Advanced Electrical Materials and Components Being Developed

NASA Technical Reports Server (NTRS)

Schwarze, Gene E.

2004-01-01

All aerospace systems require power management and distribution (PMAD) between the energy and power source and the loads. The PMAD subsystem can be broadly described as the conditioning and control of unregulated power from the energy source and its transmission to a power bus for distribution to the intended loads. All power and control circuits for PMAD require electrical components for switching, energy storage, voltage-to-current transformation, filtering, regulation, protection, and isolation. Advanced electrical materials and component development technology is a key technology to increasing the power density, efficiency, reliability, and operating temperature of the PMAD. The primary means to develop advanced electrical components is to develop new and/or significantly improved electronic materials for capacitors, magnetic components, and semiconductor switches and diodes. The next important step is to develop the processing techniques to fabricate electrical and electronic components that exceed the specifications of presently available state-of-the-art components. The NASA Glenn Research Center's advanced electrical materials and component development technology task is focused on the following three areas: 1) New and/or improved dielectric materials for the development of power capacitors with increased capacitance volumetric efficiency, energy density, and operating temperature; 2) New and/or improved high-frequency, high-temperature soft magnetic materials for the development of transformers and inductors with increased power density, energy density, electrical efficiency, and operating temperature; 3) Packaged high-temperature, high-power density, high-voltage, and low-loss SiC diodes and switches.

Mathematical Storage-Battery Models

NASA Technical Reports Server (NTRS)

Chapman, C. P.; Aston, M.

1985-01-01

Empirical formula represents performance of electrical storage batteries. Formula covers many battery types and includes numerous coefficients adjusted to fit peculiarities of each type. Battery and load parameters taken into account include power density in battery, discharge time, and electrolyte temperature. Applications include electric-vehicle "fuel" gages and powerline load leveling.

Hydrogen loading system development and evaluation of tritiated substrates to optimize performance in tritium based betavoltaics

NASA Astrophysics Data System (ADS)

Adams, Thomas E.

State-of-the-art hydrogen loading system onto thin metallic films based on differential pressure in calibrated chambers has been developed for conditions pressures and temperatures up to 69 bar and 500°C, respectively. Experiments on hydrogen loading on to palladium films of thickness 50 and 250 nm were conducted at pressure ranging from 0.2 bar to 10 bar at temperature 310°C. For first time film hydrogen loading was carried out at 1 bar and at room temperature which temperature. Beta flux exiting surface of metal tritide films has been modeled with MC-SET (Monte Carlo Simulation of Electron Trajectories in solids). Surface beta flux simulations have been improved to account for density changes from tritium loading and decay. Simulation results indicate a 300 nm slab of MgT2 has a surface flux three times higher than in ScT2, and six times higher than in TiT2. Commercial betavoltaic cells were tested at different temperature environment for their evaluation and characterization.

Peg supported thermal insulation panel

DOEpatents

Nowobilski, Jeffert J.; Owens, William J.

1985-01-01

A thermal insulation panel which is lightweight, load bearing, accommodates thermal stress, and has excellent high temperature insulation capability comprising high performance insulation between thin metal walls supported by high density, high strength glass pegs made in compliance with specified conditions of time, temperature and pressure.

The impact of different stator and rotor slot number combinations on iron losses of a three-phase induction motor at no-load

NASA Astrophysics Data System (ADS)

Marčič, T.; Štumberger, B.; Štumberger, G.; Hadžiselimović, M.; Zagradišnik, I.

The electromechanical characteristics of induction motors depend on the used stator and rotor slot combination. The correlation between the usage of different stator and rotor slot number combinations, magnetic flux density distributions, no-load iron losses and rated load winding over-temperatures for a specific induction motor is presented. The motor's magnetic field was analyzed by traces of the magnetic flux density vector, obtained by FEM. Post-processing of FE magnetic field solution was used for posterior iron loss calculation of the motor iron loss at no-load. The examined motor stator lamination had 36 semi-closed slots and the rotor laminations had 28, 33, 34, 44 and 46 semi-closed slots.

Research on particulate filter simulation and regeneration control strategy

NASA Astrophysics Data System (ADS)

Dawei, Qu; Jun, Li; Yu, Liu

2017-03-01

This paper reports a DPF (Diesel Particulate Filter) collection mathematical model for a new regeneration control strategy. The new strategy is composed by main parts, such as regeneration time capturing, temperature rising strategy and regeneration control strategy. In the part of regeneration time capturing, a multi-level regeneration capturing method is put forward based on the combined effect of the PM (Particulate Matter) loading, pressure drop and fuel consumption. The temperature rising strategy proposes the global temperature for all operating conditions. The regeneration control process considers the particle loading density, temperature and oxygen respectively. Based on the analysis of the initial overheating, runaway temperature and local hot spot, the final control strategy is established.

Peg supported thermal insulation panel

DOEpatents

Nowobilski, J.J.; Owens, W.J.

1985-04-30

A thermal insulation panel which is lightweight, load bearing, accommodates thermal stress, and has excellent high temperature insulation capability comprises high performance insulation between thin metal walls supported by high density, high strength glass pegs made in compliance with specified conditions of time, temperature and pressure. 2 figs.

Thermal management of batteries

NASA Astrophysics Data System (ADS)

Gibbard, H. F.; Chen, C.-C.

Control of the internal temperature during high rate discharge or charge can be a major design problem for large, high energy density battery systems. A systematic approach to the thermal management of such systems is described for different load profiles based on: thermodynamic calculations of internal heat generation; calorimetric measurements of heat flux; analytical and finite difference calculations of the internal temperature distribution; appropriate system designs for heat removal and temperature control. Examples are presented of thermal studies on large lead-acid batteries for electrical utility load levelling and nickel-zinc and lithium-iron sulphide batteries for electric vehicle propulsion.

Effective Thermal Conductivity of Graphite Materials with Cracks

NASA Astrophysics Data System (ADS)

Pestchaanyi, S. E.; Landman, I. S.

The dependence of effective thermal diffusivity on temperature caused by volumetric cracks is modelled for macroscopic graphite samples using the three-dimensional thermomechanics code Pegasus-3D. At high off-normal heat loads typical of the divertor armour, thermostress due to the anisotropy of graphite grains is much larger than that due to the temperature gradient. Numerical simulation demonstrated that the volumetric crack density both in fine grain graphites and in the CFC matrix depends mainly on the local sample temperature, not on the temperature gradient. This allows to define an effective thermal diffusivity for graphite with cracks. The results obtained are used to explain intense cracking and particle release from carbon based materials under electron beam heat load. Decrease of graphite thermal diffusivity with increase of the crack density explains particle release mechanism in the experiments with CFC where a clear energy threshold for the onset of particle release has been observed in J. Linke et al. Fusion Eng. Design, in press, Bazyler et al., these proceedings. Surface temperature measurement is necessary to calibrate the Pegasus-3D code for simulation of ITER divertor armour brittle destruction.

Experimental study of ELM-like heat loading on beryllium under ITER operational conditions

NASA Astrophysics Data System (ADS)

Spilker, B.; Linke, J.; Pintsuk, G.; Wirtz, M.

2016-02-01

The experimental fusion reactor ITER, currently under construction in Cadarache, France, is transferring the nuclear fusion research to the power plant scale. ITER’s first wall (FW), armoured by beryllium, is subjected to high steady state and transient power loads. Transient events like edge localized modes not only deposit power densities of up to 1.0 GW m-2 for 0.2-0.5 ms in the divertor of the machine, but also affect the FW to a considerable extent. Therefore, a detailed study was performed, in which transient power loads with absorbed power densities of up to 1.0 GW m-2 were applied by the electron beam facility JUDITH 1 on beryllium specimens at base temperatures of up to 300 °C. The induced damage was evaluated by means of scanning electron microscopy and laser profilometry. As a result, the observed damage was highly dependent on the base temperatures and absorbed power densities. In addition, five different classes of damage, ranging from ‘no damage’ to ‘crack network plus melting’, were defined and used to locate the damage, cracking, and melting thresholds within the tested parameter space.

Experimental investigations on thermo mechanical behaviour of aluminium alloys subjected to tensile loading and laser irradiation

NASA Astrophysics Data System (ADS)

Jelani, Mohsan; Li, Zewen; Shen, Zhonghua; Sardar, Maryam; Tabassum, Aasma

2017-05-01

The present work reports the investigation of the thermal and mechanical behaviour of aluminium alloys under the combined action of tensile loading and laser irradiations. The two types of aluminium alloys (Al-1060 and Al-6061) are used for the experiments. The continuous wave Ytterbium fibre laser (wavelength 1080 nm) was employed as irradiation source, while tensile loading was provided by tensile testing machine. The effects of various pre-loading and laser power densities on the failure time, temperature distribution and on deformation behaviour of aluminium alloys are analysed. The experimental results represents the significant reduction in failure time and temperature for higher laser powers and for high load values, which implies that preloading may contribute a significant role in the failure of the material at elevated temperature. The reason and characterization of material failure by tensile and laser loading are explored in detail. A comparative behaviour of under tested materials is also investigated. This work suggests that, studies considering only combined loading are not enough to fully understand the mechanical behaviour of under tested materials. For complete characterization, one must consider the effect of heating as well as loading rate.

Prediction of thermal cycling induced matrix cracking

NASA Technical Reports Server (NTRS)

Mcmanus, Hugh L.

1992-01-01

Thermal fatigue has been observed to cause matrix cracking in laminated composite materials. A method is presented to predict transverse matrix cracks in composite laminates subjected to cyclic thermal load. Shear lag stress approximations and a simple energy-based fracture criteria are used to predict crack densities as a function of temperature. Prediction of crack densities as a function of thermal cycling is accomplished by assuming that fatigue degrades the material's inherent resistance to cracking. The method is implemented as a computer program. A simple experiment provides data on progressive cracking of a laminate with decreasing temperature. Existing data on thermal fatigue is also used. Correlations of the analytical predictions to the data are very good. A parametric study using the analytical method is presented which provides insight into material behavior under cyclical thermal loads.

Scaling of X pinches from 1 MA to 6 MA.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bland, Simon Nicholas; McBride, Ryan D.; Wenger, David Franklin

This final report for Project 117863 summarizes progress made toward understanding how X-pinch load designs scale to high currents. The X-pinch load geometry was conceived in 1982 as a method to study the formation and properties of bright x-ray spots in z-pinch plasmas. X-pinch plasmas driven by 0.2 MA currents were found to have source sizes of 1 micron, temperatures >1 keV, lifetimes of 10-100 ps, and densities >0.1 times solid density. These conditions are believed to result from the direct magnetic compression of matter. Physical models that capture the behavior of 0.2 MA X pinches predict more extreme parametersmore » at currents >1 MA. This project developed load designs for up to 6 MA on the SATURN facility and attempted to measure the resulting plasma parameters. Source sizes of 5-8 microns were observed in some cases along with evidence for high temperatures (several keV) and short time durations (<500 ps).« less

High density dispersion fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hofman, G.L.

1996-09-01

A fuel development campaign that results in an aluminum plate-type fuel of unlimited LEU burnup capability with an uranium loading of 9 grams per cm{sup 3} of meat should be considered an unqualified success. The current worldwide approved and accepted highest loading is 4.8 g cm{sup {minus}3} with U{sub 3}Si{sub 2} as fuel. High-density uranium compounds offer no real density advantage over U{sub 3}Si{sub 2} and have less desirable fabrication and performance characteristics as well. Of the higher-density compounds, U{sub 3}Si has approximately a 30% higher uranium density but the density of the U{sub 6}X compounds would yield the factormore » 1.5 needed to achieve 9 g cm{sup {minus}3} uranium loading. Unfortunately, irradiation tests proved these peritectic compounds have poor swelling behavior. It is for this reason that the authors are turning to uranium alloys. The reason pure uranium was not seriously considered as a dispersion fuel is mainly due to its high rate of growth and swelling at low temperatures. This problem was solved at least for relatively low burnup application in non-dispersion fuel elements with small additions of Si, Fe, and Al. This so called adjusted uranium has nearly the same density as pure {alpha}-uranium and it seems prudent to reconsider this alloy as a dispersant. Further modifications of uranium metal to achieve higher burnup swelling stability involve stabilization of the cubic {gamma} phase at low temperatures where normally {alpha} phase exists. Several low neutron capture cross section elements such as Zr, Nb, Ti and Mo accomplish this in various degrees. The challenge is to produce a suitable form of fuel powder and develop a plate fabrication procedure, as well as obtain high burnup capability through irradiation testing.« less

Use of Pd-Pt loaded graphene aerogel on nickel foam in direct ethanol fuel cell

NASA Astrophysics Data System (ADS)

Tsang, Chi Him A.; Leung, D. Y. C.

2018-01-01

A size customized binder-free bimetallic Pd-Pt loaded graphene aerogel deposited on nickel foam plate (Pd-Pt/GA/NFP) was prepared and used as an electrode for an alkaline direct ethanol fuel cell (DEFC) under room temperature. The effect of fuel concentration and metal composition on the output power density of the DEFC was systematically investigated. Under the optimum fuel concentration, the cell could achieve a value of 3.6 mW cm-2 at room temperature for the graphene electrode with Pd/Pt ratio approaching 1:1. Such results demonstrated the possibility of producing a size customized metal loaded GA/NFP electrode for fuel cell with high performance.

Effects of Loading Frequency on Fatigue Behavior, Residual Stress, and Microstructure of Deep-Rolled Stainless Steel AISI 304 at Elevated Temperatures

NASA Astrophysics Data System (ADS)

Nikitin, I.; Juijerm, P.

2018-02-01

The effects of loading frequency on the fatigue behavior of non-deep-rolled (NDR) and deep-rolled (DR) austenitic stainless steel AISI 304 were systematically clarified at elevated temperatures, especially at temperatures exhibiting the dynamic strain aging (DSA) phenomena. Tension-compression fatigue tests were performed isothermally at temperatures of 573 K and 773 K (300 °C and 500 °C) with different loading frequencies of 5, 0.5, 0.05, and 0.005 Hz. For the DR condition, the residual stresses and work-hardening states will be presented. It was found that DSA would be detected at appropriate temperatures and deformation rates. The cyclic deformation curves and the fatigue lives of the investigated austenitic stainless steel AISI 304 are considerably affected by the DSA, especially on the DR condition having high dislocation densities at the surface and in near-surface regions. In the temperature range of the DSA, residual stresses and work-hardening states of the DR condition seem to be stabilized. The microstructural alterations were investigated by transmission electron microscopy (TEM). At an appropriate temperature with low loading frequency, the plastic deformation mechanism shifted from a wavy slip manner to a planar slip manner in the DSA regimes, whereas the dislocation movements were obstructed.

NiF2 Cathodes For Rechargeable Na Batteries

NASA Technical Reports Server (NTRS)

Bugga, Ratnakumar V.; Distefano, Salvador; Halpert, Gerald

1992-01-01

Use of NiF2 cathodes in medium-to-high-temperature rechargeable sodium batteries increases energy and power densities by 25 to 30 percent without detracting from potential advantage of safety this type of sodium battery offers over sodium batteries having sulfur cathodes. High-energy-density sodium batteries with metal fluoride cathodes used in electric vehicles and for leveling loads on powerlines.

Investigation of Tokamak Solid Divertor Target Options.

DTIC Science & Technology

1981-05-26

but materials are not known which could operate at the high resulting wall temperatures . Mist- steam flows would also demand a relatively high ...flux P = coolant density = bulk coolant viscosity w = coolant viscosity at average wall temperature = units conversion At high heat loads and moderate...therefore, the inner wall temperature will be over 300 OF, posing a high temp- erature materials challenge. E. Swirl and Mixed Flow Schemes Extensive work

Enhanced performance of a novel anodic PdAu/VGCNF catalyst for electro-oxidation in a glycerol fuel cell.

PubMed

Yahya, N; Kamarudin, S K; Karim, N A; Masdar, M S; Loh, K S

2017-11-25

This study presents a novel anodic PdAu/VGCNF catalyst for electro-oxidation in a glycerol fuel cell. The reaction conditions are critical issues affecting the glycerol electro-oxidation performance. This study presents the effects of catalyst loading, temperature, and electrolyte concentration. The glycerol oxidation performance of the PdAu/VGCNF catalyst on the anode side is tested via cyclic voltammetry with a 3 mm 2 active area. The morphology and physical properties of the catalyst are examined using X-ray diffraction (XRD), field emission scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) spectroscopy. Then, optimization is carried out using the response surface method with central composite experimental design. The current density is experimentally obtained as a response variable from a set of experimental laboratory tests. The catalyst loading, temperature, and NaOH concentration are taken as independent parameters, which were evaluated previously in the screening experiments. The highest current density of 158.34 mAcm -2 is obtained under the optimal conditions of 3.0 M NaOH concentration, 60 °C temperature and 12 wt.% catalyst loading. These results prove that PdAu-VGCNF is a potential anodic catalyst for glycerol fuel cells.

Experimental investigation on temperature distribution of foamed concrete filled steel tube column under standard fire

NASA Astrophysics Data System (ADS)

Kado, B.; Mohammad, S.; Lee, Y. H.; Shek, P. N.; Kadir, M. A. A.

2018-04-01

Standard fire test was carried out on 3 hollow steel tube and 6 foamed concrete filled steel tube columns. Temperature distribution on the columns was investigated. 1500 kg/m3 and 1800 kg/m3 foamed concrete density at 15%, 20% and 25% load level are the parameters considered. The columns investigated were 2400 mm long, 139.7 mm outer diameter and 6 mm steel tube thickness. The result shows that foamed concrete filled steel tube columns has the highest fire resistance of 43 minutes at 15% load level and low critical temperature of 671 ºC at 25% load level using 1500 kg/m3 foamed concrete density. Fire resistance of foamed concrete filled column increases with lower foamed concrete strength. Foamed concrete can be used to provide more fire resistance to hollow steel column or to replace normal weight concrete in concrete filled columns. Since filling hollow steel with foamed concrete produce column with high fire resistance than unfilled hollow steel column. Therefore normal weight concrete can be substituted with foamed concrete in concrete filled column, it will reduces the self-weight of the structure because of its light weight at the same time providing the desired fire resistance.

The 77 K operation of a multi-resonant power converter

NASA Technical Reports Server (NTRS)

Ray, Biswajit; Gerber, Scott S.; Patterson, Richard L.; Myers, Ira T.

1995-01-01

The liquid-nitrogen temperature (77 K) operation of a 55 W, 200 kHz, 48/28 V zero-voltage switching multi-resonant dc/dc converter designed with commercially available components is reported. Upon dipping the complete converter (power and control circuits) into liquid-nitrogen, the converter performance improved as compared to the room-temperature operation. The switching frequency, resonant frequency, and the characteristic impedance did not change significantly. Accordingly, the zero-voltage switching was maintained from no-load to full-load for the specified line variations. Cryoelectronics can provide high density power converters, especially for high power applications.

Solid Polymer Electrolyte (SPE) fuel cell technology program

NASA Technical Reports Server (NTRS)

1978-01-01

Many previously demonstrated improved fuel cell features were consolidated to (1) obtain a better understanding of the observed characteristics of the operating laboratory-sized cells; (2) evaluate appropriate improved fuel cell features in 0.7 sq ft cell hardware; and (3) study the resultant fuel cell capability and determine its impact on various potential fuel cell space missions. The observed performance characteristics of the fuel cell at high temperatures and high current densities were matched with a theoretical model based on the change in Gibbs free energy voltage with respect to temperature and internal resistance change with current density. Excellent agreement between the observed and model performance was obtained. The observed performance decay with operational time on cells with very low noble metal loadings (0.05 mg/sq cm) were shown to be related to loss in surface area. Cells with the baseline amount of noble catalyst electrode loading demonstrated over 40,000 hours of stable performance.

Experimental parametric study of servers cooling management in data centers buildings

NASA Astrophysics Data System (ADS)

Nada, S. A.; Elfeky, K. E.; Attia, Ali M. A.; Alshaer, W. G.

2017-06-01

A parametric study of air flow and cooling management of data centers servers is experimentally conducted for different design conditions. A physical scale model of data center accommodating one rack of four servers was designed and constructed for testing purposes. Front and rear rack and server's temperatures distributions and supply/return heat indices (SHI/RHI) are used to evaluate data center thermal performance. Experiments were conducted to parametrically study the effects of perforated tiles opening ratio, servers power load variation and rack power density. The results showed that (1) perforated tile of 25% opening ratio provides the best results among the other opening ratios, (2) optimum benefit of cold air in servers cooling is obtained at uniformly power loading of servers (3) increasing power density decrease air re-circulation but increase air bypass and servers temperature. The present results are compared with previous experimental and CFD results and fair agreement was found.

Erosion dynamics of tungsten fuzz during ELM-like heat loading

NASA Astrophysics Data System (ADS)

Sinclair, G.; Tripathi, J. K.; Hassanein, A.

2018-04-01

Transient heat loading and high-flux particle loading on plasma facing components in fusion reactors can lead to surface melting and possible erosion. Helium-induced fuzz formation is expected to exacerbate thermal excursions, due to a significant drop in thermal conductivity. The effect of heating in edge-localized modes (ELMs) on the degradation and erosion of a tungsten (W) fuzz surface was examined experimentally in the Ultra High Flux Irradiation-II facility at the Center for Materials Under Extreme Environment. W foils were first exposed to low-energy He+ ion irradiation at a fluence of 2.6 × 1024 ions m-2 and a steady-state temperature of 1223 K. Then, samples were exposed to 1000 pulses of ELM-like heat loading, at power densities between 0.38 and 1.51 GW m-2 and at a steady-state temperature of 1223 K. Comprehensive erosion analysis measured clear material loss of the fuzz nanostructure above 0.76 GW m-2 due to melting and splashing of the exposed surface. Imaging of the surface via scanning electron microscopy revealed that sufficient heating at 0.76 GW m-2 and above caused fibers to form tendrils to conglomerate and form droplets. Repetitive thermal loading on molten surfaces then led to eventual splashing. In situ erosion measurements taken using a witness plate and a quartz crystal microbalance showed an exponential increase in mass loss with energy density. Compositional analysis of the witness plates revealed an increase in the W 4f signal with increasing energy density above 0.76 GW m-2. The reduced thermal stability of the fuzz nanostructure puts current erosion predictions into question and strengthens the importance of mitigation techniques.

Measurement of He neutral temperature in detached plasmas using laser absorption spectroscopy

NASA Astrophysics Data System (ADS)

Aramaki, M.; Tsujihara, T.; Kajita, S.; Tanaka, H.; Ohno, N.

2018-01-01

The reduction of the heat load onto plasma-facing components by plasma detachment is an inevitable scheme in future nuclear fusion reactors. Since the control of the plasma and neutral temperatures is a key issue to the detached plasma generation, we have developed a laser absorption spectroscopy system for the metastable helium temperature measurements and used together with a previously developed laser Thomson scattering system for the electron temperature and density measurements. The thermal relaxation process between the neutral and the electron in the detached plasma generated in the linear plasma device, NAGDIS-II was studied. It is shown that the electron temperature gets close to the neutral temperature by increasing the electron density. On the other hand, the pressure dependence of electron and neutral temperatures shows the cooling effect by the neutrals. The possibility of the plasma fluctuation measurement using the fluctuation in the absorption signal is also shown.

Effect of epoxidised soybean oil loading as plasticiser on physical, mechanical and thermal properties of polyvinylchloride

NASA Astrophysics Data System (ADS)

Rahmah, M.; Nurazzi, N. Mohd; Farah Nordyana, A. R.; Syed Anas, S. M.

2017-07-01

The aim of this paper is to study the effect of epoxidised soybean oil (ESO) as an alternative plasticizer on physical, mechanical and thermal properties of plasticised polyvinyl chloride (PPVC). Samples were prepared using 10, 20, 30 and 40% by weight percent of ESO. The samples were characterized for density, water absorption, tensile, hardness and thermal properties. The addition of ESO as plasticizer in PVC had caused significant effect on the physical and mechanical properties of PPVC. Increasing of ESO loading had resulted in decreased density, tensile strength, tensile modulus but increased in elongation at break and shore hardness. From water absorption study, it was observed that the all the samples reached the plateau absorption at days 8 to 10 with absorption percentages of between 1.8 to 2%. In general the crystallinity of PPVC maintained between 10 to 13% with increase in ESO loading while the melting point ( Tm) is slightly decreased about 3 to 6°C. In this study, ESO which acts as plasticiser were found to result in lower glass transition temperature (Tg). The enhancements of super cooling with higher ESO loading were found to increase the crystallization temperature, promoting crystallisation and act as nucleating agent.

Hydrogen Permeability of Polymer Matrix Composites at Cryogenic Temperatures

NASA Technical Reports Server (NTRS)

Grenoble, Ray W.; Gates, Thomas S

2005-01-01

This paper presents experimental methods and results of an ongoing study of the correlation between damage state and hydrogen gas permeability of laminated composite materials under mechanical strains and thermal loads. A specimen made from IM-7/977-2 composite material has been mechanically cycled at room temperature to induce microcrack damage. Crack density and tensile modulus were observed as functions of number of cycles. Damage development was found to occur most quickly in the off-axis plies near the outside of the laminate. Permeability measurements were made after 170,000 cycles and 430,000 cycles. Leak rate was found to depend on applied mechanical strain, crack density, and test temperature.

Optimizing Injection Molding Parameters of Different Halloysites Type-Reinforced Thermoplastic Polyurethane Nanocomposites via Taguchi Complemented with ANOVA

PubMed Central

Gaaz, Tayser Sumer; Sulong, Abu Bakar; Kadhum, Abdul Amir H.; Nassir, Mohamed H.; Al-Amiery, Ahmed A.

2016-01-01

Halloysite nanotubes-thermoplastic polyurethane (HNTs-TPU) nanocomposites are attractive products due to increasing demands for specialized materials. This study attempts to optimize the parameters for injection just before marketing. The study shows the importance of the preparation of the samples and how well these parameters play their roles in the injection. The control parameters for injection are carefully determined to examine the mechanical properties and the density of the HNTs-TPU nanocomposites. Three types of modified HNTs were used as untreated HNTs (uHNTs), sulfuric acid treated (aHNTs) and a combined treatment of polyvinyl alcohol (PVA)-sodium dodecyl sulfate (SDS)-malonic acid (MA) (treatment (mHNTs)). It was found that mHNTs have the most influential effect of producing HNTs-TPU nanocomposites with the best qualities. One possible reason for this extraordinary result is the effect of SDS as a disperser and MA as a crosslinker between HNTs and PVA. For the highest tensile strength, the control parameters are demonstrated at 150 °C (injection temperature), 8 bar (injection pressure), 30 °C (mold temperature), 8 min (injection time), 2 wt % (HNTs loading) and mHNT (HNTs type). Meanwhile, the optimized combination of the levels for all six control parameters that provide the highest Young’s modulus and highest density was found to be 150 °C (injection temperature), 8 bar (injection pressure), 32 °C (mold temperature), 8 min (injection time), 3 wt % (HNTs loading) and mHNT (HNTs type). For the best tensile strain, the six control parameters are found to be 160 °C (injection temperature), 8 bar (injection pressure), 32 °C (mold temperature), 8 min (injection time), 2 wt % (HNTs loading) and mHNT (HNTs type). For the highest hardness, the best parameters are 140 °C (injection temperature), 6 bar (injection pressure), 30 °C (mold temperature), 8 min (injection time), 2 wt % (HNTs loading) and mHNT (HNTs type). The analyses are carried out by coordinating Taguchi and ANOVA approaches. Seemingly, mHNTs has shown its very important role in the resulting product. PMID:28774069

Optimizing Injection Molding Parameters of Different Halloysites Type-Reinforced Thermoplastic Polyurethane Nanocomposites via Taguchi Complemented with ANOVA.

PubMed

Gaaz, Tayser Sumer; Sulong, Abu Bakar; Kadhum, Abdul Amir H; Nassir, Mohamed H; Al-Amiery, Ahmed A

2016-11-22

Halloysite nanotubes-thermoplastic polyurethane (HNTs-TPU) nanocomposites are attractive products due to increasing demands for specialized materials. This study attempts to optimize the parameters for injection just before marketing. The study shows the importance of the preparation of the samples and how well these parameters play their roles in the injection. The control parameters for injection are carefully determined to examine the mechanical properties and the density of the HNTs-TPU nanocomposites. Three types of modified HNTs were used as untreated HNTs ( u HNTs), sulfuric acid treated ( a HNTs) and a combined treatment of polyvinyl alcohol (PVA)-sodium dodecyl sulfate (SDS)-malonic acid (MA) (treatment ( m HNTs)). It was found that m HNTs have the most influential effect of producing HNTs-TPU nanocomposites with the best qualities. One possible reason for this extraordinary result is the effect of SDS as a disperser and MA as a crosslinker between HNTs and PVA. For the highest tensile strength, the control parameters are demonstrated at 150 °C (injection temperature), 8 bar (injection pressure), 30 °C (mold temperature), 8 min (injection time), 2 wt % (HNTs loading) and m HNT (HNTs type). Meanwhile, the optimized combination of the levels for all six control parameters that provide the highest Young's modulus and highest density was found to be 150 °C (injection temperature), 8 bar (injection pressure), 32 °C (mold temperature), 8 min (injection time), 3 wt % (HNTs loading) and m HNT (HNTs type). For the best tensile strain, the six control parameters are found to be 160 °C (injection temperature), 8 bar (injection pressure), 32 °C (mold temperature), 8 min (injection time), 2 wt % (HNTs loading) and m HNT (HNTs type). For the highest hardness, the best parameters are 140 °C (injection temperature), 6 bar (injection pressure), 30 °C (mold temperature), 8 min (injection time), 2 wt % (HNTs loading) and m HNT (HNTs type). The analyses are carried out by coordinating Taguchi and ANOVA approaches. Seemingly, m HNTs has shown its very important role in the resulting product.

Thermo-mechanical characterization of silicone foams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rangaswamy, Partha; Smith, Nickolaus A.; Cady, Carl M.

Cellular solids such as elastomeric foams are used in many structural applications to absorb and dissipate energy, due to their light weight (low density) and high energy absorption capability. In this paper we will discuss foams derived from S5370, a silicone foam formulation developed by Dow Corning. In the application presented, the foam is consolidated into a cushion component of constant thickness but variable density. A mechanical material model developed by Lewis (2013), predicts material response, in part, as a function of relative density. To determine the required parameters for this model we have obtained the mechanical response in compressionmore » for ambient, cold and hot temperatures. The variable density cushion provided samples sufficient samples so that the effect of sample initial density on the mechanical response could be studied. The mechanical response data showed extreme sensitivity to relative density. We also observed at strains corresponding to 1 MPa a linear relationship between strain and initial density for all temperatures. Samples taken from parts with a history of thermal cycling demonstrated a stiffening response that was a function of temperature, with the trend of more stiffness as temperature increased above ambient. This observation is in agreement with the entropic effects on the thermo-mechanical behavior of silicone polymers. In this study, we present the experimental methods necessary for the development of a material model, the testing protocol, analysis of test data, and a discussion of load (stress) and gap (strain) as a function of sample initial densities and temperatures« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lu, Wei-Yang

Foam materials are used to protect sensitive components from impact loading. In order to predict and simulate the foam performance under various loading conditions, a validated foam model is needed and the mechanical properties of foams need to be characterized. Uniaxial compression and tension tests were conducted for different densities of foams under various temperatures and loading rates. Crush stress, tensile strength, and elastic modulus were obtained. A newly developed confined compression experiment provided data for investigating the foam flow direction. A biaxial tension experiment was also developed to explore the damage surface of a rigid polyurethane foam.

Low platinum loading for high temperature proton exchange membrane fuel cell developed by ultrasonic spray coating technique

NASA Astrophysics Data System (ADS)

Su, Huaneng; Jao, Ting-Chu; Barron, Olivia; Pollet, Bruno G.; Pasupathi, Sivakumar

2014-12-01

This paper reports use of an ultrasonic-spray for producing low Pt loadings membrane electrode assemblies (MEAs) with the catalyst coated substrate (CCS) fabrication technique. The main MEA sub-components (catalyst, membrane and gas diffusion layer (GDL)) are supplied from commercial manufacturers. In this study, high temperature (HT) MEAs with phosphoric acid (PA)-doped poly(2,5-benzimidazole) (AB-PBI) membrane are fabricated and tested under 160 °C, hydrogen and air feed 100 and 250 cc min-1 and ambient pressure conditions. Four different Pt loadings (from 0.138 to 1.208 mg cm-2) are investigated in this study. The experiment data are determined by in-situ electrochemical methods such as polarization curve, electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). The high Pt loading MEA exhibits higher performance at high voltage operating conditions but lower performances at peak power due to the poor mass transfer. The Pt loading 0.350 mg cm-2 GDE performs the peak power density and peak cathode mass power to 0.339 W cm-2 and 0.967 W mgPt-1, respectively. This work presents impressive cathode mass power and high fuel cell performance for high temperature proton exchange membrane fuel cells (HT-PEMFCs) with low Pt loadings.

Electromigration analysis of solder joints under ac load: A mean time to failure model

NASA Astrophysics Data System (ADS)

Yao, Wei; Basaran, Cemal

2012-03-01

In this study, alternating current (ac) electromigration (EM) degradation simulations were carried out for Sn95.5%Ag4.0%Cu0.5 (SAC405- by weight) solder joints. Mass transport analysis was conducted with viscoplastic material properties for quantifying damage mechanism in solder joints. Square, sine, and triangle current wave forms ac were used as input signals. dc and pulsed dc (PDC) electromigration analysis were conducted for comparison purposes. The maximum current density ranged from 2.2×106A/cm2 to 5.0×106A/cm2, frequency ranged from 0.05 Hz to 5 Hz with ambient temperature varying from 350 K to 450 K. Because the room temperature is nearly two-thirds of SAC solder joint's melting point on absolute temperature scale (494.15 K), viscoplastic material model is essential. Entropy based damage evolution model was used to investigate mean time to failure (MTF) behavior of solder joints subjected to ac stressing. It was observed that MTF was inversely proportional to ambient temperature T1.1 in Celsius and also inversely proportional to current density j0.27 in A/cm2. Higher frequency will lead to a shorter lifetime with in the frequency range we studied, and a relationship is proposed as MTF∝f-0.41. Lifetime of a solder joint subjected to ac is longer compared with dc and PDC loading conditions. By introducing frequency, ambient temperature and current density dependency terms, a modified MTTF equation was proposed for solder joints subjected to ac current stressing.

Experimental study of current loss and plasma formation in the Z machine post-hole convolute

NASA Astrophysics Data System (ADS)

Gomez, M. R.; Gilgenbach, R. M.; Cuneo, M. E.; Jennings, C. A.; McBride, R. D.; Waisman, E. M.; Hutsel, B. T.; Stygar, W. A.; Rose, D. V.; Maron, Y.

2017-01-01

The Z pulsed-power generator at Sandia National Laboratories drives high energy density physics experiments with load currents of up to 26 MA. Z utilizes a double post-hole convolute to combine the current from four parallel magnetically insulated transmission lines into a single transmission line just upstream of the load. Current loss is observed in most experiments and is traditionally attributed to inefficient convolute performance. The apparent loss current varies substantially for z-pinch loads with different inductance histories; however, a similar convolute impedance history is observed for all load types. This paper details direct spectroscopic measurements of plasma density, temperature, and apparent and actual plasma closure velocities within the convolute. Spectral measurements indicate a correlation between impedance collapse and plasma formation in the convolute. Absorption features in the spectra show the convolute plasma consists primarily of hydrogen, which likely forms from desorbed electrode contaminant species such as H2O , H2 , and hydrocarbons. Plasma densities increase from 1 ×1016 cm-3 (level of detectability) just before peak current to over 1 ×1017 cm-3 at stagnation (tens of ns later). The density seems to be highest near the cathode surface, with an apparent cathode to anode plasma velocity in the range of 35 - 50 cm /μ s . Similar plasma conditions and convolute impedance histories are observed in experiments with high and low losses, suggesting that losses are driven largely by load dynamics, which determine the voltage on the convolute.

OH radical kinetics in hydrogen-air mixtures at the conditions of strong vibrational nonequilibrium

NASA Astrophysics Data System (ADS)

Winters, Caroline; Hung, Yi-Chen; Jans, Elijah; Eckert, Zak; Frederickson, Kraig; Adamovich, Igor V.; Popov, Nikolay

2017-12-01

This work presents results of time-resolved, absolute measurements of OH number density, nitrogen vibrational temperature, and translational-rotational temperature in air and lean hydrogen-air mixtures excited by a diffuse filament nanosecond pulse discharge, at a pressure of 100 Torr and high specific energy loading. The main objective of these measurements is to study kinetics of OH radicals at the conditions of strong vibrational excitation of nitrogen, below autoignition temperature. N2 vibrational temperature and gas temperature in the discharge and the afterglow are measured by ns broadband coherent anti-Stokes Raman scattering. Hydroxyl radical number density is measured by laser induced fluorescence, calibrated by Rayleigh scattering. The results show that the discharge generates strong vibrational nonequilibrium in air and H2-air mixtures for delay times after the discharge pulse of up to ~1 ms, with a peak vibrational temperature of T v  ≈  1900 K at T  ≈  500 K. Nitrogen vibrational temperature peaks at 100-200 µs after the discharge pulse, before decreasing due to vibrational-translational relaxation by O atoms (on the time scale of several hundred µs) and diffusion (on ms time scale). OH number density increases gradually after the discharge pulse, peaking at t ~ 100-300 µs and decaying on a longer time scale, until t ~ 1 ms. Both OH rise time and decay time decrease as H2 fraction in the mixture is increased from 1% to 5%. Comparison of the experimental data with kinetic modeling predictions shows that OH kinetics is controlled primarily by reactions of H2 and O2 with O and H atoms generated during the discharge. At the present conditions, OH number density is not affected by N2 vibrational excitation directly, i.e. via vibrational energy transfer to HO2. The effect of a reaction between vibrationally excited H2 and O atoms on OH kinetics is also shown to be insignificant. As the discharge pulse coupled energy is increased, the model predicts transient OH number density overshoot due to the temperature rise caused by N2 vibrational relaxation by O atoms, which may well be a dominant effect in discharges with specific energy loading.

Polarization characteristics of a low catalyst loading PEM water electrolyzer operating at elevated temperature

NASA Astrophysics Data System (ADS)

Lee, Byung-Seok; Park, Hee-Young; Choi, Insoo; Cho, Min Kyung; Kim, Hyoung-Juhn; Yoo, Sung Jong; Henkensmeier, Dirk; Kim, Jin Young; Nam, Suk Woo; Park, Sehkyu; Lee, Kwan-Young; Jang, Jong Hyun

2016-03-01

The effect of temperature and pressure, and diffusion layer thickness is assessed on performance of a proton exchange membrane water electrolyzers (PEMWEs) with an ultralow iridium oxide (IrO2) loading (0.1 mg cm-2) anode prepared by electrodeposition and a Pt/C catalyzed cathode with a Pt loading of 0.4 mg cm-2. Increasing pressure to 2.5 bar at 120 °C enhances the water electrolysis current, so the anode electrodeposited with 0.1 mg cm-2 IrO2 gives a current density of 1.79 A cm-2 at 1.6 V, which is comparable to the conventional powder-type IrO2 electrode with 2.0 mg cm-2 at a temperature of 120 °C and pressure of 2.5 bar. The major factors for cell performances are rationalized in terms of overpotentials, water flow rates and thickness of diffusion layers, based on polarization behavior and ac-impedance response.

Power Generation from a Radiative Thermal Source Using a Large-Area Infrared Rectenna

NASA Astrophysics Data System (ADS)

Shank, Joshua; Kadlec, Emil A.; Jarecki, Robert L.; Starbuck, Andrew; Howell, Stephen; Peters, David W.; Davids, Paul S.

2018-05-01

Electrical power generation from a moderate-temperature thermal source by means of direct conversion of infrared radiation is important and highly desirable for energy harvesting from waste heat and micropower applications. Here, we demonstrate direct rectified power generation from an unbiased large-area nanoantenna-coupled tunnel diode rectifier called a rectenna. Using a vacuum radiometric measurement technique with irradiation from a temperature-stabilized thermal source, a generated power density of 8 nW /cm2 is observed at a source temperature of 450 °C for the unbiased rectenna across an optimized load resistance. The optimized load resistance for the peak power generation for each temperature coincides with the tunnel diode resistance at zero bias and corresponds to the impedance matching condition for a rectifying antenna. Current-voltage measurements of a thermally illuminated large-area rectenna show current zero crossing shifts into the second quadrant indicating rectification. Photon-assisted tunneling in the unbiased rectenna is modeled as the mechanism for the large short-circuit photocurrents observed where the photon energy serves as an effective bias across the tunnel junction. The measured current and voltage across the load resistor as a function of the thermal source temperature represents direct current electrical power generation.

Qualification testing of secondary sterilizable silver-zinc cells for use in the Jupiter atmospheric entry probe

NASA Technical Reports Server (NTRS)

Manzo, M. A.

1981-01-01

A series of qualification tests were run on the secondary, sterilizable silver oxide - zinc cell developed at the NASA Lewis Research Center to determine if the cell was capable of providing mission power requirements for the Jupiter atmospheric entry probe. The cells were tested for their ability to survive radiation at the levels predicted for the Jovian atmosphere with no loss of performance. Cell performance was evaluated under various temperature and loading conditions, and the cells were tested under various environmental conditions related to launch and to deceleration into the Jovian atmosphere. The cell performed acceptably except under the required loading at low temperatures. The cell was redesigned to improve low-temperature performance and energy density. The modified cells improved performance at all temperatures. Results of testing cells of both the original and modified designs are discussed.

METHOD AND APPARATUS FOR EARTH PENETRATION

DOEpatents

Adams, W.M.

1963-12-24

A nuclear reactor apparatus for penetrating into the earth's crust is described. The apparatus comprises a cylindrical nuclear core operating at a temperature that is higher than the melting temperature of rock. A high-density ballast member is coupled to the nuclear core such that the overall density of the core-ballast assembly is greater than the density of molten rock. The nuclear core is thermally insulated so that its heat output is constrained to flow axially, with radial heat flow being minimized. In operation, the apparatus is placed in contact with the earth's crust at the point desired to be penetrated. The heat output of the reactor melts the underlying rock, and the apparatus sinks through the resulting magma. The fuel loading of the reactor core determines the ultimate depth of crust penetration. (AEC)

Oil-Free Rotor Support Technologies for an Optimized Helicopter Propulsion System

NASA Technical Reports Server (NTRS)

DellaCorte, Christopher; Bruckner, Robert J.

2007-01-01

An optimized rotorcraft propulsion system incorporating a foil air bearing supported Oil-Free engine coupled to a high power density gearbox using high viscosity gear oil is explored. Foil air bearings have adequate load capacity and temperature capability for the highspeed gas generator shaft of a rotorcraft engine. Managing the axial loads of the power turbine shaft (low speed spool) will likely require thrust load support from the gearbox through a suitable coupling or other design. Employing specially formulated, high viscosity gear oil for the transmission can yield significant improvements (approx. 2X) in allowable gear loading. Though a completely new propulsion system design is needed to implement such a system, improved performance is possible.

A Double Layer Model of the Electromagnetic and Thermal Processes in Induction Heating of Ferromagnetic Material

NASA Astrophysics Data System (ADS)

Gilev, B.; Kraev, G.; Venkov, G. I.

2007-10-01

This paper presents the modeling of electromagnetic and heating processes in an inductor, where cylindrical ferromagnetic material has been placed. In the first part the electromagnetic mathematical problem is solved, as a result the power density is obtained. The power density takes part in the heat conduction equation. In the second part the thermal mathematical problem is solved, as a result the alteration of the temperature of the ferromagnetic material during the heating process is obtained. The parameters in both mathematical problems depend on the temperature. Because of that the stitching method is used for their finding. In [3, 4] the same mathematical problems are solved by the finite elements method. Comparing our results to those from [3] shows that they are similar. In contrast to [3, 4] our method allows the continuation of the analysis with the finding of the load power during the heating process. Thus result permits the determination of the load power alteration in the supplying inverter [1]. It is well-known that during the induction hardening it is necessary to maintain constant current amplitude in the load circuit of the inverter. So the next aim of this research is to build up a controller, based on the developed model, which will procure the necessary mode.

Rate constants for chemical reactions in high-temperature nonequilibrium air

NASA Technical Reports Server (NTRS)

Jaffe, R. L.

1986-01-01

In the nonequilibrium atmospheric chemistry regime that will be encountered by the proposed Aeroassisted Orbital Transfer Vehicle in the upper atmosphere, where air density is too low for thermal and chemical equilibrium to be maintained, the detailed high temperature air chemistry plays a critical role in defining radiative and convective heating loads. Although vibrational and electronic temperatures remain low (less than 15,000 K), rotational and translational temperatures may reach 50,000 K. Attention is presently given to the effects of multiple temperatures on the magnitudes of various chemical reaction rate constants, for the cases of both bimolecular exchange reactions and collisional excitation and dissociation reactions.

Prototype water reuse system

USGS Publications Warehouse

Lucchetti, G.; Gray, G.A.

1988-01-01

A small-scale water reuse system (150 L/min) was developed to create an environment for observing fish under a variety of temperature regimes. Key concerns of disease control, water quality, temperature control, and efficiency and case of operation were addressed. Northern squawfish (Ptychocheilus oregonensis) were held at loading densities ranging from 0.11 to 0.97 kg/L per minute and at temperatures from 10 to 20°C for 6 months with no disease problems or degradation ofwater quality in the system. The system required little maintenance during 2 years of operation.

Radio Frequency Magneto-Optical Trapping of CaF with High Density.

PubMed

Anderegg, Loïc; Augenbraun, Benjamin L; Chae, Eunmi; Hemmerling, Boerge; Hutzler, Nicholas R; Ravi, Aakash; Collopy, Alejandra; Ye, Jun; Ketterle, Wolfgang; Doyle, John M

2017-09-08

We demonstrate significantly improved magneto-optical trapping of molecules using a very slow cryogenic beam source and either rf modulated or dc magnetic fields. The rf magneto-optical trap (MOT) confines 1.0(3)×10^{5} CaF molecules at a density of 7(3)×10^{6}  cm^{-3}, which is an order of magnitude greater than previous molecular MOTs. Near Doppler-limited temperatures of 340(20)  μK are attained. The achieved density enables future work to directly load optical tweezers and create optical arrays for quantum simulation.

Mathematical modeling of the crack growth in linear elastic isotropic materials by conventional fracture mechanics approaches and by molecular dynamics method: crack propagation direction angle under mixed mode loading

NASA Astrophysics Data System (ADS)

Stepanova, Larisa; Bronnikov, Sergej

2018-03-01

The crack growth directional angles in the isotropic linear elastic plane with the central crack under mixed-mode loading conditions for the full range of the mixity parameter are found. Two fracture criteria of traditional linear fracture mechanics (maximum tangential stress and minimum strain energy density criteria) are used. Atomistic simulations of the central crack growth process in an infinite plane medium under mixed-mode loading using Large-scale Molecular Massively Parallel Simulator (LAMMPS), a classical molecular dynamics code, are performed. The inter-atomic potential used in this investigation is Embedded Atom Method (EAM) potential. The plane specimens with initial central crack were subjected to Mixed-Mode loadings. The simulation cell contains 400000 atoms. The crack propagation direction angles under different values of the mixity parameter in a wide range of values from pure tensile loading to pure shear loading in a wide diapason of temperatures (from 0.1 К to 800 К) are obtained and analyzed. It is shown that the crack propagation direction angles obtained by molecular dynamics method coincide with the crack propagation direction angles given by the multi-parameter fracture criteria based on the strain energy density and the multi-parameter description of the crack-tip fields.

Ultrasonic technique for monitoring of liquid density variations

NASA Astrophysics Data System (ADS)

Kazys, R.; Rekuviene, R.; Sliteris, R.; Mazeika, L.; Zukauskas, E.

2015-01-01

A novel ultrasonic measurement technique for density measurements of different liquids in extreme conditions has been developed. The proposed density measurement method is based on transformation of the acoustic impedance of the measured liquid. The higher accuracy of measurements is achieved by means of the λ/4 acoustic matching layer between the load and the ultrasonic waveguide transducer. Introduction of the matching layer enhances sensitivity of the measurement system. Sometimes, the density measurements must be performed in very complex conditions: high temperature (up to 200 °C), pressure (up to 10 MPa), and high chemical activity of the medium under measurement. In this case, the special geometry metal waveguides are proposed to use in order to protect the piezoelectric transducer surface from influence of a high temperature. The experimental set-up of technique was calibrated using the reference liquids with different densities: ethyl ether, ethyl alcohol, distilled water, and different concentration (20%, 40%, and 60%) sugar-water solutions. The uncertainty of measurements is less than 1%. The proposed measurement method was verified in real conditions by monitoring the density of a melted polypropylene during manufacturing process.

BLAKE - A Thermodynamics Code Based on TIGER: Users’ Guide and Manual

DTIC Science & Technology

1982-07-01

hydrazine UDMH Water H20 3S I The formulas and enthalpies of formation of these ingredients are listed in Appendix B. Wherever possible they were taken...estimates for B(T), it does not improve the estimates of C(I). Numerically the contribution of the third coefficient is necessary- for loading densities ...here, C will be assumed independent of temperature. The vejume, V, is related to the reference mass, Mo, and the density , p, by P = M /V (9) 0 The

Development of membrane electrode assembly for high temperature proton exchange membrane fuel cell by catalyst coating membrane method

NASA Astrophysics Data System (ADS)

Liang, Huagen; Su, Huaneng; Pollet, Bruno G.; Pasupathi, Sivakumar

2015-08-01

Membrane electrode assembly (MEA), which contains cathode and anode catalytic layer, gas diffusion layers (GDL) and electrolyte membrane, is the key unit of a PEMFC. An attempt to develop MEA for ABPBI membrane based high temperature (HT) PEMFC is conducted in this work by catalyst coating membrane (CCM) method. The structure and performance of the MEA are examined by scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS) and I-V curve. Effects of the CCM preparation method, Pt loading and binder type are investigated for the optimization of the single cell performance. Under 160 °C and atmospheric pressure, the peak power density of the MEA, with Pt loading of 0.5 mg cm-2 and 0.3 mg cm-2 for the cathode and the anode, can reach 277 mW cm-2, while a current density of 620 A cm-2 is delivered at the working voltage of 0.4 V. The MEA prepared by CCM method shows good stability operating in a short term durability test: the cell voltage maintained at ∼0.45 V without obvious drop when operated at a constant current density of 300 mA cm-2 and 160 °C under ambient pressure for 140 h.

Low-temperature operation of a Buck DC/DC converter

NASA Technical Reports Server (NTRS)

Ray, Biswajit; Gerber, Scott S.; Patterson, Richard L.; Myers, Ira T.

1995-01-01

Low-temperature (77 K) operation of a 42/28 V, 175 W, 50 kHz PWM Buck DC/DC converter designed with commercially available components is reported. Overall, the converter losses decreased at 77 K compared to room temperature operation. A full-load efficiency of 97 percent was recorded at liquid-nitrogen temperature, compared to 95.8 percent at room temperature. Power MOSFET operation improved significantly where as the output rectifier operation deteriorated at low-temperature. The performance of the output filter inductor and capacitor did not change significantly at 77 K compared to room temperature performance. It is possible to achieve high-density and high efficiency power conversion at low-temperatures due to improved electronic, electrical and thermal properties of materials.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Meimei; Wang, Leyun; Almer, Jonathan D.

Deformation processes in Grade 91 (Fe–9%Cr–1%Mo–V,Nb) and Grade 92 (Fe–9%Cr–0.5%Mo–2%W–V,Nb) ferritic–martensitic steels were investigated at temperatures between 20 and 650 °C using high-energy synchrotron X-ray diffraction with in situ thermal–mechanical loading. The change of the dislocation density with strain was quantified by X-ray diffraction line profile analysis complemented by transmission electron microscopy measurements. The relationship between dislocation density and strain during uniform deformation was described by a dislocation model, and two critical materials parameters, namely dislocation mean free path and dynamic recovery coefficient, were determined as a function of temperature. Effects of alloy chemistry, thermal–mechanical treatment and temperature on themore » tensile deformation process in Grade 91 and Grade 92 steels can be well understood by the dislocation evolution behavior.« less

Temperature and initial curvature effects in low-density panel flutter

NASA Technical Reports Server (NTRS)

Resende, Hugo B.

1992-01-01

The panel flutter phenomenon is studied assuming free-molecule flow. This kind of analysis is relevant in the case of hypersonic flight vehicles traveling at high altitudes, especially in the leeward portion of the vehicle. In these conditions the aerodynamic shear can be expected to be considerably larger than the pressure at a given point, so that the effects of such a loading are incorporated into the structural model. Both the pressure and shear loadings are functions of the panel temperature, which can lead to great variations on the location of the stability boundaries for parametric studies. Different locations can, however, be 'collapsed' onto one another by using as ordinate an appropriately normalized dynamic pressure parameter. This procedure works better for higher values of the panel temperature for a fixed undisturbed flow temperature. Finally, the behavior of the system is studied when the panel has some initial curvature. This leads to the conclusion that it may be unrealistic to try to distinguish between a parabolic or sinusoidal initial shape.

An active homopolar magnetic bearing with high temperature superconductor (HTS) coils and ferromagnetic cores

NASA Technical Reports Server (NTRS)

Brown, G. V.; Dirusso, E.; Provenza, A. J.

1995-01-01

A proof-of-feasibility demonstration showed that high temperature superconductor (HTS) coils can be used in a high-load, active magnetic bearing in liquid nitrogen. A homopolar radial bearing with commercially wound HTS (Bi 2223) bias and control coils produced over 200 lb (890 N) radial load capacity (measured non-rotating) and supported a shaft to 14000 rpm. The goal was to show that HTS coils can operate stably with ferromagnetic cores in a feedback controlled system at a current density similar to that in Cu in liquid nitrogen. Design compromises permitted use of circular coils with rectangular cross section. Conductor improvements will eventually permit coil shape optimization, higher current density and higher bearing load capacity. The bias coil, wound with non-twisted, multifilament HTS conductor, required negligible power to carry its direct current. The control coils were wound with monofilament HTS sheathed in Ag. These dissipated negligible power for direct current (i.e. for steady radial load components). When an alternating current (AC) was added, the AC component dissipated power which increased rapidly with frequency and quadratically with AC amplitude. In fact at frequencies above about 2 hz, the effective resistance of the control coil conductor actually exceeds that of the silver which is in electrical parallel with the oxide superconductor. This is at least qualitatively understandable in the context of a Bean-type model of flux and current penetration into a Type II superconductor. Fortunately the dynamic currents required for bearing stability are of small amplitude. These results show that while twisted multifilament conductor is not needed for stable levitation, twisted multifilaments will be required to reduce control power for sizable dynamic loads, such as those due to unbalance.

Characterization of centrifugally-loaded flame migration for ultra-compact combustors

NASA Astrophysics Data System (ADS)

LeBay, Kenneth D.

The Air Force Research Laboratory (AFRL) has designed a centrifugally-loaded Ultra-Compact Combustor (UCC) showing viable merit for reducing gas turbine combustor length by as much as 66%. The overarching goal of this research was to characterize the migration of centrifugally-loaded flames in a sectional model of the UCC to enable scaling of the design from 15 cm to the 50--75 cm diameter of most engines. Two-line Planar Laser-Induced Fluorescence thermometry (PLIF) of OH, time-resolved Particle Image Velocimetry (PIV), and high-speed video data were collected. Using a sectional UCC model, the flame migration angle was determined to be a function of the UCC/core velocity ratio (VR) while both the VR and the centrifugal or "g-load" affected the migration quantity. Higher g-loads and lower VRs yielding higher migration but lower VRs had lower core flow temperatures due to higher core air mass flow. A comparison of the straight and curved UCC sections showed the centrifugal load increased the flame migration but increased unsteadiness. The flame migration into the core was estimated using pressure and temperature measurements upstream, and PIV measurements downstream of the core flow interface with constant density and velocity profile assumptions. The flame migration quantity was used to estimate the core flow temperature which was in relatively good agreement with the measured PLIF values. The migration quantity scaled relatively linearly with the UCC tangential velocity, which corresponds to the g-load value, with the slope determined by the VR. A simple analytical model resulted for the dependence of the migration quantity on the tangential velocity and VR. The quantitative relationships determined in this research provided a detailed description of the migration of centrifugally-loaded flames in a sectional UCC.

Probing density and spin correlations in two-dimensional Hubbard model with ultracold fermions

NASA Astrophysics Data System (ADS)

Chan, Chun Fai; Drewes, Jan Henning; Gall, Marcell; Wurz, Nicola; Cocchi, Eugenio; Miller, Luke; Pertot, Daniel; Brennecke, Ferdinand; Koehl, Michael

2017-04-01

Quantum gases of interacting fermionic atoms in optical lattices is a promising candidate to study strongly correlated quantum phases of the Hubbard model such as the Mott-insulator, spin-ordered phases, or in particular d-wave superconductivity. We experimentally realise the two-dimensional Hubbard model by loading a quantum degenerate Fermi gas of 40 K atoms into a three-dimensional optical lattice geometry. High-resolution absorption imaging in combination with radiofrequency spectroscopy is applied to spatially resolve the atomic distribution in a single 2D layer. We investigate in local measurements of spatial correlations in both the density and spin sector as a function of filling, temperature and interaction strength. In the density sector, we compare the local density fluctuations and the global thermodynamic quantities, and in the spin sector, we observe the onset of non-local spin correlation, signalling the emergence of the anti-ferromagnetic phase. We would report our recent experimental endeavours to investigate further down in temperature in the spin sector.

Baseline Testing of Ultracapacitors for the Next Generation Launch Technology (NGLT) Project. Revised

NASA Technical Reports Server (NTRS)

Eichenberg, Dennis J.

2005-01-01

The NASA John H. Glenn Research Center initiated baseline testing of ultracapacitors for the Next Generation Launch Transportation (NGLT) project to obtain empirical data for determining the feasibility of using ultracapacitors for the project. There are large transient loads associated with NGLT that require either a very large primary energy source or an energy storage system. The primary power source used for these tests is a proton exchange membrane (PEM) fuel cell. The energy storage system can consist of devices such as batteries, flywheels, or ultracapacitors. Ultracapacitors were used for these tests. Ultracapacitors are ideal for applications such as NGLT where long life, maintenance-free operation, and excellent low-temperature performance is essential. State-of-the-art symmetric ultracapacitors were used for these tests. The ultracapacitors were interconnected in an innovative configuration to minimize interconnection impedance. PEM fuel cells provide excellent energy density, but not good power density. Ultracapacitors provide excellent power density, but not good energy density. The combination of PEM fuel cells and ultracapacitors provides a power source with excellent energy density and power density. The life of PEM fuel cells is shortened significantly by large transient loads. Ultracapacitors used in conjunction with PEM fuel cells reduce the transient loads applied to the fuel cell, and thus appreciably improves its life. PEM fuel cells were tested with and without ultracapacitors, to determine the benefits of ultracapacitors. The report concludes that the implementation of symmetric ultracapacitors in the NGLT power system can provide significant improvements in power system performance and reliability.

Baseline Testing of Ultracapacitors for the Next Generation Launch Technology (NGLT) Project

NASA Technical Reports Server (NTRS)

Eichenberg, Dennis J.

2004-01-01

The NASA John H. Glenn Research Center initiated baseline testing of ultracapacitors for the Next Generation Launch Transportation (NGLT) project to obtain empirical data for determining the feasibility of using ultracapacitors for the project. There are large transient loads associated with NGLT that require either a very large primary energy source or an energy storage system. The primary power source used for these tests is a proton exchange membrane (PEM) fuel cell. The energy storage system can consist of devices such as batteries, flywheels, or ultracapacitors. Ultracapacitors were used for these tests. Ultracapacitors are ideal for applications such as NGLT where long life, maintenance-free operation, and excellent low-temperature performance is essential. State-of-the-art symmetric ultracapacitors were used for these tests. The ultracapacitors were interconnected in an innovative configuration to minimize interconnection impedance. PEM fuel cells provide excellent energy density, but not good power density. Ultracapacitors provide excellent power density, but not good energy density. The combination of PEM fuel cells and ultracapacitors provides a power source with excellent energy density and power density. The life of PEM fuel cells is shortened significantly by large transient loads. Ultracapacitors used in conjunction with PEM fuel cells reduce the transient loads applied to the fuel cell, and thus appreciably improves its life. PEM fuel cells were tested with and without ultracapacitors, to determine the benefits of ultracapacitors. The report concludes that the implementation of symmetric ultracapacitors in the NGLT power system can provide significant improvements in power system performance and reliability.

A Compact, Continuous Adiabatic Demagnetization Refrigerator with High Heat Sink Temperature

NASA Technical Reports Server (NTRS)

Shirron, P. J.; Canavan, E. R.; DiPirro, M. J.; Jackson, M.; Tuttle, J. G.

2003-01-01

In the continuous adiabatic demagnetization refrigerator (ADR), the existence of a constant temperature stage attached to the load breaks the link between the requirements of the load (usually a detector array) and the operation of the ADR. This allows the ADR to be cycled much faster, which yields more than an order of magnitude improvement in cooling power density over single-shot ADRs. Recent effort has focused on developing compact, efficient higher temperature stages. An important part of this work has been the development of passive gas-gap heat switches that transition (from conductive to insulating) at temperatures around 1 K and 4 K without the use of an actively heated getter. We have found that by carefully adjusting available surface area and the number of He-3 monolayers, gas-gap switches can be made to operate passively. Passive operation greatly reduces switching time and eliminates an important parasitic heat load. The current four stage ADR provides 6 micro W of cooling at 50 mK (21 micro W at 100 mK) and weighs less than 8 kg. It operates from a 4.2 K heat sink, which can be provided by an unpumped He bath or many commercially available mechanical cryocoolers. Reduction in critical current with temperature in our fourth stage NbTi magnet presently limits the maximum temperature of our system to approx. 5 K. We are developing compact, low-current Nb3Sn magnets that will raise the maximum heat sink temperature to over 10 K.

Repeatability Measurements of Apparent Thermal Conductivity of Multilayer Insulation (MLI)

NASA Astrophysics Data System (ADS)

Vanderlaan, M.; Stubbs, D.; Ledeboer, K.; Ross, J.; Van Sciver, S.; Guo, W.

2017-12-01

This report presents and discusses the results of repeatability experiments gathered from the multi-layer insulation thermal conductivity experiment (MIKE) for the measurement of the apparent thermal conductivity of multi-layer insulation (MLI) at variable boundary temperatures. Our apparatus uses a calibrated thermal link between the lower temperature shield of a concentric cylinder insulation assembly and the cold head of a cryocooler to measure the heat leak. In addition, thermocouple readings are taken in-between the MLI layers. These measurements are part of a multi-phase NASA-Yetispace-FSU collaboration to better understand the repeatability of thermal conductivity measurements of MLI. NASA provided five 25 layer coupons and requested boundary temperatures of 20 K and 300 K. Yetispace provided ten 12-layer coupons and requested boundary temperatures of 77 K and 293 K. Test conditions must be met for a duration of four hours at a steady state variance of less than 0.1 K/hr on both cylinders. Temperatures from three Cernox® temperature sensors on each of the two cylinders are averaged to determine the boundary temperatures. A high vacuum, less than 10-5 torr, is maintained for the duration of testing. Layer density varied from 17.98 - 26.36 layers/cm for Yetispace coupons and 13.05 - 17.45 layers/cm for the NASA coupons. The average measured heat load for the Yetispace coupons was 2.40 W for phase-one and 2.92 W for phase-two. The average measured heat load for the NASA coupons was 1.10 W. This suggests there is still unknown variance of MLI performance. It has been concluded, variations in the insulation installation heavy effect the apparent thermal conductivity and are not solely dependent on layer density.

Thermal properties of silica-filled high density polyethylene composites compatibilized with glut palmitate

NASA Astrophysics Data System (ADS)

Samsudin, Dalina; Ismail, Hanafi; Othman, Nadras; Hamid, Zuratul Ain Abdul

2017-07-01

A study of thermal properties resulting from the utilization of Glut Palmitate (GP) on the silica filled high density polyethylene (HDPE) composites was carried out. The composites with the incorporation of GP at 0.5, 1.0, 2.0 and 3.0 phr were prepared by using an internal mixer at the temperature 180 °C and the rotor speed of 50 rpm. The thermal behaviours of the composites were then investigated using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). It was found that the crystallinity and the thermal stability of the composites increased with the incorporation of GP. The highest crystallinity contents and decomposition temperatures were observed at the 1 phr GP loading.

Combined heat and power supply using Carnot engines

NASA Astrophysics Data System (ADS)

Horlock, J. H.

The Marshall Report on the thermodynamic and economic feasibility of introducing large scale combined heat and electrical power generation (CHP) into the United Kingdom is summarized. Combinations of reversible power plant (Carnot engines) to meet a given demand of power and heat production are analyzed. The Marshall Report states that fairly large scale CHP plants are an attractive energy saving option for areas of high heat load densities. Analysis shows that for given requirements, the total heat supply and utilization factor are functions of heat output, reservoir supply temperature, temperature of heat rejected to the reservoir, and an intermediate temperature for district heating.

X-ray source characterization of aluminum X-pinch plasmas driven by the 0. 5 TW LION accelerator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qi, N.; Hammer, D.A.; Kalantar, D.H.

1989-12-01

Recent experiments at Cornell have been performed to investigate X-pinch plasmas as intense x-ray sources which might be used to pump resonant photoexcitation lasers. Crossed Al wires have been driven by up to 600 kA current for 40 ns. High density bright spots are observed at the crossing point(s). Various diagnostics were used to characterize the X-pinch plasmas as a function of initial mass loading for several specific wire configurations. The optimum mass loading for different ionization stages of Al, and the total x-ray energy yields, which are on the order of hundreds of Joules, were examined. Estimates of plasmamore » density, {similar to}10{sup 20} cm{sup {minus}3}, and temperature, about 400 eV, were obtained.« less

Microcracking in composite laminates under thermal and mechanical loading. Thesis

NASA Technical Reports Server (NTRS)

Maddocks, Jason R.

1995-01-01

Composites used in space structures are exposed to both extremes in temperature and applied mechanical loads. Cracks in the matrix form, changing the laminate thermoelastic properties. The goal of the present investigation is to develop a predictive methodology to quantify microcracking in general composite laminates under both thermal and mechanical loading. This objective is successfully met through a combination of analytical modeling and experimental investigation. In the analysis, the stress and displacement distributions in the vicinity of a crack are determined using a shear lag model. These are incorporated into an energy based cracking criterion to determine the favorability of crack formation. A progressive damage algorithm allows the inclusion of material softening effects and temperature-dependent material properties. The analysis is implemented by a computer code which gives predicted crack density and degraded laminate properties as functions of any thermomechanical load history. Extensive experimentation provides verification of the analysis. AS4/3501-6 graphite/epoxy laminates are manufactured with three different layups to investigate ply thickness and orientation effects. Thermal specimens are cooled to progressively lower temperatures down to -184 C. After conditioning the specimens to each temperature, cracks are counted on their edges using optical microscopy and in their interiors by sanding to incremental depths. Tensile coupons are loaded monotonically to progressively higher loads until failure. Cracks are counted on the coupon edges after each loading. A data fit to all available results provides input parameters for the analysis and shows them to be material properties, independent of geometry and loading. Correlation between experiment and analysis is generally very good under both thermal and mechanical loading, showing the methodology to be a powerful, unified tool. Delayed crack initiation observed in a few cases is attributed to a lack of preexisting flaws assumed by the analysis. Some interactions between adjacent ply groups are attributed to local stress concentrations. These two effects are not captured by the analysis due to its global nature. The analysis is conservative in these cases and agrees well with data after the observed onset of cracking.

X ray attenuation measurements for high-temperature materials characterization and in-situ monitoring of damage accumulation. Ph.D. Thesis - Cleveland State Univ., 1991

NASA Technical Reports Server (NTRS)

Baaklini, George Y.

1992-01-01

The scope of this dissertation is to develop and apply x ray attenuation measurement systems that are capable of: (1) characterizing density variations in high-temperature materials, e.g., monolithic ceramics, ceramic and intermetallic matrix composites, and (2) noninvasively monitoring damage accumulation and failure sequences in ceramic matrix composites under room temperature tensile testing. This dissertation results in the development of: (1) a point scan digital radiography system, and (2) an in-situ x ray material testing system. Radiographic evaluation before, during, and after loading shows the effect of preexisting volume flaws on the fracture behavior of composites. Results show that x ray film radiography can monitor damage accumulation during tensile loading. Matrix cracking, fiber matrix debonding, fiber bridging, and fiber pullout are imaged throughout the tensile loading of the specimens. Further in-situ radiography is found to be a practical technique for estimating interfacial shear strength between the silicon carbide fibers and the reaction bonded silicon nitride matrix. It is concluded that pretest, in-situ, and post test x ray imaging can provide for greater understanding of ceramic matrix composite mechanical behavior.

In-situ study of the gas-phase composition and temperature of an intermediate-temperature solid oxide fuel cell anode surface fed by reformate natural gas

NASA Astrophysics Data System (ADS)

Santoni, F.; Silva Mosqueda, D. M.; Pumiglia, D.; Viceconti, E.; Conti, B.; Boigues Muñoz, C.; Bosio, B.; Ulgiati, S.; McPhail, S. J.

2017-12-01

An innovative experimental setup is used for in-depth and in-operando characterization of solid oxide fuel cell anodic processes. This work focuses on the heterogeneous reactions taking place on a 121 cm2 anode-supported cell (ASC) running with a H2, CH4, CO2, CO and steam gas mixture as a fuel, using an operating temperature of 923 K. The results have been obtained by analyzing the gas composition and temperature profiles along the anode surface in different conditions: open circuit voltage (OCV) and under two different current densities, 165 mA cm-2 and 330 mA cm-2, corresponding to 27% and 54% of fuel utilization, respectively. The gas composition and temperature analysis results are consistent, allowing to monitor the evolution of the principal chemical and electrochemical reactions along the anode surface. A possible competition between CO2 and H2O in methane internal reforming is shown under OCV condition and low current density values, leading to two different types of methane reforming: Steam Reforming and Dry Reforming. Under a current load of 40 A, the dominance of exothermic reactions leads to a more marked increase of temperature in the portion of the cell close to the inlet revealing that current density is not uniform along the anode surface.

Matrix cracking in laminated composites under monotonic and cyclic loadings

NASA Technical Reports Server (NTRS)

Allen, David H.; Lee, Jong-Won

1991-01-01

An analytical model based on the internal state variable (ISV) concept and the strain energy method is proposed for characterizing the monotonic and cyclic response of laminated composites containing matrix cracks. A modified constitution is formulated for angle-ply laminates under general in-plane mechanical loading and constant temperature change. A monotonic matrix cracking criterion is developed for predicting the crack density in cross-ply laminates as a function of the applied laminate axial stress. An initial formulation for a cyclic matrix cracking criterion for cross-ply laminates is also discussed. For the monotonic loading case, a number of experimental data and well-known models are compared with the present study for validating the practical applicability of the ISV approach.

Kinetics of (3-aminopropyl)triethoxylsilane (APTES) silanization of superparamagnetic iron oxide nanoparticles.

PubMed

Liu, Yue; Li, Yueming; Li, Xue-Mei; He, Tao

2013-12-10

Silanization of magnetic ironoxide nanoparticles with (3-aminopropyl)triethoxylsilane (APTES) is reported. The kinetics of silanization toward saturation was investigated using different solvents including water, water/ethanol (1/1), and toluene/methanol (1/1) at different reaction temperature with different APTES loading. The nanoparticles were characterized by Fourier transform infrared spectroscopy, vibrating sample magnetometry, transmission electron microscopy, and thermal gravimetric analysis (TGA). Grafting density data based on TGA were used for the kinetic modeling. It is shown that initial silanization takes place very fast but the progress toward saturation is very slow, and the mechanism may involve adsorption, chemical sorption, and chemical diffusion processes. The highest equilibrium grafting density of 301 mg/g was yielded when using toluene/methanol mixture as the solvent at a reaction temperature of 70 °C.

