Science.gov

Sample records for material process quarterly

  1. Properties and processing of nanocrystalline materials. Quarterly report

    SciTech Connect

    Valiev, R.Z.

    1996-01-22

    The present Report completes the investigations in the frame of the project for the first year. It is important to estimate our achievements in the investigation of properties of nanocrystalline materials obtained by severe plastic deformation and their production. We think that the main results obtained can be summarized as follows: (1) We performed an improvement of the die-set for equal channel (ECA) pressing and torsion under high pressure with the aim to increase dimensions of the samples produced and to conduct processing of low ductile materials. (2) It was established that in pure metals severe plastic deformation led to the formation of an ultra fine-grained structure with a mean grain size of 100-200 nm, while in alloys due to severe plastic deformation and/or special methods of treatment (a decrease in the temperature of deformation, an increase of the pressure applied etc.) the grain size could be decreased down to a few tens of manometers.

  2. Process research on Semix Silicon Material (PROSSM). Quarterly report No. 5, December 1, 1981-February 28, 1982

    SciTech Connect

    Wohlgemuth, J H; Warfield, D B

    1982-01-01

    Emphasis was shifted from the development of a cost-effective process sequence to research designed to understand the mechanisms of photovoltaic conversion in semicrystalline silicon. With this change has gone a change of title from Module Experimental Process System Development Unit (MEPSDU) to Process Research of Semix Silicon Material (PROSSM). Efforts are now underway to prepare a revised program plan with emphasis on determining the mechanisms limiting voltage and current collection in the semicrystalline silicon. The efforts reported concern work done before the change in emphasis and so the continued development of the cost-effective process sequence is reported. A cost-effective process sequence was identified, equipment was designed to implement a 6.6 MW per year automated production line, and a cost analysis projected a $0.56 per watt cell add-on cost for this line. Four process steps were developed for this program: glass bead back clean-up; hot spray antireflective coating; wave-soldering of fronts; ion milling for edging. While spray dopants were advertised as an off the shelf developed product, they proved to be unreliable with shorter than advertised shelf life. Equipment for handling and processing solar cells is available for all of the cell processing steps identified in this program. During this quarter efforts included work on spray dopant, edging, AR coating, wave soldering and fluxing, ion milling and cost analysis.

  3. Silicon dendritic web material process development. First quarterly report, March 28-June 30, 1980

    SciTech Connect

    Campbell, R. B.; Stapleton, R. E.; Sienkiewicz, L.; Rai-Choudhury, P.

    1980-01-01

    Initial values of pressure, power, and speed have been determined for seam bonding interconnects to dendritic web solar cells. Satisfactory bond strengths and high yield have been achieved without cell damage. However, in case of processing large numbers of cells for module fabrication, further testing is required to assure reproducibility of this technique. Various techniques have been developed for fabricating solar modules by lamination using ethylene vinyl acetate with a glass superstrate, and no cell breakage has been noted.

  4. Process feasibility study in support of silicon material Task I. Quarterly technical progress report (XIX), March 1-May 31, 1980

    SciTech Connect

    Yaws, C.L.; Li, K.Y.

    1980-06-01

    Analyses of process system properties were continued for chemical materials important in the production of silicon. Major physical, thermodynamic and transport property data are reported for silicon including critical constants, vapor pressure, heat of vaporization, heat of sublimation, heat capacity, density, surface tension, viscosity and thermal conductivity. The property data covers both liquid and solid phases and are reported as a function of temperature for rapid engineering usage. Major efforts in chemical engineering analysis centered on the HSC process (Hemlock Semiconductor Corporation). The approach for the process involves performing initial analysis for DCS production (dichlorosilane) and then perorming analysis of polysilicon production from the DCS. For the DCS production, status and progress are reported for primary activities of base case conditions (65%), reaction chemistry (65%), process flowsheet (60%), material balance (50%) and energy balance (40%). Two key features - redistribution reactor relocation and final distillation - are introduced to increase yield of DCS by about 10 to 20%, help insure purity and reduce potential dust (fine particle nucleation) components in the polysilicon feed material. The preliminary flowsheet for DCS production was forwarded to Hemlock Semiconductor Corporation for initial screening and review. Hemlock Semiconductor is in agreement in regards to relocation of the redistribution reactor to increase yield. Additional follow-up review is in progress including boron removal options identified by Hemlock Semiconductor. 166 references.

  5. Investigation of test methods material properties, and processes for solar cell encapsulants. Fifteenth quarterly progress report, November 12, 1979-February 12, 1980

    SciTech Connect

    Willis, P. B.; Baum, B.

    1980-03-01

    The goal of this program is to identify, evaluate, and recommend encapsulant materials and processes for the production of cost-effective, long-life solar cell modules. Work performed during this quarter included the development of anti-blocking treatments for EVA sheet intended for use as a lamination pottant. Initial evaluation studies were begun on a new pottant compound, polybutyl acrylate, to assess its preparation and handling characteristics. Corrosion studies using a standard salt spray test wre conducted to determine the degree of protection afforded to a number of metals when encapsulated in candidate pottant compounds. Pottants and outer cover candidates were exposed to intervals of accelerated uv stress aging using the RS/4 fluorescent sunlamp. Results are discussed. (WHK)

  6. Investigation of test methods, material properties, and processes for solar cell encapsulants. Eighteenth quarterly progress report, August 12-November 12, 1980

    SciTech Connect

    Willis, P. B.; Baum, B.; Davis, M.

    1980-12-01

    The goal of this program is to identify, evaluate, and recommend encapsulant materials and processes for the production of cost-effective, long-life solar cell modules. A survey was made of elastomers for use as gaskets for the photovoltaic module. Of the wide variety of materials examined EPDM offered the optimum combination of low compression set and low cost. The preference for EPDM is borne out by its long history of use as an automobile gasket. The commercial availability of materials that would be useful for sealants between the edge of the module and the gasket was investigated. Butyl sealants have the best combination of physical properties, low cost and a well-documented history of performance. A preferred composition has not yet been identified. One laminating type pottant ethylene/methyl acrylate copolymer (EMA), and two casting polymers, polybutyl acrylate and polyurethane, have been under investigation this past quarter. An EMA formulation has been developed which is easily extrudable and cures to a high gel content. So far only one commercial US source (Quinn) of aliphatic polyurethane has been located. Work is continuing to improve reaction rate as well as to eliminate source(s) of bubble formation during module fabrication. Considerable effort was spent in developing an improved polybutyl acrylate casting formulation providing high gel. Many viable curing systems are now available: however, the best formulation considering physical properties, freedom from bubbles as well as cure time utilizes Lupersol II (aliphatic peroxide) initiator. This initiator gives the desired gel after 20 minute cure at 45/sup 0/C or 12 minute cure at 55/sup 0/C.

  7. Field demonstration of the conventional steam-drive process with ancillary materials. Quarterly report No. 1, October 1, 1979-December 31, 1979

    SciTech Connect

    Not Available

    1980-01-10

    The objective of this contract is to field test the potential of chemical blocking foams to increase the efficiency of steam drive operations, particularly in shallow, heavy oil reservoirs. The initial work under the contract has consisted of laboratory work to test foaming materials. The state-of-the art was surveyed through a review of current work and through meetings held with university and industry laboratories. Discussed was equipment, data, and agents in the generation and evaluation of foams. Testing during the first quarter was conducted at room temperature and atmospheric pressure to screen the foaming agent. These tests were conducted in distilled water, saline water, and water with crude oil added, as described in detail in the appendix. The preliminary results, also included in the appendix, indicate that several chemicals appear promising.

  8. Investigation of test methods, material properties, and processes for solar-cell encapsulants. Twenty-third quarterly progress report for period ending February 12, 1982

    SciTech Connect

    Willis, P.B.; Baum, B.

    1982-04-01

    During the past quarter technical investigations concerned the development of advanced cure chemistries for lamination type pottants, the continued evaluation of soil resistant surface treatments, and the results of an accelerated aging test program for the comparison of material stabilities. New compounds were evaluated for efficiency in curing both ethylene/vinyl acetate and ethylene/methyl acrylate pottants. One compound in particular, designated Lupersol - TBEC was found to be unusually effective in promoting the rapid cure of both these materials. Formulation of these resins with TBEC resulted in compositions of very high gel content, lower temperatures of activation, and much lower cure times, even in the ethylene/methyl acrylate polymer that is more difficult to cure. An experimental program continued to determine the effectiveness of soil resistant coatings. These treatments have been applied to Sunadex glass, Tedlar and oriented acrylic film. The treatments are based on silicone, acrylic, and fluorosilane chemistries. After one year of outdoor exposure, the most effective treatment of Sunadex glass appears to be a fluorosilane designated L-1668, and for both the organic films a silane modified adduct of perfluoric acid gave the best results. After one year of time there is evidence that the treatments are slowly being lost and consequently a maintenance schedule may be required to maintain effectiveness over long periods of time. An accelerated aging test program is underway for the dual purpose of generating practical and empirical data relating to the service life of candidate encapsulation materials, and to provide data that may be useful in a predictive type of analysis.

  9. Nuclear materials stabilization and packaging. Quarterly status report, January 1--March 31, 1996

    SciTech Connect

    Haschke, J.M.; Horrell, D.R.; Hoth, C.W.; Fife, K.W.; Nielsen, J.B.; Pierce, S.W.; Ricketts, T.E.; Rink, N.A.; Robinson, M.A.

    1996-08-01

    This report documents progress on the Los Alamos Nuclear Materials Stabilization and Packaging projects for the second quarter of FY 1996. It covers development and production activities for the Plutonium Packaging Project, the Plutonium Recovery and Processing Project, and the Uranium Recovery and Processing Project. In addition, it reports on quality assurance activities for the Plutonium Packaging Project.

  10. Investigation of test methods, material properties, and processes for solar-cell encapsulants. Twenty-first quarterly progress report for period ending August 12, 1981

    SciTech Connect

    Willis, P.B.; Baum, B.

    1981-10-01

    During this quarter research work continued on the evaluation of soil resistant surface treatments, the investigation of corrosion protecting coatings for mild steel substrates, the identification of primers for bonding module interfaces, and the continuation of RS/4 accelerated aging of candidate encapsulation compounds.

  11. Investigation of test methods, material properties, and processes for solar cell encapsulants. Seventeenth quarterly progress report, May 12-August 12, 1980

    SciTech Connect

    Willis, P. B.; Baum, B.

    1980-09-01

    The goal of this program is to identify, evaluate, and recommend encapsulant materials and processes for the production of cost-effective, long-life solar cell modules. Development efforts have emphasized the reformulation of polybutyl acrylate, a liquid pottant used in the casting encapsulation process. This material has been modified to yield a composition with much faster cure at lower temperatures. Minimodules have been successfully prepared from this low cost compound and are currently being evaluated by thermal/humidity cycling. Differential thermal analysis (DTA) was used for the examination of thermal stability in some of the pottant compounds of current interest. This method was useful in determining the temperatures at which oxidative or pyrolysis reactions resulted in degradation of the polymers. All the candidate pottants showed degradation onsets of over 200/sup 0/C. The effectiveness of a new primer was determined during this period. This formulation was similar to the silane coupling agent used in past experimentation but was modified with a peroxide to enhance the activity. Excellent bound strengths were obtained to glass, and mild steel that were resistant to immersion in boiling water. EVA to low iron glass gave an average bond strength of 35 lbs per inch of width. This new primer was also evaluated for the corrosion protection that could be provided to metal surfaces when primed and encapsulated in EVA. (WHK)

  12. Mechanics/heat-transfer relation for particulate materials. [Quarterly report

    SciTech Connect

    Campbell, C.S.

    1991-07-01

    The major emphasis this quarter has been in two areas. The first is to continue working the bugs out of the new particle pressure transducer. The second was to try and measure the particle pressures generated in a bed of FCC catalyst that is undergoing particulate fluidization. The results indicate that the stabilization of fluidized beds in that regime cannot be explained in terms of particle pressure generation. Instead, consistent with other recent observations,the observations can be explained by a material is that not completely fluidized but, instead, retains much of the properties of a solid and, in particular, can transmit particle pressure like a solid. 2 figs.

  13. A Novel Approach to Material Development for Advanced Reactor Systems. Quarterly progress report, Year 1 - Quarter 2

    SciTech Connect

    2000-03-27

    OAK B188 A Novel Approach to Material Development for Advanced Reactor Systems. Quarterly progress report, Year 1--Quarter 2. Year one of this project had three major goals. First, to specify, order and install a new high current ion source for more rapid and stable proton irradiation. Second, to assess the use low temperature irradiation and chromium pre-enrichment in an effort to isolate a radiation damage microstructure in stainless steels without the effects of RIS. Third, to prepare for the irradiation of reactor pressure vessel steel and Zircaloy. Program goals for Second Quarter, Year One: In year 1 quarter 2, the project goal was to complete an irradiation of an RPV steel sample and begin sample characterization. We also planned to identify sources of Zircaloy for irradiation and characterization.

  14. Investigations of test methods, material properties, and processes, for solar-cell encapsulants. Twenty-second quarterly progress report for period ending November 12, 1982

    SciTech Connect

    Not Available

    1982-01-01

    Investigations were continued into pottants, soil resistant coatings and low cost substrate materials. Two component aliphatic urethane casting syrups for use as solar module pottants were evaluated for suitability on the basis of optical, physical and fabrication characteristics. One formulation was selected as being acceptable for industrial evaluation. This urethane is characterized by high transparency, low mix viscosity, fast cure time and surprising lack of moisture sensitivity that has given trouble with previous urethane compositions. This material is produced with an ultraviolet stabilizer system already blended in. An experimental program was continued to determine the effectiveness of soil resistant coatings. These treatments have been applied to Sunadex glass, Tedlar and oriented acrylic film. The treatments are based on silicone, acrylic and fluorosilane chemistries. Test specimens are being exposed to outdoor soiling conditions with subsequent testing for short circuit-current loss using a standard cell device. After nine months of outdoor exposure, the most effective treatment appears to be a silane modified adduct of perfluorodecanoic acid. The degree of soiling also appears to correlate to the amount of rainfall that results in a natural cleaning of the surface. Wood products, such as hardboard, are potentially the lowest cost candidate substrates identified to date. The difficulty with the use of these materials lies in the very high hygroscopic expansion coefficients. Periods of dryout followed by subsequent moisture regain results in large expansions and contractions that result in cell fracture. Experiments were conducted to determine the effectiveness of occlusive coatings to prevent this effect. Both metal foils and organic films bonded to the hardboard with appropriate adhesives were found to dramatically decrease the hygroscopic response and lower the expansion coefficient by four orders of magnitude.

  15. Coal liquefaction process research quarterly report, October-December 1979

    SciTech Connect

    Bickel, T.C.; Curlee, R.M.; Granoff, B.; Stohl, F.V.; Thomas, M.G.

    1980-03-01

    This quarterly report summarizes the activities of Sandia's continuing program in coal liquefaction process research. The overall objectives are to: (1) provide a fundamental understanding of the chemistry of coal liquefaction; (2) determine the role of catalysts in coal liquefaction; and (3) determine the mechanism(s) of catalyst deactivation. The program is composed of three major projects: short-contact-time coal liquefaction, mineral effects, and catalyst studies. These projects are interdependent and overlap significantly.

  16. A characterization and evaluation of coal liquefaction process streams. Quarterly report, April 1--June 30, 1997

    SciTech Connect

    Brandes, S.D.; Robbins, G.A.; Winschel, R.A.

    1997-12-31

    This is the Technical Progress Report for the twelfth quarter of activities. Described in this report are the following activities: (1) Thirty-nine samples from four run conditions of HTI Run PB-07 were received. Appropriate samples were characterized by proton NMR spectroscopy, Fourier transform infrared spectroscopy, vacuum distillation, and solvent quality tests. (2) The University of Delaware completed their subcontract this quarter. A meeting was held on April 30, 1997 at the University to close out the subcontract. (3) Twelve sets of samples were chosen from the CONSOL sample bank for the study of the insoluble and presumed unreactive material from process stream samples. Each set consists of the whole process stream and the 454 C{sup +} (850 F{sup +}) distillation resid derived from that process stream. Processing data for all samples were compiled. The samples represent four Wilsonville pilot plant runs and two HTI runs.

  17. Materials processing in space

    NASA Technical Reports Server (NTRS)

    1975-01-01

    The feasibility and possible advantages of processing materials in a nongravitational field are considered. Areas of investigation include biomedical applications, the processing of inorganic materials, and flight programs and funding.

  18. ARRA Material Handling Equipment Composite Data Products: Data through Quarter 2 of 2012

    SciTech Connect

    Kurtz, J.; Sprik, S.; Ramsden, T.; Ainscough, C.; Saur, G.

    2012-10-01

    This presentation from the U.S. Department of Energy's National Renewable Energy Laboratory includes American Recovery and Reinvestment Act (ARRA) fuel cell material handling equipment composite data products for data through the second quarter of 2012.

  19. ARRA Material Handling Equipment Composite Data Products: Data Through Quarter 4 of 2012

    SciTech Connect

    Kurtz, J.; Sprik, S.; Ainscough, C.; Saur, G.; Post, M.; Peters, M.; Ramsden, T.

    2013-05-01

    This presentation from the U.S. Department of Energy's National Renewable Energy Laboratory includes American Recovery and Reinvestment Act (ARRA) fuel cell material handling equipment composite data products for data through the fourth quarter of 2012.

  20. Materials processing in space

    NASA Technical Reports Server (NTRS)

    Waldron, R. D.; Criswell, D. R.

    1982-01-01

    Processing-refining of raw materials from extraterrestrial sources is detailed for a space materials handling facility. The discussion is constrained to those steps necessary to separate desired components from raw or altered input ores, semi-purified feedstocks, or process scrap and convert the material into elements, alloys, and consumables. The materials are regarded as originating from dead satellites and boosters, lunar materials, and asteroids. Strong attention will be given to recycling reagent substances to avoid the necessity of transporting replacements. It is assumed that since no aqueous processes exist on the moon, the distribution of minerals will be homogeneous. The processing-refining scenario will include hydrochemical, pyrochemical, electrochemical, and physical techniques selected for the output mass rate/unit plant mass ratio. Flow charts of the various materials processing operations which could be performed with lunar materials are provided, noting the necessity of delivering several alloying elements from the earth due to scarcities on the moon.

  1. Quarterly Report: Microchannel-Assisted Nanomaterial Deposition Technology for Photovoltaic Material Production

    SciTech Connect

    Palo, Daniel R.

    2011-04-26

    Quarterly report to ITP for Nanomanufacturing program. Report covers FY11 Q2. The primary objective of this project is to develop a nanomanufacturing process which will reduce the manufacturing energy, environmental discharge, and production cost associated with current nano-scale thin-film photovoltaic (PV) manufacturing approaches. The secondary objective is to use a derivative of this nanomanufacturing process to enable greener, more efficient manufacturing of higher efficiency quantum dot-based photovoltaic cells now under development. The work is to develop and demonstrate a scalable (pilot) microreactor-assisted nanomaterial processing platform for the production, purification, functionalization, and solution deposition of nanomaterials for photovoltaic applications. The high level task duration is shown. Phase I consists of a pilot platform for Gen II PV films along with parallel efforts aimed at Gen III PV quantum dot materials. Status of each task is described.

  2. Quiet Quincy Quarter. Teacher's Guide [and] Student Materials.

    ERIC Educational Resources Information Center

    Zishka, Phyllis

    This document suggests learning activities, teaching methods, objectives, and evaluation measures for a second grade consumer education unit on quarters. The unit, which requires approximately six hours of class time, reinforces basic social studies and mathematics skills including following sequences of numbers, distinguishing left from right,…

  3. A Novel Approach to Materials Development for Advanced Reactor Systems - Quarterly Progress Report: Year 2; Quarter 1

    SciTech Connect

    G. S. Was; M. Atzmon; L. Wang

    2002-06-25

    OAK B188 A Novel Approach to Materials Development for Advanced Reactor Systems - Quarterly Progress Report: Year 2; Quarter 1. There are three major goals for year two of the program. First, to build on the successful initial experiments on proton irradiation of pressure vessel steel to expand the irradiations to study dose rate and temperature effects, radiation effects on commercial alloys and to better characterize the precipitates. Second, we will begin irradiation and characterization of the Zircaloy alloys. Finally, we will continue low temperature irradiations and begin irradiation of chromium pre-enriched samples and cold-worked samples to assess the role of microstructure in IASCC of austenitic stainless steels. In quarter 1 of year 2, the project goal was to complete irradiation of model alloys of RPV steels for a range of doses and an initial sample characterization. We also planned to begin characterization of Zircalloy alloy samples and to make a set of cold-worked samples of 304 SS that would have a fixed hardness following subsequent irradiation to different doses.

  4. Femtosecond laser materials processing

    SciTech Connect

    Stuart, B. C., LLNL

    1998-06-02

    Femtosecond lasers enable materials processing of most any material with extremely high precision and negligible shock or thermal loading to the surrounding area Applications ranging from drilling teeth to cutting explosives to making high-aspect ratio cuts in metals with no heat-affected zone are made possible by this technology For material removal at reasonable rates, we developed a fully computer-controlled 15-Watt average power, 100-fs laser machining system.

  5. Femtosecond laser materials processing

    SciTech Connect

    Stuart, B

    1998-08-05

    Femtosecond lasers enable materials processing of most any material with extremely high precision and negligible shock or thermal loading to the surrounding area. Applications ranging from drilling teeth to cutting explosives to precision cuts in composites are possible by using this technology. For material removal at reasonable rates, we have developed a fully computer-controlled 15-Watt average power, 100-fs laser machining system.

  6. Extraterrestrial materials processing

    NASA Technical Reports Server (NTRS)

    Steurer, W. H.

    1982-01-01

    The first year results of a multi-year study of processing extraterrestrial materials for use in space are summarized. Theoretically, there are potential major advantages to be derived from the use of such materials for future space endeavors. The types of known or postulated starting raw materials are described including silicate-rich mixed oxides on the Moon, some asteroids and Mars; free metals in some asteroids and in small quantities in the lunar soil; and probably volatiles like water and CO2 on Mars and some asteroids. Candidate processes for space materials are likely to be significantly different from their terrestrial counterparts largely because of: absence of atmosphere; lack of of readily available working fluids; low- or micro-gravity; no carbon-based fuels; readily available solar energy; and severe constraints on manned intervention. The extraction of metals and oxygen from lunar material by magma electrolysis or by vapor/ion phase separation appears practical.

  7. Ultrasonic Processing of Materials

    SciTech Connect

    Meek, Thomas T.; Han, Qingyou; Jian, Xiaogang; Xu, Hanbing

    2005-06-30

    The purpose of this project was to determine the impact of a new breakthrough technology, ultrasonic processing, on various industries, including steel, aluminum, metal casting, and forging. The specific goals of the project were to evaluate core principles and establish quantitative bases for the ultrasonc processing of materials, and to demonstrate key applications in the areas of grain refinement of alloys during solidification and degassing of alloy melts. This study focussed on two classes of materials - aluminum alloys and steels - and demonstrated the application of ultrasonic processing during ingot casting.

  8. 78 FR 34370 - Revisions to Electric Quarterly Report Filing Process; Notice of Availability of Video Showing...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-06-07

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Federal Energy Regulatory Commission Revisions to Electric Quarterly Report Filing Process; Notice of Availability of Video Showing How To File Electric Quarterly Reports Using the Web Interface Take notice that the Federal Energy Regulatory Commission...

  9. Superconducting materials processing

    NASA Technical Reports Server (NTRS)

    Hurley, John S.; Karikari, Emmanuel K.; Hiamang, S. O.; Danjaji, M.; Bassey, Affiong; Morgan, Andre

    1995-01-01

    The effects of materials processing on the properties and behavior of high temperature yttrium barium copper oxide (YBCO) superconductors were investigated. Electrical, magnetic, and structural characteristics of thin films (300 nm) YBA2CU3O(delta) structures grown by pulsed laser deposition on LaAlO3 and SrTiO3 substrates were used to evaluate processing. Pole projection and thin film diffraction measurements were used to establish grain orientation and verify structural integrity of the samples. Susceptibility magnetization, and transport measurements were used to evaluate the magnetic and electrical transport properties of the samples. Our results verified that an unfortunate consequence of processing is inherent changes to the internal structure of the material. This effect translates into modifications in the properties of the materials, and undesired feature that makes it very difficult to consistently predict material behavior. The results show that processing evaluation must incorporate a comprehensive understanding of the properties of the materials. Future studies will emphasize microstructural characteristics of the materials, in particular, those microscopic properties that map macroscopic behavior.

  10. Lasers in materials processing

    SciTech Connect

    Davis, J.I.; Rockower, E.B.

    1981-01-01

    A status report on the uranium Laser Isotope Separation (LIS) Program at the Lawrence Livermore National Laboratory is presented. Prior to this status report, process economic analysis is presented so as to understand how the unique properties of laser photons can be best utilized in the production of materials and components despite the high cost of laser energy. The characteristics of potential applications that are necessary for success are identified, and those factors that have up to now frustrated attempts to find commercially viable laser induced chemical and physical process for the production of new or existing materials are pointed out.

  11. Ultrasonic Processing of Materials

    NASA Astrophysics Data System (ADS)

    Han, Qingyou

    2015-08-01

    Irradiation of high-energy ultrasonic vibration in metals and alloys generates oscillating strain and stress fields in solids, and introduces nonlinear effects such as cavitation, acoustic streaming, and radiation pressure in molten materials. These nonlinear effects can be utilized to assist conventional material processing processes. This article describes recent research at Oak Ridge National Labs and Purdue University on using high-intensity ultrasonic vibrations for degassing molten aluminum, processing particulate-reinforced metal matrix composites, refining metals and alloys during solidification process and welding, and producing bulk nanostructures in solid metals and alloys. Research results suggest that high-intensity ultrasonic vibration is capable of degassing and dispersing small particles in molten alloys, reducing grain size during alloy solidification, and inducing nanostructures in solid metals.

  12. Femtosecond laser materials processing

    SciTech Connect

    Stuart, B.C.

    1997-02-01

    The use femtosecond pulses for materials processing results in very precise cutting and drilling with high efficiency. Energy deposited in the electrons is not coupled into the bulk during the pulse, resulting in negligible shock or thermal loading to adjacent areas.

  13. Laser material processing system

    DOEpatents

    Dantus, Marcos

    2015-04-28

    A laser material processing system and method are provided. A further aspect of the present invention employs a laser for micromachining. In another aspect of the present invention, the system uses a hollow waveguide. In another aspect of the present invention, a laser beam pulse is given broad bandwidth for workpiece modification.

  14. Processing Materials in Space

    NASA Technical Reports Server (NTRS)

    Zoller, L. K.

    1982-01-01

    Suggested program of material processing experiments in space described in 81 page report. For each experiment, report discusses influence of such gravitational effects as convection, buoyancy, sedimentation, and hydrostatic pressure. Report contains estimates of power and mission duration required for each experiment. Lists necessary equipment and appropriate spacecraft.

  15. Materials and Processes Technology.

    ERIC Educational Resources Information Center

    Ritz, John M.; And Others

    This instructional resource guide is intended to assist the industrial arts (IA) teacher in implementing a comprehensive materials and Processes Technology program at the technical level in Virginia high schools. The course is designed to help students make informed educational and occupational choices and prepare them for advanced technical or…

  16. AR and TD Fossil Energy Materials Program. Quarterly progress report for the period ending December 31, 1981

    SciTech Connect

    Not Available

    1982-04-01

    The ORNL Fossil Energy Materials Program Office compiles and issues this combined quarterly progress report from camera-ready copies submitted by each of the participating subcontractor organizations. This report of activities on the program is organized in accordance with a work breakdown structure defined in the AR and TD Fossil Energy Materials Program Plan for FY 1982-1986 in which projects are organized according to fossil energy technologies. This report is divided into parts and chapters with each part describing projects related to a particular fossil energy technology. Chapters within a part provide details of the various projects associated with that technology. We hope this series of AR and TD Fossil Energy Materials Program quarterly progress reports will aid in the dissemination of information developed on the program. Plans for the program will be issued annually. A draft of the program plan for FY 1982 to 1986 has been prepared and is in the review process. The implementation of these plans will be reflected by these quarterly progress reports, and this dissemination of information will bw augmented by topical or final reports as appropriate.

  17. Solvent refined coal (SRC) process. Quarterly technical progress report, January 1980-March 1980. [In process streams

    SciTech Connect

    Not Available

    1981-01-01

    This report summarizes the progress of the Solvent Refined Coal (SRC) project at the SRC Pilot Plant in Fort Lewis, Wahsington, and the Process Development Unit (P-99) in Harmarville, Pennsylvania. After the remaining runs of the slurry preheater survey test program were completed January 14, the Fort Lewis Pilot Plant was shut down to inspect Slurry Preheater B and to insulate the coil for future testing at higher rates of heat flux. Radiographic inspection of the coil showed that the welds at the pressure taps and the immersion thermowells did not meet design specifications. Slurry Preheater A was used during the first 12 days of February while weld repairs and modifications to Slurry Preheater B were completed. Two attempts to complete a material balance run on Powhatan No. 6 Mine coal were attempted but neither was successful. Slurry Preheater B was in service the remainder of the quarter. The start of a series of runs at higher heat flux was delayed because of plugging in both the slurry and the hydrogen flow metering systems. Three baseline runs and three slurry runs of the high heat flux program were completed before the plant was shut down March 12 for repair of the Inert Gas Unit. Attempts to complete a fourth slurry run at high heat flux were unsuccessful because of problems with the coal feed handling and the vortex mix systems. Process Development Unit (P-99) completed three of the four runs designed to study the effect of dissolver L/D ratio. The fourth was under way at the end of the period. SRC yield correlations have been developed that include coal properties as independent variables. A preliminary ranking of coals according to their reactivity in PDU P-99 has been made. Techniques for studying coking phenomenona are now in place.

  18. Quarterly report: Pumps-status of slurry pumps in coal liquefaction processes. Third quarter - CY 1981

    SciTech Connect

    1996-07-01

    This paper summarizes recent slurry pumps (centrifugal and reciprocal) operating experience in the liquefaction pilot plants. In addition, the activities concerning slurry pumps conducted in supporting research facilities are also noted. The purpose of the summary is to concentrate on the critical component problems common to all the liquefaction plants to avoid duplication of efforts, and to help provide timely solutions to the pump problems. The summary information used in this paper was obtained primarily from the Critical Component and Materials Meetings which are sponsored by the Office of Coal Processing of the Fossil Energy. The Department of Energy. Information from various Technical Reports published by the liquefaction plant personnel are also reviewed based on availability and relevance to topics covered in this report. It is intended that this report will be followed by updates as pertinent information concerning problem pumps becomes available. The following section s of the paper will provide a brief outline of early slurry pump experience as background material followed by a summary of recent slurry pump operating experience at liquefaction pilot plants.

  19. Lunar materials and processes

    NASA Technical Reports Server (NTRS)

    Burke, J. D.

    1986-01-01

    The paper surveys current information, describes some important unknowns about lunar materials, and discusses ways to gain more scientific and engineering knowledge concerning the industrial processes that could be used on the moon for the production of products useful in future enterprises in space. Lunar rocks and soils are rich in oxygen, but it is mostly chemically bound in silicates, so that chemical or thermal energy must be supplied to recover it. Iron and titanium are abundant and, in some of their known forms, readily recoverable; aluminum is plentiful but harder to extract. Methods for recovering lunar oxygen and metals fall into three classes: chemical, electrolytic, and dissociative, broadly characterized by their respective process temperatures. Examples of these methods are briefly discussed.

  20. Hazardous materials in aquatic environments of the Mississippi River Basin. Quarterly project status report, October 1, 1993--December 31, 1993

    SciTech Connect

    Not Available

    1993-12-31

    This quarterly project status report discusses research projects being conducted on hazardous materials in aquatic environments of the Mississippi River basin. We continued to seek improvement in our methods of communication and interactions to support the inter-disciplinary, inter-university collaborators within this program. In addition to the defined collaborative research teams, there is increasing interaction among investigators across projects. Planning for the second year of the project has included the development of our internal request for proposals, and refining the review process for selection of proposals for funding.

  1. Investigation of test methods, material properties, and processes for solar cell encapsulants. Encapsulation task of the Low-Cost Silicon Solar Array project. Thirteenth quarterly progress report, May 12, 1979-August 12, 1979

    SciTech Connect

    1980-01-01

    Springborn Laboratories is engaged in a study of evaluating potentially useful encapsulating materials for Task 3 of the Low-Cost Silicon Solar Array project (LSA) funded by DOE. The goal of this program is to identify, evaluate, and recommend encapsulant materials and processes for the product of cost-effective, long-life solar cell modules. Current technical activities are directed primarily towards the development of a solar module encapsulation technology that employs ethylene/vinyl acetate copolymer as the pottant. Due to the surface tack of EVA, a slip sheet of release paper is required between each layer to prevent the plies from adhering. Manufacturers were surveyed and a source for inexpensive release paper in roll form was identified. A survey of separator materials was also conducted. Corrosion studies using a standard salt spray test were used to determine the degree of protection offered to a variety of metals by encapsulation in EVA pottant. Due to the low surface hardness of EVA and the remaining sensitivity to ultraviolet light, outer covers are required to prevent soiling and improve the weatherability. Two candidate films (Korad 212 and Tedlar UT) have been identified for this function. These films are somewhat scratch and abrasion sensitive, however, and their useful life can be prolonged with the application of thin layers of abrasion resistant hard coats. A survey of manufacturers of these coatings was performed and the products compared. Field trials of outdoor performance must be performed to fully assess the durability of these coatings.

  2. Materials research for the clean utilization of coal. Quarterly progress report, April-June 1981

    SciTech Connect

    Not Available

    1981-01-01

    Effort this quarter has been concentrated on the book Construction Materials for Coal Conversion - Performance and Properties Data. The status of the various subsections of Section A (Materials Considerations and Performance Data) is: (1) Operating requirements - completed; (2) Performance Data and Candidate Materials - being drafted in final form. The assembling of test data for Section B is essentially complete and analysis of this data is in progress. Data was obtained on the creep of a fused cast ..cap alpha.. + ..beta.. alumina (Monofrax A) under thermal cycling conditions and on silicon nitride using both linear variable differential transformers and specimen dimension measurements.

  3. Chemical processing of lunar materials

    NASA Technical Reports Server (NTRS)

    Criswell, D. R.; Waldron, R. D.

    1979-01-01

    The paper highlights recent work on the general problem of processing lunar materials. The discussion covers lunar source materials, refined products, motivations for using lunar materials, and general considerations for a lunar or space processing plant. Attention is given to chemical processing through various techniques, including electrolysis of molten silicates, carbothermic/silicothermic reduction, carbo-chlorination process, NaOH basic-leach process, and HF acid-leach process. Several options for chemical processing of lunar materials are well within the state of the art of applied chemistry and chemical engineering to begin development based on the extensive knowledge of lunar materials.

  4. The materials processing research base of the Materials Processing Center

    NASA Technical Reports Server (NTRS)

    Flemings, M. C.; Bowen, H. K.; Kenney, G. B.

    1980-01-01

    The goals and activities of the center are discussed. The center activities encompass all engineering materials including metals, ceramics, polymers, electronic materials, composites, superconductors, and thin films. Processes include crystallization, solidification, nucleation, and polymer synthesis.

  5. Low-cost-silicon-process development. Phase IV: process improvement. Second quarterly technical progress report

    SciTech Connect

    Giraudi, R. V.; Newman, C. G.

    1981-04-01

    A number of promising techniques for improving the overall yield and economics of the tribromosilane based process to produce solar cell grade silicon is investigated. The current work is aimed at the identification of an optimum process and the characterization of that process through mini-plant operation and analysis. The three project tasks include process improvement studies, kinetic studies, and process economic studies. During this second quarter reporting period process improvement studies continued in the mini-plant, focusing on the correlation of current mini-plant yield results with prior laboratory scale work. Silicon bromination in the synthesis unit and tribromosilane purification in the distillation unit proceeded efficiently and without complication during this reporting period. Tribromosilane yields in the synthesis unit were low due to unobtainable higher reaction temperatures. Initial polycrystalline silicon production studies have indicated consistent yields of 85%. The laboratory scale static bulb reactor system was calibrated by observing the decomposition of t-butyl chloride. These results compared very well to results obtained by previous investigators for the same decomposition. Upon the conclusion of the calibration tests, the tribromosilane decomposition rate study was initiated. Two decompositions were completed and it was concluded that the reaction order can not be determined at this time. A free space reactor apparatus was assembled and tribromosilane decompositions, as a function of dilution in argon, was studied.

  6. 78 FR 53452 - Revisions to Electric Quarterly Report Filing Process; Notice of Extended Availability of Sandbox...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-08-29

    ... Quarterly Report Filing Process, Order No. 770, 77 FR 71288 (Nov. 30, 2012), FERC Stats. & Regs. ] 31,338... Availability of Sandbox Electronic Test Site Take notice that the opportunity to use the Sandbox Electronic... while the sandbox is available. Staff invites users to email comments and questions concerning the...

  7. Processing composite materials

    NASA Technical Reports Server (NTRS)

    Baucom, R. M.

    1982-01-01

    The fabrication of several composite structural articles including DC-10 upper aft rudders, L-1011 vertical fins and composite biomedical appliances are discussed. Innovative composite processing methods are included.

  8. Enforcement actions: Significant actions resolved material licensees. Quarterly progress report, April 1995--June 1995

    SciTech Connect

    1995-08-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (April-June 1995) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to material licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication.

  9. Advanced composite materials and processes

    NASA Technical Reports Server (NTRS)

    Baucom, Robert M.

    1991-01-01

    Composites are generally defined as two or more individual materials, which, when combined into a single material system, results in improved physical and/or mechanical properties. The freedom of choice of the starting components for composites allows the generation of materials that can be specifically tailored to meet a variety of applications. Advanced composites are described as a combination of high strength fibers and high performance polymer matrix materials. These advanced materials are required to permit future aircraft and spacecraft to perform in extended environments. Advanced composite precursor materials, processes for conversion of these materials to structures, and selected applications for composites are reviewed.

  10. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, April 1--June 30, 1992

    SciTech Connect

    Brandes, S.D.; Lancet, M.S.; Robbins, G.A.; Winschel, R.A.; Burke, F.P.

    1992-11-01

    This is the eleventh Quarterly Technical Progress Report under DOE Contract DE-AC22-89PC89883. Major topics reported are: (1) The results of a study designed to determine the effects of the conditions employed at the Wilsonville slurry preheater vessel on coal conversion is described. (2) Stable carbon isotope ratios were determined and used to source the carbon of three product samples from Period 49 of UOP bench-scale coprocessing Run 37. The results from this coprocessing run agree with the general trends observed in other coprocessing runs that we have studied. (3) Microautoclave tests and chemical analyses were performed to ``calibrate`` the reactivity of the standard coal used for determining donor solvent quality of process oils in this contract. (4) Several aspects of Wilsonville Close-Coupled Integrated Two-Stage Liquefaction (CC-ITSL) resid conversion kinetics were investigated; results are presented. Error limits associated with calculations of deactivation rate constants previously reported for Runs 258 and 261 are revised and discussed. A new procedure is described that relates the conversions of 850{degrees}F{sup +} , 1050{degrees}F{sup +}, and 850 {times} 1050{degrees}F material. Resid conversions and kinetic constants previously reported for Run 260 were incorrect; corrected data and discussion are found in Appendix I of this report.

  11. Telerobotic electronic materials processing experiment

    NASA Technical Reports Server (NTRS)

    Ollendorf, Stanford

    1991-01-01

    The Office of Commercial Programs (OCP), working in conjunction with NASA engineers at the Goddard Space Flight Center, is supporting research efforts in robot technology and microelectronics materials processing that will provide many spinoffs for science and industry. The Telerobotic Materials Processing Experiment (TRMPX) is a Shuttle-launched materials processing test payload using a Get Away Special can. The objectives of the project are to define, develop, and demonstrate an automated materials processing capability under realistic flight conditions. TRMPX will provide the capability to test the production processes that are dependent on microgravity. The processes proposed for testing include the annealing of amorphous silicon to increase grain size for more efficient solar cells, thin film deposition to demonstrate the potential of fabricating solar cells in orbit, and the annealing of radiation damaged solar cells.

  12. Silicon materials task of the low cost solar array project (Phase III). Effects of impurities and processing on silicon solar cells. Phase III summary and seventeenth quarterly report, Volume 2: analysis of impurity behavior

    SciTech Connect

    Hopkins, R.H.; Davis, J.R.; Rohatgi, A.; Campbell, R.B.; Blais, P.D.; Rai-Choudhury, P.; Stapleton, R.E.; Mollenkopf, H.C.; McCormick, J.R.

    1980-01-23

    The object of this phase of the program has been to investigate the effects of various processes, metal contaminants and contaminant-process interactions on the properties of silicon and on the performance of terrestrial silicon solar cells. The study encompassed topics including thermochemical (gettering) treatments, base doping concentration, base doping type (n vs. p), grain boundary-impurity interaction, non-uniformity of impurity distribution, long term effects of impurities, as well as synergic and complexing phenomena. The program approach consists in: (1) the growth of doubly and multiply-doped silicon single crystals containing a baseline boron or phosphorus dopant and specific impurities which produce deep levels in the forbidden band gap; (2) assessment of these crystals by chemical, microstructural, electrical and solar cell tests; (3) correlation of the impurity type and concentration with crystal quality and device performance; and (4) delineation of the role of impurities and processing on subsequent silicon solar cell performance. The overall results reported are based on the assessment of nearly 200 silicon ingots. (WHK)

  13. PROCESS OF FORMING POWDERED MATERIAL

    DOEpatents

    Glatter, J.; Schaner, B.E.

    1961-07-14

    A process of forming high-density compacts of a powdered ceramic material is described by agglomerating the powdered ceramic material with a heat- decompossble binder, adding a heat-decompossble lubricant to the agglomerated material, placing a quantity of the material into a die cavity, pressing the material to form a compact, pretreating the compacts in a nonoxidizing atmosphere to remove the binder and lubricant, and sintering the compacts. When this process is used for making nuclear reactor fuel elements, the ceramic material is an oxide powder of a fissionsble material and after forming, the compacts are placed in a cladding tube which is closed at its ends by vapor tight end caps, so that the sintered compacts are held in close contact with each other and with the interior wall of the cladding tube.

  14. Extraterrestrial materials processing and construction

    NASA Technical Reports Server (NTRS)

    Criswell, D. R.

    1978-01-01

    Applications of available terrestrial skills to the gathering of lunar materials and the processing of raw lunar materials into industrial feed stock were investigated. The literature on lunar soils and rocks was reviewed and the chemical processes by which major oxides and chemical elements can be extracted were identified. The gathering of lunar soil by means of excavation equipment was studied in terms of terrestrial experience with strip mining operations on earth. The application of electrostatic benefication techniques was examined for use on the moon to minimize the quantity of materials requiring surface transport and to optimize the stream of raw materials to be transported off the moon for subsequent industrial use.

  15. Compatibility of refrigerants and lubricants with motor materials. Quarterly technical progress report, April 1, 1992--June 30, 1992

    SciTech Connect

    Doerr, R.; Kujak, S.

    1992-07-23

    During this last quarter, evaluations were complete on the motor materials after 500-hr exposures to refrigerants CFC-123, HFC-134a and HCFC-22 at 90{degrees}C. Materials were also evaluated after exposure to nitrogen at 127{degrees}C to determine effect of the thermal exposure. Other exposures were started during this quarter with refrigerants HCFC-124, HFC-125, HFC-143a, HFC-32 and HFC-152a. One 500 hr exposure is set up per week and one is analyzed the same week. This will enable Trane to complete the 500 hour exposures by the end of the year.

  16. Processes for treating cellulosic material

    NASA Technical Reports Server (NTRS)

    Ladisch, Michael R. (Inventor); Kohlman, Karen L. (Inventor); Westgate, Paul L. (Inventor); Weil, Joseph R. (Inventor); Yang, Yiqi (Inventor)

    1998-01-01

    Disclosed are processes for pretreating cellulosic materials in liquid water by heating the materials in liquid water at a temperature at or above their glass transition temperature but not substantially exceeding 220.degree. C., while maintaining the pH of the reaction medium in a range that avoids substantial autohydrolysis of the cellulosic materials. Such pretreatments minimize chemical changes to the cellulose while leading to physical changes which substantially increase susceptibility to hydrolysis in the presence of cellulase.

  17. Microstructural processes in irradiated materials

    NASA Astrophysics Data System (ADS)

    Byun, Thak Sang; Morgan, Dane; Jiao, Zhijie; Almer, Jonathan; Brown, Donald

    2016-04-01

    These proceedings contain the papers presented at two symposia, the Microstructural Processes in Irradiated Materials (MPIM) and Characterization of Nuclear Reactor Materials and Components with Neutron and Synchrotron Radiation, held in the TMS 2015, 144th Annual Meeting & Exhibition at Walt Disney World, Orlando, Florida, USA on March 15-19, 2015.

  18. Energy Implications of Materials Processing

    ERIC Educational Resources Information Center

    Hayes, Earl T.

