Tectonic evolution and provenance of the Santa Bárbara Group, Camaquã Mines region, Rio Grande do Sul, Brazil

NASA Astrophysics Data System (ADS)

Bicca, Marcos Müller; Chemale, Farid; Jelinek, Andrea Ritter; de Oliveira, Christie Helouise Engelmann; Guadagnin, Felipe; Armstrong, Richard

2013-12-01

Cu- and Pb-Zn-hosting sedimentary units of the upper part of the Camaquã Basin (Ediacaran-Lower Ordovician) in the Dom Feliciano Belt of southernmost Brazil were formed during the late stages of the West Gondwana amalgamation and were controlled by large left-handed strike-slip shear zones. Integration of structural geology, stratigraphy and thermochronology allow recognition of five structural events (D1, Ediacaran-Lower Cambrian, through D5, Cretaceous). D1 structures are related to a N30E-trending, sinistral strike-slip shear zone that controlled the deposition of the mineralized sedimentary unit and its overlying units, the Santa Barbara and Guaritas Groups, respectively, in a transtensional setting. Based on U-Pb in situ methods, it is possible (a) to establish a maximum depositional age of 566 ± 6.9 Ma for the basal section of the Santa Barbara Group and, therefore, a minimum age of ca. 566 Ma for D1, and (b) to recognize two main zircon populations, Neoproterozoic and Paleoproterozoic, with sources from the eastern and southern parts of the Dom Feliciano Belt and reworking of older units of the Camaquã Basin. The D2 structures are mainly N-trending shear zones that developed after the deposition of the Guaritas Group during the Cambrian. During the Phanerozoic (post-Cambrian), the recognized structures were connected to compressional and extensional events that affected West Gondwana and the South America Platform. Thermochronological fission track analyses on apatite revealed four main age populations. The first three are interpreted to have formed during tectonic processes at the Gondwana Margin, namely the Famatinian and Gondwanides orogenies, and can be related to the D3 and D4 tectonic events in the basin. The last age population formed from thermal heating by the Upper Cretaceous continental flood basalts, which are represented in the area by volcanic intrusions, that were related to the separation of Africa and South America.

Constraining the composition and geological history of the main types of terrains found in the equatorial belt of Titan

NASA Astrophysics Data System (ADS)

Brossier, J. F.; Rodriguez, S.; Cornet, T.; Maltagliati, L.; Lucas, A.; Le Mouélic, S.; Solomonidou, A.; Coustenis, A.; Hirtzig, M.; Jaumann, R.; Stephan, K.; Brown, R. H.

2017-09-01

Over these twelve past years, near-IR imaging data from the Visual and Infrared Mapping Spectrometer (VIMS) onboard Cassini gave significant hints on the spectroscopic and geological diversity of the terrains on Titan's surface. The composition of those terrains still remains unconfirmed yet. Nonetheless, by applying a newly updated radiative transfer model, we provide excellent constraints on the composition and structure for the main IR-units present in the equatorial regions (±40˚N/S). Indeed, by combining this method of correction with a spectral mixing model for water ice and tholins, we determine the main chemical species present within IR-units and relate them to the observed geomorphology. We therefore propose a scenario that could lead to the current distribution of the IR-units.

ALTERATIONS AND ADDITIONS TO THE GATE HOUSE, United Engineering Company ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

ALTERATIONS AND ADDITIONS TO THE GATE HOUSE, United Engineering Company Ltd., Alameda Shipyard. Plan, elevations, and details of expanded structure. No architect noted. Drawn by "J.B.H." (John Hudspeth?). Sheet 2 of 2. Plan no. 10,504. Scale 1/4 inch to the foot. November 28, 1942, last revised 5/5/45. pencil on vellum - United Engineering Company Shipyard, Gate House, 2900 Main Street, Alameda, Alameda County, CA

Stratigraphy and structure of coalbed methane reservoirs in the United States: an overview

USGS Publications Warehouse

Pashin, J.C.

1998-01-01

Stratigraphy and geologic structure determine the shape, continuity and permeability of coal and are therefore critical considerations for designing exploration and production strategies for coalbed methane. Coal in the United states is dominantly of Pennsylvanian, Cretaceous and Tertiary age, and to date, more than 90% of the coalbed methane produced is from Pennsylvanian and cretaceous strata of the Black Warrior and San Juan Basins. Investigations of these basins establish that sequence stratigraphy is a promising approach for regional characterization of coalbed methane reservoirs. Local stratigraphic variation within these strata is the product of sedimentologic and tectonic processes and is a consideration for selecting completion zones. Coalbed methane production in the United States is mainly from foreland and intermontane basins containing diverse compression and extensional structures. Balanced structural models can be used to construct and validate cross sections as well as to quantify layer-parallel strain and predict the distribution of fractures. Folds and faults influence gas and water production in diverse ways. However, interwell heterogeneity related to fractures and shear structures makes the performance of individual wells difficult to predict.Stratigraphy and geologic structure determine the shape, continuity and permeability of coal and are therefore critical considerations for designing exploration and production strategies for coalbed methane. Coal in the United States is dominantly of Pennsylvanian, Cretaceous and Tertiary age, and to date, more than 90% of the coalbed methane produced is from Pennsylvanian and Cretaceous strata of the Black Warrior and San Juan Basins. Investigations of these basins establish that sequence stratigraphy is a promising approach for regional characterization of coalbed methane reservoirs. Local stratigraphic variation within these strata is the product of sedimentologic and tectonic processes and is a consideration for selecting completion zones. Coalbed methane production in the United States is mainly from foreland and intermontane basins containing diverse compressional and extensional structures. Balanced structural models can be used to construct and validate cross sections as well as to quantify layer-parallel strain and predict the distribution of fractures. Folds and faults influence gas and water production in diverse ways. However, interwell heterogeneity related to fractures and shear structures makes the performance of individual wells difficult to predict.

CIU and Main Event Analyses of the Structured Discourse of Older and Younger Adults

ERIC Educational Resources Information Center

Capilouto, Gilson; Wright, Heather Harris; Wagovich, Stacy A.

2005-01-01

Correct information unit (CIU) and main event analyses are quantitative measures for analyzing discourse of individuals with aphasia. Comparative data from healthy younger (YG) and older (OD) adults and an investigation of the influence of stimuli type would considerably extend the usefulness of such analyses. The objectives were (a) to compare…

Identification of areas of recharge and discharge using Landsat-TM satellite imagery and aerial photography mapping techniques

NASA Astrophysics Data System (ADS)

Salama, R. B.; Tapley, I.; Ishii, T.; Hawkes, G.

1994-10-01

Aerial photographs (AP) and Landsat (TM) colour composites were used to map the geomorphology, geology and structures of the Salt River System of Western Australia. Geomorphic features identified are sand plains, dissected etchplain, colluvium, lateritic duricrust and rock outcrops. The hydrogeomorphic units include streams, lakes and playas, palaeochannels and palaeodeltas. The structural features are linear and curvilinear lineaments, ring structures and dolerite dykes. Suture lines control the course of the main river channel. Permeable areas around the circular granitic plutons were found to be the main areas of recharge in the uplands. Recharge was also found to occur in the highly permeable areas of the sandplains. Discharge was shown to be primarily along the main drainage lines, on the edge of the circular sandplains, in depressions and in lakes. The groundwater occurrence and hydrogeological classification of the recharge potential of the different units were used to classify the mapped areas into recharge and discharge zones. The results also show that TM colour composites provide a viable source of data comparable with AP for mapping and delineating areas of recharge and discharge on a regional scale.

An active seismic experiment at Tenerife Island (Canary Island, Spain): Imaging an active volcano edifice

NASA Astrophysics Data System (ADS)

Garcia-Yeguas, A.; Ibañez, J. M.; Rietbrock, A.; Tom-Teidevs, G.

2008-12-01

An active seismic experiment to study the internal structure of Teide Volcano was carried out on Tenerife, a volcanic island in Spain's Canary Islands. The main objective of the TOM-TEIDEVS experiment is to obtain a 3-dimensional structural image of Teide Volcano using seismic tomography and seismic reflection/refraction imaging techniques. At present, knowledge of the deeper structure of Teide and Tenerife is very limited, with proposed structural models mainly based on sparse geophysical and geological data. This multinational experiment which involves institutes from Spain, Italy, the United Kingdom, Ireland, and Mexico will generate a unique high resolution structural image of the active volcano edifice and will further our understanding of volcanic processes.

Imaging an Active Volcano Edifice at Tenerife Island, Spain

NASA Astrophysics Data System (ADS)

Ibáñez, Jesús M.; Rietbrock, Andreas; García-Yeguas, Araceli

2008-08-01

An active seismic experiment to study the internal structure of Teide volcano is being carried out on Tenerife, a volcanic island in Spain's Canary Islands archipelago. The main objective of the Tomography at Teide Volcano Spain (TOM-TEIDEVS) experiment, begun in January 2007, is to obtain a three-dimensional (3-D) structural image of Teide volcano using seismic tomography and seismic reflection/refraction imaging techniques. At present, knowledge of the deeper structure of Teide and Tenerife is very limited, with proposed structural models based mainly on sparse geophysical and geological data. The multinational experiment-involving institutes from Spain, the United Kingdom, Italy, Ireland, and Mexico-will generate a unique high-resolution structural image of the active volcano edifice and will further our understanding of volcanic processes.

The anatomy of the Cycladic Blueschist Unit on Sifnos Island (Cyclades, Greece): implications for exhumation model of high-pressure rocks

NASA Astrophysics Data System (ADS)

Roche, Vincent; Laurent, Valentin; Jolivet, Laurent; Cardello, Giovanni Luca; Scaillet, Stéphane

2015-04-01

Key words.- Aegean sea, Cyclades, Sifnos, high pressure and low temperature metamorphism, syn-orogenic exhumation, post-orogenic extension, strain localization. Since 35 Ma, the kinematics of the Aegean domain has been mainly controlled by the southward retreat of the African slab, inducing backarc extension. The main structures and associated kinematic are well constrained, but the kinematics of deformation before 35 Ma, coeval with the exhumation of blueschists and eclogites of the Cycladic Blueschist Unit, has been so far poorly studied. Hence, syn-orogenic deformation and exhumation mechanisms of the Cycladic Blueschists Unit remain disputed in part because the structure and kinematic history of High Pressure and Low Temperature (HP-LT) rocks are interpreted differently in the literature. In order to understand and constrain the exhumation history of HP-LT rocks, Sifnos Island is particularly relevant because HP-LT parageneses are exceptionally well preserved and different degree of retrogression are observed in two main units. The aims of this work attempts at firstly solving uncertainties on the position and geometry of major contacts between units and, secondly, to provide new structural constraints on the tectonic history of HP-LT units generated in the subduction zone during the Eocene. We show, through new geological and metamorphic maps, cross-sections and analyses of kinematic indicators and their relation to metamorphism, that Sifnos is characterized by shallow-dipping shear zones reactivating weak zones due to competence contrasts or earlier tectonic contacts (i.e., syn-orogenic). Structures and kinematics, associated with these shear zones, show a top-to-the-N to -NE ductile shearing deformation. A continuum of deformation can be observed from the Eocene syn-orogenic blueschist-facies to the Oligocene-Miocene post-orogenic greenschist-facies with the same top-to-the-NE sense of shear showing that the same shear zones, formed during syn-orogenic exhumation were reactivated during the formation of the Aegean Sea. A progressive localization of strain along discrete shear zones toward the base of the tectonic pile is also observed. The present-day shape of the island is largely controlled by late brittle fault reshaping the older domal structure. These late low-angle and steeper normal faults with kinematic indicators top-to-the-SW cross-cut the ductile structure and may represent the brittle expression of the West Cycladic Detachment System. Hence, we propose a model of progressive exhumation also based on available radiochronological constraints, first in the subduction channel of the Hellenic subduction, then in the backarc region with the same top-to-the-NE non-coaxial component of shearing. This reconstruction partly explains the different degrees of retrogression observed on the Cycladic Islands. The main discontinuities allowing this exhumation are the Vari Detachment (cropping out on Tinos and Syros islands) during the syn-orogenic period (Eocene) and then the NCDS and WCDS afterward.

Quality Guidance: A Sectoral Analysis. NICEC Project Report.

ERIC Educational Resources Information Center

Watts, A. G.; Sadler, Jackie

This report reviews the structure of the guidance field and provides a sector-by-sector analysis of current quality assurance arrangements in the United Kingdom. Part 1 presents an outline of the guidance sector, including some key concepts, structures, and roles. It defines guidance and other terms; discusses the three main categories…

Morphological Structures in Visual Word Recognition: The Case of Arabic

ERIC Educational Resources Information Center

Abu-Rabia, Salim; Awwad, Jasmin (Shalhoub)

2004-01-01

This research examined the function within lexical access of the main morphemic units from which most Arabic words are assembled, namely roots and word patterns. The present study focused on the derivation of nouns, in particular, whether the lexical representation of Arabic words reflects their morphological structure and whether recognition of a…

Structure and Governance of Universities in France, the United States of America, and Mexico.

ERIC Educational Resources Information Center

Acostaromero, Salvador

This thesis reviews the main elements of university governance in France, the United States, and Mexico. A brief historical overview of higher education in the three countries precedes an individual analysis. The analysis of university governance in France focuses on the 1968 reform of higher education prompted by student protests and the 1983…

Soft-sediment deformation structures in the late Miocene Şelmo Formation around Adıyaman area, Southeastern Turkey

NASA Astrophysics Data System (ADS)

Koç Taşgın, Calibe; Orhan, Hükmü; Türkmen, İbrahim; Aksoy, Ercan

2011-04-01

The Şelmo Formation was deposited in the basins associated with the Southeastern Anatolian Thrust Belt and East Anatolian Fault Zone in SE Turkey. These structures developed as a result of compressional stresses created by the movement of the Arabian plate to the north and the Eurasian plate to the west from early Miocene to late Pliocene. The outcrops of the Şelmo Formation in the Adýyaman area (SE Turkey) comprise braided river deposits (lower alluvial unit) at the base, lacustrine and deltaic deposits in the middle (lacustrine unit) and low sinuousity river and alluvial deposits at the top (upper alluvial unit). Soft-sediment deformation structures were developed in sandstone, siltstone and marl of the deltaic and lacustrine unit of the Şelmo Formation. These are slumps, recumbent folds, load casts, ball-and-pillow structures, flame structures, neptunian dykes, chaotically associated structures and synsedimentary faults. The tectonic setting of the basin, the lateral extent of the soft-sediment deformation structures over tens of kilometers, their similarities to deformation structures interpreted as being induced seismically in other regions worldwide or in a laboratory setting, and being confined by undeformed layers suggest that the main trigger system was related to seismic activity in the area.

Depositional environments of some Pleistocene coastal terrace deposits, southwestern Oregon - case history of progradational beach and dune sequence.

USGS Publications Warehouse

Hunter, R.E.

1980-01-01

These deposits comprise a basal gravelly unit and 3 overlying sandy units, each with mud beds, a paleosol, or the modern soil in its uppermost part. The gravelly unit is interpreted as a progradational deposit. The main parts of the sandy units are made up of 1) a crossbedded sand facies, the dominant structure in which is medium-scale crossbedding (interpreted as the product of small eolian dunes), and 2) an irregularly bedded sand facies, which is locally pebbly and is dominated by scour-and-fill structures, interpreted as deposits of interdune ephemeral streams, ephemeral ponds, and wet to dry subaerial flats. The mud beds and paleosols represent times of temporary stabilization of the dune field.- from Author

Interactive Negotiation of Perspectives in Japanese: Predicate-Final Structure as a Resource to Organize Interaction

ERIC Educational Resources Information Center

Nakamura, Kanae

2009-01-01

While the predicate-final structure of the Japanese language has been considered one of the main causes of its late projectability (Tanaka, 1999), this study demonstrates that the final predicate component of a "turn constructional unit" (TCU) furnishes a useful resource for conversational participants to negotiate various aspects of interaction.…

Methods of Enhancing the Operating Characteristics of Gas-Turbine Blades

NASA Astrophysics Data System (ADS)

Ospennikova, O. G.; Visik, E. M.; Gerasimov, V. V.; Kolyadov, E. V.

2017-12-01

This paper considers the main tendencies of development and ways of introduction of new technological solutions and alloys in the production of industrial gas-turbine unit (GTU) blades and presents a review of modern corrosion-resistant alloys, casting units for high-gradient directional solidification, and the techniques providing the preparation of a single-crystal structure in the blades of stationary turbine plants.

Landslide Hazard Map of The Upper Tiber River Basin, Central Italy

NASA Astrophysics Data System (ADS)

Cardinali, M.; Carrara, A.; Guzzetti, F.; Reichenbach, P.

For the Upper Tiber River basin, which extends over 4000 km2 in Central Italy, a landslide hazard map was derived from a statistical model based on a mix of morpho- logical, lithological, structural and land use data. All these data were obtained from the analysis of different sets of aerial photographs, ranging in scale from 1:33,000 to 1:13,000, systematic field surveys and bibliographical information. Rock types were grouped in 37 units on the basis of the hard vs. soft rock percentage, as as- certained from photo-geological interpretation and field surveys. During the photo- interpretation, the spatial relations between bedding plane attitude and slope aspect were also systematically determined. The landslide inventory map recognised 17,600 slope-failures that cover nearly 12.5% of the basin area. Landslides, which are mainly slide flow slide earth-flow and compound or complex movements, were classified and mapped as shallow or deep seated. A DTM, with a grid resolution of 25x25 m, was derived from digitised contour lines of base topographic maps, 1:25,000.in scale. The basin was then automatically partitioned into nearly 16,000 main slope-units through a specifically-designed software module that, starting from a high quality DTM gen- erates fully connected and complementary drainage and divide networks and a wide spectrum of morphometric parameters. Main slope-units were then subdivided accord- ing to the major rock types cropping out in the basin generating over 28,700 hydro- morphological-lithological terrain-units. Using the presence/absence of landslide in each terrain unit, as the grouping variable, a stepwise discriminant function was ap- plied to the terrain units. of the 50 variables entered into the discriminant function, 15 are lithological, 15 morphological, 11 express the structural setting or bedding plane attitude, 7 refer to land use and the last 2 reflect local climatic conditions. The model proved to be capable of correctly classifying as stable or unstable over 75% of the terrain units.

INMARSAT - The International Maritime Satellite Organization: Origins and structure

NASA Technical Reports Server (NTRS)

Doyle, S. E.

1977-01-01

The third session of the International Conference on the Establishment of an International Maritime Satellite System established the International Maritime Satellite Organization (INMARSAT) in 1976. Its main functions are to improve maritime communications via satellite, thereby facilitating more efficient emergency communications, ship management, and maritime public correspondence services. INMARSAT's aims are similar to those of the Intergovernmental Maritime Consultative Organization (IMCO), the main United Nations organization dealing with maritime affairs. The specific functions of INMARSAT have been established by an Intersessional Working Group (IWG) which met three times between general conference meetings. Initial investment shares for the creation of INMARSAT were shared by the United States (17%), the United Kingdom (12%), the U.S.S.R. (11%), Norway (9.50%), Japan (8.45%), Italy (4.37%), and France (3.50%).

Integration of potential-field and digital geologic data for two North American geoscience transects

USGS Publications Warehouse

Phillips, J.D.

1990-01-01

Two North American contributions to the Global Geoscience Transects Program, the Quebec-Maine-Gulf of Maine transect and the Great Lakes portion of the United States-Canadian Border transect, are among the first to produce digital geology in a form that can be combined with gridded gravity and aeromagnetic data. Maps of shaded relief and color-composite bandpass-filtered potential-field data combined with overlays of digitized geologic contacts and faults reveal significant new geologic information, including the relative thickness of plutons, the structure of poorly exposed or concealed magnetic units, and possible evidence for mineralized ground. -from Author

Elemental Analysis of Beryllium Samples Using a Microzond-EGP-10 Unit

NASA Astrophysics Data System (ADS)

Buzoverya, M. E.; Karpov, I. A.; Gorodnov, A. A.; Shishpor, I. V.; Kireycheva, V. I.

2017-12-01

Results concerning the structural and elemental analysis of beryllium samples obtained via different technologies using a Microzond-EGP-10 unit with the help of the PIXE and RBS methods are presented. As a result, the overall chemical composition and the nature of inclusions were determined. The mapping method made it possible to reveal the structural features of beryllium samples: to select the grains of the main substance having different size and chemical composition, to visualize the interfaces between the regions of different composition, and to describe the features of the distribution of impurities in the samples.

Assessment of nurses' work climate at Alexandria Main University Hospital.

PubMed

Emam, Sanaa Abdel-aziz; Nabawy, Zeinab Mohamed; Mohamed, Azzaa Hassan; Sbeira, Walaa Hashem

2005-01-01

Work climate is indicative of how well the organization is realizing its full potential. An accurate assessment of work climate can identify the unnecessary obstacles to nurses interfering with their best performance. The present study aims to assess nurses' work climate at Alexandria Main University Hospital. The study sample included all nurses (N=400) who were working in inpatient medical and surgical units at the Alexandria Main University Hospital who were available at the time of data collection. A structured questionnaire was developed to assess nurses' perceptions regarding the dimensions of work climate. Data was collected by individual interview using the structured questionnaire. Results indicated that the highest percentages of nurses in medical and surgical units perceived that their work climate is characterized by good way of performance management, feeling of responsibility, warmth and supportive relationships, quality of communication, morale, organizational clarity and feeling of identity and belongness to the hospital. Nurses perceived that they are lacking work climate conducive to conflict resolution, participation in decision making, opportunity for training and development, fair rewards and recognition, calculated risks, sufficient resources, effective leadership and teamwork. There were no significant difference between nurses perceptions in medical and surgical units regarding all dimensions of work climate. The highest percentage of nurses in all units were satisfied only with the feeling of responsibility, way of performance management, and quality of communication. Conflict and identity were perceived as the most important areas that need improvement in the hospital. Based on the results recommendations were given to enhance work climate through designing compensation and recognition systems, and negotiate their requirements and accomplishment based on established standards and outcomes measures. Also, encouragement of and planning for participative decision making, teamwork, in-service training program and open communication are recommended to be present in the work units.

Seismic Reflection Characteristic and Structure Unit Division of Nanwei Uplift in the Nansha Waters, South China Sea

NASA Astrophysics Data System (ADS)

Guo, L.; Zhan, W.; Yao, Y.

2016-12-01

Nanwei uplift is located in the continent-ocean transition zone at the southern margin of the South China Sea (SCS). It has the structural characteristics in typical passive margin models. Attributed to squeezing action, the anticline and faulted anticline structure were well developed since Oligocene. The development of organic reef and marine mudstone deposit indicated the drifting and subsidence stage. In this area, the structural evolution is not only related to the dynamic systems of rifting, basin spreading and expansion ending, but also to the collisions between different plates. Meanwhile, a large number of continental margin rifting basins with rich oil and gas resources developed in Nanwei uplift. It is meaningful to analyze the characteristics of seismic reflection waves. Also, two main structural unit were divided for studying the special structures and stratigraphic features in this paper. Two high-resolution single-channel seismic Line Nan-1 and Line Nan-2 in the Nansha Waters, acquired by the trial vessel "Shiyan 2" of the South China Sea Institute of Oceanology in 2013, is interpreted and analyzed in this study. The profiles show that there are a lot of normal fault half-garben systems and depressions in NE direction. Five seismic interfaces have been distinguished, named T0,T3,T4,T5 and Tg respectively. It corresponds to different regional unconformities in different geological age which indicated the characteristics of regional tectonics. On the basis of tectonic shape and previous geophysical data, it is believed that the Nanwei uplift zone is mainly composed of two structural units, the southern subsidence belt and northern buried volcanic uplift belt. The general range of zoning is also discussed in this paper. It is considered that the buried volcanic uplift belt mainly involved the marginal area along the southern ocean basin from 63-72 km wide in SE direction, the neighboring subsidence belt in rifting stage is parallel to the buried volcanic uplift belt with 57.5-128 km wide. In addition, the epicenter distributions of sporadic and larger than 4 magnitude earthquakes suggest that the entire Nanwei uplift is still a relatively stable tectonic activity zone, the crustal stability is good.

Crystallographic features of the approximant H (Mn7Si2V) phase in the Mn-Si-V alloy system

NASA Astrophysics Data System (ADS)

Nakayama, Kei; Komatsuzaki, Takumi; Koyama, Yasumasa

2018-07-01

The intermetallic compound H (Mn7Si2V) phase in the Mn-Si-V alloy system can be regarded as an approximant phase of the dodecagonal quasicrystal as one of the two-dimensional quasicrystals. To understand the features of the approximant H phase, in this study, the crystallographic features of both the H phase and the (σ → H) reaction in Mn-Si-V alloy samples were investigated, mainly by transmission electron microscopy. It was found that, in the H phase, there were characteristic structural disorders with respect to an array of a dodecagonal structural unit consisting of 19 dodecagonal atomic columns. Concretely, penetrated structural units consisting of two dodecagonal structural units were presumed to be typical of such disorders. An interesting feature of the (σ → H) reaction was that regions with a rectangular arrangement of penetrated structural units (RAPU) first appeared in the σ matrix as the initial state, and H regions were then nucleated in contact with RAPU regions. The subsequent conversion of RAPU regions into H regions eventually resulted in the formation of the approximant H state as the final state. Furthermore, atomic positions in both the H structure and the dodecagonal quasicrystal were examined using a simple plane-wave model with 12 plane waves.

[The cell theory. Progress in studies on cell-cell communications].

PubMed

Brodskiĭ, V Ia

2009-01-01

Current data confirm the fundamental statement of the cell theory concerning the cell reproduction in a series of generations (omnis cellula e cellula). Cell communities or ensembles integrated by the signaling systems established in prokaryotes and protists and functioning in multicellular organisms including mammals are considered as the structural and functional unit of a multicellular organism. The cell is an elementary unit of life and basis of organism development and functioning. At the same time, the adult organism is not just a totality of cells. Multinucleated cells in some tissues, syncytial structure, and structural-functional units of organs are adaptations for optimal functioning of the multicellular organism and manifestations of cell-cell communications in development and definitive functioning. The cell theory was supplemented and developed by studies on cell-cell communications; however, these studies do not question the main generalizations of the theory.

Structural investigation of MO ṡ P2O5ṡ Li2O (MO = Fe2O3 or V2O5) glass systems by FTIR spectroscopy

NASA Astrophysics Data System (ADS)

Andronache, Constantin I.; Racolta, Dania

2014-11-01

Glasses from the systems xMO ṡ(100-x )[ P2O5ṡ Li2O ] (MO = Fe2O3 or V2O5) with 0 ≤ x ≤ mol % were prepared in the same conditions and characterized by IR spectroscopy. It was established the mode in which both Fe2O3 and V2O5 influences the local structure of these glasses. The iron ions generally modify in a different way the local structure of these glasses then vanadium ions. The results shown that phosphate units are the main structural units of glass system and the iron and vanadium ions are located in the network.

Structural characterization of tellurite glasses doped with transition metal oxides using Raman spectra and ab initio calculations.

PubMed

Mohamed, Tarek A; Shaltout, I; Al Yahyaei, K M

2006-05-01

Systems of iron tellurite glasses were prepared by melt quenching with compositions of [85%TeO2+5%Fe2O3+10%TMO], where transition metal oxides (TMO) are TiO2, V2O5, MnO, CoO, NiO and CuO. Furthermore, the main structural units of these samples have been characterized by means of Raman spectra (150-1200 cm(-1)) as well as wavenumber predictions by means of Gaussian 98 ab initio calculations for the proposed site symmetries of TeO4(4-) triagonal bipyramid (C2v) and Te2O7(6-) bridged tetrahedra (Cs and C1). Aided by normal coordinate analysis, calculated vibrational frequencies, Raman scattering activities, force constants in internal coordinates and potential energy distributions (PEDs), revised vibrational assignments for the fundamental modes have been proposed. The main structural features are correlated to the dominant units of triagonal bipyramid (tbp) or bridged tetrahedral (TeO3+1 binds to TeO3 through TeOTe bridge; corner sharing). Moreover, the Raman spectra of the investigated tellurites reflect a structural change from tbp (coordination number is four) to triagonal pyramidal (coordination number is three).

Soil and Living Things. Seychelles Integrated Science. [Teacher and Pupil Booklets]. Unit 4.

ERIC Educational Resources Information Center

Brophy, M.; Fryars, M.

Seychelles Integrated Science (SIS), a 3-year laboratory-based science program for students (ages 11-15) in upper primary grades 7, 8, and 9, was developed from an extensive evaluation and modification of previous P7-P9 materials. This P7 SIS unit focuses on: (1) the structure of the two main soil types in Seychelles; (2) the role of roots in…

Structural control on geothermal circulation in the Tocomar geothermal volcanic area (Puna plateau, Argentina)

NASA Astrophysics Data System (ADS)

Giordano, Guido

2016-04-01

The reconstruction of the stratigraphical-structural framework and the hydrogeology of geothermal areas is fundamental for understanding the relationships between cap rocks, reservoir and circulation of geothermal fluids and for planning the exploitation of the field. The Tocomar geothermal volcanic area (Puna plateau, Central Andes, NW Argentina) has a high geothermal potential. It is crossed by the active NW-SE trans-Andean tectonic lineament known as the Calama-Olacapato-Toro (COT) fault system, which favours a high secondary permeability testified by the presence of numerous thermal springs. This study presents new stratigraphic, structural, volcanological, geochemical and hydrogeological data on the geothermal field. Our data suggest that the main geothermal reservoir is located within or below the Pre-Palaeozoic-Ordovician basement units, characterised by unevenly distributed secondary permeability. The reservoir is recharged by infiltration in the ridges above 4500 m a.s.l., where basement rocks are in outcrop. Below 4500 m a.s.l., the reservoir is covered by the low permeable Miocene-Quaternary units that allow a poor circulation of shallow groundwater. Geothermal fluids upwell in areas with more intense fracturing, especially where main regional structures, particularly NW-SE COT-parallel lineaments, intersect with secondary structures, such as at the Tocomar field.

Geology and habitat of oil in Ras Budran field, Gulf of Suez, Egypt

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chowdhary, L.R.; Taha, S.

1987-10-01

The Ras Budran structure at the deepest mappable seismic reflector, the top of the Kareem Formation (middle Miocene), is a broad northeast-southwest-trending anticlinal feature with an anomalous strike nearly at right angles to the main Gulf of Suez trend. Oil is produced from three units of Nubian Formation sandstone from a depth of 11,000-12,000 ft (3352-3657 m). The lower unit of Paleozoic age averages 10% porosity and has up to 200 md in-situ permeability. Wells completed in this unit produce up to 2000 BOPD. In contrast, the sands to the upper two units of the Early Cretaceous have 15-20% porositymore » and up to 700 md permeability. Wells completed in this unit produce 6000-8000 BOPD. The Ras Budran structure was formed primarily during an intra-Rudeis tectonic phase (lower Miocene). Oil migration for accumulation in the structure started in the late Miocene or Pliocene when the Santonian Brown Limestone and the Eocene Thebes Formation, the main source beds in the Gulf of Suez, reached the threshold of oil generation at a burial depth of approximately 10,000 ft (3048 m). At this depth, the organic matter in the source beds had a high transformation ratio (0.10 to 0.15), high yields of C/sub 15+/ soluble organic matter and C/sub 15+/ saturated hydrocarbons, vitrinite reflectance (R/sub 0/) of 0.62%, and a time-temperature index (TTI) value of 15. Oil migration from mature source beds in adjoining lows into low-potential Nubian reservoirs is easily explained by fault planes that acted as conduits for oil migration. 16 figures, 3 tables.« less

Vertical displacements inherited from pre-Neogene time in the Gulfes of Sigacik and Kusadasi (Western Anatolia) by multi channel seismic and chirp data

NASA Astrophysics Data System (ADS)

Gurcay, S.; Cifci, G.; Dondurur, D.; Sozbilir, H.

2012-12-01

Gulfes of Sigacik and Kusadasi (Western Anatolia) are located south of the Middle Eastern Aegean depression which formed by vertical displacements along the NB- to N-trending structural planes. This study consists of the results of the multi-channel seismic reflection and chirp data acquisition by K. Piri Reis, research vessel of Dokuz Eylül University (Izmir-TURKEY), in Sigacik Gulf and Kusadasi Gulf (West Anatolia) in August-2005 and in March-2008. Data were acquired approximately along the 1300km seismic lines. Two main seismic units, lower unit (Pre-Neogene) and upper unit (Neogene), can easily be determined on multi channel seismic sections. It is also observed on seismic sections that there are many active faults deform these units. Two main submarine basins can be determined from multi-channel seismic sections, Sigacik Basin and Kusadasi Basin. The upper unit in Sigacik Basin is deformed generally by strike slip faults. But there are some faults that have sharp vertical movements on lower unit. Some of these vertical movements are followed by strike-slip active faults along the upper unit indicating that these normal movements have changed to lateral movements, recently.

Structures, microfabrics and textures of the Cordilleran-type Rechnitz metamorphic core complex, Eastern Alps☆

PubMed Central

Cao, Shuyun; Neubauer, Franz; Bernroider, Manfred; Liu, Junlai; Genser, Johann

2013-01-01

Rechnitz window group represents a Cordilleran-style metamorphic core complex, which is almost entirely located within nearly contemporaneous Neogene sediments at the transition zone between the Eastern Alps and the Neogene Pannonian basin. Two tectonic units are distinguished within the Rechnitz metamorphic core complex (RMCC): (1) a lower unit mainly composed of Mesozoic metasediments, and (2) an upper unit mainly composed of ophiolite remnants. Both units are metamorphosed within greenschist facies conditions during earliest Miocene followed by exhumation and cooling. The internal structure of the RMCC is characterized by the following succession of structure-forming events: (1) blueschist relics of Paleocene/Eocene age formed as a result of subduction (D1), (2) ductile nappe stacking (D2) of an ophiolite nappe over a distant passive margin succession (ca. E–W to WNW–ESE oriented stretching lineation), (3) greenschist facies-grade metamorphism annealing dominant in the lower unit, and (4) ductile low-angle normal faulting (D3) (with mainly NE–SW oriented stretching lineation), and (5) ca. E to NE-vergent folding (D4). The microfabrics are related to mostly ductile nappe stacking to ductile low-angle normal faulting. Paleopiezometry in conjunction with P–T estimates yield high strain rates of 10− 11 to 10− 13 s− 1, depending on the temperature (400–350 °C) and choice of piezometer and flow law calibration. Progressive microstructures and texture analysis indicate an overprint of the high-temperature fabrics (D2) by the low-temperature deformation (D3). Phengitic mica from the Paleocene/Eocene high-pressure metamorphism remained stable during D2 ductile deformation as well as preserved within late stages of final sub-greenschist facies shearing. Chlorite geothermometry yields two temperature groups, 376–328 °C, and 306–132 °C. Chlorite is seemingly accessible to late-stage resetting. The RMCC underwent an earlier large-scale coaxial deformation accommodated by a late non-coaxial shear with ductile low-angle normal faulting, resulting in subvertical thinning in the extensional deformation regime. The RMCC was rapidly exhumed during ca. 23–18 Ma. PMID:27065502

Quality in the Professions.

ERIC Educational Resources Information Center

Becher, Tony

1999-01-01

Reviews quality assurance and quality control procedures of the main requirements affecting United Kingdom medicine, pharmacy, law, accountancy, architecture, and structural engineering. Provides a taxonomy of different forms of quality maintenance and offers comparative material which may be of interest and relevance to academic readers. (EV)

Charge delocalization characteristics of regioregular high mobility polymers

DOE PAGES

Coughlin, J. E.; Zhugayevych, A.; Wang, M.; ...

2017-01-01

Controlling the regioregularity among the structural units of narrow bandgap conjugated polymer backbones has led to improvements in optoelectronic properties, for example in the mobilities observed in field effect transistor devices. To investigate how the regioregularity affects quantities relevant to hole transport, regioregular and regiorandom oligomers representative of polymeric structures were studied using density functional theory. Several structural and electronic characteristics of the oligomers were compared, including chain planarity, cation spin density, excess charges on molecular units and internal reorganizational energy. The main difference between the regioregular and regiorandom oligomers is found to be the conjugated backbone planarity, while themore » reorganizational energies calculated are quite similar across the molecular family. Lastly, this work constitutes the first step on understanding the complex interplay of atomistic changes and an oligomer backbone structure toward modeling the charge transport properties.« less

Modélisation magnétotellurique de la structure géologique profonde de l’unité granulitique de l’In Ouzzal (Hoggar occidental)

NASA Astrophysics Data System (ADS)

Bouzid, Abderrezak; Akacem, Nouredine; Hamoudi, Mohamed; Ouzegane, Khadidja; Abtout, Abdeslam; Kienast, Jean-Robert

2008-11-01

Magnetotelluric modeling of the deep geologic structure of In Ouzzal Granulitic Unit (western Hoggar). The In Ouzzal Granulitic Unit (IOGU) or In Ouzzal Terrane (IOT) is an Archaean block belonging to the Hoggar terrane mosaic. It has been reworked during the Eburnean and is characterized by ultrahigh temperature metamorphism of the structures, which are likely to be old dome and basin structures. The aim of this study, based on a survey of 12 magnetotelluric (MT) soundings, was to characterize the IOGU deep lateral boundaries and to see if it is possible to reconstruct some of these old dome and basin structures after their transformation by metamorphism and deformation. MT data analysis and modeling show that IOGU boundaries extend downwards, at least down to the crust's basement, and may represent suture zones. Inside the terrane, the MT observations do not allow separation between dome and basin structures, because these features are severely stretched. However, the main MT transverse response feature is a deeply rooted great accident, which may be interpreted as a major fault that separates IOGU into two compartments.

A Helical Structural Nucleus Is the Primary Elongating Unit of Insulin Amyloid Fibrils

PubMed Central

Roessle, Manfred; Kastrup, Jette S; van de Weert, Marco; Flink, James M; Frokjaer, Sven; Gajhede, Michael; Svergun, Dmitri I

2007-01-01

Although amyloid fibrillation is generally believed to be a nucleation-dependent process, the nuclei are largely structurally uncharacterized. This is in part due to the inherent experimental challenge associated with structural descriptions of individual components in a dynamic multi-component equilibrium. There are indications that oligomeric aggregated precursors of fibrillation, and not mature fibrils, are the main cause of cytotoxicity in amyloid disease. This further emphasizes the importance of characterizing early fibrillation events. Here we present a kinetic x-ray solution scattering study of insulin fibrillation, revealing three major components: insulin monomers, mature fibrils, and an oligomeric species. Low-resolution three-dimensional structures are determined for the fibril repeating unit and for the oligomer, the latter being a helical unit composed of five to six insulin monomers. This helical oligomer is likely to be a structural nucleus, which accumulates above the supercritical concentration used in our experiments. The growth rate of the fibrils is proportional to the amount of the helical oligomer present in solution, suggesting that these oligomers elongate the fibrils. Hence, the structural nucleus and elongating unit in insulin amyloid fibrillation may be the same structural component above supercritical concentrations. A novel elongation pathway of insulin amyloid fibrils is proposed, based on the shape and size of the fibrillation precursor. The distinct helical oligomer described in this study defines a conceptually new basis of structure-based drug design against amyloid diseases. PMID:17472440

Reactivity ratios and sequence structures of the copolymers prepared using photo-induced copolymerization of MMA with MTMP.

PubMed

Liu, Xiaoxuan; Zhang, Yongtao; Cui, Yanyan; Dong, Zhixian

2012-05-01

4-Methacryloyl-2,2,6,6-tetramethyl-piperidine (MTMP) was applied as reactive hindered amine piperidine. Photo-induced copolymerization of methyl methacrylate (MMA, M(1)) with MTMP (M(2)) was carried out in benzene solution at ambient temperature. The reactivity ratios for these monomers were measured by running a series of reactions at various feed ratios of initial monomers, and the monomer incorporation into copolymer was determined using (1)H NMR. Reactivity ratios of the MMA/MTMP system were measured to be r(1)= 0.37 and r(2)= 1.14 from extended Kelen-Tüdos method. The results show that monomer MTMP prefers homopolymerization to copolymerization in the system, whereas monomer MMA prefers copolymerization to homopolymerization. Sequence structures of the MMA/MTMP copolymers were characterized using (1)H NMR. The results show that the sequence structure for the main chain of the MMA/MTMP copolymers is mainly composed of a syndiotactic configuration, only with a little heterotactic configuration. Three kinds of the sequences of rr, rr', and lr' in the syndiotactic configuration are found. The sequence-length distribution in the MMA/MTMP copolymers is also obtained. For f(1)= 0.2, the monomer unit of MMA is mostly separated by MTMP units, and for f(1)= 0.6, the alternating tendency prevails and a large number of mono-sequences are formed; further up to f(1)= 0.8, the monomer unit of MTMP with the sequence of one unit is interspersed among the chain of MMA. Copyright © 2012 John Wiley & Sons, Ltd.

Implementation of magnetic, gravity and resistivity data in identifying groundwater occurrences in El Qaa Plain area, Southern Sinai, Egypt

NASA Astrophysics Data System (ADS)

Selim, El Sayed; Abdel-Raouf, Osama; Mesalam, Mohamed

2016-10-01

El Qaa plain is one of the areas that have been proved to be promising as to its soil and groundwater resources in the southwestern part of Sinai. This study was carried out to study the lateral and vertical variations in the subsurface lithologic properties in El Qaa plain area and delineating the subsurface structure that affecting El Qaa plain depression. Gravity, magnetic data, fifty-one (51) vertical electrical sounding (Ves's) and Digital Elevation Model (DEM) map were used. Two-dimensional density modeling, analytical signal, tilt derivatives, Euler deconvolution techniques and interpretation of the resistivity data were applied on potential data. This study concluded that, El Qaa plain is a NE-SW depression confined by two normal faults and subdivided into five sedimentary units. Rock fragments and boulders derived to the plain from the surrounding highlands are the main components of the first surface unit that characterized by high resistivity values. This layer is overly another unit composed of gravelly sand with thickness ranging between 10 and 140 m. The third unit is composed mainly of sand with intercalations of clay with thickness ranging from 2 to 152 m. A Reefal limestone unit is a fourth unit interpreted from this study. The fifth unit is composed of clay. The water bearing formations in El Qaa Plain area are located principally in the second and the third layers. Finally, the depth to the basement surface ranges from 400 m to more than 1.5 km below sea level. Also, there are many minor structural trends interpreted from this study and affecting the El Qaa plain are striking in N-S, E-W and NE-SW directions.

The analysis of parameters of the cryogenic oxygen unit cooperating with power plant to realize oxy-fuel combustion

NASA Astrophysics Data System (ADS)

Hnydiuk-Stefan, Anna; Składzień, Jan

2015-03-01

The paper examines from the thermodynamic point of view operation of coal fired power unit cooperating with the cryogenic oxygen unit, with a particular emphasis on the characteristic performance parameters of the oxygen unit. The relatively high purity technical oxygen produced in the oxygen unit is then used as the oxidant in the fluidized bed boiler of the modern coal fired power unit with electric power output of approximately 460 MW. The analyzed oxygen unit has a classical two-column structure with an expansion turbine (turboexpander), which allows the use of relatively low pressure initially compressed air. Multivariant calculations were performed, the main result being the loss of power and efficiency of the unit due to the need to ensure adequate driving power to the compressor system of the oxygen generating plant.

Effects of Caledonian tectonism in Arctic Canada

NASA Astrophysics Data System (ADS)

Miall, Andrew D.

1986-11-01

Several north-trending structures in the Canadian Arctic islands are interpreted as Caledonian in origin, in the sense that they probably represent intraplate tectonism triggered by the closing of the Iapetus Ocean along the Greenland-Scandinavia-Svalbard Caledonian suture. These structures include the Boothia uplift, Rens Fiord uplift, Inglefield uplift (redefined unit, replacing Bache Peninsula arch), and possibly several other structures, such as the Cornwall arch, which are now expressed mainly in Mesozoic-Cenozoic strata but may represent rejuvenated Caledonian lineaments.

Fluorinated arene, imide and unsaturated pyrrolidinone based donor acceptor conjugated polymers: Synthesis, structure-property and device studies

NASA Astrophysics Data System (ADS)

Liyanage, Arawwawala Don Thilanga

After the discovery of doped polyacetylene, organic semiconductor materials are widely studied as high impending active components in consumer electronics. They have received substantial consideration due to their potential for structural tailoring, low cost, large area and mechanically flexible alternatives to common inorganic semiconductors. To acquire maximum use of these materials, it is essential to get a strong idea about their chemical and physical nature. Material chemist has an enormous role to play in this novel area, including development of efficient synthetic methodologies and control the molecular self-assembly and (opto)-electronic properties. The body of this thesis mainly focuses on the substituent effects: how different substituents affect the (opto)-electronic properties of the donor-acceptor (D-A) conjugated polymers. The main priority goes to understand, how different alkyl substituent effect to the polymer solubility, crystallinity, thermal properties (e.g.: glass transition temperature) and morphological order. Three classes of D-A systems were extensively studied in this work. The second chapter mainly focuses on the synthesis and structure-property study of fluorinated arene (TFB) base polymers. Here we used commercially available 1,4-dibromo-2,3,5,6-tetrafluorobenzene (TFB) as the acceptor material and prepare several polymers using 3,3'-dialkyl(3,3'-R2T2) or 3,3'-dialkoxy bithiophene (3,3'-RO2T2) units as electron donors. A detail study was done using 3,3'-bithiophene donor units incorporating branched alkoxy-functionalities by systematic variation of branching position and chain length. The study allowed disentangling the branching effects on (i) aggregation tendency, intermolecular arrangement, (iii) solid state optical energy gaps, and (iv) electronic properties in an overall consistent picture, which might guide future polymer synthesis towards optimized materials for opto-electronic applications. The third chapter mainly focused on the structure-property study of imide functionalized D-A polymers. Here we used thiophene-imide (TPD) as the acceptor moiety and prepare several D-A polymers by varying the donor units. When selecting the donor units, more priority goes to the fused ring systems. One main reason to use imide functionality is due to the, open position of the imide nitrogen, which provides an attaching position to alkyl substituent. Through this we can easily manipulate solubility and solid state packing arrangement. Also these imide acceptors have low-lying LUMOs due to their electron deficient nature and this will allow tuning the optical energy gap by careful choice of donor materials with different electron donating ability. The fourth chapter mainly contribute to the synthesis and structure property study of a completely novel electron acceptor moiety consist of a unsaturated pyrrolidinone unit known as Pechmann dye (PD) core. Pechmann dyes are closely related to the Indigo family. This can refer as 3-butenolide dimer connected via an alkene bridge, containing a benzene ring at the 5 and 5' positions of the lactone rings. We have prepared several D-A polymers using this PD system with benzodithiophene (BDT) as the donor unit. Different to common D-A polymers the HOMO and LUMO of the PD acceptor moiety are energetically located within the gap of the BDT, so that the electronic and optical properties (HOMO-LUMO transition) are dictated by the PD properties. The promising electronic properties, band gaps, high absorption coefficients and broad absorption suggest this new D-A polymers as an interesting donor material for organic solar cell (OSC) applications. KEY WORDS: Organic semiconductor materials, Self assembly, (opto)-electronic properties, Donor-Acceptor conjugated polymers, Fluorinated arene, 3,3'-bithiophene donors, Thiophene-imide (TPD), Pechmann dye, benzodithiophene, organic solar cell.

Detection of sedimentary structural elements using formation micro imager technique, a case study from South Mansoura-1 well, Nile Delta, Egypt

NASA Astrophysics Data System (ADS)

Abd El-Wahed, Ahmed G.; Anan, Tarek I.

2016-12-01

A detailed structure and sedimentology interpretation was performed for the South Mansoura-1 well. The Formation Micro Imager (FMI) is recorded and interpreted over the interval 9100-8009 ft. This interval belongs to Sidi Salem and Qawasim Formations. Based on azimuth trend of manually picked dips (bed boundaries), the interval can be divided into 4 structural dip zones (Zone 1 (9100-8800 ft), variable azimuth direction with the major trends mainly to SW≠ Zone 2 (8800-8570 ft), bedding dip azimuth is mainly to the NW; Zone 3 (8570-8250 ft), bedding dip azimuth is mainly to the NE; and Zone 4 (8250-8009 ft), bedding dip azimuth is mainly to the NW). Lamination identified over the interval shows a dominant dip azimuth trend toward North North-West direction. The interbedded shale units are highly laminated and show little evidence of bioturbation. Sand exhibits abundant cross bedding showing a dominant dip azimuth trends toward NNE and NE and more locally to the E. Sixteen truncations identified over the interval show variable azimuth trend with the major trend mainly to the North North-West.

Structural control on geothermal circulation in the Cerro Tuzgle-Tocomar geothermal volcanic area (Puna plateau, Argentina)

NASA Astrophysics Data System (ADS)

Giordano, Guido; Pinton, Annamaria; Cianfarra, Paola; Baez, Walter; Chiodi, Agostina; Viramonte, José; Norini, Gianluca; Groppelli, Gianluca

2013-01-01

The reconstruction of the stratigraphical-structural framework and the hydrogeology of geothermal areas is fundamental for understanding the relationships between cap rocks, reservoir and circulation of geothermal fluids and for planning the exploitation of the field. The Cerro Tuzgle-Tocomar geothermal volcanic area (Puna plateau, Central Andes, NW Argentina) has a high geothermal potential. It is crossed by the active NW-SE trans-Andean tectonic lineament known as the Calama-Olacapato-Toro (COT) fault system, which favours a high secondary permeability testified by the presence of numerous springs. This study presents new stratigraphic and hydrogeological data on the geothermal field, together with the analysis from remote sensed image analysis of morphostructural evidences associated with the structural framework and active tectonics. Our data suggest that the main geothermal reservoir is located within or below the Pre-Palaeozoic-Ordovician basement units, characterised by unevenly distributed secondary permeability. The reservoir is recharged by infiltration in the ridges above 4500 m a.s.l., where basement rocks are in outcrop. Below 4500 m a.s.l., the reservoir is covered by the low permeable Miocene-Quaternary units that allow a poor circulation of shallow groundwater. Geothermal fluids upwell in areas with more intense fracturing, especially where main regional structures, particularly NW-SE COT-parallel lineaments, intersect with secondary structures, such as at the Tocomar field. Away from the main tectonic features, such as at the Cerro Tuzgle field, the less developed network of faults and fractures allows only a moderate upwelling of geothermal fluids and a mixing between hot and shallow cold waters. The integration of field-based and remote-sensing analyses at the Cerro Tuzgle-Tocomar area proved to be effective in approaching the prospection of remote geothermal fields, and in defining the conceptual model for geothermal circulation.

Structural characterization of lignin isolated from coconut (Cocos nucifera) coir fibers.

PubMed

Rencoret, Jorge; Ralph, John; Marques, Gisela; Gutiérrez, Ana; Martínez, Ángel T; del Río, José C

2013-03-13

The structure of the isolated milled "wood" lignin from coconut coir has been characterized using different analytical methods, including Py-GC/MS, 2D NMR, DFRC, and thioacidolysis. The analyses demonstrated that it is a p-hydroxyphenyl-guaiacyl-syringyl (H-G-S) lignin, with a predominance of G units (S/G ratio 0.23) and considerable amounts of associated p-hydroxybenzoates. Two-dimensional NMR indicated that the main substructures present in this lignin include β-O-4' alkyl aryl ethers followed by phenylcoumarans and resinols. Two-dimensional NMR spectra also indicated that coir lignin is partially acylated at the γ-carbon of the side chain with p-hydroxybenzoates and acetates. DFRC analysis showed that acetates preferentially acylate the γ-OH in S rather than in G units. Despite coir lignin's being highly enriched in G-units, thioacidolysis indicated that β-β' resinol structures are mostly derived from sinapyl alcohol. Finally, we find evidence that the flavone tricin is incorporated into the coconut coir lignin, as has been recently noted for various grasses.

An investigation of collisions between fiber positioning units in LAMOST

NASA Astrophysics Data System (ADS)

Liu, Xiao-Jie; Wang, Gang

2016-04-01

The arrangement of fiber positioning units in the LAMOST focal plane may lead to collisions during the fiber allocation process. To avoid these collisions, a software-based protection system has to abandon some targets located in the overlapping field of adjacent fiber units. In this paper, we first analyze the probability of collisions between fibers and infer their possible reasons. It is useful to solve the problem of collisions among fiber positioning units so as to improve the efficiency of LAMOST. Based on this, a collision handling system is designed by using a master-slave control structure between the micro control unit and microcomputer. Simulated experiments validate that the system can provide real-time inspection and swap information between the fiber unit controllers and the main controller.

Action of an endo-β-1,3(4)-glucanase on cellobiosyl unit structure in barley β-1,3:1,4-glucan

PubMed Central

Kuge, Takao; Nagoya, Hiroki; Tryfona, Theodora; Kurokawa, Tsunemi; Yoshimi, Yoshihisa; Dohmae, Naoshi; Tsubaki, Kazufumi; Dupree, Paul; Tsumuraya, Yoichi; Kotake, Toshihisa

2015-01-01

β-1,3:1,4-Glucan is a major cell wall component accumulating in endosperm and young tissues in grasses. The mixed linkage glucan is a linear polysaccharide mainly consisting of cellotriosyl and cellotetraosyl units linked through single β-1,3-glucosidic linkages, but it also contains minor structures such as cellobiosyl units. In this study, we examined the action of an endo-β-1,3(4)-glucanase from Trichoderma sp. on a minor structure in barley β-1,3:1,4-glucan. To find the minor structure on which the endo-β-1,3(4)-glucanase acts, we prepared oligosaccharides from barley β-1,3:1,4-glucan by endo-β-1,4-glucanase digestion followed by purification by gel permeation and paper chromatography. The endo-β-1,3(4)-glucanase appeared to hydrolyze an oligosaccharide with degree of polymerization 5, designated C5-b. Based on matrix-assisted laser desorption/ionization (MALDI) time-of-flight (ToF)/ToF-mass spectrometry (MS)/MS analysis, C5-b was identified as β-Glc-1,3-β-Glc-1,4-β-Glc-1,3-β-Glc-1,4-Glc including a cellobiosyl unit. The results indicate that a type of endo-β-1,3(4)-glucanase acts on the cellobiosyl units of barley β-1,3:1,4-glucan in an endo-manner. PMID:26027730

Geoenvironmental impacts of using high carbon fly ash in structural fill applications : [research summary].

DOT National Transportation Integrated Search

2013-03-01

Coal power plants generate approximately 50% of the electricity in the : United States. As a result, large amounts of coal combustion byproducts, : especially fly ash, are produced annually. Only 40% of the fly ash : (mainly C and F-type classificati...

Role of thermal history in atomic dynamics of chalcogenide glass: A case study on Ge{sub 20}Te{sub 80} glass

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sharma, Yashika; Kalra, Geetanjali; Murugavel, Sevi, E-mail: murug@physics.du.ac.in

The non-existence of thermodynamic equilibrium in glasses, their thermal history plays a very crucial role in explaining the relaxation behavior in various time scales and its configurational states. More importantly, the associated relaxation behavior is related mainly to the structural phenomenon of the glasses. Here, we report the dependence of quenching rate on the variation of structural units. The local structures of these glasses are monitored by recording the Raman spectroscopy and related to the different configurational states. The observed variations in structural differences are reflected in the measured density of the corresponding glasses. The quenching rate dependent of themore » relative fractions of edge-shared and corner-shared GeTe{sub 4} tetrahedral units are shown to be consistent with the corresponding variations in the measured density values.« less

Structural investigation of MO⋅P{sub 2}O{sub 5}⋅Li{sub 2}O (MO = Fe{sub 2}O{sub 3} or V{sub 2}O{sub 5}) glass systems by FTIR spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andronache, Constantin I., E-mail: androtin03@yahoo.com; Racolta, Dania, E-mail: androtin03@yahoo.com

2014-11-24

Glasses from the systems xMO⋅(100−x)[P{sub 2}O{sub 5}⋅Li{sub 2}O] (MO = Fe{sub 2}O{sub 3} or V{sub 2}O{sub 5}) with 0 ≤ x ≤ mol % were prepared in the same conditions and characterized by IR spectroscopy. It was established the mode in which both Fe{sub 2}O{sub 3} and V{sub 2}O{sub 5} influences the local structure of these glasses. The iron ions generally modify in a different way the local structure of these glasses then vanadium ions. The results shown that phosphate units are the main structural units of glass system and the iron and vanadium ions are located in the network.

XRD and FTIR structural investigation of gadolinium-zinc-borate glass ceramics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Borodi, G.; Pascuta, P.; Dan, V.

2013-11-13

X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy measurements have been employed to investigate the (Gd{sub 2}O{sub 3}){sub x}⋅(B{sub 2}O{sub 3}){sub (60−x)}⋅(ZnO){sub 40} glass ceramics system, with 0 ≤ x ≤ 15 mol%. After heat treatment applied at 860 °C for 2 h, some structural changes were observed and new crystalline phases appeared in the structure of the samples. In these glass ceramics four crystalline phases were identified using powder diffraction files (PDF 2), namely ZnB{sub 4}O{sub 7}, Zn{sub 4}O(B{sub 6}O{sub 12}), Zn{sub 3}(BO{sub 3}){sub 2} and GdBO{sub 3}. From the XRD data, the average unit-cell parameter and themore » quantitative ratio of the crystallographic phases in the studied samples were evaluated. FTIR data revealed that the BO{sub 3}, BO{sub 4} and ZnO{sub 4} are the main structural units of these glass ceramics network. The compositional dependence of the different structural units which appear in the studied samples was followed.« less

Comparative analysis of a jack-up drilling unit with different leg systems

NASA Astrophysics Data System (ADS)

Ren, Xiangang; Bai, Yong; Jia, Lusheng

2012-09-01

The jack-up unit is one of the best drilling platforms in offshore oil fields with water depth shallower than 150 meters. As the most pivotal component of the jack-up unit, the leg system can directly affect the global performance of a jack-up unit. Investigation shows that there are three kinds of leg structure forms in the world now: the reverse K, X, and mixing types. In order to clarify the advantage and defects of each one, as well as their effect on the global performance of the jack-up unit, this paper commenced to study performance targets of a deepwater jack-up unit with different leg systems (X type, reverse K type, and mixing type). In this paper a typical leg scantling dimension and identical external loads were selected, detailed finite element snalysis (FEA) models were built to simulate the jack-up unit's structural behavior, and the multi-point constraint (MPC) element together with the spring element was used to deal with the boundary condition. Finally, the above problems were solved by comparative analysis of their main performance targets (including ultimate static strength, dynamic response, and weight).

Scaling properties of European research units

PubMed Central

Jamtveit, Bjørn; Jettestuen, Espen; Mathiesen, Joachim

2009-01-01

A quantitative characterization of the scale-dependent features of research units may provide important insight into how such units are organized and how they grow. The relative importance of top-down versus bottom-up controls on their growth may be revealed by their scaling properties. Here we show that the number of support staff in Scandinavian research units, ranging in size from 20 to 7,800 staff members, is related to the number of academic staff by a power law. The scaling exponent of ≈1.30 is broadly consistent with a simple hierarchical model of the university organization. Similar scaling behavior between small and large research units with a wide range of ambitions and strategies argues against top-down control of the growth. Top-down effects, and externally imposed effects from changing political environments, can be observed as fluctuations around the main trend. The observed scaling law implies that cost-benefit arguments for merging research institutions into larger and larger units may have limited validity unless the productivity per academic staff and/or the quality of the products are considerably higher in larger institutions. Despite the hierarchical structure of most large-scale research units in Europe, the network structures represented by the academic component of such units are strongly antihierarchical and suboptimal for efficient communication within individual units. PMID:19625626

Sudbury project (University of Muenster-Ontario Geological Survey): Petrology, chemistry, and origin of breccia formations

NASA Technical Reports Server (NTRS)

Stoeffler, D.; Deutsch, A.; Avermann, M.; Brockmeyer, P.; Lakomy, R.; Mueller-Mohr, V.

1992-01-01

Within the Sudbury Project of the University of Muenster and the Ontario Geological Survey special emphasis was put on the breccia formations exposed at the Sudbury structure (SS) because of their crucial role for the impact hypothesis. They were mapped and sampled in selected areas of the north, east, and south ranges of the SS. The relative stratigraphic positions of these units are summarized. Selected samples were analyzed by optical microscopy, SEM, microprobe, XRF and INAA, Rb-Sr and SM-Nd-isotope geochemistry, and carbon isotope analysis. The results of petrographic and chemical analysis for those stratigraphic units that were considered the main structural elements of a large impact basin are summarized.

The impact of the structural features of the rock mass on seismicity in Polish coal mines

NASA Astrophysics Data System (ADS)

Patyńska, Renata

2017-11-01

The article presents seismic activity induced in the coal mines of the Upper Silesian Coal Basin (GZW) in relation to the locations of the occurrence of rockbursts. The comparison of these measurements with the structural features of the rock mass of coal mines indicates the possibility of estimating the so-called Unitary Energy Expenditure (UEE) in a specific time. The obtained values of UEE were compared with the distribution of seismic activity in GZW mines. The level of seismic activity in the analysed period changed and depended on the intensity of mining works and diverse mining and geological conditions. Five regions, where tremors occurred (Bytom Trough, Main Saddle, Main Trough, Kazimierz Trough, and Jejkowice and Chwałowice Trough) which belong to various structural units of the Upper Silesia were analyzed. It was found out that rock bursts were recorded only in three regions: Main Saddle, Bytom Trough, and Jejkowice and Chwałowice Trough.

RESEARCH OPPORTUNITIES AND CHALLENGES REGARDING IMPROVEMENT OF STRUCTURAL INTEGRITY MONITORING FOR DRINKING WATER MAINS

EPA Science Inventory

The United States’ water and wastewater infrastructure is large (i.e., 16,000 publicly owned treatment works, 59,000 community water supplies, 600,000 miles of sewer, 1,000,000 miles of drinking water distribution piping), complex and expensive. The reliable and efficient functio...

Volume and structural relaxation in compressed sodium borate glass.

PubMed

Svenson, Mouritz N; Youngman, Randall E; Yue, Yuanzheng; Rzoska, Sylwester J; Bockowski, Michal; Jensen, Lars R; Smedskjaer, Morten M

2016-11-21

The structure and properties of glass can be modified through compression near the glass transition temperature (T g ), and such modified structure and properties can be maintained at ambient temperature and pressure. However, once the compressed glass undergoes annealing near T g at ambient pressure, the modified structure and properties will relax. The challenging question is how the property relaxation is correlated with both the local and the medium-range structural relaxation. In this paper, we answer this question by studying the volume (density) and structural relaxation of a sodium borate glass that has first been pressure-quenched from its T g at 1 GPa, and then annealed at ambient pressure under different temperature-time conditions. Using 11 B MAS NMR and Raman spectroscopy, we find that the pressure-induced densification of the glass is accompanied by a conversion of six-membered rings into non-ring trigonal boron (B III ) units, i.e. a structural change in medium-range order, and an increase in the fraction of tetrahedral boron (B IV ), i.e. a structural change in short-range order. These pressure-induced structural conversions are reversible during ambient pressure annealing near T g , but exhibit a dependence on the annealing temperature, e.g. the ring/non-ring B III ratio stabilizes at different values depending on the applied annealing temperature. We find that conversions between structural units cannot account for the pressure-induced densification, and instead we suggest the packing of structural units as the main densification mechanism.

Sedimentology of the lower Karoo Supergroup fluvial strata in the Tuli Basin, South Africa

NASA Astrophysics Data System (ADS)

Bordy, Emese M.; Catuneanu, Octavian

2002-11-01

The Karoo Supergroup in the Tuli Basin (South Africa) consists of a sedimentary sequence (˜450-500 m) composed of four stratigraphic units, namely the informal Basal, Middle and Upper Units, and the formal Clarens Formation. The units were deposited in continental settings from approximately Late Carboniferous to Middle Jurassic. This paper focuses on the ˜60-m-thick Basal Unit, which was examined in terms of sedimentary facies and palaeo-environments based on evidence provided by primary sedimentary structures, palaeo-flow measurements, palaeontological findings, borehole data (59 core descriptions) and stratigraphic relations. Three main facies associations have been identified: (i) gravelstone (breccias and conglomerate-breccias), (ii) sandstone and (iii) fine-grained sedimentary rocks. The coarser facies are interpreted as colluvial fan deposits, possibly associated with glaciogenic diamictites. The sandstone facies association is mainly attributed to channel fills of low sinuosity, braided fluvial systems. The coal-bearing finer-grained facies are interpreted as overbank and thaw-lake deposits, and represent the lower energy correlatives of the sandy channel fills. Sediment aggradation in this fluvio-lacustrine system took place under cold climatic conditions, with floating lake ice likely associated with lacustrine environments. Palaeo-current indicators suggest that the highly weathered, quartz-vein-rich metamorphic rock source of the Basal Unit was situated east-northeast of the study area. The accumulation of the Basal Unit took place within the back-bulge depozone of the Karoo foreland system. In addition to flexural subsidence, the amount of accommodation in this tectonic setting was also possibly modified by extensional tectonism in the later stages of the basin development. Based on sedimentological and biostratigraphic evidence, the coal-bearing fine-grained facies association displays strong similarities with the Vryheid Formation of the main Karoo Basin to the south. The lowermost non-fossiliferous breccias have been correlated before with the Dwyka Group in the main Karoo, and hence the Basal Unit may be regarded as the distal equivalent of the Dwyka and Ecca groups to the south.

Contrasting patterns of genetic diversity and population structure of Armillaria mellea sensu stricto in the eastern and western United States.

PubMed

Baumgartner, Kendra; Travadon, Renaud; Bruhn, Johann; Bergemann, Sarah E

2010-07-01

ABSTRACT Armillaria mellea infects hundreds of plant species in natural and managed ecosystems throughout the Northern hemisphere. Previously reported nuclear genetic divergence between eastern and western U.S. isolates is consistent with the disjunct range of A. mellea in North America, which is restricted mainly to both coasts of the United States. We investigated patterns of population structure and genetic diversity of the eastern (northern and southern Appalachians, Ozarks, and western Great Lakes) and western (Berkeley, Los Angeles, St. Helena, and San Jose, CA) regions of the United States. In total, 156 diploid isolates were genotyped using 12 microsatellite loci. Absence of genetic differentiation within either eastern subpopulations (theta(ST) = -0.002, P = 0.5 ) or western subpopulations (theta(ST) = 0.004, P = 0.3 ) suggests that spore dispersal within each region is sufficient to prevent geographic differentiation. In contrast to the western United States, our finding of more than one genetic cluster of isolates within the eastern United States (K = 3), revealed by Bayesian assignment of multilocus genotypes in STRUCTURE and confirmed by genetic multivariate analyses, suggests that eastern subpopulations are derived from multiple founder sources. The existence of amplifiable and nonamplifiable loci and contrasting patterns of genetic diversity between the two regions demonstrate that there are two geographically isolated, divergent genetic pools of A. mellea in the United States.

Geology of the Western Part of Los Alamos National Laboratory (TA-3 to TA-16), Rio Grande Rift, New Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

C.J.Lewis; A.Lavine; S.L.Reneau

2002-12-01

We present data that elucidate the stratigraphy, geomorphology, and structure in the western part of Los Alamos National Laboratory between Technical Areas 3 and 16 (TA-3 and TA-16). Data include those gathered by geologic mapping of surficial, post-Bandelier Tuff strata, conventional and high-precision geologic mapping and geochemical analysis of cooling units within the Bandelier Tuff, logging of boreholes and a gas pipeline trench, and structural analysis using profiles, cross sections, structure contour maps, and stereographic projections. This work contributes to an improved understanding of the paleoseismic and geomorphic history of the area, which will aid in future seismic hazard evaluationsmore » and other investigations. The study area lies at the base of the main, 120-m (400-ft) high escarpment formed by the Pajarito fault, an active fault of the Rio Grande rift that bounds Los Alamos National Laboratory on the west. Subsidiary fracturing, faulting, and folding associated with the Pajarito fault zone extends at least 1,500 m (5,000 ft) to the east of the main Pajarito fault escarpment. Stratigraphic units in the study area include upper units of the Tshirege Member of the early Pleistocene Bandelier Tuff, early Pleistocene alluvial fan deposits that predate incision of canyons on this part of the Pajarito Plateau, and younger Pleistocene and Holocene alluvium and colluvium that postdate drainage incision. We discriminate four sets of structures in the area between TA-3 and TA-16: (a) north-striking faults and folds that mark the main zone of deformation, including a graben in the central part of the study area; (b) north-northwest-striking fractures and rare faults that bound the eastern side of the principal zone of deformation and may be the surface expression of deep-seated faulting; (c) rare northeast-striking structures near the northern limit of the area associated with the southern end of the Rendija Canyon fault; and (d) several small east-west-striking faults. We consider all structures to be Quaternary in that they postdate the Tshirege Member (1.22 million years old) of the Bandelier Tuff. Older mesa-top alluvial deposits (Qoal), which may have a large age range but are probably in part about 1.13 million years old, are clearly faulted or deformed by many structures. At two localities, younger alluvial units (Qfo and Qfi) appear to be truncated by faults, but field relations are obscure, and we cannot confirm the presence of fault contacts. The youngest known faulting in the study area occurred in Holocene time on a down-to-the-west fault, recently trenched at the site of a new LANL Emergency Operations Center (Reneau et al. 2002).« less

Linking hydro-morphology with invertebrate ecology in diverse morphological units of a large river-floodplain system

NASA Astrophysics Data System (ADS)

Blettler, Martín. C. M.; Amsler, Mario L.; Eberle, Eliana G.; Szupiany, Ricardo; Latosinski, Francisco G.; Abrial, Elie; Oberholster, Paul J.; Espinola, Luis A.; Paira, Aldo; Poza, Ailen; Rodrigues Capítulo, Alberto

2016-12-01

Interdisciplinary research in the fields of ecohydrology and ecogeomorphology is becoming increasingly important as a way to understand how biological and physical processes interact with each other in river systems. The objectives of the current study were 1) to determine changes in invertebrate community due to hydrological stages, 2) to link local physical features [flow configuration, sediment composition and morphological feature) with the ecological structure between and within dissimilar morphological units (meander and confluence), and 3) to determine the existence and the origin of bed hydro-geomorphic patches, determining their ecological structure. Results were discussed in the frame of prevailing ecological models and concepts. The study site extends over a floodplain area of the large Paraná River (Argentina), including minor and major secondary channels as well as the main channel. Overall results suggested that hydrodynamics was the driving force determining distribution patterns of benthic assemblages in the floodplain. However, while the invertebrates living in minor secondary channels seem to benefit from flooding, this hydrological phase had the opposite effect on organisms from the main and major secondary channels. We also found a clear linkage between physical features and invertebrate ecology, which caused a dissimilar fauna structure between and within the meander and the confluence. Furthermore, several sandy-patches were recorded in the confluence. These patches were colonized by the particular benthic assemblage recorded in the main channel, supported the view of rivers as patchy discontinua, under uncertain ecological equilibrium.

Value rules: senior management incentives in the post-option era.

PubMed

Ericson, Richard

2004-01-01

Big changes are in the news and on boardroom agendas. This is a good time for many companies to step back and think fundamentally about how senior management incentives are structured and how these programs should be redesigned for better business results. This article describes the main problems with current incentive structures. It then shows how "value rules" can help employers make better use of incentive plans and create a real stake in business units' long-term results, so that the overall structure of executive incentives consistently encourages value creation for shareholders.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cada, Glenn F; Bevelhimer, Mark S

The development of hydrokinetic (HK) energy projects is under consideration at over 150 sites in large rivers in the United States, including the Mississippi, Ohio, Tennessee, and Atchafalaya Rivers. These waterbodies support numerous fish species that might interact with the HK projects in a variety of ways, e.g., by attraction to or avoidance of project structures. Although many fish species inhabit these rivers (about 172 species in the Mississippi River alone), not all of them will encounter the HK projects. Some species prefer low-velocity, backwater habitats rather than the high-velocity, main channel areas that would be the best sites formore » HK. Other, riverbank-oriented species are weak swimmers or too small to inhabit the main channel for significant periods of time. Some larger, main channel fish species are not known to be attracted to structures. Based on a consideration of habitat preferences, size/swim speed, and behavior, fish species that are most likely to be attracted to HK structures in the main channel include carps, suckers, catfish, white bass, striped bass, smallmouth bass, spotted bass, and sauger. Proper siting of the project in order to avoid sensitive fish populations, backwater and fish nursery habitat areas, and fish migration corridors will likely minimize concerns about fish attraction to or avoidance of HK structures.« less

Overview of geology and tectonic evolution of the Baikal-Tuva area.

PubMed

Gladkochub, Dmitry; Donskaya, Tatiana

2009-01-01

This chapter provides the results of geological investigations of the main tectonic units of the Baikal-Tuva region (southwestern part of Siberia) during the last decades: the ancient Siberian craton and adjacent areas of the Central Asian Orogenic belt. In the framework of these main units we describe small-scale blocks (terranes) with focus on details of their inner structure and evolution through time. As well as describing the geology and tectonics of the area studied, we give an overview of underwater sediments, neotectonics, and some phenomena of history and development of the Baikal, Khubsugul, Chargytai, and Tore-Chol Lakes basins of the Baikal-Tuva region. It is suggested that these lakes' evolution was controlled by neotectonic processes, modern seismic activity, and global climate changes.

[Sonography of the eye and orbit with a multipurpose ultrasound unit].

PubMed

Bergès, O; Koskas, P; Lafitte, F; Piekarski, J-D

2006-04-01

Our goal is to help echographists and radiologists become familiar with the various possibilities indications, technique and results of ophtalmic ultrasonography. We used a multipurpose ultrasound unit. The frequency of the transducer has to be equal or superior to 7.5 MHz. Color Doppler allowing the study of low flows is useful. The study must be standardized: the first step is to obtain measurements of both eyes. Then the entire globe is systematically evaluated. Finally, the orbital structures and vessels of the eye and orbit are analized. After a review of the anatomy and the normal sonographic features, the main indications are described as well as the main pathologies. Special attention is paid to intravitreal hemorrhage, retinal and choroidal detachments, intraocular tumors and orbital space occupying lesions.

MODULAR CORE UNITS FOR A NEUTRONIC REACTOR

DOEpatents

Gage, J.F. Jr.; Sherer, D.B.

1964-04-01

A modular core unit for use in a nuclear reactor is described. Many identical core modules can be placed next to each other to make up a complete core. Such a module includes a cylinder of moderator material surrounding a fuel- containing re-entrant coolant channel. The re-entrant channel provides for the circulation of coolant such as liquid sodium from one end of the core unit, through the fuel region, and back out through the same end as it entered. Thermal insulation surrounds the moderator exterior wall inducing heat to travel inwardly to the coolant channel. Spaces between units may be used to accommodate control rods and support structure, which may be cooled by a secondary gas coolant, independently of the main coolant. (AEC)

EVALUATION OF OPPORTUNITIES TO IMPROVE STRUCTURAL INSPECTION CAPABILITIES FOR WATER MAINS: LARGE DIAMETER CAST IRON PIPE

EPA Science Inventory

The U.S. EPA and other organizations have projected that a large portion of the United States’ aging water conveyance infrastructure will reach the end of its service life in the next several decades. EPA has identified asset management as a critical factor in efficiently addre...

Community structure of Aspergillus flavus and A. parasiticus in major almond producing areas of California, United States

USDA-ARS?s Scientific Manuscript database

Several nut crops including almonds, pistachios, and walnuts can become contaminated with mycotoxins. Of greatest economic significance are aflatoxins, which are mainly produced by members of Aspergillus section Flavi. The distribution of the two sclerotial-size morphotypes of A. flavus (i.e. S and ...

Structural characterization of lignin in the process of cooking of cornstalk with solid alkali and active oxygen.

PubMed

Yang, Qiulin; Shi, Jianbin; Lin, Lu; Zhuang, Junping; Pang, Chunsheng; Xie, Tujun; Liu, Ying

2012-05-09

A novel, efficient, and environmentally friendly technology is used in cornstalk cooking, active oxygen (O₂ and H₂O₂) cooking with solid alkali (MgO). After the cooking, the milled wood lignin in the raw material and pulp and the water-soluble and insoluble lignin in the yellow liquor were all characterized by attenuated total reflectance Fourier transform infrared spectroscopy and two-dimensional heteronuclear single-quantum coherence NMR. The results showed that the cooking procedure with solid alkali and active oxygen had a high selectivity for delignification, which could remove 85.5% of the lignin from the raw material. The syringyl (S/S'/S') units could be dissolved preferentially because of their high reactivity, and a novel guaiacyl unit with a carbonyl group (G') was generated in the cooking process. Moreover, during the cooking, the β-O-4' (A/A'/A″) structures as the main side-chain linkages in all the lignins could be partly broken and the β-O-4' (A') with a ring-conjugated structure was readily attacked by oxygen, whereas the H unit and β-5' and β-β' structures were found to stay stable without characteristic reaction.

Structure of Agaricus spp. fucogalactans and their anti-inflammatory and antinociceptive properties.

PubMed

Komura, Dirce L; Carbonero, Elaine R; Gracher, Ana Helena P; Baggio, Cristiane H; Freitas, Cristina S; Marcon, Rodrigo; Santos, Adair R S; Gorin, Philip A J; Iacomini, Marcello

2010-08-01

Fucogalactans from Agaricus brasiliensis (EPF-Ab) and A. bisporus var. hortensis (EPF-Ah) were prepared via by aqueous extraction and a purification procedure. EPF-Ab had M(w) 19.4 x 10(3)g/mol and EPF-Ah M(w) 31.1 x 10(3)g/mol. EPF-Ab had a (1-->6)-linked alpha-D-Galp main-chain partially substituted in O-2 by non-reducing end-units of alpha-L-Fucp. EPF-Ah had a similar main-chain with O-2 substitution, but was partially methylated at HO-3, as well as having 2.5% non-reducing end-units of beta-D-Gal. In mice, EPF-Ab gave 39% antinociceptive inhibition (ID(50)>100mg/kg) and no anti-inflammatory activity. EPF-Ah also gave an inhibition of 39% at ID(50) 0.33 mg/kg and also inhibited by 61% (ID(50) 5.0mg/kg) total cell migration and by 32% peritoneal capillary permeability, which is related to the anti-inflammatory effect. The small differences in chemical structure in these polysaccharides thus modified their biological activities. (c) 2010. Published by Elsevier Ltd.

