A New Strategy to Refine Crude Indian Sardine Oil.

PubMed

Charanyaa, S; Belur, Prasanna D; Regupathi, I

2017-05-01

Current work aims to develop a refining process for removing phospholipids, free fatty acids (FFA), and metal ions without affecting n-3 polyunsaturated fatty acid (n-3 PUFA) esters present in the crude Indian sardine oil. Sardine oil was subjected to degumming with various acids (orthophosphoric acid, acetic acid, and lactic acid), conventional and membrane assisted deacidification using various solvents (methanol, ethanol, propanol and butanol) and bleaching with bleaching agents (GAC, activated earth and bentonite) and all the process parameters were further optimized. Degumming with 5%(w/w) ortho phosphoric acid, two stage solvent extraction with methanol at 1:1 (w/w) in each stage and bleaching with 3% (w/w) activated charcoal loading, at 80ºC for 10 minutes resulted in the reduction of phospholipid content to 5.66 ppm from 612.66 ppm, FFA to 0.56% from 5.64% with the complete removal of iron and mercury. Under these conditions, the obtained bleached oil showed an enhancement of n-3 PUFA from 16.39 % (11.19 Eicosapentaenoic acid (EPA) + 5.20 Docosahexaenoic acid (DHA)) to 17.91 % (11.81 EPA + 6.1 DHA). Replacing conventional solvent extraction with membrane deacidification using microporous, hydrophobic polytetrafluoroethylene membrane (PTFE), resulted in a lesser solvent residue (0.25% (w/w)) in the deacidified oil. In view of lack of reports on refining of n-3 PUFA rich marine oils without concomitant loss of n-3 PUFA, this report is significant.

Quantum Yields of CAM Plants Measured by Photosynthetic O2 Exchange 1

PubMed Central

Adams, William W.; Nishida, Kojiro; Osmond, C. Barry

1986-01-01

The quantum yield of photosynthetic O2 exchange was measured in eight species of leaf succulents representative of both malic enzyme type and phosphoenolpyruvate carboxykinase type CAM plants. Measurements were made at 25°C and CO2 saturation using a leaf disc O2 electrode system, either during or after deacidification. The mean quantum yield was 0.095 ± 0.012 (sd) moles O2 per mole quanta, which compared with 0.094 ± 0.006 (sd) moles O2 per mole quanta for spinach leaf discs measured under the same conditions. There were no consistent differences in quantum yield between decarboxylation types or during different phases of CAM metabolism. On the basis of current notions of compartmentation of CAM biochemistry, our observations are interpreted to indicate that CO2 refixation is energetically independent of gluconeogenesis during deacidification. PMID:16664793

Colloid and materials science for the conservation of cultural heritage: cleaning, consolidation, and deacidification.

PubMed

Baglioni, Piero; Chelazzi, David; Giorgi, Rodorico; Poggi, Giovanna

2013-04-30

Serendipity and experiment have been a frequent approach for the development of materials and methodologies used for a long time for either cleaning or consolidation of works of art. Recently, new perspectives have been opened by the application of materials science, colloid science, and interface science frameworks to conservation, generating a breakthrough in the development of innovative tools for the conservation and preservation of cultural heritage. This Article is an overview of the most recent contributions of colloid and materials science to the art conservation field, mainly focusing on the use of amphiphile-based fluids, gels, and alkaline earth metal hydroxide nanoparticles dispersions for the cleaning of pictorial surfaces, the consolidation of artistic substrates, and the deacidification of paper, canvas, and wood. Future possible directions for solving several conservation issues that still need to be faced are also highlighted.

Calcium hydroxide nanoparticles for the conservation of cultural heritage: new formulations for the deacidification of cellulose-based artifacts

NASA Astrophysics Data System (ADS)

Poggi, G.; Toccafondi, N.; Melita, L. N.; Knowles, J. C.; Bozec, L.; Giorgi, R.; Baglioni, P.

2014-03-01

Alkaline earth metal hydroxide nanoparticles dispersions have demonstrated to be efficient for the preservation of cellulose-based artifacts, providing a stable neutral environment and, if in excess, turning into mild alkaline species. New formulations tailored for specific conservation issues have been recently obtained via a solvothermal reaction, starting from bulk metal, and short chain alcohols. Using this synthetic procedure, stable, and high concentrated calcium hydroxide nanoparticles dispersions can be obtained. The characterization of nanoparticles was carried out by dynamic light scattering, transmission electron microscopy and X-ray powder diffraction and showed that the dispersed systems are particularly suitable for the application on porous substrates. In a direct application of this technology, acidic paper and canvas samples were artificially aged after deacidification using calcium hydroxide nanoparticles dispersed in short chain alcohols. Cellulose viscosimetric polymerization degree (DPv), cellulose pyrolysis temperature, and samples' pH were evaluated upon the aging and in terms of protective action arising from the applied treatment. In particular, determinations of DPv clearly showed that the degradation of acidic paper and canvas samples proceeds at higher rates with respect to deacidified samples. These evidences were also confirmed by the thermogravimetric analysis of samples, in which the benefits due to the deacidification treatments are measured in terms of pyrolysis temperature of cellulose. These new formulations of nanoparticles dispersions expand the palette of available tools for the conservation of cellulose-based works of art, such as easel paintings, and manuscripts, potentially opening the way for the intervention on parchment and leather, whose preservation is a particularly challenging task.

Conservation and Preservation of Archives.

ERIC Educational Resources Information Center

Kathpalia, Y. P.

1982-01-01

Presents concept of preventive conservation of archival records as a new science resulting from the use of modern techniques and chemicals. Various techniques for storage, proper environment, preventive de-acidification, fire prevention, restoration, and staff considerations are described. References are provided. (EJS)

Conservation, Preservation, and Digitization.

ERIC Educational Resources Information Center

Lynch, Clifford A.; Brownrigg, Edwin B.

1986-01-01

Digital technologies should be considered a method of preservation for library materials. Current conservation strategies of restoration, deacidification, and microfilming are expensive, and they limit access. Digitization offers improved access while preserving materials and reflects a change in the library role from depository of printed…

Enology (Winemaking) Research.

ERIC Educational Resources Information Center

Gadek, Frank J.

1982-01-01

Describes senior research project centered around three facets of wine made from locally grown grapes: methods of deacidification, effect of pectic enzyme use during vinification, and qualitative/quantitative composition of total phenols of wines. Includes student participation (1975-1980) in and outcomes of the program, and laboratory techniques…

Conservation of Moroccan manuscript papers aged 150, 200 and 800 years. Analysis by infrared spectroscopy (ATR-FTIR), X-ray diffraction (XRD), and scanning electron microscopy energy dispersive spectrometry (SEM-EDS).

PubMed

Hajji, Latifa; Boukir, Abdellatif; Assouik, Jamal; Lakhiari, Hamid; Kerbal, Abdelali; Doumenq, Pierre; Mille, Gilbert; De Carvalho, Maria Luisa

2015-02-05

The preservation of manuscripts and archive materials is a serious problem for librarians and restorers. Paper manuscript is subjected to numerous degradation factors affecting their conservation state. This research represents an attempt to evaluate the conservation restoration process applied in Moroccan libraries, especially the alkaline treatment for strengthening weakened paper. In this study, we focused on six samples of degraded and restored paper taken from three different Moroccan manuscripts aged 150, 200 and 800 years. In addition, the Japanese paper used in restoration has been characterized. A modern paper was also analyzed as reference. A three-step analytical methodology based on infrared spectroscopy (ATR-FTIR), X-ray diffraction (XRD) and scanning electron microscopy coupled to energy dispersive spectrometry (SEM-EDS) analysis was developed before and after restoration in order to determine the effect of the consolidation treatment on the paper structure. The results obtained by XRD and ATR-FTIR disclosed the presence of barium sulfate (BaSO4) in all restored paper manuscripts. The presence of calcium carbonate (CaCO3) in all considered samples was confirmed by FTIR spectroscopy. The application of de-acidification treatment causes significant changes connected with the increase of intensity mostly in the region 1426 cm(-1), assigned to the asymmetric and symmetric CO stretching mode of calcite, indicating the effectiveness of de-acidification procedure proved by the rise of the alkaline reserve content allowing the long term preservation of paper. Observations performed by SEM magnify the typical paper morphology and the structure of fibbers, highlighting the effect of the restoration process, manifested by the reduction of impurities. Copyright © 2014 Elsevier B.V. All rights reserved.

Effects of acetic acid, ethanol, and SO(2) on the removal of volatile acidity from acidic wines by two Saccharomyces cerevisiae commercial strains.

PubMed

Vilela-Moura, Alice; Schuller, Dorit; Mendes-Faia, Arlete; Côrte-Real, Manuela

2010-07-01

Herein, we report the influence of different combinations of initial concentration of acetic acid and ethanol on the removal of acetic acid from acidic wines by two commercial Saccharomyces cerevisiae strains S26 and S29. Both strains reduced the volatile acidity of an acidic wine (1.0 gl(-1) acetic acid and 11% (v/v) ethanol) by 78% and 48%, respectively. Acetic acid removal by strains S26 and S29 was associated with a decrease in ethanol concentration of 0.7 and 1.2% (v/v), respectively. Strain S26 revealed better removal efficiency due to its higher tolerance to stress factors imposed by acidic wines. Sulfur dioxide (SO(2)) in the concentration range 95-170 mg l(-1)inhibits the ability of both strains to reduce the volatile acidity of the acidic wine used under our experimental conditions. Therefore, deacidification should be carried out either in wines stabilized by filtration or in wines with SO(2)concentrations up to 70 mg l(-1). Deacidification of wines with the better performing strain S26 was associated with changes in the concentration of volatile compounds. The most pronounced increase was observed for isoamyl acetate (banana) and ethyl hexanoate (apple, pineapple), with an 18- and 25-fold increment, respectively, to values above the detection threshold. The acetaldehyde concentration of the deacidified wine was 2.3 times higher, and may have a detrimental effect on the wine aroma. Moreover, deacidification led to increased fatty acids concentration, but still within the range of values described for spontaneous fermentations, and with apparently no negative impact on the organoleptical properties.

The Once and Future Book: The Preservation Crisis.

ERIC Educational Resources Information Center

Brown, Jay Ward

1985-01-01

Discussion of problem of paper deterioration in books highlights developments in paper industry, acidic and alkaline paper, demand for book paper by publishing industry, library material conservation, and preservation activities in three areas--deacidification (use of alkaline chemicals to neutralize acidic paper), microfilming, and…

Book Preservation

NASA Technical Reports Server (NTRS)

1980-01-01

Books produced since 1850, held in the Library of Congress, have a very high acid content, hence a shorter life expectancy than prior-published volumes. A means of "deacidifying" books on a large, economically-viable scale is of great interest, particularly to the research library community, which stores millions of valuable, often irreplaceable documents. The General Electric vacuum chamber used in deacidification tests serves a dual purpose. It creates an environment in which DEZ can do its job without presence of oxygen and also dries the books. After the drying phase, DEZ is introduced to the chamber as a paper-penetrating vapor. The complete process typically takes eight days, four days for vacuum drying and four days of book exposure to DEZ. Accelerated aging tests showed that the process can extend paper life almost fourfold, even on color illustrations.

Membrane processing technology in the food industry: food processing, wastewater treatment, and effects on physical, microbiological, organoleptic, and nutritional properties of foods.

PubMed

Kotsanopoulos, Konstantinos V; Arvanitoyannis, Ioannis S

2015-01-01

Membrane processing technology (MPT) is increasingly used nowadays in a wide range of applications (demineralization, desalination, stabilization, separation, deacidification, reduction of microbial load, purification, etc.) in food industries. The most frequently applied techniques are electrodialysis (ED), reverse osmosis (RO), nanofiltration (NF), ultrafiltration (UF), and microfiltration (MF). Several membrane characteristics, such as pore size, flow properties, and the applied hydraulic pressure mainly determine membranes' potential uses. In this review paper the basic membrane techniques, their potential applications in a large number of fields and products towards the food industry, the main advantages and disadvantages of these methods, fouling phenomena as well as their effects on the organoleptic, qualitative, and nutritional value of foods are synoptically described. Some representative examples of traditional and modern membrane applications both in tabular and figural form are also provided.

Reduction of volatile acidity of acidic wines by immobilized Saccharomyces cerevisiae cells.

PubMed

Vilela, A; Schuller, D; Mendes-Faia, A; Côrte-Real, M

2013-06-01

Excessive volatile acidity in wines is a major problem and is still prevalent because available solutions are nevertheless unsatisfactory, namely, blending the filter-sterilized acidic wine with other wines of lower volatile acidity or using reverse osmosis. We have previously explored the use of an empirical biological deacidification procedure to lower the acetic acid content of wines. This winemaker's enological practice, which consists in refermentation associated with acetic acid consumption by yeasts, is performed by mixing the acidic wine with freshly crushed grapes, musts, or marc from a finished wine fermentation. We have shown that the commercial strain Saccharomyces cerevisiae S26 is able to decrease the volatile acidity of acidic wines with a volatile acidity higher than 1.44 g L(-1) acetic acid, with no detrimental impact on wine aroma. In this study, we aimed to optimize the immobilization of S26 cells in alginate beads for the bioreduction of volatile acidity of acidic wines. We found that S26 cells immobilized in double-layer alginate-chitosan beads could reduce the volatile acidity of an acidic wine (1.1 g L(-1) acetic acid, 12.5 % (v/v) ethanol, pH 3.12) by 28 and 62 % within 72 and 168 h, respectively, associated with a slight decrease in ethanol concentration (0.7 %). Similar volatile acidity removal efficiencies were obtained in medium with high glucose concentration (20 % w/v), indicating that this process may also be useful in the deacidification of grape musts. We, therefore, show that immobilized S. cerevisiae S26 cells in double-layer beads are an efficient alternative to improve the quality of wines with excessive volatile acidity.

A Multi-Analytical Approach for the Evaluation of the Efficiency of the Conservation-Restoration Treatment of Moroccan Historical Manuscripts Dating to the 16th, 17th, and 18th Centuries.

PubMed

Hajji, Latifa; Boukir, Abdellatif; Assouik, Jamal; Kerbal, Abdelali; Kajjout, Mohamed; Doumenq, Pierre; De Carvalho, Maria Luisa

2015-08-01

The most critical steps during the conservation-restoration treatment applied in Moroccan libraries are the deacidification using immersion in a saturated aqueous calcium hydroxide (Ca(OH)2) solution and the consolidation of degraded manuscripts using Japanese paper. The present study aims to assess the efficiency of this restoration method using a multi-analytical approach. For this purpose, three ancient Arabic Moroccan manuscript papers dating back to the 16th, 17th, and 18th centuries were investigated to characterize the paper support and make a comparative study between pre-restoration and post-restoration states. Three structural and molecular characterization techniques including solid-state nuclear magnetic resonance spectroscopy on (13)C with cross-polarization and magic-angle spinning nuclear magnetic resonance ((13)C CP-MAS NMR), attenuated total reflectance Fourier transform infrared spectroscopy (ATR FT-IR), and X-ray diffraction (XRD) were used to elucidate the cellulose main features, to identify the inorganic composition of the papers, and to study the crystallinity of the samples. Inductively coupled plasma atomic emission spectrometry (ICP-AES) allowed us to obtain a qualitative and quantitative characterization of the mineral fillers used in the manufacturing of the papers. Scanning electron microscopy coupled to energy dispersive spectrometry (SEM-EDS) ascertained the state of conservation of the different papers and helped us to study the elemental composition of the samples. After restoration, it was shown that the deacidification improved the stability of papers by providing an important alkaline buffer, as demonstrated using FT-IR and energy dispersive spectrometry (EDS) results. However, XRD and ICP-AES did not confirm the pertinence of the treatment for all samples because of the unequal distribution of Ca on the paper surface during the restoration. The consolidation process was studied using SEM analysis; its effectiveness in restoring torn areas was found to be significant.

Einsatz hydrogeochemischer Modelle in der Wasseraufbereitung

NASA Astrophysics Data System (ADS)

Wisotzky, Frank

2012-09-01

As part of a model-data investigation project, results of several water treatment studies were compared with hydrochemical models. The models used comparable hydrogeological reaction types that occur within aquifers and water treatment processes. They were tested on 3 different examples of water softening, de-nitrification and iron removal. Comparison of simulated and measured water chemical dynamics showed good agreement. In addition to mixing and formation of complexes, de-acidification and de-carbonisation processes were reproduced in the first example. The second example investigated de-nitrification in a straw filter and in a water plant filter with subsequent aeration. The third example showed iron removal where reactions with partially combusted dolomite were simulated with a computer model. All simulations showed good agreement with the observed data. The models have the advantage of yielding parameter results that are difficult to measure. This includes nitrogen gas release and the content of reacted and degradable organic substances. These tools may help to provide better insights into water treatment reactions.

Degradation products from naturally aged paper leaves of a 16th-century-printed book: a spectrochemical study.

PubMed

Bronzato, Maddalena; Calvini, Paolo; Federici, Carlo; Bogialli, Sara; Favaro, Gabriella; Meneghetti, Moreno; Mba, Miriam; Brustolon, Marina; Zoleo, Alfonso

2013-07-15

In this work, we present a wide-range spectrochemical analysis of the degradation products from naturally aged paper. The samples obtained from wash waters used during the de-acidification treatment of leaves from a 16th-century-printed book were analysed through NMR, IR, Raman UV/Vis, EPR and X-ray fluorescence (XRF) spectroscopy and HPLC-MS and inductively coupled plasma (ICP) analysis. By these methods we also studied some of the previous samples treated by acidification (sample AP) and catalytic hydrogenation (sample HP). Crossing all the data, we obtained precise indications about the main functional groups occurring on the degraded, water-soluble cellulose oligomers. These results point out that the chromophores responsible for browning are conjugated carbonyl and carboxyl compounds. As a whole, we show that the analysis of wash waters, used in the usual conservation treatments of paper de-acidification, gives much valuable information about both the conservation state of the book and the degradation reactions occurring on the leaves, due to the huge amount of cellulose by-products contained in the samples. We propose therefore this procedure as a new very convenient general method to obtain precious and normally unavailable information on the cellulose degradation by-products from naturally aged paper. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Carbon Dioxide Exchange and Acidity Levels in Detached Pineapple, Ananas comosus (L.), Merr., Leaves during the Day at Various Temperatures, Oxygen and Carbon Dioxide Concentrations.

PubMed

Moradshahi, A; Vines, H M; Black, C C

1977-02-01

The effects of temperature, O(2), and CO(2) on titratable acid content and on CO(2) exchange were measured in detached pineapple (Ananas comosus) leaves during the daily 15-hour light period. Comparative measurements were made in air and in CO(2)-free air. Increasing the leaf temperature from 20 to 35 C decreased the total CO(2) uptake in air and slightly increased the total CO(2) released into CO(2)-free air. Between 25 and 35 C, the activation energy for daily acid loss was near 12 kcal mol(-1), but at lower temperatures the activation energy was much greater.Increasing O(2) or decreasing the CO(2) concentration decreased the total CO(2) fixation in air, whereas the total CO(2) released in CO(2)-free air was increased. The total acid content remained constant at 20 C, but it decreased progressively with increasing temperature both in air and in CO(2)-free air. The total acid content at 30 C remained constant in 2% O(2) irrespective of CO(2) concentration. The total acid content decreased in 21 and 50% O(2) as the CO(2) increased from 0 to 300, and 540 mul/l of CO(2). The data indicate that photorespiration is present in pineapple. The lack of acid loss in 2% O(2) suggests that light deacidification is dependent upon respiration and that higher O(2) concentrations are required to saturate deacidification.

Vibrio effector protein VopQ inhibits fusion of V-ATPase–containing membranes

PubMed Central

Sreelatha, Anju; Bennett, Terry L.; Carpinone, Emily M.; O’Brien, Kevin M.; Jordan, Kamyron D.; Burdette, Dara L.; Orth, Kim; Starai, Vincent J.

2015-01-01

Vesicle fusion governs many important biological processes, and imbalances in the regulation of membrane fusion can lead to a variety of diseases such as diabetes and neurological disorders. Here we show that the Vibrio parahaemolyticus effector protein VopQ is a potent inhibitor of membrane fusion based on an in vitro yeast vacuole fusion model. Previously, we demonstrated that VopQ binds to the Vo domain of the conserved V-type H+-ATPase (V-ATPase) found on acidic compartments such as the yeast vacuole. VopQ forms a nonspecific, voltage-gated membrane channel of 18 Å resulting in neutralization of these compartments. We now present data showing that VopQ inhibits yeast vacuole fusion. Furthermore, we identified a unique mutation in VopQ that delineates its two functions, deacidification and inhibition of membrane fusion. The use of VopQ as a membrane fusion inhibitor in this manner now provides convincing evidence that vacuole fusion occurs independently of luminal acidification in vitro. PMID:25453092

Vibrio effector protein VopQ inhibits fusion of V-ATPase-containing membranes.

PubMed

Sreelatha, Anju; Bennett, Terry L; Carpinone, Emily M; O'Brien, Kevin M; Jordan, Kamyron D; Burdette, Dara L; Orth, Kim; Starai, Vincent J

2015-01-06

Vesicle fusion governs many important biological processes, and imbalances in the regulation of membrane fusion can lead to a variety of diseases such as diabetes and neurological disorders. Here we show that the Vibrio parahaemolyticus effector protein VopQ is a potent inhibitor of membrane fusion based on an in vitro yeast vacuole fusion model. Previously, we demonstrated that VopQ binds to the V(o) domain of the conserved V-type H(+)-ATPase (V-ATPase) found on acidic compartments such as the yeast vacuole. VopQ forms a nonspecific, voltage-gated membrane channel of 18 Å resulting in neutralization of these compartments. We now present data showing that VopQ inhibits yeast vacuole fusion. Furthermore, we identified a unique mutation in VopQ that delineates its two functions, deacidification and inhibition of membrane fusion. The use of VopQ as a membrane fusion inhibitor in this manner now provides convincing evidence that vacuole fusion occurs independently of luminal acidification in vitro.

Synthetic tambjamine analogues induce mitochondrial swelling and lysosomal dysfunction leading to autophagy blockade and necrotic cell death in lung cancer.

PubMed

Rodilla, Ananda M; Korrodi-Gregório, Luís; Hernando, Elsa; Manuel-Manresa, Pilar; Quesada, Roberto; Pérez-Tomás, Ricardo; Soto-Cerrato, Vanessa

2017-02-15

Current pharmacological treatments for lung cancer show very poor clinical outcomes, therefore, the development of novel anticancer agents with innovative mechanisms of action is urgently needed. Cancer cells have a reversed pH gradient compared to normal cells, which favours cancer progression by promoting proliferation, metabolic adaptation and evasion of apoptosis. In this regard, the use of ionophores to modulate intracellular pH appears as a promising new therapeutic strategy. Indeed, there is a growing body of evidence supporting ionophores as novel antitumour drugs. Despite this, little is known about the implications of pH deregulation and homeostasis imbalance triggered by ionophores at the cellular level. In this work, we deeply analyse for the first time the anticancer effects of tambjamine analogues, a group of highly effective anion selective ionophores, at the cellular and molecular levels. First, their effects on cell viability were determined in several lung cancer cell lines and patient-derived cancer stem cells, demonstrating their potent cytotoxic effects. Then, we have characterized the induced lysosomal deacidification, as well as, the massive cytoplasmic vacuolization observed after treatment with these compounds, which is consistent with mitochondrial swelling. Finally, the activation of several proteins involved in stress response, autophagy and apoptosis was also detected, although they were not significantly responsible for the cell death induced. Altogether, these evidences suggest that tambjamine analogues provoke an imbalance in cellular ion homeostasis that triggers mitochondrial dysfunction and lysosomal deacidification leading to a potent cytotoxic effect through necrosis in lung cancer cell lines and cancer stem cells. Copyright © 2016 Elsevier Inc. All rights reserved.

Physicochemical, Antioxidant and Sensory Quality of Brazilian Blueberry Wine.

PubMed

Santos, Roberta O; Trindade, Simone C; Maurer, Luana H; Bersch, Andriely M; Sautter, Claudia K; Penna, Neidi G

2016-09-01

Currently, Rio Grande do Sul state is the main producer of blueberry in Brazil. Practically all production is commercialized in fresh state and only a small portion is subject to processing. The blueberry wine making process is an alternative to expand the beverage industry and offers to the consumer a value-added product as well as a new market for Brazilian blueberry producers. The objectives of this study were to produce wines from blueberries and to evaluate the effect of deacidification (with calcium carbonate) and chaptalization (with glucose syrup or sucrose) on physicochemical characteristics, antioxidant content, and sensory parameters. Samples were analyzed for total soluble solids, pH, total titratable acidity, total sugar content, alcohol content, monomeric and total anthocyanin, total flavonols, total phenolic compounds and antioxidant activity by DPPH and FRAP methods. The use of calcium carbonate caused a reduction in total titratable acidity, while the use of glucose syrup resulted in wines with low alcohol content. The blueberries wine from Climax and Aliceblue cultivars had higher content of anthocyanin when produced with glucose syrup. The use of calcium carbonate and glucose syrup also provided wines more appreciated by tasters in relation to color. With regard to flavor, George and Aliceblue were the cultivars with lower preference under the control treatments (without carbonate and sugar). The presence of phenolic compounds may have provided a positive influence on wine flavor, once the more preferred wines presented the greater phenolic content.

Synthesis, Biological Evaluation, and Autophagy Mechanism of 12N-Substituted Sophoridinamines as Novel Anticancer Agents.

PubMed

Bi, Chongwen; Zhang, Na; Yang, Peng; Ye, Cheng; Wang, Yanxiang; Fan, Tianyun; Shao, Rongguang; Deng, Hongbin; Song, Danqing

2017-02-09

A series of 12 N -substituted sophoridinamine derivatives were synthesized and evaluated for their cytotoxic activities in human HepG2 hepatoma cells. Structure-activity relationship revealed that introduction of a suitable arylidene or arylethyl at the N '-end could greatly enhance antiproliferation potency. Among them, compound 6b possessing a N '-trimethoxyphenyl methylene exhibited potent antiproliferation effect against three human tumor cell lines including HepG2, leukemia (K562), and breast cancer (HMLE), with IC 50 between 0.55 and 1.7 μM. The underlying mechanism of 6b against tumor cells is to block autophagic flux, mainly through neutralizing lysosomal acidity. Our results indicated that compound 6b is a potent lysosomal deacidification agent and is accordingly able to block autophagic flux and inhibit tumor cell growth.

Optimizing anti-coking abilities of zeolites by ethylene diamine tetraacetie acid modification on catalytic fast pyrolysis of corn stalk

NASA Astrophysics Data System (ADS)

Zhang, Bo; Zhong, Zhaoping; Song, Zuwei; Ding, Kuan; Chen, Paul; Ruan, Roger

2015-12-01

In order to minimize coke yield during biomass catalytic fast pyrolysis (CFP) process, ethylene diamine tetraacetie acid (EDTA) chemical modification method is carried out to selectively remove the external framework aluminum of HZSM-5 catalyst. X-ray diffraction (XRD), nitrogen (N2)-adsorption and ammonia-temperature programmed desorption (NH3-TPD) techniques are employed to investigate the porosity and acidity characteristics of original and modified HZSM-5 samples. Py-GC/MS and thermo-gravimetric analyzer (TGA) experiments are further conducted to explore the catalytic effect of modified HZSM-5 samples on biomass CFP and to verify the positive effect on coke reduction. Results show that EDTA treatment does not damage the crystal structure of HZSM-5 zeolites, but leads to a slight increase of pore volume and pore size. Meanwhile, the elimination of the strong acid peak indicates the dealumination of outer surface of HZSM-5 zeolites. Treatment time of 2 h (labeled EDTA-2H) is optimal for acid removal and hydrocarbon formation. Among all modified catalysts, EDTA-2H performs the best for deacidification and can obviously increase the yields of positive chemical compositions in pyrolysis products. Besides, EDTA modification can improve the anti-coking properties of HZSM-5 zeolites, and EDTA-2H gives rise to the lowest coke yield.

Operating and environmental performances of commercial-scale waste gasification and melting technology.

PubMed

Tanigaki, Nobuhiro; Fujinaga, Yasuka; Kajiyama, Hirohisa; Ishida, Yoshihiro

2013-11-01

Gasification technologies for waste processing are receiving increased interest. A lot of gasification technologies, including gasification and melting, have been developed in Japan and Europe. However, the flue gas and heavy metal behaviors have not been widely reported, even though those of grate furnaces have been reported. This article reports flue gas components of gasification and melting technology in different flue gas treatment systems. Hydrogen chloride concentrations at the inlet of the bag filter ranged between 171 and 180 mg Nm(-3) owing to de-acidification by limestone injection to the gasifier. More than 97.8% of hydrogen chlorides were removed by a bag filter in both of the flue gas treatment systems investigated. Sulfur dioxide concentrations at the inlet of the baghouse were 4.8 mg Nm(-3) and 12.7 mg Nm(-3), respectively. Nitrogen oxides are highly decomposed by a selective catalytic reduction system. Owing to the low regenerations of polychlorinated dibenzo-p-dioxins and furans, and the selective catalytic reduction system, the concentrations of polychlorinated dibenzo-p-dioxins and furans at the stacks were significantly lower without activated carbon injection. More than 99% of chlorine is distributed in fly ash. Low-boiling-point heavy metals, such as lead and zinc, are distributed in fly ash at rates of 97.6% and 96.5%, respectively. Most high-boiling-point heavy metals, such as iron and copper, are distributed in metal. It is also clarified that the slag is stable and contains few harmful heavy metals, such as lead. The heavy metal distribution behaviors are almost the same regardless of the compositions of the processed waste. These results indicate that the gasification of municipal solid waste constitutes an ideal approach to environmental conservation and resource recycling.

Selected Schizosaccharomyces pombe Strains Have Characteristics That Are Beneficial for Winemaking

PubMed Central

Benito, Ángel; Jeffares, Daniel; Palomero, Felipe; Calderón, Fernando; Bai, Feng-Yan; Bähler, Jürg; Benito, Santiago

2016-01-01

At present, wine is generally produced using Saccharomyces yeast followed by Oenococus bacteria to complete malolactic fermentation. This method has some unsolved problems, such as the management of highly acidic musts and the production of potentially toxic products including biogenic amines and ethyl carbamate. Here we explore the potential of the fission yeast Schizosaccharomyces pombe to solve these problems. We characterise an extensive worldwide collection of S. pombe strains according to classic biochemical parameters of oenological interest. We identify three genetically different S. pombe strains that appear suitable for winemaking. These strains compare favourably to standard Saccharomyces cerevisiae winemaking strains, in that they perform effective malic acid deacidification and significantly reduce levels of biogenic amines and ethyl carbamate precursors without the need for any secondary bacterial malolactic fermentation. These findings indicate that the use of certain S. pombe strains could be advantageous for winemaking in regions where malic acid is problematic, and these strains also show superior performance with respect to food safety. PMID:27007548

Archaeal community composition affects the function of anaerobic co-digesters in response to organic overload

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lerm, S.; Kleyboecker, A.; Miethling-Graff, R.

2012-03-15

Highlights: Black-Right-Pointing-Pointer Two types of methanogens are necessary to respond successfully to perturbation. Black-Right-Pointing-Pointer Diversity of methanogens correlates with the VFA concentration and methane yield. Black-Right-Pointing-Pointer Aggregates indicate tight spatial relationship between minerals and microorganisms. - Abstract: Microbial community diversity in two thermophilic laboratory-scale and three full-scale anaerobic co-digesters was analysed by genetic profiling based on PCR-amplified partial 16S rRNA genes. In parallel operated laboratory reactors a stepwise increase of the organic loading rate (OLR) resulted in a decrease of methane production and an accumulation of volatile fatty acids (VFAs). However, almost threefold different OLRs were necessary to inhibit themore » gas production in the reactors. During stable reactor performance, no significant differences in the bacterial community structures were detected, except for in the archaeal communities. Sequencing of archaeal PCR products revealed a dominance of the acetoclastic methanogen Methanosarcina thermophila, while hydrogenotrophic methanogens were of minor importance and differed additionally in their abundance between reactors. As a consequence of the perturbation, changes in bacterial and archaeal populations were observed. After organic overload, hydrogenotrophic methanogens (Methanospirillum hungatei and Methanoculleus receptaculi) became more dominant, especially in the reactor attributed by a higher OLR capacity. In addition, aggregates composed of mineral and organic layers formed during organic overload and indicated tight spatial relationships between minerals and microbial processes that may support de-acidification processes in over-acidified sludge. Comparative analyses of mesophilic stationary phase full-scale reactors additionally indicated a correlation between the diversity of methanogens and the VFA concentration combined with the methane yield. This study demonstrates that the coexistence of two types of methanogens, i.e. hydrogenotrophic and acetoclastic methanogens is necessary to respond successfully to perturbation and leads to stable process performance.« less

Mango kernel fat fractions as potential healthy food ingredients: A review.

PubMed

Jin, Jun; Jin, Qingzhe; Akoh, Casimir C; Wang, Xingguo

2018-01-16

Mango kernel fat (MKF) has been reported to have high functional and nutritional potential. However, its application in food industry has not been fully explored or developed. In this review, the chemical compositions, physical properties and potential health benefits of MKF are described. MKF is a unique fat consisting of 28.9-65.0% of 1,3-distearoyl-2-oleoyl-glycerol with excellent oxidative stability index (58.8-85.2 h at 110 °C), making the fat and its fractions suitable for use as high-value added food ingredients such as cocoa butter alternatives, trans-free shortenings, and a source of natural antioxidants (e.g., sterol, tocopherol and squalene). Unfortunately, the long period of dehydration of mango kernels at hot temperature results in the hydrolysis of triacylglycerols. The high levels of hydrolysates (mainly free fatty acids and diacylglycerols) limit the application of MKF in manufacturing these food ingredients. It is suggested that the physico-chemical and functional properties of MKF could be further improved through moderated refining (e.g., degumming and physical deacidification), fractionation, and interesterification.

Halloysite Nanotubes: Controlled Access and Release by Smart Gates.

PubMed

Cavallaro, Giuseppe; Danilushkina, Anna A; Evtugyn, Vladimir G; Lazzara, Giuseppe; Milioto, Stefana; Parisi, Filippo; Rozhina, Elvira V; Fakhrullin, Rawil F

2017-07-28

Hollow halloysite nanotubes have been used as nanocontainers for loading and for the triggered release of calcium hydroxide for paper preservation. A strategy for placing end-stoppers into the tubular nanocontainer is proposed and the sustained release from the cavity is reported. The incorporation of Ca(OH)₂ into the nanotube lumen, as demonstrated using transmission electron microscopy (TEM) imaging and Energy Dispersive X-ray (EDX) mapping, retards the carbonatation, delaying the reaction with CO₂ gas. This effect can be further controlled by placing the end-stoppers. The obtained material is tested for paper deacidification. We prove that adding halloysite filled with Ca(OH)₂ to paper can reduce the impact of acid exposure on both the mechanical performance and pH alteration. The end-stoppers have a double effect: they preserve the calcium hydroxide from carbonation, and they prevent from the formation of highly basic pH and trigger the response to acid exposure minimizing the pH drop-down. These features are promising for a composite nanoadditive in the smart protection of cellulose-based materials.

Lactic acid bacteria in the quality improvement and depreciation of wine.

PubMed

Lonvaud-Funel, A

1999-01-01

The winemaking process includes two main steps: lactic acid bacteria are responsible for the malolactic fermentation which follows the alcoholic fermentation by yeasts. Both types of microorganisms are present on grapes and on cellar equipment. Yeasts are better adapted to growth in grape must than lactic acid bacteria, so the alcoholic fermentation starts quickly. In must, up to ten lactic acid bacteria species can be identified. They belong to the Lactobacillus, Pediococcus, Leuconostoc and Oenococcus genera. Throughout alcoholic fermentation, a natural selection occurs and finally the dominant species is O. oeni, due to interactions between yeasts and bacteria and between bacteria themselves. After bacterial growth, when the population is over 10(6) CFU/ml, malolactic transformation is the obvious change in wine composition. However, many other substrates can be metabolized. Some like remaining sugars and citric acid are always assimilated by lactic acid bacteria, thus providing them with energy and carbon. Other substrates such as some amino acids may be used following pathways restricted to strains carrying the adequate enzymes. Some strains can also produce exopolysaccharides. All these transformations greatly influence the sensory and hygienic quality of wine. Malic acid transformation is encouraged because it induces deacidification. Diacetyl produced from citric acid is also helpful to some extent. Sensory analyses show that many other reactions change the aromas and make malolactic fermentation beneficial, but they are as yet unknown. On the contrary, an excess of acetic acid, the synthesis of glucane, biogenic amines and precursors of ethylcarbamate are undesirable. Fortunately, lactic acid bacteria normally multiply in dry wines; moreover some of these activities are not widespread. Moreover, the most striking trait of wine lactic acid bacteria is their capacity to adapt to a hostile environment. The mechanisms for this are not yet completely elucidated. Molecular biology has provided some explanations for the behaviour and the metabolism of bacteria in wine. New tools are now available to detect the presence of desirable and undesirable strains. Even if much remains unknown, winemakers and oenologists can nowadays better control the process. By acting upon the diverse microflora and grape musts, they are more able to produce healthy and pleasant wines.

Newly Developed Nano-Calcium Carbonate and Nano-Calcium Propanoate for the Deacidification of Library and Archival Materials

PubMed Central

Valentini, Federica; Calcaterra, Andrea; Talamo, Maurizio

2017-01-01

Paper-based cultural heritage objects are subject to natural deterioration due to internal and external factors, that is, the presence of heavy metals, incorrect conservation, humidity, exposure of the artifacts to pollutants, light, and high temperatures. To contrast the decay of the original objects, it is necessary to study and apply innovative specific techniques, set up novel preservation methodologies, and implement or synthesize new products. As the nanomaterial science field developed over the last decades, the usage of nanomaterials in cultural heritage gained a prominent role. Such an excitement for the novel materials opened the path for an uncontrolled transfer of nanoparticles developed for different applications to paper restoration, neglecting all their possible interactions with the support or the graphic media. The aim of this work was to synthesize new nanomaterials expressly conceived for the treatment of library materials. To evaluate their possible insertion in the official conservation treatments that are subjected to validation by Istituto Centrale Restauro e Conservazione Patrimonio Archivistico e Librario, the new nanomaterials were tested both on laboratory paper samples and on original documents. This work presents the results of these studies (some of which still preliminary) stressing the positive and extremely promising outcomes of this research. PMID:29441213

Newly Developed Nano-Calcium Carbonate and Nano-Calcium Propanoate for the Deacidification of Library and Archival Materials.

PubMed

Bicchieri, Marina; Valentini, Federica; Calcaterra, Andrea; Talamo, Maurizio

2017-01-01

Paper-based cultural heritage objects are subject to natural deterioration due to internal and external factors, that is, the presence of heavy metals, incorrect conservation, humidity, exposure of the artifacts to pollutants, light, and high temperatures. To contrast the decay of the original objects, it is necessary to study and apply innovative specific techniques, set up novel preservation methodologies, and implement or synthesize new products. As the nanomaterial science field developed over the last decades, the usage of nanomaterials in cultural heritage gained a prominent role. Such an excitement for the novel materials opened the path for an uncontrolled transfer of nanoparticles developed for different applications to paper restoration, neglecting all their possible interactions with the support or the graphic media. The aim of this work was to synthesize new nanomaterials expressly conceived for the treatment of library materials. To evaluate their possible insertion in the official conservation treatments that are subjected to validation by Istituto Centrale Restauro e Conservazione Patrimonio Archivistico e Librario, the new nanomaterials were tested both on laboratory paper samples and on original documents. This work presents the results of these studies (some of which still preliminary) stressing the positive and extremely promising outcomes of this research.

Non-catalytic alcoholysis process for production of biodiesel fuel by using bubble column reactor

NASA Astrophysics Data System (ADS)

Hagiwara, S.; Nabetani, H.; Nakajima, M.

2015-04-01

Biodiesel fuel is a replacement for diesel as a fuel produced from biomass resources. It is usually defined as a fatty acid methyl ester (FAME) derived from vegetable oil or animal fat. In European countries, such as Germany and France, biodiesel fuel is commercially produced mainly from rapeseed oil, whereas in the United States and Argentina, soybean oil is more frequently used. In many other countries such as Japan and countries in Southeast Asia, lipids that cannot be used as a food source could be more suitable materials for the production of biodiesel fuel because its production from edible oils could result in an increase in the price of edible oils, thereby increasing the cost of some foodstuffs. Therefore, used edible oil, lipids contained in waste effluent from the oil milling process, byproducts from oil refining process and crude oils from industrial crops such as jatropha could be more promising materials in these countries. The materials available in Japan and Southeast Asia for the production of biodiesel fuel have common characteristics; they contain considerable amount of impurities and are high in free fatty acids (FFA). Superheated methanol vapor (SMV) reactor might be a promising method for biodiesel fuel production utilizing oil feedstock containing FFA such as waste vegetable oil and crude vegetable oil. In the conventional method using alkaline catalyst, FFA contained in waste vegetable oil is known to react with alkaline catalyst such as NaOH and KOH generating saponification products and to inactivate it. Therefore, the FFA needs to be removed from the feedstock prior to the reaction. Removal of the alkaline catalyst after the reaction is also required. In the case of the SMV reactor, the processes for removing FFA prior to the reaction and catalyst after the reaction can be omitted because it requires no catalyst. Nevertheless, detailed study on the productivity of biodiesel fuel produced from waste vegetable oils and other non-edible lipids by use of the SMV reactor has not been examined yet. Therefore, this study aims to investigate the productivity of biodiesel produced from waste vegetable oils using the SMV reactor. Biodiesel fuel is a replacement for diesel as a fuel produced from biomass resources. It is generally produced as a FAME derived from vegetable oil by using alkaline catalyzed alcoholysis process. This alkaline method requires deacidification process prior to the reaction process and the alkaline catalyst removal process after the reaction. Those process increases the total cost of biodiesel fuel production. In order to solve the problems in the conventional alkaline catalyzed alcoholysis process, the authors proposed a non-catalytic alcoholysis process called the Superheated Methanol Vapor (SMV) method with bubble column reactor. So, this study aims to investigate the productivity of biodiesel produced from vegetable oils and other lipids using the SMV method with bubble column reactor.

Heat and Mass Transfer Processes in Scrubber of Flue Gas Heat Recovery Device

NASA Astrophysics Data System (ADS)

Veidenbergs, Ivars; Blumberga, Dagnija; Vigants, Edgars; Kozuhars, Grigorijs

2010-01-01

The paper deals with the heat and mass transfer process research in a flue gas heat recovery device, where complicated cooling, evaporation and condensation processes are taking place simultaneously. The analogy between heat and mass transfer is used during the process of analysis. In order to prepare a detailed process analysis based on heat and mass process descriptive equations, as well as the correlation for wet gas parameter calculation, software in the Microsoft Office Excel environment is being developed.

Systematic and statistical uncertainties in simulated r-process abundances due to uncertain nuclear masses

DOE PAGES

Surman, Rebecca; Mumpower, Matthew; McLaughlin, Gail

2017-02-27

Unknown nuclear masses are a major source of nuclear physics uncertainty for r-process nucleosynthesis calculations. Here we examine the systematic and statistical uncertainties that arise in r-process abundance predictions due to uncertainties in the masses of nuclear species on the neutron-rich side of stability. There is a long history of examining systematic uncertainties by the application of a variety of different mass models to r-process calculations. Here we expand upon such efforts by examining six DFT mass models, where we capture the full impact of each mass model by updating the other nuclear properties — including neutron capture rates, β-decaymore » lifetimes, and β-delayed neutron emission probabilities — that depend on the masses. Unlike systematic effects, statistical uncertainties in the r-process pattern have just begun to be explored. Here we apply a global Monte Carlo approach, starting from the latest FRDM masses and considering random mass variations within the FRDM rms error. Here, we find in each approach that uncertain nuclear masses produce dramatic uncertainties in calculated r-process yields, which can be reduced in upcoming experimental campaigns.« less

Systematic and statistical uncertainties in simulated r-process abundances due to uncertain nuclear masses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Surman, Rebecca; Mumpower, Matthew; McLaughlin, Gail

Unknown nuclear masses are a major source of nuclear physics uncertainty for r-process nucleosynthesis calculations. Here we examine the systematic and statistical uncertainties that arise in r-process abundance predictions due to uncertainties in the masses of nuclear species on the neutron-rich side of stability. There is a long history of examining systematic uncertainties by the application of a variety of different mass models to r-process calculations. Here we expand upon such efforts by examining six DFT mass models, where we capture the full impact of each mass model by updating the other nuclear properties — including neutron capture rates, β-decaymore » lifetimes, and β-delayed neutron emission probabilities — that depend on the masses. Unlike systematic effects, statistical uncertainties in the r-process pattern have just begun to be explored. Here we apply a global Monte Carlo approach, starting from the latest FRDM masses and considering random mass variations within the FRDM rms error. Here, we find in each approach that uncertain nuclear masses produce dramatic uncertainties in calculated r-process yields, which can be reduced in upcoming experimental campaigns.« less

Discrete element modeling of the mass movement and loose material supplying the gully process of a debris avalanche in the Bayi Gully, Southwest China

NASA Astrophysics Data System (ADS)

Zhou, Jia-wen; Huang, Kang-xin; Shi, Chong; Hao, Ming-hui; Guo, Chao-xu

2015-03-01

The dynamic process of a debris avalanche in mountainous areas is influenced by the landslide volume, topographical conditions, mass-material composition, mechanical properties and other factors. A good understanding of the mass movement and loose material supplying the gully process is very important for understanding the dynamic properties of debris avalanches. Three-dimensional particle flow code (PFC3D) was used to simulate a debris avalanche in Quaternary deposits at the Bayi Gully, Southwest China. FORTRAN and AutoCAD were used for the secondary development to display the mass movement process and to quantitatively describe the mass movement and loose material supplying the gully process. The simulated results show that after the landslide is initiated, the gravitational potential energy is converted into kinetic energy with a variation velocity for the sliding masses. Two stages exist for the average-movement velocity: the acceleration stage and the slowdown stage, which are influenced by the topographical conditions. For the loose materials supplying the gully process, the cumulative volume of the sliding masses into the gully gradually increases over the time. When the landslide volume is not large enough, the increasing landslide volume does not obviously influence the movement process of the sliding masses. The travel distance and movement velocity increase with the decreasing numerical parameters, and the mass-movement process is finished more quickly using low-value parameters. The deposition area of the sliding masses decreases with the increasing numerical parameters and the corresponding deposition thickness increases. The mass movement of the debris avalanche is not only influenced by the mechanical parameters but is also controlled by the topographical conditions.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, Donald F.; Schulz, Carl; Konijnenburg, Marco

High-resolution Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry imaging enables the spatial mapping and identification of biomolecules from complex surfaces. The need for long time-domain transients, and thus large raw file sizes, results in a large amount of raw data (“big data”) that must be processed efficiently and rapidly. This can be compounded by largearea imaging and/or high spatial resolution imaging. For FT-ICR, data processing and data reduction must not compromise the high mass resolution afforded by the mass spectrometer. The continuous mode “Mosaic Datacube” approach allows high mass resolution visualization (0.001 Da) of mass spectrometry imaging data, butmore » requires additional processing as compared to featurebased processing. We describe the use of distributed computing for processing of FT-ICR MS imaging datasets with generation of continuous mode Mosaic Datacubes for high mass resolution visualization. An eight-fold improvement in processing time is demonstrated using a Dutch nationally available cloud service.« less

Comprehensive Mass Analysis for Chemical Processes, a Case Study on L-Dopa Manufacture

EPA Science Inventory

To evaluate the “greenness” of chemical processes in route selection and process development, we propose a comprehensive mass analysis to inform the stakeholders from different fields. This is carried out by characterizing the mass intensity for each contributing chemical or wast...

Impact of individual nuclear masses on r -process abundances

DOE PAGES

Mumpower, M. R.; Surman, R.; Fang, D. -L.; ...

2015-09-15

We have performed for the first time a comprehensive study of the sensitivity of r-process nucleosynthesis to individual nuclear masses across the chart of nuclides. Using the latest version (2012) of the Finite-Range Droplet Model, we consider mass variations of ±0.5 MeV and propagate each mass change to all affected quantities, including Q values, reaction rates, and branching ratios. We find such mass variations can result in up to an order of magnitude local change in the final abundance pattern produced in an r-process simulation. As a result, we identify key nuclei whose masses have a substantial impact on abundancemore » predictions for hot, cold, and neutron star merger r-process scenarios and could be measured at future radioactive beam facilities.« less

40 CFR 98.123 - Calculating GHG emissions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... mass balance approach to estimate your fluorinated GHG emissions from a process, you must ensure that... relative errors associated with using the mass balance approach on that process using Equations L-1 through... mass-balance approach to estimate emissions from the process if this calculation results in an absolute...

40 CFR 98.123 - Calculating GHG emissions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... mass balance approach to estimate your fluorinated GHG emissions from a process, you must ensure that... relative errors associated with using the mass balance approach on that process using Equations L-1 through... mass-balance approach to estimate emissions from the process if this calculation results in an absolute...

40 CFR 98.123 - Calculating GHG emissions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... mass balance approach to estimate your fluorinated GHG emissions from a process, you must ensure that... relative errors associated with using the mass balance approach on that process using Equations L-1 through... mass-balance approach to estimate emissions from the process if this calculation results in an absolute...

40 CFR 98.123 - Calculating GHG emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... mass balance approach to estimate your fluorinated GHG emissions from a process, you must ensure that... relative errors associated with using the mass balance approach on that process using Equations L-1 through... mass-balance approach to estimate emissions from the process if this calculation results in an absolute...

Mass Communications Students' Motivations: The Case of Kuwait

ERIC Educational Resources Information Center

Alkazemi, Mariam F.; Al Nashmi, Eisa; Wanta, Wayne

2017-01-01

Kuwaiti students intending to major in mass communication face a long process that begins in high school. A survey of students at Kuwait University examined whether the process led to disillusionment of the mass communication field and/or mass communication education. Findings show that all respondents viewed the field of journalism positively.…

Is there an aerosol signature of aqueous processing?

NASA Astrophysics Data System (ADS)

Ervens, B.; Sorooshian, A.

2017-12-01

The formation of aerosol mass in cloud water has been recognized as a substantial source of atmospheric aerosol mass. While sulfate formation can be relatively well constrained, the formation of secondary organic aerosol mass in the aqueous phase (aqSOA) is much more complex due to the multitude of precursors and variety in chemical processes. Aqueous phase processing adds aerosol mass to the droplet mode, which is formed due to mass addition to activated particles in clouds. In addition, it has been shown that aqSOA mass has specific characteristics in terms of oxidation state and hygroscopicity that might help to distinguish it from other SOA sources. Many models do not include detailed chemical mechanisms of sulfate and aqSOA formation and also lack details on the mass distribution of newly formed mass. Mass addition inside and outside clouds modifies different parts of an aerosol population and consequently affects predictions of properties and lifetime of particles. Using a combination of field data analysis and model studies for a variety of air masses, we will show which chemical and physical aerosol properties can be used, in order to identify an `aqueous phase signature' in processed aerosol populations. We will discuss differences in this signature in clean (e.g., background), moderately polluted (e.g., urban) and highly polluted (e.g., biomass burning) air masses and suggest air-mass-specific chemical and/or physical properties that will help to quantify the aqueous-phase derived aerosol mass.

Investigations of effect of phase change mass transfer rate on cavitation process with homogeneous relaxation model

DOE Office of Scientific and Technical Information (OSTI.GOV)

He, Zhixia; Zhang, Liang; Saha, Kaushik

The super high fuel injection pressure and micro size of nozzle orifice has been an important development trend for the fuel injection system. Accordingly, cavitation transient process, fuel compressibility, amount of noncondensable gas in the fuel and cavitation erosion have attracted more attention. Based on the fact of cavitation in itself is a kind of thermodynamic phase change process, this paper takes the perspective of the cavitation phase change mass transfer process to analyze above mentioned phenomenon. The two-phase cavitating turbulent flow simulations with VOF approach coupled with HRM cavitation model and U-RANS of standard k-ε turbulence model were performedmore » for investigations of cavitation phase change mass transfer process. It is concluded the mass transfer time scale coefficient in the Homogenous Relaxation Model (HRM) representing mass transfer rate should tend to be as small as possible in a condition that ensured the solver stable. At very fast mass transfer rate, the phase change occurs at very thin interface between liquid and vapor phase and condensation occurs more focused and then will contribute predictably to a more serious cavitation erosion. Both the initial non-condensable gas in fuel and the fuel compressibility can accelerate the cavitation mass transfer process.« less

Impacts of Process and Prediction Uncertainties on Projected Hanford Waste Glass Amount

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gervasio, Vivianaluxa; Vienna, John D.; Kim, Dong-Sang

Analyses were performed to evaluate the impacts of using the advanced glass models, constraints (Vienna et al. 2016), and uncertainty descriptions on projected Hanford glass mass. The maximum allowable WOL was estimated for waste compositions while simultaneously satisfying all applicable glass property and composition constraints with sufficient confidence. Different components of prediction and composition/process uncertainties were systematically included in the calculations to evaluate their impacts on glass mass. The analyses estimated the production of 23,360 MT of IHLW glass when no uncertainties were taken into accound. Accounting for prediction and composition/process uncertainties resulted in 5.01 relative percent increase in estimatedmore » glass mass 24,531 MT. Roughly equal impacts were found for prediction uncertainties (2.58 RPD) and composition/process uncertainties (2.43 RPD). ILAW mass was predicted to be 282,350 MT without uncertainty and with weaste loading “line” rules in place. Accounting for prediction and composition/process uncertainties resulted in only 0.08 relative percent increase in estimated glass mass of 282,562 MTG. Without application of line rules the glass mass decreases by 10.6 relative percent (252,490 MT) for the case with no uncertainties. Addition of prediction uncertainties increases glass mass by 1.32 relative percent and the addition of composition/process uncertainties increase glass mass by an additional 7.73 relative percent (9.06 relative percent increase combined). The glass mass estimate without line rules (275,359 MT) was 2.55 relative percent lower than that with the line rules (282,562 MT), after accounting for all applicable uncertainties.« less

Gas sampling system for a mass spectrometer

DOEpatents

Taylor, Charles E; Ladner, Edward P

2003-12-30

The present invention relates generally to a gas sampling system, and specifically to a gas sampling system for transporting a hazardous process gas to a remotely located mass spectrometer. The gas sampling system includes a capillary tube having a predetermined capillary length and capillary diameter in communication with the supply of process gas and the mass spectrometer, a flexible tube surrounding and coaxial with the capillary tube intermediate the supply of process gas and the mass spectrometer, a heat transfer tube surrounding and coaxial with the capillary tube, and a heating device in communication the heat transfer tube for substantially preventing condensation of the process gas within the capillary tube.

Mass, energy and material balances of SRF production process. Part 1: SRF produced from commercial and industrial waste.

PubMed

Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne

2014-08-01

This paper presents the mass, energy and material balances of a solid recovered fuel (SRF) production process. The SRF is produced from commercial and industrial waste (C&IW) through mechanical treatment (MT). In this work various streams of material produced in SRF production process are analyzed for their proximate and ultimate analysis. Based on this analysis and composition of process streams their mass, energy and material balances are established for SRF production process. Here mass balance describes the overall mass flow of input waste material in the various output streams, whereas material balance describes the mass flow of components of input waste stream (such as paper and cardboard, wood, plastic (soft), plastic (hard), textile and rubber) in the various output streams of SRF production process. A commercial scale experimental campaign was conducted on an MT waste sorting plant to produce SRF from C&IW. All the process streams (input and output) produced in this MT plant were sampled and treated according to the CEN standard methods for SRF: EN 15442 and EN 15443. The results from the mass balance of SRF production process showed that of the total input C&IW material to MT waste sorting plant, 62% was recovered in the form of SRF, 4% as ferrous metal, 1% as non-ferrous metal and 21% was sorted out as reject material, 11.6% as fine fraction, and 0.4% as heavy fraction. The energy flow balance in various process streams of this SRF production process showed that of the total input energy content of C&IW to MT plant, 75% energy was recovered in the form of SRF, 20% belonged to the reject material stream and rest 5% belonged with the streams of fine fraction and heavy fraction. In the material balances, mass fractions of plastic (soft), plastic (hard), paper and cardboard and wood recovered in the SRF stream were 88%, 70%, 72% and 60% respectively of their input masses to MT plant. A high mass fraction of plastic (PVC), rubber material and non-combustibles (such as stone/rock and glass particles), was found in the reject material stream. Copyright © 2014 Elsevier Ltd. All rights reserved.

Number size distribution of fine and ultrafine fume particles from various welding processes.

PubMed

Brand, Peter; Lenz, Klaus; Reisgen, Uwe; Kraus, Thomas

2013-04-01

Studies in the field of environmental epidemiology indicate that for the adverse effect of inhaled particles not only particle mass is crucial but also particle size is. Ultrafine particles with diameters below 100 nm are of special interest since these particles have high surface area to mass ratio and have properties which differ from those of larger particles. In this paper, particle size distributions of various welding and joining techniques were measured close to the welding process using a fast mobility particle sizer (FMPS). It turned out that welding processes with high mass emission rates (manual metal arc welding, metal active gas welding, metal inert gas welding, metal inert gas soldering, and laser welding) show mainly agglomerated particles with diameters above 100 nm and only few particles in the size range below 50 nm (10 to 15%). Welding processes with low mass emission rates (tungsten inert gas welding and resistance spot welding) emit predominantly ultrafine particles with diameters well below 100 nm. This finding can be explained by considerably faster agglomeration processes in welding processes with high mass emission rates. Although mass emission is low for tungsten inert gas welding and resistance spot welding, due to the low particle size of the fume, these processes cannot be labeled as toxicologically irrelevant and should be further investigated.

1995 R&D 100 Award Winners (One General Article and Five Feature Articles).

DTIC Science & Technology

1995-01-01

progress in the fields of aerogels , lasers, mass spectrometry, and electron beam processing. 14. SUBJECT TERMS SERDP, aerogels , lasers, mass...year’s awards were given to six teams of Laboratory ■dentists who made major progress in the fields of aerogels , asers, mass spectrometry, and electron...beam processing. Dne is a shared award for two aerogel processes: • A new injection molding process for aerogels was leveloped that is similar to

Examination of the mass media process and personal factors affecting the assessment of mass media-disseminated health information.

PubMed

Avcı, Kadriye; Çakır, Tülin; Avşar, Zakir; Üzel Taş, Hanife

2015-06-01

This study examined the mass media and personal characteristics leading to health communication inequality as well as the role of certain factors in health communication's mass media process. Using both sociodemographic variables and Maletzke's model as a basis, we investigated the relationship between selected components of the mass communication process, the receiving of reliable health information as a result of health communication, and the condition of its use. The study involved 1853 people in Turkey and was structured in two parts. The first part dealt with questions regarding sociodemographic characteristics, the use of the mass media and the public's ability to obtain health information from it, the public's perception of the trustworthiness of health information, and the state of translating this information into health-promoting behaviours. In the second part, questions related to the mass communication process were posed using a five-point Likert scale. This section tried to establish structural equation modelling using the judgements prepared on the basis of the mass media model. Through this study, it has been observed that sociodemographic factors such as education and age affect individuals' use of and access to communication channels; individuals' trust in and selection of health information from the programme content and their changing health behaviours (as a result of the health information) are related to both their perception of the mass communication process and to sociodemographic factors, but are more strongly related to the former. © The Author(s) 2014.

Impacts of Process and Prediction Uncertainties on Projected Hanford Waste Glass Amount

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gervasio, V.; Kim, D. S.; Vienna, J. D.

Analyses were performed to evaluate the impacts of using the advanced glass models, constraints, and uncertainty descriptions on projected Hanford glass mass. The maximum allowable waste oxide loading (WOL) was estimated for waste compositions while simultaneously satisfying all applicable glass property and composition constraints with sufficient confidence. Different components of prediction and composition/process uncertainties were systematically included in the calculations to evaluate their impacts on glass mass. The analyses estimated the production of 23,360 MT of immobilized high-level waste (IHLW) glass when no uncertainties were taken into account. Accounting for prediction and composition/process uncertainties resulted in 5.01 relative percent increasemore » in estimated glass mass of 24,531 MT. Roughly equal impacts were found for prediction uncertainties (2.58 RPD) and composition/process uncertainties (2.43 RPD). The immobilized low-activity waste (ILAW) mass was predicted to be 282,350 MT without uncertainty and with waste loading “line” rules in place. Accounting for prediction and composition/process uncertainties resulted in only 0.08 relative percent increase in estimated glass mass of 282,562 MT. Without application of line rules the glass mass decreases by 10.6 relative percent (252,490 MT) for the case with no uncertainties. Addition of prediction uncertainties increases glass mass by 1.32 relative percent and the addition of composition/process uncertainties increase glass mass by an additional 7.73 relative percent (9.06 relative percent increase combined). The glass mass estimate without line rules (275,359 MT) was 2.55 relative percent lower than that with the line rules (282,562 MT), after accounting for all applicable uncertainties.« less

Cold fission description with constant and varying mass asymmetries

NASA Astrophysics Data System (ADS)

Duarte, S. B.; Rodríguez, O.; Tavares, O. A. P.; Gonçalves, M.; García, F.; Guzmán, F.

1998-05-01

Different descriptions for varying the mass asymmetry in the fragmentation process are used to calculate the cold fission barrier penetrability. The relevance of the appropriate choice for both the description of the prescission phase and inertia coefficient to unify alpha decay, cluster radioactivity, and spontaneous cold fission processes in the same theoretical framework is explicitly shown. We calculate the half-life of all possible partition modes of nuclei of A>200 following the most recent Mass Table by Audi and Wapstra. It is shown that if one uses the description in which the mass asymmetry is maintained constant during the fragmentation process, the experimental half-life values and mass yield of 234U cold fission are satisfactorily reproduced.

Enhancement of MS Signal Processing For Improved Cancer Biomarker Discovery

NASA Astrophysics Data System (ADS)

Si, Qian

Technological advances in proteomics have shown great potential in detecting cancer at the earliest stages. One way is to use the time of flight mass spectroscopy to identify biomarkers, or early disease indicators related to the cancer. Pattern analysis of time of flight mass spectra data from blood and tissue samples gives great hope for the identification of potential biomarkers among the complex mixture of biological and chemical samples for the early cancer detection. One of the keys issues is the pre-processing of raw mass spectra data. A lot of challenges need to be addressed: unknown noise character associated with the large volume of data, high variability in the mass spectroscopy measurements, and poorly understood signal background and so on. This dissertation focuses on developing statistical algorithms and creating data mining tools for computationally improved signal processing for mass spectrometry data. I have introduced an advanced accurate estimate of the noise model and a half-supervised method of mass spectrum data processing which requires little knowledge about the data.

Mass, energy and material balances of SRF production process. Part 2: SRF produced from construction and demolition waste.

PubMed

Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne

2014-11-01

In this work, the fraction of construction and demolition waste (C&D waste) complicated and economically not feasible to sort out for recycling purposes is used to produce solid recovered fuel (SRF) through mechanical treatment (MT). The paper presents the mass, energy and material balances of this SRF production process. All the process streams (input and output) produced in MT waste sorting plant to produce SRF from C&D waste are sampled and treated according to CEN standard methods for SRF. Proximate and ultimate analysis of these streams is performed and their composition is determined. Based on this analysis and composition of process streams their mass, energy and material balances are established for SRF production process. By mass balance means the overall mass flow of input waste material stream in the various output streams and material balances mean the mass flow of components of input waste material stream (such as paper and cardboard, wood, plastic (soft), plastic (hard), textile and rubber) in the various output streams of SRF production process. The results from mass balance of SRF production process showed that of the total input C&D waste material to MT waste sorting plant, 44% was recovered in the form of SRF, 5% as ferrous metal, 1% as non-ferrous metal, and 28% was sorted out as fine fraction, 18% as reject material and 4% as heavy fraction. The energy balance of this SRF production process showed that of the total input energy content of C&D waste material to MT waste sorting plant, 74% was recovered in the form of SRF, 16% belonged to the reject material and rest 10% belonged to the streams of fine fraction and heavy fraction. From the material balances of this process, mass fractions of plastic (soft), paper and cardboard, wood and plastic (hard) recovered in the SRF stream were 84%, 82%, 72% and 68% respectively of their input masses to MT plant. A high mass fraction of plastic (PVC) and rubber material was found in the reject material stream. Streams of heavy fraction and fine fraction mainly contained non-combustible material (such as stone/rock, sand particles and gypsum material). Copyright © 2014 Elsevier Ltd. All rights reserved.

Proposal for an astronaut mass measurement device for the Space Shuttle

NASA Technical Reports Server (NTRS)

Beyer, Neil; Lomme, Jon; Mccollough, Holly; Price, Bradford; Weber, Heidi

1994-01-01

For medical reasons, astronauts in space need to have their mass measured. Currently, this measurement is performed using a mass-spring system. The current system is large, inaccurate, and uncomfortable for the astronauts. NASA is looking for new, different, and preferably better ways to perform this measurement process. After careful analysis our design team decided on a linear acceleration process. Within the process, four possible concept variants are put forth. Among these four variants, one is suggested over the others. The variant suggested is that of a motor-winch system to linearly accelerate the astronaut. From acceleration and force measurements of the process combined Newton's second law, the mass of an astronaut can be calculated.

Simulation of mass storage systems operating in a large data processing facility

NASA Technical Reports Server (NTRS)

Holmes, R.

1972-01-01

A mass storage simulation program was written to aid system designers in the design of a data processing facility. It acts as a tool for measuring the overall effect on the facility of on-line mass storage systems, and it provides the means of measuring and comparing the performance of competing mass storage systems. The performance of the simulation program is demonstrated.

A Synthetic Model of Mass Persuasion.

ERIC Educational Resources Information Center

Kneupper, Charles W.; Underwood, Willard A.

Mass persuasion involves a message production process which significantly alters or reinforces an attitude, belief, or action of the members of a large, heterogeneous audience. A synthetic communication model for mass persuasion has been constructed which incorporates aspects of several models created to describe the process of effective…

Massing in high shear wet granulation can simultaneously improve powder flow and deteriorate powder compaction: a double-edged sword.

PubMed

Shi, Limin; Feng, Yushi; Sun, Changquan Calvin

2011-05-18

The influence of massing during high shear wet granulation (HSWG) process on granule properties and performance was investigated using microcrystalline cellulose (MCC). Massing time varied from 0 to 40 min while other factors were fixed. Granule physical properties, including morphology, size, porosity, and specific surface area (SSA), were characterized. Changes in powder properties were profound in the first 10 min of massing but negligible beyond 10 min. With 10 min of massing, granule tabletability decreased by 75% while flowability increased by 75%. The significantly deteriorated tabletability and improved flowability resulted from dramatic changes in granule morphology, porosity, and SSA. The results confirm that massing time is a key process parameter in HSWG, and it must be carefully evaluated and controlled during process development, scale up, and manufacturing. Copyright © 2011 Elsevier B.V. All rights reserved.

THE OBSERVED RELATION BETWEEN STELLAR MASS, DUST EXTINCTION, AND STAR FORMATION RATE IN LOCAL GALAXIES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zahid, H. J.; Kewley, L. J.; Kudritzki, R. P.

In this study, we investigate the relation between stellar mass, dust extinction, and star formation rate (SFR) using {approx}150,000 star-forming galaxies from SDSS DR7. We show that the relation between dust extinction and SFR changes with stellar mass. For galaxies at the same stellar mass, dust extinction is anti-correlated with the SFR at stellar masses <10{sup 10} M {sub Sun }. There is a sharp transition in the relation at a stellar mass of 10{sup 10} M {sub Sun }. At larger stellar masses, dust extinction is positively correlated with the SFR for galaxies at the same stellar mass. Themore » observed relation between stellar mass, dust extinction, and SFR presented in this study helps to confirm similar trends observed in the relation between stellar mass, metallicity, and SFR. The relation reported in this study provides important new constraints on the physical processes governing the chemical evolution of galaxies. The correlation between SFR and dust extinction for galaxies with stellar masses >10{sup 10} M {sub Sun} is shown to extend to the population of quiescent galaxies suggesting that the physical processes responsible for the observed relation between stellar mass, dust extinction, and SFR may be related to the processes leading to the shutdown of star formation in galaxies.« less

High temperature abatement of acid gases from waste incineration. Part II: Comparative life cycle assessment study.