    1976-01-01

    Processing of materials could become energy-limited rather than resource-limited. Methods to extract metals, industrial minerals, and energy materials and convert them to useful states requires more than one-fifth of the United States energy budget. Energy accounting by industries must include a total systems analysis of costs to insure net energy…

  19. Development of biological coal gasification (MicGAS process). Nineth quarterly report, [July--September 1992

    SciTech Connect

    Not Available

    1992-10-30

    Laboratory scale studies examining biogasification of Texas lignite at various coal solids loadings have been completed. Bench scale bioreactors are currently being used to scale up the biogasification process to higher coal solids loadings (5% and 10%) Specific observations reported this quarter are that methane production was not curtailed when B-vitamin solution was not added to the biogasification medium and that aeration of Mic-1 did not sufficiently oxidize the medium to eliminate strict anaerobic bacteria including methanogens.

  20. CPT Word Processing Instructional Materials.

    ERIC Educational Resources Information Center

    Slaymaker, Josephine; Eakman, Donna

    A project to develop a student word processing manual was developed by using input from: (1) information specialists, employees, and educators; and (2) students using the manual. These instructional materials provide workbook assignments and reading for an individualized unit on CPT word processing to be used by 30 to 40 high school students per…

  1. Materials processing in low gravity

    NASA Technical Reports Server (NTRS)

    Workman, Gary L.

    1989-01-01

    Work is reported on the Materials Processing Low Gravity Program in which the University of Alabama worked with scientists and engineers at Marshall Space Flight Center to design, implement and perform low gravity experiments with various scientific investigators in materials processing science through March 15, 1989. The facilities used in these short duration low gravity experiments include the Drop Tube and Drop Tower at MSFC, and the KC-135 aircraft at Ellington Field. The utilization of these ground-based low gravity facilities for materials processing was instrumental in determining the feasibility of either performing a particular experiment in the microgravity of Space or continuing on-going activities which may have been delayed due to the absence of shuttle flights during this contractual effort.

  2. EPA`s overview of the Acid Rain Program`s emissions tracking system (ETS) quarterly report process

    SciTech Connect

    Wockenfuss, M.E.

    1997-12-31

    The Acid Rain Program`s Emission Tracking System (ETS) was developed to collect, quality assure and publish the monitored and sampled emissions data collected and reported by the electric utility industry. Data are collected from fossil-fuel burning electrical generating stations that are affected by the Acid Rain Program. Since its operational start in 1993 the ETS and the data collection that surrounds it, the quarterly report process, has evolved to handle the Environmental Protection Agency`s (EPA) increased expectations of quarterly report data quality. The quarterly report process that supports the ETS provides utilities with multiple data submission options. It also provides software tools so that utilities can perform their own data assessment. This paper highlights the quarterly report process and the systems that are at the center of that process. It also analyzes utility performance relating to their 1995 and 1996 quarterly data reports and previews how the EPA`s quarterly report process will evolve over the next year.

  3. Residual stresses in material processing

    SciTech Connect

    Kozaczek, K.J.; Watkins, T.R.; Hubbard, C.R.; Wang, Xun-Li; Spooner, S.

    1994-09-01

    Material manufacturing processes often introduce residual stresses into the product. The residual stresses affect the properties of the material and often are detrimental. Therefore, the distribution and magnitude of residual stresses in the final product are usually an important factor in manufacturing process optimization or component life prediction. The present paper briefly discusses the causes of residual stresses. It then adresses the direct, nondestructive methods of residual stress measurement by X-ray and neutron diffraction. Examples are presented to demonstrate the importance of residual stress measurement in machining and joining operations.

  4. Plasma Processing of Advanced Materials

    SciTech Connect

    Heberlein, Joachim, V.R.; Pfender, Emil; Kortshagen, Uwe

    2005-02-28

    Plasma Processing of Advanced Materials The project had the overall objective of improving our understanding of the influences of process parameters on the properties of advanced superhard materials. The focus was on high rate deposition processes using thermal plasmas and atmospheric pressure glow discharges, and the emphasis on superhard materials was chosen because of the potential impact of such materials on industrial energy use and on the environment. In addition, the development of suitable diagnostic techniques was pursued. The project was divided into four tasks: (1) Deposition of superhard boron containing films using a supersonic plasma jet reactor (SPJR), and the characterization of the deposition process. (2) Deposition of superhard nanocomposite films in the silicon-nitrogen-carbon system using the triple torch plasma reactor (TTPR), and the characterization of the deposition process. (3) Deposition of films consisting of carbon nanotubes using an atmospheric pressure glow discharge reactor. (4) Adapting the Thomson scattering method for characterization of atmospheric pressure non-uniform plasmas with steep spatial gradients and temporal fluctuations. This report summarizes the results.

  5. Investigation of proposed process sequence for the array automated assembly task: Phase II. Quarterly technical progress report for quarter ending December 29, 1979

    SciTech Connect

    Mardesich, N.; Bunyan, S.; Sipperly, B.

    1980-02-01

    A sulfur hexaflouride plasma etch was investigated as a possible surface treatment to improve the performance of the cell, the Radiation Technology Infrared Furnace was qualified for use in the process sequence, and work was initiated on junction clean up by laser scribing through the junction. An evaluation of the minority carrier diffusion length of silicon crystals received from various vendors was also included in this quarters activities. Results are presented and discussed.

  6. Thermal oscillations in materials processing

    NASA Technical Reports Server (NTRS)

    Ostrach, Simon; Kamotani, Yasuhiro

    1992-01-01

    The use of thermosolutal and thermocapillary convection in materials processing is experimentally investigated. The flow patterns, unsteady mass transfer, and unsteady temperature variations seen in thermosolutal convection in enclosures are examined. An extensive research program to understand the role of thermocapillary convection in crystal growth for a variety of configurations is reviewed.

  7. Space processing of composite materials

    NASA Technical Reports Server (NTRS)

    Steurer, W. H.; Kaye, S.

    1975-01-01

    Materials and processes for the testing of aluminum-base fiber and particle composites, and of metal foams under extended-time low-g conditions were investigated. A wetting and dispersion technique was developed, based on the theory that under the absence of a gas phase all solids are wetted by liquids. The process is characterized by a high vacuum environment and a high temperature cycle. Successful wetting and dispersion experiments were carried out with sapphire fibers, whiskers and particles, and with fibers of silicon carbide, pyrolytic graphite and tungsten. The developed process and facilities permit the preparation of a precomposite which serves as sample material for flight experiments. Low-g processing consists then merely in the uniform redistribution of the reinforcements during a melting cycle. For the preparation of metal foams, gas generation by means of a thermally decomposing compound was found most adaptable to flight experiments. For flight experiments, the use of compacted mixture of the component materials limits low-g processing to a simple melt cycle.

  8. Long-term materials test program. Quarterly report, January-March 1983

    SciTech Connect

    1984-03-01

    Exposure of gas turbine materials to a PFBC effluent under the Long-Term Materials Test Program has reached 1507 hours. Unprotected nickel and cobalt base blade and vane alloys show susceptibility to hot corrosion at 1500/sup 0/F (gas temperature), 1300/sup 0/F, and 1100/sup 0/F (air-cooled pins). Precious metal aluminide and M (Co,Fe) CrAlY overlay coatings continue to show good resistance to corrosion above 1450/sup 0/F, but are susceptible to varying degrees of pitting attack between 1050 and 1300/sup 0/F. Significant erosion/corrosion degradation of both base alloys and protective coatings/claddings has been observed on airfoil specimens exposed at 1350/sup 0/F, 800 to 900 fps and dust loadings less than 100 ppM for 1085 hours. Corrosion predominately occurred in areas of direct particle impaction; i.e., leading edge and pressure surface, indicating an erosion/corrosion synergism. At gas velocities of 1200 to 1400 fps, a platinum-aluminide coated IN-738 pin experienced a metal recession rate of 8 mils/1000-hours. The PFBC facility continues to show excellent operational reliability, accumulating over 1100 test hours this quarter. The only concern from an operations standpoint is the gradual thinning of the in-bed heat exchanger tubing at a rate of about 5 mils/100 hours off the diameter.

  9. The materials processing research base of the Materials Processing Center

    NASA Technical Reports Server (NTRS)

    Latanision, R. M.

    1986-01-01

    An annual report of the research activities of the Materials Processing Center of the Massachusetts Institute of Technology is given. Research on dielectrophoresis in the microgravity environment, phase separation kinetics in immiscible liquids, transport properties of droplet clusters in gravity-free fields, probes and monitors for the study of solidification of molten semiconductors, fluid mechanics and mass transfer in melt crystal growth, and heat flow control and segregation in directional solidification are discussed.

  10. Processing science and materials development

    NASA Astrophysics Data System (ADS)

    Gegel, Harold L.

    1988-08-01

    The development of advanced technologies for the fabrication of close-tolerance parts, in conjunction with the development of advanced materials, plays a key role in the design and manufacturing of affordable aerospace systems. New process and product-design concepts must be evolved in parallel with the development of advanced materials for future systems in order to exploit the achievements being made in materials science and to tailor specific properties while simultaneously producing controlled geometrical shapes. A scientific description of production equipment and, in general, physical objects, media, fields, and interface and material-related phenomena requires theoretical models which are capable of predicting the response of the fabricating system to the initial inputs. The design of a product and the corresponding manufacturing process generally requires both deterministic models and expert systems which utilize designer intuition and logic in finding acceptable solutions. Reviewed here are some of the recent developments in process modeling as related primarily to metalworking systems and how they aid in the understanding of the role of computer and human expertise in modern computer-aided engineering (CAE).

  11. Materials processing in low gravity

    NASA Technical Reports Server (NTRS)

    Workman, Gary L.

    1990-01-01

    The final report of the Materials Processing in Low Gravity Program in which The University of Alabama in Huntsville designed, fabricated and performed various low gravity experiments in materials processing from November 7, 1989 through November 6, 1990 is presented. The facilities used in these short duration low gravity experiments include the Drop Tube and Drop Tower at Marshall Space Flight Center (MSFC), and the KC-135 aircraft at Ellington Field. During the performance of this contract, the utilization of these ground-based low gravity facilities for materials processing experiments have been instrumental in providing the opportunity to determine the feasibility of performing a number of experiments in the microgravity of Space, without the expense of a space-based experiment. Since the KC-135 was out for repairs during the latter part of the reporting period, a number of the KC-135 activities concentrated on repair and maintenance of the equipment that normally is flown on the aircraft. A number of periodic reports were given to the TCOR during the course of this contract, hence this final report is meant only to summarize the many activities performed and not redundantly cover materials already submitted.

  12. Quarterly Technical Progress Report of Radioisotope Power System Materials Production and Technology Program tasks for January 2000 through March 2000

    SciTech Connect

    Moore, J.P.

    2000-08-18

    The Office of Space and Defense Power Systems (OSDPS) of the Department of Energy (DOE) provides radioisotope Power Systems (BPS) for applications where conventional power systems are not feasible. For example, radioisotope thermoelectric generators were supplied by the DOE to the National Aeronautics and Space Administration for deep space missions including the Cassini Mission launched in October of .I 997 to study the planet Saturn. The Oak Ridge National Laboratory (ORNL) has been involved in developing materials and technology and producing components for the DOE for more than three decades. For the Cassini Mission, for example, ORNL was involved in the production of carbon-bonded carbon fiber (CBCF) insulator sets, iridium alloy blanks and foil, and clad vent sets (CVSs) and weld shields (WSs). This quarterly report has been divided into three sections to reflect program guidance from OSDPS for fiscal year (FY) 2000. The first section deals primarily with maintenance of the capability to produce flight quality carbon-bonded carbon fiber (CBCF) insulator sets, iridium alloy blanks and foil, clad vent sets (CVSs), and weld shields (WSs). In all three cases, production maintenance is assured by the manufacture of limited quantities of flight quality (FQ) components. The second section deals with several technology activities to improve the manufacturing processes, characterize materials, or to develop technologies for two new RPS. The last section is dedicated to studies of the potential for the production of 238Pu at OBNL.

  13. Quarterly Technical Progress Report of Radioisotope Power System Materials Production and Technology Program tasks for April 2000 through June 2000

    SciTech Connect

    Moore, J.P.

    2000-10-23

    The Office of Space and Defense Power Systems (OSDPS) of the Department of Energy (DOE) provides Radioisotope Power Systems (RPS) for applications where conventional power systems are not feasible. For example, radioisotope thermoelectric generators were supplied by the DOE to the National Aeronautics and Space Administration for deep space missions including the Cassini Mission launched in October of 1997 to study the planet Saturn. The Oak Ridge National Laboratory (ORNL) has been involved in developing materials and technology and producing components for the DOE for more than three decades. For the Cassini Mission, for example, ORNL was involved in the production of carbon-bonded carbon fiber (CBCF) insulator sets, iridium alloy blanks and foil, and clad vent sets (CVSs) and weld shields (WSs). This quarterly report has been divided into three sections to reflect program guidance from OSDPS for fiscal year (FY) 2000. The first section deals primarily with maintenance of the capability to produce flight quality carbon-bonded carbon fiber (CBCF) insulator sets, iridium alloy blanks and foil, clad vent sets (CVSs), and weld shields (WSs). In all three cases, production maintenance is assured by the manufacture of limited quantities of flight quality (FQ) components. The second section deals with several technology activities to improve the manufacturing processes, characterize materials, or to develop technologies for two new RPS. The last section is dedicated to studies of the potential for the production of 238Pu at ORNL.

  14. Gasoline from natural gas by sulfur processing. Quarterly report No. 10, October--December 1995

    SciTech Connect

    Erekson, E.J.; Gopalakrishnan, R.

    1996-01-01

    This report presents the work performed at the Institute of Gas Technology (IGT) during the tenth program quarter from October 1 to December 31, 1995. The overall objective of this research project is to develop a catalytic process to convert natural gas to liquid transportation fuels. The process consists of two steps that each use catalysts and sulfur-containing intermediates: (1) converting natural gas to CS{sub 2} and (2) converting CS{sub 2} to gasoline-range liquids. Experimental data will be generated to demonstrate the potential of catalysts and the overall process. During this quarter, progress in the following areas has been made: Short duration activity test on catalyst IGT-MS-103 showed no deactivation over a 6 hour period and preliminary data of CS{sub 2} reaction with H{sub 2} at 400 {minus} 410{degree}C and at atmospheric pressure indicates that IGT-HS-103 is an active catalyst for hydrocarbon synthesis from CS{sub 2} and H{sub 2}.

  15. [Development of the Selective Hydrophobic Coagulation process]. [Quarterly report, January 1, 1993--March 31, 1993

    SciTech Connect

    Not Available

    1993-08-01

    A novel technique for selectively coagulating and separating mineral matter has been developed at Virginia Tech. The process, known as Selective Hydrophobic Coagulation (SHC), has been studied under the sponsorship of the US Department of Energy since 1986 (Contracts DE-AC22-86PC91221 and DE-AC22-90PC90174). The SHC process differs from oil agglomeration, shear flocculation, polymer flocculation, and electrolytic coagulation processes in that it does not require reagents or additives to induce the formation of coagula. Often, simple pH control is all that is required to (1) induce the coagulation of coal particles and (2) effectively disperse particles of mineral matter. When the coal is superficially oxidized, a small dosage of reagents may be used to promote coagulation. During the last quarter, work was completed on the collection of the surface force and hydrophobicity data required for the estimation of the parameters in the hydrophobic interaction energy function. The estimation of these parameters will be completed in May, and the development of the extended DLVO equation for coal should be completed by the end of the next quarter. In Task 3, the mixing/coagulation characteristics of in-line mixers have been established and work with the ultrasonic horn has begun. The study of the recovery of coagula by column flotation will be completed in early May, and work on the remaining sub-tasks of Advanced Separation Methods has been accelerated in an effort to complete this task on schedule.

  16. Bench-scale co-processing. Quarterly report No. 11, October 1, 1990--December 31, 1990

    SciTech Connect

    Piasecki, C.A.; Gatsis, J.G.

    1992-02-19

    The objective of this contract is to extend and optimize UOP`s single-stage, slurry-catalyzed co-processing scheme. The particular emphasis is one evaluating alternative and disposable slurry-catalyst systems. During the current quarter, Lloydminster vacuum resid was processed without the presence of coal. The objective of this study was to evaluate the manner in which the resid is upgraded at high-severity conditions to help understand the function of the resid during co-processing. This report coves Bench-Scale Runs 30 to 34. In Runs 30 to 34, Lloydminster vacuum resid was processed without the presence of coal using a 0.05 wt % molybdenum-based catalyst at 465{degrees}C.

  17. Process for preparing energetic materials

    DOEpatents

    Simpson, Randall L.; Lee, Ronald S.; Tillotson, Thomas M.; Swansiger, Rosalind W.; Fox, Glenn A.

    2011-12-13

    Sol-gel chemistry is used for the preparation of energetic materials (explosives, propellants and pyrotechnics) with improved homogeneity, and/or which can be cast to near-net shape, and/or made into precision molding powders. The sol-gel method is a synthetic chemical process where reactive monomers are mixed into a solution, polymerization occurs leading to a highly cross-linked three dimensional solid network resulting in a gel. The energetic materials can be incorporated during the formation of the solution or during the gel stage of the process. The composition, pore, and primary particle sizes, gel time, surface areas, and density may be tailored and controlled by the solution chemistry. The gel is then dried using supercritical extraction to produce a highly porous low density aerogel or by controlled slow evaporation to produce a xerogel. Applying stress during the extraction phase can result in high density materials. Thus, the sol-gel method can be used for precision detonator explosive manufacturing as well as producing precision explosives, propellants, and pyrotechnics, along with high power composite energetic materials.

  18. Industrial Materials Processing Laser Markets

    NASA Astrophysics Data System (ADS)

    Followwill, Dorman

    1989-03-01

    The way I would like to handle this morning is first, to give you an overview before I put anything up in terms of slides. An overview of the study that we produced a couple of months ago. It is entitled "Industrial Materials Processing Laser Markets", and if you want information on that particular study, then you can speak with me at the coffee break.

  19. 27 CFR 18.51 - Processing material.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Processing material. 18.51... material. (a) General. A proprietor may produce processing material or receive processing material produced elsewhere. Fermented processing material may not be used in the manufacture of concentrate....

  20. 27 CFR 18.51 - Processing material.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Processing material. 18.51... material. (a) General. A proprietor may produce processing material or receive processing material produced elsewhere. Fermented processing material may not be used in the manufacture of concentrate....

  1. Computational Material Processing in Microgravity

    NASA Technical Reports Server (NTRS)

    2005-01-01

    Working with Professor David Matthiesen at Case Western Reserve University (CWRU) a computer model of the DPIMS (Diffusion Processes in Molten Semiconductors) space experiment was developed that is able to predict the thermal field, flow field and concentration profile within a molten germanium capillary under both ground-based and microgravity conditions as illustrated. These models are coupled with a novel nonlinear statistical methodology for estimating the diffusion coefficient from measured concentration values after a given time that yields a more accurate estimate than traditional methods. This code was integrated into a web-based application that has become a standard tool used by engineers in the Materials Science Department at CWRU.

  2. The processing of semiconductor materials

    NASA Technical Reports Server (NTRS)

    1979-01-01

    Five experiments involving the processing of semiconductor materials were performed during the Skylab mission. After discussions on semiconductors and their unique electronic properties, and techniques of crystal growth, these five experiments are presented. Four melt growth experiments were attempted: (1) steady state growth and segregation under zero gravity (InSb); (2) seeded, containerless solidification of InSb; (3) influence of gravity-free solidification on microsegregation; and (4) directional solidification of InSb-GaSb alloys. One vapor growth experiment, crystal growth by vapor transport, was attempted.

  3. Advanced research and technology development fossil energy materials program. Quarterly progress report for the period ending September 30, 1981

    SciTech Connect

    Bradley, R.A.

    1981-12-01

    This is the fourth combined quarterly progress report for those projects that are part of the Advanced Research and Technology Development Fossil Energy Materials Program. The objective is to conduct a program of research and development on materials for fossil energy applications with a focus on the longer-term and generic needs of the various fossil fuel technologies. The program includes research aimed toward a better understanding of materials behavior in fossil energy environments and the development of new materials capable of substantial enhancement of plant operations and reliability. Work performed on the program generally falls into the Applied Research and Exploratory Development categories as defined in the DOE Technology Base Review, although basic research and engineering development are also conducted. A substantial portion of the work on the AR and TD Fossil Energy Materials Program is performed by participating cntractor organizations. All subcontractor work is monitored by Program staff members at ORNL and Argonne National Laboratory. This report is organized in accordance with a work breakdown structure defined in the AR and TD Fossil Energy Materials Program Plan for FY 1981 in which projects are organized according to fossil energy technologies. We hope this series of AR and TD Fossil Energy Materials Program quarterly progress reports will aid in the dissemination of information developed on the program.

  4. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, October 1--December 31, 1992

    SciTech Connect

    Brandes, S.D.; Winschel, R.A.; Burke, F.P.; Robbins, G.A.

    1993-10-01

    The Research and Development Department of CONSOL Inc. is conducted a program to characterize process and product streams from direct coal liquefaction process development projects sponsored by the Department of Energy. In this program, CONSOL obtains samples from current process development activities in coal liquefaction and coal-oil coprocessing, and characterizes them using established analytical techniques. In addition, selected samples are characterized by other analytical techniques to evaluate their potential for aiding process development. These analyses and interpretation of the results in relation to process operations are provided by the subcontractor. Major topics reported in this thirteenth quarterly report are the following: (1) Analyses were performed on three coals and eleven process oils from HRI, Inc. process development unit Run 260--03, which was the first process development unit test of Black Thunder Mine subbituminous coal, significant operating problems were encountered, and sample properties are discussed in context to the operational problems; (2) a summary of the status of the Participants Program is given; (3) summaries of the final reports produced by the University of Chicago, the University of Utah, Iowa State University, and the University of Kentucky under the Participants Program, are presented.

  5. Field study of disposed wastes from advanced coal processes. Quarterly technical progress report, November 1991--January 1992

    SciTech Connect

    Not Available

    1992-08-01

    The objective of this research is to develop information to be used by private industry and government agencies for planning waste disposal practices associated with advanced coal processes. To accomplish this objective, DOE has contracted Radian Corporation and the North Dakota Energy & Environmental Research Center (EERC) to design, construct, and monitor a limited number of field disposal tests with advanced coal process wastes. These field tests will be monitored over a three year period with the emphasis on collecting data on the field disposal of these wastes. Accomplishments for this past quarter are as follows: The 9th quarterly measurements at the Colorado site took place in December, 1991. Permeability and neutron absorption moisture content measurements were made and on site data was collected from the data logger; The 9th quarterly sampling at the Ohio site took place in November 1991. Permeability and moisture content measurements were made, and water samples were collected from the wells and lysimeters; The second quarterly core and water samples from the first Illinois test case were collected in mid November, and field data were collected from the data logger; Chemical analysis of all core and water samples continued; all chemical analyses except for some tests on Illinois second quarter cores are now complete.

  6. Integrated lunar materials manufacturing process

    NASA Technical Reports Server (NTRS)

    Gibson, Michael A. (Inventor); Knudsen, Christian W. (Inventor)

    1990-01-01

    A manufacturing plant and process for production of oxygen on the moon uses lunar minerals as feed and a minimum of earth-imported, process materials. Lunar feed stocks are hydrogen-reducible minerals, ilmenite and lunar agglutinates occurring in numerous, explored locations mixed with other minerals in the pulverized surface layer of lunar soil known as regolith. Ilmenite (FeTiO.sub.3) and agglutinates contain ferrous (Fe.sup.+2) iron reducible by hydrogen to yield H.sub.2 O and metallic Fe at about 700.degree.-1,200.degree. C. The H.sub.2 O is electrolyzed in gas phase to yield H.sub.2 for recycle and O.sub.2 for storage and use. Hydrogen losses to lunar vacuum are minimized, with no net hydrogen (or any other earth-derived reagent) consumption except for small leaks. Feed minerals are surface-mined by front shovels and transported in trucks to the processing area. The machines are manned or robotic. Ilmenite and agglutinates occur mixed with silicate minerals which are not hydrogen-reducible at 700.degree.-1,200.degree. C. and consequently are separated and concentrated before feeding to the oxygen generation process. Solids rejected from the separation step and reduced solids from the oxygen process are returned to the mine area. The plant is powered by nuclear or solar power generators. Vapor-phase water electrolysis, a staged, countercurrent, fluidized bed reduction reactor and a radio-frequency-driven ceramic gas heater are used to improve thermal efficiency.

  7. Lunar materials processing system integration

    NASA Technical Reports Server (NTRS)

    Sherwood, Brent

    1992-01-01

    The theme of this paper is that governmental resources will not permit the simultaneous development of all viable lunar materials processing (LMP) candidates. Choices will inevitably be made, based on the results of system integration trade studies comparing candidates to each other for high-leverage applications. It is in the best long-term interest of the LMP community to lead the selection process itself, quickly and practically. The paper is in five parts. The first part explains what systems integration means and why the specialized field of LMP needs this activity now. The second part defines the integration context for LMP -- by outlining potential lunar base functions, their interrelationships and constraints. The third part establishes perspective for prioritizing the development of LMP methods, by estimating realistic scope, scale, and timing of lunar operations. The fourth part describes the use of one type of analytical tool for gaining understanding of system interactions: the input/output model. A simple example solved with linear algebra is used to illustrate. The fifth and closing part identifies specific steps needed to refine the current ability to study lunar base system integration. Research specialists have a crucial role to play now in providing the data upon which this refinement process must be based.

  8. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, July 1--September 30, 1992

    SciTech Connect

    Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-11-01

    This is the twelfth Quarterly Technical Progress Report under DOE Contract DE-AC22-89PC89883. Major topics reported are: Summaries of the final reports produced by Lehigh University, West Virginia University, and Vander Sande Associates under the Participants Program are presented. Analytical data produced by CONSOL are provided in Appendix I for all samples employed in the Participants Program and issued with the samples to research groups in the Participants Program. A paper was presented at the 1992 US Department of Energy Pittsburgh Energy Technology Center Liquefaction Contractors` Review Conference, held in Pittsburgh September 23--24, 1992, entitled ``The Chemical Nature of Coal Liquid Resids and the Implications for Process Development``. It appears as Appendix 2 in this report.

  9. Gasoline from natural gas by sulfur processing. Quarterly report No. 11, January--March 1996

    SciTech Connect

    Erekson, E.J.

    1996-05-01

    The overall objective of this research project is to develop a catalytic process to convert natural gas to liquid transportation fuels. The process consists of two steps that each use catalysts and sulfur-containing intermediates: (1) converting natural has to CS{sub 2} and (2) converting CS{sub 2} to gasoline-range liquids. Experimental data will be generated to demonstrate the potential of catalysts and the overall process. During this quarter, progress in the following areas has been made: Hydrogenation of CS{sub 2} to liquid hydrocarbons was accomplished on two sets of catalyst a cobalt exchanged ZSM-5 and a mixture containing MoS{sub 2} hydrogenation catalyst and HZSM-5. CS{sub 2} conversions of up to 100% were achieved. The highest selectivity to C{sub 4}{sup +} hydrocarbons was 52%. There is interest within the oil companies we contacted for a process that converts natural gas to liquid hydrocarbons. In addition there is also interest in a process that produces hydrogen for a refinery, while at the same time it removes hydrogen sulfide.

  10. Develop apparatus and process for second-stage drying. Quarterly progress report, September 26--December 26, 1994

    SciTech Connect

    Taylor, F.

    1995-01-05

    Progress is reported on Task 1, Computer simulation refinement and extension, and its two subtasks: Verification of computer model simulation of the drying process for lumber in a superheated kiln and Establishment of energy loss predictions for specific kiln designs for the first stage kiln. A report of a trip to the Irvington Moore Corporation facility and plans for next quarter are described.

  11. Investigation of the geokinetics horizontal in situ oil shale retorting process. Quarterly report, July, August, September 1983

    SciTech Connect

    Henderson, K.B.

    1984-01-01

    Retort No. 27 was ignited using a new procedure and 47 days of operation were completed in the quarter. For retort No. 28 air injection and off gas piping and manifolding was completed along with the installation of electrical and instrumentation wiring. The off gas processing plant for the two retorts was completed and an initial shakedown run made.

  12. Lightweight combustion residues-based structural materials for use in mines. Quarterly report, 1 March 1995--31 May 1995

    SciTech Connect

    Chugh, Y.P.; Zhang, Yuzhuo; Ghosh, A.K.; Palmer, S.R.; Peng, Suping; Xiao, Y

    1995-12-31

    The overall goal of this PrOject is to develop, design, and test artificial supports (post and crib members), for use in mines, which will be manufactured from coal combustion by-products (CCB) based lightweight structural materials. During the last quarter (Dec. 1, 1994--Feb. 28, 1995), it was reported that low LOI ({approx}5%) F-fly ash-based lightweight materials with density ranging from 70-1 110 pcf and compressive strength ranging from about 1,500 psi to 5,000 psi had been developed. During this quarter, 1) similar materials were developed using higher LOI ({approx}1O%) F-fly ash, 2) performance of materials using nylon fibers rather than polypropylene fibers was examined, 3) effect of addition of small amounts of FBC spent bed material on strength-deformation properties was evaluated, 4) flexural strength tests were performed on 2 in. X 2 in. X 12 in. cast beams, 5) compressive strength tests were performed on cast hollow cylinders (6 in. outer diameter, 2.762 in. inner diameter and 12 in. long) and 6) limited number of tests were conducted to determine the effect of mixing speed on strength of developed materials. The results of these studies indicate that 1) suitable lightweight materials using 60--65% higher LOI F-fly ash can be developed for fabrication of artificial supports, 2) nylon fibers perform significantly better than Polypropylene fibers, 3) loss of strength and deformability due to the use of higher LOI fly ash can be offset to some extent by adding 5--10% FBC spent bed material, 4) relationship between flexural strength and compressive strength, similar to that in concrete exists, 5) strength-deformation properties of hollow cylinders are similar to 3 in. X 6 in. solid cylinders, and 6) strength and deformation modulus increase with mixing speed. Two mixes for final development of lightweight materials have been identified and final test` will begin June 1, 1995.

  13. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, January 1--March 31, 1992

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-08-01

    This is the tenth Quarterly Technical Progress Report under DOE Contract DE-AC22-89PC89883. Process oils from Wilsonville Run 262 were analyzed to provide information on process performance. Run 262 was operated from July 10 through September 30, 1991, in the thermal/catalytic Close-Coupled Integrated Two-Stage Liquefaction (CC-ITSL) configuration with ash recycle. The feed coal was Black Thunder Mine subbituminous coal. The high/low temperature sequence was used. Each reactor was operated at 50% of the available reactor volume. The interstage separator was in use throughout the run. The second-stage reactor was charged with aged Criterion 324 catalyst (Ni/Mo on 1/16 inch alumina extrudate support). Slurry catalysts and sulfiding agent were fed to the first-stage reactor. Molyvan L is an organometallic compound which contains 8.1% Mo, and is commercially available as an oil-soluble lubricant additive. It was used in Run 262 as a dispersed hydrogenation catalyst precursor, primarily to alleviate deposition problems which plagued past runs with Black Thunder coal. One test was made with little supported catalyst in the second stage. The role of phenolic groups in donor solvent properties was examined. In this study, four samples from direct liquefaction process oils were subjected to O-methylation of the phenolic groups, followed by chemical analysis and solvent quality testing.

  14. Gasoline from natural gas by sulfur processing. Quarterly progress report, June--September 1993

    SciTech Connect

    Erekson, E.J.; Miao, F.Q.

    1993-10-01

    The overall objective of this research project is to develop a catalytic process to convert natural gas to liquid transportation fuels. The process consists of two steps that each utilize catalysts and sulfur containing intermediates: (1) to convert natural gas to CS{sub 2}, and (2) to convert CS{sub 2} to gasoline range liquids. Experimental data will be generated to demonstrate the potential of catalysts and the overall process. During this first quarter, progress in the following areas has been made. One high surface area molybdenum catalyst has been prepared. An existing unit at IGT is being modified to accommodate the sulfur feedstocks and the higher temperatures(> 1300{degrees}K) required for studying the reactions of hydrogen sulfide and methane as proposed in Tasks 2 through 5. An HP 5890 gas chromatograph with a TCD(thermal conductivity detector) for detecting fixed gases including hydrogen and an FPD(flame photometric detector) for detecting sulfur compounds was purchased using SMP funds and has been received.

  15. Enforcement actions: Significant actions resolved material licensees (non-medical). Quarterly progress report, October 1994--December 1994

    SciTech Connect

    1995-02-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (October - December 1994) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to material licensees (non-medical) with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication.

  16. Advanced Materials and Processing 2010

    NASA Astrophysics Data System (ADS)

    Zhang, Yunfeng; Su, Chun Wei; Xia, Hui; Xiao, Pengfei

    2011-06-01

    Strain sensors made from MWNT/polymer nanocomposites / Gang Yin, Ning Hu and Yuan Li -- Shear band evolution and nanostructure formation in titanium by cold rolling / Dengke Yang, Peter D. Hodgson and Cuie Wen -- Biodegradable Mg-Zr-Ca alloys for bone implant materials / Yuncang Li ... [et al.] -- Hydroxyapatite synthesized from nanosized calcium carbonate via hydrothermal method / Yu-Shiang Wu, Wen-Ku Chang and Min Jou -- Modeling of the magnetization process and orthogonal fluxgate sensitivity of ferromagnetic micro-wire arrays / Fan Jie ... [et al.] -- Fabrication of silicon oxide nanowires on Ni coated silicon substrate by simple heating process / Bo Peng and Kwon-Koo Cho -- Deposition of TiOxNy thin films with various nitrogen flow rate: growth behavior and structural properties / S.-J. Cho ... [et al.] -- Observation on photoluminescence evolution in 300 KeV self-ion implanted and annealed silicon / Yu Yang ... [et al.] -- Facile synthesis of lithium niobate from a novel precursor H[symbol] / Meinan Liu ... [et al.] -- Effects of the buffer layers on the adhesion and antimicrobial properties of the amorphous ZrAlNiCuSi films / Pai-Tsung Chiang ... [et al.] -- Fabrication of ZnO nanorods by electrochemical deposition process and its photovoltaic properties / Jin-Hwa Kim ... [et al.] -- Cryogenic resistivities of NbTiAlVTaLax, CoCrFeNiCu and CoCrFeNiAl high entropy alloys / Xiao Yang and Yong Zhang -- Modeling of centrifugal force field and the effect on filling and solidification in centrifugal casting / Wenbin Sheng, Chunxue Ma and Wanli Gu -- Electrochemical properties of TiO[symbol] nanotube arrays film prepared by anodic oxidation / Young-Jin Choi ... [et al.] -- Effect of Ce additions on high temperature properties of Mg-5Sn-3Al-1Zn alloy / Byoung Soo Kang ... [et al.] -- Sono-electroless plating of Ni-Mo-P film / Atsushi Chiba, Masato Kanou and Wen-Chang Wu -- Diameter dependence of giant magneto-impedance effect in co-based melt extracted amorphous

  17. Advanced Materials and Processing 2010

    NASA Astrophysics Data System (ADS)

    Zhang, Yunfeng; Su, Chun Wei; Xia, Hui; Xiao, Pengfei

    2011-06-01

    Strain sensors made from MWNT/polymer nanocomposites / Gang Yin, Ning Hu and Yuan Li -- Shear band evolution and nanostructure formation in titanium by cold rolling / Dengke Yang, Peter D. Hodgson and Cuie Wen -- Biodegradable Mg-Zr-Ca alloys for bone implant materials / Yuncang Li ... [et al.] -- Hydroxyapatite synthesized from nanosized calcium carbonate via hydrothermal method / Yu-Shiang Wu, Wen-Ku Chang and Min Jou -- Modeling of the magnetization process and orthogonal fluxgate sensitivity of ferromagnetic micro-wire arrays / Fan Jie ... [et al.] -- Fabrication of silicon oxide nanowires on Ni coated silicon substrate by simple heating process / Bo Peng and Kwon-Koo Cho -- Deposition of TiOxNy thin films with various nitrogen flow rate: growth behavior and structural properties / S.-J. Cho ... [et al.] -- Observation on photoluminescence evolution in 300 KeV self-ion implanted and annealed silicon / Yu Yang ... [et al.] -- Facile synthesis of lithium niobate from a novel precursor H[symbol] / Meinan Liu ... [et al.] -- Effects of the buffer layers on the adhesion and antimicrobial properties of the amorphous ZrAlNiCuSi films / Pai-Tsung Chiang ... [et al.] -- Fabrication of ZnO nanorods by electrochemical deposition process and its photovoltaic properties / Jin-Hwa Kim ... [et al.] -- Cryogenic resistivities of NbTiAlVTaLax, CoCrFeNiCu and CoCrFeNiAl high entropy alloys / Xiao Yang and Yong Zhang -- Modeling of centrifugal force field and the effect on filling and solidification in centrifugal casting / Wenbin Sheng, Chunxue Ma and Wanli Gu -- Electrochemical properties of TiO[symbol] nanotube arrays film prepared by anodic oxidation / Young-Jin Choi ... [et al.] -- Effect of Ce additions on high temperature properties of Mg-5Sn-3Al-1Zn alloy / Byoung Soo Kang ... [et al.] -- Sono-electroless plating of Ni-Mo-P film / Atsushi Chiba, Masato Kanou and Wen-Chang Wu -- Diameter dependence of giant magneto-impedance effect in co-based melt extracted amorphous

  18. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, July 1--September 30, 1993

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1994-03-01

    This is the Sixteenth Quarterly Technical Progress Report under DOE Contract DE-AC22-89PC89883. Major topics reported are: Fifty-eight process samples from HRI CTSL Bench Unit Run CC-15 (227-75) were analyzed to provide information on process performance. Run CC-15 was operated for 14 periods (days) from October 21 through November 3, 1992 in the thermal/catalytic configuration with Black Thunder Mine (Wyodak and Anderson seams) coal and Shell S-317 Ni/Mo supported extrudate catalyst. The run was made to test performance with and without a dispersed hydrous iron hydroxide catalyst precursor impregnated in the coal. Results are compared with those of previous HRI CTSL bench unit Run CC-1, which was operated in the catalytic/catalytic configuration, also with Shell S-317 catalyst. Several HRI Run CC-15 product distillate fractions prepared by the National Institute for Petroleum and Energy Research (NIPER) for petroleum inspection tests were further characterized by CONSOL. These characterization data are presented. MicroAutoclave tests and chemical analyses were performed to evaluate the solvent quality of two potential solvents for Alberta Research Council ARC. Eight product samples from catalytic dehydrogenation experiments were characterized for the University of Pittsburgh. A description is presented of the thermogravimetric analysis (TGA) method for determination of resid concentration/resid conversion, which was adapted for use in-house from HRI`s standard method. A brief summary of the status of the Participants Program is given.

  19. EDS coal liquefaction process development: Phase V. Quarterly technical progress report, January 1-March 31, 1984

    SciTech Connect

    1984-07-01

    This report is the twenty-first Quarterly Technical Progress Report for US Department of Energy Cooperative Agreement No. DE-FC05-77ET10069 for EDS Coal Liquefaction Process Development Phase V. A detailed comparison of RCLU, CLPP, and ECLP yields has been initiated. This study builds off previous yield modeling results, which found that RCLU, CLPP, and ECLP yields were generally consistent given the scatter of the data, although some differences were noted. These pilot unit yield differences have now been quantified, and operating/configurational differences which account for some of them have been identified. Preliminary yield comparison results after correcting for these known process differences between the pilot plants indicate that: RCLU and CLPP yields are generally consistent; ECLP's conversion is about 5 lb/100 lb DAF coal lower than RCLU/CLPP at comparable operating conditions; and work has been initiated to define the EDS slurry preheater feed system design (based on slurry distributor manifold guidelines and coking correlation predictions, which influence furnace pass control issues such as slurry flow measurement). EDS hydrotreated naphtha showed a low level of systemic toxicity to rats exposed to the vapor six hours per day, five days per week for thirteen weeks.

  20. EDS coal liquefaction process development. Phase V. Quarterly technical progress report, July 1-September 30, 1980

    SciTech Connect

    1981-02-01

    This report is the tenth Quarterly Technical Progress Report for US Department of Energy Cooperative Agreement No. DE-FC01-77ET10069 (formerly EF-77-A-01-2893) for Exxon Donor Solvent (EDS) Coal Liquefaction Process Development - Phase V. The Laboratory Process Research and Development studies were conducted at various Exxon Research and Engineering Co. (ER and E) facilities: Research and Development Division at Baytown, Texas; Products Research Division at Linden, New Jersey; and the Exxon Research and Development Laboratories at Baton Rouge, Louisiana. The Engineering Research and Development studies were performed at the Synthetic Fuels Engineering and Exxon Engineering Technology Departments of ER and E at Florham Park, New Jersey. The information dealing with the Management, Detailed Engineering, and Procurement activities related to revamp of the FLEXICOKING Prototype Unit was generated at Exxon Company, USA, Houston, Texas, and Exxon Engineering - Project Management Department of ER and E, Florham Park, New Jersey. The information dealing with operation of the 250 T/D Exxon Coal Liquefaction Pilot Plant (ECLP) was generated at Exxon Company, USA, Houston, Texas.

  1. Material development of polymer/metal paste for flip-chip attach interconnection technology. Quarterly report

    SciTech Connect

    Saraf, R.F.; Roldan, J.M.; Sambucetti, C.J.

    1997-11-04

    In the last leg of the project the major thrust has been on the assembly process using the conductive adhesive, viz., the optimization of the process conditions and the bonding equipment. The past at this point is deemed optimum in terms of the three basic properties: adhesion, screenability and conductivity. The reliability and wafer level screening is proven reproducibly over several experiment constituting assembly of more than one part. Using the optimum paste the authors have provided an uninterrupted supply of reproducible (optimum) paste. By tweaking the compounding conditions a first-level scale-up was successfully achieved. The initial 30g batch to Endicott is increased to as high as 300 g batches with similar properties. The large batch material is shown to behave similar to the small batch materials. Also, it has been essential to do large wafer level studies: Endicott has scaled up their screening from 5 inch wafer to 8 inch wafer.

  2. Materials processing in space: Early experiments

    NASA Technical Reports Server (NTRS)

    Naumann, R. J.; Herring, H. W.

    1980-01-01

    The characteristics of the space environment were reviewed. Potential applications of space processing are discussed and include metallurgical processing, and processing of semiconductor materials. The behavior of fluid in low gravity is described. The evolution of apparatus for materials processing in space was reviewed.

  3. Molten Salt Coal Gasification Process Development Unit. Phase 2. Quarterly technical progress report No. 2, October-December 1980

    SciTech Connect

    Slater, M. H.

    1981-01-20

    This represents the second quarterly progress report on Phase 2 of the Molten Salt Coal Gasification Process Development Unit (PDU) Program. Phase 1 of this program started in March 1976 and included the design, construction, and initial operation of the PDU. On June 25, 1980, Phase 2 of the program was initiated. It covers a 1-year operations program utilizing the existing PDU and is planned to include five runs with a targeted total operating time of 9 weeks. During this report period, Run 6, the initial run of the Phase 2 program was completed. The gasification system was operated for a total of 95 h at pressures up to 10 atm. Average product gas HHV values of 100 Btu/scf were recorded during 10-atm operation, while gasifying coal at a rate of 1100 lb/h. The run was terminated when the melt overflow system plugged after 60 continuous hours of overflow. Following this run, melt withdrawal system revisions were made, basically by changing the orifice materials from Monofrax to an 80 Cobalt-20 Chromium alloy. By the end of the report period, the PDU was being prepared for Run 7.

  4. Aqueous Processing Material Accountability Instrumentation

    SciTech Connect

    Robert Bean

    2007-09-01

    Increased use of nuclear power will require new facilities. The U.S. has not built a new spent nuclear fuel reprocessing facility for decades. Reprocessing facilities must maintain accountability of their nuclear fuel. This survey report on the techniques used in current aqueous reprocessing facilities, and provides references to source materials to assist facility design efforts.

  5. Field Demonstration of a Membrane Process to Separate Nitrogen from Natural Gas: Nineteenth Quarterly Progress Report (Second Quarter 2006)

    SciTech Connect

    Kaaeid Lokhandwala

    2006-06-30

    The original proposal described the construction and operation of a 1 MMscfd treatment system to be operated at a Butcher Energy gas field in Ohio. The gas produced at this field contained 17% nitrogen. During pre-commissioning of the project, a series of well tests showed that the amount of gas in the field was significantly smaller than expected and that the nitrogen content of the wells was very high (25 to 30%). After evaluating the revised cost of the project, Butcher Energy decided that the plant would not be economical and withdrew from the project. Since that time, Membrane Technology and Research, Inc. (MTR) signed a marketing and sales partnership with ABB Lummus Global, a large multinational corporation, and is working with the company's Randall Gas Technology group, a supplier of equipment and processing technology to the natural gas industry. Randall's engineering group found a new site for the project at a North Texas Exploration (NTE) gas processing plant, and we continue, but have as yet been unsuccessful in our attempts, to negotiate with Atmos Energy for a final test of the project demonstration unit. In the meantime, MTR has located an alternative testing opportunity and signed a contract for a demonstration plant in Rio Vista, CA. Several commercial sales have resulted from the partnership with ABB, and total sales of nitrogen/natural gas membrane separation units are now approaching $2.6 million.