Tensile properties of chrome tanned leather waste short fibre filled unsaturated polyester composite

NASA Astrophysics Data System (ADS)

Talib, Satariah; Romli, Ahmad Zafir; Saad, Siti Zaleha

2017-12-01

Waste leather from industries was commonly disposed via land filling or incineration where the oxidation of Cr III to Cr VI by oxidants (such as peroxides and hypohalide) can easily occur. Cr VI is well known as carcinogenic and mutagenic element where the excessive exposure to this element can be very harmful. As an alternative way, the leather waste from footwear industry was utilised as filler in unsaturated polyester composite (UPC). The leather waste was ground using 0.25 mm mesh size and used without any chemical treatment. The sample was fabricated via castingtechnique and the study was carried out at 1 wt%, 2 wt% and 3 wt% filler loading. The leather waste filled composites showed lower tensile strength and Young's modulus than the unfilled composite. The increasing loading amount of leather waste led to the decreased in tensile strength and Young's modulus. The tensile results was supported by the decreasing pattern of density result which indicates the increasing of void content as the filler loading increased. The results of glass transition temperature are also parallel to the tensile properties where the increasing filler loading had decreased the glass transition temperature. Based on the morphological observation on the fractured tensile sample, much severe filler agglomerations and higher amount of voids was observed at higher filler loading compared to the lower filler loading.

In situ X-ray monitoring of damage accumulation in SiC/RBSN tensile specimens

NASA Technical Reports Server (NTRS)

Baaklini, George Y.; Bhatt, Ramkrishna T.

1991-01-01

The room-temperature tensile testing of silicon carbide fiber reinforced reaction-bonded silicon nitride (SiC/RBSN) composite specimens was monitored by using in-situ X-ray film radiography. Radiographic evaluation before, during, and after loading provided data on the effect of preexisting volume flaws (high density impurities, and local density variations) on the fracture behavior of composites. Results from (O)1, (O)3, (O)5, and (O)8 composite specimens showed that X-ray film radiography can monitor damage accumulations during tensile loading. Matrix cracking, fiber-matrix debonding, and fiber pullout were imaged throughout the tensile loading history of the specimens. Further, in-situ film radiography was found to be a helpful and practical technique for estimating interfacial shear strength between the SiC fiber and the RBSN matrix by the matrix crack spacing method. It is concluded that pretest, in-situ, and post-test radiography can provide for a greater understanding of ceramic matrix composite mechanical behavior, a verification of related experimental procedures, and a validation and development of related analytical models.

In-situ x-ray monitoring of damage accumulation in SiC/RBSN tensile specimens

NASA Technical Reports Server (NTRS)

Baaklini, George Y.; Bhatt, Ramakrishna T.

1991-01-01

The room-temperature tensile testing of silicon carbide fiber reinforced reaction-bonded silicon nitride (SiC/RBSN) composite specimens was monitored by using in-situ x ray film radiography. Radiographic evaluation before, during, and after loading provided data on the effect of preexisting volume flaws (high density impurities, and local density variations) on the fracture behavior of composites. Results from (0)1, (0)3, (0)5, and (0)8 composite specimens, showed that x ray film radiography can monitor damage accumulations during tensile loading. Matrix cracking, fiber-matrix debonding, and fiber pullout were imaged throughout the tensile loading history of the specimens. Further, in-situ film radiography was found to be a helpful and practical technique for estimating interfacial shear strength between the SiC fiber and the RBSN matrix by the matrix crack spacing method. It is concluded that pretest, in-situ, and post-test radiography can provide for a greater understanding of ceramic matrix composite mechanical behavior, a verification of related experimental procedures, and a validation and development of related analytical models.

Fatigue behavior and life prediction of a SiC/Ti-24Al-11Nb composite under isothermal conditions. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Bartolotta, Paul A.

1991-01-01

Metal Matrix Composites (MMC) and Intermetallic Matrix Composites (IMC) were identified as potential material candidates for advanced aerospace applications. They are especially attractive for high temperature applications which require a low density material that maintains its structural integrity at elevated temperatures. High temperature fatigue resistance plays an important role in determining the structural integrity of the material. This study attempts to examine the relevance of test techniques, failure criterion, and life prediction as they pertain to an IMC material, specifically, unidirectional SiC fiber reinforced titanium aluminide. A series of strain and load controlled fatigue tests were conducted on unidirectional SiC/Ti-24Al-11Nb composite at 425 and 815 C. Several damage mechanism regimes were identified by using a strain-based representation of the data, Talreja's fatigue life diagram concept. Results of these tests were then used to address issues of test control modes, definition of failure, and testing techniques. Finally, a strain-based life prediction method was proposed for an IMC under tensile cyclic loadings at elevated temperatures.

Brittle Materials Design, High Temperature Gas Turbine

DTIC Science & Technology

1976-04-01

iii iv v xii 1. Introduction 1 2. Introduction and Summary-Vehicular Turbine Project 3 2.1 Vehicular Turbine Project Plan 5 2.2 Progress and...64.4% SiaNi» - 35.6% AI2O3 + 16.1% Y-O3 Sialon Figure 4.33 Longitudinal ( V ^ and Transverse (Vt) Sonic Velocity vs Density of Silicon Nitride...Peak Load Temperature) Page No. 99 101 102 104 106 109 110 111 118 119 120 120 121 122 122 123 V ? xl R*»" - ■■ ■— ^ .w<ui>wMu

Note: High-power piezoelectric transformer fabricated with ternary relaxor ferroelectric Pb(Mg(1/3)Nb(2/3))O3-Pb(In(1/2)Nb(1/2))O3-PbTiO3 single crystal.

PubMed

Wang, Qing; Ma, Chuanguo; Wang, Feifei; Liu, Bao; Chen, Jianwei; Luo, Haosu; Wang, Tao; Shi, Wangzhou

2016-03-01

A plate-shaped piezoelectric transformer was designed and fabricated using ternary relaxor ferroelectric single crystal Pb(Mg(1/3)Nb(2/3))O3-Pb(In(1/2)Nb(1/2))O3-PbTiO3. Both the input and output sections utilized the transverse-extensional vibration mode. The frequency and load dependences of the electrical properties for the proposed transformer were systematically studied. Results indicated that under a matching load resistance of 14.9 kΩ, a maximum output power of 2.56 W was obtained with the temperature rise less than 5 °C. The corresponding power density reached up to 50 W/cm(3). This ternary single-crystal transformer had potential applications in compact-size converters requiring high power density.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sengupta, M.; Ganesh, R.

The dynamics of cylindrically trapped electron plasma has been investigated using a newly developed 2D Electrostatic PIC code that uses unapproximated, mass-included equations of motion for simulation. Exhaustive simulations, covering the entire range of Brillouin ratio, were performed for uniformly filled circular profiles in rigid rotor equilibrium. The same profiles were then loaded away from equilibrium with an initial value of rigid rotation frequency different from that required for radial force balance. Both these sets of simulations were performed for an initial zero-temperature or cold load of the plasma with no spread in either angular velocity or radial velocity. Themore » evolution of the off-equilibrium initial conditions to a steady state involve radial breathing of the profile that scales in amplitude and algebraic growth with Brillouin fraction. For higher Brillouin fractions, the growth of the breathing mode is followed by complex dynamics of spontaneous hollow density structures, excitation of poloidal modes, leading to a monotonically falling density profile.« less

Advanced rechargeable sodium batteries with novel cathodes

NASA Technical Reports Server (NTRS)

Distefano, S.; Ratnakumar, B. V.; Bankston, C. P.

1989-01-01

Various high energy density rechargeable batteries are being considered for future space applications. Of these, the sodium-sulfur battery is one of the leading candidates. The primary advantage is the high energy density (760 Wh/kg theoretical). Energy densities in excess of 180 Wh/kg were realized in practical batteries. Other technological advantages include its chemical simplicity, absence of self-discharge, and long cycle life possibility. More recently, other high temperature sodium batteries have come into the spotlight. These systems can be described as follow: Na/Beta Double Prime-Al2O3/NaAlCl4/Metal Dichloride Sodium/metal dichloride systems are colloquially known as the zebra system and are currently being developed for traction and load leveling applications. The sodium-metal dichloride systems appear to offer many of the same advantages of the Na/S system, especially in terms of energy density and chemical simplicity. The metal dichloride systems offer increased safety and good resistance to overcharge and operate over a wide range of temperatures from 150 to 400 C with less corrosion problems.

Direct thermal to electrical energy conversion using 9.5/65/35 PLZT ceramics in the ergodic relaxor phase.

PubMed

Chin, Thomas K; Lee, Felix Y; McKinley, Ian M; Goljahi, Sam; Lynch, Christopher S; Pilon, Laurent

2012-11-01

This paper reports on direct thermal to electrical energy conversion by performing the Olsen cycle on 9.5/65/35 lead lanthanum zirconate titanate (PLZT). The Olsen cycle consists of two isothermal and two isoelectric field processes in the electric displacement versus electric field diagram. It was performed by alternatively dipping the material in hot and cold dielectric fluid baths under specified electric fields. The effects of applied electric field, sample thickness, electrode material, operating temperature, and cycle frequency on the energy and power densities were investigated. A maximum energy density of 637 ± 20 J/L/cycle was achieved at 0.054 Hz with a 250-μm-thick sample featuring Pt electrodes and coated with a silicone conformal coating. The operating temperatures varied between 3°C and 140°C and the electric field was cycled between 0.2 and 6.0 MV/m. A maximum power density of 55 ± 8 W/L was obtained at 0.125 Hz under the same operating temperatures and electric fields. The dielectric strength of the material, and therefore the energy and power densities generated, increased when the sample thickness decreased from 500 to 250 μm. Furthermore, the electrode material was found to have no significant effect on the energy and power densities for samples subject to the same operating temperatures and electric fields. However, samples with electrode material possessing thermal expansion coefficients similar to that of PLZT were capable of withstanding larger temperature swings. Finally, a fatigue test showed that the power generation gradually degraded when the sample was subject to repeated thermoelectrical loading.

Thermal-gradient migration of brine inclusions in salt crystals. [Synthetic single crystals of NaCl and KCl

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yagnik, S.K.

1982-09-01

It has been proposed that high-level nuclear waste be disposed in a geologic repository. Natural-salt deposits, which are being considered for this purpose, contain a small volume fraction of water in the form of brine inclusions distributed throughout the salt. Radioactive-decay heating of the nuclear wastes will impose a temperature gradient on the surrounding salt which mobilizes the brine inclusions. Inclusions filled completely with brine migrate up the temperature gradient and eventually accumulate brine near the buried waste forms. The brine may slowly corrode or degrade the waste forms which is undesirable. In this work, thermal gradient migration of bothmore » all-liquid and gas-liquid inclusions was experimentally studied in synthetic single crystals of NaCl and KCl using a hot-stage attachment to an optical microscope which was capable of imposing temperature gradients and axial compressive loads on the crystals. The migration velocities of the inclusions were found to be dependent on temperature, temperature gradient, and inclusion shape and size. The velocities were also dictated by the interfacial mass transfer resistance at brine/solid interface. This interfacial resistance depends on the dislocation density in the crystal, which in turn, depends on the axial compressive loading of the crystal. At low axial loads, the dependence between the velocity and temperature gradient is non-linear.At high axial loads, however, the interfacial resistance is reduced and the migration velocity depends linearly on the temperature gradient. All-liquid inclusions filled with mixed brines were also studied. For gas-liquid inclusions, three different gas phases (helium, air and argon) were compared. Migration studies were also conducted on single crystallites of natural salt as well as in polycrystalline natural salt samples. The behavior of the inclusions at large angle grain boundaries was observed. 35 figures, 3 tables.« less

Tungsten and beryllium armour development for the JET ITER-like wall project

NASA Astrophysics Data System (ADS)

Maier, H.; Hirai, T.; Rubel, M.; Neu, R.; Mertens, Ph.; Greuner, H.; Hopf, Ch.; Matthews, G. F.; Neubauer, O.; Piazza, G.; Gauthier, E.; Likonen, J.; Mitteau, R.; Maddaluno, G.; Riccardi, B.; Philipps, V.; Ruset, C.; Lungu, C. P.; Uytdenhouwen, I.; EFDA contributors, JET

2007-03-01

For the ITER-like wall project at JET the present main chamber CFC tiles will be exchanged with Be tiles and in parallel a fully tungsten-clad divertor will be prepared. Therefore three R&D programmes were initiated: Be coatings on Inconel as well as Be erosion markers were developed for the first wall of the main chamber. High heat flux screening and cyclic loading tests carried out on the Be coatings on Inconel showed excellent performance, above the required power and energy density. For the divertor a conceptual design for a bulk W horizontal target plate was investigated, with the emphasis on minimizing electromagnetic forces. The design consisted of stacks of W lamellae of 6 mm width that were insulated in the toroidal direction. High heat flux tests of a test module were performed with an electron beam at an absorbed power density up to 9 MW m-2 for more than 150 pulses and finally with increasing power loads leading to surface temperatures in excess of 3000 °C. No macroscopic failure occurred during the test while SEM showed the development of micro-cracks on the loaded surface. For all other divertor parts R&D was performed to provide the technology to coat the 2-directional CFC material used at JET with thin tungsten coatings. The W-coated CFC tiles were subjected to heat loads with power densities ranging up to 23.5 MW m-2 and exposed to cyclic heat loading for 200 pulses at 10.5 MW m-2. All coatings developed cracks perpendicular to the CFC fibres due to the stronger contraction of the coating upon cool-down after the heat pulses.

Density and lithospheric structure at Tyrrhena Patera, Mars, from gravity and topography data

NASA Astrophysics Data System (ADS)

Grott, M.; Wieczorek, M. A.

2012-09-01

The Tyrrhena Patera highland volcano, Mars, is associated with a relatively well localized gravity anomaly and we have carried out a localized admittance analysis in the region to constrain the density of the volcanic load, the load thickness, and the elastic thickness at the time of load emplacement. The employed admittance model considers loading of an initially spherical surface, and surface as well as subsurface loading is taken into account. Our results indicate that the gravity and topography data available at Tyrrhena Patera is consistent with the absence of subsurface loading, but the presence of a small subsurface load cannot be ruled out. We obtain minimum load densities of 2960 kg m-3, minimum load thicknesses of 5 km, and minimum load volumes of 0.6 × 106 km3. Photogeological evidence suggests that pyroclastic deposits make up at most 30% of this volume, such that the bulk of Tyrrhena Patera is likely composed of competent basalt. Best fitting model parameters are a load density of 3343 kg m-3, a load thickness of 10.8 km, and a load volume of 1.7 × 106 km3. These relatively large load densities indicate that lava compositions are comparable to those at other martian volcanoes, and densities are comparable to those of the martian meteorites. The elastic thickness in the region is constrained to be smaller than 27.5 km at the time of loading, indicating surface heat flows in excess of 24 mW m-2.

Numerical Stress Analysis during Cooldown and Compressive Loading in an Imperfect Nb 3Sn Wire

DOE Office of Scientific and Technical Information (OSTI.GOV)

d’Hauthuille, Luc; Zhai, Yuhu

In this paper, high field superconductors are critical to the success of next step magnetic fusion confinement devices such as ITER and DEMO. The low-temperature superconducting material that is currently favored for these applications, Nb 3Sn, is susceptible to performance due to its brittleness and high strain-sensitivity. Under extreme loads, an irreversible degradation in the maximum critical current density has been shown to occur and believed to be strongly influenced by two factors: plasticity and cracked filaments. Cracks in filaments are induced when sufficiently high stress concentrations occur in the wire. In this paper, we explore using finite element analysismore » the impact that voids have on the stress distributions and peak stresses under two loading conditions: transverse compressive loading in a 2D model, and a full cool down phase in a 3D model.« less

Numerical Stress Analysis during Cooldown and Compressive Loading in an Imperfect Nb 3Sn Wire

DOE PAGES

d’Hauthuille, Luc; Zhai, Yuhu

2017-07-11

In this paper, high field superconductors are critical to the success of next step magnetic fusion confinement devices such as ITER and DEMO. The low-temperature superconducting material that is currently favored for these applications, Nb 3Sn, is susceptible to performance due to its brittleness and high strain-sensitivity. Under extreme loads, an irreversible degradation in the maximum critical current density has been shown to occur and believed to be strongly influenced by two factors: plasticity and cracked filaments. Cracks in filaments are induced when sufficiently high stress concentrations occur in the wire. In this paper, we explore using finite element analysismore » the impact that voids have on the stress distributions and peak stresses under two loading conditions: transverse compressive loading in a 2D model, and a full cool down phase in a 3D model.« less

Assessment of air quality in a commercial cattle transport vehicle in Swedish summer and winter conditions.

PubMed

Wikner, I; Gebresenbet, G; Nilsson, C

2003-03-01

Transport by road can induce significant stress in cattle. Thermal stress is among the main stress producing factors during transport. The provision of ventilation in livestock transport vehicles is usually through openings along the sides of the vehicle. The incoming air will affect air quality inside by regulating temperature, relative humidity, gas levels and levels of other contaminants. The aim of the present investigation was to map out the air quality in a commercial cattle transport vehicle under various climatic conditions and with varying stocking densities and transport times. Distributions of air temperature, relative humidity and concentrations of ammonia, carbon dioxide, oxygen and methane have been determined during 35 experimental journeys. In average the mean temperature inside the compartment was about 3 degrees C and 6 degrees C higher than outside temperature in summer (+7.8(-)+24.0 degrees C) and winter (-24.3(-)+12.7 degrees C) conditions respectively. The temperature increment inside, as could be expected from theory, increased with reduced ventilation and increased animal density. Many stops to load new animals lowered the temperature increment and relative humidity in winter time. In summer more stops made the compartment temperature and relative humidity increase. The inside temperature distribution was less than about 3 degrees C during both summer and winter season. Average ammonia level varied between 3 and 6 ppm depending on stocking density and number of stops with a maximum value of 18 ppm. No detectable methane levels could be found inside the compartment at any time.

Analysis of stationary fuel cell dynamic ramping capabilities and ultra capacitor energy storage using high resolution demand data

NASA Astrophysics Data System (ADS)

Meacham, James R.; Jabbari, Faryar; Brouwer, Jacob; Mauzey, Josh L.; Samuelsen, G. Scott

Current high temperature fuel cell (HTFC) systems used for stationary power applications (in the 200-300 kW size range) have very limited dynamic load following capability or are simply base load devices. Considering the economics of existing electric utility rate structures, there is little incentive to increase HTFC ramping capability beyond 1 kWs -1 (0.4% s -1). However, in order to ease concerns about grid instabilities from utility companies and increase market adoption, HTFC systems will have to increase their ramping abilities, and will likely have to incorporate electrical energy storage (EES). Because batteries have low power densities and limited lifetimes in highly cyclic applications, ultra capacitors may be the EES medium of choice. The current analyses show that, because ultra capacitors have a very low energy storage density, their integration with HTFC systems may not be feasible unless the fuel cell has a ramp rate approaching 10 kWs -1 (4% s -1) when using a worst-case design analysis. This requirement for fast dynamic load response characteristics can be reduced to 1 kWs -1 by utilizing high resolution demand data to properly size ultra capacitor systems and through demand management techniques that reduce load volatility.

Analysis of Temperature and Humidity Field in a New Bulk Tobacco Curing Barn Based on CFD.

PubMed

Bai, Zhipeng; Guo, Duoduo; Li, Shoucang; Hu, Yaohua

2017-01-31

A new structure bulk tobacco curing barn was presented. To study the temperature and humidity field in the new structure tobacco curing barn, a 3D transient computational fluid dynamics (CFD) model was developed using porous medium, species transport, κ-ε turbulence and discrete phase models. The CFD results demonstrated that (1) the temperature and relative humidity predictions were validated by the experimental results, and comparison of simulation results with experimental data showed a fairly close agreement; (2) the temperature of the bottom and inlet area was higher than the top and outlet area, and water vapor concentrated on the top and outlet area in the barn; (3) tobacco loading density and thickness of tobacco leaves had an explicit effect on the temperature distributions in the barn.

Limited temperature response to the very large AD 1258 volcanic eruption

NASA Astrophysics Data System (ADS)

Timmreck, Claudia; Lorenz, Stephan J.; Crowley, Thomas J.; Kinne, Stefan; Raddatz, Thomas J.; Thomas, Manu A.; Jungclaus, Johann H.

2009-11-01

The large AD 1258 eruption had a stratospheric sulfate load approximately ten times greater than the 1991 Pinatubo eruption. Yet surface cooling was not substantially larger than for Pinatubo (˜0.4 K). We apply a comprehensive Earth System Model to demonstrate that the size of the aerosol particles needs to be included in simulations, especially to explain the climate response to large eruptions. The temperature response weakens because increased density of particles increases collision rate and therefore aerosol growth. Only aerosol particle sizes substantially larger than observed after the Pinatubo eruption yield temperature changes consistent with terrestrial Northern Hemisphere summer temperature reconstructions. These results challenge an oft-held assumption of volcanic impacts not only with respect to the immediate or longer-term temperature response, but also any ecosystem response, including extinctions.

Testing of Action of Direct Flame on Concrete

PubMed Central

Valek, Jaroslav; Novosad, Petr

2015-01-01

The paper states results of experimental exposition of concrete test specimens to direct flame. Concrete test specimens made from various mixtures differing in the type of aggregate, binder, dispersed reinforcement, and technological procedure were subjected to thermal load. Physicomechanical and other properties of all test specimens were tested before exposition to open flame: density, compressive strength, flexural strength, moisture content, and surface appearance. The specimens were visually observed during exposition to open flame and changes were recorded. Exposed surface was photographically documented before thermal load and at 10-minute intervals. Development of temperature of the specimens was documented with a thermocamera. After exposition to thermal load and cooling down, concrete specimens were visually observed, network of cracks was photographically documented, and maximal depth of spalled area was measured. PMID:25830162

Warm weather transport of broiler chickens in Manitoba. II. Truck management factors associated with death loss in transit to slaughter.

PubMed

Whiting, Terry L; Drain, Mairead E; Rasali, Drona P

2007-02-01

This observational study was conducted to identify the cause of death and load level factors associated with mortality in 1 090 733 Manitoba broiler chickens transported to slaughter in spring and early summer. Death loss in transit was 0.346% and accounted for 19% of the total carcass condemnation. The death loss pattern was clearly bimodal, with a low death loss in 180 of 198 shipments. Cumulative death loss during the growing phase of production was consistently associated with increased transport mortalities in load level models and when comparing high death loss with low death loss truckloads. High ambient temperature at the time of slaughter and loading density of the truck were the major factors associated with exceptional death loss.

Equation of state and some structural and dynamical properties of the confined Lennard-Jones fluid into carbon nanotube: A molecular dynamics study

NASA Astrophysics Data System (ADS)

Abbaspour, Mohsen; Akbarzadeh, Hamed; Salemi, Sirous; Abroodi, Mousarreza

2016-11-01

By considering the anisotropic pressure tensor, two separate equations of state (EoS) as functions of the density, temperature, and carbon nanotube (CNT) diameter have been proposed for the radial and axial directions for the confined Lennard-Jones (LJ) fluid into (11,11), (12,10), and (19,0) CNTs from 120 to 600 K using molecular dynamics (MD) simulations. We have also investigated the effects of the pore size, pore loading, chirality, and temperature on some of the structural and dynamical properties of the confined LJ fluid into (11,11), (12,10), (19,0), and (19,19) CNTs such as the radial density profile and self-diffusion coefficient. We have also determined the EoS for the confined LJ fluid into double and triple walled CNTs.

Dynamic Behaviors of Materials under Ramp Wave Loading on Compact Pulsed Power Generators

NASA Astrophysics Data System (ADS)

Zhao, Jianheng; Luo, Binqiang; Wang, Guiji; Chong, Tao; Tan, Fuli; Liu, Cangli; Sun, Chengwei

The technique using intense current to produce magnetic pressure provides a unique way to compress matter near isentrope to high density without obvious temperature increment, which is characterized as ramp wave loading, and firstly developed by Sandia in 1998. Firstly recent advances on compact pulsed power generators developed in our laboratory, such as CQ-4, CQ-3-MMAF and CQ-7 devices, are simply introduced here, which devoted to ramp wave loading from 50GPa to 200 GPa, and to ultrahigh-velocity flyer launching up to 30 km/s. And then, we show our progress in data processing methods and experiments of isentropic compression conducted on these devices mentioned above. The suitability of Gruneisen EOS and Vinet EOS are validated by isentropic experiments of tantalum, and the parameters of SCG constitutive equation of aluminum and copper are modified to give better prediction under isentropic compression. Phase transition of bismuth and tin are investigated under different initial temperatures, parameters of Helmholtz free energy and characteristic relaxation time in kinetic phase transition equation are calibrated. Supported by NNSF of China under Contract No.11327803 and 11176002

Human Brown Adipose Tissue Temperature and Fat Fraction Are Related to Its Metabolic Activity.

PubMed

Koskensalo, Kalle; Raiko, Juho; Saari, Teemu; Saunavaara, Virva; Eskola, Olli; Nuutila, Pirjo; Saunavaara, Jani; Parkkola, Riitta; Virtanen, Kirsi A

2017-04-01

The metabolic activity of human brown adipose tissue (BAT) has been previously examined using positron emission tomography (PET). The aim of this study was to use proton magnetic resonance spectroscopy (1H MRS) to investigate whether the temperature and the fat fraction (FF) of BAT and white adipose tissue (WAT) are associated with BAT metabolic activity determined by deoxy-2-18F-fluoro-d-glucose (18F-FDG)-PET. Ten healthy subjects (four women, six men; 25 to 45 years of age) were studied using PET-magnetic resonance imaging during acute cold exposure and at ambient room temperature. BAT and subcutaneous WAT 1H MRS were measured. The tissue temperature and the FF were derived from the spectra. Tissue metabolic activity was studied through glucose uptake using dynamic FDG PET scanning during cold exposure. A 2-hour hyperinsulinemic euglycemic clamp was performed on eight subjects. The metabolic activity of BAT associated directly with the heat production capacity and inversely with the FF of the tissue. In addition, the lipid-burning capacity of BAT associated with whole-body insulin sensitivity. During cold exposure, the FF of BAT was lower than at room temperature, and cold-induced FF of BAT associated inversely with high-density lipoprotein and directly with low-density lipoprotein cholesterol. Both 1H MRS-derived temperature and FF are promising methods to study BAT activity noninvasively. The association between the lipid-burning capacity of BAT and whole-body insulin sensitivity emphasizes the role of BAT in glucose handling. Furthermore, the relation of FF to high-density lipoprotein and low-density lipoprotein cholesterol suggests that BAT has a role in lipid clearance, thus protecting tissues from excess lipid load. Copyright © 2017 Endocrine Society

Neutronic performance of high-density LEU fuels in water-moderated and water-reflected research reactors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bretscher, M.M.; Matos, J.E.

At the Reduced Enrichment for Research and Test Reactors (RERTR) meeting in September 1994, Durand reported that the maximum uranium loading attainable with U{sub 3}Si{sub 2} fuel is about 6.0 g U/cm{sup 3}. The French Commissariat a l`Energie Atomique (CEA) plan to perform irradiation tests with 5 plates at this loading. Compagnie pour L`Etude et La Realisation de Combustibles Atomiques (CERCA) has also fabricated a few uranium nitride (UN) plates with a uranium density in the fuel meat of 7.0 g/cm{sup 3} and found that UN is compatible with the aluminum matrix at temperatures below 500 C. High density dispersionmore » fuels proposed for development include U-Zr(4 wt%)-Nb(2 wt%), U-Mo(5 wt%), and U-Mo(9 wt%). The purpose of this note is to examine the relative neutronic behavior of these high density fuels in a typical light water-reflected and water-moderated MTR-type research reactor. The results show that a dispersion of the U-Zr-Nb alloy has the most favorable neutronic properties and offers the potential for uranium densities greater than 8.0 g/cm{sup 3}. On the other hand, UN is the least reactive fuel because of the relatively large {sup 14}N(n,p) cross section. For a fixed value of k{sub eff}, the required {sup 235}U loading per fuel element is least for the U-Zr-Nb fuel and steadily increases for the U-Mo(5%), U-Mo(9%), and UN fuels. Because of volume fraction limitations, the UO{sub 2} dispersions are only useful for uranium densities below 5.0 g/cm{sup 3}. In this density range, however, UO{sub 2} is more reactive than U{sub 3}Si{sub 2}.« less

Metal-to-insulator crossover in alkali doped zeolite

PubMed Central

Igarashi, Mutsuo; Jeglič, Peter; Krajnc, Andraž; Žitko, Rok; Nakano, Takehito; Nozue, Yasuo; Arčon, Denis

2016-01-01

We report a systematic nuclear magnetic resonance investigation of the 23Na spin-lattice relaxation rate, 1/T1, in sodium loaded low-silica X (LSX) zeolite, Nan/Na12-LSX, for various loading levels of sodium atoms n across the metal-to-insulator crossover. For high loading levels of n ≥ 14.2, 1/T1T shows nearly temperature-independent behaviour between 10 K and 25 K consistent with the Korringa relaxation mechanism and the metallic ground state. As the loading levels decrease below n ≤ 11.6, the extracted density of states (DOS) at the Fermi level sharply decreases, although a residual DOS at Fermi level is still observed even in the samples that lack the metallic Drude-peak in the optical reflectance. The observed crossover is a result of a complex loading-level dependence of electric potential felt by the electrons confined to zeolite cages, where the electronic correlations and disorder both play an important role. PMID:26725368

Effect of Fly-Ash Cenospheres on Properties of Clay-Ceramic Syntactic Foams

PubMed Central

Rugele, Kristine; Lehmhus, Dirk; Hussainova, Irina; Peculevica, Julite; Lisnanskis, Marks; Shishkin, Andrei

2017-01-01

A low-density clay ceramic syntactic foam (CSF) composite material was successfully synthesized from illitic clay added by fly ash cenospheres (CS) using the semi-dry formation method. The content of CS varied in the range of 10, 30, 50 and 60 vol %. Furthermore, reference samples without cenospheres were produced for property comparison. The materials comprising different amount of the additives were fired at temperatures of 600, 950, 1000, 1050, 1100, 1150 and 1200 °C. Firing times were kept constant at 30 min. Processing characteristics of the materials were evaluated in terms of density achieved and shrinkage observed as functions of both the CS content and the sintering temperature. The compressive strength and water uptake were determined as application-oriented properties. Except for the reference and the low CS level samples, the materials show an increase in strength with the increase in firing temperature, and a decrease of mechanical reliability with a decrease in density, which is typical for porous materials. Exceptions are the samples with no or low (10 vol %) content of cenospheres. In this case, the maximum strength is obtained at an intermediate sintering temperature of 1100 °C. At a low density (1.10 and 1.25 g/cm3), the highest levels of strength are obtained after sintering at 1200 °C. For nominal porosity levels of 50 and 60 vol %, 41 and 26 MPa peak stresses, respectively, are recorded under compressive load. PMID:28773190

Response and adaptation of Beagle dogs to hypergravity

NASA Technical Reports Server (NTRS)

Oyama, J.

1975-01-01

Eight male Beagle dogs, five months old, were centrifuged continuously for three months at progressively increasing loads. Heart rate and deep body temperature were monitored continuously by implant biotelemetry. Initially, centrifuged dogs showed transient decreases in heart rate and body temperature along with changes in their diurnal rhythm patterns. Compared with normal gravity controls, exposed dogs showed a slower growth rate and a reduced amount of body fat. Blood protein, total lipids, cholesterol, calcium, packed cell volume, red blood cell count, and hemoglobin were also decreased significantly. Absolute weights of the leg bones of centrifuged dogs were significantly greater than controls. Photon absorptiometry revealed significant density increases in selective regions of the femur and humerus of centrifuged dogs. In spite of the various changes noted, results from this and other studies affirm the view that dogs can tolerate and adapt to sustained loads as high as 2.5 g without serious impairment of their body structure and function.

Fatigue Lifetime of Ceramic Matrix Composites at Intermediate Temperature by Acoustic Emission

PubMed Central

Racle, Elie; Godin, Nathalie; Reynaud, Pascal; Fantozzi, Gilbert

2017-01-01

The fatigue behavior of a Ceramic Matrix Composite (CMC) at intermediate temperature under air is investigated. Because of the low density and the high tensile strength of CMC, they offer a good technical solution to design aeronautical structural components. The aim of the present study is to compare the behavior of this composite under static and cyclic loading. Comparison between incremental static and cyclic tests shows that cyclic loading with an amplitude higher than 30% of the ultimate tensile strength has significant effects on damage and material lifetimes. In order to evaluate the remaining lifetime, several damage indicators, mainly based on the investigation of the liberated energy, are introduced. These indicators highlight critical times or characteristic times, allowing an evaluation of the remaining lifetime. A link is established with the characteristic time around 25% of the total test duration and the beginning of the matrix cracking during cyclic fatigue. PMID:28773019

Nature of hydrothermal fluids at the shale-hosted Red Dog Zn-Pb-Ag deposits, Brooks Range, Alaska

USGS Publications Warehouse

Leach, David L.; Marsh, Erin E.; Emsbo, Poul; Rombach, Cameron; Kelley, Karen D.; Anthony, Michael W.

2004-01-01

The densities of the methane inclusions, together with the temperature of homogenization of coexisting aqueous fluid inclusions, show that these fluid inclusions were trapped between pressures of 800 and 3,400 bars and temperatures between 187° and 214°C. The pressures obtained provide unequivocal evidence that the quartz formed after ore deposition in the Carboniferous because such high fluid pressures could only have been produced from thrust loading during the Mesozoic Brookian orogeny. The observed large variation in pressure is best explained by transient fluid pressures from hydrostatic to lithostatic conditions during thrust loading. The 3,400 bars pressure corresponds with about 12 km of lithostatic burial, whereas the lower pressures (800 bars) correspond with about 8 km of hydrostatic pressure. Because of their low salinity (0-5 wt % NaCl equiv) the electrolyte compositions of the quartz fluid inclusions do not constrain their origin.

Resonant coupling through a slot to a loaded cylindrical cavity: Experimental results

NASA Astrophysics Data System (ADS)

Norgard, John D.; Sega, Ronald M.

1990-03-01

The effect of cavity geometry on the energy coupled through a slot aperture is investigated through the use of planar mappings of the internal cavity field. A copper cylinder, closed at both ends, is constructed with copper mesh sections incorporated at the ends of the cylinder and in the cylinder wall opposite a thin slot aperture placed in the wall. The frequencies used for testing are 2 to 4 GHz. Internal field mapping is accomplished by placing thin carbon-loaded sheets in the plane of interest and recording the digitized temperature distribution using an infrared scanning system. The sheets are calibrated such that the temperature data is transformed to current densities or electric field strengths. Using several positions for the detection material, a three-dimensional field profile is obtained. The onset of the internal cavity resonance is studied as it is related to the energy coupled through small apertures.

Response of a thin airfoil encountering strong density discontinuity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marble, F.E.

1993-12-01

Airfoil theory for unsteady motion has been developed extensively assuming the undisturbed medium to be of uniform density, a restriction accurate for motion in the atmosphere. In some instances, notably for airfoil comprising fan, compressor and turbine blade rows, the undisturbed medium may carry density variations or ``spots``, resulting from non-uniformities in temperature or composition, of a size comparable to the blade chord. This condition exists for turbine blades, immediately downstream of the main burner of a gas turbine engine where the density fluctuations of the order of 50 percent may occur. Disturbances of a somewhat smaller magnitude arise frommore » the ingestion of hot boundary layers into fans, and exhaust into hovercraft. Because these regions of non-uniform density convect with the moving medium, the airfoil experiences a time varying load and moment which the authors calculate.« less

The effect of high fiber fraction on some mechanical properties of unidirectional glass fiber-reinforced composite.

PubMed

Abdulmajeed, Aous A; Närhi, Timo O; Vallittu, Pekka K; Lassila, Lippo V

2011-04-01

This study was designed to evaluate the effect of an increase of fiber-density on some mechanical properties of higher volume fiber-reinforced composite (FRC). Five groups of FRC with increased fiber-density were fabricated and two additional groups were prepared by adding silanated barium-silicate glass fillers (0.7 μm) to the FRC. The unidirectional E-glass fiber rovings were impregnated with light-polymerizable bisGMA-TEGDMA (50-50%) resin. The fibers were pulled through a cylindrical mold with an opening diameter of 4.2mm, light cured for 40s and post-cured at elevated temperature. The cylindrical specimens (n=12) were conditioned at room temperature for 2 days before testing with the three-point bending test (Lloyd Instruments Ltd.) adapted to ISO 10477. Fiber-density was analyzed by combustion and gravimetric analyzes. ANOVA analysis revealed that by increasing the vol.% fraction of E-glass fibers from 51.7% to 61.7% there was a change of 27% (p<0.05) in the modulus of elasticity, 34% (p<0.05) in the toughness, and 15% (p<0.05) in the load bearing capacity, while there was only 8% (p<0.05) increase in the flexural strength although it was statistically insignificant. The addition of particulate fillers did not improve the mechanical properties. This study showed that the properties of FRC could be improved by increasing fibervolume fraction. Modulus of elasticity, toughness, and load bearing capacity seem to follow the law of ratio of quantity of fibers and volume of the polymer matrix more precisely than flexural strength when high fiber-density is used. Copyright © 2010 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

Special Considerations for Qualifying Thin Films for Supper Pressure Pumpkin Ultra Long Duration Balloon (ULDB) Missions

NASA Astrophysics Data System (ADS)

Said, M.

Pumpkin type super pressure balloons require much less stringent mechanical requirements on the envelope film material when compared to spherical super pressure type balloons. However, since suitable thin films are typically viscoelastic in nature, their creep characteristics must be fully characterized and must not exceed specific and predetermined design limits. Proper assessment of materials limits to meet these design limits requires creep-load-temperature data that characterizes the performance of the material over a time that exceeds the duration of the design service life by some specified margin. Contrary to the behavior of materials with purely elastic response, visco-elastic materials such as these considered for the ULDB design, change their geometry under sustained loading over time. This change is usually reflected by exhibiting a significant visco-elastic component over the service life of the mission. For that regime of large visco-elastic response, where the material is highly nonlinear, a certain load-temperature threshold can be reached where the creep is limited by an asymptote that depends on both the temperature and load level. Such creep is recoverable, although the recovery period may be much longer than the 100 day design service life of the ULDB structure plus the factor of safety required for the design. For a typical flight, the most significant creep occurs at the highest temperature, which also produces the highest internal pressure. At mid- latitudes a significant portion of the service life is spent at night, i.e. at low temperature and low load; for the ULDB film, this nighttime contribution to creep is insignificant in comparison to any daytime contribution. By contrast, flight exposure in an Antarctic summer is at an almost constant high temperature and corresponding high pressure. This response behavior must be sufficiently characterized to serve the needs of the structural design and performance predictions of the vehicle in service. In this work, a special emphasis will be given to the creep and dynamic characteristics of selected coextruded films and their dependence on the loading level and temperature. Preliminary testing has suggested t at the creep behavior of theh coextruded linear low density resin films is highly dependent on temperature and that the dynamic response depends on the make up of the composite film. In addition, the paper will, in general, highlight the process of qualify ing thin films for the pumpkin class of super pressure balloons.

Mechanical degradation temperature of waste storage materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fink, M.C.; Meyer, M.L.

1993-05-13

Heat loading analysis of the Solid Waste Disposal Facility (SWDF) waste storage configurations show the containers may exceed 90{degrees}C without any radioactive decay heat contribution. Contamination containment is primarily controlled in TRU waste packaging by using multiple bag layers of polyvinyl chloride and polyethylene. Since literature values indicate that these thermoplastic materials can begin mechanical degradation at 66{degrees}C, there was concern that the containment layers could be breached by heating. To better define the mechanical degradation temperature limits for the materials, a series of heating tests were conducted over a fifteen and thirty minute time interval. Samples of a low-densitymore » polyethylene (LDPE) bag, a high-density polyethylene (HDPE) high efficiency particulate air filter (HEPA) container, PVC bag and sealing tape were heated in a convection oven to temperatures ranging from 90 to 185{degrees}C. The following temperature limits are recommended for each of the tested materials: (1) low-density polyethylene -- 110{degrees}C; (2) polyvinyl chloride -- 130{degrees}C; (3) high-density polyethylene -- 140{degrees}C; (4) sealing tape -- 140{degrees}C. Testing with LDPE and PVC at temperatures ranging from 110 to 130{degrees}C for 60 and 120 minutes also showed no observable differences between the samples exposed at 15 and 30 minute intervals. Although these observed temperature limits differ from the literature values, the trend of HDPE having a higher temperature than LDPE is consistent with the reference literature. Experimental observations indicate that the HDPE softens at elevated temperatures, but will retain its shape upon cooling. In SWDF storage practices, this might indicate some distortion of the waste container, but catastrophic failure of the liner due to elevated temperatures (<185{degrees}C) is not anticipated.« less

Physical requirements and milestones for the HIT-PoP Experiment

NASA Astrophysics Data System (ADS)

Jarboe, Thomas

2011-10-01

Recent success with HIT-SI demonstrates the viability of steady inductive helicity injection (SIHI) as a spheromak formation and sustainment method. Results include the sustainment of toroidal current of over 50 kA, up to 40 kA of plasma current that is separate from the injectors, toroidal flux up to 6 times the peak injected flux, and j/n > 1014Am. All were achieved with 10MW or less applied power. This paper explores the requirements for a confinement test of the concept using a larger proof of principle experiment. The confinement experiment must not exceed the beta limit, the drift parameter limit, or the wall loading limit, where the drift parameter is (drift of electrons relative to ions to produce current)/(ion thermal speed). It must also exceed a minimum j/n, a minimum n a, and a minimum electron temperature, where a is the minor radius. The drift parameter limit and beta limit appear to play defining roles in spheromak performance leading to a very favorable scaling of wall loading with size. The milestones sequence suggested is the following: 1. Startup at drift parameter and beta limit minimum density. 2. Raise current until j/n exceeds 10-14Am. 3. Raise the current and temperature until T ~ 50 eV for good ionization. 4. Raise the current and density until n a > 2x1019 m-2 for neutral screening. 5. Raise current and temperature until T > 200eV so magnetic confinement can be studied.

Anisotropic responses and initial decomposition of condensed-phase β-HMX under shock loadings via molecular dynamics simulations in conjunction with multiscale shock technique.

PubMed

Ge, Ni-Na; Wei, Yong-Kai; Song, Zhen-Fei; Chen, Xiang-Rong; Ji, Guang-Fu; Zhao, Feng; Wei, Dong-Qing

2014-07-24

Molecular dynamics simulations in conjunction with multiscale shock technique (MSST) are performed to study the initial chemical processes and the anisotropy of shock sensitivity of the condensed-phase HMX under shock loadings applied along the a, b, and c lattice vectors. A self-consistent charge density-functional tight-binding (SCC-DFTB) method was employed. Our results show that there is a difference between lattice vector a (or c) and lattice vector b in the response to a shock wave velocity of 11 km/s, which is investigated through reaction temperature and relative sliding rate between adjacent slipping planes. The response along lattice vectors a and c are similar to each other, whose reaction temperature is up to 7000 K, but quite different along lattice vector b, whose reaction temperature is only up to 4000 K. When compared with shock wave propagation along the lattice vectors a (18 Å/ps) and c (21 Å/ps), the relative sliding rate between adjacent slipping planes along lattice vector b is only 0.2 Å/ps. Thus, the small relative sliding rate between adjacent slipping planes results in the temperature and energy under shock loading increasing at a slower rate, which is the main reason leading to less sensitivity under shock wave compression along lattice vector b. In addition, the C-H bond dissociation is the primary pathway for HMX decomposition in early stages under high shock loading from various directions. Compared with the observation for shock velocities V(imp) = 10 and 11 km/s, the homolytic cleavage of N-NO2 bond was obviously suppressed with increasing pressure.

Modelling of mitigation of the power divertor loading for the EU DEMO through Ar injection

NASA Astrophysics Data System (ADS)

Subba, Fabio; Aho-Mantila, Leena; Coster, David; Maddaluno, Giorgio; Nallo, Giuseppe F.; Sieglin, Bernard; Wenninger, Ronald; Zanino, Roberto

2018-03-01

In this paper we present a computational study on the divertor heat load mitigation through impurity injection for the EU DEMO. The study is performed by means of the SOLPS5.1 code. The power crossing the separatrix is considered fixed and corresponding to H-mode operation, whereas the machine operating condition is defined by the outboard mid-plane upstream electron density and the impurity level. The selected impurity for this study is Ar, based on its high radiation efficiency at SOL characteristic temperatures. We consider a conventional vertical target geometry for the EU DEMO and monitor target conditions for different operational points, considering as acceptability criteria the target electron temperature (≤5 eV to provide sufficiently low W sputtering rate) and the peak heat flux (below 5-10 MW m-2 to guarantee safe steady-state cooling conditions). Our simulations suggest that, neglecting the radiated power deposition on the plate, it is possible to satisfy the desired constraints. However, this requires an upstream density of the order of at least 50% of the Greenwald limit and a sufficiently high argon fraction. Furthermore, if the radiated power deposition is taken into account, the peak heat flux on the outer plate could not be reduced below 15 MW m-2 in these simulations. As these simulations do not take into account neutron loading, they strongly indicate that the vertical target divertor solution with a radiative front distributed along the divertor leg has a very marginal operational space in an EU DEMO sized reactor.

Development of thermosensitive chitosan/glicerophospate injectable in situ gelling solutions for potential application in intraoperative fluorescence imaging and local therapy of hepatocellular carcinoma: a preliminary study.

PubMed

Salis, Andrea; Rassu, Giovanna; Budai-Szűcs, Maria; Benzoni, Ilaria; Csányi, Erzsébet; Berkó, Szilvia; Maestri, Marcello; Dionigi, Paolo; Porcu, Elena P; Gavini, Elisabetta; Giunchedi, Paolo

2015-01-01

Thermosensitive chitosan/glycerophosphate (C/GP) solutions exhibiting sol-gel transition around body temperature were prepared to develop a class of injectable hydrogel platforms for the imaging and loco-regional treatment of hepatocellular carcinoma (HCC). Indocyanine green (ICG) was loaded in the thermosensitive solutions in order to assess their potential for the detection of tumor nodules by fluorescence. The gel formation of these formulations as well as their gelling time, injectability, compactness and resistance of gel structure, gelling temperature, storage conditions, biodegradability, and in vitro dye release behavior were investigated. Ex vivo studies were carried out for preliminary evaluation using an isolated bovine liver. Gel strengths and gelation rates increased with the cross-link density between C and GP. These behaviors are more evident for C/GP solutions, which displayed a gel-like precipitation at 4°C. Furthermore, formulations with the lowest cross-link density between C and GP exhibited the best injectability due to a lower resistance to flow. The loading of the dye did not influence the gelation rate. ICG was not released from the hydrogels because of a strong electrostatic interaction between C and ICG. Ex vivo preliminary studies revealed that these injectable formulations remain in correspondence of the injected site. The developed ICG-loaded hydrogels have the potential for intraoperative fluorescence imaging and local therapy of HCC as embolic agents. They form in situ compact gels and have a good potential for filling vessels and/or body cavities.

A model for the pyrolysis of unfilled and filled polymers and comparisons with NBS smoke-density chamber data

NASA Technical Reports Server (NTRS)

Kumar, R. N.

1976-01-01

This paper considers a model for the pyrolysis of polymers for use in mass loss and smoke density predictions in a fire situation. It is based on the fundamental postulate that the overall rate-limiting reactions are in the relatively low temperature condensed phase; the rate limiting step is the polymer degradation to a vaporizable state. The state of the polymer (chain length) at the surface is specified by the vapor pressure equilibrium criterion. For the case of polymers with inert fillers, like alumina trihydrate, the further assumption is made that the linear regression rate of the material is identical to the unfilled material's at the same surface temperature. The fraction of polymer mass loss converted to smoke is inferred from the literature. The smoke density in the NBS-smoke density chamber is predicted for a polyester and the same polyester with two different loads of alumina trihydrate filler. Diffusional effects in the smoke spreading are considered in an elementary manner. The comparisons with experimental data are encouraging. The overall fire characteristics are predicted using only the fundamental physicochemical property values of ingredients.

Development of sugar palm yarn/glass fibre reinforced unsaturated polyester hybrid composites

NASA Astrophysics Data System (ADS)

Nurazzi, N. Mohd; Khalina, A.; Sapuan, S. Mohd; Rahmah, M.

2018-04-01

This study investigates the effect of fibre hybridization for sugar palm yarn fibre with glass fibre reinforced with unsaturated polyester composites. In this work, unsaturated polyester resin are reinforced with fibre at a ratio of 70:30 wt% and 60:40 wt%. The hybrid composites were characterized in terms of physical (density and water absorption), mechanical (tensile, flexural and compression) and thermal properties through thermal gravimetry analysis (TGA). Density determination showed that density increased with higher wt% of glass fibre. The inherently higher density of glass fibre increased the density of hybrid composite. Resistance to water absorption is improved upon the incorporation of glass fibre and the hybrid composites were found to reach equilibrium absorption at days 4 and 5. As for mechanical performance, the highest tensile strength, tensile modulus, flexural strength, flexural modulus and compression strength were obtained from 40 wt% of fibres reinforcement with ratio of 50:50 wt% of sugar palm yarn fibre and glass fibre reinforced unsaturated polyester composites. The increase of glass fibre loading had a synergistic effect on the mechanical properties to the composites structure due to its superior strength and modulus. The thermal stability of hybrid composites was improved by the increase of onset temperature and the reduction of residues upon increase in temperature.

Ceramic-ceramic shell tile thermal protection system and method thereof

NASA Technical Reports Server (NTRS)

Riccitiello, Salvatore R. (Inventor); Smith, Marnell (Inventor); Goldstein, Howard E. (Inventor); Zimmerman, Norman B. (Inventor)

1986-01-01

A ceramic reusable, externally applied composite thermal protection system (TPS) is proposed. The system functions by utilizing a ceramic/ceramic upper shell structure which effectively separates its primary functions as a thermal insulator and as a load carrier to transmit loads to the cold structure. The composite tile system also prevents impact damage to the atmospheric entry vehicle thermal protection system. The composite tile comprises a structurally strong upper ceramic/ceramic shell manufactured from ceramic fibers and ceramic matrix meeting the thermal and structural requirements of a tile used on a re-entry aerospace vehicle. In addition, a lightweight high temperature ceramic lower temperature base tile is used. The upper shell and lower tile are attached by means effective to withstand the extreme temperatures (3000 to 3200F) and stress conditions. The composite tile may include one or more layers of variable density rigid or flexible thermal insulation. The assembly of the overall tile is facilitated by two or more locking mechanisms on opposing sides of the overall tile assembly. The assembly may occur subsequent to the installation of the lower shell tile on the spacecraft structural skin.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Plucknett, K.P.; Becher, P.F.; Waters, S.B.

TiC/Ni{sub 3}Al composites were prepared using a simple melt-infiltration process, performed at either 1300 or 1400 C, with the Ni{sub 3}Al content varied over the range of 8--25 vol%. Densities >96% of theoretical were obtained for all composites. Four-point flexure strengths at 22 C increased as the Ni{sub 3}Al content increased (i.e., {approximately}1,100 MPa at 20 vol% Ni{sub 3}Al), with the highest strengths being observed for composites processed at 1300 C, because of reduced TiC grain size. Strengths at elevated temperatures increased with test temperature, up to {approximately}1,000 C. As with the yielding behavior of the Ni{sub 3}Al alloy used,more » a maximum in composite strength ({approximately}1,350 MPa) versus temperature was observed; this occurred at 950 C, which is {approximately}300 C above the yield maximum for the alloy. Extensive plastic strain was achieved in the composites even at high loading rates at 1,135 C, and the yield stress was dependent on the applied loading rate.« less

High temperature insulation materials for reradiative thermal protection systems

NASA Technical Reports Server (NTRS)

Hughes, T. A.

1972-01-01

Results are presented of a two year program to evaluate packaged thermal insulations for use under a metallic radiative TPS of a shuttle orbiter vehicle. Evaluations demonstrated their survival for up to 100 mission reuse cycles under shuttle acoustic and thermal loads with peak temperatures of 1000 F, 1800 F, 2000 F, 2200 F and 2500 F. The specimens were composed of low density refractory fiber felts, packaged in thin gage metal foils. In addition, studies were conducted on the venting requirements of the packages, salt spray resistance of the metal foils, and the thermal conductivity of many of the insulations as a function of temperature and ambient air pressure. Data is also presented on the radiant energy transport through insulations, and back-scattering coefficients were experimentally determined as a function of source temperature.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Guangming; Zhou, Zhangjian; Mo, Kun

An application of high-energy wide angle synchrotron X-ray diffraction to investigate the tensile deformation of 9Cr ferritic/martensitic (F/M) ODS steel is presented. With tensile loading and in-situ Xray exposure, the lattice strain development of matrix was determined. The lattice strain was found to decrease with increasing temperature, and the difference in Young's modulus of six different reflections at different temperatures reveals the temperature dependence of elastic anisotropy. The mean internal stress was calculated and compared with the applied stress, showing that the strengthening factor increased with increasing temperature, indicating that the oxide nanoparticles have a good strengthening impact at highmore » temperature. The dislocation density and character were also measured during tensile deformation. The dislocation density decreased with increasing of temperature due to the greater mobility of dislocation at high temperature. The dislocation character was determined by best-fit methods for different dislocation average contrasts with various levels of uncertainty. The results shows edge type dislocations dominate the plastic strain at room temperature (RT) and 300 C, while the screw type dislocations dominate at 600 C. The dominance of edge character in 9Cr F/M ODS steels at RT and 300 C is likely due to the pinning effect of nanoparticles for higher mobile edge dislocations when compared with screw dislocations, while the stronger screw type of dislocation structure at 600 C may be explained by the activated cross slip of screw segments.« less

Increasing of the endurance of polymeric construction materials with the multilevel hierarchical structure in the microwave electromagnetic field

NASA Astrophysics Data System (ADS)

Zlobina, I. V.; Muldasheva, G. K.; Bekrenev, N. V.

2016-11-01

Here are shown the results of the effect of the microwave electromagnetic field frequency 2450 MHz and the power density 4-5, 17-18, and 30-32 W/cm3 on properties of composite materials, reinforced plastics, and additive rubber. It is found that the microwave processing with the specific power 17-18 W/cm3 increases the duration of the operation of a rod carbon construction under a load by 1.5-4.5 times. The endurance of rods made of MBS plastics increases by 2-3 times under load. The yielding of sealing rubber after the treatment in the microwave electromagnetic field increases from 18 to 70% with the applied load. This increases the stability of the specimen characteristics after putting them at temperatures from -25 to +40°C.

Thermal shaft effects on load-carrying capacity of a fully coupled, variable-properties cryogenic journal bearing

NASA Technical Reports Server (NTRS)

Braun, M. J.; Wheeler, R. L., III; Hendricks, R. C.

1986-01-01

The purpose of this work was to perform a rather complete analysis for a cryogenic (oxygen) journal bearing. The Reynolds equation required coupling and simultaneous solution with the fluid energy equation. To correctly account for the changes in the fluid viscosity, the fluid energy equation was coupled with the shaft and bearing heat conduction energy equations. The effects of pressure and temperature on the density, viscosity, and load-carrying capacity were further discussed as analysis parameters, with respect to relative eccentricity and the angular velocity. The isothermal fluid case and the adiabatic fluid case represented the limiting boundaries. The discussion was further extrapolated to study the Sommerfeld number dependency on the fluid Nusselt number and its consequence on possible total loss of load-carrying capacity and/or seizure (catastrophic failure).

A charge-density-wave oscillator based on an integrated tantalum disulfide-boron nitride-graphene device operating at room temperature.

PubMed

Liu, Guanxiong; Debnath, Bishwajit; Pope, Timothy R; Salguero, Tina T; Lake, Roger K; Balandin, Alexander A

2016-10-01

The charge-density-wave (CDW) phase is a macroscopic quantum state consisting of a periodic modulation of the electronic charge density accompanied by a periodic distortion of the atomic lattice in quasi-1D or layered 2D metallic crystals. Several layered transition metal dichalcogenides, including 1T-TaSe 2 , 1T-TaS 2 and 1T-TiSe 2 exhibit unusually high transition temperatures to different CDW symmetry-reducing phases. These transitions can be affected by the environmental conditions, film thickness and applied electric bias. However, device applications of these intriguing systems at room temperature or their integration with other 2D materials have not been explored. Here, we demonstrate room-temperature current switching driven by a voltage-controlled phase transition between CDW states in films of 1T-TaS 2 less than 10 nm thick. We exploit the transition between the nearly commensurate and the incommensurate CDW phases, which has a transition temperature of 350 K and gives an abrupt change in current accompanied by hysteresis. An integrated graphene transistor provides a voltage-tunable, matched, low-resistance load enabling precise voltage control of the circuit. The 1T-TaS 2 film is capped with hexagonal boron nitride to provide protection from oxidation. The integration of these three disparate 2D materials in a way that exploits the unique properties of each yields a simple, miniaturized, voltage-controlled oscillator suitable for a variety of practical applications.

Critical fluid light scattering

NASA Technical Reports Server (NTRS)

Gammon, Robert W.

1988-01-01

The objective is to measure the decay rates of critical density fluctuations in a simple fluid (xenon) very near its liquid-vapor critical point using laser light scattering and photon correlation spectroscopy. Such experiments were severely limited on Earth by the presence of gravity which causes large density gradients in the sample when the compressibility diverges approaching the critical point. The goal is to measure fluctuation decay rates at least two decades closer to the critical point than is possible on earth, with a resolution of 3 microK. This will require loading the sample to 0.1 percent of the critical density and taking data as close as 100 microK to the critical temperature. The minimum mission time of 100 hours will allow a complete range of temperature points to be covered, limited by the thermal response of the sample. Other technical problems have to be addressed such as multiple scattering and the effect of wetting layers. The experiment entails measurement of the scattering intensity fluctuation decay rate at two angles for each temperature and simultaneously recording the scattering intensities and sample turbidity (from the transmission). The analyzed intensity and turbidity data gives the correlation length at each temperature and locates the critical temperature. The fluctuation decay rate data from these measurements will provide a severe test of the generalized hydrodynamic theories of transport coefficients in the critical regions. When compared to equivalent data from binary liquid critical mixtures they will test the universality of critical dynamics.

Improvement of mechanical strength of sintered Mo alloyed steel by optimization of sintering and cold-forging processes with densification

NASA Astrophysics Data System (ADS)

Kamakoshi, Y.; Shohji, I.; Inoue, Y.; Fukuda, S.

2017-10-01

Powder metallurgy (P/M) materials have been expected to be spread in automotive industry. Generally, since sintered materials using P/M ones contain many pores and voids, mechanical properties of them are inferior to those of conventional wrought materials. To improve mechanical properties of the sintered materials, densification is effective. The aim of this study is to improve mechanical strength of sintered Mo-alloyed steel by optimizing conditions in sintering and cold-forging processes. Mo-alloyed steel powder was compacted. Then, pre-sintering (PS) using a vacuum sintering furnace was conducted. Subsequently, coldforging (CF) by a backward extrusion method was conducted to the pre-sintered specimen. Moreover, the cold-forged specimen was heat treated by carburizing, tempering and quenching (CQT). Afterwards, mechanical properties were investigated. As a result, it was found that the density of the PS specimen is required to be more than 7.4 Mg/m3 to strengthen the specimen by heat treatment after CF. Furthermore, density and the microstructure of the PS specimen are most important factors to make the high density and strength material by CF. At the CF load of 1200 kN, the maximum density ratio reached approximately 99% by the use of the PS specimen with proper density and microstructure. At the CF load of 900 kN, although density ratio was high like more than 97.8%, transverse rupture strength decreased sharply. Since densification caused high shear stress and stress concentration in the surface layer, microcracks occurred by the damages of inter-particle sintered connection of the surface layer. On the contrary, in case of the CF load of 1200 kN, ultra-densification of the surface layer occurred by a sufficient plastic flow. Such sufficient compressed specimens regenerated the sintered connections by high temperature heat treatment and thus the high strength densified material was obtained. These processes can be applicable to near net shape manufacturing without surface machining.

Subchondral bone density distribution of the talus in clinically normal Labrador Retrievers.

PubMed

Dingemanse, W; Müller-Gerbl, M; Jonkers, I; Vander Sloten, J; van Bree, H; Gielen, I

2016-03-15

Bones continually adapt their morphology to their load bearing function. At the level of the subchondral bone, the density distribution is highly correlated with the loading distribution of the joint. Therefore, subchondral bone density distribution can be used to study joint biomechanics non-invasively. In addition physiological and pathological joint loading is an important aspect of orthopaedic disease, and research focusing on joint biomechanics will benefit veterinary orthopaedics. This study was conducted to evaluate density distribution in the subchondral bone of the canine talus, as a parameter reflecting the long-term joint loading in the tarsocrural joint. Two main density maxima were found, one proximally on the medial trochlear ridge and one distally on the lateral trochlear ridge. All joints showed very similar density distribution patterns and no significant differences were found in the localisation of the density maxima between left and right limbs and between dogs. Based on the density distribution the lateral trochlear ridge is most likely subjected to highest loads within the tarsocrural joint. The joint loading distribution is very similar between dogs of the same breed. In addition, the joint loading distribution supports previous suggestions of the important role of biomechanics in the development of OC lesions in the tarsus. Important benefits of computed tomographic osteoabsorptiometry (CTOAM), i.e. the possibility of in vivo imaging and temporal evaluation, make this technique a valuable addition to the field of veterinary orthopaedic research.

Real-Time Observation of Atomic Layer Deposition Inhibition: Metal Oxide Growth on Self-Assembled Alkanethiols

DOE PAGES

Avila, Jason R.; DeMarco, Erica J.; Emery, Jonathan D.; ...

2014-07-21

Through in-situ quartz crystal microbalance (QCM) monitoring we resolve the growth of a self-assembled monolayer (SAM) and subsequent metal oxide deposition with high resolution. Here, we introduce the fitting of mass deposited during each atomic layer deposition (ALD) cycle to an analytical island-growth model that enables quantification of growth inhibition, nucleation density, and the uninhibited ALD growth rate. A long-chain alkanethiol was self-assembled as a monolayer on gold-coated quartz crystals in order to investigate its effectiveness as a barrier to ALD. Compared to solution-loading, vapor-loading is observed to produce a SAM with equal or greater inhibition-ability in minutes vs. days.more » The metal oxide growth temperature and the choice of precursor also significantly affect the nucleation density, which ranges from 0.001 to 1 sites/nm 2. Finally, we observe a minimum 100 cycle inhibition of an oxide ALD process, ZnO, under moderately optimized conditions.« less

Cyclic Plasticity Constitutive Model for Uniaxial Ratcheting Behavior of AZ31B Magnesium Alloy

NASA Astrophysics Data System (ADS)

Lin, Y. C.; Liu, Zheng-Hua; Chen, Xiao-Min; Long, Zhi-Li

2015-05-01

Investigating the ratcheting behavior of magnesium alloys is significant for the structure's reliable design. The uniaxial ratcheting behavior of AZ31B magnesium alloy is studied by the asymmetric cyclic stress-controlled experiments at room temperature. A modified kinematic hardening model is established to describe the uniaxial ratcheting behavior of the studied alloy. In the modified model, the material parameter m i is improved as an exponential function of the maximum equivalent stress. The modified model can be used to predict the ratcheting strain evolution of the studied alloy under the single-step and multi-step asymmetric stress-controlled cyclic loadings. Additionally, due to the significant effect of twinning on the plastic deformation of magnesium alloy, the relationship between the material parameter m i and the linear density of twins is discussed. It is found that there is a linear relationship between the material parameter m i and the linear density of twins induced by the cyclic loadings.

Targeted Single-Site MOF Node Modification: Trivalent Metal Loading via Atomic Layer Deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, In Soo; Borycz, Joshua; Platero-Prats, Ana E.

Postsynthetic functionalization of metal organic frameworks (MOFs) enables the controlled, high-density incorporation of new atoms on a crystallographically precise framework. Leveraging the broad palette of known atomic layer deposition (ALD) chemistries, ALD in MOFs (AIM) is one such targeted approach to construct diverse, highly functional, few-atom clusters. We here demonstrate the saturating reaction of trimethylindium (InMe3) with the node hydroxyls and ligated water of NU-1000, which takes place without significant loss of MOF crystallinity or internal surface area. We computationally identify the elementary steps by which trimethylated trivalent metal compounds (ALD precursors) react with this Zr-based MOF node to generatemore » a uniform and well characterized new surface layer on the node itself, and we predict a final structure that is fully consistent with experimental X-ray pair distribution function (PDF) analysis. We further demonstrate tunable metal loading through controlled number density of the reactive handles (-OH and -OH2) achieved through node dehydration at elevated temperatures.« less

Mechanical properties of chemically modified Sansevieria trifasciata/natural rubber/high density polyethylene (STF/NR/HDPE) composites: Effect of silane coupling agent

NASA Astrophysics Data System (ADS)

Zakaria, Nurzam Ezdiani; Baharum, Azizah; Ahmad, Ishak

2018-04-01

The main objective of this research is to study the effects of chemical modification on the mechanical properties of treated Sansevieria trifasciata fiber/natural rubber/high density polyethylene (TSTF/NR/HDPE) composites. Processing of STF/NR/HDPE composites was done by using an internal mixer. The processing parameters used were 135°C for temperature and a mixing rotor speed of 55 rpm for 15 minutes. Filler loading was varied from 10% to 40% of STF and the fiber size used was 125 µm. The composite blends obtained then were pressed with a hot press machine to get test samples of 1 mm and 3 mm of thickness. Samples were evaluated via tensile tests, Izod impact test and scanning electron microscopy (SEM). Results showed that tensile strength and strain value decreased while tensile modulus increased when filler loading increased. Impact strength increased when filler loading increased and began to decrease after 10% of filler amount for treated composites. For untreated composites, impact strength began to decrease after 20% of filler loading. Chemical modification by using silane coupling agent has improved certain mechanical properties of the composites such as tensile strength, strain value and tensile modulus. Adding more amount of filler will also increase the viscosity and the stiffness of the materials.

Zeno: Critical Fluid Light Scattering Experiment

NASA Technical Reports Server (NTRS)

Gammon, Robert W.; Shaumeyer, J. N.; Briggs, Matthew E.; Boukari, Hacene; Gent, David A.; Wilkinson, R. Allen

1996-01-01

The Zeno (Critical Fluid Light Scattering) experiment is the culmination of a long history of critical fluid light scattering in liquid-vapor systems. The major limitation to making accurate measurements closer to the critical point was the density stratification which occurs in these extremely compressible fluids. Zeno was to determine the critical density fluctuation decay rates at a pair of supplementary angles in the temperature range 100 mK to 100 (mu)K from T(sub c) in a sample of xenon accurately loaded to the critical density. This paper gives some highlights from operating the instrument on two flights March, 1994 on STS-62 and February, 1996 on STS-75. More detail of the experiment Science Requirements, the personnel, apparatus, and results are displayed on the Web homepage at http://www.zeno.umd.edu.

Immobilization and bonding scheme of radioactive iodine-129 in silver tellurite glass

NASA Astrophysics Data System (ADS)

Lee, Cheong Won; Pyo, Jae-Young; Park, Hwan-Seo; Yang, Jae Hwan; Heo, Jong

2017-08-01

Silver tellurite glasses with melting temperatures < 700 °C were prepared to immobilize the 129I that normally volatilizes during high-temperature melting. Glasses have densities of 6.31 ± 0.1 g/cm3 and glass transition temperatures of 165 ± 3 °C that provide thermal stability at the disposal site. Iodine waste loading in glasses was as high as 12.64 wt% of all metallic elements and 11.21 wt% including oxygen. Normalized elemental releases obtained from the product consistency test were well below US regulation of 2 g/m2. Iodines are surrounded by four Ag+ ions forming [Ag4I]3+ units that are further connected to tellurite network through bonds with non-bridging oxygens.

An Evaluation of the HVAC Load Potential for Providing Load Balancing Service

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lu, Ning

This paper investigates the potential of providing aggregated intra-hour load balancing services using heating, ventilating, and air-conditioning (HVAC) systems. A direct-load control algorithm is presented. A temperature-priority-list method is used to dispatch the HVAC loads optimally to maintain consumer-desired indoor temperatures and load diversity. Realistic intra-hour load balancing signals were used to evaluate the operational characteristics of the HVAC load under different outdoor temperature profiles and different indoor temperature settings. The number of HVAC units needed is also investigated. Modeling results suggest that the number of HVACs needed to provide a {+-}1-MW load balancing service 24 hours a day variesmore » significantly with baseline settings, high and low temperature settings, and the outdoor temperatures. The results demonstrate that the intra-hour load balancing service provided by HVAC loads meet the performance requirements and can become a major source of revenue for load-serving entities where the smart grid infrastructure enables direct load control over the HAVC loads.« less

Electron temperature and heat load measurements in the COMPASS divertor using the new system of probes

NASA Astrophysics Data System (ADS)

Adamek, J.; Seidl, J.; Horacek, J.; Komm, M.; Eich, T.; Panek, R.; Cavalier, J.; Devitre, A.; Peterka, M.; Vondracek, P.; Stöckel, J.; Sestak, D.; Grover, O.; Bilkova, P.; Böhm, P.; Varju, J.; Havranek, A.; Weinzettl, V.; Lovell, J.; Dimitrova, M.; Mitosinkova, K.; Dejarnac, R.; Hron, M.; The COMPASS Team; The EUROfusion MST1 Team

2017-11-01

A new system of probes was recently installed in the divertor of tokamak COMPASS in order to investigate the ELM energy density with high spatial and temporal resolution. The new system consists of two arrays of rooftop-shaped Langmuir probes (LPs) used to measure the floating potential or the ion saturation current density and one array of Ball-pen probes (BPPs) used to measure the plasma potential with a spatial resolution of ~3.5 mm. The combination of floating BPPs and LPs yields the electron temperature with microsecond temporal resolution. We report on the design of the new divertor probe arrays and first results of electron temperature profile measurements in ELMy H-mode and L-mode. We also present comparative measurements of the parallel heat flux using the new probe arrays and fast infrared termography (IR) data during L-mode with excellent agreement between both techniques using a heat power transmission coefficient γ  =  7. The ELM energy density {{\\varepsilon }\\parallel } was measured during a set of NBI assisted ELMy H-mode discharges. The peak values of {{\\varepsilon }\\parallel } were compared with those predicted by model and with experimental data from JET, AUG and MAST with a good agreement.

Performance of Maybach 300-horsepower airplane engine

NASA Technical Reports Server (NTRS)

Sparrow, S W

1923-01-01

This report contains the results of a test made upon a Maybach Engine in the altitude chamber of the Bureau of Standards, where controlled conditions of temperature and pressure can be made the same as those of the desired altitude. The results of this test lead to the following conclusions: from the standpoint of thermal efficiency the full-load performance of the engine is excellent at densities corresponding to altitudes up to and including 15,000 feet. The brake mean effective pressure is rather low even at wide-open throttle. This tends to give a high weight per horsepower, in as much as the weight of many engine parts is governed by the size rather than the power of the engine. At part load the thermal efficiency of the engine is low. Judged on a basis of performance the engine's chief claim to interest would appear to lie in the carburetor design, which is largely responsible excellent full-load efficiency and for its poor part-load efficiency.

Laboratory experiments for understanding mechanical properties of fractured granite under supercritical conditions

NASA Astrophysics Data System (ADS)

Kitamura, M.; Takahashi, M.; Takagi, K.; Hirano, N.; Tsuchiya, N.

2017-12-01

To extract geothermal energy effectively and safely from magma and/or adjacent hot rock, we need to tackle many issues which require new technology development, such as a technique to control a risk from induced-earthquakes. On a development of induced-earthquake mitigation technology, it is required to understand roles of factors on occurrences of the induced-earthquake (e.g., strength, crack density, and fluid-rock reaction) and their intercorrelations (e.g., Asanuma et al., 2012). Our purpose of this series of experiments is to clarify a relationship between the rock strength and the crack density under supercritical conditions. We conducted triaxial deformation test on intact granite rock strength under high-temperature (250 - 750°C), high-pressure (104 MPa) condition at a constant load velocity (0.1 μm/sec) using a gas-rig at AIST. We used Oshima granite, which has initially <0.2 % of the porosity, 4.29±0.55 km/s in Vp (dry), and 2.49±0.19 km/s in Vs (dry). All experimental products showed the brittle feature having several oblique fracture surfaces, but the amount of stress drop became smaller at higher temperature. Young's modulus increased with decreasing the temperature from 32.3 GPa at 750°C to 57.4 GPa at 250°C. At 400 °C, the stress drop accelerated the deformation with 98 times faster velocity than that at load-point. In contrast, at 650°C and 750°C, the velocity during stress drop kept the same order of the load-point velocity. Therefore, the deformation mechanism may start to be changed from brittle to ductile when the temperature exceeds 650°C. Highly dense cracked granite specimens were formed by a rapid decompression test (RDT) using an autoclave settled at Tohoku University (Hirano et al., 2016JpGU), caused by a reduction of fluid pressure within 1-2 sec from vapor/supercritical state (10 - 48 MPa, 550 °C) to ambient pressure. The specimens after RDT show numerous microcracks on X-ray CT images. The RDT imposed the porosity increasing towards 3.75 % and Vp and Vs decreasing towards 1.37±0.52 km/s and 0.97±0.25 km/s. The Poisson's ratio shows the negative values in dry and 0.5 in wet. In the meeting, we will present results of triaxial deformation test on such cracked granites and show the relationship between strength and crack density under supercritical conditions.