PubMed

Biganzoli, Laura; Racanella, Gaia; Marras, Roberto; Rigamonti, Lucia

2015-01-01

The performances of a new dolomitic sorbent, named Depurcal®MG, to be directly injected at high temperature in the combustion chamber of Waste-To-Energy (WTE) plants as a preliminary stage of deacidification, were experimentally tested during full-scale commercial operation. Results of the experimentations were promising, and have been extensively described in Biganzoli et al. (2014). This paper reports the Life Cycle Assessment (LCA) study performed to compare the traditional operation of the plants, based on the sole sodium bicarbonate feeding at low temperature, with the new one, where the dolomitic sorbent is injected at high temperature. In the latter the sodium bicarbonate is still used, but at lower rate because of the decreased load of acid gases entering the flue gas treatment line. The major goal of the LCA was to make sure that a burden shifting was not taking place somewhere in the life cycle stages, as it might be the case when a new material is used in substitution of another one. According to the comparative approach, only the processes which differ between the two operational modes were included in the system boundaries. They are the production of the two reactants and the treatment of the corresponding solid residues arising from the neutralisation of acid gases. The additional CO2 emission at the stack of the WTE plant due to the activation of the sodium bicarbonate was also included in the calculation. Data used in the modelling of the foreground system are primary, derived from the experimental tests described in Biganzoli et al. (2014) and from the dolomitic sorbent production plant. The results of the LCA show minor changes in the potential impacts between the two operational modes of the plants. These differences are for 8 impact categories in favour of the new operational mode based on the addition of the dolomitic sorbent, and for 7 impact categories in favour of the traditional operation. A final evaluation was conducted on the potential role of the dolomitic sorbent in enhancing the electric energy production efficiency of the plant, thanks to the better cleaning of the heat exchange surface that can be achieved. If such improvement is accounted for, all the potential impacts are considerably decreased (e.g. the Climate change by 28%), and in the comparison with the traditional operation 17 impact categories out of 19 are reduced. Copyright © 2014 Elsevier Ltd. All rights reserved.

MassCascade: Visual Programming for LC-MS Data Processing in Metabolomics.

PubMed

Beisken, Stephan; Earll, Mark; Portwood, David; Seymour, Mark; Steinbeck, Christoph

2014-04-01

Liquid chromatography coupled to mass spectrometry (LC-MS) is commonly applied to investigate the small molecule complement of organisms. Several software tools are typically joined in custom pipelines to semi-automatically process and analyse the resulting data. General workflow environments like the Konstanz Information Miner (KNIME) offer the potential of an all-in-one solution to process LC-MS data by allowing easy integration of different tools and scripts. We describe MassCascade and its workflow plug-in for processing LC-MS data. The Java library integrates frequently used algorithms in a modular fashion, thus enabling it to serve as back-end for graphical front-ends. The functions available in MassCascade have been encapsulated in a plug-in for the workflow environment KNIME, allowing combined use with e.g. statistical workflow nodes from other providers and making the tool intuitive to use without knowledge of programming. The design of the software guarantees a high level of modularity where processing functions can be quickly replaced or concatenated. MassCascade is an open-source library for LC-MS data processing in metabolomics. It embraces the concept of visual programming through its KNIME plug-in, simplifying the process of building complex workflows. The library was validated using open data.

Innovative application of the moisture analyzer for determination of dry mass content of processed cheese

NASA Astrophysics Data System (ADS)

Kowalska, Małgorzata; Janas, Sławomir; Woźniak, Magdalena

2018-04-01

The aim of this work was the presentation of an alternative method of determination of the total dry mass content in processed cheese. The authors claim that the presented method can be used in industry's quality control laboratories for routine testing and for quick in-process control. For the test purposes both reference method of determination of dry mass in processed cheese and moisture analyzer method were used. The tests were carried out for three different kinds of processed cheese. In accordance with the reference method, the sample was placed on a layer of silica sand and dried at the temperature of 102 °C for about 4 h. The moisture analyzer test required method validation, with regard to drying temperature range and mass of the analyzed sample. Optimum drying temperature of 110 °C was determined experimentally. For Hochland cream processed cheese sample, the total dry mass content, obtained using the reference method, was 38.92%, whereas using the moisture analyzer method, it was 38.74%. An average analysis time in case of the moisture analyzer method was 9 min. For the sample of processed cheese with tomatoes, the reference method result was 40.37%, and the alternative method result was 40.67%. For the sample of cream processed cheese with garlic the reference method gave value of 36.88%, and the alternative method, of 37.02%. An average time of those determinations was 16 min. Obtained results confirmed that use of moisture analyzer is effective. Compliant values of dry mass content were obtained for both of the used methods. According to the authors, the fact that the measurement took incomparably less time for moisture analyzer method, is a key criterion of in-process control and final quality control method selection.

A Method to Estimate the Masses of Asymptotic Giant Branch Variable Stars

NASA Astrophysics Data System (ADS)

Takeuti, Mine; Nakagawa, Akiharu; Kurayama, Tomoharu; Honma, Mareki

2013-06-01

AGB variable stars are at the transient phase between low and high mass-loss rates; estimating the masses of these stars is necessary to study the evolutionary processes and mass-loss processes during the AGB stage. We applied the pulsation constant theoretically derived by Xiong and Deng (2007 MNRAS, 378, 1270) to 15 galactic AGB stars in order to estimate their masses. We found that using the pulsation constant is effective to estimate the mass of a star pulsating with two different pulsation modes, such as S Crt and RX Boo, which provides mass estimates comparable to theoretical results of AGB star evolution. We also extended the use of the pulsation constant to single-mode variables, and analyzed the properties of AGB stars related to their masses.

Mirion--a software package for automatic processing of mass spectrometric images.

PubMed

Paschke, C; Leisner, A; Hester, A; Maass, K; Guenther, S; Bouschen, W; Spengler, B

2013-08-01

Mass spectrometric imaging (MSI) techniques are of growing interest for the Life Sciences. In recent years, the development of new instruments employing ion sources that are tailored for spatial scanning allowed the acquisition of large data sets. A subsequent data processing, however, is still a bottleneck in the analytical process, as a manual data interpretation is impossible within a reasonable time frame. The transformation of mass spectrometric data into spatial distribution images of detected compounds turned out to be the most appropriate method to visualize the results of such scans, as humans are able to interpret images faster and easier than plain numbers. Image generation, thus, is a time-consuming and complex yet very efficient task. The free software package "Mirion," presented in this paper, allows the handling and analysis of data sets acquired by mass spectrometry imaging. Mirion can be used for image processing of MSI data obtained from many different sources, as it uses the HUPO-PSI-based standard data format imzML, which is implemented in the proprietary software of most of the mass spectrometer companies. Different graphical representations of the recorded data are available. Furthermore, automatic calculation and overlay of mass spectrometric images promotes direct comparison of different analytes for data evaluation. The program also includes tools for image processing and image analysis.

The 300 Area Integrated Field Research Challenge Quality Assurance Project Plan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fix, N. J.

Pacific Northwest National Laboratory and a group of expert collaborators are using the U.S. Department of Energy Hanford Site 300 Area uranium plume within the footprint of the 300-FF-5 groundwater operable unit as a site for an Integrated Field-Scale Subsurface Research Challenge (IFRC). The IFRC is entitled Multi-Scale Mass Transfer Processes Controlling Natural Attenuation and Engineered Remediation: An IFRC Focused on the Hanford Site 300 Area Uranium Plume Project. The theme is investigation of multi-scale mass transfer processes. A series of forefront science questions on mass transfer are posed for research that relate to the effect of spatial heterogeneities; themore » importance of scale; coupled interactions between biogeochemical, hydrologic, and mass transfer processes; and measurements/approaches needed to characterize and model a mass transfer-dominated system. This Quality Assurance Project Plan provides the quality assurance requirements and processes that will be followed by the 300 Area IFRC Project. This plan is designed to be used exclusively by project staff.« less

Microphysical processing of aerosol particles in orographic clouds

NASA Astrophysics Data System (ADS)

Pousse-Nottelmann, S.; Zubler, E. M.; Lohmann, U.

2015-01-01

An explicit and detailed treatment of cloud-borne particles allowing for the consideration of aerosol cycling in clouds has been implemented in the regional weather forecast and climate model COSMO. The effects of aerosol scavenging, cloud microphysical processing and regeneration upon cloud evaporation on the aerosol population and on subsequent cloud formation are investigated. For this, two-dimensional idealized simulations of moist flow over two bell-shaped mountains were carried out varying the treatment of aerosol scavenging and regeneration processes for a warm-phase and a mixed-phase orographic cloud. The results allowed to identify different aerosol cycling mechanisms. In the simulated non-precipitating warm-phase cloud, aerosol mass is incorporated into cloud droplets by activation scavenging and released back to the atmosphere upon cloud droplet evaporation. In the mixed-phase cloud, a first cycle comprises cloud droplet activation and evaporation via the Wegener-Bergeron-Findeisen process. A second cycle includes below-cloud scavenging by precipitating snow particles and snow sublimation and is connected to the first cycle via the riming process which transfers aerosol mass from cloud droplets to snow flakes. In the simulated mixed-phase cloud, only a negligible part of the total aerosol mass is incorporated into ice crystals. Sedimenting snow flakes reaching the surface remove aerosol mass from the atmosphere. The results show that aerosol processing and regeneration lead to a vertical redistribution of aerosol mass and number. However, the processes not only impact the total aerosol number and mass, but also the shape of the aerosol size distributions by enhancing the internally mixed/soluble accumulation mode and generating coarse mode particles. Concerning subsequent cloud formation at the second mountain, accounting for aerosol processing and regeneration increases the cloud droplet number concentration with possible implications for the ice crystal number concentration.

The mass-ratio and eccentricity distributions of barium and S stars, and red giants in open clusters

NASA Astrophysics Data System (ADS)

Van der Swaelmen, M.; Boffin, H. M. J.; Jorissen, A.; Van Eck, S.

2017-01-01

Context. A complete set of orbital parameters for barium stars, including the longest orbits, has recently been obtained thanks to a radial-velocity monitoring with the HERMES spectrograph installed on the Flemish Mercator telescope. Barium stars are supposed to belong to post-mass-transfer systems. Aims: In order to identify diagnostics distinguishing between pre- and post-mass-transfer systems, the properties of barium stars (more precisely their mass-function distribution and their period-eccentricity (P-e) diagram) are compared to those of binary red giants in open clusters. As a side product, we aim to identify possible post-mass-transfer systems among the cluster giants from the presence of s-process overabundances. We investigate the relation between the s-process enrichment, the location in the (P-e) diagram, and the cluster metallicity and turn-off mass. Methods: To invert the mass-function distribution and derive the mass-ratio distribution, we used the method pioneered by Boffin et al. (1992) that relies on a Richardson-Lucy deconvolution algorithm. The derivation of s-process abundances in the open-cluster giants was performed through spectral synthesis with MARCS model atmospheres. Results: A fraction of 22% of post-mass-transfer systems is found among the cluster binary giants (with companion masses between 0.58 and 0.87 M⊙, typical for white dwarfs), and these systems occupy a wider area than barium stars in the (P-e) diagram. Barium stars have on average lower eccentricities at a given orbital period. When the sample of binary giant stars in clusters is restricted to the subsample of systems occupying the same locus as the barium stars in the (P-e) diagram, and with a mass function compatible with a WD companion, 33% (=4/12) show a chemical signature of mass transfer in the form of s-process overabundances (from rather moderate - about 0.3 dex - to more extreme - about 1 dex). The only strong barium star in our sample is found in the cluster with the lowest metallicity in the sample (I.e. star 173 in NGC 2420, with [Fe/H] = -0.26), whereas the barium stars with mild s-process abundance anomalies (from 0.25 to 0.6 dex) are found in the clusters with slightly subsolar metallicities. Our finding confirms the classical prediction that the s-process nucleosynthesis is more efficient at low metallicities, since the s-process overabundance is not clearly correlated with the cluster turn-off (TO) mass; such a correlation would instead hint at the importance of the dilution factor. We also find a mild barium star in NGC 2335, a cluster with a large TO mass of 4.3 M⊙, which implies that asymptotic giant branch stars that massive still operate the s-process and the third dredge-up. Based on observations made with the Mercator Telescope, operated on the island of La Palma by the Flemish Community, at the Spanish Observatorio del Roque de los Muchachos of the Instituto de Astrofisica de Canarias, and on observations made with the HARPS spectrograph installed on the 3.6 m telescope at the European Southern Observatory.

Mass Measurements beyond the Major r-Process Waiting Point {sup 80}Zn

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baruah, S.; Herlert, A.; Schweikhard, L.

2008-12-31

High-precision mass measurements on neutron-rich zinc isotopes {sup 71m,72-81}Zn have been performed with the Penning trap mass spectrometer ISOLTRAP. For the first time, the mass of {sup 81}Zn has been experimentally determined. This makes {sup 80}Zn the first of the few major waiting points along the path of the astrophysical rapid neutron-capture process where neutron-separation energy and neutron-capture Q-value are determined experimentally. The astrophysical conditions required for this waiting point and its associated abundance signatures to occur in r-process models can now be mapped precisely. The measurements also confirm the robustness of the N=50 shell closure for Z=30.

Mass measurements of neutron-deficient Y, Zr, and Nb isotopes and their impact on rp and νp nucleosynthesis processes

NASA Astrophysics Data System (ADS)

Xing, Y. M.; Li, K. A.; Zhang, Y. H.; Zhou, X. H.; Wang, M.; Litvinov, Yu. A.; Blaum, K.; Wanajo, S.; Kubono, S.; Martínez-Pinedo, G.; Sieverding, A.; Chen, R. J.; Shuai, P.; Fu, C. Y.; Yan, X. L.; Huang, W. J.; Xu, X.; Tang, X. D.; Xu, H. S.; Bao, T.; Chen, X. C.; Gao, B. S.; He, J. J.; Lam, Y. H.; Li, H. F.; Liu, J. H.; Ma, X. W.; Mao, R. S.; Si, M.; Sun, M. Z.; Tu, X. L.; Wang, Q.; Yang, J. C.; Yuan, Y. J.; Zeng, Q.; Zhang, P.; Zhou, X.; Zhan, W. L.; Litvinov, S.; Audi, G.; Uesaka, T.; Yamaguchi, Y.; Yamaguchi, T.; Ozawa, A.; Fröhlich, C.; Rauscher, T.; Thielemann, F.-K.; Sun, B. H.; Sun, Y.; Dai, A. C.; Xu, F. R.

2018-06-01

Using isochronous mass spectrometry at the experimental storage ring CSRe in Lanzhou, the masses of 82Zr and 84Nb were measured for the first time with an uncertainty of ∼10 keV, and the masses of 79Y, 81Zr, and 83Nb were re-determined with a higher precision. The latter are significantly less bound than their literature values. Our new and accurate masses remove the irregularities of the mass surface in this region of the nuclear chart. Our results do not support the predicted island of pronounced low α separation energies for neutron-deficient Mo and Tc isotopes, making the formation of Zr-Nb cycle in the rp-process unlikely. The new proton separation energy of 83Nb was determined to be 490(400) keV smaller than that in the Atomic Mass Evaluation 2012. This partly removes the overproduction of the p-nucleus 84Sr relative to the neutron-deficient molybdenum isotopes in the previous νp-process simulations.

Molecular dynamic approach to the study of the intense heat and mass transfer processes on the vapor-liquid interface

NASA Astrophysics Data System (ADS)

Levashov, V. Yu; Kamenov, P. K.

2017-10-01

The paper is devoted to research of the heat and mass transfer processes on the vapor-liquid interface. These processes can be realized for example at metal tempering, accidents at nuclear power stations, followed by the release of the corium into the heat carrier, getting hot magma into the water during volcanic eruptions and other. In all these examples the vapor film can arise on the heated body surface. In this paper the vapor film formation process will be considered with help of molecular dynamics simulation methods. The main attention during this process modeling will be focused on the subject of the fluid and vapor interactions with the heater surface. Another direction of this work is to study of the processes inside the droplet that may take place as result of impact of the high-power laser radiation. Such impact can lead to intensive evaporation and explosive destruction of the droplet. At that the duration of heat and mass transfer processes in droplet substance is tens of femtoseconds. Thus, the methods of molecular dynamics simulation can give the possibilities describe the heat and mass transfer processes in the droplet and the vapor phase formation.

The Link Between Rare-Earth Peak Formation and the Astrophysical Site of the R Process

DOE PAGES

Mumpower, Matthew R.; McLaughlin, Gail C.; Surman, Rebecca; ...

2016-12-20

The primary astrophysical source of the rare-earth elements is the rapid neutron capture process (r process). The rare-earth peak that is seen in the solar r-process residuals has been proposed to originate as a pile-up of nuclei during the end of the r process. Here, we introduce a new method utilizing Monte Carlo studies of nuclear masses in the rare-earth region, that includes self-consistently adjusting β-decay rates and neutron capture rates, to find the mass surfaces necessary for the formation of the rare-earth peak. We demonstrate our method with two types of astrophysical scenario, one corresponding to conditions typical ofmore » hot winds from core-collapse supernovae and stellar-mass accretion disks, and one corresponding to conditions typical of the ejection of the material from the tidal tails of neutron star mergers. In each type of astrophysical condition, this method successfully locates a region of enhanced stability in the mass surface that is responsible for the rare-earth peak. Finally, for each scenario, we find that the change in the mass surface has qualitatively different features, thus future measurements can shed light on the type of environment in which the r process occurred.« less

The Link Between Rare-Earth Peak Formation and the Astrophysical Site of the R Process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mumpower, Matthew R.; McLaughlin, Gail C.; Surman, Rebecca

The primary astrophysical source of the rare-earth elements is the rapid neutron capture process (r process). The rare-earth peak that is seen in the solar r-process residuals has been proposed to originate as a pile-up of nuclei during the end of the r process. Here, we introduce a new method utilizing Monte Carlo studies of nuclear masses in the rare-earth region, that includes self-consistently adjusting β-decay rates and neutron capture rates, to find the mass surfaces necessary for the formation of the rare-earth peak. We demonstrate our method with two types of astrophysical scenario, one corresponding to conditions typical ofmore » hot winds from core-collapse supernovae and stellar-mass accretion disks, and one corresponding to conditions typical of the ejection of the material from the tidal tails of neutron star mergers. In each type of astrophysical condition, this method successfully locates a region of enhanced stability in the mass surface that is responsible for the rare-earth peak. Finally, for each scenario, we find that the change in the mass surface has qualitatively different features, thus future measurements can shed light on the type of environment in which the r process occurred.« less

THE LINK BETWEEN RARE-EARTH PEAK FORMATION AND THE ASTROPHYSICAL SITE OF THE R PROCESS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mumpower, Matthew R.; McLaughlin, Gail C.; Surman, Rebecca

The primary astrophysical source of the rare-earth elements is the rapid neutron capture process ( r process). The rare-earth peak that is seen in the solar r -process residuals has been proposed to originate as a pile-up of nuclei during the end of the r process. We introduce a new method utilizing Monte Carlo studies of nuclear masses in the rare-earth region, that includes self-consistently adjusting β -decay rates and neutron capture rates, to find the mass surfaces necessary for the formation of the rare-earth peak. We demonstrate our method with two types of astrophysical scenario, one corresponding to conditionsmore » typical of hot winds from core-collapse supernovae and stellar-mass accretion disks, and one corresponding to conditions typical of the ejection of the material from the tidal tails of neutron star mergers. In each type of astrophysical condition, this method successfully locates a region of enhanced stability in the mass surface that is responsible for the rare-earth peak. For each scenario, we find that the change in the mass surface has qualitatively different features, thus future measurements can shed light on the type of environment in which the r process occurred.« less

A circumstellar disk associated with a massive protostellar object.

PubMed

Jiang, Zhibo; Tamura, Motohide; Fukagawa, Misato; Hough, Jim; Lucas, Phil; Suto, Hiroshi; Ishii, Miki; Yang, Ji

2005-09-01

The formation process for stars with masses several times that of the Sun is still unclear. The two main theories are mergers of several low-mass young stellar objects, which requires a high stellar density, or mass accretion from circumstellar disks in the same way as low-mass stars are formed, accompanied by outflows during the process of gravitational infall. Although a number of disks have been discovered around low- and intermediate-mass young stellar objects, the presence of disks around massive young stellar objects is still uncertain and the mass of the disk system detected around one such object, M17, is disputed. Here we report near-infrared imaging polarimetry that reveals an outflow/disk system around the Becklin-Neugebauer protostellar object, which has a mass of at least seven solar masses (M(o)). This strongly supports the theory that stars with masses of at least 7M(o) form in the same way as lower mass stars.

Of blind men and elephants: suggesting SDM-MASS as a compound measure for shared decision making integrating patient, physician and observer views.

PubMed

Geiger, Friedemann; Kasper, Jürgen

2012-01-01

Shared decision making (SDM) between patient and physician is an interpersonal process. Most SDM measures use the view of one party (patient, physician or observer) as a proxy to capture this process although these views typically diverge. This study suggests the compound measure SDM(MASS) (SDM Meeting its concept's ASSumptions) integrating these three perspectives in one single index. SDM(MASS) was derived theoretically and compared empirically to unilateral perspectives of patients, physicians and observers by application to a data set of 10 physicians (40 consultations) receiving an SDM training. The constituting parts of SDM(MASS) were highly reliable (Cronbach's alpha .94; interrater reliability .74-.87). Unilateral appraisal of training effects was divergent. SDM(MASS) revealed no effect. SDM(MASS) combines noteworthy information about SDM processes from different viewpoints and thereby delivers plausible assessments. It could overcome immanent shortcomings of unilateral approaches. However, it is a complex measure needing further validation. Copyright © 2012. Published by Elsevier GmbH.

Evolution of Mass Movements near Epicentre of Wenchuan Earthquake, the First Eight Years

PubMed Central

Zhang, Shuai; Zhang, Limin; Lacasse, Suzanne; Nadim, Farrokh

2016-01-01

It is increasingly clear that landslides represent a major cause of economic costs and deaths in earthquakes in mountains. In the Wenchuan earthquake case, post-seismic cascading landslides continue to represent a major problem eight years on. Failure to anticipate the impact of cascading landslides could lead to unexpected losses of human lives and properties. Previous studies tended to focus on separate landslide processes, with little attention paid to the quantification of long-term evolution of multiple processes or the evolution of mass movements. The very active mass movements near the epicentre of the Wenchuan earthquake provided us a unique opportunity to understand the complex processes of the evolving cascading landslides after a strong earthquake. This study budgets the mass movements on the hillslopes and in the channels in the first eight years since the Wenchuan earthquake and verify a conservation in mass movements. A system illustrating the evolution and interactions of mass movement after a strong earthquake is proposed. PMID:27824077

ISRU System Model Tool: From Excavation to Oxygen Production

NASA Technical Reports Server (NTRS)

Santiago-Maldonado, Edgardo; Linne, Diane L.

2007-01-01

In the late 80's, conceptual designs for an in situ oxygen production plant were documented in a study by Eagle Engineering [1]. In the "Summary of Findings" of this study, it is clearly pointed out that: "reported process mass and power estimates lack a consistent basis to allow comparison." The study goes on to say: "A study to produce a set of process mass, power, and volume requirements on a consistent basis is recommended." Today, approximately twenty years later, as humans plan to return to the moon and venture beyond, the need for flexible up-to-date models of the oxygen extraction production process has become even more clear. Multiple processes for the production of oxygen from lunar regolith are being investigated by NASA, academia, and industry. Three processes that have shown technical merit are molten regolith electrolysis, hydrogen reduction, and carbothermal reduction. These processes have been selected by NASA as the basis for the development of the ISRU System Model Tool (ISMT). In working to develop up-to-date system models for these processes NASA hopes to accomplish the following: (1) help in the evaluation process to select the most cost-effective and efficient process for further prototype development, (2) identify key parameters, (3) optimize the excavation and oxygen production processes, and (4) provide estimates on energy and power requirements, mass and volume of the system, oxygen production rate, mass of regolith required, mass of consumables, and other important parameters. Also, as confidence and high fidelity is achieved with each component's model, new techniques and processes can be introduced and analyzed at a fraction of the cost of traditional hardware development and test approaches. A first generation ISRU System Model Tool has been used to provide inputs to the Lunar Architecture Team studies.

Method for controlling clathrate hydrates in fluid systems

DOEpatents

Sloan, Jr., Earle D.

1995-01-01

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member and/or six member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone.

Biochemicals from food waste and recalcitrant biomass via syngas fermentation: A review.

PubMed

Wainaina, Steven; Horváth, Ilona Sárvári; Taherzadeh, Mohammad J

2018-01-01

An effective method for the production of value-added chemicals from food waste and lignocellulosic materials is a hybrid thermal-biological process, which involves gasification of the solid materials to syngas (primarily CO and H 2 ) followed by fermentation. This paper reviews the recent advances in this process. The special focus is on the cultivation methods that involve the use of single strains, defined mixed cultures and undefined mixed cultures for production of carboxylic acids and higher alcohols. A rate limiting step in these processes is the low mass transfer between the gas and the liquid phases. Therefore, novel techniques that can enhance the gas-liquid mass transfer including membrane- and trickle-bed bioreactors were discussed. Such bioreactors have shown promising results in increasing the volumetric mass transfer coefficient (k L a). High gas pressure also influences the mass transfer in certain batch processes, although the presence of impurities in the gas would impede the process. Copyright © 2017 Elsevier Ltd. All rights reserved.

Mass failures and other processes of sediment production in Pacific northwest forest landscapes

Treesearch

Frederick J. Swanson; Lee E. Benda; Stanley H. Duncan; Gordon E. Grant; Walter F. Megahan; Leslie M. Reid; Robert R. Ziemer

1987-01-01

Abstract - Accelerated sediment production by mass failures and other erosion processes is an important link between management of forest resources and fish resources. Dominant processes and the rates of sediment production vary greatly throughout the Pacific Northwest in response to geologic and climatic factors. The complex sediment routing systems characteristic...

Advanced Heat/Mass Exchanger Technology for Geothermal and Solar Renewable Energy Systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Greiner, Miles; Childress, Amy; Hiibel, Sage

2014-12-16

Northern Nevada has abundant geothermal and solar energy resources, and these renewable energy sources provide an ample opportunity to produce economically viable power. Heat/mass exchangers are essential components to any energy conversion system. Improvements in the heat/mass exchange process will lead to smaller, less costly (more efficient) systems. There is an emerging heat transfer technology, based on micro/nano/molecular-scale surface science that can be applied to heat/mass exchanger design. The objective is to develop and characterize unique coating materials, surface configurations and membranes capable of accommodating a 10-fold increase in heat/mass exchanger performance via phase change processes (boiling, condensation, etc.) andmore » single phase convective heat/mass transfer.« less

Mass, energy and material balances of SRF production process. Part 3: solid recovered fuel produced from municipal solid waste.

PubMed

Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne

2015-02-01

This is the third and final part of the three-part article written to describe the mass, energy and material balances of the solid recovered fuel production process produced from various types of waste streams through mechanical treatment. This article focused the production of solid recovered fuel from municipal solid waste. The stream of municipal solid waste used here as an input waste material to produce solid recovered fuel is energy waste collected from households of municipality. This article presents the mass, energy and material balances of the solid recovered fuel production process. These balances are based on the proximate as well as the ultimate analysis and the composition determination of various streams of material produced in a solid recovered fuel production plant. All the process streams are sampled and treated according to CEN standard methods for solid recovered fuel. The results of the mass balance of the solid recovered fuel production process showed that 72% of the input waste material was recovered in the form of solid recovered fuel; 2.6% as ferrous metal, 0.4% as non-ferrous metal, 11% was sorted as rejects material, 12% as fine faction and 2% as heavy fraction. The energy balance of the solid recovered fuel production process showed that 86% of the total input energy content of input waste material was recovered in the form of solid recovered fuel. The remaining percentage (14%) of the input energy was split into the streams of reject material, fine fraction and heavy fraction. The material balances of this process showed that mass fraction of paper and cardboard, plastic (soft) and wood recovered in the solid recovered fuel stream was 88%, 85% and 90%, respectively, of their input mass. A high mass fraction of rubber material, plastic (PVC-plastic) and inert (stone/rock and glass particles) was found in the reject material stream. © The Author(s) 2014.

Membrane device and process for mass exchange, separation, and filtration

DOEpatents

Liu, Wei; Canfield, Nathan L.

2016-11-15

A membrane device and processes for fabrication and for using are disclosed. The membrane device may include a number of porous metal membranes that provide a high membrane surface area per unit volume. The membrane device provides various operation modes that enhance throughput and selectivity for mass exchange, mass transfer, separation, and/or filtration applications between feed flow streams and permeate flow streams.

Coronoid process and residual ankylotic mass as an autograft in the management of ankylosis of the temporomandibular joint in young adolescent patients: a retrospective clinical investigation.

PubMed

Bansal, Vishal; Mowar, Apoorva; Dubey, Prajesh; Bhatnagar, Aditi; Bansal, Avi

2016-04-01

The aim of this non-randomised investigation was to assess the feasibility of using autogenous grafts (such as coronoid process and the resected ankylotic mass) in reconstruction of the condyle after gap arthroplasty for ankylosis of the temporomandibular joint (TMJ). Sixteen patients (23 joints) operated on between 2007 and 2009 were studied and postoperative measurements of maximum interincisal opening, bite force, range of movement, and infection were recorded. After a mean (SD) follow up of 55 (2.25) months mouth opening improved from 3 (3.84) mm to 33 (1.66) mm in patients treated with coronoid graft, while in patients treated with an ankylotic mass after a mean (SD) follow up of 58 (1.58) months it increased from 4 (2.64) mm to 26 (8.04) mm. Bite force six months postoperatively ranged from 18.25kg/cm(2) - 27.5kg/cm(2) after reconstruction with the coronoid process and 18.5kg/cm(2) - 23.25kg/cm(2) after reconstruction with the ankylotic mass. One patient developed reankylosis postoperatively and another developed infection, in both of which the ankylotic mass had been used. Both were managed successfully. Both the ankylotic mass and the coronoid process gave satisfactory results and seem to be options for reconstruction. However, the coronoid process graft was better than residual ankylotic mass in terms of masticatory efficiency, bite force, and range of movement. Copyright © 2016 The British Association of Oral and Maxillofacial Surgeons. Published by Elsevier Ltd. All rights reserved.

Jupiter Formation, Life in the Slow Lane?

NASA Astrophysics Data System (ADS)

Hamilton, D. P.; Kortenkamp, S. J.; Fleming, H. J.

2000-10-01

The growth of Jupiter, as predicted by the favored core-accretion model of planetary formation, is a two-stage process. First an ≈ 10 Earth mass core is formed by runaway growth of an icy protoplanet, after which the protoplanet gravitationally captures over 300 Earth masses of gas directly from the Solar Nebula. The process is thought to take ≈ 107 years. An alternate possibility, the mass-instability hypothesis, has recently experienced a resurgence of interest due to the increasingly rapid discoveries of unusual jovian-mass extrasolar planets. A sufficiently massive gas disk can become unstable and form an azimuthally asymmetric blob destined to become a giant planet in as short as 102 years. Which process actually formed Jupiter? Trojan asteroids, very numerous and with close dynamical links to Jupiter, are ideally suited to provide critical clues about Jupiter's formation. A number of processes could potentially capture objects into 1:1 resonance with Jupiter including radial migration, gas drag, mass accretion, collisional emplacement, disk tides, and gravitational scattering by massive protoplanetary embryos. We are currently undertaking a systematic study of each of these processes. The mass-instability scenario, in its simplest form, posits a fully-formed Jupiter with L4 and L5 points clear of gas and unpopulated with Trojans. By contrast, in the core-accretion model, precursor material is already trapped in 1:1 resonance with the jovian core. Furthermore, subsequent mass accretion and gas drag systematically concentrate matter toward the L4 and L5 points. The emerging theme is that a populous Trojan region is more easily achieved by the slower core-accretion model.

[Study on the dynamic model with supercritical CO2 fluid extracting the lipophilic components in Panax notoginseng].

PubMed

Duan, Xian-Chun; Wang, Yong-Zhong; Zhang, Jun-Ru; Luo, Huan; Zhang, Heng; Xia, Lun-Zhu

2011-08-01

To establish a dynamics model for extracting the lipophilic components in Panax notoginseng with supercritical carbon dioxide (CO2). Based on the theory of counter-flow mass transfer and the molecular mass transfer between the material and the supercritical CO2 fluid under differential mass-conservation equation, a dynamics model was established and computed to compare forecasting result with the experiment process. A dynamics model has been established for supercritical CO2 to extract the lipophilic components in Panax notoginseng, the computed result of this model was consistent with the experiment process basically. The supercritical fluid extract dynamics model established in this research can expound the mechanism in the extract process of which lipophilic components of Panax notoginseng dissolve the mass transfer and is tallied with the actual extract process. This provides certain instruction for the supercritical CO2 fluid extract' s industrialization enlargement.

Greenland Ice Sheet seasonal and spatial mass variability from model simulations and GRACE (2003-2012)

NASA Astrophysics Data System (ADS)

Alexander, Patrick M.; Tedesco, Marco; Schlegel, Nicole-Jeanne; Luthcke, Scott B.; Fettweis, Xavier; Larour, Eric

2016-06-01

Improving the ability of regional climate models (RCMs) and ice sheet models (ISMs) to simulate spatiotemporal variations in the mass of the Greenland Ice Sheet (GrIS) is crucial for prediction of future sea level rise. While several studies have examined recent trends in GrIS mass loss, studies focusing on mass variations at sub-annual and sub-basin-wide scales are still lacking. At these scales, processes responsible for mass change are less well understood and modeled, and could potentially play an important role in future GrIS mass change. Here, we examine spatiotemporal variations in mass over the GrIS derived from the Gravity Recovery and Climate Experiment (GRACE) satellites for the January 2003-December 2012 period using a "mascon" approach, with a nominal spatial resolution of 100 km, and a temporal resolution of 10 days. We compare GRACE-estimated mass variations against those simulated by the Modèle Atmosphérique Régionale (MAR) RCM and the Ice Sheet System Model (ISSM). In order to properly compare spatial and temporal variations in GrIS mass from GRACE with model outputs, we find it necessary to spatially and temporally filter model results to reproduce leakage of mass inherent in the GRACE solution. Both modeled and satellite-derived results point to a decline (of -178.9 ± 4.4 and -239.4 ± 7.7 Gt yr-1 respectively) in GrIS mass over the period examined, but the models appear to underestimate the rate of mass loss, especially in areas below 2000 m in elevation, where the majority of recent GrIS mass loss is occurring. On an ice-sheet-wide scale, the timing of the modeled seasonal cycle of cumulative mass (driven by summer mass loss) agrees with the GRACE-derived seasonal cycle, within limits of uncertainty from the GRACE solution. However, on sub-ice-sheet-wide scales, some areas exhibit significant differences in the timing of peaks in the annual cycle of mass change. At these scales, model biases, or processes not accounted for by models related to ice dynamics or hydrology, may lead to the observed differences. This highlights the need for further evaluation of modeled processes at regional and seasonal scales, and further study of ice sheet processes not accounted for, such as the role of subglacial hydrology in variations in glacial flow.

Devices with extended area structures for mass transfer processing of fluids

DOEpatents

TeGrotenhuis, Ward E.; Wegeng, Robert S.; Whyatt, Greg A.; King, David L.; Brooks, Kriston P.; Stenkamp, Victoria S.

2009-04-21

A microchannel device includes several mass transfer microchannels to receive a fluid media for processing at least one heat transfer microchannel in fluid communication with a heat transfer fluid defined by a thermally conductive wall, and at several thermally conductive fins each connected to the wall and extending therefrom to separate the mass transfer microchannels from one another. In one form, the device may optionally include another heat transfer microchannel and corresponding wall that is positioned opposite the first wall and has the fins and the mass transfer microchannels extending therebetween.

Measurements of the center-of-mass energies at BESIII via the di-muon process

DOE PAGES

Ablikim, M.; Achasov, M. N.; Ai, X. C.; ...

2016-06-01

From 2011 to 2014, the BESIII experiment collected about 5 fb -1 data at center-of-mass energies around 4 GeV for the studies of the charmonium-like and higher excited charmonium states. By analyzing the di-muon process e +e - → γ ISR/FSRμ +μ -, the center-of-mass energies of the data samples are measured with a precision of 0.8 MeV. The center-of-mass energy is found to be stable for most of the time during data taking.

Preliminary System Analysis of In Situ Resource Utilization for Mars Human Exploration

NASA Technical Reports Server (NTRS)

Rapp, Donald; Andringa, Jason; Easter, Robert; Smith, Jeffrey H .; Wilson, Thomas; Clark, D. Larry; Payne, Kevin

2005-01-01

We carried out a system analysis of processes for utilization of Mars resources to support human exploration of Mars by production of propellants from indigenous resources. Seven ISRU processes were analyzed to determine mass. power and propellant storage volume requirements. The major elements of each process include C02 acquisition, chemical conversion, and storage of propellants. Based on a figure of merit (the ratio of the mass of propellants that must be brought from Earth in a non-ISRU mission to the mass of the ISRU system. tanks and feedstocks that must be brought from Earth for a ISRU mission) the most attractive process (by far); is one where indigenous Mars water is accessible and this is processed via Sabatier/Electrolysis to methane and oxygen. These processes are technically relatively mature. Other processes with positive leverage involve reverse water gas shift and solid oxide electrolysis.

VizieR Online Data Catalog: Atomic mass excesses (Schatz+, 2017)

NASA Astrophysics Data System (ADS)

Schatz, H.; Ong, W.-J.

2018-03-01

X-ray burst model predictions of light curves and the final composition of the nuclear ashes are affected by uncertain nuclear masses. However, not all of these masses are determined experimentally with sufficient accuracy. Here we identify the remaining nuclear mass uncertainties in X-ray burst models using a one-zone model that takes into account the changes in temperature and density evolution caused by changes in the nuclear physics. Two types of bursts are investigated-a typical mixed H/He burst with a limited rapid proton capture process (rp-process) and an extreme mixed H/He burst with an extended rp-process. When allowing for a 3σ variation, only three remaining nuclear mass uncertainties affect the light-curve predictions of a typical H/He burst (27P, 61Ga, and 65As), and only three additional masses affect the composition strongly (80Zr, 81Zr, and 82Nb). A larger number of mass uncertainties remain to be addressed for the extreme H/He burst, with the most important being 58Zn, 61Ga, 62Ge, 65As, 66Se, 78Y, 79Y, 79Zr, 80Zr, 81Zr, 82Zr, 82Nb, 83Nb, 86Tc, 91Rh, 95Ag, 98Cd, 99In, 100In, and 101In. The smallest mass uncertainty that still impacts composition significantly when varied by 3σ is 85Mo with 16keV uncertainty. For one of the identified masses, 27P, we use the isobaric mass multiplet equation to improve the mass uncertainty, obtaining an atomic mass excess of -716(7)keV. The results provide a roadmap for future experiments at advanced rare isotope beam facilities, where all the identified nuclides are expected to be within reach for precision mass measurements. (1 data file).

Pre-processing liquid chromatography/high-resolution mass spectrometry data: extracting pure mass spectra by deconvolution from the invariance of isotopic distribution.

PubMed

Krishnan, Shaji; Verheij, Elwin E R; Bas, Richard C; Hendriks, Margriet W B; Hankemeier, Thomas; Thissen, Uwe; Coulier, Leon

2013-05-15

Mass spectra obtained by deconvolution of liquid chromatography/high-resolution mass spectrometry (LC/HRMS) data can be impaired by non-informative mass-over-charge (m/z) channels. This impairment of mass spectra can have significant negative influence on further post-processing, like quantification and identification. A metric derived from the knowledge of errors in isotopic distribution patterns, and quality of the signal within a pre-defined mass chromatogram block, has been developed to pre-select all informative m/z channels. This procedure results in the clean-up of deconvoluted mass spectra by maintaining the intensity counts from m/z channels that originate from a specific compound/molecular ion, for example, molecular ion, adducts, (13) C-isotopes, multiply charged ions and removing all m/z channels that are not related to the specific peak. The methodology has been successfully demonstrated for two sets of high-resolution LC/MS data. The approach described is therefore thought to be a useful tool in the automatic processing of LC/HRMS data. It clearly shows the advantages compared to other approaches like peak picking and de-isotoping in the sense that all information is retained while non-informative data is removed automatically. Copyright © 2013 John Wiley & Sons, Ltd.

Study of the Rock Mass Failure Process and Mechanisms During the Transformation from Open-Pit to Underground Mining Based on Microseismic Monitoring

NASA Astrophysics Data System (ADS)

Zhao, Yong; Yang, Tianhong; Bohnhoff, Marco; Zhang, Penghai; Yu, Qinglei; Zhou, Jingren; Liu, Feiyue

2018-05-01

To quantitatively understand the failure process and failure mechanism of a rock mass during the transformation from open-pit mining to underground mining, the Shirengou Iron Mine was selected as an engineering project case study. The study area was determined using the rock mass basic quality classification method and the kinematic analysis method. Based on the analysis of the variations in apparent stress and apparent volume over time, the rock mass failure process was analyzed. According to the recent research on the temporal and spatial change of microseismic events in location, energy, apparent stress, and displacement, the migration characteristics of rock mass damage were studied. A hybrid moment tensor inversion method was used to determine the rock mass fracture source mechanisms, the fracture orientations, and fracture scales. The fracture area can be divided into three zones: Zone A, Zone B, and Zone C. A statistical analysis of the orientation information of the fracture planes orientations was carried out, and four dominant fracture planes were obtained. Finally, the slip tendency analysis method was employed, and the unstable fracture planes were obtained. The results show: (1) The microseismic monitoring and hybrid moment tensor analysis can effectively analyze the failure process and failure mechanism of rock mass, (2) during the transformation from open-pit to underground mining, the failure type of rock mass is mainly shear failure and the tensile failure is mostly concentrated in the roof of goafs, and (3) the rock mass of the pit bottom and the upper of goaf No. 18 have the possibility of further damage.

Effects of mass loading on dayside solar wind-magnetosphere interactions

NASA Astrophysics Data System (ADS)

Zhang, B.; Brambles, O.; Wiltberger, M. J.; Lyon, J.; Lotko, W.

2016-12-01

Satellite observations have shown that terrestrial-sourced plasmas mass load the dayside magnetopause and cause reductions in local reconnection rates. Whether the integrated dayside reconnection rate is affected by these local mass-loading processes is still an open question. Several mechanisms have been proposed to describe the control of dayside reconnection, including the local-control and global-control hypotheses. We have conducted a series of controlled numerical simulations to investigate the response of dayside solar wind-magnetopshere (SW-M) coupling to mass loading processes. Our simulation results show that the coupled SW-M system may exhibit both local and global control behaviors depending on the amount of mass loading. With a small amount of mass loading, the changes in the local reconnection rate does not affect magnetosheath properties and the geoeffective length in the upstream solar wind, resulting in the same integrated dayside reconnection rate. With a large amount of mass loading, the magnetosheath properties and the geoeffective length are significantly modified by slowing down the local reconnection rate, resulting in a significant reduction in the integrated dayside reconnection rate. The response of magnetosheath properties to mass loading is expected from the Cassak-Shay asymmetric reconnection theory through conservation of energy. The physical origin of the transition regime between local and global control is qualitatively explained. The parameters that determine the transition regime depend on the location, spatial extension and density of the mass loading process.

From Stars to Superplanets: The Low-Mass Initial Mass Function in the Young Cluster IC 348

DTIC Science & Technology

2000-10-01

both baryonic dark matter in the Galaxy and, perhaps more importantly, the formation processes governing stars, brown dwarfs, and planets. In the...on the role of physical processes such as fragmentation in the star and planet formation process and the fraction of dark matter in the Galactic halo

Ozone mass transfer behaviors on physical and chemical absorption for hollow fiber membrane contactors.

PubMed

Zhang, Yong; Li, Kuiling; Wang, Jun; Hou, Deyin; Liu, Huijuan

2017-09-01

To understand the mass transfer behaviors in hollow fiber membrane contactors, ozone fluxes affected by various conditions and membranes were investigated. For physical absorption, mass transfer rate increased with liquid velocity and the ozone concentration in the gas. Gas flow rate was little affected when the velocity was larger than the critical value, which was 6.1 × 10 -3 m/s in this study. For chemical absorption, the flux was determined by the reaction rate between ozone and the absorbent. Therefore, concentration, species, and pH affected the mass transfer process markedly. For different absorbents, the order of mass transfer rate was the same as the reaction rate constant, which was phenol, sodium nitrite, hydrogen peroxide, and oxalate. Five hydrophobic membranes with various properties were employed and the mass transfer behavior can be described by the Graetz-Lévèque equation for the physical absorption process. The results showed the process was controlled by liquid film and the gas phase conditions, and membrane properties did not affect the ozone flux. For the chemical absorption, gas film, membrane and liquid film affected the mass transfer together, and none of them were negligible.

Heat and mass transfer in wooden dowels during a simulated fire: an experimental and analytical study

Treesearch

J. A. Mardini; A. S. Lavine; V. K. Dhir

1996-01-01

Abstract--An experimental and analytical study of heat and mass transfer in wooden dowels during a simulated fire is presented in this paper. The goal of this study is to understand the processes of heat and mass transfer in wood during wildland fires. A mathematical model is developed to describe the processes of heating, drying and pyrolysis of wood until ignition...

Mass and Environment as Drivers of Galaxy Evolution: Simplicity and its Consequences

NASA Astrophysics Data System (ADS)

Peng, Yingjie

2012-01-01

The galaxy population appears to be composed of infinitely complex different types and properties at first sight, however, when large samples of galaxies are studied, it appears that the vast majority of galaxies just follow simple scaling relations and similar evolutional modes while the outliers represent some minority. The underlying simplicities of the interrelationships among stellar mass, star formation rate and environment are seen in SDSS and zCOSMOS. We demonstrate that the differential effects of mass and environment are completely separable to z 1, indicating that two distinct physical processes are operating, namely the "mass quenching" and "environment quenching". These two simple quenching processes, plus some additional quenching due to merging, then naturally produce the Schechter form of the galaxy stellar mass functions and make quantitative predictions for the inter-relationships between the Schechter parameters of star-forming and passive galaxies in different environments. All of these detailed quantitative relationships are indeed seen, to very high precision, in SDSS, lending strong support to our simple empirically-based model. The model also offers qualitative explanations for the "anti-hierarchical" age-mass relation and the alpha-enrichment patterns for passive galaxies and makes some other testable predictions such as the mass function of the population of transitory objects that are in the process of being quenched, the galaxy major- and minor-merger rates, the galaxy stellar mass assembly history, star formation history and etc. Although still purely phenomenological, the model makes clear what the evolutionary characteristics of the relevant physical processes must in fact be.

Influence of the boundary conditions on heat and mass transfer in spacer-filled channels

NASA Astrophysics Data System (ADS)

Ciofalo, M.; La Cerva, M. F.; Di Liberto, M.; Tamburini, A.

2017-11-01

The purpose of this study is to discuss some problems which arise in heat or mass transfer in complex channels, with special reference to the spacer-filled channels adopted in membrane processes. Among the issues addressed are the consistent definition of local and mean heat or mass transfer coefficients; the influence of the wall boundary conditions; the influence of one-side versus two-side heat/mass transfer. Most of the results discussed were obtained by finite volume CFD simulations concerning heat transfer in Membrane Distillation or mass transfer in Electrodialysis and Reverse Electrodialysis, but many of the conclusions apply also to different processes involving geometrically complex channels

Model-dependence of neutrino emissivities and neutrino luminosities of neutron stars from the direct Urca processes and the modified Urca processes

NASA Astrophysics Data System (ADS)

Yin, Peng; Fan, Xiaohua; Dong, Jianmin; Guo, Wenmei; Zuo, Wei

2017-05-01

The neutrino emissivities in β-stable neutron star matter from the direct Urca (DU) processes and the modified Urca (MU) processes have been investigated by adopting 26 Skyrme interactions. Several physical quantities related to the MU processes and the DU processes have been calculated and discussed. The model-dependence of the neutrino emissivities from the DU processes is found to stem mainly from the model-dependence of the effective mass, while the neutrino emissivities from the MU processes are determined by the competition between the effects of the symmetry energy and the effective mass. Besides, we have investigated the total neutrino luminosities of neutron stars, with the masses of 1.2 , 1.4 , 1.6 and 1.8M⊙, from the DU processes and the MU processes. The neutrino luminosity of a neutron star is found to be primarily determined by whether the electron DU process is allowed or not. As long as the electron DU process can occur, the total luminosity turns out to be 5 to 8 orders of magnitude larger as compared with the case that the DU process is forbidden, which indicates that the strongest model-dependence of the neutrino luminosity comes from that of the symmetry energy and the equation of state (EOS) of neutron star matter. In the case that the DU processes are allowed, the discrepancy of the calculated neutrino luminosity using various Skyrme interactions remains noticeable, which is essentially attributed to the model-dependence of the symmetry energy, the EOS of NS matter and the effective masses.

Fate of polychlorinated dibenzo-p-dioxins and dibenzofurans in a fly ash treatment plant.

PubMed

Li, Hsing-Wang; Wu, Yee-Lin; Lee, Wen-Jhy; Chang-Chien, Guo-Ping

2007-09-01

To understand the fate of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in a fly ash treatment plant that used the Waelz rotary kiln process (hereafter the Waelz process), the samples of input and output media were collected and analyzed. The most important PCDD/F source in input mass was electric arc furnace (EAF) fly ash, which had a mean PCDD/F content of 18.51 ng/g and contributed more than 99% of PCDD/F input mass, whereas the PCDD/F input mass fractions contributed by the coke, sand, and ambient air were only 0.04%, 0.02%, and 0.000002%, respectively. For the PCDD/F output mass in the Waelz process, the major total PCDD/F contents of 43.73 and 10.78 ng/g were in bag-filter and cyclone ashes, which accounted for approximately 69% and 17%, respectively, whereas those of stack flue gas and slag were 14% and 0.423%, respectively. The Waelz process has a dechlorination mechanism for higher chlorinated congeners, but it is difficult to decompose the aromatic rings of PCDD/Fs. Therefore, this resulted in the accumulation of lower chlorinated congeners. The output/input ratio of total PCDD/F mass and total PCDD/F international toxicity equivalence (I-TEQ) was 0.62 and 1.19, respectively. Thus, the Waelz process for the depletion effect of total PCDD/F mass was positive but minor, whereas the effect for total PCDD/F I-TEQ was adverse overall.

Alteration of glacigenic landforms by gravitational mass movements, Ragnarbreen and Ebbabreen, Svalbard

NASA Astrophysics Data System (ADS)

Ewertowski, Marek; Pleskot, Krzysztof; Tomczyk, Aleksandra

2015-04-01

The extensive recession of Svalbard's glaciers exposed areas containing large amount of dead-ice covered by relatively thin - usually less than a couple of meters - veneer of debris. This landscape can be very dynamic, mainly due to the mass movement processes and dead-ice melting. Continuous redistribution of sediments causes several phases of debris transfer and relief inversion. Hence, the primary glacial deposits released from ice are subsequently transferred by mass movement processes, until they finally reach more stable position. Investigations of dynamics of the mass movement and the way in which they alter the property of glacigenic sediments are therefore cruicial for proper understanding of sedimentary records of previous glaciations. The main objectives of this study were to: (1) quantify short-term dynamic of mass wasting processes; (2) investigate the transformation of the sediment's characteristic by mass wasting processes; (3) asses the contribution of different process to the overall dynamic of proglacial landscape. We focused on the mass-wasting processes in the forelands of two glaciers, Ebbabreen and Ragnarbreen, located near the Petuniabukta at the northern end of the Billefjorden, Spitsbergen. Repetitive topographic scanning was combined with sedimentological analysis of: grain size, clast shape in macro and micro scale and thin sections. Debris falls, slides, rolls and flows were the most important processes leading to reworking of glacigenic sediments and altering their properties. Contribution of different processes to the overall dynamic of the landforms was related mainly to the local conditions. Four different morphological types of sites were identified: (1) near vertical ice-cliffs covered with debris, transformed mainly due to dead-ice backwasting and debris falls and slides, (2) steep debris slopes with exposed ice-cores dominated by debris slides, (3) gentle sediment-mantled slopes transformed due to debris flows, and (4) non-active debris-mantled areas transformed only by dead-ice downwasting. The amount of volume loss due to the active mass movement processes and dead-ice melting (including both backwasting and downwasting) was up to more than 1.8 m a-1. In comparison, the amount of volume loss due to the dead-ice downwasting only was significantly lower at a maximum of 0.3 m a-1. The spatial and temporal distribution of volume changes, however, was quite diverse and for the most part related to local geomorphic conditions (e.g. slope gradient, occurrence of streams, and meltwater channels). We proposed a simplified model of spatio-temporal switching between stable and active conditions within the forelands of the studied glaciers. Transformations of landforms were attributed to the period of deglaciation and debris cover development. Stage 1 - shortly after deglaciation when the debris cover is thin (thinner than the permafrost active layer's thickness) mass movement processes become fairly common. They are facilitated by the dead-ice melting and steepness of the slopes. This stage can be observed in many lateral moraines, which are characterised by steep slopes, abundance of active mass movement processes, and by consequence a high degree of transformation. Stage 2 - ongoing mass-wasting processes lead to the transfer of sediments from steep slopes to more stable positions. As the thickness of the sediments increases, the debris cover starts to protect the dead-ice from melting and also contribute to the decrease in slope gradient. Thus, the resulting landscape is relatively stable and in equilibrium with current climatic and topographic conditions. This stage characterises most parts of the frontal (end) moraine complex of the studied glaciers; thus, their transformation rates are either very low or close to zero. Stage 3 - some parts of this stable landscape can be subsequently transformed again into an unstable state, mainly due to the effect of external factors such as streams or meltwater channels. This can lead to the development of mass movement processes and further slope instability, which could facilitate subsequent generation of debris flows. Stages described above can occur in a sort of spatio-temporal cycle, and, depending on local and external factors, the changes between stabilization of landforms and activation of mass flows can be repeated several times for any given area until the dead-ice is completely melted.

SwePep, a database designed for endogenous peptides and mass spectrometry.

PubMed

Fälth, Maria; Sköld, Karl; Norrman, Mathias; Svensson, Marcus; Fenyö, David; Andren, Per E

2006-06-01

A new database, SwePep, specifically designed for endogenous peptides, has been constructed to significantly speed up the identification process from complex tissue samples utilizing mass spectrometry. In the identification process the experimental peptide masses are compared with the peptide masses stored in the database both with and without possible post-translational modifications. This intermediate identification step is fast and singles out peptides that are potential endogenous peptides and can later be confirmed with tandem mass spectrometry data. Successful applications of this methodology are presented. The SwePep database is a relational database developed using MySql and Java. The database contains 4180 annotated endogenous peptides from different tissues originating from 394 different species as well as 50 novel peptides from brain tissue identified in our laboratory. Information about the peptides, including mass, isoelectric point, sequence, and precursor protein, is also stored in the database. This new approach holds great potential for removing the bottleneck that occurs during the identification process in the field of peptidomics. The SwePep database is available to the public.

Evaluating the potential for secondary mass savings in vehicle lightweighting.

PubMed

Alonso, Elisa; Lee, Theresa M; Bjelkengren, Catarina; Roth, Richard; Kirchain, Randolph E

2012-03-06

Secondary mass savings are mass reductions that may be achieved in supporting (load-bearing) vehicle parts when the gross vehicle mass (GVM) is reduced. Mass decompounding is the process by which it is possible to identify further reductions when secondary mass savings result in further reduction of GVM. Maximizing secondary mass savings (SMS) is a key tool for maximizing vehicle fuel economy. In today's industry, the most complex parts, which require significant design detail (and cost), are designed first and frozen while the rest of the development process progresses. This paper presents a tool for estimating SMS potential early in the design process and shows how use of the tool to set SMS targets early, before subsystems become locked in, maximizes mass savings. The potential for SMS in current passenger vehicles is estimated with an empirical model using engineering analysis of vehicle components to determine mass-dependency. Identified mass-dependent components are grouped into subsystems, and linear regression is performed on subsystem mass as a function of GVM. A Monte Carlo simulation is performed to determine the mean and 5th and 95th percentiles for the SMS potential per kilogram of primary mass saved. The model projects that the mean theoretical secondary mass savings potential is 0.95 kg for every 1 kg of primary mass saved, with the 5th percentile at 0.77 kg/kg when all components are available for redesign. The model was used to explore an alternative scenario where realistic manufacturing and design limitations were implemented. In this case study, four key subsystems (of 13 total) were locked-in and this reduced the SMS potential to a mean of 0.12 kg/kg with a 5th percentile of 0.1 kg/kg. Clearly, to maximize the impact of mass reduction, targets need to be established before subsystems become locked in.

Microphysical processing of aerosol particles in orographic clouds

NASA Astrophysics Data System (ADS)

Pousse-Nottelmann, S.; Zubler, E. M.; Lohmann, U.

2015-08-01

An explicit and detailed treatment of cloud-borne particles allowing for the consideration of aerosol cycling in clouds has been implemented into COSMO-Model, the regional weather forecast and climate model of the Consortium for Small-scale Modeling (COSMO). The effects of aerosol scavenging, cloud microphysical processing and regeneration upon cloud evaporation on the aerosol population and on subsequent cloud formation are investigated. For this, two-dimensional idealized simulations of moist flow over two bell-shaped mountains were carried out varying the treatment of aerosol scavenging and regeneration processes for a warm-phase and a mixed-phase orographic cloud. The results allowed us to identify different aerosol cycling mechanisms. In the simulated non-precipitating warm-phase cloud, aerosol mass is incorporated into cloud droplets by activation scavenging and released back to the atmosphere upon cloud droplet evaporation. In the mixed-phase cloud, a first cycle comprises cloud droplet activation and evaporation via the Wegener-Bergeron-Findeisen (WBF) process. A second cycle includes below-cloud scavenging by precipitating snow particles and snow sublimation and is connected to the first cycle via the riming process which transfers aerosol mass from cloud droplets to snowflakes. In the simulated mixed-phase cloud, only a negligible part of the total aerosol mass is incorporated into ice crystals. Sedimenting snowflakes reaching the surface remove aerosol mass from the atmosphere. The results show that aerosol processing and regeneration lead to a vertical redistribution of aerosol mass and number. Thereby, the processes impact the total aerosol number and mass and additionally alter the shape of the aerosol size distributions by enhancing the internally mixed/soluble Aitken and accumulation mode and generating coarse-mode particles. Concerning subsequent cloud formation at the second mountain, accounting for aerosol processing and regeneration increases the cloud droplet number concentration with possible implications for the ice crystal number concentration.

The topographic development and areal parametric characterization of a stratified surface polished by mass finishing

NASA Astrophysics Data System (ADS)

Walton, Karl; Blunt, Liam; Fleming, Leigh

2015-09-01

Mass finishing is amongst the most widely used finishing processes in modern manufacturing, in applications from deburring to edge radiusing and polishing. Processing objectives are varied, ranging from the cosmetic to the functionally critical. One such critical application is the hydraulically smooth polishing of aero engine component gas-washed surfaces. In this, and many other applications the drive to improve process control and finish tolerance is ever present. Considering its widespread use mass finishing has seen limited research activity, particularly with respect to surface characterization. The objectives of the current paper are to; characterise the mass finished stratified surface and its development process using areal surface parameters, provide guidance on the optimal parameters and sampling method to characterise this surface type for a given application, and detail the spatial variation in surface topography due to coupon edge shadowing. Blasted and peened square plate coupons in titanium alloy are wet (vibro) mass finished iteratively with increasing duration. Measurement fields are precisely relocated between iterations by fixturing and an image superimposition alignment technique. Surface topography development is detailed with ‘log of process duration’ plots of the ‘areal parameters for scale-limited stratified functional surfaces’, (the Sk family). Characteristic features of the Smr2 plot are seen to map out the processing of peak, core and dale regions in turn. These surface process regions also become apparent in the ‘log of process duration’ plot for Sq, where lower core and dale regions are well modelled by logarithmic functions. Surface finish (Ra or Sa) with mass finishing duration is currently predicted with an exponential model. This model is shown to be limited for the current surface type at a critical range of surface finishes. Statistical analysis provides a group of areal parameters including; Vvc, Sq, and Sdq, showing optimal discrimination for a specific range of surface finish outcomes. As a consequence of edge shadowing surface segregation is suggested for characterization purposes.

Characterization of simultaneous heat and mass transfer phenomena for water vapour condensation on a solid surface in an abiotic environment--application to bioprocesses.

PubMed

Tiwari, Akhilesh; Kondjoyan, Alain; Fontaine, Jean-Pierre

2012-07-01

The phenomenon of heat and mass transfer by condensation of water vapour from humid air involves several key concepts in aerobic bioreactors. The high performance of bioreactors results from optimised interactions between biological processes and multiphase heat and mass transfer. Indeed in various processes such as submerged fermenters and solid-state fermenters, gas/liquid transfer need to be well controlled, as it is involved at the microorganism interface and for the control of the global process. For the theoretical prediction of such phenomena, mathematical models require heat and mass transfer coefficients. To date, very few data have been validated concerning mass transfer coefficients from humid air inflows relevant to those bioprocesses. Our study focussed on the condensation process of water vapour and developed an experimental set-up and protocol to study the velocity profiles and the mass flux on a small size horizontal flat plate in controlled environmental conditions. A closed circuit wind tunnel facility was used to control the temperature, hygrometry and hydrodynamics of the flow. The temperature of the active surface was controlled and kept isothermal below the dew point to induce condensation, by the use of thermoelectricity. The experiments were performed at ambient temperature for a relative humidity between 35-65% and for a velocity of 1.0 ms⁻¹. The obtained data are analysed and compared to available theoretical calculations on condensation mass flux.

Explaining the Origins and Expansion of Mass Education.

ERIC Educational Resources Information Center

Boli, John; And Others

1985-01-01

Theories of mass education that emphasize processes of differentiation or the reproduction of inequalities ignore the universal and institutional character of mass education. A theoretical framework emphasizing individualism and the rationalization of individual and collective authority better explains the relationship of mass education to…

Nucleosynthesis Predictions for Intermediate-Mass AGB Stars: Comparison to Observations of Type I Planetary Nebulae

NASA Technical Reports Server (NTRS)

Karakas, Amanda I.; vanRaai, Mark A.; Lugaro, Maria; Sterling, Nicholas C.; Dinerstein, Harriet L.

2008-01-01

Type I planetary nebulae (PNe) have high He/H and N/O ratios and are thought to be descendants of stars with initial masses of approx. 3-8 Stellar Mass. These characteristics indicate that the progenitor stars experienced proton-capture nucleosynthesis at the base of the convective envelope, in addition to the slow neutron capture process operating in the He-shell (the s-process). We compare the predicted abundances of elements up to Sr from models of intermediate-mass asymptotic giant branch (AGB) stars to measured abundances in Type I PNe. In particular, we compare predictions and observations for the light trans-iron elements Se and Kr, in order to constrain convective mixing and the s-process in these stars. A partial mixing zone is included in selected models to explore the effect of a C-13 pocket on the s-process yields. The solar-metallicity models produce enrichments of [(Se, Kr)/Fe] less than or approx. 0.6, consistent with Galactic Type I PNe where the observed enhancements are typically less than or approx. 0.3 dex, while lower metallicity models predict larger enrichments of C, N, Se, and Kr. O destruction occurs in the most massive models but it is not efficient enough to account for the greater than or approx. 0.3 dex O depletions observed in some Type I PNe. It is not possible to reach firm conclusions regarding the neutron source operating in massive AGB stars from Se and Kr abundances in Type I PNe; abundances for more s-process elements may help to distinguish between the two neutron sources. We predict that only the most massive (M grester than or approx.5 Stellar Mass) models would evolve into Type I PNe, indicating that extra-mixing processes are active in lower-mass stars (3-4 Stellar Mass), if these stars are to evolve into Type I PNe.

SOA formation by biogenic and carbonyl compounds: data evaluation and application.

PubMed

Ervens, Barbara; Kreidenweis, Sonia M

2007-06-01

The organic fraction of atmospheric aerosols affects the physical and chemical properties of the particles and their role in the climate system. Current models greatly underpredict secondary organic aerosol (SOA) mass. Based on a compilation of literature studies that address SOA formation, we discuss different parameters that affect the SOA formation efficiency of biogenic compounds (alpha-pinene, isoprene) and aliphatic aldehydes (glyoxal, hexanal, octanal, hexadienal). Applying a simple model, we find that the estimated SOA mass after one week of aerosol processing under typical atmospheric conditions is increased by a few microg m(-3) (low NO(x) conditions). Acid-catalyzed reactions can create > 50% more SOA mass than processes under neutral conditions; however, other parameters such as the concentration ratio of organics/NO(x), relative humidity, and absorbing mass are more significant. The assumption of irreversible SOA formation not limited by equilibrium in the particle phase or by depletion of the precursor leads to unrealistically high SOA masses for some of the assumptions we made (surface vs volume controlled processes).

A new processing scheme for ultra-high resolution direct infusion mass spectrometry data

NASA Astrophysics Data System (ADS)

Zielinski, Arthur T.; Kourtchev, Ivan; Bortolini, Claudio; Fuller, Stephen J.; Giorio, Chiara; Popoola, Olalekan A. M.; Bogialli, Sara; Tapparo, Andrea; Jones, Roderic L.; Kalberer, Markus

2018-04-01

High resolution, high accuracy mass spectrometry is widely used to characterise environmental or biological samples with highly complex composition enabling the identification of chemical composition of often unknown compounds. Despite instrumental advancements, the accurate molecular assignment of compounds acquired in high resolution mass spectra remains time consuming and requires automated algorithms, especially for samples covering a wide mass range and large numbers of compounds. A new processing scheme is introduced implementing filtering methods based on element assignment, instrumental error, and blank subtraction. Optional post-processing incorporates common ion selection across replicate measurements and shoulder ion removal. The scheme allows both positive and negative direct infusion electrospray ionisation (ESI) and atmospheric pressure photoionisation (APPI) acquisition with the same programs. An example application to atmospheric organic aerosol samples using an Orbitrap mass spectrometer is reported for both ionisation techniques resulting in final spectra with 0.8% and 8.4% of the peaks retained from the raw spectra for APPI positive and ESI negative acquisition, respectively.

40 CFR 98.422 - GHGs to report.

Code of Federal Regulations, 2010 CFR

2010-07-01

... GREENHOUSE GAS REPORTING Suppliers of Carbon Dioxide § 98.422 GHGs to report. (a) Mass of CO2 captured from each production process unit. (b) Mass of CO2 extracted from each CO2 production wells. (c) Mass of CO2 imported. (d) Mass of CO2 exported. ...

Assessment of hydrothermal carbonization and coupling washing with torrefaction of bamboo sawdust for biofuels production.

PubMed

Zhang, Shuping; Su, Yinhai; Xu, Dan; Zhu, Shuguang; Zhang, Houlei; Liu, Xinzhi

2018-06-01

Two kinds of biofuels were produced and compared from hydrothermal carbonization (HTC) and coupling washing with torrefaction (CWT) processes of bamboo sawdust in this study. The mass and energy yields, mass energy density, fuel properties, structural characterizations, combustion behavior and ash behavior during combustion process were investigated. Significant increases in the carbon contents resulted in the improvement of mass energy density and fuel properties of biofuels obtained. Both HTC and CWT improved the safety of the biofuels during the process of handling, storing and transportation. The ash-related issues of the biofuels were significantly mitigated and combustion behavior was remarkably improved after HTC and CWT processes of bamboo sawdust. In general, both HTC and CWT processes are suitable to produce biofuels with high fuel quality from bamboo sawdust. Copyright © 2018 Elsevier Ltd. All rights reserved.

Occurrence of pharmaceuticals in a municipal wastewater treatment plant: mass balance and removal processes.

PubMed

Gao, Pin; Ding, Yunjie; Li, Hui; Xagoraraki, Irene

2012-06-01

Occurrence and removal efficiencies of fifteen pharmaceuticals were investigated in a conventional municipal wastewater treatment plant in Michigan. Concentrations of these pharmaceuticals were determined in both wastewater and sludge phases by a high-performance liquid chromatograph coupled to a tandem mass spectrometer. Detailed mass balance analysis was conducted during the whole treatment process to evaluate the contributing processes for pharmaceutical removal. Among the pharmaceuticals studied, demeclocycline, sulfamerazine, erythromycin and tylosin were not detected in the wastewater treatment plant influent. Other target pharmaceuticals detected in wastewater were also found in the corresponding sludge phase. The removal efficiencies of chlortetracycline, tetracycline, sulfamerazine, acetaminophen and caffeine were >99%, while doxycycline, oxytetracycline, sulfadiazine and lincomycin exhibited relatively lower removal efficiencies (e.g., <50%). For sulfamethoxazole, the removal efficiency was approximately 90%. Carbamazepine manifested a net increase of mass, i.e. 41% more than the input from the influent. Based on the mass balance analysis, biotransformation is believed to be the predominant process responsible for the removal of pharmaceuticals (22% to 99%), whereas contribution of sorption to sludge was relatively insignificant (7%) for the investigated pharmaceuticals. Copyright © 2012 Elsevier Ltd. All rights reserved.