  6. Ion beam processing of advanced electronic materials

    SciTech Connect

    Cheung, N.W.; Marwick, A.D.; Roberto, J.B.; International Business Machines Corp., Yorktown Heights, NY . Thomas J. Watson Research Center; Oak Ridge National Lab., TN )

    1989-01-01

    This report contains research programs discussed at the materials research society symposia on ion beam processing of advanced electronic materials. Major topics include: shallow implantation and solid-phase epitaxy; damage effects; focused ion beams; MeV implantation; high-dose implantation; implantation in III-V materials and multilayers; and implantation in electronic materials. Individual projects are processed separately for the data bases. (CBS)

  7. Tags and seals for controling nuclear materials, Arms control and nonproliferation technologies. Second quarter 1993

    SciTech Connect

    Staehle, G; Talaber, C; Stull, S; Moulthrop, P

    1993-12-31

    This issue of Arms Control and Nonproliferation Technologies summarizes demonstrations and addresses related topics. The first article, ``Basic Nuclear Material Control and Accountability Concepts as Might be Applied to the Uranium from the US-Russian HEU Purchase,`` describes safeguards sybsystems necessary for effective nuclear material safeguards. It also presents a general discussion on HEU-to-low-enrichment uranium (LEU) commingling processes and suggests applicable key measurement points. The second article, ``A Framework for Evaluating Tamper-Indicating-Device Technologies (TIDs),`` describes their uses, proper selection, and evaluation. The final three articles discuss the tags and seals applications and general characteristics of several nuclear material containers: the Type 30B uranium hexafluoride container, the AT-400R container, and the DOT Specification 6M container for SNM. Finally, the Appendix displays short descriptions and illustrations of seven tags and seals, including: the E-cup and wire seal, the python seal, the secure loop inspectable tag/seal (SLITS), bolt-and-loop type electronic identification devices, and the shrink-wrap seal.

  8. Materials processing in space bibliography

    NASA Technical Reports Server (NTRS)

    Pentecost, E. (Compiler)

    1982-01-01

    Literature dealing with flight experiments utilizing a low gravity environment to elucidate and control various processes or with ground based activities that provide supporting research is listed. Included are Government reports, contractor reports, conference proceedings, and journal articles. Subdivisions of the bibliography include the five categories: crystal growth; metals, alloys, and composites, fluids and transport; glasses and ceramics; and Ultrahigh Vacuum and Containerless Processing Technologies, in addition to a list of patents and a compilation of anonymously authored collections and reports and a cross reference index.

  9. Utilization of lightweight materials made from coal gasification slags. Quarterly report, March 1995--May 1995

    SciTech Connect

    1995-06-01

    Integrated-gasification combined-cycle (IGCC) technology is an emerging technology that utilizes coal for power generation and production of chemical feedstocks. However, this process generates large amounts of solid waste, consisting of vitrified ash (slag) along with some unconverted carbon, which is disposed of as solid waste. In previous projects, Praxis investigated the utilization of {open_quotes}as-generated{close_quotes} slags for a wide variety of applications in road construction, cement and concrete production, agricultural applications, and as a landfill material. From these studies, we found that it would be extremely difficult for {open_quotes}as-generated{close_quotes} slag to find large-scale acceptance in the marketplace even at no cost because the materials it could replace were abundantly available at very low cost. It became apparent that a more promising approach would be to develop a variety of value-added products from slag that meet specific industry requirements. This approach was made feasible by the discovery that slag could be made into a lightweight material by controlled heating in a kiln at temperatures between 1400 and 1700{degrees}F. These results indicated the potential for using such materials as substitutes for conventional lightweight aggregates (LWA). The technology to produce lightweight and ultra-lightweight aggregates (ULWA) from slag was subsequently developed by Praxis with funding from the Electric Power Research Institute (EPRI), Illinois Clean Coal Institute (ICCI), and internal resources. The major objectives of the subject project, funded by DOE`s Morgantown Energy Technology Center (METC), are to demonstrate the technical and economic viability of commercial production of LWA and ULWA from slag and to test the suitability of these aggregates for various applications.

  10. Process for producing dispersed particulate composite materials

    DOEpatents

    Henager, Jr., Charles H.; Hirth, John P.

    1995-01-01

    This invention is directed to a process for forming noninterwoven dispersed particulate composite products. In one case a composite multi-layer film product comprises a substantially noninterwoven multi-layer film having a plurality of discrete layers. This noninterwoven film comprises at least one discrete layer of a first material and at least one discrete layer of a second material. In another case the first and second materials are blended together with each other. In either case, the first material comprises a metalloid and the second material a metal compound. At least one component of a first material in one discrete layer undergoes a solid state displacement reaction with at least one component of a second material thereby producing the requisite noninterwoven composite film product. Preferably, the first material comprises silicon, the second material comprises Mo.sub.2 C, the third material comprises SiC and the fourth material comprises MoSi.sub.2.

  11. Possibilities of Laser Processing of Paper Materials

    NASA Astrophysics Data System (ADS)

    Stepanov, Alexander; Saukkonen, Esa; Piili, Heidi

    Nowadays, lasers are applied in many industrial processes: the most developed technologies include such processes as laser welding, hybrid welding, laser cutting of steel, etc. In addition to laser processing of metallic materials, there are also many industrial applications of laser processing of non-metallic materials, like laser welding of polymers, laser marking of glass and laser cutting of wood-based materials. It is commonly known that laser beam is suitable for cutting of paper materials as well as all natural wood-fiber based materials. This study reveals the potential and gives overview of laser application in processing of paper materials. In 1990's laser technology increased its volume in papermaking industry; lasers at paper industry gained acceptance for different perforating and scoring applications. Nowadays, with reduction in the cost of equipment and development of laser technology (especially development of CO2 technology), laser processing of paper material has started to become more widely used and more efficient. However, there exists quite little published research results and reviews about laser processing of paper materials. In addition, forest industry products with pulp and paper products in particular are among major contributors for the Finnish economy with 20% share of total exports in the year 2013. This has been the standpoint of view and motivation for writing this literature review article: when there exists more published research work, knowledge of laser technology can be increased to apply it for processing of paper materials.

  12. Space processing of electronic materials

    NASA Technical Reports Server (NTRS)

    Holland, L. R.

    1982-01-01

    The bulk growth of solid solution alloys of mercury telluride and cadmium telluride is discussed. These alloys are usually described by the formula Hg1-xCdxTe, and are useful for the construction of infrared detectors. The electronic energy band gap can be controlled between zero and 1.6 electron volts by adjusting the composition x. The most useful materials are at x approximately 20%, suitable for detection wavelengths of about 10 micrometers. The problems of growing large crystals are rooted in the wide phase diagram of the HgTe-CdTe pseudobinary system which leads to exaggerate segregation in freezing, constitutional supercooling, and other difficulties, and in the high vapor pressure of mercury at the growth temperatures, which leads to loss of stoichiometry and to the necessity of working in strong, pressure resistant sealed containers.

  13. Laser Material Processing for Microengineering Applications

    NASA Technical Reports Server (NTRS)

    Helvajian, H.

    1995-01-01

    The processing of materials via laser irradiation is presented in a brief survey. Various techniques currently used in laser processing are outlined and the significance to the development of space qualified microinstrumentation are identified. In general the laser processing technique permits the transferring of patterns (i.e. lithography), machining (i.e. with nanometer precision), material deposition (e.g., metals, dielectrics), the removal of contaminants/debris/passivation layers and the ability to provide process control through spectroscopy.

  14. Infrared Database for Process Support Materials

    NASA Technical Reports Server (NTRS)

    Bennett, K. E.; Boothe, R. E.; Burns, H. D.

    2003-01-01

    Process support materials' compatibility with cleaning processes is critical to ensure final hardware cleanliness and that performance requirements are met. Previous discovery of potential contaminants in process materials shows the need for incoming materials testing and establishment of a process materials database. The Contamination Control Team of the Materials, Processes, and Manufacturing (MP&M) Department at Marshall Space Flight Center (MSFC) has initiated the development of such an infrared (IR) database, called the MSFC Process Materials IR database, of the common process support materials used at MSFC. These process support materials include solvents, wiper cloths, gloves, bagging materials, etc. Testing includes evaluation of the potential of gloves, wiper cloths, and other items to transfer contamination to handled articles in the absence of solvent exposure, and the potential for solvent exposure to induce material degradation. This Technical Memorandum (TM) summarizes the initial testing completed through December 2002. It is anticipated that additional testing will be conducted with updates provided in future TMs.Materials were analyzed using two different IR techniques: (1) Dry transference and (2) liquid extraction testing. The first of these techniques utilized the Nicolet Magna 750 IR spectrometer outfitted with a horizontal attenuated total reflectance (HATR) crystal accessory. The region from 650 to 4,000 wave numbers was analyzed, and 50 scans were performed per IR spectrum. A dry transference test was conducted by applying each sample with hand pressure to the HATR crystal to first obtain a spectrum of the parent material. The material was then removed from the HATR crystal and analyzed to determine the presence of any residues. If volatile, liquid samples were examined both prior to and following evaporation.The second technique was to perform an extraction test with each sample in five different solvents.Once the scans were complete for

  15. Roadmap for Process Equipment Materials Technology

    SciTech Connect

    none,

    2003-10-01

    This Technology Roadmap addresses the ever-changing material needs of the chemical and allied process industries, and the energy, economic and environmental burdens associated with corrosion and other materials performance and lifetime issues. This Technology Roadmap outlines the most critical of these R&D needs, and how they can impact the challenges facing today’s materials of construction.

  16. A calcium oxide sorbent process for bulk separation of carbon dioxide. Quarterly progress report 19, January--March, 1994

    SciTech Connect

    Harrison, D.P.

    1994-04-01

    This research project is investigating the technical feasibility of a high-temperature, high-pressure (HTHP) process for the bulk separation of CO{sub 2} from coal-derived gas. Indirect evidence which suggested that the water-gas shift reaction occurred simultaneously with CO{sub 2} removal was found. Occurrence of the simultaneous reactions created the possibility of a direct one-step process for the manufacture of hydrogen from coal-gas while at the same time separating a concentrated stream of CO{sub 2}. Previous quarterly reports have described the design, construction, and commissioning of the fixed-bed reactor, development of analytical procedures, and results of a number of tests using dolomite sorbent precursor. During the current quarter, additional tests were carried out to study the effects of calcination gas composition, temperature, and space velocity using the standard dolomite sorbents. Alternate sorbents were tested to provide direct comparison of dolomite and limestone performance. Tests were performed using an empty reactor and reactor packed with commercial shift catalyst to learn more of the characteristics of the shift reaction in the absence of carbonation. Toward the end of the quarter, emphasis changed to sorbent durability and a number of multicycle tests were completed.

  17. Bench-scale testing of the micronized magnetite process. Second quarterly technical progress report, October 1994--December 1994

    SciTech Connect

    1995-01-19

    This document contains the Quarterly Technical Progress Report for the Micronized Magnetite Testing Project being performed at PETC`s Process Research Facility (PRF). This second quarterly report covers the period from October, 1994 through December, 1994. The main accomplishments of Custom Coals and the project subcontractors, during this period, included: (1) Submitted all overdue project documents and kept up with routine reporting requirements; (2) Worked with CLI Corporation, the design subcontractor, and completed the circuit design and finalized all design drawings; (3) Specified and procured all of the process equipment for the circuit, as well as a number of ancillary equipment, instruments, and supplies; (4) Assisted Vangura Iron Inc. in detailing and constructing the structural and platework steel; (5) Subcontracted Rizzo & Sons to perform the circuit mechanical and electrical installation, and prepared for January 23rd installation start date; (6) Organized and prepared for coal and magnetite procurement; (7) Specified and organized an operating personnel plan for the commissioning and testing tasks in the project; (8) Assessed analytical challenges for project, and began to research problem areas. This report contains a short discussion of the project description, objectives, budget, schedule, and teaming arrangement. It also includes a detailed discussion of the abovementioned project accomplishments and plans, organized by the various task series within the project work plan. The final section contains an outline of the specific project goals for the next quarterly reporting period.

  18. Materials, Processes, and Environmental Engineering Network

    NASA Technical Reports Server (NTRS)

    White, Margo M.

    1993-01-01

    Attention is given to the Materials, Processes, and Environmental Engineering Network (MPEEN), which was developed as a central holding facility for materials testing information generated by the Materials and Processes Laboratory of NASA-Marshall. It contains information from other NASA centers and outside agencies, and also includes the NASA Environmental Information System (NEIS) and Failure Analysis Information System (FAIS) data. The data base is NEIS, which is accessible through MPEEN. Environmental concerns are addressed regarding materials identified by the NASA Operational Environment Team (NOET) to be hazardous to the environment. The data base also contains the usage and performance characteristics of these materials.

  19. Utilization of lightweight materials made from coal gasification slags. Quarterly report, June--August 1995

    SciTech Connect

    1995-09-01

    Integrated-gasification combined-cycle (IGCC) technology is an emerging technology that utilizes coal for power generation and production of chemical feedstocks. However, the process generates large amounts of solid waste, consisting of vitrified ash (slag) and some unconverted carbon. In previous projects, Praxis investigated the utilization of {open_quotes}as-generated{close_quotes} slags for a wide variety of applications in road construction, cement and concrete production, agricultural applications, and as a landfill material. From these studies, we found that it would be extremely difficult for {open_quotes}as-generated{close_quotes} slag to find large-scale acceptance in the marketplace even at no cost because the materials it could replace were abundantly available at very low cost. It was further determined that the unconverted carbon, or char, in the slag is detrimental to its utilization as sand or fine aggregate. It became apparent that a more promising approach would be to develop a variety of value-added products from slag that meet specific industry requirements. This approach was made feasible by the discovery that slag undergoes expansion and forms a lightweight material when subjected to controlled heating in a kiln at temperatures between 1400 and 1700{degrees}F. These results indicated the potential for using expanded slag as a substitute for conventional lightweight aggregates (LWA). The technology to produce lightweight and ultra-lightweight aggregates (ULWA) from slag was subsequently developed by Praxis with funding from the Electric Power Research Institute (EPRI), Illinois Clean Coal Institute (ICCI), and internal resources. The major objectives of the subject project are to demonstrate the technical and economic viability of commercial production of LWA and ULWA from slag and to test the suitability of these aggregates for various applications.

  20. Utilization of lightweight materials made from coal gasification slags. Quarterly report, June 1--August 31, 1996

    SciTech Connect

    1996-12-31

    Integrated-gasification combined-cycle (IGCC) technology is an emerging technology that utilizes coal for power generation and production of chemical feedstocks. However, the process generates large amounts of solid waste, consisting of vitrified ash (slag) and some unconverted carbon. In previous projects, Praxis investigated the utilization of ``as-generated`` slags for a wide variety of applications in road construction, cement and concrete production, agricultural applications, and as a landfill material. From these studies, we found that it would be extremely difficult for ``as-generated`` slag to find large-scale acceptance in the marketplace even at no cost because the materials it could replace were abundantly available at very low cost. It was further determined that the unconverted carbon, or char, in the slag is detrimental to its utilization as sand or fine aggregate. It became apparent that a more promising approach would be to develop a variety of value-added products from slag that meet specific industry requirements. This approach was made feasible by the discovery that slag undergoes expansion and forms a lightweight material when subjected to controlled heating in a kiln at temperatures between 1400 and 17000F. These results confirmed the potential for using expanded slag as a substitute for conventional lightweight aggregates (LWA). The technology to produce lightweight and ultra-lightweight aggregates (ULWA) from slag was subsequently developed by Praxis. The major objectives of the subject project are to demonstrate the technical and economic viability of commercial production of LWA and ULWA from slag and to test the suitability of these aggregates for various applications. The project goals are to be accomplished in two phases: Phase 1, comprising the production of LWA and ULWA from slag at the large pilot-scale, and Phase 2, which involves commercial evaluation of these aggregates in a number of applications. Accomplishments are described.

  1. Precision grinding process development for brittle materials

    SciTech Connect

    Blaedel, K L; Davis, P J; Piscotty, M A

    1999-04-01

    High performance, brittle materials are the materials of choice for many of today's engineering applications. This paper describes three separate precision grinding processes developed at Lawrence Liver-more National Laboratory to machine precision ceramic components. Included in the discussion of the precision processes is a variety of grinding wheel dressing, truing and profiling techniques.

  2. Thermal plasma processing of materials

    SciTech Connect

    Pfender, E.; Heberlein, J.

    1992-02-01

    Emphasis has been on plasma synthesis of fine powders, plasma Chemical Vapor Deposition (CVD), on related diagnostics, and on modeling work. Since plasma synthesis as well as plasma CVD make frequent use of plasma jets, the beginning has been devoted of plasma jets and behavior of particulates injected into such plasma jets. Although most of the construction of the Triple-Torch Plasma Reactor (TTPR) has already been done, modifications have been made in particular modifications required for plasma CVD of diamond. A new reactor designed for Counter-Flow Liquid Injection Plasma Synthesis (CFLIPS) proved to be an excellent tool for synthesis of fine powders as well as for plasma CVD. An attempt was made to model flow and temperature fields in this reactor. Substantial efforts were made to single out those parameters which govern particle size, size distribution, and powder quality in our plasma synthesis experiments. This knowledge is crucial for controlling the process and for meaningful diagnostics and modeling work. Plasma CVD of diamond films using both reactors has been very successful and we have been approached by a number of companies interested in using this technology for coating of tools.

  3. Lightweight combustion residues-based structural materials for use in mines. Quarterly report, 1 December 1994--28 February 1995

    SciTech Connect

    Chugh, Yoginder P.; Zhang, Yuzhuo; Ghosh, A.K.; Palmer, S.R; Peng, Suping, Xiao, Y.

    1995-12-31

    The overall goal of this project is to develop, design and test artificial supports (post and crib members) for use in mines manufactured from coal combustion by-product (CCB) based lightweight structural materials. The lightweight cement-fly ash grout with density ranging from 70 to 110 pcf has been developed incorporating very high volume (50--60 % of whole solid materials) fly ash. Characterization of individual component materials for the CCB-based structural materials has been performed for Class F fly ash, ASTM Type I cement, lime, silica fume, polypropylene fibers, protein-based foam, water-reducing agents, and calcium chloride. During the past quarter, we emphasized on screening mix designs and establishing mixing and curing procedures. We have demonstrated for the first time that cellular cement-fly ash grout can be developed with very low water: cement ratio (0.32--0.45). After forming, all the samples in the molds were moist cured in a chamber for 24-hours, at 90% relatively humidity (RH) and at 72{degrees}F. They were then demolded and transferred to a low pressure steam chamber (150{degrees}F and 100% RH). After steaming for 24 hours the samples were removed to a moist cure chamber prior to testing.

  4. Materials micro-processing using femtosecond lasers

    NASA Astrophysics Data System (ADS)

    Dabu, R.; Zamfirescu, M.; Anghel, I.; Jipa, F.

    2013-06-01

    Nonlinear optical phenomena which dominate the interaction of tightly focused femtosecond laser beams with materials are discussed. Different femtosecond laser based techniques for material processing such as laser ablation, two-photon photo-polymerization, and material surface nano-structuring are described. For the computer controlled micro-processing of materials, near-infrared Ti:sapphire femtosecond lasers, with nano-Joule/micro-Joule pulse energy, were coupled with direct laser writing workstations. Laser fabricated micro-nanostructures and their applications are presented.

  5. Metabonomics for detection of nuclear materials processing.

    SciTech Connect

    Alam, Todd Michael; Luxon, Bruce A.; Neerathilingam, Muniasamy; Ansari, S.; Volk, David; Sarkar, S.; Alam, Mary Kathleen

    2010-08-01

    Tracking nuclear materials production and processing, particularly covert operations, is a key national security concern, given that nuclear materials processing can be a signature of nuclear weapons activities by US adversaries. Covert trafficking can also result in homeland security threats, most notably allowing terrorists to assemble devices such as dirty bombs. Existing methods depend on isotope analysis and do not necessarily detect chronic low-level exposure. In this project, indigenous organisms such as plants, small mammals, and bacteria are utilized as living sensors for the presence of chemicals used in nuclear materials processing. Such 'metabolic fingerprinting' (or 'metabonomics') employs nuclear magnetic resonance (NMR) spectroscopy to assess alterations in organismal metabolism provoked by the environmental presence of nuclear materials processing, for example the tributyl phosphate employed in the processing of spent reactor fuel rods to extract and purify uranium and plutonium for weaponization.

  6. Utilization of lightweight materials made from coal gasification slags. Quarterly report, September--November 1995

    SciTech Connect

    1995-12-01

    Integrated-gasification combined-cycle (IGCC) technology is an emerging technology that utilizes coal for power generation and production of chemical feedstocks. However, the process generates large amounts of solid waste, consisting of vitrified ash (slag) and some unconverted carbon. Slag undergoes expansion and forms a lightweight material when subjected to controlled heating in a kiln. The potential exists for using expanded slag as a substitute for conventional lightweight aggregates (LWA). The technology to produce lightweight and ultra-lightweight aggregates (ULWA) from slag was subsequently developed. The project scope consists of collecting a 20-ton sample of slag (primary slag), processing it for char removal, and subjecting it to pyroprocessing to produce expanded slag aggregates of various size gradations and unit weights, ranging from 12 to 50 lb/ft{sup 3}. A second smaller slag sample will be used for confirmatory testing. The expanded slag aggregates will then be tested for their suitability in manufacturing precast concrete products (e.g., masonry blocks and roof tiles) and insulating concrete, first at the laboratory scale and subsequently in commercial manufacturing plants. These products will be evaluated using ASTM and industry test methods. Technical data generated during production and testing of the products will be used to assess the overall technical viability of expanded slag production. In addition, a market assessment will be made based on an evaluation of both the expanded slag aggregates and the final products, and market prices for these products will be established in order to assess the economic viability of these utilization technologies.

  7. Planning for Materials Processing in Space

    NASA Technical Reports Server (NTRS)

    1977-01-01

    A systems design study to describe the conceptual evolution, the institutional interrelationshiphs, and the basic physical requirements to implement materials processing in space was conducted. Planning for a processing era, rather than hardware design, was emphasized. Product development in space was examined in terms of fluid phenomena, phase separation, and heat and mass transfer. The effect of materials processing on the environment was studied. A concept for modular, unmanned orbiting facilities using the modified external tank of the space shuttle is presented. Organizational and finding structures which would provide for the efficient movement of materials from user to space are discussed.

  8. Materials, processes, and environmental engineering network

    NASA Technical Reports Server (NTRS)

    White, Margo M.

    1993-01-01

    The Materials, Processes, and Environmental Engineering Network (MPEEN) was developed as a central holding facility for materials testing information generated by the Materials and Processes Laboratory. It contains information from other NASA centers and outside agencies, and also includes the NASA Environmental Information System (NEIS) and Failure Analysis Information System (FAIS) data. Environmental replacement materials information is a newly developed focus of MPEEN. This database is the NASA Environmental Information System, NEIS, which is accessible through MPEEN. Environmental concerns are addressed regarding materials identified by the NASA Operational Environment Team, NOET, to be hazardous to the environment. An environmental replacement technology database is contained within NEIS. Environmental concerns about materials are identified by NOET, and control or replacement strategies are formed. This database also contains the usage and performance characteristics of these hazardous materials. In addition to addressing environmental concerns, MPEEN contains one of the largest materials databases in the world. Over 600 users access this network on a daily basis. There is information available on failure analysis, metals and nonmetals testing, materials properties, standard and commercial parts, foreign alloy cross-reference, Long Duration Exposure Facility (LDEF) data, and Materials and Processes Selection List data.

  9. Laser Materials Processing for NASA's Aerospace Structural Materials

    NASA Technical Reports Server (NTRS)

    Nagarathnam, Karthik; Hunyady, Thomas A.

    2001-01-01

    Lasers are useful for performing operations such as joining, machining, built-up freeform fabrication, and surface treatment. Due to the multifunctional nature of a single tool and the variety of materials that can be processed, these attributes are attractive in order to support long-term missions in space. However, current laser technology also has drawbacks for space-based applications. Specifically, size, power efficiency, lack of robustness, and problems processing highly reflective materials are all concerns. With the advent of recent breakthroughs in solidstate laser (e.g., diode-pumped lasers) and fiber optic technologies, the potential to perform multiple processing techniques in space has increased significantly. A review of the historical development of lasers from their infancy to the present will be used to show how these issues may be addressed. The review will also indicate where further development is necessary to realize a laser-based materials processing capability in space. The broad utility of laser beams in synthesizing various classes of engineering materials will be illustrated using state-of-the art processing maps for select lightweight alloys typically found on spacecraft. Both short- and long-term space missions will benefit from the development of a universal laser-based tool with low power consumption, improved process flexibility, compactness (e.g., miniaturization), robustness, and automation for maximum utility with a minimum of human interaction. The potential advantages of using lasers with suitable wavelength and beam properties for future space missions to the moon, Mars and beyond will be discussed. The laser processing experiments in the present report were performed using a diode pumped, pulsed/continuous wave Nd:YAG laser (50 W max average laser power), with a 1064 nm wavelength. The processed materials included Ti-6AI-4V, Al-2219 and Al-2090. For Phase I of this project, the laser process conditions were varied and optimized

  10. The processing of materials in outer space

    NASA Technical Reports Server (NTRS)

    Gelles, S. H.; Colling, E. W.

    1977-01-01

    Zero-gravity environment may lead to fabrication of new and improved materials. According to comprehensive study of application of this promising technology to superconducting and electrical contact materials, outer space processing could improve microstructure and homogeneity of many single and multicomponent systems formed from solidification of fluid phases. New structures that are impossible to form terrestrially may also be accessible in space environment.

  11. Aqueous processing in materials science and engineering

    NASA Astrophysics Data System (ADS)

    Mooiman, Michael B.; Sole, Kathryn C.

    1994-06-01

    Reviews of aqueous processing in JOM have traditionally focused on hydrometallurgical process routes. This article, however, addresses the application of aqueous processing in materials engineering and presents some promising developments that employ aqueous-based routes for the manufacture of high-tech components and specialty products. Such applications include producing metallic and ceramic powders; etching; surface modification by electroplating and electroless plating; manufacturing jewelry and intricate components by electroforming; and producing advanced ceramics, composites, and nanophase materials by sol-gel and biomimetic processing.

  12. Electronic materials processing and the microgravity environment

    NASA Technical Reports Server (NTRS)

    Witt, A. F.

    1988-01-01

    The nature and origin of deficiencies in bulk electronic materials for device fabrication are analyzed. It is found that gravity generated perturbations during their formation account largely for the introduction of critical chemical and crystalline defects and, moreover, are responsible for the still existing gap between theory and experiment and thus for excessive reliance on proprietary empiricism in processing technology. Exploration of the potential of reduced gravity environment for electronic materials processing is found to be not only desirable but mandatory.

  13. Plasma-assisted microwave processing of materials

    NASA Technical Reports Server (NTRS)

    Barmatz, Martin (Inventor); Ylin, Tzu-yuan (Inventor); Jackson, Henry (Inventor)

    1998-01-01

    A microwave plasma assisted method and system for heating and joining materials. The invention uses a microwave induced plasma to controllably preheat workpiece materials that are poorly microwave absorbing. The plasma preheats the workpiece to a temperature that improves the materials' ability to absorb microwave energy. The plasma is extinguished and microwave energy is able to volumetrically heat the workpiece. Localized heating of good microwave absorbing materials is done by shielding certain parts of the workpiece and igniting the plasma in the areas not shielded. Microwave induced plasma is also used to induce self-propagating high temperature synthesis (SHS) process for the joining of materials. Preferably, a microwave induced plasma preheats the material and then microwave energy ignites the center of the material, thereby causing a high temperature spherical wave front from the center outward.

  14. Extraterrestrial materials processing and construction. [space industrialization

    NASA Technical Reports Server (NTRS)

    Criswell, D. R.; Waldron, R. D.; Mckenzie, J. D.

    1980-01-01

    Three different chemical processing schemes were identified for separating lunar soils into the major oxides and elements. Feedstock production for space industry; an HF acid leach process; electrorefining processes for lunar free metal and metal derived from chemical processing of lunar soils; production and use of silanes and spectrally selective materials; glass, ceramics, and electrochemistry workshops; and an econometric model of bootstrapping space industry are discussed.

  15. Investigation of the geokinetics horizontal in situ oil shale retorting process. Quarterly report, October, November, December 1983

    SciTech Connect

    Henderson, K.B.

    1984-03-01

    Retort No. 27 was ignited on August 11, 1983 and by December 31 had completed 139 days of operation and produced 11,420 barrels of oil. Retort No. 28 was ignited on October 18, 1983 and on December 31 had completed 74 days of operation and produced 5,285 barrels of oil. The off-gas processing plants for the two retorts was completed and put through a shakedown run. Concentration levels of H/sub 2/S and NH/sub 3/ in the retort off gas did not warrant plant operation in the fourth quarter. Environmental studies are reported.

  16. Energy from in situ processing of antrim oil shale. Quarterly technical progress report, April-June 1980

    SciTech Connect

    Young, D.C.

    1980-07-01

    Processing of data from the F80 extraction trials continued for much of this quarter. Several computer programs were written so the data could be evaluated or accessed for plotting. Numerous computer generated plots were made for use in the topical reports which are in preparation. Activity at the experimental site has been directed toward an orderly shutdown and dismantling of equipment. All but nine of the wells were filled with cement and capped in accordance with th requirements of the Michigan Department of Natural Resources. Shale characterization work was continued at four universities in Michigan under subcontracts. Work on final reports of several of these projects has begun.

  17. Aircraft gas turbine materials and processes.

    PubMed

    Kear, B H; Thompson, E R

    1980-05-23

    Materials and processing innovations that have been incorporated into the manufacture of critical components for high-performance aircraft gas turbine engines are described. The materials of interest are the nickel- and cobalt-base superalloys for turbine and burner sections of the engine, and titanium alloys and composites for compressor and fan sections of the engine. Advanced processing methods considered include directional solidification, hot isostatic pressing, superplastic foring, directional recrystallization, and diffusion brazing. Future trends in gas turbine technology are discussed in terms of materials availability, substitution, and further advances in air-cooled hardware. PMID:17772808

  18. Aircraft gas turbine materials and processes.

    PubMed

    Kear, B H; Thompson, E R

    1980-05-23

    Materials and processing innovations that have been incorporated into the manufacture of critical components for high-performance aircraft gas turbine engines are described. The materials of interest are the nickel- and cobalt-base superalloys for turbine and burner sections of the engine, and titanium alloys and composites for compressor and fan sections of the engine. Advanced processing methods considered include directional solidification, hot isostatic pressing, superplastic foring, directional recrystallization, and diffusion brazing. Future trends in gas turbine technology are discussed in terms of materials availability, substitution, and further advances in air-cooled hardware.

  19. Materials Processing in Space (MPS) program description

    NASA Technical Reports Server (NTRS)

    1981-01-01

    Insight is provided into the scientific rotationale for materials processing in space (MPS), and a comprehensive and cohesive approach for implementation and integration of the many, diverse aspects of MPS is described. The programmatic and management functions apply to all projects and activities implemented under MPS. It is intended that specific project plans, providing project unique details, will be appended to this document for endeavors such as the Space Processing Applications Rocket (SPAR) Project, the Materials Experiment Assembly (MEA) Project, the MPS/Spacelab (MPS/SL) Project, and the Materials Experiment Carrier (MEC) Payloads.

  20. Functionally graded materials: Design, processing and applications

    SciTech Connect

    Miyamoto, Y.; Kaysser, W.A.; Rabin, B.H.; Kawasaki, A.; Ford, R.G.

    1999-09-01

    In a Functionally Graded Material (FGM), the composition and structure gradually change over volume, resulting in corresponding changes in the properties of the material. By applying the many possibilities inherent in the FGM concept, it is anticipated that materials will be improved and new functions for them created. A comprehensive description of design, modeling, processing, and evaluation of FGMs as well as their applications is covered in this book. The contents include: lessons from nature; graded microstructures; modeling and design; characterization of properties; processing and fabrication; applications; and summary and outlook.

  1. Mimicry of natural material designs and processes

    SciTech Connect

    Bond, G.M.; Richman, R.H.; McNaughton, W.P.

    1995-06-01

    Biological structural materials, although composed of unremarkable substances synthesized at low temperatures, often exhibit superior mechanical properties. In particular, the quality in which nearly all biologically derived materials excel is toughness. The advantageous mechanical properties are attributable to the hierarchical, composite, structural arrangements common to biological systems. Materials scientists and engineers have increasingly recognized that biological designs or processing approaches applied to man-made materials (biomimesis) may offer improvements in performance over conventional designs and fabrication methods. In this survey, the structures and processing routes of marine shells, avian eggshells, wood, bone, and insect cuticle are briefly reviewed, and biomimesis research inspired by these materials is discussed. In addition, this paper describes and summarizes the applications of biomineralization, self-assembly, and templating with proteins to the fabrication of thin ceramic films and nanostructure devices.

  2. Commercial use of materials processing in space

    NASA Technical Reports Server (NTRS)

    Zoller, L. K.; Brown, R. L.

    1979-01-01

    The paper examines the scientific and commercial aspects of Materials Processing in the Space program. The elimination of gravity driven convection in molten materials can preclude undesirable stirring and mixing during crystal growth, and improve the casting of alloys and composites, chemical reactions, and the separation of biological materials. The elimination of hydrostatic pressure will allow alloy heat-treatment without distortion and growth of heavy crystals, such as thorium oxide, and containerless processing of liquids and molten materials. On the other hand, more sophisticated process control and diagnostic methods in sample preparation and temperature control must be developed, concluding that space made products of commercial interest are likely to be low volume, high value items.

  3. Materials Compatibility and Lubricants Research on CFC-refrigerant substitutes. Quarterly MCLR Program technical progress report, July 1--September 30, 1995

    SciTech Connect

    Szymurski, S.R.; Hourahan, G.C.; Godwin, D.S.; Amrane, K.

    1995-10-01

    The Materials Compatibility and Lubricants Research (MCLR) program supports critical research to accelerate the introduction of CFC and HCFC refrigerant substitutes. The MCLR program addresses refrigerant and lubricant properties and materials compatibility. The primary elements of the work include data collection and dissemination, materials compatibility testing, and methods development. This report summarizes the research conducted during the third quarter of calendar year 1995 on the following projects: Thermophysical properties of HCFC alternatives; Compatibility of manufacturing process fluids with HFC refrigerants and ester lubricants; Compatibility of motor materials used in air-conditioning for retrofits with alternative refrigerants and lubricants; Compatibility of lubricant additives with HFC refrigerants and synthetic lubricants; Products of motor burnouts; Accelerated test methods for predicting the life of motor materials exposed to refrigerant-lubricant mixtures; Investigation of flushing and clean-out methods; Investigation into the fractionation of refrigerant blends; Lean flammability limits as a fundamental refrigerant property; Effect of selected contaminants in AC and R equipment; Study of foaming characteristics; Study of lubricant circulation in systems; Evaluation of HFC-245ca for commercial use in low pressure chillers; Infrared analysis of refrigerant mixtures; Refrigerant database; Refrigerant toxicity survey; Thermophysical properties of HFC-32, HFC-123, HCFC-124 and HFC-125; Thermophysical properties of HFC-143a and HFC-152a; Theoretical evaluations of R-22 alternative fluids; Chemical and thermal stability of refrigerant-lubricant mixtures with metals; Miscibility of lubricants with refrigerants; Viscosity, solubility and density measurements of refrigerant-lubricant mixtures; Electrohydrodynamic enhancement of pool and in-tube boiling of alternative refrigerants; Accelerated screening methods; and more.

  4. Gasoline from natural gas by sulfur processing. Quarterly report No. 9, July 1, 1995--September 31, 1995

    SciTech Connect

    Erekson, E.J.; Gopalakrishnan, R.

    1995-10-01

    This report presents the work performed at the Institute of Gas Technology (IGT) during the ninth program quarter from July 1 to September 30, 1995, under Department of Energy (DOE) Contract No. DE-AC22-93PC92114. This program has coordinated funding for Task 1 from IGT`s Sustaining Membership Program (SMP), while DOE is funding Tasks 2 through 8. Progress in all tasks is reported here. The overall objective of this research project is to develop a catalytic process to convert natural gas to liquid transportation fuels. The process consists of two steps that each use catalysts and sulfur-containing intermediates: (1) converting natural gas to CS{sub 2} and (2) converting CS{sub 2} to gasoline-range liquids. Experimental data will be generated to demonstrate the potential of catalysts and the overall process. During this quarter, progress in the following areas has been made: (1) Short duration activity test on catalyst IGT-MS-103 showed no deactivation over a 6 hour period; (2) Tests showed that even with CO{sub 2} in the feed, H{sub 2}S conversions of 50% can be achieved.

  5. Space Environmental Effects on Materials and Processes

    NASA Technical Reports Server (NTRS)

    Sabbann, Leslie M.

    2009-01-01

    The Materials and Processes (M&P) Branch of the Structural Engineering Division at Johnson Space Center (JSC) seeks to uphold the production of dependable space hardware through materials research, which fits into NASA's purpose of advancing human exploration, use, and development of space. The Space Environmental Effects projects fully support these Agency goals. Two tasks were assigned to support M&P. Both assignments were to further the research of material behavior outside of Earth's atmosphere in order to determine which materials are most durable and safe to use in space for mitigating risks. One project, the Materials on International Space Station Experiments (MISSE) task, was to compile data from International Space Station (ISS) experiments to pinpoint beneficial space hardware. The other project was researching the effects on composite materials of exposure to high doses of radiation for a Lunar habitat project.

  6. Artificial intelligence in the materials processing laboratory

    NASA Technical Reports Server (NTRS)

    Workman, Gary L.; Kaukler, William F.

    1990-01-01

    Materials science and engineering provides a vast arena for applications of artificial intelligence. Advanced materials research is an area in which challenging requirements confront the researcher, from the drawing board through production and into service. Advanced techniques results in the development of new materials for specialized applications. Hand-in-hand with these new materials are also requirements for state-of-the-art inspection methods to determine the integrity or fitness for service of structures fabricated from these materials. Two problems of current interest to the Materials Processing Laboratory at UAH are an expert system to assist in eddy current inspection of graphite epoxy components for aerospace and an expert system to assist in the design of superalloys for high temperature applications. Each project requires a different approach to reach the defined goals. Results to date are described for the eddy current analysis, but only the original concepts and approaches considered are given for the expert system to design superalloys.

  7. Microwave processing of radioactive materials-I

    SciTech Connect

    White, T.L.; Berry, J.B.

    1989-01-01

    This paper is the first of two papers that reviews the major past and present applications of microwave energy for processing radioactive materials, with particular emphasis on processing radioactive wastes. Microwave heating occurs through the internal friction produced inside a dielectric material when its molecules vibrate in response to an oscillating microwave field. For this presentation, we shall focus on the two FCC-approved microwave frequencies for industrial, scientific, and medical use, 915 and 2450 MHz. Also, because of space limitations, we shall postpone addressing plasma processing of hazardous wastes using microwave energy until a later date. 13 refs., 4 figs.

  8. The development of an integrated multistage fluid bed retorting process. Quarterly technical report, April 1, 1993--June 30, 1993

    SciTech Connect

    Carter, S.; Stehn, J.; Vego, A.

    1993-07-01

    This report summarizes the progress made on the development of an integrated multistage fluidized bed retorting process (KENTORT II) during the period of April 1, 1993 through June 30, 1993 under Cooperative Agreement No. DE-FC21-90MC27286 with the Morgantown Energy Technology Center, U.S. Department of Energy. The KENTORT II process includes integral fluidized bed zones for pyrolysis, gasification, and combustion of the oil shale. The purpose of this program is to design and test the KENTORT II process at the 50-lb/hr scale. The major activities for this quarter included: system leak proofing, cold flow testing, shake down of the data acquisition system, instrumentation verification, and preparation for hot operation. Once the tasks necessary for heat up are completed, shake down and operation of the Process Demonstration Unit will begin.

  9. An improved approach for process monitoring in laser material processing

    NASA Astrophysics Data System (ADS)

    König, Hans-Georg; Pütsch, Oliver; Stollenwerk, Jochen; Loosen, Peter

    2016-04-01

    Process monitoring is used in many different laser material processes due to the demand for reliable and stable processes. Among different methods, on-axis process monitoring offers multiple advantages. To observe a laser material process it is unavoidable to choose a wavelength for observation that is different to the one used for material processing, otherwise the light of the processing laser would outshine the picture of the process. By choosing a different wavelength, lateral chromatic aberration occurs in not chromatically corrected optical systems with optical scanning units and f-Theta lenses. These aberrations lead to a truncated image of the process on the camera or the pyrometer, respectively. This is the reason for adulterated measurements and non-satisfying images of the process. A new approach for solving the problem of field dependent lateral chromatic aberration in process monitoring is presented. Therefore, the scanner-based optical system is reproduced in a simulation environment, to predict the occurring lateral chromatic aberrations. In addition, a second deflecting system is integrated into the system. By using simulation, a predictive control is designed that uses the additional deflecting system to introduce reverse lateral deviations in order to compensate the lateral effect of chromatic aberration. This paper illustrates the concept and the implementation of the predictive control, which is used to eliminate lateral chromatic aberrations in process monitoring, the simulation on which the system is based the optical system as well as the control concept.

  10. Scale-up of mild gasification to a process development unit. Quarterly report, November 1993--February 1994

    SciTech Connect

    Campbell, J.A.L.; Carty, R.H.; Foster, H.

    1994-05-01

    The work performed during the ninth quarterly reporting period (November 21, 1993 through February 20, 1994) is presented in this report. The overall objective of this project is to develop the IGT Mid-Gasification MILDGAS) process for near-term commercialization. The specific objectives of the program are to: design, construct, and operate a 24-tons/day adiabatic process development unit (PDU) to obtain process performance data suitable for further design scaleup; obtain large batches of coal-derived co-products for industrial evaluation; prepare a detailed design of a demonstration unit; and develop technical and economic plans for commercialization of the MILDGAS process. The project team that is performing the initial phases of the PDU development are: Kerr-McGee Coal Corporation (K-M Coal), the Institute of Gas Technology (IGT), Bechtel Corporation (Bechtel), and Southern Illinois University at Carbondale (SIUC). The MILDGAS process is a continuous closed system for producing liquid and solid (char) co-products at mild operating conditions up to 50 psig and 1300F. It is capable of processing a wide range of both eastern caking and western noncaking coals. The 1 ton/hr PDU facility that is to be constructed is comprised of a 2.5-ft ID adiabatic gasifier for the production of gases, coal liquids, and char; a three-stage condensation train to condense and store the liquid products; and coal feeding and char handling equipment. The facility will also incorporate support equipment for environmentally acceptable disposal of process waste. A Finding of No Significant Impact (FONSI) was obtained on our NEPA submittal on February 10, 1994, allowing us to proceed with the project. The permitting documentation for the authority to construct was submitted to the Illinois EPA this quarter. Work to finalize the process design and obtain updated bids on the PDU was begun after the FONSI was obtained.

  11. Development of the integrated environmental control model: Performance and cost models for the NOXSO process. Quarterly progress report

    SciTech Connect

    Kalagnanam, J.R.; Rubin, E.S.

    1995-12-01

    This Quarterly Report documents research efforts carried out under Contract No. DE-AC22-92PC91346 from the US Department of Energy. lie purpose of this contract is to develop and refine the Integrated Environmental Control Model (IECM) created and enhanced by Carnegie Mellon University (CMU) for the US Department of Energy`s Pittsburgh Energy Technology Center (DOE/PETC) under contract Numbers DE-FG2283PC60271 and DE-AC22-87PC79864. The work in this contract is divided into two phases. Phase I deals with further developing the existing version of the IECM and training PETC personnel on the effective use of the model. Phase II deals with creating new technology modules, linking the IECM with PETC databases, and training PETC personnel on the effective use of the updated model. The present report summarizes recent progress on the Phase I effort during the period July 1, 1995 through September 30, 1995. This report presents additional details on the new performance models of the NOXSO process. For convenience, the complete description of the NOXSO performance model is presented here, including information previously presented in the Quarterly Report submitted in April 1995. Also included in this report is a newly developed cost model for the NOXSO process. Illustrative results are presented using the new performance and cost models as implemented in the IECM.

  12. Sol-gel processing of energetic materials

    SciTech Connect

    Tillotson, T.M.; Hrubesh, L.H.; Fox, G.L.; Simpson, R.L.; Lee, R.W.; Swansiger, R.W.; Simpson, L.R.

    1997-08-18

    As part of a new materials effort, we are exploring the use of sol- gel chemistry to manufacture energetic materials. Traditional manufacturing of energetic materials involves processing of granular solids. One application is the production of detonators where powders of energetic material and a binder are typically mixed and compacted at high pressure to make pellets. Performance properties are strongly dependent on particle size distribution, surface area of its constituents, homogeneity of the mix, and void volume. The goal is to produce detonators with fast energy release rate the are insensitive to unintended initiation. In this paper, we report results of our early work in this field of research, including the preparation of detonators from xerogel molding powders and aerogels, comparing the material properties with present state-of-the-art technology.