Melt volume flow rate and melt flow rate of kenaf fibre reinforced Floreon/magnesium hydroxide biocomposites.

PubMed

Lee, C H; Sapuan, S M; Lee, J H; Hassan, M R

2016-01-01

A study of the melt volume flow rate (MVR) and the melt flow rate (MFR) of kenaf fibre (KF) reinforced Floreon (FLO) and magnesium hydroxide (MH) biocomposites under different temperatures (160-180 °C) and weight loadings (2.16, 5, 10 kg) is presented in this paper. FLO has the lowest values of MFR and MVR. The increment of the melt flow properties (MVR and MFR) has been found for KF or MH insertion due to the hydrolytic degradation of the polylactic acid in FLO. Deterioration of the entanglement density at high temperature, shear thinning and wall slip velocity were the possible causes for the higher melt flow properties. Increasing the KF loadings caused the higher melt flow properties while the higher MH contents created stronger bonding for higher macromolecular chain flow resistance, hence lower melt flow properties were recorded. However, the complicated melt flow behaviour of the KF reinforced FLO/MH biocomposites was found in this study. The high probability of KF-KF and KF-MH collisions was expected and there were more collisions for higher fibre and filler loading causing lower melt flow properties.

Soot loading in a generic gas turbine combustor

NASA Technical Reports Server (NTRS)

Eckerle, W. A.; Rosfjord, T. J.

1987-01-01

Variation in soot loading along the centerline of a generic gas turbine combustor was experimentally investigated. The 12.7-cm dia burner consisted of six sheet-metal louvers. Soot loading along the burner length was quantified by acquiring measurements first at the exit of the full-length combustor and then at upstream stations by sequential removal of liner louvers to shorten the burner length. Alteration of the flow field approaching removed louvers, maintaining a constant liner pressure drop. Burner exhaust flow was sampled at the burner centerline to determine soot mass concentration and smoke number. Characteristic particle size and number density, transmissivity of the exhaust flow, and local radiation from luminous soot particles in the exhaust flow were determined by optical techniques. Four test fuels were burned at three fuel-air ratios to determine fuel chemical property and flow temperature influences. Data were acquired at two combustor pressures. Particulate concentration data indicated a strong oxidation mechanism in the combustor secondary zone, though the oxidation was significantly affected by flow temperature. Soot production was directly related to fuel smoke point. Less soot production and lower secondary-zone oxidation rates were observed at reduced combustor pressure.

Heat of adsorption, adsorption stress, and optimal storage of methane in slit and cylindrical carbon pores predicted by classical density functional theory.

PubMed

Hlushak, Stepan

2018-01-03

Temperature, pressure and pore-size dependences of the heat of adsorption, adsorption stress, and adsorption capacity of methane in simple models of slit and cylindrical carbon pores are studied using classical density functional theory (CDFT) and grand-canonical Monte-Carlo (MC) simulation. Studied properties depend nontrivially on the bulk pressure and the size of the pores. Heat of adsorption increases with loading, but only for sufficiently narrow pores. While the increase is advantageous for gas storage applications, it is less significant for cylindrical pores than for slits. Adsorption stress and the average adsorbed fluid density show oscillatory dependence on the pore size and increase with bulk pressure. Slit pores exhibit larger amplitude of oscillations of the normal adsorption stress with pore size increase than cylindrical pores. However, the increase of the magnitude of the adsorption stress with bulk pressure increase is more significant for cylindrical than for slit pores. Adsorption stress appears to be negative for a wide range of pore sizes and external conditions. The pore size dependence of the average delivered density of the gas is analyzed and the optimal pore sizes for storage applications are estimated. The optimal width of slit pore appears to be almost independent of storage pressure at room temperature and pressures above 10 bar. Similarly to the case of slit pores, the optimal radius of cylindrical pores does not exhibit much dependence on the storage pressure above 15 bar. Both optimal width and optimal radii of slit and cylindrical pores increase as the temperature decreases. A comparison of the results of CDFT theory and MC simulations reveals subtle but important differences in the underlying fluid models employed by the approaches. The differences in the high-pressure behaviour between the hard-sphere 2-Yukawa and Lennard-Jones models of methane, employed by the CDFT and MC approaches, respectively, result in an overestimation of the heat of adsorption by the CDFT theory at higher loadings. However, both adsorption stress and adsorption capacity appear to be much less sensitive to the differences between the models and demonstrate excellent agreement between the theory and the computer experiment.

Estimating the stability of electrical conductivity of filled polymers under the influence of negative temperatures

NASA Astrophysics Data System (ADS)

Minakova, N. N.; Ushakov, V. Ya.

2017-12-01

One of the key problems in modern materials technology is synthesis of materials for electrotechnical devices capable of operating under severe conditions. Electrical and power engineering, in particular, demands for electrically conductive composite materials operating at high and low temperatures, various mechanical loads, electric fields, etc. Chaotic arrangement of electrically conductive component in the matrix and its structural and geometrical inhomogeneity can increase the local electric and thermal energy flux densities up to critical values even when their average values remain moderate. Elastomers filled with technical carbon being a promising component for electrotechnical devices was chosen as an object of study.

Temperature dependence of yields from multi-foil SPES target

NASA Astrophysics Data System (ADS)

Corradetti, S.; Biasetto, L.; Manzolaro, M.; Scarpa, D.; Andrighetto, A.; Carturan, S.; Prete, G.; Zanonato, P.; Stracener, D. W.

2011-10-01

The temperature dependence of neutron-rich isotope yields was studied within the framework of the HRIBF-SPES Radioactive Ion Beams (RIB) project. On-line release measurements of fission fragments from a uranium carbide target at ensuremath 1600 {}^{circ}C , ensuremath 1800 {}^{circ}C and ensuremath 2000 {}^{circ}C were performed at ORNL (USA). The fission reactions were induced by a 40MeV proton beam accelerated into a uranium carbide target coupled to a plasma ion source. The experiments allowed for tests of performance of the SPES multi-foil target prototype loaded with seven UC2/graphite discs (ratio C/ U = 4 with density about 4g/cm3.

Submillikelvin Dipolar Molecules in a Radio-Frequency Magneto-Optical Trap.

PubMed

Norrgard, E B; McCarron, D J; Steinecker, M H; Tarbutt, M R; DeMille, D

2016-02-12

We demonstrate a scheme for magneto-optically trapping strontium monofluoride (SrF) molecules at temperatures one order of magnitude lower and phase space densities 3 orders of magnitude higher than obtained previously with laser-cooled molecules. In our trap, optical dark states are destabilized by rapidly and synchronously reversing the trapping laser polarizations and the applied magnetic field gradient. The number of molecules and trap lifetime are also significantly improved from previous work by loading the trap with high laser power and then reducing the power for long-term trapping. With this procedure, temperatures as low as 400  μK are achieved.

Thermal shock induced oxidation of beryllium

NASA Astrophysics Data System (ADS)

Spilker, B.; Linke, J.; Pintsuk, G.; Wirtz, M.

2017-12-01

Beryllium has been chosen as a plasma facing material for the first wall of the experimental fusion reactor ITER, mainly because of its low atomic number and oxygen getter capabilities, which are favorable for a high plasma performance. While the steady state operational temperature of 250 °C has no deteriorating effect on the beryllium surface, transient plasma events can deposit power densities of up to 1 GW m-2 on the beryllium armor tiles. Previous research has shown that the oxidation of beryllium can occur under these thermal shock events. In the present study, S-65 grade beryllium specimens were exposed to 100 thermal shocks with an absorbed power density of 0.6 GW m-2 and a pulse duration of 1 ms, leading to a peak surface temperature of ˜800 °C. The induced surface morphology changes were compared to a steady state heated specimen at the same surface temperature with a holding time of 150 s. As a result, a pitting structure with an average pit diameter of ˜0.45 μm was observed on the thermal shock loaded surface, which was caused by beryllium oxide grain nucleation and subsequent erosion of the weakly bound beryllium oxide particles. In contrast, the steady state heated surface exhibited a more homogeneous beryllium oxide layer featuring small pits with diameters of tens of nm and showed the beryllium oxide grain nucleation in a beginning stage. The experiment demonstrated that thermal shock loading conditions can significantly accelerate the beryllium oxide grain nucleation. The resulting surface morphology change can potentially alter the fusion application relevant erosion, absorption, and retention characteristics of beryllium.

Thermophilic-anaerobic digestion to produce class A biosolids: initial full-scale studies at Hyperion Treatment Plant.

PubMed

Iranpour, R; Cox, H H J; Oh, S; Fan, S; Kearney, R J; Abkian, V; Haug, R T

2006-02-01

The highest quality of biosolids is called exceptional quality. To qualify for this classification, biosolids must comply with three criteria: (1) metal concentrations, (2) vector-attraction reduction, and (3) the Class A pathogen-density requirements. The City of Los Angeles Bureau of Sanitation Hyperion Treatment Plant (HTP) (Playa del Rey, California) meets the first two requirements. Thus, the objective of this study was to ensure that HTP's biosolids production would meet the Class A pathogen-reduction requirements following the time-temperature regimen for batch processing (U.S. EPA, 1993; Subsection 32, Alternative 1). Because regulations require the pathogen limits to be met at the last point of plant control, biosolids sampling was not limited to immediately after the digesters, i.e., the digester outflows. The sampling extended to several locations in HTP's postdigestion train, in particular, the last points of plant control, i.e., the truck loading facility and the farm for land application. A two-stage, thermophilic-continuous-batch process, consisting of a battery of six egg-shaped digesters, was established in late 2001 for phase I of this study and modified in early 2002 for phase II. As the biosolids were discharged from the second-stage digesters, the Salmonella sp. (pathogen) and fecal-coliform (indicator) densities were well below the limits for Class A biosolids, even though the second-stage-digester temperatures were a few degrees below the temperature required by Alternative 1. Salmonella sp. densities remained below the Class A limit at all postdigestion sampling locations. Fecal-coliform densities were also below the Class A limit at postdigestion-sampling locations, except the truck-loading facility (phases I and II) and the farm for final use of the biosolids (phase II). Although federal regulations require one of the limits for either fecal coliforms or Salmonella sp. to be met, local regulations in Kern County, California, where the biosolids are land-applied, require compliance with both bacterial limits. Additional work identified dewatering, cooling of biosolids after the dewatering centrifuges, and contamination as possible factors in the rise in density of fecal coliforms. These results provided the basis for the full conversion of HTP to the Los Angeles continuous-batch, thermophilic-anaerobic-digestion process. During later phases of testing, this process was demonstrated to produce fully disinfected biosolids at the farm for land application.

Electroluminescence of hot electrons in AlGaN/GaN high-electron-mobility transistors under radio frequency operation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brazzini, Tommaso, E-mail: tommaso.brazzini@bristol.ac.uk; Sun, Huarui; Uren, Michael J.

2015-05-25

Hot electrons in AlGaN/GaN high electron mobility transistors are studied during radio frequency (RF) and DC operation by means of electroluminescence (EL) microscopy and spectroscopy. The measured EL intensity is decreased under RF operation compared to DC at the same average current, indicating a lower hot electron density. This is explained by averaging the DC EL intensity over the measured load line used in RF measurements, giving reasonable agreement. In addition, the hot electron temperature is lower by up to 15% under RF compared to DC, again at least partially explainable by the weighted averaging along the specific load line.more » However, peak electron temperature under RF occurs at high V{sub DS} and low I{sub DS} where EL is insignificant suggesting that any wear-out differences between RF and DC stress of the devices will depend on the balance between hot-carrier and field driven degradation mechanisms.« less

Venus Surface Power and Cooling System Design

NASA Technical Reports Server (NTRS)

Landis, Geoffrey A.; Mellott, Kenneth D.

2004-01-01

A radioisotope power and cooling system is designed to provide electrical power for the a probe operating on the surface of Venus. Most foreseeable electronics devices and sensors simply cannot operate at the 450 C ambient surface temperature of Venus. Because the mission duration is substantially long and the use of thermal mass to maintain an operable temperature range is likely impractical, some type of active refrigeration may be required to keep certain components at a temperature below ambient. The fundamental cooling requirements are comprised of the cold sink temperature, the hot sink temperature, and the amount of heat to be removed. In this instance, it is anticipated that electronics would have a nominal operating temperature of 300 C. Due to the highly thermal convective nature of the high-density atmosphere, the hot sink temperature was assumed to be 50 C, which provided a 500 C temperature of the cooler's heat rejecter to the ambient atmosphere. The majority of the heat load on the cooler is from the high temperature ambient surface environment on Venus. Assuming 5 cm radial thickness of ceramic blanket insulation, the ambient heat load was estimated at approximately 77 watts. With an estimated quantity of 10 watts of heat generation from electronics and sensors, and to accommodate some level of uncertainty, the total heat load requirement was rounded up to an even 100 watts. For the radioisotope Stirling power converter configuration designed, the Sage model predicts a thermodynamic power output capacity of 478.1 watts, which slightly exceeds the required 469.1 watts. The hot sink temperature is 1200 C, and the cold sink temperature is 500 C. The required heat input is 1740 watts. This gives a thermodynamic efficiency of 27.48 %. The maximum theoretically obtainable efficiency is 47.52 %. It is estimated that the mechanical efficiency of the power converter design is on the order of 85 %, based on experimental measurements taken from 500 watt power class, laboratory-tested Stirling engines at GRC. The overall efficiency is calculated to be 23.36 %. The mass of the power converter is estimated at approximately 21.6 kg.

Effects of gasoline reactivity and ethanol content on boosted premixed and partially stratified low-temperature gasoline combustion (LTGC)

DOE PAGES

Dec, John E.; Yang, Yi; Ji, Chunsheng; ...

2015-04-14

Low-temperature gasoline combustion (LTGC), based on the compression ignition of a premixed or partially premixed dilute charge, can provide thermal efficiencies (TE) and maximum loads comparable to those of turbo-charged diesel engines, and ultra-low NOx and particulate emissions. Intake boosting is key to achieving high loads with dilute combustion, and it also enhances the fuel's autoignition reactivity, reducing the required intake heating or hot residuals. These effects have the advantages of increasing TE and charge density, allowing greater timing retard with good stability, and making the fuel Φ- sensitive so that partial fuel stratification (PFS) can be applied for highermore » loads and further TE improvements. However, at high boost the autoignition reactivity enhancement can become excessive, and substantial amounts of EGR are required to prevent overly advanced combustion. Accordingly, an experimental investigation has been conducted to determine how the tradeoff between the effects of intake boost varies with fuel-type and its impact on load range and TE. Five fuels are investigated: a conventional AKI=87 petroleum-based gasoline (E0), and blends of 10 and 20% ethanol with this gasoline to reduce its reactivity enhancement with boost (E10 and E20). Furthermore, a second zero-ethanol gasoline with AKI=93 (matching that of E20) was also investigated (CF-E0), and some neat ethanol data are also reported.« less

Fighting Fire with Fire: Modeling the Datacenter-Scale Effects of Targeted Superlattice Thermal Management

DTIC Science & Technology

2011-01-01

we propose that hot-spot mitigation using thermoelectric coolers can be used as a power management mechanism to allow global coolers to be provi...sioned for a better worst case temperature leading to substan- tial savings in cooling power. In order to quantify the potential power savings from us- ing...energy density inside a processor to maximally tolerable levels, modern microprocessors make ex- tensive use of hardware structures such as the load

Hydrometallurgical process for recovery of cobalt from waste cathodic active material generated during manufacturing of lithium ion batteries

NASA Astrophysics Data System (ADS)

Swain, Basudev; Jeong, Jinki; Lee, Jae-chun; Lee, Gae-Ho; Sohn, Jeong-Soo

The paper presents a new leaching-solvent extraction hydrometallurgical process for the recovery of a pure and marketable form of cobalt sulfate solution from waste cathodic active material generated during manufacturing of lithium ion batteries (LIBs). Leaching of the waste was carried out as a function of the leachant H 2SO 4 concentration, temperature, pulp density and reductant H 2O 2 concentration. The 93% of cobalt and 94% of lithium were leached at suitable optimum conditions of pulp density: 100 g L -1, 2 M H 2SO 4, 5 vol.% of H 2O 2, with a leaching time 30 min and a temperature 75 °C. In subsequent the solvent extraction study, 85.42% of the cobalt was recovered using 1.5 M Cyanex 272 as an extractant at an O/A ratio of 1.6 from the leach liquor at pH 5.00. The rest of the cobalt was totally recovered from the raffinate using 0.5 M of Cyanex 272 and an O/A ratio of 1, and a feed pH of 5.35. Then the co-extracted lithium was scrubbed from the cobalt-loaded organic using 0.1 M Na 2CO 3. Finally, the cobalt sulfate solution with a purity 99.99% was obtained from the cobalt-loaded organic by stripping with H 2SO 4.

Study on influence of Surface roughness of Ni-Al2O3 nano composite coating and evaluation of wear characteristics

NASA Astrophysics Data System (ADS)

Raghavendra, C. R.; Basavarajappa, S.; Sogalad, Irappa

2018-02-01

Electrodeposition is one of the most technologically feasible and economically superior techniques for producing metallic coating. The advancement in the application of nano particles has grabbed the attention in all fields of engineering. In this present study an attempt has been made on the Ni-Al2O3nano particle composite coating on aluminium substrate by electrodeposition process. The aluminium surface requires a specific pre-treatment for better adherence of coating. In light of this a thin zinc layer is coated on the aluminium substrate by electroless process. In addition to this surface roughness is an important parameter for any coating method and material. In this work Ni-Al2O3 composite coating were successfully coated by varying the process parameters such as bath temperature, current density and particle loading. The experimentation was performed using central composite design based 20 trials of experiments. The effect of process parameters and surface roughness before and after coating is analyzed on wear rate and coating thickness. The results shown a better wear resistance of Ni-Al2O3 composite electrodeposited coating compared to Ni coating. The particle loading and interaction effect of current density with temperature has greater significant effect on wear rate. The surface roughness is significantly affected the wear behaviour and thickness of coating.

Coupling continuum dislocation transport with crystal plasticity for application to shock loading conditions

DOE PAGES

Luscher, Darby Jon; Mayeur, Jason Rhea; Mourad, Hashem Mohamed; ...

2015-08-05

Here, we have developed a multi-physics modeling approach that couples continuum dislocation transport, nonlinear thermoelasticity, crystal plasticity, and consistent internal stress and deformation fields to simulate the single-crystal response of materials under extreme dynamic conditions. Dislocation transport is modeled by enforcing dislocation conservation at a slip-system level through the solution of advection-diffusion equations. Nonlinear thermoelasticity provides a thermodynamically consistent equation of state to relate stress (including pressure), temperature, energy densities, and dissipation. Crystal plasticity is coupled to dislocation transport via Orowan's expression where the constitutive description makes use of recent advances in dislocation velocity theories applicable under extreme loading conditions.more » The configuration of geometrically necessary dislocation density gives rise to an internal stress field that can either inhibit or accentuate the flow of dislocations. An internal strain field associated with the internal stress field contributes to the kinematic decomposition of the overall deformation. The paper describes each theoretical component of the framework, key aspects of the constitutive theory, and some details of a one-dimensional implementation. Results from single-crystal copper plate impact simulations are discussed in order to highlight the role of dislocation transport and pile-up in shock loading regimes. The main conclusions of the paper reinforce the utility of the modeling approach to shock problems.« less

Optimization of properties and operating parameters of a passive DMFC mini-stack at ambient temperature

NASA Astrophysics Data System (ADS)

Baglio, V.; Stassi, A.; Matera, F. V.; Di Blasi, A.; Antonucci, V.; Aricò, A. S.

An investigation of properties and operating parameters of a passive DMFC monopolar mini-stack, such as catalyst loading and methanol concentration, was carried out. From this analysis, it was derived that a proper Pt loading is necessary to achieve the best compromise between electrode thickness and number of catalytic sites for the anode and cathode reactions to occur at suitable rates. Methanol concentrations ranging from 1 M up to 10 M and an air-breathing operation mode were investigated. A maximum power of 225 mW was obtained at ambient conditions for a three-cell stack, with an active single cell area of 4 cm 2, corresponding to a power density of about 20 mW cm -2.

Estimates of crystalline LiF thermal conductivity at high temperature and pressure by a Green-Kubo method

DOE PAGES

Jones, R. E.; Ward, D. K.

2016-07-18

Here, given the unique optical properties of LiF, it is often used as an observation window in high-temperature and -pressure experiments; hence, estimates of its transmission properties are necessary to interpret observations. Since direct measurements of the thermal conductivity of LiF at the appropriate conditions are difficult, we resort to molecular simulation methods. Using an empirical potential validated against ab initio phonon density of states, we estimate the thermal conductivity of LiF at high temperatures (1000–4000 K) and pressures (100–400 GPa) with the Green-Kubo method. We also compare these estimates to those derived directly from ab initio data. To ascertainmore » the correct phase of LiF at these extreme conditions, we calculate the (relative) phase stability of the B1 and B2 structures using a quasiharmonic ab initio model of the free energy. We also estimate the thermal conductivity of LiF in an uniaxial loading state that emulates initial stages of compression in high-stress ramp loading experiments and show the degree of anisotropy induced in the conductivity due to deformation.« less

Assessment of thermal comfort level at pedestrian level in high-density urban area of Hong Kong

NASA Astrophysics Data System (ADS)

Ma, J.; Ng, E.; Yuan, C.; Lai, A.

2015-12-01

Hong Kong is a subtropical city which is very hot and humid in the summer. Pedestrians commonly experience thermal discomfort. Various studies have shown that the tall bulky buildings intensify the urban heat island effect and reduce urban air ventilation. However, relatively few studies have focused on modeling the thermal load at pedestrian level (~ 2 m). This study assesses the thermal comfort level, quantified by PET (Physiological Equivalent Temperature), using a GIS - based simulation approach. A thermal comfort level map shows the PET value of a typical summer afternoon in the high building density area. For example, the averaged PET in Sheung Wan is about 41 degree Celsius in a clear day and 38 degree Celsius in a cloudy day. This map shows where the walkways, colonnades, and greening is most needed. In addition, given a start point, a end point, and weather data, we generate the most comfort walking routes weighted by the PET. In the simulation, shortwave irradiance is calculated using the topographic radiation model (Fu and Rich, 1999) under various cloud cover scenarios; longwave irradiance is calculated based the radiative transfer equation (Swinbank, 1963). Combining these two factors, Tmrt (mean radiant temperature) is solved. And in some cases, the Tmrt differ more than 40 degree Celsius between areas under the sun and under the shades. Considering thermal load and wind information, we found that shading from buildings has stronger effect on PET than poor air ventilation resulted from dense buildings. We predict that pedestrians would feel more comfortable (lower PET) in a hot summer afternoon when walking in the higher building density area.

Prediction of Long-Term Strength of Thermoplastic Composites Using Time-Temperature Superposition. Degree awarded by Texas A&M Univ., May 1998

NASA Technical Reports Server (NTRS)

Reeder, James R.

2002-01-01

Accelerated tests for composite failure were investigated. Constant ramp transverse strength tests on thermoplastic composite specimens were conducted at four temperatures from 300 F to 450 F and five duration times from 0.5 sec to 24 hrs. Up to 400 F, the time-temperature-superposition method produces a master curve allowing strength at longer times to be estimated from strength tests conducted over shorter times but at higher temperatures. The shift factors derived from compliance tests applied well to the strength data. To explain why strength behaved similar to compliance, a viscoelastic fracture model was investigated based on the hypothesis that the work of fracture for crack initiation at some critical flaw remains constant with time and temperature. The model, which used compliance as input, was found to fit the strength data only if the critical fracture energy was allowed to vary with stress rate. Fracture tests using double cantilever beam specimens were conducted from 300 F to 450 F over time scales similar to the strength study. The toughness data showed a significant change with loading rate, less variation with temperature, did not form a master curve, and could not be correlated with the fracture model. Since the fracture model did not fit the fracture data, an alternative explanation based on the dilatational strain energy density was proposed. However the usefulness of this model is severely limited because it relies on a critical parameter which varies with loading rate.

Burner liner thermal-structural load modeling

NASA Technical Reports Server (NTRS)

Maffeo, R.

1986-01-01

The software package Transfer Analysis Code to Interface Thermal/Structural Problems (TRANCITS) was developed. The TRANCITS code is used to interface temperature data between thermal and structural analytical models. The use of this transfer module allows the heat transfer analyst to select the thermal mesh density and thermal analysis code best suited to solve the thermal problem and gives the same freedoms to the stress analyst, without the efficiency penalties associated with common meshes and the accuracy penalties associated with the manual transfer of thermal data.

Studying the compactibility of the VT22 high-strength alloy powder obtained by the PREP method

NASA Astrophysics Data System (ADS)

Kryuchkov, D. I.; Berezin, I. M.; Nesterenko, A. V.; Zalazinsky, A. G.; Vichuzhanin, D. I.

2017-12-01

Compression curves are plotted for VT22 high-strength alloy powder under conditions of uniaxial compression at room temperature. The density of the compacted briquette at the loading and unloading stages is determined. It is demonstrated that strong interparticle bonds are formed in the area of the action of shear deformation. The results are supposed to be used to identify the flow model of the material studied and to perform the subsequent numerical modeling of the compaction process.

High temperature polyimide foams for shuttle upper surface thermal insulation

NASA Technical Reports Server (NTRS)

Ball, G. L., III; Leffingwell, J. W.; Salyer, I. O.; Werkmeister, D. W.

1974-01-01

Polyimide foams developed by Monsanto Company were examined for use as upper surface space shuttle thermal insulation. It was found that postcured polyimide foams having a density of 64 kg/cu m (4 lb/cu ft) had acceptable physical properties up to and exceeding 700 K (800 F). Physical tests included cyclic heating and cooling in vacuum, weight and dimensional stability, mechanical strength and impact resistance, acoustic loading and thermal conductivity. Molding and newly developed postcuring procedures were defined.

Solid polymer electrolyte (SPE) fuel cell technology program, phase 2/2A. [testing and evaluations

NASA Technical Reports Server (NTRS)

1976-01-01

Test evaluations were performed on a fabricated single solid polymer electrolyte cell unit. The cell operated at increased current density and at higher performance levels. This improved performance was obtained through a combination of increased temperature, increased reactant pressures, improved activation techniques and improved thermal control over the baseline cell configuration. The cell demonstrated a higher acid content membrane which resulted in increased performance. Reduced catalyst loading and low cost membrane development showed encouraging results.

High precision Hugoniot measurements on statically pre-compressed fluid helium

NASA Astrophysics Data System (ADS)

Seagle, Christopher T.; Reinhart, William D.; Lopez, Andrew J.; Hickman, Randy J.; Thornhill, Tom F.

2016-09-01

The capability for statically pre-compressing fluid targets for Hugoniot measurements utilizing gas gun driven flyer plates has been developed. Pre-compression expands the capability for initial condition control, allowing access to thermodynamic states off the principal Hugoniot. Absolute Hugoniot measurements with an uncertainty less than 3% on density and pressure were obtained on statically pre-compressed fluid helium utilizing a two stage light gas gun. Helium is highly compressible; the locus of shock states resulting from dynamic loading of an initially compressed sample at room temperature is significantly denser than the cryogenic fluid Hugoniot even for relatively modest (0.27-0.38 GPa) initial pressures. The dynamic response of pre-compressed helium in the initial density range of 0.21-0.25 g/cm3 at ambient temperature may be described by a linear shock velocity (us) and particle velocity (up) relationship: us = C0 + sup, with C0 = 1.44 ± 0.14 km/s and s = 1.344 ± 0.025.

Superalloy Foams for Aeroshell Applications

NASA Technical Reports Server (NTRS)

Gayda, John; Padula, Santo, II

2001-01-01

Current thermal protection systems for reentry from space, such as that employed on the space shuttle, rely on ceramic tiles with ultra-low conductivity. These materials provide excellent thermal protection but are extremely fragile, easily degraded by environmental attack, and carry no structural loads. Future thermal protection systems being proposed in NASAs MITAS Program will attempt to combine thermal protection with improved durability and structural capability without significant increases in vehicle weight. This may be accomplished by combining several materials in a layered structure to obtain the desired function for aeroshell applications. One class of materials being considered for inclusion in this concept are high temperature metal foam. The objective of this paper was to fabricate low density, superalloy foams and conduct limited testing to evaluate their thermal and structural capabilities. Superalloys were chosen for evaluation as they possesses good strength and excellent environmental endurance over a wide range of temperatures. Utilizing superalloys as low density foams, with porosity contents greater than 90%, minimizes weight and thermal conductivity.

Pressure cell for investigations of solid-liquid interfaces by neutron reflectivity.

PubMed

Kreuzer, Martin; Kaltofen, Thomas; Steitz, Roland; Zehnder, Beat H; Dahint, Reiner

2011-02-01

We describe an apparatus for measuring scattering length density and structure of molecular layers at planar solid-liquid interfaces under high hydrostatic pressure conditions. The device is designed for in situ characterizations utilizing neutron reflectometry in the pressure range 0.1-100 MPa at temperatures between 5 and 60 °C. The pressure cell is constructed such that stratified molecular layers on crystalline substrates of silicon, quartz, or sapphire with a surface area of 28 cm(2) can be investigated against noncorrosive liquid phases. The large substrate surface area enables reflectivity to be measured down to 10(-5) (without background correction) and thus facilitates determination of the scattering length density profile across the interface as a function of applied load. Our current interest is on the stability of oligolamellar lipid coatings on silicon surfaces against aqueous phases as a function of applied hydrostatic pressure and temperature but the device can also be employed to probe the structure of any other solid-liquid interface.

Preparation and Dynamic Mechanical Properties at Elevated Temperatures of a Tungsten/Glass Composite

NASA Astrophysics Data System (ADS)

Gao, Chong; Wang, Yingchun; Ma, Xueya; Liu, Keyi; Wang, Yubing; Li, Shukui; Cheng, Xingwang

2018-03-01

Experiments were conducted to prepare a borosilicate glass matrix composite containing 50 vol.% tungsten and examine its dynamic compressive behavior at elevated temperatures in the range of 450-775 °C. The results show that the homogenous microstructure of the tungsten/glass composite with relative density of 97% can be obtained by hot-pressing sintering at 800 °C for 1 h under pressure of 30 MPa. Dynamic compressive testing was carried out by a separate Hopkinson pressure bar system with a synchronous device. The results show that the peak stress decreases and the composite transforms from brittle to ductile in nature with testing temperature increasing from 450 to 750 °C. The brittle-ductile transition temperature is about 500 °C. Over 775 °C, the composite loses load-bearing capacity totally because of the excessive softening of the glass phase. In addition, the deformation and failure mechanism were analyzed.

Mass loss of a TEOS-coated, reinforced carbon-carbon composite subjected to a simulted shuttle entry environment

NASA Technical Reports Server (NTRS)

Stroud, C. W.; Rummler, D. R.

1980-01-01

Coated, reinforced carbon-carbon (RCC) is used for the leading edges of the space shuttle. The mass loss characteristics of RCC specimens coated with tetraethyl orthosilicate (TEOS) were determine for conditions which simulated the environment expected at the lug attachment area of the leading edge. Mission simulation included simultaneous application of load, temperature, and oxygen partial pressure. Maximum specimen temperature was 900 K (1160 F). Specimens were exposed for up to 80 simulated missions. Stress levels up to 6.8 MPa (980 psi) did not significantly affect the mass loss characteristics of the TEOS-coated RCC material. Mass loss was correlated with the bulk density of the specimens.

Potential efficiencies of open- and closed-cycle CO, supersonic, electric-discharge lasers

NASA Technical Reports Server (NTRS)

Monson, D. J.

1976-01-01

Computed open- and closed-cycle system efficiencies (laser power output divided by electrical power input) are presented for a CW carbon monoxide, supersonic, electric-discharge laser. Closed-system results include the compressor power required to overcome stagnation pressure losses due to supersonic heat addition and a supersonic diffuser. The paper shows the effect on the system efficiencies of varying several important parameters. These parameters include: gas mixture, gas temperature, gas total temperature, gas density, total discharge energy loading, discharge efficiency, saturated gain coefficient, optical cavity size and location with respect to the discharge, and supersonic diffuser efficiency. Maximum open-cycle efficiency of 80-90% is predicted; the best closed-cycle result is 60-70%.

The role of different ion species in the cessation of magnetic reconnection

NASA Astrophysics Data System (ADS)

Tenfjord, P.; Hesse, M.

2017-12-01

Ions of ionospheric, plasmaspheric, or plasma mantle origin mass-load the source plasma resulting in the reduction of the Alfvén velocity and reconnection rate. Among other parameters, the mass-loading effect is impacted by the gyroradii of the cold ions, which are much smaller than those of the hotter ions. Consequently the cold ions are magnetized down to smaller spatial scales compared to the hotter population. It is therefore likely that the magnitude and timescales of reconnection rate reductions are impacted not only by the mass density in the inflow region, but also by the nature of the ion species and their temperatures. Using Particle-In-Cell (PIC) simulations with time-dependent inflow of different ion species and different densities, we investigate possible mechanisms for the cessation of magnetic reconnection. We describe how protons and higher mass ions get captured by the reconnection process, and whether and when they slow down the reconnection process. Furthermore, we investigate in detail how the electron diffusion region responds to the rate changes imposed by varying inflow populations.

Targeted Single-Site MOF Node Modification: Trivalent Metal Loading via Atomic Layer Deposition

DOE PAGES

Kim, In Soo; Borycz, Joshua; Platero-Prats, Ana E.; ...

2015-07-02

Postsynthetic functionalization of metal organic frameworks (MOFs) enables the controlled, high-density incorporation of new atoms on a crystallographically precise framework. Leveraging the broad palette of known atomic layer deposition (ALD) chemistries, ALD in MOFs (AIM) is one such targeted approach to construct diverse, highly functional, few-atom clusters. In this paper, we demonstrate the saturating reaction of trimethylindium (InMe 3) with the node hydroxyls and ligated water of NU-1000, which takes place without significant loss of MOF crystallinity or internal surface area. We computationally identify the elementary steps by which trimethylated trivalent metal compounds (ALD precursors) react with this Zr-based MOFmore » node to generate a uniform and well characterized new surface layer on the node itself, and we predict a final structure that is fully consistent with experimental X-ray pair distribution function (PDF) analysis. Finally, we further demonstrate tunable metal loading through controlled number density of the reactive handles (–OH and –OH 2) achieved through node dehydration at elevated temperatures.« less

Targeted Single-Site MOF Node Modification: Trivalent Metal Loading via Atomic Layer Deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, In Soo; Borycz, Joshua; Platero-Prats, Ana E.

Postsynthetic functionalization of metal organic frameworks (MOFs) enables the controlled, high-density incorporation of new atoms on a crystallographically precise framework. Leveraging the broad palette of known atomic layer deposition (ALD) chemistries, ALD in MOFs (AIM) is one such targeted approach to construct diverse, highly functional, few-atom clusters. In this paper, we demonstrate the saturating reaction of trimethylindium (InMe 3) with the node hydroxyls and ligated water of NU-1000, which takes place without significant loss of MOF crystallinity or internal surface area. We computationally identify the elementary steps by which trimethylated trivalent metal compounds (ALD precursors) react with this Zr-based MOFmore » node to generate a uniform and well characterized new surface layer on the node itself, and we predict a final structure that is fully consistent with experimental X-ray pair distribution function (PDF) analysis. Finally, we further demonstrate tunable metal loading through controlled number density of the reactive handles (–OH and –OH 2) achieved through node dehydration at elevated temperatures.« less

Delaying microbial proliferation in freshly peeled shallots by active packaging incorporating ethanol vapour-controlled release sachets and low storage temperature.

PubMed

Utto, Weerawate; Preutikul, Rittirong; Malila, Patcharee; Noomhorm, Athapol; Bronlund, John E

2018-03-01

This research was conducted to investigate effects of ethanol vapour released in active packaging and storage temperatures on the quality of freshly peeled shallots. The package tested was a solid polypropylene tray incorporating an ethanol vapour-controlled release sachet. The sachet was made of an aluminium foil film on one side and either low-density polyethylene or nylon/polyethylene on the other. Individual sachets contained silica gel adsorbent as the carrier pre-loaded with ethanol. One sachet was placed in each tray containing the peeled shallots and the tray was heat sealed with the low-density polyethylene film lid. Packages were stored at either 10 or 25 ℃ for 10 d. Trays containing only peeled shallots were designated as controls. High storage temperature stimulated quality changes in the shallots. Although ethanol vapour accumulated in the active package headspace, the extent to which ethanol concentrations increased within the shallots was not significantly different from that in the control packages. Microbial proliferation in terms of yeast and mould counts could be delayed through a combination of 10 ℃ and ethanol vapour released from the low-density polyethylene sachet. The ethanol vapour accumulated in the packages did not have a significant effect on mass loss, firmness, and colour changes in the peeled shallots, or on the concentrations of oxygen and carbon dioxide in the packages.

Potential of energy harvesting in barium titanate based laminates from room temperature to cryogenic/high temperatures: measurements and linking phase field and finite element simulations

NASA Astrophysics Data System (ADS)

Narita, Fumio; Fox, Marina; Mori, Kotaro; Takeuchi, Hiroki; Kobayashi, Takuya; Omote, Kenji

2017-11-01

This paper studies the energy harvesting characteristics of piezoelectric laminates consisting of barium titanate (BaTiO3) and copper (Cu) from room temperature to cryogenic/high temperatures both experimentally and numerically. First, the output voltages of the piezoelectric BaTiO3/Cu laminates were measured from room temperature to a cryogenic temperature (77 K). The output power was evaluated for various values of load resistance. The results showed that the maximum output power density is approximately 2240 nW cm-3. The output voltages of the BaTiO3/Cu laminates were also measured from room temperature to a higher temperature (333 K). To discuss the output voltages of the BaTiO3/Cu laminates due to temperature changes, phase field and finite element simulations were combined. A phase field model for grain growth was used to generate grain structures. The phase field model was then employed for BaTiO3 polycrystals, coupled with the time-dependent Ginzburg-Landau theory and the oxygen vacancies diffusion, to calculate the temperature-dependent piezoelectric coefficient and permittivity. Using these properties, the output voltages of the BaTiO3/Cu laminates from room temperature to both 77 K and 333 K were analyzed by three dimensional finite element methods, and the results are presented for several grain sizes and oxygen vacancy densities. It was found that electricity in the BaTiO3 ceramic layer is generated not only through the piezoelectric effect caused by a thermally induced bending stress but also by the temperature dependence of the BaTiO3 piezoelectric coefficient and permittivity.

Modeling and Measurement of Sustained Loading and Temperature-Dependent Deformation of Carbon Fiber-Reinforced Polymer Bonded to Concrete.

PubMed

Jeong, Yoseok; Lee, Jaeha; Kim, WooSeok

2015-01-29

This paper aims at presenting the effects of short-term sustained load and temperature on time-dependent deformation of carbon fiber-reinforced polymer (CFRP) bonded to concrete and pull-off strength at room temperature after the sustained loading period. The approach involves experimental and numerical analysis. Single-lap shear specimens were used to evaluate temperature and short-term sustained loading effects on time-dependent behavior under sustained loading and debonding behavior under pull-off loading after a sustained loading period. The numerical model was parameterized with experiments on the concrete, FRP, and epoxy. Good correlation was seen between the numerical results and single-lap shear experiments. Sensitivity studies shed light on the influence of temperature, epoxy modulus, and epoxy thickness on the redistribution of interfacial shear stress during sustained loading. This investigation confirms the hypothesis that interfacial stress redistribution can occur due to sustained load and elevated temperature and its effect can be significant.

Modeling and Measurement of Sustained Loading and Temperature-Dependent Deformation of Carbon Fiber-Reinforced Polymer Bonded to Concrete

PubMed Central

Jeong, Yoseok; Lee, Jaeha; Kim, WooSeok

2015-01-01

This paper aims at presenting the effects of short-term sustained load and temperature on time-dependent deformation of carbon fiber-reinforced polymer (CFRP) bonded to concrete and pull-off strength at room temperature after the sustained loading period. The approach involves experimental and numerical analysis. Single-lap shear specimens were used to evaluate temperature and short-term sustained loading effects on time-dependent behavior under sustained loading and debonding behavior under pull-off loading after a sustained loading period. The numerical model was parameterized with experiments on the concrete, FRP, and epoxy. Good correlation was seen between the numerical results and single-lap shear experiments. Sensitivity studies shed light on the influence of temperature, epoxy modulus, and epoxy thickness on the redistribution of interfacial shear stress during sustained loading. This investigation confirms the hypothesis that interfacial stress redistribution can occur due to sustained load and elevated temperature and its effect can be significant. PMID:28787948

Room Temperature and Elevated Temperature Composite Sandwich Joint Testing

NASA Technical Reports Server (NTRS)

Walker, Sandra P.

1998-01-01

Testing of composite sandwich joint elements has been completed to verify the strength capacity of joints designed to carry specified running loads representative of a high speed civil transport wing. Static tension testing at both room and an elevated temperature of 350 F and fatigue testing at room temperature were conducted to determine strength capacity, fatigue life, and failure modes. Static tension test results yielded failure loads above the design loads for the room temperature tests, confirming the ability of the joint concepts tested to carry their design loads. However, strength reductions as large as 30% were observed at the elevated test temperature, where all failure loads were below the room temperature design loads for the specific joint designs tested. Fatigue testing resulted in lower than predicted fatigue lives.

Meteorological Predictions in Support of the Mars Science Laboratory Entry, Descent and Landing

NASA Astrophysics Data System (ADS)

Rothchild, A.; Rafkin, S. C.; Pielke, R. A., Sr.

2010-12-01

The Mars Science Laboratory (MSL) entry, descent, and landing (EDL) system employs a standard parachute strategy followed by a new sky crane concept where the rover is lowered to the ground via a tether from a hovering entry vehicle. As with previous missions, EDL system performance is sensitive to atmospheric conditions. While some observations characterizing the mean, large-scale atmospheric temperature and density data are available, there is effectively no information on the atmospheric conditions and variability at the scale that directly affects the spacecraft. In order to evaluate EDL system performance and to assess landing hazards and risk, it is necessary to simulate the atmosphere with a model that provides data at the appropriate spatial and temporal scales. Models also permit the study of the impact of the highly variable atmospheric dust loading on temperature, density and winds. There are four potential MSL landing sites: Mawrth Valle (22.3 N, 16.5W) , Gale Crater (5.4S, 137.7E), Holden Crater (26.1S, 34W), and Eberswalde Crater (24S, 33W). The final selection of the landing site will balance potential science return against landing and operational risk. Atmospheric modeling studies conducted with the Mars Regional Atmospheric Modeling System (MRAMS) is an integral part of the selection process. At each of the landing sites, a variety of simulations are conducted. The first type of simulations provide baseline predictions under nominal atmospheric dust loading conditions within the landing site window of ~Ls 150-170. The second type of simulation explores situations with moderate and high global atmospheric dust loading. The final type of simulation investigates the impact of local dust disturbances at the landing site. Mean and perturbation fields from each type of simulation at each of the potential landing sites are presented in comparison with the engineering performance limitations for the MSL EDL system. Within the lowest scale height, winds are strongly influenced by the local and regional topography and are highly variable in both space and time. Convective activity in the afternoon produces deep vertical circulations anchored primarily to topography. Aloft, winds become increasingly dominated by the large-scale circulation, but with gravity wave perturbations forced by both topography and boundary layer convective activity. The mean density field is tied directly to the level of dust loading; higher dust results in decreased densities and overall warming of the atmospheric column. In local and regional dust storm scenarios, winds are found to be enhanced, particularly in regions of active dust lifting. Local reductions in density are also pronounced. At present, the predicted mean and perturbation fields from all the simulations appear to fall within the engineering requirements, but not always comfortably so. This is in contrast to proposed landing sites for the Mars Exploration Rover mission, where the atmospheric environment presented unacceptable risk. Ongoing work is underway to confirm that atmospheric conditions will permit safe EDL operations with a tolerable level of risk.

Relationship between current load and temperature for quasi-steady state and transient conditions

NASA Astrophysics Data System (ADS)

Lyon, Bernard R., Jr.; Orlove, Gary L.; Peters, Donna L.

2000-03-01

Infrared thermographers involved in predictive maintenance programs often use temperature measurement as a means of quantifying the severity of a problem. Temperature is certainly an important factor in evaluating equipment. However, if you follow guidelines that are based solely on absolute temperature measurement--or on a temperature rise (Delta T)--you run the risk of incorrectly diagnosing your problems. The consequences of such actions can lead to a false sense of security, equipment failure, fire, and even the possibility of personal injury. Understanding the additional factors involved in diagnosis is essential for obtaining productive results. One of these factors is the load or current flowing through conductors. The load can have a drastic effect on the temperature of a component. Changing loads can cause additional concerns because temperature changes lag behind load changes. The purpose of this paper is to illustrate the relationship between load and temperature of a faulty connection. The thermal response of a changing load is also investigated.

Development and qualification of a bulk tungsten divertor row for JET

NASA Astrophysics Data System (ADS)

Mertens, Ph.; Altmann, H.; Hirai, T.; Philipps, V.; Pintsuk, G.; Rapp, J.; Riccardo, V.; Schweer, B.; Uytdenhouwen, I.; Samm, U.

2009-06-01

A bulk tungsten divertor row has been developed in the frame of the ITER-like Wall project at JET. It consists of 96 tiles grouped in 48 modules around the torus. The outer strike point is located on those tiles for most of the ITER-relevant, high triangularity plasmas. High power loads (locally up to 10-20 MW/m 2) and erosion rates are expected, even a risk of melting, especially with the transients or ELM loads. These are demanding conditions for an inertially cooled design as prescribed. A lamella design has been selected for the tungsten, arranged to control the eddy and halo current flows. The lamellae must also withstand high temperature gradients (2200 to 220 °C over 40 mm height), without overheating the supporting carrier (600-700 °C maximum). As a consequence of the tungsten emissivity, the radiative cooling drops appreciably in comparison with the current CFC tiles, calling for interleaved plasma scenarios in terms of performance. The compromise between shadowing and power handling is discussed, as well as the consequences for operation. Prototypes have been exposed in TEXTOR and in an electron beam facility (JUDITH-2) to the nominal power density of 7 MW/m 2 for 10 s and, in addition, to higher loads leading to surface temperatures above 2000 °C.

A two-stage heating scheme for heat assisted magnetic recording

NASA Astrophysics Data System (ADS)

Xiong, Shaomin; Kim, Jeongmin; Wang, Yuan; Zhang, Xiang; Bogy, David

2014-05-01

Heat Assisted Magnetic Recording (HAMR) has been proposed to extend the storage areal density beyond 1 Tb/in.2 for the next generation magnetic storage. A near field transducer (NFT) is widely used in HAMR systems to locally heat the magnetic disk during the writing process. However, much of the laser power is absorbed around the NFT, which causes overheating of the NFT and reduces its reliability. In this work, a two-stage heating scheme is proposed to reduce the thermal load by separating the NFT heating process into two individual heating stages from an optical waveguide and a NFT, respectively. As the first stage, the optical waveguide is placed in front of the NFT and delivers part of laser energy directly onto the disk surface to heat it up to a peak temperature somewhat lower than the Curie temperature of the magnetic material. Then, the NFT works as the second heating stage to heat a smaller area inside the waveguide heated area further to reach the Curie point. The energy applied to the NFT in the second heating stage is reduced compared with a typical single stage NFT heating system. With this reduced thermal load to the NFT by the two-stage heating scheme, the lifetime of the NFT can be extended orders longer under the cyclic load condition.

Modeling of crack growth under mixed-mode loading by a molecular dynamics method and a linear fracture mechanics approach

NASA Astrophysics Data System (ADS)

Stepanova, L. V.

2017-12-01

Atomistic simulations of the central crack growth process in an infinite plane medium under mixed-mode loading using Large-Scale Atomic/Molecular Massively Parallel Simulator (LAMMPS), a classical molecular dynamics code, are performed. The inter-atomic potential used in this investigation is the Embedded Atom Method (EAM) potential. Plane specimens with an initial central crack are subjected to mixed-mode loadings. The simulation cell contains 400,000 atoms. The crack propagation direction angles under different values of the mixity parameter in a wide range of values from pure tensile loading to pure shear loading in a wide range of temperatures (from 0.1 K to 800 K) are obtained and analyzed. It is shown that the crack propagation direction angles obtained by molecular dynamics coincide with the crack propagation direction angles given by the multi-parameter fracture criteria based on the strain energy density and the multi-parameter description of the crack-tip fields. The multi-parameter fracture criteria are based on the multi-parameter stress field description taking into account the higher order terms of the Williams series expansion of the crack tip fields.

High Energy Density All Solid State Asymmetric Pseudocapacitors Based on Free Standing Reduced Graphene Oxide-Co3O4 Composite Aerogel Electrodes.

PubMed

Ghosh, Debasis; Lim, Joonwon; Narayan, Rekha; Kim, Sang Ouk

2016-08-31

Modern flexible consumer electronics require efficient energy storage devices with flexible free-standing electrodes. We report a simple and cost-effective route to a graphene-based composite aerogel encapsulating metal oxide nanoparticles for high energy density, free-standing, binder-free flexible pseudocapacitive electrodes. Hydrothermally synthesized Co3O4 nanoparticles are successfully housed inside the microporous graphene aerogel network during the room temperature interfacial gelation at the Zn surface. The resultant three-dimensional (3D) rGO-Co3O4 composite aerogel shows mesoporous quasiparallel layer stack morphology with a high loading of Co3O4, which offers numerous channels for ion transport and a 3D interconnected network for high electrical conductivity. All solid state asymmetric pseudocapacitors employing the composite aerogel electrodes have demonstrated high areal energy density of 35.92 μWh/cm(2) and power density of 17.79 mW/cm(2) accompanied by excellent cycle life.

Thermophysical properties of heat-treated U-7Mo/Al dispersion fuel

NASA Astrophysics Data System (ADS)

Cho, Tae Won; Kim, Yeon Soo; Park, Jong Man; Lee, Kyu Hong; Kim, Sunghwan; Lee, Chong Tak; Yang, Jae Ho; Oh, Jang Soo; Sohn, Dong-Seong

2018-04-01

In this study, the effects of interaction layer (IL) on thermophysical properties of U-7Mo/Al dispersion fuel were examined. Microstructural analyses revealed that ILs were formed uniformly on U-Mo particles during heating of U-7Mo/Al samples. The IL volume fraction was measured by applying image analysis methods. The uranium loadings of the samples were calculated based on the measured meat densities at 298 K. The density of the IL was estimated by using the measured density and IL volume fraction. Thermal diffusivity and heat capacity of the samples after the heat treatment were measured as a function of temperature and volume fractions of U-Mo and IL. The thermal conductivity of IL-formed U-7Mo/Al was derived by using the measured thermal diffusivity, heat capacity, and density. The thermal conductivity obtained in the present study was lower than that predicted by the modified Hashin-Shtrikman model due to the theoretical model's inability to consider the thermal resistance at interfaces between the meat constituents.

Wall temperature measurements at elevated pressures and high temperatures in sooting flames in a gas turbine model combustor

NASA Astrophysics Data System (ADS)

Nau, Patrick; Yin, Zhiyao; Geigle, Klaus Peter; Meier, Wolfgang

2017-12-01

Wall temperatures were measured with thermographic phosphors on the quartz walls of a model combustor in ethylene/air swirl flames at 3 bar. Three operating conditions were investigated with different stoichiometries and with or without additional injection of oxidation air downstream of the primary combustion zone. YAG:Eu and YAG:Dy were used to cover a total temperature range of 1000-1800 K. Measurements were challenging due to the high thermal background from soot and window degradation at high temperatures. The heat flux through the windows was estimated from the temperature gradient between the in- and outside of the windows. Differences in temperature and heat flux density profiles for the investigated cases can be explained very well with the previously measured differences in flame temperatures and flame shapes. The heat loss relative to thermal load is quite similar for all investigated flames (15-16%). The results complement previous measurements in these flames to investigate soot formation and oxidation. It is expected, that the data set is a valuable input for numerical simulations of these flames.

Internal loading of an inhomogeneous compressible Earth with phase boundaries

NASA Technical Reports Server (NTRS)

Defraigne, P.; Dehant, V.; Wahr, J. M.

1996-01-01

The geoid and the boundary topography caused by mass loads inside the earth were estimated. It is shown that the estimates are affected by compressibility, by a radially varying density distribution, and by the presence of phase boundaries with density discontinuities. The geoid predicted in the chemical boundary case is 30 to 40 percent smaller than that predicted in the phase case. The effects of compressibility and radially varying density are likely to be small. The inner core-outer core topography for loading inside the mantle and for loading inside the inner core were computed.

Lithium Sulfur Primary Battery with Super High Energy Density: Based on the Cauliflower-like Structured C/S Cathode

NASA Astrophysics Data System (ADS)

Ma, Yiwen; Zhang, Hongzhang; Wu, Baoshan; Wang, Meiri; Li, Xianfeng; Zhang, Huamin

2015-10-01

The lithium-sulfur primary batteries, as seldom reported in the previous literatures, were developed in this work. In order to maximize its practical energy density, a novel cauliflower-like hierarchical porous C/S cathode was designed, for facilitating the lithium-ions transport and sulfur accommodation. This kind of cathode could release about 1300 mAh g-1 (S) capacity at sulfur loading of 6 ~ 14 mg cm-2, and showed excellent shelf stability during a month test at room temperature. As a result, the assembled Li-S soft package battery achieved an energy density of 504 Wh kg-1 (654 Wh L-1), which was the highest value ever reported to the best of our knowledge. This work might arouse the interests on developing primary Li-S batteries, with great potential for practical application.

Lithium Sulfur Primary Battery with Super High Energy Density: Based on the Cauliflower-like Structured C/S Cathode.

PubMed

Ma, Yiwen; Zhang, Hongzhang; Wu, Baoshan; Wang, Meiri; Li, Xianfeng; Zhang, Huamin

2015-10-12

The lithium-sulfur primary batteries, as seldom reported in the previous literatures, were developed in this work. In order to maximize its practical energy density, a novel cauliflower-like hierarchical porous C/S cathode was designed, for facilitating the lithium-ions transport and sulfur accommodation. This kind of cathode could release about 1300 mAh g(-1) (S) capacity at sulfur loading of 6 ~ 14 mg cm(-2), and showed excellent shelf stability during a month test at room temperature. As a result, the assembled Li-S soft package battery achieved an energy density of 504 Wh kg(-1) (654 Wh L(-1)), which was the highest value ever reported to the best of our knowledge. This work might arouse the interests on developing primary Li-S batteries, with great potential for practical application.

Lithium Sulfur Primary Battery with Super High Energy Density: Based on the Cauliflower-like Structured C/S Cathode

PubMed Central

Ma, Yiwen; Zhang, Hongzhang; Wu, Baoshan; Wang, Meiri; Li, Xianfeng; Zhang, Huamin

2015-01-01

The lithium-sulfur primary batteries, as seldom reported in the previous literatures, were developed in this work. In order to maximize its practical energy density, a novel cauliflower-like hierarchical porous C/S cathode was designed, for facilitating the lithium-ions transport and sulfur accommodation. This kind of cathode could release about 1300 mAh g−1 (S) capacity at sulfur loading of 6 ~ 14 mg cm−2, and showed excellent shelf stability during a month test at room temperature. As a result, the assembled Li-S soft package battery achieved an energy density of 504 Wh kg−1 (654 Wh L−1), which was the highest value ever reported to the best of our knowledge. This work might arouse the interests on developing primary Li-S batteries, with great potential for practical application. PMID:26456914

Mechanical properties and material characterization of polysialate structural composites

NASA Astrophysics Data System (ADS)

Foden, Andrew James

One of the major concerns in using Fiber Reinforced Composites in applications that are subjected to fire is their resistance to high temperature. Some of the fabrics used in FRC, such as carbon, are fire resistant. However, almost all the resins used cannot withstand temperatures higher than 200°C. This dissertation deals with the development and use of a potassium aluminosilicate (GEOPOLYMER) resin that is inorganic and can sustain more than 1000°C. The results presented include the mechanical properties of the unreinforced polysialate matrix in tension, flexure, and compression as well as the strain capacities and surface energy. The mechanical properties of the matrix reinforced with several different fabrics were obtained in flexure, tension, compression and shear. The strength and stiffness of the composite was evaluated for each loading condition. Tests were conducted on unexposed samples as well as samples exposed to temperatures from 200 to 1000°C. Fatigue properties were determined using flexural loading. A study of the effect of several processing variables on the properties of the composite was undertaken to determine the optimum procedure for manufacturing composite plates. The processing variables studied were the curing temperature and pressure, and the post cure drying time required to remove any residual water. The optimum manufacturing conditions were determined using the void content, density, fiber volume fraction, and flexural strength. Analytical models are presented based on both micro and macro mechanical analysis of the composite. Classic laminate theory is used to evaluate the state of the composite as it is being loaded to determine the failure mechanisms. Several failure criteria theories are considered. The analysis is then used to explain the mechanical behavior of the composite that was observed during the experimental study.

Analysis and design of an ultrahigh temperature hydrogen-fueled MHD generator

NASA Technical Reports Server (NTRS)

Moder, Jeffrey P.; Myrabo, Leik N.; Kaminski, Deborah A.

1993-01-01

A coupled gas dynamics/radiative heat transfer analysis of partially ionized hydrogen, in local thermodynamic equilibrium, flowing through an ultrahigh temperature (10,000-20,000 K) magnetohydrodynamic (MHD) generator is performed. Gas dynamics are modeled by a set of quasi-one-dimensional, nonlinear differential equations which account for friction, convective and radiative heat transfer, and the interaction between the ionized gas and applied magnetic field. Radiative heat transfer is modeled using nongray, absorbing-emitting 2D and 3D P-1 approximations which permit an arbitrary variation of the spectral absorption coefficient with frequency. Gas dynamics and radiative heat transfer are coupled through the energy equation and through the temperature- and density-dependent absorption coefficient. The resulting nonlinear elliptic problem is solved by iterative methods. Design of such MHD generators as onboard, open-cycle, electric power supplies for a particular advanced airbreathing propulsion concept produced an efficient and compact 128-MWe generator characterized by an extraction ratio of 35.5 percent, a power density of 10,500 MWe/cu m, and a specific (extracted) energy of 324 MJe/kg of hydrogen. The maximum wall heat flux and total wall heat load were 453 MW/sq m and 62 MW, respectively.

Growth of Matrix Cracks During Intermediate Temperature Stress Rupture of a SiC/SiC Composite in Air

NASA Technical Reports Server (NTRS)

Morscher, Gregory N.

2000-01-01

The crack density of woven Hi-Nicalon(sup TM) (Nippon Carbon, Japan) fiber, BN interphase, melt-infiltrated SiC matrix composites was determined for specimens subjected to tensile stress rupture at 815 C. A significant amount of matrix cracking occurs due to the growth of fiber-bridged microcracks even at stresses below the run-out condition. This increased cracking corresponded to time dependent strain accumulation and acoustic emission activity during the constant load test. However, the portion of the rupture specimens subjected to cooler temperatures (< 600 C than the hot section had significantly lower crack densities compared to the hotter regions. From the acoustic emission and time dependent strain data it can be inferred that most of the matrix crack growth occurred within the first few hours of the tensile rupture experiment. The crack growth was attributed to an interphase recession mechanism that is enhanced by the presence of a thin carbon layer between the fiber and the matrix as a result of the composite fabrication process. One important consequence of matrix crack growth at the lower stresses is poor retained strength at room temperature for specimens that did not fail.

Mechanical behaviour of pressed and sintered CP Ti and Ti-6Al-7Nb alloy obtained from master alloy addition powder.

PubMed

Bolzoni, L; Weissgaerber, T; Kieback, B; Ruiz-Navas, E M; Gordo, E

2013-04-01

The Ti-6Al-7Nb alloy was obtained using the blending elemental approach with a master alloy and elemental titanium powders. Both the elemental titanium and the Ti-6Al-7Nb powders were characterised using X-ray diffraction, differential thermal analysis and dilatometry. The powders were processed using the conventional powder metallurgy route that includes uniaxial pressing and sintering. The trend of the relative density with the sintering temperature and the microstructural evolution of the materials sintered at different temperatures were analysed using scanning electron microscopy and X-ray diffraction. A minimum sintering temperature of 1200°C has to be used to ensure the homogenisation of the alloying elements and to obtain a pore structure composed of spherical pores. The sintered samples achieve relative density values that are typical for powder metallurgy titanium and no intermetallic phases were detected. Mechanical properties comparable to those specified for wrought Ti-6Al-7Nb medical devices are normally obtained. Therefore, the produced materials are promising candidates for load bearing applications as implant materials. Copyright © 2013 Elsevier Ltd. All rights reserved.

A comparative study of noise pollution levels in some selected areas in Ilorin Metropolis, Nigeria.

PubMed

Oyedepo, Olayinka S; Saadu, Abdullahi A

2009-11-01

The noise pollution is a major problem for the quality of life in urban areas. This study was conducted to compare the noise pollution levels at busy roads/road junctions, passengers loading parks, commercial, industrial and residential areas in Ilorin metropolis. A total number of 47-locations were selected within the metropolis. Statistical analysis shows significant difference (P < 0.05) in noise pollution levels between industrial areas and low density residential areas, industrial areas and high density areas, industrial areas and passengers loading parks, industrial areas and commercial areas, busy roads/road junctions and low density areas, passengers loading parks and commercial areas and commercial areas and low density areas. There is no significant difference (P > 0.05) in noise pollution levels between industrial areas and busy roads/road junctions, busy roads/road junctions and high density areas, busy roads/road junctions and passengers loading parks, busy roads/road junctions and commercial areas, passengers loading parks and high density areas, passengers loading parks and commercial areas and commercial areas and high density areas. The results show that Industrial areas have the highest noise pollution levels (110.2 dB(A)) followed by busy roads/Road junctions (91.5 dB(A)), Passengers loading parks (87.8 dB(A)) and Commercial areas (84.4 dB(A)). The noise pollution levels in Ilorin metropolis exceeded the recommended level by WHO at 34 of 47 measuring points. It can be concluded that the city is environmentally noise polluted and road traffic and industrial machineries are the major sources of it. Noting the noise emission standards, technical control measures, planning and promoting the citizens awareness about the high noise risk may help to relieve the noise problem in the metropolis.

Systematic optimization of laser cooling of dysprosium

NASA Astrophysics Data System (ADS)

Mühlbauer, Florian; Petersen, Niels; Baumgärtner, Carina; Maske, Lena; Windpassinger, Patrick

2018-06-01

We report on an apparatus for cooling and trapping of neutral dysprosium. We characterize and optimize the performance of our Zeeman slower and 2D molasses cooling of the atomic beam by means of Doppler spectroscopy on a 136 kHz broad transition at 626 nm. Furthermore, we demonstrate the characterization and optimization procedure for the loading phase of a magneto-optical trap (MOT) by increasing the effective laser linewidth by sideband modulation. After optimization of the MOT compression phase, we cool and trap up to 10^9 atoms within 3 seconds in the MOT at temperatures of 9 μK and phase space densities of 1.7 \\cdot 10^{-5}, which constitutes an ideal starting point for loading the atoms into an optical dipole trap and for subsequent forced evaporative cooling.

Miniature Reservoir Cathode: An Update

NASA Technical Reports Server (NTRS)

Vancil, Bernard K.; Wintucky, Edwin G.

2002-01-01

We report on recent work to produce a small low power, low cost reservoir cathode capable of long life (more than 100,000 hours) at high loading (> 5 A/sq cm). Our objective is a highly manufacturable, commercial device costing less than $30. Small highly loaded cathodes are needed, especially for millimeter wave tubes, where focusing becomes difficult when area convergence ratios are too high. We currently have 3 models ranging from .060-inch diameter to. 125-inch diameter. Reservoir type barium dispenser cathodes have a demonstrated capability for simultaneous high emission density and long life. Seven reservoir cathodes continue to operate on the cathode life test facility at NSWC, Crane, Indiana at 2 and 4 amps/sq cm. They have accumulated nearly 100,000 hours with practically no change in emission levels or knee temperature.

Recent advances in solid polymer electrolyte fuel cell technology with low platinum loading electrodes

NASA Technical Reports Server (NTRS)

Srinivasan, Supramaniam; Manko, David J.; Enayatullah, Mohammad; Appleby, A. John

1989-01-01

High power density fuel cell systems for defense and civilian applications are being developed. Taking into consideration the main causes for efficiency losses (activation, mass transport and ohmic overpotentials) the only fuel cell systems capable of achieving high power densities are the ones with alkaline and solid polymer electrolyte. High power densities (0.8 W/sq cm at 0.8 V and 1 A/sq cm with H2 and O2 as reactants), were already used in NASA's Apollo and Space Shuttle flights as auxiliary power sources. Even higher power densities (4 W/sq cm - i.e., 8 A sq cm at 0.5 V) were reported by the USAF/International Fuel Cells in advanced versions of the alkaline system. High power densities (approximately 1 watt/sq cm) in solid polymer electrolyte fuel cells with ten times lower platinum loading in the electrodes (i.e., 0.4 mg/sq cm) were attained. It is now possible to reach a cell potential of 0.620 V at a current density of 2 A/sq cm and at a temperature of 95 C and pressure of 4/5 atm with H2/O2 as reactants. The slope of the linear region of the potential-current density plot for this case is 0.15 ohm-sq cm. With H2/air as reactants and under the same operating conditions, mass transport limitations are encountered at current densities above 1.4 A/sq cm. Thus, the cell potential at 1 A/sq cm with H2/air as reactants is less than that with H2/O2 as reactants by 40 mV, which is the expected value based on electrode kinetics of the oxygen reduction reaction, and at 2 A/sq cm with H2/air as reactant is less than the corresponding value with H2/O2 as reactants by 250 mV, which is due to the considerably greater mass transport limitations in the former case.

Dynamic Hydrostatic Pressure Regulates Nucleus Pulposus Phenotypic Expression and Metabolism in a Cell Density-Dependent Manner.

PubMed

Shah, Bhranti S; Chahine, Nadeen O

2018-02-01

Dynamic hydrostatic pressure (HP) loading can modulate nucleus pulposus (NP) cell metabolism, extracellular matrix (ECM) composition, and induce transformation of notochordal NP cells into mature phenotype. However, the effects of varying cell density and dynamic HP magnitude on NP phenotype and metabolism are unknown. This study examined the effects of physiological magnitudes of HP loading applied to bovine NP cells encapsulated within three-dimensional (3D) alginate beads. Study 1: seeding density (1 M/mL versus 4 M/mL) was evaluated in unloaded and loaded (0.1 MPa, 0.1 Hz) conditions. Study 2: loading magnitude (0, 0.1, and 0.6 MPa) applied at 0.1 Hz to 1 M/mL for 7 days was evaluated. Study 1: 4 M/mL cell density had significantly lower adenosine triphosphate (ATP), glycosaminoglycan (GAG) and collagen content, and increased lactate dehydrogenase (LDH). HP loading significantly increased ATP levels, and expression of aggrecan, collagen I, keratin-19, and N-cadherin in HP loaded versus unloaded groups. Study 2: aggrecan expression increased in a dose dependent manner with HP magnitude, whereas N-cadherin and keratin-19 expression were greatest in low HP loading compared to unloaded. Overall, the findings of the current study indicate that cell seeding density within a 3D construct is a critical variable influencing the mechanobiological response of NP cells to HP loading. NP mechanobiology and phenotypic expression was also found to be dependent on the magnitude of HP loading. These findings suggest that HP loading and culture conditions of NP cells may require complex optimization for engineering an NP replacement tissue.

Specimen loading list for the varying temperature experiment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qualls, A.L.; Sitterson, R.G.

1998-09-01

The varying temperature experiment HFIR-RB-13J has been assembled and inserted in the reactor. Approximately 5300 specimens were cleaned, inspected, matched, and loaded into four specimen holders. A listing of each specimen loaded into the steady temperature holder, its position in the capsule, and the identification of the corresponding specimen loaded into the varying temperature holder is presented in this report.

Dislocation and Structural Studies at Metal-Metallic Glass Interface at Low Temperature

NASA Astrophysics Data System (ADS)

Gupta, Pradeep; Yedla, Natraj

2017-12-01

In this paper, molecular dynamics (MD) simulation deformation studies on the Al (metal)-Cu50Zr50 (metallic glass) model interface is carried out based on cohesive zone model. The interface is subjected to mode-I loading at a strain rate of 109 s-1 and temperature of 100 K. The dislocations reactions and evolution of dislocation densities during the deformation have been investigated. Atomic interactions between Al, Cu and Zr atoms are modeled using EAM (embedded atom method) potential, and a timestep of 0.002 ps is used for performing the MD simulations. A circular crack and rectangular notch are introduced at the interface to investigate the effect on the deformation behavior and fracture. Further, scale size effect is also investigated. The structural changes and evolution of dislocation density are also examined. It is found that the dominant deformation mechanism is by Shockley partial dislocation nucleation. Amorphization is observed in the Al regions close to the interface and occurs at a lower strain in the presence of a crack. The total dislocation density is found to be maximum after the first yield in both the perfect and defect interface models and is highest in the case of perfect interface with a density of 6.31 × 1017 m-2. In the perfect and circular crack defect interface models, it is observed that the fraction of Shockley partial dislocation density decreases, whereas that of strain rod dislocations increases with increase in strain.

Analysis of temperature changes on three-phase synchronous generator using infrared: comparison between balanced and unbalanced load

NASA Astrophysics Data System (ADS)

Amien, S.; Yoga, W.; Fahmi, F.

2018-02-01

Synchronous generators are a major tool in an electrical energy generating systems, the load supplied by the generator is unbalanced. This paper discusses the effect of synchronous generator temperature on the condition of balanced load and unbalanced load, which will then be compared with the measurement result of both states of the generator. Unbalanced loads can be caused by various asymmetric disturbances in the power system and the failure of load forecasting studies so that the load distribution in each phase is not the same and causing the excessive heat of the generator. The method used in data collection was by using an infrared thermometer and resistance calculation method. The temperature comparison result between the resistive, inductive and capacitive loads in the highest temperature balance occured when the generator is loaded with a resistive load, where T = 31.9 ° C and t = 65 minutes. While in a state of unbalanced load the highest temperature occured when the generator is loaded with a capacitive load, where T = 40.1 ° C and t = 60 minutes. By understanding this behavior, we can maintain the generator for longer operation life.

Thermal analysis of the intact mandibular premolar: a finite element analysis.

PubMed

Oskui, I Z; Ashtiani, M N; Hashemi, A; Jafarzadeh, H

2013-09-01

To obtain temperature distribution data through human teeth focusing on the pulp-dentine junction (PDJ). A three-dimensional tooth model was reconstructed using computer-aided design software from computed tomographic images. Subsequently, temperature distribution was numerically determined through the tooth for three different heat loads. Loading type I was equivalent to a 60° C mouth temperature for 1 s. Loading type II started with a 60° C mouth temperature, decreasing linearly to 37° C over 10 s. Loading type III repeated the pattern of type II in three consecutive cycles, with a 5 s resting time between cycles. The maximum temperatures of the pulp were 37.9° C, 39.0° C and 41.2° C for loading types I, II, and III, respectively. The largest temperature rise occurred with the cyclic loading, that is, type III. For the heat loads considered, the predicted peak temperatures at the PDJ were less than the reported temperature thresholds of irreversible pulpal damage. © 2013 International Endodontic Journal. Published by John Wiley & Sons Ltd.

Temperature effect of elastic anisotropy and internal strain development in advanced nanostructured alloys: An in-situ synchrotron X-ray investigation

DOE PAGES

Gan, Yingye; Mo, Kun; Yun, Di; ...

2017-03-19

Nanostructured ferritic alloys (NFAs) are promising structural materials for advanced nuclear systems due to their exceptional radiation tolerance and high-temperature mechanical properties. Their remarkable properties result from the ultrafine ultrahigh density Y-Ti-O nanoclusters dispersed within the ferritic matrix. In this work, we performed in-situ synchrotron X-ray diffraction tests to study the tensile deformation process of the three types of NFAs: 9YWTV, 14YWT-sm13, and 14YWT-sm170 at both room temperature and elevated temperatures. A technique was developed, combining Kroner's model and X-ray measurement, to determine the intrinsic monocrystal elastic-stiffness constants, and polycrystal Young's modulus and Poisson's ratio of the NFAs. Temperature dependencemore » of elastic anisotropy was observed in the NFAs. Lastly, an analysis of intergranular strain and strengthening factors determined that 14YWT-sm13 had a higher resistance to temperature softening compared to 9YWTV, attributed to the more effective nanoparticle strengthening during high-temperature mechanical loading.« less

Stratospheric aerosol acidity, density, and refractive index deduced from SAGE 2 and NMC temperature data

NASA Technical Reports Server (NTRS)

Yue, G. K.; Poole, L. R.; Wang, P.-H.; Chiou, E. W.

