Sample records for long-term calibration stability

  1. Evaluation of the Long-Term Stability and Temperature Coefficient of Dew-Point Hygrometers

    NASA Astrophysics Data System (ADS)

    Benyon, R.; Vicente, T.; Hernández, P.; De Rivas, L.; Conde, F.

    2012-09-01

    The continuous quest for improved specifications of optical dew-point hygrometers has raised customer expectations on the performance of these devices. In the absence of a long calibration history, users with a limited prior experience in the measurement of humidity, place reliance on manufacturer specifications to estimate long-term stability. While this might be reasonable in the case of measurement of electrical quantities, in humidity it can lead to optimistic estimations of uncertainty. This article reports a study of the long-term stability of some hygrometers and the analysis of their performance as monitored through regular calibration. The results of the investigations provide some typical, realistic uncertainties associated with the long-term stability of instruments used in calibration and testing laboratories. Together, these uncertainties can help in establishing initial contributions in uncertainty budgets, as well as in setting the minimum calibration requirements, based on the evaluation of dominant influence quantities.

  2. On the long-term stability of calibration standards in different matrices.

    PubMed

    Kandić, A; Vukanac, I; Djurašević, M; Novković, D; Šešlak, B; Milošević, Z

    2012-09-01

    In order to assure Quality Control in accordance with ISO/IEC 17025, it was important, from metrological point of view, to examine the long-term stability of calibration standards previously prepared. Comprehensive reconsideration on efficiency curves with respect to the ageing of calibration standards is presented in this paper. The calibration standards were re-used after a period of 5 years and analysis of the results showed discrepancies in efficiency values. Copyright © 2012 Elsevier Ltd. All rights reserved.

  3. Long-term stability of radiotherapy dosimeters calibrated at the Polish Secondary Standard Dosimetry Laboratory.

    PubMed

    Ulkowski, Piotr; Bulski, Wojciech; Chełmiński, Krzysztof

    2015-10-01

    Unidos 10001, Unidos E (10008/10009) and Dose 1 electrometers from 14 radiotherapy centres were calibrated 3-4 times over a long period of time, together with Farmer type (PTW 30001, 30013, Nuclear Enterprises 2571 and Scanditronix-Wellhofer FC65G) cylindrical ionization chambers and plane-parallel type chambers (PTW Markus 23343 and Scanditronix-Wellhofer PPC05). On the basis of the long period of repetitive establishing of calibration coefficients for the same electrometers and ionization chambers, the accuracy of electrometers and the long-term stability of ionization chambers were examined. All measurements were carried out at the same laboratory, by the same staff, according to the same IAEA recommendations. A good accuracy and long-term stability of the dosimeters used in Polish radiotherapy centres was observed. These values were within 0.1% for electrometers and 0.2% for the chambers with electrometers. Furthermore, these values were not observed to vary over time. The observations confirm the opinion that the requirement of calibration of the dosimeters more often than every 2 years is not justified. Copyright © 2015 Elsevier Ltd. All rights reserved.

  4. Satellite Instrument Calibration for Measuring Global Climate Change. Report of a Workshop at the University of Maryland Inn and Conference Center, College Park, MD. , November 12-14, 2002

    NASA Technical Reports Server (NTRS)

    Ohring, G.; Wielicki, B.; Spencer, R.; Emery, B.; Datla, R.

    2004-01-01

    Measuring the small changes associated with long-term global climate change from space is a daunting task. To address these problems and recommend directions for improvements in satellite instrument calibration some 75 scientists, including researchers who develop and analyze long-term data sets from satellites, experts in the field of satellite instrument calibration, and physicists working on state of the art calibration sources and standards met November 12 - 14, 2002 and discussed the issues. The workshop defined the absolute accuracies and long-term stabilities of global climate data sets that are needed to detect expected trends, translated these data set accuracies and stabilities to required satellite instrument accuracies and stabilities, and evaluated the ability of current observing systems to meet these requirements. The workshop's recommendations include a set of basic axioms or overarching principles that must guide high quality climate observations in general, and a roadmap for improving satellite instrument characterization, calibration, inter-calibration, and associated activities to meet the challenge of measuring global climate change. It is also recommended that a follow-up workshop be conducted to discuss implementation of the roadmap developed at this workshop.

  5. A study to assess the long-term stability of the ionization chamber reference system in the LNMRI

    NASA Astrophysics Data System (ADS)

    Trindade Filho, O. L.; Conceição, D. A.; da Silva, C. J.; Delgado, J. U.; de Oliveira, A. E.; Iwahara, A.; Tauhata, L.

    2018-03-01

    Ionization chambers are used as secondary standard in order to maintain the calibration factors of radionuclides in the activity measurements in metrology laboratories. Used as radionuclide calibrator in nuclear medicine clinics to control dose in patients, its long-term performance is not evaluated systematically. A methodology for long-term evaluation for its stability is monitored and checked. Historical data produced monthly of 2012 until 2017, by an ionization chamber, electrometer and 226Ra, were analyzed via control chart, aiming to follow the long-term performance. Monitoring systematic errors were consistent within the limits of control, demonstrating the quality of measurements in compliance with ISO17025.

  6. Characterization of the Sonoran desert as a radiometric calibration target for Earth observing sensors

    USGS Publications Warehouse

    Angal, Amit; Chander, Gyanesh; Xiong, Xiaoxiong; Choi, Tae-young; Wu, Aisheng

    2011-01-01

    To provide highly accurate quantitative measurements of the Earth's surface, a comprehensive calibration and validation of the satellite sensors is required. The NASA Moderate Resolution Imaging Spectroradiometer (MODIS) Characterization Support Team, in collaboration with United States Geological Survey, Earth Resources Observation and Science Center, has previously demonstrated the use of African desert sites to monitor the long-term calibration stability of Terra MODIS and Landsat 7 (L7) Enhanced Thematic Mapper plus (ETM+). The current study focuses on evaluating the suitability of the Sonoran Desert test site for post-launch long-term radiometric calibration as well as cross-calibration purposes. Due to the lack of historical and on-going in situ ground measurements, the Sonoran Desert is not usually used for absolute calibration. An in-depth evaluation (spatial, temporal, and spectral stability) of this site using well calibrated L7 ETM+ measurements and local climatology data has been performed. The Sonoran Desert site produced spatial variability of about 3 to 5% in the reflective solar regions, and the temporal variations of the site after correction for view-geometry impacts were generally around 3%. The results demonstrate that, barring the impacts due to occasional precipitation, the Sonoran Desert site can be effectively used for cross-calibration and long-term stability monitoring of satellite sensors, thus, providing a good test site in the western hemisphere.

  7. Uncertainty Assessment of the SeaWiFS On-Orbit Calibration

    NASA Technical Reports Server (NTRS)

    Eplee, Robert E., Jr.; Meister, Gerhard; Patt, Frederick S.; Franz, Bryan A.; McClain, Charles R.

    2011-01-01

    Ocean color climate data records require water-leaving radiances with 5% absolute and 1% relative accuracies as input. Because of the amplification of any sensor calibration errors by the atmospheric correction, the 1% relative accuracy requirement translates into a 0.1% long-term radiometric stability requirement for top-of-the atmosphere radiances. The rigorous on-orbit calibration program developed and implemented for SeaWiFS by the NASA Ocean Biology Processing Group (OBPG) Calibration and Validation Team (CVT) has allowed the CVT to maintain the stability of the radiometric calibration of SeaWiFS at 0.13% or better over the mission. The uncertainties in the resulting calibrated top-of-the-atmosphere (TOA) radiances can be addressed in terms of accuracy (biases in the measurements), precision (scatter in the measurements), and stability (repeatability of the measurements). The calibration biases of lunar observations relative to the USGS RObotic Lunar Observatory (ROLO) photometric model of the Moon are 2-3%. The biases from the vicarious calibration against the Marine Optical Buoy (MOBY) are 1-2%. The precision of the calibration derived from the solar calibration signal-tonoise ratios are 0.16%, from the lunar residuals are 0.13%, and from the vicarious gains are 0.10%. The long-term stability of the TOA radiances, derived from the lunar time series, is 0.13%. The stability of the vicariouslycalibrated TOA radiances, incorporating the uncertainties in the MOBY measurements and the atmospheric correction, is 0.30%. These results allow the OBPG to produce climate data records from the SeaWiFS ocean color data.

  8. Long-Term Stability of One-Inch Condenser Microphones Calibrated at the National Institute of Standards and Technology

    PubMed Central

    Wagner, Randall P.; Guthrie, William F.

    2015-01-01

    The devices calibrated most frequently by the acoustical measurement services at the National Institute of Standards and Technology (NIST) over the 50-year period from 1963 to 20121 were one-inch condenser microphones of three specific standard types: LS1Pn, LS1Po, and WS1P. Due to its long history of providing calibrations of such microphones to customers, NIST is in a unique position to analyze data concerning the long-term stability of these devices. This long history has enabled NIST to acquire and aggregate a substantial amount of repeat calibration data for a large number of microphones that belong to various other standards and calibration laboratories. In addition to determining microphone sensitivities at the time of calibration, it is important to have confidence that the microphones do not typically undergo significant drift as compared to the calibration uncertainty during the periods between calibrations. For each of the three microphone types, an average drift rate and approximate 95 % confidence interval were computed by two different statistical methods, and the results from the two methods were found to differ insignificantly in each case. These results apply to typical microphones of these types that are used in a suitable environment and handled with care. The average drift rate for Type LS1Pn microphones was −0.004 dB/year to 0.003 dB/year. The average drift rate for Type LS1Po microphones was −0.016 dB/year to 0.008 dB/year. The average drift rate for Type WS1P microphones was −0.004 dB/year to 0.018 dB/year. For each of these microphone types, the average drift rate is not significantly different from zero. This result is consistent with the performance expected of condenser microphones designed for use as transfer standards. In addition, the values that bound the confidence intervals are well within the limits specified for long-term stability in international standards. Even though these results show very good long-term stability historically for these microphone types, it is expected that periodic calibrations will always be done to track the calibration history of individual microphones and check for anomalies indicative of shifts in sensitivity. PMID:26958445

  9. On the Long-Term Stability of Microwave Radiometers Using Noise Diodes for Calibration

    NASA Technical Reports Server (NTRS)

    Brown, Shannon T.; Desai, Shailen; Lu, Wenwen; Tanner, Alan B.

    2007-01-01

    Results are presented from the long-term monitoring and calibration of the National Aeronautics and Space Administration Jason Microwave Radiometer (JMR) on the Jason-1 ocean altimetry satellite and the ground-based Advanced Water Vapor Radiometers (AWVRs) developed for the Cassini Gravity Wave Experiment. Both radiometers retrieve the wet tropospheric path delay (PD) of the atmosphere and use internal noise diodes (NDs) for gain calibration. The JMR is the first radiometer to be flown in space that uses NDs for calibration. External calibration techniques are used to derive a time series of ND brightness for both instruments that is greater than four years. For the JMR, an optimal estimator is used to find the set of calibration coefficients that minimize the root-mean-square difference between the JMR brightness temperatures and the on-Earth hot and cold references. For the AWVR, continuous tip curves are used to derive the ND brightness. For the JMR and AWVR, both of which contain three redundant NDs per channel, it was observed that some NDs were very stable, whereas others experienced jumps and drifts in their effective brightness. Over the four-year time period, the ND stability ranged from 0.2% to 3% among the diodes for both instruments. The presented recalibration methodology demonstrates that long-term calibration stability can be achieved with frequent recalibration of the diodes using external calibration techniques. The JMR PD drift compared to ground truth over the four years since the launch was reduced from 3.9 to - 0.01 mm/year with the recalibrated ND time series. The JMR brightness temperature calibration stability is estimated to be 0.25 K over ten days.

  10. Development of a High-Stability Microstrip-based L-band Radiometer for Ocean Salinity Measurements

    NASA Technical Reports Server (NTRS)

    Pellerano, Fernando A.; Horgan, Kevin A.; Wilson, William J.; Tanner, Alan B.

    2004-01-01

    The development of a microstrip-based L-band Dicke radiometer with the long-term stability required for future ocean salinity measurements to an accuracy of 0.1 psu is presented. This measurement requires the L-band radiometers to have calibration stabilities of less than or equal to 0.05 K over 2 days. This research has focused on determining the optimum radiometer requirements and configuration to achieve this objective. System configuration and component performance have been evaluated with radiometer test beds at both JPL and GSFC. The GSFC testbed uses a cryogenic chamber that allows long-term characterization at radiometric temperatures in the range of 70 - 120 K. The research has addressed several areas including component characterization as a function of temperature and DC bias, system linearity, optimum noise diode injection calibration, and precision temperature control of components. A breadboard radiometer, utilizing microstrip-based technologies, has been built to demonstrate this long-term stability.

  11. Characterization of the Nimbus-7 SBUV radiometer for the long-term monitoring of stratospheric ozone

    NASA Technical Reports Server (NTRS)

    Cebula, Richard P.; Park, H.; Heath, D. F.

    1988-01-01

    Precise knowledge of in-orbit sensitivity change is critical for the successful monitoring of stratospheric ozone by satellite-based remote sensors. This paper evaluates those aspects of the in-flight operation that influence the long-term stability of the upper stratospheric ozone measurements made by the Nimbus-7 SBUV spectroradiometer and chronicles methods used to maintain the long-term albedo calibration of this UV sensor. It is shown that the instrument's calibration for the ozone measurement, the albedo calibration, has been maintained over the first 6 yr of operation to an accuracy of approximately + or - 2 percent. The instrument's wavelength calibration is shown to drift linearly with time. The knowledge of the SBUV wavelength assignment is maintained to a 0.02-nm precision.

  12. Radiometric Calibration Techniques for Signal-of-Opportunity Reflectometers

    NASA Technical Reports Server (NTRS)

    Piepmeier, Jeffrey R.; Shah, Rashmi; Deshpande, Manohar; Johnson, Carey

    2014-01-01

    Bi-static reflection measurements utilizing global navigation satellite service (GNSS) or other signals of opportunity (SoOp) can be used to sense ocean and terrestrial surface properties. End-to-end calibration of GNSS-R has been performed using well-characterized reflection surface (e.g., water), direct path antenna, and receiver gain characterization. We propose an augmented approach using on-board receiver electronics for radiometric calibration of SoOp reflectometers utilizing direct and reflected signal receiving antennas. The method calibrates receiver and correlator gains and offsets utilizing a reference switch and common noise source. On-board electronic calibration sources, such as reference switches, noise diodes and loop-back circuits, have shown great utility in stabilizing total power and correlation microwave radiometer and scatterometer receiver electronics in L-band spaceborne instruments. Application to SoOp instruments is likely to bring several benefits. For example, application to provide short and long time scale calibration stability of the direct path channel, especially in low signal-to-noise ratio configurations, is directly analogous to the microwave radiometer problem. The direct path channel is analogous to the loopback path in a scatterometer to provide a reference of the transmitted power, although the receiver is independent from the reflected path channel. Thus, a common noise source can be used to measure the gain ratio of the two paths. Using these techniques long-term (days to weeks) calibration stability of spaceborne L-band scatterometer and radiometer has been achieved better than 0.1. Similar long-term stability would likely be needed for a spaceborne reflectometer mission to measure terrestrial properties such as soil moisture.

  13. Monitoring on-orbit calibration stability of the Terra MODIS and Landsat 7 ETM+ sensors using pseudo-invariant test sites

    USGS Publications Warehouse

    Chander, G.; Xiong, X.(J.); Choi, T.(J.); Angal, A.

    2010-01-01

    The ability to detect and quantify changes in the Earth's environment depends on sensors that can provide calibrated, consistent measurements of the Earth's surface features through time. A critical step in this process is to put image data from different sensors onto a common radiometric scale. This work focuses on monitoring the long-term on-orbit calibration stability of the Terra Moderate Resolution Imaging Spectroradiometer (MODIS) and the Landsat 7 (L7) Enhanced Thematic Mapper Plus (ETM+) sensors using the Committee on Earth Observation Satellites (CEOS) reference standard pseudo-invariant test sites (Libya 4, Mauritania 1/2, Algeria 3, Libya 1, and Algeria 5). These sites have been frequently used as radiometric targets because of their relatively stable surface conditions temporally. This study was performed using all cloud-free calibrated images from the Terra MODIS and the L7 ETM+ sensors, acquired from launch to December 2008. Homogeneous regions of interest (ROI) were selected in the calibrated images and the mean target statistics were derived from sensor measurements in terms of top-of-atmosphere (TOA) reflectance. For each band pair, a set of fitted coefficients (slope and offset) is provided to monitor the long-term stability over very stable pseudo-invariant test sites. The average percent differences in intercept from the long-term trends obtained from the ETM + TOA reflectance estimates relative to the MODIS for all the CEOS reference standard test sites range from 2.5% to 15%. This gives an estimate of the collective differences due to the Relative Spectral Response (RSR) characteristics of each sensor, bi-directional reflectance distribution function (BRDF), spectral signature of the ground target, and atmospheric composition. The lifetime TOA reflectance trends from both sensors over 10 years are extremely stable, changing by no more than 0.4% per year in its TOA reflectance over the CEOS reference standard test sites.

  14. Optimization of an underwater in-situ LaBr3:Ce spectrometer with energy self-calibration and efficiency calibration.

    PubMed

    Zeng, Zhi; Pan, Xingyu; Ma, Hao; He, Jianhua; Cang, Jirong; Zeng, Ming; Mi, Yuhao; Cheng, Jianping

    2017-03-01

    An underwater in-situ gamma-ray spectrometer based on LaBr 3 :Ce was developed and optimized to monitor marine radioactivity. The intrinsic background mainly from 138 La and 227 Ac of LaBr 3 :Ce was well determined by low background measurement and pulse shape discrimination method. A method of self-calibration using three internal contaminant peaks was proposed to eliminate the peak shift during long-term monitoring. With experiments under different temperatures, the method was proved to be helpful for maintaining long-term stability. To monitor the marine radioactivity, the spectrometer's efficiency was calculated via water tank experiment as well as Monte Carlo simulation. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. An initial investigation of the long-term trends in the fluxgate magnetometer (FGM) calibration parameters on the four Cluster spacecraft

    NASA Astrophysics Data System (ADS)

    Alconcel, L. N. S.; Fox, P.; Brown, P.; Oddy, T. M.; Lucek, E. L.; Carr, C. M.

    2014-07-01

    Over the course of more than 10 years in operation, the calibration parameters of the outboard fluxgate magnetometer (FGM) sensors on the four Cluster spacecraft are shown to be remarkably stable. The parameters are refined on the ground during the rigorous FGM calibration process performed for the Cluster Active Archive (CAA). Fluctuations in some parameters show some correlation with trends in the sensor temperature (orbit position). The parameters, particularly the offsets, of the spacecraft 1 (C1) sensor have undergone more long-term drift than those of the other spacecraft (C2, C3 and C4) sensors. Some potentially anomalous calibration parameters have been identified and will require further investigation in future. However, the observed long-term stability demonstrated in this initial study gives confidence in the accuracy of the Cluster magnetic field data. For the most sensitive ranges of the FGM instrument, the offset drift is typically 0.2 nT per year in each sensor on C1 and negligible on C2, C3 and C4.

  16. An initial investigation of the long-term trends in the fluxgate magnetometer (FGM) calibration parameters on the four Cluster spacecraft

    NASA Astrophysics Data System (ADS)

    Alconcel, L. N. S.; Fox, P.; Brown, P.; Oddy, T. M.; Lucek, E. L.; Carr, C. M.

    2014-01-01

    Over the course of more than ten years in operation, the calibration parameters of the outboard fluxgate magnetometer (FGM) sensors on the four Cluster spacecraft are shown to be remarkably stable. The parameters are refined on the ground during the rigorous FGM calibration process performed for the Cluster Active Archive (CAA). Fluctuations in some parameters show some correlation with trends in the sensor temperature (orbit position). The parameters, particularly the offsets, of the Spacecraft1 (C1) sensor have undergone more long-term drift than those of the other spacecraft (C2, C3 and C4) sensors. Some potentially anomalous calibration parameters have been identified and will require further investigation in future. However, the observed long-term stability demonstrated in this initial study gives confidence in the relative accuracy of the Cluster magnetic field data. For the most sensitive ranges of the FGM instrument, the offset drift is typically 0.2 nT yr-1 in each sensor on C1 and negligible on C2, C3 and C4.

  17. The use of the Sonoran Desert as a pseudo-invariant site for optical sensor cross-calibration and long-term stability monitoring

    USGS Publications Warehouse

    Angal, A.; Chander, Gyanesh; Choi, Taeyoung; Wu, Aisheng; Xiong, Xiaoxiong

    2010-01-01

    The Sonoran Desert is a large, flat, pseudo-invariant site near the United States-Mexico border. It is one of the largest and hottest deserts in North America, with an area of 311,000 square km. This site is particularly suitable for calibration purposes because of its high spatial and spectral uniformity and reasonable temporal stability. This study uses measurements from four different sensors, Terra Moderate Resolution Imaging Spectroradiometer (MODIS), Landsat 7 (L7) Enhanced Thematic Mapper Plus (ETM+), Aqua MODIS, and Landsat 5 (L5) Thematic Mapper (TM), to assess the suitability of this site for long-term stability monitoring and to evaluate the “radiometric calibration differences” between spectrally matching bands of all four sensors. In general, the drift in the top-of-atmosphere (TOA) reflectance of each sensor over a span of nine years is within the specified calibration uncertainties. Monthly precipitation measurements of the Sonoran Desert region were obtained from the Global Historical Climatology Network (GHCN), and their effects on the retrieved TOA reflectances were evaluated. To account for the combined uncertainties in the TOA reflectance due to the surface and atmospheric Bi-directional Reflectance Distribution Function (BRDF), a semi-empirical BRDF model has been adopted to monitor and reduce the impact of illumination geometry differences on the retrieved TOA reflectances. To evaluate calibration differences between the MODIS and Landsat sensors, correction for spectral response differences using a hyperspectral sensor is also demonstrated.

  18. Using Lunar Observations for Calibration Stability and Data Continuity for SNPP VIIRS and MODIS Reflected Solar Bands

    NASA Astrophysics Data System (ADS)

    Xiong, X.; Stone, T. C.

    2017-12-01

    To meet objectives for assembling continuous Earth environmental data records from multiple satellite instruments, a key consideration is to assure consistent and stable sensor calibration across platforms and spanning mission lifetimes. Maintaining and verifying calibration stability in orbit is particularly challenging for reflected solar band (RSB) radiometer instruments, as options for stable references are limited. The Moon is used regularly as a calibration target, which has capabilities for long-term sensor performance monitoring and for use as a common reference for RSB sensor inter-calibration. Suomi NPP VIIRS has viewed the Moon nearly every month since launch, utilizing spacecraft roll maneuvers to acquire lunar observations within a small range of phase angles. The VIIRS Characterization Support Team (VCST) at NASA GSFC has processed the Moon images acquired by SNPP VIIRS into irradiance measurements for calibration purposes; however, the variations in the Moon's brightness still require normalizing the VIIRS lunar measurements using radiometric reference values generated by the USGS lunar calibration system, i.e. the ROLO model. Comparison of the lunar irradiance time series to the calibration f-factors derived from the VIIRS on-board solar diffuser system shows similar overall trends in sensor response, but also reveals residual geometric anomalies in the lunar model results. The excellent lunar radiometry achieved by SNPP VIIRS is actively being used to advance lunar model development at USGS. Both MODIS instruments also have viewed the Moon regularly since launch, providing a practical application of sensor inter-calibration using the Moon as a common reference. This paper discusses ongoing efforts aimed toward demonstrating and utilizing the full potential of lunar observations to support long-term calibration stability and consistency for SNPP VIIRS and MODIS, thus contributing to level-1B data quality assurance for continuity and monitoring global environmental changes.

  19. LWIR pupil imaging and longer-term calibration stability

    NASA Astrophysics Data System (ADS)

    LeVan, Paul D.; Sakoglu, Ünal

    2016-09-01

    A previous paper described LWIR pupil imaging, and an improved understanding of the behavior of this type of sensor for which the high-sensitivity focal plane array (FPA) operated at higher flux levels includes a reversal in signal integration polarity. We have since considered a candidate methodology for efficient, long-term calibration stability that exploits the following two properties of pupil imaging: (1) a fixed pupil position on the FPA, and (2) signal levels from the scene imposed on significant but fixed LWIR background levels. These two properties serve to keep each pixel operating over a limited dynamic range that corresponds to its location in the pupil and to the signal levels generated at this location by the lower and upper calibration flux levels. Exploiting this property for which each pixel of the Pupil Imager operates over its limited dynamic range, the signal polarity reversal between low and high flux pixels, which occurs for a circular region of pixels near the upper edges of the pupil illumination profile, can be rectified to unipolar integration with a two-level non-uniformity correction (NUC). Images corrected real-time with standard non-uniformity correction (NUC) techniques, are still subject to longer-term drifts in pixel offsets between recalibrations. Long-term calibration stability might then be achieved using either a scene-based non-uniformity correction approach, or with periodic repointing for off-source background estimation and subtraction. Either approach requires dithering of the field of view, by sub-pixel amounts for the first method, or by large off-source motions outside the 0.38 milliradian FOV for the latter method. We report on the results of investigations along both these lines.

  20. Using the Sonoran Desert test site to monitor the long-term radiometric stability of the Landsat TM/ETM+ and Terra MODIS sensors

    USGS Publications Warehouse

    Angal, A.; Xiong, X.; Choi, T.; Chander, G.; Wu, A.

    2009-01-01

    Pseudo-invariant ground targets have been extensively used to monitor the long-term radiometric calibration stability of remote sensing instruments. The NASA MODIS Characterization Support Team (MCST), in collaboration with members from the U.S. Geological Survey (USGS) Earth Resources Observation and Science (EROS) Center, has previously demonstrated the use of pseudo-invariant ground sites for the long-term stability monitoring of Terra MODIS and Landsat 7 ETM+ sensors. This paper focuses on the results derived from observations made over the Sonoran Desert. Additionally, Landsat 5 TM data over the Sonoran Desert site were used to evaluate the temporal stability of this site. Top-ofatmosphere (TOA) reflectances were computed for the closely matched TM, ETM+, and MODIS spectral bands over selected regions of interest. The impacts due to different viewing geometries, or the effect of test site Bi-directional Reflectance Distribution Function (BRDF), are also presented. ?? 2009 SPIE.

  1. Estimation of absorbed dose in clinical radiotherapy linear accelerator beams: Effect of ion chamber calibration and long-term stability

    PubMed Central

    Ravichandran, Ramamoorthy; Binukumar, Johnson Pichy; Davis, Cheriyathmanjiyil Antony

    2013-01-01

    The measured dose in water at reference point in phantom is a primary parameter for planning the treatment monitor units (MU); both in conventional and intensity modulated/image guided treatments. Traceability of dose accuracy therefore still depends mainly on the calibration factor of the ion chamber/dosimeter provided by the accredited Secondary Standard Dosimetry Laboratories (SSDLs), under International Atomic Energy Agency (IAEA) network of laboratories. The data related to Nd,water calibrations, thermoluminescent dosimetry (TLD) postal dose validation, inter-comparison of different dosimeter/electrometers, and validity of Nd,water calibrations obtained from different calibration laboratories were analyzed to find out the extent of accuracy achievable. Nd,w factors in Gray/Coulomb calibrated at IBA, GmBH, Germany showed a mean variation of about 0.2% increase per year in three Farmer chambers, in three subsequent calibrations. Another ion chamber calibrated in different accredited laboratory (PTW, Germany) showed consistent Nd,w for 9 years period. The Strontium-90 beta check source response indicated long-term stability of the ion chambers within 1% for three chambers. Results of IAEA postal TL “dose intercomparison” for three photon beams, 6 MV (two) and 15 MV (one), agreed well within our reported doses, with mean deviation of 0.03% (SD 0.87%) (n = 9). All the chamber/electrometer calibrated by a single SSDL realized absorbed doses in water within 0.13% standard deviations. However, about 1-2% differences in absorbed dose estimates observed when dosimeters calibrated from different calibration laboratories are compared in solid phantoms. Our data therefore imply that the dosimetry level maintained for clinical use of linear accelerator photon beams are within recommended levels of accuracy, and uncertainties are within reported values. PMID:24672156

  2. Application of Millisecond Pulsar Timing to the Long-Term Stability of Clock Ensembles

    NASA Technical Reports Server (NTRS)

    Foster, Roger S.; Matsakis, Demetrios N.

    1996-01-01

    We review the application of millisecond pulsars to define a precise long-term standard and positional reference system in a nearly inertial reference frame. We quantify the current timing precision of the best millisecond pulsars and define the required precise time and time interval (PTTI) accuracy and stability to enable time transfer via pulsars. Pulsars may prove useful as independent standards to examine decade-long timing stability and provide an independent natural system within which to calibrate any new, perhaps vastly improved atomic time scale. Since pulsar stability appears to be related to the lifetime of the pulsar, the new millisecond pulsar J173+0747 is projected to have a 100-day accuracy equivalent to a single HP5071 cesium standard. Over the last five years, dozens of new millisecond pulsars have been discovered. A few of the new millisecond pulsars may have even better timing properties.

  3. Monitoring and modeling of long-term settlements of an experimental landfill in Brazil.

    PubMed

    Simões, Gustavo Ferreira; Catapreta, Cícero Antônio Antunes

    2013-02-01

    Settlement evaluation in sanitary landfills is a complex process, due to the waste heterogeneity, time-varying properties and influencing factors and mechanisms, such as mechanical compression due to load application and creep, and physical-chemical and biological processes caused by the wastes decomposition. Many empirical models for the analysis of long-term settlement in landfills are reported in the literature. This paper presents the results of a settlement monitoring program carried out during 6 years in Belo Horizonte experimental landfill. Different sets of field data were used to calibrate three long-term settlement prediction models (rheological, hyperbolic and composite). The parameters obtained in the calibration were used to predict the settlements and to compare with actual field data. During the monitoring period of 6 years, significant vertical strains were observed (of up to 31%) in relation to the initial height of the experimental landfill. The results for the long-term settlement prediction obtained by the hyperbolic and rheological models significantly underestimate the settlements, regardless the period of data used in the calibration. The best fits were obtained with the composite model, except when 1 year field data were used in the calibration. The results of the composite model indicate settlements stabilization at larger times and with larger final settlements when compared to the hyperbolic and rheological models. Copyright © 2012 Elsevier Ltd. All rights reserved.

  4. A quality assurance program for clinical PDT

    NASA Astrophysics Data System (ADS)

    Dimofte, Andreea; Finlay, Jarod; Ong, Yi Hong; Zhu, Timothy C.

    2018-02-01

    Successful outcome of Photodynamic therapy (PDT) depends on accurate delivery of prescribed light dose. A quality assurance program is necessary to ensure that light dosimetry is correctly measured. We have instituted a QA program that include examination of long term calibration uncertainty of isotropic detectors for light fluence rate, power meter head intercomparison for laser power, stability of the light-emitting diode (LED) light source integrating sphere as a light fluence standard, laser output and calibration of in-vivo reflective fluorescence and absorption spectrometers. We examined the long term calibration uncertainty of isotropic detector sensitivity, defined as fluence rate per voltage. We calibrate the detector using the known calibrated light fluence rate of the LED light source built into an internally baffled 4" integrating sphere. LED light sources were examined using a 1mm diameter isotropic detector calibrated in a collimated beam. Wavelengths varying from 632nm to 690nm were used. The internal LED method gives an overall calibration accuracy of +/- 4%. Intercomparison among power meters was performed to determine the consistency of laser power and light fluence rate measured among different power meters. Power and fluence readings were measured and compared among detectors. A comparison of power and fluence reading among several power heads shows long term consistency for power and light fluence rate calibration to within 3% regardless of wavelength. The standard LED light source is used to calibrate the transmission difference between different channels for the diffuse reflective absorption and fluorescence contact probe as well as isotropic detectors used in PDT dose dosimeter.

  5. Evaluation on Radiometric Capability of Chinese Optical Satellite Sensors

    PubMed Central

    Yang, Aixia; Zhong, Bo; Wu, Shanlong; Liu, Qinhuo

    2017-01-01

    The radiometric capability of on-orbit sensors should be updated on time due to changes induced by space environmental factors and instrument aging. Some sensors, such as Moderate Resolution Imaging Spectroradiometer (MODIS), have onboard calibrators, which enable real-time calibration. However, most Chinese remote sensing satellite sensors lack onboard calibrators. Their radiometric calibrations have been updated once a year based on a vicarious calibration procedure, which has affected the applications of the data. Therefore, a full evaluation of the sensors’ radiometric capabilities is essential before quantitative applications can be made. In this study, a comprehensive procedure for evaluating the radiometric capability of several Chinese optical satellite sensors is proposed. In this procedure, long-term radiometric stability and radiometric accuracy are the two major indicators for radiometric evaluation. The radiometric temporal stability is analyzed by the tendency of long-term top-of-atmosphere (TOA) reflectance variation; the radiometric accuracy is determined by comparison with the TOA reflectance from MODIS after spectrally matching. Three Chinese sensors including the Charge-Coupled Device (CCD) camera onboard Huan Jing 1 satellite (HJ-1), as well as the Visible and Infrared Radiometer (VIRR) and Medium-Resolution Spectral Imager (MERSI) onboard the Feng Yun 3 satellite (FY-3) are evaluated in reflective bands based on this procedure. The results are reasonable, and thus can provide reliable reference for the sensors’ application, and as such will promote the development of Chinese satellite data. PMID:28117745

  6. Evaluation on Radiometric Capability of Chinese Optical Satellite Sensors.

    PubMed

    Yang, Aixia; Zhong, Bo; Wu, Shanlong; Liu, Qinhuo

    2017-01-22

    The radiometric capability of on-orbit sensors should be updated on time due to changes induced by space environmental factors and instrument aging. Some sensors, such as Moderate Resolution Imaging Spectroradiometer (MODIS), have onboard calibrators, which enable real-time calibration. However, most Chinese remote sensing satellite sensors lack onboard calibrators. Their radiometric calibrations have been updated once a year based on a vicarious calibration procedure, which has affected the applications of the data. Therefore, a full evaluation of the sensors' radiometric capabilities is essential before quantitative applications can be made. In this study, a comprehensive procedure for evaluating the radiometric capability of several Chinese optical satellite sensors is proposed. In this procedure, long-term radiometric stability and radiometric accuracy are the two major indicators for radiometric evaluation. The radiometric temporal stability is analyzed by the tendency of long-term top-of-atmosphere (TOA) reflectance variation; the radiometric accuracy is determined by comparison with the TOA reflectance from MODIS after spectrally matching. Three Chinese sensors including the Charge-Coupled Device (CCD) camera onboard Huan Jing 1 satellite (HJ-1), as well as the Visible and Infrared Radiometer (VIRR) and Medium-Resolution Spectral Imager (MERSI) onboard the Feng Yun 3 satellite (FY-3) are evaluated in reflective bands based on this procedure. The results are reasonable, and thus can provide reliable reference for the sensors' application, and as such will promote the development of Chinese satellite data.

  7. A practical approach to spectral calibration of short wavelength infrared hyper-spectral imaging systems

    NASA Astrophysics Data System (ADS)

    Bürmen, Miran; Pernuš, Franjo; Likar, Boštjan

    2010-02-01

    Near-infrared spectroscopy is a promising, rapidly developing, reliable and noninvasive technique, used extensively in the biomedicine and in pharmaceutical industry. With the introduction of acousto-optic tunable filters (AOTF) and highly sensitive InGaAs focal plane sensor arrays, real-time high resolution hyper-spectral imaging has become feasible for a number of new biomedical in vivo applications. However, due to the specificity of the AOTF technology and lack of spectral calibration standardization, maintaining long-term stability and compatibility of the acquired hyper-spectral images across different systems is still a challenging problem. Efficiently solving both is essential as the majority of methods for analysis of hyper-spectral images relay on a priori knowledge extracted from large spectral databases, serving as the basis for reliable qualitative or quantitative analysis of various biological samples. In this study, we propose and evaluate fast and reliable spectral calibration of hyper-spectral imaging systems in the short wavelength infrared spectral region. The proposed spectral calibration method is based on light sources or materials, exhibiting distinct spectral features, which enable robust non-rigid registration of the acquired spectra. The calibration accounts for all of the components of a typical hyper-spectral imaging system such as AOTF, light source, lens and optical fibers. The obtained results indicated that practical, fast and reliable spectral calibration of hyper-spectral imaging systems is possible, thereby assuring long-term stability and inter-system compatibility of the acquired hyper-spectral images.

  8. Operational Support for Instrument Stability through ODI-PPA Metadata Visualization and Analysis

    NASA Astrophysics Data System (ADS)

    Young, M. D.; Hayashi, S.; Gopu, A.; Kotulla, R.; Harbeck, D.; Liu, W.

    2015-09-01

    Over long time scales, quality assurance metrics taken from calibration and calibrated data products can aid observatory operations in quantifying the performance and stability of the instrument, and identify potential areas of concern or guide troubleshooting and engineering efforts. Such methods traditionally require manual SQL entries, assuming the requisite metadata has even been ingested into a database. With the ODI-PPA system, QA metadata has been harvested and indexed for all data products produced over the life of the instrument. In this paper we will describe how, utilizing the industry standard Highcharts Javascript charting package with a customized AngularJS-driven user interface, we have made the process of visualizing the long-term behavior of these QA metadata simple and easily replicated. Operators can easily craft a custom query using the powerful and flexible ODI-PPA search interface and visualize the associated metadata in a variety of ways. These customized visualizations can be bookmarked, shared, or embedded externally, and will be dynamically updated as new data products enter the system, enabling operators to monitor the long-term health of their instrument with ease.

  9. The moon as a radiometric reference source for on-orbit sensor stability calibration

    USGS Publications Warehouse

    Stone, T.C.

    2009-01-01

    The wealth of data generated by the world's Earth-observing satellites, now spanning decades, allows the construction of long-term climate records. A key consideration for detecting climate trends is precise quantification of temporal changes in sensor calibration on-orbit. For radiometer instruments in the solar reflectance wavelength range (near-UV to shortwave-IR), the Moon can be viewed as a solar diffuser with exceptional stability properties. A model for the lunar spectral irradiance that predicts the geometric variations in the Moon's brightness with ???1% precision has been developed at the U.S. Geological Survey in Flagstaff, AZ. Lunar model results corresponding to a series of Moon observations taken by an instrument can be used to stabilize sensor calibration with sub-percent per year precision, as demonstrated by the Sea-viewing Wide Field-of-view Sensor (SeaWiFS). The inherent stability of the Moon and the operational model to utilize the lunar irradiance quantity provide the Moon as a reference source for monitoring radiometric calibration in orbit. This represents an important capability for detecting terrestrial climate change from space-based radiometric measurements.

  10. Calibration of high voltages at the ppm level by the difference of ^{83{m}}Kr conversion electron lines at the KATRIN experiment

    NASA Astrophysics Data System (ADS)

    Arenz, M.; Baek, W.-J.; Beck, M.; Beglarian, A.; Behrens, J.; Bergmann, T.; Berlev, A.; Besserer, U.; Blaum, K.; Bode, T.; Bornschein, B.; Bornschein, L.; Brunst, T.; Buzinsky, N.; Chilingaryan, S.; Choi, W. Q.; Deffert, M.; Doe, P. J.; Dragoun, O.; Drexlin, G.; Dyba, S.; Edzards, F.; Eitel, K.; Ellinger, E.; Engel, R.; Enomoto, S.; Erhard, M.; Eversheim, D.; Fedkevych, M.; Fischer, S.; Formaggio, J. A.; Fränkle, F. M.; Franklin, G. B.; Friedel, F.; Fulst, A.; Gil, W.; Glück, F.; Ureña, A. Gonzalez; Grohmann, S.; Grössle, R.; Gumbsheimer, R.; Hackenjos, M.; Hannen, V.; Harms, F.; Haußmann, N.; Heizmann, F.; Helbing, K.; Herz, W.; Hickford, S.; Hilk, D.; Hillesheimer, D.; Howe, M. A.; Huber, A.; Jansen, A.; Kellerer, J.; Kernert, N.; Kippenbrock, L.; Kleesiek, M.; Klein, M.; Kopmann, A.; Korzeczek, M.; Kovalík, A.; Krasch, B.; Kraus, M.; Kuckert, L.; Lasserre, T.; Lebeda, O.; Letnev, J.; Lokhov, A.; Machatschek, M.; Marsteller, A.; Martin, E. L.; Mertens, S.; Mirz, S.; Monreal, B.; Neumann, H.; Niemes, S.; Off, A.; Osipowicz, A.; Otten, E.; Parno, D. S.; Pollithy, A.; Poon, A. W. P.; Priester, F.; Ranitzsch, P. C.-O.; Rest, O.; Robertson, R. G. H.; Roccati, F.; Rodenbeck, C.; Röllig, M.; Röttele, C.; Ryšavý, M.; Sack, R.; Saenz, A.; Schimpf, L.; Schlösser, K.; Schlösser, M.; Schönung, K.; Schrank, M.; Seitz-Moskaliuk, H.; Sentkerestiová, J.; Sibille, V.; Slezák, M.; Steidl, M.; Steinbrink, N.; Sturm, M.; Suchopar, M.; Suesser, M.; Telle, H. H.; Thorne, L. A.; Thümmler, T.; Titov, N.; Tkachev, I.; Trost, N.; Valerius, K.; Vénos, D.; Vianden, R.; Hernández, A. P. Vizcaya; Weber, M.; Weinheimer, C.; Weiss, C.; Welte, S.; Wendel, J.; Wilkerson, J. F.; Wolf, J.; Wüstling, S.; Zadoroghny, S.

    2018-05-01

    The neutrino mass experiment KATRIN requires a stability of 3 ppm for the retarding potential at - 18.6 kV of the main spectrometer. To monitor the stability, two custom-made ultra-precise high-voltage dividers were developed and built in cooperation with the German national metrology institute Physikalisch-Technische Bundesanstalt (PTB). Until now, regular absolute calibration of the voltage dividers required bringing the equipment to the specialised metrology laboratory. Here we present a new method based on measuring the energy difference of two ^{83{m}}Kr conversion electron lines with the KATRIN setup, which was demonstrated during KATRIN's commissioning measurements in July 2017. The measured scale factor M=1972.449(10) of the high-voltage divider K35 is in agreement with the last PTB calibration 4 years ago. This result demonstrates the utility of the calibration method, as well as the long-term stability of the voltage divider.

  11. Using the Sonoran and Libyan Desert test sites to monitor the temporal stability of reflective solar bands for Landsat 7 enhanced thematic mapper plus and Terra moderate resolution imaging spectroradiometer sensors

    USGS Publications Warehouse

    Angal, Amit; Xiong, Xiaoxiong; Choi, Tae-young; Chander, Gyanesh; Wu, Aisheng

    2010-01-01

    Remote sensing imagery is effective for monitoring environmental and climatic changes because of the extent of the global coverage and long time scale of the observations. Radiometric calibration of remote sensing sensors is essential for quantitative & qualitative science and applications. Pseudo-invariant ground targets have been extensively used to monitor the long-term radiometric calibration stability of remote sensing sensors. This paper focuses on the use of the Sonoran Desert site to monitor the radiometric stability of the Landsat 7 (L7) Enhanced Thematic Mapper Plus (ETM+) and Terra Moderate Resolution Imaging Spectroradiometer (MODIS) sensors. The results are compared with the widely used Libya 4 Desert site in an attempt to evaluate the suitability of the Sonoran Desert site for sensor inter-comparison and calibration stability monitoring. Since the overpass times of ETM+ and MODIS differ by about 30 minutes, the impacts due to different view geometries or test site Bi-directional Reflectance Distribution Function (BRDF) are also presented. In general, the long-term drifts in the visible bands are relatively large compared to the drift in the near-infrared bands of both sensors. The lifetime Top-of-Atmosphere (TOA) reflectance trends from both sensors over 10 years are extremely stable, changing by no more than 0.1% per year (except ETM+ Band 1 and MODIS Band 3) over the two sites used for the study. The use of a semi-empirical BRDF model can reduce the impacts due to view geometries, thus enabling a better estimate of sensor temporal drifts.

  12. An assessment of African test sites in the context of a global network of quality-assured reference standards

    USGS Publications Warehouse

    Chander, G.; Xiong, X.; Angal, A.; Choi, T.

    2009-01-01

    The Committee on Earth Observation Satellites (CEOS) Infrared and Visible Optical Sensors (IVOS) subgroup members established a set of CEOS-endorsed globally distributed reference standard test sites for the postlaunch calibration of space-based optical imaging sensors. This paper discusses the top five African pseudo-invariant sites (Libya 4, Mauritania 1/2, Algeria 3, Libya 1, and Algeria 5) that were identified by the IVOS subgroup. This paper focuses on monitoring the long-term radiometric stability of the Terra Moderate Resolution Imaging Spectroradiometer (MODIS) and the Landsat 7 (L7) Enhanced Thematic Mapper Plus (ETM+) sensors using near-simultaneous and cloud-free image pairs acquired from launch to December 2008 over the five African desert sites. Residual errors and coefficients of determination were also generated to support the quality assessment of the calibration differences between the two sensors. An effort was also made to evaluate the relative stability of these sites for long-term monitoring of the optical sensors. ??2009 IEEE.

  13. Long-Term Stability Assessment of Sonoran Desert for Vicarious Calibration of GOES-R

    NASA Astrophysics Data System (ADS)

    Kim, W.; Liang, S.; Cao, C.

    2012-12-01

    Vicarious calibration refers to calibration techniques that do not depend on onboard calibration devices. Although sensors and onboard calibration devices undergo rigorous validation processes before launch, performance of sensors often degrades after the launch due to exposure to the harsh space environment and the aging of devices. Such in-flight changes of devices can be identified and adjusted through vicarious calibration activities where the sensor degradation is measured in reference to exterior calibration sources such as the Sun, the Moon, and the Earth surface. Sonoran desert is one of the best calibration sites located in the North America that are available for vicarious calibration of GOES-R satellite. To accurately calibrate sensors onboard GOES-R satellite (e.g. advanced baseline imager (ABI)), the temporal stability of Sonoran desert needs to be assessed precisely. However, short-/mid-term variations in top-of-atmosphere (TOA) reflectance caused by meteorological variables such as water vapor amount and aerosol loading are often difficult to retrieve, making the use of TOA reflectance time series for the stability assessment of the site. In this paper, we address this issue of normalization of TOA reflectance time series using a time series analysis algorithm - seasonal trend decomposition procedure based on LOESS (STL) (Cleveland et al, 1990). The algorithm is basically a collection of smoothing filters which leads to decomposition of a time series into three additive components; seasonal, trend, and remainder. Since this non-linear technique is capable of extracting seasonal patterns in the presence of trend changes, the seasonal variation can be effectively identified in the time series of remote sensing data subject to various environmental changes. The experiment results performed with Landsat 5 TM data show that the decomposition results acquired for the Sonoran Desert area produce normalized series that have much less uncertainty than those of traditional BRDF models, which leads to more accurate stability assessment.

  14. Laboratory Astrophysics Using a Microcalorimeter and Bragg Crystal Spectrometer on an Electron Beam Ion Trap

    NASA Technical Reports Server (NTRS)

    Brinton, John (Technical Monitor); Silver, Eric

    2005-01-01

    We completed modifications to the new microcalorimeter system dedicated for use on the EBIT at NIST, which included: 1) a redesign of the x-ray calibration source from a direct electron impact source to one that irradiates the microcalorimeter with fluorescent x-rays. The resulting calibration lines are free of bremsstrahlung background; 2) the microcalorimeter electronic circuit was significantly improved to ensure long-term stability for lengthy experimental runs

  15. Multiyear On-orbit Calibration and Performance of Terra MODIS Thermal Emissive Bands

    NASA Technical Reports Server (NTRS)

    Xiong, Xiaoxiong; Chiang, Kwo-Fu; Wu, Aisheng; Barnes, William; Guenther, Bruce; Salomonson, Vincent

    2007-01-01

    Since launch in December 1999, Terra MODIS has been making continuous Earth observations for more than seven years. It has produced a broad range of land, ocean, and atmospheric science data products for improvements in studies of global climate and environmental change. Among its 36 spectral bands, there are 20 reflective solar bands (RSB) and 16 thermal emissive bands (TEB). MODIS thermal emissive bands cover the mid-wave infrared (MWIR) and long-wave infrared (LWIR) spectral regions with wavelengths from 3.7 to 14.4pm. They are calibrated on-orbit using an on-board blackbody (BB) with its temperature measured by a set of thermistors on a scan-by-scan basis. This paper will provide a brief overview of MODIS TEB calibration and characterization methodologies and illustrate on-board BB functions and TEB performance over more than seven years of on-orbit operation and calibration. Discussions will be focused on TEB detector short-term stability and noise characterization, and changes in long-term response (or system gain). Results show that Terra MODIS BB operation has been extremely stable since launch. When operated at its nominal controlled temperature of 290K, the BB temperature variation is typically less than +0.30mK on a scan-by-scan basis and there has been no time-dependent temperature drift. In addition to excellent short-term stability, most TEB detectors continue to meet or exceed their specified noise characterization requirements, thus enabling calibration accuracy and science data product quality to be maintained. Excluding the noisy detectors identified pre-launch and those that occurred post-launch, the changes in TEB responses have been less than 0.7% on an annual basis. The optical leak corrections applied to bands 32-36 have been effective and stable over the entire mission

  16. Time stability of spring and superconducting gravimeters through the analysis of very long gravity records

    NASA Astrophysics Data System (ADS)

    Calvo, Marta; Hinderer, Jacques; Rosat, Severine; Legros, Hilaire; Boy, Jean-Paul; Ducarme, Bernard; Zürn, Walter

    2014-10-01

    Long gravity records are of great interest when performing tidal analyses. Indeed, long series enable to separate contributions of near-frequency waves and also to detect low frequency signals (e.g. long period tides and polar motion). In addition to the length of the series, the quality of the data and the temporal stability of the noise are also very important. We study in detail some of the longest gravity records available in Europe: 3 data sets recorded with spring gravimeters in Black Forest Observatory (Germany, 1980-2012), Walferdange (Luxemburg, 1980-1995) and Potsdam (Germany, 1974-1998) and several superconducting gravimeters (SGs) data sets, with at least 9 years of continuous records, at different European GGP (Global Geodynamics Project) sites (Bad Homburg, Brussels, Medicina, Membach, Moxa, Vienna, Wettzell and Strasbourg). The stability of each instrument is investigated using the temporal variations of tidal parameters (amplitude factor and phase difference) for the main tidal waves (O1, K1, M2 and S2) as well as the M2/O1 factor ratio, the later being insensitive to the instrumental calibration. The long term stability of the tidal observations is also dependent on the stability of the scale factor of the relative gravimeters. Therefore we also check the time stability of the scale factor for the superconducting gravimeter C026 installed at the J9 Gravimetric Observatory of Strasbourg (France), using numerous calibration experiments carried out by co-located absolute gravimeter (AG) measurements during the last 15 years. The reproducibility of the scale factor and the achievable precision are investigated by comparing the results of different calibration campaigns. Finally we present a spectrum of the 25 years of SG records at J9 Observatory, with special attention to small amplitude tides in the semi-diurnal and diurnal bands, as well as to the low frequency part.

  17. The LTDP ALTS Project: Contributing to the Continued Understanding and Exploitation of the ATSR Time Series

    NASA Astrophysics Data System (ADS)

    Clarke, Hannah; Done, Fay; Casadio, Stefano; Mackin, Stephen; Dinelli, Bianca Maria; Castelli, Elisa

    2016-08-01

    The long time-series of observations made by the Along Track Scanning Radiometers (ATSR) missions represents a valuable resource for a wide range of research and EO applications.With the advent of ESA's Long-TermData Preservation (LTDP) programme, thought has turned to the preservation and improved understanding of such long time-series, to support their continued exploitation in both existing and new areas of research, bringing the possibility of improving the existing data set and to inform and contribute towards future missions. For this reason, the 'Long Term Stability of the ATSR Instrument Series: SWIR Calibration, Cloud Masking and SAA' project, commonly known as the ATSR Long Term Stability (or ALTS) project, is designed to explore the key characteristics of the data set and new and innovative ways of enhancing and exploiting it.Work has focussed on: A new approach to the assessment of Short Wave Infra-Red (SWIR) channel calibration.; Developmentof a new method for Total Column Water Vapour (TCWV) retrieval.; Study of the South Atlantic Anomaly (SAA).; Radiative Transfer (RT) modelling for ATSR.; Providing AATSR observations with their location in the original instrument grid.; Strategies for the retrieval and archiving of historical ATSR documentation.; Study of TCWV retrieval over land; Development of new methods for cloud masking This paper provides an overview of these activities and illustrates the importance of preserving and understanding 'old' data for continued use in the future.

  18. The OLI Radiometric Scale Realization Round Robin Measurement Campaign

    NASA Technical Reports Server (NTRS)

    Cutlip, Hansford; Cole,Jerold; Johnson, B. Carol; Maxwell, Stephen; Markham, Brian; Ong, Lawrence; Hom, Milton; Biggar, Stuart

    2011-01-01

    A round robin radiometric scale realization was performed at the Ball Aerospace Radiometric Calibration Laboratory in January/February 2011 in support of the Operational Land Imager (OLI) Program. Participants included Ball Aerospace, NIST, NASA Goddard Space Flight Center, and the University of Arizona. The eight day campaign included multiple observations of three integrating sphere sources by nine radiometers. The objective of the campaign was to validate the radiance calibration uncertainty ascribed to the integrating sphere used to calibrate the OLI instrument. The instrument level calibration source uncertainty was validated by quatnifying: (1) the long term stability of the NIST calibrated radiance artifact, (2) the responsivity scale of the Ball Aerospace transfer radiometer and (3) the operational characteristics of the large integrating sphere.

  19. DANSS Neutrino Spectrometer: Detector Calibration, Response Stability, and Light Yield

    NASA Astrophysics Data System (ADS)

    Alekseev, I. G.; Belov, V. V.; Danilov, M. V.; Zhitnikov, I. V.; Kobyakin, A. S.; Kuznetsov, A. S.; Machikhiliyan, I. V.; Medvedev, D. V.; Rusinov, V. Yu.; Svirida, D. N.; Skrobova, N. A.; Starostin, A. S.; Tarkovsky, E. I.; Fomina, M. V.; Shevchik, E. A.; Shirchenko, M. V.

    2018-05-01

    Apart from monitoring nuclear reactor parameters, the DANSS neutrino experiment is aimed at searching for sterile neutrinos through a detailed analysis of the ratio of reactor antineutrino spectra measured at different distances from the reactor core. The light collection system of the detector is dual, comprising both the vacuum photomultiplier tubes (PMTs) and silicon photomultipliers (SiPMs). In this paper, the techniques developed to calibrate the responses of these photodetectors are discussed in detail. The long-term stability of the key parameters of the detector and their dependences on the ambient temperature are investigated. The results of detector light yield measurements, performed independently with PMTs and SiPMs are reported.

  20. Ultra Stable Microwave Radiometers for Future Sea Surface Salinity Missions

    NASA Technical Reports Server (NTRS)

    Wilson, William J.; Tanner, Alan B.; Pellerano, Fernando A.; Horgan, Kevin A.

    2005-01-01

    The NASA Earth Science System Pathfinder (ESSP) mission Aquarius will measure global sea surface salinity with 100-km spatial resolution every 8 days with an average monthly salinity accuracy of 0.2 psu (parts per thousand). This requires an L-band low-noise radiometer with the long-term calibration stability of less than 0.1 K over 8 days. This three-year research program on ultra stable radiometers has addressed the radiometer requirements and configuration necessary to achieve this objective for Aquarius and future ocean salinity missions. The system configuration and component performance have been evaluated with radiometer testbeds at both JPL and GSFC. The research has addressed several areas including component characterization as a function of temperature, a procedure for the measurement and correction for radiometer system non-linearity, noise diode calibration versus temperature, low noise amplifier performance over voltage, and temperature control requirements to achieve the required stability. A breadboard radiometer, utilizing microstrip-based technologies, has been built to demonstrate this long-term stability. This report also presents the results of the radiometer test program, a detailed radiometer noise model, and details of the operational switching sequence optimization that can be used to achieve the low noise and stability requirements. Many of the results of this research have been incorporated into the Aquarius radiometer design and will allow this instrument to achieve its goals.

  1. Characterization of MODIS and SeaWiFS Solar Diffuser On-Orbit Degradation

    NASA Technical Reports Server (NTRS)

    Xiong, X.; Eplee, R. E., Jr.; Sun, J.; Patt, F. S.; Angal, A.; McClain, C. R.

    2009-01-01

    MODIS has 20 reflective solar bands (RSB), covering the VIS, NIR, and SWIR spectral regions. They are calibrated on-orbit using a solar diffuser (SD) panel, made of space-grade Spectralon. The SD bi-directional reflectance factor (BRF) was characterized pre-launch by the instrument vendor reference to the NIST reflectance standard. Its on-orbit degradation is tracked by an on-board solar diffuser stability monitor (SDSM). The SeaWifS on-orbit calibration strategy uses monthly lunar observations to monitor the long-term radiometric stability of the instrument and applies daily observations of its solar diffuser (an aluminum plate coated with YB71 paint) to track the short-term changes in the instrument response. This paper provides an overview of MODIS and SeaWiFS SD observations, applications, and approaches used to track their on-orbit degradations. Results from sensors are presented with emphasis on the spectral dependence and temporal trends of the SD degradation. Lessons and challenges from the use of SD for sensor on-orbit calibration are also discussed.

  2. The long-term stability of portable spirometers used in a multinational study of the prevalence of chronic obstructive pulmonary disease.

    PubMed

    Pérez-Padilla, Rogelio; Vázquez-García, Juan Carlos; Márquez, María Nelly; Jardim, José Roberto B; Pertuzé, Julio; Lisboa, Carmen; Muiño, Adriana; López, María Victorina; Tálamo, Carlos; de Oca, María Montes; Valdivia, Gonzalo; Menezes, Ana Maria B

    2006-10-01

    We report the performance of an ultrasound-based portable spirometer (EasyOne) used in a population-based survey of the prevalence of chronic obstructive pulmonary disease, conducted in 5 Latin American cities: São Paulo, Brazil; México City, México; Montevideo, Uruguay; Santiago, Chile; and Caracas, Venezuela (the Latin American COPD Prevalence Study [PLATINO]). During the survey period (which ranged from 3 months to 6 months in the various locations) we collected daily calibration data from the 70 EasyOne spirometers used in the 5 survey cities. The calibrations were conducted with a 3-L syringe, and the calibration data were stored in the spirometer's database. Ninety-seven percent of the calibration volumes were within +/- 64 mL (2.1%) of the 3-L calibration signal. Excluding data from the first city studied (São Paulo), where one calibration syringe had to be replaced, 98% of the calibration checks were within +/- 50 mL (1.7%). The measured volume was affected only minimally by the syringe's peak flow or emptying time. In these 70 EasyOne spirometers neither calibration nor linearity changed during the study. Such calibration stability is a valuable feature in spirometry surveys and in the clinical setting.

  3. Indirect check of the stability of the reference ion chamber used for accelerator output calibration

    NASA Astrophysics Data System (ADS)

    Kang, Sei-Kwon; Yoon, Jai-Woong; Park, Soah; Hwang, Taejin; Cheong, Kwang-Ho; Han, Tae Jin; Kim, Haeyoung; Lee, Me-Yeon; Kim, Kyoung Ju; Bae, Hoonsik

    2014-11-01

    A linear accelerator's output is periodically checked by using a reference ion chamber which is also periodically calibrated at the accredited standard dosimetry laboratories. We suggest a simple procedure for checking the chamber's stability between calibrations by comparison with another ion chamber. To identify the long-term stability of chambers, we collected and assessed the dose-to-water conversion factors provided by standard laboratories for three chambers during a period of four years. To develop the chamber constancy check program, we used one Farmer-type reference ion chamber FC65-G, two ion chambers (CC13a and CC13b) and one CC01 ion chamber (IBA). Under the accelerator, each chamber was placed inside the solid phantom and irradiated; the experimental configurations were identical. To check the variation in charge collection of the reference chamber, we monitored the ratios of the FC65-G values over each chamber reading. Based on the error propagation of the two chamber ratios, we estimated the uncertainty of the output calibration from the chamber variation. The calibration factors provided for the three chambers showed 0.04 ˜ 0.12% standard deviations during four years. For procedure development, the reading ratios of FC65-G over CCxx showed very good stability; the ratios of FC65-G over CC13a, CC13b and CC01 varied less than 0.059, 0.087 and 0.248%, respectively, over five measurements. By ascribing possible uncertainties of the ratio to the reference chamber alone, we could conservatively check the stability of the reference chamber for treatment safety. An extension of the chamber calibration period was also evaluated. In conclusion, we designed a stability check procedure for the reference chamber based on a reading ratio of two chambers. This could help the user assess the chamber stability between periodic chamber calibration, and the associated patient treatment could be carried out with enhanced safety.

  4. Comments on: Accuracy of Raman Lidar Water Vapor Calibration and its Applicability to Long-Term Measurements

    NASA Technical Reports Server (NTRS)

    Whiteman, David N.; Venable, Demetrius; Landulfo, Eduardo

    2012-01-01

    In a recent publication, LeBlanc and McDermid proposed a hybrid calibration technique for Raman water vapor lidar involving a tungsten lamp and radiosondes. Measurements made with the lidar telescope viewing the calibration lamp were used to stabilize the lidar calibration determined by comparison with radiosonde. The technique provided a significantly more stable calibration constant than radiosondes used alone. The technique involves the use of a calibration lamp in a fixed position in front of the lidar receiver aperture. We examine this configuration and find that such a configuration likely does not properly sample the full lidar system optical efficiency. While the technique is a useful addition to the use of radiosondes alone for lidar calibration, it is important to understand the scenarios under which it will not provide an accurate quantification of system optical efficiency changes. We offer examples of these scenarios.

  5. Common Calibration Source for Monitoring Long-term Ozone Trends

    NASA Technical Reports Server (NTRS)

    Kowalewski, Matthew

    2004-01-01

    Accurate long-term satellite measurements are crucial for monitoring the recovery of the ozone layer. The slow pace of the recovery and limited lifetimes of satellite monitoring instruments demands that datasets from multiple observation systems be combined to provide the long-term accuracy needed. A fundamental component of accurately monitoring long-term trends is the calibration of these various instruments. NASA s Radiometric Calibration and Development Facility at the Goddard Space Flight Center has provided resources to minimize calibration biases between multiple instruments through the use of a common calibration source and standardized procedures traceable to national standards. The Facility s 50 cm barium sulfate integrating sphere has been used as a common calibration source for both US and international satellite instruments, including the Total Ozone Mapping Spectrometer (TOMS), Solar Backscatter Ultraviolet 2 (SBUV/2) instruments, Shuttle SBUV (SSBUV), Ozone Mapping Instrument (OMI), Global Ozone Monitoring Experiment (GOME) (ESA), Scanning Imaging SpectroMeter for Atmospheric ChartographY (SCIAMACHY) (ESA), and others. We will discuss the advantages of using a common calibration source and its effects on long-term ozone data sets. In addition, sphere calibration results from various instruments will be presented to demonstrate the accuracy of the long-term characterization of the source itself.

  6. State-of-the-art MCT IR-modules with enhanced long term and cycle stability

    NASA Astrophysics Data System (ADS)

    Breiter, R.; Wendler, J.; Lutz, H.; Rutzinger, S.; Schallenberg, T.; Ziegler, J.; Rühlich, I.

    2012-06-01

    Current trends on the enhancement of MCT FPA IR-modules are reduction of size, weight and power (SWaP), increase of resolution with large detector arrays, provision of staring LWIR or dual-band capability. This is achieved by reduction of pixel size, higher operating temperatures (HOT) or complex pixel structures together with the optimization of dewars, adapted cooling engines and proximity electronics. To meet these demands AIM is working on MCT single-band MWIR or LWIR modules with formats 640x512 or 1280x1024 in 15μm pitch and a dual-band MWIR/LWIR module 640x512 in 20μm pitch. As a first step high operating temperatures for MWIR 120K and LWIR 80K were demonstrated, development for MWIR >= 150K and LWIR >= 90K is ongoing. The modules are realized as integrated detector cooler assemblies (IDCA) with proximity electronics. The 640x512/15μm pitch modules are already available in application specific configurations e.g. having integral rotary or split linear cooling engines. Besides implementation of the above mentioned capabilities also improvement in long term and cycle stability of IRmodules has been achieved which is important to fully benefit from increased mission times and longer maintenance periods by HOT. Especially staring MCT LWIR modules so far required sophisticated non-uniformity correction (NUC) processing to provide acceptable long term image quality while former scanning systems usually used implemented temperature references for NUC update. For a thermal imager setup with the LWIR 640x512/15μm module two-point correction with factory calibrated gain coefficients together with a new offset calibration after every cool down cycle is used. The paper will present the results of AIM's current staring single-band MCT IR-modules in MWIR or LWIR configuration especially regarding to their long term and cycle stability.

  7. Optimization of a Deep Convective Cloud Technique in Evaluating the Long-Term Radiometric Stability of MODIS Reflective Solar Bands

    NASA Technical Reports Server (NTRS)

    Mu, Qiaozhen; Wu, Aisheng; Xiong, Xiaoxiong; Doelling, David R.; Angal, Amit; Chang, Tiejun; Bhatt, Rajendra

    2017-01-01

    MODIS reflective solar bands are calibrated on-orbit using a solar diffuser and near-monthly lunar observations. To monitor the performance and effectiveness of the on-orbit calibrations, pseudo-invariant targets such as deep convective clouds (DCCs), Libya-4, and Dome-C are used to track the long-term stability of MODIS Level 1B product. However, the current MODIS operational DCC technique (DCCT) simply uses the criteria set for the 0.65- m band. We optimize several critical DCCT parameters including the 11- micrometer IR-band Brightness Temperature (BT11) threshold for DCC identification, DCC core size and uniformity to help locate DCCs at convection centers, data collection time interval, and probability distribution function (PDF) bin increment for each channel. The mode reflectances corresponding to the PDF peaks are utilized as the DCC reflectances. Results show that the BT11 threshold and time interval are most critical for the Short Wave Infrared (SWIR) bands. The Bidirectional Reflectance Distribution Function model is most effective in reducing the DCC anisotropy for the visible channels. The uniformity filters and PDF bin size have minimal impacts on the visible channels and a larger impact on the SWIR bands. The newly optimized DCCT will be used for future evaluation of MODIS on-orbit calibration by MODIS Characterization Support Team.

  8. Calibration-free optical chemical sensors

    DOEpatents

    DeGrandpre, Michael D.

    2006-04-11

    An apparatus and method for taking absorbance-based chemical measurements are described. In a specific embodiment, an indicator-based pCO2 (partial pressure of CO2) sensor displays sensor-to-sensor reproducibility and measurement stability. These qualities are achieved by: 1) renewing the sensing solution, 2) allowing the sensing solution to reach equilibrium with the analyte, and 3) calculating the response from a ratio of the indicator solution absorbances which are determined relative to a blank solution. Careful solution preparation, wavelength calibration, and stray light rejection also contribute to this calibration-free system. Three pCO2 sensors were calibrated and each had response curves which were essentially identical within the uncertainty of the calibration. Long-term laboratory and field studies showed the response had no drift over extended periods (months). The theoretical response, determined from thermodynamic characterization of the indicator solution, also predicted the observed calibration-free performance.

  9. Aquarius L-Band Microwave Radiometer: Three Years of Radiometric Performance and Systematic Effects

    NASA Technical Reports Server (NTRS)

    Piepmeier, Jeffrey R.; Hong, Liang; Pellerano, Fernando A.

    2015-01-01

    The Aquarius L-band microwave radiometer is a three-beam pushbroom instrument designed to measure sea surface salinity. Results are analyzed for performance and systematic effects over three years of operation. The thermal control system maintains tight temperature stability promoting good gain stability. The gain spectrum exhibits expected orbital variations with 1f noise appearing at longer time periods. The on-board detection and integration scheme coupled with the calibration algorithm produce antenna temperatures with NEDT 0.16 K for 1.44-s samples. Nonlinearity is characterized before launch and the derived correction is verified with cold-sky calibration data. Finally, long-term drift is discovered in all channels with 1-K amplitude and 100-day time constant. Nonetheless, it is adeptly corrected using an exponential model.

  10. An Overview of Lunar Calibration and Characterization for the EOS Terra and Aqua MODIS

    NASA Technical Reports Server (NTRS)

    Xiong, X.; Salomonson, V. V.; Sun, J.; Chiang, K.; Xiong, S.; Humphries, S.; Barnes, W.; Guenther, B.

    2004-01-01

    The Moon can be used as a stable source for Earth-observing sensors on-orbit radiometric and spatial stability monitoring in the VIS and NIR spectral regions. It can also serve as a calibration transfer vehicle among multiple sensors. Nearly identical copies of the Moderate Resolution Imaging Spectroradiometer (MODE) have been operating on-board the NASA's Earth Observing System (EOS) Terra and Aqua satellites since their launches in December 1999 and May 2002, respectively. Terra and Aqua MODIS each make observations in 36 spectral bands covering the spectral range from 0.41 to 14.5 microns and are calibrated on-orbit by a set of on-board calibrations (OBCs) including: 1) a solar diffuser (SD), 2) a solar diffuser stability monitor (SDSM), 3) a blackbody (BB), and 4) a spectro-radiometric calibration assembly (SRCA). In addition to fully utilizing the OBCs, the Moon has been used extensively by both Terra and Aqua MODIS to support their on-orbit calibration and characterization. A 4 This paper provides an overview of applications of lunar calibration and characterization from the MODIS perspective, including monitoring radiometric calibration stability for the reflective solar bands (RSBs), tracking changes of the sensors response versus scan-angle (RVS), examining the sensors spatial performance , and characterizing optical leaks and electronic crosstalk among different spectral bands and detectors. On-orbit calibration consistency between the two MODIS instruments is also addressed. Based on the existing on-orbit time series of the Terra and Aqua MODIS lunar observations, the radiometric difference between the two sensors is less than +/-1% for the RSBs. This method provides a powerful means of performing calibration comparisons among Earth-observing sensors and assures consistent data and science products for the long-term studies of climate and environmental changes.

  11. Degradation nonuniformity in the solar diffuser bidirectional reflectance distribution function.

    PubMed

    Sun, Junqiang; Chu, Mike; Wang, Menghua

    2016-08-01

    The assumption of angular dependence stability of the solar diffuser (SD) throughout degradation is critical to the on-orbit calibration of the reflective solar bands (RSBs) in many satellite sensors. Recent evidence has pointed to the contrary, and in this work, we present a thorough investigative effort into the angular dependence of the SD degradation for the Visible Infrared Imaging Radiometer Suite (VIIRS) onboard the Suomi National Polar-orbiting Partnership (SNPP) satellite and for the twin Moderate-resolution Imaging Spectroradiometer (MODIS) onboard Terra and Aqua spacecrafts. One common key step in the RSB calibration is the use of the SD degradation performance measured by an accompanying solar diffuser stability monitor (SDSM) as a valid substitute for the SD degradation factor in the direction of the RSB view. If SD degradations between these two respective directions do not maintain the same relative relationship over time, then the unmitigated use of the SDSM-measured SD degradation factor in the RSB calibration calculation will generate bias, and consequently, long-term drift in derived science products. We exploit the available history of the on-orbit calibration events to examine the response of the SDSM and the RSB detectors to the incident illumination reflecting off SD versus solar declination angle and show that the angular dependency, particularly at short wavelengths, evolves with respect to time. The generalized and the decisive conclusion is that the bidirectional reflectance distribution function (BRDF) of the SD degrades nonuniformly with respect to both incident and outgoing directions. Thus, the SDSM-based measurements provide SD degradation factors that are biased relative to the RSB view direction with respect to the SD. The analysis also reveals additional interesting phenomena, for example, the sharp behavioral change in the evolving angular dependence observed in Terra MODIS and SNPP VIIRS. For SNPP VIIRS the mitigation for this "SD degradation nonuniformity effect" with respect to angles relies on a "hybrid methodology" using lunar-based calibration to set the reliable long-term baseline. For MODIS, the use of earth targets in the major release Collection 6 to improve calibration coefficients and time-dependent response-versus-scan-angle characterization inherently averts the use of SD and its associated issues. The work further supports that having an open-close operational capability for the space view door can minimize SD degradation and its associated effects due to solar exposure, and thus provide long-term benefits for maintaining calibration and science data accuracy.

  12. Early on-orbit calibration results from Aqua MODIS

    NASA Astrophysics Data System (ADS)

    Xiong, Xiaoxiong; Barnes, William L.

    2003-04-01

    Aqua MODIS, also known as the MODIS Flight Model 1 (FM1), was launched on May 4, 2002. It opened its nadir aperture door (NAD) on June 24, 2002, beginning its Earth observing mission. In this paper, we present early results from Aqua MODIS on-orbit calibration and characterization and assess the instrument's overall performance. MODIS has 36 spectral bands located on four focal plane assemblies (FPAs). Bands 1-19, and 26 with wavelengths from 0.412 to 2.1 microns are the reflective solar bands (RSB) that are calibrated on-orbit by a solar diffuser (SD). The degradation of the SD is tracked using a solar diffuser stability monitor (SDSM). The bands 20-25, and 27-36 with wavelengths from 3.75 to 14.5 microns are the thermal emissive bands (TEB) that are calibrated on-orbit by a blackbody (BB). Early results indicate that the on-orbit performance has been in good agreement with the predications determined from pre-launch measurements. Except for band 21, the low gain fire band, band 6, known to have some inoperable detectors from pre-launch characterization, and one noisy detector in band 36, all of the detectors' noise characterizations are within their specifications. Examples of the sensor's short-term and limited long-term responses in both TEB and RSB will be provided to illustrate the sensor's on-orbit stability. In addition, we will show some of the improvements that Aqua MODIS made over its predecessor, Terra MODIS (Protoflight Model - PFM), such as removal of the optical leak into the long-wave infrared (LWIR) photoconductive (PC) bands and reduction of electronic crosstalk and out-of-band (OOB) thermal leak into the short-wave infrared (SWIR) bands.

  13. The Optical Field Angle Distortion Calibration of HST Fine Guidance Sensors 1R and 3

    NASA Technical Reports Server (NTRS)

    McArthur, B.; Benedict, G. F.; Jefferys, W. H.; Nelan, E.

    2006-01-01

    To date five OFAD (Optical Field Angle Distortion) calibrations have been performed with a star field in M35, four on FGS3 and one on FGS1, all analyzed by the Astrometry Science Team. We have recently completed an improved FGS1R OFAD calibration. The ongoing Long Term Stability Tests have also been analyzed and incorporated into these calibrations, which are time-dependent due to on-orbit changes in the FGS. Descriptions of these tests and the results of our OFAD modeling are given. Because all OFAD calibrations use the same star field, we calibrate FGS 1 and FGS 3 simultaneously. This increases the precision of our input catalog,resulting in an improvement in both the FGS 1 and FGS 3 calibrations. A redetermination of the proper motions,using 12 years of HST data has significantly improved our calibration. Residuals to our OFAD modeling indicate that FGS 1 will provide astrometry superior to FGS 3 by approx. 20%. Past and future FGS astrometric science supported by these calibrations is briefly reviewed.

  14. On-Orbit Calibration and Performance of Aqua MODIS Reflective Solar Bands

    NASA Technical Reports Server (NTRS)

    Xiong, Xiaoxiong; Sun, Junqiang; Xie, Xiaobo; Barnes, William; Salomonson, Vincent

    2009-01-01

    Aqua MODIS has successfully operated on-orbit for more than 6 years since its launch in May 2002, continuously making global observations and improving studies of changes in the Earth's climate and environment. 20 of the 36 MODIS spectral bands, covering wavelengths from 0.41 to 2.2 microns, are the reflective solar bands (RSB). They are calibrated on-orbit using an on-board solar diffuser (SD) and a solar diffuser stability monitor (SDSM). In addition, regularly scheduled lunar observations are made to track the RSB calibration stability. This paper presents Aqua MODIS RSB on-orbit calibration and characterization activities, methodologies, and performance. Included in this study are characterizations of detector signal-to-noise ratio (SNR), short-term stability, and long-term response change. Spectral wavelength dependent degradation of the SD bidirectional reflectance factor (BRF) and scan mirror reflectance, which also varies with angle of incidence (AOI), are examined. On-orbit results show that Aqua MODIS onboard calibrators have performed well, enabling accurate calibration coefficients to be derived and updated for the Level 1B (L1B) production and assuring high quality science data products to be continuously generated and distributed. Since launch, the short-term response, on a scan-by-scan basis, has remained extremely stable for most RSB detectors. With the exception of band 6, there have been no new RSB noisy or inoperable detectors. Like its predecessor, Terra MODIS, launched in December 1999, the Aqua MODIS visible (VIS) spectral bands have experienced relatively large changes, with an annual response decrease (mirror side 1) of 3.6% for band 8 at 0.412 microns, 2.3% for band 9 at 0.443 microns, 1.6% for band 3 at 0.469 microns, and 1.2% for band 10 at 0.488 microns. For other RSB bands with wavelengths greater than 0.5 microns, the annual response changes are typically less than 0.5%. In general, Aqua MODIS optics degradation is smaller than Terra MODIS and the mirror side differences are much smaller. Overall, Aqua MODIS RSB on-orbit performance is better than Terra MODIS.

  15. Assessment of MODIS On-Orbit Calibration Using a Deep Convective Cloud Technique

    NASA Technical Reports Server (NTRS)

    Mu, Qiaozhen; Wu, Aisheng; Chang, Tiejun; Angal, Amit; Link, Daniel; Xiong, Xiaoxiong; Doelling, David R.; Bhatt, Rajendra

    2016-01-01

    The MODerate Resolution Imaging Spectroradiometer (MODIS) sensors onboard Terra and Aqua satellites are calibrated on-orbit with a solar diffuser (SD) for the reflective solar bands (RSB). The MODIS sensors are operating beyond their designed lifetime and hence present a major challenge to maintain the calibration accuracy. The degradation of the onboard SD is tracked by a solar diffuser stability monitor (SDSM) over a wavelength range from 0.41 to 0.94 micrometers. Therefore, any degradation of the SD beyond 0.94 micrometers cannot be captured by the SDSM. The uncharacterized degradation at wavelengths beyond this limit could adversely affect the Level 1B (L1B) product. To reduce the calibration uncertainties caused by the SD degradation, invariant Earth-scene targets are used to monitor and calibrate the MODIS L1B product. The use of deep convective clouds (DCCs) is one such method and particularly significant for the short-wave infrared (SWIR) bands in assessing their long-term calibration stability. In this study, we use the DCC technique to assess the performance of the Terra and Aqua MODIS Collection-6 L1B for RSB 1 3- 7, and 26, with spectral coverage from 0.47 to 2.13 micrometers. Results show relatively stable trends in Terra and Aqua MODIS reflectance for most bands. Careful attention needs to be paid to Aqua band 1, Terra bands 3 and 26 as their trends are larger than 1% during the study time period. We check the feasibility of using the DCC technique to assess the stability in MODIS bands 17-19. The assessment test on response versus scan angle (RVS) calibration shows substantial trend difference for Aqua band 1between different angles of incidence (AOIs). The DCC technique can be used to improve the RVS calibration in the future.

  16. SeaWiFS long-term solar diffuser reflectance trend analysis

    NASA Astrophysics Data System (ADS)

    Eplee, Robert E., Jr.; Patt, Frederick S.; Barnes, Robert A.; McClain, Charles R.

    2006-08-01

    The NASA Ocean Biology Processing Group's Calibration and Validation (Cal/Val) Team implemented daily solar calibrations of SeaWiFS to look for step-function changes in the instrument response and has used these calibrations to supplement the monthly lunar calibrations in monitoring the radiometric stability of SeaWiFS during its first year of on-orbit operations. The Team has undertaken an analysis of the mission-long solar calibration time series, with the lunar-derived radiometric corrections over time applied, to assess the long-term degradation of the solar diffuser reflectance over nine years on orbit. The SeaWiFS diffuser is an aluminum plate coated with YB71 paint. The bidirectional reflectance distribution function of the diffuser was not fully characterized before launch, so the Cal/Val Team has implemented a regression of the solar incidence angles and the drift in the node of the satellite's orbit against the diffuser time series to correct for solar incidence angle effects. An exponential function with a time constant of 200 days yields the best fit to the diffuser time series. The decrease in diffuser reflectance over the mission is wavelength-dependent, ranging from 9% in the blue (412 nm) to 5% in the red and near infrared (670-865 nm). The degradation of diffuser reflctance is similar to that observed for SeaWiFS radiometric response itself from lunar calibration time series for bands 1-5 (412-555 nm), though the magnitude of the change is four times larger for the diffuser. Evidently, the same optical degradation process has affected both the telescope optics and the solar diffuser in the blue and green. The Cal/Val Team has developed a methodology for computing the signal-to-noise ratio (SNR) for SeaWiFS on orbit from the diffuser time series. The on-orbit change in the SNR for each band over the nine-year mission is less than 7%. The on-orbit performance of the SeaWiFS solar diffuser should offer insight into the long-term on-orbit performance of solar diffusers on other instruments, such as MODIS, VIIRS, and ABI.

  17. Use of the Moon for spacecraft calibration over 350-2500 nm

    USGS Publications Warehouse

    Kieffer, H.H.; Anderson, J.M.

    1998-01-01

    The Moon is the only natural object outside the Earth's atmosphere that is within the dynamic range of most imaging instruments on Earth-orbiting spacecraft. The excellent photometric stability of the Lunar surface will allow its use as a long-term instrument calibration source once the dependence of Lunar spectral radiance on phase and libration angles are well characterized. A program to provide this characterization is underway. Observations are being made in 23 bands within 350-950 nm, 7 of which correspond closely with spacecraft instrument bands. Observations in nine bands within 950-2500 nm began recently. Although at this time the absolute Lunar radiance model is preliminary and uncertainties are larger than most instrument calibration goals, changes in spacecraft instrument sensitivity can be precisely monitored and absolute calibration can be applied retroactively as the accuracy of the Lunar spectral radiance model improves. Several space-based imaging systems have already begun using the Moon for calibration and the EOS AM-1 platform will make periodic attitude maneuvers for Lunar and space calibration.

  18. A color management system for multi-colored LED lighting

    NASA Astrophysics Data System (ADS)

    Chakrabarti, Maumita; Thorseth, Anders; Jepsen, Jørgen; Corell, Dennis D.; Dam-Hansen, Carsten

    2015-09-01

    A new color control system is described and implemented for a five-color LED light engine, covering a wide white gamut. The system combines a new way of using pre-calibrated lookup tables and a rule-based optimization of chromaticity distance from the Planckian locus with a calibrated color sensor. The color sensor monitors the chromaticity of the mixed light providing the correction factor for the current driver by using the generated lookup table. The long term stability and accuracy of the system will be experimentally investigated with target tolerance within a circle radius of 0.0013 in the uniform chromaticity diagram (CIE1976).

  19. An integrated approach to monitoring the calibration stability of operational dual-polarization radars

    DOE PAGES

    Vaccarono, Mattia; Bechini, Renzo; Chandrasekar, Chandra V.; ...

