered in this model, then the sulfur removal rate in the ladle would be overestimated, and this trend would become more obvious with an increase of the gas flow rate and decrease of the slag layer height. With the slag basicity increasing, the total desulfurization ratio increases; however, the total desulfurization ratio changes weakly as the slag basicity exceeds 7. With the increase of the gas flow rate, the desulfurization ratio first increases and then decreases. When the gas flow rate is 200 NL/min, the desulfurization ratio reaches a maximum value in an 80-ton gas-stirred ladle.

Low-Chrome/Chrome Free Refractories for Slagging Gasifiers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bennett, J.P.; Kwong, K.-S.; Powell, C.P.

2007-01-01

Gasifiers are containment vessels used to react carbon-containing materials with oxygen and water, producing syngas (CO and H2) that is used in chemical and power production. It is also a potential source of H2 in a future hydrogen economy. Air cooled slagging gasifiers are one type of gasifier, operating at temperatures from 1275-1575º C and at pressures of 400 psi or higher. They typically use coal or petroleum coke as the carbon source, materials which contain ash impurities that liquefy at the gasification temperatures, producing liquid slag in quantities of 100 or more tons/day, depending on the carbon fed ratemore » and the percent ash present in the feedstock. The molten slag is corrosive to refractory linings, causing chemical dissolution and spalling. The refractory lining is composed of chrome oxide, alumina, and zirconia; and is replaced every 3-24 months. Gasifier users would like greater on-line availability and reliability of gasifier liners, something that has impacted gasifier acceptance by industry. Research is underway at NETL to improve refractory service life and to develop a no-chrome or low-chrome oxide alternative refractory liner. Over 250 samples of no- or low-chrome oxide compositions have been evaluated for slag interactions by cup testing; with potential candidates for further studies including those with ZrO2, Al2O3, and MgO materials. The development of improved liner materials is necessary if technologies such as IGCC and DOE’s Near Zero Emissions Advanced Fossil Fuel Power Plant are to be successful and move forward in the marketplace.« less

An Investigation of the Mold-Flux Performance for the Casting of Cr12MoV Steel Using a Mold Simulator Technique

NASA Astrophysics Data System (ADS)

Zhou, Lejun; Wang, Wanlin; Xu, Chao; Zhang, Chen

2017-08-01

Mold flux plays important roles in the process of continuous casting. In this article, the performance of mold flux for the casting of Cr12MoV steel was investigated by using a mold simulator. The results showed that the slag film formed in the gap between the initial shell and mold hot surface is thin and discontinuous during the casting process with the Flux BM, due to the absorption of chromic oxide inclusions into the liquid slag, while the slag film formed in the case of the optimized Flux NEW casting process is uniform. The main precipitated crystals in Flux BM slag film are cuspidine (Ca4Si2O7F2) and Cr3O4, but only Ca4Si2O7F2 precipitated in the Flux NEW case. Besides, both the responding temperature and heat flux in the case of Flux BM are relatively higher and fluctuate in a larger amplitude. The surface of the shell obtained in the case of the Flux BM experiment is quite uneven, and many severe depressions, cracks, and entrapped slags are observed in the surface due to the lack of lubrication. However, the obtained shell surface in the case of the Flux NEW shows good surface quality due to the addition of B2O3 and the adjustment of basicity, which can compensate for the negative effects of the mold-flux properties caused by the absorption of chromic oxide during the casting process.

Experimental Investigation of Gas/Slag/Matte/Tridymite Equilibria in the Cu-Fe-O-S-Si System in Controlled Atmospheres: Development of Technique

NASA Astrophysics Data System (ADS)

Fallah-Mehrjardi, Ata; Hidayat, Taufiq; Hayes, Peter C.; Jak, Evgueni

2017-12-01

The majority of primary pyrometallurgical copper making processes involve the formation of two immiscible liquid phases, i.e., matte product and the slag phase. There are significant gaps and discrepancies in the phase equilibria data of the slag and the matte systems due to issues and difficulties in performing the experiments and phase analysis. The present study aims to develop an improved experimental methodology for accurate characterisation of gas/slag/matte/tridymite equilibria in the Cu-Fe-O-S-Si system under controlled atmospheres. The experiments involve high-temperature equilibration of synthetic mixtures on silica substrates in CO/CO2/SO2/Ar atmospheres, rapid quenching of samples into water, and direct composition measurement of the equilibrium phases using Electron Probe X-ray Microanalysis (EPMA). A four-point-test procedure was applied to ensure the achievement of equilibrium, which included the following: (i) investigation of equilibration as a function of time, (ii) assessment of phase homogeneity, (iii) confirmation of equilibrium by approaching from different starting conditions, and (iv) systematic analysis of the reactions specific to the system. An iterative improved experimental methodology was developed using this four-point-test approach to characterize the complex multi-component, multi-phase equilibria with high accuracy and precision. The present study is a part of a broader overall research program on the characterisation of the multi-component (Cu-Fe-O-S-Si-Al-Ca-Mg), multi-phase (gas/slag/matte/metal/solids) systems with minor elements (Pb, Zn, As, Bi, Sn, Sb, Ag, and Au).

Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stephenson, M.

1994-03-01

Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because ofmore » the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.« less

Exploring the structure of high temperature, iron-bearing liquids

DOE PAGES

Wilding, Martin; Benmore, Chris; Weber, Rick; ...

2015-06-25

This paper describes the direct measurements of the structure of iron-bearing liquids using a combination of containerless techniques and in–situ high energy x-ray diffraction. These capabilities provide data that is important to help model and optimize processes such as smelting, steel making, and controlling slag chemistry. A successful programme of liquid studies has been undertaken and the Advanced Photon Source using these combined techniques which include the provision of gas mixing and the control of pO₂ and the changing influence of mixed valance elements. It is possible to combine rapid image acquisition with quenching of liquids to obtain the fullmore » diffraction patterns of deeply supercooled liquids and the metastable supercooled liquid regime, where the liquid structures and viscosity change most dramatically, can also be explored.« less

Studying the Hydration of a Retarded Suspension of Ground Granulated Blast-Furnace Slag after Reactivation

PubMed Central

Schneider, Nick; Stephan, Dietmar

2016-01-01

This article presents a combined use of a retarder (d-gluconic acid) and an alkaline activator (sodium hydroxide) in a binder system based on ground granulated blast-furnace slag. The properties of the retarder are extending the dormant hydration period and suppressing the generation of strength-giving phases. Different retarder concentrations between 0.25 and 1.00 wt.% regulate the intensity and the period of the retardation and also the characteristics of the strength development. The activator concentration of 30 and 50 wt.% regulates the overcoming of the dormant period and thereby the solution of the slag and hence the formation of the hydration products. The research objective is to produce a mineral binder system based on two separate liquid components. The highest concentration of retarder and activator generates the highest compressive strength and mass of hydration products—after 90 days of hydration a compressive strength of more than 50 N/mm2. The main phases are calcium silicate hydrate and hydrotalcite. Generally, the combination of retarder and activator shows a high potential in the performance increase of the hydration process. PMID:28774054

Dynamic control of remelting processes

DOEpatents

Bertram, Lee A.; Williamson, Rodney L.; Melgaard, David K.; Beaman, Joseph J.; Evans, David G.

2000-01-01

An apparatus and method of controlling a remelting process by providing measured process variable values to a process controller; estimating process variable values using a process model of a remelting process; and outputting estimated process variable values from the process controller. Feedback and feedforward control devices receive the estimated process variable values and adjust inputs to the remelting process. Electrode weight, electrode mass, electrode gap, process current, process voltage, electrode position, electrode temperature, electrode thermal boundary layer thickness, electrode velocity, electrode acceleration, slag temperature, melting efficiency, cooling water temperature, cooling water flow rate, crucible temperature profile, slag skin temperature, and/or drip short events are employed, as are parameters representing physical constraints of electroslag remelting or vacuum arc remelting, as applicable.

Influence of Turbulent Flows in the Nozzle on Melt Flow Within a Slab Mold and Stability of the Metal-Flux Interface

NASA Astrophysics Data System (ADS)

Calderon-Ramos, Ismael; Morales, R. D.

2016-06-01

The design of the ports of a casting nozzle has profound effects on the fluid flow patterns in slab molds. The influence of these outlets have also considerable effects on the turbulent flow and turbulence variables inside the nozzle itself. To understand the effects of nozzle design, three approaches were employed: a theoretical analysis based on the turbulent viscosity hypothesis, dimensional analysis (both analyses aided by computer fluid dynamics), and experiments using particle image velocimetry. The first approach yields a linear relation between calculated magnitudes of scalar fields of ɛ (dissipation rate of kinetic energy) and k 2 (square of the turbulent kinetic energy), which is derived from the wall and the logarithmic-wall laws in the boundary layers. The smaller the slope of this linear relation is, the better the performance of a given nozzle is for maintaining the stability of the melt-flux interface. The second approach yields also a linear relation between flow rate of liquid metal and the cubic root of the dissipation rate of kinetic energy. In this case, the larger the slope of the linear relation is, the better the performance of a given nozzle is for maintaining the stability of the melt-flux interface. Finally, PIV measurements in a mold water model, together with equations for estimation of critical melt velocities for slag entrainment, were used to quantify the effects of nozzle design on the dynamics of the metal-slag interface. The three approaches agree in the characterization of turbulent flows in continuous casting molds using different nozzles.

Quantitative and Qualitative Aspects of Gas-Metal-Oxide Mass Transfer in High-Temperature Confocal Scanning Laser Microscopy

NASA Astrophysics Data System (ADS)

Piva, Stephano P. T.; Pistorius, P. Chris; Webler, Bryan A.

2018-05-01

During high-temperature confocal scanning laser microscopy (HT-CSLM) of liquid steel samples, thermal Marangoni flow and rapid mass transfer between the sample and its surroundings occur due to the relatively small sample size (diameter around 5 mm) and large temperature gradients. The resulting evaporation and steel-slag reactions tend to change the chemical composition in the metal. Such mass transfer effects can change observed nonmetallic inclusions. This work quantifies oxide-metal-gas mass transfer of solutes during HT-CSLM experiments using computational simulations and experimental data for (1) dissolution of MgO inclusions in the presence and absence of slag and (2) Ca, Mg-silicate inclusion changes upon exposure of a Si-Mn-killed steel to an oxidizing gas atmosphere.

Modeling Manganese Silicate Inclusion Composition Changes during Ladle Treatment Using FactSage Macros

NASA Astrophysics Data System (ADS)

Piva, Stephano P. T.; Kumar, Deepoo; Pistorius, P. Chris

2017-02-01

This work investigated the use of FactSage macros to simulate steel-slag and steel-inclusion reaction kinetics in silicon-manganese killed steels, and predict oxide inclusion composition changes during ladle treatment. These changes were assessed experimentally using an induction furnace to simulate deoxidation and slag addition. The average steel mass transfer coefficient for the experimental setup was calculated from the analyzed aluminum pick-up by steel. Average oxide inclusion composition was measured using scanning electron microscopy and energy-dispersive X-ray spectroscopy. Confocal laser scanning microscopy was used to assess the physical state (solid or liquid) of oxide inclusions in selected samples. The changes in the chemical compositions of the oxide inclusions and the steel agreed with the FactSage macro simulations.

Fundamentals of several reactions for the carbothermic reduction of alumina

NASA Astrophysics Data System (ADS)

Walker, Matthew S.

The current process used for primary aluminum production, the Hall-Heroult process, is reliable, but it also is expensive, consumes large amounts of energy, and generates significant quantities of greenhouse gas emissions. One possible alternative process is the carbothermic reduction of alumina, wherein aluminum is formed by reducing alumina with carbon at high temperatures. This process, if successful, has the potential for substantial reductions in energy consumption, capital costs, and greenhouse gas emissions. One critical component to making this process successful involves obtaining a better understanding of the thermodynamics. Specifically, the key thermodynamic data are the free energies of the reactions and the thermodynamic activities of the metal (Al-C) and slag systems (Al2O3-Al4C3). These are critical for evaluating and controlling the carbothermic process, but experimental data is extremely limited and much of it was measured many years ago when the experimental techniques available may not have been adequate. The overall objective for this research was to assess the validity of the thermodynamic data for this process, as well as its suitability for predicting the behavior of the process. This was done through experimental investigations into both the slag (carbide) making reaction and the binary Al2O 3-Al4C3 phase diagram. The comparison of these results, to those expected based on the current understanding for the process thermodynamics (using FactSage along with the ALCO database), assesses the validity of the thermodynamic data. In this document, the experimental results for investigating the reactions of Al2O3 with carbon are presented. This work involved measuring the operating line for the first step of the carbothermic aluminum process, slag making. This was done using two experimental methods. One involved measuring the evolution of CO from the reactions using a mass spectrometer. The other involved using a vacuum thermobalance (TGA) to measure the weight loss from the reactions. Additionally, two separate reactors were used for the CO evolution measurements. One was carefully designed to minimize the concentration of nitrogen, from air, near the reactants (Reactor B). The other allowed for a significant concentration of nitrogen (Reactor A). The use of these two reactors allowed the influence of nitrogen on this slag making operating line to be determined. Also, experiments were performed making measurements for the binary Al2O3-Al4C3 phase diagram. These included measuring the Al2O3-Al 4O4C eutectic as well as the Al2O3 liquidus line. In general the measured operating line is close to the predicted line, with the exception being at Al2O3 saturation, where there a significant difference. The measured slag making operating line appears to support the predicted values (temperature and slag composition) through both the single phase liquid and at Al4C3 saturation. The data also supports the temperature for the operating line at Al2 O3 saturation (1948°C), but the slag composition here is measured to be much lower than predicted (5.2 mole % Al4C 3 vs. 7.6 mole % Al4C3). No clear explanation is provided for these lower than expected carbon concentration. The effect of nitrogen on this slag making operating line is minimal. No discernible difference was observed through both the single phase liquid and at Al4C3 saturation. At Al2O3 saturation, the temperatures were found to be the same, while the composition of the slag was found to be slightly less concentrated with carbon when nitrogen was present. The eutectic point for the Al2O3-Al4C 3 phase diagram was measured in two separate ways, slag solidification during cooling and slag melting during heating. Both revealed the same temperature (1885-1886°C), which is lower than the predicted value (1908°C). The measured eutectic compositions were slightly different (9.24 mole % Al 4C3 and 10.7 mole % Al4C3), but neither was significantly different than the predicted value (10.1 mole % Al 4C3). These measurements, along with the slag compositions at Al2O3 saturation from the operating line measurements appear to support the idea of a steeper alumina liquidus line. This has implications for the Al2O3-Al4C3 system and thermodynamic models that appear to be unrealistic. (Abstract shortened by UMI.)

Thermal behaviour of ESP ash from municipal solid waste incinerators.

PubMed

Yang, Y; Xiao, Y; Wilson, N; Voncken, J H L

2009-07-15

Stricter environmental regulations demand safer treatment and disposal of incinerator fly ashes. So far no sound technology or a process is available for a sustainable and ecological treatment of the waste incineration ashes, and only partial treatment is practised for temporary and short-term solutions. New processes and technology need to be developed for comprehensive utilization and detoxification of the municipal solid waste (MSW) incinerator residues. To explore the efficiency of thermal stabilisation and controlled vitrification, the thermal behaviour of electrostatic precipitator (ESP) ash was investigated under controlled conditions. The reaction stages are identified with the initial moisture removal, volatilization, melting and slag formation. At the temperature higher than 1100 degrees C, the ESP ashes have a quicker weight loss, and the total weight loss reaches up to 52%, higher than the boiler ash. At 1400 degrees C a salt layer and a homogeneous glassy slag were formed. The effect of thermal treatment on the leaching characteristics of various elements in the ESP ash was evaluated with the availability-leaching test. The leaching values of the vitrified slag are significantly lowered than that of the original ash.

Formation Mechanism of Oxide-Sulfide Complex Inclusions in High-Sulfur-Containing Steel Melts

NASA Astrophysics Data System (ADS)

Shin, Jae Hong; Park, Joo Hyun

2018-02-01

The [S] content in resulfurized steel is controlled in the range of 200 to 800 ppm to ensure good machinability and workability. It is well known that "MgAl2O4(spinel)+CaS" complex inclusions are formed in molten steel during the ladle refining process, and these cause nozzle clogging during continuous casting. Thus, in the present study, the "Refractory-Slag-Metal-Inclusions (ReSMI)" multiphase reaction model was employed in conjunction with experiments to investigate the influence of slag composition and [S] content in the steel on the formation of oxide-sulfide complex inclusions. The critical [S] and [Al] contents necessary for the precipitation of CaS in the CaO-Al2O3-MgO-SiO2 (CAMS) oxide inclusions were predicted from the composition of the liquid inclusions, as observed by scanning electron microscopy-electron dispersive spectrometry (SEM-EDS) and calculated using the ReSMI multiphase reaction model. The critical [S] content increases with increasing content of SiO2 in the slag at a given [Al] content. Formation mechanisms for spinel+CaS and spinel+MnS complex inclusions were also proposed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, S.H.; Song, B.

The reoxidation behavior of steels by slag in the secondary steelmaking process was addressed by investigating the thermodynamic equilibria between the liquid iron containing Mn and P and CaO-MgO-SiO{sub 2}-Al{sub 2}O{sub 3}-P{sub 2}O{sub 5}-MnO-Fe{sub t}O ladle slag at 1873 K. The activity coefficient of Fe{sub t}O shows a maximum value in the vicinity of the basicity ((X{sub CaO} + X{sub MgO} + X{sub MnO})/(X{sub SiO{sub 2}} + X{sub Al{sub 2}O{sub 3}} + XP{sub 2}O{sub 5})) = 2.5 at the specific mole fraction range of Fe{sub t}O, while that of MnO seems to increase gradually with increasing the basicity. However, themore » values of {gamma}{sub Fe{sub t}O} and {gamma}{sub MnO} showed minima with respect to P{sub 2}O{sub 5} content of slag. In addition, the values of {gamma}{sub Fe{sub t}O} and {gamma}{sub MnO} increased as (pct CaO)/(pct Al{sub 2}O{sub 3}) ratio increased at given SiO{sub 2}, MgO, and P{sub 2}O{sub 5} contents. The conversion equations between the Fe{sub t}O and MnO activities and their calculated activities via regular solution model were derived by the correlation between the measured and calculated activities over the limited ranges of Fe{sub t}O and MnO contents. The regular solution model was used to estimate the oxygen potential in the slag. For MgO saturated slags, a{sub Fe{sub t}O{sub (l)}} = 0.864a{sub FeO{sub (R.S.)}}, a{sub MnO{sub (l)}} = 6.38a{sub MnO{sub (R.S.)}}. For Al{sub 2}O{sub 3} saturated slags, a{sub Fe{sub t}O{sub (l)}} = 2.086a{sub FeO{sub (R.S.)}}, a{sub MnO{sub (l)}} = 14.39a{sub MnO{sub (R.S.)}}.« less

Renewable Energy Testing Center for US Army Contract W15QKN-05-D-0030 Task 5 RETC, WBS #4.6.0

DTIC Science & Technology

2010-02-01

system to produce syngas and a glass or glassy- ceramic matrix, depending on the feedstock. Figure 1.2-2 The PEAT System Installed at the RETC The...miscellaneous gases that can be processed to provide electricity or liquid fuel. All inorganic materials are converted into a glass slag . Generated syngas

Methods and apparatus for reducing corrosion in refractory linings

DOEpatents

Poeppel, Roger B.; Greenberg, Sherman; Diercks, Dwight R.

1987-01-01

Methods and apparatus are provided for reducing corrosion in a refractory lining of a liquid-containing vessel used in direct steelmaking processes. The vessel operates at between about 1600.degree. C. and about 1800.degree. C. and an oxygen partial pressure of about 10.sup.-12 atmospheres, creating slag which is rich in FeO. The refractory lining includes a significant level of chromium oxide (Cr.sub.2 O.sub.3), and has small interconnected pores which may be filled with a gas mixture having a higher total pressure and oxygen partial pressure than the total pressure and oxygen partial pressure associted with the liquid against the lining of the vessel. The gas mixture is forced through the pores of the lining so that the pores are continuously filled with the mixture. In this manner, the gas mixture creates a blanket which increases the oxygen partial pressure at the lining enough to maintain the chromium in the lining in a selected valence state in which the chromium has decreased solubility in the FeO slag, thereby reducing corrosion by the FeO and increasing the useful life of the refractory lining.

Comparative study of antimicrobial efficiency of metallurgical slags suitable for construction applications

NASA Astrophysics Data System (ADS)

Strigac, J.; Stevulova, N.; Mikusinec, J.; Varecka, L.; Hudecova, D.

2017-10-01

The article deals with comparative study of antimicrobial efficiency of metallurgical slags suitable for construction applications. The tested slags were as follows: granulated blast-furnace slag (GS1), air cooled blast-furnace slag (AS2), demetallized steel slag (DS3), calcerous ladle slag (LS4), slag from copper refining (CS5). The antimicrobial activity was tested on selected representatives of bacteria, yeasts, and filamentous fungi. The highest antibacterial activity possessed LS4, which intensely inhibited growth of bacteria with the lowest concentration of slag (10%) in the growth media. 100% inhibition of growth of some bacteria was observed only in slags LS4, DS3 and AS2 in concentrations 20% - 60% of slag. Antibacterial activity of slag samples was decreasing in the order: LS4 > DS3 > AS2 > GS1 > CS5. Growth of all model yeasts was 100% inhibited at as low concentration as 20% of slag GS1 and DS3, and 10% of slag LS4. Antiyeast activity of slags was decreasing in the order: LS4 > GS1 = DS3 > AS2 > CS5. Regarding that filamentous fungi were selectively sensitive to presence of slags, it is possible to determine only approximate order of inhibition effectiveness of slags to fungi: LS4 > GS1 = DS3 > AS2 = CS5.

Investigation of Heat Transfer and Magnetohydrodynamic Flow in Electroslag Remelting Furnace Using Vibrating Electrode

NASA Astrophysics Data System (ADS)

Wang, Fang; Wang, Qiang; Lou, Yanchun; Chen, Rui; Song, Zhaowei; Li, Baokuan

2016-01-01

A transient three-dimensional (3D) coupled mathematical model has been developed to understand the effect of a vibrating electrode on the electromagnetic, two-phase flow and temperature fields as well as the solidification in the electroslag remelting (ESR) process. With the magnetohydrodynamic model, the Joule heating and Lorentz force, which are the source terms in the energy and momentum equations, are recalculated at each iteration as a function of the phase distribution. The influence of the vibrating electrode on the formation of the metal droplet is demonstrated by the volume of fluid approach. Additionally, the solidification of the metal is modeled by an enthalpy-based technique, in which the mushy zone is treated as a porous medium with porosity equal to the liquid fraction. The present work is the first attempt to investigate the innovative technology of the ESR process with a vibrating electrode by a transient 3D comprehensive model. A reasonable agreement between the experiment and simulation is obtained. The results indicate that the whole process is presented as a periodic activity. When the metal droplets fall from the tip of the electrode, the horizontal component of velocity will generate electrode vibration. This will lead to the distribution variation of the flow field in the slag layer. The variation of temperature distribution occurs regularly and is periodically accompanied by the behavior of the falling metal droplets. With the decreasing vibrating frequency and amplitude, the relative velocity of the electrode and molten slag increase accordingly. The diameter of the molten droplets, the maximum temperature and the depth of the molten pool gradually become smaller, lower and shallower.

An overview of recovery of metals from slags.

PubMed

Shen, Huiting; Forssberg, E

2003-01-01

Various slags are produced as by-products in metallurgical processes or as residues in incineration processes. According to the origins and the characteristics, the main slags can be classified into three categories, namely ferrous slag, non-ferrous slag and incineration slag. This paper analysed and summarised the generation, characteristics and application of various slags, and discussed the potential effects of the slags on the environment. On this basis, a review of a number of methods for recovery of metals from the slags was made. It can be seen that a large amount of slags is produced each year. They usually contain a quantity of valuable metals except for blast furnace slag and they are actually a secondary resource of metals. By applying mineral processing technologies, such as crushing, grinding, magnetic separation, eddy current separation, flotation and so on, leaching or roasting, it is possible to recover metals such as Fe, Cr, Cu, Al, Pb, Zn, Co, Ni, Nb, Ta, Au, and Ag etc. from the slags. Recovery of metals from the slags and utilisation of the slags are important not only for saving metal resources, but also for protecting the environment.

Development and field testing of an alternative latrine design utilizing basic oxygen furnace slag as a treatment media for pathogen removal

NASA Astrophysics Data System (ADS)

Stimson, J.; Suhogusoff, A. V.; Blowes, D. W.; Hirata, R. A.; Ptacek, C. J.; Robertson, W. D.; Emelko, M. B.

2009-05-01

In densely-populated communities in developing countries, appropriate setback distances for pit latrines often cannot be met. An alternative latrine was designed that incorporates two permeable reactive media to treat pathogens and nitrate from effluent. Basic oxygen furnace (BOF) slag in contact with wastewater effluent elevates pH to levels (> 11) that inactivate pathogens. Saturated woodchip creates reducing conditions that encourage the growth of denitrifying bacteria which remove NO3-. The field application was constructed in Santo Antônio, a peri-urban community located 25 km south of the city of São Paulo, Brazil. A 2-m diameter pit was excavated to a depth of 4 m into the sandy-clay unsaturated zone. A geotextile liner was emplaced to create saturated conditions in the 0.5-m thick woodchip barrier. Above the woodchip barrier, a 1-m thick layer of BOF slag mixed with pea gravel and sand was emplaced. A series of filter layers, grading upward from coarse sand to fine gravel, where placed above the BOF layer, and gravel was also infilled around the outer perimeter of the excavation, to ensure O2 diffusion into the design, the formation of biofilm, and degradation of organic material. A control latrine, constructed with similar hydraulic characteristics and nonreactive materials, was constructed at a locality 100 m away, in the same geological materials. Total coliform, thermotolerant coliform, and E. coli are removed by approximately 4-5 log concentration units in less than one meter of vertical transport through the BOF slag media. In the control latrine, comparable reductions in these pathogenic indicators are observed over three meters of vertical transport. Removal of sulphur-reducing Clostridia, Clostridium perfrigens and somatic coliphage are also achieved in the alternative design, but initial concentrations in effluent are low. Some measurable concentrations of pathogen indicators are measured in lysimeters below the BOF layer, but are associated with low-TDS, neutral water that is infiltrating in from the sidewall of the excavation. Oxygen concentration is augmented (5 mg L-1) in the alternative latrine compared to the control design (1-2 mg L-1), suggesting that conditions for biofilm development are improved. The decline in pH between sampling events after 42 and 82 days of wastewater application suggest that the potential for base release is decreased over time. Somatic coliphage concentrations are 1-2 log concentration units lower in stainless steel lysimeters compared to concentrations measured in adjacent pan lysimeters, suggesting that the filtration of coliphage by the porous cup may negatively bias sampling.

Effect of sodium monofluorophosphate treatment on microstructure and frost salt scaling durability of slag cement paste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Copuroglu, O.; Fraaij, A.L.A.; Bijen, J.M.J.M.

2006-08-15

Sodium-monofluorophosphate (Na-MFP) is currently in use as a surface applied corrosion inhibitor in the concrete industry. Its basic mechanism is to protect the passive layer of the reinforcement steel against disruption due to carbonation. Carbonation is known as the most detrimental environmental effect on blast furnace slag cement (BFSC) concrete with respect to frost salt scaling. In this paper the effect of Na-MFP on the microstructure and frost salt scaling resistance of carbonated BFSC paste is presented. The results of electron microscopy, mercury intrusion porosimetry (MIP) and X-ray diffraction (XRD) are discussed. It is found that the treatment modifies themore » microstructure and improves the resistance of carbonated BFSC paste against frost salt attack.« less

Method for reducing iron losses in an iron smelting process

DOEpatents

Sarma, B.; Downing, K.B.

1999-03-23

A process of smelting iron that comprises the steps of: (a) introducing a source of iron oxide, oxygen, nitrogen, and a source of carbonaceous fuel to a smelting reactor, at least some of said oxygen being continuously introduced through an overhead lance; (b) maintaining conditions in said reactor to cause (1) at least some of the iron oxide to be chemically reduced, (2) a bath of molten iron to be created and stirred in the bottom of the reactor, surmounted by a layer of slag, and (3) carbon monoxide gas to rise through the slag; (c) causing at least some of said carbon monoxide to react in the reactor with the incoming oxygen, thereby generating heat for reactions taking place in the reactor; and (d) releasing from the reactor an offgas effluent, is run in a way that keeps iron losses in the offgas relatively low. After start-up of the process is complete, steps (a) and (b) are controlled so as to: (1) keep the temperature of the molten iron at or below about 1550 C and (2) keep the slag weight at or above about 0.8 ton per square meter. 13 figs.

Method for reducing iron losses in an iron smelting process

DOEpatents

Sarma, Balu; Downing, Kenneth B.

1999-01-01

A process of smelting iron that comprises the steps of: a) introducing a source of iron oxide, oxygen, nitrogen, and a source of carbonaceous fuel to a smelting reactor, at least some of said oxygen being continuously introduced through an overhead lance; b) maintaining conditions in said reactor to cause (i) at least some of the iron oxide to be chemically reduced, (ii) a bath of molten iron to be created and stirred in the bottom of the reactor, surmounted by a layer of slag, and (iii) carbon monoxide gas to rise through the slag; c) causing at least some of said carbon monoxide to react in the reactor with the incoming oxygen, thereby generating heat for reactions taking place in the reactor; and d) releasing from the reactor an offgas effluent, is run in a way that keeps iron losses in the offgas relatively low. After start-up of the process is complete, steps (a) and (b) are controlled so as to: e) keep the temperature of the molten iron at or below about 1550.degree. C. and f) keep the slag weight at or above about 0.8 tonne per square meter.

Progress on Protection of Titanium-Bearing Materials in Chinese Blast Furnace

NASA Astrophysics Data System (ADS)

Cai, Qiuye; Zhang, Jianliang; Jiao, Kexin; Wang, Cui

Prolonging the campaign life of the blast furnace has been an important task for iron makers, and it has been studied for decades. Adding titanium-bearing materials is a generally agreed and effective technique to protect the blast furnace hearth. Titanium from titania additions in the burden or tuyere injection react with carbon and nitrogen and form scaffolds on the hearth surface to protect the hearth from subsequent erosion. In this article, the progress on blast furnace hearth protection of titania additions in Chinese steel companies and research institutions is investigated, and the difficulties in the operation and production, such as little effect after adding titanium- bearing materials and the property deterioration of liquid iron and slags, are analyzed. The future research for protection in Chinese blast furnace is proposed, and a comprehensive process which combines protection of titanium bearing materials with reasonable thermal balance and slag- making regimes should be established.

Determination of germanium by AAS in chloride-containing matrices.

PubMed

Anwari, M A; Abbasi, H U; Volkan, M; Ataman, O Y

1996-06-01

Interference effects of NaCl on the ET-AAS determination of Ge have been studied. The use of several matrix modifiers to alleviate this problem such as Ni and Zn perchlorates and nitrates, nitric acid, ammonium nitrate are reported. The stabilizing effect of Zn and Ni perchlorates allows the use of high pretreatment temperatures. NaCl is thus thermally volatilized from the atomizer by employing pretreatment temperatures higher than 1500 degrees C resulting in an improved sensitivity. Germanium levels in zinc plant slag samples, have been determined and compared to those obtained for the same samples spiked with NaCl with platform and wall atomization using nickel perchlorate as a matrix modifier. The results were compared with those from a hydride generation system equipped with a liquid nitrogen trap. The recoveries for germanium have been almost complete and amount to 99% for the original slag samples and 80% for 15% (w/w) NaCl containing spiked samples.

Water-cooled probe technique for the study of freeze lining formation

NASA Astrophysics Data System (ADS)

Verscheure, Karel; Campforts, Mieke; Verhaeghe, Frederik; Boydens, Eddy; Blanpain, Bart; Wollants, Patrick; van Camp, Maurits

2006-12-01

Furnace protection by water-cooled freeze linings becomes increasingly important as the metal producing industry attempts to achieve higher process intensities. Systematic investigations of the growth and the resulting microstructure and compositional profile of freeze linings are necessary to understand the behavior of freeze linings, their relation with the industrial process, and their interaction with the wall cooling system. We have developed a technique based on the submergence of a water-cooled probe into a liquid slag bath. Freeze linings of two industrial nonferrous slags have been produced using this technique and their growth, microstructural, and compositional profiles as a function of submergence time were determined. Thermodynamic equilibrium for the investigated slag systems was calculated and compared with the observed microstructures. The freeze linings form in approximately 15 minutes. Close to the water cooling, the freeze linings are predominantly amorphous in structure. With increasing distance from the water cooling, the proportion of crystalline phases increases and bath material is entrapped in the microstructure. Cellular crystals are observed close to the bath. The freeze linings exhibit an approximate homogeneous composition. The results demonstrate that the technique is a successful tool in obtaining information on the growth, microstructure, and composition of freeze linings in industrial water-cooled furnaces.

Analysis of the Optimum Usage of Slag for the Compressive Strength of Concrete.

PubMed

Lee, Han-Seung; Wang, Xiao-Yong; Zhang, Li-Na; Koh, Kyung-Taek

2015-03-18

Ground granulated blast furnace slag is widely used as a mineral admixture to replace partial Portland cement in the concrete industry. As the amount of slag increases, the late-age compressive strength of concrete mixtures increases. However, after an optimum point, any further increase in slag does not improve the late-age compressive strength. This optimum replacement ratio of slag is a crucial factor for its efficient use in the concrete industry. This paper proposes a numerical procedure to analyze the optimum usage of slag for the compressive strength of concrete. This numerical procedure starts with a blended hydration model that simulates cement hydration, slag reaction, and interactions between cement hydration and slag reaction. The amount of calcium silicate hydrate (CSH) is calculated considering the contributions from cement hydration and slag reaction. Then, by using the CSH contents, the compressive strength of the slag-blended concrete is evaluated. Finally, based on the parameter analysis of the compressive strength development of concrete with different slag inclusions, the optimum usage of slag in concrete mixtures is determined to be approximately 40% of the total binder content. The proposed model is verified through experimental results of the compressive strength of slag-blended concrete with different water-to-binder ratios and different slag inclusions.

Analysis of the Optimum Usage of Slag for the Compressive Strength of Concrete

PubMed Central

Lee, Han-Seung; Wang, Xiao-Yong; Zhang, Li-Na; Koh, Kyung-Taek

2015-01-01

Ground granulated blast furnace slag is widely used as a mineral admixture to replace partial Portland cement in the concrete industry. As the amount of slag increases, the late-age compressive strength of concrete mixtures increases. However, after an optimum point, any further increase in slag does not improve the late-age compressive strength. This optimum replacement ratio of slag is a crucial factor for its efficient use in the concrete industry. This paper proposes a numerical procedure to analyze the optimum usage of slag for the compressive strength of concrete. This numerical procedure starts with a blended hydration model that simulates cement hydration, slag reaction, and interactions between cement hydration and slag reaction. The amount of calcium silicate hydrate (CSH) is calculated considering the contributions from cement hydration and slag reaction. Then, by using the CSH contents, the compressive strength of the slag-blended concrete is evaluated. Finally, based on the parameter analysis of the compressive strength development of concrete with different slag inclusions, the optimum usage of slag in concrete mixtures is determined to be approximately 40% of the total binder content. The proposed model is verified through experimental results of the compressive strength of slag-blended concrete with different water-to-binder ratios and different slag inclusions. PMID:28787998

Carbothermic reduction behaviors of Ti-Nb-bearing Fe concentrate from Bayan Obo ore in China

NASA Astrophysics Data System (ADS)

Wang, Guang; Du, Ya-xing; Wang, Jing-song; Xue, Qing-guo

2018-01-01

To support the development of technology to utilize low-grade Ti-Nb-bearing Fe concentrate, the reduction of the concentrate by coal was systematically investigated in the present paper. A liquid phase formed when the Ti-Nb-bearing Fe concentrate/coal composite pellet was reduced at temperatures greater than 1100°C. The addition of CaCO3 improved the reduction rate when the slag basicity was less than 1.0 and inhibited the formation of the liquid phase. Mechanical milling obviously increased the metallization degree compared with that of the standard pellet when reduced under the same conditions. Evolution of the mineral phase composition and microstructure of the reduced Ti-Nb-bearing Fe concentrate/coal composite pellet at 1100°C were analyzed by X-ray diffraction and scanning electron microscopy-energy-dispersive spectroscopy. The volume shrinkage value of the reduced Ti-Nb-bearing Fe concentrate/coal composite pellet with a basicity of 1.0 was approximately 35.2% when the pellet was reduced at 1100°C for 20 min, which enhanced the external heat transfer to the lower layers when reduced in a practical rotary hearth furnace. The present work provides key parameters and mechanism understanding for the development of carbothermic reduction technology of a Ti-Nb-bearing Fe concentrate incorporated in a pyrometallurgical utilization flow sheet.

Changes in mineralogical and leaching properties of converter steel slag resulting from accelerated carbonation at low CO{sub 2} pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zomeren, Andre van; Laan, Sieger R. van der; Kobesen, Hans B.A.

2011-11-15

Highlights: > Accelerated carbonation studied to improve environmental properties of steel slag. > Carbonation found to occur predominantly at surface of the steel slag grains. > Combined geochemical modelling and mineral analysis revealed controlling processes. > Enhanced V-leaching with di-Ca silicate (C2S) dissolution identified as major source. > Identified mineral transformations provide guidance for further quality improvement. - Abstract: Steel slag can be applied as substitute for natural aggregates in construction applications. The material imposes a high pH (typically 12.5) and low redox potential (Eh), which may lead to environmental problems in specific application scenarios. The aim of this studymore » is to investigate the potential of accelerated steel slag carbonation, at relatively low pCO{sub 2} pressure (0.2 bar), to improve the environmental pH and the leaching properties of steel slag, with specific focus on the leaching of vanadium. Carbonation experiments are performed in laboratory columns with steel slag under water-saturated and -unsaturated conditions and temperatures between 5 and 90 {sup o}C. Two types of steel slag are tested; free lime containing (K3) slag and K1 slag with a very low free lime content. The fresh and carbonated slag samples are investigated using a combination of leaching experiments, geochemical modelling of leaching mechanisms and microscopic/mineralogical analysis, in order to identify the major processes that control the slag pH and resulting V leaching. The major changes in the amount of sequestered CO{sub 2} and the resulting pH reduction occurred within 24 h, the free lime containing slag (K3-slag) being more prone to carbonation than the slag with lower free lime content (K1-slag). While carbonation at these conditions was found to occur predominantly at the surface of the slag grains, the formation of cracks was observed in carbonated K3 slag, suggesting that free lime in the interior of slag grains had also reacted. The pH of the K3 slag (originally pH {+-} 12.5) was reduced by about 1.5 units, while the K1 slag showed a smaller decrease in pH from about 11.7 to 11.1. However, the pH reduction after carbonation of the K3 slag was observed to lead to an increased V-leaching. Vanadium leaching from the K1 slag resulted in levels above the limit values of the Dutch Soil Quality Decree, for both the untreated and carbonated slag. V-leaching from the carbonated K3 slag remained below these limit values at the relatively high pH that remained after carbonation. The V-bearing di-Ca silicate (C2S) phase has been identified as the major source of the V-leaching. It is shown that the dissolution of this mineral is limited in fresh steel slag, but strongly enhanced by carbonation, which causes the observed enhanced release of V from the K3 slag. The obtained insights in the mineral transformation reactions and their effect on pH and V-leaching provide guidance for further improvement of an accelerated carbonation technology.« less

Comparative studies on acid leaching of zinc waste materials

NASA Astrophysics Data System (ADS)

Rudnik, Ewa; Włoch, Grzegorz; Szatan, Leszek

2017-11-01

Three industrial waste materials were characterized in terms of their elemental and phase compositions, leaching behaviour in 10% sulfuric acid solution as well as leaching thermal effects. Slag from melting of mixed metallic scrap contained about 50% Zn and 10% Pb. It consisted mainly of various oxides and oxy-chlorides of metals. Zinc spray metallizing dust contained about 77% Zn in form of zinc and/or zinc-iron oxides, zinc metal and Zn-Fe intermetallic. Zinc ash from hot dip galvanizing was a mixture of zinc oxide, metallic zinc and zinc hydroxide chloride and contained about 80% Zn. Dissolution efficiency of zinc from the first material was 80% (independently on the solid to liquid ratio, 50-150 kg/m3), while decrease of the efficacy from 80% to 60% with increased solid to liquid ratio for the two remaining materials was observed. Both increase in the temperature (20 °C to 35 °C) and agitation rate (300 rpm to 900 rpm) did not improve seriously the leaching results. In all cases, transfer of zinc ions to the leachate was accompanied by different levels of solution contamination, depending on the type of the waste. Leaching of the materials was exothermic with the similar reaction heats for two high oxide-type products (slag, zinc ash) and higher values for the spray metallizing dust.

CO2 sequestration by mineral carbonation of steel slags under ambient temperature: parameters influence, and optimization.

PubMed

Ghacham, Alia Ben; Pasquier, Louis-César; Cecchi, Emmanuelle; Blais, Jean-François; Mercier, Guy

2016-09-01

This work focuses on the influence of different parameters on the efficiency of steel slag carbonation in slurry phase under ambient temperature. In the first part, a response surface methodology was used to identify the effect and the interactions of the gas pressure, liquid/solid (L/S) ratio, gas/liquid ratio (G/L), and reaction time on the CO2 removed/sample and to optimize the parameters. In the second part, the parameters' effect on the dissolution of CO2 and its conversion into carbonates were studied more in detail. The results show that the pressure and the G/L ratio have a positive effect on both the dissolution and the conversion of CO2. These results have been correlated with the higher CO2 mass introduced in the reactor. On the other hand, an important effect of the L/S ratio on the overall CO2 removal and more specifically on the carbonate precipitation has been identified. The best results were obtained L/S ratios of 4:1 and 10:1 with respectively 0.046 and 0.052 gCO2 carbonated/g sample. These yields were achieved after 10 min reaction, at ambient temperature, and 10.68 bar of total gas pressure following direct gas treatment.

A Parametric Study of Slag Skin Formation in Electroslag Remelting

NASA Astrophysics Data System (ADS)

Yanke, Jeff; Krane, Matthew John M.

In electroslag remelting (ESR), the slag generates heat, chemically refines the melting electrode material, and forms frozen skin on the mold. An axisymmetric model is used to simulate fluid flow, heat transfer, solidification, and electromagnetics and their interaction with slag skin formation in ESR. A volume of fluid (VOF) method is used to track the slag/metal interface, allowing simulation of slag freezing to the mold. Mold diameter and applied current are varied to determine how these parameters affect melt rate and formation of slag skin during ESR. Variations in the slag skin thickness within the slag cap are found to have a significant impact on melt rate and depth of metal sump. Changes in slag cap volume resulted in small changes in melt rate.

Changes in mineralogical and leaching properties of converter steel slag resulting from accelerated carbonation at low CO2 pressure.

PubMed

van Zomeren, André; van der Laan, Sieger R; Kobesen, Hans B A; Huijgen, Wouter J J; Comans, Rob N J

2011-11-01

Steel slag can be applied as substitute for natural aggregates in construction applications. The material imposes a high pH (typically 12.5) and low redox potential (Eh), which may lead to environmental problems in specific application scenarios. The aim of this study is to investigate the potential of accelerated steel slag carbonation, at relatively low pCO2 pressure (0.2 bar), to improve the environmental pH and the leaching properties of steel slag, with specific focus on the leaching of vanadium. Carbonation experiments are performed in laboratory columns with steel slag under water-saturated and -unsaturated conditions and temperatures between 5 and 90 °C. Two types of steel slag are tested; free lime containing (K3) slag and K1 slag with a very low free lime content. The fresh and carbonated slag samples are investigated using a combination of leaching experiments, geochemical modelling of leaching mechanisms and microscopic/mineralogical analysis, in order to identify the major processes that control the slag pH and resulting V leaching. The major changes in the amount of sequestered CO2 and the resulting pH reduction occurred within 24h, the free lime containing slag (K3-slag) being more prone to carbonation than the slag with lower free lime content (K1-slag). While carbonation at these conditions was found to occur predominantly at the surface of the slag grains, the formation of cracks was observed in carbonated K3 slag, suggesting that free lime in the interior of slag grains had also reacted. The pH of the K3 slag (originally pH±12.5) was reduced by about 1.5 units, while the K1 slag showed a smaller decrease in pH from about 11.7 to 11.1. However, the pH reduction after carbonation of the K3 slag was observed to lead to an increased V-leaching. Vanadium leaching from the K1 slag resulted in levels above the limit values of the Dutch Soil Quality Decree, for both the untreated and carbonated slag. V-leaching from the carbonated K3 slag remained below these limit values at the relatively high pH that remained after carbonation. The V-bearing di-Ca silicate (C2S) phase has been identified as the major source of the V-leaching. It is shown that the dissolution of this mineral is limited in fresh steel slag, but strongly enhanced by carbonation, which causes the observed enhanced release of V from the K3 slag. The obtained insights in the mineral transformation reactions and their effect on pH and V-leaching provide guidance for further improvement of an accelerated carbonation technology. Copyright © 2011 Elsevier Ltd. All rights reserved.

Application of PCA and SIMCA statistical analysis of FT-IR spectra for the classification and identification of different slag types with environmental origin.

PubMed

Stumpe, B; Engel, T; Steinweg, B; Marschner, B

2012-04-03

In the past, different slag materials were often used for landscaping and construction purposes or simply dumped. Nowadays German environmental laws strictly control the use of slags, but there is still a remaining part of 35% which is uncontrolled dumped in landfills. Since some slags have high heavy metal contents and different slag types have typical chemical and physical properties that will influence the risk potential and other characteristics of the deposits, an identification of the slag types is needed. We developed a FT-IR-based statistical method to identify different slags classes. Slags samples were collected at different sites throughout various cities within the industrial Ruhr area. Then, spectra of 35 samples from four different slags classes, ladle furnace (LF), blast furnace (BF), oxygen furnace steel (OF), and zinc furnace slags (ZF), were determined in the mid-infrared region (4000-400 cm(-1)). The spectra data sets were subject to statistical classification methods for the separation of separate spectral data of different slag classes. Principal component analysis (PCA) models for each slag class were developed and further used for soft independent modeling of class analogy (SIMCA). Precise classification of slag samples into four different slag classes were achieved using two different SIMCA models stepwise. At first, SIMCA 1 was used for classification of ZF as well as OF slags over the total spectral range. If no correct classification was found, then the spectrum was analyzed with SIMCA 2 at reduced wavenumbers for the classification of LF as well as BF spectra. As a result, we provide a time- and cost-efficient method based on FT-IR spectroscopy for processing and identifying large numbers of environmental slag samples.

Size-dependent enrichment of waste slag aggregate fragments abraded from asphalt concrete.

PubMed

Takahashi, Fumitake; Shimaoka, Takayuki; Gardner, Kevin; Kida, Akiko

2011-10-30

Authors consider the environmental prospects of using melted waste slag as the aggregate for asphalt pavement. In particular, the enrichment of slag-derived fragments in fine abrasion dust particles originated from slag asphalt concrete and its size dependency were concerned. A series of surface abrasion tests for asphalt concrete specimens, containing only natural aggregates as reference or 30 wt% of substituted slag aggregates, were performed. Although two of three slag-asphalt concretes generated 1.5-3.0 times larger amount of abrasion dust than the reference asphalt concrete did, it could not be explained only by abrasion resistance of slag. The enrichment of slag-derived fragments in abrasion dust, estimated on the basis of the peak intensity of quartz and heavy metal concentrations, had size dependency for all slag-asphalt concretes. Slag-derived fragments were enriched in abrasion dust particles with diameters of 150-1000 μm. Enrichment factors were 1.4-2.1. In contrast, there was no enrichment in abrasion dust particles with diameter less than 75 μm. This suggests that prior airborne-size fragmentation of substituted slag aggregates does not need to be considered for tested slag aggregates when environmental risks of abrasion dust of slag-asphalt pavement are assessed. Copyright © 2011 Elsevier B.V. All rights reserved.

The opportunity of silicate product manufacturing with simultaneous pig iron reduction from slag technogenic formations

NASA Astrophysics Data System (ADS)

Sheshukov, O. Yu.; Lobanov, D. A.; Mikheenkov, M. A.; Nekrasov, I. V.; Egiazaryan, D. K.

2017-09-01

There are two main kinds of slag in modern steelmaking industry: the electric arc furnace slag (EAF slag) and ladle furnace slag (LF slag). The all known slag processing schemes provide the iron-containing component reduction while silicate component stays unprocessed. On the contrary, the silicate processing schemes doesn't provide the utilization of the iron-containing component. The present-day situation doesn't solve the problem of total slag utilization. The aim of this work is to investigate the opportunity of silicate product obtaining with simultaneous pig iron reduction from EAF and LF slags. The tests are conducted by the method of simplex-lattice design. The test samples are heated and melted under reductive conditions, slowly cooled and then analyzed by XRD methods. The experiment results prove the opportunity: the Portland clinker and pig iron can be simultaneously produced on the basis of these slags with a limestone addition.

An Analysis of the Orbital Distribution of Solid Rocket Motor Slag

NASA Technical Reports Server (NTRS)

Horstman, Matthew F.; Mulrooney, Mark

2007-01-01

The contribution made by orbiting solid rocket motors (SRMs) to the orbital debris environment is both potentially significant and insufficiently studied. A combination of rocket motor design and the mechanisms of the combustion process can lead to the emission of sufficiently large and numerous by-products to warrant assessment of their contribution to the orbital debris environment. These particles are formed during SRM tail-off, or the termination of burn, by the rapid expansion, dissemination, and solidification of the molten Al2O3 slag pool accumulated during the main burn phase of SRMs utilizing immersion-type nozzles. Though the usage of SRMs is low compared to the usage of liquid fueled motors, the propensity of SRMs to generate particles in the 100 m and larger size regime has caused concern regarding their contributing to the debris environment. Particle sizes as large as 1 cm have been witnessed in ground tests conducted under vacuum conditions and comparable sizes have been estimated via ground-based telescopic and in-situ observations of sub-orbital SRM tail-off events. Using sub-orbital and post recovery observations, a simplistic number-size-velocity distribution of slag from on-orbit SRM firings was postulated. In this paper we have developed more elaborate distributions and emission scenarios and modeled the resultant orbital population and its time evolution by incorporating a historical database of SRM launches, propellant masses, and likely location and time of particulate deposition. From this analysis a more comprehensive understanding has been obtained of the role of SRM ejecta in the orbital debris environment, indicating that SRM slag is a significant component of the current and future population.

Mineral precipitation and dissolution at two slag-disposal sites in northwestern Indiana, USA

USGS Publications Warehouse

Bayless, E.R.; Schulz, M.S.

2003-01-01

Slag is a ubiquitous byproduct of the iron- and steel-refining industries. In northwestern Indiana and northeastern Illinois, slag has been deposited over more than 52 km2 of land surface. Despite the widespread use of slag for fill and construction purposes, little is known about its chemical effects on the environment. Two slagdisposal sites were examined in northwestern Indiana where slag was deposited over the native glacial deposits. At a third site, where slag was not present, background conditions were defined. Samples were collected from cores and drill cuttings and described with scanning electron microscopy and electron microprobe analysis. Ground-water samples were collected and used to assess thermodynamic equilibria between authigenic minerals and existing conditions. Differences in the mineralogy at background and slag-affected sites were apparent. Calcite, dolomite, gypsum, iron oxides, and clay minerals were abundant in native sediments immediately beneath the slag. Mineral features indicated that these minerals precipitated rapidly from slag drainage and co-precipitated minor amounts of non-calcium metals and trace elements. Quartz fragments immediately beneath the slag showed extensive pitting that was not apparent in sediments from the background site, indicating chemical weathering by the hyperalkaline slag drainage. The environmental impacts of slag-related mineral precipitation include disruption of natural ground-water flow patterns and bed-sediment armoring in adjacent surface-water systems. Dissolution of native quartz by the hyperalkaline drainage may cause instability in structures situated over slag fill or in roadways comprised of slag aggregates.

Refractory Degradation by Slag Attack in Coal Gasification

DTIC Science & Technology

2009-02-01

REFRACTORY DEGRADATION BY SLAG ATTACK IN COAL GASIFICATION Jinichiro Nakano 1,2 , Sridhar Seetharaman 1,2 , James Bennett 3 , Kyei-Sing...and two synthetic slags (coal and petcoke). Pulverized slag samples were placed at specific microstructure locations on refractory substrates and...heated to 1500 ºC at log(Po2) = -9, using a high-speed heating chamber. Cross-sections of the slag /refractory interface indicated unique slag

Environmental characteristics and utilization potential of metallurgical slag: Chapter 19

USGS Publications Warehouse

Piatak, Nadine; De Vivo, Benedetto; Belkin, Harvey E.; Lima, Annamaria

2018-01-01

Slag, an abundant byproduct from the pyrometallurgical processing of ores, can be an environmental liability or a valuable resource. The most common environmental impact of slag is from the leaching of potentially toxic elements, acidity, or alkalinity that may impact nearby soils and surface water and groundwater. Factors that influence its environmental behavior include physical characteristics, such as grain size and porosity, chemical composition with some slag being enriched in certain elements, the mineralogy and partitioning of elements in more or less reactive phases, water-slag interactions, and site conditions. Many of these same factors also influence its resource potential. For example, crystalline ferrous slag is most commonly used as construction aggregate, whereas glassy (i.e., granulated) slag is used in cement. Also, the calcium minerals found in ferrous slag result in useful applications in water treatment. In contrast, the high trace-element content of some base-metal slags makes the slags economically attractive for extraction of residual elements. An evaluation tool is used to help categorize a particular slag as an environmental hazard or valuable byproduct. Results for one type of slag, legacy steelmaking slag from the Chicago area in the USA, suggest the material has potential to be used for treating phosphate-rich or acidic waters; however, the pH and trace-element content of resulting solutions may warrant further examination.

Immobilization of Cr (VI) in stainless steel slag and Cd, As, and Pb in wastewater using blast furnace slag via a hydrothermal treatment

NASA Astrophysics Data System (ADS)

Tae, Soon-Jae; Morita, Kazuki

2017-05-01

The immobilization of hexavalent chromium in stainless steel slag using blast furnace slag as the immobilizing agent and by performing a hydrothermal treatment was investigated. The results showed that there was no immobilization in the absence of the blast furnace slag. On the other hand, the hexavalent chromium in stainless steel slag could be immobilized through the hydrothermal reaction when blast furnace slag was used at 250 °C for 24 h. A leaching test was performed to evaluate the degree of immobilization of hexavalent chromium in the products formed by the hydrothermal reaction. It was found that the degree of immobilization was very high. Based on the results obtained, the immobilization mechanism of hexavalent chromium in stainless steel slag, resulting from the hydrothermal treatment of blast furnace slag, could be elucidated. Finally, the immobilization of cadmium, lead, and arsenic using blast furnace slag as the immobilization agent was also studied while focusing on the effects of the hydrothermal treatment.

Coal/Biomass-to-Liquids Demonstration Testing for DLA Energy: Report on Project Tests, Evaluations, and Recommendations

DTIC Science & Technology

2015-08-20

elevated temperatures with sub- stoichiometric oxygen to produce primarily hydrogen and carbon monoxide (called syngas). Syngas can be used for the...of the gasifier and flows downward concurrently with nitrogen, pure oxygen , and steam. The EFG operates at very high temperatures (nominal 2,700... temperature slagging gasifiers), these components are cracked and thermally converted to product gas, especially in the presence of steam and oxygen . For

Skid resistance performance of asphalt wearing courses with electric arc furnace slag aggregates.

PubMed

Kehagia, Fotini

2009-05-01

Metallurgical slags are by-products of the iron and steel industry and are subdivided into blast furnace slag and steel slag according to the different steel-producing processes. In Greece, slags are mostly produced from steelmaking using the electric arc furnace process, and subsequently are either disposed in a random way or utilized by the cement industry. Steel slag has been recently used, worldwide, as hard aggregates in wearing courses in order to improve the skidding resistance of asphalt pavements. At the Highway Laboratory, Department of Civil Engineering of Aristotle University of Thessaloniki research has been carried out in the field of steel slags, and especially in electric arc furnace (EAF) slag, to evaluate their possible use in highway engineering. In this paper, the recent results of anti-skidding performance of steel slag aggregates in highway pavements are presented.

Materials technology for coal-conversion processes. Seventeenth quarterly report, January-March 1979

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ellingson, W. A.

1979-01-01

Studies of slag attack on refractories were continued, utilizing conditions relevant to MHD applications. Addition of 10 wt % K/sub 2/O seed to the slag did not increase its corrosive effect on the refractories tested. A hot gas-stream cleanup erosion-monitoring system using an ANL-developed nondestructive ultrasonic system was installed at the Morgantown Energy Technology Center (METC) during this period and was 75% completed. Characteristic-slope values obtained from broadband and resonant-band acoustic-emission transducers during rapid heating of a 95% Al/sub 2/O/sub 3/ refractory panel are consistent with theory. Corrosion information on type and thickness of corrosion-product layers was obtained on Incoloymore » 800, 310 stainless steel, Inconel 671 and 871 and 982/sup 0/C. Fluid-bed corrosion studies involving sulfation accelerators have shown that addition of 0.3 mol % CaCl/sub 2/ has no significant effect on corrosion behavior of the alloys studied. However, 0.5 mol % NaCl or 1.9 mol % Na/sub 2/CO/sub 3/ increases the corrosion rates of most materials. Failure analyses were performed on components from the slagging gasifier and liquefaction unit at the Grand Forks Energy Technology Center, and a ball valve from the METC Valve Dynamic Test Unit.« less

Blind Inlet as a Possible Technology for the Remediation of Phosphorus from Surface Runoff

NASA Astrophysics Data System (ADS)

Sturmlechner, M.; Wu, X.; Livingston, S.; Klik, A.; Huang, C. H.

2015-12-01

Phosphorus (P) is an essential element for plant life, but too much P in runoff water can cause eutrophication and harmful algal blooms. Hence, mitigation of agricultural P losses into the water cycle is a very important issue. In-stream P treatment is difficult to implement because the large amount of storm runoff needs to be treated in short durations. In this research, we evaluated the potential to use blind inlet as an in-field P treatment technology. A box system was built to simulate hydrological and chemical processes occurring in a blind inlet. Current blind inlets, which are already installed in the field, use a bed of limestone with a sand/pea gravel layer on the top. In this study, steel slags has been tested, which has a very high P sorption potential, as the filter media through a series of adsorption and desorption experiments. The P mass balance results are compared with the limestone material used in current blind inlet construction. The total mass of P which was absorbed by the limestone was 14 % of the P input into the system whereas 26 % P was absorbed by the steel slags. Therefore the steel slags show potential to sequester dissolved P. Additional research is on-going to come up with a design criteria for field implementation.