1994-01-01

Water vapor concentrations obtained by the Stratospheric Aerosol and Gas Experiment 2 (SAGE 2) and collocated temperatures provided by the National Meteorological Center (NMC) from 1986 to 1990 are used to deduce seasonally and zonally averaged acidity, density, and refractive index of stratospheric aerosols. It is found that the weight percentage of sulfuric acid in the aerosols increases from about 60 just above the tropopause to about 86 at 35 km. The density increases from about 1.55 to 1.85 g/cu cm between the same altitude limits. Some seasonal variations of composition and density are evident at high latitudes. The refractive indices at 1.02, 0.694, and 0.532 micrometers increase, respectively, from about 1.425, 1.430, and 1.435 just above the tropopause to about 1.445, 1.455, and 1.458 at altitudes above 27 km, depending on the season and latitude. The aerosol properties presented can be used in models to study the effectiveness of heterogeneous chemistry, the mass loading of stratospheric aerosols, and the extinction and backscatter of aerosols at different wavelengths. Computed aerosol surface areas, rate coefficients for the heterogeneous reaction ClONO2 + H2O yields HOCl + HNO3 and aerosol mass concentrations before and after the Pinatubo eruption in June 1991 are shown as sample applications.

Performance of a 260 Hz pulse tube cooler with metal fiber as the regenerator material

NASA Astrophysics Data System (ADS)

Wang, Xiaotao; Zhang, Shuang; Yu, Guoyao; Dai, Wei; Luo, Ercang

2014-01-01

Pulse tube coolers operating at higher frequency lead to a high energy density and result in a more compact system. This paper describes the performance of a 300 Hz pulse tube cooler driven by a linear compressor. Such high frequency operation leads to decreased thermal penetration, which requires a smaller hydraulic diameter and smaller wire diameter in the regenerator. In our previous experiments, the stainless steel mesh with a mesh number of 635 was used as the regenerator material, and a no-load temperature of 63 K was obtained. Both the numerical and experimental results indicate this material causes a large loss in the regenerator. A stainless steel fiber regenerator is introduced and studied in this article. Because this fiber has a wide range of wire diameter and porosity, such material might be more suitable for higher frequency pulse tube coolers. With the fiber as the regenerator material and after a series of optimizations, a no-load temperature of 45 K is acquired in the experiment. Influences of various parameters such as frequency and inertance tube length have been investigated experimentally.

PEG 400-Based Phase Change Materials Nano-Enhanced with Functionalized Graphene Nanoplatelets.

PubMed

Marcos, Marco A; Cabaleiro, David; Guimarey, María J G; Comuñas, María J P; Fedele, Laura; Fernández, Josefa; Lugo, Luis

2017-12-29

This study presents new Nano-enhanced Phase Change Materials, NePCMs, formulated as dispersions of functionalized graphene nanoplatelets in a poly(ethylene glycol) with a mass-average molecular mass of 400 g·mol -1 for possible use in Thermal Energy Storage. Morphology, functionalization, purity, molecular mass and thermal stability of the graphene nanomaterial and/or the poly(ethylene glycol) were characterized. Design parameters of NePCMs were defined on the basis of a temporal stability study of nanoplatelet dispersions using dynamic light scattering. Influence of graphene loading on solid-liquid phase change transition temperature, latent heat of fusion, isobaric heat capacity, thermal conductivity, density, isobaric thermal expansivity, thermal diffusivity and dynamic viscosity were also investigated for designed dispersions. Graphene nanoplatelet loading leads to thermal conductivity enhancements up to 23% while the crystallization temperature reduces up to in 4 K. Finally, the heat storage capacities of base fluid and new designed NePCMs were examined by means of the thermophysical properties through Stefan and Rayleigh numbers. Functionalized graphene nanoplatelets leads to a slight increase in the Stefan number.

PEG 400-Based Phase Change Materials Nano-Enhanced with Functionalized Graphene Nanoplatelets

PubMed Central

Marcos, Marco A.; Guimarey, María J. G.; Comuñas, María J. P.

2017-01-01

This study presents new Nano-enhanced Phase Change Materials, NePCMs, formulated as dispersions of functionalized graphene nanoplatelets in a poly(ethylene glycol) with a mass-average molecular mass of 400 g·mol−1 for possible use in Thermal Energy Storage. Morphology, functionalization, purity, molecular mass and thermal stability of the graphene nanomaterial and/or the poly(ethylene glycol) were characterized. Design parameters of NePCMs were defined on the basis of a temporal stability study of nanoplatelet dispersions using dynamic light scattering. Influence of graphene loading on solid-liquid phase change transition temperature, latent heat of fusion, isobaric heat capacity, thermal conductivity, density, isobaric thermal expansivity, thermal diffusivity and dynamic viscosity were also investigated for designed dispersions. Graphene nanoplatelet loading leads to thermal conductivity enhancements up to 23% while the crystallization temperature reduces up to in 4 K. Finally, the heat storage capacities of base fluid and new designed NePCMs were examined by means of the thermophysical properties through Stefan and Rayleigh numbers. Functionalized graphene nanoplatelets leads to a slight increase in the Stefan number. PMID:29286324

Optical and probe determination of soot concentrations in a model gas turbine combustor

NASA Technical Reports Server (NTRS)

Eckerle, W. A.; Rosfjord, T. J.

1986-01-01

An experimental program was conducted to track the variation in soot loading in a generic gas turbine combustor. The burner is a 12.7-cm dia cylindrical device consisting of six sheet-metal louvers. Determination of soot loading along the burner length is achieved by measurement at the exit of the combustor and then at upstream stations by sequential removal of liner louvers to shorten burner length. Alteration of the flow field approaching and within the shortened burners is minimized by bypassing flow in order to maintain a constant linear pressure drop. The burner exhaust flow is sampled at the burner centerline to determine soot mass concentration and smoke number. Characteristic particle size and number density, transmissivity of the exhaust flow, and local radiation from luminous soot particles in the exhaust are determined by optical techniques. Four test fuels are burned at three fuel-air ratios to determine fuel chemical property and flow temperature influences. Particulate concentration data indicate a strong oxidation mechanism in the combustor secondary zone, though the oxidation is significantly affected by flow temperature. Soot production is directly related to fuel smoke point.

Structure and Thermodynamical Properties of Zirconium Hydrides from First-Principle

NASA Astrophysics Data System (ADS)

Blomqvist, Jakob; Olofsson, Johan; Alvarez, Anna-Maria; Bjerkén, Christina

Zirconium alloys are used as nuclear fuel cladding material due to their mechanical and corrosion resistant properties together with their favorable cross-section for neutron scattering. At running conditions, however, there will be an increase of hydrogen in the vicinity of the cladding surface at the water side of the fuel. The hydrogen will diffuse into the cladding material and at certain conditions, such as lower temperatures and external load, hydrides will precipitate out in the material and cause well known embrittlement, blistering and other unwanted effects. Using phase-field methods it is now possible to model precipitation buildup in metals, for example as a function of hydrogen concentration, temperature and external load, but the technique relies on input of parameters, such as the formation energy of the hydrides and matrix. To that end, we have computed, using the density functional theory (DFT) code GPAW, the latent heat of fusion as well as solved the crystal structure for three zirconium hydride polymorphs: δ-ZrH1.6, γ-ZrH, and Є-ZrH2.

A Radiographic Comparison of Progressive and Conventional Loading on Crestal Bone Loss and Density in Single Dental Implants: A Randomized Controlled Trial Study

PubMed Central

Ghoveizi, Rahab; Alikhasi, Marzieh; Siadat, Mohammad-Reza; Siadat, Hakimeh; Sorouri, Majid

2013-01-01

Objective: Crestal bone loss is a biological complication in implant dentistry. The aim of this study was to compare the effect of progressive and conventional loading on crestal bone height and bone density around single osseointegrated implants in the posterior maxilla by a longitudinal radiographic assessment technique. Materials and Methods: Twenty micro thread implants were placed in 10 patients (two implants per patient). One of the two implants in each patient was assigned to progressive and the other to conventional loading groups. Eight weeks after surgery, conventional implants were restored with a metal ceramic crown and the progressive group underwent a progressive loading protocol. The progressive loading group took different temporary acrylic crowns at 2, 4 and 6 months. After eight months, acrylic crowns were replaced with a metal ceramic crown. Computer radiography of both progressive and conventional implants was taken at 2, 4, 6, and 12 months. Image analysis was performed to measure the height of crestal bone loss and bone density. Results: The mean values of crestal bone loss at month 12 were 0.11 (0.19) mm for progressively and 0.36 (0.36) mm for conventionally loaded implants, with a statistically significant difference (P < 0.05) using Wilcoxon sign rank. Progressively loaded group showed a trend for higher bone density gain compared to the conventionally loaded group, but when tested with repeated measure ANOVA, the differences were not statistically significant (P > 0.05). Conclusion: The progressive group showed less crestal bone loss in single osseointegrated implant than the conventional group. Bone density around progressively loaded implants showed increase in crestal, middle and apical areas. PMID:23724215

Electrocatalytic performance of fuel cell reactions at low catalyst loading and high mass transport.

PubMed

Zalitis, Christopher M; Kramer, Denis; Kucernak, Anthony R

2013-03-28

An alternative approach to the rotating disk electrode (RDE) for characterising fuel cell electrocatalysts is presented. The approach combines high mass transport with a flat, uniform, and homogeneous catalyst deposition process, well suited for studying intrinsic catalyst properties at realistic operating conditions of a polymer electrolyte fuel cell (PEFC). Uniform catalyst layers were produced with loadings as low as 0.16 μgPt cm(-2) and thicknesses as low as 200 nm. Such ultra thin catalyst layers are considered advantageous to minimize internal resistances and mass transport limitations. Geometric current densities as high as 5.7 A cm(-2)Geo were experimentally achieved at a loading of 10.15 μgPt cm(-2) for the hydrogen oxidation reaction (HOR) at room temperature, which is three orders of magnitude higher than current densities achievable with the RDE. Modelling of the associated diffusion field suggests that such high performance is enabled by fast lateral diffusion within the electrode. The electrodes operate over a wide potential range with insignificant mass transport losses, allowing the study of the ORR at high overpotentials. Electrodes produced a specific current density of 31 ± 9 mA cm(-2)Spec at a potential of 0.65 V vs. RHE for the oxygen reduction reaction (ORR) and 600 ± 60 mA cm(-2)Spec for the peak potential of the HOR. The mass activity of a commercial 60 wt% Pt/C catalyst towards the ORR was found to exceed a range of literature PEFC mass activities across the entire potential range. The HOR also revealed fine structure in the limiting current range and an asymptotic current decay for potentials above 0.36 V. These characteristics are not visible with techniques limited by mass transport in aqueous media such as the RDE.

Assessment of Methods to Consolidate Iodine-Loaded Silver-Functionalized Silica Aerogel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Matyas, Josef; Engler, Robert K.

2013-09-01

The U.S. Department of Energy is currently investigating alternative sorbents for the removal and immobilization of radioiodine from the gas streams in a nuclear fuel reprocessing plant. One of these new sorbents, Ag0-functionalized silica aerogels, shows great promise as a potential replacement for Ag-bearing mordenites because of its high selectivity and sorption capacity for iodine. Moreover, a feasible consolidation of iodine-loaded Ag0-functionalized silica aerogels to a durable SiO2-based waste form makes this aerogel an attractive choice for sequestering radioiodine. This report provides a preliminary assessment of the methods that can be used to consolidate iodine-loaded Ag0-functionalized silica aerogels into amore » final waste form. In particular, it focuses on experimental investigation of densification of as prepared Ag0-functionalized silica aerogels powders, with or without organic moiety and with or without sintering additive (colloidal silica), with three commercially available techniques: 1) hot uniaxial pressing (HUP), 2) hot isostatic pressing (HIP), and 3) spark plasma sintering (SPS). The densified products were evaluated with helium gas pycnometer for apparent density, with the Archimedes method for apparent density and open porosity, and with high-resolution scanning electron microscopy and energy dispersive spectroscopy (SEM-EDS) for the extent of densification and distribution of individual elements. The preliminary investigation of HUP, HIP, and SPS showed that these sintering methods can effectively consolidate powders of Ag0-functionalized silica aerogel into products of near-theoretical density. Also, removal of organic moiety and adding 5.6 mass% of colloidal silica to Ag0-functionalized silica aerogel powders before processing provided denser products. Furthermore, the ram travel data for SPS indicated that rapid consolidation of powders can be performed at temperatures below 950°C.« less

A 3D graphene interface (Si-doped) of Ag matrix with excellent electronic transmission and thermal conductivity via nano-assembly modification

NASA Astrophysics Data System (ADS)

Ye, Xianzhu; Li, Ming; Zhang, Yafei

2018-04-01

The wide development of electronic materials requires higher load capacity and high temperature resistance. In this study, a novel architecture was fabricated consisting of a 3D reduced graphene oxide (rGO)-Si interface using a simple nano-assembly sintering to achieve high current capacity and excellent thermal features. Via the analysis of catalytic oxidation for methanol, the loading catalytic activity of nano-Ag still remained to a certain extent for the composite with 0.8 vol.% rGO. The final Ag-rGO composite apparently possesses a higher initial oxidation temperature and lower rate of oxidation for internal passing and shielding, and the thermal conductivity is significantly enhanced from 344 to 407 W m‑1 K‑1. Importantly, with a 3D synergistic transportation network, the resistivity of the Ag-rGO composite is much lower than pure Ag, and with a longer conductive time under a stress condition of current density of 6.0  ×  104 A cm‑2. Thermal-electronic features demonstrate that the dispersed graphene interface can efficiently suppress the primary failure pathways (high temperature) in Ag matrix and make it uniquely efficient for the advancement of microscale and thermal-management electronics.

Probabilistic models for reactive behaviour in heterogeneous condensed phase media

NASA Astrophysics Data System (ADS)

Baer, M. R.; Gartling, D. K.; DesJardin, P. E.

2012-02-01

This work presents statistically-based models to describe reactive behaviour in heterogeneous energetic materials. Mesoscale effects are incorporated in continuum-level reactive flow descriptions using probability density functions (pdfs) that are associated with thermodynamic and mechanical states. A generalised approach is presented that includes multimaterial behaviour by treating the volume fraction as a random kinematic variable. Model simplifications are then sought to reduce the complexity of the description without compromising the statistical approach. Reactive behaviour is first considered for non-deformable media having a random temperature field as an initial state. A pdf transport relationship is derived and an approximate moment approach is incorporated in finite element analysis to model an example application whereby a heated fragment impacts a reactive heterogeneous material which leads to a delayed cook-off event. Modelling is then extended to include deformation effects associated with shock loading of a heterogeneous medium whereby random variables of strain, strain-rate and temperature are considered. A demonstrative mesoscale simulation of a non-ideal explosive is discussed that illustrates the joint statistical nature of the strain and temperature fields during shock loading to motivate the probabilistic approach. This modelling is derived in a Lagrangian framework that can be incorporated in continuum-level shock physics analysis. Future work will consider particle-based methods for a numerical implementation of this modelling approach.

Pyrolysis-catalysis of waste plastic using a nickel-stainless-steel mesh catalyst for high-value carbon products.

PubMed

Zhang, Yeshui; Nahil, Mohamad A; Wu, Chunfei; Williams, Paul T

2017-11-01

A stainless-steel mesh loaded with nickel catalyst was produced and used for the pyrolysis-catalysis of waste high-density polyethylene with the aim of producing high-value carbon products, including carbon nanotubes (CNTs). The catalysis temperature and plastic-to-catalyst ratio were investigated to determine the influence on the formation of different types of carbon deposited on the nickel-stainless-steel mesh catalyst. Increasing temperature from 700 to 900°C resulted in an increase in the carbon deposited on the nickel-loaded stainless-steel mesh catalyst from 32.5 to 38.0 wt%. The increase in sample-to-catalyst ratio reduced the amount of carbon deposited on the mesh catalyst in terms of g carbon g -1 plastic. The carbons were found to be largely composed of filamentous carbons, with negligible disordered (amorphous) carbons. Transmission electron microscopy analysis of the filamentous carbons revealed them to be composed of a large proportion (estimated at ∼40%) multi-walled carbon nanotubes (MWCNTs). The optimum process conditions for CNT production, in terms of yield and graphitic nature, determined by Raman spectroscopy, was catalysis temperature of 800°C and plastic-to-catalyst ratio of 1:2, where a mass of 334 mg of filamentous/MWCNTs g -1 plastic was produced.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gleicher, Frederick; Ortensi, Javier; DeHart, Mark

Accurate calculation of desired quantities to predict fuel behavior requires the solution of interlinked equations representing different physics. Traditional fuels performance codes often rely on internal empirical models for the pin power density and a simplified boundary condition on the cladding edge. These simplifications are performed because of the difficulty of coupling applications or codes on differing domains and mapping the required data. To demonstrate an approach closer to first principles, the neutronics application Rattlesnake and the thermal hydraulics application RELAP-7 were coupled to the fuels performance application BISON under the master application MAMMOTH. A single fuel pin was modeledmore » based on the dimensions of a Westinghouse 17x17 fuel rod. The simulation consisted of a depletion period of 1343 days, roughly equal to three full operating cycles, followed by a station blackout (SBO) event. The fuel rod was depleted for 1343 days for a near constant total power loading of 65.81 kW. After 1343 days the fission power was reduced to zero (simulating a reactor shut-down). Decay heat calculations provided the time-varying energy source after this time. For this problem, Rattlesnake, BISON, and RELAP-7 are coupled under MAMMOTH in a split operator approach. Each system solves its physics on a separate mesh and, for RELAP-7 and BISON, on only a subset of the full problem domain. Rattlesnake solves the neutronics over the whole domain that includes the fuel, cladding, gaps, water, and top and bottom rod holders. Here BISON is applied to the fuel and cladding with a 2D axi-symmetric domain, and RELAP-7 is applied to the flow of the circular outer water channel with a set of 1D flow equations. The mesh on the Rattlesnake side can either be 3D (for low order transport) or 2D (for diffusion). BISON has a matching ring structure mesh for the fuel so both the power density and local burn up are copied accurately from Rattlesnake. At each depletion time step, Rattlesnake calculates a power density, fission density rate, burn-up distribution and fast flux based on the current water density and fuel temperature. These are then mapped to the BISON mesh for a fuels performance solve. BISON calculates the fuel temperature and cladding surface temperature based upon the current power density and bulk fluid temperature. RELAP-7 then calculates the fluid temperature, water density fraction and water phase velocity based upon the cladding surface temperature. The fuel temperature and the fluid density are then passed back to Rattlesnake for another neutronics calculation. Six Picard or fixed-point style iterations are preformed in this manner to obtain consistent tightly coupled and stable results. For this paper a set of results from the detailed calculation are provided for both during depletion and the SBO event. We demonstrate that a detailed calculation closer to first principles can be done under MAMMOTH between different applications on differing domains.« less

Effect of density and weight of load on the energy cost of carrying loads by donkeys and ponies.

PubMed

Pearson, R A; Dijkman, J T; Krecek, R C; Wright, P

1998-02-01

Two experiments were designed to compare the energy used in carrying loads by donkeys and ponies. In the first experiment 3 donkeys and 3 ponies were compared on treadmills in the UK. Density of load (lead shot or straw) had no significant effect on the energy cost of carrying loads; however, the energy cost of carrying a load decreased significantly (p < 0.001) as the weight of the load increased (in donkeys 6.44, 4.35 and 3.03 J/kg load/m, in ponies 5.82, 3.75 and 3.68 J/kg load/m, for loads of 13, 20 and 27 kg/100 kg liveweight (M) respectively). Differences between species were not significant. In the second experiment energy expenditures were determined in 3 donkeys carrying loads equivalent to 40 kg/100 kg M over gently undulating gravel tracks in Tunisia. Energy costs of carrying the load were 2.34 (SE 0.07) J/kg load/m. The results of both experiments showed that provided the load is balanced, density does not significantly affect the energy cost of carrying; however, as the load increased then the unit energy cost of carrying it decreased. This suggest that it is more efficient in terms of energy used to carry loads equivalent to 27 to 40 kg/100 kg M than it is to carry lighter loads to less than 20 kg/100 kg M.

Mechanical properties of cancellous bone in the human mandibular condyle are anisotropic.

PubMed

Giesen, E B; Ding, M; Dalstra, M; van Eijden, T M

2001-06-01

The objective of the present study was (1) to test the hypothesis that the elastic and failure properties of the cancellous bone of the mandibular condyle depend on the loading direction, and (2) to relate these properties to bone density parameters. Uniaxial compression tests were performed on cylindrical specimens (n=47) obtained from the condyles of 24 embalmed cadavers. Two loading directions were examined, i.e., a direction coinciding with the predominant orientation of the plate-like trabeculae (axial loading) and a direction perpendicular to the plate-like trabeculae (transverse loading). Archimedes' principle was applied to determine bone density parameters. The cancellous bone was in axial loading 3.4 times stiffer and 2.8 times stronger upon failure than in transverse loading. High coefficients of correlation were found among the various mechanical properties and between them and the apparent density and volume fraction. The anisotropic mechanical properties can possibly be considered as a mechanical adaptation to the loading of the condyle in vivo.

Reduced mechanical load decreases the density, stiffness, and strength of cancellous bone of the mandibular condyle.

PubMed

Giesen, E B W; Ding, M; Dalstra, M; van Eijden, T M G J

2003-05-01

To investigate the influence of decreased mechanical loading on the density and mechanical properties of the cancellous bone of the human mandibular condyle. Destructive compressive mechanical tests were performed on cancellous bone specimens.Background. Reduced masticatory function in edentate people leads to a reduction of forces acting on the mandible. As bone reacts to its mechanical environment a change in its material properties can be expected. Cylindrical bone specimens were obtained from dentate and edentate embalmed cadavers. Mechanical parameters were determined in the axial and in the transverse directions. Subsequently, density parameters were determined according to a method based on Archimedes' principle. The apparent density and volume fraction of the bone were about 18% lower in the edentate group; no age-related effect on density was found. The decrease of bone in the edentate group was associated with a lower stiffness and strength (about 22% and 28%, respectively). The ultimate strain, however, did not differ between the two groups. Both groups had similar mechanical anisotropy; in axial loading the bone was stiffer and stronger than in transverse loading. Reduced mechanical load had affected the density and herewith the mechanical properties of condylar cancellous bone, but not its anisotropy. The change in material properties of the cancellous bone after loss of teeth indicate that the mandibular condyle is sensitive for changes in its mechanical environment. Therefore, changes in mechanical loading of the condyle have to be accounted for in surgical procedures of the mandible.

Characterization and prediction of rate-dependent flexibility in lumbar spine biomechanics at room and body temperature.

PubMed

Stolworthy, Dean K; Zirbel, Shannon A; Howell, Larry L; Samuels, Marina; Bowden, Anton E

2014-05-01

The soft tissues of the spine exhibit sensitivity to strain-rate and temperature, yet current knowledge of spine biomechanics is derived from cadaveric testing conducted at room temperature at very slow, quasi-static rates. The primary objective of this study was to characterize the change in segmental flexibility of cadaveric lumbar spine segments with respect to multiple loading rates within the range of physiologic motion by using specimens at body or room temperature. The secondary objective was to develop a predictive model of spine flexibility across the voluntary range of loading rates. This in vitro study examines rate- and temperature-dependent viscoelasticity of the human lumbar cadaveric spine. Repeated flexibility tests were performed on 21 lumbar function spinal units (FSUs) in flexion-extension with the use of 11 distinct voluntary loading rates at body or room temperature. Furthermore, six lumbar FSUs were loaded in axial rotation, flexion-extension, and lateral bending at both body and room temperature via a stepwise, quasi-static loading protocol. All FSUs were also loaded using a control loading test with a continuous-speed loading-rate of 1-deg/sec. The viscoelastic torque-rotation response for each spinal segment was recorded. A predictive model was developed to accurately estimate spine segment flexibility at any voluntary loading rate based on measured flexibility at a single loading rate. Stepwise loading exhibited the greatest segmental range of motion (ROM) in all loading directions. As loading rate increased, segmental ROM decreased, whereas segmental stiffness and hysteresis both increased; however, the neutral zone remained constant. Continuous-speed tests showed that segmental stiffness and hysteresis are dependent variables to ROM at voluntary loading rates in flexion-extension. To predict the torque-rotation response at different loading rates, the model requires knowledge of the segmental flexibility at a single rate and specified temperature, and a scaling parameter. A Bland-Altman analysis showed high coefficients of determination for the predictive model. The present work demonstrates significant changes in spine segment flexibility as a result of loading rate and testing temperature. Loading rate effects can be accounted for using the predictive model, which accurately estimated ROM, neutral zone, stiffness, and hysteresis within the range of voluntary motion. Copyright © 2014 Elsevier Inc. All rights reserved.

Demonstrate Scale-up Procedure for Glass Composite Material (GCM) for Incorporation of Iodine Loaded AgZ.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nenoff, Tina M.; Garino, Terry J.; Croes, Kenneth James

2015-07-01

Two large size Glass Composite Material (GCM) waste forms containing AgI-MOR were fabricated. One contained methyl iodide-loaded AgI-MOR that was received from Idaho National Laboratory (INL, Test 5, Beds 1 – 3) and the other contained iodine vapor loaded AgIMOR that was received from Oak Ridge National Laboratory (ORNL, SHB 2/9/15 ). The composition for each GCM was 20 wt% AgI-MOR and 80 wt% Ferro EG2922 low sintering temperature glass along with enough added silver flake to prevent any I2 loss during the firing process. The silver flake amounts were 1.2 wt% for the GCM with the INL AgI-MOR andmore » 3 wt% for the GCM contained the ORNL AgI-MOR. The GCMs, nominally 100 g, were first uniaxially pressed to 6.35 cm (2.5 inch) diameter disks then cold isostatically pressed, before firing in air to 550°C for 1hr. They were cooled slowly (1°C/min) from the firing temperature to avoid any cracking due to temperature gradients. The final GCMs were ~5 cm in diameter (~2 inches) and non-porous with densities of ~4.2 g/cm³. X-ray diffraction indicated that they consisted of the amorphous glass phase with small amounts of mordenite and AgI. Furthermore, the presence of the AgI was confirmed by X-ray fluorescence. Methodology for the scaled up production of GCMs to 6 inch diameter or larger is also presented.« less

Passive Safety Features Evaluation of KIPT Neutron Source Facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhong, Zhaopeng; Gohar, Yousry

2016-06-01

Argonne National Laboratory (ANL) of the United States and Kharkov Institute of Physics and Technology (KIPT) of Ukraine have cooperated on the development, design, and construction of a neutron source facility. The facility was constructed at Kharkov, Ukraine and its commissioning process is underway. It will be used to conduct basic and applied nuclear research, produce medical isotopes, and train young nuclear specialists. The facility has an electron accelerator-driven subcritical assembly. The electron beam power is 100 kW using 100 MeV electrons. Tungsten or natural uranium is the target material for generating neutrons driving the subcritical assembly. The subcritical assemblymore » is composed of WWR-M2 - Russian fuel assemblies with U-235 enrichment of 19.7 wt%, surrounded by beryllium reflector assembles and graphite blocks. The subcritical assembly is seated in a water tank, which is a part of the primary cooling loop. During normal operation, the water coolant operates at room temperature and the total facility power is ~300 KW. The passive safety features of the facility are discussed in in this study. Monte Carlo computer code MCNPX was utilized in the analyses with ENDF/B-VII.0 nuclear data libraries. Negative reactivity temperature feedback was consistently observed, which is important for the facility safety performance. Due to the design of WWR-M2 fuel assemblies, slight water temperature increase and the corresponding water density decrease produce large reactivity drop, which offset the reactivity gain by mistakenly loading an additional fuel assembly. The increase of fuel temperature also causes sufficiently large reactivity decrease. This enhances the facility safety performance because fuel temperature increase provides prompt negative reactivity feedback. The reactivity variation due to an empty fuel position filled by water during the fuel loading process is examined. Also, the loading mistakes of removing beryllium reflector assemblies and replacing them with dummy assemblies were analyzed. In all these circumstances, the reactivity change results do not cause any safety concerns.« less

3D Printing Factors Important for the Fabrication of Polyvinylalcohol Filament-Based Tablets.

PubMed

Tagami, Tatsuaki; Fukushige, Kaori; Ogawa, Emi; Hayashi, Naomi; Ozeki, Tetsuya

2017-01-01

Three-dimensional (3D) printers have been applied in many fields, including engineering and the medical sciences. In the pharmaceutical field, approval of the first 3D-printed tablet by the U.S. Food and Drug Administration in 2015 has attracted interest in the manufacture of tablets and drugs by 3D printing techniques as a means of delivering tailor-made drugs in the future. In current study, polyvinylalcohol (PVA)-based tablets were prepared using a fused-deposition-modeling-type 3D printer and the effect of 3D printing conditions on tablet production was investigated. Curcumin, a model drug/fluorescent marker, was loaded into PVA-filament. We found that several printing parameters, such as the rate of extruding PVA (flow rate), can affect the formability of the resulting PVA-tablets. The 3D-printing temperature is controlled by heating the print nozzle and was shown to affect the color of the tablets and their curcumin content. PVA-based infilled tablets with different densities were prepared by changing the fill density as a printing parameter. Tablets with lower fill density floated in an aqueous solution and their curcumin content tended to dissolve faster. These findings will be useful in developing drug-loaded PVA-based 3D objects and other polymer-based articles prepared using fused-deposition-modeling-type 3D printers.

Materials and structures for hypersonic vehicles

NASA Technical Reports Server (NTRS)

Tenney, Darrel R.; Lisagor, W. Barry; Dixon, Sidney C.

1988-01-01

Hypersonic vehicles are envisioned to require, in addition to carbon-carbon and ceramic-matrix composities for leading edges heated to above 2000 F, such 600 to 1800 F operating temperature materials as advanced Ti alloys, nickel aluminides, and metal-matrix composited; These possess the necessary low density and high strength and stiffness. The primary design drivers are maximum vehicle heating rate, total heat load, flight envelope, propulsion system type, mission life requirements and liquid hydrogen containment systems. Attention is presently given to aspects of these materials and structures requiring more intensive development.

Constitutive Model for Anisotropic Creep Behaviors of Single-Crystal Ni-Base Superalloys in the Low-Temperature, High-Stress Regime (Postprint)

DTIC Science & Technology

2012-01-19

specific dislocation reactions. Rae et al .[4,5,7] proposed micromechanisms for primary creep caused by SF shearing of c0 precipitates by ah112i...near the [0 0 1] was done by Matan et al .[3] They proposed a phenomenological creep model, which was adopted from Gilman’s dislocation density model...the original loading orientation). MacLachlan et al .[18 21] proposed a series of creep models for anisotropic creep of single-crystal superalloys. Their

International Conference (4th) on Nanostructured Materials Held in Stockholm, Sweden on 14-19 June 1998. Special Volume - Part A. Volume 12, Numbers 1-4, 1999

DTIC Science & Technology

1998-06-19

correlation was found between the X - ray grain size and the TEM grain size. Table 2 contains the hardness and density data for the nanocrystalline 5083...temperature with a Neophot hardness tester and a load of 0.2 N. RESULTS AND DISCUSSION X - ray diffraction and transmission electron microscopy combined with...For Single- Wall Carbon Nanotubes by Raman Scattering Technique Microstructure Change in Co46AI19035 Granular Thin Films by Annealing X - Ray

PROPULSION AND POWER RAPID RESPONSE RESEARCH AND DEVELOPMENT (R&D) SUPPORT. Deliver Order 0002: Power-Dense, Solid Oxide Fuel Cell Systems: High-Performance, High-Power-Density Solid Oxide Fuel Cells - Materials and Load Control

DTIC Science & Technology

2010-04-01

aluminum titanate has evolved from a coefficient of thermal expansion (CTE) lowering additive in traditional nickel/YSZ cermets to an anchoring...provision of law, no person shall be subject to any penalty for failing to comply with a collection of information if it does not display a currently...volumetric concentrations well below percolation for traditional cermets . The coarsening of nickel after high temperature thermal treatment poses

Correlation between some technological parameters and properties of composite material based on recycled tires and polymer binder

NASA Astrophysics Data System (ADS)

Plesuma, Renate; Malers, Laimonis

2015-04-01

The present article is dedicated to the determination of a possible connection between the composition, specific properties of the composite material and molding pressure as an important technological parameter. Apparent density, Shore C hardness, compressive modulus of elasticity and compressive stress at 10% deformation was determined for composite material samples. Definite formation conditions - varying molding pressure conditions at ambient temperature and corresponding relative air humiditywere realized. The results obtained showed a significant effect of molding pressure on the apparent density, mechanical properties of composite material as well as on the compressive stress change at a cyclic mode of loading. Some general regularities were determined - mechanical properties of the composite material, as well as values of Shore C hardness increases with an increase of molding pressure.

Dynamic Consolidation and Investigation of Nanostructural W-Cu / W-Y Cylindrical Billets

NASA Astrophysics Data System (ADS)

Godibadze, B.; Dgebuadze, A.; Chagelishvili, E.; Mamniashvili, G.; Peikrishvili, A.

2018-03-01

The main purpose of presented work is to obtain W-Cu & W-Y cylindrical bulk nanostructured billets by explosive consolidation technology (ECT) in hot condition, with low porosity near to theoretical densities and improved physical / mechanical properties. Nanocomposites were subjected to densification into cylindrical steel tube containers using hot explosive consolidation (HEC) technology to fabricate high dense cylindrical billets. The first stage : Preliminary explosive densification of the precursor powder blend is carried out at room temperature with a loading intensity up to 10GPa to increase the initial density and to activate the particle surfaces in the blend. The second stage investigation were carried out for the same already predensified billets, but consolidation were conducted in hot conditions, after heating of samples in between 940-11000C, the intensity of loading was equal to 10GPa. Consolidated different type of W-Cu composition containing 10-40% of nanoscale W, during investigation showed that the combination of high temperatures (above 940°C) and two-stage shock wave compression was beneficial to the consolidation of the incompatible pair W-Cu composites, resulting in high densities, good integrity and good electronic properties. The structure and property of the samples obtained, depended on the sizes of tungsten particles. It was established that in comparison with W-Cu composites with coarse tungsten the application of nanoscale W precursors and depending of content of W gives different result. Tungsten is a prime material candidate for the first wall of a future fusion reactor. In this study, the microstructure and microhardness of tungsten-yttrium (W-Y) composites were investigated as a function of Y doping content (0.5÷2 wt. %). It was found that the crystallite sizes and the powder particle sizes were increased as a result of the increase of Y content. Nearly fully dense materials were obtained for W-Y alloys when the Y content was higher than 0.5 wt. %. Investigation revealed that the Y rich phases were complex (W-Y) oxides formed during the sintering process. Also very interesting to use doping chromium with yttrium-containing alloys. e.g. (W - 10÷12 Cr -0.5÷2 Y) wt. %. The extent up to which yttrium acts as an active element improving the adherence and stability of the protective Cr 2 O 3 layer formed during oxidation is assessed. The structure and characteristics of the obtained samples depends on the phase content, distribution of phases and processing parameters during explosive synthesis and consolidation. Cu – (10-30%) W powder mixtures were formed into cylindrical rods using a hot shock wave consolidation (HSWC) process. Different type of Cu - W precursor composition containing 10, 20 and 30% of nanoscale W were consolidated near theoretical density under 900°C The loading intensity was under 10 GPa. The investigation showed that the combination of high temperatures (above 800°C) and two stage shock wave compression was beneficial to the consolidation of the W-Cu & W-Y composites, resulting in high densities, good integrity and good electronic properties.

Temperature effect of elastic anisotropy and internal strain development in advanced nanostructured alloys: An in-situ synchrotron X-ray investigation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gan, Yingye; Mo, Kun; Yun, Di

2017-04-01

Nanostructured ferritic alloys (NFAs) are a promising structural material for advanced nuclear systems due to their exceptional radiation tolerance and high-temperature mechanical properties. Their remarkable properties result from the ultrafine ultrahigh density Y-Ti-O nanoclusters dispersed within the ferritic matrix. In this work, we performed in-situ synchrotron X-ray diffraction tests to study the tensile deformation process of the three types of NFAs: 9YWTV, 14YWT-sm13, and 14YWT-sm170 at both room temperature and elevated temperatures. A technique was developed, combining Kroner’s model and X-ray measurement, to determine the intrinsic monocrystal elastic-stiffness constants, and polycrystal Young’s modulus and Poisson’s ratio of the NFAs. Temperaturemore » dependence of elastic anisotropy was observed in the NFAs. An analysis of intergranular strain and strengthening factors determined that 14YWT-sm13 had a higher resistance to temperature softening compared to 9YWTV, attributed to the more effective nanoparticle strengthening during high-temperature mechanical loading.« less

Analysis of optimal design of low temperature economizer

NASA Astrophysics Data System (ADS)

Song, J. H.; Wang, S.

2017-11-01

This paper has studied the Off-design characteristic of low temperature economizer system based on thermodynamics analysis. Based on the data from one 1000 MW coal-fired unit, two modes of operation are contrasted and analyzed. One is to fix exhaust gas temperature and the other one is to take into account both of the average temperature difference and the exhaust gas temperature. Meanwhile, the cause of energy saving effect change is explored. Result shows that: in mode 1, the amount of decrease in coal consumption reduces from 1.11 g/kWh (under full load) to 0.54 g/kWh (under half load), and in mode 2, when the load decreases from 90% to 50%, the decrease in coal consumption reduces from 1.29 g/kWh to 0.84 g/kWh. From the result, under high load, the energy saving effect is superior, and under lower work load, energy saving effect declines rapidly when load is reduced. When load changes, the temperature difference of heat transfer, gas flow, the flue gas heat rejection and the waste heat recovery change. The energy saving effect corresponding changes result in that the energy saving effect under high load is superior and more stable. However, rational adjustment to the temperature of outlet gas can alleviate the decline of the energy saving effect under low load. The result provides theoretical analysis data for the optimal design and operation of low temperature economizer system of power plant.

Ceramic Near-Net Shaped Processing Using Highly-Loaded Aqueous Suspensions

NASA Astrophysics Data System (ADS)

Rueschhoff, Lisa

Ceramic materials offer great advantages over their metal counterparts, due to their lower density, higher hardness and wear resistance, and higher melting temperatures. However, the use of ceramics in applications where their properties would offer tremendous advantages are often limited due to the difficulty of forming them into complex and near-net shaped parts. Methods that have been developed to injection-mold or cast ceramics into more complicated shapes often use significant volume fractions of a carrier (often greater than 35 vol.% polymer), elevated temperature processing, or less-than-environmentally friendly chemicals where a complex chemical synthesis reaction must be timed perfectly for the approach to work. Furthermore, the continuing maturation of additive manufacturing methods requires a new approach for flowing/placing ceramic powders into useful designs. This thesis addresses the limitations of the current ceramic forming approaches by developing highly-stabilized and therefore high solids loading ceramic suspensions, with the requisite rheology for a variety of complex and near-net shaped forming techniques. Silicon nitride was chosen as a material of focus due to its high fracture toughness compared to other ceramic materials. Designing ceramic suspensions that are flowable at room temperature greatly simplifies processing as neither heating nor cooling are required during forming. Highly-loaded suspensions (>40 vol.%) are desired because all formed ceramic bodies have to be sintered to remove pores. Finally, using aqueous-based suspensions reduces any detrimental effect on the environment and tooling. The preparation of highly-loaded suspensions requires the development of a suitable dispersant through which particle-particle interactions are controlled. However, silicon nitride is difficult to stabilize in water due to complex surface and solution chemistry. In this study, aqueous silicon nitride suspensions up to 45 vol.% solids loading were dispersed using commercially available comb-type copolymer. These copolymers are used as superplasticizers in the concrete industry and are referred to as water-reducing admixtures (WRAs). Four different WRA dispersants were examined and chemical analysis determined that each was made up of a sodium salt of polyacrylic acid (PAA-Na) backbone with neutral polyethylene oxide (PEO) side chains that afford steric stabilization. The general structures of the WRAs were compared to each other by measuring the relative areas of their prominent FTIR peaks and calculating a PAA-Na/PEO peak ratio. Suspensions were made with as-received silicon nitride powders with 5 wt.% aluminum oxide and 5 wt.% yttrium oxide added as sintering aids. Three of the four WRA dispersants studied were able to produce suspensions with 43 vol.% solids loading and 5 vol.% polymer dispersant, while exhibiting a yield-pseudoplastic behavior for shear rates up to 30 s-1. At higher solids loading (45 to 47 vol.%), a shift to shear thickening behavior was observed at a critical shear rate for these WRAs. Those WRAs with a lower PAA-Na/PEO peak ratio displayed better stabilization and diminished shear thickening behavior. The vol.% of the dispersant was optimized, producing yield-pseudoplastic suspensions containing 45 vol.% solids loading with yield stresses less than 75 Pa, no shear thickening behavior, and viscosities less than 75 Pa-s for shear rates in the range of 1 to 30 s-1. Using suspensions prepared with two of the WRAs investigated in this work, silicon nitride near-net shaped parts were formed via a novel injection molding process by loading each suspension in a syringe and injecting them at a controlled rate into a mold. Each suspensions had carefully tailored yield-pseudoplastic rheology such that they can be injection molded at room temperature and low pressures (< 150 kPa). Four suspensions were studied; two different commercially available concrete water-reducing admixtures (WRAs) were used as dispersants with and without a polymer binder (Polyvinylprolidone, PVP) added for rheological modification and improved green body strength. Test bars formed via this process were sintered to high densities (up to 97% TD) without the use of external pressure, and had complete conversion to the desirable beta-Si3N4 phase with high flexural strengths up to 700 MPa. The specimen sets with the smallest average pore size on the fracture surface (77 mum) had the highest average flexural strengths of 573 MPa. The hardness of all specimens was approximately 16 GPa. The water-based suspensions, ease and low cost of processing, and robust mechanical properties obtained demonstrate this as a viable process for the economical and environmentally friendly production of Si3N4 parts. Finally, additive manufacturing was also used as a method to overcome ceramic forming difficulties and to create near-net shaped dense components via room-temperature direct ink writing. In this processes, highly loaded aqueous alumina suspensions were extruded in a layer-by-layer fashion using a low-cost syringe style 3D printer. With alumina as a model material, the effect of solids loading on rheology, specimen uniformity, density, microstructure, and mechanical properties was studied. All suspensions contained a polymer binder ( 5 vol.%), dispersant, and 51 to 58 vol.% alumina powder. Rheological measurements indicated all suspensions to be yield-pseudoplastic, and both yield stress and viscosity were found to increase with increasing alumina solids loading. Shear rates ranging from 19.5 to 24.2 s-1, corresponding to viscosities of 9.8 to 17.2 Pa·s, for the 53 - 56 vol.% alumina suspensions were found to produce the best results for the 1.25 mm tip employed during writing. All parts were sintered to greater than 98% of true density, with grain sizes ranging from 3.2 to 3.7 mum. The average flexure strength, which ranged from 134 to 157 MPa, was not influenced by the alumina solids loading. In limited study, additive manufacturing of silicon nitride suspensions stabilized with a WRA has been established. These processing routes have been proven as low-cost and viable means for producing robust ceramic parts, both of which can be tailored to many systems to expand the use of ceramics materials. Further studies on utilizing the flow stress behavior during both injection molding and direct ink writing could be beneficial in creating ceramic materials with carefully tailored microstructure to increase mechanical performance.

Activation energy of the low-load NaCl transition from nanoindentation loading curves.

PubMed

Kaupp, Gerd

2014-01-01

Access to activation energies E(a) of phase transitions is opened by unprecedented analyses of temperature dependent nanoindentation loading curves. It is based on kinks in linearized loading curves, with additional support by coincidence of kink and electrical conductivity of silicon loading curves. Physical properties of B1, B2, NaCl and further phases are discussed. The normalized low-load transition energy of NaCl (Wtrans/µN) increases with temperature and slightly decreases with load. Its semi-logarithmic plot versus T obtains activation energy E(a)/µN for calculation of the transition work for all interesting temperatures and pressures. Arrhenius-type activation energy (kJ/mol) is unavailable for indentation phase transitions. The E(a) per load normalization proves insensitive to creep-on-load, which excludes normalization to depth or volume for large temperature ranges. Such phase transition E(a)/µN is unprecedented material's property and will be of practical importance for the compatibility of composite materials under impact and further shearing interactions at elevated temperatures. © 2014 Wiley Periodicals, Inc.

Physical Activity and Bone Density in Women

NASA Technical Reports Server (NTRS)

Bowley, Susan M.; Whalen, R. T.

2000-01-01

A mathematical model of bone density regulation as a function of the daily tissue "effective" stress has been derived. Using the model, the influence of daily activity in the form of a daily loading history has been related to bone density of the calcaneus. The theory incorporates a stress exponent m to account for differences in the importance of magnitude and number of load cycles experienced during daily activity. We have derived a parameter from the model, the "Bone Density Index" (BDI). We have developed a method of collecting daily habitual loading histories using an insole force sensor interfaced to a portable digital data logger carried in a fanny pack. Our goal for this study was to determine a stress exponent, m, relating GRFz history to Calcaneal Bone Mineral Density (CBMD).

Dislocation density evolution of AA 7020-T6 investigated by in-situ synchrotron diffraction under tensile load

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhong, Z.Y., E-mail: zhengye.zhong@hzg.de; Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, D-21502 Geesthacht; Brokmeier, H.-G.

2015-10-15

The dislocation density evolution along the loading axis of a textured AA 7020-T6 aluminum alloy during uniaxial tension was investigated by in-situ synchrotron diffraction. The highly parallel synchrotron beam at the High Energy Materials Science beamline P07 in PETRA III, DESY, offers excellent conditions to separate different influences for line broadening from which micro-strains are obtained using the modified Williamson–Hall method which is also for defect density investigations. During tensile loading the dislocation density evolution was documented from the as-received material (initial micro-strain state) to the relaxation of the strains during elastic deformation. After yield, the increasing rate of dislocationmore » density growth was relatively fast till half-way between yield and UTS. After that, the rate started to decrease and the dislocation density fluctuated as the elongation increased due to the generation and annihilation of dislocations. When dislocation generation is dominant, the correlation between the flow stress and dislocation density satisfies the Taylor equation. Besides, a method to correct the thickness effect on peak broadening is developed in the present study. - Highlights: • In-situ synchrotron diffraction was applied to characterize peak broadening. • Dislocation evolution along the loading axis during uniaxial tension was investigated. • A method to correct the sample thickness effect on peak broadening was developed. • Dislocation density and flow stress satisfy the Taylor equation at a certain range. • The texture before load and after sample fracture was analyzed.« less

A Mechanism for Stratifying Lava Flows

NASA Astrophysics Data System (ADS)

Rice, A.

2005-12-01

Relict lava flows (e.g., komatiites) are often reported to be zoned in the vertical, each zone separated by a sharp contact. Such stratifications in igneous flows, both intrusive and extrusive, can be treated as analogues of suspended loads of sediments in rivers and streams, and hence amenable to quantitative treatment derived for the hydraulic environment as long as dynamic similitude is assured. Situations typically encountered in the hydraulic environment are streams carrying a bed load at the bottom of the stream, the bed load separated by a sharp horizon from a sediment load carried above it. This sediment load may be topped by others of decreasing density as one moves to the surface of the flow, with perhaps the uppermost layer clear of any suspended matter. Rules exist for estimating the thickness D of these loads: one of them is given by D ~ 4.4V3/rgcvs where V is the shear velocity or average velocity of the flow, r = (ρs - ρl)/ρl where ρs is the density of the suspended solid matter, ρl the density of the fluid, g the acceleration of gravity, c the concentration of the particulate content and vs the settling velocity. The settling velocity is secured through Stoke's Law and the velocity of the flow is given by V = R2/3S1/2/n where R is the hydraulic radius, S the gradient along which the fluid flows and n is the Manning Coefficient. In the igneous case, the bed load would be composed of primocrysts, i.e., of the first crystals to come out of solution as the flow cools along its run. This would leave the upper portions of the flow more evolved except perhaps for a quenched crust riding atop the flow. As the viscosity of the flow is dependent not only on temperature but on composition and crystal content, the mean velocity of each layer will be different from the layer above and below it. This requires shear at the interface of adjoining stratifications, which brings into play another mechanism: dispersive pressure (the Bagnold effect). Dispersive pressure will drive primocrysts into boundary layers such as that attending the bottom of the flow and at those separating stratifications. For instance, if the primocrysts were spinals, then a Cr high might be expected at the interfaces separating stratifications. Since the melt throughout is evolving as it moves down stream, compositional variations along strike (as well is in the vertical) might be expected. Application of the above notions falls within the confines of field observation.

Gasdynamic simulations of the solar wind interaction with Venus - Boundary layer formation

NASA Astrophysics Data System (ADS)

McGary, J. E.

1993-05-01

A 2D gasdynamic simulation of the mass-loaded solar wind flow around the dayside of Venus is presented. For average ionopause conditions near 300 km, the simulations show that mass loading from the pickup of oxygen ions produces a boundary layer of finite thickness along the ionopause. Within this layer and toward the ionopause, the temperature decreases and the total mass density increases significantly. Furthermore, there is a shear in the bulk flow velocity across the boundary layer, such that the tangential flow decreases in speed as the ionopause is approached and remains low along the ionopause which is consistent with Pioneer Venus observations. Numerical simulations are carried out for various mass addition rates and demonstrate that the boundary layer develops when oxygen ion production exceeds approximately 2 x 10 exp 5/cu m per s.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Muljadi, Eduard; Hasan, Iftekhar; Husain, Tausif

This research examines the vibration and thermal characteristics of double-sided flux concentrating Transverse Flux Machines (TFM), designed for direct drive application. Two TFM prototypes with different stator cores, one with Quasi U-Core and the other with E-Core, has been used for the study. 3D Finite Element Analysis (FEA) has been carried out to determine the no-load and with load performance of the TFMs along with their fluctuating axial electromagnetic force densities acting on the stator teeth. The deformation response of the stator cores was observed in the static structural analysis. Thermal analysis for the TFM was performed through FEA basedmore » on copper and iron losses in the machine to examine the temperature rise in different parts of the machine structure. Acceleration and noise measurements were experimentally obtained to characterize the vibrational performance of the prototypes.« less

Producing Zirconium Diboride Components with Complex, Near-Net Shape Geometries by Aqueous Room-Temperature Injection Molding

NASA Technical Reports Server (NTRS)

Wiesner, Valerie L.; Youngblood, Jeffrey; Trice, Rodney

2014-01-01

Room-temperature injection molding is proposed as a novel, low-cost and more energy efficient manufacturing process capable of forming complex-shaped zirconium diboride (ZrB2) parts. This innovative processing method utilized aqueous suspensions with high powder loading and a minimal amount (5 vol.) of water-soluble polyvinylpyrrolidone (PVP), which was used as a viscosity modifier. Rheological characterization was performed to evaluate the room-temperature flow properties of ZrB2-PVP suspensions. ZrB2 specimens were fabricated with high green body strength and were machinable prior to binder removal despite their low polymer content. After binder burnout and pressureless sintering, the bulk density and microstructure of specimens were characterized using Archimedes technique and scanning electron microscopy. X-Ray Diffraction was used to determine the phase compositions present in sintered specimens. Ultimate strength of sintered specimens will be determined using ASTM C1323-10 compressive C-ring test.

Elastic modulus measurements at variable temperature: Validation of atomic force microscopy techniques

NASA Astrophysics Data System (ADS)

Natali, Marco; Reggente, Melania; Passeri, Daniele; Rossi, Marco

2016-06-01

The development of polymer-based nanocomposites to be used in critical thermal environments requires the characterization of their mechanical properties, which are related to their chemical composition, size, morphology and operating temperature. Atomic force microscopy (AFM) has been proven to be a useful tool to develop techniques for the mechanical characterization of these materials, thanks to its nanometer lateral resolution and to the capability of exerting ultra-low loads, down to the piconewton range. In this work, we demonstrate two techniques, one quasi-static, i.e., AFM-based indentation (I-AFM), and one dynamic, i.e., contact resonance AFM (CR-AFM), for the mechanical characterization of compliant materials at variable temperature. A cross-validation of I-AFM and CR-AFM has been performed by comparing the results obtained on two reference materials, i.e., low-density polyethylene (LDPE) and polycarbonate (PC), which demonstrated the accuracy of the techniques.

Magnetic suspension using high temperature superconducting cores

NASA Technical Reports Server (NTRS)

Scurlock, R. G.

1992-01-01

The development of YBCO high temperature superconductors, in wire and tape forms, is rapidly approaching the point where the bulk transport current density j vs magnetic field H characteristics with liquid nitrogen cooling will enable its use in model cores. On the other hand, BSCCO high temperature superconductor in wire form has poor j-H characteristics at 77 K today, although with liquid helium or hydrogen cooling, it appears to be superior to NbTi superconductor. Since liquid nitrogen cooling is approx. 100 times cheaper than liquid helium cooling, the use of YBCO is very attractive for use in magnetic suspension. The design is discussed of a model core to accommodate lift and drag loads up to 6000 and 3000 N respectively. A comparison is made between the design performance of a liquid helium cooled NbTi (or BSCCO) superconducting core and a liquid nitrogen cooled YBCO superconducting core.

Macrophyte Community Response to Nitrogen Loading and ...

EPA Pesticide Factsheets

Empirical determination of nutrient loading thresholds that negatively impact seagrass communities have been elusive due to the multitude of factors involved. Using a mesocosm system that simulated Pacific Northwest estuaries, we evaluated macrophyte metrics across gradients of NO3 loading (0, 1.5, 3 and 6x ambient) and temperature (10 and 20 °C). Macroalgal growth, biomass, and C:N responded positively to increased NO3 load and floating algal mats developed at 20 ºC. Zostera japonica metrics, including C:N, responded more to temperature than to NO3 loading. Z. marina biomass exhibited a negative temperature effect and in some cases a negative NO3 effect, while growth rate increased with temperature. Shoot survival decreased at 20 ºC but was not influenced by NO3 loading. Wasting disease index exhibited a significant temperature by NO3 interaction consistent with increased disease susceptibility. Community shifts observed were consistent with the nutrient loading hypothesis at 20 ºC, but there was no evidence of other eutrophication symptoms due to the short residence time. The Nutrient Pollution Index tracked the NO3 gradient at 10 ºC but exhibited no response at 20 ºC. We suggest that systems characterized by cool temperatures, high NO3 loads, and short residence time may be resilient to many symptoms of eutrophication. Estuarine systems characterized by cool temperatures, high nutrient loads and rapid flushing may be resilient to some symptoms

New analytical technique for carbon dioxide absorption solvents

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pouryousefi, F.; Idem, R.O.

2008-02-15

The densities and refractive indices of two binary systems (water + MEA and water + MDEA) and three ternary systems (water + MEA + CO{sub 2}, water + MDEA + CO{sub 2}, and water + MEA + MDEA) used for carbon dioxide (CO{sub 2}) capture were measured over the range of compositions of the aqueous alkanolamine(s) used for CO{sub 2} absorption at temperatures from 295 to 338 K. Experimental densities were modeled empirically, while the experimental refractive indices were modeled using well-established models from the known values of their pure-component densities and refractive indices. The density and Gladstone-Dale refractive indexmore » models were then used to obtain the compositions of unknown samples of the binary and ternary systems by simultaneous solution of the density and refractive index equations. The results from this technique have been compared with HPLC (high-performance liquid chromatography) results, while a third independent technique (acid-base titration) was used to verify the results. The results show that the systems' compositions obtained from the simple and easy-to-use refractive index/density technique were very comparable to the expensive and laborious HPLC/titration techniques, suggesting that the refractive index/density technique can be used to replace existing methods for analysis of fresh or nondegraded, CO{sub 2}-loaded, single and mixed alkanolamine solutions.« less

Effect of surfactant on microstructure, surface hydrophilicity, mechanical and thermal properties of different multi-walled carbon nanotube/polystyrene composites

NASA Astrophysics Data System (ADS)

Li, Zhipeng; Zhang, Yanxia; Liang, Shaolei; Li, Guangfen

2018-05-01

We prepared nanocomposites of multi-walled carbon nanotube (MWCNT)/polystyrene via a solution casting method, where deionized water was used as coagulation bath. The influences of the type of MWCNTs and existence of surfactant on surface morphology, thermal properties and mechanical properties of MWCNT/polystyrene composites were extensively investigated. The pristine and two functionalized MWCNTs with the loading of 5 wt% were chosen for comparison. Both scanning electron microscopy and mercury intrusion porosimetry show that the composites without surfactant contain fewer pores and thus have higher bulk density, tensile strength, as well as low surface hydrophobicity. However, the porous structures within micro-range appear in all surfactant-treated composites, which decrease the bulk density and the tensile strength of their composites. This especially pronounced for the MWCNT-OH composite as the smallest pore size/highest porosity is found in the composites with loading of 5 wt% MWCNT-OH due to the higher content of hydroxyl groups. Despite the glass transition temperatures (Tg) of all the surfactant-treated composites lower compared with Tg for pure polystyrene, they increase for MWCNTs and MWCNT-OH composite without surfactant.

An alternative to hydrogenation processes. Electrocatalytic hydrogenation of benzophenone.

PubMed

Mozo Mulero, Cristina; Sáez, Alfonso; Iniesta, Jesús; Montiel, Vicente

2018-01-01

The electrocatalytic hydrogenation of benzophenone was performed at room temperature and atmospheric pressure using a polymer electrolyte membrane electrochemical reactor (PEMER). Palladium (Pd) nanoparticles were synthesised and supported on a carbonaceous matrix (Pd/C) with a 28 wt % of Pd with respect to carbon material. Pd/C was characterised by transmission electron microscopy (TEM), and thermogravimetric analysis (TGA). Cathodes were prepared using Pd electrocatalytic loadings (L Pd ) of 0.2 and 0.02 mg cm -2 . The anode consisted of hydrogen gas diffusion for the electrooxidation of hydrogen gas, and a 117 Nafion exchange membrane acted as a cationic polymer electrolyte membrane. Benzophenone solution was electrochemically hydrogenated in EtOH/water (90/10 v/v) plus 0.1 M H 2 SO 4 . Current densities of 10, 15 and 20 mA cm -2 were analysed for the preparative electrochemical hydrogenation of benzophenone and such results led to the highest fractional conversion (X R ) of around 30% and a selectivity over 90% for the synthesis of diphenylmethanol upon the lowest current density. With regards to an increase by ten times the Pd electrocatalytic loading the electrocatalytic hydrogenation led neither to an increase in fractional conversion nor to a change in selectivity.

An alternative to hydrogenation processes. Electrocatalytic hydrogenation of benzophenone

PubMed Central

Mozo Mulero, Cristina; Iniesta, Jesús; Montiel, Vicente

2018-01-01

The electrocatalytic hydrogenation of benzophenone was performed at room temperature and atmospheric pressure using a polymer electrolyte membrane electrochemical reactor (PEMER). Palladium (Pd) nanoparticles were synthesised and supported on a carbonaceous matrix (Pd/C) with a 28 wt % of Pd with respect to carbon material. Pd/C was characterised by transmission electron microscopy (TEM), and thermogravimetric analysis (TGA). Cathodes were prepared using Pd electrocatalytic loadings (LPd) of 0.2 and 0.02 mg cm−2. The anode consisted of hydrogen gas diffusion for the electrooxidation of hydrogen gas, and a 117 Nafion exchange membrane acted as a cationic polymer electrolyte membrane. Benzophenone solution was electrochemically hydrogenated in EtOH/water (90/10 v/v) plus 0.1 M H2SO4. Current densities of 10, 15 and 20 mA cm−2 were analysed for the preparative electrochemical hydrogenation of benzophenone and such results led to the highest fractional conversion (XR) of around 30% and a selectivity over 90% for the synthesis of diphenylmethanol upon the lowest current density. With regards to an increase by ten times the Pd electrocatalytic loading the electrocatalytic hydrogenation led neither to an increase in fractional conversion nor to a change in selectivity. PMID:29623115

Traffic on complex networks: Towards understanding global statistical properties from microscopic density fluctuations

NASA Astrophysics Data System (ADS)

Tadić, Bosiljka; Thurner, Stefan; Rodgers, G. J.

2004-03-01

We study the microscopic time fluctuations of traffic load and the global statistical properties of a dense traffic of particles on scale-free cyclic graphs. For a wide range of driving rates R the traffic is stationary and the load time series exhibits antipersistence due to the regulatory role of the superstructure associated with two hub nodes in the network. We discuss how the superstructure affects the functioning of the network at high traffic density and at the jamming threshold. The degree of correlations systematically decreases with increasing traffic density and eventually disappears when approaching a jamming density Rc. Already before jamming we observe qualitative changes in the global network-load distributions and the particle queuing times. These changes are related to the occurrence of temporary crises in which the network-load increases dramatically, and then slowly falls back to a value characterizing free flow.

Explosively driven low-density foams and powders

DOEpatents

Viecelli, James A [Orinda, CA; Wood, Lowell L [Simi Valley, CA; Ishikawa, Muriel Y [Livermore, CA; Nuckolls, John H [Danville, CA; Pagoria, Phillip F [Livermore, CA

2010-05-04

Hollow RX-08HD cylindrical charges were loaded with boron and PTFE, in the form of low-bulk density powders or powders dispersed in a rigid foam matrix. Each charge was initiated by a Comp B booster at one end, producing a detonation wave propagating down the length of the cylinder, crushing the foam or bulk powder and collapsing the void spaces. The PdV work done in crushing the material heated it to high temperatures, expelling it in a high velocity fluid jet. In the case of boron particles supported in foam, framing camera photos, temperature measurements, and aluminum witness plates suggest that the boron was completely vaporized by the crush wave and that the boron vapor turbulently mixed with and burned in the surrounding air. In the case of PTFE powder, X-ray photoelectron spectroscopy of residues recovered from fragments of a granite target slab suggest that heating was sufficient to dissociate the PTFE to carbon vapor and molecular fluorine which reacted with the quartz and aluminum silicates in the granite to form aluminum oxide and mineral fluoride compounds.

High Temperature Superconducting Magnets with Active Control for Attraction Levitation Transport Applications

NASA Technical Reports Server (NTRS)

Jones, Harry; Jenkins, Richard G.; Goodall, Roger M.; Macleod, Colin; ElAbbar, Abdallah A.; Campbell, Archie M.

1996-01-01

A research program, involving 3 British universities, directed at quantifying the controllability of High Temperature Superconducting (HTS) magnets for use in attraction levitation transport systems will be described. The work includes measurement of loss mechanisms for iron cored HTS magnets which need to produce a flux density of approx. 1 tesla in the airgap between the magnet poles and a ferromagnetic rail. This flux density needs to be maintained and this is done by introducing small variations of the magnet current using a feedback loop, at frequencies up to 10 Hz to compensate for load changes, track variation etc. The test magnet assemblies constructed so far will be described and the studies and modelling of designs for a practical levitation demonstrator (using commercially obtained HTS tape) will be discussed with particular emphasis on how the field distribution and its components, e.g., the component vector normal to the broad face of the tape, can radically affect design philosophy compared to the classical electrical engineering approach. Although specifically aimed at levitation transport the controllability data obtained have implications for a much wider range of applications.

High precision Hugoniot measurements on statically pre-compressed fluid helium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seagle, Christopher T.; Reinhart, William D.; Lopez, Andrew J.

Here we describe how the capability for statically pre-compressing fluid targets for Hugoniot measurements utilizing gas gun driven flyer plates has been developed. Pre-compression expands the capability for initial condition control, allowing access to thermodynamic states off the principal Hugoniot. Absolute Hugoniot measurements with an uncertainty less than 3% on density and pressure were obtained on statically pre-compressed fluid helium utilizing a two stage light gas gun. Helium is highly compressible; the locus of shock states resulting from dynamic loading of an initially compressed sample at room temperature is significantly denser than the cryogenic fluid Hugoniot even for relatively modestmore » (0.27–0.38 GPa) initial pressures. Lastly, the dynamic response of pre-compressed helium in the initial density range of 0.21–0.25 g/cm3 at ambient temperature may be described by a linear shock velocity (us) and particle velocity (u p) relationship: u s = C 0 + su p, with C 0 = 1.44 ± 0.14 km/s and s = 1.344 ± 0.025.« less

Enhanced performance of polybenzimidazole-based high temperature proton exchange membrane fuel cell with gas diffusion electrodes prepared by automatic catalyst spraying under irradiation technique

NASA Astrophysics Data System (ADS)

Su, Huaneng; Pasupathi, Sivakumar; Bladergroen, Bernard Jan; Linkov, Vladimir; Pollet, Bruno G.

2013-11-01

Gas diffusion electrodes (GDEs) prepared by a novel automatic catalyst spraying under irradiation (ACSUI) technique are investigated for improving the performance of phosphoric acid (PA)-doped polybenzimidazole (PBI) high temperature proton exchange membrane fuel cell (PEMFC). The physical properties of the GDEs are characterized by pore size distribution and scanning electron microscopy (SEM). The electrochemical properties of the membrane electrode assembly (MEA) with the GDEs are evaluated and analyzed by polarization curve, cyclic voltammetry (CV) and electrochemistry impedance spectroscopy (EIS). Effects of PTFE binder content, PA impregnation and heat treatment on the GDEs are investigated to determine the optimum performance of the single cell. At ambient pressure and 160 °C, the maximum power density can reach 0.61 W cm-2, and the current density at 0.6 V is up to 0.38 A cm-2, with H2/air and a platinum loading of 0.5 mg cm-2 on both electrodes. The MEA with the GDEs shows good stability for fuel cell operating in a short term durability test.

Advanced PIC-MCC simulation for the investigation of step-ionization effect in intermediate-pressure capacitively coupled plasmas

NASA Astrophysics Data System (ADS)

Kim, Jin Seok; Hur, Min Young; Kim, Chang Ho; Kim, Ho Jun; Lee, Hae June

2018-03-01

A two-dimensional parallelized particle-in-cell simulation has been developed to simulate a capacitively coupled plasma reactor. The parallelization using graphics processing units is applied to resolve the heavy computational load. It is found that the step-ionization plays an important role in the intermediate gas pressure of a few Torr. Without the step-ionization, the average electron density decreases while the effective electron temperature increases with the increase of gas pressure at a fixed power. With the step-ionization, however, the average electron density increases while the effective electron temperature decreases with the increase of gas pressure. The cases with the step-ionization agree well with the tendency of experimental measurement. The electron energy distribution functions show that the population of electrons having intermediate energy from 4.2 to 12 eV is relaxed by the step-ionization. Also, it was observed that the power consumption by the electrons is increasing with the increase of gas pressure by the step-ionization process, while the power consumption by the ions decreases with the increase of gas pressure.

Mechanical properties and thermal shock performance of W-Y2O3 composite prepared by high-energy-rate forging

NASA Astrophysics Data System (ADS)

Lian, Youyun; Liu, Xiang; Feng, Fan; Song, Jiupeng; Yan, Binyou; Wang, Yingmin; Wang, Jianbao; Chen, Jiming

2017-12-01

The effects of the addition of Y2O3 and hot-deformation on the mechanical properties of tungsten (W) have been studied. The processing route comprises a doping technique for the distribution of Y2O3 particles in a tungsten matrix, conventional sintering in a hydrogen environment, and high-energy-rate forging (HERF). The microstructure of the composite was characterized by using transmission electron microscopy and electron backscattering diffraction imaging technique, and its mechanical properties were studied by means of tensile testing. The thermal shock response of the HERF processed W-Y2O3 was evaluated by applying edge-localized mode-like loads (100 pulses) with a pulse duration of 1 ms and an absorbed power density of up to 1 GW m-2 at various temperatures between room temperature and 200 °C. HERF processing has produced elongated W grains with preferred orientations and a high density of structure defects in the composite. The composite material exhibits high tensile strength and good ductility, and a thermal shock cracking threshold lower than 100 °C.

High precision Hugoniot measurements on statically pre-compressed fluid helium

DOE PAGES

Seagle, Christopher T.; Reinhart, William D.; Lopez, Andrew J.; ...

2016-09-27

Here we describe how the capability for statically pre-compressing fluid targets for Hugoniot measurements utilizing gas gun driven flyer plates has been developed. Pre-compression expands the capability for initial condition control, allowing access to thermodynamic states off the principal Hugoniot. Absolute Hugoniot measurements with an uncertainty less than 3% on density and pressure were obtained on statically pre-compressed fluid helium utilizing a two stage light gas gun. Helium is highly compressible; the locus of shock states resulting from dynamic loading of an initially compressed sample at room temperature is significantly denser than the cryogenic fluid Hugoniot even for relatively modestmore » (0.27–0.38 GPa) initial pressures. Lastly, the dynamic response of pre-compressed helium in the initial density range of 0.21–0.25 g/cm3 at ambient temperature may be described by a linear shock velocity (us) and particle velocity (u p) relationship: u s = C 0 + su p, with C 0 = 1.44 ± 0.14 km/s and s = 1.344 ± 0.025.« less

Thermophysical properties of heat-treated U-7Mo/Al dispersion fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cho, Tae Won; Kim, Yeon Soo; Park, Jong Man

In this study, the effects of interaction layer (IL) on thermophysical properties of U-7Mo/Al dispersion fuel were examined. Microstructural analyses revealed that ILs were formed uniformly on U-Mo particles during heating of U-7Mo/Al samples. The IL volume fraction was measured by applying image analysis methods. The uranium loadings of the samples were calculated based on the measured meat densities at 298 K. The density of the IL was estimated by using the measured density and IL volume fraction. Thermal diffusivity and heat capacity of the samples after the heat treatment were measured as a function of temperature and volume fractionsmore » of U-Mo and IL. The thermal conductivity of IL-formed U-7Mo/Al was derived by using the measured thermal diffusivity, heat capacity, and density. The thermal conductivity obtained in the present study was lower than that predicted by the modified Hashin–Shtrikman model due to the theoretical model’s inability to consider the thermal resistance at interfaces between the meat constituents.« less

Effect of the Conditions of the Nanostructuring Frictional Treatment Process on the Structural and Phase States and the Strengthening of Metastable Austenitic Steel

NASA Astrophysics Data System (ADS)

Makarov, A. V.; Skorynina, P. A.; Yurovskikh, A. S.; Osintseva, A. L.

2017-12-01

The effect of the multiplicity of frictional loading with a sliding synthetic diamond indenter at room temperature in an argon medium and the temperature of loading in the range of -196 to +250°C on the phase composition, fine structure, and micromechanical properties of the surface layer of metastable austenitic chromium-nickel steel has been studied. It has been established that the completeness of the strain-induced martensitic γ → α' transformation in the surface layer of steel is determined by the loading multiplicity and temperature, as well as the level of strengthening grows with an increase in the frictional loading multiplicity, but weakly depends on the frictional treatment temperature. According to the microindentation data, the characteristics of the surface layer strength and resistance to elastic and plastic deformation are improved with an increase in the frictional loading multiplicity. Frictional treatment by scanning with a synthetic diamond indenter at room and negative temperatures provides high quality for the treated surface with a low roughness parameter ( Ra = 80.115 nm), and an increase in the frictional loading temperature to 150-250°C leads to the development of a seizure and growth in Ra to 195-255 nm. Using transmission electron microscopy (TEM), it has been shown that frictional treatment results in the formation of nanocrystalline and fragmented submicrocrystalline structures of strain-induced α'-martensite (at a loading temperature of -196°C) and austenite (at a loading temperature of +250°C) in the surface layer of steel alongside with two-phase martensitic-austenitic structures (at a loading temperature of +20°C).

Effects of rearing density and raceway conformation on growth, food conversion, and survival of juvenile spring chinook salmon

USGS Publications Warehouse

Ewing, R.D.; Sheahan, J.E.; Lewis, M.A.; Palmisano, Aldo N.