    2016-11-08

    The stability of weather radar calibration is a mandatory aspect for quantitative applications, such as rainfall estimation, short-term weather prediction and initialization of numerical atmospheric and hydrological models. Over the years, calibration monitoring techniques based on external sources have been developed, specifically calibration using the Sun and calibration based on ground clutter returns. In this paper, these two techniques are integrated and complemented with a self-consistency procedure and an intercalibration technique. The aim of the integrated approach is to implement a robust method for online monitoring, able to detect significant changes in the radar calibration. The physical consistency of polarimetricmore » radar observables is exploited using the self-consistency approach, based on the expected correspondence between dual-polarization power and phase measurements in rain. This technique allows a reference absolute value to be provided for the radar calibration, from which eventual deviations may be detected using the other procedures. In particular, the ground clutter calibration is implemented on both polarization channels (horizontal and vertical) for each radar scan, allowing the polarimetric variables to be monitored and hardware failures to promptly be recognized. The Sun calibration allows monitoring the calibration and sensitivity of the radar receiver, in addition to the antenna pointing accuracy. It is applied using observations collected during the standard operational scans but requires long integration times (several days) in order to accumulate a sufficient amount of useful data. Finally, an intercalibration technique is developed and performed to compare colocated measurements collected in rain by two radars in overlapping regions. The integrated approach is performed on the C-band weather radar network in northwestern Italy, during July–October 2014. The set of methods considered appears suitable to establish an online tool to monitor the stability of the radar calibration with an accuracy of about 2 dB. In conclusion, this is considered adequate to automatically detect any unexpected change in the radar system requiring further data analysis or on-site measurements.« less

  20. Experiment Pointing Subsystems (EPS) requirements for Spacelab missions

    NASA Technical Reports Server (NTRS)

    Nein, M. E.; Nicaise, P. D.

    1975-01-01

    The goal of the experiment pointing subsystems (EPS) is to accommodate a broad spectrum of instrument types by providing a number of stability and control functions that greatly exceed the capability of the shuttle. These functions include target acquisition, target tracking through wide gimbal ranges, stabilization, simultaneous pointing to one or more targets, instrument rastering, and on-orbit calibration. The experiments will vary widely in size, weight, geometry, and instrument types, and many have not been completely defined. This great diversity of requirements reflects the long term plans of the user community and establishes challenging performance requirements for the EPS.

  1. Inter-laboratory comparison of elemental analysis and gas chromatography combustion isotope ratio mass spectrometry (GC-C-IRMS). Part I: delta13C measurements of selected compounds for the development of an isotopic Grob-test.

    PubMed

    Serra, F; Janeiro, A; Calderone, G; Rojas, J M Moreno; Rhodes, C; Gonthier, L A; Martin, F; Lees, M; Mosandl, A; Sewenig, S; Hener, U; Henriques, B; Ramalho, L; Reniero, F; Teixeira, A J; Guillou, C

    2007-03-01

    This study was directed towards investigating suitable compounds to be used as stable isotope reference materials for gas chromatography combustion isotope ratio mass spectrometry (GC-C-IRMS) calibration. Several compounds were selected from those used in the 'Grob-test' mixture. Oxygen- and nitrogen-containing substances were added to these compounds to allow the mixture to be used as a possible multi-isotopic calibration tool for 2H/1H, 13C/12C, 15N/14N and 18O/16O ratio determinations. In this paper we present the results of delta13C measurements performed by the consortium of the five laboratories taking part in this inter-calibration exercise. All the compounds were individually assessed for homogeneity, short-term stability and long-term stability by means of EA-IRMS, as required by the bureau communitaire de reference (BCR) Guide for Production of Certified Reference Materials. The results were compared then with the GC-C-IRMS measurements using both polar and non-polar columns, and the final mixture of selected compounds underwent a further certification exercise assessing limits of accuracy and reproducibility under specified GC-C-IRMS conditions. Copyright 2007 John Wiley & Sons, Ltd.

  2. Direct calibration of a reference standard against the air kerma strength primary standard, at 192Ir HDR energy.

    PubMed

    Rajan, K N Govinda; Selvam, T Palani; Bhatt, B C; Vijayam, M; Patki, V S; Vinatha; Pendse, A M; Kannan, V

    2002-04-07

    The primary standard of low air kerma rate sources or beams, maintained at the Radiological Standards Laboratory (RSL) of the Bhabha Atomic Research Centre (BARC), is a 60 cm3 spherical graphite ionization chamber. A 192Ir HDR source was standardized at the hospital site in units of air kerma strength (AKS) using this primary standard. A 400 cm3 bakelite chamber, functioning as a reference standard at the RSL for a long period, at low air kerma rates (compared to external beam dose rates), was calibrated against the primary standard. It was seen that the primary standard and the reference standard, both being of low Z, showed roughly the same scatter response and yielded the same calibration factor for the 400 cm3 reference chamber, with or without room scatter. However, any likelihood of change in the reference chamber calibration factor would necessitate the re-transport of the primary standard to the hospital site for re-calibration. Frequent transport of the primary standard can affect the long-term stability of the primary standard, due to its movement or other extraneous causes. The calibration of the reference standard against the primary standard at the RSL, for an industrial type 192Ir source maintained at the laboratory, showed excellent agreement with the hospital calibration, making it possible to check the reference chamber calibration at RSL itself. Further calibration procedures have been developed to offer traceable calibration of the hospital well ionization chambers.

  3. Long-Term Stability of the NIST Standard Ultrasonic Source.

    PubMed

    Fick, Steven E

    2008-01-01

    The National Institute of Standards and Technology (NIST) Standard Ultrasonic Source (SUS) is a system comprising a transducer capable of output power levels up to 1 W at multiple frequencies between 1 MHz and 30 MHz, and an electrical impedance-matching network that allows the system to be driven by a conventional 50 Ω rf (radio-frequency) source. It is designed to allow interlaboratory replication of ultrasonic power levels with high accuracy using inexpensive readily available ancillary equipment. The SUS was offered for sale for 14 years (1985 to 1999). Each system was furnished with data for the set of calibration points (combinations of power level and frequency) specified by the customer. Of the systems that had been ordered with some calibration points in common, three were returned more than once to NIST for recalibration. Another system retained at NIST has been recalibrated periodically since 1984. The collective data for these systems comprise 9 calibration points and 102 measurements spanning a 17 year interval ending in 2001, the last year NIST ultrasonic power measurement services were available to the public. These data have been analyzed to compare variations in output power with frequency, power level, and time elapsed since the first calibration. The results verify the claim, made in the instruction sheet furnished with every SUS, that "long-term drift, if any, in the calibration of NIST Standard Sources is insignificant compared to the uncertainties associated with a single measurement of ultrasonic power by any method available at NIST."

  4. The Aquarius Ocean Salinity Mission High Stability L-band Radiometer

    NASA Technical Reports Server (NTRS)

    Pellerano, Fernando A.; Piepmeier, Jeffrey; Triesky, Michael; Horgan, Kevin; Forgione, Joshua; Caldwell, James; Wilson, William J.; Yueh, Simon; Spencer, Michael; McWatters, Dalia; hide

    2006-01-01

    The NASA Earth Science System Pathfinder (ESSP) mission Aquarius, will measure global ocean surface salinity with approx.120 km spatial resolution every 7-days with an average monthly salinity accuracy of 0.2 psu (parts per thousand). This requires an L-band low-noise radiometer with the long-term calibration stability of less than or equal to 0.15 K over 7 days. The instrument utilizes a push-broom configuration which makes it impractical to use a traditional warm load and cold plate in front of the feedhorns. Therefore, to achieve the necessary performance Aquarius utilizes a Dicke radiometer with noise injection to perform a warm - hot calibration. The radiometer sequence between antenna, Dicke load, and noise diode has been optimized to maximize antenna observations and therefore minimize NEDT. This is possible due the ability to thermally control the radiometer electronics and front-end components to 0.1 Crms over 7 days.

  5. Navy Calibration/Validation Protocols and Procedures for Visible and Thermal Satellites: Preparing for NPOESS

    DTIC Science & Technology

    2007-05-01

    difficult but it determines the long-term stability of the sensor. This step includes sensor drift ( spectral response) and spectral (channel...and Navy products using high spectral resolution satellites. This program (Hyperspectral 34 Characterization of the Coastal Zone) is a core NRLSSC...absorption and total attenuation) the standard accepted instrument is the WetLab’s Inc., ac-9, with a higher resolution spectral instrument in final

  6. On-orbit stability and performance of the Clouds and Earth's Radiant Energy System (CERES) instrument sensors onboard the Aqua and Terra Spacecraft

    NASA Astrophysics Data System (ADS)

    Shankar, Mohan; Priestley, Kory; Smith, Nitchie; Thomas, Susan; Walikainen, Dale

    2014-09-01

    The Clouds and Earth's Radiant Energy System (CERES) instruments onboard the Terra and Aqua spacecraft are part of the NASA Earth Observing System (EOS) constellation to make long-term observations of the earth. CERES measures the earth-reflected shortwave energy as well as the earth-emitted thermal energy, which are two components of the earth's radiation energy budget. These measurements are made by five instruments- Flight Models (FM) 1 and 2 onboard Terra, FMs 3 and 4 onboard Aqua and FM5 onboard Suomi NPP. Each instrument comprises three sensors that measure the radiances in different wavelength bands- a shortwave sensor that measures in the 0.3 to 5 micron band, a total sensor that measures all the incident energy (0.3-200 microns) and a window sensor that measures the water-vapor window region of 8 to 12 microns. The stability of the sensors is monitored through on-orbit calibration and validation activities. On-orbit calibration is carried out using the Internal Calibration Module (ICM) that consists of a tungsten lamp, blackbodies, and a solar diffuser known as the Mirror Attenuator Mosaic (MAM). The ICM calibration provides information about the stability of the sensors' broadband radiometric gains on-orbit. Several validation studies are conducted in order to monitor the behavior of the instruments in various spectral bands. The CERES Edition-4 data products for FM1-FM4 incorporate the latest corrections to the sensor responses using the calibration techniques. In this paper, we present the on-orbit performance stability as well as some validation studies used in deriving the CERES Edition-4 data products from all four instruments.

  7. An overview of sensor calibration inter-comparison and applications

    USGS Publications Warehouse

    Xiong, Xiaoxiong; Cao, Changyong; Chander, Gyanesh

    2010-01-01

    Long-term climate data records (CDR) are often constructed using observations made by multiple Earth observing sensors over a broad range of spectra and a large scale in both time and space. These sensors can be of the same or different types operated on the same or different platforms. They can be developed and built with different technologies and are likely operated over different time spans. It has been known that the uncertainty of climate models and data records depends not only on the calibration quality (accuracy and stability) of individual sensors, but also on their calibration consistency across instruments and platforms. Therefore, sensor calibration inter-comparison and validation have become increasingly demanding and will continue to play an important role for a better understanding of the science product quality. This paper provides an overview of different methodologies, which have been successfully applied for sensor calibration inter-comparison. Specific examples using different sensors, including MODIS, AVHRR, and ETM+, are presented to illustrate the implementation of these methodologies.

  8. A long-term validation of the modernised DC-ARC-OES solid-sample method.

    PubMed

    Flórián, K; Hassler, J; Förster, O

    2001-12-01

    The validation procedure based on ISO 17025 standard has been used to study and illustrate both the longterm stability of the calibration process of the DC-ARC solid sample spectrometric method and the main validation criteria of the method. In the calculation of the validation characteristics depending on the linearity(calibration), also the fulfilment of predetermining criteria such as normality and homoscedasticity was checked. In order to decide whether there are any trends in the time-variation of the analytical signal or not, also the Neumann test of trend was applied and evaluated. Finally, a comparison with similar validation data of the ETV-ICP-OES method was carried out.

  9. Calibrating 15 years of GOLF data

    NASA Astrophysics Data System (ADS)

    Davies, G. R.; García, R. A.

    2011-12-01

    The GOLF resonant scattering spectrophotometer aboard SoHO has now provided 15 years of continuous high precision Sun-as-a-star radial-velocity measurements. This length of time series provides very high resolution in the frequency domain and is combined with very good long-term instrumental stability. These are the requirements for measuring the low-l low-frequency global oscillations of the Sun that will unlock the secrets of the solar core. However, before the scientifically interesting gravity and mixed modes of oscillation fully reveal themselves, a correction and calibration of the whole data set is required. Here we present work towards producing a 15 year GOLF data set corrected for instrumental ageing and thermal variation.

  10. Improved luminosity determination in pp collisions at $$\\sqrt {s} = 7\\ \\mathrm{TeV}$$ using the ATLAS detector at the LHC

    DOE PAGES

    Aad, G.; Abajyan, T.; Abbott, B.; ...

    2013-08-14

    The luminosity calibration for the ATLAS detector at the LHC during pp collisions at √s = 7 TeV in 2010 and 2011 is presented. Evaluation of the luminosity scale is performed using several luminosity-sensitive detectors, and comparisons are made of the long-term stability and accuracy of this calibration applied to the pp collisions at √s = 7 TeV. A luminosity uncertainty of δL/L= ± 3.5 % is obtained for the 47 pb -1 of data delivered to ATLAS in 2010, and an uncertainty of δL/L= ± 1.8 % is obtained for the 5.5 fb -1 delivered in 2011.

  11. Utilizing the Precessing Orbit of TRMM to Produce Hourly Corrections of Geostationary Infrared Imager Data with the VIRS Sensor

    NASA Technical Reports Server (NTRS)

    Scarino, Benjamin; Doelling, David R.; Haney, Conor; Bedka, Kristopher; Minnis, Patrick; Gopalan, Arun; Bhatt, Rajendra

    2017-01-01

    Accurate characterization of the Earth's radiant energy is critical for many climate monitoring and weather forecasting applications. For example, groups at the NASA Langley Research Center rely on stable visible- and infrared-channel calibrations in order to understand the temporal/spatial distribution of hazardous storms, as determined from an automated overshooting convective top detection algorithm. Therefore, in order to facilitate reliable, climate-quality retrievals, it is important that consistent calibration coefficients across satellite platforms are made available to the remote sensing community, and that calibration anomalies are recognized and mitigated. One such anomaly is the infrared imager brightness temperature (BT) drift that occurs for some Geostationary Earth Orbit satellite (GEOsat) instruments near local midnight. Currently the Global Space-Based Inter-Calibration System (GSICS) community uses the hyperspectral Infrared Atmospheric Sounding Interferometer (IASI) sensor as a common reference to uniformly calibrate GEOsat IR imagers. However, the combination of IASI, which has a 21:30 local equator crossing time (LECT), and hyperspectral Atmospheric Infrared Sounder (AIRS; 01:30 LECT) observations are unable to completely resolve the GEOsat midnight BT bias. The precessing orbit of the Tropical Rainfall Measuring Mission (TRMM) Visible and Infrared Scanner (VIRS), however, allows sampling of all local hours every 46 days. Thus, VIRS has the capability to quantify the BT midnight effect observed in concurrent GEOsat imagers. First, the VIRS IR measurements are evaluated for long-term temporal stability between 2002 and 2012 by inter-calibrating with Aqua-MODIS. Second, the VIRS IR measurements are assessed for diurnal stability by inter-calibrating with Meteosat-9 (Met-9), a spin-stabilized GEOsat imager that does not manifest any diurnal dependency. In this case, the Met-9 IR imager is first adjusted with the official GSICS calibration coefficients. Then VIRS is used as a diurnal calibration reference transfer to produce hourly corrections of GEOsat IR imager BT. For the 9 three-axis stabilized GEO imagers concurrent with VIRS, the midnight effect increased the BT on average by 0.5 K (11 microns) and 0.4 K (12 microns), with a peak at approx.01:00 local time. As expected, the spin-stabilized GEOsats revealed a smaller diurnal temperature cycle (mostly < 0.2 K) with inconsistent peak hours.

  12. Utilizing the precessing orbit of TRMM to produce hourly corrections of geostationary infrared imager data with the VIRS sensor

    NASA Astrophysics Data System (ADS)

    Scarino, Benjamin; Doelling, David R.; Haney, Conor; Bedka, Kristopher; Minnis, Patrick; Gopalan, Arun; Bhatt, Rajendra

    2017-08-01

    Accurate characterization of the Earth's radiant energy is critical for many climate monitoring and weather forecasting applications. For example, groups at the NASA Langley Research Center rely on stable visible- and infraredchannel calibrations in order to understand the temporal/spatial distribution of hazardous storms, as determined from an automated overshooting convective top detection algorithm. Therefore, in order to facilitate reliable, climate-quality retrievals, it is important that consistent calibration coefficients across satellite platforms are made available to the remote sensing community, and that calibration anomalies are recognized and mitigated. One such anomaly is the infrared imager brightness temperature (BT) drift that occurs for some Geostationary Earth Orbit satellite (GEOsat) instruments near local midnight. Currently the Global Space-Based Inter-Calibration System (GSICS) community uses the hyperspectral Infrared Atmospheric Sounding Interferometer (IASI) sensor as a common reference to uniformly calibrate GEOsat IR imagers. However, the combination of IASI, which has a 21:30 local equator crossing time (LECT), and hyperspectral Atmospheric Infrared Sounder (AIRS; 01:30 LECT) observations are unable to completely resolve the GEOsat midnight BT bias. The precessing orbit of the Tropical Rainfall Measuring Mission (TRMM) Visible and Infrared Scanner (VIRS), however, allows sampling of all local hours every 46 days. Thus, VIRS has the capability to quantify the BT midnight effect observed in concurrent GEOsat imagers. First, the VIRS IR measurements are evaluated for long-term temporal stability between 2002 and 2012 by inter-calibrating with Aqua-MODIS. Second, the VIRS IR measurements are assessed for diurnal stability by inter-calibrating with Meteosat-9 (Met-9), a spin-stabilized GEOsat imager that does not manifest any diurnal dependency. In this case, the Met-9 IR imager is first adjusted with the official GSICS calibration coefficients. Then VIRS is used as a diurnal calibration reference transfer to produce hourly corrections of GEOsat IR imager BT. For the 9 three-axis stabilized GEO imagers concurrent with VIRS, the midnight effect increased the BT on average by 0.5 K (11 μm) and 0.4 K (12 μm), with a peak at 01:00 local time. As expected, the spin-stabilized GEOsats revealed a smaller diurnal temperature cycle (mostly < 0.2 K) with inconsistent peak hours.

  13. OPSATCOM Field Measurements. Volume II. Supplemental Information

    DTIC Science & Technology

    1976-06-01

    amplitude is to be expected. Long-term stability is determined by how well the output control system compensates for changes in the output of the flashlamp...a remotely processed S-20 photocathode. The responsivity of tile photocathode was measured at 0,039 A/W for a quantum efficiency of approximately 9...gives operator control over thle size of, thle array as well , allowinig sia 11r fraimes to be taken tmnic rap idly. 2- 25 CALIBRATION The purpose of

  14. Vicarious Calibration of EO-1 Hyperion

    NASA Technical Reports Server (NTRS)

    McCorkel, Joel; Thome, Kurt; Lawrence, Ong

    2012-01-01

    The Hyperion imaging spectrometer on the Earth Observing-1 satellite is the first high-spatial resolution imaging spectrometer to routinely acquire science-grade data from orbit. Data gathered with this instrument needs to be quantitative and accurate in order to derive meaningful information about ecosystem properties and processes. Also, comprehensive and long-term ecological studies require these data to be comparable over time, between coexisting sensors and between generations of follow-on sensors. One method to assess the radiometric calibration is the reflectance-based approach, a common technique used for several other earth science sensors covering similar spectral regions. This work presents results of radiometric calibration of Hyperion based on the reflectance-based approach of vicarious calibration implemented by University of Arizona during 2001 2005. These results show repeatability to the 2% level and accuracy on the 3 5% level for spectral regions not affected by strong atmospheric absorption. Knowledge of the stability of the Hyperion calibration from moon observations allows for an average absolute calibration based on the reflectance-based results to be determined and applicable for the lifetime of Hyperion.

  15. A large-scale, long-term study of scale drift: The micro view and the macro view

    NASA Astrophysics Data System (ADS)

    He, W.; Li, S.; Kingsbury, G. G.

    2016-11-01

    The development of measurement scales for use across years and grades in educational settings provides unique challenges, as instructional approaches, instructional materials, and content standards all change periodically. This study examined the measurement stability of a set of Rasch measurement scales that have been in place for almost 40 years. In order to investigate the stability of these scales, item responses were collected from a large set of students who took operational adaptive tests using items calibrated to the measurement scales. For the four scales that were examined, item samples ranged from 2183 to 7923 items. Each item was administered to at least 500 students in each grade level, resulting in approximately 3000 responses per item. Stability was examined at the micro level analysing change in item parameter estimates that have occurred since the items were first calibrated. It was also examined at the macro level, involving groups of items and overall test scores for students. Results indicated that individual items had changes in their parameter estimates, which require further analysis and possible recalibration. At the same time, the results at the total score level indicate substantial stability in the measurement scales over the span of their use.

  16. MODIS On-Board Blackbody Function and Performance

    NASA Technical Reports Server (NTRS)

    Xiaoxiong, Xiong; Wenny, Brian N.; Wu, Aisheng; Barnes, William

    2009-01-01

    Two MODIS instruments are currently in orbit, making continuous global observations in visible to long-wave infrared wavelengths. Compared to heritage sensors, MODIS was built with an advanced set of on-board calibrators, providing sensor radiometric, spectral, and spatial calibration and characterization during on-orbit operation. For the thermal emissive bands (TEB) with wavelengths from 3.7 m to 14.4 m, a v-grooved blackbody (BB) is used as the primary calibration source. The BB temperature is accurately measured each scan (1.47s) using a set of 12 temperature sensors traceable to NIST temperature standards. The onboard BB is nominally operated at a fixed temperature, 290K for Terra MODIS and 285K for Aqua MODIS, to compute the TEB linear calibration coefficients. Periodically, its temperature is varied from 270K (instrument ambient) to 315K in order to evaluate and update the nonlinear calibration coefficients. This paper describes MODIS on-board BB functions with emphasis on on-orbit operation and performance. It examines the BB temperature uncertainties under different operational conditions and their impact on TEB calibration and data product quality. The temperature uniformity of the BB is also evaluated using TEB detector responses at different operating temperatures. On-orbit results demonstrate excellent short-term and long-term stability for both the Terra and Aqua MODIS on-board BB. The on-orbit BB temperature uncertainty is estimated to be 10mK for Terra MODIS at 290K and 5mK for Aqua MODIS at 285K, thus meeting the TEB design specifications. In addition, there has been no measurable BB temperature drift over the entire mission of both Terra and Aqua MODIS.

  17. Development and field testing of a rapid and ultra-stable atmospheric carbon dioxide spectrometer

    DOE PAGES

    Xiang, B.; Nelson, D. D.; McManus, J. B.; ...

    2014-08-05

    We present field test results for a new spectroscopic instrument to measure atmospheric carbon dioxide (CO 2) with high precision (0.02 ppm at 1 Hz) and demonstrate high stability (within 0.1 ppm over more than 8 months), without the need for hourly, daily, or even monthly calibration against high-pressure gas cylinders. The technical novelty of this instrument ( ABsolute Carbon dioxide, ABC) is the spectral null method using an internal quartz reference cell with known CO 2 column density. Compared to a previously described prototype, the field instrument has better stability and benefits from more precise thermal control of themore » optics and more accurate pressure measurements in the sample cell (at the mTorr level). The instrument has been deployed at a long-term ecological research site (the Harvard Forest, USA), where it has measured for eight months without on-site calibration and with minimal maintenance, showing drift bounds of less than 0.1 ppm. Field measurements agree well with those of another commercially available cavity ring-down CO 2 instrument (Picarro G2301) run with a standard calibration protocol. This field test demonstrates that ABC is capable of performing high-accuracy, unattended, continuous field measurements with minimal use of calibration cylinders.« less

  18. Deformation Monitoring of the Submillimetric UPV Calibration Baseline

    NASA Astrophysics Data System (ADS)

    García-Asenjo, Luis; Baselga, Sergio; Garrigues, Pascual

    2017-06-01

    A 330 m calibration baseline was established at the Universitat Politècnica de València (UPV) in 2007. Absolute scale was subsequently transferred in 2012 from the Nummela Standard Baseline in Finland and distances between pillars were determined with uncertainties ranging from 0.1 mm to 0.3 mm. In order to assess the long-term stability of the baseline three field campaigns were carried out from 2013 to 2015 in a co-operative effort with the Universidad Complutense de Madrid (UCM), which provided the only Mekometer ME5000 distance meter available in Spain. Since the application of the ISO17123-4 full procedure did not suffice to come to a definite conclusion about possible displacements of the pillars, we opted for the traditional geodetic network approach. This approach had to be adapted to the case at hand in order to deal with problems such as the geometric weakness inherent to calibration baselines and scale uncertainty derived from both the use of different instruments and the high correlation between the meteorological correction and scale determination. Additionally, the so-called the maximum number of stable points method was also tested. In this contribution it is described the process followed to assess the stability of the UPV submillimetric calibration baseline during the period of time from 2012 to 2015.

  19. Development and field testing of a rapid and ultra-stable atmospheric carbon dioxide spectrometer

    NASA Astrophysics Data System (ADS)

    Xiang, B.; Nelson, D. D.; McManus, J. B.; Zahniser, M. S.; Wehr, R.; Wofsy, S. C.

    2014-08-01

    We present field test results for a new spectroscopic instrument to measure atmospheric carbon dioxide (CO2) with high precision (0.02 ppm at 1 Hz) and demonstrate high stability (within 0.1 ppm over more than 8 months), without the need for hourly, daily, or even monthly calibration against high-pressure gas cylinders. The technical novelty of this instrument (ABsolute Carbon dioxide, ABC) is the spectral null method using an internal quartz reference cell with known CO2 column density. Compared to a previously described prototype, the field instrument has better stability and benefits from more precise thermal control of the optics and more accurate pressure measurements in the sample cell (at the mTorr level). The instrument has been deployed at a long-term ecological research site (the Harvard Forest, USA), where it has measured for eight months without on-site calibration and with minimal maintenance, showing drift bounds of less than 0.1 ppm. Field measurements agree well with those of another commercially available cavity ring-down CO2 instrument (Picarro G2301) run with a standard calibration protocol. This field test demonstrates that ABC is capable of performing high-accuracy, unattended, continuous field measurements with minimal use of calibration cylinders.

  20. Ion chamber absorbed dose calibration coefficients, N{sub D,w}, measured at ADCLs: Distribution analysis and stability

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Muir, B. R., E-mail: Bryan.Muir@nrc-cnrc.gc.ca

    2015-04-15

    Purpose: To analyze absorbed dose calibration coefficients, N{sub D,w}, measured at accredited dosimetry calibration laboratories (ADCLs) for client ionization chambers to study (i) variability among N{sub D,w} coefficients for chambers of the same type calibrated at each ADCL to investigate ion chamber volume fluctuations and chamber manufacturing tolerances; (ii) equivalency of ion chamber calibration coefficients measured at different ADCLs by intercomparing N{sub D,w} coefficients for chambers of the same type; and (iii) the long-term stability of N{sub D,w} coefficients for different chamber types by investigating repeated chamber calibrations. Methods: Large samples of N{sub D,w} coefficients for several chamber types measuredmore » over the time period between 1998 and 2014 were obtained from the three ADCLs operating in the United States. These are analyzed using various graphical and numerical statistical tests for the four chamber types with the largest samples of calibration coefficients to investigate (i) and (ii) above. Ratios of calibration coefficients for the same chamber, typically obtained two years apart, are calculated to investigate (iii) above and chambers with standard deviations of old/new ratios less than 0.3% meet stability requirements for accurate reference dosimetry recommended in dosimetry protocols. Results: It is found that N{sub D,w} coefficients for a given chamber type compared among different ADCLs may arise from differing probability distributions potentially due to slight differences in calibration procedures and/or the transfer of the primary standard. However, average N{sub D,w} coefficients from different ADCLs for given chamber types are very close with percent differences generally less than 0.2% for Farmer-type chambers and are well within reported uncertainties. Conclusions: The close agreement among calibrations performed at different ADCLs reaffirms the Calibration Laboratory Accreditation Subcommittee process of ensuring ADCL conformance with National Institute of Standards and Technology standards. This study shows that N{sub D,w} coefficients measured at different ADCLs are statistically equivalent, especially considering reasonable uncertainties. This analysis of N{sub D,w} coefficients also allows identification of chamber types that can be considered stable enough for accurate reference dosimetry.« less

  1. Reproducibility of total ozone column monitoring by the Arosa Brewer spectrophotometer triad

    NASA Astrophysics Data System (ADS)

    Stübi, R.; Schill, H.; Klausen, J.; Vuilleumier, L.; Ruffieux, D.

    2017-04-01

    The historical review of the total ozone column measurements with the Arosa Brewer triad in operation since 1998 is presented. The calibration history of the different instruments and the data quality control performed at Arosa are described. Over the last 15 years, the Brewer triad shows a dispersion of ˜0.4% between the three collocated instruments and a long-term stability of ±0.5%. These values are a reference metric achievable with well-maintained Brewer instruments under favorable measurement conditions.

  2. Preliminary results of an intercomparison of total ozone spectrophotometers

    NASA Technical Reports Server (NTRS)

    Parsons, C. L.; Gerlach, J. C.; Williams, M. E.; Kerr, J. B.

    1981-01-01

    Preliminary results from an intercomparison of five total ozone spectrophotometers are presented. These are the Dobson spectrophotometer, the USSR M-83 ozonometer, the Canterbury filter photometer, the SenTran Company filter photometer, and the Brewer grating spectrophotometer. The pertinent characteristics of each are described, and conclusions are drawn about the agreement of each instrument's measurements with the Dobson's values over a time period of nearly one year. A discussion of the importance of calibration and long-term stability and reliability is included.

  3. Evaluation of Piecewise Polynomial Equations for Two Types of Thermocouples

    PubMed Central

    Chen, Andrew; Chen, Chiachung

    2013-01-01

    Thermocouples are the most frequently used sensors for temperature measurement because of their wide applicability, long-term stability and high reliability. However, one of the major utilization problems is the linearization of the transfer relation between temperature and output voltage of thermocouples. The linear calibration equation and its modules could be improved by using regression analysis to help solve this problem. In this study, two types of thermocouple and five temperature ranges were selected to evaluate the fitting agreement of different-order polynomial equations. Two quantitative criteria, the average of the absolute error values |e|ave and the standard deviation of calibration equation estd, were used to evaluate the accuracy and precision of these calibrations equations. The optimal order of polynomial equations differed with the temperature range. The accuracy and precision of the calibration equation could be improved significantly with an adequate higher degree polynomial equation. The technique could be applied with hardware modules to serve as an intelligent sensor for temperature measurement. PMID:24351627

  4. Nimbus-7 Earth radiation budget calibration history. Part 1: The solar channels

    NASA Technical Reports Server (NTRS)

    Kyle, H. Lee; Hoyt, Douglas V.; Hickey, John R.; Maschhoff, Robert H.; Vallette, Brenda J.

    1993-01-01

    The Earth Radiation Budget (ERB) experiment on the Nimbus-7 satellite measured the total solar irradiance plus broadband spectral components on a nearly daily basis from 16 Nov. 1978, until 16 June 1992. Months of additional observations were taken in late 1992 and in 1993. The emphasis is on the electrically self calibrating cavity radiometer, channel 10c, which recorded accurate total solar irradiance measurements over the whole period. The spectral channels did not have inflight calibration adjustment capabilities. These channels can, with some additional corrections, be used for short-term studies (one or two solar rotations - 27 to 60 days), but not for long-term trend analysis. For channel 10c, changing radiometer pointing, the zero offsets, the stability of the gain, the temperature sensitivity, and the influences of other platform instruments are all examined and their effects on the measurements considered. Only the question of relative accuracy (not absolute) is examined. The final channel 10c product is also compared with solar measurements made by independent experiments on other satellites. The Nimbus experiment showed that the mean solar energy was about 0.1 percent (1.4 W/sqm) higher in the excited Sun years of 1979 and 1991 than in the quiet Sun years of 1985 and 1986. The error analysis indicated that the measured long-term trends may be as accurate as +/- 0.005 percent. The worse-case error estimate is +/- 0.03 percent.

  5. Radiation Budget Instrument (RBI) for JPSS-2

    NASA Technical Reports Server (NTRS)

    Georgieva, Elena; Priestley, Kory; Dunn, Barry; Cageao, Richard; Barki, Anum; Osmundsen, Jim; Turczynski, Craig; Abedin, Nurul

    2015-01-01

    Radiation Budget Instrument (RBI) will be one of five instruments flying aboard the JPSS-2 spacecraft, a polar-orbiting sun-synchronous satellite in Low Earth Orbit. RBI is a passive remote sensing instrument that will follow the successful legacy of the Clouds and Earth's Radiant Energy System (CERES) instruments to make measurement of Earth's short and longwave radiation budget. The goal of RBI is to provide an independent measurement of the broadband reflected solar radiance and Earth's emitted thermal radiance by using three spectral bands (Shortwave, Longwave, and Total) that will have the same overlapped point spread function (PSF) footprint on Earth. To ensure precise NIST-traceable calibration in space the RBI sensor is designed to use a visible calibration target (VCT), a solar calibration target (SCT), and an infrared calibration target (ICT) containing phase change cells (PCC) to enable on-board temperature calibration. The VCT is a thermally controlled integrating sphere with space grade Spectralon covering the inner surface. Two sides of the sphere will have fiber-coupled laser diodes in the UV to IR wavelength region. An electrical substitution radiometer on the integrating sphere will monitor the long term stability of the sources and the possible degradation of the Spectralon in space. In addition the radiometric calibration operations will use the Spectralon diffusers of the SCT to provide accurate measurements of Solar degradation. All those stable on-orbit references will ensure that calibration stability is maintained over the RBI sensor lifetime. For the preflight calibration the RBI will view five calibration sources - two integrating spheres and three CrIS (Cross-track Infrared Sounder ) -like blackbodies whose outputs will be validated with NIST calibration approach. Thermopile are the selected detectors for the RBI. The sensor has a requirement to perform lunar calibration in addition to solar calibration in space in a way similar to CERES instruments approach. To monitor climate change and to get stable and traceable results, it is critical to assure stable calibration over instrument lifetime.

  6. Ensuring long-term stability of infrared camera absolute calibration.

    PubMed

    Kattnig, Alain; Thetas, Sophie; Primot, Jérôme

    2015-07-13

    Absolute calibration of cryogenic 3-5 µm and 8-10 µm infrared cameras is notoriously instable and thus has to be repeated before actual measurements. Moreover, the signal to noise ratio of the imagery is lowered, decreasing its quality. These performances degradations strongly lessen the suitability of Infrared Imaging. These defaults are often blamed on detectors reaching a different "response state" after each return to cryogenic conditions, while accounting for the detrimental effects of imperfect stray light management. We show here that detectors are not to be blamed and that the culprit can also dwell in proximity electronics. We identify an unexpected source of instability in the initial voltage of the integrating capacity of detectors. Then we show that this parameter can be easily measured and taken into account. This way we demonstrate that a one month old calibration of a 3-5 µm camera has retained its validity.

  7. A Raman Lidar as Operational Tool for Long-Term Water Vapor, Temperature and Aerosol Profiling in the Swiss Meteorological Office

    NASA Astrophysics Data System (ADS)

    Simeonov, Dr; Dinoev, Dr; Serikov, Dr; Calpini, Dr; Bobrovnikov, Dr; Arshinov, Dr; Ristori, Dr; van den Bergh, Dr; Parlange, Dr

    2010-09-01

    To satisfy the rising demands on the quality and frequency of atmospheric water vapor, temperature and aerosol measurements used for numerical weather prediction models, climate change observations and special events (volcanoes, dust and smoke transport) monitoring, MeteoSwiss decided to implement a lidar at his main aerological station in Payerne. The instrument is narrow field of view, narrowband UV Raman lidar designed for continuous day and night operational profiling of tropospheric water vapor, aerosol and temperature The lidar was developed and built by the Swiss Federal Institute of Technology- Lausanne (EPFL) within a joint project with MeteoSwiss. To satisfy the requirements for operational exploitation in a meteorological network the lidar had to satisfy a number of criteria, the most important of which are: accuracy and precision, traceability of the measurement, long-term data consistency, long-term system stability, automated operation, requiring minimal maintenance by a technician, and eye safety. All this requirements were taken into account during the design phase of the lidar. After a ten months test phase of the lidar at Payerne it has been in regular operation since August 2008. Selected data illustrating interesting atmospheric phenomena captured by the lidar as well as long-term intercomparison with collocated microwave radiometer, GPS, radiosonding and an airborne DIAL will be presented and discussed. The talk will address also the technical availability, alignment and calibration stabilities of the instrument.

  8. Modeling of soil carbon turnover under different crop management: Calibration of RothC-model for Pannonian climate conditions

    NASA Astrophysics Data System (ADS)

    Rampazzo Todorovic, G.; Stemmer, M.; Tatzber, M.; Katzlberger, C.; Spiegel, H.; Zehetner, F.; Gerzabek, M. H.

    2009-04-01

    Despite our knowledge about soil C dynamics, very few long-term data concerning soil organic C dynamics are available for calibrating and evaluating C models. The long-term 14C turnover field experiment, established in 1967 in Fuchsenbigl, Lower Austria, offers the unique opportunity to investigate the mineralization and stabilization of 14C-labeled wheat straw and farmyard manure under different cropping systems (crop rotation CR, spring wheat SW and bare fallow BF) in a long-term field experiment established by H.-E. Oberländer in 1967 in Fuchsenbigl/Lower Austria. In this work the Roth-C-26.3-model was calibrated for the Pannonian climatic region based on the field experiment results. Decomposition rate constants were modified regarding the possible climatic influence on carbon sequestration in soil C pools. The modeled output based on the calibrated model fitted better to measured values than data obtained with the original Roth-C-26.3-model parameters. The main change was in the decomposition rate constant for the HUM (humified) soil C pool, which is now fitted for different plots from 0.005 to 0.01 y-1 instead of 0.02 y-1 as determined in the original Rothamsted field trial. Moreover, for one plot, in addition to the HUM pool, the decomposition rate constant for RPM (resistant plant material) pool was fitted at 0.7 y-1 instead of 0.3 y-1 as originally in the Roth-C-26.3-model. These changes yielded a higher HUM pool in the calibrated model because of the longer turnover period (100-200 versus 50 years). Compared with CR and SW treatments, the decline of TOC was largest in the BF treatments as expected because no significant carbon input has occurred since 1967. Nonetheless, the decline was still not as fast as calculated with original RothC-26.3-model decomposition rate constants. The specific research question was the long-term effect of residue removal on SOM levels under different crop management, under different soil conditions and different climatic regimes of Fuchsenbigl (Austria), Rothamsted (UK) and Ultuna (Sweden). Modeling results of removing the crop residues showed that this can entail a long-term decline of SOM. However, these impacts are strongly dependent on the crop types, the soil properties, and the climatic conditions at a given location. Modeling results of the removal of crop residues showed that it can entail a long-term decline of SOM. A comparison of modeling results for winter wheat and spring barley for Rothamsted/UK, Fuchsenbigl/Austria and Ultuna/Sweden indicate slight SOC decreases at the Fuchsenbigl site when 100% of the straw was removed and increasing trends when 50% was removed. However, at the Rothamsted and Ultuna sites, 50% straw removal still resulted in declining SOC stocks.

  9. Emerging Techniques for Vicarious Calibration of Visible Through Short Wave Infrared Remote Sensing Systems

    NASA Technical Reports Server (NTRS)

    Ryan, Robert E.

    2006-01-01

    Simple field-portable white light LED calibration source shows promise for visible range (420-750 nm) 1) Prototype demonstrated <0.5% drift over 10-40 C temperature range; 2) Additional complexity (more LEDs) will be necessary for extending spectral range into the NIR and SWIR; 3) LED long lifetimes should produce at least several hundreds of hours or more stability, minimizing need for expensive calibrations and supporting long-duration field campaigns; and 4) Enabling technology for developing autonomous sites.

  10. Improvements in Calibration and Analysis of the CTBT-relevant Radioxenon Isotopes with High Resolution SiPIN-based Electron Detectors

    NASA Astrophysics Data System (ADS)

    Khrustalev, K.

    2016-12-01

    Current process for the calibration of the beta-gamma detectors used for radioxenon isotope measurements for CTBT purposes is laborious and time consuming. It uses a combination of point sources and gaseous sources resulting in differences between energy and resolution calibrations. The emergence of high resolution SiPIN based electron detectors allows improvements in the calibration and analysis process to be made. Thanks to high electron resolution of SiPIN detectors ( 8-9 keV@129 keV) compared to plastic scintillators ( 35 keV@129keV) there are a lot more CE peaks (from radioxenon and radon progenies) can be resolved and used for energy and resolution calibration in the energy range of the CTBT-relevant radioxenon isotopes. The long term stability of the SiPIN energy calibration allows one to significantly reduce the time of the QC measurements needed for checking the stability of the E/R calibration. The currently used second order polynomials for the E/R calibration fitting are unphysical and shall be replaced by a linear energy calibration for NaI and SiPIN, owing to high linearity and dynamic range of the modern digital DAQ systems, and resolution calibration functions shall be modified to reflect the underlying physical processes. Alternatively, one can completely abandon the use of fitting functions and use only point-values of E/R (similar to the efficiency calibration currently used) at the energies relevant for the isotopes of interest (ROI - Regions Of Interest ). Current analysis considers the detector as a set of single channel analysers, with an established set of coefficients relating the positions of ROIs with the positions of the QC peaks. The analysis of the spectra can be made more robust using peak and background fitting in the ROIs with a single free parameter (peak area) of the potential peaks from the known isotopes and a fixed E/R calibration values set.

  11. 2017 Update on the WFC3/UVIS Stability and Contamination Monitor

    NASA Astrophysics Data System (ADS)

    Shanahan, C. E.; Gosmeyer, C. M.; Baggett, S.

    2017-06-01

    The photometric throughput of the UVIS detector on WFC3 is monitored each cycle for its stability as a function of time, wavelength, as well as to check for any evidence of contamination on the CCD windows, which would manifest as a decrease in throughput strongest in the bluest filters. This program has been in place since the installation of WFC3 in 2009, historically making periodic observations of the spectrophotometric standard GRW+70d5824 (GRW70) in several key filters from 200 nm to 600 nm, with red filters acting as a control. This is a follow up report to the last analysis of the temporal stability of UVIS (Gosmeyer et al., 2014), since which several major changes to the program and data analysis have been implemented. Due to recent work suggesting a low-level, long-term variability for GRW70, another spectrophotometric standard star - GD153 - has been added to the program and is now analyzed in conjunction with GRW70. Data are now processed with the latest version of the CALWF3 calibration pipeline (v. 3.4), which has several new features that represent a paradigm shift in calibration methodology. Finally, the data analysis software, which was previously entirely IRAF based, was re-written in Python. We find a steady decline in the count rate for most filters but no evidence for contamination, which would manifest as a wavelength-dependent effect, impacting bluer filters more strongly. These declines range from 0.01% to 0.3% per year, and are stronger in longer wavelength filters. Similar temporal changes are found for both stars, and the long-term trends in throughput agree with previous trends derived in 2014.

  12. VIIRS Reflective Solar Band Radiometric and Stability Evaluation Using Deep Convective Clouds

    NASA Technical Reports Server (NTRS)

    Chang, Tiejun; Xiong, Xiaoxiong; Mu, Qiaozhen

    2016-01-01

    This work takes advantage of the stable distribution of deep convective cloud (DCC) reflectance measurements to assess the calibration stability and detector difference in Visible Infrared Imaging Radiometer Suite (VIIRS) reflective bands. VIIRS Sensor Data Records (SDRs) from February 2012 to June 2015 are utilized to analyze the long-term trending, detector difference, and half angle mirror (HAM) side difference. VIIRS has two thermal emissive bands with coverage crossing 11 microns for DCC pixel identification. The comparison of the results of these two processing bands is one of the indicators of analysis reliability. The long-term stability analysis shows downward trends (up to approximately 0.4 per year) for the visible and near-infrared bands and upward trends (up to 0.5per year) for the short- and mid-wave infrared bands. The detector difference for each band is calculated as the difference relative to the average reflectance overall detectors. Except for the slightly greater than 1 difference in the two bands at 1610 nm, the detector difference is less than1 for other solar reflective bands. The detector differences show increasing trends for some short-wave bands with center wavelengths from 400 to 600 nm and remain unchanged for the bands with longer center wavelengths. The HAM side difference is insignificant and stable. Those short-wave bands from 400 to 600 nm also have relatively larger HAM side difference, up to 0.25.Comparing the striped images from SDR and the smooth images after the correction validates the analyses of detector difference and HAM side difference. These analyses are very helpful for VIIRS calibration improvement and thus enhance product quality

  13. Implications of Version 8 TOMS and SBUV Data for Long-Term Trend Analysis

    NASA Technical Reports Server (NTRS)

    Frith, Stacey M.

    2004-01-01

    Total ozone data from the Total Ozone Mapping Spectrometer (TOMS) and profile/total ozone data from the Solar Backscatter Ultraviolet (SBUV; SBW/2) series of instruments have recently been reprocessed using new retrieval algorithms (referred to as Version 8 for both) and updated calibrations. In this paper, we incorporate the Version 8 data into a TOMS/SBW merged total ozone data set and an S B W merged profile ozone data set. The Total Merged Ozone Data (Total MOD) combines data from multiple TOMS and SBW instruments to form an internally consistent global data set with virtually complete time coverage from October 1978 through December 2003. Calibration differences between instruments are accounted for using external adjustments based on instrument intercomparisons during overlap periods. Previous results showed errors due to aerosol loading and sea glint are significantly reduced in the V8 TOMS retrievals. Using SBW as a transfer standard, calibration differences between V8 Nimbus 7 and Earth Probe TOMS data are approx. 1.3%, suggesting small errors in calibration remain. We will present updated total ozone long-term trends based on the Version 8 data. The Profile Merged Ozone Data (Profile MOD) data set is constructed using data from the SBUV series of instruments. In previous versions, SAGE data were used to establish the long-term external calibration of the combined data set. The SBW Version 8 we assess the V8 profile data through comparisons with SAGE and between SBW instruments in overlap periods. We then construct a consistently-calibrated long term time series. Updated zonal mean trends as a function of altitude and season from the new profile data set will be shown, and uncertainties in determining the best long-term calibration will be discussed.

  14. Evolution of Altimetry Calibration and Future Challenges

    NASA Technical Reports Server (NTRS)

    Fu, Lee-Lueng; Haines, Bruce J.

    2012-01-01

    Over the past 20 years, altimetry calibration has evolved from an engineering-oriented exercise to a multidisciplinary endeavor driving the state of the art. This evolution has been spurred by the developing promise of altimetry to capture the large-scale, but small-amplitude, changes of the ocean surface containing the expression of climate change. The scope of altimeter calibration/validation programs has expanded commensurately. Early efforts focused on determining a constant range bias and verifying basic compliance of the data products with mission requirements. Contemporary investigations capture, with increasing accuracies, the spatial and temporal characteristics of errors in all elements of the measurement system. Dedicated calibration sites still provide the fundamental service of estimating absolute bias, but also enable long-term monitoring of the sea-surface height and constituent measurements. The use of a network of island and coastal tide gauges has provided the best perspective on the measurement stability, and revealed temporal variations of altimeter measurement system drift. The cross-calibration between successive missions provided fundamentally new information on the performance of altimetry systems. Spatially and temporally correlated errors pose challenges for future missions, underscoring the importance of cross-calibration of new measurements against the established record.

  15. Evaluation of Long-Term Pavement Performance (LTTP) Climatic Data for Use in Mechanistic-Empirical Pavement Design Guide (MEPDG) Calibration and Other Pavement Analysis

    DOT National Transportation Integrated Search

    2015-05-01

    Improvements in the Long-Term Pavement Performance (LTPP) Programs climate data are needed to support current and future research into climate effects on pavement materials, design, and performance. The calibration and enhancement of the Mechanist...

  16. Global and Regional Trends of Aerosol Optical Depth over Land and Ocean Using SeaWiFS Measurements from 1997 to 2010

    NASA Technical Reports Server (NTRS)

    Hsu, N. C.; Gautam, R.; Sayer, A. M.; Bettenhausen, C.; Li, C.; Jeong, M. J.; Tsay, S. C.; Holben, B. N.

    2012-01-01

    Both sensor calibration and satellite retrieval algorithm play an important role in the ability to determine accurately long-term trends from satellite data. Owing to the unprecedented accuracy and long-term stability of its radiometric calibration, the SeaWiFS measurements exhibit minimal uncertainty with respect to sensor calibration. In this study, we take advantage of this well-calibrated set of measurements by applying a newly-developed aerosol optical depth (AOD) retrieval algorithm over land and ocean to investigate the distribution of AOD, and to identify emerging patterns and trends in global and regional aerosol loading during its 13-year mission. Our results indicate that the averaged AOD trend over global ocean is weakly positive from 1998 to 2010 and comparable to that observed by MODIS but opposite in sign to that observed by AVHRR during overlapping years. On a smaller scale, different trends are found for different regions. For example, large upward trends are found over the Arabian Peninsula that indicate a strengthening of the seasonal cycle of dust emission and transport processes over the whole region as well as over downwind oceanic regions. In contrast, a negative-neutral tendency is observed over the desert/arid Saharan region as well as in the associated dust outflow over the north Atlantic. Additionally, we found decreasing trends over the eastern US and Europe, and increasing trends over countries such as China and India that are experiencing rapid economic development. In general, these results are consistent with those derived from ground-based AERONET measurements.

  17. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Vaccarono, Mattia; Bechini, Renzo; Chandrasekar, Chandra V.

    The stability of weather radar calibration is a mandatory aspect for quantitative applications, such as rainfall estimation, short-term weather prediction and initialization of numerical atmospheric and hydrological models. Over the years, calibration monitoring techniques based on external sources have been developed, specifically calibration using the Sun and calibration based on ground clutter returns. In this paper, these two techniques are integrated and complemented with a self-consistency procedure and an intercalibration technique. The aim of the integrated approach is to implement a robust method for online monitoring, able to detect significant changes in the radar calibration. The physical consistency of polarimetricmore » radar observables is exploited using the self-consistency approach, based on the expected correspondence between dual-polarization power and phase measurements in rain. This technique allows a reference absolute value to be provided for the radar calibration, from which eventual deviations may be detected using the other procedures. In particular, the ground clutter calibration is implemented on both polarization channels (horizontal and vertical) for each radar scan, allowing the polarimetric variables to be monitored and hardware failures to promptly be recognized. The Sun calibration allows monitoring the calibration and sensitivity of the radar receiver, in addition to the antenna pointing accuracy. It is applied using observations collected during the standard operational scans but requires long integration times (several days) in order to accumulate a sufficient amount of useful data. Finally, an intercalibration technique is developed and performed to compare colocated measurements collected in rain by two radars in overlapping regions. The integrated approach is performed on the C-band weather radar network in northwestern Italy, during July–October 2014. The set of methods considered appears suitable to establish an online tool to monitor the stability of the radar calibration with an accuracy of about 2 dB. In conclusion, this is considered adequate to automatically detect any unexpected change in the radar system requiring further data analysis or on-site measurements.« less

  18. Calibration of the SBUV version 8.6 ozone data product

    NASA Astrophysics Data System (ADS)

    DeLand, M. T.; Taylor, S. L.; Huang, L. K.; Fisher, B. L.

    2012-11-01

    This paper describes the calibration process for the Solar Backscatter Ultraviolet (SBUV) Version 8.6 (V8.6) ozone data product. Eight SBUV instruments have flown on NASA and NOAA satellites since 1970, and a continuous data record is available since November 1978. The accuracy of ozone trends determined from these data depends on the calibration and long-term characterization of each instrument. V8.6 calibration adjustments are determined at the radiance level, and do not rely on comparison of retrieved ozone products with other instruments. The primary SBUV instrument characterization is based on prelaunch laboratory tests and dedicated on-orbit calibration measurements. We supplement these results with "soft" calibration techniques using carefully chosen subsets of radiance data and information from the retrieval algorithm output to validate each instrument's calibration. The estimated long-term uncertainty in albedo is approximately ±0.8-1.2% (1σ) for most of the instruments. The overlap between these instruments and the Shuttle SBUV (SSBUV) data allows us to intercalibrate the SBUV instruments to produce a coherent V8.6 data set covering more than 32 yr. The estimated long-term uncertainty in albedo is less than 3% over this period.

  19. Calibration of the SBUV version 8.6 ozone data product

    NASA Astrophysics Data System (ADS)

    DeLand, M. T.; Taylor, S. L.; Huang, L. K.; Fisher, B. L.

    2012-07-01

    This paper describes the calibration process for the Solar Backscatter Ultraviolet (SBUV) Version 8.6 (V8.6) ozone data product. Eight SBUV instruments have flown on NASA and NOAA satellites since 1970, and a continuous data record is available since November 1978. The accuracy of ozone trends determined from these data depends on the calibration and long-term characterization of each instrument. V8.6 calibration adjustments are determined at the radiance level, and do not rely on comparison of retrieved ozone products with other instruments. The primary SBUV instrument characterization is based on prelaunch laboratory tests and dedicated on-orbit calibration measurements. We supplement these results with "soft" calibration techniques using carefully chosen subsets of radiance data and information from the retrieval algorithm output to validate each instrument's calibration. The estimated long-term uncertainty in albedo is approximately ±0.8-1.2% (1σ) for most of the instruments. The overlap between these instruments and the Shuttle SBUV (SSBUV) data allows us to intercalibrate the SBUV instruments to produce a coherent V8.6 data set covering more than 32 yr. The estimated long-term uncertainty in albedo is less than 3% over this period.

  20. A rubidium traced white-light etalon calibrator for MAROON-X

    NASA Astrophysics Data System (ADS)

    Stürmer, Julian; Seifahrt, Andreas; Schwab, Christian; Bean, Jacob L.

    2016-07-01

    We report on the construction and testing of a vacuum-gap Fabry-Perot etalon calibrator for high precision radial velocity spectrographs. The etalon is referenced against hyper fine transitions of rubidium to provide a precise wavelength calibrator for MAROON-X, a new fiber-fed, red-optical, high-precision radial-velocity spectrograph currently under construction for one of the twin 6.5m Magellan Telescopes in Chile. We demonstrate a turnkey system, ready to be installed at any current and next generation radial velocity spectrograph that requires calibration over a wide spectral band-pass. Uncertainties in the position of one etalon line are at the 10 cm s-1 level in individual measurements taken at 4 Hz. Our long-term stability is mainly limited by aging effects of the spacer material Zerodur, which imprints a 12 cm s-1 daily drift. However, as the etalon position is traced by the rubidium reference with a precision of <3 cm s-1 for integration times longer than 10s, we can fully account for this effect at the RV data reduction level.

  1. Georgia Long-Term Pavement Performance (GALTPP) Program – Maintaining Georgia’s Calibration Sites and Identifying the Potential for Using MEPDG for Characterization of Non-Standard Materials and Methods (Phase 1)

    DOT National Transportation Integrated Search

    2016-10-01

    The Georgia Department of Transportation (GDOT) has initiated a Georgia Long-Term Pavement Performance (GALTPP) monitoring program 1) to provide data for calibrating the prediction models in the AASHTO Mechanistic-Empirical Pavement Design Guide (MEP...

  2. Development and field testing of a rapid and ultra-stable atmospheric carbon dioxide spectrometer

    DOE PAGES

    Xiang, B.; Nelson, D. D.; McManus, J. B.; ...

    2014-12-15

    We present field test results for a new spectroscopic instrument to measure atmospheric carbon dioxide (CO 2) with high precision (0.02 μmol mol -1, or ppm at 1 Hz) and demonstrate high stability (within 0.1 ppm over more than 8 months), without the need for hourly, daily, or even monthly calibration against high-pressure gas cylinders. The technical novelty of this instrument (ABsolute Carbon dioxide, ABC) is the spectral null method using an internal quartz reference cell with known CO 2 column density. Compared to a previously described prototype, the field instrument has better stability and benefits from more precise thermalmore » control of the optics and more accurate pressure measurements in the sample cell (at the mTorr level). The instrument has been deployed at a long-term ecological research site (the Harvard Forest, USA), where it has measured for 8 months without on-site calibration and with minimal maintenance, showing drift bounds of less than 0.1 ppm. Field measurements agree well with those of a commercially available cavity ring-down CO 2 instrument (Picarro G2301) run with a standard calibration protocol. This field test demonstrates that ABC is capable of performing high-accuracy, unattended, continuous field measurements with minimal use of reference gas cylinders.« less

  3. Development and field testing of a rapid and ultra-stable atmospheric carbon dioxide spectrometer

    NASA Astrophysics Data System (ADS)

    Xiang, B.; Nelson, D. D.; McManus, J. B.; Zahniser, M. S.; Wehr, R. A.; Wofsy, S. C.

    2014-12-01

    We present field test results for a new spectroscopic instrument to measure atmospheric carbon dioxide (CO2) with high precision (0.02 μmol mol-1, or ppm at 1 Hz) and demonstrate high stability (within 0.1 ppm over more than 8 months), without the need for hourly, daily, or even monthly calibration against high-pressure gas cylinders. The technical novelty of this instrument (ABsolute Carbon dioxide, ABC) is the spectral null method using an internal quartz reference cell with known CO2 column density. Compared to a previously described prototype, the field instrument has better stability and benefits from more precise thermal control of the optics and more accurate pressure measurements in the sample cell (at the mTorr level). The instrument has been deployed at a long-term ecological research site (the Harvard Forest, USA), where it has measured for 8 months without on-site calibration and with minimal maintenance, showing drift bounds of less than 0.1 ppm. Field measurements agree well with those of a commercially available cavity ring-down CO2 instrument (Picarro G2301) run with a standard calibration protocol. This field test demonstrates that ABC is capable of performing high-accuracy, unattended, continuous field measurements with minimal use of reference gas cylinders.

  4. JMR Noise Diode Stability and Recalibration Methodology after Three Years On-Orbit

    NASA Technical Reports Server (NTRS)

    Brown, Shannon; Desai, Shailen; Keihm, Stephen; Ruf, Christopher

    2006-01-01

    The Jason Microwave Radiometer (JMR) is included on the Jason-1 ocean altimeter satellite to measure the wet tropospheric path delay (PD) experienced by the radar altimeter signal. JMR is nadir pointing and measures the radiometric brightness temperature (T(sub B)) at 18.7, 23.8 and 34.0 GHz. JMR is a Dicke radiometer and it is the first radiometer to be flown in space that uses noise diodes for calibration. Therefore, monitoring the long term stability of the noise diodes is essential. Each channel has three redundant noise diodes which are individually coupled into the antenna signal to provide an estimate of the gain. Two significant jumps in the JMR path delays, relative to ground truth, were observed around 300 and 700 days into the mission. Slow drifts in the retrieved products were also evident over the entire mission. During a recalibration effort, it was determined that a single set of calibration coefficients was not able to remove the calibration jumps and drifts, suggesting that there was a change in the hardware and time dependent coefficients would be required. To facilitate the derivation of time dependent coefficients, an optimal estimation based calibration system was developed which iteratively determines that set of calibration coefficients which minimize the RMS difference between the JMR TBs and on-Earth hot and cold absolute references. This optimal calibration algorithm was used to fine tune the front end path loss coefficients and derive a time series of the JMR noise diode brightness temperatures for each of the nine diodes. Jumps and drifts, on the order of 1% to 2%, are observed among the noise diodes in the first three years on-orbit.

  5. Development of departmental standard for traceability of measured activity for I-131 therapy capsules used in nuclear medicine.

    PubMed

    Ravichandran, Ramamoorthy; Binukumar, Jp

    2011-01-01

    International Basic Safety Standards (International Atomic Energy Agency, IAEA) provide guidance levels for diagnostic procedures in nuclear medicine indicating the maximum usual activity for various diagnostic tests in terms of activities of injected radioactive formulations. An accuracy of ± 10% in the activities of administered radio-pharmaceuticals is being recommended, for expected outcome in diagnostic and therapeutic nuclear medicine procedures. It is recommended that the long-term stability of isotope calibrators used in nuclear medicine is to be checked periodically for their performance using a long-lived check source, such as Cs-137, of suitable activity. In view of the un-availability of such a radioactive source, we tried to develop methods to maintain traceability of these instruments, for certifying measured activities for human use. Two re-entrant chambers [(HDR 1000 and Selectron Source Dosimetry System (SSDS)] with I-125 and Ir-192 calibration factors in the Department of Radiotherapy were used to measure Iodine-131 (I-131) therapy capsules to establish traceability to Mark V isotope calibrator of the Department of Nuclear Medicine. Special nylon jigs were fabricated to keep I-131 capsule holder in position. Measured activities in all the chambers showed good agreement. The accuracy of SSDS chamber in measuring Ir-192 activities in the last 5 years was within 0.5%, validating its role as departmental standard for measuring activity. The above method is adopted because mean energies of I-131 and Ir-192 are comparable.

  6. Overview of calibration and validation activities for the EUMETSAT polar system: second generation (EPS-SG) visible/infrared imager (METimage)

    NASA Astrophysics Data System (ADS)

    Phillips, P.; Bonsignori, R.; Schlüssel, P.; Schmülling, F.; Spezzi, L.; Watts, P.; Zerfowski, I.

    2016-10-01

    The EPS-SG Visible/Infrared Imaging (VII) mission is dedicated to supporting the optical imagery user needs for Numerical Weather Prediction (NWP), Nowcasting (NWC) and climate in the timeframe beyond 2020. The VII mission is fulfilled by the METimage instrument, developed by the German Space Agency (DLR) and funded by the German government and EUMETSAT. Following on from an important list of predecessors such as the Advanced Very High Resolution Radiometer (AVHRR) and the Moderate resolution Imaging Spectro-radiometer (MODIS), METimage will fly in the mid-morning orbit of the Joint Polar System, whilst the early-afternoon orbits are served by the JPSS (U.S. Joint Polar Satellite System) Visible Infrared Imager Radiometer Suite (VIIRS). METimage itself is a cross-purpose medium resolution, multi-spectral optical imager, measuring the optical spectrum of radiation emitted and reflected by the Earth from a low-altitude sun synchronous orbit over a minimum swath width of 2700 km. The top of the atmosphere outgoing radiance will be sampled every 500 m (at nadir) with measurements made in 20 spectral channels ranging from 443 nm in the visible up to 13.345 μm in the thermal infrared. The three major objectives of the EPS-SG METimage calibration and validation activities are: • Verification of the instrument performances through continuous in-flight calibration and characterisation, including monitoring of long term stability. • Provision of validated level 1 and level 2 METimage products. • Revision of product processing facilities, i.e. algorithms and auxiliary data sets, to assure that products conform with user requirements, and then, if possible, exceed user expectations. This paper will describe the overall Calibration and Validation (Cal/Val) logic and the methods adopted to ensure that the METimage data products meet performance specifications for the lifetime of the mission. Such methods include inter-comparisons with other missions through simultaneous nadir overpasses and comparisons with ground based observations, analysis of algorithm internal diagnostics to confirm retrieval performance for geophysical products and vicarious calibration to assist with validation of the instrument on-board calibration. Any identified deficiencies in the products will lead to either an update any auxiliary data sets (e.g. calibration key data) that are used to configure the product processors or to a revision of algorithms themselves. The Cal/Val activities are mostly foreseen during commissioning but will inevitably extend to routine operations in order to take on board seasonal variations and ensure long term stability of the calibrated radiances and geophysical products. Pre-requisite to validation of products at scientific level is that the satellite and instrument itself have been verified against their respective specifications both pre-launch and during the satellite in-orbit verification phase.

  7. Impact of length of calibration period on the apex model output simulation performance

    USDA-ARS?s Scientific Manuscript database

    Datasets from long-term monitoring sites that can be used for calibration and validation of hydrologic and water quality models are rare due to resource constraints. As a result, hydrologic and water quality models are calibrated and, when possible, validated using short-term measured data. A previo...

  8. Radiometric cross-calibration of the Terra MODIS and Landsat 7 ETM+ using an invariant desert site

    USGS Publications Warehouse

    Choi, T.; Angal, A.; Chander, G.; Xiong, X.

    2008-01-01

    A methodology for long-term radiometric cross-calibration between the Terra Moderate Resolution Imaging Spectroradiometer (MODIS) and Landsat 7 (L7) Enhanced Thematic Mapper Plus (ETM+) sensors was developed. The approach involves calibration of near-simultaneous surface observations between 2000 and 2007. Fifty-seven cloud-free image pairs were carefully selected over the Libyan desert for this study. The Libyan desert site (+28.55??, +23.39??), located in northern Africa, is a high reflectance site with high spatial, spectral, and temporal uniformity. Because the test site covers about 12 kmx13 km, accurate geometric preprocessing is required to match the footprint size between the two sensors to avoid uncertainties due to residual image misregistration. MODIS Level IB radiometrically corrected products were reprojected to the corresponding ETM+ image's Universal Transverse Mercator (UTM) grid projection. The 30 m pixels from the ETM+ images were aggregated to match the MODIS spatial resolution (250 m in Bands 1 and 2, or 500 m in Bands 3 to 7). The image data from both sensors were converted to absolute units of at-sensor radiance and top-ofatmosphere (TOA) reflectance for the spectrally matching band pairs. For each band pair, a set of fitted coefficients (slope and offset) is provided to quantify the relationships between the testing sensors. This work focuses on long-term stability and correlation of the Terra MODIS and L7 ETM+ sensors using absolute calibration results over the entire mission of the two sensors. Possible uncertainties are also discussed such as spectral differences in matching band pairs, solar zenith angle change during a collection, and differences in solar irradiance models.

  9. Calibration of the Politrack® system based on CR39 solid-state nuclear track detectors for passive indoor radon concentration measurements.

    PubMed

    Kropat, G; Baechler, S; Bailat, C; Barazza, F; Bochud, F; Damet, J; Meyer, N; Palacios Gruson, M; Butterweck, G

    2015-11-01

    Swiss national requirements for measuring radon gas exposures demand a lower detection limit of 50 kBq h m(-3), representing the Swiss concentration average of 70 Bq m(-3) over a 1-month period. A solid-state nuclear track detector (SSNTD) system (Politrack, Mi.am s.r.l., Italy) has been acquired to fulfil these requirements. This work was aimed at the calibration of the Politrack system with traceability to international standards and the development of a procedure to check the stability of the system. A total of 275 SSNTDs was exposed to 11 different radon exposures in the radon chamber of the Secondary Calibration Laboratory at the Paul Scherrer Institute, Switzerland. The exposures ranged from 50 to 15000 kBq h m(-3). For each exposure of 20 detectors, 5 SSNTDs were used to monitor possible background exposures during transport and storage. The response curve and the calibration factor of the whole system were determined using a Monte Carlo fitting procedure. A device to produce CR39 samples with a reference number of tracks using a (241)Am source was developed for checking the long-term stability of the Politrack system. The characteristic limits for the detection of a possible system drift were determined following ISO Standard 11929. © The Author 2015. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  10. Simultaneous overpass off nadir (SOON): a method for unified calibration/validation across IEOS and GEOSS system of systems

    NASA Astrophysics Data System (ADS)

    Ardanuy, Philip; Bergen, Bill; Huang, Allen; Kratz, Gene; Puschell, Jeff; Schueler, Carl; Walker, Joe

    2006-08-01

    The US operates a diverse, evolving constellation of research and operational environmental satellites, principally in polar and geosynchronous orbits. Our current and enhanced future domestic remote sensing capability is complemented by the significant capabilities of our current and potential future international partners. In this analysis, we define "success" through the data customers' "eyes": participating in the sufficient and continuously improving satisfaction of their mission responsibilities. To successfully fuse together observations from multiple simultaneous platforms and sensors into a common, self-consistent, operational environment requires that there exist a unified calibration and validation approach. Here, we consider develop a concept for an integrating framework for absolute accuracy; long-term stability; self-consistency among sensors, platforms, techniques, and observing systems; and validation and characterization of performance. Across all systems, this is a non-trivial problem. Simultaneous Nadir Overpasses, or SNO's, provide a proven intercomparison technique: simultaneous, collocated, co-angular measurements. Many systems have off-nadir elements, or effects, that must be calibrated. For these systems, the nadir technique constrains the process. We define the term "SOON," for simultaneous overpass off nadir. We present a target architecture and sensitivity analysis for the affordable, sustainable implementation of a global SOON calibration/validation network that can deliver the much-needed comprehensive, common, self-consistent operational picture in near-real time, at an affordable cost.

  11. Initial evaluation of airborne water vapour measurements by the IAGOS-GHG CRDS system

    NASA Astrophysics Data System (ADS)

    Filges, Annette; Gerbig, Christoph; Smit, Herman G. J.; Krämer, Martina; Spelten, Nicole

    2013-04-01

    Accurate and reliable airborne measurements of water vapour are still a challenge. Presently, no airborne humidity sensor exists that covers the entire range of water vapour content between the surface and the upper troposphere/lower stratosphere (UT/LS) region with sufficient accuracy and time resolution. Nevertheless , these data are a pre-requisite to study the underlying processes in the chemistry and physics of the atmosphere. The DENCHAR project (Development and Evaluation of Novel Compact Hygrometer for Airborne Research) addresses this deficit by developing and characterizing novel or improved compact airborne hygrometers for different airborne applications within EUFAR (European Facility for Airborne Research). As part of the DENCHAR inter-comparison campaign in Hohn (Germany), 23 May - 1 June 2011, a commercial gas analyzer (G2401-m, Picarro Inc.,US), based on cavity ring-down spectroscopy (CRDS), was installed on a Learjet to measure water vapour, CO2, CH4 and CO. The CRDS components are identical to those chosen for integration aboard commercial airliner within IAGOS (In-service Aircraft for a Global Observing System). Thus the campaign allowed for the initial assessment validation of the long-term IAGOS H2O measurements by CRDS against reference instruments with a long performance record (FISH, the Fast In-situ Stratospheric Hygrometer, and CR2 frostpoint hygrometer, both research centre Juelich). The inlet system, a one meter long 1/8" FEP-tube connected to a Rosemount TAT housing (model 102BX, deiced) installed on a window plate of the aircraft, was designed to eliminate sampling of larger aerosols, ice particles, and water droplets, and provides about 90% of ram-pressure. In combination with a lowered sample flow of 0.1 slpm (corresponding to a 4 second response time), this ensured a fully controlled sample pressure in the cavity of 140 torr throughout an aircraft altitude operating range up to 12.5 km without the need of an upstream sampling pump. This setup ensures full compatibility with the future deployment of the analyser within IAGOS. For the initial water calibration of the instrument, a calibration of a similar instrument performed at MPI-BGC Jena against a dew point mirror (Dewmet, Michell instruments Ltd., UK) in the range from 0.7 to 3.0% was transferred to all subsequently manufactured CRDS instruments by Picarro. During the campaign the analyzer was compared against a reference frost point hygrometer, which is also used for calibration of the reference instrument FISH. The dew point mirror calibration was within 0.7 % of the FISH calibrator, but showed an offset of 14.45 ppm, which is consistent with the H2O content of dry tank air and diffusion effects through the inlet line (FEP). Furthermore, a new independent calibration method, based on the dilution effect of water vapour on CO2, was tested. It showed a 9 % low bias compared to the dew point mirror calibration. Comparison of the in-flight data against the reference systems showed that the analyzer is reliable and has a good long-term stability. Flight data from the DENCHAR campaign suggest a conservative precision estimate for measurements made at 0.4 Hz of 4 ppm for H2O < 100 ppm, and 4 % (relative) for H2O > 100 ppm. Accuracy at mixing ratios below 50 ppm was difficult to assess, as the reference instruments suffered from lack of stability. We present the results of the campaign flights and comparison with the reference instruments. The different calibration methods will be discussed.

  12. Global long-term ozone trends derived from different observed and modelled data sets

    NASA Astrophysics Data System (ADS)

    Coldewey-Egbers, M.; Loyola, D.; Zimmer, W.; van Roozendael, M.; Lerot, C.; Dameris, M.; Garny, H.; Braesicke, P.; Koukouli, M.; Balis, D.

    2012-04-01

    The long-term behaviour of stratospheric ozone amounts during the past three decades is investigated on a global scale using different observed and modelled data sets. Three European satellite sensors GOME/ERS-2, SCIAMACHY/ENVISAT, and GOME-2/METOP are combined and a merged global monthly mean total ozone product has been prepared using an inter-satellite calibration approach. The data set covers the 16-years period from June 1995 to June 2011 and it exhibits an excellent long-term stability, which is required for such trend studies. A multiple linear least-squares regression algorithm using different explanatory variables is applied to the time series and statistically significant positive trends are detected in the northern mid latitudes and subtropics. Global trends are also estimated using a second satellite-based Merged Ozone Data set (MOD) provided by NASA. For few selected geographical regions ozone trends are additionally calculated using well-maintained measurements of individual Dobson/Brewer ground-based instruments. A reasonable agreement in the spatial patterns of the trends is found amongst the European satellite, the NASA satellite, and the ground-based observations. Furthermore, two long-term simulations obtained with the Chemistry-Climate Models E39C-A provided by German Aerospace Center and UMUKCA-UCAM provided by University of Cambridge are analysed.

  13. On-Orbit Noise Characterization for MODIS Reflective Solar Bands

    NASA Technical Reports Server (NTRS)

    Xiong, X.; Xie, X.; Angal, A.

    2008-01-01

    Since launch, the Moderate Resolution Imaging Spectroradiometer (MODIS) has operated successfully on-board the NASA Earth Observing System (EOS) Terra and EOS Aqua spacecraft. MODIS is a passive cross-track scanning radiometer that makes observations in 36 spectral bands with spectral wavelengths from visible (VIS) to long-wave infrared. MODIS bands 1-19 and 26 are the reflective solar bands (RSB) with wavelengths from 0.41 to 2.2 micrometers. They are calibrated on-orbit using an on-board solar diffuser (SD) and a SD stability monitor (SDSM) system. For MODIS RSB, the level 1B calibration algorithm produces top of the atmosphere reflectance factors and radiances for every pixel of the Earth view. The sensor radiometric calibration accuracy, specified at each spectral band's typical scene radiance, is 2% for the RSB reflectance factors and 5% for the RSB radiances. Also specified at the typical scene radiance is the detector signal-to-noise ratio (SNR), a key sensor performance parameter that directly impacts its radiometric calibration accuracy and stability, as well as the image quality. This paper describes an on-orbit SNR characterization approach developed to evaluate and track MODIS RSB detector performance. In order to perform on-orbit SNR characterization, MODIS RSB detector responses to the solar illumination reflected from the SD panel must be corrected for factors due to variations of the solar angles and the SD bi-directional reflectance factor. This approach enables RSB SNR characterization to be performed at different response levels for each detector. On-orbit results show that both Terra and Aqua MODIS RSB detectors have performed well since launch. Except for a few noisy or inoperable detectors which were identified pre-launch, most RSB detectors continue to meet the SNR design requirements and are able to maintain satisfactory short-term stability. A comparison of on-orbit noise characterization results with results derived from pre-launch calibration and characterization are also provided.

  14. Validation of 10 years of SAO OMI Ozone Profiles with Ozonesonde and MLS Observations

    NASA Astrophysics Data System (ADS)

    Huang, G.; Liu, X.; Chance, K.; Bhartia, P. K.

    2015-12-01

    To evaluate the accuracy and long-term stability of the SAO OMI ozone profile product, we validate ~10 years of ozone profile product (Oct. 2004-Dec. 2014) against collocated ozonesonde and MLS data. Ozone profiles as well stratospheric, tropospheric, lower tropospheric ozone columns are compared with ozonesonde data for different latitude bands, and time periods (e.g., 2004-2008/2009-2014 for without/with row anomaly. The mean biases and their standard deviations are also assessed as a function of time to evaluate the long-term stability and bias trends. In the mid-latitude and tropical regions, OMI generally shows good agreement with ozonesonde observations. The mean ozone profile biases are generally within 6% with up to 30% standard deviations. The biases of stratospheric ozone columns (SOC) and tropospheric ozone columns (TOC) are -0.3%-2.2% and -0.2%-3%, while standard deviations are 3.9%-5.8% and 14.4%-16.0%, respectively. However, the retrievals during 2009-2014 show larger standard deviations and larger temporal variations; the standard deviations increase by ~5% in the troposphere and ~2% in the stratosphere. Retrieval biases at individual levels in the stratosphere and upper troposphere show statistically significant trends and different trends for 2004-2008 and 2009-2014 periods. The trends in integrated ozone partial columns are less significant due to cancellation from various layers, except for significant trend in tropical SOC. These results suggest the need to perform time dependent radiometric calibration to maintain the long-term stability of this product. Similarly, we are comparing the OMI stratospheric ozone profiles and SOC with collocated MLS data, and the results will be reported.

  15. Radiometric and spectral validation of Atmospheric Infrared Sounder observations with the aircraft-based Scanning High-Resolution Interferometer Sounder

    NASA Astrophysics Data System (ADS)

    Tobin, David C.; Revercomb, Henry E.; Knuteson, Robert O.; Best, Fred A.; Smith, William L.; Ciganovich, Nick N.; Dedecker, Ralph G.; Dutcher, Steven; Ellington, Scott D.; Garcia, Raymond K.; Howell, H. Benjamin; Laporte, Daniel D.; Mango, Stephen A.; Pagano, Thomas S.; Taylor, Joe K.; van Delst, Paul; Vinson, Kenneth H.; Werner, Mark W.

    2006-05-01

    The ability to accurately validate high-spectral resolution infrared radiance measurements from space using comparisons with a high-altitude aircraft spectrometer has been successfully demonstrated. The demonstration is based on a 21 November 2002 underflight of the AIRS on the NASA Aqua spacecraft by the Scanning-HIS on the NASA ER-2 high-altitude aircraft. A comparison technique which accounts for the different viewing geometries and spectral characteristics of the two sensors is introduced, and accurate comparisons are made for AIRS channels throughout the infrared spectrum. Resulting brightness temperature differences are found to be 0.2 K or less for most channels. Both the AIRS and the Scanning-HIS calibrations are expected to be very accurate (formal 3-sigma estimates are better than 1 K absolute brightness temperature for a wide range of scene temperatures), because high spectral resolution offers inherent advantages for absolute calibration and because they make use of high-emissivity cavity blackbodies as onboard radiometric references. AIRS also has the added advantage of a cold space view, and the Scanning-HIS calibration has recently benefited from the availability of a zenith view from high-altitude flights. Aircraft comparisons of this type provide a mechanism for periodically testing the absolute calibration of spacecraft instruments with instrumentation for which the calibration can be carefully maintained on the ground. This capability is especially valuable for assuring the long-term consistency and accuracy of climate observations, including those from the NASA EOS spacecraft (Terra, Aqua and Aura) and the new complement of NPOESS operational instruments. The validation role for accurately calibrated aircraft spectrometers also includes application to broadband instruments and linking the calibrations of similar instruments on different spacecraft. It is expected that aircraft flights of the Scanning-HIS and its close cousin the NPOESS Airborne Sounder Test Bed (NAST) will be used to check the long-term stability of AIRS and the NPOESS operational follow-on sounder, the Cross-track Infrared Sounder (CrIS), over the life of the missions.

  16. Calibrating a method for simulated long-term ageing of biochar

    NASA Astrophysics Data System (ADS)

    Sohi, Saran; Cross, Andrew

    2013-04-01

    We recently established a procedure that imposes oxidatiave ageing to biochar and charcoal samples over a short time-frame, that provided carbon mass loss in the range projected for wild-fire charcoal in soil over a period of approximately 100 years. The stability of biochar samples in soil (relative to charcoal) range from 45-98% could be determined repeatably with high precision. Initial tests to understand the kinetics of the accelerated ageing method showed progressive increase in surface O concentration when examined by X-ray photoelectron spectroscopy (XPS) that slowly reached equilibrium. These trends resembled patterns observed in climate-for-time studies elsewhere, on centennial time-frame. We have extended this work to a preliminary direct calibration by matching progressive oxidation achieved in the laboratory to the surface composition of charcoal fragments recovered from the environment after periods of hundred to thousands of years. We have also applied artificial ageing to the same sets of naturally pre-aged charcoal fragments, and to recreated fresh charcoal. In this presentation of the first approach to quantifiably relate a laboratory test for biochar carbon stability to field data covering multiple time scales, we report on both the process and the implications for the stability of carbon stored in biochar under different climates and diverse agro-ecosystems.

  17. The stability of the international oil trade network from short-term and long-term perspectives

    NASA Astrophysics Data System (ADS)

    Sun, Qingru; Gao, Xiangyun; Zhong, Weiqiong; Liu, Nairong

    2017-09-01

    To examine the stability of the international oil trade network and explore the influence of countries and trade relationships on the trade stability, we construct weighted and unweighted international oil trade networks based on complex network theory using oil trading data between countries from 1996 to 2014. We analyze the stability of international oil trade network (IOTN) from short-term and long-term aspects. From the short-term perspective, we find that the trade volumes play an important role on the stability. Moreover, the weighted IOTN is stable; however, the unweighted networks can better reflect the actual evolution of IOTN. From the long-term perspective, we identify trade relationships that are maintained during the whole sample period to reveal the situation of the whole international oil trade. We provide a way to quantitatively measure the stability of complex network from short-term and long-term perspectives, which can be applied to measure and analyze trade stability of other goods or services.

  18. Using a Tandem Pelletron accelerator to produce a thermal neutron beam for detector testing purposes.

    PubMed

    Irazola, L; Praena, J; Fernández, B; Macías, M; Bedogni, R; Terrón, J A; Sánchez-Nieto, B; Arias de Saavedra, F; Porras, I; Sánchez-Doblado, F

    2016-01-01

    Active thermal neutron detectors are used in a wide range of measuring devices in medicine, industry and research. For many applications, the long-term stability of these devices is crucial, so that very well controlled neutron fields are needed to perform calibrations and repeatability tests. A way to achieve such reference neutron fields, relying on a 3 MV Tandem Pelletron accelerator available at the CNA (Seville, Spain), is reported here. This paper shows thermal neutron field production and reproducibility characteristics over few days. Copyright © 2015 Elsevier Ltd. All rights reserved.

  19. New advances in non-dispersive IR technology for CO2 detection

    NASA Technical Reports Server (NTRS)

    Small, John W.; Odegard, Wayne L.

    1988-01-01

    This paper discusses new technology developments in CO2 detection using Non-Dispersive Infrared (NDIR) techniques. The method described has successfully been used in various applications and environments. It has exhibited extremely reliable long-term stability without the need of routine calibration. The analysis employs a dual wavelength, differential detection approach with compensating circuitry for component aging and dirt accumulation on optical surfaces. The instrument fails 'safe' and provides the operator with a 'fault' alarm in the event of a system failure. The NDIR analyzer described has been adapted to NASA Space Station requirements.

  20. A microcomputer-based whole-body counter for personnel routine monitoring.

    PubMed

    Chou, H P; Tsai, T M; Lan, C Y

    1993-05-01

    The paper describes a cost-effective NaI(Tl) whole-body counter developed for routine examinations of worker intakes at an isotope production facility. Signal processing, data analysis and system operation are microcomputer-controlled for minimum human interactions. The pulse height analyzer is developed as an microcomputer add-on card for easy manipulation. The scheme for radionuclide analysis is aimed for fast running according to a knowledge base established from background samples and phantom experiments in conjunction with a multivariate regression analysis. Long-term stability and calibration with standards and in vivo measurements are reported.

  1. Validation of Atmospheric InfraRed Sounder (AIRS) spectral radiances with the Scanning High-resolution Interferometer Sounder (S-HIS) aircraft instrument

    NASA Astrophysics Data System (ADS)

    Tobin, David C.; Revercomb, Henry E.; Moeller, Chris C.; Knuteson, Robert O.; Best, Fred A.; Smith, William L.; van Delst, Paul; LaPorte, Daniel D.; Ellington, Scott D.; Werner, Mark D.; Dedecker, Ralph G.; Garcia, Raymond K.; Ciganovich, Nick N.; Howell, Hugh B.; Dutcher, Steven B.; Taylor, Joe K.