Corrosion Behavior of Carbon Steel in Concrete Material Composed of Tin Slag Waste in Aqueous Chloride Solution

NASA Astrophysics Data System (ADS)

Rustandi, Andi; Cahyadi, Agung; Taruli Siallagan, Sonia; Wafa' Nawawi, Fuad; Pratesa, Yudha

2018-01-01

Tin slag is a byproduct of tin ore smelting process which is rarely utilized. The main purpose of this work is to investigate the use of tin slag for concrete cement material application compared to the industrial Ordinary Portland Cement (OPC). Tin slag composition was characterized by XRD and XRF analysis. The characterization results showed the similar chemical composition of tin slag and OPC. It also revealed the semi crystalline structure of tin slag sample. Several electrochemical tests were performed to evaluate corrosion behavior of tin slag, OPC and various mixed composition of both materials and the addition of CaO. The corrosion behavior of OPC and tin slag were evaluated by using Cyclic Polarization, Electrochemical Impedance Spectroscopy (EIS) and Electrochemical Frequency Modulation (EFM) methods. Aqueous sodium chloride (NaCl) solution with 3.5% w.t concentration which similar to seawater was used as the electrolyte in this work. The steel specimen used as the reinforce bar (rebar) material of the concrete was carbon steel AISI 1045. The rebar was embedded in the concrete cement which composed of OPC and the various composition of tin slag including slag without addition of CaO and slag mixed with addition of 50 % CaO. The electrochemical tests results revealed that tin slag affected its corrosion behavior which becoming more active and increasing the corrosion rate as well as decreasing the electrochemical impedance.

The Effect of TiO2 on the Liquidus Zone and Apparent Viscosity of SiO2-CaO-8wt.%MgO-14wt.%Al2O3 System

NASA Astrophysics Data System (ADS)

Yan, Zhiming; Lv, Xuewei; Zhang, Jie; Xu, Jian

TiO2 has been approved as a viscosity-decreasing agent in blast furnace slag under inert atmosphere both by experimental and structure calculation. However, the validity of the above conclusion in a much bigger zone in CaO-SiO2-Al2O3-MgO phase diagram has not approved. The viscosity of slag dependent on the TiO2 content and basicity were measured in the present work. It was found that the viscosity and viscous activation energy decrease with increasing TiO2 content and basicity at a reasonable range, indicating TiO2 behaved as a viscosity-decreasing agent by depolymerizing the silicate network structure when its less than 50wt. %. The liquidity of the slag can be improved when TiO2 content less than 50wt. % and basicity from 0.5 to 1.1. The free running temperature increase at TiO2 content from 10wt.% to 30wt. %. The results of calculation does not agree well with the experimental values at a high basicity of 1.3 with TiO2 content from 20wt.% to 30wt.% and the lower basicity of 0.5 with TiO2 content more than 50wt.%.

Laboratory simulation of the rocket motor thrust as a follower force

NASA Technical Reports Server (NTRS)

1990-01-01

Ground tests of solid propellant rocket motors have shown that metal-containing propellants produce various amounts of slag (primarily aluminum oxide), which is trapped in the motor case causing a loss of specific impulse. Although not yet definitely established, the presence of a liquid pool of slag also may contribute to nutational instabilities that have been observed with certain spin-stabilized, upper-stage vehicles. Because of the rocket's axial acceleration - absent in the ground tests - estimates of in-flight slag mass have been very uncertain. Yet such estimates are needed to determine the magnitude of the control authority of the systems required for eliminating the instability. A test rig with an eccentrically mounted hemispherical bowl was designed and built that incorporates a follower force that properly aligns the thrust vector along the axis of spin. A program that computes the motion of a point mass in the spinning and precessing bowl was written. Using various rpm, friction factors, and initial starting conditions, plots were generated showing the trace of the point mass around the inside of the fuel tank. The apparatus will be used extensively during the 1990 to 1991 academic year and incorporate future design features such as a variable nutation angle and a film height measuring instrument. Data obtained on the nutational instability characteristics will be used to determine order-of-magnitude estimates of control authority needed to minimize the sloshing effect.

Laboratory Simulation of the Effect of Rocket Thrust on a Precessing Space Vehicle

NASA Technical Reports Server (NTRS)

Alvarez, Oscar; Bausley, Henry; Cohen, Sam; Falcon-Martin, Miguel; Furumoto, Gary (Editor); Horio, Asikin; Levitt, David; Walsh, Amy

1990-01-01

Ground tests of solid propellant rocket motors have shown that metal-containing propellants produce various amounts of slag (primarily aluminum oxide) which is trapped in the motor case, causing a loss of specific impulse. Although not yet definitely established, the presence of a liquid pool of slag also may contribute to nutational instabilities that have been observed with certain spin-stabilized, upper-stage vehicles. Because of the rocket's axial acceleration, absent in the ground tests, estimates of in-flight slag mass have been very uncertain. Yet such estimates are needed to determine the magnitude of the control authority of the systems required for eliminating the instability. A test rig with an eccentrically mounted hemispherical bowl was designed and built which incorporates a follower force that properly aligns the thrust vector along the axis of spin. A program that computes the motion of a point mass in the spinning and precessing bowl was written. Using various RPMs, friction factors, and initial starting conditions, plots were generated showing the trace of the point mass around the inside of the fuel tank. The apparatus will incorporate future design features such as a variable nutation angle and a film height measuring instrument. Data obtained on the nutational instability characteristics will be used to determine order of magnitude estimates of control authority needed to minimize the sloshing effect.

Process for electroslag refining of uranium and uranium alloys

DOEpatents

Lewis, P.S. Jr.; Agee, W.A.; Bullock, J.S. IV; Condon, J.B.

1975-07-22

A process is described for electroslag refining of uranium and uranium alloys wherein molten uranium and uranium alloys are melted in a molten layer of a fluoride slag containing up to about 8 weight percent calcium metal. The calcium metal reduces oxides in the uranium and uranium alloys to provide them with an oxygen content of less than 100 parts per million. (auth)

Method and system for producing metallic iron nuggets

DOEpatents

Iwasaki, Iwao; Lindgren, Andrew J.; Kiesel, Richard F.

2013-06-25

Method and system for producing metallic nuggets includes providing reducible mixture of reducing material (such as carbonaceous material) and reducible iron bearing material (such as iron oxide) that may be arranged in discrete portions, such as mounds or briquettes, on at least a portion of a hearth material layer (such as carbonaceous material). A coarse overlayer of carbonaceous material may be provided over at least some of the discrete portions. Heating the reducible mixture to 1425.degree. C. or 1400.degree. C. or 1375.degree. C. results in formation of an intermediate product of one or more metallic iron nuggets, which may have a sulfur content of less than 0.03%, and slag, which may have less than 5% mass MgO, which may have a ratio of percent by weight sulfur in the slag over percent by weight sulfur in the metallic nuggets of at least about 12 or at least about 15.

Study on the Effect of Straw Fiber on the Performance of Volcanic Slag Concrete

NASA Astrophysics Data System (ADS)

Xiao, Li-guang; Liu, Xi-xu

2018-03-01

In this paper, the effects of straw fiber on the working performance, mechanical properties and frost resistance of volcanic slag lightweight aggregate concrete were studied. The experimental results show that the straw fiber is subjected to surface carbonization treatment and mixed into the volcanic slag light aggregate concrete. The flexural strength and fracture pressure ratio of volcanic slag lightweight aggregate concrete are improved obviously Improved volcanic slag lightweight aggregate concrete brittleness improves toughness. Carbonized straw fiber greatly improves the frost resistance of volcanic slag lightweight aggregate concrete. So that the volcanic slag light aggregate concrete freeze-thaw cycle can reach 300 times.

Slag of Greek provenance uses in materials science and geophysics: implications for a highly potential material in the service of the development of Greek economy

NASA Astrophysics Data System (ADS)

Leontakianakos, G.; Baziotis, I.; Sotiriadis, K.; Goulas, G.; Liakopoulos, S.; Karastathis, V.

2012-04-01

Ground granulated blast-furnace slag (GGBS) is a secondary raw material that can be used as an alternative low energy binder. Hydraulic properties can be occurred through its alkali activation. GGBS is characterized by the glassy to crystalline ratio and by its chemical and mineralogical composition. Acidic slag cannot easily get crystallized in oppose to the basic one. Crystalline phases show very low reactivity with Ca(OH)2, while amorphous phases can easily react in the presence of basic substances. The aim of the present study was to study the evolution of new advanced silicate materials presenting high durability at high temperature environments. Specimens were produced using two types of slag of Greek origin. The first type was a ferrous slag, while the second one was calcareous. Their maximum particle size was 4 mm and 0.07 mm respectively. Specimens were prepared using the above slag types and siliceous sand as an aggregate. Sand was divided according to European Standard EN 196-1 in three fractions: PG1 (1

Thermodynamic Simulation of Viscosity of TiO2-Ti2O3-CaO Ternary Slag

NASA Astrophysics Data System (ADS)

Zhang, P.; Ma, W. H.; Zhang, S. J.; Lei, Y.; Wen, J. H.

2017-12-01

The viscosity of high titanium slag at high temperature is one of the key factors of slag-iron separation. Based on the Einstein-Roscoe equation, thermodynamic simulation of viscosity of TiO2-Ti2O3-CaO ternary slag is studied by using FactSage® software, and the effects of temperature, CaO content and solid-phase particles on the viscosity of slag were studied. The results show that the increase of CaO content has the effect of reducing melting temperature and viscosity of TiO2-Ti2O3-CaO ternary slag. After the TiO2-Ti2O3-CaO ternary slag is completely melted, the increase of temperature has little effect on viscosity of slag, and the viscosity is about 110~125mPa·s. When the temperature is lower than melting temperature, TiO2-Ti2O3-CaO ternary slag will precipitate solid-phase particles, and the precipitation process is carried out in stages, and with the decrease of temperature, the precipitation will increase and the viscosity will sharply increase. TiO2-Ti2O3-CaO ternary titanium slag has obvious characteristics of short slag.

The characteristics of steel slag and the effect of its application as a soil additive on the removal of nitrate from aqueous solution.

PubMed

Liyun, Yang; Ping, Xu; Maomao, Yang; Hao, Bai

2017-02-01

This study examined the characteristics of nitrate removal from aqueous solution by steel slag and the feasibility of using steel slag as a soil additive to remove nitrate. Steel slag adsorbents were characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD), scanning electron microscopy (SEM) and infrared spectrum (IR spectrum). Adsorption isotherms and kinetics were also analysed. Various parameters were measured in a series of batch experiments, including the sorbent dose, grain size of steel slag, reaction time, initial concentration of nitrate nitrogen, relationship between Al, Fe and Si ions leached from the steel slag and residual nitrate in the aqueous solution. The nitrate adsorbing capacity increased with increasing amounts of steel slag. In addition, decreasing the grain diameter of steel slag also enhanced the adsorption efficiency. Nitrate removal from the aqueous solution was primarily related to Al, Fe, Si and Mn leached from the steel slag. The experimental data conformed to second-order kinetics and the Freundlich isothermal adsorption equation, indicating that the adsorption of nitrate by steel slag is chemisorption under the action of monolayer adsorption. Finally, it was determined that using steel slag as a soil additive to remove nitrate is a feasible strategy.

Characteristics and environmental aspects of slag: a review

USGS Publications Warehouse

Piatak, Nadine M.; Parsons, Michael B.; Seal, Robert R.

2015-01-01

The composition of ferrous slag is dominated by Ca and Si. Steel slag may contain significant Fe, whereas Mg and Al may be significant in Fe slag. Calcium-rich olivine-group silicates, melilite-group silicates that contain Al or Mg, Ca-rich glass, and oxides are the most commonly reported major phases in ferrous slag. Calcite and trace amounts of a variety of sulfides, intermetallic compounds, and pure metals are typically also present. The composition of non-ferrous slag, most commonly from base-metal production, is dominated by Fe and Si with significant but lesser amounts of Al and Ca. Silicates in the olivine, pyroxene, and melilite groups, as well as glass, spinels, and SiO2 (i.e., quartz and other polymorphs) are commonly found in non-ferrous slag. Sulfides and intermetallic compounds are less abundant than the silicates and oxides. The concentrations of some elements exceed generic USEPA soil screening levels for human contact based on multiple exposure pathways; these elements include Al, Cr, Cu, Fe, Mn, Pb, and Zn based on bulk chemical composition. Each slag type usually contains a specific suite of elements that may be of environmental concern. In general, non-ferrous slag may have a higher potential to negatively impact the environment compared to ferrous slag, and is thus a less attractive material for reuse, based on trace element chemistry, principally for base metals. However, the amount of elements released into the environment is not always consistent with bulk chemical composition. Many types of leaching tests have been used to help predict slag’s long-term environmental behavior. Overall, ferrous slags produce an alkaline leachate due to the dissolution of Ca oxides and silicates derived from compounds originally added as fluxing agents, such as lime. Ferrous slag leachate is commonly less metal-rich than leachate from non-ferrous slag generated during base metal extraction; the latter leachate may even be acidic due to the oxidation of sulfides. Because of its characteristics, ferrous slag is commonly used for construction and environmental applications, whereas both non-ferrous and ferrous slag may be reprocessed for secondary metal recovery. Both types of slag have been a source of some environmental contamination. Research into the environmental aspects of slag will continue to be an important topic whether the goal is its reuse, recycling, or remediation.

Laboratory Study on Prevention of CaO-Containing ASTM "D-Type" Inclusions in Al-Deoxidized Low-Oxygen Steel Melts During Basic Slag Refining

NASA Astrophysics Data System (ADS)

Jiang, Min; Wang, Xin-Hua; Yang, Die; Lei, Shao-Long; Wang, Kun-Peng

2015-12-01

Present work was attempted to explore the possibility of preventing CaO-containing inclusions in Al-deoxidized low-oxygen special steel during basic slag refining, which were known as ASTM D-type inclusions. Based on the analysis on formation thermodynamics of CaO-containing inclusions, a series of laboratory experiments were designed and carried out in a vacuum induction furnace. During the experiments, slag/steel reaction equilibrium was intentionally suppressed with the aim to decrease the CaO contents in inclusions, which is different from ordinary concept that slag/steel reaction should be promoted for better control of inclusions. The obtained results showed that high cleanliness of steel was obtained in all the steel melts, with total oxygen contents varied between 0.0003 and 0.0010 pct. Simultaneously, formation of CaO-containing inclusions was successfully prohibited, and all the formed oxide inclusions were MgO-Al2O3 or/and Al2O3 in very small sizes of about 1 to 3 μm. And 90 pct to nearly 98 pct of them were wrapped by relative thicker MnS outer surface layers to produce dual-phased "(MgO-Al2O3) + MnS" or "Al2O3 + MnS" complex inclusions. Because of much better ductility of MnS, certain deformability of these complex inclusions can be expected which is helpful to improve fatigue resistance property of steel. Only very limited number of singular MnS inclusions were with sizes larger than 13 μm, which were formed during solidification because of. In the end, formation of oxide inclusions in steel was qualitatively evaluated and discussed.

Use of barium-strontium carbonatite for flux welding and surfacing of mining machines

NASA Astrophysics Data System (ADS)

Kryukov, R. E.; Kozyrev, N. A.; Usoltsev, A. A.

2017-09-01

The results of application of barium-strontium carbonatite for modifying and refining iron-carbon alloys, used for welding and surfacing in ore mining and smelting industry, are generalized. The technology of manufacturing a flux additive containing 70 % of barium-strontium carbonatite and 30 % of liquid glass is proposed. Several compositions of welding fluxes based on silicomanganese slag were tested. The flux additive was introduced in an amount of 1, 3, 5 %. Technological features of welding with the application of the examined fluxes are determined. X-ray spectral analysis of the chemical composition of examined fluxes, slag crusts and weld metal was carried out, as well as metallographic investigations of welded joints. The principal possibility of applying barium-strontium carbonatite as a refining and gas-protective additive for welding fluxes is shown. The use of barium-strontium carbonatite reduces the contamination of the weld seam with nonmetallic inclusions: non-deforming silicates, spot oxides and brittle silicates, and increases the desulfurizing capacity of welding fluxes.

Integrated Experimental and Modelling Research for Non-Ferrous Smelting and Recycling Systems

NASA Astrophysics Data System (ADS)

Jak, Evgueni; Hidayat, Taufiq; Shishin, Denis; Mehrjardi, Ata Fallah; Chen, Jiang; Decterov, Sergei; Hayes, Peter

The chemistries of industrial pyrometallurgical non-ferrous smelting and recycling processes are becoming increasingly complex. Optimisation of process conditions, charge composition, temperature, oxygen partial pressure, and partitioning of minor elements between phases and different process streams require accurate description of phase equilibria and thermodynamics which are the focus of the present research. The experiments involve high temperature equilibration in controlled gas atmospheres, rapid quenching and direct measurement of equilibrium phase compositions with quantitative microanalytical techniques including electron probe X-ray microanalysis and Laser Ablation ICP-MS. The thermodynamic modelling is undertaken using computer package FactSage with the quasi-chemical model for the liquid slag phase and other advanced models. Experimental and modelling studies are combined into an integrated research program focused on the major elements Cu-Pb-Fe-O-Si-S system, slagging Al, Ca, Mg and other minor elements. The ongoing development of the research methodologies has resulted in significant advances in research capabilities. Examples of applications are given.

Multiphase Flow Modeling of Slag Entrainment During Ladle Change-Over Operation

NASA Astrophysics Data System (ADS)

Morales, Rodolfo D.; Garcia-Hernandez, Saul; Barreto, Jose de Jesus; Ceballos-Huerta, Ariana; Calderon-Ramos, Ismael; Gutierrez, Enif

2016-08-01

Steel transfer from the ladle to a single-strand tundish using a conventional ladle shroud (CLS), and a dissipative ladle shroud (DLS) is studied during the transient period of ladle change-over operation. Fluid velocities and fluid flow turbulence statistics during this unsteady operation were recorded by an ultrasound velocimetry probe in a 1/3 scale water-oil-air analog model (to emulate steel-slag-air system). Reynolds stress model and volume of fluid model allow the tracking of water-oil, water-air, and oil-air interfaces during this operation. Velocity measurements indicate a very high turbulence with the formation of a water-air bubbles-oil emulsion. Flow turbulence and the intensity of the emulsification decrease considerably due to an efficient dissipation of the turbulent kinetic energy employing the DLS instead of the CLS. The modeling results indicate that DLS is widely recommended to substitute flow control devices to improve the fluid dynamics of liquid steel during this transient operation.

Experimental investigation of basic oxygen furnace slag used as aggregate in asphalt mixture.

PubMed

Xue, Yongjie; Wu, Shaopeng; Hou, Haobo; Zha, Jin

2006-11-16

Chinese researchers have commenced a great deal of researches on the development of application fields of basic oxygen steel making furnace slag (BOF slag) for many years. Lots of new applications and properties have been found, but few of them in asphalt mixture of road construction engineering. This paper discussed the feasibility of BOF steel slag used as aggregate in asphalt pavement by two points of view including BOF steel slag's physical and micro-properties as well as steel slag asphalt materials and pavement performances. For the former part, this paper mainly concerned the mechanochemistry and physical changes of the steel slag and studied it by performing XRD, SEM, TG and mercury porosimeter analysis and testing method. In the second part, this paper intended to use BOF steel slag as raw material, and design steel slag SMA mixture. By using traditional rutting test, soak wheel track and modified Lottman test, the high temperature stability and water resistance ability were tested. Single axes compression test and indirect tensile test were performed to evaluate the low temperature crack resistance performance and fatigue characteristic. Simultaneously, by observing steel slag SMA pavement which was paved successfully. A follow-up study to evaluate the performance of the experimental pavement confirmed that the experimental pavement was comparable with conventional asphalt pavement, even superior to the later in some aspects. All of above test results and analysis had only one main purpose that this paper validated the opinion that using BOF slag in asphalt concrete is feasible. So this paper suggested that treated and tested steel slag should be used in a more extensive range, especially in asphalt mixture paving projects in such an abundant steel slag resource region.

Bacterial community structure and diversity responses to the direct revegetation of an artisanal zinc smelting slag after 5 years.

PubMed

Luo, Youfa; Wu, Yonggui; Wang, Hu; Xing, Rongrong; Zheng, Zhilin; Qiu, Jing; Yang, Lian

2018-05-01

This comparative field study examined the responses of bacterial community structure and diversity to the revegetation of zinc (Zn) smelting waste slag with eight plant species after 5 years. The microbial community structure of waste slag with and without vegetation was evaluated using high-throughput sequencing. The physiochemical properties of Zn smelting slag after revegetation with eight plant rhizospheres for 5 years were improved compared to those of bulk slag. Revegetation significantly increased the microbial community diversity in plant rhizospheres, and at the phylum level, Proteobacteria, Acidobacteria, and Bacteroidetes were notably more abundant in rhizosphere slags than those in bulk waste slag. Additionally, revegetation increased the relative abundance of plant growth-promoting rhizobacteria such as Flavobacterium, Streptomyces, and Arthrobacter as well as symbiotic N 2 fixers such as Bradyrhizobium. Three dominant native plant species (Arundo donax, Broussonetia papyrifera, and Robinia pseudoacacia) greatly increased the quality of the rhizosphere slags. Canonical correspondence analysis showed that the differences in bacterial community structure between the bulk and rhizosphere slags were explained by slag properties, i.e., pH, available copper (Cu) and lead (Pb), moisture, available nitrogen (N), phosphorus (P), and potassium (K), and organic matter (OM); however, available Zn and cadmium (Cd) contents were the slag parameters that best explained the differences between the rhizosphere communities of the eight plant species. The results suggested that revegetation plays an important role in enhancing bacterial community abundance and diversity in rhizosphere slags and that revegetation may also regulate microbiological properties and diversity mainly through changes in heavy metal bioavailability and physiochemical slag characteristics.

Control of pyrite addition in coal liquefaction process

DOEpatents

Schmid, Bruce K.; Junkin, James E.

1982-12-21

Pyrite addition to a coal liquefaction process (22, 26) is controlled (118) in inverse proportion to the calcium content of the feed coal to maximize the C.sub.5 --900.degree. F. (482.degree. C.) liquid yield per unit weight of pyrite added (110). The pyrite addition is controlled in this manner so as to minimize the amount of pyrite used and thus reduce pyrite contribution to the slurry pumping load and disposal problems connected with pyrite produced slag.

Kinetic modeling on CO₂ capture using basic oxygen furnace slag coupled with cold-rolling wastewater in a rotating packed bed.

PubMed

Chang, E-E; Chen, Tse-Lun; Pan, Shu-Yuan; Chen, Yi-Hung; Chiang, Pen-Chi

2013-09-15

In this study, direct and indirect carbonation of basic oxygen furnace slag (BOFS) coupled with cold-rolling wastewater (CRW) was carried out via a rotating packed bed (RPB). The solid products were qualitatively characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD) and quantitatively analyzed with thermogravimetric analysis (TGA). The leachate was analyzed with inductively coupled plasma-optical emission spectroscopy (ICP-OES). The results indicate that the maximum achievable carbonation conversion (MACC) of BOFS was 90.7%, corresponding to a capture capacity of 0.277 g CO₂/g of BOFS, by direct carbonation with CRW under a rotation speed of 750 rpm at 30 °C for 20 min. In addition, CO₂ mass balance among the gas, liquid, and solid phases within an RPB was well-developed, with an error less than 10%, to confirm the actual CO₂ capture capacity of BOFS with precision and accuracy. Furthermore, a reaction kinetic model based on mass balance was established to determine the reaction rate constant for various liquid agents (CRW and pure water). It was concluded that co-utilization of alkaline wastes including BOFS and CRW via the RPB is a novel approach for both enhancing CO₂ capture capacity and reducing the environmental impacts of alkaline wastes. Copyright © 2013 Elsevier B.V. All rights reserved.

Processing of Phosphorus Slag with Recovery of Rare Earth Metals and Obtaining Silicon Containing Cake

NASA Astrophysics Data System (ADS)

Karshigina, Zaure; Abisheva, Zinesh; Bochevskaya, Yelena; Akcil, Ata; Sharipova, Aynash; Sargelova, Elmira

2016-10-01

The present research is devoted to the processing of slag generating during the yellow phosphorus production. In this paper are presented studies on leaching of phosphorus production slag by nitric acid with recovery of rare earth metals (REMs) into solution. REMs recovery into the solution achieved 98 % during the leaching process with using 7.5 mol/L of HNO3, liquid-to-solid ratio is 2.6:1, temperature is 60°C, process duration is 1 hour and stirrer speed is 500 rpm. Behaviour during the leaching of associated components such as calcium, aluminium, and iron was studied. After the leaching cake contains ∼⃒75-85 % of SiO2 and it might be useful for obtaining of precipitated silicon dioxide. With the purpose of separation from the impurities, recovery and concentrating of REMs, the obtained solution after leaching was subjected to extraction processing methods. The influence of ratio of organic and aqueous phases (O: A) on the extraction of rare earth metals by tributyl phosphate (TBP) with concentrations from 20 up to 100 % was studied. The REMs extraction with increasing TBP concentration under changes O:A ratio from 1:20 down to 1:1 into the organic phase from the solutions after nitric acid leaching increased from 22.2 up to 99.3%. The duration effect of REMs extraction process was studied by tributyl phosphate. It is revealed that with increasing of duration of the extraction process from 10 to 30 minutes REMs recovery into the organic phase almost did not changed. The behaviour of iron in the extraction process by TBP was studied. It was found that such accompanying components as calcium and aluminium by tributyl phosphate didn't extracted. To construct isotherm of REMs extraction of by tributyl phosphate was used variable volume method. It was calculated three-step extraction is needed for REMs recovery from the solutions after nitric acid leaching of phosphorus production slag. The process of the three-steps counter current extraction of rare earth metals was modelled from the solutions after slag leaching with using 50 % of TBP in kerosene at the ratios O:A = 1:6 and 1:20. So, REMs recovery into the extract achieved 97.0 and 76.5 %, respectively. It was offered flowsheet of processing of phosphorus slag production with extraction of rare earth metals and obtaining silicon containing cake.

Reactions in the Tuyere Zone of Ironmaking Blast Furnace

NASA Astrophysics Data System (ADS)

Ma, Xiaodong; Zhu, Jinming; Xu, Haifa; Wang, Geoff; Lee, Hae-Geon; Zhao, Baojun

2018-02-01

A series of slags can be formed in the lower part of the ironmaking blast furnace that play important roles in smooth furnace operation, and in determining iron quality and productivity. The final slag tapped from the BF has been investigated extensively as it can be collected directly. Unfortunately, difficulties in accessing the interiors of the blast furnace limit the full understanding of other slags such as primary and bosh slags. In this study, different types of samples directly obtained from the tuyere zone of the blast furnace have been systematically analyzed and characterized using scanning electron microscopy (SEM), electron probe X-ray microanalysis (EPMA), and X-ray fluorescence (XRF), with focus on the characteristics of slags formed in the tuyere level. The samples were identified into three groups according to their morphological, mineralogical, and chemical properties: (1) tuyere slags originating from the reactions between ash and dripping slags; (2) bosh slags in the CaO-SiO2-Al2O3-MgO-FeO system, with a CaO/SiO2 weight ratio of around 1.50, and Al2O3 and MgO concentrations close to those of final slags; and (3) coke ash that did not react with bosh slags. These findings will provide useful information on the evaluation of slags inside the blast furnace and the reactions in the tuyere zone.

A discussion on improving hydration activity of steel slag by altering its mineral compositions.

PubMed

Wang, Qiang; Yan, Peiyu; Feng, Jianwen

2011-02-28

This study aims to investigate the ways to improve the cementitious properties of steel slag. The results show that the cementitious phase of steel slag is composed of silicate and aluminate, but the large particles of these phases make a very small contribution to the cementitious properties of steel slag. RO phase (CaO-FeO-MnO-MgO solid solution), Fe(3)O(4), C(2)F and f-CaO make no contribution to the cementitious properties of steel slag. A new kind of steel slag with more cementitious phase and less RO phase can be obtained by removing some large particles. This new steel slag possesses better cementitious properties than the original steel slag. The large particles can be used as fine aggregates for concrete. Adding regulating agent high in CaO and SiO(2) during manufacturing process of steel slag to increase the cementitious phase to inert phase ratio is another way to improve its cementitious properties. The regulating agent should be selected to adapt to the specific steel slag and the alkalinity should be increased as high as possible on the premise that the f-CaO content does not increase. The cooling rate should be enhanced to improve the hydration activity of the cementitious phase at the early ages and the grindability of steel slag. Copyright © 2010 Elsevier B.V. All rights reserved.

The Effects of Substitution of The Natural Sand by Steel Slag in The Properties of Eco-Friendly Concrete with The 1:2:3 Ratio Mixing Method

NASA Astrophysics Data System (ADS)

Rahmawati, A.; Saputro, I. N.

2018-03-01

This study was motivated by the need for the development of eco-friendly concrete, and the use of large quantities of steel slag as an industrial waste which is generated from the steel manufacturers. This eco-friendly concrete was developed with steel slag as a substitute for natural sand. Properties of concrete which used waste slag as the fine aggregate with the 1 cement: 2 sand : 3 coarse aggregate ratio mixing method were examined. That ratio was in volume. Then a part of natural sand replaced with steel slag sand in six variations percentages that were 0 %, 20 %, 40 %, 60 %, 80 % and 100 %. The compressive strength, tensile strength, and flexural strength of concrete specimens were determined after curing for 28 days. The research results demonstrate that waste steel slag can increase the performance of concrete. The optimal percentage substitution natural sand by steel slag sand reached of slag on the percentage of 20 % which reached strength ratios of steel slag concrete to the strength of conventional concrete with natural sandstone were 1.37 for compressive strength and 1.13 for flexural strength. While the tensile strength reached a higher ratio of concrete with steel slag sand to the concrete with natural sand on the 80% substitution of natural sand with steel slag sand.

Waste activated sludge hydrolysis and acidification: A comparison between sodium hydroxide and steel slag addition.

PubMed

Zhang, Ying; Zhang, Chaojie; Zhang, Xuan; Feng, Leiyu; Li, Yongmei; Zhou, Qi

2016-10-01

Alkaline treatment with steel slag and NaOH addition were investigated under different pH conditions for the fermentation of waste activated sludge. Better performance was achieved in steel slag addition scenarios for both sludge hydrolysis and acidification. More solubilization of organic matters and much production of higher VFA (volatile fatty acid) in a shorter time can be achieved at pH10 when adjusted by steel slag. Higher enzyme activities were also observed in steel slag addition scenarios under the same pH conditions. Phosphorus concentration in the supernatant increased with fermentation time and pH in NaOH addition scenarios, while in contrast most phosphorus was released and captured by steel slag simultaneously in steel slag addition scenarios. These results suggest that steel slag can be used as a substitute for NaOH in sludge alkaline treatment. Copyright © 2016. Published by Elsevier B.V.

Recycling of residual IGCC slags and their benefits as degreasers in ceramics.

PubMed

Iglesias Martín, I; Acosta Echeverría, A; García-Romero, E

2013-11-15

This work studies the evolution of IGCC slag grains within a ceramic matrix fired at different temperatures to investigate the effect of using IGCC slag as a degreaser. Pressed ceramic specimens from two clay mixtures are used in this study. The M1 mixture is composed of standard clays, whereas the M2 mixture is composed of the same clay mixture as M1 mixture but contains 15% by weight IGCC slag. The amount of IGCC slag added coincides with the amount of slag typically used as a degreaser in the ceramic industry. Specimens are fired at 950 °C, 1000 °C, 1050 °C, 1100 °C and 1150 °C. The mineralogical composition and the IGCC slag grain shape within the ceramic matrix are determined by X-ray diffraction, polarized light microscopy and scanning electron microscopy. The results reveal that the surface of the slag grains is welded to the ceramic matrix while the quartz grains are separated, which causes increased water absorption and reduces the mechanical strength. IGCC slag, however, reduces water absorption. This behaviour is due to the softening temperature of the slag. This property is quite important from an industrial viewpoint because IGCC slag can serve as an alternative to traditional degreasing agents in the ceramic building industry. Additionally, using IGCC slag allows for the transformation of waste into a secondary raw material, thereby avoiding disposal at landfills; moreover, these industrial wastes are made inert and improve the properties of ceramics. Copyright © 2013 Elsevier Ltd. All rights reserved.

Evaluation of the suitability of tin slag in cementitious materials: Mechanical properties and Leaching behaviour

NASA Astrophysics Data System (ADS)

Rustandi, Andi; Wafa' Nawawi, Fuad; Pratesa, Yudha; Cahyadi, Agung

2018-01-01

Tin slag, a by-product of tin production has been used in cementitious application. The present investigation focuses on the suitability of tin slag as primary component in cement and as component that substitute some amount of Portland Cement. The tin slags studied were taken from Bangka, Indonesia. The main contents of the tin slag are SiO2, Al2O3, and Fe2O3 according to the XRF investigation. The aim of this article was to study the mechanical behaviour (compressive strength), microstructure and leaching behaviour of tin slag blended cement. This study used air-cooled tin slag that had been passed through 400# sieve to replace Portland Cement with ratio 0, 10, 20, 30, 40 by weight. Cement pastes and tin slag blended cement pastes were prepared by using water/cement ratio (W/C) of 0.40 by weight and hydrated for various curing ages of 3, 7, 14 days The microstructure of the raw tin slag was investigated using Scanning Electron Microscope (SEM). The phase composition of each cement paste was investigated using X-ray Diffraction (XRD). The aim of the leachability test was to investigate the environmental impacts of tin slag blended cement product in the range 4-8 pH by using static pH-dependent leaching test. The result show that the increase of the tin slag content decreasing the mortar compressive strength at early ages. The use of tin slag in cement provide economic benefits for all related industries.

Effect of Physicochemical Properties of Slag and Flux on the Removal Rate of Oxide Inclusion from Molten Steel

NASA Astrophysics Data System (ADS)

Park, Jun Seok; Park, Joo Hyun

2016-12-01

The slag-metal reaction experiments were carried out using a high-frequency induction furnace to confirm the effect of slag composition on the removal rate of inclusions in molten steel through the CaO-based slags. The apparent rate constant of oxygen removal ( k O) was obtained as a function of slag composition. It increased with increasing basicity, and the content of MgO and CaF2, whereas it decreased by increasing the content of Al2O3 in the slag. The removal rate of inclusions was strongly affected not only by the driving force of the chemical dissolution but also by the viscosity of the slags and fluxes.

Thermodynamics of Boron Removal from Silicon Using CaO-MgO-Al2O3-SiO2 Slags

NASA Astrophysics Data System (ADS)

Jakobsson, Lars Klemet; Tangstad, Merete

2018-04-01

Slag refining is one of few metallurgical methods for removal of boron from silicon. It is important to know the thermodynamic properties of boron in slags to understand the refining process. The relation of the distribution coefficient of boron to the activity of silica, partial pressure of oxygen, and capacity of slags for boron oxide was investigated. The link between these parameters explains why the distribution coefficient of boron does not change much with changing slag composition. In addition, the thermodynamic properties of dilute boron oxide in CaO-MgO-Al2O3-SiO2 slags was determined. The ratio of the activity coefficient of boron oxide and silica was found to be the most important parameter for understanding changes in the distribution coefficient of boron for different slags. Finally, the relation between the activity coefficient of boron oxide and slag structure was investigated. It was found that the structure can explain how the distribution coefficient of boron changes depending on slag composition.

Heavy metal adsorption changes of EAF steel slag after phosphorus adsorption.

PubMed

Song, Guanling; Cao, Lijing; Chen, Xiao; Hou, Wenhua; Wang, Qunhui

2012-01-01

A kind of electric arc furnace (EAF) steel slag was phosphated, and its isothermal and dynamic adsorptions of copper, cadmium, and lead ions were measured to determine if heavy metal adsorption changes after phosphorus adsorption. The surface area increased greatly after the slag was phosphated. Isothermal adsorption experiments showed that the theoretical Q(max) of the EAF steel slag on Cu(2+), Cd(2+), and Pb(2+) improved 59, 50, and 89% respectively after it was phosphated. Dynamic adsorption results showed that the greatest adsorption capacities of unit volume of Cu(2+), Cd(2+), and Pb(2+) were 2.2, 1.8, and 1.8 times that of the column packed with original EAF steel slag when the column was packed with phosphate EAF steel slag at the same heavy metal ion concentration. The breakthrough time, the exhaustion time and elution efficiency of the column also increased when the column was packed with phosphated EAF steel slag compared with that packed with original EAF steel slag. Phosphorus adsorption could further improve the heavy metal ion adsorption of the EAF steel slag.

Hydrology and geochemistry of a slag-affected aquifer and chemical characteristics of slag-affected ground water, northwestern Indiana and northeastern Illinois

USGS Publications Warehouse

Bayless, E. Randall; Greeman, T.K.; Harvey, C.C.

1998-01-01

Slag is a by-product of steel manufacturing and a ubiquitous fill material in northwestern Indiana. Ground water associated with slag deposits generally is characterized by high pH and elevated concentrations of many inorganic water-quality constituents. The U.S. Geological Survey, in cooperation with the Indiana Department of Environmental Management, conducted a study in northwestern Indiana from June 1995 to September 1996 to improve understanding of the effects of slag deposits on the water quality of a glacial-outwash aquifer. The Bairstow Landfill, a slag-fill deposit overlying the Calumet aquifer near Hammond, Indiana, was studied to represent conditions in slag-deposit settings that are common in northwestern Indiana. Ground water from 10 observation wells, located in four nests at the site, and surface water from the adjacent Lake George were analyzed for values of field-measured parameters and concentrations of major ions, nutrients, trace elements, and bulk properties. Solid-phase samples of slag and aquifer sediment collected during drilling were examined with X-ray diffraction and geochemical digestion and analysis. Concentrations of calcium, potassium, sodium, and sulfate were highest in wells screened partly or fully in slag. Potassium concentrations in ground water ranged from 2.9 to 120 milligrams per liter (mg/L), were highest in water from slag deposits, and decreased with depth. The highest concentrations for aluminum, barium, molybdenum, nickel, and selenium were in water from the slag. Silica concentrations were highest in wells screened directly beneath the slag?aquifer interface, and magnesium concentrations were highest in intermediate and deep aquifer wells. Silica concentrations in shallow and intermediate aquifer wells ranged from 27 to 41 mg/L and were about 10 times greater than those in water from slag deposits. The highest concentrations for chromium, lead, and zinc were in ground water from immediately below the slag?aquifer interface. The solid-phase analyses indicated that calcite, dolomite, and quartz generally were present throughout the slag?aquifer system; barian celestite, cristobalite, manganese-bearing calcite, and minrecordite were present in fewer samples. Trace elements that are liberated from the slag may be incorporated as impurities during precipitation of major minerals, sorbed onto clays and other grainsize fractions not analyzed as part of this study, or present in low-abundance minerals that were not detected by the X-ray analysis. Mass-balance and speciation programs were used to identify geochemical processes that may be occurring as water infiltrates through the slag, flows into the aquifer, and discharges into Lake George. The geochemical models indicate that precipitation of calcite may be occurring where slag-affected water enters the aquifer. Models also indicate that dolomite precipitation and clay-mineral dissolution may be occurring at the slag?aquifer interface; however, dolomite precipitation is generally believed to require geologically long time periods. Silica may be dissolving where slag-affected ground water enters the aquifer and may be precipitating where slag-affected ground water discharges to the lakebed of Lake George. In addition to the site-specific study, a statistical analysis of regional water quality was done to compare ground water in wells affected and unaffected by slag. When com-pared to wells in background locations in the Calumet aquifer, wells screened in slag across northwestern Indiana and northeastern Illinois generally had relatively higher pH and specific-conductance values and relatively higher concentrations of alkalinity, dissolved solids, suspended solids, total organic carbon, calcium, potassium, sodium, chloride, aluminum, barium, and possibly magnesium, sulfate, chromium, cobalt, copper, cyanide, manganese, mercury, nickel, and vanadium. When compared to wells in slag and wells in background locations, ground water from immediat

Slag processing system for direct coal-fired gas turbines

DOEpatents

Pillsbury, Paul W.

1990-01-01

Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The systems include a primary combustion compartment coupled to an impact separator for removing molten slag from hot combustion gases. Quenching means are provided for solidifying the molten slag removed by the impact separator, and processing means are provided forming a slurry from the solidified slag for facilitating removal of the solidified slag from the system. The released hot combustion gases, substantially free of molten slag, are then ducted to a lean combustion compartment and then to an expander section of a gas turbine.

Influence of lithium slag from lepidolite on the durability of concrete

NASA Astrophysics Data System (ADS)

Qi, Luo; Shaowen, Huang; Yuxuan, Zhou; Jinyang, Li; Weiliang, Peng; Yufeng, Wen

2017-04-01

This paper mainly studies the effect of lithium slag from lepidolite on the property of concrete including dry shrinkage, anti-carbonation, wear resistance and chloride ion resistance. Concrete interface structure has been observed with SEM. The results show that adding lithium slag to concrete can improve concrete property including dry shrinkage, wear resistance and chloride ion resistance. However, the wear resistance tends to decrease when the amount of lithium slag reach 20%. Lithium slag also has negative effect on anti-carbonation property. With the increasing amount of lithium slag, anti-carbonation property of concrete decrease gradually.

Application of steel slag coated with sodium hydroxide to enhance precipitation-coagulation for phosphorus removal.

PubMed

Park, Taejun; Ampunan, Vanvimol; Maeng, Sungkyu; Chung, Eunhyea

2017-01-01

Phosphorus removal has been studied for decades to reduce the environmental impact of phosphorus in natural waterbodies. Slag has been applied for the phosphorus removal by several mechanisms. In this study, sodium hydroxide coating was applied on the slag surface to enhance the efficiency of precipitation-coagulation process. In the batch test, it was found that the capacity of the slag to maintain high pH decreases with increasing its exposure time to the aqueous solution. In the column test, the coarse-grained coated slag showed higher phosphorus removal efficiency than the fine-grained uncoated slag. The coated slag maintained pH higher than uncoated slag and, accordingly, the removal efficiency of phosphorus was higher. Especially, when pH was less than 8, the removal efficiency decreased significantly. However, coated slag provided an excess amount of aluminum and sodium. Thus, a return process to reuse aluminum and sodium as a coagulant was introduced. The return process yields longer lifespan of slag with higher phosphorus removal and lower concentration of cations in the effluent. With the return process, the phosphorus removal efficiency was kept higher than 60% until 150 bed volumes; meanwhile, the efficiency without return process became lower than 60% at 25 bed volumes. Copyright © 2016 Elsevier Ltd. All rights reserved.

A Model for Dissolution of Lime in Steelmaking Slags

NASA Astrophysics Data System (ADS)

Sarkar, Rahul; Roy, Ushasi; Ghosh, Dinabandhu

2016-08-01

In a previous study by Sarkar et al. (Metall. Mater. Trans. B 46B:961 2015), a dynamic model of the LD steelmaking was developed. The prediction of the previous model (Sarkar et al. in Metall. Mater. Trans. B 46B:961 2015) for the bath (metal) composition matched well with the plant data (Cicutti et al. in Proceedings of 6th International Conference on Molten Slags, Fluxes and Salts, Stockholm City, 2000). However, with respect to the slag composition, the prediction was not satisfactory. The current study aims to improve upon the previous model Sarkar et al. (Metall. Mater. Trans. B 46B:961 2015) by incorporating a lime dissolution submodel into the earlier one. From the industrial point of view, the understanding of the lime dissolution kinetics is important to meet the ever-increasing demand of producing low-P steel at a low basicity. In the current study, three-step kinetics for the lime dissolution is hypothesized on the assumption that a solid layer of 2CaO·SiO2 should form around the unreacted core of the lime. From the available experimental data, it seems improbable that the observed kinetics should be controlled singly by any one kinetic step. Accordingly, a general, mixed control model has been proposed to calculate the dissolution rate of the lime under varying slag compositions and temperatures. First, the rate equation for each of the three rate-controlling steps has been derived, for three different lime geometries. Next, the rate equation for the mixed control kinetics has been derived and solved to find the dissolution rate. The model predictions have been validated by means of the experimental data available in the literature. In addition, the effects of the process conditions on the dissolution rate have been studied, and compared with the experimental results wherever possible. Incorporation of this submodel into the earlier global model (Sarkar et al. in Metall. Mater. Trans. B 46B:961 2015) enables the prediction of the lime dissolution rate in the dynamic system of LD steelmaking. In addition, with the inclusion of this submodel, significant improvement in the prediction of the slag composition during the main blow period has been observed.

Environmental risk assessment of steel-making slags and the potential use of LD slag in mitigating methane emissions and the grain arsenic level in rice (Oryza sativa L.).

PubMed

Gwon, Hyo Suk; Khan, Muhammad Israr; Alam, Muhammad Ashraful; Das, Suvendu; Kim, Pil Joo

2018-04-13

Over the past decades, with increasing steel manufacturing, the huge amount of by-products (slags) generated need to be reused in an efficient way not only to reduce landfill slag sites but also for sustainable and eco-friendly agriculture. Our preliminary laboratory study revealed that compared to blast furnace slag, electric arc furnace slag and ladle furnace slag, the Linz-Donawitz converter (LD) slag markedly decreased CH 4 production rate and increased microbial activity. In the greenhouse experiment, the LD slag amendment (2.0 Mg ha -1 ) significantly (p < 0.05) increased grain yield by 10.3-15.2%, reduced CH 4 emissions by 17.8-24.0%, and decreased inorganic As concentrations in grain by 18.3-19.6%, compared to the unamended control. The increase in yield is attributed to the increased photosynthetic rates and increased availability of nutrients to the rice plant. Whereas, the decrease in CH 4 emissions could be due to the higher Fe availability in the slag amended soil, which acted as an alternate electron acceptor, thereby, suppressed CH 4 emissions. The more Fe-plaque formation which could adsorb more As and the competitive inhibition of As uptake with higher availability of Si could be the reason for the decrease in As uptake by rice cultivated with LD slag amendment. Copyright © 2018 Elsevier B.V. All rights reserved.

Influences of Steelmaking Slags on Hydration and Hardening of Concretes

NASA Astrophysics Data System (ADS)

Kirsanova, A. A.; Dildin, A. N.; Maksimov, S. P.

2017-11-01

It is shown that the slag of metallurgical production can be used in the construction industry as an active mineral additive for concrete. This approach allows us to solve environmental problems and reduce costs for the production of binder and concrete simultaneously. Most often slag is used in the form of a filler, an active mineral additive or as a part of a binder for artificial conglomerates. The introduction of slag allows one to notice a part of the cement, to obtain concretes that are more resistant to the impact of aggressive sulfate media. The paper shows the possibility of using recycled steel-smelting slags in the construction industry for the production of cement. An assessment was made of their effect on the hydration of the cement stone and hardening of the concrete together with the plasticizer under normal conditions. In the process of work, we used the slag of the Zlatoust Electrometallurgical Factory. Possible limitations of the content of steel-slag slag in concrete because of the possible presence of harmful impurities are shown. It is necessary to enter slag in conjunction with superplasticizers to reduce the flow of water mixing. Slags can be used as a hardening accelerator for cement concrete as they allow one to increase the degree of cement hydration and concrete strength. It is shown that slags can be used to produce fast-hardening concretes and their comparative characteristics with other active mineral additives are given.

Cleaning of a copper matte smelting slag from a water-jacket furnace by direct reduction of heavy metals.

PubMed

Maweja, Kasonde; Mukongo, Tshikele; Mutombo, Ilunga

2009-05-30

Cleaning experiments of a copper matte smelting slag from the water-jacket furnace was undertaken by direct reduction in a laboratory-scale electric furnace. The effects of coal-to-slag ratio, w, and the reduction time, t, were considered for two different coal/slag mixing procedures. In the first procedure, metallurgical coal was added to the molten slag, whereas in the second procedure, coal was premixed with the solid slag before charging into the furnace. The recovery of heavy metals (Cu, Co), and the fuming of Pb and Zn were investigated. Contamination of the metal phase by iron and the acidity index of the final slag were analysed as these may impede the economical viability of the process. The lower w value of 2.56% yielded a recovery rate of less than 60% for copper and less than 50% for cobalt, and around 70% for zinc. However, increasing w to 5% allowed the recovery of 70-90% for Cu, Co and Zn simultaneously after 30-60 min reduction of the molten slag. After reduction, the cleaned slags contained only small amounts of copper and cobalt (<0.4 wt%). Fuming of lead and zinc was efficient as the %Pb of the residual slag dropped to levels lower than 0.04% after 30 min of reduction. Ninety percent of the lead was removed from the initial slag and collected in the dusts. The zinc content of the cleaned slags quickly dropped to between 1 and 3 wt% from the initial 8.2% after 30 min reduction for w value of 5 and after 60 min reduction for w value of 2.56. The dusts contained about 60% Zn and 10% Pb. Recovery of lead from fuming of the slag was higher than 90% in all the experimental conditions considered in this study.

Controlling chromium slag pollution utilising scavengers: a case of Shandong Province, China.

PubMed

Liu, Changhao; Côté, Raymond P

2015-04-01

The problem of chromium slag pollution is a great challenge for China. It is now an urgent task for China to take effective measures to eliminate chromium slag pollution. This article examines the case of the treatment of chromium slag in Shandong Province and explores how chromium slag pollution can be eliminated in Shandong Province. It shows that the chromium slag stockpiled by the chemical plants was successfully utilised by local steel companies, who act as 'scavenger companies'. The driving mechanism, seeking a potential 'scavenger company' within the local region and the role of the local government on the case of Shandong Province are discussed. This article concludes that local steel companies can be utilised to effectively and efficiently treat the chromium slag while benefiting the steel companies. The local governments need to play multiple roles in solving the problem of chromium slag pollution. Seeking and identifying 'scavenger companies' within a region could be an important approach to reducing pollution within the region. © The Author(s) 2015.

Heavy metal pollution of soils and sediments at the historical smelting site of the Rudawy Janowickie Mountains (Lower Silesia, Poland).

NASA Astrophysics Data System (ADS)

Kierczak, Jakub; Néel, Catherine; Pietranik, Anna

2010-05-01

Multidisciplinary studies of historical slags are mostly focused on exploring how metallurgy evolved through human history. Another purpose for studying historical slags are potentially harmful interactions between slags, surrounding soils, sediments and waters. Metallurgical slags generally concentrate potentially toxic elements (PTE) such as arsenic, copper and lead. These elements may be mobilized and transferred into immediate surroundings. The main aim of our work is to identify factors controlling migration of metals at the historical smelting site of the Rudawy Janowickie Mountains. This study involves detailed analyzes of historical slags (older than 300 years) containing PTE, as well as surrounding soils and sediments. The Rudawy Janowickie Mountains represented an important centre of copper mining and smelting in Poland until 1925 with metallurgical activities being documented as early as in the XIV century. The exploitation of Cu ores has left large amounts of mine tailings and slags extending over ca. 35ha. The slags were deposited on ground and no barriers between the slags and environment were set. Therefore, they were continuously affected by variable factors, for example, changing weather conditions. Soils located in the study area are derived from granitic rocks. They are shallow (< 1 meter depth) and skeletic (containing > 50 wt. % of coarse fragments). Their pHw is acidic and varies from 3.4 to 4.5 from the topsoil to the deeper horizons in which slags are widespread. Mineral composition of soils and sediments is dominated by quartz, alkali feldspar, plagioclase and biotite. However, some samples may contain additionally numerous slag fragments. At present, the slags occur within three types of environments: (1) at the surface, (2) in soils and (3) in sediments from two streams: Janówka and Smelter Stream. Studied slags were sampled in the vicinity of both streams from (1) surface, (2) soil profiles and (3) streambeds. Furthermore, samples of soils and stream sediments were collected at the same time in order to observe weathering features of slags in different environments and to verify the influence of those wastes on properties of soils and sediments. Studied slags are isometric and well rounded (pebble-like), with size ranging from few to dozens of centimetres. The average chemical composition of slags is 47 wt. % Fe2O3, 40 wt. % SiO2, 8 wt. % Al2O3. Slags show elevated concentrations of Cu (up to 13400 ppm), Zn (up to 3640 ppm), Pb (up to 270 ppm) and As (up to 130 ppm). Dominant type of slag occurring in all environments is black and has massive texture. It consists of silicate glass, fayalite, hercynite, bornite, pyrhotite, intermetallic compounds of Fe and As, metallic Pb and Cu. Sulfides and metallic phases are the most important PTE carriers. Second type of slag was found only on surface. It is highly porous and often encloses small fragments of granitic rocks. Despite weathered appearance, it has similar phase composition to the dominant type of slag. The weathering products occur as aureoles and interstitial replacements within the sulfides. Secondary phases in the aureoles are: brochantite, malachite and Fe oxy-hydroxides. PTE initially concentrated in primary phases such as sulfides can be mobilized by weathering and be subsequently bounded in secondary phases (brochantite, malachite). The stability of these phases depends on the surrounding conditions (e.g. here, secondary phases are stable only in slags from surface). Presence of slags at the studied site is clearly documented by geochemical analysis of stream sediments. The Cu concentration in sediments from the area where no slags have been found is 8 ppm, while it exceeds 130 ppm in the site where slags are widespread. Our observations thus show that the studied slags release some potentially toxic elements (especially Cu) during weathering and the slag texture appears to be an important factor controlling metal migration. The work was financed by Polish Ministry of Science and Higher Education grant no. 4269/PB/ING/09.

Novel Sessile Drop Software for Quantitative Estimation of Slag Foaming in Carbon/Slag Interactions

NASA Astrophysics Data System (ADS)

Khanna, Rita; Rahman, Mahfuzur; Leow, Richard; Sahajwalla, Veena

2007-08-01

Novel video-processing software has been developed for the sessile drop technique for a rapid and quantitative estimation of slag foaming. The data processing was carried out in two stages: the first stage involved the initial transformation of digital video/audio signals into a format compatible with computing software, and the second stage involved the computation of slag droplet volume and area of contact in a chosen video frame. Experimental results are presented on slag foaming from synthetic graphite/slag system at 1550 °C. This technique can be used for determining the extent and stability of foam as a function of time.

Effect of Basicity on Basic Oxygen Furnace (BOF) Slag Solidification Microstructure and Mineralogy

NASA Astrophysics Data System (ADS)

Liu, Chunwei; Guo, Muxing; Pandelaers, Lieven; Blanpain, Bart; Huang, Shuigen

Slag valorization in added value construction applications can contribute substantially to the sustainability of steel industry. The present work aims to investigate the crystallization behavior of a typical industrial Basic Oxygen Furnace (BOF) slag (CaO-FeOx-SiO2-based slag) by varying the basicity through hot stage engineering. A sample of industry Basic Oxygen Slag (BOF) was mixed with different quantities of silica (SiO2) to modify basicity. The effect of basicity on solidification microstructure and mineralogy was studied. The results suggest that the mineralogy of the solidified slag can be manipulated to enhance its suitability as raw material for construction applications.

Industrial Tests to Modify Molten Copper Slag for Improvement of Copper Recovery

NASA Astrophysics Data System (ADS)

Guo, Zhengqi; Zhu, Deqing; Pan, Jian; Zhang, Feng; Yang, Congcong

2018-04-01

In this article, to improve the recovery of copper from copper slag by flotation process, industrial tests of the modification process involving addition of a composite additive into molten copper slag were conducted, and the modified slag was subjected to the flotation process to confirm the modification effect. The phase evolution of the slag in the modification process was revealed by thermodynamic calculations, x-ray diffraction, optical microscopy and scanning electron microscopy. The results show that more copper was transformed and enriched in copper sulfide phases. The magnetite content in the modified slag decreased, and that of "FeO" increased correspondingly, leading to a better fluidity of the molten slag, which improved the aggregation and growth of fine particles of the copper sulfide minerals. Closed-circuit flotation tests of the original and modified slags were conducted, and the results show that the copper recovery increased obviously from 69.15% to 73.38%, and the copper grade of concentrates was elevated slightly from 20.24% to 21.69%, further confirming that the industrial tests of the modification process were successful. Hence, the modification process has a bright future in industrial applications for enhancing the recovery of copper from the copper slag.

Effect of MgO and MnO on Phosphorus Utilization in P-Bearing Steelmaking Slag

NASA Astrophysics Data System (ADS)

Lin, Lu; Bao, Yan-Ping; Wang, Min; Li, Xiang

2016-04-01

In order to recycle the phosphorus in P-bearing converter slag and make it used as slag phosphate fertilizer, the effect of MgO and MnO in P-bearing steelmaking slag on phosphorus existence form, P2O5 solubility and magnetic separation behavior were researched systematically. The results show that the phosphorus in slag is mainly in the form of n2CaO · SiO2-3CaO · P2O5 (for short nC2S-C3P) solid solution in the P-rich phase for CaO-SiO2-FetO-P2O5-X (X stands for MgO and MnO, respectively). And the increasing of MgO and MnO content has no influence on precipitation of nC2S-C3P solid solution in slag, MnO and MgO mainly enter into RO phase and base phase to form MnFe2O4 and MgFe2O4, which has little effect on the P2O5 content of P-rich phase, so which has little effect on the degree of phosphorus enrichment and phosphorus occurrence form of the P-bearing slag. And adding MgO and MnO into CaO-SiO2-P2O5-Fe2O3 slag system can break the complex net structure formed by Si-O on certain degree, and also hinder the precipitation of β-Ca3(PO4)2 crystal with low citric acid solubility during the melting-cooling process. Therefore, adding appropriate MgO and MnO content into slag can improve the slag P2O5 solubility, but the effect of different amounts of MgO and MnO on the P2O5 solubility has little difference. Meanwhile, adding MgO and MnO into slag can improve the metallization of slag and magnetism of iron-rich phase, make the magnetic substances content increase and separation of phosphorus and iron incomplete, so it is adverse to phosphorus resources recovery from P-bearing slag by magnetic separation method. In order to recycle the phosphorus in P-bearing converter slag, the MgO and MnO content in the P-bearing slag should be controlled in the steelmaking process.

Characterisation of Ba(OH){sub 2}–Na{sub 2}SO{sub 4}–blast furnace slag cement-like composites for the immobilisation of sulfate bearing nuclear wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mobasher, Neda; Bernal, Susan A.; Hussain, Oday H.