2000-01-01

Four brood years of juvenile spring chinook salmon Oncorhynchus tshawytscha were reared in conventional and baffled raceways at various rearing densities and loads at Willamette Hatchery, Oregon. A period of rapid linear growth occurred from August to November, but there was little or no growth from November to March when the fish were released. Both fall and winter growth rates were inversely related to rearing density. Final weight and length were also inversely related to rearing density. No significant relationship between load and any growth variable was observed. Fish reared at lower densities in conventional raceways tended to develop bimodal length distributions in winter and early spring. Fish reared in conventional raceways showed significantly larger growth rates and final lengths and weights than those reared in baffled raceways. Food conversions and average delivery times for feed were significantly greater in baffled than in conventional raceways. No significant relationships were observed between either rearing density or load and condition factor, food conversion, or mortality. Mortality was not significantly different between the two raceway types. When fish were transported to seawater for further rearing, there were no significant relationships between mortality in seawater and rearing density or load, but fish reared in baffled raceways had significantly higher mortality than those reared in conventional raceways.

Use of Guided Acoustic Waves to Assess the Effects of Thermal-Mechanical Cycling on Composite Stiffness

NASA Technical Reports Server (NTRS)

Seale, Michael D.; Madaras, Eric I.

2000-01-01

The introduction of new, advanced composite materials into aviation systems requires it thorough understanding of the long-term effects of combined thermal and mechanical loading. As part of a study to evaluate the effects of thermal-mechanical cycling, it guided acoustic (Lamb) wave measurement system was used to measure the bending and out-of-plane stiffness coefficients of composite laminates undergoing thermal-mechanical loading. The system uses a pulse/receive technique that excites an antisymmetric Lamb mode and measures the time-of-flight over a wide frequency range. Given the material density and plate thickness, the bending and out-of-plane shear stiffnesses are calculated from a reconstruction of the velocity dispersion curve. A series of 16 and 32-ply composite laminates were subjected to it thermal-mechanical loading profile in load frames equipped with special environmental chambers. The composite systems studied were it graphite fiber reinforced amorphous thermoplastic polyimide and it graphite fiber reinforced bismaleimide thermoset. The samples were exposed to both high and low temperature extremes its well as high and low strain profiles. The bending and out-of-plane stiffnesses for composite sample that have undergone over 6,000 cycles of thermal-mechanical loading are reported. The Lamb wave generated elastic stiffness results have shown decreases of up to 20% at 4,936 loading cycles for the graphite/thermoplastic samples and up to 64% at 4,706 loading cycles for the graphite/thermoset samples.

A 5.2 mu text{A} Quiescent Current LDO Regulator With High Stability and Wide Load Range for CZT Detectors

NASA Astrophysics Data System (ADS)

Fan, Shiquan; Li, Haiqi; Guo, Zhuoqi; Geng, Li

2017-04-01

Cadmium zinc telluride detectors are the highly considered for room-temperature hard X-ray and gamma-ray detection. The readout systems are needed in the detectors to output the detecting data. The features of power supplies are very important for the readout circuits. In this paper, a low-dropout (LDO) regulator with very low power consumption and wide load variation is presented. A combining compensation method which includes partially controlled load-tracking technique and equivalent series resistance compensation technique are proposed to enhance the loop stability of the LDO regulator. Meanwhile, high dc gain is obtained to improve the power supply ripple rejection (PSRR), which can decrease the noise from the power supply. The prototype LDO chip has been fabricated and tested with a standard 0.18-μm CMOS technology. The measured results show that the LDO regulator can provide up to 150 mA load current with a stable output voltage of 2.8 V under an input voltage scope from 2.9 to 3.6 V. The measured PSRR is up to -60 dB. The output noise spectral densities are 1.16 μVRMS/√Hz and 211 nVRMS/√Hz at 1 and 100 kHz, respectively, at load current of 150 mA. Especially, the ultralow quiescent currents of 5.2 μA at no load and 18.2 μA at full load bring great benefit to the ultralow power integrated readout systems.

Characterization of a New Phase and Its Effect on the Work Characteristics of a Near-Stoichiometric Ni30Pt20Ti50 High-Temperature Shape Memory Alloy (HTSMA)

NASA Technical Reports Server (NTRS)

Garg, A.; Gaydosh, D.; Noebe, R.D.; Padula II, Santo; Bigelow, G.S.; Kaufman, M.; Kovarik, L.; Mills, M.J.; Diercks, D.; McMurray, S.

2008-01-01

A new phase observed in a nominal Ni30Pt20Ti50 (at.%) high temperature shape memory alloy has been characterized using transmission electron microscopy and 3-D atom probe tomography. This phase forms homogeneously in the B2 austenite matrix by a nucleation and growth mechanism and results in a concomitant increase in the martensitic transformation temperature of the base alloy. Although the structure of this phase typically contains a high density of faults making characterization difficult, it appears to be trigonal (-3m point group) with a(sub o) approx. 1.28 nm and c(sub o) approx. 1.4 nm. Precipitation of this phase increases the microhardness of the alloy substantially over that of the solution treated and quenched single-phase material. The effect of precipitation strengthening on the work characteristics of the alloy has been explored through load-biased strain-temperature testing in the solution-treated condition and after aging at 500 C for times ranging from 1 to 256 hours. Work output was found to increase in the aged alloy as a result of an increase in transformation strain, but was not very sensitive to aging time. The amount of permanent deformation that occurred during thermal cycling under load was small but increased with increasing aging time and stress. Nevertheless, the dimensional stability of the alloy at short aging times (1-4 hours) was still very good making it a potentially useful material for high-temperature actuator applications.

A Novel Creep-Fatigue Life Prediction Model for P92 Steel on the Basis of Cyclic Strain Energy Density

NASA Astrophysics Data System (ADS)

Ji, Dongmei; Ren, Jianxing; Zhang, Lai-Chang

2016-11-01

A novel creep-fatigue life prediction model was deduced based on an expression of the strain energy density in this study. In order to obtain the expression of the strain energy density, the load-controlled creep-fatigue (CF) tests of P92 steel at 873 K were carried out. Cyclic strain of P92 steel under CF load was divided into elastic strain, applying and unloading plastic strain, creep strain, and anelastic strain. Analysis of cyclic strain indicates that the damage process of P92 steel under CF load consists of three stages, similar to pure creep. According to the characteristics of the strains above, an expression was defined to describe the strain energy density for each cycle. The strain energy density at stable stage is inversely proportional to the total strain energy density dissipated by P92 steel. However, the total strain energy densities under different test conditions are proportional to the fatigue life. Therefore, the expression of the strain energy density at stable stage was chosen to predict the fatigue life. The CF experimental data on P92 steel were employed to verify the rationality of the novel model. The model obtained from the load-controlled CF test of P92 steel with short holding time could predict the fatigue life of P92 steel with long holding time.

Concurrent Solution and Adsorption of Hydrocarbons in Gas Chromatographic Columns Packed with Different Loadings of 3-Methylsydnone on Chromosorb P

PubMed

Castells; Romero; Nardillo

1997-08-01

Thermodynamic properties of solution in 3-methylsydnone (3MS) and of adsorption at the nitrogen/3MS interface were gas chromatographically measured for a group of fifteen hydrocarbons at infinite dilution conditions. Retention volumes were measured at five temperatures within the range 37-52°C in six columns containing different loadings of 3MS on Chromosorb P AW. Partition and adsorption coefficients were calculated and from their temperature dependence the corresponding enthalpies were obtained, although with considerable error; infinite dilution activity coefficients of the hydrocarbons in the bulk and in the surface phases demonstrated a strong correlation. Bulk activity coefficients in 3MS were very much smaller than those previously measured for the same solutes in formamide (FA) and in ethyleneglycol (EG), and were also smaller than what could be predicted on account of 3MS cohesive energy density as estimated from the quotient sigma/v1/3 (sigma, surface tension; v, molar volume). There was not such a large difference between the surface activity coefficients in the three solvents; furthermore, the quotients (surface activity coefficient/bulk activity coefficient) for a given solute in 3MS were twice as large as in FA and about three times larger than in EG. These results make evident the difficulties inherent in the prediction of surface phase properties from those in the bulk and cast doubts on the pertinency of employing the surface tension to compare cohesive energy densities of polar solvents with important chemical differences.

Nanogranular origin of concrete creep.

PubMed

Vandamme, Matthieu; Ulm, Franz-Josef

2009-06-30

Concrete, the solid that forms at room temperature from mixing Portland cement with water, sand, and aggregates, suffers from time-dependent deformation under load. This creep occurs at a rate that deteriorates the durability and truncates the lifespan of concrete structures. However, despite decades of research, the origin of concrete creep remains unknown. Here, we measure the in situ creep behavior of calcium-silicate-hydrates (C-S-H), the nano-meter sized particles that form the fundamental building block of Portland cement concrete. We show that C-S-H exhibits a logarithmic creep that depends only on the packing of 3 structurally distinct but compositionally similar C-S-H forms: low density, high density, ultra-high density. We demonstrate that the creep rate ( approximately 1/t) is likely due to the rearrangement of nanoscale particles around limit packing densities following the free-volume dynamics theory of granular physics. These findings could lead to a new basis for nanoengineering concrete materials and structures with minimal creep rates monitored by packing density distributions of nanoscale particles, and predicted by nanoscale creep measurements in some minute time, which are as exact as macroscopic creep tests carried out over years.

Nanogranular origin of concrete creep

PubMed Central

Vandamme, Matthieu; Ulm, Franz-Josef

2009-01-01

Concrete, the solid that forms at room temperature from mixing Portland cement with water, sand, and aggregates, suffers from time-dependent deformation under load. This creep occurs at a rate that deteriorates the durability and truncates the lifespan of concrete structures. However, despite decades of research, the origin of concrete creep remains unknown. Here, we measure the in situ creep behavior of calcium–silicate–hydrates (C–S–H), the nano-meter sized particles that form the fundamental building block of Portland cement concrete. We show that C–S–H exhibits a logarithmic creep that depends only on the packing of 3 structurally distinct but compositionally similar C–S–H forms: low density, high density, ultra-high density. We demonstrate that the creep rate (≈1/t) is likely due to the rearrangement of nanoscale particles around limit packing densities following the free-volume dynamics theory of granular physics. These findings could lead to a new basis for nanoengineering concrete materials and structures with minimal creep rates monitored by packing density distributions of nanoscale particles, and predicted by nanoscale creep measurements in some minute time, which are as exact as macroscopic creep tests carried out over years. PMID:19541652

The influence of void and porosity on deformation behaviour of nanocrystalline Ni under tensile followed by compressive loading

NASA Astrophysics Data System (ADS)

Meraj, Md.; Nayak, Shradha; Krishanjeet, Kumar; Pal, Snehanshu

2018-03-01

In this paper, we present a lucid understanding about the deformation behaviour of nanocrystalline (NC) Ni with and without defects subjected to tensile followed by compressive loading using molecular dynamic (MD) simulations. The embedded atom method (EAM) potential have been incorporated in the simulation for three kinds of samples-i.e. for NC Ni (without any defect), porous NC Ni and NC Ni containing a centrally located void. All the three samples, which have been prepared by implementing the Voronoi method and using Atom Eye software, consist of 16 uniform grains. The total number of atoms present in NC Ni, porous NC Ni and NC Ni containing a void are 107021, 105968 and 107012 respectively. The stress-strain response of NC Ni under tensile followed by compressive loading are simulated at a high strain rate of 107 s-1 and at a constant temperature of 300K. The stress-strain curves for the NC Ni with and without defects have been plotted for three different types of loading: (a) tensile loading (b) compressive loading (c) forward tensile loading followed by reverse compressive loading. Prominent change in yield strength of the NC Ni is observed due to the introduction of defects. For tensile followed by compressive loading (during forward loading), the yield point for NC Ni with void is lesser than the yield point of NC Ni and porous NC Ni. The saw tooth shape or serration portion of the stress-strain curve is mainly due to three characteristic phenomena, dislocation generation and its movement, dislocation pile-up at the junctions, and dislocation annihilation. Both twins and stacking faults are observed due to plastic deformation as the deformation mechanism progresses. The dislocation density, number of clusters and number of vacancy of the NC sample with and without defects are plotted against the strain developed in the sample. It is seen that introduction of defects brings about change in mechanical properties of the NC Ni. The crystalline nature of NC Ni is found to decrease with introduction of defects. The findings of this work can thus be extended in bringing a whole new insight related to the deformation behaviour and properties of Nano- materials during cyclic deformation at various temperatures.

Performance prediction for a magnetostrictive actuator using a simplified model

NASA Astrophysics Data System (ADS)

Yoo, Jin-Hyeong; Jones, Nicholas J.

2018-03-01

Iron-Gallium alloys (Galfenol) are promising transducer materials that combine high magnetostriction, desirable mechanical properties, high permeability, and a wide operational temperature range. Most of all, the material is capable of operating under tensile stress, and is relatively resistant to shock. These materials are generally characterized using a solid, cylindrically-shaped specimen under controlled compressive stress and magnetization conditions. Because the magnetostriction strongly depends on both the applied stress and magnetization, the characterization of the material is usually conducted under controlled conditions so each parameter is varied independently of the other. However, in a real application the applied stress and magnetization will not be maintained constant during operation. Even though the controlled characterization measurement gives insight into standard material properties, usage of this data in an application, while possible, is not straight forward. This study presents an engineering modeling methodology for magnetostrictive materials based on a piezo-electric governing equation. This model suggests phenomenological, nonlinear, three-dimensional functions for strain and magnetic flux density responses as functions of applied stress and magnetic field. Load line performances as a function of maximum magnetic field input were simulated based on the model. To verify the modeling performance, a polycrystalline magnetostrictive rod (Fe-Ga alloy, Galfenol) was characterized under compressive loads using a dead-weight test setup, with strain gages on the rod and a magnetic field driving coil around the sample. The magnetic flux density through the Galfenol rod was measured with a sensing coil; the compressive loads were measured using a load cell on the bottom of the Galfenol rod. The experimental results are compared with the simulation results using the suggested model, showing good agreement.

An Electrothermal Plasma Source Developed for Simulation of Transient Heat Loads in Future Large Fusion Devices

NASA Astrophysics Data System (ADS)

Gebhart, Trey; Baylor, Larry; Winfrey, Leigh

2016-10-01

The realization of fusion energy requires materials that can withstand high heat and particle fluxes at the plasma material interface. In this work, an electrothermal (ET) plasma source has been designed as a possible transient heat flux source for a linear plasma material interaction device. An ET plasma source operates in the ablative arc regime, which is driven by a DC capacitive discharge. The current travels through the 4mm bore of a boron nitride liner and subsequently ablates and ionizes the liner material. This results in a high density plasma with a large unidirectional bulk flow out of the source exit. The pulse length for the ET source has been optimized using a pulse forming network to have a duration of 1ms at full-width half maximum. The peak currents and maximum source energies seen in this system are 2kA and 5kJ. The goal of this work is to show that the ET source produces electron densities and heat fluxes that are comparable to transient events in future large magnetic confinement fusion devices. Heat flux, plasma temperature, and plasma density were determined for each test shot using infrared imaging and optical spectroscopy techniques. This work will compare the ET source output (heat flux, temperature, and density) with and without an applied magnetic field. Research sponsored by the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U. S. Department of Energy.

Time- and temperature-dependent failures of a bonded joint

NASA Astrophysics Data System (ADS)

Sihn, Sangwook

This dissertation summarizes my study of time- and temperature-dependent behavior of a tubular lap bonded joint to provide a design methodology for windmill blade structures. The bonded joint is between a cast-iron rod and a GFRP composite pipe. The adhesive material is an epoxy containing chopped glass fibers. We proposed a new fabrication method to make concentric and void-less specimens of the tubular joint with a thick adhesive bondline to stimulate the root bond of a blade. The thick bondline facilitates the joint assembly of actual blades. For a better understanding of the behavior of the bonded joint, we studied viscoelastic behavior of the adhesive materials by measuring creep compliance at several temperatures during loading period. We observed that the creep compliance depends highly on the period of loading and the temperature. We applied time-temperature equivalence to the creep compliance of the adhesive material to obtain time-temperature shift factors. We also performed constant-rate of monotonically increased uniaxial tensile tests to measure static strength of the tubular lap joint at several temperatures and different strain-rates. We observed two failure modes from load-deflection curves and failed specimens. One is the brittle mode, which was caused by weakness of the interfacial strength occurring at low temperature and short period of loading. The other is the ductile mode, which was caused by weakness of the adhesive material at high temperature and long period of loading. Transition from the brittle to the ductile mode appeared as the temperature or the loading period increased. We also performed tests under uniaxial tensile-tensile cyclic loadings to measure fatigue strength of the bonded joint at several temperatures, frequencies and stress ratios. The fatigue data are analyzed statistically by applying the residual strength degradation model to calculate statistical distribution of the fatigue life. Combining the time-temperature equivalence and the residual strength degradation model enables us to estimate the fatigue life of the bonded joint at different load levels, frequencies and temperatures with a certain probability. A numerical example shows how to apply the life estimation method to a structure subjected to a random load history by rainflow cycle counting.

Physiochemical Characterization of Briquettes Made from Different Feedstocks

PubMed Central

Karunanithy, C.; Wang, Y.; Muthukumarappan, K.; Pugalendhi, S.

2012-01-01

Densification of biomass can address handling, transportation, and storage problems and also lend itself to an automated loading and unloading of transport vehicles and storage systems. The purpose of this study is to compare the physicochemical properties of briquettes made from different feedstocks. Feedstocks such as corn stover, switchgrass, prairie cord grass, sawdust, pigeon pea grass, and cotton stalk were densified using a briquetting system. Physical characterization includes particle size distribution, geometrical mean diameter (GMD), densities (bulk and true), porosity, and glass transition temperature. The compositional analysis of control and briquettes was also performed. Statistical analyses confirmed the existence of significant differences in these physical properties and chemical composition of control and briquettes. Correlation analysis confirms the contribution of lignin to bulk density and durability. Among the feedstocks tested, cotton stalk had the highest bulk density of 964 kg/m3 which is an elevenfold increase compared to control cotton stalk. Corn stover and pigeon pea grass had the highest (96.6%) and lowest (61%) durability. PMID:22792471

Effect of the thickness of the anode electrode catalyst layers on the performance in direct methanol fuel cells

NASA Astrophysics Data System (ADS)

Glass, Dean E.; Olah, George A.; Prakash, G. K. Surya

2017-06-01

For the large scale fuel cell manufacture, the catalyst loading and layer thickness are critical factors affecting the performance and cost of membrane electrode assemblies (MEAs). The influence of catalyst layer thicknesses at the anode of a PEM based direct methanol fuel cell (DMFC) has been investigated. Catalysts were applied with the drawdown method with varied thicknesses ranging from 1 mil to 8 mils (1 mil = 25.4 μm) with a Pt/Ru anode loading of 0.25 mg cm-2 to 2.0 mg cm-2. The MEAs with the thicker individual layers (8 mils and 4 mils) performed better overall compared to the those with the thinner layers (1 mil and painted). The peak power densities for the different loading levels followed an exponential decrease of Pt/Ru utilization at the higher loading levels. The highest power density achieved was 49 mW cm-2 with the 4 mil layers at 2.0 mg cm-2 catalyst loading whereas the highest normalized power density was 116 mW mg-1 with the 8 mil layers at 0.25 mg cm-2 loading. The 8 mil drawdowns displayed a 50% and 23% increase in normalized power density compared to the 1 mil drawdowns at 0.25 mg cm-2 and 0.5 mg cm-2 loadings, respectively.

Load Forecasting of Central Urban Area Power Grid Based on Saturated Load Density Index

NASA Astrophysics Data System (ADS)

Huping, Yang; Chengyi, Tang; Meng, Yu

2018-03-01

In the current society, coordination between urban power grid development and city development has become more and more prominent. Electricity saturated load forecasting plays an important role in the planning and development of power grids. Electricity saturated load forecasting is a new concept put forward by China in recent years in the field of grid planning. Urban saturation load forecast is different from the traditional load forecasting method for specific years, the time span of it often relatively large, and involves a wide range of aspects. This study takes a county in eastern Jiangxi as an example, this paper chooses a variety of load forecasting methods to carry on the recent load forecasting calculation to central urban area. At the same time, this paper uses load density index method to predict the Longterm load forecasting of electric saturation load of central urban area lasted until 2030. And further study shows the general distribution of the urban saturation load in space.

Fatigue Behavior of Glass Fiber-Reinforced Polymer Bars after Elevated Temperatures Exposure.

PubMed

Li, Guanghui; Zhao, Jun; Wang, Zike

2018-06-16

Fiber-reinforced polymer (FRP) bars have been widely applied in civil engineering. This paper presents the results of an experimental study to investigate the tensile fatigue mechanical properties of glass fiber-reinforced polymer (GFRP) bars after elevated temperatures exposure. For this purpose, a total of 105 GFRP bars were conducted for testing. The specimens were exposed to heating regimes of 100, 150, 200, 250, 300 and 350 °C for a period of 0, 1 or 2 h. The GFRP bars were tested with different times of cyclic load after elevated temperatures exposure. The results show that the tensile strength and elastic modulus of GFRP bars decrease with the increase of elevated temperature and holding time, and the tensile strength of GFRP bars decreases obviously by 19.5% when the temperature reaches 250 °C. Within the test temperature range, the tensile strength of GFRP bars decreases at most by 28.0%. The cyclic load accelerates the degradation of GFRP bars after elevated temperature exposure. The coupling of elevated temperature and holding time enhance the degradation effect of cyclic load on GFRP bars. The tensile strength of GFRP bars after elevated temperatures exposure at 350 °C under cyclic load is reduced by 50.5% compared with that at room temperature and by 36.3% compared with that after exposing at 350 °C without cyclic load. In addition, the elastic modulus of GFRP bars after elevated temperatures exposure at 350 °C under cyclic load is reduced by 17.6% compared with that at room temperature and by 6.0% compared with that after exposing at 350 °C without cyclic load.

Correlation of cervical endplate strength with CT measured subchondral bone density

PubMed Central

Ordway, Nathaniel R.; Lu, Yen-Mou; Zhang, Xingkai; Cheng, Chin-Chang; Fang, Huang

2007-01-01

Cervical interbody device subsidence can result in screw breakage, plate dislodgement, and/or kyphosis. Preoperative bone density measurement may be helpful in predicting the complications associated with anterior cervical surgery. This is especially important when a motion preserving device is implanted given the detrimental effect of subsidence on the postoperative segmental motion following disc replacement. To evaluate the structural properties of the cervical endplate and examine the correlation with CT measured trabecular bone density. Eight fresh human cadaver cervical spines (C2–T1) were CT scanned and the average trabecular bone densities of the vertebral bodies (C3–C7) were measured. Each endplate surface was biomechanically tested for regional yield load and stiffness using an indentation test method. Overall average density of the cervical vertebral body trabecular bone was 270 ± 74 mg/cm3. There was no significant difference between levels. The yield load and stiffness from the indentation test of the endplate averaged 139 ± 99 N and 156 ± 52 N/mm across all cervical levels, endplate surfaces, and regional locations. The posterior aspect of the endplate had significantly higher yield load and stiffness in comparison to the anterior aspect and the lateral aspect had significantly higher yield load in comparison to the midline aspect. There was a significant correlation between the average yield load and stiffness of the cervical endplate and the trabecular bone density on regression analysis. Although there are significant regional variations in the endplate structural properties, the average of the endplate yield loads and stiffnesses correlated with the trabecular bone density. Given the morbidity associated with subsidence of interbody devices, a reliable and predictive method of measuring endplate strength in the cervical spine is required. Bone density measures may be used preoperatively to assist in the prediction of the strength of the vertebral endplate. A threshold density measure has yet to be established where the probability of endplate fracture outweighs the benefit of anterior cervical procedure. PMID:17712574

Control and monitoring of codling moth (Lepidoptera: Tortricidae) in walnut orchards treated with novel high-load, low-density “meso” dispensers of sex pheromone and pear ester

USDA-ARS?s Scientific Manuscript database

Novel low-density per ha “meso” dispensers loaded with both pear ester, ethyl (E,Z)-2,4-decadienoate, kairomone and codlemone, (E,E)-8,10-dodecadien-1-ol, the sex pheromone of codling moth, Cydia pomonella (L)., were evaluated versus meso dispensers loaded with pheromone-alone for their mating disru...

The effect of mass loading on the temperature of a flowing plasma. [in vicinity of Io

NASA Technical Reports Server (NTRS)

Linker, Jon A.; Kivelson, Margaret G.; Walker, Raymond J.

1989-01-01

How the addition of ions at rest (mass loading) affects the temperature of a flowing plasma in a MHD approximation is investigated, using analytic theory and time dependent, three-dimensional MHD simulations of plasma flow past Io. The MHD equations show that the temperature can increase or decrease relative to the background, depending on the local sonic Mach number M(S), of the flow. For flows with M(S) of greater than sq rt 9/5 (when gamma = 5/3), mass loading increases the plasma temperature. However, the simulations show a nonlinear response to the addition of mass. If the mass loading rate is large enough, the temperature increase may be smaller than expected, or the temperature may actually decrease, because a large mass loading rate slows the flow and decreases the thermal energy of the newly created plasma.

Detecting Damage in Ceramic Matrix Composites Using Electrical Resistance

NASA Technical Reports Server (NTRS)

Smith, Craig E.; Gyekenyesi, Andrew

2011-01-01

The majority of damage in SiC/SiC ceramic matrix composites subjected to monotonic tensile loads is in the form of distributed matrix cracks. These cracks initiate near stress concentrations, such as 90 deg fiber tows or large matrix pores and continue to accumulate with additional stress until matrix crack saturation is achieved. Such damage is difficult to detect with conventional nondestructive evaluation techniques (immersion ultrasonics, x-ray, etc.). Monitoring a specimen.s electrical resistance change provides an indirect approach for monitoring matrix crack density. Sylramic-iBN fiber- reinforced SiC composites with a melt infiltrated (MI) matrix were tensile tested at room temperature. Results showed an increase in resistance of more than 500% prior to fracture, which can be detected either in situ or post-damage. A relationship between resistance change and matrix crack density was also determined.

Detecting Cracks in Ceramic Matrix Composites by Electrical Resistance

NASA Technical Reports Server (NTRS)

Smith, Craig; Gyekenyesi, Andrew

2011-01-01

The majority of damage in SiC/SiC ceramic matrix composites subjected to monotonic tensile loads is in the form of distributed matrix cracks. These cracks initiate near stress concentrations, such as 90o fiber tows or large matrix pores and continue to accumulate with additional stress until matrix crack saturation is achieved. Such damage is difficult to detect with conventional nondestructive evaluation techniques (immersion ultrasonics, x-ray, etc.). Monitoring a specimen.s electrical resistance change provides an indirect approach for monitoring matrix crack density. Sylramic-iBN fiber- reinforced SiC composites with a melt infiltrated (MI) matrix were tensile tested at room temperature. Results showed an increase in resistance of more than 500% prior to fracture, which can be detected either in situ or post-damage. A relationship between resistance change and matrix crack density was also determined.

Statistical analysis and modeling of intermittent transport events in the tokamak scrape-off layer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anderson, Johan, E-mail: anderson.johan@gmail.com; Halpern, Federico D.; Ricci, Paolo

The turbulence observed in the scrape-off-layer of a tokamak is often characterized by intermittent events of bursty nature, a feature which raises concerns about the prediction of heat loads on the physical boundaries of the device. It appears thus necessary to delve into the statistical properties of turbulent physical fields such as density, electrostatic potential, and temperature, focusing on the mathematical expression of tails of the probability distribution functions. The method followed here is to generate statistical information from time-traces of the plasma density stemming from Braginskii-type fluid simulations and check this against a first-principles theoretical model. The analysis ofmore » the numerical simulations indicates that the probability distribution function of the intermittent process contains strong exponential tails, as predicted by the analytical theory.« less

Impact of ultra-low Pt loadings on the performance of anode/cathode in a proton-exchange membrane fuel cell

NASA Astrophysics Data System (ADS)

Billy, E.; Maillard, F.; Morin, A.; Guetaz, L.; Emieux, F.; Thurier, C.; Doppelt, P.; Donet, S.; Mailley, S.

This study focuses on the elaboration of PEMFC electrodes containing ultra-low platinum (Pt) loadings by direct liquid injection metal organic chemical vapor deposition (DLI-MOCVD). DLI-MOCVD offers a large number of advantages for the elaboration of model PEMFC electrodes. First, by using different metal precursors or elaboration temperature, the size of the Pt nanoparticles and thus the intrinsic catalytic activity can easily be tailored in the nanometer range. In this work, Pt nanoparticles (1-5 nm) with remarkable low degree of agglomeration and uniform distribution were deposited onto the microporous side of a commercial gas-diffusion layer (GDL). Second, reduction of the Pt loading is made possible by varying the Pt deposition time and its influence of the cell performance can be extracted without variation of the thickness of the catalytic layer (in previous studies, a decrease of the catalyst utilization was observed when increasing the Pt loading, i.e. the thickness of the catalytic layer (CL)). The electrocatalytic activity of home-made Pt nanoparticles elaborated by DLI-MOCVD was measured in liquid electrolyte or in complete fuel cell operating on H 2/O 2 or H 2/air and compared vs. that of a commercially available electrode containing 500 μg Pt cm -2 (Pt Ref500). At the cathode, the performance of the electrodes containing 104-226 μg of Pt per cm 2 of electrode compares favorably with that of the Pt Ref500 in H 2/O 2 conditions. In H 2/air conditions, additional mass-transport losses are detected in the low-current density region but the high effectiveness of our electrodes improves the performance in the high-current density region. At the anode, the Pt loading can be reduced to 35 μg Pt cm -2 without any voltage loss in agreement with previous observations.

Shock-adiabatic to quasi-isentropic compression of warm dense helium up to 150 GPa

NASA Astrophysics Data System (ADS)

Zheng, J.; Chen, Q. F.; Gu, Y. J.; Li, J. T.; Li, Z. G.; Li, C. J.; Chen, Z. Y.

2017-06-01

Multiple reverberation compression can achieve higher pressure, higher temperature, but lower entropy. It is available to provide an important validation for the elaborate and wider planetary models and simulate the inertial confinement fusion capsule implosion process. In the work, we have developed the thermodynamic and optical properties of helium from shock-adiabatic to quasi-isentropic compression by means of a multiple reverberation technique. By this technique, the initial dense gaseous helium was compressed to high pressure and high temperature and entered the warm dense matter (WDM) region. The experimental equation of state (EOS) of WDM helium in the pressure-density-temperature (P-ρ -T) range of 1 -150 GPa , 0.1 -1.1 g c m-3 , and 4600-24 000 K were measured. The optical radiations emanating from the WDM helium were recorded, and the particle velocity profiles detecting from the sample/window interface were obtained successfully up to 10 times compression. The optical radiation results imply that dense He has become rather opaque after the 2nd compression with a density of about 0.3 g c m-3 and a temperature of about 1 eV. The opaque states of helium under multiple compression were analyzed by the particle velocity measurements. The multiple compression technique could efficiently enhanced the density and the compressibility, and our multiple compression ratios (ηi=ρi/ρ0,i =1 -10 ) of helium are greatly improved from 3.5 to 43 based on initial precompressed density (ρ0) . For the relative compression ratio (ηi'=ρi/ρi -1) , it increases with pressure in the lower density regime and reversely decreases in the higher density regime, and a turning point occurs at the 3rd and 4th compression states under the different loading conditions. This nonmonotonic evolution of the compression is controlled by two factors, where the excitation of internal degrees of freedom results in the increasing compressibility and the repulsive interactions between the particles results in the decreasing compressibility at the onset of electron excitation and ionization. In the P-ρ -T contour with the experiments and the calculations, our multiple compression states from insulating to semiconducting fluid (from transparent to opaque fluid) are illustrated. Our results give an elaborate validation of EOS models and have applications for planetary and stellar opaque atmospheres.

Estradiol-loaded PLGA nanoparticles for improving low bone mineral density of cancellous bone caused by osteoporosis: Application of enhanced charged nanoparticles with iontophoresis.

PubMed

Takeuchi, Issei; Kobayashi, Shiori; Hida, Yukari; Makino, Kimiko

2017-07-01

Postmenopausal osteoporosis among older women, which occurs by an ovarian hormone deficiency, is one of the major public health problems. 17 β-estradiol (E2) is used to prevent and treat this disease as a drug of hormone replacement therapy. In oral administration, E2 is significantly affected by first-pass hepatic metabolism, and high dose administration must be needed to obtain drug efficacy. Therefore, alternative administration route is needed, and we have focused on the transdermal drug delivery system. In this study, we have prepared E2-loaded poly(DL-lactide-co-glycolide) (PLGA) nanoparticles for osteoporosis by using a combination of an antisolvent diffusion method with preferential solvation. The average particle diameter of the nanoparticles was 110.0±41.0nm and the surface charge number density was 82 times higher than that of conventional E2-loaded PLGA nanoparticles. Therapeutic evaluation of E2-loaded PLGA nanoparticles was carried out using ovariectomized female rats. Therapeutic efficacy was evaluated to measure bone mineral density of cancellous bone using an X-ray CT system. When the E2-loaded PLGA nanoparticles were administrated once a week, bone mineral density was significantly higher than that of the non-treated group at 60days after the start of treatment. Also, in the group administered this nanoparticle twice a week, the bone mineral density increased significantly at 45days after the start of treatment. From these results, it was revealed that E2-loaded PLGA nanoparticles with iontophoresis were useful to recover bone mineral density of cancellous bone, and it was also suggested that they extend the dosing interval of E2. Copyright © 2017 Elsevier B.V. All rights reserved.

On rate-dependent polycrystal deformation: the temperature sensitivity of cold dwell fatigue

PubMed Central

Zhang, Zhen; Cuddihy, M. A.; Dunne, F. P. E.

2015-01-01

A temperature and rate-dependent crystal plasticity framework has been used to examine the temperature sensitivity of stress relaxation, creep and load shedding in model Ti-6Al polycrystal behaviour under dwell fatigue conditions. A temperature close to 120°C is found to lead to the strongest stress redistribution and load shedding, resulting from the coupling between crystallographic slip rate and slip system dislocation hardening. For temperatures in excess of about 230°C, grain-level load shedding from soft to hard grains diminishes because of the more rapid stress relaxation, leading ultimately to the diminution of the load shedding and hence, it is argued, the elimination of the dwell debit. Under conditions of cyclic stress dwell, at temperatures between 20°C and 230°C for which load shedding occurs, the rate-dependent accumulation of local slip by ratcheting is shown to lead to the progressive cycle-by-cycle redistribution of stress from soft to hard grains. This phenomenon is termed cyclic load shedding since it also depends on the material's creep response, but develops over and above the well-known dwell load shedding, thus providing an additional rationale for the incubation of facet nucleation. PMID:26528078

Computational fluid dynamics modeling of bun baking process under different oven load conditions.

PubMed

Tank, A; Chhanwal, N; Indrani, D; Anandharamakrishnan, C

2014-09-01

A computational fluid dynamics (CFD) model was developed to study the temperature profile of the bun during baking process. Evaporation-condensation mechanism and effect of the latent heat during phase change of water was incorporated in this model to represent actual bun baking process. Simulation results were validated with experimental measurements of bun temperature at two different positions. Baking process is completed within 20 min, after the temperature of crumb become stable at 98 °C. Further, this study was extended to investigate the effect of partially (two baking trays) loaded and fully loaded (eight baking trays) oven on temperature profile of bun. Velocity and temperature profile differs in partially loaded and fully loaded oven. Bun placed in top rack showed rapid baking while bun placed in bottom rack showed slower baking due to uneven temperature distribution in the oven. Hence, placement of bun inside the oven affects temperature of bun and consequently, the quality of the product.

Platinum Nanoparticle Loading of Boron Nitride Aerogel and Its Use as a Novel Material for Low-Power Catalytic Gas Sensing

DOE PAGES

Harley-Trochimczyk, Anna; Pham, Thang; Chang, Jiyoung; ...

2015-12-09

We report that a high-surface-area, highly crystalline boron nitride aerogel synthesized with nonhazardous reactants has been loaded with crystalline platinum nanoparticles to form a novel nanomaterial that exhibits many advantages for use in a catalytic gas sensing application. The platinum nanoparticle-loaded boron nitride aerogel integrated onto a microheater platform allows for calorimetric propane detection. The boron nitride aerogel exhibits thermal stability up to 900 °C and supports disperse platinum nanoparticles, with no sintering observed after 24 h of high-temperature testing. The high thermal conductivity and low density of the boron nitride aerogel result in an order of magnitude faster responsemore » and recovery times (<2 s) than reported on alumina support and allow for 10% duty cycling of the microheater with no loss in sensitivity. Lastly, the resulting 1.5 mW sensor power consumption is two orders of magnitude less than commercially available catalytic gas sensors and unlocks the potential for wireless, battery-powered catalytic gas sensing.« less

Analysis of Composite Panels Subjected to Thermo-Mechanical Loads

NASA Technical Reports Server (NTRS)

Noor, Ahmed K.; Peters, Jeanne M.

1999-01-01

The results of a detailed study of the effect of cutout on the nonlinear response of curved unstiffened panels are presented. The panels are subjected to combined temperature gradient through-the-thickness combined with pressure loading and edge shortening or edge shear. The analysis is based on a first-order, shear deformation, Sanders-Budiansky-type shell theory with the effects of large displacements, moderate rotations, transverse shear deformation, and laminated anisotropic material behavior included. A mixed formulation is used with the fundamental unknowns consisting of the generalized displacements and the stress resultants of the panel. The nonlinear displacements, strain energy, principal strains, transverse shear stresses, transverse shear strain energy density, and their hierarchical sensitivity coefficients are evaluated. The hierarchical sensitivity coefficients measure the sensitivity of the nonlinear response to variations in the panel parameters, as well as in the material properties of the individual layers. Numerical results are presented for cylindrical panels and show the effects of variations in the loading and the size of the cutout on the global and local response quantities as well as their sensitivity to changes in the various panel, layer, and micromechanical parameters.

Hot Tearing in Aluminium — Copper Alloys

NASA Astrophysics Data System (ADS)

Viano, David; StJohn, David; Grandfield, John; Cáceres, Carlos

For many aluminium alloys, hot tearing susceptibility follows a lambda curve relationship when hot tearing severity is plotted as a function of solute content. In the past, there has been some difficulty quantifying hot tearing. Traditional methods rely upon measuring electrical resistivity or the number and/or length of cracks in tests such as the ring test. In this experimental program, a hot tear test rig was used to investigate a series of binary Al-Cu alloys. This device measures the load imposed on the mushy zone during solidification. Hot tearing susceptibility was quantified in two ways. The first method involved measuring the load at the solidus temperature (548°C). The second method was to radiograph the hot spot and measure the image density of the cracks. Both methods had advantages and disadvantages. It was found that the results from the hot tear rig correlates with other published data using different experimental methods.

Biofouling community composition across a range of environmental conditions and geographical locations suitable for floating marine renewable energy generation.

PubMed

Macleod, Adrian K; Stanley, Michele S; Day, John G; Cook, Elizabeth J

2016-01-01

Knowledge of biofouling typical of marine structures is essential for engineers to define appropriate loading criteria in addition to informing other stakeholders about the ecological implications of creating novel artificial environments. There is a lack of information regarding biofouling community composition (including weight and density characteristics) on floating structures associated with future marine renewable energy generation technologies. A network of navigation buoys were identified across a range of geographical areas, environmental conditions (tidal flow speed, temperature and salinity), and deployment durations suitable for future developments. Despite the perceived importance of environmental and temporal factors, geographical location explained the greatest proportion of the observed variation in community composition, emphasising the importance of considering geography when assessing the impact of biofouling on device functioning and associated ecology. The principal taxa associated with variation in biofouling community composition were mussels (Mytilus edulis), which were also important when determining loading criteria.

IN-VITRO CHARACTERIZATION OF GASTRORETENTIVE MICROBALLOONS PREPARED BY THE EMULSION SOLVENT DIFFUSION METHOD

PubMed Central

Yadav, Akash; Jain, Dinesh Kumar

2010-01-01

Microballoons floatable on JPXIII No.1 solution were developed as a dosage form capable of floating in the stomach. Microballoons were prepared by the emulsion solvent diffusion method using enteric acrylic and other polymers with drug in a mixture of dichloromethane and ethanol. It was found that preparation temperature determined the formation of cavity inside the microsphere and the surface smoothness, determining the floatability and the drug release rate of the microballoons. The correlation between the buoyancy of microballoons and their physical properties, e.g. apparent density and roundness of microballoons were elucidated. The drug loading efficiency of microballoons was also determined. The optimum loading amount of metformin in the microballoons was found to impart ideal floatable properties to the microballoons. By fitting the data into zero order, first order and Highuchi model it was concluded that the release followed zero order release. PMID:22247832

Direct N2H4/H2O2 Fuel Cells Powered by Nanoporous Gold Leaves

PubMed Central

Yan, Xiuling; Meng, Fanhui; Xie, Yun; Liu, Jianguo; Ding, Yi

2012-01-01

Dealloyed nanoporous gold leaves (NPGLs) are found to exhibit high electrocatalytic properties toward both hydrazine (N2H4) oxidation and hydrogen peroxide (H2O2) reduction. This observation allows the implementation of a direct hydrazine-hydrogen peroxide fuel cell (DHHPFC) based on these novel porous membrane catalysts. The effects of fuel and oxidizer flow rate, concentration and cell temperature on the performance of DHHPFC are systematically investigated. With a loading of ~0.1 mg cm−2 Au on each side, an open circuit voltage (OCV) of 1.2 V is obtained at 80°C with a maximum power density 195 mW cm−2, which is 22 times higher than that of commercial Pt/C electrocatalyst at the same noble metal loading. NPGLs thus hold great potential as effective and stable electrocatalysts for DHHPFCs. PMID:23230507

Full load testing in the platform module prior to tow-out: A case history of subsynchronous instability

NASA Technical Reports Server (NTRS)

Fulton, J. W.

1984-01-01

An electric motor driven centrifugal compressor to supply gas for further compression and reinjection on a petroleum production platform in the North Sea was examined. The compressor design, raised concerns about susceptibility to subsynchronous instability. Log decrement, aerodynamic features, and the experience of other compressors with similar ratios of operating to critical speed ratio versus gas density led to the decision to full load test. Mixed hydrocarbon gas was chosen for the test to meet discharge temperature restrictions. The module was used as the test site. Subsynchronous vibrations made the compressor inoperable above approximately one-half the rated discharge pressure of 14500 kPa. Modifications, which includes shortening the bearing span, change of leakage inlet flow direction on the back to back labyrinth, and removal of the vaned diffusers on all stages were made simultaneously. The compressor is operating with satisfactory vibration levels.

An Investigation of SiC/SiC Woven Composite Under Monotonic and Cyclic Loading

NASA Technical Reports Server (NTRS)

Lang, J.; Sankar, J.; Kelkar, A. D.; Bhatt, R. T.; Singh, M.; Lua, J.

1997-01-01

The desirable properties in ceramic matrix composites (CMCs), such as high temperature strength, corrosion resistance, high toughness, low density, or good creep resistance have led to increased use of CMCs in high-speed engine structural components and structures that operate in extreme temperature and hostile aero-thermo-chemical environments. Ceramic matrix composites have been chosen for turbine material in the design of 21 st-century civil propulsion systems to achieve high fuel economy, improved reliability, extended life, and reduced cost. Most commercial CMCs are manufactured using a chemical vapor infiltration (CVI) process. However, a lower cost fabrication known as melt-infiltration process is also providing CMCs marked for use in hot sections of high-speed civil transports. The scope of this paper is to report on the material and mechanical characterization of the CMCs subjected to this process and to predict the behavior through an analytical model. An investigation of the SiC/SiC 8-harness woven composite is ongoing and its tensile strength and fatigue behavior is being characterized for room and elevated temperatures. The investigation is being conducted at below and above the matrix cracking stress once these parameters are identified. Fractography and light microscopy results are being studied to characterize the failure modes resulting from pure uniaxial loading. A numerical model is also being developed to predict the laminate properties by using the constituent material properties and tow undulation.

Micro/nano composited tungsten material and its high thermal loading behavior

NASA Astrophysics Data System (ADS)

Fan, Jinglian; Han, Yong; Li, Pengfei; Sun, Zhiyu; Zhou, Qiang

2014-12-01

Tungsten (W) is considered as promising candidate material for plasma facing components (PFCs) in future fusion reactors attributing to its many excellent properties. Current commercial pure tungsten material in accordance with the ITER specification can well fulfil the performance requirements, however, it has defects such as coarse grains, high ductile-brittle transition temperature (DBTT) and relatively low recrystallization temperature compared with its using temperature, which cannot meet the harsh wall loading requirement of future fusion reactor. Grain refinement has been reported to be effective in improving the thermophysical and mechanical properties of W. In this work, rare earth oxide (Y2O3/La2O3) and carbides (TiC/ZrC) were used as dispersion phases to refine W grains, and micro/nano composite technology with a process of "sol gel - heterogeneous precipitation - spray drying - hydrogen reduction - ordinary consolidation sintering" was invented to introduce these second-phase particles uniformly dispersed into W grains and grain-boundaries. Via this technology, fine-grain W materials with near-full density and relatively high mechanical properties compared with traditional pure W material were manufactured. Preliminary transient high-heat flux tests were performed to evaluate the thermal response under plasma disruption conditions, and the results show that the W materials prepared by micro/nano composite technology can endure high-heat flux of 200 MW/m2 (5 ms).

Nanostructuring and texturing of pulsed laser deposited hydroxyapatite thin films

NASA Astrophysics Data System (ADS)

Kim, Hyunbin; Catledge, Shane; Vohra, Yogesh; Camata, Renato; Lacefield, William

2003-03-01

Hydroxyapatite (HA) [Ca_10(PO_4)_6(OH)_2] is commonly deposited onto orthopedic and dental metallic implants to speed up bone formation around devices, allowing earlier stabilization in a patient. Pulsed laser deposition (PLD) is a suitable means of placing thin HA films on these implants because of its control over stoichiometry, crystallinity, and nanostructure. These characteristics determine the mechanical properties of the films that must be optimized to improve the performance of load-bearing implants and other devices that undergo bone insertion. We have used PLD to produce nanostructured and preferentially oriented HA films and evaluated their mechanical properties. Pure, highly crystalline HA films on Ti-6Al-4V substrates were obtained using a KrF excimer laser (248nm) with energy density of 4-8 J/cm^2 and deposition temperature of 500-700^rcC. Scanning electron and atomic force microscopies reveal that our careful manipulation of energy density and substrate temperature has led to films made up of HA grains in the nanometer scale. Broadening of x-ray diffraction peaks as a function of deposition temperature suggests it may be possible to control the film nanostructure to a great extent. X-ray diffraction also shows that as the laser energy density is increased in the 4-8 J/cm^2 range, the hexagonal HA films become preferentially oriented along the c-axis perpendicular to the substrate. Texture, nanostructure, and phase make-up all significantly influence the mechanical properties. We will discuss how each of these factors affects hardness and Young's modulus of the HA films as measured by nanoindentation.

Characterization of Low Noise, Precision Voltage Reference REF5025-HT Under Extreme Temperatures

NASA Technical Reports Server (NTRS)

Patterson, Richard; Hammoud, Ahmad

2010-01-01

The performance of Texas Instruments precision voltage reference REF5025-HT was assessed under extreme temperatures. This low noise, 2.5 V output chip is suitable for use in high temperature down-hole drilling applications, but no data existed on its performance at cryogenic temperatures. The device was characterized in terms of output voltage and supply current at different input voltage levels as a function of temperature between +210 C and -190 C. Line and load regulation characteristics were also established at six load levels and at different temperatures. Restart capability at extreme temperatures and the effects of thermal cycling, covering the test temperature range, on its operation and stability were also investigated. Under no load condition, the voltage reference chip exhibited good stability in its output over the temperature range of -50 C to +200 C. Outside that temperature range, output voltage did change as temperature was changed. For example, at the extreme temperatures of +210 C and - 190 C, the output level dropped to 2.43 V and 2.32 V, respectively as compared to the nominal value of 2.5 V. At cryogenic test temperatures of -100 C and -150 C the output voltage dropped by about 20%. The quiescent supply current of the voltage reference varied slightly with temperature but remained close to its specified value. In terms of line regulation, the device exhibited excellent stability between -50 C and +150 C over the entire input voltage range and load levels. At the other test temperatures, however, while line regulation became poor at cryogenic temperatures of -100 C and below, it suffered slight degradation at the extreme high temperature but only at the high load level of 10 mA. The voltage reference also exhibited very good load regulation with temperature down to -100 C, but its output dropped sharply at +210 C only at the heavy load of 10 mA. The semiconductor chip was able restart at the extreme temperatures of -190 C and +210 C, and the limited thermal cycling did not influence its characteristics and had no impact on its packaging as no structural or physical damage was observed.

Superfluid transition in the attractive Hofstadter-Hubbard model

NASA Astrophysics Data System (ADS)

Umucalılar, R. O.; Iskin, M.

2016-08-01

We consider a Fermi gas that is loaded onto a square optical lattice and subjected to a perpendicular artificial magnetic field, and determine its superfluid transition boundary by adopting a BCS-like mean-field approach in momentum space. The multiband structure of the single-particle Hofstadter spectrum is taken explicitly into account while deriving a generalized pairing equation. We present the numerical solutions as functions of the artificial magnetic flux, interaction strength, Zeeman field, chemical potential, and temperature, with a special emphasis on the roles played by the density of single-particle states and center-of-mass momentum of Cooper pairs.

Oxygen ionization rates at Mars and Venus - Relative contributions of impact ionization and charge exchange

NASA Astrophysics Data System (ADS)

Zhang, M. H. G.; Luhmann, J. G.; Nagy, A. F.; Spreiter, J. R.; Stahara, S. S.

1993-02-01

Oxygen ion production rates above the ionopauses of Venus and Mars are calculated for photoionization, charge exchange, and solar wind electron impact ionization processes. The latter two require the use of the Spreiter and Stahara (1980) gas dynamic model to estimate magnetosheath velocities, densities, and temperatures. The results indicate that impact ionization is the dominant mechanism for the production of O(+) ions at both Venus and Mars. This finding might explain both the high ion escape rates measured by Phobos 2 and the greater mass loading rate inferred for Venus from the bow shock positions.

[Numeric simulation of functional remodeling of the anterior alveolar bone].

PubMed

Wang, Wei-feng; Xin, Hai-tao; Zang, Shun-lai; Ding, Jie

2012-04-01

To study the remodeling of the anterior alveolar bone with parodontium under physiology loading using finite element method (FEM) and theory of bone remodeling. A FEM model of the maxillary central incisor with parodontium was established, and the change of bone density during the remodeling of alveolar bone was investigated under physiology loading (60 - 150 N) based on the theory of bone remodeling about strain energy density (SED). The finite element analysis software Abaqus user material subroutine (UMAT) were used. With the increase of physiology loading, the pressure stress on the buccal cervical margin increased gradually while the density was decreased gradually. The cortical bone was lower than its initial density 1.74 g/cm(3), which was 1.74 - 1.63 g/cm(3). The density of cancellous bone was 0.90 - 0.77 g/cm(3), which was lower than its intial density 0.90 g/cm(3). The lingual cervical margin was under tensile stress which also increased with loading, the density had no significant change. When the achieve to 120 N, the density of cortical bone was 1.74 - 1.73 g/cm(3). No significant change was found in the cancellous bone. The simulation of the perodontium remodeling is achieved and proved to be effective by the relevant research based on the method of the study. And the result will be helpful to form the basis of analysis bone remodeling process and predict the results in the clinical work.

Mechanistic basis of temperature-dependent dwell fatigue in titanium alloys

NASA Astrophysics Data System (ADS)

Zheng, Zebang; Balint, Daniel S.; Dunne, Fionn P. E.

2017-10-01

The temperature-dependent dwell sensitivity of Ti-6242 and Ti-6246 alloys has been assessed over a temperature range from - 50∘ C to 390 °C using discrete dislocation plasticity which incorporates both thermal activation of dislocation escape from obstacles and slip transfer across grain boundaries. The worst-case load shedding in Ti-6242 alloy is found to be at or close to 120 °C under dwell fatigue loading, which diminishes and vanishes at temperatures lower than - 50∘ C or higher than 230 °C. Load shedding behaviour is predicted to occur in alloy Ti-6246 also but over a range of higher temperatures which are outside those relevant to in-service conditions. The key controlling dislocation mechanism with respect to load shedding in titanium alloys, and its temperature sensitivity, is shown to be the time constant associated with the thermal activation of dislocation escape from obstacles, with respect to the stress dwell time. The mechanistic basis of load shedding and dwell sensitivity in dwell fatigue loading is presented and discussed in the context of experimental observations.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rao, Rekha R.; Mondy, Lisa Ann; Noble, David R.

We are studying PMDI polyurethane with a fast catalyst, such that filling and polymerization occur simultaneously. The foam is over-packed to tw ice or more of its free rise density to reach the density of interest. Our approach is to co mbine model development closely with experiments to discover new physics, to parameterize models and to validate the models once they have been developed. The model must be able to repres ent the expansion, filling, curing, and final foam properties. PMDI is chemically blown foam, wh ere carbon dioxide is pr oduced via the reaction of water and isocyanate. Themore » isocyanate also re acts with polyol in a competing reaction, which produces the polymer. A new kinetic model is developed and implemented, which follows a simplified mathematical formalism that decouple s these two reactions. The model predicts the polymerization reaction via condensation chemis try, where vitrification and glass transition temperature evolution must be included to correctly predict this quantity. The foam gas generation kinetics are determined by tracking the molar concentration of both water and carbon dioxide. Understanding the therma l history and loads on the foam due to exothermicity and oven heating is very important to the results, since the kinetics and ma terial properties are all very sensitive to temperature. The conservation eq uations, including the e quations of motion, an energy balance, and thr ee rate equations are solved via a stabilized finite element method. We assume generalized-Newtonian rheology that is dependent on the cure, gas fraction, and temperature. The conservation equations are comb ined with a level set method to determine the location of the free surface over time. Results from the model are compared to experimental flow visualization data and post-te st CT data for the density. Seve ral geometries are investigated including a mock encapsulation part, two configur ations of a mock stru ctural part, and a bar geometry to specifically test the density model. We have found that the model predicts both average density and filling profiles well. However, it under predicts density gradients, especially in the gravity direction. Thoughts on m odel improvements are also discussed.« less

Improved Regression Analysis of Temperature-Dependent Strain-Gage Balance Calibration Data

NASA Technical Reports Server (NTRS)

Ulbrich, N.

2015-01-01

An improved approach is discussed that may be used to directly include first and second order temperature effects in the load prediction algorithm of a wind tunnel strain-gage balance. The improved approach was designed for the Iterative Method that fits strain-gage outputs as a function of calibration loads and uses a load iteration scheme during the wind tunnel test to predict loads from measured gage outputs. The improved approach assumes that the strain-gage balance is at a constant uniform temperature when it is calibrated and used. First, the method introduces a new independent variable for the regression analysis of the balance calibration data. The new variable is designed as the difference between the uniform temperature of the balance and a global reference temperature. This reference temperature should be the primary calibration temperature of the balance so that, if needed, a tare load iteration can be performed. Then, two temperature{dependent terms are included in the regression models of the gage outputs. They are the temperature difference itself and the square of the temperature difference. Simulated temperature{dependent data obtained from Triumph Aerospace's 2013 calibration of NASA's ARC-30K five component semi{span balance is used to illustrate the application of the improved approach.

Steady-state temperature determination on the base of hysteresis loop energy for CuZn37 brass

NASA Astrophysics Data System (ADS)

Lipski, Adam; Skibicki, Dariusz; Pejkowski, Łukasz

2017-03-01

This paper presents the verification of the relationship between the temperature and the hysteresis loop energy for the CuZn37 brass under multiaxial fatigue loading. Fatigue tests were performed on the hollow specimens subjected to fully reversed tension-compression, torsion, proportional loading, 90° out-of-phase non-proportional loading and two another non-proportional loadings with frequency differences. All test were strain-controlled. Calculations of a plastic strain energy were based on midlife strain hysteresis loops data. The calculated specimen temperatures were compared with temperatures observed by thermographic camera.

Note: Motor-piezoelectricity coupling driven high temperature fatigue device

NASA Astrophysics Data System (ADS)

Ma, Z. C.; Du, X. J.; Zhao, H. W.; Ma, X. X.; Jiang, D. Y.; Liu, Y.; Ren, L. Q.

2018-01-01

The design and performance evaluation of a novel high temperature fatigue device simultaneously driven by servo motor and piezoelectric actuator is our focus. The device integrates monotonic and cyclic loading functions with a maximum tensile load of 1800 N, driving frequency of 50 Hz, alternating load of 95 N, and maximum service temperature of 1200 °C. Multimodal fatigue tests with arbitrary combinations of static and dynamic loads are achieved. At temperatures that range from RT to 1100 °C, the tensile and tensile-fatigue coupling mechanical behaviors of UM Co50 alloys are investigated to verify the feasibility of the device.

Dynamic compressive loading enhances cartilage matrix synthesis and distribution and suppresses hypertrophy in hMSC-laden hyaluronic acid hydrogels.

PubMed

Bian, Liming; Zhai, David Y; Zhang, Emily C; Mauck, Robert L; Burdick, Jason A

2012-04-01

Mesenchymal stem cells (MSCs) are being recognized as a viable cell source for cartilage repair, and there is growing evidence that mechanical signals play a critical role in the regulation of stem cell chondrogenesis and in cartilage development. In this study we investigated the effect of dynamic compressive loading on chondrogenesis, the production and distribution of cartilage specific matrix, and the hypertrophic differentiation of human MSCs encapsulated in hyaluronic acid (HA) hydrogels during long term culture. After 70 days of culture, dynamic compressive loading increased the mechanical properties, as well as the glycosaminoglycan (GAG) and collagen contents of HA hydrogel constructs in a seeding density dependent manner. The impact of loading on HA hydrogel construct properties was delayed when applied to lower density (20 million MSCs/ml) compared to higher seeding density (60 million MSCs/ml) constructs. Furthermore, loading promoted a more uniform spatial distribution of cartilage matrix in HA hydrogels with both seeding densities, leading to significantly improved mechanical properties as compared to free swelling constructs. Using a previously developed in vitro hypertrophy model, dynamic compressive loading was also shown to significantly reduce the expression of hypertrophic markers by human MSCs and to suppress the degree of calcification in MSC-seeded HA hydrogels. Findings from this study highlight the importance of mechanical loading in stem cell based therapy for cartilage repair in improving neocartilage properties and in potentially maintaining the cartilage phenotype.

High-loading Fe2O3/SWNT composite films for lithium-ion battery applications

NASA Astrophysics Data System (ADS)

Wang, Ying; Guo, Jiahui; Li, Li; Ge, Yali; Li, Baojun; Zhang, Yingjiu; Shang, Yuanyuan; Cao, Anyuan

2017-08-01

Single-walled carbon nanotube (SWNT) films are a potential candidate as porous conductive electrodes for energy conversion and storage; tailoring the loading and distribution of active materials grafted on SWNTs is critical for achieving maximum performance. Here, we show that as-synthesized SWNT samples containing residual Fe catalyst can be directly converted to Fe2O3/SWNT composite films by thermal annealing in air. The mass loading of Fe2O3 nanoparticles is tunable from 63 wt% up to 96 wt%, depending on the annealing temperature (from 450 °C to 600 °C), while maintaining the porous network structure. Interconnected SWNT networks containing high-loading active oxides lead to synergistic effect as an anode material for lithium ion batteries. The performance is improved consistently with increasing Fe2O3 loading. As a result, our Fe2O3/SWNT composite films exhibit a high reversible capacity (1007.1 mA h g-1 at a current density of 200 mA g-1), excellent rate capability (384.9 mA h g-1 at 5 A g-1) and stable cycling performance with the discharge capacity up to 567.1 mA h g-1 after 600 cycles at 2 A g-1. The high-loading Fe2O3/SWNT composite films have potential applications as nanostructured electrodes for various energy devices such as supercapacitors and Li-ion batteries.

Impact on the deuterium retention of simultaneous exposure of tungsten to a steady state plasma and transient heat cycling loads

NASA Astrophysics Data System (ADS)

Huber, A.; Sergienko, G.; Wirtz, M.; Steudel, I.; Arakcheev, A.; Brezinsek, S.; Burdakov, A.; Dittmar, T.; Esser, H. G.; Kreter, A.; Linke, J.; Linsmeier, Ch; Mertens, Ph; Möller, S.; Philipps, V.; Pintsuk, G.; Reinhart, M.; Schweer, B.; Shoshin, A.; Terra, A.; Unterberg, B.

2016-02-01

The impact on the deuterium retention of simultaneous exposure of tungsten to a steady-state plasma and transient cyclic heat loads has been studied in the linear PSI-2 facility with the main objective of qualifying tungsten (W) as plasma-facing material. The transient heat loads were applied by a high-energy laser, a Nd:YAG laser (λ = 1064 nm) with an energy per pulse of up to 32 J and a duration of 1 ms. A pronounced increase in the D retention by a factor of 13 has been observed during the simultaneous transient heat loads and plasma exposure. These data indicate that the hydrogen clustering is enhanced by the thermal shock exposures, as seen on the increased blister size due to mobilization and thermal production of defects during transients. In addition, the significant increase of the D retention during the simultaneous loads could be explained by an increased diffusion of D atoms into the W material due to strong temperature gradients during the laser pulse exposure and to an increased mobility of D atoms along the shock-induced cracks. Only 24% of the retained deuterium is located inside the near-surface layer (d<4 μm). Enhanced blister formation has been observed under combined loading conditions at power densities close to the threshold for damaging. Blisters are not mainly responsible for the pronounced increase of the D retention.

Io's Plasma Environment During the Galileo Flyby: Global Three-Dimensional MHD Modeling with Adaptive Mesh Refinement

NASA Technical Reports Server (NTRS)

Combi, M. R.; Kabin, K.; Gombosi, T. I.; DeZeeuw, D. L.; Powell, K. G.

1998-01-01

The first results for applying a three-dimensional multimedia ideal MHD model for the mass-loaded flow of Jupiter's corotating magnetospheric plasma past Io are presented. The model is able to consider simultaneously physically realistic conditions for ion mass loading, ion-neutral drag, and intrinsic magnetic field in a full global calculation without imposing artificial dissipation. Io is modeled with an extended neutral atmosphere which loads the corotating plasma torus flow with mass, momentum, and energy. The governing equations are solved using adaptive mesh refinement on an unstructured Cartesian grid using an upwind scheme for AHMED. For the work described in this paper we explored a range of models without an intrinsic magnetic field for Io. We compare our results with particle and field measurements made during the December 7, 1995, flyby of to, as published by the Galileo Orbiter experiment teams. For two extreme cases of lower boundary conditions at Io, our model can quantitatively explain the variation of density along the spacecraft trajectory and can reproduce the general appearance of the variations of magnetic field and ion pressure and temperature. The net fresh ion mass-loading rates are in the range of approximately 300-650 kg/s, and equivalent charge exchange mass-loading rates are in the range approximately 540-1150 kg/s in the vicinity of Io.

Strain Measurement System Developed for Biaxially Loaded Cruciform Specimens

NASA Technical Reports Server (NTRS)

Krause, David L.

2000-01-01

A new extensometer system developed at the NASA Glenn Research Center at Lewis Field measures test area strains along two orthogonal axes in flat cruciform specimens. This system incorporates standard axial contact extensometers to provide a cost-effective high-precision instrument. The device was validated for use by extensive testing of a stainless steel specimen, with specimen temperatures ranging from room temperature to 1100 F. In-plane loading conditions included several static biaxial load ratios, plus cyclic loadings of various waveform shapes, frequencies, magnitudes, and durations. The extensometer system measurements were compared with strain gauge data at room temperature and with calculated strain values for elevated-temperature measurements. All testing was performed in house in Glenn's Benchmark Test Facility in-plane biaxial load frame.

Mercury's lithospheric thickness and crustal density, as inferred from MESSENGER observations

NASA Astrophysics Data System (ADS)

James, P. B.; Mazarico, E.; Genova, A.; Smith, D. E.; Neumann, G. A.; Solomon, S. C.

2015-12-01

The gravity field and topography of Mercury measured by the MESSENGER spacecraft have provided insights into the thickness of the planet's elastic lithosphere, Te. We localized the HgM006 free-air gravity anomaly and gtmes_125v03 shape datasets to search for theoretical elastic thickness solutions that best fit a variety of localized coherence spectra between Bouguer gravity anomaly and topography. We adopted a crustal density of ρcrust =2700 kg m-3 for the Bouguer gravity correction, but density uncertainty did not markedly affect the elastic thickness estimates. A best-fit solution in the northern smooth plains (NSP) gives an elastic thickness of Te =30-60 km at the time of formation of topography for a range of ratios of top to bottom loading from 1 to 5. For a mechanical lithosphere with a thickness of ~2Te and a temperature of 1600 °C at the base, this solution is consistent with a geothermal gradient of 9-18 K km-1. A similar coherence analysis exterior to the NSP produces an elastic thickness estimate of Te =20-50 km, albeit with a poorer fit. Coherence in the northern hemisphere as a whole does not approach zero at any wavelength, because of the presence of variations in crustal thickness that are unassociated with elastic loading. The ratios and correlations of gravity and topography at intermediate wavelengths (harmonic degree l between 30 and 50) also constrain regional crustal densities. We localized gravity and topography with a moving Slepian taper and calculated regionally averaged crustal densities with the approximation ρcrust=Zl/(2πG), where Zl is the localized admittance and G is the gravitational constant. The only regional density estimates greater than 2000 kg m-3 for l=30 correspond to the NSP. Density estimates outside of the NSP were unreasonably low, even for highly porous crust. We attribute these low densities to the confounding effects of crustal thickness variations and Kaula filtering of the gravity dataset at the highest harmonic degrees, both of which tend to introduce a downward bias to crustal density estimation. An alternative analysis—which corrected for crustal thickness variability and was restricted to regions with gravity/topography coherence greater than 0.6—yielded an aggregate crustal density of ρcrust=2602 ± 470 kg m-3 for Mercury's high northern latitudes.

Material Assessment for ITER's Collective Thomson Scattering first mirror

DOE Office of Scientific and Technical Information (OSTI.GOV)

Santos, R.; Policarpo, H.; Goncalves, B.

2015-07-01

The International Thermonuclear Energy Reactor (ITER) Collective Thomson Scattering (CTS) system is a diagnostic instrument that measures plasma density and velocity through Thomson scattering of microwave radiation. Some of the key components of the CTS are quasi-optical mirrors that are used to produce astigmatic beam patterns, which have impact on the strength and spatial resolution of the diagnostic signal. The mirrors are exposed to neutron radiation, which may alter the quality of the signal received. In this work, three different materials (molybdenum (Mo), stainless steel 316 (SS-316) and tungsten (W)) are considered for the first mirror of the CTS. Themore » objective is to access which of the material studied are best suited for this mirror, considering different neutron radiation loads simulated scenarios defined by ITER, based on the resultant stresses and temperature distributions. For it, the neutron irradiation, and subsequent heat-load on the mirrors are simulated using the Monte Carlo N-Particle (MCNP) code. Based on the MCNP heat-load results, transient thermal-structural Finite Element Analysis (FEA) of the mirror over a 400 s discharge, with and without cooling on the rear side, are conducted using in commercial FEA software ANSYS. Results show that of the tested materials Mo and W are the most suitable material for this application. Even though, this study does not yet consider the variation of the material properties with temperature, it presents a quick initial satisfactory assessment that may be considered in subsequent and more complex analysis. (authors)« less

The effect of temperature, gradient, and load carriage on oxygen consumption, posture, and gait characteristics.

PubMed

Hinde, Katrina; Lloyd, Ray; Low, Chris; Cooke, Carlton

2017-03-01

The purpose of this experiment was to evaluate the effect of load carriage in a range of temperatures to establish the interaction between cold exposure, the magnitude of change from unloaded to loaded walking and gradient. Eleven participants (19-27 years) provided written informed consent before performing six randomly ordered walking trials in six temperatures (20, 10, 5, 0, -5, and -10 °C). Trials involved two unloaded walking bouts before and after loaded walking (18.2 kg) at 4 km · h -1 , on 0 and 10% gradients in 4 min bouts. The change in absolute oxygen consumption (V̇O 2 ) from the first unloaded bout to loaded walking was similar across all six temperatures. When repeating the second unloaded bout, V̇O 2 at both -5 and -10 °C was greater compared to the first. At -10 °C, V̇O 2 was increased from 1.60 ± 0.30 to 1.89 ± 0.51 L · min -1 . Regardless of temperature, gradient had a greater effect on V̇O 2 and heart rate (HR) than backpack load. HR was unaffected by temperature. Stride length (SL) decreased with decreasing temperature, but trunk forward lean was greater during cold exposure. Decreased ambient temperature did not influence the magnitude of change in V̇O 2 from unloaded to loaded walking. However, in cold temperatures, V̇O 2 was significantly higher than in warm conditions. The increased V̇O 2 in colder temperatures at the same exercise intensity is predicted to ultimately lead to earlier onset of fatigue and cessation of exercise. These results highlight the need to consider both appropriate clothing and fitness during cold exposure.

A finite element/level set model of polyurethane foam expansion and polymerization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rao, Rekha R.; Long, Kevin Nicholas; Roberts, Christine Cardinal

Polyurethane foams are used widely for encapsulation and structural purposes because they are inexpensive, straightforward to process, amenable to a wide range of density variations (1 lb/ft3 - 50 lb/ft3), and able to fill complex molds quickly and effectively. Computational model of the filling and curing process are needed to reduce defects such as voids, out-of-specification density, density gradients, foam decomposition from high temperatures due to exotherms, and incomplete filling. This paper details the development of a computational fluid dynamics model of a moderate density PMDI structural foam, PMDI-10. PMDI is an isocyanate-based polyurethane foam, which is chemically blown withmore » water. The polyol reacts with isocyanate to produces the polymer. PMDI- 10 is catalyzed giving it a short pot life: it foams and polymerizes to a solid within 5 minutes during normal processing. To achieve a higher density, the foam is over-packed to twice or more of its free rise density of 10 lb/ft3. The goal for modeling is to represent the expansion, filling of molds, and the polymerization of the foam. This will be used to reduce defects, optimize the mold design, troubleshoot the processed, and predict the final foam properties. A homogenized continuum model foaming and curing was developed based on reaction kinetics, documented in a recent paper; it uses a simplified mathematical formalism that decouples these two reactions. The chemo-rheology of PMDI is measured experimentally and fit to a generalized- Newtonian viscosity model that is dependent on the extent of cure, gas fraction, and temperature. The conservation equations, including the equations of motion, an energy balance, and three rate equations are solved via a stabilized finite element method. The equations are combined with a level set method to determine the location of the foam-gas interface as it evolves to fill the mold. Understanding the thermal history and loads on the foam due to exothermicity and oven curing is very important to the results, since the kinetics, viscosity, and other material properties are all sensitive to temperature. Results from the model are compared to experimental flow visualization data and post-test X-ray computed tomography (CT) data for the density. Several geometries are investigated including two configurations of a mock structural part and a bar geometry to specifically test the density model. We have found that the model predicts both average density and filling profiles well. However, it under predicts density gradients, especially in the gravity direction. Further model improvements are also discussed for future work.« less

Buckling of Thermoviscoelastic Structures Under Temporal and Spatial Temperature Variations

NASA Technical Reports Server (NTRS)

Tsuyuki, Richard; Knauss, Wolfgang G.

1992-01-01

The problem of lateral instability of a viscoelastic in-plane loaded structure is considered in terms of thermorheolgically simple materials. As an example of a generally in-plane loaded structure, we examine the simple column under axial load: Both cyclic loading is considered (with constant or in-phase variable temperature excursions) as well as the case of constant load in the presence of thermal gradients through the thickness of the structure. The latter case involves a continuous movement of the neutral axis from the center to the colder side and then back to the center. In both cases, temperature has a very strong effect on the instability evolution, and under in-phase thermal cycling the critical loads are reduced compared to those at constant temperatures. The primary effect of thermal gradients beyond that of thermally-induced rate accelerations is occasioned by the generation of an "initial imperfection" or "structural bowing." Because the coefficient of thermal expansion tends to be large for many polymeric materials, it it may be necessary to take special care in lay-up design of composite structures intended for use under compressive loads in high-temperature applications. Finally, the implications for the temperature sensitivities of composites to micro-instability (fiber crimping) are also apparent from the results delineated here.

Study on power grid characteristics in summer based on Linear regression analysis

NASA Astrophysics Data System (ADS)

Tang, Jin-hui; Liu, You-fei; Liu, Juan; Liu, Qiang; Liu, Zhuan; Xu, Xi

2018-05-01

The correlation analysis of power load and temperature is the precondition and foundation for accurate load prediction, and a great deal of research has been made. This paper constructed the linear correlation model between temperature and power load, then the correlation of fault maintenance work orders with the power load is researched. Data details of Jiangxi province in 2017 summer such as temperature, power load, fault maintenance work orders were adopted in this paper to develop data analysis and mining. Linear regression models established in this paper will promote electricity load growth forecast, fault repair work order review, distribution network operation weakness analysis and other work to further deepen the refinement.