    2004-11-01

    The ability to accurately validate high spectral resolution infrared radiance measurements from space using comparisons with aircraft spectrometer observations has been successfully demonstrated. The demonstration is based on an under-flight of the Atmospheric Infrared Sounder (AIRS) on the NASA Aqua spacecraft by the Scanning High resolution Interferometer Sounder (S-HIS) on the NASA ER-2 high altitude aircraft on 21 November 2002 and resulted in brightness temperature differences approaching 0.1K for most of the spectrum. This paper presents the details of this AIRS/S-HIS validation case and also presents comparisons of Aqua AIRS and Moderate Resolution Imaging Spectroradiometer (MODIS) radiance observations. Aircraft comparisons of this type provide a mechanism for periodically testing the absolute calibration of spacecraft instruments with instrumentation for which the calibration can be carefully maintained on the ground. This capability is especially valuable for assuring the long-term consistency and accuracy of climate observations. It is expected that aircraft flights of the S-HIS and its close cousin the National Polar Orbiting Environmental Satellite System (NPOESS) Atmospheric Sounder Testbed (NAST) will be used to check the long-term stability of the NASA EOS spacecrafts (Terra, Aqua and Aura) and the follow-on complement of operational instruments, including the Cross-track Infrared Sounder (CrIS).

  2. Laser frequency stabilization by combining modulation transfer and frequency modulation spectroscopy.

    PubMed

    Zi, Fei; Wu, Xuejian; Zhong, Weicheng; Parker, Richard H; Yu, Chenghui; Budker, Simon; Lu, Xuanhui; Müller, Holger

    2017-04-01

    We present a hybrid laser frequency stabilization method combining modulation transfer spectroscopy (MTS) and frequency modulation spectroscopy (FMS) for the cesium D2 transition. In a typical pump-probe setup, the error signal is a combination of the DC-coupled MTS error signal and the AC-coupled FMS error signal. This combines the long-term stability of the former with the high signal-to-noise ratio of the latter. In addition, we enhance the long-term frequency stability with laser intensity stabilization. By measuring the frequency difference between two independent hybrid spectroscopies, we investigate the short-and long-term stability. We find a long-term stability of 7.8 kHz characterized by a standard deviation of the beating frequency drift over the course of 10 h and a short-term stability of 1.9 kHz characterized by an Allan deviation of that at 2 s of integration time.

  3. The effect of accelerated aging on the wear of UHMWPE.

    PubMed

    Sakoda, H; Fisher, J; Lu, S; Buchanan, F

    2001-01-01

    Oxidative degradation of UHMWPE has been found to be a cause of elevated wear rate of the polymer in total joint replacement leading to failure of these devices. In order to evaluate long term stability of polymers, various accelerated aging methods have been developed. In this study, wear rates of shelf aged UHMWPE and "accelerated aged" UHMWPE were compared using a multi-directional pin-on-plate wear test machine in order to evaluate the effect of the accelerated aging on wear. Wear factors of the aged materials were found to depend on their density, which is a measure of oxidation level. Finally, accelerated aging was calibrated against shelf aging in terms of wear rate. Copyright 2001 Kluwer Academic Publishers

  4. How Long Do Satellites Need to Overlap? Evaluation of Climate Data Stability from Overlapping Satellite Records

    NASA Technical Reports Server (NTRS)

    Weatherhead, Elizabeth C.; Harder, Jerald; Araujo-Pradere, Eduardo A.; Bodeker, Greg; English, Jason M.; Flynn, Lawrence E.; Frith, Stacey M.; Lazo, Jeffrey K.; Pilewskie, Peter; Weber, Mark; hide

    2017-01-01

    Sensors on satellites provide unprecedented understanding of the Earth's climate system by measuring incoming solar radiation, as well as both passive and active observations of the entire Earth with outstanding spatial and temporal coverage. A common challenge with satellite observations is to quantify their ability to provide well-calibrated, long-term, stable records of the parameters they measure. Ground-based intercomparisons offer some insight, while reference observations and internal calibrations give further assistance for understanding long-term stability. A valuable tool for evaluating and developing long-term records from satellites is the examination of data from overlapping satellite missions. This paper addresses how the length of overlap affects the ability to identify an offset or a drift in the overlap of data between two sensors. Ozone and temperature data sets are used as examples showing that overlap data can differ by latitude and can change over time. New results are presented for the general case of sensor overlap by using Solar Radiation and Climate Experiment (SORCE) Spectral Irradiance Monitor (SIM) and Solar Stellar Irradiance Comparison Experiment (SOLSTICE) solar irradiance data as an example. To achieve a 1 % uncertainty in estimating the offset for these two instruments' measurement of the Mg II core (280 nm) requires approximately 5 months of overlap. For relative drift to be identified within 0.1 %/yr uncertainty (0.00008 W/sq m/nm/yr), the overlap for these two satellites would need to be 2.5 years. Additional overlap of satellite measurements is needed if, as is the case for solar monitoring, unexpected jumps occur adding uncertainty to both offsets and drifts; the additional length of time needed to account for a single jump in the overlap data may be as large as 50 % of the original overlap period in order to achieve the same desired confidence in the stability of the merged data set. Results presented here are directly applicable to satellite Earth observations. Approaches for Earth observations offer additional challenges due to the complexity of the observations, but Earth observations may also benefit from ancillary observations taken from ground-based and in situ sources. Difficult choices need to be made when monitoring approaches are considered; we outline some attempts at optimizing networks based on economic principles. The careful evaluation of monitoring overlap is important to the appropriate application of observational resources and to the usefulness of current and future observations.

  5. How long do satellites need to overlap? Evaluation of climate data stability from overlapping satellite records

    NASA Astrophysics Data System (ADS)

    Weatherhead, Elizabeth C.; Harder, Jerald; Araujo-Pradere, Eduardo A.; Bodeker, Greg; English, Jason M.; Flynn, Lawrence E.; Frith, Stacey M.; Lazo, Jeffrey K.; Pilewskie, Peter; Weber, Mark; Woods, Thomas N.

    2017-12-01

    Sensors on satellites provide unprecedented understanding of the Earth's climate system by measuring incoming solar radiation, as well as both passive and active observations of the entire Earth with outstanding spatial and temporal coverage. A common challenge with satellite observations is to quantify their ability to provide well-calibrated, long-term, stable records of the parameters they measure. Ground-based intercomparisons offer some insight, while reference observations and internal calibrations give further assistance for understanding long-term stability. A valuable tool for evaluating and developing long-term records from satellites is the examination of data from overlapping satellite missions. This paper addresses how the length of overlap affects the ability to identify an offset or a drift in the overlap of data between two sensors. Ozone and temperature data sets are used as examples showing that overlap data can differ by latitude and can change over time. New results are presented for the general case of sensor overlap by using Solar Radiation and Climate Experiment (SORCE) Spectral Irradiance Monitor (SIM) and Solar Stellar Irradiance Comparison Experiment (SOLSTICE) solar irradiance data as an example. To achieve a 1 % uncertainty in estimating the offset for these two instruments' measurement of the Mg II core (280 nm) requires approximately 5 months of overlap. For relative drift to be identified within 0.1 % yr-1 uncertainty (0.00008 W m-2 nm-1 yr-1), the overlap for these two satellites would need to be 2.5 years. Additional overlap of satellite measurements is needed if, as is the case for solar monitoring, unexpected jumps occur adding uncertainty to both offsets and drifts; the additional length of time needed to account for a single jump in the overlap data may be as large as 50 % of the original overlap period in order to achieve the same desired confidence in the stability of the merged data set. Results presented here are directly applicable to satellite Earth observations. Approaches for Earth observations offer additional challenges due to the complexity of the observations, but Earth observations may also benefit from ancillary observations taken from ground-based and in situ sources. Difficult choices need to be made when monitoring approaches are considered; we outline some attempts at optimizing networks based on economic principles. The careful evaluation of monitoring overlap is important to the appropriate application of observational resources and to the usefulness of current and future observations.

  6. Evaluation of VIIRS and MODIS Thermal Emissive Band Calibration Stability Using Ground Target

    NASA Technical Reports Server (NTRS)

    Madhavan, Sriharsha; Brinkmann, Jake; Wenny, Brian N.; Wu, Aisheng; Xiong, Xiaoxiong

    2017-01-01

    The S-NPP Visible Infrared Imaging Radiometer Suite (VIIRS) instrument, a polar orbiting Earth remote sensing instrument built using a strong MODIS background, employs a similarly designed on-board calibrating source - a V-grooved blackbody for the thermal emissive bands (TEB). The central wavelengths of most VIIRS TEBs are very close to those of MODIS with the exception of the 10.7 micron channel. To ensure the long term continuity of climate data records derived using VIIRS and MODIS TEB, it is necessary to assess any systematic differences between the two instruments, including scenes with temperatures significantly lower than blackbody operating temperatures at approximately 290 K. Previous work performed by the MODIS Characterization Support Team (MCST) at NASAGSFC used the frequent observations of the Dome Concordia site located in Antarctica to evaluate the calibration stability and consistency of Terra and Aqua MODIS over the mission lifetime. The near-surface temperature measurements from an automatic weather station (AWS) provide a direct reference useful for tracking the stability and determining the relative bias between the two MODIS instruments. In this study, the same technique is applied to the VIIRS TEB and the results are compared with those from the matched MODIS TEB. The results of this study show a small negative bias when comparing the matching VIIRS and Aqua MODIS TEB, implying a higher scene temperature retrieval for S-VIIRS at the cold end. Statistically no significant drift is observed for VIIRS TEB performance over the first 3.5 years of the mission.

  7. Ultrastable low-noise current amplifier: a novel device for measuring small electric currents with high accuracy.

    PubMed

    Drung, D; Krause, C; Becker, U; Scherer, H; Ahlers, F J

    2015-02-01

    An ultrastable low-noise current amplifier (ULCA) is presented. The ULCA is a non-cryogenic instrument based on specially designed operational amplifiers and resistor networks. It involves two stages, the first providing a 1000-fold current gain and the second performing a current-to-voltage conversion via an internal 1 MΩ reference resistor or, optionally, an external standard resistor. The ULCA's transfer coefficient is highly stable versus time, temperature, and current amplitude within the full dynamic range of ±5 nA. The low noise level of 2.4 fA/√Hz helps to keep averaging times short at small input currents. A cryogenic current comparator is used to calibrate both input current gain and output transresistance, providing traceability to the quantum Hall effect. Within one week after calibration, the uncertainty contribution from short-term fluctuations and drift of the transresistance is about 0.1 parts per million (ppm). The long-term drift is typically 5 ppm/yr. A high-accuracy variant is available that shows improved stability of the input gain at the expense of a higher noise level of 7.5 fA/√Hz. The ULCA also allows the traceable generation of small electric currents or the calibration of high-ohmic resistors.

  8. Ultrastable low-noise current amplifier: A novel device for measuring small electric currents with high accuracy

    NASA Astrophysics Data System (ADS)

    Drung, D.; Krause, C.; Becker, U.; Scherer, H.; Ahlers, F. J.

    2015-02-01

    An ultrastable low-noise current amplifier (ULCA) is presented. The ULCA is a non-cryogenic instrument based on specially designed operational amplifiers and resistor networks. It involves two stages, the first providing a 1000-fold current gain and the second performing a current-to-voltage conversion via an internal 1 MΩ reference resistor or, optionally, an external standard resistor. The ULCA's transfer coefficient is highly stable versus time, temperature, and current amplitude within the full dynamic range of ±5 nA. The low noise level of 2.4 fA/√Hz helps to keep averaging times short at small input currents. A cryogenic current comparator is used to calibrate both input current gain and output transresistance, providing traceability to the quantum Hall effect. Within one week after calibration, the uncertainty contribution from short-term fluctuations and drift of the transresistance is about 0.1 parts per million (ppm). The long-term drift is typically 5 ppm/yr. A high-accuracy variant is available that shows improved stability of the input gain at the expense of a higher noise level of 7.5 fA/√Hz. The ULCA also allows the traceable generation of small electric currents or the calibration of high-ohmic resistors.

  9. OMPS SDR Calibration and Validation

    NASA Astrophysics Data System (ADS)

    Sen, B.; Done, J.; Buss, R.; Jaross, G. R.; Kelly, T. J.

    2009-12-01

    The Ozone Mapper and Profiler Suite (OMPS) is scheduled to be launched on the NPOESS Preparatory Project (NPP) platform in early 2011. The OMPS will continue monitoring ozone from space, using three instruments, namely the Total Column Mapper (heritage: TOMS), the Nadir Profiler (heritage: SBUV) and the Limb Profiler (heritage: SOLSE/LORE). The Total Column Mapper (TC) sensor images the Earth through a slit, nadir-cell horizontally spaced at 49.5 km cross-track with an along-track reporting interval of 50 km. The total field of view (FOV) cross-track is 110 degree to provide daily global coverage. The TC sensor, a grating spectrometer, provides 0.45 nm spectral sampling across the wavelength range of 300-380 nm. The calibration stability, which is essential to enable long-term ozone monitoring, is maintained by periodic observations of the Sun, using a diffuser to redirect the solar irradiance into the sensor. We describe the plans to calibrate the TC sensor and validate the radiance data (TC Sensor Data Record or TC SDR) after launch. We discuss the measurements planned during the Intensive Cal/Val (ICV) phase of NPP mission, the data analysis methodology and results from the analysis of OMPS calibration measurements.

  10. Improvement in QEPAS system utilizing a second harmonic based wavelength calibration technique

    NASA Astrophysics Data System (ADS)

    Zhang, Qinduan; Chang, Jun; Wang, Fupeng; Wang, Zongliang; Xie, Yulei; Gong, Weihua

    2018-05-01

    A simple laser wavelength calibration technique, based on second harmonic signal, is demonstrated in this paper to improve the performance of quartz enhanced photoacoustic spectroscopy (QEPAS) gas sensing system, e.g. improving the signal to noise ratio (SNR), detection limit and long-term stability. Constant current, corresponding to the gas absorption line, combining f/2 frequency sinusoidal signal are used to drive the laser (constant driving mode), a software based real-time wavelength calibration technique is developed to eliminate the wavelength drift due to ambient fluctuations. Compared to conventional wavelength modulation spectroscopy (WMS), this method allows lower filtering bandwidth and averaging algorithm applied to QEPAS system, improving SNR and detection limit. In addition, the real-time wavelength calibration technique guarantees the laser output is modulated steadily at gas absorption line. Water vapor is chosen as an objective gas to evaluate its performance compared to constant driving mode and conventional WMS system. The water vapor sensor was designed insensitive to the incoherent external acoustic noise by the numerical averaging technique. As a result, the SNR increases 12.87 times in wavelength calibration technique based system compared to conventional WMS system. The new system achieved a better linear response (R2 = 0 . 9995) in concentration range from 300 to 2000 ppmv, and achieved a minimum detection limit (MDL) of 630 ppbv.

  11. Bore-sight calibration of the profile laser scanner using a large size exterior calibration field

    NASA Astrophysics Data System (ADS)

    Koska, Bronislav; Křemen, Tomáš; Štroner, Martin

    2014-10-01

    The bore-sight calibration procedure and results of a profile laser scanner using a large size exterior calibration field is presented in the paper. The task is a part of Autonomous Mapping Airship (AMA) project which aims to create s surveying system with specific properties suitable for effective surveying of medium-wide areas (units to tens of square kilometers per a day). As is obvious from the project name an airship is used as a carrier. This vehicle has some specific properties. The most important properties are high carrying capacity (15 kg), long flight time (3 hours), high operating safety and special flight characteristics such as stability of flight, in terms of vibrations, and possibility to flight at low speed. The high carrying capacity enables using of high quality sensors like professional infrared (IR) camera FLIR SC645, high-end visible spectrum (VIS) digital camera and optics in the visible spectrum and tactical grade INSGPS sensor iMAR iTracerRT-F200 and profile laser scanner SICK LD-LRS1000. The calibration method is based on direct laboratory measuring of coordinate offset (lever-arm) and in-flight determination of rotation offsets (bore-sights). The bore-sight determination is based on the minimization of squares of individual point distances from measured planar surfaces.

  12. A zero-augmented generalized gamma regression calibration to adjust for covariate measurement error: A case of an episodically consumed dietary intake

    PubMed Central

    Agogo, George O.

    2017-01-01

    Measurement error in exposure variables is a serious impediment in epidemiological studies that relate exposures to health outcomes. In nutritional studies, interest could be in the association between long-term dietary intake and disease occurrence. Long-term intake is usually assessed with food frequency questionnaire (FFQ), which is prone to recall bias. Measurement error in FFQ-reported intakes leads to bias in parameter estimate that quantifies the association. To adjust for bias in the association, a calibration study is required to obtain unbiased intake measurements using a short-term instrument such as 24-hour recall (24HR). The 24HR intakes are used as response in regression calibration to adjust for bias in the association. For foods not consumed daily, 24HR-reported intakes are usually characterized by excess zeroes, right skewness, and heteroscedasticity posing serious challenge in regression calibration modeling. We proposed a zero-augmented calibration model to adjust for measurement error in reported intake, while handling excess zeroes, skewness, and heteroscedasticity simultaneously without transforming 24HR intake values. We compared the proposed calibration method with the standard method and with methods that ignore measurement error by estimating long-term intake with 24HR and FFQ-reported intakes. The comparison was done in real and simulated datasets. With the 24HR, the mean increase in mercury level per ounce fish intake was about 0.4; with the FFQ intake, the increase was about 1.2. With both calibration methods, the mean increase was about 2.0. Similar trend was observed in the simulation study. In conclusion, the proposed calibration method performs at least as good as the standard method. PMID:27704599

  13. Instrument development and field application of the in situ pH Calibrator at the Ocean Observatory

    NASA Astrophysics Data System (ADS)

    Tan, C.; Ding, K.; Seyfried, W. E.

    2012-12-01

    A novel, self-calibrating instrument for in-situ measurement of pH in deep sea environments up to 4000 m has recently been developed. The device utilizes a compact fluid delivery system to perform measurement and two-point calibration of the solid state pH sensor array (Ir|IrOx| Ag|AgCl), which is sealed in a flow cell to enhance response time. The fluid delivery system is composed of a metering pump and valves, which periodically deliver seawater samples into the flow cell to perform measurements. Similarly, pH buffer solutions can be delivered into the flow cell to calibrate the electrodes under operational conditions. Sensor signals are acquired and processed by a high resolution (0.25 mV) datalogger circuit with a size of 114 mm×31 mm×25 mm. Eight input channels are available: two high impedance sensor input channels, two low impedance sensor input channel, two thermocouple input channels and two thermistor input channels. These eight channels provide adequate measurement flexibility to enhance applications in deep sea environments. The two high impedance channels of the datalogger are especially designed with the input impedance of 1016 Ω for YSZ (yittria-stabilized zirconia) ceramic electrodes characterized by the extremely low input bias current and high resistance. Field tests have been performed in 2008 by ROV at the depth up to 3200 m. Using the continuous power supply and TCP/IP network capability of the Monterey Accelerated Research System (MARS) ocean observatory, the so-called "pH Calibrator" has the capability of long term operation up to six months. In the observatory mode, the electronics are configured with DC-DC power converter modules and Ethernet to serial module to gain access to the science port of seafloor junction box. The pH Calibrator will be deployed at the ocean observatory in October and the in situ data will be on line on the internet. The pH Calibrator presents real time pH data at high pressures and variable temperatures, while the in situ calibration capability enhances the accuracy of electrochemical measurements of seawater pH, fulfilling the need for long term objectives for marine studies.

  14. Development and Performance of a Filter Radiometer Monitor System for Integrating Sphere Sources

    NASA Technical Reports Server (NTRS)

    Ding, Leibo; Kowalewski, Matthew G.; Cooper, John W.; Smith, GIlbert R.; Barnes, Robert A.; Waluschka, Eugene; Butler, James J.

    2011-01-01

    The NASA Goddard Space Flight Center (GSFC) Radiometric Calibration Laboratory (RCL) maintains several large integrating sphere sources covering the visible to the shortwave infrared wavelength range. Two critical, functional requirements of an integrating sphere source are short and long-term operational stability and repeatability. Monitoring the source is essential in determining the origin of systemic errors, thus increasing confidence in source performance and quantifying repeatability. If monitor data falls outside the established parameters, this could be an indication that the source requires maintenance or re-calibration against the National Institute of Science and Technology (NIST) irradiance standard. The GSFC RCL has developed a Filter Radiometer Monitoring System (FRMS) to continuously monitor the performance of its integrating sphere calibration sources in the 400 to 2400nm region. Sphere output change mechanisms include lamp aging, coating (e.g. BaSO4) deterioration, and ambient water vapor level. The Filter Radiometer Monitor System (FRMS) wavelength bands are selected to quantify changes caused by these mechanisms. The FRMS design and operation are presented, as well as data from monitoring four of the RCL s integrating sphere sources.

  15. Reduced Kalman Filters for Clock Ensembles

    NASA Technical Reports Server (NTRS)

    Greenhall, Charles A.

    2011-01-01

    This paper summarizes the author's work ontimescales based on Kalman filters that act upon the clock comparisons. The natural Kalman timescale algorithm tends to optimize long-term timescale stability at the expense of short-term stability. By subjecting each post-measurement error covariance matrix to a non-transparent reduction operation, one obtains corrected clocks with improved short-term stability and little sacrifice of long-term stability.

  16. Therapeutic drug monitoring of beta-lactam antibiotics - Influence of sample stability on the analysis of piperacillin, meropenem, ceftazidime and flucloxacillin by HPLC-UV.

    PubMed

    Pinder, Nadine; Brenner, Thorsten; Swoboda, Stefanie; Weigand, Markus A; Hoppe-Tichy, Torsten

    2017-09-05

    Therapeutic drug monitoring (TDM) is a useful tool to optimize antibiotic therapy. Increasing interest in alternative dosing strategies of beta-lactam antibiotics, e.g. continuous or prolonged infusion, require a feasible analytical method for quantification of these antimicrobial agents. However, pre-analytical issues including sample handling and stability are to be considered to provide valuable analytical results. For the simultaneous determination of piperacillin, meropenem, ceftazidime and flucloxacillin, a high performance liquid chromatography (HPLC) method including protein precipitation was established utilizing ertapenem as internal standard. Long-term stability of stock solutions and plasma samples were monitored. Furthermore, whole blood stability of the analytes in heparinized blood tubes was investigated comparing storage under ambient conditions and 2-8°C. A calibration range of 5-200μg/ml (piperacillin, ceftazidime, flucloxacillin) and 2-200μg/ml (meropenem) was linear with r 2 >0.999, precision and inaccuracy were <9% and <11%, respectively. The successfully validated HPLC assay was applied to clinical samples and stability investigations. At -80°C, plasma samples were stable for 9 months (piperacillin, meropenem) or 13 months (ceftazidime, flucloxacillin). Concentrations of the four beta-lactam antibiotics in whole blood tubes were found to remain within specifications for 8h when stored at 2-8°C but not at room temperature. The presented method is a rapid and simple option for routine TDM of piperacillin, meropenem, ceftazidime and flucloxacillin. Whereas long-term storage of beta-lactam samples at -80°C is possible for at least 9 months, whole blood tubes are recommended to be kept refrigerated until analysis. Copyright © 2017 Elsevier B.V. All rights reserved.

  17. An integrated CAD/CAM/robotic milling method for custom cementless femoral prostheses.

    PubMed

    Wen-ming, Xi; Ai-min, Wang; Qi, Wu; Chang-hua, Liu; Jian-fei, Zhu; Fang-fang, Xia

    2015-09-01

    Aseptic loosening is the primary cause of cementless femoral prosthesis failure and is related to the primary stability of the cementless femoral prosthesis in the femoral cavity. The primary stability affects both the osseointegration and the long-term stability of cementless femoral prostheses. A custom cementless femoral prosthesis can improve the fit and fill of the prosthesis in the femoral cavity and decrease the micromotion of the proximal prosthesis such that the primary stability of the custom prosthesis can be improved, and osseointegration of the proximal prosthesis is achieved. These results will help to achieve long-term stability in total hip arthroplasty (THA). In this paper, we introduce an integrated CAD/CAM/robotic method of milling custom cementless femoral prostheses. The 3D reconstruction model uses femoral CT images and 3D design software to design a CAD model of the custom prosthesis. After the transformation matrices between two units of the robotic system are calibrated, consistency between the CAM software and the robotic system can be achieved, and errors in the robotic milling can be limited. According to the CAD model of the custom prosthesis, the positions of the robotic tool points are produced by the CAM software of the CNC machine. The normal vector of the three adjacent robotic tool point positions determines the pose of the robotic tool point. In conclusion, the fit rate of custom pig femur stems in the femoral cavities was 90.84%. After custom femoral prostheses were inserted into the femoral cavities, the maximum gaps between the prostheses and the cavities measured less than 1 mm at the diaphysis and 1.3 mm at the metaphysis. Copyright © 2015 IPEM. Published by Elsevier Ltd. All rights reserved.

  18. Intraindividual stability of cortisol and cortisone and the ratio of cortisol to cortisone in saliva, urine and hair.

    PubMed

    Zhang, Quan; Chen, Zheng; Chen, Shenghuo; Xu, Youyun; Deng, Huihua

    2017-02-01

    Cortisol, cortisone and the ratio of cortisol to cortisone in saliva, urine and hair are acute, short-term and long-term biomarkers to reliably assess the activity of hypothalamic-pituitary-adrenal (HPA) axis and 11β-hydroxysteroid dehydrogenase (11β-HSD). One key issue is whether these biomarkers have intraindividual relative stability. Salivary, urinary and hair cortisol was proven to show considerable long-term intraindividual relative stability. However, currently unknown is whether cortisone and the ratio in saliva, urine and hair show intraindividual relative stability. The present study utilized a longitudinal design to validate long-term stability within two weeks of three biomarkers in saliva and urine, and long-term stability within twelve months of three hair biomarkers. Salivary, urinary and hair steroids were measured with high performance liquid chromatography tandem mass spectrometry. Three biomarkers in urine and hair showed moderate test-retest correlations with coefficient (r) ranging between 0.22 and 0.56 and good multiple-test consistencies with coefficient of intraclass correlation (ICC) ranging between 0.42 and 0.67. Three single-point salivary biomarkers showed weak to moderate test-retest correlations (r's between 0.01 and 0.38) and poor to fair multiple-test consistencies (ICC's between 0.29 and 0.53) within two weeks. Three single-day salivary biomarkers showed moderate test-retest correlations (r's between 0.23 and 0.53) and good multiple-test consistencies (ICC's between 0.56 and 0.66) within two weeks. Three biomarkers in urine and hair showed moderate long-term intraindividual relative stability. Three single-point salivary biomarkers showed weak to moderate short-term and long-term intraindividual relative stability, but three single-day salivary biomarkers showed moderate short-term and long-term intraindividual relative stability. Copyright © 2016 Elsevier Inc. All rights reserved.

  19. Unprecedented long-term frequency stability with a microwave resonator oscillator.

    PubMed

    Grop, Serge; Schafer, Wolfgang; Bourgeois, Pierre-Yves; Kersale, Yann; Oxborrow, Mark; Rubiola, Enrico; Giordano, Vincent

    2011-08-01

    This article reports on the long-term frequency stability characterization of a new type of cryogenic sapphire oscillator using an autonomous pulse-tube cryocooler as its cold source. This new design enables a relative frequency stability of better than 4.5 x 10(-15) over one day of integration. To the best of our knowledge, this represents the best long-term frequency stability ever obtained with a signal source based on a macroscopic resonator.

  20. Bundle Adjustment-Based Stability Analysis Method with a Case Study of a Dual Fluoroscopy Imaging System

    NASA Astrophysics Data System (ADS)

    Al-Durgham, K.; Lichti, D. D.; Detchev, I.; Kuntze, G.; Ronsky, J. L.

    2018-05-01

    A fundamental task in photogrammetry is the temporal stability analysis of a camera/imaging-system's calibration parameters. This is essential to validate the repeatability of the parameters' estimation, to detect any behavioural changes in the camera/imaging system and to ensure precise photogrammetric products. Many stability analysis methods exist in the photogrammetric literature; each one has different methodological bases, and advantages and disadvantages. This paper presents a simple and rigorous stability analysis method that can be straightforwardly implemented for a single camera or an imaging system with multiple cameras. The basic collinearity model is used to capture differences between two calibration datasets, and to establish the stability analysis methodology. Geometric simulation is used as a tool to derive image and object space scenarios. Experiments were performed on real calibration datasets from a dual fluoroscopy (DF; X-ray-based) imaging system. The calibration data consisted of hundreds of images and thousands of image observations from six temporal points over a two-day period for a precise evaluation of the DF system stability. The stability of the DF system - for a single camera analysis - was found to be within a range of 0.01 to 0.66 mm in terms of 3D coordinates root-mean-square-error (RMSE), and 0.07 to 0.19 mm for dual cameras analysis. It is to the authors' best knowledge that this work is the first to address the topic of DF stability analysis.

  1. Spurious changes in the ISCCP dataset

    NASA Technical Reports Server (NTRS)

    Klein, Stephen A.; Hartmann, Dennis L.

    1993-01-01

    The International Satellite Cloud Climatology Project (ISCCP) data set for July 1983-December 1990 exhibits a long term decrease in mean cloud optical depth and mean cloudtop temperature which is large compared to the mean for this period. It is here suggested that this decrease is an artifact of incomplete normalization of the visible channel on successive polar orbiters employed as the ISCCP's calibration standard; more accurate calibration techniques are required for the establishment of long-term climate trends.

  2. Promoting Healthy Weight with "Stability Skills First": A Randomized Trial

    ERIC Educational Resources Information Center

    Kiernan, Michaela; Brown, Susan D.; Schoffman, Danielle E.; Lee, Katherine; King, Abby C.; Taylor, C. Barr; Schleicher, Nina C.; Perri, Michael G.

    2013-01-01

    Objective: Although behavioral weight-loss interventions produce short-term weight loss, long-term maintenance remains elusive. This randomized trial examined whether learning a novel set of "stability skills" before losing weight improved long-term weight management. Stability skills were designed to optimize individuals' current…

  3. Improved Band-to-Band Registration Characterization for VIIRS Reflective Solar Bands Based on Lunar Observations

    NASA Technical Reports Server (NTRS)

    Wang, Zhipeng; Xiong, Xiaoxiong; Li, Yonghong

    2015-01-01

    Spectral bands of the Visible Infrared Imaging Radiometer Suite (VIIRS) instrumentaboard the Suomi National Polar-orbiting Partnership (S-NPP) satellite are spatially co-registered.The accuracy of the band-to-band registration (BBR) is one of the key spatial parameters that must becharacterized. Unlike its predecessor, the Moderate Resolution Imaging Spectroradiometer (MODIS), VIIRS has no on-board calibrator specifically designed to perform on-orbit BBR characterization.To circumvent this problem, a BBR characterization method for VIIRS reflective solar bands (RSB) based on regularly-acquired lunar images has been developed. While its results can satisfactorily demonstrate that the long-term stability of the BBR is well within +/- 0.1 moderate resolution bandpixels, undesired seasonal oscillations have been observed in the trending. The oscillations are most obvious between the visiblenear-infrared bands and short-middle wave infrared bands. This paper investigates the oscillations and identifies their cause as the band spectral dependence of the centroid position and the seasonal rotation of the lunar images over calibration events. Accordingly, an improved algorithm is proposed to quantify the rotation and compensate for its impact. After the correction, the seasonal oscillation in the resulting BBR is reduced from up to 0.05 moderate resolution band pixels to around 0.01 moderate resolution band pixels. After removing this spurious seasonal oscillation, the BBR, as well as its long-term drift are well determined.

  4. Emerging Techniques for Vicarious Calibration of Visible Through Short Wave Infrared Remote Sensing Systems

    NASA Technical Reports Server (NTRS)

    Ryan, Robert E.; Harrington, Gary; Holekamp, Kara; Pagnutti, Mary; Russell, Jeffrey; Frisbie, Troy; Stanley, Thomas

    2007-01-01

    Autonomous Visible to SWIR ground-based vicarious Cal/Val will be an essential Cal/Val component with such a large number of systems. Radiometrically calibrated spectroradiometers can improve confidence in current ground truth data through validation of radiometric modeling and validation or replacement of traditional sun photometer measurement. They also should enable significant reduction in deployed equipment such as equipment used in traditional sun photometer approaches. Simple, field-portable, white-light LED calibration source shows promise for visible range (420-750 nm). Prototype demonstrated <0.5% drift over 10-40 C temperature range. Additional complexity (more LEDs) will be necessary for extending spectral range into the NIR and SWIR. LED long lifetimes should produce at least several hundreds of hours or more of stability, minimizing the need for expensive calibrations and supporting long-duration field campaigns.

  5. Long term pavement performance program protocol for calibrating traffic data collection equipment

    DOT National Transportation Integrated Search

    1998-05-10

    This document describes the procedures that the Long Term Pavement Performance (LTPP) program recommends for ensuring that traffic data collection equipment used for LTPP traffic monitoring efforts operates correctly and collects valid data.

  6. Long term stability following genioplasty: a cephalometric study.

    PubMed

    Kumar, B Lakshman; Raju, G Kranthi Praveen; Kumar, N Dilip; Reddy, G Vivek; Naik, B Ravindra; Achary, C Ravindranath

    2015-04-01

    A receding chin associated with an orthognathic mandible is a common situation and surgical changes in chin position are often required to improve the overall harmony of the face. Genioplasty is one such procedure. Stability of hard and soft tissue changes following genioplasty on a long term basis needs to be assessed. Studies on the stability of hard and soft tissue changes following genioplasty on a short term basis have revealed it as a procedure with good stability. This study is done to assess the stability of hard and soft tissue changes following genioplasty on a long term basis. Pre-surgical, postsurgical and long term post-surgical cephalograms of 15 cases treated by vertical reduction augmentation genioplasty were obtained. Paired t-test was used to compare the changes between pre-surgical, postsurgical and long term postsurgical cephalograms. Findings of this study demonstrated that genioplasty is a stable procedure. After long term follow-up period, there was a relapse of 1.5 mm at the pogonion accounting for 24% of the surgical advancement. This is attributed to the remodeling that occurs at the surgical site, but not the instability due to the surgical procedure. With the present study, it can be concluded that vertical reduction and advancement genioplasty can be considered as an adjunctive procedure that produces predictable results and the bony and soft tissue stability were generally very good.

  7. Long Term Stability Following Genioplasty: A Cephalometric Study

    PubMed Central

    Kumar, B Lakshman; Raju, G Kranthi Praveen; Kumar, N Dilip; Reddy, G Vivek; Naik, B Ravindra; Achary, C Ravindranath

    2015-01-01

    Background: A receding chin associated with an orthognathic mandible is a common situation and surgical changes in chin position are often required to improve the overall harmony of the face. Genioplasty is one such procedure. Stability of hard and soft tissue changes following genioplasty on a long term basis needs to be assessed. Studies on the stability of hard and soft tissue changes following genioplasty on a short term basis have revealed it as a procedure with good stability. This study is done to assess the stability of hard and soft tissue changes following genioplasty on a long term basis. Materials and Methods: Pre-surgical, postsurgical and long term post-surgical cephalograms of 15 cases treated by vertical reduction augmentation genioplasty were obtained. Paired t-test was used to compare the changes between pre-surgical, postsurgical and long term postsurgical cephalograms. Results: Findings of this study demonstrated that genioplasty is a stable procedure. After long term follow-up period, there was a relapse of 1.5 mm at the pogonion accounting for 24% of the surgical advancement. This is attributed to the remodeling that occurs at the surgical site, but not the instability due to the surgical procedure. Conclusion: With the present study, it can be concluded that vertical reduction and advancement genioplasty can be considered as an adjunctive procedure that produces predictable results and the bony and soft tissue stability were generally very good. PMID:25954070

  8. Global and regional trends of aerosol optical depth over land and ocean using SeaWiFS measurements from 1997 to 2010

    NASA Astrophysics Data System (ADS)

    Hsu, N. C.; Gautam, R.; Sayer, A. M.; Bettenhausen, C.; Li, C.; Jeong, M. J.; Tsay, S.-C.; Holben, B. N.

    2012-09-01

    Both sensor calibration and satellite retrieval algorithm play an important role in the ability to determine accurately long-term trends from satellite data. Owing to the unprecedented accuracy and long-term stability of its radiometric calibration, SeaWiFS measurements exhibit minimal uncertainty with respect to sensor calibration. In this study, we take advantage of this well-calibrated set of measurements by applying a newly-developed aerosol optical depth (AOD) retrieval algorithm over land and ocean to investigate the distribution of AOD, and to identify emerging patterns and trends in global and regional aerosol loading during its 13-yr mission. Our correlation analysis between climatic indices (such as ENSO) and AOD suggests strong relationships for Saharan dust export as well as biomass-burning activity in the tropics, associated with large-scale feedbacks. The results also indicate that the averaged AOD trend over global ocean is weakly positive from 1998 to 2010 and comparable to that observed by MODIS but opposite in sign to that observed by AVHRR during overlapping years. On regional scales, distinct tendencies are found for different regions associated with natural and anthropogenic aerosol emission and transport. For example, large upward trends are found over the Arabian Peninsula that indicate a strengthening of the seasonal cycle of dust emission and transport processes over the whole region as well as over downwind oceanic regions. In contrast, a negative-neutral tendency is observed over the desert/arid Saharan region as well as in the associated dust outflow over the north Atlantic. Additionally, we found decreasing trends over the eastern US and Europe, and increasing trends over countries such as China and India that are experiencing rapid economic development. In general, these results are consistent with those derived from ground-based AERONET measurements.

  9. Highly accurate FTIR observations from the scanning HIS aircraft instrument

    NASA Astrophysics Data System (ADS)

    Revercomb, Henry E.; Tobin, David C.; Knuteson, Robert O.; Best, Fred A.; Smith, William L., Sr.; van Delst, Paul F. W.; LaPorte, Daniel D.; Ellington, Scott D.; Werner, Mark W.; Dedecker, Ralph G.; Garcia, Raymond K.; Ciganovich, Nick N.; Howell, Hugh B.; Olson, Erik R.; Dutcher, Steven B.; Taylor, Joseph K.

    2005-01-01

    Development in the mid 80s of the High-resolution Interferometer Sounder (HIS) instrument for the high altitude NASA ER2 aircraft demonstrated the capability for advanced atmospheric temperature and water vapor sounding and set the stage for new satellite instruments that are now becoming a reality [AIRS(2002), CrIS(2006), IASI(2006), GIFTS(200?), HES(2013)]. Follow-on developments at the University of Wisconsin that employ Fourier Transform Infrared (FTIR) for Earth observations include the ground-based Atmospheric Emitted Radiance Interferometer (AERI) and the new Scanning HIS aircraft instrument. The Scanning HIS is a smaller version of the original HIS that uses cross-track scanning to enhance spatial coverage. Scanning HIS and its close cousin, the NPOESS Airborne Sounder Testbed (NAST), are being used for satellite instrument validation and for atmospheric research. A novel detector configuration on Scanning HIS allows the incorporation of a single focal plane and cooler with three or four spectral bands that view the same spot on the ground. The calibration accuracy of the S-HIS and results from recent field campaigns are presented, including validation comparisons with the NASA EOS infrared observations (AIRS and MODIS). Aircraft comparisons of this type provide a mechanism for periodically testing the absolute calibration of spacecraft instruments with instrumentation for which the calibration can be carefully maintained on the ground. This capability is especially valuable for assuring the long-term consistency and accuracy of climate observations, including those from the NASA EOS spacecrafts (Terra, Aqua and Aura) and the new complement of NPOESS operational instruments. It is expected that aircraft flights of the S-HIS and the NAST will be used to check the long-term stability of AIRS and the NPOESS operational follow-on sounder, the Cross-track Infrared Sounder (CrIS), over the life of the mission.

  10. Assessment of the Short-Term Radiometric Stability between Terra MODIS and Landsat 7 ETM+ Sensors

    NASA Technical Reports Server (NTRS)

    Choi, Taeyoung; Xiong, Xiaxiong; Chander, G.; Angal, Amit

    2009-01-01

    The Landsat 7 (L7) Enhanced Thematic Mapper (ETM+) sensor was launched on April 15th, 1999 and has been in operation for over nine years. It has six reflective solar spectral bands located in the visible and shortwave infrared part of the electromagnetic spectrum (0.5 - 2.5 micron) at a spatial resolution of 30 m. The on-board calibrators are used to monitor the on-orbit sensor system changes. The ETM+ performs solar calibrations using on-board Full Aperture Solar Calibrator (FASC) and the Partial Aperture Solar Calibrator (PASC). The Internal Calibrator Lamp (IC) lamps, a blackbody and shutter optics constitute the on-orbit calibration mechanism for ETM+. On 31 May 2003, a malfunction of the scan-line corrector (SLC) mirror assembly resulted in the loss of approximately 22% of the normal scene area. The missing data affects most of the image with scan gaps varying in width from one pixel or less near the centre of the image to 14 pixels along the east and west edges of the image, creating a wedge-shaped pattern. However, the SLC failure has no impacts on the radiometric performance of the valid pixels. On December 18, 1999, the Moderate Resolution Imaging Spectroradiometer (MODIS) Proto-Flight Model (PFM) was launched on-board the NASA's EOS Terra spacecraft. Terra MODIS has 36 spectral bands with wavelengths ranging from 0.41 to 14.5 micron and collects data over a wide field of view angle (+/-55 deg) at three nadir spatial resolutions of 250 m, 500 in 1 km for bands 1 to 2, 3 to 7, and 8 to 36, respectively. It has 20 reflective solar bands (RSB) with spectral wavelengths from 0.41 to 2.1 micron. The RSB radiometric calibration is performed by using on-board solar diffuser (SD), solar diffuser stability monitor (SDSM), space-view (SV), and spectro-radiometric calibration assembly (SRCA). Through the SV port, periodic lunar observations are used to track radiometric response changes at different angles of incidence (AOI) of the scan mirror. As a part of the AM Constellation satellites, Terra MODIS flies approximately 30 minutes behind L7 ETM+ in the same orbit. The orbit of L7 is repetitive, circular, sunsynchronous, and near polar at a nominal altitude of 705 km (438 miles) at the Equator. The spacecraft crosses the Equator from north to south on a descending node between 10:00 AM and 10:15 AM. Circling the Earth at 7.5 km/sec, each orbit takes nearly 99 minutes. The spacecraft completes just over 14 orbits per day, covering the entire Earth between 81 degrees north and south latitude every 16 days. The longest continuous imaging swath that L7 sensor can collect is for a 14-minute subinterval contact period which is equivalent to 35 full WRS-2 scenes. On the other hand, Terra can provide the entire corresponding orbit with wider swath at any given ETM+ collection without contact time limitation. There are six spectral matching band pairs between MODIS (bands 3, 4, 1, 2, 6, 7) and ETM+ (bands 1, 2, 3, 4, 5, 7) sensor. MODIS has narrower spectral responses than ETM+ in all the bands. A short-term radiometric stability was evaluated using continuous ETM+ scenes within the contact period and the corresponding half orbit MODIS scenes. The near simultaneous earth observations (SNO) were limited by the smaller swath size of ETM+ (187 km) as compared to MODIS (2330 km). Two sets of continuous granules for MODIS and ETM+ were selected and mosaiced based on pixel geolocation information for non cloudy pixels over the North American continent. The Top-of- Atmosphere (TOA) reflectances were computed for the spectrally matching bands between ETM+ and MODIS over the regions of interest (ROI). The matching pixel pairs were aggregated from a finer to a coarser pixel resolution and the TOA reflectance values covering a wide dynamic range of the sensors were compared and analyzed. Considering the uncertainties of the absolute calibration of the both sensors, radiometric stability was verified for the band pairs. The Railroad Valley Playa, Nada (RVPN) was included in the path of this continuous orbit, which served as a verification point between the shortterm and the long-term trending results from previous studies. This work focuses on monitoring the short-term on-orbit stability of MODIS and the ETM+ RSB. It also provides an assessment of the absolute calibration differences between the two sensors over their wide dynamic ranges.

  11. Assessment of SNPP VIIRS VIS NIR Radiometric Calibration Stability Using Aqua MODIS and Invariant Surface Targets

    NASA Technical Reports Server (NTRS)

    Wu, Aisheng; Xiong, Xiaoxiong; Cao, Changyong; Chiang, Kwo-Fu

    2016-01-01

    The first Visible Infrared Imaging Radiometer Suite (VIIRS) is onboard the Suomi National Polar-orbiting Partnership (SNPP) satellite. As a primary sensor, it collects imagery and radiometric measurements of the land, atmosphere, cryosphere, and oceans in the spectral regions from visible (VIS) to long-wave infrared. NASA's National Polar-orbiting Partnership (NPP) VIIRS Characterization Support Team has been actively involved in the VIIRS radiometric and geometric calibration to support its Science Team Principal Investigators for their independent quality assessment of VIIRS Environmental Data Records. This paper presents the performance assessment of the radiometric calibration stability of the VIIRS VIS and NIR spectral bands using measurements from SNPP VIIRS and Aqua MODIS simultaneous nadir overpasses and over the invariant surface targets at the Libya-4 desert and Antarctic Dome Concordia snow sites. The VIIRS sensor data records (SDRs) used in this paper are reprocessed by the NASA SNPP Land Product Evaluation and Analysis Tool Element. This paper shows that the reprocessed VIIRS SDRs have been consistently calibrated from the beginning of the mission, and the calibration stability is similar to or better than MODIS. Results from different approaches indicate that the calibrations of the VIIRS VIS and NIR spectral bands are maintained to be stable to within 1% over the first three-year mission. The absolute calibration differences between VIIRS and MODIS are within 2%, with an exception for the 0.865-m band, after correction of their spectral response differences.

  12. In-Flight Calibration Methods for Temperature-Dependent Offsets in the MMS Fluxgate Magnetometers

    NASA Technical Reports Server (NTRS)

    Bromund, K. R.; Plaschke, F.; Strangeway, R. J.; Anderson, B. J.; Huang, B. G.; Magnes, W.; Fischer, D.; Nakamura, R.; Leinweber, H. K.; Russell, C. T.; hide

    2016-01-01

    During the first dayside season of the Magnetospheric Multiscale (MMS) mission, the in-flight calibration process for the Fluxgate magnetometers (FGM) implemented an algorithm that selected a constant offset (zero-level) for each sensor on each orbit. This method was generally able to reduce the amplitude of residual spin tone to less than 0.2 nT within the region of interest. However, there are times when the offsets do show significant short-term variations. These variations are most prominent in the nighttime season (phase 1X), when eclipses are accompanied by offset changes as large as 1 nT. Eclipses are followed by a recovery period as long as 12 hours where the offsets continue to change as temperatures stabilize. Understanding and compensating for these changes will become critical during Phase 2 of the mission in 2017, when the nightside will become the focus of MMS science. Although there is no direct correlation between offset and temperature, the offsets are seen for the period of any given week to be well-characterized as function of instrument temperature. Using this property, a new calibration method has been developed that has proven effective in compensating for temperature-dependent offsets during phase 1X of the MMS mission and also promises to further refine calibration quality during the dayside season.

  13. Primary flow meter for calibrating a sniffer test leak artefact by a pressure rise method

    NASA Astrophysics Data System (ADS)

    Arai, Kenta; Yoshida, Hajime

    2014-10-01

    Sniffer tests are used to locate leaks in equipment during operation. The sensitivity of a sniffer leak detector must be calibrated against a known gas flow to atmospheric pressure generated by a sniffer test leak artefact. We have developed a primary flow meter for calibrating gas flows to atmospheric pressure through the leak artefact. The flow meter is based on a pressure rise method and two chambers are used to measure the pressure rise with small uncertainty even at atmospheric pressure. The calibration range of the flow rate is 5 × 10-7 Pa m3 s-1 to 7 × 10-4 Pa m3 s-1 to atmospheric pressure at 23.0 °C with a minimum uncertainty of 1.4% (k = 2), as well as 4 × 10-8 Pa m3 s-1 to 5 × 10-4 Pa m3 s-1 to a vacuum at 23.0 °C. The long term stability of the flow meter was determined as 0.41% by repeated measurements of the conductance of the leak artefact. In case of the flow rate into a vacuum, the flow meter was successfully linked to the international reference value of CCM.P-K12 by a lab-internal comparison.

  14. Calibration Challenges and Improvements for Terra and Aqua MODIS Level-1B Data Product Qualit

    NASA Astrophysics Data System (ADS)

    Xiong, X.; Angal, A.; Chen, H.; Geng, X.; Li, Y.; Link, D.; Salomonson, V.; Twedt, K.; Wang, Z.; Wilson, T.; Wu, A.

    2017-12-01

    Terra and Aqua MODIS instruments launched in 1999 and 2002, respectively, have provided the remote sensing community and users worldwide a series of high quality long-term data records. They have enabled a broad range of scientific studies of the Earth's system and changes in its key geophysical and environmental parameters. To date, both MODIS instruments continue to operate nominally with all on-board calibrators (OBC) functioning properly. MODIS reflective solar bands (RSB) are currently calibrated by a solar diffuser (SD) and solar diffuser stability monitor (SDSM) system, coupled with regularly scheduled lunar observations and trending results from selected ground reference targets. The thermal emissive bands (TEB) calibration is performed using an on-board blackbody (BB) on a scan-by-scan basis. The sensor's spectral and spatial characteristics are periodically tracked by the on-board spectroradiometric calibration assembly (SRCA). On-orbit changes in sensor responses or performance characteristics, often in non-deterministic ways, underscore the need for dedicated calibration efforts to be made over the course of the sensor's entire mission. For MODIS instruments, this task has been undertaken by the MODIS Characterization Support Team (MCST). In this presentation, we provide an overview of MODIS instrument operation and calibration activities with a focus on recent challenging issues. We describe the efforts made and methodologies developed to address various challenging issues, including on-orbit characterization of sensor response versus scan angle (RVS) and polarization sensitives in the reflective solar spectral region, and electronic crosstalk impact on sensor calibration. Also discussed are the latest improvements made into the MODIS Level-1B data products as well as lessons that could benefit other instruments (e.g. VIIRS) for their on-orbit calibration and characterization.

  15. Stability and predictors of change in salivary cortisol measures over six years: MESA.

    PubMed

    Wang, Xu; Sánchez, Brisa N; Golden, Sherita Hill; Shrager, Sandi; Kirschbaum, Clemens; Karlamangla, Arun S; Seeman, Teresa E; Roux, Ana V Diez

    2014-11-01

    A major challenge in characterizing features of the daily cortisol curve is variability in features over time. Few studies have examined the stability of daily features of the cortisol curve over long periods or the predictors of long term changes. Repeated salivary cortisol measures on 580 adults from the MESA Stress study were used to examine the stability of various features of the daily cortisol curve (wakeup value, the cortisol awakening response (CAR), the early and late decline slope and the area under the curve (AUC)), over short periods (several days) and long periods (approximately 6-years) and to investigate the association of demographic factors with the changes. Intraclass correlation coefficients (ICCs) were used to estimate the short and long term stability. Piecewise linear mixed models were used to assess factors associated with changes in features over time. For most features, short term stability (ICCs: 0.17-0.74) was higher than long term stability (ICCs: 0.05-0.42), and long term stability was highest when several days were averaged for each time point. The decline over the day showed the highest long term stability: when several days for each wave were averaged the stability of the daily decline slope across 6 years was similar (or higher) than the stability across short periods. AUC had high stability over short periods (ICCs: 0.65-0.74) but much lower stability across long periods (ICC: 0.05). All features of daily cortisol curve investigated changed significantly over the approximately 6 year follow-up period. The wakeup cortisol became higher; the CAR became smaller; both the early and late decline became flatter; and the AUC became larger. Hispanics experienced significantly larger increases in the wakeup value; and African-Americans and Hispanics showed less flattening over time of the early decline slope than Non-Hispanic Whites. Our findings have implications for characterization of features in studies linking cortisol to health outcomes. The presence of variability over time suggests opportunities for future investigation of the predictors of changes over time as well as the links between these changes and health outcomes. Copyright © 2014 Elsevier Ltd. All rights reserved.

  16. Calibration Techniques for Accurate Measurements by Underwater Camera Systems

    PubMed Central

    Shortis, Mark

    2015-01-01

    Calibration of a camera system is essential to ensure that image measurements result in accurate estimates of locations and dimensions within the object space. In the underwater environment, the calibration must implicitly or explicitly model and compensate for the refractive effects of waterproof housings and the water medium. This paper reviews the different approaches to the calibration of underwater camera systems in theoretical and practical terms. The accuracy, reliability, validation and stability of underwater camera system calibration are also discussed. Samples of results from published reports are provided to demonstrate the range of possible accuracies for the measurements produced by underwater camera systems. PMID:26690172

  17. The Melting Point of Palladium Using Miniature Fixed Points of Different Ceramic Materials: Part II—Analysis of Melting Curves and Long-Term Investigation

    NASA Astrophysics Data System (ADS)

    Edler, F.; Huang, K.

    2016-12-01

    Fifteen miniature fixed-point cells made of three different ceramic crucible materials (Al2O3, ZrO2, and Al2O3(86 %)+ZrO2(14 %)) were filled with pure palladium and used to calibrate type B thermocouples (Pt30 %Rh/Pt6 %Rh). A critical point by using miniature fixed points with small amounts of fixed-point material is the analysis of the melting curves, which are characterized by significant slopes during the melting process compared to flat melting plateaus obtainable using conventional fixed-point cells. The method of the extrapolated starting point temperature using straight line approximation of the melting plateau was applied to analyze the melting curves. This method allowed an unambiguous determination of an electromotive force (emf) assignable as melting temperature. The strict consideration of two constraints resulted in a unique, repeatable and objective method to determine the emf at the melting temperature within an uncertainty of about 0.1 μ V. The lifetime and long-term stability of the miniature fixed points was investigated by performing more than 100 melt/freeze cycles for each crucible of the different ceramic materials. No failure of the crucibles occurred indicating an excellent mechanical stability of the investigated miniature cells. The consequent limitation of heating rates to values below {± }3.5 K min^{-1} above 1100° C and the carefully and completely filled crucibles (the liquid palladium occupies the whole volume of the crucible) are the reasons for successfully preventing the crucibles from breaking. The thermal stability of the melting temperature of palladium was excellent when using the crucibles made of Al2O3(86 %)+ZrO2(14 %) and ZrO2. Emf drifts over the total duration of the long-term investigation were below a temperature equivalent of about 0.1 K-0.2 K.

  18. Characterization and Correction of Aquarius Long Term Calibration Drift Using On-Earth Brightness Temperature Refernces

    NASA Technical Reports Server (NTRS)

    Brown, Shannon; Misra, Sidharth

    2013-01-01

    The Aquarius/SAC-D mission was launched on June 10, 2011 from Vandenberg Air Force Base. Aquarius consists of an L-band radiometer and scatterometer intended to provide global maps of sea surface salinity. One of the main mission objectives is to provide monthly global salinity maps for climate studies of ocean circulation, surface evaporation and precipitation, air/sea interactions and other processes. Therefore, it is critical that any spatial or temporal systematic biases be characterized and corrected. One of the main mission requirements is to measure salinity with an accuracy of 0.2 psu on montly time scales which requires a brightness temperature stability of about 0.1K, which is a challenging requirement for the radiometer. A secondary use of the Aquarius data is for soil moisture applications, which requires brightness temperature stability at the warmer end of the brightness temperature dynamic range. Soon after launch, time variable drifts were observed in the Aquarius data compared to in-situ data from ARGO and models for the ocean surface salinity. These drifts could arise from a number of sources, including the various components of the retrieval algorithm, such as the correction for direct and reflected galactic emission, or from the instrument brightness temperature calibration. If arising from the brightness temperature calibration, they could have gain and offset components. It is critical that the nature of the drifts be understood before a suitable correction can be implemented. This paper describes the approach that was used to detect and characterize the components of the drift that were in the brightness temperature calibration using on-Earth reference targets that were independent of the ocean model.

  19. [Stabilization and long-term effect of chromium contaminated soil].

    PubMed

    Wang, Jing; Luo, Qi-Shi; Zhang, Chang-Bo; Tan, Liang; Li, Xu

    2013-10-01

    Short-term (3 d and 28 d) and long-term (1 a) stabilization effects of Cr contaminated soil were investigated through nature curing, using four amendments including ferrous sulfide, ferrous sulfate, zero-valent iron and sodium dithionite. The results indicated that ferrous sulfide and zero-valent iron were not helpful for the stabilization of Cr(VI) when directly used because of their poor solubility and immobility. Ferrous sulfate could effectively and rapidly decrease total leaching Cr and Cr(VI) content. The stabilization effect was further promoted by the generation of iron hydroxides after long-term curing. Sodium dithionite also had positive effect on soil stabilization. Appropriate addition ratio of the two chemicals could help maintain the soil pH in range of 6-8.

  20. Long-Term Stability of Oxide Nanowire Sensors via Heavily Doped Oxide Contact.

    PubMed

    Zeng, Hao; Takahashi, Tsunaki; Kanai, Masaki; Zhang, Guozhu; He, Yong; Nagashima, Kazuki; Yanagida, Takeshi

    2017-12-22

    Long-term stability of a chemical sensor is an essential quality for long-term collection of data related to exhaled breath, environmental air, and other sources in the Internet of things (IoT) era. Although an oxide nanowire sensor has shown great potential as a chemical sensor, the long-term stability of sensitivity has not been realized yet due to electrical degradation under harsh sensing conditions. Here, we report a rational concept to accomplish long-term electrical stability of metal oxide nanowire sensors via introduction of a heavily doped metal oxide contact layer. Antimony-doped SnO 2 (ATO) contacts on SnO 2 nanowires show much more stable and lower electrical contact resistance than conventional Ti contacts for high temperature (200 °C) conditions, which are required to operate chemical sensors. The stable and low contact resistance of ATO was confirmed for at least 1960 h under 200 °C in open air. This heavily doped oxide contact enables us to realize the long-term stability of SnO 2 nanowire sensors while maintaining the sensitivity for both NO 2 gas and light (photo) detections. The applicability of our method is confirmed for sensors on a flexible polyethylene naphthalate (PEN) substrate. Since the proposed fundamental concept can be applied to various oxide nanostructures, it will give a foundation for designing long-term stable oxide nanomaterial-based IoT sensors.

  1. Developing a lower-cost atmospheric CO2 monitoring system using commercial NDIR sensor

    NASA Astrophysics Data System (ADS)

    Arzoumanian, E.; Bastos, A.; Gaynullin, B.; Laurent, O.; Vogel, F. R.

    2017-12-01

    Cities release to the atmosphere about 44 % of global energy-related CO2. It is clear that accurate estimates of the magnitude of anthropogenic and natural urban emissions are needed to assess their influence on the carbon balance. A dense ground-based CO2 monitoring network in cities would potentially allow retrieving sector specific CO2 emission estimates when combined with an atmospheric inversion framework using reasonably accurate observations (ca. 1 ppm for hourly means). One major barrier for denser observation networks can be the high cost of high precision instruments or high calibration cost of cheaper and unstable instruments. We have developed and tested a novel inexpensive NDIR sensors for CO2 measurements which fulfils cost and typical parameters requirements (i.e. signal stability, efficient handling, and connectivity) necessary for this task. Such sensors are essential in the market of emissions estimates in cities from continuous monitoring networks as well as for leak detection of MRV (monitoring, reporting, and verification) services for industrial sites. We conducted extensive laboratory tests (short and long-term repeatability, cross-sensitivities, etc.) on a series of prototypes and the final versions were also tested in a climatic chamber. On four final HPP prototypes the sensitivity to pressure and temperature were precisely quantified and correction&calibration strategies developed. Furthermore, we fully integrated these HPP sensors in a Raspberry PI platform containing the CO2 sensor and additional sensors (pressure, temperature and humidity sensors), gas supply pump and a fully automated data acquisition unit. This platform was deployed in parallel to Picarro G2401 instruments in the peri-urban site Saclay - next to Paris, and in the urban site Jussieu - Paris, France. These measurements were conducted over several months in order to characterize the long-term drift of our HPP instruments and the ability of the correction and calibration scheme to provide bias free observations. From the lessons learned in the laboratory tests and field measurements, we developed a specific correction and calibration strategy for our NDIR sensors. Latest results and calibration strategies will be shown.

  2. The JPSS CrIS Instrument and the Evolution of Space-Based Infrared Sounders

    NASA Technical Reports Server (NTRS)

    Glumb, Ronald; Suwinski, Lawrence; Wells, Steven; Glumb, Anna; Malloy, Rebecca; Colton, Marie

    2018-01-01

    This paper will summarize the development of infrared sounders since the 1970s, describe the technological hurdles that were overcome to provide ever-increasing performance capabilities, and highlight the radiometric performance of the CrIS instrument on JPSS-1 (CrIS-JPSS1). This includes details of the CrIS-JPSS1 measured noise-equivalent spectral radiance (NEdN) performance, radiometric uncertainty performance utilizing a new and improved internal calibration target, short-term and long-term repeatability, spectral uncertainty, and spectral stability. In addition, the full-resolution operating modes for CrIS-JPSS1 will be reviewed, including a discussion of how these modes will be used during on-orbit characterization tests. We will provide a brief update of CrIS-SNPP on-obit performance and the production status of the CrIS instruments for JPSS-2 through JPSS-4. Current technological challenges will also be reviewed, including how ongoing research and development is enabling improvements to future sounders. The expanding usage of infrared sounding data will also be discussed, including demonstration of value via data assimilation, the roles of the public/private sector in communicating the importance of sounding data for long-term observations, and the long road to success from research to operational data products.

  3. Evaluation of the Sensor Data Record from the Nadir Instruments of the Ozone Mapping Profiler Suite (OMPS)

    NASA Technical Reports Server (NTRS)

    Wu, Xiangqian; Liu, Quanhua; Zeng, Jian; Grotenhuis, Michael; Qian, Haifeng; Caponi, Maria; Flynn, Larry; Jaross, Glen; Sen, Bhaswar; Buss, Richard H., Jr.; hide

    2014-01-01

    This paper evaluates the first 15 months of the Ozone Mapping and Profiler Suite (OMPS) Sensor Data Record (SDR) acquired by the nadir sensors and processed by the National Oceanic and Atmospheric Administration Interface Data Processing Segment. The evaluation consists of an inter-comparison with a similar satellite instrument, an analysis using a radiative transfer model, and an assessment of product stability. This is in addition to the evaluation of sensor calibration and the Environment Data Record product that are also reported in this Special Issue. All these are parts of synergetic effort to provide comprehensive assessment at every level of the products to ensure its quality. It is found that the OMPS nadir SDR quality is satisfactory for the current Provisional maturity. Methods used in the evaluation are being further refined, developed, and expanded, in collaboration with international community through the Global Space-based Inter-Calibration System, to support the upcoming long-term monitoring.

  4. Modeling ecohydrologic processes at Hubbard Brook: Initial results for Watershed 6 stream discharge and chemistry

    EPA Science Inventory

    The Hubbard Brook Long Term Ecological Research site has produced some of the most extensive and long-running databases on the hydrology, biology and chemistry of forest ecosystem responses to climate and forest harvest. We used these long-term databases to calibrate and apply G...

  5. A simple, accurate, field-portable mixing ratio generator and Rayleigh distillation device

    USDA-ARS?s Scientific Manuscript database

    Routine field calibration of water vapor analyzers has always been a challenging problem for those making long-term flux measurements at remote sites. Automated sampling of standard gases from compressed tanks, the method of choice for CO2 calibration, cannot be used for H2O. Calibrations are typica...

  6. Evaluation of impact of length of calibration time period on the APEX model streamflow simulation

    USDA-ARS?s Scientific Manuscript database

    Due to resource constraints, continuous long-term measured data for model calibration and validation (C/V) are rare. As a result, most hydrologic and water quality models are calibrated and, if possible, validated using limited available measured data. However, little research has been carried out t...

  7. Impact of length of dataset on streamflow calibration parameters and performance of APEX model

    USDA-ARS?s Scientific Manuscript database

    Due to resource constraints, long-term monitoring data for calibration and validation of hydrologic and water quality models are rare. As a result, most models are calibrated and, if possible, validated using limited measured data. However, little research has been done to determine the impact of le...

  8. Impact of length of calibration period on the APEX model water quantity and quality simulation performance

    USDA-ARS?s Scientific Manuscript database

    Availability of continuous long-term measured data for model calibration and validation is limited due to time and resources constraints. As a result, hydrologic and water quality models are calibrated and, if possible, validated when measured data is available. Past work reported on the impact of t...

  9. Modeling Long-Term Corn Yield Response to Nitrogen Rate and Crop Rotation

    PubMed Central

    Puntel, Laila A.; Sawyer, John E.; Barker, Daniel W.; Dietzel, Ranae; Poffenbarger, Hanna; Castellano, Michael J.; Moore, Kenneth J.; Thorburn, Peter; Archontoulis, Sotirios V.

    2016-01-01

    Improved prediction of optimal N fertilizer rates for corn (Zea mays L.) can reduce N losses and increase profits. We tested the ability of the Agricultural Production Systems sIMulator (APSIM) to simulate corn and soybean (Glycine max L.) yields, the economic optimum N rate (EONR) using a 16-year field-experiment dataset from central Iowa, USA that included two crop sequences (continuous corn and soybean-corn) and five N fertilizer rates (0, 67, 134, 201, and 268 kg N ha-1) applied to corn. Our objectives were to: (a) quantify model prediction accuracy before and after calibration, and report calibration steps; (b) compare crop model-based techniques in estimating optimal N rate for corn; and (c) utilize the calibrated model to explain factors causing year to year variability in yield and optimal N. Results indicated that the model simulated well long-term crop yields response to N (relative root mean square error, RRMSE of 19.6% before and 12.3% after calibration), which provided strong evidence that important soil and crop processes were accounted for in the model. The prediction of EONR was more complex and had greater uncertainty than the prediction of crop yield (RRMSE of 44.5% before and 36.6% after calibration). For long-term site mean EONR predictions, both calibrated and uncalibrated versions can be used as the 16-year mean differences in EONR’s were within the historical N rate error range (40–50 kg N ha-1). However, for accurate year-by-year simulation of EONR the calibrated version should be used. Model analysis revealed that higher EONR values in years with above normal spring precipitation were caused by an exponential increase in N loss (denitrification and leaching) with precipitation. We concluded that long-term experimental data were valuable in testing and refining APSIM predictions. The model can be used as a tool to assist N management guidelines in the US Midwest and we identified five avenues on how the model can add value toward agronomic, economic, and environmental sustainability. PMID:27891133

  10. Modeling Long-Term Corn Yield Response to Nitrogen Rate and Crop Rotation.

    PubMed

    Puntel, Laila A; Sawyer, John E; Barker, Daniel W; Dietzel, Ranae; Poffenbarger, Hanna; Castellano, Michael J; Moore, Kenneth J; Thorburn, Peter; Archontoulis, Sotirios V

    2016-01-01

    Improved prediction of optimal N fertilizer rates for corn ( Zea mays L. ) can reduce N losses and increase profits. We tested the ability of the Agricultural Production Systems sIMulator (APSIM) to simulate corn and soybean ( Glycine max L. ) yields, the economic optimum N rate (EONR) using a 16-year field-experiment dataset from central Iowa, USA that included two crop sequences (continuous corn and soybean-corn) and five N fertilizer rates (0, 67, 134, 201, and 268 kg N ha -1 ) applied to corn. Our objectives were to: (a) quantify model prediction accuracy before and after calibration, and report calibration steps; (b) compare crop model-based techniques in estimating optimal N rate for corn; and (c) utilize the calibrated model to explain factors causing year to year variability in yield and optimal N. Results indicated that the model simulated well long-term crop yields response to N (relative root mean square error, RRMSE of 19.6% before and 12.3% after calibration), which provided strong evidence that important soil and crop processes were accounted for in the model. The prediction of EONR was more complex and had greater uncertainty than the prediction of crop yield (RRMSE of 44.5% before and 36.6% after calibration). For long-term site mean EONR predictions, both calibrated and uncalibrated versions can be used as the 16-year mean differences in EONR's were within the historical N rate error range (40-50 kg N ha -1 ). However, for accurate year-by-year simulation of EONR the calibrated version should be used. Model analysis revealed that higher EONR values in years with above normal spring precipitation were caused by an exponential increase in N loss (denitrification and leaching) with precipitation. We concluded that long-term experimental data were valuable in testing and refining APSIM predictions. The model can be used as a tool to assist N management guidelines in the US Midwest and we identified five avenues on how the model can add value toward agronomic, economic, and environmental sustainability.

  11. Measuring temporal stability of positron emission tomography standardized uptake value bias using long-lived sources in a multicenter network.

    PubMed

    Byrd, Darrin; Christopfel, Rebecca; Arabasz, Grae; Catana, Ciprian; Karp, Joel; Lodge, Martin A; Laymon, Charles; Moros, Eduardo G; Budzevich, Mikalai; Nehmeh, Sadek; Scheuermann, Joshua; Sunderland, John; Zhang, Jun; Kinahan, Paul

    2018-01-01

    Positron emission tomography (PET) is a quantitative imaging modality, but the computation of standardized uptake values (SUVs) requires several instruments to be correctly calibrated. Variability in the calibration process may lead to unreliable quantitation. Sealed source kits containing traceable amounts of [Formula: see text] were used to measure signal stability for 19 PET scanners at nine hospitals in the National Cancer Institute's Quantitative Imaging Network. Repeated measurements of the sources were performed on PET scanners and in dose calibrators. The measured scanner and dose calibrator signal biases were used to compute the bias in SUVs at multiple time points for each site over a 14-month period. Estimation of absolute SUV accuracy was confounded by bias from the solid phantoms' physical properties. On average, the intrascanner coefficient of variation for SUV measurements was 3.5%. Over the entire length of the study, single-scanner SUV values varied over a range of 11%. Dose calibrator bias was not correlated with scanner bias. Calibration factors from the image metadata were nearly as variable as scanner signal, and were correlated with signal for many scanners. SUVs often showed low intrascanner variability between successive measurements but were also prone to shifts in apparent bias, possibly in part due to scanner recalibrations that are part of regular scanner quality control. Biases of key factors in the computation of SUVs were not correlated and their temporal variations did not cancel out of the computation. Long-lived sources and image metadata may provide a check on the recalibration process.

  12. Summary of Terra and Aqua MODIS Long-Term Performance

    NASA Technical Reports Server (NTRS)

    Xiong, Xiaoxiong (Jack); Wenny, Brian N.; Angal, Amit; Barnes, William; Salomonson, Vincent

    2011-01-01

    Since launch in December 1999, the MODIS ProtoFlight Model (PFM) onboard the Terra spacecraft has successfully operated for more than 11 years. Its Flight Model (FM) onboard the Aqua spacecraft, launched in May 2002, has also successfully operated for over 9 years. MODIS observations are made in 36 spectral bands at three nadir spatial resolutions and are calibrated and characterized regularly by a set of on-board calibrators (OBC). Nearly 40 science products, supporting a variety of land, ocean, and atmospheric applications, are continuously derived from the calibrated reflectances and radiances of each MODIS instrument and widely distributed to the world-wide user community. Following an overview of MODIS instrument operation and calibration activities, this paper provides a summary of both Terra and Aqua MODIS long-term performance. Special considerations that are critical to maintaining MODIS data quality and beneficial for future missions are also discussed.

  13. Long Term Uncertainty Investigations of 1 MN Force Calibration Machine at NPL, India (NPLI)

    NASA Astrophysics Data System (ADS)

    Kumar, Rajesh; Kumar, Harish; Kumar, Anil; Vikram

    2012-01-01

    The present paper is an attempt to study the long term uncertainty of 1 MN hydraulic multiplication system (HMS) force calibration machine (FCM) at the National Physical Laboratory, India (NPLI), which is used for calibration of the force measuring instruments in the range of 100 kN - 1 MN. The 1 MN HMS FCM was installed at NPLI in 1993 and was built on the principle of hydraulic amplifications of dead weights. The best measurement capability (BMC) of the machine is ± 0.025% (k = 2) and it is traceable to national standards by means of precision force transfer standards (FTS). The present study discusses the uncertainty variations of the 1 MN HMS FCM over the years and describes the other parameters in detail, too. The 1 MN HMS FCM was calibrated in the years 2004, 2006, 2007, 2008, 2009 and 2010 and the results have been reported.

  14. Late holocene climate changes in eastern North America estimated from pollen data

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gajewski, K.

    Well-dated pollen profiles from six sites from Maine to Minnesota record vegetation changes indicative of summer temperature and annual precipitation variations over the past 2000 yr. Laminations in the sediment provide accurate time control. Multiple regression techniques were used to calculate calibration functions from a spatial network of modern pollen and climate data. When applied to the six pollen diagrams, these calibration functions yielded estimates that show a long-term trend toward lower summer temperature. Superimposed on this long-term trend are short-term fluctuations that are frequently in phase at the sites. Departures from the long-term cooling trend are positive around 1500more » yr ago (indicating relative warmth) and negative between 200 and 500 yr ago (indicating relative cold). Annual precipitation showed a slight increase at several sites during the past 1000 yr relative to the previous 1000 yr.« less

  15. Validation of SCIAMACHY and TOMS UV Radiances Using Ground and Space Observations

    NASA Technical Reports Server (NTRS)

    Hilsenrath, E.; Bhartia, P. K.; Bojkov, B. R.; Kowalewski, M.; Labow, G.; Ahmad, Z.

    2004-01-01

    Verification of a stratospheric ozone recovery remains a high priority for environmental research and policy definition. Models predict an ozone recovery at a much lower rate than the measured depletion rate observed to date. Therefore improved precision of the satellite and ground ozone observing systems are required over the long term to verify its recovery. We show that validation of satellite radiances from space and from the ground can be a very effective means for correcting long term drifts of backscatter type satellite measurements and can be used to cross calibrate all B W instruments in orbit (TOMS, SBW/2, GOME, SCIAMACHY, OM, GOME-2, OMPS). This method bypasses the retrieval algorithms used for both satellite and ground based measurements that are normally used to validate and correct the satellite data. Radiance comparisons employ forward models and are inherently more accurate than inverse (retrieval) algorithms. This approach however requires well calibrated instruments and an accurate radiative transfer model that accounts for aerosols. TOMS and SCIAMACHY calibrations are checked to demonstrate this method and to demonstrate applicability for long term trends.

  16. Overview of intercalibration of satellite instruments

    USGS Publications Warehouse

    Chander, G.; Hewison, T.J.; Fox, N.; Wu, X.; Xiong, X.; Blackwell, W.J.

    2013-01-01

    Inter-calibration of satellite instruments is critical for detection and quantification of changes in the Earth’s environment, weather forecasting, understanding climate processes, and monitoring climate and land cover change. These applications use data from many satellites; for the data to be inter-operable, the instruments must be cross-calibrated. To meet the stringent needs of such applications requires that instruments provide reliable, accurate, and consistent measurements over time. Robust techniques are required to ensure that observations from different instruments can be normalized to a common scale that the community agrees on. The long-term reliability of this process needs to be sustained in accordance with established reference standards and best practices. Furthermore, establishing physical meaning to the information through robust Système International d'unités (SI) traceable Calibration and Validation (Cal/Val) is essential to fully understand the parameters under observation. The processes of calibration, correction, stability monitoring, and quality assurance need to be underpinned and evidenced by comparison with “peer instruments” and, ideally, highly calibrated in-orbit reference instruments. Inter-calibration between instruments is a central pillar of the Cal/Val strategies of many national and international satellite remote sensing organizations. Inter-calibration techniques as outlined in this paper not only provide a practical means of identifying and correcting relative biases in radiometric calibration between instruments but also enable potential data gaps between measurement records in a critical time series to be bridged. Use of a robust set of internationally agreed upon and coordinated inter-calibration techniques will lead to significant improvement in the consistency between satellite instruments and facilitate accurate monitoring of the Earth’s climate at uncertainty levels needed to detect and attribute the mechanisms of change. This paper summarizes the state-of-the-art of post-launch radiometric calibration of remote sensing satellite instruments, through inter-calibration.

  17. In-Flight Calibration of the MMS Fluxgate Magnetometers

    NASA Technical Reports Server (NTRS)

    Bromund, K. R.; Plaschke, F.; Strangeway, R. J.; Anderson, B. J.; Huang, B. G.; Magnes, W.; Fischer, D.; Nakamura, R.; Leinweber, H. K.; Russell, C. T.; hide

    2017-01-01

    We present an overview of the approach to in-flight calibration, which is a coordinated effort between the University of California Los Angeles (UCLA), Space Research Institute, Graz, Austria (IWF) and the NASA Goddard Space Flight Center (GSFC). We present details of the calibration effort at GSFC. During the first dayside season of the Magnetospheric Multiscale (MMS) mission, the in-flight calibration process for the Fluxgate magnetometers (FGM) implemented an algorithm that selected a constant offset (zero-level) for each sensor on each orbit. This method was generally able to reduce the amplitude of residual spin tone to less than 0.2 nT within the region of interest. However, there are times when the offsets do show significant short-term variations. These variations are most prominent in the nighttime season (phase 1X), when eclipses are accompanied by offset changes as large as 1 nT. Eclipses are followed by a recovery period as long as 12 hours where the offsets continue to change as temperatures stabilize. Understanding and compensating for these changes will become critical during Phase 2 of the mission in 2017, when the nightside will become the focus of MMS science. Although there is no direct correlation between offset and temperature, the offsets are seen for the period of any given week to be well-characterized as function of instrument temperature. Using this property, a new calibration method has been developed that has proven effective in compensating for temperature-dependent offsets during phase 1X of the MMS mission and also promises to further refine calibration quality during the dayside season.

  18. Long-term stability of diurnal salivary cortisol and alpha-amylase secretion patterns.

    PubMed

    Skoluda, Nadine; La Marca, Roberto; Gollwitzer, Mario; Müller, Andreas; Limm, Heribert; Marten-Mittag, Birgitt; Gündel, Harald; Angerer, Peter; Nater, Urs M

    2017-06-01

    This study aimed to investigate long-term stability and variability of diurnal cortisol and alpha-amylase patterns. Diurnal cortisol and alpha-amylase secretion patterns were assessed on a single workday with three waves of measurement across a total time period of 24months in 189 participants. Separate hierarchical linear models were analyzed, with and without a number of potential predictor variables (age, BMI, smoking, chronic stress, stress reactivity). While low long-term stability was found in diurnal cortisol, the stability of diurnal alpha-amylase was moderate across the time period of 24months. Several predictor variables had a positive impact on diurnal cortisol and alpha-amylase secretion patterns averaged across waves. Our findings underpin the notion that long-term stability is not necessarily warranted in longitudinal studies. It is important to choose an appropriate study design when attempting to disentangle clinically and biologically relevant changes from naturally occurring variations in diurnal cortisol and alpha-amylase. Copyright © 2017 Elsevier Inc. All rights reserved.

  19. Some Thoughts on Stability in Nonlinear Periodic Focusing Systems

    DOE R&D Accomplishments Database

    McMillan, E. M.

    1967-09-05

    A brief discussion is given of the long-term stability of particle motions through periodic focusing structures containing lumped nonlinear elements. A method is presented whereby one can specify the nonlinear elements in such a way as to generate a variety of structures in which the motion has long-term stability.

  20. Long-term stability of sodium caseinate-stabilized nanoemulsions.

    PubMed

    Yerramilli, Manispuritha; Ghosh, Supratim

    2017-01-01

    Oil-in-water (5 wt%) nanoemulsions were prepared with different concentration (2.5-10 wt%) of sodium caseinate as a sole emulsifier and their long-term storage stability was investigated for 6 months. Previous studies associated with sodium caseinate looked only into nanoemulsion formation; hence the challenges with long-term stability were not addressed. All nanoemulsions displayed an average droplet size <200 nm, which remained unchanged over 6 months. However, all of them displayed rapid creaming due to unabsorbed protein induced depletion flocculation, whose extent increased with protein concentration, although the cream layer formed was weak and re-dispersible upon gentle mixing. Microstructural analysis of the cream layer showed compaction of flocculated nanodroplet network with time leaving the aqueous phase out. Calculation of depletion interaction energy showed an increase in inter-droplet attraction with protein concentration and decrease with a reduction in droplet size, making the nanoemulsions more resistant to flocculation than conventional emulsions. This work aids in understanding the dependence of protein concentration on long-term stability of sodium caseinate-stabilized nanoemulsions.

  1. A novel high pressure, high temperature vessel used to conduct long-term stability measurements of silicon MEMS pressure transducers

    NASA Astrophysics Data System (ADS)

    Wisniewiski, David

    2014-03-01

    The need to quantify and to improve long-term stability of pressure transducers is a persistent requirement from the aerospace sector. Specifically, the incorporation of real-time pressure monitoring in aircraft landing gear, as exemplified in Tire Pressure Monitoring Systems (TPMS), has placed greater demand on the pressure transducer for improved performance and increased reliability which is manifested in low lifecycle cost and minimal maintenance downtime through fuel savings and increased life of the tire. Piezoresistive (PR) silicon MEMS pressure transducers are the primary choice as a transduction method for this measurement owing to their ability to be designed for the harsh environment seen in aircraft landing gear. However, these pressure transducers are only as valuable as the long-term stability they possess to ensure reliable, real-time monitoring over tens of years. The "heart" of the pressure transducer is the silicon MEMS element, and it is at this basic level where the long-term stability is established and needs to be quantified. A novel High Pressure, High Temperature (HPHT) vessel has been designed and constructed to facilitate this critical measurement of the silicon MEMS element directly through a process of mechanically "floating" the silicon MEMS element while being subjected to the extreme environments of pressure and temperature, simultaneously. Furthermore, the HPHT vessel is scalable to permit up to fifty specimens to be tested at one time to provide a statistically significant data population on which to draw reasonable conclusions on long-term stability. With the knowledge gained on the silicon MEMS element, higher level assembly to the pressure transducer envelope package can also be quantified as to the build-effects contribution to long-term stability in the same HPHT vessel due to its accommodating size. Accordingly, a HPHT vessel offering multiple levels of configurability and robustness in data measurement is presented, along with 10 year long-term stability results.

  2. Study of the GPS inter-frequency calibration of timing receivers

    NASA Astrophysics Data System (ADS)

    Defraigne, P.; Huang, W.; Bertrand, B.; Rovera, D.

    2018-02-01

    When calibrating Global Positioning System (GPS) stations dedicated to timing, the hardware delays of P1 and P2, the P(Y)-codes on frequencies L1 and L2, are determined separately. In the international atomic time (TAI) network the GPS stations of the time laboratories are calibrated relatively against reference stations. This paper aims at determining the consistency between the P1 and P2 hardware delays (called dP1 and dP2) of these reference stations, and to look at the stability of the inter-signal hardware delays dP1-dP2 of all the stations in the network. The method consists of determining the dP1-dP2 directly from the GPS pseudorange measurements corrected for the frequency-dependent antenna phase center and the frequency-dependent ionosphere corrections, and then to compare these computed dP1-dP2 to the calibrated values. Our results show that the differences between the computed and calibrated dP1-dP2 are well inside the expected combined uncertainty of the two quantities. Furthermore, the consistency between the calibrated time transfer solution obtained from either single-frequency P1 or dual-frequency P3 for reference laboratories is shown to be about 1.0 ns, well inside the 2.1 ns uB uncertainty of a time transfer link based on GPS P3 or Precise Point Positioning. This demonstrates the good consistency between the P1 and P2 hardware delays of the reference stations used for calibration in the TAI network. The long-term stability of the inter-signal hardware delays is also analysed from the computed dP1-dP2. It is shown that only variations larger than 2 ns can be detected for a particular station, while variations of 200 ps can be detected when differentiating the results between two stations. Finally, we also show that in the differential calibration process as used in the TAI network, using the same antenna phase center or using different positions for L1 and L2 signals gives maximum differences of 200 ps on the hardware delays of the separate codes P1 and P2; however, the final impact on the P3 combination is less than 10 ps.

  3. In-Flight Calibration Methods for Temperature-Dependendent Offsets in the MMS Fluxgate Magnetometers

    NASA Astrophysics Data System (ADS)

    Bromund, K. R.; Plaschke, F.; Strangeway, R. J.; Anderson, B. J.; Huang, B. G.; Magnes, W.; Fischer, D.; Nakamura, R.; Leinweber, H. K.; Russell, C. T.; Baumjohann, W.; Chutter, M.; Torbert, R. B.; Le, G.; Slavin, J. A.; Kepko, L.