2014-12-15

Soluble sulfate ions in nuclear waste can have detrimental effects on cementitious wasteforms and disposal facilities based on Portland cement. As an alternative, Ba(OH){sub 2}–Na{sub 2}SO{sub 4}–blast furnace slag composites are studied for immobilisation of sulfate-bearing nuclear wastes. Calcium aluminosilicate hydrate (C–A–S–H) with some barium substitution is the main binder phase, with barium also present in the low solubility salts BaSO{sub 4} and BaCO{sub 3}, along with Ba-substituted calcium sulfoaluminate hydrates, and a hydrotalcite-type layered double hydroxide. This reaction product assemblage indicates that Ba(OH){sub 2} and Na{sub 2}SO{sub 4} act as alkaline activators and control the reaction of the slagmore » in addition to forming insoluble BaSO{sub 4}, and this restricts sulfate availability for further reaction as long as sufficient Ba(OH){sub 2} is added. An increased content of Ba(OH){sub 2} promotes a higher degree of reaction, and the formation of a highly cross-linked C–A–S–H gel. These Ba(OH){sub 2}–Na{sub 2}SO{sub 4}–blast furnace slag composite binders could be effective in the immobilisation of sulfate-bearing nuclear wastes.« less

Mineral resource of the month: ferrous slag

USGS Publications Warehouse

,

2009-01-01

The article offers information on mineral resource ferrous slag. Ferrous slag is produced through the addition of materials such as limestone and dolomite to blast and steel furnaces to remove impurities from iron ore and to lower the heat requirements for processes in iron and steel making. It is stated that the method of cooling is important for the market uses and value of ferrous slag. Some types of slag can be used in construction, glass manufacturing and thermal insulation.

A novel process for preparation of titanium dioxide from Ti-bearing electric furnace slag: NH4HF2-HF leaching and hydrolyzing process.

PubMed

Zheng, Fuqiang; Guo, Yufeng; Qiu, Guanzhou; Chen, Feng; Wang, Shuai; Sui, Yulei; Jiang, Tao; Yang, Lingzhi

2018-02-15

A novel process to prepare titanium dioxide from Ti-bearing electric furnace slag by NH 4 HF 2 -HF leaching and hydrolyzing process has been developed. In this present study, the effects of [NH 4 + ]/[F] mXolar ratio, leaching temperature, [F] concentration, liquid/solid mass ratio, leaching time on the Ti extraction, and the phase transformations have been investigated to reveal the leaching mechanism of Ti-bearing electric furnace slag in NH 4 HF 2 -HF solution. In the NH 4 HF 2 -HF leaching process, the MgTi 2 O 5 and Al 2 TiO 5 are converted to TiF 6 2- and Mg-Al-bearing precipitate. Ti extraction rate reached 98.84% under the optimal conditions. In addition, 98.25% iron ions can be removed in the presence of NaCl prior to hydrolysis process. The effects of pH and temperature on the selective hydrolysis of TiF 6 2- during hydrolysis process were also studied. In the hydrolysis process, the TiF 6 2- is converted to (NH 4 ) 2 TiOF 4 . By calcination, high grade TiO 2 powder with its purity of 99.88% was obtained, using which the products, well crystallized anatase and rutile, were obtained through roasting at 800°C and 1000°C, respectively. Copyright © 2017 Elsevier B.V. All rights reserved.

Calcium Treatment for FeSi-killed Fe-13 Pct Cr Stainless Steel with Various Top Slag Compositions

NASA Astrophysics Data System (ADS)

Wang, Qi; Wang, Lijun; Zhai, Jun; Li, Jianmin; Chou, Kuochih

2018-02-01

Calcium treatment of Fe-13 pct Cr stainless steel, with inclusion modification as its main purpose, was evaluated on a laboratory scale. The stability diagram of Ca-Al was obtained using the FactSage software and could be divided into three parts based on the [Al] content: the ultra-low-Al region, the low-Al region, and the medium-high-Al region. Each of these regions required different amounts of calcium for inclusion modification. The ferrosilicon deoxidation product could be modified into low melting temperature inclusions by a CaO-SiO2 top slag in the ultra-low-Al region ([Al] content less than 40 ppm). Calcium treatment was necessary to modify the ferrosilicon deoxidation product into low melting temperature inclusions in the low-Al region ([Al] content from 40 to 100 ppm) for the CaO-SiO2-Al2O3 top slag. Calcium addition has a "liquid window" where adding calcium can accelerate inclusion modification. Adding calcium for 15 and 30 minutes resulted in complete modification times of 45 and 60 minutes, respectively, which indicates that early calcium treatment can produce plastic inclusions sooner. The relationship between the steel and inclusion content was determined by fitting the experimental data in the low-Al region. An appropriate range of T.Ca/T.O (total calcium content/total oxygen content) for inclusion modification is 0.99 to 1.44.

A Shallow Layer Approach for Geo-flow emplacement

NASA Astrophysics Data System (ADS)

Costa, A.; Folch, A.; Mecedonio, G.

2009-04-01

Geophysical flows such as lahars or lava flows severely threat the communities located on or near the volcano flanks. Risks and damages caused by the propagation of this kind of flows require a quantitative description of this phenomenon and reliable tools for forecasting their emplacement. Computational models are a valuable tool for planning risk mitigation countermeasures, such as human intervention to force flow diversion, artificial barriers, and allow for significant economical and social benefits. A FORTRAN 90 code based on a Shallow Layer Approach for Geo-flows (SLAG) for describing transport and emplacement of diluted lahars, water and lava was developed in both serial and parallel version. Three rheological models, such as those describing i) a viscous, ii) a turbulent, and iii) a dilatant flow respectively, were implemented in order to describe transport of lavas, water and diluted lahars. The code was made user-friendly by creating some interfaces that allow the user to easily define the problem, extract and interpolate the topography of the simulation domain. Moreover SLAG outputs can be written in both GRD format (e.g., Surfer), NetCDF format, or visualized directly in GoogleEarth. In SLAG the governing equations were treated using a Godunov splitting method following George (2008) algorithm based on a Riemann solver for the shallow water equations that decomposes an augmented state variable the depth, momentum, momentum flux, and bathymetry into four propagating discontinuities or waves. For our application, the algorithm was generalized for solving the energy equation. For validating the code in simulating real geophysical flows, we performed few simulations the lava flow event of the the 3rd and 4th January 1992 Etna eruption, the July 2001 Etna lava flows, January 2002 Nyragongo lava flows and few test cases for simulating transport of diluted lahars. Ref: George, D.L. (2008), Augmented Riemann Solvers for the Shallow Water Equations over Variable Topography with Steady States and Inundation, J. Comput. Phys., 227 (6), 3089-3113, doi:10.1016/j.jcp.2007.10.027.

Geophysical exploration of historical mine dumps for the estimation of valuable residuals

NASA Astrophysics Data System (ADS)

Martin, Tina; Knieß, Rudolf; Noell, Ursula; Hupfer, Sarah; Kuhn, Kerstin; Günther, Thomas

2015-04-01

Within the project ROBEHA, funded by the German Federal Ministry of Education and Research (033R105) the economic potential of different abandoned dump sites for mine waste in the Harz Mountains was investigated. Two different mining dumps were geophysically and mineralogically analysed in order to characterize the mine dump structure and to estimate the volume of the potential recycling material. The geophysical methods comprised geoelectrics, radar, and spectral induced polarization (SIP). One about 100-year old mining dump containing residues from density separated Ag- and Sb-rich Pb (Zn)-gangue ores was investigated in detail. Like most small-scale mining waste disposal sites this investigated dump is very heterogeneously structured. Therefore, 27 geoelectrical profiles, more than 50 radar profiles, and several SIP profiles were measured and analysed. The results from the radar measurements, registered with the GSSI system and a shielded 200 MHz antenna, show the near surface boundary layer (down to 3-4 m beneath surface) of the waste residuals. These results can be used as pre-information for the inversion process of the geoelectrical data. The geoelectrical results reveal the mineral residues as layers with higher resistivities (> 300 Ohm*m) than the surrounding material. The SIP method found low phase signals (< 0.5°) for the residues. To estimate the volume of the potentially reusable material we analysed each geoelectrical profile and interpolated between the single profiles using the BERT algorithm. Taking into account the wooded areas of the mine dump and other parameters we get a first estimate for the volume of the residues but the economical viability and the environmental impact of the reworking of the dump still needs to be evaluated in detail. The results of the second mine dump, an abandoned Cu and Zn-rich slag heap, show that the slag residues are characterized by higher resistivities and higher phases. A localization of the slag residues which are covered by organic material could be realized applying these geophysical methods.

Effect of Iron Redox Equilibrium on the Foaming Behavior of MgO-Saturated Slags

NASA Astrophysics Data System (ADS)

Park, Youngjoo; Min, Dong Joon

2018-04-01

In this study, the foaming index of CaO-SiO2-FetO and CaO-SiO2-FetO-Al2O3 slags saturated with MgO was measured to understand the relationship between their foaming behavior and physical properties. The foaming index of MgO-saturated slags increases with the FetO content due to the redox equilibrium of FetO. Experimental results indicated that MgO-saturated slag has relatively high ferric ion concentration, and the foaming index increases due to the effect of ferric ion. Therefore, the foaming behavior of MgO-saturated slag is more reasonably explained by considering the effect of ferric ion on the estimation of slag properties such as viscosity, surface tension, and density. Specifically, the estimation of slag viscosity was additionally verified by NBO/T, and this is experimentally obtained through Raman spectroscopy.

The Effect of Propellant Variables on Slag in Subscale Spin Motors. Part 1; Design and Qualification of a Slag Discrimination Motor

NASA Technical Reports Server (NTRS)

Perkins, F. M.; Beus, R. W.; May, D. H.

1995-01-01

The formation, collection, and expulsion of aluminum oxide slag is known to affect the performance of many solid rocket motor systems. Slag expulsion, in particular, is believed to be capable of causing pressure and thrust perturbations. Propellant combustion studies, performed and documented by many investigators, have shown that variations in propellant raw materials and processing affect the nature of alumina droplets at the burning propellant surface, and hence, may affect the quantity of slag retained in the motor chamber, available for expulsion. Thiokol has completed an experimental and analytical evaluation to determine the effects of several material and process variables on Space SHuttle propellant and its propensity to 'slag'. This paper describes the test article, a small scale spin motor with special nozzle, designed and qualified as a slag discriminating tool for use in the evaluation.

Evaluation of copper slag to catalyze advanced oxidation processes for the removal of phenol in water.

PubMed

Huanosta-Gutiérrez, T; Dantas, Renato F; Ramírez-Zamora, R M; Esplugas, S

2012-04-30

The aim of this work was to evaluate the use of copper slag to catalyze phenol degradation in water by advanced oxidation processes (AOPs). Copper slag was tested in combination with H(2)O(2) (slag/H(2)O(2)) and H(2)O(2)/UV (slag/H(2)O(2)/UV). The studied methods promoted the complete photocatalytic degradation of phenol. Besides, they were able to reduce about 50% the TOC content in the samples. Slag/H(2)O(2)/UV and slag/H(2)O(2) treatments have favored biodegradability increment along the reaction time. Nevertheless, the irradiated method achieved higher values of the biodegradability indicator (BOD(5)/TOC). The toxicity assessment indicated the formation of more toxic compounds in both treatments. However, the control of the reaction time would minimize the environmental impact of the effluents. Copyright © 2012 Elsevier B.V. All rights reserved.

Utilization of High-Temperature Slags From Metallurgy Based on Crystallization Behaviors

NASA Astrophysics Data System (ADS)

Sun, Yongqi; Zhang, Zuotai

2018-05-01

Here, following the principle of modifying crystallization behaviors, including avoidance and optimization, we review recent research on the utilization of hot slags. Because of the high-temperature property (1450-1650°C), the utilization of hot slags are much different from that of other wastes. We approach this issue from two main directions, namely, material recycling and heat utilization. From the respect of material recycling, the utilization of slags mainly follows total utilization and partial utilization, whereas the heat recovery from slags follows two main paths, namely, physical granulation and chemical reaction. The effective disposal of hot slags greatly depends on clarifying the crystallization behaviors, and thus, we discuss some optical techniques and their applicable scientific insights. For the purpose of crystallization avoidance, characterizing the glass-forming ability of slags is of great significance, whereas for crystallization modification, the selection of chemical additives and control of crystallization conditions comprise the central routes.

Influence of amount of oxidizing slag discharged from stainless steelmaking process of electric arc furnace on elution behavior into fresh water

NASA Astrophysics Data System (ADS)

Yokoyama, S.; Shimomura, T.; Hisyamudin, M. N. N.; Takahashi, T.; Izaki, M.

2012-03-01

Fundamental study was carried out for provision for acidification of soil due to acid rain. The influence of weight of the additive slag on elution behavior of the slag into water was studied in this study. Elution experiment was carried out on a basis of JIS K 0058-1. Generally, the pH in the aqueous solution increased with an increase in weight of the additive slag. The pH converged to approximately eight. Calcium, magnesium and manganese, which were essential elements for plants, were eluted from the slag irrespective to elution condition. The eluted concentrations of Ca and Mg increased with an increase in weight of the additive slag. Silicon and zinc were also eluted depending on the conditions. Aluminum that was harmful for plants was not eluted from the used slag.

Moderate Dilution of Copper Slag by Natural Gas

NASA Astrophysics Data System (ADS)

Zhang, Bao-jing; Zhang, Ting-an; Niu, Li-ping; Liu, Nan-song; Dou, Zhi-he; Li, Zhi-qiang

2018-01-01

To enable use of copper slag and extract the maximum value from the contained copper, an innovative method of reducing moderately diluted slag to smelt copper-containing antibacterial stainless steel is proposed. This work focused on moderate dilution of copper slag using natural gas. The thermodynamics of copper slag dilution and ternary phase diagrams of the slag system were calculated. The effects of blowing time, temperature, matte settling time, and calcium oxide addition were investigated. The optimum reaction conditions were identified to be blowing time of 20 min, reaction temperature of 1250°C, settling time of 60 min, CaO addition of 4% of mass of slag, natural gas flow rate of 80 mL/min, and outlet pressure of 0.1 MPa. Under these conditions, the Fe3O4 and copper contents of the residue were 7.36% and 0.50%, respectively.

Method of fabrication of supported liquid membranes

DOEpatents

Luebke, David R.; Hong, Lei; Myers, Christina R.

2015-11-17

Method for the fabrication of a supported liquid membrane having a dense layer in contact with a porous layer, and a membrane liquid layer within the interconnected pores of the porous layer. The dense layer is comprised of a solidified material having an average pore size less than or equal to about 0.1 nanometer, while the porous layer is comprised of a plurality of interconnected pores and has an average pore size greater than 10 nanometers. The supported liquid membrane is fabricated through the preparation of a casting solution of a membrane liquid and a volatile solvent. A pressure difference is established across the dense layer and porous layer, the casting solution is applied to the porous layer, and the low viscosity casting solution is drawn toward the dense layer. The volatile solvent is evaporated and the membrane liquid precipitates, generating a membrane liquid layer in close proximity to the dense layer.

A New Experimental Design to Study the Kinetics of Solid Dissolution into Liquids at Elevated Temperature

NASA Astrophysics Data System (ADS)

Wang, Huijun; White, Jesse F.; Sichen, Du

2018-04-01

A new method was developed to study the dissolution of a solid cylinder in a liquid under forced convection at elevated temperature. In the new design, a rotating cylinder was placed concentrically in a crucible fabricated by boring four holes into a blank material for creating an internal volume with a quatrefoil profile. A strong flow in the radial direction in the liquid was created, which was evidently shown by computational fluid dynamic (CFD) calculations and experiments at both room temperature and elevated temperature. The new setup was able to freeze the sample as it was at experimental temperature, particularly the interface between the solid and the liquid. This freezing was necessary to obtain reliable information for understanding the reaction mechanism. This was exemplified by the study of dissolution of a refractory in liquid slag. The absence of flow in the radial direction in the traditional setup using a symmetrical cylinder was also discussed. The differences in the findings by past investigators using the symmetrical cylinder are most likely due to the extent of misalignment of the cylinder in the containment vessel.

Utilizing steel slag in environmental application - An overview

NASA Astrophysics Data System (ADS)

Lim, J. W.; Chew, L. H.; Choong, T. S. Y.; Tezara, C.; Yazdi, M. H.

2016-06-01

Steel slags are generated as waste material or byproduct every day from steel making industries.The potential environmental issues which are related with the slag dump or reprocessing for metal recovery are generally being focused in the research. However the chemistry and mineralogy of slag depends on metallurgical process which is able to determine whether the steel slag can be the reusable products or not. Nowadays, steel slag are well characterized by using several methods, such as X-ray Diffraction, ICP-OES, leaching test and many more. About the industrial application, it is mainly reused as aggregate for road construction, as armour stones for hydraulic engineering constructions and as fertilizers for agricultural purposes. To ensure the quality of steel slag for the end usage, several test methods are developed for evaluating the technical properties of steel slag, especially volume stability and environmental behaviour. In order to determine its environmental behaviour, leaching tests have been developed. The focus of this paper however is on those applications that directly affect environmental issues including remediation, and mitigation of activities that negatively impact the environment.

Glass ceramics for incinerator ash immobilization

NASA Astrophysics Data System (ADS)

Malinina, G. A.; Stefanovsky, O. I.; Stefanovsky, S. V.

2011-09-01

Calcined solid radioactive waste (incinerator slag) surrogate and either Na 2Si 2O 5 or Na 2B 4O 7 (borax) at various mass ratios were melted in silicon carbide crucibles in a resistive furnace at temperatures of up to 1775 K (slag without additives). Portions of the melts were poured onto a metal plate; the residues were slowly cooled in turned-off furnace. Both quenched and slowly cooled materials were composed of the same phases. At high slag contents in silicate-based materials nepheline and britholite were found to be major phases. Britholite formed at higher slag content (85 wt.%) became major phase in the vitrified slag. In the system with borax at low slag contents (25 and 50 wt.%) material are composed of predominant vitreous and minor calcium silicate larnite type phase Ca 2SiO 4 where Ca 2+ ions are replaced by different cations. The materials containing slag in amount of 75 wt.% and more are chemically durable. The changes in the structure of anionic motif of quenched samples depending on slag loading were studied by IR spectroscopy.

Predicting Slag Generation in Sub-Scale Test Motors Using a Neural Network

NASA Technical Reports Server (NTRS)

Wiesenberg, Brent

1999-01-01

Generation of slag (aluminum oxide) is an important issue for the Reusable Solid Rocket Motor (RSRM). Thiokol performed testing to quantify the relationship between raw material variations and slag generation in solid propellants by testing sub-scale motors cast with propellant containing various combinations of aluminum fuel and ammonium perchlorate (AP) oxidizer particle sizes. The test data were analyzed using statistical methods and an artificial neural network. This paper primarily addresses the neural network results with some comparisons to the statistical results. The neural network showed that the particle sizes of both the aluminum and unground AP have a measurable effect on slag generation. The neural network analysis showed that aluminum particle size is the dominant driver in slag generation, about 40% more influential than AP. The network predictions of the amount of slag produced during firing of sub-scale motors were 16% better than the predictions of a statistically derived empirical equation. Another neural network successfully characterized the slag generated during full-scale motor tests. The success is attributable to the ability of neural networks to characterize multiple complex factors including interactions that affect slag generation.

Mineralogy and origin of coarse-grained segregations in the pyrometallurgical Zn-Pb slags from Katowice-Wełnowiec (Poland)

NASA Astrophysics Data System (ADS)

Warchulski, R.; Gawęda, A.; Janeczek, J.; Kądziołka-Gaweł, M.

2016-10-01

The unique among pyrometallurgical slags, coarse-grained (up to 2.5 cm) segregations (up to 40 cm long) rimmed by "aplitic" border zones occur within holocrystalline historical Zn-smelting slag in Katowice, S Poland. Slag surrounding the segregations consists of olivine, spinel series, melilite, clinopyroxene, leucite, nepheline and sulphides. Ca-olivines, kalsilite and mica compositionally similar to oxykinoshitalite occur in border zones in addition to olivine, spinel series and melilite. Miarolitic and massive pegmatite-like segregations are built of subhedral crystals of melilite, leucite, spinel series, clinopyroxene and hematite. Melilite, clinopyroxenes and spinels in the segregations are enriched in Zn relatively to original slag and to fine-grained border zones. The segregations originated as a result of crystallization from residual melt rich in volatiles (presumably CO2). The volatile-rich melt was separated during fractional crystallization of molten slag under the cover of the overlying hot (ca. 1250 °C) vesicular slag, preventing the escape of volatiles. That unique slag system is analogous to natural magmatic systems.

Modified DHTT Equipment for Crystallization Studies of Mold Slags

NASA Astrophysics Data System (ADS)

Kölbl, Nathalie; Harmuth, Harald; Marschall, Irmtraud

2018-04-01

The double hot thermocouple technique (DHTT) enables simulations of the temperature gradient at near-service conditions during continuous casting of steel. With the equipment applied so far, a rectangular slag film of even thickness often cannot be achieved. Further, the minimum temperature frequently lies within the slag film. Modified equipment can avoid these disadvantages via the following design features. The entire furnace chamber is heated to the selected temperature of the cold wire, and the minimum temperature is not located within the slag film. Furthermore, the shape of the heating wire is improved, which enables mounting of a thin, rectangular slag film between four platinum wires. This modification allows for investigations on transparent and translucent slags. So far, the results from DHTT investigations were represented via snapshots of the samples at certain experimental times. Therefore, appropriate methods for the graphical representation of the results were suggested: the maximum crystallinity, the time related to certain crystallinities with a dependence on the position within the slag film, and the crystal growth rate. The CaO-MgO-Al2O3-SiO2 slag investigated with this equipment was mineralogically examined additionally, and based on thermodynamic calculations, the allocation of temperatures to certain positions within the crystallized slag film was possible.

Environmental impacts of asphalt mixes with electric arc furnace steel slag.

PubMed

Milačič, Radmila; Zuliani, Tea; Oblak, Tina; Mladenovič, Ana; Ančar, Janez Šč

2011-01-01

Electric arc furnace (EAF) steel slag can be used as an alternative high-quality material in road construction. Although asphalts with slag aggregates have been recognized as environmentally acceptable, there is a lack of data concerning the potential leaching of toxic Cr(VI) due to the highly alkaline media of EAF slag. Leaching of selected water extractable metals from slag indicated elevated concentrations of total chromium and Cr(VI). To estimate the environmental impacts of asphalt mixes with slag, leachability tests based on diffusion were performed using pure water and salt water as leaching agents. Compact and ground asphalt composites with natural aggregates, and asphalt composites in which the natural aggregates were completely replaced by slag were prepared. The concentrations of total chromium and Cr(VI) were determined in leachates over a time period of 6 mo. After 1 and 6 mo, the concentrations of some other metals were also determined in the leachates. The results indicated that chromium in leachates from asphalt composites with the addition of slag was present almost solely in its hexavalent form. However, the concentrations were very low (below 25 μg L) and did not represent an environmental burden. The leaching of other metals from asphalt composites with the addition of slag was negligible. Therefore, the investigated EAF slag can be considered as environmentally safe substitute for natural aggregates in asphalt mixes. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Pilot-scale steam aging of steel slags.

PubMed

Kumar, Praveen; Satish Kumar, D; Marutiram, K; Prasad, Smr

2017-06-01

Solid waste management has gained importance in the steel industry in view of rising environmental concerns and scarcity of raw materials. In spite of significant developments in reducing waste generation and development of recycling technologies, steel slag is still a concern for the industry as most of it is dumped. Steel slag is similar to stone aggregates in strength, but its volumetric instability in contact with water hinders its application as aggregates in construction. A part of steel slag is normally exposed to rain and sun for natural aging and stabilization for months before use. The natural aging process is slow and time-consuming, and thus restricts its usage. The steelmaking slag can be put to effective use as coarse aggregates if quickly aged and stabilized by pre-reacting the free expansive phases. In the present work, a new process has been developed to accelerate the steel slag aging process using steam in a 30 T pilot scale facility. The setup has controlled steam injection, distribution, and process control system for steam, temperature, flow, and pressure. Steam percolates through the minute pores in the slag lumps and hydrates the expansive free lime and MgO phases, making it stable. The aged slag expansion properties were tested using an in-house developed expansion testing apparatus. The process is capable of reducing the expansion of steel slag from 3.5% to <1.5% (standard requirement) in 7 days. The aged steel slag is currently being used in roads at JSW Steel, Vijayanagar Works.

The investigation of solid slag obtained by neutralization of sewage sludge.

PubMed

Kavaliauskas, Zydrunas; Valincius, Vitas; Stravinskas, Giedrius; Milieska, Mindaugas; Striugas, Nerijus

2015-11-01

The purpose of this research is to investigate the feasibility of utilizing the slag collected after gasification of organic fuel combined with sewage sludge. The residue left after gasification process is likely usable as raw material for production of supercondensers. The sewage sludge neutralization system consists of a dosing system (fuel tank), gasifier, plasma reactor, electrostatic filter, and heat exchangers. For the gasification process, dried solid sewage is supplied in proportion of 70% to biomass 30% by weight. The slag is collected in a specially designed chamber beneath the gasifier. A scanning electron microscope (SEM) was used to evaluate surface morphology of the samples. Elemental analysis of the sewage sludge slag was performed using the energy-dispersive spectroscopy (EDS) method, which showed different solid-state elements contained in the porous structure of the solid phase: carbon 29%, aluminum 26%, potassium 20%, chlorine 1%, and others. The specific surface area of the sewage sludge slag is 6.15 m(2)/g as the BET analysis shows. In order to use the slag as a secondary raw material, detailed analysis of the structure and properties is necessary for a decision on whether the slag left after gasification of sewage sludge is suitable for any further usages. Initial results indicate that the slag may be used for production of electrodes for supercapacitors. Every year thousands of tons of sewage sludge are formed in Lithuania. Sewage sludge consists of organic and inorganic compounds. Partial combustion, plasma decomposition, and other methods are used to neutralize the sewage sludge. The incineration of sewage sludge results in generation of solid-phase slag. In this paper the material structure and composition of a solid slag (formed during neutralization of sewage sludge) is considered. Also, the impact the ambient temperature on structure and composition of solid slag is analyzed.

The pH-dependent leaching behavior of slags from various stages of a copper smelting process: Environmental implications.

PubMed

Jarošíková, Alice; Ettler, Vojtěch; Mihaljevič, Martin; Kříbek, Bohdan; Mapani, Ben

2017-02-01

The leaching behaviors of primary copper (Cu) slags originating from Ausmelt, reverbatory, and converter furnaces operating under a single technological process were compared to a residual slag tailing obtained by slag re-processing via flotation and metal recovery. The EN 12457-2 leaching test, used for assessment of the hazardous properties, was followed by the CEN/TS 14997 pH-static leaching test (pH range 3-12). Both leaching experiments were coupled with a mineralogical investigation of the primary and secondary phases as well as geochemical modeling. Metals (Cd, Cu, Pb, Zn) exhibit the highest leaching at low pH. Under acidic conditions (pH 3-6), Ausmelt slag and slag tailing exhibited higher metal leaching compared to other slag types. Very low leaching of metals (far below EU limits for non-hazardous waste) was observed at natural pH (7.9-9.0) for all the studied slag samples. In contrast, relatively high leaching of As was observed over the entire pH range, especially for Ausmelt slag (exceeding the EU limit for hazardous waste by 1.7×). However, geochemical modeling and scanning electron microscopy indicated that formation of stable Ca-Cu-Pb arsenates and the binding of As to newly formed Fe (oxyhydr)oxides play an important role in efficient As immobilization at the slag-water interface. In contrast, no controls were predicted for Sb, whose leaching was almost pH-independent. Nevertheless Sb leached concentrations at natural pH were below EU limit for hazardous waste. Re-processing of primary Cu slags for metal recovery, and subsequent co-disposal of the resulting slag tailing with dolomite-rich mine tailing and local laterite is suitable for stabilizing the remaining contaminants (except Sb) and limiting their leaching into the environment. Copyright © 2016 Elsevier Ltd. All rights reserved.

Geophysical Investigation of Buried Slag at the Parrot Tailings Site, Butte, Montana

NASA Astrophysics Data System (ADS)

Ha, C. D. M.; Shepherd, K.; Mack, A.; Rutherford, B. S.; Speece, M. A.

2016-12-01

Butte, Montana, has served as an important mining district for more than 120 years. This area contains historic mine waste from decades of unregulated mining practices. In July 1881, the Parrot smelter in Butte started operations and was soon processing ore and producing copper. The Parrot smelter also had a concentrating plant that treated the ore prior to smelting. The Parrot smelter wastes (slag and tailings) were later covered with Berkeley Pit crushed quartz monzonite overburden. The slag is bricked because it was deposited hot and, as a consequence forms a laterally extensive, cohesive, hard body that is difficult to remove without blasting. With the mine waste being covered by unknown quantities of overburden and soil throughout the area, and core data being limited and expensive to retrieve, the only economical method of discovery is geophysics. Several geophysical techniques were used to determine the lateral boundaries and depth of the buried slag body. The geophysical methods used were seismic, gravity, electromagnetic induction, and magnetics. Not all of these geophysical surveys produced useful results due to the nature of the slag. For instance, electromagnetic induction could not distinguish between the slag and adjacent tailings; and, the microgravity profiles showed only a small gravitational field variation caused by the density contrast between slag and the surrounding tailings, sediment and granitic cover. On the other hand, the seismic surveys resulted in unexpected first arrival times that distinctly showed velocity variations due to the slag. In addition, the slag body produced a large magnetic response. Unpublished, proprietary well data allowed us to model the slag body from our magnetic data. This model was confirmed by projecting velocity tomograms, that we created using seismic diving waves, onto our magnetic models. Model results were combined to form a three-dimensional image of the slag body. These results will be used to help construct a remediation plan to remove the slag along with the associated tailings.

Computational Fluid Dynamic Modeling of Zinc Slag Fuming Process in Top-Submerged Lance Smelting Furnace

NASA Astrophysics Data System (ADS)

Huda, Nazmul; Naser, Jamal; Brooks, Geoffrey; Reuter, Markus A.; Matusewicz, Robert W.

2012-02-01

Slag fuming is a reductive treatment process for molten zinciferous slags for extracting zinc in the form of metal vapor by injecting or adding a reductant source such as pulverized coal or lump coal and natural gas. A computational fluid dynamic (CFD) model was developed to study the zinc slag fuming process from imperial smelting furnace (ISF) slag in a top-submerged lance furnace and to investigate the details of fluid flow, reaction kinetics, and heat transfer in the furnace. The model integrates combustion phenomena and chemical reactions with the heat, mass, and momentum interfacial interaction between the phases present in the system. A commercial CFD package AVL Fire 2009.2 (AVL, Graz, Austria) coupled with a number of user-defined subroutines in FORTRAN programming language were used to develop the model. The model is based on three-dimensional (3-D) Eulerian multiphase flow approach, and it predicts the velocity and temperature field of the molten slag bath, generated turbulence, and vortex and plume shape at the lance tip. The model also predicts the mass fractions of slag and gaseous components inside the furnace. The model predicted that the percent of ZnO in the slag bath decreases linearly with time and is consistent broadly with the experimental data. The zinc fuming rate from the slag bath predicted by the model was validated through macrostep validation process against the experimental study of Waladan et al. The model results predicted that the rate of ZnO reduction is controlled by the mass transfer of ZnO from the bulk slag to slag-gas interface and rate of gas-carbon reaction for the specified simulation time studied. Although the model is based on zinc slag fuming, the basic approach could be expanded or applied for the CFD analysis of analogous systems.

SiO2 and CaF2 Behavior During Shielded Metal Arc Welding and Their Effect on Slag Detachability of the CaO-CaF2-SiO2 Type ENiCrFe-7-Covered Electrode

NASA Astrophysics Data System (ADS)

Wang, Huang; Qin, Renyao; He, Guo

2016-09-01

The metallurgical behavior during shielded metal arc welding (SMAW) and the slag detachability of the CaO-CaF2-SiO2 type ENiCrFe-7-covered electrodes was investigated. The results indicated that the slag detachability could be improved as the SiO2 in the flux coatings decreased. When the SiO2 in the flux coating was 10.9 pct, about 28.3 pct CaF2 resulted in the best slag detachability. The CaF2 and SiO2 in the flux coating interacted during SMAW to form gaseous SiF4 to be evacuated. In the reactions, one SiO2 consumed two CaF2, leading to the reduction of the ratio of CaF2/SiO2. After comparing the slag compositions, the best slag detachability was obtained at CaO:CaF2:SiO2 = 1.7:1.8:1, but the worst slag detachability appeared at CaO:CaF2:SiO2 = 1.3:0.9:1. The XRD analysis revealed that the oxides and fluorides in the slags preferred to gather together to form cuspidine and other complex phases. If the CaF2 was dominant in the slags, they intended to form homogenous porous microstructures that were relatively strong and would most likely detach from the weld metal in blocks, exhibiting good slag detachability. If the cuspidine phase was dominant, the slags exhibited a `rock strata'-like microstructure in the intergranular area. Such microstructure was very fragile and could be broken into fine powders that were easily embedded in the weld ripples, leading to slag adhesions. This work provides the researcher with a wealth of information and data, which will also be beneficial to the welding material producers and users.

Numerical investigation of slag formation in an entrained-flow gasifier

NASA Astrophysics Data System (ADS)

Zageris, G.; Geza, V.; Jakovics, A.

2018-05-01

A CFD mathematical model for an entrained-flow gasifier is constructed – the model of an actual gasifier is rendered in 3D and appropriately meshed. Then, the turbulent gas flow in the gasifier is modeled with the realizable k-ε approach, taking devolatilization, combustion and coal gasification in account. Various such simulations are conducted, obtaining results for different air inlet positions and by tracking particles of varying sizes undergoing devolatilization and gasification. The model identifies potential problematic zones where most particles collide with the gasifier walls, indicating risk regions where ash deposits could most likely form. In conclusion, effects on the formation of an ash layer of air inlet positioning and particle size allowed in the main gasifier tank are discussed, and viable solutions such as radial inlet positioning for decreasing the amount of undesirable deposits are proposed. We also conclude that the particular chemical reactions that take place inside the gasifier play a significant role in determining how slagging occurs inside a gasifier.

Role of a gas phase in the kinetics of zinc and iron reduction with carbon from slag melts

NASA Astrophysics Data System (ADS)

Chumarev, V. M.; Selivanov, E. N.

2013-03-01

The influence of the mass transfer conditions in the gas phase having formed at the carbon-slag melt interface on CO regeneration is approximately estimated in the framework of a two-stage scheme of metal reduction from slag melts by carbon. The effect of zinc vapors on the combined reduction of iron and zinc from slags is considered. The influence of the slag composition and temperature on the critical concentration of zinc oxide above which no iron forms as an individual phase is explained.

Study of flame combustion of off-design binary coal blends in steam boilers

NASA Astrophysics Data System (ADS)

Kapustyanskii, A. A.

2017-07-01

Changes in the structure of the fuel consumption by the thermal power stations of Ukraine caused by failure in supplying anthracite from the Donets Basin are analyzed and the major tasks of maintaining the functioning of the coal industry are formulated. The possibility of using, in the near future, the flame combustion of off-design solid fuels in the power boilers of the thermal power plants and combined heat and power plants is studied. The article presents results of expert tests of the TPP-210A and TP-15 boilers under flame combustion of mixtures of anthracites, lean coal, and the coal from the RSA in various combinations. When combusting, such mixtures have higher values of the combustibles yield and the ash fusibility temperature. The existence of the synergetic effect in the flame combustion of binary coal blends with different degrees of metamorphism is discussed. A number of top-priority measures have been worked out that allow for switching over the boilers designed to be fired with anthracite to using blends of coals of different ranks. Zoned thermal analysis of the TP-15 boiler furnace was performed for numerical investigation of the temperature distribution between the furnace chamber zones and exploration of the possibility of the liquid slag disposal and the temperature conditions for realization of this process. A positive result was achieved by combusting anthracite culm (AC), the coal from the RSA, and their mixtures with lean coal within the entire range of the working loads of the boilers in question. The problems of normalization of the liquid slag flow were also successfully solved without closing the slag notch. The results obtained by balance experiments suggest that the characteristics of the flame combustion of a binary blend, i.e., the temperature conditions in the furnace, the support flame values, and the degree of the fuel burnout, are similar to the characteristics of the flame of the coal with a higher reactive capacity, which proves the existence of the synergetic effect in the processes of cocombustion of coals of various grades.

Evaluation of electric arc furnace-processed steel slag for dermal corrosion, irritation, and sensitization from dermal contact.

PubMed

Suh, Mina; Troese, Matthew J; Hall, Debra A; Yasso, Blair; Yzenas, John J; Proctor, Debora M

2014-12-01

Electric arc furnace (EAF) steel slag is alkaline (pH of ~11-12) and contains metals, most notably chromium and nickel, and thus has potential to cause dermal irritation and sensitization at sufficient dose. Dermal contact with EAF slag occurs in many occupational and environmental settings because it is used widely in construction and other industrial sectors for various applications including asphaltic paving, road bases, construction fill, and as feed for cement kilns construction. However, no published study has characterized the potential for dermal effects associated with EAF slag. To assess dermal irritation, corrosion and sensitizing potential of EAF slag, in vitro and in vivo dermal toxicity assays were conducted based on the Organisation for Economic Co-operation and Development (OECD) guidelines. In vitro dermal corrosion and irritation testing (OECD 431 and 439) of EAF slag was conducted using the reconstructed human epidermal (RHE) tissue model. In vivo dermal toxicity and delayed contact sensitization testing (OECD 404 and 406) were conducted in rabbits and guinea pigs, respectively. EAF slag was not corrosive and not irritating in any tests. The results of the delayed contact dermal sensitization test indicate that EAF slag is not a dermal sensitizer. These findings are supported by the observation that metals in EAF slag occur as oxides of low solubility with leachates that are well below toxicity characteristic leaching procedure (TCLP) limits. Based on these results and in accordance to the OECD guidelines, EAF slag is not considered a dermal sensitizer, corrosive or irritant. Copyright © 2014 John Wiley & Sons, Ltd.

Availability of arsenic, copper, lead, thallium, and zinc to various vegetables grown in slag-contaminated soils.

PubMed

Bunzl, K; Trautmannsheimer, M; Schramel, P; Reifenhäuser, W

2001-01-01

To anticipate a possible hazard resulting from the plant uptake of metals from slag-contaminated soils, it is useful to study whether vegetables exist that are able to mobilize a given metal in the slag to a larger proportion than in an uncontaminated control soil. For this purpose, we studied the soil to plant transfer of arsenic, copper, lead, thallium, and zinc by the vegetables bean (Phaseolus vulgaris L. 'dwarf bean Modus'), kohlrabi (Brassica oleracea var. gongylodes L.), mangold (Beta vulgaris var. macrorhiza ), lettuce (Lactuca sativa L. 'American gathering brown'), carrot (Daucus carota L. 'Rotin', 'Sperlings's'), and celery [Apium graveiolus var. dulce (Mill.) Pers.] from a control soil (Ap horizon of a Entisol) and from a contaminated soil (1:1 soil-slag mixtures). Two types of slags were used: an iron-rich residue from pyrite (FeS2) roasting and a residue from coal firing. The metal concentrations in the slags, soils, and plants were used to calculate for each metal and soil-slag mixture the plant-soil fractional concentration ratio (CRfractional,slag), that is, the concentration ratio of the metal that results only from the slag in the soil. With the exception of TI, the resulting values obtained for this quantity for As, Cu, Pb, and Zn and for all vegetables were significantly smaller than the corresponding plant-soil concentration ratios (CRcontrol soil) for the uncontaminated soil. The results demonstrate quantitatively that the ability of a plant to accumulate a given metal as observed for a control soil might not exist for a soil-slag mixture, and vice versa.

Advantages and risks of using steel slag in preparing composts from raw organic waste.

PubMed

Tu, Xuefei; Aneksampant, Apichaya; Kobayashi, Shizusa; Tanaka, Atsushi; Nishimoto, Ryo; Fukushima, Masami

2017-01-02

It had been reported that iron and manganese oxides in steel slag enhanced the production of humic acid (HA) from low-molecular-weight compounds, such as phenolic acids, amino acids, and saccharides. In the present study, this function of steel slag was applied to the composting of raw organic wastes (ROWs). The degree of humification of HAs is an important factor in evaluating compost quality. Thus, HAs were extracted from the prepared composts and the humification parameters were determined, in terms of elemental compositions, acidic functional group contents, molecular weights, spectroscopic parameters from UV-vis absorption and 13 C NMR spectra. The timing for adding steel slag affected the degree of humification of HAs in the composts. The weight average molecular weight of a HA when slag was added initially (29 kDa) was significantly higher than when slag was added after elevating the temperature of the compost pile (17-18 kDa). These results show that ROWs are decomposed to low-molecular-weight compounds after the pile temperature is elevated and the presence of slag enhances the polycondensation of these compounds to produce HAs with a higher degree of humification. Because the slag used in the present study contained several-tens ng g -1 to several μg g -1 of toxic elements (B, Cu, Cr, and Zn), leaching tests for these elements from the prepared composts were carried out. Levels for leaching boron from composts prepared by adding slag (0.2-0.4 mg L -1 ) were obviously higher than the corresponding levels without slag (0.05 mg L -1 ).

Study of Reaction Between Slag and Carbonaceous Materials

NASA Astrophysics Data System (ADS)

Maroufi, Samane; Mayyas, Mohannad; Mansuri, Irshad; O'Kane, Paul; Skidmore, Catherine; Jin, Zheshi; Fontana, Andrea; Sahajwalla, Veena

2017-10-01

The chemical interaction of a typical slag of EAF with three different carbon sources, coke, rubber-derived carbon (RDC), coke-RDC blend, was studied in atmospheric pressure at 1823 K (1550 °C). Using an IR-gas analyzer, off-gases evolved from the sample were monitored. While the coke-RDC blend exhibited the best reducing performance in reaction with molten slag, the RDC sample showed poor interaction with the molten slag. The gasification of the coke, RDC, and coke-RDC blend was also carried out under oxidizing conditions using a gas mixture of CO2 (4 wt pct) and Ar (96 wt pct) and it was shown that the RDC sample had the highest rate of gasification step C0 {\\longrightarrow}\\limits{{k3 }}{CO} + nCf (11.6 site/g s (×6.023 × 1023/2.24 × 104)). This may be attributed to its disordered structure confirmed by Raman spectra and its nano-particle morphology observed by FE-SEM. The high reactivity of RDC with CO2 provided evidence that the Boudouard reaction was fast during the interaction with molten slag. However, low reduction rate of iron oxide from slag with RDC can be attributed to the initial weak contact between RDC and molten slag implying that the contact between carbonaceous matter and slag plays significant roles in the reduction of iron oxide from slag.

Removal of hexavalent chromium in carbonic acid solution by oxidizing slag discharged from steelmaking process in electric arc furnace

NASA Astrophysics Data System (ADS)

Yokoyama, Seiji; Okazaki, Kohei; Sasano, Junji; Izaki, Masanobu

2014-02-01

Hexavalent chromium (Cr(VI)) is well-known to be a strong oxidizer, and is recognized as a carcinogen. Therefore, it is regulated for drinking water, soil, groundwater and sea by the environmental quality standards all over the world. In this study, it was attempted to remove Cr(VI) ion in a carbonic acid solution by the oxidizing slag that was discharged from the normal steelmaking process in an electric arc furnace. After the addition of the slag into the aqueous solution contained Cr(VI) ion, concentrations of Cr(VI) ion and total chromium (Cr(VI) + trivalent chromium (Cr(III)) ions decreased to lower detection limit of them. Therefore, the used slag could reduce Cr(VI) and fix Cr(III) ion on the slag. While Cr(VI) ion existed in the solution, iron did not dissolve from the slag. From the relation between predicted dissolution amount of iron(II) ion and amount of decrease in Cr(VI) ion, the Cr(VI) ion did not react with iron(II) ion dissolved from the slag. Therefore, Cr(VI) ion was removed by the reductive reaction between Cr(VI) ion and the iron(II) oxide (FeO) in the slag. This reaction progressed on the newly appeared surface of iron(II) oxide due to the dissolution of phase composed of calcium etc., which existed around iron(II) oxide grain in the slag.

Characterization and recovery of copper values from discarded slag.

PubMed

Das, Bisweswar; Mishra, Barada Kanta; Angadi, Shivakumar; Pradhan, Siddharth Kumar; Prakash, Sandur; Mohanty, Jayakrushna

2010-06-01

In any copper smelter large quantities of copper slag are discarded as waste material causing space and environmental problems. This discarded slag contains important amounts of metallic values such as copper and iron. The recovery of copper values from an Indian smelter slag that contains 1.53% Cu, 39.8% Fe and 34.65% SiO(2) was the focus of the present study. A complete investigation of the different phases present in the slag has been carried out by means of optical microscopy, Raman spectroscopy, scanning electron microscopy (SEM), and X-ray diffraction (XRD) techniques. It is observed that iron and silica are mostly associated with the fayalite phase whereas copper is present in both oxide and sulfide phases. These oxide and sulfide phases of copper are mostly present within the slag phase and to some extent the slag is also embedded inside the oxide and sulfide phases. The recovery of copper values from the discarded slag has been explored by applying a flotation technique using conventional sodium isopropyl xanthate (SIX) as the collector. The effects of flotation parameters such as pH and collector concentration are investigated. Under optimum flotation conditions, it is possible to achieve 21% Cu with more than 80% recovery.

Effect of electric arc furnace slag on growth and physiology of maize (Zea mays L.).

PubMed

Radić, Sandra; Crnojević, Helena; Sandev, Dubravka; Jelić, Sonja; Sedlar, Zorana; Glavaš, Katarina; Pevalek-Kozlina, Branka

2013-12-01

Basic slag, used in this study as a potential source of certain nutrients, is a byproduct of the production of steel in electric arc furnace (EAF). A pot experiment with two nutrient-poor substrates was conducted to investigate to compare the effect of EAF steel slag and fertilizers NPK + F e on growth and availability of specific nutrients to maize. Mineral content of both substrate and plant leaves, growth, chlorophyll fluorescence and photosynthetic pigments were measured following six weeks of cultivation. As steel slag also contains trace amounts of heavy metals, certain oxidative parameters (antioxidative enzyme activities and lipid peroxidation) were evaluated as well. The steel slag improved soil mineral composition, increased above ground maize biomass by providing Fe, Mn, Mg, K and partly P and improved photosynthetic parameters. The potential phytotoxicity of EAF slag containing substrates was not determined as evaluated by MDA (malondialdehyde), GR (glutathione reductase) and APX (ascorbate peroxidase) levels. The obtained results show that EAF steel slag is comparable to NPK + F e in supplying nutrients for maize growth, indicating the potential of EAF steel slag as an inexpensive and non-phytotoxic nutrient supplier especially in poor soils.

Fort Campbell Childers House: Historic Maintenance and Repair Manual

DTIC Science & Technology

2006-09-01

coal-tar pitch and surfaced with a layer of gravel or slag in a heavy coat of asphalt or coal-tar pitch or finished with a cap sheet; generally used...such as lead, tin, copper, terneplate, and zinc with appropriate chemical methods because their finishes can be easily abraded by blasting methods...tin, copper, terneplate, and zinc with grit blasting which will abrade the surface of the metal. • Using cleaning methods, which alter or damage

Coal combustion system

DOEpatents

Wilkes, Colin; Mongia, Hukam C.; Tramm, Peter C.

1988-01-01

In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

The effect of slag addition on strength development of Class C fly ash geopolymer concrete at normal temperature

NASA Astrophysics Data System (ADS)

Wardhono, Arie; Law, David W.; Sutikno, Dani, Hasan

2017-09-01

This paper presents the effect of slag addition on strength development and workability of fly ash/slag based geopolymer (FASLG) concrete cured at normal temperature. Class C fly ash with high ferrite (Fe) content was used as the primary material. The proportions of fly ash (FA) to slag (SL) are: 1 FA : 0 SL, 0.9 FA : 0.1 SL, 0.7 FA : 0.3 SL, and 0.5 FA : 0.5 SL. The workability and strength properties were determined by slump, vikat, and compressive strength tests. The result shows that the highest compressive strength was achieved by FASLG-3 concrete with 30% slag addition and exhibited a comparable strength to that normal concrete at 28 days. The 30% slag addition also improve the workability and increase the setting time of FASLG concrete specimens. It can be concluded that the slag inclusion on fly ash will improve the performance of geopolymer concrete at normal temperature.

Triple-activated blast furnace slag

DOE Office of Scientific and Technical Information (OSTI.GOV)

Clarke, W.J.

1995-12-31

The current shortage of portland cement in the world will require the use of Ground Granulated Blast Furnace Slag (GGBFS) to fill demands in many industrialized countries. Therefore, an extensive series of triple-activated slag experiments have been undertaken to optimize an economical combination of mechanical properties for alkali-activated slags. Na{sub 2}OSiO{sub 2} (N Grade), Ca(OH){sub 2}, H{sub 2}O and Na{sub 2}CO{sub 3} have been added as activators in 5 to 10, 0 to 5 and 0 to 5 weight percentages of water and slag in a mix with a water:cement ratio of 1:1. Silica Fume and Sika 10 superplasticizer havemore » been added as 1 and 10 weight percent of slag. Set times, initial hardening times and compressive strengths at percentages of the mix to identify more refined formulations. Finally, the resulting aggregate to develop a triple-activated slag formulation with the ultimate objective of contributing toward satisfying the world shortage of high performance concrete.« less

Growth promotion effect of steelmaking slag on Spirulina platensis

NASA Astrophysics Data System (ADS)

Nogami, R.; Tam, L. T.; Anh, H. T. L.; Quynh, H. T. H.; Thom, L. T.; Nhat, P. V.; Thu, N. T. H.; Hong, D. D.; Wakisaka, M.

2016-04-01

A growth promotion effect of steelmaking slag on Spirulina platensis M135 was investigated. The growth promotion effect was obtained that was 1.27 times greater than that obtained by the control by adding 500 mg L-1 of steelmaking slag and culturing for 60 days. The lipid content decreased in a concentration-dependent manner with steelmaking slag, whereas the carbohydrate content remained constant. The protein content of S. platensis M135 increased in a concentration-dependent manner with steelmaking slag when cultured at day 45. The superoxide dismutase activity of S. platensis M135 exhibited a decreasing trend in a time-dependent manner and an increasing trend in the control. The superoxide dismutase activity was lower than that of the control at day 1 but was higher at day 30. No genetic damage was observed up to 500 mg L-1 of steelmaking slag at 30 days of culture. Recovery from genetic damage was observed at 1,000 mg L-1 of steelmaking slag but not at higher concentrations.

Reuse of EAF Slag as Reinforcing Filler for Polypropylene Matrix Composites

NASA Astrophysics Data System (ADS)

Cornacchia, G.; Agnelli, S.; Gelfi, M.; Ramorino, G.; Roberti, R.

2015-06-01

Electric-arc furnace (EAF) slag, the by-product of steel fabricated at the EAF, is in most cases still sent to dumps, with serious environmental consequences. This work shows an innovative, economically convenient application for EAF slag: its use as reinforcing filler for polypropylene. Composites based on polypropylene containing 10-40 wt.% of EAF slag particles were prepared by melt compounding followed by injection molding. A physical-chemical analysis of the EAF slag was performed to determine microstructural features and main component phases. Leaching tests demonstrated that, although EAF slag can release small amounts of toxic elements, such as heavy metals, incorporating such material into the polymeric matrix immobilizes the heavy metals inside that matrix. The mechanical characterization of the polymer-based composites was performed. Incorporating EAF slag particles raises the Young's modulus and the tensile strength at yield, whereas elongation at break and the impact strength of the polymer-based composite are significantly reduced only when large amounts of filler are added, i.e., 30% or more.

Research on the compressive strength of basic magnesium salts and cyanide slag solidified body

NASA Astrophysics Data System (ADS)

Tu, Yubo; Han, Peiwei; Ye, Shufeng; Wei, Lianqi; Zhang, Xiaomeng; Fu, Guoyan; Yu, Bo

2018-02-01

The solidification of cyanide slag by using basic magnesium salts could reduce pollution and protect the environment. Experiments were carried out to investigate the effects of age, mixing amount of cyanide slag, water cement ratio and molar ratio of MgO to MgSO4 on the compressive strength of basic magnesium salts and cyanide slag solidified body in the present paper. It was found that compressive strength of solidified body increased with the increase of age, and decreased with the increase of mixing amount of cyanide slag and water cement ratio. The molar ratio of MgO to MgSO4 should be controlled in the range from 9 to 11 when the mixing amount of cyanide slag was larger than 80 mass%.

Mineralogical Characterization of Copper Slag from Tongling Nonferrous Metals Group China

NASA Astrophysics Data System (ADS)

Chun, Tiejun; Ning, Chao; Long, Hongming; Li, Jiaxin; Yang, Jialong

2016-09-01

In this paper, the mineralogical characterization of typical copper slag supplied by the Tongling Nonferrous Metals Group China was performed based on x-ray fluorescence, x-ray diffraction, and scanning electron microscopy with energy dispersive spectroscopy. The results show that the dominant phases of the slag are fayalite, glassy substance and magnetite. The minor accessory phases consist of copper matte, metallic copper and other complex lead and zinc minerals. The contents of iron, copper, lead and zinc in copper slag are 40.21%, 0.79%, 0.24%, and 2.80%, respectively. The mineralogy of copper slag indicates that these valuable elements are difficult to recover by beneficiation processes due to the complicated occurrences. Instead, the pyro-metallurgical processes appear promising in recovering the valuable metals from copper slag.

Evaluation of copper slag blast media for railcar maintenance

NASA Technical Reports Server (NTRS)

Sagers, N. W.; Finlayson, Mack H.

1989-01-01

Copper slag was tested as a blasting substitute for zirconium silicate which is used to remove paint from railroad cars. The copper slag tested is less costly, strips paint faster, is produced near the point of need, provides a good bonding surface for paint, and permits the operator to work in a more comfortable position, i.e., standing nearly erect instead of having to crouch. Outdoor blasting with the tested Blackhawk (20 to 40 mesh) copper slag is also environmentally acceptable to the State of Utah. Results of tests for the surface erosion rate with copper slag blasting are included.

Mineralogical and geochemical controls on the release of trace elements from slag produced by base- and precious-metal smelting at abandoned mine sites

USGS Publications Warehouse

Piatak, N.M.; Seal, R.R.; Hammarstrom, J.M.

2004-01-01

Slag collected from smelter sites associated with historic base-metal mines contains elevated concentrations of trace elements such as Cu, Zn and Pb. Weathering of slag piles, many of which were deposited along stream banks, potentially may release these trace elements into the environment. Slags were sampled from the Ely and Elizabeth mines in the Vermont copper belt, from the copper Basin mining district at Ducktown, Tennessee and from the Clayton silver mine in the Bayhorse mining district, Idaho, in the USA. Primary phases in the slags include: olivine-group minerals, glass, spinels, sulfide minerals and native metals for Vermont samples; glass, sulfide minerals and native metals for the Ducktown sample; and olivine-group minerals, clinopyroxenes, spinels, sulfide minerals, native metals and other unidentified metallic compounds for Clayton slag. Olivine-group minerals and pyroxenes are dominantly fayalitic and hedenbergitic in composition, respectively and contain up to 1.25 wt.% ZnO. Spinel minerals range between magnetite and hercynite in composition and contain Zn (up to 2.07 wt.% ZnO), Ti (up to 4.25 wt.% TiO2) and Cr (up to 1.39 wt.% Cr2O3). Cobalt, Ni, Cu, As, Ag, Sb and Pb occur in the glass phase, sulfides, metallic phases and unidentified metallic compounds. Bulk slag trace-element chemistry shows that the metals of the Vermont and Tennessee slags are dominated by Cu (1900-13,500 mg/kg) and Zn (2310-10,200 mg/kg), whereas the Clayton slag is dominated by Pb (63,000 mg/kg), Zn (19,700 mg/kg), Cu (7550 mg/kg), As (555 mg/kg), Sn (363 mg/kg) and Ag (200 mg/kg). Laboratory-based leach tests indicate metals can be released under simulated natural conditions. Leachates from most slags were found to contain elevated concentrations of Cu and Zn (up to 1800 and 470 ??g/l, respectively), well in excess of the acute toxicity guidelines for aquatic life. For the Idaho slag, the concentration of Pb in the leachate (11,000 ??g/l) is also in excess of the acute toxicity guideline. Geochemical modeling of the leachate chemistry suggests that leachates from the Vermont, Tennessee and Clayton slags are saturated with amorphous silica and Al hydroxide. Therefore, the dissolution of silicate and oxide phases, the oxidation of sulfide phases, as well as the precipitation of secondary phases may control the composition of leachate from slags. The presence of secondary minerals on slag deposits in the field is evidence that these materials are reactive. The petrographic data and results of leaching tests from this study indicate slag may be a source of potentially toxic metals at abandoned mine sites.

Off-design performance analysis of MHD generator channels

NASA Technical Reports Server (NTRS)

Wilson, D. R.; Williams, T. S.

1980-01-01

A computer code for performing parametric design point calculations, and evaluating the off-design performance of MHD generators has been developed. The program is capable of analyzing Faraday, Hall, and DCW channels, including the effect of electrical shorting in the gas boundary layers and coal slag layers. Direct integration of the electrode voltage drops is included. The program can be run in either the design or off-design mode. Details of the computer code, together with results of a study of the design and off-design performance of the proposed ETF MHD generator are presented. Design point variations of pre-heat and stoichiometry were analyzed. The off-design study included variations in mass flow rate and oxygen enrichment.

Exchangeable Sodium Percentage decrease in saline sodic soil after Basic Oxygen Furnace Slag application in a lysimeter trial.