[Work process and workers' health in a food and nutrition unit: prescribed versus actual work].

PubMed

Colares, Luciléia Granhen Tavares; Freitas, Carlos Machado de

2007-12-01

This study focuses on the relationship between the work process in a food and nutrition unit and workers' health, in the words of the participants themselves. Direct observation, a semi-structured interview, and focus groups were used to collect the data. The reference was the dialogue between human ergonomics and work psychodynamics. The results showed that work organization in the study unit represents a routine activity, the requirements of which in terms of the work situation are based on criteria set by the institution. Variability in the activities is influenced mainly by the available equipment, instruments, and materials, thereby generating improvisation in meal production that produces both a physical and psychological cost for workers. Dissatisfaction during the performance of tasks results mainly from the supervisory style and relationship to immediate superiors. Workers themselves proposed changes in the work organization, based on greater dialogue and trust between supervisors and the workforce. Finally, the study identifies the need for an intervention that encourages workers' participation as agents of change.

Models for structuring a clinical initiative to enhance palliative care in the intensive care unit: a report from the IPAL-ICU Project (Improving Palliative Care in the ICU).

PubMed

Nelson, Judith E; Bassett, Rick; Boss, Renee D; Brasel, Karen J; Campbell, Margaret L; Cortez, Therese B; Curtis, J Randall; Lustbader, Dana R; Mulkerin, Colleen; Puntillo, Kathleen A; Ray, Daniel E; Weissman, David E

2010-09-01

To describe models used in successful clinical initiatives to improve the quality of palliative care in critical care settings. We searched the MEDLINE database from inception to April 2010 for all English language articles using the terms "intensive care," "critical care," or "ICU" and "palliative care"; we also hand-searched reference lists and author files. Based on review and synthesis of these data and the experiences of our interdisciplinary expert Advisory Board, we prepared this consensus report. We critically reviewed the existing data with a focus on models that have been used to structure clinical initiatives to enhance palliative care for critically ill patients in intensive care units and their families. There are two main models for intensive care unit-palliative care integration: 1) the "consultative model," which focuses on increasing the involvement and effectiveness of palliative care consultants in the care of intensive care unit patients and their families, particularly those patients identified as at highest risk for poor outcomes; and 2) the "integrative model," which seeks to embed palliative care principles and interventions into daily practice by the intensive care unit team for all patients and families facing critical illness. These models are not mutually exclusive but rather represent the ends of a spectrum of approaches. Choosing an overall approach from among these models should be one of the earliest steps in planning an intensive care unit-palliative care initiative. This process entails a careful and realistic assessment of available resources, attitudes of key stakeholders, structural aspects of intensive care unit care, and patterns of local practice in the intensive care unit and hospital. A well-structured intensive care unit-palliative care initiative can provide important benefits for patients, families, and providers.

Ghaba salt basin province and Fahud salt basin province, Oman; geological overview and total petroleum systems

USGS Publications Warehouse

Pollastro, R.M.

1999-01-01

Three Total Petroleum Systems each consisting of one assessment unit have been identified in the Ghaba and Fahud Salt Basin Provinces of north-central Oman. One Total Petroleum System and corresponding assessment unit, the North Oman Huqf/`Q'? Haushi(!) Total Petroleum System (201401) and Ghaba-Makarem Combined Structural Assessment Unit (20140101), were identified for the Ghaba Salt Basin Province (2014). In the Fahud Salt Basin Province, however, two overlapping Total Petroleum Systems (TPS) were recognized: 1) the North Oman Huqf ? Shu'aiba(!) TPS (201601); Fahud-Huqf Combined Structural Assessment Unit (20160101), and 2) the Middle Cretaceous Natih(!) TPS (201602); Natih-Fiqa Structural/Stratigraphic Assessment Unit (20160201). The boundary for each Total Petroleum System also defines the boundary of the corresponding assessment unit and includes all trap styles and hydrocarbon producing reservoirs within the petroleum system. In both the Ghaba and Fahud Salt Basin Provinces, hydrocarbons were generated from several deeply-buried source rocks within the Infracambrian Huqf Supergroup. One general `North Oman Huqf' type oil is dominant in the Fahud Salt Basin. Oils in the Ghaba Salt Basin are linked to at least two distinct Huqf source-rock units based on oil geochemistry: a general North Oman Huqf-type oil source and a more dominant `questionable unidentified-source' or `Q'-type Huqf oil source. These two Huqf-sourced oils are commonly found as admixtures in reservoirs throughout north-central Oman. Hydrocarbons generated from Huqf sources are produced from a variety of reservoir types and ages ranging from Precambrian to Cretaceous in both the Ghaba and Fahud Salt Basin Provinces. Clastic reservoirs of the Gharif and Al Khlata Formations, Haushi Group (M. Carboniferous to L. Permian), dominate oil production in the Ghaba Salt Basin Province and form the basis for the Huqf/`Q' ? Haushi(!) TPS. In contrast, the Lower Cretaceous Shu'aiba and Middle Cretaceous Natih limestones account for most of the production in the Fahud Salt Basin with about 50 percent of the basin's production from porous, fractured Shu'aiba limestones in Yibal field, thus the name North Oman Huqf ? Shu'aiba(!) TPS. Deep gas is produced mainly from Middle Cambrian to Lower Ordovician clastic reservoirs of the Haima Supergroup. Traps in nearly all hydrocarbon accumulations of these petroleum systems are mainly structural and were formed by one or more mechanisms. These trap-forming mechanisms were mainly periodic halokinesis of the thick Cambrian Ara Salt and consequent folding and faulting from basin loading, rifting, or other major tectonic events, particularly those events forming the Oman Mountains and associated foreland-basin system during the Late Cretaceous and Late Tertiary. Many of the future new-field targets will likely be low-relief, subtle structures, as many of the large structures have been drilled. Oman's recent interest and commitments to liquid natural gas export make deep gas a primary objective in the two North Oman Huqf petroleum systems. New-field exploration of deep gas and exploring deeper targets for gas in existing fields will likely identify a significant gas resource in the next thirty years. Moreover, salt-diapir flank traps in these two North Oman Huqf petroleum systems and salt basin provinces have gone essentially untested and will likely be targeted in the near-future. The Middle Cretaceous Natih(!) TPS is a small efficient system of the Fahud Salt Basin. Natih source rocks are only mature in the Late Cretaceous/Tertiary foredeep and production is primarily from Natih reservoirs; minor production from the Shu'aiba limestone is documented along fault-dip structures. Most traps are structural and are related to development of the foreland basin and formation of the Oman Mountains. Future targets of the Natih TPS will be less obvious than those of Fahud and Natih fields and likely includ

Ghaba salt basin province and Fahud salt basin province, Oman; geological overview and total petroleum systems

USGS Publications Warehouse

Pollastro, Richard M.

1999-01-01

Three Total Petroleum Systems each consisting of one assessment unit have been identified in the Ghaba and Fahud Salt Basin Provinces of north-central Oman. One Total Petroleum System and corresponding assessment unit, the North Oman Huqf/?Q??Haushi(!) Total Petroleum System (201401) and Ghaba- Makarem Combined Structural Assessment Unit (20140101), were identified for the Ghaba Salt Basin Province (2014). In the Fahud Salt Basin Province, however, two overlapping Total Petroleum Systems (TPS) were recognized: (1) the North Oman Huqf?Shu?aiba(!) TPS (201601); Fahud-Huqf Combined Structural Assessment Unit (20160101), and (2) the middle Cretaceous Natih(!) TPS (201602); Natih-Fiqa Structural/Stratigraphic Assessment Unit (20160201). The boundary for each Total Petroleum System also defines the boundary of the corresponding assessment unit and includes all trap styles and hydrocarbon-producing reservoirs within the petroleum system. In both the Ghaba and Fahud Salt Basin Provinces, hydrocarbons were generated from several deeply buried source rocks within the Infracambrian Huqf Supergroup. One general ?North Oman Huqf? type oil is dominant in the Fahud Salt Basin. Oils in the Ghaba Salt Basin are linked to at least two distinct Huqf source-rock units based on oil geochemistry: a general North Oman Huqf-type oil source and a more dominant ?questionable unidentified source? or ?Q?-type Huqf oil source. These two Huqf-sourced oils are commonly found as admixtures in reservoirs throughout northcentral Oman. Hydrocarbons generated from Huqf sources are produced from a variety of reservoir types and ages ranging from Precambrian to Cretaceous in both the Ghaba and Fahud Salt Basin Provinces. Clastic reservoirs of the Gharif and Al Khlata Formations, Haushi Group (middle Carboniferous to Lower Permian), dominate oil production in the Ghaba Salt Basin Province and form the basis for the Huqf/?Q??Haushi(!) TPS. In contrast, the Lower Cretaceous Shu?aiba and middle Cretaceous Natih limestones account for most of the production in the Fahud Salt Basin with about 50 percent of the basin?s production from porous, fractured Shu?aiba limestones in Yibal field, thus the name North Oman Huqf? Shu?aiba(!) TPS. Deep gas is produced mainly from Middle Cambrian to Lower Ordovician clastic reservoirs of the Haima Supergroup. Traps in nearly all hydrocarbon accumulations of these petroleum systems are mainly structural and were formed by one or more 3 mechanisms. These trap-forming mechanisms were mainly periodic halokinesis of the thick Cambrian Ara Salt and consequent folding and faulting from basin loading, rifting, or other major tectonic events, particularly those events forming the Oman Mountains and associated foreland-basin system during the Late Cretaceous and late Tertiary. Many of the future new-field targets will likely be low-relief, subtle structures, as many of the large structures have been drilled. Oman?s recent interest and commitments to liquid natural gas export make deep gas a primary objective in the two North Oman Huqf petroleum systems. New-field exploration of deep gas and exploring deeper targets for gas in existing fields will likely identify a significant gas resource in the next 30 years. Moreover, salt-diapir flank traps in these two North Oman Huqf petroleum systems and salt basin provinces have gone essentially untested and will likely be targeted in the near future. The middle Cretaceous Natih(!) TPS is a small efficient system of the Fahud Salt Basin. Natih source rocks are only mature in the Late Cretaceous/Tertiary foredeep and production is primarily from Natih reservoirs; minor production from the Shu?aiba limestone is documented along fault-dip structures. Most traps are structural and are related to development of the foreland basin and formation of the Oman Mountains. Future targets of the Natih TPS will be less obvious

Origin and development of plains-type folds in the mid-continent (United States) during the late Paleozoic

USGS Publications Warehouse

Merriam, D.F.

2005-01-01

Plains-type folds are local, subtle anticlines formed in the thin sedimentary package overlying a shallow, crystalline basement on the craton. They are small in areal extent (usually less than 1-3 km 2 [0.4-1.2 mi2]), and their amplitude increases with depth (usually tens of meters), which is mainly the result of differential compaction of sediments (usually clastic units) over tilted, rigid, basement fault blocks. The development of these structural features by continuous but intermittent movement of the basement fault blocks in the late Paleozoic in the United States mid-continent is substantiated by a record of stratigraphic and sedimentological evidence. The recurrent structural movement, which reflects adjustment to external stresses, is expressed by the change in thickness of stratigraphic units over the crest of the fold compared to the flanks. By plotting the change in thickness for different stratigraphic units of anticlines on different fault blocks, it is possible to determine the timing of movement of the blocks that reflect structural adjustment. These readjustments are confirmed by sedimentological evidence, such as convolute, soft-sediment deformation features and small intraformational faults. The stratigraphic interval change in thickness for numerous structures in the Cherokee, Forest City, and Salina basins and on the Nemaha anticline of the mid-continent United States was determined and compared for location and timing of the adjustments. Most of the adjustment occurred during and after time of deposition of the Permian-Pennsylvanian clastic units, which, in turn, reflect tectonic disturbance in adjacent areas, and the largest amount of movement on the plains-type structures occurred on those nearest and semiparallel to major positive features, such as the Nemaha anticline. Depending on the time of origin and development of plains-type folds, they may control the entrapment and occurrence of oil and gas. Copyright ??2005. The American Association of Petroleum Geologists. All rights reserved.

Anatomy of an Active Seismic Source: the Interplay between Present-Day Seismic Activity and Inherited Fault Zone Architecture (Central Apennines, Italy)

NASA Astrophysics Data System (ADS)

Fondriest, M.; Demurtas, M.; Bistacchi, A.; Fabrizio, B.; Storti, F.; Valoroso, L.; Di Toro, G.

2017-12-01

The mechanics and seismogenic behaviour of fault zones are strongly influenced by their internal structure, in terms of both fault geometry and fault rock constitutive properties. In recent years high-resolution seismological techniques yielded new constraints on the geometry and velocity structure of seismogenic faults down to 10s meters length scales. This reduced the gap between geophysical imaging of active seismic sources and field observations of exhumed fault zones. Nevertheless fundamental questions such as the origin of geometrical and kinematic complexities associated to seismic faulting remain open. We addressed these topics by characterizing the internal structure of the Vado di Corno Fault Zone, an active seismogenic normal fault cutting carbonates in the Central Apennines of Italy and comparing it with the present-day seismicity of the area. The fault footwall block, which was exhumed from < 2 km depth, was mapped with high detail (< 1 m spatial resolution) for 2 km of exposure along strike, combining field structural data and photogrammetric surveys in a three dimensional structural model. Three main structural units separated by principal fault strands were recognized: (i) cataclastic unit (20-100 m thick), (ii) damage zone (≤ 300 m thick), (iii) breccia unit ( 20 thick). The cataclastic unit lines the master fault and represents the core of the normal fault zone. In-situ shattering together with evidence of extreme (possibly coseismic) shear strain localization (e.g., mirror-like faults with truncated clasts, ultrafine-grained sheared veins) was recognized. The breccia unit is an inherited thrust zone affected by pervasive veining and secondary dolomitization. It strikes subparallel to the active normal fault and is characterized by a non-cylindrical geometry with 10-100 m long frontal and lateral ramps. The cataclastic unit cuts through thrust flats within the breccia unit, whereas normal to oblique inversion occur on frontal and lateral ramps. A comparable structural setting was imaged South-West of the study area, during the 2009 L'Aquila seismic sequence. Here at 2 km depth, the master normal fault cross-cuts a 10 km long flat structure and clear lateral ramps are illuminated, suggesting the superposition of normal seismic faulting on inherited compressional structures.

Sea Cucumber Glycosides: Chemical Structures, Producing Species and Important Biological Properties.

PubMed

Mondol, Muhammad Abdul Mojid; Shin, Hee Jae; Rahman, M Aminur; Islam, Mohamad Tofazzal

2017-10-17

Sea cucumbers belonging to echinoderm are traditionally used as tonic food in China and other Asian countries. They produce abundant biologically active triterpene glycosides. More than 300 triterpene glycosides have been isolated and characterized from various species of sea cucumbers, which are classified as holostane and nonholostane depending on the presence or absence of a specific structural unit γ(18,20)-lactone in the aglycone. Triterpene glycosides contain a carbohydrate chain up to six monosaccharide units mainly consisting of d-xylose, 3-O-methy-d-xylose, d-glucose, 3-O-methyl-d-glucose, and d-quinovose. Cytotoxicity is the common biological property of triterpene glycosides isolated from sea cucumbers. Besides cytotoxicity, triterpene glycosides also exhibit antifungal, antiviral and hemolytic activities. This review updates and summarizes our understanding on diverse chemical structures of triterpene glycosides from various species of sea cucumbers and their important biological activities. Mechanisms of action and structural-activity relationships (SARs) of sea cucumber glycosides are also discussed briefly.

Setting up a mobile dental practice within your present office structure.

PubMed

Morreale, James P; Dimitry, Susan; Morreale, Mark; Fattore, Isabella

2005-02-01

Different service models have emerged in Canada and the United States to address the issue of senior citizens' lack of access to comprehensive dental care. Over the past decade, one such model, the use of mobile dental service units, has emerged as a practical strategy. This article describes a mobile unit, operated as an adjunct to the general practitioner's office and relying mainly on existing office resources, both human and capital, to deliver services at long-term care institutions. The essential components of a profitable geriatric mobile unit are described, including education, equipment, marketing research and development, and human resource management. Issues related to patient consent and operating expenditures are also discussed. Data from one practitioner's mobile dental unit, in Hamilton, Ontario, are presented to demonstrate the feasibility and profitability of this approach.

Structural and Luminescent property of Holmium doped Borate Glasses

NASA Astrophysics Data System (ADS)

Usharani, V. L.; Eraiah, B.

2018-02-01

Holmium doped Lithium Lead Borate glasses of different compositions were prepared by melt quenching technique. Fourier transform infrared investigations on lithium lead borate glasses have been made to study the local order and vibrations of atoms in the glass network and it contains mainly BO3 and BO4 structural units. Photoluminescence techniques were employed to investigate the luminescent property of these glasses excited at 451nm. Blue emission have been observed from the transition 495 (5F3 → 5I8).

[Retrospective analysis of primary disability among employees of enterprises for the production of technical ceramics].

PubMed

Serebryakov, P V; Khoshtariya, N V; Mustafina, I Z

On the example of588 disability cases registered in employees of the plant for the production of technical ceramics during the 1975-2014 the analysis of the dynamics of illness, gender and age structure of disability indices on the main Origlnarartlcie and auxiliary units of the enterprise was executed for the interval of 10 years periods. There were followed trends in the alteration of the structure of the disability caused by the socio-economic, hygienic and demographic factors.

Structure of a normal seismogenic fault zone in carbonates: The Vado di Corno Fault, Campo Imperatore, Central Apennines (Italy)

NASA Astrophysics Data System (ADS)

Demurtas, Matteo; Fondriest, Michele; Balsamo, Fabrizio; Clemenzi, Luca; Storti, Fabrizio; Bistacchi, Andrea; Di Toro, Giulio

2016-09-01

The Vado di Corno Fault Zone (VCFZ) is an active extensional fault cutting through carbonates in the Italian Central Apennines. The fault zone was exhumed from ∼2 km depth and accommodated a normal throw of ∼2 km since Early-Pleistocene. In the studied area, the master fault of the VCFZ dips N210/54° and juxtaposes Quaternary colluvial deposits in the hangingwall with cataclastic dolostones in the footwall. Detailed mapping of the fault zone rocks within the ∼300 m thick footwall-block evidenced the presence of five main structural units (Low Strain Damage Zone, High Strain Damage Zone, Breccia Unit, Cataclastic Unit 1 and Cataclastic Unit 2). The Breccia Unit results from the Pleistocene extensional reactivation of a pre-existing Pliocene thrust. The Cataclastic Unit 1 forms a ∼40 m thick band lining the master fault and recording in-situ shattering due to the propagation of multiple seismic ruptures. Seismic faulting is suggested also by the occurrence of mirror-like slip surfaces, highly localized sheared calcite-bearing veins and fluidized cataclasites. The VCFZ architecture compares well with seismological studies of the L'Aquila 2009 seismic sequence (mainshock MW 6.1), which imaged the reactivation of shallow-seated low-angle normal faults (Breccia Unit) cut by major high-angle normal faults (Cataclastic Units).

Crystal structure of 1,3-bis-(1H-benzotriazol-1-yl-meth-yl)benzene.

PubMed

Macías, Mario A; Nuñez-Dallos, Nelson; Hurtado, John; Suescun, Leopoldo

2016-06-01

The mol-ecular structure of the title compound, C20H16N6, contains two benzotriazole units bonded to a benzene nucleus in a meta configuration, forming dihedral angles of 88.74 (11) and 85.83 (10)° with the central aromatic ring and 57.08 (9)° with each other. The three-dimensional structure is controlled mainly by weak C-H⋯N and C-H⋯π inter-actions. The mol-ecules are connected in inversion-related pairs, forming the slabs of infinite chains that run along the [-110] and [110] directions.

4. General view of the N elevation, showing the rear ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. General view of the N elevation, showing the rear of the main block and the courtyard between the E & W wings; looking S. Note structure 73, an air-conditioning unit, in the end of the courtyard. (Ceronie) - Rock Island Arsenal, Building No. 62, Rodman Avenue between First & Second Streets, Rock Island, Rock Island County, IL

Inheritance, Variscan tectonometamorphic evolution and Permian to Mesozoic rejuvenations in the metamorphic basement complexes of the Romanian Carpathians revealed by monazite microprobe geochronology

NASA Astrophysics Data System (ADS)

Săbău, Gavril; Negulescu, Elena

2014-05-01

Monazite U-Th-Pb chemical dating reaches an acceptable compromise between precision and accuracy on one side, and spatial resolution and textural constraints on the other side. Thus it has a powerful potential in testing the coherence of individual metamorphic basement units, and enabling correlations among them. Yet, sensitivity and specificity issues in monazite response to thermotectonic events, especially in the case of superposed effects, remain still unclear. Monazite dating at informative to detailed scale in the main metamorphic basement units of the Carpathians resulted in complex age spectra. In the main, the spectra are dominated by the most pervasive thermal and structural overprint, as checked against independent geochronological data. Post-peak age resetting is mostly present, but statistically subordinate. Resetting in case of superposed events is correlated with the degree of textural and paragenetic overprinting, inheritances being always indicated by more or less well-defined age clusters. The lack of relict ages correlating with prograde structural and porphyroblast zonation patterns is indicative for juvenile formations. Age data distribution in the Carpathians allowed distinction of pre-Variscan events, syn-metamorphic Variscan tectonic stacking of juvenile and reworked basement, post-Variscan differential tectonic uplift, as well as prograde metamorphic units ranging down to Upper Cretaceous ages. In the South Carpathians, the Alpine Danubian domain consists of several Variscan and Alpine thrust sheets containing a metamorphic complex dominated by Upper Proterozoic to Lower Cambrian metamorphic and magmatic ages (Lainici-Păiuş), and several complexes with metamorphic overprints ranging from Carboniferous to Lower Permian. Any correlation among these units, as well as geotectonic models placing a Lower Paleozoic oceanic domain between pre-existing Lainici-Păiuş and Drăgşan terranes are precluded by the age data. Other basement of the South Carpathians contain lower Paleozoic or older units intruded by Ordovician granitoids, imbricated with juvenile Variscan slivers, the structural sequence differing in individual basement complexes. So, in the Leaota Massif the lowermost term of the sequence is prograde Variscan, tectonically overlain by reworked lower Paleozoic gneisses, supporting thrust sheets with very low- to low-grade Variscan schists. In the Făgăraş Massif a lower Paleozoic (Cumpăna) complex bearing a strong Variscan overprint, straddles Variscan juvenile rocks, and the lowermost visible structural level is assumed by upper Carboniferous to Permian juvenile medium-grade metamorphic schists. In the Lotru Metamorphic Suite of the Alpine Getic Nappe, the Variscan stacking is overprinted by post-orogenic differential uplift, documented by the correlation among younging ages, structural and metamorphic low-pressure overprints, recording often higher metamorphic temperatures. The most spectacular structure is Upper Jurassic in age, contains high-grade metamorphic rocks and peraluminous anatectic granitoids, is outlined by a deformed boundary evolving from ductile to brittle regime during cooling, and induces a thermal overprint in the neighbouring rocks. In the basement units thrust over the Getic Nappe, the Sibişel unit yielded Permian prograde peak metamorphic ages and Triassic post-peak overprints, while an adjacent gneissic unit (Laz) delivered an exclusively Cretaceous age pattern. Unexpectedly young metamorphic ages resulted also for the East Carpathians and the Apuseni Mountains. While most of the ages obtained so far correspond to Variscan retrogression of older basement units, the lowermost structural unit of the infra-Bucovinian nappe system in the East Carpathians yielded Upper Cretaceous metamorphic ages in apparently monometamorphic medium-grade schists. In the Apuseni Mountains, schists of the Baia de Arieş Unit display an Upper Jurassic age spectrum, corresponding to a clearly prograde medium-grade event. The ages recorded not only question some of the currently accepted correlations among basement units, but urge to reconsideration of the way in which the basement-cover relationships are interpreted and extrapolated.

Influence of surrounding structures upon the aerodynamic and acoustic performance of the outdoor unit of a split air-conditioner

NASA Astrophysics Data System (ADS)

Wu, Chengjun; Liu, Jiang; Pan, Jie

2014-07-01

DC-inverter split air-conditioner is widely used in Chinese homes as a result of its high-efficiency and energy-saving. Recently, the researches on its outdoor unit have focused on the influence of surrounding structures upon the aerodynamic and acoustic performance, however they are only limited to the influence of a few parameters on the performance, and practical design of the unit requires more detailed parametric analysis. Three-dimensional computational fluid dynamics(CFD) and computational aerodynamic acoustics(CAA) simulation based on FLUENT solver is used to study the influence of surrounding structures upon the aforementioned properties of the unit. The flow rate and sound pressure level are predicted for different rotating speed, and agree well with the experimental results. The parametric influence of three main surrounding structures(i.e. the heat sink, the bell-mouth type shroud and the outlet grille) upon the aerodynamic performance of the unit is analyzed thoroughly. The results demonstrate that the tip vortex plays a major role in the flow fields near the blade tip and has a great effect on the flow field of the unit. The inlet ring's size and throat's depth of the bell-mouth type shroud, and the through-flow area and configuration of upwind and downwind sections of the outlet grille are the most important factors that affect the aerodynamic performance of the unit. Furthermore, two improved schemes against the existing prototype of the unit are developed, which both can significantly increase the flow rate more than 6 %(i.e. 100 m3·h-1) at given rotating speeds. The inevitable increase of flow noise level when flow rate is increased and the advantage of keeping a lower rotating speed are also discussed. The presented work could be a useful guideline in designing the aerodynamic and acoustic performance of the split air-conditioner in engineering practice.

Geology of the Göçükdibi Cu-Pb-Zn Mineralization, Gökçedoǧan, Çorum (Turkey): Preliminary Findings on Its Formation

NASA Astrophysics Data System (ADS)

Yalçin, Cihan; Hanilçi, Nurullah; Kumral, Mustafa; Abdelnasser, Amr

2016-04-01

Göçükdibi Cu-Pb-Zn mineralization is located 3 km north west of Gökçedoǧan village where is 30 km east of the Kargı, Çorum. The geology of the mineralization area is represented by Mesozoic and Upper Pliocene lithostratigraphic units in different origin. These units with respect to their structural locations have identified as autochthonous and allachtonous. The autochthonous units which are the basement of the region are represented by Bekirli Metamorphites (Triassic-Liassic) and Beşpınar formation (Upper Cretaceous-Lower Eocene) which overlies the Bekirli Metamorphites as angular discordance. The allachtonous units are represented by Saraycık formation belongs to Kargı Ophioltic Melange, and located on the autochthonous units as tectonically. These allocthonous units are the product of the Neotethyan Ocean. The autochthonous and allachtonous units are overlaid by Upper Pliocene Ilgaz Formation and Plio-Quaternary stream sediments. The Cu-Pb-Zn mineralization is located in northwest of the Gökçedoǧan village within the Bekirli Metamorphites. The ore zone has N80E direction, 5 m wide and 120 m in length. The mineralizations which follow NE-SW trending structural line occurred as alternation with quartz-chlorite schists of the Bekirli Metamorphites. The mineralization is generally concordant to the foliation of schist's and also occurred as disseminated in the wall rocks. The ore paragenesis comprises with pyrite, chalcopyrite, sphalerite and galenit as the main sulphide minerals, and the malachite, azurite and limonite as the production of the oxidation. Preliminary data such as relationship between the ore and host rock, inner-structure of the ore and indicate that the Gökçedoǧan Cu-Pb-Zn mineralization was likely to have originated syngenetic. In addition, the geochemical behaviour of rare earth elements (REE) of the altered and mineralized samples collected from the alteration zone show that light REE enrichment with fair depletion of heavy REE during the alteration processes with positive Eu anomalies. As well as there is a positive correlation between K2O index and LREE that reveal the addition of K and La and the sericitization is the main alteration associated with the studied deposit. Key Words: Cu-Pb-Zn mineralization, Syngenetic, Bekirli Metamorphites, Gökçedoǧan.

Sedimentology of the Ripogenus Formation, Maine: A Silurian carbonate-siliciclastic depositional system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Comrie, T.A.; Caldwell, D.W.

The Ripogenus Formation of north-central Maine is shallow marine unit of probable Wenlockian age characterized by interbeds of sandstone and limestone less than 50 cm. in thickness and separated by sharp, often erosional, contacts. Reefal material with abundant stromatoporoids is exposed in the eastern part of the formation and is overlain locally by Silurian andesite and Siluro-Devonian redbeds. Sediment size and bed thickness decrease to the west, as does the relative amount of carbonate sediment. Common fossils also include stromatolites, brachiopods, gastropods, crinoids, and corals. Large fossils, notably the stromatoporoids and stromatolites, are often found in growth position, but smallermore » fossils are usually found to have been abraided and transported. The formation was deposited in an area shown by paleogeographic reconstructions to have been located just south of the equator (probably near one or more islands) in the lapetus Ocean prior to its closure. Although sedimentary structures are often not well preserved due to its closure. Although sedimentary structures are often not well preserved due to soft-sedimentary deformation and slight metamorphism, there is some evidence of storm-controlled deposition. Deposition of this unit and other Silurian carbonates found in Maine and the Maritime Provinces are unlike those found throughout N. America in that they are the product of localized deposition in an unstable tectonic environment.« less

Mild acetosolv process to fractionate bamboo for the biorefinery: structural and antioxidant properties of the dissolved lignin.

PubMed

Li, Ming-Fei; Sun, Shao-Ni; Xu, Feng; Sun, Run-Cang

2012-02-22

Fractionation of lignocellulosic material into its constitutive components is of vital importance for the production of biofuels as well as other value-added chemicals. The conventional acetosolv processes are mainly focused on the production of pulp from woody lignocelluloses. In this study, a mild acetosolv process was developed to fractionate bamboo under atmospheric pressure to obtain cellulosic pulp, water-soluble fraction, and acetic acid lignin. The structural features of the lignins obtained under various conditions were characterized with elemental analysis, sugar analysis, alkaline nitrobenzene oxidation, gel permeation chromatography (GPC), (1)H nuclear magnetic resonance ((1)H NMR), and heteronuclear single-quantum coherence (HSQC) spectroscopy. As compared to milled wood lignin (MWL) of bamboo, acetic acid lignins had low impurities (carbohydrates 2.48-4.56%) mainly due to the cleavage of linkages between lignin and carbohydrates. In addition, acetic acid lignins showed a low proportion of syringyl (S) units. Due to the cleavage of linkages between lignin units, acetic acid lignins had weight-average molecular weights ranging from 4870 to 5210 g/mol, less than half that of MWL (13000 g/mol). In addition, acetic acid lignins showed stronger antioxidant activity mainly due to the significant increase of free phenolic hydroxyls. The lignins obtained with such low impurities, high free phenolic hydroxyls, and medium molecular weights are promising feedstocks to replace petroleum chemicals.

Deformation patterns in the southwestern part of the Mediterranean Ridge (South Matapan Trench, Western Greece)

NASA Astrophysics Data System (ADS)

Andronikidis, Nikolaos; Kokinou, Eleni; Vafidis, Antonios; Kamberis, Evangelos; Manoutsoglou, Emmanouil

2017-12-01

Seismic reflection data and bathymetry analyses, together with geological information, are combined in the present work to identify seabed structural deformation and crustal structure in the Western Mediterranean Ridge (the backstop and the South Matapan Trench). As a first step, we apply bathymetric data and state of art methods of pattern recognition to automatically detect seabed lineaments, which are possibly related to the presence of tectonic structures (faults). The resulting pattern is tied to seismic reflection data, further assisting in the construction of a stratigraphic and structural model for this part of the Mediterranean Ridge. Structural elements and stratigraphic units in the final model are estimated based on: (a) the detected lineaments on the seabed, (b) the distribution of the interval velocities and the presence of velocity inversions, (c) the continuity and the amplitudes of the seismic reflections, the seismic structure of the units and (d) well and stratigraphic data as well as the main tectonic structures from the nearest onshore areas. Seabed morphology in the study area is probably related with the past and recent tectonics movements that result from African and European plates' convergence. Backthrusts and reverse faults, flower structures and deep normal faults are among the most important extensional/compressional structures interpreted in the study area.

Mapping urban geology of the city of Girona, Catalonia

NASA Astrophysics Data System (ADS)

Vilà, Miquel; Torrades, Pau; Pi, Roser; Monleon, Ona

2016-04-01

A detailed and systematic geological characterization of the urban area of Girona has been conducted under the project '1:5000 scale Urban geological map of Catalonia' of the Catalan Geological Survey (Institut Cartogràfic i Geològic de Catalunya). The results of this characterization are organized into: i) a geological information system that includes all the information acquired; ii) a stratigraphic model focused on identification, characterization and correlation of the geological materials and structures present in the area and; iii) a detailed geological map that represents a synthesis of all the collected information. The mapping project integrates in a GIS environment pre-existing cartographic documentation (geological and topographical), core data from compiled boreholes, descriptions of geological outcrops within the urban network and neighbouring areas, physico-chemical characterisation of representative samples of geological materials, detailed geological mapping of Quaternary sediments, subsurface bedrock and artificial deposits and, 3D modelling of the main geological surfaces. The stratigraphic model is structured in a system of geological units that from a chronostratigrafic point of view are structured in Palaeozoic, Paleogene, Neogene, Quaternary and Anthropocene. The description of the geological units is guided by a systematic procedure. It includes the main lithological and structural features of the units that constitute the geological substratum and represents the conceptual base of the 1:5000 urban geological map of the Girona metropolitan area, which is organized into 6 map sheets. These map sheets are composed by a principal map, geological cross sections and, several complementary maps, charts and tables. Regardless of the geological map units, the principal map also represents the main artificial deposits, features related to geohistorical processes, contours of outcrop areas, information obtained in stations, borehole data, and contour lines of the top of the pre-Quaternary basement surface. The most representative complementary maps are the quaternary map, the subsurface bedrock map and the isopach map of thickness of superficial deposits (Quaternary and anthropogenic). The map sheets also include charts and tables of relevant physic-chemical parameters of the geological materials, harmonized downhole lithological columns from selected boreholes, stratigraphic columns, and, photographs and figures illustrating the geology of the mapped area and how urbanization has changed the natural environment. The development of systematic urban geological mapping projects, such as the example of Girona's case, which provides valuable resources to address targeted studies related to urban planning, geoengineering works, soil pollution and other important environmental issues that society should deal with in the future.

Current Status of Continued Operation for Kori unit 1 beyond Design Life

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tai-hyun Kim; Pan-sool Kim; Yeon-sang Yu

2006-07-01

Since the commercial operation of Kori Nuclear Power Plant unit 1 in April 1978, Korea has achieved rapid growth in its nuclear industry, and now has 20 operating nuclear power plants. As the design life of Kori unit 1 comes to an end, Korea Hydro and Nuclear Power Co., Ltd.(KHNP) is preparing for the continued operation of the plant for the first time in Korea. The feasibility of continued operation beyond design life has been already proven in many countries. Developed countries, such as the USA, England, Japan and so on, are also proceeding with the continued operation of NPPsmore » whose design life or license is due to expire, as long as the adequate safety and aging management review meet the acceptance criteria. Continued operation is absolutely needed for countries lacking in natural resources, such as Korea, in view of the efficient utilization of energy resources and reduction of greenhouse gases (CO{sub 2}) emission. For the continued operation beyond design life (30 yrs) of Kori unit 1, KHNP has performed Lifetime Management (PLiM) study, Periodic Safety Review (PSR), Probabilistic Safety Assessment (PSA) and Environmental Qualification (EQ), etc. and replaced main equipment, such as Steam Generators, Low Pressure Turbine Rotor, RCP Internals, Main Transformer, Main Generator, and so on. In September 2005, The Regulation of Atomic Energy Act in Korea was revised and published referring to License Renewal Rule of the USA. According to the revised regulations, KHNP is performing Life Assessment for Main Systems, Structures and Components (SSCs) and Radiological Impacts on the Environment with PSR for continued operation. (authors)« less

Average crystal structure(s) of the embedded meta stable η‧-phase in the Al-Mg-Zn system

NASA Astrophysics Data System (ADS)

Bøvik Larsen, Helge; Thorkildsen, Gunnar; Natland, Sølvi; Pattison, Philip

2014-05-01

Meta stable embedded nano-sized ?-particles within a single grain extracted from an alloy having the nominal composition ? have been examined with X-ray diffraction. By applying the orientational and metric relationships that exist between the hexagonal unit cell of the ?-particles and the cubic unit cell of the Al-matrix, it has been proven possible to directly collect diffracted intensity data from the ?-particle ensemble. This has been done using synchrotron radiation and a ?-diffractometer having a scintillator point detector setup. The approach has resulted in improved data quality compared to previous experiments. The interpretation of the data set, based on a combination of Patterson syntheses, direct methods and geometrical restraints, yielded two possible average structural representations: one Al-rich with the approximate stoichiometric composition ? and one Al-depleted with approximate stoichiometric composition ?. Both structures are realized in the same space group, ?, and are most probably superimposed in the crystalline system examined. The geometries are discussed within the atomic environment approach where icosahedral or near-icosahedral configurations are encountered. Comparison with previous published models and the equilibrium structure reveals a main difference related to the distribution of the Zn-sites in the unit cell. A possible transformation path is also suggested. Various aspects and challenges regarding data collection, data reduction and data quality are specifically addressed.

Molecular structure of dextran sulphate sodium in aqueous environment

NASA Astrophysics Data System (ADS)

Yu, Miao; Every, Hayley A.; Jiskoot, Wim; Witkamp, Geert-Jan; Buijs, Wim

2018-03-01

Here we propose a 3D-molecular structural model for dextran sulphate sodium (DSS) in a neutral aqueous environment based on the results of a molecular modelling study. The DSS structure is dominated by the stereochemistry of the 1,6-linked α-glucose units and the presence of two sulphate groups on each α-glucose unit. The structure of DSS can be best described as a helix with various patterns of di-sulphate substitution on the glucose rings. The presence of a side chain does not alter the 3D-structure of the linear main chain much, but affects the overall spatial dimension of the polymer. The simulated polymers have a diameter similar to or in some cases even larger than model α-hemolysin nano-pores for macromolecule transport in many biological processes, indicating a size-limited translocation through such pores. All results of the molecular modelling study are in line with previously reported experimental data. This study establishes the three-dimensional structure of DSS and summarizes the spatial dimension of the polymer, serving as the basis for a better understanding on the molecular level of DSS-involved electrostatic interaction processes with biological components like proteins and cell pores.

Maine: 2002 Economic Census. Educational Services, Geographic Area Series. EC02-61A-ME.

ERIC Educational Resources Information Center

US Department of Commerce, 2005

2005-01-01

The economic census is the major source of facts about the structure and functioning of the nation's economy. It provides essential information for government, business, industry, and the general public. Title 13 of the United States Code (Sections 131, 191, and 224) directs the Census Bureau to take the economic census every 5 years, covering…

Pay Attention to the Phrasal Structures: Going beyond T-Units--A Response to Weiwei Yang

ERIC Educational Resources Information Center

Biber, Douglas; Gray, Bethany; Poonpon, Kornwipa

2013-01-01

WeiWei Yang, in her forum piece, raises two main criticisms of the authors' "TQ" article on grammatical complexity: "The study the authors conducted [1] is not capable of answering development-related questions and [2] is mathematically questionable" (Yang, 2013, p. 190). In addition, Yang's article has a third goal that is not explicitly…

Ambivalence and Fluidity in the Teenage Smoking and Quitting Experience: Lessons from a Qualitative Study at an English Secondary School

ERIC Educational Resources Information Center

Buswell, Marina; Duncan, Peter

2013-01-01

Objective: To evaluate a school-based stop smoking pilot project and to understand the teenage experience of smoking and quitting within that context. Design: Flexible design methods. Setting: A Kent (United Kingdom [UK]) secondary school. Methods: Semi-structured interviews analyzed following a grounded theory approach. Results: The main themes…

Comparing the effectiveness of thinning and prescribed fire for modifying structure in dry coniferous forests

Treesearch

Richy J. Harrod; Nicholas A. Povak; David W. Peterson

2007-01-01

Forest thinning and prescribed fires are the main practices used by managers to address concerns over ecosystem degradation and severe wildland fire potential in dry forests of the Western United States. There is some debate, however, about treatment effectiveness in meeting management objectives as well as their ecological consequences. This study assesses the...

Kinematic evolution of southern Hellenides (western Crete, Greece)

NASA Astrophysics Data System (ADS)

Chatzaras, V.; Xypolias, P.; Kokkalas, S.; Koukouvelas, I. K.

2010-05-01

Combined kinematic, structural and paleostress analyses were performed to reevaluate the tectonic evolution of the southern Hellenides in western Crete. Our work shows that the structural architecture of the study area was mainly established by two contractional deformation phases. SSW-directed thrusting from Oligocene to lower Miocene times (D1 phase) lead to brittle stacking of the upper thrust sheets and concomitant ductile exhumation-related imbrication of the lower HP tectonic units (Phyllite-Quartzite (PQ), Tripali and Plattenkalk units). Kinematic analysis in the PQ unit reveals a main southward ductile transport followed by late bulk coaxial deformation. The PQ unit rocks comprise the body of a crustal scale shear zone confined at its base by a major ductile thrust and in accordance with the proposed models we suggest that the exhumation process of the PQ unit involved S-directed ductile extrusion. Structural trends of ductile D1 thrusts define a salient bounded to the east by a NE-trending transverse zone situated in the western margin of the Lefka Ori window. At the eastern limb of the salient, the trajectories of L1 stretching lineation formed on a gently dipping S1 foliation in the PQ unit, show a clockwise rotation with proximity to the transverse zone. This suggests that the latter acted as an oblique buttress against the southward extruding PQ unit rocks causing their lateral escape. D2 phase was governed by regional NNW to NNE compression and involved significant folding and out-of-sequence with respect to D1 thrusting. The early D2a phase is related to the brittle-stage of exhumation of the HP-units and spans from middle to upper Miocene. D2a deformation involved thrust-related folding, tectonic imbrication and the formation of a middle Miocene thrust-top basin. The F2a folds are characterized by a predominant S(SE)-vergence and show a pronounced curvature of their hinge orientations from a regional E-W to a local NE-SW trend, the latter only present at the eastern limb of the salient. In the transverse zone, combined forward-directed imbricate thrusting and backthrusting lead to the development of a major pop-up structure and a triangle zone. Moreover, the trend of compression axes at the salient's eastern limb are deflected from the regional NNE to NNW orientation to a local NW orientation perpendicular to the transverse zone. These findings suggest that the transverse zone should have served as an oblique ramp to the southward transport of HP-rocks, while the steep dip of the ramp may has impeded displacement of the PQ unit rocks up the ramp acting as a buttress to their foreland propagation. The late D2b phase lasted from upper Miocene to Pleistocene and involved SW-directed thrust-related folding with synchronous sinistral strike-slip faulting and NE-striking normal faulting causing extension parallel to F2b fold hinges. The D2b-related paleostress field is characterized by local NE compression and NW extension orientations defining a transpressive to pure extensive regime. Where these coexist, the normal faults related to tension cut all previous structures suggesting that the extension postdates compression. This could possibly be attributed to a relaxation of the NE compression, which progressively evolved to the NW extension. The described kinematic evolution of southern Hellenides in western Crete reveals that the NE-trending transverse zone, which is possibly aligned with an inherited rift-related Mesozoic fault system, exerted significant control on the deformation pattern at progressively shallower structural levels within the crust.

Metal carboxylates with open architectures.

PubMed

Rao, C N R; Natarajan, Srinivasan; Vaidhyanathan, R

2004-03-12

The field of inorganic open-framework materials is dominated by aluminosilicates and phosphates. The metal carboxylates have emerged as an important family in the last few years. This family includes not only mono- and dicarboxylates of transition, rare-earth, and main-group metals, but also a variety of hybrid structures. Some of the carboxylates possess novel adsorption and magnetic properties. Dicarboxylates and related species provide an effective means of designing novel hybrid structures with porous and other properties. In some of these structures, the dicarboxylate acts as a linker between two inorganic units. Hybrid nanocomposites are also of particular note, for example, cadmium oxalate host lattices that can accommodate extended alkali-metal halide structures. This Review discusses the synthesis, structure, and properties of various types of open-framework metal carboxylates.

Active faults of the Baikal depression

USGS Publications Warehouse

Levi, K.G.; Miroshnichenko, A.I.; San'kov, V. A.; Babushkin, S.M.; Larkin, G.V.; Badardinov, A.A.; Wong, H.K.; Colman, S.; Delvaux, D.

1997-01-01

The Baikal depression occupies a central position in the system of the basins of the Baikal Rift Zone and corresponds to the nucleus from which the continental lithosphere began to open. For different reasons, the internal structure of the Lake Baikal basin remained unknown for a long time. In this article, we present for the first time a synthesis of the data concerning the structure of the sedimentary section beneath Lake Baikal, which were obtained by complex seismic and structural investigations, conducted mainly from 1989 to 1992. We make a brief description of the most interesting seismic profiles which provide a rough idea of a sedimentary unit structure, present a detailed structural interpretation and show the relationship between active faults in the lake, heat flow anomalies and recent hydrothermalism.

Diagenetic gypsum related to sulfur deposits in evaporites (Libros Gypsum, Miocene, NE Spain)

NASA Astrophysics Data System (ADS)

Ortí, Federico; Rosell, Laura; Anadón, Pere

2010-07-01

The Libros Gypsum is the thickest evaporite unit of the Miocene infill of the Teruel Basin in NE Spain. During the deposition of this unit, intense bacterial sulfate-reducing (BSR) activity in the lake depocenter generated a native sulfur deposit. Diagenetic gypsum resulted from subsequent sulfur oxidation. The different processes involved in these transformations were first investigated by Anadón et al. (1992). The present paper is concerned with this diagenetic gypsum from the stratigraphic, petrographic, isotopic and genetic points of view. Diagenetic gypsum occurs mainly as continuous or discontinuous layers, individual levels or lenses, irregular masses, nodules and micronodules, and veins. Its main textures are coarse-crystalline anhedral and fine-grained (alabastrine), both of which can replace any former lithology (carbonate, gypsum, and sulfur). The following sequence of processes and mineral/textural transformations is deduced: primary gypsum deposition — BSR and biodiagenetic carbonate/H 2S production — growth of native sulfur — growth of diagenetic gypsum — partial recrystallization of the diagenetic gypsum textures. The gypsification of the native sulfur generated two types of banded structures in the diagenetic gypsum: (1) concentric structures of centripetal growth, and (2) expansive, roughly concentric structures. In the first type, the gypsification operated from the outer boundaries towards the inner parts. In the second type, part of the carbonate hosting the sulfur was also gypsified (replaced/cemented). In the diagenetic gypsum, the δ34S values are in agreement with a native sulfur and H 2S provenance. The δ18O sulfate values, however, enable us to differentiate two main groups of values: one with positive values and the other with negative values. In the group of positive values, interstitial (evaporated) solutions participated in the sulfur oxidation; this process presumably occurred in a first oxidation stage during shallow-to-deeper burial of the Libros Gypsum unit. In the group of negative values, however, only meteoric waters participated in the oxidation, which presumably occurred in a second oxidation stage during the final exhumation of the unit. A third group of values is characterized by very high sulfur and oxygen values, suggesting that BSR residual solutions also participated in the oxidation processes locally. During the two oxidation stages, both the textural characteristics and the isotopic composition of the diagenetic gypsum indicate that gypsification operated as a multistadic process.

Geology and habitat of oil in Ras Budran field, Gulf of Suez, Egypt

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chowdhary, L.R.; Taha, S.

1987-05-01

Deminex discovered the Ras Budran oil field in 1978. Discovery well EE 85-1 was drilled in about 140 ft of water, 4 km off the Sinai coast of the Gulf of Suez. Appraisal drilling (EE 85-2, 3, and 4 wells) confirmed the presence of a major field with an estimated 700 million bbl oil in place. The field, developed from three wellhead platforms, went on production in April 1983. To date, 20 development wells have been drilled. The Ras Budran structure at the deepest mappable seismic reflector, top Kareem (middle Miocene), is a broad northeast-southwest-trending anticlinal feature striking nearly atmore » right angles to the main Gulf of Suez trend. At pre-Miocene producing horizons, the structure is complex and consists of a northeast-dipping flank (14-15) broken into several blocks by faults and limited to the south and west by major bounding faults. Oil is produced from three units of Nubian sandstone at a depth of 11,000 to 12,000 ft. The lower unit of Paleozoic age averages 10% porosity and up to 200 md in -situ permeability. The wells completed in this unit produce up to 2000 BOPD. In contrast, the sands of the upper two units of Lower Cretaceous age have a 15-20% porosity and up to 700 md permeability. The wells completed in these units produce 6000-8000 BOPD. The Ras Budran structure was primarily formed during the intra-Rudeis tectonic phase (lower Miocene). Migration of oil for accumulation in Ras Budran started late in the upper Miocene or Pliocene when the Santonian Brown Limestone and the Eocene Thebes Formation, the main source beds in the Gulf, reached the threshold of oil generation at a burial depth of about 10,000 ft (3000 m). At these depths, the organic matter in the source beds have a transformation ratio (0.10 to 0.15), increased yields of C15 + soluble organic matter and C15 + saturated hydrocarbons, a vitrinite reflectance of 0.62%, and a TTI value of 15.« less

Boron environments in Pyrex® glass--a high resolution, Double-Rotation NMR and thermodynamic modelling study.

PubMed

Howes, A P; Vedishcheva, N M; Samoson, A; Hanna, J V; Smith, M E; Holland, D; Dupree, R

2011-07-07

It is shown, using the important technological glass Pyrex® as an example, that 1D and 2D (11)B Double-Rotation (DOR) NMR experiments, in combination with thermodynamic modelling, are able to provide unique structural information about complex glasses. (11)B DOR NMR has been applied to Pyrex® glass in order to remove both dipolar and quadrupolar broadening of the NMR lines, leading to high resolution spectra that allow unambiguous, accurate peak fitting to be carried out, of particular importance in the case of the 3-coordinated [BO(3)] (B3) trigonal planar environments. The data obtained are of sufficient quality that they can be used to test the distributions of borate and borosilicate superstructural units predicted by the thermodynamics-based Model of Associated Solutions. The model predicts the dominant boron-containing chemical groupings in Pyrex® glass to be those associated with B(2)O(3) and sodium tetraborate (with smaller amounts of sodium triborate, sodium diborate, sodium pentaborate, danburite and reedmergnerite). Excellent agreement is found between model and experiment provided the (11)B peaks with isotropic chemical shifts of -1.4 ppm and 0.5 ppm are assigned to B4 species from borosilicate units ([B(OSi)(4)] and [B(OSi)(3)(OB)]) and borate superstructural units (mainly triborate rings with some pentaborate and diborate) respectively. The peaks with isotropic shifts of 14 ppm and 18.1 ppm are then assigned to B3 in borate superstructural units (mainly triborate and pentaborate along with connecting B3) and boroxol rings respectively. The assignments of the DOR NMR peaks, are supported by the presence of cross-peaks in (11)B spin-diffusion DOR NMR spectra which can be used to develop a structural model in which B(2)O(3)-like regions are linked, via borate and borosilicate superstructural units, to the majority silica network. Pyrex® is thus shown to have a heterogeneous structure, with distinct molecular groupings that are far removed from a random distribution of network polyhedra with only short-range order. This journal is © the Owner Societies 2011

Gaseous Elemental Mercury and Total and Leached Mercury in Building Materials from the Former Hg-Mining Area of Abbadia San Salvatore (Central Italy).

PubMed

Vaselli, Orlando; Nisi, Barbara; Rappuoli, Daniele; Cabassi, Jacopo; Tassi, Franco

2017-04-15

Mercury has a strong environmental impact since both its organic and inorganic forms are toxic, and it represents a pollutant of global concern. Liquid Hg is highly volatile and can be released during natural and anthropogenic processes in the hydrosphere, biosphere and atmosphere. In this study, the distribution of Gaseous Elemental Mercury (GEM) and the total and leached mercury concentrations on paint, plaster, roof tiles, concrete, metals, dust and wood structures were determined in the main buildings and structures of the former Hg-mining area of Abbadia San Salvatore (Siena, Central Italy). The mining complex (divided into seven units) covers a surface of about 65 ha and contains mining structures and managers' and workers' buildings. Nine surveys of GEM measurements were carried out from July 2011 to August 2015 for the buildings and structures located in Units 2, 3 and 6, the latter being the area where liquid mercury was produced. Measurements were also performed in February, April, July, September and December 2016 in the edifices and mining structures of Unit 6. GEM concentrations showed a strong variability in time and space mostly depending on ambient temperature and the operational activities that were carried out in each building. The Unit 2 surveys carried out in the hotter period (from June to September) showed GEM concentrations up to 27,500 ng·m -3 , while in Unit 6, they were on average much higher, and occasionally, they saturated the GEM measurement device (>50,000 ng·m -3 ). Concentrations of total (in mg·kg -1 ) and leached (in μg·L -1 ) mercury measured in different building materials (up to 46,580 mg·kg -1 and 4470 mg·L -1 , respectively) were highly variable, being related to the edifice or mining structure from which they were collected. The results obtained in this study are of relevant interest for operational cleanings to be carried out during reclamation activities.

[Continuity and discontinuity of the geomerida: the bionomic and biotic aspects].

PubMed

Kafanov, A I

2005-01-01

The view of the spatial structure of the geomerida (Earth's life cover) as a continuum that prevails in modern phytocoenology is mostly determined by a physiognomic (landscape-bionomic) discrimination of vegetation components. In this connection, geography of life forms appears as subject of the landscapebionomic biogeography. In zoocoenology there is a tendency of synthesis of alternative concepts based on the assumption that there are no absolute continuum and absolute discontinuum in the organic nature. The problem of continuum and discontinuum of living cover being problem of scale aries from fractal structure of geomerida. This problem arises from fractal nature of the spatial structure of geomerida. The continuum mainly belongs to regularities of topological order. At regional and subregional scale the continuum of biochores is rather rare. The objective evidences of relative discontinuity of the living cover are determined by significant alterations of species diversity at the regional, subregional and even topological scale Alternatively to conventionally discriminated units in physionomically continuous vegetation, the same biotic complexes, represented as operational units of biogeographical and biocenological zoning, are distinguished repeatedly and independently by different researchers. An area occupied by certain flora (fauna, biota) could be considered as elementary unit of biotic diversity (elementary biotic complex).

A novel ultrasonic phased array inspection system to NDT for offshore platform structures

NASA Astrophysics Data System (ADS)

Wang, Hua; Shan, Baohua; Wang, Xin; Ou, Jinping

2007-01-01

A novel ultrasonic phased array detection system is developed for nondestructive testing (NDT). The purpose of the system is to make acquisition of data in real-time from 64-element ultrasonic phased array transducer, and to enable real- time processing of the acquired data. The system is composed of five main parts: master unit, main board, eight transmit/receive units, a 64-element transducer and an external PC. The system can be used with 64 element transducers, excite 32 elements, receive and sample echo signals form 32 elements simultaneously at 62.5MHz with 8 bit precision. The external PC is used as the user interface showing the real time images and controls overall operation of the system through USB serial link. The use of Universal Serial Bus (USB) improves the transform speed and reduces hardware interface complexity. The program of the system is written in Visual C++.NET and is platform independent.

Open-shell characters and second hyperpolarizabilities of one-dimensional graphene nanoflakes composed of trigonal graphene units.

PubMed

Yoneda, Kyohei; Nakano, Masayoshi; Fukui, Hitoshi; Minami, Takuya; Shigeta, Yasuteru; Kubo, Takashi; Botek, Edith; Champagne, Benoît

2011-06-20

The impact of topology on the open-shell characters and the second hyperpolarizabilities (γ) has been addressed for one-dimensional graphene nanoflakes (GNFs) composed of the smallest trigonal graphene (phenalenyl) units. The main results are: 1) These GNFs show not only diradical but also multiradical characters when increasing the number of linked units. 2) GNFs composed of an equivalent number of units can exhibit a wide range of open-shell characters-from nearly closed-shell to pure multiradical characters-depending on the linking pattern of the trigonal units. 3) This wide variation in open-shell characters is explained by their resonance structures and/or by their (HOMO-i)-(LUMO+i) gaps deduced from the orbital correlations. 4) The change in the linking structure of the units can effectively control their open-shell characters as well as their γ values, of which the longitudinal components are significantly enhanced for the singlet GNFs having intermediate open-shell characters. 5) Singlet alternately linked (AL) systems present intermediate multiradical characters even in the case of a large number of units, which creates a significant enhancement of γ with increasing the size, whereas nonalternately linked (NAL) systems, which present pure multiradical characters, possess much smaller γ values. Finally 6) by switching from the singlet to the highest spin states, the γ values of NAL systems hardly change, whereas those of AL systems exhibit large reductions. These fascinating structure-property relationships between the topology of the GNFs, their open-shell characters, and their γ values not only deepen the understanding of open-shell characters of GNFs but aim also at stimulating further design studies to achieve giant NLO responses based on open-shell graphene-like materials. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Validation of the Transient Structural Response of a Threaded Assembly: Phase I

DOE Office of Scientific and Technical Information (OSTI.GOV)

Doebling, Scott W.; Hemez, Francois M.; Robertson, Amy N.

2004-04-01

This report explores the application of model validation techniques in structural dynamics. The problem of interest is the propagation of an explosive-driven mechanical shock through a complex threaded joint. The study serves the purpose of assessing whether validating a large-size computational model is feasible, which unit experiments are required, and where the main sources of uncertainty reside. The results documented here are preliminary, and the analyses are exploratory in nature. The results obtained to date reveal several deficiencies of the analysis, to be rectified in future work.

Application of LANDSAT satellite imagery for iron ore prospecting in the Western Desert of Egypt

NASA Technical Reports Server (NTRS)

Elshazly, E. M.; Abdelhady, M. A.; Elghawaby, M. A.; Khawasik, S. M.

1977-01-01

Prospecting for iron ore occurrences was conducted by the Remote Sensing Center in Bahariya Oasis-El Faiyum area covering some 100,000 km squared in the Western Desert of Egypt. LANDSAT-1 satellite images were utilized as the main tool in the regional prospecting of the iron ores. The delineation of the geological units and geological structure through the interpretation of the images corroborated by field observations and structural analysis led to the discovery of new iron ore occurrences in the area of investigation.

Crystal structure of 1,3-bis­(1H-benzotriazol-1-yl­meth­yl)benzene

PubMed Central

Macías, Mario A.; Nuñez-Dallos, Nelson; Hurtado, John; Suescun, Leopoldo

2016-01-01

The mol­ecular structure of the title compound, C20H16N6, contains two benzotriazole units bonded to a benzene nucleus in a meta configuration, forming dihedral angles of 88.74 (11) and 85.83 (10)° with the central aromatic ring and 57.08 (9)° with each other. The three-dimensional structure is controlled mainly by weak C—H⋯N and C—H⋯π inter­actions. The mol­ecules are connected in inversion-related pairs, forming the slabs of infinite chains that run along the [-110] and [110] directions. PMID:27308049

Glycan analysis of Fonsecaea monophora from clinical and environmental origins reveals different structural profile and human antigenic response

PubMed Central

Burjack, Juliana R.; Santana-Filho, Arquimedes P.; Ruthes, Andrea C.; Riter, Daniel S.; Vicente, Vania A.; Alvarenga, Larissa M.; Sassaki, Guilherme L.

2014-01-01

Dematiaceous fungi constitute a large and heterogeneous group, characterized by having a dark pigment, the dihydroxynaftalen melanin—DHN, inside their cell walls. In nature they are found mainly as soil microbiota or decomposing organic matter, and are spread in tropical and subtropical regions. The fungus Fonsecaea monophora causes chromoblastomycosis in humans, and possesses essential mechanisms that may enhance pathogenicity, proliferation and dissemination inside the host. Glycoconjugates confer important properties to these pathogenic microorganisms. In this work, structural characterization of glycan structures present in two different strains of F. monophora MMHC82 and FE5p4, from clinical and environmental origins, respectively, was performed. Each one were grown on Minimal Medium (MM) and Czapeck-Dox (CD) medium, and the water soluble cell wall glycoconjugates and exopolysaccharides (EPS) were evaluated by NMR, methylation and principal component analysis (PCA). By combining the methylation and 2D NMR analyses, it was possible to visualize the glycosidic profiles of the complex carbohydrate mixtures. Significant differences were observed in β-D-Galf-(1→5) and (1→6) linkages, α- and β-D-Glcp-(1→3), (1→4), and (1→6) units, as well as in α-D-Manp. PCA from 1H-NMR data showed that MMHC82 from CD medium showed a higher variation in the cell wall carbohydrates, mainly related to O-2 substituted β-D-Galf (δ 106.0/5.23 and δ 105.3/5.23) units. In order to investigate the antigenic response of the glycoconjugates, these were screened against serum from chromoblastomycosis patients. The antigen which contained the cell wall of MMHC82 grown in MM had β-D-Manp units that promoted higher antigenic response. The distribution of these fungal species in nature and the knowledge of how cell wall polysaccharides and glycoconjugates structure vary, may contribute to the better understanding and the elucidation of the pathology caused by this fungus. PMID:25401093

Characterization of origami shape memory metamaterials (SMMM) made of bio-polymer blends

NASA Astrophysics Data System (ADS)

Kshad, Mohamed Ali E.; Naguib, Hani E.

2016-04-01

Shape memory materials (SMMs) are materials that can return to their virgin state and release mechanically induced strains by external stimuli. Shape memory polymers (SMPs) are a class of SMMs that show a high shape recoverability and which have attractive potential for structural applications. In this paper, we experimentally study the shape memory effect of origami based metamaterials. The main focus is on the Muira origami metamaterials. The fabrication technique used to produce origami structure is direct molding where all the geometrical features are molded from thermally virgin polymers without post folding of flat sheets. The study shows experimental investigations of shape memory metamaterials (SMMMs) made of SMPs that can be used in different applications such as medicine, robotics, and lightweight structures. The origami structure made from SMP blends, activated with uniform heating. The effect of blend composition on the shape memory behavior was studied. Also the influence of the thermomechanical and the viscoelastic properties of origami unit cell on the activation process have been discussed, and stress relaxation and shape recovery were investigated. Activation process of the unit cell has been demonstrated.

Lignin Composition and Structure Differs between Xylem, Phloem and Phellem in Quercus suber L.

PubMed Central

Lourenço, Ana; Rencoret, Jorge; Chemetova, Catarina; Gominho, Jorge; Gutiérrez, Ana; del Río, José C.; Pereira, Helena

2016-01-01

The composition and structure of lignin in different tissues—phellem (cork), phloem and xylem (wood)—of Quercus suber was studied. Whole cell walls and their respective isolated milled lignins were analyzed by pyrolysis coupled with gas chromatography/mass spectrometry (Py-GC/MS), two-dimensional nuclear magnetic resonance spectroscopy (2D-NMR) and derivatization followed by reductive cleavage (DFRC). Different tissues presented varied p-hydroxyphenyl:guaiacyl:syringyl (H:G:S) lignin compositions. Whereas lignin from cork has a G-rich lignin (H:G:S molar ratio 2:85:13), lignin from phloem presents more S-units (H:G:S molar ratio of 1:58:41) and lignin from xylem is slightly enriched in S-lignin (H:G:S molar ratio 1:45:55). These differences were reflected in the relative abundances of the different interunit linkages. Alkyl-aryl ethers (β–O–4′) were predominant, increasing from 68% in cork, to 71% in phloem and 77% in xylem, as consequence of the enrichment in S-lignin units. Cork lignin was enriched in condensed structures such as phenylcoumarans (β-5′, 20%), dibenzodioxocins (5–5′, 5%), as corresponds to a lignin enriched in G-units. In comparison, lignin from phloem and xylem presented lower levels of condensed linkages. The lignin from cork was highly acetylated at the γ-OH of the side-chain (48% lignin acetylation), predominantly over G-units; while the lignins from phloem and xylem were barely acetylated and this occurred mainly over S-units. These results are a first time overview of the lignin structure in xylem, phloem (generated by cambium), and in cork (generated by phellogen), in agreement with literature that reports that lignin biosynthesis is flexible and cell specific. PMID:27833631

Texture segmentation: do the processing units on the saliency map increase with eccentricity?

PubMed

Schade, Ursula; Meinecke, Cristina

2011-01-01

The saliency map is a computational model and has been constructed for simulating human saliency processing, e.g. pop-out target detection (e.g. Itti & Koch, 2000). In this study the spatial structure on the saliency map was investigated. It is proposed that the saliency map is structured into processing units whose size is increasing with retinal eccentricity. In two experiments the distance between a target in the stimulus and an irrelevant structure in the mask was varied systematically. Our findings had two main points. Firstly, in texture segmentation tasks the saliency signals from two texture irregularities interfere, when these irregularities appear within a critical spatial distance. Second, the critical distances increase with target eccentricity. The eccentricity-dependent critical distances can be interpreted as crowding effects. It is assumed that additionally to the target eccentricity, also the strength of a saliency signal can determine the spatial area of its impairing influence. Copyright © 2010 Elsevier Ltd. All rights reserved.

An investigation on wireless sensors for asset management and health monitoring of civil structures

NASA Astrophysics Data System (ADS)

Furkan, Mustafa; Mao, Qiang; Mazzotti, Matteo; DeVitis, John; Sumitro, S. Paul; Faridazar, Fred; Aktan, A. Emin; Moon, Franklin; Bartoli, Ivan

2016-04-01

Application of wireless sensors and sensor networks for Structural Health Monitoring has been investigated for a long time. Key limitations for practical use are energy requirements, connectivity, and integration with existing systems. Current sensors and sensor networks mainly rely on wired connectivity for communication and external power source for energy. This paper presents a suite of wireless sensors that are low-cost, maintenance free, rugged, and have long service life. The majority of the sensors considered were designed by transforming existing, proven, and robust wired sensors into wireless units. In this study, the wireless sensors were tested in laboratory conditions for calibration and evaluation along with wired sensors. The experimental results were also compared to theoretical results. The tests mostly show satisfactory performance of the wireless units. This work is part of a broader Federal Highway Administration sponsored project intended to ultimately validate a wireless sensing system on a real, operating structure to account for all the uncertainties, environmental conditions and operational variability that are encountered in the field.

Sea Cucumber Glycosides: Chemical Structures, Producing Species and Important Biological Properties

PubMed Central

Mondol, Muhammad Abdul Mojid; Shin, Hee Jae; Rahman, M. Aminur; Islam, Mohamad Tofazzal

2017-01-01

Sea cucumbers belonging to echinoderm are traditionally used as tonic food in China and other Asian countries. They produce abundant biologically active triterpene glycosides. More than 300 triterpene glycosides have been isolated and characterized from various species of sea cucumbers, which are classified as holostane and nonholostane depending on the presence or absence of a specific structural unit γ(18,20)-lactone in the aglycone. Triterpene glycosides contain a carbohydrate chain up to six monosaccharide units mainly consisting of d-xylose, 3-O-methy-d-xylose, d-glucose, 3-O-methyl-d-glucose, and d-quinovose. Cytotoxicity is the common biological property of triterpene glycosides isolated from sea cucumbers. Besides cytotoxicity, triterpene glycosides also exhibit antifungal, antiviral and hemolytic activities. This review updates and summarizes our understanding on diverse chemical structures of triterpene glycosides from various species of sea cucumbers and their important biological activities. Mechanisms of action and structural–activity relationships (SARs) of sea cucumber glycosides are also discussed briefly. PMID:29039760

Crystallization and preliminary crystallographic investigation of a low-pH native insulin monomer with flexible behaviour.

PubMed

Zhang, Youshang; Whittingham, Jean L; Turkenburg, Johan P; Dodson, Eleanor J; Brange, Jens; Dodson, G Guy

2002-01-01

Insulin naturally aggregates as dimers and hexamers, whose structures have been extensively analysed by X-ray crystallography. Structural determination of the physiologically relevant insulin monomer, however, is an unusual challenge owing to the difficulty in finding solution conditions in which the concentration of insulin is high enough for crystallization yet the molecule remains monomeric. By utilizing solution conditions known to inhibit insulin assembly, namely 20% acetic acid, crystals of insulin in the monomeric state have been obtained. The crystals are strongly diffracting and a data set extending to 1.6 A has recently been collected. The crystals nominally belong to the space group I422, with unit-cell parameters a = b = 57.80, c = 54.61 A, giving rise to one molecule in the asymmetric unit. Preliminary electron-density maps show that whilst most of the insulin monomer is well ordered and similar in conformation to other insulin structures, parts of the B-chain C-terminus main chain adopt more than one conformation.

[Profile of public dental care for children and adolescents in São Luís, Maranhão State].

PubMed

Batista da Silva, Mariana Carvalho; da Silva, Raimundo Antônio; Costa Ribeiro, Cecília Cláudia; Nogueira da Cruz, Maria Carmem Fontoura

2007-01-01

This profile of public dental care for children/adolescents in São Luís, Maranhão State, Brazil, is based on a survey conducted through interviews, designed to identify these services and help upgrade Health Services available in this city. It describes the pediatric dental care available and the age groups attended, the qualifications of the practitioners involved, the types of treatment for primary and permanent teeth and oral health education programs run at the Municipal Healthcare Units with dental facilities, analyzed through visits and structured interviews. The findings show that dental care was available for children/adolescents (mainly between 6 and 12 years old) at 91.1% of the Healthcare Units offering daily and universal care (65.75%), as well as at those whose services are limited to certain specialties and/or specific days (34.15%). All the public Healthcare Units offered surgical treatment for permanent teeth. Fillings are used more for permanent teeth than primary teeth. Among the public Healthcare Units, 25 (55.5%) did not offer or run oral health programs. At most (75.5%) of the Units visited, dental treatment for children and adolescents is limited to basic care and directed mainly to permanent teeth. The traditional welfare model of providing care as freely demanded remains in place.

[Alcohol-related mortality in the assessments of hospital unit physicians and pathologists: analysis of accounting medical documents].

PubMed

Solov'ev, A G; Viaz'min, A M; Mordovskiĭ, É A; Krasil'nikov, S V

2014-01-01

To make a comparative analysis of the data available in the accounting medical documents drawn up at a multidisciplinary hospital on the level and structure of alcohol-related mortality (ARM) and to evaluate the efficiency of its accounting. Accounting medical documents, such as 453 inpatient cards (Form 003/y), 453 postmortem protocols (cards) (Form 013/H-80), and 453 death certificates (Form 106/y-08), were chosen as the basis for the study. The data of the final clinical and postmortem diagnoses in the patients who had died at hospital and their primary cause of death were comparatively analyzed. According to Form 003/y, ARM was 5.5%; the detection rate of alcohol-related disease (ARD) was 11% (95% confidence interval (CI), 8.3 to 14.3%); according to Form 013/H-80, ARM was 7.1% (95% CI, 4.9 to 9.8%) and the detection rate of ARD was 12.6% (95% CI, 9.7 to 16%). The consistency of the diagnoses of ARD as a main cause of death, made by hospital unit physicians and pathologists, is estimated as the mean--the Cohen's kappa coefficient (kappa) is 0.570) (p < 0.001). The results of the investigation suggest that there are 3 types of ARM, which differ in its level and structure: ARM in the assessments of hospital unit physicians; that in the assessments of pathologists, and that according to the death certificates drawn up. The consistency index for the diagnosis of ARD as a main cause of death indicates that the hospital unit physicians only determine the etiology of alcohol-related cause of death, without identifying it specifically.

Used Oil and Its Regulation in the United States

DTIC Science & Technology

1988-09-30

product containing significant quantities of alkyl, naphthenic , and aromatic hydrocarbons. The oil may also contain additives to improve its...delivered to the re-refiners each year is disposed of primarily in the process residues including spent clay, acid sludge, and wastewater.13 8 13 7 Frank...hydrocarbon structure into three main groups: parafinic, naphthenic , and aromatic. Paraffinic (alkanic) crude oils contain mostly saturated straight and

[Organizational wellbeing in the health sector: the Piemonte Region experience].

PubMed

Converso, Daniela; Baratti, Alberto

2010-01-01

In 2007, the Health Councillorship of the Piedmont region announced, in convention with the Psychology Department of the University of Turin, of the creation of "Workgroup for Safeguard of Organizational Wellbeing" composed by psychologists, occupational doctors, and superintendents for Prevention and Protection services. This group is aimed at promoting pilot experiences in the Health Units in order to prevent and combat psychosocial discomfort and to sustain workers' wellbeing. A complex intervention started in January 2009 and involved the personnel from Services for the Organization and Development of Human Resources, Personnel Services, Services for Occupational Medicine, Services of Communication, Quality Services, belonging to all of the Health Units from Piedmont, and of some structures operating within the national health service, for a total of 23 work groups. Based on the results produced and/or from the shared reflections in the classroom between the 23 groups, four main themes were singled out, corresponding to different levels and fields of interventions, in order to favour the contrast of psychosocial distress and to promote a culture of wellbeing, were adopted taking into account needs and cultural specificity of different Units' realities. The activities embarked on, inside every main theme represent, in the expectations of all the participants, good practices that could be spread to the different Local Health Units.

Design and fabrication of advanced materials from Illinois coal wastes. Quarterly report, 1 March 1995--31 May 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Malhotra, V.M.; Wright, M.A.

1995-12-31

The main goal of this project is to develop a bench-scale procedure to design and fabricate advanced brake and structural composite materials from Illinois coal combustion residues. Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), differential thermal analysis (DTA), and transmission-Fourier transform infrared (FTIR) were conducted on PCC fly ash (Baldwin), FBC fly ash (ADM unit1-6), FBC fly ash (S.I. coal), FBC spent bed ash (ADM unit1-6), bottom ash, and scrubber sludge (CWLP) residues to characterize their geometrical shapes, mineral phases, and thermal stability. Our spectroscopic results indicate that the scrubber sludge is mainly composed of a gypsum-like phase whosemore » lattice structure is different from the lattice structure of conventional gypsum, and sludge does not contain hannebachite (CaSO{sub 3}0.5H{sub 2}O) phase. In the second and third quarters the focus of research has been on developing protocols for the formation of advanced brake composites and structural composites. Our attempts to fabricate brake frictional shoes, in the form of 1.25 inch disks, from PCC fly ash, FBC spent bed ash, scrubber sludge, coal char, iron particles, and coal tar were successful. Based on the experience gained and microscopic analyses, we have now upscaled our procedures to fabricate 2.5 inch diameter disks from coal combustion residues. The SEM and Young`s modulus analyses of brake composites fabricated at 400 psi < Pressure < 2200 psi suggest pressure has a strong influence on the particle packing and the filling of interstices in our composites.« less

Structural styles and zircon ages of the South Tianshan accretionary complex, Atbashi Ridge, Kyrgyzstan: Insights for the anatomy of ocean plate stratigraphy and accretionary processes

NASA Astrophysics Data System (ADS)

Sang, Miao; Xiao, Wenjiao; Orozbaev, Rustam; Bakirov, Apas; Sakiev, Kadyrbek; Pak, Nikolay; Ivleva, Elena; Zhou, Kefa; Ao, Songjian; Qiao, Qingqing; Zhang, Zhixin

2018-03-01

The anatomy of an ancient accretionary complex has a significance for a better understanding of the tectonic processes of accretionary orogens and complex because of its complicated compositions and strong deformation. With a thorough structural and geochronological study of a fossil accretionary complex in the Atbashi Ridge, South Tianshan (Kyrgyzstan), we analyze the structure and architecture of ocean plate stratigraphy in the western Central Asian Orogenic Belt. The architecture of the Atbashi accretionary complex is subdivisible into four lithotectonic assemblages, some of which are mélanges with "block-in-matrix" structure: (1) North Ophiolitic Mélange; (2) High-pressure (HP)/Ultra-high-pressure (UHP) Metamorphic Assemblage; (3) Coherent & Mélange Assemblage; and (4) South Ophiolitic Mélange. Relationships between main units are tectonic contacts presented by faults. The major structures and lithostratigraphy of these units are thrust-fold nappes, thrusted duplexes, and imbricated ocean plate stratigraphy. All these rock units are complicatedly stacked in 3-D with the HP/UHP rocks being obliquely southwestward extruded. Detrital zircon ages of meta-sediments provide robust constraints on their provenance from the Ili-Central Tianshan Arc. The isotopic ages of the youngest components of the four units are Late Permian, Early-Middle Triassic, Early Carboniferous, and Early Triassic, respectively. We present a new tectonic model of the South Tianshan; a general northward subduction polarity led to final closure of the South Tianshan Ocean in the End-Permian to Late Triassic. These results help to resolve the long-standing controversy regarding the subduction polarity and the timing of the final closure of the South Tianshan Ocean. Finally, our work sheds lights on the use of ocean plate stratigraphy in the analysis of the tectonic evolution of accretionary orogens.

Physics Goals for the Planned Next Linear Collider Engineering Test Facility

NASA Astrophysics Data System (ADS)

Raubenheimer, T. O.

2001-10-01

The Next Linear Collider (NLC) Collaboration is planning to construct an Engineering Test Facility (ETF) at Fermilab. As presently envisioned, the ETF would comprise a fundamental unit of the NLC main linac to include X-band klystrons and modulators, a delay-line power-distribution system (DLDS), and NLC accelerating structures that serve as loads. The principal purpose of the ETF is to validate stable operation of the power-distribution system, first without beam, then with a beam having the NLC pulse structure. This paper concerns the possibility of configuring and using the ETF to accelerate beam with an NLC pulse structure, as well as of doing experiments to measure beam-induced wakefields in the rf structures and their influence back on the beam.

DNA-lipid complexes: stability of honeycomb-like and spaghetti-like structures.