  13. Advances in Processing of Bulk Ferroelectric Materials

    NASA Astrophysics Data System (ADS)

    Galassi, Carmen

    The development of ferroelectric bulk materials is still under extensive investigation, as new and challenging issues are growing in relation to their widespread applications. Progress in understanding the fundamental aspects requires adequate technological tools. This would enable controlling and tuning the material properties as well as fully exploiting them into the scale production. Apart from the growing number of new compositions, interest in the first ferroelectrics like BaTiO3 or PZT materials is far from dropping. The need to find new lead-free materials, with as high performance as PZT ceramics, is pushing towards a full exploitation of bariumbased compositions. However, lead-based materials remain the best performing at reasonably low production costs. Therefore, the main trends are towards nano-size effects and miniaturisation, multifunctional materials, integration, and enhancement of the processing ability in powder synthesis. Also, in control of dispersion and packing, to let densification occur in milder conditions. In this chapter, after a general review of the composition and main properties of the principal ferroelectric materials, methods of synthesis are analysed with emphasis on recent results from chemical routes and cold consolidation methods based on the colloidal processing.

  14. Advanced Technology Composite Fuselage - Materials and Processes

    NASA Technical Reports Server (NTRS)

    Scholz, D. B.; Dost, E. F.; Flynn, B. W.; Ilcewicz, L. B.; Nelson, K. M.; Sawicki, A. J.; Walker, T. H.; Lakes, R. S.

    1997-01-01

    The goal of Boeing's Advanced Technology Composite Aircraft Structures (ATCAS) program was to develop the technology required for cost and weight efficient use of composite materials in transport fuselage structure. This contractor report describes results of material and process selection, development, and characterization activities. Carbon fiber reinforced epoxy was chosen for fuselage skins and stiffening elements and for passenger and cargo floor structures. The automated fiber placement (AFP) process was selected for fabrication of monolithic and sandwich skin panels. Circumferential frames and window frames were braided and resin transfer molded (RTM'd). Pultrusion was selected for fabrication of floor beams and constant section stiffening elements. Drape forming was chosen for stringers and other stiffening elements. Significant development efforts were expended on the AFP, braiding, and RTM processes. Sandwich core materials and core edge close-out design concepts were evaluated. Autoclave cure processes were developed for stiffened skin and sandwich structures. The stiffness, strength, notch sensitivity, and bearing/bypass properties of fiber-placed skin materials and braided/RTM'd circumferential frame materials were characterized. The strength and durability of cocured and cobonded joints were evaluated. Impact damage resistance of stiffened skin and sandwich structures typical of fuselage panels was investigated. Fluid penetration and migration mechanisms for sandwich panels were studied.

  15. Metals and Alloys Material Stabilization Process Plan

    SciTech Connect

    RISENMAY, H.R.; BURK, R.A.

    2000-05-18

    This Plan outlines the process for brushing metal and alloys in accordance with the path forward discussed in the Integrated Project Management Plan for the Plutonium Finishing Plant Stabilization and Deactivation Project, HNF-3617, and requirements set forth in the Project Management Plan for Materials Stabilization, HNF-3605. This plan provides the basis for selection of the location to process, the processes involved, equipment to be used, and the characterization of the contents of the can. The scope of the process is from retrieval of metals and alloys from storage to transfer back to storage in a repackaged configuration.

  16. Coprecal: materials accounting in the modified process

    SciTech Connect

    Dayem, H.A.; Kern, E.A.; Shipley, J.P.

    1980-05-01

    This report presents the design and evaluation of an advanced materials accounting system for a uranium-plutonium nitrate-to-oxide coconversion facility based on the General Electric Coprecal process as modified by Savannah River Laboratory and Plant and DuPont Engineering. The modifications include adding small aliquot tanks to feed the process and reconfiguring the calciner filter systems. Diversion detection sensitivities for the modified Coprecal process are somewhat better than the original Coprecal design, but they are still significantly worse than a same-sized conversion facility based on the oxalate (III) precipitation process.

  17. Robot development for nuclear material processing

    SciTech Connect

    Pedrotti, L.R.; Armantrout, G.A.; Allen, D.C.; Sievers, R.H. Sr.

    1991-07-01

    The Department of Energy is seeking to modernize its special nuclear material (SNM) production facilities and concurrently reduce radiation exposures and process and incidental radioactive waste generated. As part of this program, Lawrence Livermore National Laboratory (LLNL) lead team is developing and adapting generic and specific applications of commercial robotic technologies to SNM pyrochemical processing and other operations. A working gantry robot within a sealed processing glove box and a telerobot control test bed are manifestations of this effort. This paper describes the development challenges and progress in adapting processing, robotic, and nuclear safety technologies to the application. 3 figs.

  18. Simulation of materials processing: Fantasy or reality?

    NASA Technical Reports Server (NTRS)

    Jenkins, Thomas J.; Bright, Victor M.

    1994-01-01

    This experiment introduces students to the application of computer-aided design (CAD) and analysis of materials processing in the context of integrated circuit (IC) fabrication. The fabrication of modern IC's is a complex process which consists of several sequential steps. These steps involve the precise control of processing variables such as temperature, humidity, and ambient gas composition. In essence, the particular process employed during the fabrication becomes a 'recipe'. Due to economic and other considerations, CAD is becoming an indispensable part of the development of new recipes for IC fabrication. In particular, this experiment permits the students to explore the CAD of the thermal oxidation of silicon.

  19. Long term materials test program. Quarterly report, April-June 1983

    SciTech Connect

    Not Available

    1984-01-01

    Corrosion and erosion/corrosion testing of gas turbine materials in the effluent from a pressurized fluidized bed coal combustor continues under the Long Term Materials Test program. Two 1000-hour erosion/corrosion screening tests of twelve candidate gas turbine vane and blade base alloys and a variety of protective coating systems have been completed. Test conditions included 1350/sup 0/F, 800 to 900 ft/s and particulate loadings of 30 to 90 ppM. Erosion/corrosion degradation rates of 1 to 4 mils/1000 hours were observed with corrosion predominant in areas of particle impaction. FeCrAlY, CoCrAlY and rhodium aluminide coatings show significantly better resistance to degradation than unprotected base alloys, aluminide or platinum-aluminide diffusion coatings.

  20. Thermoplastics as engineering materials: The mechanics, materials, design, processing link

    SciTech Connect

    Stokes, V.K.

    1995-10-01

    While the use of plastics has been growing at a significant pace because of weight reduction, ease of fabrication of complex shapes, and cost reduction resulting from function integration, the engineering applications of plastics have only become important in the past fifteen years. An inadequate understanding of the mechanics issues underlying the close coupling among the design, the processing (fabrication), and the assembly with these materials is a barrier to their use in structural applications. Recent progress on some issues relating to the engineering uses of plastics is surveyed, highlighting the need for a better understanding of plastics and how processing affects the performance of plastic parts. Topics addressed include the large deformation behavior of ductile resins, fiber orientation in chopped-fiber filled materials, structural foams, random glass mat composites, modeling of thickness distributions in blow-molded and thermoformed parts, dimensional stability (shrinkage, warpage, and residual stresses) in injection-molded parts, and welding of thermoplastics.

  1. Heat accumulation during pulsed laser materials processing.

    PubMed

    Weber, Rudolf; Graf, Thomas; Berger, Peter; Onuseit, Volkher; Wiedenmann, Margit; Freitag, Christian; Feuer, Anne

    2014-05-01

    Laser materials processing with ultra-short pulses allows very precise and high quality results with a minimum extent of the thermally affected zone. However, with increasing average laser power and repetition rates the so-called heat accumulation effect becomes a considerable issue. The following discussion presents a comprehensive analytical treatment of multi-pulse processing and reveals the basic mechanisms of heat accumulation and its consequence for the resulting processing quality. The theoretical findings can explain the experimental results achieved when drilling microholes in CrNi-steel and for cutting of CFRP. As a consequence of the presented considerations, an estimate for the maximum applicable average power for ultra-shorts pulsed laser materials processing for a given pulse repetition rate is derived.

  2. Materials evaluation for a transuranic processing facility

    SciTech Connect

    Barker, S.A., Schwenk, E.B. ); Divine, J.R. )

    1990-11-01

    The Westinghouse Hanford Company, with the assistance of the Pacific Northwest Laboratory, is developing a transuranium extraction process for preheating double-shell tank wastes at the Hanford Site to reduce the volume of transuranic waste being sent to a repository. The bench- scale transuranium extraction process development is reaching a stage where a pilot plant design has begun for the construction of a facility in the existing B Plant. Because of the potential corrosivity of neutralized cladding removal waste process streams, existing embedded piping alloys in B Plant are being evaluated and new'' alloys are being selected for the full-scale plant screening corrosion tests. Once the waste is acidified with HNO{sub 3}, some of the process streams that are high in F{sup {minus}} and low in Al and zr can produce corrosion rates exceeding 30,000 mil/yr in austenitic alloys. Initial results results are reported concerning the applicability of existing plant materials to withstand expected process solutions and conditions to help determine the feasibility of locating the plant at the selected facility. In addition, process changes are presented that should make the process solutions less corrosive to the existing materials. Experimental work confirms that Hastelloy B is unsatisfactory for the expected process solutions; type 304L, 347 and 309S stainless steels are satisfactory for service at room temperature and 60{degrees}C, if process stream complexing is performed. Inconel 625 was satisfactory for all solutions. 17 refs., 5 figs., 8 tabs.

  3. Analytical and experimental studies for thermal plasma processing of materials

    NASA Astrophysics Data System (ADS)

    Work continued on thermal plasma processing of materials. This quarter, ceramic powders of carbides, aluminum nitride, oxides, solids solutions, magnetic and non magnetic spinels, superconductors, and composites have been successfully synthesized in a Triple DC Torch Plasma Jet Reactor (TTPR) and in a single DC Plasma Jet Reactor. All the ceramic powders with the exception of AIN were synthesized using a novel injection method developed to overcome the problems associated with solid injection, in particular for the single DC plasma jet reactor, and to realize the benefits of gas phase reactions. Also, initial experiments have been performed for the deposition of diamond coatings on Si wafers using the TTPR with methane as the carbon source. Well faceted diamond crystallites were deposited on the surface of the wafers, forming a continuous one particle thick coating. For measuring temperature and velocity fields in plasma systems, enthalpy probes have been developed and tested. The validity has been checked by performing energy and mass flux balances in an argon plasma jet operated in argon atmosphere. Total Gibbs free energy minimization calculations using a quasi-equilibrium modification have been applied to simulate several chemical reactions. Plasma reactor modelling has been performed for the counter-flow liquid injection plasma synthesis experiment. Plasma diagnostics has been initiated to determine the pressure gradient in the coalesced part of the plasma jet. The pressure gradient drives the diffusion of chemical species which ultimately controls the chemical reactions.

  4. Applications of membrane processes for in-process materials recycling

    SciTech Connect

    Kim, B.M.; Thornton, R.F.; Shapiro, A.P.; Freshour, A.R.; El-Shoubary, Y.

    1996-12-31

    Zero discharge of wastes should be the ultimate goal of manufacturers. Waste reduction lowers costs and lessens liability associated with plant effluents. One approach toward this goal is elimination or minimization of wastes by in-process recycling of waste materials. We have examined opportunities for waste minimization for many equipment manufacturing plants and have evaluated membrane processes for in-process recycling. Membrane processes evaluated include vibrating membranes for suspended solid removal, ion exchange membranes for acid recovery, reverse osmosis and electrodialysis for dissolved salt removal, microporous membranes for recycling of machining coolants, oil emulsions, alkaline cleaners and others. This paper presents several examples of evaluations of membrane processes for materials recycling in manufacturing plants. 5 figs., 1 tab.

  5. Coal combustion: Effect of process conditions on char reactivity. Quarterly technical report, January 1, 1995--March 31, 1995

    SciTech Connect

    Zygourakis, K.

    1995-08-01

    The project will quantify the effect of the following pyrolysis conditions on the macropore structure and on the subsequent reactivity of chars: (a) pyrolysis heating rate; (b) final heat treatment temperature (HTT); (c) duration of heat treatment at HTT (or soak time); (d) pyrolysis atmosphere (N{sub 2} or O{sub 2}/N{sub 2} mixtures); (e) coal particle size (100--1000 {mu}m in diameter); (f) sulfur-capturing additives (limestone); and (g) coal rank. Pyrolysis experiments will be carried out for three coals from the Argonne collection: (1) a high-volatile bituminous coal with high ash content (Illinois {number_sign}6), (2) a bituminous coal with low ash content (Utah Blind Canyon) and (3) a lower rank subbituminous coal (Wyodak-Anderson seam). A systematic study was carried out in the past quarter to validate the mathematical model for ignition phenomena presented in the previous quarterly report. Model predictions of the effect of pyrolysis heating rate, particle size, and oxygen concentration on ignition behavior are in excellent agreement with experimental results. Moreover, our results show that the model can be used to estimate the particle temperature during ignition and the minimum ignition temperature for various process conditions.

  6. Alternative starting materials for industrial processes.

    PubMed Central

    Mitchell, J W

    1992-01-01

    In the manufacture of chemical feedstocks and subsequent processing into derivatives and materials, the U.S. chemical industry sets the current standard of excellence for technological competitiveness. This world-class leadership is attributed to the innovation and advancement of chemical engineering process technology. Whether this status is sustained over the next decade depends strongly on meeting increasingly demanding challenges stimulated by growing concerns about the safe production and use of chemicals without harmful impacts on the environment. To comply with stringent environmental regulations while remaining economically competitive, industry must exploit alternative benign starting materials and develop environmentally neutral industrial processes. Opportunities are described for development of environmentally compatible alternatives and substitutes for some of the most abundantly produced, potentially hazardous industrial chemicals now labeled as "high-priority toxic chemicals." For several other uniquely important commodity chemicals where no economically competitive, environmentally satisfactory, nontoxic alternative starting material exists, we advocate the development of new dynamic processes for the on-demand generation of toxic chemicals. In this general concept, which obviates mass storage and transportation of chemicals, toxic raw materials are produced in real time, where possible, from less-hazardous starting materials and then chemically transformed immediately into the final product. As a selected example for semiconductor technology, recent progress is reviewed for the on-demand production of arsine in turnkey electrochemical generators. Innovation of on-demand chemical generators and alternative processes provide rich areas for environmentally responsive chemical engineering processing research and development for next-generation technology. Images PMID:11607260

  7. Utilization of lightweight materials made from coal gasification slags. Quarterly report, September 1--November 30, 1997

    SciTech Connect

    1997-12-31

    In previous projects, Praxis investigated the utilization of as-generated slags for a wide variety of applications in road construction, cement and concrete production, agricultural applications, and as a landfill material. From these studies, the authors found that it would be extremely difficult for as-generated slag to find large-scale acceptance in the marketplace even at no cost because the materials it could replace were abundantly available at very low cost. It became apparent that a more promising approach would be to develop a variety of value-added products from slag that meet specific industry requirements. This approach was made feasible by the discovery that slag undergoes expansion and forms a lightweight material when subjected to controlled heating in a kiln at temperatures between 1,400 and 1,700 F. These results confirmed the potential for using expanded slag as a substitute for conventional lightweight aggregates (LWA). The technology to produce lightweight and ultra-lightweight aggregates (ULWA) from slag was subsequently developed by Praxis. The major objectives of the subject project are to demonstrate the technical and economic viability of commercial production of LWA and ULWA from slag and to test the suitability of these aggregates for various applications. The project goals are to be accomplished in two phases: Phase 1, comprising the production of LWA and ULWA from slag at the large pilot scale, and Phase 2, which involves commercial evaluation of these aggregates in a number of applications. This document summarizes the Phase 2 accomplishments to date along with the major accomplishments from Phase 1.

  8. Plasma characterization studies for materials processing

    SciTech Connect

    Pfender, E.; Heberlein, J.

    1995-12-31

    New applications for plasma processing of materials require a more detailed understanding of the fundamental processes occurring in the processing reactors. We have developed reactors offering specific advantages for materials processing, and we are using modeling and diagnostic techniques for the characterization of these reactors. The emphasis is in part set by the interest shown by industry pursuing specific plasma processing applications. In this paper we report on the modeling of radio frequency plasma reactors for use in materials synthesis, and on the characterization of the high rate diamond deposition process using liquid precursors. In the radio frequency plasma torch model, the influence of specific design changes such as the location of the excitation coil on the enthalpy flow distribution is investigated for oxygen and air as plasma gases. The diamond deposition with liquid precursors has identified the efficient mass transport in form of liquid droplets into the boundary layer as responsible for high growth, and the chemical properties of the liquid for the film morphology.

  9. Design and fabrication of advanced materials from Illinois coal wastes. Quarterly report, 1 December 1994--28 February 1995

    SciTech Connect

    Malhotra, V.M.; Wright, M.A.

    1995-12-31

    The main goal of this project is to develop a bench-scale procedure to design and fabricate advanced brake and structural composite materials from Illinois coal combustion residues. During the first two quarters of the project, the thrust of the work directed towards characterizing the various coal combustion residues and FGD residue, i.e., scrubber sludge. Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), differential thermal analysis (DTA), and transmission-Fourier transform infrared (FTIR) were conducted on PCC fly ash (Baldwin), FBC fly ash (ADK unit l-6), FBC fly ash (S.I. coal), FBC spent bed ash (ADM, unit l-6), bottom ash, and scrubber sludge (CWLP) residues to characterize their geometrical shapes, mineral phases, and thermal stability. Our spectroscopic results indicate that the scrubber sludge is mainly composed of a gypsum-like phase whose lattice structure is different from the lattice structure of conventional gypsum, and sludge does not contain hannebachite (CaSO{sub 3}.0.5H{sub 2}O) phase. Our attempts to fabricate brake frictional shoes, in the form of 1.25 inch disks, from PCC fly ash, FBC spent bed ash, scrubber sludge, coal char, iron particles, and coal tar were successful. Based on the experience gained and microscopic analyses, we have now upscaled our procedures to fabricate 2.5 inch diameter disk,- from coal combustion residues. This has been achieved. The SEM and Young`s modulus analyses of brake composites fabricated at 400 psi < Pressure < 2200 psi suggest pressure has a strong influence on the particle packing and the filling of interstices in our composites. Also, these results along with mechanical behavior of the fabricated disks lead us to believe that the combination of surface altered PCC fly ash and scrubber sludge particles, together ed ash particles are ideal for our composite materials.

  10. PREFACE: Processing, Microstructure and Performance of Materials

    NASA Astrophysics Data System (ADS)

    Chiu, Yu Lung; Chen, John J. J.; Hodgson, Michael A.; Thambyah, Ashvin

    2009-07-01

    A workshop on Processing, Microstructure and Performance of Materials was held at the University of Auckland, School of Engineering, on 8-9 April 2009. Organised by the Department of Chemical and Materials Engineering, University of Auckland, this meeting consisted of international participants and aimed at addressing the state-of-the-art research activities in processing, microstructure characterization and performance integrity investigation of materials. This two-day conference brought together scientists and engineers from New Zealand, Australia, Hong Kong, France, and the United Kingdom. Undoubtedly, this diverse group of participants brought a very international flair to the proceedings which also featured original research papers on areas such as Materials processing; Microstructure characterisation and microanalysis; Mechanical response at different length scales, Biomaterials and Material Structural integrity. There were a total of 10 invited speakers, 16 paper presentations, and 14 poster presentations. Consequently, the presentations were carefully considered by the scientific committee and participants were invited to submit full papers for this volume. All the invited paper submissions for this volume have been peer reviewed by experts in the various fields represented in this conference, this in accordance to the expected standards of the journal's Peer review policy for IOP Conference Series: Materials Science and Engineering. The works in this publication consists of new and original research as well as several expert reviews of current state-of-the art technologies and scientific developments. Knowing some of the real constraints on hard-copy publishing of high quality, high resolution images, the editors are grateful to IOP Publishing for this opportunity to have the papers from this conference published on the online open-access platform. Listed in this volume are papers on a range of topics on materials research, including Ferguson's high strain

  11. 27 CFR 18.51 - Processing material.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Processing material. 18.51 Section 18.51 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS PRODUCTION OF VOLATILE FRUIT-FLAVOR CONCENTRATE Operations § 18.51...

  12. ENVIRONMENTAL TOOLS FOR MATERIAL AND PROCESS SELECTION

    EPA Science Inventory

    A number of tools are being used within the Sustainable Technology Division of the U.S. Environmental Protection Agency to provide decision-makers with information on environmentally favorable materials and processes. These tools include LCA (Life Cycle Assessment), GREENSCOPE (...

  13. Materials processing in space: Future technology trends

    NASA Technical Reports Server (NTRS)

    Barter, N. J.

    1980-01-01

    NASA's materials processing in space- (MPS) program involves both ground and space-based research and looks to frequent and cost effective access to the space environment for necessary progress. The first generation payloads for research are under active design and development. They will be hosted by the Space Shuttle/Spacelab on Earth orbital flights in the early 1980's. hese missions will focus on the acquisition of materials behavior research data, the potential enhancement of Earth based technology, and the implementation of space based processing for specialized, high value materials. Some materials to be studied in these payloads may provide future breakthroughs for stronger alloys, ultrapure glasses, superior electronic components, and new or better chemicals. An operational 25 kW power system is expected to be operational to support sustained, systematic space processing activity beyond shuttle capability for second generation payload systems for SPACELAB and free flyer missions to study solidification and crystal growth and to process metal/alloys, glasses/ceramics, and chemicals and biologicals.

  14. Materials processing in space program support

    NASA Technical Reports Server (NTRS)

    Glicksman, Martin; Vanalstine, James M.

    1987-01-01

    Activities in support of NASA's Materials Processing in Space (MPS) program are reported. The overall task of the MPS project support contract was to provide the organization and administration of colloquiums, science reviews, workshops, technical meetings, bibliographic services, and visiting scientist programs. The research objectives and accomplishments of the University Space Research Association visiting scientist team are also summarized.

  15. Materials processing in space program tasks

    NASA Technical Reports Server (NTRS)

    Naumann, R. J. (Editor)

    1980-01-01

    The history, strategy, and overall goal of NASA's Office of Space and Terrestrial Applications program for materials processing in space are described as well as the organizational structures and personnel involved. An overview of each research task is presented and recent publications are listed.

  16. Food Processing Curriculum Material and Resource Guide.

    ERIC Educational Resources Information Center

    Louisiana State Dept. of Education, Baton Rouge.

    Intended for secondary vocational agriculture teachers, this curriculum guide contains a course outline and a resource manual for a seven-unit food processing course on meats. Within the course outline, units are divided into separate lessons. Materials provided for each lesson include preparation for instruction (student objectives, review of…

  17. Long term materials test program. Quarterly report, October-December 1983

    SciTech Connect

    Not Available

    1984-01-01

    The long-term exposure of gas turbine vane and blade base alloys and a variety of protective coating systems to the effluent from a pressurized fluidized bed coal combustor has reached 4398 hours. After 4053 hours, FeCrAlY overlay coatings and platinum/rhodium-aluminide pack diffusion coatings show excellent resistance to corrosion attack at 1500/sup 0/F. Cobalt-base coatings are somewhat more susceptible to hot corrosion, and the unprotected nickel and cobalt-base alloys are most susceptible to corrosion, although corrosion rates have decreased to less than 1 mil/1000 hours for all materials at 1500/sup 0/F; i.e., corrosion penetration data is evolving parabolically. The three-stage cyclone cleanup system became severely distorted after approximately 5600 hours total service life. Distortion of the cyclones contributed to an increased dust loading to the material test sections, 110 to 250 ppM versus normal loadings of 30 to 90 ppM, for a period of about 75 hours. This increase in dust loading caused severe erosion of the airfoils in the high-velocity test section. Metal recession ranged 4 to 18 mils of leading edge loss on the impulse airfoils, and 11 to 27 mils of leading edge loss on the reaction airfoils. A new three-stage cyclone system was installed and dust loadings now range from 15 to 45 ppM.

  18. Advanced laser processing of glass materials

    NASA Astrophysics Data System (ADS)

    Sugioka, Koji; Obata, Kotaro; Cheng, Ya; Midorikawa, Katsumi

    2003-09-01

    Three kinds of advanced technologies using lasers for glass microprocessing are reviewed. Simultaneous irradiation of vacuum ultraviolet (VUV) laser beam, which possesses extremely small laser fluence, with ultraviolet (UV) laser achieves enhanced high surface and edge quality ablation in fused silica and other hard materials with little debris deposition as well as high-speed and high-efficiency refractive index modification of fused silica (VUV-UV multiwavelength excitation processing). Metal plasma generated by the laser beam effectively assists high-quality ablation of transparent materials, resulting in surface microstructuring, high-speed holes drilling, crack-free marking, color marking, painting and metal interconnection for the various kinds of glass materials (laser-induced plasma-assisted ablation (LIPAA)). In the meanwhile, a nature of multiphoton absorption of femtosecond laser by transparent materials realizes fabrication of true three-dimensional microstructures embedded in photosensitive glass.

  19. Processing of materials for uniform field emission

    DOEpatents

    Pam, Lawrence S.; Felter, Thomas E.; Talin, Alec; Ohlberg, Douglas; Fox, Ciaran; Han, Sung

    1999-01-01

    This method produces a field emitter material having a uniform electron emitting surface and a low turn-on voltage. Field emitter materials having uniform electron emitting surfaces as large as 1 square meter and turn-on voltages as low as 16V/.mu.m can be produced from films of electron emitting materials such as polycrystalline diamond, diamond-like carbon, graphite and amorphous carbon by the method of the present invention. The process involves conditioning the surface of a field emitter material by applying an electric field to the surface, preferably by scanning the surface of the field emitter material with an electrode maintained at a fixed distance of at least 3 .mu.m above the surface of the field emitter material and at a voltage of at least 500V. In order to enhance the uniformity of electron emission the step of conditioning can be preceeded by ion implanting carbon, nitrogen, argon, oxygen or hydrogen into the surface layers of the field emitter material.

  20. Processing of materials for uniform field emission

    DOEpatents

    Pam, L.S.; Felter, T.E.; Talin, A.; Ohlberg, D.; Fox, C.; Han, S.

    1999-01-12

    This method produces a field emitter material having a uniform electron emitting surface and a low turn-on voltage. Field emitter materials having uniform electron emitting surfaces as large as 1 square meter and turn-on voltages as low as 16V/{micro}m can be produced from films of electron emitting materials such as polycrystalline diamond, diamond-like carbon, graphite and amorphous carbon by the method of the present invention. The process involves conditioning the surface of a field emitter material by applying an electric field to the surface, preferably by scanning the surface of the field emitter material with an electrode maintained at a fixed distance of at least 3 {micro}m above the surface of the field emitter material and at a voltage of at least 500V. In order to enhance the uniformity of electron emission the step of conditioning can be preceded by ion implanting carbon, nitrogen, argon, oxygen or hydrogen into the surface layers of the field emitter material. 2 figs.

  1. Utilization of lightweight materials made from coal gasification slags. Quarterly report, September 15--November 30, 1994

    SciTech Connect

    1997-07-01

    Coal gasification technologies are finding increasing commercial applications for power generation or production of chemical feedstocks. The integrated-gasification-combined-cycle (IGCC) coal conversion process has been demonstrated to be a clean, efficient, and environmentally acceptable method of generating power. However, the gasification process produces relatively large quantities of a solid waste termed slag. Regulatory trends with respect to solid waste disposal, landfill development costs, and public concern make utilization of slag a high-priority issue. Therefore, it is imperative that slag utilization methods be developed, tested, and commercialized in order to offset disposal costs. This project aims to demonstrate the technical and economic viability of the slag utilization technologies developed by Praxis to produce lightweight aggregates (LWA) and ultra-lightweight aggregates (ULWA) from slag in a large-scale pilot operation, followed by total utilization of these aggregates in a number of applications.

  2. Materials for Conoco zinc chloride hydrocracking process

    SciTech Connect

    Baylor, V.B.; Keiser, J.R.; DeVan, J.H.

    1980-01-01

    Use of zinc chloride to augment hydrogenation of coal and yield a high-octane gasoline product is the most significant feature of a coal liquefaction process being developed by Conoco Coal Development Company. The zinc chloride catalyst is regenerated in a fluidized sand bed, where the spent melt is mixed with air and hydrogen chloride at about 1000/sup 0/C. Recovery is completed at 370/sup 0/C in a condenser, where the zinc chloride is collected and the oxygen and sulfur are separated as H/sub 2/O and SO/sub 2/. The economic viability of the entire process is highly dependent on almost complete recovery of the zinc chloride. The severe environmental conditions of this recovery process cause unique materials problems. Although high-temperature oxidation and sulfidation are being studied in related programs, suitable materials to resist their combined effects along with those of chlorides have not yet been specifically addressed. Common engineering materials, such as the austenitic stainless steels and many nickel-base alloys, are unsuitable because of their inability to tolerate the elevated temperatures and sulfidation, respectively. The objectives of this task are to screen various metallic and ceramic materials for resistance to the zinc chloride recovery system environment and to determine the nature of the attack by exposing coupons to the simulated environment in the laboratory.

  3. Long term materials test program. Quarterly report, October-December 1982

    SciTech Connect

    Not Available

    1982-01-01

    Four hundred hours of long-term material testing have been completed. The PFB combustor operated at 1650/sup 0/F utilizing Pittsburgh No. 8 coal (3% sulfur, 0.06% chlorine) and Pfizer dolomite. After 285 hours, visual inspection of corrosion pins in the low velocity test section indicated that unprotected blade and vane alloys, IN-738, IN-939, U-500 and FSX-414 experienced significant corrosion attack at all three metal temperatures, 1500/sup 0/, 1300/sup 0/ and 1100/sup 0/F. Precious metal aluminide coatings showed good resistance to corrosion at 1500/sup 0/ and 1300/sup 0/F, but appeared susceptible to attack at the 1100/sup 0/F metal temperature. CoCrAlY and FeCrAlY overlay coatings were generally resistant to attack at all three temperatures, although some pitting attack was observed on CoNiCrAlY and FeCrAlY cladding at 1300/sup 0/ and 1100/sup 0/F.

  4. Long Term Materials Test Program. Quarterly report, July-September 1983

    SciTech Connect

    Not Available

    1984-04-01

    Corrosion and erosion/corrosion testing of gas turbine vane and blade base alloys and a variety of protective coating systems under the Long Term Materials Test program has surpassed 3400 hours. The PFBC facility at Malta, New York continues to show an exceptionally high degree of reliability and consistency in performance. Operating conditions include a 1650/sup 0/F bed temperature at 10 atmospheres pressures utilizing Pittsburgh No. 8 coal and a low alkali dolomite sulfur sorbent. After 2687 hours, unprotected nickel and cobalt base vane and blade alloys generally experienced corrosion rates of 1 to 2 mils/1000 hours at metal temperatures of 1100, 1300, and 1500/sup 0/F. Precious metal aluminide and MCrAlY coatings continue to show excellent corrosion resistance (<0.5 mils/1000 hrs) at 1500/sup 0/F, but are susceptible to varying degrees of pitting attack at 1100/sup 0/ and 1300/sup 0/F. Erosion/corrosion degradation rates at 800 to 900 fps., 1350/sup 0/F and less than 100 ppM dust loading ranged from 1 to 4 mils/1000 hours with corrosion predominately concentrated in areas of particle impaction indicating an erosion/corrosion synergism.

  5. Dielectric barrier discharge processing of aerospace materials

    NASA Astrophysics Data System (ADS)

    Scott, S. J.; Figgures, C. C.; Dixon, D. G.

    2004-08-01

    We report the use of atmospheric pressure, air based, dielectric barrier discharges (DBD) to treat materials commonly used in the aerospace industries. The material samples were processed using a test-bed of a conventional DBD configuration in which the sample formed one of the electrodes and was placed in close proximity to a ceramic electrode. The discharges generated a powerful, cold oxidizing environment which was able to remove organic contaminants, etch primer and paint layers, oxidize aluminium and roughen carbon fibre composites by the selective removal of resin.

  6. Early space experiments in materials processing

    NASA Technical Reports Server (NTRS)

    Naumann, R. J.

    1979-01-01

    A comprehensive survey of the flight experiments conducted in conjunction with the United States Materials Processing in Space Program is presented. Also included are a brief description of the conditions prevailing in an orbiting spacecraft and the research implications provided by this unique environment. What was done and what was learned are summarized in order to serve as a background for future experiments. It is assumed that the reader has some knowledge of the physical sciences but no background in spaceflight experimentation or in the materials science per se.

  7. Utilization of lightweight materials made from coal gasification slags. Quarterly report, March 1--May 31, 1996

    SciTech Connect

    1996-12-31

    Integrated-gasification combined-cycle (IGCC) technology is an emerging technology that utilizes coal for power generation and production of chemical feedstocks. However, the process generates large amounts of solid waste, consisting of vitrified ash (slag) and some unconverted carbon. The major objectives of the subject project are to demonstrate the technical and economic viability of commercial production of lightweight aggregates (LWA) and ultra-lightweight (ULWA) from slag and to test the suitability of these aggregates for various applications. The project goals are to be accomplished in two phases: Phase 1, comprising the production of LWA and ULWA from slag at the large pilot-scale, and Phase 2, which involves commercial evaluation of these aggregates in a number of applications. The following significant events occurred during this reporting period: testing of slag-based lightweight aggregates for roof tile and concrete applications.

  8. Utilization of lightweight materials made from coal gasification slags. Quarterly report, December 1994--February 1995

    SciTech Connect

    1995-03-01

    Integrated-gasification combined-cycle (IGCC) technology is an emerging technology that utilizes coal for power generation and production of chemical feedstocks. However, this process generates large amounts of solid waste, consisting of vitrified ash (slag) along with some unconverted carbon, which is disposed of as solid waste. The objectives of this project is to demonstrate the technical and economic viability of slag utilization technologies for commercial production of lightweight aggregates (LWA) and ultra-lightweight aggregates (ULWA) from slag and to test the suitability of these aggregates for various applications. The scheduled date for completing Phase I, which includes production of LWA and ULWA from slag at the large pilot-scale, is 14 December 1995. The scheduled start date for Phase II, which involves commercial utilization of these aggregates in a number of applications, is 15 December 1995, and the scheduled completion date of the project is 14 March 1997.

  9. Coal combustion: Effect of process conditions on char reactivity. Ninth quarterly technical report, September 1, 1992--December 1, 1993

    SciTech Connect

    Zygourakis, K.

    1993-12-31

    Our efforts during the past quarter focused on the development of an image processing technique for characterizing the macropore structure of chars produced from Illinois No. 6 coal. Pyrolysis experiments were carried out in a microscope-stage reactor in inert and reacting atmospheres and at various pyrolysis heating rates. Particles from several pyrolysis runs were embedded in an epoxy resin block and polished sections . were prepared. Digital images of char particle cross-sections were acquired and analyzed to measure the structural properties of the chars. The macropore analysis procedure is presented here in detail. Future reports will present the data showing the effects of pyrolysis conditions on the macropore structure of Illinois No. 6 chars.

  10. Investigation of the Geokinetics horizontal in situ oil shale retorting process. Quarterly report, July, August, September 1980

    SciTech Connect

    Hutchinson, D.L.

    1980-11-01

    Progress is reported by Geokinetics on the successful blasting of Retort No. 25. Preparations are described for the ignition of Retort No. 24 nearing completion. This will be the largest retort processing facility utilized to date. Meteorological data of the area was obtained for permit applications from the Utah Air Conservation Committee and the US EPA. These must be obtained before ignition of retort No. 24. Drilling for the post-burn core sampling program (Retorts No. 16 and No. 17) was completed during the quarter. Approval to inject effluent water into the Mesa Verde Formation through a deep well was obtained. Construction of a new 1 1/2 acre evaporating pond has begun. The DOE Oil Shale Task Force will aid in the environmental research program; its role is described. A new vibro-rotary hammer was tested. Drilling penetration rates increased by 35%. A patent on horizontal fracturing methods was obtained. (DMC)

  11. 76 FR 72902 - Materials Processing Equipment Technical Advisory Committee;

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-11-28

    ... Bureau of Industry and Security Materials Processing Equipment Technical Advisory Committee; Notice of Partially Closed Meeting The Materials Processing Equipment Technical Advisory Committee (MPETAC) will meet... controls applicable to materials processing equipment and related technology. Agenda Open Session...

  12. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, October 1993--December 1993

    SciTech Connect

    1994-01-30

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a {open_quotes}Coal-Fired Combustion System for Industrial Process Heating Applications{close_quotes} is a project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the past quarter, the major effort was completing the system modification installation designs, completing the TSCA ash testing, and conducting additional industry funded testing. Final detailed installation designs for the integrated test system configuration are being completed.

  13. Limited reaction processing for semiconductor materials preparation

    NASA Astrophysics Data System (ADS)

    Hoyt, J. L.

    1991-07-01

    Limited Reaction Processing (LRP) is a layer deposition technique based upon a combination of rapid thermal processing (RTP) and chemical vapor deposition. The versatility of LRP was shwon in research on epitaxial growth in three different materials systems. Research was spurred at several other laboratories in the area of epitaxial growth and applications involving RTP techniques, particularly in the Si(1-x)Ge(x) materials system. The first CVD grown Si/Si(1-x)Ge(x) heterojunction bipolar transistors were fabricated using this technique, with maximum oscillation frequencies on the order of 40 GHz. In the III-V area, arsine alternative sources were explored for GaAs expitaxy which greatly improve the safety of MOCVD. A new atomic layer growth technique was developed by combining LRP with an alternating gas pulse method.

  14. Tubular filamentation for laser material processing

    PubMed Central

    Xie, Chen; Jukna, Vytautas; Milián, Carles; Giust, Remo; Ouadghiri-Idrissi, Ismail; Itina, Tatiana; Dudley, John M.; Couairon, Arnaud; Courvoisier, Francois

    2015-01-01

    An open challenge in the important field of femtosecond laser material processing is the controlled internal structuring of dielectric materials. Although the availability of high energy high repetition rate femtosecond lasers has led to many advances in this field, writing structures within transparent dielectrics at intensities exceeding 1013 W/cm2 has remained difficult as it is associated with significant nonlinear spatial distortion. This letter reports the existence of a new propagation regime for femtosecond pulses at high power that overcomes this challenge, associated with the generation of a hollow uniform and intense light tube that remains propagation invariant even at intensities associated with dense plasma formation. This regime is seeded from higher order nondiffracting Bessel beams, which carry an optical vortex charge. Numerical simulations are quantitatively confirmed by experiments where a novel experimental approach allows direct imaging of the 3D fluence distribution within transparent solids. We also analyze the transitions to other propagation regimes in near and far fields. We demonstrate how the generation of plasma in this tubular geometry can lead to applications in ultrafast laser material processing in terms of single shot index writing, and discuss how it opens important perspectives for material compression and filamentation guiding in atmosphere. PMID:25753215

  15. Tubular filamentation for laser material processing

    NASA Astrophysics Data System (ADS)

    Xie, Chen; Jukna, Vytautas; Milián, Carles; Giust, Remo; Ouadghiri-Idrissi, Ismail; Itina, Tatiana; Dudley, John M.; Couairon, Arnaud; Courvoisier, Francois

    2015-03-01

    An open challenge in the important field of femtosecond laser material processing is the controlled internal structuring of dielectric materials. Although the availability of high energy high repetition rate femtosecond lasers has led to many advances in this field, writing structures within transparent dielectrics at intensities exceeding 1013 W/cm2 has remained difficult as it is associated with significant nonlinear spatial distortion. This letter reports the existence of a new propagation regime for femtosecond pulses at high power that overcomes this challenge, associated with the generation of a hollow uniform and intense light tube that remains propagation invariant even at intensities associated with dense plasma formation. This regime is seeded from higher order nondiffracting Bessel beams, which carry an optical vortex charge. Numerical simulations are quantitatively confirmed by experiments where a novel experimental approach allows direct imaging of the 3D fluence distribution within transparent solids. We also analyze the transitions to other propagation regimes in near and far fields. We demonstrate how the generation of plasma in this tubular geometry can lead to applications in ultrafast laser material processing in terms of single shot index writing, and discuss how it opens important perspectives for material compression and filamentation guiding in atmosphere.

  16. Tubular filamentation for laser material processing.

    PubMed

    Xie, Chen; Jukna, Vytautas; Milián, Carles; Giust, Remo; Ouadghiri-Idrissi, Ismail; Itina, Tatiana; Dudley, John M; Couairon, Arnaud; Courvoisier, Francois

    2015-01-01

    An open challenge in the important field of femtosecond laser material processing is the controlled internal structuring of dielectric materials. Although the availability of high energy high repetition rate femtosecond lasers has led to many advances in this field, writing structures within transparent dielectrics at intensities exceeding 10(13) W/cm(2) has remained difficult as it is associated with significant nonlinear spatial distortion. This letter reports the existence of a new propagation regime for femtosecond pulses at high power that overcomes this challenge, associated with the generation of a hollow uniform and intense light tube that remains propagation invariant even at intensities associated with dense plasma formation. This regime is seeded from higher order nondiffracting Bessel beams, which carry an optical vortex charge. Numerical simulations are quantitatively confirmed by experiments where a novel experimental approach allows direct imaging of the 3D fluence distribution within transparent solids. We also analyze the transitions to other propagation regimes in near and far fields. We demonstrate how the generation of plasma in this tubular geometry can lead to applications in ultrafast laser material processing in terms of single shot index writing, and discuss how it opens important perspectives for material compression and filamentation guiding in atmosphere. PMID:25753215

  17. Materials processing in space program tasks

    NASA Technical Reports Server (NTRS)

    Mckannan, E. C. (Editor)

    1978-01-01

    A list of active research tasks as of the end of 1978 of the Materials Processing in Space Program of the Office of Space and Terrestrial Applications, involving several NASA Centers and other organizations is reported. An overview of the program scope for managers and scientists in industry, university and government communities is provided. The program, its history, strategy and overall goal; the organizational structures and people involved; and each research task are described. Tasks are categorized by ground based research according to four process areas. Cross references to the performing organizations and principal investigators are provided.

  18. Computational Modeling in Structural Materials Processing

    NASA Technical Reports Server (NTRS)

    Meyyappan, Meyya; Arnold, James O. (Technical Monitor)

    1997-01-01

    High temperature materials such as silicon carbide, a variety of nitrides, and ceramic matrix composites find use in aerospace, automotive, machine tool industries and in high speed civil transport applications. Chemical vapor deposition (CVD) is widely used in processing such structural materials. Variations of CVD include deposition on substrates, coating of fibers, inside cavities and on complex objects, and infiltration within preforms called chemical vapor infiltration (CVI). Our current knowledge of the process mechanisms, ability to optimize processes, and scale-up for large scale manufacturing is limited. In this regard, computational modeling of the processes is valuable since a validated model can be used as a design tool. The effort is similar to traditional chemically reacting flow modeling with emphasis on multicomponent diffusion, thermal diffusion, large sets of homogeneous reactions, and surface chemistry. In the case of CVI, models for pore infiltration are needed. In the present talk, examples of SiC nitride, and Boron deposition from the author's past work will be used to illustrate the utility of computational process modeling.

  19. Salmonella prevalence and characterization in a free-range pig processing plant: tracking in trucks, lairage, slaughter line and quartering.

    PubMed

    Hernández, Manuela; Gómez-Laguna, Jaime; Luque, Inmaculada; Herrera-León, Silvia; Maldonado, Alfonso; Reguillo, Lucía; Astorga, Rafael J

    2013-03-01

    New consumer tendencies are focused on products derived from systems which allow both a high animal welfare condition and a high food safety level. However, sometimes animal welfare regulations make the adoption of adequate bio-security measures difficult, representing a barrier for animal health and food safety. Thus the aim of this study was to determine the prevalence of Salmonella at different points of the pig slaughtering process (Trucks, Lairage, Slaughter line and Quartering, TLSQ) from pigs reared in free-range systems. From eight samplings a total of 126 Salmonella isolates out of 1160 different samples were recovered (10.86%). The highest percentage of isolates was detected at the points of pre-scalding (29/80, 36.25%), trucks (13/56, 23.21%), cecal contents (17/80, 21.25%), tonsils (14/80, 17.50%), ileocecal lymph nodes (13/80, 16.25%) and lairage (9/64, 14.06%). Furthermore, eighteen isolates were obtained from different environmental samples from slaughter line and quartering plant (knives and surface of tables) (5.63%) and three isolates at the quartering plant samples (ham, shoulder and loin) (3.75%). Fourteen different serotypes were isolated: Bredeney, Rissen, Derby, Typhimurium, Montevideo, Israel, Anatum, Emek, Monophasic Salmonella Typhimurium (mST), Choleraesuis, Durban, Kentucky, London and Sandiego. S. Typhimurium phage types U311, 193, 104b and UT were identified. Moreover, mST strain was phage typed as U311. From TLSQ1, TLSQ2 and TLSQ4, different strains of S. Derby, S. Rissen and S. Bredeney serotypes were isolated from pig and environmental samples, pointing to a potential cross contamination. Molecular typing (Pulsed-Field Gel Electrophoresis, PFGE) of these strains confirmed the cross contamination. In the remaining samplings, different serotypes were obtained in each sampled point of the chain, assuming that the isolated serotypes belonged to different epidemiological origins. Our results show the isolation of different serotypes of

  20. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1993--June 1993

    SciTech Connect

    Not Available

    1993-07-30

    Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a ``Coal-Fired Combustion System for Industrial Process Heating Applications`` is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the past quarter, the designs of the remaining major components of the integrated system were completed and the equipment was ordered. DOE has elected to modify the scope of the existing R&D program being conducted under this contract to include testing of a simulated TSCA incinerator ash. The modification will be in the form of an additional Task (Task 8 -- TSCA Ash Testing) to the original Statement of Work.