PubMed

Pistocchi, Chiara; Ragaglini, Giorgio; Colla, Valentina; Branca, Teresa Annunziata; Tozzini, Cristiano; Romaniello, Lea

2017-12-01

The Basic Oxygen Furnace Slag results from the conversion of hot metal into steel. Some properties of this slag, such as the high pH or calcium and magnesium content, makes it suitable for agricultural use as a soil amendment. Slag application to agricultural soils is allowed in some European countries, but to date there is no common regulation in the European Union. In Italy soils in coastal areas are often affected by excess sodium, which has several detrimental effects on the soil structure and crop production. In this study, carried out within an European project, the ability of the Basic Oxygen Furnace Slag to decrease the soil Exchangeable Sodium Percentage of a sodic soil was evaluated. A three-year lysimeter trial with wheat and tomato crops was carried out to assess the effects of two slag doses (D1, 3.5 g kg -1 year -1 and D, 2, 7 g kg -1 year -1 ) on exchangeable cations in comparison with unamended soil. In addition, the accumulation in the topsoil of vanadium and chromium, the two main trace metals present in the Basic Oxygen Furnace Slag, was assessed. After two years, the soil Exchangeable Sodium Percentage was reduced by 40% in D1 and 45% in D2 compared to the control. A concomitant increase in exchangeable bivalent cations (Ca ++ and Mg ++ ) was observed. We concluded that bivalent cations supplied with the slag competed with sodium for the sorption sites in the soil. The slag treatments also had a positive effect on tomato yields, which were higher than the control. Conversely the wheat yield was lower in the slag-amended soil, possibly because of the toxicity of vanadium added with the slag. This study showed that Basic Oxygen Furnace Slag decreased the Exchangeable Sodium Percentage, but precautions are needed to avoid the build up of toxic concentrations of trace metals in the soil, especially vanadium. Copyright © 2017 Elsevier Ltd. All rights reserved.

Visualisation and quantification of heavy metal accessibility in smelter slags: The influence of morphology on availability.

PubMed

Morrison, Anthony L; Swierczek, Zofia; Gulson, Brian L

2016-03-01

The Imperial Smelting Furnace (ISF) for producing lead and zinc simultaneously has operated on four continents and in eleven countries from the 1950's. One of the process changes that the ISF introduced was the production of a finely granulated slag waste. Although this slag contained significant amounts of residual lead (Pb) and zinc (Zn), because of its glassy nature it was considered environmentally benign. From the Cockle Creek smelter near Boolaroo at the northern end of Lake Macquarie, NSW, Australia, it is estimated that around 2.1 million tonnes of the fine slag was distributed into the community and most remains where it was originally utilised. Residual tonnages of slag of this magnitude are common worldwide wherever the ISF operated. Studies of base metal smelting slags have concluded that mineralogical and morphological characteristics of the slag play a critical role in moderating environmental release of toxic elements. Scanning electron microscopy (SEM) and microanalysis of the ISF slags has shown that the Pb and associated elements are present as discrete nodules (∼6-22 μm) in the slag and that they are not associated with Zn which is contained in the glass slag phase. Using an automated SEM and analysis technique (QEMSCAN(®)) to "map" the mineralogical structure of the particles, it was possible to quantitatively determine the degree of access infiltrating fluids might have to the reaction surface of the Pb phases. The level of access decreases with increasing particle size, but in even the largest sized particles (-3350 + 2000 μm) nearly 80% of the Pb-containing phases were totally or partially accessible. These results provide evidence that the toxic elements in the slags are not contained by the glassy phase and will be vulnerable to leaching over time depending on their individual phase reactivity. Copyright © 2015 Elsevier Ltd. All rights reserved.

Molybdate adsorption from steel slag eluates by subsoils.

PubMed

Matern, K; Rennert, T; Mansfeldt, T

2013-11-01

Steel slags are industrial by-products which are generated in large amounts worldwide, e.g. 150-230×10(6) Mg in 2012, and which are partly used for construction. Molybdenum (Mo) can be added during steel processing in order to harden the steel. The objective of this study was to evaluate the adsorption behaviour of molybdate (MoO4(2-)) from slag eluates in subsoils. Molybdate batch adsorption experiments were carried out with eluates obtained from two different kinds of steel slags (i) LD slag (Linz-Donawitz operation, LDS) and (ii) electric arc furnace slag (EAF) to assess the risk that may arise from the contamination of groundwater by the leaching of molybdate. Six different subsoils were chosen in order to provide a wide range of chemical properties (pH 4.0-7.6; dithionite-extractable Fe 0.73-14.7 g kg(-1)). Molybdate adsorption experiments were carried out at the pH of the steel slag eluates (pH 11-12) as well as at pH values adjusted to the soil pH. The data were evaluated with the Freundlich equation. Molybdate adsorption exhibited a maximum near pH 4 for steel slag eluates adjusted to the soil pH, and decreased rapidly with increasing pH until adsorption was virtually zero at pH>11. Adsorption was greater for soils with high amounts of dithionite-extractable Fe oxides. The extent and behaviour of molybdate adsorption from both eluates was similar. After a reaction time of 24h, the pH of the EAF slag eluate was lower than that of the LD steel slag eluate, which was caused by different acid buffer capacities. Some soils were able to decrease the pH of the EAF slag eluates by about 4 pH units, enhancing the adsorption of molybdate. Transport simulations indicated that molybdate discharge is low in acidic soils. Copyright © 2013 Elsevier Ltd. All rights reserved.

Observation of surface layering in a nonmetallic liquid

NASA Astrophysics Data System (ADS)

Mo, Haiding; Evmenenko, Guennadi; Kewalramani, Sumit; Kim, Kyungil; Dutta, Pulak; Ehrlich, Steven

2006-03-01

Non-monotonic density profiles (layers) have previously been observed at the free surfaces of many metallic liquids, but not in isotropic dielectric liquids. Whether the presence of an electron gas is necessary for surface layering has been the subject of debate. Until recently, MD simulations have suggested that layering at free liquid interface may be a generic phenomenon and is not limited to the metallic liquids^1. The theories predict that if normal liquids can be cooled down to temperatures low enough, layering structure should be observed experimentally. However, this is difficult for most molecular liquids because these liquids freeze well above the temperature necessary for observing the layering structure. By studying the surface structure of liquid TEHOS (tetrakis(2-ethylhexoxy)silane), which combines relatively low freezing point and high boiling point compared to that of most molecular liquids, we have observed the evidence of layering at the free interface of liquid TEHOS using x-ray reflectivity. When cooled to T/Tc 0.25 (well above the bulk freezing point, Tc is the critical temperature of TEHOS), the surface roughness drops sharply and density oscillations appear near the surface. Lateral ordering of the surface layers is liquid-like, just as at liquid metal surfaces. 1. E. Chac'on and P. Tarazona, Phys. Rev. Lett. 91 166103-1 (2003)

Integrated coal cleaning, liquefaction, and gasification process

DOEpatents

Chervenak, Michael C.

1980-01-01

Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

Basic Oxygen Furnace steel slag aggregates for phosphorus treatment. Evaluation of its potential use as a substrate in constructed wetlands.

PubMed

Blanco, Ivan; Molle, Pascal; Sáenz de Miera, Luis E; Ansola, Gemma

2016-02-01

Basic Oxygen Furnace (BOF) steel slag aggregates from NW Spain were tested in batch and column experiments to evaluate its potential use as a substrate in constructed wetlands (CWs). The objectives of this study were to identify the main P removal mechanisms of BOF steel slag and determine its P removal capacity. Also, the results were used to discuss the suitability of this material as a substrate to be used in CWs. Batch experiments with BOF slag aggregates and increasing initial phosphate concentrations showed phosphate removal efficiencies between 84 and 99% and phosphate removal capacities from 0.12 to 8.78 mg P/g slag. A continuous flow column experiment filled with BOF slag aggregates receiving an influent synthetic solution of 15 mg P/L during 213 days showed a removal efficiency greater than 99% and a phosphate removal capacity of 3.1 mg P/g slag. In both experiments the main P removal mechanism was found to be calcium phosphate precipitation which depends on Ca(2+) and OH(-) release from the BOF steel slag after dissolution of Ca(OH)2 in water. P saturation of slag was reached within the upper sections of the column which showed phosphate removal capacities between 1.7 and 2.5 mg P/g slag. Once Ca(OH)2 was completely dissolved in these column sections, removal efficiencies declined gradually from 99% until reaching stable outlet concentrations with P removal efficiencies around 7% which depended on influent Ca(2+) for limited continuous calcium phosphate precipitation. Copyright © 2015 Elsevier Ltd. All rights reserved.

Refining of metallurgical-grade silicon

NASA Technical Reports Server (NTRS)

Dietl, J.

1986-01-01

A basic requirement of large scale solar cell fabrication is to provide low cost base material. Unconventional refining of metallurical grade silicon represents one of the most promising ways of silicon meltstock processing. The refining concept is based on an optimized combination of metallurgical treatments. Commercially available crude silicon, in this sequence, requires a first pyrometallurgical step by slagging, or, alternatively, solvent extraction by aluminum. After grinding and leaching, high purity qualtiy is gained as an advanced stage of refinement. To reach solar grade quality a final pyrometallurgical step is needed: liquid-gas extraction.

Chemsheet as a Simulation Platform for Pyrometallurgical Processes

NASA Astrophysics Data System (ADS)

Penttilä, Karri; Salminen, Justin; Tripathi, Nagendra; Koukkari, Pertti

ChemSheet is a thermodynamic multi-phase multi-component simulation software, which is used as an Add-in in Microsoft Excel. In ChemSheet, the unique Constrained Gibbs free energy method can be used to include dynamic constraints and reaction rates of kinetically slow reactions, yet retaining full consistency of the multiphase thermodynamic model. With appropriate data, ChemSheet models can be used to simulate reactors and processes in all fields of thermochemistry. The presentation will cover off-line modeling of Cu-flash smelters and advanced thermochemical simulation coupled with on-line process control of Cu-Ni smelting. The presentation will describe an off-line model of Cu-smelter based on critically assessed properties of the Al-Ca-Cu-Fe-O-S-Si -system (slag, matte and liquid metal) by using the quasichemical model. A four-stage reactor model (shaft, settler, uptake and bath) is used for optimizing process parameters and feed particle distribution. As a second example, an advanced thermochemical model of a Ni-Cu sulphide smelting plant will be given. The on-line model covers the operation of treating Ni-Cu-S concentrate via roasters, electric furnace and converters, producing a high grade Bessemer matte product for further refining. The model integrates the thermochemistry of the roasters and electric furnace, and predicts important process parameters such as degree of sulphur elimination in the fluid-bed roasters, matte grade, iron metallization, slag losses and the iron to silica ratio in the electric furnace slag. Both models can be used to assist process engineers and operators in calculating the addition rates of coke, flux and air for different feed scenarios.

Characterization and Recovery of Valuables from Waste Copper Smelting Slag

NASA Astrophysics Data System (ADS)

Prince, Sarfo; Young, Jamie; Ma, Guojun; Young, Courtney

Silicate slags produced from smelting copper concentrates contains valuables such as Cu and Fe as well as heavy metals such as Pb and As which are considered hazardous. In this paper, various slags were characterized with several techniques: SEM-MLA, XRD, TG-DTA and ICP-MS. A recovery process was developed to separate the valuables from the silicates thereby producing value-added products and simultaneously reducing environmental concerns. Results show that the major phases in air-cooled slag are fayalite and magnetite whereas the water-cooled slag is amorphous. Thermodynamic calculations and carbothermal reduction experiments indicate that most of Cu and Fe can be recovered from both types using minor amounts of lime and alumina and treating at 1350°C (1623K) or higher for 30 min. The secondary slag can be recycled to the glass and/or ceramic industries.

Mechanism of Selenium Loss in Copper Slag

NASA Astrophysics Data System (ADS)

Desai, Bhavin; Tathavadkar, Vilas; Basu, Somnath

2018-03-01

During smelting of copper sulfide concentrate, selenium is distributed between silica-saturated iron-silicate slag and copper-iron sulfide matte. The recovery coefficients of selenium between slag and matte were determined as a function of the initial concentration of selenium at 1523 K (1250 °C) under an inert atmosphere in a vertical tubular furnace. The initial concentration of selenium was varied by the addition of metallic selenium as well as selenium dioxide to the mixture of slag and matte. Analysis of the results indicated high affinity of selenium for matte. The apparent loss of selenium with the slag was attributed to the presence of selenium-enriched matte particles entrapped in the slag, rather than dissolved SeO2. The mechanisms proposed by previous investigators were discussed and also compared with the results of the present investigation.

Mechanism of Selenium Loss in Copper Slag

NASA Astrophysics Data System (ADS)

Desai, Bhavin; Tathavadkar, Vilas; Basu, Somnath

2018-06-01

During smelting of copper sulfide concentrate, selenium is distributed between silica-saturated iron-silicate slag and copper-iron sulfide matte. The recovery coefficients of selenium between slag and matte were determined as a function of the initial concentration of selenium at 1523 K (1250 °C) under an inert atmosphere in a vertical tubular furnace. The initial concentration of selenium was varied by the addition of metallic selenium as well as selenium dioxide to the mixture of slag and matte. Analysis of the results indicated high affinity of selenium for matte. The apparent loss of selenium with the slag was attributed to the presence of selenium-enriched matte particles entrapped in the slag, rather than dissolved SeO2. The mechanisms proposed by previous investigators were discussed and also compared with the results of the present investigation.

Crystallization of Synthetic Blast Furnace Slags Pertaining to Heat Recovery

NASA Astrophysics Data System (ADS)

Esfahani, Shaghayegh

Heat recovery from blast furnace slags is often contradicted by another requirement, to generate amorphous slag for its use in cement production. As both the rate and extent of heat recovery and slag structure are determined by its cooling rate, a relation between the crystallization kinetics and the cooling conditions is highly desired. In this study, CaO-SiO2-Al2O3-MgO (CSAM) slags with different basicities were studied by Single Hot Thermocouple Technique (SHTT) during isothermal treatment and non-isothermal cooling. Their time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams were plotted and compared with each other. Furthermore, kinetic parameters such as the Avrami exponent (n), rate coefficient (K) and effective activation energy of crystallization (EA) were found by analysis of data obtained from in-situ observation of glassy to crystalline transformation and image analysis. Also, the dependence of nucleation and growth rates of crystalline phases were quantified as a function of time, temperature, and slag basicity. Together with the observations of crystallization front, they facilitated establishing the dominant mechanisms of crystallization. In addition to the experimental work, a mathematical model was developed and validated that predicts the amount of crystallization during cooling. A second mathematical model that calculates temperature history of slag during its cooling was coupled with the above model, to allow studying the effect of parameters such as the slag/air ratio and granule size on the heat recovery and glass content of slag.

Suitability of adsorption isotherms for predicting the retention capacity of active slag filters removing phosphorus from wastewater.

PubMed

Pratt, C; Shilton, A

2009-01-01

Active slag filters are an emerging technology for removing phosphorus (P) from wastewater. A number of researchers have suggested that adsorption isotherms are a useful tool for predicting P retention capacity. However, to date the appropriateness of using isotherms for slag filter design remains unverified due to the absence of benchmark data from a full-scale, field filter operated to exhaustion. This investigation compared the isotherm-predicted P retention capacity of a melter slag with the P adsorption capacity determined from a full-scale, melter slag filter which had reached exhaustion after five years of successfully removing P from waste stabilization pond effluent. Results from the standard laboratory batch test showed that P adsorption correlated more strongly with the Freundlich Isotherm (R(2)=0.97, P<0.01) than the Langmuir Isotherm, a similar finding to previous studies. However, at a P concentration of 10 mg/L, typical of domestic effluent, the Freundlich equation predicted a retention capacity of 0.014 gP/kg slag; markedly lower than the 1.23 gP/kg slag adsorbed by the field filter. Clearly, the result generated by the isotherm bears no resemblance to actual field capacity. Scanning electron microscopy analysis revealed porous, reactive secondary minerals on the slag granule surfaces from the field filter which were likely created by weathering. This slow weathering effect, which generates substantial new adsorption sites, is not accounted for by adsorption isotherms rendering them ineffective in slag filter design.

Activity coefficients of NiO and CoO in CaO-Al2O3-SiO2 slag and their application to the recycling of Ni-Co-Fe-based end-of-life superalloys via remelting

NASA Astrophysics Data System (ADS)

Lu, Xin; Miki, Takahiro; Nagasaka, Tetsuya

2017-01-01

To design optimal pyrometallurgical processes for nickel and cobalt recycling, and more particularly for the end-of-life process of Ni-Co-Fe-based end-of-life (EoL) superalloys, knowledge of their activity coefficients in slags is essential. In this study, the activity coefficients of NiO and CoO in CaO-Al2O3-SiO2 slag, a candidate slag used for the EoL superalloy remelting process, were measured using gas/slag/metal equilibrium experiments. These activity coefficients were then used to consider the recycling efficiency of nickel and cobalt by remelting EoL superalloys using CaO-Al2O3-SiO2 slag. The activity coefficients of NiO and CoO in CaO-Al2O3-SiO2 slag both show a positive deviation from Raoult's law, with values that vary from 1 to 5 depending on the change in basicity. The activity coefficients of NiO and CoO peak in the slag with a composition near B = (%CaO)/(%SiO2) = 1, where B is the basicity. We observed that controlling the slag composition at approximately B = 1 effectively reduces the cobalt and nickel oxidation losses and promotes the oxidation removal of iron during the remelting process of EoL superalloys.

Preliminary findings of chemistry and bioaccessibility in base metal smelter slags.

PubMed

Morrison, Anthony L; Gulson, Brian L

2007-08-15

Leaching of toxic metals from slag waste produced during smelting of Pb-Zn ores is generally considered to be negligible. A 1.4 million tonne stockpile of slag containing up to 2.5% Pb and other contaminants has accumulated on a smelter site at North Lake Macquarie, New South Wales, Australia, and it has also been freely used within the community for landscaping and drainage projects. It had been suggested that Pb in fine particles derived from the slags may be a potential contributor to the blood Pb of some children in this community, although there is conflicting evidence in the literature for such a hypothesis. Bioaccessibility of lead and selected metals derived from nine slag samples collected from areas of public open space was examined using a relatively simple in vitro gastric dissolution technique. Size analyses of the slag samples demonstrate that finely-sized material was present in the slags which could be ingested, especially by children. The finer-sized particles contain high levels of Pb (6,490-41,400 ppm), along with Cd and As. Pb bioaccessibility of the slags was high, averaging 45% for -250 microm material and 75% for particles in the size range -53+32 microm. Increasing bioaccessibility and Pb concentration showed an inverse relationship to particle size. Almost 100% of Pb would be bioaccessible in the smallest slag particles (<20 microm), which also contained very high Pb levels ranging from 50,000 to 80,000 ppm and thus constitute a potential health hazard for children.

Evolution of Oxide Inclusions in Si-Mn Killed Steels During Hot-Rolling Process

NASA Astrophysics Data System (ADS)

Yang, Wen; Guo, Changbo; Zhang, Lifeng; Ling, Haitao; Li, Chao

2017-10-01

The evolution of oxide inclusions in Si-Mn killed steels refined by slags of different basicity during a four-pass industrial hot-rolling process was investigated using an automated microscopy system. High-basicity refining slag induced the formation of CaO- and Al2O3-containing inclusions, while refining slag with 0.8 basicity induced dominant inclusions of SiO2 and MnO-SiO2. CaO-SiO2-Al2O3 inclusions mainly formed endogenously during solidification and cooling of Ca-containing steels, where Ca originated from slag-steel reactions. However, the larger-sized higher-CaO inclusions originated from slag entrainment. Different inclusions presented different hot-rolling behaviors. The inclusion composition changed by deformation and new phase formation. The dominant oxide types were unchanged under refinement by low-basicity slag; however, they changed under refinement with high-basicity slag. The deformation index of inclusions decreased with increasing accumulated reduction (AR) of the steel. The difference in deformation index between different inclusion types was the largest in the first rolling stage and decreased in subsequent stages. SiO2-CaO and SiO2-MnO-CaO inclusions had larger deformation indices during hot rolling but smaller indices in the last two stages. High-basicity slag increased inclusion complexity; from the perspective of cold-drawing performance, low-basicity refining slag is better for the industrial production of tire-cord steels.

An accidental geophysical discovery of an Iron Age archaeological site on the western shore of Lake Baikal

NASA Astrophysics Data System (ADS)

Kozhevnikov, Nikolai O.; Kharinsky, Arthur V.; Kozhevnikov, Oleg K.

2001-06-01

Slowly decaying transients were measured during a TEM survey over crystalline metamorphic rocks in the vicinity of the village of Chernorud, on the western shore of Lake Baikal. Once converted to apparent resistivities, these transients resulted in values of about 2-5 Ω m. Because neither in-field nor laboratory DC resistivity measurements indicate conductive rocks, the TEM results are confusing. It is hypothesized that the anomalous transients were caused by the relaxation of the magnetization of extremely fine ferri- and/or ferromagnetic particles concentrated in the near-surface layer. In 1997, in the soil thrown out of a gopher burrow, slags and charcoal fragments were found which suggested ancient metallurgical activity. Despite the slags being electrically poorly conductive, once placed into a small coil, they produced slowly decaying transients caused by magnetic viscosity effects. On the basis of their chemical and mineral composition, the Chernorud site slags proved to be identical to those which are known to have been formed during the production of iron in ancient bloomery furnaces. An excavation carried out at the site of the gopher burrow resulted in the discovery of a large bloomery furnace, much slag, charcoal, and baked clay fragments. In 1999, reconnaissance magnetic field and galvanic resistivity profiling measurements were conducted, focused on the site's archaeological potential. Data were taken over a 96×100 m area at 4 m intervals along parallel profiles spaced at 4 m. The magnetic field contour and surface maps exhibited an isometrically shaped positive anomaly with an amplitude of 40-50 nT, that was 30-40 m in diameter. The bloomery and other archaeometallurgical structures fall within the central part of the magnetic anomaly. The galvanic profiling has revealed a resistivity high (1000-1500 Ω m against 300-500 Ω m) which might be attributed to ancient human activity. Radiocarbon dating of three charcoal fragments sampled during the excavation from different depth intervals has given uncalibrated ages of 1915±35, 2050±35 and 2180±30 years BP. These results make it apparent that the Iron Age on the western shore of Lake Baikal started about 700-900 years earlier than is generally accepted. Occurrence of slags over an area of no less than 15 ha suggests that iron production in the Barun-Khal valley was performed on a large scale.

Constant voltage electro-slag remelting control

DOEpatents

Schlienger, Max E.

1996-01-01

A system for controlling electrode gap in an electro-slag remelt furnace has a constant regulated voltage and an eletrode which is fed into the slag pool at a constant rate. The impedance of the circuit through the slag pool is directly proportional to the gap distance. Because of the constant voltage, the system current changes are inversely proportional to changes in gap. This negative feedback causes the gap to remain stable.

Evaluation of Alternative Causes of Widespread, Low Concentration Perchlorate Impacts to Groundwater

DTIC Science & Technology

2008-07-01

they self-extinguished. 4. After burning ceased, the residue and remaining slag were collected. 5. The slag was weighed in order to approximate...aluminum sheets were washed thoroughly with triple distilled, deionized water. 7. The washings and slag from each flare were placed in separate round... slag containing elevated perchlorate concentrations remained in all cases. If we assume that approximately 30,000,000 American flares are sold

Effect of Silicate Slag Application on Wheat Grown Under Two Nitrogen Rates

PubMed Central

White, Brandon; Tubana, Brenda S.; Babu, Tapasya; Mascagni, Henry; Agostinho, Flavia; Datnoff, Lawrence E.; Harrison, Steve

2017-01-01

Field studies were established on the alluvial floodplain soils in Louisiana, from 2013 to 2015, to evaluate the effect of silicate slag applications on productivity of wheat (Triticum aestivum), under sufficient and high nitrogen (N) application rates. Treatments were arranged in a randomized complete block design, with four replications consisting of twelve treatments: a factorial combination of two N (101 and 145 kg N ha−1) and five silicate slag rates (0, 1, 2, 4.5, and 9 Mg ha−1), and two control plots (with and without lime). Nitrogen had a greater impact on wheat productivity than silicate slag application. Wheat grain yield reached over 7000 kg ha−1 with applications of 145 kg N, and 9 Mg silicate slag per ha for soil having Si level <20 mg kg−1. Yield increases due to N or Si were attributed to the increase in number of spike m−2 and grain number spike−1. Silicate slag application effectively raised soil pH, and availability of several plant-essential nutrients, including plant-available N (nitrate, NO3−), demonstrating the benefits of slag application are beyond increasing plant-available Si. The benefits of silicate slag application were clearly observed in wheat supplied with high N, and on soil with low plant-available Si. PMID:29019922

Synthesis of inorganic polymers using fly ash and primary lead slag.

PubMed

Onisei, S; Pontikes, Y; Van Gerven, T; Angelopoulos, G N; Velea, T; Predica, V; Moldovan, P

2012-02-29

The present work reports on the synthesis and properties of inorganic polymers ("geopolymers") made of 100% fly ash from lignite's combustion, 100% primary lead slag and mixtures of the two. In the inorganic polymers with both fly ash and lead slag the main crystalline phases detected are wüstite, magnetite, sodium zinc silicate, quartz, anorthite, and gehlenite; litharge partially dissolves. FTIR analysis in these samples revealed that the main peaks and bands of end members also exist, along with a new amorphous reaction product. In terms of microstructure, both fly ash and lead slag dissolve and contribute in the binding phase whereas the larger particles act as aggregates. For an increasing lead slag in the composition, the binding phase is changing in chemistry and reaches PbO values higher than 50 wt.% for the 100% lead slag inorganic polymer. Regarding the properties of fly ash and lead slag inorganic polymers, compressive strength is higher than 35 MPa in all cases and water absorption diminishes as the lead slag content increases. A comparison of leaching results before and after polymerisation reveals that pH is an important factor as Pb is immobilised in the binding phase, unlike Zn and As. Copyright © 2011 Elsevier B.V. All rights reserved.

Changes of toxic metals during biological stabilization and their potential ecological risk assessment.

PubMed

Wang, Hou-cheng; Zeng, Zheng-zhong; Zhang, He-fei; Nan, Zhong-ren

2015-01-01

With various disadvantages of pollution control technologies for toxic metal-contaminated soil, we mixed contaminated soil with sludge for in situ composting to stabilize toxic metals, so plants are enriched to take up the toxic metals. When simulating the above, we added toxic metal solution into sewage sludge, and then composed it with steel slag to determine inhibition of the availability of toxic metals. When toxic metals were added into sludge, the potential ecological index and geoaccumulation index of Cd became high while Zn was low. Steel slag had an inhibited availability of Cd, and when the adjunction of steel slag was 7%, the availability of Cd was lowest. Steel slag promoted the availability of Zn, and when the adjunction of steel slag was 27%, the availability of Zn was highest. Results showed that during composting, with increasing steel slag, Cd stabilizing time was reached sooner but Zn stabilizing time was slower, and the availability of all metals became lower. In the end, composting inhibited the potential ecological index of Cd, but it promoted the potential ecological index of Zn. Steel slag promoted the stability of Cd and Zn as Fe/Mn oxide-bound and residual species. Therefore, composting sludge and steel slag could be used as an effective inhibitor of Zn and Cd pollution.

The potential for using slags activated with near neutral salts as immobilisation matrices for nuclear wastes containing reactive metals

NASA Astrophysics Data System (ADS)

Bai, Y.; Collier, N. C.; Milestone, N. B.; Yang, C. H.

2011-06-01

The UK currently uses composite blends of Portland cement and other inorganic cementitious material such as blastfurnace slag and pulverised fuel ash to encapsulate or immobilise intermediate and low level radioactive wastes. Typically levels up 9:1 blast furnace slag:Portland cement or 4:1 pulverised fuel ash:Portland cement are used. Whilst these systems offer many advantages, their high pH causes corrosion of various metallic intermediate level radioactive wastes. To address this issue, lower pH/weakly alkaline cementitious systems have to be explored. While the blast furnace slag:Portland cement system is referred to as a composite cement system, the underlying reaction is actually an indirect activation of the slag hydration by the calcium hydroxide generated by the cement hydration, and by the alkali ions and gypsum present in the cement. However, the slag also can be activated directly with activators, creating a system known as alkali-activated slag. Whilst these activators used are usually strongly alkaline, weakly alkaline and near neutral salts can also be used. In this paper, the potential for using weakly alkaline and near neutral salts to activate slag in this manner is reviewed and discussed, with particular emphasis placed on the immobilisation of reactive metallic nuclear wastes.

Effect of Slag Impregnation on Macroscopic Deformation of Bauxite-Based Material

NASA Astrophysics Data System (ADS)

Coulon, Antoine; De Bilbao, Emmanuel; Michel, Rudy; Bouchetou, Marie-Laure; Brassamin, Séverine; Gazeau, Camille; Zanghi, Didier; Poirier, Jacques

This work aims at studying the volume change of bauxite corroded by a molten slag. Cylindrical samples were prepared by mixing ground bauxite with slag. Optical measurement at high temperature (1450 °C) of deformation with a high-resolution camera has been developed. Image processing allowed for determining the change in diameter of the sample. We showed that the deformation was induced by the precipitation of new expansive crystallised phases observed by SEM-EDS analyses. Adding pellets of the same slag upon the samples allowed to emphasize the effect of the slag amount on the size change. The change in diameter significantly increased in the impregnated area.

System and method for producing metallic iron

DOEpatents

Englund, David J.; Schlichting, Mark; Meehan, John; Crouch, Jeremiah; Wilson, Logan

2014-07-29

A method of production of metallic iron nodules comprises assembling a hearth furnace having a moveable hearth comprising refractory material and having a conversion zone and a fusion zone, providing a hearth material layer comprising carbonaceous material on the refractory material, providing a layer of reducible material comprising and iron bearing material arranged in discrete portions over at least a portion of the hearth material layer, delivering oxygen gas into the hearth furnace to a ratio of at least 0.8:1 ponds of oxygen to pounds of iron in the reducible material to heat the conversion zone to a temperature sufficient to at least partially reduce the reducible material and to heat the fusion zone to a temperature sufficient to at least partially reduce the reducible material, and heating the reducible material to form one or more metallic iron nodules and slag.

Studies on use of Copper Slag as Replacement Material for River Sand in Building Constructions

NASA Astrophysics Data System (ADS)

Madheswaran, C. K.; Ambily, P. S.; Dattatreya, J. K.; Rajamane, N. P.

2014-09-01

This work focuses on the use of copper slag, as a partial replacement of sand for use in cement concrete and building construction. Cement mortar mixtures prepared with fine aggregate made up of different proportions of copper slag and sand were tested for use as masonry mortars and plastering. Three masonry wall panels of dimensions 1 × 1 m were plastered. The studies showed that although copper slag based mortar is suitable for plastering, with the increase in copper slag content, the wastage due to material rebounding from the plastered surfaces increases. It is therefore suggested that the copper slag can be used for plastering of floorings and horizontal up to 50 % by mass of the fine aggregate, and for vertical surfaces, such as, brick/block walls it can be used up to 25 %. In this study on concrete mixtures were prepared with two water cement ratios and different proportions of copper slag ranging from 0 % (for the control mix) to 100 % of fine aggregate. The Concrete mixes were evaluated for workability, density, and compressive strength.

Enhanced humification by carbonated basic oxygen furnace steel slag--I. Characterization of humic-like acids produced from humic precursors.

PubMed

Qi, Guangxia; Yue, Dongbei; Fukushima, Masami; Fukuchi, Shigeki; Nie, Yongfeng

2012-01-01

Carbonated basic oxygen furnace steel slag (hereinafter referred to as "steel slag") is generated during iron and steel manufacturing and is often classified as waste. The effect of steel slag on humification process was investigated. Catechol, glycine and glucose were used as model humic precursors from degraded biowastes. To verify that humification occurred in the system, humic-like acids (HLAs) were isolated and characterized structurally by elemental analysis, FTIR spectra, solid-state CP-MAS (13)C NMR spectra, and TMAH-Py-GC/MS. Characteristics of the steel slag-HLA were compared with those of HLAs formed in the presence of zeolite and birnessite, and with that of mature compost humic acid. The results showed that steel slag-HLA, like zeolite- and birnessite-HLA, is complex organic material containing prominent aromatic structures. Steel slag substantially accelerated the humification process, which would be highly significant for accelerating the stabilization of biowastes during composting (e.g. municipal solid waste, sewage sludge, and food waste). Copyright © 2011 Elsevier Ltd. All rights reserved.

Long term mechanical properties of alkali activated slag

NASA Astrophysics Data System (ADS)

Zhu, J.; Zheng, W. Z.; Xu, Z. Z.; Leng, Y. F.; Qin, C. Z.

2018-01-01

This article reports a study on the microstructural and long-term mechanical properties of the alkali activated slag up to 180 days, and cement paste is studied as the comparison. The mechanical properties including compressive strength, flexural strength, axis tensile strength and splitting tensile strength are analyzed. The results showed that the alkali activated slag had higher compressive and tensile strength, Slag is activated by potassium silicate (K2SiO3) and sodium hydroxide (NaOH) solutions for attaining silicate modulus of 1 using 12 potassium silicate and 5.35% sodium hydroxide. The volume dosage of water is 35% and 42%. The results indicate that alkali activated slag is a kind of rapid hardening and early strength cementitious material with excellent long-term mechanical properties. Single row of holes block compressive strength, single-hole block compressive strength and standard solid brick compressive strength basically meet engineering requirements. The microstructures of alkali activated slag are studied by X-ray diffraction (XRD). The hydration products of alkali-activated slag are assured as hydrated calcium silicate and hydrated calcium aluminate.

Mineralogical determination and geo-chemical modeling of chromium release from AOD slag: Distribution and leachability aspects.

PubMed

Li, Junguo; Liu, Bao; Zeng, Yanan; Wang, Ziming

2017-01-01

AOD (argon oxygen decarburization) slag, which is the by-product of the stainless steel refining process, is a recyclable slag because of its high content of calcium and silicon. The leaching toxicity cannot be ignored in the recycling process because the slag contains a certain amount of Cr. In this study, the mineral analysis, batch leaching tests and thermodynamic and kinetic modeling by PHREEQC combined with FactSage software were performed to explore the influence of the dissolution of primary minerals and the precipitation of secondary minerals on the elution of Cr from AOD slag. The results indicated that the main minerals in the original AOD slag are larnite, merwinite, pyroxene and periclase. Cr was dispersed in the mineral phases mentioned above. The simulation of Cr leaching controlled by Cr(III)-hydroxide corresponded better to the batch leaching tests, while the Cr leaching controlled by chromite or double control was underestimated. Increasing the L/S ratio enhances the pH of the leachate and restrains the elution of Cr from the AOD slag. Copyright © 2016 Elsevier Ltd. All rights reserved.

Slag-Based Nanomaterial in the Removal of Hexavalent Chromium

NASA Astrophysics Data System (ADS)

Baalamurugan, J.; Ganesh Kumar, V.; Govindaraju, K.; Naveen Prasad, B. S.; Bupesh Raja, V. K.; Padmapriya, R.

Slag-based nanomaterial is a by-product obtained during steel production and has wide range of components in the form of oxides. In this study, Induction Furnace (IF) steel slag-based application in adsorption of hexavalent chromium is investigated. IF slag has mixture of oxides mainly Fe2O3 and Chromium (VI) a highly toxic pollutant leads to environmental pollution and causes problem to human health mainly, carcinogenetic diseases. Slag-based nanomaterial is characterized using High Resolution Scanning Electron Microscope (HR-SEM) in which the size was around 100nm and X-ray Fluorescence (XRF) spectroscopy. Further inductively coupled plasma mass spectroscopy and Fourier transform infrared spectroscopy were used for adsorption studies. Slag activation using NaOH (alkali activation) to the intent of surface hydroxyl (-OH) group attachment will be a cost-effective process in the removal of hexavalent chromium. Cr(VI) ions are adsorbed on the surface of alkali activated slag material. The core-shell formation of Fe(II)/Fe(III)/Cr(VI) and the adsorption are investigated in detail in the present study.

Constant voltage electro-slag remelting control

DOEpatents

Schlienger, M.E.

1996-10-22

A system for controlling electrode gap in an electro-slag remelt furnace has a constant regulated voltage and an electrode which is fed into the slag pool at a constant rate. The impedance of the circuit through the slag pool is directly proportional to the gap distance. Because of the constant voltage, the system current changes are inversely proportional to changes in gap. This negative feedback causes the gap to remain stable. 1 fig.

Morphological Characterization Of Titania Slag Obtained From Red Sediment Placer Ilmenite Using Microwave Energy

NASA Astrophysics Data System (ADS)

Srikant, S. S.; Mukherjee, P. S.; Bhima Rao, R.

2015-04-01

This paper deals with the main objective to observe the effect of microwave heat treatment for the production of Titania rich slag and pig iron from placer ilmenite. The experiments carried out in the present investigation on the oxidized ilmenite sample for microwave heat treatment in microwave sintering furnace reveals that a product can be obtained containing Titania rich slag and metalized iron. The in-depth characterisation of these products using SEM-EDAX shows that around 75-85 % of titanium dioxide is formed in terms of titania rich slag by using microwave sintering furnace after reduction of oxidized ilmenite with proper stoichiometric graphitic carbon and silicon carbide (SiC) susceptor. The titania rich slag is considered to be better input material for production of pigment grade titanium dioxide. On the other hand, the pig iron obtained as by product from titania rich slag is also important for automobile and steel industries application.

Electrorheological effect of Ti-bearing blast furnace slag with different TiC contents at 1500°C

NASA Astrophysics Data System (ADS)

Yue, Hong-rui; Jiang, Tao; Zhang, Qiao-yi; Duan, Pei-ning; Xue, Xiang-xin

2017-07-01

The electrorheological properties of CaO-SiO2-Al2O3-MgO-TiO2-TiC slags were investigated to enhance understanding of the effect of TiC addition on the viscosity, yield stress, and fluid pattern of Ti-bearing slags in a direct-current electric field. The viscosities and shear stresses of 4wt% and 8wt% TiC slags were found to increase substantially with increasing electric field intensity, whereas virtually no rheological changes were observed in the 0wt% TiC slag. The Herschel-Bulkley model was applied to demonstrate that the fluid pattern of the 4wt% TiC slag was converted from that of a Newtonian fluid to that of a Bingham fluid in response to the applied electric field; and the static yield stress increased linearly with the square of the electric field intensity.

Effect of calcium silicate slag application on radium-226 concentrations in plant tissues

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mortvedt, J.J.

A greenhouse pot experiment was conducted to determine if plants absorb Ra from slag applied to soil. Slag at rates equivalent to 0 and 22 mt/ha was mixed with Mountview silt loam (Typic Paleudults) limed to pH 5.8 and 7.2. Three clippings each of fescue (Festuca arundiancea Schreb.), and Swiss chard (Beta vulgaris L.), and one harvest of wheat (Triticum aestivum L.) for grain and straw were grown on separate series of treated soil, and plant samples were analyzed for radioactivity due to /sup 226/Ra uptake. Samples of sugarcane (Saccharum officinarum L.) forage and extracted juice from field experiments inmore » Florida testing this slage as a Si source also were analyzed for radioactivity. Dry forage yields of fescue and wheat were not affected by slag applications, but those of Swiss chard were somewhat higher on slag-treated soil at pH 5.8. Wheat grain and straw yields were higher on soil at pH 7.2 than at pH 5.8 regardless of slag treatment. Uptake of /sup 226/Ra by fescue forage and wheat grain and straw was not affected by slag application. Concentrations of /sup 226/Ra were similar in forage and extracted juice from untreated sugarcane or that treated with slag at rates up to 5.6 mt/ha. These results suggest that plant uptake of radionuclides is negligible from calcium silicate slag applied at the recommended rates for liming acid soils or as a source of Si for sugarcane.« less

Thermodynamics and Kinetics of Boron Removal from Metallurgical Grade Silicon by Addition of High Basic Potassium Carbonate to Calcium Silicate Slag

NASA Astrophysics Data System (ADS)

Wu, Jijun; Wang, Fanmao; Ma, Wenhui; Lei, Yun; Yang, Bin

2016-06-01

In this study, we investigated the thermodynamics and kinetics of boron removal from metallurgical grade silicon (MG-Si) using a calcium silicate slag containing a high basic potassium carbonate. The distribution of boron between slag and silicon was theoretically derived and the distribution coefficients ( L B) of boron with different compositions of CaO, SiO2, and K2CO3 in slag reagents were determined. The maximal value of L B reached 2.08 with a high basicity slag of 40 pctCaO-40 pctSiO2-20 pctK2CO3 (Λ = 0.73). The boron removal rates from MG-Si using CaO-SiO2 and CaO-SiO2-K2CO3 slags at 1823 K (1550 °C) were investigated in an electromagnetic induction furnace. The results showed that the boron concentration in MG-Si can be reduced from 22 to 1.8 ppmw at 1823 K (1550 °C) with 20 pct K2CO3 addition to calcium silicate slag, where the removal efficiency of boron reached 91.8 pct. The mass transfer coefficient ( β S) of boron in binary 50 pctCaO-50 pctSiO2 slag was 3.16 × 10-6 m s-1 at 1823 K (1550 °C) and was 2.43 × 10-5 m s-1 in ternary 40 pctCaO-40 pctSiO2-20 pctK2CO3 slag.

Investigations on phosphorus recovery and reuse as soil amendment from electric arc furnace slag filters.

PubMed

Bird, Simon C; Drizo, Aleksandra

2009-11-01

Electric arc furnace (EAF) steel slag has been identified as an effective filter material for the removal of phosphorus (P) from both point and non-point sources. To determine the feasibility of land-applying P saturated EAF steel slag this study was undertaken to investigate (i) saturated EAF steel slag material's potential as a P fertilizer or soil amendment and (ii) P desorption and metals leachate from saturated EAF steel slag material to surface runoff. Medicago sativa (alfalfa) was planted in a nutrient depleted washed sand media. Phosphorus was added either as saturated EAF steel slag or as a standard commercial phosphate fertilizer in order to assess the plant availability of the P from saturated EAF steel slag. Four different P application levels were tested: a low (20 lbs acre furrow slice(-1) (5.5 g P m(-3))) two medium (40 and 60 lbs. acre f.s.(-1) (11 and 16.5 g P m(-3))) and a high (120 lbs. acre f.s.(-1) (33 g P m(-3))). The above-ground biomass of half of the plants was harvested after 5 weeks and the second half at 10 weeks. All treatments regardless of the P source used showed high rates of germination. At the first harvest period (5 weeks) significantly higher above-ground biomass (p < 0.01) was seen at the 3 highest P amendment rates in treatments with triple super phosphate fertilizer (TSP) than with EAF steel slag. However, by the second harvest (10 weeks) only the highest amendment rate of TSP showed a significantly higher amount of biomass (p < 0.01), suggesting that EAF steel slag might be an effective slow release P source. In a second experiment, a rain simulator was used to assess desorption of DRP, TP and metals from a saturated and semi-saturated EAF steel slag. The results revealed that the total amounts of DRP and TP released to surface runoff from EAF steel slag were negligible when compared to the total quantities of P retained by this material. Overall the results from this study demonstrated that once the EAF steel slag filter reaches its saturation point, the material could be re-used as soil amendment for the slow release of bioavailable P with minimal risk for loss of P to surface runoff, bringing further benefits to the environment.

Effects of industrial and agricultural waste amendment on soil greenhouse gas production in a paddy field in Southeastern China

NASA Astrophysics Data System (ADS)

Wang, Weiqi; Neogi, Suvadip; Lai, Derrick Y. F.; Zeng, Congsheng; Wang, Chun; Zeng, Dongping

2017-09-01

Controlling the production and subsequent emissions of greenhouse gases (GHGs) from paddy fields is crucial to minimize the climatic impacts arising from crop production. The application of chemical or biological amendments is one possible way to limit the production of GHGs in paddy soils. Yet, few existing studies have examined the impacts of applying fertilizers originated from industrial and agricultural wastes on soil GHG production and its governing factors in subtropical paddy fields. In this study, we examined the effects of various agricultural and industrial amendments, including biochar, steel slag, shell slag, gypsum slag, and slag-derived silicate and calcium fertilizers, on the production potential of GHGs in an early paddy field in southeast China. The mean CO2 production rates from soils amended with steel slag as well as silicate and calcium fertilizers were significantly higher than those of the controls by 13.4% and 18.6%, respectively (P < 0.05). Mean soil CH4 production rates from the plots amended with steel slag, biochar, shell slag, and gypsum slag were significantly lower than those of the controls by 42.5%, 36.1%, 60.8%, and 61.8%, respectively (P < 0.05). Meanwhile, we found no significant difference in mean soil N2O production rates between the control and any of the treatments (P > 0.05). Overall, the soil production rate of CO2 was positively correlated with that of CH4 (P < 0.05), but negatively correlated with that of N2O (P < 0.05). When compared to the controls, the ratio of soil CO2:CH4 production increased significantly in the plots receiving biochar, and silicate and calcium fertilizer amendments (P < 0.05), while that of CO2:N2O production increased significantly only in the biochar-amended plots. Soil CH4:N2O production ratio decreased significantly in the plots amended with steel slag and gypsum slag, as compared to the controls (P < 0.05). Our results suggest that the application of biochar, shell slag and gypsum slag would help reduce greenhouse gas production and mitigate climate change impacts of rice cultivation, largely attributable to the reduction in methanogenesis.

Evaluation of Alternative Causes of Widespread, Low Concentration Perchlorate Impacts to Groundwater

DTIC Science & Technology

2008-07-01

burning ceased, the residue and remaining slag were collected. 5. The slag was weighed in order to approximate the extent to which the flare had...with triple distilled, deionized water. 7. The washings and slag from each flare were placed in separate round-bottom flasks and stirred for ten...remaining was 0.027% on average or 99.97% of the original perchlorate was consumed (Table 3.3). Nevertheless, a slag containing elevated perchlorate

Impact of steel slag on the ammonium adsorption by zeolite and a new configuration of zeolite-steel slag substrate for constructed wetlands.

PubMed

Shi, Pengbo; Jiang, Yingbo; Zhu, Hongtao; Sun, Dezhi

2017-07-01

The CaO dissolution from slag, as well as the effects of influencing parameters (i.e. pH and Ca 2+ concentration) on the ammonium adsorption onto zeolite, was systematically studied in this paper. Modeling results of Ca 2+ and OH - release from slag indicated that pseudo-second-order reaction had a better fitness than pseudo-first-order reaction. Changing pH value from 7 to 12 resulted in a drastic reduction of the ammonium adsorption capacity on zeolite, from the peak adsorption capacity at pH 7. High Ca 2+ concentration in solution also inhibited the adsorption of ammonium onto zeolite. There are two proposed mechanisms for steel slag inhibiting the ammonium adsorption capacity of zeolite. On the one hand, OH - released from steel slag can react with ammonium ions to produce the molecular form of ammonia (NH 3 ·H 2 O), which would cause the dissociation of NH 4 + from zeolite. On the other hand, Ca 2+ could replace the NH 4 + ions to adhere onto the surface of zeolite. An innovative substrate filling configuration with zeolite placed upstream of the steel slag was then proposed to eliminate the disadvantageous effects of steel slag. Experimental results showed that this novel filling configuration was superior to two other filling configurations in terms of ammonium removal.

Converter slag-coal cinder columns for the removal of phosphorous and other pollutants.

PubMed

Yang, Jian; Wang, Su; Lu, Zhibo; Yang, Jian; Lou, Shanjie

2009-08-30

A mixture of converter slag and coal cinder as adsorbent for the removal of phosphorous and other pollutants was studied in the paper. The maximum P adsorption capacity, pH of solution, contact time and initial phosphate concentration were evaluated in batch experiments for the two materials firstly. The data of P sorption were best fitted to Langumir equation, and the maximum adsorption capacities of converter slag and coal cinder were 2.417 and 0.398 mg P/g, respectively. The pH of solutions with converter slag and coal cinder changed dramatically with time and closed to 8 in 8h, and the influence of initial pH on phosphate removal by coal cinder was more significant than by converter slag. Phosphate removal rate by converter slag decreased with increase of initial phosphate concentrations. Subsequently, two flow-through columns (Column 1#, V(converter slag):V(coal cinder)=1:5; Column 2#, V(converter slag):V(coal cinder)=1:3) were operated for the removal of phosphorous and other pollutants from the effluents of a vermifilter for nearly eleven months. Results indicated the average removal efficiency of total phosphorus, dissolved phosphorus, COD and NH(4)(+)-N by Column 1# were 44%, 56%, 31% and 67%, and by Column 2# were 42%, 54%, 24% and 57%, respectively. Column 1# had higher removal efficiency for P and other pollutants.

Two-zone countercurrent smelter system and process

DOEpatents

Cox, J.H.; Fruehan, R.J.; Elliott, J.F.

1995-01-03

A process for continuously smelting iron ore by use of coal to yield molten iron or semi-steel is disclosed. The process comprises the steps of establishing a melt covered by slag; inducing the slag and the molten iron to flow countercurrently to one another, toward opposite ends of the smelter; maintaining iron oxide-reducing conditions in that zone of the smelter towards which the slag flows; maintaining carbon-oxidizing conditions in that zone of the smelter towards which the molten iron flows; continuously or semicontinuously tapping the slag from the reducing zone end of the smelter; continuously or semicontinuously tapping the molten iron from the oxidizing zone end of the smelter; and adding to both zones iron ore, coal, oxygen, and flux at addition rates sufficient to keep the molten iron in the reducing zone substantially saturated with carbon, maintain in the slag being tapped an FeO content of about 5 weight percent or less, and maintain in the molten iron being tapped a carbon content of about 0.5 to 5 weight percent. A slag dam preferably is included in the smelter, to impede the backflow of the slag from the reducing zone to the oxidizing zone. A metal bath dam with one or more flow-through portals also is preferably used, submerged below the slag dam, to impede the backflow of the hot metal. 8 figures.

Two-zone countercurrent smelter system and process

DOEpatents

Cox, James H.; Fruehan, Richard J.; Elliott, deceased, John F.

1995-01-01

A process for continuously smelting iron ore by use of coal to yield molten iron or semi-steel is disclosed. The process comprises the steps of establishing a melt covered by slag; inducing the slag and the molten iron to flow countercurrently to one another, toward opposite ends of the smelter; maintaining iron oxide-reducing conditions in that zone of the smelter towards which the slag flows; maintaining carbon-oxidizing conditions in that zone of the smelter towards which the molten iron flows; continuously or semicontinuously tapping the slag from the reducing zone end of the smelter; continuously or semicontinuously tapping the molten iron from the oxidizing zone end of the smelter; and adding to both zones iron ore, coal, oxygen, and flux at addition rates sufficient to keep the molten iron in the reducing zone substantially saturated with carbon, maintain in the slag being tapped an FeO content of about 5 weight percent or less, and maintain in the molten iron being tapped a carbon content of about 0.5 to 5 weight percent. A slag dam preferably is included in the smelter, to impede the backflow of the slag from the reducing zone to the oxidizing zone. A metal bath dam with one or more flow-through portals also is preferably used, submerged below the slag dam, to impede the backflow of the hot metal.

Carbon transfer from magnesia-graphite ladle refractories to ultra-low carbon steel

NASA Astrophysics Data System (ADS)

Russo, Andrew Arthur

Ultra-low carbon steels are utilized in processes which require maximum ductility. Increases in interstitial carbon lower the ductility of steel; therefore, it is important to examine possible sources of carbon. The refractory ladle lining is one such source. Ladle refractories often contain graphite for its desirable thermal shock and slag corrosion resistance. This graphite is a possible source of carbon increase in ultra-low carbon steels. The goal of this research is to understand and evaluate the mechanisms by which carbon transfers to ultra-low carbon steel from magnesia-graphite ladle refractory. Laboratory dip tests were performed in a vacuum induction furnace under an argon atmosphere to investigate these mechanisms. Commercial ladle refractories with carbon contents between 4-12 wt% were used to investigate the effect of refractory carbon content. Slag-free dip tests and slag-containing dip tests with varying MgO concentrations were performed to investigate the influence of slag. Carbon transfer to the steel was controlled by steel penetrating into the refractory and dissolving carbon in dip tests where no slag was present. The rate limiting step for this mechanism is convective mass transport of carbon into the bulk steel. No detectable carbon transfer occurred in dip tests with 4 and 6 wt%C refractories without slag because no significant steel penetration occurred. Carbon transfer was controlled by the corrosion of refractory by slag in dip tests where slag was present.

Carbothermic Reduction Reactions at the Metal-Slag Interface in Ti-Bearing Slag from a Blast Furnace

NASA Astrophysics Data System (ADS)

Wang, Yao-Zu; Zhang, Jian-Liang; Liu, Zheng-Jian; Du, Cheng-Bo

2017-11-01

Carbothermic reduction reactions at the metal-slag interface and the mechanisms of iron loss during the smelting of vanadium-bearing titanomagnetite in a blast furnace are still not clear as a result of the limited ability to observe the high-temperature zone of a blast furnace. The chemical composition of a Ti-bearing slag was determined by x-ray fluorescence and x-ray diffraction. The interfaces were characterized by scanning electron microscopy coupled with energy-dispersive x-ray spectroscopy. The interfacial chemical reactions were deduced based on the characterization results and on the thermodynamic calculations performed using Factsage 6.4. The results indicated that the forms of iron in the slag were iron droplets wetted by Ti(C x , N1- x ), mechanically separated by iron and iron oxide. The different forms possessed unique characteristics and were formed by different mechanisms. Iron droplets wetted by Ti(C x , N1- x ) were generated through a series of interfacial reactions between TiO2 in the slag and [C] and [N] in the metal. Iron droplets without attached Ti(C x , N1- x ) were mainly located on the edges of pores and were attributed to the reduction of Fe x O in the slag. Insufficient reduction of iron-bearing minerals made it difficult for iron droplets to aggregate and separate from the slag, which created an Fe x O-enriched zone.

In situ stabilization of heavy metals in multiple-metal contaminated paddy soil using different steel slag-based silicon fertilizer.

PubMed

Ning, Dongfeng; Liang, Yongchao; Song, Alin; Duan, Aiwang; Liu, Zhandong

2016-12-01

Steel slag has been widely used as amendment and silicon fertilizer to alleviate the mobility and bioavailability of heavy metals in soil. The objective of this study was to evaluate the influence of particle size, composition, and application rate of slag on metal immobilization in acidic soil, metals uptake by rice and rice growth. The results indicated that application of slag increased soil pH, plant-available silicon concentrations in soil, and decreased the bioavailability of metals compared with control treatment, whereas pulverous slag (S1) was more effective than granular slag (S2 and S3). The acid-extractable fraction of Cd in the spiked soil was significantly decreased with application of S1 at rates of 1 and 3 %, acid-extractable fractions of Cu and Zn were decreased when treated at 3 %. Use of S1 at both rates resulted in significantly lower Cd, Cu, and Zn concentrations in rice tissues than in controls by 82.6-92.9, 88.4-95.6, and 67.4-81.4 %, respectively. However, use of pulverous slag at 1 % significantly promotes rice growth, restricted rice growth when treated at 3 %. Thus, the results explained that reduced particle size and suitable application rate of slag could be beneficial to rice growth and metals stabilization.

Elemental properties of coal slag and measured airborne exposures at two coal slag processing facilities

PubMed Central

Mugford, Christopher; Boylstein, Randy; Gibbs, Jenna L

2017-01-01

In 1974, the National Institute for Occupational Safety and Health recommended a ban on the use of silica sand abrasives containing >1% silica due to the risk of silicosis. This gave rise to substitutes including coal slag. An Occupational Safety and Health Administration investigation in 2010 uncovered a case cluster of suspected pneumoconiosis in four former workers at a coal slag processing facility in Illinois, possibly attributable to occupational exposure to coal slag dust. This article presents the results from a National Institute for Occupational Safety and Health industrial hygiene survey at the same coal slag processing facility and a second facility. The industrial hygiene survey consisted of the collection of: a) bulk samples of unprocessed coal slag, finished granule product, and settled dust for metals and silica; b) full-shift area air samples for dust, metals, and crystalline silica; and c) full-shift personal air samples for dust, metals, and crystalline silica. Bulk samples consisted mainly of iron, manganese, titanium, and vanadium. Some samples had detectable levels of arsenic, beryllium, cadmium, and cobalt. Unprocessed coal slags from Illinois and Kentucky contained 0.43–0.48% (4,300–4,800 mg/kg) silica. Full-shift area air samples identified elevated total dust levels in the screen (2–38 mg/m3) and bag house (21 mg/m3) areas. Full-shift area air samples identified beryllium, chromium, cobalt, copper, iron, nickel, manganese, and vanadium. Overall, personal air samples for total and respirable dust (0.1–6.6 mg/m3 total; and 0.1–0.4 mg/m3 respirable) were lower than area air samples. All full-shift personal air samples for metals and silica were below published occupational exposure limits. All bulk samples of finished product granules contained less than 1% silica, supporting the claim coal slag may present less risk for silicosis than silica sand. We note that the results presented here are solely from two coal slag processing facilities, and more in-depth air monitoring is needed to better characterize occupational exposure to coal slag dust, metals, and silica at similar facilities. PMID:27808662

Elemental properties of coal slag and measured airborne exposures at two coal slag processing facilities.

PubMed

Mugford, Christopher; Boylstein, Randy; Gibbs, Jenna L

2017-05-01

In 1974, the National Institute for Occupational Safety and Health recommended a ban on the use of silica sand abrasives containing >1% silica due to the risk of silicosis. This gave rise to substitutes including coal slag. An Occupational Safety and Health Administration investigation in 2010 uncovered a case cluster of suspected pneumoconiosis in four former workers at a coal slag processing facility in Illinois, possibly attributable to occupational exposure to coal slag dust. This article presents the results from a National Institute for Occupational Safety and Health industrial hygiene survey at the same coal slag processing facility and a second facility. The industrial hygiene survey consisted of the collection of: (a) bulk samples of unprocessed coal slag, finished granule product, and settled dust for metals and silica; (b) full-shift area air samples for dust, metals, and crystalline silica; and (c) full-shift personal air samples for dust, metals, and crystalline silica. Bulk samples consisted mainly of iron, manganese, titanium, and vanadium. Some samples had detectable levels of arsenic, beryllium, cadmium, and cobalt. Unprocessed coal slags from Illinois and Kentucky contained 0.43-0.48% (4,300-4,800 mg/kg) silica. Full-shift area air samples identified elevated total dust levels in the screen (2-38 mg/m 3 ) and bag house (21 mg/m 3 ) areas. Full-shift area air samples identified beryllium, chromium, cobalt, copper, iron, nickel, manganese, and vanadium. Overall, personal air samples for total and respirable dust (0.1-6.6 mg/m 3 total; and 0.1-0.4 mg/m 3 respirable) were lower than area air samples. All full-shift personal air samples for metals and silica were below published occupational exposure limits. All bulk samples of finished product granules contained less than 1% silica, supporting the claim coal slag may present less risk for silicosis than silica sand. We note that the results presented here are solely from two coal slag processing facilities, and more in-depth air monitoring is needed to better characterize occupational exposure to coal slag dust, metals, and silica at similar facilities.