PubMed Central

May, S; Ben-Shaul, A

1997-01-01

A molecular level theory is presented for the thermodynamic stability of two (similar) types of structural complexes formed by (either single strand or supercoiled) DNA and cationic liposomes, both involving a monolayer-coated DNA as the central structural unit. In the "spaghetti" complex the central unit is surrounded by another, oppositely curved, monolayer, thus forming a bilayer mantle. The "honeycomb" complex is a bundle of hexagonally packed DNA-monolayer units. The formation free energy of these complexes, starting from a planar cationic/neutral lipid bilayer and bare DNA, is expressed as a sum of electrostatic, bending, mixing, and (for the honeycomb) chain frustration contributions. The electrostatic free energy is calculated using the Poisson-Boltzmann equation. The bending energy of the mixed lipid layers is treated in the quadratic curvature approximation with composition-dependent bending rigidity and spontaneous curvature. Ideal lipid mixing is assumed within each lipid monolayer. We found that the most stable monolayer-coated DNA units are formed when the charged/neutral lipid composition corresponds (nearly) to charge neutralization; the optimal monolayer radius corresponds to close DNA-monolayer contact. These conclusions are also valid for the honeycomb complex, as the chain frustration energy is found to be negligible. Typically, the stabilization energies for these structures are on the order of 1 k(B)T/A of DNA length, reflecting mainly the balance between the electrostatic and bending energies. The spaghetti complexes are less stable due to the additional bending energy of the external monolayer. A thermodynamic analysis is presented for calculating the equilibrium lipid compositions when the complexes coexist with excess bilayer. PMID:9370436

Supramolecular structure formation of Langmuir-Blodgett films of comblike precursor and polyimide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goloudina, S. I., E-mail: goloudina@mail.ru; Luchinin, V. V.; Rozanov, V. V.

2013-03-15

The surface structure of Langmuir-Blodgett films of a comblike polyimide precursor-a rigid-chain polyamic acid alkylamine salt bearing multichains of tertiary amine-and films of the corresponding polyimide were studied by atomic force microscopy (AFM). An analysis of the images of the surface of three-layer films revealed a domain structure. It was found that the Langmuir-Blodgett film formation of the precursor occurs as a result of the layer-by-layer deposition of two-dimensional domains (composed of polyamic acid salt molecules on the water surface) onto a substrate. The formation of domains in a monolayer is associated with the chemical structure of the precursor, tomore » be more precise, with the rigidity of the main chain and the presence of closely spaced aliphatic side chains in the polymer chain, whose total cross-section area is close to the surface area of the projection onto the plane of the repeating unit of the main chain. Polyimide films inherit the domain structure of the precursor films; the inhomogeneity of the film thickness substantially decreases, whereas the domain size and character of their distribution in the film remain unchanged.« less

Stratigraphic and structural relationships between Meso-Cenozoic Lagonegro basin and coeval carbonate platforms in southern Apennines, Italy

NASA Astrophysics Data System (ADS)

Pescatore, Tullio; Renda, Pietro; Schiattarella, Marcello; Tramutoli, Mariano

1999-12-01

Stratigraphic studies and facies analysis integrated with a new geological and structural survey of the Meso-Cenozoic units outcropping in the Campania-Lucania Apennines, southern Italy, allowed us to restore the palaeogeographic pattern and the tectonic evolution of the chain during Oligo-Miocene times. The southern Apennines are a N150°-striking and NE-verging fold-and-thrust belt mainly derived from the deformation of the African-Apulian passive margin. Four wide belts with different features have been recognized in the chain area. From east to west the following units outcrop: (a) successions characterized by basinal to marginal facies, ranging in age from Cretaceous to Miocene, tectonically lying on Plio-Pleistocene foredeep deposits; (b) successions characterized by shallow-water, basinal and shelf-margin facies, ranging in age from middle Triassic to Miocene ('Lagonegro units'), overthrust on the previous ones; (c) Triassic to Miocene carbonate platform successions ('Apenninic platform units'), overthrust on the Lagonegro units; (d) Jurassic-Cretaceous to Miocene deep-water successions (ophiolite-bearing or 'internal' units and associated siliciclastic wedges), outcropping along the Tyrrhenian belt and the Calabria-Lucania boundary, overthrust on the Apenninic platform units. All these units tectonically lie on the buried Apulian platform which is covered, at least in the eastern sector of the chain, by Pliocene to Pleistocene foredeep deposits. Stratigraphic patterns of the Cretaceous to lower Miocene Lagonegro successions are coherent with the platform margin ones. Calcareous clastics of the Lagonegro basin are in fact supplied by an adjacent western platform, as inferred by several sedimentological evidences (slump and palaeocurrent directions and decreasing grain size towards the depocentre of the basin). Tectonic relationships among the different units of the chain — with particular emphasis on the Lagonegro and Apenninic platform units of the Lucanian segment — are shown by means of both regional and detailed geological cross-sections. The Lagonegro units constantly underlie the carbonate units originating from detachment and thrusting of the western platform and overlie the eastern (i.e. Apulian) platform. The Lagonegro units show a strong lateral variability of map-scale structures. Dome-and-basin folds are in fact largely observable in the Lucanian Apennine. Further, the belt is widely affected by Plio-Quaternary strike-slip and extensional faults. Yet, excluding the brittle deformation due to Quaternary faulting, the complexity of structural styles seems to result from the Neogene refolding of more ancient structures produced by Oligo-Miocene intraplate deformation. This hypothesis is supported by two independent lines of evidence: the first is the recognition of unconformities between the lower Miocene Numidian sandstone and the underlying Lagonegro successions, at least in the southwestern sectors; the second is that the internal (i.e. western) platform remains undeformed until the early Miocene. Both stratigraphic and structural data suggest an external position of the Meso-Cenozoic Lagonegro basin with regard to the coeval Apenninic platform.

Uplift Sequence of the Main Morphoestructural Units of the South Central Andes at 30°S: Insights from a Multidisciplinary Approach

NASA Astrophysics Data System (ADS)

Lossada, A. C.; Mardónez, D.; Suriano, J.; Hoke, G. D.; Fitzgerald, P. G.; Mahoney, J. B.; Giambiagi, L.; Aragon, E.

2015-12-01

The South Central Andes at 30°S represent a key area to understand the Andes geodynamics as it corresponds to the flat slab segment, characterized by a subhorizontal subduction angle, absence of Neogene magmatism and a highly compressive tectonic regime. Under these settings, crustal shortening is believed to be the principal mechanism responsible for the rise of the Andes. However, the sequence of uplift of the different morphoestructural units composing the orogen is not fully understood; neither do the location and time of activity of intracrustal detachments and their connection with shallower structures. We attempt to develop a multidisciplinary analysis that allow us to characterize the timing, magnitude and activity of the principal structures involved in the construction of the Andes at 30°S trough the Coastal Range, the Frontal Cordillera and the Precordillera. The main phase of deformation in the Coastal Range occurred between 60 and 40Ma, based on published thermochronological and structural data. Our structural analyses constrain the Frontal Cordillera uplift between 18 and 13Ma. In the Precordillera area, in turn, we carried out structural, sedimentological and U-Pb provenience studies. Provenience studies and the 12 and 9Ma ages obtained for the youngest zircons indicated that the main thrusts uplifting the western sector of the Precordillera thrust system were activated since 13Ma at this latitude, and not before that time as it was previously suggested. In order to better constrain the exhumation and thermal history of Frontal Cordillera, a thermochronological study is being conducted. Twenty samples for apatite fission tracks (AFT) and apatite (U-Th)/He (AHe) were collected from two vertical profiles located at western sector (Guanta granitoid) and eastern sector (Colanguil granitoid) of the Frontal Cordillera system. Samples are currently being processed, and they are partially reseted, which will allow us to obtain a cooling age. The aim is to combine this new thermochronologic data with field observations of the geological structures and kinematic analysis of the principal features, and develop an exhumation/uplift model for the Frontal Cordillera at 30°S, which will improve our understanding of the structural evolution of this area.

Sedimentary and tectonic evolution of Plio Pleistocene alluvial and lacustrine deposits of Fucino Basin (central Italy)

NASA Astrophysics Data System (ADS)

Cavinato, Gian Paolo; Carusi, Claudio; Dall'Asta, Massimo; Miccadei, Enrico; Piacentini, Tommaso

2002-04-01

The Fucino Basin was the greatest lake of the central Italy, which was completely drained at the end of 19th century. The basin is an intramontane half-graben filled by Plio-Quaternary alluvial and lacustrine deposits located in the central part of the Apennines chain, which was formed in Upper Pliocene and in Quaternary time by the extensional tectonic activity. The analysis of the geological surface data allows the definition of several stratigraphic units grouped in Lower Units and Upper Units. The Lower Units (Upper Pliocene) are exposed along the northern and north-eastern basin margins. They consist of open to marginal lacustrine deposits, breccia deposits and fluvial deposits. The Upper Units (Lower Pliocene-Holocene) consist of interbedded marginal lacustrine deposits and fluvial deposits; thick coarse-grained fan-delta deposits are interfingered at the foot of the main relief with fluvial-lacustrine deposits. Most of the thickness of the lacustrine sequences (more than 1000-m thick) is buried below the central part of the Fucino Plain. The basin is bounded by E-W, WSW-ENE and NW-SE fault systems: Velino-Magnola Fault (E-W) and Tremonti-Celano-Aielli Fault (WSW-ENE) and S. Potito-Celano Fault (NW-SE) in the north; the Trasacco Fault, the Pescina-Celano Fault and the Serrone Fault (NW-SE) in the south-east. The geometry and kinematic indicators of these faults indicate normal or oblique movements. The study of industrial seismic profiles across the Fucino Basin gives a clear picture of the subsurface basin geometry; the basin shows triangular-shaped basin-fill geometry, with the maximum deposits thickness toward the main east boundary fault zones that dip south-westward (Serrone Fault, Trasacco Fault, Pescina-Celano Fault). On the basis of geological surface data, borehole stratigraphy and seismic data analysis, it is possible to recognize and to correlate sedimentary and seismic facies. The bottom of the basin is well recognized in the seismic lines available from the good and continuous signals of the top of Meso-Cenozoic carbonate rocks. The shape of sedimentary bodies indicates that the filling of the basin was mainly controlled by normal slip along the NW-SE boundary faults. In fact, the continental deposits are frequently in on-lap contact over the carbonate substratum; several disconformable contacts occurred during the sedimentary evolution of the basin. The main faults (with antithetic and synthetic fault planes) displace the whole sedimentary sequence up to the surface indicating a recent faults' activity (1915 Avezzano earthquake, Ms=7.0). The stratigraphic and tectonic setting of the Fucino Basin and neighboring areas indicates that the extensional tectonic events have had an important role in driving the structural-sedimentary evolution of the Plio-Quaternary deposits. The geometry of the depositional bodies, of the fault planes and their relationships indicate that the Fucino Basin was formed as a half-graben type structure during Plio-Quaternary extensional events. Some internal complexities are probably related to the fold-and-thrust structures of the Apenninic orogeny formed in Messinian time, in this area, and to a different activity timing of the E-W and WSW-ENE fault systems and the NW-SE fault systems. We believe, based on the similarity of the surface characteristics, that the structural setting of the Fucino Basin can be extrapolated to the other great intramontane basins in Central Italy (e.g. Rieti, L'Aquila, Sulmona, Sora, Isernia basins).

The Internal Medicine of the 21st century: Organizational and operational standards.

PubMed

Casariego-Vales, E; Zapatero-Gaviria, A; Elola-Somoza, F J

2017-12-01

The Spanish Society of Internal Medicine has developed a consensus document on the standards and recommendations that they consider essential to the organisation of internal medicine units for conducting their activities efficiently and with high quality. We defined 3 groups of key processes: the care of acutely ill adult patients, the comprehensive care of complex chronic patients and the examination of a patient with a difficult diagnosis and no organ-specific disease. As support processes, we identified the structure and operation of the Internal Medicine units. As strategic processes, we identified training and research. The main subprocesses are structured below, and we established the standards and recommendations for each of them. Lastly, we proposed resulting workloads. The prepared standards must be reviewed within a maximum of 4 years. Copyright © 2017 Elsevier España, S.L.U. and Sociedad Española de Medicina Interna (SEMI). All rights reserved.

A method for real-time implementation of HOG feature extraction

NASA Astrophysics Data System (ADS)

Luo, Hai-bo; Yu, Xin-rong; Liu, Hong-mei; Ding, Qing-hai

2011-08-01

Histogram of oriented gradient (HOG) is an efficient feature extraction scheme, and HOG descriptors are feature descriptors which is widely used in computer vision and image processing for the purpose of biometrics, target tracking, automatic target detection(ATD) and automatic target recognition(ATR) etc. However, computation of HOG feature extraction is unsuitable for hardware implementation since it includes complicated operations. In this paper, the optimal design method and theory frame for real-time HOG feature extraction based on FPGA were proposed. The main principle is as follows: firstly, the parallel gradient computing unit circuit based on parallel pipeline structure was designed. Secondly, the calculation of arctangent and square root operation was simplified. Finally, a histogram generator based on parallel pipeline structure was designed to calculate the histogram of each sub-region. Experimental results showed that the HOG extraction can be implemented in a pixel period by these computing units.

β-K3Fe(MoO4)2Mo2O7

PubMed Central

Souilem, Amira; Zid, Mohamed Faouzi; Driss, Ahmed

2014-01-01

The title compound, tripotassium iron(III) bis­(ortho­molyb­date) dimolybdate, was obtained by a solid-state reaction. The main structural building units are one FeO6 octa­hedron, two MoO4 tetra­hedra and one Mo2O7 dimolybdate group, all with point group symmetries m. These units are linked via corner-sharing to form ribbons parallel to [010]. The three K+ cations are located between the ribbons on mirror planes and have coordination numbers of 10 and 12. Two O atoms of one of the MoO4 tetra­hedra of the dimolybdate group are disordered over two positions in a 0.524 (11):0.476 (11) ratio. The structure of the title compound is compared briefly with that of Rb3FeMo4O15. PMID:25161509

Structural Aspects LiNbO3 Nanoparticles and Their Ferromagnetic Properties

PubMed Central

Diaz-Moreno, Carlos A.; Farias-Mancilla, Rurik; Elizalde-Galindo, Jose T.; González-Hernández, Jesus; Hurtado-Macias, Abel; Bahena, Daniel; José-Yacamán, Miguel; Ramos, Manuel

2014-01-01

We present a solid-state synthesis of ferromagnetic lithium niobate nanoparticles (LiNbO3) and their corresponding structural aspects. In order to investigate the effect of heat treatments, two batches of samples with a heat-treated (HT) and non-heat-treated (nHT) reduction at 650 °C in 5% of hydrogen/argon were considered to investigate the multiferroic properties and their corresponding structural aspects; using magnetometry and scanning transmission electron microscopy (STEM). Results indicate the existence of ferromagnetic domains with a magnetic moment per unit cell of 5.24 × 10−3 μB; caused mainly due to voids and defects on the nanoparticle surface, as confirmed by STEM measurements. PMID:28788242

Les amas sulfurés du massif miocène d'El Aouana (Algérie)— I. Dynamisme de mise en place des roches volcaniques et implications métallogéniques

NASA Astrophysics Data System (ADS)

Villemaire, Cl.

Two main units have been distinguished in the Miocene El Aouana area. A tectonic event occurs between their respective deposits inducing faulting, tilting of the lower volcanic unit and caldeira structure. The lower unit comprises first continental air fall pyroclastic rocks and dacitic flows, then marine flow pyroclastic rocks, dacitic flows and epiclastic rocks. The upper volcanic unit, announced by extensive andesitic flows, is characterized by pyroclastic flow sheets. The two units are intruded by dacitic domes. These volcanic rocks belong to the calco-alcaline succession, with well-expressed acidic terms. The ore deposits are formed by lenses, stockworks and lodes. They are massive sulphides ore type. Mineralizations are strictly localized at the contact boundary between dacitic intrusive rocks and marine pyroclastic flows and epiclastic rocks. We suggest that the systematic research of dacitic domes would be successful to increase the mining reserves of this area.

Mechanism for controlling the monomer-dimer conversion of SARS coronavirus main protease.

PubMed

Wu, Cheng Guo; Cheng, Shu Chun; Chen, Shiang Chuan; Li, Juo Yan; Fang, Yi Hsuan; Chen, Yau Hung; Chou, Chi Yuan

2013-05-01

The Severe acute respiratory syndrome coronavirus (SARS-CoV) main protease (M(pro)) cleaves two virion polyproteins (pp1a and pp1ab); this essential process represents an attractive target for the development of anti-SARS drugs. The functional unit of M(pro) is a homodimer and each subunit contains a His41/Cys145 catalytic dyad. Large amounts of biochemical and structural information are available on M(pro); nevertheless, the mechanism by which monomeric M(pro) is converted into a dimer during maturation still remains poorly understood. Previous studies have suggested that a C-terminal residue, Arg298, interacts with Ser123 of the other monomer in the dimer, and mutation of Arg298 results in a monomeric structure with a collapsed substrate-binding pocket. Interestingly, the R298A mutant of M(pro) shows a reversible substrate-induced dimerization that is essential for catalysis. Here, the conformational change that occurs during substrate-induced dimerization is delineated by X-ray crystallography. A dimer with a mutual orientation of the monomers that differs from that of the wild-type protease is present in the asymmetric unit. The presence of a complete substrate-binding pocket and oxyanion hole in both protomers suggests that they are both catalytically active, while the two domain IIIs show minor reorganization. This structural information offers valuable insights into the molecular mechanism associated with substrate-induced dimerization and has important implications with respect to the maturation of the enzyme.

A novel trigger for pseudospark switch with high repetition rate, low jitter, and compact structure

NASA Astrophysics Data System (ADS)

Yan, Jiaqi; Shen, Saikang; Wang, Yanan; Zhang, Siyu; Cheng, Le; Ding, Weidong

2018-06-01

This paper presents the design and development of a trigger with a high repetition rate, low jitter, and compact structure for the pseudospark switch (PSS), which includes an improved Marx generator based on avalanche transistors and a corona-plasma trigger unit. The generator adopted a novel 3 × 12-stage Marx circuit based on avalanche transistors in which the failure rate of transistors in the first and second stages was significantly reduced by connecting the parallel capacitors compared to the previous similar generator. The reason for the improved performance was also discussed. The main parameters of output pulses were an amplitude of -7 kV, rise time of 6 ns, jitter of 0.2 ns, and repetition rate of 2 kHz. The corona-plasma trigger unit adopted BaTiO3 ceramics with high ɛr as the dielectric and was arranged in the hollow cathode of the PSS. The experiments of triggering a PSS prototype were conducted. The influence of anode voltage and pressure on the trigger delay and jitter was studied, and the minimum trigger jitter achieved <1 ns. This trigger worked for 107 shots at the repetition rate of 2 kHz continuously without obvious performance degradation and any failure of the generator. The main advantage of this trigger is the simultaneous combination of the high repetition rate, low jitter, long lifetime, and great simplicity in a compact structure.

Unravelling Some of the Key Transformations in the Hydrothermal Liquefaction of Lignin.

PubMed

Lui, Matthew Y; Chan, Bun; Yuen, Alexander K L; Masters, Anthony F; Montoya, Alejandro; Maschmeyer, Thomas

2017-05-22

Using both experimental and computational methods, focusing on intermediates and model compounds, some of the main features of the reaction mechanisms that operate during the hydrothermal processing of lignin were elucidated. Key reaction pathways and their connection to different structural features of lignin were proposed. Under neutral conditions, subcritical water was demonstrated to act as a bifunctional acid/base catalyst for the dissection of lignin structures. In a complex web of mutually dependent interactions, guaiacyl units within lignin were shown to significantly affect overall lignin reactivity. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Rotordynamic Characteristics of the HPOTP (High Pressure Oxygen Turbopump) of the SSME (Space Shuttle Main Engine)

NASA Technical Reports Server (NTRS)

Childs, D. W.

1984-01-01

Rotational stability of turbopump components in the space shuttle main engine was studied via analysis of component and structural dynamic models. Subsynchronous vibration caused unacceptable migration of the rotor/housing unit with unequal load sharing of the synchronous bearings that resulted in the failure of the High Pressure Oxygen Turbopump. Linear analysis shows that a shrouded inducer eliminates the second critical speed and the stability problem, a stiffened rotor improves the rotordynamic characteristics of the turbopump, and installing damper boost/impeller seals reduces bearing loads. Nonlinear analysis shows that by increasing the "dead band' clearances, a marked reduction in peak bearing loads occurs.

Russia and NATO Enlargement: The Assurances in 1990 and Their Implications

DTIC Science & Technology

2009-06-01

to achieve “an agreement on the final legal settlement of the German question, which would serve our security interests and the cause of stability... intrinsically coupled to new security structures in Europe with no dominant player, particularly not the Soviet Union’s rival, the United States...main European security issues and would unconditionally acknowledge the CIS [Commonwealth of Independent States] as a sphere of vital interest to

Preliminary Integrated Geologic Map Databases for the United States: Connecticut, Maine, Massachusetts, New Hampshire, New Jersey, Rhode Island and Vermont

USGS Publications Warehouse

Nicholson, Suzanne W.; Dicken, Connie L.; Horton, John D.; Foose, Michael P.; Mueller, Julia A.L.; Hon, Rudi

2006-01-01

The rapid growth in the use of Geographic Information Systems (GIS) has highlighted the need for regional and national scale digital geologic maps that have standardized information about geologic age and lithology. Such maps can be conveniently used to generate derivative maps for manifold special purposes such as mineral-resource assessment, metallogenic studies, tectonic studies, and environmental research. Although two digital geologic maps (Schruben and others, 1994; Reed and Bush, 2004) of the United States currently exist, their scales (1:2,500,000 and 1:5,000,000) are too general for many regional applications. Most states have digital geologic maps at scales of about 1:500,000, but the databases are not comparably structured and, thus, it is difficult to use the digital database for more than one state at a time. This report describes the result for a seven state region of an effort by the U.S. Geological Survey to produce a series of integrated and standardized state geologic map databases that cover the entire United States. In 1997, the United States Geological Survey's Mineral Resources Program initiated the National Surveys and Analysis (NSA) Project to develop national digital databases. One primary activity of this project was to compile a national digital geologic map database, utilizing state geologic maps, to support studies in the range of 1:250,000- to 1:1,000,000-scale. To accomplish this, state databases were prepared using a common standard for the database structure, fields, attribution, and data dictionaries. For Alaska and Hawaii new state maps are being prepared and the preliminary work for Alaska is being released as a series of 1:250,000 scale quadrangle reports. This document provides background information and documentation for the integrated geologic map databases of this report. This report is one of a series of such reports releasing preliminary standardized geologic map databases for the United States. The data products of the project consist of two main parts, the spatial databases and a set of supplemental tables relating to geologic map units. The datasets serve as a data resource to generate a variety of stratigraphic, age, and lithologic maps. This documentation is divided into four main sections: (1) description of the set of data files provided in this report, (2) specifications of the spatial databases, (3) specifications of the supplemental tables, and (4) an appendix containing the data dictionaries used to populate some fields of the spatial database and supplemental tables.

Extending the applicability of the Goldschmidt tolerance factor to arbitrary ionic compounds

PubMed Central

Sato, Toyoto; Takagi, Shigeyuki; Deledda, Stefano; Hauback, Bjørn C.; Orimo, Shin-ichi

2016-01-01

Crystal structure determination is essential for characterizing materials and their properties, and can be facilitated by various tools and indicators. For instance, the Goldschmidt tolerance factor (T) for perovskite compounds is acknowledged for evaluating crystal structures in terms of the ionic packing. However, its applicability is limited to perovskite compounds. Here, we report on extending the applicability of T to ionic compounds with arbitrary ionic arrangements and compositions. By focussing on the occupancy of constituent spherical ions in the crystal structure, we define the ionic filling fraction (IFF), which is obtained from the volumes of crystal structure and constituent ions. Ionic compounds, including perovskites, are arranged linearly by the IFF, providing consistent results with T. The linearity guides towards finding suitable unit cell and composition, thus tackling the main obstacle for determining new crystal structures. We demonstrate the utility of the IFF by solving the structure of three hydrides with new crystal structures. PMID:27032978

Extending the applicability of the Goldschmidt tolerance factor to arbitrary ionic compounds.

PubMed

Sato, Toyoto; Takagi, Shigeyuki; Deledda, Stefano; Hauback, Bjørn C; Orimo, Shin-ichi

2016-04-01

Crystal structure determination is essential for characterizing materials and their properties, and can be facilitated by various tools and indicators. For instance, the Goldschmidt tolerance factor (T) for perovskite compounds is acknowledged for evaluating crystal structures in terms of the ionic packing. However, its applicability is limited to perovskite compounds. Here, we report on extending the applicability of T to ionic compounds with arbitrary ionic arrangements and compositions. By focussing on the occupancy of constituent spherical ions in the crystal structure, we define the ionic filling fraction (IFF), which is obtained from the volumes of crystal structure and constituent ions. Ionic compounds, including perovskites, are arranged linearly by the IFF, providing consistent results with T. The linearity guides towards finding suitable unit cell and composition, thus tackling the main obstacle for determining new crystal structures. We demonstrate the utility of the IFF by solving the structure of three hydrides with new crystal structures.

Structural Alterations of Lignins in Transgenic Poplars with Depressed Cinnamyl Alcohol Dehydrogenase or Caffeic Acid O-Methyltransferase Activity Have an Opposite Impact on the Efficiency of Industrial Kraft Pulping1

PubMed Central

Lapierre, Catherine; Pollet, Brigitte; Petit-Conil, Michel; Toval, Gabriel; Romero, Javier; Pilate, Gilles; Leplé, Jean-Charles; Boerjan, Wout; Ferret, Valérie; De Nadai, Véronique; Jouanin, Lise

1999-01-01

We evaluated lignin profiles and pulping performances of 2-year-old transgenic poplar (Populus tremula × Populus alba) lines severely altered in the expression of caffeic acid/5-hydroxyferulic acid O-methyltransferase (COMT) or cinnamyl alcohol dehydrogenase (CAD). Transgenic poplars with CAD or COMT antisense constructs showed growth similar to control trees. CAD down-regulated poplars displayed a red coloration mainly in the outer xylem. A 90% lower COMT activity did not change lignin content but dramatically increased the frequency of guaiacyl units and resistant biphenyl linkages in lignin. This alteration severely lowered the efficiency of kraft pulping. The Klason lignin level of CAD-transformed poplars was slightly lower than that of the control. Whereas CAD down-regulation did not change the frequency of labile ether bonds or guaiacyl units in lignin, it increased the proportion of syringaldehyde and diarylpropane structures and, more importantly with regard to kraft pulping, of free phenolic groups in lignin. In the most depressed line, ASCAD21, a substantially higher content in free phenolic units facilitated lignin solubilization and fragmentation during kraft pulping. These results point the way to genetic modification of lignin structure to improve wood quality for the pulp industry. PMID:9880356

Isolation and structural characterization of the milled wood lignin, dioxane lignin, and cellulolytic lignin preparations from brewer's spent grain.

PubMed

Rencoret, Jorge; Prinsen, Pepijn; Gutiérrez, Ana; Martínez, Ángel T; Del Río, José C

2015-01-21

The structure of the lignin from brewer's spent grain (BSG) has been studied in detail. Three different lignin preparations, the so-called "milled-wood" lignin (MWL), dioxane lignin (DL), and cellulolytic lignin (CEL), were isolated from BSG and then thoroughly characterized by pyrolysis GC/MS, 2D-NMR, and derivatization followed by reductive cleavage (DFRC). The data indicated that BSG lignin presents a predominance of guaiacyl units (syringyl/guaiacyl ratio of 0.4-0.5) with significant amounts of associated p-coumarates and ferulates. The flavone tricin was also present in the lignin from BSG, as also occurred in other grasses. 2D-NMR (HSQC) revealed that the main substructures present are β-O-4' alkyl-aryl ethers (77-79%) followed by β-5' phenylcoumarans (11-13%) and lower amounts of β-β' resinols (5-6%) and 5-5' dibenzodioxocins (3-5%). The results from 2D-NMR (HMBC) and DFRC indicated that p-coumarates are acylating the γ-carbon of lignin side chains and are mostly involved in condensed structures. DFRC analyses also indicated a minor degree of γ-acylation with acetate groups, which takes place preferentially on S lignin (6% of S units are acetylated) over G lignin (only 1% of G units are acetylated).

The mapping competences of the nurse Case/Care Manager in the context of Intensive Care.

PubMed

Alfieri, Emanuela; Ferrini, Anna Chiara; Gianfrancesco, Francesca; Lise, Gianluca; Messana, Giovanni; Tirelli, Lorenzo; Lorenzo, Ana; Sarli, Leopoldo

2017-03-15

Since the recent introduction of the Case/Care Manager's professional figure, it is quite difficult to identify properly his/her own particular features, which could be mainly be found revising mainly in American studies. Therefore, the present study intended to identify the Case/Care Manager's skills and professional profile in an Intensive Care Unit experience, taking into consideration the staff's activities, perception and expectations towards the Case/Care Manager. In particular, it has been compared the experience of an Intensive Care Units where the Case/Care Manager's profile is operational to a different Unit where a Case/Care Manager is not yet in force. a Levati's model was used to map the Case/Care Manager's skills, involving each unit whole working staff, executives and caregivers through semi-structured interviews. It has been taken into consideration the Anaesthesia Unit and Emergency Unit of Cesena's healthcare organisation (AUSL of Romagna) and a Cardiology Intensive Care Unit of Piacenza's healthcare organisation, where the Case/Care Manager's profile has not been experimented yet. Firstly, it a data collection in each healthcare organization has been organised. Subsequently, semi-structured interviews to doctors, unit nurses, caregivers, nurses' coordinators and medical staff have been used to compare each healthcare system. The interviewees' described their expectations in relation to the Case/Care Manager working in a critical area. Then, every data collected during interviews has been organised to map a Case/Care Manager's essential professional profile to work in a critical area together with medical staff. Piacenza's O.U. critical area experience reported a major demand for patients' and patient's families' assistance. On the other hand, the very same aspects seem to have been better achieved in Cesena's O.U., where a Case/Care Manager's recent introduction has actually helped to overcome the void in organising systems. a Case/Care Manager's profile has been drafted on the basis of the comparative analysis conducted. It has been noted how the Case/Care Manager's professional profile can really improve relationships and communications between medical staff and patients, promoting a major unity among the working team. According to the present research, the Case/Care Manager's profile has been proved helpful in positively influencing the team activity and to elicit major satisfaction both in patients and their family.

Directional ratio based on parabolic molecules and its application to the analysis of tubular structures

NASA Astrophysics Data System (ADS)

Labate, Demetrio; Negi, Pooran; Ozcan, Burcin; Papadakis, Manos

2015-09-01

As advances in imaging technologies make more and more data available for biomedical applications, there is an increasing need to develop efficient quantitative algorithms for the analysis and processing of imaging data. In this paper, we introduce an innovative multiscale approach called Directional Ratio which is especially effective to distingush isotropic from anisotropic structures. This task is especially useful in the analysis of images of neurons, the main units of the nervous systems which consist of a main cell body called the soma and many elongated processes called neurites. We analyze the theoretical properties of our method on idealized models of neurons and develop a numerical implementation of this approach for analysis of fluorescent images of cultured neurons. We show that this algorithm is very effective for the detection of somas and the extraction of neurites in images of small circuits of neurons.

[Principles of surgical care organization and structural characteristics of sanitary casualties in counter-terrorist operations in the Northern Caucasus (Report I)].

PubMed

Gumanenko, E K; Samokhvalov, I M; Trusov, A A; Severin, V V

2005-01-01

Two operational-and-tactical factors had the main influence on organization of the surgical care rendered to the casualties on the Northern Caucasus: the fulminant and maneuverable nature of combat operations at the beginning of both armed conflicts and rather small territory of war theatre. The main special features of organization of surgical care to the casualties were the use of Medical Squads of Special Purpose in the combat conditions and maximal approximation of the specialized surgical care to the wounded by echelonment of medical units and wide use of helicopter evacuation. The structure of sanitary losses was characterized by the increase in the frequency of mechanical traumas, thermal and combined injuries, by the high share of the casualties with head injuries. Besides the number of seriously wounded and critical casualties has increased.

Extending the mind: a review of ethnographies of neuroscience practice.

PubMed

Mahfoud, Tara

2014-01-01

THIS PAPER REVIEWS ETHNOGRAPHIES OF NEUROSCIENCE LABORATORIES IN THE UNITED STATES AND EUROPE, ORGANIZING THEM INTO THREE MAIN SECTIONS: (1) descriptions of the capabilities and limitations of technologies used in neuroimaging laboratories to map "activity" or "function" onto structural models of the brain; (2) discussions of the "distributed" or "extended" mind in neuroscience practice; and (3) the implications of neuroscience research and the power of brain images outside the laboratory. I will try to show the importance of ethnographic work in such settings, and place this body of ethnographic work within its historical framework-such ethnographies largely emerged within the Decade of the Brain, as announced by former President of the United States George H. W. Bush in 1990. The main argument is that neuroscience research and the context within which it is taking place has changed since the 1990's-specifically with the launch of "big science" projects such as the Human Brain Project (HBP) in the European Union and the BRAIN initiative in the United States. There is an opportunity for more research into the institutional and politico-economic context within which neuroscience research is taking place, and for continued engagement between the social and biological sciences.

The political economy of medical care. An explanation of the composition, nature, and functions of the present health sector of the United States.

PubMed

Navarro, V

1975-01-01

This presentation provides an alternative explanation of the present composition, nature, and functions of the health sector in the United States to those frequently given in sociological, economic, and medical care literature. These expalantions usually maintain that the Amcerican health sector is a result of the value system of the assumedly middle class American society. In this presentation it is postulated that the present economic structure of the United States determines and maintains a social class structure, both outside and within the health sector, and that the different degrees of ownership, control, and influence that these classes have on the means of production, reproduction, and legitimization in the United States explain the composition, nature, and functions of the health sector. It is further postulated that the value system is not the cuase, but a sysmptom, of these class controls and influences. The paper is divided into three sections. The first part profices a description of the class structure, which includes the corporate class, upper middle class, lower middle class, and working class, and it describes the mechanisms whereby this structure is maintained and replicated, both outside and within the health sector. The second section analyzes: (1)the production characteristics and social make-up of the thre main sectors of the U. S. economy-the monpolistic, state, and competitive sectors-and it focuses especially on the monopolistic sector, which is assumed to be the dominant sector in the U. S. economy, with its needs determining to a large degree the functions of the social sectors, including those of the health sector; (2) the increasing dominance of the monopolistic sector in the health sector, by means of the financial institutions, which conflicts primarily with the providers'relative control of the financing of health services; and (3) the main conflict in the control of the reproductive (academic) an distributive (delivery) institutions which, it is postulated, is not, as is generally belived, between the providers and the so-called consumers, but rather between the corporate and upper middle classes (including the providers), who control those institutions, and the majority of the U. S. population, the lower middle and working classes, who do not control them...

States of paleostress north and south of the Periadriatic fault: Comparison of the Drau Range and the Friuli Southalpine wedge

PubMed Central

Bartel, Esther Maria; Neubauer, Franz; Genser, Johann; Heberer, Bianca

2014-01-01

This study focuses on the analysis of structures and kinematics of a N–S profile along the axis of maximum shortening of the European Eastern Alps. The area includes the southern Austroalpine unit in the north and the Southalpine unit, which is a part of the Adriatic indenter. The stratigraphically different units are separated by the Periadriatic fault, the major strike-slip fault within the Alps. In order to assess the kinematics of these units, mainly fault-slip data from north and south of the Periadriatic fault were analyzed. We distinguish a succession of five main kinematic groups in both units: (1) N–S compression; (2) NW–SE compression; (3) NE–SW compression, σ3 changes gradually from subvertical to subhorizontal; (4) N–S compression; and (5) NW–SE compression. Our study reveals that the deformation sequence on either sides of the PAF is similar. The mean orientations of the principal stress axes, however, show small, but consistent differences: The subhorizontal axes north of the Periadriatic fault plunge northward, in the south southward. A counterclockwise (CCW) rotation of the southern part in respect to the north is evident and in line with the well-known counterclockwise rotation of the Adriatic indenter as well as dextral displacement of the N-fanning stress-field along the Periadriatic fault. Opposing plunge directions are interpreted as a primary feature of the internal stress-field within an orogenic wedge further increased during ongoing compression. PMID:27064736

Structural analysis of a homogeneous polysaccharide from Achatina fulica.

PubMed

Liu, Jie; Shang, Feineng; Yang, Zengming; Wu, Mingyi; Zhao, Jinhua

2017-05-01

Edible snails have been widely used as a health food and medicine in many countries. In our study, a water-soluble polysaccharide (AF-1) was isolated and purified from Achatina fulica by papain enzymolysis, alcohol precipitation and strong anion exchange chromatography. Structureof the polysaccharide was analyzed and characterized by chemical and instrumental methods, such as Fourier transform infrared spectroscopy, high performance liquid chromatography, analysis of monosaccharide composition, methylation analysis, and nuclear magnetic resonance (NMR) spectroscopy ( 1 H, 13 C, COSY, TOCSY, NOESY, HSQC and HMBC). Chemical composition analysis indicated that AF-1 is composed of glucose (Glc) and its average molecular weight is 1710kDa. Structural analysis suggested that AF-1 is mainly consisted of a linear repeating backbone of (1→4) linked α-d-Glc p residues with one branch, α-d-Glc p, attached to the main chain by (1→6) glycosidic bonds at every five main-chain units. Further studies on biological activities of the polysaccharide are currently in progress. Copyright © 2017 Elsevier B.V. All rights reserved.

Structural characterization of hemicelluloses and topochemical changes in Eucalyptus cell wall during alkali ethanol treatment.

PubMed

Li, Han-Yin; Sun, Shao-Ni; Zhou, Xia; Peng, Feng; Sun, Run-Cang

2015-06-05

Eucalyptus was sequentially extracted with 70% ethanol containing 0.4, 1.0, 2.0, 3.0, and 5.0% NaOH for 2h at 80°C. The chemical composition and structural features of the hemicellulosic fractions obtained were comparatively characterized by the combination of high-performance anion-exchange chromatography, gel permeation chromatography, Fourier transform infrared, and nuclear magnetic resonance spectroscopies. Furthermore, the main component distribution and their changes in cell wall were investigated by confocal Raman microscopy. Based on the Fourier transform infrared and nuclear magnetic resonance analyses, the hemicelluloses extracted from Eucalyptus mainly have a linear backbone of (1→4)-linked-β-d-xylopyranosyl residues decorated with branch at O-2 of 4-O-methyl-α-glucuronic acid unit. Raman analysis revealed that the dissolution of hemicelluloses was different in the morphological regions, and the hemicelluloses released mainly originated from the secondary wall. The information obtained from the study conducted by combining chemical characterization with ultrastructure provides important basis for studying the mechanism of the alkali treatment. Copyright © 2015 Elsevier Ltd. All rights reserved.

Structure, age, and regional significance of syntectonic augen gneisses in the Pan-African Zambezi belt, south-central Zambia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hanson, R.E.; Wilson, T.J.; Wardlaw, M.S.

1985-01-01

The Pan-African Zambezi belt in Zambia contains two major augen gneiss units that are elongated parallel to regional strike. These were previously regarded as slices of sialic basement structurally interleaved with Katangan metasedimentary rocks. New field and geochronologic evidence suggests that the gneisses are syntectonic granites intruded as large concordant sheets during main-phase (D/sub 1/) Pan-African deformation. A pervasive, horizontal or shallowly plunging mineral lineation on S/sub 1/ in the gneisses indicates that the parent granites were injected along major zones of transcurrent shear. The northern gneiss unit shows local discordant contacts against, and contains xenoliths of, adjacent Katangan rocks.more » Large, partly polygonized K-spar augen in the gneiss are wrapped around by S/sub 1/ and offset by microfractures antithetic to S/sub 1/. Finer grained granites intruding the gneiss are penetratively foliated to nondeformed, indicating that they were injected at various times relative to D/sub 1/. In the more intensely deformed southern gneiss unit, local pods of protomylonitic flaser gneiss grade into mylonites containing asymmetric K-spar augen set in a dynamically recrystallized matrix. U-Pb analyses of four fractions plus an air-abraded split of one fraction form a normal linear discordance pattern with an upper intercept of 820 +/- 7 Ma, taken as the age of igneous crystallization. Comparison with other available geochronologic data indicates that this age dates main-phase deformation in the Zambezi belt, and that deformation in the supposedly continuous Damaran belt to the SW was significantly younger.« less

Water-soluble polysaccharides from Pleurotus ostreatus var. florida mycelial biomass.

PubMed

Komura, Dirce L; Ruthes, Andrea C; Carbonero, Elaine R; Gorin, Philip A J; Iacomini, Marcello

2014-09-01

Pleurotus ostreatus var. florida known as Hiratake has a high nutritional value, presents medicinal and nutraceutical properties and it is one of the consumed mushrooms in Brazil. Thus, the aim of this study was to characterize the chemical structure of polysaccharides found in mycelial biomass produced by submerged culture of P. ostreatus var. florida in order to compare with those found in P. ostreatus var. florida fruit bodies. Aqueous and alkali extracts obtained from mycelial biomass were purified, 13C NMR, GC-MS and chemical techniques were used to characterize three polysaccharide structures: a mannogalactan (MG-PfM) with α-D-Galp and 3-O-Me-α-D-Galp units, both (1→6)-linked, highly substituted at O-2 by D-Manp, a glycogen-like polymer (GLY-PfM) with α-D-Glp (1→4)-linked main chain, partially substituted at O-6 by α-D-Glcp side chains and a (1→3), (1→6) β-D-glucan (βGLC-PfM) with a main chain of β-D-Glcp (1→3)-linked units, partially substituted at O-6 by side chains of 6-O-substituted β-D-glucopyranosyl units, on an average of one to every two residues of the backbone. These results show the possibility to obtain similar and also different molecules from those found in the fruiting body of the same mushroom species, therefore the submerged culture of mushroom is a promising way to give raise molecules of interest. Copyright © 2014. Published by Elsevier B.V.

The barriers to the prevention of ventilator-associated pneumonia from the perspective of critical care nurses: A qualitative descriptive study.

PubMed

Atashi, Vajihe; Yousefi, Hojatollah; Mahjobipoor, Hosein; Yazdannik, Ahmadreza

2018-03-01

The aim of this study was to explore the perspectives of Iranian critical care nurses on the barriers to ventilator-associated pneumonia prevention in intensive care units. Most patients hospitalized in intensive care units need mechanical ventilation. One of the most prevalent and serious complications of mechanical ventilation is ventilator-associated pneumonia. There are different barriers to the prevention of this kind of pneumonia. Qualitative descriptive design was used. In this qualitative study, 23 critical care nurses were recruited via purposive sampling. Semi-structured interviews were done for data collection. The interviews were recorded digitally, transcribed word by word, and analyzed using the inductive content analysis approach. The barriers to the prevention of ventilator-associated pneumonia fell into three main categories, namely nurses' limited professional competence, unfavorable environmental conditions, and passive human resource management. The 10 subcategories of these main categories were unfavorable professional attitude, limited professional knowledge, low job motivation, limited professional accountability, non-standard physical structure, inadequate or inappropriate equipment, heavy workload, staff shortage, inadequate staff training, and ineffective supervision. The barriers to the prevention of ventilator-associated pneumonia in intensive care units are very diverse and complex and include a wide range of interrelated personal, environmental, and organizational barriers. This study created a better understanding of the barriers to ventilator-associated pneumonia prevention. Moreover, highlighted the importance of sufficient resources, adequate staffing level, and contextually-appropriate evidence-based guidelines for effective ventilator-associated pneumonia prevention. © 2017 John Wiley & Sons Ltd.

Gaseous Elemental Mercury and Total and Leached Mercury in Building Materials from the Former Hg-Mining Area of Abbadia San Salvatore (Central Italy)

PubMed Central

Vaselli, Orlando; Nisi, Barbara; Rappuoli, Daniele; Cabassi, Jacopo; Tassi, Franco

2017-01-01

Mercury has a strong environmental impact since both its organic and inorganic forms are toxic, and it represents a pollutant of global concern. Liquid Hg is highly volatile and can be released during natural and anthropogenic processes in the hydrosphere, biosphere and atmosphere. In this study, the distribution of Gaseous Elemental Mercury (GEM) and the total and leached mercury concentrations on paint, plaster, roof tiles, concrete, metals, dust and wood structures were determined in the main buildings and structures of the former Hg-mining area of Abbadia San Salvatore (Siena, Central Italy). The mining complex (divided into seven units) covers a surface of about 65 ha and contains mining structures and managers’ and workers’ buildings. Nine surveys of GEM measurements were carried out from July 2011 to August 2015 for the buildings and structures located in Units 2, 3 and 6, the latter being the area where liquid mercury was produced. Measurements were also performed in February, April, July, September and December 2016 in the edifices and mining structures of Unit 6. GEM concentrations showed a strong variability in time and space mostly depending on ambient temperature and the operational activities that were carried out in each building. The Unit 2 surveys carried out in the hotter period (from June to September) showed GEM concentrations up to 27,500 ng·m−3, while in Unit 6, they were on average much higher, and occasionally, they saturated the GEM measurement device (>50,000 ng·m−3). Concentrations of total (in mg·kg−1) and leached (in μg·L−1) mercury measured in different building materials (up to 46,580 mg·kg−1 and 4470 mg·L−1, respectively) were highly variable, being related to the edifice or mining structure from which they were collected. The results obtained in this study are of relevant interest for operational cleanings to be carried out during reclamation activities. PMID:28420130

Periodic Density Functional Theory Study of the Structure, Raman Spectrum, and Mechanical Properties of Schoepite Mineral.

PubMed

Colmenero, Francisco; Cobos, Joaquín; Timón, Vicente

2018-04-16

The structure and Raman spectrum of schoepite mineral, [(UO 2 ) 8 O 2 (OH) 12 ]·12H 2 O, was studied by means of theoretical calculations. The computations were carried out by using density functional theory with plane waves and pseudopotentials. A norm-conserving pseudopotential specific for the U atom developed in a previous work was employed. Because it was not possible to locate H atoms directly from X-ray diffraction (XRD) data by structure refinement in previous experimental studies, all of the positions of the H atoms in the full unit cell were determined theoretically. The structural results, including the lattice parameters, bond lengths, bond angles, and powder XRD pattern, were found to be in good agreement with their experimental counterparts. However, the calculations performed using the unit cell designed by Ostanin and Zeller in 2007, involving half of the atoms of the full unit cell, led to significant errors in the computed powder XRD pattern. Furthermore, Ostanin and Zeller's unit cell contains hydronium ions, H 3 O + , which are incompatible with the experimental information. Therefore, while the use of this schoepite model may be a very useful approximation requiring a much smaller amount of computational effort, the full unit cell should be used to study this mineral accurately. The Raman spectrum was also computed by means of density functional perturbation theory and compared with the experimental spectrum. The results were also in agreement with the experimental data. A normal-mode analysis of the theoretical spectra was performed to assign the main bands of the Raman spectrum. This assignment significantly improved the current empirical assignment of the bands of the Raman spectrum of schoepite mineral. In addition, the equation of state and elastic properties of this mineral were determined. The crystal structure of schoepite was found to be stable mechanically and dynamically. Schoepite can be described as a brittle material exhibiting small anisotropy and large compressibility in the direction perpendicular to the layers, which characterize its structure. The calculated bulk modulus, B, was ∼35 GPa.

Shyok Suture Zone, N Pakistan: late Mesozoic Tertiary evolution of a critical suture separating the oceanic Ladakh Arc from the Asian continental margin

NASA Astrophysics Data System (ADS)

Robertson, Alastair H. F.; Collins, Alan S.

2002-02-01

The Shyok Suture Zone (Northern Suture) of North Pakistan is an important Cretaceous-Tertiary suture separating the Asian continent (Karakoram) from the Cretaceous Kohistan-Ladakh oceanic arc to the south. In previously published interpretations, the Shyok Suture Zone marks either the site of subduction of a wide Tethyan ocean, or represents an Early Cretaceous intra-continental marginal basin along the southern margin of Asia. To shed light on alternative hypotheses, a sedimentological, structural and igneous geochemical study was made of a well-exposed traverse in North Pakistan, in the Skardu area (Baltistan). To the south of the Shyok Suture Zone in this area is the Ladakh Arc and its Late Cretaceous, mainly volcanogenic, sedimentary cover (Burje-La Formation). The Shyok Suture Zone extends northwards (ca. 30 km) to the late Tertiary Main Karakoram Thrust that transported Asian, mainly high-grade metamorphic rocks southwards over the suture zone. The Shyok Suture Zone is dominated by four contrasting units separated by thrusts, as follows: (1). The lowermost, Askore amphibolite, is mainly amphibolite facies meta-basites and turbiditic meta-sediments interpreted as early marginal basin rift products, or trapped Tethyan oceanic crust, metamorphosed during later arc rifting. (2). The overlying Pakora Formation is a very thick (ca. 7 km in outcrop) succession of greenschist facies volcaniclastic sandstones, redeposited limestones and subordinate basaltic-andesitic extrusives and flow breccias of at least partly Early Cretaceous age. The Pakora Formation lacks terrigenous continental detritus and is interpreted as a proximal base-of-slope apron related to rifting of the oceanic Ladakh Arc; (3). The Tectonic Melange (<300 m thick) includes serpentinised ultramafic rocks, near mid-ocean ridge-type volcanics and recrystallised radiolarian cherts, interpreted as accreted oceanic crust. (4). The Bauma-Harel Group (structurally highest) is a thick succession (several km) of Ordovician and Carboniferous to Permian-Triassic, low-grade, mixed carbonate/siliciclastic sedimentary rocks that accumulated on the south-Asian continental margin. A structurally associated turbiditic slope/basinal succession records rifting of the Karakoram continent (part of Mega-Lhasa) from Gondwana. Red clastics of inferred fluvial origin ('molasse') unconformably overlie the Late Palaeozoic-Triassic succession and are also intersliced with other units in the suture zone. Reconnaissance further east (north of the Shyok River) indicates the presence of redeposited volcaniclastic sediments and thick acid tuffs, derived from nearby volcanic centres, presumed to lie within the Ladakh Arc. In addition, comparison with Lower Cretaceous clastic sediments (Maium Unit) within the Northern Suture Zone, west of the Nanga Parbat syntaxis (Hunza River) reveals notable differences, including the presence of terrigenous quartz-rich conglomerates, serpentinite debris-flow deposits and a contrasting structural history. The Shyok Suture Zone in the Skardu area is interpreted to preserve the remnants of a rifted oceanic back-arc basin and components of the Asian continental margin. In the west (Hunza River), a mixed volcanogenic and terrigenous succession (Maium Unit) is interpreted to record syn-deformational infilling of a remnant back-arc basin/foreland basin prior to suturing of the Kohistan Arc with Asia (75-90 Ma).

Ethical problems experienced by oncology nurses.

PubMed

da Luz, Kely Regina; Vargas, Mara Ambrosina de Oliveira; Schmidtt, Pablo Henrique; Barlem, Edison Luiz Devos; Tomaschewski-Barlem, Jamila Geri; da Rosa, Luciana Martins

2015-01-01

To know the ethical problems experienced by oncology nurses. Descriptive and exploratory study with a qualitative approach, performed in inpatient units and in chemotherapy out-patients units that provide assistance to oncological patients in two capitals in the South region of Brazil. Eighteen nurses participated in this study, selected by snowball sampling type. For data collection, semi-structured interviews were carried out, which were recorded and transcribed, and then analyzed by thematic analysis. Two categories were established: when informing or not becomes a dilemma - showing the main difficulties related to oncological treatment information regarding health staff, health system, and infrastructure; to invest or not - dilemmas related to finitude - showing situations of dilemmas related to pain and confrontation with finitude. For the effective confrontation of the ethical problems experienced by oncology nurses to occur, it is important to invest in the training of these professionals, preparing them in an ethical and human way to act as lawyers of the patient with cancer, in a context of dilemmas related mainly to the possibility of finitude.

Physics Goals for the Planned Next Linear Collider Engineering Test Facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Raubenheimer, Tor O

2001-10-02

The Next Linear Collider (NLC) Collaboration is planning to construct an Engineering Test Facility (ETF) at Fermilab. As presently envisioned, the ETF would comprise a fundamental unit of the NLC main linac to include X-band klystrons and modulators, a delay-line power-distribution system (DLDS), and NLC accelerating structures that serve as loads. The principal purpose of the ETF is to validate stable operation of the power-distribution system, first without beam, then with a beam having the NLC pulse structure. This paper concerns the possibility of configuring and using the ETF to accelerate beam with an NLC pulse structure, as well asmore » of doing experiments to measure beam-induced wakefields in the rf structures and their influence back on the beam.« less

Physics goals for the planned next linear collider engineering test facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Courtlandt L Bohn et al.

2001-06-26

The Next Linear Collider (NLC) Collaboration is planning to construct an Engineering Test Facility (ETF) at Fermilab. As presently envisioned, the ETF would comprise a fundamental unit of the NLC main linac to include X-band klystrons and modulators, a delay-line power-distribution system (DLDS), and NLC accelerating structures that serve as loads. The principal purpose of the ETF is to validate stable operation of the power-distribution system, first without beam, then with a beam having the NLC pulse structure. This paper concerns the possibility of configuring and using the ETF to accelerate beam with an NLC pulse structure, as well asmore » of doing experiments to measure beam-induced wakefields in the rf structures and their influence back on the beam.« less

Physics goals for the planned next linear collider engineering test facility.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bohn, C.; Michelotti, L.; Ostiguy, J.-F.

2001-07-17

The Next Linear Collider (NLC) Collaboration is planning to construct an Engineering Test Facility (ETF) at Fermilab. As presently envisioned, the ETF would comprise a fundamental unit of the NLC main linac to include X-band klystrons and modulators, a delay-line power-distribution system (DLDS), and NLC accelerating structures that serve as loads. The principal purpose of the ETF is to validate stable operation of the power-distribution system, first without beam, then with a beam having the NLC pulse structure. This paper concerns the possibility of configuring and using the ETF to accelerate beam with an NLC pulse structure, as well asmore » of doing experiments to measure beam-induced wakefields in the rf structures and their influence back on the beam.« less

The chemical structure of macromolecular fractions of a sulfur-rich oil

NASA Astrophysics Data System (ADS)

Richnow, Hans H.; Jenisch, Angela; Michaelis, Walter

1993-06-01

A selective stepwise chemical degradation has been developed for structural studies of highmolecularweight (HMW) fractions of sulfur-rich oils. The degradation steps are: (i) desulfurization (ii) cleavage of oxygen-carbon bonds (iii) oxidation of aromatic structural units. After each step, the remaining macromolecular matter was subjected to the subsequent reaction. This degradation scheme was applied to the asphaltene, the resin and a macromolecular fraction of low polarity (LPMF) of the Rozel Point oil. Total amounts of degraded low-molecular-weight compounds increased progressively in the order asphaltene < resin < LPMF. Desulfurization yielded mainly phytane, steranes and triterpanes. Oxygen-carbon bond cleavage resulted in hydrocarbon fractions predominated by n-alkanes and acyclic isoprenoids. The oxidation step afforded high amounts of linear carboxylic acids in the range of C 11 to C 33. The released compounds provide a more complete picture of the molecular structure of the oil fractions than previously available. Labelling experiments with deuterium atoms allowed to characterize the site of bonding and the type of linkage for the released compounds. Evidence is presented that subunits of the macromolecular network are attached simultaneously by oxygen and sulfur (n-alkanes, hopanes) or by sulfur and aromatic units ( n-alkanes, steranes).

Changing organizational structure and organizational memory in primary care practices: a qualitative interview study.

PubMed

Alyahya, Mohammad

2012-02-01

Organizational structure is built through dynamic processes which blend historical force and management decisions, as a part of a broader process of constructing organizational memory (OM). OM is considered to be one of the main competences leading to the organization's success. This study focuses on the impact of the Quality and Outcome Framework (QOF), which is a Pay-for-Performance scheme, on general practitioner (GP) practices in the UK. The study is based on semistructured interviews with four GP practices in the north of England involving 39 informants. The findings show that the way practices assigned different functions into specialized units, divisions or departments shows the degree of specialization in their organizational structures. More specialized unit arrangements, such as an IT division, particular chronic disease clinics or competence-based job distributions enhanced procedural memory development through enabling regular use of knowledge in specific context, which led to competence building. In turn, such competence at particular functions or jobs made it possible for the practices to achieve their goals more efficiently. This study concludes that organizational structure contributed strongly to the enhancement of OM, which in turn led to better organizational competence.

Development and fabrication of structural components for a scramjet engine

NASA Technical Reports Server (NTRS)

Buchmann, O. A.

1990-01-01

A program broadly directed toward design and development of long-life (100 hours and 1,000 cycles with a goal of 1,000 hours and 10,000 cycles) hydrogen-cooled structures for application to scramjets is presented. Previous phases of the program resulted in an overall engine design and analytical and experimental characterization of selected candidate materials and concepts. The latter efforts indicated that the basic life goals for the program can be reached with available means. The main objective of this effort was an integrated, experimental evaluation of the results of the previous program phases. The fuel injection strut was selected for this purpose, including fabrication development and fabrication of a full-scale strut. Testing of the completed strut was to be performed in a NASA-Langley wind tunnel. In addition, conceptual designs were formulated for a heat transfer test unit and a flat panel structural test unit. Tooling and fabrication procedures required to fabricate the strut were developed, and fabrication and delivery to NASA of all strut components, including major subassemblies, were completed.

Structural study and conformational behavior of the two different lipopolysaccharide O-antigens produced by the cystic fibrosis pathogen Burkholderia multivorans.

PubMed

Ieranò, Teresa; Silipo, Alba; Cescutti, Paola; Leone, Maria Rosaria; Rizzo, Roberto; Lanzetta, Rosa; Parrilli, Michelangelo; Molinaro, Antonio

2009-07-20

Lipopolysaccharides (LPSs) are virulence factors expressed by gram-negative bacteria; they are among those mainly responsible for bacterial virulence. In this work we define the primary structure and the conformational features of the O-chain from the LPS produced by the highly virulent clinical isolate Burkholderia multivorans strain C1576, an opportunistic human pathogen isolated in a cystic fibrosis center and causative of an outbreak with lethal outcome. We demonstrate that the LPS from this clinical isolate consists of two O-polysaccharide chains present in different amounts and made up of repeating units, both containing deoxy sugar. Additionally, conformational studies have been performed to establish and compare the spatial arrangements of the two polysaccharides and differences in their shape have been highlighted. The comprehension of the structural and conformational features of the two repeating units may help to explain their biological significance, the molecular shape of the bacterial external surface, and the comprehension at the molecular level of the recognition mechanisms of the antibodies.

Coriariin M, a trimeric hydrolysable tannin with dehydrodigalloyl and valoneoyl groups as linking units, and accompanying dimeric hydrolysable tannins from Coriaria japonica.

PubMed

Shimozu, Yuuki; Hirai, Takayasu; Hatano, Tsutomu

2018-07-01

Three oligomeric hydrolysable tannins, coriariins K, L, and M, which were previously undescribed, together with five known hydrolysable tannins were isolated from dried leaves of Coriaria japonica. Their structures were determined based on 1D and 2D NMR spectroscopy, HR-ESI-MS, and ECD spectroscopy experiments. Among the isolated compounds, coriariin M has a unique trimer structure where both dehydrodigalloyl and valoneoyl group linkages were found between the hydrolysable tannin monomers. Dimeric hydrolysable tannins coriariins K and L, having a dehydrodigalloyl group as the linking unit, were structurally related to coriariin A, the main hydrolysable tannin of this plant species. Additionally, the complexation of the eight hydrolysable tannins isolated in this study with bovine serum albumin (BSA) to form water-soluble macromolecules was analyzed using native polyacrylamide gel electrophoresis (PAGE). A comparison of the behaviors of the oligomeric hydrolysable tannins suggested the participation of the hexahydroxydiphenoyl group and the importance of the molecular sizes of the hydrolysable tannins in the formation of macromolecules. Copyright © 2018 Elsevier Ltd. All rights reserved.

Energy consumption analysis and simulation of waste heat recovery technology of ceramic rotary kiln

NASA Astrophysics Data System (ADS)

Chen, Zhiguang; Zhou, Yu; Qin, Chaokui; Zhang, Xuemei

2018-03-01

Ceramsite is widely used in the construction industry, insulation works and oil industry in China, and the manufacture equipment is mainly industrial kiln. In this paper, energy consumption analysis had been carried out through experimental test of a Ceramsite kiln in Henan province. Results showed that the discharge temperature of Ceramsite was about 1393K, and the waste heat accounted for 22.1% of the total energy consumption. A structure of cyclone preheater which recovered waste heat of the high temperature Ceramsite by blast cooling was designed. Then, using Fluent software, performance of the unit was simulated. The minimum temperature that Ceramsite could reach, heat dissipating capacity of Ceramsite, temperature at air outlet, wall temperature of the unit and pressure loss were analyzed. Performance of the designed unit under different inlet velocity was analyzed as well.

Assessing effects of structural zeros on models of canine cancer incidence: a case study of the Swiss Canine Cancer Registry.

PubMed

Boo, Gianluca; Leyk, Stefan; Fabrikant, Sara Irina; Pospischil, Andreas; Graf, Ramona

2017-05-11

Epidemiological research of canine cancers could inform comparative studies of environmental determinants for a number of human cancers. However, such an approach is currently limited because canine cancer data sources are still few in number and often incomplete. Incompleteness is typically due to under-ascertainment of canine cancers. A main reason for this is because dog owners commonly do not seek veterinary care for this diagnosis. Deeper knowledge on under-ascertainment is critical for modelling canine cancer incidence, as an indication of zero incidence might originate from the sole absence of diagnostic examinations within a given sample unit. In the present case study, we investigated effects of such structural zeros on models of canine cancer incidence. In doing so, we contrasted two scenarios for modelling incidence data retrieved from the Swiss Canine Cancer Registry. The first scenario was based on the complete enumeration of incidence data for all Swiss municipal units. The second scenario was based on a filtered sample that systematically discarded structural zeros in those municipal units where no diagnostic examination had been performed. By means of cross-validation, we assessed and contrasted statistical performance and predictive power of the two modelling scenarios. This analytical step allowed us to demonstrate that structural zeros impact on the generalisability of the model of canine cancer incidence, thus challenging future comparative studies of canine and human cancers. The results of this case study show that increased awareness about the effects of structural zeros is critical to epidemiological research.

Development of Inspection and Repair Technology for Heat Exchanger Tubes in Fast Breeder Reactors

DTIC Science & Technology

2009-06-01

Technology for Heat Exchanger Tubes in Fast Breeder Reactors Akihiko NISHIMURA *1 , Takahisa SHOBU, Kiyoshi OKA, Toshihiko YAMAGUCHI, Yukihiro SHIMADA...fast breeder reactors (FBRs). It comprises a laser processing head combined with an eddy current testing unit. Ultrashort laser pulse ablation is used...be applied in the main- tenance of large structures such as nuclear reactors and chemical factories [1]. Internal access to a blanket cooling pipe

Physiographic map of the Sicilian region (1:250,000 scale)

NASA Astrophysics Data System (ADS)

Priori, Simone; Fantappiè, Maria; Costantini, Edoardo A. C.

2015-04-01

Physiographic maps summarize and group the landforms of a territory into homogeneous areas in terms of kind and intensity of main geomorphological process. Most of the physiographic maps have large scale, which is national or continental scale. Other maps have been produced at the semi-detailed scales, while examples at the regional scale are much less common. However, being the Region the main administrative level in Europe, they can be very useful for land planning in many fields, such as ecological studies, risk maps, and soil mapping. This work presents a methodological example of regional physiographic map, compiled at 1:250,000 scale, representing the whole Sicilian region, the largest and most characteristic of Mediterranean island. The physiographic units were classed matching thematich layers (NDVI, geology, DEM, land cover) with the main geomorphological processes that were identified by stereo-interpretation of aerial photographs (1:70,000 scale). In addition, information from other published maps, representing geomorphological forms, aeolian deposits, anthropic terraced slopes, and landslide were used to improve the accuracy and reliability of the map. The classification of the physiographic units, and then the map legend, was built up on the basis of literature and taking into account Italian geomorphological legend. The legend proposed in this map, which can be applied also in other Mediterranean countries, is suitable for different scales. The landform units were grouped on the base of a geomorphological classification of the forms into: anthropogenic, eolian, coastal, valley floor, intermountain fluvial, slope erosional, structural, karstic, and volcanic.

C-glucosidic ellagitannins from Lythri herba (European Pharmacopoeia): chromatographic profile and structure determination.

PubMed

Piwowarski, Jakub P; Kiss, Anna K

2013-01-01

Lythri herba, a pharmacopoeial plant material (European Pharmacopoea), is obtained from flowering parts of purple loosestrife (Lythrum salicaria L.). Although extracts from this plant material have been proven to possess some interesting biological activities and its pharmacopoeial standardisation is based on total tannin content determination, the phytochemical characterisation of this main group of compounds has not yet been fully conducted. To isolate ellagitannins from Lythri herba, determine their structures and develop chromatographic methods for their qualitative analysis. Five C-glucosidic ellagitannins - monomeric- vescalagin and castalagin together with new dimeric structures - salicarinins A-C, composed of vescalagin and stachyurin, vescalagin and casuarinin, castalagin and casuarinin units connected via formation of valoneoyl group, were isolated using column chromatography and preparative HPLC. Structures were determined according to (1) H and (13) C-NMR (one- and two-dimensional), electrospray ionisation-time of flight (ESI-TOF), electrospray ionisation-ion trap (ESI-MS(n) ) and circular dichroism (CD) spectra, together with acidic hydrolysis products analysis. HPTLC on RP-18 modified plates and HPLC-DAD-MS(n) on RP-18 column methods were developed for separation of the five main ellagitannins. Copyright © 2012 John Wiley & Sons, Ltd.

Integrable nonlinear Schrödinger system on a lattice with three structural elements in the unit cell

NASA Astrophysics Data System (ADS)

Vakhnenko, Oleksiy O.

2018-05-01

Developing the idea of increasing the number of structural elements in the unit cell of a quasi-one-dimensional lattice as applied to the semi-discrete integrable systems of nonlinear Schrödinger type, we construct the zero-curvature representation for the general integrable nonlinear system on a lattice with three structural elements in the unit cell. The integrability of the obtained general system permits to find explicitly a number of local conservation laws responsible for the main features of system dynamics and in particular for the so-called natural constraints separating the field variables into the basic and the concomitant ones. Thus, considering the reduction to the semi-discrete integrable system of nonlinear Schrödinger type, we revealed the essentially nontrivial impact of concomitant fields on the Poisson structure and on the whole Hamiltonian formulation of system dynamics caused by the nonzero background values of these fields. On the other hand, the zero-curvature representation of a general nonlinear system serves as an indispensable key to the dressing procedure of system integration based upon the Darboux transformation of the auxiliary linear problem and the implicit Bäcklund transformation of field variables. Due to the symmetries inherent to the six-component semi-discrete integrable nonlinear Schrödinger system with attractive-type nonlinearities, the Darboux-Bäcklund dressing scheme is shown to be simplified considerably, giving rise to the appropriately parameterized multi-component soliton solution consisting of six basic and four concomitant components.

Significance of the Nestos Shearzone in the southern Rhodopes (Northern Greece/Southern Bulgaria)

NASA Astrophysics Data System (ADS)

Nagel, Thorsten; Schmidt, Silke; Janak, Marian; Jahn-Awe, Silke; Froitzheim, Niko; Georgiev, Neven

2010-05-01

The Nestos Shearzone can be traced over 100 kilometers and separates the two main units of the Rhodopes, the Rhodope Terrane in the hangingwall from the Pangaion-Pirin Unit in the footwall. The Rhodope Terrane consists of mingled continental and oceanic basement rocks, intruded by granitic bodies of Cenozoic age. It underwent at least amphibolite facies conditions during the Alpine orogenic cycle and several localities with preserved highpressure and/or ultrahigh-pressure rocks have been found. The age of orogenesis and metamorphism is ambiguous and several Mesozoic and Tertiary cycles may be recorded in that unit. The lowermost level immediately on top of the Nestos Shearzone (Sidironero subunit) mainly consists of rocks derived from a Jurassic arc and appears to show the youngest reported (i.e. Eocene) high-grade metamorphism (including ultra-high-pressure conditions and a subsequent migmatic stage). The underlying Pangaion-Pirin Unit beneath the Nestos Shearzone is build of marbles and Variscan gneisses of disputed Mesozoic paleogeographic position. It is intruded by Oligocene granitoids, which also crosscut the Nestos Shearzone. The Pangaion-Pirin Unit experienced a clockwise PT-path culminating at upper greenschist facies conditions during the Alpine cycle. The Nestos Shearzone is defined by top-to-the-southwest-directed mylonites formed under upper greenschist facies conditions. So far, it has been viewed as a thrust. We present structural and petrological data suggesting that the Nestos Shearzone instead represents a major detachment horizon related to late Eo-Oligocene normal faults in the overlying units. Mylonitisation along the shear zone occurred under conditions postdating peak pressures. The shear zone formed between about 40 Ma and 34 Ma as indicated by the age of high temperature conditions in the hangingwall and the age of Oligocene granitoids crosscutting the mylonites. During this time, pronounced extension and basin formation took place in the hangingwall of the Nestos Shearzone. We propose that the brittle Mesta detachment, which bounds the Mesta Graben to the East, roots into the Nestos Shearzone. Themetamorphic history of the Pangaion-Pirin Unit as well as the proposed young age of the Nestos Shearzone is in conflict with studies proposing that this unit represents an independent microcontinent (Drama) accreted to the future Rhodopes in late Jurassic or early Cretaceous times. Instead, we propose that the Pangaion-Pirin Unit could be derived from the Apulian plate, which would have far reaching consequences for the structural architecture of the Hellenic orogen.

Performance evaluation of the Fiber Bragg Grating (FBG) sensing device and comparison with piezoelectric sensors for AE detection

NASA Astrophysics Data System (ADS)

Zhang, Chuang; Bond, Leonard J.

2017-02-01

Structural health monitoring (SHM) of engineering structures in service has assumed a significant role in assessing their safety and integrity. Several sensing modalities have been developed to monitor cracking, using acoustic emission (AE). Piezoelectric sensors are commonly used in AE systems, however, for some applications there are limitations and challenges. One alternative approach that is being investigated is using Fiber Bragg Grating (FBG) sensors which have emerged as a reliable, in situ and nondestructive tool in some applications for monitoring and diagnostics in large-scale structure. The main objective of this work is to evaluate and compare the AE sensing characteristics for FBG and piezoelectric sensors. A ball drop impact is used as the source for generating waves in an Aluminum plate. The source repeatability was verified and a 4-channel FBG AE detection device was used to compare with the response of PZT sensors, investigating amplitude and frequency response which can indicate sensitivity. The low sensitivity and slow sampling rate are identified, for the unit investigated, as the main factors limiting FBG engineering AE applications.

Risk factors and injury prevention in elite athletes: a descriptive study of the opinions of physical therapists, doctors and trainers.

PubMed

Saragiotto, Bruno T; Di Pierro, Carla; Lopes, Alexandre D

2014-01-01

Musculoskeletal injuries occur frequently in elite athletes. Understanding what professionals who work with patients with sports injuries think about prevention has been suggested as an important aspect to improve the effectiveness of programs to prevent sports injuries. To describe and characterize the opinions of physical therapists, physicians and trainers on 'risk factors' and 'prevention of injury' in elite athletes. This is a qualitative study with semi-structured interviews with members of the medical and technical department of the Brazilian delegation who participated in the Pan American Games of Guadalajara 2011. The interview was conducted using two questions: 1) "What do you think can cause injuries in athletes participating in your sport?" 2) "What do you do to prevent injuries in your sport?" The interviews were analyzed in two stages, the identification of thematic units, followed by the categorization and grouping of thematic units. We interviewed a total of 30 professionals. Regarding question 1, the main factors attributed as responsible for injury were over-training and incorrect sports techniques. Regarding question 2, the main reported strategies used to prevent injuries were muscle strengthening, nutritional counseling and guidance. The main factors affecting the appearance of lesions were over-training, incorrect sports technique, inadequate nutrition and factors related to the athlete's behavior. The main injury prevention strategies were muscle strengthening, nutritional counseling and guidance.

Sedimentology of the upper Karoo fluvial strata in the Tuli Basin, South Africa

NASA Astrophysics Data System (ADS)

Bordy, Emese M.; Catuneanu, Octavian

2001-08-01

The sedimentary rocks of the Karoo Supergroup in the Tuli Basin (South Africa) may be grouped in four stratigraphic units: the basal, middle and upper units, and the Clarens Formation. This paper presents the findings of the sedimentological investigation of the fluvial terrigenous clastic and chemical deposits of the upper unit. Evidence provided by primary sedimentary structures, palaeontological record, borehole data, palaeo-flow measurements and stratigraphic relations resulted in the palaeo-environmental reconstruction of the upper unit. The dominant facies assemblages are represented by sandstones and finer-grained sediments, which both can be interbedded with subordinate intraformational coarser facies. The facies assemblages of the upper unit are interpreted as deposits of a low-sinuosity, ephemeral stream system with calcretes and silcretes in the dinosaur-inhabited overbank area. During the deposition of the upper unit, the climate was semi-arid with sparse precipitation resulting in high-magnitude, low-frequency devastating flash floods. The current indicators of the palaeo-drainage system suggest flow direction from northwest to southeast, in a dominantly extensional tectonic setting. Based on sedimentologic and biostratigraphic evidence, the upper unit of the Tuli Basin correlates to the Elliot Formation in the main Karoo Basin to the south.

Insertion of linear 8.4 μm diameter 16 channel carbon fiber electrode arrays for single unit recordings

PubMed Central

Patel, Paras R.; Na, Kyounghwan; Zhang, Huanan; Kozai, Takashi D. Y.; Kotov, Nicholas A.; Yoon, Euisik; Chestek, Cynthia A.

2016-01-01

Objective Single carbon fiber electrodes (d=8.4 μm) insulated with parylene-c and functionalized with PEDOT:pTS have been shown to record single unit activity but manual implantation of these devices with forceps can be difficult. Without an improvement in the insertion method any increase in the channel count by fabricating carbon fiber arrays would be impractical. In this study, we utilize a water soluble coating and structural backbones that allow us to create, implant, and record from fully functionalized arrays of carbon fibers with ~150 μm pitch. Approach Two approaches were tested for the insertion of carbon fiber arrays. The first method used a PEG coating that temporarily stiffened the fibers while leaving a small portion at the tip exposed. The small exposed portion (500 μm – 1 mm) readily penetrated the brain allowing for an insertion that did not require the handling of each fiber by forceps. The second method involved the fabrication of silicon support structures with individual shanks spaced 150 μm apart. Each shank consisted of a small groove that held an individual carbon fiber. Main results Our results showed that the PEG coating allowed for the chronic implantation of carbon fiber arrays in 5 rats with unit activity detected at 31 days post-implant. The silicon support structures recorded single unit activity in 3 acute rat surgeries. In one of those surgeries a stacked device with 3 layers of silicon support structures and carbon fibers was built and shown to readily insert into the brain with unit activity on select sites. Significance From these studies we have found that carbon fibers spaced at ~150 μm readily insert into the brain. This greatly increases the recording density of chronic neural probes and paves the way for even higher density devices that have a minimal scarring response. PMID:26035638

Seamount subduction at seismogenic depths: structural and metamorphic evidence from the Zagros suture zone

NASA Astrophysics Data System (ADS)

Bonnet, G.; Agard, P.; Angiboust, S.; Fournier, M.; Omrani, J.

2017-12-01

Large-scale seafloor topographic features, such as seamounts, are for the most part subducted with the downgoing oceanic plate. They are expected to critically impact the seismogenic and mechanic behavior of subduction zones, but their exact role is strongly debated (i.e., as to whether they represent barriers to propagation or asperities promoting nucleation). Rare natural examples of metamorphosed seamounts, which got sliced off the slab along the plate interface and escaped recycling into the mantle, are therefore precious witnesses to document processes operating at depths of 0-30 km. We herein report the existence of a large-scale oceanic topographic structure sandwiched in the Zagros suture zone (Siah Kuh - SK - unit), most probably a former seamount, along with other blueschist units (Angiboust et al., EPSL 2016). The main criteria for identifying this seamount are its: (1) shape: the SK unit is a 1.5-2 km thick, rounded-shaped body with a 15-20 km diameter, (2) lithologies: it is made mainly of a regular succession of massive basaltic flows, commonly as pillow basalts, minor ophiolite-type gabbros and serpentinite, together with subordinate more differenciated volcanic and plutonic rocks. (3) sedimentary cover: basalts are overlain by shallowly deposited reef limestone and deepening-up sediments with the occurrence of cherts and pelagic limestones (which points to possible subsidence). Basalts have been analyzed for trace elements and have usually a N-MORB to OIB signature, which might be explained by its potential origin as a mid-oceanic ridge seamount. HP-LT minerals (lawsonite, aragonite, blue amphiboles) found across the whole structure, particularly in zones of localized compressive deformation, indicate that this seamount was shallowly subducted at 20 km. This deformation, interpreted to be syn-subduction, is assisted by a décollement rooting in serpentinite and/or oceanic metasediments and is associated with rare cataclase in magmatic rocks. We interpret these structures as related to the internal slicing of the seamount in subduction. The presence of these soft layers may prevent seismogenic deformation, since no pseudotachylites have been found.

78 FR 79289 - Airworthiness Directives; The Boeing Company Airplanes

Federal Register 2010, 2011, 2012, 2013, 2014

2013-12-30

... leakage into the main deck cargo wire integration unit (WIU). The water flowed from the main deck floor... deck cargo wire integration unit (WIU). The water flowed from the main deck floor panels, through...

Search for giant magnetic anisotropy in transition-metal dimers on defected hexagonal boron nitride sheet

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, J.; Wang, H.; Wu, R. Q., E-mail: wur@uci.edu

2016-05-28

Structural and magnetic properties of many transition-metal dimers embedded in a defected hexagonal boron nitride monolayer are investigated through density functional calculations to search for systems with magnetic anisotropy energies (MAEs) larger than 30meV. In particular, Ir–Ir@Dh–BN is found to have both large MAE (∼126 meV) and high structural stability against dissociation and diffusion, and it hence can serve as magnetic unit in spintronics and quantum computing devices. This giant MAE mainly results from the spin orbit coupling and the magnetization of the upper Ir atom, which is in a rather isolated environment.

Study and evaluation of ferro-cement for use in wind tunnel construction

NASA Technical Reports Server (NTRS)

Larsen, H. J., Jr. (Compiler)

1972-01-01

The structural suitability and cost effectiveness of ferro-cement for large subsonic wind tunnel structures is investigated. This investigation was carried out in the following four main categories: (1) a state-of-the-art survey into the uses, properties, and costs of ferro-cement; (2) an evaluation of those ferro-cement properties critical to construction of large, subsonic wind tunnels, which have not been adequately established to date; (3) a laboratory testing program to determine preliminary values for those properties; and (4) a study to establish cost factors for ferro-cement as related to a preliminary construction scheme for a nacelle and shroud unit.