    2016-12-01

    During the first dayside season of the Magnetospheric Multiscale (MMS) mission, the in-flight calibration process for the Fluxgate magnetometers (FGM) implemented an algorithm that selected a constant offset (zero-level) for each sensor on each orbit. This method was generally able to reduce the amplitude of residual spin tone to less than 0.2 nT within the region of interest. However, there are times when the offsets do show significant short-term variations. These variations are most prominent in the nighttime season (phase 1X), when eclipses are accompanied by offset changes as large as 1 nT. Eclipses are followed by a recovery period as long as 12 hours where the offsets continue to change as temperatures stabilize. Understanding and compensating for these changes will become critical during Phase 2 of the mission in 2017, when the nightside will become the focus of MMS science. Although there is no direct correlation between offset and temperature, the offsets are seen — for the period of any given week — to be well-characterized as function of instrument temperature. Using this property, a new calibration method has been developed that has proven effective in compensating for temperature-dependent offsets during phase 1X of the MMS mission and also promises to further refine calibration quality during the dayside season.

  4. Multiple calibrator measurements improve accuracy and stability estimates of automated assays.

    PubMed

    Akbas, Neval; Budd, Jeffrey R; Klee, George G

    2016-01-01

    The effects of combining multiple calibrations on assay accuracy (bias) and measurement of calibration stability were investigated for total triiodothyronine (TT3), vitamin B12 and luteinizing hormone (LH) using Beckman Coulter's Access 2 analyzer. Three calibration procedures (CC1, CC2 and CC3) combined 12, 34 and 56 calibrator measurements over 1, 2, and 3 days. Bias was calculated between target values and average measured value over 3 consecutive days after calibration. Using regression analysis of calibrator measurements versus measurement date, calibration stability was determined as the maximum number of days before a calibrator measurement exceeded 5% tolerance limits. Competitive assays (TT3, vitamin B12) had positive time regression slopes, while sandwich assay (LH) had a negative slope. Bias values for TT3 were -2.49%, 1.49%, and -0.50% using CC1, CC2 and CC3 respectively, with calibrator stability of 32, 20, and 30 days. Bias values for vitamin B12 were 2.44%, 0.91%, and -0.50%, with calibrator stability of 4, 9, and 12 days. Bias values for LH were 2.26%, 1.44% and -0.29% with calibrator stability of >43, 39 and 36 days. Measured stability was more consistent across calibration procedures using percent change rather than difference from target: 26 days for TT3, 12 days for B12 and 31 days for LH. Averaging over multiple calibrations produced smaller bias, consistent with improved accuracy. Time regression slopes in percent change were unaffected by number of calibration measurements but calibrator stability measured from the target value was highly affected by the calibrator value at time zero.

  5. Long-term stability and properties of zirconia ceramics for heavy duty diesel engine components

    NASA Technical Reports Server (NTRS)

    Larsen, D. C.; Adams, J. W.

    1985-01-01

    Physical, mechanical, and thermal properties of commercially available transformation-toughened zirconia are measured. Behavior is related to the material microstructure and phase assemblage. The stability of the materials is assessed after long-term exposure appropriate for diesel engine application. Properties measured included flexure strength, elastic modulus, fracture toughness, creep, thermal shock, thermal expansion, internal friction, and thermal diffusivity. Stability is assessed by measuring the residual property after 1000 hr/1000C static exposure. Additionally static fatigue and thermal fatigue testing is performed. Both yttria-stabilized and magnesia-stabilized materials are compared and contrasted. The major limitations of these materials are short term loss of properties with increasing temperature as the metastable tetragonal phase becomes more stable. Fine grain yttria-stabilized material (TZP) is higher strength and has a more stable microstructure with respect to overaging phenomena. The long-term limitation of Y-TZP is excessive creep deformation. Magnesia-stabilized PSZ has relatively poor stability at elevated temperature. Overaging, decomposition, and/or destabilization effects are observed. The major limitation of Mg-PSZ is controlling unwanted phase changes at elevated temperature.

  6. Calibrating Historical IR Sensors Using GEO, and AVHRR Infrared Tropical Mean Calibration Models

    NASA Technical Reports Server (NTRS)

    Scarino, Benjamin; Doelling, David R.; Minnis, Patrick; Gopalan, Arun; Haney, Conor; Bhatt, Rajendra

    2014-01-01

    Long-term, remote-sensing-based climate data records (CDRs) are highly dependent on having consistent, wellcalibrated satellite instrument measurements of the Earth's radiant energy. Therefore, by making historical satellite calibrations consistent with those of today's imagers, the Earth-observing community can benefit from a CDR that spans a minimum of 30 years. Most operational meteorological satellites rely on an onboard blackbody and space looks to provide on-orbit IR calibration, but neither target is traceable to absolute standards. The IR channels can also be affected by ice on the detector window, angle dependency of the scan mirror emissivity, stray-light, and detector-to-detector striping. Being able to quantify and correct such degradations would mean IR data from any satellite imager could contribute to a CDR. Recent efforts have focused on utilizing well-calibrated modern hyper-spectral sensors to intercalibrate concurrent operational IR imagers to a single reference. In order to consistently calibrate both historical and current IR imagers to the same reference, however, another strategy is needed. Large, well-characterized tropical-domain Earth targets have the potential of providing an Earth-view reference accuracy of within 0.5 K. To that effort, NASA Langley is developing an IR tropical mean calibration model in order to calibrate historical Advanced Very High Resolution Radiometer (AVHRR) instruments. Using Meteosat-9 (Met-9) as a reference, empirical models are built based on spatially/temporally binned Met-9 and AVHRR tropical IR brightness temperatures. By demonstrating the stability of the Met-9 tropical models, NOAA-18 AVHRR can be calibrated to Met-9 by matching the AVHRR monthly histogram averages with the Met-9 model. This method is validated with ray-matched AVHRR and Met-9 biasdifference time series. Establishing the validity of this empirical model will allow for the calibration of historical AVHRR sensors to within 0.5 K, and thereby establish a climate-quality IR data record.

  7. Predicting long-term neurological outcomes after severe traumatic brain injury requiring decompressive craniectomy: A comparison of the CRASH and IMPACT prognostic models.

    PubMed

    Honeybul, Stephen; Ho, Kwok M

    2016-09-01

    Predicting long-term neurological outcomes after severe traumatic brain (TBI) is important, but which prognostic model in the context of decompressive craniectomy has the best performance remains uncertain. This prospective observational cohort study included all patients who had severe TBI requiring decompressive craniectomy between 2004 and 2014, in the two neurosurgical centres in Perth, Western Australia. Severe disability, vegetative state, or death were defined as unfavourable neurological outcomes. Area under the receiver-operating-characteristic curve (AUROC) and slope and intercept of the calibration curve were used to assess discrimination and calibration of the CRASH (Corticosteroid-Randomisation-After-Significant-Head injury) and IMPACT (International-Mission-For-Prognosis-And-Clinical-Trial) models, respectively. Of the 319 patients included in the study, 119 (37%) had unfavourable neurological outcomes at 18-month after decompressive craniectomy for severe TBI. Both CRASH (AUROC 0.86, 95% confidence interval 0.81-0.90) and IMPACT full-model (AUROC 0.85, 95% CI 0.80-0.89) were similar in discriminating between favourable and unfavourable neurological outcome at 18-month after surgery (p=0.690 for the difference in AUROC derived from the two models). Although both models tended to over-predict the risks of long-term unfavourable outcome, the IMPACT model had a slightly better calibration than the CRASH model (intercept of the calibration curve=-4.1 vs. -5.7, and log likelihoods -159 vs. -360, respectively), especially when the predicted risks of unfavourable outcome were <80%. Both CRASH and IMPACT prognostic models were good in discriminating between favourable and unfavourable long-term neurological outcome for patients with severe TBI requiring decompressive craniectomy, but the calibration of the IMPACT full-model was better than the CRASH model. Crown Copyright © 2016. Published by Elsevier Ltd. All rights reserved.

  8. Long-term calibration monitoring of Spectralon diffusers BRDF in the air-ultraviolet.

    PubMed

    Georgiev, Georgi T; Butler, James J

    2007-11-10

    Long-term calibration monitoring of the bidirectional reflectance distribution function (BRDF) of Spectralon diffusers in the air-ultraviolet is presented. Four Spectralon diffusers were monitored in this study. Three of the diffusers, designated as H1, H2, and H3, were used in the prelaunch radiance calibration of the Solar Backscatter Ultraviolet/2 (SBUV/2) satellite instruments on National Oceanic and Atmospheric Administration (NOAA) 14 and 16. A fourth diffuser, designated as the 400 diffuser, was used in the prelaunch calibration of the Ozone Mapping and Profiler Suite (OMPS) instrument scheduled for initial flight in 2009 on the National Polar Orbiting Environmental Satellite System Preparatory Project. The BRDF data of this study were obtained between 1994 and 2005 using the scatterometer located in the National Aeronautics and Space Administration Goddard Space Flight Center Diffuser Calibration Laboratory. The diffusers were measured at 13 wavelengths between 230 and 425 nm at the incident and scatter angles used in the prelaunch calibrations of SBUV/2 and OMPS. Spectral features in the BRDF of Spectralon are also discussed. The comparison shows how the air-ultraviolet BRDF of these Spectralon samples changed over time under clean room deployment conditions.

  9. Development of Long-term Datasets from Satellite BUV Instruments: The "Soft" Calibration Approach

    NASA Technical Reports Server (NTRS)

    Bhartia, Pawan K.; Taylor, Steven; Jaross, Glen

    2005-01-01

    The first BUV instrument was launched in April 1970 on NASA's Nimbus4 satellite. More than a dozen instruments, broadly based on the same principle, but using very different technologies, have been launched in the last 35 years on NASA, NOAA, Japanese and European satellites. In this paper we describe the basic principles of the "soft" calibration approach that we have successfully applied to the data from many of these instruments to produce a consistent long-term record of total ozone, ozone profile and aerosols. This approach is based on using accurate radiative transfer models and assumed/known properties of the atmosphere in ultraviolet to derive calibration parameters. Although the accuracy of the results inevitably depends upon how well the assumed atmospheric properties are known, the technique has several built-in cross- checks that improve the robustness of the method. To develop further confidence in the data the soft calibration technique can be combined with data collected from few well- calibrated ground-based instruments. We will use examples from past and present BUV instruments to show how the method works.

  10. Related Studies in Long Term Lithium Battery Stability

    NASA Technical Reports Server (NTRS)

    Horning, R. J.; Chua, D. L.

    1984-01-01

    The continuing growth of the use of lithium electrochemical systems in a wide variety of both military and industrial applications is primarily a result of the significant benefits associated with the technology such as high energy density, wide temperature operation and long term stability. The stability or long term storage capability of a battery is a function of several factors, each important to the overall storage life and, therefore, each potentially a problem area if not addressed during the design, development and evaluation phases of the product cycle. Design (e.g., reserve vs active), inherent material thermal stability, material compatibility and self-discharge characteristics are examples of factors key to the storability of a power source.

  11. Atomic-Scale Origin of Long-Term Stability and High Performance of p-GaN Nanowire Arrays for Photocatalytic Overall Pure Water Splitting.

    PubMed

    Kibria, Md Golam; Qiao, Ruimin; Yang, Wanli; Boukahil, Idris; Kong, Xianghua; Chowdhury, Faqrul Alam; Trudeau, Michel L; Ji, Wei; Guo, Hong; Himpsel, F J; Vayssieres, Lionel; Mi, Zetian

    2016-10-01

    The atomic-scale origin of the unusually high performance and long-term stability of wurtzite p-GaN oriented nanowire arrays is revealed. Nitrogen termination of both the polar (0001¯) top face and the nonpolar (101¯0) side faces of the nanowires is essential for long-term stability and high efficiency. Such a distinct atomic configuration ensures not only stability against (photo) oxidation in air and in water/electrolyte but, as importantly, also provides the necessary overall reverse crystal polarization needed for efficient hole extraction in p-GaN. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Equilibrium high entropy alloy phase stability from experiments and thermodynamic modeling

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Saal, James E.; Berglund, Ida S.; Sebastian, Jason T.

    Long-term stability of high entropy alloys (HEAs) is a critical consideration for the design and practical application of HEAs. It has long been assumed that many HEAs are a kinetically-stabilized metastable structure, and recent experiments have confirmed this hypothesis by observing HEA ecomposition after long-termequilibration. In the presentwork,we demonstrate the use of the CALculation of PHAse Diagrams (CALPHAD) approach to predict HEA stability and processing parameters, comparing experimental long-term annealing observations to CALPHAD phase diagrams from a commercially-available HEA database. As a result, we find good agreement between single- and multi-phase predictions and experiments.

  13. Equilibrium high entropy alloy phase stability from experiments and thermodynamic modeling

    DOE PAGES

    Saal, James E.; Berglund, Ida S.; Sebastian, Jason T.; ...

    2017-10-29

    Long-term stability of high entropy alloys (HEAs) is a critical consideration for the design and practical application of HEAs. It has long been assumed that many HEAs are a kinetically-stabilized metastable structure, and recent experiments have confirmed this hypothesis by observing HEA ecomposition after long-termequilibration. In the presentwork,we demonstrate the use of the CALculation of PHAse Diagrams (CALPHAD) approach to predict HEA stability and processing parameters, comparing experimental long-term annealing observations to CALPHAD phase diagrams from a commercially-available HEA database. As a result, we find good agreement between single- and multi-phase predictions and experiments.

  14. Monitoring the On-Orbit Calibration of Terra MODIS Reflective Solar Bands Using Simultaneous Terra MISR Observations

    NASA Technical Reports Server (NTRS)

    Angal, Amit; Xiong, Xiaoxiong; Wu, Aisheng

    2016-01-01

    On December 18, 2015, the Terra spacecraft completed 16 years of successful operation in space. Terra has five instruments designed to facilitate scientific measurements of the earths land, ocean, and atmosphere. The Moderate Resolution Imaging Spectroradiometer (MODIS) and the Multiangle Imaging Spectroradiometer (MISR) instruments provide information for the temporal studies of the globe. After providing over 16 years of complementary measurements, a synergistic use of the measurements obtained from these sensors is beneficial for various science products. The 20 reflective solar bands (RSBs) of MODIS are calibrated using a combination of solar diffuser and lunar measurements, supplemented by measurements from pseudoinvariant desert sites. MODIS views the on-board calibrators and the earth via a two-sided scan mirror at three spatial resolutions: 250 m using 40 detectors in bands 1 and 2, 500 m using 20 detectors in bands 3 and 4, and 1000 m using 10 detectors in bands 819 and 26. Simultaneous measurements of the earths surface are acquired in a push-broom fashion by MISR at nine view angles spreading out in the forward and backward directions along the flight path. While the swath width for MISR acquisitions is 360 km, MODIS scans a wider swath of 2330 km via its two-sided scan mirror. The reflectance of the MODIS scan mirror has an angle dependence characterized by the response versus scan angle (RVS). Its on-orbit change is derived using the gain from a combination of on-board and earth-view measurements. The on-orbit RVS for MODIS has experienced a significant change, especially for the short-wavelength bands. The on-orbit RVS change for the short-wavelength bands (bands 3, 8, and 9) at nadir is observed to be greater than 10 over the mission lifetime. Due to absence of a scanning mechanism, MISR can serve as an effective tool to evaluate and monitor the on-orbit performance of the MODIS RVS. Furthermore, it can also monitor the detector and scan-mirror differences for the MODIS bands using simultaneous measurements from earth-scene targets, e.g., North Atlantic Ocean and North African desert. Simultaneous measurements provide the benefit of minimizing the impact of earth-scene features while comparing the radiometric performance using vicarious techniques. Long-term observations of both instruments using select ground targets also provide an evaluation of the long-term calibration stability. The goal of this paper is to demonstrate the use of MISR to monitor and enhance the on-orbit calibration of the MODIS RSB. The radiometric calibration requirements for the MODIS RSB are +/- 2% in reflectance and +/- 5% in radiance at typical radiance levels within +/- 45 deg. of nadir. The results show that the long-term changes in the MODIS reflectance at nadir frames are generally within 1. The MODIS level 1B calibrated products, generated after correcting for the on-orbit changes in the gain and RVS, do not have any correction for changes in the instruments polarization sensitivity. The mirror-side-dependent polarization sensitivity exhibits an on-orbit change, primarily in the blue bands, that manifests in noticeable mirror side differences in the MODIS calibrated products. The mirror side differences for other RSB are observed to be less than 1%, therefore demonstrating an excellent on-orbit performance. The detector differences in the blue bands of MODIS exhibit divergence in recent years beyond 1%, and a calibration algorithm improvement has been identified to mitigate this effect. Short-term variations in the recent year caused by the forward updates were identified in bands 1 and 2 and are planned to be corrected in the next reprocess.

  15. Ultrastable low-noise current amplifier: A novel device for measuring small electric currents with high accuracy

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Drung, D.; Krause, C.; Becker, U.

    2015-02-15

    An ultrastable low-noise current amplifier (ULCA) is presented. The ULCA is a non-cryogenic instrument based on specially designed operational amplifiers and resistor networks. It involves two stages, the first providing a 1000-fold current gain and the second performing a current-to-voltage conversion via an internal 1 MΩ reference resistor or, optionally, an external standard resistor. The ULCA’s transfer coefficient is highly stable versus time, temperature, and current amplitude within the full dynamic range of ±5 nA. The low noise level of 2.4 fA/√Hz helps to keep averaging times short at small input currents. A cryogenic current comparator is used to calibratemore » both input current gain and output transresistance, providing traceability to the quantum Hall effect. Within one week after calibration, the uncertainty contribution from short-term fluctuations and drift of the transresistance is about 0.1 parts per million (ppm). The long-term drift is typically 5 ppm/yr. A high-accuracy variant is available that shows improved stability of the input gain at the expense of a higher noise level of 7.5 fA/√Hz. The ULCA also allows the traceable generation of small electric currents or the calibration of high-ohmic resistors.« less

  16. Long-Term Stability of Scores on the Wechsler Intelligence Scale for Children-Fourth Edition in Children with Learning Disabilities

    ERIC Educational Resources Information Center

    Lander, Jenny

    2010-01-01

    The present investigation explored the stability of scores on the Wechsler Intelligence Scale for Children-IV (WISC-IV) over approximately a three-year period. Previous research has suggested that some children with Learning Disabilities (LD) do not demonstrate long-term stability of intelligence. Legally, school districts are no longer required…

  17. Establishing the Antarctic Dome C community reference standard site towards consistent measurements from Earth observation satellites

    USGS Publications Warehouse

    Cao, C.; Uprety, S.; Xiong, J.; Wu, A.; Jing, P.; Smith, D.; Chander, G.; Fox, N.; Ungar, S.

    2010-01-01

    Establishing satellite measurement consistency by using common desert sites has become increasingly more important not only for climate change detection but also for quantitative retrievals of geophysical variables in satellite applications. Using the Antarctic Dome C site (75°06′S, 123°21′E, elevation 3.2 km) for satellite radiometric calibration and validation (Cal/Val) is of great interest owing to its unique location and characteristics. The site surface is covered with uniformly distributed permanent snow, and the atmospheric effect is small and relatively constant. In this study, the long-term stability and spectral characteristics of this site are evaluated using well-calibrated satellite instruments such as the Moderate Resolution Imaging Spectroradiometer (MODIS) and Sea-viewing Wide Field-of-view Sensor (SeaWiFS). Preliminary results show that despite a few limitations, the site in general is stable in the long term, the bidirectional reflectance distribution function (BRDF) model works well, and the site is most suitable for the Cal/Val of reflective solar bands in the 0.4–1.0 µm range. It was found that for the past decade, the reflectivity change of the site is within 1.35% at 0.64 µm, and interannual variability is within 2%. The site is able to resolve calibration biases between instruments at a level of ~1%. The usefulness of the site is demonstrated by comparing observations from seven satellite instruments involving four space agencies, including OrbView-2–SeaWiFS, Terra–Aqua MODIS, Earth Observing 1 (EO-1) – Hyperion, Meteorological Operational satellite programme (MetOp) – Advanced Very High Resolution Radiometer (AVHRR), Envisat Medium Resolution Imaging Spectrometer (MERIS) – dvanced Along-Track Scanning Radiometer (AATSR), and Landsat 7 Enhanced Thematic Mapper Plus (ETM+). Dome C is a promising candidate site for climate quality calibration of satellite radiometers towards more consistent satellite measurements, as part of the framework for climate change detection and data quality assurance for the Global Earth Observation System of Systems (GEOSS).

  18. 75 FR 33769 - Manufacturing Extension Partnership (MEP) Availability of Funds for Projects To Develop and...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-06-15

    ... to the long-term economic stability of the region. Please see the NIST MEP Web site, http://www.nist... region, and contribute to the long-term economic stability of the region. Competitive projects will use...

  19. A uniform geostationary visible calibration approach to achieve a climate quality dataset

    NASA Astrophysics Data System (ADS)

    Haney, C.; Doelling, D.; Bhatt, R.; Scarino, B. R.; Gopalan, A.

    2013-12-01

    The geostationary (GEO) weather satellite visible and IR image record has surpassed 30 years. They have been preserved in the ISCCP-B1U 3-hourly dataset and other archives such as McIDAS, EUMETSAT, and NOAA CLASS. Since they were designed to aid in weather forecasting, long-term calibration stability was not a high priority. All GEO imagers lack onboard visible calibration and suffer from optical degradation after they are launched. In order to piece together the 35+ GEO satellite record both in time and space, a uniform calibration approach is desired to remove individual GEO temporal trends, as well as GEO spectral band differences. Otherwise, any artificial discontinuities caused by sequential GEO satellite records or spurious temporal trends caused by optical degradation may be interpreted as a change in climate. The approach relies on multiple independent methods to reduce the overall uncertainty of the GEO calibration coefficients. Consistency among methods validates the approach. During the MODIS record (2000 to the present) the GEO satellites are inter-calibrated against MODIS using ray-matched or bore-sighted radiance pairs. The MODIS and the VIIRS follow on instruments are equipped with onboard calibration thereby providing a stable calibration reference. The GEO spectral band differences are accounted for using a Spectral Band Adjustment Factor (SBAF) based on hyper-spectral SCIAMACHY data. During the pre-MODIS era, invariant earth targets of deserts and deep convective clouds (DCC) are used. Since GEO imagers have maintained their imaging scan schedules, GEO desert and DCC bidirectional reflectance distribution functions (BRDF) can be constructed and validated during the MODIS era. The BRDF models can then be applied to historical GEO imagers. Consistency among desert and DCC GEO calibration gains validates the approach. This approach has been applied to the GEO record beginning in 1985 and the results will be presented at the meeting.

  20. Consideration of measurement error when using commercial indoor radon determinations for selecting radon action levels

    USGS Publications Warehouse

    Reimer, G.M.; Szarzi, S.L.; Dolan, Michael P.

    1998-01-01

    An examination of year-long, in-home radon measurement in Colorado from commercial companies applying typical methods indicates that considerable variation in precision exists. This variation can have a substantial impact on any mitigation decisions, either voluntary or mandated by law, especially regarding property sale or exchange. Both long-term exposure (nuclear track greater than 90 days), and short-term (charcoal adsorption 4-7 days) exposure methods were used. In addition, periods of continuous monitoring with a highly calibrated alpha-scintillometer took place for accuracy calibration. The results of duplicate commercial analysis show that typical results are no better than ??25 percent with occasional outliers (up to 5 percent of all analyses) well beyond that limit. Differential seasonal measurements (winter/summer) by short-term methods provide equivalent information to single long-term measurements. Action levels in the U.S. for possible mitigation decisions should be selected so that they consider the measurement variability; specifically, they should reflect a concentration range similar to that adopted by the European Community.

  1. Local-scale spatial modelling for interpolating climatic temperature variables to predict agricultural plant suitability

    NASA Astrophysics Data System (ADS)

    Webb, Mathew A.; Hall, Andrew; Kidd, Darren; Minansy, Budiman

    2016-05-01

    Assessment of local spatial climatic variability is important in the planning of planting locations for horticultural crops. This study investigated three regression-based calibration methods (i.e. traditional versus two optimized methods) to relate short-term 12-month data series from 170 temperature loggers and 4 weather station sites with data series from nearby long-term Australian Bureau of Meteorology climate stations. The techniques trialled to interpolate climatic temperature variables, such as frost risk, growing degree days (GDDs) and chill hours, were regression kriging (RK), regression trees (RTs) and random forests (RFs). All three calibration methods produced accurate results, with the RK-based calibration method delivering the most accurate validation measures: coefficients of determination ( R 2) of 0.92, 0.97 and 0.95 and root-mean-square errors of 1.30, 0.80 and 1.31 °C, for daily minimum, daily maximum and hourly temperatures, respectively. Compared with the traditional method of calibration using direct linear regression between short-term and long-term stations, the RK-based calibration method improved R 2 and reduced root-mean-square error (RMSE) by at least 5 % and 0.47 °C for daily minimum temperature, 1 % and 0.23 °C for daily maximum temperature and 3 % and 0.33 °C for hourly temperature. Spatial modelling indicated insignificant differences between the interpolation methods, with the RK technique tending to be the slightly better method due to the high degree of spatial autocorrelation between logger sites.

  2. Rubidium-traced white-light etalon calibrator for radial velocity measurements at the cm s-1 level

    NASA Astrophysics Data System (ADS)

    Stürmer, Julian; Seifahrt, Andreas; Schwab, Christian; Bean, Jacob L.

    2017-04-01

    We report on the construction and testing of a vacuum-gap Fabry-Pérot etalon calibrator for high precision radial velocity spectrographs. Our etalon is traced against a rubidium frequency standard to provide a cost effective, yet ultra precise wavelength reference. We describe here a turn-key system working at 500 to 900 nm, ready to be installed at any current and next-generation radial velocity spectrograph that requires calibration over a wide spectral bandpass. Where appropriate, we have used off-the-shelf, commercial components with demonstrated long-term performance to accelerate the development timescale of this instrument. Our system combines for the first time the advantages of passively stabilized etalons for optical and near-infrared wavelengths with the laser-locking technique demonstrated for single-mode fiber etalons. We realize uncertainties in the position of one etalon line at the 10 cm s-1 level in individual measurements taken at 4 Hz. When binning the data over 10 s, we are able to trace the etalon line with a precision of better than 3 cm s-1. We present data obtained during a week of continuous operation where we detect (and correct for) the predicted, but previously unobserved shrinking of the etalon Zerodur spacer corresponding to a shift of 13 cm s-1 per day.

  3. Nimbus-7 Earth radiation budget calibration history. Part 2: The Earth flux channels

    NASA Technical Reports Server (NTRS)

    Kyle, H. Lee; Hucek, Douglas Richard R.; Ardanuy, Philip E.; Hickey, John R.; Maschhoff, Robert H.; Penn, Lanning M.; Groveman, Brian S.; Vallette, Brenda J.

    1994-01-01

    Nine years (November 1978 to October 1987) of Nimbus-7 Earth radiation budget (ERB) products have shown that the global annual mean emitted longwave, absorbed shortwave, and net radiation were constant to within about + 0.5 W/sq m. Further, most of the small annual variations in the emitted longwave have been shown to be real. To obtain this measurement accuracy, the wide-field-of-view (WFOV) Earth-viewing channels 12 (0.2 to over 50 micrometers), 13 (0.2 to 3.8 micrometers), and 14 (0.7 to 2.8 micrometers) have been characterized in their satellite environment to account for signal variations not considered in the prelaunch calibration equations. Calibration adjustments have been derived for (1) extraterrestrial radiation incident on the detectors, (2) long-term degradation of the sensors, and (3) thermal perturbations within the ERB instrument. The first item is important in all the channels; the second, mainly in channels 13 and 14, and the third, only in channels 13 and 14. The Sun is used as a stable calibration source to monitor the long-term degradation of the various channels. Channel 12, which is reasonably stable to both thermal perturbations and sensor degradation, is used as a reference and calibration transfer agent for the drifting sensitivities of the filtered channels 13 and 14. Redundant calibration procedures were utilized. Laboratory studies complemented analyses of the satellite data. Two nearly independent models were derived to account for the thermal perturbations in channels 13 and 14. The global annual mean terrestrial shortwave and longwave signals proved stable enough to act as secondary calibration sources. Instantaneous measurements may still, at times, be in error by as much as a few Wm(exp -2), but the long-term averages are stable to within a fraction of a Wm(exp -2).

  4. SEALDH-II-An Autonomous, Holistically Controlled, First Principles TDLAS Hygrometer for Field and Airborne Applications: Design-Setup-Accuracy/Stability Stress Test.

    PubMed

    Buchholz, Bernhard; Kallweit, Sören; Ebert, Volker

    2016-12-30

    Instrument operation in harsh environments often significantly impacts the trust level of measurement data. While commercial instrument manufacturers clearly define the deployment conditions to achieve trustworthy data in typical standard applications, it is frequently unavoidable in scientific field applications to operate instruments outside these commercial standard application specifications. Scientific instrumentation, however, is employing cutting-edge technology and often highly optimized but also lacks long-term field tests to assess the field vs. laboratory performance. Recently, we developed the Selective Extractive Laser Diode Hygrometer (SEALDH-II), which addresses field and especially airborne applications as well as metrological laboratory validations. SEALDH-II targets reducing deviations between airborne hygrometers (currently up to 20% between the most advanced hygrometers) with a new holistic, internal control and validation concept, which guarantees the transfer of the laboratory performance into a field scenario by capturing more than 80 instrument internal "housekeeping" data to nearly perfectly control SEALDH-II's health status. SEALDH-II uses a calibration-free, first principles based, direct Tuneable Diode Laser Absorption Spectroscopy (dTDLAS) approach, to cover the entire atmospheric humidity measurement range from about 3 to 40,000 ppmv with a calculated maximum uncertainty of 4.3% ± 3 ppmv. This is achieved not only by innovations in internal instrument monitoring and design, but also by active control algorithms such as a high resolution spectral stabilization. This paper describes the setup, working principles, and instrument stabilization, as well as its precision validation and long-term stress tests in an environmental chamber over an environmental temperature and humidity range of ΔT = 50 K and ΔRH = 80% RH, respectively.

  5. SEALDH-II—An Autonomous, Holistically Controlled, First Principles TDLAS Hygrometer for Field and Airborne Applications: Design–Setup–Accuracy/Stability Stress Test

    PubMed Central

    Buchholz, Bernhard; Kallweit, Sören; Ebert, Volker

    2016-01-01

    Instrument operation in harsh environments often significantly impacts the trust level of measurement data. While commercial instrument manufacturers clearly define the deployment conditions to achieve trustworthy data in typical standard applications, it is frequently unavoidable in scientific field applications to operate instruments outside these commercial standard application specifications. Scientific instrumentation, however, is employing cutting-edge technology and often highly optimized but also lacks long-term field tests to assess the field vs. laboratory performance. Recently, we developed the Selective Extractive Laser Diode Hygrometer (SEALDH-II), which addresses field and especially airborne applications as well as metrological laboratory validations. SEALDH-II targets reducing deviations between airborne hygrometers (currently up to 20% between the most advanced hygrometers) with a new holistic, internal control and validation concept, which guarantees the transfer of the laboratory performance into a field scenario by capturing more than 80 instrument internal “housekeeping” data to nearly perfectly control SEALDH-II’s health status. SEALDH-II uses a calibration-free, first principles based, direct Tuneable Diode Laser Absorption Spectroscopy (dTDLAS) approach, to cover the entire atmospheric humidity measurement range from about 3 to 40,000 ppmv with a calculated maximum uncertainty of 4.3% ± 3 ppmv. This is achieved not only by innovations in internal instrument monitoring and design, but also by active control algorithms such as a high resolution spectral stabilization. This paper describes the setup, working principles, and instrument stabilization, as well as its precision validation and long-term stress tests in an environmental chamber over an environmental temperature and humidity range of ΔT = 50 K and ΔRH = 80% RH, respectively. PMID:28042844

  6. Solubility of Sulfur in Shergottitic Silicate Melts Up to 0.8 GPA: Implications for S Contents of Shergottites

    NASA Technical Reports Server (NTRS)

    Righter, K.; Pando, K.M.; Danielson, L.

    2009-01-01

    Shergottites have high S contents (1300 to 4600 ppm; [1]), but it is unclear if they are sulfide saturated or under-saturated. This issue has fundamental implications for determining the long term S budget of the martian surface and atmosphere (from mantle degassing), as well as evolution of the highly siderophile elements (HSE) Au, Pd, Pt, Re, Rh, Ru, Ir, and Os, since concentrations of the latter are controlled by sulfide stability. Resolution of sulfide saturation depends upon temperature, pressure, oxygen fugacity (and FeO), and magma composition [2]. Expressions derived from experimental studies allow prediction of S contents, though so far they are not calibrated for shergottitic liquids [3-5]. We have carried out new experiments designed to test current S saturation models, and then show that existing calibrations are not suitable for high FeO and low Al2O3 compositions characteristic of shergottitic liquids. The new results show that existing models underpredict S contents of sulfide saturated shergottitic liquids by a factor of 2.

  7. Coastal zone color scanner 'system calibration': A retrospective examination

    NASA Technical Reports Server (NTRS)

    Evans, Robert H.; Gordon, Howard R.

    1994-01-01

    During its lifetime the Coastal Zone Color Scanner (CZCS) produced approximately 66,000 images. These have been placed in an archive of 'raw' radiance (sensor counts) in a subsampled format that is easily accessible. They have also been processed to form global fields, at reduced resolution, of normalized water-leaving radiance, phytoplankton pigments, and diffuse attenuation coefficient. Using this archive, we have tried to characterize some aspects of the 'system calibration' for the 8-year lifetime of CZCS. Specifically, we have assumed that the sensitivity of the red band decayed in a simple manner similar to the well-known long-term degradation of the shorter-wavelength bands, and we examined the sensitivity of the green and yellow bands by computing the globally averaged water-leaving radiance, over 10-day periods, for all of the imagery. The results provided evidence that in addition to the long-term degradation, short-term (2 weeks to 1 month) variations in the radiometric sensitivity of these bands started in early fall 1981 and continued for the rest of the mission. In contrast, the data suggested the absence of such variations prior to August 1981. It is reasonable to believe that the sensitivity of the blue (and probably the red) band underwent such variations as well; however our methodology cannot be used to study the other bands. Thus, after these fluctuations began, the actual values of CZCS - estimated pigment concentrations at a given location should be viewed with skepticism; however, the global patterns of derived pigment concentrations should be valid. Had an extensive set of surface measurements of water-leaving radiance, e.r., from moored buoyes or drifters, had been available during the CZCS mission, these fluctuations could have been removed from the data set, and this would have greatly increased its value. The lessons learned from CZCS that is, the requirement of good radiometric calibration and stability and the necessity of 'sea truth' stations to monitor the performance of the system (sensor plus algorithms), are being applied to the sea-viewing wide-field-of-view senso (Sea WiFS) scheduled for launch in August 1993.

  8. Coastal zone color scanner ``system calibration'': A retrospective examination

    NASA Astrophysics Data System (ADS)

    Evans, Robert H.; Gordon, Howard R.

    1994-04-01

    During its lifetime the coastal zone color scanner (CZCS) produced approximately 66,000 images. These have been placed in an archive of "raw" radiance (sensor counts) in a subsampled format that is easily accessible. They have also been processed to form global fields, at reduced resolution, of normalized water-leaving radiance, phytoplankton pigments, and diffuse attenuation coefficient. Using this archive, we have tried to characterize some aspects of the "system calibration" for the 8-year lifetime of CZCS. Specifically, we have assumed that the sensitivity of the red band decayed in a simple manner similar to the well-known long-term degradation of the shorter-wavelength bands, and we examined the sensitivity of the green and yellow bands by computing the globally averaged water-leaving radiance, over 10-day periods, for all of the imagery. The results provide evidence that in addition to the long-term degradation, short-term (2 weeks to 1 month) variations in the radiometric sensitivity of these bands started in early fall 1981 and continued for the rest of the mission. In contrast, the data suggest the absence of such variations prior to August 1981. It is reasonable to believe that the sensitivity of the blue (and probably the red) band underwent such variations as well; however, our methodology cannot be used to study the other bands. Thus after these fluctuations began, the actual values of CZCS-estimated pigment concentrations at a given location should be viewed with skepticism; however, the global patterns of derived pigment concentration should be valid. Had an extensive set of surface measurements of water-leaving radiance, e.g., from moored buoys or drifters, been available during the CZCS mission, these fluctuations could have been removed from the data set, and this would have greatly increased its value. The lessons learned from CZCS, that is, the requirement of good radiometric calibration and stability and the necessity of "sea truth" stations to monitor the performance of the system (sensor plus algorithms), are being applied to the seaviewing wide-field-of-view sensor (SeaWiFS) scheduled for launch in August 1993.

  9. Diffuse sunlight based calibration of the water vapor channel in the upc raman lidar

    NASA Astrophysics Data System (ADS)

    Muñoz-Porcar, Constantino; Comeron, Adolfo; Sicard, Michaël; Barragan, Ruben; Garcia-Vizcaino, David; Rodríguez-Gómez, Alejandro; Rocadenbosch, Francesc

    2018-04-01

    A method for determining the calibration factor of the water vapor channel of a Raman lidar, based on zenith measurements of diffuse sunlight and on assumptions regarding some system parameters and Raman scattering models, has been applied to the lidar system of Universitat Politècnica de Catalunya (UPC; Technical University of Catalonia, Spain). Results will be analyzed in terms of stability and comparison with typical methods relying on simultaneous radiosonde measurements.

  10. Some Thoughts on Stability in Nonlinear Periodic Focusing Systems [Addendum

    DOE R&D Accomplishments Database

    McMillan, Edwin M.

    1968-03-29

    Addendum to September 5, 1967 report with the same title and with the abstract: A brief discussion is given of the long-term stability of particle motions through periodic focusing structures containing lumped nonlinear elements. A method is presented whereby one can specify the nonlinear elements in such a way as to generate a variety of structures in which the motion has long-term stability.

  11. Understanding the interdiffusion behavior and determining the long term stability of tungsten fiber reinforced niobium-base matrix composite systems

    NASA Technical Reports Server (NTRS)

    Tien, John K.

    1990-01-01

    The long term interdiffusional stability of tungsten fiber reinforced niobium alloy composites is addressed. The matrix alloy that is most promising for use as a high temperature structural material for reliable long-term space power generation is Nb1Zr. As an ancillary project to this program, efforts were made to assess the nature and kinetics of interphase reaction between selected beryllide intermetallics and nickel and iron aluminides.

  12. Hydrodynamic Energy Saving Enhancements for DDG 51 Class Ships

    DTIC Science & Technology

    2012-02-01

    temperature and pressure in the hydraulic pitch control system, expansion and contraction of the pitch control rods, improper pitch calibration procedure ...outdated pitch calibration, etc. Experience during hot pitch calibration procedures conducted by NSWCCD prior to powering trials has indicated that...18% increase in power.10 Sea trials conducted during a long-term evaluation on the USS WHIPPLE (FF 1062), showed that by 800 days out of drydock

  13. From Cell to Module: Fabrication and Long-term Stability of Dye-sensitized Solar Cells

    NASA Astrophysics Data System (ADS)

    Nursam, N. M.; Hidayat, J.; Muliani, L.; Anggraeni, P. N.; Retnaningsih, L.; Idayanti, N.

    2017-07-01

    Dye-sensitized solar cell (DSSC), which has been firstly developed by Graetzel et al back in 1991, has attracted a considerable interest since its discovery. However, two of the main challenges that the DSSC technology will have to overcome towards commercialization involve device scale-up and long-term stability. In our group, the fabrication technology of DSSC has been developed from laboratory to module scale over the past few years, nevertheless, the long-term stability has still became a major concern. In this contribution, the long-term DSSC performance in relation to their scale-up from cell to module is investigated. The photoelectrode of the DSSCs were fabricated using nanocrystalline titanium dioxide materials that were subsequently sensitized using ruthenium-based dye. Additionally, TiCl4 pre- and post-treatment were carried out to enhance the overall device efficiency. When fabricated as cells, the DSSC prototypes showed relatively stable performance during repeated tests over three months. In order to increase the output power of the solar cells, the DSSCs were then connected in a Z-type series connection to obtain sub-module panels. The DSSC sub-modules exhibit poor stability, particularly as indicated by the significant decrease in the short circuit current (ISC ). Herein, the effect of photoelectrode and sealant materials as well as module design are investigated, highlighting their profound influence upon the DSSC efficiency and long-term stability.

  14. 'Enzyme Test Bench': A biochemical application of the multi-rate modeling

    NASA Astrophysics Data System (ADS)

    Rachinskiy, K.; Schultze, H.; Boy, M.; Büchs, J.

    2008-11-01

    In the expanding field of 'white biotechnology' enzymes are frequently applied to catalyze the biochemical reaction from a resource material to a valuable product. Evolutionary designed to catalyze the metabolism in any life form, they selectively accelerate complex reactions under physiological conditions. Modern techniques, such as directed evolution, have been developed to satisfy the increasing demand on enzymes. Applying these techniques together with rational protein design, we aim at improving of enzymes' activity, selectivity and stability. To tap the full potential of these techniques, it is essential to combine them with adequate screening methods. Nowadays a great number of high throughput colorimetric and fluorescent enzyme assays are applied to measure the initial enzyme activity with high throughput. However, the prediction of enzyme long term stability within short experiments is still a challenge. A new high throughput technique for enzyme characterization with specific attention to the long term stability, called 'Enzyme Test Bench', is presented. The concept of the Enzyme Test Bench consists of short term enzyme tests conducted under partly extreme conditions to predict the enzyme long term stability under moderate conditions. The technique is based on the mathematical modeling of temperature dependent enzyme activation and deactivation. Adapting the temperature profiles in sequential experiments by optimum non-linear experimental design, the long term deactivation effects can be purposefully accelerated and detected within hours. During the experiment the enzyme activity is measured online to estimate the model parameters from the obtained data. Thus, the enzyme activity and long term stability can be calculated as a function of temperature. The results of the characterization, based on micro liter format experiments of hours, are in good agreement with the results of long term experiments in 1L format. Thus, the new technique allows for both: the enzyme screening with regard to the long term stability and the choice of the optimal process temperature. The presented article gives a successful example for the application of multi-rate modeling, experimental design and parameter estimation within biochemical engineering. At the same time, it shows the limitations of the methods at the state of the art and addresses the current problems to the applied mathematics community.

  15. A Novel Miniature Wide-band Radiometer for Space Applications

    NASA Astrophysics Data System (ADS)

    Sykulska-Lawrence, H. M.

    2016-12-01

    Design, development and testing of a novel miniaturised infrared radiometer is described. The instrument opens up new possibilities in planetary science of deployment on smaller platforms - such as unmanned aerial vehicles and microprobes - to enable study of a planet's radiation balance, as well as terrestrial volcano plumes and trace gases in planetary atmospheres, using low-cost long-term observations. Thus a key enabling development is that of miniaturised, low-power and well-calibrated instrumentation. The talk reports advances in miniature technology to perform high accuracy visible / IR remote sensing measurements. The infrared radiometer is akin to those widely used for remote sensing for earth and space applications, which are currently either large instruments on orbiting platforms or medium-sized payloads on balloons. We use MEMS microfabrication techniques to shrink a conventional design, while combining the calibration benefits of large (>1kg) type radiometers with the flexibility and portability of a <10g device. The instrument measures broadband (0.2 to 100µm) upward and downward radiation fluxes, showing improvements in calibration stability and accuracy,with built-in calibration capability, incorporating traceability to temperature standards such as ITS-90. The miniature instrument described here was derived from a concept developed for a European Space Agency study, Dalomis (Proc. of 'i-SAIRAS 2005', Munich, 2005), which involved dropping multiple probes into the atmosphere of Venus from a balloon to sample numerous parts of the complex weather systems on the planet. Data from such an in-situ instrument would complement information from a satellite remote sensing instrument or balloon radiosonde. Moreover, the addition of an internal calibration standard facilitates comparisons between datasets. One of the main challenges for a reduced size device is calibration. We use an in-situ method whereby a blackbody source is integrated within the device and a micromirror switches the input to the detector between the measured signal and the calibration target. Achieving two well-calibrated radiometer channels within a small (<10g) payload is made possible by using modern micromachining techniques.

  16. Search for double beta decay with HPGe detectors at the Gran Sasso underground laboratory

    NASA Astrophysics Data System (ADS)

    Chkvorets, Oleg

    2008-12-01

    Neutrinoless double-beta decay is practically the only way to establish the Majorana nature of the neutrino mass and its decay rate provides a probe of an effective neutrino mass. Double beta experiments are long-running underground experiments with specific challenges concerning the background reduction and the long term stability. These problems are addressed in this work for the Heidelberg-Moscow (HdM), GENIUS Test Facility (TF) and GERDA experiments. The HdM experiment collected data with enriched 76Ge high purity (HPGe) detectors from 1990 to 2003. An improved analysis of HdM data is presented, exploiting new calibration and spectral shape measurements with the HdM detectors. GENIUS-TF was a test-facility that verified the feasibility of using bare germanium detectors in liquid nitrogen. The first year results of this experiment are discussed. The GERDA experiment has been designed to further increase the sensitivity by operating bare germanium detectors in a high purity cryogenic liquid, which simultaneously serves as a shielding against background and as a cooling media. In the preparatory stage of GERDA, an external background gamma flux measurement was done at the experimental site in the Hall A of the Gran Sasso laboratory. The characterization of the enriched detectors from the HdM and IGEX experiments was performed in the underground detector laboratory for the GERDA collaboration. Long term stability measurements of a bare HPGe detector in liquid argon were carried out. Based on these measurements, the first lower limit on the half-life of neutrinoless double electron capture of 36Ar was established to be 1.85*10^18 years at 68% C.L.

  17. On-ground re-calibration of the GOME-2 satellite spectrometer series

    NASA Astrophysics Data System (ADS)

    Otter, Gerard; Dijkhuizen, Niels; Vosteen, Amir; Brinkers, Sanneke; Gür, Bilgehan; Kenter, Pepijn; Sallusti, Marcello; Tomuta, Dana; Veratti, Rubes; Cappani, Annalisa

    2017-11-01

    The Global Ozone Monitoring Experiment-2[1] (GOME-2) represents one of the European instruments carried on board the MetOp satellite within the ESA's "Living Planet Program". Consisting of three flight models (FM's) it is intended to provide long-term monitoring of atmospheric ozone and other trace gases over a time frame of 15-20 years, thus contributing valuable input towards climate and atmospheric research and providing near real-time data for use in air quality forecasting. The ambition to achieve highly accurate scientific results requires a thorough calibration and characterization of the instrument prior to launch. These calibration campaigns were performed by TNO in Delft in the Netherlands, in the "Thermal Vacuum Calibration Facility" of the institute. Due to refurbishment and / or storage of the instruments over a period of a few years, several re-calibration campaigns were necessary. These re-calibrations provided the unique opportunity to study the effects of long term storage and build up statistics on the instrument as well as the calibration methods used. During the re-calibration of the second flight model a difference was found in the radiometric calibration output, which was not understood initially. In order to understand the anomalies on the radiometry, a deep investigation was performed using numerous variations of the setup and different sources. The major contributor was identified to be a systematic error in the alignment, for which a correction was applied. Apart from this, it was found that the geometry of the sources influenced the results. Based on the calibration results combined with a theoretical geometrical hypothesis inferred that the on-ground calibration should mimic as close as possible the in-orbit geometry.

  18. BOUSSOLE: A Joint CNRS-INSU, ESA, CNES, and NASA Ocean Color Calibration and Validation Activity

    NASA Technical Reports Server (NTRS)

    Antoine, David; Chami, Malik; Claustre, Herve; d'Ortenzio, Fabrizio; Morel, Andre; Becu, Guislain; Gentili, Bernard; Louis, Francis; Ras, Josephine; Roussier, Emmanuel; hide

    2006-01-01

    This report presents the Bouee pour l'acquisition de Series Optiques a Long Terme (BOUSSOLE) project, the primary objectives of which are to provide a long-term time series of optical properties in support of a) calibration and validation activities associated with satellite ocean color missions, and b) bio-optical research in oceanic waters. The following are included in the report: 1) an introduction to the rationale for establishing the project; 2) a definition of vicarious calibration and the specific requirements attached to it; 3) the organization of the project and the characteristics of the measurement site--in the northwestern Mediterranean Sea; 4) a qualitative overview of the collected data; 5) details about the buoy that was specifically designed and built for this project; 6) data collection protocols and data processing techniques; 7) a quantitative summary of the collected data, and a discussion of some sample results, including match-up analyses for the currently operational ocean color sensors, namely MERIS, SeaWiFS, and MODIS; and 8) preliminary results of the vicarious radiometric calibration of MERIS, including a tentative uncertainty budget. The results of this match-up analysis allow performance comparisons of various ocean color sensors to be performed, demonstrating the ability of the BOUSSOLE activity, i.e., combining a dedicated platform and commercial-off-the-shelf instrumentation, to provide data qualified to monitor the quality of ocean color products on the long term.

  19. Limitations and possibilities of green synthesis and long-term stability of colloidal Ag nanoparticles

    NASA Astrophysics Data System (ADS)

    Velgosová, Oksana; Mražíková, Anna

    2017-12-01

    In this paper the influence of algae life cycle and the solutions pH on the green synthesis of colloidal Ag nanoparticles (AgNPs) as well as effect of different storage conditions on AgNPs long-term stability was investigated. Silver nanoparticles were biologically synthesized using extracts of Parachlorella kessleri algae cultivated 1, 2, 3 and 4 weeks. The formation of AgNPs was monitored using a UV-vis spectrophotometer and verified by TEM observation. The results confirmed formation of polyhedron and/or near polyhedron AgNPs, ranging between 5 and 60 nm in diameter. The age of algae influenced the synthesis rate and an amount of AgNPs in solution. The best results were obtained using tree weeks old algae. UV-vis analysis and TEM observation also revealed that the size and the stability of AgNPs depend on the pH of solution. AgNPs formed in solutions of higher pH (8 and 10) are polyhedron, fine, with narrow size interval and stabile. Nanoparticles formed in solutions of low pH (2, 4 and 6) started to lose their stability on 10th day of experiment, and the particle size interval was wide. The long-term stability of AgNPs can be influenced by light and temperature conditions. The most significant stability loss was observed at day light and room temperature (21°C). After 200-days significant amount of agglomerated particles settled on the bottom of the Erlenmeyer flask. AgNPs stored at dark and room temperature showed better long-term stability, weak particles agglomeration was observed. AgNPs stored at dark and at temperature 5°C showed the best long-term stability. Such AgNPs remained spherical, fine (5-20 nm), with narrow size interval and stable (no agglomeration) even after more than six months.

  20. Long-term greenhouse gas measurements from aircraft

    NASA Astrophysics Data System (ADS)

    Karion, A.; Sweeney, C.; Wolter, S.; Newberger, T.; Chen, H.; Andrews, A.; Kofler, J.; Neff, D.; Tans, P.

    2013-03-01

    In March 2009 the NOAA/ESRL/GMD Carbon Cycle and Greenhouse Gases Group collaborated with the US Coast Guard (USCG) to establish the Alaska Coast Guard (ACG) sampling site, a unique addition to NOAA's atmospheric monitoring network. This collaboration takes advantage of USCG bi-weekly Arctic Domain Awareness (ADA) flights, conducted with Hercules C-130 aircraft from March to November each year. Flights typically last 8 h and cover a large area, traveling from Kodiak up to Barrow, Alaska, with altitude profiles near the coast and in the interior. NOAA instrumentation on each flight includes a flask sampling system, a continuous cavity ring-down spectroscopy (CRDS) carbon dioxide (CO2)/methane (CH4)/carbon monoxide (CO)/water vapor (H2O) analyzer, a continuous ozone analyzer, and an ambient temperature and humidity sensor. Air samples collected in flight are analyzed at NOAA/ESRL for the major greenhouse gases and a variety of halocarbons and hydrocarbons that influence climate, stratospheric ozone, and air quality. We describe the overall system for making accurate greenhouse gas measurements using a CRDS analyzer on an aircraft with minimal operator interaction and present an assessment of analyzer performance over a three-year period. Overall analytical uncertainty of CRDS measurements in 2011 is estimated to be 0.15 ppm, 1.4 ppb, and 5 ppb for CO2, CH4, and CO, respectively, considering short-term precision, calibration uncertainties, and water vapor correction uncertainty. The stability of the CRDS analyzer over a seven-month deployment period is better than 0.15 ppm, 2 ppb, and 4 ppb for CO2, CH4, and CO, respectively, based on differences of on-board reference tank measurements from a laboratory calibration performed prior to deployment. This stability is not affected by variation in pressure or temperature during flight. We conclude that the uncertainty reported for our measurements would not be significantly affected if the measurements were made without in-flight calibrations, provided ground calibrations and testing were performed regularly. Comparisons between in situ CRDS measurements and flask measurements are consistent with expected measurement uncertainties for CH4 and CO, but differences are larger than expected for CO2. Biases and standard deviations of comparisons with flask samples suggest that atmospheric variability, flask-to-flask variability, and possible flask sampling biases may be driving the observed flask versus in situ CO2 differences rather than the CRDS measurements.

  1. Assessing applicability of SWAT calibrated at multiple spatial scales from field to stream

    USDA-ARS?s Scientific Manuscript database

    The capability of SWAT for simulating long-term hydrology and water quality was evaluated using data collected in subwatershed K of the Little River Experimental watershed located in South Atlantic Coastal Plain of the USA. The SWAT model was calibrated to measurements made at various spatial scales...

  2. Scaling and calibration of a core validation site for the soil moisture active passive mission

    USDA-ARS?s Scientific Manuscript database

    The calibration and validation of soil moisture remote sensing products is complicated due to the logistics of installing a long term soil moisture monitoring network in an active landscape. It is more efficient to locate these stations along agricultural field boundaries, but unfortunately this oft...

  3. In Vivo Integrity and Biological Fate of Chelator-Free Zirconium-89-Labeled Mesoporous Silica Nanoparticles

    PubMed Central

    2015-01-01

    Traditional chelator-based radio-labeled nanoparticles and positron emission tomography (PET) imaging are playing vital roles in the field of nano-oncology. However, their long-term in vivo integrity and potential mismatch of the biodistribution patterns between nanoparticles and radio-isotopes are two major concerns for this approach. Here, we present a chelator-free zirconium-89 (89Zr, t1/2 = 78.4 h) labeling of mesoporous silica nanoparticle (MSN) with significantly enhanced in vivo long-term (>20 days) stability. Successful radio-labeling and in vivo stability are demonstrated to be highly dependent on both the concentration and location of deprotonated silanol groups (−Si–O–) from two types of silica nanoparticles investigated. This work reports 89Zr-labeled MSN with a detailed labeling mechanism investigation and long-term stability study. With its attractive radio-stability and the simplicity of chelator-free radio-labeling, 89Zr-MSN offers a novel, simple, and accurate way for studying the in vivo long-term fate and PET image-guided drug delivery of MSN in the near future. PMID:26213260

  4. In Vivo Integrity and Biological Fate of Chelator-Free Zirconium-89-Labeled Mesoporous Silica Nanoparticles.

    PubMed

    Chen, Feng; Goel, Shreya; Valdovinos, Hector F; Luo, Haiming; Hernandez, Reinier; Barnhart, Todd E; Cai, Weibo

    2015-08-25

    Traditional chelator-based radio-labeled nanoparticles and positron emission tomography (PET) imaging are playing vital roles in the field of nano-oncology. However, their long-term in vivo integrity and potential mismatch of the biodistribution patterns between nanoparticles and radio-isotopes are two major concerns for this approach. Here, we present a chelator-free zirconium-89 ((89)Zr, t1/2 = 78.4 h) labeling of mesoporous silica nanoparticle (MSN) with significantly enhanced in vivo long-term (>20 days) stability. Successful radio-labeling and in vivo stability are demonstrated to be highly dependent on both the concentration and location of deprotonated silanol groups (-Si-O(-)) from two types of silica nanoparticles investigated. This work reports (89)Zr-labeled MSN with a detailed labeling mechanism investigation and long-term stability study. With its attractive radio-stability and the simplicity of chelator-free radio-labeling, (89)Zr-MSN offers a novel, simple, and accurate way for studying the in vivo long-term fate and PET image-guided drug delivery of MSN in the near future.

  5. Stability of Chronic Hepatitis-Related Parameters in Serum Samples After Long-Term Storage.

    PubMed

    Yu, Rentao; Dan, Yunjie; Xiang, Xiaomei; Zhou, Yi; Kuang, Xuemei; Yang, Ge; Tang, Yulan; Liu, Mingdong; Kong, Weilong; Tan, Wenting; Deng, Guohong

    2017-06-01

    Serum samples are widely used in clinical research, but a comprehensive research of the stability of parameters relevant to chronic hepatitis and the effect of a relatively long-term (up to 10 years) storage on the stability have rarely been studied. To investigate the stability of chronic hepatitis-related parameters in serum samples after long-term storage. The storage stability of common clinical parameters such as total bile acid (TBA), total bilirubin (TBIL), potassium, cholesterol, and protein parameters such as alanine aminotransferase (ALT), creatine kinase (CK), γ-glutamyltransferase (GGT), albumin, high-density lipoprotein (HDL) and also hepatitis B virus (HBV) DNA, hepatitis C virus (HCV) RNA, hepatitis B surface antigen (HBsAg), and chemokine (C-X-C motif) ligand 10 (CXCL10) were tested in serum samples after storing at -20°C or -70°C for 1, 2, 3, 7, 8, and 10 years. Levels of TBA, TBIL, and protein parameters such as ALT, CK, GGT, HDL, and HBsAg decreased significantly, but levels of potassium and cholesterol increased significantly after long-term storage, whereas blood glucose and triglycerides were stable during storage. HBV DNA remained stable at -70°C but changed at -20°C, whereas HCV RNA was stable after 1-, 2-, and 3-year storage. CXCL10 was still detectable after 8-year storage. Low temperatures (-70°C/80°C) are necessary for storage of serum samples in chronic hepatitis B research after long-term storage.

  6. ARCSTONE: Accurate Calibration of Lunar Spectral Reflectance from space

    NASA Astrophysics Data System (ADS)

    Young, C. L.; Lukashin, C.; Jackson, T.; Cooney, M.; Ryan, N.; Beverly, J.; Davis, W.; Nguyen, T.; Rutherford, G.; Swanson, R.; Kehoe, M.; Kopp, G.; Smith, P.; Woodward, J.; Carvo, J.; Stone, T.

    2017-12-01

    Calibration accuracy and consistency are key on-orbit performance metrics for Earth observing sensors. The accuracy and consistency of measurements across multiple instruments in low Earth and geostationary orbits are directly connected to the scientific understanding of complex systems, such as Earth's weather and climate. Recent studies have demonstrated the quantitative impacts of observational accuracy on the science data products [1] and the ability to detect climate change trends for essential climate variables (e.g., Earth's radiation budget, cloud feedback, and long-term trends in cloud parameters) [2, 3]. It is common for sensors to carry references for calibration at various wavelengths onboard, but these can be subject to degradation and increase mass and risk. The Moon can be considered a natural solar diffuser in space. Establishing the Moon as an on-orbit high-accuracy calibration reference enables broad intercalibration opportunities, as the lunar reflectance is time-invariant and can be directly measured by most Earth-observing instruments. Existing approaches to calibrate sensors against the Moon can achieve stabilities of a tenth of a percent over a decade, as demonstrated by the SeaWIFS. However, the current lunar calibration quality, with 5 - 10% bias, depends on the photometric model of the Moon [4]. Significant improvements in the lunar reference are possible and are necessary for climate-level absolute calibrations using the Moon. The ARCSTONE instrument will provide a reliable reference for high-accuracy on-orbit calibration for reflected solar instruments. An orbiting spectrometer flying on a CubeSat in low Earth orbit will provide lunar spectral reflectance with accuracy < 0.5% (k = 1), sufficient to establish an SI-traceable absolute lunar calibration standard for past, current, and future Earth weather and climate sensors. The ARCSTONE team will present the instrument design status and path forward for development, building, calibration and testing. [1] Lyapustin, A. Y. et al., 2014, Atmos. Meas. Tech., 7, pp. 4353 - 4365. [2] Wielicki, B. A., et al., 2013, Bull. Amer. Meteor. Soc., 94, pp. 1519 - 1539. [3] Shea, Y. L., et al., 2017 J. of Climate. [4] Kieffer, H. H., et al., 2005, The Astronomical J., v. 129, pp. 2887 - 2901.

  7. ISCCP-B1U Geostationary Satellite VIS Channel Vicarious Calibration/Validation in support of creation of long term climate data records

    NASA Astrophysics Data System (ADS)

    Gopalan, A.; Doelling, D. R.; Bhatt, R.; Haney, C.; Scarino, B. R.

    2017-12-01

    The International Satellite Cloud Climatology Project (ISCCP) provides a 40-year geostationary (GEO) imager record from satellites worldwide of 3-hourly cloud properties and surface reflectances. ISCCP B1 data archived at the National Climatic Data Center (NCDC) are a collection of measurements from imagers on international GEO meteorological satellites which are sampled to approximately 10-km and at 3-hour intervals. ISCCP coordinated the ingestion of 3-hour geostationary imager pixel level radiances and placed them in a common and consistent unified format (ISCCP-B1U) across GEO imagers and archived the datasets at NCDC for future reprocessing efforts. The GEO imagers in the B1U record lacked onboard calibration to monitor the temporal stability of the visible channel. Consistent calibration of the B1U GEO imager record opens up the potential for their use in global climate studies. The NASA CERES project released the Edition4 products, where the GEO imager calibration has been referenced to the Aqua-MODIS band-1 Collection 6 calibration. This was done by matching coincident GEO and MODIS radiance pairs to transfer the MODIS calibration. This primary method was then validated by the independent vicarious calibration methods using invariant desert and deep convective cloud (DCC) targets. In this study we extend these vicarious methods to the historical ISCCP-B1U format GEO record going back from 2000-1978 while addressing some of the challenges viz. the short historical GEO imager lifetimes, spurious imagery, non-stationary VIS channel space counts, data source processing differences, inadequate spectral response function characterization and possible wavelength dependent degradations. Another challenge, is the occasional abrupt calibration gain discontinuities in time, these are validated by tracking the brightest pixels over time. We discuss the methodology used to address some of the challenges and present results from the two independent vicarious calibration approaches that are then merged according to their respective uncertainties to obtain optimal and self-consistent calibration gain timelines for the various GEO sensors in the historical record in support of global climate change studies

  8. Comparison of continuous in-situ CO2 observations at Jungfraujoch using two different measurement techniques

    NASA Astrophysics Data System (ADS)

    Schibig, M. F.; Steinbacher, M.; Buchmann, B.; van der Laan-Luijkx, I. T.; van der Laan, S.; Ranjan, S.; Leuenberger, M. C.

    2014-07-01

    Since 2004, atmospheric carbon dioxide (CO2) is measured at the High Altitude Research Station Jungfraujoch by the division of Climate and Environmental Physics at the University of Bern (KUP) using a nondispersive infrared gas analyzer (NDIR) in combination with a paramagnetic O2 analyzer. In January 2010, CO2 measurements based on cavity ring down spectroscopy (CRDS) as part of the Swiss National Air Pollution Monitoring Network have been added by the Swiss Federal Laboratories for Materials Science and Technology (Empa). To ensure a smooth transition - a prerequisite when merging two datasets e.g. for trend determinations - the two measurement systems run in parallel for several years. Such a long-term intercomparison also allows identifying potential offsets between the two datasets and getting information about the compatibility of the two systems on different time scales. A good agreement of the seasonality as well as for the short-term variations was observed and to a lesser extent for trend calculations mainly due to the short common period. However, the comparison revealed some issues related to the stability of the calibration gases of the KUP system and their assigned CO2 mole fraction. It was possible to adapt an improved calibration strategy based on standard gas determinations, which lead to better agreement between the two data sets. By excluding periods with technical problems and bad calibration gas cylinders, the average hourly difference (CRDS - NDIR) of the two systems is -0.03 ppm ± 0.25 ppm. Although the difference of the two datasets is in line with the compatibility goal of ±0.1 ppm of the World Meteorological Organization (WMO), the standard deviation is still too high. A significant part of this uncertainty originates from the necessity to switch the KUP system frequently (every 12 min) for 6 min from ambient air to a working gas in order to correct short-term variations of the O2 measurement system. Allowing additionally for signal stabilization after switching the sample, an effective data coverage of only 1/6 for the KUP system is achieved while the Empa system has a nearly complete data coverage. Additionally, different internal volumes and flow rates between the two systems may affect observed differences.

  9. Comparison of continuous in situ CO2 observations at Jungfraujoch using two different measurement techniques

    NASA Astrophysics Data System (ADS)

    Schibig, M. F.; Steinbacher, M.; Buchmann, B.; van der Laan-Luijkx, I. T.; van der Laan, S.; Ranjan, S.; Leuenberger, M. C.

    2015-01-01

    Since 2004, atmospheric carbon dioxide (CO2) is being measured at the High Altitude Research Station Jungfraujoch by the division of Climate and Environmental Physics at the University of Bern (KUP) using a nondispersive infrared gas analyzer (NDIR) in combination with a paramagnetic O2 analyzer. In January 2010, CO2 measurements based on cavity ring-down spectroscopy (CRDS) as part of the Swiss National Air Pollution Monitoring Network were added by the Swiss Federal Laboratories for Materials Science and Technology (Empa). To ensure a smooth transition - a prerequisite when merging two data sets, e.g., for trend determinations - the two measurement systems run in parallel for several years. Such a long-term intercomparison also allows the identification of potential offsets between the two data sets and the collection of information about the compatibility of the two systems on different time scales. A good agreement of the seasonality, short-term variations and, to a lesser extent mainly due to the short common period, trend calculations is observed. However, the comparison reveals some issues related to the stability of the calibration gases of the KUP system and their assigned CO2 mole fraction. It is possible to adapt an improved calibration strategy based on standard gas determinations, which leads to better agreement between the two data sets. By excluding periods with technical problems and bad calibration gas cylinders, the average hourly difference (CRDS - NDIR) of the two systems is -0.03 ppm ± 0.25 ppm. Although the difference of the two data sets is in line with the compatibility goal of ±0.1 ppm of the World Meteorological Organization (WMO), the standard deviation is still too high. A significant part of this uncertainty originates from the necessity to switch the KUP system frequently (every 12 min) for 6 min from ambient air to a working gas in order to correct short-term variations of the O2 measurement system. Allowing additional time for signal stabilization after switching the sample, an effective data coverage of only one-sixth for the KUP system is achieved while the Empa system has a nearly complete data coverage. Additionally, different internal volumes and flow rates may affect observed differences.

  10. The Effect of a Short-Term and Long-Term Whole-Body Vibration in Healthy Men upon the Postural Stability

    PubMed Central

    Piecha, Magdalena; Juras, Grzegorz; Król, Piotr; Sobota, Grzegorz; Polak, Anna; Bacik, Bogdan

    2014-01-01

    The study aimed to establish the short-term and long-term effects of whole-body vibration on postural stability. The sample consisted of 28 male subjects randomly allocated to four comparative groups, three of which exercised on a vibration platform with parameters set individually for the groups. The stabilographic signal was recorded before the test commenced, after a single session of whole-body vibration, immediately after the last set of exercises of the 4-week whole-body vibration training, and one week after the training ended. The subjects were exposed to vibrations 3 times a week for 4 weeks. Long-term vibration training significantly shortened the rambling and trembling paths in the frontal plane. The path lengths were significantly reduced in the frontal plane one week after the training end date. Most changes in the values of the center of pressure (COP) path lengths in the sagittal and frontal plane were statistically insignificant. We concluded that long-term vibration training improves the postural stability of young healthy individuals in the frontal plane. PMID:24520362

  11. Multicore-shell nanofiber architecture of polyimide/polyvinylidene fluoride blend for thermal and long-term stability of lithium ion battery separator.

    PubMed

    Park, Sejoon; Son, Chung Woo; Lee, Sungho; Kim, Dong Young; Park, Cheolmin; Eom, Kwang Sup; Fuller, Thomas F; Joh, Han-Ik; Jo, Seong Mu

    2016-11-11

    Li-ion battery, separator, multicoreshell structure, thermal stability, long-term stability. A nanofibrous membrane with multiple cores of polyimide (PI) in the shell of polyvinylidene fluoride (PVdF) was prepared using a facile one-pot electrospinning technique with a single nozzle. Unique multicore-shell (MCS) structure of the electrospun composite fibers was obtained, which resulted from electrospinning a phase-separated polymer composite solution. Multiple PI core fibrils with high molecular orientation were well-embedded across the cross-section and contributed remarkable thermal stabilities to the MCS membrane. Thus, no outbreaks were found in its dimension and ionic resistance up to 200 and 250 °C, respectively. Moreover, the MCS membrane (at ~200 °C), as a lithium ion battery (LIB) separator, showed superior thermal and electrochemical stabilities compared with a widely used commercial separator (~120 °C). The average capacity decay rate of LIB for 500 cycles was calculated to be approximately 0.030 mAh/g/cycle. This value demonstrated exceptional long-term stability compared with commercial LIBs and with two other types (single core-shell and co-electrospun separators incorporating with functionalized TiO 2 ) of PI/PVdF composite separators. The proper architecture and synergy effects of multiple PI nanofibrils as a thermally stable polymer in the PVdF shell as electrolyte compatible polymers are responsible for the superior thermal performance and long-term stability of the LIB.

  12. Multicore-shell nanofiber architecture of polyimide/polyvinylidene fluoride blend for thermal and long-term stability of lithium ion battery separator

    PubMed Central

    Park, Sejoon; Son, Chung Woo; Lee, Sungho; Kim, Dong Young; Park, Cheolmin; Eom, Kwang Sup; Fuller, Thomas F.; Joh, Han-Ik; Jo, Seong Mu

    2016-01-01

    Li-ion battery, separator, multicoreshell structure, thermal stability, long-term stability. A nanofibrous membrane with multiple cores of polyimide (PI) in the shell of polyvinylidene fluoride (PVdF) was prepared using a facile one-pot electrospinning technique with a single nozzle. Unique multicore-shell (MCS) structure of the electrospun composite fibers was obtained, which resulted from electrospinning a phase-separated polymer composite solution. Multiple PI core fibrils with high molecular orientation were well-embedded across the cross-section and contributed remarkable thermal stabilities to the MCS membrane. Thus, no outbreaks were found in its dimension and ionic resistance up to 200 and 250 °C, respectively. Moreover, the MCS membrane (at ~200 °C), as a lithium ion battery (LIB) separator, showed superior thermal and electrochemical stabilities compared with a widely used commercial separator (~120 °C). The average capacity decay rate of LIB for 500 cycles was calculated to be approximately 0.030 mAh/g/cycle. This value demonstrated exceptional long-term stability compared with commercial LIBs and with two other types (single core-shell and co-electrospun separators incorporating with functionalized TiO2) of PI/PVdF composite separators. The proper architecture and synergy effects of multiple PI nanofibrils as a thermally stable polymer in the PVdF shell as electrolyte compatible polymers are responsible for the superior thermal performance and long-term stability of the LIB. PMID:27833132

  13. Characterization of the Exradin W1 scintillator for use in radiotherapy.

    PubMed

    Carrasco, P; Jornet, N; Jordi, O; Lizondo, M; Latorre-Musoll, A; Eudaldo, T; Ruiz, A; Ribas, M

    2015-01-01

    To evaluate the main characteristics of the Exradin W1 scintillator as a dosimeter and to estimate measurement uncertainties when used in radiotherapy. We studied the calibration procedure, energy and modality dependence, short-term repeatability, dose-response linearity, angular dependence, temperature dependence, time to reach thermal equilibrium, dose-rate dependence, water-equivalent depth of the effective measurement point, and long-term stability. An uncertainty budget was derived for relative and absolute dose measurements in photon and electron beams. Exradin W1 showed a temperature dependence of -0.225% °C(-1). The loss of sensitivity with accumulated dose decreased with use. The sensitivity of Exradin W1 was energy independent for high-energy photon and electron beams. All remaining dependencies of Exradin W1 were around or below 0.5%, leading to an uncertainty budget of about 1%. When a dual channel electrometer with automatic trigger was not used, timing effects became significant, increasing uncertainties by one order of magnitude. The Exradin W1 response is energy independent for high energy x-rays and electron beams, and only one calibration coefficient is needed. A temperature correction factor should be applied to keep uncertainties around 2% for absolute dose measurements and around 1% for relative measurements in high-energy photon and electron beams. The Exradin W1 scintillator is an excellent alternative to detectors such as diodes for relative dose measurements.

  14. Response of hydrology to climate change in the southern Appalachian mountains using Bayesian inference

    Treesearch

    Wei Wu; James S. Clark; James M. Vose

    2012-01-01

    Predicting long-term consequences of climate change on hydrologic processes has been limited due to the needs to accommodate the uncertainties in hydrological measurements for calibration, and to account for the uncertainties in the models that would ingest those calibrations and uncertainties in climate predictions as basis for hydrological predictions. We implemented...

  15. Long Term Stability of Learning Outcomes in Undergraduates after an Open-Inquiry Instruction on Thermal Science

    ERIC Educational Resources Information Center

    Adorno, Dominique Persano; Pizzolato, Nicola; Fazio, Claudio

    2018-01-01

    This paper investigates the efficacy of an open-inquiry approach to achieve a long term stability of physics instruction. This study represents the natural continuation of a research project started four years ago when a sample of thirty engineering undergraduates, having already attended traditional university physics instruction, were involved…

  16. Development of side-chain NLO polymer materials with high electro-optic activity and long-term stability

    NASA Astrophysics Data System (ADS)

    Huang, Diyun; Parker, Timothy; Guan, Hann Wen; Cong, Shuxin; Jin, Danliang; Dinu, Raluca; Chen, Baoquan; Tolstedt, Don; Wolf, Nick; Condon, Stephen

    2005-01-01

    The electro-optic coefficient and long-term dipole alignment stability are two major factors in the development of high performance NLO materials for the application of high-speed EO devices. We have developed a high performance non-linear organic chromophore and incorporated it into a crosslinkable side-chain polyimide system. The polymer was synthesized through stepwise grafting of the crosslinker followed by the chromophore onto the polyimide backbone via esterification. Different chromophore loading levels were achieved by adjusting the crosslinker/chromophore feeding ratio. The polyimides films were contact-poled with second-harmonic generation monitoring. A large EO coefficient value was obtained and good long-term thermal stability at 85°C was observed.

  17. Short- and long-term responses of total soil organic carbon to harvesting in a northern hardwood forest

    Treesearch

    Kristofer Johnson; Frederick N. Scatena; Yude Pan

    2010-01-01

    The long-term response of total soil organic carbon pools ('total SOC', i.e. soil and dead wood) to different harvesting scenarios in even-aged northern hardwood forest stands was evaluated using two soil carbon models, CENTURY and YASSO, that were calibrated with forest plot empirical data in the Green Mountains of Vermont. Overall, 13 different harvesting...

  18. Long-term stability of FeSO4 and H2SO4 treated chromite ore processing residue (COPR): Importance of H+ and SO42.

    PubMed

    Wang, Xin; Zhang, Jingdong; Wang, Linling; Chen, Jing; Hou, Huijie; Yang, Jiakuan; Lu, Xiaohua

    2017-01-05

    In this study, the long-term stability of Cr(VI) in the FeSO 4 and H 2 SO 4 (FeSO 4 -H 2 SO 4 ) treated chromite ore processing residue (COPR) after 400 curing days and the stabilization mechanisms were investigated. FeSO 4 -H 2 SO 4 treatment significantly reduced toxicity characteristic leaching procedure (TCLP) and synthetic precipitation leaching procedure (SPLP) Cr(VI) concentrations to lower than the regulatory limit of 1.5mgL -1 (HJ/T 301-2007, China EPA) even for the samples curing 400days, achieving an outstanding long-term stability. Our independent leaching tests revealed that H + and SO 4 2- have synergistic effect on promoting the release of Cr(VI), which would make Cr(VI) easier accessed by Fe(II) during stabilization. The contributions of H + and SO 4 2- to Cr(VI) release ratio were 25%-44% and 19%-38%, respectively, as 5mol H 2 SO 4 per kg COPR was used. X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and alkaline digestion analyses were also employed to interpret the possible stabilization mechanism. Cr(VI) released from COPR solid was reduced to Cr(III) by Fe(II), and then formed stable Fe x Cr (1-x) (OH) 3 precipitate. This study provides a facile and reliable scheme for COPR stabilization, and verifies the excellent long-term stability of the FeSO 4 -H 2 SO 4 treated COPR. Copyright © 2016 Elsevier B.V. All rights reserved.

  19. Aquarius L-Band Radiometers Calibration Using Cold Sky Observations

    NASA Technical Reports Server (NTRS)

    Dinnat, Emmanuel P.; Le Vine, David M.; Piepmeier, Jeffrey R.; Brown, Shannon T.; Hong, Liang

    2015-01-01

    An important element in the calibration plan for the Aquarius radiometers is to look at the cold sky. This involves rotating the satellite 180 degrees from its nominal Earth viewing configuration to point the main beams at the celestial sky. At L-band, the cold sky provides a stable, well-characterized scene to be used as a calibration reference. This paper describes the cold sky calibration for Aquarius and how it is used as part of the absolute calibration. Cold sky observations helped establish the radiometer bias, by correcting for an error in the spillover lobe of the antenna pattern, and monitor the long-term radiometer drift.

  20. Characterization and calibration of piezoelectric polymers: In situ measurements of body vibrations

    NASA Astrophysics Data System (ADS)

    Kappel, Marcel; Abel, Markus; Gerhard, Reimund

    2011-07-01

    Piezoelectric polymers are known for their flexibility in applications, mainly due to their bending ability, robustness, and variable sensor geometry. It is an optimal material for minimal-invasive investigations in vibrational systems, e.g., for wood, where acoustical impedance matches particularly well. Many applications may be imagined, e.g., monitoring of buildings, vehicles, machinery, alarm systems, such that our investigations may have a large impact on technology. Longitudinal piezoelectricity converts mechanical vibrations normal to the polymer-film plane into an electrical signal, and the respective piezoelectric coefficient needs to be carefully determined in dependence on the relevant material parameters. In order to evaluate efficiency and durability for piezopolymers, we use polyvinylidene fluoride and measure the piezoelectric coefficient with respect to static pressure, amplitude of the dynamically applied force, and long-term stability. A known problem is the slow relaxation of the material towards equilibrium, if the external pressure changes; here, we demonstrate how to counter this problem with careful calibration. Since our focus is on acoustical measurements, we determine accurately the frequency response curve - for acoustics probably the most important characteristic. Eventually, we show that our piezopolymer transducers can be used as a calibrated acoustical sensors for body vibration measurements on a wooden musical instrument, where it is important to perform minimal-invasive measurements. A comparison with the simultaneously recorded airborne sound yields important insight of the mechanism of sound radiation in comparison with the sound propagating in the material. This is especially important for transient signals, where not only the long-living eigenmodes contribute to the sound radiation. Our analyses support that piezopolymer sensors can be employed as a general tool for the determination of the internal dynamics of vibrating systems.

  1. MODIS Instrument Operation and Calibration Improvements

    NASA Technical Reports Server (NTRS)

    Xiong, X.; Angal, A.; Madhavan, S.; Link, D.; Geng, X.; Wenny, B.; Wu, A.; Chen, H.; Salomonson, V.

    2014-01-01

    Terra and Aqua MODIS have successfully operated for over 14 and 12 years since their respective launches in 1999 and 2002. The MODIS on-orbit calibration is performed using a set of on-board calibrators, which include a solar diffuser for calibrating the reflective solar bands (RSB) and a blackbody for the thermal emissive bands (TEB). On-orbit changes in the sensor responses as well as key performance parameters are monitored using the measurements of these on-board calibrators. This paper provides an overview of MODIS on-orbit operation and calibration activities, and instrument long-term performance. It presents a brief summary of the calibration enhancements made in the latest MODIS data collection 6 (C6). Future improvements in the MODIS calibration and their potential applications to the S-NPP VIIRS are also discussed.

  2. Modeling Suomi-NPP VIIRS Solar Diffuser Degradation due to Space Radiation

    NASA Astrophysics Data System (ADS)

    Shao, X.; Cao, C.

    2014-12-01

    The Visible Infrared Imaging Radiometer Suite (VIIRS) onboard Suomi-NPP uses a solar diffuser (SD) as on-board radiometric calibrator for the reflective solar band (RSB) calibration. Solar diffuser is made of Spectralon (one type of fluoropolymer) and was chosen because of its controlled reflectance in the VIS-NIR-SWIR region and its near-Lambertian reflectance profile. Spectralon is known to degrade in reflectance at the blue end of the spectrum due to exposure to space radiations such as solar UV radiation and energetic protons. These space radiations can modify the Spectralon surface through breaking C-C and C-F bonds and scissioning or cross linking the polymer, which causes the surface roughness and degrades its reflectance. VIIRS uses a SDSM (Solar Diffuser Stability Monitor) to monitor the change in the Solar Diffuser reflectance in the 0.4 - 0.94 um wavelength range and provide a correction to the calibration constants. The H factor derived from SDSM reveals that reflectance of 0.4 to 0.6um channels of VIIRS degrades faster than the reflectance of longer wavelength RSB channels. A model is developed to derive characteristic parameters such as mean SD surface roughness height and autocovariance length of SD surface roughness from the long term spectral degradation of SD reflectance as monitored by SDSM. These two parameters are trended to assess development of surface roughness of the SD over the operation period of VIIRS.

  3. Radiometric characterization of type-II InAs/GaSb superlattice (t2sl) midwave infrared photodetectors and focal plane arrays

    NASA Astrophysics Data System (ADS)

    Nghiem, Jean; Giard, E.; Delmas, M.; Rodriguez, J. B.; Christol, P.; Caes, M.; Martijn, H.; Costard, E.; Ribet-Mohamed, I.

    2017-09-01

    In recent years, Type-II InAs/GaSb superlattice (T2SL) has emerged as a new material technology suitable for high performance infrared (IR) detectors operating from Near InfraRed (NIR, 2-3μm) to Very Long Wavelength InfraRed (LWIR, λ > 15μm) wavelength domains. To compare their performances with well-established IR technologies such as MCT, InSb or QWIP cooled detectors, specific electrical and radiometric characterizations are needed: dark current, spectral response, quantum efficiency, temporal and spatial noises, stability… In this paper, we first present quantum efficiency measurements performed on T2SL MWIR (3-5μm) photodiodes and on one focal plane array (320x256 pixels with 30μm pitch, realized in the scope of a french collaboration ). Different T2SL structures (InAs-rich versus GaSb-rich) with the same cutoff wavelength (λc= 5μm at 80K) were studied. Results are analysed in term of carrier diffusion length in order to define the optimum thickness and type of doping of the absorbing zone. We then focus on the stability over time of a commercial T2SL FPA (320x256 pixels with 30μm pitch), measuring the commonly used residual fixed pattern noise (RFPN) figure of merit. Results are excellent, with a very stable behaviour over more than 3 weeks, and less than 10 flickering pixels, possibly giving access to long-term stability of IR absolute calibration.

  4. Fiber-optic microsensor for high resolution pCO2 sensing in marine environment.

    PubMed

    Neurauter, G; Klimant, I; Wolfbeis, O S

    2000-03-01

    A fast responding fiber-optic microsensor for sensing pCO2 in marine sediments with high spatial resolution is presented. The tip diameter varies typically between 20 and 50 microm. In order to make the pH-indicator 8-hydroxypyrene-1,3,6-trisulfonate soluble in the ethyl cellulose matrix, it was lipophilized with tetraoctylammonium as the counterion [HPTS-(TOA)4]. The microsensor was tuned to sense very low levels of dissolved carbon dioxide which are typically present in marine systems. The detection limit is 0.04 hPa pCO2 which corresponds to 60 ppb CO2 of dissolved carbon dioxide. A soluble Teflon derivative with an extraordinarily high gas permeability was chosen as a protective coating to eliminate interferences by ionic species like chloride or pH. Response times of less than 1 min were observed. The performance of the new microsensor is described with respect to reproducibility of the calibration curves, dynamic range, temperature behavior, long term stability and storage stability. The effect of hydrogen sulfide as an interferent, which is frequently present in anaerobic sediment layers, was studied in detail.