Slags in a Large Variation Range of Oxygen Potential Based on the Ion and Molecule Coexistence Theory

NASA Astrophysics Data System (ADS)

Yang, Xue-Min; Li, Jin-Yan; Zhang, Meng; Chai, Guo-Min; Zhang, Jian

2014-12-01

A thermodynamic model for predicting sulfide capacity of CaO-FeO-Fe2O3-Al2O3-P2O5 slags in a large variation range of oxygen potential corresponding to mass percentage of FetO from 1.88 to 55.50 pct, i.e., IMCT- model, has been developed by coupling with the deduced desulfurization mechanism of the slags based on the ion and molecule coexistence theory (IMCT). The developed IMCT- model has been verified through comparing the determined sulfide capacity after Ban-ya et al.[20] with the calculated by the developed IMCT- model and the calculated by the reported sulfide capacity models such as the KTH model. Mass percentage of FetO as 6.75 pct corresponding to the mass action concentration of FetO as 0.0637 or oxygen partial as 2.27 × 10-6 Pa is the criterion for distinguishing reducing and oxidizing zones for the slags. Sulfide capacity of the slags in reducing zone is controlled by reaction ability of CaO regardless of slag oxidization ability. However, sulfide capacity of the slags in oxidizing zone shows an obvious increase tendency with the increasing of slag oxidization ability. Sulfide capacity of the slags in reducing zone keeps almost constant with variation of the simplified complex basicity (pct CaO)/((pct Al2O3) + (pct P2O5)), or optical basicity, or the mass action concentration ratios of N FeO/ N CaO, , , and . Sulfide capacity of the slags in oxidizing zone shows an obvious increase with the increasing of the simplified complex basicity (pct CaO)/((pct Al2O3) + (pct P2O5)) or optical basicity, or the aforementioned mass action concentration ratios. Thus, the aforementioned mass action concentration ratios and the corresponding mass percentage ratios of various iron oxides to basic oxide CaO are recommended to represent the comprehensive effect of various iron oxides and basic oxide CaO on sulfide capacity of the slags.

Effects of body formulation and firing temperature to properties of ceramic tile incorporated with electric arc furnace (EAF) slag waste

NASA Astrophysics Data System (ADS)

Sharif, Nurulakmal Mohd; Lim, Chi Yang; Teo, Pao Ter; Seman, Anasyida Abu

2017-07-01

Significant quantities of sludge and slag are generated as waste materials or by-products from steel industries. One of the by-products is Electric Arc Furnace (EAF) steel slag which consists of oxides such as CaO, Al2O3 and FeO. This makes it possible for slag to partially replace the raw materials in ceramic tile production. In our preliminary assessment of incorporating the EAF slag into ceramic tile, it was revealed that at fixed firing temperature of 1150°C, the tile of composition 40 wt.% EAF slag - 60 wt.% ball clay has comparable properties with commercial ceramic tile. Thus, this current study would focus on effects of body formulation (different weight percentages of K-feldspar and silica) and different firing temperatures to properties of EAF slag added ceramic tile. EAF slag from Southern Steel Berhad (SSB) was crushed into micron size (EAF slag content was 40 wt.%) and milled with ball clay, K-feldspar and silica before compacted and fired at 1125°C and 1150°C. The EAF slag added tile was characterized in terms of water absorption, apparent porosity, bulk density, modulus of rupture (MOR) and phase analysis via X-ray diffraction (XRD). The composition of 40 wt.% EAF slag - 30 wt.% ball clay - 10 wt.% K-feldspar - 20 wt.% silica (10F_20S), fired at 1150°C showed the lowest water absorption, apparent porosity and highest bulk density due to enhancement of densification process during firing. However, the same composition of ceramic tile (10F_20S) had the highest MOR at lower firing temperature of 1125°C, contributed by presence of the highest total amount of anorthite and wollastonite reinforcement crystalline phases (78.40 wt.%) in the tile. Overall, both the water absorption and MOR of all ceramic tiles surpassed the requirement regulated by MS ISO 13006:2014 Standard (Annex G: Dry-pressed ceramic tile with low water absorption, Eb ≤ 0.50 % and minimum MOR of 35 MPa).

Efficient Separation and Extraction of Vanadium and Chromium in High Chromium Vanadium Slag by Selective Two-Stage Roasting-Leaching

NASA Astrophysics Data System (ADS)

Wen, Jing; Jiang, Tao; Xu, Yingzhe; Liu, Jiayi; Xue, Xiangxin

2018-06-01

Vanadium and chromium are important rare metals, leading to a focus on high chromium vanadium slag (HCVS) as a potential raw material to extract vanadium and chromium in China. In this work, a novel method based on selective two-stage roasting-leaching was proposed to separate and extract vanadium and chromium efficiently in HCVS. XRD, FT-IR, and SEM were utilized to analyze the phase evolutions and microstructure during the whole process. Calcification roasting, which can calcify vanadium selectively using thermodynamics, was carried out in the first roasting stage to transfer vanadium into acid-soluble vanadate and leave chromium in the leaching residue as (Fe0.6Cr0.4)2O3 after H2SO4 leaching. When HCVS and CaO were mixed in the molar ratio CaO/V2O3 (n(CaO)/n(V2O3)) of 0.5 to 1.25, around 90 pct vanadium and less than 1 pct chromium were extracted in the first leaching liquid, thus achieving the separation of vanadium and chromium. In the second roasting stage, sodium salt, which combines with chromium easily, was added to the first leaching residue to extract chromium and 95.16 pct chromium was extracted under the optimal conditions. The total vanadium and chromium leaching rates were above 95 pct, achieving the efficient separation and extraction of vanadium and chromium. The established method provides a new technique to separate vanadium and chromium during roasting rather than in the liquid form, which is useful for the comprehensive application of HCVS.

Efficient Separation and Extraction of Vanadium and Chromium in High Chromium Vanadium Slag by Selective Two-Stage Roasting-Leaching

NASA Astrophysics Data System (ADS)

Wen, Jing; Jiang, Tao; Xu, Yingzhe; Liu, Jiayi; Xue, Xiangxin

2018-04-01

Vanadium and chromium are important rare metals, leading to a focus on high chromium vanadium slag (HCVS) as a potential raw material to extract vanadium and chromium in China. In this work, a novel method based on selective two-stage roasting-leaching was proposed to separate and extract vanadium and chromium efficiently in HCVS. XRD, FT-IR, and SEM were utilized to analyze the phase evolutions and microstructure during the whole process. Calcification roasting, which can calcify vanadium selectively using thermodynamics, was carried out in the first roasting stage to transfer vanadium into acid-soluble vanadate and leave chromium in the leaching residue as (Fe0.6Cr0.4)2O3 after H2SO4 leaching. When HCVS and CaO were mixed in the molar ratio CaO/V2O3 (n(CaO)/n(V2O3)) of 0.5 to 1.25, around 90 pct vanadium and less than 1 pct chromium were extracted in the first leaching liquid, thus achieving the separation of vanadium and chromium. In the second roasting stage, sodium salt, which combines with chromium easily, was added to the first leaching residue to extract chromium and 95.16 pct chromium was extracted under the optimal conditions. The total vanadium and chromium leaching rates were above 95 pct, achieving the efficient separation and extraction of vanadium and chromium. The established method provides a new technique to separate vanadium and chromium during roasting rather than in the liquid form, which is useful for the comprehensive application of HCVS.

Alkali-Activated Natural Pozzolan/Slag Binder for Sustainable Concrete

NASA Astrophysics Data System (ADS)

Najimi, Meysam

This study aimed to fully replace Portland cement (PC) with environmentally friendly binders capable of improving longevity of concrete. The new binders consisted of different proportions of natural Pozzolan and slag which were alkaline-activated with various combinations of sodium hydroxide and sodium silicate. A step-by-step research program was designed to (1) develop alkali-activated natural Pozzolan/slag pastes with adequate fresh and strength properties, (2) produce alkali-activated natural Pozzolan/slag mortars to assess the effects of dominant variables on their plastic and hardened properties, and (3) finally produce and assess fresh, mechanical, dimensional, transport and durability properties of alkali-activated natural Pozzolan/slag concretes. The major variables included in this study were binder combination (natural Pozzolan/slag combinations of 70/30, 50/50 and 30/70), activator combination (sodium silicate/sodium hydroxide combinations of 20/80, 25/75 and 30/70), and sodium hydroxide concentration (1, 1.75 and 2.5M). The experimental program assessed performance of alkali-activated natural Pozzolan/slag mixtures including fresh properties (flow and setting times), unit weights (fresh, demolded and oven-dry), mechanical properties (compressive and tensile strengths, and modulus of elasticity), transport properties (absorption, rapid chloride penetration, and rapid chloride migration), durability (frost resistance, chloride induced corrosion, and resistance to sulfuric acid attack), and dimensional stability (drying shrinkage). This study also compared the performance of alkali-activated natural Pozzolan/slag concretes with that of an equivalent reference Portland cement concrete having a similar flow and strength characteristics. The results of this study revealed that it was doable to find optimum binder proportions, activator combinations and sodium hydroxide concentrations to achieve adequate plastic and hardened properties. Nearly for all studied alkali-activated concretes, workability and setting times were in the acceptable ranges. Overall, a 50/50 combination of natural Pozzolan and slag developed the highest strengths. Increasing slag content to 70%, however, was useful for mixtures with high NaOH concentrations (2.5M) and for acceleration of initial reactions. The strength of alkali-activated concretes improved with increases in sodium silicate portion of activator. Regarding effects of sodium hydroxide concentration on strength properties, there were optimum NaOH molarities which increased with an increase in slag portion of the binder. A 50/50 combination of natural Pozzolan and slag also proved to be the optimum combination for the results of absorption test. NaOH concentration and sodium silicate dosage had marginal effects on the absorption and volume of permeable voids. The chloride penetration depth reduced with decreases in natural Pozzolan portion of the binder (particularly from 70 to 50%), sodium silicate dosage, and NaOH concentration. A nearly similar trend was seen for the drying shrinkage of studied alkali-activated natural Pozzolan/slag concretes, as reduction of these variables also reduced the drying shrinkage. The mass loss of alkali-activated concretes subjected to acid attack increased with increases in slag content, sodium silicate dosage, and sodium hydroxide concentration. The failure time in corrosion test improved (increased) with increases in natural Pozzolan content, sodium silicate dosage, and sodium hydroxide concentration. The frost resistance of alkali-activated concretes improved as slag portion of the binder was increased. An increase in sodium silicate dosage was beneficial in improving frost resistance of concretes made with binders having 50 and 70% slag. An opposite trend was seen when slag portion of the binder was reduced to 30%. The mechanical properties (compressive strength, tensile strength and elastic modulus) of alkali-activated concretes made with activators having 20 and 25% sodium silicate were lower than those of the reference Portland cement concrete. As sodium silicate dosage of activator was increased to 30%, the compressive strengths of alkali-activated concretes were similar to those of the reference Portland cement concrete. Absorption of the studied alkali-activated natural Pozzolan/slag concretes was averagely 26% lower than that of the reference Portland cement concrete. Their chloride penetration depths were significantly lower (averagely about 80%) than that of the reference Portland cement concrete. The average drying shrinkage of alkali-activated natural Pozzolan/slag concretes was lower than that of reference PC concrete by nearly 26%. While the drying shrinkage of the worst performed alkali-activated natural Pozzolan/slag concrete was about 25% higher than that of the reference Portland cement concrete, there were several alkali-activated concretes that shrank considerably less than the reference Portland cement concrete. The corrosion and acid attack resistances of alkali-activated natural Pozzolan/slag concretes were significantly higher than that of the reference Portland cement concrete. The frost resistance of alkali-activated concretes having binders made with 50 and 70% slag was significantly higher than that of the reference Portland cement concrete. On the other hand, the frost resistance of concretes made with binders having 30% slag was similar to or less than (depending on sodium silicate content) that of the reference Portland cement concrete.

Evaluation of hydraulic cement concretes containing slag added at the mixer.

DOT National Transportation Integrated Search

1985-01-01

The study evaluated the effect of ground, granulated, iron slags on the properties of hydraulic cement concretes such as normally used in highway construction. Two cements with different alkali contents and two slags with different activity indices, ...

[Influence of liquid ceramic additive on binding of heavy metal during the vitrification of fly ash from municipal solid waste incinerator].

PubMed

Li, Run-dong; Nie, Yong-feng; Li, Ai-min; Wang, Lei; Chi, Yong; Cen, Ke-fa

2004-09-01

Vitrification process can effectively control the leachability of heavy metals in fly ash generated from municipal solid waste incinerator (MWSI). The use of liquid ceramic (LC) additive as a heavy metal chemical stabilization agent was evaluated for MSWI fly ash. The residuals of chromium, lead and zinc in slag increase by different degree with liquid ceramic additive at 1400 degrees C, while those of cadmium and copper decreases. The migrating characteristic of nickel is hardly affected by the additive less than 10%. The volatilization of Cr and Zn occurs after 61 minute with 10% addition of LC, and the binding efficiency of Cr decreases with increasing of melting temperature. The results indicate that the binding efficiency of heavy metals was affected greatly by LC additive and showed significant differences according to type of heavy metal during melting process. The short melting time (no longer than 33 min) is useful to obtain high binding efficiency of heavy metals.

Functions of slags and gravels as substrates in large-scale demonstration constructed wetland systems for polluted river water treatment.

PubMed

Ge, Yuan; Wang, Xiaochang; Zheng, Yucong; Dzakpasu, Mawuli; Zhao, Yaqian; Xiong, Jiaqing

2015-09-01

The choice of substrates with high adsorption capacity, yet readily available and economical is vital for sustainable pollutants removal in constructed wetlands (CWs). Two identical large-scale demonstration horizontal subsurface flow (HSSF) CWs (surface area, 340 m(2); depth, 0.6 m; HLR, 0.2 m/day) with gravel or slag substrates were evaluated for their potential use in remediating polluted urban river water in the prevailing climate of northwest China. Batch experiments to elucidate phosphorus adsorption mechanisms indicated a higher adsorption capacity of slag (3.15 g/kg) than gravel (0.81 g/kg), whereby circa 20 % more total phosphorus (TP) removal was recorded in HSSF-slag than HSSF-gravel. TP removal occurred predominantly via CaO-slag dissolution followed by Ca phosphate precipitation. Moreover, average removals of chemical oxygen demand and biochemical oxygen demand were approximately 10 % higher in HSSF-slag than HSSF-gravel. Nevertheless, TP adsorption by slag seemed to get quickly saturated over the monitoring period, and the removal efficiency of the HSSF-slag approached that of the HSSF-gravel after 1-year continuous operation. In contrast, the two CWs achieved similar nitrogen removal during the 2-year monitoring period. Findings also indicated that gravel provided better support for the development of other wetland components such as biomass, whereby the biomass production and the amount of total nitrogen (TN; 43.1-59.0 g/m(2)) and TP (4.15-5.75 g/m(2)) assimilated by local Phragmites australis in HSSF-gravel were higher than that in HSSF-slag (41.2-52.0 g/m(2) and 3.96-4.07 g/m(2), respectively). Overall, comparable pollutant removal rates could be achieved in large-scale HSSF CWs with either gravel or slag as substrate and provide a possible solution for polluted urban river remediation in northern China.

Separation of Iron Phase and P-Bearing Slag Phase from Gaseous-Reduced, High-Phosphorous Oolitic Iron Ore at 1473 K (1200 °C) by Super Gravity

NASA Astrophysics Data System (ADS)

Gao, Jintao; Zhong, Yiwei; Guo, Lei; Guo, Zhancheng

2016-04-01

In situ observation on the morphology evolution and phosphorous migration of gaseous-reduced, high-phosphorous oolitic iron ore during the melting process was carried out with a high-temperature confocal scanning laser microscope. The results showed that 1473 K (1200 °C) was a critical temperature at which the gangue minerals started to form into the slag phase while the iron grains remained in a solid state; in addition, the phosphorus remained in the slag phase. Since the separation of iron grains and P-bearing slag was not achieved at the low temperature under the conventional conditions, separate experiments of the iron phase and the P-bearing slag phase from gaseous-reduced, high-phosphorous oolitic iron ore at 1473 K (1200 °C) by super gravity were carried out in this study. Based on the iron-slag separation by super gravity, phosphorus was removed effectively from the iron phase at the temperature below the melting point of iron. Iron grains moved along the super-gravity direction, joined, and concentrated as the iron phase on the filter, whereas the slag phase containing apatite crystals broke through the barriers of the iron grains and went through the filter. Consequently, increasing the gravity coefficient was definitely beneficial for the separation of the P-bearing slag phase from the iron phase. With the gravity coefficient of G = 1200, the mass fractions of separated slag and iron phases were close to their respective theoretical values, and the mass fraction of MFe in the separated iron phase was up to 98.09 wt pct and that of P was decreased to 0.083 wt pct. The recovery of MFe in the iron phase and that of P in the slag phase were up to 99.19 and 95.83 pct, respectively.

Synthesis and Characterization of Titanium Slag from Ilmenite by Thermal Plasma Processing

NASA Astrophysics Data System (ADS)

Samal, Sneha

2016-09-01

Titanium rich slag has emerged as a raw material for alternative titanium source. Ilmenite contains 42-50% TiO2 as the mineralogical composition depending on the geographical resources. Application of titanium in paper, plastic, pigment and other various industries is increasing day by day. Due to the scarcity of natural raw mineral rutile (TiO2), ilmenite is considered as precursor for the extraction of TiO2. Ilmenite is reduced at the initial stage for the conversion of complex iron oxide into simpler form. Therefore, pre-reduction of ilmenite concentrate is essential to minimize the energy consumption during thermal plasma process. Thermal plasma processing of ilmenite for the production of titania rich slag is considered to be the direct route to meet the current demand of industrial needs of titanium. Titania rich slag contains 70-80% TiO2 as the major component with some other minor impurities, like oxide phases of Si, Al, Cr, Mg, Mn, Ca, etc. Usually titanium is present in tetravalent forms with globular metallic iron in the slag. Titania rich slag undergoes leaching for the removal of iron and transforming the slag into synthetic rutile having 85-95% of TiO2.

Phase Equilibria of ``Cu2O''-``FeO''-CaO-MgO-Al2O3 Slags at PO2 of 10-8.5 atm in Equilibrium with Metallic Copper for a Copper Slag Cleaning Production

NASA Astrophysics Data System (ADS)

Henao, Hector M.; Pizarro, Claudio; Font, Jonkion; Moyano, Alex; Hayes, Peter C.; Jak, Evgueni

2010-12-01

Limited data are available on phase equilibria of the multicomponent slag system at the oxygen partial pressures used in the copper smelting, converting, and slag-cleaning processes. Recently, experimental procedures have been developed and have been applied successfully to characterize several complex industrial slags. The experimental procedures involve high-temperature equilibration on a substrate and quenching followed by electron probe X-ray microanalysis. This technique has been used to construct the liquidus for the “Cu2O”-“FeO”-SiO2-based slags with 2 wt pct of CaO, 0.5 wt pct of MgO, and 4.0 wt pct of Al2O3 at controlled oxygen partial pressures in equilibrium with metallic copper. The selected ranges of compositions and temperatures are directly relevant to the copper slag-cleaning processes. The new experimental equilibrium results are presented in the form of ternary sections and as a liquidus temperature vs Fe/SiO2 weight ratio diagram. The experimental results are compared with the FactSage thermodynamic model calculations.

Integrated carbon dioxide/sludge gasification using waste heat from hot slags: syngas production and sulfur dioxide fixation.

PubMed

Sun, Yongqi; Zhang, Zuotai; Liu, Lili; Wang, Xidong

2015-04-01

The integrated CO2/sludge gasification using the waste heat in hot slags, was explored with the aim of syngas production, waste heat recovery and sewage sludge disposal. The results demonstrated that hot slags presented multiple roles on sludge gasification, i.e., not only a good heat carrier (500-950 °C) but also an effective desulfurizer (800-900 °C). The total gas yields increased from 0.022 kg/kgsludge at 500 °C to 0.422 kg/kgsludge at 900 °C; meanwhile, the SO2 concentration at 900 °C remarkably reduced from 164 ppm to 114 ppm by blast furnace slags (BFS) and 93 ppm by steel slags (SS), respectively. A three-stage reaction was clarified including volatile release, char transformation and fixed carbon using Gaussian fittings and the kinetic model was analyzed. Accordingly, a decline process using the integrated method was designed and the optimum slag/sludge ratio was deduced. These deciphered results appealed potential ways of reasonable disposal of sewage sludge and efficient recovery of waste heat from hot slags. Copyright © 2015 Elsevier Ltd. All rights reserved.

Bioleaching of metals from steel slag by Acidithiobacillus thiooxidans culture supernatant.

PubMed

Hocheng, Hong; Su, Cheer; Jadhav, Umesh U

2014-12-01

The generation of 300–500 kg of slag per ton of the steel produced is a formidable amount of solid waste available for treatment. They usually contain considerable quantities of valuable metals. In this sense, they may become either important secondary resource if processed in eco-friendly manner for secured supply of contained metals or potential pollutants, if not treated properly. It is possible to recover metals from steel slag by applying bioleaching process. Electric arc furnace (EAF) slag sample was used for bioleaching of metals. In the present study, before bioleaching experiment water washing of an EAF slag was carried out. This reduced slag pH from 11.2 to 8.3. Culture supernatants of Acidithiobacillus thiooxidans (At. thiooxidans), Acidithiobacillus ferrooxidans (At. ferrooxidans), and Aspergillus niger (A. niger) were used for metal solubilization. At. thiooxidans culture supernatant containing 0.016 M sulfuric acid was found most effective for bioleaching of metals from an EAF slag. Maximum metal extraction was found for Mg (28%), while it was least for Mo (0.1%) in six days. Repeated bioleaching cycles increased metal recovery from 28% to 75%, from 14% to 60% and from 11% to 27%, for Mg, Zn and Cu respectively.

Reuse of steel slag in bituminous paving mixtures.

PubMed

Sorlini, Sabrina; Sanzeni, Alex; Rondi, Luca

2012-03-30

This paper presents a comprehensive study to evaluate the mechanical properties and environmental suitability of electric arc furnace (EAF) steel slag in bituminous paving mixtures. A variety of tests were executed on samples of EAF slag to characterize the physical, geometrical, mechanical and chemical properties as required by UNI EN specifications, focusing additionally on the volumetric expansion associated with hydration of free CaO and MgO. Five bituminous mixtures of aggregates for flexible road pavement were designed containing up to 40% of EAF slag and were tested to determine Marshall stability and indirect tensile strength. The leaching behaviour of slag samples and bituminous mixtures was evaluated according to the UNI EN leaching test. The tested slag showed satisfactory physical and mechanical properties and a release of pollutants generally below the limits set by the Italian code. Tests on volume stability of fresh materials confirmed that a period of 2-3 months is necessary to reduce effects of oxides hydration. The results of tests performed on bituminous mixtures with EAF slag were comparable with the performance of mixtures containing natural aggregates and the leaching tests provided satisfactory results. Copyright © 2012 Elsevier B.V. All rights reserved.

40 CFR 424.30 - Applicability; description of the slag processing subcategory.

Code of Federal Regulations, 2010 CFR

2010-07-01

... processing subcategory. 424.30 Section 424.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS FERROALLOY MANUFACTURING POINT SOURCE CATEGORY Slag Processing Subcategory § 424.30 Applicability; description of the slag processing subcategory. The provisions of this...

Use of soil-steel slag-class-C fly ash mixtures in subgrade applications.

DOT National Transportation Integrated Search

2012-12-07

In Indiana, large quantities of recyclable : materials - such as steel slag, blast furnace : slag and fly ash - are generated each year as : by-products of various industries. Instead of : disposing these by-products into landfills, : we can recycle ...

Steel slag in hot mix asphalt concrete : final report

DOT National Transportation Integrated Search

2000-04-01

In September 1994, steel slag test and control sections were constructed in Oregon to evaluate the use of steel slag in hot mix asphalt concrete (HMAC). This report covers the construction and five-year performance of a pavement constructed with 30% ...

Simplified model for determining local heat flux boundary conditions for slagging wall

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bingzhi Li; Anders Brink; Mikko Hupa

2009-07-15

In this work, two models for calculating heat transfer through a cooled vertical wall covered with a running slag layer are investigated. The first one relies on a discretization of the velocity equation, and the second one relies on an analytical solution. The aim is to find a model that can be used for calculating local heat flux boundary conditions in computational fluid dynamics (CFD) analysis of such processes. Two different cases where molten deposits exist are investigated: the black liquor recovery boiler and the coal gasifier. The results show that a model relying on discretization of the velocity equationmore » is more flexible in handling different temperature-viscosity relations. Nevertheless, a model relying on an analytical solution is the one fast enough for a potential use as a CFD submodel. Furthermore, the influence of simplifications to the heat balance in the model is investigated. It is found that simplification of the heat balance can be applied when the radiation heat flux is dominant in the balance. 9 refs., 7 figs., 10 tabs.« less

Process of discharging charge-build up in slag steelmaking processes

DOEpatents

Pal, Uday B.; Gazula, Gopala K. M.; Hasham, Ali

1994-01-01

A process and apparatus for improving metal production in ironmaking and steelmaking processes is disclosed. The use of an inert metallic conductor in the slag-containing crucible and the addition of a transition metal oxide to the slag are the disclosed process improvements.

Evaluation of portland cement concrete pavement with high slag content cement.

DOT National Transportation Integrated Search

2013-10-01

The performance of a section of concrete pavement built with 30 percent Ground Granulated Blast Furnace Slag (GGBFS) is compared to a control section of concrete pavement built with 25 percent GGBFS to determine if the higher slag content pavement is...

15. TAKING A CAST AT FURNACE NO. 1 HOT SLAG, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

15. TAKING A CAST AT FURNACE NO. 1 HOT SLAG, BY-PRODUCT IN SMELTING OF PIG IRON, CAN BE SEEN FLOWING INTO THE SLAG YARD. VIEW IS LOOKING SOUTH. - Corrigan, McKinney Steel Company, 3100 East Forty-fifth Street, Cleveland, Cuyahoga County, OH

Rare and Rare-Earth Metals in Coal Processing Waste

NASA Astrophysics Data System (ADS)

Cherkasova, Tatiana; Cherkasova, Elizaveta; Tikhomirova, Anastasia; Bobrovni-kova, Alyona; Goryunova, Irina

2017-11-01

An urgent issue for power plants operating on solid fuels (coal) is the issue of utilization or use of accumulated production waste - ash and slag materials - in the related production. Ash-slag materials are classified as "waste", usually grade 5; tens of millions of tons of them being pro-duced annually in the Kemerovo region, which threatens the ecology of the region. At the same time, ash and slag is a very promising raw material. The use of this material as a base for the final product allows us to signifi-cantly expand the possibilities of using coal. The most widespread is the system of ash and slag involving in construction or as a replacement for sand in road construction, or as an additive to building mixtures. However, there are both industrially valuable and environmentally dangerous ele-ments in ash-slag materials. Ash-slag materials can be considered as inde-pendent ore deposits located on the surface and requiring the costs of their extraction.

Artificial intelligence-based computer modeling tools for controlling slag foaming in electric arc furnaces

NASA Astrophysics Data System (ADS)

Wilson, Eric Lee

Due to increased competition in a world economy, steel companies are currently interested in developing techniques that will allow for the improvement of the steelmaking process, either by increasing output efficiency or by improving the quality of their product, or both. Slag foaming is one practice that has been shown to contribute to both these goals. However, slag foaming is highly dynamic and difficult to model or control. This dissertation describes an effort to use artificial intelligence-based tools (genetic algorithms, fuzzy logic, and neural networks) to both model and control the slag foaming process. Specifically, a neural network is trained and tested on slag foaming data provided by a steel plant. This neural network model is then controlled by a fuzzy logic controller, which in turn is optimized by a genetic algorithm. This tuned controller is then installed at a steel plant and given control be a more efficient slag foaming controller than what was previously used by the steel plant.

Heavy metal recovery from electric arc furnace steel slag by using hydrochloric acid leaching

NASA Astrophysics Data System (ADS)

Wei, Lim Jin; Haan, Ong Teng; Shean Yaw, Thomas Choong; Chuah Abdullah, Luqman; Razak, Mus'ab Abdul; Cionita, Tezara; Toudehdehghan, Abdolreza

2018-03-01

Electric Arc Furnace steel slag (EAFS) is the waste produced in steelmaking industry. Environmental problem such as pollution will occur when dumping the steel slag waste into the landfill. These steel slags have properties that are suitable for various applications such as water treatment and wastewater. The objective of this study is to develop efficient and economical chlorination route for EAFS extraction by using leaching process. Various parameters such as concentration of hydrochloric acid, particle size of steel slag, reaction time and reaction temperature are investigated to determine the optimum conditions. As a result, the dissolution rate can be determined by changing the parameters, such as concentration of hydrochloric acid, particle size of steel slag, reaction time and reaction temperature. The optimum conditions for dissolution rates for the leaching process is at 3.0 M hydrochloric acid, particle size of 1.18 mm, reaction time of 2.5 hour and the temperature of 90°C.

Friction and Braking Application of Unhazardous Palm Slag Brake Pad Composite

NASA Astrophysics Data System (ADS)

Khoni, Norizzahthul Ainaa Abdul; Ruzaidi Ghazali, Che Mohd; Bakri Abdullah, Mohd Mustafa Al

2018-03-01

This paper reveals new alternative friction materials for brake pads. Palm slag was studied as new friction materials in brake pads but its much harder made it difficult to be applied. As a way to reduce the hardness, tire dust was including as purpose on stabilizing the hardness of brake pads. The palm slag was sieves to get desired size that is 150 μm, 300 μm and 600 μm. The percentage weight of materials used are 20% graphite, 20% aluminium oxide, 20% steel fiber, 20% polyester resin and another 40% are varied between tire dust and palm slag. All of materials were blend and compress by using hot pressed machine. The composites properties that were examined are density, porosity, hardness, compressive strength, microstructure analysis and wear rate. The composition of 30% palm slag, 10% tire dust and larger size of filler give better result of mechanical properties and less wear rate of brake pads composites. Then, palm slag can be used in producing of non asbestos brake pads.

Crystallization Behavior of Copper Smelter Slag During Molten Oxidation

NASA Astrophysics Data System (ADS)

Fan, Yong; Shibata, Etsuro; Iizuka, Atsushi; Nakamura, Takashi

2015-10-01

Copper slag is composed of iron silicate obtained by smelting copper concentrate and silica flux. One of the most important criteria for the utilization of this secondary resource is the recovery of iron from the slag matrix to decrease the volume of dumped slag. The molten oxidation process with crushing magnetic separation appears to be a more sustainable approach and is based on directly blowing oxidizing gas onto molten slag after the copper smelting process. In the current study, using an infrared furnace, the crystallization behavior of the slag during molten oxidation was studied to better understand the trade-off between magnetite and hematite precipitations, as assessed by X-ray diffraction (using an internal standard). Furthermore, the crystal morphology was examined using a laser microscope and Raman imaging system to understand the iron oxide transformation, and the distribution of impurities such as Cu, Zn, As, Cr, and Pb were complemented with scanning electron microscopy and energy dispersive spectroscopy. In addition, the reaction mechanism was investigated with a focus on the oxidation processes.

Effect of Liquid Viscosity on Dispersion of Quasi-Lamb Waves in an Elastic-Layer-Viscous-Liquid-Layer System

NASA Astrophysics Data System (ADS)

Guz, A. N.; Bagno, A. M.

2017-07-01

The dispersion curves are constructed and propagation of quasi-Lamb waves are studied for wide range of frequencies based on the Navier -Stokes three-dimensional linearized equations for a viscous liquid and linear equations of the classical theory of elasticity for an elastic layer. For a thick liquid layer, the effect of the viscosity of the liquid and the thickness of elastic and liquid layers on the phase velocities and attenuation coefficients of quasi-Lamb modes is analyzed. It is shown that in the case of a thick liquid layer for all modes, there are elastic layers of certain thickness with minimal effect of liquid viscosity on the phase velocities and attenuation coefficients of modes. It is also discovered that for some modes, there are both certain thicknesses and certain ranges of thickness where the effect of liquid viscosity on the phase velocities and attenuation coefficients of these modes is considerable. We ascertain that liquid viscosity promotes decrease of the penetration depth of the lowest quasi-Lamb mode into the liquid. The developed approach and the obtained results make it possible to ascertain for wave processes the limits of applicability of the model of ideal compressible fluid. Numerical results in the form of graphs are adduced and analyzed.

Crystallization phenomena in slags

NASA Astrophysics Data System (ADS)

Orrling, Carl Folke

2000-09-01

The crystallization of the mold slag affects both the heat transfer and the lubrication between the mold and the strand in continuous casting of steel. In order for mold slag design to become an engineering science rather than an empirical exercise, a fundamental understanding of the melting and solidification behavior of a slag must be developed. Thus it is necessary to be able to quantify the phenomena that occur under the thermal conditions that are found in the mold of a continuous caster. The double hot thermocouple technique (DHTT) and the Confocal Laser Scanning Microscope used in this study are two novel techniques for investigating melting and solidification phenomena of transparent slags. Results from these techniques are useful in defining the phenomena that occur when the slag film infiltrates between the mold and the shell of the casting. TTT diagrams were obtained for various slags and indicated that the onset of crystallization is a function of cooling rate and slag chemistry. Crystal morphology was found to be dependent upon the experimental temperature and four different morphologies were classified based upon the degree of melt undercooling. Continuous cooling experiments were carried out to develop CCT diagrams and it was found that the amount and appearance of the crystalline fraction greatly depends on the cooling conditions. The DHTT can also be used to mimic the cooling profile encountered by the slag in the mold of a continuous caster. In this differential cooling mode (DCT), it was found that the details of the cooling rate determine the actual response of the slag to a thermal gradient and small changes can lead to significantly different results. Crystal growth rates were measured and found to be in the range between 0.11 mum/s to 11.73 mum/s depending on temperature and slag chemistry. Alumina particles were found to be effective innoculants in oxide melts reducing the incubation time for the onset of crystallization and also extending the temperature range of observed crystallization. The effect of changing the gas atmosphere surrounding the sample has been studied. The presence of water vapor increased the nucleation rate and crystal growth rate significantly when compared to experiments carried out in a dry atmosphere. With an atmosphere of Argon and Argon-3% Hydrogen mixture, the incubation time for crystallization was increased with several minutes. The crystal growth rate in these atmospheres was also drastically reduced compared to an atmosphere of normal air. Significant numbers of bubbles were formed during the initial melting of mold slag samples and the melting rate of the slag was found to be related to the rate of bubble generation and to the rate of heat transport.

Leaching modelling of slurry-phase carbonated steel slag.

PubMed

Costa, G; Polettini, A; Pomi, R; Stramazzo, A

2016-01-25

In the present work the influence of accelerated mineral carbonation on the leaching behaviour of basic oxygen furnace steel slag was investigated. The environmental behaviour of the material as evaluated through the release of major elements and toxic metals under varying pH conditions was the main focus of the study. Geochemical modelling of the eluates was used to derive a theoretical description of the underlying leaching phenomena for the carbonated material as compared to the original slag. Among the investigated elements, Ca and Si were most appreciably affected by carbonation. A very clear effect of carbonation on leaching was observed for silicate phases, and lower-Ca/Si-ratio minerals were found to control leaching in carbonated slag eluates as compared to the corresponding untreated slag sample as a result of Ca depletion from the residual slag particles. Clear evidence was also gained of solubility control for Ca, Mg and Mn by a number of carbonate minerals, indicating a significant involvement of the original slag constituents in the carbonation process. The release of toxic metals (Zn, V, Cr, Mo) was found to be variously affected by carbonation, owing to different mechanisms including pH changes, dissolution/precipitation of carbonates as well as sorption onto reactive mineral surfaces. The leaching test results were used to derive further considerations on the expected metal release levels on the basis of specific assumptions on the relevant pH domains for the untreated and carbonated slag. Copyright © 2015 Elsevier B.V. All rights reserved.

Effect of blast furnace slag on self-healing of microcracks in cementitious materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, Haoliang, E-mail: haoliang.huang@tudelft.nl; Ye, Guang; Magnel Laboratory for Concrete Research, Department of Structural Engineering, Ghent University

The physico-chemical process of self-healing in blast furnace slag cement paste was investigated in this paper. With a high slag content i.e., 66% in cement paste and saturated Ca(OH)₂ solution as activator, it was found that the reaction products formed in cracks are composed of C-S-H, ettringite, hydrogarnet and OH–hydrotalcite. The fraction of C-S-H in the reaction products is much larger than the other minerals. Large amount of ettringite formed in cracks indicates the leaching of SO₄⁻² ions from the bulk paste and consequently the recrystallization. Self-healing proceeds fast within 50 h and then slows down. According to thermodynamic modeling,more » when the newly formed reaction products are carbonated, the filling fraction of crack increases first and then decreases. Low soluble minerals such as silica gel, gibbsite and calcite are formed. Compared to Portland cement paste, the potential of self-healing in slag cement paste is higher when the percentage of slag is high. Highlights: • Self-healing reaction products in slag cement paste were characterized. • Self-healing reaction products formed in time were quantified with image analysis. • Self-healing in slag cement paste was simulated with a reactive transport model. • Effect of carbonation on self-healing was investigated by thermodynamic modeling. • Effect of slag on self-healing was discussed based on experiments and simulation.« less

Toxicity assessment and geochemical model of chromium leaching from AOD slag.

PubMed

Liu, Bao; Li, Junguo; Zeng, Yanan; Wang, Ziming

2016-02-01

AOD (Argon Oxygen Decarburization) slag is a by-product of the stainless steel refining process. The leaching toxicity of chromium from AOD slag cannot be ignored in the recycling process of the AOD slag. To assess the leaching toxicity of the AOD slag, batch leaching tests have been performed. PHREEQC simulations combined with FactSage were carried out based on the detailed mineralogical analysis and petrophysical data. Moreover, Pourbaix diagram of the Cr-H2O system was protracted by HSC 5.0 software to explore the chromium speciation in leachates. It was found that AOD slag leachate is an alkaline and reductive solution. The Pourbaix diagram of the Cr-H2O system indicated that trivalent chromium, such as Cr(OH)4(-), is the major chromium species in the experimental Eh-pH region considered. However, toxic hexavalent chromium was released with maximum concentrations of 30 µg L(-1) and 18 µg L(-1) at L/S 10 and 100, respectively, during the earlier leaching stage. It concluded that the AOD slag possessed a certain leaching toxicity. After 10 d of leaching, trivalent chromium was the dominant species in the leachates, which corresponded to the results of PHREEQC simulation. Leaching toxicity of AOD slag is based on the chromium speciation and its transformation. Great attention should be focused on such factors as aging, crystal form of chromium-enriched minerals, and electrochemical characteristics of the leachates. Copyright © 2015 Elsevier Ltd. All rights reserved.

Determining the slag fraction, water/binder ratio and degree of hydration in hardened cement pastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yio, M.H.N., E-mail: marcus.yio11@imperial.ac.uk; Phelan, J.C.; Wong, H.S.

2014-02-15

A method for determining the original mix composition of hardened slag-blended cement-based materials based on analysis of backscattered electron images combined with loss on ignition measurements is presented. The method does not require comparison to reference standards or prior knowledge of the composition of the binders used. Therefore, it is well-suited for application to real structures. The method is also able to calculate the degrees of reaction of slag and cement. Results obtained from an experimental study involving sixty samples with a wide range of water/binder (w/b) ratios (0.30 to 0.50), slag/binder ratios (0 to 0.6) and curing ages (3more » days to 1 year) show that the method is very promising. The mean absolute errors for the estimated slag, water and cement contents (kg/m{sup 3}), w/b and s/b ratios were 9.1%, 1.5%, 2.5%, 4.7% and 8.7%, respectively. 91% of the estimated w/b ratios were within 0.036 of the actual values. -- Highlights: •A new method for estimating w/b ratio and slag content in cement pastes is proposed. •The method is also able to calculate the degrees of reaction of slag and cement. •Reference standards or prior knowledge of the binder composition are not required. •The method was tested on samples with varying w/b ratios and slag content.« less

Evaluation of novel reactive MgO activated slag binder for the immobilisation of lead and zinc.

PubMed

Jin, Fei; Al-Tabbaa, Abir

2014-12-01

Although Portland cement is the most widely used binder in the stabilisation/solidification (S/S) processes, slag-based binders have gained significant attention recently due to their economic and environmental merits. In the present study, a novel binder, reactive MgO activated slag, is compared with hydrated lime activated slag in the immobilisation of lead and zinc. A series of lead or zinc-doped pastes and mortars were prepared with metal to binder ratio from 0.25% to 1%. The hydration products and microstructure were studied by X-ray diffraction, thermogravimetric analysis and scanning electron microscopy. The major hydration products were calcium silicate hydrate and hydrotalcite-like phases. The unconfined compressive strength was measured up to 160 d. Findings show that lead had a slight influence on the strength of MgO-slag paste while zinc reduced the strength significantly as its concentration increased. Leachate results using the TCLP tests revealed that the immobilisation degree was dependent on the pH and reactive MgO activated slag showed an increased pH buffering capacity, and thus improved the immobilisation efficiency compared to lime activated slag. It was proposed that zinc was mainly immobilised within the structure of the hydrotalcite-like phases or in the form of calcium zincate, while lead was primarily precipitated as the hydroxide. It is concluded, therefore, that reactive MgO activated slag can serve as clinker-free alternative binder in the S/S process. Copyright © 2014 Elsevier Ltd. All rights reserved.

Three-Dimensional Mathematical Model of Oxygen Transport Behavior in Electroslag Remelting Process

NASA Astrophysics Data System (ADS)

Huang, Xuechi; Li, Baokuan; Liu, Zhongqiu

2018-04-01

A transient three-dimensional model has been proposed to investigate the oxygen transport behavior in electroslag remelting process. The electromagnetism, heat transfer, multiphase flow, and species transport were calculated simultaneously by finite volume method. The volume of fluid approach was adopted to trace the metal-slag-air three-phase flow. Based on the necessary thermodynamics of oxygen transport behavior, a kinetic model was established to predict the mass source terms in species transport equation. The kinetic correction factor was proposed to account for the effect of the oxide scale formed on the electrode on the FeO content in slag. Finally, the effect of applied current on the oxygen transfer was studied. The predicted result agrees well with the measured data when the kinetic correction factor is set to be 0.5. The temperature distribution that affects the thermodynamics differs at the interfaces. The oxygen in air is absorbed into slag due to the oxidation at the slag/air interface. The Fe2O3 in slag and the oxide scale contribute to the increase of FeO content in slag, and the latter one plays the leading role. The oxygen transfer from slag to metal mainly occurs during the formation of the droplet at the slag/metal droplet interface. With the current increasing from 1200 to 1800 A, the oxygen content increases from 76.4 to 89.8 ppm, and then slightly declines to 89.2 ppm when the current increases to 2100 A.

Experimental and Theoretical Studies on the Viscosity-Structure Correlation for High Alumina-Silicate Melts

NASA Astrophysics Data System (ADS)

Talapaneni, Trinath; Yedla, Natraj; Pal, Snehanshu; Sarkar, Smarajit

2017-06-01

Blast furnaces are encountering high Alumina (Al2O3 > 25 pct) in the final slag due to the charging of low-grade ores. To study the viscosity behavior of such high alumina slags, synthetic slags are prepared in the laboratory scale by maintaining a chemical composition of Al2O3 (25 to 30 wt pct) CaO/SiO2 ratio (0.8 to 1.6) and MgO (8 to 16 wt pct). A chemical thermodynamic software FactSage 7.0 is used to predict liquidus temperature and viscosity of the above slags. Experimental viscosity measurements are performed above the liquidus temperature in the range of 1748 K to 1848 K (1475 °C to 1575 °C). The viscosity values obtained from FactSage closely fit with the experimental values. The viscosity and the slag structure properties are intent by Fourier Transform Infrared (FTIR) and Raman spectroscopy. It is observed that increase in CaO/SiO2 ratio and MgO content in the slag depolymerizes the silicate structure. This leads to decrease in viscosity and activation energy (167 to 149 kJ/mol) of the slag. Also, an addition of Al2O3 content increases the viscosity of slag by polymerization of alumino-silicate structure and activation energy from 154 to 161 kJ/mol. It is witnessed that the activation energy values obtained from experiment closely fit with the Shankar model based on Arrhenius equation.

Reproducing ten years of road ageing--accelerated carbonation and leaching of EAF steel slag.

PubMed

Suer, Pascal; Lindqvist, Jan-Erik; Arm, Maria; Frogner-Kockum, Paul

2009-09-01

Reuse of industrial aggregates is still hindered by concern for their long-term properties. This paper proposes a laboratory method for accelerated ageing of steel slag, to predict environmental and technical properties, starting from fresh slag. Ageing processes in a 10-year old asphalt road with steel slag of electric arc furnace (EAF) type in the subbase were identified by scanning electron microscopy (SEM) and leaching tests. Samples from the road centre and the pavement edge were compared with each other and with samples of fresh slag. It was found that slag from the pavement edge showed traces of carbonation and leaching processes, whereas the road centre material was nearly identical to fresh slag, in spite of an accessible particle structure. Batches of moisturized road centre material exposed to oxygen, nitrogen or carbon dioxide (CO2) were used for accelerated ageing. Time (7-14 days), temperature (20-40 degrees C) and initial slag moisture content (8-20%) were varied to achieve the carbonation (decrease in pH) and leaching that was observed in the pavement edge material. After ageing, water was added to assess leaching of metals and macroelements. 12% moisture, CO2 and seven days at 40 degrees C gave the lowest pH value. This also reproduced the observed ageing effect for Ca, Cu, Ba, Fe, Mn, Pb, Ca (decreased leaching) and for V, Si, and Al (increased leaching). However, ageing effects on SO4, DOC and Cr were not reproduced.

Multiple model approach to evaluation of accelerated carbonation for steelmaking slag in a slurry reactor.

PubMed

Pan, Shu-Yuan; Liu, Hsing-Lu; Chang, E-E; Kim, Hyunook; Chen, Yi-Hung; Chiang, Pen-Chi

2016-07-01

Basic oxygen furnace slag (BOFS) exhibits highly alkaline properties due to its high calcium content, which is beneficial to carbonation reaction. In this study, accelerated carbonation of BOFS was evaluated under different reaction times, temperatures, and liquid-to-solid (L/S) ratios in a slurry reactor. CO2 mass balance within the slurry reactor was carried out to validate the technical feasibility of fixing gaseous CO2 into solid precipitates. After that, a multiple model approach, i.e., theoretical kinetics and empirical surface model, for carbonation reaction was presented to determine the maximal carbonation conversion of BOFS in a slurry reactor. On one hand, the reaction kinetics of BOFS carbonation was evaluated by the shrinking core model (SCM). Calcite (CaCO3) was identified as a reaction product through the scanning electronic microscopy and X-ray diffraction analyses, which provided the rationale of applying the SCM in this study. The rate-limiting step of carbonation was found to be ash-diffusion controlled, and the effective diffusivity for carbonation of BOFS in a slurry reactor were determined accordingly. On the other hand, the carbonation conversion of BOFS was predicted by the response surface methodology (RSM) via a nonlinear mathematical programming. According to the experimental data, the highest carbonation conversion of BOFS achieved was 57% under an L/S ratio of 20 mL g(-1), a CO2 flow rate of 0.1 L min(-1), and a pressure of 101.3 kPa at 50 °C for 120 min. Furthermore, the applications and limitations of SCM and RSM were examined and exemplified by the carbonation of steelmaking slags. Copyright © 2016 Elsevier Ltd. All rights reserved.

Deoxidation Limits of Titanium Alloys during Pressure Electro Slag Remelting

NASA Astrophysics Data System (ADS)

Bartosinski, M.; Hassan-Pour, S.; Friedrich, B.; Ratiev, S.; Ryabtsev, A.

2016-07-01

This paper focuses on deoxidation of titanium alloys produced by aluminothermic reduction (ATR) and subsequent homogenizing and alloying by vacuum induction melting (VIM). The main goal of the performed research work is to outline the deoxidation limit during pressure electro slag remelting (PESR) of the described material. To obtain electrodes for deoxidation, a Ti-24Al-16V masteralloy was produced by ATR and afterwards melted in a 0.5 litre calcium- zirconate (lab scale) or 14 litres high purity calcia (pilot scale) crucibles with continuous addition of Ti-sponge after reaching liquid state in order to obtain a final Ti-6Al-4V alloy. During melting, in both cases evaporation of calcium was noticed. The cast ingots were analysed for oxygen using inert gas fusion method, matrix and alloying elements were analysed by XRF. Results show oxygen levels between 0.5 and 0.95 wt.-% for the ingots which were melted in calcium-zirconate crucibles and approx. 1 - 1.2 wt.-% for the material produced by utilization of calcia crucibles. The subsequent deoxidation was carried out in lab and pilot scale electroslag remelting furnaces using a commercially pure calcium fluoride slag and metallic calcium as deoxidation agent. It could be shown, that deoxidation of the highly contaminated material is possible applying this method to a certain limit. Pilot scale trials showed a reduction of oxygen contents by 1500 - 3500 ppm. Oxygen levels in lab scale trials showed weaker deoxidation effects. In order to describe the achieved deoxidation effects in a quantitative way, the analyzed oxygen contents of the obtained ingots are compared with calculated data resulting from a mathematical kinetic model. The modelled datasets are in good agreement with experimental oxygen values.

Experimental Phase Equilibria Studies of the Pb-Fe-O System in Air, in Equilibrium with Metallic Lead and at Intermediate Oxygen Potentials

NASA Astrophysics Data System (ADS)

Shevchenko, M.; Jak, E.

2017-12-01

The phase equilibria information on the Pb-Fe-O system is of practical importance for the improvement of the existing thermodynamic database of lead-containing slag systems (Pb-Zn-Fe-Cu-Si-Ca-Al-Mg-O). Phase equilibria of the Pb-Fe-O system have been investigated: (a) in air at temperatures between 1053 K and 1373 K (780 °C and 1100 °C); (b) in equilibrium with metallic lead at temperatures between 1053 K and 1373 K (780 °C and 1100 °C); and (c) at intermediate oxidation conditions for the liquid slag in equilibrium with two solids (spinel + magnetoplumbite), at temperatures between 1093 K and 1373 K (820 °C and 1100 °C). The high-temperature equilibration/quenching/electron probe X-ray microanalysis technique has been used to accurately determine the compositions of the phases in equilibrium in the system. The Pb and Fe concentrations in the phases were determined directly; preliminary thermodynamic modeling with FactSage was used to estimate the ferrous-to-ferric ratios and to present the results in the ternary diagram.

Effects of Al2O3 and CaO/SiO2 Ratio on Phase Equilbria in the ZnO-"FeO"-Al2O3-CaO-SiO2 System in Equilibrium with Metallic Iron

NASA Astrophysics Data System (ADS)

Zhao, Baojun; Hayes, Peter C.; Jak, Evgueni

2011-02-01

The phase equilibria and liquidus temperatures in the ZnO-"FeO"-Al2O3-CaO-SiO2 system in equilibrium with metallic iron have been determined experimentally in the temperature range 1383 K to 1573 K (1150 °C to 1300 °C). The experimental conditions were selected to characterize lead blast furnace and imperial smelting furnace slags. The results are presented in a form of pseudoternary sections ZnO-"FeO"-(Al2O3 + CaO + SiO2) with fixed CaO/SiO2 and (CaO + SiO2)/Al2O3 ratios. It was found that wustite and spinel are the major primary phases in the composition range investigated. Effects of Al2O3 concentration as well as the CaO/SiO2 ratio on the primary phase field, the liquidus temperature, and the partitioning of ZnO between liquid and solid phases have been discussed for zinc-containing slags.

Phase Equilibria Studies in the System ZnO-``FeO''-Al2O3-CaO-SiO2 Relevant to Imperial Smelting Furnace Slags: Part I

NASA Astrophysics Data System (ADS)

Zhao, Baojun; Hayes, Peter C.; Jak, Evgueni

2010-04-01

The phase equilibria and liquidus temperatures in the system ZnO-“FeO”-Al2O3-CaO-SiO2 in equilibrium with metallic iron have been determined experimentally in the temperature range of 1423 K to 1553 K. The experimental conditions were focused on the composition range relevant to Imperial Smelting Furnace slags. The results are presented in the form of a pseudo-ternary section ZnO-“FeO”-(CaO + SiO2 + Al2O3) in which CaO/SiO2 = 0.93 and (CaO + SiO2)/Al2O3 = 7.0. It was found that wustite and spinel are the major primary phases and that zincite and melilite are also present in the composition range investigated. Wustite (Fe2+,Zn)O and spinel (Fe2+,Zn)O (A1,Fe3+)2O3 solid solutions are formed in this system, and the ZnO concentration in the spinel phase is found to be much greater than in the liquid phase.

Investigation of Use of Slag Aggregates and Slag Cements in Concrete Pavements to Reduce the Maintenance Cost

DOT National Transportation Integrated Search

2017-12-01

The objective of this research was to evaluate the influence of using the ACBFS aggregate (slag aggregate) as a replacement for natural aggregates on the properties of pavement concrete designed to meet the standard specifications of the Indiana Depa...

54. View from southeast of KinneyOsborne slag granulator at right ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

54. View from southeast of Kinney-Osborne slag granulator at right and stack at left that vented steam generated when water was sprayed on hot slag to solidify and fracture it. - Sloss-Sheffield Steel & Iron, First Avenue North Viaduct at Thirty-second Street, Birmingham, Jefferson County, AL

Basalt Fiber for Volcanic Slag Lightweight Aggregate Concrete Research on the Impact of Performance

NASA Astrophysics Data System (ADS)

Xiao, Li-guang; Li, Gen-zhuang

2018-03-01

In order to study the effect of basalt fiber on the mechanical properties and durability of volcanic slag lightweight aggregate concrete, the experimental study on the flexural strength, compressive strength and freeze-thaw resistance of volcanic slag concrete with different basalt fiber content were carried out, the basalt fiber was surface treated with NaOH and water glass, the results show that the surface treatment of basalt fiber can significantly improve the mechanical properties, durability and other properties of volcanic slag lightweight aggregate concrete.

Optical Measurements on Solid Specimens of Solid Rocket Motor Exhaust and Solid Rocket Motor Slag

NASA Technical Reports Server (NTRS)

Roberts, F. E., III

1991-01-01

Samples of aluminum slag were investigated to aid the Earth Science and Applications Division at the Marshall Space Flight Center (MSFC). Alumina from space motor propellant exhaust and space motor propellant slag was examined as a component of space refuse. Thermal emittance and solar absorptivity measurements were taken to support their comparison with reflectance measurements derived from actual debris. To determine the similarity between the samples and space motor exhaust or space motor slag, emittance and absorbance results were correlated with an examination of specimen morphology.

The behavior of sulfur in industrial pyrometallurgical slags

NASA Astrophysics Data System (ADS)

Nagamori, Meguru

1994-08-01

Dissolution of sulfur in industrial slags, even at such a low level as 1 mass% S or so, increases the solubility of certain valuable metals by an order of magnitude. The phenomenon is accounted for in terms of Flood-Førland-Grjotheim's model for dianionic salt solutions, whereas its rigorous analysis requires the digaseous Gibbs-Duhem integration. In the research described here, the distribution of sulfur among gas, slag, and metallic iron phases in the bath smelting of iron ore was computer-simulated based on a two-sites model coupled with sulfide capacity data. The solubilities of Ag, Cu, Co, and Ni in industrial slags are reviewed by applying the sulfidic-oxidic dissolution model to copper-matte smelting, nickel-slag cleaning (Falconbridge, Canada), and the imperial smelting process for zinc and lead (Hachinohe, Japan).

Evaluation of steel slag coarse aggregate in hot mix asphalt concrete.

PubMed

Ahmedzade, Perviz; Sengoz, Burak

2009-06-15

This paper presents the influences of the utilization of steel slag as a coarse aggregate on the properties of hot mix asphalt. Four different asphalt mixtures containing two types of asphalt cement (AC-5; AC-10) and coarse aggregate (limestone; steel slag) were used to prepare Marshall specimens and to determine optimum bitumen content. Mechanical characteristics of all mixtures were evaluated by Marshall stability, indirect tensile stiffness modulus, creep stiffness, and indirect tensile strength tests. The electrical sensitivity of the specimens were also investigated in accordance with ASTM D257-91. It was observed that steel slag used as a coarse aggregate improved the mechanical properties of asphalt mixtures. Moreover, volume resistivity values demonstrated that the electrical conductivity of steel slag mixtures were better than that of limestone mixtures.

Stabilization of carbon dioxide and chromium slag via carbonation.

PubMed

Wu, Xingxing; Yu, Binbin; Xu, Wei; Fan, Zheng; Wu, Zucheng; Zhang, Huimin

2017-08-01

As the main greenhouse gas, CO 2 is considered as a threat in the context of global warming. Many available technologies to reduce CO 2 emission was about CO 2 separation from coal combustion and geological sequestration. However, how to deal with the cost-effective storage of CO 2 has become a new challenge. Moreover, chromium pollution, the treatment of which requires huge energy consumption, has attracted people's widespread attention. This study is aimed to develop the sequestration of CO 2 via chromium slag. A dynamic leaching experiment of chromium slag was designed to testify the ability of CO 2 adsorption onto chromium slag and to release Cr(VI) for stabilization. The results showed that the accumulative amounts of Cr(VI) were ca. 2.6 mg/g released from the chromium slag after 24 h of leaching. In addition, ca. 89 mg/g CO 2 was adsorbed by using pure CO 2 in the experiment at 12 h. Calcite is the only carbonate species in the post-carbonated slag analyzed by powder X-ray diffraction and thermal analysis. The approach provides the feasibility of the utilization of chromium slag and sequestration of the carbon dioxide at the same time at ordinary temperatures and pressures.

Kinetic Investigations of SiMn Slags From Different Mn Sources

NASA Astrophysics Data System (ADS)

Kim, Pyunghwa Peace; Tangstad, Merete

2018-06-01

The kinetics of MnO and SiO2 reduction were investigated for Silicomanganese (SiMn) slags using a Thermogravimetric analysis (TGA) between 1773 K and 1923 K (1500 °C and 1650 °C) under CO atmospheric pressure. The charge materials were based on Assmang ore and HC FeMn Slag. Rate models for MnO and SiO2 reduction were applied to describe the metal-producing rates, as shown by the following equations: r_{MnO} = k_{MnO} × A × ( {a_{MnO} - {a_{Mn} }/{K_{T }}} ) r_{{{SiO}2 }} = k_{SiO2} × A × ( {a_{{{SiO}2 }} - {a_{Si} }/{K_{T }}} ). The results show that the choice of raw materials in the charge considerably affected the reduction rate of MnO and SiO2. The highest reduction rate was found to be from charges using HC FeMn slag. The difference in the driving forces was insignificant among the SiMn slags, and the similar slag viscosities could not explain the different reduction rates. Instead, the difference is attributed to small amounts of sulfur and the amount of iron in the charge. In addition, the rate models were applicable to describe the reduction of MnO and SiO2 in SiMn slags.