46 CFR 108.401 - Fire main system.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 46 Shipping 4 2013-10-01 2013-10-01 false Fire main system. 108.401 Section 108.401 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS DESIGN AND EQUIPMENT Fire Extinguishing Systems § 108.401 Fire main system. Each unit must have a fire main system. ...

46 CFR 108.401 - Fire main system.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 4 2010-10-01 2010-10-01 false Fire main system. 108.401 Section 108.401 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS DESIGN AND EQUIPMENT Fire Extinguishing Systems § 108.401 Fire main system. Each unit must have a fire main system. ...

46 CFR 108.401 - Fire main system.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 46 Shipping 4 2012-10-01 2012-10-01 false Fire main system. 108.401 Section 108.401 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS DESIGN AND EQUIPMENT Fire Extinguishing Systems § 108.401 Fire main system. Each unit must have a fire main system. ...

46 CFR 108.401 - Fire main system.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 46 Shipping 4 2014-10-01 2014-10-01 false Fire main system. 108.401 Section 108.401 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS DESIGN AND EQUIPMENT Fire Extinguishing Systems § 108.401 Fire main system. Each unit must have a fire main system. ...

46 CFR 108.401 - Fire main system.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 46 Shipping 4 2011-10-01 2011-10-01 false Fire main system. 108.401 Section 108.401 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS DESIGN AND EQUIPMENT Fire Extinguishing Systems § 108.401 Fire main system. Each unit must have a fire main system. ...

Fire fighter fatalities 1998–2001: overview with an emphasis on structure related traumatic fatalities

PubMed Central

Hodous, T; Pizatella, T; Braddee, R; Castillo, D

2004-01-01

Objective: To review the causes of all fire fighter line-of-duty-deaths from 1998 through 2001, and present recommendations for preventing fatalities within the specific subgroup of structure related events. Methods: Fire fighter fatality data from the United States Fire Administration were reviewed and classified into three main categories of injury. Investigations conducted through the National Institute for Occupational Safety and Health (NIOSH) Fire Fighter Fatality Investigation and Prevention Program provided the basis for the recommendations presented in this paper. Results: During the time period from 1998–2001, there were 410 line-of-duty deaths among fire fighters in the United States, excluding the 343 fire fighters who died at the World Trade Center on 11 September 2001. The 410 fatalities included 191 medical (non-traumatic) deaths (47%), 75 motor vehicle related fatalities (18%), and 144 other traumatic fatalities (35%). The latter group included 68 fatalities that were associated with structures which commonly involved structural collapse, rapid fire progression, and trapped fire fighters. Conclusions: Structural fires pose particular hazards to fire fighters. Additional efforts must be directed to more effectively use what we have learned through the NIOSH investigations and recommendations from published experts in the safety community, consensus standards, and national fire safety organizations to reduce fire fighter fatalities during structural fire fighting. PMID:15314049

A practical approach for calculating the settlement and storage capacity of landfills based on the space and time discretization of the landfilling process.

PubMed

Gao, Wu; Xu, Wenjie; Bian, Xuecheng; Chen, Yunmin

2017-11-01

The settlement of any position of the municipal solid waste (MSW) body during the landfilling process and after its closure has effects on the integrity of the internal structure and storage capacity of the landfill. This paper proposes a practical approach for calculating the settlement and storage capacity of landfills based on the space and time discretization of the landfilling process. The MSW body in the landfill was divided into independent column units, and the filling process of each column unit was determined by a simplified complete landfilling process. The settlement of a position in the landfill was calculated with the compression of each MSW layer in every column unit. Then, the simultaneous settlement of all the column units was integrated to obtain the settlement of the landfill and storage capacity of all the column units; this allowed to obtain the storage capacity of the landfill based on the layer-wise summation method. When the compression of each MSW layer was calculated, the effects of the fluctuation of the main leachate level and variation in the unit weight of the MSW on the overburdened effective stress were taken into consideration by introducing the main leachate level's proportion and the unit weight and buried depth curve. This approach is especially significant for MSW with a high kitchen waste content and landfills in developing countries. The stress-biodegradation compression model was used to calculate the compression of each MSW layer. A software program, Settlement and Storage Capacity Calculation System for Landfills, was developed by integrating the space and time discretization of the landfilling process and the settlement and storage capacity algorithms. The landfilling process of the phase IV of Shanghai Laogang Landfill was simulated using this software. The maximum geometric volume of the landfill error between the calculated and measured values is only 2.02%, and the accumulated filling weight error between the calculated value and measured value is less than 5%. These results show that this approach is practical for satisfactorily and reliably calculating the settlement and storage capacity. In addition, the development of the elevation lines in the landfill sections created with the software demonstrates that the optimization of the design of the structures should be based on the settlement of the landfill. Since this practical approach can reasonably calculate the storage capacity of landfills and efficiently provide the development of the settlement of each landfilling stage, it can be used for the optimizations of landfilling schemes and structural designs. Copyright © 2017 Elsevier Ltd. All rights reserved.

The crustal structure of the eastern Fennoscandian Shield and central part of the East-European platform based on seismic, regional geophysic and geological data

NASA Astrophysics Data System (ADS)

Mints, M. V.; Berzin, R. G.; Babayants, P. S.; Konilov, A. N.; Suleimanov, A. K.; Zamozhniaya, N. G.; Zlobin, V. L.

2003-04-01

The 1-EU and 4B CDP transects worked out during 1998-2002 years by "Spetsgeophyzica", together with previously developed CDP profiles, have crossed most of the main tectonic units of the eastern Fennoscandian Shield and central part of the East-European platform. They provide seismic images of the Early Precambrian crust and upper mantle from the surface to about 80 km depth (25 s). The Neoarchaean granite-greenstone complexes of the Karelia craton along the 4B profile form a series of the tectonic slices descending eastward, some of which can be traced to the Moho. The Palaeoproterozoic structures presented by two main types: (1) volcano-sedimentary (VS) and (2) granulite-gneiss (GN) belts. The Pechenga-Varzuga VS belt has been identified as overthrust-underthrust southward-dipping package. Tectonic slices formed by the Palaeoproterozoic VS belts alternating with slices of the Neoarchaean granite-gneisses form the imbricated crustal unit that extends along the eastern margin of the Neoarchaean Karelia craton. The slices dip steeply northeastward flattening and partially juxtaposing at 20 km depth at the 1-EU cross-section. This level, which can be understood as the surface of main detachment, ascends westward. An imbrication and related thickening of the crust was caused by displacement of crustal slices in western and southwestern directions because of the Palaeoproterozoic collision event. The Palaeoproterozoic Onega unit comprising VS assemblages originated in a setting of the rifted passive margin forms the northwestward displaced thrust nappe complex. It is considered initially belonging to the southern edge of the Svecofennian passive margin. The Lapland GN belt has been transected by the Polar and EGGI profiles. Both cross-sections demonstrated that it constitutes thick composite crustal-scale tectonic slice. According to geophysical data, the continuation of the Lapland GN belt beneath the platform cover of the East European Craton forms an extended arch-shaped system of the belts approximately 2000 km long. In the vicinity of Moscow the thrust-nappe structure of these belts was recently recognized from reflection seismic profiling along 1-EU profile. The work has been developed in frames of the MPR RF Program and The SVEKALAPKO project and supported by the RFBR, grant No.00-05-64241.

The role of detachment and interlayer shear zones in the structural evolution of the southern Espinhaço range, eastern Brazil

NASA Astrophysics Data System (ADS)

Kuchenbecker, Matheus; Sanglard, Júlio Carlos Destro

2018-07-01

Sedimentary rocks usually show a significant mechanical anisotropy due to its layered nature. Because of this, they play an important role controlling rock deformation and the study of the deformation partitioning caused by rheological heterogeneities becomes a crucial step to understand the inversion of sedimentary basins. The detachment and interlayer shear zones, described at southern Espinhaço range, correspond to part of the structural collection that records the compressive deformation which is associated to the Brazilian-Pan African orogeny during Gondwana amalgamation. The mechanical contrast between lithological units is the main parameter of control for the occurrence of these zones which can be found with variable thickness from millimeter interlayer shear zones to regional-sized basement-cover detachment zones. The phyllitic layers are the most incompetent lithotype among metasedimentary rocks and they play an important role in the ductile-brittle regional deformation by accommodating much of the deformation during faulting and/or folding. Even though being a more competent rock, internal interlayer shear zones and other shear structures can be found in quartzite when in contact with weaker rocks. These structures accommodate a significant amount of deformation at the southern Espinhaço range and, because of this, they are of great value in understanding the inversion of the Espinhaço basins during West Gondwana assembly. The focus of the present paper is to discuss the main situations where interlayer shear occurs, to present a brief compendium of the main structures associated to this process and to add parameters to its recognition and interpretation.

The role of post-collisional strike-slip tectonics in the geological evolution of the late Neoproterozoic volcano-sedimentary Guaratubinha Basin, southern Brazil

NASA Astrophysics Data System (ADS)

Barão, Leonardo M.; Trzaskos, Barbara; Vesely, Fernando F.; de Castro, Luís Gustavo; Ferreira, Francisco J. F.; Vasconcellos, Eleonora M. G.; Barbosa, Tiago C.

2017-12-01

The Guaratubinha Basin is a late Neoproterozoic volcano-sedimentary basin included in the transitional-stage basins of the South American Platform. The aim of this study is to investigate its tectonic evolution through a detailed structural analysis based on remote sensing and field data. The structural and aerogeophysics data indicate that at least three major deformational events affected the basin. Event E1 caused the activation of the two main basin-bounding fault zones, the Guaratubinha Master Fault and the Guaricana Shear Zone. These structures, oriented N20-45E, are associated with well-defined right-lateral to oblique vertical faults, conjugate normal faults and vertical flow structures. Progressive transtensional deformation along the two main fault systems was the main mechanism for basin formation and the deposition of thick coarse-grained deposits close to basin-borders. The continuous opening of the basin provided intense intermediate and acid magmatism as well as deposition of volcaniclastic sediments. Event E2 characterizes generalized compression, recorded as minor thrust faults with tectonic transport toward the northwest and left-lateral activation of the NNE-SSW Palmital Shear Zone. Event E3 is related to the Mesozoic tectonism associated with the South Atlantic opening, which generated diabase dykes and predominantly right-lateral strike-slip faults oriented N10-50W. Its rhomboidal geometry with long axis parallel to major Precambrian shear zones, the main presence of high-angle, strike-slip or oblique faults, the asymmetric distribution of geological units and field evidence for concomitant Neoproterozoic magmatism and strike-slip movements are consistent with pull-apart basins reported in the literature.

Spectroscopic classification of icy satellites of Saturn II: Identification of terrain units on Rhea

NASA Astrophysics Data System (ADS)

Scipioni, F.; Tosi, F.; Stephan, K.; Filacchione, G.; Ciarniello, M.; Capaccioni, F.; Cerroni, P.

2014-05-01

Rhea is the second largest icy satellites of Saturn and it is mainly composed of water ice. Its surface is characterized by a leading hemisphere slightly brighter than the trailing side. The main goal of this work is to identify homogeneous compositional units on Rhea by applying the Spectral Angle Mapper (SAM) classification technique to Rhea’s hyperspectral images acquired by the Visual and Infrared Mapping Spectrometer (VIMS) onboard the Cassini Orbiter in the infrared range (0.88-5.12 μm). The first step of the classification is dedicated to the identification of Rhea’s spectral endmembers by applying the k-means unsupervised clustering technique to four hyperspectral images representative of a limited portion of the surface, imaged at relatively high spatial resolution. We then identified eight spectral endmembers, corresponding to as many terrain units, which mostly distinguish for water ice abundance and ice grain size. In the second step, endmembers are used as reference spectra in SAM classification method to achieve a comprehensive classification of the entire surface. From our analysis of the infrared spectra returned by VIMS, it clearly emerges that Rhea’ surface units shows differences in terms of water ice bands depths, average ice grain size, and concentration of contaminants, particularly CO2 and hydrocarbons. The spectral units that classify optically dark terrains are those showing suppressed water ice bands, a finer ice grain size and a higher concentration of carbon dioxide. Conversely, spectral units labeling brighter regions have deeper water ice absorption bands, higher albedo and a smaller concentration of contaminants. All these variations reflect surface’s morphological and geological structures. Finally, we performed a comparison between Rhea and Dione, to highlight different magnitudes of space weathering effects in the icy satellites as a function of the distance from Saturn.

Structural characterization of a glucuronoarabinoxylan from pineapple (Ananas comosus (L.) Merrill) gum exudate.

PubMed

Simas-Tosin, Fernanda F; de Souza, Lauro M; Wagner, Ricardo; Pereira, Graciele C Z; Barraza, Ruth R; Wendel, Cinthia F; Sassaki, Guilherme L; Iacomini, Marcello; Gorin, Philip A J

2013-04-15

Native polysaccharide from pineapple gum (PANP) was obtained following alkaline extraction of gum and fractionation with cetylpyridinium chloride. It was characterized as a glucuronoarabinoxylan using NMR, methylation data, controlled Smith degradation, carboxy-reduction, and ESI-MS of oligosaccharides produced on mild acid hydrolysis of PANP. HSPEC-MALLS-RI of carboxy-reduced fraction showed homogeneous profile (Mw 1.943×10(5) g/mol). PANP was composed of Ara, Xyl, Gal, and GlcpA (40:23:7:30 molar ratio). Its main chain presented (1→4)-linked β-xylan, highly substituted at O-2 and O-3 by side chains of 3-O- and 3,5-di-O-linked α-Araf, 2-O- and 4-O-linked α-GlcpA, and nonreducing end-units of α-Araf, β-Arap, β-Galp, and α-GlcpA. ESI-MS of a mixture of oligosaccharides formed on the mild acid hydrolysis of PANP was consistent with repetitive structures of α-GlcpA O-3 linked at β-Xylp units, whereas in others glucuronoarabinoxylan-type gum exudates, α-GlcpA units had been previously found to be linked at O-2. Copyright © 2013 Elsevier Ltd. All rights reserved.

Summary of the San Juan structural basin regional aquifer-system analysis, New Mexico, Colorado, Arizona, and Utah

USGS Publications Warehouse

Levings, G.W.; Kernodle, J.M.; Thorn, C.R.

1996-01-01

Ground-water resources are the only source of water in most of the San Juan structural basin and are mainly used for municipal, industrial, domestic, and stock purposes. Industrial use increased dramatically during the late 1970's and early 1980's because of increased exploration and development of uranium and coal resources. The San Juan structural basin is a northwest-trending, asymmetric structural depression at the eastern edge of the Colorado Plateau. The basin contains as much as 14,000 feet of sedimentary rocks overlying a Precambrian basement complex. The sedimentary rocks dip basinward from the basin margins toward the troughlike structural center, or deepest part of the basin. Rocks of Triassic age were selected as the lower boundary for the study. The basin is well defined by structural boundaries in many places with structural relief of as much as 20,000 feet reported. Faulting is prevalent in parts of the basin with displacement of several thousand feet along major faults. The regional aquifers in the basin generally are coincident with the geologic units that have been mapped. Data on the hydrologic properties of the regional aquifers are minimal. Most data were collected on those aquifers associated with uranium and coal resource production. These data are summarized in table format in the report. The regional flow system throughout most of the basin has been affected by the production of oil or gas and subsequent disposal of produced brine. To date more than 26,000 oil- or gas- test holes have been drilled in the basin, the majority penetrating no deeper than the bottom of the Cretaceous rocks. The general water chemistry of the regional aquifers is based on available data. The depositional environments are the major factor controlling the quality of water in the units. The dominant ions are generally sodium, bicarbonate, and sulfate. A detailed geochemical study of three sandstone aquifers--Morrison, Dakota, and Gallup--was undertaken in the northwestern part of the study area. Results of this study indicate that water chemistry changed in individual wells over short periods of time, not expected in a regional flow system. The chemistry of the water is affected by mixing of recharge, ion filtrate, or very dilute ancient water, and by leakage of saline water. The entire system of ground-water flow and its controlling factors has been defined as the conceptual model. A steady-state, three-dimensional ground-water flow model was constructed to simulate modern predevelopment flow in the post-Jurassic rocks of the regional flow system. In the ground-water flow model, 14 geologic units or combinations of geologic units were considered to be regional aquifers, and 5 geologic units or combinations of geologic units were considered to be regional confining units. The model simulated flow in 12 layers (hydrostratigraphic units) and used harmonic-mean vertical leakance to indirectly simulate aquifer connection across 3 other hydrostratigraphic confining units in addition to coupling the 12 units.

Development of a transition pathway model using three traditional variables to describe the main structural characteristics of a forest stand type, size, and density

Treesearch

Chad Larson

2006-01-01

The Central Hardwood Region is a unique forest region in the United States, encompassing 340 million acres of land, of which 100 million acres are forested (Parker 1993). The region contains one-fourth of the U.S. population, with approximately 90 percent of the land in private ownership (Parker 1993). In general, private forested lands in the Central Hardwood Region...

Complete Bouguer gravity and aeromagnetic maps of the Rattlesnake Roadless Area, Missoula County, Montana

USGS Publications Warehouse

Kulik, Dolores M.

1986-01-01

The rocks in the study area consist mainly of the Helena Formation and the Missoula Group of the Belt Supergroup (Proterozoic Y).  Rock units of less importance are diabase sills and dikes of probable Proterozoic Z age, Middle Cambrian rocks, and glacial deposits.  Structurally, the study area consists of the Rattlesnake thrust system in the south part and a parautochthonous area broken by vertical faults in the north part.

Analysis of High Spatial, Temporal, and Directional Resolution Recordings of Biological Sounds in the Southern California Bight

DTIC Science & Technology

2012-09-30

tested in this research is that the evolution of unit structure and song characteristics in the population of transiting humpback whales in the Southern...behavior of transiting humpback whales in the Southern California Bight, b) the use of passive underwater acoustic techniques for improved habitat...man-made sounds on the calling behavior of transiting humpback whales in the Southern California Bight”. The main scientific hypothesis to be

Real time 3D structural and Doppler OCT imaging on graphics processing units

NASA Astrophysics Data System (ADS)

Sylwestrzak, Marcin; Szlag, Daniel; Szkulmowski, Maciej; Gorczyńska, Iwona; Bukowska, Danuta; Wojtkowski, Maciej; Targowski, Piotr

2013-03-01

In this report the application of graphics processing unit (GPU) programming for real-time 3D Fourier domain Optical Coherence Tomography (FdOCT) imaging with implementation of Doppler algorithms for visualization of the flows in capillary vessels is presented. Generally, the time of the data processing of the FdOCT data on the main processor of the computer (CPU) constitute a main limitation for real-time imaging. Employing additional algorithms, such as Doppler OCT analysis, makes this processing even more time consuming. Lately developed GPUs, which offers a very high computational power, give a solution to this problem. Taking advantages of them for massively parallel data processing, allow for real-time imaging in FdOCT. The presented software for structural and Doppler OCT allow for the whole processing with visualization of 2D data consisting of 2000 A-scans generated from 2048 pixels spectra with frame rate about 120 fps. The 3D imaging in the same mode of the volume data build of 220 × 100 A-scans is performed at a rate of about 8 frames per second. In this paper a software architecture, organization of the threads and optimization applied is shown. For illustration the screen shots recorded during real time imaging of the phantom (homogeneous water solution of Intralipid in glass capillary) and the human eye in-vivo is presented.

Perinatal mental health service provision in Switzerland and in the UK.

PubMed

Amiel Castro, Rita T; Schroeder, Katrin; Pinard, Claudia; Blöchlinger, Patricia; Künzli, Hansjörg; Riecher-Rössler, Anita; Kammerer, Martin

2015-01-01

The epidemiology of maternal perinatal-psychiatric disorders as well as their effect on the baby is well recognised. Increasingly well researched specialised treatment methods can reduce maternal morbidity, positively affect mother-baby bonding and empower women's confidence as a mother. Here, we aimed to compare guidelines and the structure of perinatal-psychiatric service delivery in the United Kingdom and in Switzerland from the government's perspective. Swiss cantons provided information regarding guidelines and structure of service delivery in 2000. A subsequent survey using the same questionnaire was carried out in 2007. In the UK, similar information was accessed through published reports from 2000-2012. Guidelines for perinatal psychiatry exist in the UK, whereas in Switzerland in 2000 none of the 26 cantons had guidelines, and in 2007 only one canton did. Joint mother-baby admissions on general psychiatric wards were offered by 92% of the Swiss cantons. In the UK, pregnant women and joint mother-baby admissions are only advised onto specialised perinatal-psychiatric units. In Switzerland, in 2007, three specialised units (max. 24 beds) were in place corresponding to 1 unit per 2.5 million people, while in the UK there were 22 mother-baby units (168 beds) in 2012 (1 unit per 2.8 million). In the UK, less than 50% of trusts provided specialised perinatal-psychiatric health care. The main difference between the UK and Switzerland was the absence of guidelines, regular assessment and plans for future development of perinatal psychiatry in Switzerland. There are still geographical differences in the provision of perinatal-psychiatric services in the UK.

Cover sequence stratigraphy and structure: Salem Church basement culmination, Georgia Blue Ridge

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, L.; Tull, J.F.

The Salem Church anticline SW of Jasper, Georgia in the western Blue Ridge is roughly an oval shaped structural dome with its long axis trending NE-SW. The anticline is cored by the Grenville age Corbin Gneiss which represents allochthonous North American basement. In debate for decades has been the age and origin of several kilometers of poly-deformed cover sequence rocks which were metamorphosed to greenschist facies and were probably transported over a long distance inland after their deposition. The stratigraphy of the cover sequence exhibits rapid lithofacies changes. At most localities, the basement is overlain by a 500--600 m thickmore » coarse clastic unit sourced from the basement rocks, composed mainly of metaconglomerate, metasandstone and metadiamictite. A thin unit less than 20 m thick of sericite phyllite occurs between the basement and the coarse clastic unit along the SE limb of the anticline but pinches out to the MW. A relatively sharp stratigraphic contact occurs between quartzite unit and overlying dark colored metagreywackes and metadiamictites containing distinctive cobbles and boulders of granitic and gneissic basement rocks up to 1 meter in length. This unit is about 100 m thick in the SW but thins rapidly towards the NE. It grades up into a geographically widespread graphitic phyllite which encircles most of the anticline. Unlike the cover sequence above the corbin basement west of Waleska, Georgia, no carbonate is found in this area.« less

NMR studies of structure, hydrogen exchange, and main-chain dynamics in a disrupted-core mutant of thioredoxin.

PubMed Central

De Lorimier, R.; Hellinga, H. W.; Spicer, L. D.

1996-01-01

Core-packing mutants of proteins often approach molten globule states, and hence may have attributes of folding intermediates. We have studied a core-packing mutant of thioredoxin, L78K, in which a leucine residue is substituted by lysine, using 15N heteronuclear two- and three-dimensional NMR. Chemical shift differences between the mutant and wild-type main-chain resonances reveal that structural changes caused by the mutation are localized within 12 A of the altered side chain. The majority of resonances are unchanged, as are many 1H-1H NOEs indicative of the main-chain fold, suggesting that the structure of L78K is largely similar to wild type. Hydrogen exchange studies reveal that residues comprising the central beta-sheet of both mutant and wild-type proteins constitute a local unfolding unit, but with the unfolding/folding equilibrium approximately 12 times larger in L78K. The dynamics of main-chain NH bonds in L78K were studied by 15N spin relaxation and compared with a previous study of wild type. Order parameters for angular motion of NH bonds in the mutant are on average lower than in wild type, suggesting greater spatial freedom on a rapid time scale, but may also be related to different rotational correlation times in the two proteins. There is also evidence of greater conformational exchange in the mutant. Differences between mutant and wild type in hydrogen exchange and main-chain dynamics are not confined to the vicinity of the mutation. We infer that mispacking of the protein core in one location affects local dynamics and stability throughout. PMID:8976564

Main-chain optically active riboflavin polymer for asymmetric catalysis and its vapochromic behavior.

PubMed

Iida, Hiroki; Iwahana, Soichiro; Mizoguchi, Tomohisa; Yashima, Eiji

2012-09-12

A novel optically active polymer consisting of riboflavin units as the main chain (poly-1) was prepared from naturally occurring riboflavin (vitamin B(2)) in three steps. The riboflavin residues of poly-1 were converted to 5-ethylriboflavinium cations (giving poly-2), which could be reversibly transformed into the corresponding 4a-hydroxyriboflavins (giving poly-2OH) through hydroxylation/dehydroxylation reactions. This reversible structural change was accompanied by a visible color change along with significant changes in the absorption and circular dichroism (CD) spectra. The nuclear Overhauser effect spectroscopy (NOESY) and CD spectra of poly-2 revealed a supramolecularly twisted helical structure with excess one-handedness through face-to-face stacking of the intermolecular riboflavinium units, as evidenced by the apparent NOE correlations between the interstrand riboflavin units and intense Cotton effects induced in the flavinium chromophore regions. The hydroxylation of poly-2 at the 4a-position proceeded in a diastereoselective fashion via chirality transfer from the induced supramolecular helical chirality assisted by the ribityl pendants, resulting in a 83:17 diastereomeric mixture of poly-2OH. The diastereoselectivity of poly-2 was remarkably higher than that of the corresponding monomeric model (64.5:35.5), indicating amplification of the chirality resulting from the supramolecular chirality induced in the stacked poly-2 backbones. The optically active poly-2 efficiently catalyzed the asymmetric organocatalytic oxidation of sulfides with hydrogen peroxide, yielding optically active sulfoxides with up to 60% enantiomeric excess (ee), whose enantioselectivity was higher than that catalyzed by the monomeric counterpart (30% ee). In addition, upon exposure to primary and secondary amines, poly-2 exhibited unique high-speed vapochromic behavior arising from the formation of 4a-amine adducts in the film.

Needs Analysis of Employee in Riau Main Island: A Reflection from Universitas Lancang Kuning Context

NASA Astrophysics Data System (ADS)

Hasnati; Chintia Utami, Bunga; Saputra, Trio

2018-05-01

Performance of employees is a major concern for all organization. It’s depend on workload. The availability of staff in Lancang Kuning University which established in Riau Main island is not adjusted to the changing needs of the Organizational Structure and the workload of the employees. One preparation to Achieve the Strategic HR Planning Is that ripe with a set amount of human resources that is ideal to get UNILAK UNGGUL 2030. But, it will not happen if the distribution of employees have not Referred to the real needs of the organization. The distribution has not been based on the workload of the organization. Stacking employees in one unit without clear work and lack of staff in other units is a fact of the underlying problem at Lancang Kuning University. So in order to Achieve the performance of employees, we must to to be done structuring. In the implementation, Lancang Kuning University conducted an analysis of positions that include positions produce information Position Information Analysis. The purpose of this study is to projection of the Needed Employees with qualitative method. The research informants were selected from three institutions / units in the University of Lancang Kuning. The results of the workload analysis of staff at the University of Lancang Kuning can be done if there is clarity of guidelines or work instructions, a good understanding of the work guidelines to everyone, the suitability between work guidelines and knowledge of educational personnel. Based on job information and workloads, it is found that only two institutions are LPPM and BPM roomates is suitable of needs but in other side there are excess and lack, library excess 1 employee.

Isotopic perspectives on the western Himalayan syntaxis

NASA Astrophysics Data System (ADS)

Argles, T. W.; Foster, G. L.; Whittington, A. G.; George, M. T.

2003-04-01

The western syntaxis has been characterised as a structural and metamorphic anomaly within the Himalaya, resulting from extreme Neogene exhumation and associated partial melting. However, an integration of detailed fieldwork with whole-rock isotopic data indicates that all the major tectonic units observed along the arc of the orogen also occur in the syntaxis. Most of the rocks exposed by the extreme exhumation have very different characteristics to their correlatives in the rest of the Himalayan mountain belt, because they represent very different crustal levels. The generally higher metamorphic grade of most syntaxial units obscures their affinities, while high strain throughout the syntaxis also conspires to mask the major tectonic faults that form boundaries to the units in the rest of the orogen. The Lesser Himalayan affinity of the gneissic core of the Nanga Parbat massif has been revealed previously using Nd isotopes. This study confirms the distinction between Lesser (E(Nd) = -20 to -29) and High (E(Nd) = -12 to -19) Himalayan rocks, but further subdivides those units with a High Himalayan Nd signature using Sr isotopic data. Some low-grade schists within the syntaxis have a relatively low 87Sr/86Sr ratio (<0.720) that distinguishes them from the High Himalayan rocks, and suggests they are metamorphic equivalents of the Tethyan sediments exposed in the main Himalayan orogen. The tectonic contact between the Lesser and High Himalayan units in the central Himalaya is the Main Central Thrust, a zone characterised by inverted metamorphism and high strain, but in the uniformly high-strain syntaxis this thrust is difficult to locate except by isotopic signatures. Extensive thermobarometric studies in the syntaxis, however, show two things. The first is the varying intensity of Neogene metamorphic overprint, whose strength is closely related to the degree of deformation (and rheology). The second is a zone of distinctly lower temperature mineral assemblages related to extensional (top-to-the-north) fabrics that straddles the boundary between the High Himalayan gneisses and the Tethyan metasediments. This extensional zone occupies the same structural position in the syntaxis as the South Tibetan Detachment System does in the central Himalaya.

Audio-magnetotelluric investigation of allochthonous iron formations in the Archaean Reguibat shield (Mauritania): structural and mining implications

NASA Astrophysics Data System (ADS)

Bronner, G.; Fourno, J. P.

1992-11-01

The M'Haoudat range, considered as an allochthonous unit amid the strongly metamorphosed Archaean basement (Tiris Group), belongs to the Lower Proterozoic Ijil Group, weakly metamorphosed, constituted mainly by iron quartzites including red jaspers and high grade iron ore. Audio-magnetotelluric (AMT) soundings (frequency range 1-7500 HZ) were performed together with the systematic survey of the range (SNIM mining company). The non-linear least squares method was used to perform a smoothness-constrained data model. The obvious AMT resistivity contrasts between the M'Haoudat Unit (150-3500 ohm. m) and the Archaean basement (20 000 ohm. m) allow to state precisely that the two thrust surfaces, on both sides of the range, join together at a depth which increases from North-West to South-East, as the ore bodies. Inside the steeply dipping M'Haoudat Unit, the main beds of iron quartzites (1500-3500 ohm. m), schists (1000-1500 ohm. m) and hematite ores (150-300 ohm. m) were distinguished when their thickness exceeded 30 to 50 m. The existence of an hydrostatic level (1-50 ohm. m) and the steeply dipping architecture, very likely responsible for the lack of resistivity contrast on the upper part of some profiles, complicate the interpretation at high frequencies the thin layers being poorly defined.

Characterization of the COL2A1 VNTR polymorphism

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berg, E.S.; Olaisen, B.

1993-05-01

The variable number of tandem repeat (VNTR) region 3{prime} to the collagen type II gene (COL2A1) was amplified in vitro by the polymerase chain reaction. Subsequent high-resolution gel electrophoresis showed that the five earlier reported alleles could be further subtyped. A total of 17 allelic variants with a heterozygosity of 73.0% were found in 202 unrelated Norwegians. DNA sequencing of 19 COL2A1 alleles has been performed. The internal organization of the VNTR was common for all alleles, as previously shown for a few alleles. Moreover, the polymorphism in the COL2A1 locus is mainly due to variation in the numbers ofmore » copies of two repeat units, containing 34 and 31 bp, respectively, and/or to small deletions in either of the two units. DNA sequencing of alleles with the same electrophoretic size revealed no heterogeneity such as an alternating order of the different units, a feature that might have been expected to be the result of unequal crossing-over events. The observed ordered structure of the VNTR and the possibility of single-stranded DNA from the cores in the VNTR forming hairpins and loops suggest that the COL2A1 polymorphism may have evolved mainly by replication slippage mechanisms. 23 refs., 2 figs., 3 tabs.« less

International Space Station Future Correlation Analysis Improvements

NASA Technical Reports Server (NTRS)

Laible, Michael R.; Pinnamaneni, Murthy; Sugavanam, Sujatha; Grygier, Michael

2018-01-01

Ongoing modal analyses and model correlation are performed on different configurations of the International Space Station (ISS). These analyses utilize on-orbit dynamic measurements collected using four main ISS instrumentation systems: External Wireless Instrumentation System (EWIS), Internal Wireless Instrumentation System (IWIS), Space Acceleration Measurement System (SAMS), and Structural Dynamic Measurement System (SDMS). Remote Sensor Units (RSUs) are network relay stations that acquire flight data from sensors. Measured data is stored in the Remote Sensor Unit (RSU) until it receives a command to download data via RF to the Network Control Unit (NCU). Since each RSU has its own clock, it is necessary to synchronize measurements before analysis. Imprecise synchronization impacts analysis results. A study was performed to evaluate three different synchronization techniques: (i) measurements visually aligned to analytical time-response data using model comparison, (ii) Frequency Domain Decomposition (FDD), and (iii) lag from cross-correlation to align measurements. This paper presents the results of this study.

Luminescent substituted fluoranthenes - synthesis, structure, electrochemical and optical properties.

PubMed

Slodek, Aneta; Maroń, Anna; Pająk, Michał; Matussek, Marek; Grudzka-Flak, Iwona; Małecki, Jan Grzegorz; Świtlicka, Anna; Krompiec, Stanisław; Danikiewicz, Witold; Grela, Małgorzata; Gryca, Izabela; Penkala, Mateusz

2018-04-16

Six novel fluoranthene derivatives, three terminally substituted and three bis(fluoranthenes) with fluorene, bithiophene and carbazole spacers were obtained via [2+2+2] cycloaddition and thoroughly characterized. Based on the conducted studies, the obtained derivatives can be classified as D-A (donor-acceptor) and A-D-A (acceptor-donor-acceptor) systems, where fluoranthene unit acts as an electron-withdrawing unit. The optical results revealed that novel fluoranthene derivatives absorb light in the range of 236-417 nm originating from ππ* transition within the conjugated system. The compounds exhibit fluorescence ranging from deep blue to green originating mainly from intramolecular charge transfer (ICT) states. The high Stoke shifts, high quantum yield in solution (φ= 0.22-0.57) and in the solid state (φ= 0.18-0.44) have been observed for fluoranthene derivatives. All derivatives possess multi-step oxidations at low potentials. The electronic structure of presented compounds is additionally supported by TD-DFT computations. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Plate-boundary kinematics in the Alps: Motion in the Arosa suture zone

NASA Astrophysics Data System (ADS)

Ring, Uwe; Ratschbacher, Lothar; Frisch, Wolfgang

1988-08-01

The Arosa zone forms a melange complex along the Penninic/Austroalpine boundary and belongs to the main Alpine suture zone. Accretion and plate collision occurred during Cretaceous and lower Tertiary time. A mixture of ophiolitic rocks and pelagic sediments is imbricated with flysch and blocks of Austroalpine (continental) derivation. We present a description of deformation structures, an analysis of strain, and a kinematic interpretation based on structural work. Deformation histories of imbricates show a translation path that was west-directed between ca. 110 and 50 Ma and north-directed thereafter. The kinematics of the Arosa zone agrees with the recently deduced displacement history of the Austroalpine units in the Eastern Alps during the Cretaceous orogeny. This calls for a predominantly top-to-the-west imbrication of Austroalpine and Penninic units and is in contradiction to what is inferred in most models of the Eastern Alps. A direct relation between the deformation along the Austroalpine margin and relative plate motion existed.

Structural model of homogeneous As–S glasses derived from Raman spectroscopy and high-resolution XPS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Golovchak, R.; Shpotyuk, O.; Mccloy, J. S.

2010-11-28

The structure of homogeneous bulk As x S 100- x (25 ≤ x ≤ 42) glasses, prepared by the conventional rocking–melting–quenching method, was investigated using high-resolution X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. It is shown that the main building blocks of their glass networks are regular AsS 3/2 pyramids and sulfur chains. In the S-rich domain, the existence of quasi-tetrahedral (QT) S = As(S 1/2) 3 units is deduced from XPS data, but with a concentration not exceeding ~3–5% of total atomic sites. Therefore, QT units do not appear as primary building blocks of the glass backbone in thesemore » materials, and an optimally-constrained network may not be an appropriate description for glasses when x < 40. Finally, it is shown that, in contrast to Se-based glasses, the ‘chain-crossing’ model is only partially applicable to sulfide glasses.« less

Wheel liner design for improved sound and structural performances

NASA Astrophysics Data System (ADS)

Oltean, Alexandru; Diaconescu, Claudiu; Tabacu, Ştefan

2017-10-01

Vehicle noise is composed mainly of wheel-road noise and noise from the power unit. At low speeds power unit noise dominates while at high speeds wheel-road noise dominates as wheel-road noise level increases approximately logarithmically with speed. The wheel liner is designed as a component of the vehicle that has a multiple role. It has to prevent the dirt or water from the road surface that are engaged by the wheel to access the engine/front bay. Same time it has the important role to reduce perceived noised in the passenger’s compartment that comes from the wheel-road interaction. Progress in plastic injection moulding technology allowed for new structures to be developed - nonwoven materials in combination with a PP based carrier structure which benefits from a cell structure caused by MuCell injection moulding. The results are light parts with increased sound absorption performances. An adapted combination of materials and production processes can provide the solution for stiff yet soundproofing structures valued for modern vehicles. Sound absorption characteristics of materials used for wheel liners applications were reported in this study. Different polypropylene and polyester fibre-based thermally bonded nonwovens varying in weight and thickness were investigated. Having as a background the performances of the nonwoven material the microcellular structure was part of the analysis. Acoustical absorptive behaviour was explained by analysing the results obtained using the impedance tube and correlating with the knowledge of materials structure.

Determination, by using GPR, of the volumetric water content in structures, sub-structures, foundations and soil - ongoing activities in Working Project 2.5 of COST Action TU1208

NASA Astrophysics Data System (ADS)

Tosti, Fabio; Slob, Evert

2015-04-01

This work will endeavour to review the current status of research activities carried out in Working Project 2.5 'Determination, by using GPR, of the volumetric water content in structures, sub-structures, foundations and soil' within the framework of Working Group 2 'GPR surveying of pavements, bridges, tunnels and buildings; underground utility and void sensing' of the COST (European COoperation in Science and Technology) Action TU1208 'Civil Engineering Applications of Ground Penetrating Radar' (www.GPRadar.eu). Overall, the Project includes 55 Participants from over 21 countries representing 33 Institutions. By considering the type of Institution, a percentage of 64% (35 units) comes from the academic world, while Research Centres and Companies include, respectively, the 27% (15 units) and 9% (5 units) of Institutions. Geographically speaking, Europe is the continent most represented with 18 out of 21 countries, followed by Africa (2 countries) and Asia (1 country). In more details and according to the Europe sub-regions classification provided by the United Nations, Southern Europe includes 39% of countries, Western Europe 27%, while Northern and Eastern Europe are equally present with 17% of countries each. Relying on the main purpose of Working Project 2.5, namely, the ground-penetrating radar-based evaluation of volumetric water content in structures, substructures , foundations, and soils, four main issues have been overall addressed over the first two years of activities. The first one, has been related to provide a comprehensive state of the art on the topic, due to the wide-ranging applications covered in the main disciplines of civil engineering, differently demanding. In this regard, two main publications reviewing the state of the art have been produced [1,2]. Secondly, discussions among Working Group Chairs and other Working Project Leaders have been undertaken and encouraged to avoid the risk of overlapping amongst similar topics from other Working Projects which directly could have dealt with moisture evaluation. As a result, independent and complementary targets have been singled out. To cite a few, interesting exchange of views took place in both the First and Second Action General Meetings of Rome and Vienna, respectively, in July 2013 and May 2014. In addition, a questionnaire with a relevant list of topics together with the identification of test scenarios for advanced comparison of inspection procedures have gathered invaluable information on the main expertises, fields of application, and equipments managed by the Project participants. The heterogeneous scenario outlined consequently, has indeed represented the third main issue to address. According to the Participants responses, roads were found to be the main target investigated (53%) so far, followed by soil materials (21%). In line with this, asphalt and compacted loose materials gathered the main interest among the main constituent materials with, respectively, 39% and 22%, as well as organic soils (22%). In this framework, the intermediate scale of investigation s, i.e., 0.01 m2 < s < 100 m2, was found to be the most used for surveying. Finally, the fourth issue has been focused at avoiding the research to get blocked by ensuring a continuous updating of the latest results in moisture assessment using ground-penetrating radar achieved by Project 2.5 Participants [3-9]. Acknowledgements The authors would like to thank COST, for funding the COST Action TU1208 'Civil Engineering Applications of Ground Penetrating Radar'. References [1] Tosti, F., Determination, by using GPR, of the volumetric water content in structures, substructures, foundations and soil. State of the art and open issues. Proceedings of the 1st COST Action General Meeting TU1208, Rome, Italy, 22-24 July 2013, pp. 99-105. ISBN: 978-88-548-6190-9. [2] Tosti, F., Slob, E.C., Determination, by using GPR, of the volumetric water content in structures, substructures, foundations and soil. In. 'Civil Engineering applications of Ground Penetrating Radar', Springer ed., 2015. [3] De Coster A., Tran A.P. and Lambot S. Information content in frequency-dependent, multi-offset GPR data for layered media reconstruction using full-wave inversion, EGU Conference, 2014, Vienna, Austria. [4] De Coster A., Tran A.P. and Lambot S. Impact of the antenna offset and the number of frequencies on layered media reconstruction using full-wave inversion in near-field conditions, GPR Conference, 2014, Brussels, Belgium. [5] De Pue J., Van Meirvenne M. and Cornelis W. Simultaneous measurement of surface and subsoil water content with air-coupled GPR, GPR Conference, 2014, Brussels, Belgium. [6] Fernandes J.M. and Pais J. Assessment of moisture in road pavements, GPR Conference, 2014, Brussels, Belgium. [7] Hugenschmidt J., Wenk F.and Brühwiler E. GPR chloride inspection of a RC bridge deck slab followed by an examination of the results, GPR Conference, 2014, Brussels, Belgium [8] Mourmeaux N., Meunier F., Tran A.P. and Lambot S. High-resolution monitoring of root water uptake dynamics in laboratory conditions using full-wave inversion of near-field radar data, EGU Conference, 2014, Vienna, Austria. [9] Mourmeaux N., Tran A.P. and Lambot S. Soil permittivity and conductivity characterization by full-wave inversion of near-field GPR data, GPR Conference, 2014, Brussels, Belgium.

Change in Sediment Provenance Near the Current Estuary of Yellow River Since the Holocene Transgression

NASA Astrophysics Data System (ADS)

Song, Sheng; Feng, Xiuli; Li, Guogang; Liu, Xiao; Xiao, Xiao; Feng, Li

2018-06-01

Sedimentary sequence and sediment provenance are important factors when it comes to the studies on marine sedimentation. This paper studies grain size distribution, lithological characteristics, major and rare earth elemental compositions, micropaleontological features and 14C ages in order to examine sedimentary sequence and sediment provenance of the core BH6 drilled at the mouth of the Yellow River in Bohai Sea. According to the grain size and the micropaleontological compositions, 4 sedimentary units have been identified. Unit 1 (0-8.08 mbsf) is of the delta sedimentary facies, Unit 2 (8.08-12.08 mbsf) is of the neritic shelf facies, Unit 3 (12.08-23.85 mbsf) is of near-estuary beach-tidal facies, and Unit 4 (23.85 mbsf-) is of the continental lake facies. The deposits from Unit 1 to Unit 3 have been found to be marine strata formed after the Holocene transgression at about 10 ka BP, while Unit 4 is continental lacustrine deposit formed before 10 ka BP. The provenances of core BH6 sediments show properties of the continental crust and vary in different sedimentary periods. For Unit 4 sediments, the source regions are dispersed while the main provenance is not clear, although the parent rock characteristics of a few samples are similar to the Luanhe River sediments. For Unit 3, sediments at 21.1-23.85 mbsf have been mainly transported from the Liaohe River, while sediments above 21.1 mbsf are mainly from the Yellow River and partially from the Liaohe River. For Unit 2, the sediments have been mainly transported from the Yellow River, with a small amount from other rivers. For Unit 1, the provenance is mainly the Yellow River catchment. These results help in better understanding the evolution of the Yellow River Delta.

Significance of the Nestos Shearzone in the southern Rhodopes (Northern Greece/Southern Bulgaria)

NASA Astrophysics Data System (ADS)

Nagel, T. J.; Schmidt, S.; Froitzheim, N.; Jahn-Awe, S.; Georgiev, N.

2009-04-01

The Nestos Shearzone can be traced over 100 kilometers and separates the two main units of the Rhodopes, the Upper Complex in the hangingwall from the Pangaion-Pirin Unit in the footwall. The Upper Complex consists of mingled continental and oceanic basement rocks, intruded by granitic bodies of Cretaceous and Tertiary age. It underwent at least amphibolite facies conditions during the Alpine orogenic cycle and several localities with preserved high-pressure and/or ultrahigh-pressure rocks have been found. The age of orogenesis and metamorphism is ambiguous and several Mesozoic and Tertiary cycles may be recorded in that unit. The lowermost level immediately on top of the Nestos Shearzone (Sidironero subunit) mainly consists of rocks derived from a Jurassic arc and appears to show the youngest reported (i.e. Eocene) high-grade metamorphism (including ultra-high-pressure conditions and a subsequent migmatic stage). The underlying Pangaion-Pirin Unit beneath the Nestos Shearzone is build of marbles and Variscan gneisses of disputed Mesozoic paleogeographic position. It is intruded by Oligocene granitoids, which also crosscut the Nestos shearzone. The Pangaion-Pirin Unit experienced only blueschist facies and subsequent upper greenschist facies conditions during the Alpine cycle. The Nestos Shearzone is defined by top-to-the-southwest-directed mylonites formed under upper greenschist facies conditions. So far, it has been viewed as a thrust. We present structural and petrological data suggesting that the Nestos Shearzone is instead a major mid-crustal detachment related to late Eo-Oligocene backarc extension. Mylonitisation along the shear zone occurred under greenschist facies conditions and postdates the blueschist facies stage. The shear zone formed between about 40 Ma and 34 Ma as indicated by the age of high temperature conditions in the hangingwall and the age of Oligocene granitoids crosscutting the mylonites. During this time, pronounced extension and basin formation took place in the hangingwall of the Nestos Shearzone. We propose that the brittle Mesta detachment, which bounds the Mesta Graben to the East, roots into the Nestos Shearzone. The metamorphic history of the Pangaion-Pirin Unit as well as the proposed young age of the Nestos Shearzone is in conflict with studies proposing that this unit represents an independent microcontinent (Drama) accreted to the future Rhodopes in late Jurassic or early Cretaceous times. Instead, we hypothesize that the Pangaion-Pirin Unit could be derived from the Apulian plate, which would have far reaching consequences for the structural architecture of the Aegean Sea area.

The Cimmerian accretionary wedge of Anarak, Central Iran

NASA Astrophysics Data System (ADS)

Zanchi, Andrea; Malaspina, Nadia; Zanchetta, Stefano; Berra, Fabrizio; Benciolini, Luca; Bergomi, Maria; Cavallo, Alessandro; Javadi, Hamid Reza; Kouhpeyma, Meyssam

2015-04-01

The occurrence in Iran of several ophiolite belts dating between Late Palaeozoic to Triassic poses several questions on the possible existence of various sutures marking the closure of the Palaeotethys ocean between Eurasia and this Gondwana-derived microplate. In this scenario, the Anarak region in Central Iran still represents a conundrum. Contrasting geochronological, paleontological, paleomagnetic data and reported field evidence suggest different origins for the Anarak Metamorphic Complex (AMC). The AMC is either interpreted, as: (1) relict of an accretionary wedge developed at the Eurasia margin during the Palaeotethys subduction as part of the Cimmerian suture zone of NE Iran, displaced to Central Iran by a large counter-clockwise rotation of the central Iranian blocks; (2) autochthonous unit forming a secondary branch of the main suture zone. Our structural, petrographic and geochemical data indicate that the AMC consists of several metamorphic units also including dismembered "ophiolites" which display different tectono-metamorphic evolutions. Three main ductile deformational events can be distinguished in the AMC. The Morghab and Chah Gorbeh complexes preserve a different M1 metamorphism, characterized by blueschist relics in the S1 foliation of the former unit, and greenschist assemblages in the latter. They share a subsequent similar D2 deformational and M2 metamorphic history, showing a prograde metamorphism with syn- to post-deformation growth of blueschist facies mineral assemblages on pre-existing greenschist facies associations. High pressure, low temperature (HP/LT) metamorphism responsible for the growth of sodic amphibole has been recognized also within marble lenses at the contact between the Chah Gorbeh Complex and serpentinites. Evidence of HP/LT metamorphism also occurs in glaucophane-bearing meta-pillow lavas and serpentinites, which contain antigorite and form most of the "ophiolites" within the AMC. Structural relationships show that the Chah Gorbeh and Morghab units and the "ophiolites" were tectonically coupled within an accretionary wedge before the D2 folding stage. The other units of the AMC lack evidence of HP metamorphism in the area around Anarak, especially the Lakh Marble, a large thrust sheet that occupies the uppermost structural position in the AMC. Available radiometric ages of trondhjemite dikes and stocks that intruded the accretionary wedge, as well as our new data, constrain the subduction event at the end of the Carboniferous, before 290 Ma. These data suggest that the AMC is part of an allochthonous crustal fragment belonging to the Variscan belt developed along the southern Eurasian margin before the Cimmerian collision of Iran. Subsequent deformational events that occurred during the Mesozoic and the Cenozoic, up to the Miocene and possibly later, resulted in folding, thrusting and faulting that dismembered the original structure of the wedge accompanying its displacement to the present day position.

Molecular analysis of proanthocyanidins related to pigmentation in brown cotton fibre (Gossypium hirsutum L.).

PubMed

Feng, Hongjie; Li, Yanjun; Wang, Shaofang; Zhang, Liangliang; Liu, Yongchuang; Xue, Fei; Sun, Yuqiang; Wang, Yongmei; Sun, Jie

2014-11-01

The structural characteristics and component differences of proanthocyanidins in brown and white cotton fibres were identified by nuclear magnetic resonance (NMR) and matrix-assisted laser desorption/ionization time of flight mass spectrometry (MALDI-TOF MS) analyses. Proanthocyanidins in brown and white cotton fibres were found to contain mainly procyanidin (PC) and prodelphidin (PD) units with 2, 3-cis form (epigallocatechin and epicatechin). However, part of the proanthocyanidins in the white cotton fibres were modified by acylation and were constitutively different from the proanthocyanidins in brown cotton fibres. The relative amount of PD was similar to that of PC in white cotton fibres, while proanthocyanidins in brown cotton fibres consisted mainly of PD units with a relative ratio of 9:1. In brown cotton fibres, the proanthocyanidin monomeric composition was consistent with the expression profiles of proanthocyanidin synthase genes, suggesting that anthocyanidin reductase represented the major flow of the proanthocyanidin biosynthesis pathway. In addition, the structural characteristics and component differences of proanthocanidins in brown and white cotton fibres suggested that quinones, the oxidation products of proanthocyanidins, were the direct contributors to colour development in brown cotton fibre. This was demonstrated by vanillin-HCl staining and Borntrager's test. Collectively, these data demonstrated that the biosynthesis of proanthocyanidins is a crucial pigmentation process in brown cotton fibre, and that quinones may represent the main pigments contributing to formation of the the brown colour. This study revealed the molecular basis of pigmentation in brown cotton fibres, and provided important insights for genetic manipulation of pigment production in cotton fibres. © The Author 2014. Published by Oxford University Press on behalf of the Society for Experimental Biology. All rights reserved. For permissions, please email: journals.permissions@oup.com.

[From empowerment to customer satisfaction: experience of a medical oncology unit].

PubMed

Cifaldi, L; Gareri, R; Cristina, G; Felicetti, V; Gremigni, U

2009-01-01

The purpose of the study was the objective assessment of the outpatients satisfaction of the Medical Oncology Unit in Colleferro (USL Roma G), Italy. A retrospective survey conducted on 584 patients using a closed questionnaire focusing on nine items assess the degree of satisfaction expressed by patients relating to the different aspects of the service. The main aspects object of analysis were the accommodation, the relationship with the staff, the comfort of the structure and the health assistance received. The survey showed a high percentage of overall satisfaction for each of the nine parameters evaluated. There were no significant differences appreciated on a personal variables. The evaluation of customer satisfaction is a useful tool to measure patients approval and to meet their needs.

Localized defects in radiation-damaged zircon

PubMed

Rios; Malcherek; Salje; Domeneghetti

2000-12-01

The crystal structure of a radiation-damaged natural zircon, ZrSiO(4) (alpha-decay radiation dose is ca 1.8 x 10(18) alpha-decay events g(-1)), has been determined. The anisotropic unit-cell swelling observed in the early stages of the amorphization process (0.17% along the a axis and 0.62% along the c axis compared with the undamaged material) is a consequence of the anisotropy of the expansion of ZrO(8) polyhedra. Larger anisotropic displacement parameters were found for Zr and O atoms, indicating that the distortion produced by alpha particle-induced localized defects mainly affects the ZrO(8) unit. The overall shape of SiO(4) tetrahedra remains essentially undistorted, while Si-O bonds are found to lengthen by 0.43%.

Smart manufacturing of complex shaped pipe components

NASA Astrophysics Data System (ADS)

Salchak, Y. A.; Kotelnikov, A. A.; Sednev, D. A.; Borikov, V. N.

2018-03-01

Manufacturing industry is constantly improving. Nowadays the most relevant trend is widespread automation and optimization of the production process. This paper represents a novel approach for smart manufacturing of steel pipe valves. The system includes two main parts: mechanical treatment and quality assurance units. Mechanical treatment is performed by application of the milling machine with implementation of computerized numerical control, whilst the quality assurance unit contains three testing modules for different tasks, such as X-ray testing, optical scanning and ultrasound testing modules. The advances of each of them provide reliable results that contain information about any failures of the technological process, any deviations of geometrical parameters of the valves. The system also allows detecting defects on the surface or in the inner structure of the component.

[Integrated Development of Full-automatic Fluorescence Analyzer].

PubMed

Zhang, Mei; Lin, Zhibo; Yuan, Peng; Yao, Zhifeng; Hu, Yueming

2015-10-01

In view of the fact that medical inspection equipment sold in the domestic market is mainly imported from abroad and very expensive, we developed a full-automatic fluorescence analyzer in our center, presented in this paper. The present paper introduces the hardware architecture design of FPGA/DSP motion controlling card+PC+ STM32 embedded micro processing unit, software system based on C# multi thread, design and implementation of double-unit communication in detail. By simplifying the hardware structure, selecting hardware legitimately and adopting control system software to object-oriented technology, we have improved the precision and velocity of the control system significantly. Finally, the performance test showed that the control system could meet the needs of automated fluorescence analyzer on the functionality, performance and cost.

Exopolysaccharides produced by Burkholderia cenocepacia recA lineages IIIA and IIIB.

PubMed

Chiarini, Luigi; Cescutti, Paola; Drigo, Laura; Impallomeni, Giuseppe; Herasimenka, Yury; Bevivino, Annamaria; Dalmastri, Claudia; Tabacchioni, Silvia; Manno, Graziana; Zanetti, Flavio; Rizzo, Roberto

2004-08-01

Clinical and environmental strains of Burkholderia cenocepacia belonging to the recA lineages IIIA and IIIB were examined for exopolysaccharide (EPS) production. The exopolysaccharides structure was determined using mainly gas chromatography coupled to mass spectrometry and NMR spectroscopy. All the strains produced Cepacian, a highly branched polysaccharide constituted of a heptasaccharide repeating unit, composed of one rhamnose, one glucose, one glucuronic acid, one mannose and three galactose residues. This polymer is the most common exopolysaccharide produced by strains of the Burkholderia cepacia (Bcc) complex. One clinical strain produced also another polysaccharide constituted of three galactose units and one 3-deoxy-D-manno-2-octulosonic acid residues, a polymer that was previously isolated from two strains of B. cepacia genomovar I and B. cenocepacia IIIA.

Traffic flow collection wireless sensor network node for intersection light control

NASA Astrophysics Data System (ADS)

Li, Xu; Li, Xue

2011-10-01

Wireless sensor network (WSN) is expected to be deployed in intersection to monitor the traffic flow continuously, and the monitoring datum can be used as the foundation of traffic light control. In this paper, a WSN based on ZigBee protocol for monitoring traffic flow is proposed. Structure, hardware and work flow of WSN nodes are designed. CC2431 from Texas Instrument is chosen as the main computational and transmission unit, and CC2591 as the amplification unit. The stability experiment and the actual environment experiment are carried out in the last of the paper. The results of experiments show that WSN has the ability to collect traffic flow information quickly and transmit the datum to the processing center in real time.

Advances in the development of remote sensing technology for agricultural applications

NASA Technical Reports Server (NTRS)

Powers, J. E.; Erb, R. B.; Hall, F. G.; Macdonald, R. B.

1979-01-01

The application of remote sensing technology to crop forecasting is discussed. The importance of crop forecasts to the world economy and agricultural management is explained, and the development of aerial and spaceborne remote sensing for global crop forecasting by the United States is outlined. The structure, goals and technical aspects of the Large Area Crop Inventory Experiment (LACIE) are presented, and main findings on the accuracy, efficiency, applicability and areas for further study of the LACIE procedure are reviewed. The current status of NASA crop forecasting activities in the United States and worldwide is discussed, and the objectives and organization of the newly created Agriculture and Resources Inventory Surveys through Aerospace Remote Sensing (AgRISTARS) program are presented.

Modeling Global Spatial-Temporal Evolution of Society: Hyperbolic Growth and Historical Cycles

NASA Astrophysics Data System (ADS)

Kurkina, E. S.

2011-09-01

The global historical processes are under consideration; and laws of global evolution of the world community are studied. The world community is considered as a united complex self-developing and self-organizing system. It supposed that the main driving force of social-economical evolution was the positive feedback between the population size and the level of technological development, which was a cause of growth in blow-up regime both of population and of global economic indexes. The study is supported by the results of mathematical modeling founded on a nonlinear heat equation with a source. Every social-economical epoch characterizes by own specific spatial distributed structures. So the global dynamics of world community during the whole history is investigated throughout the prism of the developing of spatial-temporal structures. The model parameters have been chosen so that 1) total population follows stable hyperbolic growth, consistently with the demographic data; 2) the evolution of the World-System goes through 11 stages corresponding to the main historical epochs.

The system of sulfated galactans from the red seaweed Gymnogongrus torulosus (Phyllophoraceae, Rhodophyta): Location and structural analysis.

PubMed

Estevez, José M; Ciancia, Marina; Cerezo, Alberto S

2008-09-05

Sulfated polysaccharides were localized in the cuticle, cortex and medulla of the gametophyte thallus, being more concentrated in the intercellular matrix than in the cell walls. During the water extraction sequence, a small percentage of galactan sulfates (5.1% of dry seaweed) with average low Mr (6-11.4kDa) were extracted at room temperature without disturbing the cellular arrangement, while sulfated galactans of average medium Mr (18-45kDa) were obtained by further hot-water extractions (52.4% of dry seaweed), with diorganization of the tissue. The residue (40.0% of dry seaweed) still contained carrageenan-type (major) and agaran-type (minor) galactans. Part of these galactans was extracted with 8.4% LiCl solution in DMSO, from which "pure" κ/ι-carrageenans were isolated. Carrageenans and agarans were extracted in a ratio 1:0.5, showing the highest amount of agaran-structures for a carrageenophyte. The galactans comprise alternating 4-sulfated (major) and non-sulfated (minor) 3-linked β-d-galactopyranose units, and 4-linked α-galactopyranose units with the following substitutions: (i) non-sulfated and 2-sulfated 3,6-anhydro-α-d-galactopyranose residues in the carrageenan-structures, which belong to the κ-family (κ/ι-carrageenans); (ii) 3-sulfated α-l-galactopyranose units and 2-sulfated 3,6-anhydro-α-l-galactopyranose residues in the agaran-structures. Alkaline treatment and alkaline dialysis of the main extracts gave "pure" κ/ι-carrageenans, showing that carrageenan molecules are extracted together with low Mr agarans or agaran-dl-hybrids. Copyright © 2008 Elsevier Ltd. All rights reserved.

Expression, purification, crystallization and preliminary X-ray crystallographic analysis of human histidine triad nucleotide-binding protein 2 (hHINT2)

PubMed Central

Dolot, Rafał; Włodarczyk, Artur; Bujacz, Grzegorz D.; Nawrot, Barbara

2013-01-01

Histidine triad nucleotide-binding protein 2 (HINT2) is a mitochondrial adenosine phosphoramidase mainly expressed in the pancreas, liver and adrenal gland. HINT2 possibly plays a role in apoptosis, as well as being involved in steroid biosynthesis, hepatic lipid metabolism and regulation of hepatic mitochondria function. The expression level of HINT2 is significantly down-regulated in hepatocellular carcinoma patients. To date, endogenous substrates for this enzyme, as well as the three-dimensional structure of human HINT2, are unknown. In this study, human HINT2 was cloned, overexpressed in Escherichia coli and purified. Crystallization was performed at 278 K using PEG 4000 as the main precipitant; the crystals, which belonged to the tetragonal space group P41212 with unit-cell parameters a = b = 76.38, c = 133.25 Å, diffracted to 2.83 Å resolution. Assuming two molecules in the asymmetric unit, the Matthews coefficient and the solvent content were calculated to be 2.63 Å3 Da−1 and 53.27%, respectively. PMID:23832208

Ethical problems experienced by oncology nurses1

PubMed Central

da Luz, Kely Regina; Vargas, Mara Ambrosina de Oliveira; Schmidtt, Pablo Henrique; Barlem, Edison Luiz Devos; Tomaschewski-Barlem, Jamila Geri; da Rosa, Luciana Martins

2015-01-01

Objective: to know the ethical problems experienced by oncology nurses. Method: descriptive and exploratory study with a qualitative approach, performed in inpatient units and in chemotherapy out-patients units that provide assistance to oncological patients in two capitals in the South region of Brazil. Eighteen nurses participated in this study, selected by snowball sampling type. For data collection, semi-structured interviews were carried out, which were recorded and transcribed, and then analyzed by thematic analysis. Results: two categories were established: when informing or not becomes a dilemma - showing the main difficulties related to oncological treatment information regarding health staff, health system, and infrastructure; to invest or not - dilemmas related to finitude - showing situations of dilemmas related to pain and confrontation with finitude. Conclusion: for the effective confrontation of the ethical problems experienced by oncology nurses to occur, it is important to invest in the training of these professionals, preparing them in an ethical and human way to act as lawyers of the patient with cancer, in a context of dilemmas related mainly to the possibility of finitude. PMID:26626012

Characterization of coffee (Coffea arabica) husk lignin and degradation products obtained after oxygen and alkali addition.

PubMed

de Carvalho Oliveira, Fernanda; Srinivas, Keerthi; Helms, Gregory L; Isern, Nancy G; Cort, John R; Gonçalves, Adilson Roberto; Ahring, Birgitte Kiær

2018-06-01

The full use of biomass in future biorefineries has stimulated studies on utilization of lignin from agricultural crops, such as coffee husk, a major residue from coffee processing. This study focuses on characterizing the lignin obtained from coffee husk and its further wet oxidation products as a function of alkali loading, temperature and residence time. The lignin fraction after diluted acid and alkali pretreatments is composed primarily of p-hydroxylphenyl units (≥49%), with fewer guaiacyl and syringyl units. Linkages appear to be mainly β-O-4 ether linkages. Thermal degradation of pretreated lignin during wet oxidation occurred in two stages. Carboxylic acids were the main degradation product. Due to the condensed structure of this lignin, relatively low yields of aromatic aldehydes were achieved, except with temperatures over 210 °C, 5 min residence time and 11.7 wt% NaOH. Optimization of the pretreatment and oxidation parameters are important to maximizing yield of high-value bioproducts from lignin. Copyright © 2018. Published by Elsevier Ltd.

Fine Structure of Tibetan Kefir Grains and Their Yeast Distribution, Diversity, and Shift

PubMed Central

Lu, Man; Wang, Xingxing; Sun, Guowei; Qin, Bing; Xiao, Jinzhou; Yan, Shuling; Pan, Yingjie; Wang, Yongjie

2014-01-01

Tibetan kefir grains (TKGs), a kind of natural starter for fermented milk in Tibet, China, host various microorganisms of lactic acid bacteria, yeasts, and occasionally acetic acid bacteria in a polysaccharide/protein matrix. In the present study, the fine structure of TKGs was studied to shed light on this unusual symbiosis with stereomicroscopy and thin sections. The results reveal that TKGs consist of numerous small grain units, which are characterized by a hollow globular structure with a diameter between 2.0 and 9.0 mm and a wall thickness of approximately 200 µm. A polyhedron-like net structure, formed mainly by the bacteria, was observed in the wall of the grain units, which has not been reported previously to our knowledge. Towards the inside of the grain unit, the polyhedron-like net structures became gradually larger in diameter and fewer in number. Such fine structures may play a crucial role in the stability of the grains. Subsequently, the distribution, diversity, and shift of yeasts in TKGs were investigated based on thin section, scanning electron microscopy, cloning and sequencing of D1/D2 of the 26S rRNA gene, real-time quantitative PCR, and in situ hybridization with specific fluorescence-labeled oligonucleotide probes. These show that (i) yeasts appear to localize on the outer surface of the grains and grow normally together to form colonies embedded in the bacterial community; (ii) the diversity of yeasts is relatively low on genus level with three dominant species – Saccharomyces cerevisiae, Kluyveromyces marxianus, and Yarrowia lipolytica; (iii) S. cerevisiae is the stable predominant yeast species, while the composition of Kluyveromyces and Yarrowia are subject to change over time. Our results indicate that TKGs are relatively stable in structure, and culture conditions to some extent shape the microbial community and interaction in kefir grains. These findings pave the way for further study of the specific symbiotic associations between S. cerevisiae and Lactobacillus bacteria in TKGs. PMID:24977409

Sedimentology and composition of sands injected during the seismic crisis of May 2012 (Emilia, Italy): clues for source layer identification and liquefaction regime

NASA Astrophysics Data System (ADS)

Fontana, D.; Lugli, S.; Marchetti Dori, S.; Caputo, R.; Stefani, M.

2015-07-01

In May 2012 widespread sand blows formed along buried channels in the eastern sector of the Po Plain (Northern Italy) as a consequence of a series of seismic events with main shocks of Mw 6.1 and 5.9. At San Carlo (Ferrara) a trench dug a few week after the earthquakes exposed sand dikes cutting through an old Reno River channel-levee system that was diverted in the 18th century and was deposited starting from the 14th century (unit A). This sequence overlies a Holocene muddy floodplain deposits and contains scattered sandy channel deposits (unit B) and a Pleistocene channel sand unit (unit C). Sands with inverse and normal grading, concave layering and vertical lamination coexisting along the dikes suggest multiple rhythmic opening and closing of the fractures that were injected and filled by a slurry of sand during the compression pulses, and emptied during the extension phase. The pulse mechanism may have lasted for several minutes and formed well stratified sand volcanoes structures that formed at the top of the fractures. Sands from dikes and from the various units show well defined compositional fields from lithoarenitic to quartz-feldspar-rich compositions. Sands from the old Reno levee and channel fill (unit A) have abundant lithic fragments derived from the erosion of Apennine sedimentary carbonate and terrigenous successions. Composition of the sand filling the dikes show clear affinities with sand layers of the old Reno River channel (Unit A) and clearly differ from any sand from deeper Holocene and Pleistocene layers (Unit B and C), which are richer in quartz and feldspar and poorer in sedimentary lithic fragments. Sorting related to sediment flux variations did not apparently affect the sand composition across the sedimentary structures. Textural and compositional data indicate that the liquefaction processes originated from a relatively shallow source consisting of channel sands located within Unit A at 6.8.to 7.5 m depth.

Effect of the Sintering Temperature on the Formation of Ferroelectric Properties of a Lead Zirconate-Titanate Ceramic

NASA Astrophysics Data System (ADS)

Barabanova, E. V.; Topchiev, A. A.; Malyshkina, O. V.

2018-04-01

Effect of the sintering temperature on the formation of the microstructure, the domain structure, and the ferroelectric properties of a lead zirconate-titanate Pb(Ti x Zr1 - x )O3 piezoelectric ceramics has been studied. It is shown that the ferroelectric phase forms at a sintering temperature of 860°C. At higher sintering temperatures, the main effect on the properties is due to a unit cell deformation and free charge carriers.

Structural features of northern Tarim basin: Implications for regional tectonics and petroleum traps

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dong Jia; Juafu Lu; Dongsheng Cai

1998-01-01

The rhombus-shaped Tarim basin in northwestern China is controlled mainly by two left-lateral strike-slip systems: the northeast-trending Altun fault zone along its southeastern side and the northeast-trending Aheqi fault zone along its northwestern side. In this paper, we discuss the northern Tarim basin`s structural features, which include three main tectonic units: the Kalpin uplift, the Kuqa depression, and the North Tarim uplift along the northern margin of the Tarim basin. Structural mapping in the Kalpin uplift shows that a series of imbricated thrust sheets have been overprinted by strike-slip faulting. The amount of strike-slip displacement is estimated to be 148more » km by restoration of strike-slip structures in the uplift. The Kuqa depression is a Mesozoic-Cenozoic foredeep depression with well-developed flat-ramp structures and fault-related folds. The Baicheng basin, a Quaternary pull-apart basin, developed at the center of the Kuqa depression. Subsurface structures in the North Tarim uplift can be divided into the Mesozoic-Cenozoic and the Paleozoic lithotectonic sequences in seismic profiles. The Paleozoic litho-tectonic sequence exhibits the interference of earlier left-lateral and later right-lateral strike-slip structures. Many normal faults in the Mesozoic-Cenozoic litho-tectonic sequence form the negative flower structures in the North Tarim uplift; these structures commonly directly overlie the positive flower structures in the Paleozoic litho-tectonic sequence. The interference regions of the northwest-trending and northeast-trending folds in the Paleozoic tectonic sequence have been identified to have the best trap structures. Our structural analysis indicates that the Tarim basin is a transpressional foreland basin rejuvenated during the Cenozoic.« less

A new subdivision of the central Sesia Zone (Aosta Valley, Italy)

NASA Astrophysics Data System (ADS)

Giuntoli, Francesco; Engi, Martin; Manzotti, Paola; Ballèvre, Michel

2015-04-01

The Sesia Zone in the Western Alps is a continental terrane probably derived from the NW-Adriatic margin and polydeformed at HP conditions during Alpine convergence. Subdivisions of the Sesia Zone classically have been based on the dominant lithotypes: Eclogitic Micaschist Complex, Seconda Zona Diorito-Kinzigitica, and Gneiss Minuti Complex. However, recent work (Regis et al., 2014) on what was considered a single internal unit has revealed that it comprises two or more tectonic slices that experienced substantially different PTDt-evolutions. Therefore, detailed regional petrographic and structural mapping (1:3k to 1:10k) was undertaken and combined with extensive sampling for petrochronological analysis. Results allow us to propose a first tectonic scheme for the Sesia Zone between the Aosta Valley and Val d'Ayas. A set of field criteria was developed and applied, aiming to recognize and delimit the first order tectonic units in this complex structural and metamorphic context. The approach rests on three criteria used in the field: (1) Discontinuously visible metasedimentary trails (mostly carbonates) considered to be monocyclic (Permo-Mesozoic protoliths); (2) mappable high-strain zones; and (3) visible differences in the metamorphic imprint. None of these key features used are sufficient by themselves, but in combination they allow us to propose a new map that delimits main units. We propose an Internal Complex with three eclogitic sheets, each 0.5-3 km thick. Dominant lithotypes include micaschists associated with mafic rocks and minor orthogneiss. The main foliation is of HP, dipping moderately NW. Each of these sheets is bounded by (most likely monometamorphic) sediments, <10-50 m thick. HP-relics (of eclogite facies) are widespread, but a greenschist facies overprint locally is strong close to the tectonic contact to neighbouring sheets. An Intermediate Complex lies NW of the Internal Complex and comprises two thinner, wedge-shaped units termed slices. These are composed of siliceous dolomite marbles, meta-granites and -diorites with few mafic boudins. The main foliation dips SE and is of greenschist facies, but omphacite, glaucophane, and garnet occur as relics. Towards the SW, the width of the Intermediate Complex is reduced from 0.5 km to a few meters. In the External Complex several discontinuous lenses occur; these comprise 2DK-lithotypes and are aligned with greenschist facies shear zones mapped within Gneiss Minuti. By combining these features, three main sheets were delimited in the External Complex, with the main foliation being of greenschist facies and dipping moderately SE. Petrological work and in situ U-Th-Pb dating of accessory phases is underway in several of these subunits of the Sesia Zone to constrain their PTDt-history and thus their Alpine assembly. REFERENCE Regis, D., Rubatto, D., Darling, J., Cenki-Tok, B., Zucali, M., Engi, M., 2014. Multiple metamorphic stages within an eclogite-facies terrane (Sesia Zone, Western Alps) revealed by Th-U-Pb petrochronology. J.Petrol. 55, 1429-1456.

ReHypar: A Recursive Hybrid Chunk Partitioning Method Using NAND-Flash Memory SSD

PubMed Central

Park, Sung-Soon; Lim, Cheol-Su

2014-01-01

Due to the rapid development of flash memory, SSD is considered to be the replacement of HDD in the storage market. Although SSD retains several promising characteristics, such as high random I/O performance and nonvolatility, its high expense per capacity is the main obstacle in replacing HDD in all storage solutions. An alternative is to provide a hybrid structure where a small portion of SSD address space is combined with the much larger HDD address space. In such a structure, maximizing the space utilization of SSD in a cost-effective way is extremely important to generate high I/O performance. We developed ReHypar (recursive hybrid chunk partitioning) that enables improving the space utilization of SSD in the hybrid structure. The first objective of ReHypar is to mitigate the fragmentation overhead of SSD address space, by reusing the remaining free space of I/O units as much as possible. Furthermore, ReHypar allows defining several, logical data sections in SSD address space, with each of those sections being configured with the different I/O unit. We integrated ReHypar with ext2 and ext4 and evaluated it using two public benchmarks including IOzone and Postmark. PMID:24987741

Synthesis and structure of U(VI), Np(VI), and Pu(VI) propionates

NASA Astrophysics Data System (ADS)

Serezhkin, V. N.; Grigor'ev, M. S.; Abdul'myanov, A. R.; Fedoseev, A. M.; Serezhkina, L. B.

2015-11-01

Crystals of [ AnO2(C2H5COO)2(H2O)2], where An = U (I), Np (II), or Pu (III), have been synthesized and studied by X-ray diffraction at 100 K. Compounds I-III are isostructural and crystallize in the monoclinic system, sp. gr. C2/ c, Z = 4, with the following unit-cell parameters: a = 7.4677(2), 7.4740(1), 7.512(2) Å, b = 14.2384(4), 14.1681(3), 14.182(4) Å, c = 10.5977(3), 10.5875(2), 10.607(3) Å, β = 92.384(1)°, 92.476(1)°, 92.668(17)°. Crystals I-III are composed of the mononuclear complexes [ AnO2(C2H5COO)2(H2O)2] as the main structural units belonging to the crystal-chemical group AB 01 2 M 1 2 ( A= AnO2+ 2, B 01 = C2H5COO-, M 1 = H2O). The crystal-chemical analysis of the structures of compounds of the composition UO2 L 2 · nH2O, where L is the carboxylate ion, is performed.

Risk factors and injury prevention in elite athletes: a descriptive study of the opinions of physical therapists, doctors and trainers

PubMed Central

Saragiotto, Bruno T.; Di Pierro, Carla; Lopes, Alexandre D.

2014-01-01

Background Musculoskeletal injuries occur frequently in elite athletes. Understanding what professionals who work with patients with sports injuries think about prevention has been suggested as an important aspect to improve the effectiveness of programs to prevent sports injuries. Objectives To describe and characterize the opinions of physical therapists, physicians and trainers on 'risk factors' and 'prevention of injury' in elite athletes. Method This is a qualitative study with semi-structured interviews with members of the medical and technical department of the Brazilian delegation who participated in the Pan American Games of Guadalajara 2011. The interview was conducted using two questions: 1) "What do you think can cause injuries in athletes participating in your sport?" 2) "What do you do to prevent injuries in your sport?" The interviews were analyzed in two stages, the identification of thematic units, followed by the categorization and grouping of thematic units. Results We interviewed a total of 30 professionals. Regarding question 1, the main factors attributed as responsible for injury were over-training and incorrect sports techniques. Regarding question 2, the main reported strategies used to prevent injuries were muscle strengthening, nutritional counseling and guidance. Conclusions The main factors affecting the appearance of lesions were over-training, incorrect sports technique, inadequate nutrition and factors related to the athlete's behavior. The main injury prevention strategies were muscle strengthening, nutritional counseling and guidance. PMID:24845023

Capability of ERTS-1 imagery to investigate geological and structural features in a sedimentary basin (Bassin Parisien, France)

NASA Technical Reports Server (NTRS)

Cavelier, C.; Scanvic, J. Y.; Weecksteen, G.; Zizerman, A.

1973-01-01

A preliminary study of the MSS imagery of a sedimentary basin whose structure is regular is reported. Crops and natural vegetation are distributed all over the site located under temperate climate. Ground data available concern plant species geology and tectonic and are correlated with results from ERTS 1 imagery. This comparison shows a good correlation. The main geological units are detected or enhanced by way of agricultural land use and/or natural vegetation. Alluvial deposits are outlined by vegetation grass land and poplar trees. Some spatial relationship of geostructures, suspected until now, are identified or extended in associating results from different spectral bands.

A tocotrienol series with an oxidative terminal prenyl unit from Garcinia amplexicaulis.