  5. Thermocouple Calibration and Accuracy in a Materials Testing Laboratory

    NASA Technical Reports Server (NTRS)

    Lerch, B. A.; Nathal, M. V.; Keller, D. J.

    2002-01-01

    A consolidation of information has been provided that can be used to define procedures for enhancing and maintaining accuracy in temperature measurements in materials testing laboratories. These studies were restricted to type R and K thermocouples (TCs) tested in air. Thermocouple accuracies, as influenced by calibration methods, thermocouple stability, and manufacturer's tolerances were all quantified in terms of statistical confidence intervals. By calibrating specific TCs the benefits in accuracy can be as great as 6 C or 5X better compared to relying on manufacturer's tolerances. The results emphasize strict reliance on the defined testing protocol and on the need to establish recalibration frequencies in order to maintain these levels of accuracy.

  6. Precise and long-term stabilization of the carrier-envelope phase of femtosecond laser pulses using an enhanced direct locking technique.

    PubMed

    Yu, Tae Jun; Hong, Kyung-Han; Choi, Hyun-Gyug; Sung, Jae Hee; Choi, Il Woo; Ko, Do-Kyeong; Lee, Jongmin; Kim, Junwon; Kim, Dong Eon; Nam, Chang Hee

    2007-06-25

    We demonstrate a long-term operation with reduced phase noise in the carrier-envelope-phase (CEP) stabilization process by employing a double feedback loop and an improved signal detection in the direct locking technique [Opt. Express 13, 2969 (2005)]. A homodyne balanced detection method is employed for efficiently suppressing the dc noise in the f-2f beat signal, which is converted into the CEP noise in the direct locking loop working at around zero carrier-envelope offset frequency (f(ceo)). In order to enhance the long-term stability, we have used the double feedback scheme that modulates both the oscillator pump power for a fast control and the intracavity-prism insertion depth for a slow and high-dynamic-range control. As a result, the in-loop phase jitter is reduced from 50 mrad of the previous result to 29 mrad, corresponding to 13 as in time scale, and the long-term stable operation is achieved for more than 12 hours.

  7. Paper Microzone Plates as Analytical Tools for Studying Enzyme Stability: A Case Study on the Stabilization of Horseradish Peroxidase Using Trehalose and SU-8 Epoxy Novolac Resin.

    PubMed

    Ganaja, Kirsten A; Chaplan, Cory A; Zhang, Jingyi; Martinez, Nathaniel W; Martinez, Andres W

    2017-05-16

    Paper microzone plates in combination with a noncontact liquid handling robot were demonstrated as tools for studying the stability of enzymes stored on paper. The effect of trehalose and SU-8 epoxy novolac resin (SU-8) on the stability of horseradish peroxidase (HRP) was studied in both a short-term experiment, where the activity of various concentrations of HRP dried on paper were measured after 1 h, and a long-term experiment, where the activity of a single concentration of HRP dried and stored on paper was monitored for 61 days. SU-8 was found to stabilize HRP up to 35 times more than trehalose in the short-term experiment for comparable concentrations of the two reagents, and a 1% SU-8 solution was found to stabilize HRP approximately 2 times more than a 34% trehalose solution in both short- and long-term experiments. The results suggest that SU-8 is a promising candidate for use as an enzyme-stabilizing reagent for paper-based diagnostic devices and that the short-term experiment could be used to quickly evaluate the capacity of various reagents for stabilizing enzymes to identify and characterize new enzyme-stabilizing reagents.

  8. In-Flight Performance of the Ozone Monitoring Instrument

    NASA Technical Reports Server (NTRS)

    Schenkeveld, V.M. Erik; Jaross, Glen; Marchenko, Sergey; Haffner, David; Kleipool, Quintus L.; Rozemeijer, Nico C.; Veefkind, J. Pepijn; Levelt, Pieternel F.

    2017-01-01

    The Dutch-Finnish Ozone Monitoring Instrument (OMI) is an imaging spectrograph flying on NASA's EOS Aura satellite since 15 July 2004. OMI is primarily used to map trace-gas concentrations in the Earth's atmosphere, obtaining mid-resolution (0.4-0.6 nm) ultraviolet-visible (UV- VIS; 264-504 nm) spectra at multiple (30-60) simultaneous fields of view. Assessed via various approaches that include monitoring of radiances from selected ocean, land ice and cloud areas, as well as measurements of line profiles in the solar spectra, the instrument shows low optical degradation and high wavelength stability over the mission lifetime. In the regions relatively free from the slowly unraveling "row anomaly" (RA) the OMI irradiances have degraded by 3- 8 %, while radiances have changed by 1-2 %. The long-term wavelength calibration of the instrument remains stable to 0.005-0.020 nm.

  9. Frequency stability of maser oscillators operated with cavity Q. [hydrogen and rubidium masers

    NASA Technical Reports Server (NTRS)

    Tetu, M.; Tremblay, P.; Lesage, P.; Petit, P.; Audoin, C.

    1982-01-01

    The short term frequency stability of masers equipped with an external feedback loop to increase the cavity quality factor was studied. The frequency stability of a hydrogen and a rubidium maser were measured and compared with theoretical evaluation. It is shown that the frequency stability passes through an optimum when the cavity Q is varied. Long term fluctuations are discussed and the optimum mid term frequency stability achievably by small size active and passive H-masers is considered.

  10. Long-term effect of lime-fly ash treated soils.

    DOT National Transportation Integrated Search

    2003-12-01

    In October of 2000 MDOT initiated State Study No. 147, entitled "Long-Term Effect of Lime-Fly Ash Treated Soils." The purpose of this study : was to evaluate the long-term performance of LFA stabilized soil as a base course material. Part of the impe...

  11. Clinical characteristics and long-term response to mood stabilizers in patients with bipolar disorder and different age at onset

    PubMed Central

    Dell’Osso, Bernardo; Buoli, Massimiliano; Riundi, Riccardo; D’Urso, Nazario; Pozzoli, Sara; Bassetti, Roberta; Mundo, Emanuela; Altamura, A Carlo

    2009-01-01

    Introduction Bipolar disorder (BD) is a prevalent, comorbid, and impairing condition. Potential predictors of response to pharmacological treatment are object of continuous investigation in patients with BD. The present naturalistic study was aimed to assess clinical features and long-term response to mood stabilizers in a sample of bipolar subjects with different ages at onset. Methods The study sample included 108 euthymic patients, diagnosed as affected by BD, either type I or II, according to the DSM-IV-TR, who were started on mood stabilizer treatment. Patients were followed-up for 24 months and the occurrence of any mood episode collected. At the end of the follow-up, patients were divided in 3 subgroups according to the age at onset (early-onset ≤30 years, middle-onset >30–≤45 years, and late-onset >45 years, respectively) and the long-term response to mood stabilizers was compared between them along with other clinical features. Results The three subgroups showed significant differences in terms of clinical and demographic features and, with respect to long-term response to mood stabilizers, the early-onset subgroup showed a better outcome in terms of reduction of major depressive episodes during the 24-month follow-up compared to the other subgroups (one way ANOVA, F = 3.57, p = 0.032). Conclusions Even though further controlled studies are needed to clarify the relationship between age at onset and outcome in BD, the present follow-up study suggests clinical peculiarities and different patterns of response to mood stabilizers across distinct subgroups of patients with BD and different ages at onset. PMID:19649214

  12. Long Term Analysis of Deformations in Salt Mines: Kłodawa Salt Mine Case Study, Central Poland

    NASA Astrophysics Data System (ADS)

    Cała, Marek; Tajduś, Antoni; Andrusikiewicz, Wacław; Kowalski, Michał; Kolano, Malwina; Stopkowicz, Agnieszka; Cyran, Katarzyna; Jakóbczyk, Joanna

    2017-09-01

    Located in central Poland, the Kłodawa salt dome is 26 km long and about 2 km wide. Exploitation of the dome started in 1956, currently rock salt extraction is carried out in 7 mining fields and the 12 mining levels at the depth from 322 to 625 meters below sea level (m.b.s.l.). It is planned to maintain the mining activity till 2052 and extend rock salt extraction to deeper levels. The dome is characterised by complex geological structure resulted from halokinetic and tectonic processes. Projection of the 3D numerical analysis took into account the following factors: mine working distribution within the Kłodawa mine (about 1000 rooms, 350 km of galleries), complex geological structure of the salt dome, complicated structure and geometry of mine workings and distinction in rocks mechanical properties e.g. rock salt and anhydrite. Analysis of past mine workings deformation and prediction of future rock mass behaviour was divided into four stages: building of the 3D model (state of mine workings in year 2014), model extension of the future mine workings planned for extraction in years 2015-2052, the 3D model calibration and stability analysis of all mine workings. The 3D numerical model of Kłodawa salt mine included extracted and planned mine workings in 7 mining fields and 14 mining levels (about 2000 mine workings). The dimensions of the model were 4200 m × 4700 m × 1200 m what was simulated by 33 million elements. The 3D model was calibrated on the grounds of convergence measurements and laboratory tests. Stability assessment of mine workings was based on analysis of the strength/stress ratio and vertical stress. The strength/stress ratio analysis enabled to indicate endangered area in mine workings and can be defined as the factor of safety. Mine workings in state close to collapse are indicated by the strength/stress ratio equals 1. Analysis of the vertical stress in mine workings produced the estimation of current state of stress in comparison to initial (pre-mining) conditions. The long-term deformation analysis of the Kłodawa salt mine for year 2014 revealed that stability conditions were fulfilled. Local disturbances indicated in the numerical analysis were connected with high chambers included in the mining field no 1 and complex geological structure in the vicinity of mine workings located in the mining fields no 2 and 3. Moreover, numerical simulations that projected the future extraction progress (till year 2052) showed positive performance. Local weakness zones in the mining field no 7 are associated with occurrence of carnallite layers and intensive mining which are planned in the mining field no 6 at the end of rock salt extraction.

  13. LONG TERM STABILITY STUDY AT FNAL AND SLAC USING BINP DEVELOPED HYDROSTATIC LEVEL SYSTEM

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Seryi, Andrei

    2003-05-28

    Long term ground stability is essential for achieving the performance goals of the Next Linear Collider. To characterize ground motion on relevant time scales, measurements have been performed at three geologically different locations using a hydrostatic level system developed specifically for these studies. Comparative results from the different sites are presented in this paper.

  14. Long-term Stability of a Camouflage Retreatment of an Asymmetric Class III/Posterior Open Bite Using Sliding Jigs.

    PubMed

    Oliveira, Dauro Douglas; de Oliveira, Bruno Franco; Figueiredo, Daniel Santos Fonseca; Antunes, Alberto Nogueira da Gama; Seraidarian, Paulo Isaías

    2017-10-01

    This article reports the camouflage retreatment of an adult patient presenting an asymmetric Class III malocclusion and posterior open bite. Sliding jigs (SJs) associated with intermaxillary elastics were used. The long-term stability of the excellent results suggests that the use of SJs to correct asymmetric posterior occlusions may be effective.

  15. Climate observing system studies: An element of the NASA Climate Research Program: Workshop report

    NASA Technical Reports Server (NTRS)

    1980-01-01

    Plans for NASA's efforts in climatology were discussed. Targets for a comprehensive observing system for the early 1990's were considered. A program to provide useful data in the near and mid-term, and a program to provide for a feasibility assessment of instruments and methods for the development of a long-term system were discussed. Climate parameters that cannot be measured from space were identified. Long-term calibration, intercomparison, standards, and ground truth were discussed.

  16. ISFET sensor evaluation and modification for seawater pH measurement

    NASA Astrophysics Data System (ADS)

    Martz, T. R.; Johnson, K. S.; Jannasch, H.; Coletti, L.; Barry, J.; Lovera, C.

    2008-12-01

    In the future, short-term cycles (daily to subannual) and long-term trends (annual and greater) in the carbonate system will be observed by autonomous sensors operating from a variety of platforms (e.g., moorings, profiling floats, AUVs, etc.). Of the four carbonate parameters, pH measurement has the longest history of development - yet robust autonomous sensing techniques remain elusive due to a catalog of technical challenges. Existing commercial sensor technologies generally do not meet the stringent demands of accuracy, long-term stability, low power, pressure tolerance, resistance to biofouling, and ease of use required by the oceanographic community. We report here on some recent advances in Ion Sensitive Field Effect Transistor (ISFET) technology that may open the door for more widespread autonomous seawater pH measurements. Much of our work has focused on applications of the Honeywell Durafet pH sensor, a product designed for industrial process control. Initial results from laboratory testing and deployments in the MBARI test tank and near shore moorings will be presented. Sensor calibration techniques will be addressed. Applications of now-available off-the-shelf sensors including shipboard underway measurement, shallow water mooring deployment, and a gas controlled seawater aquarium for pH perturbation experiments will be discussed. We hope that an ongoing collaboration between MBARI and Honeywell will result in a commercially available product, designed specifically for oceanographic applications, within the next several years.

  17. Simultaneous transfer of optical frequency and time over 306 km long-haul optical fibre link

    NASA Astrophysics Data System (ADS)

    Hucl, Vaclav; Cizek, Martin; Pravdova, Lenka; Rerucha, Simon; Hrabina, Jan; Mikel, Bretislav; Smotlacha, Vladimir; Vojtech, Josef; Lazar, Josef; Cip, Ondrej

    2016-12-01

    Optical fibre links for distributing optical frequencies and time stamps were researched and experimentally tested in the past fifteen years. They have been used mainly for stability comparison of experimental optical clocks. But recent development puts demands on a technology transfer from laboratory experiments to the real industry. The remote calibration of interrogators of Fibre Bragg Grating strain sensory networks is one of important examples. The first step of the adoption the time and frequency broadcasting should be the drop-out free long-term operation of this technology between research laboratories connected via long-haul fibre links. We present a 306 km long-haul optical fibre link between the cities of Prague and Brno in the Czech Republic where a coherent transfer of stable optical frequency and a stable time signal has been firstly demonstrated. The link between ISI CAS Brno and CESNET Prague uses an internet communication fibre where a window of 1540-1546 nm is dedicated for the coherent transfer and 1PPS signal. The link is equipped with 6 bidirectional EDFA amplifiers. The optical frequency standard based on the highly-coherent laser Koheras Adjustik working at 1540.5 nm and stabilized with a saturation absorption spectroscopy technique was used for the coherent wave transfer. The suppression of the Doppler shift induced by the optical fibre was based on an accoustooptical modulator with a servo-loop including a fast PID controller processing the beat-note frequency given by mixing of the Adjustik laser (Brno) and the reflected frequency of this laser from the far end of 306 km long-haul fibre link (Prague). We verified the Doppler shift suppression for the coherent wave with a measuring method analysing the transport delay of the 1PPS signal.

  18. Application of long-term simulation programs for analysis of system islanding

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sancha, J.L.; Llorens, M.L.; Moreno, J.M.

    1997-02-01

    This paper describes the main results and conclusions from the application of two different long-term stability programs to the analysis of a system islanding scenario for a study case developed by Red Electrica de Espana (REE), based on the Spanish system. Two main goals were to evaluate the performance of both the influence of some important control and protection elements (tie-line loss-of-synchronism relays, underfrequency load-shedding, load-frequency control, and power plant dynamics). Conclusions about modeling and computational requirements for system islanding (frequency) scenarios and use of long-term stability programs are presented.

  19. Integrating river incision rates over timescales in the Ecuadorian Andes: from uplift history to current erosion rates

    NASA Astrophysics Data System (ADS)

    Campforts, Benjamin; Govers, Gerard; Vanacker, Veerle; Tenorio, Gustavo

    2013-04-01

    River profile development is studied at different timescales, from the response to uplift over millions of years over steady state erosion rates over millennia to the response to a single event, such as a major landslide. At present, few attempts have been made to compare data obtained over various timescales. Therefore we do not know to what extent data and model results are compatible: do long-term river profile development models yield erosion rates that are compatible with information obtained over shorter time spans, both in terms of absolute rates and spatial patterns or not? Such comparisons could provide crucial insights into the nature of river development and allow us to assess the confidence we may have when predicting river response at different timescales (e.g. Kirchner et al., 2001). A major issue hampering such comparison is the uncertainty involved in the calibration of long-term river profile development models. Furthermore, calibration data on different timescales are rarely available for a specific region. In this research, we set up a river profile development model similar to the one used by Roberts & White (2010) and successfully calibrated it for the northern Ecuadorian Andes using detailed uplift and sedimentological data. Subsequently we used the calibrated model to simulate river profile development in the southern Ecuadorian Andes. The calibrated model allows to reconstruct the Andean uplift history in southern Ecuador, which is characterized by a very strong uplift phase during the last 5 My. Erosion rates derived from the modeled river incision rates were then compared with 10Be derived basin-wide erosion rates for a series of basins within the study area. We found that the model-inferred erosion rates for the last millennia are broadly compatible with the cosmogenic derived denudation rates, both in terms of absolute erosion rates as well as in terms of their spatial distribution. Hence, a relatively simple river profile development model captures the essential controls on long-term landscape development in the studied landscapes. Kirchner, J., Finkel, R., and Riebe, C., 2001, Mountain erosion over 10 yr, 10 ky, and 10 my time scales: Geology, v. 29, no. 7, p. 591-594. Roberts, G., and White, N., 2010, Estimating uplift rate histories from river profiles using African examples: Journal of Geophysical Research, v. 115, p. 1-24.

  20. Long Term Stability and Relapse Following Mandibular Advancement and Mandibular Setback Surgeries: A Cephalometric Study

    PubMed Central

    Darshan, S Vinay; Ronad, Yusuf Ahammed; Kishore, M S V; Shetty, K Sadashiva; Rajesh, M; Suman, S D

    2014-01-01

    Background: The aim was to evaluate the long-term hard and soft tissue changes following mandibular advancement and setback surgeries. Materials and Methods: A total of 16 subjects each were selected who underwent bilateral sagittal split osteotomy mandibular advancement and mandibular setback groups. Pre-surgical (T1), immediate post-surgical (T2) and long-term post-surgical (T3) cephalograms were compared for hard and soft tissue changes. After cephalometric measurements, the quantity of changes between T1-T2 and T1-T3 were determined for each patient. The mean difference between T1-T2 and T1-T3 was compared with assess the long-term changes and stability. Results: In mandibular advancement the mean difference between immediate post-surgical and long term post-surgical is 7%, which accounts for a relapse of 7%. In mandibular setback, the mean difference between immediate post-surgical and long-term post-surgical is 29%, which accounts for a relapse of 29%. Conclusion: Mandibular advancement remained stable over the long period when compared to mandibular setback. PMID:25395792

  1. Long term stability and relapse following mandibular advancement and mandibular setback surgeries: a cephalometric study.

    PubMed

    Darshan, S Vinay; Ronad, Yusuf Ahammed; Kishore, M S V; Shetty, K Sadashiva; Rajesh, M; Suman, S D

    2014-09-01

    The aim was to evaluate the long-term hard and soft tissue changes following mandibular advancement and setback surgeries. A total of 16 subjects each were selected who underwent bilateral sagittal split osteotomy mandibular advancement and mandibular setback groups. Pre-surgical (T1), immediate post-surgical (T2) and long-term post-surgical (T3) cephalograms were compared for hard and soft tissue changes. After cephalometric measurements, the quantity of changes between T1-T2 and T1-T3 were determined for each patient. The mean difference between T1-T2 and T1-T3 was compared with assess the long-term changes and stability. In mandibular advancement the mean difference between immediate post-surgical and long term post-surgical is 7%, which accounts for a relapse of 7%. In mandibular setback, the mean difference between immediate post-surgical and long-term post-surgical is 29%, which accounts for a relapse of 29%. Mandibular advancement remained stable over the long period when compared to mandibular setback.

  2. Accuracy metrics for judging time scale algorithms

    NASA Technical Reports Server (NTRS)

    Douglas, R. J.; Boulanger, J.-S.; Jacques, C.

    1994-01-01

    Time scales have been constructed in different ways to meet the many demands placed upon them for time accuracy, frequency accuracy, long-term stability, and robustness. Usually, no single time scale is optimum for all purposes. In the context of the impending availability of high-accuracy intermittently-operated cesium fountains, we reconsider the question of evaluating the accuracy of time scales which use an algorithm to span interruptions of the primary standard. We consider a broad class of calibration algorithms that can be evaluated and compared quantitatively for their accuracy in the presence of frequency drift and a full noise model (a mixture of white PM, flicker PM, white FM, flicker FM, and random walk FM noise). We present the analytic techniques for computing the standard uncertainty for the full noise model and this class of calibration algorithms. The simplest algorithm is evaluated to find the average-frequency uncertainty arising from the noise of the cesium fountain's local oscillator and from the noise of a hydrogen maser transfer-standard. This algorithm and known noise sources are shown to permit interlaboratory frequency transfer with a standard uncertainty of less than 10(exp -15) for periods of 30-100 days.

  3. Automated test-site radiometer for vicarious calibration

    NASA Astrophysics Data System (ADS)

    Li, Xin; Yin, Ya-peng; Liu, En-chao; Zhang, Yan-na; Xun, Li-na; Wei, Wei; Zhang, Zhi-peng; Qiu, Gang-gang; Zhang, Quan; Zheng, Xiao-bing

    2014-11-01

    In order to realize unmanned vicarious calibration, Automated Test-site Radiometer (ATR) was developed for surface reflectance measurements. ATR samples the spectrum from 400nm-1600 nm with 8 interference filters coupled with silicon and InGaAs detectors. The field of view each channel is 10 ° with parallel optical axis. One SWIR channel lies in the center and the other seven VNIR channels are on the circle of 4.8cm diameters which guarantee each channel to view nearly the same section of ground. The optical head as a whole is temperature controlled utilizing a TE cooler for greater stability and lower noise. ATR is powered by a solar panel and transmit its data through a BDS (China's BeiDou Navigation Satellite System) terminator for long-term measurements without personnel in site. ATR deployed in Dunhuang test site with ground field about 30-cm-diameter area for multi-spectral reflectance measurements. Other instruments at the site include a Cimel sunphotometer and a diffuser-to-globe irradiance meter for atmosphere observations. The methodology for band-averaged reflectance retrieval and hyperspectral reflectance fitting process are described. Then the hyperspectral reflectance and atmospheric parameters are put into 6s code to predict TOA radiance which compare with MODIS radiance.

  4. A New Approach for Spectroradiometric Calibration Consistency on the Ground and in Space

    NASA Technical Reports Server (NTRS)

    Heath, Donald F.; Geprgoev. Geprgo

    2013-01-01

    A Space-based Calibration Transfer Spectroradiometer (SCATS) is combined with a ground calibration spectral albedo radiometric standard which consists of an opaque quartz glass Mie scattering diffuser (MSD) which has very good Lambertian scattering properties in both reflectance and transmittance modes. This system provides the capability for determining long term changes in the spectral albedo calibrations which operate in the solar reflective wavelength region. The spectral albedo calibration would be traceable to the SIRCUS and STARR NIST calibration facilities. The on-orbit radiometric standard is the Sun. The NIST traceable ground spectral albedo calibration is invariant between the ground and on-orbit over the instrument lifetime due to the use of a field of view defining mechanical baffle to differentiate between radiance and irradiance.

  5. Evaluation of a gully headcut retreat model using multitemporal aerial photographs and digital elevation models

    NASA Astrophysics Data System (ADS)

    Campo-Bescós, M. A.; Flores-Cervantes, J. H.; Bras, R. L.; Casalí, J.; Giráldez, J. V.

    2013-12-01

    large fraction of soil erosion in temperate climate systems proceeds from gully headcut growth processes. Nevertheless, headcut retreat is not well understood. Few erosion models include gully headcut growth processes, and none of the existing headcut retreat models have been tested against long-term retreat rate estimates. In this work the headcut retreat resulting from plunge pool erosion in the Channel Hillslope Integrated Landscape Development (CHILD) model is calibrated and compared to long-term evolution measurements of six gullies at the Bardenas Reales, northeast Spain. The headcut retreat module of CHILD was calibrated by adjusting the shape factor parameter to fit the observed retreat and volumetric soil loss of one gully during a 36 year period, using reported and collected field data to parameterize the rest of the model. To test the calibrated model, estimates by CHILD were compared to observations of headcut retreat from five other neighboring gullies. The differences in volumetric soil loss rates between the simulations and observations were less than 0.05 m3 yr-1, on average, with standard deviations smaller than 0.35 m3 yr-1. These results are the first evaluation of the headcut retreat module implemented in CHILD with a field data set. These results also show the usefulness of the model as a tool for simulating long-term volumetric gully evolution due to plunge pool erosion.

  6. Using the Moon to Track MODIS Reflective Solar Bands Calibration Stability

    NASA Technical Reports Server (NTRS)

    Xiong, Xiaoxiong; Geng, Xu; Angal, Amit; Sun, Junqiang; Barnes, William

    2011-01-01

    MODIS has 20 reflective solar bands (RSB) in the visible (VIS), near infrared (NIR), and short-wave infrared (SWIR) spectral regions. In addition to instrument on-board calibrators (OBC), lunar observations have been used by both Terra and Aqua MODIS to track their reflective solar bands (RSB) on-orbit calibration stability. On a near monthly basis, lunar observations are scheduled and implemented for each instrument at nearly the same lunar phase angles. A time series of normalized detector responses to the Moon is used to monitor its on-orbit calibration stability. The normalization is applied to correct the differences of lunar viewing geometries and the Sun-Moon-Sensor distances among different lunar observations. Initially, the lunar calibration stability monitoring was only applied to MODIS bands (1-4 and 8-12) that do not saturate while viewing the Moon. As the mission continued, we extended the lunar calibration stability monitoring to other RSB bands (bands 13-16) that contain saturated pixels. For these bands, the calibration stability is monitored by referencing their non-saturated pixels to the matched pixels in a non-saturation band. In this paper, we describe this relative approach and apply it to MODIS regularly scheduled lunar observations. We present lunar trending results for both Terra and Aqua MODIS over their entire missions. Also discussed in the paper are the advantages and limitations of this approach and its potential applications to other earth-observing sensors. Keywords: Terra, Aqua, MODIS, sensor, Moon, calibration, stability

  7. New kind of injection-locked oscillator and its corresponding long-term stability control.

    PubMed

    Hong, Jun; Liu, An; Wang, Xiao-hu; Yao, Sheng-xing; Li, Zu-ling

    2015-09-20

    A new type of opto-electronic hybrid oscillator is proposed for the first time, to the best of our knowledge, and verified by experiments in this paper. Typical electronic oscillator-dielectric resonator oscillator as the first injection source is used to injection lock the first long-fiber loop-based opto-electronic oscillator (OEO); then its output is used to injection lock the second long-fiber opto-electronic oscillator. Using this method, low-phase noise output signal can be obtained. Experiments show that single side-band (SSB) phase noise of a 9.5 GHz oscillation signal at 10 kHz offset frequency decreases from -123 to -135  dBc/Hz after the first injection, then, through the second injection, the SSB phase noise drops down to -146  dBc/Hz. In order to solve the long-term stability problem of the above oscillator, a new stability-control circuit also is designed and verified by experiments. Experiments show that the Allan deviation decreases from 9.0×10(-11) to 2.2×10(-12) during 1 s after the long-term stability-control circuit being used.

  8. Limb Sensing, on the Path to Better Weather Forecasting.

    NASA Astrophysics Data System (ADS)

    Gordley, L. L.; Marshall, B. T.; Lachance, R. L.; Fritts, D. C.; Fisher, J.

    2017-12-01

    Earth limb observations from orbiting sensors have a rich history. The cold space background, long optical paths, and limb geometry provide formidable advantages for calibration, sensitivity and retrieval of vertically well-resolved geophysical parameters. The measurement of limb ray refraction now provides temperature and pressure profiles unburdened by requirements of spectral calibration or gas concentration knowledge, leading to reliable long-term trends. This talk discusses those advantages and our relevant achievements with data from the SOFIE instrument on the AIM satellite. We then describe a path to advances in calibration, sensitivity, profile fidelity, and synergy between limb sensors and nadir sounders. These advances also include small-sat compatible size, elimination of on-board calibration systems and simple static designs, dramatically reducing risk, complexity and cost. Finally, we show how these advances, made possible by modern ADCS, FPA and GPS capabilities, will lead to improvements in weather forecasting and climate observation.

  9. Characterization and control of EUV scanner dose uniformity and stability

    NASA Astrophysics Data System (ADS)

    Robinson, Chris; Corliss, Dan; Meli, Luciana; Johnson, Rick

    2018-03-01

    The EUV source is an impressive feat of engineering that provides 13.5 nm radiation by vaporizing tin droplets with a high power CO2 laser and focusing the photons produced in the resultant plasma into the scanner illumination system. Great strides have been made in addressing the many potential stability challenges, but there are still residual spatial and temporal dose non-uniformity signatures. Since even small dose errors can impact the yieldable process window for the advanced lithography products that are exposed on EUV scanners it is crucial to monitor and control the dose variability. Using on-board metrology, the EUV scanner outputs valuable metrics that provide real time insight into the dose performance. We have supplemented scanner data collection with a wafer based methodology that provides high throughput, high sensitivity, quantitative characterization of the EUV scanner dose delivery. The technique uses open frame EUV exposures, so it is exclusive of lithographic pattern imaging, exclusive of lithographic mask pattern and not limited by placement of metrology features. Processed wafers are inspected rapidly, providing 20,000 pixels of detail per exposure field in approximately one minute. Exposing the wafer on the scanner with a bit less than the resist E0 (open frame clearing dose) results in good sensitivity to small variations in the EUV dose delivered. The nominal exposure dose can be modulated by field to calibrate the inspection results and provide quantitative assessment of variations with < 1% sensitivity. This technique has been used for dose uniformity assessments. It is also being used for long term dose stability monitoring and has proven valuable for short term dose stability follow up investigations.

  10. Calibration of passive remote observing optical and microwave instrumentation; Proceedings of the Meeting, Orlando, FL, Apr. 3-5, 1991

    NASA Technical Reports Server (NTRS)

    Guenther, Bruce W. (Editor)

    1991-01-01

    Various papers on the calibration of passive remote observing optical and microwave instrumentation are presented. Individual topics addressed include: on-board calibration device for a wide field-of-view instrument, calibration for the medium-resolution imaging spectrometer, cryogenic radiometers and intensity-stabilized lasers for EOS radiometric calibrations, radiometric stability of the Shuttle-borne solar backscatter ultraviolet spectrometer, ratioing radiometer for use with a solar diffuser, requirements of a solar diffuser and measurements of some candidate materials, reflectance stability analysis of Spectralon diffuse calibration panels, stray light effects on calibrations using a solar diffuser, radiometric calibration of SPOT 23 HRVs, surface and aerosol models for use in radiative transfer codes. Also addressed are: calibrated intercepts for solar radiometers used in remote sensor calibration, radiometric calibration of an airborne multispectral scanner, in-flight calibration of a helicopter-mounted Daedalus multispectral scanner, technique for improving the calibration of large-area sphere sources, remote colorimetry and its applications, spatial sampling errors for a satellite-borne scanning radiometer, calibration of EOS multispectral imaging sensors and solar irradiance variability.

  11. Intercomparison of 30+ years of AVHRR and Landsat-5 TM Surface Reflectance using Multiple Pseudo-Invariant Calibration Sites

    NASA Astrophysics Data System (ADS)

    Santamaría-Artigas, A. E.; Franch, B.; Vermote, E.; Roger, J. C.; Justice, C. O.

    2017-12-01

    The 30+ years daily surface reflectance long term data record (LTDR) from the Advanced Very High Resolution Radiometer (AVHRR) is a valuable source of information for long-term studies of the Earth surface. This LTDR was generated by combining observations from multiple AVHRR sensors aboard different NOAA satellites starting from the early 1980s, and due to the lack of on-board calibration its quality should be evaluated. Previous studies have used observations from the Moderate Resolution Imaging Spectroradiometer (MODIS) over pseudo-invariant calibration sites (PICS) as a calibrated reference to assess the performance of AVHRR products. However, this limits the evaluation to the period after MODIS launch. In this work, the AVHRR surface reflectance LTDR was evaluated against Landsat-5 Thematic Mapper (TM) data using observations from 4 well known pseudo-invariant calibration sites (i.e. Sonoran, Saharan, Sudan1, and Libya4) over an extended time period (1984-2011). For the intercomparison, AVHRR and TM observations of each site were extracted and averaged over a 20 km x 20 km area and aggregated to monthly mean values. In order to account for the spectral differences between sensors, Hyperion hyperspectral data from the Sonoran and Libya4 sites were convolved with sensor-specific relative spectral responses, and used to compute spectral band adjustment factors (SBAFs). Results of the intercomparison are reported in terms of the root mean square difference (RMSD) and determination coefficient (r2). In general, there is good agreement between the surface reflectance products from both sensors. The overall RMSD and r2 for all the sites and AVHRR/TM combinations were 0.03 and 0.85 for the red band, and 0.04 and 0.81 for the near-infrared band. These results show the strong performance of the AVHRR surface reflectance LTDR through all of the considered period. Thus, remarking its usefulness and value for long term Earth studies. Figure 1 shows the red (filled markers) and near-infrared (empty markers) surface reflectance from AVHRR and TM for the complete evaluation period over the Saharan (diamond), Libya4 (square), Sudan1 (triangle), and Sonoran (circle) PICS.

  12. Temperature regulation during ultrasonic manipulation for long-term cell handling in a microfluidic chip

    NASA Astrophysics Data System (ADS)

    Svennebring, J.; Manneberg, O.; Wiklund, M.

    2007-12-01

    We demonstrate simultaneous micromanipulation and temperature regulation by the use of ultrasonic standing wave technology in a microfluidic chip. The system is based on a microfabricated silicon structure sandwiched between two glass layers, and an external ultrasonic transducer using a refractive wedge placed on top of the chip for efficient coupling of ultrasound into the microchannel. The chip is fully transparent and compatible with any kind of high-resolution optical microscopy. The temperature regulation method uses calibration data of the temperature increase due to the ultrasonic actuation for determining the temperature of the surrounding air and microscope table, controlled by a warm-air heating unit and a heatable mounting frame. The heating methods are independent of each other, resulting in a flexible choice of ultrasonic actuation voltage and flow rate for different cell and particle manipulation purposes. Our results indicate that it is possible to perform stable temperature regulation with an accuracy of the order of ±0.1 °C around any physiologically relevant temperature (e.g., 37 °C) with high temporal stability and repeatability. The purpose is to use ultrasound for long-term cell and/or particle handling in a microfluidic chip while controlling and maintaining the biocompatibility of the system.

  13. Highly stable liquid metal-based pressure sensor integrated with a microfluidic channel.

    PubMed

    Jung, Taekeon; Yang, Sung

    2015-05-21

    Pressure measurement is considered one of the key parameters in microfluidic systems. It has been widely used in various fields, such as in biology and biomedical fields. The electrical measurement method is the most widely investigated; however, it is unsuitable for microfluidic systems because of a complicated fabrication process and difficult integration. Moreover, it is generally damaged by large deflection. This paper proposes a thin-film-based pressure sensor that is free from these limitations, using a liquid metal called galinstan. The proposed pressure sensor is easily integrated into a microfluidic system using soft lithography because galinstan exists in a liquid phase at room temperature. We investigated the characteristics of the proposed pressure sensor by calibrating for a pressure range from 0 to 230 kPa (R2 > 0.98) using deionized water. Furthermore, the viscosity of various fluid samples was measured for a shear-rate range of 30-1000 s(-1). The results of Newtonian and non-Newtonian fluids were evaluated using a commercial viscometer and normalized difference was found to be less than 5.1% and 7.0%, respectively. The galinstan-based pressure sensor can be used in various microfluidic systems for long-term monitoring with high linearity, repeatability, and long-term stability.

  14. Highly Stable Liquid Metal-Based Pressure Sensor Integrated with a Microfluidic Channel

    PubMed Central

    Jung, Taekeon; Yang, Sung

    2015-01-01

    Pressure measurement is considered one of the key parameters in microfluidic systems. It has been widely used in various fields, such as in biology and biomedical fields. The electrical measurement method is the most widely investigated; however, it is unsuitable for microfluidic systems because of a complicated fabrication process and difficult integration. Moreover, it is generally damaged by large deflection. This paper proposes a thin-film-based pressure sensor that is free from these limitations, using a liquid metal called galinstan. The proposed pressure sensor is easily integrated into a microfluidic system using soft lithography because galinstan exists in a liquid phase at room temperature. We investigated the characteristics of the proposed pressure sensor by calibrating for a pressure range from 0 to 230 kPa (R2 > 0.98) using deionized water. Furthermore, the viscosity of various fluid samples was measured for a shear-rate range of 30–1000 s−1. The results of Newtonian and non-Newtonian fluids were evaluated using a commercial viscometer and normalized difference was found to be less than 5.1% and 7.0%, respectively. The galinstan-based pressure sensor can be used in various microfluidic systems for long-term monitoring with high linearity, repeatability, and long-term stability. PMID:26007732

  15. Long term in vitro stability of fully integrated wireless neural interfaces based on Utah slant electrode array

    NASA Astrophysics Data System (ADS)

    Sharma, Asha; Rieth, Loren; Tathireddy, Prashant; Harrison, Reid; Solzbacher, Florian

    2010-02-01

    We herein report in vitro functional stability and recording longevity of a fully integrated wireless neural interface (INI). The INI uses biocompatible Parylene-C as an encapsulation layer, and was immersed in phosphate buffered saline (PBS) for a period of over 150 days. The full functionality (wireless radio-frequency power, command, and signal transmission) and the ability of INI to record artificial action potentials even after 150 days of PBS soaking without any change in signal/noise amplitude constitutes a major milestone in long term stability, and evaluate the encapsulation reliability, functional stability, and potential usefulness for future chronic implants.

  16. Optimization of scintillator loading with the tellurium-130 isotope for long-term stability

    NASA Astrophysics Data System (ADS)

    Duhamel, Lauren; Song, Xiaoya; Goutnik, Michael; Kaptanoglu, Tanner; Klein, Joshua; SNO+ Collaboration

    2017-09-01

    Tellurium-130 was selected as the isotope for the SNO + neutrinoless double beta decay search, as 130Te decays to 130Xe via double beta decay. Linear alkyl benzene(LAB) is the liquid scintillator for the SNO + experiment. To load tellurium into scintillator, it is combined with 1,2-butanediol to form an organometallic complex, commonly called tellurium butanediol (TeBD). This study focuses on maximizing the percentage of tellurium loaded into scintillator and evaluates the complex's long-term stability. Studies on the effect of nucleation due to imperfections in the detector's surface and external particulates were employed by filtration and induced nucleation. The impact of water on the stability of TeBD complex was evaluated by liquid-nitrogen sparging, variability in pH and induced humidity. Alternative loading methods were evaluated, including the addition of stability-inducing organic compounds. Samples of tellurium-loaded scintillator were synthesized, treated, and consistently monitored in a controlled environment. It was found that the hydronium ions cause precipitation in the loaded scintillator, demonstrating that water has a detrimental effect on long-term stability. Optimization of loaded scintillator stability can contribute to the SNO + double beta decay search.

  17. Long-Term Evaluation of the AMSR-E Soil Moisture Product Over the Walnut Gulch Watershed, AZ

    NASA Astrophysics Data System (ADS)

    Bolten, J. D.; Jackson, T. J.; Lakshmi, V.; Cosh, M. H.; Drusch, M.

    2005-12-01

    The Advanced Microwave Scanning Radiometer -Earth Observing System (AMSR-E) was launched aboard NASA's Aqua satellite on May 4th, 2002. Quantitative estimates of soil moisture using the AMSR-E provided data have required routine radiometric data calibration and validation using comparisons of satellite observations, extended targets and field campaigns. The currently applied NASA EOS Aqua ASMR-E soil moisture algorithm is based on a change detection approach using polarization ratios (PR) of the calibrated AMSR-E channel brightness temperatures. To date, the accuracy of the soil moisture algorithm has been investigated on short time scales during field campaigns such as the Soil Moisture Experiments in 2004 (SMEX04). Results have indicated self-consistency and calibration stability of the observed brightness temperatures; however the performance of the moisture retrieval algorithm has been poor. The primary objective of this study is to evaluate the quality of the current version of the AMSR-E soil moisture product for a three year period over the Walnut Gulch Experimental Watershed (150 km2) near Tombstone, AZ; the northern study area of SMEX04. This watershed is equipped with hourly and daily recording of precipitation, soil moisture and temperature via a network of raingages and a USDA-NRCS Soil Climate Analysis Network (SCAN) site. Surface wetting and drying are easily distinguished in this area due to the moderately-vegetated terrain and seasonally intense precipitation events. Validation of AMSR-E derived soil moisture is performed from June 2002 to June 2005 using watershed averages of precipitation, and soil moisture and temperature data from the SCAN site supported by a surface soil moisture network. Long-term assessment of soil moisture algorithm performance is investigated by comparing temporal variations of moisture estimates with seasonal changes and precipitation events. Further comparisons are made with a standard soil dataset from the European Centre for Medium-Range Weather Forecasts. The results of this research will contribute to a better characterization of the low biases and discrepancies currently observed in the AMSR-E soil moisture product.

  18. The role of silica nanoparticles on long-term room-temperature stabilization of water-in-oil emulsions containing microalgae.

    PubMed

    Fernández, L; Scher, H; VanderGheynst, J S

    2015-12-01

    Prior research has demonstrated that microalgae can be stored for extended periods of time at room temperature in water-in-oil (W/O) emulsions stabilized by surface modified silica nanoparticles. However, little research has been done to examine the impact of nanoparticle concentration on emulsion stability. Such information is important for large-scale production of emulsions for microalgae storage and delivery. Studies were done to examine the impact of silica nanoparticle concentration on emulsion stability and identify the lower limit for nanoparticle concentration. Emulsion physical stability was determined using internal phase droplet size measurements and biological stability was evaluated using cell density measurements. The results demonstrate that nanoparticle concentrations as low as 0·5wt% in the oil phase can be used without significant losses in emulsion stability and microalgae viability. Stabilization technologies are needed for long-term storage and application of microalgae in agricultural-scale systems. While prior work has demonstrated that water-in-oil emulsions containing silica nanoparticles offer a promising solution for long-term microalgae storage at room temperature, little research has been done to examine the impact of nanoparticle concentration on emulsion stability. Here, we show the effects of silica nanoparticle concentration on maintaining physical stability of emulsions and sustaining viable cells. The results enable informed decisions to be made regarding production of emulsions containing silica nanoparticles and associated impacts on stabilization of microalgae. © 2015 The Society for Applied Microbiology.

  19. MODIS and SeaWIFS on-orbit lunar calibration

    USGS Publications Warehouse

    Sun, Jielun; Eplee, R.E.; Xiong, X.; Stone, T.; Meister, G.; McClain, C.R.

    2008-01-01

    The Moon plays an important role in the radiometric stability monitoring of the NASA Earth Observing System's (EOS) remote sensors. The MODIS and SeaWIFS are two of the key instruments for NASA's EOS missions. The MODIS Protoflight Model (PFM) on-board the Terra spacecraft and the MODIS Flight Model 1 (FM1) on-board the Aqua spacecraft were launched on December 18, 1999 and May 4, 2002, respectively. They view the Moon through the Space View (SV) port approximately once a month to monitor the long-term radiometric stability of their Reflective Solar Bands (RSB). SeaWIFS was launched on-board the OrbView-2 spacecraft on August 1, 1997. The SeaWiFS lunar calibrations are obtained once a month at a nominal phase angle of 7??. The lunar irradiance observed by these instruments depends on the viewing geometry. The USGS photometric model of the Moon (the ROLO model) has been developed to provide the geometric corrections for the lunar observations. For MODIS, the lunar view responses with corrections for the viewing geometry are used to track the gain change for its reflective solar bands (RSB). They trend the system response degradation at the Angle Of Incidence (AOI) of sensor's SV port. With both the lunar observation and the on-board Solar Diffuser (SD) calibration, it is shown that the MODIS system response degradation is wavelength, mirror side, and AOI dependent. Time-dependent Response Versus Scan angle (RVS) Look-Up Tables (LUT) are applied in MODIS RSB calibration and lunar observations play a key role in RVS derivation. The corrections provided by the RVS in the Terra and Aqua MODIS data from the 412 nm band are as large as 16% and 13%, respectively. For SeaWIFS lunar calibrations, the spacecraft is pitched across the Moon so that the instrument views the Moon near nadir through the same optical path as it views the Earth. The SeaWiFS system gain changes for its eight bands are calibrated using the geometrically-corrected lunar observations. The radiometric corrections to the SeaWiFS data, after more than ten years on orbit, are 19% at 865 nm, 8% at 765 nm, and 1-3% in the other bands. In this report, the lunar calibration algorithms are reviewed and the RSB gain changes observed by the lunar observations are shown for all three sensors. The lunar observations for the three instruments are compared using the USGS photometric model. The USGS lunar model facilitates the cross calibration of instruments with different spectra bandpasses whose measurements of the Moon differ in time and observing geometry.

  20. Estimation Filter for Alignment of the Spitzer Space Telescope

    NASA Technical Reports Server (NTRS)

    Bayard, David

    2007-01-01

    A document presents a summary of an onboard estimation algorithm now being used to calibrate the alignment of the Spitzer Space Telescope (formerly known as the Space Infrared Telescope Facility). The algorithm, denoted the S2P calibration filter, recursively generates estimates of the alignment angles between a telescope reference frame and a star-tracker reference frame. At several discrete times during the day, the filter accepts, as input, attitude estimates from the star tracker and observations taken by the Pointing Control Reference Sensor (a sensor in the field of view of the telescope). The output of the filter is a calibrated quaternion that represents the best current mean-square estimate of the alignment angles between the telescope and the star tracker. The S2P calibration filter incorporates a Kalman filter that tracks six states - two for each of three orthogonal coordinate axes. Although, in principle, one state per axis is sufficient, the use of two states per axis makes it possible to model both short- and long-term behaviors. Specifically, the filter properly models transient learning, characteristic times and bounds of thermomechanical drift, and long-term steady-state statistics, whether calibration measurements are taken frequently or infrequently. These properties ensure that the S2P filter performance is optimal over a broad range of flight conditions, and can be confidently run autonomously over several years of in-flight operation without human intervention.

  1. INFLUENCE OF IRON CHELATION ON R1 AND R2 CALIBRATION CURVES IN GERBIL LIVER AND HEART

    PubMed Central

    Wood, John C.; Aguilar, Michelle; Otto-Duessel, Maya; Nick, Hanspeter; Nelson, Marvin D.; Moats, Rex

    2008-01-01

    MRI is gaining increasing importance for the noninvasive quantification of organ iron burden. Since transverse relaxation rates depend on iron distribution as well as iron concentration, physiologic and pharmacologic processes that alter iron distribution could change MRI calibration curves. This paper compares the effect of three iron chelators, deferoxamine, deferiprone, and deferasirox on R1 and R2 calibration curves according to two iron loading and chelation strategies. 33 Mongolian gerbils underwent iron loading (iron dextran 500 mg/kg/wk) for 3 weeks followed by 4 weeks of chelation. An additional 56 animals received less aggressive loading (200 mg/kg/week) for 10 weeks, followed by 12 weeks of chelation. R1 and R2 calibration curves were compared to results from 23 iron-loaded animals that had not received chelation. Acute iron loading and chelation biased R1 and R2 from the unchelated reference calibration curves but chelator-specific changes were not observed, suggesting physiologic rather than pharmacologic differences in iron distribution. Long term chelation deferiprone treatment increased liver R1 50% (p<0.01), while long term deferasirox lowered liver R2 30.9% (p<0.0001). The relationship between R1 and R2 and organ iron concentration may depend upon the acuity of iron loading and unloading as well as the iron chelator administered. PMID:18581418

  2. Calibrating electromagnetic induction conductivities with time-domain reflectometry measurements

    NASA Astrophysics Data System (ADS)

    Dragonetti, Giovanna; Comegna, Alessandro; Ajeel, Ali; Piero Deidda, Gian; Lamaddalena, Nicola; Rodriguez, Giuseppe; Vignoli, Giulio; Coppola, Antonio

    2018-02-01

    This paper deals with the issue of monitoring the spatial distribution of bulk electrical conductivity, σb, in the soil root zone by using electromagnetic induction (EMI) sensors under different water and salinity conditions. To deduce the actual distribution of depth-specific σb from EMI apparent electrical conductivity (ECa) measurements, we inverted the data by using a regularized 1-D inversion procedure designed to manage nonlinear multiple EMI-depth responses. The inversion technique is based on the coupling of the damped Gauss-Newton method with truncated generalized singular value decomposition (TGSVD). The ill-posedness of the EMI data inversion is addressed by using a sharp stabilizer term in the objective function. This specific stabilizer promotes the reconstruction of blocky targets, thereby contributing to enhance the spatial resolution of the EMI results in the presence of sharp boundaries (otherwise smeared out after the application of more standard Occam-like regularization strategies searching for smooth solutions). Time-domain reflectometry (TDR) data are used as ground-truth data for calibration of the inversion results. An experimental field was divided into four transects 30 m long and 2.8 m wide, cultivated with green bean, and irrigated with water at two different salinity levels and using two different irrigation volumes. Clearly, this induces different salinity and water contents within the soil profiles. For each transect, 26 regularly spaced monitoring soundings (1 m apart) were selected for the collection of (i) Geonics EM-38 and (ii) Tektronix reflectometer data. Despite the original discrepancies in the EMI and TDR data, we found a significant correlation of the means and standard deviations of the two data series; in particular, after a low-pass spatial filtering of the TDR data. Based on these findings, this paper introduces a novel methodology to calibrate EMI-based electrical conductivities via TDR direct measurements. This calibration strategy consists of a linear mapping of the original inversion results into a new conductivity spatial distribution with the coefficients of the transformation uniquely based on the statistics of the two original measurement datasets (EMI and TDR conductivities).

  3. Short- and long-term responses of total soil organic carbon to harvesting in a northern hardwood forest

    Treesearch

    K. Johnson; F. N. Scatena; Y. Pan

    2010-01-01

    The long-term response of total soil organic carbon pools (‘total SOC’, i.e. soil and dead wood) to different harvesting scenarios in even-aged northern hardwood forest stands was evaluated using two soil carbon models, CENTURY and YASSO, that were calibrated with forest plot empirical data in the Green Mountains of Vermont. Overall, 13 different harvesting scenarios...

  4. Large variability of biochar stability and biochar properties

    NASA Astrophysics Data System (ADS)

    Lehmann, J.; Nguyen, B.; Hanley, K.; Enders, A.

    2008-12-01

    In general, charring or purposeful pyrolysis increases the stability of biomass. It is less clear, however, to what extent biochar properties influence its stability. Chemical and physical properties of biochars and biomass-derived black carbons (BC) vary greatly as a function of the type of biomass it was generated from and of the production temperature. We show that these properties greatly affect the stability of BC is a function of both these factors, with highly significant interactions. BC produced from corn stalks produced at 350°C decomposed much quicker when incubated at field capacity at 30°C for one year than those produced at 600°C. In contrast, there was hardly a difference noted between those two temperatures if oak was the precursor biomass. Such differences in labile carbon not only affect the proportion of stable carbon in BC, but also influence the quantification of long-term stability. Extrapolation from short-term decay to long-term stability may require prior knowledge about the decay rate of the labile fraction of BC. Some indications are provided for the short-term oxidation of BC.

  5. Long-term maintenance of the carrier-envelope phase coherence of a femtosecond laser.

    PubMed

    Kim, Eok Bong; Lee, Jae-Hwan; Lee, Won-Kyu; Luu, Tran Trung; Nam, Chang Hee

    2010-12-06

    The long-term carrier-envelope phase (CEP) coherence of a femtosecond laser with same pulse-to-pulse CEP value, obtained using the direct locking method, is demonstrated by employing a quasi-common-path interferometer (QPI). For the evaluation of the CEP stability, the phase noise properties of a femtosecond laser with the CEP stabilized using a QPI are compared with those obtained using a Mach-Zehnder f-2f interferometer, for which the phase power spectral density and the Allan deviation were calculated from the beat signals of the interferometers. With the improved CEP stability, the long-term CEP coherent signal with an accumulated phase noise well below 1 radian can be maintained for more than 56 hours, i.e., the CEP coherence is preserved without a phase cycle slip for more than 1.6 × 10(13) pulses at a repetition rate of 80 MHz. The relative stability is also estimated to be approximately 1.4 × 10(-22) at a central wavelength of 790 nm.

  6. Influence of the dynamic Stark effect on long-term frequency stability of a self-oscillating magnetometer with laser-pumped alkali atoms

    NASA Astrophysics Data System (ADS)

    Baranov, A. A.; Ermak, S. V.; Kulachenkov, N. K.; Petrenko, M. V.; Sagitov, E. A.; Semenov, V. V.

    2017-11-01

    This paper presents the results of investigation Stark shift effect influence on the long-term stability of a dual scheme of quantum magnetometers. Such scheme allows suppressing Stark shift components when a certain pumping light polarization is applied. As a result, long-term stability of a quantum sensor increases. However, when low-frequency (LF) and microwave fields are attached to a single vapor cell a coherence circulation in hyperfine structure of alkali atoms takes place. Physical origin of this effect is associated with the so called “dressed” atom theory, when atom is “dressed” by LF field. It yields in multiphoton absorption and resonance frequency shift. First estimates for this shift based on density matrix evolution formalism are provided in the paper.

  7. Tracking Trends in Fractional Forest Cover Change using Long Term Data from AVHRR and MODIS

    NASA Astrophysics Data System (ADS)

    Kim, D. H.; DiMiceli, C.; Sohlberg, R. A.; Hansen, M.; Carroll, M.; Kelly, M.; Townshend, J. R.

    2014-12-01

    Tree cover affects terrestrial energy and water exchanges, photosynthesis and transpiration, net primary production, and carbon and nutrient fluxes. Accurate and long-term continuous observation of tree cover change is critical for the study of the gradual ecosystem change. Tree cover is most commonly inferred from categorical maps which may inadequately represent within-class heterogeneity for many analyses. Alternatively, Vegetation Continuous Fields data measures fractions or proportions of pixel area. Recent development in remote sensing data processing and cross sensor calibration techniques enabled the continuous, long-term observations such as Land Long-Term Data Records. Such data products and their surface reflectance data have enhanced the possibilities for long term Vegetation Continuous Fields data, thus enabling the estimation of long term trend of fractional forest cover change. In this presentation, we will summarize the progress in algorithm development including automation of training selection for deciduous and evergreen forest, the preliminary results, and its future applications to relate trends in fractional forest cover change and environmental change.

  8. Long-term stable active mount for reflective optics

    NASA Astrophysics Data System (ADS)

    Reinlein, C.; Brady, A.; Damm, C.; Mohaupt, M.; Kamm, A.; Lange, N.; Goy, M.

    2016-07-01

    We report on the development of an active mount with an orthogonal actuator matrix offering a stable shape optimization for gratings or mirrors. We introduce the actuator distribution and calculate the accessible Zernike polynomials from their actuator influence function. Experimental tests show the capability of the device to compensate for aberrations of grating substrates as we report measurements of a 110x105 mm2 and 220x210 mm2 device With these devices, we evaluate the position depending aberrations, long-term stability shape results, and temperature-induced shape variations. Therewith we will discuss potential applications in space telescopes and Earth-based facilities where long-term stability is mandatory.

  9. Simbol-X Telescope Scientific Calibrations: Requirements and Plans

    NASA Astrophysics Data System (ADS)

    Malaguti, G.; Angelini, L.; Raimondi, L.; Moretti, A.; Trifoglio, M.

    2009-05-01

    The Simbol-X telescope characteristics and the mission scientific requirements impose a challenging calibration plan with a number of unprecedented issues. The 20 m focal length implies for the incoming X-ray beam a divergence comparable to the incidence angle of the mirror surface also for 100 m-long facilities. Moreover this is the first time that a direct focussing X-ray telescope will be calibrated on an energy band covering about three decades, and with a complex focal plane. These problems require a careful plan and organization of the measurements, together with an evaluation of the calibration needs in terms of both hardware and software.

  10. Note: Improving long-term stability of hot-wire anemometer sensors by means of annealing

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lundström, H., E-mail: hans.lundstrom@hig.se

    2015-08-15

    Annealing procedures for hot-wire sensors of platinum and platinum-plated tungsten have been investigated experimentally. It was discovered that the two investigated sensor metals behave quite differently during the annealing process, but for both types annealing may improve long-term stability considerably. Measured drift of sensors both without and with prior annealing is presented. Suggestions for suitable annealing temperatures and times are given.

  11. Long-term Stabilization of Disturbed Slopes Resulting from Construction Operations

    DOT National Transportation Integrated Search

    2018-01-01

    Highway construction disturbs soil, which must be stabilized to prevent migration of soil particles into water bodies. Stabilization is enforced by law, regulation, and a permit system. Stabilization is most efficiently attained by reestablishment of...

  12. Field campaigns of the autonomous, closed-path, airborne TDLAS Hygrometer SEALDH-II and traceability to the German Primary Humidity Standards.

    NASA Astrophysics Data System (ADS)

    Buchholz, Bernhard; Ebert, Volker

    2014-05-01

    Airborne hygrometry is often demanded in scientific flight campaigns to provide datasets for environmental modeling or to correct for water vapor dilution or cross sensitivity effects in other gas analytical techniques. Water vapor measurements, however, are quite challenging due to the large dynamic range in the atmosphere (between 2 and 40000 ppmv) and the high spatio-temporal variability. Airborne hygrometers therefore need to combine a large measurement range with high temporal resolution to resolve - at typical airspeeds of 500 to 900 km/h - atmospheric gradients of several 1000 ppmv/s. Especially during the ascent into the upper troposphere, hygrometers need to work at high gas exchange rates to minimize water vapor adsorption effects. On the other hand, water vapor sensors are difficult to calibrate due to the strong water adsorption and the lack of bottled reference gas standards, which requires pre- or/and post-flight field calibrations. Recently in-flight calibration using an airborne H2O generator was demonstrated, which minimizes calibration drift but still imposes a lot of additional work and hardware to the experiments, since these kind of calibrations just transfer the accuracy level issues to the in-flight calibration-source. To make things worse, the low gas flow (1-5 std l/min, compared with up to 100 std l/min in flight for fast response instruments) adheres critical questions of wall absorption/desorption of the source and instrument even during the calibration process. The national metrological institutes (NMIs) maintain a global metrological water vapor scale which is defined via national primary humidity generators. These provide for calibration purposes well-defined, accurate water vapor samples of excellent comparability and stability traced back to the SI-units. The humidity calibration chain is maintained via high accuracy (but rather slow) Dew-Point-Mirror-Hygrometers as transfer standards. These provide a traceable performance and calibration link to any industrial or research laboratory hygrometer. To establish metrological traceability in field and particular in airborne hygrometers is however challenging and requires fast, field-compatible, metrologically qualified transfer hygrometry standards to link the metrological and the environmental sciences water scales. The SEALDH (Selective Extractive Airborne Laser Diode Hygrometer) development started 3 years ago and aims at filling this gap by using Tunable Diode Laser Absorption Spectroscopy (TDLAS) with a special, calibration-free data evaluation [1]. Previously developed, laboratory-based TDLAS instruments, such as [2] [3], were starting points to develop an autonomously operating, extractive water vapor sensor in a compact 19' 4 HU form factor. This new airborne package and far-reaching developments [4] in hard- and software allow an autonomous, low maintenance, airborne operation. SEALDH-II can be used in a calibration-free field sensor mode (with an absolute, metrologically defined uncertainty of 4.3% +- 3ppmv). The response time is mainly limited by the gas flow and significantly below 1 sec with a precision down to 0.08 ppmv (1σ, 1sec) measured at 600 ppmv and 1000 hPa. The excellent long-term stability of SEALDH-II (

  13. Development of certified reference materials for electrolytes in human serum (GBW09124-09126).

    PubMed

    Feng, Liuxing; Wang, Jun; Cui, Yanjie; Shi, Naijie; Li, Haifeng; Li, Hongmei

    2017-05-01

    Three reference materials, at relatively low, middle, and high concentrations, were developed for analysis of the mass fractions of electrolytes (K, Ca, Na, Mg, Cl, and Li) in human serum. The reference materials were prepared by adding high purity chloride salts to normal human serum. The concentration range of the three levels is within ±20% of normal human serum. It was shown that 14 units with duplicate analysis is enough to demonstrate the homogeneity of these candidate reference materials. The statistical results also showed no significant trends in both short-term stability test for 1 week at 40 °C and long-term stability test for 14 months. The certification methods of the six elements include isotope dilution inductively coupled plasma mass spectrometry (ID-ICP-MS), inductively coupled plasma optical emission spectroscopy (ICP-OES), atomic absorption spectroscopy (AAS), ion chromatography (IC), and ion-selective electrode (ISE). The certification methods were validated by international comparisons among a number of national metrology institutes (NMIs). The combined relative standard uncertainties of the property values were estimated by considering the uncertainties of the analytical methods, homogeneity, and stability. The range of the expanded uncertainties of all the elements is from 2.2% to 3.9%. The certified reference materials (CRMs) are primarily intended for use in the calibration and validation of procedures in clinical analysis for the determination of electrolytes in human serum or plasma. Graphical Abstract Certified reference materials for K, Ca, Mg, Na, Cl and Li in human serum (GBW09124-09126).

  14. In-flight performance of the Ozone Monitoring Instrument

    PubMed Central

    Schenkeveld, V.M. Erik; Jaross, Glen; Marchenko, Sergey; Haffner, David; Kleipool, Quintus L.; Rozemeijer, Nico C.; Veefkind, J. Pepijn; Levelt, Pieternel F.

    2018-01-01

    The Dutch-Finnish Ozone Monitoring Instrument (OMI) is an imaging spectrograph flying on NASA’s EOS Aura satellite since July 15, 2004. OMI is primarily used to map trace gas concentrations in the Earth’s atmosphere, obtaining mid-resolution (0.4–0.6 nm) UV-VIS (264–504 nm) spectra at multiple (30–60) simultaneous fields of view. Assessed via various approaches that include monitoring of radiances from selected ocean, land, ice and cloud areas, as well as measurements of line profiles in the Solar spectra, the instrument shows low optical degradation and high wavelength stability over the mission lifetime. In the regions relatively free from the slowly unraveling ‘row anomaly’ the OMI irradiances have degraded by 3–8%, while radiances have changed by 1–2%. The long-term wavelength calibration of the instrument remains stable to 0.005–0.020 nm. PMID:29657582

  15. Miniature Extreme Ultraviolet Solar Radiometers

    NASA Astrophysics Data System (ADS)

    McMullin, D. R.; Seely, J. F.; Bremer, J.; Jones, A. R.; Vest, R.; Sakdinawat, A.

    2015-12-01

    Free-standing zone plates for use in EUV solar radiometers have been fabricated using electron beam lithography and calibrated at the NIST SURF synchrotron facility. The radiometers that we are developing use zone plates (ZPs) to focus the total solar irradiance in narrow EUV spectral bands and measure it with negligible sensitivity to field angle and polarization, and with greater accuracy and greater long-term stability than radiometers that have alternative architectures. These radiometers are easy to accommodate on spacecraft due to their small size, low mass, low power requirements, low data rates, and modest pointing requirements. A proto-type instrument will be presented with performance characteristics and spacecraft resource requirements for hosting these new instruments. The compact size of the optical train make these zone plates attractive for small CubeSats. The robustness of the compact design makes these radiometers available for a large variety of applications.

  16. SeaWiFS technical report series. Volume 10: Modeling of the SeaWiFS solar and lunar observations

    NASA Technical Reports Server (NTRS)

    Woodward, Robert H.; Barnes, Robert A.; Mcclain, Charles R.; Esaias, Wayne E.; Barnes, William L.; Mecherikunnel, Ann T.; Hooker, Stanford B. (Editor); Firestone, Elaine R. (Editor)

    1993-01-01

    Post-launch stability monitoring of the Sea-viewing Wide Field-of-view Sensor (SeaWifs) will include periodic sweeps of both an onboard solar diffuser plate and the moon. The diffuser views will provide short-term checks and the lunar views will monitor long-term trends in the instrument's radiometric stability. Models of the expected sensor response to these observations were created on the SeaWiFS computer at the National Aeronautics and Space Administration's (NASA) Goddard Space Flight Center (GSFC) using the Interactive Data Language (IDL) utility with a graphical user interface (GUI). The solar model uses the area of intersecting circles to simulate the ramping of sensor response while viewing the diffuser. This model is compared with preflight laboratory scans of the solar diffuser. The lunar model reads a high-resolution lunar image as input. The observations of the moon are simulated with a bright target recovery algorithm that includes ramping and ringing functions. Tests using the lunar model indicate that the integrated radiance of the entire lunar surface provides a more stable quantity than the mean of radiances from centralized pixels. The lunar model is compared to ground-based scans by the SeaWiFS instrument of a full moon in December 1992. Quality assurance and trend analyses routines for calibration and for telemetry data are also discussed.

  17. Mucin and carbon nanotube-based biosensor for detection of glucose in human plasma.

    PubMed

    Comba, Fausto N; Romero, Marcelo R; Garay, Fernando S; Baruzzi, Ana M

    2018-06-01

    This work reports an amperometric enzyme-electrode prepared with glucose oxidase, which have been immobilized by a cross-linking step with glutaraldehyde in a mixture containing albumin and a novel carbon nanotubes-mucin composite (CNT-muc). The obtained hydrogel matrix was trapped between two polycarbonate membranes and then fixed at the surface of a Pt working electrode. The developed biosensor was optimized by evaluating different compositions and the analytical properties of an enzymatic matrix with CNT-muc. Then, the performance of the resulting enzymatic matrix was evaluated for direct glucose quantification in human blood plasma. The novel CNT-muc composite provided a sensitivity of 0.44 ± 0.01 mA M -1 and a response time of 28 ± 2 s. These values were respectively 20% higher and 40% shorter than those obtained with a sandwich-type biosensor prepared without CNT. Additionally, CNT-muc based biosensor exhibited more than 3 orders of magnitude of linear dynamic calibration range and a detection limit of 3 μM. The short-term and long-term stabilities of the biosensors were also examined and excellent results were obtained through successive experiments performed within the first 60 days from their preparation. Finally, the storage stability was remarkable during the first 300 days. Copyright © 2018 Elsevier Inc. All rights reserved.

  18. Shutterless non-uniformity correction for the long-term stability of an uncooled long-wave infrared camera

    NASA Astrophysics Data System (ADS)

    Liu, Chengwei; Sui, Xiubao; Gu, Guohua; Chen, Qian

    2018-02-01

    For the uncooled long-wave infrared (LWIR) camera, the infrared (IR) irradiation the focal plane array (FPA) receives is a crucial factor that affects the image quality. Ambient temperature fluctuation as well as system power consumption can result in changes of FPA temperature and radiation characteristics inside the IR camera; these will further degrade the imaging performance. In this paper, we present a novel shutterless non-uniformity correction method to compensate for non-uniformity derived from the variation of ambient temperature. Our method combines a calibration-based method and the properties of a scene-based method to obtain correction parameters at different ambient temperature conditions, so that the IR camera performance can be less influenced by ambient temperature fluctuation or system power consumption. The calibration process is carried out in a temperature chamber with slowly changing ambient temperature and a black body as uniform radiation source. Enough uniform images are captured and the gain coefficients are calculated during this period. Then in practical application, the offset parameters are calculated via the least squares method based on the gain coefficients, the captured uniform images and the actual scene. Thus we can get a corrected output through the gain coefficients and offset parameters. The performance of our proposed method is evaluated on realistic IR images and compared with two existing methods. The images we used in experiments are obtained by a 384× 288 pixels uncooled LWIR camera. Results show that our proposed method can adaptively update correction parameters as the actual target scene changes and is more stable to temperature fluctuation than the other two methods.

  19. Long-term dynamic and pseudo-state modeling of complete partial nitrification process at high nitrogen loading rates in a sequential batch reactor (SBR).

    PubMed

    Soliman, Moomen; Eldyasti, Ahmed

    2017-06-01

    Recently, partial nitrification has been adopted widely either for the nitrite shunt process or intermediate nitrite generation step for the Anammox process. However, partial nitrification has been hindered by the complexity of maintaining stable nitrite accumulation at high nitrogen loading rates (NLR) which affect the feasibility of the process for high nitrogen content wastewater. Thus, the operational data of a lab scale SBR performing complete partial nitrification as a first step of nitrite shunt process at NLRs of 0.3-1.2kg/(m 3 d) have been used to calibrate and validate a process model developed using BioWin® in order to describe the long-term dynamic behavior of the SBR. Moreover, an identifiability analysis step has been introduced to the calibration protocol to eliminate the needs of the respirometric analysis for SBR models. The calibrated model was able to predict accurately the daily effluent ammonia, nitrate, nitrite, alkalinity concentrations and pH during all different operational conditions. Copyright © 2017 Elsevier Ltd. All rights reserved.

  20. Monitoring the long term stability of the IRS-P6 AWiFS sensor using the Sonoran and RVPN sites

    NASA Astrophysics Data System (ADS)

    Chander, Gyanesh; Sampath, Aparajithan; Angal, Amit; Choi, Taeyoung; Xiong, Xiaoxiong

    2010-10-01

    This paper focuses on radiometric and geometric assessment of the Indian Remote Sensing (IRS-P6) Advanced Wide Field Sensor (AWiFS) sensor using the Sonoran desert and Railroad Valley Playa, Nevada (RVPN) ground sites. Imageto- Image (I2I) accuracy and relative band-to-band (B2B) accuracy were measured. I2I accuracy of the AWiFS imagery was assessed by measuring the imagery against Landsat Global Land Survey (GLS) 2000. The AWiFS images were typically registered to within one pixel to the GLS 2000 mosaic images. The B2B process used the same concepts as the I2I, except instead of a reference image and a search image; the individual bands of a multispectral image are tested against each other. The B2B results showed that all the AWiFS multispectral bands are registered to sub-pixel accuracy. Using the limited amount of scenes available over these ground sites, the reflective bands of AWiFS sensor indicate a long-term drift in the top-of-atmosphere (TOA) reflectance. Because of the limited availability of AWiFS scenes over these ground sites, a comprehensive evaluation of the radiometric stability using these sites is not possible. In order to overcome this limitation, a cross-comparison between AWiFS and Landsat 7 (L7) Enhanced Thematic Mapper Plus (ETM+) was performed using image statistics based on large common areas observed by the sensors within 30 minutes. Regression curves and coefficients of determination for the TOA trends from these sensors were generated to quantify the uncertainty in these relationships and to provide an assessment of the calibration differences between these sensors.

  1. Evaluation of a photon counting Medipix3RX CZT spectral x-ray detector

    PubMed Central

    Jorgensen, Steven M.; Vercnocke, Andrew J.; Rundle, David S.; Butler, Philip H.; McCollough, Cynthia H.; Ritman, Erik L.

    2016-01-01

    We assessed the performance of a cadmium zinc telluride (CZT)-based Medipix3RX x-ray detector as a candidate for micro-computed tomography (micro-CT) imaging. This technology was developed at CERN for the Large Hadron Collider. It features an array of 128 by 128, 110 micrometer square pixels, each with eight simultaneous threshold counters, five of which utilize real-time charge summing, significantly reducing the charge sharing between contiguous pixels. Pixel response curves were created by imaging a range of x-ray intensities by varying x-ray tube current and by varying the exposure time with fixed x-ray current. Photon energy-related assessments were made by flooding the detector with the tin foil filtered emission of an I-125 radioisotope brachytherapy seed and sweeping the energy threshold of each of the four charge-summed counters of each pixel in 1 keV steps. Long term stability assessments were made by repeating exposures over the course of one hour. The high properly-functioning pixel yield (99%), long term stability (linear regression of whole-chip response over one hour of acquisitions: y = −0.0038x + 2284; standard deviation: 3.7 counts) and energy resolution (2.5 keV FWHM (single pixel), 3.7 keV FWHM across the full image) make this device suitable for spectral micro-CT. The charge summing performance effectively reduced the measurement corruption caused by charge sharing which, when unaccounted for, shifts the photon energy assignment to lower energies, degrading both count and energy accuracy. Effective charge summing greatly improves the potential for calibrated, energy-specific material decomposition and K edge difference imaging approaches. PMID:27795606

  2. Evaluation of a photon counting Medipix3RX CZT spectral x-ray detector.

    PubMed

    Jorgensen, Steven M; Vercnocke, Andrew J; Rundle, David S; Butler, Philip H; McCollough, Cynthia H; Ritman, Erik L

    2016-08-28

    We assessed the performance of a cadmium zinc telluride (CZT)-based Medipix3RX x-ray detector as a candidate for micro-computed tomography (micro-CT) imaging. This technology was developed at CERN for the Large Hadron Collider. It features an array of 128 by 128, 110 micrometer square pixels, each with eight simultaneous threshold counters, five of which utilize real-time charge summing, significantly reducing the charge sharing between contiguous pixels. Pixel response curves were created by imaging a range of x-ray intensities by varying x-ray tube current and by varying the exposure time with fixed x-ray current. Photon energy-related assessments were made by flooding the detector with the tin foil filtered emission of an I-125 radioisotope brachytherapy seed and sweeping the energy threshold of each of the four charge-summed counters of each pixel in 1 keV steps. Long term stability assessments were made by repeating exposures over the course of one hour. The high properly-functioning pixel yield (99%), long term stability (linear regression of whole-chip response over one hour of acquisitions: y = -0.0038x + 2284; standard deviation: 3.7 counts) and energy resolution (2.5 keV FWHM (single pixel), 3.7 keV FWHM across the full image) make this device suitable for spectral micro-CT. The charge summing performance effectively reduced the measurement corruption caused by charge sharing which, when unaccounted for, shifts the photon energy assignment to lower energies, degrading both count and energy accuracy. Effective charge summing greatly improves the potential for calibrated, energy-specific material decomposition and K edge difference imaging approaches.

  3. Long term stability of Oligo (dT) 25 magnetic beads for the expression analysis of Euglena gracilis for long term space projects

    NASA Astrophysics Data System (ADS)

    Becker, Ina; Strauch, Sebastian M.; Hauslage, Jens; Lebert, Michael

    2017-05-01

    The unicellular freshwater flagellate Euglena gracilis has a highly developed sensory system. The cells use different stimuli such as light and gravity to orient themselves in the surrounding medium to find areas for optimal growth. Due to the ability to produce oxygen and consume carbon dioxide, Euglena is a suitable candidate for life support systems. Participation in a long-term space experiment would allow for the analysis of changes and adaptations to the new environment, and this could bring new insights into the mechanism of perception of gravity and the associated signal transduction chain. For a molecular analysis of transcription patterns, an automated system is necessary, capable of performing all steps from taking a sample, processing it and generating data. One of the developmental steps is to find long-term stable reagents and materials and test them for stability at higher-than-recommended temperature conditions during extended storage time. We investigated the usability of magnetic beads in an Euglena specific lysis buffer after addition of the RNA stabilizer Dithiothreitol over 360 days and the lysis buffer with the stabilizer alone over 455 days at the expected storage temperature of 19 °C. We can claim that the stability is not impaired at all after an incubation period of over one year. This might be an interesting result for researchers who have to work under non-standard lab conditions, as in biological or medicinal fieldwork.

  4. A Comprehensive Plan for the Long-Term Calibration and Validation of Oceanic Biogeochemical Satellite Data

    NASA Technical Reports Server (NTRS)

    Hooker, Stanford B.; McClain, Charles R.; Mannino, Antonio

    2007-01-01

    The primary objective of this planning document is to establish a long-term capability and validating oceanic biogeochemical satellite data. It is a pragmatic solution to a practical problem based primarily o the lessons learned from prior satellite missions. All of the plan's elements are seen to be interdependent, so a horizontal organizational scheme is anticipated wherein the overall leadership comes from the NASA Ocean Biology and Biogeochemistry (OBB) Program Manager and the entire enterprise is split into two components of equal sature: calibration and validation plus satellite data processing. The detailed elements of the activity are based on the basic tasks of the two main components plus the current objectives of the Carbon Cycle and Ecosystems Roadmap. The former is distinguished by an internal core set of responsibilities and the latter is facilitated through an external connecting-core ring of competed or contracted activities. The core elements for the calibration and validation component include a) publish protocols and performance metrics; b) verify uncertainty budgets; c) manage the development and evaluation of instrumentation; and d) coordinate international partnerships. The core elements for the satellite data processing component are e) process and reprocess multisensor data; f) acquire, distribute, and archive data products; and g) implement new data products. Both components have shared responsibilities for initializing and temporally monitoring satellite calibration. Connecting-core elements include (but are not restricted to) atmospheric correction and characterization, standards and traceability, instrument and analysis round robins, field campaigns and vicarious calibration sites, in situ database, bio-optical algorithm (and product) validation, satellite characterization and vicarious calibration, and image processing software. The plan also includes an accountability process, creating a Calibration and Validation Team (to help manage the activity), and a discussion of issues associated with the plan's scientific focus.

  5. Amplitude calibration of an acoustic backscattered signal from a bottom-moored ADCP based on long-term measurement series

    NASA Astrophysics Data System (ADS)

    Piotukh, V. B.; Zatsepin, A. G.; Kuklev, S. B.

    2017-05-01

    A possible approach to, and preliminary results of, amplitude calibration of acoustic signals backscattered from an ADCP moored at the bottom of the near-shelf zone of the Black Sea is considered. The aim of this work is to obtain vertical profiles of acoustic scattering signal levels, showing the real characteristics of the volume content of suspended sediments in sea water in units of conventional acoustic turbidity for a given signal frequency. In this case, the assumption about the intervals of maximum acoustic transparency and vertical homogeneity of the marine environment in long-term series of ADCP measurements is used. According to this hypothesis, the intervals of the least values of acoustic backscattered signals are detected, an empirical transfer function of the ADCP reception path is constructed, and it is calibrated. Normalized sets of acoustic backscattered signals relative to a signal from a level of conventionally clear water are obtained. New features in the behavior of vertical profiles of an acoustic echo-signal are revealed due to the calibration. The results of this work will be used in subsequent analysis of the vertical and time variations in suspended sediment content in the near-shelf zone of the Black Sea.

  6. Merged Long-Term Data Sets from TOMS and SBUV Total Ozone Measurements

    NASA Technical Reports Server (NTRS)

    Stolarski, Richard; McPeters, Richard; Labow, Gordon J.; Hollandsworth, Stacey; Flynn, Larry; Einaudi, Franco (Technical Monitor)

    2000-01-01

    Total ozone has been measured by a series of nadir-viewing satellite instruments. These measurements begin with the Total Ozone Mapping Spectrometer (TOMS) and Solar Backscatter UltraViolet (SBUV) instruments on Nimbus 7, launched in late 1978. The measurements have continued with the Meteor 3 TOMS, Earth Probe TOMS, and NOAA 9,11,14 SBUV/2 instruments. The problem for producing a long-term data set is establishing the relative calibration of the various instruments to better than 1%. There was a nearly two year gap between the Meteor 3 TOMS and the Earth Probe TOMS. This gap is filled by the NOAA 9 and 11 SBUV/2 instruments, but they were in drifting orbits that result in effective gaps in the record when the equator crossing time occurs at large solar zenith angle. We have used recently re-derived calibrations of the SBUV instruments using the D-pair (306/313 nm wavelengths) data at the equator. These equatorial D-pair measurements should maintain the internal calibration of each instrument better than previous approaches. We then use the comparisons between instruments during their overlap periods to establish a consistent calibration over the entire data set. The resulting merged ozone data set is independent of the ground-based Dobson/Brewer network.

  7. Effect of desliming of sulphide-rich mill tailings on the long-term strength of cemented paste backfill.

    PubMed

    Ercikdi, Bayram; Baki, Hakan; İzki, Muhammet

    2013-01-30

    This paper presents the effect of desliming on the short- and long-term strength, stability and rheological properties of cemented paste backfill (CPB) produced from two different mill tailings. A 28-day unconfined compressive strength (UCS) of ≥1.0 MPa and the maintenance of stability over 224 days of curing were selected as the design criteria for the evaluation of paste backfill performance. Desliming induced some changes in the physical, chemical, mineralogical and rheological properties of the tailings. CPB mixture of the deslimed tailings achieved the required consistency at a lower water to cement ratio. The short-term UCSs of CPB samples of the deslimed tailings were found to be 30-100% higher than those samples of the reference tailings at all the binder dosages and curing times. CPB samples of the deslimed tailings achieved the long-term stability at relatively low binder dosages (e.g. 5 wt% c.f. ≥6.1% for the reference tailings). It was also estimated that desliming could allow a 13.4-23.1% reduction in the binder consumption depending apparently on the inherent characteristics of the tailings. Over the curing period, generation of sulphate and acid by the oxidation of pyrite present in the tailings was also monitored to correlate with the strength losses observed in the long term. Scanning electron microscope (SEM) and Mercury Intrusion Porosimetry (MIP) analyses provided an insight into the microstructure of CPB and the formation of secondary mineral phases (i.e. gypsum) confirming the beneficial effect of desliming. These findings suggest that desliming can be suitably exploited for CPB of sulphide-rich mill tailings to improve the strength and stability particularly in the long term and to reduce binder consumption. Copyright © 2012 Elsevier Ltd. All rights reserved.

  8. Development of a Hard X-ray Beam Position Monitor for Insertion Device Beams at the APS

    NASA Astrophysics Data System (ADS)

    Decker, Glenn; Rosenbaum, Gerd; Singh, Om

    2006-11-01

    Long-term pointing stability requirements at the Advanced Photon Source (APS) are very stringent, at the level of 500 nanoradians peak-to-peak or better over a one-week time frame. Conventional rf beam position monitors (BPMs) close to the insertion device source points are incapable of assuring this level of stability, owing to mechanical, thermal, and electronic stability limitations. Insertion device gap-dependent systematic errors associated with the present ultraviolet photon beam position monitors similarly limit their ability to control long-term pointing stability. We report on the development of a new BPM design sensitive only to hard x-rays. Early experimental results will be presented.

  9. Basic performance and stability of a CdTe solid-state detector panel.

    PubMed

    Tsuchiya, Katsutoshi; Takahashi, Isao; Kawaguchi, Tsuneaki; Yokoi, Kazuma; Morimoto, Yuuichi; Ishitsu, Takafumi; Suzuki, Atsurou; Ueno, Yuuichirou; Kobashi, Keiji

    2010-05-01

    We have developed a prototype gamma camera system (R1-M) using a cadmium telluride (CdTe) detector panel and evaluated the basic performance and the spectral stability. The CdTe panel consists of 5-mm-thick crystals. The field of view is 134 x 268 mm comprising 18,432 pixels with a pixel pitch of 1.4 mm. Replaceable small CdTe modules are mounted on to the circuit board by dedicated zero insertion force connectors. To make the readout circuit compact, the matrix read out is processed by dedicated ASICs. The panel is equipped with a cold-air cooling system. The temperature and humidity in the panel were kept at 20 degrees C and below 70% relative humidity. CdTe polarization was suppressed by the bias refresh technique to stabilize the detector. We also produced three dedicated square pixel-matched collimators: LEGP (20 mm-thick), LEHR (27 mm-thick), and LEUHR (35 mm-thick). We evaluated their basic performance (energy resolution, system resolution, and sensitivity) and the spectral stability in terms of short-term (several hours of continuous acquisition) and long-term (infrequent measurements over more than a year) activity. The intrinsic energy resolution (FWHM) acquired with Tc-99m (140.5 keV) was 6.6%. The spatial resolutions (FWHM at a distance of 100 mm) with LEGP, LEHR, and LEUHR collimators were 5.7, 4.9, and 4.2 mm, and the sensitivities were 71, 39, and 23 cps/MBq, respectively. The energy peak position and the intrinsic energy resolution after several hours of operation were nearly the same as the values a few minutes after the system was powered on; the variation of the peak position was <0.2%, and that of the resolution was about 0.3%. Infrequent measurements conducted over a year showed that the variations of the energy peak position and the intrinsic energy resolution of the system were at a similar level to those described above. The basic performance of the CdTe-gamma camera system was evaluated, and its stability was verified. It was shown that the camera could be operated daily for several months without calibration.