Rehabilitating acid soils for increasing crop productivity through low-cost liming material.

PubMed

Bhat, Javid Ahmad; Kundu, Manik Chandra; Hazra, Gora Chand; Santra, Gour Hari; Mandal, Biswapati

2010-09-15

Productivity of red and lateritic soils is low because of their acidity and deficiencies in few essential nutrients viz., nitrogen, phosphorus, calcium, zinc, boron, molybdenum etc. We compared the effectiveness of basic slag, a low-cost liming material, with that of calcite as an ameliorant for these soils using mustard followed by rice as test crops. Experiments were conducted with three levels of each of basic slag and calcite along with a control on farmers' fields at 14 different locations. Influence of farmyard manure (FYM) and poultry manure (PM) on the effectiveness of the slag was also tested. On an average, basic slag performed better than calcite in increasing yields of both mustard and rice and left over higher amounts of available Ca, Si and Zn in residual soils. The slag also improved N, P, K and Ca nutrition of mustard and Si and Zn nutrition of rice with a favorable benefit:cost (B:C) ratio over the calcite (4.82 vs. 1.44). Effectiveness of the basic slag improved when it was applied in combination with FYM or PM (B:C, 5.83 and 6.27). Basic slag can, therefore, be advocated for use in the acidic red and lateritic soils for economically improving their productivity. Copyright 2010 Elsevier B.V. All rights reserved.

Steel Slag and Shredded Tires as Media for Blind Inlets to Improve Water Quality

NASA Astrophysics Data System (ADS)

Gonzalez, J. M.; Smith, D. R.; Livingston, S.

2015-12-01

Off-site transport of contaminants through surface runoff affects water quality. Blind inlets are proven conservation practices for reducing surface runoff, and consequently reducing nutrient loadings from small agricultural closed depressions to water bodies. Gravel is the most widely used blind inlet media to reduce flow, but not to sorb contaminants from the water. Readily available byproducts, such as steel slag and shredded tires, could be used as alternative media in blind inlets to sorb nutrients and pesticides from surface runoff. Sorption isotherms were performed to investigate the sorption capabilities of steel slag and shredded tires for phosphate and atrazine in electrolyte background solutions containing either 10 mM CaCl2 or KCl. Results of this research demonstrated that phosphate and atrazine were irreversibly sorbed by the steel slag and shredded tires. The steel slag increased the pH solution increased about 4 pH units after the sorption step; while the pH of the solution with shredded tires remained the same. Desorption of the phosphate and atrazine was low from the steel slag and shredded tires, respectively. Thus, the above results suggest that the steel slag and shredded tires can potentially be used as media to sorb phosphate and atrazine, respectively.

Alteration of municipal and industrial slags under atmospheric conditions

NASA Astrophysics Data System (ADS)

Rafał Kowalski, Piotr; Michalik, Marek

2014-05-01

The Waste Management System in Poland is being consequently built since 1998. After important changes in legislation, local governments have taken over the duty of waste collection. New points of selective collection of wastes have been opened and new sorting and composting plants were built. The last stage of introducing the Waste Management System is construction of waste incineration power plants. From nine installations which were planned, six are now under construction and they will start operating within the next two years. It is assumed that the consumption of raw wastes for these installations will reach 974 thousand tons per year. These investments will result in increased slags and ashes production. Now in Poland several local waste incinerators are operating and predominant amount of produced incineration residues is landfilled. These materials are exposed to atmospheric conditions in time of short term storage (just after incineration) and afterwards for a longer period of time on the landfill site. During the storage of slags low temperature mineral transformations and chemical changes may occur and also some components can be washed out. These materials are stored wet because of the technological processes. The aim of this study is to investigate the influence of storage in atmospheric conditions on slags from incineration of industrial and municipal wastes. The experiment started in January 2013. During this period slag samples from incineration of industrial and municipal wastes were exposed to atmospheric conditions. Samples were collected after 6 and 12 months. Within this time the pH value was measured monthly, and during the experimental period remained constant on the level of 9.5. After 6 months of exposure only slight changes in mineral compositions were observed in slags. The results of XRD analysis of municipal slags showed increase in content of carbonate minerals in comparison to the raw slag samples. In industrial slags, a decrease in content of soluble minerals, like halite, in comparison to the output samples was noted. These phases where probably dissolved and washed out from the samples. After 12 months of atmospheric exposure in municipal slags only slight changes in weight (1 wt%) were observed, whereas in industrial slags slightly above 10 wt% of the material was removed. After 12 months of atmospheric exposure more significant changes are expected such as changes in chemical and mineral compositions and changes in heavy metals and toxic elements concentrations due to leaching.

Surface order in cold liquids: X-ray reflectivity studies of dielectric liquids and comparison to liquid metals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chattopadhyay, S.; Ehrlich, S.; Uysal, A.

2010-05-17

Oscillatory surface-density profiles layers have previously been reported in several metallic liquids, one dielectric liquid, and in computer simulations of dielectric liquids. We have now seen surface layers in two other dielectric liquids, pentaphenyl trimethyl trisiloxane, and pentavinyl pentamethyl cyclopentasiloxane. These layers appear below T?285 K and T?130 K, respectively; both thresholds correspond to T/Tc?0.2 where Tc is the liquid-gas critical temperature. All metallic and dielectric liquid surfaces previously studied are also consistent with the existence of this T/Tc threshold, first indicated by the simulations of Chacon et al. The layer width parameters, determined using a distorted-crystal fitting model, followmore » common trends as functions of Tc for both metallic and dielectric liquids.« less

Effective removal of cesium from wastewater solutions using an innovative low-cost adsorbent developed from sewage sludge molten slag.

PubMed

Khandaker, Shahjalal; Toyohara, Yusaku; Kamida, Seiya; Kuba, Takahiro

2018-06-01

This study investigates the effective removal of cesium (Cs) from aqueous solution using sewage sludge molten (SSM) slag that has undergone the surface modification with alkali (NaOH) hydrothermal treatment. The raw and modified slags were characterised systematically using the BET method, the FESEM, the XRF, the XRD spectroscopy and the CEC analysis to understand the physicochemical changes of the materials, and its sensitivity to Cs ions adsorption. Batch adsorption experiments were carried out to investigate the effects of adsorbent dose, contact time, solution pH, different initial Cs concentrations, temperature and the effect of competitive ions on Cs adsorption. The adsorption isotherm, kinetic and thermodynamic studies were also evaluated based on the experimental results. A higher Cs removal efficiency of almost 100% (for 20-100 mg/L of initial concentration) was achieved by the modified SSM slag, and the maximum adsorption capacity was found to be 52.36 mg/g. Several types of synthetic zeolites such as zeolite X, zeolite Y, zeolite A, and sodalite were formed on surface of the modified slag through the modification process which might be enhanced the Cs adsorption capacity. Kinetic parameters were fitted by the pseudo-second order model. The adsorption isotherms data of modified slag were well-fitted to the Langmuir (R 2  = 0.989) and Freundlich isotherms (R 2  = 0.988). The thermodynamic studies indicated that the adsorption process by the modified slag was spontaneous and exothermic. In the competitive ions effect, the modified slag effectively captured the Cs ion in the presence of Na + and K + , especially at their lower concentrations. Moreover, the modified slag was reused for several cycles after the successful elution process with an appropriate eluting agent (0.5 M H 2 SO 4 ), without deterioration of its original performance. Therefore, the SSM modified slag could be effectively used as a low-cost potential adsorbent for high Cs adsorption from wastewater. Copyright © 2018 Elsevier Ltd. All rights reserved.

Characterization of the lead smelter slag in Santo Amaro, Bahia, Brazil.

PubMed

Lima, L R P de Andrade; Bernardez, L A

2011-05-30

For 33 years, a primary lead smelter operated in Santo Amaro (Brazil). Since the 1970s, large amounts of Pb and Cd have been widely documented in the blood and hair of people living near the smelter. The plant closed down in 1993, and several years later, the Pb levels in the blood of children under 4 years of age living near the smelter were high, where the disposed lead slag was suspected to be the main source of this contamination. The objective of this study is to elucidate the source of the Pb contamination and any other potentially toxic contamination, focusing on the characterization of the slag. The samples used for this characterization study were taken from the slag heaps. The results of the chemical analysis showed that the major constituents of the slag, in decreasing order of wt%, were the following: Fe(2)O(3) (28.10), CaO (23.11), SiO(2) (21.39), ZnO (9.47), MgO (5.44), PbO (4.06), Al(2)O(3) (3.56), C (2.26), MnO (1.44), Na(2)O (0.27), S (0.37), K(2)O (0.26), and TiO(2) (0.25). The Cd content of the slag was 57.3mg/kg, which is relatively low. The X-ray diffraction and the electron probe microanalyzer X-ray mapping indicated that the major phases in the slag were wüstite, olivine, kirschsteinite, and franklinite. Only spheroidal metallic Pb was found in the slag. The leaching study showed that the slag was stable at a pH greater than 2.8, and only in an extremely acidic environment was the solubilization of the Pb enhanced significantly. The solubilization of Zn was very limited in the acidic and alkaline environments. These results can be explained by the limited leachability of the metallic Pb and Zn-bearing compounds. The leaching study used TCLP, SPLP, and SWEP and indicated that the lead slag was stable in weak acidic environments for short contact times. Copyright © 2011 Elsevier B.V. All rights reserved.

Leaching Behavior of Slags from AN Old Lead Smelter in Chihuahua, Mexico: Metals, Chlorides, Nitrates, Sulfates and Tds Analyses

NASA Astrophysics Data System (ADS)

Espejel-Garcia, D.; Wenglas-Lara, G.; Villalobos-Aragon, A.; Espejel-Garcia, V. V.

2013-05-01

Waste materials (such as, smelter slags, waste glass, tires, plastics, rubbish, ashes, etc.), have a large potential to substitute natural materials, reducing costs, especially for the construction industry. Smelter slags are resistant and have better compression strength values in comparison to natural aggregates, and generally are far beyond of what the standard ratios need to qualify a material as a good one for construction. But this material has a big problem within it: the existence of toxic elements and compounds in high concentrations, which means that water and soil contamination can be present after water infiltrates through this material; so we perform leaching experiments to characterize and measure the possible contamination under controlled conditions. To perform the slags-leaching experiments, we used an EA-NEN-7375-2004 tank test standard from Netherlands. This test was selected because to our knowledge it is the only one which allows the use of coarse material, as the one utilized in construction. The leaching experiments sampling was performed at different times: 6, 24, 168 and 360 hours, to compare the leachate concentration at the two different pH's values (5 and 8) selected to simulate real conditions. For the leaching experiments, the slags were mixed with natural road base material (gravel-sands from volcanic rocks) at different proportions of 30% and 50%. In order to understand the slags' leaching behavior, other experiments were carried out with the pure material, for both (slags and natural aggregates). After analyses by ICP-OES , the slags from this smelter in Chihuahua contain Pb (0.5 - 4 wt.%), Zn (15-35 wt.%) and As (0.6 wt.%), as well such as: bicarbonates, chlorides, nitrates, sulfates, Mg, K, Na, Ca and TDS. Based on the results of the leaching analyses, via atomic absorption technique, we conclude that Pb and As concentrations are provided by the slags, meanwhile, the bicarbonates, chlorides, Na and Ca are contributed by the road base natural materials. Summarizing, he possibility exists to use the slags as a minor constituent (<30%) in road base materials.

Reconstruction of the inner structure of small scale mining waste dumps by combining GPR and ERTdata.

NASA Astrophysics Data System (ADS)

Kniess, Rudolf; Martin, Tina

2015-04-01

Two abandoned small waste dumps in the west of the Harz mountains (Germany) were analysed using ground penetrating radar (GPR) and electrical resistivity tomography (ERT). Aim of the project (ROBEHA, funded by the German Federal Ministry of Education and Research (033R105)) is the assessment of the recycling potential of the mining residues taking into account environmental risks of reworking the dump site. One task of the geophysical prospection is the investigation of the inner structure of the mining dump. This is important for the estimation of the approximate volume of potentially reusable mining deposits within the waste dump. The two investigated dump sites are different in age and therefore differ in their structure. The older residues (< 1930) consist of ore processing waste from density separation (stamp mill sand). The younger dump site descends from comprises slag dump waste. The layer of fine grained residues at the first dump site is less than 6 m thick and the slag layer is less than 2 m thick. Both sites are partially overlain by forest or grassland vegetation and characterized by topographical irregularities. Due to the inhomogeneity of the sites we applied electrical resistivity tomography (ERT) and ground penetrating radar (GPR) for detailed investigation. Using ERT we could distinguish various layers within the mining dumps. The resistivities of the dumped material differ from the bedrock resistivities at both sites. The GPR measurements show near surface layer boundaries down to 3 - 4 m. In consecutive campaigns 100 MHz and 200 MHz antennas were used. The GPR results (layer boundaries) were included into the ERT inversion algorithm to enable more precise and stable resistivity models. This needs some special preprocessing steps. The 3D-Position of every electrode from ERT measurement and the GPR antenna position on the surface require an accuracy of less than 1cm. At some points, the layer boundaries and radar wave velocities can be calibrated with borehole stratigraphic data from a mineralogical drilling campaign. This is important for a precise time-depth conversion of reflectors from GPR measurement. This reflectors were taken from radargram and have been adopted as resistivity boundary in the start model of the geoelectric inversion algorithm.

In situ stabilization of trace metals in a copper-contaminated soil using P-spiked Linz-Donawitz slag.

PubMed

Negim, Osama; Mench, Michel; Bes, Clémence; Motelica-Heino, Mikael; Amin, Fouad; Huneau, Frédéric; Le Coustumer, Philippe

2012-03-01

A former wood exploitation revealing high Cu and As concentration of the soils served as a case study for assisted phytoextraction. P-spiked Linz-Donawitz (LD) slag was used as a soil additive to improve physico-chemical soil properties and in situ stabilize Cu and other trace metals in a sandy Cu-contaminated soil (630 mg kg⁻¹ soil). The LD slag was incorporated into the contaminated soil to consist four treatments: 0% (T1), 1% (T2), 2% (T3), and 4% (T4). A similar uncontaminated soil was used as a control (CTRL). After a 1-month reaction period, potted soils were used for a 2-week growth experiment with dwarf beans. Soil pH increased with the incorporation rate of LD slag. Similarly the soil electrical conductivity (EC, in millisiemens per centimetre) is ameliorated. Bean plants grown on the untreated soil (T1) showed a high phytotoxicity. All incorporation rates of LD slag increased the root and shoot dry weight yields compared to the T1. The foliar Ca concentration of beans was enhanced for all LD slag-amended soil, while the foliar Mg, K, and P concentrations were not increased. Foliar Cu, Zn, and Cr concentrations of beans decreased with the LD slag incorporation rate. P-spiked LD slag incorporation into polluted soil allow the bean growth and foliar Ca concentration, but also to reduce foliar Cu concentration below its upper critical value avoiding an excessive soil EC and Zn deficiency. This dual effect can be of interest for soil remediation at larger scale.

Simulation of primary-slag melting behavior in the cohesive zone of a blast furnace, considering the effect of Al{sub 2}O{sub 3}, Fe{sub t}O, and basicity in the sinter ore

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hino, Mitsutaka; Nagasaka, Tetsuya; Katsumata, Akitoshi

1999-08-01

The alumina content in the iron ore imported to Japan is increasing year by year, and some problems in blast furnace operation, due to the use of the high-alumina-containing sinter, have already been reported. In order to clarify the mechanism of the harmful effect of alumina on the blast furnace operation, the behavior of the primary melt, which is formed in the sinter at the cohesive zone of the blast furnace, has been simulated by dripping slag through an iron or oxide funnel. The effects of basicity, Al{sub 2}O{sub 3}, and Fe{sub t}O contents in the five slag systems onmore » the dripping temperature and weight of slag remaining on the funnel have been discussed. It was found that the eutectic melt formed in the sinter would play an important role in the dripping behavior of the slag in the blast furnace through the fine porosity of the reduced iron and ore particles. Al{sub 2}O{sub 3} increased the weight of the slag remaining on the funnel, and its effect became very significant in the acidic and low-Fe{sub t}O-containing slag. It was estimated that the increase of the weight of the slag remaining on the funnel by Al{sub 2}O{sub 3} in the ore could result in a harmful effect on the permeability resistance and an indirect reduction rate of the sinter in the blast furnace.« less

Steel slag carbonation in a flow-through reactor system: the role of fluid-flux.

PubMed

Berryman, Eleanor J; Williams-Jones, Anthony E; Migdisov, Artashes A

2015-01-01

Steel production is currently the largest industrial source of atmospheric CO2. As annual steel production continues to grow, the need for effective methods of reducing its carbon footprint increases correspondingly. The carbonation of the calcium-bearing phases in steel slag generated during basic oxygen furnace (BOF) steel production, in particular its major constituent, larnite {Ca2SiO4}, which is a structural analogue of olivine {(MgFe)2SiO4}, the main mineral subjected to natural carbonation in peridotites, offers the potential to offset some of these emissions. However, the controls on the nature and efficiency of steel slag carbonation are yet to be completely understood. Experiments were conducted exposing steel slag grains to a CO2-H2O mixture in both batch and flow-through reactors to investigate the impact of temperature, fluid flux, and reaction gradient on the dissolution and carbonation of steel slag. The results of these experiments show that dissolution and carbonation of BOF steel slag are more efficient in a flow-through reactor than in the batch reactors used in most previous studies. Moreover, they show that fluid flux needs to be optimized in addition to grain size, pressure, and temperature, in order to maximize the efficiency of carbonation. Based on these results, a two-stage reactor consisting of a high and a low fluid-flux chamber is proposed for CO2 sequestration by steel slag carbonation, allowing dissolution of the slag and precipitation of calcium carbonate to occur within a single flow-through system. Copyright © 2014. Published by Elsevier B.V.

Investigation of using steel slag in hot mix asphalt for the surface course of flexible pavements

NASA Astrophysics Data System (ADS)

Nguyen, Hien Q.; Lu, Dai X.; Le, Son D.

2018-04-01

The rapid development of heavy industry in Vietnam leads to the establishments of steel industry. Steel slag, a by-product of steelwork industry, under Vietnamese’s law, was considered as a deleterious solid waste which needed to be processed and landfilled. However, this has changed recently, and steel slag is now seen as a normal or non-deleterious solid waste, and has been studied for reuse in the construction industry. In this study, steel slag was used, as a replacement for mineral aggregate, in hot mix asphalt. Two hot mix asphalt mixtures with an equivalent nominal aggregate size of 12.5 (C12.5) and 19 mm (C19) were produced using steel slag. In addition, one conventional hot mix asphalt mixture of C19 was produced using mineral aggregate for comparison purpose. Investigation in laboratory condition and trial sections was carried out on Marshall tests, surface roughness, skid resistance, and modulus of the pavement before and after applying a new surface course of hot mix asphalt. The study showed that all steel slag asphalt mixtures passed the Marshall stability and flow test requirements. The skid resistance of steel slag hot mix asphalt mixtures for the surface course satisfied the Vietnamese specification for asphalt. Moreover, the pavement sections with the surface course of steel slag hot mix asphalt showed a considerable higher modulus than that of the conventional one. Only the roughness of the surface course paved with C19 did not pass the requirement of the specification.

Fuel injection device and method

DOEpatents

Carlson, L.W.

1983-12-21

A fuel injection system and method provide for shaping a combustion plume within a combustion chamber to effectively recirculate hot combustion gases for stable combustion conditions while providing symmetrical combustion conditions. Char and molten slag are passed to the outer boundary layer to complete combustion of char while permitting initial substoichiometric combustion in a reductive atmosphere for reducing discharge of nitrogen oxides. Shaping of the plume is accomplished by an axially adjustable pintle which permits apportionment of driving pressure between elements which contribute tangential and those which contribute radial directional components to oxidant flow entering the combustion chamber.

Fuel injection device and method

DOEpatents

Carlson, Larry W.

1986-01-01

A fuel injection system and method provide for shaping a combustion plume within a combustion chamber to effectively recirculate hot combustion gases for stable combustion conditions while providing symmetrical combustion conditions. Char and molten slag are passed to the outer boundary layer to complete combustion of char while permitting initial substoichiometric combustion in a reductive atmosphere for reducing discharge of nitrogen oxides. Shaping of the plume is accomplished by an axially adjustable pintle which permits apportionment of driving pressure between elements which contribute tangential and those which contribute radial directional components to oxidant flow entering the combustion chamber.

Fuel injection device and method

DOEpatents

Carlson, Larry W.

1986-02-04

A fuel injection system and method provide for shaping a combustion plume within a combustion chamber to effectively recirculate hot combustion gases for stable combustion conditions while providing symmetrical combustion conditions. Char and molten slag are passed to the outer boundary layer to complete combustion of char while permitting initial substoichiometric combustion in a reductive atmosphere for reducing discharge of nitrogen oxides. Shaping of the plume is accomplished by an axially adjustable pintle which permits apportionment of driving pressure between elements which contribute tangential and those which contribute radial directional components to oxidant flow entering the combustion chamber.

Thermocapillary convection in two immiscible liquid layers with free surface

NASA Technical Reports Server (NTRS)

Doi, Takao; Koster, Jean N.

1993-01-01

Thermocapillary convection is studied in two immiscible liquid layers with one free surface, one liquid/liquid interface, and differential heating applied parallel to the interfaces. An analytical solution is introduced for infinite horizontal layers. The defining parameter for the flow pattern is lambda, the ratio of the temperature coefficient of the interfacial tension to that of the surface tension. Four different flow patterns exist under zero gravity conditions. 'Halt' conditions which halt the fluid motion in the lower encapsulated liquid layer have been found. A numerical experiment is carried out to study effects of vertical end walls on the double layer convection in a 2D cavity. The halt condition obtained from the analytical study is found to be valid in the limit of small Reynolds numbers. The flow in the encapsulated liquid layer can be suppressed substantially.

Substrate pH and butterfly bush response to dolomitic lime or steel slag amendment

USDA-ARS?s Scientific Manuscript database

Steel slag is a fertilizer amendment with a high concentration of calcium oxide, and thus capable of raising substrate pH similar to dolomitic lime. Steel slag, however, contains higher concentrations of some nutrients, such as iron, manganese, and silicon, compared to dolomitic lime. The objectiv...

Micronutrient availability from steel slag amendment in pine bark substrates

USDA-ARS?s Scientific Manuscript database

Steel slag is a byproduct of the steel industry that can be used as a liming agent, but also has a high mineral nutrient content. While micronutrients are present in steel slag, it is not known if the mineral form of the micronutrients would render them available for plant uptake. The objective of...

Production of brown and black pigments by using flotation waste from copper slag.

PubMed

Ozel, Emel; Turan, Servet; Coruh, Semra; Ergun, Osman Nuri

2006-04-01

One of the major problems in copper-producing countries is the treatment of the large amount of copper slag or copper flotation waste generated from copper slag which contains significant amounts of heavy metals such as Cu, Zn, Pb and Co. Dumping or disposal of such large quantities of flotation waste from copper slag causes environmental and space problems. In this study, the treatment of flotation waste from copper slag by a thermal method and its use as an iron source in the production of inorganic brown and black pigments that are used in the ceramic industry were investigated. The pigments were produced by calcining different amounts of flotation waste and chromite, Cr2O3, ZnO and CoO mixtures. The pigments obtained were added to transparent ceramic glazes and porcelainized tile bodies. Their colours were defined by L*a*b* measurements with a spectrophotometer. The results showed that flotation waste from copper slag could be used as an iron source to produce brown and black pigments in both ceramic body and glazes.

CO2 Mineralization and Utilization using Steel Slag for Establishing a Waste-to-Resource Supply Chain.

PubMed

Pan, Shu-Yuan; Chung, Tai-Chun; Ho, Chang-Ching; Hou, Chin-Jen; Chen, Yi-Hung; Chiang, Pen-Chi

2017-12-08

Both steelmaking via an electric arc furnace and manufacturing of portland cement are energy-intensive and resource-exploiting processes, with great amounts of carbon dioxide (CO 2 ) emission and alkaline solid waste generation. In fact, most CO 2 capture and storage technologies are currently too expensive to be widely applied in industries. Moreover, proper stabilization prior to utilization of electric arc furnace slag are still challenging due to its high alkalinity, heavy metal leaching potentials and volume instability. Here we deploy an integrated approach to mineralizing flue gas CO 2 using electric arc furnace slag while utilizing the reacted product as supplementary cementitious materials to establish a waste-to-resource supply chain toward a circular economy. We found that the flue gas CO 2 was rapidly mineralized into calcite precipitates using electric arc furnace slag. The carbonated slag can be successfully utilized as green construction materials in blended cement mortar. By this modulus, the global CO 2 reduction potential using iron and steel slags was estimated to be ~138 million tons per year.

The Effect of CaO on Gas/Slag/Matte/Tridymite Equilibria in Fayalite-Based Copper Smelting Slags at 1473 K (1200 °C) and P(SO2) = 0.25 Atm

NASA Astrophysics Data System (ADS)

Fallah-Mehrjardi, Ata; Hayes, Peter C.; Jak, Evgueni

2018-04-01

Fundamental experimental studies have been undertaken to determine the effect of CaO on the equilibria between the gas phase (CO/CO2/SO2/Ar) and slag/matte/tridymite phases in the Cu-Fe-O-S-Si-Ca system at 1473 K (1200 °C) and P(SO2) = 0.25 atm. The experimental methodology developed in the Pyrometallurgy Innovation Centre was used. New experimental data have been obtained for the four-phase equilibria system for fixed concentrations of CaO (up to 4 wt pct) in the slag phase as a function of copper concentration in matte, including the concentrations of dissolved sulfur and copper in slag, and Fe/SiO2 ratios in slag at tridymite saturation. The new data provided in the present study are of direct relevance to the pyrometallurgical processing of copper and will be used as an input to optimize the thermodynamic database for the copper-containing multi-component multi-phase system.

Properties of Controlled Low Strength Material with Circulating Fluidized Bed Combustion Ash and Recycled Aggregates

PubMed Central

Weng, Tsai-Lung; Cheng, An; Chao, Sao-Jeng; Hsu, Hui-Mi

2018-01-01

This study aims to investigate the effect of adding circulating fluidized bed combustion (CFBC) ash, desulfurization slag, air-cooled blast-furnace slag and coal bottom ash to the controlled low-strength material (CLSM). Test methods include slump flow test, ball drop test, water soluble chloride ion content measurement, compressive strength and length change measurement. The results show that (1) the use of CFBC hydration ash with desulfurization slag of slump flow is the best, and the use of CFBC hydration ash with coal bottom ash and slump flow is the worst; (2) CFBC hydration ash with desulfurization slag and chloride ion content is the highest; (3) 24 h ball drop test (diameter ≤ 76 mm), and test results are 70 mm to 76 mm; (4) CFBC hydration ash with desulfurization slag and compression strength is the highest, with the coal bottom ash being the lowest; increase of CFBC hydration ash can reduce compressive strength; and (5) the water-quenched blast furnace slag and CFBC hydration ash would expand, which results in length changes of CLSM specimens. PMID:29724055

Combined Performance of Polypropylene Fibre and Weld Slag in High Performance Concrete

NASA Astrophysics Data System (ADS)

Ananthi, A.; Karthikeyan, J.

2017-12-01

The effect of polypropylene fibre and weld slag on the mechanical properties of High Performance Concrete (HPC) containing silica fume as the mineral admixtures was experimentally verified in this study. Sixteen series of HPC mixtures(70 MPa) were designed with varying fibre fractions and Weld Slag (WS). Fibre added at different proportion (0, 0.1, 0.3 and 0.6%) to the weight of cement. Weld slag was substituted to the fine aggregate (0, 10, 20 and 30%) at volume. The addition of fibre decreases the slump at 5, 9 and 14%, whereas the substitution of weld slag decreases by about 3, 11 and 21% with respect to the control mixture. Mechanical properties like compressive strength, split tensile strength, flexural strength, Ultrasonic Pulse Velocity test (UPV) and bond strength were tested. Durability studies such as Water absorption and Sorptivity test were conducted to check the absorption of water in HPC. Weld slag of 10% and fibre dosage of 0.3% in HPC, attains the maximum strength and hence this combination is most favourable for the structural applications.

Surface order in cold liquids: X-ray reflectivity studies of dielectric liquids and comparison to liquid metals

NASA Astrophysics Data System (ADS)

Chattopadhyay, Sudeshna; Uysal, Ahmet; Stripe, Benjamin; Ehrlich, Steven; Karapetrova, Evguenia A.; Dutta, Pulak

2010-05-01

Oscillatory surface-density profiles (layers) have previously been reported in several metallic liquids, one dielectric liquid, and in computer simulations of dielectric liquids. We have now seen surface layers in two other dielectric liquids, pentaphenyl trimethyl trisiloxane, and pentavinyl pentamethyl cyclopentasiloxane. These layers appear below T˜285K and T˜130K , respectively; both thresholds correspond to T/Tc˜0.2 where Tc is the liquid-gas critical temperature. All metallic and dielectric liquid surfaces previously studied are also consistent with the existence of this T/Tc threshold, first indicated by the simulations of Chacón [Phys. Rev. Lett. 87, 166101 (2001)]. The layer width parameters, determined using a distorted-crystal fitting model, follow common trends as functions of Tc for both metallic and dielectric liquids.

Preparation of fly ash-granulated blast furnace slag-carbide slag binder and application in total tailings paste backfill

NASA Astrophysics Data System (ADS)

Li, Chao; Hao, Ya-fei; Zhao, Feng-qing

2018-03-01

Based on activation and synergistic effect among various materials, a low-cost mine backfill cementing material, FGC binder, was prepared by using fly ash, granulated blast-furnace slag (GBFS), carbide slag and composite activator. The proper proportioning of FGC binder is obtained by response surface experiment optimization method: fly ash 62 %, GBFS 20 %, carbide slag 8 % and compound activators 10 %. Adjusting the material ratio obtains different cementing material which could satisfy requirements of different mined-out areas. With the mass ratio of cementing material and tailings 1:4∼1:8, the concentration of total solid 70 %, the compressive strength values of total tailings filling body at 28 d reaches 1.64∼4.14 MPa, and the backfilling cost is 20 % lower than using OPC cement.

Foaming Index of CaO-SiO2-FeO-MgO Slag System

NASA Astrophysics Data System (ADS)

Park, Youngjoo; Min, Dong Joon

A study on the effect of FeO and MgO content on foaming index in EAF slag system was carried out. The height of the slag foam was measured by electric probe maintaining steady state in gas formation and escape. Foaming index, which is the measurement of gas capturing potential of the slag, is calculated from the foam height and gas flow rate. Viscosity and surface tension, which are the key properties for the foaming index, are calculated by Urbain's model and additive method, respectively. Dimensional analysis also performed to determine the dominancy of properties and resulted that the important factor was a ratio between viscosity and surface tension. The effect of each component on the viscosity, surface tension and foaming index of the slag is evaluated to be in strong relationship.

Removal of Sulfur from CaF2 Containing Desulfurization Slag Exhausted from Secondary Steelmaking Process by Oxidation

NASA Astrophysics Data System (ADS)

Hiraki, Takehito; Kobayashi, Junichi; Urushibata, Satomi; Matsubae, Kazuyo; Nagasaka, Tetsuya

2012-08-01

The oxidation behavior of sulfur in desulfurization slag generated from the secondary steelmaking process with air has been investigated in the temperature range of 973 K to 1373 K (700 °C to 1100 °C). Although a high removal rate of sulfur is not achieved at temperatures lower than 1273 K (1000 °C) because of the formation of CaSO4, most of the sulfur is rapidly removed from slag as SO2 gas in the 1273 K to 1373 K (700 °C to 1100 °C) range. This finding indicates that the desulfurization slag generated from the secondary steelmaking process can be reused as a desulfurized flux through air oxidation, making it possible to reduce significantly the amount of desulfurization slag for disposal.

Function evaluation of asphalt mixture with industrially produced BOF slag aggregate.

PubMed

Zhao, Meiling; Wu, Shaopeng; Chen, Zongwu; Li, Chao

2016-07-04

Laboratory research suggested that basic oxygen furnace (BOF) slag-based asphalt mixture was a functional material. However, the BOF slag aggregate's quality was difficult to control when it was heavily used in entity engineering. The primary objective of this research was to evaluate the functional performances of asphalt mixture containing BOF slag coarse aggregate (BSCA), which was from an industrialized production line. Limestone mixture was a control group. The Marshall method was first adopted to design asphalt mixtures. The performances of limestone asphalt mixture and BOF slag asphalt mixture including fatigue failure resistance and moisture stability were then evaluated and compared. Results showed that the asphalt mixture containing BSCA possessed better durability, which meant the quality of BSCA from industrialized production lines was well controlled and this BSCA can be heavily used in entity engineering.

Characterization of structure and thermophysical properties of three ESR slags

NASA Astrophysics Data System (ADS)

Plotkowski, A.; deBarbadillo, J.; Krane, Matthew J. M.

2016-07-01

The structure and properties of electroslag remelting (ESR) slags were characterized. Slags samples of three compositions were obtained from industrial remelting processes at Special Metals Corporation and from casting in a laboratory vacuum induction melter. The structure of the slag samples was observed using optical and electron microscopy, and phases were identified and their relative amounts quantified using X-ray diffraction. Laser flash thermal diffusivity, density, and differential scanning calorimetry measurements for specific heat were performed to determine the bulk thermal conductivity of the samples. Sample porosity was measured as a function of depth using a serial sectioning technique, and a onedimensional computational model was developed to estimate the thermal conductivity of the fully dense slags. These results are discussed in context with previous studies, and opportunities for future research are identified. AFRL Case Number: 88ABW-2015-1871.

Study on the ratio and properties of the slurry of light insulation masonry with volcanic slag

NASA Astrophysics Data System (ADS)

Liguang, Xiao; Dawei, Jiang

2017-12-01

Volcanic slag is a kind of natural high quality porous material, and it has a good thermal insulation effect, and it is an extremely rich natural resource. Therefore, this paper adopts the natural volcanic slag as the aggregate to build the insulation mortar mix design for the slag masonry, and tests the related performance of the mortar. The results show that adopts natural volcanic slag as the aggregate and the cement use fly ash to replace, and the appropriate uniform sealing pores were introduced into the mortar mix. The performance of the manufactured products can meet the requirements of JC/T890. The coefficient of thermal conductivity of lightweight masonry mortar is less than 0.14W/(m•K), and the frost resistance is greater than 100 times, and it is with a low price.

Viscosity Determination of Molten Ash from Low-Grade US Coals

DOE PAGES

Zhu, Jingxi; Nakano, Jinichiro; Kaneko, Tetsuya Kenneth; ...

2012-10-01

In entrained slagging gasifiers, the fluidity of the molten ash is a critical factor for process control since it affects slag formation, the capture of inorganic constituents, refractory wear, and slag drainage along the gasification chamber walls. The use of western coal, or mixtures of eastern and western coals as gasifier feedstock, is likely to occur as western coals become available and technological issues that hinder their use are being resolved. In the present work, the viscosity of synthetic slags with ash chemistries simulating the western U.S. coals, was experimentally measured at a Po 2 = 10 - 8 atmmore » in the temperature range of 1773–1573 K (1500–1300 °C) using a rotating-bob viscometer. Alumina spindles and containment crucibles of both alumina and zirconia were used. Crystallization studies of this slag using a confocal scanning laser microscope found that a (Mg,Fe)Al 2O 4-based spinel precipitated at temperatures below 1723 K (1450 °C), and this agreed with FactSage equilibrium phase prediction. The same spinels were observed in the post-viscometry experiment slags when ZrO 2 crucibles were used and assumed to be in equilibrium with the slag at the higher temperatures. Zirconia dissolution resulted in a slight increase in the solid fraction present in slags at lower temperatures, compared to spinel fraction. Crystal precipitation changed the apparent activation energy and required a longer stabilization times for viscosity measurements. The viscosity results were used in predictive equations based on Veytsman and Einstein's models, with critical nucleation temperatures and the solid fraction calculated with FactSage. In the simulated eastern/western coal feedstock blends based on ash compositions, the fractions of the solid precipitates were also calculated using the thermodynamic program FactSage for each blend composition, and the plastic viscosity of each eastern/western coal slag blend was predicted using Veytsman's model and compared to available experimental data.« less

Design of a Subscale Propellant Slag Evaluation Motor Using Two-Phase Fluid Dynamic Analysis

NASA Technical Reports Server (NTRS)

Whitesides, R. Harold; Dill, Richard A.; Purinton, David C.; Sambamurthi, Jay K.

1996-01-01

Small pressure perturbations in the Space Shuttle Reusable Solid Rocket Motor (RSRM) are caused by the periodic expulsion of molten aluminum oxide slag from a pool that collects in the aft end of the motor around the submerged nozzle nose during the last half of motor operation. It is suspected that some motors produce more slag than others due to differences in aluminum oxide agglomerate particle sizes that may relate to subtle differences in propellant ingredient characteristics such as particle size distributions or processing variations. A subscale motor experiment was designed to determine the effect of propellant ingredient characteristics on the propensity for slag production. An existing 5 inch ballistic test motor was selected as the basic test vehicle. The standard converging/diverging nozzle was replaced with a submerged nose nozzle design to provide a positive trap for the slag that would increase the measured slag weights. Two-phase fluid dynamic analyses were performed to develop a nozzle nose design that maintained similitude in major flow field features with the full scale RSRM. The 5 inch motor was spun about its longitudinal axis to further enhance slag collection and retention. Two-phase flow analysis was used to select an appropriate spin rate along with other considerations, such as avoiding bum rate increases due to radial acceleration effects. Aluminum oxide particle distributions used in the flow analyses were measured in a quench bomb for RSRM type propellants with minor variations in ingredient characteristics. Detailed predictions for slag accumulation weights during motor bum compared favorably with slag weight data taken from defined zones in the subscale motor and nozzle. The use of two-phase flow analysis proved successful in gauging the viability of the experimental program during the planning phase and in guiding the design of the critical submerged nose nozzle.

Evaluation on chemical stability of lead blast furnace (LBF) and imperial smelting furnace (ISF) slags.

PubMed

Yin, Nang-Htay; Sivry, Yann; Guyot, François; Lens, Piet N L; van Hullebusch, Eric D

2016-09-15

The leaching behavior of Pb and Zn from lead blast furnace (LBF) and imperial smelting furnace (ISF) slags sampled in the North of France was studied as a function of pHs and under two atmospheres (open air and nitrogen). The leaching of major elements from the slags was monitored as a function of pH (4, 5.5, 7, 8.5 and 10) under both atmospheres for different slag-water interaction times (1 day and 9 days). The leaching results were coupled with a geochemical model; Visual MINTEQ version 3.0, and a detailed morphological and mineralogical analysis was performed on the leached slags by scanning and transmission electron microscopy (SEM and TEM). Significant amounts of Ca, Fe and Zn were released under acidic conditions (pH 4) with a decrease towards the neutral to alkaline conditions (pH 7 and 10) for both LBF and ISF slags. On the other hand, Fe leachability was limited at neutral to alkaline pH for both slags. The concentrations of all elements increased gradually after 216 h compared to initial 24 h of leaching period. The presence of oxygen under open-air atmosphere not only enhanced oxidative weathering but also encouraged formation of secondary oxide and carbonate phases. Formation of carbonates and clay minerals was suggested by Visual MINTEQ which was further confirmed by SEM & TEM. The hydration and partial dissolution of hardystonite, as well as the destabilization of amorphous glassy matrix mainly contributed to the release of major elements, whereas the spinel related oxides were resistant against pH changes and atmospheres within the time frame concerned for both LBF and ISF slags. The total amount of Pb leached out at pH 7 under both atmospheres suggested that both LBF and ISF slags are prone to weathering even at neutral environmental conditions. Copyright © 2016 Elsevier Ltd. All rights reserved.

Leaching of cadmium, chromium, copper, lead, and zinc from two slag dumps with different environmental exposure periods under dynamic acidic condition.

PubMed

Jin, Zhisheng; Liu, Taoze; Yang, Yuangen; Jackson, Daniel

2014-06-01

Over the past few decades, zinc smelting activities in Guizhou, China have produced numerous slag dumps, which are often dispersed on roadsides and hill slopes throughout the region. During periods of acid rain, these exposed slags release heavy metals into surface water bodies. A column leaching study was designed to test the potential release of the heavy metals cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), and zinc (Zn) under simulated acid rain events. Two slags with varying environmental exposure periods were packed in columns and subjected to leaching solutions of pH 3.5, 5.5, or DI H2O at intervals of 1, 7, 14, 28, 56d. Pulse concentrations of Cd in leachate were found above 5μg/L, Cr, Pb, and Zn >10μg/L, whereas, Cu reached 10μg/L. After five leaching events, the leachability (percentage of cumulative heavy metal leached after five leaching events as in its respective total concentration in slags) of Cd was 0.05 percent and 0.035 percent from the old and young slag, respectively. Cr (0.035 percent and 0.05 percent) was greater than Cu (0.002 percent and 0.005 percent) and Zn (0.006 percent and 0.003 percent), while the lowest leachability was observed for Pb (0.0005 percent and 0.0002 percent) from the old and young slags, respectively. Reaction rates (release amount of heavy metals in certain period of leaching) of heavy metals in the leachates demonstrated the sequence of Zn>Cr>Cd, Cu>Pb. Leaching release of heavy metals was jointly affected by the pH of leaching solution and mineral composition of slags (including chemical forms of Cd, Cr, Cu, Pb, and Zn). Environmental exposure period of slags, resulting in the alteration of minerals, could affect the release process of heavy metals in leaching as well. Copyright © 2014 Elsevier Inc. All rights reserved.

Thermodynamics Behavior of Germanium During Equilibrium Reactions between FeOx-CaO-SiO2-MgO Slag and Molten Copper

NASA Astrophysics Data System (ADS)

Shuva, M. A. H.; Rhamdhani, M. A.; Brooks, G. A.; Masood, S.; Reuter, M. A.

2016-10-01

The distribution ratio of germanium (Ge), L_{{Ge}}^{s/m} during equilibrium reactions between magnesia-saturated FeOx-CaO-SiO2 (FCS) slag and molten copper has been measured under oxygen partial pressures from 10-10 to 10-7 atm and at temperatures 1473 to 1623 K (1200 to 1350 °C). It was observed that the Ge distribution ratio increases with increasing oxygen partial pressure, and with decreasing temperature. It was also observed that the distribution ratio is strongly dependent on slag basicity. The distribution ratio was observed to increase with increasing optical basicity. At fixed CaO concentration in the slag, the distribution ratio was found to increase with increasing Fe/SiO2 ratio, tending to a plateau at L_{{Ge}}^{s/m} = 0.8. This behavior is consistent with the assessment of ionic bond fraction carried out in this study, and suggested the acidic nature of germanium oxide (GeO2) in the slag system studied. The characterisation results of the quenched slag suggested that Ge is present in the FeOx-CaO-SiO2-MgO slag predominantly as GeO2. At 1573 K (1300 °C) and p_{{{{O}}2 }} = 10-8 atm, the activity coefficient of GeO2 in the slag was calculated to be in the range of 0.24 to 1.50. The results from the current study suggested that less-basic slag, high operating temperature, and low oxygen partial pressure promote a low Ge distribution ratio. These conditions are desired for maximizing Ge recovery, for example, during pyrometallurgical processing of Ge-containing e-waste through secondary copper smelting. Overall, the thermodynamics data generated from this study can be used for process modeling purposes for improving recovery of Ge in primary and secondary copper smelting processes.

Experimental study of dissolution of minerals and CO2 sequestration in steel slag.

PubMed

Yadav, Shashikant; Mehra, Anurag

2017-06-01

This study strives to achieve a substantial amount of steel slag carbonation without using any harmful chemicals. For this purpose, experiments were performed in an aqueous medium, in a semi-batch reactor, to investigate the effect of varying reaction conditions during the steel slag CO 2 sequestration process. Further, studying the effect of dissolution on carbonation reactions and the mineralogical changes that subsequently occur within the slag helps provide insight into the parameters that ultimately have an impact on the carbonation rate as well the magnitude of the impact. Copyright © 2017 Elsevier Ltd. All rights reserved.

Accelerated decarburization of Fe-C metal alloys

DOEpatents

Pal, Uday B.; Sadoway, Donald R.

1997-01-01

A process for improving the rate of metal production and FeO utilization in a steelmaking process or a process combining iron-making and steelmaking in a single reactor that uses or generates Fe-C metal alloy droplets submerged in an FeO-containing slag. The process involves discharging a charge build-up (electron accumulation) in the slag at the slag-metal alloy interface by means of an electron conductor connected between the metal alloy droplets and a gas at a gas-slag interface, said gas having an oxygen partial pressure of at least about 0.01 atmosphere.

Accelerated decarburization of Fe-C metal alloys

DOEpatents

Pal, U.B.; Sadoway, D.R.

1997-05-27

A process is described for improving the rate of metal production and FeO utilization in a steelmaking process or a process combining iron-making and steelmaking in a single reactor that uses or generates Fe-C metal alloy droplets submerged in an FeO-containing slag. The process involves discharging a charge build-up (electron accumulation) in the slag at the slag-metal alloy interface by means of an electron conductor connected between the metal alloy droplets and a gas at a gas-slag interface, said gas having an oxygen partial pressure of at least about 0.01 atmosphere. 2 figs.

Rapid Separation of Copper Phase and Iron-Rich Phase From Copper Slag at Low Temperature in a Super-Gravity Field

NASA Astrophysics Data System (ADS)

Lan, Xi; Gao, Jintao; Huang, Zili; Guo, Zhancheng

2018-03-01

A novel approach for quickly separating a metal copper phase and iron-rich phase from copper slag at low temperature is proposed based on a super-gravity method. The morphology and mineral evolution of the copper slag with increasing temperature were studied using in situ high-temperature confocal laser scanning microscopy and ex situ scanning electron microscopy and X-ray diffraction methods. Fe3O4 particles dispersed among the copper slag were transformed into FeO by adding an appropriate amount of carbon as a reducing agent, forming the slag melt with SiO2 at low temperature and assisting separation of the copper phase from the slag. Consequently, in a super-gravity field, the metallic copper and copper matte were concentrated as the copper phase along the super-gravity direction, whereas the iron-rich slag migrated in the opposite direction and was quickly separated from the copper phase. Increasing the gravity coefficient (G) significantly enhanced the separation efficiency. After super-gravity separation at G = 1000 and 1473 K (1200 °C) for 3 minutes, the mass fraction of Cu in the separated copper phase reached 86.11 wt pct, while that in the separated iron-rich phase was reduced to 0.105 wt pct. The recovery ratio of Cu in the copper phase was as high as up to 97.47 pct.

Maximum availability and mineralogical control of chromium released from AOD slag.

PubMed

Li, Junguo; Liu, Bao; Zeng, Yanan; Wang, Ziming; Gao, Zhiyuan

2017-03-01

AOD (argon oxygen decarburization) slag is the by-product in the stainless steel refining process. Chromium existing in AOD slag can leach out and probably poses a serious threat to the environment. To assess the leaching toxicity of chromium released from AOD slag, the temperature-dependent maximum availability leaching test was performed. To determine the controlling mineralogical phases of chromium released from AOD slag, a Visual MINTEQ simulation was established based on Vminteq30 and the FactSage 7.0 database. The leaching tests indicated that the leaching availability of chromium was slight and mainly consisted of trivalent chromium. Aging of AOD slag under the atmosphere can oxidize trivalent chromium to hexavalent chromium, which could be leached out by rainwater. According to the simulation, the chromium concentration in leachates was controlled by the freely soluble pseudo-binary phases in the pH = 7.0 leaching process and controlled by the Cr 2 O 3 phase in the pH = 4.0 leaching process. Chromium concentrations were underestimated when the controlling phases were determined to be FeCr 2 O 4 and MgCr 2 O 4 . Facilitating the generation of the insoluble spinel-like phases during the cooling and disposal process of the molten slag could be an effective approach to decreasing the leaching concentration of chromium and its environmental risk.

-Based Slag System

NASA Astrophysics Data System (ADS)

Jiang, Binbin; Wang, Wanlin; Sohn, Il; Wei, Juan; Zhou, Lejun; Lu, Boxun

2014-06-01

The crystallization behavior of a CaO-Al2O3-based slag system with various ZrO2 content (from 1 to 5 wt pct) and CaO/Al2O3 (C/A) ratio (from 0.8 to 1.2) has been studied by using single hot thermocouple technology (SHTT) in this article. The continuous-cooling-transformation (CCT) diagrams and time-temperature-transformation (TTT) diagrams of the above slag system were constructed for the analysis of the varying crystallization behaviors. The results suggested that Al2O3 tended to enhance the slag samples crystallization when the C/A ratio ranged from 0.8 to 1.2, and the critical cooling rate and crystallization temperature increased with the decrease of C/A ratio; meanwhile, the incubation time was also getting shorter with the reduction of C/A ratio. The addition of ZrO2 would enhance the crystallization of slag samples because of the induced heterogeneous nucleation of molten slag. However, the general crystallization was determined by the balance between molten slag viscosity and heterogeneous nucleation, such that Sample 3 (C/A = 1.0, ZrO2 = 3 pct, B2O3 = 10 pct, Li2O = 3 pct [in wt pct]) would demonstrate the strongest crystallization kinetics in a high-temperature zone. The different crystals formed during the tests were also analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD).

Viscosity of TiO2-FeO-Ti2O3-SiO2-MgO-CaO-Al2O3 for High-Titania Slag Smelting Process

NASA Astrophysics Data System (ADS)

Hu, Kai; Lv, Xuewei; Li, Shengping; Lv, Wei; Song, Bing; Han, Kexi

2018-05-01

The present study demonstrates the dependence of viscosity on chemical composition and temperature of high-titania slag, a very important raw material for producing titanium dioxide. The results indicated that completely molten high-titania slag exhibits a viscosity of less than 1 dPa s with negligible dependence on temperature. However, it increases dramatically with decreasing temperature slightly below the critical temperature, i.e., the solidus temperature of the slag. Above the critical temperature, the slag samples displayed the same order of viscosity at 0.6 dPa s, regardless of their compositional variation. However, the FeO, CaO, and MgO were confirmed to decrease viscosity, while SiO2 and Ti2O3 increase it. The apparent activation energy for viscosity-temperature relation and liquidus temperature based on experiments and thermodynamic calculations are also presented. Conclusively, the critical temperatures of the slags are on average 15 K below their corresponding calculated liquidus temperatures. The increase in FeO content was found to considerably lower the critical temperature, while the increase in both Ti2O3 and TiO2 contents increases it. The main phases of the slag in solid state, as indicated by X-ray diffraction, are (Fe, Mg) x Ti y O5 (x + y = 3, pseudobrookite) and rutile.

Remediation of TCE-contaminated groundwater using acid/BOF slag enhanced chemical oxidation.

PubMed

Tsai, T T; Kao, C M; Wang, J Y

2011-04-01

The objective of this study was to evaluate the potential of applying acid/H(2)O(2)/basic oxygen furnace slag (BOF slag) and acid/S(2)O(8)(2-)/BOF slag systems to enhance the chemical oxidation of trichloroethylene (TCE)-contaminated groundwater. Results from the bench-scale study indicate that TCE oxidation via the Fenton-like oxidation process can be enhanced with the addition of BOF slag at low pH (pH=2-5.2) and neutral (pH=7.1) conditions. Because the BOF slag has iron abundant properties (14% of FeO and 6% of Fe(2)O(3)), it can be sustainably reused for the supplement of iron minerals during the Fenton-like or persulfate oxidation processes. Results indicate that higher TCE removal efficiency (84%) was obtained with the addition of inorganic acid for the activation of Fenton-like reaction compared with the experiments with organic acids addition (with efficiency of 10-15% lower) (BOF slag=10gL(-1); initial pH=5.2). This could be due to the fact that organic acids would compete with TCE for available oxidants. Results also indicate that the pH value had a linear correlation with the observed first-order decay constant of TCE, and thus, lower pH caused a higher TCE oxidation rate. Copyright © 2011 Elsevier Ltd. All rights reserved.

Rapid Separation of Copper Phase and Iron-Rich Phase From Copper Slag at Low Temperature in a Super-Gravity Field

NASA Astrophysics Data System (ADS)

Lan, Xi; Gao, Jintao; Huang, Zili; Guo, Zhancheng

2018-06-01

A novel approach for quickly separating a metal copper phase and iron-rich phase from copper slag at low temperature is proposed based on a super-gravity method. The morphology and mineral evolution of the copper slag with increasing temperature were studied using in situ high-temperature confocal laser scanning microscopy and ex situ scanning electron microscopy and X-ray diffraction methods. Fe3O4 particles dispersed among the copper slag were transformed into FeO by adding an appropriate amount of carbon as a reducing agent, forming the slag melt with SiO2 at low temperature and assisting separation of the copper phase from the slag. Consequently, in a super-gravity field, the metallic copper and copper matte were concentrated as the copper phase along the super-gravity direction, whereas the iron-rich slag migrated in the opposite direction and was quickly separated from the copper phase. Increasing the gravity coefficient (G) significantly enhanced the separation efficiency. After super-gravity separation at G = 1000 and 1473 K (1200 °C) for 3 minutes, the mass fraction of Cu in the separated copper phase reached 86.11 wt pct, while that in the separated iron-rich phase was reduced to 0.105 wt pct. The recovery ratio of Cu in the copper phase was as high as up to 97.47 pct.

Chembio extraction on a chip by nanoliter droplet ejection.

PubMed

Yu, Hongyu; Kwon, Jae Wan; Kim, Eun Sok

2005-03-01

This paper describes a novel liquid separation technique for chembio extraction by an ultrasonic nanoliter-liquid-droplet ejector built on a PZT sheet. This technique extracts material from an aqueous two-phase system (ATPS) in a precise amount through digital control of the number of nanoliter droplets, without any mixing between the two liquids in the ATPS. The ultrasonic droplet ejector uses an acoustic streaming effect produced by an acoustic beam focused on the liquid surface, and ejects liquid droplets only from the liquid surface without disturbing most of the liquid below the surface. This unique characteristic of the focused acoustic beam is perfect (1) for separating a top-layer liquid (from the bulk of liquid) that contains particles of interest or (2) for recovering a top-layer liquid that has different phase from a bottom-layer liquid. Three kinds of liquid extraction are demonstrated with the ultrasonic droplet ejector: (1) 16 microl of top layer in Dextran-polyethylene glycol-water ATPS (aqueous two-phase system) is recovered within 20 s; (2) micron sized particles that float on water surface are ejected out with water droplets; and (3) oil layer on top of water is separated out.

Model of Draining of the Blast Furnace Hearth with an Impermeable Zone

NASA Astrophysics Data System (ADS)

Saxén, Henrik

2015-02-01

Due to demands of lower costs and higher productivity in the steel industry, the volume of operating blast furnaces has grown during the last decades. As the height is limited by the allowable pressure drop, the hearth diameter has grown considerably and, along with this, also draining-related problems. In this paper a mathematical model is developed for simulating the drainage in the case where an impermeable region exists in the blast furnace hearth. The model describes the quasi-stationary drainage process of a hearth with two operating tapholes, where the communication between the two pools of molten slag and iron can be controlled by parameterized expressions. The model also considers the case where the buoyancy of the liquids is sufficient for lifting the coke bed. The implications of different size of the liquid pools, communication between the pools, bed porosity, etc. are studied by simulation, and conclusions concerning their effect on the drainage behavior and evolution of the liquid levels in the hearth are drawn. The simulated liquid levels are finally demonstrated to give rise to a pressure profile acting on the hearth which agrees qualitatively with signals from strain gauges mounted in the hearth wall of an industrial ironmaking process.

40 CFR 421.75 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... produced Lead .000 .000 Zinc .000 .000 (c) Subpart G—Blast Furnace Slag Granulation. PSES Pollutant or... blast furance lead bullion produced Lead .000 .000 Zinc .000 .000 (d) Subpart G—Dross Reverberatory Slag... (pounds per billion pounds) of slag, speiss, or matte granulated Lead 1,612.000 748.400 Zinc 5,872.000 2...

40 CFR 421.75 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... produced Lead .000 .000 Zinc .000 .000 (c) Subpart G—Blast Furnace Slag Granulation. PSES Pollutant or... blast furance lead bullion produced Lead .000 .000 Zinc .000 .000 (d) Subpart G—Dross Reverberatory Slag... (pounds per billion pounds) of slag, speiss, or matte granulated Lead 1,612.000 748.400 Zinc 5,872.000 2...

The measurement of the heat-transfer coefficient between high-temperature liquids and solid surfaces

NASA Astrophysics Data System (ADS)

Utigard, T. A.; Warczok, A.; Desclaux, P.

1994-01-01

Two experimental techniques were developed for the purpose of measuring the heat-transfer coefficient between liquid slags/salts and solid surfaces. This was carried out because the heat-transfer coefficient is important for the design and operation of metallurgical reactors. A “cold-finger” technique was developed for the purpose of carrying out heat-transfer measurements during steady-state conditions simulating heat fluxes through furnace sidewalls. A lump capacitance method was developed and tested for the purpose of simulating transient conditions. To determine the effect of fluid flow on the heat-transfer coefficient, nitrogen gas stirring was used. The two techniques were tested in molten (1) and NaNO3, (2) NaCl, (3) Na3AlF6, and (4) 2FeO·SiO2, giving consistent results. It was found that the heat-transfer coefficient increases with increasing bath superheat and stirring.

Long-Wavelength Instability in Marangoni Convection

NASA Technical Reports Server (NTRS)

VanHook, Stephen J.; Schatz, Michael F.; Swift, Jack B.; McCormick, W. D.; Swinney, Harry L.

1996-01-01

Our experiments in thin liquid layers (approximately 0.1 mm thick) heated from below reveal a well-defined long-wavelength instability: at a critical temperature difference across the layer, the depth of the layer in the center of the cell spontaneously decreases until the liquid-air interface ruptures and a dry spot forms. The onset of this critical instability occurs at a temperature difference across the liquid layer that is 35% smaller than that predicted in earlier theoretical studies of a single layer model. Our analysis of a two-layer model yields predictions in accord with the observations for liquid layer depths greater than or equal to 0.15 mm, but for smaller depths there is an increasing difference between our predictions and observations (the difference is 25% for a layer 0.06 mm thick). In microgravity environments the long-wavelength instability observed in our terrestrial experiments is expected to replace cellular convection as the primary instability in thick as well as thin liquid layers heated quasistatically from below.