Quantifying solute transport processes: are chemically "conservative" tracers electrically conservative?

USGS Publications Warehouse

Singha, Kamini; Li, Li; Day-Lewis, Frederick D.; Regberg, Aaron B.

2012-01-01

The concept of a nonreactive or conservative tracer, commonly invoked in investigations of solute transport, requires additional study in the context of electrical geophysical monitoring. Tracers that are commonly considered conservative may undergo reactive processes, such as ion exchange, thus changing the aqueous composition of the system. As a result, the measured electrical conductivity may reflect not only solute transport but also reactive processes. We have evaluated the impacts of ion exchange reactions, rate-limited mass transfer, and surface conduction on quantifying tracer mass, mean arrival time, and temporal variance in laboratory-scale column experiments. Numerical examples showed that (1) ion exchange can lead to resistivity-estimated tracer mass, velocity, and dispersivity that may be inaccurate; (2) mass transfer leads to an overestimate in the mobile tracer mass and an underestimate in velocity when using electrical methods; and (3) surface conductance does not notably affect estimated moments when high-concentration tracers are used, although this phenomenon may be important at low concentrations or in sediments with high and/or spatially variable cation-exchange capacity. In all cases, colocated groundwater concentration measurements are of high importance for interpreting geophysical data with respect to the controlling transport processes of interest.

Convective radiation fluid-dynamics: formation and early evolution of ultra low-mass objects

NASA Astrophysics Data System (ADS)

Wuchterl, G.

2005-12-01

The formation process of ultra low-mass objects is some kind of extension of the star formation process. The physical changes towards lower mass are discussed by investigating the collapse of cloud cores that are modelled as Bonnor-Ebert spheres. Their collapse is followed by solving the equations of fluid dynamics with radiation and a model of time-dependent convection that has been calibrated to the Sun. For a sequence of cloud-cores with 1 to 0.01 solar masses, evolutionary tracks and isochrones are shown in the mass-radius diagram, the Hertzsprung-Russel diagram and the effective temperature-surface gravity or Kiel diagram. The collapse and the early hydrostatic evolution to ages of few Ma are briefly discussed and compared to observations of objects in Upper Scorpius and the low-mass components of GG Tau.

The integrated contaminant elution and tracer test toolkit, ICET3, for improved characterization of mass transfer, attenuation, and mass removal

NASA Astrophysics Data System (ADS)

Brusseau, Mark L.; Guo, Zhilin

2018-01-01

It is evident based on historical data that groundwater contaminant plumes persist at many sites, requiring costly long-term management. High-resolution site-characterization methods are needed to support accurate risk assessments and to select, design, and operate effective remediation operations. Most subsurface characterization methods are generally limited in their ability to provide unambiguous, real-time delineation of specific processes affecting mass-transfer, transformation, and mass removal, and accurate estimation of associated rates. An integrated contaminant elution and tracer test toolkit, comprising a set of local-scale groundwater extraction-and injection tests, was developed to ameliorate the primary limitations associated with standard characterization methods. The test employs extended groundwater extraction to stress the system and induce hydraulic and concentration gradients. Clean water can be injected, which removes the resident aqueous contaminant mass present in the higher-permeability zones and isolates the test zone from the surrounding plume. This ensures that the concentrations and fluxes measured within the isolated area are directly and predominantly influenced by the local mass-transfer and transformation processes controlling mass removal. A suite of standard and novel tracers can be used to delineate specific mass-transfer and attenuation processes that are active at a given site, and to quantify the associated mass-transfer and transformation rates. The conceptual basis for the test is first presented, followed by an illustrative application based on simulations produced with a 3-D mathematical model and a brief case study application.

The complex fluid dynamics of simple diffusion

NASA Astrophysics Data System (ADS)

Vold, Erik

2017-11-01

Diffusion as the mass transport process responsible for mixing fluids at the atomic level is often underestimated in its complexity. An initial discontinuity between two species of different atomic masses exhibits a mass density discontinuity under isothermal pressure equilibrium implying equal species molar densities. The self-consistent kinetic transport processes across such an interface leads to a zero sum of mass flux relative to the center of mass and so diffusion alone cannot relax an initially stationary mass discontinuity nor broaden the density profile at the interface. The diffusive mixing leads to a molar imbalance which drives a center of mass velocity which moves the heavier species toward the lighter species leading to the interfacial density relaxation. Simultaneously, the species non-zero molar flux modifies the pressure profile in a transient wave and in a local perturbation. The resulting center of mass velocity has two components; one, associated with the divergence of the flow, persists in the diffusive mixing region throughout the diffusive mixing process, and two, travelling waves at the front of the pressure perturbations propagate away from the mixing region. The momentum in these waves is necessary to maintain momentum conservation in the center of mass frame. Thus, in a number of ways, the diffusive mixing provides feedback into the small scale advective motions. Numerical methods which diffuse all species assuming P-T equilibrium may not recover the subtle dynamics of mass transport at an interface. Work performed by the LANS, LLC, under USDOE Contract No. DE-AC52-06NA25396, funded by the (ASC) Program.

40 CFR 98.185 - Procedures for estimating missing data.

Code of Federal Regulations, 2010 CFR

2010-07-01

... facility that estimate annual process CO2 emissions using the carbon mass balance procedure in § 98.183(b... best available estimate of the mass of the material from all available process data or data used for accounting purposes (such as purchase records). ...

High-precision mass measurements for the rp-process at JYFLTRAP

NASA Astrophysics Data System (ADS)

Canete, Laetitia; Eronen, Tommi; Jokinen, Ari; Kankainen, Anu; Moore, Ian D.; Nesterenko, Dimitry; Rinta-Antila, Sami

2018-01-01

The double Penning trap JYFLTRAP at the University of Jyväskylä has been successfully used to achieve high-precision mass measurements of nuclei involved in the rapid proton-capture (rp) process. A precise mass measurement of 31Cl is essential to estimate the waiting point condition of 30S in the rp-process occurring in type I x-ray bursts (XRBs). The mass-excess of 31C1 measured at JYFLTRAP, -7034.7(3.4) keV, is 15 more precise than the value given in the Atomic Mass Evaluation 2012. The proton separation energy Sp determined from the new mass-excess value confirmed that 30S is a waiting point, with a lower-temperature limit of 0.44 GK. The mass of 52Co effects both 51Fe(p,γ)52Co and 52Co(p,γ)53Ni reactions. The mass-excess value measured, - 34 331.6(6.6) keV is 30 times more precise than the value given in AME2012. The Q values for the 51Fe(p,γ)52Co and 52Co(p,γ)53Ni reactions are now known with a high precision, 1418(11) keV and 2588(26) keV respectively. The results show that 52Co is more proton bound and 53Ni less proton bound than what was expected from the extrapolated value.

Mass Spectrometry: A Technique of Many Faces

PubMed Central

Olshina, Maya A.; Sharon, Michal

2016-01-01

Protein complexes form the critical foundation for a wide range of biological process, however understanding the intricate details of their activities is often challenging. In this review we describe how mass spectrometry plays a key role in the analysis of protein assemblies and the cellular pathways which they are involved in. Specifically, we discuss how the versatility of mass spectrometric approaches provides unprecedented information on multiple levels. We demonstrate this on the ubiquitin-proteasome proteolytic pathway, a process that is responsible for protein turnover. We follow the various steps of this degradation route and illustrate the different mass spectrometry workflows that were applied for elucidating molecular information. Overall, this review aims to stimulate the integrated use of multiple mass spectrometry approaches for analyzing complex biological systems. PMID:28100928

Dynamical Aspects of Quasifission Process in Heavy-Ion Reactions

NASA Astrophysics Data System (ADS)

Knyazheva, G. N.; Itkis, I. M.; Kozulin, E. M.

2015-06-01

The study of mass-energy distributions of binary fragments obtained in the reactions of 36S, 48Ca, 58Fe and 64Ni ions with the 232Th, 238U, 244Pu and 248Cm at energies below and above the Coulomb barrier is presented. For all the reactions the main component of the distributions corresponds to asymmetrical mass division typical for asymmetric quasifission process. To describe the quasifission mass distribution the simple method has been proposed. This method is based on the driving potential of the system and time dependent mass drift. This procedure allows to estimate QF time scale from the measured mass distributions. It has been found that the QF time exponentially decreases when the reaction Coulomb factor Z1Z2 increases.

Membrane protein separation and analysis by supercritical fluid chromatography-mass spectrometry.

PubMed

Zhang, Xu; Scalf, Mark; Westphall, Michael S; Smith, Lloyd M

2008-04-01

Membrane proteins comprise 25-30% of the human genome and play critical roles in a wide variety of important biological processes. However, their hydrophobic nature has compromised efforts at structural characterization by both X-ray crystallography and mass spectrometry. The detergents that are generally used to solubilize membrane proteins interfere with the crystallization process essential to X-ray studies and cause severe ion suppression effects that hinder mass spectrometric analysis. In this report, the use of supercritical fluid chromatography-mass spectrometry for the separation and analysis of integral membrane proteins and hydrophobic peptides is investigated. It is shown that detergents are rapidly and effectively separated from the proteins and peptides, yielding them in a state suitable for direct mass spectrometric analysis.

Modeling the chemistry of plasma polymerization using mass spectrometry.

PubMed

Ihrig, D F; Stockhaus, J; Scheide, F; Winkelhake, Oliver; Streuber, Oliver

2003-04-01

The goal of the project is a solvent free painting shop. The environmental technologies laboratory is developing processes of plasma etching and polymerization. Polymerized thin films are first-order corrosion protection and primer for painting. Using pure acetylene we get very nice thin films which were not bonded very well. By using air as bulk gas it is possible to polymerize, in an acetylene plasma, well bonded thin films which are stable first-order corrosion protections and good primers. UV/Vis spectroscopy shows nitrogen oxide radicals in the emission spectra of pure nitrogen and air. But nitrogen oxide is fully suppressed in the presence of acetylene. IR spectroscopy shows only C=O, CH(2) and CH(3) groups but no nitrogen species. With the aid of UV/Vis spectra and the chemistry of ozone formation it is possible to define reactive traps and steps, molecule depletion and processes of proton scavenging and proton loss. Using a numerical model it is possible to evaluate these processes and to calculate theoretical mass spectra. Adjustment of theoretical mass spectra to real measurements leads to specific channels of polymerization which are driven by radicals especially the acetyl radical. The estimated theoretical mass spectra show the specific channels of these chemical processes. It is possible to quantify these channels. This quantification represents the mass flow through this chemical system. With respect to these chemical processes it is possible to have an idea of pollutant production processes.

High-Precision Mass Measurement of Cu 56 and the Redirection of the r p -Process Flow

NASA Astrophysics Data System (ADS)

Valverde, A. A.; Brodeur, M.; Bollen, G.; Eibach, M.; Gulyuz, K.; Hamaker, A.; Izzo, C.; Ong, W.-J.; Puentes, D.; Redshaw, M.; Ringle, R.; Sandler, R.; Schwarz, S.; Sumithrarachchi, C. S.; Surbrook, J.; Villari, A. C. C.; Yandow, I. T.

2018-01-01

We report the mass measurement of Cu 56 , using the LEBIT 9.4 T Penning trap mass spectrometer at the National Superconducting Cyclotron Laboratory at Michigan State University. The mass of Cu 56 is critical for constraining the reaction rates of the Ni 55 (p ,γ ) Cu 56 (p ,γ ) Zn 57 (β+) Cu 57 bypass around the Ni 56 waiting point. Previous recommended mass excess values have disagreed by several hundred keV. Our new value, ME =-38 626.7 (7.1 ) keV , is a factor of 30 more precise than the extrapolated value suggested in the 2012 atomic mass evaluation [Chin. Phys. C 36, 1603 (2012), 10.1088/1674-1137/36/12/003], and more than a factor of 12 more precise than values calculated using local mass extrapolations, while agreeing with the newest 2016 atomic mass evaluation value [Chin. Phys. C 41, 030003 (2017), 10.1088/1674-1137/41/3/030003]. The new experimental average, using our new mass and the value from AME2016, is used to calculate the astrophysical Ni 55 (p ,γ ) and Cu 56 (p ,γ ) forward and reverse rates and perform reaction network calculations of the r p process. These show that the r p -process flow redirects around the Ni 56 waiting point through the Ni 55 (p ,γ ) route, allowing it to proceed to higher masses more quickly and resulting in a reduction in ashes around this waiting point and an enhancement to higher-mass ashes.

Factors influencing public risk-benefit considerations of nanotechnology: Assessing the effects of mass media, interpersonal communication, and elaborative processing.

PubMed

Ho, Shirley S; Scheufele, Dietram A; Corley, Elizabeth A

2013-07-01

This study examines the influence of mass media, interpersonal communication, and elaborative processing on public perception of benefits and risks of nanotechnology, based on a large-scale nationally representative telephone survey of U.S. adult citizens. Results indicate that cognitive processes in the form of news elaboration had a significant positive main effect on benefits outweigh risks perception. The influences of attention to science in newspapers, attention to science news on television, and interpersonal communication about science on public perception of benefits outweigh risks were moderated by elaborative processing, after controlling for socio-demographic variables, religious beliefs, trust in scientists, and scientific knowledge. The findings highlight the importance of elaborative processing when it comes to understanding how the mass media differentially influence public benefits outweigh risks perception of emerging technologies. Specifically, high elaborative processing emphasizes higher levels of perceived benefits outweigh risks than low elaborative processing. This study explores explanations for this phenomenon and offers implications for future research and policy.

VOLATILIZATION OF ALKYLBENZENES FROM WATER.

USGS Publications Warehouse

Rathbun, R.E.; Tai, D.Y.

1985-01-01

Volatilization is a physical process of importance in determining the fate of many organic compounds in streams and rivers. This process is frequently described by the conceptual-two-film model. The model assumes uniformly mixed water and air phases separated by thin films of water and air in which mass transfer is by molecular diffusion. Mass-transfer coefficients for the water and air films are related to an overall mass-transfer coefficient for volatilization through the Henry's law constant.

Hierarchical Galaxy Growth and Scatter in the Stellar Mass-Halo Mass Relation

NASA Astrophysics Data System (ADS)

Gu, Meng; Conroy, Charlie; Behroozi, Peter

2016-12-01

The relation between galaxies and dark matter halos reflects the combined effects of many distinct physical processes. Observations indicate that the z = 0 stellar mass-halo mass (SMHM) relation has remarkably small scatter in stellar mass at fixed halo mass (≲0.2 dex), with little dependence on halo mass. We investigate the origins of this scatter by combining N-body simulations with observational constraints on the SMHM relation. We find that at the group and cluster scale ({M}{vir}\\gt {10}14 {M}⊙ ) the scatter due purely to hierarchical assembly is ≈ 0.16 dex, which is comparable to recent direct observational estimates. At lower masses, mass buildup since z≈ 2 is driven largely by in situ growth. We include a model for the in situ buildup of stellar mass and find that an intrinsic scatter in this growth channel of 0.2 dex produces a relation between scatter and halo mass that is consistent with observations from {10}12 {M}⊙ \\lt {M}{vir}\\lt {10}14.75 {M}⊙ . The approximately constant scatter across a wide range of halo masses at z = 0 thus appears to be a coincidence, as it is determined largely by in situ growth at low masses and by hierarchical assembly at high masses. These results indicate that the scatter in the SMHM relation can provide unique insight into the regularity of the galaxy formation process.

Numerical modeling of heat and mass transport processes in an evaporative thermal protection system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bobrov, I.N.; Kuryachii, A.P.

1992-08-01

We propose a mathematical model of heat and mass transport processes in a moist, porous material subject to capillary action. The material is in contact with a heated surface, and the processes take place while the liquid is evaporating in a cavity with a drainage hole. A sample calculation based on the model is presented. 45 refs., 4 figs.

First observation of a mass independent isotopic fractionation in a condensation reaction

NASA Technical Reports Server (NTRS)

Thiemens, M. H.; Nelson, R.; Dong, Q. W.; Nuth, Joseph A., III

1994-01-01

Thiemens and Heidenreich (1983) first demonstrated that a chemically produced mass independent isotopic fractionation process could produce an isotopic composition which is identical to that observed in Allende inclusions. This raised the possibility that the meteoritic components could be produced by chemical, rather than nuclear processes. In order to develop a mechanistic model of the early solar system, it is important that relevant reactions be studied, particularly, those which may occur in the earliest condensation reactions. The isotopic results for isotopic fractionations associated with condensation processes are reported. A large mass independent isotopic fractionation is observed in one of the experiments.

Advances in Proteomics Data Analysis and Display Using an Accurate Mass and Time Tag Approach

PubMed Central

Zimmer, Jennifer S.D.; Monroe, Matthew E.; Qian, Wei-Jun; Smith, Richard D.

2007-01-01

Proteomics has recently demonstrated utility in understanding cellular processes on the molecular level as a component of systems biology approaches and for identifying potential biomarkers of various disease states. The large amount of data generated by utilizing high efficiency (e.g., chromatographic) separations coupled to high mass accuracy mass spectrometry for high-throughput proteomics analyses presents challenges related to data processing, analysis, and display. This review focuses on recent advances in nanoLC-FTICR-MS-based proteomics approaches and the accompanying data processing tools that have been developed to display and interpret the large volumes of data being produced. PMID:16429408

Determining the locus of a processing zone in an in situ oil shale retort by sound monitoring

DOEpatents

Elkington, W. Brice

1978-01-01

The locus of a processing zone advancing through a fragmented permeable mass of particles in an in situ oil shale retort in a subterranean formation containing oil shale is determined by monitoring for sound produced in the retort, preferably by monitoring for sound at at least two locations in a plane substantially normal to the direction of advancement of the processing zone. Monitoring can be effected by placing a sound transducer in a well extending through the formation adjacent the retort and/or in the fragmented mass such as in a well extending into the fragmented mass.

40 CFR 63.605 - Monitoring requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... the mass flow of phosphorus-bearing feed material to the process. The monitoring system shall have an... either the mass flow of phosphorus-bearing feed material to the dryer or calciner, or the mass flow of... total mass rate in metric ton/hour of phosphorus bearing feed using a monitoring system for measuring...

40 CFR 63.605 - Monitoring requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... the mass flow of phosphorus-bearing feed material to the process. The monitoring system shall have an... either the mass flow of phosphorus-bearing feed material to the dryer or calciner, or the mass flow of... total mass rate in metric ton/hour of phosphorus bearing feed using a monitoring system for measuring...

Pathogen propagation in cultured three-dimensional tissue mass

NASA Technical Reports Server (NTRS)

Wolf, David A. (Inventor); Spaulding, Glenn F. (Inventor); Goodwin, Thomas J. (Inventor)

2000-01-01

A process for propagating a pathogen in a three-dimensional tissue mass cultured at microgravity conditions in a culture vessel containing culture media and a culture matrix is provided. The three-dimensional tissue mass is inoculated with a pathogen and pathogen replication in the cells of the tissue mass achieved.

40 CFR 63.7824 - What test methods and other procedures must I use to establish and demonstrate initial compliance...

Code of Federal Regulations, 2013 CFR

2013-07-01

... sinter produced (tons/day). (3) Compute the process-weighted mass emissions (Ev) each day using Equation 1 of this section as follows: ER20MY03.002 Where: Ev = Process-weighted mass emissions of volatile...

ANALYSIS OF TRACE-LEVEL ORGANIC COMBUSTION PROCESS EMISSIONS USING NOVEL MULTIDIMENSIONAL GAS CHROMATOGRAPHY-MASS SPECTROMETRY PROCEDURES

EPA Science Inventory

The paper discusses the analysis of trace-level organic combustion process emissions using novel multidimensional gas chromatography-mass spectrometry (MDGC-MS) procedures. It outlines the application of the technique through the analyses of various incinerator effluent and produ...

A POLLUTION REDUCTION METHODOLOGY FOR CHEMICAL PROCESS SIMULATORS

EPA Science Inventory

A pollution minimization methodology was developed for chemical process design using computer simulation. It is based on a pollution balance that at steady state is used to define a pollution index with units of mass of pollution per mass of products. The pollution balance has be...

40 CFR 63.446 - Standards for kraft pulping process condensates.

Code of Federal Regulations, 2012 CFR

2012-07-01

... prorated mass standard that is calculated by prorating the applicable mass standards (kilograms of total... 40 Protection of Environment 10 2012-07-01 2012-07-01 false Standards for kraft pulping process... PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES...

40 CFR 63.446 - Standards for kraft pulping process condensates.

Code of Federal Regulations, 2011 CFR

2011-07-01

... prorated mass standard that is calculated by prorating the applicable mass standards (kilograms of total... 40 Protection of Environment 9 2011-07-01 2011-07-01 false Standards for kraft pulping process... PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES...

40 CFR 63.446 - Standards for kraft pulping process condensates.

Code of Federal Regulations, 2010 CFR

2010-07-01

... prorated mass standard that is calculated by prorating the applicable mass standards (kilograms of total... 40 Protection of Environment 9 2010-07-01 2010-07-01 false Standards for kraft pulping process... PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES...

Supergravity separation of Pb and Sn from waste printed circuit boards at different temperatures

NASA Astrophysics Data System (ADS)

Meng, Long; Wang, Zhe; Zhong, Yi-wei; Chen, Kui-yuan; Guo, Zhan-cheng

2018-02-01

Printed circuit boards (PCBs) contain many toxic substances as well as valuable metals, e.g., lead (Pb) and tin (Sn). In this study, a novel technology, named supergravity, was used to separate different mass ratios of Pb and Sn from Pb-Sn alloys in PCBs. In a supergravity field, the liquid metal phase can permeate from solid particles. Hence, temperatures of 200, 280, and 400°C were chosen to separate Pb and Sn from PCBs. The results depicted that gravity coefficient only affected the recovery rates of Pb and Sn, whereas it had little effect on the mass ratios of Pb and Sn in the obtained alloys. With an increase in gravity coefficient, the recovery values of Pb and Sn in each step of the separation process increased. In the single-step separation process, the mass ratios of Pb and Sn in Pb-Sn alloys were 0.55, 0.40, and 0.64 at 200, 280, and 400°C, respectively. In the two-step separation process, the mass ratios were 0.12 and 0.55 at 280 and 400°C, respectively. Further, the mass ratio was observed to be 0.76 at 400°C in the three-step separation process. This process provides an innovative approach to the recycling mechanism of Pb and Sn from PCBs.

Dependence of X-Ray Burst Models on Nuclear Masses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schatz, H.; Ong, W.-J.

X-ray burst model predictions of light curves and the final composition of the nuclear ashes are affected by uncertain nuclear masses. However, not all of these masses are determined experimentally with sufficient accuracy. Here we identify the remaining nuclear mass uncertainties in X-ray burst models using a one-zone model that takes into account the changes in temperature and density evolution caused by changes in the nuclear physics. Two types of bursts are investigated—a typical mixed H/He burst with a limited rapid proton capture process (rp-process) and an extreme mixed H/He burst with an extended rp-process. When allowing for a 3more » σ variation, only three remaining nuclear mass uncertainties affect the light-curve predictions of a typical H/He burst ({sup 27}P, {sup 61}Ga, and {sup 65}As), and only three additional masses affect the composition strongly ({sup 80}Zr, {sup 81}Zr, and {sup 82}Nb). A larger number of mass uncertainties remain to be addressed for the extreme H/He burst, with the most important being {sup 58}Zn, {sup 61}Ga, {sup 62}Ge, {sup 65}As, {sup 66}Se, {sup 78}Y, {sup 79}Y, {sup 79}Zr, {sup 80}Zr, {sup 81}Zr, {sup 82}Zr, {sup 82}Nb, {sup 83}Nb, {sup 86}Tc, {sup 91}Rh, {sup 95}Ag, {sup 98}Cd, {sup 99}In, {sup 100}In, and {sup 101}In. The smallest mass uncertainty that still impacts composition significantly when varied by 3 σ is {sup 85}Mo with 16 keV uncertainty. For one of the identified masses, {sup 27}P, we use the isobaric mass multiplet equation to improve the mass uncertainty, obtaining an atomic mass excess of −716(7) keV. The results provide a roadmap for future experiments at advanced rare isotope beam facilities, where all the identified nuclides are expected to be within reach for precision mass measurements.« less

The impact of nuclear mass models on r-process nucleosynthesis network calculations

NASA Astrophysics Data System (ADS)

Vaughan, Kelly

2002-10-01

An insight into understanding various nucleosynthesis processes is via modelling of the process with network calculations. My project focus is r-process network calculations where the r-process is nucleosynthesis via rapid neutron capture thought to take place in high entropy supernova bubbles. One of the main uncertainties of the simulations is the Nuclear Physics input. My project investigates the role that nuclear masses play in the resulting abundances. The code tecode, involves rapid (n,γ) capture reactions in competition with photodisintegration and β decay onto seed nuclei. In order to fully analyze the effects of nuclear mass models on the relative isotopic abundances, calculations were done from the network code, keeping the initial environmental parameters constant throughout. The supernova model investigated by Qian et al (1996) in which two r-processes, of high and low frequency with seed nucleus ^90Se and of fixed luminosity (fracL_ν_e(0)r_7(0)^2 ˜= 8.77), contribute to the nucleosynthesis of the heavier elements. These two r-processes, however, do not contribute equally to the total abundance observed. The total isotopic abundance produced from both events was therefore calculated using equation refabund. Y(H+L) = fracY(H)+fY(L)f+1 <~belabund where Y(H) denotes the relative isotopic abundance produced in the high frequency event, Y(L) corresponds to the low freqeuncy event and f is the ratio of high event matter to low event matter produced. Having established reliable, fixed parameters, the network code was run using data files containing parameters such as the mass excess, neutron separation energy, β decay rates and neutron capture rates based around three different nuclear mass models. The mass models tested are the HFBCS model (Hartree-Fock BCS) derived from first principles, the ETFSI-Q model (Extended Thomas-Fermi with Strutinsky Integral including shell Quenching) known for its particular successes in the replication of Solar System abundances, and the P-Scheme Model tePscheme. The aims of this research is to test the applicability of the P-Scheme in relation to the other mass models to the r-process network calculations. 02 Pscheme Aprahamian,A., Gadala-Maria,A. & Cuka,N. 1996, Revista Mexicana de Fisica,42,1 code Surman,R. & Engel,J. 1998, Phys.Rev. C,54,4 thebibliography

Charged lepton flavor violation in a class of radiative neutrino mass generation models

NASA Astrophysics Data System (ADS)

Chowdhury, Talal Ahmed; Nasri, Salah

2018-04-01

We investigate the charged lepton flavor violating processes μ →e γ , μ →e e e ¯, and μ -e conversion in nuclei for a class of three-loop radiative neutrino mass generation models with electroweak multiplets of increasing order. We find that, because of certain cancellations among various one-loop diagrams which give the dipole and nondipole contributions in an effective μ e γ vertex and a Z-penguin contribution in an effective μ e Z vertex, the flavor violating processes μ →e γ and μ -e conversion in nuclei become highly suppressed compared to μ →e e e ¯ process. Therefore, the observation of such a pattern in LFV processes may reveal the radiative mechanism behind neutrino mass generation.

Development of Parametric Mass and Volume Models for an Aerospace SOFC/Gas Turbine Hybrid System

NASA Technical Reports Server (NTRS)

Tornabene, Robert; Wang, Xiao-yen; Steffen, Christopher J., Jr.; Freeh, Joshua E.

2005-01-01

In aerospace power systems, mass and volume are key considerations to produce a viable design. The utilization of fuel cells is being studied for a commercial aircraft electrical power unit. Based on preliminary analyses, a SOFC/gas turbine system may be a potential solution. This paper describes the parametric mass and volume models that are used to assess an aerospace hybrid system design. The design tool utilizes input from the thermodynamic system model and produces component sizing, performance, and mass estimates. The software is designed such that the thermodynamic model is linked to the mass and volume model to provide immediate feedback during the design process. It allows for automating an optimization process that accounts for mass and volume in its figure of merit. Each component in the system is modeled with a combination of theoretical and empirical approaches. A description of the assumptions and design analyses is presented.

POLLUTION BALANCE: A NEW METHODOLOGY FOR MINIMIZING WASTE PRODUCTION IN MANUFACTURING PROCESSES.

EPA Science Inventory

A new methodolgy based on a generic pollution balance equation, has been developed for minimizing waste production in manufacturing processes. A "pollution index," defined as the mass of waste produced per unit mass of a product, has been introduced to provide a quantitative meas...

Selection of basic data for numerical modeling of rock mass stress state at Mirny Mining and Processing Works, Alrosa Group of Companies

NASA Astrophysics Data System (ADS)

Bokiy, IB; Zoteev, OV; Pul, VV; Pul, EK

2018-03-01

The influence of structural features on the strength and elasticity modulus is studied in rock mass in the area of Mirny Mining and Processing Works. The authors make recommendations on the values of physical properties of rocks.

Assessing Process Mass Intensity and Waste via an "aza"-Baylis-Hillman Reaction

ERIC Educational Resources Information Center

Go´mez-Biagi, Rodolfo F.; Dicks, Andrew P.

2015-01-01

A synthetic procedure is outlined where upper-level undergraduate organic chemistry students perform a two-week, semimicroscale "aza"-Baylis-Hillman reaction to generate an allylic sulfonamide product. Students evaluate several green chemistry reaction metrics of industrial importance (process mass intensity (PMI), E factor, and reaction…

40 CFR 63.446 - Standards for kraft pulping process condensates.

Code of Federal Regulations, 2013 CFR

2013-07-01

... pulp products, owners and operators may meet a prorated mass standard that is calculated by prorating the applicable mass standards (kilograms of total HAP per megagram of ODP) for bleached and unbleached... 40 Protection of Environment 10 2013-07-01 2013-07-01 false Standards for kraft pulping process...

40 CFR 63.446 - Standards for kraft pulping process condensates.

Code of Federal Regulations, 2014 CFR

2014-07-01

... pulp products, owners and operators may meet a prorated mass standard that is calculated by prorating the applicable mass standards (kilograms of total HAP per megagram of ODP) for bleached and unbleached... 40 Protection of Environment 10 2014-07-01 2014-07-01 false Standards for kraft pulping process...

The time scale of quasifission process in reactions with heavy ions

NASA Astrophysics Data System (ADS)

Knyazheva, G. N.; Itkis, I. M.; Kozulin, E. M.

2014-05-01

The study of mass-energy distributions of binary fragments obtained in the reactions of 36S, 48Ca, 58Fe and 64Ni ions with the 232Th, 238U, 244Pu and 248Cm at energies below and above the Coulomb barrier is presented. These data have been measured by two time-of-flight CORSET spectrometer. The mass resolution of the spectrometer for these measurements was about 3u. It allows to investigate the features of mass distributions with good accuracy. The properties of mass and TKE of QF fragments in dependence on interaction energy have been investigated and compared with characteristics of the fusion-fission process. To describe the quasifission mass distribution the simple method has been proposed. This method is based on the driving potential of the system and time dependent mass drift. This procedure allows to estimate QF time scale from the measured mass distributions. It has been found that the QF time exponentially decreases when the reaction Coulomb factor Z1Z2 increases.

Mass Loss during Late Stellar Evolution

NASA Astrophysics Data System (ADS)

Olofsson, Hans

1999-10-01

Extensive post-main sequence mass loss occurs for low- and intermediate-mass (up to ~8MSun) stars on the asymptotic giant branch (AGB), and for the higher-mass stars during their red supergiant evolution. These winds have a profound effect on the evolution of the stars, as well as for the enrichment of the interstellar medium with heavy elements and grain particles. The mass loss on the AGB is the by far most well studied, but a good deal of the basic processes are still not understood or cannot be described in a proper quantitative way, e.g., the mass loss mechanism itself. Furthermore, these objects provide us with fascinating systems, where intricate interplays between various physical and chemical processes take place, and their relative simplicity in terms of geometry, density distribution, and kinematics makes them excellent astrophysical laboratories. In this review we will concentrate on those aspects of AGB mass loss that are particularly well studied using a large millimetre array.

Controls of sediment transfers, sedimentary budgets and relief development in cold environments: Results from four catchment systems in Iceland, Swedish Lapland and Finnish Lapland

NASA Astrophysics Data System (ADS)

Beylich, A. A.

2012-04-01

By the combined, longer-term and quantitative recording of relevant denudative slope processes and stream work in four selected catchment systems in sub-arctic oceanic Eastern Iceland (Hrafndalur and Austdalur), arctic-oceanic Swedish Lapland (Latnjavagge) and sub-arctic oceanic Finnish Lapland (Kidisjoki), information on the absolute and relative importance of the different denudative processes is collected. Direct comparison of the four catchment geo-systems (the catchment sizes range from 7 km2 to 23 km2) allows conclusions on major controls of sediment transfers, sedimentary budgets and relief development in theses cold climate environments. To allow direct comparison of the different processes, all mass transfers are calculated as tonnes multiplied by meter per year, i.e. as the product of the annually transferred mass and the corresponding transport distance. Ranking the different processes according to their annual mass transfers shows that stream work dominates over slope denudation. For Hrafndalur (Eastern Iceland) the following order of denudative processes is found after nine years of process studies (2001 - 2010): (1) Fluvial suspended sediment plus bedload transport, (2) Fluvial solute transport, (3) Rock falls plus boulder falls, (4) Chemical slope denudation, (5) Mechanical fluvial slope denudation (slope wash), (6) Creep processes, (7) Avalanches, (8) Debris flows, (9) Translation slides, (10) Deflation. Compared to that, in Austdalur the following ranking is given after fourten years of process studies (1996 - 2010): (1) Fluvial suspended sediment plus bedload transport, (2) Fluvial solute transport, (3) Mechanical fluvial slope denudation (slope wash), (4) Chemical slope denudation, (5) Avalanches, (6) Rock falls plus boulder falls, (7) Creep processes, (8) Debris flows, (9) Deflation, (10) Translation slides. In the Latnjavagge catchment (Swedish Lapland) the ranking is (eleven-years period of studies, 1999 - 2010): (1) Fluvial solute transport, (2) Fluvial suspended sediment plus bedload transport, (3) Rock falls plus boulder falls, (4) Chemical slope denudation, (5) Mechanical fluvial slope denudation (slope wash), (6) Avalanches, (7) Creep processes and solifluction, (8) Slush flows, (9) Debris flows, (10) Translation slides, (11) Deflation. In Kidisjoki (Finnish Lapland) the order of processes, as determined after a nine-years period (2001 - 2010) of geomorphic process studies, is: (1) Fluvial solute transport, (2) Chemical slope denudation, (3) Fluvial suspended sediment plus bedload transport, (4) Mechanical fluvial slope denudation, (5) Creep processes, (6) Avalanches and slush flows, (7) Debris flows and slides, (8) Rock and boulder falls, (9) Deflation. As a result, in all four selected cold climate study areas the intensity of contemporary denudative processes and mass transfers is altogether rather low, which is in opposition to the earlier postulated oppinion of a generally high intensity of geomorphic processes in cold climate environments. A direct comparison of the annual mass transfers summarises that there are differences between process intensities and the relative importance of different denudative processes within the four study areas. The major controls of these detected differences are: (i) Climate: The higher annual precipitation along with the larger number of extreme rainfall events and the higher frequency of snowmelt and rainfall generated peak runoff events in Eastern Iceland as compared to Swedish Lapland and Finnish Lapland lead to higher mass transfers, (ii) Lithology: The low resistance of rhyolites in Hrafndalur causes especially high weathering rates and connected mass transfers in this catchment. Due to the lower resistance of the rhyolites as compared to the basalts found in Austdalur Postglacial modification of the glacially formed relief is clearly further advanced in Hrafndalur as compared to Austdalur, (iii) Relief: The greater steepness of the Icelandic catchments leads to higher mass transfers here as compared to Latnjavagge and Kidisjoki, (iv) Vegetation cover: The significant disturbance of the vegetation cover by human impacts in Easter Iceland causes higher mass transfers (slope wash) whereas restricted sediment availability is a main reason for lower mass transfers in Swedish Lapland and Finnish Lapland. The applied catchment-based approach seems to be effective for analysing sediment budgets and trends of Postglacial relief development in selected study areas with given environmental settings. Direct comparison of investigated catchments will improve possibilities to model relief development as well as possible effects of projected climate change in cold climate environments.

Searching for Low-mass Companions of Cepheids, Part II

NASA Astrophysics Data System (ADS)

Remage Evans, Nancy; Tingle, E.; Bond, H. E.; Schaefer, G. H.; Mason, B.; Karovska, M.; Wolk, S.; Pillitteri, I.; DePasquale, J.; Guinan, E.; Engle, S.

2012-01-01

The formation of a binary/multiple system is an effective way to manipulate angular momentum during the star-formation process. The properties of binary systems (separations and mass ratios) are thus the ``fingerprints" of the process. Low mass companions are the most difficult to identify particularly for massive stars. We are conducting a snapshot survey of the nearest Cepheids (5 Msun stars) using the Hubble Space Telescope Wide Field Camera 3 (WFC3) to discover possible resolved low mass companions. The color-magnitude combination is the first approach to identifying probable physical companions. The distributions of mass and separation for these stars will be discussed. Financial suppoet was provided by Hubble grant GO-12215.01-A and the Chandra X-ray Center NASA contract NAS8-03060.

Water Vapour Effects in Mass Measurement

NASA Astrophysics Data System (ADS)

Khélifa, N.

2008-01-01

Water vapour density inside the mass comparator enclosure is a critical parameter whose fluctuations during mass weighing can lead to errors in the determination of an unknown mass. To monitor them, a method using DFB laser diode in the near infrared has been proposed and tested. Preliminary results of our observation of water vapour sorption and de-sorption processes from the walls and the mass standard are reported.

On-line Monitoring of Continuous Flow Chemical Synthesis Using a Portable, Small Footprint Mass Spectrometer

NASA Astrophysics Data System (ADS)

Bristow, Tony W. T.; Ray, Andrew D.; O'Kearney-McMullan, Anne; Lim, Louise; McCullough, Bryan; Zammataro, Alessio

2014-10-01

For on-line monitoring of chemical reactions (batch or continuous flow), mass spectrometry (MS) can provide data to (1) determine the fate of starting materials and reagents, (2) confirm the presence of the desired product, (3) identify intermediates and impurities, (4) determine steady state conditions and point of completion, and (5) speed up process optimization. Recent developments in small footprint atmospheric pressure ionization portable mass spectrometers further enable this coupling, as the mass spectrometer can be easily positioned with the reaction system to be studied. A major issue for this combination is the transfer of a sample that is representative of the reaction and also compatible with the mass spectrometer. This is particularly challenging as high concentrations of reagents and products can be encountered in organic synthesis. The application of a portable mass spectrometer for on-line characterization of flow chemical synthesis has been evaluated by coupling a Microsaic 4000 MiD to the Future Chemistry Flow Start EVO chemistry system. Specifically, the Hofmann rearrangement has been studied using the on-line mass spectrometry approach. Sample transfer from the flow reactor is achieved using a mass rate attenuator (MRA) and a sampling make-up flow from a high pressure pump. This enables the appropriate sample dilution, transfer, and preparation for electrospray ionization. The capability of this approach to provide process understanding is described using an industrial pharmaceutical process that is currently under development. The effect of a number of key experimental parameters, such as the composition of the sampling make-up flow and the dilution factor on the mass spectrometry data, is also discussed.

Response of Jupiter's Aurora to Plasma Mass Loading Rate Monitored by the Hisaki Satellite During Volcanic Eruptions at Io

NASA Astrophysics Data System (ADS)

Kimura, T.; Hiraki, Y.; Tao, C.; Tsuchiya, F.; Delamere, P. A.; Yoshioka, K.; Murakami, G.; Yamazaki, A.; Kita, H.; Badman, S. V.; Fukazawa, K.; Yoshikawa, I.; Fujimoto, M.

2018-03-01

The production and transport of plasma mass are essential processes in the dynamics of planetary magnetospheres. At Jupiter, it is hypothesized that Io's volcanic plasma carried out of the plasma torus is transported radially outward in the rotating magnetosphere and is recurrently ejected as plasmoid via tail reconnection. The plasmoid ejection is likely associated with particle energization, radial plasma flow, and transient auroral emissions. However, it has not been demonstrated that plasmoid ejection is sensitive to mass loading because of the lack of simultaneous observations of both processes. We report the response of plasmoid ejection to mass loading during large volcanic eruptions at Io in 2015. Response of the transient aurora to the mass loading rate was investigated based on a combination of Hisaki satellite monitoring and a newly developed analytic model. We found that the transient aurora frequently recurred at a 2-6 day period in response to a mass loading increase from 0.3 to 0.5 t/s. In general, the recurrence of the transient aurora was not significantly correlated with the solar wind, although there was an exceptional event with a maximum emission power of 10 TW after the solar wind shock arrival. The recurrence of plasmoid ejection requires the precondition that an amount comparable to the total mass of magnetosphere, 1.5 Mt, is accumulated in the magnetosphere. A plasmoid mass of more than 0.1 Mt is necessary in case that the plasmoid ejection is the only process for mass release.

An order insertion scheduling model of logistics service supply chain considering capacity and time factors.

PubMed

Liu, Weihua; Yang, Yi; Wang, Shuqing; Liu, Yang

2014-01-01

Order insertion often occurs in the scheduling process of logistics service supply chain (LSSC), which disturbs normal time scheduling especially in the environment of mass customization logistics service. This study analyses order similarity coefficient and order insertion operation process and then establishes an order insertion scheduling model of LSSC with service capacity and time factors considered. This model aims to minimize the average unit volume operation cost of logistics service integrator and maximize the average satisfaction degree of functional logistics service providers. In order to verify the viability and effectiveness of our model, a specific example is numerically analyzed. Some interesting conclusions are obtained. First, along with the increase of completion time delay coefficient permitted by customers, the possible inserting order volume first increases and then trends to be stable. Second, supply chain performance reaches the best when the volume of inserting order is equal to the surplus volume of the normal operation capacity in mass service process. Third, the larger the normal operation capacity in mass service process is, the bigger the possible inserting order's volume will be. Moreover, compared to increasing the completion time delay coefficient, improving the normal operation capacity of mass service process is more useful.

A Stringent Limit on the Mass Production Rate of r-process Elements in the Milky Way

NASA Astrophysics Data System (ADS)

Macias, Phillip; Ramirez-Ruiz, Enrico

2018-06-01

We analyze data from several studies of metal-poor stars in the Milky Way, focusing individually on the main r-process elements (Eu) as well as the lighter neutron-capture element Sr, at the neutron-magic peak N = 50. Because these elements were injected in an explosion, we calculate the mass swept up when the blast wave first becomes radiative, yielding a lower limit for the dilution of such elements and hence a lower limit on the ejecta mass that is incorporated into the next generation of stars. Our study demonstrates that in order to explain the largest enhancements in [Eu/Fe] observed in stars at low [Fe/H] metallicities, individual r-process production events must synthesize a minimum of roughly 10‑3 M ⊙ of r-process material. This provides a critical constraint on galactic chemical evolution models. We also show independently that if the site of Mg production is the same as that of Eu, individual injection events must synthesize up to ∼10‑3 M ⊙ of r-process material. On the other hand, demanding that Sr traces Mg production results in r-process masses per event of ∼10‑5 M ⊙ . This suggests that the astrophysical sites responsible for the genesis of the main r-process elements need to operate at a drastically reduced rate when compared to standard core-collapse supernovae.

The Multi-Scale Mass Transfer Processes Controlling Natural Attenuation and Engineered Remediation: An IFC Focused on Hanford’s 300 Area Uranium Plume Quality Assurance Project Plan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fix, N. J.

The purpose of the project is to conduct research at an Integrated Field-Scale Research Challenge Site in the Hanford Site 300 Area, CERCLA OU 300-FF-5 (Figure 1), to investigate multi-scale mass transfer processes associated with a subsurface uranium plume impacting both the vadose zone and groundwater. The project will investigate a series of science questions posed for research related to the effect of spatial heterogeneities, the importance of scale, coupled interactions between biogeochemical, hydrologic, and mass transfer processes, and measurements/approaches needed to characterize a mass-transfer dominated system. The research will be conducted by evaluating three (3) different hypotheses focused onmore » multi-scale mass transfer processes in the vadose zone and groundwater, their influence on field-scale U(VI) biogeochemistry and transport, and their implications to natural systems and remediation. The project also includes goals to 1) provide relevant materials and field experimental opportunities for other ERSD researchers and 2) generate a lasting, accessible, and high-quality field experimental database that can be used by the scientific community for testing and validation of new conceptual and numerical models of subsurface reactive transport.« less

Spray-dried respirable powders containing bacteriophages for the treatment of pulmonary infections.

PubMed

Matinkhoo, Sadaf; Lynch, Karlene H; Dennis, Jonathan J; Finlay, Warren H; Vehring, Reinhard

2011-12-01

Myoviridae bacteriophages were processed into a dry powder inhalable dosage form using a low-temperature spray-drying process. The phages were incorporated into microparticles consisting of trehalose, leucine, and optionally a third excipient (either a surfactant or casein sodium salt). The particles were designed to have high dispersibility and a respirable particle size, and to preserve the phages during processing. Bacteriophages KS4- M, KS14, and cocktails of phages ΦKZ/D3 and ΦKZ/D3/KS4-M were spray-dried with a processing loss ranging from 0.4 to 0.8 log pfu. The aerosol performance of the resulting dry powders as delivered from an Aerolizer® dry powder inhaler (DPI) exceeded the performance of commercially available DPIs; the emitted mass and the in vitro total lung mass of the lead formulation were 82.7% and 69.7% of filled capsule mass, respectively. The total lung mass had a mass median aerodynamic diameter of 2.5-2.8 µm. The total in vitro lung doses of the phages, delivered from a single actuation of the inhaler, ranged from 10(7) to 10(8) pfu, levels that are expected to be efficacious in vivo. Spray drying of bacteriophages into a respirable dry powder was found to be feasible. Copyright © 2011 Wiley-Liss, Inc.

Method for controlling clathrate hydrates in fluid systems

DOEpatents

Sloan, Jr., Earle D.

1995-01-01

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

Method for controlling clathrate hydrates in fluid systems

DOEpatents

Sloan, E.D. Jr.

1995-07-11

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

An insight into the adsorption and electrochemical processes occurring during the analysis of copper and lead in wines, using an electrochemical quartz crystal nanobalance.

PubMed

Yamasaki, Alzira; Oliveira, João A B P; Duarte, Armando C; Gomes, M Teresa S R

2012-08-30

Copper and lead in wine were quantified by anodic stripping voltammetry (ASV), performed onto the gold electrode of a piezoelectric quartz crystal. Both current or mass changes could be used as analytical signals, without a statistical difference in the results (α=0.05). However, the plot of mass vs. potential provided an in depth understanding of the electrochemical processes and allowed studying adsorption phenomena. Copper interaction with fructose is an example of a process which was not possible to ignore by observing the mass change on the gold electrode of the piezoelectric quartz crystal. Copyright © 2012 Elsevier B.V. All rights reserved.

Estimating the Contribution of Dynamical Ejecta in the Kilonova Associated with GW170817

NASA Astrophysics Data System (ADS)

Abbott, B. P.; Abbott, R.; Abbott, T. D.; Acernese, F.; Ackley, K.; Adams, C.; Adams, T.; Addesso, P.; Adhikari, R. X.; Adya, V. B.; Affeldt, C.; Afrough, M.; Agarwal, B.; Agathos, M.; Agatsuma, K.; Aggarwal, N.; Aguiar, O. D.; Aiello, L.; Ain, A.; Ajith, P.; Allen, B.; Allen, G.; Allocca, A.; Altin, P. A.; Amato, A.; Ananyeva, A.; Anderson, S. B.; Anderson, W. G.; Angelova, S. V.; Antier, S.; Appert, S.; Arai, K.; Araya, M. C.; Areeda, J. S.; Arnaud, N.; Arun, K. G.; Ascenzi, S.; Ashton, G.; Ast, M.; Aston, S. M.; Astone, P.; Atallah, D. V.; Aufmuth, P.; Aulbert, C.; AultONeal, K.; Austin, C.; Avila-Alvarez, A.; Babak, S.; Bacon, P.; Bader, M. K. M.; Bae, S.; Baker, P. T.; Baldaccini, F.; Ballardin, G.; Banagiri, S.; Barayoga, J. C.; Barclay, S. E.; Barish, B. C.; Barker, D.; Barkett, K.; Barone, F.; Barr, B.; Barsotti, L.; Barsuglia, M.; Barta, D.; Bartlett, J.; Bartos, I.; Bassiri, R.; Basti, A.; Batch, J. C.; Bawaj, M.; Bayley, J. C.; Bazzan, M.; Bécsy, B.; Beer, C.; Bejger, M.; Belahcene, I.; Bell, A. S.; Bergmann, G.; Bernuzzi, S.; Bero, J. J.; Berry, C. P. L.; Bersanetti, D.; Bertolini, A.; Betzwieser, J.; Bhagwat, S.; Bhandare, R.; Bilenko, I. A.; Billingsley, G.; Billman, C. R.; Birch, J.; Birney, R.; Birnholtz, O.; Biscans, S.; Biscoveanu, S.; Bisht, A.; Bitossi, M.; Biwer, C.; Bizouard, M. A.; Blackburn, J. K.; Blackman, J.; Blair, C. D.; Blair, D. G.; Blair, R. M.; Bloemen, S.; Bock, O.; Bode, N.; Boer, M.; Bogaert, G.; Bohe, A.; Bondu, F.; Bonilla, E.; Bonnand, R.; Boom, B. A.; Bork, R.; Boschi, V.; Bose, S.; Bossie, K.; Bouffanais, Y.; Bozzi, A.; Bradaschia, C.; Brady, P. R.; Branchesi, M.; Brau, J. E.; Briant, T.; Brillet, A.; Brinkmann, M.; Brisson, V.; Brockill, P.; Broida, J. E.; Brooks, A. F.; Brown, D. D.; Brunett, S.; Buchanan, C. C.; Buikema, A.; Bulik, T.; Bulten, H. J.; Buonanno, A.; Buskulic, D.; Buy, C.; Byer, R. L.; Cabero, M.; Cadonati, L.; Cagnoli, G.; Cahillane, C.; Calderón Bustillo, J.; Callister, T. A.; Calloni, E.; Camp, J. B.; Canepa, M.; Canizares, P.; Cannon, K. C.; Cao, H.; Cao, J.; Capano, C. D.; Capocasa, E.; Carbognani, F.; Caride, S.; Carney, M. F.; Casanueva Diaz, J.; Casentini, C.; Caudill, S.; Cavaglià, M.; Cavalier, F.; Cavalieri, R.; Cella, G.; Cepeda, C. B.; Cerdá-Durán, P.; Cerretani, G.; Cesarini, E.; Chamberlin, S. J.; Chan, M.; Chao, S.; Charlton, P.; Chase, E.; Chassande-Mottin, E.; Chatterjee, D.; Chatziioannou, K.; Cheeseboro, B. D.; Chen, H. Y.; Chen, X.; Chen, Y.; Cheng, H.-P.; Chia, H.; Chincarini, A.; Chiummo, A.; Chmiel, T.; Cho, H. S.; Cho, M.; Chow, J. H.; Christensen, N.; Chu, Q.; Chua, A. J. K.; Chua, S.; Chung, A. K. W.; Chung, S.; Ciani, G.; Ciolfi, R.; Cirelli, C. E.; Cirone, A.; Clara, F.; Clark, J. A.; Clearwater, P.; Cleva, F.; Cocchieri, C.; Coccia, E.; Cohadon, P.-F.; Cohen, D.; Colla, A.; Collette, C. G.; Cominsky, L. R.; Constancio, M., Jr.; Conti, L.; Cooper, S. J.; Corban, P.; Corbitt, T. R.; Cordero-Carrión, I.; Corley, K. R.; Cornish, N.; Corsi, A.; Cortese, S.; Costa, C. A.; Coughlin, M. W.; Coughlin, S. B.; Coulon, J.-P.; Countryman, S. T.; Couvares, P.; Covas, P. B.; Cowan, E. E.; Coward, D. M.; Cowart, M. J.; Coyne, D. C.; Coyne, R.; Creighton, J. D. E.; Creighton, T. D.; Cripe, J.; Crowder, S. G.; Cullen, T. J.; Cumming, A.; Cunningham, L.; Cuoco, E.; Dal Canton, T.; Dálya, G.; Danilishin, S. L.; D'Antonio, S.; Danzmann, K.; Dasgupta, A.; Da Silva Costa, C. F.; Dattilo, V.; Dave, I.; Davier, M.; Davis, D.; Daw, E. J.; Day, B.; De, S.; DeBra, D.; Degallaix, J.; De Laurentis, M.; Deléglise, S.; Del Pozzo, W.; Demos, N.; Denker, T.; Dent, T.; De Pietri, R.; Dergachev, V.; De Rosa, R.; DeRosa, R. T.; De Rossi, C.; DeSalvo, R.; de Varona, O.; Devenson, J.; Dhurandhar, S.; Díaz, M. C.; Dietrich, T.; Di Fiore, L.; Di Giovanni, M.; Di Girolamo, T.; Di Lieto, A.; Di Pace, S.; Di Palma, I.; Di Renzo, F.; Doctor, Z.; Dolique, V.; Donovan, F.; Dooley, K. L.; Doravari, S.; Dorrington, I.; Douglas, R.; Dovale Álvarez, M.; Downes, T. P.; Drago, M.; Dreissigacker, C.; Driggers, J. C.; Du, Z.; Ducrot, M.; Dupej, P.; Dwyer, S. E.; Edo, T. B.; Edwards, M. C.; Effler, A.; Eggenstein, H.-B.; Ehrens, P.; Eichholz, J.; Eikenberry, S. S.; Eisenstein, R. A.; Essick, R. C.; Estevez, D.; Etienne, Z. B.; Etzel, T.; Evans, M.; Evans, T. M.; Factourovich, M.; Fafone, V.; Fair, H.; Fairhurst, S.; Fan, X.; Farinon, S.; Farr, B.; Farr, W. M.; Fauchon-Jones, E. J.; Favata, M.; Fays, M.; Fee, C.; Fehrmann, H.; Feicht, J.; Fejer, M. M.; Fernandez-Galiana, A.; Ferrante, I.; Ferreira, E. C.; Ferrini, F.; Fidecaro, F.; Finstad, D.; Fiori, I.; Fiorucci, D.; Fishbach, M.; Fisher, R. P.; Fitz-Axen, M.; Flaminio, R.; Fletcher, M.; Fong, H.; Font, J. A.; Forsyth, P. W. F.; Forsyth, S. S.; Fournier, J.-D.; Frasca, S.; Frasconi, F.; Frei, Z.; Freise, A.; Frey, R.; Frey, V.; Fries, E. M.; Fritschel, P.; Frolov, V. V.; Fulda, P.; Fyffe, M.; Gabbard, H.; Gadre, B. U.; Gaebel, S. M.; Gair, J. R.; Gammaitoni, L.; Ganija, M. R.; Gaonkar, S. G.; Garcia-Quiros, C.; Garufi, F.; Gateley, B.; Gaudio, S.; Gaur, G.; Gayathri, V.; Gehrels, N.; Gemme, G.; Genin, E.; Gennai, A.; George, D.; George, J.; Gergely, L.; Germain, V.; Ghonge, S.; Ghosh, Abhirup; Ghosh, Archisman; Ghosh, S.; Giaime, J. A.; Giardina, K. D.; Giazotto, A.; Gill, K.; Glover, L.; Goetz, E.; Goetz, R.; Gomes, S.; Goncharov, B.; González, G.; Gonzalez Castro, J. M.; Gopakumar, A.; Gorodetsky, M. L.; Gossan, S. E.; Gosselin, M.; Gouaty, R.; Grado, A.; Graef, C.; Granata, M.; Grant, A.; Gras, S.; Gray, C.; Greco, G.; Green, A. C.; Gretarsson, E. M.; Groot, P.; Grote, H.; Grunewald, S.; Gruning, P.; Guidi, G. M.; Guo, X.; Gupta, A.; Gupta, M. K.; Gushwa, K. E.; Gustafson, E. K.; Gustafson, R.; Halim, O.; Hall, B. R.; Hall, E. D.; Hamilton, E. Z.; Hammond, G.; Haney, M.; Hanke, M. M.; Hanks, J.; Hanna, C.; Hannam, M. D.; Hannuksela, O. A.; Hanson, J.; Hardwick, T.; Harms, J.; Harry, G. M.; Harry, I. W.; Hart, M. J.; Haster, C.-J.; Haughian, K.; Healy, J.; Heidmann, A.; Heintze, M. C.; Heitmann, H.; Hello, P.; Hemming, G.; Hendry, M.; Heng, I. S.; Hennig, J.; Heptonstall, A. W.; Heurs, M.; Hild, S.; Hinderer, T.; Hoak, D.; Hofman, D.; Holt, K.; Holz, D. E.; Hopkins, P.; Horst, C.; Hough, J.; Houston, E. A.; Howell, E. J.; Hreibi, A.; Hu, Y. M.; Huerta, E. A.; Huet, D.; Hughey, B.; Husa, S.; Huttner, S. H.; Huynh-Dinh, T.; Indik, N.; Inta, R.; Intini, G.; Isa, H. N.; Isac, J.-M.; Isi, M.; Iyer, B. R.; Izumi, K.; Jacqmin, T.; Jani, K.; Jaranowski, P.; Jawahar, S.; Jiménez-Forteza, F.; Johnson, W. W.; Johnson-McDaniel, N. K.; Jones, D. I.; Jones, R.; Jonker, R. J. G.; Ju, L.; Junker, J.; Kalaghatgi, C. V.; Kalogera, V.; Kamai, B.; Kandhasamy, S.; Kang, G.; Kanner, J. B.; Kapadia, S. J.; Karki, S.; Karvinen, K. S.; Kasprzack, M.; Kastaun, W.; Katolik, M.; Katsavounidis, E.; Katzman, W.; Kaufer, S.; Kawabe, K.; Kawaguchi, K.; Kéfélian, F.; Keitel, D.; Kemball, A. J.; Kennedy, R.; Kent, C.; Key, J. S.; Khalili, F. Y.; Khan, I.; Khan, S.; Khan, Z.; Khazanov, E. A.; Kijbunchoo, N.; Kim, Chunglee; Kim, J. C.; Kim, K.; Kim, W.; Kim, W. S.; Kim, Y.-M.; Kimbrell, S. J.; King, E. J.; King, P. J.; Kinley-Hanlon, M.; Kirchhoff, R.; Kissel, J. S.; Kleybolte, L.; Klimenko, S.; Knowles, T. D.; Koch, P.; Koehlenbeck, S. M.; Koley, S.; Kondrashov, V.; Kontos, A.; Korobko, M.; Korth, W. Z.; Kowalska, I.; Kozak, D. B.; Krämer, C.; Kringel, V.; Królak, A.; Kuehn, G.; Kumar, P.; Kumar, R.; Kumar, S.; Kuo, L.; Kutynia, A.; Kwang, S.; Lackey, B. D.; Lai, K. H.; Landry, M.; Lang, R. N.; Lange, J.; Lantz, B.; Lanza, R. K.; Larson, S. L.; Lartaux-Vollard, A.; Lasky, P. D.; Laxen, M.; Lazzarini, A.; Lazzaro, C.; Leaci, P.; Leavey, S.; Lee, C. H.; Lee, H. K.; Lee, H. M.; Lee, H. W.; Lee, K.; Lehmann, J.; Lenon, A.; Leonardi, M.; Leroy, N.; Letendre, N.; Levin, Y.; Li, T. G. F.; Linker, S. D.; Littenberg, T. B.; Liu, J.; Liu, X.; Lo, R. K. L.; Lockerbie, N. A.; London, L. T.; Lord, J. E.; Lorenzini, M.; Loriette, V.; Lormand, M.; Losurdo, G.; Lough, J. D.; Lousto, C. O.; Lovelace, G.; Lück, H.; Lumaca, D.; Lundgren, A. P.; Lynch, R.; Ma, Y.; Macas, R.; Macfoy, S.; Machenschalk, B.; MacInnis, M.; Macleod, D. M.; Magaña Hernandez, I.; Magaña-Sandoval, F.; Magaña Zertuche, L.; Magee, R. M.; Majorana, E.; Maksimovic, I.; Man, N.; Mandic, V.; Mangano, V.; Mansell, G. L.; Manske, M.; Mantovani, M.; Marchesoni, F.; Marion, F.; Márka, S.; Márka, Z.; Markakis, C.; Markosyan, A. S.; Markowitz, A.; Maros, E.; Marquina, A.; Martelli, F.; Martellini, L.; Martin, I. W.; Martin, R. M.; Martynov, D. V.; Mason, K.; Massera, E.; Masserot, A.; Massinger, T. J.; Masso-Reid, M.; Mastrogiovanni, S.; Matas, A.; Matichard, F.; Matone, L.; Mavalvala, N.; Mazumder, N.; McCarthy, R.; McClelland, D. E.; McCormick, S.; McCuller, L.; McGuire, S. C.; McIntyre, G.; McIver, J.; McManus, D. J.; McNeill, L.; McRae, T.; McWilliams, S. T.; Meacher, D.; Meadors, G. D.; Mehmet, M.; Meidam, J.; Mejuto-Villa, E.; Melatos, A.; Mendell, G.; Mercer, R. A.; Merilh, E. L.; Merzougui, M.; Meshkov, S.; Messenger, C.; Messick, C.; Metzdorff, R.; Meyers, P. M.; Miao, H.; Michel, C.; Middleton, H.; Mikhailov, E. E.; Milano, L.; Miller, A. L.; Miller, B. B.; Miller, J.; Millhouse, M.; Milovich-Goff, M. C.; Minazzoli, O.; Minenkov, Y.; Ming, J.; Mishra, C.; Mitra, S.; Mitrofanov, V. P.; Mitselmakher, G.; Mittleman, R.; Moffa, D.; Moggi, A.; Mogushi, K.; Mohan, M.; Mohapatra, S. R. P.; Montani, M.; Moore, C. J.; Moraru, D.; Moreno, G.; Morriss, S. R.; Mours, B.; Mow-Lowry, C. M.; Mueller, G.; Muir, A. W.; Mukherjee, Arunava; Mukherjee, D.; Mukherjee, S.; Mukund, N.; Mullavey, A.; Munch, J.; Muñiz, E. A.; Muratore, M.; Murray, P. G.; Napier, K.; Nardecchia, I.; Naticchioni, L.; Nayak, R. K.; Neilson, J.; Nelemans, G.; Nelson, T. J. N.; Nery, M.; Neunzert, A.; Nevin, L.; Newport, J. M.; Newton, G.; Ng, K. K. Y.; Nguyen, T. T.; Nichols, D.; Nielsen, A. B.; Nissanke, S.; Nitz, A.; Noack, A.; Nocera, F.; Nolting, D.; North, C.; Nuttall, L. K.; Oberling, J.; O'Dea, G. D.; Ogin, G. H.; Oh, J. J.; Oh, S. H.; Ohme, F.; Okada, M. A.; Oliver, M.; Oppermann, P.; Oram, Richard J.; O'Reilly, B.; Ormiston, R.; Ortega, L. F.; O'Shaughnessy, R.; Ossokine, S.; Ottaway, D. J.; Overmier, H.; Owen, B. J.; Pace, A. E.; Page, J.; Page, M. A.; Pai, A.; Pai, S. A.; Palamos, J. R.; Palashov, O.; Palomba, C.; Pal-Singh, A.; Pan, Howard; Pan, Huang-Wei; Pang, B.; Pang, P. T. H.; Pankow, C.; Pannarale, F.; Pant, B. C.; Paoletti, F.; Paoli, A.; Papa, M. A.; Parida, A.; Parker, W.; Pascucci, D.; Pasqualetti, A.; Passaquieti, R.; Passuello, D.; Patil, M.; Patricelli, B.; Pearlstone, B. L.; Pedraza, M.; Pedurand, R.; Pekowsky, L.; Pele, A.; Penn, S.; Perez, C. J.; Perreca, A.; Perri, L. M.; Pfeiffer, H. P.; Phelps, M.; Piccinni, O. J.; Pichot, M.; Piergiovanni, F.; Pierro, V.; Pillant, G.; Pinard, L.; Pinto, I. M.; Pirello, M.; Pitkin, M.; Poe, M.; Poggiani, R.; Popolizio, P.; Porter, E. K.; Post, A.; Powell, J.; Prasad, J.; Pratt, J. W. W.; Pratten, G.; Predoi, V.; Prestegard, T.; Prijatelj, M.; Principe, M.; Privitera, S.; Prodi, G. A.; Prokhorov, L. G.; Puncken, O.; Punturo, M.; Puppo, P.; Pürrer, M.; Qi, H.; Quetschke, V.; Quintero, E. A.; Quitzow-James, R.; Rabeling, D. S.; Radkins, H.; Raffai, P.; Raja, S.; Rajan, C.; Rajbhandari, B.; Rakhmanov, M.; Ramirez, K. E.; Ramos-Buades, A.; Rapagnani, P.; Raymond, V.; Razzano, M.; Read, J.; Regimbau, T.; Rei, L.; Reid, S.; Reitze, D. H.; Ren, W.; Reyes, S. D.; Ricci, F.; Ricker, P. M.; Rieger, S.; Riles, K.; Rizzo, M.; Robertson, N. A.; Robie, R.; Robinet, F.; Rocchi, A.; Rolland, L.; Rollins, J. G.; Roma, V. J.; Romano, R.; Romel, C. L.; Romie, J. H.; Rosińska, D.; Ross, M. P.; Rowan, S.; Rüdiger, A.; Ruggi, P.; Rutins, G.; Ryan, K.; Sachdev, S.; Sadecki, T.; Sadeghian, L.; Sakellariadou, M.; Salconi, L.; Saleem, M.; Salemi, F.; Samajdar, A.; Sammut, L.; Sampson, L. M.; Sanchez, E. J.; Sanchez, L. E.; Sanchis-Gual, N.; Sandberg, V.; Sanders, J. R.; Sassolas, B.; Sauter, O.; Savage, R. L.; Sawadsky, A.; Schale, P.; Scheel, M.; Scheuer, J.; Schmidt, J.; Schmidt, P.; Schnabel, R.; Schofield, R. M. S.; Schönbeck, A.; Schreiber, E.; Schuette, D.; Schulte, B. W.; Schutz, B. F.; Schwalbe, S. G.; Scott, J.; Scott, S. M.; Seidel, E.; Sellers, D.; Sengupta, A. S.; Sentenac, D.; Sequino, V.; Sergeev, A.; Shaddock, D. A.; Shaffer, T. J.; Shah, A. A.; Shahriar, M. S.; Shaner, M. B.; Shao, L.; Shapiro, B.; Shawhan, P.; Sheperd, A.; Shoemaker, D. H.; Shoemaker, D. M.; Siellez, K.; Siemens, X.; Sieniawska, M.; Sigg, D.; Silva, A. D.; Singer, L. P.; Singh, A.; Singhal, A.; Sintes, A. M.; Slagmolen, B. J. J.; Smith, B.; Smith, J. R.; Smith, R. J. E.; Somala, S.; Son, E. J.; Sonnenberg, J. A.; Sorazu, B.; Sorrentino, F.; Souradeep, T.; Spencer, A. P.; Srivastava, A. K.; Staats, K.; Staley, A.; Steinke, M.; Steinlechner, J.; Steinlechner, S.; Steinmeyer, D.; Stevenson, S. P.; Stone, R.; Stops, D. J.; Strain, K. A.; Stratta, G.; Strigin, S. E.; Strunk, A.; Sturani, R.; Stuver, A. L.; Summerscales, T. Z.; Sun, L.; Sunil, S.; Suresh, J.; Sutton, P. J.; Swinkels, B. L.; Szczepańczyk, M. J.; Tacca, M.; Tait, S. C.; Talbot, C.; Talukder, D.; Tanner, D. B.; Tápai, M.; Taracchini, A.; Tasson, J. D.; Taylor, J. A.; Taylor, R.; Tewari, S. V.; Theeg, T.; Thies, F.; Thomas, E. G.; Thomas, M.; Thomas, P.; Thorne, K. A.; Thrane, E.; Tiwari, S.; Tiwari, V.; Tokmakov, K. V.; Toland, K.; Tonelli, M.; Tornasi, Z.; Torres-Forné, A.; Torrie, C. I.; Töyrä, D.; Travasso, F.; Traylor, G.; Trinastic, J.; Tringali, M. C.; Trozzo, L.; Tsang, K. W.; Tse, M.; Tso, R.; Tsukada, L.; Tsuna, D.; Tuyenbayev, D.; Ueno, K.; Ugolini, D.; Unnikrishnan, C. S.; Urban, A. L.; Usman, S. A.; Vahlbruch, H.; Vajente, G.; Valdes, G.; van Bakel, N.; van Beuzekom, M.; van den Brand, J. F. J.; Van Den Broeck, C.; Vander-Hyde, D. C.; van der Schaaf, L.; van Heijningen, J. V.; van Veggel, A. A.; Vardaro, M.; Varma, V.; Vass, S.; Vasúth, M.; Vecchio, A.; Vedovato, G.; Veitch, J.; Veitch, P. J.; Venkateswara, K.; Venugopalan, G.; Verkindt, D.; Vetrano, F.; Viceré, A.; Viets, A. D.; Vinciguerra, S.; Vine, D. J.; Vinet, J.-Y.; Vitale, S.; Vo, T.; Vocca, H.; Vorvick, C.; Vyatchanin, S. P.; Wade, A. R.; Wade, L. E.; Wade, M.; Walet, R.; Walker, M.; Wallace, L.; Walsh, S.; Wang, G.; Wang, H.; Wang, J. Z.; Wang, W. H.; Wang, Y. F.; Ward, R. L.; Warner, J.; Was, M.; Watchi, J.; Weaver, B.; Wei, L.-W.; Weinert, M.; Weinstein, A. J.; Weiss, R.; Wen, L.; Wessel, E. K.; Weßels, P.; Westerweck, J.; Westphal, T.; Wette, K.; Whelan, J. T.; Whiting, B. F.; Whittle, C.; Wilken, D.; Williams, D.; Williams, R. D.; Williamson, A. R.; Willis, J. L.; Willke, B.; Wimmer, M. H.; Winkler, W.; Wipf, C. C.; Wittel, H.; Woan, G.; Woehler, J.; Wofford, J.; Wong, K. W. K.; Worden, J.; Wright, J. L.; Wu, D. S.; Wysocki, D. M.; Xiao, S.; Yamamoto, H.; Yancey, C. C.; Yang, L.; Yap, M. J.; Yazback, M.; Yu, Hang; Yu, Haocun; Yvert, M.; Zadrożny, A.; Zanolin, M.; Zelenova, T.; Zendri, J.-P.; Zevin, M.; Zhang, L.; Zhang, M.; Zhang, T.; Zhang, Y.-H.; Zhao, C.; Zhou, M.; Zhou, Z.; Zhu, S. J.; Zhu, X. J.; Zimmerman, A. B.; Zucker, M. E.; Zweizig, J.; (LIGO Scientific Collaboration; Virgo Collaboration

2017-12-01

The source of the gravitational-wave (GW) signal GW170817, very likely a binary neutron star merger, was also observed electromagnetically, providing the first multi-messenger observations of this type. The two-week-long electromagnetic (EM) counterpart had a signature indicative of an r-process-induced optical transient known as a kilonova. This Letter examines how the mass of the dynamical ejecta can be estimated without a direct electromagnetic observation of the kilonova, using GW measurements and a phenomenological model calibrated to numerical simulations of mergers with dynamical ejecta. Specifically, we apply the model to the binary masses inferred from the GW measurements, and use the resulting mass of the dynamical ejecta to estimate its contribution (without the effects of wind ejecta) to the corresponding kilonova light curves from various models. The distributions of dynamical ejecta mass range between {M}{ej}={10}-3-{10}-2 {M}⊙ for various equations of state, assuming that the neutron stars are rotating slowly. In addition, we use our estimates of the dynamical ejecta mass and the neutron star merger rates inferred from GW170817 to constrain the contribution of events like this to the r-process element abundance in the Galaxy when ejecta mass from post-merger winds is neglected. We find that if ≳10% of the matter dynamically ejected from binary neutron star (BNS) mergers is converted to r-process elements, GW170817-like BNS mergers could fully account for the amount of r-process material observed in the Milky Way.