Separation of density and viscosity influence on liquid-loaded surface acoustic wave devices

NASA Astrophysics Data System (ADS)

Herrmann, F.; Hahn, D.; Büttgenbach, S.

1999-05-01

Love-mode sensors are reported for separate measurement of liquid density and viscosity. They combine the general merits of Love-mode devices, e.g., ease of sensitivity adjustment and robustness, with a highly effective procedure of separate determination of liquid density and viscosity. A model is proposed to describe the frequency response of the devices to liquid loading. Moreover, design rules are given for further optimization and sensitivity enhancement.

Effectiveness of eugenol sedation to reduce the metabolic rates of cool and warm water fish at high loading densities

USGS Publications Warehouse

Cupp, Aaron R.; Hartleb, Christopher F.; Fredricks, Kim T.; Gaikowski, Mark P.

2016-01-01

Effects of eugenol (AQUI-S®20E, 10% active eugenol) sedation on cool water, yellow perch Perca flavescens (Mitchill), and warm water, Nile tilapia Oreochromis niloticus L. fish metabolic rates were assessed. Both species were exposed to 0, 10, 20 and 30 mg L−1 eugenol using static respirometry. In 17°C water and loading densities of 60, 120 and 240 g L−1, yellow perch controls (0 mg L−1 eugenol) had metabolic rates of 329.6–400.0 mg O2 kg−1 h−1, while yellow perch exposed to 20 and 30 mg L−1 eugenol had significantly reduced metabolic rates of 258.4–325.6 and 189.1–271.0 mg O2 kg−1 h−1 respectively. Nile tilapia exposed to 30 mg L−1 eugenol had a significantly reduced metabolic rate (424.5 ± 42.3 mg O2 kg−1 h−1) relative to the 0 mg L−1 eugenol control (546.6 ± 53.5 mg O2 kg−1 h−1) at a loading density of 120 g L−1 in 22°C water. No significant differences in metabolic rates for Nile tilapia were found at 240 or 360 g L−1 loading densities when exposed to eugenol. Results suggest that eugenol sedation may benefit yellow perch welfare at high densities (e.g. live transport) due to a reduction in metabolic rates, while further research is needed to assess the benefits of eugenol sedation on Nile tilapia at high loading densities.

The computation of thermo-chemical nonequilibrium hypersonic flows

NASA Technical Reports Server (NTRS)

Candler, Graham

1989-01-01

Several conceptual designs for vehicles that would fly in the atmosphere at hypersonic speeds have been developed recently. For the proposed flight conditions the air in the shock layer that envelops the body is at a sufficiently high temperature to cause chemical reaction, vibrational excitation, and ionization. However, these processes occur at finite rates which, when coupled with large convection speeds, cause the gas to be removed from thermo-chemical equilibrium. This non-ideal behavior affects the aerothermal loading on the vehicle and has ramifications in its design. A numerical method to solve the equations that describe these types of flows in 2-D was developed. The state of the gas is represented with seven chemical species, a separate vibrational temperature for each diatomic species, an electron translational temperature, and a mass-average translational-rotational temperature for the heavy particles. The equations for this gas model are solved numerically in a fully coupled fashion using an implicit finite volume time-marching technique. Gauss-Seidel line-relaxation is used to reduce the cost of the solution and flux-dependent differencing is employed to maintain stability. The numerical method was tested against several experiments. The calculated bow shock wave detachment on a sphere and two cones was compared to those measured in ground testing facilities. The computed peak electron number density on a sphere-cone was compared to that measured in a flight test. In each case the results from the numerical method were in excellent agreement with experiment. The technique was used to predict the aerothermal loads on an Aeroassisted Orbital Transfer Vehicle including radiative heating. These results indicate that the current physical model of high temperature air is appropriate and that the numerical algorithm is capable of treating this class of flows.

Load sensing system

DOEpatents

Sohns, Carl W.; Nodine, Robert N.; Wallace, Steven Allen

1999-01-01

A load sensing system inexpensively monitors the weight and temperature of stored nuclear material for long periods of time in widely variable environments. The system can include an electrostatic load cell that encodes weight and temperature into a digital signal which is sent to a remote monitor via a coaxial cable. The same cable is used to supply the load cell with power. When multiple load cells are used, vast

Thermal effects on the enhanced ductility in non-monotonic uniaxial tension of DP780 steel sheet

NASA Astrophysics Data System (ADS)

Majidi, Omid; Barlat, Frederic; Korkolis, Yannis P.; Fu, Jiawei; Lee, Myoung-Gyu

2016-11-01

To understand the material behavior during non-monotonic loading, uniaxial tension tests were conducted in three modes, namely, the monotonic loading, loading with periodic relaxation and periodic loading-unloadingreloading, at different strain rates (0.001/s to 0.01/s). In this study, the temperature gradient developing during each test and its contribution to increasing the apparent ductility of DP780 steel sheets were considered. In order to assess the influence of temperature, isothermal uniaxial tension tests were also performed at three temperatures (298 K, 313 K and 328 K (25 °C, 40 °C and 55 °C)). A digital image correlation system coupled with an infrared thermography was used in the experiments. The results show that the non-monotonic loading modes increased the apparent ductility of the specimens. It was observed that compared with the monotonic loading, the temperature gradient became more uniform when a non-monotonic loading was applied.

Dielectric, thermal and mechanical properties of zirconium silicate reinforced high density polyethylene composites for antenna applications.

PubMed

Varghese, Jobin; Nair, Dinesh Raghavan; Mohanan, Pezholil; Sebastian, Mailadil Thomas

2015-06-14

A low cost and low dielectric loss zirconium silicate (ZrSiO4) reinforced HDPE (high-density polyethylene) composite has been developed for antenna applications. The 0-3 type composite is prepared by dispersing ZrSiO4 fillers for various volume fractions (0.1 to 0.5) in the HDPE matrix by the melt mixing process. The composite shows good microwave dielectric properties with a relative permittivity of 5.6 and a dielectric loss of 0.003 at 5 GHz at the maximum filler loading of 0.5 volume fraction. The composite exhibits low water absorption, excellent thermal and mechanical properties. It shows a water absorption of 0.03 wt%, a coefficient of thermal expansion of 70 ppm per °C and a room temperature thermal conductivity of 2.4 W mK(-1). The composite shows a tensile strength of 22 MPa and a microhardness of 13.9 kg mm(-2) for the filler loading of 0.5 volume fraction. The HDPE-ZrSiO4 composites show good dielectric, thermal and mechanical properties suitable for microwave soft substrate applications. A microstrip patch antenna is designed and fabricated using the HDPE-0.5 volume fraction ZrSiO4 substrate and the antenna parameters are investigated.

Engine materials characterization and damage monitoring by using x ray technologies

NASA Technical Reports Server (NTRS)

Baaklini, George Y.

1993-01-01

X ray attenuation measurement systems that are capable of characterizing density variations in monolithic ceramics and damage due to processing and/or mechanical testing in ceramic and intermetallic matrix composites are developed and applied. Noninvasive monitoring of damage accumulation and failure sequences in ceramic matrix composites is used during room-temperature tensile testing. This work resulted in the development of a point-scan digital radiography system and an in situ x ray material testing system. The former is used to characterize silicon carbide and silicon nitride specimens, and the latter is used to image the failure behavior of silicon-carbide-fiber-reinforced, reaction-bonded silicon nitride matrix composites. State-of-the-art x ray computed tomography is investigated to determine its capabilities and limitations in characterizing density variations of subscale engine components (e.g., a silicon carbide rotor, a silicon nitride blade, and a silicon-carbide-fiber-reinforced beta titanium matrix rod, rotor, and ring). Microfocus radiography, conventional radiography, scanning acoustic microscopy, and metallography are used to substantiate the x ray computed tomography findings. Point-scan digital radiography is a viable technique for characterizing density variations in monolithic ceramic specimens. But it is very limited and time consuming in characterizing ceramic matrix composites. Precise x ray attenuation measurements, reflecting minute density variations, are achieved by photon counting and by using microcollimators at the source and the detector. X ray computed tomography is found to be a unique x ray attenuation measurement technique capable of providing cross-sectional spatial density information in monolithic ceramics and metal matrix composites. X ray computed tomography is proven to accelerate generic composite component development. Radiographic evaluation before, during, and after loading shows the effect of preexisting volume flaws on the fracture behavior of composites. Results from one-, three-, five-, and eight-ply ceramic composite specimens show that x ray film radiography can monitor damage accumulation during tensile loading. Matrix cracking, fiber-matrix debonding, fiber bridging, and fiber pullout are imaged throughout the tensile loading of the specimens. In situ film radiography is found to be a practical technique for estimating interfacial shear strength between the silicon carbide fibers and the reaction-bonded silicon nitride matrix. It is concluded that pretest, in situ, and post-test x ray imaging can provide greater understanding of ceramic matrix composite mechanical behavior.

Development of Rene 41 honeycomb structure as an integral cryogenic tankage/fuselage concept for future space transportation systems

NASA Technical Reports Server (NTRS)

Shideler, J. L.; Swegle, A. R.; Fields, R. A.

1982-01-01

The status of the structural development of an integral cryogenic-tankage/hot-fuselage concept for future space transportation systems is reviewed. The concept comprises a honeycomb sandwich structure that serves the combined functions of containing the cryogenic fuel, supporting the vehicle loads, and protecting the spacecraft from entry heating. The inner face sheet is exposed to cryogenic temperature of -423 F during boost; the outer face sheet, which is slotted to reduce thermal stress, is exposed to a maximum temperature of 1400 F during a high-altitude gliding entry. Attention is given to the development of a fabrication process for a Rene 41 honeycomb sandwich panel with a core density of less than 1 percent that is consistent with desirable heat treatment processes for high strength.

Development of Rene' 41 honeycomb structure as an integral cryogenic tankage/fuselage concept for future space transportation systems

NASA Technical Reports Server (NTRS)

Shideler, J. J.; Swegle, A. R.; Fields, R. A.

1982-01-01

The status of the structural development of an integral cryogenic-tankage/hot-fuselage concept for future space transportation systems (STS) is discussed. The concept consists of a honeycomb sandwich structure which serves the combined functions of containment of cryogenic fuel, support of vehicle loads, and thermal protection from an entry heating environment. The inner face sheet is exposed to a cryogenic (LH2) temperature of -423 F during boost; and the outer face sheet, which is slotted to reduce thermal stress, is exposed to a maximum temperature of 1400 F during a high altitude, gliding entry. A fabrication process for a Rene' 41 honeycomb sandwich panel with a core density less than 1 percent was developed which is consistent with desirable heat treatment processes for high strength.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dec, John E.; Yang, Yi; Ji, Chunsheng

Low-temperature gasoline combustion (LTGC), based on the compression ignition of a premixed or partially premixed dilute charge, can provide thermal efficiencies (TE) and maximum loads comparable to those of turbo-charged diesel engines, and ultra-low NOx and particulate emissions. Intake boosting is key to achieving high loads with dilute combustion, and it also enhances the fuel's autoignition reactivity, reducing the required intake heating or hot residuals. These effects have the advantages of increasing TE and charge density, allowing greater timing retard with good stability, and making the fuel Φ- sensitive so that partial fuel stratification (PFS) can be applied for highermore » loads and further TE improvements. However, at high boost the autoignition reactivity enhancement can become excessive, and substantial amounts of EGR are required to prevent overly advanced combustion. Accordingly, an experimental investigation has been conducted to determine how the tradeoff between the effects of intake boost varies with fuel-type and its impact on load range and TE. Five fuels are investigated: a conventional AKI=87 petroleum-based gasoline (E0), and blends of 10 and 20% ethanol with this gasoline to reduce its reactivity enhancement with boost (E10 and E20). Furthermore, a second zero-ethanol gasoline with AKI=93 (matching that of E20) was also investigated (CF-E0), and some neat ethanol data are also reported.« less

Structural Analysis of Pressurized Small Diameter Lines in a Random Vibration Environment

NASA Technical Reports Server (NTRS)

Davis, Mark; Ridnour, Andrew; Brethen, Mark

2011-01-01

The pressurization and propellant feed lines for the Ares 1 Upper Stage Reaction and Roll Control Systems (ReCS and RoCS) were required to be in a high g-load random vibration flight environment. The lines connected the system components and were filled with both liquid hydrazine and gaseous helium. They are considered small and varied between one fourth to one inch in diameter. The random vibration of the lines was considered to be base excitation through the mating components and mounting hardware. It was found that reducing the amount of support structure for the lines added flexibility to the system and improved the line stresses from random vibration, but caused higher stresses from the static g-loads. The locations and number of brackets were optimized by analyzing the mode shapes of the lines causing high stresses. The use of brackets that only constrain motion in the direction of concern further reduced the stresses in the lines. Finite element analysis was used to perform the analysis. The lines were pre-stressed by temperature and internal pressure with fluid and insulation included as non-structural mass. Base excitation was added to the model using Power Spectral Density (PSD) data for the expected flight loads. The random vibration and static g-load cases were combined to obtain the total stress in the lines. This approach advances the state of the art in line analysis by using FEA to predict the stresses in the lines and to optimize the entire system based on the expected flight environment. Adding flexibility to lines has been used in piping system for temperature loads, but in flight environments flexibility has been limited for the static stresses. Adding flexibility to the system in a flight environment by reducing brackets has the benefit of reducing stresses and weight

Boron Carbide: Stabilization of Highly-Loaded Aqueous Suspensions, Pressureless Sintering, and Room Temperature Injection Molding

NASA Astrophysics Data System (ADS)

Diaz-Cano, Andres

Boron carbide (B4C) is the third hardest material after diamond and cubic boron nitride. It's unique combination of properties makes B4C a highly valuable material. With hardness values around 35 MPa, a high melting point, 2450°C, density of 2.52 g/cm3, and high chemical inertness, boron carbide is used in severe wear components, like cutting tools and sandblasting nozzles, nuclear reactors' control rots, and finally and most common application, armor. Production of complex-shaped ceramic component is complex and represents many challenges. Present research presents a new and novel approach to produce complex-shaped B4C components. Proposed approach allows forming to be done at room temperatures and under very low forming pressures. Additives and binder concentrations are kept as low as possible, around 5Vol%, while ceramics loadings are maximized above 50Vol%. Given that proposed approach uses water as the main solvent, pieces drying is simple and environmentally safe. Optimized formulation allows rheological properties to be tailored and adjust to multiple processing approaches, including, injection molding, casting, and additive manufacturing. Boron carbide samples then were pressureless sintered. Due to the high covalent character of boron carbide, multiples sintering aids and techniques have been proposed in order to achieve high levels of densification. However, is not possible to define a clear sintering methodology based on literature. Thus, present research developed a comprehensive study on the effect of multiple sintering aids on the densification of boron carbide when pressureless sintered. Relative densities above 90% were achieved with values above 30MPa in hardness. Current research allows extending the uses and application of boron carbide, and other ceramic systems, by providing a new approach to produce complex-shaped components with competitive properties.

Atmospheric Environments for Entry, Descent and Landing (EDL)

NASA Technical Reports Server (NTRS)

Justus, Carl G.; Braun, Robert D.

2007-01-01

Scientific measurements of atmospheric properties have been made by a wide variety of planetary flyby missions, orbiters, and landers. Although landers can make in-situ observations of near-surface atmospheric conditions (and can collect atmospheric data during their entry phase), the vast majority of data on planetary atmospheres has been collected by remote sensing techniques from flyby and orbiter spacecraft (and to some extent by Earth-based remote sensing). Many of these remote sensing observations (made over a variety of spectral ranges), consist of vertical profiles of atmospheric temperature as a function of atmospheric pressure level. While these measurements are of great interest to atmospheric scientists and modelers of planetary atmospheres, the primary interest for engineers designing entry descent and landing (EDL) systems is information about atmospheric density as a function of geometric altitude. Fortunately, as described in in this paper, it is possible to use a combination of the gas-law relation and the hydrostatic balance relation to convert temperature-versus-pressure, scientific observations into density-versus-altitude data for use in engineering applications. The following section provides a brief introduction to atmospheric thermodynamics, as well as constituents, and winds for EDL. It also gives methodology for using atmospheric information to do "back-of-the-envelope" calculations of various EDL aeroheating parameters, including peak deceleration rate ("g-load"), peak convective heat rate. and total heat load on EDL spacecraft thermal protection systems. Brief information is also provided about atmospheric variations and perturbations for EDL guidance and control issues, and atmospheric issues for EDL parachute systems. Subsequent sections give details of the atmospheric environments for five destinations for possible EDL missions: Venus. Earth. Mars, Saturn, and Titan. Specific atmospheric information is provided for these destinations, and example results are presented for the "back-of-the-envelope" calculations mentioned above.

Wear Behavior and Mechanism of a Cr-Mo-V Cast Hot-Working Die Steel

NASA Astrophysics Data System (ADS)

Wei, M. X.; Wang, S. Q.; Zhao, Y. T.; Chen, K. M.; Cui, X. H.

2011-06-01

The wear behavior and mechanisms of a Cr-Mo-V cast hot-working die steel with three microstructures (tempered martensite, troostite, and sorbite) were studied systematically through the dry-sliding wear tests within a normal load range of 50 to 300 N and an ambient temperature range of 298 K to 673 K (25 °C to 400 °C) by a pin-on-disk high-temperature wear machine. Five different mechanisms were observed in the experiments, namely adhesive, abrasive, mild oxidative, oxidative, and extrusive wear; one or more of those mechanisms would be dominant within particular ranges of load and temperature. The transition of wear mechanisms depended on the formation of tribo-oxides, which was related closely to load and temperature, and their delamination, which was mainly influenced by the matrix. By increasing the load and ambient temperature, the protective effect of tribo-oxides first strengthened, then decreased, and in some cases disappeared. Under a load ranging 50 to 300 N at 298 K (25 °C) and a load of 50 N at 473 K (200 °C), adhesive wear was the dominant wear mechanism, and abrasive wear appeared simultaneously. The wear was of mild oxidative type under a load ranging 100 to 300 N at 473 K (200 °C) and a load ranging 50 to 150 N at 673 K (400 °C) for tempered martensite and tempered troostite as well as under a load of 100 N at 473 K (200 °C) and a load ranging 50 to 100 N at 673 K (400 °C) for tempered sorbite. At the load of 200 N or greater, or the temperatures above 673 K (400 °C), oxidative wear (beyond mild oxidative wear) prevailed. When the highest load of 300 N at 673 K (400 °C) was applied, extrusive wear started to dominate for the tempered sorbite.

Effects of microbial loading and sporulation temperature on atmospheric plasma inactivation of Bacillus subtilis spores

NASA Astrophysics Data System (ADS)

Deng, X. T.; Shi, J. J.; Shama, G.; Kong, M. G.

2005-10-01

Current inactivation studies of Bacillus subtilis spores using atmospheric-pressure glow discharges (APGD) do not consider two important factors, namely microbial loading at the surface of a substrate and sporulation temperature. Yet these are known to affect significantly microbial resistance to heat and hydrogen peroxide. This letter investigates effects of microbial loading and sporulation temperature on spore resistance to APGD. It is shown that microbial loading can lead to a stacking structure as a protective shield against APGD treatment and that high sporulation temperature increases spore resistance by altering core water content and cross-linked muramic acid content of B. subtilis spores.

Combined Loads Test Fixture for Thermal-Structural Testing Aerospace Vehicle Panel Concepts

NASA Technical Reports Server (NTRS)

Fields, Roger A.; Richards, W. Lance; DeAngelis, Michael V.

2004-01-01

A structural test requirement of the National Aero-Space Plane (NASP) program has resulted in the design, fabrication, and implementation of a combined loads test fixture. Principal requirements for the fixture are testing a 4- by 4-ft hat-stiffened panel with combined axial (either tension or compression) and shear load at temperatures ranging from room temperature to 915 F, keeping the test panel stresses caused by the mechanical loads uniform, and thermal stresses caused by non-uniform panel temperatures minimized. The panel represents the side fuselage skin of an experimental aerospace vehicle, and was produced for the NASP program. A comprehensive mechanical loads test program using the new test fixture has been conducted on this panel from room temperature to 500 F. Measured data have been compared with finite-element analyses predictions, verifying that uniform load distributions were achieved by the fixture. The overall correlation of test data with analysis is excellent. The panel stress distributions and temperature distributions are very uniform and fulfill program requirements. This report provides details of an analytical and experimental validation of the combined loads test fixture. Because of its simple design, this unique test fixture can accommodate panels from a variety of aerospace vehicle designs.

High strain rate behaviour of polypropylene microfoams

NASA Astrophysics Data System (ADS)

Gómez-del Río, T.; Garrido, M. A.; Rodríguez, J.; Arencón, D.; Martínez, A. B.

2012-08-01

Microcellular materials such as polypropylene foams are often used in protective applications and passive safety for packaging (electronic components, aeronautical structures, food, etc.) or personal safety (helmets, knee-pads, etc.). In such applications the foams which are used are often designed to absorb the maximum energy and are generally subjected to severe loadings involving high strain rates. The manufacture process to obtain polymeric microcellular foams is based on the polymer saturation with a supercritical gas, at high temperature and pressure. This method presents several advantages over the conventional injection moulding techniques which make it industrially feasible. However, the effect of processing conditions such as blowing agent, concentration and microfoaming time and/or temperature on the microstructure of the resulting microcellular polymer (density, cell size and geometry) is not yet set up. The compressive mechanical behaviour of several microcellular polypropylene foams has been investigated over a wide range of strain rates (0.001 to 3000 s-1) in order to show the effects of the processing parameters and strain rate on the mechanical properties. High strain rate tests were performed using a Split Hopkinson Pressure Bar apparatus (SHPB). Polypropylene and polyethylene-ethylene block copolymer foams of various densities were considered.

Equations of state of detonation products: ammonia and methane

NASA Astrophysics Data System (ADS)

Lang, John; Dattelbaum, Dana; Goodwin, Peter; Garcia, Daniel; Coe, Joshua; Leiding, Jeffery; Gibson, Lloyd; Bartram, Brian

2015-06-01

Ammonia (NH3) and methane (CH4) are two principal product gases resulting from explosives detonation, and the decomposition of other organic materials under shockwave loading (such as foams). Accurate thermodynamic descriptions of these gases are important for understanding the detonation performance of high explosives. However, shock compression data often do not exist for molecular species in the dense gas phase, and are limited in the fluid phase. Here, we present equation of state measurements of elevated initial density ammonia and methane gases dynamically compressed in gas-gun driven plate impact experiments. Pressure and density of the shocked gases on the principal Hugoniot were determined from direct particle velocity and shock wave velocity measurements recorded using optical velocimetry (Photonic Doppler velocimetry (PDV) and VISAR (velocity interferometer system for any reflector)). Streak spectroscopy and 5-color pyrometry were further used to measure the emission from the shocked gases, from which the temperatures of the shocked gases were estimated. Up to 0.07 GPa, ammonia was not observed to ionize, with temperature remaining below 7000 K. These results provide quantitative measurements of the Hugoniot locus for improving equations of state models of detonation products.

Halide-oxide carbon vapor transport of ZnO: Novel approach for unseeded growth of single crystals with controllable growth direction

NASA Astrophysics Data System (ADS)

Colibaba, G. V.

2018-05-01

The thermodynamic analysis of using HCl + CO gas mixture as a chemical vapor transport agent (TA) for ZnO single crystal growth in closed ampoules, including 11 chemical species, is carried out for wide temperature and loaded TA pressure ranges. The advantages of HCl + CO TA for faster and more stable growth are shown theoretically in comparison with HCl, HCl + H2 and CO. The influence of the growth temperature, of the TA density, of the HCl/CO ratio, and of the undercooling on the ZnO mass transport rate was investigated theoretically and experimentally. The HCl/CO ratios favorable for the growth of m planes and (0001)Zn surface were found. It was shown that HCl + CO TA provides: (i) a rather high growth rate (up to 1.5 mm per day); (ii) a decrease of wall adhesion effect and an etch pit density down to 103 cm-2; (iii) a minimization of growth nucleus quantity down to 1; (iv) stable unseeded growth of the high crystalline quality large single crystals with a controllable preferred growth direction. The characterization by the photoluminescence spectra, the transmission spectra and the electrical properties are analyzed.

Eliminating micro-porous layer from gas diffusion electrode for use in high temperature polymer electrolyte membrane fuel cell

NASA Astrophysics Data System (ADS)

Su, Huaneng; Xu, Qian; Chong, Junjie; Li, Huaming; Sita, Cordellia; Pasupathi, Sivakumar

2017-02-01

In this work, we report a simple strategy to improve the performance of high temperature polymer electrolyte membrane fuel cell (HT-PEMFC) by eliminating the micro-porous layer (MPL) from its gas diffusion electrodes (GDEs). Due to the absence of liquid water and the general use of high amount of catalyst, the MPL in a HT-PEMFC system works limitedly. Contrarily, the elimination of the MPL leads to an interlaced micropore/macropore composited structure in the catalyst layer (CL), which favors gas transport and catalyst utilization, resulting in a greatly improved single cell performance. At the normal working voltage (0.6 V), the current density of the GDE eliminated MPL reaches 0.29 A cm-2, and a maximum power density of 0.54 W cm-2 at 0.36 V is obtained, which are comparable to the best results yet reported for the HT-PEMFCs with similar Pt loading and operated using air. Furthermore, the MPL-free GDE maintains an excellent durability during a preliminary 1400 h HT-PEMFC operation, owing to its structure advantages, indicating the feasibility of this electrode for practical applications.

X-ray scattering to probe cracks in rubbers

NASA Astrophysics Data System (ADS)

Creton, Costantino; Demassieux, Quentin; Berghezan, Daniel

Natural rubber is a well-known very tough elastomer and its toughness is generally attributed to its aptitude to crystallize under strain. Yet the mechanism linking the extent of strain induced crystallization to the toughness gamma is still unclear. We mapped by scanning microbeam X-ray diffraction (20 microns resolution), the strain induced crystallization near the crack tip of highly crosslinked and carbon-black filled natural rubbers. Experiments were carried out on static cracks loaded at different values of energy release rates G and for different filler and crosslinker concentrations. We specifically investigated the effect of the crosslinking density, the effect of thermal (oxygen-free) aging and the effect of temperature (between 23 and 100 °C). Several novel findings are reported : a significant amount of crystallization was still present at the crack tip at 100°C, thermal aging (in the absence of oxygen) greatly reduces the amount of crystallization at the crack tip without much effect on the room temperature resistance to fatigue crack propagation of the material, and an increase in crosslinking density reduces the extent of crystallinity at the crack tip for the same applied G. We acknowledge the financial support of Michelin.

Hardness and wear analysis of Cu/Al2O3 composite for application in EDM electrode

NASA Astrophysics Data System (ADS)

Hussain, M. Z.; Khan, U.; Jangid, R.; Khan, S.

2018-02-01

Ceramic materials, like Aluminium Oxide (Al2O3), have high mechanical strength, high wear resistance, high temperature resistance and good chemical durability. Powder metallurgy processing is an adaptable method commonly used to fabricate composites because it is a simple method of composite preparation and has high efficiency in dispersing fine ceramic particles. In this research copper and novel material aluminium oxide/copper (Al2O3/Cu) composite has been fabricated for the application of electrode in Electro-Discharge Machine (EDM) using powder metallurgy technique. Al2O3 particles with different weight percentages (0, 1%, 3% and 5%) were reinforced into copper matrix using powder metallurgy technique. The powders were blended and compacted at a load of 100MPa to produce green compacts and sintered at a temperature of 574 °C. The effect of aluminium oxide content on mass density, Rockwell hardness and wear behaviour were investigated. Wear behaviour of the composites was investigated on Die-Sink EDM (Electro-Discharge Machine). It was found that wear rate is highly depending on hardness, mass density and green protective carbonate layer formation at the surface of the composite.

A dinoflagellate Cochlodinium geminatum bloom in the Zhujiang (Pearl) River estuary in autumn 2009

NASA Astrophysics Data System (ADS)

Ke, Zhixin; Huang, Liangmin; Tan, Yehui; Song, Xingyu

2012-05-01

A severe Cochlodinium geminatum red tide (>300 km2) was observed in the Zhujiang (Pearl) River estuary, South China Sea in autumn 2009. We evaluated the environmental conditions and phytoplankton community structure during the outbreak. The red tide water mass had significantly higher dissolved inorganic phosphate (DIP), ammonia, and temperature, but significantly lower nitrite, nitrate, dissolved inorganic nitrogen (DIN), and DIN/DIP relative to the non-red-tide zones. The phytoplankton assemblage was dominated by dinoflagellates and diatoms during the red tide. C. geminatum was the most abundant species, with a peak density of 4.13×107 cell/L, accounting for >65% of the total phytoplankton density. The DIN/DIP ratio was the most important predictor of species, accounting for 12.45% of the total variation in the phytoplankton community. Heavy phosphorus loading, low precipitation, and severe saline intrusion were likely responsible for the bloom of C. geminatum.

Direct methanol fuel cell with extended reaction zone anode: PtRu and PtRuMo supported on graphite felt

NASA Astrophysics Data System (ADS)

Bauer, Alex; Gyenge, Előd L.; Oloman, Colin W.

Pressed graphite felt (thickness ∼350 μm) with electrodeposited PtRu (43 g m -2, 1.4:1 atomic ratio) or PtRuMo (52 g m -2, 1:1:0.3 atomic ratio) nanoparticle catalysts was investigated as an anode for direct methanol fuel cells. At temperatures above 333 K the fuel cell performance of the PtRuMo catalyst was superior compared to PtRu. The power density was 2200 W m -2 with PtRuMo at 5500 A m -2 and 353 K while under the same conditions PtRu yielded 1925 W m -2. However, the degradation rate of the Mo containing catalyst formulation was higher. Compared to conventional gas diffusion electrodes with comparable PtRu catalyst composition and load, the graphite felt anodes gave higher power densities mainly due to the extended reaction zone for methanol oxidation.

Study on load forecasting to data centers of high power density based on power usage effectiveness

NASA Astrophysics Data System (ADS)

Zhou, C. C.; Zhang, F.; Yuan, Z.; Zhou, L. M.; Wang, F. M.; Li, W.; Yang, J. H.

2016-08-01

There is usually considerable energy consumption in data centers. Load forecasting to data centers is in favor of formulating regional load density indexes and of great benefit to getting regional spatial load forecasting more accurately. The building structure and the other influential factors, i.e. equipment, geographic and climatic conditions, are considered for the data centers, and a method to forecast the load of the data centers based on power usage effectiveness is proposed. The cooling capacity of a data center and the index of the power usage effectiveness are used to forecast the power load of the data center in the method. The cooling capacity is obtained by calculating the heat load of the data center. The index is estimated using the group decision-making method of mixed language information. An example is given to prove the applicability and accuracy of this method.

Optical Emission Spectroscopy in an Unmagnetized Plasma

NASA Astrophysics Data System (ADS)

Milhone, Jason; Cooper, Christopher; Desangles, Victor; Nornberg, Mark; Seidlitz, Blair; Forest, Cary; WiPAL Team

2015-11-01

An optical emission spectroscopic analysis has been developed to measure electron temperature, neutral burnout, and Zeff in Ar and He plasmas in the Wisconsin plasma astrophysics laboratory (WiPAL). The WiPAL vacuum chamber is a 3 meter diameter spherical vessel lined with 3000 SmCo permanent magnets (B > 3 kG) that create an axisymmetric multi-cusp ring for confining the plasma. WiPAL is designed to study unmagnetized plasmas that are hot (Te > 10 eV), dense (ne >1018), and with high ionization fraction. Electron temperature and density can be measured via Langmuir probes. However, probes can disturb the plasma, be difficult to interpret, and become damaged by large heat loads from the plasma. A low cost non-invasive spectroscopy system capable of scanning the plasma via a linear stage has been installed to study plasma properties. From the neutral particle emission, the neutral burnout and estimated neutral temperature can be inferred. A modified coronal model with metastable states is being implemented to determine Te for Ar plasmas.

Superfluidity of 4He in dense aerogel studied using quartz tuning fork

NASA Astrophysics Data System (ADS)

Matsumoto, K.; Okamoto, R.; Nakajima, A.; Abe, S.

2018-03-01

Superfluid 4He in aerogel is of interest because it has a normal component coupling to gel strand due to viscosity and a superfluid component with zero viscosity. Superfluid helium in aerogel has two sound modes, a slow critical mode and a fast one. In this study, quartz tuning fork was used in order to study acoustic properties of liquid 4He in aerogel with 90% porosity. Two pieces of aerogel were glued on both prongs of quartz tuning fork that had a resonance frequency of 33 kHz. The tuning fork was immersed in liquid 4He from 2 to 20 bar. The resonance frequency increased in the superfluid phase due to decrease in loaded mass. Temperature variation of resonance frequency was explained by that of superfluid density. Superfluid transition in aerogel was 2 mK lower than that without gel. Additional dissipation was observed in the temperature range between 1 K and transition temperature.

Transient multi-physics analysis of a magnetorheological shock absorber with the inverse Jiles-Atherton hysteresis model

NASA Astrophysics Data System (ADS)

Zheng, Jiajia; Li, Yancheng; Li, Zhaochun; Wang, Jiong

2015-10-01

This paper presents multi-physics modeling of an MR absorber considering the magnetic hysteresis to capture the nonlinear relationship between the applied current and the generated force under impact loading. The magnetic field, temperature field, and fluid dynamics are represented by the Maxwell equations, conjugate heat transfer equations, and Navier-Stokes equations. These fields are coupled through the apparent viscosity and the magnetic force, both of which in turn depend on the magnetic flux density and the temperature. Based on a parametric study, an inverse Jiles-Atherton hysteresis model is used and implemented for the magnetic field simulation. The temperature rise of the MR fluid in the annular gap caused by core loss (i.e. eddy current loss and hysteresis loss) and fluid motion is computed to investigate the current-force behavior. A group of impulsive tests was performed for the manufactured MR absorber with step exciting currents. The numerical and experimental results showed good agreement, which validates the effectiveness of the proposed multi-physics FEA model.

Evaluation of the Effect of Sulfur on the Performance of Nickel/Gadolinium‐Doped Ceria Based Solid Oxide Fuel Cell Anodes

PubMed Central

Yurkiv, Vitaliy; Costa, Rémi; Schiller, Günter; Friedrich, K. Andreas

2016-01-01

Abstract The focus of this study is the measurement and understanding of the sulfur poisoning phenomena of Ni/gadolinium‐doped ceria (CGO) based solid oxide fuel cells (SOFC). Cells with Ni/CGO10 and NiCu5/CGO40 anodes were characterized by using impedance spectroscopy at different temperatures and H2/H2O fuel ratios. The short‐term sulfur poisoning behavior was investigated systematically at temperatures of 800–950 °C, current densities of 0–0.75 A cm−2, and H2S concentrations of 1–20 ppm. A sulfur poisoning mitigation effect was observed at high current loads and temperatures. The poisoning behavior was reversible for short exposure times. It was observed that the sulfur‐affected processes exhibited significantly different relaxation times that depend on the Gd content in the CGO phase. Moreover, it was demonstrated that the capacitance of Ni/CGO10 anodes is strongly dependent on the temperature and gas‐phase composition, which reflects a changing Ce3+/Ce4+ ratio. PMID:27863123

Wind farm density and harvested power in very large wind farms: A low-order model

NASA Astrophysics Data System (ADS)

Cortina, G.; Sharma, V.; Calaf, M.

2017-07-01

In this work we create new understanding of wind turbine wakes recovery process as a function of wind farm density using large-eddy simulations of an atmospheric boundary layer diurnal cycle. Simulations are forced with a constant geostrophic wind and a time varying surface temperature extracted from a selected period of the Cooperative Atmospheric Surface Exchange Study field experiment. Wind turbines are represented using the actuator disk model with rotation and yaw alignment. A control volume analysis around each turbine has been used to evaluate wind turbine wake recovery and corresponding harvested power. Results confirm the existence of two dominant recovery mechanisms, advection and flux of mean kinetic energy, which are modulated by the background thermal stratification. For the low-density arrangements advection dominates, while for the highly loaded wind farms the mean kinetic energy recovers through fluxes of mean kinetic energy. For those cases in between, a smooth balance of both mechanisms exists. From the results, a low-order model for the wind farms' harvested power as a function of thermal stratification and wind farm density has been developed, which has the potential to be used as an order-of-magnitude assessment tool.

High energy density propulsion systems and small engine dynamometer

NASA Astrophysics Data System (ADS)

Hays, Thomas

2009-07-01

Scope and Method of Study. This study investigates all possible methods of powering small unmanned vehicles, provides reasoning for the propulsion system down select, and covers in detail the design and production of a dynamometer to confirm theoretical energy density calculations for small engines. Initial energy density calculations are based upon manufacturer data, pressure vessel theory, and ideal thermodynamic cycle efficiencies. Engine tests are conducted with a braking type dynamometer for constant load energy density tests, and show true energy densities in excess of 1400 WH/lb of fuel. Findings and Conclusions. Theory predicts lithium polymer, the present unmanned system energy storage device of choice, to have much lower energy densities than other conversion energy sources. Small engines designed for efficiency, instead of maximum power, would provide the most advantageous method for powering small unmanned vehicles because these engines have widely variable power output, loss of mass during flight, and generate rotational power directly. Theoretical predictions for the energy density of small engines has been verified through testing. Tested values up to 1400 WH/lb can be seen under proper operating conditions. The implementation of such a high energy density system will require a significant amount of follow-on design work to enable the engines to tolerate the higher temperatures of lean operation. Suggestions are proposed to enable a reliable, small-engine propulsion system in future work. Performance calculations show that a mature system is capable of month long flight times, and unrefueled circumnavigation of the globe.

Sintered bentonite ceramics for the immobilization of cesium- and strontium-bearing radioactive waste

NASA Astrophysics Data System (ADS)

Ortega, Luis Humberto

The Advanced Fuel Cycle Initiative (AFCI) is a Department of Energy (DOE) program, that has been investigating technologies to improve fuel cycle sustainability and proliferation resistance. One of the program's goals is to reduce the amount of radioactive waste requiring repository disposal. Cesium and strontium are two primary heat sources during the first 300 years of spent nuclear fuel's decay, specifically isotopes Cs-137 and Sr-90. Removal of these isotopes from spent nuclear fuel will reduce the activity of the bulk spent fuel, reducing the heat given off by the waste. Once the cesium and strontium are separated from the bulk of the spent nuclear fuel, the isotopes must be immobilized. This study is focused on a method to immobilize a cesium- and strontium-bearing radioactive liquid waste stream. While there are various schemes to remove these isotopes from spent fuel, this study has focused on a nitric acid based liquid waste. The waste liquid was mixed with the bentonite, dried then sintered. To be effective sintering temperatures from 1100 to 1200°C were required, and waste concentrations must be at least 25 wt%. The product is a leach resistant ceramic solid with the waste elements embedded within alumino-silicates and a silicon rich phase. The cesium is primarily incorporated into pollucite and the strontium into a monoclinic feldspar. The simulated waste was prepared from nitrate salts of stable ions. These ions were limited to cesium, strontium, barium and rubidium. Barium and rubidium will be co-extracted during separation due to similar chemical properties to cesium and strontium. The waste liquid was added to the bentonite clay incrementally with drying steps between each addition. The dry powder was pressed and then sintered at various temperatures. The maximum loading tested is 32 wt. percent waste, which refers to 13.9 wt. percent cesium, 12.2 wt. percent barium, 4.1 wt. percent strontium, and 2.0 wt. percent rubidium. Lower loadings of waste were also tested. The final solid product was a hard dense ceramic with a density that varied from 2.12 g/cm3 for a 19% waste loading with a 1200°C sintering temperature to 3.03 g/cm 3 with a 29% waste loading and sintered at 1100°C. Differential Scanning Calorimetry and Thermal Gravimetric Analysis (DSC-TGA) of the loaded bentonite displayed mass loss steps which were consistent with water losses in pure bentonite. Water losses were complete after dehydroxylation at ˜650°C. No mass losses were evident beyond the dehydroxylation. The ceramic melts at temperatures greater than 1300°C. Light flash analysis found heat capacities of the ceramic to be comparable to those of strontium and barium feldspars as well as pollucite. Thermal conductivity improved with higher sintering temperatures, attributed to lower porosity. Porosity was minimized in 1200°C sinterings. Ceramics with waste loadings less than 25 wt% displayed slump, the lowest waste loading, 15 wt% bloated at a 1200°C sintering. Waste loading above 25 wt% produced smooth uniform ceramics when sintered >1100°C. Sintered bentonite may provide a simple alternative to vitrification and other engineered radioactive waste-forms.

A coupled diffusion-fluid pressure model to predict cell density distribution for cells encapsulated in a porous hydrogel scaffold under mechanical loading.

PubMed

Zhao, Feihu; Vaughan, Ted J; Mc Garrigle, Myles J; McNamara, Laoise M

2017-10-01

Tissue formation within tissue engineering (TE) scaffolds is preceded by growth of the cells throughout the scaffold volume and attachment of cells to the scaffold substrate. It is known that mechanical stimulation, in the form of fluid perfusion or mechanical strain, enhances cell differentiation and overall tissue formation. However, due to the complex multi-physics environment of cells within TE scaffolds, cell transport under mechanical stimulation is not fully understood. Therefore, in this study, we have developed a coupled multiphysics model to predict cell density distribution in a TE scaffold. In this model, cell transport is modelled as a thermal conduction process, which is driven by the pore fluid pressure under applied loading. As a case study, the model is investigated to predict the cell density patterns of pre-osteoblasts MC3T3-e1 cells under a range of different loading regimes, to obtain an understanding of desirable mechanical stimulation that will enhance cell density distribution within TE scaffolds. The results of this study have demonstrated that fluid perfusion can result in a higher cell density in the scaffold region closed to the outlet, while cell density distribution under mechanical compression was similar with static condition. More importantly, the study provides a novel computational approach to predict cell distribution in TE scaffolds under mechanical loading. Copyright © 2017 Elsevier Ltd. All rights reserved.

46 CFR 42.50-5 - International load line certificates.

Code of Federal Regulations, 2010 CFR

2010-10-01

...) __ (inches) (WNA) __ (inches) below (S). Allowance for fresh water for all freeboards __ (inches). (All... point of departure and the sea. 2. When a ship is in fresh water of unit density, the appropriate load line may be submerged by the amount of the fresh water allowance shown above. Where the density is...

Free-Spinning Wind-Tunnel Tests of a Low-Wing Monoplane with Systematic Changes in Wings and Tails V : Effect of Airplane Relative Density

NASA Technical Reports Server (NTRS)

Seidman, Oscar; Neihouse, A I

1940-01-01

The reported tests are a continuation of an NACA investigation being made in the free-spinning wind tunnel to determine the effects of independent variations in load distribution, wing and tail arrangement, and control disposition on the spin characteristics of airplanes. The standard series of tests was repeated to determine the effect of airplane relative density. Tests were made at values of the relative-density parameter of 6.8, 8.4 (basic), and 12.0; and the results were analyzed. The tested variations in the relative-density parameter may be considered either as variations in the wing loading of an airplane spun at a given altitude, with the radii of gyration kept constant, or as a variation of the altitude at which the spin takes place for a given airplane. The lower values of the relative-density parameter correspond to the lower wing loadings or to the lower altitudes of the spin.

Parametric analysis of parameters for electrical-load forecasting using artificial neural networks

NASA Astrophysics Data System (ADS)

Gerber, William J.; Gonzalez, Avelino J.; Georgiopoulos, Michael

1997-04-01

Accurate total system electrical load forecasting is a necessary part of resource management for power generation companies. The better the hourly load forecast, the more closely the power generation assets of the company can be configured to minimize the cost. Automating this process is a profitable goal and neural networks should provide an excellent means of doing the automation. However, prior to developing such a system, the optimal set of input parameters must be determined. The approach of this research was to determine what those inputs should be through a parametric study of potentially good inputs. Input parameters tested were ambient temperature, total electrical load, the day of the week, humidity, dew point temperature, daylight savings time, length of daylight, season, forecast light index and forecast wind velocity. For testing, a limited number of temperatures and total electrical loads were used as a basic reference input parameter set. Most parameters showed some forecasting improvement when added individually to the basic parameter set. Significantly, major improvements were exhibited with the day of the week, dew point temperatures, additional temperatures and loads, forecast light index and forecast wind velocity.

The Grid Density Dependence of the Unsteady Pressures of the J-2X Turbines

NASA Technical Reports Server (NTRS)

Schmauch, Preston B.

2011-01-01

The J-2X engine was originally designed for the upper stage of the cancelled Crew Launch Vehicle. Although the Crew Launch Vehicle was cancelled the J-2X engine, which is currently undergoing hot-fire testing, may be used on future programs. The J-2X engine is a direct descendent of the J-2 engine which powered the upper stage during the Apollo program. Many changes including a thrust increase from 230K to 294K lbf have been implemented in this engine. As part of the design requirements, the turbine blades must meet minimum high cycle fatigue factors of safety for various vibrational modes that have resonant frequencies in the engine's operating range. The unsteady blade loading is calculated directly from CFD simulations. A grid density study was performed to understand the sensitivity of the spatial loading and the magnitude of the on blade loading due to changes in grid density. Given that the unsteady blade loading has a first order effect on the high cycle fatigue factors of safety, it is important to understand the level of convergence when applying the unsteady loads. The convergence of the unsteady pressures of several grid densities will be presented for various frequencies in the engine's operating range.

A mathematical method for quantifying in vivo mechanical behaviour of heel pad under dynamic load.

PubMed

Naemi, Roozbeh; Chatzistergos, Panagiotis E; Chockalingam, Nachiappan

2016-03-01

Mechanical behaviour of the heel pad, as a shock attenuating interface during a foot strike, determines the loading on the musculoskeletal system during walking. The mathematical models that describe the force deformation relationship of the heel pad structure can determine the mechanical behaviour of heel pad under load. Hence, the purpose of this study was to propose a method of quantifying the heel pad stress-strain relationship using force-deformation data from an indentation test. The energy input and energy returned densities were calculated by numerically integrating the area below the stress-strain curve during loading and unloading, respectively. Elastic energy and energy absorbed densities were calculated as the sum of and the difference between energy input and energy returned densities, respectively. By fitting the energy function, derived from a nonlinear viscoelastic model, to the energy density-strain data, the elastic and viscous model parameters were quantified. The viscous and elastic exponent model parameters were significantly correlated with maximum strain, indicating the need to perform indentation tests at realistic maximum strains relevant to walking. The proposed method showed to be able to differentiate between the elastic and viscous components of the heel pad response to loading and to allow quantifying the corresponding stress-strain model parameters.

Phase change based cooling for high burst mode heat loads with temperature regulation above the phase change temperature

DOEpatents

The United States of America as represented by the United States Department of Energy

2009-12-15

An apparatus and method for transferring thermal energy from a heat load is disclosed. In particular, use of a phase change material and specific flow designs enables cooling with temperature regulation well above the fusion temperature of the phase change material for medium and high heat loads from devices operated intermittently (in burst mode). Exemplary heat loads include burst mode lasers and laser diodes, flight avionics, and high power space instruments. Thermal energy is transferred from the heat load to liquid phase change material from a phase change material reservoir. The liquid phase change material is split into two flows. Thermal energy is transferred from the first flow via a phase change material heat sink. The second flow bypasses the phase change material heat sink and joins with liquid phase change material exiting from the phase change material heat sink. The combined liquid phase change material is returned to the liquid phase change material reservoir. The ratio of bypass flow to flow into the phase change material heat sink can be varied to adjust the temperature of the liquid phase change material returned to the liquid phase change material reservoir. Varying the flowrate and temperature of the liquid phase change material presented to the heat load determines the magnitude of thermal energy transferred from the heat load.

Mechanical annealing under low-amplitude cyclic loading in micropillars

NASA Astrophysics Data System (ADS)

Cui, Yi-nan; Liu, Zhan-li; Wang, Zhang-jie; Zhuang, Zhuo

2016-04-01

Mechanical annealing has been demonstrated to be an effective method for decreasing the overall dislocation density in submicron single crystal. However, simultaneously significant shape change always unexpectedly happens under extremely high monotonic loading to drive the pre-existing dislocations out of the free surfaces. In the present work, through in situ TEM experiments it is found that cyclic loading with low stress amplitude can drive most dislocations out of the submicron sample with virtually little change of the shape. The underlying dislocation mechanism is revealed by carrying out discrete dislocation dynamic (DDD) simulations. The simulation results indicate that the dislocation density decreases within cycles, while the accumulated plastic strain is small. By comparing the evolution of dislocation junction under monotonic, cyclic and relaxation deformation, the cumulative irreversible slip is found to be the key factor of promoting junction destruction and dislocation annihilation at free surface under low-amplitude cyclic loading condition. By introducing this mechanics into dislocation density evolution equations, the critical conditions for mechanical annealing under cyclic and monotonic loadings are discussed. Low-amplitude cyclic loading which strengthens the single crystal without seriously disturbing the structure has the potential applications in the manufacture of defect-free nano-devices.

Elevated temperature biaxial fatigue

NASA Technical Reports Server (NTRS)

Jordan, E. H.

1983-01-01

Biaxial fatigue is often encountered in the complex thermo-mechanical loadings present in gas turbine engines. Engine strain histories can involve non-constant temperature, mean stress, creep, environmental effects, both isotropic and anisotropic materials and non-proportional loading. Life prediction for the general case involving all the above factors is not a practicable research project. The current research program is limited to isothermal fatigue at room temperature and 1200 F of Hastalloy-X for both proportional and non-proportional loading. An improved method for predicting the fatigue life and deformation response under biaxial cycle loading is sought.

Nighttime Infrared radiative cooling and opacity inferred by REMS Ground Temperature Sensor Measurements

NASA Astrophysics Data System (ADS)

Martín-Torres, Javier; Paz Zorzano, María; Pla-García, Jorge; Rafkin, Scot; Lepinette, Alain; Sebastián, Eduardo; Gómez-Elvira, Javier; REMS Team

2013-04-01

Due to the low density of the Martian atmosphere, the temperature of the surface is controlled primarily by solar heating, and infrared cooling to the atmosphere and space, rather than heat exchange with the atmosphere. In the absence of solar radiation the infrared (IR) cooling, and then the nighttime surface temperatures, are directly controlled by soil termal inertia and atmospheric optical thickness (τ) at infrared wavelengths. Under non-wind conditions, and assuming no processes involving latent heat changes in the surface, for a particular site where the rover stands the main parameter controlling the IR cooling will be τ. The minimal ground temperature values at a fixed position may thus be used to detect local variations in the total dust/aerosols/cloud tickness. The Ground Temperature Sensor (GTS) and Air Temperature Sensor (ATS) in the Rover Environmental Monitoring Station (REMS) on board the Mars Science Laboratory (MSL) Curiosity rover provides hourly ground and air temperature measurements respectively. During the first 100 sols of operation of the rover, within the area of low thermal inertia, the minimal nightime ground temperatures reached values between 180 K and 190 K. For this season the expected frost point temperature is 200 K. Variations of up to 10 K have been observed associated with dust loading at Gale at the onset of the dust season. We will use these measurements together with line-by-line radiative transfer simulations using the Full Transfer By Optimized LINe-by-line (FUTBOLIN) code [Martín-Torres and Mlynczak, 2005] to estimate the IR atmospheric opacity and then dust/cloud coverage over the rover during the course of the MSL mission. Monitoring the dust loading and IR nightime cooling evolution during the dust season will allow for a better understanding of the influence of the atmosphere on the ground temperature and provide ground truth to models and orbiter measurements. References Martín-Torres, F. J. and M. G. Mlynczak, Application of FUTBOLIN (FUll Transfer By Ordinary Line-by-Line) to the analysis of the solar system and extrasolar planetary atmospheres, Bulletin of the American Astronomical Society, Vol. 37, p.1566, 2005

Influence of density and environmental factors on decomposition kinetics of amorphous polylactide - Reactive molecular dynamics studies.

PubMed

Mlyniec, A; Ekiert, M; Morawska-Chochol, A; Uhl, T

2016-06-01

In this work, we investigate the influence of the surrounding environment and the initial density on the decomposition kinetics of polylactide (PLA). The decomposition of the amorphous PLA was investigated by means of reactive molecular dynamics simulations. A computational model simulates the decomposition of PLA polymer inside the bulk, due to the assumed lack of removal of reaction products from the polymer matrix. We tracked the temperature dependency of the water and carbon monoxide production to extract the activation energy of thermal decomposition of PLA. We found that an increased density results in decreased activation energy of decomposition by about 50%. Moreover, initiation of decomposition of the amorphous PLA is followed by a rapid decline in activation energy caused by reaction products which accelerates the hydrolysis of esters. The addition of water molecules decreases initial energy of activation as well as accelerates the decomposition process. Additionally, we have investigated the dependency of density on external loading. Comparison of pressures needed to obtain assumed densities shows that this relationship is bilinear and the slope changes around a density equal to 1.3g/cm(3). The conducted analyses provide an insight into the thermal decomposition process of the amorphous phase of PLA, which is particularly susceptible to decomposition in amorphous and semi-crystalline PLA polymers. Copyright © 2016 Elsevier Inc. All rights reserved.

[Optimization on trehalose loading technique as protective conditioning for lyophilization of human platelets].

PubMed

Liu, Jing-Han; Zhou, Jun; Ouyang, Xi-Lin; Li, Xi-Jin; Lu, Fa-Qiang

2005-08-01

This study was aimed to further optimize trehalose loading technique including loading temperature, loading time, loading solution and loading concentration of trehalose, based on the established parameters. Loading efficiency in plasma was compared with that in buffer at 37 degrees C; the curves of intracellular trehalose concentration versus loading time at 37 degrees C and 16 degrees C were measured; curves of mean platelet volume (MPV) versus loading time and loading concentration were investigated and compared. According to results obtained, the loaing time, loading temperature, loading solution and trehalose concentration were ascertained for high loading efficiency of trehalose into human platelet. The results showed that the loading efficiency in plasma was markedly higher than that in buffer at 37 degrees C, the loading efficiency in plasma at 37 degrees C was significantly higher than that at 16 degrees C and reached 19.51% after loading for 4 hours, but 6.16% at 16 degrees C. MPV at 16 degrees C was increased by 43.2% than that at 37 degrees C, but had no distinct changes with loading time and loading concentration. In loading at 37 degrees C, MPV increased with loading time and loading concentration positively. Loading time and loading concentration displayed synergetic effect on MPV. MPV increased with loading time and concentration while trehalose loading concentration was above 50 mmol/L. It is concluded that the optimization parameters of trehalose loading technique are 37 degrees C (temperature), 4 hours (leading time), plasma (loading solution), 50 mmol/L (feasible trehalose concentration). The trehalose concentration can be adjusted to meet the requirement of lyophilization.

Optimal Base Station Density of Dense Network: From the Viewpoint of Interference and Load.

PubMed

Feng, Jianyuan; Feng, Zhiyong

2017-09-11

Network densification is attracting increasing attention recently due to its ability to improve network capacity by spatial reuse and relieve congestion by offloading. However, excessive densification and aggressive offloading can also cause the degradation of network performance due to problems of interference and load. In this paper, with consideration of load issues, we study the optimal base station density that maximizes the throughput of the network. The expected link rate and the utilization ratio of the contention-based channel are derived as the functions of base station density using the Poisson Point Process (PPP) and Markov Chain. They reveal the rules of deployment. Based on these results, we obtain the throughput of the network and indicate the optimal deployment density under different network conditions. Extensive simulations are conducted to validate our analysis and show the substantial performance gain obtained by the proposed deployment scheme. These results can provide guidance for the network densification.

Molecular mechanisms of hydrogen loaded B-hydroquinone clathrate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Daschbach, John L.; Chang, Tsun-Mei; Corrales, Louis R.

2006-09-07

Molecular dynamics simulations are used to investigate the molecular interactions of hydrogen loaded beta-hydroquinone clathrate. It is found that at lower temperatures, higher loadings are more stable, whereas, at higher temperatures, lower loadings are more stable. This trend can be understood based on the interactions in the system. For loadings greater than one, the repulsive forces between the guest molecules shove each other towards the attractive forces between the guest and host molecules leading to a stabilized minimum energy configuration at low temperatures. At higher temperatures greater displacements take the system away from the shallow energy minimum and the trendmore » reverses. The asymmetries of the clathrate cage structure are due to the presence of the attractive forces at loadings greater than one that lead to confined states. The nature of the cavity structure is nearly spherical for a loading of one, leads to preferential occupation near the hydroxyl ring crowns of the cavity with a loading of two, and at higher loadings, leads to occupation of the interstitial sites (the hydroxyl rings) between cages by a single H2 molecule with the remaining molecules occupying the equatorial plane of the cavity. At higher temperatures, the cavity is more uniformly occupied for all loadings, where the occupation of the interstitial positions of the cavities leads to facile diffusion. ACKNOWLEDGEMENT This work was partially supported by NIDO (Japan), LDRD (PNNL), EERE U.S. Department of Energy, and by OBES, U.S. DOE. The Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy« less

The effect of core configuration on temperature coefficient of reactivity in IRR-1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bettan, M.; Silverman, I.; Shapira, M.

1997-08-01

Experiments designed to measure the effect of coolant moderator temperature on core reactivity in an HEU swimming pool type reactor were performed. The moderator temperature coefficient of reactivity ({alpha}{sub {omega}}) was obtained and found to be different in two core loadings. The measured {alpha}{sub {omega}} of one core loading was {minus}13 pcm/{degrees}C at the temperature range of 23-30{degrees}C. This value of {alpha}{sub {omega}} is comparable to the data published by the IAEA. The {alpha}{sub {omega}} measured in the second core loading was found to be {minus}8 pcm/{degrees}C at the same temperature range. Another phenomenon considered in this study is coremore » behavior during reactivity insertion transient. The results were compared to a core simulation using the Dynamic Simulator for Nuclear Power Plants. It was found that in the second core loading factors other than the moderator temperature influence the core reactivity more than expected. These effects proved to be extremely dependent on core configuration and may in certain core loadings render the reactor`s reactivity coefficient undesirable.« less

High temperature lubricating process

DOEpatents

Taylor, R.W.; Shell, T.E.

1979-10-04

It has been difficult to provide adequate lubrication for load bearing, engine components when such engines are operating in excess of about 475/sup 0/C. The present invention is a process for providing a solid lubricant on a load bearing, solid surface, such as in an engine being operated at temperatures in excess of about 475/sup 0/C. The process comprises contacting and maintaining the following steps: a gas phase is provided which includes at least one component reactable in a temperature dependent reaction to form a solid lubricant; the gas phase is contacted with the load bearing surface; the load bearing surface is maintained at a temperature which causes reaction of the gas phase component and the formation of the solid lubricant; and the solid lubricant is formed directly on the load bearing surface. The method is particularly suitable for use with ceramic engines.

High temperature lubricating process

DOEpatents

Taylor, Robert W.; Shell, Thomas E.

1982-01-01

It has been difficult to provide adaquate lubrication for load bearing, engine components when such engines are operating in excess of about 475.degree. C. The present invention is a process for providing a solid lubricant on a load bearing, solid surface (14), such as in an engine (10) being operated at temperatures in excess of about 475.degree. C. The process comprises contacting and maintaining steps. A gas phase (42) is provided which includes at least one component reactable in a temperature dependent reaction to form a solid lubricant. The gas phase is contacted with the load bearing surface. The load bearing surface is maintained at a temperature which causes reaction of the gas phase component and the formation of the solid lubricant. The solid lubricant is formed directly on the load bearing surface. The method is particularly suitable for use with ceramic engines.

Design and performance of an ultra-high vacuum scanning tunneling microscope operating at dilution refrigerator temperatures and high magnetic fields.

PubMed

Misra, S; Zhou, B B; Drozdov, I K; Seo, J; Urban, L; Gyenis, A; Kingsley, S C J; Jones, H; Yazdani, A

2013-10-01

We describe the construction and performance of a scanning tunneling microscope capable of taking maps of the tunneling density of states with sub-atomic spatial resolution at dilution refrigerator temperatures and high (14 T) magnetic fields. The fully ultra-high vacuum system features visual access to a two-sample microscope stage at the end of a bottom-loading dilution refrigerator, which facilitates the transfer of in situ prepared tips and samples. The two-sample stage enables location of the best area of the sample under study and extends the experiment lifetime. The successful thermal anchoring of the microscope, described in detail, is confirmed through a base temperature reading of 20 mK, along with a measured electron temperature of 250 mK. Atomically resolved images, along with complementary vibration measurements, are presented to confirm the effectiveness of the vibration isolation scheme in this instrument. Finally, we demonstrate that the microscope is capable of the same level of performance as typical machines with more modest refrigeration by measuring spectroscopic maps at base temperature both at zero field and in an applied magnetic field.

Mechanical behavior of a triaxially braided textile composite at high temperature

NASA Astrophysics Data System (ADS)

El Mourid, Amine

The work presented in this thesis aimed at understanding the influence of viscoelasticity, temperature and aging on the mechanical behaviour of a textile composite using experimental, analytical and numerical tools. The studied material was a triaxially braided composite with fibres in the 0°/+/-60° directions. The yarns were made of carbon fibres, embedded in an MVK10 temperature resistant polyimide matrix. The first step consisted in developing analytical and numerical frameworks to predict viscoelastic behaviour in textile composites. Simulations were performed for both braided and woven textile architectures, at different stiffness contrasts and yarns volume fractions. The analytical framework accuracy was verified with the help of the numerical simulations. An important finding of this study was that the analytical framework, combined with the Mori-Tanaka model, leads to relatively accurate predictions for both the permanent and transient parts. Therefore, the authors believe that the Mori-Tanaka model with an adjusted aspect ratio to take into account yarn curvature is reliable for predicting viscoelastic behaviour in textile composites. The textile composite that was studied in this project did not display viscoelastic behaviour, due to the high yarn volume fraction. However, the framework remains relevant for higher temperature applications or lower yarn volume fractions. The second step was to investigate the temperature effect on the tensile behavior of the carbon/MVK10 triaxially braided composite material studied in this project. To achieve this goal, a series of room and high temperature tensile tests on both matrix and composite samples were performed. The tests on composite samples were performed along two different material directions at the maximum service temperature allowed by the Federal Aviation Administration for aircraft components, and a dedicated replication technique was developed in order to track crack densities as a function of loading, for both test temperatures. Then, both analytical and numerical homogenization models were used to quantify the stress distribution at the yarns level as a function of the applied temperature. Finally, the homogenization models were used to explain the failure mechanisms obtained at both temperatures, for the two material directions tested. The study revealed that the impact of the temperature on the failure mechanisms of the textile composite was dependent on the loading direction. It was observed that the yarns and matrix were more compliant at high temperature, especially for the transverse and shear properties. These changes had negligible effects on the elastic properties of the composite in both directions. However, they created local stress redistributions at the yarns level, which in turn affected the ultimate tensile strength of the composite. The concentration of stress in specific yarns decreased the UTS of the composite and changed the damage profile during loading. The analysis showed the potential of analytical and numerical models to explain failure paths in textile composites. At high temperature, the evolution in the constituent elastic properties was responsible for the changes in the stress profile in the material. The final step consisted in the study of the aging effect on the tensile strength and the failure mechanisms of a carbon/MVK10 triaxially braided composite for two material directions. The damage evolution was monitored with the help of edge and cross-section microscopical observations. At the maximum service temperature, the effect of physical aging on the composite's stiffness and density was negligible while the effect of chemical aging was gradually detrimental to the UTS. It was found that the UTS decreased by 30% in Direction 1 and by 20% in Direction 2 after 9 months of aging. Cracks initiated after 1 month of aging, preferentially on the edge surfaces of the specimen and grew inward as aging time increased. The yarns that were transverse to the sample cutting direction acted as catalyst to the aging process, creating anisotropy in the reduction of mechanical properties. Thermal oxidation was the main agent behind UTS degradation in the triaxially braided composite, causing the initiation of transverse cracks on transverse yarns at the surface of the specimen. The crack density and depth increased during aging, further weakening the material. The FAA requirement for a maximum service temperature is suitable to prevent physical aging. However, it does not prevent UTS degradation caused by chemical aging when fibres are in contact with the oxidizing environment. Nevertheless, the MVK10 matrix tested in this work exhibited relative properties retention similar to that of PMR15, which might make this matrix a suitable replacement. (Abstract shortened by UMI.).

A New Understanding of the Europa Atmosphere and Limits on Geophysical Activity

NASA Astrophysics Data System (ADS)

Shemansky, D. E.; Yung, Y. L.; Liu, X.; Yoshii, J.; Hansen, C. J.; Hendrix, A. R.; Esposito, L. W.

2014-12-01

Deep extreme ultraviolet spectrograph exposures of the plasma sheet at the orbit of Europa, obtained in 2001 using the Cassini Ultraviolet Imaging Spectrograph experiment, have been analyzed to determine the state of the gas. The results are in basic agreement with earlier results, in particular with Voyager encounter measurements of electron density and temperature. Mass loading rates and lack of detectable neutrals in the plasma sheet, however, are in conflict with earlier determinations of atmospheric composition and density at Europa. A substantial fraction of the plasma species at the Europa orbit are long-lived sulfur ions originating at Io, with ~25% derived from Europa. During the outward radial diffusion process to the Europa orbit, heat deposition forces a significant rise in plasma electron temperature and latitudinal size accompanied with conversion to higher order ions, a clear indication that mass loading from Europa is very low. Analysis of far ultraviolet spectra from exposures on Europa leads to the conclusion that earlier reported atmospheric measurements have been misinterpreted. The results in the present work are also in conflict with a report that energetic neutral particles imaged by the Cassini ion and neutral camera experiment originate at the Europa orbit. An interpretation of persistent energetic proton pitch angle distributions near the Europa orbit as an effect of a significant population of neutral gas is also in conflict with the results of the present work. The general conclusion drawn here is that Europa is geophysically far less active than inferred in previous research, with mass loading of the plasma sheet <=4.5 × 1025 atoms s-1 two orders of magnitude below earlier published calculations. Temporal variability in the region joining the Io and Europa orbits, based on the accumulated evidence, is forced by the response of the system to geophysical activity at Io. No evidence for the direct injection of H2O into the Europa atmosphere or from Europa into the magnetosphere system, as has been observed at Enceladus in the Saturn system, is obtained in the present investigation.

A NEW UNDERSTANDING OF THE EUROPA ATMOSPHERE AND LIMITS ON GEOPHYSICAL ACTIVITY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shemansky, D. E.; Liu, X.; Yoshii, J.

2014-12-20

Deep extreme ultraviolet spectrograph exposures of the plasma sheet at the orbit of Europa, obtained in 2001 using the Cassini Ultraviolet Imaging Spectrograph experiment, have been analyzed to determine the state of the gas. The results are in basic agreement with earlier results, in particular with Voyager encounter measurements of electron density and temperature. Mass loading rates and lack of detectable neutrals in the plasma sheet, however, are in conflict with earlier determinations of atmospheric composition and density at Europa. A substantial fraction of the plasma species at the Europa orbit are long-lived sulfur ions originating at Io, with ∼25%more » derived from Europa. During the outward radial diffusion process to the Europa orbit, heat deposition forces a significant rise in plasma electron temperature and latitudinal size accompanied with conversion to higher order ions, a clear indication that mass loading from Europa is very low. Analysis of far ultraviolet spectra from exposures on Europa leads to the conclusion that earlier reported atmospheric measurements have been misinterpreted. The results in the present work are also in conflict with a report that energetic neutral particles imaged by the Cassini ion and neutral camera experiment originate at the Europa orbit. An interpretation of persistent energetic proton pitch angle distributions near the Europa orbit as an effect of a significant population of neutral gas is also in conflict with the results of the present work. The general conclusion drawn here is that Europa is geophysically far less active than inferred in previous research, with mass loading of the plasma sheet ≤4.5 × 10{sup 25} atoms s{sup –1} two orders of magnitude below earlier published calculations. Temporal variability in the region joining the Io and Europa orbits, based on the accumulated evidence, is forced by the response of the system to geophysical activity at Io. No evidence for the direct injection of H{sub 2}O into the Europa atmosphere or from Europa into the magnetosphere system, as has been observed at Enceladus in the Saturn system, is obtained in the present investigation.« less

Pioneer Venus Data Analysis

NASA Technical Reports Server (NTRS)

Jones, Douglas E.

1996-01-01

Analysis and interpretation of data from the Orbiter Retarding Potential Analyzer (ORPA) onboard the Pioneer Venus Orbiter is reported. By comparing ORPA data to proton data from the Orbiter Plasma Analyzer (OPA), it was found that the ORPA suprathermal electron densities taken outside the Venusian ionopause represent solar wind electron densities, thus allowing the high resolution study of Venus bow shocks using both magnetic field and solar wind electron data. A preliminary analysis of 366 bow shock penetrations was completed using the solar wind electron data as determined from ORPA suprathermal electron densities and temperatures, resulting in an estimate of the extent to which mass loading pickup of O+ (UV ionized O atoms flowing out of the Venus atmosphere) upstream of the Venus obstacle occurred. The pickup of O+ averaged 9.95%, ranging from 0.78% to 23.63%. Detailed results are reported in two attached theses: (1) Comparison of ORPA Suprathermal Electron and OPA Solar Wind Proton Data from the Pioneer Venus Orbiter and (2) Pioneer Venus Orbiter Retarding Potential Analyzer Observations of the Electron Component of the Solar Wind, and of the Venus Bow Shock and Magnetosheath.

Current and efficiency optimization under oscillating forces in entropic barriers

NASA Astrophysics Data System (ADS)

Nutku, Ferhat; Aydıner, Ekrem

2016-09-01

The transport of externally overdriven particles confined in entropic barriers is investigated under various types of oscillating and temporal forces. Temperature, load, and amplitude dependence of the particle current and energy conversion efficiency are investigated in three dimensions. For oscillating forces, the optimized temperature-load, amplitude-temperature, and amplitude-load intervals are determined when fixing the amplitude, load, and temperature, respectively. By using three-dimensional plots rather than two-dimensional ones, it is clearly shown that oscillating forces provide more efficiency compared with a temporal one in specified optimized parameter regions. Furthermore, the dependency of efficiency to the angle between the unbiased driving force and a constant force is investigated and an asymmetric angular dependence is found for all types of forces. Finally, it is shown that oscillating forces with a high amplitude and under a moderate load lead to higher efficiencies than a temporal force at both low and high temperatures for the entire range of contact angle. Project supported by the Istanbul University, Turkey (Grant No. 55383).

Ballistic piston fissioning plasma experiment.

NASA Technical Reports Server (NTRS)

Miller, B. E.; Schneider, R. T.; Thom, K.; Lalos, G. T.

1971-01-01

The production of fissioning uranium plasma samples such that the fission fragment stopping distance is less than the dimensions of the plasma is approached by using a ballistic piston device for the compression of uranium hexafluoride. The experimental apparatus is described. At room temperature the gun can be loaded up to 100 torr UF6 partial pressure, but at compression a thousand fold increase of pressure can be obtained at a particle density on the order of 10 to the 19th power per cu cm. Limited spectral studies of UF6 were performed while obtaining the pressure-volume data. The results obtained and their implications are discussed.

Nuclear Rocket Ceramic Metal Fuel Fabrication Using Tungsten Powder Coating and Spark Plasma Sintering

NASA Technical Reports Server (NTRS)

Barnes, M. W.; Tucker, D. S.; Hone, L.; Cook, S.

2017-01-01

Nuclear thermal propulsion is an enabling technology for crewed Mars missions. An investigation was conducted to evaluate spark plasma sintering (SPS) as a method to produce tungsten-depleted uranium dioxide (W-dUO2) fuel material when employing fuel particles that were tungsten powder coated. Ceramic metal fuel wafers were produced from a blend of W-60vol% dUO2 powder that was sintered via SPS. The maximum sintering temperatures were varied from 1,600 to 1,850 C while applying a 50-MPa axial load. Wafers exhibited high density (>95% of theoretical) and a uniform microstructure (fuel particles uniformly dispersed throughout tungsten matrix).

46 CFR 42.50-15 - Coastwise load line certificates for U.S.-flag vessels.

Code of Federal Regulations, 2010 CFR

2010-10-01

... center of ring. Winter __ (inches) (W) __ (inches) below (S). Allowance for fresh water for all... point of departure and the sea. 2. When a ship is in fresh water of unit density the appropriate load line may be submerged by the amount of the fresh water allowance shown above. Where the density is...