Effect of the CaO/SiO2 mass ratio and FeO content on the viscosity of CaO-SiO2-"FeO"-12wt%ZnO-3wt%Al2O3 slags

NASA Astrophysics Data System (ADS)

Lü, Jian-fang; Jin, Zhe-nan; Yang, Hong-ying; Tong, Lin-lin; Chen, Guo-bao; Xiao, Fa-xin

2017-07-01

An effective process for recycling lead from hazardous waste cathode ray tubes (CRTs) funnel glass through traditional lead smelting has been presented previously. The viscous behavior of the molten high lead slag, which is affected by the addition of funnel glass, plays a critical role in determining the production efficiency. Therefore, the viscosities of the CaO-SiO2-"FeO"-12wt%ZnO-3wt%Al2O3 slags were measured in the current study using the rotating spindle method. The slag viscosity decreases as the CaO/SiO2 mass ratio is increased from 0.8 to 1.2 and also as the FeO content is increased from 8wt% to 20wt%. The breaking temperature of the slag is lowered substantially by the addition of FeO, whereas the influence of the CaO/SiO2 mass ratio on the breaking temperature is complex. The structural analysis of quenched slags using Fourier transform infrared (FTIR) spectroscopy and Raman spectroscopy reveals that the silicate network structure is depolymerized with increasing CaO/SiO2 mass ratio or increasing FeO content. The [FeO6]-octahedra in the slag melt increase as the CaO/SiO2 mass ratio or the FeO content increases. This increase can further decrease the degree of polymerization (DOP) of the slag. Furthermore, the activation energy for viscous flow decreases both with increasing CaO/SiO2 mass ratio and increasing FeO content.

Recovery of metal values from copper slag and reuse of residual secondary slag.

PubMed

Sarfo, Prince; Das, Avimanyu; Wyss, Gary; Young, Courtney

2017-12-01

Resource and environmental factors have become major forces in mining and metallurgy sectors driving research for sustainability purposes. The concept of zero-waste processing has been gaining ground readily. The scant availability of high quality raw materials has forced the researchers to shift their focus to recycling while the exceedingly stringent environmental regulations have forced researchers to explore new frontiers of minimizing/eliminating waste generation. The present work is aimed at addressing both aspects by employing recycling to generate wealth from copper slag and producing utilizable materials at the same time thus restoring the ecosystem. Copper slag was characterized and processed. The pyro-metallurgical processing prospects to generate utilizable materials were arrived at through rigorous thermodynamic analysis. Carbothermal reduction at elevated temperature (near 1440°C) helped recover a majority of the metal values (e.g., Fe, Cu and Mo) into the iron-rich alloy product which can be a feed material for steel making. On the other hand, the non-metallic residue, the secondary slag, can be used in the glass and ceramic industries. Reduction time and temperature and carbon content were shown to be the most important process variables for the reaction which were optimized to identify the most favored operating regime that maximizes the metal recovery and simultaneously maximizes the hardness of the secondary slag and minimizes its density, the two major criteria for the secondary slag product to be utilizable. The flux addition level was shown to have relatively less impact on the process performance if these are maintained at an adequate level. The work established that the copper slag, a waste material, can be successfully processed to generate reusable products through pyrometallurgical processing. Copyright © 2017 Elsevier Ltd. All rights reserved.

Pore Structure Characterization of Sodium Hydroxide Activated Slag Using Mercury Intrusion Porosimetry, Nitrogen Adsorption, and Image Analysis.

PubMed

Zuo, Yibing; Ye, Guang

2018-06-19

The pore structure of alkali-activated slag has a significant influence on its performance. However, the literature shows insufficient studies regarding the suitability of different techniques for characterizing the pore structure and the influences of Na₂O and curing age on pore structure development. In pursuit of a better understanding, the pore structure of sodium hydroxide activated slag paste was characterized by multiple techniques, e.g., mercury intrusion porosimetry (MIP), nitrogen (N₂) adsorption, and scanning electron microscopy (SEM) image analysis. The sodium hydroxide activated slag pastes were prepared with three different contents of Na₂O (Na₂O/slag = 4, 6, and 8%) and cured for different times up to 360 days. The microstructure observation reveals that outer C⁻(N⁻)A⁻S⁻H and inner C⁻(N⁻)A⁻S⁻H grow successively around the reacting slag grains, along with crystalline reaction products which are formed in the empty coarse pore space. The increase of Na₂O content and curing age lead to a finer pore structure. The MIP measurements show that the total porosity drops about 70% within the first day, and that one peak at most, corresponding to gel pores, was identified in the differential curves of all the investigated samples from 1 to 360 days. On the contrary, only one peak, corresponding to capillary pores, was identified by SEM-image analysis. The differential curves derived from N₂ adsorption generally reveal two peaks, and the trend that the pore diameters of those two peaks vary with curing age depends on the content of Na₂O. Compared to Portland cement, sodium hydroxide activated slag has a higher pore space filling capacity ( χ , V products / V slag-reacted ), while the capacity decreases with increasing Na₂O content and curing age.

Environmental impact of ferrochrome slag in road construction.

PubMed

Lind, B B; Fällman, A M; Larsson, L B

2001-01-01

Vargon Alloys in Western Sweden is one of the largest producers of ferrochrome slag in Europe. Ferrochrome slag is a by-product from the production of ferrochrome, an essential component in stainless steel. Extensive tests have been carried out on the physical properties of the ferrochrome slag from Vargon Alloys and it was found to be highly suitable as road construction material. The composition and leaching tests of the ferrochrome slag show that the chromium content is high, 1-3%, although leaching under normal conditions is very low. With the exception of potassium (K), which had a potential leaching capacity (availability test) of around 16%, the leaching of chromium, nickel, zinc and other elements was just a few per cent. However, all these tests were conducted in the laboratory. What happens out in the field, under the influence of acid rain and biological activity, and how does this compare with the laboratory results? To answer this question an investigation was carried out to study the environmental impact of ferrochrome slag in roads that were built in 1994. The investigation includes soil sampling (total content and leachable amounts of metals) and groundwater analysis (filtered and non-filtered samples). In addition, a new method involving the bio-uptake of chromium and other metals by the roots of the dandelion (Taraxacum officinale) was tested. The results show that there was a low migration of particles from the slag to the underlying soil and that the leaching into the groundwater was also low for all the elements analysed. However, there seemed to be a significant uptake of Cr by plants growing with their roots in the slag. An investigation of plant uptake was an important complement to laboratory leaching tests on alternative materials.

Effect of Initial FeO Content and CaO:SiO2 Ratio on the Reduction Smelting Kinetics of the CaO-SiO2-MgOsatd.-FeO Slag System

NASA Astrophysics Data System (ADS)

Kim, Jong Bae; Sohn, Il

2018-02-01

The effect of the initial FeO content and CaO:SiO2 ratio (CaO mass pct/SiO2 mass pct) on the reduction smelting of FeO with carbon flake addition is investigated in the CaO-MgOsatd.-SiO2-FeO slag system at 1823 K (1550 °C). Carbon rapidly reacted with FeO in the molten slag, causing both foaming and compositional changes in the slag. As FeO is reduced, the MgO saturation is modified, and solid precipitants, including MgO and other complex oxides, were observed, which significantly affected the slag properties, including the viscosity and foaming behavior. The solid-phase fraction and viscosity were estimated from changes in the measured FeO content over time using the thermochemical software FactSage. The iron recovery, which is distinguished from the amount of reduced Fe droplets, showed opposite behavior to the measured maximum foaming height and modified foaming index. According to the FeO mass transfer coefficient considering slag foaming at various initial FeO contents and CaO:SiO2 ratios, the reduction rate was optimal at higher initial FeO contents and a CaO:SiO2 ratio of 2.0, which did not correspond to the optimal iron recovery at an initial FeO content of 44 mass pct and above and a CaO:SiO2 ratio of 1.2. The results showed that slag foaming may increase the reduction kinetics, but the slag composition needs to be optimized for greater iron recovery.

Dynamic Model of Basic Oxygen Steelmaking Process Based on Multi-zone Reaction Kinetics: Model Derivation and Validation

NASA Astrophysics Data System (ADS)

Rout, Bapin Kumar; Brooks, Geoff; Rhamdhani, M. Akbar; Li, Zushu; Schrama, Frank N. H.; Sun, Jianjun

2018-04-01

A multi-zone kinetic model coupled with a dynamic slag generation model was developed for the simulation of hot metal and slag composition during the basic oxygen furnace (BOF) operation. The three reaction zones (i) jet impact zone, (ii) slag-bulk metal zone, (iii) slag-metal-gas emulsion zone were considered for the calculation of overall refining kinetics. In the rate equations, the transient rate parameters were mathematically described as a function of process variables. A micro and macroscopic rate calculation methodology (micro-kinetics and macro-kinetics) were developed to estimate the total refining contributed by the recirculating metal droplets through the slag-metal emulsion zone. The micro-kinetics involves developing the rate equation for individual droplets in the emulsion. The mathematical models for the size distribution of initial droplets, kinetics of simultaneous refining of elements, the residence time in the emulsion, and dynamic interfacial area change were established in the micro-kinetic model. In the macro-kinetics calculation, a droplet generation model was employed and the total amount of refining by emulsion was calculated by summing the refining from the entire population of returning droplets. A dynamic FetO generation model based on oxygen mass balance was developed and coupled with the multi-zone kinetic model. The effect of post-combustion on the evolution of slag and metal composition was investigated. The model was applied to a 200-ton top blowing converter and the simulated value of metal and slag was found to be in good agreement with the measured data. The post-combustion ratio was found to be an important factor in controlling FetO content in the slag and the kinetics of Mn and P in a BOF process.

Recovery of Copper from Slow Cooled Ausmelt Furnace Slag by Floatation

NASA Astrophysics Data System (ADS)

Xue, Ping; Li, Guangqiang; Qin, Qingwei

Ausmelt furnace slag contains about 0.9% Cu (mass %). With increasing the amount of Ausmelt furnace slag, the recovery of copper from it will produce an enormous economic yield. The recovery of copper by floatation from slow cooled Ausmelt furnace slag was studied in this paper. The phases and composition of the slow cooled slag were analyzed. The factors which affected the copper recovery efficiency such as grinding fineness, pH value of flotation medium, different collectors and floating process were investigated. It was shown that the size distribution of the primary grinding and secondary grinding of middling were 75% for particles less than 0.074mm and 82% for particles less than 0.043mm respectively. The closed-circuit experimental results with butyl xanthate as collector in laboratory showed that the copper grade reached 16.11% and the recovery rate of copper reached 69.90% and the copper grade of tailings was only 0.2%.

Pragmatic analysis of the electric submerged arc furnace continuum

NASA Astrophysics Data System (ADS)

Karalis, K.; Karkalos, N.; Antipas, G. S. E.; Xenidis, A.

2017-09-01

A transient mathematical model was developed for the description of fluid flow, heat transfer and electromagnetic phenomena involved in the production of ferronickel in electric arc furnaces. The key operating variables considered were the thermal and electrical conductivity of the slag and the shape, immersion depth and applied electric potential of the electrodes. It was established that the principal stimuli of the velocities in the slag bath were the electric potential and immersion depth of the electrodes and the thermal and electrical conductivities of the slag. Additionally, it was determined that, under the set of operating conditions examined, the maximum slag temperature ranged between 1756 and 1825 K, which is in accordance with industrial measurements. Moreover, it was affirmed that contributions to slag stirring due to Lorentz forces and momentum forces due to the release of carbon monoxide bubbles from the electrode surface were negligible.

Nitrogen removal in wood chip combined substrate baffled subsurface-flow constructed wetlands: impact of matrix arrangement and intermittent aeration.

PubMed

Li, Huai; Chi, Zifang; Yan, Baixing; Cheng, Long; Li, Jianzheng

2017-02-01

In this study, two lab-scale baffled subsurface-flow constructed wetlands (BSFCWs), including gravel-wood chips-slag and gravel-slag-wood chips, were operated at different intermittent aeration to evaluate the effect of artificial aeration and slow-released carbon source on the treatment efficiency of high-strength nitrogen wastewater. Results indicated that gravel-slag-wood chips extended aerobic/anaerobic alternating environment to gravel and slag zones and maintained anaerobic condition in the subsequent wood chip section. The order of gravel-slag-wood chip was more beneficial to pollutant removal. Sufficient carbon source supply resulted from wood-chip-framework substrate simultaneously obtained high removals of COD (97%), NH 4 + -N (95%), and TN (94%) in BSFCWs at 2 h aeration per day. The results suggest that intermittent aeration combined with wood chips could achieve high nitrogen removal in BSFCWs.

Element Distribution in the Oxygen-Rich Side-Blow Bath Smelting of a Low-Grade Bismuth-Lead Concentrate

NASA Astrophysics Data System (ADS)

Yang, Tianzu; Xiao, Hui; Chen, Lin; Chen, Wei; Liu, Weifeng; Zhang, Duchao

2018-03-01

Oxygen-rich side-blow bath smelting (OSBS) technology offers an efficient method for processing complex bismuth-lead concentrates; however, the element distributions in the process remain unclear. This work determined the distributions of elements, i.e., bismuth, lead, silver, copper, arsenic and antimony, in an industrial-scale OSBS process. The feed, oxidized slag and final products were collected from the respective sampling points and analyzed. For the oxidative smelting process, 65% of bismuth and 76% of silver in the concentrate report to the metal alloy, whereas less lead reports to the metal ( 31%) than the oxidized slag ( 44%). Approximately 50% of copper enters the matte, while more than 63% of arsenic and antimony report to the slag. For the reductive smelting process, less than 4.5% of bismuth, lead, silver and copper in the oxidized slag enter the reduced slag, indicating high recoveries of these metal values.

Pragmatic analysis of the electric submerged arc furnace continuum

PubMed Central

Karkalos, N.; Xenidis, A.

2017-01-01

A transient mathematical model was developed for the description of fluid flow, heat transfer and electromagnetic phenomena involved in the production of ferronickel in electric arc furnaces. The key operating variables considered were the thermal and electrical conductivity of the slag and the shape, immersion depth and applied electric potential of the electrodes. It was established that the principal stimuli of the velocities in the slag bath were the electric potential and immersion depth of the electrodes and the thermal and electrical conductivities of the slag. Additionally, it was determined that, under the set of operating conditions examined, the maximum slag temperature ranged between 1756 and 1825 K, which is in accordance with industrial measurements. Moreover, it was affirmed that contributions to slag stirring due to Lorentz forces and momentum forces due to the release of carbon monoxide bubbles from the electrode surface were negligible. PMID:28989738

Element Distribution in the Oxygen-Rich Side-Blow Bath Smelting of a Low-Grade Bismuth-Lead Concentrate

NASA Astrophysics Data System (ADS)

Yang, Tianzu; Xiao, Hui; Chen, Lin; Chen, Wei; Liu, Weifeng; Zhang, Duchao

2018-06-01

Oxygen-rich side-blow bath smelting (OSBS) technology offers an efficient method for processing complex bismuth-lead concentrates; however, the element distributions in the process remain unclear. This work determined the distributions of elements, i.e., bismuth, lead, silver, copper, arsenic and antimony, in an industrial-scale OSBS process. The feed, oxidized slag and final products were collected from the respective sampling points and analyzed. For the oxidative smelting process, 65% of bismuth and 76% of silver in the concentrate report to the metal alloy, whereas less lead reports to the metal ( 31%) than the oxidized slag ( 44%). Approximately 50% of copper enters the matte, while more than 63% of arsenic and antimony report to the slag. For the reductive smelting process, less than 4.5% of bismuth, lead, silver and copper in the oxidized slag enter the reduced slag, indicating high recoveries of these metal values.

Vitrification of MSWI Fly Ash by Thermal Plasma Melting and Fate of Heavy Metals

NASA Astrophysics Data System (ADS)

Ni, Guohua; Zhao, Peng; Jiang, Yiman; Meng, Yuedong

2012-09-01

Municipal solid waste incinerator (MSWI) fly ash with high basicity (about 1.68) was vitrified in a thermal plasma melting furnace system. Through the thermal plasma treatment, the vitrified product (slag) with amorphous dark glassy structure was obtained, and the leachability of hazardous metals in slag was significantly reduced. Meanwhile, it was found that the cooling rate affects significantly the immobility of heavy metals in slag. The mass distribution of heavy metals (Zn, Cd, Cr, Pb, As, Hg) was investigated in residual products (slag, secondary residues and flue gas), in order to analyze the behavior of heavy metals in thermal plasma atmosphere. Heavy metal species with low boiling points accounting for the major fraction of their input-mass were adsorbed in secondary residues by pollution abatement devices, while those with high boiling points tended to be encapsulated in slag.

Researches concerning influence of magnesium, aluminum and titanium lime on steel desulfurization

NASA Astrophysics Data System (ADS)

Putan, V.; Putan, A.; Josan, A.; Vilceanu, L.

2016-02-01

The paper presents the results of laboratory experiments on steel desulphurisation with slag from the system MgO-Al2O3-TiO2. To determine the influence, on the desulphurisation process, of the titanium oxide added in calcium aluminate slag, we experimented, in the laboratory phase, the steel treatment with a mechanical mixture consisting of lime, aluminous slag and slag obtained from the titanium making process through the aluminothermic technology. The steel melting was carried out in an induction furnace of 10 kg capacity, existent in the "Metallic Melts" laboratory of the Engineering Faculty of Hunedoara. During the research, we aimed to establish correlation equations between the sulphur distribution coefficient and the slag components (MgO, Al2O3, TiO2). The data obtained in the experiments were processed in MATLAB programs, resulting multiple correlation equations, which allowed the elucidation of some physical-chemical phenomena specific to the desulphurisation processes.

Vortex Flows in the Liquid Layer and Droplets on a Vibrating Flexible Plate

NASA Astrophysics Data System (ADS)

Aleksandrov, Vladimir; Kopysov, Sergey; Tonkov, Leonid

2018-02-01

In certain conditions, in the layers and droplets of a liquid on a vibrating rectangular flexible plate, vortex flows are formed simultaneously with the excitation of capillary oscillations on the free surface of the liquid layers and droplets. Capillary oscillations in the form of two-dimensional standing waves form Faraday ripples on the free surface of the liquid layer. On the surface of the vibrating droplets, at the excitation of capillary oscillations a light spot reflected from a spotlight source moves along a trajectory in the form of a Lissajous figure observed with a microscope. When vortex flows visualized with graphite microparticles appear in the layer and droplets of a transparent liquid, the trajectory of the light spot on the layer and droplet surface is a two-dimensional trajectory in the form of an ellipse or a saddle. This indicates that the generation of the vortex flows in a liquid at vibrations is due to capillary oscillations in the orthogonally related directions. In the liquid layer and droplets on the surface of the flexible plate, the vibrations of which are generated by bending vibrations, the vortex flows appear due to the plate vibrations and the capillary oscillations of the surface of a layer or a droplet of the liquid. On the free surface of the liquid, the capillary waves, which are parametrically excited by the plate bending vibrations, are additionally modulated by the same bending vibrations in the transverse direction.

Method for improving the durability of ion insertion materials

DOEpatents

Lee, Se-Hee; Tracy, C. Edwin; Cheong, Hyeonsik M.

2002-01-01

The invention provides a method of protecting an ion insertion material from the degradative effects of a liquid or gel-type electrolyte material by disposing a protective, solid ion conducting, electrically insulating, layer between the ion insertion layer and the liquid or gel-type electrolyte material. The invention further provides liquid or gel-type electrochemical cells having improved durability having a pair of electrodes, a pair of ion insertion layers sandwiched between the pair of electrodes, a pair of solid ion conducting layers sandwiched between the ion insertion layers, and a liquid or gel-type electrolyte material disposed between the solid ion conducting layers, where the solid ion conducting layer minimizes or prevents degradation of the faces of the ion insertion materials facing the liquid or gel-type electrolyte material. Electrochemical cells of this invention having increased durability include secondary lithium batteries and electrochromic devices.

40 CFR 421.73 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... produced Lead .000 .000 Zinc .000 .000 (d) Subpart G—Dross Reverberatory Slag Granulation. BAT Effluent... per billion pounds) of slag, speiss, or matte granulated Lead 1,612.000 748.400 Zinc 5,872.000 2,418... produced Lead .000 .000 Zinc .000 .000 (g) Subpart G—Hard Lead Refining Slag Granulation. BAT Effluent...

40 CFR 421.73 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2011 CFR

2011-07-01

... produced Lead .000 .000 Zinc .000 .000 (d) Subpart G—Dross Reverberatory Slag Granulation. BAT Effluent... per billion pounds) of slag, speiss, or matte granulated Lead 1,612.000 748.400 Zinc 5,872.000 2,418... produced Lead .000 .000 Zinc .000 .000 (g) Subpart G—Hard Lead Refining Slag Granulation. BAT Effluent...

URANIUM RECOVERY PROCESS

DOEpatents

Stevenson, J.W.; Werkema, R.G.

1959-07-28

The recovery of uranium from magnesium fluoride slag obtained as a by- product in the production of uranium metal by the bomb reduction prccess is presented. Generally the recovery is accomplished by finely grinding the slag, roasting ihe ground slag air, and leaching the roasted slag with a hot, aqueous solution containing an excess of the sodium bicarbonate stoichiometrically required to form soluble uranium carbonate complex. The roasting is preferably carried out at between 425 and 485 deg C for about three hours. The leaching is preferably done at 70 to 90 deg C and under pressure. After leaching and filtration the uranium may be recovered from the clear leach liquor by any desired method.

A Slag Management Toolset for Determining Optimal Coal Gasification Temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kwong, Kyei-Sing; Bennett, James P.

Abstract Gasifier operation is an intricate process because of the complex relationship between slag chemistry and temperature, limitations of feedstock materials, and operational preference. High gasification temperatures increase refractory degradation, while low gasification temperatures can lead to slag buildup on the gasifier sidewall or exit, either of which are problematic during operation. Maximizing refractory service life and gasifier performance require finding an optimized operating temperature range which is a function of the coal slag chemistry and viscosity. Gasifier operators typically use a slag’s viscosity-temperature relationship and/or ash-fusion fluid temperature to determine the gasification temperature range. NETL has built a slagmore » management toolset to determine the optimal temperature range for gasification of a carbon feedstock. This toolset is based on a viscosity database containing experimental data, and a number of models used to predict slag viscosity as a function of composition and temperature. Gasifier users typically have no scientific basis for selecting an operational temperature range for gasification, instead using experience to select operational conditions. The use of the toolset presented in this paper provides a basis for estimating or modifying carbon feedstock slags generated from ash impurities in carbon feedstock.« less

Analysis on the Oversize Blast Furnace Desulfurization and a Sulfide Capacity Prediction Model Based on Congregated Electron Phase

NASA Astrophysics Data System (ADS)

Zhenyang, Wang; Jianliang, Zhang; Gang, An; Zhengjian, Liu; Zhengming, Cheng; Junjie, Huang; Jingwei, Zhang

2016-02-01

Through analyzed and regressed the actual productive desulfurization data from the oversize blast furnace (5500 m3) in north China, the relationship between the sulfur distribution parameters and the slag composition in actual production situation was investigated. As the slag and hot metal phases have their own balance sulfur content or sulfur partial pressure in gas phase, respectively, the non-equilibrium of sulfur among gas, slag, and metal phases leads to the transmission and distribution of sulfur. Combined with sulfur transmission reactions between gas, slag and metal phases, C/CO pairs equilibrium, and Wagner model, the measured sulfide capacity can be acquired using sulfur distribution ratio, sulfur activity coefficient, and oxygen activity in hot metal. Based on the theory of congregated electron phase, a new sulfide capacity prediction model (CEPM) has been developed, which has a good liner relationship with the measured sulfide capacity. Thus, using the burden structure for BF, the ironmaking slag composition can be obtained simply and can be used to reliably predict the ironmaking slag desulfurization ability a few hours later after charging under a certain temperature by CEPM.

Risk assessment of heavy metals from combustion of pelletized municipal sewage sludge.

PubMed

Xiao, Zhihua; Yuan, Xingzhong; Leng, Lijian; Jiang, Longbo; Chen, Xiaohong; Zhibin, Wu; Xin, Peng; Jiachao, Zhang; Zeng, Guangming

2016-02-01

Fly ash and slag are important by-products obtained from combustion of municipal sewage sludge (MSS) after pelletization. The quantitative environmental impact assessment of heavy metals in fly ash and slag, compared to MSS, were performed in accordance with bioavailability and eco-toxicity, geo-accumulation index (GAI), risk assessment code (RAC), and potential ecological risk index (PERI). The results demonstrated that not only direct but also long-term bioavailability and eco-toxicity of heavy metals in fly ash and slag decreased except direct bioavailability and eco-toxicity of Pb in fly ash. The GAI demonstrated that combustion significantly weakened (P < 0.05) the pollution levels of heavy metals. PERI indicated that all risks attributed to heavy metals were significantly lowered (P < 0.05) from 777.07 (very high risk) in MSS to 288.72 (moderate risk) and 64.55 (low risk) in fly ash and slag, respectively. In terms of the RAC, seven heavy metals had low even no risk to the environments after combustion besides As in slag. The environmental risk of heavy metals in fly ash and slag was decreased compared with MSS. However, the results of PERI showed that fly ash had a moderate risk.

A Slag Management Toolset for Determining Optimal Coal Gasification Temperatures

DOE PAGES

Kwong, Kyei-Sing; Bennett, James P.

2016-11-25

Abstract Gasifier operation is an intricate process because of the complex relationship between slag chemistry and temperature, limitations of feedstock materials, and operational preference. High gasification temperatures increase refractory degradation, while low gasification temperatures can lead to slag buildup on the gasifier sidewall or exit, either of which are problematic during operation. Maximizing refractory service life and gasifier performance require finding an optimized operating temperature range which is a function of the coal slag chemistry and viscosity. Gasifier operators typically use a slag’s viscosity-temperature relationship and/or ash-fusion fluid temperature to determine the gasification temperature range. NETL has built a slagmore » management toolset to determine the optimal temperature range for gasification of a carbon feedstock. This toolset is based on a viscosity database containing experimental data, and a number of models used to predict slag viscosity as a function of composition and temperature. Gasifier users typically have no scientific basis for selecting an operational temperature range for gasification, instead using experience to select operational conditions. The use of the toolset presented in this paper provides a basis for estimating or modifying carbon feedstock slags generated from ash impurities in carbon feedstock.« less

Intrinsic differences in atomic ordering of calcium (alumino)silicate hydrates in conventional and alkali-activated cements

DOE Office of Scientific and Technical Information (OSTI.GOV)

White, Claire E., E-mail: whitece@princeton.edu; Andlinger Center for Energy and the Environment, Princeton University, Princeton; Lujan Neutron Scattering Center, Los Alamos National Laboratory, Los Alamos

2015-01-15

The atomic structures of calcium silicate hydrate (C–S–H) and calcium (–sodium) aluminosilicate hydrate (C–(N)–A–S–H) gels, and their presence in conventional and blended cement systems, have been the topic of significant debate over recent decades. Previous investigations have revealed that synthetic C–S–H gel is nanocrystalline and due to the chemical similarities between ordinary Portland cement (OPC)-based systems and low-CO{sub 2} alkali-activated slags, researchers have inferred that the atomic ordering in alkali-activated slag is the same as in OPC–slag cements. Here, X-ray total scattering is used to determine the local bonding environment and nanostructure of C(–A)–S–H gels present in hydrated tricalcium silicatemore » (C{sub 3}S), blended C{sub 3}S–slag and alkali-activated slag, revealing the large intrinsic differences in the extent of nanoscale ordering between C–S–H derived from C{sub 3}S and alkali-activated slag systems, which may have a significant influence on thermodynamic stability, and material properties at higher length scales, including long term durability of alkali-activated cements.« less

Geochemical characterization of slags, other mines wastes, and their leachates from the Elizabeth and Ely mines (Vermont), the Ducktown mining district (Tennessee), and the Clayton smelter site (Idaho)

USGS Publications Warehouse

Piatak, Nadine M.; Seal, Robert R.; Hammarstrom, Jane M.; Meier, Allen L.; Briggs, Paul H.

2003-01-01

Waste-rock material produced at historic metal mines contains elevated concentrations of potentially toxic trace elements. Two types of mine waste were examined in this study: sintered waste rock and slag. The samples were collected from the Elizabeth and Ely mines in the Vermont copper belt (Besshi-type massive sulfide deposits), from the Copper Basin mining district near Ducktown, Tennessee (Besshi-type massive sulfide deposits), and from the Clayton silver mine in the Bayhorse mining district, Idaho (polymetallic vein and replacement deposits). The data in this report are presented as a compilation with minimal interpretation or discussion. A detailed discussion and interpretation of the slag data are presented in a companion paper. Data collected from sintered waste rock and slag include: (1) bulk rock chemistry, (2) mineralogy, (3) and the distribution of trace elements among phases for the slag samples. In addition, the reactivity of the waste material under surficial conditions was assessed by examining secondary minerals formed on slag and by laboratory leaching tests using deionized water and a synthetic solution approximating precipitation in the eastern United States.

Environmental and Geotechnical Assessment of the Steel Slags as a Material for Road Structure.

PubMed

Sas, Wojciech; Głuchowski, Andrzej; Radziemska, Maja; Dzięcioł, Justyna; Szymański, Alojzy

2015-07-30

Slags are the final solid wastes from the steel industry. Their production from waste and associated materials is a proper implementation of the basic objectives and principles of the waste management. This study aims to investigate the chemical and selected significant geotechnical parameters of steel slag as the alternative materials used in road construction. These investigations are strongly desired for successful application in engineering. Young's modules E , and resilient modules M r showed that their values corresponding with requirements for subbase (principal or auxiliary) and riding surface as well. Tested mechanical properties were conducted in soaked and un-soaked (optimal moisture content) conditions. The designated high content of chromium and zinc are strongly associated with the internal crystal structure of steel slag. The results do not lead to threats when they are applied in roads' structures. Mechanical characterization was obtained by performing California bearing ratio (CBR) tests for steel slag in fixed compaction and moisture content conditions. Moreover, cyclic loading of steel slag was conducted with the application of cyclic California bearing ratio (cCBR) apparatus to characterization of this material as a controlled low-strength material. Finally, field studies that consist of static load plate VSS tests were presented.

Investigating waste rock, tailings, slag and coal ash clinker as adsorbents for heavy metals: Batch and column studies

NASA Astrophysics Data System (ADS)

Letina, D.; Letshwenyo, W. M.

2018-06-01

Wastewater from the mining industry is a concern because most of the time it contains heavy metals with concentrations above permissible levels, posing a threat to terrestrial and aquatic life. The study was conducted to evaluate the effectiveness of locally available waste materials (waste rock, tailings, coal ash clinker, and slag) generated by BCL (Ltd) mine, a copper and nickel mining and smelting company in Botswana, for removal of nickel and copper from the real mining wastewater. Batch adsorption studies were conducted to establish the adsorptive efficiency and kinetics of each media with respect to nickel and copper ions. The best media was further evaluated through fixed bed column studies at 24 and 48 h empty bed contact time. The results indicate that the percentage removal for coal ash clinker, waste rock, smelter slag and tailings was 98%, 15%, 3% and -3% with respect to copper ions, and 46%, 9%, 7% and 2% with respect to nickel ions for each media respectively. Coal ash clinker followed pseudo first order kinetic model and Langmuir isotherm model with respect to nickel ions indicating the dominance of physisorption and mono layer coverage respectively. The Langmuir separation factor (RL) was 0.37 suggesting favourable adsorption onto the media. Fixed bed column studies revealed that copper was completely retained in the bed at both 24 and 48 h contact times. In the case of nickel, removal efficiency ranged between 83% and 99% when contact time was 48 h and between 68% and 99% when the contact time was reduced to 24 h. Breakthrough was not reached after 19 bed volumes. It can be concluded that coal ash clinker is a better candidate for the removal of copper and nickel ions from mining wastewater.

Study on dynamic deformation synchronized measurement technology of double-layer liquid surfaces

NASA Astrophysics Data System (ADS)

Tang, Huiying; Dong, Huimin; Liu, Zhanwei

2017-11-01

Accurate measurement of the dynamic deformation of double-layer liquid surfaces plays an important role in many fields, such as fluid mechanics, biomechanics, petrochemical industry and aerospace engineering. It is difficult to measure dynamic deformation of double-layer liquid surfaces synchronously for traditional methods. In this paper, a novel and effective method for full-field static and dynamic deformation measurement of double-layer liquid surfaces has been developed, that is wavefront distortion of double-wavelength transmission light with geometric phase analysis (GPA) method. Double wavelength lattice patterns used here are produced by two techniques, one is by double wavelength laser, and the other is by liquid crystal display (LCD). The techniques combine the characteristics such as high transparency, low reflectivity and fluidity of liquid. Two color lattice patterns produced by laser and LCD were adjusted at a certain angle through the tested double-layer liquid surfaces simultaneously. On the basis of the refractive indexes difference of two transmitted lights, the double-layer liquid surfaces were decoupled with GPA method. Combined with the derived relationship between phase variation of transmission-lattice patterns and out-of plane heights of two surfaces, as well as considering the height curves of the liquid level, the double-layer liquid surfaces can be reconstructed successfully. Compared with the traditional measurement method, the developed method not only has the common advantages of the optical measurement methods, such as high-precision, full-field and non-contact, but also simple, low cost and easy to set up.

Thermodynamic effects of calcium and iron oxides on crystal phase formation in synthetic gasifier slags containing from 0 to 27wt.% V 2O 3

DOE PAGES

Nakano, Jinichiro; Duchesne, Marc; Bennett, James; ...

2014-11-15

Thermodynamic phase equilibria in synthetic slags (Al 2O 3–CaO–FeO–SiO 2–V 2O 3) were investigated with 0–27 wt.% vanadium oxide corresponding to industrial coal–petroleum coke (petcoke) feedstock blends in a simulated gasifier environment. Samples encompassing coal–petcoke mixed slag compositions were equilibrated at 1500 °C in a 64 vol.% CO/36 vol.% CO 2 atmosphere (Po 2 ≈ 10 –8 atm at 1500 °C) for 72 h, followed by rapid water quench, then analyzed by inductively coupled plasma optical emission spectrometry, X-ray diffractometry, and scanning electron microscopy with wavelength dispersive spectroscopy. With increasing CaO content, FeO content, or both; the slag homogeneity regionmore » expanded and a composition range exhibiting crystals was reduced. The mullite (Al 6Si 2O 13) crystalline phase was not present in the slags above 9 wt.% FeO while the karelianite (V 2O 3) crystalline phase was always present in compositions studied if a sufficient amount of vanadium existed in the slag. Furthermore, based on the present experimental equilibrium evaluation, a set of isothermal phase diagrams showing effects of CaO and FeO on thermodynamic phase stabilities in the vanadium-bearing slags is proposed. Some uses of the diagrams for potential industrial practice are discussed.« less

Gel nanostructure in alkali-activated binders based on slag and fly ash, and effects of accelerated carbonation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bernal, Susan A., E-mail: s.bernal@sheffield.ac.uk; Department of Materials Science and Engineering, The University of Sheffield, Sheffield S1 3JD; Provis, John L., E-mail: j.provis@sheffield.ac.uk

2013-11-15

Binders formed through alkali-activation of slags and fly ashes, including ‘fly ash geopolymers’, provide appealing properties as binders for low-emissions concrete production. However, the changes in pH and pore solution chemistry induced during accelerated carbonation testing provide unrealistically low predictions of in-service carbonation resistance. The aluminosilicate gel remaining in an alkali-activated slag system after accelerated carbonation is highly polymerised, consistent with a decalcification mechanism, while fly ash-based binders mainly carbonate through precipitation of alkali salts (bicarbonates at elevated CO{sub 2} concentrations, or carbonates under natural exposure) from the pore solution, with little change in the binder gel identifiable by nuclearmore » magnetic resonance spectroscopy. In activated fly ash/slag blends, two distinct gels (C–A–S–H and N–A–S–H) are formed; under accelerated carbonation, the N–A–S–H gel behaves comparably to fly ash-based systems, while the C–A–S–H gel is decalcified similarly to alkali-activated slag. This provides new scope for durability optimisation, and for developing appropriate testing methodologies. -- Highlights: •C-A-S-H gel in alkali-activated slag decalcifies during accelerated carbonation. •Alkali-activated fly ash gel changes much less under CO{sub 2} exposure. •Blended slag-fly ash binder contains two coexisting gel types. •These two gels respond differently to carbonation. •Understanding of carbonation mechanisms is essential in developing test methods.« less

Copper slag as a catalyst for mercury oxidation in coal combustion flue gas.

PubMed

Li, Hailong; Zhang, Weilin; Wang, Jun; Yang, Zequn; Li, Liqing; Shih, Kaimin

2018-04-01

Copper slag is a byproduct of the pyrometallurgical smelting of copper concentrate. It was used in this study to catalyze elemental mercury (Hg 0 ) oxidation in simulated coal combustion flue gas. The copper slag exhibited excellent catalytic performance in Hg 0 oxidation at temperatures between 200 °C and 300 °C. At the most optimal temperature of 250 °C, a Hg 0 oxidation efficiency of 93.8% was achieved under simulated coal combustion flue gas with both a high Hg 0 concentration and a high gas hourly space velocity of 128,000 h -1 . Hydrogen chloride (HCl) was the flue gas component responsible for Hg 0 oxidation over the copper slag. The transition metal oxides, including iron oxides and copper oxide in the copper slag, exhibited significant catalytic activities in the surface-mediated oxidation of Hg 0 in the presence of HCl. It is proposed that the Hg 0 oxidation over the copper slag followed the Langmuir-Hinshelwood mechanism whereby reactive chlorine species that originated from HCl reacted with the physically adsorbed Hg 0 to form oxidized mercury. This study demonstrated the possibility of reusing copper slag as a catalyst for Hg 0 oxidation and revealed the mechanisms involved in the process and the key factors in the performance. This knowledge has fundamental importance in simultaneously reducing industrial waste and controlling mercury emissions from coal-fired power plants. Copyright © 2017 Elsevier Ltd. All rights reserved.

Tracing the Origin of Non-ferrous Oxides in Lamination Defects on Hot-Rolled Coils: Mold Slag Entrainment vs Submerged Entry Nozzle Reaction Products

NASA Astrophysics Data System (ADS)

Sengo, Sabri; Romano Triguero, Patricia; Zinngrebe, Enno; Mensonides, Fokko

2017-06-01

In this work, lamination defects (slivers) on hot-rolled coils of Ca-treated steel were investigated for microstructure and composition using optical and scanning electron microscopy combined with microanalysis (SEM/EDS). The goal was to identify possible origins for the observed defects which contain a complex assemblage of phases, such as different types of calcium aluminates (CA, CA2, CA6), melilite (C2AS), spinel (MA), and a newly identified phase, CNA2. Mold slag similar to that employed during the cast was absent. Analysis of the bulk composition of some of the defects indicated these to be too rich in alumina to be derived from mold slag through steel-slag redox exchange. In contrast, microstructural observation of the inner side of the submerged entry nozzles (SEN) used during casting showed deposits with compositions comparable to those of the defect material. Based on an estimation of the chemical evolution of mold slag interacting with steel, it is found that the defects are not likely to be entrained mold slag but remobilized SEN deposits, as supported by several microstructural and trace phase criteria. However, it should be noted that extensive reduction of mold slag by steel can lead to compositions rich in sodic-calcic aluminates (CNA2). Therefore, differentiation between specific locations of the defect materials within a casting system requires detailed analysis from the potential sources of origin as well as from the materials found in the defects.

Evaluation of the microstructure, secondary dendrite arm spacing, and mechanical properties of Al-Si alloy castings made in sand and Fe-Cr slag molds

NASA Astrophysics Data System (ADS)

Narasimha Murthy, I.; Babu Rao, J.

2017-07-01

The microstructure and mechanical properties of as-cast A356 (Al-Si) alloy castings were investigated. A356 alloy was cast into three different molds composed of sand, ferrochrome (Fe-Cr) slag, and a mixture of sand and Fe-Cr. A sodium silicate-CO2 process was used to make the necessary molds. Cylindrical-shaped castings were prepared. Cast products with no porosity and a good surface finish were achieved in all of the molds. These castings were evaluated for their metallography, secondary dendrite arm spacing (SDAS), and mechanical properties, including hardness, compression, tensile, and impact properties. Furthermore, the tensile and impact samples were analyzed by fractography. The results show that faster heat transfer in the Fe-Cr slag molds than in either the silica sand or mixed molds led to lower SDAS values with a refined microstructure in the products cast in Fe-Cr slag molds. Consistent and enhanced mechanical properties were observed in the slag mold products than in the castings obtained from either sand or mixed molds. The fracture surface of the slag mold castings shows a dimple fracture morphology with a transgranular fracture nature. However, the fracture surfaces of the sand mold castings display brittle fracture. In conclusion, products cast in Fe-Cr slag molds exhibit an improved surface finish and enhanced mechanical properties compared to those of products cast in sand and mixed molds.

Cleaning of waste smelter slags and recovery of valuable metals by pressure oxidative leaching.

PubMed

Li, Yunjiao; Perederiy, Ilya; Papangelakis, Vladimiros G

2008-04-01

Huge quantities of slag, a waste solid product of pyrometallurgical operations by the metals industry are dumped continuously around the world, posing a potential environmental threat due to entrained values of base metals and sulfur. High temperature pressure oxidative acid leaching of nickel smelter slags was investigated as a process to facilitate slag cleaning and selective dissolution of base metals for economic recovery. Five key parameters, namely temperature, acid addition, oxygen overpressure, solids loading and particle size, were examined on the process performance. Base metal recoveries, acid and oxygen consumptions were accurately measured, and ferrous/ferric iron concentrations were also determined. A highly selective leaching of valuable metals with extractions of >99% for nickel and cobalt, >97% for copper, >91% for zinc and <2.2% for iron was successfully achieved for 20 wt.% acid addition and 25% solids loading at 200-300 kPa O(2) overpressure at 250 degrees C in 2h. The acid consumption was measured to be 38.5 kg H(2)SO(4)/t slag and the oxygen consumption was determined as 84 kg O(2)/t slag which is consistent with the estimated theoretical oxygen consumption. The as-produced residue containing less than 0.01% of base metals, hematite and virtually zero sulfidic sulfur seems to be suitable for safe disposal. The process seems to be able to claim economic recovery of base metals from slags and is reliable and feasible.

The Integration of Plant Sample Analysis, Laboratory Studies, and Thermodynamic Modeling to Predict Slag-Matte Equilibria in Nickel Sulfide Converting

NASA Astrophysics Data System (ADS)

Hidayat, Taufiq; Shishin, Denis; Grimsey, David; Hayes, Peter C.; Jak, Evgueni

2018-02-01

The Kalgoorlie Nickel Smelter (KNS) produces low Fe, low Cu nickel matte in its Peirce-Smith converter operations. To inform process development in the plant, new fundamental data are required on the effect of CaO in slag on the distribution of arsenic between slag and matte. A combination of plant sample analysis, high-temperature laboratory experiments, and thermodynamic modeling was carried out to identify process conditions in the converter and to investigate the effect of slag composition on the chemical behavior of the system. The high-temperature experiments involved re-equilibration of industrial matte-slag-lime samples at 1498 K (1225 °C) and P(SO2) = 0.12 atm on a magnetite/quartz substrate, rapid quenching in water, and direct measurement of phase compositions using electron probe X-ray microanalysis (EPMA) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). A private thermodynamic database for the Ca-Cu-Fe-Mg-Ni-O-S-Si-(As) system was used together with the FactSage software package to assist in the analysis. Thermodynamic predictions combined with plant sample characterization and the present experimental data provide a quantitative basis for the analysis of the effect of CaO fluxing on the slag-matte thermochemistry during nickel sulfide converting, in particular on the spinel liquidus and the distribution of elements between slag and matte as a function of CaO addition.

Characteristics of waste automotive glasses as silica resource in ferrosilicon synthesis.

PubMed

Farzana, Rifat; Rajarao, Ravindra; Sahajwalla, Veena

2016-02-01

This fundamental research on end-of-life automotive glasses, which are difficult to recycle, is aimed at understanding the chemical and physical characteristics of waste glasses as a resource of silica to produce ferrosilicon. Laboratory experiments at 1550°C were carried out using different automotive glasses and the results compared with those obtained with pure silica. In situ images of slag-metal separation showed similar behaviour for waste glasses and silica-bearing pellets. Though X-ray diffraction (XRD) showed different slag compositions for glass and silica-bearing pellets, formation of ferrosilicon was confirmed. Synthesized ferrosilicon alloy from waste glasses and silica were compared by Raman, X-ray photoelectron spectroscopy and scanning electron microscopy (SEM) analysis. Silicon concentration in the synthesized alloys showed almost 92% silicon recovery from the silica-bearing pellet and 74-92% silicon recoveries from various waste glass pellets. The polyvinyl butyral (PVB) plastic layer in the windshield glass decomposed at low temperature and did not show any detrimental effect on ferrosilicon synthesis. This innovative approach of using waste automotive glasses as a silica source for ferrosilicon production has the potential to create sustainable pathways, which will reduce specialty glass waste in landfill. © The Author(s) 2015.

A novel method of utilization of hot dip galvanizing slag using the heat waste from itself for protection from radiation.

PubMed

Dong, Mengge; Xue, Xiangxin; Kumar, Ashok; Yang, He; Sayyed, M I; Liu, Shan; Bu, Erjun

2018-02-15

A novel, unconventional, low cost, eco-friendly and effective shielding materials have been made utilizing the hot dip galvanizing slag using the heat waste from itself, thereby saving the natural resources and preventing the environmental pollution. SEM-EDS of shielding materials indicates that the other elements are distributed in Zn element. The mass attenuation properties of shielding materials were measured using a narrow beam geometrical setup at 0.662MeV, 1.17MeV and 1.33MeV. The half value thickness layer, effective atomic number, and electron density were used to analyze the shielding performance of the materials. The EBFs and EABFs for the prepared shielding materials were also studied with incident photon energy for penetration depths upto 40mfp. The shielding effectiveness has been compared with lead, iron, zinc, some standard shielding concretes, different glasses and some alloys. The shielding effectiveness of the prepared samples is almost found comparable to iron, zinc, selected alloys and glasses while better than some standard shielding concretes. In addition, it is also found that the bending strength of all shielding materials is more than 110MPa. Copyright © 2017 Elsevier B.V. All rights reserved.

The influence of the mould cooling temperature on the surface appearance and the internal quality of ESR ingots

NASA Astrophysics Data System (ADS)

Kubin, M.; Ofner, B.; Holzgruber, H.; Schneider, R.; Enzenhofer, D.; Filzwieser, A.; Konetschnik, S.

2016-07-01

One of the main benefits of the ESR process is to obtain an ingot surface which is smooth and allows a subsequent forging operation without any surface dressing. The main influencing factor on surface quality is the precise controlling of the process such as melt rate and electrode immersion depth. However, the relatively strong cooling effect of water as a cooling medium can result in the solidification of the meniscus of the liquid steel on the boundary liquid steel and slag which is most likely the origin of surface defects. The usage of different cooling media like ionic liquids, a salt solution which can be heated up to 250°C operating temperature might diminish the meniscus solidification phenomenon. This paper shows the first results of the usage of an ionic liquid as a mould cooling medium. In doing so, 210mm diameter ESR ingots were produced with the laboratory scale ESR furnace at the university of applied science using an ionic liquid cooling device developed by the company METTOP. For each trial melt different inlet and outlet temperatures of the ionic liquid were chosen and the impact on the surface appearance and internal quality were analyzed. Furthermore the influence on the energy balance is also briefly highlighted. Ultimately, an effect of the usage of ionic liquids as a cooling medium could be determined and these results will be described in detail within the scope of this paper.

Forensic Investigation of AC and PCC Pavements with Extended Service Life : Volume 3 : Petrographic Examination of Blast Furnace Slag Aggregate Concrete Cores taken from PCC Pavements in Cuyahoga County , Ohio : Executive Summary Report

DOT National Transportation Integrated Search

2010-09-01

Air-cooled blast furnace slag has been used as a coarse : aggregate in portland cement-based pavement concretes : since at least the early 1900s. Many of these concretes : have performed satisfactorily. In recent times a number : of PCC slag aggre...

Removal of copper from ferrous scrap

DOEpatents

Blander, M.; Sinha, S.N.

1987-07-30

A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

Removal of copper from ferrous scrap

DOEpatents

Blander, M.; Sinha, S.N.

1990-05-15

A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

Removal of copper from ferrous scrap

DOEpatents

Blander, Milton; Sinha, Shome N.

1990-01-01

A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

The use of steel slag in concrete

NASA Astrophysics Data System (ADS)

Martauz, P.; Vaclavik, V.; Cvopa, B.

2017-10-01

This paper presents the results of a research dealing with the use of unstable steel slag as a 100% substitute for natural aggregate in the production of concrete. Portland cement CEM I 42.5N and alkali activated hybrid cement H-CEMENT were used as the binder. The test results confirm the possibility to use steel slag as the filler in the production of concrete.

Geochemical and mineralogical controls on trace element release from the Penn Mine base-metal slag dump, California

USGS Publications Warehouse

Parsons, M.B.; Bird, D.K.; Einaudi, M.T.; Alpers, Charles N.

2001-01-01

Base-metal slag deposits at the Penn Mine in Calaveras County, California, are a source of environmental contamination through leaching of potentially toxic elements. Historical Cu smelting at Penn Mine (1865-1919) generated approximately 200,000 m3 of slag. The slag deposits, which are flooded annually by a reservoir used for drinking water and irrigation, also may be in contact with acidic ground waters (pH < 4) from the adjacent mine area. Slags vary from grey to black, are glassy to crystalline, and range in size from coarse sand to large (0.6 ?? 0.7 ?? 1.5 m), tub-shaped casts. Metals are hosted by a variety of minerals and two glass phases. On the basis of mineralogy, slags are characterized by 4 main types: fayalite-rich, glassy, willemite-rich, and sulfide-rich. The ranges in metal and metalloid concentrations of 17 slag samples are: As, 0.0004-0.92; Ba, 0.13-2.9; Cd, 0.0014-1.4; Cu, 0.18-6.4; Pb, 0.02-11; and Zn, 3.2-28 wt.%. Leachates from Toxicity Characteristic Leaching Procedure tests (acetic acid buffered at pH 4.93) on two wiltemite-rich slags contained Cd and Pb concentrations (up to 2.5 and 30 mg/l, respectively) in excess of US Environmental Protection Agency (USEPA) regulatory limits. Analyses of filtered (0.45 ??m) water, collected within the flooded slag dump during reservoir drawdown, reveal concentrations of Cd (1.7 ??g/l), Cu (35 ??g/l), and Zn (250 ??g/l) that exceed USEPA chronic toxicity guidelines for the protection of aquatic life. Data from field and laboratory studies were used to develop geochemical models with the program EQ3/6 that simulate irreversible mass-transfer between slag deposits and reservoir waters. These models include kinetic rate laws for abiotic sulfide oxidation and surface-controlled dissolution of silicates, oxides, and glass. Calculations demonstrate that the main processes controlling dissolved metal concentrations are (1) dissolution of fayalite, willemite, and glass; (2) sulfide oxidation; and (3) secondary phase precipitation. Close agreement between model results and measured concentrations of Al, Ba, Cu, Fe, SiO2, and SO4 in the slag dump pore waters suggests that the dissolved concentrations of these elements are controlled by solubility equilibrium with secondary phases. Differences between predicted and measured Cd and Pb concentrations imply that field weathering rates of glass and sulfides are approximately two orders of magnitude lower than laboratory rates. Overprediction of Pb release may also reflect other attenuation processes in the natural system, such as sorption or coprecipitation. ?? 2001 Elsevier Science Ltd. All rights reserved.

Recycling of Malaysia's electric arc furnace (EAF) slag waste into heavy-duty green ceramic tile.

PubMed

Teo, Pao-Ter; Anasyida, Abu Seman; Basu, Projjal; Nurulakmal, Mohd Sharif

2014-12-01

Recently, various solid wastes from industry such as glass waste, fly ash, sewage sludge and slag have been recycled into various value-added products such as ceramic tile. The conventional solutions of dumping the wastes in landfills or incineration, including in Malaysia are getting obsolete as the annual huge amount of the solid wastes would boost-up disposal cost and may cause permanent damage to the flora and fauna. This recent waste recycling approach is much better and greener as it can resolve problems associated with over-limit storage of industrial wastes and reduce exploration of natural resources for ceramic tile to continuously sustain the nature. Therefore, in this project, an attempt was made to recycle electric arc furnace (EAF) slag waste, obtained from Malaysia's steel making industry, into ceramic tile via conventional powder compaction method. The research work was divided into two stages. The first stage was to evaluate the suitability of EAF slag in ceramic tile by varying weight percentage of EAF slag (40 wt.%, 50 wt.% and 60 wt.%) and ball clay (40 wt.%, 50 wt.% and 60 wt.%), with no addition of silica and potash feldspar. In the second stage, the weight percentage of EAF slag was fixed at 40 wt.% and the percentage of ball clay (30 wt.% and 40 wt.%), feldspar (10 wt.% and 20 wt.%) and silica (10 wt.% and 20 wt.%) added was varied accordingly. Results obtained show that as weight percentage of EAF slag increased up to 60 wt.%, the percentage of apparent porosity and water absorption also rose, with a reduction in tile flexural strength and increased porosity. On the other hand, limiting the weight percentage of EAF slag to 40 wt.% while increasing the weight percentage of ball clay led to a higher total percentage of anorthite and wollastonite minerals, resulting in higher flexural strength. It was found that introduction of silica and feldspar further improved the flexural strength due to optimization of densification process. The highest flexural strength, lowest apparent porosity and water absorption of EAF slag based tile was attained at the composition of 40 wt.% EAF slag--30 wt.% ball clay--10 wt.% feldspar--20 wt.% silica. The properties of ceramic tile made with EAF slag waste (up to 40 wt.%), especially flexural strength are comparable to those of commercial ceramic tile and are, therefore, suitable as high flexural strength and heavy-duty green ceramic floor tile. Continuous development is currently underway to improve the properties of tile so that this recycling approach could be one of the potential effective, efficient and sustainable solutions in sustaining our nature. Copyright © 2014 Elsevier Ltd. All rights reserved.

Effect of MgO on Liquidus Temperatures in the ZnO-"FeO"-Al2O3-CaO-SiO2-MgO System in Equilibrium with Metallic Iron

NASA Astrophysics Data System (ADS)

Zhao, Baojun; Hayes, Peter C.; Jak, Evgueni

2011-06-01

The phase equilibria in the ZnO-"FeO"-Al2O3-CaO-SiO2-MgO system have been determined experimentally in equilibrium with metallic iron. Synthetic slags were equilibrated at a high temperature, quenched, and then the compositions of the phases in equilibrium were measured using electron probe X-ray microanalysis. Pseudoternary sections of the form ZnO-"FeO"-(Al2O3 + CaO + SiO2) for CaO/SiO2 = 0.71, (CaO + SiO2)/Al2O3 = 5 and fixed MgO concentrations of 2, 4, and 6 wt pct have been constructed. Wustite (Fe2+,Mg,Zn)O and spinel (Fe2+,Mg,Zn)O·(Al,Fe3+)2O3 are the major primary phases in the temperature and composition ranges investigated. The liquidus temperatures are increased by 140 K in the wustite primary phase field and by 70 K in the spinel primary phase field with the addition of 6 wt pct MgO in the slag. The partitioning of MgO and ZnO between the solid and liquid phases has been discussed.

Bona-fide method for the determination of short range order and transport properties in a ferro-aluminosilicate slag

PubMed Central

Karalis, Konstantinos T.; Dellis, Dimitrios; Antipas, Georgios S. E.; Xenidis, Anthimos

2016-01-01

The thermodynamics, structural and transport properties (density, melting point, heat capacity, thermal expansion coefficient, viscosity and electrical conductivity) of a ferro-aluminosilicate slag have been studied in the solid and liquid state (1273–2273 K) using molecular dynamics. The simulations were based on a Buckingham-type potential, which was extended here, to account for the presence of Cr and Cu. The potential was optimized by fitting pair distribution function partials to values determined by Reverse Monte Carlo modelling of X-ray and neutron diffraction experiments. The resulting short range order features and ring statistics were in tight agreement with experimental data and created consensus for the accurate prediction of transport properties. Accordingly, calculations yielded rational values both for the average heat capacity, equal to 1668.58 J/(kg·K), and for the viscosity, in the range of 4.09–87.64 cP. The potential was consistent in predicting accurate values for mass density (i.e. 2961.50 kg/m3 vs. an experimental value of 2940 kg/m3) and for electrical conductivity (5.3–233 S/m within a temperature range of 1273.15–2273.15 K). PMID:27455915

Low emission U-fired boiler combustion system

DOEpatents

Ake, Terence; Beittel, Roderick; Lisauskas, Robert A.; Reicker, Eric

2000-01-01

At least one main combustion chamber contains at least one pulverized coal burner. Each pulverized coal burner is operatively arranged for minimizing NO.sub.X production and for maintaining a predetermined operating temperature to liquefy ash within the combustion chamber. The combustion chamber includes a slag drain for removing slag from the combustion chamber. A slag screen is positioned in a generally U-shaped furnace flow pattern. The slag screen is positioned between the combustion chamber and a radiant furnace. The radiant furnace includes a reburning zone for in-furnace No.sub.X reduction. The reburning zone extends between a reburning fuel injection source and at least one overfire air injection port for injecting air.

Si-based technologies for reduction of the pollutant leaching from landfills and mine tails.

PubMed

Bocharnikova, E; Matichenkov, V; Jiang, J; Yuejin, C

2017-07-01

Monosilicic and polysilicic acids were shown to react with different types of the pollutants. The direction of these reactions can be managed by changing the monosilicic and polysilicic acid concentration in soil or water media. The objective of this study was to determine the effect of Si-treated calcium metallurgical slag and battery slag on the As, Se, Cd, Pb, Ni, Cr, and Hg mobility and bioavailability in mine tailings (Xikuangshan mine, Hunan, China). The results of column experiment showed that the Si-activated slags reduced leaching of As, Se, Cd, Pb, Ni, Cr, and Hg by 13-89% and transformed them into plant-unavailable forms. The greenhouse test has demonstrated that the Si-treated slags provided reinforced plant resistance to heavy metal toxicity and reduced pollutants in barley and pea leaves. Si-treated local solid slags could be used for creating the biogeochemical barriers on the pollutant streams from landfills or mine tailings sites.