Nuclear Masses in the A=80 Region of Nuclei

NASA Astrophysics Data System (ADS)

Cuka, N.; Gadala-Maria, A.; Aprahamian, A.

1996-05-01

Nucleosynthesis in explosive hydrogen burning at high temperatures above 8x10^8 K is characterized by the rp-process. A recent study^1 of the reaction flow and their associated time scales showed that the reaction path may in fact proceed well beyond the A=80 region of nuclei. An accurate simulation of the nucleosynthesis and energy generation of this process strongly depends on reliable nuclear physics input parameters such as masses, lifetimes, and reaction rates. We have extended the use of the simple P-parametrization^2,3 that had been applied to the characterization of the structure contributions to the nuclear masses in the actinides to include the A=80 region. The results will be presented along with predictions of masses for presently unknown masses of nuclei along the rp-process path. ^1 R. Wallace and S. Woosley, Ap. J. Suppl. 45, 389 (81). ^2 R. F. Casten, D.S. Brenner and P.E. Haustein, Phys. Rev. Lett. 58, 658 (87). ^3 P. Haustein, D.S. Brenner and R.F. Casten, Phys. Rev. C 38, 467 (88).

BatMass: a Java Software Platform for LC-MS Data Visualization in Proteomics and Metabolomics.

PubMed

Avtonomov, Dmitry M; Raskind, Alexander; Nesvizhskii, Alexey I

2016-08-05

Mass spectrometry (MS) coupled to liquid chromatography (LC) is a commonly used technique in metabolomic and proteomic research. As the size and complexity of LC-MS-based experiments grow, it becomes increasingly more difficult to perform quality control of both raw data and processing results. In a practical setting, quality control steps for raw LC-MS data are often overlooked, and assessment of an experiment's success is based on some derived metrics such as "the number of identified compounds". The human brain interprets visual data much better than plain text, hence the saying "a picture is worth a thousand words". Here, we present the BatMass software package, which allows for performing quick quality control of raw LC-MS data through its fast visualization capabilities. It also serves as a testbed for developers of LC-MS data processing algorithms by providing a data access library for open mass spectrometry file formats and a means of visually mapping processing results back to the original data. We illustrate the utility of BatMass with several use cases of quality control and data exploration.

BatMass: a Java software platform for LC/MS data visualization in proteomics and metabolomics

PubMed Central

Avtonomov, Dmitry; Raskind, Alexander; Nesvizhskii, Alexey I.

2017-01-01

Mass spectrometry (MS) coupled to liquid chromatography (LC) is a commonly used technique in metabolomic and proteomic research. As the size and complexity of LC/MS based experiments grow, it becomes increasingly more difficult to perform quality control of both raw data and processing results. In a practical setting, quality control steps for raw LC/MS data are often overlooked and assessment of an experiment's success is based on some derived metrics such as “the number of identified compounds”. Human brain interprets visual data much better than plain text, hence the saying “a picture is worth a thousand words”. Here we present BatMass software package which allows to perform quick quality control of raw LC/MS data through its fast visualization capabilities. It also serves as a testbed for developers of LC/MS data processing algorithms by providing a data access library for open mass spectrometry file formats and a means of visually mapping processing results back to the original data. We illustrate the utility of BatMass with several use cases of quality control and data exploration. PMID:27306858

Oxygen production System Models for Lunar ISRU

NASA Technical Reports Server (NTRS)

Santiago-Maldonado, Edgardo

2007-01-01

In-Situ Resource Utilization (ISRU) seeks to make human space exploration feasible; by using available resources from a planet or the moon to produce consumables, parts, and structures that otherwise would be brought from Earth. Producing these in situ reduces the mass of such that must be launched and doing so allows more payload mass' for each mission. The production of oxygen from lunar regolith, for life support and propellant, is one of the tasks being studied under ISRU. NASA is currently funding three processes that have shown technical merit for the production of oxygen from regolith: Molten Salt Electrolysis, Hydrogen Reduction of Ilmenite, and Carbothermal Reduction. The ISRU program is currently developing system models of, the , abovementioned processes to: (1) help NASA in the evaluation process to select the most cost-effective and efficient process for further prototype development, (2) identify key parameters, (3) optimize the oxygen production process, (4) provide estimates on energy and power requirements, mass and volume.of the system, oxygen production rate, mass of regolith required, mass of consumables, and other important parameters, and (5) integrate into the overall end-to-end ISRU system model, which could be integrated with mission architecture models. The oxygen production system model is divided into modules that represent unit operations (e.g., reactor, water electrolyzer, heat exchanger). Each module is modeled theoretically using Excel and Visual Basic for Applications (VBA), and will be validated using experimental data from on-going laboratory work. This modularity (plug-n-play) feature of each unit operation allows the use of the same model on different oxygen production systems simulations resulting in comparable results. In this presentation, preliminary results for mass, power, volume will be presented along with brief description of the oxygen production system model.

Constraints on the spin evolution of young planetary-mass companions

NASA Astrophysics Data System (ADS)

Bryan, Marta L.; Benneke, Björn; Knutson, Heather A.; Batygin, Konstantin; Bowler, Brendan P.

2018-02-01

Surveys of young star-forming regions have discovered a growing population of planetary-mass (<13 MJup) companions around young stars1. There is an ongoing debate as to whether these companions formed like planets (that is, from the circumstellar disk)2, or if they represent the low-mass tail of the star-formation process3. In this study, we utilize high-resolution spectroscopy to measure rotation rates of three young (2-300 Myr) planetary-mass companions and combine these measurements with published rotation rates for two additional companions4,5 to provide a picture of the spin distribution of these objects. We compare this distribution to complementary rotation-rate measurements for six brown dwarfs with masses <20 MJup, and show that these distributions are indistinguishable. This suggests that either these two populations formed via the same mechanism, or that processes regulating rotation rates are independent of formation mechanism. We find that rotation rates for both populations are well below their break-up velocities and do not evolve significantly during the first few hundred million years after the end of accretion. This suggests that rotation rates are set during the late stages of accretion, possibly by interactions with a circumplanetary disk. This result has important implications for our understanding of the processes regulating the angular momentum evolution of young planetary-mass objects, and of the physics of gas accretion and disk coupling in the planetary-mass regime.

40 CFR 63.4371 - What definitions apply to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... wiper blades. Thus, it includes any cleaning material used in the web coating and printing subcategory... process operation run at atmospheric pressure would be a different operating scenario from the same dyeing process operation run under pressure. Organic HAP content means the mass of organic HAP per mass of solids...

40 CFR 63.4371 - What definitions apply to this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

... wiper blades. Thus, it includes any cleaning material used in the web coating and printing subcategory... process operation run at atmospheric pressure would be a different operating scenario from the same dyeing process operation run under pressure. Organic HAP content means the mass of organic HAP per mass of solids...

40 CFR 63.4371 - What definitions apply to this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

... wiper blades. Thus, it includes any cleaning material used in the web coating and printing subcategory... process operation run at atmospheric pressure would be a different operating scenario from the same dyeing process operation run under pressure. Organic HAP content means the mass of organic HAP per mass of solids...

40 CFR 63.4371 - What definitions apply to this subpart?

Code of Federal Regulations, 2014 CFR

2014-07-01

... wiper blades. Thus, it includes any cleaning material used in the web coating and printing subcategory... process operation run at atmospheric pressure would be a different operating scenario from the same dyeing process operation run under pressure. Organic HAP content means the mass of organic HAP per mass of solids...

40 CFR 63.4371 - What definitions apply to this subpart?

Code of Federal Regulations, 2013 CFR

2013-07-01

... wiper blades. Thus, it includes any cleaning material used in the web coating and printing subcategory... process operation run at atmospheric pressure would be a different operating scenario from the same dyeing process operation run under pressure. Organic HAP content means the mass of organic HAP per mass of solids...

Processing of Mass/Count Information in Alzheimer's Disease and Mild Cognitive Impairment

ERIC Educational Resources Information Center

Taler, Vanessa; Jarema, Gonia

2004-01-01

This study examines the processing of a specific linguistic distinction, the mass/count distinction, in patients suffering from Alzheimer's disease (AD) and mild cognitive impairment (MCI). Fourteen AD and 10 MCI subjects were tested using a sentence grammaticality judgement task where grammaticality violations were caused by determiner--noun…

Mass Measurements of Proton-Rich Isotopes between Mo and Pd using the Canadian Penning Trap Mass Spectrometer

NASA Astrophysics Data System (ADS)

Fallis, J.; Sharma, K. S.; Sharma, H.; Savard, G.; Levand, A. F.; Sun, T.; Clark, J. A.; Deibel, C.; Parikh, A.; Wrede, C.; Lascar, D.; Segel, R.; Caldwell, S.; Sternberg, M.; van Schelt, J.; Buchinger, F.; Crawford, J. E.; Gulick, S.; Lee, J. K. P.; Li, G.; Scielzo, N. D.; Hecht, A. A.

2008-04-01

In our understanding of the origin of elemental abundances the means of producing the observed abundances of ^92Mo and ^94Mo have long been unknown. These ``light p'' nuclei cannot be adequately produced by the classic p-process alone. The νp-process however, which occurs due to the neutrino wind in core collapse supernovae explosions, involves both proton-capture and neutron-capture reactions and can produce ^92Mo and ^94Mo. The final abundances of these isotopes depend directly on the values of the proton separation energies, Sp, along the reaction path of this process. Recent mass measurements performed with the Canadian Penning Trap Mass Spectrometer have dramatically reduced the uncertainties of Sp values of proton-rich nuclei between Mo and Pd. These measurements and the resulting implications for both the νp-process path and the ^92Mo/^94Mo abundance ratio will be discussed. This work was supported by grants from NSERC, Canada and the U.S. DOE, Nucl. Phys. Div.,under Contract W-31-109-ENG-38

Justification of process of loading coal onto face conveyors by auger heads of shearer-loader machines

NASA Astrophysics Data System (ADS)

Nguyen, K. L.; Gabov, V. V.; Zadkov, D. A.; Le, T. B.

2018-03-01

This paper analyzes the processes of removing coal from the area of its dislodging and loading the disintegrated mass onto face conveyors by auger heads of shearer-loader machines. The loading process is assumed to consist of four subprocesses: dislodging coal, removal of the disintegrated mass by auger blades from the crushing area, passive transportation of the disintegrated mass, and forming the load flow on the bearing surface of a face conveyor. Each of the considered subprocesses is different in its physical nature, the number of factors influencing it, and can be complex or multifactor. Possibilities of improving the efficiency of loading coal onto a face conveyor are addressed. The selected criteria of loading efficiency are load rate, specific energy consumption, and coal size reduction. Efficiency is improved by reducing the resistance to movement of the disintegrated mass during loading by increasing the area of the loading window section and the volume of the loading area on the conveyor, as well as by coordination of intensity of flows related to the considered processes in local areas.

On-field study of anaerobic digestion full-scale plants (part I): an on-field methodology to determine mass, carbon and nutrients balance.

PubMed

Schievano, Andrea; D'Imporzano, Giuliana; Salati, Silvia; Adani, Fabrizio

2011-09-01

The mass balance (input/output mass flows) of full-scale anaerobic digestion (AD) processes should be known for a series of purposes, e.g. to understand carbon and nutrients balances, to evaluate the contribution of AD processes to elemental cycles, especially when digestates are applied to agricultural land and to measure the biodegradation yields and the process efficiency. In this paper, three alternative methods were studied, to determine the mass balance in full-scale processes, discussing their reliability and applicability. Through a 1-year survey on three full-scale AD plants and through 38 laboratory-scale batch digesters, the congruency of the considered methods was demonstrated and a linear equation was provided that allows calculating the wet weight losses (WL) from the methane produced (MP) by the plant (WL=41.949*MP+20.853, R(2)=0.950, p<0.01). Additionally, this new tool was used to calculate carbon, nitrogen, phosphorous and potassium balances of the three observed AD plants. Copyright © 2011 Elsevier Ltd. All rights reserved.

"EMERGING" POLLUTANTS, MASS SPECTROMETRY, AND COMMUNICATING SCIENCE: PHARMACEUTICALS IN THE ENVIRONMENT

EPA Science Inventory

A foundation for Environmental Science - Mass Spectrometry: Historically fundamental to amassing our understanding of environmental processes and chemical pollution is the realm of mass spectrometry - the mainstay of analytical chemistry - the workhorse that supplies much of the...

An RFID-Based Manufacturing Control Framework for Loosely Coupled Distributed Manufacturing System Supporting Mass Customization

NASA Astrophysics Data System (ADS)

Chen, Ruey-Shun; Tsai, Yung-Shun; Tu, Arthur

In this study we propose a manufacturing control framework based on radio-frequency identification (RFID) technology and a distributed information system to construct a mass-customization production process in a loosely coupled shop-floor control environment. On the basis of this framework, we developed RFID middleware and an integrated information system for tracking and controlling the manufacturing process flow. A bicycle manufacturer was used to demonstrate the prototype system. The findings of this study were that the proposed framework can improve the visibility and traceability of the manufacturing process as well as enhance process quality control and real-time production pedigree access. Using this framework, an enterprise can easily integrate an RFID-based system into its manufacturing environment to facilitate mass customization and a just-in-time production model.

A High-Resolution Model of Water Mass Transformation and Transport in the Weddell Sea

NASA Astrophysics Data System (ADS)

Hazel, J.; Stewart, A.

2016-12-01

The ocean circulation around the Antarctic margins has a pronounced impact on the global ocean and climate system. One of these impacts includes closing the global meridional overturning circulation (MOC) via formation of dense Antarctic Bottom Water (AABW), which ventilates a large fraction of the subsurface ocean. AABW is also partially composed of modified Circumpolar Deep Water (CDW), a warm, mid-depth water mass whose transport towards the continent has the potential to induce rapid retreat of marine-terminating glaciers. Previous studies suggest that these water mass exchanges may be strongly influenced by high-frequency processes such as downslope gravity currents, tidal flows, and mesoscale/submesoscale eddy transport. However, evaluating the relative contributions of these processes to near-Antarctic water mass transports is hindered by the region's relatively small scales of motion and the logistical difficulties in taking measurements beneath sea ice.In this study we develop a regional model of the Weddell Sea, the largest established source of AABW. The model is forced by an annually-repeating atmospheric state constructed from the Antarctic Mesoscale Prediction System data and by annually-repeating lateral boundary conditions constructed from the Southern Ocean State Estimate. The model incorporates the full Filchner-Ronne cavity and simulates the thermodynamics and dynamics of sea ice. To analyze the role of high-frequency processes in the transport and transformation of water masses, we compute the model's overturning circulation, water mass transformations, and ice sheet basal melt at model horizontal grid resolutions ranging from 1/2 degree to 1/24 degree. We temporally decompose the high-resolution (1/24 degree) model circulation into components due to mean, eddy and tidal flows and discuss the geographical dependence of these processes and their impact on water mass transformation and transport.

The mesoscale forcing of a midlatitude upper-tropospheric jet streak by a simulated convective system. 1: Mass circulation and ageostrophic processes

NASA Technical Reports Server (NTRS)

Wolf, Bart J.; Johnson, D. R.

1995-01-01

The mutual forcing of a midlatitude upper-tropospheric jet streak by organized mesoscale adiabatic and diabatic processes within a simulated convective system (SCS) is investigated. Using isentropic diagnostics, results from a three-dimensional numerical simulation of an SCS are examined to study the isallobaric flow field, modes of dominant ageostrophic motion, and stability changes in relation to the mutual interdependence of adiabatic processes and latent heat release. Isentropic analysis affords an explicit isolation of a component of isallobaric flow associated with diabatic processes within the SCS. Prior to convective development within the simulations, atmospheric destabilization occurs through adiabatic ageostrophic mass adjustment and low-level convergence in association with the preexisting synoptic-scale upper-tropospheric jet streak. The SCS develops in a baroclinic zone and quickly initiates a vigorous mass circulation. By the mature stage, a pronounced vertical couplet of low-level convergence and upper-level mass divergence is established, linked by intense midtropospoheric diabatic heating. Significant divergence persists aloft for several hours subsequent to SCS decay. The dominant role of ageostrophic motion within which the low-level mass convergence develops is the adiabatic isallobaric component, while the mass divergence aloft develops principally through the diabatic isallobaric component. Both compnents are intrinsically linked to the convectively forced vertical mass transport. The inertial diabatic ageostrophic component is largest near the level of maximum heating and is responsible for the development of inertial instability to the north of SCS, resulting in this quadrant being preferred for outflow. The inertial advective component, the dominant term that produces the new downstream wind maximum, rapidly develops north of the SCS and through mutual adjustment creates the baroclinic support for the new jet streak.

Using the Earth as a guide to martian mass movement processes: From form to process

NASA Astrophysics Data System (ADS)

Lanza, N.; Newsom, H. E.; Osterloo, M. M.; Okubo, C. H.

2011-12-01

The discovery of gully features on Mars has led to renewed interest in hillslope processes on that planet, in particular mass movement and the morphologies that it produces. Mass movement is a collection of gravity-driven processes that act to move materials down a hillslope. Here, we examine how mass movements on hillslopes may be expected to differ on Earth and Mars as the result of gravity differences between these planets. Downslope movement of unconsolidated materials is generally controlled by the bulk shear strength of these materials. Although the relationship between gravity and shear strength is largely dependent on variables that are independent of gravity, the lower gravity on Mars is expected to produce some systematic changes in mass movement behaviors that may in turn create morphological features that are observably different from their terrestrial counterparts. After scaling for gravity and modifying empirically derived relationships, we may expect the following differences on martian hillslopes when compared to their terrestrial counterparts: ==On Mars, hillslopes may have steeper angles of repose in fine grained (< ~2 mm) materials, even when dry. No change in angle of repose is expected for larger particles; ==An increase in soil moisture content (e.g., excess pore pressure) is expected to weaken unconsolidated slope materials more on Mars for a particular regolith type, which in turn may produce --An increase in creep rates for a given pore pressure, and --An increase in effectiveness of frost heave to transport materials downslope; ==Processes triggered by saturation may occur at lower pore pressures on Mars; --A smaller amount of fluid is needed to achieve failure; ==Shorter runout lengths are expected for rapid mass movements; ==On Mars, overland flow will exert a proportionally lower shear stress on slope materials; --In cohesive materials, the same volume of water will detach sediments of smaller sizes. On Earth, mass movement processes may be directly observed and measured as they occur, whereas on Mars only the resultant landforms may be studied at present. By understanding how martian hillslope processes are expected to be modified by lower gravity, the interpretation of martian landforms may be greatly aided. Examples of observations that support some of these predicted differences will be presented, with a focus on saturation-triggered events in unconsolidated materials.

Oxidation reactions of solid carbonaceous and resinous substances in supercritical water

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koda, S.

Recent kinetic studies, particularly those by means of shadowgraphy and X-ray radiography, for supercritical water oxidation of solid carbonaceous and resinous substances have revealed the importance of the O{sub 2} mass transfer process over the intrinsic surface reaction at higher temperatures. The mass transfer processes, internal and external one, should be incorporated in designing SCWO processes for solid substances and related processes such as catalytic SCWO. Some model calculation efforts of late are briefly described. Finally, fundamental information required for future development is itemed.

Processing of higher count rates in Troitsk nu-mass experiment

NASA Astrophysics Data System (ADS)

Nozik, Alexander; Chernov, Vaslily

2018-04-01

In this article we give a short outline of current status of search for sterile neutrinos with masses up to 4 keV in "Troitsk nu-mass experiment". We also discuss major sources of systematic uncertainties and methods to lower them.

COMPARATIVE EVALUATION OF GC/MS (GAS CHROMATOGRAPHY/MASS SPECTROMETRY) DATA ANALYSIS PROCESSING

EPA Science Inventory

Mass spectra obtained by fused silica capillary gas chromatography/mass spectrometry/data system (GC/MS/DS) analysis of mixtures of organic chemicals adsorbed on Tenax GC cartridges was subjected to manual and automated interpretative techniques. Synthetic mixtures (85 chemicals ...

Martian resource utilization. 1: Plant design and transportation selection criteria

NASA Technical Reports Server (NTRS)

Kaloupis, Peter; Nolan, Peter E.; Cutler, Andrew H.

1992-01-01

Indigenous Space Materials Utilization (ISMU) provides an opportunity to make Mars exploration mission scenarios more affordable by reducing the initial mass necessary in Low Earth Orbit (LEO). Martian propellant production is discussed in terms of simple design and economic tradeoffs. Fuel and oxidizer combinations included are H2/O2, CH4/O2, and CO/O2. Process flow diagrams with power and mass flow requirements are presented for a variety of processes, and some design requirements are derived. Maximum allowable plant masses for single use amortization are included.

Martian resource utilization. 1: Plant design and transportation selection criteria

NASA Astrophysics Data System (ADS)

Kaloupis, Peter; Nolan, Peter E.; Cutler, Andrew H.

Indigenous Space Materials Utilization (ISMU) provides an opportunity to make Mars exploration mission scenarios more affordable by reducing the initial mass necessary in Low Earth Orbit (LEO). Martian propellant production is discussed in terms of simple design and economic tradeoffs. Fuel and oxidizer combinations included are H2/O2, CH4/O2, and CO/O2. Process flow diagrams with power and mass flow requirements are presented for a variety of processes, and some design requirements are derived. Maximum allowable plant masses for single use amortization are included.

DEUTERIUM BURNING IN MASSIVE GIANT PLANETS AND LOW-MASS BROWN DWARFS FORMED BY CORE-NUCLEATED ACCRETION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bodenheimer, Peter; D'Angelo, Gennaro; Lissauer, Jack J.

Using detailed numerical simulations, we study the formation of bodies near the deuterium-burning limit according to the core-nucleated giant planet accretion scenario. The objects, with heavy-element cores in the range 5-30 M{sub Circled-Plus }, are assumed to accrete gas up to final masses of 10-15 Jupiter masses (M{sub Jup}). After the formation process, which lasts 1-5 Myr and which ends with a ''cold-start'', low-entropy configuration, the bodies evolve at constant mass up to an age of several Gyr. Deuterium burning via proton capture is included in the calculation, and we determined the mass, M{sub 50}, above which more than 50%more » of the initial deuterium is burned. This often-quoted borderline between giant planets and brown dwarfs is found to depend only slightly on parameters, such as core mass, stellar mass, formation location, solid surface density in the protoplanetary disk, disk viscosity, and dust opacity. The values for M{sub 50} fall in the range 11.6-13.6 M{sub Jup}, in agreement with previous determinations that do not take the formation process into account. For a given opacity law during the formation process, objects with higher core masses form more quickly. The result is higher entropy in the envelope at the completion of accretion, yielding lower values of M{sub 50}. For masses above M{sub 50}, during the deuterium-burning phase, objects expand and increase in luminosity by one to three orders of magnitude. Evolutionary tracks in the luminosity versus time diagram are compared with the observed position of the companion to Beta Pictoris.« less

Quantifying Tropical Glacier Mass Balance Sensitivity to Climate Change Through Regional-Scale Modeling and The Randolph Glacier Inventory

NASA Astrophysics Data System (ADS)

Malone, A.

2017-12-01

Quantifying mass balance sensitivity to climate change is essential for forecasting glacier evolution and deciphering climate signals embedded in archives of past glacier changes. Ideally, these quantifications result from decades of field measurement, remote sensing, and a hierarchy modeling approach, but in data-sparse regions, such as the Himalayas and tropical Andes, regional-scale modeling rooted in first principles provides a first-order picture. Previous regional-scaling modeling studies have applied a surface energy and mass balance approach in order to quantify equilibrium line altitude sensitivity to climate change. In this study, an expanded regional-scale surface energy and mass balance model is implemented to quantify glacier-wide mass balance sensitivity to climate change for tropical Andean glaciers. Data from the Randolph Glacier Inventory are incorporated, and additional physical processes are included, such as a dynamic albedo and cloud-dependent atmospheric emissivity. The model output agrees well with the limited mass balance records for tropical Andean glaciers. The dominant climate variables driving interannual mass balance variability differ depending on the climate setting. For wet tropical glaciers (annual precipitation >0.75 m y-1), temperature is the dominant climate variable. Different hypotheses for the processes linking wet tropical glacier mass balance variability to temperature are evaluated. The results support the hypothesis that glacier-wide mass balance on wet tropical glaciers is largely dominated by processes at the lowest elevation where temperature plays a leading role in energy exchanges. This research also highlights the transient nature of wet tropical glaciers - the vast majority of tropical glaciers and a vital regional water resource - in an anthropogenic warming world.

Comparison of oil refining and biodiesel production process between screw press and n-hexane techniques from beauty leaf feedstock

NASA Astrophysics Data System (ADS)

Bhuiya, M. M. K.; Rasul, M. G.; Khan, M. M. K.; Ashwath, N.

2016-07-01

The Beauty Leaf Tree (Callophylum inophyllum) is regarded as an alternative source of energy to produce 2nd generation biodiesel due to its potentiality as well as high oil yield content in the seed kernels. The treating process is indispensable during the biodiesel production process because it can augment the yield as well as quality of the product. Oil extracted from both mechanical screw press and solvent extraction using n-hexane was refined. Five replications each of 25 gm of crude oil for screw press and five replications each of 25 gm of crude oil for n-hexane were selected for refining as well as biodiesel conversion processes. The oil refining processes consists of degumming, neutralization as well as dewaxing. The degumming, neutralization and dewaxing processes were performed to remove all the gums (phosphorous-based compounds), free fatty acids, and waxes from the fresh crude oil before the biodiesel conversion process carried out, respectively. The results indicated that up to 73% and 81% of mass conversion efficiency of the refined oil in the screw press and n-hexane refining processes were obtained, respectively. It was also found that up to 88% and 90% of biodiesel were yielded in terms of mass conversion efficiency in the transesterification process for the screw press and n-hexane techniques, respectively. While the entire processes (refining and transesterification) were considered, the conversion of beauty leaf tree (BLT) refined oil into biodiesel was yielded up to 65% and 73% of mass conversion efficiency for the screw press and n-hexane techniques, respectively. Physico-chemical properties of crude and refined oil, and biodiesel were characterized according to the ASTM standards. Overall, BLT has the potential to contribute as an alternative energy source because of high mass conversion efficiency.

Two-structured solid particle model for predicting and analyzing supercritical extraction performance.

PubMed

Samadi, Sara; Vaziri, Behrooz Mahmoodzadeh

2017-07-14

Solid extraction process, using the supercritical fluid, is a modern science and technology, which has come in vogue regarding its considerable advantages. In the present article, a new and comprehensive model is presented for predicting the performance and separation yield of the supercritical extraction process. The base of process modeling is partial differential mass balances. In the proposed model, the solid particles are considered twofold: (a) particles with intact structure, (b) particles with destructed structure. A distinct mass transfer coefficient has been used for extraction of each part of solid particles to express different extraction regimes and to evaluate the process accurately (internal mass transfer coefficient was used for the intact-structure particles and external mass transfer coefficient was employed for the destructed-structure particles). In order to evaluate and validate the proposed model, the obtained results from simulations were compared with two series of available experimental data for extraction of chamomile extract with supercritical carbon dioxide, which had an excellent agreement. This is indicative of high potentiality of the model in predicting the extraction process, precisely. In the following, the effect of major parameters on supercritical extraction process, like pressure, temperature, supercritical fluid flow rate, and the size of solid particles was evaluated. The model can be used as a superb starting point for scientific and experimental applications. Copyright © 2017 Elsevier B.V. All rights reserved.

EFFECT OF ENVIRONMENT ON GALAXIES' MASS-SIZE DISTRIBUTION: UNVEILING THE TRANSITION FROM OUTSIDE-IN TO INSIDE-OUT EVOLUTION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cappellari, Michele

2013-11-20

The distribution of galaxies on the mass-size plane as a function of redshift or environment is a powerful test for galaxy formation models. Here we use integral-field stellar kinematics to interpret the variation of the mass-size distribution in two galaxy samples spanning extreme environmental densities. The samples are both identically and nearly mass-selected (stellar mass M {sub *} ≳ 6 × 10{sup 9} M {sub ☉}) and volume-limited. The first consists of nearby field galaxies from the ATLAS{sup 3D} parent sample. The second consists of galaxies in the Coma Cluster (Abell 1656), one of the densest environments for which good, resolvedmore » spectroscopy can be obtained. The mass-size distribution in the dense environment differs from the field one in two ways: (1) spiral galaxies are replaced by bulge-dominated disk-like fast-rotator early-type galaxies (ETGs), which follow the same mass-size relation and have the same mass distribution as in the field sample; (2) the slow-rotator ETGs are segregated in mass from the fast rotators, with their size increasing proportionally to their mass. A transition between the two processes appears around the stellar mass M {sub crit} ≈ 2 × 10{sup 11} M {sub ☉}. We interpret this as evidence for bulge growth (outside-in evolution) and bulge-related environmental quenching dominating at low masses, with little influence from merging. In contrast, significant dry mergers (inside-out evolution) and halo-related quenching drives the mass and size growth at the high-mass end. The existence of these two processes naturally explains the diverse size evolution of galaxies of different masses and the separability of mass and environmental quenching.« less

Mass Detection in Mammographic Images Using Wavelet Processing and Adaptive Threshold Technique.

PubMed

Vikhe, P S; Thool, V R

2016-04-01

Detection of mass in mammogram for early diagnosis of breast cancer is a significant assignment in the reduction of the mortality rate. However, in some cases, screening of mass is difficult task for radiologist, due to variation in contrast, fuzzy edges and noisy mammograms. Masses and micro-calcifications are the distinctive signs for diagnosis of breast cancer. This paper presents, a method for mass enhancement using piecewise linear operator in combination with wavelet processing from mammographic images. The method includes, artifact suppression and pectoral muscle removal based on morphological operations. Finally, mass segmentation for detection using adaptive threshold technique is carried out to separate the mass from background. The proposed method has been tested on 130 (45 + 85) images with 90.9 and 91 % True Positive Fraction (TPF) at 2.35 and 2.1 average False Positive Per Image(FP/I) from two different databases, namely Mammographic Image Analysis Society (MIAS) and Digital Database for Screening Mammography (DDSM). The obtained results show that, the proposed technique gives improved diagnosis in the early breast cancer detection.

Identification of isomers and control of ionization and dissociation processes using dual-mass-spectrometer scheme and genetic algorithm optimization

NASA Astrophysics Data System (ADS)

Chen, Zhou; Tong, Qiu-Nan; Zhang, Cong-Cong; Hu, Zhan

2015-04-01

Identification of acetone and its two isomers, and the control of their ionization and dissociation processes are performed using a dual-mass-spectrometer scheme. The scheme employs two sets of time of flight mass spectrometers to simultaneously acquire the mass spectra of two different molecules under the irradiation of identically shaped femtosecond laser pulses. The optimal laser pulses are found using closed-loop learning method based on a genetic algorithm. Compared with the mass spectra of the two isomers that are obtained with the transform limited pulse, those obtained under the irradiation of the optimal laser pulse show large differences and the various reaction pathways of the two molecules are selectively controlled. The experimental results demonstrate that the scheme is quite effective and useful in studies of two molecules having common mass peaks, which makes a traditional single mass spectrometer unfeasible. Project supported by the National Basic Research Program of China (Grant No. 2013CB922200) and the National Natural Science Foundation of China (Grant No. 11374124).

Mass Accretion Processes in Young Stellar Objects: Role of Intense Flaring Activity

NASA Astrophysics Data System (ADS)

Orlando, Salvatore; Reale, Fabio; Peres, Giovanni; Mignone, Andrea

2014-11-01

According to the magnetospheric accretion scenario, young low-mass stars are surrounded by circumstellar disks which they interact with through accretion of mass. The accretion builds up the star to its final mass and is also believed to power the mass outflows, which may in turn have a signicant role in removing the excess angular momentum from the star-disk system. Although the process of mass accretion is a critical aspect of star formation, some of its mechanisms are still to be fully understood. On the other hand, strong flaring activity is a common feature of young stellar objects (YSOs). In the Sun, such events give rise to perturbations of the interplanetary medium. Similar but more energetic phenomena occur in YSOs and may influence the circumstellar environment. In fact, a recent study has shown that an intense flaring activity close to the disk may strongly perturb the stability of circumstellar disks, thus inducing mass accretion episodes (Orlando et al. 2011). Here we review the main results obtained in the field and the future perspectives.

On Illicit Economic Relations in the Sphere of Higher Education

ERIC Educational Resources Information Center

Shevchenko, I. O.; Gavrilov, A. A.

2007-01-01

These days, processes of corruption in colleges and universities are vividly reflected in the mass consciousness. In spite of numerous reports about these processes in the mass media, however, there are no exact data about the prevalence of bribery in higher education. Just what phenomena of bribery exist in higher education, and to what extent?…

Spent Nuclear Fuel (SNF) Project Canister Storage Building (CSB) Process Flow Diagram Mass Balance Calculations

DOE Office of Scientific and Technical Information (OSTI.GOV)

KLEM, M.J.

2000-05-11

The purpose of these calculations is to develop the material balances for documentation of the Canister Storage Building (CSB) Process Flow Diagram (PFD) and future reference. The attached mass balances were prepared to support revision two of the PFD for the CSB. The calculations refer to diagram H-2-825869.

Status quo and future research challenges on organic food quality determination with focus on laboratory methods.

PubMed

Kahl, Johannes; Bodroza-Solarov, Marija; Busscher, Nicolaas; Hajslova, Jana; Kneifel, Wolfgang; Kokornaczyk, Maria Olga; van Ruth, Saskia; Schulzova, Vera; Stolz, Peter

2014-10-01

Organic food quality determination needs multi-dimensional evaluation tools. The main focus is on the authentication as an analytical verification of the certification process. New fingerprinting approaches such as ultra-performance liquid chromatography-mass spectrometry, gas chromatography-mass spectrometry, direct analysis in real time-high-resolution mass spectrometry as well as crystallization with and without the presence of additives seem to be promising methods in terms of time of analysis and detecting organic system-related parameters. For further methodological development, a system approach is recommended, which also takes into account food structure aspects. Furthermore, the authentication of processed organic samples needs more consciousness, hence most of organic food is complex and processed. © 2013 Society of Chemical Industry.

Acetylene fuel from atmospheric CO2 on Mars

NASA Technical Reports Server (NTRS)

Landis, Geoffrey A.; Linne, Diane L.

1992-01-01

The Mars mission scenario proposed by Baker and Zubrin (1990) intended for an unmanned preliminary mission is extended to maximize the total impulse of fuel produced with a minimum mass of hydrogen from Earth. The hydrogen along with atmospheric carbon dioxide is processed into methane and oxygen by the exothermic reaction in an atmospheric processing module. Use of simple chemical reactions to produce acetylene/oxygen rocket fuel on Mars from hydrogen makes it possible to produce an amount of fuel that is nearly 100 times the mass of hydrogen brought from earth. If such a process produces the return propellant for a manned Mars mission, the required mission mass in LEO is significantly reduced over a system using all earth-derived propellants.

Permafrost on Mars: distribution, formation, and geological role

NASA Technical Reports Server (NTRS)

Nummedal, D.

1984-01-01

The morphology of channels, valleys, chaotic and fretted terrains and many smaller features on Mars is consistent with the hypothesis that localized deterioration of thick layers of ice-rich permafrost was a dominant geologic process on the Martian surface. Such ground ice deterioration gave rise to large-scale mass movement, including sliding, slumping and sediment gravity flowage, perhaps also catastropic floods. In contrast to Earth, such mass movement processes on Mars lack effective competition from erosion by surface runoff. Therefore, Martian features due to mass movement grew to reach immense size without being greatly modified by secondary erosional processes. The Viking Mission to Mars in 1976 provided adequate measurements of the relevant physical parameters to constrain models for Martian permafrost.

Using nonlinear programming to correct leakage and estimate mass change from GRACE observation and its application to Antarctica

NASA Astrophysics Data System (ADS)

Tang, Jingshi; Cheng, Haowen; Liu, Lin

2012-11-01

The Gravity Recovery And Climate Experiment (GRACE) mission has been providing high quality observations since its launch in 2002. Over the years, fruitful achievements have been obtained and the temporal gravity field has revealed the ongoing geophysical, hydrological and other processes. These discoveries help the scientists better understand various aspects of the Earth. However, errors exist in high degree and order spherical harmonics, which need to be processed before use. Filtering is one of the most commonly used techniques to smooth errors, yet it attenuates signals and also causes leakage of gravity signal into surrounding areas. This paper reports a new method to estimate the true mass change on the grid (expressed in equivalent water height or surface density). The mass change over the grid can be integrated to estimate regional or global mass change. This method assumes the GRACE-observed apparent mass change is only caused by the mass change on land. By comparing the computed and observed apparent mass change, the true mass change can be iteratively adjusted and estimated. The problem is solved with nonlinear programming (NLP) and yields solutions which are in good agreement with other GRACE-based estimates.

Determination of the System Mass and the Individual Masses of the Pluto System from New Horizons Radio Tracking

NASA Astrophysics Data System (ADS)

Hahn, Matthias; Pätzold, Martin; Andert, Tom; Bird, Michael K.; Tyler, Leonard G.; Linscott, Ivan; Hinson, Dave P.; Stern, Alan; Weaver, Hal; Olkin, Cathrin; Young, Leslie; Ennico, Kimberly

2015-11-01

One objective of the New Horizons Radio Science Experiment REX is the determination of the system mass and the individual masses of Pluto and Charon. About four weeks of two-way radio tracking centered around the closest approach of New Horizons to the Pluto system were processed. Major problems during the processing were caused by the small net forces of the spacecraft thruster activity, which produce extra Δv on the spacecraft motion superposed onto the continuously perturbed motion caused by the attracting forces of the Pluto system. The times of spacecraft thruster activity are known but the applied Δv needs to be specifically adjusted. No two-way tracking was available for the day of the flyby, but slots of REX one-way uplink tracking are used to cover the most important times near closest approach, e.g. during occultation entries and exits. This will help to separate the individual masses of Pluto and Charon from the system mass.

[Clinical application of mass spectrometry in the pediatric field: current topics].

PubMed

Yamaguchi, Seiji

2013-09-01

Mass spectrometry, including tandem mass spectrometry (MS/MS) and gas chromatography-mass spectrometry (GC/MS), is becoming prominent in the diagnosis of metabolic disorders in the pediatric field. It enables biochemical diagnosis of metabolic disorders from the metabolic profiles obtained by MS/MS and/or GC/MS. In neonatal mass screening for inherited metabolic disease (IMD) using MS/MS, amino acids and acylcarnitines on dried blood spots are analyzed. The target diseases include amino acidemia, urea cycle disorder, organic acidemia, and fatty acid oxidation disorder. In the MS/MS screening, organic acid analysis using GC/MS is required for differential and/or definite diagnosis of the IMDs. GC/MS data processing, however, is difficult, and metabolic diagnosis often requires the necessary skills and expertize. We developed an automated system of GC/MS data processing and autodiagnosis, and the biochemical diagnosis using GC/MS became markedly easier and user-friendly. Mass spectrometric techniques will expand from research laboratories to clinical laboratories in the near future.

Evaluation of resonating Si cantilevers sputter-deposited with AlN piezoelectric thin films for mass sensing applications

NASA Astrophysics Data System (ADS)

Sökmen, Ü.; Stranz, A.; Waag, A.; Ababneh, A.; Seidel, H.; Schmid, U.; Peiner, E.

2010-06-01

We report on a micro-machined resonator for mass sensing applications which is based on a silicon cantilever excited with a sputter-deposited piezoelectric aluminium nitride (AlN) thin film actuator. An inductively coupled plasma (ICP) cryogenic dry etching process was applied for the micro-machining of the silicon substrate. A shift in resonance frequency was observed, which was proportional to a mass deposited in an e-beam evaporation process on top. We had a mass sensing limit of 5.2 ng. The measurements from the cantilevers of the two arrays revealed a quality factor of 155-298 and a mass sensitivity of 120.34 ng Hz-1 for the first array, and a quality factor of 130-137 and a mass sensitivity of 104.38 ng Hz-1 for the second array. Furthermore, we managed to fabricate silicon cantilevers, which can be improved for the detection in the picogram range due to a reduction of the geometrical dimensions.

Black hole binaries dynamically formed in globular clusters

NASA Astrophysics Data System (ADS)

Park, Dawoo; Kim, Chunglee; Lee, Hyung Mok; Bae, Yeong-Bok; Belczynski, Krzysztof

2017-08-01

We investigate properties of black hole (BH) binaries formed in globular clusters via dynamical processes, using directN-body simulations. We pay attention to effects of BH mass function on the total mass and mass ratio distributions of BH binaries ejected from clusters. First, we consider BH populations with two different masses in order to learn basic differences from models with single-mass BHs only. Secondly, we consider continuous BH mass functions adapted from recent studies on massive star evolution in a low metallicity environment, where globular clusters are formed. In this work, we consider only binaries that are formed by three-body processes and ignore stellar evolution and primordial binaries for simplicity. Our results imply that most BH binary mergers take place after they get ejected from the cluster. Also, mass ratios of dynamically formed binaries should be close to 1 or likely to be less than 2:1. Since the binary formation efficiency is larger for higher-mass BHs, it is likely that a BH mass function sampled by gravitational-wave observations would be weighed towards higher masses than the mass function of single BHs for a dynamically formed population. Applying conservative assumptions regarding globular cluster populations such as small BH mass fraction and no primordial binaries, the merger rate of BH binaries originated from globular clusters is estimated to be at least 6.5 yr-1 Gpc-3. Actual rate can be up to more than several times of our conservative estimate.

Influences of Altered River Geomorphology on Channel-Floodplain Mass and Momentum Transfer

NASA Astrophysics Data System (ADS)

Byrne, C. F.; Stone, M. C.

2017-12-01

River management strategies, including both river engineering and restoration, have altered river geomorphology and associated lateral channel-floodplain connectivity throughout the world. This altered connectivity is known to drive changes in ecologic and geomorphic processes during floods, however, quantification of altered connectivity is difficult due to the highly dynamic spatial and temporal nature of flood wave conditions. The objective of this research was to quantify the physical processes of lateral mass and momentum transfer at the channel-floodplain interface. The objective was achieved with the implementation of novel scripting and high-resolution, two-dimensional hydrodynamic modeling techniques under unsteady flow conditions. The process-based analysis focused on three geomorphic feature types within the Middle Rio Grande, New Mexico, USA: (1) historical floodplain surfaces, (2) inset floodplain surfaces formed as a result of channel training and hydrologic alteration, and (3) mechanically restored floodplain surfaces. Results suggest that inset floodplain feature types are not only subject to greater mass and momentum transfer magnitudes, but those connections are also more heterogeneous in nature compared with historical feature types. While restored floodplain feature types exhibit transfer magnitudes and heterogeneity comparable to inset feature types, the surfaces are not of great enough spatial extent to substantially influence total channel-floodplain mass and momentum transfer. Mass and momentum transfer also displayed differing characteristic changes as a result of increased flood magnitude, indicating that linked hydrodynamic processes can be altered differently as a result of geomorphic and hydrologic change. The results display the potential of high-resolution modeling strategies in capturing the spatial and temporal complexities of river processes. In addition, the results have implications for other fields of river science including biogeochemical exchange at the channel-floodplain interface and quantification of process associated with environmental flow and river restoration strategies.

Origin of the heavy elements in binary neutron-star mergers from a gravitational-wave event.

PubMed

Kasen, Daniel; Metzger, Brian; Barnes, Jennifer; Quataert, Eliot; Ramirez-Ruiz, Enrico

2017-11-02

The cosmic origin of elements heavier than iron has long been uncertain. Theoretical modelling shows that the matter that is expelled in the violent merger of two neutron stars can assemble into heavy elements such as gold and platinum in a process known as rapid neutron capture (r-process) nucleosynthesis. The radioactive decay of isotopes of the heavy elements is predicted to power a distinctive thermal glow (a 'kilonova'). The discovery of an electromagnetic counterpart to the gravitational-wave source GW170817 represents the first opportunity to detect and scrutinize a sample of freshly synthesized r-process elements. Here we report models that predict the electromagnetic emission of kilonovae in detail and enable the mass, velocity and composition of ejecta to be derived from observations. We compare the models to the optical and infrared radiation associated with the GW170817 event to argue that the observed source is a kilonova. We infer the presence of two distinct components of ejecta, one composed primarily of light (atomic mass number less than 140) and one of heavy (atomic mass number greater than 140) r-process elements. The ejected mass and a merger rate inferred from GW170817 imply that such mergers are a dominant mode of r-process production in the Universe.

An Order Insertion Scheduling Model of Logistics Service Supply Chain Considering Capacity and Time Factors

PubMed Central

Yang, Yi; Wang, Shuqing; Liu, Yang

2014-01-01

Order insertion often occurs in the scheduling process of logistics service supply chain (LSSC), which disturbs normal time scheduling especially in the environment of mass customization logistics service. This study analyses order similarity coefficient and order insertion operation process and then establishes an order insertion scheduling model of LSSC with service capacity and time factors considered. This model aims to minimize the average unit volume operation cost of logistics service integrator and maximize the average satisfaction degree of functional logistics service providers. In order to verify the viability and effectiveness of our model, a specific example is numerically analyzed. Some interesting conclusions are obtained. First, along with the increase of completion time delay coefficient permitted by customers, the possible inserting order volume first increases and then trends to be stable. Second, supply chain performance reaches the best when the volume of inserting order is equal to the surplus volume of the normal operation capacity in mass service process. Third, the larger the normal operation capacity in mass service process is, the bigger the possible inserting order's volume will be. Moreover, compared to increasing the completion time delay coefficient, improving the normal operation capacity of mass service process is more useful. PMID:25276851

Copper-Sulfate Pentahydrate as a Product of the Waste Sulfuric Acid Solution Treatment

NASA Astrophysics Data System (ADS)

Marković, Radmila; Stevanović, Jasmina; Avramović, Ljiljana; Nedeljković, Dragutin; Jugović, Branimir; Stajić-Trošić, Jasna; Gvozdenović, Milica

2012-12-01

The aim of this study is synthesis of copper-sulfate pentahydrate from the waste sulfuric acid solution-mother liquor generated during the regeneration process of copper bleed solution. Copper is removed from the mother liquor solution in the process of the electrolytic treatment using the insoluble lead anodes alloyed with 6 mass pct of antimony on the industrial-scale equipment. As the result of the decopperization process, copper is removed in the form of the cathode sludge and is precipitated at the bottom of the electrolytic cell. By this procedure, the content of copper could be reduced to the 20 mass pct of the initial value. Chemical characterization of the sludge has shown that it contains about 90 mass pct of copper. During the decopperization process, the very strong poison, arsine, can be formed, and the process is in that case terminated. The copper leaching degree of 82 mass pct is obtained using H2SO4 aqueous solution with the oxygen addition during the cathode sludge chemical treatment at 80 °C ± 5 °C. Obtained copper salt satisfies the requirements of the Serbian Standard for Pesticide, SRPS H.P1. 058. Therefore, the treatment of waste sulfuric acid solutions is of great economic and environmental interest.

Determination of toxic compounds in paper-recycling process waters by gas chromatography-mass spectrometry and liquid chromatography-mass spectrometry.

PubMed

Rigol, A; Latorre, A; Lacorte, S; Barceló, D

2002-07-19

Three analytical methods were developed for the determination of toxic compounds in recirculating waters of a paper-recycling industry. Three main groups of compounds were considered: (i) wood extractives originated from the raw material; (ii) biocides added during the production process and (iii) surfactants and other adjuvants present in the formulates of these biocides. Wood extractives considered in this study included fatty and resin acids. They were analysed by liquid-liquid extraction using methyl tert.-butyl ether, followed by gas chromatography-mass spectrometry for previous formation of the respective trimethylsilyl esters. Water samples were also extracted with Oasis HLB (copolymer [poly(divinylbenzene-co-N-vinylpyrrolidone]) solid-phase extraction cartridges of 60 mg and analysed by liquid chromatography-electrospray mass spectrometry for the determination of additives and biocides. Using these two approaches levels up to 15 mg/l for total resin and fatty acids, 5 mg/l for alkylbenzene sulfonates and 2-(thiocyanomethylthio)benzotiazol, 100 microg/l for bisphenol A and 2,2-dibromo-3-nitrilepropionamide, and 300 microg/l for nonylphenol ethoxycarboxylate were detected in process waters at different production treatment stages. These levels are of relevance since poor water quality affects the paper-recycling process, the primary water treatment process and eventually, the environmental water quality.

Analysis of the combustion and pyrolysis of dried sewage sludge by TGA and MS.

PubMed

Magdziarz, Aneta; Werle, Sebastian

2014-01-01

In this study, the combustion and pyrolysis processes of three sewage sludge were investigated. The sewage sludge came from three wastewater treatment plants. Proximate and ultimate analyses were performed. The thermal behaviour of studied sewage sludge was investigated by thermogravimetric analysis with mass spectrometry (TGA-MS). The samples were heated from ambient temperature to 800 °C at a constant rate 10 °C/min in air (combustion process) and argon flows (pyrolysis process). The thermal profiles presented in form of TG/DTG curves were comparable for studied sludges. All TG/DTG curves were divided into three stages. The main decomposition of sewage sludge during the combustion process took place in the range 180-580 °C with c.a. 70% mass loss. The pyrolysis process occurred in lower temperature but with less mass loss. The evolved gaseous products (H2, CH4, CO2, H2O) from the decomposition of sewage sludge were identified on-line. Copyright © 2013 Elsevier Ltd. All rights reserved.

System enhancements of Mesoscale Analysis and Space Sensor (MASS) computer system

NASA Technical Reports Server (NTRS)

Hickey, J. S.; Karitani, S.

1985-01-01

The interactive information processing for the mesoscale analysis and space sensor (MASS) program is reported. The development and implementation of new spaceborne remote sensing technology to observe and measure atmospheric processes is described. The space measurements and conventional observational data are processed together to gain an improved understanding of the mesoscale structure and dynamical evolution of the atmosphere relative to cloud development and precipitation processes. A Research Computer System consisting of three primary computers was developed (HP-1000F, Perkin-Elmer 3250, and Harris/6) which provides a wide range of capabilities for processing and displaying interactively large volumes of remote sensing data. The development of a MASS data base management and analysis system on the HP-1000F computer and extending these capabilities by integration with the Perkin-Elmer and Harris/6 computers using the MSFC's Apple III microcomputer workstations is described. The objectives are: to design hardware enhancements for computer integration and to provide data conversion and transfer between machines.

Parametric Power Spectral Density Analysis of Noise from Instrumentation in MALDI TOF Mass Spectrometry

PubMed Central

Shin, Hyunjin; Mutlu, Miray; Koomen, John M.; Markey, Mia K.

2007-01-01

Noise in mass spectrometry can interfere with identification of the biochemical substances in the sample. For example, the electric motors and circuits inside the mass spectrometer or in nearby equipment generate random noise that may distort the true shape of mass spectra. This paper presents a stochastic signal processing approach to analyzing noise from electrical noise sources (i.e., noise from instrumentation) in MALDI TOF mass spectrometry. Noise from instrumentation was hypothesized to be a mixture of thermal noise, 1/f noise, and electric or magnetic interference in the instrument. Parametric power spectral density estimation was conducted to derive the power distribution of noise from instrumentation with respect to frequencies. As expected, the experimental results show that noise from instrumentation contains 1/f noise and prominent periodic components in addition to thermal noise. These periodic components imply that the mass spectrometers used in this study may not be completely shielded from the internal or external electrical noise sources. However, according to a simulation study of human plasma mass spectra, noise from instrumentation does not seem to affect mass spectra significantly. In conclusion, analysis of noise from instrumentation using stochastic signal processing here provides an intuitive perspective on how to quantify noise in mass spectrometry through spectral modeling. PMID:19455245

VLTI Imaging of a High-Mass Protobinary System: Unveiling the Dynamical Processes in High-Mass Star Formation

NASA Astrophysics Data System (ADS)

Kraus, S.; Kluska, J.; Kreplin, A.; Bate, M.; Harries, T.; Hofmann, K.-H.; Hone, E.; Monnier, J.; Weigelt, G.; Anugu, N.; de Wit, W.-J..; Wittkowski, M.

2017-12-01

High-mass stars exhibit a significantly higher multiplicity frequency than low-mass stars, likely reflecting differences in how they formed. Theory suggests that high-mass binaries may form by the fragmentation of self-gravitational discs or by alternative scenarios such as disc-assisted capture. Near-infrared interferometric observations reveal the high-mass young stellar object IRAS 17216-3801 to be a close high-mass protobinary with a separation of 0.058 arcseconds ( 170 au). This is the closest high-mass protobinary system imaged to date. We also resolve near- infrared excess emission around the individual stars, which is associated with hot dust in circumstellar discs. These discs are strongly misaligned with respect to the binary separation vector, indicating that tidal forces have not yet had time to realign. We measure a higher accretion rate towards the circumsecondary disc, confirming a hydrodynamic effect where the secondary star disrupts the primary star’s accretion stream and effectively limits the mass that the primary star can accrete. NACO L'-band imaging may also have resolved the circumbinary disc that feeds the accretion onto the circumstellar discs. This discovery demonstrates the unique capabilities of the VLTI, creating exciting new opportunities to study the dynamical processes that govern the architecture of close multiple systems.

Visual measurement of the evaporation process of a sessile droplet by dual-channel simultaneous phase-shifting interferometry.

PubMed

Sun, Peng; Zhong, Liyun; Luo, Chunshu; Niu, Wenhu; Lu, Xiaoxu

2015-07-16

To perform the visual measurement of the evaporation process of a sessile droplet, a dual-channel simultaneous phase-shifting interferometry (DCSPSI) method is proposed. Based on polarization components to simultaneously generate a pair of orthogonal interferograms with the phase shifts of π/2, the real-time phase of a dynamic process can be retrieved with two-step phase-shifting algorithm. Using this proposed DCSPSI system, the transient mass (TM) of the evaporation process of a sessile droplet with different initial mass were presented through measuring the real-time 3D shape of a droplet. Moreover, the mass flux density (MFD) of the evaporating droplet and its regional distribution were also calculated and analyzed. The experimental results show that the proposed DCSPSI will supply a visual, accurate, noncontact, nondestructive, global tool for the real-time multi-parameter measurement of the droplet evaporation.

Estimating the Contribution of Dynamical Ejecta in the Kilonova Associated with GW170817

DOE PAGES

Abbott, B. P.; Abbott, R.; Abbott, T. D.; ...

2017-12-01

The source of the gravitational-wave (GW) signal GW170817, very likely a binary neutron star merger, was also observed electromagnetically, providing the first multi-messenger observations of this type. The two-week-long electromagnetic (EM) counterpart had a signature indicative of an r-process-induced optical transient known as a kilonova. This Letter examines how the mass of the dynamical ejecta can be estimated without a direct electromagnetic observation of the kilonova, using GW measurements and a phenomenological model calibrated to numerical simulations of mergers with dynamical ejecta. Specifically, we apply the model to the binary masses inferred from the GW measurements, and use the resulting mass of the dynamical ejecta to estimate its contribution (without the effects of wind ejecta) to the corresponding kilonova light curves from various models. The distributions of dynamical ejecta mass range betweenmore » $${M}_{\\mathrm{ej}}={10}^{-3}-{10}^{-2}\\,{M}_{\\odot }$$ for various equations of state, assuming that the neutron stars are rotating slowly. In addition, we use our estimates of the dynamical ejecta mass and the neutron star merger rates inferred from GW170817 to constrain the contribution of events like this to the r-process element abundance in the Galaxy when ejecta mass from post-merger winds is neglected. We find that if ≳10% of the matter dynamically ejected from binary neutron star (BNS) mergers is converted to r-process elements, GW170817-like BNS mergers could fully account for the amount of r-process material observed in the Milky Way.« less

Estimating the Contribution of Dynamical Ejecta in the Kilonova Associated with GW170817

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abbott, B. P.; Abbott, R.; Abbott, T. D.

The source of the gravitational-wave (GW) signal GW170817, very likely a binary neutron star merger, was also observed electromagnetically, providing the first multi-messenger observations of this type. The two-week-long electromagnetic (EM) counterpart had a signature indicative of an r-process-induced optical transient known as a kilonova. This Letter examines how the mass of the dynamical ejecta can be estimated without a direct electromagnetic observation of the kilonova, using GW measurements and a phenomenological model calibrated to numerical simulations of mergers with dynamical ejecta. Specifically, we apply the model to the binary masses inferred from the GW measurements, and use the resulting mass of the dynamical ejecta to estimate its contribution (without the effects of wind ejecta) to the corresponding kilonova light curves from various models. The distributions of dynamical ejecta mass range betweenmore » $${M}_{\\mathrm{ej}}={10}^{-3}-{10}^{-2}\\,{M}_{\\odot }$$ for various equations of state, assuming that the neutron stars are rotating slowly. In addition, we use our estimates of the dynamical ejecta mass and the neutron star merger rates inferred from GW170817 to constrain the contribution of events like this to the r-process element abundance in the Galaxy when ejecta mass from post-merger winds is neglected. We find that if ≳10% of the matter dynamically ejected from binary neutron star (BNS) mergers is converted to r-process elements, GW170817-like BNS mergers could fully account for the amount of r-process material observed in the Milky Way.« less

Automated characterisation of ultrasound images of ovarian tumours: the diagnostic accuracy of a support vector machine and image processing with a local binary pattern operator.

PubMed

Khazendar, S; Sayasneh, A; Al-Assam, H; Du, H; Kaijser, J; Ferrara, L; Timmerman, D; Jassim, S; Bourne, T

2015-01-01

Preoperative characterisation of ovarian masses into benign or malignant is of paramount importance to optimise patient management. In this study, we developed and validated a computerised model to characterise ovarian masses as benign or malignant. Transvaginal 2D B mode static ultrasound images of 187 ovarian masses with known histological diagnosis were included. Images were first pre-processed and enhanced, and Local Binary Pattern Histograms were then extracted from 2 × 2 blocks of each image. A Support Vector Machine (SVM) was trained using stratified cross validation with randomised sampling. The process was repeated 15 times and in each round 100 images were randomly selected. The SVM classified the original non-treated static images as benign or malignant masses with an average accuracy of 0.62 (95% CI: 0.59-0.65). This performance significantly improved to an average accuracy of 0.77 (95% CI: 0.75-0.79) when images were pre-processed, enhanced and treated with a Local Binary Pattern operator (mean difference 0.15: 95% 0.11-0.19, p < 0.0001, two-tailed t test). We have shown that an SVM can classify static 2D B mode ultrasound images of ovarian masses into benign and malignant categories. The accuracy improves if texture related LBP features extracted from the images are considered.

PeakML/mzMatch: a file format, Java library, R library, and tool-chain for mass spectrometry data analysis.

PubMed

Scheltema, Richard A; Jankevics, Andris; Jansen, Ritsert C; Swertz, Morris A; Breitling, Rainer

2011-04-01

The recent proliferation of high-resolution mass spectrometers has generated a wealth of new data analysis methods. However, flexible integration of these methods into configurations best suited to the research question is hampered by heterogeneous file formats and monolithic software development. The mzXML, mzData, and mzML file formats have enabled uniform access to unprocessed raw data. In this paper we present our efforts to produce an equally simple and powerful format, PeakML, to uniformly exchange processed intermediary and result data. To demonstrate the versatility of PeakML, we have developed an open source Java toolkit for processing, filtering, and annotating mass spectra in a customizable pipeline (mzMatch), as well as a user-friendly data visualization environment (PeakML Viewer). The PeakML format in particular enables the flexible exchange of processed data between software created by different groups or companies, as we illustrate by providing a PeakML-based integration of the widely used XCMS package with mzMatch data processing tools. As an added advantage, downstream analysis can benefit from direct access to the full mass trace information underlying summarized mass spectrometry results, providing the user with the means to rapidly verify results. The PeakML/mzMatch software is freely available at http://mzmatch.sourceforge.net, with documentation, tutorials, and a community forum.

Estimation of Greenland's Ice Sheet Mass Balance Using ICESat and GRACE Data

NASA Astrophysics Data System (ADS)

Slobbe, D.; Ditmar, P.; Lindenbergh, R.

2007-12-01

Data of the GRACE gravity mission and the ICESat laser altimetry mission are used to create two independent estimates of Greenland's ice sheet mass balance over the full measurement period. For ICESat data, a processing strategy is developed using the elevation differences of geometrically overlapping footprints of both crossing and repeated tracks. The dataset is cleaned using quality flags defined by the GLAS science team. The cleaned dataset reveals some strong, spatially correlated signals that are shown to be related to physical phenomena. Different processing strategies are used to convert the observed temporal height differences to mass changes for 6 different drainage systems, further divided into a region above and below 2000 meter elevation. The results are compared with other altimetry based mass balance estimates. In general, the obtained results confirm trends discovered by others, but we also show that the choice of processing strategy strongly influences our results, especially for the areas below 2000 meter. Furthermore, GRACE based monthly variations of the Earth's gravity field as processed by CNES, CSR, GFZ and DEOS are used to estimate the mass balance change for North and South Greenland. It is shown that our results are comparable with recently published GRACE estimates (mascon solutions). On the other hand, the estimates based on GRACE data are only partly confirmed by the ICESat estimates. Possible explanations for the obvious differences will be discussed.

Mass Transfer Coefficientin Stirred Tank for p-Cresol Extraction Process from Coal Tar

NASA Astrophysics Data System (ADS)

Fardhyanti, D. S.; Tyaningsih, D. S.; Afifah, S. N.

2017-04-01

Indonesia is a country that has a lot of coal resources. The Indonesian coal has a low caloric value. Pyrolysis is one of the process to increase the caloric value. One of the by-product of the pyrolysis process is coal tar. It contains a lot of aliphatic or aromatic compounds such asp-cresol (11% v/v). It is widely used as a disinfectant. Extractionof p-Cresol increases the economic value of waste of coal. The aim of this research isto study about mass tranfer coefficient in the baffled stirred tank for p-Cresolextraction from coal tar. Mass transfer coefficient is useful for design and scale up of industrial equipment. Extraction is conducted inthe baffled stirred tank equipped with a four-bladed axial impeller placed vertically in the vessel. Sample for each time processing (5, 10, 15, 20, 25 and 30minutes) was poured into a separating funnel, settled for an hour and separated into two phases. Then the two phases were weighed. The extract phases and raffinate phases were analyzed by Spectronic UV-Vis. The result showed that mixing speed of p-Cresol extraction increasesthe yield of p-Cresol and the mass transfer coefficient. The highest yield of p-Cresol is 49.32% and the highest mass transfer coefficient is 4.757 x 10-6kg/m2s.

Neural correlates of the spacing effect in explicit verbal semantic encoding support the deficient-processing theory.

PubMed

Callan, Daniel E; Schweighofer, Nicolas

2010-04-01

Spaced presentations of to-be-learned items during encoding leads to superior long-term retention over massed presentations. Despite over a century of research, the psychological and neural basis of this spacing effect however is still under investigation. To test the hypotheses that the spacing effect results either from reduction in encoding-related verbal maintenance rehearsal in massed relative to spaced presentations (deficient processing hypothesis) or from greater encoding-related elaborative rehearsal of relational information in spaced relative to massed presentations (encoding variability hypothesis), we designed a vocabulary learning experiment in which subjects encoded paired-associates, each composed of a known word paired with a novel word, in both spaced and massed conditions during functional magnetic resonance imaging. As expected, recall performance in delayed cued-recall tests was significantly better for spaced over massed conditions. Analysis of brain activity during encoding revealed that the left frontal operculum, known to be involved in encoding via verbal maintenance rehearsal, was associated with greater performance-related increased activity in the spaced relative to massed condition. Consistent with the deficient processing hypothesis, a significant decrease in activity with subsequent episodes of presentation was found in the frontal operculum for the massed but not the spaced condition. Our results suggest that the spacing effect is mediated by activity in the frontal operculum, presumably by encoding-related increased verbal maintenance rehearsal, which facilitates binding of phonological and word level verbal information for transfer into long-term memory. Copyright 2009 Wiley-Liss, Inc.

The infection rate of Daphnia magna by Pasteuria ramosa conforms with the mass-action principle.

PubMed

Regoes, R R; Hottinger, J W; Sygnarski, L; Ebert, D

2003-10-01

In simple epidemiological models that describe the interaction between hosts with their parasites, the infection process is commonly assumed to be governed by the law of mass action, i.e. it is assumed that the infection rate depends linearly on the densities of the host and the parasite. The mass-action assumption, however, can be problematic if certain aspects of the host-parasite interaction are very pronounced, such as spatial compartmentalization, host immunity which may protect from infection with low doses, or host heterogeneity with regard to susceptibility to infection. As deviations from a mass-action infection rate have consequences for the dynamics of the host-parasite system, it is important to test for the appropriateness of the mass-action assumption in a given host-parasite system. In this paper, we examine the relationship between the infection rate and the parasite inoculum for the water flee Daphnia magna and its bacterial parasite Pasteuria ramosa. We measured the fraction of infected hosts after exposure to 14 different doses of the parasite. We find that the observed relationship between the fraction of infected hosts and the parasite dose is largely consistent with an infection process governed by the mass-action principle. However, we have evidence for a subtle but significant deviation from a simple mass-action infection model, which can be explained either by some antagonistic effects of the parasite spores during the infection process, or by heterogeneity in the hosts' susceptibility with regard to infection.