PubMed

Lavaud, Alexis; Richomme, Pascal; Gatto, Julia; Aumond, Marie-Christine; Poullain, Cyril; Litaudon, Marc; Andriantsitohaina, Ramaroson; Guilet, David

2015-01-01

Ten tocotrienol derivatives, i.e., amplexichromanols (1-10), were isolated from stem bark of Garcinia amplexicaulis Vieill. ex Pierre collected in Caledonia. The structures of the compounds 1-5 were determined to be chromanol derivatives substituted by a polyprenyl chain oxidized in terminal position. The remaining compounds 6-10 are the corresponding dimeric derivatives. Eleven known compounds, including xanthones, tocotrienol derivatives, triterpenes and phenolic compounds, were also isolated. Their structures were mainly determined using one and two-dimensional NMR and mass spectroscopy analysis. The compounds and some amplexichromanol molecules formerly isolated from G. amplexicaulis exhibited significant antioxidant activity against lipid peroxidation and in the ORAC assay. Copyright © 2014 Elsevier Ltd. All rights reserved.

Examination of the Reelfoot Rift Petroleum System, south-central United States, and the elements that remain for potential exploration and development

USGS Publications Warehouse

Coleman, James; Pratt, Thomas L.

2016-01-01

No production has been established in the Reel-foot rift. However, at least nine of 22 exploratory wells have reported petroleum shows, mainly gas shows with some asphalt or solid hydrocarbon residue. Regional seismic profiling shows the presence of two large inversion structures (Blytheville arch and Pascola arch). The Blytheville arch is marked by a core of structurally thickened Elvins Shale, whereas the Pascola arch reflects the structural uplift of a portion of the entire rift basin. Structural uplift and faulting within the Reelfoot rift since the late Paleozoic appear to have disrupted older conventional hydrocarbon traps and likely spilled any potential conventional petroleum accumulations. The remaining potential resources within the Reelfoot rift are likely shale gas accumulations within the Elvins Shale; however, reservoir continuity and porosity as well as pervasive faulting appear to be significant future challenges for explorers and drillers.

Evolution of groundwater chemistry along fault structures in sandstone

NASA Astrophysics Data System (ADS)

Dausse, A.; Guiheneuf, N.; Pierce, A. A.; Cherry, J. A.; Parker, B. L.

2016-12-01

Fluid-rock interaction across geological structures plays a major role on evolution of groundwater chemistry and physical properties of reservoirs. In particular, groundwater chemistry evolve on different facies according to residence times which can be linked to hydraulic properties of the geological unit. In this study, we analyze groundwater samples collected at an 11 km² site located in southern California (USA) to evaluate the evolution of groundwater chemistry according to different geological structures. Major and minor elements were sampled at the same period of time from 40 wells located along the main structures in the northeast of the site, where major NE-SW trending faults and other oriented ESE-WNW are present in sandstone Chatsworth formation. By analyzing the spatial distribution of ions concentration at the site scale, several hydrochemical compartments (main- and sub-compartments) can be distinguished and are in agreement with structural and hydrological information. In particular, as previously observed from piezometric informations, the shear zone fault serves as a barrier for groundwater flow and separates the site on two mains compartments. In addition, the analysis along major faults oriented orthogonal to this shear zone (ESE-WNW) in the eastern part of the site, shows an increase in mineralization following the hydraulic gradient. This salinization has been confirmed by ionic ratio and Gibbs plots and is attributed to fluid-rock interaction processes. In particular, groundwater chemistry seems to evolve from bicarbonate to sodium facies. Moreover, the gradient of concentrations vary depending on fault locations and can be related to their hydraulic properties and hence to different characteristic times from point to point. To conclude, major faults across the site display different degrees of groundwater chemistry evolution, linked to their physical properties, which may in turn have a large impact on contaminant transport and attenuation.

Polyoxometalates paneling through {Mo2O2S2} coordination: cation-directed conformations and chemistry of a supramolecular hexameric scaffold.

PubMed

Marrot, Jérôme; Pilette, Marie Anne; Haouas, Mohamed; Floquet, Sébastien; Taulelle, Francis; López, Xavier; Poblet, Josep M; Cadot, Emmanuel

2012-01-25

The chemical system based on the [Mo(2)O(2)S(2)(OH(2))(6)](2+) aqua cation (noted L) and the trivacant [AsW(9)O(33)](9-) polyoxometalate (noted POM) has been investigated. Depending upon the ionic strength and the nature of the alkali cations, these complementary components assemble to yield three different architectures derived as hexamer (1), tetramer (2), and dimer (3). This series of clusters displays the same stoichiometry {POM(6)L(9)}(36-), {POM(4)L(6)}(24-), and {POM(2)L(3)}(12-) for 1, 2, and 3, respectively, and their conditions of formation differ mainly by the nature and the concentration of the alkali cation (from Li to Cs). Structural characterizations of 1 reveal a large hexameric supramolecular scaffold (about 25 Å in diameter), which encloses a large internal hole (about 200 Å(3)) filled by water molecules and alkali cations (Na(+) or K(+)). The hexameric scaffold 1 exhibits a rare flexibility property evidenced in the solid state by two distinct conformations, either eclipsed (1a) or staggered-off (1b). Both conformations appear clearly separated by a large twist angle (~40°) and depend mainly on the composition of the internal hole. Structure of anion 2 shows a tetrahedral arrangement where the four POM units and the six connecting {Mo(2)O(2)S(2)} linkers are located at the corners and at the edges, respectively. The structure of anion 3 corresponds to the simplest arrangement, described as a dimeric association of two POM units linked by three {Mo(2)S(2)O(2)} pillars. Stability of the hexameric scaffold has been investigated in solution by (183)W and (39)K NMR and by UV-vis, showing that stability of 1 depends strongly on the proportion of potassium ions, which interfere through host-guest exchange. Density functional methodology (DFT) has been applied to compute the geometries and energies of dimer (3), tetramer (2) and hexamer (1) based on {AsW(9)O(33)} (POM) and {Mo(2)O(2)S(2)} (L) units. Calculations tend to show that internal cations act as "glue" to maintain the POM units connected through the conformationally inward-directed {Mo(2)O(2)S(2)} linkers. © 2011 American Chemical Society

Mesozoic intracontinental underthrust in the SE margin of the North China Block: Insights from the Xu-Huai thrust-and-fold belt

NASA Astrophysics Data System (ADS)

Shu, Liangshu; Yin, Hongwei; Faure, Michel; Chen, Yan

2017-06-01

The Xu-Huai thrust-and-fold belt, located in the southeastern margin of the North China Block, consists mainly of thrust and folded pre-Mesozoic strata. Its geodynamic evolution and tectonic setting are topics of long debate. This paper provides new evidence from geological mapping, structural analysis, and making balance cross-sections, with restoration of cross-sections. Results suggest that this belt was subjected to two-phase deformation, including an early-phase regional-scale NW-ward thrust and fold, and a late-phase extension followed by the emplacement of dioritic, monzodioritic porphyrites dated at 131-135 Ma and locally strike-slip shearing. According to the mapping, field observations and drill-hole data, three structural units were distinguished, namely, (1) the pre-Neoproterozoic crystalline basement in the eastern segment, (2) the nappe unit or the thrust-and-fold zone in the central segment, which is composed of Neoproterozoic to Ordovician carbonate rocks and Carboniferous-Permian coal-bearing rocks, about 2600 m thick, and (3) the western frontal zone. A major decollement fault has also been identified in the base of the nappe unit, on which dozen-meter to km-scale thrust-and-fold bodies were commonly developed. All pre-Mesozoic depositional sequences were involved into a widespread thrust and fold event. Six uncompetent-rock layers with biostratigraphic ages (Nanjing University, 1996) have been recognized, and each uncompetent-rock layer occurred mainly in the top of the footwall, playing an important role in the development of the Xu-Huai thrust-and-fold belt. Geometry of the major decollement fault suggests that the nappe unit of this belt was rooted in its eastern side, near the Tan-Lu Fault Zone. Two geological cross-sections were chosen for structural balancing and restoration. From the balanced cross-sections, ramp-flat and imbricated faults as well as fault-related folds were identified. A shortening of 20.6-29.6 km was obtained from restoration of balanced sections, corresponding to a shortening rate of 43.6-46.4%. This shortening deformation was likely related to the SE-ward intracontinental underthrust of the North China Block beneath the South China Block during the Mesozoic.

Genetic diversity and population structure of the tsetse fly Glossina fuscipes fuscipes (Diptera: Glossinidae) in Northern Uganda: Implications for vector control

PubMed Central

Echodu, Richard; Opiyo, Elizabeth A.; Dion, Kirstin; Halyard, Alexis; Dunn, Augustine W.; Aksoy, Serap; Caccone, Adalgisa

2017-01-01

Uganda is the only country where the chronic and acute forms of human African Trypanosomiasis (HAT) or sleeping sickness both occur and are separated by < 100 km in areas north of Lake Kyoga. In Uganda, Glossina fuscipes fuscipes is the main vector of the Trypanosoma parasites responsible for these diseases as well for the animal African Trypanosomiasis (AAT), or Nagana. We used highly polymorphic microsatellite loci and a mitochondrial DNA (mtDNA) marker to provide fine scale spatial resolution of genetic structure of G. f. fuscipes from 42 sampling sites from the northern region of Uganda where a merger of the two disease belts is feared. Based on microsatellite analyses, we found that G. f. fuscipes in northern Uganda are structured into three distinct genetic clusters with varying degrees of interconnectivity among them. Based on genetic assignment and spatial location, we grouped the sampling sites into four genetic units corresponding to northwestern Uganda in the Albert Nile drainage, northeastern Uganda in the Lake Kyoga drainage, western Uganda in the Victoria Nile drainage, and a transition zone between the two northern genetic clusters characterized by high level of genetic admixture. An analysis using HYBRIDLAB supported a hybrid swarm model as most consistent with tsetse genotypes in these admixed samples. Results of mtDNA analyses revealed the presence of 30 haplotypes representing three main haplogroups, whose location broadly overlaps with the microsatellite defined clusters. Migration analyses based on microsatellites point to moderate migration among the northern units located in the Albert Nile, Achwa River, Okole River, and Lake Kyoga drainages, but not between the northern units and the Victoria Nile drainage in the west. Effective population size estimates were variable with low to moderate sizes in most populations and with evidence of recent population bottlenecks, especially in the northeast unit of the Lake Kyoga drainage. Our microsatellite and mtDNA based analyses indicate that G. f. fuscipes movement along the Achwa and Okole rivers may facilitate northwest expansion of the Rhodesiense disease belt in Uganda. We identified tsetse migration corridors and recommend a rolling carpet approach from south of Lake Kyoga northward to minimize disease dispersal and prevent vector re-colonization. Additionally, our findings highlight the need for continuing tsetse monitoring efforts during and after control. PMID:28453513

The Mt. Ochi melange (South Evvia Island, Greece): a case study for HP metamorphism and syn-convergent exhumation.

NASA Astrophysics Data System (ADS)

Moustaka, Eleni; Soukis, Konstantinos; Huet, Benjamin; Lozios, Stylianos; Magganas, Andreas

2014-05-01

The Attic-Cycladic complex (central Aegean Sea, Greece) experienced profound extension since at least the Oligo-Miocene boundary during which the previously thickened crust was reworked by a series of detachments forming the NE directed North Cycladic Detachment System (NCDS) and the SSW directed West Cycladic Detachment System (WCDS). South Evvia Island is located at the northwestern part of the Attic Cycladic complex linking the highly thinned and polymetamorphosed central part of the complex with mainland Greece. Furthermore, greenschists-facies retrograde metamorphism has only partially overprinted the HP mineral assemblages. Consequently, it is an ideal area to study tectonic processes associated with subduction, HP metamorphism and subsequent exhumation from eclogitic depths to the surface. Geological mapping in 1:2:000 scale revealed that the tectonostratigraphy of Mt. Ochi includes three distinct units all metamorphosed in HP conditions followed by greenschist facies overprint. These units are from top to bottom a) the Ochi Unit, a thick metavolcanosedimentary sequence with some intensely folded cipoline marble intercalations and isolated occurrences of metabasic rocks b) the ophiolitic mélange (metagabbros, metawherlites, peridotites, metabasites within a metasedimentary+serpentinite matrix) and c) the lowermost Styra Unit, a cipoline marble-dominated unit with thin mica schists and rare quartzitic layers often boudinaged. The thrust fault that was responsible for the juxtaposition of these three units acted in an early stage during HP metamorphism and it was isoclinally folded and sheared by the following syn-metamorphic deformation events. Detailed structural study in meso- and microscopic scale combined with petrological and geochemical analyses of the Mt Ochi rocks led to the distinction of at least three syn-metamorphic and two post-metamorphic deformation episodes that affected all units. The oldest structure identified is a relic foliation formed by the mineral assemblage Na-amphibole + lawsonite seen as inclusion in epidote porphyroblasts within the melange. It could represent a structure of the prograde path but it could also have formed during the peak HP event. This is followed by successive folding episodes that are related to axial plane foliations and a ~E-W intersection/stretching lineation formed by typical blueschist- to epidote-blueschist facies mineral assemblages. The main foliation that can be observed in all three units is a greenschist-facies axial plane foliation accompanied by a ~ENE-WSW stretching lineation. The shear sense during the prograde path is constantly towards the WSW. In the greenschists-facies an unambiguous top-to ENE can be observed mostly in mylonitic rocks. The following deformation episodes include semi-brittle to brittle structures (shear bands brittle open folds, crenulation cleavage, and faults with increasingly higher-angle) that are not as penetrative and record the passage of the units through the brittle-ductile transitions and to higher structural levels. The kinematics of these late episodes is also towards the NE. Based on the above, the Mt Ochi HP units exhibit a common tectonometamorphic evolution since at least the early stages of the prograde path. The Ochi Unit/Styra Unit contact is a structure that formed prior to or during peak HP metamorphism and therefore it couldn't have served as the normal fault to an extrusion wedge.

Locomotive Emission and Engine Idle Reduction Technology Demonstration Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

John R. Archer

2005-03-14

In response to a United States Department of Energy (DOE) solicitation, the Maryland Energy Administration (MEA), in partnership with CSX Transportation, Inc. (CSXT), submitted a proposal to DOE to support the demonstration of Auxiliary Power Unit (APU) technology on fifty-six CSXT locomotives. The project purpose was to demonstrate the idle fuel savings, the Nitrous Oxide (NOX) emissions reduction and the noise reduction capabilities of the APU. Fifty-six CSXT Baltimore Division locomotives were equipped with APUs, Engine Run Managers (ERM) and communications equipment to permit GPS tracking and data collection from the locomotives. Throughout the report there is mention of themore » percent time spent in the State of Maryland. The fifty-six locomotives spent most of their time inside the borders of Maryland and some spent all their time inside the state borders. Usually when a locomotive traveled beyond the Maryland State border it was into an adjoining state. They were divided into four groups according to assignment: (1) Power Unit/Switcher Mate units, (2) Remote Control units, (3) SD50 Pusher units and (4) Other units. The primary data of interest were idle data plus the status of the locomotive--stationary or moving. Also collected were main engine off, idling or working. Idle data were collected by county location, by locomotive status (stationary or moving) and type of idle (Idle 1, main engine idling, APU off; Idle 2, main engine off, APU on; Idle 3, main engine off, APU off; Idle 4, main engine idle, APU on). Desirable main engine idle states are main engine off and APU off or main engine off and APU on. Measuring the time the main engine spends in these desirable states versus the total time it could spend in an engine idling state allows the calculation of Percent Idle Management Effectiveness (%IME). IME is the result of the operation of the APU plus the implementation of CSXT's Warm Weather Shutdown Policy. It is difficult to separate the two. The units demonstrated an IME of 64% at stationary idle for the test period. The data collected during calendar year 2004 demonstrated that 707,600 gallons of fuel were saved and 285 tons of NOX were not emitted as a result of idle management in stationary idle, which translates to 12,636 gallons and 5.1 tons of NOx per unit respectively. The noise reduction capabilities of the APU demonstrated that at 150 feet from the locomotive the loaded APU with the main engine shut down generated noise that was only marginally above ambient noise level.« less

Structural analysis and thermal remote sensing of the Los Humeros Volcanic Complex: Implications for volcano structure and geothermal exploration

NASA Astrophysics Data System (ADS)

Norini, G.; Groppelli, G.; Sulpizio, R.; Carrasco-Núñez, G.; Dávila-Harris, P.; Pellicioli, C.; Zucca, F.; De Franco, R.

2015-08-01

The Los Humeros Volcanic Complex (LHVC) is an important geothermal target in the Trans-Mexican Volcanic Belt. Understanding the structure of the LHVC and its influence on the occurrence of thermal anomalies and hydrothermal fluids is important to get insights into the interplay between the volcano-tectonic setting and the characteristics of the geothermal resources in the area. In this study, we present a structural analysis of the LHVC, focused on Quaternary tectonic and volcano-tectonic features, including the areal distribution of monogenetic volcanic centers. Morphostructural analysis and structural field mapping revealed the geometry, kinematics and dynamics of the structural features in the study area. Also, thermal infrared remote sensing analysis has been applied to the LHVC for the first time, to map the main endogenous thermal anomalies. These data are integrated with newly proposed Unconformity Bounded Stratigraphic Units, to evaluate the implications for the structural behavior of the caldera complex and geothermal field. The LHVC is characterized by a multistage formation, with at least two major episodes of caldera collapse: Los Humeros Caldera (460 ka) and Los Potreros Caldera (100 ka). The study suggests that the geometry of the first collapse recalls a trap-door structure and impinges on a thick volcanic succession (10.5-1.55 Ma), now hosting the geothermal reservoir. The main ring-faults of the two calderas are buried and sealed by the widespread post-calderas volcanic products, and for this reason they probably do not have enough permeability to be the main conveyers of the hydrothermal fluid circulation. An active, previously unrecognized fault system of volcano-tectonic origin has been identified inside the Los Potreros Caldera. This fault system is the main geothermal target, probably originated by active resurgence of the caldera floor. The active fault system defines three distinct structural sectors in the caldera floor, where the occurrence of hydrothermal fluids is controlled by fault-induced secondary permeability. The resurgence of the caldera floor could be induced by an inferred magmatic intrusion, representing the heat source of the geothermal system and feeding the simultaneous monogenetic volcanic activity around the deforming area. The operation of the geothermal field and the plans for further exploration should focus on, both, the active resurgence fault system and the new endogenous thermal anomalies mapped outside the known boundaries of the geothermal field.

Systems to support health technology assessment (HTA) in member states of the European union with limited institutionalization of HTA.

PubMed

Moharra, Montse; Espallargues, Mireia; Kubesch, Nadine; Estrada, Maria-Dolors; Parada, Antoni; Vondeling, Hindrik; Lo Scalzo, Alessandra; Cristofides, Stelios; Turk, Eva; Raab, Martin

2009-12-01

The aim of this study was to support health technology assessment (HTA) capacity building in Member States of the European Union with limited experience or without institutionalized HTA. The main output is a Handbook on HTA Capacity Building. The methods used were worldwide surveys of (i) HTA organizations, (ii) information management units, and (iii) HTA educational programs. The results of two surveys (i & ii) were combined with expert opinion to produce the Handbook on HTA Capacity Building. Survey of HTA organizations (n = 41, response rate 35 percent). Most of the organizations were established by the government (61 percent), and all were not-for-profit. Working on HTA (80.5 percent) and doing research (63.4 percent) were the main lines of activity. Survey on information management units (n = 23, response rate 23 percent). Most (74.2 percent) of the responding HTA agencies reported having personnel dedicated to HTA information services. Survey on HTA educational programs (n = 48, response rate 60 percent). In total, nine Master of Science (MSc) programs were identified (three MSc in HTA and six MSc in HTA-related areas). Handbook on HTA Capacity Building. A group of twenty experts from thirteen countries developed the handbook. It consists of nine chapters focusing on HTA institutional development (structural setup, work processes, and visibility). Setting up organizational structures and establishing effective HTA programs that guide key policy decisions is a challenging task. There are no standard models or pathways. "One size fits all" is not a useful principle because of the wide systemic and cultural differences between countries. The Handbook on HTA Capacity Building includes approaches for overall institutional development, especially in formulating objectives, setting up structures, and defining work processes.

Development of structural diagram of automated dispatch control system for power consumption at non-ferrous metallurgy enterprises

NASA Astrophysics Data System (ADS)

Klyuev, R. V.; Bosikov, I. I.; Madaeva, M. Z.; A-V Turluev, R.

2018-03-01

The structural scheme of the automated control system of power consumption at the industrial enterprise is developed in the article. At the non-ferrous metallurgy enterprise, an energy inspection and a rank analysis of the electrical energy consumption of the main processing equipment were carried out. It is established that the enterprises of non-ferrous metallurgy are a complex process system consisting of a set of thousands of jointly functioning technological facilities. For the most effective estimation of power consumption of enterprises, it is reasonable to use the automated system of dispatching control of power consumption (ASDCPC). The paper presents the results of the development of the ASDCPC structural diagram that allows one to perform on-line control and management of the energy and process parameters of the main production units and the enterprise as a whole. As a result of the introduction of ASDCPC at the non-ferrous metallurgy enterprise, the consumed active power was reduced during the peak hours of the load by 20%, the specific electricity consumption - by 14%, the cost of the energy component in the cost of production of hard alloys - by 3%.

Joint inversion of seismic and gravity data for imaging seismic velocity structure of the crust and upper mantle beneath Utah, United States

NASA Astrophysics Data System (ADS)

Syracuse, E. M.; Zhang, H.; Maceira, M.

2017-10-01

We present a method for using any combination of body wave arrival time measurements, surface wave dispersion observations, and gravity data to simultaneously invert for three-dimensional P- and S-wave velocity models. The simultaneous use of disparate data types takes advantage of the differing sensitivities of each data type, resulting in a comprehensive and higher resolution three-dimensional geophysical model. In a case study for Utah, we combine body wave first arrivals mainly from the USArray Transportable Array, Rayleigh wave group and phase velocity dispersion data, and Bouguer gravity anomalies to invert for crustal and upper mantle structure of the region. Results show clear delineations, visible in both P- and S-wave velocities, between the three main tectonic provinces in the region. Without the inclusion of the surface wave and gravity constraints, these delineations are less clear, particularly for S-wave velocities. Indeed, checkerboard tests confirm that the inclusion of the additional datasets dramatically improves S-wave velocity recovery, with more subtle improvements to P-wave velocity recovery, demonstrating the strength of the method in successfully recovering seismic velocity structure from multiple types of constraints.

Advance Care Planning in palliative care: a qualitative investigation into the perspective of Paediatric Intensive Care Unit staff.

PubMed

Mitchell, Sarah; Dale, Jeremy

2015-04-01

The majority of children and young people who die in the United Kingdom have pre-existing life-limiting illness. Currently, most such deaths occur in hospital, most frequently within the intensive care environment. To explore the experiences of senior medical and nursing staff regarding the challenges associated with Advance Care Planning in relation to children and young people with life-limiting illnesses in the Paediatric Intensive Care Unit environment and opportunities for improvement. Qualitative one-to-one, semi-structured interviews were conducted with Paediatric Intensive Care Unit consultants and senior nurses, to gain rich, contextual data. Thematic content analysis was carried out. UK tertiary referral centre Paediatric Intensive Care Unit. Eight Paediatric Intensive Care Unit consultants and six senior nurses participated. Four main themes emerged: recognition of an illness as 'life-limiting'; Advance Care Planning as a multi-disciplinary, structured process; the value of Advance Care Planning and adverse consequences of inadequate Advance Care Planning. Potential benefits of Advance Care Planning include providing the opportunity to make decisions regarding end-of-life care in a timely fashion and in partnership with patients, where possible, and their families. Barriers to the process include the recognition of the life-limiting nature of an illness and gaining consensus of medical opinion. Organisational improvements towards earlier recognition of life-limiting illness and subsequent Advance Care Planning were recommended, including education and training, as well as the need for wider societal debate. Advance Care Planning for children and young people with life-limiting conditions has the potential to improve care for patients and their families, providing the opportunity to make decisions based on clear information at an appropriate time, and avoid potentially harmful intensive clinical interventions at the end of life. © The Author(s) 2015.

Interior view, main entry lobby on Fourteenth Street United ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Interior view, main entry lobby on Fourteenth Street - United States Department of Commerce, Bounded by Fourteenth, Fifteenth, and E streets and Constitution Avenue, Washington, District of Columbia, DC

Effect of intensive care unit organizational model and structure on outcomes in patients with acute lung injury.

PubMed

Treggiari, Miriam M; Martin, Diane P; Yanez, N David; Caldwell, Ellen; Hudson, Leonard D; Rubenfeld, Gordon D

2007-10-01

Prior studies supported an association between intensive care unit (ICU) organizational model or staffing patterns and outcome in critically ill patients. To examine the association of closed versus open models with patient mortality across adult ICUs in King County (WA). Cohort study of patients with acute lung injury (ALI). ICU structure, organization, and patient care practices were assessed using self-administered mail questionnaires completed by the medical director and nurse manager. We defined closed ICUs as units that required patient transfer to or mandatory patient comanagement by an intensivist and open ICUs as those relying on other organizational models. Outcomes were obtained from the King County Lung Injury Project, a population-based cohort of patients with ALI. The main endpoint was hospital mortality. Of 24 eligible ICUs, 13 ICUs were designated closed and 11 open. Complete survey data were available for 23 (96%) ICUs. Higher physician and nurse availability was reported in closed versus open ICUs. A total of 684 of 1,075 (63%) of patients with ALI were cared for in closed ICUs. After adjusting for potential confounders, patients with ALI cared for in closed ICUs had reduced hospital mortality (adjusted odds ratio, 0.68; 95% confidence interval, 0.53, 0.89; P = 0.004). Consultation by a pulmonologist in open ICUs was not associated with improved mortality (adjusted odds ratio, 0.94; 95% confidence interval, 0.74, 1.20; P = 0.62). These findings were robust for varying assumptions about the study population definition. Patients with ALI cared for in a closed-model ICU have reduced mortality. These data support recommendations to implement structured intensive care in the United States.

Styrene-spaced copolymers including anthraquinone and β-O-4 lignin model units: synthesis, characterization and reactivity under alkaline pulping conditions.

PubMed

Megiatto, Jackson D; Cazeils, Emmanuel; Ham-Pichavant, Frédérique; Grelier, Stéphane; Gardrat, Christian; Castellan, Alain

2012-05-14

A series of random copoly(styrene)s has been synthesized via radical polymerization of functionalized anthraquinone (AQ) and β-O-4 lignin model monomers. The copolymers were designed to have a different number of styrene spacer groups between the AQ and β-O-4 lignin side chains aiming at investigating the distance effects on AQ/β-O-4 electron transfer mechanisms. A detailed molecular characterization, including techniques such as size exclusion chromatography, MALDI-TOF mass spectrometry, and (1)H, (13)C, (31)P NMR and UV-vis spectroscopies, afforded quantitative information about the composition of the copolymers as well as the average distribution of the AQ and β-O-4 groups in the macromolecular structures. TGA and DSC thermal analysis have indicated that the copolymers were thermally stable under regular pulping conditions, revealing the inertness of the styrene polymer backbone in the investigation of electron transfer mechanisms. Alkaline pulping experiments showed that close contact between the redox active side chains in the copolymers was fundamental for an efficient degradation of the β-O-4 lignin model units, highlighting the importance of electron transfer reactions in the lignin degradation mechanisms catalyzed by AQ. In the absence of glucose, AQ units oxidized phenolic β-O-4 lignin model parts, mainly by electron transfer leading to vanillin as major product. By contrast, in presence of glucose, anthrahydroquinone units (formed by reduction of AQ) reduced the quinone-methide units (issued by dehydration of phenolic β-O-4 lignin model part) mainly by electron transfer leading to guaiacol as major product. Both processes were distance dependent.

Folding pattern in the Fars province, Zagros folded belt: case study on the Karbasi and Khaftar anticlines, interior Fars, Iran

NASA Astrophysics Data System (ADS)

Maleki, Z.; Arian, M.; Solgi, A.

2015-08-01

The anticlines in Fars region, which are located in Zagros fold-thrust belt, are valuable because they possess several hydrocarbons and this area is easily recognized by the NW-SE trending parallel anticlines that verge to the SW. According to the geological classification, the study area is located in Interior Fars region. Due to increasing complication of structural geometry in Fars region and necessity to explore activities for deeper horizons especially the Paleozoic ones, the analysis of fold style elements, which is known as one of the main parts in structural studies, seems necessary. The Karbasi and Khaftar anticlines are case study anticlines in the interior Fars sub-basin (Fassa area). These anticlines have an asymmetric structure and some faults with large strike separation are observed in these structures. Due to increasing complication of structural geometry in Fars region and necessity to explore activities for deeper horizons especially the Paleozoic ones, the analysis of fold style elements, which is known as one of the main parts in structural studies, seems necessary. Description of fold geometry is important because it allows comparisons within and between folds and also allows us to recognize patterns in the occurrence and distribution of fold systems. The main aim of this paper is to determine fold style elements and folding pattern in the study area. This paper presents a part of the results of a regional study of Fars province in the Zagros Simply folded belt, based on satellite images, geological maps, and well data. In the Interior Fars area, it seems that folding pattern is controlled by structural elements such as the Nezamabad basement fault and Dashtak formation. In fact, as a middle detachment unit, Dashtak formation plays an important role regarding folding geometry and fold in style in the study area.

Quantitative characterization of the atomic-scale structure of oxyhydroxides in rusts formed on steel surfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saito, M.; Suzuki, S.; Kimura, M.

Quantitative X-ray structural analysis coupled with anomalous X-ray scattering has been used for characterizing the atomic-scale structure of rust formed on steel surfaces. Samples were prepared from rust layers formed on the surfaces of two commercial steels. X-ray scattered intensity profiles of the two samples showed that the rusts consisted mainly of two types of ferric oxyhydroxide, {alpha}-FeOOH and {gamma}-FeOOH. The amounts of these rust components and the realistic atomic arrangements in the components were estimated by fitting both the ordinary and the environmental interference functions with a model structure calculated using the reverse Monte Carlo simulation technique. The twomore » rust components were found to be the network structure formed by FeO{sub 6} octahedral units, the network structure itself deviating from the ideal case. The present results also suggest that the structural analysis method using anomalous X-ray scattering and the reverse Monte Carlo technique is very successful in determining the atomic-scale structure of rusts formed on the steel surfaces.« less

Extensional Structures on the Po Valley Side of the Northern Apennines

NASA Astrophysics Data System (ADS)

Bettelli, G.; Vannucchi, P.; Capitani, M.

2001-12-01

The present-day tectonics of the Northern Apennines is characterized by extension in the inner Tyrrhenian side and compression in the outer Po Valley-Adriatic side. The boundary separating the two domains, extensional and compressional, is still largely undetermined and mainly based on geophysical data (focal mechanisms of earthquakes). Map-scale extensional structures have been studied only along the Tyrrhenian side of the Northern Apennines (Tuscany), while along the Po Valley-Adriatic area the field studies concentrated on compressional features. A new, detailed field mapping of the Po Valley side of the Northern Apennines carried out in the last ten years within the Emilia Romagna Geological Mapping Program has shown the presence of a large extensional fault crossing the high Bologna-Modena-Reggio Emilia provinces, from the Sillaro to the Val Secchia valleys. This Sillaro-Val Secchia Normal Fault (SVSNF) is NW-SE trending, NE dipping and about 80 km long. The age, based on the younger displaced deposits, is post-Miocene. The SVSNF is a primary regional structure separating the Tuscan foredeep units from the Ligurian Units in the south-east sector of the Northern Apennines, and it is responsible for the exhumation of the Tuscan foredeep units along the Apennine water divide. The sub-vertical, SW-NE trending faults, formerly interpreted as strike slip, are transfer faults associated to the extensional structure. A geological cross-section across the SVSNF testifies a former thickness reduction and lamination of the Ligurian Units, as documented in the field, in the innermost areas of the Bologna-Modena-Reggio Emilia hills, implying the occurrence of a former extensional fault. These data indicate that the NE side of the water divide has already gone under extension reducing the compressional domain to the Po Valley foothills and plain. They can also help in interpreting the complex Apennines kinematics.

Tomographic Imaging of the Seismic Structure Beneath the East Anatolian Plateau, Eastern Turkey

NASA Astrophysics Data System (ADS)

Gökalp, Hüseyin

2012-10-01

The high level of seismic activity in eastern Turkey is thought to be mainly associated with the continuing collision of the Arabian and Eurasian tectonic plates. The determination of a detailed three-dimensional (3D) structure is crucial for a better understanding of this on-going collision or subduction process; therefore, a body wave tomographic inversion technique was performed on the region. The tomographic inversion used high quality arrival times from earthquakes occurring in the region from 1999 to 2001 recorded by a temporary 29 station broadband IRIS-PASSCAL array operated by research groups from the Universities of Boğaziçi (Turkey) and Cornell (USA). The data was inverted and consisted of 3,114 P- and 2,298 S-wave arrival times from 252 local events with magnitudes ( M D) ranging from 2.5 to 4.8. The stability and resolution of the results were qualitatively assessed by two synthetic tests: a spike test and checkerboard resolution test and it was found that the models were well resolved for most parts of the imaged domain. The tomographic inversion results reveal significant lateral heterogeneities in the study area to a depth of ~20 km. The P- and S-wave velocity models are consistent with each other and provide evidence for marked heterogeneities in the upper crustal structure beneath eastern Turkey. One of the most important features in the acquired tomographic images is the high velocity anomalies, which are generally parallel to the main tectonic units in the region, existing at shallow depths. This may relate to the existence of ophiolitic units at shallow depths. The other feature is that low velocities are widely dispersed through the 3D structure beneath the region at deeper crustal depths. This feature can be an indicator of the mantle upwelling or support the hypothesis that the Anatolian Plateau is underlain by a partially molten uppermost mantle.

Tectonic map of Uruguay

NASA Astrophysics Data System (ADS)

Sanchez Bettucci, L.; Oyhantcabal, P.

2008-05-01

A compilation of available data about the geology of Uruguay allowed the definition of its main events and tectonic units. Based on a critical revision of different tectonic hypothesis found in the literature, a parsimonious tectonic evolution schema is presented, in the context of Western Gondwana. The tectonic map illustrates the general features of the structure and main tectonic units of Uruguay. The Precambrian shield, cropping out in the South and Southeast of the country is an Archean to Paleoprtoerozoic basement divided in three main tectonostratigraphic terrranes: the Piedra Alta (PAT) a juvenile Paleoproterozoic unit not reworked by later events; the Nico Pérez (NPT) a complex unit composed of several blocks where Archean to Mesoproterozoic events are recognised. The NPT was strongly reworked by Neoproterozoic (Brasiliano) orogeny. The Dom Feliciano Belt cropping out in eastern Uruguay is related to Western Gondwana amalgamation. Different tectonic settings are considered: pre-Brasiliano Basement inliers; supracrustal successions representing the evolution from a back- arc to a foreland basin; a magmatic arc; and post-collisional basins and related magmatism. In lower Paleozoic the Paraná foreland basin was generated as a consequence of orogenic events. The sedimentary successions in Uruguay include continental to shallow marine deposits where the influence of carboniferous to Permian glacial episode is recorded. The Mesozoic record is characterised by the influence of extension related to the break-up of Gondwana and the formation of the Atlantic Ocean: huge amounts of tholeiitic basalt were erupted (near 30.000 km3 in Uruguay), followed by cretaceous sediments in the northern area of the country while in the south-east, bimodal magmatism and sediments of the same age are associated to rift basins. The Cenozoic is characterised by tectonic quiescence. Subsidence is only observed in the western region (Chaco-Paraná Basin) and in the east (Laguna Merín Basin).

[Hygiene in endoscopy in the clinic and practice, 2003: Results of infection hygiene survey on endoscopy services in Frankfurt am Main by the public health service].

PubMed

Heudorf, U; Hofmann, H; Kutzke, G; Otto, U; Exner, M

2004-08-01

Guidelines for reprocessing flexible endoscopes have been published in many countries. Compliance to the German guidelines, published in 2002 by the Commission on Hospital Hygiene and Infection Prevention on the Robert Koch Institute is mandatory in all endoscopic units, in hospitals as well as in private practices. Here, a survey of current reprocessing practices in an urban region in Germany is published, covering all hospitals and private practices in this region. In summer 2003, all endoscopic units in Frankfurt/Main, Germany--15 hospitals and 23 private practices -- were visited by members of the public health service, using a checklist based on the recommendations of the German guideline. In these institutions, more than 70 000 endoscopic examinations per year are performed. 87 % (13 /15) of the hospitals and 43 % (10/23) of the practices, reported to conduct more than 1000 procedures per year. Great differences were found in hygienic quality comparing endoscopic units in hospitals and in private practices. In hospitals compliance with the guidelines was satisfactory. Main problems in the practices were: missing facilities for ultrasonic cleaning (74%) and sterilizing (43%), faults in reprocessing the bottle and tube for air/water-channel flushing (26%) which was filled in with water not sterilised (48%), storage of the endoscope with risk of recontamination (48%), missing routine-tests of the endoscopes after reprocessing (44%). Generally, hygienic conditions and procedures were worse in smaller units than in bigger ones. The data from Frankfurt hospitals are satisfactory. In private practices, however, especially in smaller ones, improvements are mandatory. Improvements should cover the quality of structure and process, i.e. specific education of the nurses, availability of ultrasonic cleaners and sterilizators and -- preferably -- automatic dishwashers, as well as implementation of a written protocol for hygiene in endoscopy, based on the German Guidelines.

Exhumation history of the deepest central Himalayan rocks, Ama Drime range: Key pressure-temperature-deformation-time constraints on orogenic models

NASA Astrophysics Data System (ADS)

Kali, E.; Leloup, P. H.; Arnaud, N.; MahéO, G.; Liu, Dunyi; Boutonnet, E.; van der Woerd, J.; Liu, Xiaohan; Liu-Zeng, Jing; Li, Haibing

2010-04-01

The Ama Drime range located at the transition between the high Himalayan range and south Tibet is a N-S active horst that offsets the South Tibetan Detachment System (STDS). Within the horst, a paragneissic unit, possibly attributed to the upper Himalayan crystalline series, overly the lower Himalayan crystalline series Ama Drime orthogneissic unit containing large metabasite layers and pods that have experienced pressure ≥1.4 GPa. Combining structural analysis with new and published pressure-temperature (P-T) estimates as well as U-Th/Pb, 39Ar/40Ar and (U-Th)/He ages, the P-T-deformation-time (P-T-D-t) paths of the main units within and on both sides of the horst are reconstructed. They imply that N-S normal faults initiated prior to 11 Ma and have accounted for a total exhumation ≤0.6 GPa (22 km) that probably occurred in two phases: the first one until ˜9 Ma and the second one since 6 to 4 Ma at a rate of ˜1 mm/yr. In the Ama Drime unit, 1 to 1.3 GPa (37 to 48 km) of exhumation occurred after partial melting since ˜30 Ma until ˜13 Ma, above the Main Central Trust (MCT) and below the STDS when these two fault systems were active together. The switch from E-W (STDS) to N-S (Ama Drime horst) normal faulting between 13 and 12 Ma occurs at the time of propagation of thrusting from the MCT to the Main Boundary Thrust. These data are in favor of a wedge extrusion or thrust system rather than a crustal flow model for the building of the Himalaya. We propose that the kinematics of south Tibet Cenozoic extension phases is fundamentally driven by the direction and rate of India underthrusting.

The Focal Surface of the JEM-EUSO Instrument

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kawasaki, Y.; EUSO Team, ASI, RIKEN; Casolino, M.

The Extreme Universe Space Observatory on JEM/EF (JEM-EUSO) is a space mission to study extremely high-energy cosmic rays. The JEM-EUSO instrument is a wide-angle refractive telescope in the near-ultraviolet wavelength region which will be mounted to the International Space Station. Its goal is to measure time-resolved fluorescence images of extensive air showers in the atmosphere. In this paper we describe in detail the main features and technological aspects of the focal surface of the instrument. The JEM-EUSO focal surface is a spherically curved surface, with an area of about 4.5m{sup 2}. The focal surface detector is made of more thanmore » 5,000 multi-anode photomultipliers (MAPMTs). Current baseline is Hamamatsu R11265-03-M64. The approach to the focal surface detector is highly modular. Photo-Detector-Modules (PDM) are the basic units that drive the mechanical structure and data acquisition. Each PDM consists of 9 Elementary Cells (ECs). The EC, which is the basic unit of the MAPMT support structure and of the front-end electronics, contains 4 units of MAPMTs. In total, about 1,200 ECs or about 150 PDMs are arranged on the whole of the focal surface of JEM-EUSO.« less

Sorption, degradation and transport phenomena of alcohol ethoxysulfates in agricultural soils. Laboratory studies.

PubMed

Fernández-Ramos, C; Rodríguez-Gómez, R; Reis, M S; Zafra-Gómez, A; Verge, C; de Ferrer, J A; Pérez-Pascual, M; Vílchez, J L

2017-03-01

In the present work, laboratory studies were conducted in order to determine and model the sorption, degradation and transport processes of alcohol ethoxysulfates (AES), one of the most important groups of anionic surfactants. Adsorption/desorption isotherms were obtained for several structurally related AES ethoxymers (homologue AES-C 12 E n with n = 0-10 ethoxymer units and homologue AES-C 14 E n with n = 0-7 ethoxymer units) using a batch equilibrium method. Data were fitted to a linear and a Freundlich isotherm models. Additionally, experiments in continuous-flow soil columns were also carried out and the breakthrough curves observed for each compound were studied. Breakthrough curves were used to determine the fundamental parameters of the transport model (hydrodynamic dispersion coefficient, degradation rate constant and adsorption/desorption isotherm slope), that is the main phenomena that take place simultaneously when AES move through agricultural soil. When the results obtained for the AES ethoxymers are combined, they reveal a clear and consistent trend towards a sorption increase with the number of ethoxylated units and with the length of the alkyl chain that opens the possibility to estimate the values of the transport parameters for other structurally related ethoxymers. Copyright © 2016 Elsevier Ltd. All rights reserved.

Two fucosylated chondroitin sulfates from the sea cucumber Eupentacta fraudatrix.

PubMed

Ustyuzhanina, Nadezhda E; Bilan, Maria I; Dmitrenok, Andrey S; Nifantiev, Nikolay E; Usov, Anatolii I

2017-05-15

Two fucosylated chondroitin sulfates EF1 and EF2 were isolated from the sea cucumber Eupentacta fraudatrix. Separation of the polysaccharides was performed using anion-exchange chromatography on DEAE-Sephacel by elution of 0.75M and 1.0M NaCl solutions. The structures of biopolymers were determined by chemical and NMR spectroscopic methods. The backbone of EF1 was found to be composed of chondroitin sulfate A and E units in a ratio of about 1:1. The core of EF2 along with chondroitin sulfate A and E fragments contained unusual disaccharide repeating units →4)-β-d-GlcpA2S3S-(1→3)-β-d-GalpNAc6S-(1→. The main type of branches in both polysaccharides was α-l-Fucp3S4S unit attached to O-3 of GlcA residues. Another type of branches was found to be the disaccharide fragment α-l-Fucp-(1→2)-α-l-Fucp3S4S-(1→ linked to O-3 of GlcA. The presence of structurally different fucosylated chondroitin sulfates in one species of sea cucumber is rather unusual and has not been described previously. Copyright © 2017 Elsevier Ltd. All rights reserved.

Late-Paleozoic-Mesozoic deformational and deformation related metamorphic structures of Kuznetsk-Altai region

NASA Astrophysics Data System (ADS)

Zinoviev, Sergei

2014-05-01

Kuznetsk-Altai region is a part of the Central Asian Orogenic Belt. The nature and formation mechanisms of the observed structure of Kuznetsk-Altai region are interpreted by the author as the consequence of convergence of Tuva-Mongolian and Junggar lithospheric block structures and energy of collision interaction between the blocks of crust in Late-Paleozoic-Mesozoic period. Tectonic zoning of Kuznetsk-Altai region is based on the principle of adequate description of geological medium (without methods of 'primary' state recovery). The initial indication of this convergence is the crust thickening in the zone of collision. On the surface the mechanisms of lateral compression form a regional elevation; with this elevation growth the 'mountain roots' start growing. With an approach of blocks an interblock elevation is divided into various fragments, and these fragments interact in the manner of collision. The physical expression of collision mechanisms are periodic pulses of seismic activity. The main tectonic consequence of the block convergence and collision of interblock units is formation of an ensemble of regional structures of the deformation type on the basis of previous 'pre-collision' geological substratum [Chikov et al., 2012]. This ensemble includes: 1) allochthonous and autochthonous blocks of weakly deformed substratum; 2) folded (folded-thrust) systems; 3) dynamic metamorphism zones of regional shears and main faults. Characteristic of the main structures includes: the position of sedimentary, magmatic and PT-metamorphic rocks, the degree of rock dynamometamorphism and variety rock body deformation, as well as the styles and concentrations of mechanic deformations. 1) block terranes have weakly elongated or isometric shape in plane, and they are the systems of block structures of pre-collision substratum separated by the younger zones of interblock deformations. They stand out among the main deformation systems, and the smallest are included into the deformation systems. 2) folded (folded-thrust) deformation systems combine deformation zones with relic lenses of Paleozoid substratum, and predominantly conform systems of the main faults. Despite a high degree of regional deformation the sedimentary-stratified and intrusive-contact relations of geological bodies are stored within the deformation systems, and this differs in the main the collision systems from zones of dynamic metamorphism. 3) regional zones of dynamic metamorphism of Kuznetsk-Altai region are the concentration belts of multiple mechanic deformations and contrast dynamometamorphism of complexes. The formational basis of dynamic metamorphism zones is tectonites of the collision stage. Zones of dynamic metamorphism attract special attention in the structural model of Kuznetsk-Altai region. They not only form the typical tectonic framework of collision sutures, but also contain the main part of ore deposits of this region. Pulse mode of structure formation of Kuznetsk-Altai region is detected. Major collision events in Kuznetsk-Altai region were in the late-Carboniferous-Triassic time (307-310, 295-285, 260-250 and 240-220 Ma). This study was supported by a grant of the Russian Foundation for Basic Research (project nos. 14-05-00117).

Isolation and structural characterization of lignin from cotton stalk treated in an ammonia hydrothermal system.

PubMed

Kang, Sumin; Xiao, Lingping; Meng, Lingyan; Zhang, Xueming; Sun, Runcang

2012-11-16

To investigate the potential for the utilization of cotton stalk, ammonia hydrothermal treatment was applied to fractionate the samples into aqueous ammonia-soluble and ammonia-insoluble portions. The ammonia-soluble portion was purified to yield lignin fractions. The lignin fractions obtained were characterized by wet chemistry (carbohydrate analysis) and spectroscopy methods (FT-IR, 13C and 1H-13C HSQC NMR spectroscopy) as well as gel permeation chromatography (GPC). The results showed that the cotton stalk lignin fractions were almost absent of neutral sugars (0.43%-1.29%) and had relatively low average molecular weights (1255-1746 g/mol). The lignin fractions belonged to typical G-S lignin, which was composed predominately of G-type units (59%) and noticeable amounts of S-type units (40%) together with a small amount of H-type units (~1%). Furthermore, the ammonia-extractable lignin fractions were mainly composed of β-0-4' inter-unit linkages (75.6%), and small quantities of β-β' (12.2%), together with lower amounts of β-5' carbon-carbon linkages (7.4%) and p-hydroxycinnamyl alcohol end groups.

Are there co-occurrence patterns that structure snake communities in Central Brazil?

PubMed

França, F G R; Araújo, A F B

2007-02-01

The main factors that structure Neotropical animal communities have been the subject of discussion in ecology communities. We used a set of null models to investigate the existence of structure in snake communities from the Cerrado in Central Brazil in relation to the co-occurrence of species and guilds concerning specific resources. We used fragments (conservation units) inside the Distrito Federal and neighbor municipalities. In spite of recent human colonization in the region from the end of the 1950s, intense habitat modification and fragmentation has taken place. Sixty three snake species are present in the Distrito Federal. Co-occurrence analysis of species and guilds associated to snake diets and habitats suggested a lack of organization. The homogeneity of habitats in Central Brazil and the minor importance of ecological effects can lead to random arrangement.

Matching of energetic, mechanic and control characteristics of positioning actuator

NASA Astrophysics Data System (ADS)

Y Nosova, N.; Misyurin, S. Yu; Kreinin, G. V.

2017-12-01

The problem of preliminary choice of parameters of the automated drive power channel is discussed. The drive of the mechatronic complex divides into two main units - power and control. The first determines the energy capabilities and, as a rule, the overall dimensions of the complex. The sufficient capacity of the power unit is a necessary condition for successful solution of control tasks without excessive complication of the control system structure. Preliminary selection of parameters is carried out based on the condition of providing the necessary drive power. The proposed approach is based on: a research of a sufficiently developed but not excessive dynamic model of the power block with the help of a conditional test control system; a transition to a normalized model with the formation of similarity criteria; constructing the synthesis procedure.

Self-assembly of an amphiphilic macromolecule under spherical confinement: An efficient route to generate hollow nanospheres

NASA Astrophysics Data System (ADS)

Glagoleva, A. A.; Vasilevskaya, V. V.; Yoshikawa, K.; Khokhlov, A. R.

2013-12-01

In general, bio-macromolecules are composed of hydrophilic and hydrophobic moieties and are confined within small cavities, such as cell membranes and intracellular organelles. Here, we studied the self-organization of macromolecules having groups with different affinities to solvents under spherical nano-scale confinement by means of computer modeling. It is shown that depending on the interaction parameters of monomer units composed of side- and main-chain monomer groups along a single linear macromolecule and on cavity size, such amphiphilic polymers undergo the conformational transitions between hollow nanospheres, rod-like and folded cylindrical structures, and a necklace conformation with and without a particular ordering of beads. The diagram of the conformations in the variables the incompatibility parameter of monomer units and the cavity radius is constructed.

Magneto-structural correlation in a series of bimetallic alternating chain complexes of [CrIIIL(CN)4]n[MnIII(salpn)]n.nsolvents (L=2,2'-bipy or 9,10-phen, salpn=substituted salicyldehyde, solvents=water and methanol).

PubMed

Pan, Feng; Wang, Zhe-Ming; Gao, Song

2007-11-26

Five chain compounds based on the building block of [Cr(L)(CN)4]- (L=2,2'-bipy, 1-4; L=9,10-phen, 5) and [Mn(salpn)]+ (salpn=substituted salicyldehyde-type Schiff base in Scheme 1) have been prepared and characterized structurally and magnetically. The four compounds (1-4) consisting of [Cr(bipy)(CN)4]- units possess straight bimetallic chains as the [Cr(bpy)(CN)4]- unit links the two neighbor [Mn(salpn)]+ units with the two trans-cyanide ligands, while in 5 the chain is zigzag because the [Cr(phen)(CN)4]- unit connects the [Mn(salpn)]+ units with its two cis-cyanide ligands. The bond angles of Mn-N-C-Cr are adjusted by different coligands of salpn and bipy/phen. The chains are stacking via mainly the aromatic pi-pi-type interactions. All compounds show 3D antiferromagnetic ordering with Néel temperatures ranging from 3.7 to 8.1 K, and they are metamagnets displaying antiferromagnetic to ferrimagnetic transition at critical fields of 4.0-13.1 kOe at 1.9 K. This is due to weak interchain antiferromagnetic interactions between the ferrimagnetic bimetallic chains in the materials. The intrachain couplings (J, in cm(-1)) in the materials, between cyanide-bridged CrIII and MnIII ions, from -1.84 to -5.35 cm(-1), follow a linear relationship (J=-33+0.18alpha) to the Mn-N-C angles (alpha, in deg). In addition, the weak interchain antiferromagnetic interactions and critical fields for antiferromagnetic-ferrimagnetic transition are closely related to some of their structural factors, which were studied very superficially only referring to the separations of nearest chains in each material.

Nonequilibrium self-organization of colloidal particles on substrates: adsorption, relaxation, and annealing.

PubMed

Araújo, Nuno A M; Dias, Cristóvão S; Telo da Gama, Margarida M

2017-01-11

Colloidal particles are considered ideal building blocks to produce materials with enhanced physical properties. The state-of-the-art techniques for synthesizing these particles provide control over shape, size, and directionality of the interactions. In spite of these advances, there is still a huge gap between the synthesis of individual components and the management of their spontaneous organization towards the desired structures. The main challenge is the control over the dynamics of self-organization. In their kinetic route towards thermodynamically stable structures, colloidal particles self-organize into intermediate (mesoscopic) structures that are much larger than the individual particles and become the relevant units for the dynamics. To follow the dynamics and identify kinetically trapped structures, one needs to develop new theoretical and numerical tools. Here we discuss the self-organization of functionalized colloids (also known as patchy colloids) on attractive substrates. We review our recent results on the adsorption and relaxation and explore the use of annealing cycles to overcome kinetic barriers and drive the relaxation towards the targeted structures.

Stressors in the relatives of patients admitted to an intensive care unit.

PubMed

Barth, Angélica Adam; Weigel, Bruna Dorfey; Dummer, Claus Dieter; Machado, Kelly Campara; Tisott, Taís Montagner

2016-09-01

To identify and stratify the main stressors for the relatives of patients admitted to the adult intensive care unit of a teaching hospital. Cross-sectional descriptive study conducted with relatives of patients admitted to an intensive care unit from April to October 2014. The following materials were used: a questionnaire containing identification information and demographic data of the relatives, clinical data of the patients, and 25 stressors adapted from the Intensive Care Unit Environmental Stressor Scale. The degree of stress caused by each factor was determined on a scale of values from 1 to 4. The stressors were ranked based on the average score obtained. The main cause of admission to the intensive care unit was clinical in 36 (52.2%) cases. The main stressors were the patient being in a state of coma (3.15 ± 1.23), the patient being unable to speak (3.15 ± 1.20), and the reason for admission (3.00 ± 1.27). After removing the 27 (39.1%) coma patients from the analysis, the main stressors for the relatives were the reason for admission (2.75 ± 1.354), seeing the patient in the intensive care unit (2.51 ± 1.227), and the patient being unable to speak (2.50 ± 1.269). Difficulties in communication and in the relationship with the patient admitted to the intensive care unit were identified as the main stressors by their relatives, with the state of coma being predominant. By contrast, the environment, work routines, and relationship between the relatives and intensive care unit team had the least impact as stressors.

Forest management and water in the United States [Chapter 13

Treesearch

Daniel G. Neary

2017-01-01

This chapter outlines a brief history of the United States native forests and forest plantations. It describes the past and current natural and plantation forest distribution (map, area, main species), as well as main products produced (timber, pulp, furniture, etc.). Integrated into this discussion is a characterization of the water resources of the United States and...

The Rise and Decline of the International Baccalaureate Diploma Programme in the United Kingdom

ERIC Educational Resources Information Center

Bunnell, Tristan

2015-01-01

The three main programmes of the Geneva-registered International Baccalaureate (IB) have grown substantially worldwide over the past decade, although the programmes have found a natural "home" in the United States. This paper charts the growth of the IB in the United Kingdom (UK) revealing that involvement there, mainly in England and…

Tomographic models and seismotectonics of the Reggio Emilia region, Italy

NASA Astrophysics Data System (ADS)

Ciaccio, M. G.; Chiarabba, C.

2002-02-01

The aim of this study is to define the Vp and Vp/Vs structure of the fault zone ruptured by the M L 5.1 earthquake of October 15, 1996 which occurred near Reggio Emilia (central-northern Italy). A 1-month-long seismic sequence followed the mainshock and occurred in a small region along the outer border of the northern Apenninic belt, at depth ranging between 10 and 17 km. P- and S-wave arrival times from 304 aftershocks recorded by two local dense seismic arrays installed in the epicentral region have been inverted to obtain one- and three-dimensional velocity models by using state of the art local earthquake tomographic techniques. Velocity models and aftershock relocation help us to infer the seismotectonic of the region. Earthquakes originated along a NW-dipping backthrust of a NE-trending main thrust, composing the western part of the broad Ferrara Arc. A main high Vp and high Vp/Vs region delineates a pop-up structure in the center of the area. The high Vp/Vs within the pop-up structure supports the presence of a zone with increased pore pressure. The hypocentral depth of both mainshock and aftershocks is greater than those usually found for the main seismogenic regions of the Apenninic belt. P-wave velocity values in the seismogenic area, obtained by tomography, are compatible with rocks of the Mesozoic cover and suggest that seismicity occurred within the Mesozoic units stack at present by compressional tectonics.

Mineralogical composition of boiler fouling and slagging deposits and their relation to fly ashes: the case of Kardia power plant.

PubMed

Kostakis, George

2011-01-30

Slagging and fouling deposits from a pulverized lignite fired steam generating unit of the Kardia power plant (West Macedonia, Greece) were mineralogically investigated. The structure and cohesion of these deposits varied, usually depending on the level height of the boiler unit where they were formed. Some of the deposits had complex phase composition. The dominant components of the deposits of the burner zone and of the lower and intermediate boiler zones were the amorphous, anhydrite and hematite, while those of the highest levels contained amorphous, and anhydrite. Furthermore, in deposits formed in various other boiler areas gehlenite, anorthite, diopside, quartz, Ca(2)SiO(4), brownmillerite and other crystalline phases were also identified, usually in low amounts or in traces. The major part of the phases constituting the deposits were formed in the boiler, since only a minor part derived from the unreacted minerals present in lignite. Anhydrite was generated from the reaction of SO(2) with CaO formed mainly by the calcination of calcite as well as from dehydration of gypsum contained in lignite, while hematite was produced mainly from the oxidation of pyrite. The calcium-containing silicates formed in the boiler were mainly the products of reactions between CaO and minerals contained in the lignite. Copyright © 2010 Elsevier B.V. All rights reserved.

Lignin Composition and Structure in Young versus Adult Eucalyptus globulus Plants1

PubMed Central

Rencoret, Jorge; Gutiérrez, Ana; Nieto, Lidia; Jiménez-Barbero, J.; Faulds, Craig B.; Kim, Hoon; Ralph, John; Martínez, Ángel T.; del Río, José C.

2011-01-01

Lignin changes during plant growth were investigated in a selected Eucalyptus globulus clone. The lignin composition and structure were studied in situ by a new procedure enabling the acquisition of two-dimensional nuclear magnetic resonance (2D-NMR) spectra on wood gels formed in the NMR tube as well as by analytical pyrolysis-gas chromatography-mass spectrometry. In addition, milled-wood lignins were isolated and analyzed by 2D-NMR, pyrolysis-gas chromatography-mass spectrometry, and thioacidolysis. The data indicated that p-hydroxyphenyl and guaiacyl units are deposited at the earlier stages, whereas the woods are enriched in syringyl (S) lignin during late lignification. Wood 2D-NMR showed that β-O-4′ and resinol linkages were predominant in the eucalypt lignin, whereas other substructures were present in much lower amounts. Interestingly, open β-1′ structures could be detected in the isolated lignins. Phenylcoumarans and cinnamyl end groups were depleted with age, spirodienone abundance increased, and the main substructures (β-O-4′ and resinols) were scarcely modified. Thioacidolysis revealed a higher predominance of S units in the ether-linked lignin than in the total lignin and, in agreement with NMR, also indicated that resinols are the most important nonether linkages. Dimer analysis showed that most of the resinol-type structures comprised two S units (syringaresinol), the crossed guaiacyl-S resinol appearing as a minor substructure and pinoresinol being totally absent. Changes in hemicelluloses were also shown by the 2D-NMR spectra of the wood gels without polysaccharide isolation. These include decreases of methyl galacturonosyl, arabinosyl, and galactosyl (anomeric) signals, assigned to pectin and related neutral polysaccharides, and increases of xylosyl (which are approximately 50% acetylated) and 4-O-methylglucuronosyl signals. PMID:21098672

Power in health care organizations: contemplations from the first-line management perspective.

PubMed

Isosaari, Ulla

2011-01-01

The aim of this paper is to examine health care organizations' power structures from the first-line management perspective. What liable power structures derive from the theoretical bases of bureaucratic, professional and result based organizations, and what power type do health care organizations represent, according to the empirical data? The paper seeks to perform an analysis using Mintzberg's power configurations of instrument, closed system, meritocracy and political arena. The empirical study was executed at the end of 2005 through a survey in ten Finnish hospital districts in both specialized and primary care. Respondents were all first-line managers in the area and a sample of staff members from internal disease, surgical and psychiatric units, as well as out-patient and primary care units. The number of respondents was 1,197 and the response percentage was 38. The data were analyzed statistically. As a result, it can be seen that a certain kind of organization structure supports the generation of a certain power type. A bureaucratic organization generates an instrument or closed system organization, a professional organization generates meritocracy and also political arena, and a result-based organization has a connection to political arena and meritocracy. First line managers regarded health care organizations as instruments when staff regarded them mainly as meritocracies having features of political arena. Managers felt their position to be limited by rules, whereas staff members regarded their position as having lots of space and influence potential. If the organizations seek innovative and active managers at the unit level, they should change the organizational structure and redistribute the work so that there could be more space for meaningful management. This research adds to the literature and gives helpful suggestions that will be of interest to those in the position of first-line management in health care.

Structural Analysis of Active North Bozgush Fault Zone (NW Iran)

NASA Astrophysics Data System (ADS)

Saber, R.; Isik, V.; Caglayan, A.

2013-12-01

NW Iran is one of the seismically active regions between Zagros Thrust Belt at the south and Caucasus at the north. Not only large magnitude historical earthquakes (Ms>7), but also 1987 Bozgush, 1997 Ardebil (Mw 6.1) and 2012 Ahar-Varzagan (Mw 6.4) earthquakes reveal that the region is seismically active. The North Bozgush Fault Zone (NBFZ) in this region has tens of kilometers in length and hundreds of meters in width. The zone has produced some large and destructive earthquakes (1593 M:6.1 and 1883 M:6.2). The NBFZ affects the Cenozoic units and along this zone Eocene units thrusted over Miocene and/or Plio-Quaternary sedimentary units. Together with morphologic features (stream offsets and alluvial fan movements) affecting the young unites reveal that the zone is active. The zone is mainly characterized by strike-slip faults with reverse component and reverse faults. Reverse faults striking N55°-85°E and dip of 40°-50° to the SW while strike-slip faults show right lateral slip with N60°-85°W and N60°-80°E directions. Our structural data analysis in NBFZ indicates that the axis direction of σ2 principal stress is vertical and the stress ratio (R) is 0.12. These results suggest that the tectonic regime along the North Bozgush Fault Zone is transpressive. Obtained other principal stresses (σ1, σ3) results are compatible with stress directions and GPS velocity suggested for NW Iran.

Rio Grande valley Colorado new Mexico and Texas

USGS Publications Warehouse

Ellis, Sherman R.; Levings, Gary W.; Carter, Lisa F.; Richey, Steven F.; Radell, Mary Jo

1993-01-01

Two structural settings are found in the study unit: alluvial basins and bedrock basins. The alluvial basins can have through-flowing surface water or be closed basins. The discussion of streamflow and water quality for the surface-water system is based on four river reaches for the 750 miles of the main stem. the quality of the ground water is affected by both natural process and human activities and by nonpoint and point sources. Nonpoint sources for surface water include agriculture, hydromodification, and mining operations; point sources are mainly discharge from wastewater treatment plants. Nonpoint sources for ground water include agriculture and septic tanks and cesspools; point sources include leaking underground storage tanks, unlined or manure-lined holding ponds used for disposal of dairy wastes, landfills, and mining operations.

Thermodynamic analysis of the advanced zero emission power plant

NASA Astrophysics Data System (ADS)

Kotowicz, Janusz; Job, Marcin

2016-03-01

The paper presents the structure and parameters of advanced zero emission power plant (AZEP). This concept is based on the replacement of the combustion chamber in a gas turbine by the membrane reactor. The reactor has three basic functions: (i) oxygen separation from the air through the membrane, (ii) combustion of the fuel, and (iii) heat transfer to heat the oxygen-depleted air. In the discussed unit hot depleted air is expanded in a turbine and further feeds a bottoming steam cycle (BSC) through the main heat recovery steam generator (HRSG). Flue gas leaving the membrane reactor feeds the second HRSG. The flue gas consist mainly of CO2 and water vapor, thus, CO2 separation involves only the flue gas drying. Results of the thermodynamic analysis of described power plant are presented.

Using inertial measurement units originally developed for biomechanics for modal testing of civil engineering structures

NASA Astrophysics Data System (ADS)

Hester, David; Brownjohn, James; Bocian, Mateusz; Xu, Yan; Quattrone, Antonino

2018-05-01

This paper explores the use of wireless Inertial Measurement Units (IMU) originally developed for bio-mechanical research applications for modal testing of civil engineering infrastructure. Due to their biomechanics origin, these devices combine a triaxial accelerometer with gyroscopes and magnetometers for orientation, as well as on board data logging capability and wireless communication for optional data streaming and to coordinate synchronisation with other IMUs in a network. The motivation for application to civil structures is that their capabilities and simple operating procedures make them suitable for modal testing of many types of civil infrastructure of limited dimension including footbridges and floors while also enabling recovering of dynamic forces generated and applied to structures by moving humans. To explore their capabilities in civil applications, the IMUs are evaluated through modal tests on three different structures with increasing challenge of spatial and environmental complexity. These are, a full-scale floor mock-up in a laboratory, a short span road bridge and a seven story office tower. For each case, the results from the IMUs are compared with those from a conventional wired system to identify the limitations. The main conclusion is that the relatively high noise floor and limited communication range will not be a serious limitation in the great majority of typical civil modal test applications where convenient operation is a significant advantage over conventional wired systems.

Subsurface geology of the Lusi region: preliminary results from a comprehensive seismic-stratigraphic study.

NASA Astrophysics Data System (ADS)

Moscariello, Andrea; Do Couto, Damien; Lupi, Matteo; Mazzini, Adriano

2016-04-01

We investigate the subsurface data of a large sector in the Sidoarjo district (East Java, Indonesia) where the sudden catastrophic Lusi eruption started the 26th May 2006. Our goal is to understand the stratigraphic and structural features which can be genetically related to the surface manifestations of deep hydrothermal fluids and thus allow us to predict possible future similar phenomena in the region. In the framework of the Lusi Lab project (ERC grant n° 308126) we examined a series of densely spaced 2D reflection commercial seismic lines This allowed the reconstruction of the lateral variability of key stratigraphic horizons as well as the main tectonic features. In particular, we shed light on the deep structure of the Watukosek fault system and the associated fracture corridors crossing the entire stratigraphic successions. To the South-West, when approaching the volcanic complex, we could identify a clear contrast in seismic facies between chaotic volcanoclastic wedges and clastic-prone sedimentary successions as well as between the deeper stratigraphic units consisting of carbonates and lateral shales units. The latter show possible ductile deformation associated to fault-controlled diapirism which control in turns deformation of overlying stratigraphic units and deep geo-fluids circulation. Large collapse structures recognized in the study area (e.g. well PRG-1) are interpreted as the results of shale movement at depth. Similarly to Lusi, vertical deformation zones ("pipes"), likely associated with deeply rooted strike-slip systems seem to be often located at the interface between harder carbonate rocks forming isolated build ups and the laterally nearby clastic (shale-prone)-units. The mechanisms of deformation of structural features (strike vs dip slip systems) which may affect either the basement rock or the overlying deeper stratigraphic rocks is also being investigated to understand the relationship between deep and shallower (i.e. meteoric) fluid circulation. Seismic stratigraphic study of the basin margin (closer to volcanic accumulations) will also allow reconstructing the relationships between present and past volcanic activity recorded in the deep subsurface with the genesis of piercement structures and development of vertical deformation zones

The renal excretion and retention of macromolecules: The chemical structure effect.

PubMed

Rypácek, F; Drobník, J; Chmelar, V; Kálal, J

1982-01-01

Five derivatives of polyaspartamide were used as macromolecular models to study the effect of chemical structure of macromolecules on their renal excretion and retention. The parent polymer was formed solely by N(2-hydroxyethyl)aspartamide units (I) and in its derivatives about 20% of 2-hydroxyethyl groups were randomly replaced by either n-butyl- (II), 2(4-hydroxyphenyl)ethyl- (III, N- dimethylamino propyl- (IV) or the aspartamide unit was modified to free aspartic acid carboxyl (V). The rate of clearance from the serum, the deposition in the kidney tissue in comparison with the deposition in reticuloendothelial system organs-liver and spleen, as well as tissue and cellular localisation of deposits were studied on rabbits and mice taking advantage of fluorescence labelling. The clearance of macromolecular models from the serum compartment by the glomerular filtration is mainly molecular weight controlled, while the retention of macromolecules possessing the same molecular weight by the kidney tubular epithelium is strongly affected chemical modification. About thirty and hundred times higher retentions due to reabsorption in proximal tubule were found with macromolecular models II and III respectively.

Seismic sequence stratigraphy and platform to basin reservoir structuring of Lower Cretaceous deposits in the Sidi Aïch-Majoura region (Central Tunisia)

NASA Astrophysics Data System (ADS)

Azaïez, Hajer; Bédir, Mourad; Tanfous, Dorra; Soussi, Mohamed

2007-05-01

In central Tunisia, Lower Cretaceous deposits represent carbonate and sandstone reservoir series that correspond to proven oil fields. The main problems for hydrocarbon exploration of these levels are their basin tectonic configuration and their sequence distribution in addition to the source rock availability. The Central Atlas of Tunisia is characterized by deep seated faults directed northeast-southwest, northwest-southeast and north-south. These faults limit inherited tectonic blocks and show intruded Triassic salt domes. Lower Cretaceous series outcropping in the region along the anticline flanks present platform deposits. The seismic interpretation has followed the Exxon methodologies in the 26th A.A.P.G. Memoir. The defined Lower Cretaceous seismic units were calibrated with petroleum well data and tied to stratigraphic sequences established by outcrop studies. This allows the subsurface identification of subsiding zones and thus sequence deposit distribution. Seismic mapping of these units boundary shows a structuring from a platform to basin blocks zones and helps to understand the hydrocarbon reservoir systems-tract and horizon distribution around these domains.

Trends in Labor Force Participation: How Much is Due to Changes in Pensions?

PubMed Central

Rohwedder, Susann

2011-01-01

In the United States, beginning in the late 1980s there was a substantial increase in the labor force participation of men and women in their 60s. Over the same time period the type of pension plans offered by employers shifted strongly from defined benefit plans to defined contribution plans. Defined benefit plans typically have optimal retirement ages embedded in their structure which induce early retirement, whereas defined contribution plans do not favor any particular retirement age. Based on panel data, this paper quantifies the increase in participation due to the change in pension structure. The main result is that the pension changes account for a considerable part of the increase, but other factors also made a contribution. PMID:21857886

Band structure analysis of a thin plate with periodic arrangements of slender beams

NASA Astrophysics Data System (ADS)

Serrano, Ó.; Zaera, R.; Fernández-Sáez, J.

2018-04-01

This work analyzes the wave propagation in structures composed of a periodic arrangement of vertical beams rigidly joined to a plate substrate. Three different configurations for the distribution of the beams have been analyzed: square, triangular, and hexagonal. A dimensional analysis of the problem indicates the presence of three dimensionless groups of parameters controlling the response of the system. The main features of the wave propagation have been found using numerical procedures based on the Finite Element Method, through the application of the Bloch's theorem for the corresponding primitive unit cells. Illustrative examples of the effect of the different dimensionless parameters on the dynamic behavior of the system are presented, providing information relevant for design.

Conceptual design of free-piston Stirling conversion system for solar power units

NASA Astrophysics Data System (ADS)

Loktionov, Iu. V.

A conversion system has been conceptually designed for solar power units of the dish-Stirling type. The main design objectives were to demonstrate the possibility of attaining such performance characteristics as low manufacturing and life cycle costs, high reliability, long life, high efficiency, power output stability, self-balance, automatic (or self-) start-up, and easy maintenance. The system design includes a heat transfer and utilization subsystem with a solar receiver, a free-piston engine, an electric power generation subsystem, and a control subsystem. The working fluid is helium. The structural material is stainless steel for hot elements, aluminum alloys and plastics for others. The electric generation subunit can be fabricated in three options: with an induction linear alternator, with a permanent magnet linear alternator, and with a serial rotated induction generator and a hydraulic drive subsystem. The heat transfer system is based on heat pipes or the reflux boiler principle. Several models of heat transfer units using a liquid metal (Na or Na-K) have been created and demonstrated.

Compact hybrid optoelectrical unit for image processing and recognition

NASA Astrophysics Data System (ADS)

Cheng, Gang; Jin, Guofan; Wu, Minxian; Liu, Haisong; He, Qingsheng; Yuan, ShiFu

1998-07-01

In this paper a compact opto-electric unit (CHOEU) for digital image processing and recognition is proposed. The central part of CHOEU is an incoherent optical correlator, which is realized with a SHARP QA-1200 8.4 inch active matrix TFT liquid crystal display panel which is used as two real-time spatial light modulators for both the input image and reference template. CHOEU can do two main processing works. One is digital filtering; the other is object matching. Using CHOEU an edge-detection operator is realized to extract the edges from the input images. Then the reprocessed images are sent into the object recognition unit for identifying the important targets. A novel template- matching method is proposed for gray-tome image recognition. A positive and negative cycle-encoding method is introduced to realize the absolute difference measurement pixel- matching on a correlator structure simply. The system has god fault-tolerance ability for rotation distortion, Gaussian noise disturbance or information losing. The experiments are given at the end of this paper.

Reinsurance of health insurance for the informal sector.

PubMed Central

Dror, D. M.

2001-01-01

Deficient financing of health services in low-income countries and the absence of universal insurance coverage leaves most of the informal sector in medical indigence, because people cannot assume the financial consequences of illness. The role of communities in solving this problem has been recognized, and many initiatives are under way. However, community financing is rarely structured as health insurance. Communities that pool risks (or offer insurance) have been described as micro-insurance units. The sources of their financial instability and the options for stabilization are explained. Field data from Uganda and the Philippines, as well as simulated situations, are used to examine the arguments. The article focuses on risk transfer from micro-insurance units to reinsurance. The main insight of the study is that when the financial results of micro-insurance units can be estimated, they can enter reinsurance treaties and be stabilized from the first year. The second insight is that the reinsurance pool may require several years of operation before reaching cost neutrality. PMID:11477971

Performance evaluation of automated manufacturing systems using generalized stochastic Petri Nets. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Al-Jaar, Robert Y.; Desrochers, Alan A.

1989-01-01

The main objective of this research is to develop a generic modeling methodology with a flexible and modular framework to aid in the design and performance evaluation of integrated manufacturing systems using a unified model. After a thorough examination of the available modeling methods, the Petri Net approach was adopted. The concurrent and asynchronous nature of manufacturing systems are easily captured by Petri Net models. Three basic modules were developed: machine, buffer, and Decision Making Unit. The machine and buffer modules are used for modeling transfer lines and production networks. The Decision Making Unit models the functions of a computer node in a complex Decision Making Unit Architecture. The underlying model is a Generalized Stochastic Petri Net (GSPN) that can be used for performance evaluation and structural analysis. GSPN's were chosen because they help manage the complexity of modeling large manufacturing systems. There is no need to enumerate all the possible states of the Markov Chain since they are automatically generated from the GSPN model.

Design and manufacture of the integrated field unit for the NIRSpec spectrometer on JWST

NASA Astrophysics Data System (ADS)

Lobb, Daniel; Robertson, David; Closs, Martin; Barnes, Andy

2008-09-01

The NIRSpec imaging spectrometer, which forms part of the James Webb Space Telescope instrumentation, will include an integrated field unit (IFU). The IFU will be tasked specifically with efficient analysis of extended objects, including galaxies; it will accept a square image area at the spectrometer entrance field, dissect this area into 30 parallel sub-slits, and image the sub-slits end-to-end, forming a single virtual entrance slit. The IFU, uses all-mirror optics to operate over the spectral range 700nm to 5000nm. 95 mirrors and the main support structure are made in a common aluminium alloy, to achieve athermal performance down to an operating temperature of around 30K. Relatively complex mirror surface shapes are produced by diamond machining. The IFU has been designed and constructed by SSTL, with optics produced by CfAI; the unit is currently undergoing performance tests. This paper describes the IFU optical design and performance, and outlines the mirror manufacturing methods and alignment procedures.

[Pleasure in nursing technicians working at an emergency unit of a public university hospital].

PubMed

Garcia, Alessandra Bassalobre; Dellaroza, Mara Solange Gomes; Haddad, Maria do Carmo Lourenço; Pachemshy, Luiza Rita

2012-06-01

This study aimed to reveal the main aspects of the work process and feelings of pleasure experienced by nursing technicians who work at an emergency unit in Paraná, Brazil. The theoretical basis is the psychodynamics of work. This is a qualitative and descriptive study. Data were collected and analyzed using a semi-structured interview and the content analysis technique. Subjects were selected using a snowball sampling. Important aspects of the work process were revealed such as the unpredictability of working in an emergency unit, the impact of team work, and the comprehensive care model as a precursor to humanized care. Pleasure originates from the acknowledgement of their work either by the working subject him/herself by patients or society; and from the team work, realized by the cooperation among professionals. Feelings of pleasure are linked to the acknowledgment of their work, which should be valued since gratification contributes to the psychological health of workers.

The Foote House (10-AA-96), An Historic Archaeological Complex in the Boise River Canyon, Idaho.

DTIC Science & Technology

1982-01-01

into four or perhaps five basic rooms, three of which opened into one another (Paul 1972:293). The main front entrance faced west, and consisted of low...sediments were dry screened through 1/4 in. hardward mesh. Four areas in or adjacent to the Foote House were tested to provide structural and (if possible...down into the soil matrix through the first excavation level, to 10 cm depth. At this level, in the northwest quadrant of the unit, a thin layer of

Archaeological Survey and Testing of Areas along Main Ditch and Ditch 9, Pemiscot County, Missouri.

DTIC Science & Technology

1987-01-15

authors of the great earthworks of the eastern United States. Most of the early work was concerned with the collection of specimerns for museums (e.g...h,-storic rnater-al, ircY.udirg archtectural e’ese•.. No structure was located; !92 anc M93--P’robaoly mccern -e` se piles, small scatters of historic...Anthropological Papers of the American Museum of Natural H-story, Vol. 50, Part 1, New York. Ford, James A., and Gordon R. Willey 1941 An Interpretation

Detecting molecular features of spectra mainly associated with structural and non-structural carbohydrates in co-products from bioEthanol production using DRIFT with uni- and multivariate molecular spectral analyses.