  1. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, April 1--June 30, 1995

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1995-09-01

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. The paper describes activities carried out this quarter. 11 refs., 21 figs., 17 tabs.

  2. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, January 1, through March 31, 1995

    SciTech Connect

    1995-05-01

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. Accomplishments for this quarter are described.

  3. Simple process for building large homogeneous adaptable retarders made from polymeric materials.

    PubMed

    Delplancke, F; Sendrowicz, H; Bernaerd, R; Ebbeni, J

    1995-06-01

    A process for building large, homogeneous, adaptable retarders easily and at low cost is proposed and analyzed. This method is based on the properties of high polymers to present variable birefringence as a function of applied stresses and on the possibility of freezing these stresses inside the material by a thermal process. Various geometries for the applied forces make obtaining a large range of birefringence profiles possible. In the process that we describe composed bending leads to a linear birefringence profile. The superimposition of two pieces with identical profiles with opposite directions gives homogeneous constant retardation. This retardation can be adjusted by a relative displacement between the pieces. A precision of better than 1% over large areas (more than 3 cm in diameter) for a quarter-wave value has been obtained. The correct choice of material makes many applications possible with a large range of wavelengths.

  4. Femtosecond laser processing of fuel injectors - a materials processing evaluation

    SciTech Connect

    Stuart, B C; Wynne, A

    2000-12-16

    Lawrence Livermore National Laboratory (LLNL) has developed a new laser-based machining technology that utilizes ultrashort-pulse (0.1-1.0 picosecond) lasers to cut materials with negligible generation of heat or shock. The ultrashort pulse laser, developed for the Department of Energy (Defense Programs) has numerous applications in operations requiring high precision machining. Due to the extremely short duration of the laser pulse, material removal occurs by a different physical mechanism than in conventional machining. As a result, any material (e.g., hardened steel, ceramics, diamond, silicon, etc.) can be machined with minimal heat-affected zone or damage to the remaining material. As a result of the threshold nature of the process, shaped holes, cuts, and textures can be achieved with simple beam shaping. Conventional laser tools used for cutting or high-precision machining (e.g., sculpting, drilling) use long laser pulses (10{sup -8} to over 1 sec) to remove material by heating it to the melting or boiling point (Figure 1.1a). This often results in significant damage to the remaining material and produces considerable slag (Figure 1.2a). With ultrashort laser pulses, material is removed by ionizing the material (Figure 1.1b). The ionized plasma expands away from the surface too quickly for significant energy transfer to the remaining material. This distinct mechanism produces extremely precise and clean-edged holes without melting or degrading the remaining material (Figures 1.2 and 1.3). Since only a very small amount of material ({approx} <0.5 microns) is removed per laser pulse, extremely precise machining can be achieved. High machining speed is achieved by operating the lasers at repetition rates up to 10,000 pulses per second. As a diagnostic, the character of the short-pulse laser produced plasma enables determination of the material being machined between pulses. This feature allows the machining of multilayer materials, metal on metal or metal on

  5. Process Research of Polycrystalline Silicon Material (PROPSM)

    NASA Technical Reports Server (NTRS)

    Culik, J. S.

    1984-01-01

    A passivation process (hydrogenation) that will improve the power generation of solar cells fabricated from presently produced, large grain, cast polycrystalline silicon (Semix), a potentially low cost material are developed. The first objective is to verify the operation of a DC plasma hydrogenation system and to investigate the effect of hydrogen on the electrical performance of a variety of polycrystalline silicon solar cells. The second objective is to parameterize and optimize a hydrogenation process for cast polycrystalline silicon, and will include a process sensitivity analysis. The sample preparation for the first phase is outlined. The hydrogenation system is described, and some early results that were obtained using the hydrogenation system without a plasma are summarized. Light beam induced current (LBIC) measurements of minicell samples, and their correlation to dark current voltage characteristics, are discussed.

  6. Materials processing in space program tasks

    NASA Technical Reports Server (NTRS)

    Pentecost, E. (Compiler)

    1982-01-01

    Active research areas as of the end of the fiscal year 1982 of the Materials Processing in Space Program, NASA-Office of Space and Terrestrial Applications, involving several NASA centers and other organizations are highlighted to provide an overview of the program scope for managers and scientists in industry, university, and government communities. The program is described as well as its history, strategy and overall goal; the organizational structures and people involved are identified and each research task is described together with a list of recent publications. The tasks are grouped into four categories: crystal growth; solidification of metals, alloys, and composites; fluids, transports, and chemical processes; and ultrahigh vacuum and containerless processing technologies.

  7. Processes and Materials for Organic Photovoltaics

    NASA Astrophysics Data System (ADS)

    Cox, Marshall

    The field of organic photovoltaics is driven by the desire for better and cheaper solar cells. While showing much promise, current generations of organic photovoltaic (OPV) devices do not exhibit properties that are suited for wide scale commercialization. While much research has been dedicated towards this goal, more yet needs to be done before it can be clear whether this is an achievable goal. This thesis describes new materials investigations for higher efficiency better stability organic photovoltaics, as well as new processes that broaden the application and fabrication space for these devices. The application of electro-polymerization, a deposition process, towards organic thin-film fabrication is discussed. This novel process for OPVs is followed by an analysis of new and interesting materials for OPV devices, including a higher efficiency hole-transporting material, and two hole-transporting molecules that exhibit self-assembly during OPV fabrication. The results of these investigations indicate the possibility for increased fabrication freedom and control, molecular species design that could allow higher efficiency devices, as well as indications of the role that molecular interactions in OPV heterojunctions play. In addition, the possibilities of integrating graphene, the two-dimensional form of carbon, into OPV architectures is discussed. A new process for graphene transfer that allows the integration of graphene into chemically and physically more fragile systems including those composed of small molecule semiconductors is described and experimentally verified. Graphene is then integrated as a cathode in OPVs, and a modeling and experimental investigation is performed to evaluate the potential for integrating graphene as a recombination layer in tandem OPVs. Based on this investigation, the integration of graphene into tandem OPVs could enable higher efficiency devices and significantly broadened architectural freedom for tandem fabrication.

  8. Short-pulse laser materials processing

    SciTech Connect

    Stuart, B.C.; Perry, M.D.; Myers, B.R.; Banks, P.S.; Honea, E.C.

    1997-06-18

    While there is much that we have learned about materials processing in the ultrashort-pulse regime, there is an enormous amount that we don`t know. How short does the pulse have to be to achieve a particular cut (depth, material, quality)? How deep can you cut? What is the surface roughness? These questions are clearly dependent upon the properties of the material of interest along with the short-pulse interaction physics. From a technology standpoint, we are asked: Can you build a 100 W average power system ? A 1000 W average power system? This proposal seeks to address these questions with a combined experimental and theoretical program of study. Specifically, To develop an empirical database for both metals and dielectrics which can be used to determine the pulse duration and wavelength necessary to achieve a specific machining requirement. To investigate Yb:YAG as a potential laser material for high average power short-pulse systems both directly and in combination with titanium doped sapphire. To develop a conceptual design for a lOOW and eventually 5OOW average power short-pulse system.

  9. Manned Spacecraft Requirements for Materials and Processes

    NASA Technical Reports Server (NTRS)

    Vaughn, Timothy P.

    2006-01-01

    A major cause of project failure can be attributed to an emphasized focus on end products and inadequate attention to resolving development risks during the initial phases of a project. The initial phases of a project, which we will call the "study period", are critical to determining project scope and costs, and can make or break most projects. If the requirements are not defined adequately, how can the scope be adequately determined, also how can the costs of the entire project be effectively estimated, and how can the risk of project success be accurately assessed? Using the proper material specifications and standards and incorporating these specifications and standards in the design process should be considered inherently crucial to the technical success of a project as just as importantly, crucial to the cost and schedule success. This paper will intertwine several important aspects or considerations for project success: 1) Characteristics of a "Good Material Requirement"; 2) Linking material requirements to the implementation of "Design for Manufacturing"; techniques and 3) The importance of decomposing materials requirements during the study phase/development phase to mitigate project risk for the maturation of technologies before the building of hardware.

  10. Development of the Selective Hydrophobic Coagulation process. Fifth quarterly technical progress report, October 1, 1992--December 30, 1992

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.

    1992-12-31

    A novel technique for selectively coagulating and separating coal from dispersed mineral matter has been developed at Virginia Tech. The process, Selective Hydrophobic Coagulation (SHC), has been studied since 1986 under the sponsorship of the US Department of Energy (Contracts AC22-86PC91221 and AC22-90PC90174). The SHC process differs from oil agglomeration, shear or polymer flocculation, and electrolytic coagulation processes in that it does not require reagents or additives to induce the formation of coagula. In most cases, simple pH control is all that is required to (1) induce the coagulation of coal particles and (2) effectively disperse particles of mineral matter. If the coal is oxidized, a small dosage of reagents can be used to enhance the process. During the quarter, the Anutech Mark IV surface force apparatus was used to generate surface force-distance data for the mica/dodecylamine hydrochloride system (Task 2.1.1). Work to characterize the hydrophobicity of this system and the mica/DDOA{sup {minus}} system was also initiated (Task 2.1.2). In Task 3, the mixing/coagulation characteristics of a small Kenics static mixer/agitation system have been investigated (Task 3.2.1), a lamella thickener for the recovery of coagula has been built (Task 3.3.1), and the test program for the recovery of coagula by column flotation has been initiated (Task 3.3.4).

  11. Development of the selective hydrophobic coagulation process. Fourth quarterly technical progress report, July 1, 1992--September 30, 1992

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.

    1992-12-31

    A novel technique for selectively coagulating and separating coal from dispersed mineral matter has been developed at Virginia Tech. The process, Selective Hydrophobic Coagulation (SHC), has been studied since 1986 under the sponsorship of the US Department of Energy. The SHC process differs from oil agglomeration, shear or polymer flocculation, and electrolytic coagulation processes in that it does not require reagents or additives to induce the formation of coagula. In most cases, simple pH control is all that is required to (i) induce the coagulation of coal particles and (ii) effectively disperse particles of mineral matter. If the coal is oxidized, a small dosage of reagents can be used to enhance the process. The technical work program was initiated on July 1, 1992. Force-distance curves were generated for DDOA Br-coated mica surfaces in water and used to calculate hydrophobicity constants and decay lengths for this system; and a new device for the measurement of water contact angles, similar to the Wilhelmy plate balance, has been built 225 kg samples of Pittsburgh No. 8 and Elkhom No. 3 seam coals were obtained; a static mixer test facility for the study of coagula growth was set up and was undergoing shakedown tests at the end of the quarter; a bench-scale lamella thickener was being constructed; and preliminary coagula/ mineral separation tests were being conducted in a bench-scale continuous drum filter.

  12. Development of the Selective Hydrophobic Coagulation process. Seventh quarterly technical progress report, April 1, 1993--June 30, 1993

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.

    1993-11-01

    A novel technique for selectively coagulating and separating coal from dispersed mineral matter has been developed at Virginia Tech. The process, known as Selective Hydrophobic Coagulation (SHC), has been studied under the sponsorship of the US Department of Energy since 1986 (Contracts DE-AC22-86PC91221 and DE-AC22-90PC90174). The SHC process differs from oil agglomeration, shear flocculation, polymer flocculation, and electrolytic coagulation processes in that it does not require reagents or additives to induce the formation of coagula. Often, simple pH control is all that is required to (i) induce the coagulation of coal particles, and (ii) effectively disperse particles of mineral matter. When the coal is superficially oxidized, a small dosage of reagents may be used to promote coagulation. During the quarter, work was completed on the development of the hydrophobic interaction energy function (Subtask 2.1) and the extended DLVO equation (Subtask 2.2.). Work to predict optimum operating conditions using the extended DLVO equation (Subtask 2.3) is underway. In Task 3 -- Process Development, work was completed on the study to determine the effect of mixing on coagula growth (Subtask 3.2) and on the use of column flotation for the recovery of coal coagula (subtask 3.3.4). Work is underway on the use of the lamella thickener and filter for the recovery of coagula (Subtasks 3.3.1 and 3.3.2).

  13. Development of the selective hydrophobic coagulation process. Tenth quarterly technical progress report, January 1, 1994--March 31, 1994

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.

    1994-08-01

    A novel technique for selectively coagulating and separating coal from dispersed mineral matter has been developed at Virginia Tech. The process, known as Selective Hydrophobic Coagulation (SHC), has been studied since 1986. The SHC process differs from oil agglomeration, shear flocculation, polymer flocculation, and electrolytic coagulation processes in that it does not require reagents or additives to induce the formation of coagula. Often, simple pH control is all that is required to (1) induced the coagulation of coal particles, and (2) effectively disperse particles of mineral matter. When the coal is superficially oxidized, a small dosage of reagents may be used to promote coagulation. During the past quarter, calculations were carried out under Subtask 2.3 (Predicting Optimum Conditions Using the Extended DLVO Equation) to explain the selectivity window that occurs between pH 7--9 in the SHC process. These calculations suggest that particle interactions involving the edge surfaces of clay are the most important, while interactions involving silica and face surfaces of clay are not as important. Experiments were also continued under Subtask 3.3 (Advanced Separation Methods) to investigate the performance of a centrifuge for separating hydrophobic coagula from dispersed mineral matter. These tests show that coagula recovery increases with centrifugal field strength and decreases with solids content and feed flow rate. Work is now in progress to evaluate the performance of a vacuum filter for coagula recovery.

  14. Cibachrome testing. [photographic processing and printing materials

    NASA Technical Reports Server (NTRS)

    Weinstein, M. S.

    1974-01-01

    The use of Cibachrome products as a solution to problems encountered when contact printing Kodak film type SO-397 onto Kodak Ektrachrome color reversal paper type 1993 is investigated. A roll of aerial imagery consisting of Kodak film types SO-397 and 2443 was contact printed onto Cibachrome and Kodak materials and compared in terms of color quality, resolution, cost, and compatibility with existing equipment and techniques. Objective measurements are given in terms of resolution and sensitometric response. Comparison prints and transparencies were viewed and ranked according to overall quality and aesthetic appeal. It is recommended that Cibachrome Print material be used in place of Kodak Ektachrome paper because it is more easily processed, the cost is equivalent, and it provides improved resolution, color quality, and image fade resistance.

  15. Skylab materials processing facility experiment developer's report

    NASA Technical Reports Server (NTRS)

    Parks, P. G.

    1975-01-01

    The development of the Skylab M512 Materials Processing Facility is traced from the design of a portable, self-contained electron beam welding system for terrestrial applications to the highly complex experiment system ultimately developed for three Skylab missions. The M512 experiment facility was designed to support six in-space experiments intended to explore the advantages of manufacturing materials in the near-zero-gravity environment of Earth orbit. Detailed descriptions of the M512 facility and related experiment hardware are provided, with discussions of hardware verification and man-machine interfaces included. An analysis of the operation of the facility and experiments during the three Skylab missions is presented, including discussions of the hardware performance, anomalies, and data returned to earth.

  16. Down Select Report of Chemical Hydrogen Storage Materials, Catalysts, and Spent Fuel Regeneration Processes - May 2008

    SciTech Connect

    Ott, Kevin C.; Linehan, Sue; Lipiecki, Frank; Christopher, Aardahl L.

    2008-05-12

    Chemical Hydrogen Storage Center of Excellence FY2008 Second Quarter Milestone Report: Technical report describing assessment of hydrogen storage materials and progress towards meeting DOE’s hydrogen storage targets.

  17. 2010 Membranes: Materials & Processes Gordon Research Conference

    SciTech Connect

    Jerry Lin

    2010-07-30

    The GRC series on Membranes: Materials and Processes have gained significant international recognition, attracting leading experts on membranes and other related areas from around the world. It is now known for being an interdisciplinary and synergistic meeting. The next summer's edition will keep with the past tradition and include new, exciting aspects of material science, chemistry, chemical engineering, computer simulation with participants from academia, industry and national laboratories. This edition will focus on cutting edge topics of membranes for addressing several grand challenges facing our society, in particular, energy, water, health and more generally sustainability. During the technical program, we want to discuss new membrane structure and characterization techniques, the role of advanced membranes and membrane-based processes in sustainability/environment (including carbon dioxide capture), membranes in water processes, and membranes for biological and life support applications. As usual, the informal nature of the meeting, excellent quality of the oral presentations and posters, and ample opportunity to meet many outstanding colleagues make this an excellent conference for established scientists as well as for students. A Gordon Research Seminar (GRS) on the weekend prior to the GRC meeting will provide young researchers an opportunity to present their work and network with outstanding experts. It will also be a right warm-up for the conference participants to join and enjoy the main conference.

  18. Microwave processing of materials. Final report

    SciTech Connect

    McMillan, A.D.; Lauf, R.J.; Garard, R.S.

    1997-11-01

    A Cooperative Research and Development Agreement (CRADA) between Lockheed Martin Energy Systems, Inc. (LMES) and Lambda Technologies, Inc. (Lambda) of Raleigh, N.C., was initiated in May 1995. [Lockheed Martin Energy Research, Corp. (LMER) has replaced LMES]. The completion data for the Agreement was December 31, 1996. The purpose of this work is to explore the feasibility of several advanced microwave processing concepts to develop new energy-efficient materials and processes. The project includes two tasks: (1) commercialization of the variable-frequency microwave furnace (VFMF); and (2) microwave curing of polymer composites. The VFMF, whose initial conception and design was funded by the Advanced Industrial Concepts (AIC) Materials Program, will allow us, for the first time, to conduct microwave processing studies over a wide frequency range. This novel design uses a high-power traveling wave tube (TWT) originally developed for electronic warfare. By using this microwave source, one can not only select individual microwave frequencies for particular experiments, but also achieve uniform power densities over a large area by the superposition of many different frequencies.

  19. Chemistry and Processing of Nanostructured Materials

    SciTech Connect

    Fox, G A; Baumann, T F; Hope-Weeks, L J; Vance, A L

    2002-01-18

    Nanostructured materials can be formed through the sol-gel polymerization of inorganic or organic monomer systems. For example, a two step polymerization of tetramethoxysilane (TMOS) was developed such that silica aerogels with densities as low as 3 kg/m{sup 3} ({approx} two times the density of air) could be achieved. Organic aerogels based upon resorcinol-formaldehyde and melamine-formaldehyde can also be prepared using the sol-gel process. Materials of this type have received significant attention at LLNL due to their ultrafine cell sizes, continuous porosity, high surface area and low mass density. For both types of aerogels, sol-gel polymerization depends upon the transformation of these monomers into nanometer-sized clusters followed by cross-linking into a 3-dimensional gel network. While sol-gel chemistry provides the opportunity to synthesize new material compositions, it suffers from the inability to separate the process of cluster formation from gelation. This limitation results in structural deficiencies in the gel that impact the physical properties of the aerogel, xerogel or nanocomposite. In order to control the properties of the resultant gel, one should be able to regulate the formation of the clusters and their subsequent cross-linking. Towards this goal, we are utilizing dendrimer chemistry to separate the cluster formation from the gelation so that new nanostructured materials can be produced. Dendrimers are three-dimensional, highly branched macromolecules that are prepared in such a way that their size, shape and surface functionality are readily controlled. The dendrimers will be used as pre-formed clusters of known size that can be cross-linked to form an ordered gel network.

  20. Saving Material with Systematic Process Designs

    NASA Astrophysics Data System (ADS)

    Kerausch, M.

    2011-08-01

    Global competition is forcing the stamping industry to further increase quality, to shorten time-to-market and to reduce total cost. Continuous balancing between these classical time-cost-quality targets throughout the product development cycle is required to ensure future economical success. In today's industrial practice, die layout standards are typically assumed to implicitly ensure the balancing of company specific time-cost-quality targets. Although die layout standards are a very successful approach, there are two methodical disadvantages. First, the capabilities for tool design have to be continuously adapted to technological innovations; e.g. to take advantage of the full forming capability of new materials. Secondly, the great variety of die design aspects have to be reduced to a generic rule or guideline; e.g. binder shape, draw-in conditions or the use of drawbeads. Therefore, it is important to not overlook cost or quality opportunities when applying die design standards. This paper describes a systematic workflow with focus on minimizing material consumption. The starting point of the investigation is a full process plan for a typical structural part. All requirements are definedaccording to a predefined set of die design standards with industrial relevance are fulfilled. In a first step binder and addendum geometry is systematically checked for material saving potentials. In a second step, blank shape and draw-in are adjusted to meet thinning, wrinkling and springback targets for a minimum blank solution. Finally the identified die layout is validated with respect to production robustness versus splits, wrinkles and springback. For all three steps the applied methodology is based on finite element simulation combined with a stochastical variation of input variables. With the proposed workflow a well-balanced (time-cost-quality) production process assuring minimal material consumption can be achieved.

  1. Hazardous materials in aquatic environments of the Mississippi River Basin. Quarterly progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    1995-12-01

    This report is the quarterly progress report for July through September 1995 for work done by Tulane and Xavier Universities under DOE contract number DE-FG01-93-EW53023. Accomplishments for various tasks including administrative activities, collaborative cluster projects, education projects, initiation projects, coordinated instrumentation facility, and an investigators` retreat are detailed in the report.

  2. Bench-scale testing of the micronized magnetite process. Sixth quarterly technical progress report, October--December, 1995

    SciTech Connect

    1996-08-13

    The major focus of the project is to install and test a 500 lbs./hr. fine-coal cleaning circuit at DOE`s Process Research Facility (PRF), located at the Pittsburgh Energy Technology Center (PETC). The circuit will utilize an extremely fine, micron-sized magnetite media and small diameter cyclones to make efficient density separations on minus-28-Mesh coal. The circuit consists of three subcircuits: Classification Circuit; Dense-Medium Cycloning Circuit; and Magnetite Recovery Circuit. The testing scope involves initial closed-loop testing of each subcircuit to optimize the performance of the equipment in each subcircuit (i.e., Component Testing), followed by open-circuit testing of the entire integrated circuit to optimize the process and quantify the process efficiency (i.e., Integrated Testing). This report contains a short discussion of the project description, objectives, budget, schedule, and teaming arrangement. It also includes a detailed discussion of the above mentioned project accomplishments and plans, organized by the various task series within the project work plan. The final section contains an outline of the specific project goals for the next quarterly reporting period.

  3. Bench-scale testing of the micronized magnetite process. Eighth quarterly technical progress report, April--June, 1996

    SciTech Connect

    1996-08-13

    The major focus of the project is to install and test a 500 lbs./hr. fine-coal cleaning circuit at DOE`s Process Research Facility (PRF), located at the Pittsburgh Energy Technology Center (PETC). The circuit will utilize an extremely fine, micron-sized magnetite media and small diameter cyclones to make efficient density separations on minus-28-Mesh coal. The circuit consists of three subcircuits: Classification Circuit; Dense-Medium Cycloning Circuit; and Magnetite Recovery Circuit. The testing scope involves initial closed-loop testing of each subcircuit to optimize the performance of the equipment in each subcircuit (i.e., Component Testing), followed by open-circuit testing of the entire integrated circuit to optimize the process and quantify the process efficiency (i.e., Integrated Testing). This report contains a short discussion of the project description, objectives, budget, schedule, and teaming arrangement. It also includes a detailed discussion of the above mentioned project accomplishments and plans, organized by the various task series within the project work plan. The final section contains an outline of the specific project goals for the next quarterly reporting period.

  4. Bench-scale testing of the micronized magnetite process. Seventh quarterly technical progress report, January--March, 1996

    SciTech Connect

    1996-08-13

    The major focus of the project is to install and test a 500 lbs./hr. fine-coal cleaning circuit at DOE`s Process Research Facility (PRF), located at the Pittsburgh Energy Technology Center (PETC). The circuit will utilize an extremely fine, micron-sized magnetite media and small diameter cyclones to make efficient density separations on minus-28-Mesh coal. The circuit consists of three subcircuits: Classification Circuit; Dense-Medium Cycloning Circuit; and Magnetite Recovery Circuit. The testing scope involves initial closed-loop testing of each subcircuit to optimize the performance of the equipment in each subcircuit (i.e., Component Testing), followed by open-circuit testing of the entire integrated circuit to optimize the process and quantify the process efficiency (i.e., Integrated Testing). This report contains a short discussion of the project description, objectives, budget, schedule, and teaming arrangement. It also includes a detailed discussion of the above mentioned project accomplishments and plans, organized by the various task series within the project work plan. The final section contains an outline of the specific project goals for the next quarterly reporting period.

  5. Process for Coating Substrates with Catalytic Materials

    NASA Technical Reports Server (NTRS)

    Klelin, Ric J. (Inventor); Upchurch, Billy T. (Inventor); Schryer, David R. (Inventor)

    2004-01-01

    A process for forming catalysts by coating substrates with two or more catalytic components, which comprises the following sequence of steps. First, the substrate is infused with an adequate amount of solution having a starting material comprising a catalytic component precursor, wherein the thermal decomposition product of the catalytic component precursor is a catalytic component. Second, the excess of the solution is removed from the substrate. thereby leaving a coating of the catalytic component precursor on the surface of the substrate. Third, the coating of the catalytic component precursor is converted to the catalytic component by thermal decomposition. Finally, the coated substance is etched to increase the surface area. The list three steps are then repeated for at least a second catalytic component. This process is ideally suited for application in producing efficient low temperature oxidation catalysts.

  6. Solar Energy: Materials, Materials Handling, and Fabrication Processes: Student Material. First Edition.

    ERIC Educational Resources Information Center

    Bolin, William Everet; Orsak, Charles G., Jr.

    Designed for student use in "Materials, Materials Handling, and Fabrication Processes," one of 11 courses in a 2-year associate degree program in solar technology, this manual provides readings, exercises, worksheets, bibliographies, and illustrations for 13 course modules. The manual, which corresponds to an instructor guide for the same course,…

  7. Coal liquefaction process streams characterization and evaluation. Quarterly technical progresss report, January 1--March 31, 1991

    SciTech Connect

    Brandes, S.D.; Winschel, R.A.; Burke, F.P.; Robbins, G.A.

    1991-09-01

    Consol R&D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  8. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, April 1--June 30, 1991

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1991-11-01

    Consol R&D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  9. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, July 1--September 30, 1991

    SciTech Connect

    Winschel, R.A.; Brandes, S.D.; Robbins, G.A.; Burke, F.P.

    1991-11-01

    Consol R&D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-field: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  10. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, October 1--December 31, 1991

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-03-01

    CONSOL R&D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  11. Bench-scale co-processing. Quarterly report No. 16, April 1, 1992--June 30, 1992

    SciTech Connect

    Schauer, J.; Gatsis, J.G.

    1993-11-15

    The high-severity co-processing long-term operability test and the detailed product analyses from the operability test have been completed. Operational data and detailed product analyses have been used to characterize the high-severity co-processing operation. Using the process characterizations, yield estimate for a commercial-sized high-severity co-processing unit has been performed using operational data and detailed product analysis from the long-term operability study. The estimate is based on a co-processing unit processing the vacuum resid from 50,000 barrels per day (BPD) of Lloydminster crude and also processing 2,400 metric tons per day (MT/day) of Illinois No. 6 coal. The feedstock characteristics for the yield estimate are summarized in Table 1.

  12. Bench-scale testing of the micronized magnetite process. Third quarterly technical progress report, January 1995--March 1995

    SciTech Connect

    1995-04-29

    The major focus of the project, which is scheduled to occur through December 1995, will be to install and test a 500{number_sign}/hr. fine-coal cleaning circuit at DOE`s Process Research Facility (PRF), located at the Pittsburgh Energy Technology Center (PETC). The circuit will utilize an extremely fine, micron-sized magnetite media and small diameter cyclones to make efficient density separations on minus-28-Mesh coal. The overall objectives of the project are to: Determine the effects of operating time on the characteristics of the recirculating medium in a continuous integrated processing circuit, and subsequently, the sensitivity of cyclone separation performance to the quality of the recirculating medium; and determine the technical and economic feasibility of various unit operations and systems in optimizing the separation and recovery of the micronized magnetite from the coal products. This report contains a short discussion of the project description, objectives, budget, schedule, and teaming arrangement. The final section contains an outline of the specific project goals for the next quarterly reporting period.

  13. Measurement and modeling of advanced coal conversion processes. Twenty-second quarterly report, January 2, 1992--March 31, 1992

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.; Smoot, L.D.; Brewster, B.S.

    1992-12-01

    The objectives of this proposed study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. This report describes progress during twenty second quarter of the program. Specifically, the paper discusses progress in three task areas: (1) Submodel development and evaluation: coal to char chemistry submodel; fundamental high-pressure reaction rate data; secondary reaction of pyrolysis product and burnout submodels; ash physics and chemistry submodel; large particle submodels; large char particle oxidation at high pressures; and SO{sub x}-NO{sub x} submodel development and evaluation; (2) Comprehensive model development and evaluation: integration of advanced submodels into entrained-flow code, with evaluation and documentation; comprehensive fixed-bed modeling review, development evaluation and implementation; and generalized fuels feedstock submodel; and (3) Application of integrated codes: application of generalized pulverized coal comprehensive code and application of fixed-bed code.

  14. Enforcement actions: Significant actions resolved material licensees (non-medical). Volume 14, No. 1, Part 3, Quarterly progress report, January--March 1995

    SciTech Connect

    1995-05-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (January--March 1995) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to Material Licensees (non-Medical) with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication.

  15. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, July 1--September 30, 1995

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1995-12-01

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. Some of the contract activities for this quarter are: We completed many of the analyses on the 81 samples received from HTI bench-scale run CMSL-9, in which coal, coal/mixed plastics, and coal/high density polyethylene were fed; Liquid chromatographic separations of the 15 samples in the University of Delaware sample set were completed; and WRI completed CP/MAS {sup 13}C-NMR analyses on the Delaware sample set.

  16. /sup 238/Pu fuel form processes quarterly report, April-June 1980

    SciTech Connect

    Folger, R. L.

    1980-06-01

    Savannah River Laboratory (SRL) completed the development of a production process to fabricate /sup 238/PuO/sub 2/ fuel forms for the GPHS. The fabrication flowsheet was based on a flowsheet originally developed at Los Alamos National Scientific Laboratory (LANSL). A summary report of the SRL process development effort is presented.

  17. Advanced Coal Conversion Process Demonstration Project. Quarterly technical progress report, January 1, 1994--March 31, 1994

    SciTech Connect

    1996-02-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1994, through March 31, 1994. This project demonstrates an advanced, thermal, coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal processing, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and operated in an extended startup mode through August 10, 1993, when the facility became commercial. Rosebud SynCoal Partnership instituted an aggressive program to overcome startup obstacles and now focuses on supplying product coal to customers. Significant accomplishments in the history of the SynCoal{reg_sign} process development are shown in Appendix A.

  18. 5th Conference on Aerospace Materials, Processes, and Environmental Technology

    NASA Technical Reports Server (NTRS)

    Cook, M. B. (Editor); Stanley, D. Cross (Editor)

    2003-01-01

    Records are presented from the 5th Conference on Aerospace Materials, Processes, and Environmental Technology. Topics included pollution prevention, inspection methods, advanced materials, aerospace materials and technical standards,materials testing and evaluation, advanced manufacturing,development in metallic processes, synthesis of nanomaterials, composite cryotank processing, environmentally friendly cleaning, and poster sessions.

  19. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, July 1993--September 1993

    SciTech Connect

    Not Available

    1993-10-30

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase 3 research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase 3 project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the past quarter, the major effort was completing some of the system modification installation designs, completing industry funded testing, developing a surrogate TSCA ash composition, and completing the TSCA ash Test Plan. The installation designs will be used for the equipment modifications planned for the end of CY 93. The industry funded testing consisted of vitrifying Spent Aluminum Potliner (SPL) which is a listed hazardous waste. This testing has verified that SPL can be vitrified into a safe, recyclable glass product. Some results from this testing are provided in Section 2.2.1. The surrogate TSCA ash composition was developed with input from various DOE laboratories and subcontractors. The surrogate ash consists of a mixture of MSW fly ash and bottom ash spiked with heavy metal contaminants. The levels of metal additives are sufficient to ascertain the partitioning of the contaminants between the glass and effluent flow streams. Details of the surrogate composition and the planned testing is provided in Section 4.2.2.

  20. Development of the selective hydrophobic coagulation process. Technical progress report for the ninth quarter, October 1--December 31, 1993

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.

    1994-07-01

    A novel technique for selectively coagulating and separating coal from dispersed mineral matter has been developed at Virginia Tech. The process, known as Selective Hydrophobic Coagulation (SHC), has been studied under the sponsorship of the U.S. Department of Energy since 1986 (Contracts DE-AC22-86PC91221 & DE-AC22- 9OPC90174). The SHC process differs from oil agglomeration, shear flocculation, polymer flocculation, and electrolytic coagulation processes in that it does not require reagents or additives to induce the formation of coagula. Often, simple pH control is all that is required to (i) induce the coagulation of coal particles, and (ii) effectively disperse particles of mineral matter. When the coal is superficially oxidized, a small dosage of reagents may be used to promote coagulation. During the past quarter, stability calculations were carried out to develop a better understanding of the selective coagulation of fine coal and associated mineral matter. The calculations were performed for interactions involving coal, silica and clay particles. The analyses suggest that the heterocoagulation of the edges of clay particles with coal particles controls the overall selectivity of the SHC process. In Subtask 3.3, froth flotation was explored as a possible technique for recovering hydrophobic coagula. Experimental test data obtained using this technique were analyzed using a statistical regression program. The analyses indicate that froth flotation can be used to successfully recover hydrophobic coagula provided that adequate precautions are taken to minimize coagula breakage due to turbulence. Recommendations include the use of low aeration rates and little or no additions of wash water.

  1. Integration mockup and process material management system

    NASA Technical Reports Server (NTRS)

    Verble, Adas James, Jr.

    1992-01-01

    Work to define and develop a full scale Space Station Freedom (SSF) mockup with the flexibility to evolve into future designs, to validate techniques for maintenance and logistics and verify human task allocations and support trade studies is described. This work began in early 1985 and ended in August, 1991. The mockups are presently being used at MSFC in Building 4755 as a technology and design testbed, as well as for public display. Micro Craft also began work on the Process Material Management System (PMMS) under this contract. The PMMS simulator was a sealed enclosure for testing to identify liquids, gaseous, particulate samples, and specimen including, urine, waste water, condensate, hazardous gases, surrogate gasses, liquids, and solids. The SSF would require many trade studies to validate techniques for maintenance and logistics and verify system task allocations; it was necessary to develop a full scale mockup which would be representative of current SSF design with the ease of changing those designs as the SSF design evolved and changed. The tasks defined for Micro Craft were to provide the personnel, services, tools, and materials for the SSF mockup which would consist of four modules, nodes, interior components, and part task mockups of MSFC responsible engineering systems. This included the Engineering Control and Life Support Systems (ECLSS) testbed. For the initial study, the mockups were low fidelity, soft mockups of graphics art bottle, and other low cost materials, which evolved into higher fidelity mockups as the R&D design evolved, by modifying or rebuilding, an important cost saving factor in the design process. We designed, fabricated, and maintained the full size mockup shells and support stands. The shells consisted of cylinders, end cones, rings, longerons, docking ports, crew airlocks, and windows. The ECLSS required a heavier cylinder to support the ECLSS systems test program. Details of this activity will be covered. Support stands were

  2. Integration mockup and process material management system

    NASA Astrophysics Data System (ADS)

    Verble, Adas James, Jr.

    1992-02-01

    Work to define and develop a full scale Space Station Freedom (SSF) mockup with the flexibility to evolve into future designs, to validate techniques for maintenance and logistics and verify human task allocations and support trade studies is described. This work began in early 1985 and ended in August, 1991. The mockups are presently being used at MSFC in Building 4755 as a technology and design testbed, as well as for public display. Micro Craft also began work on the Process Material Management System (PMMS) under this contract. The PMMS simulator was a sealed enclosure for testing to identify liquids, gaseous, particulate samples, and specimen including, urine, waste water, condensate, hazardous gases, surrogate gasses, liquids, and solids. The SSF would require many trade studies to validate techniques for maintenance and logistics and verify system task allocations; it was necessary to develop a full scale mockup which would be representative of current SSF design with the ease of changing those designs as the SSF design evolved and changed. The tasks defined for Micro Craft were to provide the personnel, services, tools, and materials for the SSF mockup which would consist of four modules, nodes, interior components, and part task mockups of MSFC responsible engineering systems. This included the Engineering Control and Life Support Systems (ECLSS) testbed. For the initial study, the mockups were low fidelity, soft mockups of graphics art bottle, and other low cost materials, which evolved into higher fidelity mockups as the R&D design evolved, by modifying or rebuilding, an important cost saving factor in the design process. We designed, fabricated, and maintained the full size mockup shells and support stands. The shells consisted of cylinders, end cones, rings, longerons, docking ports, crew airlocks, and windows. The ECLSS required a heavier cylinder to support the ECLSS systems test program. Details of this activity will be covered. Support stands were

  3. Solvent Refined Coal (SRC) process. Quarterly technical progress report, January 1979-March 1979

    SciTech Connect

    Not Available

    1980-02-01

    This report summarizes the progress of the Solvent Refined Coal (SRC) Project by the Pittsburg and Midway Coal Mining Co. for the Department of Energy for the period January 1, 1979 to March 31, 1979. Activities included the operation and modification of the Solvent Refined Coal Pilot Plant at Fort Lewis, Washington; the Process Development Unit P-99 at Harmarville, Pennsylvania; and research at Merriam Laboratory in Merriam, Kansas. The Pilot Plant processed Powhatan No. 5 Coal in the SRC-II mode of operation studying the effect of coal particle size and system temperature on coal slurry blending and the effect of carbon monoxide concentration in the reaction feed gas on process yields. January and February were spent completing installation of a fourth High Pressure Separator on Process Development Unit P-99 to better simulate operating conditions for the proposed Demonstration Plant. During March, one run was completed at P-99 feeding Pittsburgh Seam Coal from the Powhatan No. 5 Mine. Merriam investigations included a study of the effect of iron containing additives on SRC-I operation, the addition of carbon monoxide to the feed gas, utilization of a hydrogenated solvent (Cresap process solvent) in the SRC-I mode under both normal and short residence time operating conditions, and development of a simulated distillation technique to determine the entire boiling range distribution of product oils.

  4. Utilization of geothermal energy in the mining and processing of tungsten ore. 2nd quarterly report

    SciTech Connect

    Erickson, M.V.; Willens, C.A.; Walter, K.M.; Carrico, R.L.; Lowe, G.D.; Lacy, S.B.

    1980-06-01

    The completed geochemical analysis of groundwater in the Pine Creek area for evaluation of the geothermal potential of this location is presented. Also included is an environmental constraints analysis of Pine Creek noting any potential environmental problems if a geothermal system was developed onsite. Design of a geothermal system is discussed for site-specific applications and is discussed in detail with equipment recommendations and material specifications. A preliminary financial, economic, and institutional assessment of geothermal system located totally on Union Carbide property at Pine Creek is included. (MHR)

  5. New microorganisms and processes for MEOR. Quarterly report ending September 30, 1992

    SciTech Connect

    Sperl, G.T.; Sperl, P.L.

    1992-12-31

    Oil reservoirs naturally contain inorganic and organic materials which can be exploited through simple supplementation to support the growth of microorganisms which aid in the release of oil from the rock matrix. Other compounds which may serve as nutritional sources for microorganisms are added to reservoirs during production and operation of oil fields. These materials include sulfate, nitrate, carbonate, volatile fatty acids, nitrogen-containing corrosion inhibitors, phosphorous-containing scale inhibitors and trace elements. Our experiments show that, with minimal supplementation, growth of naturally-occurring microorganisms can be used to produce viscosifying agents to aid oil recovery. This natural microflora is also capable of removing sulfide from oil reservoirs and preventing the formation of new sulfide leading to both more oil recovery and increased value of the produced oil. The metabolic products of these microorganisms are Co{sub 2}, water, N{sub 2} and oxidized forms of sulfur, all of which are environmentally innocuous. Laboratory experiments with both defined mixtures of microorganisms as well as mixed populations both release more oil from sand pack columns.

  6. Development of biological coal gasification (MicGAS Process). Seventh quarterly report

    SciTech Connect

    Not Available

    1992-04-30

    In order for the coal biogasification process to be economically feasible, an inexpensive nutrient amendment must be found to replace the Difco{trademark} yeast extract and tryptic soy broth (YE/TSB) used in the current medium formulation. Five products have been identified which support greater methane production from Texas lignite than YE/TSB.

  7. Analysis and evaluation in the production process and equipment area of the Low-Cost Solar Array Project. Quarterly report, April-July 1980

    SciTech Connect

    Goldman, H.; Wolf, M.

    1981-01-01

    After the influence of the metallization design on the performance of solar cells, particularly large area cells such as 10 cm x 10 cm size, has been analyzed, and a set of design rules derived from this analysis in the two preceding quarterly reports, this report deals with the available options for metal deposition. The principles underlying the different options are described. These options include chemical deposition methods, both electroless and electrolytic, and physical methods, which comprise the various types of vacuum deposition as well as the thick film processes. A qualitative comparison of the practical aspects of the application of these processes to solar cell manufacturing is given. The next quarterly report will contain the detailed economic data of these options, and an evaluation of these data.

  8. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, October 1994--December 1994

    SciTech Connect

    1995-03-01

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a {open_quotes}Coal-Fired Combustion System for Industrial Process Heating Applications{close_quotes} is a project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the past quarter, the major effort was concentrated on conducting the 100 hour demonstration test. The test was successfully conducted from September 12th through the 16th. The test program consisted of one test run, with a duration of 100 hours at a nominal feed rate of 1000 lbs/hr. Throughout the test, the CMS was fired with coal and a coal by-product (i.e. coal-fired boiler flyash) as the primary fuels. Natural gas was used as an auxiliary fuel as necessary to provide process trim. The feedstock consisted of a coal-fired utility boiler flyash and dolomite and produced a stable, fully-reacted vitrified product. The fly ash, supplied by PENELEC, contained between 6 and 12% by weight of carbon because of the low NO{sub x} burners on the PENELEC boilers.

  9. Development of mild gasification process. Quarterly report, October--December 1988

    SciTech Connect

    Chu, C.I.C.; Williams, S.W.

    1989-01-01

    Under a previous contract with Morgantown Energy Technology Center (METC), Department of Energy (DOE) Contract No. AC21-84MC21108, UCC Research Corporation (UCCRC) built and tested a 1500 lb/day Mild Gasification Process Development Unit (MGU). The MGU, as tested under the previous contract, is shown in Figure 1. Testing completed under the previous contract showed that good quality hydrocarbon liquids and good quality char can be produced in the MGU. However, the MGU is not optimized. The primary objectives of the current project are to optimize the MGU and determine the suitability of char for several commercial applications. The program consists of four tasks; Task 1 -- Test Plan; Task 2 -- Optimization of Mild Gasification Process; Task 3 -- Evaluation of Char and Char/Coal Blends as a Boiler/Blast Furnace Fuel; and Task 4 -- Analysis of Data and Preparation of Final Report. Task 1 has been completed while work continued on Task 2.

  10. Development of mild gasification process. Quarterly report, July--September 1987

    SciTech Connect

    Chu, C.I.C.; Gillespie, B.L.

    1987-11-01

    Under a previous contract with Morgantown Energy Technology Center (METC), Department of Energy (DOE) Contract No. AC21-84MC21108, UCC Research Corporation (UCCRC) built and tested a 1500 lb/day Mild Gasification Process Development Unit (MGU). The MGU, as tested under the previous contract, is shown in Figure 1. Testing completed under the previous contract showed that good quality hydrocarbon liquids and good quality char can be produced in the MGU. However, the MGU is not optimized. The primary objectives of the current project are to optimize the MGU and determine the suitability of char for several commercial applications. The program consists of four tasks; Task 1 -- Test Plan; Task 2 -- Optimization of Mild Gasification Process; Task 3 -- Evaluation of Char and Char/Coal Blends as a Boiler/Blast Furnace Fuel; and Task 4 -- Analysis of Data and Preparation of Final Report. Task 1 has been completed while work continued on Task 2.

  11. Development of mild gasification process. Quarterly report, April--June 1988

    SciTech Connect

    Chu, C.I.C.; Derting, T.M.

    1988-07-01

    Under a previous contract with Morgantown Energy Technology Center (METC), Department of Energy (DOE) Contract No. AC21-84MC21108, UCC Research Corporation (UCCRC) built and tested a 1500 lb/day Mild Gasification Process Development Unit (MGU). The MGU, as tested under the previous contract, is shown in Figure 1. Testing completed under the previous contract showed that good quality hydrocarbon liquids and good quality char can be produced in the MGU. However, the MGU is not optimized. The primary objectives of the current project are to optimize the MGU and determine the suitability of char for several commercial applications. The program consists of four tasks; Task 1 -- Test Plan; Task 2 -- Optimization of Mild Gasification Process; Task 3 -- Evaluation of Char and Char/Coal Blends as a Boiler/Blast Furnace Fuel; and Task 4 -- Analysis of Data and Preparation of Final Report. Task 1 has been completed while work continued on Task 2.

  12. Development of mild gasification process. Quarterly report, October--December, 1987

    SciTech Connect

    Chu, C.I.C.; Gillespie, B.L.