Mass and energy flow in prominences

NASA Technical Reports Server (NTRS)

Poland, Arthur I.

1990-01-01

Mass and energy flow in quiescent prominences is considered based on the hypothesis that active region prominences have a different structure and thus different mass and energy flow characteristics. Several important physical parameters have been plotted using the computational model, representing the evolutionary process after the prominence formation. The temperature, velocity, conductive flux, and enthalpy flux are plotted against distance from the highest point in the loop to the coolest part of the prominence. It is shown that the maximum velocity is only about 5 km/s. The model calculations indicate that the transition region of prominences is dominated by complex processes. It is necessary to take into account mass flow at temperatures below 200,000 K, and both mass flow and optical depth effects in hydrogen at temperatures below 30,000 K. Both of these effects lead to a less steep temperature gradient through the prominence corona interface than can be obtained from the conduction alone.

Paravertebral masses in blue-tailed monitor, Varanus dorianus, indicative of soft-tissue infection with associated osteomyelitis.

PubMed

Rothschild, Bruce M

2014-03-01

Paravertebral osseous masses in reptiles have been attributed to Paget's disease on the basis of histology. Histologically recognized mosaic architecture and cement lines, however, lack specificity. A Varanus dorianus with this condition was subjected to standard and computerized tomography. Because the masses were extraskeletal in nature, Paget's disease could be excluded. Although interpretation of the computed tomography suggested the process to be entirely extraskeletal, standard radiographs revealed disorganized vertebral architecture characteristic of osteomyelitis, crossing intervertebral spaces. Posttraumatic myositis ossificans and calcified hematoma were confidently excluded as diagnoses. The etiology of paraspinal masses in this V. dorianus appears attributable to infection, with infection of a puncture wound hypothesized as the underlying process. If one extrapolates the findings in this one animal, it seems reasonable to suggest that consideration be given to investigating the possibility of an infectious origin when similar masses are recognized in other reptiles.

Quantitative mass imaging of single biological macromolecules.

PubMed

Young, Gavin; Hundt, Nikolas; Cole, Daniel; Fineberg, Adam; Andrecka, Joanna; Tyler, Andrew; Olerinyova, Anna; Ansari, Ayla; Marklund, Erik G; Collier, Miranda P; Chandler, Shane A; Tkachenko, Olga; Allen, Joel; Crispin, Max; Billington, Neil; Takagi, Yasuharu; Sellers, James R; Eichmann, Cédric; Selenko, Philipp; Frey, Lukas; Riek, Roland; Galpin, Martin R; Struwe, Weston B; Benesch, Justin L P; Kukura, Philipp

2018-04-27

The cellular processes underpinning life are orchestrated by proteins and their interactions. The associated structural and dynamic heterogeneity, despite being key to function, poses a fundamental challenge to existing analytical and structural methodologies. We used interferometric scattering microscopy to quantify the mass of single biomolecules in solution with 2% sequence mass accuracy, up to 19-kilodalton resolution, and 1-kilodalton precision. We resolved oligomeric distributions at high dynamic range, detected small-molecule binding, and mass-imaged proteins with associated lipids and sugars. These capabilities enabled us to characterize the molecular dynamics of processes as diverse as glycoprotein cross-linking, amyloidogenic protein aggregation, and actin polymerization. Interferometric scattering mass spectrometry allows spatiotemporally resolved measurement of a broad range of biomolecular interactions, one molecule at a time. Copyright © 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.

OpenMS: a flexible open-source software platform for mass spectrometry data analysis.

PubMed

Röst, Hannes L; Sachsenberg, Timo; Aiche, Stephan; Bielow, Chris; Weisser, Hendrik; Aicheler, Fabian; Andreotti, Sandro; Ehrlich, Hans-Christian; Gutenbrunner, Petra; Kenar, Erhan; Liang, Xiao; Nahnsen, Sven; Nilse, Lars; Pfeuffer, Julianus; Rosenberger, George; Rurik, Marc; Schmitt, Uwe; Veit, Johannes; Walzer, Mathias; Wojnar, David; Wolski, Witold E; Schilling, Oliver; Choudhary, Jyoti S; Malmström, Lars; Aebersold, Ruedi; Reinert, Knut; Kohlbacher, Oliver

2016-08-30

High-resolution mass spectrometry (MS) has become an important tool in the life sciences, contributing to the diagnosis and understanding of human diseases, elucidating biomolecular structural information and characterizing cellular signaling networks. However, the rapid growth in the volume and complexity of MS data makes transparent, accurate and reproducible analysis difficult. We present OpenMS 2.0 (http://www.openms.de), a robust, open-source, cross-platform software specifically designed for the flexible and reproducible analysis of high-throughput MS data. The extensible OpenMS software implements common mass spectrometric data processing tasks through a well-defined application programming interface in C++ and Python and through standardized open data formats. OpenMS additionally provides a set of 185 tools and ready-made workflows for common mass spectrometric data processing tasks, which enable users to perform complex quantitative mass spectrometric analyses with ease.

Elucidating the mass spectrum of the retronecine alkaloid using DFT calculations.

PubMed

Modesto-Costa, Lucas; Martinez, Sabrina T; Pinto, Angelo C; Vessecchi, Ricardo; Borges, Itamar

2018-06-23

Pyrrolizidine alkaloids are natural molecules playing important roles in different biochemical processes in nature and in humans. In this work, the electron ionization mass spectrum (EI-MS) of retronecine, an alkaloid molecule found in plants, is investigated computationally. Its mass spectrum can be characterized by three main fragment ions having the following m/z ratios: 111, 94 and 80. In order to rationalize the mass spectrum, minima and transition state geometries were computed using density functional theory (DFT). It was showed that the dissociation process includes an aromatization of the originally five-membered ring of retronecine converted into a six-membered ring compound. A fragmentation pathway mechanism involving dissociation activation barriers that are easily overcome by the initial ionization energy was found. From the computed quantum chemical geometric, atomic charges and energetic parameters, the abundance of each ion in the mass spectrum of retronecine was discussed. This article is protected by copyright. All rights reserved.

Two competing ionization processes in ESI-MS analysis of N-(1,3-diphenylallyl)benzenamines: formation of the unusual [M-H]+ ion versus the regular [M+H]+ ion.

PubMed

Fang, Liwen; Dong, Cheng; Guo, Cheng; Xu, Jianxing; Liu, Qiaoling; Qu, Zhirong; Jiang, Kezhi

2018-06-01

A series of N-(1,3-diphenylallyl)benzenamine derivatives (M) were investigated by electrospray ionization mass spectrometry in the positive-ion mode. Both the anomalous [M-H] + and the regular [M+H] + were observed in the ESI mass spectra. The occurrence of [M-H] + has been supported by accurate mass spectrometry, liquid chromatography mass spectrometry, and tandem mass spectrometry analysis. Calculation results indicated that formation of [M-H] + is attributed to the ion-molecule reaction of M with the protonated ESI solvent molecule (e.g. CH 3 OH 2 + ) via hydride abstraction from a tertiary C sp3 -H. The competing ionization processes leading to [M-H] + or [M+H] + were significantly affected by the concentration of formic acid in the electrospray ionization solvent and the proton affinity of the N atom.

Jason Woods | NREL

Science.gov Websites

doctoral student since 2007. Jason's area of expertise is heat and mass transfer, including the design , analysis, and testing of heat and mass transfer devices and processes. Research Interests Membrane Thermal energy storage Heat and mass transfer enhancements Combined cooling, heat, and power (CCHP

Aluminothermic Reduction-Molten Salt Electrolysis Using Inert Anode for Oxygen and Al-Base Alloy Extraction from Lunar Soil Simulant

NASA Astrophysics Data System (ADS)

Xie, Kaiyu; Shi, Zhongning; Xu, Junli; Hu, Xianwei; Gao, Bingliang; Wang, Zhaowen

2017-10-01

Aluminothermic reduction-electrolysis using an inert anode process is proposed to extract oxygen and metals from Minnesota Lunar Simulant-1 (MLS-1). Effective aluminothermic reduction between dissolved MLS-1 and dissolved metal aluminum was achieved in cryolite salt media. The product phases obtained by aluminothermic reduction at 980°C for 4 h were Al, Si, and Al5FeSi, while the chemical components were 79.71 mass% aluminum, 12.03 mass% silicon, 5.91 mass% iron, and 2.35 mass% titanium. The cryolite salt containing Al2O3 was subsequently electrolyzed with Fe0.58-Ni0.42 inert anode at 960°C for 4 h. Oxygen was evolved at the anode with an anodic current efficiency of 78.28%. The results demonstrate that this two-step process is remarkably feasible for the extraterrestrial extraction of oxygen and metals. This process will help expand the existing in situ resource utilization methods.

Electronic and software systems of an automated portable static mass spectrometer

NASA Astrophysics Data System (ADS)

Chichagov, Yu. V.; Bogdanov, A. A.; Lebedev, D. S.; Kogan, V. T.; Tubol'tsev, Yu. V.; Kozlenok, A. V.; Moroshkin, V. S.; Berezina, A. V.

2017-01-01

The electronic systems of a small high-sensitivity static mass spectrometer and software and hardware tools, which allow one to determine trace concentrations of gases and volatile compounds in air and water samples in real time, have been characterized. These systems and tools have been used to set up the device, control the process of measurement, synchronize this process with accompanying measurements, maintain reliable operation of the device, process the obtained results automatically, and visualize and store them. The developed software and hardware tools allow one to conduct continuous measurements for up to 100 h and provide an opportunity for personnel with no special training to perform maintenance on the device. The test results showed that mobile mass spectrometers for geophysical and medical research, which were fitted with these systems, had a determination limit for target compounds as low as several ppb(m) and a mass resolving power (depending on the current task) as high as 250.

Mass media in health promotion: an analysis using an extended information-processing model.

PubMed

Flay, B R; DiTecco, D; Schlegel, R P

1980-01-01

The information-processing model of the attitude and behavior change process was critically examined and extended from six to 12 levels for a better analysis of change due to mass media campaigns. Findings from social psychology and communications research, and from evaluations of mass media health promotion programs, were reviewed to determine how source, message, channel, receiver, and destination variables affect each of the levels of change of major interest (knowledge, beliefs, attitudes, intentions and behavior). Factors found to most likely induce permanent attitude and behavior change (most important in health promotion) were: presentation and repetition over long time periods, via multiple sources, at different times (including "prime" or high-exposure times), by multiple sources, in novel and involving ways, with appeals to multiple motives, development of social support, and provisions of appropriate behavioral skills, alternatives, and reinforcement (preferably in ways that get the active participation of the audience). Suggestions for evaluation of mass media programs that take account of this complexity were advanced.

Nuclear robustness of the r process in neutron-star mergers

NASA Astrophysics Data System (ADS)

Mendoza-Temis, Joel de Jesús; Wu, Meng-Ru; Langanke, Karlheinz; Martínez-Pinedo, Gabriel; Bauswein, Andreas; Janka, Hans-Thomas

2015-11-01

We have performed r -process calculations for matter ejected dynamically in neutron star mergers based on a complete set of trajectories from a three-dimensional relativistic smoothed particle hydrodynamic simulation with a total ejected mass of ˜1.7 ×10-3M⊙ . Our calculations consider an extended nuclear network, including spontaneous, β - and neutron-induced fission and adopting fission yield distributions from the abla code. In particular we have studied the sensitivity of the r -process abundances to nuclear masses by using different models. Most of the trajectories, corresponding to 90% of the ejected mass, follow a relatively slow expansion allowing for all neutrons to be captured. The resulting abundances are very similar to each other and reproduce the general features of the observed r -process abundance (the second and third peaks, the rare-earth peak, and the lead peak) for all mass models as they are mainly determined by the fission yields. We find distinct differences in the predictions of the mass models at and just above the third peak, which can be traced back to different predictions of neutron separation energies for r -process nuclei around neutron number N =130 . In all simulations, we find that the second peak around A ˜130 is produced by the fission yields of the material that piles up in nuclei with A ≳250 due to the substantially longer β -decay half-lives found in this region. The third peak around A ˜195 is generated in a competition between neutron captures and β decays during r -process freeze-out. The remaining trajectories, which contribute 10% by mass to the total integrated abundances, follow such a fast expansion that the r process does not use all the neutrons. This also leads to a larger variation of abundances among trajectories, as fission does not dominate the r -process dynamics. The resulting abundances are in between those associated to the r and s processes. The total integrated abundances are dominated by contributions from the slow abundances and hence reproduce the general features of the observed r -process abundances. We find that, at timescales of weeks relevant for kilonova light curve calculations, the abundance of actinides is larger than the one of lanthanides. This means that actinides can be even more important than lanthanides to determine the photon opacities under kilonova conditions. Moreover, we confirm that the amount of unused neutrons may be large enough to give rise to another observational signature powered by their decay.

Incomplete mass transfer processes in 28Si +93Nb reaction

NASA Astrophysics Data System (ADS)

Tripathi, R.; Sodaye, S.; Ramachandran, K.; Sharma, S. K.; Pujari, P. K.

Cross sections of reaction products were measured in 28Si +93Nb reaction using recoil catcher technique involving by off-line gamma-ray spectrometry at beam energies of 105 and 155MeV. At Elab = 155MeV, the contribution from different incomplete mass transfer processes is investigated. Results of the present studies show the contribution from deep inelastic collision (DIC), massive transfer or incomplete fusion (ICF) and quasi-elastic transfer (QET). The contribution from massive transfer reactions was confirmed from the fractional yield of the reaction products in the forward catcher foil. The present results are different from those from the reactions with comparatively higher entrance channel mass asymmetry with lighter projectiles, for which dominant transfer processes are ICF and QET which involve mass transfer predominantly from projectile to target. The N/Z values of the products close to the target mass were observed to be in a wide range, starting from N/Z of the target (93Nb) and extending slightly below the N/Z of the composite system, consistent with the contribution from DIC and QET reactions. At Elab = 105MeV, a small contribution from QET was observed in addition to complete fusion.

Model Scramjet Inlet Unstart Induced by Mass Addition and Heat Release

NASA Astrophysics Data System (ADS)

Im, Seong-Kyun; Baccarella, Damiano; McGann, Brendan; Liu, Qili; Wermer, Lydiy; Do, Hyungrok

2015-11-01

The inlet unstart phenomena in a model scramjet are investigated at an arc-heated hypersonic wind tunnel. The unstart induced by nitrogen or ethylene jets at low or high enthalpy Mach 4.5 freestream flow conditions are compared. The jet injection pressurizes the downstream flow by mass addition and flow blockage. In case of the ethylene jet injection, heat release from combustion increases the backpressure further. Time-resolved schlieren imaging is performed at the jet and the lip of the model inlet to visualize the flow features during unstart. High frequency pressure measurements are used to provide information on pressure fluctuation at the scramjet wall. In both of the mass and heat release driven unstart cases, it is observed that there are similar flow transient and quasi-steady behaviors of unstart shockwave system during the unstart processes. Combustion driven unstart induces severe oscillatory flow motions of the jet and the unstart shock at the lip of the scramjet inlet after the completion of the unstart process, while the unstarted flow induced by solely mass addition remains relatively steady. The discrepancies between the processes of mass and heat release driven unstart are explained by flow choking mechanism.

Optimum process design of packed bed type thermal storage systems and other applications

DOEpatents

Bindra, Hitesh; Bueno, Pablo

2016-10-25

Methods and systems for optimizing the process of heat and/or mass transfer operations in packed beds and embodiments of applications of the methods are disclosed herein below. In one instance, the method results in the profile of the quantity representative of the heat and/or mass transfer operation having a propagating substantially sharp front.

Application of mass spectrometry to process control for polymer material in autoclave curing

NASA Technical Reports Server (NTRS)

Smith, A. C.

1983-01-01

Mass spectrometer analysis of gas samples collected during a cure cycle of polymer materials can be used as a process control technique. This technique is particularly helpful in studying the various types of solvents and resin systems used in the preparation of polymer materials and characterizing the chemical composition of different resin systems and their mechanism of polymerization.

40 CFR 63.645 - Test methods and procedures for miscellaneous process vents.

Code of Federal Regulations, 2010 CFR

2010-07-01

... TOC emission rate, as specified under paragraph (f) of this section, the sampling site shall be after... process vent TOC mass flow rate is less than 33 kilograms per day for an existing source or less than 6.8... shall determine the TOC mass flow rate by the following procedures: (1) The sampling site shall be...

Review of Peak Detection Algorithms in Liquid-Chromatography-Mass Spectrometry

PubMed Central

Zhang, Jianqiu; Gonzalez, Elias; Hestilow, Travis; Haskins, William; Huang, Yufei

2009-01-01

In this review, we will discuss peak detection in Liquid-Chromatography-Mass Spectrometry (LC/MS) from a signal processing perspective. A brief introduction to LC/MS is followed by a description of the major processing steps in LC/MS. Specifically, the problem of peak detection is formulated and various peak detection algorithms are described and compared. PMID:20190954

Fuel conditioning facility zone-to-zone transfer administrative controls.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pope, C. L.

2000-06-21

The administrative controls associated with transferring containers from one criticality hazard control zone to another in the Argonne National Laboratory (ANL) Fuel Conditioning Facility (FCF) are described. FCF, located at the ANL-West site near Idaho Falls, Idaho, is used to remotely process spent sodium bonded metallic fuel for disposition. The process involves nearly forty widely varying material forms and types, over fifty specific use container types, and over thirty distinct zones where work activities occur. During 1999, over five thousand transfers from one zone to another were conducted. Limits are placed on mass, material form and type, and container typesmore » for each zone. Ml material and containers are tracked using the Mass Tracking System (MTG). The MTG uses an Oracle database and numerous applications to manage the database. The database stores information specific to the process, including material composition and mass, container identification number and mass, transfer history, and the operators involved in each transfer. The process is controlled using written procedures which specify the zone, containers, and material involved in a task. Transferring a container from one zone to another is called a zone-to-zone transfer (ZZT). ZZTs consist of four distinct phases, select, request, identify, and completion.« less

Cooling of hypernuclear compact stars

NASA Astrophysics Data System (ADS)

Raduta, Adriana R.; Sedrakian, Armen; Weber, Fridolin

2018-04-01

We study the thermal evolution of hypernuclear compact stars constructed from covariant density functional theory of hypernuclear matter and parametrizations which produce sequences of stars containing two-solar-mass objects. For the input in the simulations, we solve the Bardeen-Cooper-Schrieffer gap equations in the hyperonic sector and obtain the gaps in the spectra of Λ, Ξ0, and Ξ- hyperons. For the models with masses M/M⊙ ≥ 1.5 the neutrino cooling is dominated by hyperonic direct Urca processes in general. In the low-mass stars the (Λp) plus leptons channel is the dominant direct Urca process, whereas for more massive stars the purely hyperonic channels (Σ-Λ) and (Ξ-Λ) are dominant. Hyperonic pairing strongly suppresses the processes on Ξ-s and to a lesser degree on Λs. We find that intermediate-mass 1.5 ≤ M/M⊙ ≤ 1.8 models have surface temperatures which lie within the range inferred from thermally emitting neutron stars, if the hyperonic pairing is taken into account. Most massive models with M/M⊙ ≃ 2 may cool very fast via the direct Urca process through the (Λp) channel because they develop inner cores where the S-wave pairing of Λs and proton is absent.

Star formation in simulated galaxies: understanding the transition to quiescence at 3 × 1010 M⊙

NASA Astrophysics Data System (ADS)

Taylor, Philip; Federrath, Christoph; Kobayashi, Chiaki

2017-08-01

Star formation in galaxies relies on the availability of cold, dense gas, which, in turn, relies on factors internal and external to the galaxies. In order to provide a simple model for how star formation is regulated by various physical processes in galaxies, we analyse data at redshift z = 0 from a hydrodynamical cosmological simulation that includes prescriptions for star formation and stellar evolution, active galactic nuclei, and their associated feedback processes. This model can determine the star formation rate (SFR) as a function of galaxy stellar mass, gas mass, black hole mass, and environment. We find that gas mass is the most important quantity controlling star formation in low-mass galaxies, and star-forming galaxies in dense environments have higher SFR than their counterparts in the field. In high-mass galaxies, we find that black holes more massive than ˜ 107.5 M⊙ can be triggered to quench star formation in their host; this mass scale is emergent in our simulations. Furthermore, this black hole mass corresponds to a galaxy bulge mass ˜ 2 × 1010 M⊙, consistent with the mass at which galaxies start to become dominated by early types ( ˜ 3 × 1010 M⊙, as previously shown in observations by Kauffmann et al.). Finally, we demonstrate that our model can reproduce well the SFR measured from observations of galaxies in the Galaxy And Mass Assembly and Arecibo Legacy Fast ALFA surveys.

Persuasion and the Mass Communication Process.

ERIC Educational Resources Information Center

Sternthal, Brian

The author addresses his dissertation to two audiences: the mass communications practitioner, to help update his knowledge about the phenomena, and the researcher, to provide a starting point for a systematic pursuit of knowledge about media. In the first part, the author presents a model for persuasive mass communications, specifying the critical…

Seed Cotton Mass Flow Measurement in the Gin

USDA-ARS?s Scientific Manuscript database

Seed cotton mass flow measurement is necessary for the development of improved gin process control systems that can increase gin efficiency and improve fiber quality. Previous studies led to the development of a seed cotton mass flow rate sensor based on the static pressure drop across the blowbox, ...

Mass transfer apparatus and method for separation of gases

DOEpatents

Blount, Gerald C.

2015-10-13

A process and apparatus for separating components of a source gas is provided in which more soluble components of the source gas are dissolved in an aqueous solvent at high pressure. The system can utilize hydrostatic pressure to increase solubility of the components of the source gas. The apparatus includes gas recycle throughout multiple mass transfer stages to improve mass transfer of the targeted components from the liquid to gas phase. Separated components can be recovered for use in a value added application or can be processed for long-term storage, for instance in an underwater reservoir.

Intensification of heat and mass transfer by ultrasound: application to heat exchangers and membrane separation processes.

PubMed

Gondrexon, N; Cheze, L; Jin, Y; Legay, M; Tissot, Q; Hengl, N; Baup, S; Boldo, P; Pignon, F; Talansier, E

2015-07-01

This paper aims to illustrate the interest of ultrasound technology as an efficient technique for both heat and mass transfer intensification. It is demonstrated that the use of ultrasound results in an increase of heat exchanger performances and in a possible fouling monitoring in heat exchangers. Mass transfer intensification was observed in the case of cross-flow ultrafiltration. It is shown that the enhancement of the membrane separation process strongly depends on the physico-chemical properties of the filtered suspensions. Copyright © 2014 Elsevier B.V. All rights reserved.

Mass transfer apparatus and method for separation of gases

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blount, Gerald C.; Gorensek, Maximilian Boris; Hamm, Luther L.

A process and apparatus for separating components of a source gas is provided in which more soluble components of the source gas are dissolved in an aqueous solvent at high pressure. The system can utilize hydrostatic pressure to increase solubility of the components of the source gas. The apparatus includes gas recycle throughout multiple mass transfer stages to improve mass transfer of the targeted components from the liquid to gas phase. Separated components can be recovered for use in a value added application or can be processed for long-term storage, for instance in an underwater reservoir.

One possible source of mass-independent fractionation of sulfur isotopes in the Archean atmosphere of Earth

NASA Astrophysics Data System (ADS)

Babikov, Dmitri; Semenov, Alexander; Teplukhin, Alexander

2017-05-01

Energy transfer mechanism for recombination of two sulfur atoms into a diatomic molecule, S2, is studied theoretically and computationally to determine whether the rate coefficient of this process can be significantly affected by isotopic substitutions, and whether the resultant isotope effect is expected to be mass-dependent or mass-independent. This is one of sulfur polymerization processes thought to be important in the anoxic atmosphere of the Archean Earth and, potentially, relevant to mass-independent fractionation of sulfur isotopes. A simplified theoretical approach is employed, in which all properties of S2 molecule are characterized rather accurately, whereas the process of stabilization of metastable S2∗ by bath gas collisions is described approximately. Properties of individual scattering resonances in S2 are studied in detail, and it is found that most important contributions to the recombination process come from ro-vibrational states formed near the top of centrifugal barrier, and that the number of such states is about 50 (in 32S32S). Absolute value of recombination rate coefficient is computed to be 1.22 × 10-33 cm6/s (for 32S32S at room temperature and atmospheric pressure), close to experimental result. Two distinct isotope effects are identified. One is a classical mass-dependent effect due to translational partition function, which leads to a weak, smooth, and negative mass-dependence of rate coefficient (4% decrease when the mass is raised from 32S32S to 34S34S). Second effect, due to quantized resonances, is two orders of magnitude stronger, but is local. In practice, due to presence of multiple individual resonances, this phenomenon leads to irregular mass-independent variations of rate coefficients in the ranges ±5%. It is also demonstrated that in real molecules this irregular behavior is expected to be somewhat smoother, and the isotope effect is somewhat smaller, due to dependence of stabilization cross section on properties of individual resonances (not described by present model). Thus, additional calculations of stabilization cross sections are needed in order to give quantitative prediction of this mass-independent isotope effect, and to determine its relevance to mass-independent fractionation of sulfur isotopes in the Archean rock record.

Measuring the Autocorrelation Function of Nanoscale Three-Dimensional Density Distribution in Individual Cells Using Scanning Transmission Electron Microscopy, Atomic Force Microscopy, and a New Deconvolution Algorithm.

PubMed

Li, Yue; Zhang, Di; Capoglu, Ilker; Hujsak, Karl A; Damania, Dhwanil; Cherkezyan, Lusik; Roth, Eric; Bleher, Reiner; Wu, Jinsong S; Subramanian, Hariharan; Dravid, Vinayak P; Backman, Vadim

2017-06-01

Essentially all biological processes are highly dependent on the nanoscale architecture of the cellular components where these processes take place. Statistical measures, such as the autocorrelation function (ACF) of the three-dimensional (3D) mass-density distribution, are widely used to characterize cellular nanostructure. However, conventional methods of reconstruction of the deterministic 3D mass-density distribution, from which these statistical measures can be calculated, have been inadequate for thick biological structures, such as whole cells, due to the conflict between the need for nanoscale resolution and its inverse relationship with thickness after conventional tomographic reconstruction. To tackle the problem, we have developed a robust method to calculate the ACF of the 3D mass-density distribution without tomography. Assuming the biological mass distribution is isotropic, our method allows for accurate statistical characterization of the 3D mass-density distribution by ACF with two data sets: a single projection image by scanning transmission electron microscopy and a thickness map by atomic force microscopy. Here we present validation of the ACF reconstruction algorithm, as well as its application to calculate the statistics of the 3D distribution of mass-density in a region containing the nucleus of an entire mammalian cell. This method may provide important insights into architectural changes that accompany cellular processes.

A universal model for solar eruptions.

PubMed

Wyper, Peter F; Antiochos, Spiro K; DeVore, C Richard

2017-04-26

Magnetically driven eruptions on the Sun, from stellar-scale coronal mass ejections to small-scale coronal X-ray and extreme-ultraviolet jets, have frequently been observed to involve the ejection of the highly stressed magnetic flux of a filament. Theoretically, these two phenomena have been thought to arise through very different mechanisms: coronal mass ejections from an ideal (non-dissipative) process, whereby the energy release does not require a change in the magnetic topology, as in the kink or torus instability; and coronal jets from a resistive process involving magnetic reconnection. However, it was recently concluded from new observations that all coronal jets are driven by filament ejection, just like large mass ejections. This suggests that the two phenomena have physically identical origin and hence that a single mechanism may be responsible, that is, either mass ejections arise from reconnection, or jets arise from an ideal instability. Here we report simulations of a coronal jet driven by filament ejection, whereby a region of highly sheared magnetic field near the solar surface becomes unstable and erupts. The results show that magnetic reconnection causes the energy release via 'magnetic breakout'-a positive-feedback mechanism between filament ejection and reconnection. We conclude that if coronal mass ejections and jets are indeed of physically identical origin (although on different spatial scales) then magnetic reconnection (rather than an ideal process) must also underlie mass ejections, and that magnetic breakout is a universal model for solar eruptions.

Modifier mass transfer kinetic effect in the performance of solvent gradient simulated moving bed (SG-SMB) process

NASA Astrophysics Data System (ADS)

Câmara, L. D. T.

2015-09-01

The solvent-gradient simulated moving bed process (SG-SMB) is the new tendency in the performance improvement if compared to the traditional isocratic solvent conditions. In such SG-SMB separation process the modulation of the solvent strength leads to significant increase in the purities and productivity followed by reduction in the solvent consumption. A stepwise modelling approach was utilized in the representation of the interconnected chromatographic columns of the system combined with lumped mass transfer models between the solid and liquid phase. The influence of the solvent modifier was considered applying the Abel model which takes into account the effect of modifier volume fraction over the partition coefficient. The modelling and simulations were carried out and compared to the experimental SG-SMB separation of the amino acids phenylalanine and tryptophan. A lumped mass transfer kinetic model was applied for both the modifier (ethanol) as well as the solutes. The simulation results showed that such simple and global mass transfer models are enough to represent all the mass transfer effect between the solid adsorbent and the liquid phase. The separation performance can be improved reducing the interaction or the mass transfer kinetic effect between the solid adsorbent phase and the modifier. The simulations showed great agreement fitting the experimental data of the amino acids concentrations both at the extract as well as at the raffinate.

Theoretical models for supercritical fluid extraction.

PubMed

Huang, Zhen; Shi, Xiao-Han; Jiang, Wei-Juan

2012-08-10

For the proper design of supercritical fluid extraction processes, it is essential to have a sound knowledge of the mass transfer mechanism of the extraction process and the appropriate mathematical representation. In this paper, the advances and applications of kinetic models for describing supercritical fluid extraction from various solid matrices have been presented. The theoretical models overviewed here include the hot ball diffusion, broken and intact cell, shrinking core and some relatively simple models. Mathematical representations of these models have been in detail interpreted as well as their assumptions, parameter identifications and application examples. Extraction process of the analyte solute from the solid matrix by means of supercritical fluid includes the dissolution of the analyte from the solid, the analyte diffusion in the matrix and its transport to the bulk supercritical fluid. Mechanisms involved in a mass transfer model are discussed in terms of external mass transfer resistance, internal mass transfer resistance, solute-solid interactions and axial dispersion. The correlations of the external mass transfer coefficient and axial dispersion coefficient with certain dimensionless numbers are also discussed. Among these models, the broken and intact cell model seems to be the most relevant mathematical model as it is able to provide realistic description of the plant material structure for better understanding the mass-transfer kinetics and thus it has been widely employed for modeling supercritical fluid extraction of natural matters. Copyright © 2012 Elsevier B.V. All rights reserved.

Experimental investigation and model verification for a GAX absorber

DOE Office of Scientific and Technical Information (OSTI.GOV)

Palmer, S.C.; Christensen, R.N.

1996-12-31

In the ammonia-water generator-absorber heat exchange (GAX) absorption heat pump, the heat and mass transfer processes which occur between the generator and absorber are the most crucial in assuring that the heat pump will achieve COPs competitive with those of current technologies. In this study, a model is developed for the heat and mass transfer processes that occur in a counter-current vertical fluted tube absorber (VFTA) with inserts. Correlations for heat and mass transfer in annuli are used to model the processes in the VTA. Experimental data is used to validate the model for three different insert geometries. Comparison ofmore » model results with experimental data provides insight into model corrections necessary to bring the model into agreement with the physical phenomena observed in the laboratory.« less

Mathematical Simulation of the Process of Aerobic Treatment of Wastewater under Conditions of Diffusion and Mass Transfer Perturbations

NASA Astrophysics Data System (ADS)

Bomba, A. Ya.; Safonik, A. P.

2018-05-01

A mathematical model of the process of aerobic treatment of wastewater has been refined. It takes into account the interaction of bacteria, as well as of organic and biologically nonoxidizing substances under conditions of diffusion and mass transfer perturbations. An algorithm of the solution of the corresponding nonlinear perturbed problem of convection-diffusion-mass transfer type has been constructed, with a computer experiment carried out based on it. The influence of the concentration of oxygen and of activated sludge on the quality of treatment is shown. Within the framework of the model suggested, a possibility of automated control of the process of deposition of impurities in a biological filter depending on the initial parameters of the water medium is suggested.

``Sweetening'' Technical Physics with Hershey's Kisses

NASA Astrophysics Data System (ADS)

Stone, Chuck

2003-04-01

This paper describes an activity in which students measure the mass of each candy in one full bag of Hershey's Kisses and then use a simple spreadsheet program to construct a histogram showing the number of candies as a function of mass. Student measurements indicate that one single bag of 80 Kisses yields enough data to produce a noticeable variation in the candy's mass distribution. The bimodal character of this distribution provides a useful discussion topic. This activity can be performed as a classroom project, a laboratory exercise, or an interactive lecture demonstration. In all these formats, students have the opportunity to collect, organize, process, and analyze real data. In addition to strengthening graphical analysis skills, this activity introduces students to fundamentals of statistics, manufacturing processes in the industrial workplace, and process control techniques.

Mathematical Simulation of the Process of Aerobic Treatment of Wastewater under Conditions of Diffusion and Mass Transfer Perturbations

NASA Astrophysics Data System (ADS)

Bomba, A. Ya.; Safonik, A. P.

2018-03-01

A mathematical model of the process of aerobic treatment of wastewater has been refined. It takes into account the interaction of bacteria, as well as of organic and biologically nonoxidizing substances under conditions of diffusion and mass transfer perturbations. An algorithm of the solution of the corresponding nonlinear perturbed problem of convection-diffusion-mass transfer type has been constructed, with a computer experiment carried out based on it. The influence of the concentration of oxygen and of activated sludge on the quality of treatment is shown. Within the framework of the model suggested, a possibility of automated control of the process of deposition of impurities in a biological filter depending on the initial parameters of the water medium is suggested.

10 CFR 70.60 - Applicability.

Code of Federal Regulations, 2011 CFR

2011-01-01

... Certain Licensees Authorized To Possess a Critical Mass of Special Nuclear Material § 70.60 Applicability... critical mass of special nuclear material, and engaged in enriched uranium processing, fabrication of...

Vacuum Technology Considerations For Mass Metrology

PubMed Central

Abbott, Patrick J.; Jabour, Zeina J.

2011-01-01

Vacuum weighing of mass artifacts eliminates the necessity of air buoyancy correction and its contribution to the measurement uncertainty. Vacuum weighing is also an important process in the experiments currently underway for the redefinition of the SI mass unit, the kilogram. Creating the optimum vacuum environment for mass metrology requires careful design and selection of construction materials, plumbing components, pumping, and pressure gauging technologies. We review the vacuum technology1 required for mass metrology and suggest procedures and hardware for successful and reproducible operation. PMID:26989593

Prediction of mass transfer coefficient in rotating bed contactor (Higee) using artificial neural network

NASA Astrophysics Data System (ADS)

Saha, Dipendu

2009-02-01

The feasibility of drastically reducing the contactor size in mass transfer processes utilizing centrifugal field has generated a lot of interest in rotating packed bed (Higee). Various investigators have proposed correlations to predict mass transfer coefficients in Higee, but, none of the correlations was more than 20-30% accurate. In this work, artificial neural network (ANN) is employed for predicting mass transfer coefficient data. Results show that ANN provides better estimation of mass transfer coefficient with accuracy 5-15%.

Aircraft Structural Mass Property Prediction Using Conceptual-Level Structural Analysis

NASA Technical Reports Server (NTRS)

Sexstone, Matthew G.

1998-01-01

This paper describes a methodology that extends the use of the Equivalent LAminated Plate Solution (ELAPS) structural analysis code from conceptual-level aircraft structural analysis to conceptual-level aircraft mass property analysis. Mass property analysis in aircraft structures has historically depended upon parametric weight equations at the conceptual design level and Finite Element Analysis (FEA) at the detailed design level. ELAPS allows for the modeling of detailed geometry, metallic and composite materials, and non-structural mass coupled with analytical structural sizing to produce high-fidelity mass property analyses representing fully configured vehicles early in the design process. This capability is especially valuable for unusual configuration and advanced concept development where existing parametric weight equations are inapplicable and FEA is too time consuming for conceptual design. This paper contrasts the use of ELAPS relative to empirical weight equations and FEA. ELAPS modeling techniques are described and the ELAPS-based mass property analysis process is detailed. Examples of mass property stochastic calculations produced during a recent systems study are provided. This study involved the analysis of three remotely piloted aircraft required to carry scientific payloads to very high altitudes at subsonic speeds. Due to the extreme nature of this high-altitude flight regime, few existing vehicle designs are available for use in performance and weight prediction. ELAPS was employed within a concurrent engineering analysis process that simultaneously produces aerodynamic, structural, and static aeroelastic results for input to aircraft performance analyses. The ELAPS models produced for each concept were also used to provide stochastic analyses of wing structural mass properties. The results of this effort indicate that ELAPS is an efficient means to conduct multidisciplinary trade studies at the conceptual design level.

Aircraft Structural Mass Property Prediction Using Conceptual-Level Structural Analysis

NASA Technical Reports Server (NTRS)

Sexstone, Matthew G.

1998-01-01

This paper describes a methodology that extends the use of the Equivalent LAminated Plate Solution (ELAPS) structural analysis code from conceptual-level aircraft structural analysis to conceptual-level aircraft mass property analysis. Mass property analysis in aircraft structures has historically depended upon parametric weight equations at the conceptual design level and Finite Element Analysis (FEA) at the detailed design level ELAPS allows for the modeling of detailed geometry, metallic and composite materials, and non-structural mass coupled with analytical structural sizing to produce high-fidelity mass property analyses representing fully configured vehicles early in the design process. This capability is especially valuable for unusual configuration and advanced concept development where existing parametric weight equations are inapplicable and FEA is too time consuming for conceptual design. This paper contrasts the use of ELAPS relative to empirical weight equations and FEA. ELAPS modeling techniques are described and the ELAPS-based mass property analysis process is detailed Examples of mass property stochastic calculations produced during a recent systems study are provided This study involved the analysis of three remotely piloted aircraft required to carry scientific payloads to very high altitudes at subsonic speeds. Due to the extreme nature of this high-altitude flight regime,few existing vehicle designs are available for use in performance and weight prediction. ELAPS was employed within a concurrent engineering analysis process that simultaneously produces aerodynamic, structural, and static aeroelastic results for input to aircraft performance analyses. The ELAPS models produced for each concept were also used to provide stochastic analyses of wing structural mass properties. The results of this effort indicate that ELAPS is an efficient means to conduct multidisciplinary trade studies at the conceptual design level.

The Face that Launched a Thousand Slips

NASA Technical Reports Server (NTRS)

Moore, J. M.; Howard, A. D.; Schenk, P.; Thomas, P. C.

2013-01-01

Helene, (approximately 17.6 kilometers mean radius) is an L4 Trojan co-orbital of Saturn's moon Dione. Its hemisphere features an unusual morphology consisting of broad depressions and a generally smooth surface patterned with streaks and grooves. The streaks appear to be oriented down-gradient, as are the grooves. This pattern suggests intensive mass-wasting as a dominant process on the leading hemisphere. Kilometer-scale impact craters are very sparse on the leading hemisphere other than the degraded kilometer-scale basins defining the overall satellite shape, and many small craters have a diffuse appearance suggesting ongoing mass wasting. Thus mass wasting must dominate surface-modifying processes at present. In fact, the mass wasting appears to have been sufficient in magnitude to narrow the divides between adjacent basins to narrow septa, similar, but in lower relief, to the honeycomb pattern of Hyperion. The prominent groves occur primarily near topographic divides and appear have cut into a broad, slightly lower albedo surface largely conforming to the present topography but elevated a few meters above the smooth surfaces undergoing mass wasting flow. Low ridges and albedo markings on the surface suggest surface flow of materials traveling up to several kilometers. Diffusive mass wasting produces smooth surfaces - such a pattern characterizes most of the low-lying surfaces. The grooves, however, imply that the transport process is advective at those locations where they occur, that is, erosion tends to concentrate along linear pathways separated by divides. In fact, in many places grooves have a fairly regular spacing of 125-160 meters, defining a characteristic erosional scale. Several questions are prompted by the unusual morphology of Helene: 1) What is the nature of the surface materials? 2) Are the transport processes gradual or catastrophic motion from one or a few events? 3) What mechanisms drive mass wasting and groove development? 4) Have the formative processes been active in the recent past? 5) Finally, is the surface accreting or eroding? The smooth character of the leading edge hemisphere of Helene and the dominance of mass wasting suggest that the surface is composed of fine-grained debris, probably dominated by dust-size to small gravel particles. The Lagrangian points of saturnian satellites are locations where planetesimals might have accreted to form co-orbital satellites such as and they may capture ejecta from their master moon. Published models suggest that Helene is a site of net accretion, but we find no extant explanation for the dominance of fine grain sizes for the surface (and probable subsurface) composition of Helene and the other Lagrangian satellites. Observation of the mass wasting tracks on Helene suggests the presence of well-defined streams of debris with low bordering levees that may be depositional features or remnants of the dissected higher surface. Some flows in grazing illumination appear to have a convex cross-section. This mass-flow morphology might be consistent with the occurrence of large-scale flow events, but which might have occurred through rapid emplacement or slow glacier-like creep. On the other hand, small craters appear to have been "softened" by creep-like processes, indicating ongoing mass wasting.

Changes in denudation rates and erosion processes in the transition from a low-relief, arid orogen interior to a high-relief, humid mountain-front setting, Toro Basin, southern Central Andes

NASA Astrophysics Data System (ADS)

Tofelde, S.; Düsing, W.; Schildgen, T. F.; Wittmann, H.; Alonso, R. N.; Strecker, M. R.

2017-12-01

In tectonically active mountain belts positive correlations between denudation rates and hillslope angles are commonly observed, supporting the notion that landscape morphology may reflect tectonic forcing. However, this relationship generally breaks down at 30°, when hillslopes reach threshold angles. Beyond this threshold, faster denudation may occur by an increased contribution from mass-wasting processes. We test this idea in the 4000 km2 Toro Basin, a fault-bounded basin in the Eastern Cordillera of the southern Central Andes. This N-S oriented basin is located between low-relief, arid conditions in the orogen interior (N) and a high-relief, humid setting at its fluvial outlet (S). We measured in-situ produced 10Be concentration in fluvial sediments, which can be converted into basin-mean denudation rates, assuming a spatially uniform contribution of sediment from the catchment. However, in landslide-influenced areas, this assumption is often violated. Previous studies have suggested that clast-size material is mainly contributed by mass-wasting processes, whereas sand is derived from a broad range of erosional processes. Hence, a combination of clast and sand samples can reveal information about the basin-mean denudation rate as well as the contribution of mass-wasting processes. We sampled 13 pebble (1-3 cm) and sand (250-500 µm) pairs across the basin. The sand-derived denudation rates increase from N to S, ranging from 0.010 mm/yr to 1.337 mm/yr, and reveal a non-linear positive correlation with median basin slope. The clast/sand ratios also increase from N to S, indicating amplified mass-wasting processes with increasing slopes. To test if our ratios represent a real shift in erosional processes, we mapped different erosional processes in the study area (e.g. deep-seated landslides, scree erosion,.., diffusion). We assume that today's distribution of processes has not changed over the integration time of 10Be derived denudation rates. This detailed erosion inventory indicates a shift in the dominant erosional processes with increasing clast/sand ratios and thus with increasing slopes. We provide empirical data supporting the hypothesis that higher denudation rates can be achieved by an increased contribution of mass-wasting processes after threshold slopes have been reached.

Process Analytical Technology for High Shear Wet Granulation: Wet Mass Consistency Reported by In-Line Drag Flow Force Sensor Is Consistent With Powder Rheology Measured by At-Line FT4 Powder Rheometer.

PubMed

Narang, Ajit S; Sheverev, Valery; Freeman, Tim; Both, Douglas; Stepaniuk, Vadim; Delancy, Michael; Millington-Smith, Doug; Macias, Kevin; Subramanian, Ganeshkumar

2016-01-01

Drag flow force (DFF) sensor that measures the force exerted by wet mass in a granulator on a thin cylindrical probe was shown as a promising process analytical technology for real-time in-line high-resolution monitoring of wet mass consistency during high shear wet granulation. Our previous studies indicated that this process analytical technology tool could be correlated to granulation end point established independently through drug product critical quality attributes. In this study, the measurements of flow force by a DFF sensor, taken during wet granulation of 3 placebo formulations with different binder content, are compared with concurrent at line FT4 Powder Rheometer characterization of wet granules collected at different time points of the processing. The wet mass consistency measured by the DFF sensor correlated well with the granulation's resistance to flow and interparticulate interactions as measured by FT4 Powder Rheometer. This indicated that the force pulse magnitude measured by the DFF sensor was indicative of fundamental material properties (e.g., shear viscosity and granule size/density), as they were changing during the granulation process. These studies indicate that DFF sensor can be a valuable tool for wet granulation formulation and process development and scale up, as well as for routine monitoring and control during manufacturing. Copyright © 2016. Published by Elsevier Inc.

Processing MALDI mass spectra to improve mass spectral direct tissue analysis

NASA Astrophysics Data System (ADS)

Norris, Jeremy L.; Cornett, Dale S.; Mobley, James A.; Andersson, Malin; Seeley, Erin H.; Chaurand, Pierre; Caprioli, Richard M.

2007-02-01

Profiling and imaging biological specimens using MALDI mass spectrometry has significant potential to contribute to our understanding and diagnosis of disease. The technique is efficient and high-throughput providing a wealth of data about the biological state of the sample from a very simple and direct experiment. However, in order for these techniques to be put to use for clinical purposes, the approaches used to process and analyze the data must improve. This study examines some of the existing tools to baseline subtract, normalize, align, and remove spectral noise for MALDI data, comparing the advantages of each. A preferred workflow is presented that can be easily implemented for data in ASCII format. The advantages of using such an approach are discussed for both molecular profiling and imaging mass spectrometry.

Delivering Mass-Produced Bespoke and Appealing Products

NASA Astrophysics Data System (ADS)

Childs, Thomas Hc; Dalgarno, Kenneth W.; McKay, Alison

The bottleneck in introducing successful new products quickly to market is moving from factory floor manufacturing to the product design process and interfaces between designers, manufacturers and users. ‘Quality’, for products that contact people, has moved beyond functionality and usability to satisfying people’s subjective and emotional lifestyle needs. Affective (kansei) engineering design offers approaches that can be used to bring the emotional responses of consumers into the design process. In parallel, mass customisation promises the delivery of mass-produced bespoke products to individual users. Together, affective engineering and mass customisation are having a dramatic impact on the ways in which designers, engineers and manufacturers interact with each other. The challenge for leading edge manufacture is to create new product opportunities through integration of and new developments in technology, systems and design.

Determination of the System Mass and the Individual Masses of Pluto and Charon from New Horizons Radio Tracking

NASA Astrophysics Data System (ADS)

Hahn, M.; Paetzold, M.; Andert, T.; Bird, M. K.; Tyler, G. L.; Hinson, D. P.; Linscott, I.; Stern, A.; Weaver, H. A., Jr.; Young, L. A.; Ennico Smith, K.; Olkin, C.

2016-12-01

One objective of the New Horizons Radio Science Experiment REX is the direct determination of the system mass and the individual masses of Pluto and Charon. About four weeks of two-way radio tracking centered around the closest approach of New Horizons to the Pluto system were processed. Major problems during the processing were the changes in spacecraft attitude by thrusters which applied extra Δv to the spacecraft motion masking partially the continuously perturbed motion caused by the attracting forces of the Pluto system members. The times of the spacecraft thruster activity are known but the applied Δv magnitude needed to be specifically adjusted. No two-way tracking was available during the flyby day on 14th July but slots of the REX one-way uplink observations cover the most important time near closest approach, these are for example the Pluto and Charon Earth occultation entries and exits. The REX data during the flyby day allowed to extract the individual masses of Pluto and Charon from the system mass at high precision. The relative errors of the mass determinations are below 0.02% and 0.2%, respectively. The masses of the 4 small satellites in the Pluto system could not be resolved.

Concept development of X-ray mass thickness detection for irradiated items upon electron beam irradiation processing

NASA Astrophysics Data System (ADS)

Qin, Huaili; Yang, Guang; Kuang, Shan; Wang, Qiang; Liu, Jingjing; Zhang, Xiaomin; Li, Cancan; Han, Zhiwei; Li, Yuanjing

2018-02-01

The present project will adopt the principle and technology of X-ray imaging to quickly measure the mass thickness (wherein the mass thickness of the item =density of the item × thickness of the item) of the irradiated items and thus to determine whether the packaging size and inside location of the item will meet the requirements for treating thickness upon electron beam irradiation processing. The development of algorithm of X-ray mass thickness detector as well as the prediction of dose distribution have been completed. The development of the algorithm was based on the X-ray attenuation. 4 standard modules, Al sheet, Al ladders, PMMA sheet and PMMA ladders, were selected for the algorithm development. The algorithm was optimized until the error between tested mass thickness and standard mass thickness was less than 5%. Dose distribution of all energy (1-10 MeV) for each mass thickness was obtained using Monte-carlo method and used for the analysis of dose distribution, which provides the information of whether the item will be penetrated or not, as well as the Max. dose, Min. dose and DUR of the whole item.

A prevalence of dynamo-generated magnetic fields in the cores of intermediate-mass stars.

PubMed

Stello, Dennis; Cantiello, Matteo; Fuller, Jim; Huber, Daniel; García, Rafael A; Bedding, Timothy R; Bildsten, Lars; Aguirre, Victor Silva

2016-01-21

Magnetic fields play a part in almost all stages of stellar evolution. Most low-mass stars, including the Sun, show surface fields that are generated by dynamo processes in their convective envelopes. Intermediate-mass stars do not have deep convective envelopes, although 10 per cent exhibit strong surface fields that are presumed to be residuals from the star formation process. These stars do have convective cores that might produce internal magnetic fields, and these fields might survive into later stages of stellar evolution, but information has been limited by our inability to measure the fields below the stellar surface. Here we report the strength of dipolar oscillation modes for a sample of 3,600 red giant stars. About 20 per cent of our sample show mode suppression, by strong magnetic fields in the cores, but this fraction is a strong function of mass. Strong core fields occur only in red giants heavier than 1.1 solar masses, and the occurrence rate is at least 50 per cent for intermediate-mass stars (1.6-2.0 solar masses), indicating that powerful dynamos were very common in the previously convective cores of these stars.

Space Geodesy Monitoring Mass Transport in Global Geophysical Fluids

NASA Technical Reports Server (NTRS)

Chao, Benjamin F.

2004-01-01

Mass transports occurring in the atmosphere-hydrosphere-cryosphere-solid Earth-core system (the 'global geophysical fluids') are important geophysical phenomena. They occur on all temporal and spatial scales. Examples include air mass and ocean circulations, oceanic and solid tides, hydrological water and idsnow redistribution, mantle processes such as post-glacial rebound, earthquakes and tectonic motions, and core geodynamo activities. The temporal history and spatial pattern of such mass transport are often not amenable to direct observations. Space geodesy techniques, however, have proven to be an effective tool in monitorihg certain direct consequences of the mass transport, including Earth's rotation variations, gravitational field variations, and the geocenter motion. Considerable advances have been made in recent years in observing and understanding of these geodynamic effects. This paper will use several prominent examples to illustrate the triumphs in research over the past years under a 'Moore's law' in space geodesy. New space missions and projects promise to further advance our knowledge about the global mass transports. The latter contributes to our understanding of the geophysical processes that produce and regulate the mass transports, as well as of the solid Earth's response to such changes in terms of Earth's mechanical properties.

Monitoring and mass balance analysis of endocrine disrupting compounds and their transformation products in an anaerobic-anoxic-oxic wastewater treatment system in Xiamen, China.

PubMed

Ashfaq, Muhammad; Li, Yan; Wang, Yuwen; Qin, Dan; Rehman, Muhammad Saif Ur; Rashid, Azhar; Yu, Chang-Ping; Sun, Qian

2018-08-01

We investigated the occurrence, removal and mass balance of 8 endocrine disrupting compounds (EDCs), including estrone (E1), estradiol (E2), estriol (E3), ethinylestradiol (EE2), triclosan (TCS), triclocarbon (TCC), 4-n-nonyl phenol (NP) and 4-n-octyl phenol (OP), along with 5 of their transformation products (TPs), including 4-hydroxy estrone (4-OH E1), 4-hydroxy estradiol (4-OH E2), methyl triclosan (MeTCS), carbanilide (NCC), dichlorocarbanilide (DCC) in a wastewater treatment plant. Generally, E3 showed the highest concentrations in wastewater with median value of 514 ng/L in influent, while TCS and TCC showed highest level in sludge and suspended solids (SS) with median value of 960 and 724 μg/kg, respectively. Spatial variations were observed along each unit of the wastewater treatment processes for dissolved analytes in wastewater and adsorbed analytes in suspended solids and sludge. Special emphasis was placed to understand the mass load of EDCs and their TPs to the wastewater treatment unit and mass loss during the wastewater treatment processes. Mass loss based on both aqueous and suspended phase concentration revealed that majority of these chemicals were significantly removed during the treatment process except for TCS, TCC, and three of their TPs (MeTCS, NCC, DCC), which were released or generated during the treatment process. Mass load results showed that 42.4 g of these EDCs and their TPs entered this wastewater treatment system daily via influent, whereas 6.15 g and 7.60 g were discharged through effluent and sludge. Copyright © 2018 Elsevier Ltd. All rights reserved.

Local mass and energy transports in evaporation processes from a vapor-liquid interface in a slit pore based on molecular dynamics

NASA Astrophysics Data System (ADS)

Fujiwara, K.; Shibahara, M.

2018-02-01

Molecular evaporation processes from a vapor-liquid interface formed in a slit-like pore were examined based on the classical molecular dynamics method, in order to elucidate a molecular mechanism of local mass and energy transports in a slit. The calculation system consisted of monatomic molecules and atoms which interact through the 12-6 Lennard-Jones potential. At first, a liquid was situated in a slit with a vapor-liquid interface, and instantaneous amounts of the mass and energy fluxes defined locally in the slit were obtained in two dimensions to reveal local fluctuation properties of the fluid in equilibrium states. Then, imposing a temperature gradient in the calculation system, non-equilibrium evaporation processes in the slit were investigated in details based on the local mass and energy fluxes. In this study, we focused on the fluid which is in the vicinity of the solid surface and in contact with the vapor phase. In the non-equilibrium evaporation processes, the results revealed that the local energy transport mechanism in the vicinity of the solid surface is different from that of the vapor phase, especially in the case of the relatively strong fluid-solid interaction. The results also revealed that the local mass transport in the vicinity of the solid surface can be interpreted based on the mechanism of the local energy transport, and the mechanism provides valuable information about pictures of the evaporation phenomena especially in the vicinity of the hydrophilic surfaces. It suggests that evaluating and changing this mechanism of the local energy transport are necessary to control the local mass flux more precisely in the vicinity of the solid surface.

40 CFR 63.5345 - How do I distinguish between the two upholstery product process operations?

Code of Federal Regulations, 2014 CFR

2014-07-01

... less than 4 grams of finish add-on per square foot, and operations with 4 grams or more of finish add... process. (2) Use a scale with an accuracy of at least 5 percent of the mass in grams of the representative... mass in grams gained on the representative section by its surface area in square feet to determine...

40 CFR 63.5345 - How do I distinguish between the two upholstery product process operations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... less than 4 grams of finish add-on per square foot, and operations with 4 grams or more of finish add... process. (2) Use a scale with an accuracy of at least 5 percent of the mass in grams of the representative... mass in grams gained on the representative section by its surface area in square feet to determine...

A reconstruction of the propagation of the Montaguto earthflow

NASA Astrophysics Data System (ADS)

Lollino, Piernicola; Giordan, Daniele; Allasia, Paolo

2014-05-01

Flow-like landslides represent a class of mass movement that, owing to long run-out, may generate significant damages to infrastructure lines as well as economic losses. Therefore, assessing the main kinematical features of landslide propagation for similar processes can provide useful information to mitigate landslide risk. The present abstract discusses the case history of a huge earthflow developed in 2005 - 2006 in the area of Montaguto town (Southern Apennines, Italy), that produced significant damages to both a national road and a national railway connecting Naples and Bari at the slope toe. The volume of the involved landslide mass has been evaluated to be about 4 million m3, whereas the total length of the earthflow, from the source area to the foot, is approximately 3 km, with the thickness of the landslide mass ranging between 4 and 30 m and the average displacement rate estimated for the propagation stage between 3 and 7 m/day. A reconstruction of the propagation stage of this landslide during the first high-mobility phase is here proposed as first, according to a detailed geomorphological analysis aimed at defining the main features of the in-situ landslide propagation. Later on, a back-analysis of the kinematical evolution of the same process, based on a 1-D sliding-visco-consolidation model as modified from the original sliding-consolidation model proposed by Hutchinson (1986), is presented to investigate the role of important factors controlling the process of landslide propagation. The analysis highlights that the development of high excess pore water pressures due to undrained loading processes active in the slope during the most critical stage along with the following consolidation process can represent a reasonable key to explain the earthflow mobility. In particular, the influence of mobilized friction angle and coefficient of consolidation of the soil, landslide mass thickness and initial value of the excess pore pressure at the base of the landslide mass is explored. Field evidence of the existence of residual excess pore water pressures in the landslide mass as measured in situ during different monitoring campaigns corroborates the proposed interpretation of the landslide process.

I-process Nucleosynthesis and Mass Retention Efficiency in He-shell Flash Evolution of Rapidly Accreting White Dwarfs

NASA Astrophysics Data System (ADS)

Denissenkov, Pavel A.; Herwig, Falk; Battino, Umberto; Ritter, Christian; Pignatari, Marco; Jones, Samuel; Paxton, Bill

2017-01-01

Based on stellar evolution simulations, we demonstrate that rapidly accreting white dwarfs (WDs) in close binary systems are an astrophysical site for the intermediate neutron-capture process. During recurrent and very strong He-shell flashes in the stable H-burning accretion regime H-rich material enters the He-shell flash convection zone. {}12{{C}}(p,γ ){}13{{N}} reactions release enough energy to potentially impact convection, and I process is activated through the {}13{{C}}{(α ,{{n}})}16{{O}} reaction. The H-ingestion flash may not cause a split of the convection zone as it was seen in simulations of He-shell flashes in post-AGB and low-Z asymptotic giant branch (AGB) stars. We estimate that for the production of first-peak heavy elements this site can be of similar importance for galactic chemical evolution as the s-process production by low-mass AGB stars. The He-shell flashes result in the expansion and, ultimately, ejection of the accreted and then I-process enriched material, via super-Eddington-luminosity winds or Roche-lobe overflow. The WD models do not retain any significant amount of the accreted mass, with a He retention efficiency of ≲ 10 % depending on mass and convective boundary mixing assumptions. This makes the evolutionary path of such systems to supernova Ia explosion highly unlikely.

OBSIFRAC: database-supported software for 3D modeling of rock mass fragmentation

NASA Astrophysics Data System (ADS)

Empereur-Mot, Luc; Villemin, Thierry

2003-03-01

Under stress, fractures in rock masses tend to form fully connected networks. The mass can thus be thought of as a 3D series of blocks produced by fragmentation processes. A numerical model has been developed that uses a relational database to describe such a mass. The model, which assumes the fractures to be plane, allows data from natural networks to test theories concerning fragmentation processes. In the model, blocks are bordered by faces that are composed of edges and vertices. A fracture can originate from a seed point, its orientation being controlled by the stress field specified by an orientation matrix. Alternatively, it can be generated from a discrete set of given orientations and positions. Both kinds of fracture can occur together in a model. From an original simple block, a given fracture produces two simple polyhedral blocks, and the original block becomes compound. Compound and simple blocks created throughout fragmentation are stored in the database. Several fragmentation processes have been studied. In one scenario, a constant proportion of blocks is fragmented at each step of the process. The resulting distribution appears to be fractal, although seed points are random in each fragmented block. In a second scenario, division affects only one random block at each stage of the process, and gives a Weibull volume distribution law. This software can be used for a large number of other applications.

The spatial-temporal evolution law of microseismic activities in the failure process of deep rock masses

NASA Astrophysics Data System (ADS)

Yuan-hui, Li; Gang, Lei; Shi-da, Xu; Da-wei, Wu

2018-07-01

Under high stress and blasting disturbance, the failure of deep rock masses is a complex, dynamic evolutionary process. To reveal the relation between macroscopic failure of deep rock masses and spatial-temporal evolution law of micro-cracking within, the initiation, extension, and connection of micro-cracks under blasting disturbance and the deformation and failure mechanism of deep rock masses were studied. The investigation was carried out using the microseismic (MS) monitoring system established in the deep mining area of Ashele Copper Mine (Xinjiang Uygur Autonomous Region, China). The results showed that the failure of the deep rock masses is a dynamic process accompanied with stress release and stress adjustment. It is not only related to the blasting-based mining, but also associated with zones of stress concentration formed due to the mining. In that space, the concentrated area in the cloud chart for the distribution of MS event density before failure of the rocks shows the basically same pattern with the damaged rocks obtained through scanning of mined-out areas, which indicates that the cloud chart can be used to determine potential risk areas of rocks in the spatial domain. In the time domain, relevant parameters of MS events presented different changes before the failure of the rocks: the energy index decreased while the cumulative apparent volume gradually increased, the magnitude distribution of microseismic events decreased rapidly, and the fractal dimension decreased at first and then remained stable. This demonstrates that the different changes in relevant MS parameters allow researchers to predict the failure time of the rocks. By analysing the dynamic evolution process of the failure of the deep rock masses, areas at potential risk can be predicted spatially and temporally. The result provides guidance for those involved in the safe production and management of underground engineering and establishes a theoretical basis for the study on the stability of deep rock masses.

Search for supersymmetry in events with one lepton and multiple jets in proton-proton collisions at s = 13 TeV

DOE PAGES

Khachatryan, V.; Sirunyan, A. M.; Tumasyan, A.; ...

2017-01-27

Here, a search for supersymmetry is performed in events with a single electron or muon in proton-proton collisions at a center-of-mass energy of 13 TeV. The data were recorded by the CMS experiment at the LHC and correspond to an integrated luminosity of 2.3 fb –1. Several exclusive search regions are defined based on the number of jets and b-tagged jets, the scalar sum of the jet transverse momenta, and the scalar sum of the missing transverse momentum and the transverse momentum of the lepton. The observed event yields in data are consistent with the expected backgrounds from standard modelmore » processes. The results are interpreted using two simplified models of supersymmetric particle spectra, both of which describe gluino pair production. In the first model, each gluino decays via a three-body process to top quarks and a neutralino, which is associated with the observed missing transverse momentum in the event. Gluinos with masses up to 1.6 TeV are excluded for neutralino masses below 600 GeV. In the second model, each gluino decays via a three-body process to two light quarks and a chargino, which subsequently decays to a W boson and a neutralino. The mass of the chargino is taken to be midway between the gluino and neutralino masses. In this model, gluinos with masses below 1.4 TeV are excluded for neutralino masses below 700 GeV.« less

Characterizing the Sources and Processing of Submicron Aerosols at a Coastal Site near Houston, TX, with a Specific Focus on the Impact of Regional Shipping Emissions

NASA Astrophysics Data System (ADS)

Schulze, B.; Wallace, H. W., IV; Bui, A.; Flynn, J. H., III; Erickson, M. H.; Griffin, R. J.

2017-12-01

The Texas Gulf Coast region historically has been influenced heavily by regional shipping emissions. However, the effects of the recent establishment of the North American Emissions Control Area (ECA) on aerosol properties in this region are presently unknown. In order to understand better the current sources and processing mechanisms influencing coastal aerosol near Houston, a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) was deployed for three weeks at a coastal location during May-June 2016. Total mass loadings of organic and inorganic non-refractory aerosol components during onshore flow periods were similar to those published before establishment of the regulations. Using estimated methanesulfonic acid (MSA) mass loadings and published biogenic MSA:non-sea-salt-sulfate (nss-SO4) ratios, we determined that over 70% of nss-SO4 over the Gulf was from anthropogenic sources, predominantly shipping emissions. Mass spectral analysis indicated that for periods with similar backward-trajectory-averaged meteorological conditions, air masses influenced by shipping emissions have an increased mass fraction of ions related to carboxylic acids and a significantly larger oxygen-to-carbon (O:C) ratio than air masses that stay within the ECA boundary, suggesting that shipping emissions impact marine organic aerosol (OA) oxidation state. Amine fragment mass loadings were positively correlated with anthropogenic nss-SO4 during onshore flow, implying anthropogenic-biogenic interaction in marine OA production. Five OA factors were resolved by positive matrix factorization, corresponding to a hydrocarbon-like OA, a semi-volatile OA, and three different oxygenated organic aerosols ranked by their O:C ratio (OOA-1, OOA-2, and OOA-3). OOA-1 constituted the majority of OA mass during a period likely influenced by aqueous-phase processing and may be linked to local glyoxal/methylglyoxal-related sources. OOA-2 was produced within the Houston urban region and was dominant during a multi-day period of air mass recirculation due to land-sea breeze effects. OOA-3, which was linked to shipping emissions, represented the majority of OA mass during onshore flow periods.

Predictive models of radiative neutrino masses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Julio, J., E-mail: julio@lipi.go.id

2016-06-21

We discuss two models of radiative neutrino mass generation. The first model features one–loop Zee model with Z{sub 4} symmetry. The second model is the two–loop neutrino mass model with singly- and doubly-charged scalars. These two models fit neutrino oscillation data well and predict some interesting rates for lepton flavor violation processes.

The Communicative Arts: An Introduction to Mass Media.

ERIC Educational Resources Information Center

Steinberg, Charles S.

All areas of mass communication are surveyed. Man's earliest efforts as a communicator are considered, and what is known about the development of speech and writing is explored. Various theories (including mathematical ones) are reviewed which attempt to explain the processes of both personal and mass communication. Separate chapters focus on the…

Research in Mass Media and Face-to-Face Communication: Bridging the Gap.

ERIC Educational Resources Information Center

Avery, Robert K.; McCain, Thomas A.

Taking the viewpoint of the receiver, this paper explores some differences between interpersonal transactions people have with each other and with the mass media. After addressing an orientation held by many communication scholars that the process of mass communication and interpersonal communication differ only in degree, the paper focuses on a…

Evaluation of a mass flow sensor at a gin

USDA-ARS?s Scientific Manuscript database

As part of a system to optimize the cotton ginning process, a custom-built mass flow sensor was evaluated at USDA-ARS Cotton Ginning Research Unit at Stoneville, Mississippi. The mass flow sensor was fabricated based on the principle of the sensor patented by Thomasson and Sui. The optical and ele...

Mathematical modeling heat and mass transfer processes in porous media

NASA Astrophysics Data System (ADS)

Akhmed-Zaki, Darkhan

2013-11-01

On late development stages of oil-fields appears a complex problem of oil-recovery reduction. One of solution approaches is injecting of surfactant together with water in the form of active impurities into the productive layer - for decreasing oil viscosity and capillary forces between ``oil-water'' phases system. In fluids flow the surfactant can be in three states: dissolved in water, dissolved in oil and adsorbed on pore channels' walls. The surfactant's invasion into the reservoir is tracked by its diffusion with reservoir liquid and mass-exchange with two phase (liquid and solid) components of porous structure. Additionally, in this case heat exchange between fluids (injected, residual) and framework of porous medium has practical importance for evaluating of temperature influences on enhancing oil recovery. Now, the problem of designing an adequate mathematical model for describing a simultaneous flowing heat and mass transfer processes in anisotropic heterogeneous porous medium -surfactant injection during at various temperature regimes has not been fully researched. In this work is presents a 2D mathematical model of surfactant injections into the oil reservoir. Description of heat- and mass transfer processes in a porous media is done through differential and kinetic equations. For designing a computational algorithm is used modify version of IMPES method. The sequential and parallel computational algorithms are developed using an adaptive curvilinear meshes which into account heterogeneous porous structures. In this case we can evaluate the boundaries of our process flows - fronts (``invasion'', ``heat'' and ``mass'' transfers), according to the pressure, temperature, and concentration gradient changes.