PubMed

Yu, Peiqiang; Damiran, Daalkhaijav; Azarfar, Arash; Niu, Zhiyuan

2011-01-01

The objective of this study was to use DRIFT spectroscopy with uni- and multivariate molecular spectral analyses as a novel approach to detect molecular features of spectra mainly associated with carbohydrate in the co-products (wheat DDGS, corn DDGS, blend DDGS) from bioethanol processing in comparison with original feedstock (wheat (Triticum), corn (Zea mays)). The carbohydrates related molecular spectral bands included: A_Cell (structural carbohydrates, peaks area region and baseline: ca. 1485-1188 cm(-1)), A_1240 (structural carbohydrates, peak area centered at ca. 1240 cm(-1) with region and baseline: ca. 1292-1198 cm(-1)), A_CHO (total carbohydrates, peaks region and baseline: ca. 1187-950 cm(-1)), A_928 (non-structural carbohydrates, peak area centered at ca. 928 cm(-1) with region and baseline: ca. 952-910 cm(-1)), A_860 (non-structural carbohydrates, peak area centered at ca. 860 cm(-1) with region and baseline: ca. 880-827 cm(-1)), H_1415 (structural carbohydrate, peak height centered at ca. 1415 cm(-1) with baseline: ca. 1485-1188 cm(-1)), H_1370 (structural carbohydrate, peak height at ca. 1370 cm(-1) with a baseline: ca. 1485-1188 cm(-1)). The study shows that the grains had lower spectral intensity (KM Unit) of the cellulosic compounds of A_1240 (8.5 vs. 36.6, P < 0.05), higher (P < 0.05) intensities of the non-structural carbohydrate of A_928 (17.3 vs. 2.0) and A_860 (20.7 vs. 7.6) than their co-products from bioethanol processing. There were no differences (P > 0.05) in the peak area intensities of A_Cell (structural CHO) at 1292-1198 cm(-1) and A_CHO (total CHO) at 1187-950 cm(-1) with average molecular infrared intensity KM unit of 226.8 and 508.1, respectively. There were no differences (P > 0.05) in the peak height intensities of H_1415 and H_1370 (structural CHOs) with average intensities 1.35 and 1.15, respectively. The multivariate molecular spectral analyses were able to discriminate and classify between the corn and corn DDGS molecular spectra, but not wheat and wheat DDGS. This study indicated that the bioethanol processing changes carbohydrate molecular structural profiles, compared with the original grains. However, the sensitivities of different types of carbohydrates and different grains (corn and wheat) to the processing differ. In general, the bioethanol processing increases the molecular spectral intensities for the structural carbohydrates and decreases the intensities for the non-structural carbohydrates. Further study is needed to quantify carbohydrate related molecular spectral features of the bioethanol co-products in relation to nutrient supply and availability of carbohydrates.

Teaching Three-Dimensional Structural Chemistry Using Crystal Structure Databases. 2. Teaching Units that Utilize an Interactive Web-Accessible Subset of the Cambridge Structural Database

ERIC Educational Resources Information Center

Battle, Gary M.; Allen, Frank H.; Ferrence, Gregory M.

2010-01-01

A series of online interactive teaching units have been developed that illustrate the use of experimentally measured three-dimensional (3D) structures to teach fundamental chemistry concepts. The units integrate a 500-structure subset of the Cambridge Structural Database specially chosen for their pedagogical value. The units span a number of key…

Evidence for population bottlenecks and subtle genetic structure in the yellow rail

USGS Publications Warehouse

Popper, Kenneth J.; Miller, Leonard F.; Green, Michael; Haig, Susan M.; Mullins, Thomas D.

2012-01-01

The Yellow Rail (Coturnicops noveboracencis) is among the most enigmatic and least studied North American birds. Nesting exclusively in marshes and wetlands, it breeds largely east of the Rocky Mountains in the northern United States and Canada, but there is an isolated population in southern Oregon once believed extirpated. The degree of connectivity of the Oregon population with the main population is unknown. We used mitochondrial DNA sequences (mtDNA) and six microsatellite loci to characterize the Yellow Rail's genetic structure and diversity patterns in six areas. Our mtDNA-based analyses of genetic structure identified significant population differentiation, but pairwise comparison of regions identified no clear geographic trends. In contrast, microsatellites suggested subtle genetic structure differentiating the Oregon population from those in the five regions sampled in the Yellow Rail's main breeding range. The genetic diversity of the Oregon population was also the lowest of the six regions sampled, and Oregon was one of three regions that demonstrated evidence of recent population bottlenecks. Factors that produced population reductions may include loss of wetlands to development and agricultural conversion, drought, and wildfire. At this time, we are unable to determine if the high percentage (50%) of populations having experienced bottlenecks is representative of the Yellow Rail's entire range. Further genetic data from additional breeding populations will be required for this issue to be addressed.

Multi-disciplinary team meetings in stroke rehabilitation: an observation study and conceptual framework.

PubMed

Tyson, S F; Burton, L; McGovern, A

2014-12-01

To explore how multi-disciplinary team meetings operate in stroke rehabilitation. Non-participant observation of multi-disciplinary team meetings and semi-structured interviews with attending staff. Twelve meetings were observed (at least one at each site) and 18 staff (one psychologist, one social worker; four nurses; four physiotherapists four occupational therapists, two speech and language therapists, one stroke co-ordinator and one stroke ward manager) were interviewed in eight in-patient stroke rehabilitation units. Multi-disciplinary team meetings in stroke rehabilitation were complex, demanding and highly varied. A model emerged which identified the main inputs to influence conduct of the meetings were personal contributions of the members and structure and format of the meetings. These were mediated by the team climate and leadership skills of the chair. The desired outputs; clinical decisions and the attributes of apparently effective meetings were identified by the staff. A notable difference between the meetings that staff considered effective and those that were not, was their structure and format. Successful meetings tended to feature a set agenda, structured documentation; formal use of measurement tools; pre-meeting preparation and skilled chairing. These features were often absent in meetings perceived to be ineffective. The main features of operation of multi-disciplinary team meetings have been identified which will enable assessment tools and interventions to improve effectiveness to be developed. © The Author(s) 2014.

Isolation and structure elucidation of pectic polysaccharide from rose hip fruits (Rosa canina L.).

PubMed

Ognyanov, Manol; Remoroza, Connie; Schols, Henk A; Georgiev, Yordan; Kratchanova, Maria; Kratchanov, Christo

2016-10-20

A pectic polysaccharide from rose hip (RH) fruits has been obtained by extraction with 1% aqueous citric acid. It was found that the polysaccharide fraction mainly consisted of galacturonic acid (45.5%) next to galactose (5.5%) and arabinose (4.7%). RH pectin is having a relatively high degree of methylesterification (62%) and acetylation (10%) and consists of different molecular weight populations in the range of 10-100kDa. Enzymatic fingerprinting was performed using a combination of pectin lyase (PL) and endo-polygalacturonase. Detailed information about the structure and level of galacturonic acid oligomers released was obtained using LC-HILIC-MS/ELSD and HPAEC. Predominantly, unsaturated and methyl-esterified oligomers (DP 3-5) were released indicating that high proportions of methylesterified 'PL degradable' areas were present within the pectin. The data revealed that homogalacturonan is the main building block of the extracted pectin and consists of long methylesterified/acetylated GalA sequences interspersed with small blocks of non-methyl-esterified GalA units. Copyright © 2016 Elsevier Ltd. All rights reserved.

Online measurement for geometrical parameters of wheel set based on structure light and CUDA parallel processing

NASA Astrophysics Data System (ADS)

Wu, Kaihua; Shao, Zhencheng; Chen, Nian; Wang, Wenjie

2018-01-01

The wearing degree of the wheel set tread is one of the main factors that influence the safety and stability of running train. Geometrical parameters mainly include flange thickness and flange height. Line structure laser light was projected on the wheel tread surface. The geometrical parameters can be deduced from the profile image. An online image acquisition system was designed based on asynchronous reset of CCD and CUDA parallel processing unit. The image acquisition was fulfilled by hardware interrupt mode. A high efficiency parallel segmentation algorithm based on CUDA was proposed. The algorithm firstly divides the image into smaller squares, and extracts the squares of the target by fusion of k_means and STING clustering image segmentation algorithm. Segmentation time is less than 0.97ms. A considerable acceleration ratio compared with the CPU serial calculation was obtained, which greatly improved the real-time image processing capacity. When wheel set was running in a limited speed, the system placed alone railway line can measure the geometrical parameters automatically. The maximum measuring speed is 120km/h.

Backbone conformations and side chain flexibility of two somatostatin mimics investigated by molecular dynamics simulations.

PubMed

Interlandi, Gianluca

2009-05-15

Molecular dynamics simulations with two designed somatostatin mimics, SOM230 and SMS 201-995, were performed in explicit water for a total aggregated time of 208 ns. Analysis of the runs with SOM230 revealed the presence of two clusters of conformations. Strikingly, the two sampled conformers correspond to the two main X-ray structures in the asymmetric unit of SMS 201-995. Structural comparison between the residues of SOM230 and SMS 201-995 provides an explanation for the high binding affinity of SOM230 to four of five somatostatin receptors. Similarly, cluster analysis of the simulations with SMS 201-995 shows that the backbone of the peptide interconverts between its two main crystallographic conformers. The conformations of SMS 201-995 sampled in the two clusters violated two different sets of NOE distance constraints in agreement with a previous NMR study. Differences in side chain fluctuations between SOM230 and SMS 201-995 observed in the simulations may contribute to the relatively higher binding affinity of SOM230 to most somatostatin receptors.

Stressors in the relatives of patients admitted to an intensive care unit

PubMed Central

Barth, Angélica Adam; Weigel, Bruna Dorfey; Dummer, Claus Dieter; Machado, Kelly Campara; Tisott, Taís Montagner

2016-01-01

Objective To identify and stratify the main stressors for the relatives of patients admitted to the adult intensive care unit of a teaching hospital. Methods Cross-sectional descriptive study conducted with relatives of patients admitted to an intensive care unit from April to October 2014. The following materials were used: a questionnaire containing identification information and demographic data of the relatives, clinical data of the patients, and 25 stressors adapted from the Intensive Care Unit Environmental Stressor Scale. The degree of stress caused by each factor was determined on a scale of values from 1 to 4. The stressors were ranked based on the average score obtained. Results The main cause of admission to the intensive care unit was clinical in 36 (52.2%) cases. The main stressors were the patient being in a state of coma (3.15 ± 1.23), the patient being unable to speak (3.15 ± 1.20), and the reason for admission (3.00 ± 1.27). After removing the 27 (39.1%) coma patients from the analysis, the main stressors for the relatives were the reason for admission (2.75 ± 1.354), seeing the patient in the intensive care unit (2.51 ± 1.227), and the patient being unable to speak (2.50 ± 1.269). Conclusion Difficulties in communication and in the relationship with the patient admitted to the intensive care unit were identified as the main stressors by their relatives, with the state of coma being predominant. By contrast, the environment, work routines, and relationship between the relatives and intensive care unit team had the least impact as stressors. PMID:27737424

Influence of molecular designs on polaronic and vibrational transitions in a conjugated push-pull copolymer

NASA Astrophysics Data System (ADS)

Cobet, Christoph; Gasiorowski, Jacek; Menon, Reghu; Hingerl, Kurt; Schlager, Stefanie; White, Matthew S.; Neugebauer, Helmut; Sariciftci, N. Serdar; Stadler, Philipp

2016-10-01

Electron-phonon interactions of free charge-carriers in doped pi-conjugated polymers are conceptually described by 1-dimensional (1D) delocalization. Thereby, polaronic transitions fit the 1D-Froehlich model in quasi-confined chains. However, recent developments in conjugated polymers have diversified the backbones to become elaborate heterocylcic macromolecules. Their complexity makes it difficult to investigate the electron-phonon coupling. In this work we resolve the electron-phonon interactions in the ground and doped state in a complex push-pull polymer. We focus on the polaronic transitions using in-situ spectroscopy to work out the differences between single-unit and push-pull systems to obtain the desired structural- electronic correlations in the doped state. We apply the classic 1D-Froehlich model to generate optical model fits. Interestingly, we find the 1D-approach in push-pull polarons in agreement to the model, pointing at the strong 1D-character and plain electronic structure of the push-pull structure. In contrast, polarons in the single-unit polymer emerge to a multi- dimensional problem difficult to resolve due to their anisotropy. Thus, we report an enhancement of the 1D-character by the push-pull concept in the doped state - an important view in light of the main purpose of push-pull polymers for photovoltaic devices.

Nanoscale structural and electronic characterization of α-RuCl3 layered compound

NASA Astrophysics Data System (ADS)

Ziatdinov, Maxim; Maksov, Artem; Banerjee, Arnab; Zhou, Wu; Berlijn, Tom; Yan, Jiaqiang; Nagler, Stephen; Mandrus, David; Baddorf, Arthur; Kalinin, Sergei

The exceptional interplay of spin-orbit effects, Coulomb interaction, and electron-lattice coupling is expected to produce an elaborate phase space of α-RuCl3 layered compound, which to date remains largely unexplored. Here we employ a combination of scanning transmission electron microscopy (STEM) and scanning tunneling microscopy (STM) for detailed evaluation of the system's microscopic structural and electronic orders with a sub-nanometer precision. The STM and STEM measurements are further supported by neutron scattering, X-Ray diffraction, density functional theory (DFT), and multivariate statistical analysis. Our results show a trigonal distortion of Cl octahedral ligand cage along the C3 symmetry axes in each RuCl3 layer. The lattice distortion is limited mainly to the Cl subsystem leaving the Ru honeycomb lattice nearly intact. The STM topographic and spectroscopic characterization reveals an intra unit cell electronic symmetry breaking in a spin-orbit coupled Mott insulating phase on the Cl-terminated surface of α-RuCl3. The associated long-range charge order (CO) pattern is linked to a surface component of Cl cage distortion. We finally discuss a fine structure of CO and its potential relation to variations of average unit cell geometries found in multivariate analysis of STEM data. The research was sponsored by the U.S. Department of Energy.

Oxygen Displacement in Cuprates under Ionic Liquid Field-Effect Gating

PubMed Central

Dubuis, Guy; Yacoby, Yizhak; Zhou, Hua; He, Xi; Bollinger, Anthony T.; Pavuna, Davor; Pindak, Ron; Božović, Ivan

2016-01-01

We studied structural changes in a 5 unit cell thick La1.96Sr0.04CuO4 film, epitaxially grown on a LaSrAlO4 substrate with a single unit cell buffer layer, when ultra-high electric fields were induced in the film by applying a gate voltage between the film (ground) and an ionic liquid in contact with it. Measuring the diffraction intensity along the substrate-defined Bragg rods and analyzing the results using a phase retrieval method we obtained the three-dimensional electron density in the film, buffer layer, and topmost atomic layers of the substrate under different applied gate voltages. The main structural observations were: (i) there were no structural changes when the voltage was negative, holes were injected into the film making it more metallic and screening the electric field; (ii) when the voltage was positive, the film was depleted of holes becoming more insulating, the electric field extended throughout the film, the partial surface monolayer became disordered, and equatorial oxygen atoms were displaced towards the surface; (iii) the changes in surface disorder and the oxygen displacements were both reversed when a negative voltage was applied; and (iv) the c-axis lattice constant of the film did not change in spite of the displacement of equatorial oxygen atoms. PMID:27578237

Generation of a consensus protein domain dictionary

PubMed Central

Schaeffer, R. Dustin; Jonsson, Amanda L.; Simms, Andrew M.; Daggett, Valerie

2011-01-01

Motivation: The discovery of new protein folds is a relatively rare occurrence even as the rate of protein structure determination increases. This rarity reinforces the concept of folds as reusable units of structure and function shared by diverse proteins. If the folding mechanism of proteins is largely determined by their topology, then the folding pathways of members of existing folds could encompass the full set used by globular protein domains. Results: We have used recent versions of three common protein domain dictionaries (SCOP, CATH and Dali) to generate a consensus domain dictionary (CDD). Surprisingly, 40% of the metafolds in the CDD are not composed of autonomous structural domains, i.e. they are not plausible independent folding units. This finding has serious ramifications for bioinformatics studies mining these domain dictionaries for globular protein properties. However, our main purpose in deriving this CDD was to generate an updated CDD to choose targets for MD simulation as part of our dynameomics effort, which aims to simulate the native and unfolding pathways of representatives of all globular protein consensus folds (metafolds). Consequently, we also compiled a list of representative protein targets of each metafold in the CDD. Availability and implementation: This domain dictionary is available at www.dynameomics.org. Contact: daggett@u.washington.edu Supplementary information: Supplementary data are available at Bioinformatics online. PMID:21068000

The auxetic behavior of an expanded periodic cellular structure

NASA Astrophysics Data System (ADS)

Ciolan, Mihaela A.; Lache, Simona; Velea, Marian N.

2018-02-01

Within nowadays research, when it comes to lightweight sandwich panels, periodic cellular structures are considered real trendsetters. One of the most used type of core in producing sandwich panels is the honeycomb. However, due to its relatively high manufacturing cost, this structure has limited applications; therefore, research has been carried out in order to develop alternative solutions. An example in this sense is the ExpaAsym cellular structure, developed at the Transilvania University of Braşov; it represents a periodic cellular structure manufactured through a mechanically expansion process of a previously cut and perforated sheet material. The relative density of the structure was proven to be significantly lower than the one of the honeycomb. This gives a great advantage to the structure, due to the fact that when the internal angle A of the unit cell is 60°, after the mechanical expansion it results a hexagonal structure. The main objective of this paper is to estimate the in-plane Poisson ratios of the structure, in terms of its geometrical parameters. It is therefore analytically shown that for certain values of the geometric parameters, the in-plane Poisson ratios have negative values when the internal angle exceeds 90°, which determines its auxetic behavior.

Mathematical structure of unit systems

NASA Astrophysics Data System (ADS)

Kitano, Masao

2013-05-01

We investigate the mathematical structure of unit systems and the relations between them. Looking over the entire set of unit systems, we can find a mathematical structure that is called preorder (or quasi-order). For some pair of unit systems, there exists a relation of preorder such that one unit system is transferable to the other unit system. The transfer (or conversion) is possible only when all of the quantities distinguishable in the latter system are always distinguishable in the former system. By utilizing this structure, we can systematically compare the representations in different unit systems. Especially, the equivalence class of unit systems (EUS) plays an important role because the representations of physical quantities and equations are of the same form in unit systems belonging to an EUS. The dimension of quantities is uniquely defined in each EUS. The EUS's form a partially ordered set. Using these mathematical structures, unit systems and EUS's are systematically classified and organized as a hierarchical tree.

Post-magmatic tectonic deformation of the outer Izu-Bonin-Mariana forearc system: initial results of IODP Expedition 352

NASA Astrophysics Data System (ADS)

Kurz, Walter; Ferré, Eric C.; Robertson, Alastair; Avery, Aaron; Christeson, Gail L.; Morgan, Sally; Kutterorf, Steffen; Sager, William W.; Carvallo, Claire; Shervais, John; Party IODP Expedition 352, Scientific

2015-04-01

IODP Expedition 352 was designed to drill through the entire volcanic sequence of the Bonin forearc. Four sites were drilled, two on the outer fore arc and two on the upper trench slope. Site survey seismic data, combined with borehole data, indicate that tectonic deformation in the outer IBM fore arc is mainly post-magmatic. Post-magmatic extension resulted in the formation of asymmetric sedimentary basins such as, for example, the half-grabens at sites 352-U1439 and 352-U1442 located on the upper trench slope. Along their eastern margins these basins are bounded by west-dipping normal faults. Sedimentation was mainly syn-tectonic. The lowermost sequence of the sedimentary units was tilted eastward by ~20°. These tilted bedding planes were subsequently covered by sub-horizontally deposited sedimentary beds. Based on biostratigraphic constraints, the minimum age of the oldest sediments is ~ 35 Ma; the timing of the sedimentary unconformities lies between ~ 27 and 32 Ma. At sites 352-U1440 and 352-U1441, located on the outer forearc, post-magmatic deformation resulted mainly in strike-slip faults possibly bounding the sedimentary basins. The sedimentary units within these basins were not significantly affected by post-sedimentary tectonic tilting. Biostratigraphic ages indicate that the minimum age of the basement-cover contact lies between ~29.5 and 32 Ma. Overall, the post-magmatic tectonic structures observed during Expedition 352 reveal a multiphase tectonic evolution of the outer IBM fore arc. At sites 352-U1439 and 352-U1442, shear with dominant reverse to oblique reverse displacement was localized along distinct subhorizontal cataclastic shear zones as well as steeply dipping slickensides and shear fractures. These structures, forming within a contractional tectonic regime, were either re-activated as or cross-cut by normal-faults as well as strike-slip faults. Extension was also accommodated by steeply dipping to subvertical mineralized veins and extensional fractures. Faults observed at sites 352-U1440 and 352-U1441 show mainly strike-slip. The sediments overlying the igneous basement, of maximum Late Eocene to Recent age, document ash and aeolian input, together with mass wasting of the fault-bounded sediment ponds.

Tectonic evolution and crustal-scale structure of Kyrgyz Central Asian Orogenic Belt: new insights from the Darius programme

NASA Astrophysics Data System (ADS)

Rolland, Yann; Loury, Chloé; Guillot, Stéphane; Mikolaichuk, Alexander

2014-05-01

Mechanisms and history of the Late Palaeozoic accretion followed by formation of trunscurrent strike-slip faults were studied in the southern segment of the Central Asian Orogenic Belt (CAOB) within Kyrgyz South Tianshan. 1. South Tianshan Suture: ending accretion process after docking of Tarim craton This study gives insights into the crustal-scale structure and Upper Paleozoic history of this mountain belt, currently intensely reactivated by the India-Asia collision. Structural, petrological and geochronological studies were carried out within South Tianshan suture east of the Talas-Ferghana Fault (TFF). New data highlight a south-dipping structure featured by a HP metamorphic core complex comprised of c. 320 Ma continental and oceanic eclogites exhumed by top-to-North motion. A large massif (10 x 50 km) of continental HP rocks in the Atbashi Range is comprised of hectometric boudins of eclogites embedded in metapelites and gneissesMetamorphic units exhibit blueschist to eclogite facies conditions, with oceanic (MORB) rocks in the blueschist facies representing the accretionary oceanic prism being thrusted by oceanic rocks and a continental unit in the eclogite facies (510 ± 50°C and 24 ± 2 kbar). Evidence for eclogite facies both in metasediments and mafic lithologies and geological structure are in agreement with a previously thinned continental margin. Subduction of this thinned COT (Continent-Ocean Transition) probably occurred by slab pull in a south-dipping subduction zone, while another north-dipping subduction was active below Middle Tianshan. Final stacking of Middle and South Tianshan occurred at 320-310 Ma. These opposite subduction zones are still reflected in the main structures of Tianshan. Reactivation of the South-dipping structures since 30-25 Ma is ascribed to explain the current Tianshan intra-continental subduction from seismology. 2. Talas-Ferghana Fault (TFF) activity & Basin formation After this accretionary episode, the South Tianshan suture was cross-cut by the TFF, which was active in several stages from 320 Ma to present. The main events of basin formation are ascribed to the activity of the dextral TFF (Rolland et al. 2013, JAES). Ar-Ar dating undertaken on syn-kinematic minerals that feature the phases of motion of the TFF show a first stage of activation occurred at 312 ± 4 Ma, followed by a main stage of dextral motion in the Late Permian at 256 - 250 Ma, while late stages of reactivation of TFF is featured by emplacement of 195 ± 3 Ma pegmatitic dykes, formation of transtensional basins during Jurassic, dextral offsets of river valleys and ongoing seismicity. 3. Reactivation of South Tian Shan Suture Most prominent topography in Central Asia corresponds to the former South Tianshan suture which has been reactivated since about 30 Ma, the former Carboniferous thrusts are reactivated in a pop-up structure with top-north and top-south faults bounding the high mountains of Khan Tengri and Pobeda peaks (7440 m a.s.l.).

78 FR 18325 - Intent To Prepare an Environmental Impact Statement (EIS) for the Formal Training Unit (FTU) and...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-26

... Statement (EIS) for the Formal Training Unit (FTU) and Main Operating Base 1 (MOB 1) for the Beddown of KC... Statement (EIS) for the Formal Training Unit (FTU) and Main Operating Base 1 (MOB 1) for the Beddown of KC...-46A tanker aircraft, associated infrastructure and manpower of the FTU and MOB 1 at existing active...

Structural definition of arabinomannans from Mycobacterium bovis BCG.

PubMed

Nigou, J; Gilleron, M; Brando, T; Vercellone, A; Puzo, G

1999-06-01

The structures of the hydrophilic parietal and cellular arabinomannans isolated from Mycobacterium bovis BCG cell wall [Nigou et al. (1997) J Biol Chem 272: 23094-103] were investigated. Their molecular mass as determined by MALDI-TOF mass spectrometry was around 16 kDa. Concerning cap structure, capillary electrophoresis analysis demonstrated that dimannoside (Manpalpha1-->2Manp) was the most abundant motif (65-75%). Using two-dimensional 1H-13C NMR spectroscopy, the mannan core was unambiguously demonstrated to be composed of -->6Manpalpha1--> backbone substituted at some O-2 by a single Manp unit. The branching degree was determined as 84%. Finally, arabinomannans were found to be devoid of the phosphatidyl-myo-inositol anchor and, by aminonaphthalene disulfonate tagging, the mannan core was shown to contain a reducing end. This constitutes the main difference between arabinomannans and lipoarabinomannans from Mycobacterium bovis BCG.

Investigation of methanogenic community structures in rural biogas digesters from different climatic regions in Yunnan, southwest China.

PubMed

Dong, Minghua; Wu, Yan; Li, Qiumin; Tian, Guangliang; Yang, Bin; Li, Yingjuan; Zhang, Lijuan; Wang, Yongxia; Xiao, Wei; Yin, Fang; Zhao, Xingling; Zhang, Wudi; Cui, Xiaolong

2015-05-01

Understanding of the microbial community structures of the biogas digesters in different climatic regions can help improve the methane production in the fermentation process. The methanogenic archaeal diversity in four rural biogas digesters (BNA, JSA, LJA, and XGA) was investigated by a culture-independent rRNA approach in different climatic regions in Yunnan. Community structure composed of 711 clones in the all libraries. A total of 33 operational taxonomic units (OTUs) were detected, and major groups of methanogens were the orders Methanosarcinales and Methanomicrobiales. 63.2 % of all archaeal OTUs belong to the order Methanosarcinales which mostly contain acetotrophic methanogens. Methanomicrobiales (19.5 % in all OTUs) were detected in considerable number. Additionally, there were minor rates of uncultured archaea. The principal component analysis indicated that the genus Methanosaeta was mainly affected by the fermentation temperatures.

The influence of the structure of the metal load removal from liquid steel in electric arc furnaces

NASA Astrophysics Data System (ADS)

Pǎcurar, Cristina; Hepuť, Teodor; Crisan, Eugen

2016-06-01

One of the main technical and economic indicators in the steel industry and steel respectively the development it is the removal of liquid steel. This indicator depends on several factors, namely technology: the structure and the quality metal load, the degree of preparedness of it, and the content of non-metallic material accompanying the unit of drawing up, the technology for the elaboration, etc. research has been taken into account in drawing up steel electric arc furnace type spring EBT (Electric Bottom taping), seeking to load and removing components of liquid steel. Metal load has been composed of eight metal grades, in some cases with great differences in terms of quality. Data obtained were processed in the EXCEL spreadsheet programs and MATLAB, the results obtained being presented both graphically and analytically. On the basis of the results obtained may opt for a load optimal structure metal.

3-Methyl-5-methyl­sulfanyl-1,3,4-thia­diazole-2(3H)-thione

PubMed Central

Suarez, Sebastian A.; Hazari, Saroj K. S.; Ganguly, Biplab; Doctorovich, Fabio; G. Roy, Tapashi; Baggio, Ricardo

2012-01-01

The title compound, C4H6N2S3, has two very similar mol­ecules per asymmetric unit. The nine non-H atoms in each mol­ecule are coplanar, both having comparable r.m.s. deviations of 0.002 Å. The main inter­est in the rather simple structure resides in a survey of very weak (in some cases, borderline) non-bonding inter­actions of various kinds, viz. S⋯S, C—H⋯π, π–π [centroid–centroid distance = 3.8958 (13) Å] and C—S⋯π [3.7271 (11) Å], which act as the major driving force for the arrangement of mol­ecules in the structure. The role of long, though highly directional, S⋯S contacts (d > 3.60 Å), and their relevance to the stability of the structure is discussed. PMID:23125808

Understanding the Relationship Between Structure and Thermophysical Properties of CaO-SiO2-MgO-Al2O3 Molten Slags

NASA Astrophysics Data System (ADS)

Sun, Yongqi; Wang, Hao; Zhang, Zuotai

2018-04-01

In the present work, the relationship between the microscopic structure and macroscopic thermophysical properties in a basic CaO-SiO2-MgO-Al2O3 quaternary system was identified using Fourier transformation infrared, Raman and 27Al magic angular spinning nuclear magnetic resonance (MAS-NMR) techniques. The Raman spectra quantitatively proved that with increasing Al2O3 content, the concentrations of the symmetric units of Q 0(Si) and Q 2(Si) decreased, while those of the asymmetric units of Q 1(Si) and Q 3(Si) increased; consequently, the degree of polymerization of the networks increased, which resulted in an increase in slag viscosity. The 27Al MAS-NMR spectra demonstrated that three structural units of Al atoms, namely, AlO4, AlO5, and AlO6, mainly existed in the networks. With increasing Al2O3 content, the concentration of AlO4 slightly decreased, while those of AlO5 and AlO6 increased; overall, Al2O3 acted as a network former in the present system. The increasing Al2O3 content led to additional AlO6 and Si-NBO-Ca-NBO-Al frameworks, which replaced Si-NBO-Ca-NBO-Si in the networks (NBO: non-bridging oxygen) and induced a change in the primarily precipitated crystalline phase from Ca2MgSi2O7 and Ca2Al2SiO7 to MgAlO4.

Quantitative analysis of ground penetrating radar data in the Mu Us Sandland

NASA Astrophysics Data System (ADS)

Fu, Tianyang; Tan, Lihua; Wu, Yongqiu; Wen, Yanglei; Li, Dawei; Duan, Jinlong

2018-06-01

Ground penetrating radar (GPR), which can reveal the sedimentary structure and development process of dunes, is widely used to evaluate aeolian landforms. The interpretations for GPR profiles are mostly based on qualitative descriptions of geometric features of the radar reflections. This research quantitatively analyzed the waveform parameter characteristics of different radar units by extracting the amplitude and time interval parameters of GPR data in the Mu Us Sandland in China, and then identified and interpreted different sedimentary structures. The results showed that different types of radar units had specific waveform parameter characteristics. The main waveform parameter characteristics of sand dune radar facies and sandstone radar facies included low amplitudes and wide ranges of time intervals, ranging from 0 to 0.25 and 4 to 33 ns respectively, and the mean amplitudes changed gradually with time intervals. The amplitude distribution curves of various sand dune radar facies were similar as unimodal distributions. The radar surfaces showed high amplitudes with time intervals concentrated in high-value areas, ranging from 0.08 to 0.61 and 9 to 34 ns respectively, and the mean amplitudes changed drastically with time intervals. The amplitude and time interval values of lacustrine radar facies were between that of sand dune radar facies and radar surfaces, ranging from 0.08 to 0.29 and 11 to 30 ns respectively, and the mean amplitude and time interval curve was approximately trapezoidal. The quantitative extraction and analysis of GPR reflections could help distinguish various radar units and provide evidence for identifying sedimentary structure in aeolian landforms.

Multi-scale strain localization within orthogneiss during subduction and exhumation (Tenda unit, Alpine Corsica)

NASA Astrophysics Data System (ADS)

Beaudoin, Alexandre; Augier, Romain; Jolivet, Laurent; Raimbourg, Hugues; Jourdon, Anthony; Scaillet, Stéphane; Cardello, Giovanni Luca

2016-04-01

Strain localization depends upon scale-related factors resulting in a gap between small-scale studies of deformation mechanisms and large-scale numerical and tectonic models. The former often ignore the variations in composition and water content across tectonic units, while the latter oversimplify the role of the deformation mechanisms. This study aims to heal this gap, by considering microstructures and strain localization not only at a single shear zone-scale but across a 40km-wide tectonic unit and throughout its complex polyphased evolution. The Tenda unit (Alpine Corsica) is an external continental unit mainly composed of granites, bounded by the East Tenda Shear Zone (ETSZ) that separates it from the overlying oceanic-derived HP tectonic units. Previous studies substantially agreed on (1) the burial of the Tenda unit down to blueschist-facies conditions associated with top-to-the-west shearing (D1) and (2) subsequent exhumation accommodated by a localized top-to-the-east shear zone (D2). Reaction-softening is the main localizing mechanism proposed in the literature, being associated with the transformation of K-feldspar into white-mica. In this work, the Tenda unit is reviewed through (1) the construction of a new field-based strain map accompanied by cross-sections representing volumes of rock deformed at different grades related to large-scale factors of strain localization and (2) the structural study of hand-specimens and thin-sections coupled with EBSD analysis in order to target the deformation processes. We aim to find how softening and localization are in relation to the map-scale distribution of strain. The large-scale study shows that the whole Tenda unit is affected by the two successive stages of deformation. However, a more intense deformation is observed along the eastern margin, which originally led to the definition of the ETSZ, with a present-day anastomosed geometry of deformation. Strain localization is clearly linked to rheological/lithological contrasts as it concentrates either along preexisting intrusive and tectonic contacts. As K-feldspar-poor granites remain relatively undeformed, reaction-softening seems to be a major mechanism during D1. However, evidences suggest that this mechanism is in competition with dynamic recrystallization: at outcrop and hand-specimen scale, the correlation between localized structures such as C-planes and phengite-rich zones is not always observed. This same competition remains active during D2 where top-to-the-east C-planes are common in phengite-rich layers, but an overall grain-size reduction is also observed across the different strain grades, suggesting that dynamic recrystallization remains active during the whole story. Final localization is sometimes observed in phengite-poor aplitic ultramylonites characterized by a very fine quartz-albite matrix suggesting that grain-size sensitive flow would be the major mechanism involved in the final rheology of the ETSZ.

Coordination of Leaf Photosynthesis, Transpiration, and Structural Traits in Rice and Wild Relatives (Genus Oryza)1[W][OA

PubMed Central

Giuliani, Rita; Koteyeva, Nuria; Voznesenskaya, Elena; Evans, Marc A.; Cousins, Asaph B.; Edwards, Gerald E.

2013-01-01

The genus Oryza, which includes rice (Oryza sativa and Oryza glaberrima) and wild relatives, is a useful genus to study leaf properties in order to identify structural features that control CO2 access to chloroplasts, photosynthesis, water use efficiency, and drought tolerance. Traits, 26 structural and 17 functional, associated with photosynthesis and transpiration were quantified on 24 accessions (representatives of 17 species and eight genomes). Hypotheses of associations within, and between, structure, photosynthesis, and transpiration were tested. Two main clusters of positively interrelated leaf traits were identified: in the first cluster were structural features, leaf thickness (Thickleaf), mesophyll (M) cell surface area exposed to intercellular air space per unit of leaf surface area (Smes), and M cell size; a second group included functional traits, net photosynthetic rate, transpiration rate, M conductance to CO2 diffusion (gm), stomatal conductance to gas diffusion (gs), and the gm/gs ratio. While net photosynthetic rate was positively correlated with gm, neither was significantly linked with any individual structural traits. The results suggest that changes in gm depend on covariations of multiple leaf (Smes) and M cell (including cell wall thickness) structural traits. There was an inverse relationship between Thickleaf and transpiration rate and a significant positive association between Thickleaf and leaf transpiration efficiency. Interestingly, high gm together with high gm/gs and a low Smes/gm ratio (M resistance to CO2 diffusion per unit of cell surface area exposed to intercellular air space) appear to be ideal for supporting leaf photosynthesis while preserving water; in addition, thick M cell walls may be beneficial for plant drought tolerance. PMID:23669746

Coordination of Leaf Photosynthesis, Transpiration, and Structural Traits in Rice and Wild Relatives (Genus Oryza).

PubMed

Giuliani, Rita; Koteyeva, Nuria; Voznesenskaya, Elena; Evans, Marc A; Cousins, Asaph B; Edwards, Gerald E

2013-07-01

The genus Oryza, which includes rice (Oryza sativa and Oryza glaberrima) and wild relatives, is a useful genus to study leaf properties in order to identify structural features that control CO(2) access to chloroplasts, photosynthesis, water use efficiency, and drought tolerance. Traits, 26 structural and 17 functional, associated with photosynthesis and transpiration were quantified on 24 accessions (representatives of 17 species and eight genomes). Hypotheses of associations within, and between, structure, photosynthesis, and transpiration were tested. Two main clusters of positively interrelated leaf traits were identified: in the first cluster were structural features, leaf thickness (Thick(leaf)), mesophyll (M) cell surface area exposed to intercellular air space per unit of leaf surface area (S(mes)), and M cell size; a second group included functional traits, net photosynthetic rate, transpiration rate, M conductance to CO(2) diffusion (g(m)), stomatal conductance to gas diffusion (g(s)), and the g(m)/g(s) ratio.While net photosynthetic rate was positively correlated with gm, neither was significantly linked with any individual structural traits. The results suggest that changes in gm depend on covariations of multiple leaf (S(mes)) and M cell (including cell wall thickness) structural traits. There was an inverse relationship between Thick(leaf) and transpiration rate and a significant positive association between Thick(leaf) and leaf transpiration efficiency. Interestingly, high g(m) together with high g(m)/g(s) and a low S(mes)/g(m) ratio (M resistance to CO(2) diffusion per unit of cell surface area exposed to intercellular air space) appear to be ideal for supporting leaf photosynthesis while preserving water; in addition, thick M cell walls may be beneficial for plant drought tolerance.

The Solar-Terrestrial Environment

NASA Astrophysics Data System (ADS)

Hargreaves, John Keith

1995-05-01

The book begins with three introductory chapters that provide some basic physics and explain the principles of physical investigation. The principal material contained in the main part of the book covers the neutral and ionized upper atmosphere, the magnetosphere, and structures, dynamics, disturbances, and irregularities. The concluding chapter deals with technological applications. The account is introductory, at a level suitable for readers with a basic background in engineering or physics. The intent is to present basic concepts, and for that reason, the mathematical treatment is not complex. SI units are given throughout, with helpful notes on cgs units where these are likely to be encountered in the research literature. This book is suitable for advanced undergraduate and graduate students who are taking introductory courses on upper atmospheric, ionospheric, or magnetospheric physics. This is a successor to The Upper Atmosphere and Solar-Terrestrial Relations, published in 1979.

Biodegradation of photo-oxidized lignite and characterization of the products

NASA Astrophysics Data System (ADS)

Li, Jiantao; Liu, Xiangrong; Yue, Zilin; Zhang, Yaowen

2018-01-01

Biodegradation of photo-oxidized Inner Mongolia lignite by pseudomonas aeruginosa was studied and the degradation percentage reached 56.27%, while the corresponding degradation percentage of the strain degrading raw Inner Mongolia lignite is only 23.16%. The degradation products were characterized. Proximate and ultimate analyses show that the higher oxygen content increased by photo-oxidation pretreatment maybe promoted the degradation process. Ultraviolet spectroscopy (UV) analysis of the liquid product reveals that it contains unsaturated structures and aromatic rings are the main structure units. Gas chromatography-mass spectrometry (GC-MS) analysis indicates that the main components of the ethyl acetate extracts are low molecular weight organic compounds, such as ketones, acids, hydrocarbons, esters and alcohols. Infrared spectroscopy (IR) analysis of raw lignite, photo-oxidized lignite and residual lignite demonstrates that the absorption peaks of functional groups in residual lignite disappeared or weakened obviously. Scanning electron microscopy (SEM) analysis manifests that small holes appear in photo-oxidized lignite surface, which may be promote the degradation process and this is only from the physical morphology aspects, so it can be inferred from the tests and analyses results that the more important reason of the high degradation percentage is mostly that the photo-oxidation pretreatment changes the chemical structures of lignite.

Joint inversion of seismic and gravity data for imaging seismic velocity structure of the crust and upper mantle beneath Utah, United States

DOE PAGES

Syracuse, Ellen Marie; Zhang, Haijiang; Maceira, Monica

2017-07-11

Here, we present a method for using any combination of body wave arrival time measurements, surface wave dispersion observations, and gravity data to simultaneously invert for three-dimensional P- and S-wave velocity models. The simultaneous use of disparate data types takes advantage of the differing sensitivities of each data type, resulting in a comprehensive and higher resolution three-dimensional geophysical model. In a case study for Utah, we combine body waves first arrivals mainly from the USArray Transportable Array, Rayleigh wave group and phase velocity dispersion data, and Bouguer gravity anomalies to invert for crustal and upper mantle structure of the region.more » Results show clear delineations, visible in both P- and S-wave velocities, between the three main tectonic provinces in the region. In conclusion, without the inclusion of the surface wave and gravity constraints, these delineations are less clear, particularly for S-wave velocities. Indeed, checkerboard tests confirm that the inclusion of the additional datasets dramatically improves S-wave velocity recovery, with more subtle improvements to P-wave velocity recovery, demonstrating the strength of the method in successfully recovering seismic velocity structure from multiple types of constraints.« less

Joint inversion of seismic and gravity data for imaging seismic velocity structure of the crust and upper mantle beneath Utah, United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Syracuse, Ellen Marie; Zhang, Haijiang; Maceira, Monica

Here, we present a method for using any combination of body wave arrival time measurements, surface wave dispersion observations, and gravity data to simultaneously invert for three-dimensional P- and S-wave velocity models. The simultaneous use of disparate data types takes advantage of the differing sensitivities of each data type, resulting in a comprehensive and higher resolution three-dimensional geophysical model. In a case study for Utah, we combine body waves first arrivals mainly from the USArray Transportable Array, Rayleigh wave group and phase velocity dispersion data, and Bouguer gravity anomalies to invert for crustal and upper mantle structure of the region.more » Results show clear delineations, visible in both P- and S-wave velocities, between the three main tectonic provinces in the region. In conclusion, without the inclusion of the surface wave and gravity constraints, these delineations are less clear, particularly for S-wave velocities. Indeed, checkerboard tests confirm that the inclusion of the additional datasets dramatically improves S-wave velocity recovery, with more subtle improvements to P-wave velocity recovery, demonstrating the strength of the method in successfully recovering seismic velocity structure from multiple types of constraints.« less

Hierarchical control of two-dimensional gaze saccades

PubMed Central

Optican, Lance M.; Blohm, Gunnar; Lefèvre, Philippe

2014-01-01

Coordinating the movements of different body parts is a challenging process for the central nervous system because of several problems. Four of these main difficulties are: first, moving one part can move others; second, the parts can have different dynamics; third, some parts can have different motor goals; and fourth, some parts may be perturbed by outside forces. Here, we propose a novel approach for the control of linked systems with feedback loops for each part. The proximal parts have separate goals, but critically the most distal part has only the common goal. We apply this new control policy to eye-head coordination in two-dimensions, specifically head-unrestrained gaze saccades. Paradoxically, the hierarchical structure has controllers for the gaze and the head, but not for the eye (the most distal part). Our simulations demonstrate that the proposed control structure reproduces much of the published empirical data about gaze movements, e.g., it compensates for perturbations, accurately reaches goals for gaze and head from arbitrary initial positions, simulates the nine relationships of the head-unrestrained main sequence, and reproduces observations from lesion and single-unit recording experiments. We conclude by showing how our model can be easily extended to control structures with more linked segments, such as the control of coordinated eye on head on trunk movements. PMID:24062206

Internode data communications in a parallel computer

DOEpatents

Archer, Charles J.; Blocksome, Michael A.; Miller, Douglas R.; Parker, Jeffrey J.; Ratterman, Joseph D.; Smith, Brian E.

2013-09-03

Internode data communications in a parallel computer that includes compute nodes that each include main memory and a messaging unit, the messaging unit including computer memory and coupling compute nodes for data communications, in which, for each compute node at compute node boot time: a messaging unit allocates, in the messaging unit's computer memory, a predefined number of message buffers, each message buffer associated with a process to be initialized on the compute node; receives, prior to initialization of a particular process on the compute node, a data communications message intended for the particular process; and stores the data communications message in the message buffer associated with the particular process. Upon initialization of the particular process, the process establishes a messaging buffer in main memory of the compute node and copies the data communications message from the message buffer of the messaging unit into the message buffer of main memory.

Internode data communications in a parallel computer

DOEpatents

Archer, Charles J; Blocksome, Michael A; Miller, Douglas R; Parker, Jeffrey J; Ratterman, Joseph D; Smith, Brian E

2014-02-11

Internode data communications in a parallel computer that includes compute nodes that each include main memory and a messaging unit, the messaging unit including computer memory and coupling compute nodes for data communications, in which, for each compute node at compute node boot time: a messaging unit allocates, in the messaging unit's computer memory, a predefined number of message buffers, each message buffer associated with a process to be initialized on the compute node; receives, prior to initialization of a particular process on the compute node, a data communications message intended for the particular process; and stores the data communications message in the message buffer associated with the particular process. Upon initialization of the particular process, the process establishes a messaging buffer in main memory of the compute node and copies the data communications message from the message buffer of the messaging unit into the message buffer of main memory.

Situational and dispositional influences on nurses' workplace well-being: the role of empowering unit leadership.

PubMed

Spence Laschinger, Heather K; Finegan, Joan; Wilk, Piotr

2011-01-01

Unit-level leadership and structural empowerment play key roles in creating healthy work environments, yet few researchers have examined these contextual effects on nurses' well-being. The aim of this study was to test a multilevel model of structural empowerment examining the effect of nursing unit leadership quality and structural empowerment on nurses' experiences of burnout and job satisfaction and to examine the effect of a personal dispositional variable, core self-evaluation, on these nurse experiences. Nurses (n = 3,156) from 217 hospital units returned surveys that included measures of leader-member exchange, structural empowerment, burnout, core self-evaluation, and job satisfaction. Multilevel structural equation modeling was used to test the model. Nurses' shared perceptions of leader-member exchange quality on their units positively influenced their shared perceptions of unit structural empowerment (Level 2), which resulted in significantly higher levels of individual nurse job satisfaction (Level 1). Unit-level leader-member exchange quality also directly influenced individual nurse job satisfaction. Unit leader-member exchange quality and structural empowerment influenced emotional exhaustion and cynicism differentially. Higher unit-level leader-member exchange quality was associated with lower cynicism; higher unit-level structural empowerment was associated with lower emotional exhaustion. At Level 1, higher core self-evaluation was associated with lower levels of both emotional exhaustion and cynicism, both of which were associated with lower job satisfaction. This study provides a theoretical understanding of how unit leadership affects both unit- and individual-level outcomes.

The impact of long-term hydrocarbon exposure on the structure, activity, and biogeochemical functioning of microbial mats.

PubMed

Aubé, Johanne; Senin, Pavel; Pringault, Olivier; Bonin, Patricia; Deflandre, Bruno; Bouchez, Olivier; Bru, Noëlle; Biritxinaga-Etchart, Edurne; Klopp, Christophe; Guyoneaud, Rémy; Goñi-Urriza, Marisol

2016-10-15

Photosynthetic microbial mats are metabolically structured systems driven by solar light. They are ubiquitous and can grow in hydrocarbon-polluted sites. Our aim is to determine the impact of chronic hydrocarbon contamination on the structure, activity, and functioning of a microbial mat. We compared it to an uncontaminated mat harboring similar geochemical characteristics. The mats were sampled in spring and fall for 2years. Seasonal variations were observed for the reference mat: sulfur cycle-related bacteria dominated spring samples, while Cyanobacteria dominated in autumn. The contaminated mat showed minor seasonal variation; a progressive increase of Cyanobacteria was noticed, indicating a perturbation of the classical seasonal behavior. Hydrocarbon content was the main factor explaining the differences in the microbial community structure; however, hydrocarbonoclastic bacteria were among rare or transient Operational Taxonomic Units (OTUs) in the contaminated mat. We suggest that in long-term contaminated systems, hydrocarbonoclastic bacteria cannot be considered a sentinel of contamination. Copyright © 2016 Elsevier Ltd. All rights reserved.

Integrating geologic and satellite radar data for mapping dome-and-basin patterns in the In Ouzzal Terrane, Western Hoggar, Algeria

NASA Astrophysics Data System (ADS)

Deroin, Jean-Paul; Djemai, Safouane; Bendaoud, Abderrahmane; Brahmi, Boualem; Ouzegane, Khadidja; Kienast, Jean-Robert

2014-11-01

The In Ouzzal Terrane (IOT) located in the north-western part of the Tuareg Shield forms an elongated N-S trending block, more than 400 km long and 80 km wide. It involves an Archaean crust remobilized during a very high-temperature metamorphic event related to the Palaeoproterozoic orogeny. The IOT largely crops out in the rocky and sandy desert of Western Hoggar. It corresponds mainly to a flat area with some reliefs composed of Late Panafrican granites, dyke networks or Cambrian volcanic rocks. These flat areas are generally covered by thin sand veneers. They are favorable for discriminating bedrock geological units using imaging radar, backscattering measurements, and field checking, because the stony desert is particularly sensitive to the radar parameters such as wavelength or polarization. The main radar data used are those obtained with the ALOS-PALSAR sensor (L-band), in ScanSAR mode (large swath) and Fine Beam modes. The PALSAR sensor has been also compared to ENVISAT-ASAR and to optical imagery. Detailed mapping of some key areas indicates extensive Archaean dome-and-basin patterns. In certain parts, the supracrustal synforms and orthogneiss domes exhibit linear or circular features corresponding to shear zones or rolling structures, respectively. The geological mapping of these dome-and-basin structures, and more generally of the Archaean and Proterozoic lithological units, is more accurate with the SAR imagery, particularly when using the L-band, than with the optical imagery. A quantitative approach is carried out in order to estimate the backscatter properties of the main rock types. Due to the large variety of configurations, radar satellite imagery such as ALOS PALSAR represents a key tool for geological mapping in arid region at different scales from the largest (e.g., 1:500,000) to the smallest (e.g., 1:50,000).

The process of implementation of emergency care units in Brazil.

PubMed

O'Dwyer, Gisele; Konder, Mariana Teixeira; Reciputti, Luciano Pereira; Lopes, Mônica Guimarães Macau; Agostinho, Danielle Fernandes; Alves, Gabriel Farias

2017-12-11

To analyze the process of implementation of emergency care units in Brazil. We have carried out a documentary analysis, with interviews with twenty-four state urgency coordinators and a panel of experts. We have analyzed issues related to policy background and trajectory, players involved in the implementation, expansion process, advances, limits, and implementation difficulties, and state coordination capacity. We have used the theoretical framework of the analysis of the strategic conduct of the Giddens theory of structuration. Emergency care units have been implemented after 2007, initially in the Southeast region, and 446 emergency care units were present in all Brazilian regions in 2016. Currently, 620 emergency care units are under construction, which indicates expectation of expansion. Federal funding was a strong driver for the implementation. The states have planned their emergency care units, but the existence of direct negotiation between municipalities and the Union has contributed with the significant number of emergency care units that have been built but that do not work. In relation to the urgency network, there is tension with the hospital because of the lack of beds in the country, which generates hospitalizations in the emergency care unit. The management of emergency care units is predominantly municipal, and most of the emergency care units are located outside the capitals and classified as Size III. The main challenges identified were: under-funding and difficulty in recruiting physicians. The emergency care unit has the merit of having technological resources and being architecturally differentiated, but it will only succeed within an urgency network. Federal induction has generated contradictory responses, since not all states consider the emergency care unit a priority. The strengthening of the state management has been identified as a challenge for the implementation of the urgency network.

The process of implementation of emergency care units in Brazil

PubMed Central

O'Dwyer, Gisele; Konder, Mariana Teixeira; Reciputti, Luciano Pereira; Lopes, Mônica Guimarães Macau; Agostinho, Danielle Fernandes; Alves, Gabriel Farias

2017-01-01

ABSTRACT OBJECTIVE To analyze the process of implementation of emergency care units in Brazil. METHODS We have carried out a documentary analysis, with interviews with twenty-four state urgency coordinators and a panel of experts. We have analyzed issues related to policy background and trajectory, players involved in the implementation, expansion process, advances, limits, and implementation difficulties, and state coordination capacity. We have used the theoretical framework of the analysis of the strategic conduct of the Giddens theory of structuration. RESULTS Emergency care units have been implemented after 2007, initially in the Southeast region, and 446 emergency care units were present in all Brazilian regions in 2016. Currently, 620 emergency care units are under construction, which indicates expectation of expansion. Federal funding was a strong driver for the implementation. The states have planned their emergency care units, but the existence of direct negotiation between municipalities and the Union has contributed with the significant number of emergency care units that have been built but that do not work. In relation to the urgency network, there is tension with the hospital because of the lack of beds in the country, which generates hospitalizations in the emergency care unit. The management of emergency care units is predominantly municipal, and most of the emergency care units are located outside the capitals and classified as Size III. The main challenges identified were: under-funding and difficulty in recruiting physicians. CONCLUSIONS The emergency care unit has the merit of having technological resources and being architecturally differentiated, but it will only succeed within an urgency network. Federal induction has generated contradictory responses, since not all states consider the emergency care unit a priority. The strengthening of the state management has been identified as a challenge for the implementation of the urgency network. PMID:29236876

Reconnaissance geologic study of the Vazante zinc district, Minas Gerais, Brazil

USGS Publications Warehouse

Thorman, Charles H.; Nahass, Samir

1977-01-01

The Vazante district, Minas Gerais, 130 km south of Paracatu, produces nearly all of Brazil's zinc metal. The district is situated on the western side of the Late Precambrian Bambul basin and along the eastern and leading edge of the north-trending Brazilian orogenic belt (ca. 600-500 m.y. old) that borders the western margin of the basin. Reconnaissance study indicates that bedding and low-angle thrust faulting, folding, and low-grade metamorphism dominated the structural development of the district. The structural trend within the district is northeasterly, and dips 20?-45 ? NW. Three sets of folds developed during the main period of eastward thrusting of older Precambrian rocks over the western margin of the Bambui basin. A fourth fold set is transverse to the regional trend. The rocks in the district are tentatively assigned to the Paraopeba Formation of the Bambui Group and are designated A through C in ascending order. Unit A is phyllite to phyllitic siltstone. Unit B consists of interbedded dolomitic limestone and marl-limestone. Irregularly distributed limestone ledges 20 to 100 m thick have the appearance of boudins. Their origin is attributed to a combination of rapid lateral facies changes and differential movement at different structural levels along bedding and low-angle thrust faults, with the formation of tear faults vertically limited by the thrust faults. Unit C consists of interbedded siltstone, dolomitic limestone, and sandstone. Phyllitic rocks along member interfaces in units B and C and at the base of unit C indicate differential penetrative deformation and bedding faulting. The contacts between units A, B, and C are interpreted to be low-angle or bedding faults, and their original stratigraphic positions with respect to each other is unknown. Zinc silicate minerals (hemimorphite and willemite) occur in a folded breccia zone in the lower part of unit B. The breccia zone is interpreted to be tectonic in origin, having formed along the step of a step-bedding-plane fault during the Brazilian orogeny. The zinc is probably syngenetic, and ore deposition in the breccia may have occurred during Brazilian time. Broad uplift and deep weathering of the region took place during late Mesozoic and Cenozoic time. Reserves may be as high as 3 million tons of zinc metal.

The geology and chronology of the Acheulean deposits in the Mieso area (East-Central Ethiopia).

PubMed

Benito-Calvo, Alfonso; Barfod, Dan N; McHenry, Lindsay J; de la Torre, Ignacio

2014-11-01

This paper presents the Quaternary sequence of the Mieso area of Central-East Ethiopia, located in the piedmont between the SE Ethiopian Escarpment and the Main Ethiopian Rift-Afar Rift transition sector.In this region, a piedmont alluvial plain is terraced at þ25 m above the two main fluvial courses, the Mieso and Yabdo Rivers. The piedmont sedimentary sequence is divided into three stratigraphic units separated by unconformities. Mieso Units I and II contain late Acheulean assemblages and a weakly consolidated alluvial sequence, consisting mainly of fine sediments with buried soils and, to a lesser degree, conglomerates. Palaeo-wetland areas were common in the alluvial plain, represented by patches of tufas, stromatolites and clays. At present, the piedmont alluvial surface is preserved mainly on a dark brown soil formed at the top of Unit II. Unit III corresponds to a fluvial deposit overlying Unit II, and is defined by sands, silty clays and gravels, including several Later Stone Age (LSA) occurrences. Three fine-grained tephra levels are interbedded in Unit I (tuffs TBI and TA) and II (tuff CB), and are usually spatially-constrained and reworked. Argon/argon (40Ar/39Ar) dating from tuff TA, an ash deposit preserved in a palustrine environment, yielded an age of 0.212 ± 0.016 Ma (millions of years ago). This date places thetop of Unit I in the late Middle Pleistocene, with Acheulean sites below and above tuff TA. Regional correlations tentatively place the base of Unit I around the Early-Middle Pleistocene boundary, Unit II inthe late Middle Pleistocene and within the Late Pleistocene, and the LSA occurrences of Unit III in the LatePleistoceneeHolocene.

3. ELEVATIONS, ADDITION TO POWER HOUSE. United Engineering Company Ltd., ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. ELEVATIONS, ADDITION TO POWER HOUSE. United Engineering Company Ltd., Alameda Shipyard. John Hudspeth, architect, foot of Main Street, Alameda, California. Sheet 4. Plan no. 10,548. Scale 1/4 inch to the foot, elevations, and one inch to the foot, sections and details. April 30, 1945, last revised 6/19/45. pencil on vellum - United Engineering Company Shipyard, Boiler House, 2900 Main Street, Alameda, Alameda County, CA

A dual-route cascaded model of reading by deaf adults: evidence for grapheme to viseme conversion.

PubMed

Elliott, Eeva A; Braun, Mario; Kuhlmann, Michael; Jacobs, Arthur M

2012-01-01

There is an ongoing debate whether deaf individuals access phonology when reading, and if so, what impact the ability to access phonology might have on reading achievement. However, the debate so far has been theoretically unspecific on two accounts: (a) the phonological units deaf individuals may have of oral language have not been specified and (b) there seem to be no explicit cognitive models specifying how phonology and other factors operate in reading by deaf individuals. We propose that deaf individuals have representations of the sublexical structure of oral-aural language which are based on mouth shapes and that these sublexical units are activated during reading by deaf individuals. We specify the sublexical units of deaf German readers as 11 "visemes" and incorporate the viseme set into a working model of single-word reading by deaf adults based on the dual-route cascaded model of reading aloud by Coltheart, Rastle, Perry, Langdon, and Ziegler (2001. DRC: A dual route cascaded model of visual word recognition and reading aloud. Psychological Review, 108, 204-256. doi: 10.1037//0033-295x.108.1.204). We assessed the indirect route of this model by investigating the "pseudo-homoviseme" effect using a lexical decision task in deaf German reading adults. We found a main effect of pseudo-homovisemy, suggesting that at least some deaf individuals do automatically access sublexical structure during single-word reading.

Barriers to the sustainability of an intervention designed to improve patient engagement within NHS mental health rehabilitation units: a qualitative study nested within a randomised controlled trial.

PubMed

Lean, Melanie; Leavey, Gerard; Killaspy, Helen; Green, Nicholas; Harrison, Isobel; Cook, Sarah; Craig, Thomas; Holloway, Frank; Arbuthnott, Maurice; King, Michael

2015-09-02

We undertook a cluster randomised controlled trial to assess the effectiveness of a staff training intervention to improve patient engagement in activities in inpatient mental health rehabilitation units. Concurrently, we undertook a qualitative study to investigate the experiences of staff within the intervention units and the contextual issues that may have influenced the effectiveness of the intervention. We conducted focus groups with staff working in the inpatient units that received the intervention, sampled using a maximum variation strategy. The intervention was accepted by staff. However, the skills gained, and changes to the unit's processes and structures that were agreed with the intervention team were not sustained after they left. The main reasons for this were a) external factors (economic recession, resource limitations); b) organisation level factors (lack of senior staff support; competing priorities); c) limitations of the intervention itself (length of intensive training period; reinforcement of skills). This study illustrates some of the inter-related factors which operate at different levels within and outside of NHS organisations that may impact on the success of complex interventions. These factors need to be considered when designing interventions to ensure adequate buy-in from senior staff. Current Controlled Trials ISRCTN25898179 (Registered 23 April 2010).

Structural style and hydrocarbon trap of Karbasi anticline, in the Interior Fars region, Zagros, Iran

NASA Astrophysics Data System (ADS)

Maleki, Z.; Arian, M.; Solgi, A.

2014-07-01

Karbasi anticline between west-northwest parts of Jahrom town is located in northwest 40 km distance of Aghar gas anticline in interior Fars region. This anticline has asymmetric structure and some faults with large strike separation observed in its structure. The operation of Nezamabad sinistral strike slip fault in west part of this anticline caused fault plunge change in this region. Because of complication increasing of structures geometry in Fars region and necessity to exploration activities for deeper horizons especially the Paleozoic ones, the analysis of fold style elements, which is known as one of the main parts in structural studies seems necessary. In this paper because of some reasons such as Karbasi anticline structural complication, importance of drilling and hydrocarbon explorations in Fars region, it is proceed to analysis and evaluation of fold style elements and geometry with emphasis on Nezamabad fault operation in Interior Fars region. According to fold style elements analysis results, it became clear that in east part of anticline the type of fold horizontal moderately inclined and in west part it is upright moderately plunging, so west evaluation of anticline is affected by more deformation. In this research the relationship present faults especially the Nezamabad sinistral strike slip one with folding and its affection on Dehram horizon and Bangestan group were modeled. Based on received results may be the Nezamabad fault is located between G-G' and E-E' structural sections and this fault in this area operated same as fault zone. In different parts of Karbasi anticline, Dashtak formation as a middle detachment unit plays an important role in connection to folding geometry, may be which is affected by Nezamabad main fault.

75 FR 10669 - Airworthiness Directives; The Boeing Company Model 747-100, 747-200B, 747-300, and 747SR Series...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-03-09

... results from a report of water contamination in the electrical and electronic units in the main equipment... from a report of water contamination in the electrical and electronic units in the main equipment...

Thermoacoustic refrigerators and engines comprising cascading stirling thermodynamic units

DOEpatents

Backhaus, Scott; Swift, Greg

2013-06-25

The present invention includes a thermoacoustic assembly and method for improved efficiency. The assembly has a first stage Stirling thermal unit comprising a main ambient heat exchanger, a regenerator and at least one additional heat exchanger. The first stage Stirling thermal unit is serially coupled to a first end of a quarter wavelength long coupling tube. A second stage Stirling thermal unit comprising a main ambient heat exchanger, a regenerator, and at least one additional heat exchanger, is serially coupled to a second end of the quarter wavelength long coupling tube.

Isolation and Structural Characterization of Lignin from Cotton Stalk Treated in an Ammonia Hydrothermal System

PubMed Central

Kang, Sumin; Xiao, Lingping; Meng, Lingyan; Zhang, Xueming; Sun, Runcang

2012-01-01

To investigate the potential for the utilization of cotton stalk, ammonia hydrothermal treatment was applied to fractionate the samples into aqueous ammonia-soluble and ammonia-insoluble portions. The ammonia-soluble portion was purified to yield lignin fractions. The lignin fractions obtained were characterized by wet chemistry (carbohydrate analysis) and spectroscopy methods (FT-IR, 13C and 1H-13C HSQC NMR spectroscopy) as well as gel permeation chromatography (GPC). The results showed that the cotton stalk lignin fractions were almost absent of neutral sugars (0.43%–1.29%) and had relatively low average molecular weights (1255–1746 g/mol). The lignin fractions belonged to typical G-S lignin, which was composed predominately of G-type units (59%) and noticeable amounts of S-type units (40%) together with a small amount of H-type units (~1%). Furthermore, the ammonia-extractable lignin fractions were mainly composed of β-O-4′ inter-unit linkages (75.6%), and small quantities of β-β′ (12.2%), together with lower amounts of β-5′ carbon-carbon linkages (7.4%) and p-hydroxycinnamyl alcohol end groups. PMID:23203120

Design and optimize of 3-axis filament winding machine

NASA Astrophysics Data System (ADS)

Quanjin, Ma; Rejab, M. R. M.; Idris, M. S.; Bachtiar, B.; Siregar, J. P.; Harith, M. N.

2017-10-01

Filament winding technique is developed as the primary process for composite cylindrical structures fabrication at low cost. Fibres are wound on a rotating mandrel by a filament winding machine where resin impregnated fibres pass through a pay-out eye. This paper aims to develop and optimize a 3-axis, lightweight, practical, efficient, portable filament winding machine to satisfy the customer demand, which can fabricate pipes and round shape cylinders with resins. There are 3 main units on the 3-axis filament winding machine, which are the rotary unit, the delivery unit and control system unit. Comparison with previous existing filament winding machines in the factory, it has 3 degrees of freedom and can fabricate more complex shape specimens based on the mandrel shape and particular control system. The machine has been designed and fabricated on 3 axes movements with control system. The x-axis is for movement of the carriage, the y-axis is the rotation of mandrel and the z-axis is the movement of the pay-out eye. Cylindrical specimens with different dimensions and winding angles were produced. 3-axis automated filament winding machine has been successfully designed with simple control system.

Multistory duplexes with forward dipping roofs, north central Brooks Range, Alaska

USGS Publications Warehouse

Wallace, W.K.; Moore, Thomas E.; Plafker, G.

1997-01-01

The Endicott Mountains allochthon has been thrust far northward over the North Slope parautochthon in the northern Brooks Range. Progressively younger units are exposed northward within the allochthon. To the south, the incompetent Hunt Fork Shale has thickened internally by asymmetric folds and thrust faults. Northward, the competent Kanayut Conglomerate forms a duplex between a floor thrust in Hunt Fork and a roof thrust in the Kayak Shale. To the north, the competent Lisburne Group forms a duplex between a floor thrust in Kayak and a roof thrust in the Siksikpuk Formation. Both duplexes formed from north vergent detachment folds whose steep limbs were later truncated by south dipping thrust faults that only locally breach immediately overlying roof thrusts. Within the parautochthon, the Kayak, Lisburne, and Siksikpuk-equivalent Echooka Formation form a duplex identical to that in the allochthon. This duplex is succeeded abruptly northward by detachment folds in Lisburne. These folds are parasitic to an anticlinorium interpreted to reflect a fault-bend folded horse in North Slope "basement," with a roof thrust in Kayak and a floor thrust at depth. These structures constitute two northward tapered, internally deformed wedges that are juxtaposed at the base of the allochthon. Within each wedge, competent units have been shortened independently between detachments, located mainly in incompetent units. The basal detachment of each wedge cuts upsection forward (northward) to define a wedge geometry within which units dip regionally forward. These dips reflect forward decrease in internal structural thickening by forward vergent folds and hindward dipping thrust faults. Copyright 1997 by the American Geophysical Union.

Geological Map of the Fredegonde (V-57) Quadrangle, Venus

NASA Technical Reports Server (NTRS)

Ivanov, M. A.; Head, J. W.

2009-01-01

The area of V-57, the Fredegonde quadrangle (50-75degS, 60-120degE, Fig.1), is located within the eastern portion of Lada Terra within the topographic province of midlands (0-2 km above MPR [1,2]). Midlands form the most abundant portion of the surface of Venus and are characterized by diverse sets of units and structures [3-11]. The area of the Fredegonde quadrangle is in contact with the elevated portion of Lada Terra to the W and with the lowland of Aino Planitia to the NE. The transitions of the mid-lands to the lowlands and highlands are, thus, one of the main themes of the geology within the V-57 quadrangle. The character of the transitions and distribution and sequence of units/structures in the midlands are crucially important in understanding the time and modes of formation of this topographic province. The most prominent features in the map area are linear deformational zones consisting of swarms of grooves and graben and large coronae. The zones characterize the central and NW portions of the map area and represent regionally important, broad (up to 100s km wide) ridges that are 100s m high. Relatively small (100s km across, 100s m deep) equidimensional basins occur between the corona-groove-chains in the west and border the central chain from the east. Here we describe units that make up the surface within the V-57 quadrangle and present a summary of our geological map that shows the areal distribution of the major groups of units.

Crystalline molecular machines: Encoding supramolecular dynamics into molecular structure

PubMed Central

Garcia-Garibay, Miguel A.

2005-01-01

Crystalline molecular machines represent an exciting new branch of crystal engineering and materials science with important implications to nanotechnology. Crystalline molecular machines are crystals built with molecules that are structurally programmed to respond collectively to mechanic, electric, magnetic, or photonic stimuli to fulfill specific functions. One of the main challenges in their construction derives from the picometric precision required for their mechanic operation within the close-packed, self-assembled environment of crystalline solids. In this article, we outline some of the general guidelines for their design and apply them for the construction of molecular crystals with units intended to emulate macroscopic gyroscopes and compasses. Recent advances in the preparation, crystallization, and dynamic characterization of these interesting systems offer a foothold to the possibilities and help highlight some avenues for future experimentation. PMID:16046543

KSC-07pd2025

NASA Image and Video Library

2007-07-19

KENNEDY SPACE CENTER, Fla. -- In the Orbiter Processing Facility bay 3, a crane lowers the main bus switching unit into Discovery's payload bay. The unit is part of the payload on mission STS-120.A main bus switching unit is used for power distribution, circuit protection and fault isolation on the space station's power system. The units route power to proper locations in the space station, such as from solar arrays through umbilicals into the U.S. Lab. The unit will be installed on the external stowage platform 2 attached to the Quest airlock for temporary storage. Discovery is targeted to launch mission STS-120 no earlier than Oct. 20. Photo credit: NASA/Jim Grossmann

Argument structure hierarchy system and method for facilitating analysis and decision-making processes

DOEpatents

Janssen, Terry

2000-01-01

A system and method for facilitating decision-making comprising a computer program causing linkage of data representing a plurality of argument structure units into a hierarchical argument structure. Each argument structure unit comprises data corresponding to a hypothesis and its corresponding counter-hypothesis, data corresponding to grounds that provide a basis for inference of the hypothesis or its corresponding counter-hypothesis, data corresponding to a warrant linking the grounds to the hypothesis or its corresponding counter-hypothesis, and data corresponding to backing that certifies the warrant. The hierarchical argument structure comprises a top level argument structure unit and a plurality of subordinate level argument structure units. Each of the plurality of subordinate argument structure units comprises at least a portion of the grounds of the argument structure unit to which it is subordinate. Program code located on each of a plurality of remote computers accepts input from one of a plurality of contributors. Each input comprises data corresponding to an argument structure unit in the hierarchical argument structure and supports the hypothesis or its corresponding counter-hypothesis. A second programming code is adapted to combine the inputs into a single hierarchical argument structure. A third computer program code is responsive to the second computer program code and is adapted to represent a degree of support for the hypothesis and its corresponding counter-hypothesis in the single hierarchical argument structure.

Buckling behavior of origami unit cell facets under compressive loads

NASA Astrophysics Data System (ADS)

Kshad, Mohamed Ali Emhmed; Naguib, Hani E.

2018-03-01

Origami structures as cores for sandwich structures are designed to withstand the compressive loads and to dissipate compressive energy. The deformation of the origami panels and the unit cell facets are the primary factors behind the compressive energy dissipation in origami structures. During the loading stage, the origami structures deform through the folding and unfolding process of the unit cell facets, and also through the plastic deformation of the facets. This work presents a numerical study of the buckling behavior of different origami unit cell elements under compressive loading. The studied origami configurations were Miura and Ron-Resch-like origami structures. Finite element package was used to model the origami structures. The study investigated the buckling behavior of the unit cell facets of two types of origami structures Miura origami and Ron-Resch-Like origami structures. The simulation was conducted using ANSYS finite element software, in which the model of the unit cell represented by shell elements, and the eigenvalues buckling solver was used to predict the theoretical buckling of the unit cell elements.

11. VIEW NORTH, SOUTH FRONT OF MAIN OFFICE UNIT (BUILDING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. VIEW NORTH, SOUTH FRONT OF MAIN OFFICE UNIT (BUILDING I, 2); SOUTH AND EAST FRONTS OF SEED STORAGE BUILDING (BUILDING 21); EAST FRONT OF GREENHOUSE #1 (BUILDING 5) - U.S. Plant Introduction Station, 11601 Old Pond Road, Glenn Dale, Prince George's County, MD

Structural rearrangements in chloroplast thylakoid membranes revealed by differential scanning calorimetry and circular dichroism spectroscopy. Thermo-optic effect.

PubMed

Dobrikova, Anelia G; Várkonyi, Zsuzsanna; Krumova, Sashka B; Kovács, László; Kostov, Georgi K; Todinova, Svetla J; Busheva, Mira C; Taneva, Stefka G; Garab, Gyozo

2003-09-30

The thermo-optic mechanism in thylakoid membranes was earlier identified by measuring the thermal and light stabilities of pigment arrays with different levels of structural complexity [Cseh, Z., et al. (2000) Biochemistry 39, 15250-15257]. (According to the thermo-optic mechanism, fast local thermal transients, arising from the dissipation of excess, photosynthetically not used, excitation energy, induce elementary structural changes due to the "built-in" thermal instabilities of the given structural units.) The same mechanism was found to be responsible for the light-induced trimer-to-monomer transition in LHCII, the main chlorophyll a/b light-harvesting antenna of photosystem II (PSII) [Garab, G., et al. (2002) Biochemistry 41, 15121-15129]. In this paper, differential scanning calorimetry (DSC) and circular dichroism (CD) spectroscopy on thylakoid membranes of barley and pea are used to correlate the thermo-optically inducible structural changes with well-discernible calorimetric transitions. The thylakoid membranes exhibited six major DSC bands, with maxima between about 43 and 87 degrees C. The heat sorption curves were analyzed both by mathematical deconvolution of the overall endotherm and by a successive annealing procedure; these yielded similar thermodynamic parameters, transition temperature and calorimetric enthalpy. A systematic comparison of the DSC and CD data on samples with different levels of complexity revealed that the heat-induced disassembly of chirally organized macrodomains contributes profoundly to the first endothermic event, a weak and broad DSC band between 43 and 48 degrees C. Similarly to the main macrodomain-associated CD signals, this low enthalpy band could be diminished by prolonged photoinhibitory preillumination, the extent of which depended on the temperature of preillumination. By means of nondenaturing, "green" gel electrophoresis and CD fingerprinting, it is shown that the second main endotherm, around 60 degrees C, originates to a large extent from the monomerization of LHCII trimers. The main DSC band, around 70 degrees C, which exhibits the highest enthalpy change, and another band around 75-77 degrees C relate to the dismantling of LHCII and other pigment-protein complexes, which under physiologically relevant conditions cannot be induced by light. The currently available data suggest the following sequence of events of thermo-optically inducible changes: (i) unstacking of membranes, followed by (ii) lateral disassembly of the chiral macrodomains and (iii) monomerization of LHCII trimers. We propose that thermo-optical structural reorganizations provide a structural flexibility, which is proportional to the intensity of the excess excitation, while for their localized nature, the structural stability of the system can be retained.

Structure and formation of highly luminescent protein-stabilized gold clusters† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc05086k

PubMed Central

Chevrier, D. M.; Thanthirige, V. D.; Luo, Z.; Driscoll, S.; Cho, P.; MacDonald, M. A.; Yao, Q.; Guda, R.; Xie, J.; Johnson, E. R.; Chatt, A.; Zheng, N.

2018-01-01

Highly luminescent gold clusters simultaneously synthesized and stabilized by protein molecules represent a remarkable category of nanoscale materials with promising applications in bionanotechnology as sensors. Nevertheless, the atomic structure and luminescence mechanism of these gold clusters are still unknown after several years of developments. Herein, we report findings on the structure, luminescence and biomolecular self-assembly of gold clusters stabilized by the large globular protein, bovine serum albumin. We highlight the surprising identification of interlocked gold-thiolate rings as the main gold structural unit. Importantly, such gold clusters are in a rigidified state within the protein scaffold, offering an explanation for their highly luminescent character. Combined free-standing cluster synthesis (without protecting protein scaffold) with rigidifying and un-rigidifying experiments, were designed to further verify the luminescence mechanism and gold atomic structure within the protein. Finally, the biomolecular self-assembly process of the protein-stabilized gold clusters was elucidated by time-dependent X-ray absorption spectroscopy measurements and density functional theory calculations. PMID:29732064

Velocity and pressure fields associated with near-wall turbulence structures

NASA Technical Reports Server (NTRS)

Johansson, Arne V.; Alfredsson, P. Henrik; Kim, John

1990-01-01

Computer generated databases containing velocity and pressure fields in three-dimensional space at a sequence of time-steps, were used for the investigation of near-wall turbulence structures, their space-time evolution, and their associated pressure fields. The main body of the results were obtained from simulation data for turbulent channel flow at a Reynolds number of 180 (based on half-channel height and friction velocity) with a grid of 128 x 129 x and 128 points. The flow was followed over a total time of 141 viscous time units. Spanwise centering of the detected structures was found to be essential in order to obtain a correct magnitude of the associated Reynolds stress contribution. A positive wall-pressure peak is found immediately beneath the center of the structure. The maximum amplitude of the pressure pattern was, however, found in the buffer region at the center of the shear-layer. It was also found that these flow structures often reach a maximum strength in connection with an asymmetric spanwise motion, which motivated the construction of a conditional sampling scheme that preserved this asymmetry.

Family Structure and Adolescent Substance Use: An International Perspective.

PubMed

Hoffmann, John P

2017-11-10

Numerous studies indicate that family structure is a key correlate of adolescent substance use. Yet there are some important limitations to this research. Studies have been conducted mainly in the United States, with relatively few studies that have compared family structure and youth substance use across nations. There is also a lack of recognition of the complexity of family types prevalent in contemporary global society. Moreover, there remains a need to consider personal, interpersonal, and macro-level characteristics that may help account for the association between family structure and youth substance use. This study uses data from 37 countries to examine several models that purport to explain the association between family structure and substance use. The data are from the 2005-2006 WHO-sponsored Health Behaviour in School-Aged Children (HBSC) (n = 193,202). Multilevel models, including linear, probit, and structural equation models (SEMs), were used to test several hypotheses. The results suggest that time spent with friends largely accounted for the association between specific types of family structures and frequency of alcohol use and getting drunk, but that cannabis use was negatively associated with living with both biological parents irrespective of other factors.

The lived experiences of autonomous Angolan midwives working in midwifery-led, maternity units.