The Effects of Presentation Method and Information Density on Visual Search Ability and Working Memory Load

ERIC Educational Resources Information Center

Chang, Ting-Wen; Kinshuk; Chen, Nian-Shing; Yu, Pao-Ta

2012-01-01

This study investigates the effects of successive and simultaneous information presentation methods on learner's visual search ability and working memory load for different information densities. Since the processing of information in the brain depends on the capacity of visual short-term memory (VSTM), the limited information processing capacity…

Glnemo2: Interactive Visualization 3D Program

NASA Astrophysics Data System (ADS)

Lambert, Jean-Charles

2011-10-01

Glnemo2 is an interactive 3D visualization program developed in C++ using the OpenGL library and Nokia QT 4.X API. It displays in 3D the particles positions of the different components of an nbody snapshot. It quickly gives a lot of information about the data (shape, density area, formation of structures such as spirals, bars, or peanuts). It allows for in/out zooms, rotations, changes of scale, translations, selection of different groups of particles and plots in different blending colors. It can color particles according to their density or temperature, play with the density threshold, trace orbits, display different time steps, take automatic screenshots to make movies, select particles using the mouse, and fly over a simulation using a given camera path. All these features are accessible from a very intuitive graphic user interface. Glnemo2 supports a wide range of input file formats (Nemo, Gadget 1 and 2, phiGrape, Ramses, list of files, realtime gyrfalcON simulation) which are automatically detected at loading time without user intervention. Glnemo2 uses a plugin mechanism to load the data, so that it is easy to add a new file reader. It's powered by a 3D engine which uses the latest OpenGL technology, such as shaders (glsl), vertex buffer object, frame buffer object, and takes in account the power of the graphic card used in order to accelerate the rendering. With a fast GPU, millions of particles can be rendered in real time. Glnemo2 runs on Linux, Windows (using minGW compiler), and MaxOSX, thanks to the QT4API.

Fatigue behaviour of core-spun yarns containing filament by means of cyclic dynamic loading

NASA Astrophysics Data System (ADS)

Esin, S.; Osman, B.

2017-10-01

The behaviour of yarns under dynamic loading is important that leads to understand the growth characteristics which is exposed to repetitive loadings during usage of fabric made from these yarns. Fabric growth is undesirable property that originated from low resilience characteristics of fabric. In this study, the effects of the filament fineness and yarn linear density on fatigue behaviour of rigid-core spun yarns were determined. Cotton covered yarns containing different filament fineness of polyester (PET) draw textured yarns (DTY) (100d/36f, 100d/96f, 100d/144f, 100d/192f and 100d/333f) and yarn linear densities (37 tex, 30 tex, 25 tex and 21 tex) were manufactured by using a modified ring spinning system at the same spinning parameters. Repetitive loads were applied for 25 cycles at levels between 0.1 and 3 N. Dynamic modulus and dynamic strain of yarn samples were analyzed statistically. Results showed that filament fineness and yarn linear density have significance effect on dynamic modulus and dynamic strain after cyclic loading.

A computer solution for the dynamic load, lubricant film thickness, and surface temperatures in spiral-bevel gears

NASA Technical Reports Server (NTRS)

Chao, H. C.; Baxter, M.; Cheng, H. S.

1983-01-01

A computer method for determining the dynamic load between spiral bevel pinion and gear teeth contact along the path of contact is described. The dynamic load analysis governs both the surface temperature and film thickness. Computer methods for determining the surface temperature, and film thickness are presented along with results obtained for a pair of typical spiral bevel gears.

Recrystallization and grain growth behavior of rolled tungsten under VDE-like short pulse high heat flux loads

NASA Astrophysics Data System (ADS)

Yuan, Y.; Greuner, H.; Böswirth, B.; Krieger, K.; Luo, G.-N.; Xu, H. Y.; Fu, B. Q.; Li, M.; Liu, W.

2013-02-01

Short pulse heat loads expected for vertical displacement events (VDEs) in ITER were applied in the high heat flux (HHF) test facility GLADIS at IPP-Garching onto samples of rolled W. Pulsed neutral beams with the central heat flux of 23 MW/m2 were applied for 0.5, 1.0 and 1.5 s, respectively. Rapid recrystallization of the adiabatically loaded 3 mm thick samples was observed when the pulse duration was up to 1.0 s. Grains grew markedly following recrystallization with increasing pulse length. The recrystallization temperature and temperature dependence of the recrystallized grain size were also investigated. The results showed that the recrystallization temperature of the W grade was around 2480 °C under the applied heat loading condition, which was nearly 1150 °C higher than the conventional recrystallization temperature, and the grains were much finer. A linear relationship between the logarithm of average grain size (ln d) and the inverse of maximum surface temperature (1/Tmax) was found and accordingly the activation energy for grain growth in temperature evolution up to Tmax in 1.5 s of the short pulse HHF load was deduced to be 4.1 eV. This provided an effective clue to predict the structure evolution under short pulse HHF loads.

Progress Toward a Compact 0.05 K Magnet Refrigerator Operating from 10 K

NASA Technical Reports Server (NTRS)

Canavan, Edgar; Shirron, Peter; DiPirro, Micheal; Tuttle, James; Jackson, Michael; King, Todd; Numazawa, Takenori

2003-01-01

Much of the most interesting information regarding our universe is hidden in the sub-millimeter, infrared, and x-rays bands of the spectrum, to which our atmosphere is largely opaque. Thus, missions exploring these bands are a very important part of NASA s Space Science program. Coincidentally, the most sensitive detectors in these spectral regions operate at extremely low temperatures, typically 0.05 - 0.10 K. Generally these temperatures will be achieved using magnetic refrigerators, also know as Adiabatic Demagnetization Refrigerators, or ADRs. Current ADRs, such as the one used in the XRS-II instrument on the Astro-E2 satellite, use a single-stage to cool detectors from 1.3 K to 0.06 K. The ADR is designed so that it can absorb the heat on the detector stage for at least 24 hours before it must stop, warm up to the helium bath temperature (1.3 K), and dump the accumulated heat. Future detector arrays will be much larger and will have higher heat dissipation. Furthermore, future missions will use mechanical cryocoolers to provide upper stage cooling, but they can only reach 4 - 10 K. Trying to scale heavy (-15 kg) single stage ADRs up to the higher heat loads and higher heat rejection temperatures required leads to unacceptably large systems. The GSFC Cryogenics Branch has developed the Continuous ADR (CADR) to solve this problem. The CADR consists of a series of ADR stages that sequentially pass heat from the load up to the high temperature heat sink. The stage connected to the load remains at a constant temperature. The continuous stage effectively decouples detector operation from ADR operation, allowing the ADR stages to be cycled much more rapidly. Rapid cycling leads to higher cooling power density. The cascading, multistage arrangement allows the magnetic refrigerant of each stage to be optimized for its own temperature swing. In the past year, we have made good progress toward a 0.05 to 10K system. A four-stage system that operates from 4.2 K was demonstrated. Magnetic shielding was added to eliminate inter-stage coupling. Improvements were made to superconducting and passive gas-gap heat switches. A second type of passive gas gap switch, one meant for use at higher temperature, was demonstrated. The presentation will focus primarily on these recent design improvements, and on the challenges that remain on the progress toward a system that will operate from 10 K or higher.

Continuous Magnetic Refrigerators for Cooling in the 0.05 to 10 K Range: Progress and Future Development

NASA Technical Reports Server (NTRS)

Shirron, Peter; DiPirro, Michael; Canavan, Edgar; Tuttle, James; King, Todd; Numazawa, Takenori

2003-01-01

Low temperature refrigeration is an increasingly vital technology for NASA s Space Science program since most detectors being developed for x-ray, IR and sub-millimeter missions must be cooled to below 100 mK in order to meet the requirements for energy and spatial resolution. For space applications, magnetic refrigeration has an inherent advantage over alternative techniques because it does not depend on gravity. Adiabatic demagnetization refrigerators, or ADRs, are relatively simple, solid state devices. The basic elements are a magnetocaloric refrigerant (usually an encapsulated paramagnetic salt) located in the bore of a superconducting magne$, and a heat switch linking the salt to a heat sink. The alignment of magnetic spins with the magnetic field causes the refrigerant to warm as the magnetic field increases and cool as the field decreases. Thus the simple process of magnetizing the refrigerant to high field with the heat switch closed, then demagnetizing it with the heat switch open allows one to obtain temperatures well below 100 mK using a heat sink as warm as 4.2 K. The refrigerant can maintain a low temperature for a length of time depending on the applied and parasitic heat loads, its mass, and the initial magnetic field strength. Typically ADRs are designed for 12-24 hours of hold time, after which they must be warmed up and recycled. The drawback to single-shot ADRs is that the cooling power per unit mass is relatively low. Refrigerants that are suitable for low temperature operation necessarily have low magnetic ion density, and therefore low entropy density. Since ADRs store entropy, systems with even modest cooling powers (a few microwatts) at temperatures below 100 mK tend to be massive, averaging 10-15 kg.

Thermal Buckling Analysis of Rectangular Panels Subjected to Humped Temperature Profile Heating

NASA Technical Reports Server (NTRS)

Ko, William I.

2004-01-01

This research investigates thermal buckling characteristics of rectangular panels subjected to different types of humped temperature profile heating. Minimum potential energy and finite-element methods are used to calculate the panel buckling temperatures. The two methods give fairly close thermal buckling solutions. 'Buckling temperature magnification factor of the first kind, eta' is established for the fixed panel edges to scale up the buckling solution of uniform temperature loading case to give the buckling solution of the humped temperature profile loading cases. Also, 'buckling temperature magnification factor of the second kind, xi' is established for the free panel edges to scale up the buckling solution of humped temperature profile loading cases with unheated boundary heat sinks to give the buckling solutions when the boundary heat sinks are heated up.

Fabrication of highly dense isotropic Nd-Fe-B nylon bonded magnets via extrusion-based additive manufacturing [Fabrication of highly dense isotropic Nd-Fe-B bonded magnets via extrusion-based additive manufacturing

DOE PAGES

Li, Ling; Jones, Kodey E.; Sales, Brian C.; ...

2018-04-03

Magnetically isotropic bonded magnets with a high loading fraction of 70 vol.% Nd-Fe-B are fabricated via an extrusion-based additive manufacturing, or 3D printing system that enables rapid production of large parts. The density of the printed magnet is ~5.2 g/cm 3. The room temperature magnetic properties are: intrinsic coercivity Hci = 8.9 kOe (708.2 kA/m), remanence Br = 5.8 kG (0.58 T), and energy product (BH)max = 7.3 MGOe (58.1 kJ/m 3). The as-printed magnets are then coated with two types of polymers, both of which improve the thermal stability as revealed by flux aging loss measurements. Tensile tests performedmore » at 25 °C and 100 °C show that the ultimate tensile stress (UTS) increases with increasing loading fraction of the magnet powder, and decreases with increasing temperature. AC magnetic susceptibility and resistivity measurements show that the 3D printed Nd-Fe-B bonded magnets exhibit extremely low eddy current loss and high resistivity. Lastly, we demonstrate the performance of the 3D printed magnets in a DC motor configuration via back electromotive force measurements.« less

Nitric Oxide Studies in Low Temperature Plasmas Generated with a Nanosecond Pulse Sphere Gap Electrical Discharge

NASA Astrophysics Data System (ADS)

Burnette, David Dean

This dissertation presents studies of NO kinetics in a plasma afterglow using various nanosecond pulse discharges across a sphere gap. The discharge platform is developed to produce a diffuse plasma volume large enough to allow for laser diagnostics in a plasma that is rich in vibrationally-excited molecules. This plasma is characterized by current and voltage traces as well as ICCD and NO PLIF images that are used to monitor the plasma dimensions and uniformity. Temperature and vibrational loading measurements are performed via coherent anti-Stokes Raman spectroscopy (CARS). Absolute NO concentrations are obtained by laser-induce fluorescence (LIF) measurements, and N and O densities are found using two photon absorption laser-induced fluorescence (TALIF). For all dry air conditions studied, the NO behavior is characterized by a rapid rate of formation consistent with an enhanced Zeldovich process involving electronically-excited nitrogen species that are generated within the plasma. After several microseconds, the NO evolution is entirely controlled by the reverse Zeldovich process. These results show that under the chosen range of conditions and even in extreme instances of vibrational loading, there is no formation channel beyond ~2 musec. Both the NO formation and consumption mechanisms are strongly affected by the addition of fuel species, producing much greater NO concentrations in the afterglow.

Fabrication of highly dense isotropic Nd-Fe-B nylon bonded magnets via extrusion-based additive manufacturing [Fabrication of highly dense isotropic Nd-Fe-B bonded magnets via extrusion-based additive manufacturing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Ling; Jones, Kodey E.; Sales, Brian C.

Magnetically isotropic bonded magnets with a high loading fraction of 70 vol.% Nd-Fe-B are fabricated via an extrusion-based additive manufacturing, or 3D printing system that enables rapid production of large parts. The density of the printed magnet is ~5.2 g/cm 3. The room temperature magnetic properties are: intrinsic coercivity Hci = 8.9 kOe (708.2 kA/m), remanence Br = 5.8 kG (0.58 T), and energy product (BH)max = 7.3 MGOe (58.1 kJ/m 3). The as-printed magnets are then coated with two types of polymers, both of which improve the thermal stability as revealed by flux aging loss measurements. Tensile tests performedmore » at 25 °C and 100 °C show that the ultimate tensile stress (UTS) increases with increasing loading fraction of the magnet powder, and decreases with increasing temperature. AC magnetic susceptibility and resistivity measurements show that the 3D printed Nd-Fe-B bonded magnets exhibit extremely low eddy current loss and high resistivity. Lastly, we demonstrate the performance of the 3D printed magnets in a DC motor configuration via back electromotive force measurements.« less

A Modeling Investigation of Thermal and Strain Induced Recovery and Nonlinear Hardening in Potential Based Viscoplasticity

NASA Technical Reports Server (NTRS)

Arnold, S. M.; Saleeb, A. F.; Wilt, T. E.

1993-01-01

Specific forms for both the Gibb's and the complementary dissipation potentials were chosen such that a complete potential based multiaxial, isothermal, viscoplastic model was obtained. This model in general possesses three internal state variables (two scalars associated with dislocation density and one tensor associated with dislocation motion) both thermal and dynamic recovery mechanisms, and nonlinear kinematic hardening. This general model, although possessing associated flow and evolutionary laws, is shown to emulate three distinct classes of theories found in the literature, by modification of the driving threshold function F. A parametric study was performed on a specialized nondimensional multiaxial form containing only a single tensorial internal state variable (i.e., internal stress). The study was conducted with the idea of examining the impact of including a strain-induced recovery mechanism and the compliance operator, derived from the Gibb's potential, on the uniaxial and multiaxial response. One important finding was that inclusion of strain recovery provided the needed flexibility in modeling stress-strain and creep response of metals at low homologous temperatures, without adversely affecting the high temperature response. Furthermore, for nonproportional loading paths, the inclusion of the compliance operator had a significant influence on the multiaxial response, but had no influence on either uniaxial or proportional load histories.

Estimation of constituent concentrations, densities, loads, and yields in lower Kansas River, northeast Kansas, using regression models and continuous water-quality monitoring, January 2000 through December 2003

USGS Publications Warehouse

Rasmussen, Teresa J.; Ziegler, Andrew C.; Rasmussen, Patrick P.

2005-01-01

The lower Kansas River is an important source of drinking water for hundreds of thousands of people in northeast Kansas. Constituents of concern identified by the Kansas Department of Health and Environment (KDHE) for streams in the lower Kansas River Basin include sulfate, chloride, nutrients, atrazine, bacteria, and sediment. Real-time continuous water-quality monitors were operated at three locations along the lower Kansas River from July 1999 through September 2004 to provide in-stream measurements of specific conductance, pH, water temperature, turbidity, and dissolved oxygen and to estimate concentrations for constituents of concern. Estimates of concentration and densities were combined with streamflow to calculate constituent loads and yields from January 2000 through December 2003. The Wamego monitoring site is located 44 river miles upstream from the Topeka monitoring site, which is 65 river miles upstream from the DeSoto monitoring site, which is 18 river miles upstream from where the Kansas River flows into the Missouri River. Land use in the Kansas River Basin is dominated by grassland and cropland, and streamflow is affected substantially by reservoirs. Water quality at the three monitoring sites varied with hydrologic conditions, season, and proximity to constituent sources. Nutrient and sediment concentrations and bacteria densities were substantially larger during periods of increased streamflow, indicating important contributions from nonpoint sources in the drainage basin. During the study period, pH remained well above the KDHE lower criterion of 6.5 standard units at all sites in all years, but exceeded the upper criterion of 8.5 standard units annually between 2 percent of the time (Wamego in 2001) and 65 percent of the time (DeSoto in 2003). The dissolved oxygen concentration was less than the minimum aquatic-life-support criterion of 5.0 milligrams per liter less than 1 percent of the time at all sites. Dissolved solids, a measure of the dissolved material in water, exceeded 500 milligrams per liter about one-half of the time at the three Kansas River sites. Larger dissolved-solids concentrations upstream likely were a result of water inflow from the highly mineralized Smoky Hill River that is diluted by tributary flow as it moves downstream. Concentrations of total nitrogen and total phosphorus at the three monitoring sites exceeded the ecoregion water-quality criteria suggested by the U.S. Environmental Protection Agency during the entire study period. Median nitrogen and phosphorus concentrations were similar at all three sites, and nutrient load increased moving from the upstream to downstream sites. Total nitrogen and total phosphorus yields were nearly the same from site to site indicating that nutrient sources were evenly distributed throughout the lower Kansas River Basin. About 11 percent of the total nitrogen load and 12 percent of the total phosphorus load at DeSoto during 2000-03 originated from wastewater-treatment facilities. Escherichia coli bacteria densities were largest at the middle site, Topeka. On average, 83 percent of the annual bacteria load at DeSoto during 2000-03 occurred during 10 percent of the time, primarily in conjunction with runoff. The average annual sediment loads at the middle and downstream monitoring sites (Topeka and DeSoto) were nearly double those at the upstream site (Wamego). The average annual sediment yield was largest at Topeka. On average, 64 percent of the annual suspended-sediment load at DeSoto during 2000-03 occurred during 10 percent of the time. Trapping of sediment by reservoirs located on contributing tributaries decreases transport of sediment and sediment-related constituents. The average annual suspended-sediment load in the Kansas River at DeSoto during 2000-03 was estimated at 1.66 million tons. An estimated 13 percent of this load consisted of sand-size particles, so approximately 216,000 tons of sand were transported

Global exospheric temperatures and densities under active solar conditions. [measured by OGO-6

NASA Technical Reports Server (NTRS)

Wydra, B. J.

1975-01-01

Temperatures measured by the OGO-6 satellite using the 6300 A airglow spectrum are compared with temperatures derived from total densities and N2 densities. It is shown that while the variation of the total densities with latitude and magnetic activity agree well with values used for CIRA (1972), the temperature behavior is very different. While the temperatures derived from the N2 density were in much better agreement there were several important differences which radically affect the pressure gradients. The variation of temperature with magnetic activity indicated a seasonal and local time effect and also a latitude and delay time variation different from previous density derived temperatures. A new magnetic index is proposed that is better correlated with the observed temperatures. The temperature variations at high latitudes were examined for three levels of magnetic activity for both solstices and equinox conditions. A temperature maximum in the pre-midnight sector and a minimum in the noon sector were noted and seasonal and geomagnetic time and latitude effects discussed. Neutral temperature, density, pressure and boundary oxygen variations for the great storm of March 8, 1970 are presented.

High performance light-colored nitrile-butadiene rubber nanocomposites.

PubMed

Lei, Yanda; Guo, Baochun; Chen, Feng; Zhu, Lixin; Zhou, Wenyou; Jia, Demin

2011-12-01

High mechanical performance nitrile-butadiene rubber (NBR) with light color was fabricated by the method of in situ formation of zinc disorbate (ZDS) or magnesium disorbate (MDS). The in situ formed ZDS and its polymerization via internal mixing was confirmed by X-ray diffaraction. The mechanical properties, ageing resistance, morphology and the dynamic mechanical analysis were fully studied. It was found that with increasing loading of metallic disorbate both the curing rate and the ionic crosslink density was largely increased. The modulus, tensile strength and tear strength were largely increased. With a comparison between internal mixing and opening mixing, the mechanical performance for the former one was obviously better than the latter one. The high performance was ascribed to the finely dispersion nano domains with irregular shape and obscure interfacial structures. Except for the NBR vulcanizate with a high loading of MDS, the others' ageing resistance with incorporation of these two metallic disorbate was found to be good. Dynamic mechanical analysis (DMA) showed that, with increasing loading of metallic disorbate, the highly increased storage modulus above -20 degrees C, the up-shifted glass transition temperature (Tg) and the reduced mechanical loss were ascribed to strengthened interfacial interactions.

Bentonite-Clay Waste Form for the Immobilization of Cesium and Strontium from Fuel Processing Waste Streams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaminski, Michael D.; Mertz, Carol J.

2016-01-01

The physical properties of a surrogate waste form containing cesium, strontium, rubidium, and barium sintered into bentonite clay were evaluated for several simulant feed streams: chlorinated cobalt dicarbollide/polyethylene glycol (CCD-PEG) strip solution, nitrate salt, and chloride salt feeds. We sintered bentonite clay samples with a loading of 30 mass% of cesium, strontium, rubidium, and barium to a density of approximately 3 g/cm 3. Sintering temperatures of up to 1000°C did not result in volatility of cesium. Instead, there was an increase in crystallinity of the waste form upon sintering to 1000ºC for chloride- and nitrate-salt loaded clays. The nitrate saltmore » feed produced various cesium pollucite phases, while the chloride salt feed did not produce these familiar phases. In fact, many of the x-ray diffraction peaks could not be matched to known phases. Assemblages of silicates were formed that incorporated the Sr, Rb, and Ba ions. Gas evolution during sintering to 1000°C was significant (35% weight loss for the CCD-PEG waste-loaded clay), with significant water being evolved at approximately 600°C.« less

Probe manipulators for Wendelstein 7-X and their interaction with the magnetic topology

NASA Astrophysics Data System (ADS)

M, RACK; D, HÖSCHEN; D, REITER; B, UNTERBERG; J, W. COENEN; S, BREZINSEK; O, NEUBAUER; S, BOZHENKOV; G, CZYMEK; Y, LIANG; M, HUBENY; Ch, LINSMEIER; the Wendelstein 7-X Team

2018-05-01

Probe manipulators are a versatile addition to typical plasma edge diagnostics. Equipped with material samples they allow for detailed investigation of plasma–wall interaction processes, such as material erosion, deposition or impurity transport pathways. When combined with electrical probes, a study of scrape-off layer and plasma edge density, temperature and flow profiles as well as magnetic topologies is possible. A mid-plane manipulator is already in operation on Wendelstein 7-X. A system in the divertor region is currently under development. In the present paper we discuss the critical issue of heat and power loads, power redistribution and experimental access to the complex magnetic topology of Wendelstein 7-X. All the aforementioned aspects are of relevance for the design and operation of a probe manipulator in a device like Wendelstein 7-X. A focus is put on the topological region that is accessible for the different coil current configurations at Wendelstein 7-X and the power load on the manipulator with respect to the resulting different magnetic configurations. Qualitative analysis of power loads on plasma-facing components is performed using a numerical tracer particle diffusion tool provided via the Wendelstein 7-X Webservices.

Energy balance in a Z pinch with suppressed Rayleigh-Taylor instability

NASA Astrophysics Data System (ADS)

Baksht, R. B.; Oreshkin, V. I.; Rousskikh, A. G.; Zhigalin, A. S.

2018-03-01

At present Z-pinch has evolved into a powerful plasma source of soft x-ray. This paper considers the energy balance in a radiating metallic gas-puff Z pinch. In this type of Z pinch, a power-law density distribution is realized, promoting suppression of Rayleigh-Taylor (RT) instabilities that occur in the pinch plasma during compression. The energy coupled into the pinch plasma, is determined as the difference between the total energy delivered to the load from the generator and the magnetic energy of the load inductance. A calibrated voltage divider and a Rogowski coil were used to determine the coupled energy and the load inductance. Time-gated optical imaging of the pinch plasma showed its stable compression up to the stagnation phase. The pinch implosion was simulated using a 1D two-temperature radiative magnetohydrodynamic code. Comparison of the experimental and simulation results has shown that the simulation adequately describes the pinch dynamics for conditions in which RT instability is suppressed. It has been found that the proportion of the Ohmic heating in the energy balance of a Z pinch with suppressed RT instability is determined by Spitzer resistance and makes no more than ten percent.

Scaling Relations of Starburst-driven Galactic Winds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tanner, Ryan; Cecil, Gerald; Heitsch, Fabian, E-mail: rytanner@augusta.edu

2017-07-10

Using synthetic absorption lines generated from 3D hydrodynamical simulations, we explore how the velocity of a starburst-driven galactic wind correlates with the star formation rate (SFR) and SFR density. We find strong correlations for neutral and low ionized gas, but no correlation for highly ionized gas. The correlations for neutral and low ionized gas only hold for SFRs below a critical limit set by the mass loading of the starburst, above which point the scaling relations flatten abruptly. Below this point the scaling relations depend on the temperature regime being probed by the absorption line, not on the mass loading.more » The exact scaling relation depends on whether the maximum or mean velocity of the absorption line is used. We find that the outflow velocity of neutral gas can be up to five times lower than the average velocity of ionized gas, with the velocity difference increasing for higher ionization states. Furthermore, the velocity difference depends on both the SFR and mass loading of the starburst. Thus, absorption lines of neutral or low ionized gas cannot easily be used as a proxy for the outflow velocity of the hot gas.« less

A method for continuous monitoring of the Ground Reaction Force during daily activity

NASA Technical Reports Server (NTRS)

Whalen, Robert; Quintana, Jason; Emery, Jeff

1993-01-01

Theoretical models and experimental studies of bone remodeling have identified peak cyclic force levels (or cyclic tissue strain energy density), number of daily loading cycles, and load (strain) rate as possible contributors to bone modeling and remodeling stimulus. To test our theoretical model and further investigate the influence of mechanical forces on bone density, we have focused on the calcaneus as a model site loaded by calcaneal surface tractions which are predominantly determined by the magnitude of the external ground reaction force (GRF).

Upper Atmospheric Monitoring for Ares I-X Ascent Loads and Trajectory Evaluation on the Day-of-Launch

NASA Technical Reports Server (NTRS)

Roberts, Barry C.; McGrath, Kevin; Starr, Brett; Brandon, Jay

2009-01-01

During the launch countdown of the Ares I-X test vehicle, engineers from Langley Research Center will use profiles of atmospheric density and winds in evaluating vehicle ascent loads and controllability. A schedule for the release of balloons to measure atmospheric density and winds has been developed by the Natural Environments Branch at Marshall Space Flight Center to help ensure timely evaluation of the vehicle ascent loads and controllability parameters and support a successful launch of the Ares I-X vehicle.

Understanding the Thermal Stability of Palladium–Platinum Core–Shell Nanocrystals by In Situ Transmission Electron Microscopy and Density Functional Theory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vara, Madeline; Roling, Luke T.; Wang, Xue

Core–shell nanocrystals offer many advantages for heterogeneous catalysis, including precise control over both the surface structure and composition, as well as reduction in loading for rare and costly metals. Although many catalytic processes are operated at elevated temperatures, the adverse impacts of heating on the shape and structure of core–shell nanocrystals are yet to be understood. In this work, we used ex situ heating experiments to demonstrate that Pd@Pt 4L core–shell nanoscale cubes and octahedra are promising for catalytic applications at temperatures up to 400 °C. We also used in situ transmission electron microscopy to monitor the thermal stability ofmore » the core–shell nanocrystals in real time. Our results demonstrate a facet dependence for the thermal stability in terms of shape and composition. Specifically, the cubes enclosed by {100} facets readily deform shape at a temperature 300 °C lower than that of the octahedral counterparts enclosed by {111} facets. A reversed trend is observed for composition, as alloying between the Pd core and the Pt shell of an octahedron occurs at a temperature 200 °C lower than that for the cubic counterpart. Density functional theory calculations provide atomic-level explanations for the experimentally observed behaviors, demonstrating that the barriers for edge reconstruction determine the relative ease of shape deformation for cubes compared to octahedra. Furthermore, the opposite trend for alloying of the core–shell structure can be attributed to a higher propensity for subsurface Pt vacancy formation in octahedra than in cubes.« less

Understanding the Thermal Stability of Palladium–Platinum Core–Shell Nanocrystals by In Situ Transmission Electron Microscopy and Density Functional Theory

DOE PAGES

Vara, Madeline; Roling, Luke T.; Wang, Xue; ...

2017-05-09

Core–shell nanocrystals offer many advantages for heterogeneous catalysis, including precise control over both the surface structure and composition, as well as reduction in loading for rare and costly metals. Although many catalytic processes are operated at elevated temperatures, the adverse impacts of heating on the shape and structure of core–shell nanocrystals are yet to be understood. In this work, we used ex situ heating experiments to demonstrate that Pd@Pt 4L core–shell nanoscale cubes and octahedra are promising for catalytic applications at temperatures up to 400 °C. We also used in situ transmission electron microscopy to monitor the thermal stability ofmore » the core–shell nanocrystals in real time. Our results demonstrate a facet dependence for the thermal stability in terms of shape and composition. Specifically, the cubes enclosed by {100} facets readily deform shape at a temperature 300 °C lower than that of the octahedral counterparts enclosed by {111} facets. A reversed trend is observed for composition, as alloying between the Pd core and the Pt shell of an octahedron occurs at a temperature 200 °C lower than that for the cubic counterpart. Density functional theory calculations provide atomic-level explanations for the experimentally observed behaviors, demonstrating that the barriers for edge reconstruction determine the relative ease of shape deformation for cubes compared to octahedra. Furthermore, the opposite trend for alloying of the core–shell structure can be attributed to a higher propensity for subsurface Pt vacancy formation in octahedra than in cubes.« less

Understanding the Thermal Stability of Palladium-Platinum Core-Shell Nanocrystals by In Situ Transmission Electron Microscopy and Density Functional Theory.

PubMed

Vara, Madeline; Roling, Luke T; Wang, Xue; Elnabawy, Ahmed O; Hood, Zachary D; Chi, Miaofang; Mavrikakis, Manos; Xia, Younan

2017-05-23

Core-shell nanocrystals offer many advantages for heterogeneous catalysis, including precise control over both the surface structure and composition, as well as reduction in loading for rare and costly metals. Although many catalytic processes are operated at elevated temperatures, the adverse impacts of heating on the shape and structure of core-shell nanocrystals are yet to be understood. In this work, we used ex situ heating experiments to demonstrate that Pd@Pt 4L core-shell nanoscale cubes and octahedra are promising for catalytic applications at temperatures up to 400 °C. We also used in situ transmission electron microscopy to monitor the thermal stability of the core-shell nanocrystals in real time. Our results demonstrate a facet dependence for the thermal stability in terms of shape and composition. Specifically, the cubes enclosed by {100} facets readily deform shape at a temperature 300 °C lower than that of the octahedral counterparts enclosed by {111} facets. A reversed trend is observed for composition, as alloying between the Pd core and the Pt shell of an octahedron occurs at a temperature 200 °C lower than that for the cubic counterpart. Density functional theory calculations provide atomic-level explanations for the experimentally observed behaviors, demonstrating that the barriers for edge reconstruction determine the relative ease of shape deformation for cubes compared to octahedra. The opposite trend for alloying of the core-shell structure can be attributed to a higher propensity for subsurface Pt vacancy formation in octahedra than in cubes.

Geophysical Age Dating of Seamounts using Dense Core Flexure Model

NASA Astrophysics Data System (ADS)

Hwang, Gyuha; Kim, Seung-Sep

2016-04-01

Lithospheric flexure of oceanic plate is thermo-mechanical response of an elastic plate to the given volcanic construct (e.g., seamounts and ocean islands). If the shape and mass of such volcanic loads are known, the flexural response is governed by the thickness of elastic plate, Te. As the age of oceanic plate increases, the elastic thickness of oceanic lithosphere becomes thicker. Thus, we can relate Te with the age of plate at the time of loading. To estimate the amount of the driving force due to seamounts on elastic plate, one needs to approximate their density structure. The most common choice is uniform density model, which utilizes constant density value for a seamount. This approach simplifies computational processes for gravity prediction and error estimates. However, the uniform density model tends to overestimate the total mass of the seamount and hence produces more positive gravitational contributions from the load. Minimization of gravity misfits using uniform density, therefore, favors thinner Te in order to increase negative contributions from the lithospheric flexure, which can compensate for the excessive positives from the seamount. An alternative approach is dense core model, which approximate the heterogeneity nature of seamount density as three bodies of infill sediment, edifice, and dense core. In this study, we apply the dense core model to the Louisville Seamount Chain for constraining flexural deformation. We compare Te estimates with the loading time of the examined seamounts to redefine empirical geophysical age dating of seamounts.

Design of Friction Stir Spot Welding Tools by Using a Novel Thermal-Mechanical Approach

PubMed Central

Su, Zheng-Ming; Qiu, Qi-Hong; Lin, Pai-Chen

2016-01-01

A simple thermal-mechanical model for friction stir spot welding (FSSW) was developed to obtain similar weld performance for different weld tools. Use of the thermal-mechanical model and a combined approach enabled the design of weld tools for various sizes but similar qualities. Three weld tools for weld radii of 4, 5, and 6 mm were made to join 6061-T6 aluminum sheets. Performance evaluations of the three weld tools compared fracture behavior, microstructure, micro-hardness distribution, and welding temperature of welds in lap-shear specimens. For welds made by the three weld tools under identical processing conditions, failure loads were approximately proportional to tool size. Failure modes, microstructures, and micro-hardness distributions were similar. Welding temperatures correlated with frictional heat generation rate densities. Because the three weld tools sufficiently met all design objectives, the proposed approach is considered a simple and feasible guideline for preliminary tool design. PMID:28773800

Design of Friction Stir Spot Welding Tools by Using a Novel Thermal-Mechanical Approach.

PubMed

Su, Zheng-Ming; Qiu, Qi-Hong; Lin, Pai-Chen

2016-08-09

A simple thermal-mechanical model for friction stir spot welding (FSSW) was developed to obtain similar weld performance for different weld tools. Use of the thermal-mechanical model and a combined approach enabled the design of weld tools for various sizes but similar qualities. Three weld tools for weld radii of 4, 5, and 6 mm were made to join 6061-T6 aluminum sheets. Performance evaluations of the three weld tools compared fracture behavior, microstructure, micro-hardness distribution, and welding temperature of welds in lap-shear specimens. For welds made by the three weld tools under identical processing conditions, failure loads were approximately proportional to tool size. Failure modes, microstructures, and micro-hardness distributions were similar. Welding temperatures correlated with frictional heat generation rate densities. Because the three weld tools sufficiently met all design objectives, the proposed approach is considered a simple and feasible guideline for preliminary tool design.

Performance Optimization of Irreversible Air Heat Pumps Considering Size Effect

NASA Astrophysics Data System (ADS)

Bi, Yuehong; Chen, Lingen; Ding, Zemin; Sun, Fengrui

2018-06-01

Considering the size of an irreversible air heat pump (AHP), heating load density (HLD) is taken as thermodynamic optimization objective by using finite-time thermodynamics. Based on an irreversible AHP with infinite reservoir thermal-capacitance rate model, the expression of HLD of AHP is put forward. The HLD optimization processes are studied analytically and numerically, which consist of two aspects: (1) to choose pressure ratio; (2) to distribute heat-exchanger inventory. Heat reservoir temperatures, heat transfer performance of heat exchangers as well as irreversibility during compression and expansion processes are important factors influencing on the performance of an irreversible AHP, which are characterized with temperature ratio, heat exchanger inventory as well as isentropic efficiencies, respectively. Those impacts of parameters on the maximum HLD are thoroughly studied. The research results show that HLD optimization can make the size of the AHP system smaller and improve the compactness of system.

Advanced Strain-Isolation-Pad Material with Bonded Fibrous Construction

NASA Technical Reports Server (NTRS)

Seibold, R. W.; Saito, C. A.; Buller, B. W.

1982-01-01

The feasibility of utilizing air lay and liquid lay felt deposition techniques to fabricate strain isolation pad (SIP) materials for the Space Shuttle Orbiter was demonstrated. These materials were developed as candidate replacements for the present needled felt SIP used between the ceramic tiles and the aluminum skin on the undersurface of the Orbiter. The SIP materials that were developed consisted of high temperature aramid fibers deposited by controlled fluid (air or liquid) carriers to form low density unbonded felts. The deposited felts were then bonded at the fiber intersections with a small amount of high temperature polyimide resin. This type of bonded felt construction can potentially eliminate two of the problems associated with the present SIP, viz., transmittal of localized stresses into the tiles and load history dependent mechanical response. However, further work is needed to achieve adequate through thickness tensile strength in the bonded felts.

In-Situ Optical Determination of Thermomechanical Properties of ZnSe and ZnTe Crystals

NASA Technical Reports Server (NTRS)

Burger, A.; Ndap, J.-O.; Chattopadhyay, K.; Ma, X.; Silberman, E.; Feth, S.; Palosz, W.; Su, C.-H.

1999-01-01

At temperatures above 1/2 T(sub m), the generation and movement of dislocations may result due to the load created by the weight of the crystal itself The deformation may be expected to increase the line defect density and may result in generation of low angle grain boundaries, especially in the regions of the crystal attached to the ampule. It has often been suspected that elimination of this effect in space can improve crystallinity of crystals grown under microgravity conditions, however, a direct experimental proof of such relation is still missing. In this work we have designed and built a system of in-situ optical detection and measurement of the mechanical deformations of a crystal wafer under its own weight, and studied the deformation effects as a function of temperature. The results of the measurements for ZnSe and ZnTe crystal wafers will be presented.

Phenomenological study of a cellular material behaviour under dynamic loadings

NASA Astrophysics Data System (ADS)

Bouix, R.; Viot, Ph.; Lataillade, J.-L.

2006-08-01

Polypropylene foams are cellular materials, which are often use to fill structures subjected to crash or violent impacts. Therefore, it is necessary to know and to characterise in experiments their mechanical behaviour in compression at high strain rates. So, several apparatus have been used in order to highlight the influence of strain rate, material density and also temperature. A split Hopkinson Pressure Bar has been used for impact tests, a fly wheel to test theses materials at medium strain rate and an electro-mechanical testing machine associated to a climatic chamber for temperature tests. Then, a rheological model has been used in order to describe the material behaviour. The mechanical response to compression of these foams presents three typical domains: a linear elastic step, a wide collapse plateau stress, which leads to a densification, which are related to a standard rheological model.

Thermal Peak Management Using Organic Phase Change Materials for Latent Heat Storage in Electronic Applications

PubMed Central

Maxa, Jacob; Novikov, Andrej; Nowottnick, Mathias

2017-01-01

Modern high power electronics devices consists of a large amount of integrated circuits for switching and supply applications. Beside the benefits, the technology exhibits the problem of an ever increasing power density. Nowadays, heat sinks that are directly mounted on a device, are used to reduce the on-chip temperature and dissipate the thermal energy to the environment. This paper presents a concept of a composite coating for electronic components on printed circuit boards or electronic assemblies that is able to buffer a certain amount of thermal energy, dissipated from a device. The idea is to suppress temperature peaks in electronic components during load peaks or electronic shorts, which otherwise could damage or destroy the device, by using a phase change material to buffer the thermal energy. The phase change material coating could be directly applied on the chip package or the PCB using different mechanical retaining jigs.

Effect of production microclimate on female thermal state with increased temperature and air humidity

NASA Technical Reports Server (NTRS)

Machablishvili, O. G.

1980-01-01

The thermal state of women during the effect of high air temperature and relative humidity with a varying degree of physical loads was studied. Parameters for air temperature, relative humidity, and air movement were established. It was established that in women the thermo-regulatory stress occurs at lower air temperatures and with lower physical loads than in men. The accumulation of heat in women was revealed with lower air temperature than in men. It is concluded that to preserve the normal physiological state of the female organism it is necessary to create more favorable microclimate conditions and decrease the physical loads.

Native and domestic browsers and grazers reduce fuels, fire temperatures, and acacia ant mortality in an African savanna.

PubMed

Kimuyu, Duncan M; Sensenig, Ryan L; Riginos, Corinna; Veblen, Kari E; Young, Truman P

2014-06-01

Despite the importance of fire and herbivory in structuring savanna systems, few replicated experiments have examined the interactive effects of herbivory and fire on plant dynamics. In addition, the effects of fire on associated ant-tree mutualisms have been largely unexplored. We carried out small controlled burns in each of 18 herbivore treatment plots of the Kenya Long-term Exclosure Experiment (KLEE), where experimentally excluding elephants has resulted in 42% greater tree densities. The KLEE design includes six different herbivore treatments that allowed us to examine how different combinations of megaherbivore wildlife, mesoherbivore wildlife, and cattle affect fire temperatures and subsequent loss of ant symbionts from Acacia trees. Before burning, we quantified herbaceous fuel loads and plant community composition. We tagged all trees, measured their height and basal diameter, and identified the resident ant species on each. We recorded weather conditions during the burns and used ceramic tiles painted with fire-sensitive paints to estimate fire temperatures at different heights and in different microsites (under vs. between trees). Across all treatments, fire temperatures were highest at 0-50 cm off the ground and hotter in the grass under trees than in the grassy areas between trees. Plots with more trees burned hotter than plots with fewer trees, perhaps because of greater fine woody debris. Plots grazed by wildlife and by cattle prior to burning had lower herbaceous fuel loads and experienced lower burn temperatures than ungrazed plots. Many trees lost their ant colonies during the burns. Ant survivorship differed by ant species and at the plot level was positively associated with previous herbivory (and lower fire temperatures). Across all treatments, ant colonies on taller trees were more likely to survive, but even some of the tallest trees lost their ant colonies. Our study marks a significant step in understanding the mechanisms that underlie the interactions between fire and herbivory in savanna ecosystems.

Load sensing system

DOEpatents

Sohns, C.W.; Nodine, R.N.; Wallace, S.A.

1999-05-04

A load sensing system inexpensively monitors the weight and temperature of stored nuclear material for long periods of time in widely variable environments. The system can include an electrostatic load cell that encodes weight and temperature into a digital signal which is sent to a remote monitor via a coaxial cable. The same cable is used to supply the load cell with power. When multiple load cells are used, vast inventories of stored nuclear material can be continuously monitored and inventoried of minimal cost. 4 figs.

Densities and temperatures in the polar thermosphere

NASA Technical Reports Server (NTRS)

Gardner, L. J.

1977-01-01

The atomic oxygen density at 120 km, the 630 nm airglow temperature, the helium density at 300 km and the molecular nitrogen density near 400 km were examined as functions of geomagnetic latitude, geomagnetic time, season and magnetic activity level. The long-term averages of these quantities were examined so as to provide a baseline of these thermospheric parameters from which future studies may be made for comparison. The hours around magnetic noon are characterized by low temperatures, high 0 and He densities, and median nitrogen densities. The pre-midnight hours exhibit high temperatures, high He density, low nitrogen density and median 0 densities. The post-midnight sector shows low 0 and He densities, median temperatures and high nitrogen densities. These results are compared to recent models and observations and are discussed with respect to their causes due to divergence of the wind field and energy deposition in the thermosphere.

Impacct of scalding duration and scalding water temperature on broiler processing wastewater loadings

USDA-ARS?s Scientific Manuscript database

The effects of scalding water temperature and immersion time on impact to poultry processing wastewater (PPW) loading were evaluated following the slaughter of commercially raised broilers. Based on previous research, the hypothesis was that immersion time would have a significant impact on PPW load...

Delivery of enteric neural progenitors with 5-HT4 agonist-loaded nanoparticles and thermosensitive hydrogel enhances cell proliferation and differentiation following transplantation in vivo

PubMed Central

Graham, Hannah K.; Nagy, Nandor; Belkind-Gerson, Jaime; Mattheolabakis, George; Amiji, Mansoor M.; Goldstein, Allan M.

2016-01-01

Cell therapy offers an innovative approach for treating enteric neuropathies. Postnatal gut-derived enteric neural stem/progenitor cells (ENSCs) represent a potential autologous source, but have a limited capacity for proliferation and neuronal differentiation. Since serotonin (5-HT) promotes enteric neuronal growth during embryonic development, we hypothesized that serotonin receptor agonism would augment growth of neurons from transplanted ENSCs. Postnatal ENSCs were isolated from 2-4 week-old mouse colon and cultured with 5-HT4 receptor agonist (RS67506)-loaded liposomal nanoparticles. ENSCs were co-cultured with mouse colon explants in the presence of RS67506-loaded (n=3) or empty nanoparticles (n=3). ENSCs were also transplanted into mouse rectum in vivo with RS67506-loaded (n=8) or blank nanoparticles (n=4) confined in a thermosensitive hydrogel, Pluronic F-127. Neuronal density and proliferation were analyzed immunohistochemically. Cultured ENSCs gave rise to significantly more neurons in the presence of RS67506-loaded nanoparticles. Similarly, colon explants had significantly increased neuronal density when RS67506-loaded nanoparticles were present. Finally, following in vivo cell delivery, co-transplantation of ENSCs with 5-HT4 receptor agonist-loaded nanoparticles led to significantly increased neuronal density and proliferation. We conclude that optimization of postnatal ENSCs can support their use in cell-based therapies for neurointestinal diseases. PMID:26922325

Compliant Foil Journal Bearing Performance at Alternate Pressures and Temperatures

NASA Technical Reports Server (NTRS)

Bruckner, Robert J.; Puleo, Bernadette J.

2008-01-01

An experimental test program has been conducted to determine the highly loaded performance of current generation gas foil bearings at alternate pressures and temperatures. Typically foil bearing performance has been reported at temperatures relevant to turbomachinery applications but only at an ambient pressure of one atmosphere. This dearth of data at alternate pressures has motivated the current test program. Two facilities were used in the test program, the ambient pressure rig and the high pressure rig. The test program utilized a 35 mm diameter by 27 mm long foil journal bearing having an uncoated Inconel X-750 top foil running against a shaft with a PS304 coated journal. Load capacity tests were conducted at 3, 6, 9, 12, 15, 18, and 21 krpm at temperatures from 25 to 500 C and at pressures from 0.1 to 2.5 atmospheres. Results show an increase in load capacity with increased ambient pressure and a reduction in load capacity with increased ambient temperature. Below one-half atmosphere of ambient pressure a dramatic loss of load capacity is experienced. Additional lightly loaded foil bearing performance in nitrogen at 25 C and up to 48 atmospheres of ambient pressure has also been reported. In the lightly loaded region of operation the power loss increases for increasing pressure at a fixed load. Knowledge of foil bearing performance at operating conditions found within potential machine applications will reduce program development risk of future foil bearing supported turbomachines.

Effect of temperature on the orthodontic clinical applications of niti closed-coil springs

PubMed Central

Espinar-Escalona, Eduardo; Llamas-Carreras, José M.; Barrera-Mora, José M.; Abalos-Lasbrucci, Camilo

2013-01-01

NiTi spring coils were used to obtain large deformation under a constant force. The device consists on a NiTi coil spring, superelastic at body temperature, in order to have a stress plateau during the austenitic retransformation during the unloading. The temperature variations induced changes in the spring force. Objectives: The aim of this study is to investigate the effect of the temperature variations in the spring forces and corrosion behaviour simulating the ingestion hot/cold drinks and food. Study Design: The springs were subjected to a tensile force using universal testing machine MTS-Adamel (100 N load cell). All tests were performed in artificial saliva maintained at different temperatures. The corrosion tests were performed according to the ISO-standard 10993-15:2000. Results: The increase in temperature of 18oC induced an increase in the spring force of 30%. However, when the temperature returns to 37oC the distraction force recovers near the initial level. After cooling down the spring to 15oC, the force decreased by 46%. This investigation show as the temperature increase, the corrosion potential shifts towards negative values and the corrosion density is rising. Conclusions: The changes of the temperatures do not modify the superelastic behaviour of the NiTi closed-coil springs. The corrosion potential of NiTi in artificial saliva is decreasing by the rise of the temperatures. Key words:Superelasticity, NiTi, springs, orthodontic, coils, recovery, temperature. PMID:23722142

Roughness and temperature effects on the filter media of a trickling filter for nitrification.

PubMed

Kishimoto, Naoyuki; Ohara, Tetsuya; Hinobayashi, Jouji; Hashimoto, Tsutomu

2014-01-01

The performance of trickling filters using two types of plastic media with the same material, the same shape and different roughness was evaluated during a temperature-decreasing period to understand the roughness and temperature effects on the filter media. Real restaurant wastewater was used for the experiments. The chemical oxygen demand (COD) removal and nitrification performance of plastic media with a rough surface (LT-15) was superior to that with a smooth surface (KT-15). Because the biomass of microorganisms attached on the LT-15 was twice that attached on the KT-15, the larger biomass attached on the LT-15 was thought to be responsible for the higher performance. During the operation, the COD loading and water temperature varied in the range from 0.37 to 1.9 kg m(-3) d(-1) and 17.0--10.0 degrees C, respectively. However, the COD removal performance was not dependent on the COD loading or water temperature. On the contrary, the COD loading and the water temperature influenced the nitrification performance. Although a nitrification efficiency of 100% was recorded at a COD loading of 0.37 kg m(-3) d(-1), it deteriorated to 17-28% at higher COD loading. Moreover, a decline in the water temperature decreased the nitrification performance. The temperature-activity coefficient for nitrification was estimated to be 1.096. Based on this value, it was inferred that the COD loading should be set at less than 0.20 kg m(-3) d(-1) for the complete nitrification of the restaurant wastewater in winter, when the water temperature usually drops to around 10 degrees C.

Application of Temperature Sensitivities During Iterative Strain-Gage Balance Calibration Analysis

NASA Technical Reports Server (NTRS)

Ulbrich, N.

2011-01-01

A new method is discussed that may be used to correct wind tunnel strain-gage balance load predictions for the influence of residual temperature effects at the location of the strain-gages. The method was designed for the iterative analysis technique that is used in the aerospace testing community to predict balance loads from strain-gage outputs during a wind tunnel test. The new method implicitly applies temperature corrections to the gage outputs during the load iteration process. Therefore, it can use uncorrected gage outputs directly as input for the load calculations. The new method is applied in several steps. First, balance calibration data is analyzed in the usual manner assuming that the balance temperature was kept constant during the calibration. Then, the temperature difference relative to the calibration temperature is introduced as a new independent variable for each strain--gage output. Therefore, sensors must exist near the strain--gages so that the required temperature differences can be measured during the wind tunnel test. In addition, the format of the regression coefficient matrix needs to be extended so that it can support the new independent variables. In the next step, the extended regression coefficient matrix of the original calibration data is modified by using the manufacturer specified temperature sensitivity of each strain--gage as the regression coefficient of the corresponding temperature difference variable. Finally, the modified regression coefficient matrix is converted to a data reduction matrix that the iterative analysis technique needs for the calculation of balance loads. Original calibration data and modified check load data of NASA's MC60D balance are used to illustrate the new method.

The effect of loading time on flexible pavement dynamic response: a finite element analysis

NASA Astrophysics Data System (ADS)

Yin, Hao; Solaimanian, Mansour; Kumar, Tanmay; Stoffels, Shelley

2007-12-01

Dynamic response of asphalt concrete (AC) pavements under moving load is a key component for accurate prediction of flexible pavement performance. The time and temperature dependency of AC materials calls for utilizing advanced material characterization and mechanistic theories, such as viscoelasticity and stress/strain analysis. In layered elastic analysis, as implemented in the new Mechanistic-Empirical Pavement Design Guide (MEPDG), the time dependency is accounted for by calculating the loading times at different AC layer depths. In this study, the time effect on pavement response was evaluated by means of the concept of “pseudo temperature.” With the pavement temperature measured from instrumented thermocouples, the time and temperature dependency of AC materials was integrated into one single factor, termed “effective temperature.” Via this effective temperature, pavement responses under a transient load were predicted through finite element analysis. In the finite element model, viscoelastic behavior of AC materials was characterized through relaxation moduli, while the layers with unbound granular material were assumed to be in an elastic mode. The analysis was conducted for two different AC mixtures in a simplified flexible pavement structure at two different seasons. Finite element analysis results reveal that the loading time has a more pronounced impact on pavement response in the summer for both asphalt types. The results indicate that for reasonable prediction of dynamic response in flexible pavements, the effect of the depth-dependent loading time on pavement temperature should be considered.

A temperature match based optimization method for daily load prediction considering DLC effect

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yu, Z.

This paper presents a unique optimization method for short term load forecasting. The new method is based on the optimal template temperature match between the future and past temperatures. The optimal error reduction technique is a new concept introduced in this paper. Two case studies show that for hourly load forecasting, this method can yield results as good as the rather complicated Box-Jenkins Transfer Function method, and better than the Box-Jenkins method; for peak load prediction, this method is comparable in accuracy to the neural network method with back propagation, and can produce more accurate results than the multi-linear regressionmore » method. The DLC effect on system load is also considered in this method.« less

FPGA-based prototype storage system with phase change memory

NASA Astrophysics Data System (ADS)

Li, Gezi; Chen, Xiaogang; Chen, Bomy; Li, Shunfen; Zhou, Mi; Han, Wenbing; Song, Zhitang

2016-10-01

With the ever-increasing amount of data being stored via social media, mobile telephony base stations, and network devices etc. the database systems face severe bandwidth bottlenecks when moving vast amounts of data from storage to the processing nodes. At the same time, Storage Class Memory (SCM) technologies such as Phase Change Memory (PCM) with unique features like fast read access, high density, non-volatility, byte-addressability, positive response to increasing temperature, superior scalability, and zero standby leakage have changed the landscape of modern computing and storage systems. In such a scenario, we present a storage system called FLEET which can off-load partial or whole SQL queries to the storage engine from CPU. FLEET uses an FPGA rather than conventional CPUs to implement the off-load engine due to its highly parallel nature. We have implemented an initial prototype of FLEET with PCM-based storage. The results demonstrate that significant performance and CPU utilization gains can be achieved by pushing selected query processing components inside in PCM-based storage.

A novel liquid organic hydrogen carrier system based on catalytic peptide formation and hydrogenation

PubMed Central

Hu, Peng; Fogler, Eran; Diskin-Posner, Yael; Iron, Mark A.; Milstein, David

2015-01-01

Hydrogen is an efficient green fuel, but its low energy density when stored under high pressure or cryogenically, and safety issues, presents significant disadvantages; hence finding efficient and safe hydrogen carriers is a major challenge. Of special interest are liquid organic hydrogen carriers (LOHCs), which can be readily loaded and unloaded with considerable amounts of hydrogen. However, disadvantages include high hydrogen pressure requirements, high reaction temperatures for both hydrogenation and dehydrogenation steps, which require different catalysts, and high LOHC cost. Here we present a readily reversible LOHC system based on catalytic peptide formation and hydrogenation, using an inexpensive, safe and abundant organic compound with high potential capacity to store and release hydrogen, applying the same catalyst for loading and unloading hydrogen under relatively mild conditions. Mechanistic insight of the catalytic reaction is provided. We believe that these findings may lead to the development of an inexpensive, safe and clean liquid hydrogen carrier system. PMID:25882348

Application and advantages of novel clay ceramic particles (CCPs) in an up-flow anaerobic bio-filter (UAF) for wastewater treatment.

PubMed

Han, Wei; Yue, Qinyan; Wu, Suqing; Zhao, Yaqin; Gao, Baoyu; Li, Qian; Wang, Yan

2013-06-01

Utilization of clay ceramic particles (CCPs) as the novel filter media employed in an up-flow anaerobic bio-filter (UAF) was investigated. After a series of tests and operations, CCPs have presented higher total porosity and roughness, meanwhile lower bulk and grain density. When CCPs were utilized as fillers, the reactor had a shorter start up period of 45 days comparing with conventional reactors, and removal rate of chemical oxygen demand (COD) still reached about 76% at a relatively lower temperature during the stable state. In addition, degradation of COD and ammonia nitrogen (NH4-N) at different media height along the reactor was evaluated, and the dates showed that the main reduction process happened within the first 30 cm media height from the bottom flange. Five phases were observed according to different organic loadings during the experiment period, and the results indicated that COD removal increased linearly when the organic loading was increased. Copyright © 2013 Elsevier Ltd. All rights reserved.

The influence of loading frequency on the high-temperature fatigue behavior of a Nicalon-fabric-reinforced polymer-derived ceramic-matrix composite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vanswijgenhoven, E.; Holmes, J.; Wevers, M.

Fiber-reinforced ceramic-matrix composites are under development for high-temperature structural applications. These applications involve fatigue loading under a wide range of frequencies. To date, high-temperature fatigue experiments have typically been performed at loading frequencies of 10 Hz or lower. At higher frequencies, a strong effect of loading frequency on fatigue life has been demonstrated for certain CMC`s tested at room temperature. The fatigue life of CMC`s with weak fiber-matrix interfaces typically decreases as the loading frequency increases. This decrease is attributed to frictional heating and frequency dependent interface and fiber damage. More recently, it has been shown that the room temperaturemore » fatigue life of a Nicalon-fabric-reinforced composite with a strong interface (SYLRAMIC{trademark}) appears to be independent of loading frequency. The high-temperature low-frequency fatigue behavior of the SYLRAMIC composite has also been investigated. For a fatigue peak stress {sigma}{sub peak} above a proportional limit stress of 70 MPa, the number of cycles to failure N{sub f} decreased with an increase in {sigma}{sub peak}. The material endured more than 10{sup 6} cycles for {sigma}{sub peak} below 70 MPa. In this paper, the influence of loading frequency on the high-temperature fatigue behavior of the SYLRAMIC composite is reported. It will be shown that the fatigue limit is unaffected by the loading frequency, that the number of fatigue cycles to failure N{sub f} increases with an increase in frequency, and that the time to failure t{sub f} decreases with an increase in frequency.« less

Structural characteristics of methylsilsesquioxane based porous low-k thin films fabricated with increasing cross-linked particle porogen loading

NASA Astrophysics Data System (ADS)

Lee, Hae-Jeong; Soles, Christopher L.; Liu, Da-Wei; Bauer, Barry J.; Lin, Eric K.; Wu, Wen-Li; Gallagher, Michael

2006-09-01

Methylsilsesquioxane (MSQ) based porous low-k dielectric films are characterized by x-ray porosimetry (XRP) to determine their pore size distribution, average density, wall density, and porosity. By varying the porogen content from 1% to 30% by mass, the porosity changes from 12% to 34% by volume, indicating that the base MSQ matrix material contains approximately 10% by volume inherent microporosity. The wall density of this matrix material is measured to be 1.33-1.35g/cm3, independent of porosity. The average pore radii determined from the XRP adsorption isotherms increase from 6to27Å with increased porogen loadings. Small angle neutron scattering measurements confirm these XRP average pore radii for the films with porogen loading higher than 10% by mass.

Early direct-injection, low-temperature combustion of diesel fuel in an optical engine utilizing a 15-hole, dual-row, narrow-included-angle nozzle.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gehrke, Christopher R.; Radovanovic, Michael S.; Milam, David M.

2008-04-01

Low-temperature combustion of diesel fuel was studied in a heavy-duty, single-cylinder optical engine employing a 15-hole, dual-row, narrow-included-angle nozzle (10 holes x 70/mD and 5 holes x 35/mD) with 103-/gmm-diameter orifices. This nozzle configuration provided the spray targeting necessary to contain the direct-injected diesel fuel within the piston bowl for injection timings as early as 70/mD before top dead center. Spray-visualization movies, acquired using a high-speed camera, show that impingement of liquid fuel on the piston surface can result when the in-cylinder temperature and density at the time of injection are sufficiently low. Seven single- and two-parameter sweeps around amore » 4.82-bar gross indicated mean effective pressure load point were performed to map the sensitivity of the combustion and emissions to variations in injection timing, injection pressure, equivalence ratio, simulated exhaust-gas recirculation, intake temperature, intake boost pressure, and load. High-speed movies of natural luminosity were acquired by viewing through a window in the cylinder wall and through a window in the piston to provide quasi-3D information about the combustion process. These movies revealed that advanced combustion phasing resulted in intense pool fires within the piston bowl, after the end of significant heat release. These pool fires are a result of fuel-films created when the injected fuel impinged on the piston surface. The emissions results showed a strong correlation with pool-fire activity. Smoke and NO/dx emissions rose steadily as pool-fire intensity increased, whereas HC and CO showed a dramatic increase with near-zero pool-fire activity.« less

Effects of different loading patterns on the trabecular bone morphology of the proximal femur using adaptive bone remodeling.

PubMed

Banijamali, S Mohammad Ali; Oftadeh, Ramin; Nazarian, Ara; Goebel, Ruben; Vaziri, Ashkan; Nayeb-Hashemi, Hamid

2015-01-01

In this study, the changes in the bone density of human femur model as a result of different loadings were investigated. The model initially consisted of a solid shell representing cortical bone encompassing a cubical network of interconnected rods representing trabecular bone. A computationally efficient program was developed that iteratively changed the structure of trabecular bone by keeping the local stress in the structure within a defined stress range. The stress was controlled by either enhancing existing beam elements or removing beams from the initial trabecular frame structure. Analyses were performed for two cases of homogenous isotropic and transversely isotropic beams.Trabecular bone structure was obtained for three load cases: walking, stair climbing and stumbling without falling. The results indicate that trabecular bone tissue material properties do not have a significant effect on the converged structure of trabecular bone. In addition, as the magnitude of the loads increase, the internal structure becomes denser in critical zones. Loading associated with the stumbling results in the highest density;whereas walking, considered as a routine daily activity, results in the least internal density in different regions. Furthermore, bone volume fraction at the critical regions of the converged structure is in good agreement with previously measured data obtained from combinations of dual X-ray absorptiometry (DXA) and computed tomography (CT). The results indicate that the converged bone architecture consisting of rods and plates are consistent with the natural bone morphology of the femur. The proposed model shows a promising means to understand the effects of different individual loading patterns on the bone density.

Quantitative Assessment of Temperature Sensitivity of the ...

EPA Pesticide Factsheets

The Total Maximum Daily Load (TMDL) program, established by the Clean Water Act, is used to establish limits on loading of pollutants from point and nonpoint sources necessary to achieve water quality standards. One important use of a temperature TMDL is to allocate thermal loads to achieve water temperature criteria established for the protection of cold water fisheries. The pollutant in this case is thermal load and allocations to reduce the load often involve restoration of stream shading, which reduces the solar input. While many temperature TMDLs have been established, the supporting analyses have generally assumed a stationary climate under which historical data on flow and air temperature can serve as an adequate guide to future conditions. Projected changes in climate over the 21st century contradict this assumption. Air temperature is expected to increase in most parts of the US, accompanied in many areas by seasonal shifts in the timing and amount of precipitation, which in turn will alter stream flow. This study evaluates the implications of climate change for the water temperature TMDL developed for the South Fork Nooksack River in northwest Washington by the Department of Ecology, where multiple water body segments exceed temperature criteria established for the protection of cold water salmonid populations (Ecology, 2016). The purpose of this report is to provide a “companion technical methods manual” as documentation for the draft SFNR tempera

Effect of water temperature on cyclic fatigue properties of glass-fiber-reinforced hybrid composite resin and its fracture pattern after flexural testing.

PubMed

Kuroda, Soichi; Shinya, Akikazu; Vallittu, Pekka K; Nakasone, Yuji; Shinya, Akiyoshi

2013-02-01

To evaluate in vitro the influence of dynamic loading applied to a glass-fiber-reinforced hybrid composite resin on its flexural strength in a moist, simulated oral environment. Three-point flexural strength specimens were subjected to cyclic loading in water at 37°C and 55°C to investigate the influence of immersion temperature on impact fatigue properties. Specimens were subjected to cyclic impact loading at 1 Hz for up to 5 × 105 cycles to obtain the number of cycles to failure, the number of unbroken specimens after 5 × 105 cycles, and the residual flexural strength of unbroken specimens. Maximum loads of 100, 200, and 300 N were chosen for both the non-reinforced and the glass-fiber reinforced hybrid composite resins. The mean residual flexural strength for 100 N impact loading at temperatures of 37°C and 55°C was 634 and 636 MPa, respectively. All specimens fractured at fewer than 5 × 105 cycles for loads of 200 and 300 N. Reduced numbers of cycles to fracture and lower fatigue values were observed as both the maximum load and immersion temperature increased.

Capillary Limit in a Loop Heat Pipe with Dual Evaporators

NASA Technical Reports Server (NTRS)

Ku, Jentung; Birur, Gajanana; Obenschain, Arthur F. (Technical Monitor)

2002-01-01

This paper describes a study on the capillary limit of a loop heat pipe (LHP) with two evaporators and two condensers. Both theoretical analysis and experimental investigation are conducted. Tests include heat load to one evaporator only, even heat loads to both evaporators and uneven heat load to both evaporators. Results show that after the capillary limit is exceeded, vapor will penetrate through the wick of the weaker evaporator and the compensation chamber (CC) of that evaporator will control the loop operating temperature regardless of which CC has been in control prior to the event Because the evaporator can tolerate vapor bubbles, the loop may continue to work and reach a new steady state at a higher operating temperature. The loop may even function with a modest increase in the heat load past the capillary limit With a heat load to only one evaporator, the capillary limit can be identified by rapid increases in the operating temperature and in the temperature difference between the evaporator and the CC. However, it is more difficult to tell when the capillary limit is exceeded if heat loads are applied to both evaporators. In all cases, the loop can recover by reducing the heat load to the loop.

Dynamic strain aging in stress controlled creep-fatigue tests of 316L stainless steel under different loading conditions

NASA Astrophysics Data System (ADS)

Jiang, Huifeng; Chen, Xuedong; Fan, Zhichao; Dong, Jie; Jiang, Heng; Lu, Shouxiang

2009-08-01

Stress controlled fatigue-creep tests were carried out for 316L stainless steel under different loading conditions, i.e. different loading levels at the fixed temperature (loading condition 1, LC1) and different temperatures at the fixed loading level (loading condition 2, LC2). Cyclic deformation behaviors were investigated with respect to the evolutions of strain amplitude and mean strain. Abrupt mean strain jumps were found during cyclic deformation, which was in response to the dynamic strain aging effect. Moreover, as to LC1, when the minimum stress is negative at 550 °C, abrupt mean strain jumps occur at the early stage of cyclic deformation and there are many jumps during the whole process. While the minimum stress is positive, mean strain only jumps once at the end of deformation. Similar results were also found in LC2, when the loading level is fixed at -100 to 385 MPa, at higher temperatures (560, 575 °C), abrupt mean strain jumps occur at the early stage of cyclic deformation and there are many jumps during the whole process. While at lower temperature (540 °C), mean strain only jumps once at the end of deformation.

Interactions Between Housing Density and Ambient Temperature in the Cage Environment: Effects on Mouse Physiology and Behavior.

PubMed

Toth, Linda A; Trammell, Rita A; Ilsley-Woods, Megan

2015-11-01

To determine how housing density and ambient temperature interact to influence the physiology and behavior of mice, we systematically varied housing density (1 to 5 mice per cage) and ambient temperature (22, 26, or 30 °C) and measured effects on body weight, food intake, diurnal patterns of locomotor activity and core temperature, fecal corticosterone, and serum cytokine and adipokine panels. Temperatures inside cages housing 5 mice were 1 to 2 °C higher than the ambient temperature. As the housing density decreased, in-cage temperatures began to fall at a density of 2 or 3 mice per cage and did not differ from ambient temperature at 1 mouse per cage. Ambient temperature, but not housing density, significantly affected food intake. Although neither ambient temperature nor housing density affected core temperature or activity, hyperthermia and behavioral activation occurred during the 12-h period after cage change. Fecal concentrations of corticosterone metabolites and serum cytokines, chemokines, insulin, and leptin were not influenced by cage density and were only sporadically influenced by ambient temperature. Our data document that the number of mice housed per cage influences the intracage environmental conditions and that ambient temperature influences food intake even when temperatures are within or near recommended or thermoneutral ranges. We conclude that investigators should be cautious when changing the number of mice housed in a cage over the course of a study, because doing so significantly alters the cage environment to which remaining mice are exposed.

Interactions Between Housing Density and Ambient Temperature in the Cage Environment: Effects on Mouse Physiology and Behavior

PubMed Central

Toth, Linda A; Trammell, Rita A; Ilsley-Woods, Megan

2015-01-01

To determine how housing density and ambient temperature interact to influence the physiology and behavior of mice, we systematically varied housing density (1 to 5 mice per cage) and ambient temperature (22, 26, or 30 °C) and measured effects on body weight, food intake, diurnal patterns of locomotor activity and core temperature, fecal corticosterone, and serum cytokine and adipokine panels. Temperatures inside cages housing 5 mice were 1 to 2 °C higher than the ambient temperature. As the housing density decreased, in-cage temperatures began to fall at a density of 2 or 3 mice per cage and did not differ from ambient temperature at 1 mouse per cage. Ambient temperature, but not housing density, significantly affected food intake. Although neither ambient temperature nor housing density affected core temperature or activity, hyperthermia and behavioral activation occurred during the 12-h period after cage change. Fecal concentrations of corticosterone metabolites and serum cytokines, chemokines, insulin, and leptin were not influenced by cage density and were only sporadically influenced by ambient temperature. Our data document that the number of mice housed per cage influences the intracage environmental conditions and that ambient temperature influences food intake even when temperatures are within or near recommended or thermoneutral ranges. We conclude that investigators should be cautious when changing the number of mice housed in a cage over the course of a study, because doing so significantly alters the cage environment to which remaining mice are exposed. PMID:26632780

Stability of mechanical joints in launching vehicles: Local and global stationary values of energy density

NASA Astrophysics Data System (ADS)

Chue, Ching-Hwei

A method was developed for predicting the behavior of mechanical joints in launch vehicles with particular emphasis placed on how the combined effects of loading, geometry, and materials could be optimized in terms of structure instability and/or integrity. What was considered to be essential is the fluctuation of the volume energy density with time in the structure. The peaks and valleys of the volume energy density function will be associated with failure by fracture and/or yielding while the distance between their local and global stationary values govern the structure instability. The Solid Rocket Booster (SRB) of the space shuttle was analyzed under axisymmetric and non-axisymmetric loadings. A semi-analytical finite element program was developed for solving the case of non-axisymmetric loading. Following a dynamic stress analysis, contours of the volume energy density in the structure were obtained as a function of time. The magnitudes and locations of these stationary values were then calculated locally and globally and related to possible failure by fracture. In the case of axisymmetric flight, the local and global instability behavior do not change appreciably. Fluctuations in the energy density and the dynamic stability length parameter become appreciable when the non-axisymmetric loads are considered. The magnitude of the energy in the shell structure is sensitive to alterations in the gas pressure induced by the solid propellant.

Assessment of Possible Cycle Lengths for Fully-Ceramic Micro-Encapsulated Fuel-Based Light Water Reactor Concepts

DOE Office of Scientific and Technical Information (OSTI.GOV)

R. Sonat Sen; Michael A. Pope; Abderrafi M. Ougouag

2012-04-01

The tri-isotropic (TRISO) fuel developed for High Temperature reactors is known for its extraordinary fission product retention capabilities [1]. Recently, the possibility of extending the use of TRISO particle fuel to Light Water Reactor (LWR) technology, and perhaps other reactor concepts, has received significant attention [2]. The Deep Burn project [3] currently focuses on once-through burning of transuranic fissile and fissionable isotopes (TRU) in LWRs. The fuel form for this purpose is called Fully-Ceramic Micro-encapsulated (FCM) fuel, a concept that borrows the TRISO fuel particle design from high temperature reactor technology, but uses SiC as a matrix material rather thanmore » graphite. In addition, FCM fuel may also use a cladding made of a variety of possible material, again including SiC as an admissible choice. The FCM fuel used in the Deep Burn (DB) project showed promising results in terms of fission product retention at high burnup values and during high-temperature transients. In the case of DB applications, the fuel loading within a TRISO particle is constituted entirely of fissile or fissionable isotopes. Consequently, the fuel was shown to be capable of achieving reasonable burnup levels and cycle lengths, especially in the case of mixed cores (with coexisting DB and regular LWR UO2 fuels). In contrast, as shown below, the use of UO2-only FCM fuel in a LWR results in considerably shorter cycle length when compared to current-generation ordinary LWR designs. Indeed, the constraint of limited space availability for heavy metal loading within the TRISO particles of FCM fuel and the constraint of low (i.e., below 20 w/0) 235U enrichment combine to result in shorter cycle lengths compared to ordinary LWRs if typical LWR power densities are also assumed and if typical TRISO particle dimensions and UO2 kernels are specified. The primary focus of this summary is on using TRISO particles with up to 20 w/0 enriched uranium kernels loaded in Pressurized Water Reactor (PWR) assemblies. In addition to consideration of this 'naive' use of TRISO fuel in LWRs, several refined options are briefly examined and others are identified for further consideration including the use of advanced, high density fuel forms and larger kernel diameters and TRISO packing fractions. The combination of 800 {micro}m diameter kernels of 20% enriched UN and 50% TRISO packing fraction yielded reactivity sufficient to achieve comparable burnup to present-day PWR fuel.« less

Mechanical Behavior and Microcrack Development in Nominally Dry Synthetic Salt-rock During Cyclic Loading

NASA Astrophysics Data System (ADS)

Ding, J.; Chester, F. M.; Chester, J. S.; Zhu, C.; Shen, X.; Arson, C. F.