Automated characterisation of ultrasound images of ovarian tumours: the diagnostic accuracy of a support vector machine and image processing with a local binary pattern operator

PubMed Central

Khazendar, S.; Sayasneh, A.; Al-Assam, H.; Du, H.; Kaijser, J.; Ferrara, L.; Timmerman, D.; Jassim, S.; Bourne, T.

2015-01-01

Introduction: Preoperative characterisation of ovarian masses into benign or malignant is of paramount importance to optimise patient management. Objectives: In this study, we developed and validated a computerised model to characterise ovarian masses as benign or malignant. Materials and methods: Transvaginal 2D B mode static ultrasound images of 187 ovarian masses with known histological diagnosis were included. Images were first pre-processed and enhanced, and Local Binary Pattern Histograms were then extracted from 2 × 2 blocks of each image. A Support Vector Machine (SVM) was trained using stratified cross validation with randomised sampling. The process was repeated 15 times and in each round 100 images were randomly selected. Results: The SVM classified the original non-treated static images as benign or malignant masses with an average accuracy of 0.62 (95% CI: 0.59-0.65). This performance significantly improved to an average accuracy of 0.77 (95% CI: 0.75-0.79) when images were pre-processed, enhanced and treated with a Local Binary Pattern operator (mean difference 0.15: 95% 0.11-0.19, p < 0.0001, two-tailed t test). Conclusion: We have shown that an SVM can classify static 2D B mode ultrasound images of ovarian masses into benign and malignant categories. The accuracy improves if texture related LBP features extracted from the images are considered. PMID:25897367

The mass formula for an exotic BTZ black hole

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Baocheng, E-mail: zhangbc.zhang@yahoo.com

2016-04-15

An exotic Bañados–Teitelboim–Zanelli (BTZ) black hole has an angular momentum larger than its mass in three dimension (3D), which suggests the possibility that cosmic censorship could be violated if angular momentum is extracted by the Penrose process. In this paper, we propose a mass formula for the exotic BTZ black hole and show no violation of weak cosmic censorship in the gedanken process above by understanding properly its mass formula. Unlike the other black holes, the total energy of the exotic BTZ black hole is represented by the angular momentum instead of the mass, which supports a basic point ofmore » view that the same geometry should be determined by the same energy in 3D general relativity whose equation of motion can be given either by normal 3D Einstein gravity or by exotic 3D Einstein gravity. However, only the mass of the exotic black hole is related to the thermodynamics and other forms of energy are “dumb”, which is consistent with the earlier thermodynamic analysis about exotic black holes.« less

Low-Mass, Low-Power Hall Thruster System

NASA Technical Reports Server (NTRS)

Pote, Bruce

2015-01-01

NASA is developing an electric propulsion system capable of producing 20 mN thrust with input power up to 1,000 W and specific impulse ranging from 1,600 to 3,500 seconds. The key technical challenge is the target mass of 1 kg for the thruster and 2 kg for the power processing unit (PPU). In Phase I, Busek Company, Inc., developed an overall subsystem design for the thruster/cathode, PPU, and xenon feed system. This project demonstrated the feasibility of a low-mass power processing architecture that replaces four of the DC-DC converters of a typical PPU with a single multifunctional converter and a low-mass Hall thruster design employing permanent magnets. In Phase II, the team developed an engineering prototype model of its low-mass BHT-600 Hall thruster system, with the primary focus on the low-mass PPU and thruster. The goal was to develop an electric propulsion thruster with the appropriate specific impulse and propellant throughput to enable radioisotope electric propulsion (REP). This is important because REP offers the benefits of nuclear electric propulsion without the need for an excessively large spacecraft and power system.

Direct mass measurements of proton-rich isotopes of Ge, As, Se, and Br

NASA Astrophysics Data System (ADS)

Lima, G. F.; Lépine-Szily, A.; Audi, G.; Mittig, W.; Chartier, M.; Orr, N. A.; Lichtenthaler, R.; Angelique, J. C.; Casandjian, J. M.; Cunsolo, A.; Donzaud, C.; Foti, A.; Gillibert, A.; Lewitowicz, M.; Lukyanov, S.; MacCormick, M.; Morrissey, D. J.; Ostrowski, A. N.; Sherrill, B. M.; Stephan, C.; Suomijarvi, T.; Tassan-Got, L.; Vieira, D. J.; Villari, A. C.; Wouters, J. M.

2002-04-01

The masses of neutron-deficient nuclei close to the proton drip line are an important input for the rapid proton-capture process modeling above 56Ni. The measurement of the masses of proton-rich nuclei with 32<=Z<=35 has been made using a direct time-of-flight technique. The masses of the nuclides 66As,68Se, and 71Br are reported for the first time, with mass excesses of -51 500(680), -53 620(1000), and -57 060(570) keV being found. The masses agree well in most cases with the Audi-Wapstra systematics.

Nuclear weak interactions, supernova nucleosynthesis and neutrino oscillation

NASA Astrophysics Data System (ADS)

Kajino, Toshitaka

2013-07-01

We study the nuclear weak response in light-to-heavy mass nuclei and calculate neutrino-nucleus cross sections. We apply these cross sections to the explosive nucleosynthesis in core-collapse supernovae and find that several isotopes of rare elements 7Li, 11B, 138La, 180Ta and several others are predominantly produced by the neutrino-process nucleosynthesis. We discuss how to determine the suitable neutrino spectra of three different flavors and their anti-particles in order to explain the observed solar system abundances of these isotopes, combined with Galactic chemical evolution of the light nuclei and the heavy r-process elements. Light-mass nuclei like 7Li and 11B, which are produced in outer He-layer, are strongly affected by the neutrino flavor oscillation due to the MSW (Mikheyev-Smirnov-Wolfenstein) effect, while heavy-mass nuclei like 138La, 180Ta and r-process elements, which are produced in the inner O-Ne-Mg layer or the atmosphere of proto-neutron star, are likely to be free from the MSW effect. Using such a different nature of the neutrino-process nucleosynthesis, we study the neutrino oscillation effects on their abundances, and propose a new novel method to determine the unknown neutrino oscillation parameters, θ13 and mass hierarchy, simultaneously. There is recent evidence that some SiC X grains from the Murchison meteorite may contain supernova-produced neutrino-process 11B and 7Li encapsulated in the grains. Combining the recent experimental constraints on θ13, we show that although the uncertainties are still large, our method hints at a marginal preference for an inverted neutrino mass hierarchy for the first time.

Quantification of colloidal and aqueous element transfer in soils: The dual-phase mass balance model

USGS Publications Warehouse

Bern, Carleton R.; Thompson, Aaron; Chadwick, Oliver A.

2015-01-01

Mass balance models have become standard tools for characterizing element gains and losses and volumetric change during weathering and soil development. However, they rely on the assumption of complete immobility for an index element such as Ti or Zr. Here we describe a dual-phase mass balance model that eliminates the need for an assumption of immobility and in the process quantifies the contribution of aqueous versus colloidal element transfer. In the model, the high field strength elements Ti and Zr are assumed to be mobile only as suspended solids (colloids) and can therefore be used to distinguish elemental redistribution via colloids from redistribution via dissolved aqueous solutes. Calculations are based upon element concentrations in soil, parent material, and colloids dispersed from soil in the laboratory. We illustrate the utility of this model using a catena in South Africa. Traditional mass balance models systematically distort elemental gains and losses and changes in soil volume in this catena due to significant redistribution of Zr-bearing colloids. Applying the dual-phase model accounts for this colloidal redistribution and we find that the process accounts for a substantial portion of the major element (e.g., Al, Fe and Si) loss from eluvial soil. In addition, we find that in illuvial soils along this catena, gains of colloidal material significantly offset aqueous elemental loss. In other settings, processes such as accumulation of exogenous dust can mimic the geochemical effects of colloid redistribution and we suggest strategies for distinguishing between the two. The movement of clays and colloidal material is a major process in weathering and pedogenesis; the mass balance model presented here is a tool for quantifying effects of that process over time scales of soil development.

Theory of Bipolar Outflows from Accreting Hot Stars

NASA Astrophysics Data System (ADS)

Konigl, A.

1996-05-01

There is a growing number of observational indicators for the presence of bipolar outflows in massive, young stellar objects that are still accreting mass as part of their formation process. In particular, there is evidence that the outflows from these objects can attain higher velocities and kinetic luminosities than their lower-mass counterparts. Furthermore, the higher-mass objects appear to smoothly continue the correlation found in T Tauri stars between outflow and accretion signatures, and in several cases there are direct clues to the existence of a disk from optical and infrared spectroscopy. These results suggest that the disk--outflow connection found in low-mass pre--main-sequence stars extends to more massive objects, and that a similar physical mechanism may drive the outflows in both cases. In this presentation, I first critically examine the observational basis for this hypothesis, considering, among other things, the possibility that several low-luminosity outflows might occasionally masquerade as a single flow from a luminous object, and the effects that the radiation field of a hot star could have on the spectroscopic diagnostics of an accretion-driven outflow. I then go on to consider how the commonly invoked centrifugally driven wind models of bipolar outflows in low-mass stars would be affected by the various physical processes (such as photoionization, photoevaporation, radiation pressure, and stellar wind ram pressure) that operate in higher-mass stars. I conclude by mentioning some of the tantalizing questions that one could hope to address as this young field of research continues to develop (for example: is there a high-mass analog of the FU Orionis outburst phenomenon? Could one use observations of progressively more massive, and hence less convective, stars to elucidate the role of stellar magnetic fields in the accretion and outflow processes? Would it be possible to observationally identify massive stars that have reached the main sequence while they were still accreting? Does the evolution of protostellar disks differ in low-mass and high-mass objects?).

Decon2LS: An open-source software package for automated processing and visualization of high resolution mass spectrometry data

PubMed Central

Jaitly, Navdeep; Mayampurath, Anoop; Littlefield, Kyle; Adkins, Joshua N; Anderson, Gordon A; Smith, Richard D

2009-01-01

Background Data generated from liquid chromatography coupled to high-resolution mass spectrometry (LC-MS)-based studies of a biological sample can contain large amounts of biologically significant information in the form of proteins, peptides, and metabolites. Interpreting this data involves inferring the masses and abundances of biomolecules injected into the instrument. Because of the inherent complexity of mass spectral patterns produced by these biomolecules, the analysis is significantly enhanced by using visualization capabilities to inspect and confirm results. In this paper we describe Decon2LS, an open-source software package for automated processing and visualization of high-resolution MS data. Drawing extensively on algorithms developed over the last ten years for ICR2LS, Decon2LS packages the algorithms as a rich set of modular, reusable processing classes for performing diverse functions such as reading raw data, routine peak finding, theoretical isotope distribution modelling, and deisotoping. Because the source code is openly available, these functionalities can now be used to build derivative applications in relatively fast manner. In addition, Decon2LS provides an extensive set of visualization tools, such as high performance chart controls. Results With a variety of options that include peak processing, deisotoping, isotope composition, etc, Decon2LS supports processing of multiple raw data formats. Deisotoping can be performed on an individual scan, an individual dataset, or on multiple datasets using batch processing. Other processing options include creating a two dimensional view of mass and liquid chromatography (LC) elution time features, generating spectrum files for tandem MS data, creating total intensity chromatograms, and visualizing theoretical peptide profiles. Application of Decon2LS to deisotope different datasets obtained across different instruments yielded a high number of features that can be used to identify and quantify peptides in the biological sample. Conclusion Decon2LS is an efficient software package for discovering and visualizing features in proteomics studies that require automated interpretation of mass spectra. Besides being easy to use, fast, and reliable, Decon2LS is also open-source, which allows developers in the proteomics and bioinformatics communities to reuse and refine the algorithms to meet individual needs. Decon2LS source code, installer, and tutorials may be downloaded free of charge at . PMID:19292916

Decon2LS: An open-source software package for automated processing and visualization of high resolution mass spectrometry data.

PubMed

Jaitly, Navdeep; Mayampurath, Anoop; Littlefield, Kyle; Adkins, Joshua N; Anderson, Gordon A; Smith, Richard D

2009-03-17

Data generated from liquid chromatography coupled to high-resolution mass spectrometry (LC-MS)-based studies of a biological sample can contain large amounts of biologically significant information in the form of proteins, peptides, and metabolites. Interpreting this data involves inferring the masses and abundances of biomolecules injected into the instrument. Because of the inherent complexity of mass spectral patterns produced by these biomolecules, the analysis is significantly enhanced by using visualization capabilities to inspect and confirm results. In this paper we describe Decon2LS, an open-source software package for automated processing and visualization of high-resolution MS data. Drawing extensively on algorithms developed over the last ten years for ICR2LS, Decon2LS packages the algorithms as a rich set of modular, reusable processing classes for performing diverse functions such as reading raw data, routine peak finding, theoretical isotope distribution modelling, and deisotoping. Because the source code is openly available, these functionalities can now be used to build derivative applications in relatively fast manner. In addition, Decon2LS provides an extensive set of visualization tools, such as high performance chart controls. With a variety of options that include peak processing, deisotoping, isotope composition, etc, Decon2LS supports processing of multiple raw data formats. Deisotoping can be performed on an individual scan, an individual dataset, or on multiple datasets using batch processing. Other processing options include creating a two dimensional view of mass and liquid chromatography (LC) elution time features, generating spectrum files for tandem MS data, creating total intensity chromatograms, and visualizing theoretical peptide profiles. Application of Decon2LS to deisotope different datasets obtained across different instruments yielded a high number of features that can be used to identify and quantify peptides in the biological sample. Decon2LS is an efficient software package for discovering and visualizing features in proteomics studies that require automated interpretation of mass spectra. Besides being easy to use, fast, and reliable, Decon2LS is also open-source, which allows developers in the proteomics and bioinformatics communities to reuse and refine the algorithms to meet individual needs.Decon2LS source code, installer, and tutorials may be downloaded free of charge at http://http:/ncrr.pnl.gov/software/.

A parametric study of segregation effects during vertical Bridgman crystal growth with an axial magnetic field

NASA Astrophysics Data System (ADS)

Ma, N.; Walker, J. S.

2000-01-01

This paper presents a model for the unsteady transport of a dopant during the vertical Bridgman crystal growth process with a planar crystal-melt interface and with an axial magnetic field, and investigates the effects of varying different process variables on the crystal composition. The convective mass transport due to the buoyant convection in the melt produces nonuniformities in the concentration in both the melt and the crystal. The convective mass transport plays an important role for all magnetic field strengths considered. Diffusive mass transport begins to dominate for a magnetic flux density of 4 T and a fast growth rate, producing crystals which have an axial variation of the radially averaged crystal composition approaching that of the diffusion-controlled limit. Dopant distributions for several different combinations of process parameters are presented.

[THE ROLE OF SYSTEM QUORUM SENSING UNDER CHRONIC UROGENITAL CHLAMYDIA INFECTION].

PubMed

2015-10-01

It is established that system quorum sensing (QS) assure social behavior of bacteria in regulation of genes of virulence and generalization of inflectional inflammatory process under chronic urogenital chlamydia infection. The techniques of gas chromatography and mass-spectrometry were applied to detect molecular markers of generalization of infectious process under urogenital chlamydiasis--activators of QS microbes (lactones, quinolones, furan ethers). The developed diagnostic gas chromatography and mass-spectrometry criteria of indexation of molecular markers under chronic urogenital chlamydia infection have high level of diagnostic sensitivity, specificity and prognostic value of positive and negative result. The application of techniques of gas chromatography and mass-spectrometry permits enhancing effectiveness of diagnostic of chronic inflectional inflammatory diseases of urogenital system of chlamydia etiology with identification of prognostic criteria of generalization of infectious process and subsequent prescription of timely and appropriate therapy

Exploring bubble oscillation and mass transfer enhancement in acoustic-assisted liquid-liquid extraction with a microfluidic device

NASA Astrophysics Data System (ADS)

Xie, Yuliang; Chindam, Chandraprakash; Nama, Nitesh; Yang, Shikuan; Lu, Mengqian; Zhao, Yanhui; Mai, John D.; Costanzo, Francesco; Huang, Tony Jun

2015-07-01

We investigated bubble oscillation and its induced enhancement of mass transfer in a liquid-liquid extraction process with an acoustically-driven, bubble-based microfluidic device. The oscillation of individually trapped bubbles, of known sizes, in microchannels was studied at both a fixed frequency, and over a range of frequencies. Resonant frequencies were analytically identified and were found to be in agreement with the experimental observations. The acoustic streaming induced by the bubble oscillation was identified as the cause of this enhanced extraction. Experiments extracting Rhodanmine B from an aqueous phase (DI water) to an organic phase (1-octanol) were performed to determine the relationship between extraction efficiency and applied acoustic power. The enhanced efficiency in mass transport via these acoustic-energy-assisted processes was confirmed by comparisons against a pure diffusion-based process.

Regolith-Derived Heat Shield for Planetary Body Entry and Descent System with In Situ Fabrication

NASA Technical Reports Server (NTRS)

Hogue, Michael D.; Mueller, Robert P.; Rasky, Daniel J.; Hintze, Paul E.; Sibille, Laurent

2011-01-01

In this paper we will discuss a new mass-efficient and innovative way of protecting high-mass spacecraft during planetary Entry, Descent & Landing (EDL). Heat shields fabricated in situ can provide a thermal-protection system (TPS) for spacecraft that routinely enter a planetary atmosphere. By fabricating the heat shield with space resources from regolith materials available on moons and asteroids, it is possible to avoid launching the heat-shield mass from Earth. Three regolith processing and manufacturing methods will be discussed: 1) oxygen & metal extraction ISRU processes produce glassy melts enriched in alumina and titania, processed to obtain variable density, high melting point and heat-resistance; 2) compression and sintering of the regolith yield low density materials; 3) in-situ derived high-temperature polymers are created to bind regolith particles together, with a lower energy budget.

Mass Measurement of 80Y by β-γ Coincidence Spectroscopy

NASA Astrophysics Data System (ADS)

Brenner, D. S.; Barton, C. J.; Zamfir, N. V.; Caprio, M. A.; Aprahamian, A.; Beausang, C. W.; Berant, Z.; Casten, R. F.; Cooper, J. R.; Gill, R. L.; Kruecken, R.; Novak, J. R.; Pietralla, N.; Shawcross, M.; Teymurazyan, A.; Wolf, A.; Wiescher, M.

2003-06-01

The QEC value of 80Y has been measured by β-γ coincidence spectroscopy to be ≥8929(83) keV. Combing this result with the adopted mass excess of the daughter 80Sr gives a mass excess for 80Y of ≥ -61376(83) keV. Results are compared with other measurements, with Audi-Wapstra systematics, and with predictions of mass formulas. Implications for rp-process simulations are considered.

Apparatus and methods for continuous beam fourier transform mass spectrometry

DOEpatents

McLuckey, Scott A.; Goeringer, Douglas E.

2002-01-01

A continuous beam Fourier transform mass spectrometer in which a sample of ions to be analyzed is trapped in a trapping field, and the ions in the range of the mass-to-charge ratios to be analyzed are excited at their characteristic frequencies of motion by a continuous excitation signal. The excited ions in resonant motions generate real or image currents continuously which can be detected and processed to provide a mass spectrum.

Head-on collisions of unequal mass black holes in D=5 dimensions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Witek, Helvi; Cardoso, Vitor; Department of Physics and Astronomy, University of Mississippi, University, Mississippi 38677

We study head-on collisions of unequal mass black hole binaries in D=5 spacetime dimensions, with mass ratios between 1:1 and 1:4. Information about gravitational radiation is extracted by using the Kodama-Ishibashi gauge-invariant formalism and details of the apparent horizon of the final black hole. We present waveforms, total integrated energy and momentum for this process. Our results show surprisingly good agreement, within 5% or less, with those extrapolated from linearized, point-particle calculations. Our results also show that consistency with the area theorem bound requires that the same process in a large number of spacetime dimensions must display new features.

Focused analyte spray emission apparatus and process for mass spectrometric analysis

DOEpatents

Roach, Patrick J [Kennewick, WA; Laskin, Julia [Richland, WA; Laskin, Alexander [Richland, WA

2012-01-17

An apparatus and process are disclosed that deliver an analyte deposited on a substrate to a mass spectrometer that provides for trace analysis of complex organic analytes. Analytes are probed using a small droplet of solvent that is formed at the junction between two capillaries. A supply capillary maintains the droplet of solvent on the substrate; a collection capillary collects analyte desorbed from the surface and emits analyte ions as a focused spray to the inlet of a mass spectrometer for analysis. The invention enables efficient separation of desorption and ionization events, providing enhanced control over transport and ionization of the analyte.

THE PROCESS OF MASS TRANSFER ON THE SOLID-LIQUID BOUNDARY LAYER DURING THE RELEASE OF DICLOFENAC SODIUM AND PAPAVERINE HYDROCHLORIDE FROM TABLETS IN A PADDLE APPARATUS.

PubMed

Kasperek, Regina; Zimmer, Lukasz; Poleszak, Ewa

2016-01-01

The release study of diclofenac sodium (DIC) and papaverine hydrochloride (PAP) from two formulations of the tablets in the paddle apparatus using different rotation speeds to characterize the process of mass transfer on the solid-liquid boundary layer was carried out. The dissolution process of active substances was described by values of mass transfer coefficients, the diffusion boundary layer thickness and dimensionless numbers (Sh and Re). The values of calculated parameters showed that the release of DIC and PAP from tablets comprising potato starch proceeded faster than from tablets containing HPMC and microcrystalline cellulose. They were obtained by direct dependencies between Sh and Re in the range from 75 rpm to 125 rpm for both substances from all tablets. The description of the dissolution process with the dimensionless numbers make it possible to plan the drug with the required release profile under given in vitro conditions.

Effects of oxygen content on the oxidation process of Si-containing steel during anisothermal heating

NASA Astrophysics Data System (ADS)

Yuan, Qing; Xu, Guang; Liang, Wei-cheng; He, Bei; Zhou, Ming-xing

2018-02-01

The oxidizing behavior of Si-containing steel was investigated in an O2 and N2 binary-component gas with oxygen contents ranging between 0.5vol% and 4.0vol% under anisothermal-oxidation conditions. A simultaneous thermal analyzer was employed to simulate the heating process of Si-containing steel in industrial reheating furnaces. The oxidation gas mixtures were introduced from the commencement of heating. The results show that the oxidizing rate remains constant in the isothermal holding process at high temperatures; therefore, the mass change versus time presents a linear law. A linear relation also exists between the oxidizing rate and the oxygen content. Using the linear regression equation, the oxidation rate at different oxygen contents can be predicted. In addition, the relationship between the total mass gain and the oxygen content is linear; thus, the total mass gain at oxygen contents between 0.5vol%-4.0vol% can be determined. These results enrich the theoretical studies of the oxidation process in Si-containing steels.

Development of wet process with substitution reaction for the mass production of Li 2TiO 3 pebbles

NASA Astrophysics Data System (ADS)

Tsuchiya, Kunihiko; Kawamura, Hiroshi

2000-12-01

Recently, lithium titanate (Li 2TiO 3) has attracted the attention of many researchers from the point of good tritium recovery at low temperature, chemical stability, etc. As the shape of Li 2TiO 3, a small pebble was selected as the Japanese design for a fusion reactor blanket. On the other hand, as the fabrication method of Li 2TiO 3 pebbles, the wet process is the most advantageous from the viewpoint of mass production, etc. In this study, fabrication of small Li 2TiO 3 pebbles less than ∅0.5 mm was performed by the wet process with substitution reaction, and the characteristics of Li 2TiO 3 pebbles fabricated by this process were evaluated. From the results of the fabrication tests, excellent prospects were obtained concerning mass production of Li 2TiO 3 pebbles with the target density (80-85% T.D.) and target diameter (less than ∅0.5 mm).

Sailboats, Inc.: A Fourth Grade Mass Production Program

ERIC Educational Resources Information Center

Kazarian, Edward N.; And Others

1976-01-01

Describes the implementation of a hands-on minicourse on mass production designed to help students understand this industrial process. Provides instructions and pattern guide for making string-art mandala sailboats. (TA)

Recent progress in understanding the eruptions of classical novae

NASA Technical Reports Server (NTRS)

Shara, Michael M.

1988-01-01

Dramatic progress has occurred in the last two decades in understanding the physical processes and events leading up to, and transpiring during the eruption of a classical nova. The mechanism whereby a white dwarf accreting hydrogen-rich matter from a low-mass main-sequence companion produces a nova eruption has been understood since 1970. The mass-transferring binary stellar configuration leads inexorably to thermonuclear runaways detected at distances of megaparsecs. Summarized here are the efforts of many researchers in understanding the physical processes which generate nova eruptions; the effects upon nova eruptions of different binary-system parameters (e.g., chemical composition or mass of the white dwarf, different mass accretion rates); the possible metamorphosis from dwarf to classical novae and back again; and observational diagnostics of novae, including x ray and gamma ray emission, and the characteristics and distributions of novae in globular clusters and in extragalactic systems. While the thermonuclear-runaway model remains the successful cornerstone of nova simulation, it is now clear that a wide variety of physical processes, and three-dimensional hydrodynamic simulations, will be needed to explain the rich spectrum of behavior observed in erupting novae.

A Procedure to Simultaneously Determine the Calcium, Chromium, and Titanium Isotopic Compositions of Astromaterials

NASA Technical Reports Server (NTRS)

Tappa, M. J.; Simon, J. I; Jordan, M. K.; Young, E. D.

2015-01-01

Many elements display both linear (mass-dependent) and non-linear (mass-independent) isotope anomalies (relative to a common reservoir). In early Solar System objects, with the exception of oxygen, mass-dependent isotope anomalies are most commonly thought to result from phase separation processes such as evaporation and condensation, whereas many mass-independent isotope anomalies likely reflect radiogenic ingrowth or incomplete mixing of presolar components in the proto-planetary disk. Coupling the isotopic characterization of multiple elements with differing volatilities in single objects may provide information regarding the location, source material, and/or processes involved in the formation of early Solar System solids. Here, we follow up on the work presented in, and detail new procedures developed to make high-precision multi-isotope measurements of Calcium, Chromium, and Titanium with small or limited amounts of sample using thermal ionization mass spectrometry and multi-collector ICP-MS, and characterize a suite of chondritic and terrestrial standards.

Comparison of ocean mass content change from direct and inversion based approaches

NASA Astrophysics Data System (ADS)

Uebbing, Bernd; Kusche, Jürgen; Rietbroek, Roelof

2017-04-01

The GRACE satellite mission provides an indispensable tool for measuring oceanic mass variations. Such time series are essential to separate global mean sea level rise in thermosteric and mass driven contributions, and thus to constrain ocean heat content and (deep) ocean warming when viewed together with altimetry and Argo data. However, published estimates over the GRACE era differ, not only depending on the time window considered. Here, we will look into sources of such differences with direct and inverse approaches. Deriving ocean mass time series requires several processing steps; choosing a GRACE (and altimetry and Argo) product, data coverage, masks and filters to be applied in either spatial or spectral domain, corrections related to spatial leakage, GIA and geocenter motion need to be accounted for. In this study, we quantify the effects of individual processing choices and assumptions of the direct and inversion based approaches to derive ocean mass content change. Furthermore, we compile the different estimates from existing literature and sources, to highlight the differences.

The Nuclear and Particle Physics of Neutrinoless Double Beta Decay

NASA Astrophysics Data System (ADS)

Haxton, Wick

2014-03-01

Fortuitous properties of nuclei allow us to isolate and study the rare second-order weak process of double beta decay. In particular, the decay channel in which a final state of two electrons and no neutrinos is produced - neutrinoless double beta decay - provides our best test of lepton number conservation and the Majorana mass of the electron neutrino. I will describe the connections between this process and the charge conjugation properties of the neutrino, including the possibility that the presence of both Dirac and Majorana masses accounts for the anomalous scale of neutrino masses. The extraordinary progress made over the past two decades has prepared the way for next-generation experiments that will probe Majorana masses at levels where nonzero rates may be found, given what we now know about neutrino mass splittings. I will describe some of the heroic efforts underway to develop detectors of unprecedented size, radiopurity, depth, and thus sensitivity. Work supported by the Office of Science, US DOE.

Upper bound on the center-of-mass energy of the collisional Penrose process

NASA Astrophysics Data System (ADS)

Hod, Shahar

2016-08-01

Following the interesting work of Bañados, Silk, and West (2009) [6], it is repeatedly stated in the physics literature that the center-of-mass energy, Ec.m, of two colliding particles in a maximally rotating black-hole spacetime can grow unboundedly. For this extreme scenario to happen, the particles have to collide at the black-hole horizon. In this paper we show that Thorne's famous hoop conjecture precludes this extreme scenario from occurring in realistic black-hole spacetimes. In particular, it is shown that a new (and larger) horizon is formed before the infalling particles reach the horizon of the original black hole. As a consequence, the center-of-mass energy of the collisional Penrose process is bounded from above by the simple scaling relation Ec.mmax / 2 μ ∝(M / μ) 1 / 4, where M and μ are respectively the mass of the central black hole and the proper mass of the colliding particles.

Barium and neodymium isotopic anomalies in the Allende meteorite

NASA Technical Reports Server (NTRS)

Mcculloch, M. T.; Wasserburg, G. J.

1978-01-01

The discovery of Ba and Nd isotopic anomalies in two inclusions from the Allende meteorite is reported. The inclusions are Ca-Al-rich objects typical of the type considered as high-temperature condensation products in the solar nebula and contain distinctive Mg and O isotopic anomalies of the FUN (mass Fractionation, Unknown Nuclear processes) type. Mass-spectrometry results are discussed which show that inclusion C1 has anomalies in Ba at masses 134 and 136, while inclusion EK1-4-1 exhibits large marked negative anomalies at 130, 132, 134, and 136, as well as a positive anomaly at 137. It is also found that inclusion EK1-4-1 shows marked negative anomalies in Nd at masses 142, 146, 148, and 150, in addition to a positive anomaly at 145. These isotopic shifts are attributed to addition of r-process nuclei rather than mass fractionation. It is suggested that an onion-shell supernova explosion followed by injection into the solar nebula is the most likely generic model that may explain the observations.

A common mass scaling for satellite systems of gaseous planets.

PubMed

Canup, Robin M; Ward, William R

2006-06-15

The Solar System's outer planets that contain hydrogen gas all host systems of multiple moons, which notably each contain a similar fraction of their respective planet's mass (approximately 10(-4)). This mass fraction is two to three orders of magnitude smaller than that of the largest satellites of the solid planets (such as the Earth's Moon), and its common value for gas planets has been puzzling. Here we model satellite growth and loss as a forming giant planet accumulates gas and rock-ice solids from solar orbit. We find that the mass fraction of its satellite system is regulated to approximately 10(-4) by a balance of two competing processes: the supply of inflowing material to the satellites, and satellite loss through orbital decay driven by the gas. We show that the overall properties of the satellite systems of Jupiter, Saturn and Uranus arise naturally, and suggest that similar processes could limit the largest moons of extrasolar Jupiter-mass planets to Moon-to-Mars size.

The stellar metallicity gradients in galaxy discs in a cosmological scenario

NASA Astrophysics Data System (ADS)

Tissera, Patricia B.; Machado, Rubens E. G.; Sanchez-Blazquez, Patricia; Pedrosa, Susana E.; Sánchez, Sebastián F.; Snaith, Owain; Vilchez, Jose

2016-08-01

Context. The stellar metallicity gradients of disc galaxies provide information on disc assembly, star formation processes, and chemical evolution. They also might store information on dynamical processes that could affect the distribution of chemical elements in the gas phase and the stellar components. Understanding their joint effects within a hierarchical clustering scenario is of paramount importance. Aims: We studied the stellar metallicity gradients of simulated discs in a cosmological simulation. We explored the dependence of the stellar metallicity gradients on stellar age and on the size and mass of the stellar discs. Methods: We used a catalogue of galaxies with disc components selected from a cosmological hydrodynamical simulation performed including a physically motivated supernova feedback and chemical evolution. Disc components were defined based on angular momentum and binding energy criteria. The metallicity profiles were estimated for stars with different ages. We confront our numerical findings with results from the Calar Alto Legacy Integral Field Area (CALIFA) Survey. Results: The simulated stellar discs are found to have metallicity profiles with slopes in global agreement with observations. Low stellar mass galaxies tend to have a larger variety of metallicity slopes. When normalized by the half-mass radius, the stellar metallicity gradients do not show any dependence and the dispersion increases significantly, regardless of the galaxy mass. Galaxies with stellar masses o f around 1010M⊙ show steeper negative metallicity gradients. The stellar metallicity gradients correlate with the half-mass radius. However, the correlation signal is not present when they are normalized by the half-mass radius. Stellar discs with positive age gradients are detected to have negative and positive metallicity gradients, depending on the relative importance of recent star formation activity in the central regions. Conclusions: Our results suggest that inside-out formation is the main process responsible for the metallicity and age profiles. The large dispersions in the metallicity gradients as a function of stellar mass could be ascribed to the effects of dynamical processes such as mergers, interactions and/or migration as well as those regulating the conversion of gas into stars. The fingerprints of the inside-out formation seem better preserved by the stellar metallicity gradients as a function of the half-mass radius.

Cascading Air Power Effects Simulation (CAPES)

DTIC Science & Technology

2010-05-01

governments using autmated natural language processing techniques. New data on the attitudes of the masses and Arabic mass media were also collected using...environmental contexts. To meet this objective, new data was collected on the behavior of groups and governments using automated natural language processing...illustrate one fruitful avenue for future research. We show that we can model the first, second , and third order effects of US actions on group violence

EOforge: Generic Open Framework for Earth Observation Data Processing Systems

DTIC Science & Technology

2006-09-01

Allow the use of existing interfaces, i.e. MUIS: ESA multimission catalogue for EO products. • Support last EO systems technologies, i.e. MASS ...5. Extensibility and configurability to allow customisation and the inclusion of new functionality. 6. Multi-instrument and multi-mission processing...such as: • MUIS: ESA multimission catalogue for EO products. • MASS (Multi-Application Support Service System): ESA web services technology standard

Proteomic Prediction of Breast Cancer Risk: A Cohort Study

DTIC Science & Technology

2007-03-01

Total 1728 1189 68.81 (c) Data processing. Data analysis was performed using in-house software (Du P , Angeletti RH. Automatic deconvolution of...isotope-resolved mass spectra using variable selection and quantized peptide mass distribution. Anal Chem., 78:3385-92, 2006; P Du, R Sudha, MB...control. Reportable Outcomes So far our publications have been on the development of algorithms for signal processing: 1. Du P , Angeletti RH

Carbon nanotube mass production: principles and processes.

PubMed

Zhang, Qiang; Huang, Jia-Qi; Zhao, Meng-Qiang; Qian, Wei-Zhong; Wei, Fei

2011-07-18

Our society requires new materials for a sustainable future, and carbon nanotubes (CNTs) are among the most important advanced materials. This Review describes the state-of-the-art of CNT synthesis, with a focus on their mass-production in industry. At the nanoscale, the production of CNTs involves the self-assembly of carbon atoms into a one-dimensional tubular structure. We describe how this synthesis can be achieved on the macroscopic scale in processes akin to the continuous tonne-scale mass production of chemical products in the modern chemical industry. Our overview includes discussions on processing methods for high-purity CNTs, and the handling of heat and mass transfer problems. Manufacturing strategies for agglomerated and aligned single-/multiwalled CNTs are used as examples of the engineering science of CNT production, which includes an understanding of their growth mechanism, agglomeration mechanism, reactor design, and process intensification. We aim to provide guidelines for the production and commercialization of CNTs. Although CNTs can now be produced on the tonne scale, knowledge of the growth mechanism at the atomic scale, the relationship between CNT structure and application, and scale-up of the production of CNTs with specific chirality are still inadequate. A multidisciplinary approach is a prerequisite for the sustainable development of the CNT industry. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Data on the impact of increasing the W amount on the mass density and compressive properties of Ni-W alloys processed by spark plasma sintering.

PubMed

Sadat, T; Hocini, A; Lilensten, L; Faurie, D; Tingaud, D; Dirras, G

2016-06-01

Bulk Ni-W alloys having composite-like microstructures are processed by spark plasma sintering (SPS) route of Ni and W powder blends as reported in a recent study of Sadat et al. (2016) (DOI of original article: doi:10.1016/j.matdes.2015.10.083) [1]. The present dataset deals with determination of mass density and evaluation of room temperature compressive mechanical properties as function of the amount of W (%wt. basis). The presented data concern: (i) measurement of the mass of each investigated Ni-W alloy which is subsequently used to compute the mass density of the alloy and (ii) the raw (stress (MPa) and strain ([Formula: see text])) data, which can be subsequently used for stress/ strain plots.

Data on the impact of increasing the W amount on the mass density and compressive properties of Ni–W alloys processed by spark plasma sintering

PubMed Central

Sadat, T.; Hocini, A.; Lilensten, L.; Faurie, D.; Tingaud, D.; Dirras, G.

2016-01-01

Bulk Ni–W alloys having composite-like microstructures are processed by spark plasma sintering (SPS) route of Ni and W powder blends as reported in a recent study of Sadat et al. (2016) (DOI of original article: doi:10.1016/j.matdes.2015.10.083) [1]. The present dataset deals with determination of mass density and evaluation of room temperature compressive mechanical properties as function of the amount of W (%wt. basis). The presented data concern: (i) measurement of the mass of each investigated Ni–W alloy which is subsequently used to compute the mass density of the alloy and (ii) the raw (stress (MPa) and strain (ΔLL0)) data, which can be subsequently used for stress/ strain plots. PMID:27158658

Evaporation of (quantum) black holes and energy conservation

NASA Astrophysics Data System (ADS)

Torres, R.; Fayos, F.; Lorente-Espín, O.

2013-03-01

We consider Hawking radiation as due to a tunneling process in a black hole were quantum corrections, derived from Quantum Einstein Gravity, are taken into account. The consequent derivation, satisfying conservation laws, leads to a deviation from an exact thermal spectrum. This has consequences for the information loss paradox since the non-thermal radiation is shown to carry information out of the black hole. Under the appropriate approximation, a quantum corrected temperature is assigned to the black hole. The evolution of the quantum black hole as it evaporates is then described by taking into account the full implications of energy conservation as well as the backscattered radiation. It is shown that, as a critical mass of the order of Planck's mass is reached, the evaporation process decelerates abruptly while the black hole mass decays towards this critical mass.

A Universal Model for Solar Eruptions

NASA Technical Reports Server (NTRS)

Wyper, Peter F.; Antiochos, Spiro K.; Devore, C. Richard

2017-01-01

Magnetically driven eruptions on the Sun, from stellar-scale coronal mass ejections1 to small-scale coronal X-ray and extreme-ultraviolet jets, have frequently been observed to involve the ejection of the highly stressed magnetic flux of a filament. Theoretically, these two phenomena have been thought to arise through very different mechanisms: coronal mass ejections from an ideal (non-dissipative) process, whereby the energy release does not require a change in the magnetic topology, as in the kink or torus instability; and coronal jets from a resistive process, involving magnetic reconnection. However, it was recently concluded from new observations that all coronal jets are driven by filament ejection, just like large mass ejections. This suggests that the two phenomena have physically identical origin and hence that a single mechanism may be responsible, that is, either mass ejections arise from reconnection, or jets arise from an ideal instability. Here we report simulations of a coronal jet driven by filament ejection, whereby a region of highly sheared magnetic field near the solar surface becomes unstable and erupts. The results show that magnetic reconnection causes the energy release via 'magnetic breakout', a positive feedback mechanism between filament ejection and reconnection. We conclude that if coronal mass ejections and jets are indeed of physically identical origin (although on different spatial scales) then magnetic reconnection (rather than an ideal process) must also underlie mass ejections, and that magnetic breakout is a universal model for solar eruptions.

Elucidating rhizosphere processes by mass spectrometry - A review.

PubMed

Rugova, Ariana; Puschenreiter, Markus; Koellensperger, Gunda; Hann, Stephan

2017-03-01

The presented review discusses state-of-the-art mass spectrometric methods, which have been developed and applied for investigation of chemical processes in the soil-root interface, the so-called rhizosphere. Rhizosphere soil's physical and chemical characteristics are to a great extent influenced by a complex mixture of compounds released from plant roots, i.e. root exudates, which have a high impact on nutrient and trace element dynamics in the soil-root interface as well as on microbial activities or soil physico-chemical characteristics. Chemical characterization as well as accurate quantification of the compounds present in the rhizosphere is a major prerequisite for a better understanding of rhizosphere processes and requires the development and application of advanced sampling procedures in combination with highly selective and sensitive analytical techniques. During the last years, targeted and non-targeted mass spectrometry-based methods have emerged and their combination with specific separation methods for various elements and compounds of a wide polarity range have been successfully applied in several studies. With this review we critically discuss the work that has been conducted within the last decade in the context of rhizosphere research and elemental or molecular mass spectrometry emphasizing different separation techniques as GC, LC and CE. Moreover, selected applications such as metal detoxification or nutrient acquisition will be discussed regarding the mass spectrometric techniques applied in studies of root exudates in plant-bacteria interactions. Additionally, a more recent isotope probing technique as novel mass spectrometry based application is highlighted. Copyright © 2017 Elsevier B.V. All rights reserved.

Experimental study and numerical simulation of evacuation from a dormitory

NASA Astrophysics Data System (ADS)

Lei, Wenjun; Li, Angui; Gao, Ran; Zhou, Ning; Mei, Sen; Tian, Zhenguo

2012-11-01

The evacuation process of students from a dormitory is investigated by both experiment and modeling. We investigate the video record of pedestrian movement in a dormitory, and find some typical characteristics of evacuation, including continuous pedestrian flow, mass behavior and so on. Based on the experimental observation, we found that simulation results considering pre-movement time are closer to the experimental results. With the model considering pre-movement time, we simulate the evacuation process and compare the simulation results with the experimental results, and find that they agree with each other closely. The crowd massing phenomenon is conducted in this paper. It is found that different crowd massing phenomena will emerge due to different desired velocities. The crowd massing phenomenon could be more serious with the increase of the desired velocity. In this study, we also found the faster-is-slower effect. When the positive effect produced by increasing the desired velocity is not sufficient for making up for its negative effect, the phenomenon of the greater the desired velocity the longer the time required for evacuation will emerge. From the video record, it can be observed that the mass behavior is obvious during the evacuation process. And the mass phenomenon could also be found in simulation. The results obtained from our study are also suitable to all these buildings in which both living and resting areas occupy the majority space, such as dormitories, residential buildings, hotels (restaurants) and so on.

How good are the Garvey-Kelson predictions of nuclear masses?

NASA Astrophysics Data System (ADS)

Morales, Irving O.; López Vieyra, J. C.; Hirsch, J. G.; Frank, A.

2009-09-01

The Garvey-Kelson relations are used in an iterative process to predict nuclear masses in the neighborhood of nuclei with measured masses. Average errors in the predicted masses for the first three iteration shells are smaller than those obtained with the best nuclear mass models. Their quality is comparable with the Audi-Wapstra extrapolations, offering a simple and reproducible procedure for short range mass predictions. A systematic study of the way the error grows as a function of the iteration and the distance to the known masses region, shows that a correlation exists between the error and the residual neutron-proton interaction, produced mainly by the implicit assumption that V varies smoothly along the nuclear landscape.

Low-mass black holes as the remnants of primordial black hole formation.

PubMed

Greene, Jenny E

2012-01-01

Bridging the gap between the approximately ten solar mass 'stellar mass' black holes and the 'supermassive' black holes of millions to billions of solar masses are the elusive 'intermediate-mass' black holes. Their discovery is key to understanding whether supermassive black holes can grow from stellar-mass black holes or whether a more exotic process accelerated their growth soon after the Big Bang. Currently, tentative evidence suggests that the progenitors of supermassive black holes were formed as ∼10(4)-10(5) M(⊙) black holes via the direct collapse of gas. Ongoing searches for intermediate-mass black holes at galaxy centres will help shed light on this formation mechanism.

Physical Vapor Transport of Lead Telluride

NASA Technical Reports Server (NTRS)

Palosz, W.

1997-01-01

Mass transport properties of physical vapor transport of PbTe are investigated. Thermochemical analysis of the system and its implications for the growth conditions are discussed. The effect of the material preparation and pre-processing on the stoichiometry and residual gas pressure and composition, and on related mass flux is shown. A procedure leading to high mass transport rates is presented.

40 CFR Table 5 to Subpart Ppp of... - Process Vents From Batch Unit Operations-Monitoring, Recordkeeping, and Reporting Requirements

Code of Federal Regulations, 2011 CFR

2011-07-01

... Carbon Adsorber f Total regeneration stream mass or volumetric flow during carbon bed regeneration cycle(s), and 1. Record of total regeneration stream mass or volumetric flow for each carbon bed regeneration cycle.2. Record and report the total regeneration stream mass or volumetric flow during each...

40 CFR Table 5 to Subpart Ppp of... - Process Vents From Batch Unit Operations-Monitoring, Recordkeeping, and Reporting Requirements

Code of Federal Regulations, 2012 CFR

2012-07-01

... Carbon Adsorber f Total regeneration stream mass or volumetric flow during carbon bed regeneration cycle(s), and 1. Record of total regeneration stream mass or volumetric flow for each carbon bed regeneration cycle.2. Record and report the total regeneration stream mass or volumetric flow during each...

40 CFR Table 5 to Subpart Ppp of... - Process Vents From Batch Unit Operations-Monitoring, Recordkeeping, and Reporting Requirements

Code of Federal Regulations, 2010 CFR

2010-07-01

... Carbon Adsorber f Total regeneration stream mass or volumetric flow during carbon bed regeneration cycle(s), and 1. Record of total regeneration stream mass or volumetric flow for each carbon bed regeneration cycle.2. Record and report the total regeneration stream mass or volumetric flow during each...

Mass Balance. Operational Control Tests for Wastewater Treatment Facilities. Instructor's Manual [and] Student Workbook.

ERIC Educational Resources Information Center

Carnegie, John W.

This module describes the process used to determine solids mass and location throughout a waste water treatment plant, explains how these values are used to determine the solids mass balance around single treatment units and the entire system, and presents calculations of solids in pounds and sludge units. The instructor's manual contains a…

A Communication Model for Teaching a Course in Mass Media and Society.

ERIC Educational Resources Information Center

Crumley, Wilma; Stricklin, Michael

Many professors of mass media and society courses have relied on a teaching model implying that students are sponges soaking up information. A more appropriate model invites concern with an active audience, transaction, the interpersonal mass media mix, a general systems approach, and process and change--in other words, utilization of current and…

Cuban Mass Media: Organization, Control and Functions. Journalism Monographs Number Seventy-Eight.

ERIC Educational Resources Information Center

Nichols, John Spicer

The mass media as interdependent parts of a larger social system both control and are controlled by other subsystems. The various combinations of control, in turn, determine the functions the media system will serve. In the 1960's, the Cuban mass media underwent frequent change that reflected the volatility of the revolutionary process. Today,…

Evaluation of an experimental mass-flow sensor of cotton-lint at the gin

USDA-ARS?s Scientific Manuscript database

As part of a system to optimize the cotton ginning process, a custom built mass-flow sensor was evaluated at USDA-ARS Cotton Ginning Research Unit at Stoneville, Mississippi. The mass-flow sensor was fabricated based on the principle of the senor patented by Thomasson and Sui (2004). The optical a...

Impacts of land use conversion on bankfull discharge and mass wasting

Treesearch

Mark S. Riedel; Elon S. Verry; Kenneth N. Brooks

2005-01-01

Mass wasting and channel incision are widespread in the Nemadji River watershed of eastern Minnesota and northwestern Wisconsin. While much of this is a natural response to glacial rebound, sediment coring and tree ring data suggest that land use has also influenced these erosional processes. We characterized land use, inventoried mass wasting, surveyed stream channels...

Deciphering the Mode of Action of the Processive Polysaccharide Modifying Enzyme Dermatan Sulfate Epimerase 1 by Hydrogen-Deuterium Exchange Mass Spectrometry.

PubMed

Tykesson, Emil; Mao, Yang; Maccarana, Marco; Pu, Yi; Gao, Jinshan; Lin, Cheng; Zaia, Joseph; Westergren-Thorsson, Gunilla; Ellervik, Ulf; Malmström, Lars; Malmström, Anders

2016-02-01

Distinct from template-directed biosynthesis of nucleic acids and proteins, the enzymatic synthesis of heterogeneous polysaccharides is a complex process that is difficult to study using common analytical tools. Therefore, the mode of action and processivity of those enzymes are largely unknown. Dermatan sulfate epimerase 1 (DS-epi1) is the predominant enzyme during the formation of iduronic acid residues in the glycosaminoglycan dermatan sulfate. Using recombinant DS-epi1 as a model enzyme, we describe a tandem mass spectrometry-based method to study the mode of action of polysaccharide processing enzymes. The enzyme action on the substrate was monitored by hydrogen-deuterium exchange mass spectrometry and the sequence information was then fed into mathematical models with two different assumptions of the mode of action for the enzyme: processive reducing end to non-reducing end, and processive non-reducing end to reducing end. Model data was scored by correlation to experimental data and it was found that DS-epi1 attacks its substrate on a random position, followed by a processive mode of modification towards the non-reducing end and that the substrate affinity of the enzyme is negatively affected by each additional epimerization event. It could also be shown that the smallest active substrate was the reducing end uronic acid in a tetrasaccharide and that octasaccharides and longer oligosaccharides were optimal substrates. The method of using tandem mass spectrometry to generate sequence information of the complex enzymatic products in combination with in silico modeling can be potentially applied to study the mode of action of other enzymes involved in polysaccharide biosynthesis.

A mass census of the nearby universe with the RESOLVE survey

NASA Astrophysics Data System (ADS)

Eckert, Kathleen

The galaxy mass function, i.e., the distribution of galaxies as a function of mass, is a useful way to characterize the galaxy population. In this work, we examine the stellar and baryonic mass function, and the velocity function of galaxies and galaxy groups for two volume-limited surveys of the nearby universe. Stellar masses are estimated from multi-band photometry, and we add cold atomic gas from measurements and a newly calibrated estimator to obtain baryonic mass. Velocities are measured from the internal motions of galaxies and groups and account for all matter within the system. We compare our observed mass and velocity functions with the halo mass function from theoretical simulations of dark matter, which predict a much more steeply rising low-mass slope than is normally observed for the galaxy mass function. We show that taking into account the cold gas mass, which dominates the directly detectable mass of low-mass galaxies, steepens the low-mass slope of the galaxy mass function. The low- mass slope of the baryonic mass function, however, is still much shallower than that of the halo mass function. The discrepancy in low-mass slope persists when examining the velocity function, which accounts for all matter in galaxies (detectable or not), suggesting that some mechanism must reduce the mass in halos or destroy them completely. We investigate the role of environment by performing group finding and examining the mass and velocity functions as a function of group halo mass. Broken down by halo mass regime, we find dips and varying low-mass slopes in the mass and velocity functions, suggesting that group formation processes such as merging and stripping, which destroy and lower the mass of low-mass satellites respectively, potentially contribute to the discrepancy in low-mass slope. In particular, we focus on the nascent group regime, groups of mass 10 11.4-12 [solar mass] with few members, which has a depressed and flat low-mass slope in the galaxy mass and velocity function. We find that nascent groups are at the peak baryonic collapse efficiency (group-integrated cold baryonic mass divided by the group halo mass), while isolated dwarfs in lower mass halos are rapidly growing in their collapsed baryonic mass and larger groups are increasingly dominated by their hot halo gas. Scatter in this collapsed baryon efficiency could indicate varying hot gas fractions in nascent groups, suggestive of a wide variety of group formation processes occurring at these scales. We point to this nascent group regime as a period of transition in group evolution, where merging and stripping remove galaxies from the population, contributing to the discrepancy in low-mass slope between observations and dark matter simulations.

Efficiency of ETV diagrams as diagnostic tools for long-term period variations. II. Non-conservative mass transfer, and gravitational radiation

NASA Astrophysics Data System (ADS)

Nanouris, N.; Kalimeris, A.; Antonopoulou, E.; Rovithis-Livaniou, H.

2015-03-01

Context. The credibility of an eclipse timing variation (ETV) diagram analysis is investigated for various manifestations of the mass transfer and gravitational radiation processes in binary systems. The monotonicity of the period variations and the morphology of the respective ETV diagrams are thoroughly explored in both the direct impact and the accretion disk mode of mass transfer, accompanied by different types of mass and angular momentum losses (through a hot-spot emission from the gainer and via the L2/L3 points). Aims: Our primary objective concerns the traceability of each physical mechanism by means of an ETV diagram analysis. Also, possible critical mass ratio values are sought for those transfer modes that involve orbital angular momentum losses strong enough to dictate the secular period changes even when highly competitive mechanisms with the opposite direction act simultaneously. Methods: The dot{J-dot{P}} relation that governs the orbital evolution of a binary system is set to provide the exact solution for the period and the function expected to represent the subsequent eclipse timing variations. The angular momentum transport is parameterized through appropriate empirical relations, which are inferred from semi-analytical ballistic models. Then, we numerically determine the minimum temporal range over which a particular mechanism is rendered measurable, as well as the critical mass ratio values that signify monotonicity inversion in the period modulations. Results: Mass transfer rates comparable to or greater than 10-8 M⊙ yr-1 are measurable for typical noise levels of the ETV diagrams, regardless of whether the process is conservative. However, the presence of a transient disk around the more massive component defines a critical mass ratio (qcr ≈ 0.83) above which the period turns out to decrease when still in the conservative regime, rendering the measurability of the anticipated variations a much more complicated task. The effects of gravitational radiation proved to be rather undetectable, except for systems with physical characteristics that only refer to cataclysmic variables. Conclusions: The monotonicity of the period variations and the curvature of the respective ETV diagrams depend strongly on the accretion mode and the degree of conservatism of the transfer process. Unlike the hot-spot effects, the Lagrangian points L2 and L3 support very efficient routes of strong angular momentum loss. It is further shown that escape of mass via the L3 point - when the donor is the less massive component - safely provides critical mass ratios above which the period is expected to decrease, no matter how intense the process is.

Mass measurement of 80Y by β-γ coincidence spectroscopy

NASA Astrophysics Data System (ADS)

Barton, C. J.; Brenner, D. S.; Zamfir, N. V.; Caprio, M. A.; Aprahamian, A.; Wiescher, M. C.; Beausang, C. W.; Berant, Z.; Casten, R. F.; Cooper, J. R.; Gill, R. L.; Krücken, R.; Novak, J. R.; Pietralla, N.; Shawcross, M.; Teymurazyan, A.; Wolf, A.

2003-03-01

The QEC value of 80Y has been measured by β-γ coincidence spectroscopy to be ⩾8929(83) keV. Combining this result with the adopted mass excess of the daughter 80Sr gives a mass excess for 80Y of ⩾-61 376(83) keV. Results are compared with other measurements, with Audi-Wapstra systematics, and with predictions of mass formulas. Implications of this measurement are considered for the rp process.

From Stars to Super-Planets: The Low-Mass IMF in the Young Cluster IC348

NASA Technical Reports Server (NTRS)

Najita, Joan R.; Tiede, Glenn P.; Carr, John S.

2000-01-01

We investigate the low-mass population of the young cluster IC348 down to the deuterium-burning limit, a fiducial boundary between brown dwarf and planetary mass objects, using a new and innovative method for the spectral classification of late-type objects. Using photometric indices, constructed from HST/NICMOS narrow-band imaging, that measure the strength of the 1.9 micron water band, we determine the spectral type and reddening for every M-type star in the field, thereby separating cluster members from the interloper population. Due to the efficiency of our spectral classification technique, our study is complete from approximately 0.7 solar mass to 0.015 solar mass. The mass function derived for the cluster in this interval, dN/d log M alpha M(sup 0.5), is similar to that obtained for the Pleiades, but appears significantly more abundant in brown dwarfs than the mass function for companions to nearby sun-like stars. This provides compelling observational evidence for different formation and evolutionary histories for substellar objects formed in isolation vs. as companions. Because our determination of the IMF is complete to very low masses, we can place interesting constraints on the role of physical processes such as fragmentation in the star and planet formation process and the fraction of dark matter in the Galactic halo that resides in substellar objects.

Determination of the mass transfer limiting step of dye adsorption onto commercial adsorbent by using mathematical models.

PubMed

Marin, Pricila; Borba, Carlos Eduardo; Módenes, Aparecido Nivaldo; Espinoza-Quiñones, Fernando R; de Oliveira, Silvia Priscila Dias; Kroumov, Alexander Dimitrov

2014-01-01

Reactive blue 5G dye removal in a fixed-bed column packed with Dowex Optipore SD-2 adsorbent was modelled. Three mathematical models were tested in order to determine the limiting step of the mass transfer of the dye adsorption process onto the adsorbent. The mass transfer resistance was considered to be a criterion for the determination of the difference between models. The models contained information about the external, internal, or surface adsorption limiting step. In the model development procedure, two hypotheses were applied to describe the internal mass transfer resistance. First, the mass transfer coefficient constant was considered. Second, the mass transfer coefficient was considered as a function of the dye concentration in the adsorbent. The experimental breakthrough curves were obtained for different particle diameters of the adsorbent, flow rates, and feed dye concentrations in order to evaluate the predictive power of the models. The values of the mass transfer parameters of the mathematical models were estimated by using the downhill simplex optimization method. The results showed that the model that considered internal resistance with a variable mass transfer coefficient was more flexible than the other ones and this model described the dynamics of the adsorption process of the dye in the fixed-bed column better. Hence, this model can be used for optimization and column design purposes for the investigated systems and similar ones.

OT1_ipascucc_1: Understanding the Origin of Transition Disks via Disk Mass Measurements

NASA Astrophysics Data System (ADS)

Pascucci, I.

2010-07-01

Transition disks are a distinguished group of few Myr-old systems caught in the phase of dispersing their inner dust disk. Three different processes have been proposed to explain this inside-out clearing: grain growth, photoevaporation driven by the central star, and dynamical clearing by a forming giant planet. Which of these processes lead to a transition disk? Distinguishing between them requires the combined knowledge of stellar accretion rates and disk masses. We propose here to use 43.8 hours of PACS spectroscopy to detect the [OI] 63 micron emission line from a sample of 21 well-known transition disks with measured mass accretion rates. We will use this line, in combination with ancillary CO millimeter lines, to measure their gas disk mass. Because gas dominates the mass of protoplanetary disks our approach and choice of lines will enable us to trace the bulk of the disk mass that resides beyond tens of AU from young stars. Our program will quadruple the number of transition disks currently observed with Herschel in this setting and for which disk masses can be measured. We will then place the transition and the ~100 classical/non-transition disks of similar age (from the Herschel KP "Gas in Protoplanetary Systems") in the mass accretion rate-disk mass diagram with two main goals: 1) reveal which gaps have been created by grain growth, photoevaporation, or giant planet formation and 2) from the statistics, determine the main disk dispersal mechanism leading to a transition disk.

The effects of gray scale image processing on digital mammography interpretation performance.

PubMed

Cole, Elodia B; Pisano, Etta D; Zeng, Donglin; Muller, Keith; Aylward, Stephen R; Park, Sungwook; Kuzmiak, Cherie; Koomen, Marcia; Pavic, Dag; Walsh, Ruth; Baker, Jay; Gimenez, Edgardo I; Freimanis, Rita

2005-05-01

To determine the effects of three image-processing algorithms on diagnostic accuracy of digital mammography in comparison with conventional screen-film mammography. A total of 201 cases consisting of nonprocessed soft copy versions of the digital mammograms acquired from GE, Fischer, and Trex digital mammography systems (1997-1999) and conventional screen-film mammograms of the same patients were interpreted by nine radiologists. The raw digital data were processed with each of three different image-processing algorithms creating three presentations-manufacturer's default (applied and laser printed to film by each of the manufacturers), MUSICA, and PLAHE-were presented in soft copy display. There were three radiologists per presentation. Area under the receiver operating characteristic curve for GE digital mass cases was worse than screen-film for all digital presentations. The area under the receiver operating characteristic for Trex digital mass cases was better, but only with images processed with the manufacturer's default algorithm. Sensitivity for GE digital mass cases was worse than screen film for all digital presentations. Specificity for Fischer digital calcifications cases was worse than screen film for images processed in default and PLAHE algorithms. Specificity for Trex digital calcifications cases was worse than screen film for images processed with MUSICA. Specific image-processing algorithms may be necessary for optimal presentation for interpretation based on machine and lesion type.

Controls and variability of solute and sedimentary fluxes in Arctic and sub-Arctic Environments

NASA Astrophysics Data System (ADS)

Dixon, John

2015-04-01

Six major factors consistently emerge as controls on the spatial and temporal variability in sediment and solute fluxes in cold climates. They are climatic, geologic, physiographic or relief, biologic, hydrologic, and regolith factors. The impact of these factors on sediment and solute mass transfer in Arctic and sub-Arctic environments is examined. Comparison of non-glacierized Arctic vs. subarctic drainage basins reveals the effects of these controls. All drainage basins exhibit considerable variability in rates of sediment and solute fluxes. For the non-glacierized drainage basins there is a consistent increase in sediment mass transfer by slope processes and fluvial processes as relief increases. Similarly, a consistent increase in sediment mass transfer by slope and fluvial processes is observed as total precipitation increases. Similar patterns are also observed with respect to solute transport and relief and precipitation. Lithologic factors are most strongly observed in the contrast between volcanic vs. plutonic igneous bedrock substrates. Basins underlain by volcanic rocks display greater mass transfers than those underlain by plutonic rocks. Biologic influences are most strongly expressed by variations in extent of vegetation cover and the degree of human interference, with human impacted basins generating greater fluxes. For glacierized basins the fundamental difference to non-glacierized basins is an overall increase in mean annual mass transfers of sediment and a generally smaller magnitude solute transfer. The principal role of geology is observed with respect to lithology. Catchments underlain by limestone demonstrate substantially greater solute mass transfers than sediment transfer. The influence of relief is seen in the contrast in mass transfers between upland and lowland drainage basins with upland basins generating greater sediment and solute transfers than lowland basins. For glacierized basins the effects of biology and regolith appear to be largely overridden by the hydrologic impacts of glacierization.

Modelling river bank erosion processes and mass failure mechanisms using 2-D depth averaged numerical model

NASA Astrophysics Data System (ADS)

Die Moran, Andres; El kadi Abderrezzak, Kamal; Tassi, Pablo; Herouvet, Jean-Michel

2014-05-01

Bank erosion is a key process that may cause a large number of economic and environmental problems (e.g. land loss, damage to structures and aquatic habitat). Stream bank erosion (toe erosion and mass failure) represents an important form of channel morphology changes and a significant source of sediment. With the advances made in computational techniques, two-dimensional (2-D) numerical models have become valuable tools for investigating flow and sediment transport in open channels at large temporal and spatial scales. However, the implementation of mass failure process in 2D numerical models is still a challenging task. In this paper, a simple, innovative algorithm is implemented in the Telemac-Mascaret modeling platform to handle bank failure: failure occurs whether the actual slope of one given bed element is higher than the internal friction angle. The unstable bed elements are rotated around an appropriate axis, ensuring mass conservation. Mass failure of a bank due to slope instability is applied at the end of each sediment transport evolution iteration, once the bed evolution due to bed load (and/or suspended load) has been computed, but before the global sediment mass balance is verified. This bank failure algorithm is successfully tested using two laboratory experimental cases. Then, bank failure in a 1:40 scale physical model of the Rhine River composed of non-uniform material is simulated. The main features of the bank erosion and failure are correctly reproduced in the numerical simulations, namely the mass wasting at the bank toe, followed by failure at the bank head, and subsequent transport of the mobilised material in an aggradation front. Volumes of eroded material obtained are of the same order of magnitude as the volumes measured during the laboratory tests.

Mass Wasting

NASA Image and Video Library

2011-12-06

Mass Wasting is the term given to the process of change on a surface due to gravity things moving downhill due to the force of gravity. Dark streaks mark the slopes of craters and hills in this region of Amazonis Planitia.

AUTOMATIC MASS SPECTROMETER

DOEpatents

Hanson, M.L.; Tabor, C.D. Jr.

1961-12-01

A mass spectrometer for analyzing the components of a gas is designed which is capable of continuous automatic operation such as analysis of samples of process gas from a continuous production system where the gas content may be changing. (AEC)

"EMERGING" POLLUTANTS, AND COMMUNICATING THE ...

EPA Pesticide Factsheets

This paper weaves a rnulti-dimensioned perspective of mass spectrometry as a career against the backdrop of mass spectrometry's key role in the past and future of environmental chemistry. Along the way, some insights are offered for better focusing the spotlight on the discipline of mass spectrometry. A Foundation for Environmental Science-Mass Spectrometry Historically fundamental to our understanding of environmental processes and chemical pollution is mass spectrometry. This branch of analytical chemistry is the workhorse which supplies much of the definitive data to environmental scientists and engineers for identifying the molecular compositions, and ultimately the structures, of chemicals. This is not to ignore the complementary and critical roles played by the adjunct practices of sample enrichment (e.g., to lower method detection limits via any of various means of selective extraction) and analyte separation (e.g., to lessen contaminant interferences via the myriad forms of chromatography and electrophoresis). While the power of mass spectrometry has long been highly visible to the practicing environmental chemist, it borders on continued obscurity to the lay public and most non-chemists. Even though mass spectrometry has played a long, historic and Largely invisible role in establishing or undergirding our existing knowledge about environmental processes and pollution, what recognition it does enjoy is usually relegated to that of a tool. It is usually

Rapid recovery from the Late Ordovician mass extinction

NASA Technical Reports Server (NTRS)

Krug, A. Z.; Patzkowsky, M. E.

2004-01-01

Understanding the evolutionary role of mass extinctions requires detailed knowledge of postextinction recoveries. However, most models of recovery hinge on a direct reading of the fossil record, and several recent studies have suggested that the fossil record is especially incomplete for recovery intervals immediately after mass extinctions. Here, we analyze a database of genus occurrences for the paleocontinent of Laurentia to determine the effects of regional processes on recovery and the effects of variations in preservation and sampling intensity on perceived diversity trends and taxonomic rates during the Late Ordovician mass extinction and Early Silurian recovery. After accounting for variation in sampling intensity, we find that marine benthic diversity in Laurentia recovered to preextinction levels within 5 million years, which is nearly 15 million years sooner than suggested by global compilations. The rapid turnover in Laurentia suggests that processes such as immigration may have been particularly important in the recovery of regional ecosystems from environmental perturbations. However, additional regional studies and a global analysis of the Late Ordovician mass extinction that accounts for variations in sampling intensity are necessary to confirm this pattern. Because the record of Phanerozoic mass extinctions and postextinction recoveries may be compromised by variations in preservation and sampling intensity, all should be reevaluated with sampling-standardized analyses if the evolutionary role of mass extinctions is to be fully understood.

Electrical characterization of non‐Fickian transport in groundwater and hyporheic systems

USGS Publications Warehouse

Singha, Kamini; Pidlisecky, Adam; Day-Lewis, Frederick D.; Gooseff, Michael N.

2008-01-01

Recent work indicates that processes controlling solute mass transfer between mobile and less mobile domains in porous media may be quantified by combining electrical geophysical methods and electrically conductive tracers. Whereas direct geochemical measurements of solute preferentially sample the mobile domain, electrical geophysical methods are sensitive to changes in bulk electrical conductivity (bulk EC) and therefore sample EC in both the mobile and immobile domains. Consequently, the conductivity difference between direct geochemical samples and remotely sensed electrical geophysical measurements may provide an indication of mass transfer rates and mobile and immobile porosities in situ. Here we present (1) an overview of a theoretical framework for determining parameters controlling mass transfer with electrical resistivity in situ; (2) a review of a case study estimating mass transfer processes in a pilot‐scale aquifer storage recovery test; and (3) an example application of this method for estimating mass transfer in watershed settings between streams and the hyporheic corridor. We demonstrate that numerical simulations of electrical resistivity studies of the stream/hyporheic boundary can help constrain volumes and rates of mobile‐immobile mass transfer. We conclude with directions for future research applying electrical geophysics to understand field‐scale transport in aquifer and fluvial systems subject to rate‐limited mass transfer.

Influence of heteroatom pre-selection on the molecular formula assignment of soil organic matter components determined by ultrahigh resolution mass spectrometry.