  10. CW injection locking for long-term stability of frequency combs

    NASA Astrophysics Data System (ADS)

    Williams, Charles; Quinlan, Franklyn; Delfyett, Peter J.

    2009-05-01

    Harmonically mode-locked semiconductor lasers with external ring cavities offer high repetition rate pulse trains while maintaining low optical linewidth via long cavity storage times. Continuous wave (CW) injection locking further reduces linewidth and stabilizes the optical frequencies. The output can be stabilized long-term with the help of a modified Pound-Drever-Hall feedback loop. Optical sidemode suppression of 36 dB has been shown, as well as RF supermode noise suppression of 14 dB for longer than 1 hour. In addition to the injection locking of harmonically mode-locked lasers requiring an external frequency source, recent work shows the viability of the injection locking technique for regeneratively mode-locked lasers, or Coupled Opto-Electronic Oscillators (COEO).

  11. Long-term stability of GOES-8 and -9 attitude control

    NASA Astrophysics Data System (ADS)

    Carr, James L.

    1996-10-01

    An independent audit of the in-orbit behavior of the GOES-8 and GOES-9 satellites has been conducted for the NASA/GSFC. This audit utilized star and landmark observations from the GOES imager to determine long-term histories for spacecraft attitude, orbital position, and instrument internal misalignments. The paper presents results from this audit. Long-term drifts are found in the attitude histories, whereas the misalignment histories are shown to be diurnally stable. The GOES image navigation and registration system is designed to compensate for instrument internal misalignments, and both the diurnally repeatable and drift components of the attitude. Correlations between GOES-8 and GOES-9 long-term roll and pitch drifts implicate the Earth sensor as the origin of these observed drifts. This results clearly demonstrates the enhanced registration stability to be obtained with stellar inertial attitude determination replacing or supplementing Earth sensor control on future GOES missions.

  12. Comparison of nitrous oxide (N2O) analyzers for high-precision measurements of atmospheric mole fractions

    NASA Astrophysics Data System (ADS)

    Lebegue, B.; Schmidt, M.; Ramonet, M.; Wastine, B.; Yver Kwok, C.; Laurent, O.; Belviso, S.; Guemri, A.; Philippon, C.; Smith, J.; Conil, S.; Jost, H. J.; Crosson, E. R.

    2015-10-01

    Over the last few decades, in-situ measurements of atmospheric N2O mole fractions have been performed using gas chromatographs (GCs) equipped with electron capture detectors (ECDs). When trying to meet the World Meteorological Organization's (WMO) quality goal, this technique becomes very challenging as the detectors are highly non-linear and the GCs at remote stations require a considerable amount of maintenance by qualified technicians to maintain good short-term and long-term repeatability. With more robust optical spectrometers being now available for N2O measurements, we aim to identify a robust and stable analyzer that can be integrated into atmospheric monitoring networks, such as the Integrated Carbon Observation System (ICOS). In this study, we tested seven analyzers that were developed and commercialized from five different companies and compared the results with established techniques. Each instrument was characterized during a time period of approximately eight weeks. The test protocols included the characterization of the short-term and long-term repeatability, drift, temperature dependence, linearity and sensitivity to water vapor. During the test period, ambient air measurements were compared under field conditions at the Gif-sur-Yvette station. All of the analyzers showed a standard deviation better than 0.1 ppb for the 10 min averages. Some analyzers would benefit from improvements in temperature stability to reduce the instrument drift, which could then help in reducing the frequency of calibrations. For most instruments, the water vapor correction algorithms applied by companies are not sufficient for high-precision atmospheric measurements, which results in the need to dry the ambient air prior to analysis.

  13. An International Intercomparison of Argon Triple Point Calibration Facilities, Accommodating Long-stem Thermometers

    NASA Astrophysics Data System (ADS)

    Bloembergen, P.; Bonnier, G.; Ronsin, H.

    1990-01-01

    Argon triple point calibration facilities have been compared among eight laboratories with one transfer system, employing local long-stem standard platinum resistance thermometers. The apparatus intercompared, included a sealed cell and its associated cryostat. As is evidenced by the results of long-term investigations, previously performed at the INM, cells of the type employed may show a triple-point temperature, which is stable within the reproducibility of the measurements (simeq0,1 mK) over a period of about 10 years. At each laboratory the mean difference between the Argon triple-point temperature of the transfer cell (t) and the local cell (i) has been determined, using a standard resistance thermometer previously calibrated at the fixed points, according to the IPTS-68; associated repeatabilities are typically of the order of 0,1 mK. The reproducibility attained by measuring the mean difference in different laboratories, using cells of the same type and origin (INM), amounts to 0,4 mK.

  14. Thermal Infrared Radiometric Calibration of the Entire Landsat 4, 5, and 7 Archive (1982-2010)

    NASA Technical Reports Server (NTRS)

    Schott, John R.; Hook, Simon J.; Barsi, Julia A.; Markham, Brian L.; Miller, Jonathan; Padula, Francis P.; Raqueno, Nina G.

    2012-01-01

    Landsat's continuing record of the thermal state of the earth's surface represents the only long term (1982 to the present) global record with spatial scales appropriate for human scale studies (i.e., tens of meters). Temperature drives many of the physical and biological processes that impact the global and local environment. As our knowledge of, and interest in, the role of temperature on these processes have grown, the value of Landsat data to monitor trends and process has also grown. The value of the Landsat thermal data archive will continue to grow as we develop more effective ways to study the long term processes and trends affecting the planet. However, in order to take proper advantage of the thermal data, we need to be able to convert the data to surface temperatures. A critical step in this process is to have the entire archive completely and consistently calibrated into absolute radiance so that it can be atmospherically compensated to surface leaving radiance and then to surface radiometric temperature. This paper addresses the methods and procedures that have been used to perform the radiometric calibration of the earliest sizable thermal data set in the archive (Landsat 4 data). The completion of this effort along with the updated calibration of the earlier (1985 1999) Landsat 5 data, also reported here, concludes a comprehensive calibration of the Landsat thermal archive of data from 1982 to the present

  15. Evolution of the Southern Oscillation as observed by the Nimbus-7 ERB experiment

    NASA Technical Reports Server (NTRS)

    Ardanuy, Philip E.; Kyle, H. Lee; Chang, Hyo-Duck

    1987-01-01

    The Nimbus-7 satellite has been in a 955-km, sun-synchronous orbit since October 1978. The Earth Radiation Budget (ERB) experiment has taken approximately 8 years of high-quality data during this time, of which seven complete years have been archived at the National Space Science Data Center. A final reprocessing of the wide-field-of-view channel dataset is underway. Error analyses indicate a long-term stability of 1 percent better over the length of the data record. As part of the validation of the ERB measurements, the archived 7-year Nimbus-7 ERB dataset is examined for the presence and accuracy of interannual variations including the Southern Oscillation signal. Zonal averages of broadband outgoing longwave radiation indicate a terrestrial response of more than 2 years to the oceanic and atmospheric manifestations of the 1982-83 El Nino/Southern Oscillation (ENSO) event, especially in the tropics. This signal is present in monthly and seasonal averages and is shown here to derive primarily from atmospheric responses to adjustments in the Pacific Ocean. The calibration stability of this dataset thus provides a powerful new tool to examine the physics of the ENSO phenomena.

  16. High-Resolution Spectroscopy at the Wyoming Infrared Observatory: Setting TESS Science on FHiRE

    NASA Astrophysics Data System (ADS)

    Jang-Condell, Hannah; Pierce, Michael J.; Pilachowski, C. A.; Kobulnicky, Henry; McLane, Jacob N.

    2018-01-01

    The Fiber High Resolution Echelle (FHiRE) spectrograph is a new instrument designed for the 2.3-m Wyoming InfraRed Observatory (WIRO). With the construction of a vacuum chamber for FHiRE to stabilize the spectrograph and a temperature-stabilized Thorium-Argon lamp for precise velocity calibration, we will be able to achieve 1 m/s RV precision, making it an ideal instrument for finding exoplanets. Details of the design of FHiRE are presented in a companion poster (Pierce et al.). The construction of this instrument is well-timed with the planned 2018 launch of NASA's Transiting Exoplanet Survey Satellite (TESS) mission. TESS will require a great deal of follow-up spectroscopy to characterize potential exoplanet host stars as well as radial velocity measurements to confirm new exoplanets. WIRO is ideally suited to acquire the long-term, high-cadence observations that will be required to make progress in this frontier area of astrophysics. We will coordinate our efforts with the TESS Follow-up Observing Program (TFOP), specifically as part of the Recon Spectroscopy and Precise Radial Velocity Work sub-groups.This work is supported by a grant from NASA EPSCOR.

  17. Effectiveness of Career Counseling: A One-Year Follow-Up

    ERIC Educational Resources Information Center

    Perdrix, Sophie; Stauffer, Sarah; Masdonati, Jonas; Massoudi, Koorosh; Rossier, Jerome

    2012-01-01

    The short-term effectiveness of career counseling is well supported in the literature. However, the long-term impact is often overlooked. This study quantitatively investigated the long-term stability of the positive effects gained through the career counseling process and qualitatively observed participants' levels of career project…

  18. Where Is the “Optimal” Fontan Hemodynamics?

    PubMed Central

    2017-01-01

    Fontan circulation is generally characterized by high central venous pressure, low cardiac output, and slightly low arterial oxygen saturation, and it is quite different from normal biventricular physiology. Therefore, when a patient with congenital heart disease is selected as a candidate for this type of circulation, the ultimate goals of therapy consist of 2 components. One is a smooth adjustment to the new circulation, and the other is long-term circulatory stabilization after adjustment. When either of these goals is not achieved, the patient is categorized as having “failed” Fontan circulation, and the prognosis is dismal. For the first goal of smooth adjustment, a lot of effort has been made to establish criteria for patient selection and intensive management immediately after the Fontan operation. For the second goal of long-term circulatory stabilization, there is limited evidence of successful strategies for long-term hemodynamic stabilization. Furthermore, there have been no data on optimal hemodynamics in Fontan circulation that could be used as a reference for patient management. Although small clinical trials and case reports are available, the results cannot be generalized to the majority of Fontan survivors. We recently reported the clinical and hemodynamic characteristics of early and late failing Fontan survivors and their association with all-cause mortality. This knowledge could provide insight into the complex Fontan pathophysiology and might help establish a management strategy for long-term hemodynamic stabilization. PMID:29035429

  19. Optical frequency locked loop for long-term stabilization of broad-line DFB laser frequency difference

    NASA Astrophysics Data System (ADS)

    Lipka, Michał; Parniak, Michał; Wasilewski, Wojciech

    2017-09-01

    We present an experimental realization of the optical frequency locked loop applied to long-term frequency difference stabilization of broad-line DFB lasers along with a new independent method to characterize relative phase fluctuations of two lasers. The presented design is based on a fast photodiode matched with an integrated phase-frequency detector chip. The locking setup is digitally tunable in real time, insensitive to environmental perturbations and compatible with commercially available laser current control modules. We present a simple model and a quick method to optimize the loop for a given hardware relying exclusively on simple measurements in time domain. Step response of the system as well as phase characteristics closely agree with the theoretical model. Finally, frequency stabilization for offsets within 4-15 GHz working range achieving <0.1 Hz long-term stability of the beat note frequency for 500 s averaging time period is demonstrated. For these measurements we employ an I/Q mixer that allows us to precisely and independently measure the full phase trace of the beat note signal.

  20. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lill, R.; Sereno, N.; Yang, B.

    The Advanced Photon Source (APS) is currently in the preliminary design phase for the multi-bend achromat (MBA) lattice upgrade. Beam stability is critical for the MBA and will require long term drift defined as beam mo-tion over a seven-day timescale to be no more than 1 mi-cron at the insertion device locations and beam angle change no more than 0.25 micro-radian. Mechanical stabil-ity of beam position monitor (BPM) pickup electrodes mounted on insertion device vacuum chambers place a fun-damental limitation on long-term beam stability for inser-tion device beamlines. We present the design and imple-mentation of prototype mechanical motion system (MMS)more » instrumentation for quantifying this type of motion specif-ically in the APS accelerator tunnel and experiment hall floor under normal operating conditions. The MMS pres-ently provides critical position information on the vacuum chamber and BPM support systems. Initial results of the R&D prototype systems have demonstrated that the cham-ber movements far exceed the long-term drift tolerance specified for the APS Upgrade MBA storage ring.« less

  1. Landsat 8 OLI radiometric calibration performance after three years (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Morfitt, Ron A.

    2016-09-01

    The Landsat 8 Operational Land Imager (OLI) impressed science users soon after launch in early 2013 with both its radiometric and geometric performance. After three years on-orbit, OLI continues to exceed expectations with its high signal-to-noise ratio, low striping, and stable response. The few artifacts that do exist, such as ghosting, continue to be minimal and show no signs of increasing. The on-board calibration sources showed a small decrease in response during the first six months of operations in the coastal aerosol band, but that decrease has stabilized to less than a half percent per year since that time. The other eight bands exhibit very little change over the past three years and have remained well within a half percent of their initial response to all on-board calibration sources. Analysis of lunar acquisitions also agree with the on-board calibrators. Overall, the OLI on-board the Landsat 8 spacecraft continues to provide exceptional measurements of the Earth's surface to continue the long tradition of Landsat.

  2. Performance assessment of FY-3C/MERSI on early orbit

    NASA Astrophysics Data System (ADS)

    Hu, Xiuqing; Xu, Na; Wu, Ronghua; Chen, Lin; Min, Min; Wang, Ling; Xu, Hanlie; Sun, Ling; Yang, Zhongdong; Zhang, Peng

    2014-11-01

    FY-3C/MERSI has some remarkable improvements compared to the previous MERSIs including better spectral response function (SRF) consistency of different detectors within one band, increasing the capability of lunar observation by space view (SV) and the improvement of radiometric response stability of solar bands. During the In-orbit verification (IOV) commissioning phase, early results that indicate the MERSI representative performance were derived, including the signal noise ratio (SNR), dynamic range, MTF, B2B registration, calibration bias and instrument stability. The SNRs at the solar bands (Bands 1-4 and 6-20) was largely beyond the specifications except for two NIR bands. The in-flight calibration and verification for these bands are also heavily relied on the vicarious techniques such as China radiometric calibration sites(CRCS), cross-calibration, lunar calibration, DCC calibration, stability monitoring using Pseudo Invariant Calibration Sites (PICS) and multi-site radiance simulation. This paper will give the results of the above several calibration methods and monitoring the instrument degradation in early on-orbit time.

  3. Homogenization of long instrumental temperature and precipitation series over the Spanish Northern Coast

    NASA Astrophysics Data System (ADS)

    Sigro, J.; Brunet, M.; Aguilar, E.; Stoll, H.; Jimenez, M.

    2009-04-01

    The Spanish-funded research project Rapid Climate Changes in the Iberian Peninsula (IP) Based on Proxy Calibration, Long Term Instrumental Series and High Resolution Analyses of Terrestrial and Marine Records (CALIBRE: ref. CGL2006-13327-C04/CLI) has as main objective to analyse climate dynamics during periods of rapid climate change by means of developing high-resolution paleoclimate proxy records from marine and terrestrial (lakes and caves) deposits over the IP and calibrating them with long-term and high-quality instrumental climate time series. Under CALIBRE, the coordinated project Developing and Enhancing a Climate Instrumental Dataset for Calibrating Climate Proxy Data and Analysing Low-Frequency Climate Variability over the Iberian Peninsula (CLICAL: CGL2006-13327-C04-03/CLI) is devoted to the development of homogenised climate records and sub-regional time series which can be confidently used in the calibration of the lacustrine, marine and speleothem time series generated under CALIBRE. Here we present the procedures followed in order to homogenise a dataset of maximum and minimum temperature and precipitation data on a monthly basis over the Spanish northern coast. The dataset is composed of thirty (twenty) precipitation (temperature) long monthly records. The data are quality controlled following the procedures recommended by Aguilar et al. (2003) and tested for homogeneity and adjusted by following the approach adopted by Brunet et al. (2008). Sub-regional time series of precipitation, maximum and minimum temperatures for the period 1853-2007 have been generated by averaging monthly anomalies and then adding back the base-period mean, according to the method of Jones and Hulme (1996). Also, a method to adjust the variance bias present in regional time series associated over time with varying sample size has been applied (Osborn et al., 1997). The results of this homogenisation exercise and the development of the associated sub-regional time series will be widely discussed. Initial comparisons with rapidly growing speleothems in two different caves indicate that speleothem trace element ratios like Ba/Ca are recording the decrease in littoral precipitation in the last several decades. References Aguilar, E., Auer, I., Brunet, M., Peterson, T. C. and Weringa, J. 2003. Guidelines on Climate Metadata and Homogenization, World Meteorological Organization (WMO)-TD no. 1186 / World Climate Data and Monitoring Program (WCDMP) no. 53, Geneva: 51 pp. Brunet M, Saladié O, Jones P, Sigró J, Aguilar E, Moberg A, Lister D, Walther A, Almarza C. 2008. A case-study/guidance on the development of long-term daily adjusted temperature datasets, WMO-TD-1425/WCDMP-66, Geneva: 43 pp. Jones, P D, and Hulme M, 1996, Calculating regional climatic time series for temperature and precipitation: Methods and illustrations, Int. J. Climatol., 16, 361- 377. Osborn, T. J., Briffa K. R., and Jones P. D., 1997, Adjusting variance for sample-size in tree-ring chronologies and other regional mean time series, Dendrochronologia, 15, 89- 99.

  4. Long-Term Stability of the SGA-WZ Strapdown Airborne Gravimeter

    PubMed Central

    Cai, Shaokun; Zhang, Kaidong; Wu, Meiping; Huang, Yangming

    2012-01-01

    Accelerometers are one of the most important sensors in a strapdown airborne gravimeter. The accelerometer's drift determines the long-term accuracy of the strapdown inertial navigation system (SINS), which is the primary and most critical component of the strapdown airborne gravimeter. A long-term stability test lasting 104 days was conducted to determine the characteristics of the strapdown airborne gravimeter's long-term drift. This stability test was based on the first set of strapdown airborne gravimeters built in China, the SGA-WZ. The test results reveal a quadratic drift in the strapdown airborne gravimeter data. A drift model was developed using the static data in the two end sections, and then this model was used to correct the test data. After compensating for the drift, the drift effect improved from 70 mGal to 3.46 mGal with a standard deviation of 0.63 mGal. The quadratic curve better reflects the drift's real characteristics. In comparison with other methodologies, modelling the drift as a quadratic curve was shown to be more appropriate. Furthermore, this method allows the drift to be adjusted throughout the course of the entire campaign. PMID:23112647

  5. Landsat-7 ETM+ On-Orbit Reflective-Band Radiometric Stability and Absolute Calibration

    NASA Technical Reports Server (NTRS)

    Markham, Brian L.; Thome, Kurtis J.; Barsi, Julia A.; Kaita, Ed; Helder, Dennis L.; Barker, John L.

    2003-01-01

    The Landsat-7 spacecraft carries the Enhanced Thematic Mapper Plus (ETM+) instrument. This instrument images the Earth land surface in eight parts of the electromagnetic spectrum, termed spectral bands. These spectral images are used to monitor changes in the land surface, so a consistent relationship, i.e., calibration, between the image data and the Earth surface brightness, is required. The ETM+ has several on- board calibration devices that are used to monitor this calibration. The best on-board calibration source employs a flat white painted reference panel and has indicated changes of between 0.5% to 2% per year in the ETM+ response, depending on the spectral band. However, most of these changes are believed to be caused by changes in the reference panel, as opposed to changes in the instrument's sensitivity. This belief is based partially on on-orbit calibrations using instrumented ground sites and observations of "invariant sites", hyper-arid sites of the Sahara and Arabia. Changes determined from these data sets indicate are 0.1% - 0.6% per year. Tests and comparisons to other sensors also indicate that the uncertainty of the calibration is at the 5% level.

  6. Use of Naturally Available Reference Targets to Calibrate Airborne Laser Scanning Intensity Data

    PubMed Central

    Vain, Ants; Kaasalainen, Sanna; Pyysalo, Ulla; Krooks, Anssi; Litkey, Paula

    2009-01-01

    We have studied the possibility of calibrating airborne laser scanning (ALS) intensity data, using land targets typically available in urban areas. For this purpose, a test area around Espoonlahti Harbor, Espoo, Finland, for which a long time series of ALS campaigns is available, was selected. Different target samples (beach sand, concrete, asphalt, different types of gravel) were collected and measured in the laboratory. Using tarps, which have certain backscattering properties, the natural samples were calibrated and studied, taking into account the atmospheric effect, incidence angle and flying height. Using data from different flights and altitudes, a time series for the natural samples was generated. Studying the stability of the samples, we could obtain information on the most ideal types of natural targets for ALS radiometric calibration. Using the selected natural samples as reference, the ALS points of typical land targets were calibrated again and examined. Results showed the need for more accurate ground reference data, before using natural samples in ALS intensity data calibration. Also, the NIR camera-based field system was used for collecting ground reference data. This system proved to be a good means for collecting in situ reference data, especially for targets with inhomogeneous surface reflection properties. PMID:22574045

  7. A model based on Rock-Eval thermal analysis to quantify the size of the centennially persistent organic carbon pool in temperate soils

    NASA Astrophysics Data System (ADS)

    Cécillon, Lauric; Baudin, François; Chenu, Claire; Houot, Sabine; Jolivet, Romain; Kätterer, Thomas; Lutfalla, Suzanne; Macdonald, Andy; van Oort, Folkert; Plante, Alain F.; Savignac, Florence; Soucémarianadin, Laure N.; Barré, Pierre

    2018-05-01

    Changes in global soil carbon stocks have considerable potential to influence the course of future climate change. However, a portion of soil organic carbon (SOC) has a very long residence time ( > 100 years) and may not contribute significantly to terrestrial greenhouse gas emissions during the next century. The size of this persistent SOC reservoir is presumed to be large. Consequently, it is a key parameter required for the initialization of SOC dynamics in ecosystem and Earth system models, but there is considerable uncertainty in the methods used to quantify it. Thermal analysis methods provide cost-effective information on SOC thermal stability that has been shown to be qualitatively related to SOC biogeochemical stability. The objective of this work was to build the first quantitative model of the size of the centennially persistent SOC pool based on thermal analysis. We used a unique set of 118 archived soil samples from four agronomic experiments in northwestern Europe with long-term bare fallow and non-bare fallow treatments (e.g., manure amendment, cropland and grassland) as a sample set for which estimating the size of the centennially persistent SOC pool is relatively straightforward. At each experimental site, we estimated the average concentration of centennially persistent SOC and its uncertainty by applying a Bayesian curve-fitting method to the observed declining SOC concentration over the duration of the long-term bare fallow treatment. Overall, the estimated concentrations of centennially persistent SOC ranged from 5 to 11 g C kg-1 of soil (lowest and highest boundaries of four 95 % confidence intervals). Then, by dividing the site-specific concentrations of persistent SOC by the total SOC concentration, we could estimate the proportion of centennially persistent SOC in the 118 archived soil samples and the associated uncertainty. The proportion of centennially persistent SOC ranged from 0.14 (standard deviation of 0.01) to 1 (standard deviation of 0.15). Samples were subjected to thermal analysis by Rock-Eval 6 that generated a series of 30 parameters reflecting their SOC thermal stability and bulk chemistry. We trained a nonparametric machine-learning algorithm (random forests multivariate regression model) to predict the proportion of centennially persistent SOC in new soils using Rock-Eval 6 thermal parameters as predictors. We evaluated the model predictive performance with two different strategies. We first used a calibration set (n = 88) and a validation set (n = 30) with soils from all sites. Second, to test the sensitivity of the model to pedoclimate, we built a calibration set with soil samples from three out of the four sites (n = 84). The multivariate regression model accurately predicted the proportion of centennially persistent SOC in the validation set composed of soils from all sites (R2 = 0.92, RMSEP = 0.07, n = 30). The uncertainty of the model predictions was quantified by a Monte Carlo approach that produced conservative 95 % prediction intervals across the validation set. The predictive performance of the model decreased when predicting the proportion of centennially persistent SOC in soils from one fully independent site with a different pedoclimate, yet the mean error of prediction only slightly increased (R2 = 0.53, RMSEP = 0.10, n = 34). This model based on Rock-Eval 6 thermal analysis can thus be used to predict the proportion of centennially persistent SOC with known uncertainty in new soil samples from different pedoclimates, at least for sites that have similar Rock-Eval 6 thermal characteristics to those included in the calibration set. Our study reinforces the evidence that there is a link between the thermal and biogeochemical stability of soil organic matter and demonstrates that Rock-Eval 6 thermal analysis can be used to quantify the size of the centennially persistent organic carbon pool in temperate soils.

  8. Direct Left Atrial Pressure Monitoring in Severe Heart Failure: Long-Term Sensor Performance

    PubMed Central

    Ritzema, Jay; Eigler, Neal L.; Melton, Iain C.; Krum, Henry; Adamson, Philip B.; Kar, Saibal; Shah, Prediman K.; Whiting, James S.; Heywood, J. Thomas; Rosero, Spencer; Singh, Jagmeet P.; Saxon, Leslie; Matthews, Ray; Crozier, Ian G.; Abraham, William T.

    2010-01-01

    We report the stability, accuracy, and development history of a new left atrial pressure (LAP) sensing system in ambulatory heart failure (HF) patients. A total of 84 patients with advanced HF underwent percutaneous transseptal implantation of the pressure sensor. Quarterly noninvasive calibration by modified Valsalva maneuver was achieved in all patients, and 96.5% of calibration sessions were successful with a reproducibility of 1.2 mmHg. Absolute sensor drift was maximal after 3 months at 4.7 mmHg (95% CI, 3.2–6.2 mmHg) and remained stable through 48 months. LAP was highly correlated with simultaneous pulmonary wedge pressure at 3 and 12 months (r = 0.98, average difference of 0.8 ± 4.0 mmHg). Freedom from device failure was 95% (n = 37) at 2 years and 88% (n = 12) at 4 years. Causes of failure were identified and mitigated with 100% freedom from device failure and less severe anomalies in the last 41 consecutive patients (p = 0.005). Accurate and reliable LAP measurement using a chronic implanted monitoring system is safe and feasible in patients with advanced heart failure. PMID:20945124

  9. Frequency standard stability for Doppler measurements on-board the shuttle

    NASA Technical Reports Server (NTRS)

    Harton, P. L.

    1974-01-01

    The short and long term stability characteristics of crystal and atomic standards are described. Emphasis is placed on crystal oscillators because of the selection which was made for the shuttle baseline and the complexities which are introduced by the shuttle environment. Attention is given, first, to the definitions of stability and the application of these definitions to the shuttle system and its mission. Data from time domain measurements are used to illustrate the definitions. Results of a literature survey to determine environmental effects on frequency reference sources are then presented. Finally, methods of standard frequency dissemination over radio frequency carriers are noted as a possible means of measuring absolute accuracy and long term stability characteristics during on one way Doppler equipment.

  10. Spectrally narrow, long-term stable optical frequency reference based on a Eu3+:Y2SiO5 crystal at cryogenic temperature.

    PubMed

    Chen, Qun-Feng; Troshyn, Andrei; Ernsting, Ingo; Kayser, Steffen; Vasilyev, Sergey; Nevsky, Alexander; Schiller, Stephan

    2011-11-25

    Using an ultrastable continuous-wave laser at 580 nm we performed spectral hole burning of Eu(3+):Y(2)SiO(5) at a very high spectral resolution. The essential parameters determining the usefulness as a macroscopic frequency reference, linewidth, temperature sensitivity, and long-term stability, were characterized using a H-maser stabilized frequency comb. Spectral holes with a linewidth as low as 6 kHz were observed and the upper limit of the drift of the hole frequency was determined to be 5±3 mHz/s. We discuss the necessary requirements for achieving ultrahigh stability in laser frequency stabilization to these spectral holes.

  11. Explaining Variance in Long-Term Recall in 3- and 4-Year-Old Children: The Importance of Post-Encoding Processes

    ERIC Educational Resources Information Center

    Bauer, Patricia J.; Larkina, Marina; Doydum, Ayzit O.

    2012-01-01

    Long-term recall is influenced by what originally was encoded as well as by the efficacy of retrieval processes. The possible explanatory role of post-encoding processes by which initially labile memory traces are stabilized and integrated into long-term memory (i.e., consolidated) has received relatively less research attention. In the current…

  12. Stabilization of dynamics of oscillatory systems by nonautonomous perturbation.

    PubMed

    Lucas, Maxime; Newman, Julian; Stefanovska, Aneta

    2018-04-01

    Synchronization and stability under periodic oscillatory driving are well understood, but little is known about the effects of aperiodic driving, despite its abundance in nature. Here, we consider oscillators subject to driving with slowly varying frequency, and investigate both short-term and long-term stability properties. For a phase oscillator, we find that, counterintuitively, such variation is guaranteed to enlarge the Arnold tongue in parameter space. Using analytical and numerical methods that provide information on time-variable dynamical properties, we find that the growth of the Arnold tongue is specifically due to the growth of a region of intermittent synchronization where trajectories alternate between short-term stability and short-term neutral stability, giving rise to stability on average. We also present examples of higher-dimensional nonlinear oscillators where a similar stabilization phenomenon is numerically observed. Our findings help support the case that in general, deterministic nonautonomous perturbation is a very good candidate for stabilizing complex dynamics.

  13. Stabilization of dynamics of oscillatory systems by nonautonomous perturbation

    NASA Astrophysics Data System (ADS)

    Lucas, Maxime; Newman, Julian; Stefanovska, Aneta

    2018-04-01

    Synchronization and stability under periodic oscillatory driving are well understood, but little is known about the effects of aperiodic driving, despite its abundance in nature. Here, we consider oscillators subject to driving with slowly varying frequency, and investigate both short-term and long-term stability properties. For a phase oscillator, we find that, counterintuitively, such variation is guaranteed to enlarge the Arnold tongue in parameter space. Using analytical and numerical methods that provide information on time-variable dynamical properties, we find that the growth of the Arnold tongue is specifically due to the growth of a region of intermittent synchronization where trajectories alternate between short-term stability and short-term neutral stability, giving rise to stability on average. We also present examples of higher-dimensional nonlinear oscillators where a similar stabilization phenomenon is numerically observed. Our findings help support the case that in general, deterministic nonautonomous perturbation is a very good candidate for stabilizing complex dynamics.

  14. SU-E-T-223: Computed Radiography Dose Measurements of External Radiotherapy Beams

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Aberle, C; Kapsch, R

    2015-06-15

    Purpose: To obtain quantitative, two-dimensional dose measurements of external radiotherapy beams with a computed radiography (CR) system and to derive volume correction factors for ionization chambers in small fields. Methods: A commercial Kodak ACR2000i CR system with Kodak Flexible Phosphor Screen HR storage foils was used. Suitable measurement conditions and procedures were established. Several corrections were derived, including image fading, length-scale corrections and long-term stability corrections. Dose calibration curves were obtained for cobalt, 4 MV, 8 MV and 25 MV photons, and for 10 MeV, 15 MeV and 18 MeV electrons in a water phantom. Inherent measurement inhomogeneities were studiedmore » as well as directional dependence of the response. Finally, 2D scans with ionization chambers were directly compared to CR measurements, and volume correction factors were derived. Results: Dose calibration curves (0.01 Gy to 7 Gy) were obtained for multiple photon and electron beam qualities. For each beam quality, the calibration curves can be described by a single fit equation over the whole dose range. The energy dependence of the dose response was determined. The length scale on the images was adjusted scan-by-scan, typically by 2 percent horizontally and by 3 percent vertically. The remaining inhomogeneities after the system’s standard calibration procedure were corrected for. After correction, the homogeneity is on the order of a few percent. The storage foils can be rotated by up to 30 degrees without a significant effect on the measured signal. First results on the determination of volume correction factors were obtained. Conclusion: With CR, quantitative, two-dimensional dose measurements with a high spatial resolution (sub-mm) can be obtained over a large dose range. In order to make use of these advantages, several calibrations, corrections and supporting measurements are needed. This work was funded by the European Metrology Research Programme (EMRP) project HLT09 MetrExtRT Metrology for Radiotherapy using Complex Radiation Fields.« less

  15. A HIGH-PRECISION NEAR-INFRARED SURVEY FOR RADIAL VELOCITY VARIABLE LOW-MASS STARS USING CSHELL AND A METHANE GAS CELL

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gagné, Jonathan; Plavchan, Peter; Gao, Peter

    2016-05-01

    We present the results of a precise near-infrared (NIR) radial velocity (RV) survey of 32 low-mass stars with spectral types K2–M4 using CSHELL at the NASA InfraRed Telescope Facility in the K band with an isotopologue methane gas cell to achieve wavelength calibration and a novel, iterative RV extraction method. We surveyed 14 members of young (≈25–150 Myr) moving groups, the young field star ε Eridani, and 18 nearby (<25 pc) low-mass stars and achieved typical single-measurement precisions of 8–15 m s{sup −1}with a long-term stability of 15–50 m s{sup −1} over longer baselines. We obtain the best NIR RVmore » constraints to date on 27 targets in our sample, 19 of which were never followed by high-precision RV surveys. Our results indicate that very active stars can display long-term RV variations as low as ∼25–50 m s{sup −1} at ≈2.3125 μ m, thus constraining the effect of jitter at these wavelengths. We provide the first multiwavelength confirmation of GJ 876 bc and independently retrieve orbital parameters consistent with previous studies. We recovered RV variabilities for HD 160934 AB and GJ 725 AB that are consistent with their known binary orbits, and nine other targets are candidate RV variables with a statistical significance of 3 σ –5 σ . Our method, combined with the new iSHELL spectrograph, will yield long-term RV precisions of ≲5 m s{sup −1} in the NIR, which will allow the detection of super-Earths near the habitable zone of mid-M dwarfs.« less

  16. Long term stability of Oligo (dT) 25 magnetic beads for the expression analysis of Euglena gracilis for long term space projects.

    PubMed

    Becker, Ina; Strauch, Sebastian M; Hauslage, Jens; Lebert, Michael

    2017-05-01

    The unicellular freshwater flagellate Euglena gracilis has a highly developed sensory system. The cells use different stimuli such as light and gravity to orient themselves in the surrounding medium to find areas for optimal growth. Due to the ability to produce oxygen and consume carbon dioxide, Euglena is a suitable candidate for life support systems. Participation in a long-term space experiment would allow for the analysis of changes and adaptations to the new environment, and this could bring new insights into the mechanism of perception of gravity and the associated signal transduction chain. For a molecular analysis of transcription patterns, an automated system is necessary, capable of performing all steps from taking a sample, processing it and generating data. One of the developmental steps is to find long-term stable reagents and materials and test them for stability at higher-than-recommended temperature conditions during extended storage time. We investigated the usability of magnetic beads in an Euglena specific lysis buffer after addition of the RNA stabilizer Dithiothreitol over 360 days and the lysis buffer with the stabilizer alone over 455 days at the expected storage temperature of 19 °C. We can claim that the stability is not impaired at all after an incubation period of over one year. This might be an interesting result for researchers who have to work under non-standard lab conditions, as in biological or medicinal fieldwork. Copyright © 2017 The Committee on Space Research (COSPAR). Published by Elsevier Ltd. All rights reserved.

  17. Stability analysis for a multi-camera photogrammetric system.

    PubMed

    Habib, Ayman; Detchev, Ivan; Kwak, Eunju

    2014-08-18

    Consumer-grade digital cameras suffer from geometrical instability that may cause problems when used in photogrammetric applications. This paper provides a comprehensive review of this issue of interior orientation parameter variation over time, it explains the common ways used for coping with the issue, and describes the existing methods for performing stability analysis for a single camera. The paper then points out the lack of coverage of stability analysis for multi-camera systems, suggests a modification of the collinearity model to be used for the calibration of an entire photogrammetric system, and proposes three methods for system stability analysis. The proposed methods explore the impact of the changes in interior orientation and relative orientation/mounting parameters on the reconstruction process. Rather than relying on ground truth in real datasets to check the system calibration stability, the proposed methods are simulation-based. Experiment results are shown, where a multi-camera photogrammetric system was calibrated three times, and stability analysis was performed on the system calibration parameters from the three sessions. The proposed simulation-based methods provided results that were compatible with a real-data based approach for evaluating the impact of changes in the system calibration parameters on the three-dimensional reconstruction.

  18. Stability Analysis for a Multi-Camera Photogrammetric System

    PubMed Central

    Habib, Ayman; Detchev, Ivan; Kwak, Eunju

    2014-01-01

    Consumer-grade digital cameras suffer from geometrical instability that may cause problems when used in photogrammetric applications. This paper provides a comprehensive review of this issue of interior orientation parameter variation over time, it explains the common ways used for coping with the issue, and describes the existing methods for performing stability analysis for a single camera. The paper then points out the lack of coverage of stability analysis for multi-camera systems, suggests a modification of the collinearity model to be used for the calibration of an entire photogrammetric system, and proposes three methods for system stability analysis. The proposed methods explore the impact of the changes in interior orientation and relative orientation/mounting parameters on the reconstruction process. Rather than relying on ground truth in real datasets to check the system calibration stability, the proposed methods are simulation-based. Experiment results are shown, where a multi-camera photogrammetric system was calibrated three times, and stability analysis was performed on the system calibration parameters from the three sessions. The proposed simulation-based methods provided results that were compatible with a real-data based approach for evaluating the impact of changes in the system calibration parameters on the three-dimensional reconstruction. PMID:25196012

  19. Geocoronal hydrogen studies using Fabry Perot interferometers, part 2: Long-term observations

    NASA Astrophysics Data System (ADS)

    Nossal, S. M.; Mierkiewicz, E. J.; Roesler, F. L.; Reynolds, R. J.; Haffner, L. M.

    2006-09-01

    Long-term data sets are required to investigate sources of natural variability in the upper atmosphere. Understanding the influence of sources of natural variability such as the solar cycle is needed to characterize the thermosphere + exosphere, to understand coupling processes between atmospheric regions, and to isolate signatures of natural variability from those due to human-caused change. Multi-year comparisons of thermospheric + exospheric Balmer α emissions require cross-calibrated and well-understood instrumentation, a stable calibration source, reproducible observing conditions, separation of the terrestrial from the Galactic emission line, and consistent data analysis accounting for differences in viewing geometry. We discuss how we address these criteria in the acquisition and analysis of a mid-latitude geocoronal Balmer α column emission data set now spanning two solar cycles and taken mainly from Wisconsin and Kitt Peak, Arizona. We also discuss results and outstanding challenges for increasing the accuracy and use of these observations.

  20. Application of DSSAT-CROPGRO-Cotton Model to Assess Long Term (1924-2012) Cotton Yield under Different Irrigation Management Strategies

    NASA Astrophysics Data System (ADS)

    Adhikari, P.; Gowda, P. H.; Northup, B. K.; Rocateli, A.

    2017-12-01

    In this study a well calibrated and validated DSSAT-CROPGRO-Cotton model was used for assessing the irrigation management in the Texas High Plains (THP). Long term (1924-2012) historic lint yield were simulated under different irrigation management practices which were commonly used in the THP. The simulation treatments includes different amount of irrigation water high (H; 6.4 mm d-1), medium (M; 3.2 mm d-1) and low (L; 0 mm d-1) during emergence (S1), vegetative (S2) and maturity (S3) stage. The combination of these treatments resulted into 27 treatments. The amount and date of irrigation for each stage were obtained from the recent cotton irrigation experiment at Halfway, TX (Brodovsky, et al., 2015). Similarly, calibrated model was also used to observe the effect of plantation date on crop yield in the THP regions.

  1. Long-term stability of crystal-stabilized water-in-oil emulsions.

    PubMed

    Ghosh, Supratim; Pradhan, Mamata; Patel, Tejas; Haj-Shafiei, Samira; Rousseau, Dérick

    2015-12-15

    The impact of cooling rate and mixing on the long-term kinetic stability of wax-stabilized water-in-oil emulsions was investigated. Four cooling/mixing protocols were investigated: cooling from 45°C to either 25°C or 4°C with/without stirring and two cooling rates - slow (1°C/min) and fast (5°C/min). The sedimentation behaviour of the emulsions was significantly affected by cooling protocol. Stirring was critical to the stability of all emulsions, with statically-cooled (no stirring) emulsions suffering from extensive aqueous phase separation. Emulsions stirred while cooling showed sedimentation of a waxy emulsion layer leaving a clear oil layer at the top, with a smaller separation and droplet size distribution at 4°C compared to 25°C, indicating the importance of the amount of crystallized wax on emulsion stability. Light microscopy revealed that crystallized wax appeared both on the droplet surface and in the continuous phase, suggesting that stirring ensured dispersibility of the water droplets during cooling as the wax was crystallizing. Wax crystallization on the droplet surface provided stability against droplet coalescence while continuous phase wax crystals minimized inter-droplet collisions. The key novel aspect of this research is in the simplicity to tailor the spatial distribution of wax crystals, i.e., either at the droplet surface or in the continuous phase via use of a surfactant and judicious stirring and/or cooling. Knowledge gained from this research can be applied to develop strategies for long-term storage stability of crystal-stabilized W/O emulsions. Copyright © 2015 Elsevier Inc. All rights reserved.

  2. Polymer Latex Stability Modification by Exposure to Hydrophobic Solvents.

    PubMed

    de Oliveira Cardoso A; Galembeck

    1998-08-01

    The stability of latex particles toward coagulation in the presence of salt is modified by swelling the latex with toluene and chloroform vapors. Short-term stability was determined by turbidimetric titrations, and the long-term stability was evaluated by adding latex and salt solutions, allowing the mixture to age for 24 or 48 h and determining the characteristics of the supernatant and of the sediment. Nine different latexes were examined, with variable results: in some cases, both apolar solvents stabilize the latex; in other cases, increased stability is induced by only one of the solvents, either toluene or chloroform. There is also coherence, but not a strict correlation, between the solvent effects on short- and long-term stability. For instance, in the case of a core-and-shell styrene-butyl methacrylate latex, chloroform has a small stabilizing effect in the titration experiment, but it prevents the formation of a coagulated latex sediment even 48 h after mixing latex and salt. Two hypotheses are discussed to account for these observations: (i) swelling solvents decrease the particles ability to dissipate the collision kinetic energy, so that particles collide but without joining each other; (ii) the solvents induce the release of trapped charged groups from the particle interior to the interface, enhancing the usual (electrostatic, steric, hydration) stability factors. Copyright 1998 Academic Press.

  3. The stability of liquid-filled matrix ionization chamber electronic portal imaging devices for dosimetry purposes.

    PubMed

    Louwe, R J W; Tielenburg, R; van Ingen, K M; Mijnheer, B J; van Herk, M B

    2004-04-01

    This study was performed to determine the stability of liquid-filled matrix ionization chamber (LiFi-type) electronic portal imaging devices (EPID) for dosimetric purposes. The short- and long-term stability of the response was investigated, as well as the importance of factors influencing the response (e.g., temperature fluctuations, radiation damage, and the performance of the electronic hardware). It was shown that testing the performance of the electronic hardware as well as the short-term stability of the imagers may reveal the cause of a poor long-term stability of the imager response. In addition, the short-term stability was measured to verify the validity of the fitted dose-response curve immediately after beam startup. The long-term stability of these imagers could be considerably improved by correcting for room temperature fluctuations and gradual changes in response due to radiation damage. As a result, the reproducibility was better than 1% (1 SD) over a period of two years. The results of this study were used to formulate recommendations for a quality control program for portal dosimetry. The effect of such a program was assessed by comparing the results of portal dosimetry and in vivo dosimetry using diodes during the treatment of 31 prostate patients. The improvement of the results for portal dosimetry was consistent with the deviations observed with the reproducibility tests in that particular period. After a correction for the variation in response of the imager, the average difference between the measured and prescribed dose during the treatment of prostate patients was -0.7%+/-1.5% (1 SD), and -0.6%+/-1.1% (1 SD) for EPID and diode in vivo dosimetry, respectively. It can be concluded that a high stability of the response can be achieved for this type of EPID by applying a rigorous quality control program.

  4. Dynamic studies of small animals with a four-color diffuse optical tomography imager

    NASA Astrophysics Data System (ADS)

    Schmitz, Christoph H.; Graber, Harry L.; Pei, Yaling; Farber, Mark; Stewart, Mark; Levina, Rita D.; Levin, Mikhail B.; Xu, Yong; Barbour, Randall L.

    2005-09-01

    We present newly developed instrumentation for full-tomographic four-wavelength, continuous wave, diffuse optical tomography (DOT) imaging on small animals. A small-animal imaging stage was constructed, from materials compatible with in-magnet studies, which offers stereotaxic fixation of the animal and precise, stable probe positioning. Instrument performance, based on calibration and phantom studies, demonstrates excellent long-term signal stability. DOT measurements of the functional rat brain response to electric paw stimulation are presented, and these demonstrate high data quality and excellent sensitivity to hemodynamic changes. A general linear model analysis on individual trials is used to localize and quantify the occurrence of functional behavior associated with the different hemoglobin state responses. Statistical evaluation of outcomes of individual trials is employed to identify significant regional response variations for different stimulation sites. Image results reveal a diffuse cortical response and a strong reaction of the thalamus, both indicative of activation of pain pathways by the stimulation. In addition, a weaker lateralized functional component is observed in the brain response, suggesting presence of motor activation. An important outcome of the experiment is that it shows that reactions to individual provocations can be monitored, without having to resort to signal averaging. Thus the described technology may be useful for studies of long-term trends in hemodynamic response, as would occur, for example, in behavioral studies involving freely moving animals.

  5. Five Years of JOSIE: Assessment of the Performance of Ozone Sondes Under Quasi-Flight Conditions in the Environmental Simulation Chamber With Regard to Satellite Validation

    NASA Astrophysics Data System (ADS)

    Smit, H. G.; Straeter, W.; Helten, M.; Kley, D.

    2002-05-01

    Up to an altitude of about 20 km ozone sondes constitute the most important data source with long term data coverage for the derivation of ozone trends with sufficient vertical resolution, particularly in the important altitude region around the tropopause. In this region and also above in lower/middle stratosphere up to 30-35 km altitude ozone sondes are of crucial importance to validate and evaluate satellite measurements, particularly for their long term stability. Each ozone sounding is made with an individual disposable instrument and, therefore, have to be characterized well prior to flight. Therefore, quality assurance of ozone sonde performance is a pre-requisite. As part of the quality assurance (QA) plan for ozone sondes that are in routine use in the Global Atmosphere Watch program of the World Meteorological Organization the environmental simulation chamber at the Research Centre Juelich (Germany) is established as World Calibration Centre for Ozone Sondes. The facility enables control of pressure, temperature and ozone concentration and can simulate flight conditions of ozone soundings up to an altitude of 35 km, whereby an accurate UV-photometer serves as a reference. In the scope of this QA-plan for ozonesondes since 1996 several JOSIE (= Juelich Ozone Sonde Intercomparison Experiment) experiments to assess the performance of ozone sondes of different types and manufacturers have been conducted at the calibration facility. We will present an overview of the results obtained from the different JOSIE experiments. The results will be discussed with regard to the use of ozone sondes to validate satellite measurements. Special attention will be paid to the influence of operating procedures on the performance of sondes and the need for standardization to assure ozone sounding data of sufficient quality to use for satellite validations.

  6. Marijuana effects on long-term memory assessment and retrieval.

    PubMed

    Darley, C F; Tinklenberg, J R; Roth, W T; Vernon, S; Kopell, B S

    1977-05-09

    The ability of 16 college-educated male subjects to recall from long-term memory a series of common facts was tested during intoxication with marijuana extract calibrated to 0.3 mg/kg delta-9-tetrahydrocannabinol and during placebo conditions. The subjects' ability to assess their memory capabilities was then determined by measuring how certain they were about the accuracy of their recall performance and by having them predict their performance on a subsequent recognition test involving the same recall items. Marijuana had no effect on recall or recognition performance. These results do not support the view that marijuana provides access to facts in long-term storage which are inaccessible during non-intoxication. During both marijuana and placebo conditions, subjects could accurately predict their recognition memory performance. Hence, marijuana did not alter the subjects' ability to accurately assess what information resides in long-term memory even though they did not have complete access to that information.

  7. Humidity-corrected Arrhenius equation: The reference condition approach.

    PubMed

    Naveršnik, Klemen; Jurečič, Rok

    2016-03-16

    Accelerated and stress stability data is often used to predict shelf life of pharmaceuticals. Temperature, combined with humidity accelerates chemical decomposition and the Arrhenius equation is used to extrapolate accelerated stability results to long-term stability. Statistical estimation of the humidity-corrected Arrhenius equation is not straightforward due to its non-linearity. A two stage nonlinear fitting approach is used in practice, followed by a prediction stage. We developed a single-stage statistical procedure, called the reference condition approach, which has better statistical properties (less collinearity, direct estimation of uncertainty, narrower prediction interval) and is significantly easier to use, compared to the existing approaches. Our statistical model was populated with data from a 35-day stress stability study on a laboratory batch of vitamin tablets and required mere 30 laboratory assay determinations. The stability prediction agreed well with the actual 24-month long term stability of the product. The approach has high potential to assist product formulation, specification setting and stability statements. Copyright © 2016 Elsevier B.V. All rights reserved.

  8. 3D printed cellular solid outperforms traditional stochastic foam in long-term mechanical response

    DOE PAGES

    Maiti, A.; Small, W.; Lewicki, J.; ...

    2016-04-27

    3D printing of polymeric foams by direct-ink-write is a recent technological breakthrough that enables the creation of versatile compressible solids with programmable microstructure, customizable shapes, and tunable mechanical response including negative elastic modulus. However, in many applications the success of these 3D printed materials as a viable replacement for traditional stochastic foams critically depends on their mechanical performance and micro-architectural stability while deployed under long-term mechanical strain. To predict the long-term performance of the two types of foams we employed multi-year-long accelerated aging studies under compressive strain followed by a time-temperature-superposition analysis using a minimum-arc-length-based algorithm. The resulting master curvesmore » predict superior long-term performance of the 3D printed foam in terms of two different metrics, i.e., compression set and load retention. To gain deeper understanding, we imaged the microstructure of both foams using X-ray computed tomography, and performed finite-element analysis of the mechanical response within these microstructures. As a result, this indicates a wider stress variation in the stochastic foam with points of more extreme local stress as compared to the 3D printed material, which might explain the latter’s improved long-term stability and mechanical performance.« less

  9. 3D printed cellular solid outperforms traditional stochastic foam in long-term mechanical response

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Maiti, A.; Small, W.; Lewicki, J.

    3D printing of polymeric foams by direct-ink-write is a recent technological breakthrough that enables the creation of versatile compressible solids with programmable microstructure, customizable shapes, and tunable mechanical response including negative elastic modulus. However, in many applications the success of these 3D printed materials as a viable replacement for traditional stochastic foams critically depends on their mechanical performance and micro-architectural stability while deployed under long-term mechanical strain. To predict the long-term performance of the two types of foams we employed multi-year-long accelerated aging studies under compressive strain followed by a time-temperature-superposition analysis using a minimum-arc-length-based algorithm. The resulting master curvesmore » predict superior long-term performance of the 3D printed foam in terms of two different metrics, i.e., compression set and load retention. To gain deeper understanding, we imaged the microstructure of both foams using X-ray computed tomography, and performed finite-element analysis of the mechanical response within these microstructures. As a result, this indicates a wider stress variation in the stochastic foam with points of more extreme local stress as compared to the 3D printed material, which might explain the latter’s improved long-term stability and mechanical performance.« less

  10. 3D printed cellular solid outperforms traditional stochastic foam in long-term mechanical response

    NASA Astrophysics Data System (ADS)

    Maiti, A.; Small, W.; Lewicki, J. P.; Weisgraber, T. H.; Duoss, E. B.; Chinn, S. C.; Pearson, M. A.; Spadaccini, C. M.; Maxwell, R. S.; Wilson, T. S.

    2016-04-01

    3D printing of polymeric foams by direct-ink-write is a recent technological breakthrough that enables the creation of versatile compressible solids with programmable microstructure, customizable shapes, and tunable mechanical response including negative elastic modulus. However, in many applications the success of these 3D printed materials as a viable replacement for traditional stochastic foams critically depends on their mechanical performance and micro-architectural stability while deployed under long-term mechanical strain. To predict the long-term performance of the two types of foams we employed multi-year-long accelerated aging studies under compressive strain followed by a time-temperature-superposition analysis using a minimum-arc-length-based algorithm. The resulting master curves predict superior long-term performance of the 3D printed foam in terms of two different metrics, i.e., compression set and load retention. To gain deeper understanding, we imaged the microstructure of both foams using X-ray computed tomography, and performed finite-element analysis of the mechanical response within these microstructures. This indicates a wider stress variation in the stochastic foam with points of more extreme local stress as compared to the 3D printed material, which might explain the latter’s improved long-term stability and mechanical performance.

  11. 3D printed cellular solid outperforms traditional stochastic foam in long-term mechanical response

    PubMed Central

    Maiti, A.; Small, W.; Lewicki, J. P.; Weisgraber, T. H.; Duoss, E. B.; Chinn, S. C.; Pearson, M. A.; Spadaccini, C. M.; Maxwell, R. S.; Wilson, T. S.

    2016-01-01

    3D printing of polymeric foams by direct-ink-write is a recent technological breakthrough that enables the creation of versatile compressible solids with programmable microstructure, customizable shapes, and tunable mechanical response including negative elastic modulus. However, in many applications the success of these 3D printed materials as a viable replacement for traditional stochastic foams critically depends on their mechanical performance and micro-architectural stability while deployed under long-term mechanical strain. To predict the long-term performance of the two types of foams we employed multi-year-long accelerated aging studies under compressive strain followed by a time-temperature-superposition analysis using a minimum-arc-length-based algorithm. The resulting master curves predict superior long-term performance of the 3D printed foam in terms of two different metrics, i.e., compression set and load retention. To gain deeper understanding, we imaged the microstructure of both foams using X-ray computed tomography, and performed finite-element analysis of the mechanical response within these microstructures. This indicates a wider stress variation in the stochastic foam with points of more extreme local stress as compared to the 3D printed material, which might explain the latter’s improved long-term stability and mechanical performance. PMID:27117858

  12. Long-Term Survival Prediction for Coronary Artery Bypass Grafting: Validation of the ASCERT Model Compared With The Society of Thoracic Surgeons Predicted Risk of Mortality.

    PubMed

    Lancaster, Timothy S; Schill, Matthew R; Greenberg, Jason W; Ruaengsri, Chawannuch; Schuessler, Richard B; Lawton, Jennifer S; Maniar, Hersh S; Pasque, Michael K; Moon, Marc R; Damiano, Ralph J; Melby, Spencer J

    2018-05-01

    The recently developed American College of Cardiology Foundation-Society of Thoracic Surgeons (STS) Collaboration on the Comparative Effectiveness of Revascularization Strategy (ASCERT) Long-Term Survival Probability Calculator is a valuable addition to existing short-term risk-prediction tools for cardiac surgical procedures but has yet to be externally validated. Institutional data of 654 patients aged 65 years or older undergoing isolated coronary artery bypass grafting between 2005 and 2010 were reviewed. Predicted survival probabilities were calculated using the ASCERT model. Survival data were collected using the Social Security Death Index and institutional medical records. Model calibration and discrimination were assessed for the overall sample and for risk-stratified subgroups based on (1) ASCERT 7-year survival probability and (2) the predicted risk of mortality (PROM) from the STS Short-Term Risk Calculator. Logistic regression analysis was performed to evaluate additional perioperative variables contributing to death. Overall survival was 92.1% (569 of 597) at 1 year and 50.5% (164 of 325) at 7 years. Calibration assessment found no significant differences between predicted and actual survival curves for the overall sample or for the risk-stratified subgroups, whether stratified by predicted 7-year survival or by PROM. Discriminative performance was comparable between the ASCERT and PROM models for 7-year survival prediction (p < 0.001 for both; C-statistic = 0.815 for ASCERT and 0.781 for PROM). Prolonged ventilation, stroke, and hospital length of stay were also predictive of long-term death. The ASCERT survival probability calculator was externally validated for prediction of long-term survival after coronary artery bypass grafting in all risk groups. The widely used STS PROM performed comparably as a predictor of long-term survival. Both tools provide important information for preoperative decision making and patient counseling about potential outcomes after coronary artery bypass grafting. Copyright © 2018 The Society of Thoracic Surgeons. Published by Elsevier Inc. All rights reserved.

  13. Effects of Sustained Abstinence Among Treated Substance-Abusing Homeless Persons on Housing and Employment

    PubMed Central

    Schumacher, Joseph E.; Wallace, Dennis; Vuchinich, Rudy; Mennemeyer, Stephen T.; Kertesz, Stefan G.

    2010-01-01

    Objectives. We examined whether cocaine-dependent homeless persons had stable housing and were employed 6, 12, and 18 months after they entered a randomized controlled trial comparing 2 treatments. Methods. One group (n = 103) received abstinence-contingent housing, vocational training, and work; another group (n = 103) received the same intervention plus cognitive behavioral day treatment. We examined baseline and early treatment variables for association with long-term housing and employment. Results. Although the enhanced-treatment group achieved better abstinence rates, the groups did not differ in long-term housing and employment stability. However, consecutive weeks of abstinence during treatment (and to a lesser extent, older age and male gender) predicted long-term housing and employment stability after adjustment for baseline differences in employment, housing, and treatment. Conclusions. Our data showed a relationship of abstinence with housing stability. Contrasting these results with the increasingly popular Housing First interventions reveals important gaps in our knowledge to be addressed in future research. PMID:19833998

  14. Long-term efficient organic photovoltaics based on quaternary bulk heterojunctions

    NASA Astrophysics Data System (ADS)

    Nam, Minwoo; Cha, Minjeong; Lee, Hyun Hwi; Hur, Kahyun; Lee, Kyu-Tae; Yoo, Jaehong; Han, Il Ki; Kwon, S. Joon; Ko, Doo-Hyun

    2017-01-01

    A major impediment to the commercialization of organic photovoltaics (OPVs) is attaining long-term morphological stability of the bulk heterojunction (BHJ) layer. To secure the stability while pursuing optimized performance, multi-component BHJ-based OPVs have been strategically explored. Here we demonstrate the use of quaternary BHJs (q-BHJs) composed of two conjugated polymer donors and two fullerene acceptors as a novel platform to produce high-efficiency and long-term durable OPVs. A q-BHJ OPV (q-OPV) with an experimentally optimized composition exhibits an enhanced efficiency and extended operational lifetime than does the binary reference OPV. The q-OPV would retain more than 72% of its initial efficiency (for example, 8.42-6.06%) after a 1-year operation at an elevated temperature of 65 °C. This is superior to those of the state-of-the-art BHJ-based OPVs. We attribute the enhanced stability to the significant suppression of domain growth and phase separation between the components via kinetic trapping effect.

  15. Epoxide-functionalization of polyethyleneimine for synthesis of stable carbon dioxide adsorbent in temperature swing adsorption

    PubMed Central

    Choi, Woosung; Min, Kyungmin; Kim, Chaehoon; Ko, Young Soo; Jeon, Jae Wan; Seo, Hwimin; Park, Yong-Ki; Choi, Minkee

    2016-01-01

    Amine-containing adsorbents have been extensively investigated for post-combustion carbon dioxide capture due to their ability to chemisorb low-concentration carbon dioxide from a wet flue gas. However, earlier studies have focused primarily on the carbon dioxide uptake of adsorbents, and have not demonstrated effective adsorbent regeneration and long-term stability under such conditions. Here, we report the versatile and scalable synthesis of a functionalized-polyethyleneimine (PEI)/silica adsorbent which simultaneously exhibits a large working capacity (2.2 mmol g−1) and long-term stability in a practical temperature swing adsorption process (regeneration under 100% carbon dioxide at 120 °C), enabling the separation of concentrated carbon dioxide. We demonstrate that the functionalization of PEI with 1,2-epoxybutane reduces the heat of adsorption and facilitates carbon dioxide desorption (>99%) during regeneration compared with unmodified PEI (76%). Moreover, the functionalization significantly improves long-term adsorbent stability over repeated temperature swing adsorption cycles due to the suppression of urea formation and oxidative amine degradation. PMID:27572662

  16. On-orbit characterizations of Earth Radiation Budget Experiment broadband shortwave active cavity radiometer sensor responses

    NASA Astrophysics Data System (ADS)

    Lee, Robert B., III; Wilson, Robert S.; Smith, G. Louis; Bush, Kathryn A.; Thomas, Susan; Pandey, Dhirendra K.; Paden, Jack

    2004-12-01

    The NASA Earth Radiation Budget Experiment (ERBE) missions were designed to monitor long-term changes in the earth radiation budget components which may cause climate changes. During the October 1984 through September 2004 period, the NASA Earth Radiation Budget Satellite (ERBS)/ERBE nonscanning active cavity radiometers (ACR) were used to monitor long-term changes in the earth radiation budget components of the incoming total solar irradiance (TSI), earth-reflected TSI, and earth-emitted outgoing longwave radiation (OLR). The earth-reflected total solar irradiances were measured using broadband shortwave fused, waterless quartz (Suprasil) filters and ACR"s that were covered with a black paint absorbing surface. Using on-board calibration systems, 1984 through 1999, long-term ERBS/ERBE ACR sensor response changes were determined from direct observations of the incoming TSI in the 0.2-5 micrometer shortwave broadband spectral region. During the October 1984 through September 1999 period, the ERBS shortwave sensor responses were found to decrease as much as 8.8% when the quartz filter transmittances decreased due to direct exposure to TSI. On October 6, 1999, the on-board ERBS calibration systems failed. To estimate the 1999-2004, ERBS sensor response changes, the 1984-1997 NOAA-9, and 1986-1995 NOAA-10 Spacecraft ERBE ACR responses were used to characterize response changes as a function of exposure time. The NOAA-9 and NOAA-10 ACR responses decreased as much as 10% due to higher integrated TSI exposure times. In this paper, for each of the ERBS, NOAA-9, and NOAA-10 Spacecraft platforms, the solar calibrations of the ERBE sensor responses are described as well as the derived ERBE sensor response changes as a function of TSI exposure time. For the 1984-2003 ERBS data sets, it is estimated that the calibrated ERBE earth-reflected TSI measurements have precisions approaching 0.2 Watts-per-squared-meter at satellite altitudes.

  17. Effect of year-to-year variability of leaf area index on variable infiltration capacity model performance and simulation of streamflow during drought

    NASA Astrophysics Data System (ADS)

    Tesemma, Z. K.; Wei, Y.; Peel, M. C.; Western, A. W.

    2014-09-01

    This study assessed the effect of using observed monthly leaf area index (LAI) on hydrologic model performance and the simulation of streamflow during drought using the variable infiltration capacity (VIC) hydrological model in the Goulburn-Broken catchment of Australia, which has heterogeneous vegetation, soil and climate zones. VIC was calibrated with both observed monthly LAI and long-term mean monthly LAI, which were derived from the Global Land Surface Satellite (GLASS) observed monthly LAI dataset covering the period from 1982 to 2012. The model performance under wet and dry climates for the two different LAI inputs was assessed using three criteria, the classical Nash-Sutcliffe efficiency, the logarithm transformed flow Nash-Sutcliffe efficiency and the percentage bias. Finally, the percentage deviation of the simulated monthly streamflow using the observed monthly LAI from simulated streamflow using long-term mean monthly LAI was computed. The VIC model predicted monthly streamflow in the selected sub-catchments with model efficiencies ranging from 61.5 to 95.9% during calibration (1982-1997) and 59 to 92.4% during validation (1998-2012). Our results suggest systematic improvements from 4 to 25% in the Nash-Sutcliffe efficiency in pasture dominated catchments when the VIC model was calibrated with the observed monthly LAI instead of the long-term mean monthly LAI. There was limited systematic improvement in tree dominated catchments. The results also suggest that the model overestimation or underestimation of streamflow during wet and dry periods can be reduced to some extent by including the year-to-year variability of LAI in the model, thus reflecting the responses of vegetation to fluctuations in climate and other factors. Hence, the year-to-year variability in LAI should not be neglected; rather it should be included in model calibration as well as simulation of monthly water balance.

  18. The effect of year-to-year variability of leaf area index on Variable Infiltration Capacity model performance and simulation of runoff

    NASA Astrophysics Data System (ADS)

    Tesemma, Z. K.; Wei, Y.; Peel, M. C.; Western, A. W.

    2015-09-01

    This study assessed the effect of using observed monthly leaf area index (LAI) on hydrological model performance and the simulation of runoff using the Variable Infiltration Capacity (VIC) hydrological model in the Goulburn-Broken catchment of Australia, which has heterogeneous vegetation, soil and climate zones. VIC was calibrated with both observed monthly LAI and long-term mean monthly LAI, which were derived from the Global Land Surface Satellite (GLASS) leaf area index dataset covering the period from 1982 to 2012. The model performance under wet and dry climates for the two different LAI inputs was assessed using three criteria, the classical Nash-Sutcliffe efficiency, the logarithm transformed flow Nash-Sutcliffe efficiency and the percentage bias. Finally, the deviation of the simulated monthly runoff using the observed monthly LAI from simulated runoff using long-term mean monthly LAI was computed. The VIC model predicted monthly runoff in the selected sub-catchments with model efficiencies ranging from 61.5% to 95.9% during calibration (1982-1997) and 59% to 92.4% during validation (1998-2012). Our results suggest systematic improvements, from 4% to 25% in Nash-Sutcliffe efficiency, in sparsely forested sub-catchments when the VIC model was calibrated with observed monthly LAI instead of long-term mean monthly LAI. There was limited systematic improvement in tree dominated sub-catchments. The results also suggest that the model overestimation or underestimation of runoff during wet and dry periods can be reduced to 25 mm and 35 mm respectively by including the year-to-year variability of LAI in the model, thus reflecting the responses of vegetation to fluctuations in climate and other factors. Hence, the year-to-year variability in LAI should not be neglected; rather it should be included in model calibration as well as simulation of monthly water balance.

  19. Exploring the performance of the SEDD model to predict sediment yield in eucalyptus plantations. Long-term results from an experimental catchment in Southern Italy

    NASA Astrophysics Data System (ADS)

    Porto, P.; Cogliandro, V.; Callegari, G.

    2018-01-01

    In this paper, long-term sediment yield data, collected in a small (1.38 ha) Calabrian catchment (W2), reafforested with eucalyptus trees (Eucalyptus occidentalis Engl.) are used to validate the performance of the SEdiment Delivery Distributed Model (SEDD) in areas with high erosion rates. At first step, the SEDD model was calibrated using field data collected in previous field campaigns undertaken during the period 1978-1994. This first phase allowed the model calibration parameter β to be calculated using direct measurements of rainfall, runoff, and sediment output. The model was then validated in its calibrated form for an independent period (2006-2016) for which new measurements of rainfall, runoff and sediment output are also available. The analysis, carried out at event and annual scale showed good agreement between measured and predicted values of sediment yield and suggested that the SEDD model can be seen as an appropriate means of evaluating erosion risk associated with manmade plantations in marginal areas. Further work is however required to test the performance of the SEDD model as a prediction tool in different geomorphic contexts.

  20. Using the World Primary Standard Dobson Spectrometer to Monitor the Stability of a Multi-Instrument Satellite Ozone Dataset

    NASA Technical Reports Server (NTRS)

    McPeters, R.D.; Oltmans, Samuel J.

    2000-01-01

    NASA is creating a long term satellite ozone time series by combining data from multiple instruments: Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) (1978 - 1993), Meteor 3 TOMS (1991 - 1994), Earth Probe TOMS (1996 - present), Nimbus 7 SB-JV (1978 - 1990), NOAA-9 Solar Backscatter UV Spectrometer (SBUV/2) (1984 - 1997), NOAA-11 SBUV/2 (1989 - 1994), and NOAA-14 SBUV/2 (1995 - present). The stability of individual data sets and possible instrument-to-instrument differences are best checked by comparison with ground-based measurements. We have examined the time dependence of the calibrations of these instruments by comparing satellite derived ozone with that measured by the world primary standard Dobson spectrometer No. 83. This instrument has been maintained since 1962 as a standard for total ozone to an uncertainty of plus or minus 0.5%. Measurements of AD pair ozone made with instrument No. 83 at Mauna Loa observatory most summers since 1979 were compared with coincident TOMS and SBUV(/2) ozone measurements. The comparison shows that the various instruments were stable relative to instrument No. 83 to within about plus or minus 1%, but that there are instrument-to-instrument biases of as much as 3%. Earth Probe TOMS, for example, is 1% to 2% high relative to Nimbus 7 TOMS when the world standard instrument is used as a transfer standard. Similar results are seen when comparisons are made with an ensemble of 41 Dobson stations throughout the world, demonstrating that the ensemble as a whole is stable despite the fact that many instruments within the ensemble have clear calibration changes.

  1. Aquarius Whole Range Calibration: Celestial Sky, Ocean, and Land Targets

    NASA Technical Reports Server (NTRS)

    Dinnat, Emmanuel P.; Le Vine, David M.; Bindlish, Rajat; Piepmeier, Jeffrey R.; Brown, Shannon T.

    2014-01-01

    Aquarius is a spaceborne instrument that uses L-band radiometers to monitor sea surface salinity globally. Other applications of its data over land and the cryosphere are being developed. Combining its measurements with existing and upcoming L-band sensors will allow for long term studies. For that purpose, the radiometers calibration is critical. Aquarius measurements are currently calibrated over the oceans. They have been found too cold at the low end (celestial sky) of the brightness temperature scale, and too warm at the warm end (land and ice). We assess the impact of the antenna pattern model on the biases and propose a correction. We re-calibrate Aquarius measurements using the corrected antenna pattern and measurements over the Sky and oceans. The performances of the new calibration are evaluated using measurements over well instrument land sites.

  2. Superior long-term stability of a glucose biosensor based on inserted barrel plating gold electrodes.

    PubMed

    Hsu, Cheng-Teng; Hsiao, Hung-Chan; Fang, Mei-Yen; Zen, Jyh-Myng

    2009-10-15

    Disposable one shot usage blood glucose strips are routinely used in the diagnosis and management of diabetes mellitus and their performance can vary greatly. In this paper we critically evaluated the long-term stability of glucose strips made of barrel plating gold electrodes. Compared to other glucose biosensing platforms of vapor deposited palladium and screen printed carbon electrodes, the proposed glucose biosensor was found to show the best stability among the three biosensing platforms in thermal acceleration experiments at 40 degrees C for 6 months with an average bias of 3.4% at glucose concentrations of 5-20 mM. The precision test of this barrel plating gold glucose biosensor also showed the best performance (coefficients of variation in the range of 1.4-2.4%) in thermal acceleration experiments at 40 degrees C, 50 degrees C and 70 degrees C for 27 days. Error grid analysis revealed that all measurements fell in zone A and zone B. Regression analysis showed no significant difference between the proposed biosensor and the reference method at 99% confidence level. The amperometric glucose biosensor fabricated by inserting two barrel plating gold electrodes onto an injection-molding plastic base followed by immobilizing with a bio-reagent layer and membrane was very impressive with a long-term stability up to 2.5 years at 25 degrees C. Overall, these results indicated that the glucose oxidase/barrel plating gold biosensing platform is ideal for long-term accurate glycemic control.

  3. Parametric decadal climate forecast recalibration (DeFoReSt 1.0)

    NASA Astrophysics Data System (ADS)

    Pasternack, Alexander; Bhend, Jonas; Liniger, Mark A.; Rust, Henning W.; Müller, Wolfgang A.; Ulbrich, Uwe

    2018-01-01

    Near-term climate predictions such as decadal climate forecasts are increasingly being used to guide adaptation measures. For near-term probabilistic predictions to be useful, systematic errors of the forecasting systems have to be corrected. While methods for the calibration of probabilistic forecasts are readily available, these have to be adapted to the specifics of decadal climate forecasts including the long time horizon of decadal climate forecasts, lead-time-dependent systematic errors (drift) and the errors in the representation of long-term changes and variability. These features are compounded by small ensemble sizes to describe forecast uncertainty and a relatively short period for which typically pairs of reforecasts and observations are available to estimate calibration parameters. We introduce the Decadal Climate Forecast Recalibration Strategy (DeFoReSt), a parametric approach to recalibrate decadal ensemble forecasts that takes the above specifics into account. DeFoReSt optimizes forecast quality as measured by the continuous ranked probability score (CRPS). Using a toy model to generate synthetic forecast observation pairs, we demonstrate the positive effect on forecast quality in situations with pronounced and limited predictability. Finally, we apply DeFoReSt to decadal surface temperature forecasts from the MiKlip prototype system and find consistent, and sometimes considerable, improvements in forecast quality compared with a simple calibration of the lead-time-dependent systematic errors.

  4. Ambient measurement of ammonia and formaldehyde: Open path vs. extractive approach.

    NASA Astrophysics Data System (ADS)

    Rajamäki, Timo

    2017-04-01

    Ammonia NH3 and formaldehyde CH2O are some of the most critical chemicals for air quality. Reliable online measurement of these gases is one of the key operations for air quality and safety monitoring, in indoor, outdoor and process applications alike. Ammonia and formaldehyde are reactive compounds and they are harmful, even in very low ppb level concentrations. This means challenges for measurement system in all of its critical aspects: sampling, calibration and sensitivity. We are applying techniques so far successfully used to measure reactive inorganic compounds like ammonia NH3 and hydrogen fluoride HF to tackle these challenges. Now a novel setup based on direct laser absorption with cavity enhancement employing fundamental vibration level excitations of ammonia and formaldehyde molecules is constructed in connection with new mechanics and algorithms optimized for gas exchange and sampling in the case of these reactive molecules easily sticking to surfaces. An aberration corrected multipass sample cell in vacuum pressure is used in parallel with an open path multipass setup. The CH2O and NH3 calibration gases necessary for system calibration are dynamically generated using traceable standards and components. We compare these two approaches with special emphasis on the system's response time, robustness, sensitivity, usability in field conditions, maintenance need and long term stability. A further coal is to enable the use of the same setups also for simultaneous measurement of other reactive compounds often encountered in air quality monitoring. This would make possible more comprehensive and also economic monitoring of these compounds with a single device.

  5. Long-term Operation of an External Cavity Quantum Cascade Laser-based Trace-gas Sensor for Building Air Monitoring

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Phillips, Mark C.; Craig, Ian M.

    2013-11-03

    We analyze the long-term performance and stability of a trace-gas sensor based on an external cavity quantum cascade laser using data collected over a one-year period in a building air monitoring application.

  6. In situ calibration of an infrared imaging video bolometer in the Large Helical Device

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mukai, K., E-mail: mukai.kiyofumi@LHD.nifs.ac.jp; Peterson, B. J.; Pandya, S. N.

    The InfraRed imaging Video Bolometer (IRVB) is a powerful diagnostic to measure multi-dimensional radiation profiles in plasma fusion devices. In the Large Helical Device (LHD), four IRVBs have been installed with different fields of view to reconstruct three-dimensional profiles using a tomography technique. For the application of the measurement to plasma experiments using deuterium gas in LHD in the near future, the long-term effect of the neutron irradiation on the heat characteristics of an IRVB foil should be taken into account by regular in situ calibration measurements. Therefore, in this study, an in situ calibration system was designed.

  7. Formulation of immunoassay calibrators in pasteurized albumin can significantly enhance their durability.

    PubMed

    Warren, David J; Nordlund, Marianne S; Paus, Elisabeth

    2010-02-28

    Calibrator matrix can have significant effects on the commutability of assay standards and on the maintenance of their integrity. We have observed marked instability in progastrin-releasing peptide (proGRP) assay standards traceable to the bovine serum albumin (BSA) used in matrix formulation. Attempts were made to improve calibrator stability using different albumin pretreatments. Observed analyte recoveries in calibrators prepared with untreated BSA were consistently less than 45% after 1 week of storage at 4 degrees C. Pre-treating the BSA by chromatography on immobilized heparin or benzamidine failed to improve calibrator durability with day 7 recoveries of less than 55%. In marked contrast, calibrators formulated with albumin pasteurized at pH 3.0 displayed remarkable stability. Recoveries of >97% were observed after 4 weeks of storage at either 4 degrees C or room temperature. Even calibrators incubated for 4 weeks at 37 degrees C gave recoveries between 91-106%. This improvement was not seen with BSA pasteurized at neutral pH. Albumin pretreatment is straightforward, easily scalable and dramatically improves calibrator stability. Matrix formulated with acid-pasteurized BSA may prove more generally useful when assays are plagued by poor calibrator durability. 2009 Elsevier B.V. All rights reserved.

  8. Long-Term Stage, Stage-Residual, and Width Data for Streams in the Piedmont Physiographic Region, Georgia

    USGS Publications Warehouse

    Riley, Jeffrey W.; Jacobson, Robert B.

    2009-01-01

    This report presents the data used to assess geomorphic adjustment of streams over time and to changing land-use conditions. Thirty-seven U.S. Geological Survey streamgages were selected within the Piedmont physiographic region of Georgia. Width, depth, stage, and discharge data from these streams were analyzed to assess channel stability and determine if systematic adjustments of channel morphology could be related to time or land use and land cover. Residual analyses of stage-discharge data were used to infer channel stability, which could then be used as an indicator of habitat stability. Streamgages, representing a gradient of urbanization, were selected to test hypotheses regarding stream stability and adjustment to urban conditions. Results indicate that 14 sites exhibited long-term channel stability, 11 were degrading, 6 were aggrading, and 6 showed variability in response over the study period.

  9. Production stability of active polysaccharides of Dendrobium huoshanense using long-term cultures of protocorm-like bodies.

    PubMed

    Zha, Xue-Qiang; Luo, Jian-Ping

    2008-01-01

    In this study, the production stability of active polysaccharides in protocorm-like bodies (PLBs) induced from the seedling segments of Dendrobium huoshanense C. Z. Tang et S. J. Cheng was investigated during long-term subculture. Subcultures were conducted once every 30 days. With an average inoculum of 39 g/L fresh PLBs, the increase in biomass ranged from 95.7 g/L to 103.9 g/L in fresh weight and 3.2 g/L to 3.4 g/L in dry weight during eighteen continuous subcultures while polysaccharide content in PLBs was from 0.8 mg/g Fw (mg polysaccharide per gram PLBs in fresh weight) to 1.0 mg/g Fw. In addition, polysaccharides from all cultures showed a similar potential of stimulating interferon gamma (IFN-gamma) release in the supernatant of splenocytes and tumor necrosis factor alpha (TNF-alpha) release in the supernatant of peritoneal macrophages. To elucidate the genetic basis of polysaccharide production stability in long-term subculture of PLBs, the genetic fingerprints by RAPD were further analyzed using plantlets from PLB development. Results showed that there is no evidence of genetic variation both within the plantlets from the different subcultures of PLBs and between long-term subcultures and the donor plants.

  10. Simple surface engineering of polydimethylsiloxane with polydopamine for stabilized mesenchymal stem cell adhesion and multipotency

    PubMed Central

    Chuah, Yon Jin; Koh, Yi Ting; Lim, Kaiyang; Menon, Nishanth V.; Wu, Yingnan; Kang, Yuejun

    2015-01-01

    Polydimethylsiloxane (PDMS) has been extensively exploited to study stem cell physiology in the field of mechanobiology and microfluidic chips due to their transparency, low cost and ease of fabrication. However, its intrinsic high hydrophobicity renders a surface incompatible for prolonged cell adhesion and proliferation. Plasma-treated or protein-coated PDMS shows some improvement but these strategies are often short-lived with either cell aggregates formation or cell sheet dissociation. Recently, chemical functionalization of PDMS surfaces has proved to be able to stabilize long-term culture but the chemicals and procedures involved are not user- and eco-friendly. Herein, we aim to tailor greener and biocompatible PDMS surfaces by developing a one-step bio-inspired polydopamine coating strategy to stabilize long-term bone marrow stromal cell culture on PDMS substrates. Characterization of the polydopamine-coated PDMS surfaces has revealed changes in surface wettability and presence of hydroxyl and secondary amines as compared to uncoated surfaces. These changes in PDMS surface profile contribute to the stability in BMSCs adhesion, proliferation and multipotency. This simple methodology can significantly enhance the biocompatibility of PDMS-based microfluidic devices for long-term cell analysis or mechanobiological studies. PMID:26647719

  11. [Evaluation of the influence of sterilization method on the stability of carboxymethyl cellulose wound dressing].

    PubMed

    Muselík, Jan; Wojnarová, Lenka; Masteiková, Ruta; Sopuch, Tomáš

    2013-04-01

    Carboxymethyl cellulose, especially its sodium salt, is a versatile pharmaceutical excipient. From a therapeutic point of view, sodium salt of carboxymethyl cellulose is used in the production of modern wound dressings to allow moist wound healing. Wound dressings must be sterile and stable throughout their shelf life and have to be able to withstand different temperature conditions. At the present time, a number of sterilization methods are available. In the case of polymeric materials, the selected sterilization process must not induce any changes in the polymer structure, such as polymer chains cleavage, changes in cross-linking, etc. This paper evaluates the influence of different sterilization methods (γ-radiation, β-radiation, ethylene oxide) on the stability of carboxymethyl cellulose and the results of long-term and accelerated stability testing. Evaluation of samples was performed using size-exclusion chromatography. The obtained results showed that ethylene oxide sterilization was the least aggressive variant of the sterilization methods tested. When the γ-radiation sterilization was used, the changes in the size of the carboxymethyl cellulose molecule occurred. In the course of accelerated and long term stability studies, no further degradation changes were observed, and thus sterilized samples are suitable for long term storage.

  12. Multisite evaluation of APEX for water quality: II. Regional parameterization

    USDA-ARS?s Scientific Manuscript database

    Phosphorus (P) index assessment requires independent estimates of long-term average annual P loss from multiple locations, management practices, soils, and landscape positions. Because currently available measured data are insufficient, calibrated and validated process-based models have been propos...

  13. Long term stability of nanowire nanoelectronics in physiological environments.

    PubMed

    Zhou, Wei; Dai, Xiaochuan; Fu, Tian-Ming; Xie, Chong; Liu, Jia; Lieber, Charles M

    2014-03-12

    Nanowire nanoelectronic devices have been exploited as highly sensitive subcellular resolution detectors for recording extracellular and intracellular signals from cells, as well as from natural and engineered/cyborg tissues, and in this capacity open many opportunities for fundamental biological research and biomedical applications. Here we demonstrate the capability to take full advantage of the attractive capabilities of nanowire nanoelectronic devices for long term physiological studies by passivating the nanowire elements with ultrathin metal oxide shells. Studies of Si and Si/aluminum oxide (Al2O3) core/shell nanowires in physiological solutions at 37 °C demonstrate long-term stability extending for at least 100 days in samples coated with 10 nm thick Al2O3 shells. In addition, investigations of nanowires configured as field-effect transistors (FETs) demonstrate that the Si/Al2O3 core/shell nanowire FETs exhibit good device performance for at least 4 months in physiological model solutions at 37 °C. The generality of this approach was also tested with in studies of Ge/Si and InAs nanowires, where Ge/Si/Al2O3 and InAs/Al2O3 core/shell materials exhibited stability for at least 100 days in physiological model solutions at 37 °C. In addition, investigations of hafnium oxide-Al2O3 nanolaminated shells indicate the potential to extend nanowire stability well beyond 1 year time scale in vivo. These studies demonstrate that straightforward core/shell nanowire nanoelectronic devices can exhibit the long term stability needed for a range of chronic in vivo studies in animals as well as powerful biomedical implants that could improve monitoring and treatment of disease.