PubMed

Pettersson, K O; Svensson, M L; Christensson, K

2001-06-01

to describe the lived experiences of autonomous midwives working in Angolan midwifery-led maternity units. a qualitative approach using semi-structured, audiotaped interviews, in Portugese. Data were analysed in a six-step process. three midwifery-led maternity units in the most densely populated suburbs in the capital of Angola, Luanda. The average number of deliveries per unit was 2500 per year. 11 midwives from the three maternity units. four main areas emerged: society/culture, significant others, personal self and professional self. Sub-areas, concepts and supporting statements were defined in each area. the midwives served within a population living in rough circumstances but which maintained strong traditional roots. The midwives did not support homebirths, but did assist when needed. The midwives described their professional role as a 'calling', which was very independent. Cure, was considered more important than care, and strong emotions were expressed when discussing cases of failure. The partograph was viewed as an important instrument and continuous learning as crucial in their role as autonomous midwives. the model of a midwifery-led delivery unit described in this study may be used in other countries facing the same problems as Angola. Difficulties concerning transfer should be seriously considered as well as adequate education for the midwives. A pre-requisite in order for peripheral maternity units to have any impact on maternal morbidity and mortality, is a well-organised first-referral level. Copyright 2001 Harcourt Publishers Ltd.

Structural and petrographic constraints on the stratigraphy of the Lapataia Formation, with implications for the tectonic evolution of the Fuegian Andes

NASA Astrophysics Data System (ADS)

Cao, Sebastián J.; Torres Carbonell, Pablo J.; Dimieri, Luis V.

2018-07-01

The structure of the Fuegian Andes central belt is characterized by a first phase of peak metamorphism and ductile deformation, followed by a brittle-ductile thrusting phase including juxtaposition of different (first phase) structural levels; both related to the closure and inversion of the Late Jurassic-Early Cretaceous Rocas Verdes basin. The second phase involved thrust sheets of pre-Jurassic basement, as well as Upper Jurassic and Lower Cretaceous units from the volcanic-sedimentary fill of the basin. Rock exposures in the Parque Nacional Tierra del Fuego reveal a diversity of metamorphic mineral assemblages, dynamic recrystallization grades and associated structures, evidencing a variety of protoliths and positions in the crust during their orogenic evolution. Among the units present in this sector, the Lapataia Formation portrays the higher metamorphic grade reported in the Argentine side of the Fuegian Andes, and since no precise radiometric ages have been established to date, its stratigraphic position remains a matter of debate: the discussion being whether it belongs to the pre-Jurassic basement, or the Upper Jurassic volcanic/volcaniclastic initial fill of the Rocas Verdes basin. The mapping and petrographic/microstructural study of the Lapataia Formation and those of undoubtedly Mesozoic age, allow to characterize the former as a group of rocks with great lithological affinity with the Upper Jurassic metamorphic rocks found elsewhere in the central belt of the Fuegian Andes. The main differences in metamorphic grade are indebted to its deformation at deeper crustal levels, but during the same stages than the Mesozoic rocks. Accordingly, we interpret the regional structure to be associated with the stacking of thrust sheets from different structural levels through the emplacement of a duplex system during the growth of the Fuegian Andes.

The modifiable areal unit problem (MAUP) in the relationship between exposure to NO2 and respiratory health

PubMed Central

2011-01-01

Background Many Canadian population health studies, including those focusing on the relationship between exposure to air pollution and health, have operationalized neighbourhoods at the census tract scale. At the same time, the conceptualization of place at the local scale is one of the weakest theoretical aspects in health geography. The modifiable areal unit problem (MAUP) raises issues when census tracts are used as neighbourhood proxies, and no other alternate spatial structure is used for sensitivity analysis. In the literature, conclusions on the relationship between NO2 and health outcomes are divided, and this situation may in part be due to the selection of an inappropriate spatial structure for analysis. Here, we undertake an analysis of NO2 and respiratory health in Ottawa, Canada using three different spatial structures in order to elucidate the effects that the spatial unit of analysis can have on analytical results. Results Using three different spatial structures to examine and quantify the relationship between NO2 and respiratory morbidity, we offer three main conclusions: 1) exploratory spatial analytical methods can serve as an indication of the potential effect of the MAUP; 2) OLS regression results differ significantly using different spatial representations, and this could be a contributing factor to the lack of consensus in studies that focus on the relation between NO2 and respiratory health at the area-level; and 3) the use of three spatial representations confirms no measured effect of NO2 exposure on respiratory health in Ottawa. Conclusions Area units used in population health studies should be delineated so as to represent the a priori scale of the expected scale interaction between neighbourhood processes and health. A thorough understanding of the role of the MAUP in the study of the relationship between NO2 and respiratory health is necessary for research into disease pathways based on statistical models, and for decision-makers to assess the scale at which interventions will have maximum benefit. In general, more research on the role of spatial representation in health studies is needed. PMID:22040001

The Vertebrate Brain, Evidence of Its Modular Organization and Operating System: Insights into the Brain's Basic Units of Structure, Function, and Operation and How They Influence Neuronal Signaling and Behavior.

PubMed

Baslow, Morris H

2011-01-01

The human brain is a complex organ made up of neurons and several other cell types, and whose role is processing information for use in eliciting behaviors. However, the composition of its repeating cellular units for both structure and function are unresolved. Based on recent descriptions of the brain's physiological "operating system", a function of the tri-cellular metabolism of N-acetylaspartate (NAA) and N-acetylaspartylglutamate (NAAG) for supply of energy, and on the nature of "neuronal words and languages" for intercellular communication, insights into the brain's modular structural and functional units have been gained. In this article, it is proposed that the basic structural unit in brain is defined by its physiological operating system, and that it consists of a single neuron, and one or more astrocytes, oligodendrocytes, and vascular system endothelial cells. It is also proposed that the basic functional unit in the brain is defined by how neurons communicate, and consists of two neurons and their interconnecting dendritic-synaptic-dendritic field. Since a functional unit is composed of two neurons, it requires two structural units to form a functional unit. Thus, the brain can be envisioned as being made up of the three-dimensional stacking and intertwining of myriad structural units which results not only in its gross structure, but also in producing a uniform distribution of binary functional units. Since the physiological NAA-NAAG operating system for supply of energy is repeated in every structural unit, it is positioned to control global brain function.

Lithium formate ion clusters formation during electrospray ionization: Evidence of magic number clusters by mass spectrometry and ab initio calculations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shukla, Anil, E-mail: Anil.Shukla@pnnl.gov; Bogdanov, Bogdan

2015-02-14

Small cationic and anionic clusters of lithium formate were generated by electrospray ionization and their fragmentations were studied by tandem mass spectrometry (collision-induced dissociation with N{sub 2}). Singly as well as multiply charged clusters were formed in both positive and negative ion modes with the general formulae, (HCOOLi){sub n}Li{sup +}, (HCOOLi){sub n}Li{sub m}{sup m+}, (HCOOLi){sub n}HCOO{sup −}, and (HCOOLi){sub n}(HCOO){sub m}{sup m−}. Several magic number cluster (MNC) ions were observed in both the positive and negative ion modes although more predominant in the positive ion mode with (HCOOLi){sub 3}Li{sup +} being the most abundant and stable cluster ion. Fragmentations ofmore » singly charged positive clusters proceed first by the loss of a dimer unit ((HCOOLi){sub 2}) followed by the loss of monomer units (HCOOLi) although the former remains the dominant dissociation process. In the case of positive cluster ions, all fragmentations lead to the magic cluster (HCOOLi){sub 3}Li{sup +} as the most abundant fragment ion at higher collision energies which then fragments further to dimer and monomer ions at lower abundances. In the negative ion mode, however, singly charged clusters dissociated via sequential loss of monomer units. Multiply charged clusters in both positive and negative ion modes dissociated mainly via Coulomb repulsion. Quantum chemical calculations performed for smaller cluster ions showed that the trimer ion has a closed ring structure similar to the phenalenylium structure with three closed rings connected to the central lithium ion. Further additions of monomer units result in similar symmetric structures for hexamer and nonamer cluster ions. Thermochemical calculations show that trimer cluster ion is relatively more stable than neighboring cluster ions, supporting the experimental observation of a magic number cluster with enhanced stability.« less

CLOSE UP OF THE RECESSED MAIN ENTRY OF THE UNIT ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

CLOSE UP OF THE RECESSED MAIN ENTRY OF THE UNIT - Camp H.M. Smith and Navy Public Works Center Manana Title VII (Capehart) Housing, U-Shaped Two-Bedroom Single-Family Type 6, Birch Circle, Elm Drive, Elm Circle, and Date Drive, Pearl City, Honolulu County, HI

14 CFR 27.725 - Limit drop test.

Code of Federal Regulations, 2011 CFR

2011-01-01

... M for main gear units (lbs.), equal to the static reaction on the particular unit with the... reaction, taking into consideration the moment arm between the main wheel reaction and the rotorcraft... reaction that would exist at the nose wheel, assuming that the mass of the rotorcraft acts at the center of...

Hexakis(N,N-dimethyl­formamide-κO)cobalt(II) bis­(perchlorate)

PubMed Central

Eissmann, Frank; Böhle, Tony; Mertens, Florian O. R. L.; Weber, Edwin

2010-01-01

The asymmetric unit of the title complex, [Co(DMF)6](ClO4)2 (DMF = N,N-dimethyl­formamide, C3H7NO), consists of two half complex cations with the Co2+ metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co2+ ion is coordinated by six mol­ecules of DMF in a slightly distorted octa­hedral geometry. The crystal structure is mainly stabilized by coordinative, ionic and C—H⋯O hydrogen-bonding inter­actions. PMID:21580225

ENEL power generation and transmission control (PGTC) system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Galli, F.; Schiavi

1986-08-01

The ENEL (Italian State Power Board) PGTC System has a multi-level architecture which consists of a National Control Center (NCC), eight Area Control Centers (ACC), and Remote Terminal Units (RTU). Remote Control Centers (RCC), representing the third hierarchical level of the control system, will be integrated into the system beginning in 1987. This paper describes the structure of the PGTC system from the remote stations up to the NCC and the main control functions. The method of implementation, the organizational and managerial problems that were faced in the development of the project are also described.

[Considering human peculiarities in attention to health care through dialogue and assistance].

PubMed

Pereira, Adriana Dall'Asta; de Freitas, Hilda Maria Barbosa; Ferreira, Carla Lizandra de Lima; Marchiori, Mara Regina Caino Teixeira; Souza, Martha Helena Teixeira; Backes, Dirce Stein

2010-03-01

The aim of this qualitative exploratory research is to understand how health workers relate to the main object of their work--the user--both subject and author of his/her life history. Eleven nursing practitioners from a Basic Health Unit participated in a semi-structured instrument, in March and April, 2008. The speeches revealed two converging themes: (1) Consideration of human peculiarities in attention to health care; and (2) dialogue and assistance as interactive possibilities. We found that the attention to health care is broadening the debates over valuing human peculiarities through dialogue and assistance as interactive possibilities.

Diagnosis and management of acute heart failure.

PubMed

Ural, Dilek; Çavuşoğlu, Yüksel; Eren, Mehmet; Karaüzüm, Kurtuluş; Temizhan, Ahmet; Yılmaz, Mehmet Birhan; Zoghi, Mehdi; Ramassubu, Kumudha; Bozkurt, Biykem

2015-11-01

Acute heart failure (AHF) is a life threatening clinical syndrome with a progressively increasing incidence in general population. Turkey is a country with a high cardiovascular mortality and recent national statistics show that the population structure has turned to an 'aged' population.As a consequence, AHF has become one of the main reasons of admission to cardiology clinics. This consensus report summarizes clinical and prognostic classification of AHF, its worldwide and national epidemiology, diagnostic work-up, principles of approach in emergency department,intensive care unit and ward, treatment in different clinical scenarios and approach in special conditions and how to plan hospital discharge.

Efficiency of optical-electronic systems: methods application for the analysis of structural changes in the process of eye grounds diagnosis

NASA Astrophysics Data System (ADS)

Saldan, Yosyp R.; Pavlov, Sergii V.; Vovkotrub, Dina V.; Saldan, Yulia Y.; Vassilenko, Valentina B.; Mazur, Nadia I.; Nikolaichuk, Daria V.; Wójcik, Waldemar; Romaniuk, Ryszard; Suleimenov, Batyrbek; Bainazarov, Ulan

2017-08-01

Process of eye tomogram obtaining by means of optical coherent tomography is studied. Stages of idiopathic macula holes formation in the process of eye grounds diagnostics are considered. Main stages of retina pathology progression are determined: Fuzzy logic units for obtaining reliable conclusions regarding the result of diagnosis are developed. By the results of theoretical and practical research system and technique of retinal macular region of the eye state analysis is developed ; application of the system, based on fuzzy logic device, improves the efficiency of eye retina complex.

A new method for the preparation of a [Sn2(H2PO2)3]Br SHG-active polar crystal via surfactant-induced strategy.

PubMed

Xie, Jie-Ling; Zhou, Yu-Hua; Li, Long-Hua; Zhang, Jian-Han; Song, Jun-Ling

2017-07-25

Herein, unprecedented NLO-brominated tin hypophosphites, namely [Sn 2 (H 2 PO 2 ) 3 ]Br, were discovered via a facile surfactant-induced method, which displayed a moderate powder SHG intensity (3.0 × KDP) in type - I phase matching behavior. This complex has high chemical and thermal stability at room temperature. DFT calculations and SHG coefficient analyses revealed that the alignment of the SHG-active-units SnO 3 trigonal pyramids and Br - anions in its structure mainly contribute to the macroscopical SHG behaviors.

Design and fabrication of advanced materials from Illinois coal wastes. Quarterly report, 1 December 1994--28 February 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Malhotra, V.M.; Wright, M.A.

1995-12-31

The main goal of this project is to develop a bench-scale procedure to design and fabricate advanced brake and structural composite materials from Illinois coal combustion residues. During the first two quarters of the project, the thrust of the work directed towards characterizing the various coal combustion residues and FGD residue, i.e., scrubber sludge. Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), differential thermal analysis (DTA), and transmission-Fourier transform infrared (FTIR) were conducted on PCC fly ash (Baldwin), FBC fly ash (ADK unit l-6), FBC fly ash (S.I. coal), FBC spent bed ash (ADM, unit l-6), bottom ash, and scrubbermore » sludge (CWLP) residues to characterize their geometrical shapes, mineral phases, and thermal stability. Our spectroscopic results indicate that the scrubber sludge is mainly composed of a gypsum-like phase whose lattice structure is different from the lattice structure of conventional gypsum, and sludge does not contain hannebachite (CaSO{sub 3}.0.5H{sub 2}O) phase. Our attempts to fabricate brake frictional shoes, in the form of 1.25 inch disks, from PCC fly ash, FBC spent bed ash, scrubber sludge, coal char, iron particles, and coal tar were successful. Based on the experience gained and microscopic analyses, we have now upscaled our procedures to fabricate 2.5 inch diameter disk,- from coal combustion residues. This has been achieved. The SEM and Young`s modulus analyses of brake composites fabricated at 400 psi < Pressure < 2200 psi suggest pressure has a strong influence on the particle packing and the filling of interstices in our composites. Also, these results along with mechanical behavior of the fabricated disks lead us to believe that the combination of surface altered PCC fly ash and scrubber sludge particles, together ed ash particles are ideal for our composite materials.« less

An overview of wireless structural health monitoring for civil structures.

PubMed

Lynch, Jerome Peter

2007-02-15

Wireless monitoring has emerged in recent years as a promising technology that could greatly impact the field of structural monitoring and infrastructure asset management. This paper is a summary of research efforts that have resulted in the design of numerous wireless sensing unit prototypes explicitly intended for implementation in civil structures. Wireless sensing units integrate wireless communications and mobile computing with sensors to deliver a relatively inexpensive sensor platform. A key design feature of wireless sensing units is the collocation of computational power and sensors; the tight integration of computing with a wireless sensing unit provides sensors with the opportunity to self-interrogate measurement data. In particular, there is strong interest in using wireless sensing units to build structural health monitoring systems that interrogate structural data for signs of damage. After the hardware and the software designs of wireless sensing units are completed, the Alamosa Canyon Bridge in New Mexico is utilized to validate their accuracy and reliability. To improve the ability of low-cost wireless sensing units to detect the onset of structural damage, the wireless sensing unit paradigm is extended to include the capability to command actuators and active sensors.

High performance photovoltaic applications using solution-processed small molecules.

PubMed

Chen, Yongsheng; Wan, Xiangjian; Long, Guankui

2013-11-19

Energy remains a critical issue for the survival and prosperity of humancivilization. Many experts believe that the eventual solution for sustainable energy is the use of direct solar energy as the main energy source. Among the options for renewable energy, photovoltaic technologies that harness solar energy offer a way to harness an unlimited resource and minimum environment impact in contrast with other alternatives such as water, nuclear, and wind energy. Currently, almost all commercial photovoltaic technologies use Si-based technology, which has a number of disadvantages including high cost, lack of flexibility, and the serious environmental impact of the Si industry. Other technologies, such as organic photovoltaic (OPV) cells, can overcome some of these issues. Today, polymer-based OPV (P-OPV) devices have achieved power conversion efficiencies (PCEs) that exceed 9%. Compared with P-OPV, small molecules based OPV (SM-OPV) offers further advantages, including a defined structure for more reproducible performance, higher mobility and open circuit voltage, and easier synthetic control that leads to more diversified structures. Therefore, while largely undeveloped, SM-OPV is an important emerging technology with performance comparable to P-OPV. In this Account, we summarize our recent results on solution-processed SM-OPV. We believe that solution processing is essential for taking full advantage of OPV technologies. Our work started with the synthesis of oligothiophene derivatives with an acceptor-donor-acceptor (A-D-A) structure. Both the backbone conjugation length and electron withdrawing terminal groups play an important role in the light absorption, energy levels and performance of the devices. Among those molecules, devices using a 7-thiophene-unit backbone and a 3-ethylrhodanine (RD) terminal unit produced a 6.1% PCE. With the optimized conjugation length and terminal unit, we borrowed from the results with P-OPV devices to optimize the backbone. Thus we selected BDT (benzo[1,2-b:4,5-b']dithiophene) and DTS (dithienosilole) to replace the central thiophene unit, leading to a PCE of 8.12%. In addition to our molecules, Bazan and co-workers have developed another excellent system using DTS as the core unit that has also achieved a PCE greater than 8%.

HESTIA Commodities Exchange Pallet and Sounding Rocket Test Stand

NASA Technical Reports Server (NTRS)

Chaparro, Javier

2013-01-01

During my Spring 2016 internship, my two major contributions were the design of the Commodities Exchange Pallet and the design of a test stand for a 100 pounds-thrust sounding rocket. The Commodities Exchange Pallet is a prototype developed for the Human Exploration Spacecraft Testbed for Integration and Advancement (HESTIA) program. Under the HESTIA initiative the Commodities Exchange Pallet was developed as a method for demonstrating multi-system integration thru the transportation of In-Situ Resource Utilization produced oxygen and water to a human habitat. Ultimately, this prototype's performance will allow for future evaluation of integration, which may lead to the development of a flight capable pallet for future deep-space exploration missions. For HESTIA, my main task was to design the Commodities Exchange Pallet system to be used for completing an integration demonstration. Under the guidance of my mentor, I designed, both, the structural frame and fluid delivery system for the commodities pallet. The fluid delivery system includes a liquid-oxygen to gaseous-oxygen system, a water delivery system, and a carbon-dioxide compressors system. The structural frame is designed to meet safety and transportation requirements, as well as the ability to interface with the ER division's Portable Utility Pallet. The commodities pallet structure also includes independent instrumentation oxygen/water panels for operation and system monitoring. My major accomplishments for the commodities exchange pallet were the completion of the fluid delivery systems and the structural frame designs. In addition, parts selection was completed in order to expedite construction of the prototype, scheduled to begin in May of 2016. Once the commodities pallet is assembled and tested it is expected to complete a fully integrated transfer demonstration with the ISRU unit and the Environmental Control and Life Support System test chamber in September of 2016. In addition to the development of the Commodities Exchange Pallet, I also assisted in preparation for testing the upper stage of a sounding rocket developed as a Center Innovation Fund project. The main objective of this project is to demonstrate the integration between a propulsion system and a solid oxide fuel cell (SOFC). The upper stage and SOFC are scheduled to complete an integrated test in August of 2016. As part of preparation for scheduled testing, I was responsible for designing the upper stage's test stand/support structure and main engine plume deflector to be used during hot-fire testing (fig. 3). The structural components of the test stand need to meet safety requirements for operation of the propulsion system, which consist of a 100 pounds-thrust main engine and two 15 pounds-thrust reaction control thrusters. My main accomplishment for this project was the completion of the design and the parts selection for construction of the structure, scheduled to begin late April of 2016.

Functional subdivisions in low-frequency primary auditory cortex (AI).

PubMed

Wallace, M N; Palmer, A R

2009-04-01

We wished to test the hypothesis that there are modules in low-frequency AI that can be identified by their responsiveness to communication calls or particular regions of space. Units were recorded in anaesthetised guinea pig AI and stimulated with conspecific vocalizations and a virtual motion stimulus (binaural beats) presented via a closed sound system. Recording tracks were mainly oriented orthogonally to the cortical surface. Some of these contained units that were all time-locked to the structure of the chutter call (14/22 tracks) and/or the purr call (12/22 tracks) and/or that had a preference for stimuli from a particular region of space (8/20 tracks with four contralateral, two ipsilateral and two midline), or where there was a strong asymmetry in the response to beats of different direction (two tracks). We conclude that about half of low-frequency AI is organized into modules that are consistent with separate "what" and "where" pathways.

Comprehensive analysis of translational osteochondral repair: Focus on the histological assessment.

PubMed

Orth, Patrick; Peifer, Carolin; Goebel, Lars; Cucchiarini, Magali; Madry, Henning

2015-10-01

Articular cartilage guarantees for an optimal functioning of diarthrodial joints by providing a gliding surface for smooth articulation, weight distribution, and shock absorbing while the subchondral bone plays a crucial role in its biomechanical and nutritive support. Both tissues together form the osteochondral unit. The structural assessment of the osteochondral unit is now considered the key standard procedure for evaluating articular cartilage repair in translational animal models. The aim of this review is to give a detailed overview of the different methods for a comprehensive evaluation of osteochondral repair. The main focus is on the histological assessment as the gold standard, together with immunohistochemistry, and polarized light microscopy. Additionally, standards of macroscopic, non-destructive imaging such as high resolution MRI and micro-CT, biochemical, and molecular biological evaluations are addressed. Potential pitfalls of analysis are outlined. A second focus is to suggest recommendations for osteochondral evaluation. Copyright © 2015 Elsevier GmbH. All rights reserved.

Swedish nurses' experiences of caring for dying people: a holistic approach.

PubMed

Iranmanesh, Sedigheh; Häggström, Terttu; Axelsson, Karin; Sävenstedt, Stefan

2009-01-01

Most people need to be cared for at the end of their lives by professionals. This study aimed to elucidate the meaning of nurses' experiences of caring for dying persons at home and in a special unit in a hospital. Four registered nurses working in private homes and 4 registered nurses working in a specific unit in a hospital setting were interviewed. The study was planned and carried out with a phenomenological hermeneutic approach. A naive reading guided a structural analysis, which resulted in 3 main themes: meeting patients and family members as unique persons, learning in a challenging environment, and gaining personal strength. The interpreted comprehensive understanding conveyed a meaning that caring for families with a member awaiting the end of life created a situation where the presence of an inevitable death demanded nurses to create close relationships with each unique person involved.

The Eocene-Miocene tectonic evolution of the Rif chain (Morocco): new data from the Jebha area

NASA Astrophysics Data System (ADS)

D'Assisi Tramparulo, Francesco; Ciarcia, Sabatino; El Ouaragli, Bilal; Vitale, Stefano; Najib Zaghloul, Mohamed

2016-04-01

Keywords: structural analysis, tectonics, shear bands, Miocene, Jebha Fault The Jebha area, located in the Central Rif, is a key sector to understand the orogenic evolution of the Rif chain. Here, the left lateral Jebha-Chrafate transfer fault, allowed, in the Miocene time, the westward migration of the internal thrust front. The structural analysis of the area revealed a complex tectonic history. The Eocene orogenic pulse produced the tectonic stacking of the Ghomaride thrust sheets. During the late Aquitanian and Langhian, under a dominant ENE-WSW shortening, imbrication of several Internal Dorsale Calcaire slices occurred. The following orogenic stage, characterized by a main SE tectonic transport, allowed the External Dorsale Calcaire to overthrust the Maghrebian Flysch Basin Units by means of a dominant thin-skinned tectonics. Synchronously with the buttressing following the collision of the allochthonous wedge against the External Rif domain, an out-of-sequence thrusting stage involved the Ghomaride and Dorsale Calcaire Units and a general back-thrusting deformed the entire tectonic pile. A renewal of the NE-SW shortening produced strike-slip faults and SW-verging folds and finally a radial extension affected the whole chain.

Study of the electronic structure and half-metallicity of CaMnO3/BaTiO3 superlattice

NASA Astrophysics Data System (ADS)

Wang, Kai; Jiang, Wei; Chen, Jun-Nan; Huang, Jian-Qi

2016-09-01

In this paper, the electronic structure, magnetic properties and half-metallicity of the CaMnO3/BaTiO3 superlattice are investigated by employing the first-principle calculation based on density functional theory within the GGA or GGA + U exchange-correlation functional. The CaMnO3/BaTiO3 superlattice is constructed by the cubic CaMnO3 and the tetragonal ferroelectric BaTiO3 growing alternately along (0 0 1) direction. The cubic CaMnO3 presents a robust half-metallicity and a metastable ferromagnetic phase. Its magnetic moment is an integral number of 3.000 μB per unit cell. However, the CaMnO3/BaTiO3 superlattice has a stable ferromagnetic phase, for which the magnetic moment is 12.000 μB per unit cell. It also retains the robust half-metallicity which mainly results from the strong hybridization between Mn and O atoms. The results show that the constructed CaMnO3/BaTiO3 superlattice exhibits superior magnetoelectric properties. It may provide a theoretical reference for the design and preparation of new multiferroic materials.

Health policies and intervention strategies: a description of current issues and approaches to care of the public health and health care system in the United Arab emirates.

PubMed

Mosaad, Aliye T; Younis, Mustafa Z

2014-01-01

The demographic factors of the United Arab Emirates (UAE) have changed drastically within one generation. This is evident in how quickly it has moved from a developing nation, where fishing was once the main source of income, to a country that is quite developed, competing on a global level. From one perspective, socio-economic progress has brought many benefits to the population. These include improved education, better access to health care, and safe drinking water. However, on the other hand, economic development has been the cause for changes in lifestyles, eating habits, and traditional societal and family structures. Over time, these changes have added up, creating an unprecedented impact on the population's health. This impact has crept up onto the society until suddenly a notable epidemic has become recognized in the country. According to the UAE Ministry of Health, 19.5 percent of the UAE population has diabetes, making it the second highest rate in the world. The structure and responsibilities of the current UAE health care systems along with other cultural factors were investigated in order to determine their impact on the growing epidemic.

Negative electrospray ionization mass spectrometry: a method for sequencing and determining linkage position in oligosaccharides from branched hemicelluloses.

PubMed

Quéméner, Bernard; Vigouroux, Jacqueline; Rathahao, Estelle; Tabet, Jean Claude; Dimitrijevic, Aleksandra; Lahaye, Marc

2015-01-01

Xyloglucans of apple, tomato, bilberry and tamarind were hydrolyzed by commercial endo β-1-4-D-endoglucanase. The xylo-gluco-oligosaccharides (XylGos) released were separated on CarboPac PA 200 column in less than 15 min, and, after purification, they were structurally characterized by negative electrospray ionization mass spectrometry using a quadrupole time-of-flight (ESI-Q-TOF), a hybrid linear ion trap (LTQ)/Orbitrap and a hybrid quadrupole Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometers. In order to corroborate the fragmentation routes observed on XylGos, some commercial galacto-manno-oligosaccharides (GalMOs) and glucurono-xylo-oligosaccharides were also studied. The fragmentation pathways of the ionized GalMos were similar to those of XylGos ones. The product ion spectra were mainly characterized by prominent double cleavage (D) ions corresponding to the entire inner side chains. The directed fragmentation from the reducing end to the other end was observed for the main glycosylated backbone but also for the side-chains, allowing their complete sequencing. Relevant cross-ring cleavage ions from (0,2)X(j)-type revealed to be diagnostic of the 1-2-linked- glycosyl units from XylGos together with the 1-2-linked glucuronic acid unit from glucuronoxylans. Resonant activation in the LTQ Orbitrap allowed not only determining the type of all linkages but also the O-acetyl group location on fucosylated side-chains. Moreover, the fragmentation of the different side chains using the MS(n) capabilities of the LTQ/Orbitrap analyzer also allowed differentiating terminal arabinosyl and xylosyl substituents inside S and U side-chains of XylGos, respectively. The CID spectra obtained were very informative for distinction of isomeric structures differing only in their substitution pattern. These features together makes the fragmentation in negative ionization mode a relevant and powerful technique useful to highlight the subtle structural changes generally observed during the development of plant organs such as during fruit ripening and for the screening of cell wall mutants with altered hemicellulose structure. Copyright © 2015 John Wiley & Sons, Ltd.

4. FLOOR PLAN AND SECTIONS, ADDITION TO POWER HOUSE. United ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. FLOOR PLAN AND SECTIONS, ADDITION TO POWER HOUSE. United Engineering Company Ltd., Alameda Shipyard. Also includes plot plan at 1 inch to 100 feet. John Hudspeth, architect, foot of Main Street, Alameda, California. Sheet 3. Plan no. 10,548. Scale 1/4 inch and h inch to the foot. April 30, 1945, last revised 6/22/45. pencil on vellum - United Engineering Company Shipyard, Boiler House, 2900 Main Street, Alameda, Alameda County, CA

Detecting Molecular Features of Spectra Mainly Associated with Structural and Non-Structural Carbohydrates in Co-Products from BioEthanol Production Using DRIFT with Uni- and Multivariate Molecular Spectral Analyses

PubMed Central

Yu, Peiqiang; Damiran, Daalkhaijav; Azarfar, Arash; Niu, Zhiyuan

2011-01-01

The objective of this study was to use DRIFT spectroscopy with uni- and multivariate molecular spectral analyses as a novel approach to detect molecular features of spectra mainly associated with carbohydrate in the co-products (wheat DDGS, corn DDGS, blend DDGS) from bioethanol processing in comparison with original feedstock (wheat (Triticum), corn (Zea mays)). The carbohydrates related molecular spectral bands included: A_Cell (structural carbohydrates, peaks area region and baseline: ca. 1485–1188 cm−1), A_1240 (structural carbohydrates, peak area centered at ca. 1240 cm−1 with region and baseline: ca. 1292–1198 cm−1), A_CHO (total carbohydrates, peaks region and baseline: ca. 1187–950 cm−1), A_928 (non-structural carbohydrates, peak area centered at ca. 928 cm−1 with region and baseline: ca. 952–910 cm−1), A_860 (non-structural carbohydrates, peak area centered at ca. 860 cm−1 with region and baseline: ca. 880–827 cm−1), H_1415 (structural carbohydrate, peak height centered at ca. 1415 cm−1 with baseline: ca. 1485–1188 cm−1), H_1370 (structural carbohydrate, peak height at ca. 1370 cm−1 with a baseline: ca. 1485–1188 cm−1). The study shows that the grains had lower spectral intensity (KM Unit) of the cellulosic compounds of A_1240 (8.5 vs. 36.6, P < 0.05), higher (P < 0.05) intensities of the non-structural carbohydrate of A_928 (17.3 vs. 2.0) and A_860 (20.7 vs. 7.6) than their co-products from bioethanol processing. There were no differences (P > 0.05) in the peak area intensities of A_Cell (structural CHO) at 1292–1198 cm−1 and A_CHO (total CHO) at 1187–950 cm−1 with average molecular infrared intensity KM unit of 226.8 and 508.1, respectively. There were no differences (P > 0.05) in the peak height intensities of H_1415 and H_1370 (structural CHOs) with average intensities 1.35 and 1.15, respectively. The multivariate molecular spectral analyses were able to discriminate and classify between the corn and corn DDGS molecular spectra, but not wheat and wheat DDGS. This study indicated that the bioethanol processing changes carbohydrate molecular structural profiles, compared with the original grains. However, the sensitivities of different types of carbohydrates and different grains (corn and wheat) to the processing differ. In general, the bioethanol processing increases the molecular spectral intensities for the structural carbohydrates and decreases the intensities for the non-structural carbohydrates. Further study is needed to quantify carbohydrate related molecular spectral features of the bioethanol co-products in relation to nutrient supply and availability of carbohydrates. PMID:21673931

KSC-07pd2026

NASA Image and Video Library

2007-07-19

KENNEDY SPACE CENTER, Fla. -- In the Orbiter Processing Facility bay 3, workers are ready to move a main bus switching unit into Discovery's payload bay. A main bus switching unit is used for power distribution, circuit protection and fault isolation on the space station's power system. The units route power to proper locations in the space station, such as from solar arrays through umbilicals into the U.S. Lab. The unit will be installed on the external stowage platform 2 attached to the Quest airlock for temporary storage. Discovery is targeted to launch mission STS-120 no earlier than Oct. 20. Photo credit: NASA/Jim Grossmann

KSC-07pd2028

NASA Image and Video Library

2007-07-19

KENNEDY SPACE CENTER, Fla. -- In the Orbiter Processing Facility bay 3, workers check the placement of a main bus switching unit in Discovery's payload bay. A main bus switching unit is used for power distribution, circuit protection and fault isolation on the space station's power system. The units route power to proper locations in the space station, such as from solar arrays through umbilicals into the U.S. Lab. The unit will be installed on the external stowage platform 2 attached to the Quest airlock for temporary storage. Discovery is targeted to launch mission STS-120 no earlier than Oct. 20. Photo credit: NASA/Jim Grossmann

KSC-07pd2024

NASA Image and Video Library

2007-07-19

KENNEDY SPACE CENTER, Fla. -- In the Orbiter Processing Facility bay 3, a crane moves the main bus switching unit that will be installed in Discovery's payload bay. The unit is part of the payload on mission STS-120. A main bus switching unit is used for power distribution, circuit protection and fault isolation on the space station's power system. The units route power to proper locations in the space station, such as from solar arrays through umbilicals into the U.S. Lab. The unit will be installed on the external stowage platform 2 attached to the Quest airlock for temporary storage. Discovery is targeted to launch mission STS-120 no earlier than Oct. 20. Photo credit: NASA/Jim Grossmann

KSC-07pd2023

NASA Image and Video Library

2007-07-19

KENNEDY SPACE CENTER, Fla. -- In the Orbiter Processing Facility bay 3, a crane lifts the main bus switching unit that will be installed in Discovery's payload bay. The unit is part of the payload on mission STS-120. A main bus switching unit is used for power distribution, circuit protection and fault isolation on the space station's power system. The units route power to proper locations in the space station, such as from solar arrays through umbilicals into the U.S. Lab. The unit will be installed on the external stowage platform 2 attached to the Quest airlock for temporary storage. Discovery is targeted to launch mission STS-120 no earlier than Oct. 20. Photo credit: NASA/Jim Grossmann

SUMMARY OF 2010 DOE EM INTERNATIONAL PROGRAM STUDIES OF WASTE GLASS STRUCTURE AND PROPERTIES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fox, K.; Choi, A.; Marra, J.

2011-02-07

Collaborative work between the Savannah River National Laboratory (SRNL) and SIA Radon in Russia was divided among three tasks for calendar year 2010. The first task focused on the study of simplified high level waste glass compositions with the objective of identifying the compositional drivers that lead to crystallization and poor chemical durability. The second task focused on detailed characterization of more complex waste glass compositions with unexpectedly poor chemical durabilities. The third task focused on determining the structure of select high level waste glasses made with varying frit compositions in order to improve models under development for predicting themore » melt rate of the Defense Waste Processing Facility (DWPF) glasses. The majority of these tasks were carried out at SIA Radon. Selection and fabrication of the glass compositions, along with chemical composition measurements and evaluations of durability were carried out at SRNL and are described in this report. SIA Radon provided three summary reports based on the outcome of the three tasks. These reports are included as appendices to this document. Briefly, the result of characterization of the Task 1 glasses may indicate that glass compositions where iron is predominantly tetrahedrally coordinated have more of a tendency to crystallize nepheline or nepheline-like phases. For the Task 2 glasses, the results suggested that the relatively low fraction of tetrahedrally coordinated boron and the relatively low concentrations of Al{sub 2}O{sub 3} available to form [BO{sub 4/2}]{sup -}Me{sup +} and [AlO{sub 4/2}]{sup -}Me{sup +} tetrahedral units are not sufficient to consume all of the alkali ions, and thus these alkali ions are easily leached from the glasses. All of the twelve Task 3 glass compositions were determined to be mainly amorphous, with some minor spinel phases. Several key structural units such as metasilicate chains and rings were identified, which confirms the current modeling approach for the silicate phase. The coordination of aluminum and iron was found to be mainly tetrahedral, with some octahedral iron ions. In all samples, trigonally-coordinated boron was determined to dominate over tetrahedrally-coordinated boron. The results further suggested that BO{sub 4} tetrahedra and BO{sub 3} triangles form complex borate units and may be present as separate constituents. However, no quantification of tetrahedral-to-trigonal boron ratio was made.« less

Resource use efficiency of closed plant production system with artificial light: Concept, estimation and application to plant factory

PubMed Central

KOZAI, Toyoki

2013-01-01

Extensive research has recently been conducted on plant factory with artificial light, which is one type of closed plant production system (CPPS) consisting of a thermally insulated and airtight structure, a multi-tier system with lighting devices, air conditioners and fans, a CO2 supply unit, a nutrient solution supply unit, and an environment control unit. One of the research outcomes is the concept of resource use efficiency (RUE) of CPPS. This paper reviews the characteristics of the CPPS compared with those of the greenhouse, mainly from the viewpoint of RUE, which is defined as the ratio of the amount of the resource fixed or held in plants to the amount of the resource supplied to the CPPS. It is shown that the use efficiencies of water, CO2 and light energy are considerably higher in the CPPS than those in the greenhouse. On the other hand, there is much more room for improving the light and electric energy use efficiencies of CPPS. Challenging issues for CPPS and RUE are also discussed. PMID:24334509

Petrography and stratigraphy of productive beds in the Morgan Formation, Church Buttes Unit No. 19, southwest Wyoming

DOE Office of Scientific and Technical Information (OSTI.GOV)

Picard, M.D.

1977-01-01

The combination stratigraphic and structural traps in the Morgan Formation of Pennsylvanian age of Church Buttes, Butcher Knife, and Bruff that produce gas and condensate are directly related to folding of the Church Buttes Arch in SW. Wyoming and NE. Utah. Present knowledge indicates that the Morgan gas and condensate originated in source beds in the lower Morgan formation west of the present Church Buttes Arch and were trapped mainly in porous barrier deposits in the Morgan. Folding of the Church Buttes Arch liberated these accumulations and they migrated updip in their present traps. This work summarizes the sedimentary petrographymore » of the productive beds in the Morgan Formation at the Church Buttes Unit No. 19 (SEC. 8, T 16 N, R 112 W), Uinta County, Wyoming. The stratigraphy is outlined for the whole region and the productive interval at Church Buttes is correlated with other rock units. Nearly all of the rocks studied are dolomite, which is difficult to interpret because of pronounced diagenesis. 33 references.« less

Characteristics of Lignin Fractions from Dilute Acid Pretreated Switchgrass and Their Effect on Cellobiohydrolase from Trichoderma longibrachiatum

DOE PAGES

Yao, Lan; Yang, Haitao; Yoo, Chang Geun; ...

2018-02-06

To investigate the interactions between acid pretreated switchgrass lignin and cellobiohydrolase (CBH), three different lignin fractions were isolated from dilute acid pretreated switchgrass by (i) ethanol extraction, followed by (ii) dioxane/H2O extraction, and (iii) cellulase treatment, respectively. Structural properties of each lignin fraction were elucidated by GPC, 13C-NMR, and 2D-HSQC NMR analyses. The adsorptions of CBH to the isolated lignin fractions were also studied by Langmuir adsorption isotherms. Ethanol-extractable lignin fraction, mainly composed of syringyl (S) and guaiacyl (G) units, had the lowest molecular weight, while dioxane/H2O-extracted lignin fraction had the lowest S/G ratio with higher content of p-coumaric acidmore » (pCA) unit. The residual lignin fraction after enzymatic treatment had the highest S/G ratio without hydroxyphenyl (H) unit. Strong associations were found between lignin properties such as lignin composition and S/G ratio and its non-productive enzyme adsorption factors including the maximum adsorption capacity and binding strength.« less

Factors associated with the process of adaptation among Pakistani adolescent females living in United States.

PubMed

Khuwaja, Salma A; Selwyn, Beatrice J; Mgbere, Osaro; Khuwaja, Alam; Kapadia, Asha; McCurdy, Sheryl; Hsu, Chiehwen E

2013-04-01

This study explored post-migration experiences of recently migrated Pakistani Muslim adolescent females residing in the United States. In-depth, semi-structured interviews were conducted with thirty Pakistani Muslim adolescent females between the ages of 15 and 18 years living with their families in Houston, Texas. Data obtained from the interviews were evaluated using discourse analysis to identify major reoccurring themes. Participants discussed factors associated with the process of adaptation to the American culture. The results revealed that the main factors associated with adaptation process included positive motivation for migration, family bonding, social support networks, inter-familial communication, aspiration of adolescents to learn other cultures, availability of English-as-second-language programs, participation in community rebuilding activities, and faith practices, English proficiency, peer pressure, and inter-generational conflicts. This study provided much needed information on factors associated with adaptation process of Pakistani Muslim adolescent females in the United States. The results have important implications for improving the adaptation process of this group and offer potential directions for intervention and counseling services.

Resource use efficiency of closed plant production system with artificial light: concept, estimation and application to plant factory.

PubMed

Kozai, Toyoki

2013-01-01

Extensive research has recently been conducted on plant factory with artificial light, which is one type of closed plant production system (CPPS) consisting of a thermally insulated and airtight structure, a multi-tier system with lighting devices, air conditioners and fans, a CO2 supply unit, a nutrient solution supply unit, and an environment control unit. One of the research outcomes is the concept of resource use efficiency (RUE) of CPPS.This paper reviews the characteristics of the CPPS compared with those of the greenhouse, mainly from the viewpoint of RUE, which is defined as the ratio of the amount of the resource fixed or held in plants to the amount of the resource supplied to the CPPS.It is shown that the use efficiencies of water, CO2 and light energy are considerably higher in the CPPS than those in the greenhouse. On the other hand, there is much more room for improving the light and electric energy use efficiencies of CPPS. Challenging issues for CPPS and RUE are also discussed.

Characteristics of Lignin Fractions from Dilute Acid Pretreated Switchgrass and Their Effect on Cellobiohydrolase from Trichoderma longibrachiatum

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yao, Lan; Yang, Haitao; Yoo, Chang Geun

To investigate the interactions between acid pretreated switchgrass lignin and cellobiohydrolase (CBH), three different lignin fractions were isolated from dilute acid pretreated switchgrass by (i) ethanol extraction, followed by (ii) dioxane/H2O extraction, and (iii) cellulase treatment, respectively. Structural properties of each lignin fraction were elucidated by GPC, 13C-NMR, and 2D-HSQC NMR analyses. The adsorptions of CBH to the isolated lignin fractions were also studied by Langmuir adsorption isotherms. Ethanol-extractable lignin fraction, mainly composed of syringyl (S) and guaiacyl (G) units, had the lowest molecular weight, while dioxane/H2O-extracted lignin fraction had the lowest S/G ratio with higher content of p-coumaric acidmore » (pCA) unit. The residual lignin fraction after enzymatic treatment had the highest S/G ratio without hydroxyphenyl (H) unit. Strong associations were found between lignin properties such as lignin composition and S/G ratio and its non-productive enzyme adsorption factors including the maximum adsorption capacity and binding strength.« less

Crystallographic analysis of ground and space thermostable T1 lipase crystal obtained via counter diffusion method approach.

PubMed

Mohamad Aris, Sayangku Nor Ariati; Thean Chor, Adam Leow; Mohamad Ali, Mohd Shukuri; Basri, Mahiran; Salleh, Abu Bakar; Raja Abd Rahman, Raja Noor Zaliha

2014-01-01

Three-dimensional structure of thermostable lipase is much sought after nowadays as it is important for industrial application mainly found in the food, detergent, and pharmaceutical sectors. Crystallization utilizing the counter diffusion method in space was performed with the aim to obtain high resolution diffracting crystals with better internal order to improve the accuracy of the structure. Thermostable T1 lipase enzyme has been crystallized in laboratory on earth and also under microgravity condition aboard Progress spacecraft to the ISS in collaboration with JAXA (Japanese Aerospace Exploration Agency). This study is conducted with the aims of improving crystal packing and structure resolution. The diffraction data set for ground grown crystal was collected to 1.3 Å resolution and belonged to monoclinic C2 space group with unit cell parameters a = 117.40 Å, b = 80.95 Å, and c = 99.81 Å, whereas the diffraction data set for space grown crystal was collected to 1.1 Å resolution and belonged to monoclinic C2 space group with unit cell parameters a = 117.31 Å, b = 80.85 Å, and c = 99.81 Å. The major difference between the two crystal growth systems is the lack of convection and sedimentation in microgravity environment resulted in the growth of much higher quality crystals of T1 lipase.

Oxygen Displacement in Cuprates under IonicLiquid Field-Effect Gating

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dubuis, Guy; Yacoby, Yizhak; Zhou, Hua

We studied structural changes in a 5 unit cell thick La 1.96Sr 0.04CuO 4 film, epitaxially grown on a LaSrAlO 4 substrate with a single unit cell buffer layer, when ultra-high electric fields were induced in the film by applying a gate voltage between the film and an ionic liquid in contact with it. Measuring the diffraction intensity along the substrate-defined Bragg rods and analyzing the results using a phase retrieval method we obtained the three-dimensional electron density in the film, buffer layer, and topmost atomic layers of the substrate under different applied gate voltages. The main structural observations were:more » (i) there were no structural changes when the voltage was negative, holes were injected into the film making it more metallic and screening the electric field; (ii) when the voltage was positive, the film was depleted of holes becoming more insulating, the electric field extended throughout the film, the partial surface monolayer became disordered, and planar oxygen atoms were displaced towards the sample surface; (iii) the changes in surface disorder and the oxygen displacements were both reversed when a negative voltage was applied; and (iv) the c-axis lattice constant of the film did not change in spite of the displacement of planar oxygen atoms.« less

Oxygen Displacement in Cuprates under IonicLiquid Field-Effect Gating

DOE PAGES

Dubuis, Guy; Yacoby, Yizhak; Zhou, Hua; ...

2016-08-15

We studied structural changes in a 5 unit cell thick La 1.96Sr 0.04CuO 4 film, epitaxially grown on a LaSrAlO 4 substrate with a single unit cell buffer layer, when ultra-high electric fields were induced in the film by applying a gate voltage between the film and an ionic liquid in contact with it. Measuring the diffraction intensity along the substrate-defined Bragg rods and analyzing the results using a phase retrieval method we obtained the three-dimensional electron density in the film, buffer layer, and topmost atomic layers of the substrate under different applied gate voltages. The main structural observations were:more » (i) there were no structural changes when the voltage was negative, holes were injected into the film making it more metallic and screening the electric field; (ii) when the voltage was positive, the film was depleted of holes becoming more insulating, the electric field extended throughout the film, the partial surface monolayer became disordered, and planar oxygen atoms were displaced towards the sample surface; (iii) the changes in surface disorder and the oxygen displacements were both reversed when a negative voltage was applied; and (iv) the c-axis lattice constant of the film did not change in spite of the displacement of planar oxygen atoms.« less

How ligands improve the hydrothermal stability and affect the adsorption in the IRMOF family.

PubMed

Bellarosa, Luca; Gutiérrez-Sevillano, Juan J; Calero, Sofía; López, Núria

2013-10-28

Metal-Organic Frameworks are considered to be the next generation of sorbents both because of their synthetic versatility and high selectivity potential. In the first generation (IRMOF), the main drawback for commercial implementation is the lack of hydrothermal stability. Even if several studies have been conducted to elucidate the reasons behind their structural weakness in humid environments, how apparently small changes in the stoichiometry of the building units affect the stability of the lattice is still poorly understood. Using density functional theory and ab initio molecular dynamics we investigated the reason behind the different behaviour of several substituted IRMOF-1 structures. We show that hydrophilic variations in the organic linkers work as new basins of attraction for the incoming water molecules, thus depleting the water content at the metal center. To confirm this, we performed Monte Carlo simulations to provide insights into the adsorption energies and check the effectiveness of the adsorption sites in the substituted structures for a variety of polar and non-polar molecules. The results show that linker modification affects molecular adsorption and can improve the overall stability of the lattice redirecting water to the new sites in the case of hydrophilic units. Three key parameters have been singled out to rationalize this behaviour, and used to predict the favoured adsorption sites in the case of gas mixtures.

Structural changes of polymer-coated microgranules and excipients on tableting investigated by microtomography using synchrotron X-ray radiation.

PubMed

Kajihara, Ryusuke; Noguchi, Shuji; Iwao, Yasunori; Suzuki, Yoshio; Terada, Yasuko; Uesugi, Kentaro; Itai, Shigeru

2015-03-15

Multiple-unit tablets consisting of polymer-coated microgranules and excipients have a number of advantageous pharmaceutical properties. Polymer-coated microgranules are known to often lose their functionality because of damage to the polymer coating caused by tableting, and the mechanism of polymer coating damage as well as the structural changes of excipients upon tableting had been investigated but without in-situ visualization and quantitative analysis. To elucidate the mechanism of coating damage, the internal structures of multiple-unit tablets were investigated by X-ray computed microtomography using synchrotron X-rays. Cross sectional images of the tablets with sub-micron spatial resolution clearly revealed that void spaces remained around the compressed excipient particles in the tablets containing an excipient composed of cellulose and lactose (Cellactose(®) 80), whereas much smaller void spaces remained in the tablets containing an excipient made of sorbitol (Parteck(®) SI 150). The relationships between the void spaces and the physical properties of the tablets such as hardness and disintegration were investigated. Damage to the polymer coating in tablets was found mainly where polymer-coated microgranules were in direct contact with each other in both types of tablets, which could be attributed to the difference in hardness of excipient particles and the core of the polymer-coated microgranules. Copyright © 2015 Elsevier B.V. All rights reserved.

Towards sustainable fishery management for skates in South America: The genetic population structure of Zearaja chilensis and Dipturus trachyderma (Chondrichthyes, Rajiformes) in the south-east Pacific Ocean.

PubMed

Vargas-Caro, Carolina; Bustamante, Carlos; Bennett, Michael B; Ovenden, Jennifer R

2017-01-01

The longnose skates (Zearaja chilensis and Dipturus trachyderma) are the main component of the elasmobranch fisheries in the south-east Pacific Ocean. Both species are considered to be a single stock by the fishery management in Chile however, little is known about the level of demographic connectivity within the fishery. In this study, we used a genetic variation (560 bp of the control region of the mitochondrial genome and ten microsatellite loci) to explore population connectivity at five locations along the Chilean coast. Analysis of Z. chilensis populations revealed significant genetic structure among off-shore locations (San Antonio, Valdivia), two locations in the Chiloé Interior Sea (Puerto Montt and Aysén) and Punta Arenas in southern Chile. For example, mtDNA haplotype diversity was similar across off-shore locations and Punta Arenas (h = 0.46-0.50), it was significantly different to those in the Chiloé Interior Sea (h = 0.08). These results raise concerns about the long-term survival of the species within the interior sea, as population resilience will rely almost exclusively on self-recruitment. In contrast, little evidence of genetic structure was found for D. trachyderma. Our results provide evidence for three management units for Z. chilensis, and we recommend that separate management arrangements are required for each of these units. However, there is no evidence to discriminate the extant population of Dipturus trachyderma as separate management units. The lack of genetic population subdivision for D. trachyderma appears to correspond with their higher dispersal ability and more offshore habitat preference.

Geologic columns for the ICDP-USGS Eyreville A and C cores, Chesapeake Bay impact structure: Postimpact sediments, 444 to 0 m depth

USGS Publications Warehouse

Edwards, L.E.; Powars, D.S.; Browning, J.V.; McLaughlin, P.P.; Miller, K.G.; ,; Kulpecz, A.A.; Elbra, T.

2009-01-01

A 443.9-m-thick, virtually undisturbed section of postimpact deposits in the Chesapeake Bay impact structure was recovered in the Eyreville A and C cores, Northampton County, Virginia, within the "moat" of the structure's central crater. Recovered sediments are mainly fine-grained marine siliciclastics, with the exception of Pleistocene sand, clay, and gravel. The lowest postimpact unit is the upper Eocene Chickahominy Formation (443.9-350.1 m). At 93.8 m, this is the maximum thickness yet recovered for deposits that represent the return to "normal marine" sedimentation. The Drummonds Corner beds (informal) and the Old Church Formation are thin Oligocene units present between 350.1 and 344.7 m. Above the Oligocene, there is a more typical Virginia coastal plain succession. The Calvert Formation (344.7-225.4 m) includes a thin lower Miocene part overlain by a much thicker middle Miocene part. From 225.4 to 206.0 m, sediments of the middle Miocene Choptank Formation, rarely reported in the Virginia coastal plain, are present. The thick upper Miocene St. Marys and Eastover Formations (206.0-57.8 m) appear to represent a more complete succession than in the type localities. Correlation with the nearby Kiptopeke core indicates that two Pliocene units are present: Yorktown (57.8-32.2 m) and Chowan River Formations (32.2-18.3 m). Sediments at the top of the section represent an upper Pleistocene channel-fill and are assigned to the Butlers Bluff and Occohannock Members of the Nassawadox Formation (18.3-0.6 m). ?? 2009 The Geological Society of America.

Towards sustainable fishery management for skates in South America: The genetic population structure of Zearaja chilensis and Dipturus trachyderma (Chondrichthyes, Rajiformes) in the south-east Pacific Ocean

PubMed Central

Bustamante, Carlos; Bennett, Michael B.; Ovenden, Jennifer R.

2017-01-01

The longnose skates (Zearaja chilensis and Dipturus trachyderma) are the main component of the elasmobranch fisheries in the south-east Pacific Ocean. Both species are considered to be a single stock by the fishery management in Chile however, little is known about the level of demographic connectivity within the fishery. In this study, we used a genetic variation (560 bp of the control region of the mitochondrial genome and ten microsatellite loci) to explore population connectivity at five locations along the Chilean coast. Analysis of Z. chilensis populations revealed significant genetic structure among off-shore locations (San Antonio, Valdivia), two locations in the Chiloé Interior Sea (Puerto Montt and Aysén) and Punta Arenas in southern Chile. For example, mtDNA haplotype diversity was similar across off-shore locations and Punta Arenas (h = 0.46–0.50), it was significantly different to those in the Chiloé Interior Sea (h = 0.08). These results raise concerns about the long-term survival of the species within the interior sea, as population resilience will rely almost exclusively on self-recruitment. In contrast, little evidence of genetic structure was found for D. trachyderma. Our results provide evidence for three management units for Z. chilensis, and we recommend that separate management arrangements are required for each of these units. However, there is no evidence to discriminate the extant population of Dipturus trachyderma as separate management units. The lack of genetic population subdivision for D. trachyderma appears to correspond with their higher dispersal ability and more offshore habitat preference. PMID:28207832

Analysis of the Geologic Structure and Compilation of the Geologic Map of the Northern Part of Planet Venus

NASA Astrophysics Data System (ADS)

Basilevsky, A. T.; Burba, G. A.; Ivanov, M. A.; Bobina, N. N.; Shashkina, V. P.; Head, J. W.

Based on an analysis of the images of the Venusian surface obtained by the side-looking radar of the Magellan orbiter, a geologic map of the northern part of Venus (the region extending to the north of the 35°N latitude) at 1 : 10 000 000 scale is compiled. The map of this vast territory, comprising one-fifth of the planet surface, was compiled using only 12 geologic units, which implies a uniform character of terrains and land- forms on the investigated territory and, therefore, the uniformity of geologic processes that occurred on this planet. These units are the products of four main groups of geologic processes that occurred on Venus during the last 0.51 Myr: (1) basaltic volcanism; (2) tectonic compression and tensile deformation; (3) impact crater- ing; and (4) wind-related mobilization, transportation, and deposition of loose fine-grained materials. Basaltic volcanism is the main process that supplies new material on the surface of Venus. Tectonic deformation struc- tures, superposed on the material of different geologic units, determined the morphology of the units and formed the surfaces of unconformity between neighboring units. Ten of 12 geologic units form an age sequence that is virtually identical over the entire mapped territory of the planet. The possible incon- sistency of this sequence caused by anomalous relations existing between smooth plains (Ps) in the southeastern part of Lakshmi Planum and wrinkle ridged plains (Pwr) in the northern part of Sedna Planitia does not destroy this sequence as a whole. The results of our mapping support the model of global stratigraphy of Venus proposed by Basilevsky and Head (19951998) and provide evidence of the quasi-synchronous character of single-type geologic units on different areas of Venus rather than of the absence of synchronism. An analysis of the distribution of impact craters on different geologic units has shown the proximity of mean absolute ages of the material of the surface of Pwr plains, of the entire studied territory, and of the entire Venusian surface. The results of our analysis suggest that, within the area under study, the intensity of the leading geologic processes at the beginning of the studied segment of the geologic history was relatively high but decreased dramatically later.

The Vertebrate Brain, Evidence of Its Modular Organization and Operating System: Insights into the Brain's Basic Units of Structure, Function, and Operation and How They Influence Neuronal Signaling and Behavior

PubMed Central

Baslow, Morris H.

2011-01-01

The human brain is a complex organ made up of neurons and several other cell types, and whose role is processing information for use in eliciting behaviors. However, the composition of its repeating cellular units for both structure and function are unresolved. Based on recent descriptions of the brain's physiological “operating system”, a function of the tri-cellular metabolism of N-acetylaspartate (NAA) and N-acetylaspartylglutamate (NAAG) for supply of energy, and on the nature of “neuronal words and languages” for intercellular communication, insights into the brain's modular structural and functional units have been gained. In this article, it is proposed that the basic structural unit in brain is defined by its physiological operating system, and that it consists of a single neuron, and one or more astrocytes, oligodendrocytes, and vascular system endothelial cells. It is also proposed that the basic functional unit in the brain is defined by how neurons communicate, and consists of two neurons and their interconnecting dendritic–synaptic–dendritic field. Since a functional unit is composed of two neurons, it requires two structural units to form a functional unit. Thus, the brain can be envisioned as being made up of the three-dimensional stacking and intertwining of myriad structural units which results not only in its gross structure, but also in producing a uniform distribution of binary functional units. Since the physiological NAA–NAAG operating system for supply of energy is repeated in every structural unit, it is positioned to control global brain function. PMID:21720525

Structure of the Anayet Permian basin (Axial Zone, Central Pyrenees)

NASA Astrophysics Data System (ADS)

Rodriguez, L.; Cuevas, J.; Tubía, J. M.

2012-04-01

The Anayet Permian basin was generated by strike-slip tectonics that opened subsident basins with pull-apart geometries in the western Spanish Axial Zone (between the Aragon and Tena valleys). A continental succession of Permian age, that represents the first post-variscan deposits in the area, fills the basin and covers discordantly Devonian to Carboniferous limestones, sandstones and slates. Permian deposits have been classically divided in four main detrital groups, with three basic volcanic episodes interbedded (Gisbert, 1984, Bixel, 1987): the Grey Unit (50-120 m, Estefanian to Kungurian) with slates, conglomerates, tobaceous slates, coal and pyroclastic deposits, the Transition Unit (50 m maximum) showing grey and red sandstones and lutites with oolitic limestones intercalated, the Lower Red Unit (250 m) composed of cross-bedded red sandstones and andesitic volcanic rocks at the top, and finally the Upper Red Unit (400 m minimum, top eroded) formed by three fining up megasequences of carbonates, red sandstones and lutites with lacustrine carbonates intercalated and alkali basalts at the top. Increasingly older rocks are found towards the western part of the basin, where its depocenter is located. South-vergent angular folds deform the Permian sedimentary succession. Fold axes are N115 °E-trending, almost horizontal and are characterized by a remarkably constant orientation. Folds exhibit a long limb dipping slightly to the north and a short vertical limb, occasionally reversed. In the Anayet basin four main folds, with a wavelength of 400 m, can be distinguished, two anticlines and two synclines, with minor folds associated. Related to the angular folds an axial plane foliation, E-trending and dipping 40 to 60° to the north, is developed in the lutites. The more competent rocks, conglomerates and breccias, only locally show a spaced fracture cleavage. No main thrusts have been detected in Permian rocks. However, minor scale decollements, usually low angle to bedding-parallel, have been identified along low-dipping limbs of the folds. They can be recognized due to the high colour contrast between the red-coloured Permian beds and the concentration of calcite veins in the decollements. The development of the structures above described has to be linked to the Alpine compressional tectonics. This interpretation is supported by the good correlation in geometry and orientation between the structures observed in the Permian basin and in southernmost areas of the South Pyrenean Zone, where the deformation is imprinted in Cretaceous to Tertiary rocks. In this regard, the southern border of the Anayet basin, at least in the western part, can be interpreted as a normal fault reactivated as a high-angle reverse fault during the positive inversion tectonics induced by the Alpine Orogeny. Bixel, F., 1987. Le volcanisme stephano-permien des Pyrenees petrographie, mineralogie, geochimie. Cuadernos de Geología Ibérica 11, 41-55. Gisbert, J., 1984. Las molasas tardihercínicas del Pirineo, in: Geología de España. Libro Jubilar de J. M. Ríos, Comba, J.A. (Ed.), IGME, Madrid, 168-186.

76 FR 75508 - United States Navy Restricted Area, SUPSHIP Bath Maine Detachment Mobile at AUSTAL, USA, Mobile...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-02

... DEPARTMENT OF DEFENSE Department of the Army, Corps of Engineers 33 CFR Part 334 United States Navy Restricted Area, SUPSHIP Bath Maine Detachment Mobile at AUSTAL, USA, Mobile, AL; Restricted Area... craft, except those vessels under the supervision or contract to local military or Naval authority...

14 CFR 29.725 - Limit drop test.

Code of Federal Regulations, 2011 CFR

2011-01-01

....), equal to the static reaction on the particular unit with the rotorcraft in the most critical attitude. A rational method may be used in computing a main gear static reaction, taking into consideration the moment arm between the main wheel reaction and the rotorcraft center of gravity. W=W N for nose gear units...

14 CFR 29.725 - Limit drop test.

Code of Federal Regulations, 2010 CFR

2010-01-01

....), equal to the static reaction on the particular unit with the rotorcraft in the most critical attitude. A rational method may be used in computing a main gear static reaction, taking into consideration the moment arm between the main wheel reaction and the rotorcraft center of gravity. W=W N for nose gear units...

Use of satellite pictures for determining major shield fractures relevant for ore prospecting, northern Finland

NASA Technical Reports Server (NTRS)

Tuominen, H. V.; Aarnisalo, J. (Principal Investigator)

1976-01-01

The author has identified the following significant results. A combined analysis of LANDSAT 1 imagery, aeromagnetic and other maps, and aerial photos has revealed a dense network of bedrock fractures in northern Finland. They form several fracturing zones, which obviously represent surficial manifestations of major fractures. The fractures follow, in general, the eight main trends of crustal shear characteristics of the Baltic Shield, but show distinct deviations from them in detail. The major fracture zones divide the bedrock into a mosaic of polygonal blocks, which in many cases coincide with the main rock units of the area and are characterized by different patterns of internal fracturing. Known mineralizations show a tendency to concentrate along the fracture zones. Optical filtering of original LANDSAT images might provide a rapid tool for the analysis of major structural trends in extensive areas such as shields or entire continents.

Body-Mind Healing Strategies in Patients with Cancer: a Qualitative Content Analysis

PubMed

Khoshnood, Zohreh; Iranmanesh, Sedigheh; Rayyani, Masoud; Dehghan, Mahlegha

2018-06-25

Background: Cancer is a major health problem around the world. The use of coping strategies among patients with cancer depends on several issues. This study was conducted to determine coping strategies used by patients with cancer in south-east Iran. Methods: This study is a conventional, qualitative content analysis with a descriptive explorative approach. Data saturation achieved after interviewing 13 participants in 15 interviews. Using an in-depth individual semi-structured approach the participants were asked to narrate their experiences of strategies that they used to cope with cancer. The following were considered: unit of analysis, meaning unit, condensation, code, sub-category, category, and main category. Results: Data analysis led to extraction of two main categories of body-mind healing strategies: being connected to the body and mindfully reconnected to the self. The first category was explained with reference to two sub-categories, being aware of intelligence and body nurturing. The second category was explained with the three sub-categories of using embodying knowledge, living for the moment, and being connected to nature. Conclusion: According to the results of this qualitative study, it is possible to form discussion groups with peers or to have self-reflective practice learning groups to reflect patients’ questions and strategies that they use for body-mind healing. Creative Commons Attribution License

Function does not follow form in gene regulatory circuits.

PubMed

Payne, Joshua L; Wagner, Andreas

2015-08-20

Gene regulatory circuits are to the cell what arithmetic logic units are to the chip: fundamental components of information processing that map an input onto an output. Gene regulatory circuits come in many different forms, distinct structural configurations that determine who regulates whom. Studies that have focused on the gene expression patterns (functions) of circuits with a given structure (form) have examined just a few structures or gene expression patterns. Here, we use a computational model to exhaustively characterize the gene expression patterns of nearly 17 million three-gene circuits in order to systematically explore the relationship between circuit form and function. Three main conclusions emerge. First, function does not follow form. A circuit of any one structure can have between twelve and nearly thirty thousand distinct gene expression patterns. Second, and conversely, form does not follow function. Most gene expression patterns can be realized by more than one circuit structure. And third, multifunctionality severely constrains circuit form. The number of circuit structures able to drive multiple gene expression patterns decreases rapidly with the number of these patterns. These results indicate that it is generally not possible to infer circuit function from circuit form, or vice versa.

Civionics specifications for fiber optic sensors for structural health monitoring

NASA Astrophysics Data System (ADS)

Rivera, Evangeline; Mufti, Aftab A.; Thomson, Douglas J.

2004-07-01

As the design and construction of civil structures continue to evolve, it is becoming imperative that these structures be monitored for their health. In order to meet this need, the discipline of Civionics has emerged. It involves the applications to civil structures and aims to assist engineers in realizing the full benefits of structural health monitoring (SHM). Therefore, the goal of the specification outlined in this work is to ensure that correct installation and operating of fiber optic sensors, such as bridges, will be discussed that motivated the writing of these specifications. The main reason for the failure of FOS based monitoring systems can be traced directly to the installation of the fiber sensor itself. Therefore, by creating a standard procedure for SHM, several ambiguities are eliminated such as fiber sensor specifications and the types of cables required. As a result, these specifications will help ensure that the sensors will survive the installation process and eventually prove their value over years of monitoring the health of the structure. The Civionics FOS specifications include the requirements for fiber sensors, specifically Bragg grating sensors, and their corresponding readout unit. It also includes specifications on the cables, conduits, junction boxes, cable termination and the environmental.

Automatic Modelling of Rubble Mound Breakwaters from LIDAR Data

NASA Astrophysics Data System (ADS)

Bueno, M.; Díaz-Vilariño, L.; González-Jorge, H.; Martínez-Sánchez, J.; Arias, P.

2015-08-01

Rubble mound breakwaters maintenance is critical to the protection of beaches and ports. LiDAR systems provide accurate point clouds from the emerged part of the structure that can be modelled to make it more useful and easy to handle. This work introduces a methodology for the automatic modelling of breakwaters with armour units of cube shape. The algorithm is divided in three main steps: normal vector computation, plane segmentation, and cube reconstruction. Plane segmentation uses the normal orientation of the points and the edge length of the cube. Cube reconstruction uses the intersection of three perpendicular planes and the edge length. Three point clouds cropped from the main point cloud of the structure are used for the tests. The number of cubes detected is around 56 % for two of the point clouds and 32 % for the third one over the total physical cubes. Accuracy assessment is done by comparison with manually drawn cubes calculating the differences between the vertexes. It ranges between 6.4 cm and 15 cm. Computing time ranges between 578.5 s and 8018.2 s. The computing time increases with the number of cubes and the requirements of collision detection.

Global diversity patterns in sandy beach macrofauna: a biogeographic analysis.

PubMed

Barboza, Francisco Rafael; Defeo, Omar

2015-09-28

Unlike the advances generated on land, the knowledge of global diversity patterns in marine ecosystems is limited to a small number of studies. For sandy beaches, which dominate the world's ocean shores, previous meta-analyses highlighted the role of beach morphodynamics in explaining species richness patterns. Oceanographic variables and historical processes have not been considered, even though they could be main predictors of community structure. Our work, based on 256 sandy beaches around the world, analysed species richness considering for the first time temperature, salinity and primary productivity. Biogeographic units (realms, provinces and ecoregions) were used to incorporate historical factors in modelling processes. Ecoregions, which implicitly include isolation and coastal complexity among other historical geographic factors, best represented trends in species richness worldwide. Temperature was a main predictor of species richness, which increased from temperate to tropical sandy beaches. Species richness increased with tide range and towards wide beaches with gentle slopes and fine grains, which is consistent with the hypothesis that habitat availability has an important role in structuring sandy beach communities. The role of temperature and habitat availability suggests that ocean warming and sea level rise could affect the distribution of obligate species living in these narrow ecosystems.

Global diversity patterns in sandy beach macrofauna: a biogeographic analysis

PubMed Central

Rafael Barboza, Francisco; Defeo, Omar

2015-01-01

Unlike the advances generated on land, the knowledge of global diversity patterns in marine ecosystems is limited to a small number of studies. For sandy beaches, which dominate the world’s ocean shores, previous meta-analyses highlighted the role of beach morphodynamics in explaining species richness patterns. Oceanographic variables and historical processes have not been considered, even though they could be main predictors of community structure. Our work, based on 256 sandy beaches around the world, analysed species richness considering for the first time temperature, salinity and primary productivity. Biogeographic units (realms, provinces and ecoregions) were used to incorporate historical factors in modelling processes. Ecoregions, which implicitly include isolation and coastal complexity among other historical geographic factors, best represented trends in species richness worldwide. Temperature was a main predictor of species richness, which increased from temperate to tropical sandy beaches. Species richness increased with tide range and towards wide beaches with gentle slopes and fine grains, which is consistent with the hypothesis that habitat availability has an important role in structuring sandy beach communities. The role of temperature and habitat availability suggests that ocean warming and sea level rise could affect the distribution of obligate species living in these narrow ecosystems. PMID:26411697

Electronic and mechanic properties of trigonal boron nitride by first-principles calculations

NASA Astrophysics Data System (ADS)

Mei, Hua Yue; Pang, Yong; Liu, Ding Yu; Cheng, Nanpu; Zheng, Shaohui; Song, Qunliang; Wang, Min

2018-07-01

A new boron nitride allotrope with 6 atoms in a unit cell termed as trigonal BN (TBN), which belongs to P3121 space group, is theoretically investigated. Electronic structures, mechanic properties, phonon spectra and other properties were calculated by using first-principles based on density functional theory (DFT). The elastic constants reveal that TBN is mechanically stable. Furthermore, phonon dispersion indicates that TBN is dynamically stable. The calculated bulk modulus and shear modulus of TBN are 323 and 342 GPa, respectively. The calculated Young's modulus are Ex = Ey = 760 GPa, Ez = 959 GPa, indicating that TBN is a super-hard and brittle material. The universal anisotropy index, which is only 0.296, shows its weak anisotropy. Band structure states clearly that TBN is an indirect semiconductor with a band gap of 3.87 eV. The valence bands are mainly composed of N 2p states, and the conduction bands are mainly contributed by B 2p states. Simulated X-ray diffraction patterns (XRD) and Raman spectra were also provided for future experimental characterizations. Due to its band gap and super-hard properties, TBN may possess potential in super-hard, optical and electronic applications.

Detrital zircon geochronology of pre- and syncollisional strata, Acadian orogen, Maine Appalachians

USGS Publications Warehouse

Bradley, Dwight C.; O'Sullivan, Paul B.

2017-01-01

The Central Maine Basin is the largest expanse of deep-marine, Upper Ordovician to Devonian metasedimentary rocks in the New England Appalachians, and is a key to the tectonics of the Acadian Orogeny. Detrital zircon ages are reported from two groups of strata: (1) the Quimby, Rangeley, Perry Mountain and Smalls Falls Formations, which were derived from inboard, northwesterly sources and are supposedly older; and (2) the Madrid, Carrabassett and Littleton Formations, which were derived from outboard, easterly sources and are supposedly younger. Deep-water deposition prevailed throughout, with the provenance shift inferred to mark the onset of foredeep deposition and orogeny. The detrital zircon age distribution of a composite of the inboard-derived units shows maxima at 988 and 429 Ma; a composite from the outboard-derived units shows maxima at 1324, 1141, 957, 628, and 437 Ma. The inboard-derived units have a greater proportion of zircons between 450 and 400 Ma. Three samples from the inboard-derived group have youngest age maxima that are significantly younger than the nominal depositional ages. The outboard-derived group does not share this problem. These results are consistent with the hypothesised provenance shift, but they signal potential problems with the established stratigraphy, structure, and (or) regional mapping. Shallow-marine deposits of the Silurian to Devonian Ripogenus Formation, from northwest of the Central Maine Basin, yielded detrital zircons featuring a single age maximum at 441 Ma. These zircons were likely derived from a nearby magmatic arc now concealed by younger strata. Detrital zircons from the Tarratine Formation, part of the Acadian foreland-basin succession in this strike belt, shows age maxima at 1615, 980 and 429 Ma. These results are consistent with three episodes of zircon recycling beginning with the deposition of inboard-derived strata of the Central Maine Basin, which were shed from post-Taconic highlands located to the northwest. Next, southeasterly parts of this succession were deformed in the Acadian orogeny, shedding detritus towards the northwest into what remained of the basin. Finally, by Pragian time, all strata in the Central Maine Basin had been deformed and detritus from this new source accumulated as the Tarratine Formation in a new incarnation of the foreland basin. Silurian-Devonian strata from the Central Maine Basin have similar detrital zircon age distributions to coeval rocks from the Arctic Alaska and Farewell terranes of Alaska and the Northwestern terrane of Svalbard. We suggest that these strata were derived from different segments of the 6500-km-long Appalachian-Caledonide orogen.

Integrated and holistic suitability assessment of recycling options for masonry rubble

NASA Astrophysics Data System (ADS)

Herbst, T.; Rübner, K.; Meng, B.

2012-04-01

Our industrial society depends on continuous mining and consumption of raw materials and energy. Besides, the building sector causes one of the largest material streams in Germany. On the one hand, the building sector is connected with a high need in material and energetic resources as well as financial expenditures. On the other hand, nearly 50 % of the volume of waste arises from the building industry. During the last years, the limitation of natural resources, increasing negative environmental consequences as well as rising prices and shortages of dump space have led to a change in thinking in the building and waste industry to a closed substance cycle waste management. In consideration of the production figures of the main kinds of masonry units (clay bricks, sand-lime bricks, autoclaved aerated concrete brick, concrete blocks), a not unimportant quantity of masonry rubble (including gypsum plaster boards, renders, mortars and mineral insulating materials) of more than 20 million tons per year is generated in the medium term. With regard to a sustainable closed substance cycle waste management, these rest masses have to be recycled if possible. Processed aggregates made from masonry rubble can be recycled in the production of new masonry units under certain conditions. Even carefully deconstructed masonry units can once more re-used as masonry units, particularly in the area of the preservation of monuments and historical buildings. In addition, masonry rubble in different processing qualities is applied in earth and road construction, horticulture and scenery construction as well as concrete production. The choice of the most suitable recycling option causes technical, economical and ecological questions. At present, a methodology for a comprehensive suitability assessment with a passable scope of work does not exist. Basic structured and structuring information on the recycling of masonry rubble is absent up to now. This as well as the economic and technical constraints lead to a subordinated utilization on a rather low application level (downcycling). However, masonry rubble should also be recycled on a higher level (upcycling) in the future. For this purpose, an integrated and holistic but also practically oriented methodology for the suitability assessment of different recycling applications for masonry rubble is developed for a PhD currently. The suitability assessment includes the simultaneous evaluation of technical, economical and ecological aspects. Therefore, all recycling phases (demolition, processing, re-use) and the main kinds of masonry units (sorted or mixed) with their specific properties have to be considered.

Case mix management education in a Canadian hospital.

PubMed

Moffat, M; Prociw, M

1992-01-01

The Sunnybrook Health Science Centre's matrix organization model includes a traditional departmental structure, a strategic program-based structure and a case management-based structure--the Clinical Unit structure. The Clinical Unit structure allows the centre to give responsibility for the management of case mix and volume to decentralized Clinical Unit teams, each of which manages its own budget. To train physicians and nurses in their respective roles of Medical Unit directors and Nursing Unit directors, Sunnybrook designed unique short courses on financial management and budgeting, and case-costing and case mix management. This paper discusses how these courses were organized, details their contents and explains how they fit into Sunnybrook's program of decentralized management.