PubMed

Ohno, Tsutomu; Ohno, Paul E

2013-04-01

Soil organic matter (SOM) is involved in many important ecosystem processes. Ultrahigh resolution mass spectrometry has become a powerful technique in the chemical characterization of SOM, allowing assignment of elemental formulae for thousands of peaks resolved in a typical mass spectrum. We investigated how the addition of N, S, and P heteroatoms in the formula calculation stage of the mass spectra processing workflow affected the formula assignments of mass spectra peaks. Dissolved organic matter extracted from plant biomass and soil as well as the soil humic acid fraction was studied. We show that the addition of S and P into the molecular formula calculation increased peak assignments on average by 17.3 % and 10.7 %, respectively, over the assignments based on the CHON elements frequently reported by SOM researchers using ultrahigh resolution mass spectrometry. The organic matter chemical characteristics as represented by van Krevelen diagrams were appreciably affected by differences in the heteroatom pre-selection for the three organic matter samples investigated, especially so for the wheat-derived dissolved organic matter. These results show that inclusion of both S and P heteroatoms into the formula calculation step, which is not routinely done, is important to obtain a more chemically complete interpretation of the ultrahigh resolution mass spectra of SOM.

Connecting massive galaxies to dark matter haloes in BOSS - I. Is galaxy colour a stochastic process in high-mass haloes?

NASA Astrophysics Data System (ADS)

Saito, Shun; Leauthaud, Alexie; Hearin, Andrew P.; Bundy, Kevin; Zentner, Andrew R.; Behroozi, Peter S.; Reid, Beth A.; Sinha, Manodeep; Coupon, Jean; Tinker, Jeremy L.; White, Martin; Schneider, Donald P.

2016-08-01

We use subhalo abundance matching (SHAM) to model the stellar mass function (SMF) and clustering of the Baryon Oscillation Spectroscopic Survey (BOSS) `CMASS' sample at z ˜ 0.5. We introduce a novel method which accounts for the stellar mass incompleteness of CMASS as a function of redshift, and produce CMASS mock catalogues which include selection effects, reproduce the overall SMF, the projected two-point correlation function wp, the CMASS dn/dz, and are made publicly available. We study the effects of assembly bias above collapse mass in the context of `age matching' and show that these effects are markedly different compared to the ones explored by Hearin et al. at lower stellar masses. We construct two models, one in which galaxy colour is stochastic (`AbM' model) as well as a model which contains assembly bias effects (`AgM' model). By confronting the redshift dependent clustering of CMASS with the predictions from our model, we argue that that galaxy colours are not a stochastic process in high-mass haloes. Our results suggest that the colours of galaxies in high-mass haloes are determined by other halo properties besides halo peak velocity and that assembly bias effects play an important role in determining the clustering properties of this sample.

Toward Surface Mass Balance Modeling over Antarctic Peninsula with Improved Snow/Ice Physics within WRF

NASA Astrophysics Data System (ADS)

Villamil-Otero, G.; Zhang, J.; Yao, Y.

2017-12-01

The Antarctic Peninsula (AP) has long been the focus of climate change studies due to its rapid environmental changes such as significantly increased glacier melt and retreat, and ice-shelf break-up. Progress has been continuously made in the use of regional modeling to simulate surface mass changes over ice sheets. Most efforts, however, focus on the ice sheets of Greenland with considerable fewer studies in Antarctica. In this study the Weather Research and Forecasting (WRF) model, which has been applied to the Antarctic region for weather modeling, is adopted to capture the past and future surface mass balance changes over AP. In order to enhance the capabilities of WRF model simulating surface mass balance over the ice surface, we implement various ice and snow processes within the WRF and develop a new WRF suite (WRF-Ice). The WRF-Ice includes a thermodynamic ice sheet model that improves the representation of internal melting and refreezing processes and the thermodynamic effects over ice sheet. WRF-Ice also couples a thermodynamic sea ice model to improve the simulation of surface temperature and fluxes over sea ice. Lastly, complex snow processes are also taken into consideration including the implementation of a snowdrift model that takes into account the redistribution of blowing snow as well as the thermodynamic impact of drifting snow sublimation on the lower atmospheric boundary layer. Intensive testing of these ice and snow processes are performed to assess the capability of WRF-Ice in simulating the surface mass balance changes over AP.

[Bladder pseudotumor in childhood].

PubMed

Fernández Arjona, M; Muñoz-Delgado Salmerón, J; Shihadei, S; Colomar, P J; García Estevez, J A

1997-01-01

Case report of a 10 year-old male with vesical mass suggestive of a rabdomiosarcoma based on the radiologic studies performed. The existence of an inflammatory process with no signs of malignancy was confirmed by transurethral resection. The serological studies were negative and the absence of malignant disease in further substantiated by immunohistochemistry. We want to emphasize that certain vesical masses. which appear to be malignant on the radiological study (Pseudotumours), may be just inflammatory processes.

The Use of Mass Spectrometry to Study the Structure of Flames and Combustion Processes

NASA Astrophysics Data System (ADS)

Korobeinichev, Oleg P.

1980-06-01

The general characteristic methods of the mass-spectrometric study of flames and combustion processes, and the latest achievements in experimental technique in the molecular-beam diagnostics of flames have been examined. The problems associated with the use of probe methods — the effects of freezing the chemical reactions, translational-vibrational relaxation, and perturbations introduced by the probe in the combustion process — have been analysed. The possibilities provided by the technique have been demonstrated for various examples in the study of the combustion of gaseous, liquid, and solid fuels, including that in various technical arrangements — internal combustion engines and liquid rocket motors. Questions related to the use of mass-spectrometric probes for the study of the mechanism and kinetics of chemical reactions in flames and for the determination of the rate constants of the elementary stages have been discussed. The bibliography contains 53 references.

Mechanical erosion of xenoliths by magmatic shear flow

NASA Astrophysics Data System (ADS)

Del Gaudio, Piero; Ventura, Guido

2008-05-01

We focus on the role of mechanical erosion by magmatic shear flow in the formation of xenoliths occurring in lava flows. The process is analyzed by combining the physics of fragmentation and erosion to the concept of rock mass. The conditions for the country rock fragmentation are analyzed as a function of the magma viscosity, strain rate and tensile strength of the rock mass. In reservoirs, mechanical processes play a subordinate role and thermal erosion processes prevail. In conduits, intermediate and silicic magmas may erode and, eventually, fragment good to poor quality country rock masses. Basalts may erode poor quality country rocks. A crystal-rich magma has more chance to break up the conduit walls with respect to a vesiculated melt. The variety of xenoliths of a lava reflects a set of wall-rocks with similar mechanical properties and may not mirror the stratigraphy of the substratum of a volcanic area.

Surfactant effects on alpha-factors in aeration systems.

PubMed

Rosso, Diego; Stenstrom, Michael K

2006-04-01

Aeration in wastewater treatment processes accounts for the largest fraction of plant energy costs. Aeration systems function by shearing the surface (surface aerators) or releasing bubbles at the bottom of the tank (coarse- or fine-bubble aerators). Surfactant accumulation on gas-liquid interfaces reduces mass transfer rates, and this reduction in general is larger for fine-bubble aerators. This study evaluates mass transfer effects on the characterization and specification of aeration systems in clean and process water conditions. Tests at different interfacial turbulence regimes show higher gas transfer depression for lower turbulence regimes. Contamination effects can be offset at the expense of operating efficiency, which is characteristic of surface aerators and coarse-bubble diffusers. Results describe the variability of alpha-factors measured at small scale, due to uncontrolled energy density. Results are also reported in dimensionless empirical correlations describing mass transfer as a function of physiochemical and geometrical characteristics of the aeration process.

Exploring bubble oscillation and mass transfer enhancement in acoustic-assisted liquid-liquid extraction with a microfluidic device

PubMed Central

Xie, Yuliang; Chindam, Chandraprakash; Nama, Nitesh; Yang, Shikuan; Lu, Mengqian; Zhao, Yanhui; Mai, John D.; Costanzo, Francesco; Huang, Tony Jun

2015-01-01

We investigated bubble oscillation and its induced enhancement of mass transfer in a liquid-liquid extraction process with an acoustically-driven, bubble-based microfluidic device. The oscillation of individually trapped bubbles, of known sizes, in microchannels was studied at both a fixed frequency, and over a range of frequencies. Resonant frequencies were analytically identified and were found to be in agreement with the experimental observations. The acoustic streaming induced by the bubble oscillation was identified as the cause of this enhanced extraction. Experiments extracting Rhodanmine B from an aqueous phase (DI water) to an organic phase (1-octanol) were performed to determine the relationship between extraction efficiency and applied acoustic power. The enhanced efficiency in mass transport via these acoustic-energy-assisted processes was confirmed by comparisons against a pure diffusion-based process. PMID:26223474

Identifying the production process of new physics at colliders; symmetric or asymmetric?

NASA Astrophysics Data System (ADS)

Lim, Sung Hak

2016-06-01

We propose a class of kinematic variables, which is a smooth generalization of min-max type mass variables such as the Cambridge- M T 2 and M 2, for measuring a mass spectrum of intermediate resonances in a semi-invisibly decaying pair production. While kinematic endpoints of min-max type mass variables are only sensitive to a heavier resonance mass, kinematic endpoints of new variables are sensitive to all masses. These new mass variables can be used to resolve a mass spectrum, so that if the true mass spectrum is asymmetric, then the kinematic endpoints are separate while the endpoints are the same for the symmetric true mass spectrum. We demonstrate the behavior of kinematic endpoint of these new variables in pair production of two-body and three-body decays with one invisible particle.

Sedimentary masses and concepts about tectonic processes at underthrust ocean margins ( subduction).

USGS Publications Warehouse

Scholl, D. W.; von Huene, Roland E.; Vallier, T.L.; Howell, D.G.

1980-01-01

Tectonic processes associated with subduction of oceanic crust, but unrelated to the collision of thick crustal masses or microplates, are presumed by many geologists to significantly affect the formation and deformation of large sedimentary bodies at underthrust ocean margins. More geologists are familiar with the concept of subduction accretion than with other noncollision processes - for example, sediment subduction, subduction erosion, and subduction kneading. In our opinion, no single subduction-related tectonic process is the dominant or typical one that forges the geologic framework of modern underthrust ocean margins. It is likely, therefore, that the rock records of ancient underthrust margins are preserved in a multitude of structural and stratigraphic forms.-from Authors

Exploring the Largest Mass Fraction of the Solar System: the Case for Planetary Interiors

NASA Technical Reports Server (NTRS)

Danielson, L. R.; Draper, D.; Righter, K.; McCubbin, F.; Boyce, J.

2017-01-01

Why explore planetary interiors: The typical image that comes to mind for planetary science is that of a planet surface. And while surface data drive our exploration of evolved geologic processes, it is the interiors of planets that hold the key to planetary origins via accretionary and early differentiation processes. It is that initial setting of the bulk planet composition that sets the stage for all geologic processes that follow. But nearly all of the mass of planets is inaccessible to direct examination, making experimentation an absolute necessity for full planetary exploration.

Mathematical simulation of the process of condensing natural gas

NASA Astrophysics Data System (ADS)

Tastandieva, G. M.

2015-01-01

Presents a two-dimensional unsteady model of heat transfer in terms of condensation of natural gas at low temperatures. Performed calculations of the process heat and mass transfer of liquefied natural gas (LNG) storage tanks of cylindrical shape. The influence of model parameters on the nature of heat transfer. Defined temperature regimes eliminate evaporation by cooling liquefied natural gas. The obtained dependence of the mass flow rate of vapor condensation gas temperature. Identified the possibility of regulating the process of "cooling down" liquefied natural gas in terms of its partial evaporation with low cost energy.

40 CFR Table 5 to Subpart Ppp of... - Process Vents From Batch Unit Operations-Monitoring, Recordkeeping, and Reporting Requirements

Code of Federal Regulations, 2013 CFR

2013-07-01

... collected—PR. d,e Carbon Adsorber f Total regeneration stream mass or volumetric flow during carbon bed regeneration cycle(s), and 1. Record of total regeneration stream mass or volumetric flow for each carbon bed regeneration cycle.2. Record and report the total regeneration stream mass or volumetric flow during each...

40 CFR Table 6 to Subpart Ppp of... - Process Vents From Continuous Unit Operations-Monitoring, Recordkeeping, and Reporting Requirements

Code of Federal Regulations, 2014 CFR

2014-07-01

... operating—PR. d e Carbon Adsorber f Total regeneration stream mass or volumetric flow during carbon bed regeneration cycle(s), and 1. Record of total regeneration stream mass or volumetric flow for each carbon bed regeneration cycle.2. Record and report the total regeneration stream mass or volumetric flow during each...

40 CFR Table 5 to Subpart Ppp of... - Process Vents From Batch Unit Operations-Monitoring, Recordkeeping, and Reporting Requirements

Code of Federal Regulations, 2014 CFR

2014-07-01

... collected—PR. d e Carbon Adsorber f Total regeneration stream mass or volumetric flow during carbon bed regeneration cycle(s), and 1. Record of total regeneration stream mass or volumetric flow for each carbon bed regeneration cycle.2. Record and report the total regeneration stream mass or volumetric flow during each...

40 CFR Table 6 to Subpart Ppp of... - Process Vents From Continuous Unit Operations-Monitoring, Recordkeeping, and Reporting Requirements

Code of Federal Regulations, 2013 CFR

2013-07-01

... operating—PR. d,e Carbon Adsorber f Total regeneration stream mass or volumetric flow during carbon bed regeneration cycle(s), and 1. Record of total regeneration stream mass or volumetric flow for each carbon bed regeneration cycle.2. Record and report the total regeneration stream mass or volumetric flow during each...

Initiatives and Challenges in Consequence Management after a WMD Attack

DTIC Science & Technology

2004-08-01

Challenges in Consequence Management people to seek shelter or other protection when possible, to avoid exposure to weapons of mass destruction effects . The...Potential Effects .........................................9 V. Methods for Managing the Consequences of WMD Use.................14 VI. Toward a...mass destruction (WMD). Consequence management1 is a process to mitigate the effects of the use of weapons of mass destruction, including

40 CFR Table 11 to Subpart Xxxx of... - Minimum Data for Continuous Compliance With the Emission Limits for Tire Cord Production Affected...

Code of Federal Regulations, 2011 CFR

2011-07-01

...) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emissions Standards... method, test results, indicating the mass percent of each HAP for coating used.b. The mass of each coating used each monthly operating period. c. The total mass of fabric processed each monthly operating...

Issues in the assessment of children's coping in the context of mass trauma.

PubMed

Pfefferbaum, Betty; Noffsinger, Mary A; Wind, Leslie H

2012-06-01

Exposure to mass trauma has contributed to increasing concern about the well-being of children, families, and communities. In spite of global awareness of the dramatic impact of mass trauma on youth, little is known about how children and adolescents cope with and adapt to disasters and terrorism. While coping has yet to be fully conceptualized as a unified construct, the process of responding to stress includes recognized cognitive, emotional, and behavioral components. Unfortunately, research on the complex process of adaptation in the aftermath of mass trauma is a relatively recent focus. Further study is needed to build consensus in terminology, theory, methods, and assessment techniques to assist researchers and clinicians in measuring children's coping, both generally and within the context of mass trauma. Advancements are needed in the area of coping assessment to identify internal and external factors affecting children's stress responses. Additionally, enhanced understanding of children's disaster coping can inform the development of prevention and intervention programs to promote resilience in the aftermath of traumatic events. This article examines the theoretical and practical issues in assessing coping in children exposed to mass trauma, and includes recommendations to guide assessment and research of children's coping within this specialized context.

Issues in the Assessment of Children's Coping in the Context of Mass Trauma

PubMed Central

Pfefferbaum, Betty; Noffsinger, Mary A.; Wind, Leslie H.

2012-01-01

Exposure to mass trauma has contributed to increasing concern about the well-being of children, families, and communities. In spite of global awareness of the dramatic impact of mass trauma on youth, little is known about how children and adolescents cope with and adapt to disasters and terrorism. While coping has yet to be fully conceptualized as a unified construct, the process of responding to stress includes recognized cognitive, emotional, and behavioral components. Unfortunately, research on the complex process of adaptation in the aftermath of mass trauma is a relatively recent focus. Further study is needed to build consensus in terminology, theory, methods, and assessment techniques to assist researchers and clinicians in measuring children's coping, both generally and within the context of mass trauma. Advancements are needed in the area of coping assessment to identify internal and external factors affecting children's stress responses. Additionally, enhanced understanding of children's disaster coping can inform the development of prevention and intervention programs to promote resilience in the aftermath of traumatic events. This article examines the theoretical and practical issues in assessing coping in children exposed to mass trauma, and includes recommendations to guide assessment and research of children's coping within this specialized context. PMID:22691268

Direct estimation of mass flow and diffusion of nitrogen compounds in solution and soil.

PubMed

Oyewole, Olusegun Ayodeji; Inselsbacher, Erich; Näsholm, Torgny

2014-02-01

Plant nutrient uptake from soil is mainly governed by diffusion and transpirationally induced mass flow, but the current methods for assessing the relative importance of these processes are indirect. We developed a microdialysis method using solutions of different osmotic potentials as perfusates to simulate diffusion and mass flow processes, and assessed how induced mass flow affected fluxes of nitrogen (N) compounds in solution and in boreal forest soil. Varying the osmotic potential of perfusates induced vertical fluxes in the direction of the dialysis membranes at rates of between 1 × 10(-8) and 3 × 10(-7)  m s(-1) , thus covering the estimated range of water velocities perpendicular to root surfaces and induced by transpiration. Mass flow increased N fluxes in solution but even more so in soil. This effect was explained by an indirect effect of mass flow on rates of diffusive fluxes, possibly caused by the formation of steeper gradients in concentrations of N compounds from membrane surfaces out in the soil. Our results suggest that transpiration may be an essential driver of plant N acquisition. © 2013 The Authors. New Phytologist © 2013 New Phytologist Trust.

In Situ Observation of Hard Surrounding Rock Displacement at 2400-m-Deep Tunnels

NASA Astrophysics Data System (ADS)

Feng, Xia-Ting; Yao, Zhi-Bin; Li, Shao-Jun; Wu, Shi-Yong; Yang, Cheng-Xiang; Guo, Hao-Sen; Zhong, Shan

2018-03-01

This paper presents the results of in situ investigation of the internal displacement of hard surrounding rock masses within deep tunnels at China's Jinping Underground Laboratory Phase II. The displacement evolution of the surrounding rock during the entire excavation processes was monitored continuously using pre-installed continuous-recording multi-point extensometers. The evolution of excavation-damaged zones and fractures in rock masses were also observed using acoustic velocity testing and digital borehole cameras, respectively. The results show four kinds of displacement behaviours of the hard surrounding rock masses during the excavation process. The displacement in the inner region of the surrounding rock was found to be greater than that of the rock masses near the tunnel's side walls in some excavation stages. This leads to a multi-modal distribution characteristic of internal displacement for hard surrounding rock masses within deep tunnels. A further analysis of the evolution information on the damages and fractures inside the surrounding rock masses reveals the effects of excavation disturbances and local geological conditions. This recognition can be used as the reference for excavation and supporting design and stability evaluations of hard-rock tunnels under high-stress conditions.

Examination of the Mass Transfer of Additive Elements in Barium Titanate Ceramics during Sintering Process by Laser Ablation ICP-MS.

PubMed

Sakate, Daisuke; Iwazaki, Yoshiki; Kon, Yoshiaki; Yokoyama, Takaomi; Ohata, Masaki

2018-01-01

The mass transfer of additive elements during the sintering of barium titanate (BaTiO 3 ) ceramic was examined by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) in the present study. An analytical sample consisting of two pellets of BaTiO 3 with different concentrations of additive elements of manganese (Mn) and holmium (Ho) as well as silicon (Si) as a sintering reagent was prepared and measured by LA-ICP-MS with small laser irradiated diameter of 10 μm to evaluate the distributions and concentrations of additive elements in order to examine their mass transfers. As results, enrichments of Mn and Si as an additive element and a sintering reagent, respectively, were observed on the adhesive surface between two BaTiO 3 pellets, even though Ho did not show a similar phenomenon. The mass transfers of additive elements of Mn and Ho were also examined, and Mn seemed to show a larger mass transfer than that of Ho during the sintering process for BaTiO 3 ceramics. The results obtained in this study shows the effectives of LA-ICP-MS for the future improvement of MLCCs.

Experimental results on Zc(3900)

NASA Astrophysics Data System (ADS)

Shen, C. P.

2015-10-01

This report reviewed the recently discovered Zc(3900) at around 3.9 GeV/c2 in the π±J/ψ mass spectrum by the Belle and BESIII collaborations simultaneously. Belle collaboration observed it in the process e+e- → π+π- J/ψ within the Y (4260) signal region with a 967 fb-1 data sample using initial-stateradiation technology. BESIII collaboration discovered it in the same process at a fixed center-of-mass energy of 4.260 GeV using a 525 pb-1 data sample. The measured resonance masses and widths from Belle and BESIII measurements are consistent with each other within the errors. The Zc(3900) can be interpreted as a new charged charmonium-like state.

Penning trap mass measurement of 56Cu

NASA Astrophysics Data System (ADS)

Valverde, A. A.; Brodeur, M.; Bollen, G.; Eibach, M.; Gulyuz, K.; Hamacker, A.; Izzo, C.; Ong, W.-J.; Puentes, D.; Redshaw, M.; Ringle, R.; Sandler, R.; Schwarz, S.; Sumithrarachchi, C. S.; Surbrook, J.; Villari, A. C. C.; Yandow, I. T.

2017-09-01

The doubly-magic nucleus 56Ni is one of the most important waiting point nuclei in the rp-process. While we now know that it is not the endpoint of the rp-process, which continues to the Sn-Sb-Te cycle, the flow around this nucleus is still not well understood. A pathway bypassing 56Ni through the 55Ni(p, γ)56Cu reaction exists, but the rate depends on the Q value of this reaction, which has not been experimentally determined. Mass measurements were undertaken using the LEBIT 9.4T Penning trap mass spectrometer at the National Superconducting Cyclotron Laboratory to rectify this situation. This work was supported in part by the National Science Foundation.

Influence of Process Parameters on the Process Efficiency in Laser Metal Deposition Welding

NASA Astrophysics Data System (ADS)

Güpner, Michael; Patschger, Andreas; Bliedtner, Jens

Conventionally manufactured tools are often completely constructed of a high-alloyed, expensive tool steel. An alternative way to manufacture tools is the combination of a cost-efficient, mild steel and a functional coating in the interaction zone of the tool. Thermal processing methods, like laser metal deposition, are always characterized by thermal distortion. The resistance against the thermal distortion decreases with the reduction of the material thickness. As a consequence, there is a necessity of a special process management for the laser based coating of thin parts or tools. The experimental approach in the present paper is to keep the energy and the mass per unit length constant by varying the laser power, the feed rate and the powder mass flow. The typical seam parameters are measured in order to characterize the cladding process, define process limits and evaluate the process efficiency. Ways to optimize dilution, angular distortion and clad height are presented.

Processing of thermionic power on an electrically propelled spacecraft

NASA Technical Reports Server (NTRS)

Macie, T. W.

1973-01-01

A study to define the power processing equipment required between a thermionic reactor and an array of mercury-ion thrusters for a nuclear electric propulsion system is reported. Observations and recommendations that resulted from this study were: (1) the preferred thermionic-fuel-element source voltages are 23 V or higher; (2) transistor characteristics exert a strong effect on power processor mass; (3) the power processor mass could be considerably reduced should the magnetic materials that exhibit low losses at high frequencies, that have a high Curie point, and that can operate at 15 to 20 kG become avaliable; (4) electrical component packaging on the radiator could reduce the area that is sensitive to meteoroid penetration, thereby reducing the meteoroid shielding mass requirement; (5) an experimental model of the power processor design should be built and tested to verify the efficiencies, masses, and all the automatic operational aspects of the design.

Influence of fluid dynamic conditions on enzymatic hydrolysis of lignocellulosic biomass: Effect of mass transfer rate.

PubMed

Wojtusik, Mateusz; Zurita, Mauricio; Villar, Juan C; Ladero, Miguel; Garcia-Ochoa, Felix

2016-09-01

The effect of fluid dynamic conditions on enzymatic hydrolysis of acid pretreated corn stover (PCS) has been assessed. Runs were performed in stirred tanks at several stirrer speed values, under typical conditions of temperature (50°C), pH (4.8) and solid charge (20% w/w). A complex mixture of cellulases, xylanases and mannanases was employed for PCS saccharification. At low stirring speeds (<150rpm), estimated mass transfer coefficients and rates, when compared to chemical hydrolysis rates, lead to results that clearly show low mass transfer rates, being this phenomenon the controlling step of the overall process rate. However, for stirrer speed from 300rpm upwards, the overall process rate is controlled by hydrolysis reactions. The ratio between mass transfer and overall chemical reaction rates changes with time depending on the conditions of each run. Copyright © 2016 Elsevier Ltd. All rights reserved.

An Automated Peak Identification/Calibration Procedure for High-Dimensional Protein Measures From Mass Spectrometers.

PubMed

Yasui, Yutaka; McLerran, Dale; Adam, Bao-Ling; Winget, Marcy; Thornquist, Mark; Feng, Ziding

2003-01-01

Discovery of "signature" protein profiles that distinguish disease states (eg, malignant, benign, and normal) is a key step towards translating recent advancements in proteomic technologies into clinical utilities. Protein data generated from mass spectrometers are, however, large in size and have complex features due to complexities in both biological specimens and interfering biochemical/physical processes of the measurement procedure. Making sense out of such high-dimensional complex data is challenging and necessitates the use of a systematic data analytic strategy. We propose here a data processing strategy for two major issues in the analysis of such mass-spectrometry-generated proteomic data: (1) separation of protein "signals" from background "noise" in protein intensity measurements and (2) calibration of protein mass/charge measurements across samples. We illustrate the two issues and the utility of the proposed strategy using data from a prostate cancer biomarker discovery project as an example.

Modeling the influence of coupled mass transfer processes on mass flux downgradient of heterogeneous DNAPL source zones

NASA Astrophysics Data System (ADS)

Yang, Lurong; Wang, Xinyu; Mendoza-Sanchez, Itza; Abriola, Linda M.

2018-04-01

Sequestered mass in low permeability zones has been increasingly recognized as an important source of organic chemical contamination that acts to sustain downgradient plume concentrations above regulated levels. However, few modeling studies have investigated the influence of this sequestered mass and associated (coupled) mass transfer processes on plume persistence in complex dense nonaqueous phase liquid (DNAPL) source zones. This paper employs a multiphase flow and transport simulator (a modified version of the modular transport simulator MT3DMS) to explore the two- and three-dimensional evolution of source zone mass distribution and near-source plume persistence for two ensembles of highly heterogeneous DNAPL source zone realizations. Simulations reveal the strong influence of subsurface heterogeneity on the complexity of DNAPL and sequestered (immobile/sorbed) mass distribution. Small zones of entrapped DNAPL are shown to serve as a persistent source of low concentration plumes, difficult to distinguish from other (sorbed and immobile dissolved) sequestered mass sources. Results suggest that the presence of DNAPL tends to control plume longevity in the near-source area; for the examined scenarios, a substantial fraction (43.3-99.2%) of plume life was sustained by DNAPL dissolution processes. The presence of sorptive media and the extent of sorption non-ideality are shown to greatly affect predictions of near-source plume persistence following DNAPL depletion, with plume persistence varying one to two orders of magnitude with the selected sorption model. Results demonstrate the importance of sorption-controlled back diffusion from low permeability zones and reveal the importance of selecting the appropriate sorption model for accurate prediction of plume longevity. Large discrepancies for both DNAPL depletion time and plume longevity were observed between 2-D and 3-D model simulations. Differences between 2- and 3-D predictions increased in the presence of sorption, especially for the case of non-ideal sorption, demonstrating the limitations of employing 2-D predictions for field-scale modeling.

Effect of body mass and clothing on decomposition of pig carcasses.

PubMed

Matuszewski, Szymon; Konwerski, Szymon; Frątczak, Katarzyna; Szafałowicz, Michał

2014-11-01

Carcass mass and carcass clothing are factors of potential high forensic importance. In casework, corpses differ in mass and kind or extent of clothing; hence, a question arises whether methods for post-mortem interval estimation should take these differences into account. Unfortunately, effects of carcass mass and clothing on specific processes in decomposition and related entomological phenomena are unclear. In this article, simultaneous effects of these factors are analysed. The experiment followed a complete factorial block design with four levels of carcass mass (small carcasses 5-15 kg, medium carcasses 15.1-30 kg, medium/large carcasses 35-50 kg, large carcasses 55-70 kg) and two levels of carcass clothing (clothed and unclothed). Pig carcasses (N = 24) were grouped into three blocks, which were separated in time. Generally, carcass mass revealed significant and frequently large effects in almost all analyses, whereas carcass clothing had only minor influence on some phenomena related to the advanced decay. Carcass mass differently affected particular gross processes in decomposition. Putrefaction was more efficient in larger carcasses, which manifested itself through earlier onset and longer duration of bloating. On the other hand, active decay was less efficient in these carcasses, with relatively low average rate, resulting in slower mass loss and later onset of advanced decay. The average rate of active decay showed a significant, logarithmic increase with an increase in carcass mass, but only in these carcasses on which active decay was driven solely by larval blowflies. If a blowfly-driven active decay was followed by active decay driven by larval Necrodes littoralis (Coleoptera: Silphidae), which was regularly found in medium/large and large carcasses, the average rate showed only a slight and insignificant increase with an increase in carcass mass. These results indicate that lower efficiency of active decay in larger carcasses is a consequence of a multi-guild and competition-related pattern of this process. Pattern of mass loss in large and medium/large carcasses was not sigmoidal, but rather exponential. The overall rate of decomposition was strongly, but not linearly, related to carcass mass. In a range of low mass decomposition rate increased with an increase in mass, then at about 30 kg, there was a distinct decrease in rate, and again at about 50 kg, the rate slightly increased. Until about 100 accumulated degree-days larger carcasses gained higher total body scores than smaller carcasses. Afterwards, the pattern was reversed; moreover, differences between classes of carcasses enlarged with the progress of decomposition. In conclusion, current results demonstrate that cadaver mass is a factor of key importance for decomposition, and as such, it should be taken into account by decomposition-related methods for post-mortem interval estimation.

Modeling aerosol suspension from soils and oceans as sources of micropollutants to air.

PubMed

Qureshi, Asif; MacLeod, Matthew; Hungerbühler, Konrad

2009-10-01

Soil and marine aerosol suspension are two physical mass transfer processes that are not usually included in models describing fate and transport of environmental pollutants. Here, we review the literature on soil and marine aerosol suspension and estimate aerosol suspension mass transfer velocities for inclusion in multimedia models, as a global average and on a 1 x 1 scale. The yearly, global average mass transfer velocity for soil aerosol suspension is estimated to be 6 x 10(-10)mh(-1), approximately an order of magnitude smaller than marine aerosol suspension, which is estimated to be 8 x 10(-9)mh(-1). Monthly averages of these velocities can be as high as 10(-7)mh(-1) and 10(-5)mh(-1) for soil and marine aerosol suspension, respectively, depending on location. We use a unit-world multimedia model to analyze the relevance of these two suspension processes as a mechanism that enhances long-range atmospheric transport of pollutants. This is done by monitoring a metric of long-range transport potential, phi-one thousand (phi1000), that denotes the fraction of modeled emissions to air, water or soil in a source region that reaches a distance of 1000 km in air. We find that when the yearly, globally averaged mass transfer velocity is used, marine aerosol suspension increases phi1000 only fractionally for both emissions to air and water. However, enrichment of substances in marine aerosols, or speciation between ionic and neutral forms in ocean water may increase the influence of this surface-to-air transfer process. Soil aerosol suspension can be the dominant process for soil-to-air transfer in an emission-to-soil scenario for certain substances that have a high affinity to soil. When a suspension mass transfer velocity near the maximum limit is used, soil suspension remains important if the emissions are made to soil, and marine aerosol suspension becomes important regardless of if emissions are made to air or water compartments. We recommend that multimedia models designed to assess the environmental fate and long-range transport behavior of substances with a range of chemical properties include both aerosol suspension processes, using the mass transfer velocities estimated here.

Influence of heat transfer rates on pressurization of liquid/slush hydrogen propellant tanks

NASA Technical Reports Server (NTRS)

Sasmal, G. P.; Hochstein, J. I.; Hardy, T. L.

1993-01-01

A multi-dimensional computational model of the pressurization process in liquid/slush hydrogen tank is developed and used to study the influence of heat flux rates at the ullage boundaries on the process. The new model computes these rates and performs an energy balance for the tank wall whereas previous multi-dimensional models required a priori specification of the boundary heat flux rates. Analyses of both liquid hydrogen and slush hydrogen pressurization were performed to expose differences between the two processes. Graphical displays are presented to establish the dependence of pressurization time, pressurant mass required, and other parameters of interest on ullage boundary heat flux rates and pressurant mass flow rate. Detailed velocity fields and temperature distributions are presented for selected cases to further illuminate the details of the pressurization process. It is demonstrated that ullage boundary heat flux rates do significantly effect the pressurization process and that minimizing heat loss from the ullage and maximizing pressurant flow rate minimizes the mass of pressurant gas required to pressurize the tank. It is further demonstrated that proper dimensionless scaling of pressure and time permit all the pressure histories examined during this study to be displayed as a single curve.

The R-Process Alliance: 2MASS J09544277+5246414, the Most Actinide-enhanced R-II Star Known

NASA Astrophysics Data System (ADS)

Holmbeck, Erika M.; Beers, Timothy C.; Roederer, Ian U.; Placco, Vinicius M.; Hansen, Terese T.; Sakari, Charli M.; Sneden, Christopher; Liu, Chao; Lee, Young Sun; Cowan, John J.; Frebel, Anna

2018-06-01

We report the discovery of a new actinide-boost star, 2MASS J09544277+5246414, originally identified as a very bright (V = 10.1), extremely metal-poor ([Fe/H] = ‑2.99) K giant in the LAMOST survey, and found to be highly r-process-enhanced (r-II; [Eu/Fe] = +1.28]), during the snapshot phase of the R-Process Alliance (RPA). Based on a high signal-to-noise ratio (S/N), high-resolution spectrum obtained with the Harlan J. Smith 2.7 m telescope, this star is the first confirmed actinide-boost star found by RPA efforts. With an enhancement of [Th/Eu] = +0.37, 2MASS J09544277+5246414 is also the most actinide-enhanced r-II star yet discovered, and only the sixth metal-poor star with a measured uranium abundance ([U/Fe] = +1.40). Using the Th/U chronometer, we estimate an age of 13.0 ± 4.7 Gyr for this star. The unambiguous actinide-boost signature of this extremely metal-poor star, combined with additional r-process-enhanced and actinide-boost stars identified by the RPA, will provide strong constraints on the nature and origin of the r-process at early times.

Modeling and validation of heat and mass transfer in individual coffee beans during the coffee roasting process using computational fluid dynamics (CFD).

PubMed

Alonso-Torres, Beatriz; Hernández-Pérez, José Alfredo; Sierra-Espinoza, Fernando; Schenker, Stefan; Yeretzian, Chahan

2013-01-01

Heat and mass transfer in individual coffee beans during roasting were simulated using computational fluid dynamics (CFD). Numerical equations for heat and mass transfer inside the coffee bean were solved using the finite volume technique in the commercial CFD code Fluent; the software was complemented with specific user-defined functions (UDFs). To experimentally validate the numerical model, a single coffee bean was placed in a cylindrical glass tube and roasted by a hot air flow, using the identical geometrical 3D configuration and hot air flow conditions as the ones used for numerical simulations. Temperature and humidity calculations obtained with the model were compared with experimental data. The model predicts the actual process quite accurately and represents a useful approach to monitor the coffee roasting process in real time. It provides valuable information on time-resolved process variables that are otherwise difficult to obtain experimentally, but critical to a better understanding of the coffee roasting process at the individual bean level. This includes variables such as time-resolved 3D profiles of bean temperature and moisture content, and temperature profiles of the roasting air in the vicinity of the coffee bean.

"Magic" Ionization Mass Spectrometry

NASA Astrophysics Data System (ADS)

Trimpin, Sarah

2016-01-01

The systematic study of the temperature and pressure dependence of matrix-assisted ionization (MAI) led us to the discovery of the seemingly impossible, initially explained by some reviewers as either sleight of hand or the misinterpretation by an overzealous young scientist of results reported many years before and having little utility. The "magic" that we were attempting to report was that with matrix assistance, molecules, at least as large as bovine serum albumin (66 kDa), are lifted into the gas phase as multiply charged ions simply by exposure of the matrix:analyte sample to the vacuum of a mass spectrometer. Applied heat, a laser, or voltages are not necessary to achieve charge states and ion abundances only previously observed with electrospray ionization (ESI). The fundamentals of how solid phase volatile or nonvolatile compounds are converted to gas-phase ions without added energy currently involves speculation providing a great opportunity to rethink mechanistic understanding of ionization processes used in mass spectrometry. Improved understanding of the mechanism(s) of these processes and their connection to ESI and matrix-assisted laser desorption/ionization may provide opportunities to further develop new ionization strategies for traditional and yet unforeseen applications of mass spectrometry. This Critical Insights article covers developments leading to the discovery of a seemingly magic ionization process that is simple to use, fast, sensitive, robust, and can be directly applied to surface characterization using portable or high performance mass spectrometers.

Bulgeless Galaxies Hosting 107 M⊙ AGN in Galaxy Zoo: The Growth of Black Holes via Secular Processes

NASA Astrophysics Data System (ADS)

Simmons, Brooke; Lintott, C. J.; Schawinski, K.; Moran, E. C.; Han, A.; Kaviraj, S.; Masters, K. L.; Urry, C. M.; Willett, K.; Bamford, S. P.; Nichol, R.

2013-01-01

The growth of supermassive black holes (SMBHs) appears to proceed via multiple pathways including mergers and secular processes, but these are difficult to disentangle for most galaxies given their complex evolutionary histories. In order to understand the effects of secular galaxy evolution on black hole growth, we require a sample of active galactic nuclei (AGN) in galaxies with a calm formation history free of significant mergers, a population that heretofore has been difficult to locate. Here we present a sample of 13 AGN in massive galaxies lacking the classical bulges believed inevitably to result from mergers; they also either lack or have extremely small pseudobulges, meaning they have had very calm accretion histories. This is the largest sample to date of massive, bulgeless AGN host galaxies selected without any direct restriction on the SMBH mass. The broad-line objects in the sample have black hole masses of 106-7 M⊙ Eddington arguments imply similar masses for the rest of the sample, meaning these black holes have grown substantially in the absence of mergers or other bulge-building processes such as violent disk instabilities. The black hole masses are systematically higher than expected from established bulge-black hole relations. However, these systems may be consistent with the correlation between black hole mass and total stellar mass. We discuss these results in the context of other studies and consider the implication that the details of stellar galaxy evolution and dynamics may not be fundamental to the co-evolution of galaxies and black holes.

MassImager: A software for interactive and in-depth analysis of mass spectrometry imaging data.

PubMed

He, Jiuming; Huang, Luojiao; Tian, Runtao; Li, Tiegang; Sun, Chenglong; Song, Xiaowei; Lv, Yiwei; Luo, Zhigang; Li, Xin; Abliz, Zeper

2018-07-26

Mass spectrometry imaging (MSI) has become a powerful tool to probe molecule events in biological tissue. However, it is a widely held viewpoint that one of the biggest challenges is an easy-to-use data processing software for discovering the underlying biological information from complicated and huge MSI dataset. Here, a user-friendly and full-featured MSI software including three subsystems, Solution, Visualization and Intelligence, named MassImager, is developed focusing on interactive visualization, in-situ biomarker discovery and artificial intelligent pathological diagnosis. Simplified data preprocessing and high-throughput MSI data exchange, serialization jointly guarantee the quick reconstruction of ion image and rapid analysis of dozens of gigabytes datasets. It also offers diverse self-defined operations for visual processing, including multiple ion visualization, multiple channel superposition, image normalization, visual resolution enhancement and image filter. Regions-of-interest analysis can be performed precisely through the interactive visualization between the ion images and mass spectra, also the overlaid optical image guide, to directly find out the region-specific biomarkers. Moreover, automatic pattern recognition can be achieved immediately upon the supervised or unsupervised multivariate statistical modeling. Clear discrimination between cancer tissue and adjacent tissue within a MSI dataset can be seen in the generated pattern image, which shows great potential in visually in-situ biomarker discovery and artificial intelligent pathological diagnosis of cancer. All the features are integrated together in MassImager to provide a deep MSI processing solution at the in-situ metabolomics level for biomarker discovery and future clinical pathological diagnosis. Copyright © 2018 The Authors. Published by Elsevier B.V. All rights reserved.

Forensic Investigation of mass disasters in Nigeria: A review

PubMed Central

Obafunwa, John Oladapo; Faduyile, Francis Adedayo; Soyemi, Sunday Sokunle; Eze, Uwom Okereke; Nwana, Edmund J. C.; Odesanmi, William Olufemi

2015-01-01

This paper is to establish the present state of things in the country in terms of legal framework and the availability of personnel with a view to presenting an overview of proper mass disaster investigations. This is a retrospective review of mass disasters in Nigeria that occurred within the last 20 years. The study therefore reviews the state of the forensic investigation of the mass disasters as well as the efforts made to identify the victims of the disaster. The process of proper forensic investigation from the stage of evaluation of the scene and recovery process to the final identification of victims are presented to serve as a protocol for the country. The assessment of the present state of preparedness in Nigeria is also examined with a view to improving the practice to international standards. Data were retrieved from official documents from the aviation industry as well as Nigeria news reports. The standard protocols for disaster victim identification were retrieved from the guide released by the INTERPOL. The state of preparedness of the country and recommendations for improvement are presented. The Federal government and the states of the federation should without further delay put in place the process of reviewing the law of Coroner's system and provide the enabling environment for the proper forensic investigation. The training curriculum of the first responders should incorporate mass disaster investigations in order to produce efficient officers and personnel. A functional disaster victim identification (DVI) team is strongly advocated to incorporate different professionals involved in mass disaster management. PMID:25657485

High temperature abatement of acid gases from waste incineration. Part II: Comparative life cycle assessment study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Biganzoli, Laura, E-mail: laura.biganzoli@mail.polimi.it; Racanella, Gaia; Marras, Roberto

Highlights: • Two scenarios of acid gases removal in WTE plants were compared in an LCA study. • A detailed inventory based on primary data has been reported for the production of the new dolomitic sorbent. • Results show that the comparison between the two scenarios does not show systematic differences. • The potential impacts are reduced only if there is an increase in the energy efficiency of the WTE plant. - Abstract: The performances of a new dolomitic sorbent, named Depurcal®MG, to be directly injected at high temperature in the combustion chamber of Waste-To-Energy (WTE) plants as a preliminarymore » stage of deacidification, were experimentally tested during full-scale commercial operation. Results of the experimentations were promising, and have been extensively described in Biganzoli et al. (2014). This paper reports the Life Cycle Assessment (LCA) study performed to compare the traditional operation of the plants, based on the sole sodium bicarbonate feeding at low temperature, with the new one, where the dolomitic sorbent is injected at high temperature. In the latter the sodium bicarbonate is still used, but at lower rate because of the decreased load of acid gases entering the flue gas treatment line. The major goal of the LCA was to make sure that a burden shifting was not taking place somewhere in the life cycle stages, as it might be the case when a new material is used in substitution of another one. According to the comparative approach, only the processes which differ between the two operational modes were included in the system boundaries. They are the production of the two reactants and the treatment of the corresponding solid residues arising from the neutralisation of acid gases. The additional CO{sub 2} emission at the stack of the WTE plant due to the activation of the sodium bicarbonate was also included in the calculation. Data used in the modelling of the foreground system are primary, derived from the experimental tests described in Biganzoli et al. (2014) and from the dolomitic sorbent production plant. The results of the LCA show minor changes in the potential impacts between the two operational modes of the plants. These differences are for 8 impact categories in favour of the new operational mode based on the addition of the dolomitic sorbent, and for 7 impact categories in favour of the traditional operation. A final evaluation was conducted on the potential role of the dolomitic sorbent in enhancing the electric energy production efficiency of the plant, thanks to the better cleaning of the heat exchange surface that can be achieved. If such improvement is accounted for, all the potential impacts are considerably decreased (e.g. the Climate change by 28%), and in the comparison with the traditional operation 17 impact categories out of 19 are reduced.« less

Biomarkers to Assess Possible Biological Effects on Reproductive Potential, Immune Function, and Energetic Fitness of Bottlenose Dolphins Exposed to Sounds Consistent with Naval Sonars

DTIC Science & Technology

2013-09-30

ion modes. The resulting chromatograms were then processed using XCMS (alignment and peak picking ). The data were processed with in-house...UHPLC liquid chromatography Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry ( MS ). A standard method was developed for rapid analysis...extraction protocols and then implemented LC- MS / MS analyses on our Thermo Fisher Scientific TSQ Vantage triple quadrupole mass spectrometer. This

Cosmic-Ray Energetics and Mass (CREAM) Processing - Bonding

NASA Image and Video Library

2017-06-20

In the Space Station Processing Facility at NASA's Kennedy Space Center in Florida, technicians and engineers inspect components for the Cosmic-Ray Energetics and Mass investigation, or CREAM, instrument. It is designed to measure the charges of cosmic rays to better understand what gives them such incredible energies, and how that effects the composition of the universe. The instrument will be launched to the space station on the SpaceX CRS-12 commercial resupply mission in August 2017.

Cosmic-Ray Energetics and Mass (CREAM) Processing - Bonding

NASA Image and Video Library

2017-06-20

In the Space Station Processing Facility at NASA's Kennedy Space Center in Florida, a technician remove a protective cover on the Cosmic-Ray Energetics and Mass investigation, or CREAM, instrument. It is designed to measure the charges of cosmic rays to better understand what gives them such incredible energies, and how that effects the composition of the universe. The instrument will be launched to the space station on the SpaceX CRS-12 commercial resupply mission in August 2017.

Submarine landslides in Arctic sedimentation: Canada Basin

USGS Publications Warehouse

Mosher, David C.; Shimeld, John; Hutchinson, Deborah R.; Lebedova-Ivanova, N; Chapman, C.

2016-01-01

Canada Basin of the Arctic Ocean is the least studied ocean basin in the World. Marine seismic field programs were conducted over the past 6 years using Canadian and American icebreakers. These expeditions acquired more than 14,000 line-km of multibeam bathymetric and multi-channel seismic reflection data over abyssal plain, continental rise and slope regions of Canada Basin; areas where little or no seismic reflection data existed previously. Canada Basin is a turbidite-filled basin with flat-lying reflections correlateable over 100s of km. For the upper half of the sedimentary succession, evidence of sedimentary processes other than turbidity current deposition is rare. The Canadian Archipelago and Beaufort Sea margins host stacked mass transport deposits from which many of these turbidites appear to derive. The stratigraphic succession of the MacKenzie River fan is dominated by mass transport deposits; one such complex is in excess of 132,000 km2 in area and underlies much of the southern abyssal plain. The modern seafloor is also scarred with escarpments and mass failure deposits; evidence that submarine landsliding is an ongoing process. In its latest phase of development, Canada Basin is geomorphologically confined with stable oceanographic structure, resulting in restricted depositional/reworking processes. The sedimentary record, therefore, underscores the significance of mass-transport processes in providing sediments to oceanic abyssal plains as few other basins are able to do.

Mass Communication Functions in a Media-Rich Developing Society

ERIC Educational Resources Information Center

Chaffee, Steven H.; Izcaray, Fausto

1975-01-01

Discusses media-centered communication research models and applies them to a field setting in Venezuela in an attempt to assess the extent to which social processes depend on mass communication. See CS 703 632 for subscription information. (MH)

Neutrino-heated winds from millisecond protomagnetars as sources of the weak r-process

NASA Astrophysics Data System (ADS)

Vlasov, Andrey D.; Metzger, Brian D.; Lippuner, Jonas; Roberts, Luke F.; Thompson, Todd A.

2017-06-01

We explore heavy element nucleosynthesis in neutrino-driven winds from rapidly rotating, strongly magnetized protoneutron stars ('millisecond protomagnetars') for which the magnetic dipole is aligned with the rotation axis, and the field is assumed to be a static force-free configuration. We process the protomagnetar wind trajectories calculated by Vlasov, Metzger & Thompson through the r-process nuclear reaction network SkyNet using contemporary models for the evolution of the wind electron fraction during the protoneutron star cooling phase. Although we do not find a successful second or third-peak r-process for any rotation period P, we show that protomagnetars with P ˜ 1-5 ms produce heavy element abundance distributions that extend to higher nuclear mass number than from otherwise equivalent spherical winds (with the mass fractions of some elements enhanced by factors of ≳100-1000). The heaviest elements are synthesized by outflows emerging along flux tubes that graze the closed zone and pass near the equatorial plane outside the light cylinder. Due to dependence of the nucleosynthesis pattern on the magnetic field strength and rotation rate of the protoneutron star, natural variations in these quantities between core collapse events could contribute to the observed diversity of the abundances of weak r-process nuclei in metal-poor stars. Further diversity, including possibly even a successful third-peak r-process, could be achieved for misaligned rotators with non-zero magnetic inclination with respect to the rotation axis. If protomagnetars are central engines for GRBs, their relativistic jets should contain a high-mass fraction of heavy nuclei of characteristic mass number \\bar{A}≈ 100, providing a possible source for ultrahigh energy cosmic rays comprised of heavy nuclei with an energy spectrum that extends beyond the nominal Grezin-Zatsepin-Kuzmin cut-off for protons or iron nuclei.

Mass-dependent Mo isotope variations in oceanic basalts - a new tracer for mantle recycling processes

NASA Astrophysics Data System (ADS)

Willbold, M.; Freymuth, H.; Hibbert, K.; Lai, Y. J.; Elliott, T.

2016-12-01

How and to what extent crustal material is recycled into the deeper mantle as a result of plate tectonic processes is a long-standing but still not fully understood question in Earth Sciences. Indirect evidence from chemical as well as radiogenic isotope data in oceanic basalts suggest that such a process may indeed have operated over much of Earth's history. Yet, uncertainties in characterising the age of the presumed recycled crustal components as well as the wide range in their chemical composition do not allow us to verify the mantle recycling hypothesis. Technological advances now enable us to explore new isotopic tracers that could shed light on this question. One of these new tools are mass-dependent isotope variation of molybdenum (Mo). Mass-dependent Mo isotope data in clastic and chemical sediments are a well-established geochemical tool to study redox conditions in the Earth's water masses over the geological past [1, 2, 3]. Being an intrinsic property of rocks exposed to the hydrosphere (see Anbar [4] for an overview), mass-dependent Mo isotope variation in mantle-derived rocks from oceanic settings could therefore be used a tracer of recycled crustal material in the Earth's mantle. In this contribution we provide a current overview over how different geological and magmatic processes - such as seawater alteration of oceanic crust, slab dehydration during plate subduction as well as magmatic emplacement - could affect the Mo isotopic composition of crustal components being transferred into the deeper mantle, as well as that of mantle melts that may contain such a recycled component. With this in mind, we explore the use of mass-dependent Mo isotope variations in mantle-derived rocks as a tracer of recycled crust in the mantle. [1] Archer & Vance (2008) Nature Geoscience 1, 597-600. [2] Barling et al. (2001) EPSL 193, 447-457. [3] Siebert et al. (2003) EPSL 211, 159-171. [4] Anbar (2004) Rev. Min. Geochem. 55, 429-454.

A canary in the coal mine: documenting citizenship and identity in the State of Massachusetts.

PubMed

Kwong, Richard M; Miller, Edward Alan

2010-06-01

The U.S. federal government requires original documentation of citizenship and identity for applicants to qualify for coverage under Medicaid. The purpose of this investigation is to identify what challenges one state Medicaid agency has faced when implementing this requirement; and to identify what strategies this agency and other interested parties (e.g., providers, community advocates) adopted to help overcome them. The setting for this study is MassHealth, the Medicaid agency for the State of Massachusetts. Data derive from archival documents, direct observation, and in-depth interviews with key stakeholders, including state officials, provider agencies, community health centers, and beneficiary advocates. While MassHealth has met several of the implementation benchmarks put forth in federal regulations and guidance letters, the agency has fallen short in several respects. This includes assisting applicants seeking to enroll in MassHealth and maintaining a seamless documentation submission process. The result has been an increase in application processing time and misinterpretations in the MassHealth community; for example, that legal immigrants should not apply for coverage even though the new requirement does not affect them. Assuming a prominent role in informing and assisting MassHealth applicants has been providers and community-based organizations. Consumer advocacy groups have also worked to streamline the process for demonstrating citizenship and identity. Synergies have been formed between MassHealth and these other organizations as well. Findings suggest a number of lessons for state Medicaid agencies wishing to address the challenges posed by federal requirements to demonstrate citizenship and identity. These include working to ensure the readability, comprehension and non-English translation of materials provided to program applicants. It also includes strengthening the document handling process and forming partnerships with providers, beneficiary advocates, and other community organizations. Copyright (c) 2009 Elsevier Ireland Ltd. All rights reserved.

Combining targeted and nontargeted data analysis for liquid chromatography/high-resolution mass spectrometric analyses.

PubMed

Croley, Timothy R; White, Kevin D; Wong, Jon; Callahan, John H; Musser, Steven M; Antler, Margaret; Lashin, Vitaly; McGibbon, Graham A

2013-03-01

Increasing importation of food and the diversity of potential contaminants have necessitated more analytical testing of these foods. Historically, mass spectrometric methods for testing foods were confined to monitoring selected ions (SIM or MRM), achieving sensitivity by focusing on targeted ion signals. A limiting factor in this approach is that any contaminants not included on the target list are not typically identified and retrospective data mining is limited. A potential solution is to utilize high-resolution MS to acquire accurate mass full-scan data. Based on the instrumental resolution, these data can be correlated to the actual mass of a contaminant, which would allow for identification of both target compounds and compounds that are not on a target list (nontargets). The focus of this research was to develop software algorithms to provide rapid and accurate data processing of LC/MS data to identify both targeted and nontargeted analytes. Software from a commercial vendor was developed to process LC/MS data and the results were compared to an alternate, vendor-supplied solution. The commercial software performed well and demonstrated the potential for a fully automated processing solution. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Tandem mass spectrometry of nitric oxide and hydrogen sulfide releasing aspirins: a hint into activity behavior.

PubMed

Crestoni, Maria Elisa; Chiavarino, Barbara; Guglielmo, Stefano; Lilla, Valentina; Fornarini, Simonetta

2013-01-01

Aspirin (acetylsalicylic acid, ASA) is the most popular non-steroidal anti-inflammatory drug. However, due to its action on cyclooxygenase and its acid nature, aspirin is associated with adverse gastrointestinal effects. In an effort to minimize these side effects, NO-donor and H2S-donor ASA co-drugs have been designed and tested. Their mass spectrometric behavior is now analyzed and reported. Positive ions were obtained by electrospray ionization involving protonation or alkali metal attachment. Their dissociation processes have been studied by collision induced dissociation in a triple quadrupole instrument. High mass accuracy measurements have been recorded on a Fourier transform ion cyclotron resonance mass spectrometer. The protonated molecules dissociate by an exclusive or largely prevailing path leading to acetyloxy-substituted benzoyl cation, namely an ASA unit. The process is reminiscent of the enzymatic hydrolysis, releasing intact ASA to a large extent. Only at higher collision energy does the formal ketene loss disrupt the ASA moiety. The gas phase chemistry of protonated ASA-releasing drugs develops along elementary dissociation steps analogous to the reactive processes in complex biological environments. This notion may provide a tool for preliminary testing of new compounds.

From Nuclei to Dust Grains: How the AGB Machinery Works

NASA Astrophysics Data System (ADS)

Gobrecht, D.; Cristallo, S.; Piersanti, L.

2015-12-01

With their circumstellar envelopes AGB stars are marvelous laboratories to test our knowledge of microphysics (opacities, equation of state), macrophysics (convection, rotation, stellar pulsations, magnetic fields) and nucleosynthesis (nuclear burnings, slow neutron capture processes, molecules and dust formation). Due to the completely different environments those processes occur, the interplay between stellar interiors (dominated by mixing events like convection and dredge-up episodes) and stellar winds (characterized by dust formation and wind acceleration) is often ignored. We intend to develop a new approach involving a transition region, taking into consideration hydrodynamic processes which may drive AGB mass-loss. Our aim is to describe the process triggering the mass-loss in AGB stars with different masses, metallicities and chemical enrichments, possibly deriving a velocity field of the outflowing matter. Moreover, we intend to construct an homogeneous theoretical database containing detailed abundances of atomic and molecular species produced by these objects. As a long term goal, we will derive dust production rates for silicates, alumina and silicon carbides, in order to explain laboratory measurements of isotopic ratios in AGB dust grains.

REVIEW ARTICLE: Current trends and future requirements for the mass spectrometric investigation of microbial, mammalian and plant metabolomes

NASA Astrophysics Data System (ADS)

Dunn, Warwick B.

2008-03-01

The functional levels of biological cells or organisms can be separated into the genome, transcriptome, proteome and metabolome. Of these the metabolome offers specific advantages to the investigation of the phenotype of biological systems. The investigation of the metabolome (metabolomics) has only recently appeared as a mainstream scientific discipline and is currently developing rapidly for the study of microbial, plant and mammalian metabolomes. The metabolome pipeline or workflow encompasses the processes of sample collection and preparation, collection of analytical data, raw data pre-processing, data analysis and data storage. Of these processes the collection of analytical data will be discussed in this review with specific interest shown in the application of mass spectrometry in the metabolomics pipeline. The current developments in mass spectrometry platforms (GC-MS, LC-MS, DIMS and imaging MS) and applications of specific interest will be highlighted. The current limitations of these platforms and applications will be discussed with areas requiring further development also highlighted. These include the detectable coverage of the metabolome, the identification of metabolites and the process of converting raw data to biological knowledge.

Surfactant effects on alpha factors in full-scale wastewater aeration systems.

PubMed

Rosso, D; Larson, L E; Stenstrom, M K

2006-01-01

Aeration is an essential process in the majority of wastewater treatment processes, and accounts for the largest fraction of plant energy costs. Aeration systems can achieve wastewater oxygenation by shearing the surface (surface aerators) or releasing bubbles at the bottom of the tank (coarse- or fine-bubble aerators). Surfactants accumulate on gas-liquid interfaces and reduce mass transfer rates. This reduction in general is larger for fine-bubble aerators. This study was conducted to evaluate mass transfer effects on the characterization and specification of aeration systems in clean and process water conditions. Tests at different interfacial turbulence regimes were analysed, showing higher gas transfer depression for lower turbulence regimes. Higher turbulence regimes can offset contamination effects, at the expense of operating efficiency. This phenomenon is characteristic of surface aerators and coarse bubble diffusers and is here discussed. The results explain the variability of alpha factors measured at small scale, due to uncontrolled energy density. Results are also reported in dimensionless empirical correlations that describe mass transfer as a function of physiochemical and geometrical characteristics of the aeration process.

Secondary organic aerosol formation through cloud processing of aromatic VOCs

NASA Astrophysics Data System (ADS)

Herckes, P.; Hutchings, J. W.; Ervens, B.

2010-12-01

Field observations have shown substantial concentrations (20-5,500 ng L-1) of aromatic volatile organic compounds (VOC) in cloud droplets. The potential generation of secondary organic aerosol mass through the processing of these anthropogenic VOCs was investigated through laboratory and modeling studies. Under simulated atmospheric laboratory conditions, in idealized solutions, benzene, toluene, ethylbenzene, and xylene (BTEX) degraded quickly in the aqueous phase. The degradation process yielded less volatile products which would contribute to new aerosol mass upon cloud evaporation. However, when realistic cloud solutions containing natural organic matter were used in the experiments, the reaction rates decreased with increasing organic carbon content. Kinetic data derived from these experiments were used as input to a multiphase box model in order to evaluate the secondary organic aerosol (SOA) mass formation potential of cloud processing of BTEX. Model results will be presented that quantify the SOA amounts from these aqueous phase pathways. The efficiency of this multiphase SOA source will be compared to SOA yields from the same aromatics as treated in traditional SOA models that are restricted to gas phase oxidation and subsequent condensation on particles.

Evaluation of the mass transfer process on thin layer drying of papaya seeds from the perspective of diffusive models

NASA Astrophysics Data System (ADS)

Dotto, Guilherme Luiz; Meili, Lucas; Tanabe, Eduardo Hiromitsu; Chielle, Daniel Padoin; Moreira, Marcos Flávio Pinto

2018-02-01

The mass transfer process that occurs in the thin layer drying of papaya seeds was studied under different conditions. The external mass transfer resistance and the dependence of effective diffusivity ( D EFF ) in relation to the moisture ratio ( \\overline{MR} ) and temperature ( T) were investigated from the perspective of diffusive models. It was verified that the effective diffusivity was affected by the moisture content and temperature. A new correlation was proposed for drying of papaya seeds in order to describe these influences. Regarding the use of diffusive models, the results showed that, at conditions of low drying rates ( T ≤ 70 °C), the external mass transfer resistance, as well as the dependence of the effective diffusivity with respect to the temperature and moisture content should be considered. At high drying rates ( T > 90 °C), the dependence of the effective diffusivity with respect to the temperature and moisture content can be neglected, but the external mass transfer resistance was still considerable in the range of air velocities used in this work.

Conference on Continental margin mass wasting and Pleistocene sea-level changes, August 13-15, 1980

USGS Publications Warehouse

Folger, David W.; Hathaway, J.C.

1987-01-01

A conference on Continental Margin Mass Wasting and Pleistocene Sea-Level Changes was held in Woods Hole, Mass., August 13-15, 1980. Forty-seven participants, representing many government, academic, and industrial organizations, discussed the current state of knowledge of the features of marine mass wasting and of the interrelations of factors influencing them. These factors include sediment source, composition, textures, sedimentation rates, climatic and sea-level changes, gas and gas hydrate (clathrate) contents of sediments, geotechnical characteristics, oceanographic and morphological factors, ground-water processes, and seismic events. The part played by these factors in the processes and features of mass movement and the engineering considerations imposed by the emplacement of manmade structures on the sea floor were considered vital to the evaluation of hazards involved in offshore exploration and development. The conference concluded with a call for bold programs to establish the probability of occurrence and the quantitative importance of these factors and to devise more reliable means of measurement, particularly in place, of the characteristics of the sediment and features involved.

Mass discharge assessment at a brominated DNAPL site: Effects of known DNAPL source mass removal

NASA Astrophysics Data System (ADS)

Johnston, C. D.; Davis, G. B.; Bastow, T. P.; Woodbury, R. J.; Rao, P. S. C.; Annable, M. D.; Rhodes, S.

2014-08-01

Management and closure of contaminated sites is increasingly being proposed on the basis of mass flux of dissolved contaminants in groundwater. Better understanding of the links between source mass removal and contaminant mass fluxes in groundwater would allow greater acceptance of this metric in dealing with contaminated sites. Our objectives here were to show how measurements of the distribution of contaminant mass flux and the overall mass discharge emanating from the source under undisturbed groundwater conditions could be related to the processes and extent of source mass depletion. In addition, these estimates of mass discharge were sought in the application of agreed remediation targets set in terms of pumped groundwater quality from offsite wells. Results are reported from field studies conducted over a 5-year period at a brominated DNAPL (tetrabromoethane, TBA; and tribromoethene, TriBE) site located in suburban Perth, Western Australia. Groundwater fluxes (qw; L3/L2/T) and mass fluxes (Jc; M/L2/T) of dissolved brominated compounds were simultaneously estimated by deploying Passive Flux Meters (PFMs) in wells in a heterogeneous layered aquifer. PFMs were deployed in control plane (CP) wells immediately down-gradient of the source zone, before (2006) and after (2011) 69-85% of the source mass was removed, mainly by groundwater pumping from the source zone. The high-resolution (26-cm depth interval) measures of qw and Jc along the source CP allowed investigation of the DNAPL source-zone architecture and impacts of source mass removal. Comparable estimates of total mass discharge (MD; M/T) across the source zone CP reduced from 104 g day- 1 to 24-31 g day- 1 (70-77% reductions). Importantly, this mass discharge reduction was consistent with the estimated proportion of source mass remaining at the site (15-31%). That is, a linear relationship between mass discharge and source mass is suggested. The spatial detail of groundwater and mass flux distributions also provided further evidence of the source zone architecture and DNAPL mass depletion processes. This was especially apparent in different mass-depletion rates from distinct parts of the CP. High mass fluxes and groundwater fluxes located near the base of the aquifer dominated in terms of the dissolved mass flux in the profile, although not in terms of concentrations. Reductions observed in Jc and MD were used to better target future remedial efforts. Integration of the observations from the PFM deployments and the source mass depletion provided a basis for establishing flux-based management criteria for the site.

Mass discharge assessment at a brominated DNAPL site: Effects of known DNAPL source mass removal.

PubMed

Johnston, C D; Davis, G B; Bastow, T P; Woodbury, R J; Rao, P S C; Annable, M D; Rhodes, S

2014-08-01

Management and closure of contaminated sites is increasingly being proposed on the basis of mass flux of dissolved contaminants in groundwater. Better understanding of the links between source mass removal and contaminant mass fluxes in groundwater would allow greater acceptance of this metric in dealing with contaminated sites. Our objectives here were to show how measurements of the distribution of contaminant mass flux and the overall mass discharge emanating from the source under undisturbed groundwater conditions could be related to the processes and extent of source mass depletion. In addition, these estimates of mass discharge were sought in the application of agreed remediation targets set in terms of pumped groundwater quality from offsite wells. Results are reported from field studies conducted over a 5-year period at a brominated DNAPL (tetrabromoethane, TBA; and tribromoethene, TriBE) site located in suburban Perth, Western Australia. Groundwater fluxes (qw; L(3)/L(2)/T) and mass fluxes (Jc; M/L(2)/T) of dissolved brominated compounds were simultaneously estimated by deploying Passive Flux Meters (PFMs) in wells in a heterogeneous layered aquifer. PFMs were deployed in control plane (CP) wells immediately down-gradient of the source zone, before (2006) and after (2011) 69-85% of the source mass was removed, mainly by groundwater pumping from the source zone. The high-resolution (26-cm depth interval) measures of qw and Jc along the source CP allowed investigation of the DNAPL source-zone architecture and impacts of source mass removal. Comparable estimates of total mass discharge (MD; M/T) across the source zone CP reduced from 104gday(-1) to 24-31gday(-1) (70-77% reductions). Importantly, this mass discharge reduction was consistent with the estimated proportion of source mass remaining at the site (15-31%). That is, a linear relationship between mass discharge and source mass is suggested. The spatial detail of groundwater and mass flux distributions also provided further evidence of the source zone architecture and DNAPL mass depletion processes. This was especially apparent in different mass-depletion rates from distinct parts of the CP. High mass fluxes and groundwater fluxes located near the base of the aquifer dominated in terms of the dissolved mass flux in the profile, although not in terms of concentrations. Reductions observed in Jc and MD were used to better target future remedial efforts. Integration of the observations from the PFM deployments and the source mass depletion provided a basis for establishing flux-based management criteria for the site. Copyright © 2013 Elsevier B.V. All rights reserved.

Rapid sample classification using an open port sampling interface coupled with liquid introduction atmospheric pressure ionization mass spectrometry

DOE PAGES

Van Berkel, Gary J.; Kertesz, Vilmos

2016-11-15

An “Open Access”-like mass spectrometric platform to fully utilize the simplicity of the manual open port sampling interface for rapid characterization of unprocessed samples by liquid introduction atmospheric pressure ionization mass spectrometry has been lacking. The in-house developed integrated software with a simple, small and relatively low-cost mass spectrometry system introduced here fills this void. Software was developed to operate the mass spectrometer, to collect and process mass spectrometric data files, to build a database and to classify samples using such a database. These tasks were accomplished via the vendorprovided software libraries. Sample classification based on spectral comparison utilized themore » spectral contrast angle method. As a result, using the developed software platform near real-time sample classification is exemplified using a series of commercially available blue ink rollerball pens and vegetable oils. In the case of the inks, full scan positive and negative ion ESI mass spectra were both used for database generation and sample classification. For the vegetable oils, full scan positive ion mode APCI mass spectra were recorded. The overall accuracy of the employed spectral contrast angle statistical model was 95.3% and 98% in case of the inks and oils, respectively, using leave-one-out cross-validation. In conclusion, this work illustrates that an open port sampling interface/mass spectrometer combination, with appropriate instrument control and data processing software, is a viable direct liquid extraction sampling and analysis system suitable for the non-expert user and near real-time sample classification via database matching.« less

Rapid sample classification using an open port sampling interface coupled with liquid introduction atmospheric pressure ionization mass spectrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Van Berkel, Gary J.; Kertesz, Vilmos

An “Open Access”-like mass spectrometric platform to fully utilize the simplicity of the manual open port sampling interface for rapid characterization of unprocessed samples by liquid introduction atmospheric pressure ionization mass spectrometry has been lacking. The in-house developed integrated software with a simple, small and relatively low-cost mass spectrometry system introduced here fills this void. Software was developed to operate the mass spectrometer, to collect and process mass spectrometric data files, to build a database and to classify samples using such a database. These tasks were accomplished via the vendorprovided software libraries. Sample classification based on spectral comparison utilized themore » spectral contrast angle method. As a result, using the developed software platform near real-time sample classification is exemplified using a series of commercially available blue ink rollerball pens and vegetable oils. In the case of the inks, full scan positive and negative ion ESI mass spectra were both used for database generation and sample classification. For the vegetable oils, full scan positive ion mode APCI mass spectra were recorded. The overall accuracy of the employed spectral contrast angle statistical model was 95.3% and 98% in case of the inks and oils, respectively, using leave-one-out cross-validation. In conclusion, this work illustrates that an open port sampling interface/mass spectrometer combination, with appropriate instrument control and data processing software, is a viable direct liquid extraction sampling and analysis system suitable for the non-expert user and near real-time sample classification via database matching.« less

Falling Behind: International Scrutiny of the Peaceful Atom

DTIC Science & Technology

2008-02-01

confused with critical masses .5 Significant quantity values currently in use by the IAEA are given in Table 1. In a previous Natural Resources... actinides and fission products would not add significantly to the plutonium mass , the state could divert the spiked plutonium to a small clandestine...and manufacturing processes and should not be 152 confused with critical masses . Significant quantities are used in establishing the quantity

40 CFR 63.7941 - How do I conduct a performance test, design evaluation, or other type of initial compliance...

Code of Federal Regulations, 2010 CFR

2010-07-01

... vent; Ei, Eo = Mass rate of total organic compounds (TOC) (minus methane and ethane) or total HAP, from... reduction for all affected process vents, percent Ei = Mass rate of TOC (minus methane and ethane) or total... uncontrolled vents, as calculated in this section, kilograms TOC per hour or kilograms HAP per hour; Eo = Mass...