  14. Long Term Stability of Nanowire Nanoelectronics in Physiological Environments

    PubMed Central

    2015-01-01

    Nanowire nanoelectronic devices have been exploited as highly sensitive subcellular resolution detectors for recording extracellular and intracellular signals from cells, as well as from natural and engineered/cyborg tissues, and in this capacity open many opportunities for fundamental biological research and biomedical applications. Here we demonstrate the capability to take full advantage of the attractive capabilities of nanowire nanoelectronic devices for long term physiological studies by passivating the nanowire elements with ultrathin metal oxide shells. Studies of Si and Si/aluminum oxide (Al2O3) core/shell nanowires in physiological solutions at 37 °C demonstrate long-term stability extending for at least 100 days in samples coated with 10 nm thick Al2O3 shells. In addition, investigations of nanowires configured as field-effect transistors (FETs) demonstrate that the Si/Al2O3 core/shell nanowire FETs exhibit good device performance for at least 4 months in physiological model solutions at 37 °C. The generality of this approach was also tested with in studies of Ge/Si and InAs nanowires, where Ge/Si/Al2O3 and InAs/Al2O3 core/shell materials exhibited stability for at least 100 days in physiological model solutions at 37 °C. In addition, investigations of hafnium oxide-Al2O3 nanolaminated shells indicate the potential to extend nanowire stability well beyond 1 year time scale in vivo. These studies demonstrate that straightforward core/shell nanowire nanoelectronic devices can exhibit the long term stability needed for a range of chronic in vivo studies in animals as well as powerful biomedical implants that could improve monitoring and treatment of disease. PMID:24479700

  15. Simple transfer calibration method for a Cimel Sun-Moon photometer: calculating lunar calibration coefficients from Sun calibration constants.

    PubMed

    Li, Zhengqiang; Li, Kaitao; Li, Donghui; Yang, Jiuchun; Xu, Hua; Goloub, Philippe; Victori, Stephane

    2016-09-20

    The Cimel new technologies allow both daytime and nighttime aerosol optical depth (AOD) measurements. Although the daytime AOD calibration protocols are well established, accurate and simple nighttime calibration is still a challenging task. Standard lunar-Langley and intercomparison calibration methods both require specific conditions in terms of atmospheric stability and site condition. Additionally, the lunar irradiance model also has some known limits on its uncertainty. This paper presents a simple calibration method that transfers the direct-Sun calibration constant, V0,Sun, to the lunar irradiance calibration coefficient, CMoon. Our approach is a pure calculation method, independent of site limits, e.g., Moon phase. The method is also not affected by the lunar irradiance model limitations, which is the largest error source of traditional calibration methods. Besides, this new transfer calibration approach is easy to use in the field since CMoon can be obtained directly once V0,Sun is known. Error analysis suggests that the average uncertainty of CMoon over the 440-1640 nm bands obtained with the transfer method is 2.4%-2.8%, depending on the V0,Sun approach (Langley or intercomparison), which is comparable with that of lunar-Langley approach, theoretically. In this paper, the Sun-Moon transfer and the Langley methods are compared based on site measurements in Beijing, and the day-night measurement continuity and performance are analyzed.

  16. Calibration Matters: Advances in Strapdown Airborne Gravimetry

    NASA Astrophysics Data System (ADS)

    Becker, D.

    2015-12-01

    Using a commercial navigation-grade strapdown inertial measurement unit (IMU) for airborne gravimetry can be advantageous in terms of cost, handling, and space consumption compared to the classical stable-platform spring gravimeters. Up to now, however, large sensor errors made it impossible to reach the mGal-level using such type IMUs as they are not designed or optimized for this kind of application. Apart from a proper error-modeling in the filtering process, specific calibration methods that are tailored to the application of aerogravity may help to bridge this gap and to improve their performance. Based on simulations, a quantitative analysis is presented on how much IMU sensor errors, as biases, scale factors, cross couplings, and thermal drifts distort the determination of gravity and the deflection of the vertical (DOV). Several lab and in-field calibration methods are briefly discussed, and calibration results are shown for an iMAR RQH unit. In particular, a thermal lab calibration of its QA2000 accelerometers greatly improved the long-term drift behavior. Latest results from four recent airborne gravimetry campaigns confirm the effectiveness of the calibrations applied, with cross-over accuracies reaching 1.0 mGal (0.6 mGal after cross-over adjustment) and DOV accuracies reaching 1.1 arc seconds after cross-over adjustment.

  17. Functional Evidence for Memory Stabilization in Sensorimotor Adaptation: A 24-h Resting-State fMRI Study.

    PubMed

    Della-Maggiore, Valeria; Villalta, Jorge I; Kovacevic, Natasa; McIntosh, Anthony Randal

    2017-03-01

    Adaptation learning is crucial to maintain precise motor control in face of environmental perturbations. Although much progress has been made in understanding the psychophysics and neurophysiology of sensorimotor adaptation (SA), the time course of memory consolidation remains elusive. The lack of a reproducible gradient of memory resistance using protocols of retrograde interference has even led to the proposal that memories produced through SA do not consolidate. Here, we pursued an alternative approach using resting-state fMRI to track changes in functional connectivity (FC) induced by learning. Given that consolidation leads to long-term memory, we hypothesized that a change in FC that predicted long-term memory but not short-term memory would provide indirect evidence for memory stabilization. Six scans were acquired before, 15 min, 1, 3, 5.5, and 24 h after training on a center-out task under veridical or distorted visual feedback. The experimental group showed an increment in FC of a network including motor, premotor, posterior parietal cortex, cerebellum, and putamen that peaked at 5.5 h. Crucially, the strengthening of this network correlated positively with long-term retention but negatively with short-term retention. Our work provides evidence, suggesting that adaptation memories stabilize within a 6-h window, and points to different mechanisms subserving short- and long-term memory. © The Author 2015. Published by Oxford University Press. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

  18. Alumina/polymer-coated nanocrystals with extremely high stability used as a color conversion material in LEDs

    NASA Astrophysics Data System (ADS)

    Woo, Ju Yeon; Lee, Jongsoo; Han, Chang-Soo

    2013-12-01

    The long-term stability of quantum dot (QD)-based devices under harsh environmental conditions has been a critical bottleneck to be resolved for commercial use. Here, we demonstrate an extremely stable QD/alumina/polymer hybrid structure by combining internal atomic layer deposition (ALD) infilling with polymer encapsulation. ALD infilling and polymer encapsulation of QDs synergistically prohibit the degradation of QDs in terms of optical, thermal and humid attacks. Our hybrid QD/alumina/polymer film structure showed no noticeable reduction in photoluminescence even in a commercial grade test (85% humidity at 85 ° C) over 28 days. In addition, we successfully fabricated a QD-based light-emitting device with excellent long-term stability by incorporating hybrid QD/alumina/polymer film as a color conversion material on light-emitting diode chips.

  19. ALMA long baseline phase calibration using phase referencing

    NASA Astrophysics Data System (ADS)

    Asaki, Yoshiharu; Matsushita, Satoki; Fomalont, Edward B.; Corder, Stuartt A.; Nyman, Lars-Åke; Dent, William R. F.; Philips, Neil M.; Hirota, Akihiko; Takahashi, Satoko; Vila-Vilaro, Baltasar; Nikolic, Bojan; Hunter, Todd R.; Remijan, Anthony; Vlahakis, Catherine

    2016-08-01

    The Atacama Large Millimeter/submillimeter Array (ALMA) is the world's largest millimeter/submillimeter telescope and provides unprecedented sensitivities and spatial resolutions. To achieve the highest imaging capabilities, interferometric phase calibration for the long baselines is one of the most important subjects: The longer the baselines, the worse the phase stability becomes because of turbulent motions of the Earth's atmosphere, especially, the water vapor in the troposphere. To overcome this subject, ALMA adopts a phase correction scheme using a Water Vapor Radiometer (WVR) to estimate the amount of water vapor content along the antenna line of sight. An additional technique is phase referencing, in which a science target and a nearby calibrator are observed by turn by quickly changing the antenna pointing. We conducted feasibility studies of the hybrid technique with the WVR phase correction and the antenna Fast Switching (FS) phase referencing (WVR+FS phase correction) for the ALMA 16 km longest baselines in cases that (1) the same observing frequency both for a target and calibrator is used, and (2) higher and lower frequencies for a target and calibrator, respectively, with a typical switching cycle time of 20 s. It was found that the phase correction performance of the hybrid technique is promising where a nearby calibrator is located within roughly 3◦ from a science target, and that the phase correction with 20 s switching cycle time significantly improves the performance with the above separation angle criterion comparing to the 120 s switching cycle time. The currently trial phase calibration method shows the same performance independent of the observing frequencies. This result is especially important for the higher frequency observations because it becomes difficult to find a bright calibrator close to an arbitrary sky position. In the series of our experiments, it is also found that phase errors affecting the image quality come from not only the water vapor content in the lower troposphere but also a large structure of the atmosphere with a typical cell scale of a few tens of kilometers.

  20. Stability in the metamemory realism of eyewitness confidence judgments.

    PubMed

    Buratti, Sandra; Allwood, Carl Martin; Johansson, Marcus

    2014-02-01

    The stability of eyewitness confidence judgments over time in regard to their reported memory and accuracy of these judgments is of interest in forensic contexts because witnesses are often interviewed many times. The present study investigated the stability of the confidence judgments of memory reports of a witnessed event and of the accuracy of these judgments over three occasions, each separated by 1 week. Three age groups were studied: younger children (8-9 years), older children (10-11 years), and adults (19-31 years). A total of 93 participants viewed a short film clip and were asked to answer directed two-alternative forced-choice questions about the film clip and to confidence judge each answer. Different questions about details in the film clip were used on each of the three test occasions. Confidence as such did not exhibit stability over time on an individual basis. However, the difference between confidence and proportion correct did exhibit stability across time, in terms of both over/underconfidence and calibration. With respect to age, the adults and older children exhibited more stability than the younger children for calibration. Furthermore, some support for instability was found with respect to the difference between the average confidence level for correct and incorrect answers (slope). Unexpectedly, however, the younger children's slope was found to be more stable than the adults. Compared to the previous research, the present study's use of more advanced statistical methods provides a more nuanced understanding of the stability of confidence judgments in the eyewitness reports of children and adults.

  1. Dissolved oxygen control and monitoring implementation in the liquid lead bismuth eutectic loop: HELIOS

    NASA Astrophysics Data System (ADS)

    Nam, Hyo On; Lim, Jun; Han, Dong Yoon; Hwang, Il Soon

    2008-06-01

    A 12 m tall LBE coolant loop, named as HELIOS, has been developed by thermal-hydraulic scaling of the PEACER-300MWe. Thermo-hydraulic experiment and materials test are the principal purposes of HELIOS operation. In this study, an yttria stabilized zirconia (YSZ) based oxygen sensor that was hermetically sealed for long-term applications using the electromagnetically swaged metal-ceramic joining method, have been developed for high temperature oxygen control application over a long period of time. The rugged electrode design has been calibrated to absolute metal-oxide equilibrium by using a first principle of detecting pure metal-oxide transition using electrochemical impedance spectroscopy (EIS). During the materials tests in HELIOS, dissolved oxygen concentration was administered at the intended condition of 10 -6 wt% by direct gas bubbling with Ar + 4%H 2, Ar + 5%O 2 and/or pure Ar while corrosion tests were conducted for up to 1000 h with inspection after each 333 h. During the total 1000 h corrosion test, oxygen concentration was measured by oxygen sensor. The result confirmed that the direct gas bubbling method is a viable and practical option for controlling oxygen concentration in large loops including HELIOS.

  2. Current and future effects of varicella and herpes zoster vaccination in Germany - Insights from a mathematical model in a country with universal varicella vaccination.

    PubMed

    Horn, Johannes; Karch, André; Damm, Oliver; Kretzschmar, Mirjam E; Siedler, Anette; Ultsch, Bernhard; Weidemann, Felix; Wichmann, Ole; Hengel, Hartmut; Greiner, Wolfgang; Mikolajczyk, Rafael T

    2016-07-02

    Varicella zoster virus (VZV) is primarily known for causing varicella in childhood, but can reactivate again as herpes zoster (HZ) after a period of latency, mainly in persons older than 50 years. Universal varicella vaccination was introduced in Germany in 2004, while HZ vaccination has not been recommended yet. We aimed to quantify the potential long-term effects of universal childhood varicella vaccination and HZ vaccination of the elderly on varicella and HZ incidence in Germany over a time horizon of 100 years, using a transmission model calibrated to pre-vaccination data and validated against early post-vaccination data. Using current vaccination coverage rates of 87% (64%) with one (two) varicella vaccine dose(s), the model predicts a decrease in varicella cases by 89% for the year 2015. In the long run, the incidence reduction will stabilize at about 70%. Under the assumption of the boosting hypothesis of improved HZ protection caused by exposure to VZV, the model predicts a temporary increase in HZ incidence of up to 20% for around 50 years. HZ vaccination of the elderly with an assumed coverage of 20% has only limited effects in counteracting this temporary increase in HZ incidence. However, HZ incidence is shown to decrease in the long-term by 58% as vaccinated individuals get older and finally reach age-classes with originally high HZ incidence. Despite substantial uncertainties around several key variables, the model's results provide valuable insights that support decision-making regarding national VZV vaccination strategies.

  3. Frequency stabilization of an optically pumped far-infrared laser to the harmonic of a microwave synthesizer.

    PubMed

    Danylov, A A; Light, A R; Waldman, J; Erickson, N

    2015-12-10

    Measurements of the frequency stability of a far-infrared molecular laser have been made by mixing the harmonic of an ultrastable microwave source with a portion of the laser output signal in a terahertz (THz) Schottky diode balanced mixer. A 3 GHz difference-frequency signal was used in a frequency discriminator circuit to lock the laser to the microwave source. Comparisons of the short- and long-term laser frequency stability under free-running and locked conditions show a significant improvement with locking. Short-term frequency jitter was reduced by an order of magnitude, from approximately 40 to 4 kHz, and long-term drift was reduced by more than three orders of magnitude, from approximately 250 kHz to 80 Hz. The results, enabled by the efficient Schottky diode balanced mixer downconverter, demonstrate that ultrastable microwave-based frequency stabilization of THz optically pumped lasers (OPLs) will now be possible at frequencies extending well above 4.0 THz.

  4. Tailored interfaces of unencapsulated perovskite solar cells for >1,000 hour operational stability

    DOE PAGES

    Christians, Jeffrey A.; Schulz, Philip; Tinkham, Jonathan S.; ...

    2017-11-28

    Long-term device stability is the most pressing issue that impedes perovskite solar cell commercialization, given the achieved 22.7% efficiency. The perovskite absorber material itself has been heavily scrutinized for being prone to degradation by water, oxygen and ultraviolet light. To date, most reports characterize device stability in the absence of these extrinsic factors. Here we show that, even under the combined stresses of light (including ultraviolet light), oxygen and moisture, perovskite solar cells can retain 94% of peak efficiency despite 1,000 hours of continuous unencapsulated operation in ambient air conditions (relative humidity of 10-20%). Each interface and contact layer throughoutmore » the device stack plays an important role in the overall stability which, when appropriately modified, yields devices in which both the initial rapid decay (often termed burn-in) and the gradual slower decay are suppressed. This extensively modified device architecture and the understanding developed will lead towards durable long-term device performance.« less

  5. Tailored interfaces of unencapsulated perovskite solar cells for >1,000 hour operational stability

    NASA Astrophysics Data System (ADS)

    Christians, Jeffrey A.; Schulz, Philip; Tinkham, Jonathan S.; Schloemer, Tracy H.; Harvey, Steven P.; Tremolet de Villers, Bertrand J.; Sellinger, Alan; Berry, Joseph J.; Luther, Joseph M.

    2018-01-01

    Long-term device stability is the most pressing issue that impedes perovskite solar cell commercialization, given the achieved 22.7% efficiency. The perovskite absorber material itself has been heavily scrutinized for being prone to degradation by water, oxygen and ultraviolet light. To date, most reports characterize device stability in the absence of these extrinsic factors. Here we show that, even under the combined stresses of light (including ultraviolet light), oxygen and moisture, perovskite solar cells can retain 94% of peak efficiency despite 1,000 hours of continuous unencapsulated operation in ambient air conditions (relative humidity of 10-20%). Each interface and contact layer throughout the device stack plays an important role in the overall stability which, when appropriately modified, yields devices in which both the initial rapid decay (often termed burn-in) and the gradual slower decay are suppressed. This extensively modified device architecture and the understanding developed will lead towards durable long-term device performance.

  6. Calibration of GafChromic EBT3 for absorbed dose measurements in 5 MeV proton beam and (60)Co γ-rays.

    PubMed

    Vadrucci, M; Esposito, G; Ronsivalle, C; Cherubini, R; Marracino, F; Montereali, R M; Picardi, L; Piccinini, M; Pimpinella, M; Vincenti, M A; De Angelis, C

    2015-08-01

    To study EBT3 GafChromic film in low-energy protons, and for comparison purposes, in a reference (60)Co beam in order to use it as a calibrated dosimetry system in the proton irradiation facility under construction within the framework of the Oncological Therapy with Protons (TOP)-Intensity Modulated Proton Linear Accelerator for RadioTherapy (IMPLART) Project at ENEA-Frascati, Italy. EBT3 film samples were irradiated at the Istituto Nazionale di Fisica Nucleare-Laboratori Nazionali di Legnaro, Italy, with a 5 MeV proton beam generated by a 7 MV Van de Graaff CN accelerator. The nominal dose rates used were 2.1 Gy/min and 40 Gy/min. The delivered dose was determined by measuring the particle fluence and the energy spectrum in air with silicon surface barrier detector monitors. A preliminary study of the EBT3 film beam quality dependence in low-energy protons was conducted by passively degrading the beam energy. EBT3 films were also irradiated at ENEA-National Institute of Ionizing Radiation Metrology with gamma radiation produced by a (60)Co source characterized by an absorbed dose to water rate of 0.26 Gy/min as measured by a calibrated Farmer type ionization chamber. EBT3 film calibration curves were determined by means of a set of 40 film pieces irradiated to various doses ranging from 0.5 Gy to 30 Gy absorbed dose to water. An EPSON Expression 11000XL color scanner in transmission mode was used for film analysis. Scanner response stability, intrafilm uniformity, and interfilm reproducibility were verified. Optical absorption spectra measurements were performed on unirradiated and irradiated EBT3 films to choose the most sensitive color channel to the dose range used. EBT3 GafChromic films show an under response up to about 33% for low-energy protons with respect to (60)Co gamma radiation, which is consistent with the linear energy transfer dependence already observed with higher energy protons, and a negligible dose-rate dependence in the 2-40 Gy/min range. Short- and long-term scanner stabilities were 0.5% and 1.5%, respectively; film uniformity and reproducibility were better than 0.5%. The main purpose of this study was to implement EBT3 dosimetry in the proton low-energy radiobiology line of the TOP-IMPLART accelerator, having a maximum energy of 7 MeV. Low-energy proton and (60)Co calibrated sources were used to investigate the behavior of film response vs to be written in italicum dose. The calibration in 5 MeV protons is currently used for dose assessment in the radiobiological experiments at the TOP-IMPLART accelerator carried out at that energy value.

  7. Uncertainty quantification for constitutive model calibration of brain tissue.

    PubMed

    Brewick, Patrick T; Teferra, Kirubel

    2018-05-31

    The results of a study comparing model calibration techniques for Ogden's constitutive model that describes the hyperelastic behavior of brain tissue are presented. One and two-term Ogden models are fit to two different sets of stress-strain experimental data for brain tissue using both least squares optimization and Bayesian estimation. For the Bayesian estimation, the joint posterior distribution of the constitutive parameters is calculated by employing Hamiltonian Monte Carlo (HMC) sampling, a type of Markov Chain Monte Carlo method. The HMC method is enriched in this work to intrinsically enforce the Drucker stability criterion by formulating a nonlinear parameter constraint function, which ensures the constitutive model produces physically meaningful results. Through application of the nested sampling technique, 95% confidence bounds on the constitutive model parameters are identified, and these bounds are then propagated through the constitutive model to produce the resultant bounds on the stress-strain response. The behavior of the model calibration procedures and the effect of the characteristics of the experimental data are extensively evaluated. It is demonstrated that increasing model complexity (i.e., adding an additional term in the Ogden model) improves the accuracy of the best-fit set of parameters while also increasing the uncertainty via the widening of the confidence bounds of the calibrated parameters. Despite some similarity between the two data sets, the resulting distributions are noticeably different, highlighting the sensitivity of the calibration procedures to the characteristics of the data. For example, the amount of uncertainty reported on the experimental data plays an essential role in how data points are weighted during the calibration, and this significantly affects how the parameters are calibrated when combining experimental data sets from disparate sources. Published by Elsevier Ltd.

  8. Relationship of physiography and snow area to stream discharge. [Kings River Watershed, California

    NASA Technical Reports Server (NTRS)

    Mccuen, R. H. (Principal Investigator)

    1979-01-01

    The author has identified the following significant results. A comparison of snowmelt runoff models shows that the accuracy of the Tangborn model and regression models is greater if the test data falls within the range of calibration than if the test data lies outside the range of calibration data. The regression models are significantly more accurate for forecasts of 60 days or more than for shorter prediction periods. The Tangborn model is more accurate for forecasts of 90 days or more than for shorter prediction periods. The Martinec model is more accurate for forecasts of one or two days than for periods of 3,5,10, or 15 days. Accuracy of the long-term models seems to be independent of forecast data. The sufficiency of the calibration data base is a function not only of the number of years of record but also of the accuracy with which the calibration years represent the total population of data years. Twelve years appears to be a sufficient length of record for each of the models considered, as long as the twelve years are representative of the population.

  9. Automatic estimation of aquifer parameters using long-term water supply pumping and injection records

    NASA Astrophysics Data System (ADS)

    Luo, Ning; Illman, Walter A.

    2016-09-01

    Analyses are presented of long-term hydrographs perturbed by variable pumping/injection events in a confined aquifer at a municipal water-supply well field in the Region of Waterloo, Ontario (Canada). Such records are typically not considered for aquifer test analysis. Here, the water-level variations are fingerprinted to pumping/injection rate changes using the Theis model implemented in the WELLS code coupled with PEST. Analyses of these records yield a set of transmissivity ( T) and storativity ( S) estimates between each monitoring and production borehole. These individual estimates are found to poorly predict water-level variations at nearby monitoring boreholes not used in the calibration effort. On the other hand, the geometric means of the individual T and S estimates are similar to those obtained from previous pumping tests conducted at the same site and adequately predict water-level variations in other boreholes. The analyses reveal that long-term municipal water-level records are amenable to analyses using a simple analytical solution to estimate aquifer parameters. However, uniform parameters estimated with analytical solutions should be considered as first rough estimates. More accurate hydraulic parameters should be obtained by calibrating a three-dimensional numerical model that rigorously captures the complexities of the site with these data.

  10. EO-1 Hyperion reflectance time series at calibration and validation sites: stability and sensitivity to seasonal dynamics

    Treesearch

    Petya K. Entcheva Campbell; Elizabeth M. Middleton; Kurt J. Thome; Raymond F. Kokaly; Karl Fred Huemmrich; David Lagomasino; Kimberly A. Novick; Nathaniel A. Brunsell

    2013-01-01

    This study evaluated Earth Observing 1 (EO-1) Hyperion reflectance time series at established calibration sites to assess the instrument stability and suitability for monitoring vegetation functional parameters. Our analysis using three pseudo-invariant calibration sites in North America indicated that the reflectance time series are devoid of apparent spectral trends...

  11. Comprehensive laboratory and field testing of cavity ring-down spectroscopy analyzers measuring H2O, CO2, CH4 and CO

    NASA Astrophysics Data System (ADS)

    Yver Kwok, C.; Laurent, O.; Guemri, A.; Philippon, C.; Wastine, B.; Rella, C. W.; Vuillemin, C.; Truong, F.; Delmotte, M.; Kazan, V.; Darding, M.; Lebègue, B.; Kaiser, C.; Xueref-Rémy, I.; Ramonet, M.

    2015-09-01

    To develop an accurate measurement network of greenhouse gases, instruments in the field need to be stable and precise and thus require infrequent calibrations and a low consumption of consumables. For about 10 years, cavity ring-down spectroscopy (CRDS) analyzers have been available that meet these stringent requirements for precision and stability. Here, we present the results of tests of CRDS instruments in the laboratory (47 instruments) and in the field (15 instruments). The precision and stability of the measurements are studied. We demonstrate that, thanks to rigorous testing, newer models generally perform better than older models, especially in terms of reproducibility between instruments. In the field, we see the importance of individual diagnostics during the installation phase, and we show the value of calibration and target gases that assess the quality of the data. Finally, we formulate recommendations for use of these analyzers in the field.

  12. Comprehensive laboratory and field testing of cavity ring-down spectroscopy analyzers measuring H2O, CO2, CH4 and CO

    NASA Astrophysics Data System (ADS)

    Yver Kwok, C.; Laurent, O.; Guemri, A.; Philippon, C.; Wastine, B.; Rella, C. W.; Vuillemin, C.; Truong, F.; Delmotte, M.; Kazan, V.; Darding, M.; Lebègue, B.; Kaiser, C.; Ramonet, M.

    2015-04-01

    To develop an accurate measurement network of greenhouse gases, instruments in the field need to be stable and precise and thus require infrequent calibrations and a low consumption of consumables. For about ten years, cavity ring-down spectroscopy (CRDS) analyzers have been available that meet these stringent requirements for precision and stability. Here, we present the results of tests of CRDS instruments in the laboratory (47 instruments) and in the field (15 instruments). The precision and stability of the measurements are studied. We demonstrate that, thanks to rigorous testing, newer models generally perform better than older models, especially in terms of reproducibility between instruments. In the field, we see the importance of individual diagnostics during the installation phase, and we show the value of calibration and target gases that assess the quality of the data. Finally, we formulate recommendations for use of these analyzers in the field.

  13. Leveraging Venture Capital and Commercial Business: Enhancing Stability Operations

    DTIC Science & Technology

    2011-03-24

    Economic Stability Operations have emerged as a new element of United States national strategic power. The creation of jobs, through commercial...examine the key strategic factors influencing long-term economic stability following the withdrawal of combat forces. This paper provides a model for

  14. Catchment-scale modeling of nitrogen dynamics in a temperate forested watershed, Oregon. An interdisciplinary communication strategy.

    Treesearch

    Kellie Vache; Lutz Breuer; Julia Jones; Phil Sollins

    2015-01-01

    We present a systems modeling approach to the development of a place-based ecohydrological model. The conceptual model is calibrated to a variety of existing observations, taken in watershed 10 (WS10) at the HJ Andrews Experimental Forest (HJA) in Oregon, USA, a long term ecological research (LTER) site with a long history of catchment-...

  15. Atomic References for Measuring Small Accelerations

    NASA Technical Reports Server (NTRS)

    Maleki, Lute; Yu, Nan

    2009-01-01

    Accelerometer systems that would combine the best features of both conventional (e.g., mechanical) accelerometers and atom interferometer accelerometers (AIAs) have been proposed. These systems are intended mainly for use in scientific research aboard spacecraft but may also be useful on Earth in special military, geological, and civil-engineering applications. Conventional accelerometers can be sensitive, can have high dynamic range, and can have high frequency response, but they lack accuracy and long-term stability. AIAs have low frequency response, but they offer high sensitivity, and high accuracy for measuring small accelerations. In a system according to the proposal, a conventional accelerometer would be used to perform short-term measurements of higher-frequency components of acceleration, while an AIA would be used to provide consistent calibration of, and correction of errors in, the measurements of the conventional accelerometer in the lower-frequency range over the long term. A brief description of an AIA is prerequisite to a meaningful description of a system according to the proposal. An AIA includes a retroreflector next to one end of a cell that contains a cold cloud of atoms in an ultrahigh vacuum. The atoms in the cloud are in free fall. The retroreflector is mounted on the object, the acceleration of which is to be measured. Raman laser beams are directed through the cell from the end opposite the retroreflector, then pass back through the cell after striking the retroreflector. The Raman laser beams together with the cold atoms measure the relative acceleration, through the readout of the AIA, between the cold atoms and the retroreflector.

  16. Long-term manure amendments reduced soil aggregate stability via redistribution of the glomalin-related soil protein in macroaggregates

    PubMed Central

    Xie, Hongtu; Li, Jianwei; Zhang, Bin; Wang, Lianfeng; Wang, Jingkuan; He, Hongbo; Zhang, Xudong

    2015-01-01

    Glomalin-related soil protein (GRSP) contributes to the formation and maintenance of soil aggregates, it is however remains unclear whether long-term intensive manure amendments alter soil aggregates stability and whether GRSP regulates these changes. Based on a three-decade long fertilization experiment in northeast China, this study examined the impact of long-term manure input on soil organic carbon (SOC), total and easily extractable GRSP (GRSPt and GRSPe) and their respective allocations in four soil aggregates (>2000 μm; 2000–250 μm; 250–53 μm; and <53 μm). The treatments include no fertilization (CK), low and high manure amendment (M1, M2), chemical nitrogen, phosphorus and potassium fertilizers (NPK), and combined manure and chemical fertilizers (NPKM1, NPKM2). Though SOC, GRSPe and GRSPt in soil and SOC in each aggregate generally increased with increasing manure input, GRSPt and GRSPe in each aggregate showed varying changes with manure input. Both GRSP in macroaggregates (2000–250 μm) were significantly higher under low manure input, a pattern consistent with changes in soil aggregate stability. Constituting 38~49% of soil mass, macroaggregates likely contributed to the nonlinear changes of aggregate stability under manure amendments. The regulatory process of GRSP allocations in soil aggregates has important implications for manure management under intensive agriculture. PMID:26423355

  17. Long-term actuarial survivorship analysis of an interspinous stabilization system

    PubMed Central

    Sénégas, Jacques; Pointillart, Vincent; Mangione, Paolo

    2007-01-01

    In 1986, an interspinous dynamic stabilization system (the prototype of the current Wallis implant) was designed to stiffen unstable operated degenerate lumbar segments with a hard interspinous blocker to limit extension and a tension band around the spinous processes to secure the implant and limit flexion. Restoring physiological mechanical conditions to the treated level(s) while preserving some intervertebral mobility was intended to treat low-back pain related to degenerative instability without increasing stress forces in the adjacent segments. The procedure was easily reversible. If low back pain persisted or recurred, the device was removed and stability was achieved using fusion. The intermediate-term results were promising, but the long-term safety and efficacy of this dynamic interspinous stabilization device has not been previously documented. We retrospectively reviewed the hospital files of all the patients (n = 241) who had this dynamic stabilization system implanted between 1987 and 1995, contacting as many as possible to determine the actuarial survivorship of the system. In this manner, 142 of the 241 patients (58.9%) were contacted by telephone. The endpoints used for the survivorship analysis were ‘any subsequent lumbar operation’ and ‘implant removal’. At 14 years follow-up, values of actuarial survivorship with 95% confidence interval were 75.9 ± 8.3 and 81.3 ± 6.8% for the endpoints ‘any subsequent lumbar operation’ and ‘implant removal’, respectively. There was no difference in survivorship of multiple-level implants with respect to single-level devices. Although the conclusions of the present study must be tempered by the 41% attrition rate, these findings support the long-term safety of this system, and possibly long-term protective action against adjacent-level degeneration by motion preservation. Outcomes at least equivalent to those of fusion were observed without the primary drawbacks of fusion. PMID:17426988

  18. Long-Term Dynamics of Autonomous Fractional Differential Equations

    NASA Astrophysics Data System (ADS)

    Liu, Tao; Xu, Wei; Xu, Yong; Han, Qun

    This paper aims to investigate long-term dynamic behaviors of autonomous fractional differential equations with effective numerical method. The long-term dynamic behaviors predict where systems are heading after long-term evolution. We make some modification and transplant cell mapping methods to autonomous fractional differential equations. The mapping time duration of cell mapping is enlarged to deal with the long memory effect. Three illustrative examples, i.e. fractional Lotka-Volterra equation, fractional van der Pol oscillator and fractional Duffing equation, are studied with our revised generalized cell mapping method. We obtain long-term dynamics, such as attractors, basins of attraction, and saddles. Compared with some existing stability and numerical results, the validity of our method is verified. Furthermore, we find that the fractional order has its effect on the long-term dynamics of autonomous fractional differential equations.

  19. Meteorological fluctuations define long-term crop yield patterns in conventional and organic production systems

    USDA-ARS?s Scientific Manuscript database

    Periodic variability in meteorological patterns presents significant challenges to crop production consistency and yield stability. Meteorological influences on corn and soybean grain yields were analyzed over an 18-year period at a long-term experiment in Beltsville, Maryland, U.S.A., comparing c...

  20. 41 CFR 51-6.3 - Long-term procurements.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 1 2010-07-01 2010-07-01 true Long-term procurements. 51-6.3 Section 51-6.3 Public Contracts and Property Management Other Provisions Relating to Public... ensure stability of employment and development of job skills for persons who are blind or have other...

  1. Accelerated long-term assessment of thermal and chemical stability of bio-based phase change materials

    USDA-ARS?s Scientific Manuscript database

    Thermal energy storage (TES) systems incorporated with phase change materials (PCMs) have potential applications to control energy use by building envelopes. However, it is essential to evaluate long term performance of the PCMs and cost effectiveness prior to full scale implementation. For this rea...

  2. Continuous Odour Measurement with Chemosensor Systems

    NASA Astrophysics Data System (ADS)

    Boeker, Peter; Haas, T.; Diekmann, B.; Lammer, P. Schulze

    2009-05-01

    The continuous odour measurement is a challenging task for chemosensor systems. Firstly, a long term and stable measurement mode must be guaranteed in order to preserve the validity of the time consuming and expensive olfactometric calibration data. Secondly, a method is needed to deal with the incoming sensor data. The continuous online detection of signal patterns, the correlated gas emission and the assigned odour data is essential for the continuous odour measurement. Thirdly, a severe danger of over-fitting in the process of the odour calibration is present, because of the high measurement uncertainty of the olfactometry. In this contribution we present a technical solution for continuous measurements comprising of a hybrid QMB-sensor array and electrochemical cells. A set of software tools enables the efficient data processing and calibration and computes the calibration parameters. The internal software of the measurement systems microcontroller processes the calibration parameters online for the output of the desired odour information.

  3. Nimbus-7 TOMS Version 7 Calibration

    NASA Technical Reports Server (NTRS)

    Wellemeyer, C. G.; Taylor, S. L.; Jaross, G.; DeLand, M. T.; Seftor, C. J.; Labow, G.; Swissler, T. J.; Cebula, R. P.

    1996-01-01

    This report describes an improved instrument characterization used for the Version 7 processing of the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) data record. An improved internal calibration technique referred to as spectral discrimination is used to provide long-term calibration precision of +/- 1%/decade in total column ozone amount. A revised wavelength scale results in a day one calibration that agrees with other satellite and ground-based measurements of total ozone, while a wavelength independent adjustment of the initial radiometric calibration constants provides good agreement with surface reflectivity measured by other satellite-borne ultraviolet measurements. The impact of other aspects of the Nimbus-7 TOMS instrument performance are also discussed. The Version 7 data should be used in all future studies involving the Nimbus-7 TOMS measurements of ozone. The data are available through the NASA Goddard Space Flight Center's Distributive Active Archive Center (DAAC).

  4. Stability of the Medial Olivocochlear Reflex as Measured by Distortion Product Otoacoustic Emissions

    PubMed Central

    Abdala, Carolina

    2015-01-01

    Purpose The purpose of this study was to assess the repeatability of a fine-resolution, distortion product otoacoustic emission (DPOAE)–based assay of the medial olivocochlear (MOC) reflex in normal-hearing adults. Method Data were collected during 36 test sessions from 4 normal-hearing adults to assess short-term stability and 5 normal-hearing adults to assess long-term stability. DPOAE level and phase measurements were recorded with and without contralateral acoustic stimulation. MOC reflex indices were computed by (a) noting contralateral acoustic stimulation-induced changes in DPOAE level (both absolute and normalized) at fine-structure peaks, (b) recording the effect as a vector difference, and (c) separating DPOAE components and considering a component-specific metric. Results Analyses indicated good repeatability of all indices of the MOC reflex in most frequency ranges. Short- and long-term repeatability were generally comparable. Indices normalized to a subject's own baseline fared best, showing strong short- and long-term stability across all frequency intervals. Conclusions These results suggest that fine-resolution DPOAE-based measures of the MOC reflex measured at strategic frequencies are stable, and natural variance from day-to-day or week-to-week durations is small enough to detect between-group differences and possibly to monitor intervention-related success. However, this is an empirical question that must be directly tested to confirm its utility. PMID:25320951

  5. Measuring night sky brightness: methods and challenges

    NASA Astrophysics Data System (ADS)

    Hänel, Andreas; Posch, Thomas; Ribas, Salvador J.; Aubé, Martin; Duriscoe, Dan; Jechow, Andreas; Kollath, Zoltán; Lolkema, Dorien E.; Moore, Chadwick; Schmidt, Norbert; Spoelstra, Henk; Wuchterl, Günther; Kyba, Christopher C. M.

    2018-01-01

    Measuring the brightness of the night sky has become an increasingly important topic in recent years, as artificial lights and their scattering by the Earth's atmosphere continue spreading around the globe. Several instruments and techniques have been developed for this task. We give an overview of these, and discuss their strengths and limitations. The different quantities that can and should be derived when measuring the night sky brightness are discussed, as well as the procedures that have been and still need to be defined in this context. We conclude that in many situations, calibrated consumer digital cameras with fisheye lenses provide the best relation between ease-of-use and wealth of obtainable information on the night sky. While they do not obtain full spectral information, they are able to sample the complete sky in a period of minutes, with colour information in three bands. This is important, as given the current global changes in lamp spectra, changes in sky radiance observed only with single band devices may lead to incorrect conclusions regarding long term changes in sky brightness. The acquisition of all-sky information is desirable, as zenith-only information does not provide an adequate characterization of a site. Nevertheless, zenith-only single-band one-channel devices such as the "Sky Quality Meter" continue to be a viable option for long-term studies of night sky brightness and for studies conducted from a moving platform. Accurate interpretation of such data requires some understanding of the colour composition of the sky light. We recommend supplementing long-term time series derived with such devices with periodic all-sky sampling by a calibrated camera system and calibrated luxmeters or luminance meters.

  6. Implementation of a Water Heat Pipe at CETIAT

    NASA Astrophysics Data System (ADS)

    Favreau, J. O.; Georgin, E.; Savanier, B.; Merlone, A.

    2017-12-01

    CETIAT's calibration laboratory, accredited by COFRAC, is a secondary thermometry laboratory. It uses overflow and stirred calibration baths (from - 80 {°}C up to + 215 {°}C), dry blocks and furnaces (from + 100 {°}C up to + 1050 {°}C) and thermostatic chambers (from - 30 {°}C up to + 160 {°}C). Typical calibration uncertainties that can be reached for platinum resistance thermometers in a thermostatic bath are between 0.03 {°}C and 0.06 {°}C. In order to improve its calibration capabilities, CETIAT is working on the implementation of a gas-controlled heat pipe (GCHP) temperature generator, used for industrial sensor calibrations. This article presents the results obtained during the characterization of water GCHP for industrial applications. This is a new approach to the use of a heat pipe as a temperature generator for industrial sensor calibrations. The objective of this work is to improve measurement uncertainties and daily productivity. Indeed, as has been shown in many studies (Dunn and Reay in Heat Pipes, Pergamon Press, Oxford, 1976; Merlone et al. 2012), the temperature of the system is pressure dependent and the response time, in temperature, follows the pressure accordingly. Thanks to this generator, it is possible to perform faster calibrations with smaller uncertainties. In collaboration with INRiM, the GCHP developed at CETIAT works with water and covers a temperature range from + 30 {°}C up to + 150 {°}C. This device includes some improvements such as a removable cover, which allows us to have different sets of thermometric wells adjustable according to the probe to be calibrated, and a pressure controller based on a temperature sensor. This article presents the metrological characterization in terms of homogeneity and stability in temperature. A rough investigation of the response time of the system is also presented in order to evaluate the time for reaching thermal equilibrium. The results obtained in this study concern stability and thermal homogeneity. The homogeneity on 200 mm is better than 5 mK and with a calibration uncertainty reduced by a factor of three.

  7. SCALA: In situ calibration for integral field spectrographs

    NASA Astrophysics Data System (ADS)

    Lombardo, S.; Küsters, D.; Kowalski, M.; Aldering, G.; Antilogus, P.; Bailey, S.; Baltay, C.; Barbary, K.; Baugh, D.; Bongard, S.; Boone, K.; Buton, C.; Chen, J.; Chotard, N.; Copin, Y.; Dixon, S.; Fagrelius, P.; Feindt, U.; Fouchez, D.; Gangler, E.; Hayden, B.; Hillebrandt, W.; Hoffmann, A.; Kim, A. G.; Leget, P.-F.; McKay, L.; Nordin, J.; Pain, R.; Pécontal, E.; Pereira, R.; Perlmutter, S.; Rabinowitz, D.; Reif, K.; Rigault, M.; Rubin, D.; Runge, K.; Saunders, C.; Smadja, G.; Suzuki, N.; Taubenberger, S.; Tao, C.; Thomas, R. C.; Nearby Supernova Factory

    2017-11-01

    Aims: The scientific yield of current and future optical surveys is increasingly limited by systematic uncertainties in the flux calibration. This is the case for type Ia supernova (SN Ia) cosmology programs, where an improved calibration directly translates into improved cosmological constraints. Current methodology rests on models of stars. Here we aim to obtain flux calibration that is traceable to state-of-the-art detector-based calibration. Methods: We present the SNIFS Calibration Apparatus (SCALA), a color (relative) flux calibration system developed for the SuperNova integral field spectrograph (SNIFS), operating at the University of Hawaii 2.2 m (UH 88) telescope. Results: By comparing the color trend of the illumination generated by SCALA during two commissioning runs, and to previous laboratory measurements, we show that we can determine the light emitted by SCALA with a long-term repeatability better than 1%. We describe the calibration procedure necessary to control for system aging. We present measurements of the SNIFS throughput as estimated by SCALA observations. Conclusions: The SCALA calibration unit is now fully deployed at the UH 88 telescope, and with it color-calibration between 4000 Å and 9000 Å is stable at the percent level over a one-year baseline.

  8. Long-term data archiving

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Moore, David Steven

    2009-01-01

    Long term data archiving has much value for chemists, not only to retain access to research and product development records, but also to enable new developments and new discoveries. There are some recent regulatory requirements (e.g., FDA 21 CFR Part 11), but good science and good business both benefit regardless. A particular example of the benefits of and need for long term data archiving is the management of data from spectroscopic laboratory instruments. The sheer amount of spectroscopic data is increasing at a scary rate, and the pressures to archive come from the expense to create the data (or recreatemore » it if it is lost) as well as its high information content. The goal of long-term data archiving is to save and organize instrument data files as well as any needed meta data (such as sample ID, LIMS information, operator, date, time, instrument conditions, sample type, excitation details, environmental parameters, etc.). This editorial explores the issues involved in long-term data archiving using the example of Raman spectral databases. There are at present several such databases, including common data format libraries and proprietary libraries. However, such databases and libraries should ultimately satisfy stringent criteria for long term data archiving, including readability for long times into the future, robustness to changes in computer hardware and operating systems, and use of public domain data formats. The latter criterion implies the data format should be platform independent and the tools to create the data format should be easily and publicly obtainable or developable. Several examples of attempts at spectral libraries exist, such as the ASTM ANDI format, and the JCAMP-DX format. On the other hand, proprietary library spectra can be exchanged and manipulated using proprietary tools. As the above examples have deficiencies according to the three long term data archiving criteria, Extensible Markup Language (XML; a product of the World Wide Web Consortium, an independent standards body) as a new data interchange tool is being investigated and implemented. In order to facilitate data archiving, Raman data needs calibration as well as some other kinds of data treatment. Figure 1 illustrates schematically the present situation for Raman data calibration in the world-wide Raman spectroscopy community, and presents some of the terminology used.« less

  9. Aggregate Stability of Tropical Soils Under Long-Term Eucalyptus Cultivation

    USDA-ARS?s Scientific Manuscript database

    Eucalyptus cultivation has increased in all Brazilian regions. Despite the large amount of cultivated area, little is known about how this kind of management system affects soil properties, mainly the aggregate stability. Aggregate stability analyses have proved to be a sensitive tool to measure soi...

  10. Long-term stabilization of place cell remapping produced by a fearful experience

    PubMed Central

    Wang, Melissa E.; Wann, Ellen G.; Yuan, Robin K.; Ramos Álvarez, Manuel M.; Stead, Squire M.; Muzzio, Isabel A.

    2012-01-01

    Fear is an emotional response to danger that is highly conserved throughout evolution because it is critical for survival. Accordingly, episodic memory for fearful locations is widely studied using contextual fear conditioning, a hippocampus-dependent task (Kim and Fanselow, 1992; Phillips and LeDoux, 1992). The hippocampus has been implicated in episodic emotional memory and is thought to integrate emotional stimuli within a spatial framework. Physiological evidence supporting the role of the hippocampus in contextual fear indicates that pyramidal cells in this region, which fire in specific locations as an animal moves through an environment, shift their preferred firing locations shortly after the presentation of an aversive stimulus (Moita et al., 2004). However, the long-term physiological mechanisms through which emotional memories are encoded by the hippocampus are unknown. Here we show that during and directly after a fearful experience, new hippocampal representations are established and persist in the long term. We recorded from the same place cells in mouse hippocampal area CA1 over several days during predator odor contextual fear conditioning and found that a subset of cells changed their preferred firing locations in response to the fearful stimulus. Furthermore, the newly formed representations of the fearful context stabilized in the long term. Our results demonstrate that place cells respond to the presence of an aversive stimulus, modify their firing patterns during emotional learning, and stabilize a long-term spatial representation in response to a fearful encounter. The persistent nature of these representations may contribute to the enduring quality of emotional memories. PMID:23136419

  11. Static Stability in the Global Upper Troposphere and Lower Stratosphere: Observations of Long-term Mean Structure and Variability using GPS Radio Occultation Data

    NASA Astrophysics Data System (ADS)

    Grise, K. M.; Thompson, D. W.; Birner, T.

    2009-12-01

    Static stability is a fundamental dynamical quantity that measures the vertical temperature stratification of the atmosphere. The long-term mean static stability field is characterized by the well-known transition from low values in the troposphere to high values in the stratosphere. However, the magnitude and structure of fine-scale static stability features near the tropopause are difficult to discern in temperature data with low vertical resolution. In this study, the authors apply over six years of high vertical resolution Global Positioning System radio occultation temperature profiles to document the long-term mean structure and variability of static stability in the global upper troposphere and lower stratosphere (UTLS). The results of this study demonstrate that a shallow but pronounced maximum in static stability exists just above the tropopause at all latitudes (i.e., the “tropopause inversion layer,” or TIL). This study also uncovers two novel aspects of static stability in the global UTLS. In the tropical lower stratosphere, the results reveal a unique vertically and horizontally varying static stability structure, with maxima located at ~17 km and ~19 km. The upper feature peaks during the NH cold season and has its largest magnitude between 10 and 15 degrees latitude in both hemispheres; the lower feature exhibits a weaker seasonal cycle and is centered at the Equator. The results also demonstrate that the strength of the TIL is closely tied to stratospheric dynamic variability. The magnitude of the TIL is enhanced following sudden stratospheric warmings in the polar regions and the easterly phase of the quasi-biennial oscillation in the tropics.

  12. Static Stability in the Global Upper Troposphere and Lower Stratosphere: Observations of Long-term Mean Structure and Variability using GPS Radio Occultation Data

    NASA Astrophysics Data System (ADS)

    Grise, Kevin M.; Thompson, David W. J.; Birner, Thomas

    2010-05-01

    Static stability is a fundamental dynamical quantity that measures the vertical temperature stratification of the atmosphere. The long-term mean static stability field is characterized by the well-known transition from low values in the troposphere to high values in the stratosphere. However, the magnitude and structure of fine-scale static stability features near the tropopause are difficult to discern in temperature data with low vertical resolution. In this study, the authors apply over six years of high vertical resolution Global Positioning System radio occultation temperature profiles to document the long-term mean structure and variability of static stability in the global upper troposphere and lower stratosphere (UTLS). The results of this study demonstrate that a shallow but pronounced maximum in static stability exists just above the tropopause at all latitudes (i.e., the "tropopause inversion layer," or TIL). This study also uncovers two novel aspects of static stability in the global UTLS. In the tropical lower stratosphere, the results reveal a unique vertically and horizontally varying static stability structure, with maxima located at ~17 km and ~19 km. The upper feature peaks during the NH cold season and has its largest magnitude between 10 and 15 degrees latitude in both hemispheres; the lower feature exhibits a weaker seasonal cycle and is centered at the Equator. The results also demonstrate that the strength of the TIL is closely tied to stratospheric dynamic variability. The magnitude of the TIL is enhanced following sudden stratospheric warmings in the polar regions and the easterly phase of the quasi-biennial oscillation in the tropics.

  13. Long-term surgical-orthodontic management of hemimandibular hyperplasia.

    PubMed

    Bennett, Samuel C; Goonewardene, Mithran S

    2016-05-01

    Hemimandibular hyperplasia (HH), also known as hemimandibular hypertrophy, is characterised by excessive unilateral three-dimensional growth of the mandible after birth. Vertical unilateral elongation of the mandible becomes clinically evident as a rare form of vertical facial asymmetry. Aberrant growth of the facial skeleton affects the developing dentition and the dental compensatory mechanism is usually unable to maintain optimal occlusal relationships. The resulting malocclusion is effectively managed by combined surgical-orthodontic care to address the facial, skeletal and dental problems that confront clinicians. Orthodontists are advised to assess patients with HH during the post-treatment retention stage for continuing mandibular growth and assess the stability of treatment outcomes with long-term follow-up and records as required. To present a case of hemimandibular hyperplasia treated successfully by combined surgical-orthodontic care and evaluated for stability over a seven-year follow-up period. Surgical-orthodontic management was accomplished in four stages: 1) pre-surgical orthodontic; 21 surgical; 3) post-surgical orthodontic; and 4) post-treatment orthodontic retention. Complete orthodontic records, including extra- and intra-oral photographs, study models, and cephalograms plus panoramic radiographs were taken at the pretreatment, post-treatment, and seven-year orthodontic retention time-points. Facial, skeletal and dental goals were achieved in the three planes of space and the long-term stability of the treatment results was shown during a post-treatment orthodontic retention period of seven years. Hemimandibular hyperplasia is a true growth anomaly which may be managed effectively. Clinicians may expect successful long-term correction and stability by utilising a comprehensive surgical-orthodontic treatment approach.

  14. Dual-Function Au@Y2O3:Eu3+ Smart Film for Enhanced Power Conversion Efficiency and Long-Term Stability of Perovskite Solar Cells.

    PubMed

    Kim, Chang Woo; Eom, Tae Young; Yang, In Seok; Kim, Byung Su; Lee, Wan In; Kang, Yong Soo; Kang, Young Soo

    2017-07-28

    In the present study, a dual-functional smart film combining the effects of wavelength conversion and amplification of the converted wave by the localized surface plasmon resonance has been investigated for a perovskite solar cell. This dual-functional film, composed of Au nanoparticles coated on the surface of Y 2 O 3 :Eu 3+ phosphor (Au@Y 2 O 3 :Eu 3+ ) nanoparticle monolayer, enhances the solar energy conversion efficiency to electrical energy and long-term stability of photovoltaic cells. Coupling between the Y 2 O 3 :Eu 3+ phosphor monolayer and ultraviolet solar light induces the latter to be converted into visible light with a quantum yield above 80%. Concurrently, the Au nanoparticle monolayer on the phosphor nanoparticle monolayer amplifies the converted visible light by up to 170%. This synergy leads to an increased solar light energy conversion efficiency of perovskite solar cells. Simultaneously, the dual-function film suppresses the photodegradation of perovskite by UV light, resulting in long-term stability. Introducing the hybrid smart Au@Y 2 O 3 :Eu 3+ film in perovskite solar cells increases their overall solar-to-electrical energy conversion efficiency to 16.1% and enhances long-term stability, as compared to the value of 15.2% for standard perovskite solar cells. The synergism between the wavelength conversion effect of the phosphor nanoparticle monolayer and the wave amplification by the localized surface plasmon resonance of the Au nanoparticle monolayer in a perovskite solar cell is comparatively investigated, providing a viable strategy of broadening the solar spectrum utilization.

  15. Infiltration in layered loessial deposits: Revised numerical simulations and recharge assessment

    NASA Astrophysics Data System (ADS)

    Dafny, Elad; Šimůnek, Jirka

    2016-07-01

    The objective of this study is to assess recharge rates and their timing under layered loessial deposits at the edge of arid zones. Particularly, this study is focused on the case of the coastal plain of Israel and Gaza. First, results of a large-scale field infiltration test were used to calibrate the van Genuchten parameters of hydraulic properties of the loessial sediments using HYDRUS (2D/3D). Second, optimized soil hydraulic parameters were used by HYDRUS-1D to simulate the water balance of the sandy-loess sediments during a 25-year period (1990-2015) for three environmental conditions: bare soil, and soil with both sparse and dense natural vegetation. The best inverse parameter optimization run fitted the infiltration test data with the RMSE of 0.27 d (with respect to a moisture front arrival) and R2 of 96%. The calibrated model indicates that hydraulic conductivities of the two soil horizons, namely sandy loam and sandy clay loam, are 81 cm/d and 17.5 cm/d, respectively. These values are significantly lower than those previously reported, based on numerical simulations, for the same site. HYDRUS-1D simulation of natural recharge under bare soil resulted in recharge estimates (to the aquifer) in the range of 21-93 mm/yr, with an average recharge of 63 mm/yr. Annual precipitation in the same period varied between 100 and 300 mm/yr, with an average of 185 mm/yr. For semi-stabilized dunes, with 26% of the soil surface covered by local shrub (Artemisia monosperma), the mean annual recharge was 28 mm. For the stabilized landscape, with as much as 50% vegetation coverage, it was only 2-3 mm/yr. In other words, loessial sediments can either be a source of significant recharge, or of no recharge at all, depending on the degree of vegetative cover. Additionally, the time lag between specific rainy seasons and corresponding recharge events at a depth of 22 m, increased from 2.5 to 5 years, and to about 20 years, respectively, with an increasing vegetative cover. For this reason, and also likely due to a great depth of loessial sediments, no correlation was found between annual recharge and annual precipitations of the same year or subsequent years. Similarly, no differences were found between summer and winter recharge fluxes. Instead, numerical simulations indicated continuous year-round recharge of the aquifer. We conclude that the layered subsurface acts as a short-term (annual) and long-term (multi-annual) buffer to smooth sudden precipitation/infiltration events. Vegetation conditions can help in predicting long-term recharge rates (as percentage of annual precipitation), which in turn need to be considered when assigning recharge characteristics in regional assessments and models.

  16. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Christians, Jeffrey A.; Schulz, Philip; Tinkham, Jonathan S.

    Long-term device stability is the most pressing issue that impedes perovskite solar cell commercialization, given the achieved 22.7% efficiency. The perovskite absorber material itself has been heavily scrutinized for being prone to degradation by water, oxygen and ultraviolet light. To date, most reports characterize device stability in the absence of these extrinsic factors. Here we show that, even under the combined stresses of light (including ultraviolet light), oxygen and moisture, perovskite solar cells can retain 94% of peak efficiency despite 1,000 hours of continuous unencapsulated operation in ambient air conditions (relative humidity of 10-20%). Each interface and contact layer throughoutmore » the device stack plays an important role in the overall stability which, when appropriately modified, yields devices in which both the initial rapid decay (often termed burn-in) and the gradual slower decay are suppressed. This extensively modified device architecture and the understanding developed will lead towards durable long-term device performance.« less

  17. Long-Term Monitoring of Brain Dopamine Metabolism In Vivo with Carbon Paste Electrodes

    PubMed Central

    O'Neill, Robert D.

    2005-01-01

    This review focuses on the stability of voltammetric signals recorded over periods of months with carbon paste electrodes (CPEs) implanted in the brain. The key interaction underlying this stability is between the pasting oil and brain lipids that are capable of inhibiting the fouling caused by proteins. In brain regions receiving a significant dopaminergic input, a peak due to the methylated metabolites of dopamine, principally homovanillic acid (HVA), is clearly resolved using slow sweep voltammetry. Although a number of factors limit the time resolution for monitoring brain HVA concentration dynamics, the stability of CPEs allows investigations of long-term effects of drugs, as well as behavioral studies, not possible using other in-vivo monitoring techniques.

  18. Editors' Choice—Field Trials Testing of Mixed Potential Electrochemical Hydrogen Safety Sensors at Commercial California Hydrogen Filling Stations

    DOE PAGES

    Brosha, Eric Lanich; Romero, Christopher Jesse; Poppe, Daniel; ...

    2017-10-27

    Hydrogen safety sensors must meet specific performance requirements, mandated by the U.S. Department of Energy, for hydrogen fueling station monitoring. Here, we describe the long-term performance of two zirconia-based mixed potential electrochemical hydrogen gas sensors, developed specifically with a high sensitivity to hydrogen, low cross-sensitivity, and fast response time. Over a two-year period, sensors with tin-doped indium oxide and strontium doped lanthanum chromite electrodes were deployed at two stations in four field trials tests conducted in Los Angeles. The sensors documented the existence of hydrogen plumes ranging in concentration from 100 to as high as 2700 ppm in the areamore » surrounding the dispenser, consistent with depressurization from 700 bar following vehicle refueling. As expected, the hydrogen concentration reported by the mixed potential sensors was influenced by wind direction. Baseline stability testing at a Chino, CA station showed no measureable baseline drift throughout 206 days of uninterrupted data acquisition. The high baseline stability, excellent correlation with logged fueling/depressurization events, and absence of false alarms suggest that the zirconia-based mixed potential sensor platform is a good candidate for protecting hydrogen infrastructure where frequent calibrations or sensor replacement to reduce the false alarm frequency have been shown to be cost prohibitive.« less

  19. Editors' Choice—Field Trials Testing of Mixed Potential Electrochemical Hydrogen Safety Sensors at Commercial California Hydrogen Filling Stations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Brosha, Eric Lanich; Romero, Christopher Jesse; Poppe, Daniel

    Hydrogen safety sensors must meet specific performance requirements, mandated by the U.S. Department of Energy, for hydrogen fueling station monitoring. Here, we describe the long-term performance of two zirconia-based mixed potential electrochemical hydrogen gas sensors, developed specifically with a high sensitivity to hydrogen, low cross-sensitivity, and fast response time. Over a two-year period, sensors with tin-doped indium oxide and strontium doped lanthanum chromite electrodes were deployed at two stations in four field trials tests conducted in Los Angeles. The sensors documented the existence of hydrogen plumes ranging in concentration from 100 to as high as 2700 ppm in the areamore » surrounding the dispenser, consistent with depressurization from 700 bar following vehicle refueling. As expected, the hydrogen concentration reported by the mixed potential sensors was influenced by wind direction. Baseline stability testing at a Chino, CA station showed no measureable baseline drift throughout 206 days of uninterrupted data acquisition. The high baseline stability, excellent correlation with logged fueling/depressurization events, and absence of false alarms suggest that the zirconia-based mixed potential sensor platform is a good candidate for protecting hydrogen infrastructure where frequent calibrations or sensor replacement to reduce the false alarm frequency have been shown to be cost prohibitive.« less

  20. Fabrication of Smart Chemical Sensors Based on Transition-Doped-Semiconductor Nanostructure Materials with µ-Chips

    PubMed Central

    Rahman, Mohammed M.; Khan, Sher Bahadar; Asiri, Abdullah M.

    2014-01-01

    Transition metal doped semiconductor nanostructure materials (Sb2O3 doped ZnO microflowers, MFs) are deposited onto tiny µ-chip (surface area, ∼0.02217 cm2) to fabricate a smart chemical sensor for toxic ethanol in phosphate buffer solution (0.1 M PBS). The fabricated chemi-sensor is also exhibited higher sensitivity, large-dynamic concentration ranges, long-term stability, and improved electrochemical performances towards ethanol. The calibration plot is linear (r2 = 0.9989) over the large ethanol concentration ranges (0.17 mM to 0.85 M). The sensitivity and detection limit is ∼5.845 µAcm−2mM−1 and ∼0.11±0.02 mM (signal-to-noise ratio, at a SNR of 3) respectively. Here, doped MFs are prepared by a wet-chemical process using reducing agents in alkaline medium, which characterized by UV/vis., FT-IR, Raman, X-ray photoelectron spectroscopy (XPS), powder X-ray diffraction (XRD), and field-emission scanning electron microscopy (FE-SEM) etc. The fabricated ethanol chemical sensor using Sb2O3-ZnO MFs is simple, reliable, low-sample volume (<70.0 µL), easy of integration, high sensitivity, and excellent stability for the fabrication of efficient I–V sensors on μ-chips. PMID:24454785

  1. Function of an Implanted Tissue Glucose Sensor for More than One Year in Animals

    PubMed Central

    Gough, David A.; Kumosa, Lucas S.; Routh, Timothy L.; Lin, Joe T.; Lucisano, Joseph Y.

    2015-01-01

    An implantable sensor capable of long-term monitoring of tissue glucose concentrations by wireless telemetry has been developed for eventual application in people with diabetes. In a recent trial, the sensor-telemetry system functioned continuously while implanted in subcutaneous tissues of two pigs for a total of 222 days and 520 days respectively, with each animal in both non-diabetic and diabetic states. The sensor detects glucose via an enzyme electrode principle that is based on differential electrochemical oxygen detection, which reduces the sensitivity of the sensor to encapsulation by the body, variations in local microvascular perfusion, limited availability of tissue oxygen, and inactivation of the enzymes. After an initial two-week stabilization period, the implanted sensors maintained stability of calibration for extended periods. The lag between blood and tissue glucose concentrations was 11.8 ± 5.7 minutes and 6.5 ± 13.3 minutes respectively, for rising and falling blood glucose challenges (mean ± SD). The lag was determined mainly by glucose mass transfer in the tissues, rather than the intrinsic response of the sensor, and showed no systematic change over implant test periods. These results represent a milestone in the translation of the sensor system to human applications. PMID:20668297

  2. Fabrication of smart chemical sensors based on transition-doped-semiconductor nanostructure materials with µ-chips.

    PubMed

    Rahman, Mohammed M; Khan, Sher Bahadar; Asiri, Abdullah M

    2014-01-01

    Transition metal doped semiconductor nanostructure materials (Sb2O3 doped ZnO microflowers, MFs) are deposited onto tiny µ-chip (surface area, ∼0.02217 cm(2)) to fabricate a smart chemical sensor for toxic ethanol in phosphate buffer solution (0.1 M PBS). The fabricated chemi-sensor is also exhibited higher sensitivity, large-dynamic concentration ranges, long-term stability, and improved electrochemical performances towards ethanol. The calibration plot is linear (r(2) = 0.9989) over the large ethanol concentration ranges (0.17 mM to 0.85 M). The sensitivity and detection limit is ∼5.845 µAcm(-2)mM(-1) and ∼0.11±0.02 mM (signal-to-noise ratio, at a SNR of 3) respectively. Here, doped MFs are prepared by a wet-chemical process using reducing agents in alkaline medium, which characterized by UV/vis., FT-IR, Raman, X-ray photoelectron spectroscopy (XPS), powder X-ray diffraction (XRD), and field-emission scanning electron microscopy (FE-SEM) etc. The fabricated ethanol chemical sensor using Sb2O3-ZnO MFs is simple, reliable, low-sample volume (<70.0 µL), easy of integration, high sensitivity, and excellent stability for the fabrication of efficient I-V sensors on μ-chips.

  3. Compact LWIR sensors using spatial interferometric technology (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Bingham, Adam L.; Lucey, Paul G.; Knobbe, Edward T.

    2017-05-01

    Recent developments in reducing the cost and mass of hyperspectral sensors have enabled more widespread use for short range compositional imaging applications. HSI in the long wave infrared (LWIR) is of interest because it is sensitive to spectral phenomena not accessible to other wavelengths, and because of its inherent thermal imaging capability. At Spectrum Photonics we have pursued compact LWIR hyperspectral sensors both using microbolometer arrays and compact cryogenic detector cameras. Our microbolometer-based systems are principally aimed at short standoff applications, currently weigh 10-15 lbs and feature sizes approximately 20x20x10 cm, with sensitivity in the 1-2 microflick range, and imaging times on the order of 30 seconds. Our systems that employ cryogenic arrays are aimed at medium standoff ranges such as nadir looking missions from UAVs. Recent work with cooled sensors has focused on Strained Layer Superlattice (SLS) technology, as these detector arrays are undergoing rapid improvements, and have some advantages compared to HgCdTe detectors in terms of calibration stability. These sensors include full on-board processing sensor stabilization so are somewhat larger than the microbolometer systems, but could be adapted to much more compact form factors. We will review our recent progress in both these application areas.

  4. Free-Standing Zone Plate Optimized for He II 30.4 nm Solar Irradiance Measurements Having High Accuracy and Stability in Space

    NASA Astrophysics Data System (ADS)

    Seely, J. F.; McMullin, D. R.; Vest, R.; Sakdinawat, A.; Chang, C.; Jones, A. R.; Bremer, J.

    2015-12-01

    A zone plate was designed to record the He II 30.4 nm solar irradiance, was fabricated using electron beam lithography, and was absolutely calibrated using the NIST SURF synchrotron. The zone plate has an open support grid identical to those used to successfully launch transmission gratings in previous solar radiometers and is otherwise free-standing with no support membrane that would absorb EUV radiation. The measured efficiency of 3.0 ± 0.1% at 30.4 nm is consistent with detailed modeling of the efficiency and accounting for the geometrical transmittance of the support grid. The binary nature of the zone plate, consisting of opaque gold bars and open spaces with no support membrane, results in excellent long-term stability in space against contamination, radiation damage, and other effects that could alter the efficiency and instrument throughput. The zone plate's focusing property enables the rejection of out-of-band radiation by small apertures and high signal to background values that are superior to previous radiometers. The 4 mm outer diameter of the zone plate and the 25 mm focal length for 30.4 nm radiation enable a compact instrument that is attractive for small CubeSats and other space flight missions where resources are extremely limited.

  5. WIM scale calibration: a vital activity for LTPP sites

    DOT National Transportation Integrated Search

    1998-07-01

    Long-Term Pavement Performance (LTPP) data are the foundation for new pavement designs for years to come. As such, data collected at LTPP test sites need to be as accurate and complete as possible. For the collection of truck weight data, this requir...

  6. Long-Term Pavement Performance Materials Characterization Program: Verification of Dynamic Test Systems with an Emphasis on Resilient Modulus

    DOT National Transportation Integrated Search

    2005-09-01

    This document describes a procedure for verifying a dynamic testing system (closed-loop servohydraulic). The procedure is divided into three general phases: (1) electronic system performance verification, (2) calibration check and overall system perf...

  7. Simplified spatiotemporal electromagnetic induction - salinity multi-field calibration

    USDA-ARS?s Scientific Manuscript database

    Salinity-affected farmlands are common in arid and semi-arid regions. To assure long-term sustainability of farming practices in these areas, soil salinity (ECe) should be routinely mapped and monitored. Salinity can be measured through soil sampling directed by geospatial measurements of apparent s...

  8. Long-term characterization of neural electrodes based on parylene-caulked polydimethylsiloxane substrate.

    PubMed

    Jeong, Jinmo; Chou, Namsun; Kim, Sohee

    2016-06-01

    This study investigates the mechanical and long-term electrical properties of parylene-caulked polydimethylsiloxane (PDMS) as a substrate for implantable electrodes. The parylene-caulked PDMS is a structure where particles of parylene fill the porous surface of PDMS. This material is expected to have low water absorption and desirable mechanical properties such as flexibility and elasticity that are beneficial in many biomedical applications. To evaluate the mechanical property and electrical stability of parylene-caulked PDMS for potential in-vivo uses, tensile tests were conducted firstly, which results showed that the mechanical strength of parylene-caulked PDMS was comparable to that of native PDMS. Next, surface electrodes based on parylene-caulked PDMS were fabricated and their impedance was measured in phosphate-buffered saline (PBS) solution at 36.5 °C over seven months. The electrodes based on parylene-caulked PDMS exhibited the improved stability in impedance over time than native PDMS. Thus, with improved electrical stability in wet environment and preserved mechanical properties of PDMS, the electrodes based on parylene-caulked PDMS are expected to be suitable for long-term in-vivo applications.

  9. The Global Precipitation Measurement (GPM) Microwave Imager (GMI): Instrument Overview and Early On-Orbit Performance

    NASA Technical Reports Server (NTRS)

    Draper, David W.; Newell, David A.; Wentz, Frank J.; Krimchansky, Sergey; Jackson, Gail

    2015-01-01

    The Global Precipitation Measurement (GPM) mission is an international satellite mission that uses measurements from an advanced radar/radiometer system on a core observatory as reference standards to unify and advance precipitation estimates made by a constellation of research and operational microwave sensors. The GPM core observatory was launched on February 27, 2014 at 18:37 UT in a 65? inclination nonsun-synchronous orbit. GPM focuses on precipitation as a key component of the Earth's water and energy cycle, and has the capability to provide near-real-time observations for tracking severe weather events, monitoring freshwater resources, and other societal applications. The GPM microwave imager (GMI) on the core observatory provides the direct link to the constellation radiometer sensors, which fly mainly in polar orbits. The GMI sensitivity, accuracy, and stability play a crucial role in unifying the measurements from the GPM constellation of satellites. The instrument has exhibited highly stable operations through the duration of the calibration/validation period. This paper provides an overview of the GMI instrument and a report of early on-orbit commissioning activities. It discusses the on-orbit radiometric sensitivity, absolute calibration accuracy, and stability for each radiometric channel. Index Terms-Calibration accuracy, passive microwave remote sensing, radiometric sensitivity.

  10. Decomposition of heterogeneous organic matterand its long-term stabilization in soils

    USGS Publications Warehouse

    Sierra, Carlos A.; Harmon, Mark E.; Perakis, Steven S.

    2011-01-01

    Soil organic matter is a complex mixture of material with heterogeneous biological, physical, and chemical properties. Decomposition models represent this heterogeneity either as a set of discrete pools with different residence times or as a continuum of qualities. It is unclear though, whether these two different approaches yield comparable predictions of organic matter dynamics. Here, we compare predictions from these two different approaches and propose an intermediate approach to study organic matter decomposition based on concepts from continuous models implemented numerically. We found that the disagreement between discrete and continuous approaches can be considerable depending on the degree of nonlinearity of the model and simulation time. The two approaches can diverge substantially for predicting long-term processes in soils. Based on our alternative approach, which is a modification of the continuous quality theory, we explored the temporal patterns that emerge by treating substrate heterogeneity explicitly. The analysis suggests that the pattern of carbon mineralization over time is highly dependent on the degree and form of nonlinearity in the model, mostly expressed as differences in microbial growth and efficiency for different substrates. Moreover, short-term stabilization and destabilization mechanisms operating simultaneously result in long-term accumulation of carbon characterized by low decomposition rates, independent of the characteristics of the incoming litter. We show that representation of heterogeneity in the decomposition process can lead to substantial improvements in our understanding of carbon mineralization and its long-term stability in soils.

  11. Satellite Calibration With LED Detectors at Mud Lake

    NASA Technical Reports Server (NTRS)

    Hiller, Jonathan D.

    2005-01-01

    Earth-monitoring instruments in orbit must be routinely calibrated in order to accurately analyze the data obtained. By comparing radiometric measurements taken on the ground in conjunction with a satellite overpass, calibration curves are derived for an orbiting instrument. A permanent, automated facility is planned for Mud Lake, Nevada (a large, homogeneous, dry lakebed) for this purpose. Because some orbiting instruments have low resolution (250 meters per pixel), inexpensive radiometers using LEDs as sensors are being developed to array widely over the lakebed. LEDs are ideal because they are inexpensive, reliable, and sense over a narrow bandwidth. By obtaining and averaging widespread data, errors are reduced and long-term surface changes can be more accurately observed.

  12. The Second "Ring of Towers": Over-sampling the Mid Continent Intensive region CO2 mixing ratio?

    NASA Astrophysics Data System (ADS)

    Richardson, S.; Miles, N.; Davis, K.; Crosson, E.; Denning, S.; Zupanksi, D.; Uliasz, M.

    2007-12-01

    A central barrier preventing the scientific community from understanding the carbon balance of the continent is methodological; it is technically difficult to bridge the gap in spatial scales that exists between the detailed understanding of ecological processes that can be gathered via intensive local field study, and the overarching but mechanistically poor understanding of the global carbon cycle that is gained by analyzing the atmospheric CO2 budget. The NACP's Midcontinental Intensive (MCI) study seeks to bridge this gap by conducting a rigorous methodological test of our ability to measure the terrestrial carbon balance of the upper Midwest. A critical need in bridging this gap is increased data density. A primary goal of the project is to increase the regional atmospheric CO2 data density so that 1) atmospheric inversions can derive well-constrained regional ecosystem carbon flux estimates and 2) the trade off between data density and accuracy of the flux estimates can be determined quantitatively using field observations, thus providing guidance to future observational network designs. Our work adds a regional network of five communications-tower based atmospheric CO2 observations to the planned long-term atmospheric CO2 observing network (tall towers, flux towers and aircraft profiles) in the midcontinent intensive region. Measurements began in April-June 2007, If the measurements are shown to be spatially dense enough to over sample the CO2 mixing ratio, the experiment will provide an upper bounds on the density of measurements required to produce the most accurate flux possible with current atmospheric inversions. The five sites for "Ring 2" and deployment dates are Centerville, IA (Apr 07), Round Lake, MN (May 07), Kewanee, IL (Apr 07), Mead, NE (Apr 07), Galesville, WI (June 07). Two heights are sampled at each tower (30 m AGL and between 110 and 140 m AGL). More details are available at www.ring2.psu.edu. In addition, two systems in PSU's network of well-calibrated CO2 mixing ratio measurements deployed at Ameriflux towers are within the midcontinental region: Ozark, MO (30 m AGL) and Mead, NE (3-6 m AGL) (www.amerifluxco2.psu.edu). The instruments chosen for the Ring 2 deployment are Picarro Inc., Cavity Ring-Down Spectroscopy (CRDS) instruments. One advantage of the CRDS instruments is the reduced need for calibration compared to the systems used in PSU's Ameriflux CO2 network which are calibrated every four hours using four calibration tanks. Although the long-term stability is not exactly known, tests have shown accuracy to within 0.2 ppm on a monthly time scale without additional calibration. Preliminary results show spatial differences in daytime CO2 across the ring that are as large as 40 ppm, and highly variable in time. We will present observations and preliminary interpretation of these data.

  13. Information footprint of different ecohydrological data sources: using multi-objective calibration of a physically-based model as hypothesis testing

    NASA Astrophysics Data System (ADS)

    Kuppel, S.; Soulsby, C.; Maneta, M. P.; Tetzlaff, D.

    2017-12-01

    The utility of field measurements to help constrain the model solution space and identify feasible model configurations has been an increasingly central issue in hydrological model calibration. Sufficiently informative observations are necessary to ensure that the goodness of model-data fit attained effectively translates into more physically-sound information for the internal model parameters, as a basis for model structure evaluation. Here we assess to which extent the diversity of information content can inform on the suitability of a complex, process-based ecohydrological model to simulate key water flux and storage dynamics at a long-term research catchment in the Scottish Highlands. We use the fully-distributed ecohydrological model EcH2O, calibrated against long-term datasets that encompass hydrologic and energy exchanges and ecological measurements: stream discharge, soil moisture, net radiation above canopy, and pine stand transpiration. Diverse combinations of these constraints were applied using a multi-objective cost function specifically designed to avoid compensatory effects between model-data metrics. Results revealed that calibration against virtually all datasets enabled the model to reproduce streamflow reasonably well. However, parameterizing the model to adequately capture local flux and storage dynamics, such as soil moisture or transpiration, required calibration with specific observations. This indicates that the footprint of the information contained in observations varies for each type of dataset, and that a diverse database informing about the different compartments of the domain, is critical to test hypotheses of catchment function and identify a consistent model parameterization. The results foster confidence in using EcH2O to help understanding current and future ecohydrological couplings in Northern catchments.

  14. Agricultural Policy Environmental eXtender Simulation of Three Adjacent Row-Crop Watersheds in the Claypan Region.

    PubMed

    Anomaa Senaviratne, G M M M; Udawatta, Ranjith P; Baffaut, Claire; Anderson, Stephen H

    2013-01-01

    The Agricultural Policy Environmental Extender (APEX) model is used to evaluate best management practices on pollutant loading in whole farms or small watersheds. The objectives of this study were to conduct a sensitivity analysis to determine the effect of model parameters on APEX output and use the parameterized, calibrated, and validated model to evaluate long-term benefits of grass waterways. The APEX model was used to model three (East, Center, and West) adjacent field-size watersheds with claypan soils under a no-till corn ( L.)/soybean [ (L.) Merr.] rotation. Twenty-seven parameters were sensitive for crop yield, runoff, sediment, nitrogen (dissolved and total), and phosphorous (dissolved and total) simulations. The model was calibrated using measured event-based data from the Center watershed from 1993 to 1997 and validated with data from the West and East watersheds. Simulated crop yields were within ±13% of the measured yield. The model performance for event-based runoff was excellent, with calibration and validation > 0.9 and Nash-Sutcliffe coefficients (NSC) > 0.8, respectively. Sediment and total nitrogen calibration results were satisfactory for larger rainfall events (>50 mm), with > 0.5 and NSC > 0.4, but validation results remained poor, with NSC between 0.18 and 0.3. Total phosphorous was well calibrated and validated, with > 0.8 and NSC > 0.7, respectively. The presence of grass waterways reduced annual total phosphorus loadings by 13 to 25%. The replicated study indicates that APEX provides a convenient and efficient tool to evaluate long-term benefits of conservation practices. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  15. Long-term stability of the Leksell Gamma Knife{sup ®} Perfexion™ patient positioning system (PPS)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Novotny, J., E-mail: josef.novotnyml@homolka.cz; Department of Medical Physics, Na Homolce Hospital, Prague 150 30; Institute of Biophysics and Informatics, First Faculty of Medicine, Charles University in Prague, Prague 120 00

    2014-03-15

    Purpose: To assess the long-term mechanical stability and accuracy of the patient positioning system (PPS) of the Leksell Gamma Knife{sup ®} Perfexion™ (LGK PFX). Methods: The mechanical stability of the PPS of the LGK PFX was evaluated using measurements obtained between September 2007 and June 2011. Three methods were employed to measure the deviation of the coincidence of the radiological focus point (RFP) and the PPS calibration center point (CCP). In the first method, the onsite diode test tool with single diode detector was used together with the 4 mm collimator on a daily basis. In the second method, amore » service diode test tool with three diode detectors was used biannually at the time of the routine preventive maintenance. The test performed with the service diode test tool measured the deviations for all three collimators 4, 8, and 16 mm and also for three different positions of the PPS. The third method employed the conventional film pin-prick method. This test was performed annually for the 4 mm collimator at the time of the routine annual QA. To estimate the effect of the patient weight on the performance of the PPS, the focus precision tests were also conducted with varying weights on the PPS using a set of lead bricks. Results: The average deviations measured from the 641 daily focus precision tests were 0.1 ± 0.1, 0.0 ± 0.0, and 0.0 ± 0.0 mm, respectively, for the 4 mm collimator in the X (left/right of the patient), Y (anterior/posterior of the patient), and Z (superior/inferior of the patient) directions. The average of the total radial deviations as measured during ten semiannual measurements with the service diode test tool were 0.070 ± 0.029, 0.060 ± 0.022, and 0.103 ± 0.028 mm, respectively for the central, long, and short diodes for the 4 mm collimator. Similarly, the average total radial deviations measured during the semiannual measurements for the 4, 8, and 16 mm collimators and using the central diode were 0.070 ± 0.029, 0.097 ± 0.025, 0.159 ± 0.028 mm, respectively. The average values of the deviations as obtained from the five annual film pin-prick tests for the 4 mm collimator were 0.10 ± 0.06, 0.06 ± 0.09, and 0.03 ± 0.03 mm for the X, Y, Z stereotactic directions, respectively. Only a minor change was observed in the total radial deviations of the PPS as a function of the simulated patient weight up to 202 kg on the PPS. Conclusions: Excellent long-term mechanical stability and high accuracy was observed for the PPS of the LGK PFX. No PPS recalibration or any adjustment in the PPS was needed during the monitored period of time. Similarly, the weight on the PPS did not cause any significant disturbance in the performance of the PPS for up to 202 kg simulated patient weight.« less

  16. Application of micro-porous polycarbonate membranes in dye-sensitized solar cells: Cell performance and long-term stability

    NASA Astrophysics Data System (ADS)

    Lue, Shingjiang Jessie; Lo, Pei Wen; Hung, Ling-Yung; Tung, Yung Liang

    This research investigates the cell performance and long-term stability of dye-sensitized solar cells (DSSCs) containing micro-porous polycarbonate (PC) film as the frame work material to stabilize the electrolyte solution. The track-etched PC film has cylindrical pore geometry, which is beneficial for ion transport in the electrolyte trapped inside the PC film. The photovoltaic efficiency of the DSSC with 0.2-μm PC membrane is 5.75 ± 0.73% under irradiation of 100 mW cm -2, which is slightly lower than that (6.34 ± 0.44%) of cells without PC film. The differences in fill factor and open-circuit voltage between the DSSCs with and without PC film are not statistically significant. The long-term cell performance is carried out at continuous illumination of 100 mW cm -2 (1 sun) and in darkness at 60 °C for up to 1000 h. There is no significant efficiency difference between the cells with and without PC film in light soaking (4.33% vs. 4.52%) for 960 h. In darkness, however, the cells with PC film demonstrate much higher efficiency (at 2.37%) than cells without PC (0.85%) after 1000 h. The improved long-term efficiency data and the higher percentage of working cells confirm the superior lifetime and performance using the micro-porous PC film.

  17. Instrument Drift Uncertainties and the Long-Term TOMS/SBUV Total Ozone Record

    NASA Technical Reports Server (NTRS)

    Solarski, Richard S.; Frith, Stacey

    2005-01-01

    Long-term climate records from satellites are often constructed from the measurements of a sequence of instruments launched at different times. Each of these instruments is calibrated prior to launch. After launch they are subjected to potential offsets and slow drifts in calibration. We illustrate these issues in the construction of a merged total ozone record from two TOMS and three SBUV instruments. This record extends from late 1978 through the present. The question is "How good are these records?". We have examined the uncertainty in determining the relative calibration of two instruments during an overlap period in their measurements. When comparing a TOMS instrument, such as that on Nimbus 7, with an SBUV instrument, also on Nimbus 7, we find systematic differences and random differences. We have combined these findings with estimates of individual instrument drift into a monte- carlo uncertainty propagation model. We estimate an instrument drift uncertainty of a little larger than 1 percent per decade over the 25-year history of the TOMS/SBUV measurements. We make an independent estimate of the drift uncertainty in the ground-based network of total ozone measurements and find it to be of similar, but slightly smaller magnitude. The implications of these uncertainties for trend and recovery determination will be discussed.

  18. Core Facility of the Juelich Observatory for Cloud Evolution (JOYCE - CF)

    NASA Astrophysics Data System (ADS)

    Beer, J.; Troemel, S.