8. SHEET 2, CONTROL HOUSE FOR DRY DOCK. United Engineering ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

8. SHEET 2, CONTROL HOUSE FOR DRY DOCK. United Engineering Company Ltd., Alameda Shipyard, Ship Repair Facilities, Office Building. John Hudspeth, Architect, at foot of Main Street, Alameda, Calif. Sheet no. 2 of 2 sheets, Plan no. 10,507. Various scales. January 4, 1943, last revised 1/19/43. U.S. Navy, Bureau of Yards & Docks, Contract no. bs 76. Approved for construction October 9, 1943. blueprint - United Engineering Company Shipyard, Control House for Dry Dock, 2900 Main Street, Alameda, Alameda County, CA

Detection of tectonometamorphic discontinuities within the Himalayan orogen: Structural and petrological constraints from the Rasuwa district, central Nepal Himalaya

NASA Astrophysics Data System (ADS)

Rapa, Giulia; Mosca, Pietro; Groppo, Chiara; Rolfo, Franco

2018-06-01

A detailed structural, lithological and petrological study of different transects in the Rasuwa district of central Nepal Himalaya allows the characterization of the tectonostratigraphic architecture of the area. It also facilitates constraining the P-T evolution of the different units within the Lesser (LHS) and Greater (GHS) Himalayan Sequences. Peak P-T conditions obtained for the studied metapelite samples using the pseudosection approach and the Average PT method highlight the existence of four different T/P ratio populations in different tectonometamorphic units: 80 ± 11 °C/kbar (LHS), 66 ± 7 °C/kbar (RTS), 73 ± 1 °C/kbar (Lower-GHS) and 101 ± 12 °C/kbar (Upper-GHS). Integration of structural and petrological data emphasizes the existence of three tectonometamorphic discontinuities bounding these units, characterized by top-to-the-south sense of shear: the Ramgarh Thrust, which separates the LHS (peak metamorphism at ∼600 °C, 7.5 kbar) from the overlying RTS (peak metamorphism at ∼635 °C, 10 kbar); the Main Central Thrust, which separates the RTS from the Lower-GHS (peak at 700-740 °C, 9.5-10.5 kbar with a prograde increase in both P and T in the kyanite stability field), and the Langtang Thrust, which juxtaposes the Upper-GHS (peak at 780-800 °C, 7.5-8.0 kbar with a nearly isobaric heating in the sillimanite stability field) onto the Lower-GHS. An increase in the intensity of deformation, with development of pervasive mylonitic fabrics and/or shear zones, is generally observed approaching the discontinuities from either side. Overall, data and results presented in this paper demonstrate that petrological and structural analysis combined together, are reliable methods adequate to identify tectonometamorphic discontinuities in both the LHS and GHS. Geochronological data from the literature allow the interpretation of these discontinuities as in-sequence thrusts.

Beyond the Cosmological: Numerical Scenarios underneath Ancient Annular Architectural Structures

NASA Astrophysics Data System (ADS)

Ranieri, M.

2009-08-01

``Cecì est la regle du carré et du cercle. Pour toutes choses, la circonférence (tcheou) est en usage, et les figures circulaire et carrée sont employées. L'officier dit ta-tsiang (grand charpentier, titre du Tcheou-li) prend ses mesures. Le compass et le règle sont apprêtés. Tantot on rompt le carré et on fait un cercle. Tantot on brise le cercle et on fait un carré. Au milieu d'un carré, quand on fait un cercle, on appelle cette figure cercle-carré. Au milieu d'un cercle, quand on fait un carré, on appelle cette figure carré-cercle.'' (Tcheou-Pei-Souan-King, book one, trad. E.Biot, Journal Asiatique, Juin 1841 p. 614 Circles and squares, as geometrical representations of the cosmos, are frequent in ancient cultures, mainly with the earth represented by the square and the sky by the circle. Quite many are the circular or circle-and-square architectures of the past that are to be interpreted as related to the cosmologies of the cultures to which they belong. In this paper we focus on those relevant annular geometries (CQC) where the square inscribable into the external circumference in turn perfectly circumscribes the internal one. Beyond the possible cosmological significances, a CQC geometry bears underneath a strict numerical structure that can be put in relation to the length-units used by the builders. Results are presented of CAD (Computer Aided Drawing) analyses performed on the plans of ancient structures where the CQC geometry was suspected to exist. A large repertory of such structures has been found, from Nuragic Sardinia to Mesoamerica including Minoans, Greeks, Romans and others. In many cases the found length-units coincide with known ancient units. The large variety presented at CAC 2000 cannot be shown in this paper for reasons of space and only a smaller but significant selection is presented.

Essays in environmental and energy economics

NASA Astrophysics Data System (ADS)

Hancevic, Pedro I.

Chapter 1: I measure the impact of the 1990 Clean Air Act Amendment on the productivity and output of US coal-fired power generating units. The Act led to power units adopting a number of different pollution abating behaviors, one of which was an input change to lower SO2 emitting coal. A key feature of coal generating units is each one is designed to burn a particular variety of coal, with significant deviations from the targeted coal characteristics resulting in productivity loss. The main innovation is to quantify the effect that switching to cleaner coal had on productivity, output and generation costs. With data spanning over twenty one years, I first compute the unconstrained coal type of each unit and document ensuing deviations caused by switching to cleaner coal. I then incorporate the effect of this deviation directly into a production function to explicitly quantify the resulting productivity loss. Chapter 2: Since the 1990-CAAA was implemented and a market for SO2 emission permits was established, coal-fired power generating units have had to choose among three main compliance alternatives: i) burn high-sulfur coal and buy additional permits to cover the excess emissions, ii) retrofit the boiler and convert it to low-sulfur coal, or iii) adopt a flue gas desulfurization unit (scrubber). The decision problem has dynamic implications driven by the evolution of input, output, and allowance prices and is revised whenever significant changes in the industry occur. I assume output level is randomly and exogenously assigned to each boiler and estimate a structural dynamic discrete choice model to recover the relative compliance costs. Chapter 3: We study a cycle of subsidized energy prices and estimate its welfare impact on households in the Buenos Aires Metropolitan Region. A simple framework explains its emergence in terms of the preference of a median household (voter) for receiving transfer gains followed by a future flow of transfer losses. We evaluate actual transfers and welfare effects that a departure of prices of natural gas and electricity generation from opportunity costs since 2003 had on households, and explore the impact of a way back to opportunity cost pricing.

Tectonics, Deep-Seated Structure and Recent Geodynamics of the Caucasus

NASA Astrophysics Data System (ADS)

Amanatashvili, I.; Adamia, Sh.; Lursmanashvili, N.; Sadradze, N.; Meskhia, V.; Koulakov, I.; Zabelina, I.; Jakovlev, A.

2012-04-01

The tectonics and deep-seated structure of the Caucasus are determined by its position between the still converging Eurasian and Africa-Arabian plates, within a wide zone of continental collision. The region in the Late Proterozoic - Early Cenozoic belonged to the Tethys Ocean and its Eurasian and Africa-Arabian margins. During Oligocene-Middle Miocene and Late Miocene-Quaternary time as a result of collision back-arc basins were inverted to form fold-thrust mountain belts and the Transcaucasian intermontane lowlands. The Caucasus is divided into platform and fold-thrust units, and forelands superimposed mainly on the rigid platform zones. The youngest structural units composed of Neogene-Quaternary continental volcanic formations of the Armenian and Javakheti highlands and extinct volcanoes of the Great Caucasus. As a result of detailed geophysical study of the gravity, magnetic, seismic, and thermal fields, the main features of the deep crustal structure of the Caucasus have been determined. Knowledge on the deep lithospheric structure of the Caucasus region is based on surface geology and deep and super deep drilling data combined with gravity, seismic, heat flow, and magnetic investigations. Close correlation between the geology and its deep-seated structures appears in the peculiarities of spatial distribution of gravitational, thermal and magnetic fields, particularly generally expressed in orientation of regional anomalies that is in good agreement with general tectonic structures. In this study we present two tomographic models derived for the region based on two different tomographic approaches. In the first case, we use the travel time data on regional seismicity recorded by networks located in Caucasus. The tomographic inversion is based on the LOTOS code which enables simultaneous determination of P and S velocity distributions and source locations. The obtained model covers the crustal and uppermost mantle depths. The second model, which is constructed for the upper mantle down to 700 km depth, is based on the data from the global ISC catalogue. We use travel times corresponding to rays which travel, at least partly, through the study volume. These data include rays from events in the study area recorded by worldwide stations, as well as teleseismic data recorded at regional stations. The computed seismic models reveal some deep traces of recent tectonic processes in the Caucasus: • For the 5, 15, 25 and 60-km-depth, there appears a clear coincidence between anomalous low velocities of P and S-waves with the fold-thrust mountainous belts of the Great and Lesser Caucasus, and also connection of high-velocity anomalies with the Trasncaucasian forelands. • Lowest-velocity anomalies are characteristic of the areas of Neogene-Quaternary volcanism of the Great and Lesser Caucasus. Areas with the lowest velocities of P- and S-waves coincide with the mountainous-folded belts, whereas the areas of high-velocity predominantly coincide with the platformal structures and forelands, as well as with basins of the Black and Caspian Seas. • Clear spatial correlation of the areas of lowest values of P- and S-velocities with the areas of Neogene-Quaternary volcanism occurs up to the depth of 150-200km that evidences location of magma sources within the crust - upper mantle - asthenosphere. • Tomographic data unambiguously confirm spatial unity of the main structures of the Caucasus and its basement, the location of the structures in situ in Late Cenozoic and connection of the volcanic constructions with their roots - magma chambers.

Structural Maps of the V-17 Beta Regio Quadrangle, Venus

NASA Technical Reports Server (NTRS)

Basilevsky, A. t.; Head, James W.

2008-01-01

These represent slices of the geologic map into 7 time-stratigraphic levels whose descriptions are found in [3-6]. From older to younger they are: 1) Tessera material unit (t), 2) Densely fractured plains material unit (pdf), 3) Fractured and ridged plains material unit (pfr), 4) Tessera transitional terrain structural unit (tt), 5) Fracture belts structural unit (fb), 6) Shield plains (psh) and plains with wrinkle ridges (pwr) material units combined, and 7) Lobate (pl) and smooth (ps) plains material units combined and, approximately contemporaneous with them, the structural unit of rifted terrain (rt). Each slice shows the generalized pattern of structures typical of these units. Figures 1-7 show the seven maps and Figure 8 shows the combined map illustrating what is shown in the seven maps. To visualize the Beta Regio uplift outlines, the major structure of this area, we show the +0.5 km and +2.5 km contour lines, corresponding respectively to the base and the mid-height of the uplift. It is seen in Figures 1-2 and 4 the trends of t, pdf and tt occupy relatively small areas and their structures seen in these small windows appear rather variable and with almost no orientation heritage with time. Figure 3 shows that swarms of ridge belts trend mostly NW and go through the Beta structure with no alignment with it, suggesting that this structure did not yet exist at this time. Figure 5 shows that fracture belts align along the northern base of the Beta uplift suggesting onset of the formation of this structure. Figure 6 shows that wrinkle ridges do not show alignment with the Beta uplift suggesting that this already forming structure was not high enough to exert topographic stress in its vicinity. Figure 7 shows that the Beta uplift has Devana Chasma as an axial rift zone, suggesting a genetic link between the uplift and rifting. Figure 8 shows that structural trends in this area significantly changed with time.

Two structurally similar fucosylated chondroitin sulfates from the holothurian species Stichopus chloronotus and Stichopus horrens.

PubMed

Ustyuzhanina, Nadezhda E; Bilan, Maria I; Dmitrenok, Andrey S; Shashkov, Alexander S; Nifantiev, Nikolay E; Usov, Anatolii I

2018-06-01

Two fucosylated chondroitin sulfates SC and SH were isolated from the holothurian species Stichopus chloronotus and Stichopus horrens, respectively. The molar ratio of monosaccharides and sulfate (GalNAc:GlcA:Fuc:SO 3 Na) was suggested as ∼1:1:1:4 for both polysaccharides. Really this theoretical ratio was slightly distorted by the presence of some fucan sulfate in both preparations (about 2% in SH and 10% in SC), which could not be separated probably due to coincidence with the main components in charge density and molecular weight. The 1D and 2D NMR spectroscopic methods were applied for the detailed structural characterization of SC and SH, which were found to have similar structures. The main chain of SC and SH was shown to be composed of the repeating disaccharide units →4)-β-d-GlcA-(1 → 3)-β-d-GalNAc-(1→ sulfated at O-4 or both at O-4 and O-6 of the N-acetyl-galactosaminyl residues. The ratio of mono- and disulfated GalNAc residues was determined as 1:9 for SC and SH. Only one type of branches linked to O-3 of glucuronyl residues, namely fucosyl 2,4-disulfate residues, were found in both polysaccharides. Therefore polysaccharides SC and SH are two new examples of highly regular fucosylated chondroitin sulfates. Copyright © 2018 Elsevier Ltd. All rights reserved.

Geologic map of the Sherbrooke-Lewiston area, Maine, New Hampshire, and Vermont, United States, and Quebec, Canada

USGS Publications Warehouse

Moench, R.H.; Boone, G.M.; Bothner, Wallace A.; Boudette, E.L.; Hatch, N.L.; Hussey, A. M.; Marvinney, R.G.

1995-01-01

This map is part of a folio of maps of the Lewiston 1° x 2° quadrangle, Maine, New Hampshire, and Vermont, and part of the Sherbrooke 1° x 2° quadrangle, Maine, New Hampshire, and Vermont, United States, and Quebec, Canada, prepared under the Conterminous United States Mineral Assessment Program (CUSMAP). Adjacent areas in Quebec are shown, in order to illustrate the geologic continuity between northwestern Maine and northern Vermont and New Hampshire. Other results of the project are contained in reports by Nowlan and others (1990a,b,c; stream sediment geochemistry), and Cox (1990; potential tin resources related to the White Mountain Plutonic-Volcanic Suite), Bothner and others (in press; complete Bouguer gravity and aeromagnetic maps), Moench and Boudette (in press, geologic synthesis and mineral occurrence map), and Moench (in press; metallic mineral resources).

Forward and adjoint spectral-element simulations of seismic wave propagation using hardware accelerators

NASA Astrophysics Data System (ADS)

Peter, Daniel; Videau, Brice; Pouget, Kevin; Komatitsch, Dimitri

2015-04-01

Improving the resolution of tomographic images is crucial to answer important questions on the nature of Earth's subsurface structure and internal processes. Seismic tomography is the most prominent approach where seismic signals from ground-motion records are used to infer physical properties of internal structures such as compressional- and shear-wave speeds, anisotropy and attenuation. Recent advances in regional- and global-scale seismic inversions move towards full-waveform inversions which require accurate simulations of seismic wave propagation in complex 3D media, providing access to the full 3D seismic wavefields. However, these numerical simulations are computationally very expensive and need high-performance computing (HPC) facilities for further improving the current state of knowledge. During recent years, many-core architectures such as graphics processing units (GPUs) have been added to available large HPC systems. Such GPU-accelerated computing together with advances in multi-core central processing units (CPUs) can greatly accelerate scientific applications. There are mainly two possible choices of language support for GPU cards, the CUDA programming environment and OpenCL language standard. CUDA software development targets NVIDIA graphic cards while OpenCL was adopted mainly by AMD graphic cards. In order to employ such hardware accelerators for seismic wave propagation simulations, we incorporated a code generation tool BOAST into an existing spectral-element code package SPECFEM3D_GLOBE. This allows us to use meta-programming of computational kernels and generate optimized source code for both CUDA and OpenCL languages, running simulations on either CUDA or OpenCL hardware accelerators. We show here applications of forward and adjoint seismic wave propagation on CUDA/OpenCL GPUs, validating results and comparing performances for different simulations and hardware usages.

Insights into the crustal structure and magmatic evolution of the High and Western Plateau of the Manihiki Plateau, Central Pacific

NASA Astrophysics Data System (ADS)

Hochmuth, Katharina; Gohl, Karsten; Uenzelmann-Neben, Gabriele

2014-05-01

The Manihiki Plateau is a Large Igneous Province (LIP) located in the Central Pacific. It is assumed, that the formation of the Manihiki Plateau took place during the early Cretaceous in multiple volcanic stages as part of the "Super-LIP" Ontong-Java-Nui. The plateau consists of several sub-plateaus of which the Western Plateau und High Plateau are the largest. In addressing the plateau's magmatic evolutionary history, one of the key questions is whether all sub-plateaus experienced the same magmatic history or if distinct phases of igneous or tectonic processes led to its fragmentation. During the RV Sonne cruise SO-224 in 2012; we collected two deep crustal seismic refraction/wide-angle reflection lines, crossing the two main sub-plateaus. Modeling of P- and S-wave phases reveals the different crustal nature of both sub-plateaus. On the High Plateau, the 20 km thick crust is divided into four seismic units, interpreted to range from basaltic composition in the uppermost crust to peridotitic composition in the middle and lower crust. The Western Plateau on the other hand shows multiple rift structures and no indications of basalt flows. With a maximum of 17 km crustal thickness, the Western Plateau is also thinner than the High Plateau. The upper basement layers show relatively low P-wave velocities (3.0 - 5.0 km/s), which infers that on the Western Plateau these layers consist of volcanoclastic and carbonatic rocks rather than basaltic flow units. Later volcanic stages may be restricted to the High Plateau with a possible eastward trend in the center of volcanic activity. Extensive secondary volcanism does not seem to have occurred on the Western Plateau, and its later deformation is mainly caused by tectonic extension and rifting.

Sulfated Polysaccharides in the Freshwater Green Macroalga Cladophora surera Not Linked to Salinity Adaptation

PubMed Central

Arata, Paula X.; Alberghina, Josefina; Confalonieri, Viviana; Errea, María I.; Estevez, José M.; Ciancia, Marina

2017-01-01

The presence of sulfated polysaccharides in cell walls of seaweeds is considered to be a consequence of the physiological adaptation to the high salinity of the marine environment. Recently, it was found that sulfated polysaccharides were present in certain freshwater Cladophora species and some vascular plants. Cladophora (Ulvophyceae, Chlorophyta) is one of the largest genera of green algae that are able to grow in both, seas and freshwater courses. Previous studies carried out on the water-soluble polysaccharides of the marine species C. falklandica established the presence of sulfated xylogalactoarabinans constituted by a backbone of 4-linked β-L-arabinopyranose units partially sulfated mainly on C3 and also on C2 with partial glycosylation, mostly on C2, with terminal β-D-xylopyranose or β-D-galactofuranose units. Besides, minor amounts of 3-, 6- and/or 3,6-linked β-D-galactan structures, with galactose in the pyranosic form were detected. In this work, the main water soluble cell wall polysaccharides from the freshwater alga Cladophora surera were characterized. It was found that this green alga biosynthesizes sulfated polysaccharides, with a structure similar to those found in marine species of this genus. Calibration of molecular clock with fossil data suggests that colonization of freshwater environments occurred during the Miocene by its ancestor. Therefore, the presence of sulfated polysaccharides in the freshwater green macroalga C. surera could be, in this case, an adaptation to transient desiccation and changes in ionic strength. Retention of sulfated polysaccharides at the cell walls may represent a snapshot of an evolutionary event, and, thus constitutes an excellent model for further studies on the mechanisms of sulfation on cell wall polysaccharides and environmental stress co-evolution. PMID:29181012

Riparian vegetation structure under desertification scenarios

NASA Astrophysics Data System (ADS)

Rosário Fernandes, M.; Segurado, Pedro; Jauch, Eduardo; Ferreira, M. Teresa

2015-04-01

Riparian areas are responsible for many ecological and ecosystems services, including the filtering function, that are considered crucial to the preservation of water quality and social benefits. The main goal of this study is to quantify and understand the riparian variability under desertification scenario(s) and identify the optimal riparian indicators for water scarcity and droughts (WS&D), henceforth improving river basin management. This study was performed in the Iberian Tâmega basin, using riparian woody patches, mapped by visual interpretation on Google Earth imagery, along 130 Sampling Units of 250 m long river stretches. Eight riparian structural indicators, related with lateral dimension, weighted area and shape complexity of riparian patches were calculated using Patch Analyst extension for ArcGis 10. A set of 29 hydrological, climatic, and hydrogeomorphological variables were computed, by a water modelling system (MOHID), using monthly meteorological data between 2008 and 2014. Land-use classes were also calculated, in a 250m-buffer surrounding each sampling unit, using a classification based system on Corine Land Cover. Boosted Regression Trees identified Mean-width (MW) as the optimal riparian indicator for water scarcity and drought, followed by the Weighted Class Area (WCA) (classification accuracy =0.79 and 0.69 respectively). Average Flow and Strahler number were consistently selected, by all boosted models, as the most important explanatory variables. However, a combined effect of hidrogeomorphology and land-use can explain the high variability found in the riparian width mainly in Tâmega tributaries. Riparian patches are larger towards Tâmega river mouth although with lower shape complexity, probably related with more continuous and almost monospecific stands. Climatic, hydrological and land use scenarios, singly and combined, were used to quantify the riparian variability responding to these changes, and to assess the loss of riparian functions such as nutrient incorporation and sediment flux alterations.

Sulfated Polysaccharides in the Freshwater Green Macroalga Cladophora surera Not Linked to Salinity Adaptation.

PubMed

Arata, Paula X; Alberghina, Josefina; Confalonieri, Viviana; Errea, María I; Estevez, José M; Ciancia, Marina

2017-01-01

The presence of sulfated polysaccharides in cell walls of seaweeds is considered to be a consequence of the physiological adaptation to the high salinity of the marine environment. Recently, it was found that sulfated polysaccharides were present in certain freshwater Cladophora species and some vascular plants. Cladophora (Ulvophyceae, Chlorophyta) is one of the largest genera of green algae that are able to grow in both, seas and freshwater courses. Previous studies carried out on the water-soluble polysaccharides of the marine species C. falklandica established the presence of sulfated xylogalactoarabinans constituted by a backbone of 4-linked β-L-arabinopyranose units partially sulfated mainly on C3 and also on C2 with partial glycosylation, mostly on C2, with terminal β-D-xylopyranose or β-D-galactofuranose units. Besides, minor amounts of 3-, 6- and/or 3,6-linked β-D-galactan structures, with galactose in the pyranosic form were detected. In this work, the main water soluble cell wall polysaccharides from the freshwater alga Cladophora surera were characterized. It was found that this green alga biosynthesizes sulfated polysaccharides, with a structure similar to those found in marine species of this genus. Calibration of molecular clock with fossil data suggests that colonization of freshwater environments occurred during the Miocene by its ancestor. Therefore, the presence of sulfated polysaccharides in the freshwater green macroalga C. surera could be, in this case, an adaptation to transient desiccation and changes in ionic strength. Retention of sulfated polysaccharides at the cell walls may represent a snapshot of an evolutionary event, and, thus constitutes an excellent model for further studies on the mechanisms of sulfation on cell wall polysaccharides and environmental stress co-evolution.

[Selection criteria of mobile lifters in the hospital setting].

PubMed

Ferriero, G; Ottonello, M; Franchignoni, F

2002-01-01

The manual handling of patients with limited mobility represents the major cause of musculoskeletal injury to the spine in paramedical health care workers. Within the hospital, the more complex procedures of patient transfer often require the use of mobile hoists. The aim of this paper is to describe the basic criteria for the selection of such hoists. The main characteristics of a hoist are its stability, the sling attachment, the speed of operation, range of movement of the spreader bar, safety of the operation being performed, patient comfort, the physical effort required on the part of the health care worker, manoeuvrability and simplicity of use. Important organizational-structural features to evaluate include: the type of patient normally present in the unit concerned, the specific movement to be performed, the structural characteristics of the environment, and the work organization of the personnel.

A New Model for the Organizational Structure of Medical Record Departments in Hospitals in Iran

PubMed Central

Moghaddasi, Hamid; Hosseini, Azamossadat; Sheikhtaheri, Abbas

2006-01-01

The organizational structure of medical record departments in Iran is not appropriate for the efficient management of healthcare information. In addition, there is no strong information management division to provide comprehensive information management services in hospitals in Iran. Therefore, a suggested model was designed based on four main axes: 1) specifications of a Health Information Management Division, 2) specifications of a Healthcare Information Management Department, 3) the functions of the Healthcare Information Management Department, and 4) the units of the Healthcare Information Management Department. The validity of the model was determined through use of the Delphi technique. The results of the validation process show that the majority of experts agree with the model and consider it to be appropriate and applicable for hospitals in Iran. The model is therefore recommended for hospitals in Iran. PMID:18066362

Craterlike structures on the laser cut surface

NASA Astrophysics Data System (ADS)

Shulyatyev, V. B.; Orishich, A. M.

2017-10-01

Analysis of the laser cut surface morphology remain topical. It is related with the fact that the surface roughness is the main index of the cut quality. The present paper deals with the experimental study of the relatively unstudied type of defects on the laser cut surface, dimples, or craters. According to the measurement results, amount of craters per unit of the laser cut surface area rises as the sheet thickness rises. The crater diameter rises together with the sheet thickness and distance from the upper sheet edge. The obtained data permit concluding that the defects like craters are observed predominantly in the case of thick sheets. The results agree with the hypothesis of crater formation as impact structures resulting from the melt drops getting on the cut channel walls upon separation from the cut front by the gas flow.

Redetermination of AgPO(3).

PubMed

Terebilenko, Katherina V; Zatovsky, Igor V; Ogorodnyk, Ivan V; Baumer, Vyacheslav N; Slobodyanik, Nikolay S

2011-02-09

Single crystals of silver(I) polyphosphate(V), AgPO(3), were prepared via a phospho-ric acid melt method using a solution of Ag(3)PO(4) in H(3)PO(4). In comparison with the previous study based on single-crystal Weissenberg photographs [Jost (1961 ▶). Acta Cryst. 14, 779-784], the results were mainly confirmed, but with much higher precision and with all displacement parameters refined anisotropically. The structure is built up from two types of distorted edge- and corner-sharing [AgO(5)] polyhedra, giving rise to multidirectional ribbons, and from two types of PO(4) tetra-hedra linked into meandering chains (PO(3))(n) spreading parallel to the b axis with a repeat unit of four tetra-hedra. The calculated bond-valence sum value of one of the two Ag(I) ions indicates a significant strain of the structure.

Imaging the Variscan suture at the KTB deep drilling site, Germany

NASA Astrophysics Data System (ADS)

Bianchi, Irene; Bokelmann, Götz

2018-03-01

The upper crust of the KTB (Kontinentales Tiefbohrprogramm) area in Southeastern Germany is a focal point for the Earth Science community due to the huge amount of information collected throughout the last thirty years. In this study we explore the crustal structure of the KTB area through the application of the receiver function (RF) technique to a new data set recorded by 9 temporary seismic stations and 1 permanent station. We aim to unravel the isotropic structure and compare our results with previous information from the reflection profiles collected during the initial site investigations. Due to the large amount of information collected by previous studies, in terms of P-wave velocity, depth and location of major reflectors, depth reconstruction of major faults zones, this area represents a unique occasion to test the resolution capability of a passive seismological study performed by the application of the RF. We aim to verify which contribution could be given by the application of the receiver functions technique, for future studies, in order to get clear images of the deep structure, and up to which resolution. The RF technique has apparently not been applied in the area before, yet it may give useful additional insight in subsurface structure, particularly at depths larger than the maximum depth reached by drilling, but also on structures in the upper crust, around the area that has been studied in detail previously. In our results vS-depth profiles for stations located on the same geological units display common features and show shallow S-wave velocities typical of the outcropping geological units (i.e. sedimentary basin, granites, metamorphic rocks). At around 10 km depth we observe a strong velocity increase beneath all stations. For the stations located in the center of the area, this variation is weaker, which we assume to be the signature of the main tectonic suture in the area (i.e. the Saxothuringian-Moldanubian suture), along an West-to-East extended region, may be due to the presence of the allochthonous klippe trapped between the main crustal terrains that came in touch during the Variscan orogeny. In the lower crust we see only small variations throughout the area, at the resolution that is possible with a small temporary experiment with just 10 stations.

Imaging the Variscan suture at the KTB deep drilling site, Germany

NASA Astrophysics Data System (ADS)

Bianchi, Irene; Bokelmann, Götz

2018-06-01

The upper crust of the KTB (Kontinentales Tiefbohrprogramm) area in the Southeastern Germany is a focal point for the Earth Science community due to the huge amount of information collected throughout the last 30 yr. In this study, we explore the crustal structure of the KTB area through the application of the Receiver Function (RF) technique to a new data set recorded by nine temporary seismic stations and one permanent station. We aim to unravel the isotropic structure and compare our results with previous information from the reflection profiles collected during the initial site investigations. Due to the large amount of information collected by previous studies, in terms of P-wave velocity, depth and location of major reflectors, depth reconstruction of major faults zones, this area represents a unique occasion to test the resolution capability of a passive seismological study performed by the application of the RF. We aim to verify which contribution could be given by the application of the RF technique, for future studies, in order to get clear images of the deep structure and up to which resolution. The RF technique has apparently not been applied in the area before, yet it may give useful additional insight in subsurface structure, particularly at depths larger than the maximum depth reached by drilling, but also on structures in the upper crust, around the area that has been studied in detail previously. In our results vS-depth profiles for stations located on the same geological units display common features and show shallow S-wave velocities typical of the outcropping geological units (i.e. sedimentary basin, granites and metamorphic rocks). At around 10 km depth, we observe a strong velocity increase beneath all stations. For the stations located in the centre of the area, this variation is weaker, which we assume to be the signature of the main tectonic suture in the area (i.e. the Saxothuringian-Moldanubian suture), along a west-to-east extended region, may be due to the presence of the allochthonous klippe trapped between the main crustal terrains that came in touch during the Variscan orogeny. In the lower crust we see only small variations throughout the area, at the resolution that is possible with a small temporary experiment with just 10 stations.

14 CFR 27.547 - Main rotor structure.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Main rotor structure. 27.547 Section 27.547... structure. (a) Each main rotor assembly (including rotor hubs and blades) must be designed as prescribed in this section. (b) [Reserved] (c) The main rotor structure must be designed to withstand the following...

Lower Miocene stratigraphy of the Gebel Shabrawet area, north Eastern desert Egypt

NASA Astrophysics Data System (ADS)

Abdelghany, Osman

2002-05-01

The Lower Miocene carbonate/siliciclastic sequence of the Shabrawet area, comprises a complex alternation of autochthonous and allogenic sediments. The sequence can be subdivided into two lithostratigraphic units. The lower unit (unit I) is equivalent to the Gharra Formation. It is mainly clastic and composed of sandstones, siltstones and shales with minor limestone intercalations. These sediments are rich in Clypeaster spp., Scutella spp., Miogypsina intermedia, Operculina complanata, and smaller foraminifera. The upper unit (unit II) was considered by previous workers as being equivalent to the Marmarica Formation. It consists mainly of non-clastic rocks, dominated by sandy and chalky limestones rich in larger foraminifera (miogypsinids and nummulitids). This unit is topped by a highly fossiliferous ( Heterostegina, Operculina and Planostegina) sandy limestone. The present study places both units in the Gharra Formation and reports for the first time M. intermedia from the Miocene sequence of the Shabrawet area.

Structural violence and marginalisation. The sexual and reproductive health experiences of separated young people on the move. A rapid review with relevance to the European humanitarian crisis.

PubMed

Mason-Jones, A J; Nicholson, P

2018-05-01

To explore the main sexual and reproductive health (SRH) issues for separated young migrants. We conducted a rapid review. The search for articles published between 2000 and June 2017 including peer-reviewed and 'grey' published literature from a range of databases including MEDLINE, AMED, Embase, ASSIA, Scopus, Web of Science and websites of international organisations (Missing Children Alliance, United Nations Population Fund (UNFPA), World Health Organization (WHO), United Nations Human Rights Council (UNHRC), Human Rights Watch, United Nations Children's Fund (UNICEF) and FBX Centre for Health and Human Rights) took place over 4 months. Themes emerging from the included studies and articles were synthesised. We found 44 articles from a range of countries of which 64% were peer-reviewed and 36% were from 'grey' literature. Structural violence and marginalisation were the key analytical themes that emerged and included young people's vulnerability to violence, unmet knowledge and service needs, barriers and stigma and poor SRH outcomes. This is the first known review to summarise the key SRH issues for separated young migrants. As Europe hosts the greatest number of separated young people in recent history, their unique SRH concerns risk being overlooked. Public health practitioners and policy makers are encouraged to challenge the gaps that exist in their services. Copyright © 2018 The Royal Society for Public Health. Published by Elsevier Ltd. All rights reserved.

Oligothiophene-Indandione-Linked Narrow-Band Gap Molecules: Impact of π-Conjugated Chain Length on Photovoltaic Performance.

PubMed

Komiyama, Hideaki; To, Takahiro; Furukawa, Seiichi; Hidaka, Yu; Shin, Woong; Ichikawa, Takahiro; Arai, Ryota; Yasuda, Takuma

2018-04-04

Solution-processed organic solar cells (OSCs) based on narrow-band gap small molecules hold great promise as next-generation energy-converting devices. In this paper, we focus on a family of A-π-D-π-A-type small molecules, namely, BDT- nT-ID ( n = 1-4) oligomers, consisting of benzo[1,2- b:4,5- b']dithiophene (BDT) as the central electron-donating (D) core, 1,3-indandione (ID) as the terminal electron-accepting (A) units, and two regioregular oligo(3-hexylthiophene)s ( nT) with different numbers of thiophene rings as the π-bridging units, and elucidate their structure-property-function relationships. The effects of the length of the π-bridging nT units on the optical absorption, thermal behavior, morphology, hole mobility, and OSC performance were systematically investigated. All oligomers exhibited broad and intense visible photoabsorption in the 400-700 nm range. The photovoltaic performances of bulk heterojunction OSCs based on BDT- nT-IDs as donors and a fullerene derivative as an acceptor were studied. Among these oligomers, BDT-2T-ID, incorporating bithiophene as the π-bridging units, showed better photovoltaic performance with a maximum power conversion efficiency as high as 6.9% under AM 1.5G illumination without using solvent additives or postdeposition treatments. These favorable properties originated from the well-developed interpenetrating network morphology of BDT-2T-ID, with larger domain sizes in the photoactive layer. Even though all oligomers have the same A-D-A main backbone, structural modulation of the π-bridging nT length was found to impact their self-organization and nanostructure formation in the solid state, as well as the corresponding OSC device performance.

Fore arc tectonothermal evolution of the El Oro metamorphic province (Ecuador) during the Mesozoic

NASA Astrophysics Data System (ADS)

Riel, Nicolas; Martelat, Jean-Emmanuel; Guillot, Stéphane; Jaillard, Etienne; Monié, Patrick; Yuquilema, Jonatan; Duclaux, Guillaume; Mercier, Jonathan

2014-10-01

The El Oro metamorphic province of SW Ecuador is a composite massif made of juxtaposed terranes of both continental and oceanic affinity that has been located in a fore-arc position since Late Paleozoic times. Various geochemical, geochronological, and metamorphic studies have been undertaken on the El Oro metamorphic province, providing an understanding of the origin and age of the distinct units. However, the internal structures and geodynamic evolution of this area remain poorly understood. Our structural analysis and thermal modeling in the El Oro metamorphic province show that this fore-arc zone underwent four main geological events. (1) During Triassic times (230-225 Ma), the emplacement of the Piedras gabbroic unit at crustal-root level ( 9 kbar) triggered partial melting of the metasedimentary sequence under an E-W extensional regime at pressure-temperature conditions ranging from 4.5 to 8.5 kbar and from 650 to 900°C for the migmatitic unit. (2) At 226 Ma, the tectonic underplating of the Arenillas-Panupalí oceanic unit (9 kbar and 300°C) thermally sealed the fore-arc region. (3) Around the Jurassic-Cretaceous boundary, the shift from trench-normal to trench-parallel subduction triggered the exhumation and underplating of the high-pressure, oceanic Raspas Ophiolitic Complex (18 kbar and 600°C) beneath the El Oro Group (130-120 Ma). This was followed by the opening of a NE-SW pull-apart basin, which tilted the massif along an E-W subhorizontal axis (110 Ma). (4) In Late Cretaceous times, an N-S compressional event generated heterogeneous deformation due to the presence of the Cretaceous Celica volcanic arc, which acted as a buttress and predominantly affected the central and eastern part of the massif.

Dual Coding of Frequency Modulation in the Ventral Cochlear Nucleus.

PubMed

Paraouty, Nihaad; Stasiak, Arkadiusz; Lorenzi, Christian; Varnet, Léo; Winter, Ian M

2018-04-25

Frequency modulation (FM) is a common acoustic feature of natural sounds and is known to play a role in robust sound source recognition. Auditory neurons show precise stimulus-synchronized discharge patterns that may be used for the representation of low-rate FM. However, it remains unclear whether this representation is based on synchronization to slow temporal envelope (ENV) cues resulting from cochlear filtering or phase locking to faster temporal fine structure (TFS) cues. To investigate the plausibility of those encoding schemes, single units of the ventral cochlear nucleus of guinea pigs of either sex were recorded in response to sine FM tones centered at the unit's best frequency (BF). The results show that, in contrast to high-BF units, for modulation depths within the receptive field, low-BF units (<4 kHz) demonstrate good phase locking to TFS. For modulation depths extending beyond the receptive field, the discharge patterns follow the ENV and fluctuate at the modulation rate. The receptive field proved to be a good predictor of the ENV responses for most primary-like and chopper units. The current in vivo data also reveal a high level of diversity in responses across unit types. TFS cues are mainly conveyed by low-frequency and primary-like units and ENV cues by chopper and onset units. The diversity of responses exhibited by cochlear nucleus neurons provides a neural basis for a dual-coding scheme of FM in the brainstem based on both ENV and TFS cues. SIGNIFICANCE STATEMENT Natural sounds, including speech, convey informative temporal modulations in frequency. Understanding how the auditory system represents those frequency modulations (FM) has important implications as robust sound source recognition depends crucially on the reception of low-rate FM cues. Here, we recorded 115 single-unit responses from the ventral cochlear nucleus in response to FM and provide the first physiological evidence of a dual-coding mechanism of FM via synchronization to temporal envelope cues and phase locking to temporal fine structure cues. We also demonstrate a diversity of neural responses with different coding specializations. These results support the dual-coding scheme proposed by psychophysicists to account for FM sensitivity in humans and provide new insights on how this might be implemented in the early stages of the auditory pathway. Copyright © 2018 the authors 0270-6474/18/384123-15$15.00/0.

Phylogeography and historical demography of the Pacific Sierra mackerel (Scomberomorus sierra) in the Eastern Pacific

PubMed Central

2010-01-01

Background Testing connectivity among populations of exploited marine fish is a main concern for the development of conservation strategies. Even though marine species are often considered to display low levels of population structure, barriers to dispersal found in the marine realm may restrict gene flow and cause genetic divergence of populations. The Pacific Sierra mackerel (Scomberomorus sierra) is a pelagic fish species distributed throughout the tropical and subtropical waters of the eastern Pacific. Seasonal spawning in different areas across the species range, as well as a limited dispersal, may result in a population genetic structure. Identification of genetically discrete units is important in the proper conservation of the fishery. Results Samples collected from the Eastern Pacific, including the areas of main abundance of the species, presented high levels of mtDNA genetic diversity and a highly significant divergence. At least two genetically discrete groups were detected in the northern (Sinaloa) and central areas (Oaxaca and Chiapas) of the species range, exhibiting slight genetic differences with respect to the samples collected in the southern region (Peru), together with a "chaotic genetic patchiness" pattern of differentiation and no evidence of isolation by distance. Historical demographic parameters supported the occurrence of past population expansions, whereas the divergence times between populations coincided with the occurrence of glacial maxima some 220 000 years ago. Conclusions The population genetic structure detected for the Pacific Sierra mackerel is associated with a limited dispersal between the main abundance areas that are usually linked to the spawning sites of the species. Population expansions have coincided with glacial-interglacial episodes in the Pleistocene, but they may also be related to the increase in the SST and with upwelling areas in the EEP since the early Pleistocene. PMID:20438637

An Algebraic Approach to Unital Quantities and their Measurement

NASA Astrophysics Data System (ADS)

Domotor, Zoltan; Batitsky, Vadim

2016-06-01

The goals of this paper fall into two closely related areas. First, we develop a formal framework for deterministic unital quantities in which measurement unitization is understood to be a built-in feature of quantities rather than a mere annotation of their numerical values with convenient units. We introduce this idea within the setting of certain ordered semigroups of physical-geometric states of classical physical systems. States are assumed to serve as truth makers of metrological statements about quantity values. A unital quantity is presented as an isomorphism from the target system's ordered semigroup of states to that of positive reals. This framework allows us to include various derived and variable quantities, encountered in engineering and the natural sciences. For illustration and ease of presentation, we use the classical notions of length, time, electric current and mean velocity as primordial examples. The most important application of the resulting unital quantity calculus is in dimensional analysis. Second, in evaluating measurement uncertainty due to the analog-to-digital conversion of the measured quantity's value into its measuring instrument's pointer quantity value, we employ an ordered semigroup framework of pointer states. Pointer states encode the measuring instrument's indiscernibility relation, manifested by not being able to distinguish the measured system's topologically proximal states. Once again, we focus mainly on the measurement of length and electric current quantities as our motivating examples. Our approach to quantities and their measurement is strictly state-based and algebraic in flavor, rather than that of a representationalist-style structure-preserving numerical assignment.

KSC-07pd2019

NASA Image and Video Library

2007-07-19

KENNEDY SPACE CENTER, Fla. -- In the Orbiter Processing Facility bay 3, the main bus switching unit that is part of the payload on mission STS-120 is being prepared for inspection. A main bus switching unit is used for power distribution, circuit protection and fault isolation on the space station's power system. The units route power to proper locations in the space station, such as from solar arrays through umbilicals into the U.S. Lab. The unit will be installed on the external stowage platform 2 attached to the Quest airlock for temporary storage. Discovery is targeted to launch mission STS-120 no earlier than Oct. 20. Photo credit: NASA/Jim Grossmann

KSC-07pd2016

NASA Image and Video Library

2007-07-19

KENNEDY SPACE CENTER, Fla. -- In the Orbiter Processing Facility bay 3, a worker checks the cover on a main bus switching unit, part of the payload on mission STS-120. A main bus switching unit is used for power distribution, circuit protection and fault isolation on the space station's power system. The units route power to proper locations in the space station, such as from solar arrays through umbilicals into the U.S. Lab. The unit will be installed on the external stowage platform 2 attached to the Quest airlock for temporary storage. Discovery is targeted to launch mission STS-120 no earlier than Oct. 20. Photo credit: NASA/Jim Grossmann

KSC-07pd2027

NASA Image and Video Library

2007-07-19

KENNEDY SPACE CENTER, Fla. -- In the Orbiter Processing Facility bay 3, with the help of a crane, workers check the placement of a main bus switching unit in Discovery's payload bay. A main bus switching unit is used for power distribution, circuit protection and fault isolation on the space station's power system. The units route power to proper locations in the space station, such as from solar arrays through umbilicals into the U.S. Lab. The unit will be installed on the external stowage platform 2 attached to the Quest airlock for temporary storage. Discovery is targeted to launch mission STS-120 no earlier than Oct. 20. Photo credit: NASA/Jim Grossmann

[Nitrous oxide production by the German Armed Forces in the 20th century : History of medicine and pharmacy in the Armed Forces].

PubMed

Kronabel, D B J

2010-03-01

The nitrous oxide production unit of the German Armed Forces was a worldwide unique facility which was only employed in the former main medical depot at Euskirchen (nitrous oxide: medical gas which is now obsolete). The last unit was phased out in 2002 and brought to the main medical depot at Blankenburg. Unfortunately the unit is now no longer in the depot and seems to have disappeared. This article describes the nitrous oxide production process and the use of the production unit which was designed by the Socsil company of Switzerland.

Wood used in industrial markets in the United States--2000

Treesearch

Chris Gaston

2002-01-01

The main objective of this study was to gather information on the volume of wood products used by industrial manufacturers across the United States (U.S.). Specific objectives included the following: 1. To identify and categorize the main industrial manufacturing industries in the U.S. that are likely to use wood products (using the North American Industrial...

Effect of trivalent iron substitution on structure and properties of PLZT ceramics

NASA Astrophysics Data System (ADS)

Dutta, S.; Choudhary, R. N. P.

2008-02-01

Polycrystalline samples of Fe-modified PLZT (lead lanthanum zirconate titanate) are prepared by a mixed-oxide reaction technique. The formation of the compound has been confirmed by X-ray powder diffraction studies. The unit cell structure of the material has been found to be rhombohedral. Fourier-transform infrared reflection (FTIR) spectra have been recorded to correspond the structural changes associated with the phase formation. The effects of Fe concentration on the microstructure and dielectric constant of PLZT materials have been investigated. The ferroelectric phase transition of PLFZT materials is studied using dielectric measurements, which shows a shift in the transition temperature towards the higher-temperature side with increased Fe ion concentration. The piezoelectric constants of this system are investigated by the same way of changed contents of Fe ion in the main PLZT compound. The optimum values of Qm, kp, and d33 are 73, 0.32 and 406. The electrical conductivity increases with the increase in Fe ion concentration.

Super-elastic and fatigue resistant carbon material with lamellar multi-arch microstructure

NASA Astrophysics Data System (ADS)

Gao, Huai-Ling; Zhu, Yin-Bo; Mao, Li-Bo; Wang, Feng-Chao; Luo, Xi-Sheng; Liu, Yang-Yi; Lu, Yang; Pan, Zhao; Ge, Jin; Shen, Wei; Zheng, Ya-Rong; Xu, Liang; Wang, Lin-Jun; Xu, Wei-Hong; Wu, Heng-An; Yu, Shu-Hong

2016-09-01

Low-density compressible materials enable various applications but are often hindered by structure-derived fatigue failure, weak elasticity with slow recovery speed and large energy dissipation. Here we demonstrate a carbon material with microstructure-derived super-elasticity and high fatigue resistance achieved by designing a hierarchical lamellar architecture composed of thousands of microscale arches that serve as elastic units. The obtained monolithic carbon material can rebound a steel ball in spring-like fashion with fast recovery speed (~580 mm s-1), and demonstrates complete recovery and small energy dissipation (~0.2) in each compress-release cycle, even under 90% strain. Particularly, the material can maintain structural integrity after more than 106 cycles at 20% strain and 2.5 × 105 cycles at 50% strain. This structural material, although constructed using an intrinsically brittle carbon constituent, is simultaneously super-elastic, highly compressible and fatigue resistant to a degree even greater than that of previously reported compressible foams mainly made from more robust constituents.

In-situ chemical analyses of trans-polyisoprene by histochemical staining and Fourier transform infrared microspectroscopy in a rubber-producing plant, Eucommia ulmoides Oliver.

PubMed

Bamba, Takeshi; Fukusaki, Ei-Ichiro; Nakazawa, Yoshihisa; Kobayashi, Akio

2002-10-01

The localization of polyisoprene in young stem tissues of Eucommia ulmoides Oliver was investigated by histochemical staining and Fourier transform infrared (FT-IR) microspectroscopy. The fibrous structures were stained with Oil Red O. FT-IR microspectroscopic analysis proved that the fibrous structures were trans-polyisoprene. Granular structures stained with the dye, and characteristic absorptions at 2,960 cm(-1) and 1,430 cm(-1) in FT-IR suggested that trans-polyisoprene accumulated in the vicinity of the cambium layer. We have thus successfully shown for the first time the localization of trans-polyisoprene in plant tissues, and our histological investigation allowed us to presume the main sites of biosynthesis and accumulation of trans-rubber. Furthermore, a new technical approach, the preparation of sections using an electronic freezing unit and the in situ analysis of polyisoprene using FT-IR microspectroscopy, is demonstrated to be a promising method for determining the accumulation of polyisoprene as well as other metabolites.

L'aquifère du bassin de la Mamora, Maroc: geometrie et ecoulements souterrainsThe aquifer of the Mamora Basin, Morocco: geometry and groundwater flow

NASA Astrophysics Data System (ADS)

Zouhri, L.

2001-05-01

The Mamora aquifer, in the northern Moroccan Meseta, constitutes the main regional water resource. Its impermeable basement is mostly composed of blue marls. The lithostratigraphy of the basin aquifer is characterised by a sequence of sandstones, sandy limestones, conglomerates and sandy clays. The structure of the basement of the Mamora aquifer, deduced from electrical resistivity measurements, allowed the hydrogeological behaviour of the reservoir, and the direction of the groundwater flow, to be established. The combination of the lithological, morphological, piezometric, geophysical and structural investigations revealed a northward thickening of the substrate with groundwater flow towards the Rharb (to the north) and towards the Atlantic Ocean (northwest). This 'multicriteria' approach enabled a structural model to be defined, which correlated well with the aquifer geometry and the groundwater flow. The variability of the hydrogeological units, and the northward thickening of the sedimentary facies, were controlled by northeast-southwest orientated faults, which affect their impermeability.

Ultra-Thin Multi-Band Polarization-Insensitive Microwave Metamaterial Absorber Based on Multiple-Order Responses Using a Single Resonator Structure

PubMed Central

Cheng, Zheng Ze; Mao, Xue Song; Gong, Rong Zhou

2017-01-01

We design an ultra-thin multi-band polarization-insensitive metamaterial absorber (MMA) using a single circular sector resonator (CSR) structure in the microwave region. Simulated results show that the proposed MMA has three distinctive absorption peaks at 3.35 GHz, 8.65 GHz, and 12.44 GHz, with absorbance of 98.8%, 99.7%, and 98.3%, respectively, which agree well with an experiment. Simulated surface current distributions of the unit-cell structure reveal that the triple-band absorption mainly originates from multiple-harmonic magnetic resonance. The proposed triple-band MMA can remain at a high absorption level for all polarization of both transverse-electric (TE) and transverse-magnetic (TM) modes under normal incidence. Moreover, by further optimizing the geometric parameters of the CSRs, four-band and five-band MMAs can also be obtained. Thus, our design will have potential application in detection, sensing, and stealth technology. PMID:29077036

Using pig manure to promote fermentation of sugarcane molasses alcohol wastewater and its effects on microbial community structure.

PubMed

Shen, Peihong; Han, Fei; Su, Shuquan; Zhang, Junya; Chen, Zhineng; Li, Junfang; Gan, Jiayi; Feng, Bin; Wu, Bo

2014-03-01

Molasses alcohol wastewater (MAW) is difficult to be bio-treated and converted into biogas. In this study, MAW mixed with pig manure (PM) in different ratios was co-digested. Biogas production, chemical oxygen demand (COD) removal and the structure of microbial communities were monitored in the process. Our results showed that under the optimal COD ratio of PM:MAW (1.0:1.5), CODremoval and biogas yield were the highest. And in fermentation tanks with different PM to MAW ratios, the structure and composition of bacterial communities varied in the early and late stage. Furthermore, the type of main bacterial operational taxonomic units (OTUs) have no differences, yet the relative abundance of OTUs varied. The current research showed that there was a good potential to the use of PM as a co-digested material to anaerobic treatment of MAW and provided references for further improving bio-treatment of MAW. Copyright © 2014 Elsevier Ltd. All rights reserved.

Influence of the Kingak Shale ultimate shelf margin on frontal structures of the Brooks Range in the National Petroleum Reserve in Alaska

USGS Publications Warehouse

Stier, Natalie E.; Connors, Christopher D.; Houseknecht, David W.

2014-01-01

The Jurassic–Lower Cretaceous Kingak Shale in the National Petroleum Reserve in Alaska (NPRA) includes several southward-offlapping depositional sequences that culminate in an ultimate shelf margin, which preserves the depositional profile in southern NPRA. The Kingak Shale thins abruptly southward across the ultimate shelf margin and grades into condensed shale, which is intercalated with underlying condensed shale and chert of the Upper Triassic Shublik Formation and overlying condensed shale of the Lower Cretaceous pebble shale unit and the gamma-ray zone (GRZ) of the Hue Shale. This composite of condensed shale forms a thin (≈300-meter) and mechanically weak section between much thicker and mechanically stronger units, including the Sadlerochit and Lisburne Groups below and the sandstone-prone foredeep wedge of the Torok Formation above. Seismic interpretation indicates that the composite condensed section acted as the major detachment during an Early Tertiary phase of deformation in the northern foothills of the Brooks Range and that thrust faults step up northward to the top of the Kingak, or to other surfaces within the Kingak or the overlying Torok. The main structural style is imbricate fault-bend folding, although fault-propagation folding is evident locally, and large-displacement thrust faults incorporate backthrusting to form structural wedges. The Kingak ultimate shelf margin served as a ramp to localize several thrust faults, and the spatial relationship between the ultimate shelf margin and thrust vergence is inferred to have controlled many structures in southern NPRA. For example, the obliqueness of the Carbon Creek anticline relative to other structures in the foothills is the result of northward-verging thrust faults impinging obliquely on the Kingak ultimate shelf margin in southwestern NPRA.

Effect of the Sm content on the structure and electrochemical properties of La 1.3 - xSm xCaMg 0.7Ni 9 ( x = 0-0.3) hydrogen storage alloys

NASA Astrophysics Data System (ADS)

Tang, Rui; Wei, Xuedong; Liu, Yongning; Zhu, Changchun; Zhu, Jiewu; Yu, Guang

La 1.3 - xSm xCaMg 0.7Ni 9 (x = 0-0.3) hydrogen storage alloys were prepared by inductive melting and the effect of the Sm content on the structure and electrochemical properties was investigated in the paper. The Sm substitution for La in La 1.3 - xSm xCaMg 0.7Ni 9 (x = 0-0.3) alloys does not change the main phase structure (the rhombohedral PuNi 3-type structure), but leads to a shrinkage of unit cell and a decrease of hydrogen storage capacity. With the increase of the Sm content in the alloys, the maximum discharge capacity of electrode decreases from 400.2 (x = 0) to 346.6 mAh g -1 (x = 0.3), but the high-rate dischargeability and cycling stability is improved. After 100 cycles, the capacity retention rate increases from 75 (x = 0) to 85% (x = 0.3).

Crystal growth, electronic structure and optical properties of Sr2Mg(BO3)2

NASA Astrophysics Data System (ADS)

Lv, Xianshun; Wei, Lei; Wang, Xuping; Xu, Jianhua; Yu, Huajian; Hu, Yanyan; Zhang, Huadi; Zhang, Cong; Wang, Jiyang; Li, Qinggang

2018-02-01

Single crystals of Sr2Mg(BO3)2 (SMBO) were grown by Kyropoulos method. X-ray powder diffraction (XRD) analysis, transmission spectrum, thermal properties, band structure, density of states and charge distribution as well as Raman spectra of SMBO were described. The as-grown SMBO crystals show wide transparency range with UV cut-off below 180 nm. A direct band gap of 4.66 eV was obtained from the calculated electronic structure results. The calculated band structure and density of states results indicated the top valence band is determined by O 2p states whereas the low conduction band mainly consists of Sr 5s states. Twelve Raman peaks were observed in the experimental spectrum, fewer than the number predicted by the site group analysis. Raman peaks of SMBO were assigned combining first-principle calculation and site group analysis results. The strongest peak at 917 cm-1 in the experimental spectrum is assigned to symmetric stretching mode A1‧(ν1) of free BO3 units. SMBO is a potential Raman crystal which can be used in deep UV laser frequency conversion.

In situ structural analysis of calcium aluminosilicate glasses under high pressure.

PubMed

Muniz, R F; de Ligny, D; Martinet, C; Sandrini, M; Medina, A N; Rohling, J H; Baesso, M L; Lima, S M; Andrade, L H C; Guyot, Y

2016-08-10

In situ micro-Raman spectroscopy was used to investigate the structural evolution of OH(-)-free calcium aluminosilicate glasses, under high pressure and at room temperature. Evaluation was made of the role of the SiO2 concentration in percalcic join systems, for Al/(Al  +  Si) in the approximate range from 0.9 to 0.2. Under high pressure, the intensity of the main band related to the bending mode of bridging oxygen ([Formula: see text][T-O-T], where T  =  Si or Al) decreased gradually, suggesting that the bonds were severely altered or even destroyed. In Si-rich glasses, compression induced a transformation of Q (n) species to Q (n-1). In the case of Al-rich glass, the Al in the smallest Q (n) units evolved from tetrahedral to higher-coordinated Al (([5])Al and ([6])Al). Permanent structural changes were observed in samples recovered from the highest pressure of around 15 GPa and, particularly for Si-rich samples, the recovered structure showed an increase of three-membered rings in the Si/Al tetrahedral network.

Low-Cost Composite Materials and Structures for Aircraft Applications

NASA Technical Reports Server (NTRS)

Deo, Ravi B.; Starnes, James H., Jr.; Holzwarth, Richard C.

2003-01-01

A survey of current applications of composite materials and structures in military, transport and General Aviation aircraft is presented to assess the maturity of composites technology, and the payoffs realized. The results of the survey show that performance requirements and the potential to reduce life cycle costs for military aircraft and direct operating costs for transport aircraft are the main reasons for the selection of composite materials for current aircraft applications. Initial acquisition costs of composite airframe components are affected by high material costs and complex certification tests which appear to discourage the widespread use of composite materials for aircraft applications. Material suppliers have performed very well to date in developing resin matrix and fiber systems for improved mechanical, durability and damage tolerance performance. The next challenge for material suppliers is to reduce material costs and to develop materials that are suitable for simplified and inexpensive manufacturing processes. The focus of airframe manufacturers should be on the development of structural designs that reduce assembly costs by the use of large-scale integration of airframe components with unitized structures and manufacturing processes that minimize excessive manual labor.

Fiber Reinforced Concrete (FRC) for High Rise Construction: Case Studies

NASA Astrophysics Data System (ADS)

Gharehbaghi, Koorosh; Chenery, Rhea

2017-12-01

Due to its material element, Fiber Reinforced Concrete (FRC) could be stronger than traditional Concrete. This is due to FRC internal material compounds and elements. Furthermore, FRC can also significantly improve flexural strength when compared to traditional Concrete. This improvement in flexural strength can be varied depending on the actual fibers used. Although not new, FRC is gradually gaining popularity in the construction industry, in particular for high rise structures. This is due to its flexural strength, especially for high seismic zones, as it will provide a better solution then reinforced Concrete. The main aim of this paper is to investigate the structural importance of FRC for the high rise construction. Although there has been numerous studies and literature in justifying the FRC for general construction; this paper will consider its use specifically for high rise construction. Moreover, this paper will closely investigate eight case studies from Australian and United States as a part of the FRC validation for high rise construction. In doing so, this paper will examine their Structural Health Monitoring (SHM) to determine their overall structural performance.

Epiplasmins and epiplasm in paramecium: the building of a submembraneous cytoskeleton.

PubMed

Aubusson-Fleury, Anne; Bricheux, Geneviève; Damaj, Raghida; Lemullois, Michel; Coffe, Gérard; Donnadieu, Florence; Koll, France; Viguès, Bernard; Bouchard, Philippe

2013-07-01

In ciliates, basal bodies and associated appendages are bound to a submembrane cytoskeleton. In Paramecium, this cytoskeleton takes the form of a thin dense layer, the epiplasm, segmented into regular territories, the units where basal bodies are inserted. Epiplasmins, the main component of the epiplasm, constitute a large family of 51 proteins distributed in 5 phylogenetic groups, each characterized by a specific molecular design. By GFP-tagging, we analyzed their differential localisation and role in epiplasm building and demonstrated that: 1) The epiplasmins display a low turnover, in agreement with the maintenance of an epiplasm layer throughout the cell cycle; 2) Regionalisation of proteins from different groups allows us to define rim, core, ring and basal body epiplasmins in the interphase cell; 3) Their dynamics allows definition of early and late epiplasmins, detected early versus late in the duplication process of the units. Epiplasmins from each group exhibit a specific combination of properties. Core and rim epiplasmins are required to build a unit; ring and basal body epiplasmins seem more dispensable, suggesting that they are not required for basal body docking. We propose a model of epiplasm unit assembly highlighting its implication in structural heredity in agreement with the evolutionary history of epiplasmins. Copyright © 2013 Elsevier GmbH. All rights reserved.

A compact, low jitter, nanosecond rise time, high voltage pulse generator with variable amplitude.

PubMed

Mao, Jiubing; Wang, Xin; Tang, Dan; Lv, Huayi; Li, Chengxin; Shao, Yanhua; Qin, Lan

2012-07-01

In this paper, a compact, low jitter, nanosecond rise time, command triggered, high peak power, gas-switch pulse generator system is developed for high energy physics experiment. The main components of the system are a high voltage capacitor, the spark gap switch and R = 50 Ω load resistance built into a structure to obtain a fast high power pulse. The pulse drive unit, comprised of a vacuum planar triode and a stack of avalanche transistors, is command triggered by a single or multiple TTL (transistor-transistor logic) level pulses generated by a trigger pulse control unit implemented using the 555 timer circuit. The control unit also accepts user input TTL trigger signal. The vacuum planar triode in the pulse driving unit that close the first stage switches is applied to drive the spark gap reducing jitter. By adjusting the charge voltage of a high voltage capacitor charging power supply, the pulse amplitude varies from 5 kV to 10 kV, with a rise time of <3 ns and the maximum peak current up to 200 A (into 50 Ω). The jitter of the pulse generator system is less than 1 ns. The maximum pulse repetition rate is set at 10 Hz that limited only by the gas-switch and available capacitor recovery time.

Ion-pair high-speed countercurrent chromatography in fractionation of a high-molecular weight variation of acyl-oligosaccharide linked betacyanins from purple bracts of Bougainvillea glabra.

PubMed

Wybraniec, Sławomir; Jerz, Gerold; Gebers, Nadine; Winterhalter, Peter

2010-02-15

The natural pigment composition of purple bracts of Bougainvillea glabra (Nyctaginaceae) consists of a highly complex mixture of betacyanins solely differing by the substitution with a variety of acyl-oligoglycoside units. This study was focused on a two-dimensional chromatography approach, a combination of preparative high-speed countercurrent chromatography (HSCCC) and analytical C18-HPLC with ESI-DAD-MS/MS detection which finally enabled a more detailed view into the pigment profile and elucidated the existence of an overwhelming amount of varying betacyanin structures occurring in Bougainvillea bracts. The detected molecular weights of the pigments reached so far unknown high values and ranged up to maximum values of 1653 and 1683 Da for the largest molecules due to oligosaccharide linkage and multiple acyl substitutions. The preparative IP-HSCCC separation yielded 15 complex fractions containing betacyanins of enhanced polarity as well as structures with highly increased lipophilicity. Betacyanin structures extended by large oligosaccharide chains with bigger number of glycoside units and also carrying a reduced number of hydroxycinnamic acid substitutions were characteristic for polar pigments occurring mainly in the early eluting CCC fractions. IP-HSCCC was proven to be extremely effective for fractionating this complex crude betalain pigment extract into more defined 'polarity-windows'. Structural analysis by analytical LC-ESI-MS/MS in the positive ionization mode detected a total sum of 146 different betacyanin pigments in the CCC fractions of reduced complexity. Copyright 2010 Elsevier B.V. All rights reserved.

Structurally integrated steel solar collector

DOEpatents

Moore, Stanley W.

1977-03-08

Herein is disclosed a flat plate solar heat collector unit. The solar collector is integrated as a structural unit so that the collector also functions as the building roof. The functions of efficient heat collection, liquid coolant flow passages, roof structural support and building insulation are combined into one unit.

Structurally integrated steel solar collector

DOEpatents

Moore, S.W.

1975-06-03

Herein is disclosed a flate plate solar heat collector unit. The solar collector is integrated as a structural unit so that the collector also functions as the building roof. The functions of efficient heat collection, liquid coolant flow passages, roof structural support, and building insulation are combined into one unit.

[Network structures in biological systems].

PubMed

Oleskin, A V

2013-01-01

Network structures (networks) that have been extensively studied in the humanities are characterized by cohesion, a lack of a central control unit, and predominantly fractal properties. They are contrasted with structures that contain a single centre (hierarchies) as well as with those whose elements predominantly compete with one another (market-type structures). As far as biological systems are concerned, their network structures can be subdivided into a number of types involving different organizational mechanisms. Network organization is characteristic of various structural levels of biological systems ranging from single cells to integrated societies. These networks can be classified into two main subgroups: (i) flat (leaderless) network structures typical of systems that are composed of uniform elements and represent modular organisms or at least possess manifest integral properties and (ii) three-dimensional, partly hierarchical structures characterized by significant individual and/or intergroup (intercaste) differences between their elements. All network structures include an element that performs structural, protective, and communication-promoting functions. By analogy to cell structures, this element is denoted as the matrix of a network structure. The matrix includes a material and an immaterial component. The material component comprises various structures that belong to the whole structure and not to any of its elements per se. The immaterial (ideal) component of the matrix includes social norms and rules regulating network elements' behavior. These behavioral rules can be described in terms of algorithms. Algorithmization enables modeling the behavior of various network structures, particularly of neuron networks and their artificial analogs.

Improved energy output levels from small-scale Microbial Fuel Cells.

PubMed

Ieropoulos, I; Greenman, J; Melhuish, C

2010-04-01

This study reports on the findings from the investigation into small-scale (6.25 mL) MFCs, connected together as a network of multiple units. The MFCs contained unmodified (no catalyst) carbon fibre electrodes and for initial and later experiments, a standard ion-exchange membrane for the proton transfer from the anode to the cathode. The anode microbial culture was of the type commonly found in domestic wastewater fed with 5 mM acetate as the carbon-energy (C/E) source. The cultures were mature and acclimatised in the MFC environment for approximately 2 months before being re-inoculated in the experimental MFC units. The cathode was of the O(2) diffusion open-to-air type, but for the purposes of the polarization experiments, the cathodic electrodes were moistened with ferricyanide. The main aim of this study was to investigate the effects of connecting multiples of MFC units together as a method of scale up by using stacks and comparison of the effects of different PEM and MFC structural materials on the performance. Impedance matching (maximum-power-transfer) was achieved through calculation of total internal impedance. Three different PEM materials were compared in otherwise identical MFCs in sets of three. For individual isolated MFCs, Hyflon E87-03 was shown to produce twice, whilst E87-10 produced approximately 1.5 times the power output of the control (standard) PEM. However, when MFCs containing the E87-03 and E87-10 membranes were connected in a stack, the system suffered from severe instability and cell reversal. To study the effects of the various polymeric MFC structural materials, four small-scale units were manufactured from three different types of RP material; acrylo-butadiene-styrene coated (ABS), ABS coated (ABS-MEK) and polycarbonate (polyC). The stack of four (4) units prototyped out of polyC produced the highest power density values in polarisation experiments (80 mW/m(2)). 2009 Elsevier B.V. All rights reserved.

Geothermal energy development in the Eastern United States. Technical assistance report no. 6, geothermal space heating and conditioning: McGuire Air Force Base, New Jersey

NASA Astrophysics Data System (ADS)

Hill, F. K.; Vonbriesen, R.

1980-12-01

The feasibility of space heating and cooling 200 multifamily on-base housing units using nonreversible heat pumps and ground water from 1000 ft. depth was studied. The 200 housing units are a part of the 1452 main base multifamily housing complex which is heated from a high temperature and pressure water line. The main system will be converted from natural gas to coal in 1984. Relative cost, amortization periods, and fossil fuel projections are compared.

EXTERIOR ELEVATIONS. United Engineering Company Ltd., Alameda Shipyard, Ship Repair ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

EXTERIOR ELEVATIONS. United Engineering Company Ltd., Alameda Shipyard, Ship Repair Facilities, Office Building. Includes lettering detail for front elevation. John Hudspeth, Architect, at foot of Main Street, Alameda, Calif. Sheet no. A3 of 8 sheets, Plan no. 10,007. Scale 1/8 inch to the foot. March 18, 1942, last revised 9/21/43. U.S. Navy, Bureau of Yards & Docks, Contract no. bs 76. Approved for construction October 9, 1943. blueprint - United Engineering Company Shipyard, Office Building No. 137, 2900 Main Street, Alameda, Alameda County, CA

SECOND FLOOR AND ROOF PLANS. United Engineering Company Ltd., Alameda ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

SECOND FLOOR AND ROOF PLANS. United Engineering Company Ltd., Alameda Shipyard, Ship Repair Facilities, Office Building. Second floor plan, and roof plan. John Hudspeth, Architect, at foot of Main Street, Alameda, Calif. Sheet no. A2 of 8 sheets, Plan no. 10,007. Scale 1/8 inch to the foot. March 18, 1942, last revised 9/22/43. U.S. Navy, Bureau of Yards & Docks, Contract no. bs 76. Approved for construction October 9, 1943. blueprint - United Engineering Company Shipyard, Office Building No. 137, 2900 Main Street, Alameda, Alameda County, CA

7. SHEET 1, CONTROL HOUSE FOR DRY DOCK. United Engineering ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. SHEET 1, CONTROL HOUSE FOR DRY DOCK. United Engineering Company Ltd., Alameda Shipyard, Ship Repair Facilities, Office Building. Plans, elevations, sections, details. John Hudspeth, Architect, at foot of Main Street, Alameda, Calif. Sheet no. 1 of 2 sheets, Plan no. 10,507. Various scales. January 4, 1943, last revised 1/28/43. U.S. Navy, Bureau of Yards & Docks, Contract no. bs 76. Approved for construction October 9, 1943. blueprint - United Engineering Company Shipyard, Control House for Dry Dock, 2900 Main Street, Alameda, Alameda County, CA

Regional tectonic evaluation of the Tuscan Apenine, vulcanism, thermal anomalies and the relation to structural units

NASA Technical Reports Server (NTRS)

Bodechtel, J. (Principal Investigator)

1975-01-01

The author has identified the following significant results. The geological interpretation on data exhibiting the Italian peninsula led to the recognition of tectonic features which are explained by a clockwise rotation of various blocks along left-handed transform faults. These faults can be interpreted as resulting from shear due to main stress directed north-eastwards. A land use map of the mountainous regions of Italy was produced on a scale of 1:250,000. For the digital treatment of MSS-CCTs an image processing software was written in FORTRAN 4. The software package includes descriptive statistics and also classification algorithms.

Predictors of employment status of treated patients with DSM-III-R diagnosis. Can logistic regression model find a solution?

PubMed

Daradkeh, T K; Karim, L

1994-01-01

To investigate the predictors of employment status of patients with DSM-III-R diagnosis, 55 patients were selected by a simple random technique from the main psychiatric clinic in Al Ain, United Arab Emirates. Structured and formal assessments were carried out to extract the potential predictors of outcome of schizophrenia. Logistic regression model revealed that being married, absence of schizoid personality, free or with minimum symptoms of the illness, later age of onset, and higher educational attainment were the most significant predictors of employment outcome. The implications of the results of this study are discussed in the text.

Diagnosis and management of acute heart failure

PubMed Central

Ural, Dilek; Çavuşoğlu, Yüksel; Eren, Mehmet; Karaüzüm, Kurtuluş; Temizhan, Ahmet; Yılmaz, Mehmet Birhan; Zoghi, Mehdi; Ramassubu, Kumudha; Bozkurt, Biykem

2016-01-01

Acute heart failure (AHF) is a life threatening clinical syndrome with a progressively increasing incidence in general population. Turkey is a country with a high cardiovascular mortality and recent national statistics show that the population structure has turned to an ‘aged’ population. As a consequence, AHF has become one of the main reasons of admission to cardiology clinics. This consensus report summarizes clinical and prognostic classification of AHF, its worldwide and national epidemiology, diagnostic work-up, principles of approach in emergency department, intensive care unit and ward, treatment in different clinical scenarios and approach in special conditions and how to plan hospital discharge. PMID:26574757

The effect of user fees on the utilization of family planning services. A clinical study.

PubMed

Bailey, W; Wynter, H H; Lee, A; Oliver, P; Jackson, J

1994-06-01

A new fee structure was introduced to the Advanced Training and Research in Fertility Management Unit in 1992. The study looked at the effect of the new fees on attendance and the choice of contraceptive methods through an examination of clinical records and a questionnaire survey. There was a decline in attendance of roughly 28 per cent between 1992 and 1993. The decline affected mainly new clients and those who accepted injectables. A reduction in the price of injectables is suggested since the fee for this short-term method is more in line with those charged for long-term and permanent methods.

Phase stabilities of pyrite-related MTCh compounds (M=Ni, Pd, Pt; T=Si, Ge, Sn, Pb; Ch=S, Se, Te): A systematic DFT study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bachhuber, Frederik; School of Chemical Sciences, University of Auckland, Private Bag 92019, Auckland; Krach, Alexander

2015-03-15

Pyrite-type and related systems appear for a wide range of binary and ternary combinations of transition metals and main group elements that form Zintl type dumbbell anion units. Those representatives with 20 valence electrons exhibit an extraordinary structural flexibility and interesting properties as low-gap semiconductors or thermoelectric and electrode materials. This work is devoted to the systematic exploration of novel compounds within the class of MTCh compounds (M=Ni, Pd, Pt; T=Si, Ge, Sn, Pb; Ch=S, Se, Te) by means of density functional calculations. Their preferred structures are predicted from an extended scheme of colored pyrites and marcasites. To determine theirmore » stabilities, competing binary MT{sub 2} and MCh{sub 2} boundary phases are taken into account as well as ternary M{sub 3}T{sub 2}Ch{sub 2} and M{sub 2}T{sub 3}Ch{sub 3} systems. Recently established stability diagrams are presented to account for MTCh ordering phenomena with a focus on a not-yet-reported ordering variant of the NiAs{sub 2} type. Due to the good agreement with experimental data available for several PtTCh systems, the predictions for the residual systems are considered sufficiently accurate. - Graphical abstract: Compositional and structural stability of MTCh compounds is investigated from first principle calculations. A conceptional approach is presented to study and predict novel stable and metastable compounds and structures of low gap semiconductors with TCh dumbbell units that are isoelectronic and structurally related to pyrite (FeS{sub 2}). - Highlights: • Study of compositional stability of MTCh vs. M{sub 3}T{sub 2}Ch{sub 2} and M{sub 2}T{sub 3}Ch{sub 3} compounds. • Study of structural stability of known and novel MTCh compounds. • Prediction of novel stable and metastable structures and compounds isoelectronic to pyrite, FeS{sub 2}.« less

Crystal structures of the free and inhibited forms of plasmepsin I (PMI) from Plasmodium falciparum

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhaumik, Prasenjit; Horimoto, Yasumi; Xiao, Huogen

2011-09-06

Plasmepsin I (PMI) is one of the four vacuolar pepsin-like proteases responsible for hemoglobin degradation by the malarial parasite Plasmodium falciparum, and the only one with no crystal structure reported to date. Due to substantial functional redundancy of these enzymes, lack of inhibition of even a single plasmepsin can defeat efforts in creating effective antiparasitic agents. We have now solved crystal structures of the recombinant PMI as apoenzyme and in complex with the potent peptidic inhibitor, KNI-10006, at the resolution of 2.4 and 3.1 {angstrom}, respectively. The apoenzyme crystallized in the orthorhombic space group P2{sub 1}2{sub 1}2{sub 1} with twomore » molecules in the asymmetric unit and the structure has been refined to the final R-factor of 20.7%. The KNI-10006 bound enzyme crystallized in the tetragonal space group P4{sub 3} with four molecules in the asymmetric unit and the structure has been refined to the final R-factor of 21.1%. In the PMI-KNI-10006 complex, the inhibitors were bound identically to all four enzyme molecules, with the opposite directionality of the main chain of KNI-10006 relative to the direction of the enzyme substrates. Such a mode of binding of inhibitors containing an allophenylnorstatine-dimethylthioproline insert in the P1-P1' positions, previously reported in a complex with PMIV, demonstrates the importance of satisfying the requirements for the proper positioning of the functional groups in the mechanism-based inhibitors towards the catalytic machinery of aspartic proteases, as opposed to binding driven solely by the specificity of the individual enzymes. A comparison of the structure of the PMI-KNI-10006 complex with the structures of other vacuolar plasmepsins identified the important differences between them and may help in the design of specific inhibitors targeting the individual enzymes.« less

32 CFR 989.29 - Force structure and unit move proposals.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 32 National Defense 6 2010-07-01 2010-07-01 false Force structure and unit move proposals. 989.29 Section 989.29 National Defense Department of Defense (Continued) DEPARTMENT OF THE AIR FORCE ENVIRONMENTAL PROTECTION ENVIRONMENTAL IMPACT ANALYSIS PROCESS (EIAP) § 989.29 Force structure and unit move...

Design study on the efficiency of the thermal scheme of power unit of thermal power plants in hot climates

NASA Astrophysics Data System (ADS)

Sedlov, A.; Dorokhov, Y.; Rybakov, B.; Nenashev, A.

2017-11-01

At the stage of pre-proposals unit of the thermal power plants for regions with a hot climate requires a design study on the efficiency of possible options for the structure of the thermal circuit and a set of key parameters. In this paper, the thermal circuit of the condensing unit powerfully 350 MW. The main feature of the external conditions of thermal power plants in hot climates is the elevated temperature of cooling water of the turbine condensers. For example, in the Persian Gulf region as the cooling water is sea water. In the hot season of the year weighted average sea water temperature of 30.9 °C and during the cold season to 22.8 °C. From the turbine part of the steam is supplied to the distillation-desalination plant. In the hot season of the year heat scheme with pressure fresh pair of 23.54 MPa, temperature 570/560 °C and feed pump with electric drive (EDP) is characterized by a efficiency net of 0.25% higher than thermal schem with feed turbine pump (TDP). However, the supplied power unit with PED is less by 11.6 MW. Calculations of thermal schemes in all seasons of the year allowed us to determine the difference in the profit margin of units of the TDP and EDP. During the year the unit with the TDP provides the ability to obtain the profit margin by 1.55 million dollars more than the unit EDP. When using on the market subsidized price of electricity (Iran) marginal profit of a unit with TDP more at 7.25 million dollars.

The cooperative forestry research unit Commercial Thinning Research Network--9-year results

Treesearch

Robert S. Seymour; Spencer R. Meyer; Robert G. Wagner

2014-01-01

The Commercial Thinning Research Network (CTRN) was established throughout the spruce-fir forest of Maine beginning in 2000 with substantial funding from the University of Maine's Cooperative Forestry Research Unit. One of six replicates of the precommercially thinned stand condition in the CTRN is located in compartment 23A in the U.S. Department of Agriculture,...

Research Assessment Exercise Results and Research Funding in the United Kingdom: A Comparative Analysis

ERIC Educational Resources Information Center

Chatterji, Monojit; Seaman, Paul

2006-01-01

A considerable sum of money is allocated to UK universities on the basis of Research Assessment Exercise performance. In this paper we analyse the two main funding models used in the United Kingdom and discuss their strengths and weaknesses. We suggest that the benchmarking used by the two main models have significant weaknesses, and propose an…

Place-Based Education and Geographic Information Systems: Enhancing the Spatial Awareness of Middle School Students in Maine

ERIC Educational Resources Information Center

Perkins, Nancy; Hazelton, Eric; Erickson, Jeryl; Allan, Walter

2010-01-01

Spatial literacy is a new frontier in K-12 education. This article describes a place-based introductory GIS/GPS middle school curriculum unit in which students used measuring tools, GPS units, and My World GIS software to collect physical and spatial data of trees to create a schoolyard tree inventory. Maine students completed "memory…