A System Dynamics Approach for Information Technology Implementation and Sustainment

DTIC Science & Technology

2003-03-01

mass media in nature, or (2) originating from either local or cosmopolite sources (Rogers, 1995). Mass media channels are a means of transmitting...interpersonal channels are more important at the persuasion stage in the innovation-decision process (Rogers, 1995). Cosmopolite communication channels...are those from outside the social system of study” (Rogers, 1995:196). Interpersonal channels can be either local or cosmopolite , whereas mass media

Multiplying the Origins of Mass Schooling: An Analysis of the Preconditions Common to Schooling and the School Building Process in Sweden, 1840-1900

ERIC Educational Resources Information Center

Westberg, Johannes

2015-01-01

The emergence of mass schooling is undoubtedly one of the most significant transformations that took place during the eighteenth and nineteenth centuries. This article takes a new approach to this fundamental issue by analysing the historical conditions required for the construction of school buildings and the advent of mass schooling, in the…

Discovery and characterization of antibody variants using mass spectrometry-based comparative analysis for biosimilar candidates of monoclonal antibody drugs.

PubMed

Li, Wenhua; Yang, Bin; Zhou, Dongmei; Xu, Jun; Ke, Zhi; Suen, Wen-Chen

2016-07-01

Liquid chromatography mass spectrometry (LC-MS) is the most commonly used technique for the characterization of antibody variants. MAb-X and mAb-Y are two approved IgG1 subtype monoclonal antibody drugs recombinantly produced in Chinese hamster ovary (CHO) cells. We report here that two unexpected and rare antibody variants have been discovered during cell culture process development of biosimilars for these two approved drugs through intact mass analysis. We then used comprehensive mass spectrometry-based comparative analysis including reduced light, heavy chains, and domain-specific mass as well as peptide mapping analysis to fully characterize the observed antibody variants. The "middle-up" mass comparative analysis demonstrated that the antibody variant from mAb-X biosimilar candidate was caused by mass variation of antibody crystalline fragment (Fc), whereas a different variant with mass variation in antibody antigen-binding fragment (Fab) from mAb-Y biosimilar candidate was identified. Endoproteinase Lys-C digested peptide mapping and tandem mass spectrometry analysis further revealed that a leucine to glutamine change in N-terminal 402 site of heavy chain was responsible for the generation of mAb-X antibody variant. Lys-C and trypsin coupled non-reduced and reduced peptide mapping comparative analysis showed that the formation of the light-heavy interchain trisulfide bond resulted in the mAb-Y antibody variant. These two cases confirmed that mass spectrometry-based comparative analysis plays a critical role for the characterization of monoclonal antibody variants, and biosimilar developers should start with a comprehensive structural assessment and comparative analysis to decrease the risk of the process development for biosimilars. Copyright © 2016 Elsevier B.V. All rights reserved.

THE IMPACT OF MASS SEGREGATION AND STAR FORMATION ON THE RATES OF GRAVITATIONAL-WAVE SOURCES FROM EXTREME MASS RATIO INSPIRALS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aharon, Danor; Perets, Hagai B.

Compact stellar objects inspiraling into massive black holes (MBHs) in galactic nuclei are some of the most promising gravitational-wave (GWs) sources for next-generation GW detectors. The rates of such extreme mass ratio inspirals (EMRIs) depend on the dynamics and distribution of compact objects (COs) around the MBH. Here, we study the impact of mass-segregation processes on EMRI rates. In particular, we provide the expected mass function (MF) of EMRIs, given an initial MF of stellar black holes (SBHs), and relate it to the mass-dependent detection rate of EMRIs. We then consider the role of star formation (SF) on the distributionmore » of COs and its implication on EMRI rates. We find that the existence of a wide spectrum of SBH masses leads to the overall increase of EMRI rates and to high rates of the EMRIs from the most massive SBHs. However, it also leads to a relative quenching of EMRI rates from lower-mass SBHs, and together produces a steep dependence of the EMRI MF on the highest-mass SBHs. SF history plays a relatively small role in determining the EMRI rates of SBHs, since most of them migrate close to the MBH through mass segregation rather than forming in situ. However, the EMRI rate of neutron stars (NSs) can be significantly increased when they form in situ close to the MBH, as they can inspiral before relaxation processes significantly segregate them outward. A reverse but weaker effect of decreasing the EMRI rates from NSs and white dwarfs occurs when SF proceeds far from the MBH.« less

Non-Target Screening of Veterinary Drugs Using Tandem Mass Spectrometry on SmartMass

NASA Astrophysics Data System (ADS)

Xia, Bing; Liu, Xin; Gu, Yu-Cheng; Zhang, Zhao-Hui; Wang, Hai-Yan; Ding, Li-Sheng; Zhou, Yan

2013-05-01

Non-target screening of veterinary drugs using tandem mass spectrometric data was performed on the SmartMass platform. This newly developed software uses the characteristic fragmentation patterns (CFP) to identify chemicals, especially those containing particular substructures. A mixture of 17 sulfonamides was separated by ultra performance liquid chromatography (UPLC), and SmartMass was used to process the tandem mass spectrometry (MS/MS) data acquired on an Orbitrap mass spectrometer. The data were automatically extracted, and each sulfonamide was recognized and analyzed with a prebuilt analysis rule. By using this software, over 98 % of the false candidate structures were eliminated, and all the correct structures were found within the top 10 of the ranking lists. Furthermore, SmartMass could also be used to identify slightly modified contraband drugs and metabolites with simple prebuilt rules. [Figure not available: see fulltext.

The Morphology and Uniformity of Circumstellar OH/H2O Masers around OH/IR Stars

NASA Astrophysics Data System (ADS)

Felli, Derek Sean

Even though low mass stars ( 8 solar masses), the more massive stars drive the chemical evolution of galaxies from which the next generation of stars and planets can form. Understanding mass loss of asymptotic giant branch stars contributes to our understanding of the chemical evolution of the galaxy, stellar populations, and star formation history. Stars with mass 8 solar masses go supernova. In both cases, these stars enrich their environments with elements heavier than simple hydrogen and helium molecules. While some general info about how stars die and form planetary nebulae are known, specific details are missing due to a lack of high-resolution observations and analysis of the intermediate stages. For example, we know that mass loss in stars creates morphologically diverse planetary nebulae, but we do not know the uniformity of these processes, and therefore lack detailed models to better predict how spherically symmetric stars form asymmetric nebulae. We have selected a specific group of late-stage stars and observed them at different scales to reveal the uniformity of mass loss through different layers close to the star. This includes observing nearby masers that trace the molecular shell structure around these stars. This study revealed detailed structure that was analyzed for uniformity to place constraints on how the mass loss processes behave in models. These results will feed into our ability to create more detailed models to better predict the chemical evolution of the next generation of stars and planets.

Properties of r-process nuclei near N=82 shell closure

NASA Astrophysics Data System (ADS)

Farhan, A. R.; Sharma, M. M.

2004-10-01

We have studied properties of nuclei in r-process region near N=82 shell closure with the RMF calculations in a deformed basis using the force NL-SV1 that includes vector self-coupling of w meson. It is shown that nuclei above N=82 in several isotopic chains in the r-process region exhibit an onset of deformation beyond the drip line. Consequently, induced by the deformation these nuclei show an extra stability above the shell closure. This stability of nuclei is expected to contribute to the r-process nucleosynthesis of nuclei below the abundance peak at A ˜130. A comparison with the mass formulae shows that our microscopic calculations with NL-SV1 show a decrease of shell strength with increase in isospin. This is in contrast to the strong shell effects shown by FRDM and ETF-SI in going to the drip line. The stiffness of the shell structure with FRDM and ETF-SI is known to lead to a shortfall in the r-process abundances. This shortcoming of the above mass formulae has inspired an ad-hoc inclusion of shell quenching in the mass formula ETF-SI(Q) with a view to better reproduce the r-process abundances. In comparison, our model shows a decrease of the shell strength in going from the r-process path to the drip line. Therefore, this represents a natural behaviour as required by r-process abundances. It may, however, be confirmed in network chain calculations using inputs from our microscopic model.

Effect of rice husk ash mass on sustainability pyrolysis zone of fixed bed downdraft gasifier with capacity of 10 kg/hour

NASA Astrophysics Data System (ADS)

Surjosatyo, Adi; Haq, Imaduddin; Dafiqurrohman, Hafif; Gibran, Felly Rihlat

2017-03-01

The formation of pyrolysis sustainability (Sustainable Pyrolysis) is the objective of the gasification process. Pyrolysis zone in the gasification process is the result of the endothermic reaction that get heat from oxidation (combustion) of the fuel with oxygen, where cracking biomass rice husk result of such as charcoal, water vapor, steam tar, and gas - gas (CO, H 2, CH 4, CO 2 and N 2) and must be maintained at a pyrolysis temperature to obtain results plentiful gas (producer gas) or syngas (synthetic gas). Obtaining continuously syngas is indicated by flow rate (discharge) producer gas well and the consistency of the flame on the gas burner, it is highly influenced by the gasification process and the operation of the gasifier and the mass balance (mass balance) between the feeding rate of rice husk with the disposal of ash (ash removal). In experiments conducted is using fixed bed gasifier type downdraft capacity of 10 kg/h. Besides setting the mass of rice husks into the gasifier and disposal arrangements rice husk ash may affect the sustainability of the pyrolysis process, but tar produced during the gasification process causes sticky rice husk ash in the plenum gasifier. Modifications disposal system rice husk ash can facilitate the arrangement of ash disposal then could control the temperature pyrolysis with pyrolysis at temperatures between 500-750 ° C. The experimental study was conducted to determine the effect of mass quantities of rice husk ash issued against sustainability pyrolysis temperature which is obtained at each time disposal of rice husk ash to produce 60-90 grams of ash issued. From some experimental phenomena is expected to be seen pyrolysis and its effect on the flow rate of syngas and the stability of the flame on the gas burner so that this research can find a correlation to obtain performance (performance) gasifier optimal.

Spatio-temporal changes in river bank mass failures in the Lockyer Valley, Queensland, Australia

NASA Astrophysics Data System (ADS)

Thompson, Chris; Croke, Jacky; Grove, James; Khanal, Giri

2013-06-01

Wet-flow river bank failure processes are poorly understood relative to the more commonly studied processes of fluvial entrainment and gravity-induced mass failures. Using high resolution topographic data (LiDAR) and near coincident aerial photography, this study documents the downstream distribution of river bank mass failures which occurred as a result of a catastrophic flood in the Lockyer Valley in January 2011. In addition, this distribution is compared with wet flow mass failure features from previous large floods. The downstream analysis of these two temporal data sets indicated that they occur across a range of river lengths, catchment areas, bank heights and angles and do not appear to be scale-dependent or spatially restricted to certain downstream zones. The downstream trends of each bank failure distribution show limited spatial overlap with only 17% of wet flows common to both distributions. The modification of these features during the catastrophic flood of January 2011 also indicated that such features tend to form at some 'optimum' shape and show limited evidence of subsequent enlargement even when flow and energy conditions within the banks and channel were high. Elevation changes indicate that such features show evidence for infilling during subsequent floods. The preservation of these features in the landscape for a period of at least 150 years suggests that the seepage processes dominant in their initial formation appear to have limited role in their continuing enlargement over time. No evidence of gully extension or headwall retreat is evident. It is estimated that at least 12 inundation events would be required to fill these failures based on the average net elevation change recorded for the 2011 event. Existing conceptual models of downstream bank erosion process zones may need to consider a wider array of mass failure processes to accommodate for wet flow failures.

Proteolytic processing and activation of Clostridium perfringens epsilon toxin by caprine small intestinal contents.

PubMed

Freedman, John C; Li, Jihong; Uzal, Francisco A; McClane, Bruce A

2014-10-21

Epsilon toxin (ETX), a pore-forming toxin produced by type B and D strains of Clostridium perfringens, mediates severe enterotoxemia in livestock and possibly plays a role in human disease. During enterotoxemia, the nearly inactive ETX prototoxin is produced in the intestines but then must be activated by proteolytic processing. The current study sought to examine ETX prototoxin processing and activation ex vivo using the intestinal contents of a goat, a natural host species for ETX-mediated disease. First, this study showed that the prototoxin has a KEIS N-terminal sequence with a molecular mass of 33,054 Da. When the activation of ETX prototoxin ex vivo by goat small intestinal contents was assessed by SDS-PAGE, the prototoxin was processed in a stepwise fashion into an ~27-kDa band or higher-molecular-mass material that could be toxin oligomers. Purified ETX corresponding to the ~27-kDa band was cytotoxic. When it was biochemically characterized by mass spectrometry, the copresence of three ETX species, each with different C-terminal residues, was identified in the purified ~27-kDa ETX preparation. Cytotoxicity of each of the three ETX species was then demonstrated using recombinant DNA approaches. Serine protease inhibitors blocked the initial proteotoxin processing, while carboxypeptidase inhibitors blocked further processing events. Taken together, this study provides important new insights indicating that, in the intestinal lumen, serine protease (including trypsin and possibly chymotrypsin) initiates the processing of the prototoxin but other proteases, including carboxypeptidases, then process the prototoxin into multiple active and stable species. Importance: Processing and activation by intestinal proteases is a prerequisite for ETX-induced toxicity. Previous studies had characterized the activation of ETX using only arbitrarily chosen amounts of purified trypsin and/or chymotrypsin. Therefore, the current study examined ETX activation ex vivo by natural host intestinal contents. These analyses demonstrated that (i) ETX processing in host intestinal contents occurs in an ordered, stepwise fashion, (ii) processing of prototoxin by host intestinal contents results in higher-molecular-mass material and 3 distinct ~27-kDa ETX species, and (iii) serine proteases, such as trypsin, chymotrypsin, and other proteases, including carboxypeptidases, play a role in the activation of ETX by intestinal contents. These studies provide new insights into the activation and processing of ETX and demonstrate that this process is more complicated than previously appreciated. Copyright © 2014 Freedman et al.

Modeling of acetone biofiltration process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hsiu-Mu Tang; Shyh-Jye Hwang; Wen-Chuan Wang

1996-12-31

The objective of this research was to investigate the kinetic behavior of the biofiltration process for the removal of acetone 41 which was used as a model compound for highly water soluble gas pollutants. A mathematical model was developed by taking into account diffusion and biodegradation of acetone and oxygen in the biofilm, mass transfer resistance in the gas film, and flow pattern of the bulk gas phase. The simulated results obtained by the proposed model indicated that mass transfer resistance in the gas phase was negligible for this biofiltration process. Analysis of the relative importance of various rate stepsmore » indicated that the overall acetone removal process was primarily limited by the oxygen diffusion rate. 11 refs., 6 figs., 1 tab.« less

Luminosity segregation in galaxy clusters as an indication of dynamical evolution

NASA Technical Reports Server (NTRS)

Baier, F. W.; Schmidt, K.-H.

1993-01-01

Theoretical models describing the dynamical evolution of self-gravitating systems predict a spatial mass segregation for more evolved systems, with the more massive objects concentrated toward the center of the configuration. From the observational point of view, however, the existence of mass segregation in galaxy clusters seems to be a matter of controversy. A special problem in this connection is the formation of cD galaxies in the centers of galaxy clusters. The most promising scenarios of their formation are galaxy cannibalism (merger scenario) and growing by cooling flows. It seems to be plausible to consider the swallowing of smaller systems by a dominant galaxy as an important process in the evolution of a cD galaxy. The stage of the evolution of the dominant galaxy should be reflected by the surrounding galaxy population, especially by possible mass segregation effects. Assuming that mass segregation is tantamount to luminosity segregation we analyzed luminosity segregation in roughly 40 cD galaxy clusters. Obviously there are three different groups of clusters: (1) clusters with luminosity segregation, (2) clusters without luminosity segregation, and (3) such objects exhibiting a phenomenon which we call antisegregation in luminosity, i.e. a deficiency of bright galaxies in the central regions of clusters. This result is interpreted in the sense of different degrees of mass segregation and as an indication for different evolution stages of these clusters. The clusters are arranged in the three segregation classes 2, 1, and 0 (S2 = strong mass segregation, S1 = moderate mass segregation, S0 = weak or absent mass segregation). We assume that a galaxy cluster starts its dynamical evolution after virialization without any radial mass segregation. Energy exchange during encounters of cluster members as well as merger processes between cluster galaxies lead to an increasing radial mass segregation in the cluster (S1). If a certain degree of segregation (S2) has been established, an essential number of slow-moving and relative massive cluster members in the center will be cannibalized by the initial brightest cluster galaxy. This process should lead to the growing of the predominate galaxy, which is accompanied by a diminution of the mass segregation (transition to S1 and S0, respectively) in the neighborhood of the central very massive galaxy. An increase of the areal density of brighter galaxies towards the outer cluster regions (antisegregation of luminosity), i.e. an extreme low degree of mass segregation was estimated for a substantial percentage of cD clusters. This result favors the cannibalism scenario for the formation of cD galaxies.

Electrostatic application of antimicrobial sprays to sanitize food handling and processing surfaces for enhanced food safety

NASA Astrophysics Data System (ADS)

Lyons, Shawn M.; Harrison, Mark A.; Law, S. Edward

2011-06-01

Human illnesses and deaths caused by foodborne pathogens (e.g., Salmonella enterica, Listeria monocytogenes, Escherichia coli O157:H7, etc.) are of increasing concern globally in maintaining safe food supplies. At various stages of the food production, processing and supply chain antimicrobial agents are required to sanitize contact surfaces. Additionally, during outbreaks of contagious pathogenic microorganisms (e.g., H1N1 influenza), public health requires timely decontamination of extensive surfaces within public schools, mass transit systems, etc. Prior publications verify effectiveness of air-assisted, induction-charged (AAIC) electrostatic spraying of various chemical and biological agents to protect on-farm production of food crops...typically doubling droplet deposition efficiency with concomitant increases in biological control efficacy. Within a biosafety facility this present work evaluated the AAIC electrostatic-spraying process for application of antimicrobial liquids onto various pathogen-inoculated food processing and handling surfaces as a food safety intervention strategy. Fluoroanalysis of AAIC electrostatic sprays (-7.2 mC/kg charge-to-mass ratio) showed significantly greater (p<0.05) mass of tracer active ingredient (A.I.) deposited onto target surfaces at various orientations as compared both to a similar uncharged spray nozzle (0 mC/kg) and to a conventional hydraulic-atomizing nozzle. Per unit mass of A.I. dispensed toward targets, for example, A.I. mass deposited by AAIC electrostatic sprays onto difficult to coat backsides was 6.1-times greater than for similar uncharged sprays and 29.0-times greater than for conventional hydraulic-nozzle sprays. Even at the 56% reduction in peracetic acid sanitizer A.I. dispensed by AAIC electrostatic spray applications, they achieved equal or greater CFU population reductions of Salmonella on most target orientations and materials as compared to uncharged sprays and conventional full-rate hydraulic-nozzle sprays.

Exoplanet recycling in massive white-dwarf debris discs

NASA Astrophysics Data System (ADS)

Van Lieshout, Rik

2017-06-01

When a star evolves into a white dwarf, the planetary system it hosts can become unstable. Planets in such systems may then be scattered onto star-grazing orbits, leading to their tidal disruption as they pass within the white dwarf’s Roche limit. We study the massive, compact debris discs that may arrise from this process using a combination of analytical estimates and numerical modelling. The discs are gravitationally unstable, resulting in an enhanced effective viscosity due to angular momentum transport associated with self-gravity wakes. For disc masses greater than ~1026 g (corresponding to progenitor objects comparable to the Galilean moons), viscous spreading dominates over Poynting-Robertson drag in the outer parts of the disc. In such massive discs, mass is transported both in- and outwards. When the outward-flowing material spreads beyond the Roche limit, it coagulates into new (minor) planets in a process analogous to the ongoing formation of Saturn’s innermost moonlets. This process recycles a substantial fraction of the original disc mass (tens of percents), with the bulk of the mass locked in a single large body orbitting in a 2:1 mean-motion resonance with the Roche limit. As such, the recycling of a tidally disrupted super-Earth could yield an Earth-mass planet on a 10--20 hr orbit. For white dwarfs with a temperature below 6000-7000 K (corresponding to a cooling age of >1--2 Gyr), this orbit is located in the white dwarf’s habitable zone. The recycling process also creates a string of smaller bodies just outside the Roche limit. These may account for the collection of minor planets postulated to orbit white dwarf WD 1145+017.

Constraining the inclination of the Low-Mass X-ray Binary Cen X-4

NASA Astrophysics Data System (ADS)

Hammerstein, Erica K.; Cackett, Edward M.; Reynolds, Mark T.; Miller, Jon M.

2018-05-01

We present the results of ellipsoidal light curve modeling of the low mass X-ray binary Cen X-4 in order to constrain the inclination of the system and mass of the neutron star. Near-IR photometric monitoring was performed in May 2008 over a period of three nights at Magellan using PANIC. We obtain J, H and K lightcurves of Cen X-4 using differential photometry. An ellipsoidal modeling code was used to fit the phase folded light curves. The lightcurve fit which makes the least assumptions about the properties of the binary system yields an inclination of 34.9^{+4.9}_{-3.6} degrees (1σ), which is consistent with previous determinations of the system's inclination but with improved statistical uncertainties. When combined with the mass function and mass ratio, this inclination yields a neutron star mass of 1.51^{+0.40}_{-0.55} M⊙. This model allows accretion disk parameters to be free in the fitting process. Fits that do not allow for an accretion disk component in the near-IR flux gives a systematically lower inclination between approximately 33 and 34 degrees, leading to a higher mass neutron star between approximately 1.7 M⊙ and 1.8 M⊙. We discuss the implications of other assumptions made during the modeling process as well as numerous free parameters and their effects on the resulting inclination.

Online monitoring of coffee roasting by proton transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS): towards a real-time process control for a consistent roast profile.

PubMed

Wieland, Flurin; Gloess, Alexia N; Keller, Marco; Wetzel, Andreas; Schenker, Stefan; Yeretzian, Chahan

2012-03-01

A real-time automated process control tool for coffee roasting is presented to consistently and accurately achieve a targeted roast degree. It is based on the online monitoring of volatile organic compounds (VOC) in the off-gas of a drum roaster by proton transfer reaction time-of-flight mass spectrometry at a high time (1 Hz) and mass resolution (5,500 m/Δm at full width at half-maximum) and high sensitivity (better than parts per billion by volume). Forty-two roasting experiments were performed with the drum roaster being operated either on a low, medium or high hot-air inlet temperature (= energy input) and the coffee (Arabica from Antigua, Guatemala) being roasted to low, medium or dark roast degrees. A principal component analysis (PCA) discriminated, for each one of the three hot-air inlet temperatures, the roast degree with a resolution of better than ±1 Colorette. The 3D space of the three first principal components was defined based on 23 mass spectral profiles of VOCs and their roast degree at the end point of roasting. This provided a very detailed picture of the evolution of the roasting process and allowed establishment of a predictive model that projects the online-monitored VOC profile of the roaster off-gas in real time onto the PCA space defined by the calibration process and, ultimately, to control the coffee roasting process so as to achieve a target roast degree and a consistent roasting.

A New Method for Estimation of Emissions and Sources of Measurements Error in the Silicon Refining Process

NASA Astrophysics Data System (ADS)

Næss, Mari k.; Kero, Ida; Tranell, Gabriella

2013-08-01

In the production of metallurgical grade silicon (MG-Si), fugitive emissions are a serious concern due to the health risks associated with the fumes formed in different parts of the production. The fumes are also a potential environmental hazard. Yet, the chemical composition of the fumes from most process steps in the silicon plant, such as oxidative refining ladle, remains unknown. This in turn constitutes a problem with respect to the correct assessment of the environmental impact and working conditions. A comprehensive industrial measurement campaign was performed at the Elkem Salten MG-Si production plant in Norway. Samples of the ingoing and outgoing mass flows were analyzed by high-resolution inductively coupled plasma mass spectrometry, with respect to 62 elements. In every step of the sampling and sample treatment processes, possible sources of error have been identified and quantified, including process variation, mass measurement accuracy, and contamination risk. Total measurement errors for all elements in all phases are established. The method is applied to estimate the order of magnitude of the elemental emissions via the fumes from the tapping and refining processes, with respect to production mass and year. The elements with higher concentrations in the fume than slag and refined silicon include Ag, Bi, Cd, Cu, In, K, Mg, Na, Pb, Rb, Se, Sn, Tl, and Zn: all being present in the ppm range. This work constitutes new and vital information to enable the correct assessment of the environmental impact and working conditions at an MG-Si plant.

Compact mass spectrometer for plasma discharge ion analysis

DOEpatents

Tuszewski, M.G.

1997-07-22

A mass spectrometer and methods are disclosed for mass spectrometry which are useful in characterizing a plasma. This mass spectrometer for determining type and quantity of ions present in a plasma is simple, compact, and inexpensive. It accomplishes mass analysis in a single step, rather than the usual two-step process comprised of ion extraction followed by mass filtering. Ions are captured by a measuring element placed in a plasma and accelerated by a known applied voltage. Captured ions are bent into near-circular orbits by a magnetic field such that they strike a collector, producing an electric current. Ion orbits vary with applied voltage and proton mass ratio of the ions, so that ion species may be identified. Current flow provides an indication of quantity of ions striking the collector. 7 figs.

Compact mass spectrometer for plasma discharge ion analysis

DOEpatents

Tuszewski, Michel G.

1997-01-01

A mass spectrometer and methods for mass spectrometry which are useful in characterizing a plasma. This mass spectrometer for determining type and quantity of ions present in a plasma is simple, compact, and inexpensive. It accomplishes mass analysis in a single step, rather than the usual two-step process comprised of ion extraction followed by mass filtering. Ions are captured by a measuring element placed in a plasma and accelerated by a known applied voltage. Captured ions are bent into near-circular orbits by a magnetic field such that they strike a collector, producing an electric current. Ion orbits vary with applied voltage and proton mass ratio of the ions, so that ion species may be identified. Current flow provides an indication of quantity of ions striking the collector.

Two-Dimensional Mathematical Modeling of the Pack Carburizing Process

NASA Astrophysics Data System (ADS)

Sarkar, S.; Gupta, G. S.

2008-10-01

Pack carburization is the oldest method among the case-hardening treatments, and sufficient attempts have not been made to understand this process in terms of heat and mass transfer, effect of alloying elements, dimensions of the sample, etc. Thus, a two-dimensional mathematical model in cylindrical coordinate is developed for simulating the pack carburization process for chromium-bearing steel in this study. Heat and mass balance equations are solved simultaneously, where the surface temperature of the sample varies with time, but the carbon potential at the surface during the process remains constant. The fully implicit finite volume technique is used to solve the governing equations. Good agreement has been found between the predicted and published data. The effect of temperature, carburizing time, dimensions of the sample, etc. on the pack carburizing process shows some interesting results. It is found that the two-dimensional model gives better insight into understanding the carburizing process.

Directed-energy process technology efforts

NASA Technical Reports Server (NTRS)

Alexander, P.

1985-01-01

A summary of directed-energy process technology for solar cells was presented. This technology is defined as directing energy or mass to specific areas on solar cells to produce a desired effect in contrast to exposing a cell to a thermal or mass flow environment. Some of these second generation processing techniques are: ion implantation; microwave-enhanced chemical vapor deposition; rapid thermal processing; and the use of lasers for cutting, assisting in metallization, assisting in deposition, and drive-in of liquid dopants. Advantages of directed energy techniques are: surface heating resulting in the bulk of the cell material being cooler and unchanged; better process control yields; better junction profiles, junction depths, and metal sintering; lower energy consumption during processing and smaller factory space requirements. These advantages should result in higher-efficiency cells at lower costs. The results of the numerous contracted efforts were presented as well as the application potentials of these new technologies.

Diffusion of Mass Media Messages among Brazilian Farmers.

ERIC Educational Resources Information Center

Schneider, Ivo A.; Fett, John H.

1978-01-01

Reports on a study designed to discover the nature of the flow of messages about recommended agricultural practices first introduced through the mass media in a developing country, and to explore the role opinion leaders plan in the process. (GW)

Fast Data Acquisition For Mass Spectrometer

NASA Technical Reports Server (NTRS)

Lincoln, K. A.; Bechtel, R. D.

1988-01-01

New equipment has speed and capacity to process time-of-flight data. System relies on fast, compact waveform digitizer with 32-k memory coupled to personal computer. With digitizer, system captures all mass peaks on each 25- to 35-microseconds cycle of spectrometer.

EMERGING POLLUTANTS, MASS SPECTROMETRY, AND COMMUNICATING SCIENCE: PHARMACEUTICALS IN THE ENVIRONMENT

EPA Science Inventory

Historically fundamental to amassing our understanding of environmental processes and chemical pollution is the realm of mass spectrometry (MS) - the mainstay of analytical
chemistry - the workhorse that supplies definitive data that environmental scientists and engineers...

Recycling Titanium and Its Alloys by Utilizing Molten Salt

NASA Astrophysics Data System (ADS)

Okabe, Toru H.; Taninouchi, Yu-ki

It is commonly believed that the deoxidation of titanium (Ti), or the direct removal of oxygen (O) dissolved in metallic Ti, is practically impossible when magnesium (Mg) is used as the deoxidizing agent. In recent years, it has been experimentally demonstrated that O dissolved in Ti can be directly removed using MgCl2 molten salt electrolysis. By the electrochemical deoxidation technique, Ti wires containing 0.12 mass% O were deoxidized to less than 0.02 mass% O. In some cases, the concentration of O in the Ti wires was reduced to the level of 0.01 mass% O, which cannot be attained using the current Kroll process. The possible application of this deoxidation technique to practical industrial recycling processes is also discussed.

Two-dimensional CFD modeling of the heat and mass transfer process during sewage sludge drying in a solar dryer

NASA Astrophysics Data System (ADS)

Krawczyk, Piotr; Badyda, Krzysztof

2011-12-01

The paper presents key assumptions of the mathematical model which describes heat and mass transfer phenomena in a solar sewage drying process, as well as techniques used for solving this model with the Fluent computational fluid dynamics (CFD) software. Special attention was paid to implementation of boundary conditions on the sludge surface, which is a physical boundary between the gaseous phase - air, and solid phase - dried matter. Those conditions allow to model heat and mass transfer between the media during first and second drying stages. Selection of the computational geometry is also discussed - it is a fragment of the entire drying facility. Selected modelling results are presented in the final part of the paper.

Big Data in the Industry - Overview of Selected Issues

NASA Astrophysics Data System (ADS)

Gierej, Sylwia

2017-12-01

This article reviews selected issues related to the use of Big Data in the industry. The aim is to define the potential scope and forms of using large data sets in manufacturing companies. By systematically reviewing scientific and professional literature, selected issues related to the use of mass data analytics in production were analyzed. A definition of Big Data was presented, detailing its main attributes. The importance of mass data processing technology in the development of Industry 4.0 concept has been highlighted. Subsequently, attention was paid to issues such as production process optimization, decision making and mass production individualisation, and indicated the potential for large volumes of data. As a result, conclusions were drawn regarding the potential of using Big Data in the industry.

Three phase heat and mass transfer model for unsaturated soil freezing process: Part 2 - model validation

NASA Astrophysics Data System (ADS)

Zhang, Yaning; Xu, Fei; Li, Bingxi; Kim, Yong-Song; Zhao, Wenke; Xie, Gongnan; Fu, Zhongbin

2018-04-01

This study aims to validate the three-phase heat and mass transfer model developed in the first part (Three phase heat and mass transfer model for unsaturated soil freezing process: Part 1 - model development). Experimental results from studies and experiments were used for the validation. The results showed that the correlation coefficients for the simulated and experimental water contents at different soil depths were between 0.83 and 0.92. The correlation coefficients for the simulated and experimental liquid water contents at different soil temperatures were between 0.95 and 0.99. With these high accuracies, the developed model can be well used to predict the water contents at different soil depths and temperatures.

A factory concept for processing and manufacturing with lunar material

NASA Technical Reports Server (NTRS)

Driggers, G. W.

1977-01-01

A conceptual design for an orbital factory sized to process 1.5 million metric tons per year of raw lunar fines into 0.3 million metric tons of manufacturing materials is presented. A conservative approach involving application of present earth-based technology leads to a design devoid of new inventions. Earth based counterparts to the factory machinery were used to generate subsystem masses and lumped parameters for volume and mass estimates. The results are considered to be conservative since technologies more advanced than those assumed are presently available in many areas. Some attributes of potential space processing technologies applied to material refinement and component manufacture are discussed.

Uprating the Frontal Thrust of a Spherical Gas-Dynamical Resonator-Pulse Amplifier

NASA Astrophysics Data System (ADS)

Bogdanov, V. I.; Khantalin, D. S.

2017-01-01

Calculations were carried out with application of current numerical methods and with the use of scientific-technical developments of a gas-dynamical resonator-thrust amplifier. The possibility of creating an exit device with a resonator for a small-size gas-turbine engine that in flight provides for thrust uprating by no less than 6% via gas mass attachment in the pulsating process is shown. In this way the size-mass characteristics of the exit device are preserved in the process.

Proceedings of the conference on energy conservation: Retrofit of Municipal Wastewater Treatment Facilities

NASA Astrophysics Data System (ADS)

1982-02-01

The concepts of the roles of heat and temperature, ventilation and water removal when organic material is assembled into a self insulating mass are summarized. The practical application of these concepts in static pile configuration or the Rutgers process are outlined. The concepts and means of application are relevant to all design approaches whether or not a reactor structure is involved, whether the process is batch or continuous, and whether the mass is agitated or static.

Resolving components of wind accreting systems: a case study of Mira AB

NASA Astrophysics Data System (ADS)

Karovska, M.

2004-12-01

Mass transfer in many systems occurs by wind interaction rather then by tidal interaction, because the primary does not fill its Roche surface. The nearby detached binary Mira AB provides a unique laboratory for studying wind accretion processes because this system can be resolved and the interacting components can be studied individually, which is not possible in most accreting systems. The study of Mira AB wind accretion and mass transfer may therefore help understand the accretion processes in many other astronomical systems.

Rotorcraft Use in Disaster Relief and Mass Casualty Incidents - Case Studies

DTIC Science & Technology

1990-06-01

Disaster Relief and Mass 6. Performing Organization Code C asuallty Incidents- C ase Studies 8._P rfo minOr ani ati nR porNo 7. Author (s) 8...disaster planning process; and 3) produce a color video tape promoting the need for and the use of rotorcraft and heliports in disaster relief. 17...disaster prepaLedness ageicies for use in the integration of local helicopter assets into the disaster planning process; and 3) produce a color video tape

Cosmic-Ray Energetics and Mass (CREAM) Processing - Bonding

NASA Image and Video Library

2017-06-20

In the Space Station Processing Facility at NASA's Kennedy Space Center in Florida, technicians and engineers remove a protective cover on the Cosmic-Ray Energetics and Mass investigation, or CREAM, instrument. It is designed to measure the charges of cosmic rays to better understand what gives them such incredible energies, and how that effects the composition of the universe. The instrument will be launched to the space station on the SpaceX CRS-12 commercial resupply mission in August 2017.

Cloud processing of organic compounds: Secondary organic aerosol and nitrosamine formation

NASA Astrophysics Data System (ADS)

Hutchings, James W., III

Cloud processing of atmospheric organic compounds has been investigated through field studies, laboratory experiments, and numerical modeling. Observational cloud chemistry studies were performed in northern Arizona and fog studies in central Pennsylvania. At both locations, the cloud and fogs showed low acidity due to neutralization by soil dust components (Arizona) and ammonia (Pennsylvania). The field observations showed substantial concentrations (20-5500 ng•L -1) of volatile organic compounds (VOC) in the cloud droplets. The potential generation of secondary organic aerosol mass through the processing of these anthropogenic VOCs was investigated through laboratory and modeling studies. Under simulated atmospheric conditions, in idealized solutions, benzene, toluene, ethylbenzene, and xylene (BTEX) degraded quickly in the aqueous phase with half lives of approximately three hours. The degradation process yielded less volatile products which would contribute to new aerosol mass upon cloud evaporation. However, when realistic cloud solutions containing natural organic matter were used in the experiments, the reaction kinetics decreased with increasing organic carbon content, resulting in half lives of approximately 7 hours. The secondary organic aerosol (SUA) mass formation potential of cloud processing of BTEX was evaluated. SOA mass formation by cloud processing of BTEX, while strongly dependent on the atmospheric conditions, could contribute up to 9% of the ambient atmospheric aerosol mass, although typically ˜1% appears realistic. Field observations also showed the occurrence of N-nitrosodimethylamine (NDMA), a potent carcinogen, in fogs and clouds (100-340 ng•L -1). Laboratory studies were conducted to investigate the formation of NDMA from nitrous acid and dimethylamine in the homogeneous aqueous phase within cloud droplets. While NDMA was produced in the cloud droplets, the low yields (<1%) observed could not explain observational concentrations. Therefore heterogeneous or gaseous formation of NDMA with partitioning to droplet must be the source of aqueous NDMA. Box-model calculations tended to demonstrate a predominance of a gas phase formation mechanism followed by partitioning into the cloud droplets. The calculations were consistent with field measurements of gaseous and aqueous NDMA concentrations. Measurements and model calculations showed that while NDMA is eventually photolyzed, it might persist in the atmosphere for hours.

Chromatography - mass spectrometry in aerospace industry

NASA Astrophysics Data System (ADS)

Buryak, A. K.; Serdyuk, T. M.

2013-01-01

The applications of chromatography - mass spectrometry in aerospace industry are considered. The primary attention is devoted to the development of physicochemical grounds of the use of various chromatography - mass spectrometry procedures to solve topical problems of this industry. Various methods for investigation of the composition of rocket fuels, surfaces of structural materials and environmental media affected by aerospace activities are compared. The application of chromatography - mass spectrometry for the development and evaluation of processes for decontaminations of equipment, industrial wastes and soils from rocket fuel components is substantiated. The bibliography includes 135 references.

Laser mass spectrometry of chemical warfare agents using ultrashort laser pulses

NASA Astrophysics Data System (ADS)

Weickhardt, C.; Grun, C.; Grotemeyer, J.

1998-12-01

Fast relaxation processes in excited molecules such as IC, ISC, and fragmentation are observed in many environmentally and technically relevant substances. They cause severe problems to resonance ionization mass spectrometry because they reduce the ionization yield and lead to mass spectra which do not allow the identification of the compound. By the use of ultrashort laser pulses these problems can be overcome and the advantages of REMPI over conventional ionization techniques in mass spectrometry can be regained. This is demonstrated using soil samples contaminated with a chemical warfare agent.

Mass Measurements of Proton-rich Nuclides at the Cooler Storage Ring at IMP

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Y. H.; Xu, H. S.; Wang, M.

2011-11-30

Recent results and progress of mass measurements of proton-rich nuclei using isochronous mass spectrometry (IMS) are reported. The nuclei under investigation were produced via fragmentation of relativistic energy heavy ions of {sup 78}Kr and {sup 58}Ni. After in-flight separation by the fragment separator RIBLL-2, the nuclei were injected and stored in the experimental storage ring CSRe, and their masses were determined from measurements of the revolution times. The impact of these measurements on the stellar nucleosynthesis in the rp-process is discussed.

Surveying Low-Mass Star Formation with the Submillimeter Array

NASA Astrophysics Data System (ADS)

Dunham, Michael

2018-01-01

Large astronomical surveys yield important statistical information that can’t be derived from single-object and small-number surveys. In this talk I will review two recent surveys in low-mass star formation undertaken by the Submillimeter Array (SMA): a millimeter continuum survey of disks surrounding variably accreting young stars, and a complete continuum and molecular line survey of all protostars in the nearby Perseus Molecular Cloud. I will highlight several new insights into the processes by which low-mass stars gain their mass that have resulted from the statistical power of these surveys.

[Advances in mass spectrometry-based approaches for neuropeptide analysis].

PubMed

Ji, Qianyue; Ma, Min; Peng, Xin; Jia, Chenxi; Ji, Qianyue

2017-07-25

Neuropeptides are an important class of endogenous bioactive substances involved in the function of the nervous system, and connect the brain and other neural and peripheral organs. Mass spectrometry-based neuropeptidomics are designed to study neuropeptides in a large-scale manner and obtain important molecular information to further understand the mechanism of nervous system regulation and the pathogenesis of neurological diseases. This review summarizes the basic strategies for the study of neuropeptides using mass spectrometry, including sample preparation and processing, qualitative and quantitative methods, and mass spectrometry imagining.

Simulation of the usage of Gaussian mixture models for the purpose of modelling virtual mass spectrometry data.

PubMed

Plechawska, Małgorzata; Polańska, Joanna

2009-01-01

This article presents the method of the processing of mass spectrometry data. Mass spectra are modelled with Gaussian Mixture Models. Every peak of the spectrum is represented by a single Gaussian. Its parameters describe the location, height and width of the corresponding peak of the spectrum. An authorial version of the Expectation Maximisation Algorithm was used to perform all calculations. Errors were estimated with a virtual mass spectrometer. The discussed tool was originally designed to generate a set of spectra within defined parameters.

Application of an atmospheric pressure sampling mass spectrometer to chlorination reactions

NASA Technical Reports Server (NTRS)

Jacobson, N. S.

1986-01-01

An atmospheric pressure mass spectrometric sampling system, based on a free jet expansion was used to study certain M-Cl-O reactions at high temperatures. The apparatus enables the volatile species from a 1-atm chemical process to be directly identified with a mass spectrometer which operates at approx. 10 to the minus 8th power torr. Studies for both pure metals and alloys are discussed. It is shown that this mass spectrometer system aids in identifying the volatile species, and provides fundamental information on the reaction mechanism.

Cost-Effective, Ultra-Sensitive Groundwater Monitoring for Site Remediation and Management

DTIC Science & Technology

2015-08-01

Micrometer ml Milliliter MS Mass Spectrometry MW Molecular Weight MΩ Mega-ohm NAS Naval Air Station 6 NASNI Naval Air Station North Island...feasibility studies. ..........42 Table 5-2 Compounds screened in the laboratory for IS2 sampling ......................................44 Table 5-3 Mass ...concentration data is derived directly from the mass of analyte recovered from the sorbent cartridge and the known volume of water processed. This

Cancellation of the central singularity of the Schwarzschild solution with natural mass inversion process

NASA Astrophysics Data System (ADS)

Petit, Jean-Pierre; D'Agostini, G.

2015-03-01

We reconsider the classical Schwarzschild solution in the context of a Janus cosmological model. We show that the central singularity can be eliminated through a simple coordinate change and that the subsequent transit from one fold to the other is accompanied by mass inversion. In such scenario matter swallowed by black holes could be ejected as invisible negative mass and dispersed in space.

A microelectromechanical accelerometer fabricated using printed circuit processing techniques

NASA Astrophysics Data System (ADS)

Rogers, J. E.; Ramadoss, R.; Ozmun, P. M.; Dean, R. N.

2008-01-01

A microelectromechanical systems (MEMS) capacitive-type accelerometer fabricated using printed circuit processing techniques is presented. A Kapton polymide film is used as the structural layer for fabricating the MEMS accelerometer. The accelerometer proof mass along with four suspension beams is defined in the Kapton polyimide film. The proof mass is suspended above a Teflon substrate using a spacer. The deflection of the proof mass is detected using a pair of capacitive sensing electrodes. The top electrode of the accelerometer is defined on the top surface of the Kapton film. The bottom electrode is defined in the metallization on the Teflon substrate. The initial gap height is determined by the distance between the bottom electrode and the Kapton film. For an applied external acceleration (normal to the proof mass), the proof mass deflects toward or away from the fixed bottom electrode due to inertial force. This deflection causes either a decrease or increase in the air-gap height thereby either increasing or decreasing the capacitance between the top and the bottom electrodes. An example PCB MEMS accelerometer with a square proof mass of membrane area 6.4 mm × 6.4 mm is reported. The measured resonant frequency is 375 Hz and the Q-factor in air is 0.52.

Subunit mass analysis for monitoring antibody oxidation.

PubMed

Sokolowska, Izabela; Mo, Jingjie; Dong, Jia; Lewis, Michael J; Hu, Ping

2017-04-01

Methionine oxidation is a common posttranslational modification (PTM) of monoclonal antibodies (mAbs). Oxidation can reduce the in-vivo half-life, efficacy and stability of the product. Peptide mapping is commonly used to monitor the levels of oxidation, but this is a relatively time-consuming method. A high-throughput, automated subunit mass analysis method was developed to monitor antibody methionine oxidation. In this method, samples were treated with IdeS, EndoS and dithiothreitol to generate three individual IgG subunits (light chain, Fd' and single chain Fc). These subunits were analyzed by reversed phase-ultra performance liquid chromatography coupled with an online quadrupole time-of-flight mass spectrometer and the levels of oxidation on each subunit were quantitated based on the deconvoluted mass spectra using the UNIFI software. The oxidation results obtained by subunit mass analysis correlated well with the results obtained by peptide mapping. Method qualification demonstrated that this subunit method had excellent repeatability and intermediate precision. In addition, UNIFI software used in this application allows automated data acquisition and processing, which makes this method suitable for high-throughput process monitoring and product characterization. Finally, subunit mass analysis revealed the different patterns of Fc methionine oxidation induced by chemical and photo stress, which makes it attractive for investigating the root cause of oxidation.

Probing Interfacial Processes on Graphene Surface by Mass Detection

NASA Astrophysics Data System (ADS)

Kakenov, Nurbek; Kocabas, Coskun

2013-03-01

In this work we studied the mass density of graphene, probed interfacial processes on graphene surface and examined the formation of graphene oxide by mass detection. The graphene layers were synthesized by chemical vapor deposition method on copper foils and transfer-printed on a quartz crystal microbalance (QCM). The mass density of single layer graphene was measured by investigating the mechanical resonance of the QCM. Moreover, we extended the developed technique to probe the binding dynamics of proteins on the surface of graphene, were able to obtain nonspecific binding constant of BSA protein of graphene surface in aqueous solution. The time trace of resonance signal showed that the BSA molecules rapidly saturated by filling the available binding sites on graphene surface. Furthermore, we monitored oxidation of graphene surface under oxygen plasma by tracing the changes of interfacial mass of the graphene controlled by the shifts in Raman spectra. Three regimes were observed the formation of graphene oxide which increases the interfacial mass, the release of carbon dioxide and the removal of small graphene/graphene oxide flakes. Scientific and Technological Research Council of Turkey (TUBITAK) grant no. 110T304, 109T209, Marie Curie International Reintegration Grant (IRG) grant no 256458, Turkish Academy of Science (TUBA-Gebip).

An exactly solvable model of polymerization

NASA Astrophysics Data System (ADS)

Lushnikov, A. A.

2017-08-01

This paper considers the evolution of a polydisperse polymerizing system comprising g1,g2 … - mers carrying ϕ1,ϕ2 … functional groups reacting with one another and binding the g-mers together. In addition, the g-mers are assumed to be added at random by one at a time with a known rate depending on their mass g and functionality ϕ . Assuming that the rate of binding of two g-mers is proportional to the product of the numbers of nonreacted functional groups the kinetic equation for the distribution of clusters (g-mers) over their mass and functionalities is formulated and then solved by applying the generating function method. In contrast to existing approaches this kinetic equation operates with the efficiencies proportional to the product of the numbers of active functional groups in the clusters rather than to the product of their masses. The evolution process is shown to reveal a phase transition: the emergence of a giant linked cluster (the gel) whose mass is comparable to the total mass of the whole polymerizing system. The time dependence of the moments of the distribution of linked components over their masses and functionalities is investigated. The polymerization process terminates by forming a residual spectrum of sol particles in addition to the gel.

40 CFR Table 7 to Subpart Ppp of... - Process Vents From Continuous Unit Operations-Monitoring, Recordkeeping, and Reporting Requirements

Code of Federal Regulations, 2013 CFR

2013-07-01

... regeneration stream mass or volumetric flow during carbon bed regeneration cycle; and temperature of the carbon bed after regeneration (and within 15 minutes of completing any cooling cycle(s)) Maximum mass or...

Fate of very low-mass secondaries in accreting binaries and the 1.5-ms pulsar

NASA Technical Reports Server (NTRS)

Ruderman, M. A.; Shaham, J.

1983-01-01

It is shown analytically that the canonical stability postulate for low-mass binaries can be inaccurate when the secondary component mass is less than 0.02 solar mass. The adjustable evolutionary parameter h is demonstrated to have a value (in terms of the mass flow effects) of 2/3, less than which catastrophic instability and tidal disruption of the secondary might occur. The disrupted secondary would be reduced to a remnant significantly smaller in mass than the earth, and not be observable visually. Additionally, close passage by another star could accelerate or initiate the process. The model is applicable to the pulsar binary PSR1937+214, and is noted not to conflict with spin-up theories.

Hydromechanical coupling in fractured rock masses: mechanisms and processes of selected case studies

NASA Astrophysics Data System (ADS)

Zangerl, Christian

2015-04-01

Hydromechanical (HM) coupling in fractured rock play an important role when events including dam failures, landslides, surface subsidences due to water withdrawal or drainage, injection-induced earthquakes and others are analysed. Generally, hydromechanical coupling occurs when a rock mass contain interconnected pores and fractures which are filled with water and pore/fracture pressures evolves. In the on hand changes in the fluid pressure can lead to stress changes, deformations and failures of the rock mass. In the other hand rock mass stress changes and deformations can alter the hydraulic properties and fluid pressures of the rock mass. Herein well documented case studies focussing on surface subsidence due to water withdrawal, reversible deformations of large-scale valley flanks and failure as well as deformation processes of deep-seated rock slides in fractured rock masses are presented. Due to pore pressure variations HM coupling can lead to predominantly reversible rock mass deformations. Such processes can be considered by the theory of poroelasticity. Surface subsidence reaching magnitudes of few centimetres and are caused by water drainage into deep tunnels are phenomenas which can be assigned to processes of poroelasticity. Recently, particular focus was given on large tunnelling projects to monitor and predict surface subsidence in fractured rock mass in oder to avoid damage of surface structures such as dams of large reservoirs. It was found that surface subsidence due to tunnel drainage can adversely effect infrastructure when pore pressure drawdown is sufficiently large and spatially extended and differential displacements which can be amplified due to topographical effects e.g. valley closure are occurring. Reversible surface deformations were also ascertained on large mountain slopes and summits with the help of precise deformation measurements i.e. permanent GPS or episodic levelling/tacheometric methods. These reversible deformations are often in the range of millimetres to a very few centimetres and can be linked to annual groundwater fluctuations. Due to pore pressure variations HM coupling can influence seepage forces and effective stresses in the rock mass. Effective stress changes can adversely affect the stability and deformation behaviour of deep-seated rock slides by influencing the shear strength or the time dependent (viscous) material behaviour of the basal shear zone. The shear strength of active shear zones is often reasonably well described by Coulomb's law. In Coulomb's law the operative normal stresses to the shear surface/zone are effective stresses and hence pore pressures which should be taken into account reduces the shear strength. According to the time dependent material behaviour a few effective stress based viscous models exists which are able to consider pore pressures. For slowly moving rock slides HM coupling could be highly relevant when low-permeability clayey-silty shear zones (fault gouges) are existing. An important parameters therefore is the hydraulic diffusivity, which is controlled by the permeability and fluid-pore compressibility of the shear zone, and by fluid viscosity. Thus time dependent pore pressure diffusion in the shear zone can either control the stability condition or the viscous behaviour (creep) of the rock slide. Numerous cases studies show that HM coupling can effect deformability, shear strength and time dependent behaviour of fractured rock masses. A process-based consideration can be important to avoid unexpected impacts on infrastructures and to understand complex rock mass as well rock slide behaviour.

Physical properties and evolutionary time scales of disks around solar-type and intermediate mass stars

NASA Technical Reports Server (NTRS)

Strom, Stephen E.; Edwards, Suzan

1993-01-01

Recent observations of circumstellar disks and their evolutionary timescales are reviewed. It is concluded that disks appear to be a natural outcome of the star-formation process. The disks surrounding young stars initially are massive, with optically thick structures comprised of gas and micron-sized grains. Disk masses are found to range from 0.01 to 0.2 solar masses for solar-type PMS stars, and from 0.01 to 6 solar masses for young, intermediate mass stars. Massive, optically thick accretion disks have accretion rates between 10 exp -8 and 10 exp -6 solar masses/yr for solar type PMS stars and between 10 exp -6 and 10 exp -4 solar masses/yr for intermediate stars. The results suggest that a significant fraction of the mass comprising the star may have passed through a circumstellar accretion disk.

Ruprecht 106: The first single population globular cluster?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Villanova, S.; Geisler, D.; Muñoz, C.

2013-12-01

All old Galactic globular clusters (GCs) studied in detail to date host at least two generations of stars, where the second is formed from gas polluted by processed material produced by massive stars of the first. This process can happen if the initial mass of the cluster exceeds a threshold above which ejecta are retained and a second generation is formed. A determination of this mass threshold is mandatory in order to understand how GCs form. We analyzed nine red giant branch stars belonging to the cluster Ruprecht 106. Targets were observed with the UVES@VLT2 spectrograph. Spectra cover a widemore » range and allowed us to measure abundances for light (O, Na, Mg, Al), α (Si, Ca, Ti), iron-peak (Sc, V, Cr, Mn, Fe, Co, Ni, Cu, Zn), and neutron-capture (Y, Zr, Ba, La, Ce, Pr, Nd, Sm, Eu, Dy, Pb) elements. Based on these abundances, we show that Ruprecht 106 is the first convincing example of a single-population GC (i.e., a true simple stellar population), although the sample is relatively small. This result is supported also by an independent photometric test and by the horizontal branch morphology and the dynamical state. It is old (∼12 Gyr) and, at odds with other GCs, has no α-enhancement. The material it formed from was contaminated by both s- and r-process elements. The abundance pattern points toward an extragalactic origin. Its present-day mass (M = 10{sup 4.83} M {sub ☉}) can be assumed as a strong lower limit for the initial mass threshold below which no second generation is formed. Clearly, its initial mass must have been significantly greater, but we have no current constraints on the amount of mass loss during its evolution.« less

Mass spectrometric screening and identification of acidic metabolites in fulvic acid fractions of contaminated groundwater.

PubMed

Jobelius, Carsten; Frimmel, Fritz H; Zwiener, Christian

2014-05-01

The anaerobic microbial degradation of aromatic and heterocyclic compounds is a prevalent process in contaminated groundwater systems. The introduction of functional groups into the contaminant molecules often results in aromatic and heterocyclic and succinic acids. These metabolites can be used as indicators for prevailing degradation processes. Therefore, there is a strong interest in developing analytical methods for screening and identification of these metabolites. In this study, neutral loss scans (NLS) by liquid chromatography-electrospray ionization/tandem mass spectrometry with losses of CO2 (NL ∆m/z = 44) and C2H4(CO2)2 (NL ∆m/z = 116) were applied for the first time successfully to screen selectively for acidic and succinic metabolites of aromatic and heterocyclic contaminants in two fulvic acid fractions from a contaminated site and a downstream region of a tar oil-polluted groundwater. Identification of these preselected signals was performed by high-resolution mass spectrometry with a liquid chromatography-electrospray ionization quadrupole time-of-flight mass spectrometry instrument. High-resolution mass and mass fragmentation data were then compared with a list of known metabolites from a literature search or matched with chemical databases supported with in silico fragmentation. Based on authentic analytical standards, several compounds from NLS were identified (e.g., 4-hydroxy-3-methylbenzoic acid, benzylsuccinic acid, naphthyl-2-methylsuccinic acid, 2-carboxyindane, and 2-carboxybenzothiophene) and tentatively identified (e.g., benzofuranmethylsuccinic acid and dihydrocarboxybenzothiophene) as aromatic, phenolic, heterocyclic, and succinic acids. The acidic metabolites were found exclusively in the contaminated region of the aquifer which indicates active biodegradation processes and no relevant occurrence of acidic metabolites in the downstream region.

imzML: Imaging Mass Spectrometry Markup Language: A common data format for mass spectrometry imaging.

PubMed

Römpp, Andreas; Schramm, Thorsten; Hester, Alfons; Klinkert, Ivo; Both, Jean-Pierre; Heeren, Ron M A; Stöckli, Markus; Spengler, Bernhard

2011-01-01

Imaging mass spectrometry is the method of scanning a sample of interest and generating an "image" of the intensity distribution of a specific analyte. The data sets consist of a large number of mass spectra which are usually acquired with identical settings. Existing data formats are not sufficient to describe an MS imaging experiment completely. The data format imzML was developed to allow the flexible and efficient exchange of MS imaging data between different instruments and data analysis software.For this purpose, the MS imaging data is divided in two separate files. The mass spectral data is stored in a binary file to ensure efficient storage. All metadata (e.g., instrumental parameters, sample details) are stored in an XML file which is based on the standard data format mzML developed by HUPO-PSI. The original mzML controlled vocabulary was extended to include specific parameters of imaging mass spectrometry (such as x/y position and spatial resolution). The two files (XML and binary) are connected by offset values in the XML file and are unambiguously linked by a universally unique identifier. The resulting datasets are comparable in size to the raw data and the separate metadata file allows flexible handling of large datasets.Several imaging MS software tools already support imzML. This allows choosing from a (growing) number of processing tools. One is no longer limited to proprietary software, but is able to use the processing software which is best suited for a specific question or application. On the other hand, measurements from different instruments can be compared within one software application using identical settings for data processing. All necessary information for evaluating and implementing imzML can be found at http://www.imzML.org .

r.avaflow v1, an advanced open-source computational framework for the propagation and interaction of two-phase mass flows

NASA Astrophysics Data System (ADS)

Mergili, Martin; Fischer, Jan-Thomas; Krenn, Julia; Pudasaini, Shiva P.

2017-02-01

r.avaflow represents an innovative open-source computational tool for routing rapid mass flows, avalanches, or process chains from a defined release area down an arbitrary topography to a deposition area. In contrast to most existing computational tools, r.avaflow (i) employs a two-phase, interacting solid and fluid mixture model (Pudasaini, 2012); (ii) is suitable for modelling more or less complex process chains and interactions; (iii) explicitly considers both entrainment and stopping with deposition, i.e. the change of the basal topography; (iv) allows for the definition of multiple release masses, and/or hydrographs; and (v) serves with built-in functionalities for validation, parameter optimization, and sensitivity analysis. r.avaflow is freely available as a raster module of the GRASS GIS software, employing the programming languages Python and C along with the statistical software R. We exemplify the functionalities of r.avaflow by means of two sets of computational experiments: (1) generic process chains consisting in bulk mass and hydrograph release into a reservoir with entrainment of the dam and impact downstream; (2) the prehistoric Acheron rock avalanche, New Zealand. The simulation results are generally plausible for (1) and, after the optimization of two key parameters, reasonably in line with the corresponding observations for (2). However, we identify some potential to enhance the analytic and numerical concepts. Further, thorough parameter studies will be necessary in order to make r.avaflow fit for reliable forward simulations of possible future mass flow events.

'Isotopo' a database application for facile analysis and management of mass isotopomer data.

PubMed

Ahmed, Zeeshan; Zeeshan, Saman; Huber, Claudia; Hensel, Michael; Schomburg, Dietmar; Münch, Richard; Eylert, Eva; Eisenreich, Wolfgang; Dandekar, Thomas

2014-01-01

The composition of stable-isotope labelled isotopologues/isotopomers in metabolic products can be measured by mass spectrometry and supports the analysis of pathways and fluxes. As a prerequisite, the original mass spectra have to be processed, managed and stored to rapidly calculate, analyse and compare isotopomer enrichments to study, for instance, bacterial metabolism in infection. For such applications, we provide here the database application 'Isotopo'. This software package includes (i) a database to store and process isotopomer data, (ii) a parser to upload and translate different data formats for such data and (iii) an improved application to process and convert signal intensities from mass spectra of (13)C-labelled metabolites such as tertbutyldimethylsilyl-derivatives of amino acids. Relative mass intensities and isotopomer distributions are calculated applying a partial least square method with iterative refinement for high precision data. The data output includes formats such as graphs for overall enrichments in amino acids. The package is user-friendly for easy and robust data management of multiple experiments. The 'Isotopo' software is available at the following web link (section Download): http://spp1316.uni-wuerzburg.de/bioinformatics/isotopo/. The package contains three additional files: software executable setup (installer), one data set file (discussed in this article) and one excel file (which can be used to convert data from excel to '.iso' format). The 'Isotopo' software is compatible only with the Microsoft Windows operating system. http://spp1316.uni-wuerzburg.de/bioinformatics/isotopo/. © The Author(s) 2014. Published by Oxford University Press.

Lattice Boltzmann simulation of the gas-solid adsorption process in reconstructed random porous media.

PubMed

Zhou, L; Qu, Z G; Ding, T; Miao, J Y

2016-04-01

The gas-solid adsorption process in reconstructed random porous media is numerically studied with the lattice Boltzmann (LB) method at the pore scale with consideration of interparticle, interfacial, and intraparticle mass transfer performances. Adsorbent structures are reconstructed in two dimensions by employing the quartet structure generation set approach. To implement boundary conditions accurately, all the porous interfacial nodes are recognized and classified into 14 types using a proposed universal program called the boundary recognition and classification program. The multiple-relaxation-time LB model and single-relaxation-time LB model are adopted to simulate flow and mass transport, respectively. The interparticle, interfacial, and intraparticle mass transfer capacities are evaluated with the permeability factor and interparticle transfer coefficient, Langmuir adsorption kinetics, and the solid diffusion model, respectively. Adsorption processes are performed in two groups of adsorbent media with different porosities and particle sizes. External and internal mass transfer resistances govern the adsorption system. A large porosity leads to an early time for adsorption equilibrium because of the controlling factor of external resistance. External and internal resistances are dominant at small and large particle sizes, respectively. Particle size, under which the total resistance is minimum, ranges from 3 to 7 μm with the preset parameters. Pore-scale simulation clearly explains the effect of both external and internal mass transfer resistances. The present paper provides both theoretical and practical guidance for the design and optimization of adsorption systems.

Lattice Boltzmann simulation of the gas-solid adsorption process in reconstructed random porous media

NASA Astrophysics Data System (ADS)

Zhou, L.; Qu, Z. G.; Ding, T.; Miao, J. Y.

2016-04-01

The gas-solid adsorption process in reconstructed random porous media is numerically studied with the lattice Boltzmann (LB) method at the pore scale with consideration of interparticle, interfacial, and intraparticle mass transfer performances. Adsorbent structures are reconstructed in two dimensions by employing the quartet structure generation set approach. To implement boundary conditions accurately, all the porous interfacial nodes are recognized and classified into 14 types using a proposed universal program called the boundary recognition and classification program. The multiple-relaxation-time LB model and single-relaxation-time LB model are adopted to simulate flow and mass transport, respectively. The interparticle, interfacial, and intraparticle mass transfer capacities are evaluated with the permeability factor and interparticle transfer coefficient, Langmuir adsorption kinetics, and the solid diffusion model, respectively. Adsorption processes are performed in two groups of adsorbent media with different porosities and particle sizes. External and internal mass transfer resistances govern the adsorption system. A large porosity leads to an early time for adsorption equilibrium because of the controlling factor of external resistance. External and internal resistances are dominant at small and large particle sizes, respectively. Particle size, under which the total resistance is minimum, ranges from 3 to 7 μm with the preset parameters. Pore-scale simulation clearly explains the effect of both external and internal mass transfer resistances. The present paper provides both theoretical and practical guidance for the design and optimization of adsorption systems.

Development of a continuous roll-to-roll processing system for mass production of plastic optical film

NASA Astrophysics Data System (ADS)

Chang, Chih-Yuan; Tsai, Meng-Hsun

2015-12-01

This paper reports a highly effective method for the mass production of large-area plastic optical films with a microlens array pattern based on a continuous roll-to-roll film extrusion and roller embossing process. In this study, a thin steel mold with a micro-circular hole array pattern is fabricated by photolithography and a wet chemical etching process. The thin steel mold was then wrapped onto a metal cylinder to form an embossing roller mold. During the roll-to-roll process operation, a thermoplastic raw material (polycarbonate grains) was put into the barrel of the plastic extruder with a flat T-die. Then, the molten polymer film was extruded and immediately pressed against the surface of the embossing roller mold. Under the proper processing conditions, the molten polymer will just partially fill the micro-circular holes of the mold and due to surface tension form a convex lens surface. A continuous plastic optical film with a microlens array pattern was obtained. Experiments are carried out to investigate the effect of plastic microlens formation on the roll-to-roll process. Finally, the geometrical and optical properties of the fabricated plastic optical film were measured and proved satisfactory. This technique shows great potential for the mass production of large-area plastic optical films with a microlens array pattern.

Effect of the secondary process on mass point vibration velocity propagation in magneto-acoustic tomography and magneto-acousto-electrical tomography.

PubMed

Sun, Zhishen; Liu, Guoqiang; Guo, Liang; Xia, Hui; Wang, Xinli

2016-04-29

As two of the new biological electrical impedance tomography (EIT), magneto-acoustic tomography (MAT) and magneto-acousto-electrical tomography (MAET) achieve both the high contrast property of EIT and the high spatial resolution property of sonography through combining EIT and sonography. As both MAT and MAET contain a uniform magnetic field, vibration and electrical current density, there is a secondary process both in MAT and in MAET, which is MAET and MAT respectively. To analyze the effect of the secondary process on mass point vibration velocity (MPVV) propagation in MAT and MAET. By analyzing the total force to the sample, the wave equations of MPVV in MAT and MAET - when the secondary processes were considered - were derived. The expression of the attenuation constant in the wave number was derived in the case that the mass point vibration velocity propagates in the form of cylindrical wave and plane wave. Attenuations of propagation of the MPVV in several samples were quantified. Attenuations of the MPVV after propagating for 1 mm in copper or aluminum foil, and for 5 cm in gel phantom or biological soft tissue were less than 1%. Attenuations of the MPVV in MAT and MAET due to the secondary processes are relatively minor, and effects of the secondary processes on MPVV propagation in MAT and MAET can be ignored.

Black holes as bubble nucleation sites

NASA Astrophysics Data System (ADS)

Gregory, Ruth; Moss, Ian G.; Withers, Benjamin

2014-03-01

We consider the effect of inhomogeneities on the rate of false vacuum decay. Modelling the inhomogeneity by a black hole, we construct explicit Euclidean instantons which describe the nucleation of a bubble of true vacuum centred on the inhomogeneity. We find that inhomogeneity significantly enhances the nucleation rate over that of the Coleman-de Luccia instanton — the black hole acts as a nucleation site for the bubble. The effect is larger than previously believed due to the contributions to the action from conical singularities. For a sufficiently low initial mass, the original black hole is replaced by flat space during this process, as viewed by a single causal patch observer. Increasing the initial mass, we find a critical value above which a black hole remnant survives the process. This resulting black hole can have a higher mass than the original black hole, but always has a lower entropy. We compare the process to bubble-to-bubble transitions, where there is a semi-classical Lorentzian description in the WKB approximation.