    1988-02-01

    Under a previous contract with Morgantown Energy Technology Center (METC), Department of Energy (DOE) Contract No. DE-AC21-84MC21108, UCC Research Corporation (UCCRC) built and tested a 1500 lb/day Mild Gasification Process Development Unit (MGU). The MGU, as tested under the previous contract, is shown in Figure 1. Testing completed under the previous contract showed that good quality hydrocarbon liquids and good quality char can be produced in the MGU. However, the MGU is not optimized. The primary objectives of the current project are to optimize the MGU and determine the suitability of char for several commercial applications. The program consists of four tasks; Task 1-Test Plan; Task 2-Optimization of Mild Gasification Process; Task 3-Evaluation of Char and Char/Coal Blends as a Boiler/Blast Furnace Fuel; and Task 4-Analysis of Data and Preparation of Final Report. Task 1 has been completed while work continued on Task 2.

  13. Processes for fabricating composite reinforced material

    SciTech Connect

    Seals, Roland D.; Ripley, Edward B.; Ludtka, Gerard M.

    2015-11-24

    A family of materials wherein nanostructures and/or nanotubes are incorporated into a multi-component material arrangement, such as a metallic or ceramic alloy or composite/aggregate, producing a new material or metallic/ceramic alloy. The new material has significantly increased strength, up to several thousands of times normal and perhaps substantially more, as well as significantly decreased weight. The new materials may be manufactured into a component where the nanostructure or nanostructure reinforcement is incorporated into the bulk and/or matrix material, or as a coating where the nanostructure or nanostructure reinforcement is incorporated into the coating or surface of a "normal" substrate material. The nanostructures are incorporated into the material structure either randomly or aligned, within grains, or along or across grain boundaries.

  14. Supercritical fluid processing: opportunities for new resist materials and processes

    NASA Astrophysics Data System (ADS)

    Gallagher-Wetmore, Paula M.; Ober, Christopher K.; Gabor, Allen H.; Allen, Robert D.

    1996-05-01

    Over the past two decades supercritical fluids have been utilized as solvents for carrying out separations of materials as diverse as foods, polymers, pharmaceuticals, petrochemicals, natural products, and explosives. More recently they have been used for non-extractive applications such as recrystallization, deposition, impregnation, surface modification, and as a solvent alternative for precision parts cleaning. Today, supercritical fluid extraction is being practiced in the foods and beverage industries; there are commercial plants for decaffeinating coffee and tea, extracting beer flavoring agents from hops, and separating oils and oleoresins from spices. Interest in supercritical fluid processing of polymers has grown over the last ten years, and many new purification, fractionation, and even polymerization techniques have emerged. One of the most significant motivations for applying this technology to polymers has been increased performance demands. More recently, with increasing scrutiny of traditional solvents, supercritical fluids, and in particular carbon dioxide, are receiving widespread attention as 'environmentally conscious' solvents. This paper describes several examples of polymers applications, including a few involving photoresists, which demonstrate that as next- generation advanced polymer systems emerge, supercritical fluids are certain to offer advantages as cutting edge processing tools.

  15. Material Processing of Quantum Well Infrared Photodetectors

    NASA Astrophysics Data System (ADS)

    Malin, Jay Ira

    1995-01-01

    The material and device characterization of furnace and rapid thermally annealed (RTA) GaAs/AlGaAs multiple quantum well (MQW) infrared (IR) photodetectors (QWIPs) epitaxially grown on GaAs and Si substrates is presented. The advances in epitaxial growth allow the precise control of the dimensions, doping, and matrix concentration of the MQW. Therefore, the design of a QWIP with particular electrical and optical characteristics may be undertaken. To utilize a post-growth anneal to improve the QWIP's performance, the trade-offs must be considered to determine its usefulness. Depending on the application, the anneal may be deemed unnecessary due to its detrimental effect on a particular aspect of the operation. The availability of high quality GaAs and Si substrates, complemented by the maturity of GaAs device processing techniques, makes the QWIP an ideal candidate for 8-14 μm long wavelength infrared (LWIR) detection. An extensive exploration of the interdiffusion process leads to the development of a suitable technique for shifting the optical response without harming the electrical characteristics. This, however, is a difficult task in light of the out-diffusion of the dopant from the wells into the barriers, which results in a high dark current. Reading-out the QWIP focal plane array (FPA) (on GaAs substrate) is accomplished by indium bump-bonding the FPA to a Si multiplexer. Thermal cycling the hybrid, unfortunately, results in destroyed bonds due to the difference in thermal expansion coefficient of the two substrates. Growing the QWIP on a Si substrate better satisfies the packaging requirements; however, the dark current is higher. The technique of annealing for the purpose of defect annihilation results in improvements in the absolute response and a reduction in the dark current.

  16. Materials Processing with Intense Pulsed Ion Beams*

    NASA Astrophysics Data System (ADS)

    Renk, T. J.; Johnson, D. J.; Friedmann, T. A.; Provencio, P. P.; Thompson, M. O.; Sanders, P. G.; Kasuya, K.; Kishimoto, N.

    1999-11-01

    Materials applications are being investigated on the 700 kV RHEPP-1 facility at Sandia National Laboratories. Surface modification for property improvement is possible in the fluence range 1-5 J/cm^2, with ablation and thin-film synthesis at 5-20 J/cm^2 fluences. Differences from previous efforts include selectability of accelerating ions (H, He, C, N, Ne, Ar, and Xe), and repetitive pulsing of the MAP (Magnetically Confined Anode Plasma) gas-breakdown ion source. Surface modification using melt-resolidification cycles has led to improvement in hardness and corrosion resistance of various metals. Mixing of pre-applied thin-films into the bulk has led to even greater performance improvements. Characterization is ongoing to determine the microstructural basis for these improvements. We have characterized liquid-phase diffusion of implanted elements in Ti and Si during the power pulse. Experiments with Si device processing and polymer modification are also ongoing. Thin-films are being formed from graphite, YBCO, and ZnO targets for various applications, including hard-coatings and optical coatings. Surface topography, stoichiometry, and optical and infrared absorption measurements have been made. *Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Co., under US DOE Contract DE-AC04-94AL85000.

  17. Integration of advanced nuclear materials separation processes

    SciTech Connect

    Jarvinen, G.D.; Worl, L.A.; Padilla, D.D.; Berg, J.M.; Neu, M.P.; Reilly, S.D.; Buelow, S.

    1998-12-31

    This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project has examined the fundamental chemistry of plutonium that affects the integration of hydrothermal technology into nuclear materials processing operations. Chemical reactions in high temperature water allow new avenues for waste treatment and radionuclide separation.Successful implementation of hydrothermal technology offers the potential to effective treat many types of radioactive waste, reduce the storage hazards and disposal costs, and minimize the generation of secondary waste streams. The focus has been on the chemistry of plutonium(VI) in solution with carbonate since these are expected to be important species in the effluent from hydrothermal oxidation of Pu-containing organic wastes. The authors investigated the structure, solubility, and stability of the key plutonium complexes. Installation and testing of flow and batch hydrothermal reactors in the Plutonium Facility was accomplished. Preliminary testing with Pu-contaminated organic solutions gave effluent solutions that readily met discard requirements. A new effort in FY 1998 will build on these promising initial results.

  18. English Leadership Quarterly, 1992.

    ERIC Educational Resources Information Center

    Strickland, James, Ed.

    1992-01-01

    These four issues of the English Leadership Quarterly represent those published during 1992. Articles in number 1 deal with testing assessing, and measuring student performance, and include: "Real Evaluation: Portfolios as an Effective Alternative to Standardized Testing" (Kate Kiefer); "No More Objective Tests, Ever" (Carol Jago); "Process-Based…

  19. Development and fabrication of a solar cell junction processing system. Quarterly report No. 2, July 1980

    SciTech Connect

    Siesling, R.

    1980-07-01

    The basic objectives of the program are the following: (1) to design, develop, construct and deliver a junction processing system which will be capable of producing solar cell junctions by means of ion implantation followed by pulsed electron beam annealing; (2) to include in the system a wafer transport mechanism capable of transferring 4-inch-diameter wafers into and out of the vacuum chamber where the ion implantation and pulsed electron beam annealing processes take place; (3) to integrate, test and demonstrate the system prior to its delivery to JPL along with detailed operating and maintenance manuals; and (4) to estimate component lifetimes and costs, as necessary for the contract, for the performance of comprehensive analyses in accordance with the Solar Array Manufacturing Industry Costing Standards (SAMICS). Under this contract the automated junction formation equipment to be developed involves a new system design incorporating a modified, government-owned, JPL-controlled ion implanter into a Spire-developed pulsed electron beam annealer and wafer transport system. When modified, the ion implanter will deliver a 16 mA beam of /sup 31/P/sup +/ ions with a fluence of 2.5 x 10/sup 15/ ions per square centimeter at an energy of 10 keV. The throughput design goal rate for the junction processor is 10/sup 7/ four-inch-diameter wafers per year.

  20. The space technology demand on materials and processes

    NASA Technical Reports Server (NTRS)

    Dauphin, J.

    1983-01-01

    Space technology requires a rational and accurate policy of materials and processes selection. This paper examines some areas of space technology where materials and process problems have occurred in the past and how they can be solved in the future.

  1. /sup 238/Pu fuel form processes. Quarterly report, October-December 1980

    SciTech Connect

    Not Available

    1981-08-01

    Goals of the Savannah River Laboratory (SRL) program include providing technical support for the production of /sup 238/PuO/sub 2/ fuel forms in the Savannah River Plant's (SRP) Plutonium Fuel Form (PuFF) Facility. Progress is reported including studies on the impact response of SRP MHW /sup 238/PuO/sub 2/ fuel spheres. The iridium containment shell of an encapsulated SRP fuel sphere, Multi-hundred Watt Fuel Test (MHFT) 65 split open during a Safety Verification Impact Test (SVT), and about 2 g of /sup 238/PuO/sub 2/ was released. (Typical oxide releases in previous tests were 1 to 10 mg). The cause of the impact failure was investigated. Also, the feasibility of using a direct fabrication process to produce full-scale GPHS fuel pellets has been demonstrated. (WHK)

  2. Development of the integrated environmental control model: Performance model for the NOXSO process. Quarterly progress report

    SciTech Connect

    Kalagnanam, J.R.; Rubin, E.S.

    1995-04-01

    In its current configuration, the IECM provides a capability to model various conventional and advanced processes for controlling air pollutant emissions from coal-fired power plants before, during, or after combustion. The principal purpose of the model is to calculate the performance, emissions, and cost of power plant configurations employing alternative environmental control methods. The model consists of various control technology modules, which may be integrated into a complete utility plant in any desired combination. In contrast to conventional deterministic models, the IECM offers the unique capability to assign probabilistic values to all model input parameters, and to obtain probabilistic outputs in the form of cumulative distribution functions indicating the likelihood of different costs and performance results. The most recent version of the IECM, implemented on a MacIntosh II computer, was delivered to DOE/PETC at the end of the last contract in May 1991. The current contract will continue the model development effort to provide DOE/PETC with improved model capabilities, including new software developments to facilitate model use and new technical capabilities for analysis of environmental control technologies. Integrated environmental control systems involving pre-combustion, combustion, and post-combustion control methods will be considered. Phase I involves developing the existing modules of the IECM. Phase II deals with creating new technology modules, linking the IECM with PETC databases, and training PETC personnel on the use of the updated models. The present report summarizes recent progress on the Phase I effort during the period January 1 - March 31, 1995. A preliminary summary is given of the new performance model developed for the NOXSO process. The performance model is developed from first principles and parametrized based on experimental data from pilot plants.

  3. Concurrent materials and process selection in conceptual design

    SciTech Connect

    Kleban, S.D.

    1998-07-01

    The sequential manner in which materials and processes for a manufactured product are selected is inherently less than optimal. Designers` tendency to choose processes and materials with which they are familiar exacerbate this problem. A method for concurrent selection of materials and a joining process based on product requirements using a knowledge-based, constraint satisfaction approach is presented.

  4. New microorganisms and processes for MEOR. Quarterly report ending, December 31, 1992

    SciTech Connect

    Sperl, P.L.; Sperl, G.T.

    1992-12-31

    We have been successful in isolating and characterizing sulfate reducing bacteria and denitrifying Thiobacillus sp. from oil field waters which can use volatile fatty acids and dissolve carbonates found in these waters and formations. We have shown that these cultures can feed each other in sequential cultures and survive in mixed culture as long as sterile conditions are maintained. When nonsterile conditions are present both organism types are only successful to a limited degree, and, instead, an additional microflora develop belonging to the heterotrophic denitrifying bacteria. These microorganisms appear to be potentially useful in new MEOR processes through the production of pressure forming gases, viscosifying agents and the removal and prevention of de novo synthesis of hydrogen sulfide and are currently being pursued. They are capable of producing large amounts of gas, predominantly nitrogen and carbon dioxide and also form viscosifying agents under conditions which we believe we can easily maintain in an oil reservoir. In this report we show that they are also potent agents for the control of SRB growth, development and production of sulfide.

  5. Advanced materials for geothermal energy processes

    SciTech Connect

    Kukacka, L.E.

    1985-08-01

    The primary goal of the geothermal materials program is to ensure that the private sector development of geothermal energy resources is not constrained by the availability of technologically and economically viable materials of construction. This requires the performance of long-term high risk GHTD-sponsored materials R and D. Ongoing programs described include high temperature elastomers for dynamic sealing applications, advanced materials for lost circulation control, waste utilization and disposal, corrosion resistant elastomeric liners for well casing, and non-metallic heat exchangers. 9 refs.

  6. /sup 238/Pu fuel form processes. Quarterly report, April-June 1982

    SciTech Connect

    j

    1982-11-01

    Progress in studies of /sup 238/Pu fuel form processes is reported. Analytical studies of weld-quench cracking in DOP-26 iridium alloy-clad vent sets in General Purpose Heat Sources (GPHS) showed that weld-quench cracking is much more severe in MER alloy than in LR and NR alloys. Spark source mass spectrometry indicated that areas in DOP-26 alloy with severe weld-quench cracking have high thorium inhomogeneity. Secondary ion mass spectrometry revealed differences in LR and MR alloys that may be related to their dissimilar susceptibilities for weld-quench cracking. Impact ductility tests showed that welds in DOP-26 alloy clad vent sets made using parameters similar to PuFF production welding had high elongations. Decontamination of encapsulated GPHS pellets in PuFF was demonstrated using a solution of 3.5 M HNO/sub 3/ + 6.4 M HF which is capable of reducing transferable contamination below the specified 10/sup 3/ dpm upper limit in <30 minutes at a bath temperature of 80/sup 0/C using ultrasonic cleaning. Decontamination vessels were constructed to trap and condense acid vapors during decontamination. Impact and metallographic data showed that although the micro and macrostructures between LANL and SRL pellets have large differences, the difference in impact response between these two types of pellets is not correspondingly large. Both types of pellets have impacted successfully. The micro and macrostructures of SRP pellets made with either low fired shards sintered in Ar/5%O/sub 2/ or Ar are intermediate between those of the LANL and SRL pellets. Therefore, either type of SRP pellet should impact successfully.

  7. Catalysts and process developments for two-stage liquefaction. Report No. 12, quarterly technical progress report, April 1, 1989--June 30, 1989, third quarter FY 1989

    SciTech Connect

    Cronauer, D.C.; Swanson, A.J.; Sajkowski, D.J.

    1994-11-01

    Research underway in this project centers upon developing and evaluating catalysts and process improvements for coal liquefaction in the two-stage close-coupled catalytic process. The project is being carried out under contract to the United States Department of Energy.

  8. Investigation of the geokinetics horizontal in situ oil shale retorting process. Quarterly report, October-December 1979

    SciTech Connect

    Hutchinson, D.L.

    1980-02-01

    The burn of Retort 17 was terminated December 10. Retort 18 was ignited November 12. Retort 17 produced 510 bbl during the quarter for the total of 3,775 bbl, while Retort 18 produced 1,187 bbl. The shale oil was analyzed. Environmental studies were done.

  9. Hazardous materials in aquatic environments of the Mississippi River basin. Quarterly project status report, April 1, 1993--June 30, 1993

    SciTech Connect

    Not Available

    1993-08-01

    During this quarter, the Review Panel made its final recommendations regarding which of the proposals should be funded. Included in this report is a brief status report of each of the research and education projects that are currently funded in this project. The Coordinated Instrumentation Facility (CIF) sponsored 3 seminars on Environmental Sample Preparation Techniques. These seminars were designed to educate the investigators on the use of microwave digestion systems for sample preparation and the use of Inductively Coupled Plasma and Atomic Absorption Specrtroscopy for analyses. During this period, Tulane and Xavier Universities have worked closely with Oak Ridge National Laboratories (ORNL) to develop a long term relationship that will encourage interaction and collaborations among the investigators at all of the institutions.

  10. Study of materials for space processing

    NASA Technical Reports Server (NTRS)

    Lal, R. B.

    1975-01-01

    Materials were selected for device applications and their commercial use. Experimental arrangements were also made for electrical characterization of single crystals using electrical resistivity and Hall effect measurements. The experimental set-up was tested with some standard samples.

  11. Utilization of lightweight materials made from coal gasification slags. Quarterly report, September 1, 1996--November 30, 1996

    SciTech Connect

    1997-04-01

    Integrated-gasification combined-cycle (IGCC) technology is an emerging technology that utilizes coal for power generation and production of chemical feedstocks. However, the process generates large amounts of solid waste, consisting of vitrified ash (slag) and some unconverted carbon. In previous projects, Praxis investigated the utilization of {open_quotes}as-generated{close_quotes} slags for a wide variety of applications in road construction, cement and concrete production, agricultural applications, and as a landfill material. From these studies, we found that it would be extremely difficult for {open_quotes}as-generated{close_quotes} slag to find large-scale acceptance in the marketplace even at no cost because the materials it could replace were abundantly available at very low cost. It was further determined that the unconverted carbon, or char, in the slag is detrimental to its utilization as sand or fine aggregate. It became apparent that a more promising approach would be to develop a variety of value-added products from slag that meet specific industry requirements. This approach was made feasible by the discovery that slag undergoes expansion and forms a lightweight material when subjected to controlled heating in a kiln at temperatures between 1400 and 1700{degrees}F. These results confirmed the potential for using expanded slag as a substitute for conventional lightweight aggregates (LWA). The major objectives of the subject project are to demonstrate the technical and economic viability of commercial production of LWA and ULWA from slag and to test the suitability of these aggregates for various applications.

  12. Development of a solid absorption process for removal of sulfur from fuel gas. First quarterly technical report

    SciTech Connect

    Stegen, G.E.; Olson, K.M.

    1980-05-01

    Battelle Pacific Northwest Laboratories has begun to develop a project for removing sulfur compounds from fuel gases at elevated temperature (> 700/sup 0/C) based on the use of molten mixtures of alkali metal carbonates and calcium carbonate as the active reactants. The sulfur removal capacity of the molten salt mixture may be regenerated by stripping with CO/sub 2/ and steam, usually at a reduced temperature. In this process, the molten salt mixture is contained within the pores of a porous ceramic substrate material which may be used in a packed bed, moving bed, or fluidized bed absorber. The process would be used most advantageously in applications where it is desirable to reduce or eliminate any cooling of the fuel gas between the gasifier outlet and the gas user. Examples of such applications include gas turbines, high temperature fuel cells, boilers, and furnaces which operate in relatively close proximity to a coal gasifier. In these applications, reduction or elimination of the gas cooling requirements will generally improve thermal efficiency by retaining the sensible heat in the gas and may result in simplification of the process by elimination of gas cooling (and in some cases reheating) equipment and by elimination of process condensates and the equipment required for their handling and treatment. The objectives of the program are to obtain process and materials data sufficient to demonstrate feasibility of the process at bench scale and to allow preliminary economic analysis. Process data to be obtained include sorbent sulfur capacity, reaction kinetics, and other operating characteristics. Various candidate materials will be purchased or fabricated and tested for suitability as porous ceramic substrate materials.

  13. Hazardous materials in aquatic environments of the Mississippi River Basin Project management. Technical quarterly progress report, April 1, 1996--June 30, 1996

    SciTech Connect

    McLachlan, J.; Ide, C.F.; O`Connor, S.

    1996-08-01

    This quarterly report summarizes accomplishments for the Project examining hazardous materials in aquatic environments of the Mississippi River Basin. Among the many research areas summarized are the following: assessment of mechanisms of metal-induced reproductive toxicity in aquatic species as a biomarker of exposure; hazardous wastes in aquatic environment;ecological sentinels of aquatic contamination in the lower Mississippi River System; remediation of selected contaminants; rapid on-site immunassay for heavy metal contamination; molecular mechanisms of developmental toxicity induced by retinoids and retinoid-like molecules; resuseable synthetic membranes for the removal of aromatic and halogenated organic pollutants from waste water; Effects of steroid receptor activation in neurendocrine cell of the mammalian hypothalamus; modeling and assessment of environmental quality of louisiana bayous and swamps; enhancement of environmental education. The report also contains a summary of publications resulting from this project and an appendix with analytical core protocals and target compounds and metals.

  14. Matrix Characterization in Threat Material Detection Processes

    SciTech Connect

    Obhodas, J.; Sudac, D.; Valkovic, V.

    2009-03-10

    Matrix characterization in the threat material detection is of utmost importance, it generates the background against which the threat material signal has to be identified. Threat materials (explosive, chemical warfare, ...) are usually contained within small volume inside large volumes of variable matrices. We have studied the influence of matrix materials on the capability of neutron systems to identify hidden threat material. Three specific scenarios are considered in some details: case 1--contraband material in the sea containers, case 2 - explosives in soil (landmines), case 3 - explosives and chemical warfare on the sea bottom. Effects of container cargo material on tagged neutron system are seen in the increase of gamma background and the decrease of neutron beam intensity. Detection of landmines is more complex because of variable soil properties. We have studied in detail space and time variations of soil elemental compositions and in particular hydrogen content (humidity). Of special interest are ammunitions and chemical warfare on the sea bottom, damping sites and leftovers from previous conflicts (WW-I, WW-II and local). In this case sea sediment is background source and its role is similar to the role of the soil in the landmine detection. In addition to geochemical cycling of chemical elements in semi-enclosed sea, like the Adriatic Sea, one has to consider also anthropogenic influence, especially when studying small scale variations in concentration levels. Some preliminary experimental results obtained with tagged neutron sensor inside an underwater vehicle are presented as well as data on sediment characterization by X-Ray Fluorescence.

  15. The materials processing research base of the Materials Processing Center. Report for FY 1982

    NASA Technical Reports Server (NTRS)

    Flemings, M. C.

    1983-01-01

    The work described, while involving research in the broad field of materials processing, has two common features: the problems are closed related to space precessing of materials and have both practical and fundamental significance. An interesting and important feature of many of the projects is that the interdisciplinary nature of the problem mandates complementary analytical modeling/experimental approaches. An other important aspect of many of the projects is the increasing use of mathematical modeling techniques as one of the research tools. The predictive capability of these models, when tested against measurements, plays a very important role in both the planning of experimental programs and in the rational interpretation of the results. Many of the projects described have a space experiment as their ultimate objective. Mathematical models are proving to be extremely valuable in projecting the findings of ground - based experiments to microgravity conditions.

  16. Pulse thermal processing of functional materials using directed plasma arc

    DOEpatents

    Ott, Ronald D.; Blue, Craig A.; Dudney, Nancy J.; Harper, David C.

    2007-05-22

    A method of thermally processing a material includes exposing the material to at least one pulse of infrared light emitted from a directed plasma arc to thermally process the material, the pulse having a duration of no more than 10 s.

  17. Materials and Processes for the New Millennium

    NASA Technical Reports Server (NTRS)

    Hayes, Paul W.; Richardson, Rod W.

    2004-01-01

    The single greatest threat to material availability over the last decade has been Compliance to New Environmental Regulations. Federal Regulations: a) Clean Air Acts Amendments - 1990 - Titles I, III and VI; b) NASA Interim Policy- 1995 end date; c) Montreal Protocol - 2000 and 2005 end dates; d) Industrial Toxics Project - HAP emissions by 1995; e) Florida DER - VOC limits by 1995 (CA); f) OSHA Health Related Regulations 1) Carcinogens 2) Mutagens 3). Material availability is complicated by local and state regulations and their own compliance schedules.

  18. Materials processing in space bibliography, 1983, revised

    NASA Technical Reports Server (NTRS)

    Pentecost, E. (Compiler)

    1983-01-01

    Flight experiments utilizing a low gravity environment to elucidate and control various processes, or ground based activities that provide supporting research are compiled. Six major categories: crystal growth; solidification of metals, alloys, and composites; fluids, transports, and chemical processes; glasses and ceramics; ultrahigh vacuum and containerless processing technologies; and combustion are included. A list of patents and appendices providing a compilation of anonymously authored collections and reports and a cross reference index are included.

  19. Electrochromic materials, devices and process of making

    DOEpatents

    Richardson, Thomas J.

    2003-11-11

    Thin films of transition metal compositions formed with magnesium that are metals, alloys, hydrides or mixtures of alloys, metals and/or hydrides exhibit reversible color changes on application of electric current or hydrogen. Thin films of these materials are suitable for optical switching elements, thin film displays, sun roofs, rear-view mirrors and architectural glass.

  20. Metal containing material processing on coater/developer system

    NASA Astrophysics Data System (ADS)

    Kawakami, Shinichiro; Mizunoura, Hiroshi; Matsunaga, Koichi; Hontake, Koichi; Nakamura, Hiroshi; Shimura, Satoru; Enomoto, Masashi

    2016-03-01

    Challenges of processing metal containing materials need to be addressed in order apply this technology to Behavior of metal containing materials on coater/developer processing including coating process, developer process and tool metal contamination is studied using CLEAN TRACKTM LITHIUS ProTM Z (Tokyo Electron Limited). Through this work, coating uniformity and coating film defectivity were studied. Metal containing material performance was comparable to conventional materials. Especially, new dispense system (NDS) demonstrated up to 80% reduction in coating defect for metal containing materials. As for processed wafer metal contamination, coated wafer metal contamination achieved less than 1.0E10 atoms/cm2 with 3 materials. After develop metal contamination also achieved less than 1.0E10 atoms/cm2 with 2 materials. Furthermore, through the metal defect study, metal residues and metal contamination were reduced by developer rinse optimization.

  1. Process modeling for carbon-phenolic nozzle materials

    NASA Technical Reports Server (NTRS)

    Letson, Mischell A.; Bunker, Robert C.; Remus, Walter M., III; Clinton, R. G.

    1989-01-01

    A thermochemical model based on the SINDA heat transfer program is developed for carbon-phenolic nozzle material processes. The model can be used to optimize cure cycles and to predict material properties based on the types of materials and the process by which these materials are used to make nozzle components. Chemical kinetic constants for Fiberite MX4926 were determined so that optimization of cure cycles for the current Space Shuttle Solid Rocket Motor nozzle rings can be determined.

  2. Investigation of the Geokinetics horizontal in situ oil shale retorting process. Quarterly report, January-March 1980

    SciTech Connect

    Hutchinson, D.L.

    1980-05-01

    Retort No. 18 produced 3479 barrels of oil during the quarter for a total of 4528 barrels to date. Chromatographic analyses of Retort No. 18 shale oil by the GKI analytical laboratory indicated variation in the oil from the wells near the air-in end and from the air-out end of the retort. Shale oil has been blended with Altamont crude (the Roosevelt refinery's normal feedstock); the distillation, API gravity, pour point, flash point, Naptha and Cat Gas were not affected by the shale oil. The diesel off the crude unit changed from water white to yellow, however, and a fine grayish-brown precipitate formed. Re-entry drilling was performed on Retorts No. 21, No. 22, and No. 23 during the quarter; tracer tests were run by Sandia Laboratories on Retorts No. 19, No. 21, No. 22, and No. 23. Blasthole drilling began on Retort No. 25.

  3. Process feasibility study in support of silicon material task 1

    NASA Technical Reports Server (NTRS)

    Yaws, C. L.; Li, K. Y.; Hopper, J. R.; Fang, C. S.; Hansen, K. C.

    1981-01-01

    Results for process system properties, chemical engineering and economic analyses of the new technologies and processes being developed for the production of lower cost silicon for solar cells are presented. Analyses of process system properties are important for chemical materials involved in the several processes under consideration for semiconductor and solar cell grade silicon production. Major physical, thermodynamic and transport property data are reported for silicon source and processing chemical materials.

  4. Organic materials for ceramic molding processes

    NASA Technical Reports Server (NTRS)

    Saito, K.

    1984-01-01

    Ceramic molding processes are examined. Binders, wetting agents, lubricants, plasticizers, surface active agents, dispersants, etc., for pressing, rubber pressing, sip casting, injection casting, taping, extrusion, etc., are described, together with forming machines.

  5. Multiphysical Simulation of Laser Material Processing

    NASA Astrophysics Data System (ADS)

    Otto, Andreas; Koch, Holger; Vazquez, Rodrigo Gomez

    Within this paper a multiphysical simulation model is presented that is capable for simulating a wide range of laser processes like e.g. laser beam welding, brazing, cutting, drilling or ablation. Some important aspects of the model are explained more in detail and results from test cases are compared with analytical solutions revealing the high accuracy of the model. Finally exemplary results from process simulations on laser beam remote cutting of steel and laser beam scribing of silicon wafers are given.

  6. IMPROVEMENT OF WEAR COMPONENT'S PERFORMANCE BY UTILIZING ADVANCED MATERIALS AND NEW MANUFACTURING TECHNOLOGIES: CASTCON PROCESS FOR MINING APPLICATIONS

    SciTech Connect

    Xiaodi Huang; Richard Gertsch

    2002-08-27

    The project has seen quite a bit of activity in this quarter, highlighted by the fabrication of a bit insert for field testing. In addition: (1) Several alternative process techniques were attempted to prevent bloating, cracking and delamination of FM material that occurs during binder burnout. The approaches included fabrication of FM material by three pass extrusion and warm isostatic pressing of green material, slow and confined burnouts as well as, burnout of thin plate instead of rod stock. Happily, a confined burnout followed by HIPing, produced FM button inserts without bloating or delamination. (2) Four rock bit inserts were produced from FM material and are ready for use on blast hole bits in the field. (3) Six of the project participants from Michigan Technological University, Advanced Ceramic Manufacturing, and The Robbins Group visited the Superior Rock Bit Company in Minnesota and planned the field test of FM inserts.

  7. Process for Self-Repair of Insulation Material

    NASA Technical Reports Server (NTRS)

    Parrish, Clyde F. (Inventor)

    2007-01-01

    A self-healing system for an insulation material initiates a self-repair process by rupturing a plurality of microcapsules disposed on the insulation material. When the plurality of microcapsules are ruptured reactants witlun the plurality of microcapsules react to form a replacement polymer in a break of the insulation material. This self-healing system has the ability to repair multiple breaks in a length of insulation material without exhausting the repair properties of the material.

  8. Process for self-repair of insulation material

    NASA Technical Reports Server (NTRS)

    Parrish, Clyde F. (Inventor)

    2007-01-01

    A self-healing system for an insulation material initiates a self-repair process by rupturing a plurality of microcapsules disposed on the insulation material. When the plurality of microcapsules are ruptured reactants within the plurality of microcapsules react to form a replacement polymer in a break of the insulation material. This self-healing system has the ability to repair multiple breaks in a length of insulation material without exhausting the repair properties of the material.

  9. Utilization of lightweight materials made from coal gasification slags. Quarterly report, December 1, 1995--February 28, 1996

    SciTech Connect

    1996-12-31

    The project scope consists of collecting a 20-ton sample of slag (primary slag), processing it for chart removal, and subjecting it to pyroprocessing to produce expanded slag aggregates of various size gradations and unit weights, ranging from 12 to 50 lb/fg{sup 3}. A second smaller slag sample will be used for confirmatory testing. The expanded slag aggregates will then be tested for their suitability in manufacturing precast concrete products (e.g., masonry blocks and roof tiles) and insulating concrete, first at the laboratory scale and subsequently in commercial manufacturing plants. These products will be evaluated using ASTM and industry test methods. Technical data generated during production and testing of the products will be used to assess the overall technical viability of expanded slag production. In addition, a market assessment will be made based on an evaluation of both the expanded slag aggregates and the final products, and market prices for these products will be established in order to assess the economic viability of these utilization technologies. Relevant cost data for physical and pyroprocessing of slag to produce expanded slag aggregates will be gathered for comparison with (1) the management and disposal costs for slag or similar wastes and (2) production costs for conventional materials which the slag aggregates would replace. This will form the basis for an overall economic evaluation of expanded slag utilization technologies.

  10. Laser processing for manufacturing nanocarbon materials

    NASA Astrophysics Data System (ADS)

    Van, Hai Hoang

    CNTs have been considered as the excellent candidate to revolutionize a broad range of applications. There have been many method developed to manipulate the chemistry and the structure of CNTs. Laser with non-contact treatment capability exhibits many processing advantages, including solid-state treatment, extremely fast processing rate, and high processing resolution. In addition, the outstanding monochromatic, coherent, and directional beam generates the powerful energy absorption and the resultant extreme processing conditions. In my research, a unique laser scanning method was developed to process CNTs, controlling the oxidation and the graphitization. The achieved controllability of this method was applied to address the important issues of the current CNT processing methods for three applications. The controllable oxidation of CNTs by laser scanning method was applied to cut CNT films to produce high-performance cathodes for FE devices. The production method includes two important self-developed techniques to produce the cold cathodes: the production of highly oriented and uniformly distributed CNT sheets and the precise laser trimming process. Laser cutting is the unique method to produce the cathodes with remarkable features, including ultrathin freestanding structure (~200 nm), greatly high aspect ratio, hybrid CNT-GNR emitter arrays, even emitter separation, and directional emitter alignment. This unique cathode structure was unachievable by other methods. The developed FE devices successfully solved the screening effect issue encounter by current FE devices. The laser-control oxidation method was further developed to sequentially remove graphitic walls of CNTs. The laser oxidation process was directed to occur along the CNT axes by the laser scanning direction. Additionally, the oxidation was further assisted by the curvature stress and the thermal expansion of the graphitic nanotubes, ultimately opening (namely unzipping) the tubular structure to

  11. Molten salt applications in materials processing

    NASA Astrophysics Data System (ADS)

    Mishra, Brajendra; Olson, David L.

    2005-02-01

    The science of molten salt electrochemistry for electrowinning of reactive metals, such as calcium, and its in situ application in pyro-reduction has been described. Calcium electrowinning has been performed in a 5 10 wt% calcium oxide calcium chloride molten salt by the electrolytic dissociation of calcium oxide. This electrolysis requires the use of a porous ceramic sheath around the anode to keep the cathodically deposited calcium and the anodic gases separate. Stainless steel cathode and graphite anode have been used in the temperature range of 850 950 °C. This salt mixture is produced as a result of the direct oxide reduction (DOR) of reactive metal oxides by calcium in a calcium chloride bath. The primary purpose of this process is to recover the expensive calcium reductant and to recycle calcium chloride. Experimental data have been included to justify the suitability as well as limitations of the electrowinning process. Transport of oxygen ions through the sheath is found to be the rate controlling step. Under the constraints of the reactor design, a calcium recovery rate of approx. 150 g/h was achieved. Feasibility of a process to produce metals by pyrometallurgical reduction, using the calcium reductant produced electrolytically within the same reactor, has been shown in a hybrid process. Several processes are currently under investigation to use this electrowon calcium for in situ reduction of metal oxides.

  12. Dielectric particle injector for material processing

    NASA Technical Reports Server (NTRS)

    Leung, Philip L. (Inventor)

    1992-01-01

    A device for use as an electrostatic particle or droplet injector is disclosed which is capable of injecting dielectric particles or droplets. The device operates by first charging the dielectric particles or droplets using ultraviolet light induced photoelectrons from a low work function material plate supporting the dielectric particles or droplets, and then ejecting the charged particles or droplets from the plate by utilizing an electrostatic force. The ejected particles or droplets are mostly negatively charged in the preferred embodiment; however, in an alternate embodiment, an ion source is used instead of ultraviolet light to eject positively charged dielectric particles or droplets.

  13. Processing of monolayer materials via interfacial reactions

    DOEpatents

    Sutter, Peter Werner; Sutter, Eli Anguelova

    2014-05-20

    A method of forming and processing of graphene is disclosed based on exposure and selective intercalation of the partially graphene-covered metal substrate with atomic or molecular intercalation species such as oxygen (O.sub.2) and nitrogen oxide (NO.sub.2). The process of intercalation lifts the strong metal-carbon coupling and restores the characteristic Dirac behavior of isolated monolayer graphene. The interface of graphene with metals or metal-decorated substrates also provides for controlled chemical reactions based on novel functionality of the confined space between a metal surface and a graphene sheet.

  14. Process Research ON Semix Silicon Materials (PROSSM)

    NASA Astrophysics Data System (ADS)

    Wohlgemuth, J. H.; Warfield, D. B.

    1982-02-01

    A cost effective process sequence was identified, equipment was designed to implement a 6.6 MW per year automated production line, and a cost analysis projected a $0.56 per watt cell add-on cost for this line. Four process steps were developed for this program: glass beads back clean-up, hot spray antireflective coating, wave soldering of fronts, and ion milling for edging. While spray dopants were advertised as an off the shelf developed product, they were unreliable with shorter than advertised shelf life.

  15. Alternative Processing of High Temperature Hafnium and Zirconium Based Materials

    NASA Technical Reports Server (NTRS)

    Gasch, Matthew; Gusman, Michael; Ellerby, Don; Irby, Edward; Johnson, Sylvia M.

    2003-01-01

    The behavior of refractory hafnium and zirconium based materials are being investigated at NASA Ames as part of ongoing research aimed at developing superior heat resistant materials for aerospace applications. Hafnium and zirconium diboride based materials have shown high temperature capabilities in simulated reentry environments indicating that these materials may successfully operate as reusable oxidation resistant components for leading edge applications. Due to the refractory nature of these materials, processing of fine-grained uniform microstructures poses a number of challenges. To better understand the process-property-microstructure relationship, processing of these materials has been carried out with conventional hot pressing in addition to the novel approach of Spark Plasma Sintering (SPS). The two processing methods are compared and contrasted in an evaluation of the sintering behavior of high temperature diboride based materials and preliminary physical and mechanical properties are presented.

  16. 2005 Research Briefs : Materials and Process Sciences Center.

    SciTech Connect

    Cieslak, Michael J.

    2005-05-01

    This report is the latest in a continuing series that highlights the recent technical accomplishments associated with the work being performed within the Materials and Process Sciences Center. Our research and development activities primarily address the materials-engineering needs of Sandia's Nuclear-Weapons (NW) program. In addition, we have significant efforts that support programs managed by the other laboratory business units. Our wide range of activities occurs within six thematic areas: Materials Aging and Reliability, Scientifically Engineered Materials, Materials Processing, Materials Characterization, Materials for Microsystems, and Materials Modeling and Simulation. We believe these highlights collectively demonstrate the importance that a strong materials-science base has on the ultimate success of the NW program and the overall DOE technology portfolio.

  17. 2003 research briefs : Materials and Process Sciences Center.

    SciTech Connect

    Cieslak, Michael J.

    2003-08-01

    This report is the latest in a continuing series that highlights the recent technical accomplishments associated with the work being performed within the Materials and Process Sciences Center. Our research and development activities primarily address the materials-engineering needs of Sandia's Nuclear-Weapons (NW) program. In addition, we have significant efforts that support programs managed by the other laboratory business units. Our wide range of activities occurs within six thematic areas: Materials Aging and Reliability, Scientifically Engineered Materials, Materials Processing, Materials Characterization, Materials for Microsystems and Materials Modeling and Computational Simulation. We believe these highlights collectively demonstrate the importance that a strong materials-science base has on the ultimate success of the NW program and the overall DOE technology portfolio.

  18. 2004 research briefs :Materials and Process Sciences Center.

    SciTech Connect

    Cieslak, Michael J.

    2004-01-01

    This report is the latest in a continuing series that highlights the recent technical accomplishments associated with the work being performed within the Materials and Process Sciences Center. Our research and development activities primarily address the materials-engineering needs of Sandia's Nuclear-Weapons (NW) program. In addition, we have significant efforts that support programs managed by the other laboratory business units. Our wide range of activities occurs within six thematic areas: Materials Aging and Reliability, Scientifically Engineered Materials, Materials Processing, Materials Characterization, Materials for Microsystems, and Materials Modeling and Simulation. We believe these highlights collectively demonstrate the importance that a strong materials-science base has on the ultimate success of the NW program and the overall DOE technology portfolio.

  19. Modern processes of copper concentration from mineral raw materials

    NASA Astrophysics Data System (ADS)

    Chekushin, V. S.; Oleinikova, N. V.; Shubakova, M. A.

    2015-12-01

    The modern technologies of processing of sulfide copper raw materials using high-output autogenous and semiautogenous processes are analyzed and compared with the "dead" roasting-reduction smelting technology.

  20. Hazardous materials in aquatic environments of the Mississippi River Basin. Quarterly project status report, July 1, 1993--September 30, 1993

    SciTech Connect

    Not Available

    1993-11-01

    This document is a brief progress report from each of the research and education projects that are currently funded through the ERWM contract. During third quarter 1993, approval was given by DOE for purchase of equipment. Equipment purchases were initiated and much of the equipment has been received and installed. The committees in charge of coordination of sampling and analyses associated with the collaborative research groups continued to meet and address these issues. Sampling has been done in the lower part of Devil`s Swamp and in the Devil`s Swamp Lake area. In addition, extensive sampling has been done in Bayou Trepagnier and in Bayou St. John. During this period, Tulane and Xavier Universities continued working closely with Oak Ridge National Laboratories (ORNL). The ORNL 1993 summer student internship program was completed. Plans were made for expanding the program to support 8 students next summer. Leonard Price, a Xavier University Chemistry professor and John Walz, a Tulane University Engineering professor each spent 5 weeks at ORNL. During this time these faculty worked with ORNL researchers exploring mutual interests and discussing possible future collaborations. In September, Drs. Carl Gehrs, Lee Shugart and Marshall Adams of ORNL, visited the Tulane and Xavier campuses. They presented two seminars and met with several of the investigators being supported by the ERWM contract. Tulane/Xavier project administrators participated in the Office of Technology Development`s ``New Technologies and Program Exhibition`` in the Rayburn House Office Building on September 23 and in the Hart Senate Office Building on September 27.

  1. Emerging materials for solar cell applications: electrodeposited CdTe. First quarter report, February 15-May 15, 1980

    SciTech Connect

    Rod, R L; Basol, B; Stafsudd, O

    1980-06-30

    The present program is a continuation of earlier efforts to develop electrochemically deposited films of compound semiconductors and solar cells made from them. Primary objectives include the development and characterization of controllably doped n and p type CdTe films with densities of 5.8 gm/cm/sup 3/, appropriate grain sizes, good film morphology and freedom from pinholes, and carrier concentrations from 10/sup 16/ to 10/sup 18//cm/sup 3/. The end result of the effort is to demonstrate by the seventh month, or September 15, 1980, solar cells over 1 cm/sup 2/ in area showing total area conversion efficiencies exceeding 4%. By the end of the first quarter, milestones were met calling for us to supply characterized n type CdTe films that were reproducible and free from pinholes. Also, prototype electrodeposited CdTe solar cells were fabricated and evaluated. Characterizations of p-type CdTe and ZnTe films were complicated by interferences existing between them and adjacent substrates. A number of devices, including the glass/ITO/n-CdTe:In/Au Schottky structure and an ITO/n-CdTe:In/p-Cu/sub 2-x/Te heterojunction, have been fabricated. The highest internal efficiency of the Schottky devices, which have yet to have fingered grids and anti-reflection coatings applied, is 4%. The heterojunction is a larger area device 2 cm/sup 2/ in area. It shows promise of meeting the 4% total area efficiency as does the Schottky when grids and A/R coatings are applied.

  2. Processing of superconductive materials and high frequency

    SciTech Connect

    Smith, J.L.

    1987-01-01

    We do not know yet if superconductivity will become useful without refrigeration. Now, the superconductors are so different from copper that it is difficult to imagine replacing copper with such a brittle material. Superconductors conduct dc with no loss, ac with small losses, and microwaves in co-axial lines with almost no loss and with no dispersion from dc to the highest frequencies. They will probably allow us to close the gap between radio frequency and infrared optical transmission. Clearly your industry should know some things about where superconductivity may lead us and must consider whether the greater risk is to develop them or to let others try it. There are no easy answers yet.

  3. Numerical study of the flow of granular materials down an inclined plane. Quarterly report, March 1, 1994--June 30, 1994

    SciTech Connect

    Not Available

    1994-09-01

    In the previous report the governing equations for the flow of granular materials down an inclined plane using the continuum model proposed by Rajagopal and Massoudi, were derived. The authors studied the effect of the various forms of the materials parameters ({beta}`s) on the velocity, volume fraction and temperature fields. In this report, the authors derive the governing equations for the flow of granular materials down an inclined plane using the kinetic theory based model proposed by Boyle and Massoudi.

  4. PROCESS OF DECONTAMINATING MATERIAL CONTAMINATED WITH RADIOACTIVITY

    DOEpatents

    Overholt, D.C.; Peterson, M.D.; Acken, M.F.

    1958-09-16

    A process is described for decontaminating metallic objects, such as stainless steel equipment, which consists in contacting such objects with nltric acid in a concentration of 35 to 60% to remove the major portion of the contamination; and thereafter contacting the partially decontaminated object with a second solution containing up to 20% of alkali metal hydroxide and up to 20% sodium tartrate to remove the remaining radioactive contaminats.