A New Technique for Preparation of High-Grade Titanium Slag from Titanomagnetite Concentrate by Reduction-Melting-Magnetic Separation Processing

NASA Astrophysics Data System (ADS)

Lv, Chao; Yang, Kun; Wen, Shu-ming; Bai, Shao-jun; Feng, Qi-cheng

2017-10-01

This paper proposes a new technique for preparation of high-grade titanium slag from Panzhihua vanadium titanomagnetite concentrate by reduction-melting-magnetic separation processing. Chemical analysis, x-ray diffraction, and scanning electron microscopy in conjunction with energy-dispersive spectroscopy were used to characterize the samples. The effective separation of iron and titanium slag could be realized by melting metallized pellets at 1550°C for 60 min with the addition of 1% CaO (basicity of 1.1) and 2% graphite powder. The small iron particles embedded in the slag could be removed by fine grinding and magnetic separation process. The grade of TiO2 in the obtained high-grade titanium slag reached 60.68% and the total recovery of TiO2 was 91.25%, which could be directly applied for producing titanium white by the sulfuric acid process. This technique provides an alternative method to use vanadium titanomagnetite concentrate of the Panzhihua area in China.

Experimental Investigation of Gas/Slag/Matte/Spinel Equilibria in the Cu-Fe-O-S-Si System at 1473 K (1200 °C) and P(SO2) = 0.25 atm

NASA Astrophysics Data System (ADS)

Hidayat, Taufiq; Fallah-Mehrjardi, Ata; Hayes, Peter C.; Jak, Evgueni

2018-04-01

New experimental data were obtained on the gas/slag/matte/spinel equilibria in the Cu-Fe-O-S-Si system at 1473 K (1200 °C) and P(SO2) = 0.25 atm covering Cu concentrations in matte between 42 and 78 wt pct Cu. Accurate measurements were obtained using high-temperature equilibration and the rapid quenching technique, followed by electron-probe X-ray microanalysis of equilibrium phase compositions. The use of spinel substrates made to support the samples ensures equilibrium with this primary phase solid, eliminates crucible contamination, and facilitates direct gas-condensed phase equilibrium and high quenching rates. Particular attention was given to the confirmation of the achievement of equilibrium. The results quantify the relationship between Cu in matte and oxygen partial pressure, sulfur in matte, oxygen in matte, Fe/SiO2 at slag liquidus, sulfur in slag, and dissolved copper in slag.

Producing fired bricks using coal slag from a gasification plant in indiana

USGS Publications Warehouse

Chen, L.-M.; Chou, I.-Ming; Chou, S.-F.J.; Stucki, J.W.

2009-01-01

Integrated gasification combined cycle (IGCC) is a promising power generation technology which increases the efficiency of coal-to-power conversion and enhances carbon dioxide concentration in exhaust emissions for better greenhouse gas capture. Two major byproducts from IGCC plants are bottom slag and sulfur. The sulfur can be processed into commercially viable products, but high value applications need to be developed for the slag material in order to improve economics of the process. The purpose of this study was to evaluate the technical feasibility of incorporating coal slag generated by the Wabash River IGCC plant in Indiana as a raw material for the production of fired bricks. Full-size bricks containing up to 20 wt% of the coal slag were successfully produced at a bench-scale facility. These bricks have color and texture similar to those of regular fired bricks and their water absorption properties met the ASTM specifications for a severe weathering grade. Other engineering properties tests, including compressive strength tests, are in progress.

Utilization of steel slag for Portland cement clinker production.

PubMed

Tsakiridis, P E; Papadimitriou, G D; Tsivilis, S; Koroneos, C

2008-04-01

The aim of the present research work is to investigate the possibility of adding steel slag, a by-product of the conversion of iron to steel process, in the raw meal for the production of Portland cement clinker. Two samples of raw meals were prepared, one with ordinary raw materials, as a reference sample ((PC)(Ref)), and another with 10.5% steel slag ((PC)(S/S)). Both raw meals were sintered at 1450 degrees C. The results of chemical and mineralogical analyses as well as the microscopic examination showed that the use of the steel slag did not affect the mineralogical characteristics of the so produced Portland cement clinker. Furthermore, both clinkers were tested by determining the grindability, setting times, compressive strengths and soundness. The hydration products were examined by XRD analysis at 2, 7, 28 and 90 days. The results of the physico-mechanical tests showed that the addition of the steel slag did not negatively affect the quality of the produced cement.

Remediation of chromium-slag leakage with electricity cogeneration via a urea-Cr(VI) cell

PubMed Central

Yu, Binbin; Zhang, Huimin; Xu, Wei; Li, Gang; Wu, Zucheng

2014-01-01

Chromium pollution has been historically widespread throughout the world. Most available remediation technologies often require energy consumption. This study is aimed to develop electrochemical remediation for Cr(VI) in chromium-slag leakage with self-generated electricity. Dynamic leaching experiments of chromium-slag samples were conducted to survey the release and leaching behavior of Cr(VI). Based on previous work, a unique urea-Cr(VI) was designed, in which urea was employed as the fuel and Cr(VI) from the leakage of the dichromate slag served as the oxidant. Furthermore, the electrochemical results showed that the removal percent of Cr(VI) was more than 96% after 18 h with the leakage Cr(VI) concentration of 2.69 mM. The open circuit potential (OCP) varied in the range of 1.56 ~ 1.59 V under different initial Cr(VI) leakage concentrations. The approach explores the feasibility of the promising technique without the need of energy input for simultaneous chromium-slag remediation and generation of electricity. PMID:25168513

Methods of Fabricating a Layer of Metallic Glass-Based Material Using Immersion and Pouring Techniques

NASA Technical Reports Server (NTRS)

Hofmann, Douglas (Inventor)

2015-01-01

Systems and methods in accordance with embodiments of the invention implement layers of metallic glass-based materials. In one embodiment, a method of fabricating a layer of metallic glass includes: applying a coating layer of liquid phase metallic glass to an object, the coating layer being applied in a sufficient quantity such that the surface tension of the liquid phase metallic glass causes the coating layer to have a smooth surface; where the metallic glass has a critical cooling rate less than 1000 K/s; and cooling the coating layer of liquid phase metallic glass to form a layer of solid phase metallic glass.

Porous materials produced from incineration ash using thermal plasma technology.

PubMed

Yang, Sheng-Fu; Chiu, Wen-Tung; Wang, To-Mai; Chen, Ching-Ting; Tzeng, Chin-Ching

2014-06-01

This study presents a novel thermal plasma melting technique for neutralizing and recycling municipal solid waste incinerator (MSWI) ash residues. MSWI ash residues were converted into water-quenched vitrified slag using plasma vitrification, which is environmentally benign. Slag is adopted as a raw material in producing porous materials for architectural and decorative applications, eliminating the problem of its disposal. Porous materials are produced using water-quenched vitrified slag with Portland cement and foaming agent. The true density, bulk density, porosity and water absorption ratio of the foamed specimens are studied here by varying the size of the slag particles, the water-to-solid ratio, and the ratio of the weights of the core materials, including the water-quenched vitrified slag and cement. The thermal conductivity and flexural strength of porous panels are also determined. The experimental results show the bulk density and the porosity of the porous materials are 0.9-1.2 g cm(-3) and 50-60%, respectively, and the pore structure has a closed form. The thermal conductivity of the porous material is 0.1946 W m(-1) K(-1). Therefore, the slag composite materials are lightweight and thermal insulators having considerable potential for building applications. Copyright © 2013 Elsevier Ltd. All rights reserved.

Construction material properties of slag from the high temperature arc gasification of municipal solid waste.

PubMed

Roessler, Justin G; Olivera, Fernando D; Wasman, Scott J; Townsend, Timothy G; McVay, Michael C; Ferraro, Christopher C; Blaisi, Nawaf I

2016-06-01

Slag from the high temperature arc gasification (HTAG) of municipal solid waste (MSW) was tested to evaluate its material properties with respect to use as a construction aggregate. These data were compared to previously compiled values for waste to energy bottom ash, the most commonly produced and beneficially used thermal treatment residue. The slag was tested using gradations representative of a base course and a course aggregate. Los Angeles (LA) abrasion testing demonstrated that the HTAG slag had a high resistance to fracture with a measured LA loss of 24%. Soundness testing indicated a low potential for reactivity and good weathering resistance with a mean soundness loss of 3.14%. The modified Proctor compaction testing found the slag to possess a maximum dry density (24.04kN/m(3)) greater than conventionally used aggregates and WTE BA. The LBR tests demonstrated a substantial bearing capacity (>200). Mineralogical analysis of the HTAG suggested the potential for self cementing character which supports the elevated LBR results. Preliminary material characterization of the HTAG slag establishes potential for beneficial use; larger and longer term studies focusing on the material's possibility for swelling and performance at the field scale level are needed. Copyright © 2016 Elsevier Ltd. All rights reserved.

Evaluation of solubility in simulated lung fluid of metals present in the slag from a metallurgical industry to produce metallic zinc.

PubMed

Lima, Rosilda M G; Carneiro, Luana G; Afonso, Júlio C; Cunha, Kenya M D

2013-01-01

The objective of this study was to determine the solubility parameters (rapid and slow dissolution rates, rapid and slow dissolution fractions) for nickel, cadmium, zinc and manganese compounds present in a pile of slag accumulated under exposure to weathering. This slag was generated by a metallurgical industry that produced zinc and zinc alloys from hemimorphite (Zn(4)(OH)(2)Si(2)O(7).H(2)O) and willemite (Zn(2)SiO(4)) minerals. A static dissolution test in vitro was used to determine the solubility parameters and Gamble's solution was used as the simulated lung fluid (SLF), on a time basis ranging from 10 min to 1 year. The metal concentrations in the slag samples and in the SLF were determined using Particle Induced X-rays Emission (PIXE). There are significant differences in terms of solubility parameters among the metals. The results indicated that the zinc, nickel, cadmium and manganese compounds present in the slag were moderately soluble in the SLF. The rapid dissolution fractions of these metals are associated with their sulfates. In conclusion, this study confirms the harmful effects on the neighboring population of the airborne particles containing these metals that came from the slag.

Environmental and Geotechnical Assessment of the Steel Slags as a Material for Road Structure

PubMed Central

Sas, Wojciech; Głuchowski, Andrzej; Radziemska, Maja; Dzięcioł, Justyna; Szymański, Alojzy

2015-01-01

Slags are the final solid wastes from the steel industry. Their production from waste and associated materials is a proper implementation of the basic objectives and principles of the waste management. This study aims to investigate the chemical and selected significant geotechnical parameters of steel slag as the alternative materials used in road construction. These investigations are strongly desired for successful application in engineering. Young’s modules E, and resilient modules Mr showed that their values corresponding with requirements for subbase (principal or auxiliary) and riding surface as well. Tested mechanical properties were conducted in soaked and un-soaked (optimal moisture content) conditions. The designated high content of chromium and zinc are strongly associated with the internal crystal structure of steel slag. The results do not lead to threats when they are applied in roads’ structures. Mechanical characterization was obtained by performing California bearing ratio (CBR) tests for steel slag in fixed compaction and moisture content conditions. Moreover, cyclic loading of steel slag was conducted with the application of cyclic California bearing ratio (cCBR) apparatus to characterization of this material as a controlled low-strength material. Finally, field studies that consist of static load plate VSS tests were presented. PMID:28793477

Advances in chemical and physical properties of electric arc furnace carbon steel slag by hot stage processing and mineral mixing.

PubMed

Liapis, Ioannis; Papayianni, Ioanna

2015-01-01

Slags are recognised as a highly efficient, cost effective tool in the metal processing industry, by minimising heat losses, reducing metal oxidation through contact with air, removing metal impurities and protecting refractories and graphite electrodes. When compared to natural aggregates for use in the construction industry, slags have higher specific weight that acts as an economic deterrent. A method of altering the specific weight of EAFC slag by hot stage processing and mineral mixing, during steel production is presented in this article. The method has minimal interference with the production process of steel, even by limited additions of appropriate minerals at high temperatures. Five minerals are examined, namely perlite, ladle furnace slag, bauxite, diatomite and olivine. Measurements of specific weight are accompanied by X-ray diffraction (XRD) and fluorescence (XRF) analysis and scanning electron microscopy spectral images. It is also shown how altering the chemical composition is expected to affect the furnace refractory lining. Additionally, the process has been repeated for the most suitable mix in gas furnace and physical properties (FI, SI, LA, PSV, AAV, volume stability) examined. Alteration of the specific weight can result in tailoring slag properties for specific applications in the construction sector. Copyright © 2014 Elsevier B.V. All rights reserved.

Benard and Marangoni convection in multiple liquid layers

NASA Technical Reports Server (NTRS)

Koster, Jean N.; Prakash, A.; Fujita, D.; Doi, T.

1992-01-01

Convective fluid dynamics of immiscible double and triple liquid layers are considered. First results on multilayer convective flow, in preparation for spaceflight experiment aboard IML-2 (International Microgravity Laboratory), are discussed. Convective flow in liquid layers with one or two horizontal interfaces with heat flow applied parallel to them is one of the systems investigated. The second system comprises two horizontally layered immiscible liquids heated from below and cooled from above, that is, heat flow orthogonal to the interface. In this system convection results due to the classical Benard instability.

Upgrading constructed wetlands phosphorus reduction from a dairy effluent using electric arc furnace steel slag filters.

PubMed

Weber, D; Drizo, A; Twohig, E; Bird, S; Ross, D

2007-01-01

In 2003, a subsurface flow constructed wetlands (SSF-CW) system was built at the University of Vermont (UVM) Paul Miller Dairy Farm as an alternative nutrient management approach for treating barnyard runoff and milk parlour waste. Given the increasing problem of phosphorus (P) pollution in the Lake Champlain region, a slag based P-removal filter technology (PFT) was established (2004) at the CW with two objectives: (i) to test the filters' efficiency as an upgrade unit for improving P removal performance via SSF-CW (ii) to investigate the capacity of filters technology to remove P as a "stand alone" unit. Six individual filters (F1-F6) were filled with electric arc furnace (EAF) steel slag, each containing 112.5 kg of material with a pore volume of 21 L. F1-F4, fed with CW treated water, received approximately 2.17 g DRP kg(-1) EAF steel slag (0.25 kg DRP total) during the 259 day feeding period. F1-F4 retained 1.7 g DRP kg(-1) EAF steel slag, resulting in an average P removal efficiency of 75%. The addition of filters improved CW DRP removal efficiency by 74%. F5 and F6, fed non-treated water, received 1.9 g DRP kg(-1) EAF steel slag (0.22 kg DRP in total) and retained 1.5 g DRP kg(-1) resulting in a P removal efficiency of 72%. The establishment of the EAF slag based PFT is the first in-field evaluation of this technology to reduce P from dairy farm effluent in Vermont.

Optimization of the thermodynamic properties and phase diagrams of P2O5-containing systems

NASA Astrophysics Data System (ADS)

Hudon, Pierre; Jung, In-Ho

2014-05-01

P2O5 is an important oxide component in the late stage products of numerous igneous rocks such as granites and pegmatites. Typically, P2O5 combines with CaO and crystallizes in the form of apatite, while in volatile-free conditions, Ca-whitlockite is formed. In spite of their interest, the thermodynamic properties and phase diagrams of P2O5-containg systems are not well known yet. In the case of the pure P2O5 for example, no experimental thermodynamic data are available for the liquid and the O and O' solid phases. As a result, we re-evaluated all the thermodynamic and phase diagram data of the P2O5 unary system [1]. Optimization of the thermodynamic properties and phase diagrams of the binary P2O5 systems was then performed including the Li2O-, Na2O-, MgO-, CaO-, BaO-, MnO-, FeO-, Fe2O3-, ZnO-, Al2O3-, and SiO2-P2O5 [2] systems. All available thermodynamic and phase equilibrium data were simultaneously reproduced in order to obtain a set of model equations for the Gibbs energies of all phases as functions of temperature and composition. In particular, the Gibbs energy of the liquid solution was described using the Modified Quasichemical Model [3-5] implemented in the FactSage software [6]. Thermodynamic modeling of the Li2O-Na2O-K2O-MgO-CaO-FeO-Fe2O3-Al2O3-SiO2 system, which include many granite-forming minerals such as nepheline, leucite, pyroxene, melilite, feldspar and spinel is currently in progress. [1] Jung, I.-H., Hudon, P. (2012) Thermodynamic assessment of P2O5. J. Am. Ceram. Soc., 95 (11), 3665-3672. [2] Rahman, M., Hudon, P. and Jung, I.-H. (2013) A coupled experimental study and thermodynamic modeling of the SiO2-P2O5 system. Metall. Mater. Trans. B, 44 (4), 837-852. [3] Pelton, A.D. and Blander, M. (1984) Computer-assisted analysis of the thermodynamic properties and phase diagrams of slags. Proc. AIME Symp. Metall. Slags Fluxes, TMS-AIME, 281-294. [4] Pelton, A.D. and Blander, M. (1986) Thermodynamic analysis of ordered liquid solutions by a modified quasichemical approach application to silicate slags. Metall. Trans. B, 17, 805-815. [5] A.D. Pelton, S.A. Decterov, G. Eriksson, C. Robelin and Y. Dessureault (2000) The modified quasichemical model - I Binary solutions. Metall. Mater. Trans. B, 31, 651-660. [6] C.W. Bale, P. Chartrand, S.A. Decterov, G. Eriksson, K. Hack, R. Ben Mahfoud, J. Melançon, A.D. Pelton and S. Petersen. (2002) FactSage Thermochemical Software and Databases. Calphad, 26, 189-228.

Application of Two-Phase CFD to the Design and Analysis of a Subscale Motor Experiment to Evaluate Propellant Slag Production

NASA Technical Reports Server (NTRS)

Whitesides, R. Harold; Dill, Richard A.

1996-01-01

The redesigned solid rocket motor (RSRM) Pressure Perturbation Investigation Team concluded that the cause of recent pressure spikes during both static and flight motor burns was the expulsion of molten aluminum oxide slag from a pool which collects in the aft end of the motor around the submerged nozzle nose during the last half of motor operation. It is suspected that some motors produce more slag than others due to differences in aluminum oxide agglomerate particle sizes which may relate to subtle differences in propellant ingredient characteristics such as particle size distribution, contaminants, or processing variations. In order to determine the effect of suspect propellant ingredient characteristics on the propensity for slag production in a real motor environment, a subscale motor experiment was designed. An existing 5 inch ballistic test motor was selected as the basic test vehicle due to low cost and quick turn around times. The standard converging/diverging nozzle was replaced with a submerged nozzle nose design to provide a positive trap for the slag which would increase both the quantity and repeatability of measured slag weights. Computational fluid dynamics (CFD) was used to assess a variety of submerged nose configurations to identify the design which possessed the best capability to reliably collect slag. CFD also was used to assure that the final selected nozzle design would result in flow field characteristics such as dividing streamline location, nose attach point, and separated flow structure which would have similtude with the RSRM submerged nozzle nose flow field. It also was decided to spin the 5 inch motor about its longitudinal axis to further enhance slag collection quantities. Again, CFD was used to select an appropriate spin rate along with other considerations, including the avoidance of burn rate enhancement from radial acceleration effects.

Erosion wear response of epoxy composites filled with steel industry slag and sludge particles: A comparative study

NASA Astrophysics Data System (ADS)

Purohit, Abhilash; Satapathy, Alok

2018-03-01

In the field of composite research, use of industrial wastes such as slag and sludge particles as filler in wear resistant polymer composites has not been very common. Owing to the very high cost of conventional filler materials in polymer composites, exploring the possibility of using low cost minerals and industrial wastes for this purpose has become the need of the hour. In this context this work explores the possibility of such polymer composites filled with low cost industrial wastes and presents a comparison of mechanical characteristics among three types of epoxy based composites filled with Linz - Donawitz sludge (LD sludge), blast furnace slag (BF slag) and Linz - Donawitz slag (LD slag) respectively. A comparative study in regard to their solid particle erosion wear characteristics under similar test conditions is also included. Composites with different weight proportions (0, 5, 10, 15 and 20 wt. %) of LD sludge are fabricated by solution casting technique. Mechanical properties such as micro- hardness, tensile strength and flexural strength of three types of composites have been evaluated as per ASTM test standards and solid particle erosion wear test is performed following a design of experiment approach based on Taguchi’s orthogonal array. Five control factors (impact velocity, erodent size, filler content, impingement angle and erodent temperature) each at five levels are considered to conduct erosion wear tests. The test results for epoxy-LD sludge composites are compared with those of epoxy-BF slag and epoxy-LD slag composites reported by previous investigators. The comparison reveals that epoxy filled with LD sludge exhibits superior mechanical and erosion wear characteristics among the three types of composites considered in this study. This work also opens up a new avenue for value added utilization of an abundant industrial waste in the making of epoxy based functional composites.

Mitigating yield-scaled greenhouse gas emissions through combined application of soil amendments: A comparative study between temperate and subtropical rice paddy soils.

PubMed

Ali, Muhammad Aslam; Kim, P J; Inubushi, K

2015-10-01

Effects of different soil amendments were investigated on methane (CH4) and nitrous oxide (N2O) emissions, global warming potential (GWP) and yield scaled GWPs in paddy soils of Republic of Korea, Japan and Bangladesh. The experimental treatments were NPK only, NPK+fly ash, NPK+silicate slag, NPK+phosphogypsum(PG), NPK+blast furnace slag (BFS), NPK+revolving furnace slag (RFS), NPK+silicate slag (50%)+RFS (50%), NPK+biochar, NPK+biochar+Azolla-cyanobacteria, NPK+silicate slag+Azolla-cyanobacteria, NPK+phosphogypsum (PG)+Azolla-cyanobacteria. The maximum decrease in cumulative seasonal CH4 emissions was recorded 29.7% and 32.6% with Azolla-cyanobacteria plus phospho-gypsum amendments in paddy soils of Japan and Bangladesh respectively, followed by 22.4% and 26.8% reduction with silicate slag plus Azolla-cyanobacteria application. Biochar amendments in paddy soils of Japan and Bangladesh decreased seasonal cumulative N2O emissions by 31.8% and 20.0% respectively, followed by 26.3% and 25.0% reduction with biochar plus Azolla-cyanobacteria amendments. Although seasonal cumulative CH4 emissions were significantly increased by 9.5-14.0% with biochar amendments, however, global warming potentials were decreased by 8.0-12.0% with cyanobacterial inoculation plus biochar amendments. The maximum decrease in GWP was calculated 22.0-30.0% with Azolla-cyanobacteria plus silicate slag amendments. The evolution of greenhouse gases per unit grain yield (yield scaled GWP) was highest in the NPK treatment, which was decreased by 43-50% from the silicate slag and phosphogypsum amendments along with Azolla-cyanobacteria inoculated rice planted soils. Conclusively, it is recommended to incorporate Azolla-cyanobacteria with inorganic and organic amendments for reducing GWP and yield scaled GWP from the rice planted paddy soils of temperate and subtropical countries. Copyright © 2015 Elsevier B.V. All rights reserved.

[A field experiment of runoff and sediment yielding processes from residues in Shenfu-Dongsheng Coalfield].

PubMed

Li, Jian-Ming; Wang, Wen-Long; Wang, Zhen; Luo, Ting; Li, Hong-Wei; Jin, Jian

2013-12-01

The processes of runoff and sediment yields from and the benefits of water and sediment reductions by the residues produced in the Shenfu-Dongsheng Coalfield were investigated by a simulated field rainfall experiment. The runoff generation time generally presented a decreasing trend with increasing rainfall intensity, but varied widely with the change of residue compositions. Runoff from the slag reached a steady velocity faster than that from the spoil, and the average velocities of runoff from the residues were gradually decreased in the spoil, the slag with more sand and less stone, and the slag with less sand and more stone. Runoff rates for the residues reached a steady rate 6 min after runoff generation, and were significantly correlated with the rainfall intensities. Erosion on the residues mainly occurred in the first 6 min after runoff generation. Average sediment concentrations in the first 6 min were 0.43-4.27 times of those thereafter for the spoil, and 1.43-54.93 times for the slag. The runoff volume was a linear function of the rainfall intensity for the spoil and the slag with more sand and less stone, and was a power function of rainfall intensity for the slag with less sand and more stone. The relationships between single erosion and rainfall intensity for the spoil and the slag with less sand and more stone can be described by exponential and power functions, respectively. For the spoil, the erosion rate was a linear function of the runoff volume. When fish-scale pits and vegetation coverage were adopted on the surface of the slag, the generation of runoff lagged 24 min behind initial rainfall applications at intensities of 1.0 and 1.5 mm x min(-1), and the runoff and sediment yields were reduced by 29.5%-52.9% and 85.7%-97.9%, respectively.

Temporal dissolution of potentially toxic elements from silver smelting slag by synthetic environmental solutions.

PubMed

Ash, Christopher; Borůvka, Luboš; Tejnecký, Václav; Šebek, Ondřej; Nikodem, Antonín; Drábek, Ondřej

2013-11-15

Waste slag which is created during precious metal smelting contains high levels of potentially toxic elements (PTE) which can be mobilised from unconfined deposits into the local environment. This paper examines the extractability of selected PTE (Pb, Zn, Cd, Mn) from slag samples by synthetic solutions designed to replicate those in the environment. Extracting agents were used to replicate potential leaching scenarios which are analogous to natural chemical weathering. Slag was submersed in a rainwater simulation solution (RSS), weak citric acid solution (representing rhizosphere secretions) and control solutions (deionised water) for a one month period with solution analyses made at intervals of 1, 24, 168 and 720 h. In 1 mM citric acid, dissolution of Cd and Zn showed little change with time, although for Zn the initial dissolution was considerable. Lead in citric acid was characterized by overall poor extractability. Mn solubility increased until an equilibrium state occurred within 24 h. The solubility of studied metals in citric acid can be characterized by a short time to equilibrium. RSS proved to be an effective solvent that, unlike citric acid solution, extracted increasing concentrations of Cd, Mn and Zn with time. Solubility of Pb in RSS was again very low. When taken as a proportion of a single 2 M HNO3 extraction which was applied to slag samples, Cd was the element most readily leached into RSS and control samples. In both studied solvents, slag heterogeneity is prominent in the case of Cd and Zn solubility. Contact time with solvent appears to be an important variable for the release of PTE from slag into solution. The purpose of this study was to provide insight into the environmental chemical dissolution of PTE from slag, which causes their enrichment in surrounding soils and surface waters. Copyright © 2013 Elsevier Ltd. All rights reserved.

Applying a uniform layer of disinfectant by wiping.

PubMed

Cooper, D W

2000-01-01

Disinfection or sterilization often requires applying a film of liquid to a surface, frequently done by using a wiper as the applicator. The wiper must not only hold a convenient amount of liquid, it must deposit it readily and uniformly. Contact time is critical to disinfection efficacy. Evaporation can limit the contact time. To lengthen the contact time, thickly applied layers are generally preferred. The thickness of such layers can be determined by using dyes or other tracers, as long as the tracers do not significantly affect the liquid's surface tension and viscosity and thus do not affect the thickness of the applied layer. Alternatively, as done here, the thickness of the layer can be inferred from the weight loss of the wiper. Results are reported of experiments on thickness of the layers applied under various conditions. Near saturation, hydrophilic polyurethane foam wipers gave layers roughly 10 microns thick, somewhat less than expected from hydrodynamic theory, but more than knitted polyester or woven cotton. Wipers with large liquid holding capacity, refilled often, should produce more nearly uniform layers. Higher pressures increase saturation in the wiper, tending to thicken the layer, but higher pressures also force liquid from the interface, tending to thin the layer, so the net result could be thicker or thinner layers, and there is likely to be an optimal pressure.

Pyrochemical recovery of plutonium from calcium fluoride reduction slag

DOEpatents

Christensen, D.C.

A pyrochemical method of recovering finely dispersed plutonium metal from calcium fluoride reduction slag is claimed. The plutonium-bearing slag is crushed and melted in the presence of at least an equimolar amount of calcium chloride and a few percent metallic calcium. The calcium chloride reduces the melting point and thereby decreases the viscosity of the molten mixture. The calcium reduces any oxidized plutonium in the mixture and also causes the dispersed plutonium metal to coalesce and settle out as a separate metallic phase at the bottom of the reaction vessel. Upon cooling the mixture to room temperature, the solid plutonium can be cleanly separated from the overlying solid slag, with an average recovery yield on the order of 96 percent.

The effect of alumina in slag on manganese and silicon distributions in silicomanganese smelting

NASA Astrophysics Data System (ADS)

Swinbourne, D. R.; Rankin, W. J.; Eric, R. H.

1995-02-01

The distribution ratios of manganese and silicon between silicomanganese alloy and slag, in equilibrium with carbon, were investigated at 1500 °C. The alumina content of the slag was varied from about 9 to 32 pct. Both distribution ratios decreased as A12O3 increased to about 20 pct and, thereafter, remained constant. The value of the “apparent equilibrium constant” displayed a maximum at about 24 pct A12O3, mainly because of the variation in the values of the activity coefficients of SiO2 and MnO. It was concluded that the slag and silicomanganese alloy in a submerged arc furnace are at, or at least close to, equilibrium.

Transient liquid phase ceramic bonding

DOEpatents

Glaeser, Andreas M.

1994-01-01

Ceramics are joined to themselves or to metals using a transient liquid phase method employing three layers, one of which is a refractory metal, ceramic or alloy. The refractory layer is placed between two metal layers, each of which has a lower melting point than the refractory layer. The three layers are pressed between the two articles to be bonded to form an assembly. The assembly is heated to a bonding temperature at which the refractory layer remains solid, but the two metal layers melt to form a liquid. The refractory layer reacts with the surrounding liquid and a single solid bonding layer is eventually formed. The layers may be designed to react completely with each other and form refractory intermetallic bonding layers. Impurities incorporated into the refractory metal may react with the metal layers to form refractory compounds. Another method for joining ceramic articles employs a ceramic interlayer sandwiched between two metal layers. In alternative embodiments, the metal layers may include sublayers. A method is also provided for joining two ceramic articles using a single interlayer. An alternate bonding method provides a refractory-metal oxide interlayer placed adjacent to a strong oxide former. Aluminum or aluminum alloys are joined together using metal interlayers.

Mineralogy and environmental geochemistry of historical iron slag, Hopewell Furnace National Historic Site, Pennsylvania, USA

USGS Publications Warehouse

Piatak, N.M.; Seal, R.R.

2012-01-01

The Hopewell Furnace National Historic Site in southeastern Pennsylvania, which features an Fe smelter that was operational in the 18th and 19th centuries, is dominated by three slag piles. Pile 1 slag, from the Hopewell Furnace, and pile 2 slag, likely from the nearby Cornwall Furnace, were both produced in cold-blast charcoal-fired smelters. In contrast, pile 3 slag was produced in an anthracite furnace. Ore samples from the nearby Jones and Hopewell mines that fed the smelter are mainly magnetite-rich with some sulfides (pyrite, chalcopyrite, sphalerite) and accessory silicates (quartz, garnet, feldspar, and clay minerals). Slag piles 1 and 2 are similar mineralogically containing predominantly skeletal and dendritic aluminian diopside and augite, skeletal forsteritic olivine, glass, rounded blebs of metallic Fe, and exotic quartz. Olivine is a major phase in all samples from pile 2, whereas it occurs in only a few samples from pile 1. Samples of the <2mm-size fraction of surface composite slag material or crushed slag from at depth in piles 1 and 2 are mineralogically similar to the large surface slag fragments from those piles with the addition of phases such as feldspars, Fe oxides, and clay minerals that are either secondary weathering products or entrained from the underlying bedrock. Pile 3 slag contains mostly skeletal forsteritic olivine and Ti-bearing aluminian diopside, dendritic or fine-grained subhedral melilite, glass, euhedral spinel, metallic Fe, alabandite-oldhamite solid solution, as well as a sparse Ti carbonitride phase. The bulk chemistry of the slag is dominated by Al 2O 3 (8.5-16.2wt.%), CaO (8.2-26.2wt.%), MgO (4.2-24.7wt.%), and SiO 2 (36.4-59.8wt.%), constituting between 81% and 97% of the mass of the samples. Piles 1 and 2 are chemically similar; pile 1 slag overall contains the highest Fe 2O 3, K 2O and MnO, and the lowest MgO concentrations. Pile 3 slag is high in Al 2O 3, CaO and S, and low in Fe 2O 3, K 2O and SiO 2 compared to the other piles. In general, piles 1 and 2 are chemically similar to each other, whereas pile 3 is distinct - a conclusion that reflects their mineralogy. The similarities and differences among piles in terms of mineralogy and major element chemistry result from the different smelting conditions under which the slag formed and include the fuel source, the composition of the ore and flux, the type of blast (cold versus hot), which affects the furnace temperature, and other beneficiation methods.The three distinct slag piles at Hopewell are enriched in numerous trace elements, such as As (up to 12. mg/kg), Cd (up to 0.4. mg/kg), Co (up to 31.8. mg/kg), Cu (up to 647. mg/kg), Mn (up to 0.69. wt.%), Pb (up to 172. mg/kg) and Zn (up to 393. mg/kg), together with Fe (13.9. wt.%), when compared to the average for the continental crust, with the <2. mm-size fraction commonly containing the highest concentrations. Enrichments in various elements (e.g., Cd, Co, Cu, Pb, Zn) were also found in the ore samples. Despite these enrichments, comparison of bulk chemistry trace-element concentrations to the environmental guidelines suggests most elements are likely not problematic with the exception of As, Co, Fe and Mn. Leachate tests that simulate weathering indicate Fe (up to 973??g/L) and Mn (up to 133??g/L) are readily released in potentially harmful concentrations compared to secondary drinking water and some aquatic ecosystem toxicity criteria. Aluminum and Cu, although not high in the solid compared to environmental guidelines, also exceed relevant criteria in leachate extracts with maximum concentrations of 2700??g/L and 17.7??g/L, respectively. In contrast, As and Co, which are significant in the solids, are not leached in concentrations that exceed guidelines (i.e., 3??g/L or less for both elements). The weathering rates of the Fe metal and Fe oxides, which host Cu and some Fe, are likely higher than the silicate glass, which hosts the majority of Al, Mn and so

Gravitational instability of thin gas layer between two thick liquid layers

NASA Astrophysics Data System (ADS)

Pimenova, A. V.; Goldobin, D. S.

2016-12-01

We consider the problem of gravitational instability (Rayleigh-Taylor instability) of a horizontal thin gas layer between two liquid half-spaces (or thick layers), where the light liquid overlies the heavy one. This study is motivated by the phenomenon of boiling at the surface of direct contact between two immiscible liquids, where the rate of the "break-away" of the vapor layer growing at the contact interface due to development of the Rayleigh-Taylor instability on the upper liquid-gas interface is of interest. The problem is solved analytically under the assumptions of inviscid liquids and viscous weightless vapor. These assumptions correspond well to the processes in real systems, e.g., they are relevant for the case of interfacial boiling in the system water- n-heptane. In order to verify the results, the limiting cases of infinitely thin and infinitely thick gas layers were considered, for which the results can be obviously deduced from the classical problem of the Rayleigh-Taylor instability. These limiting cases are completely identical to the well-studied cases of gravity waves at the liquidliquid and liquid-gas interfaces. When the horizontal extent of the system is long enough, the wavenumber of perturbations is not limited from below, and the system is always unstable. The wavelength of the most dangerous perturbations and the rate of their exponential growth are derived as a function of the layer thickness. The dependence of the exponential growth rate on the gas layer thickness is cubic.

Mineralogy and the release of trace elements from slag from the Hegeler Zinc smelter, Illinois (USA)

USGS Publications Warehouse

Piatak, Nadine M.; Seal, Robert R.

2010-01-01

Slag from the former Hegeler Zn-smelting facility in Illinois (USA) is mainly composed of spinifex Ca-rich plagioclase, fine-grained dendritic or coarse-grained subhedral to anhedral clinopyroxenes, euhedral to subhedral spinels, spherical blebs of Fe sulfides, silicate glass, and less commonly fayalitic olivine. Mullite and quartz were also identified in one sample as representing remnants of the furnace lining. Secondary phases such as goethite, hematite and gypsum are significant in some samples and reflect surficial weathering of the dump piles or represent byproducts of roasting. A relatively rare Zn-rich material contains anhedral willemite, subhedral gahnite, massive zincite, hardystonite and a Zn sulfate (brianyoungite), among other phases, and likely represents the molten content of the smelting furnace before Zn extraction. The bulk major-element chemistry of most slag samples is dominated by SiO2, Al2O3, Fe2O3 and CaO. The bulk composition of the slag suggests a high viscosity of the melt and the mineralogy suggests a high silica content of the melt. Bulk slag trace-element chemistry shows that the dominant metal is Zn with >28.4 wt.% in the Zn-rich material and between 212 and 14,900 mg/kg in the other slags. The concentrations of other trace elements reach the following: 45 mg/kg As, 1170 mg/kg Ba, 191 mg/kg Cd, 242 mg/kg Co, 103 mg/kg Cr, 6360 mg/kg Cu, 107 mg/kg Ni, and 711 mg/kg Pb.Zinc, as the dominant metal in the slags, is likely the most environmentally significant metal in these samples; Cd, Cu, and Pb are also of concern and their concentrations exceed US Environmental Protection Agency preliminary remediation goals for residential soils. Spinel was found to be the dominant concentrator of Zn for samples containing significant Zn (>1 wt.%); the silicate glass also contained relatively high concentrations of Zn compared to other phases. Zinc partitioned into the silicates and oxides in these samples is generally more resistant to weathering and therefore less leached when compared to the slag samples with lower bulk Zn concentrations where Zn is likely partitioned into volumetrically minor sulfides. This is confirmed by leachate tests that resulted in low leachate Zn concentrations for samples with Zn partitioned into spinel. In contrast, the concentrations of Zn and SO4 are close to those expected from the dissolution of stoichiometric ZnS in leachates from samples in which the dominant host of Zn is suspected to be sulfides. The fact that Zn and other metals occur commonly as sulfides, which are more reactive than the silicates and oxides into which they dominantly partition according to other slag studies, indicates the Hegeler slag pile may be more of an environmental concern than other slag piles.

Method and apparatus for processing algae

DOEpatents

Chew, Geoffrey; Reich, Alton J.; Dykes, Jr., H. Waite; Di Salvo, Roberto

2012-07-03

Methods and apparatus for processing algae are described in which a hydrophilic ionic liquid is used to lyse algae cells. The lysate separates into at least two layers including a lipid-containing hydrophobic layer and an ionic liquid-containing hydrophilic layer. A salt or salt solution may be used to remove water from the ionic liquid-containing layer before the ionic liquid is reused. The used salt may also be dried and/or concentrated and reused. The method can operate at relatively low lysis, processing, and recycling temperatures, which minimizes the environmental impact of algae processing while providing reusable biofuels and other useful products.

Growth and Cd uptake by rice (Oryza sativa) in acidic and Cd-contaminated paddy soils amended with steel slag.

PubMed

He, Huaidong; Tam, Nora F Y; Yao, Aijun; Qiu, Rongliang; Li, Wai Chin; Ye, Zhihong

2017-12-01

Contamination of rice (Oryza sativa) by Cd is of great concern. Steel slag could be used to amend Cd-contaminated soils and make them safe for cereal production. This work was conducted to study the effects of steel slag on Cd uptake and growth of rice plants in acidic and Cd-contaminated paddy soils and to determine the possible mechanisms behind these effects. Pot (rhizobag) experiments were conducted using rice plants grown on two acidic and Cd-contaminated paddy soils with or without steel slag amendment. Steel slag amendment significantly increased grain yield by 36-45% and root catalase activity, and decreased Cd concentrations in brown rice by 66-77% compared with the control, in both soils. Steel slag amendment also markedly decreased extractable soil Cd, Cd concentrations in pore-water and Cd translocation from roots to above-ground parts. It also significantly increased soil pH, extractable Si and Ca in soils and Ca concentrations in roots. Significant positive correlations were found between extractable soil Cd and Cd concentrations in rice tissues, but it was negatively correlated with soil pH and extractable Si. Calcium in root tissues significantly and negatively correlated with Cd translocation factors from roots to straw. Overall, steel slag amendment not only significantly promoted rice growth but decreased Cd accumulation in brown rice. These benefits appear to be related to improvements in soil conditions (e.g. increasing pH, extractable Si and Ca), a reduction in extractable soil Cd, and suppression of Cd translocation from roots to above-ground parts. Copyright © 2017 Elsevier Ltd. All rights reserved.

Slow angled-descent forepaw grasping (SLAG): an innate behavioral task for identification of individual experimental mice possessing functional vision.

PubMed

Gil-Pagés, Macarena; Stiles, Robert J; Parks, Christopher A; Neier, Steven C; Radulovic, Maja; Oliveros, Alfredo; Ferrer, Alejandro; Reed, Brendan K; Wilton, Katelynn M; Schrum, Adam G

2013-08-23

There is significant interest in the generation of improved assays to clearly identify experimental mice possessing functional vision, a property that could qualify mice for inclusion in behavioral and neuroscience studies. Widely employed current methods rely on mouse responses to visual cues in assays of reflexes, depth perception, or cognitive memory. However, commonly assessed mouse reflexes can sometimes be ambiguous in their expression, while depth perception assays are sometimes confounded by variation in anxiety responses and exploratory conduct. Furthermore, in situations where experimental groups vary in their cognitive memory capacity, memory assays may not be ideal for assessing differences in vision. We have optimized a non-invasive behavioral assay that relies on an untrained, innate response to identify individual experimental mice possessing functional vision: slow angled-descent forepaw grasping (SLAG). First, we verified that SLAG performance depends on vision and not olfaction. Next, all members of an age-ranged cohort of 158 C57BL/6 mice (57 wild-type, 101 knockout, age range 44-241 days) were assessed for functional vision using the SLAG test without training or conditioning. Subjecting the population to a second innate behavioral test, Dark Chamber preference, corroborated that the functional vision assessment of SLAG was valid. We propose that the SLAG assay is immediately useful to quickly and clearly identify experimental mice possessing functional vision. SLAG is based on a behavioral readout with a significant innate component with no requirement for training. This will facilitate the selection of mice of known sighted status in vision-dependent experiments that focus on other types of behavior, neuroscience, and/or cognitive memory.

Slow angled-descent forepaw grasping (SLAG): an innate behavioral task for identification of individual experimental mice possessing functional vision

PubMed Central

2013-01-01

Background There is significant interest in the generation of improved assays to clearly identify experimental mice possessing functional vision, a property that could qualify mice for inclusion in behavioral and neuroscience studies. Widely employed current methods rely on mouse responses to visual cues in assays of reflexes, depth perception, or cognitive memory. However, commonly assessed mouse reflexes can sometimes be ambiguous in their expression, while depth perception assays are sometimes confounded by variation in anxiety responses and exploratory conduct. Furthermore, in situations where experimental groups vary in their cognitive memory capacity, memory assays may not be ideal for assessing differences in vision. Results We have optimized a non-invasive behavioral assay that relies on an untrained, innate response to identify individual experimental mice possessing functional vision: slow angled-descent forepaw grasping (SLAG). First, we verified that SLAG performance depends on vision and not olfaction. Next, all members of an age-ranged cohort of 158 C57BL/6 mice (57 wild-type, 101 knockout, age range 44–241 days) were assessed for functional vision using the SLAG test without training or conditioning. Subjecting the population to a second innate behavioral test, Dark Chamber preference, corroborated that the functional vision assessment of SLAG was valid. Conclusions We propose that the SLAG assay is immediately useful to quickly and clearly identify experimental mice possessing functional vision. SLAG is based on a behavioral readout with a significant innate component with no requirement for training. This will facilitate the selection of mice of known sighted status in vision-dependent experiments that focus on other types of behavior, neuroscience, and/or cognitive memory. PMID:23971729

A Navy User’s Guide for Quality Assurance of New Concrete Construction

DTIC Science & Technology

2012-06-01

types and blends of cements, fly ash, silica fume, and blast furnace slag . During construction, concrete samples are taken to test and document the...chemical compositions provided by specific types and blends of cements, fly ash, silica fume, and blast furnace slag when used with specific aggregates...of portland cement and blast furnace slag . Before the 11 owner accepts the completed structure, all cracks transverse to the steel rebar in excess

New design incinerator being built

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1980-09-01

A $14 million garbage-burning facility is being built by Reedy Creek Utilities Co. in cooperation with DOE at Lake Buena Vista, Fla., on the edge of Walt Disney World. The nation's first large-volume slagging pyrolysis incinerator will burn municipal waste in a more beneficial way and supply 15% of the amusement park's energy demands. By studying the new incinerators slag-producing capabilities, engineers hope to design similar facilities for isolating low-level nuclear wastes in inert, rocklike slag.

The Use Of Phosphates To Reduce Slag Penetration In Cr203-Based Refractories

DOEpatents

Kwong, Kyei-Sing; Dogan, Cynthia P.; Bennett, James P.; Chinn, Richard E.; Petty, Arthur V.

2004-11-09

A high-chromium refractory material that provides improved resistance to coal slag penetration is presented. The refractory mixture comprises a blend of chromium oxide, aluminum oxide and phosphates. The refractory mixture may be blended with an aggregate and cured. In addition a phosphorous oxide may be blended with chromium oxide and aluminum oxide and additionally an aggregate. The refractory mixture reduces the rate of coal slag penetration into the surface of the cured refractory.

Titanium: Industrial Base, Price Trends, and Technology Initiatives

DTIC Science & Technology

2009-01-01

respectively.3 All titanium metal production begins with rutile (titanium oxide, or TiO2). High-titania slag , produced by ilmen- ite smelting, is the first...Ilmenite ores are used in iron production. They leave a TiO2-rich slag , which is usually upgraded to be used in titanium production. 4 According to the...and least expensive process for producing titanium sponge, has four major steps. First, rutile con- centrate or synthetic rutile (titanium slag ) is

Use of 87Sr/86Sr and δ11B to Identify Slag-Affected Sediment in Southern Lake Michigan

USGS Publications Warehouse

Bayless, E. Randall; Bullen, Thomas D.; Fitzpatrick, John A.

2004-01-01

Slag is a ubiquitous byproduct of the iron-smelting industry and influences geochemistry and water quality in adjacent geologic units, ground and surface water. Despite extensive slag deposition along the Indiana shoreline of Lake Michigan, definitive evidence that slag has affected lakebed sediments has not been established. Concerns for the protection of water and ecosystem resources in the Great Lakes motivated this study to determine if strontium and boron isotopes could be used to identify and delineate slag-affected bed sediment in Lake Michigan. Sixty-five samples of bed sediment were acquired from the southern lobe of Lake Michigan and analyzed for 87Sr/86Sr and ??11B. Samples immediately offshore from Indiana steel mills and slag-disposal sites contained higher median 87Sr/86Sr values (0.70881) than shoreline sediments collected elsewhere in the basin (0.70847) and uniquely decreased with increasing distance from the shoreline. The highest ??11B values occurred in sediments from the Indiana shoreline (+12.9 to 16.4???) but were also elevated in sediments collected offshore from three Lake Michigan cities (+11.7 to 12.7???). Contoured isotope data indicated that 82-154 km2 of bed sediment along the Indiana shoreline had elevated 87Sr/86Sr and ??11B values relative to shoreline sediments elsewhere in southern Lake Michigan.

Mechanism of Phase Formation in the Batch Mixtures for Slag-Bearing Glass Ceramics - 12207

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stefanovsky, Sergey V.; Stefanovsky, Olga I.; Malinina, Galina A.

2012-07-01

Slag surrogate was produced from chemicals by heating to 900 deg. C and keeping at this temperature for 1 hr. The product obtained was intermixed with either sodium di-silicate (75 wt.% waste loading) or borax (85 wt.% slag loading). The mixtures were heat-treated within a temperature range of 25 to 1300 deg. C. The products were examined by X-ray diffraction and infrared spectroscopy. The products prepared at temperatures of up to 1000 deg. C contained both phase typical of the source slag and intermediate phases as well as phases typical of the materials melted at 1350 deg. C such asmore » nepheline, britholite, magnetite and matrix vitreous phase. Vitrification process in batch mixtures consisting of slag surrogate and either sodium di-silicate or sodium tetraborate runs through formation of intermediate phases mainly silico-phosphates capable to incorporate Sm as trivalent actinides surrogate. Reactions in the batch mixtures are in the whole completed by ∼1000 deg. C but higher temperatures are required to homogenize the products. If in the borate-based system the mechanism is close to simple dissolution of slag constituents in the low viscous borate melt, then in the silicate-based system the mechanism was found to be much complicated and includes re-crystallization during melting with segregation of newly-formed nepheline type phase. (authors)« less

Steel slag: a waste industrial by-product as an alternative sustainable green building material in construction applications--an attempt for solid waste management.

PubMed

Pofale, Arun D; Nadeem, Mohammed

2012-01-01

This investigation explores the possibility of utilizing granular slag as an alternative to fine aggregate (natural sand) in construction applications like masonry and plastering. Construction industry utilizes large volume of fine aggregate in all the applications which has resulted into shortage of good quality naturally available fine aggregate. Use of granular slag serves two fold purposes, i.e. waste utilisation as well as alternative eco-friendly green building material for construction. The investigation highlights comparative study of properties with partial and full replacement of fine aggregate (natural sand) by granular slag in cement mortar applications (masonry and plastering). For this purpose, cement mortar mix proportions from 1:3, 1:4, 1:5 & 1:6 by volume were selected for 0, 25, 50, 75 & 100% replacement levels with w/c ratios of 0.60, 0.65, 0.70 & 0.72 respectively. Based on the study results, it could be inferred that replacement of natural sand with granular slag from 25 to 75% increased the packing density of mortar which resulted into reduced w/c ratio, increased strength properties of all mortar mixes. Hence, it could be recommended that the granular slag could be effectively utilized as fine aggregate in masonry and plastering applications in place of conventional cement mortar mixes using natural sand.

Integration of coal gasification and waste heat recovery from high temperature steel slags: an emerging strategy to emission reduction

NASA Astrophysics Data System (ADS)

Sun, Yongqi; Sridhar, Seetharaman; Liu, Lili; Wang, Xidong; Zhang, Zuotai

2015-11-01

With the continuous urbanization and industrialization in the world, energy saving and greenhouse gas (GHG) emission reduction have been serious issues to be addressed, for which heat recovery from traditional energy-intensive industries makes up a significant strategy. Here we report a novel approach to extract the waste heat and iron from high temperature steel slags (1450-1650 oC) produced in the steel industry, i.e., integration of coal gasification and steel slag treatment. Both the thermodynamics and kinetics of the pertinent reactions were identified. It was clarified that the kinetic mechanism for gasification varied from A2 model to A4 model (Avrami-Erofeev) in the presence of slags. Most importantly, the steel slags acted not only as good heat carriers but also as effective catalysts where the apparent activation energy for char gasification got remarkably reduced from 95.7 kJ/mol to 12.1 kJ/mol (A2 model). Furthermore, the FeO in the slags was found to be oxidized into Fe3O4, with an extra energy release, which offered a potential for magnetic separation. Moreover, based on the present research results, an emerging concept, composed of multiple industrial sectors, was proposed, which could serve as an important route to deal with the severe environmental problems in modern society.

Integration of coal gasification and waste heat recovery from high temperature steel slags: an emerging strategy to emission reduction

PubMed Central

Sun, Yongqi; Sridhar, Seetharaman; Liu, Lili; Wang, Xidong; Zhang, Zuotai

2015-01-01

With the continuous urbanization and industrialization in the world, energy saving and greenhouse gas (GHG) emission reduction have been serious issues to be addressed, for which heat recovery from traditional energy-intensive industries makes up a significant strategy. Here we report a novel approach to extract the waste heat and iron from high temperature steel slags (1450–1650 oC) produced in the steel industry, i.e., integration of coal gasification and steel slag treatment. Both the thermodynamics and kinetics of the pertinent reactions were identified. It was clarified that the kinetic mechanism for gasification varied from A2 model to A4 model (Avrami-Erofeev) in the presence of slags. Most importantly, the steel slags acted not only as good heat carriers but also as effective catalysts where the apparent activation energy for char gasification got remarkably reduced from 95.7 kJ/mol to 12.1 kJ/mol (A2 model). Furthermore, the FeO in the slags was found to be oxidized into Fe3O4, with an extra energy release, which offered a potential for magnetic separation. Moreover, based on the present research results, an emerging concept, composed of multiple industrial sectors, was proposed, which could serve as an important route to deal with the severe environmental problems in modern society. PMID:26558350

Pre-fired, refractory block slag dams for wet bottom furnace floors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vihnicka, R.S.; Meskimen, R.L.

1998-12-31

Slagging (wet bottom), utility boilers count on a refractory coating over the furnace floor tube structure for protection from corrosion damage from both the harsh, hot gas atmosphere from the burning fuel and the acidic coal slag. To protect and extend the life of this protective refractory coating the boiler original equipment manufacturers (OEMs) utilized a water-cooled monkey ring or slag chill ring (typically a 6--8 inch high ring of small diameter tubes) surrounding the slag tap locations on most wet bottom furnace floors (both utility and package boilers). The old water-cooled tube ring was such a high maintenance item,more » however, that it`s use has been discontinued in all but the most extreme environments throughout both utility and industrial applications. Where the use of the ring was discontinued, there has been a corresponding shortening of life on the protective floor refractory coatings (high maintenance cost), further aggravated by recent OSHA restrictions limiting the use of chrome oxide refractory materials in these types of boilers. This paper describes the developmental process and the final resultant product (a non-watercooled, slag dam made from pre-fired refractory shapes), undertaken by the inventors. Derived operational benefits a concept 2 project, with NO{sub x} Title 4 and Title 1 significance (which is currently underway) will also be detailed.« less

Alkali activated slag mortars provide high resistance to chloride-induced corrosion of steel

NASA Astrophysics Data System (ADS)

Criado, Maria; Provis, John L.

2018-06-01

The pore solutions of alkali-activated slag cements and Portland-based cements are very different in terms of their chemical and redox characteristics, particularly due to the high alkalinity and high sulfide content of alkali-activated slag cement. Therefore, differences in corrosion mechanisms of steel elements embedded in these cements could be expected, with important implications for the durability of reinforced concrete elements. This study assesses the corrosion behaviour of steel embedded in alkali-activated blast furnace slag (BFS) mortars exposed to alkaline solution, alkaline chloride-rich solution, water, and standard laboratory conditions, using electrochemical techniques. White Portland cement (WPC) mortars and blended cement mortars (white Portland cement and blast furnace slag) were also tested for comparative purposes. The steel elements embedded in immersed alkali-activated slag mortars presented very negative redox potentials and high apparent corrosion current values; the presence of sulfide reduced the redox potential, and the oxidation of the reduced sulfur-containing species within the cement itself gave an electrochemical signal that classical electrochemical tests for reinforced concrete durability would interpret as being due to steel corrosion processes. However, the actual observed resistance to chloride-induced corrosion was very high, as measured by extraction and characterisation of the steel at the end of a 9-month exposure period, whereas the steel embedded in white Portland cement mortars was significantly damaged under the same conditions.

Integration of coal gasification and waste heat recovery from high temperature steel slags: an emerging strategy to emission reduction.

PubMed

Sun, Yongqi; Sridhar, Seetharaman; Liu, Lili; Wang, Xidong; Zhang, Zuotai

2015-11-12

With the continuous urbanization and industrialization in the world, energy saving and greenhouse gas (GHG) emission reduction have been serious issues to be addressed, for which heat recovery from traditional energy-intensive industries makes up a significant strategy. Here we report a novel approach to extract the waste heat and iron from high temperature steel slags (1450-1650 (o)C) produced in the steel industry, i.e., integration of coal gasification and steel slag treatment. Both the thermodynamics and kinetics of the pertinent reactions were identified. It was clarified that the kinetic mechanism for gasification varied from A2 model to A4 model (Avrami-Erofeev) in the presence of slags. Most importantly, the steel slags acted not only as good heat carriers but also as effective catalysts where the apparent activation energy for char gasification got remarkably reduced from 95.7 kJ/mol to 12.1 kJ/mol (A2 model). Furthermore, the FeO in the slags was found to be oxidized into Fe3O4, with an extra energy release, which offered a potential for magnetic separation. Moreover, based on the present research results, an emerging concept, composed of multiple industrial sectors, was proposed, which could serve as an important route to deal with the severe environmental problems in modern society.

Refractory Wear Mechanisms in the Nonferrous Metal Industry: Testing and Modeling Results

NASA Astrophysics Data System (ADS)

Gregurek, D.; Ressler, A.; Reiter, V.; Franzkowiak, A.; Spanring, A.; Prietl, T.

2013-11-01

Nonferrous pyrometallurgical processes today operate at a high intensity requiring the best standards for the furnace refractory systems. From one plant to another, there is a range of process conditions such as temperature, slag chemistry, and feed types, and each of these parameters can influence refractory life. It is generally understood that process changes at plants can impact refractory life. The ability to test and understand refractory responses to a wide range of furnace operating conditions is therefore important. The RHI Technology Centre in Leoben, Austria is well equipped with laboratory and pilot plant facilities to evaluate refractory suitability over the range of conditions encountered in modern nonferrous pyrometallurgical systems. This article describes refractory testing at the RHI Technology Centre of the impact of two metallurgical slags on a number of different RHI test bricks. The slags were a fayalite slag and a calcium ferrite slag supplied by two smelter plants. High-temperature corrosion tests were carried out in a 250-mm-diameter induction furnace and a 165-mm-diameter short rotary kiln; each unit was lined with a number of refractory bricks and tested against attack by the particular slag. After testing, the refractory bricks were subjected to several laboratory tests to determine the extent of corrosion. Optimal refractory choices for the customers' plants were developed based on the test results.

Versatile alignment layer method for new types of liquid crystal photonic devices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Finnemeyer, V.; Bryant, D.; Lu, L.

2015-07-21

Liquid crystal photonic devices are becoming increasingly popular. These devices often present a challenge when it comes to creating a robust alignment layer in pre-assembled cells. In this paper, we describe a method of infusing a dye into a microcavity to produce an effective photo-definable alignment layer. However, previous research on such alignment layers has shown that they have limited stability, particularly against subsequent light exposure. As such, we further describe a method of utilizing a pre-polymer, infused into the microcavity along with the liquid crystal, to provide photostability. We demonstrate that the polymer layer, formed under ultraviolet irradiation ofmore » liquid crystal cells, has been effectively localized to a thin region near the substrate surface and provides a significant improvement in the photostability of the liquid crystal alignment. This versatile alignment layer method, capable of being utilized in devices from the described microcavities to displays, offers significant promise for new photonics applications.« less