2016-12-01

Synthetic salt-rock is produced through uniaxial consolidation of sieved granular salt (0.3-0.355 mm grain diam.) at 75-107 MPa pressure and 100-200 0 C for 15 min duration, to produce low porosity (3%-6%) aggregates. Based on microstructural observations, consolidation mechanisms are grain rearrangement, intragranular plastic flow, and minor microfracture and recrystallization. Following consolidation, the salt-rock is deformed by cyclic, triaxial loading at room temperature and 4 MPa confining pressure to investigate microfracture development, closure and healing effects on elastic properties and flow strength. Load cycles are performed within the elastic regime, up to yielding, and during steady ductile flow. The mechanical properties are determined using an internal load cell and strain gages bonded to the samples. Elastic properties vary systematically during deformation reflecting cracking and pore and grain shape changes. Between triaxial load cycles, samples are held at isostatic loads for durations up to one day to determine healing rates and strength recovery; a change in mechanical behavior is observed when significant healing is induced. The microstructures of all samples are characterized before and after cyclic loading using optical microscopy. The consolidation and cyclic triaxial tests, and optical microscopy investigations, are conducted in a controlled low-humidity environment to ensure nominally dry conditions. The microstructures of samples from different stages of cyclic triaxial deformation indicate that intracrystalline plasticity, accompanied by minor recovery by recrystallization, is dominant; but, grain-boundary crack opening also becomes significant. Grain-boundary microcracks have preferred orientations that are sub-parallel to the load axis. The stress-strain behavior correlates with microcrack fabrics and densities during cyclic loading. These experiments are used to both inform and test continuum damage mechanics models of salt-rock deformation in the semibrittle domain, as well as to help design and optimize salt-rock storage facilities.

14 CFR 23.341 - Gust loads factors.

Code of Federal Regulations, 2014 CFR

2014-01-01

... loads factors. (a) Each airplane must be designed to withstand loads on each lifting surface resulting...=airplane mass ratio; U de=Derived gust velocities referred to in § 23.333(c) (f.p.s.); ρ=Density of air... C NA per radian if the gust loads are applied to the wings and horizontal tail surfaces...

14 CFR 23.341 - Gust loads factors.

Code of Federal Regulations, 2012 CFR

2012-01-01

... loads factors. (a) Each airplane must be designed to withstand loads on each lifting surface resulting...=airplane mass ratio; U de=Derived gust velocities referred to in § 23.333(c) (f.p.s.); ρ=Density of air... C NA per radian if the gust loads are applied to the wings and horizontal tail surfaces...

14 CFR 23.341 - Gust loads factors.

Code of Federal Regulations, 2013 CFR

2013-01-01

... loads factors. (a) Each airplane must be designed to withstand loads on each lifting surface resulting...=airplane mass ratio; U de=Derived gust velocities referred to in § 23.333(c) (f.p.s.); ρ=Density of air... C NA per radian if the gust loads are applied to the wings and horizontal tail surfaces...

14 CFR 23.341 - Gust loads factors.

Code of Federal Regulations, 2011 CFR

2011-01-01

... loads factors. (a) Each airplane must be designed to withstand loads on each lifting surface resulting...=airplane mass ratio; U de=Derived gust velocities referred to in § 23.333(c) (f.p.s.); ρ=Density of air... C NA per radian if the gust loads are applied to the wings and horizontal tail surfaces...

Effects of low central fuelling on density and ion temperature profiles in reversed shear plasmas on JT-60U

NASA Astrophysics Data System (ADS)

Takenaga, H.; Ide, S.; Sakamoto, Y.; Fujita, T.; JT-60 Team

2008-07-01

Effects of low central fuelling on density and ion temperature profiles have been investigated using negative ion based neutral beam injection and electron cyclotron heating (ECH) in reversed shear plasmas on JT-60U. Strong internal transport barrier (ITB) was maintained in density and ion temperature profiles, when central fuelling was decreased by switching positive ion based neutral beam injection to ECH after the strong ITB formation. Similar density and ion temperature ITBs were formed for the low and high central fuelling cases during the plasma current ramp-up phase. Strong correlation between the density gradient and the ion temperature gradient was observed, indicating that particle transport and ion thermal transport are strongly coupled or the density gradient assists the ion temperature ITB formation through suppression of drift wave instabilities such as ion temperature gradient mode. These results support that the density and ion temperature ITBs can be formed under reactor relevant conditions.

Langmuir Probe Diagnostics of Pulsed Plasma Doping System

NASA Astrophysics Data System (ADS)

Lei, Yu; Overzet, Lawrence J.; Felch, Susan B.; Fang, Ziwei; Koo, Bon-Woong; Goeckner, Matthew J.

2002-10-01

Pulsed plasma doping (P2LAD) is a potential solution to implement ultra-shallow junctions. In this study, Langmuir probe diagnostics techniques were investigated thoroughly for its application to P2LAD system, and the current sensing scheme using batteries and a 'downstairs' load resistor turned out to be the most reliable. Severe limitations of current transformers were found in diagnostics of pulsed plasma. A floating probe was proven to be good at monitoring the disturbances of the Langmuir probe and the cathode voltage. With the above technique, time-resolved Langmuir probe measurements have been carried out in a P2LAD system. The Langmuir probe data in Ar plasma indicate that during a 20 microns long implant pulse the plasma density ranges from 1E9 1E10 cm-3 and the electron temperature ranges from 0.4 to 14 eV. Between the pulses, the density keeps at the high level for 30 ms and then decays exponentially until reaching the range of 3E8 1E9 cm-3, which demonstrates the presence of residual plasma between pulses. A non-zero plasma density during the afterglow is also observed for BF3 plasma. Significant amounts of primary electron and electron beams are present during the ignition and ensuing steady region in both Ar and BF3 plasmas while they are much stronger in BF3 plasma. Plasma density is observed to increase with cathode voltage and pressure while the electron temperature is mainly influenced by the pressure. An overshoot of the cathode voltage during the afterglow region was found, and it significantly influences the plasma potential during the afterglow.

Advances in sublimation studies for particles of explosives

NASA Astrophysics Data System (ADS)

Furstenberg, Robert; Nguyen, Viet; Fischer, Thomas; Abrishami, Tara; Papantonakis, Michael; Kendziora, Chris; Mott, David R.; McGill, R. Andrew

2015-05-01

When handling explosives, or related surfaces, the hands routinely become contaminated with particles of explosives and related materials. Subsequent contact with a solid surface results in particle crushing and deposition. These particles provide an evidentiary trail which is useful for security applications. As such, the opto-physico-chemical characteristics of these particles are critical to trace explosives detection applications in DOD or DHS arenas. As the persistence of these particles is vital to their forensic exploitation, it is important to understand which factors influence their persistence. The longevity or stability of explosives particles on a substrate is a function of several environmental parameters or particle properties including: Vapor pressure, particle geometry, airflow, particle field size, substrate topography, humidity, reactivity, adlayers, admixtures, particle areal density, and temperature. In this work we deposited particles of 2,4-dinitrotoluene on standard microscopy glass slides by particle sieving and studied their sublimation as a function of airflow velocity, areal particle density and particle field size. Analysis of 2D microscopic images was used to compute and track particle size and geometrical characteristics. The humidity, temperature and substrate type were kept constant for each experiment. A custom airflow cell, using standard microscopy glass slide, allowed in-situ photomicroscopy. Areal particle densities and airflow velocities were selected to provide relevant loadings and flow velocities for a range of potential applications. For a chemical of interest, we define the radial sublimation velocity (RSV) for the equivalent sphere of a particle as the parameter to characterize the sublimation rate. The RSV is a useful parameter because it is independent of particle size. The sublimation rate for an ensemble of particles was found to significantly depend on airflow velocity, the areal density of the particles, and the particle field size. To compare sublimation studies these parameters must be known.

The deformation and acoustic emission of aluminum-magnesium alloy under non-isothermal thermo-mechanical loading

DOE Office of Scientific and Technical Information (OSTI.GOV)

Makarov, S. V.; Plotnikov, V. A., E-mail: plotnikov@phys.asu.ru; Lysikov, M. V.

2015-10-27

The following study investigates the deformation behavior and acoustic emission in aluminum-magnesium alloy under conditions of non-isothermal thermo-mechanical loading. The accumulation of deformation in the alloy, in conditions of change from room temperature to 500°C, occurs in two temperature intervals (I, II), characterized by different rates of deformation. The rate of deformation accumulation is correlated with acoustic emission. With load increasing in cycles from 40 to 200 MPa, the value of the boundary temperature (T{sub b}) between intervals I and II changes non-monotonically. In cycles with load up to 90 MPa, the T{sub b} value increases, while an increase up to 200 MPamore » makes T{sub b} shift toward lower temperatures. This suggests that the shift of boundaries in the region of low temperatures and the appearance of high-amplitude pulses of acoustic emission characterize the decrease of the magnitude of thermal fluctuations with increasing mechanical load, leading to the rupture of interatomic bonds in an elementary deformation act.« less

Development and evaluation of garlic incorporated ready-to-eat extruded snacks.

PubMed

Haritha, D; Vijayalakshmi, V; Gulla, S

2014-11-01

The present study was carried out to develop and evaluate ready to eat extruded snacks incorporated with garlic powder at various levels (5 %, 10 %, 15 %, 20 %). The organoleptic evaluation was conducted for the developed products and the well accepted products were selected for further studies like physical properties and shelf life (stored at room temperature for 2 months). The organoleptic evaluation of the developed snacks revealed that 15 % and 20 % garlic incorporated snacks were not acceptable due to strong garlic flavor, therefore T1 (control), T2 (5 % garlic) and T3 ( 10 % garlic) were selected for further studies. The physical properties showed significant changes with incorporation of garlic powder at 0 %-10 % level. There was an increase in mass flow rate, tap density and bulk density but decrease in the water holding capacity, oil absorption capacity and expansion ratio. The water soluble index and moisture retention of the products showed the same values for all the three selected treatments. The products were packed by ordinary, nitrogen and vacuum packing and stored for 2 months. It was found that there was an increase in moisture content and microbial load, however the increase was within limits. The increase in the moisture content was low in nitrogen packed products where as the microbial load decreased with increase in the percentage of garlic incorporation. The nitrogen and vacuum packed products showed less microbial load than the ordinary packed products. Garlic powder can be incorporated at 5 and 10 % levels in ready-to-eat extruded snacks with well acceptability and can be stored for a period of 2 months with nitrogen packing as an effective packaging.

Quantitative Assessment of Temperature Sensitivity of the South Fork Nooksack River under Future Climates using QUAL2Kw

EPA Science Inventory

The Total Maximum Daily Load (TMDL) program, established by the Clean Water Act, is used to establish limits on loading of pollutants from point and nonpoint sources necessary to achieve water quality standards. One important use of a temperature TMDL is to allocate thermal loads...

La and Al co-doped CaMnO 3 perovskite oxides: From interplay of surface properties to anion exchange membrane fuel cell performance

DOE PAGES

Dzara, Michael J.; Christ, Jason M.; Joghee, Prabhuram; ...

2017-09-01

This work reports the first account of perovskite oxide and carbon composite oxygen reduction reaction (ORR) catalysts integrated into anion exchange membrane fuel cells (AEMFCs). Perovskite oxides with a theoretical stoichiometry of Ca 0.9La 0.1Al 0.1Mn 0.9O 3-δ are synthesized by an aerogel method and calcined at various temperatures, resulting in a set of materials with varied surface chemistry and surface area. Material composition is evaluated by X-ray diffraction, energy dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. The perovskite oxide calcined at 800 degrees C shows the importance of balance between surface area, purity of the perovskite phase, and surfacemore » composition, resulting in the highest ORR mass activity when evaluated in rotating disk electrodes. Integration of this catalyst into AEMFCs reveals that the best AEMFC performance is obtained when using composites with 30:70 perovskite oxide:carbon composition. Doubling the loading leads to an increase in the power density from 30 to 76 mW cm -2. The AEMFC prepared with a composite based on perovskite oxide and N-carbon achieves a power density of 44 mW cm -2, demonstrating an ~50% increase when compared to the highest performing composite with undoped carbon at the same loading.« less

La and Al co-doped CaMnO3 perovskite oxides: From interplay of surface properties to anion exchange membrane fuel cell performance

NASA Astrophysics Data System (ADS)

Dzara, Michael J.; Christ, Jason M.; Joghee, Prabhuram; Ngo, Chilan; Cadigan, Christopher A.; Bender, Guido; Richards, Ryan M.; O'Hayre, Ryan; Pylypenko, Svitlana

2018-01-01

This work reports the first account of perovskite oxide and carbon composite oxygen reduction reaction (ORR) catalysts integrated into anion exchange membrane fuel cells (AEMFCs). Perovskite oxides with a theoretical stoichiometry of Ca0.9La0.1Al0.1Mn0.9O3-δ are synthesized by an aerogel method and calcined at various temperatures, resulting in a set of materials with varied surface chemistry and surface area. Material composition is evaluated by X-ray diffraction, energy dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. The perovskite oxide calcined at 800 °C shows the importance of balance between surface area, purity of the perovskite phase, and surface composition, resulting in the highest ORR mass activity when evaluated in rotating disk electrodes. Integration of this catalyst into AEMFCs reveals that the best AEMFC performance is obtained when using composites with 30:70 perovskite oxide:carbon composition. Doubling the loading leads to an increase in the power density from 30 to 76 mW cm-2. The AEMFC prepared with a composite based on perovskite oxide and N-carbon achieves a power density of 44 mW cm-2, demonstrating an ∼50% increase when compared to the highest performing composite with undoped carbon at the same loading.

Theoretical investigations of electrical transport properties in CoSb3 skutterudites under hydrostatic loadings

DOE PAGES

Hu, Chongze; Ni, Peter; Zhan, Li; ...

2018-01-30

We report that CoSb 3-based skutterudites have been a benchmark mid-temperature thermoelectric material under intensive experimental and theoretical studies for decades. Doping and filling, to the first order, alter the crystal lattice constant of CoSb 3 in the context of “chemical pressure.” In this work, we employed ab initio density functional theory in conjunction with semiclassical Boltzmann transport theory to investigate the mechanical properties and especially how hydrostatic loadings, i.e., “physical pressure,” impact the electronic band structure, Seebeck coefficient, and power factor of pristine CoSb 3. It is found that hydrostatic pressure enlarges the band gap, suppresses the density ofmore » states (DOS) near the valence band edge, and fosters the band convergence between the valley bands and the conduction band minimum (CBM). By contrast, hydrostatic tensile reduces the band gap, increases the DOS near the valence band edge, and diminishes the valley bands near the CBM. Therefore, applying hydrostatic pressure provides an alternative avenue for achieving band convergence to improve thermoelectric properties of N-type CoSb 3, which is further supported by our carrier concentration studies. Lastly, these results provide valuable insight into the further improvement of thermoelectric performance of CoSb 3-based skutterudites via a synergy of physical and chemical pressures.« less

Experimental study of thermo-mechanical behavior of a thermosetting shape-memory polymer

NASA Astrophysics Data System (ADS)

Liu, Ruoxuan; Li, Yunxin; Liu, Zishun

2018-01-01

The thermo-mechanical behavior of shape-memory polymers (SMPs) serves for the engineering applications of SMPs. Therefore the understanding of thermo-mechanical behavior of SMPs is of great importance. This paper investigates the influence of loading rate and loading level on the thermo-mechanical behavior of a thermosetting shape-memory polymer through experimental study. A series of cyclic tension tests and shape recovery tests at different loading conditions are performed to study the strain level and strain rate effect. The results of tension tests show that the thermosetting shape-memory polymer will behave as rubber material at temperature lower than the glass transition temperature (Tg) and it can obtain a large shape fix ratio at cyclic loading condition. The shape recovery tests exhibit that loading rate and loading level have little effect on the beginning and ending of shape recovery process of the thermosetting shape-memory polymer. Compared with the material which is deformed at temperature higher than Tg, the material deformed at temperature lower than Tg behaves a bigger recovery speed.

An investigation on dry sliding wear behaviour of AA6061-AlNp composite

NASA Astrophysics Data System (ADS)

Mahesh Naidu, K.; Mohan Reddy, Chandra

2018-03-01

This paper studies the effect of load, sliding distance, reinforcement percentage and temperature on dry sliding wear behaviour of Al-AlNp composites by using pin on disc machine. The wear test was conducted at different loads (1,2,3 & 4 Kg), temperatures (30°C, 100°C, 170°C & 240°C) and sliding distances (500m,1000m,1500m and 2000m). Increase in wear rate has been observed by increasing the load and sliding distance, at the same time it has been decreased by increasing the reinforcement percentage and temperature. At the higher loads, temperatures and sliding distances adhesive wear, abrasive wear and oxidation wear are observed to be dominant modes of wear mechanisms in the composite.

Shock-activated reaction synthesis and high pressure response of titanium-based ternary carbide and nitride ceramics

NASA Astrophysics Data System (ADS)

Jordan, Jennifer Lynn

The objectives of this study were to (a) investigate the effect of shock activation of precursor powders for solid-state reaction synthesis of Ti-based ternary ceramics and (b) to determine the high pressure phase stability and Hugoniot properties of Ti3SiC2. Dynamically densified compacts of Ti, SiC, and graphite precursor powders and Ti and AlN precursor powders were used to study the shock-activated formation of Ti 3SiC2 and Ti2AlN ternary compounds, respectively, which are considered to be novel ceramics having high stiffness but low hardness. Gas gun and explosive loading techniques were used to obtain a range of loading conditions resulting in densification and activation. Measurements of fraction reacted as a function of time and temperature and activation energies obtained from DTA experiments were used to determine the degree of activation caused by shock compression and its subsequent effect on the reaction mechanisms and kinetics. In both systems, shock activation led to an accelerated rate of reaction at temperatures less than 1600°C and, above that temperature, it promoted the formation of almost 100% of the ternary compound. A kinetics-based mathematical model based on mass and thermal transport was developed to predict the effect of shock activation and reaction synthesis conditions that ensure formation of the ternary compounds. Model predictions revealed a transition temperature above which the reaction is taken over by the "run-away" combustion-type mode. The high pressure phase stability of pre-alloyed Ti 3SiC2 compound was investigated by performing Hugoniot shock and particle velocity measurements using the facilities at the National Institute for Materials Science (Tsukuba, Japan). Experiments performed at pressures of 95--120 GPa showed that the compressibility of Ti3SiC 2 at these pressures deviates from the previously reported compressibility of the material under static high pressure loading. The deviation in compressibility behavior is indicative of the transformation of the Ti3 SiC2 ceramic to a high pressure, high density phase.

Thermally determining flow and/or heat load distribution in parallel paths

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chainer, Timothy J.; Iyengar, Madhusudan K.; Parida, Pritish R.

A method including obtaining calibration data for at least one sub-component in a heat transfer assembly, wherein the calibration data comprises at least one indication of coolant flow rate through the sub-component for a given surface temperature delta of the sub-component and a given heat load into said sub-component, determining a measured heat load into the sub-component, determining a measured surface temperature delta of the sub-component, and determining a coolant flow distribution in a first flow path comprising the sub-component from the calibration data according to the measured heat load and the measured surface temperature delta of the sub-component.

Thermally determining flow and/or heat load distribution in parallel paths

DOEpatents

Chainer, Timothy J.; Iyengar, Madhusudan K.; Parida, Pritish R.

2016-12-13

A method including obtaining calibration data for at least one sub-component in a heat transfer assembly, wherein the calibration data comprises at least one indication of coolant flow rate through the sub-component for a given surface temperature delta of the sub-component and a given heat load into said sub-component, determining a measured heat load into the sub-component, determining a measured surface temperature delta of the sub-component, and determining a coolant flow distribution in a first flow path comprising the sub-component from the calibration data according to the measured heat load and the measured surface temperature delta of the sub-component.

Force spectroscopy of quadruple H-bonded dimers by AFM: dynamic bond rupture and molecular time-temperature superposition.

PubMed

Zou, Shan; Schönherr, Holger; Vancso, G Julius

2005-08-17

We report on the application of the time-temperature superposition principle to supramolecular bond-rupture forces on the single-molecule level. The construction of force-loading rate master curves using atomic force microscopy (AFM)-based single-molecule force spectroscopy (SMFS) experiments carried out in situ at different temperatures allows one to extend the limited range of the experimentally accessible loading rates and hence to cross from thermodynamic nonequilibrium to quasi-equilibrium states. The approach is demonstrated for quadruple H-bonded ureido-4[1H]-pyrimidinone (UPy) moieties studied by variable-temperature SMFS in organic media. The unbinding forces of single quadruple H-bonding (UPy)2 complexes, which were identified based on a polymeric spacer strategy, were found to depend on the loading rate in the range of 5 nN/s to 500 nN/s at 301 K in hexadecane. By contrast, these rupture forces were independent of the loading rate from 5 to 200 nN/s at 330 K. These results indicate that the unbinding behavior of individual supramolecular complexes can be directly probed under both thermodynamic nonequilibrium and quasi-equilibrium conditions. On the basis of the time-temperature superposition principle, a master curve was constructed for a reference temperature of 301 K, and the crossover force (from loading-rate independent to -dependent regimes) was determined as approximately 145 pN (at a loading rate of approximately 5.6 nN/s). This approach significantly broadens the accessible loading-rate range and hence provides access to fine details of potential energy landscape of supramolecular complexes based on SMFS experiments.

Static and Dynamic Compaction of CL-20 Powders

NASA Astrophysics Data System (ADS)

Cooper, Marcia; Brundage, Aaron; Dudley, Evan

2009-06-01

Hexanitrohexaazaisowurtzitane (CL-20) powders were compacted under quasi-static and dynamic loading conditions. A uniaxial compression apparatus quasi-statically compressed the powders to 90% theoretical maximum density with applied stresses up to 0.5 GPa. Dynamic compaction measurements using low-density pressings (62-70% theoretical maximum density) were obtained in a single-stage gas gun at impact velocities between 0.17-0.70 km/s. Experiments were conducted in a reverse ballistic arrangement in which the CL-20 ladened projectile impacted a target consisting of an aluminized window. VISAR-measured particle velocities at the explosive-window interface determined the shock Hugoniot states for pressures up to 0.9 GPa. The powder compaction behavior is found to be stiffer under dynamic loading than under quasi-static loading. Additional gas gun tests were conducted in which the low-density CL-20 pressings were confined within a target cup by the aluminized window. This arrangement enabled temporal measurement of the transmitted wave profiles in which elastic wave precursors were observed.

Measurement of heat load density profile on acceleration grid in MeV-class negative ion accelerator.

PubMed

Hiratsuka, Junichi; Hanada, Masaya; Kojima, Atsushi; Umeda, Naotaka; Kashiwagi, Mieko; Miyamoto, Kenji; Yoshida, Masafumi; Nishikiori, Ryo; Ichikawa, Masahiro; Watanabe, Kazuhiro; Tobari, Hiroyuki

2016-02-01

To understand the physics of the negative ion extraction/acceleration, the heat load density profile on the acceleration grid has been firstly measured in the ITER prototype accelerator where the negative ions are accelerated to 1 MeV with five acceleration stages. In order to clarify the profile, the peripheries around the apertures on the acceleration grid were separated into thermally insulated 34 blocks with thermocouples. The spatial resolution is as low as 3 mm and small enough to measure the tail of the beam profile with a beam diameter of ∼16 mm. It was found that there were two peaks of heat load density around the aperture. These two peaks were also clarified to be caused by the intercepted negative ions and secondary electrons from detailed investigation by changing the beam optics and gas density profile. This is the first experimental result, which is useful to understand the trajectories of these particles.

Analysis of Cantilever-Beam Bending Stress Relaxation Properties of Thin Wood Composites

Treesearch

John F. Hunt; Houjiang Zhang; Yan Huang

2015-01-01

An equivalent strain method was used to analyze and determine material relaxation properties for specimens from particleboard, high density fiberboard, and medium density fiberboard. Cantilever beams were clamped and then deflected to 11 m and held for either 2 h or 3 h, while the load to maintain that deflection was measured vs. time. Plots of load relaxation for each...

Study of ND3-enhanced MAR processes in D2-N2 plasmas to induce plasma detachment

NASA Astrophysics Data System (ADS)

Abe, Shota; Chakraborty Thakur, Saikat; Doerner, Russ; Tynan, George

2017-10-01

The Molecular Assisted Recombination (MAR) process is thought to be a main channel of volumetric recombination to induce the plasma detachment operation. Authors have focused on a new plasma recombination process supported by ammonia molecules, which will be formed by impurity seeding of N2 for controlling divertor plasma temperature and heat loads in ITER. This ammonia-enhanced MAR process would occur throughout two steps. In this study, the first step of the new MAR process is investigated in low density plasmas (Ne 1016 m-3, Te 4 eV) fueled by D2 and N2. Ion and neutral densities are measured by a calibrated Electrostatic Quadrupole Plasma (EQP) analyzer, combination of an ion energy analyzer and mass spectrometer. The EQP shows formation of ND3 during discharges. Ion densities calculated by a rate equation model are compared with experimental results. We find that the model can reproduce the observed ion densities in the plasma. The model calculation shows that the dominant neutralization channel of Dx+(x =1-3) ions in the volume is the formation of NDy+(y =3 or 4) throughout charge/D+ exchange reactions with ND3. Furthermore, high density plasmas (Ne 1016 m-3) have been achieved to investigate electron-impact dissociative recombination processes of formed NDy+,which is the second step of this MAR process.

Fatigue crack growth at elevated temperature 316 stainless steel and H-13 steel

NASA Technical Reports Server (NTRS)

Chen, W. C.; Liu, H. W.

1976-01-01

Crack growths were measured at elevated temperatures under four types of loading: pp, pc, cp, and cc. In H-13 steel, all these four types of loading gave nearly the same crack growth rates, and the length of hold time had negligible effects. In AISI 316 stainless steel, the hold time effects on crack growth rate were negligible if the loading was tension-tension type; however, these effects were significant in reversed bending load, and the crack growth rates under these four types of loading varied considerably. Both tensile and compressive hold times caused increased crack growth rate, but the compressive hold period was more deleterious than the tensile one. Metallographic examination showed that all the crack paths under different types of loading were largely transgranular for both CTS tension-tension specimens and SEN reversed cantilever bending specimens. In addition, an electric potential technique was used to monitor crack growth at elevated temperature.

Production of Biodiesel by Esterification of Free Fatty Acid over Solid Catalyst from Biomass Waste

NASA Astrophysics Data System (ADS)

Mukti, N. I. F.; Sutrisno, B.; Hidayat, A.

2018-05-01

Recently, low cost feedstocks have been utilized to replace vegetable oils in order to improve the economic feasibility of biodiesel. The esterification of free fatty acid (FFA) on Palm Fatty Acid Distillate (PFAD) with methanol using solid catalyst generated from bagasse fly ash is a promising method to convert FFA into biodiesel. In this research, the esterification of FFA on PFAD using the sulfonated bagasse fly ash catalyst was studied. The performances of the catalysts were evaluated in terms of the reaction temperatures, the molar ratios of methanol to PFAD, and the catalyst loading. The effects of the mass ratio of catalyst to oil (1-10%), the molar ratio of methanol to oil (6:1-12:1), and the reaction temperature (40-60°C) were studied for the conversion of PFAD to optimize the reaction conditions. The results showed that the optimum conditions were methanol to PFAD molar ratio of 12:1, the amount of catalyst of 10%wt. of PFAD, and reaction temperature of 6°C. The reusability of the solid acid carbon catalysts was also studied in this work. The catalytic activity decreased up to 38% after third cycle. The significant decline in catalyst esterification activity was due to acid site leaching. The physico-characteristics and acid site densities were analyzed by Nitrogen gas adsorption, surface functional groups by Fourier transform infrared spectroscopy (FT-IR), elemental analysis using X-ray fluorescent (XRF), and acid-base back titration methods for determination of acid density.

Thermal loading of natural streams

USGS Publications Warehouse

Jackman, Alan P.; Yotsukura, Nobuhiro

1977-01-01

The impact of thermal loading on the temperature regime of natural streams is investigated by mathematical models, which describe both transport (convection-diffusion) and decay (surface dissipation) of waste heat over 1-hour or shorter time intervals. The models are derived from the principle of conservation of thermal energy for application to one- and two-dimensional spaces. The basic concept in these models is to separate water temperature into two parts, (1) excess temperature due to thermal loading and (2) natural (ambient) temperature. This separation allows excess temperature to be calculated from the models without incoming radiation data. Natural temperature may either be measured in prototypes or calculated from the model. If use is made of the model, however, incoming radiation is required as input data. Comparison of observed and calculated temperatures in seven natural streams shows that the models are capable of predicting transient temperature regimes satisfactorily in most cases. (Woodard-USGS)

A Load-Based Temperature Prediction Model for Anomaly Detection

NASA Astrophysics Data System (ADS)

Sobhani, Masoud

Electric load forecasting, as a basic requirement for the decision-making in power utilities, has been improved in various aspects in the past decades. Many factors may affect the accuracy of the load forecasts, such as data quality, goodness of the underlying model and load composition. Due to the strong correlation between the input variables (e.g., weather and calendar variables) and the load, the quality of input data plays a vital role in forecasting practices. Even if the forecasting model were able to capture most of the salient features of the load, a low quality input data may result in inaccurate forecasts. Most of the data cleansing efforts in the load forecasting literature have been devoted to the load data. Few studies focused on weather data cleansing for load forecasting. This research proposes an anomaly detection method for the temperature data. The method consists of two components: a load-based temperature prediction model and a detection technique. The effectiveness of the proposed method is demonstrated through two case studies: one based on the data from the Global Energy Forecasting Competition 2014, and the other based on the data published by ISO New England. The results show that by removing the detected observations from the original input data, the final load forecast accuracy is enhanced.

Callus remodelling model

NASA Astrophysics Data System (ADS)

Miodowska, Justyna; Bielski, Jan; Kromka-Szydek, Magdalena

2018-01-01

The objective of this paper is to investigate the healing process of the callus using bone remodelling approach. A new mathematical model of bone remodelling is proposed including both underload and overload resorption, as well as equilibrium and bone growth states. The created model is used to predict the stress-stimulated change in the callus density. The permanent and intermittent loading programs are considered. The analyses indicate that obtaining a sufficiently high values of the callus density (and hence the elasticity) modulus is only possible using time-varying load parameters. The model predictions also show that intermittent loading program causes delayed callus healing. Understanding how mechanical conditions influence callus remodelling process may be relevant in the bone fracture treatment and initial bone loading during rehabilitation.

Short Term Load Forecasting with Fuzzy Logic Systems for power system planning and reliability-A Review

NASA Astrophysics Data System (ADS)

Holmukhe, R. M.; Dhumale, Mrs. Sunita; Chaudhari, Mr. P. S.; Kulkarni, Mr. P. P.

2010-10-01

Load forecasting is very essential to the operation of Electricity companies. It enhances the energy efficient and reliable operation of power system. Forecasting of load demand data forms an important component in planning generation schedules in a power system. The purpose of this paper is to identify issues and better method for load foecasting. In this paper we focus on fuzzy logic system based short term load forecasting. It serves as overview of the state of the art in the intelligent techniques employed for load forecasting in power system planning and reliability. Literature review has been conducted and fuzzy logic method has been summarized to highlight advantages and disadvantages of this technique. The proposed technique for implementing fuzzy logic based forecasting is by Identification of the specific day and by using maximum and minimum temperature for that day and finally listing the maximum temperature and peak load for that day. The results show that Load forecasting where there are considerable changes in temperature parameter is better dealt with Fuzzy Logic system method as compared to other short term forecasting techniques.

Alternate Methods in Refining the SLS Nozzle Plug Loads

NASA Technical Reports Server (NTRS)

Burbank, Scott; Allen, Andrew

2013-01-01

Numerical analysis has shown that the SLS nozzle environmental barrier (nozzle plug) design is inadequate for the prelaunch condition, which consists of two dominant loads: 1) the main engines startup pressure and 2) an environmentally induced pressure. Efforts to reduce load conservatisms included a dynamic analysis which showed a 31% higher safety factor compared to the standard static analysis. The environmental load is typically approached with a deterministic method using the worst possible combinations of pressures and temperatures. An alternate probabilistic approach, utilizing the distributions of pressures and temperatures, resulted in a 54% reduction in the environmental pressure load. A Monte Carlo simulation of environmental load that used five years of historical pressure and temperature data supported the results of the probabilistic analysis, indicating the probabilistic load is reflective of a 3-sigma condition (1 in 370 probability). Utilizing the probabilistic load analysis eliminated excessive conservatisms and will prevent a future overdesign of the nozzle plug. Employing a similar probabilistic approach to other design and analysis activities can result in realistic yet adequately conservative solutions.

An Experimental Study of Briquetting Process of Torrefied Rubber Seed Kernel and Palm Oil Shell.

PubMed

Hamid, M Fadzli; Idroas, M Yusof; Ishak, M Zulfikar; Zainal Alauddin, Z Alimuddin; Miskam, M Azman; Abdullah, M Khalil

2016-01-01

Torrefaction process of biomass material is essential in converting them into biofuel with improved calorific value and physical strength. However, the production of torrefied biomass is loose, powdery, and nonuniform. One method of upgrading this material to improve their handling and combustion properties is by densification into briquettes of higher density than the original bulk density of the material. The effects of critical parameters of briquetting process that includes the type of biomass material used for torrefaction and briquetting, densification temperature, and composition of binder for torrefied biomass are studied and characterized. Starch is used as a binder in the study. The results showed that the briquette of torrefied rubber seed kernel (RSK) is better than torrefied palm oil shell (POS) in both calorific value and compressive strength. The best quality of briquettes is yielded from torrefied RSK at the ambient temperature of briquetting process with the composition of 60% water and 5% binder. The maximum compressive load for the briquettes of torrefied RSK is 141 N and the calorific value is 16 MJ/kg. Based on the economic evaluation analysis, the return of investment (ROI) for the mass production of both RSK and POS briquettes is estimated in 2-year period and the annual profit after payback was approximately 107,428.6 USD.

Modeling and experimental performance of an intermediate temperature reversible solid oxide cell for high-efficiency, distributed-scale electrical energy storage

NASA Astrophysics Data System (ADS)

Wendel, Christopher H.; Gao, Zhan; Barnett, Scott A.; Braun, Robert J.

2015-06-01

Electrical energy storage is expected to be a critical component of the future world energy system, performing load-leveling operations to enable increased penetration of renewable and distributed generation. Reversible solid oxide cells, operating sequentially between power-producing fuel cell mode and fuel-producing electrolysis mode, have the capability to provide highly efficient, scalable electricity storage. However, challenges ranging from cell performance and durability to system integration must be addressed before widespread adoption. One central challenge of the system design is establishing effective thermal management in the two distinct operating modes. This work leverages an operating strategy to use carbonaceous reactant species and operate at intermediate stack temperature (650 °C) to promote exothermic fuel-synthesis reactions that thermally self-sustain the electrolysis process. We present performance of a doped lanthanum-gallate (LSGM) electrolyte solid oxide cell that shows high efficiency in both operating modes at 650 °C. A physically based electrochemical model is calibrated to represent the cell performance and used to simulate roundtrip operation for conditions unique to these reversible systems. Design decisions related to system operation are evaluated using the cell model including current density, fuel and oxidant reactant compositions, and flow configuration. The analysis reveals tradeoffs between electrical efficiency, thermal management, energy density, and durability.

Li intercalation in graphite: A van der Waals density-functional study

NASA Astrophysics Data System (ADS)

Hazrati, E.; de Wijs, G. A.; Brocks, G.

2014-10-01

Modeling layered intercalation compounds from first principles poses a problem, as many of their properties are determined by a subtle balance between van der Waals interactions and chemical or Madelung terms, and a good description of van der Waals interactions is often lacking. Using van der Waals density functionals we study the structures, phonons and energetics of the archetype layered intercalation compound Li-graphite. Intercalation of Li in graphite leads to stable systems with calculated intercalation energies of -0.2 to -0.3 eV/Li atom, (referred to bulk graphite and Li metal). The fully loaded stage 1 and stage 2 compounds LiC6 and Li1 /2C6 are stable, corresponding to two-dimensional √{3 }×√{3 } lattices of Li atoms intercalated between two graphene planes. Stage N >2 structures are unstable compared to dilute stage 2 compounds with the same concentration. At elevated temperatures dilute stage 2 compounds easily become disordered, but the structure of Li3 /16C6 is relatively stable, corresponding to a √{7 }×√{7 } in-plane packing of Li atoms. First-principles calculations, along with a Bethe-Peierls model of finite temperature effects, allow for a microscopic description of the observed voltage profiles.

40 CFR 86.1229-85 - Dynamometer load determination and fuel temperature profile.

Code of Federal Regulations, 2012 CFR

2012-07-01

... specified driving schedule. The design of the laboratory facility should include consideration of any parameters that may affect fuel temperatures, such as solar loading, pavement heat, and relative wind... be at least 125 °F throughout the driving period. Pavement temperature shall be measured and recorded...

40 CFR 86.1229-85 - Dynamometer load determination and fuel temperature profile.

Code of Federal Regulations, 2010 CFR

2010-07-01

... specified driving schedule. The design of the laboratory facility should include consideration of any parameters that may affect fuel temperatures, such as solar loading, pavement heat, and relative wind... be at least 125 °F throughout the driving period. Pavement temperature shall be measured and recorded...

40 CFR 86.1229-85 - Dynamometer load determination and fuel temperature profile.

Code of Federal Regulations, 2013 CFR

2013-07-01

... specified driving schedule. The design of the laboratory facility should include consideration of any parameters that may affect fuel temperatures, such as solar loading, pavement heat, and relative wind... be at least 125 °F throughout the driving period. Pavement temperature shall be measured and recorded...

40 CFR 86.1229-85 - Dynamometer load determination and fuel temperature profile.

Code of Federal Regulations, 2011 CFR

2011-07-01

... specified driving schedule. The design of the laboratory facility should include consideration of any parameters that may affect fuel temperatures, such as solar loading, pavement heat, and relative wind... be at least 125 °F throughout the driving period. Pavement temperature shall be measured and recorded...

Effects of volcano profile on dilute pyroclastic density currents: Numerical simulations

NASA Astrophysics Data System (ADS)

Doronzo, D. M.; Valentine, G. A.; Dellino, P.; de Tullio, M. D.

2012-04-01

Explosive activity and lava dome collapse at stratovolcanoes can lead to pyroclastic density currents (PDCs; mixtures of volcanic gas, air, and volcanic particles) that produce complex deposits and pose a hazard to surrounding populations. Two-dimensional numerical simulations of dilute PDCs (characterized by a turbulent suspended load and deposition through a bed load) are carried out with the Euler-Lagrange approach of multiphase physics. The fluid phase is modeled as a dusty gas (1.88 kg/m3 dense), and the solid phase is modeled as discrete particles (1 mm, 5 mm, and 10 mm; 1500 kg/m3 dense and irregularly-shaped), which are two-way coupled to the gas, i.e. they affect the fluid turbulence. The initial PDC, which enters a volcano domain 5 km long and 1.9 km high, has the following characteristics: thickness of 200 m, velocity of 20 m/s, temperature of 573 K, turbulence of 5 %, and sediment concentration of 3 % by volume. The actual physics of flow boundary zone is simulated at the PDC base, by monitoring the sediment flux toward the substrate, which acts through the flow boundary zone, and the grain-size distribution. Also, the PDC velocity and dynamic pressure are calculated. The simulations show that PDC transport, deposition, and hazard potential are sensitive to the shape of the volcano slope (profile) down which they flow. In particular, three generic volcano profiles, straight, concave-upward, and convex-upward are focused on. Dilute PDCs that flow down a constant slope gradually decelerate over the simulated run-out distance (5 km in the horizontal direction) due to a combination of sedimentation, which reduces the density of the PDC, and mixing with the atmosphere. However, dilute PDCs down a concave-upward slope accelerate high on the volcano flanks and have less sedimentation until they begin to decelerate over the shallow lower slopes. A convex-upward slope causes dilute PDCs to lose relatively more of their pyroclast load on the upper slopes of a volcano, and although they accelerate as they reach the lower, steeper slopes, the acceleration is reduced because of the upstream loss of pyroclasts (lower density contrast with the atmosphere). The dynamic pressure, a measure of the damage that can be caused by PDCs, reflects these complex relations. Details are found in Valentine et al. (2011). Reference Valentine G.A., Doronzo D.M., Dellino P., de Tullio M.D. (2011), Effects of volcano profile on dilute pyroclastic density currents: Numerical simulations, Geology, 39, 947-950.

Nutrient loads within the Sava River Catchment and comparison with load relations in the Baltic region

NASA Astrophysics Data System (ADS)

Levi, Lea; Cvetkovic, Vladimir; Destouni, Georgia

2015-04-01

This study compiles estimates of total nitrogen and phosphorus loads in the Sava River Catchment (SRC), investigates the load relations to human drivers of excess nutrient loading, and compares them with corresponding relations implied by data reported for the Baltic region. Nutrient load data, associated average discharge concentrations (ratio of load to water discharge) and their relations to human drivers are investigated across subcatchments of the SRC with different agricultural and population conditions. The Zagreb subcatchment, which has the smallest area but the highest population density and runoff among the investigated SRC subcatchments, exhibits the highest loads of both nitrogen and phosphorus. Overall for the SRC, results show high correlation (R2=0.93-0.95) of nutrient loads with population density and of concentrations with farmland share. A further question investigated here is then to what degree these relations are comparable with such relations found also for the Baltic region. The two regions are otherwise quite different in their climatic, agricultural and wastewater treatment conditions, so relation consistency, even if surprising, would be important in indicating some degree of relation transferability worthy of further investigation also in other regions. For the Baltic region corresponding correlations to those found in the SRC are in the range R2=0.79-0.88. In particular nitrogen and phosphorus concentration correlations with farmland share are qualitatively consistent between the regions. At the same time, phosphorus concentration correlation with population density shows quite different results between regions. Obtained results indicate a certain level of transferability of dependencies between the two regions and call for further detailed investigations on finer spatial-temporal scales.

Development of high-temperature Kolsky compression bar techniques for recrystallization investigation

NASA Astrophysics Data System (ADS)

Song, B.; Antoun, B. R.; Boston, M.

2012-05-01

We modified the design originally developed by Kuokkala's group to develop an automated high-temperature Kolsky compression bar for characterizing high-rate properties of 304L stainless steel at elevated temperatures. Additional features have been implemented to this high-temperature Kolsky compression bar for recrystallization investigation. The new features ensure a single loading on the specimen and precise time and temperature control for quenching to the specimen after dynamic loading. Dynamic compressive stress-strain curves of 304L stainless steel were obtained at 21, 204, 427, 649, and 871 °C (or 70, 400, 800, 1200, and 1600 °F) at the same constant strain rate of 332 s-1. The specimen subjected to specific time and temperature control for quenching after a single dynamic loading was preserved for investigating microstructure recrystallization.

A low thermal impact annealing process for SiO2-embedded Si nanocrystals with optimized interface quality

NASA Astrophysics Data System (ADS)

Hiller, Daniel; Gutsch, Sebastian; Hartel, Andreas M.; Löper, Philipp; Gebel, Thoralf; Zacharias, Margit

2014-04-01

Silicon nanocrystals (Si NCs) for 3rd generation photovoltaics or optoelectronic applications can be produced by several industrially compatible physical or chemical vapor deposition technologies. A major obstacle for the integration into a fabrication process is the typical annealing to form and crystallize these Si quantum dots (QDs) which involves temperatures ≥1100 °C for 1 h. This standard annealing procedure allows for interface qualities that correspond to more than 95% dangling bond defect free Si NCs. We study the possibilities to use rapid thermal annealing (RTA) and flash lamp annealing to crystallize the Si QDs within seconds or milliseconds at high temperatures. The Si NC interface of such samples exhibits huge dangling bond defect densities which makes them inapplicable for photovoltaics or optoelectronics. However, if the RTA high temperature annealing is combined with a medium temperature inert gas post-annealing and a H2 passivation, luminescent Si NC fractions of up to 90% can be achieved with a significantly reduced thermal load. A new figure or merit, the relative dopant diffusion length, is introduced as a measure for the impact of a Si NC annealing procedure on doping profiles of device structures.

Charles River Crossing

DTIC Science & Technology

2012-04-06

48 MODAL ANALYSIS...2. Lateral Loads 3. Non-uniform Loads 4. Modal Analysis 5. Seismic Analysis 6. Moving Load Analysis All of these analyses were conducted with...Tandem c onsisting of a t wo a xle ve hicle with 25 kips on each axle spaced by 4 ft Self-Weight Dead Load: Steel density of 0.49 kips per cubic foot

Characterization of deformation mechanisms in zirconium alloys: effect of temperature and irradiation

NASA Astrophysics Data System (ADS)

Long, Fei

Zirconium alloys have been widely used in the CANDU (CANada Deuterium Uranium) reactor as core structural materials. Alloy such as Zircaloy-2 has been used for calandria tubes; fuel cladding; the pressure tube is manufactured from alloy Zr-2.5Nb. During in-reactor service, these alloys are exposed to a high flux of fast neutron at elevated temperatures. It is important to understand the effect of temperature and irradiation on the deformation mechanism of zirconium alloys. Aiming to provide experimental guidance for future modeling predictions on the properties of zirconium alloys this thesis describes the result of an investigation of the change of slip and twinning modes in Zircaloy-2 and Zr-2.5Nb as a function of temperature and irradiation. The aim is to provide scientific fundamentals and experimental evidences for future industry modeling in processing technique design, and in-reactor property change prediction of zirconium components. In situ neutron diffraction mechanical tests carried out on alloy Zircaloy-2 at three temperatures: 100¢ªC, 300¢ªC, and 500¢ªC, and described in Chapter 3. The evolution of the lattice strain of individual grain families in the loading and Poisson's directions during deformation, which probes the operation of slip and twinning modes at different stress levels, are described. By using the same type of in situ neutron diffraction technique, tests on Zr-2.5Nb pressure tube material samples, in either the fast-neutron irradiated or un-irradiated condition, are reported in Chapter 4. In Chapter 5, the measurement of dislocation density by means of line profile analysis of neutron diffraction patterns, as well as TEM observations of the dislocation microstructural evolution, is described. In Chapter 6 a hot-rolled Zr-2.5Nb with a larger grain size compared with the pressure tubing was used to study the development of dislocation microstructures with increasing plastic strain. In Chapter 7, in situ loading of heavy ion irradiated hot-rolled Zr-2.5Nb alloy is described, providing evidence for the interaction between moving dislocations and irradiation induced loops. Chapter 8 gives the effect on the dislocation structure of different levels of compressive strains along two directions in the hot-rolled Zr-2.5Nb alloy. By using high resolution neutron diffraction and TEM observations, the evolution of type and dislocation densities, as well as changes of dislocation microstructure with plastic strain were characterized.

Verification of the Multi-Axial, Temperature and Time Dependent (MATT) Failure Criterion

NASA Technical Reports Server (NTRS)

Richardson, David E.; Macon, David J.

2005-01-01

An extensive test and analytical effort has been completed by the Space Shuttle's Reusable Solid Rocket Motor (KSKM) nozzle program to characterize the failure behavior of two epoxy adhesives (TIGA 321 and EA946). As part of this effort, a general failure model, the "Multi-Axial, Temperature, and Time Dependent" or MATT failure criterion was developed. In the initial development of this failure criterion, tests were conducted to provide validation of the theory under a wide range of test conditions. The purpose of this paper is to present additional verification of the MATT failure criterion, under new loading conditions for the adhesives TIGA 321 and EA946. In many cases, the loading conditions involve an extrapolation from the conditions under which the material models were originally developed. Testing was conducted using three loading conditions: multi-axial tension, torsional shear, and non-uniform tension in a bondline condition. Tests were conducted at constant and cyclic loading rates ranging over four orders of magnitude. Tests were conducted under environmental conditions of primary interest to the RSRM program. The temperature range was not extreme, but the loading ranges were extreme (varying by four orders of magnitude). It should be noted that the testing was conducted at temperatures below the glass transition temperature of the TIGA 321 adhesive. However for the EA946, the testing was conducted at temperatures that bracketed the glass transition temperature.

Optimally oriented grooves on dental implants improve bone quality around implants under repetitive mechanical loading.

PubMed

Kuroshima, Shinichiro; Nakano, Takayoshi; Ishimoto, Takuya; Sasaki, Muneteru; Inoue, Maaya; Yasutake, Munenori; Sawase, Takashi

2017-01-15

The aim was to investigate the effect of groove designs on bone quality under controlled-repetitive load conditions for optimizing dental implant design. Anodized Ti-6Al-4V alloy implants with -60° and +60° grooves around the neck were placed in the proximal tibial metaphysis of rabbits. The application of a repetitive mechanical load was initiated via the implants (50N, 3Hz, 1800 cycles, 2days/week) at 12weeks after surgery for 8weeks. Bone quality, defined as osteocyte density and degree of biological apatite (BAp) c-axis/collagen fibers, was then evaluated. Groove designs did not affect bone quality without mechanical loading; however, repetitive mechanical loading significantly increased bone-to-implant contact, bone mass, and bone mineral density (BMD). In +60° grooves, the BAp c-axis/collagen fibers preferentially aligned along the groove direction with mechanical loading. Moreover, osteocyte density was significantly higher both inside and in the adjacent region of the +60° grooves, but not -60° grooves. These results suggest that the +60° grooves successfully transmitted the load to the bone tissues surrounding implants through the grooves. An optimally oriented groove structure on the implant surface was shown to be a promising way for achieving bone tissue with appropriate bone quality. This is the first report to propose the optimal design of grooves on the necks of dental implants for improving bone quality parameters as well as BMD. The findings suggest that not only BMD, but also bone quality, could be a useful clinical parameter in implant dentistry. Although the paradigm of bone quality has shifted from density-based assessments to structural evaluations of bone, clarifying bone quality based on structural bone evaluations remains challenging in implant dentistry. In this study, we firstly demonstrated that the optimal design of dental implant necks improved bone quality defined as osteocytes and the preferential alignment degree of biological apatite c-axis/collagen fibers using light microscopy, polarized light microscopy, and a microbeam X-ray diffractometer system, after application of controlled mechanical load. Our new findings suggest that bone quality around dental implants could become a new clinical parameter as well as bone mineral density in order to completely account for bone strength in implant dentistry. Copyright © 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Superior performance asymmetric supercapacitors based on a directly grown commercial mass 3D Co3O4@Ni(OH)2 core-shell electrode.

PubMed

Tang, Chun-hua; Yin, Xuesong; Gong, Hao

2013-11-13

Pseudocapacitors based on fast surface Faradaic reactions can achieve high energy densities together with high power densities. Usually, researchers develop a thin layer of active materials to increase the energy density by enhancing the surface area; meanwhile, this sacrifices the mass loading. In this work, we developed a novel 3D core-shell Co3O4@Ni(OH)2 electrode that can provide high energy density with very high mass loading. Core-shell porous nanowires (Co3O4@Ni(OH)2) were directly grown on a Ni current collector as an integrated electrode/collector for the supercapacitor anode. This Co3O4@Ni(OH)2 core-shell nanoarchitectured electrode exhibits an ultrahigh areal capacitance of 15.83 F cm(-2). The asymmetric supercapacitor prototypes, assembled using Co3O4@Ni(OH)2 as the anode, reduced graphene oxide (RGO) or active carbon (AC) as the cathode, and 6 M aqueous KOH as the electrolyte, exhibit very high energy densities falling into the energy-density range of Li-ion batteries. Because of the large mass loading and high energy density, the prototypes can drive a minifan or light a bulb even though the size is very small. These results indicate that our asymmetric supercapacitors have outstanding potential in commercial applications. Systematic study and scientific understanding were carried out.

Analytical Prediction of Motor Component Vibrations Driven by Acoustic Combustion Instability

DTIC Science & Technology

1976-02-01

27"V 1Sy 1 2 oiihedr41 Symmetry .. .. . ., . . C-28 3 SPCD Bulk Data Card Format ......... . . .. .- 29 4 CYJOIN Bulk Data Card Format...analysis, the loads, the values of enforced displacements, and the temperatures may vary from element to element. The SPCD bulk data card (Figure 3) is...Static loads for vech suhc’: -e are spcified with LOAD, ’TEMPERATURE (LOAD), or DE .-I, oiectic.-,!•. Enforced deformations may be specified on SPCD

Microfracture and changes in energy absorption to fracture of young vertebral cancellous bone following physiological fatigue loading.

PubMed

Lu, W W; Luk, K D K; Cheung, K C M; Gui-Xing, Qiu; Shen, J X; Yuen, L; Ouyang, J; Leong, J C Y

2004-06-01

Fifty-five human thoracolumbar vertebrae were randomly fatigue loaded and analyzed. The purpose of this study was to explore the relationship between fatigue loading, trabecular microfracture, and energy absorption to fracture in human cadaveric thoracolumbar vertebrae. Although trabecular microfractures are found in vivo and have been produced by fatigue loading in vitro, the effect of the level of physiologic fatigue loading on microfracture and energy absorption has not been investigated. Fifty-five human thoracolumbar vertebrae (T11-L4) were randomly divided into 5 groups: 1) control (no loading, n = 6); 2) axial compression to yield (n = 7); and 3-5) 20,000 cycles of fatigue loading at 2 Hz (each n = 14). The level of fatigue loading was determined as a proportion of the yield load of Group 2 as follows: 10% (Group 3), 20% (Group 4), and 30% (Group 5). Half of the specimens in groups 3 to 5 were used for radiographic and histomorphometric analysis to determine microfracture density and distribution, whereas the other half were tested to determine the energy absorption to yield failure. No radiographic evidence of gross fracture was found in any of the groups following fatigue loading. A mean 7.5% increase in stiffness was found in specimens subject to cyclic loading at 10% of yield stress (Group 3). Fatigue at 20% (Group 4) and 30% of yield stress (Group 5) caused significantly higher (P < 0.05) increases in mean stiffness of 23.6% and 24.2%, respectively. Microfracture density increased from 0.46/mm in Group 3 to 0.66/mm in Group 4 and 0.94/mm in Group 5 (P < 0.05). The energy absorbed to failure decreased from 21.9 J in Group 3 to 18.1 J and 19.6 J in Groups 4 and 5, respectively (P < 0.05). Fatigue loading at physiologic levels produced microfractures that are not detectable by radiography. Increased fatigue load results in an increase in microfracture density and decrease energy absorbed to fracture, indicating a reduced resistance to further fatigue loading.

Method of forming metallic coatings on polymeric substrates

DOEpatents

Liepins, Raimond

1984-01-01

Very smooth polymeric coatings or films graded in atomic number and density an readily be formed by first preparing the coating or film from the desired monomeric material and then contacting it with a fluid containing a metal or a mixture of metals for a time sufficient for such metal or metals to sorb and diffuse into the coating or film. Metal resinate solutions are particularly advantageous for this purpose. A metallic coating can in turn be produced on the metal-loaded film or coating by exposing it to a low pressure plasma of air, oxygen, or nitrous oxide. The process permits a metallic coating to be formed on a heat sensitive substrate without the use of elevated temperatures.

Method of forming graded polymeric coatings or films

DOEpatents

Liepins, Raimond

1983-01-01

Very smooth polymeric coatings or films graded in atomic number and density can readily be formed by first preparing the coating or film from the desired monomeric material and then contacting it with a fluid containing a metal or a mixture of metals for a time sufficient for such metal or metals to sorb and diffuse into the coating or film. Metal resinate solutions are particularly advantageous for this purpose. A metallic coating can in turn be produced on the metal-loaded film or coating by exposing it to a low pressure plasma of air, oxygen, or nitrous oxide. The process permits a metallic coating to be formed on a heat sensitive substrate without the use of elevated temperatures.

20 kHz, 25 kVA node power transformer

NASA Technical Reports Server (NTRS)

Hussey, S.

1989-01-01

The electrical and mechanical design information and the electrical and thermal testing performed on the 440-208-V rms, 20-kHz, 25-kVa prototype node transformer are summarized. The calculated efficiency of the node transformer is 99.3 percent based on core loss and copper loss test data, and its maximum calculated load regulation is 0.7 percent. The node transformer has a weight of 19.7 lb and has a power density of 0.8 lb/kW. The hot-spot temperature rise is estimated to be 33 C above the cold plate mounting base. This proof-of-concept transformer design is a viable candidate for the space station Freedom application.

Creep Behavior of High-Strength Concrete Subjected to Elevated Temperatures.

PubMed

Yoon, Minho; Kim, Gyuyong; Kim, Youngsun; Lee, Taegyu; Choe, Gyeongcheol; Hwang, Euichul; Nam, Jeongsoo

2017-07-11

Strain is generated in concrete subjected to elevated temperatures owing to the influence of factors such as thermal expansion and design load. Such strains resulting from elevated temperatures and load can significantly influence the stability of a structure during and after a fire. In addition, the lower the water-to-binder (W-B) ratio and the smaller the quantity of aggregates in high-strength concrete, the more likely it is for unstable strain to occur. Hence, in this study, the compressive strength, elastic modulus, and creep behavior were evaluated at target temperatures of 100, 200, 300, 500, and 800 °C for high-strength concretes with W-B ratios of 30%, 26%, and 23%. The loading conditions were set as non-loading and 0.33f cu . It was found that as the compressive strength of the concrete increased, the mechanical characteristics deteriorated and transient creep increased. Furthermore, when the point at which creep strain occurred at elevated temperatures after the occurrence of transient creep was considered, greater shrinkage strain occurred as the compressive strength of the concrete increased. At a heating temperature of 800 °C, the 80 and 100 MPa test specimens showed creep failure within a shrinkage strain range similar to the strain at the maximum load.

A numerical and experimental study of temperature effects on deformation behavior of carbon steels at high strain rates

NASA Astrophysics Data System (ADS)

Pouya, M.; Winter, S.; Fritsch, S.; F-X Wagner, M.

2017-03-01

Both in research and in the light of industrial applications, there is a growing interest in methods to characterize the mechanical behavior of materials at high strain rates. This is particularly true for steels (the most important structural materials), where often the strain rate-dependent material behavior also needs to be characterized in a wide temperature range. In this study, we use the Finite Element Method (FEM), first, to model the compressive deformation behavior of carbon steels under quasi-static loading conditions. The results are then compared to experimental data (for a simple C75 steel) at room temperature, and up to testing temperatures of 1000 °C. Second, an explicit FEM model that captures wave propagation phenomena during dynamic loading is developed to closely reflect the complex loading conditions in a Split-Hopkinson Pressure Bar (SHPB) - an experimental setup that allows loading of compression samples with strain rates up to 104 s-1 The dynamic simulations provide a useful basis for an accurate analysis of dynamically measured experimental data, which considers reflected elastic waves. By combining numerical and experimental investigations, we derive material parameters that capture the strain rate- and temperature-dependent behavior of the C75 steel from room temperature to 1000 °C, and from quasi-static to dynamic loading.

Creep Behavior of High-Strength Concrete Subjected to Elevated Temperatures

PubMed Central

Yoon, Minho; Kim, Gyuyong; Kim, Youngsun; Lee, Taegyu; Choe, Gyeongcheol; Hwang, Euichul; Nam, Jeongsoo

2017-01-01

Strain is generated in concrete subjected to elevated temperatures owing to the influence of factors such as thermal expansion and design load. Such strains resulting from elevated temperatures and load can significantly influence the stability of a structure during and after a fire. In addition, the lower the water-to-binder (W–B) ratio and the smaller the quantity of aggregates in high-strength concrete, the more likely it is for unstable strain to occur. Hence, in this study, the compressive strength, elastic modulus, and creep behavior were evaluated at target temperatures of 100, 200, 300, 500, and 800 °C for high-strength concretes with W–B ratios of 30%, 26%, and 23%. The loading conditions were set as non-loading and 0.33fcu. It was found that as the compressive strength of the concrete increased, the mechanical characteristics deteriorated and transient creep increased. Furthermore, when the point at which creep strain occurred at elevated temperatures after the occurrence of transient creep was considered, greater shrinkage strain occurred as the compressive strength of the concrete increased. At a heating temperature of 800 °C, the 80 and 100 MPa test specimens showed creep failure within a shrinkage strain range similar to the strain at the maximum load. PMID:28773144

An Imposed Dynamo Current Drive Experiment: Demonstration of Confinement

NASA Astrophysics Data System (ADS)

Jarboe, Thomas; Hansen, Chris; Hossack, Aaron; Marklin, George; Morgan, Kyle; Nelson, Brian; Sutherland, Derek; Victor, Brian

2014-10-01

An experiment for studying and developing the efficient sustainment of a spheromak with sufficient confinement (current-drive power heats the plasma to its stability β-limit) and in the keV temperature range is discussed. A high- β spheromak sustained by imposed dynamo current drive (IDCD) is justified because: previous transient experiments showed sufficient confinement in the keV range with no external toroidal field coil; recent results on HIT-SI show sustainment with sufficient confinement at low temperature; the potential of IDCD of solving other fusion issues; a very attractive reactor concept; and the general need for efficient current drive in magnetic fusion. The design of a 0.55 m minor radius machine with the required density control, wall loading, and neutral shielding for a 2 s pulse is presented. Peak temperatures of 1 keV and toroidal currents of 1.35 MA and 16% wall-normalized plasma beta are envisioned. The experiment is large enough to address the key issues yet small enough for rapid modification and for extended MHD modeling of startup and code validation.

Analysis of Percent On-Cell Reformation of Methane in SOFC Stacks: Thermal, Electrical and Stress Analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Recknagle, Kurtis P.; Yokuda, Satoru T.; Jarboe, Daniel T.

2006-04-07

This report summarizes a parametric analysis performed to determine the effect of varying the percent on-cell reformation (OCR) of methane on the thermal and electrical performance for a generic, planar solid oxide fuel cell (SOFC) stack design. OCR of methane can be beneficial to an SOFC stack because the reaction (steam-methane reformation) is endothermic and can remove excess heat generated by the electrochemical reactions directly from the cell. The heat removed is proportional to the amount of methane reformed on the cell. Methane can be partially pre-reformed externally, then supplied to the stack, where rapid reaction kinetics on the anodemore » ensures complete conversion. Thus, the thermal load varies with methane concentration entering the stack, as does the coupled scalar distributions, including the temperature and electrical current density. The endotherm due to the reformation reaction can cause a temperature depression on the anode near the fuel inlet, resulting in large thermal gradients. This effect depends on factors that include methane concentration, local temperature, and stack geometry.« less

A user-friendly one-dimensional model for wet volcanic plumes

USGS Publications Warehouse

Mastin, Larry G.

2007-01-01

This paper presents a user-friendly graphically based numerical model of one-dimensional steady state homogeneous volcanic plumes that calculates and plots profiles of upward velocity, plume density, radius, temperature, and other parameters as a function of height. The model considers effects of water condensation and ice formation on plume dynamics as well as the effect of water added to the plume at the vent. Atmospheric conditions may be specified through input parameters of constant lapse rates and relative humidity, or by loading profiles of actual atmospheric soundings. To illustrate the utility of the model, we compare calculations with field-based estimates of plume height (∼9 km) and eruption rate (>∼4 × 105 kg/s) during a brief tephra eruption at Mount St. Helens on 8 March 2005. Results show that the atmospheric conditions on that day boosted plume height by 1–3 km over that in a standard dry atmosphere. Although the eruption temperature was unknown, model calculations most closely match the observations for a temperature that is below magmatic but above 100°C.

Growth characteristics of a plane crack subjected to three-dimensional loading. [based on stress intensity factors

NASA Technical Reports Server (NTRS)

Hartranft, R. J.; Sih, G. C.

1973-01-01

The closed form expressions for the stress intensity factors due to concentrated forces applied to the surfaces of a half plane crack in an infinite body are used to generate solutions for distributed loads in this geometry. The stress intensity factors for uniformly distributed loads applied over a rectangular portion of the crack surface are given in closed form. An example of non-uniformly distributed loads which can be treated numerically is also included. In particular, combinations of normal and shear stresses on the crack which simulate the case of loading at an angle to the crack front are considered. The resulting stress intensity factors are combined with the strain energy density fracture criterion for the purpose of predicting the most likely direction of crack propagation. The critical value of the energy density factor can then be used for determining the allowable load on a specimen with a crack front not perpendicular to the tensile axis.

A Programmable Optical Stimulator for the Drosophila Eye.

PubMed

Chen, Xinping; Leon-Salas, Walter D; Zigon, Taylor; Ready, Donald F; Weake, Vikki M

2017-10-01

A programmable optical stimulator for Drosophila eyes is presented. The target application of the stimulator is to induce retinal degeneration in fly photoreceptor cells by exposing them to light in a controlled manner. The goal of this work is to obtain a reproducible system for studying age-related changes in susceptibility to environmental ocular stress. The stimulator uses light emitting diodes and an embedded computer to control illuminance, color (blue or red) and duration in two independent chambers. Further, the stimulator is equipped with per-chamber light and temperature sensors and a fan to monitor light intensity and to control temperature. An ON/OFF temperature control implemented on the embedded computer keeps the temperature from reaching levels that will induce the heat shock stress response in the flies. A custom enclosure was fabricated to house the electronic components of the stimulator. The enclosure provides a light-impermeable environment that allows air flow and lets users easily load and unload fly vials. Characterization results show that the fabricated stimulator can produce light at illuminances ranging from 0 to 16000 lux and power density levels from 0 to 7.2 mW/cm 2 for blue light. For red light the maximum illuminance is 8000 lux which corresponds to a power density of 3.54 mW/cm 2 . The fans and the ON/OFF temperature control are able to keep the temperature inside the chambers below 28.17°C. Experiments with white-eye male flies were performed to assess the ability of the fabricated simulator to induce blue light-dependent retinal degeneration. Retinal degeneration is observed in flies exposed to 8 hours of blue light at 7949 lux. Flies in a control experiment with no light exposure show no retinal degeneration. Flies exposed to red light for the similar duration and light intensity (8 hours and 7994 lux) do not show retinal degeneration either. Hence, the fabricated stimulator can be used to create environmental ocular stress using blue light.

Fatigue crack propagation in additively manufactured porous biomaterials.

PubMed

Hedayati, R; Amin Yavari, S; Zadpoor, A A

2017-07-01

Additively manufactured porous titanium implants, in addition to preserving the excellent biocompatible properties of titanium, have very small stiffness values comparable to those of natural bones. Although usually loaded in compression, biomedical implants can also be under tensional, shear, and bending loads which leads to crack initiation and propagation in their critical points. In this study, the static and fatigue crack propagation in additively manufactured porous biomaterials with porosities between 66% and 84% is investigated using compact-tension (CT) samples. The samples were made using selective laser melting from Ti-6Al-4V and were loaded in tension (in static study) and tension-tension (in fatigue study) loadings. The results showed that displacement accumulation diagram obtained for different CT samples under cyclic loading had several similarities with the corresponding diagrams obtained for cylindrical samples under compression-compression cyclic loadings (in particular, it showed a two-stage behavior). For a load level equaling 50% of the yield load, both the CT specimens studied here and the cylindrical samples we had tested under compression-compression cyclic loading elsewhere exhibited similar fatigue lives of around 10 4 cycles. The test results also showed that for the same load level of 0.5F y , the lower density porous structures demonstrate relatively longer lives than the higher-density ones. This is because the high bending stresses in high-density porous structures gives rise to local Mode-I crack opening in the rough external surface of the struts which leads to quicker formation and propagation of the cracks. Under both the static and cyclic loading, all the samples showed crack pathways which were not parallel to but made 45 ° angles with respect to the notch direction. This is due to the fact that in the rhombic dodecahedron unit cell, the weakest struts are located in 45 ° direction with respect to the notch direction. Copyright © 2017 Elsevier B.V. All rights reserved.

Effect of grid transparency and finite collector size on determining ion temperature and density by the retarding potential analyzer

NASA Technical Reports Server (NTRS)

Troy, B. E., Jr.; Maier, E. J.

1975-01-01

The effects of the grid transparency and finite collector size on the values of thermal ion density and temperature determined by the standard RPA (retarding potential analyzer) analysis method are investigated. The current-voltage curves calculated for varying RPA parameters and a given ion mass, temperature, and density are analyzed by the standard RPA method. It is found that only small errors in temperature and density are introduced for an RPA with typical dimensions, and that even when the density error is substantial for nontypical dimensions, the temperature error remains minimum.

An Asymmetric Supercapacitor with Both Ultra-High Gravimetric and Volumetric Energy Density Based on 3D Ni(OH)2/MnO2@Carbon Nanotube and Activated Polyaniline-Derived Carbon.

PubMed

Shen, Juanjuan; Li, Xiaocheng; Wan, Liu; Liang, Kun; Tay, Beng Kang; Kong, Lingbin; Yan, Xingbin

2017-01-11

Development of a supercapacitor device with both high gravimetric and volumetric energy density is one of the most important requirements for their practical application in energy storage/conversion systems. Currently, improvement of the gravimetric/volumetric energy density of a supercapacitor is restricted by the insufficient utilization of positive materials at high loading density and the inferior capacitive behavior of negative electrodes. To solve these problems, we elaborately designed and prepared a 3D core-shell structured Ni(OH) 2 /MnO 2 @carbon nanotube (CNT) composite via a facile solvothermal process by using the thermal chemical vapor deposition grown-CNTs as support. Owing to the superiorities of core-shell architecture in improving the service efficiency of pseudocapacitive materials at high loading density, the prepared Ni(OH) 2 /MnO 2 @CNT electrode demonstrated a high capacitance value of 2648 F g -1 (1 A g -1 ) at a high loading density of 6.52 mg cm -2 . Coupled with high-performance activated polyaniline-derived carbon (APDC, 400 F g -1 at 1 A g -1 ), the assembled Ni(OH) 2 /MnO 2 @CNT//APDC asymmetric device delivered both high gravimetric and volumetric energy density (126.4 Wh kg -1 and 10.9 mWh cm -3 , respectively), together with superb rate performance and cycling lifetime. Moreover, we demonstrate an effective approach for building a high-performance supercapacitor with high gravimetric/volumetric energy density.

Response of shallow geothermal energy pile from laboratory model tests

NASA Astrophysics Data System (ADS)

Marto, A.; Amaludin, A.

2015-09-01

In shallow geothermal energy pile systems, the thermal loads from the pile, transferred and stored in the soil will cause thermally induced settlement. This factor must be considered in the geotechnical design process to avoid unexpected hazards. Series of laboratory model tests were carried out to study the behaviour of energy piles installed in kaolin soil, subjected to thermal loads and a combination of axial and thermal loads (henceforth known as thermo-axial loads). Six tests which included two thermal load tests (35°C and 40°C) and four thermo-axial load tests (100 N and 200 N, combined with 35°C and 40°C thermal loads) were conducted. To simulate the behaviour of geothermal energy piles during its operation, the thermo-axial tests were carried out by applying an axial load to the model pile head, and a subsequent application of thermal load. The model soil was compacted at 90% maximum dry density and had an undrained shear strength of 37 kPa, thus classified as having a firm soil consistency. The behaviour of model pile, having the ultimate load capacity of 460 N, was monitored using a linear variable displacement transducer, load cell and wire thermocouple, to measure the pile head settlement, applied axial load and model pile temperature. The acquired data from this study was used to define the thermo-axial response characteristics of the energy pile model. In this study, the limiting settlement was defined as 10% of the model pile diameter. For thermal load tests, higher thermal loads induced higher values of thermal settlement. At 40°C thermal load an irreversible settlement was observed after the heating and cooling cycle was applied to the model pile. Meanwhile, the pile response to thermo-axial loads were attributed to soil consistency and the magnitude of both the axial and thermal loads applied to the pile. The higher the thermoaxial loads, the higher the settlements occurred. A slight hazard on the model pile was detected, since the settlement occurred was greater than the limiting value when the pile was loaded with thermo-axial loads of 40°C and 200 N. It is therefore recommended that the global factor of safety to be applied for energy pile installed in firm soil should be more than 2.3 to prevent any hazard to occur in the future, should the pile also be subjected to thermal load of 40°C or greater.