  5. FLUORINE PROCESS FOR SEPARATION OF MATERIALS

    DOEpatents

    Seaborg, G.T.; Brown, H.S.

    1958-05-01

    A process is described for separating plutoniunn from neutron-irradiated uranium, which consists of reacting the irradiated uranium mass with HF to form the tetrafluorides of U, Pu, and Np, and then reacting this mixture of tetrafluorides with fiuorine at temperature between 140 and 315 d C. This causes volatile hexafluorides of U and Np to form while at the temperature employed the Pu tetrafluoride is unaffected and remains as a residue.

  6. Microgravity Effects on Materials Processing: A Review. Appendix D

    NASA Technical Reports Server (NTRS)

    Wilcox, William R.; Regel, Liya L.

    2003-01-01

    Materials processing in space has been studied both theoretically and experimentally for over 1/4 of a century. In the beginning, we naively spoke of zero gravity, elimination of convection, growth of perfect crystals, and eventual manufacturing in space. All of these appear to have fallen by the wayside. On the other hand, we have learned an unprecedented amount about the influences of gravity on materials processing. We have had many surprises, and not all experimental results have yet been satisfactorily explained. Gravity was found to influence processes that were thought to be gravity-independent. One consequence is that materials processing on earth has often been improved. And it is difficult to imagine how the materials-processing industries could have flourished without the engineers and scientists who received their training by working on microgravity materials processing.

  7. Material Control and Accountability Measurements for FB-Line Processes

    SciTech Connect

    Casella, V.R.

    2002-12-03

    This report provides an overview of FB-Line processes and nuclear material accountability measurements. Flow diagrams for the product, waste, and packaging and stabilization processes are given along with the accountability measurements done before and after each of these processes. Brief descriptions of these measurements are provided. This information provides a better understanding of the general FB-Line processes and how MC and A measurements are used to keep track of the accountable material inventory.

  8. Process Feasibility Study in Support of Silicon Material, Task 1

    NASA Technical Reports Server (NTRS)

    Li, K. Y.; Hansen, K. C.; Yaws, C. L.

    1979-01-01

    During this reporting period, major activies were devoted to process system properties, chemical engineering and economic analyses. Analyses of process system properties was continued for materials involved in the alternate processes under consideration for solar cell grade silicon. The following property data are reported for silicon tetrafluoride: critical constants, vapor pressure, heat of varporization, heat capacity, density, surface tension, viscosity, thermal conductivity, heat of formation and Gibb's free energy of formation. Chemical engineering analysis of the BCL process was continued with primary efforts being devoted to the preliminary process design. Status and progress are reported for base case conditions; process flow diagram; reaction chemistry; material and energy balances; and major process equipment design.

  9. High temperature electrochemical polishing of H{sub 2}S from coal gasification process streams. Quarterly progress report, October 1, 1995--December 31, 1995

    SciTech Connect

    Winnick, J.

    1995-12-31

    An advanced process for the separation of hydrogen sulfide (H{sub 2}S) from coal gasification product streams through an electrochemical membrane is being developed. H{sub 2}S is removed from the syn-gas stream, split into hydrogen, which enriches the exiting syn-gas, and sulfur, which is condensed from an inert sweep gas stream. The process allows removal of H{sub 2}S without cooling the gas stream and with negligible pressure loss through the separator. The process is made economically attractive by the lack of need for a Claus process for sulfur recovery. Membrane manufacturing coupled with full-cell experimentation was the primary focus this quarter. A tape-casted zirconia membrane was developed and utilized in one full-cell experiment (run 25); run 24 utilized a fabricated membrane purchased from Zircar Corporation. Results are discussed.

  10. Process Research On Polycrystalline Silicon Material (PROPSM)

    NASA Technical Reports Server (NTRS)

    Culik, J. S.; Wohlgemuth, J. H.

    1982-01-01

    Performance limiting mechanisms in polycrystalline silicon are investigated by fabricating a matrix of solar cells of various thicknesses from polycrystalline silicon wafers of several bulk resistivities. The analysis of the results for the entire matrix indicates that bulk recombination is the dominant factor limiting the short circuit current in large grain (greater than 1 to 2 mm diameter) polycrystalline silicon, the same mechanism that limits the short circuit current in single crystal silicon. An experiment to investigate the limiting mechanisms of open circuit voltage and fill factor for large grain polycrystalline silicon is designed. Two process sequences to fabricate small cells are investigated.

  11. Materials processing with superposed Bessel beams

    NASA Astrophysics Data System (ADS)

    Yu, Xiaoming; Trallero-Herrero, Carlos A.; Lei, Shuting

    2016-01-01

    We report experimental results of femtosecond laser processing on the surface of glass and metal thin film using superposed Bessel beams. These beams are generated by a combination of a spatial light modulator (SLM) and an axicon with >50% efficiency, and they possess the long depth-of-focus (propagation-invariant) property as found in ordinary Bessel beams. Through micromachining experiments using femtosecond laser pulses, we show that multiple craters can be fabricated on glass with single-shot exposure, and the 1+(-1) superposed beam can reduce collateral damage caused by the rings in zero-order Bessel beams in the scribing of metal thin film.

  12. Process for fabricating composite material having high thermal conductivity

    DOEpatents

    Colella, Nicholas J.; Davidson, Howard L.; Kerns, John A.; Makowiecki, Daniel M.

    2001-01-01

    A process for fabricating a composite material such as that having high thermal conductivity and having specific application as a heat sink or heat spreader for high density integrated circuits. The composite material produced by this process has a thermal conductivity between that of diamond and copper, and basically consists of coated diamond particles dispersed in a high conductivity metal, such as copper. The composite material can be fabricated in small or relatively large sizes using inexpensive materials. The process basically consists, for example, of sputter coating diamond powder with several elements, including a carbide forming element and a brazeable material, compacting them into a porous body, and infiltrating the porous body with a suitable braze material, such as copper-silver alloy, thereby producing a dense diamond-copper composite material with a thermal conductivity comparable to synthetic diamond films at a fraction of the cost.

  13. Neutral beam processing of semiconductor materials

    SciTech Connect

    Cross, J.; Hoffbauer, M.

    1996-09-01

    This is the final report of a one-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The most important challenge facing the US and global microelectronics industry is to identify and develop the next generation of processing technology to produce device structures with dimensions substantially less than 0.25 microns. This project sought to develop controlled, contamination-free etching techniques that are more selective and less damaging than current methods, which are based on inducing surface chemical reactions by rather crude ion-damage mechanisms. The use of non-charged particle etching and cleaning processes in the production of memory and microprocessor chips has been identified by The National Technology Roadmap for Semiconductors as a new manufacturing technique that may aid in the quest for feature sizes of 0.1 micron and lower. The Hyperthermal Neutral Beam Facility at Los Alamos has demonstrated significant improvement over ion-assisted etching in experiments using energetic oxygen and chlorine atoms.

  14. Nonterrestrial material processing and manufacturing of large space systems

    NASA Technical Reports Server (NTRS)

    Vontiesenhausen, G. F.

    1978-01-01

    An attempt is made to provide pertinent and readily usable information on the extraterrestrial processing of materials and manufacturing of components and elements of these planned large space systems from preprocessed lunar materials which are made available at a processing and manufacturing site in space. Required facilities, equipment, machinery, energy and manpower are defined.

  15. Tulane/Xavier Universities hazardous materials in aquatic environments of the Mississippi River Basin. Quarterly progress report, October 1, 1995--December 31, 1995

    SciTech Connect

    1995-12-31

    To provide the necessary administrative support to assure that the scientific and educational goals of the project are obtained and to assure that all Department of Energy reporting requirements and requests are fulfilled.The grant reporting is divided into three aspects: Collaborative Cluster projects, Initiation projects and Education projects. A cluster project is one or more closely related collaborative, multidisciplinary research projects in which a group of investigators employs a synergistic approach to the solution of problems in the same general area of research. An initiation project typically involves a single investigator. The purpose of the project is to undertaken pilot work, lasting no more than one year, which will lead to the successful submission of an externally-funded proposal or the development of a collaborative cluster project. The education projects are designed to develop courses with emphasis on environmental studies and/or to train students in areas of environmental research. Accomplishments this quarter are: (1) Issued a request for proposals (RFP) to complete work during the next year of the project. Forty-two proposals were received in response to the RFP. (2) Selected and convened a panel of experts to review the proposals and make funding recommendations. (3) Assigned each proposal to two or more reviewers and sent copies of all proposals to each review panelist. (4) Interfaced with Oak Ridge National Laboratory regarding QA/QC issues related to sampling and analysis for the project. (5) Held numerous phone conversations with DOE representatives regarding funding allocations procedure changes as a result of the delays in the Federal budget and appropriations process this year. This quarterly report briefly describes research projects ongoing in this program.

  16. The role of the resid solvent in co-processing with finely divided catalysts. Quarterly report April--June 1993

    SciTech Connect

    Curtis, C.W.

    1993-11-01

    The primary purpose of the work performed this quarter was to establish under thermal and catalytic reaction conditions whether hydrogen transfer occurred between cycloalkane type structures that are present in resids and heteroatomic species that are present in coal and liquefied coal. The research this quarter focused upon evaluating benzophenone (BENZ) as a model acceptor for hydrogen that might be transferred from a cycloalkane, perhydropyrene (PHP), under coprocessing conditions. Hence, a number of reactions was performed in which BENZ was reacted alone in hydrogen and nitrogen atmospheres in the presence and absence of a catalytic agent, molybdenum naphthenate. Reactions were also performed using a combination of PHP and BENZ at a 1 to 1 weight ratio. Also performing this quarter were initial separations with petroleum resids. Two different resids were used, Maya and LHC-362. The literature was also surveyed to determine important characteristics that should be evaluated for selecting resids. The resids that are desired for this project are resids with high-, medium-, and low-naphthenic content. Different levels of asphaltenes are also desirable. Resids with these characteristics are currently being sought. The model compound PHP that had been commercially available as naphthene representative of resids is now no longer available. Hence, several scoping experiments were performed in order to determine conditions for synthesizing PHP. The synthesis procedure reported in US Patent 3,303,227 was used as a basis for this work. Although more than 85% PHP was synthesized, partially hydrogenated pyrenes were also produced which will require separation in order to obtain pure PHP.

  17. Computer-Aided Process Model For Carbon/Phenolic Materials

    NASA Technical Reports Server (NTRS)

    Letson, Mischell A.; Bunker, Robert C.

    1996-01-01

    Computer program implements thermochemical model of processing of carbon-fiber/phenolic-matrix composite materials into molded parts of various sizes and shapes. Directed toward improving fabrication of rocket-engine-nozzle parts, also used to optimize fabrication of other structural components, and material-property parameters changed to apply to other materials. Reduces costs by reducing amount of laboratory trial and error needed to optimize curing processes and to predict properties of cured parts.

  18. Energy from in situ processing of antrim oil shale. Quarterly technical progress report, October-December 1979

    SciTech Connect

    Washington, L.J. Jr.

    1980-01-21

    Extraction trials on the new site were begun. The first trial, F80-1, was completed in Well No. 301 in October, 1979. Using a methane burner and an ignition service from TOR Developments, Inc., downhole burner ignition was readily achieved. Shale ignition occurred within two days. Combustion in the wellbore was so intense that the burner was lost, and subsequently shale combustion decreased and the trial was terminated. After some modification of equipment and procedures, the second trial, F80-2, was begun in late November, 1979. Combustion was achieved and the trial was still in progress at the end of the quarter.

  19. Portable nuclear material detector and process

    DOEpatents

    Hofstetter, Kenneth J; Fulghum, Charles K; Harpring, Lawrence J; Huffman, Russell K; Varble, Donald L

    2008-04-01

    A portable, hand held, multi-sensor radiation detector is disclosed. The detection apparatus has a plurality of spaced sensor locations which are contained within a flexible housing. The detection apparatus, when suspended from an elevation, will readily assume a substantially straight, vertical orientation and may be used to monitor radiation levels from shipping containers. The flexible detection array can also assume a variety of other orientations to facilitate any unique container shapes or to conform to various physical requirements with respect to deployment of the detection array. The output of each sensor within the array is processed by at least one CPU which provides information in a usable form to a user interface. The user interface is used to provide the power requirements and operating instructions to the operational components within the detection array.

  20. Compatibility of refrigerants and lubricants with motor materials. Quarterly technical progress report, 1 July 1992--30 September 1992

    SciTech Connect

    Doerr, R.; Kujak, S.

    1992-10-01

    During the compatibility study of 10 pure refrigerants with 24 motor materials, it was observed that the greatest damage to the insulation system was caused by absorption of refrigerant followed by rapid desorption. The observed effects were blisters, cracking, internal bubbles and delamination. Measured results includes decreased bond strength, dielectric strength and overall integrity of the material. Refrigerants HCFC-22, HFC-32, HFC-134 and HFC-152a exhibited this phenomena. The effect of HCFC-22 was most severe of the tested refrigerants. Since HCFC-22 has an excellent reliability history with many of the materials tested, compatibility with the new refrigerants is expected.

  1. Investigation of test methods, material properties, and processes for solar cell encapsulants. Encapsulation task of the low-cost silicon solar array project

    NASA Technical Reports Server (NTRS)

    1977-01-01

    During this quarter, flat-plate solar collector systems were considered and six basic construction elements were identified: outer coatings, superstrates, pottants, substrates, undercoats, and adhesives. Materials surveys were then initiated to discover either generic classes or/and specific products to function as each construction element. Cost data included in the surveys permit ready evaluation of each material. Silicones, fluorocarbons, glass, and acrylic polymers have the highest inherent weatherability of materials studied to date. Only acrylics, however, combine low costs, environmental resistance, and potential processability. This class will receive particular emphasis.

  2. Ground based research in microgravity materials processing

    NASA Technical Reports Server (NTRS)

    Workman, Gary L.; Rathz, Tom

    1994-01-01

    The core activities performed during this time period have been concerned with tracking the TEMPEST experiments on the shuttle with drops of Zr, Ni, and Nb alloys. In particular a lot of Zr drops are being made to better define the recalescence characteristics of that system so that accurate comparisons of the drop tube results with Tempest can be made. A new liner, with minimal reflectivity characteristics, has been inserted into the drop tube in order to improve the recalescence measurements of the falling drops. The first installation to make the geometric measurements to ensure a proper fit has been made. The stovepipe sections are currently in the shop at MSFC being painted with low reflectivity black paint. Work has also continued on setting up the MEL apparatus obtained from Oak Ridge in the down stairs laboratory at the Drop Tube Facilities. Some ground-based experiments on the same metals as are being processed on TEMPEST are planned for the MEL. The flight schedules for the KC-135 experiments are still to be determined in the near future.

  3. A survey of the economics of materials processing in space. [accenting biomedical materials

    NASA Technical Reports Server (NTRS)

    Miller, B. P.

    1975-01-01

    A survey of the economics of space materials processing has been performed with the objectives of identifying those areas of space materials processing that give preliminary indication of significant economic potential, and to identify possible approaches to quantify the economic potential. It is concluded that limited economic studies have been performed to date, primarily in the area of the processing of inorganic materials, but that the economics of space processing of biological material has not received adequate attention. Specific studies are recommended to evaluate the economic impact of human lymphocyte subgroup separation on organ transplantation, and on the separation and concentration of urokinase producing cells.

  4. Conversion of coal wastes into waste-cleaning materials. Quarterly progress report, January 1, 1997--March 31, 1997

    SciTech Connect

    Shih, W.H.

    1997-09-01

    In this report, we present more detailed study on the microstructure and chemical compositions of the MCM-41 phase converted from Conemiaugh ash. The converted mesoporous material was analyzed by TEM and the Energy Dispersive X-ray Spectroscopy in the TEM. This part of the work was done in collaboration with Princeton University. The hexagonal mesoporous structure was found to have a pore size about 26. 1 {Angstrom} with a Si/Al mole ratio of 13.4. In addition, we studied the conversion of several other fly ashes with a wide range of chemical compositions to mesoporous aluminosilicates. It was found that both Eddystone and Goudey fly ashes can be successfully converted into MCM-41 aluminosilicates. Moreover, besides working on the synthesis of aluminosilicate mesoporous materials by fusion of fly ash and Ca(OH){sub 2} powder. The nitrogen adsorption/desorption isotherms and XRD patterns of this mesoporous material using Ca(OH){sub 2} were similar to those of mesoporous material using NaOH. It is not clear at the moment whether the mesoporous materials using Ca(OH){sub 2} contains any Ca or not. If it odes, then the mesoporous materials synthesized with Ca(OH){sub 2} may be very useful for SO{sub 2}/NO gas adsorption in pollutant emission control by the reaction between those gases with Ca.

  5. Materials-based process tolerances for neutron generator encapsulation.

    SciTech Connect

    Berry, Ryan S.; Adolf, Douglas Brian; Stavig, Mark Edwin

    2007-10-01

    Variations in the neutron generator encapsulation process can affect functionality. However, instead of following the historical path in which the effects of process variations are assessed directly through functional tests, this study examines how material properties key to generator functionality correlate with process variations. The results of this type of investigation will be applicable to all generators and can provide insight on the most profitable paths to process and material improvements. Surprisingly, the results at this point imply that the process is quite robust, and many of the current process tolerances are perhaps overly restrictive. The good news lies in the fact that our current process ensures reproducible material properties. The bad new lies in the fact that it would be difficult to solve functional problems by changes in the process.

  6. Surface engineering of glazing materials and structures using plasma processes

    SciTech Connect

    Anders, Andre; Monteiro, Othon R.

    2003-04-10

    A variety of coatings is commercially produced on a very large scale, including transparent conducting oxides and multi-layer silver-based low-emissivity and solar control coatings. A very brief review of materials and manufacturing process is presented and illustrated by ultrathin silver films and chevron copper films. Understanding the close relation between manufacturing processes and bulk and surface properties of materials is crucial for film growth and self-assembly processes.

  7. Numerical study of the flow of granular materials down an inclined plane. Quarterly report, October 1, 1994--January 30, 1995

    SciTech Connect

    Rajagopal, K.R.

    1994-12-31

    In the previous report the governing equations were derived for the flow of granular materials down an inclined plane using the kinetic theory based model proposed by Boyle and Massoudi (1990). For a fully developed flow of these materials down an inclined plane, the equations reduce to a system of coupled non-linear ordinary differential equations. The resulting boundary value problem was solved numerically and a parametric study was carried out to delineate how the various non-dimensional parameters affect the structure of the solution. Further parametric studies were carried out and the results were in keeping with the previous studies. Also, a study of the flow of granular material between two vertical plates was carried out and compared with experiments in order to evaluate the continuum model.

  8. Materials Compatibility and Lubricants Research on CFC-refrigerant substitutes. Quarterly progress report, 1 July 1992--30 September 1992

    SciTech Connect

    Hourahan, G.C.; Szymurski, S.R.

    1992-10-01

    The Materials Compatibility and Lubricants Research (MCLR) program supports critical research to accelerate the introduction of CFC-refrigerant substitutes. The MCLR program addresses refrigerant and lubricant properties and materials compatibility. The primary elements of the work include data collection and dissemination, materials compatibility testing, and methods development. The work is guided by an Advisory Committee consisting of technical experts from the refrigeration and air-conditioning industry and government agencies. Under the current MCLR pregrain the Air-Conditioning and Refrigeration Technology Institute, Inc., (ARTI) is contracting and managing several research projects and a data collection and dissemination effort. Preliminary results is from these projects are reported in technical progress reports prepared by each researcher.

  9. Inline quality prognosis of material condition induced process variations

    NASA Astrophysics Data System (ADS)

    Heinzler, Felix A.; Wortberg, Johannes

    2014-05-01

    The main variation in a good quality production are induced by material condition. Processing technical polymers like PA, ABS or PBT possible influences are residual moisture conditions of the material or minor variations of raw material charges. Small changes in the material properties are difficult to detect at first quality controls and can be within the property tolerances. But even these small differences cause defects. The effects range from viscosity variations to varied crystalline properties. The influence of material properties on the processing have to be detected inline and combined with material analysis to a quality prognosis. The equipped sensors at injection molding machines enable an adequate process performance. The recently available solutions for power consumption monitoring enhance the available process control opportunities. Because of the high process speed of injection molding machines, the required sampling rate has to be minimal 500 Hz. A setup of high bandwidth data processing linked to the machine control enables precise characterization of the production. Identified index numbers, energetic data and characteristic development of measured process figures enable a high resolution detection of material induced variations. This prognosis enables inline classification of the produced parts and a compensation by correlating quality requirements with adjusted filling and packing parameters.

  10. Compatibility of refrigerants and lubricants with motor materials. Quarterly technical progress report, 1 October 1992--31 December 1992

    SciTech Connect

    Doerr, R.; Kujak, S.; Waite, T.

    1993-01-01

    Equipment manufacturers are challenged to replace CFC-based refrigerants and their lubricants with environmentally acceptable alternatives. Information on the compatibility of motor materials with these alternative refrigerants and lubricants is a basic requirement for reliable performance. This report presents compatibility data for 24 commercially used motor materials exposed to 17 refrigerant/lubricant combinations. This compatibility data will enable the phase out of CFC`s to continue at its current fast pace and insure the continued reliable performance of refrigerant-based equipment.

  11. Processing and analysis techniques involving in-vessel material generation

    DOEpatents

    Schabron, John F.; Rovani, Jr., Joseph F.

    2012-09-25

    In at least one embodiment, the inventive technology relates to in-vessel generation of a material from a solution of interest as part of a processing and/or analysis operation. Preferred embodiments of the in-vessel material generation (e.g., in-vessel solid material generation) include precipitation; in certain embodiments, analysis and/or processing of the solution of interest may include dissolution of the material, perhaps as part of a successive dissolution protocol using solvents of increasing ability to dissolve. Applications include, but are by no means limited to estimation of a coking onset and solution (e.g., oil) fractionating.

  12. Processing and analysis techniques involving in-vessel material generation

    DOEpatents

    Schabron, John F.; Rovani, Jr., Joseph F.

    2011-01-25

    In at least one embodiment, the inventive technology relates to in-vessel generation of a material from a solution of interest as part of a processing and/or analysis operation. Preferred embodiments of the in-vessel material generation (e.g., in-vessel solid material generation) include precipitation; in certain embodiments, analysis and/or processing of the solution of interest may include dissolution of the material, perhaps as part of a successive dissolution protocol using solvents of increasing ability to dissolve. Applications include, but are by no means limited to estimation of a coking onset and solution (e.g., oil) fractionating.

  13. Process for application of powder particles to filamentary materials

    NASA Technical Reports Server (NTRS)

    Baucom, Robert M. (Inventor); Snoha, John J. (Inventor); Marchello, Joseph M. (Inventor)

    1991-01-01

    This invention is a process for the uniform application of polymer powder particles to a filamentary material in a continuous manner to form a uniform composite prepreg material. A tow of the filamentary material is fed under carefully controlled tension into a spreading unit, where it is spread pneumatically into an even band. The spread filamentary tow is then coated with polymer particles from a fluidized bed, after which the coated filamentary tow is fused before take-up on a package for subsequent utilization. This process produces a composite prepreg uniformly without imposing severe stress on the filamentary material, and without requiring long, high temperature residence times for the polymer.

  14. High-energy ion processing of materials for improved hardcoatings

    SciTech Connect

    Williams, J.M.; Gorbatkin, S.M.; Rhoades, R.L.; Oliver, W.C.; Riester, L.; Tsui, T.Y.

    1994-02-01

    Research has been directed toward use of economically viable ion processing strategies for production and improvement of hardcoatings. Processing techniques were high-energy ion implantation and electron cyclotron resonance microwave plasma processing. Subject materials were boron suboxides, Ti-6Al-4V alloy, CoCrMo alloy (a Stellite{trademark}), and electroplated Cr. These materials may be regarded either as coatings themselves (which might be deposited by thermal spraying, plasma processing, etc.) or in some cases, as substrates whose surfaces can be improved. hardness and other properties in relation to process variables are reported.

  15. Oil shale, tar sand, coal research advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, October--December 1992

    SciTech Connect

    Speight, J.G.

    1992-12-31

    Accomplishments for the past quarter are presented for the following five tasks: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale research covers oil shale process studies. Tar sand research is on process development of Recycle Oil Pyrolysis and Extraction (ROPE) Process. Coal research covers: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes: advanced process concepts;advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; NMR analysis of samples from the ocean drilling program; in situ treatment of manufactured gas plant contaminated soils demonstration program; and solid state NMR analysis of naturally and artificially matured kerogens.

  16. Numerical study of the flow of granular materials down an inclined plane. Quarterly report, October 1, 1993--February 28, 1994

    SciTech Connect

    Rajagopal, K.R.

    1994-05-01

    In the previous report the governing equations for the flow of granular materials down an inclined plane, modeled by the constitutive theory proposed by Boyle and Massoudi (1990) were derived. These equations are solved numerically subject to the appropriate boundary conditions. The effect of various non-dimensional parameters on the volume fraction and velocity are presented in the form of graphs. In this report we derive the governing equations for the flow of granular materials down an inclined plane using the continuum model proposed by Rajagopal and Massoudi [cf. Goodman and Cowin (1971, 1972), Rajagopal and Massoudi (1990)]. Here, we study the effect of the various forms of the materials parameters ({Beta}`s) as discussed in Case I, II, and III in the following sections. The numerical solutions for case I and case II were presented in the earlier reports and case III are presented in the form of graphs for various nondimensional parameters. Also, the solutions from Case I, II, and III are compared to see how the structure of the material parameters affect the velocity, volume fraction and temperature fields.

  17. Alternative processing methods for tungsten-base composite materials

    SciTech Connect

    Ohriner, E.K.; Sikka, V.K.

    1995-12-31

    Tungsten composite materials contain large amounts of tungsten distributed in a continuous matrix phase. Current commercial materials include the tungsten-nickel-iron with cobalt replacing some or all of the iron, and also tungsten-copper materials. Typically, these are fabricated by liquid-phase sintering of blended powders. Liquid-phase sintering offers the advantages of low processing costs, established technology, and generally attractive mechanical properties. However, liquid-phase sintering is restricted to a very limited number of matrix alloying elements and a limited range of tungsten and alloying compositions. In the past few years, there has been interest in a wider range of matrix materials that offer the potential for superior composite properties. These must be processed by solid-state processes and at sufficiently low temperatures to avoid undesired reactions between the tungsten and the matrix phase. These processes, in order of decreasing process temperature requirements, include hot-isostatic pressing (HIPing), hot extrusion, and dynamic compaction. The HIPing and hot extrusion processes have also been used to improve mechanical properties of conventional liquid-phase-sintered materials. Results of laboratory-scale investigations of solid-state consolidation of a variety of matrix materials, including titanium, hafnium, nickel aluminide, and steels are reviewed. The potential advantages and disadvantages of each of the possible alternative consolidation processes are identified. Postconsolidation processing to control microstructure and macrostructure is discussed, including novel methods of controlling microstructure alignment.

  18. Alternative processing methods for tungsten-base composite materials

    SciTech Connect

    Ohriner, E.K.; Sikka, V.K.

    1996-06-01

    Tungsten composite materials contain large amounts of tungsten distributed in a continuous matrix phase. Current commercial materials include the tungsten-nickel-iron with cobalt replacing some or all of the iron, and also tungsten-copper materials. Typically, these are fabricated by liquid-phase sintering of blended powders. Liquid-phase sintering offers the advantages of low processing costs, established technology, and generally attractive mechanical properties. However, liquid-phase sintering is restricted to a very limited number of matrix alloying elements and a limited range of tungsten and alloying compositions. In the past few years, there has been interest in a wider range of matrix materials that offer the potential for superior composite properties. These must be processed by solid-state processes and at sufficiently low temperatures to avoid undesired reactions between the tungsten and the matrix phase. These processes, in order of decreasing process temperature requirements, include hot isostatic pressing (HEPing), hot extrusion, and dynamic compaction. The HIPing and hot extrusion processes have also been used to improve mechanical properties of conventional liquid-phase-sintered materials. The results of laboratory-scale investigations of solid-state consolidation of a variety of matrix materials, including titanium, hafnium, nickel aluminide, and steels are reviewed. The potential advantages and disadvantages of each of the possible alternative consolidation processes are identified. Post consolidation processing to control microstructure and macrostructure is discussed, including novel methods of controlling microstructure alignment.

  19. Solid electrolyte material manufacturable by polymer processing methods

    DOEpatents

    Singh, Mohit; Gur, Ilan; Eitouni, Hany Basam; Balsara, Nitash Pervez

    2012-09-18

    The present invention relates generally to electrolyte materials. According to an embodiment, the present invention provides for a solid polymer electrolyte material that is ionically conductive, mechanically robust, and can be formed into desirable shapes using conventional polymer processing methods. An exemplary polymer electrolyte material has an elastic modulus in excess of 1.times.10.sup.6 Pa at 90 degrees C. and is characterized by an ionic conductivity of at least 1.times.10.sup.-5 Scm-1 at 90 degrees C. An exemplary material can be characterized by a two domain or three domain material system. An exemplary material can include material components made of diblock polymers or triblock polymers. Many uses are contemplated for the solid polymer electrolyte materials. For example, the present invention can be applied to improve Li-based batteries by means of enabling higher energy density, better thermal and environmental stability, lower rates of self-discharge, enhanced safety, lower manufacturing costs, and novel form factors.

  20. Optical waveguide solar energy system for lunar material processing

    SciTech Connect

    Nakamura, T.; Senior, C.L.; Shoji, J.M.; Waldron, R.D.

    1995-11-01

    This paper summarizes the study on the optical waveguide (OW) solar energy system for lunar material processing. In the OW solar energy system, solar radiation is collected by the concentrator which transfers the concentrated solar radiation to the OW transmission line consisting of low-loss optical fibers and related optical components. The OW line transmits the high intensity solar radiation to the thermal reactor of the lunar materials processing plant. Based on the results discussed in this paper the authors conclude that the OW solar energy system is a viable concept which can effectively utilize solar energy for lunar material processing.

  1. Challenge to advanced materials processing with lasers in Japan

    NASA Astrophysics Data System (ADS)

    Miyamoto, Isamu

    2003-02-01

    Japan is one of the most advanced countries in manufacturing technology, and lasers have been playing an important role for advancement of manufacturing technology in a variety of industrial fields. Contribution of laser materials processing to Japanese industry is significant for both macroprocessing and microprocessing. The present paper describes recent trend and topics of industrial applications in terms of the hardware and the software to show how Japanese industry challenges to advanced materials processing using lasers, and national products related to laser materials processing are also briefly introduced.

  2. Processing and Disposition of Special Actinide Target Materials - 13138

    SciTech Connect

    Robinson, Sharon M.; Patton, Brad D.; Allender, Jeffrey S.

    2013-07-01

    The Department of Energy (DOE) manages an inventory of materials that contains a range of long-lived radioactive isotopes that were produced from the 1960's through the 1980's by irradiating targets in high-flux reactors at the Savannah River Site (SRS) to produce special heavy isotopes for DOE programmatic use, scientific research, and industrial and medical applications. Among the products were californium-252, heavy curium (including Cm-246 through Cm-248), and plutonium-242 and -244. Many of the isotopes are still in demand today, and they can be recovered from the remaining targets previously irradiated at SRS or produced from the recovered isotopes. Should the existing target materials be discarded, the plutonium (Pu) and curium (Cm) isotopes cannot be replaced readily with existing production sources. Some of these targets are stored at SRS, while other target material is stored at Oak Ridge National Laboratory (ORNL) at several stages of processing. The materials cannot be stored in their present form indefinitely. Their long-term management involves processing items for beneficial use and/or for disposition, using storage and process facilities at SRS and ORNL. Evaluations are under way for disposition options for these materials, and demonstrations of improved flow sheets to process the materials are being conducted at ORNL and the Savannah River National Laboratory (SRNL). The disposition options and a management evaluation process have been developed. Processing demonstrations and evaluations for these unique materials are under way. (authors)

  3. High temperature electrochemical separation of H{sub 2}S from coal gasification process streams. Quarterly progress report, January 1, 1994--March 31, 1994

    SciTech Connect

    Winnick, J.

    1994-07-01

    An electrochemical membrane separation system for removing H{sub 2}S from coal gasification product steams is the subject of this investigation. The high operating temperature, flow-through design, and capability of selective H{sub 2}S removal and direct production of elemental sulfur offered by this process provide several advantages over existing and developmental H{sub 2}S removal technologies. Two experiments (Run {number_sign}17 & {number_sign}18) examining the removal capability of the EMS with cobalt cathode were performed this quarter. The focus dealt with H{sub 2}S removal as well as impeding hydrogen cross-over from the process gas side (cathode) of the membrane to the sweep gas side (anode).

  4. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, January--March 1993

    SciTech Connect

    Not Available

    1993-09-01

    Accomplishments for the past quarter are briefly described for the following areas of research: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale and tar sand researches cover processing studies. Coal research includes: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology covers: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW{sup TM} field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid-state NMR analysis of Mesaverde Group, Greater Green River Basin tight gas sands; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; oil field waste cleanup using tank bottom recovery process; remote chemical sensor development; in situ treatment of manufactured gas plant contaminated soils demonstration program; solid-state NMR analysis of naturally and artificially matured kerogens; and development of an effective method for the clean-up of natural gas.

  5. Field study of disposed wastes from advanced coal processes. Quarterly technical progress report, October--December 1992

    SciTech Connect

    Not Available

    1992-12-31

    The specific objectives for the reporting period of October, 1992 to December, 1992 were as follows: (1) Finish analyzing leachates from the third annual core samples from the Ohio site, collected in August 1992; (2) Collect and analyze the sixth quarterly water samples from the first Illinois test case in August, 1992. Make field measurements and collect data from the data logger; (3) Begin construction of the second Illinois test case; (4) Continue production of a video presentation on the project; (5) Load all remaining EERC data on the Colorado and Ohio sites into the project database; (6) Finalize plans with METC for continued monitoring at the Colorado and Ohio sites beyond the initial three year period, and (7) Submit and the Final Case Report on the Colorado site to the DOE and EPRI.

  6. Oxidation processes in magneto-optic and related materials

    NASA Technical Reports Server (NTRS)

    Lee, Paul A.; Armstrong, Neal R.; Danzinger, James L.; England, Craig D.

    1992-01-01

    The surface oxidation processes of thin films of magneto-optic materials, such as the rare-earth transition metal alloys have been studied, starting in ultrahigh vacuum environments, using surface analysis techniques, as a way of modeling the oxidation processes which occur at the base of a defect in an overcoated material, at the instant of exposure to ambient environments. Materials examined have included FeTbCo alloys, as well as those same materials with low percentages of added elements, such a Ta, and their reactivities to both O2 and H2O compared with materials such as thin Fe films coated with ultrathin adlayers of Ti. The surface oxidation pathways for these materials is reviewed, and XPS data presented which indicates the type of oxides formed, and a critical region of Ta concentration which provides optimum protection.

  7. Chalcogenide material strengthening through the lens molding process

    NASA Astrophysics Data System (ADS)

    Nelson, J.; Scordato, M.; Lucas, Pierre; Coleman, Garrett J.

    2016-05-01

    The demand for infrared transmitting materials has grown steadily for several decades as markets realize new applications for longer wavelength sensing and imaging. With this growth has come the demand for new and challenging material requirements that cannot be satisfied with crystalline products alone. Chalcogenide materials, with their unique physical, thermal, and optical properties, have found acceptance by designers and fabricators to meet these demands. No material is perfect in every regard, and chalcogenides are no exception. A cause for concern has been the relatively low fracture toughness and the propensity of the bulk material to fracture. This condition is amplified when traditional subtractive manufacturing processes are employed. This form of processing leaves behind micro fractures and sub surface damage, which act as propagation points for both local and catastrophic failure of the material. Precision lens molding is not a subtractive process, and as a result, micro fractures and sub surface damage are not created. This results in a stronger component than one produced by traditional methods. New processing methods have also been identified that result in an even stronger surface that is more resistant to breakage, without the need for post processing techniques that may compromise surface integrity. This paper will discuss results achieved in the process of lens molding development at Edmund Optics that result in measurably stronger chalcogenide components. Various metrics will be examined and data will be presented that quantifies component strength for different manufacturing processes.

  8. Optical Waveguide Solar Energy System for Lunar Materials Processing

    NASA Technical Reports Server (NTRS)

    Nakamura, T.; Case, J. A.; Senior, C. L.

    1997-01-01

    This paper discusses results of our work on development of the Optical Waveguide (OW) Solar Energy System for Lunar Materials Processing. In the OW system as shown, solar radiation is collected by the concentrator which transfers the concentrated solar radiation to the OW transmission line consisting of low-loss optical fibers. The OW line transmits the solar radiation to the thermal reactor of the lunar materials processing plant. The feature of the OW system are: (1) Highly concentrated solar radiation (up to 104 suns) can be transmitted via flexible OW lines directly into the thermal reactor for materials processing: (2) Solar radiation intensity or spectra can be tailored to specific materials processing steps; (3) Provide solar energy to locations or inside of enclosures that would not otherwise have an access to solar energy; and (4) The system can be modularized and can be easily transported to and deployed at the lunar base.

  9. Use of energetic ion beams in materials synthesis and processing

    SciTech Connect

    Appleton, B R

    1991-01-01

    A brief review of the use energetic ion beams and related techniques for the synthesis, processing, and characterization of materials is presented. Selected opportunity areas are emphasized with examples, and references are provided for more extensive coverage.

  10. Missouri Introduction to Materials and Processing Technology. Instructor Guide.

    ERIC Educational Resources Information Center

    Missouri Univ., Columbia. Instructional Materials Lab.

    This guide is intended to support a high school specialization course in materials and processing technology. The document contains three sections: (1) information on using the material; (2) a set of instructor guides for eight instructional units; (3) 15 technological activity modules and teacher and student instructions for their use; and (4)…

  11. Processing lunar soils for oxygen and other materials

    NASA Technical Reports Server (NTRS)

    Knudsen, Christian W.; Gibson, Michael A.

    1992-01-01

    Two types of lunar materials are excellent candidates for lunar oxygen production: ilmenite and silicates such as anorthite. Both are lunar surface minable, occurring in soils, breccias, and basalts. Because silicates are considerably more abundant than ilmenite, they may be preferred as source materials. Depending on the processing method chosen for oxygen production and the feedstock material, various useful metals and bulk materials can be produced as byproducts. Available processing techniques include hydrogen reduction of ilmenite and electrochemical and chemical reductions of silicates. Processes in these categories are generally in preliminary development stages and need significant research and development support to carry them to practical deployment, particularly as a lunar-based operation. The goal of beginning lunar processing operations by 2010 requires that planning and research and development emphasize the simplest processing schemes. However, more complex schemes that now appear to present difficult technical challenges may offer more valuable metal byproducts later. While they require more time and effort to perfect, the more complex or difficult schemes may provide important processing and product improvements with which to extend and elaborate the initial lunar processing facilities. A balanced R&D program should take this into account. The following topics are discussed: (1) ilmenite--semi-continuous process; (2) ilmenite--continuous fluid-bed reduction; (3) utilization of spent ilmenite to produce bulk materials; (4) silicates--electrochemical reduction; and (5) silicates--chemical reduction.

  12. Information systems for material flow management in construction processes

    NASA Astrophysics Data System (ADS)

    Mesároš, P.; Mandičák, T.

    2015-01-01

    The article describes the options for the management of material flows in the construction process. Management and resource planning is one of the key factors influencing the effectiveness of construction project. It is very difficult to set these flows correctly. The current period offers several options and tools to do this. Information systems and their modules can be used just for the management of materials in the construction process.

  13. Utilization of lightweight materials made from coal gasification slags. Quarterly report, December 1, 1997--February 28, 1998

    SciTech Connect

    1998-12-31

    In previous projects, Praxis investigated the utilization of as-generated slags for a wide variety of applications in road construction, cement and concrete production, agricultural applications, and as a landfill material. From these studies, the authors found that it would be extremely difficult for as-generated slag to find large-scale acceptance in the marketplace even at no cost because the materials it could replace were abundantly available at very low cost. It became apparent that a more promising approach would be to develop a variety of value-added products from slag that meet specific industry requirements. This approach was made feasible by the discovery that slag undergoes expansion and forms a lightweight material when subjected to controlled heating in a kiln at temperatures between 1,400 and 1,700 F. These results confirmed the potential for using expanded slag as a substitute for conventional lightweight aggregates (LWA). The technology to produce lightweight and ultra-lightweight aggregates (ULWA) from slag was subsequently developed by Praxis. The major objectives of the subject project are to demonstrate the technical and economic viability of commercial production of LWA and ULWA from slag and to test the suitability of these aggregates for various applications. The project goals are to be accomplished in two phases: Phase 1, comprising the production of LWA and ULWA from slag at the large pilot scale, and Phase 2, which involves commercial evaluation of these aggregates in a number of applications. This document summarizes the Phase 2 accomplishments to date along with the major accomplishments from Phase 1.

  14. Automation in a material processing/storage facility

    SciTech Connect

    Peterson, K.; Gordon, J.

    1997-05-01

    The Savannah River Site (SRS) is currently developing a new facility, the Actinide Packaging and Storage Facility (APSF), to process and store legacy materials from the United States nuclear stockpile. A variety of materials, with a variety of properties, packaging and handling/storage requirements, will be processed and stored at the facility. Since these materials are hazardous and radioactive, automation will be used to minimize worker exposure. Other benefits derived from automation of the facility include increased throughput capacity and enhanced security. The diversity of materials and packaging geometries to be handled poses challenges to the automation of facility processes. In addition, the nature of the materials to be processed underscores the need for safety, reliability and serviceability. The application of automation in this facility must, therefore, be accomplished in a rational and disciplined manner to satisfy the strict operational requirements of the facility. Among the functions to be automated are the transport of containers between process and storage areas via an Automatic Guided Vehicle (AGV), and various processes in the Shipping Package Unpackaging (SPU) area, the Accountability Measurements (AM) area, the Special Isotope Storage (SIS) vault and the Special Nuclear Materials (SNM) vault. Other areas of the facility are also being automated, but are outside the scope of this paper.

  15. Negative tone imaging process and materials for EUV lighography

    NASA Astrophysics Data System (ADS)

    Tarutani, Shinji; Nihashi, Wataru; Hirano, Shuuji; Yokokawa, Natsumi; Takizawa, Hiroo

    2013-03-01

    The advantages of NTI process in EUV is demonstrated by optical simulation method for 0.25NA and 0.33NA illumination system with view point of optical aerial image quality and photon density. The extendability of NTI for higher NA system is considered for further tight pitch and small size contact hole imaging capability. Process and material design strategy to NTI were discussed with consideration on comparison to ArF NTI process and materials, and challenges in EUV materials dedicated to NTI process were discussed as well. A new polymer was well designed for EUV-NTD process, and the resists formulated with the new polymer demonstrated good advantage of resolution and sensitivity in isolated trench imaging, and 24 nm half pitch resolution at dense C/H, with 0.3NA MET tool.

  16. Benefit evaluation of space processing of biological materials

    NASA Technical Reports Server (NTRS)

    1977-01-01

    A rational analytical basis for the evaluation of potential benefits of space processing of biological materials is described. A preliminary evaluation of three candidate space processed biological materials was accomplished. Materials investigated were human lymphocytes, urokinase, and Beta cells. Separation of lymphocyte groups was considered in order to improve the matching of donors and recipients for kidney transplantation, while urokinase was examined in regard to treatment of thromboembolic diseases. Separation of Beta cells was studied since it could provide a highly effective means for the treatment of juvenile-onset diabetes.

  17. Oil shale, tar sand, coal research, advanced exploratory process technology jointly sponsored research. Quarterly technical progress report, April--June 1992

    SciTech Connect

    Not Available

    1992-12-01

    Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesa Verde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced recovery techniques; and menu driven access to the WDEQ Hydrologic Data Management Systems.

  18. Materials Science and Technology, Volume 16, Processing of Semiconductors

    NASA Astrophysics Data System (ADS)

    Jackson, Kenneth A.

    1996-09-01

    This self-contained handbook deals with the enabling materials technology for the electronics industry. World renowned authors have contributed to this unique treatment of the processing of semiconductors and related technologies. Contents: Wilkes: Silicon Processing. Mullin: Compound Semiconductor Processing, Kuech/BleLagally/Tischler: Epitaxial Growth. Leuschner/Pawlowski: Photolithography. Griffin: Doping. Turner/Donohoe: Etching Processes in Semiconductor Manufacturing. Chang/Sze: Silicon Device Structures. Lam/Stanchina: Compound Semiconductor Device Structures. Kwong: Silicon Device Processing. Parsey, Jr: Compound Semiconductor Device Processing. Amey: Chip Carriers. Knausenberger/Turlik: Interconnection Systems.

  19. Teratologic studies of solvent-refined-coal-process materials

    SciTech Connect

    Hackett, P.L.; Sikov, M.R.; Springer, D.L.; Mahlum, D.D.; Kelman, B.J.

    1983-09-01

    The most striking effects observed following intragastric or inhalation exposure of pregnant rats to SRC materials were related to the fetal lungs: a dose-dependent decrease in weight and an increased incidence of small lungs. Whether the SRC materials was heavy distillate or a process development unit material (HPS) did not appear to influence fetal effects, but higher-boiling-range materials induced fetal responses at lower doses. The most sensitive period for production of small lungs and cleft palate was from 12 through 14 days gestation.