    2017-12-01

    A multiple and holistic multi-sensor monitoring of clouds and precipitation processes is a challenging but promising task in the meteorological community. Instrument synergies offer detailed views in microphysical and dynamical developments of clouds. Since 2017 The the Juelich Observatory for Cloud Evolution (JOYCE) is transformed into a Core Facility (JOYCE - CF). JOYCE - CF offers multiple long-term remote sensing observations of the atmosphere, develops an easy access to all observations and invites scientists word wide to exploit the existing data base for their research but also to complement JOYCE-CF with additional long-term or campaign instrumentation. The major instrumentation contains a twin set of two polarimetric X-band radars, a microwave profiler, two cloud radars, an infrared spectrometer, a Doppler lidar and two ceilometers. JOYCE - CF offers easy and open access to database and high quality calibrated observations of all instruments. E.g. the two polarimetric X-band radars which are located in 50 km distance are calibrated using the self-consistency method, frequently repeated vertical pointing measurements as well as instrument synergy with co-located micro-rain radar and distrometer measurements. The presentation gives insights into calibration procedures, the standardized operation procedures and recent synergistic research exploiting our radars operating at three different frequencies.

  19. Four Years of Absolutely Calibrated Hyperspectral Data from the Atmospheric Infrared Sounder (AIRS) on the Eos Aqua

    NASA Technical Reports Server (NTRS)

    Aumann, Hartmut H.; Broberg, Steve; Elliott, Denis; Gregorich, Dave

    2006-01-01

    This viewgraph presentation reviews four years of absolute calibration of hyperspectral data from the AIRS instrument located on the EOS AQUA spacecraft. The following topics are discussed: 1) A quick overview of AIRS; 2) What absolute calibration accuracy and stability are required for climate applications?; 3) Validating of radiance accuracy and stability: Results from four years of AIRS data; and 4) Conclusions.

  20. Water-Balance Model to Simulate Historical Lake Levels for Lake Merced, California

    NASA Astrophysics Data System (ADS)

    Maley, M. P.; Onsoy, S.; Debroux, J.; Eagon, B.

    2009-12-01

    Lake Merced is a freshwater lake located in southwestern San Francisco, California. In the late 1980s and early 1990s, an extended, severe drought impacted the area that resulted in significant declines in Lake Merced lake levels that raised concerns about the long-term health of the lake. In response to these concerns, the Lake Merced Water Level Restoration Project was developed to evaluate an engineered solution to increase and maintain Lake Merced lake levels. The Lake Merced Lake-Level Model was developed to support the conceptual engineering design to restore lake levels. It is a spreadsheet-based water-balance model that performs monthly water-balance calculations based on the hydrological conceptual model. The model independently calculates each water-balance component based on available climate and hydrological data. The model objective was to develop a practical, rule-based approach for the water balance and to calibrate the model results to measured lake levels. The advantage of a rule-based approach is that once the rules are defined, they enhance the ability to then adapt the model for use in future-case simulations. The model was calibrated to historical lake levels over a 70-year period from 1939 to 2009. Calibrating the model over this long historical range tested the model over a variety of hydrological conditions including wet, normal and dry precipitation years, flood events, and periods of high and low lake levels. The historical lake level range was over 16 feet. The model calibration of historical to simulated lake levels had a residual mean of 0.02 feet and an absolute residual mean of 0.42 feet. More importantly, the model demonstrated the ability to simulate both long-term and short-term trends with a strong correlation of the magnitude for both annual and seasonal fluctuations in lake levels. The calibration results demonstrate an improved conceptual understanding of the key hydrological factors that control lake levels, reduce uncertainty in the hydrological conceptual model, and increase confidence in the model’s ability to forecast future lake conditions. The Lake Merced Lake-Level Model will help decision-makers with a straightforward, practical analysis of the major contributions to lake-level declines that can be used to support engineering, environmental and other decisions.

  1. Metal-Free Cataluminescence Gas Sensor for Hydrogen Sulfide Based on Its Catalytic Oxidation on Silicon Carbide Nanocages.

    PubMed

    Wu, Liqian; Zhang, Lichun; Sun, Mingxia; Liu, Rui; Yu, Lingzhu; Lv, Yi

    2017-12-19

    Cataluminescence- (CTL-) based sensors are among the most attractive and effective tools for gas sensing, owing to their efficient selectivity, high sensitivity, and rapidity. As the sensing materials of CTL-based sensors, metal-based catalysts easily bring about high costs and environmental pollution of heavy metals. More importantly, the long-term stability of metal-based catalysts is usually rather poor. Metal-free catalysts have unique advantages such as environmental friendliness, low costs, and long-term stability, making them promising materials for CTL-based sensors. Herein, we report the fabrication of a CTL sensor based on a metal-free catalyst. F-doped cage-like SiC was synthesized by wet chemical etching. The as-prepared products showed a rapid, stable, highly selective, and sensitive cataluminescent response to H 2 S. The stability of the sensor was demonstrated to be fairly good for at least 15 days. After CTL tests, F-doped cage-like SiC retained its original morphology, structure, and chemical composition. In addition, to the best of our knowledge, this is the first report of a metal-free CTL sensor. Metal-free catalysts are environmentally friendly and low in cost and exhibit long-term stability, which could open a new avenue of CTL sensing.

  2. ASSESSMENT OF MOLECULAR GENETIC STABILITY BETWEEN LONG-TERM CRYOPRESERVED AND TISSUE CULTURED WASABI (Wasabia japonica) PLANTS.

    PubMed

    Maki, S; Hirai, Y; Niino, T; Matsumoto, T

    2015-01-01

    Maintaining the genetic integrity in long-term tissue cultured and cryopreserved plants is important for the conservation of plant genetic resources. In this study, the genetic stability of cryopreserved wasabi shoot tips stored for 10 years at -150 degree C was visualized using Amplified Fragment Length Polymorphism (AFLP) and Methylation Sensitive Amplified Polymorphism (MSAP). The study included plants derived from cryopreserved shoot tips after 10.5 years storage at -150 degree C (LN10yr), after 2 h storage at -196 degree C (LN2hr), cryopreservation controls (No LN cooling (TC)) and non-treated controls without LN cooling (LC). The donor plants for LN2hr, TC and LC were also maintained in vitro at 20 degree C for the same period. Neither technique detected genetic variations in either control or cryopreserved plants. Some mutations were noted in plants maintained in tissue culture for 10 years. Comparison of genome stability for TC and LN2hr plants showed only a minor change in DNA. However, when comparing the LC and Ln10yr, many differences were found. We conclude that cryopreservation is a superior conservation method compared to tissue culture in maintaining genetic stability for a long-term storage of wasabi germplasm.

  3. Effect of mesogenic ligands on short and long-term spectral stability of CdSe/ZnS quantum dots

    NASA Astrophysics Data System (ADS)

    Amaral, Jose; Betady, Edwin; Quint, Makiko; Martin, Denzal; Riahinasab, Sheida; Hirst, Linda; Ghosh, Sayantani

    Surface modification of chemically synthesized CdSe/ZnS quantum dots (QDs) by performing a ligand-exchange can improve the optical properties, including short- and long-term photo-stability. Using a custom-designed mesogenic ligand, we significantly and advantageously alter the photophysical properties of CdSe/ZnS core-shell QDs. Our investigation is two-fold, as we follow the effect of ligand exchange on (1) the static and dynamic photoluminescence (PL) properties of QDs under continuous illumination, and (2) the temperature dependence of PL. We find that a reduction in Forster resonance energy transfer due to the ligand exchange process results in stabilizing both recombination lifetimes and emission intensity for over an hour of high power photo-excitation. Our temperature-dependent PL studies indicate thermally activated PL recovery at higher temperatures, and a lack of emission enhancement at low temperatures resulting from greater charge separation by the mesogenic ligands. We conclude that this process improves photoluminescence stability and sample longevity of QD films whose applications require long term resistance to photobleaching. This research was supported by funds from the National Aeronautics and Space Administration (NASA) Grant No. NNX15AQ01A, UCMEXUS-CONACYT, and National Science Foundation (NSF) Grants No. DMR-1056860, DMR-1359406 and CBET-1507551.

  4. Long-Term Stability of Tutor Performance.

    ERIC Educational Resources Information Center

    Dolmans, Diana H. J. M.; And Others

    1996-01-01

    Examined the extent to which tutor ratings remained stable in the long term by evaluating 291 ratings of 140 tutors at Maastricht University in the Netherlands between 1992 and 1995. The results indicated that, if the aggregated score and overall judgement are used to interpret the precision of individual scores, four and two occasions,…

  5. A single-mode external cavity diode laser using an intra-cavity atomic Faraday filter with short-term linewidth <400 kHz and long-term stability of <1 MHz.

    PubMed

    Keaveney, James; Hamlyn, William J; Adams, Charles S; Hughes, Ifan G

    2016-09-01

    We report on the development of a diode laser system - the "Faraday laser" - using an atomic Faraday filter as the frequency-selective element. In contrast to typical external-cavity diode laser systems which offer tunable output frequency but require additional control systems in order to achieve a stable output frequency, our system only lases at a single frequency, set by the peak transmission frequency of the internal atomic Faraday filter. Our system has both short-term and long-term stability of less than 1 MHz, which is less than the natural linewidth of alkali-atomic D-lines, making similar systems suitable for use as a "turn-key" solution for laser-cooling experiments.

  6. Satb2 determines miRNA expression and long-term memory in the adult central nervous system.

    PubMed

    Jaitner, Clemens; Reddy, Chethan; Abentung, Andreas; Whittle, Nigel; Rieder, Dietmar; Delekate, Andrea; Korte, Martin; Jain, Gaurav; Fischer, Andre; Sananbenesi, Farahnaz; Cera, Isabella; Singewald, Nicolas; Dechant, Georg; Apostolova, Galina

    2016-11-29

    SATB2 is a risk locus for schizophrenia and encodes a DNA-binding protein that regulates higher-order chromatin configuration. In the adult brain Satb2 is almost exclusively expressed in pyramidal neurons of two brain regions important for memory formation, the cerebral cortex and the CA1-hippocampal field. Here we show that Satb2 is required for key hippocampal functions since deletion of Satb2 from the adult mouse forebrain prevents the stabilization of synaptic long-term potentiation and markedly impairs long-term fear and object discrimination memory. At the molecular level, we find that synaptic activity and BDNF up-regulate Satb2, which itself binds to the promoters of coding and non-coding genes. Satb2 controls the hippocampal levels of a large cohort of miRNAs, many of which are implicated in synaptic plasticity and memory formation. Together, our findings demonstrate that Satb2 is critically involved in long-term plasticity processes in the adult forebrain that underlie the consolidation and stabilization of context-linked memory.

  7. Estimating Uncertainties in the Multi-Instrument SBUV Profile Ozone Merged Data Set

    NASA Technical Reports Server (NTRS)

    Frith, Stacey; Stolarski, Richard

    2015-01-01

    The MOD data set is uniquely qualified for use in long-term ozone analysis because of its long record, high spatial coverage, and consistent instrument design and algorithm. The estimated MOD uncertainty term significantly increases the uncertainty over the statistical error alone. Trends in the post-2000 period are generally positive in the upper stratosphere, but only significant at 1-1.6 hPa. Remaining uncertainties not yet included in the Monte Carlo model are Smoothing Error ( 1 from 10 to 1 hPa) Relative calibration uncertainty between N11 and N17Seasonal cycle differences between SBUV records.

  8. Stability of Uncemented Cups - Long-Term Effect of Screws, Pegs and HA Coating: A 14-Year RSA Follow-Up of Total Hip Arthroplasty.

    PubMed

    Otten, Volker T C; Crnalic, Sead; Röhrl, Stephan M; Nivbrant, Bo; Nilsson, Kjell G

    2016-01-01

    Screws, pegs and hydroxyapatite-coating are used to enhance the primary stability of uncemented cups. We present a 14-year follow-up of 48 hips randomized to four groups: press-fit only, press-fit plus screws, press-fit plus pegs and hydroxyapatite-coated cups. Radiostereometric migration measurements showed equally good stability regardless cup augmentation. The mean wear rate was high, 0.21 mm/year, with no differences between the groups. Seven hips had radiographical osteolysis but only in hips with augmented cups. Cups without screw-holes compared with cups with screw-holes resulted in better clinical outcome at the 14-year follow-up. Thus, augmentation of uncemented cups with screws, pegs, or hydroxyapatite did not appear to improve the long-term stability compared with press-fit only. Copyright © 2016 Elsevier Inc. All rights reserved.

  9. Stable radio-frequency transfer over optical fiber by phase-conjugate frequency mixing.

    PubMed

    He, Yabai; Orr, Brian J; Baldwin, Kenneth G H; Wouters, Michael J; Luiten, Andre N; Aben, Guido; Warrington, R Bruce

    2013-08-12

    We demonstrate long-distance (≥100-km) synchronization of the phase of a radio-frequency reference over an optical-fiber network without needing to actively stabilize the optical path length. Frequency mixing is used to achieve passive phase-conjugate cancellation of fiber-length fluctuations, ensuring that the phase difference between the reference and synchronized oscillators is independent of the link length. The fractional radio-frequency-transfer stability through a 100-km "real-world" urban optical-fiber network is 6 × 10(-17) with an averaging time of 10(4) s. Our compensation technique is robust, providing long-term stability superior to that of a hydrogen maser. By combining our technique with the short-term stability provided by a remote, high-quality quartz oscillator, this system is potentially applicable to transcontinental optical-fiber time and frequency dissemination where the optical round-trip propagation time is significant.

  10. A role of abdomen in butterfly's flapping flight

    NASA Astrophysics Data System (ADS)

    Jayakumar, Jeeva; Senda, Kei; Yokoyama, Naoto

    2017-11-01

    Butterfly's forward flight with periodic flapping motion is longitudinally unstable, and control of the thoracic pitching angle is essential to stabilize the flight. This study aims to comprehend roles which the abdominal motion play in the pitching stability of butterfly's flapping flight by using a two-dimensional model. The control of the thoracic pitching angle by the abdominal motion is an underactuated problem because of the limit on the abdominal angle. The control input of the thorax-abdomen joint torque is obtained by the hierarchical sliding mode control in this study. Numerical simulations reveal that the control by the abdominal motion provides short-term pitching stabilization in the butterfly's flight. Moreover, the control input due to a large thorax-abdomen joint torque can counteract a quite large perturbation, and can return the pitching attitude to the periodic trajectory with a short recovery time. These observations are consistent with biologists' view that living butterflies use their abdomens as rudders. On the other hand, the abdominal control mostly fails in long-term pitching stabilization, because it cannot directly alter the aerodynamic forces. The control for the long-term pitching stabilization will also be discussed.

  11. Characterization of air manganese exposure estimates for residents in two Ohio towns

    PubMed Central

    Colledge, Michelle A.; Julian, Jaime R.; Gocheva, Vihra V.; Beseler, Cheryl L.; Roels, Harry A.; Lobdell, Danelle T.; Bowler, Rosemarie M.

    2016-01-01

    This study was conducted to derive receptor-specific outdoor exposure concentrations of total suspended particulate (TSP) and respirable (dae ≤ 10 μm) air manganese (air-Mn) for East Liverpool and Marietta (Ohio) in the absence of facility emissions data, but where long-term air measurements were available. Our “site-surface area emissions method” used U.S. Environmental Protection Agency’s (EPA) AERMOD (AMS/EPA Regulatory Model) dispersion model and air measurement data to estimate concentrations for residential receptor sites in the two communities. Modeled concentrations were used to create ratios between receptor points and calibrated using measured data from local air monitoring stations. Estimated outdoor air-Mn concentrations were derived for individual study subjects in both towns. The mean estimated long-term air-Mn exposure levels for total suspended particulate were 0.35 μg/m3 (geometric mean [GM]) and 0.88 μg/m3 (arithmetic mean [AM]) in East Liverpool (range: 0.014–6.32 μg/m3) and 0.17 μg/m3 (GM) and 0.21 μg/m3 (AM) in Marietta (range: 0.03–1.61 μg/m3). Modeled results compared well with averaged ambient air measurements from local air monitoring stations. Exposure to respirable Mn particulate matter (PM10; PM <10 μm) was higher in Marietta residents. Implications Few available studies evaluate long-term health outcomes from inhalational manganese (Mn) exposure in residential populations, due in part to challenges in measuring individual exposures. Local long-term air measurements provide the means to calibrate models used in estimating long-term exposures. Furthermore, this combination of modeling and ambient air sampling can be used to derive receptor-specific exposure estimates even in the absence of source emissions data for use in human health outcome studies. PMID:26211636

  12. Development and Testing of a Simple Calibration Technique for Long-Term Hydrological Impact Assessment (L-THIA) Model

    NASA Astrophysics Data System (ADS)

    Muthukrishnan, S.; Harbor, J.

    2001-12-01

    Hydrological studies are significant part of every engineering, developmental project and geological studies done to assess and understand the interactions between the hydrology and the environment. Such studies are generally conducted before the beginning of the project as well as after the project is completed, such that a comprehensive analysis can be done on the impact of such projects on the local and regional hydrology of the area. A good understanding of the chain of relationships that form the hydro-eco-biological and environmental cycle can be of immense help in maintaining the natural balance as we work towards exploration and exploitation of the natural resources as well as urbanization of undeveloped land. Rainfall-Runoff modeling techniques have been of great use here for decades since they provide fast and efficient means of analyzing vast amount of data that is gathered. Though process based, detailed models are better than the simple models, the later ones are used more often due to their simplicity, ease of use, and easy availability of data needed to run them. The Curve Number (CN) method developed by the United States Department of Agriculture (USDA) is one of the most widely used hydrologic modeling tools in the US, and has earned worldwide acceptance as a practical method for evaluating the effects of land use changes on the hydrology of an area. The Long-Term Hydrological Impact Assessment (L-THIA) model is a basic, CN-based, user-oriented model that has gained popularity amongst watershed planners because of its reliance on readily available data, and because the model is easy to use (http://www.ecn.purdue.edu/runoff) and produces results geared to the general information needs of planners. The L-THIA model was initially developed to study the relative long-term hydrologic impacts of different land use (past/current/future) scenarios, and it has been successful in meeting this goal. However, one of the weaknesses of L-THIA, as well as other models that focus strictly on surface runoff, is that many users are interested in predictions of runoff that match observations of flow in streams and rivers. To make L-THIA more useful for the planners and engineers alike, a simple, long-term calibration method based on linear regression of L-THIA predicted and observed surface runoff has been developed and tested here. The results from Little Eagle Creek (LEC) in Indiana show that such calibrations are successful and valuable. This method can be used to calibrate other simple rainfall-runoff models too.

  13. Reconstructing Forty Years of Landsat Observations

    NASA Astrophysics Data System (ADS)

    Meyer, D. J.; Dwyer, J. L.; Steinwand, D.

    2013-12-01

    In July 1972, NASA launched the Earth Resource Technology Satellite (ERTS), the first of what was to be the series of Earth-observing satellites we now know as the Landsat system. This system, originally conceived in the 1960's within the US Department of the Interior and US Geological Survey (USGS), has continued with little interruption for over 40 years, creating the longest record of satellite-based global land observations. The current USGS archive of Landsat images exceeds 4 million scenes, and the recently launched Landsat 8 platform will extend that archive to nearly 50 years of observations. Clearly, these observations are critical to the study of Earth system processes, and the interaction between these processes and human activities. However, the seven successful Landsat missions represent more of an ad hoc program than a long-term record of consistent observations, due largely to changing Federal policies and challenges finding an operational home for the program. Technologically, these systems evolved from the original Multispectral Scanning System (MSS) through the Thematic Mapper and Enhanced Thematic Mapper Plus (ETM+) systems, to the current Observational Land Imager (OLI) and Thermal Infrared Sensor (TIRS) systems. Landsat data were collected globally by a network of international cooperators having diverse data management policies. Much of the oldest data were stored on archaic media that could not be retrieved using modern media readers. Collecting these data from various sensors and sources, and reconstructing them into coherent Earth observation records, posed numerous challenges. We present here a brief overview of work done to overcome these challenges and create a consistent, long-term Landsat observation record. Much of the current archive was 'repatriated' from international cooperators and often required the reconstruction of (sometimes absent) metadata for geo-location and radiometric calibration. The older MSS data, some of which had been successfully retrieved from outdated wide band video media, required similar metadata reconstruction. TM data from Landsats 4 and 5 relied on questionable on-board lamp data for calibration, thus the calibration history for these missions was reconstructed to account for sensor degradation over time. To improve continuity between platforms, Landsat 7 and 8 missions employed 'under-flight' maneuvers to reduce inter-calibration error. Data from the various sensors, platforms and sources were integrated into a common metadata standard, with quality assurance information, to ensure understandability of the data for long-term preservation. Because of these efforts, the current Landsat archive can now support the creation of the long-term climate data records and essential climate variables required to monitor changes on the Earth's surface quantitatively over decades of observations.

  14. Agar-Silica-Gel Heating Phantom May Be Suitable for Long-Term Quality Assurance of MRgHIFU

    NASA Astrophysics Data System (ADS)

    Partanen, Ari

    2009-04-01

    In MRgHIFU, the purpose of frequent quality assurance is to detect changes in system performance to prevent adverse effects during treatments. Due to high ultrasound intensities in MRgHIFU, it is essential to assure that the procedure is safe and efficacious and that image-based guidance of the treatment is reliable. We aimed to develop a guideline for MRgHIFU QA by acquiring MR temperature maps during ultrasonic heating of an agar-silica-gel phantom over a four month-period using three separate MRgHIFU uterine leiomyoma treatment systems. From this data, the stability of the maximum temperature elevation, the targeting accuracy, and the dimensions of the heated volume were analyzed. Additionally, we studied the sensitivity of these parameters to reveal hypothetical decrease in HIFU performance. After calibration, the mean targeting offsets of the heated volume were observed to be less than 2 mm in the three orthogonal directions. The measured maximum temperature elevation and the length and the width of the heated volume remained consistent throughout the four-month period. Furthermore, it was found that the parameters under investigation were sensitive to reveal the decreased HIFU performance. We conclude that an agar-silica -based phantom is suitable for targeting accuracy and heating properties QA of MRgHIFU system even in long-term use. Moreover, this simple QA method may be used to reveal small changes in HIFU performance assuring consistent functionality and safety of the MRgHIFU system.

  15. Design and Calibration of the X-33 Flush Airdata Sensing (FADS) System

    NASA Technical Reports Server (NTRS)

    Whitmore, Stephen A.; Cobleigh, Brent R.; Haering, Edward A.

    1998-01-01

    This paper presents the design of the X-33 Flush Airdata Sensing (FADS) system. The X-33 FADS uses a matrix of pressure orifices on the vehicle nose to estimate airdata parameters. The system is designed with dual-redundant measurement hardware, which produces two independent measurement paths. Airdata parameters that correspond to the measurement path with the minimum fit error are selected as the output values. This method enables a single sensor failure to occur with minimal degrading of the system performance. The paper shows the X-33 FADS architecture, derives the estimating algorithms, and demonstrates a mathematical analysis of the FADS system stability. Preliminary aerodynamic calibrations are also presented here. The calibration parameters, the position error coefficient (epsilon), and flow correction terms for the angle of attack (delta alpha), and angle of sideslip (delta beta) are derived from wind tunnel data. Statistical accuracy of' the calibration is evaluated by comparing the wind tunnel reference conditions to the airdata parameters estimated. This comparison is accomplished by applying the calibrated FADS algorithm to the sensed wind tunnel pressures. When the resulting accuracy estimates are compared to accuracy requirements for the X-33 airdata, the FADS system meets these requirements.

  16. An accuracy assessment of Magellan Very Long Baseline Interferometry (VLBI)

    NASA Technical Reports Server (NTRS)

    Engelhardt, D. B.; Kronschnabl, G. R.; Border, J. S.

    1990-01-01

    Very Long Baseline Interferometry (VLBI) measurements of the Magellan spacecraft's angular position and velocity were made during July through September, 1989, during the spacecraft's heliocentric flight to Venus. The purpose of this data acquisition and reduction was to verify this data type for operational use before Magellan is inserted into Venus orbit, in August, 1990. The accuracy of these measurements are shown to be within 20 nanoradians in angular position, and within 5 picoradians/sec in angular velocity. The media effects and their calibrations are quantified; the wet fluctuating troposphere is the dominant source of measurement error for angular velocity. The charged particle effect is completely calibrated with S- and X-Band dual-frequency calibrations. Increasing the accuracy of the Earth platform model parameters, by using VLBI-derived tracking station locations consistent with the planetary ephemeris frame, and by including high frequency Earth tidal terms in the Earth rotation model, add a few nanoradians improvement to the angular position measurements. Angular velocity measurements were insensitive to these Earth platform modelling improvements.

  17. Mitigating Uncertainty from Vegetation Spatial Complexity with Highly Portable Lidar

    NASA Astrophysics Data System (ADS)

    Paynter, I.; Schaaf, C.; Peri, F.; Saenz, E. J.; Genest, D.; Strahler, A. H.; Li, Z.

    2015-12-01

    To fully utilize the excellent spatial coverage and temporal resolution offered by satellite resources for estimating ecological variables, fine-scale observations are required for comparison, calibration and validation. Lidar instruments have proved effective in estimating the properties of vegetation components of ecosystems, but they are often challenged by occlusion, especially in structurally complex and spatially fragmented ecosystems such as tropical forests. Increasing the range of view angles, both horizontally and vertically, by increasing the number of scans, can mitigate occlusion. However these scans must occur within the window of temporal stability for the ecosystem and vegetation property being measured. The Compact Biomass Lidar (CBL) is a TLS optimized for portability and scanning speed, developed and operated by University of Massachusetts Boston. This 905nm wavelength scanner achieves an angular resolution of 0.25 degrees at a rate of 33 seconds per scan. The ability to acquire many scans within narrow windows of temporal stability for ecological variables has facilitated the more complete investigation of ecosystem structural characteristics, and their expression as a function of view angle. The lightweight CBL has facilitated the use of alternative deployment platforms including towers, trams and masts, allowing analysis of the vertical structure of ecosystems, even in highly enclosed environments such as the sub-canopy of tropical forests where aerial vehicles cannot currently operate. We will present results from view angle analyses of lidar surveys of tropical rainforest in La Selva, Costa Rica where the CBL was deployed at heights up to 10m in Carbono long-term research plots utilizing a portable mast, and on a 25m stationary tower; and temperate forest at Harvard Forest, Massachusetts, USA, where the CBL has been deployed biannually at long-term research plots of hardwood and hemlock, as well as at heights of up to 25m utilizing a stationary tower.

  18. Assessment of the terrestrial water balance using the global water availability and use model WaterGAP - status and challenges

    NASA Astrophysics Data System (ADS)

    Müller Schmied, Hannes; Döll, Petra

    2017-04-01

    The estimation of the World's water resources has a long tradition and numerous methods for quantification exists. The resulting numbers vary significantly, leaving room for improvement. Since some decades, global hydrological models (GHMs) are being used for large scale water budget assessments. GHMs are designed to represent the macro-scale hydrological processes and many of those models include human water management, e.g. irrigation or reservoir operation, making them currently the first choice for global scale assessments of the terrestrial water balance within the Anthropocene. The Water - Global Assessment and Prognosis (WaterGAP) is a model framework that comprises both the natural and human water dimension and is in development and application since the 1990s. In recent years, efforts were made to assess the sensitivity of water balance components to alternative climate forcing input data and, e.g., how this sensitivity is affected by WaterGAP's calibration scheme. This presentation shows the current best estimate of terrestrial water balance components as simulated with WaterGAP by 1) assessing global and continental water balance components for the climate period 1971-2000 and the IPCC reference period 1986-2005 for the most current WaterGAP version using a homogenized climate forcing data, 2) investigating variations of water balance components for a number of state-of-the-art climate forcing data and 3) discussing the benefit of the calibration approach for a better observation-data constrained global water budget. For the most current WaterGAP version 2.2b and a homogenized combination of the two WATCH Forcing Datasets, global scale (excluding Antarctica and Greenland) river discharge into oceans and inland sinks (Q) is assessed to be 40 000 km3 yr-1 for 1971-2000 and 39 200 km3 yr-1 for 1986-2005. Actual evapotranspiration (AET) is close to each other with around 70 600 (70 700) km3 yr-1 as well as water consumption with 1000 (1100) km3 yr-1. The main reason for differing Q is varying precipitation (P, 111 600 km3 yr-1 vs. 110 900 km3 yr-1). The sensitivity of water balance components to alternative climate forcing data is high. Applying 5 state-of-the-art climate forcing data sets, long term average P differs globally by 8000 km3 yr-1, mainly due to different handling of precipitation undercatch correction (or neglecting it). AET differs by 5500 km3 yr-1 whereas Q varies by 3000 km3 yr-1. The sensitivity of human water consumption to alternative climate input data is only about 5%. WaterGAP's calibration approach forces simulated long-term river discharge to be approximately equal to observed values at 1319 gauging stations during the time period selected for calibration. This scheme greatly reduces the impact of uncertain climate input on simulated Q data in these upstream drainage basins (as well as downstream). In calibration areas, the Q variation among the climate input data is much lower (1.6%) than in non-calibrated areas (18.5%). However, variation of Q at the grid cell-level is still high (an average of 37% for Q in grid cells in calibration areas vs. 74% outside). Due to the closed water balance, variation of AET is higher in calibrated areas than in non-calibrated areas. Main challenges in assessing the world's water resources by GHMs like WaterGAP are 1) the need of consistent long-term climate forcing input data sets, especial considering a suitable handling of P undercatch, 2) the accessibility of in-situ data for river discharge or alternative calibration data for currently non-calibrated areas, and 3) an improved simulation in semi-arid and arid river basins. As an outlook, a multi-model, multi-forcing study of global water balance components within the frame of the Inter-Sectoral Impact Model Intercomparison Project is proposed.

  19. Microstructural Changes in Inconel 740 After Long-Term Aging in the Presence and Absence of Stress

    NASA Astrophysics Data System (ADS)

    Unocic, K. A.; Shingledecker, J. P.; Tortorelli, P. F.

    2014-12-01

    The Ni-based alloy, Inconel® 740, is being extensively examined for use in advanced ultrasupercritical steam boilers because its precipitation-strengthened microstructure appears to offer the necessary creep strength under the high temperatures and pressures (up to 760°C and 35 MPa) needed for high efficiency power generation. However, because this application requires extremely long lifetimes under these conditions (up to 30 years), long-term microstructure stability is a major concern. In this paper, results from microstructural analyses of Inconel 740 specimens aged at 700 and 750°C in the presence and absence of creep loading for times up to ~31,000 h are presented. The primary focus was on the development of the eta η (Ni3Ti) phase and coarsening of coherent γ'-Ni3(Al,Ti) precipitates and its depletion near eta/matrix interfaces. However, despite these processes, Inconel 740 showed adequate long-term microstructural stability to assure adequate creep strength for the intended application.

  20. Stressed Stability Techniques for Adjuvant Formulations.

    PubMed

    Hasija, Manvi; Sheung, Anthony; Rahman, Nausheen; Ausar, Salvador F

    2017-01-01

    Stressed stability testing is crucial to the understanding of mechanisms of degradation and the effects of external stress factors on adjuvant stability. These studies vastly help the development of stability indicating tests and the selection of stabilizing conditions for long term storage. In this chapter, we provide detailed protocols for the execution of forced degradation experiments that evaluate the robustness of adjuvant formulations against thermal, mechanical, freeze-thawing, and photo stresses.

  1. Calibration standard of body tissue with magnetic nanocomposites for MRI and X-ray imaging

    NASA Astrophysics Data System (ADS)

    Rahn, Helene; Woodward, Robert; House, Michael; Engineer, Diana; Feindel, Kirk; Dutz, Silvio; Odenbach, Stefan; StPierre, Tim

    2016-05-01

    We present a first study of a long-term phantom for Magnetic Resonance Imaging (MRI) and X-ray imaging of biological tissues with magnetic nanocomposites (MNC) suitable for 3-dimensional and quantitative imaging of tissues after, e.g. magnetically assisted cancer treatments. We performed a cross-calibration of X-ray microcomputed tomography (XμCT) and MRI with a joint calibration standard for both imaging techniques. For this, we have designed a phantom for MRI and X-ray computed tomography which represents biological tissue enriched with MNC. The developed phantoms consist of an elastomer with different concentrations of multi-core MNC. The matrix material is a synthetic thermoplastic gel, PermaGel (PG). The developed phantoms have been analyzed with Nuclear Magnetic Resonance (NMR) Relaxometry (Bruker minispec mq 60) at 1.4 T to obtain R2 transverse relaxation rates, with SQUID (Superconducting QUantum Interference Device) magnetometry and Inductively Coupled Plasma Mass Spectrometry (ICP-MS) to verify the magnetite concentration, and with XμCT and 9.4 T MRI to visualize the phantoms 3-dimensionally and also to obtain T2 relaxation times. A specification of a sensitivity range is determined for standard imaging techniques X-ray computed tomography (XCT) and MRI as well as with NMR. These novel phantoms show a long-term stability over several months up to years. It was possible to suspend a particular MNC within the PG reaching a concentration range from 0 mg/ml to 6.914 mg/ml. The R2 relaxation rates from 1.4 T NMR-relaxometry show a clear connection (R2=0.994) with MNC concentrations between 0 mg/ml and 4.5 mg/ml. The MRI experiments have shown a linear correlation of R2 relaxation and MNC concentrations as well but in a range between MNC concentrations of 0 mg/ml and 1.435 mg/ml. It could be shown that XμCT displays best moderate and high MNC concentrations. The sensitivity range for this particular XμCT apparatus yields from 0.569 mg/ml to 6.914 mg/ml. The cross-calibration has defined a shared sensitivity range of XμCT, 1.4 T NMR relaxometer minispec, and 9.4 T MRI. The shared sensitivity range for the measuring method (NMR relaxometry) and the imaging modalities (XμCT and MRI) is from 0.569 mg/ml, limited by XμCT, and 1.435 mg/ml, limited by MRI. The presented phantoms have been found to be suitable to act as a body tissue substitute for XCT imaging as well as an acceptable T2 phantom of biological tissue enriched with magnetic nanoparticles for MRI.

  2. Watershed models for decision support in the Yakima River basin, Washington

    USGS Publications Warehouse

    Mastin, M.C.; Vaccaro, J.J.

    2002-01-01

    A Decision Support System (DSS) is being developed by the U.S. Geological Survey and the Bureau of Reclamation as part of a long-term project, the Watershed and River Systems Management Program. The goal of the program is to apply the DSS to U.S. Bureau of Reclamation projects in the western United States. The DSS was applied to the Reclamation's Yakima Project in the Yakima River Basin in eastern Washington. An important component of the DSS is the physical hydrology modeling. For the application to the Yakima River Basin, the physical hydrology component consisted of constructing four watershed models using the U.S. Geological Survey's Precipitation-Runoff Modeling System within the Modular Modeling System. The implementation of these models is described. To facilitate calibration of the models, mean annual streamflow also was estimated for ungaged subbasins. The models were calibrated for water years 1950-94 and tested for water years 1995-98. The integration of the models in the DSS for real-time water-management operations using an interface termed the Object User Interface is also described. The models were incorporated in the DSS for use in long-term to short-term planning and have been used in a real-time operational mode since water year 1999.

  3. Response of Late Cretaceous migrating deltaic facies systems to sea level, tectonics, and sediment supply changes, New Jersey Coastal Plain, U.S.A.

    USGS Publications Warehouse

    Kulpecz, A.A.; Miller, K.G.; Sugarman, P.J.; Browning, J.V.

    2008-01-01

    Paleogeographic, isopach, and deltaic lithofacies mapping of thirteen depositional sequences establish a 35 myr high resolution (> 1 Myr) record of Late Cretaceous wave- and tide-influenced deltaic sedimentation. We integrate sequences defined on the basis of lithologic, biostratigraphic, and Sr-isotope stratigraphy from cores with geophysical log data from 28 wells to further develop and extend methods and calibrations of well-log recognition of sequences and facies variations. This study reveals the northeastward migration of depocenters from the Cenomanian (ca. 98 Ma) through the earliest Danian (ca. 64 Ma) and documents five primary phases of paleodeltaic evolution in response to long-term eustatic changes, variations in sediment supply, the location of two long-lived fluvial axes, and thermoflexural basement subsidence: (1) Cenomanian-early Turonian deltaic facies exhibit marine and nonmarine facies and are concentrated in the central coastal plain; (2) high sediment rates, low sea level, and high accommodation rates in the northern coastal plain resulted in thick, marginal to nonmarine mixed-influenced deltaic facies during the Turonign-Coniacian; (3) comparatively low sediment rates and high long-term sea level in the Santonian resulted in a sediment-starved margin with low deltaic influence; (4) well-developed Campanian deltaic sequences expand to the north and exhibit wave reworking and longshore transport of sands, and (5) low sedimentation rates and high long-term sea level during the Maastrichtian resulted in the deposition of a sediment-starved glauconitic shelf. Our study illustrates the widely known variability of mixed-influence deltaic systems, but also documents the relative stability of deltaic facies systems on the 106-107 yr scale, with long periods of cyclically repeating systems tracts controlled by eustasy. Results from the Late Cretaceous further show that although eustasy provides the template for sequences globally, regional tectonics (rates of subsidence and accommodation), changes in sediment supply, proximity to sediment input, and flexural subsidence from depocenter loading determines the regional to local preservation and facies expression of sequences. Copyright ?? 2008, SEPM (Society for Sedimentary Geology).

  4. A combined interfacial and in-situ polymerization strategy to construct well-defined core-shell epoxy-containing SiO2-based microcapsules with high encapsulation loading, super thermal stability and nonpolar solvent tolerance

    NASA Astrophysics Data System (ADS)

    Jia; Wang; Tian; Li; Xu; Jiao; Cao; Wu

    2016-10-01

    SiO2-based microcapsules containing hydrophobic molecules exhibited potential applications such as extrinsic self-healing, drug delivery, due to outstanding thermal and chemical stability of SiO2. However, to construct SiO2-based microcapsules with both high encapsulation loading and long-term structural stability is still a troublesome issue, limiting their further utilization. We herein design a single-batch route, a combined interfacial and in-situ polymerization strategy, to fabricate epoxy-containing SiO2-based microcapsules with both high encapsulation loading and long-term structural stability. The final SiO2-based microcapsules preserve high encapsulation loading of 85.7 wt% by controlling exclusively hydrolysis and condensed polymerization at oil/water interface in the initial interfacial polymerization step. In the subsequent in-situ polymerization step, the initial SiO2-based microcapsules as seeds could efficiently harvest SiO2 precursors and primary SiO2 particles to finely tune the SiO2 wall thickness, thereby enhancing long-term structural stability of the final SiO2-based microcapsules including high thermal stability with almost no any weight loss until 250°C, and strong tolerance against nonpolar solvents such as CCl4 with almost unchanged core-shell structure and unchanged core weight after immersing into strong solvents for up to 5 days. These SiO2-based microcapsules are extremely suited for processing them into anticorrosive coating in the presence of nonpolar solvents for self-healing application.

  5. Accurate Determination of Soluble Axl by Enzyme-Linked Immunosorbent Assay.

    PubMed

    Dengler, Mirko; Huber, Heidemarie; Müller, Christian J; Zellmer, Angela; Rauch, Peter; Mikulits, Wolfgang

    2016-11-01

    Levels of soluble Axl (sAxl) are routinely assessed in human sera by sandwich enzyme-linked immunosorbent assay (ELISA). Although sAxl values are suggested to diagnose different types of disorders, no uniform ELISA method is available, allowing the reliable interassay comparison between results. Furthermore, little is known about the stability of sAxl under storage conditions, which is a relevant parameter for biomedical trials. The evaluation of sAxl stability under various stress conditions and the determination of proper conditions to use the sAxl ELISA for routine clinical applications are of great interest. In this study, serum samples were subjected to freeze-thaw cycles and incubation at different temperatures to analyze the stability of sAxl by ELISA. Dilution and spike-in experiments were carried out to examine the impact of serum and diluent components on the ELISA performance. Various diluents and media were employed to resolve masking effects of the serum. The assay components were further optimized for long-term usability by treatment with stabilizers and validation under temperature stress. Indeed, sAxl showed long-term stability in serum during freeze-thaw cycles and incubation under temperature stress conditions. The dilution experiments revealed that unknown components in the serum caused masking effects that can be reduced by proper dilutions. The assay performance was further increased by using a standardized buffer system to dilute serum samples. Stabilization of coated plates and of streptavidin-horseradish peroxidase allowed long-term storage for up to 6 months. In sum, our data demonstrate proper ELISA conditions, allowing the accurate analysis of sAxl levels in human serum.

  6. GLAS Long-Term Archive: Preservation and Stewardship for a Vital Earth Observing Mission

    NASA Astrophysics Data System (ADS)

    Fowler, D. K.; Moses, J. F.; Zwally, J.; Schutz, B. E.; Hancock, D.; McAllister, M.; Webster, D.; Bond, C.

    2012-12-01

    Data Stewardship, preservation, and reproducibility are fast becoming principal parts of a data manager's work. In an era of distributed data and information systems, it is of vital importance that organizations make a commitment to both current and long-term goals of data management and the preservation of scientific data. Satellite missions and instruments go through a lifecycle that involves pre-launch calibration, on-orbit data acquisition and product generation, and final reprocessing. Data products and descriptions flow to the archives for distribution on a regular basis during the active part of the mission. However there is additional information from the product generation and science teams needed to ensure the observations will be useful for long term climate studies. Examples include ancillary input datasets, product generation software, and production history as developed by the team during the course of product generation. These data and information will need to be archived after product data processing is completed. NASA has developed a set of Earth science data and information content requirements for long term preservation that is being used for all the EOS missions as they come to completion. Since the ICESat/GLAS mission was one of the first to end, NASA and NSIDC, in collaboration with the science team, are collecting data, software, and documentation, preparing for long-term support of the ICESat mission. For a long-term archive, it is imperative to preserve sufficient information about how products were prepared in order to ensure future researchers that the scientific results are accurate, understandable, and useable. Our experience suggests data centers know what to preserve in most cases. That is, the processing algorithms along with the Level 0 or Level 1a input and ancillary products used to create the higher-level products will be archived and made available to users. In other cases, such as pre-launch, calibration/validation, and test data, the data centers must seek guidance from the science team. All these data are essential for product provenance, contributing to and helping establish the integrity of the scientific observations for long term climate studies. In this presentation we will describe application of information gathering with guidance from the ICESat/GLAS Science Team, and the flow of additional information from the ICESat Science team and Science Investigator-Led Processing System to the NSIDC Distributed Active Archive Center. This presentation will also cover how we envision user support through the years of the Long-Term Archive.

  7. Aspartame-stabilized gold-silver bimetallic biocompatible nanostructures with plasmonic photothermal properties, antibacterial activity, and long-term stability.

    PubMed

    Fasciani, Chiara; Silvero, M Jazmin; Anghel, Maria Alexandra; Argüello, Gerardo A; Becerra, Maria Cecilia; Scaiano, Juan C

    2014-12-17

    Gold-silver core-shell nanoparticles stabilized with a common sweetener, aspartame (AuNP@Ag@Asm), combine the antimicrobial properties of silver with the photoinduced plasmon-mediated photothermal effects of gold. The particles were tested with several bacterial strains, while biocompatibility was verified with human dermal fibroblasts.

  8. The lightest organic radical cation for charge storage in redox flow batteries

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Huang, Jinhua; Pan, Baofei; Duan, Wentao

    2016-08-25

    Electrochemically reversible fluids of high energy density are promising materials for capturing the electrical energy generated from intermittent sources like solar and wind. To meet this technological challenge there is a need to understand the fundamental limits and interplay of electrochemical potential, stability and solubility in “lean” derivatives of redox-active molecules. Here we describe the process of molecular pruning, illustrated for 2,5-di-tert-butyl-1,4-bis(2-methoxyethoxy)benzene, a molecule known to produce a persistently stable, high-potential radical cation. By systematically shedding molecular fragments considered important for radical cation steric stabilization, we discovered a minimalistic structure that retains long-term stability in its oxidized form. Interestingly, wemore » find the tert-butyl groups are unnecessary; high stability of the radical cation and high solubility are both realized in derivatives having appropriately positioned arene methyl groups. These stability trends are rationalized by mechanistic considerations of the postulated decomposition pathways. We suggest that the molecular pruning approach will uncover lean redox active derivatives for electrochemical energy storage leading to materials with long-term stability and high intrinsic capacity.« less

  9. Cross-calibration between airborne SAR sensors

    NASA Technical Reports Server (NTRS)

    Zink, Manfred; Olivier, Philippe; Freeman, Anthony

    1993-01-01

    As Synthetic Aperture Radar (SAR) system performance and experience in SAR signature evaluation increase, quantitative analysis becomes more and more important. Such analyses require an absolute radiometric calibration of the complete SAR system. To keep the expenditure on calibration of future multichannel and multisensor remote sensing systems (e.g., X-SAR/SIR-C) within a tolerable level, data from different tracks and different sensors (channels) must be cross calibrated. The 1989 joint E-SAR/DC-8 SAR calibration campaign gave a first opportunity for such an experiment, including cross sensor and cross track calibration. A basic requirement for successful cross calibration is the stability of the SAR systems. The calibration parameters derived from different tracks and the polarimetric properties of the uncalibrated data are used to describe this stability. Quality criteria for a successful cross calibration are the agreement of alpha degree values and the consistency of radar cross sections of equally sized corner reflectors. Channel imbalance and cross talk provide additional quality in case of the polarimetric DC-8 SAR.

  10. The long-term hydrological effect of forest stands on the stability of slopes

    NASA Astrophysics Data System (ADS)

    Bogaard, T. A.; Meng, W.; van Beek, L. P. H.

    2012-04-01

    Forest is widely known to improve slope stability as a result of mechanical and hydrological effects. While the mechanics underlying the stabilizing process of root reinforcement are well understood and quantified, the influence of forest on the occurrence of critical hydrological conditions in terms of suction or pore pressure remains uncertain. Due to seasonal and inter-annual fluctuations, the stabilizing influence of evaporation and transpiration is difficult to isolate from the overall noise of the hydrological signal. More long-term effects of forest stands on soil development are highly variable and thus difficult to observe and quantify. Often these effects are ambivalent, having potentially a stabilizing or destabilizing influence on a slope under particular conditions (e.g., more structured soils leading to both rapid infiltration and drainage). Consequently, it can be postulated that forests will hydrologically influence the magnitude-frequency distribution of landsliding, not only at the stand level but also on a regional scale through the groundwater system. The overall aim of this research is to understand and quantify the stabilizing hydrological effect of forests on potentially unstable slopes. To this end, we focus on the changes in the magnitude-frequency distribution of landsliding that arise as a result of variations in evapotranspiration losses over the life cycle of stands. Temporal variations in evapotranspiration comprise first of all the interception that can account for an important amount of evaporation from a forest, and that changes with seasonal and annual variations in the interception capacity of the canopy and forest floor. Transpiration also represents an important loss that varies over the various growth stages of a forest stand. Based on a literature review of water consumption by tree species and water balance studies of forested catchments we defined the potential transpiration for different growth stages. This information we used in a spatially distributed, physical-based, dynamical model to simulate the hydrology and resulting stability for a catchment on a daily scale. The results can be used to identify end members of the hydrological influence of forests on slope stability and the typical variations in stability associated with the various growth stages. They indicate that the influence of forest stand age on the water consumption can be significant and has clear consequences for the antecedent soil moisture condition within a slope and thus on the potential for slope destabilization. The outcome should help to understand the long-term impact of vegetation on slope hydrology and define sustainable and reliable management strategies at the scale of forest stands. Keywords: slope stability, hydrology, vegetation, long-tem effect

  11. SiC/Mg multilayer coatings for SCORE coronagraph: long term stability analysis

    NASA Astrophysics Data System (ADS)

    Pelizzo, Maria Guglielmina; Fineschi, Silvano; Zuppella, Paola; Corso, Alain Jody; Windt, David L.; Nicolosi, Piergiorgio

    2011-10-01

    SiC/Mg multilayers have been used as coatings of the Sounding-rocket CORonagraphic Experiment (SCORE) telescope mirrors launched during the NASA HERSCHEL program. This materials couple has been largely studied by researchers since it provides higher performances than a standard Mo/Si multilayer; the SCORE mirrors show in fact a peak reflectance of around 40% at HeII 30.4 nm. Nevertheless, long term stability of this coating is an open problem. A study on the aging and stability of this multilayer has been carried on. SiC/Mg multilayer samples characterized by different structural parameters have been deposited. They have been measured just after deposition and four years later to verify degradation based on natural aging. Experimental results and analysis are presented.

  12. Multiphysics processes in partially saturated fractured rock: Experiments and models from Yucca Mountain

    NASA Astrophysics Data System (ADS)

    Rutqvist, Jonny; Tsang, Chin-Fu

    2012-09-01

    The site investigations at Yucca Mountain, Nevada, have provided us with an outstanding data set, one that has significantly advanced our knowledge of multiphysics processes in partially saturated fractured geological media. Such advancement was made possible, foremost, by substantial investments in multiyear field experiments that enabled the study of thermally driven multiphysics and testing of numerical models at a large spatial scale. The development of coupled-process models within the project have resulted in a number of new, advanced multiphysics numerical models that are today applied over a wide range of geoscientific research and geoengineering applications. Using such models, the potential impact of thermal-hydrological-mechanical (THM) multiphysics processes over the long-term (e.g., 10,000 years) could be predicted and bounded with some degree of confidence. The fact that the rock mass at Yucca Mountain is intensively fractured enabled continuum models to be used, although discontinuum models were also applied and are better suited for analyzing some issues, especially those related to predictions of rockfall within open excavations. The work showed that in situ tests (rather than small-scale laboratory experiments alone) are essential for determining appropriate input parameters for multiphysics models of fractured rocks, especially related to parameters defining how permeability might evolve under changing stress and temperature. A significant laboratory test program at Yucca Mountain also made important contributions to the field of rock mechanics, showing a unique relation between porosity and mechanical properties, a time dependency of strength that is significant for long-term excavation stability, a decreasing rock strength with sample size using very large core experiments, and a strong temperature dependency of the thermal expansion coefficient for temperatures up to 200°C. The analysis of in situ heater experiments showed that fracture closure/opening caused by changes in normal stress across fractures was the dominant mechanism for thermally induced changes in intrinsic fracture permeability during rock mass heating/cooling and that fracture shear dilation appears to be less significant. Significant effort was devoted to predicting the long-term stability of underground excavations under (mechanical) strength degradation and seismic loading, perhaps one of the most challenging tasks within the project. We note that such long-term strength degradation is actually an example of a chemically mediated process governed by underlying (microscopic) stress corrosion and chemical diffusion processes. In the Yucca Mountain Project, such chemically mediated mechanical changes were considered implicitly through model calibrations against laboratory and in situ heater experiments at temperatures anticipated to be experienced by the rock. A possible future research direction would be to simulate such processes mechanistically in a complete coupled THMC framework where C denotes chemical processes.

  13. Remote sensing of an agricultural soil moisture network in Walnut Creek, Iowa

    USDA-ARS?s Scientific Manuscript database

    The calibration and validation of soil moisture remote sensing products is complicated by the logistics of installing a soil moisture network for a long term period in an active landscape. Usually soil moisture sensors are added to existing precipitation networks which have as a singular requiremen...

  14. Solar diameter measurements for study of Sun climate coupling

    NASA Technical Reports Server (NTRS)

    Hill, H. A.

    1983-01-01

    Changes in solar shape and diameter were detected as a possible probe of variability in solar luminosity, an important climatic driving function. A technique was designed which will allow the calibration of the telescope field, providing a scale for long-term comparison of these and future measurements.

  15. Calibration of high frequency pollen sequences and tree-ring records

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wigand, P.E.; Rose, M.R.

    This paper examines two radiocarbon dated paleoenvironmental records from southern Nevada for the possibility of correlating high-frequency pollen samples with nearby long-term tree-ring sequences. Variable deposition rate are discussed. Radiocarbon dating control of the pollen cores, as well as closer interval sampling is presented.

  16. Urban tree growth modeling

    Treesearch

    E. Gregory McPherson; Paula J. Peper

    2012-01-01

    This paper describes three long-term tree growth studies conducted to evaluate tree performance because repeated measurements of the same trees produce critical data for growth model calibration and validation. Several empirical and process-based approaches to modeling tree growth are reviewed. Modeling is more advanced in the fields of forestry and...

  17. Preconcentration for Improved Long-Term Monitoring of Contaminants in Groundwater: Sorbent Development

    DTIC Science & Technology

    2013-02-11

    calibration curves was ±5%. Ion chromatography (IC) was used for analysis of perchlorate and other ionic targets. Analysis was carried out on a...The methods utilize liquid or gas chromatography , techniques that do not lend themselves well to portable devices and methods. Portable methods are...

  18. Development of a package-free transparent disposable biosensor chip for simultaneous measurements of blood constituents and investigation of its storage stability.

    PubMed

    Nakamura, Hideaki; Tohyama, Kana; Tanaka, Masanori; Shinohara, Shouji; Tokunaga, Yuichi; Kurusu, Fumiyo; Koide, Satoshi; Gotoh, Masao; Karube, Isao

    2007-12-15

    A package-free transparent disposable biosensor chip was developed by a screen-printing technique. The biosensor chip was fabricated by stacking a substrate with two carbon electrodes on its surface, a spacer consisting of a resist layer and an adhesive layer, and a cover. The structure of the chip keeps the interior of the reaction-detecting section airtight until use. The chip is equipped with double electrochemical measuring elements for the simultaneous measurement of multiple items, and the reagent layer was developed in sample-feeding path. The sample-inlet port and air-discharge port are simultaneously opened by longitudinally folding in two biosensor units with a notch as a boundary. Then the shape of the chip is changed to a V-shape. The reaction-detecting section of the chip has a 1.0 microl sample volume for one biosensor unit. Excellent results were obtained with the chip in initial simultaneous chronoamperometric measurements of both glucose (r=1.00) and lactate (r=0.998) in the same samples. The stability of the enzyme sensor signals of the chip was estimated at ambient atmosphere on 8 testing days during a 6-month period. The results were compared with those obtained for an unpackaged chip used as a control. The package-free chip proved to be twice as good as the control chip in terms of the reproducibility of slopes from 16 calibration curves (one calibration curve: 0, 100, 300, 500 mg dl(-1) glucose; n=3) and 4.6 times better in terms of the reproducibility of correlation coefficients from the 16 calibration curves.

  19. Rapid Recovery of Clofazimine-Loaded Nanoparticles with Long-Term Storage Stability as Anti-Cryptosporidium Therapy.

    PubMed

    Feng, Jie; Zhang, Yingyue; McManus, Simon A; Ristroph, Kurt D; Lu, Hoang D; Gong, Kai; White, Claire E; Prud'homme, Robert K

    2018-05-25

    While the formulation of nanoparticle (NP) suspensions has been widely applied in materials and life science, the recovery of NPs from such a suspension into a solid state is practically important to confer long-term storage stability. However, solidification, while preserving the original nanoscale properties, remains a formidable challenge in the pharmaceutical and biomedical applications of NPs. Herein we combined flash nanoprecipitation (FNP) and spray-drying as a nanofabrication platform for NP formulation and recovery without compromising the dissolution kinetics of the active ingredient. Clofazimine was chosen to be the representative drug, which has been recently repurposed as a potential treatment for cryptosporidiosis. Clofazimine was encapsulated in NPs with low-cost surface coatings, hypromellose acetate succinate (HPMCAS) and lecithin, which were required by the ultimate application to global health. Spray-drying and lyophilization were utilized to produce dried powders with good long-term storage stability for application in hot and humid climatic zones. The particle morphology, yield efficiency, drug loading, and clofazimine crystallinity in the spray-dried powders were characterized. The in vitro release kinetics of spray-dried NP powders were compared to analogous dissolution profiles from standard lyophilized NP samples, crystalline clofazimine powder, and the commercially available formulation Lamprene. The spray-dried powders showed a supersaturation level of up to 60 times the equilibrium solubility and remarkably improved dissolution rates. In addition, the spray-dried powders with both surface coatings showed excellent stability during aging studies with elevated temperature and humidity, in view of the dissolution and release in vitro. Considering oral delivery for pediatric administration, the spray-dried powders show less staining effects with simulated skin than crystalline clofazimine and may be made into minitablets without additional excipients. These results highlight the potential of combining FNP and spray-drying as a feasible and versatile platform to design and rapidly recover amorphous NPs in a solid dosage form, with the advantages of satisfactory long-term storage stability, low cost, and easy scalability.

  20. Calibration procedure for Slocum glider deployed optical instruments.

    PubMed

    Cetinić, Ivona; Toro-Farmer, Gerardo; Ragan, Matthew; Oberg, Carl; Jones, Burton H

    2009-08-31

    Recent developments in the field of the autonomous underwater vehicles allow the wide usage of these platforms as part of scientific experiments, monitoring campaigns and more. The vehicles are often equipped with sensors measuring temperature, conductivity, chlorophyll a fluorescence (Chl a), colored dissolved organic matter (CDOM) fluorescence, phycoerithrin (PE) fluorescence and spectral volume scattering function at 117 degrees, providing users with high resolution, real time data. However, calibration of these instruments can be problematic. Most in situ calibrations are performed by deploying complementary instrument packages or water samplers in the proximity of the glider. Laboratory calibrations of the mounted sensors are difficult due to the placement of the instruments within the body of the vehicle. For the laboratory calibrations of the Slocum glider instruments we developed a small calibration chamber where we can perform precise calibrations of the optical instruments aboard our glider, as well as sensors from other deployment platforms. These procedures enable us to obtain pre- and post-deployment calibrations for optical fluorescence instruments, which may differ due to the biofouling and other physical damage that can occur during long-term glider deployments. We found that biofouling caused significant changes in the calibration scaling factors of fluorescent sensors, suggesting the need for consistent and repetitive calibrations for gliders as proposed in this paper.

  1. Use of inexpensive vegetable oils to ensure the long-term stability of sweet sorghum syrups for the manufacture of bioproducts

    USDA-ARS?s Scientific Manuscript database

    Fundamental processing needs identified by industry for the large-scale manufacture of biofuels and bioproducts from sweet sorghum (Sorghum bicolor L. Moench), include the long-term storage of 65 Brix syrups for year-round supply, efficient transport, and acceptable end-product yields. Sweet sorghu...

  2. Long-term tillage and cropping effects on biological properties associated with soil aggregation in semi-arid eastern Montana, USA

    USDA-ARS?s Scientific Manuscript database

    Long-term tillage and cropping may influence biological attributes responsible for semi-arid soil aggregation in Montana, USA. Aggregate stability, glomalin, basidiomycete fungi, uronic acids, total organic C (TOC) and total N (TN) at 0-5 cm soil depth from 1991 to 2003 were evaluated in different a...

  3. Long-term N fertilization and conservation tillage practices conserve surface but not profile SOC stocks under semi-arid irrigated corn

    USDA-ARS?s Scientific Manuscript database

    No tillage (NT) and N fertilization can increase surface soil organic C (SOC) stocks, but the effects deeper in the soil profile are uncertain. Subsequent tillage could counter SOC stabilized through NT practices by disrupting soil aggregation and promoting decomposition. We followed a long-term ti...

  4. The Incidence of Adjacent Segment Degeneration after the Use of a Versatile Dynamic Hybrid Stabilization Device in Lumbar Stenosis: Results of a 5–8-Year Follow-up

    PubMed Central

    Dobran, Mauro; Esposito, Domenico Paolo; Gladi, Maurizio; Scerrati, Massimo; Iacoangeli, Maurizio

    2018-01-01

    Study Design Retrospective study with long-term follow-up. Purpose To evaluate the long-term incidence of adjacent segment degeneration (ASD) and clinical outcomes in a consecutive series of patients who underwent spinal decompression associated with dynamic or hybrid stabilization with a Flex+TM stabilization system (SpineVision, Antony, France) for lumbar spinal stenosis. Overview of Literature The incidence of ASD and clinical outcomes following dynamic or hybrid stabilization with the Flex+TM system used for lumbar spinal stenosis have not been well investigated. Methods Twenty-one patients with lumbar stenosis and probable post-decompressive spinal instability underwent decompressive laminectomy followed by spinal stabilization using the Flex+TM stabilization system. The indication for a mono-level dynamic stabilization was a preoperative magnetic resonance imaging (MRI) demonstrating evidence of severe disc disease associated with severe spinal stenosis. The hybrid stabilization (rigid-dynamic) system was used for multilevel laminectomies with associated initial degenerative scoliosis, first-grade spondylolisthesis, or rostral pathology. Results The improvement in Visual Analog Scale and Oswestry Disability Index scores at follow-up were statistically significant (p<0.0001 and p<0.0001, respectively). At the 5–8-year follow-up, clinical examination, MRI, and X-ray findings showed an ASD complication with pain and disability in one of 21 patients. The clinical outcomes were similar in patients treated with dynamic or hybrid fixation. Conclusions Patients treated with laminectomy and Flex+TM stabilization presented a satisfactory clinical outcome after 5–8 years of follow-up, and ASD incidence in our series was 4.76% (one patient out of 21). We are aware that this is a small series, but our long-term follow-up may be sufficient to contribute to the expanding body of literature on the development of symptomatic ASD associated with dynamic or hybrid fixation. PMID:29713407

  5. Characterization of highly concentrated antibody solution - A toolbox for the description of protein long-term solution stability

    PubMed Central

    Schermeyer, Marie-Therese; Wöll, Anna K.; Eppink, Michel; Hubbuch, Jürgen

    2017-01-01

    ABSTRACT High protein titers are gaining importance in biopharmaceutical industry. A major challenge in the development of highly concentrated mAb solutions is their long-term stability and often incalculable viscosity. The complexity of the molecule itself, as well as the various molecular interactions, make it difficult to describe their solution behavior. To study the formulation stability, long- and short-range interactions and the formation of complex network structures have to be taken into account. For a better understanding of highly concentrated solutions, we combined established and novel analytical tools to characterize the effect of solution properties on the stability of highly concentrated mAb formulations. In this study, monoclonal antibody solutions in a concentration range of 50–200 mg/ml at pH 5–9 with and without glycine, PEG4000, and Na2SO4 were analyzed. To determine the monomer content, analytical size-exclusion chromatography runs were performed. ζ-potential measurements were conducted to analyze the electrophoretic properties in different solutions. The melting and aggregation temperatures were determined with the help of fluorescence and static light scattering measurements. Additionally, rheological measurements were conducted to study the solution viscosity and viscoelastic behavior of the mAb solutions. The so-determined analytical parameters were scored and merged in an analytical toolbox. The resulting scoring was then successfully correlated with long-term storage (40 d of incubation) experiments. Our results indicate that the sensitivity of complex rheological measurements, in combination with the applied techniques, allows reliable statements to be made with respect to the effect of solution properties, such as protein concentration, ionic strength, and pH shift, on the strength of protein-protein interaction and solution colloidal stability. PMID:28617076

  6. An Overview of Suomi NPP VIIRS Calibration Maneuvers

    NASA Technical Reports Server (NTRS)

    Butler, James J.; Xiong, Xiaoxiong; Barnes, Robert A.; Patt, Frederick S.; Sun, Junqiang; Chiang, Kwofu

    2012-01-01

    The first Visible Infrared Imager Radiometer Suite (VIIRS) instrument was successfully launched on-board the Suomi National Polar-orbiting Partnership (SNPP) spacecraft on October 28, 2011. Suomi NPP VIIRS observations are made in 22 spectral bands, from the visible (VIS) to the long-wave infrared (LWIR), and are used to produce 22 Environmental Data Records (EDRs) with a broad range of scientific applications. The quality of these VIIRS EDRs strongly depends on the quality of its calibrated and geo-located Sensor Date Records (SDRs). Built with a strong heritage to the NASA's EOS MODerate resolution Imaging Spectroradiometer (MODIS) instrument, the VIIRS is calibrated on-orbit using a similar set of on-board calibrators (OBC), including a solar diffuser (SD) and solar diffuser stability monitor (SDSM) system for the reflective solar bands (RSB) and a blackbody (BB) for the thermal emissive bands (TEB). On-orbit maneuvers of the SNPP spacecraft provide additional calibration and characterization data from the VIIRS instrument which cannot be obtained pre-launch and are required to produce the highest quality SDRs. These include multi-orbit yaw maneuvers for the characterization of SD and SDSM screen transmission, quasi-monthly roll maneuvers to acquire lunar observations to track sensor degradation in the visible through shortwave infrared, and a driven pitch-over maneuver to acquire multiple scans of deep space to determine TEB response versus scan angle (RVS). This paper pro-vides an overview of these three SNPP calibration maneuvers. Discussions are focused on their potential calibration and science benefits, pre-launch planning activities, and on-orbit scheduling and implementation strategies. Results from calibration maneuvers performed during the Intensive Calibration and Validation (ICV) period for the VIIRS sensor are illustrated. Also presented in this paper are lessons learned regarding the implementation of calibration spacecraft maneuvers on follow-on missions.

  7. An overview of Suomi NPP VIIRS calibration maneuvers

    NASA Astrophysics Data System (ADS)

    Butler, James J.; Xiong, Xiaoxiong; Barnes, Robert A.; Patt, Frederick S.; Sun, Junqiang; Chiang, Kwofu

    2012-09-01

    The first Visible Infrared Imager Radiometer Suite (VIIRS) instrument was successfully launched on-board the Suomi National Polar-orbiting Partnership (SNPP) spacecraft on October 28, 2011. Suomi NPP VIIRS observations are made in 22 spectral bands, from the visible (VIS) to the long-wave infrared (LWIR), and are used to produce 22 Environmental Data Records (EDRs) with a broad range of scientific applications. The quality of these VIIRS EDRs strongly depends on the quality of its calibrated and geo-located Sensor Date Records (SDRs). Built with a strong heritage to the NASA's EOS MODerate resolution Imaging Spectroradiometer (MODIS) instrument, the VIIRS is calibrated on-orbit using a similar set of on-board calibrators (OBC), including a solar diffuser (SD) and solar diffuser stability monitor (SDSM) system for the reflective solar bands (RSB) and a blackbody (BB) for the thermal emissive bands (TEB). Onorbit maneuvers of the SNPP spacecraft provide additional calibration and characterization data from the VIIRS instrument which cannot be obtained pre-launch and are required to produce the highest quality SDRs. These include multiorbit yaw maneuvers for the characterization of SD and SDSM screen transmission, quasi-monthly roll maneuvers to acquire lunar observations to track sensor degradation in the visible through shortwave infrared, and a driven pitch-over maneuver to acquire multiple scans of deep space to determine TEB response versus scan angle (RVS). This paper provides an overview of these three SNPP calibration maneuvers. Discussions are focused on their potential calibration and science benefits, pre-launch planning activities, and on-orbit scheduling and implementation strategies. Results from calibration maneuvers performed during the Intensive Calibration and Validation (ICV) period for the VIIRS sensor are illustrated. Also presented in this paper are lessons learned regarding the implementation of calibration spacecraft maneuvers on follow-on missions.

  8. No Future in the Past? The role of initial topography on landform evolution model predictions

    NASA Astrophysics Data System (ADS)

    Hancock, G. R.; Coulthard, T. J.; Lowry, J.

    2014-12-01

    Our understanding of earth surface processes is based on long-term empirical understandings, short-term field measurements as well as numerical models. In particular, numerical landscape evolution models (LEMs) have been developed which have the capability to capture a range of both surface (erosion and deposition), tectonics, as well as near surface or critical zone processes (i.e. pedogenesis). These models have a range of applications for understanding both surface and whole of landscape dynamics through to more applied situations such as degraded site rehabilitation. LEMs are now at the stage of development where if calibrated, can provide some level of reliability. However, these models are largely calibrated based on parameters determined from present surface conditions which are the product of much longer-term geology-soil-climate-vegetation interactions. Here, we assess the effect of the initial landscape dimensions and associated error as well as parameterisation for a potential post-mining landform design. The results demonstrate that subtle surface changes in the initial DEM as well as parameterisation can have a large impact on landscape behaviour, erosion depth and sediment discharge. For example, the predicted sediment output from LEM's is shown to be highly variable even with very subtle changes in initial surface conditions. This has two important implications in that decadal time scale field data is needed to (a) better parameterise models and (b) evaluate their predictions. We question how a LEM using parameters derived from field plots can firstly be employed to examine long-term landscape evolution. Secondly, the potential range of outcomes is examined based on estimated temporal parameter change and thirdly, the need for more detailed and rigorous field data for calibration and validation of these models is discussed.

  9. On-orbit Metrology and Calibration Requirements for Space Station Activities Definition Study

    NASA Technical Reports Server (NTRS)

    Cotty, G. M.; Ranganathan, B. N.; Sorrell, A. L.

    1989-01-01

    The Space Station is the focal point for the commercial development of space. The long term routine operation of the Space Station and the conduct of future commercial activities suggests the need for in-space metrology capabilities analogous when possible to those on-Earth. The ability to perform periodic calibrations and measurements with proper traceability is imperative for the routine operation of the Space Station. An initial review, however, indicated a paucity of data related to metrology and calibration requirements for in-space operations. This condition probably exists because of the highly developmental aspect of space activities to date, their short duration, and nonroutine nature. The on-orbit metrology and calibration needs of the Space Station were examined and assessed. In order to achieve this goal, the following tasks were performed: an up-to-date literature review; identification of on-orbit calibration techniques; identification of sensor calibration requirements; identification of calibration equipment requirements; definition of traceability requirements; preparation of technology development plans; and preparation of the final report. Significant information and major highlights pertaining to each task is presented. In addition, some general (generic) conclusions/observations and recommendations that are pertinent to the overall in-space metrology and calibration activities are presented.

  10. Application of the Geophysical Scale Multi-Block Transport Modeling System to Hydrodynamic Forcing of Dredged Material Placement Sediment Transport within the James River Estuary

    NASA Astrophysics Data System (ADS)

    Kim, S. C.; Hayter, E. J.; Pruhs, R.; Luong, P.; Lackey, T. C.

    2016-12-01

    The geophysical scale circulation of the Mid Atlantic Bight and hydrologic inputs from adjacent Chesapeake Bay watersheds and tributaries influences the hydrodynamics and transport of the James River estuary. Both barotropic and baroclinic transport govern the hydrodynamics of this partially stratified estuary. Modeling the placement of dredged sediment requires accommodating this wide spectrum of atmospheric and hydrodynamic scales. The Geophysical Scale Multi-Block (GSMB) Transport Modeling System is a collection of multiple well established and USACE approved process models. Taking advantage of the parallel computing capability of multi-block modeling, we performed one year three-dimensional modeling of hydrodynamics in supporting simulation of dredged sediment placements transport and morphology changes. Model forcing includes spatially and temporally varying meteorological conditions and hydrological inputs from the watershed. Surface heat flux estimates were derived from the National Solar Radiation Database (NSRDB). The open water boundary condition for water level was obtained from an ADCIRC model application of the U. S. East Coast. Temperature-salinity boundary conditions were obtained from the Environmental Protection Agency (EPA) Chesapeake Bay Program (CBP) long-term monitoring stations database. Simulated water levels were calibrated and verified by comparison with National Oceanic and Atmospheric Administration (NOAA) tide gage locations. A harmonic analysis of the modeled tides was performed and compared with NOAA tide prediction data. In addition, project specific circulation was verified using US Army Corps of Engineers (USACE) drogue data. Salinity and temperature transport was verified at seven CBP long term monitoring stations along the navigation channel. Simulation and analysis of model results suggest that GSMB is capable of resolving the long duration, multi-scale processes inherent to practical engineering problems such as dredged material placement stability.

  11. Lessons Learned from GOSAT; Instrument Design, Calibration, Operation, Data Processing, and International Collaboration

    NASA Astrophysics Data System (ADS)

    Kuze, A.; Suto, H.; Shiomi, K.; Nakajima, M.

    2012-12-01

    Advantage of satellite observation is its ability to monitor long term and global distribution with a single instrument. Ozone observation from space has been successful for long term monitoring purposes. Monitoring gradual increase and distribution of greenhouse gases in the troposphere with sub-percent accuracy has become a challenging subject. Interference of cloud and aerosol in radiative transfer has to be corrected for troposphere measurement. Accurate O2-A band measurement can retrieve surface pressure and aerosol distribution property. We have selected a Fourier Transform spectrometer (FTS) to achieve high throughput and wide spectral coverage with uniform spectral resolution. On the other hand, it is difficult to modulate short wave such as 0.76μm and avoid micro vibration interference. Prelaunch, we took special care to select optical components of excellent surface quality and isolate vibration. Design parameters such as IFOV, spectral resolution, observation interval within limited satellite resources must be carefully optimized. Greenhouse gases Observing SATellite (GOSAT) has been providing global high spectral resolution data for almost 4 years. Instrument performance, radiometric calibration, radiative transfer calculation and laboratory spectroscopy are all important. The first step was to reduce bias of column-averaged dry air mole fractions (the Level 2 product) of CO2 and CH4 (XCO2 and XCH4) and validate using well calibrated data such as TCCON. After 2 years of operation, latitudinal distribution of zonal mean and seasonal variation at these sites can be measured with better than 2ppm accuracy. However, validations are limited to ideal conditions. Next step is to evaluate consistency of measured values from long periods since launch, different surface types, and various input radiance with different instrument gain. For long term radiometric calibration, we have uses vicarious, onboard solar diffuser, and lunar calibration data. Over the ocean we target sun glint (specular reflection) points, where the surface reflectance is not uniform or randomly distributed. Over the desert area, where surface reflectance is high and dust layers extend to high altitude, we have to use lower gain to avoid saturation and multiple scattering is complicated. For both ocean high albedo targets, validation data of XCO2 and XCH4 are limited. Validation by airplane become accurate but extrapolation is needed above flight attitude. Comparison of surface pressure between retrieved data and a priori model forecast fields is useful. For such kind of consistency, measurement must be very linear within wide dynamic range. After launch, we are re-evaluating the linearity of the detector, analog circuit and AD converters using a lab-model on the ground. Since launch, we have received feedback about the radiance spectra data from many data users of diverse institutes. We have gathered many calibration and validation data from international collaboration. We have modified the Level 1 algorithm and instrument calibrations several times. We are currently measuring the grid point of the Earth's surface, but the sampling for source and sink retrieval has not been optimized yet. We will present how we have solved problems, which portions of the instrument design we should modify, and items that we have not understood well yet.

  12. Long time stability of lamps with nanostructural carbon field emission cathodes

    NASA Astrophysics Data System (ADS)

    Kalenik, J.; Firek, P.; Szmidt, J.; Czerwosz, E.; Kozłowski, M.; Stepińska, I.; Wódka, T.

    2017-08-01

    A luminescent lamp with field emission cathode was constructed and tested. Phosphor excited by electrons from field emission cathode is the source of light. The cathode is covered with nickel-carbon film containing multilayer carbon nanotubes that enhance electron emission from the cathode. Results of luminance stability measurements are presented. Luminance of elaborated luminance lamp is high enough for lighting application. Long term stability (1000 hours) is satisfactory for mass lamp application. Initial short time decrease of luminance is still too high and it needs reduction.

  13. Calibrating damping rates with LEGACY linewidths

    NASA Astrophysics Data System (ADS)

    Houdek, Günter

    2017-10-01

    Linear damping rates of radial oscillation modes in selected Kepler stars are estimated with the help of a nonadiabatic stability analysis. The convective fluxes are obtained from a nonlocal, time-dependent convection model. The mixing-length parameter is calibrated to the surface-convection-zone depth of a stellar model obtained from fitting adiabatic frequencies to the LEGACY* observations, and two of the three nonlocal convection parameters are calibrated to the corresponding LEGACY* linewidth measurements. The atmospheric structure in the 1D stability analysis adopts a temperature-optical-depth relation derived from 3D hydrodynamical simulations. Results from 3D simulations are also used to calibrate the turbulent pressure and to guide the functional form of the depth-dependence of the anisotropy of the turbulent velocity field in the 1D stability computations.

  14. System stability and calibrations for hand-held electromagnetic frequency domain instruments

    NASA Astrophysics Data System (ADS)

    Saksa, Pauli J.; Sorsa, Joona

    2017-05-01

    There are a few multiple-frequency domain electromagnetic induction (EMI) hand-held rigid boom systems available for shallow geophysical resistivity investigations. They basically measure secondary field real and imaginary components after the system calibrations. One multiple-frequency system, the EMP-400 Profiler from Geophysical Survey Systems Inc., was tested for system calibrations, stability and various effects present in normal measurements like height variation, tilting, signal stacking and time stability. Results indicated that in test conditions, repeatable high-accuracy imaginary component values can be recorded for near-surface frequency soundings. In test conditions, real components are also stable but vary strongly in normal surveying measurements. However, certain calibration issues related to the combination of user influence and measurement system height were recognised as an important factor in reducing for data errors and for further processing like static offset corrections.

  15. A variable acceleration calibration system

    NASA Astrophysics Data System (ADS)

    Johnson, Thomas H.

    2011-12-01

    A variable acceleration calibration system that applies loads using gravitational and centripetal acceleration serves as an alternative, efficient and cost effective method for calibrating internal wind tunnel force balances. Two proof-of-concept variable acceleration calibration systems are designed, fabricated and tested. The NASA UT-36 force balance served as the test balance for the calibration experiments. The variable acceleration calibration systems are shown to be capable of performing three component calibration experiments with an approximate applied load error on the order of 1% of the full scale calibration loads. Sources of error are indentified using experimental design methods and a propagation of uncertainty analysis. Three types of uncertainty are indentified for the systems and are attributed to prediction error, calibration error and pure error. Angular velocity uncertainty is shown to be the largest indentified source of prediction error. The calibration uncertainties using a production variable acceleration based system are shown to be potentially equivalent to current methods. The production quality system can be realized using lighter materials and a more precise instrumentation. Further research is needed to account for balance deflection, forcing effects due to vibration, and large tare loads. A gyroscope measurement technique is shown to be capable of resolving the balance deflection angle calculation. Long term research objectives include a demonstration of a six degree of freedom calibration, and a large capacity balance calibration.

  16. Zairian Political Conditions and Prospects for Economic Development,

    DTIC Science & Technology

    1984-08-15

    political conditions and potential for long-term economic development. Two different approaches to the question of political stability and economic...development are presented. Each assumes that political stability is a necessary, though not sufficient, condition for economic development and that, therefore

  17. Spectral radiance source based on supercontinuum laser and wavelength tunable bandpass filter: the spectrally tunable absolute irradiance and radiance source.

    PubMed

    Levick, Andrew P; Greenwell, Claire L; Ireland, Jane; Woolliams, Emma R; Goodman, Teresa M; Bialek, Agnieszka; Fox, Nigel P

    2014-06-01

    A new spectrally tunable source for calibration of radiometric detectors in radiance, irradiance, or power mode has been developed and characterized. It is termed the spectrally tunable absolute irradiance and radiance source (STAIRS). It consists of a supercontinuum laser, wavelength tunable bandpass filter, power stabilization feedback control scheme, and output coupling optics. It has the advantages of relative portability and a collimated beam (low étendue), and is an alternative to conventional sources such as tungsten lamps, blackbodies, or tunable lasers. The supercontinuum laser is a commercial Fianium SC400-6-02, which has a wavelength range between 400 and 2500 nm and a total power of 6 W. The wavelength tunable bandpass filter, a PhotonEtc laser line tunable filter (LLTF), is tunable between 400 and 1000 nm and has a bandwidth of 1 or 2 nm depending on the wavelength selected. The collimated laser beam from the LLTF filter is converted to an appropriate spatial and angular distribution for the application considered (i.e., for radiance, irradiance, or power mode calibration of a radiometric sensor) with the output coupling optics, for example, an integrating sphere, and the spectral radiance/irradiance/power of the source is measured using a calibration optical sensor. A power stabilization feedback control scheme has been incorporated that stabilizes the source to better than 0.01% for averaging times longer than 100 s. The out-of-band transmission of the LLTF filter is estimated to be < -65 dB (0.00003%), and is sufficiently low for many end-user applications, for example the spectral radiance calibration of earth observation imaging radiometers and the stray light characterization of array spectrometers (the end-user optical sensor). We have made initial measurements of two end-user instruments with the STAIRS source, an array spectrometer and ocean color radiometer.

  18. Cross Calibration of TOMS, SBUV/2 and SCIAMACHY Radiances from Ground Observations

    NASA Technical Reports Server (NTRS)

    Hilsenrath, Ernest; Bhartia, P. K.; Bojkov, B.; Kowaleski, M.; Labow, G.; Ahmad, Z.

    2002-01-01

    We have shown that validation of radiances is a very effective means for correcting absolute accuracy and long term drifts of backscatter type satellite measurements. This method by-passes the algorithms used for both satellite and ground based measurements which are normally used to validate and correct the satellite data. A new method for satellite validation is planned which will compliment measurements from the existing ground-based networks. This method will employ very accurate comparisons between ground based zenith sky radiances and satellite nadir radiances. These comparisons will rely heavily on the experience derived from the Shuttle SBUV (SSBUV) program which provided a reference standard of radiance measurements for SBUV/2, TOMS, and GOME. This new measurement program, called 'Skyrad', employs two well established capabilities at the Goddard Space Flight Center, 1) the SSBUV calibration facilities and 2) the radiative transfer codes used for the TOMS and SBUV/2 algorithms and their subsequent refinements. Radiative transfer calculations show that ground based zenith sky and satellite nadir backscatter ultraviolet comparisons can be made very accurately under certain viewing conditions. The Skyrad instruments (SSBUV, Brewer spectrophotometers, and possibly others) will be calibrated and maintained to a precision of a few tenths of a percent. Skyrad data will then enable long term calibration of upcoming satellite instruments such as QuickTOMS, SBUV/2s and SCIAMACHY with a high degree of precision. This technique can be further employed to monitor the performance of future instruments such as GOMEZ, OMI, and OMPS. Additional information is included in the original extended abstract.

  19. Measures and Relative Motions of Some Mostly F. G. W. Struve Doubles

    NASA Astrophysics Data System (ADS)

    Wiley, E. O.

    2012-04-01

    Measures of 59 pairs of double stars with long observational histories using "lucky imaging" techniques are reported. Relative motions of 59 pairs are investigated using histories of observation, scatter plots of relative motion, ordinary least-squares (OLS) and total proper motion analyses performed in "R," an open source programming language. A scatter plot of the coefficient of determinations derived from the OLS y|epoch and OLS x|epoch clearly separates common proper motion pairs from optical pairs and what are termed "long-period binary candidates." Differences in proper motion separate optical pairs from long-term binary candidates. An Appendix is provided that details how to use known rectilinear pairs as calibration pairs for the program REDUC.

  20. Microhotplate Temperature Sensor Calibration and BIST.

    PubMed

    Afridi, M; Montgomery, C; Cooper-Balis, E; Semancik, S; Kreider, K G; Geist, J

    2011-01-01

    In this paper we describe a novel long-term microhotplate temperature sensor calibration technique suitable for Built-In Self Test (BIST). The microhotplate thermal resistance (thermal efficiency) and the thermal voltage from an integrated platinum-rhodium thermocouple were calibrated against a freshly calibrated four-wire polysilicon microhotplate-heater temperature sensor (heater) that is not stable over long periods of time when exposed to higher temperatures. To stress the microhotplate, its temperature was raised to around 400 °C and held there for days. The heater was then recalibrated as a temperature sensor, and microhotplate temperature measurements were made based on the fresh calibration of the heater, the first calibration of the heater, the microhotplate thermal resistance, and the thermocouple voltage. This procedure was repeated 10 times over a period of 80 days. The results show that the heater calibration drifted substantially during the period of the test while the microhotplate thermal resistance and the thermocouple-voltage remained stable to within about plus or minus 1 °C over the same period. Therefore, the combination of a microhotplate heater-temperature sensor and either the microhotplate thermal resistance or an integrated thin film platinum-rhodium thermocouple can be used to provide a stable, calibrated, microhotplate-temperature sensor, and the combination of the three sensor is suitable for implementing BIST functionality. Alternatively, if a stable microhotplate-heater temperature sensor is available, such as a properly annealed platinum heater-temperature sensor, then the thermal resistance of the microhotplate and the electrical resistance of the platinum heater will be sufficient to implement BIST. It is also shown that aluminum- and polysilicon-based temperature sensors, which are not stable enough for measuring high microhotplate temperatures (>220 °C) without impractically frequent recalibration, can be used to measure the silicon substrate temperature if never exposed to temperatures above about 220 °C.

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