  20. Processing and Properties of HfB2 Based Materials

    NASA Technical Reports Server (NTRS)

    Johnson, Sylvia M.; Beckman, Sarah; Irby, Edward; Ellerby, Don; Gasch, Matthew; Gusman, Michael

    2003-01-01

    Contents include the following: Modified hot pressing schedule has significantly improved UHTC billet processing: density and microstructure uniformity have improved. 2 in. dia. x 2 in. tall UHTC billets have been successfully hot pressed: scaled up billets have slightly higher density gradients axially than 1 in. billets. Hot press schedule has not been optimized for scaled up billets. Strengths and strength distributions are improving with experience: need to evaluate strength uniformity in the center of the billets. CTE or ARC materials compares favorably with heritage materials. Thermal conductivity of ARC materials considerably different than that of heritage materials.

  1. Friction stir welding tool and process for welding dissimilar materials

    DOEpatents

    Hovanski, Yuri; Grant, Glenn J; Jana, Saumyadeep; Mattlin, Karl F

    2013-05-07

    A friction stir welding tool and process for lap welding dissimilar materials are detailed. The invention includes a cutter scribe that penetrates and extrudes a first material of a lap weld stack to a preselected depth and further cuts a second material to provide a beneficial geometry defined by a plurality of mechanically interlocking features. The tool backfills the interlocking features generating a lap weld across the length of the interface between the dissimilar materials that enhances the shear strength of the lap weld.

  2. Container assessment: corrosion study of HLW container materials. Quarterly progress report, July-September 1981. Volume 1, No. 3

    SciTech Connect

    Ahn, T M; Soo, P

    1982-01-01

    Work has been started on the corrosion and hydrogen embrittlement behavior of commercially pure titanium (ASTM Grade 2), TiCode-12 (ASTM Grade 12), and OFHC copper, which are primary candidate materials for high level waste containers. The test environment used is a simulated brine solution typical of bedded salt at 150 C or room temperature. The immersion test results for these materials are in reasonable agreement with previous screening test results of Sandia National Laboratory; electron beam welded titanium and TiCode-12 samples show higher corrosion rates than the non-welded samples. To understand the difference between titanium and TiCode-12 in uniform and crevice corrosion, electrochemical tests were performed. While the initial repassivation behavior is similar in terms of charge density transfer after scratching tests in 1 M HCl solution at 80 C, titanium shows an active peak in polarization curves in brine at room temperature while TiCode-12 does not. Also, the open circuit corrosion potential of TiCode-12 is about 300 mV more anodic than that of titanium in 0.1 M HCl plus 0.9 M KCl solution at 85 C. Slow strain rate embrittlement and impact embrittlement have been observed in cathodically hydrogen charged commercially pure titanium and TiCode-12 in tension and buckling tests. C-ring and U-bend specimens of titanium and TiCode-12 have been designed and a slow strain rate test machine is being built to study stress corrosion cracking. Alternating Current Impedance and Scanning Reference Electrode Techniques are ready for pitting studies. For the study of radiation-induced corrosion, an irradiation cell was set up in the gamma pool to estimate quantitatively the oxidants as well as hydrogen produced by the gamma radiation in the brine solutions. 35 refs., 18 figs., 5 tabs.

  3. Materials processing with a high power diode laser

    SciTech Connect

    Li, L.; Lawrence, J.; Spencer, J.T.

    1996-12-31

    This paper reports on work exploring the feasibility of a range of materials processing applications using a Diomed 60W diode laser delivered through a 600{mu}m diameter optical fibre to a 3 axis CNC workstation. The applications studied include: marking/engraving natural stones (marble and granite), marking ceramic tiles, sealing tile grouts, cutting and marking glass, marking/engraving wood, stripping paint and lacquer, and welding metallic wires. The study shows that even at the present limited power level of diode lasers, many materials processing applications can be accomplished with satisfactory results. Through the study an initial understanding of interaction of high power diode laser (HPDL) beam with various materials has been gained. Also, within the paper basic beam characteristics, and current R&D activities in HPDL technology and materials processing applications are reviewed.

  4. Deployable Crew Quarters

    NASA Technical Reports Server (NTRS)

    Izenson, Michael G.; Chen, Weibo

    2008-01-01

    The deployable crew quarters (DCQ) have been designed for the International Space Station (ISS). Each DCQ would be a relatively inexpensive, deployable boxlike structure that is designed to fit in a rack bay. It is to be occupied by one crewmember to provide privacy and sleeping functions for the crew. A DCQ comprises mostly hard panels, made of a lightweight honeycomb or matrix/fiber material, attached to each other by cloth hinges. Both faces of each panel are covered with a layer of Nomex cloth and noise-suppression material to provide noise isolation from ISS. On Earth, the unit is folded flat and attached to a rigid pallet for transport to the ISS. On the ISS, crewmembers unfold the unit and install it in place, attaching it to ISS structural members by use of soft cords (which also help to isolate noise and vibration). A few hard pieces of equipment (principally, a ventilator and a smoke detector) are shipped separately and installed in the DCQ unit by use of a system of holes, slots, and quarter-turn fasteners. Full-scale tests showed that the time required to install a DCQ unit amounts to tens of minutes. The basic DCQ design could be adapted to terrestrial applications to satisfy requirements for rapid deployable emergency shelters that would be lightweight, portable, and quickly erected. The Temporary Early Sleep Station (TeSS) currently on-orbit is a spin-off of the DCQ.

  5. Corrosion-Resistant Container for Molten-Material Processing

    NASA Technical Reports Server (NTRS)

    Stern, Theodore G.; McNaul, Eric

    2010-01-01

    In a carbothermal process, gaseous methane is passed over molten regolith, which is heated past its melting point to a temperature in excess of 1,625 C. At this temperature, materials in contact with the molten regolith (or regolith simulant) corrode and lose their structural properties. As a result, fabricating a crucible to hold the molten material and providing a method of contact heating have been problematic. Alternative containment approaches use a large crucible and limit the heat zone of the material being processed, which is inefficient because of volume and mass constraints. Alternative heating approaches use non-contact heating, such as by laser or concentrated solar energy, which can be inefficient in transferring heat and thus require higher power heat sources to accomplish processing. The innovation is a combination of materials, with a substrate material having high structural strength and stiffness and high-temperature capability, and a coating material with a high corrosion resistance and high-temperature capability. The material developed is a molybdenum substrate with an iridium coating. Creating the containment crucible or heater jacket using this material combination requires only that the molybdenum, which is easily processed by conventional methods such as milling, electric discharge machining, or forming and brazing, be fabricated into an appropriate shape, and that the iridium coating be applied to any surfaces that may come in contact with the corrosive molten material. In one engineering application, the molybdenum was fashioned into a container for a heat pipe. Since only the end of the heat pipe is used to heat the regolith, the container has a narrowing end with a nipple in which the heat pipe is snugly fit, and the external area of this nipple, which contacts the regolith to transfer heat into it, is coated with iridium. At the time of this reporting, no single material has been found that can perform the functions of this combination

  6. Processing and characterization of novel biobased and biodegradable materials

    NASA Astrophysics Data System (ADS)

    Pilla, Srikanth

    Human society has benefited tremendously from the use of petroleum-based plastics. However, there are growing concerns with their adverse environmental impacts and volatile costs attributed to the skyrocketing oil prices. Additionally most of the petroleum-based polymers are non-biodegradable causing problems about their disposal. Thus, during the last couple of decades, scientists ail over the world have been focusing on developing new polymeric materials that are biobased and biodegradable, also termed as green plastics . This study aims to develop green materials based on polylactide (PLA) biopolymer that can be made from plants. Although PLA can provide important advantages in terms of sustainability and biodegradability, it has its own challenges such as high cost, brittleness, and narrow processing window. These challenges are addressed in this study by investigating both new material formulations and processes. To improve the material properties and control the material costs, PLA was blended with various fillers and modifiers. The types of fillers investigated include carbon nanotube (CNT) nanoparticles and various natural fibers such as pine-wood four, recycled-wood fibers and flax fiber. Using natural fibers as fillers for PLA can result in fully biodegradable and eco-friendly biocomposites. Also due to PLA's sensitivity to moisture and temperature, molecular degradation can occur during processing leading to inferior material properties. To address this issue, one of the approaches adopted by this study was to incorporate a multifunctional chain-extender into PLA, which increased the molecular weight of PLA thereby improving the material properties. To improve the processability and reduce the material cost, both microcellular injection molding and extrusion processes have been studied. The microcellular technology allows the materials to be processed at a lower temperature, which is attractive for thermo- and moisture-sensitive materials like PLA. They

  7. Materials And Processes Technical Information System (MAPTIS) LDEF materials data base

    NASA Technical Reports Server (NTRS)

    Funk, Joan G.; Strickland, John W.; Davis, John M.

    1993-01-01

    A preliminary Long Duration Exposure Facility (LDEF) Materials Data Base was developed by the LDEF Materials Special Investigation Group (MSIG). The LDEF Materials Data Base is envisioned to eventually contain the wide variety and vast quantity of materials data generated from LDEF. The data is searchable by optical, thermal, and mechanical properties, exposure parameters (such as atomic oxygen flux) and author(s) or principal investigator(s). Tne LDEF Materials Data Base was incorporated into the Materials and Processes Technical Information System (MAPTIS). MAPTIS is a collection of materials data which has been computerized and is available to engineers, designers, and researchers in the aerospace community involved in the design and development of spacecraft and related hardware. The LDEF Materials Data Base is described and step-by-step example searches using the data base are included. Information on how to become an authorized user of the system is included.

  8. Designing Educative Curriculum Materials: A Theoretically and Empirically Driven Process

    ERIC Educational Resources Information Center

    Davis, Elizabeth A.; Palincsar, Annemarie Sullivan; Arias, Anna Maria; Bismack, Amber Schultz; Marulis, Loren M.; Iwashyna, Stefanie K.

    2014-01-01

    In this article, the authors argue for a design process in the development of educative curriculum materials that is theoretically and empirically driven. Using a design-based research approach, they describe their design process for incorporating educative features intended to promote teacher learning into existing, high-quality curriculum…

  9. Process material management in the Space Station environment

    NASA Technical Reports Server (NTRS)

    Perry, J. L.; Humphries, W. R.

    1988-01-01

    The Space Station will provide a unique facility for conducting material-processing and life-science experiments under microgravity conditions. These conditions place special requirements on the U.S. Laboratory for storing and transporting chemicals and process fluids, reclaiming water from selected experiments, treating and storing experiment wastes, and providing vacuum utilities. To meet these needs and provide a safe laboratory environment, the Process Material Management System (PMMS) is being developed. Preliminary design requirements and concepts related to the PMMS are addressed, and the MSFC PMMS breadboard test facility and a preliminary plan for validating the overall system design are discussed.

  10. Concurrent materials and process selection in conceptual design

    SciTech Connect

    Kleban, Stephen D.; Knorovsky, Gerald A.

    2000-08-16

    A method for concurrent selection of materials and a joining process based on product requirements using a knowledge-based, constraint satisfaction approach facilitates the product design and manufacturing process. Using a Windows-based computer video display and a data base of materials and their properties, the designer can ascertain the preferred composition of two parts based on various operating/environmental constraints such as load, temperature, lifetime, etc. Optimum joinder of the two parts may simultaneously be determined using a joining process data base based upon the selected composition of the components as well as the operating/environmental constraints.

  11. THE USE OF POWER ULTRASOUND FOR MATERIAL PROCESSING

    SciTech Connect

    Han, Qingyou

    2007-01-01

    The U.S. Department of Energy and Oak Ridge National laboratory have been sponsoring a number of projects investigating the use of high intensity ultrasonic vibrations for material processing. High intensity ultrasonic vibrations have been tested for degassing of molten aluminum, grain refinement of alloys of industrial importance, and modification of welding structure. The project results have indicated that power ultrasound can be used for fast degassing of molten metal, for significant grain refinement of alloys during their solidification processes, and for improving the microstructure in the weldment of steels. This article describes the project results and outlines the limits of using ultrasonic vibrations for material processing.

  12. Long-Term Materials Test program. Quarterly report, January-March 1984. [Metal aluminide and MCrAlY coatings

    SciTech Connect

    Not Available

    1984-01-01

    Corrosion and erosion/corrosion testing of gas turbine vane and blade base alloys and a variety of protective coating systems under the Long-Term Materials Test program has surpassed 5574 hours. The Pressurized Fluidized Bed Combustion (PFBC) facility at Malta, New York continues to show an exceptionally high degree of reliability and consistency in performance. Operating conditions include a 1650/sup 0/F bed temperature at 10 atmospheres pressure utilizing Pittsburgh No. 8 coal and a low alkali dolomite sulfur sorbent. After 2687 hours, unprotected nickel and cobalt base vane and blade alloys generally experienced corrosion rates of 1 to 2 mils/1000 hours at metal temperatures of 1100/sup 0/, 1300/sup 0/ and 1500/sup 0/F. Precious metal aluminide and MCrAlY coatings continue to show excellent corrosion resistance (<0.5 mils/1000 hrs) at 1500/sup 0/F, but are susceptible to varying degrees of pitting attack at 1100/sup 0/ and 1300/sup 0/F. Erosion/corrosion degradation rates at 800 to 900 ft/s, 1350/sup 0/F and less than 100 ppM dust loading ranged from 1 to 4 mils/1000 h with corrosion predominately concentrated in areas of particle impaction indicating an erosion/corrosion synergism. 6 figures, 3 tables.

  13. Hazardous materials in aquatic environments of the Mississippi River Basin. Quarterly project status report, October 1, 1994--December 31, 1994

    SciTech Connect

    Not Available

    1995-02-01

    This report briefly summerizes the following projects on hazardous materials in the aquatic environments of the Mississippi River Basin: Biotic and abiotic studies on the biological fate, transport and ecotoxicity of toxic and Hazardous waste in the Mississippi River Basin; The effect of depositional environment on the fate and transport of contaminants in aquatic environments;Assessment of mechanisms of metal-induced reproductive toxicity in aquatic species as biomarkers of exposure; Hazardous wastes in aquantic environments: biological uptake and metabolism studies; bioremediation of selected contaminants in aquatic environments of the Mississippi River Basin; Development of Novel dechlorination catalysts; pore-level flow, transport, agglomeration and reaction kinetics of microorganisms; novel polymer-semiconductor composits for photocatalytic destruction of organic contaminants in aqueous environments; biomarkers of exposure and ecotoxicity in the Mississippi River Basin; Natural and Active Chemical remediation cluster; collaborative research with the Institute of Radiological Problems (IREP) - fate and transport of radionuclides following the Chernobyl Accident; Exper geographical information systems for assessing hazardous wastes in aquatic environments; computation of Taylor Dispersion coefficient.

  14. Advanced Process Technology: Combi Materials Science and Atmospheric Processing (Fact Sheet)

    SciTech Connect

    Not Available

    2011-06-01

    Capabilities fact sheet for the National Center for Photovoltaics: Process Technology and Advanced Concepts -- High-Throughput Combi Material Science and Atmospheric Processing that includes scope, core competencies and capabilities, and contact/web information.

  15. Picosecond and femtosecond lasers for industrial material processing

    NASA Astrophysics Data System (ADS)

    Mayerhofer, R.; Serbin, J.; Deeg, F. W.

    2016-03-01

    Cold laser materials processing using ultra short pulsed lasers has become one of the most promising new technologies for high-precision cutting, ablation, drilling and marking of almost all types of material, without causing unwanted thermal damage to the part. These characteristics have opened up new application areas and materials for laser processing, allowing previously impossible features to be created and also reducing the amount of post-processing required to an absolute minimum, saving time and cost. However, short pulse widths are only one part of thee story for industrial manufacturing processes which focus on total costs and maximum productivity and production yield. Like every other production tool, ultra-short pulse lasers have too provide high quality results with maximum reliability. Robustness and global on-site support are vital factors, as well ass easy system integration.

  16. Process feasibility study in support of silicon material task 1

    NASA Technical Reports Server (NTRS)

    Fang, C. S.; Hansen, K. C.; Miller, J. W., Jr.; Yaws, C. L.

    1978-01-01

    Initial results for gas thermal conductivity of silicon tetrafluoride and trichlorosilane are reported in respective temperature ranges of 25 to 400 C and 50 to 400 C. For chemical engineering analyses, the preliminary process design for the original silane process of Union Carbide was completed for Cases A and B, Regular and Minimum Process Storage. Included are raw material usage, utility requirements, major process equipment lists, and production labor requirements. Because of the large differences in surge tankage between major unit operations the fixed capital investment varied from $19,094,000 to $11,138,000 for Cases A and B, respectively. For the silane process the original flowsheet was revised for a more optimum arrangement of major equipment, raw materials and operating conditions. The initial issue of the revised flowsheet (Case C) for the silane process indicated favorable cost benefits over the original scheme.

  17. Catalyst and process development for synthesis gas conversion to isobutylene. Quarterly report, January 1, 1993--March 31, 1993

    SciTech Connect

    Anthony, R.G.; Akgerman, A.

    1993-04-17

    The objectives of this project are to develop a new catalyst, the kinetics for this catalyst, reactor models for trickle bed, slurry and fixed bed reactors, and simulate the performance of fixed bed trickle flow reactors, slurry flow reactors, and fixed bed gas phase reactors for conversion of a hydrogen lean synthesis gas to isobutylene. The six main accomplishments for the quarter are the following: (1) activity testing with the 7% (wt) Ce-ZrO{sub 2}, (2) activity testing the same catalyst with CO from an aluminum cylinder, (3) preparation of ZrO{sub 2} by heating zirconyl nitrate, (4) preparation of an active zirconia prepared by a modified sol gel procedure and evaluation of the catalytic activity of a commercial zirconia and the catalysts prepared by the sol gel procedure, (5) determining the effect of separator temperatures and oil flow rate on the performance of a trickle bed reactor, and (6) calculation of the equilibrium composition of the C{sub 2} to C{sub 5} olefins, and initiation of the development of a macrokinetic model. The details of each of these accomplishments are discussed.

  18. Bench-scale testing of the micronized magnetite process. Fourth quarterly technical progress report, April--June 1995

    SciTech Connect

    1995-08-10

    The main accomplishments of Custom Coals and the project subcontractors, during this period, included: continued purchase of small equipment and supplies for the circuit; completed the circuit commissioning task; procured one lot of PennMag Grade-K and one lot Grade-L magnetite; completed work on analytical investigations; completed Classifying Circuit Component Testing on Pittsburgh No. 8 coal; completed the final Heavy-Media cyclone component testing on the Pittsburgh No. 8 seam using Grade-K and Grade-L magnetites; continued QA/QC tests on wet screening, wet splitting, Marcy Balance, and reproducibility checks on component tests and component test samples; and completed the magnetite recovery circuit component testing with and without screens using the Grade-K magnetite and the Pittsburgh No. 8 coal seam. This report contains a short discussion of the project description, objectives, budget, schedule, and teaming arrangement. It also includes a detailed discussion of the above mentioned project accomplishments and plans, organized by the various task series within the project work plan. The final section contains an outline of the specific project goals for the next quarterly reporting period.

  19. Marshall Space Flight Center Materials and Processes Laboratory

    NASA Technical Reports Server (NTRS)

    Tramel, Terri L.

    2012-01-01

    Marshall?s Materials and Processes Laboratory has been a core capability for NASA for over fifty years. MSFC has a proven heritage and recognized expertise in materials and manufacturing that are essential to enable and sustain space exploration. Marshall provides a "systems-wise" capability for applied research, flight hardware development, and sustaining engineering. Our history of leadership and achievements in materials, manufacturing, and flight experiments includes Apollo, Skylab, Mir, Spacelab, Shuttle (Space Shuttle Main Engine, External Tank, Reusable Solid Rocket Motor, and Solid Rocket Booster), Hubble, Chandra, and the International Space Station. MSFC?s National Center for Advanced Manufacturing, NCAM, facilitates major M&P advanced manufacturing partnership activities with academia, industry and other local, state and federal government agencies. The Materials and Processes Laborato ry has principal competencies in metals, composites, ceramics, additive manufacturing, materials and process modeling and simulation, space environmental effects, non-destructive evaluation, and fracture and failure analysis provide products ranging from materials research in space to fully integrated solutions for large complex systems challenges. Marshall?s materials research, development and manufacturing capabilities assure that NASA and National missions have access to cutting-edge, cost-effective engineering design and production options that are frugal in using design margins and are verified as safe and reliable. These are all critical factors in both future mission success and affordability.

  20. Idaho National Laboratory Quarterly Occurrence Analysis

    SciTech Connect

    Mitchell, Lisbeth Ann

    2015-11-01

    This report is published quarterly by the Idaho National Laboratory (INL) Quality and Performance Management Organization. The Department of Energy (DOE) Occurrence Reporting and Processing System (ORPS), as prescribed in DOE Order 232.2, “Occurrence Reporting and Processing of Operations Information,” requires a quarterly analysis of events, both reportable and not reportable, for the previous 12 months. This report is the analysis of 85 reportable events (18 from the 4th Qtr FY-15 and 67 from the prior three reporting quarters), as well as 25 other issue reports (including events found to be not reportable and Significant Category A and B conditions) identified at INL during the past 12 months (8 from this quarter and 17 from the prior three quarters).

  1. Process Materialization Using Templates and Rules to Design Flexible Process Models

    NASA Astrophysics Data System (ADS)

    Kumar, Akhil; Yao, Wen

    The main idea in this paper is to show how flexible processes can be designed by combining generic process templates and business rules. We instantiate a process by applying rules to specific case data, and running a materialization algorithm. The customized process instance is then executed in an existing workflow engine. We present an architecture and also give an algorithm for process materialization. The rules are written in a logic-based language like Prolog. Our focus is on capturing deeper process knowledge and achieving a holistic approach to robust process design that encompasses control flow, resources and data, as well as makes it easier to accommodate changes to business policy.

  2. Anion-exchange resin-based desulfurization process. Quarterly technical progress report, April 1, 1993--June 30, 1993

    SciTech Connect

    Sheth, A.C.; Dharmapurikar, R.

    1993-09-01

    Under the current grant (No. DE-FG22-90PC90309), the University of Tennessee Space Institute (UTSI) will perform the bench scale evaluation and further development of the anion-exchange resin-based desulfurization concept to desulfurize alkali metal sulfates. The developmental program proposed under this DOE grant includes screening of commercially available resins to select three candidate resins for further study. These three resins will undergo a series of experiments designed to test the resins` performance under different process conditions (including the use of spent MHD seed material). The best of these resins will be used in optimizing the regeneration step and in testing the effects of performance enhancers. During this reporting period, April 1, 1993 to June 30, 1993, the procedure to evaluate the cycle efficiency of candidate resins in the fixed-bed mode was slightly modified to ensure complete regeneration of the exhausted resin. Using this revised procedure, ten consecutive cycles for all the three resins have been completed and the results are being analyzed.

  3. Method for materials deposition by ablation transfer processing

    DOEpatents

    Weiner, Kurt H.

    1996-01-01

    A method in which a thin layer of semiconducting, insulating, or metallic material is transferred by ablation from a source substrate, coated uniformly with a thin layer of said material, to a target substrate, where said material is desired, with a pulsed, high intensity, patternable beam of energy. The use of a patternable beam allows area-selective ablation from the source substrate resulting in additive deposition of the material onto the target substrate which may require a very low percentage of the area to be covered. Since material is placed only where it is required, material waste can be minimized by reusing the source substrate for depositions on multiple target substrates. Due to the use of a pulsed, high intensity energy source the target substrate remains at low temperature during the process, and thus low-temperature, low cost transparent glass or plastic can be used as the target substrate. The method can be carried out atmospheric pressures and at room temperatures, thus eliminating vacuum systems normally required in materials deposition processes. This invention has particular application in the flat panel display industry, as well as minimizing materials waste and associated costs.

  4. Method for materials deposition by ablation transfer processing

    DOEpatents

    Weiner, K.H.

    1996-04-16

    A method in which a thin layer of semiconducting, insulating, or metallic material is transferred by ablation from a source substrate, coated uniformly with a thin layer of said material, to a target substrate, where said material is desired, with a pulsed, high intensity, patternable beam of energy. The use of a patternable beam allows area-selective ablation from the source substrate resulting in additive deposition of the material onto the target substrate which may require a very low percentage of the area to be covered. Since material is placed only where it is required, material waste can be minimized by reusing the source substrate for depositions on multiple target substrates. Due to the use of a pulsed, high intensity energy source the target substrate remains at low temperature during the process, and thus low-temperature, low cost transparent glass or plastic can be used as the target substrate. The method can be carried out atmospheric pressures and at room temperatures, thus eliminating vacuum systems normally required in materials deposition processes. This invention has particular application in the flat panel display industry, as well as minimizing materials waste and associated costs. 1 fig.

  5. Spacecraft materials guide. [including: encapsulants and conformal coatings; optical materials; lubrication; and, bonding and joining processes

    NASA Technical Reports Server (NTRS)

    Staugaitis, C. L. (Editor)

    1975-01-01

    Materials which have demonstrated their suitability for space application are summarized. Common, recurring problems in encapsulants and conformal coatings, optical materials, lubrication, and bonding and joining are noted. The subjects discussed include: low density and syntactic foams, electrical encapsulants; optical glasses, interference filter, mirrors; oils, greases, lamillar lubricants; and, soldering and brazing processes.

  6. Hydraulically-assisted compression molding material and process development

    SciTech Connect

    Collister, J.E.; Butler, K.I.; Rinz, J.E.

    1996-11-01

    The Sheet Molding Compound (SMC) industry has recently seen an introduction of novel materials which are claimed to allow molders of SMC parts to alter their process to mold at substantially lower molding pressures. Although this is viewed as a major advantage for SMC molders, little description of molding processes has been given which take full advantage of these novel materials. The work reported in this paper describes one possible alternative process which will enable molders to capture the low-cost potential of reducing the required molding pressures. This process involves the use of low-cost mold construction, and the use of a novel method of applying molding pressure that obviates the need for a high-cost compression press, which causes the authors to apply a new name to this process; Hydraulic-Assisted Compression Molding. Molding results are presented for SMC which was designed to be molded at reduced pressures and temperatures (6.9 bar and 100 C).

  7. Process feasibility study in support of silicon material task 1

    NASA Technical Reports Server (NTRS)

    Li, K. Y.; Hansen, K. C.; Yaws, C. L.

    1978-01-01

    Process system properties are analyzed for materials involved in the alternate processes under consideration for solar cell grade silicon. The following property data are reported for trichlorosilane: critical constants, vapor pressure, heat of vaporization, gas heat capacity, liquid heat capacity, density, surface tension, viscosity, thermal conductivity, heat of formation, and Gibb's free energy of formation. Work continued on the measurement of gas viscosity values of silicon source materials. Gas phase viscosity values for silicon tetrafluoride between 40 C and 200 C were experimentally determined. Major efforts were expended on completion of the preliminary economic analysis of the silane process. Cost, sensitivity and profitability analysis results are presented based on a preliminary process design of a plant to produce 1,000 metric tons/year of silicon by the revised process.

  8. Material quality development during the automated tow placement process

    NASA Astrophysics Data System (ADS)

    Tierney, John Joseph

    Automated tow placement (ATP) of thermoplastic composites builds on the existing industrial base for equipment, robotics and kinematic placement of material with the aim of further cost reduction by eliminating the autoclave entirely. During ATP processing, thermoplastic composite tows are deposited on a preconsolidated substrate at rates ranging from 10--100mm/s and consolidated using the localized application of heat and pressure by a tow placement head mounted on a robot. The process is highly non-isothermal subjecting the material to multiple heating and cooling rates approaching 1000°C/sec. The requirement for the ATP process is to achieve the same quality in seconds (low void content, full translation of mechanical properties and degree of bonding and minimal warpage) as the autoclave process achieves in hours. The scientific challenge was to first understand and then model the relationships between processing, material response, microstructure and quality. The important phenomena affecting quality investigated in this study include a steady state heat transfer simulation, consolidation and deconsolidation (void dynamics), intimate contact and polymer interdiffusion (degree of bonding/mechanical properties) and residual stress and warpage (crystallization and viscoelastic response). A fundamental understanding of the role of materials related to these mechanisms and their relationship to final quality is developed and applied towards a method of process control and optimization.

  9. Technology Assessment of Laser-Assisted Materials Processing in Space

    NASA Technical Reports Server (NTRS)

    Nagarathnam, Karthik; Taminger, Karen M. B.

    2001-01-01

    Lasers are useful for performing operations such as joining, machining, built-up freeform fabrication, shock processing, and surface treatments. These attributes are attractive for the supportability of longer-term missions in space due to the multi-functionality of a single tool and the variety of materials that can be processed. However, current laser technology also has drawbacks for space-based applications, specifically size, power efficiency, lack of robustness, and problems processing highly reflective materials. A review of recent laser developments will be used to show how these issues may be reduced and indicate where further improvement is necessary to realize a laser-based materials processing capability in space. The broad utility of laser beams in synthesizing various classes of engineering materials will be illustrated using state-of-the art processing maps for select lightweight alloys typically found on spacecraft. With the advent of recent breakthroughs in diode-pumped solid-state lasers and fiber optic technologies, the potential to perform multiple processing techniques is increasing significantly. Lasers with suitable wavelengths and beam properties have tremendous potential for supporting future space missions to the moon, Mars and beyond.

  10. Support Assembly for Composite Laminate Materials During Roll Press Processing

    NASA Technical Reports Server (NTRS)

    Catella, Luke A.

    2011-01-01

    A composite laminate material is supported during the roll press processing thereof by an assembly having: first and second perforated films disposed adjacent to first and second opposing surfaces of a mixture of uncured resin and fibers defining the composite laminate material, a gas permeable encasement surrounding the mixture and the first and second films, a gas impervious envelope sealed about the gas permeable encasement, and first and second rigid plates clamped about the gas impervious envelope.

  11. NBS (National Bureau of Standards): Materials measurements. [space processing experiments

    NASA Technical Reports Server (NTRS)

    Manning, J. R.

    1983-01-01

    Work directed toward the measurement of materials properties important to the design and interpretation of space processing experiments and determinations of how the space environment may offer a unique opportunity for performing improved measurements and producing materials with improved properties is reported. Surface tensions and their variations with temperature and impurities; convection during undirectional solidification; and measurement of the high temperature thermophysical properties of tungsten group liquids and solids are discussed and results are summarized.

  12. Containerless Liquid-Phase Processing of Ceramic Materials

    NASA Technical Reports Server (NTRS)

    Weber, J. K. Richard (Principal Investigator); Nordine, Paul C.

    1996-01-01

    The present project builds on the results of research supported under a previous NASA grant to investigate containerless liquid-phase processing of molten ceramic materials. The research used an aero-acoustic levitator in combination with cw CO2 laser beam heating to achieve containerless melting, superheating, undercooling, and solidification of poorly-conducting solids and liquids. Experiments were performed on aluminum oxide, binary aluminum oxide-silicon dioxide materials, and oxide superconductors.

  13. Method for co-processing waste rubber and carbonaceous material

    DOEpatents

    Farcasiu, Malvina; Smith, Charlene M.

    1991-01-01

    In a process for the co-processing of waste rubber and carbonaceous material to form a useful liquid product, the rubber and the carbonaceous material are combined and heated to the depolymerization temperature of the rubber in the presence of a source of hydrogen. The depolymerized rubber acts as a liquefying solvent for the carbonaceous material while a beneficial catalytic effect is obtained from the carbon black released on depolymerization the reinforced rubber. The reaction is carried out at liquefaction conditions of 380.degree.-600.degree. C. and 70-280 atmospheres hydrogen pressure. The resulting liquid is separated from residual solids and further processed such as by distillation or solvent extraction to provide a carbonaceous liquid useful for fuels and other purposes.

  14. Oil shale programs. Sixteenth quarterly report, October-December 1979

    SciTech Connect

    Stevens, A. L.

    1980-06-01

    This document is the sixteenth in a continuing series of quarterly reports, and describes the Sandia National Laboratories oil shale activities during the period between October 1, 1979 and December 31, 1979. Sandia's major responsibility to the DOE in situ oil shale program is to provide a quantitative evaluation to DOE of the various field projects being supported by DOE in the development of commercial in situ oil shale processes. This requires the deployment of instrumentation systems and analysis techniques to evaluate key procedures and operations. In order to fulfill this responsibility, it is necessary to develop new and advanced instrumentation systems and associated deployment, recording and analysis techniques that are unique to the field projects. In addition, a rock mechanics program provides material properties, material response models, and computational methods to support the design and evaluation functions. This report describes detailed activities in these project areas over the last quarter.

  15. Neural network modeling of the laser material-removal process

    NASA Astrophysics Data System (ADS)

    Yousef, Basem F.; Knopf, George K.; Bordatchev, Evgueni V.; Nikumb, Suwas K.

    2001-12-01

    Industrial lasers are used extensively in modern manufacturing for a variety of applications because these tools provide a highly focused energy source that can be easily transmitted and manipulated for micro-machining. The quantity of material removed and the roughness of the finished surface are a function of the crater geometry formed by a laser pulse with specific energy (power). Laser micro-machining is, however, a complex nonlinear process with numerous stochastic parameters related to the laser apparatus and the material specimen. Consequently, the operator must manually set the process control parameters by trial and error. This paper describes how an artificial neural network can be used to create a nonlinear model of the laser material-removal process in order to automate micro-machining tasks. The multi-layered neural network predicts the pulse energy needed to create a crater of specific depth and average diameter. Laser pulses of different energy levels are impinged on the surface of the test material in order to investigate the effect of pulse energy on the resulting crater geometry and volume of material removed. Experimentally acquired data from several sample materials are used to train and test the network's performance. The key system inputs for the modeler are mean depth of crater and mean diameter of crater, and the system outputs are pulse energy, variance of depth and variance of diameter. The preliminary study using the experimentally acquired data demonstrates that the proposed network can simulate the behavior of the physical process to a high degree of accuracy. Future work involves investigating the effect of different input parameters on the output behavior of the process in hopes that the process performance, and the final product quality, can be improved.

  16. Development of the selective hydrophobic coagulation process. Technical progess report for the eighth quarter, 1 July 1993--30 September 1993

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.

    1993-12-31

    A novel technique for selectively coagulating and separating coal from dispersed mineral matter has been developed at Virginia Tech. The process, known as Selective Hydrophobic Coagulation (SHC), has been studied under the sponsorship of the U.S. Department of Energy since 1986. The SHC process differs from oil agglomeration, shear flocculation, polymer flocculation, and electrolytic coagulation processes in that it does not require reagents or additives to induce the formation of coagula. Often, simple pH control is all that is required to (i) induce the coagulation of coal particles, and (ii) effectively disperse particles of mineral matter. When the coal is superficially oxidized, a small dosage of reagents may be used to promote coagulation. During the past quarter, work was completed on the prediction of optimum conditions for the SHC process using the extended DLVO equation (Subtask 2.3). In addition, the evaluation of the lamella thickener for separating hydrophobic coagula from dispersed mineral matter was completed. Work is now underway to complete the evaluation of other separation devices including a vacuum filter, flotation column and centrifuge (Subtask 3.3).

  17. Understanding Thermal Behavior in Lens Processing of Structural Materials

    SciTech Connect

    Ensz, M.T.; Greene, D.L.; Griffith, M.L.; Harwell, L.D.; Hofmeister, W.H.; Nelson, D.V.; Robino, C.V.; Schlienger, M.E.; Smugeresky, J.E.; Wert, M.J.

    1998-11-05

    In direct laser metal deposition technologies, such as the Laser (LENS) process, it is important to understand and control the Engineered Net Shaping thermal behavior during fabrication. With this control, components can be reliably fabricated with desired structural material properties. This talk will describe the use of contact and imaging techniques to monitor the thermal signature during LENS processing. Recent results show a direct correlation between thermal history and material properties, where the residual stress magnitude decreases as the laser power, and therefore thermal signature, increases. Development of an understanding of solidification behavior, residual stress, and microstructural evolution with respect to thermal behavior will be discussed.

  18. Method of processing materials using an inductively coupled plasma

    DOEpatents

    Hull, D.E.; Bieniewski, T.M.

    1987-04-13

    A method of processing materials. The invention enables ultrafine, ultrapure powders to be formed from solid ingots in a gas free environment. A plasma is formed directly from an ingot which insures purity. The vaporized material is expanded through a nozzle and the resultant powder settles on a cold surface. An inductively coupled plasma may also be used to process waste chemicals. Noxious chemicals are directed through a series of plasma tubes, breaking molecular bonds and resulting in relatively harmless atomic constituents. 3 figs.

  19. Composition and process for making an insulating refractory material

    SciTech Connect

    Pearson, Alan; Swansiger, Thomas G.

    1998-04-28

    A composition and process for making an insulating refractory material. The composition includes calcined alumina powder, flash activated alumina powder, an organic polymeric binder and a liquid vehicle which is preferably water. Starch or modified starch may also be added. A preferred insulating refractory material made with the composition has a density of about 2.4-2.6 g/cm.sup.3 with reduced thermal conductivity, compared with tabular alumina. Of importance, the formulation has good abrasion resistance and crush strength during intermediate processing (commercial sintering) to attain full strength and refractoriness, good abrasion resistance and crush strength.

  20. Composition and process for making an insulating refractory material

    SciTech Connect

    Pearson, A.; Swansiger, T.G.

    1998-04-28

    A composition and process are disclosed for making an insulating refractory material. The composition includes calcined alumina powder, flash activated alumina powder, an organic polymeric binder and a liquid vehicle which is preferably water. Starch or modified starch may also be added. A preferred insulating refractory material made with the composition has a density of about 2.4--2.6 g/cm{sup 3} with reduced thermal conductivity, compared with tabular alumina. Of importance, the formulation has good abrasion resistance and crush strength during intermediate processing (commercial sintering) to attain full strength and refractoriness.

  1. Large scale molecular dynamics modeling of materials fabrication processes

    SciTech Connect

    Belak, J.; Glosli, J.N.; Boercker, D.B.; Stowers, I.F.

    1994-02-01

    An atomistic molecular dynamics model of materials fabrication processes is presented. Several material removal processes are shown to be within the domain of this simulation method. Results are presented for orthogonal cutting of copper and silicon and for crack propagation in silica glass. Both copper and silicon show ductile behavior, but the atomistic mechanisms that allow this behavior are significantly different in the two cases. The copper chip remains crystalline while the silicon chip transforms into an amorphous state. The critical stress for crack propagation in silica glass was found to be in reasonable agreement with experiment and a novel stick-slip phenomenon was observed.

  2. A factory concept for processing and manufacturing with lunar material

    NASA Technical Reports Server (NTRS)

    Driggers, G. W.

    1977-01-01

    A conceptual design for an orbital factory sized to process 1.5 million metric tons per year of raw lunar fines into 0.3 million metric tons of manufacturing materials is presented. A conservative approach involving application of present earth-based technology leads to a design devoid of new inventions. Earth based counterparts to the factory machinery were used to generate subsystem masses and lumped parameters for volume and mass estimates. The results are considered to be conservative since technologies more advanced than those assumed are presently available in many areas. Some attributes of potential space processing technologies applied to material refinement and component manufacture are discussed.

  3. Recent results from material processing studies on new generation lasers

    SciTech Connect

    Kautz, D.D.; Dragon, E.P.; Werve, M.E.; Hargrove, R.S.

    1993-12-09

    High power and radiance dye lasers developed at Lawrence Livermore National Laboratory show promise for material processing tasks. Evaluation using welding heat flow models suggests significant increases in precision and speed are expected. We started processing studies to determine the viability of these lasers for cutting and drilling. Titanium and stainless steel alloys were chosen as materials for the preliminary studies. Results show that cuts and holes with extremely fine features can be made with dye and copper-vapor lasers. High radiance beams produce low distortion and small heat affected zones. We have accomplished very high aspect ratios and micron scale kerfs and holes in both stainless steel and titanium alloys.

  4. Pyrometric temperature control system for microwave processing of materials

    SciTech Connect

    Pert, E.; Calame, J.P.; Gershon, D.; Carmel, Y.; Calame, J.P.

    1998-12-31

    Accurate temperature measurements and uniform processing of a material with microwaves can be difficult with thermocouples that perturb the electromagnetic field. Arcing and field intensification is particularly a problem with low loss materials that do not couple well. Optical pyrometers offer a non-invasive alternative, but are generally restricted to surface temperature measurements and are usually non-linear over the temperature range of interest. Improved accuracy over the entire range of interest is possible with an integrated approach using a pc to calibrate the pyrometer against a thermocouple reference. A pyrometer-retrofitted microwave processing system that can measure and control from 40 C to 1,600 C is presented.

  5. Development of a material processing plant for lunar soil

    NASA Technical Reports Server (NTRS)

    Goettsch, Ulix; Ousterhout, Karl

    1992-01-01

    Currently there is considerable interest in developing in-situ materials processing plants for both the Moon and Mars. Two of the most important aspects of developing such a materials processing plant is the overall system design and the integration of the different technologies into a reliable, lightweight, and cost-effective unit. The concept of an autonomous materials processing plant that is capable of producing useful substances from lunar regolith was developed. In order for such a materials processing plant to be considered as a viable option, it must be totally self-contained, able to operate autonomously, cost effective, light weight, and fault tolerant. In order to assess the impact of different technologies on the overall systems design and integration, a one-half scale model was constructed that is capable of scooping up (or digging) lunar soil, transferring the soil to a solar furnace, heating the soil in the furnace to liberate the gasses, and transferring the spent soil to a 'tile' processing center. All aspects of the control system are handled by a 386 class PC via D/A, A/D, and DSP (Digital Signal Processor) control cards.

  6. Quantitative characterization of spatial distribution of particles in materials: Application to materials processing

    NASA Technical Reports Server (NTRS)

    Parse, J. B.; Wert, John A.

    1990-01-01

    Most engineering materials contain second phase particles or fibers which serve to reinforce the matrix phase. The effect of reinforcements on material properties is usually analyzed in terms of the average volume fraction and spacing of reinforcements, quantities which are global microstructural characteristics. However, material properties can also depend on local microstructural characteristics; for example, on how uniformly the reinforcing phase is distributed in the material. The analysis method will then be applied to a materials processing problem to discover how processing parameters can be selected to maximize redistribution of the reinforcing phase during processing. Several mathematical analysis methods could be adapted to the problem of characterizing the distribution of particles in materials. A tessellation-based method was selected. In the first phase of the investigation, a software package was written to automate the analysis. Typical results are shown. The analysis technique allows the degree to which particles are clustered together, the size and spacing of particle clusters, and the particle density in clusters to be found. The analysis methods were applied to computer-generated distributions and to a few real particle-containing materials. Methods for analyzing a nonuniform particle distribution in a material can be applied to two broad classes of materials science problems: understanding how the resulting particle distribution affects properties. The analysis method described is applied to a materials processing problem: how to select extrusion conditions to maximize the redistribution of reinforcing particles that are initially nonuniformly distributed. In addition, the tessellation-based method to analyze star distributions in spiral galaxies was adapted, illustrating the diverse types of problems to which the analysis method can be applied.

  7. Microassembly of Heterogeneous Materials using Transfer Printing and Thermal Processing.

    PubMed

    Keum, Hohyun; Yang, Zining; Han, Kewen; Handler, Drew E; Nguyen, Thong Nhu; Schutt-Aine, Jose; Bahl, Gaurav; Kim, Seok

    2016-01-01

    Enabling unique architectures and functionalities of microsystems for numerous applications in electronics, photonics and other areas often requires microassembly of separately prepared heterogeneous materials instead of monolithic microfabrication. However, microassembly of dissimilar materials while ensuring high structural integrity has been challenging in the context of deterministic transferring and joining of materials at the microscale where surface adhesion is far more dominant than body weight. Here we present an approach to assembling microsystems with microscale building blocks of four disparate classes of device-grade materials including semiconductors, metals, dielectrics, and polymers. This approach uniquely utilizes reversible adhesion-based transfer printing for material transferring and thermal processing for material joining at the microscale. The interfacial joining characteristics between materials assembled by this approach are systematically investigated upon different joining mechanisms using blister tests. The device level capabilities of this approach are further demonstrated through assembling and testing of a microtoroid resonator and a radio frequency (RF) microelectromechanical systems (MEMS) switch that involve optical and electrical functionalities with mechanical motion. This work opens up a unique route towards 3D heterogeneous material integration to fabricate microsystems. PMID:27427243

  8. Microassembly of Heterogeneous Materials using Transfer Printing and Thermal Processing

    NASA Astrophysics Data System (ADS)

    Keum, Hohyun; Yang, Zining; Han, Kewen; Handler, Drew E.; Nguyen, Thong Nhu; Schutt-Aine, Jose; Bahl, Gaurav; Kim, Seok

    2016-07-01

    Enabling unique architectures and functionalities of microsystems for numerous applications in electronics, photonics and other areas often requires microassembly of separately prepared heterogeneous materials instead of monolithic microfabrication. However, microassembly of dissimilar materials while ensuring high structural integrity has been challenging in the context of deterministic transferring and joining of materials at the microscale where surface adhesion is far more dominant than body weight. Here we present an approach to assembling microsystems with microscale building blocks of four disparate classes of device-grade materials including semiconductors, metals, dielectrics, and polymers. This approach uniquely utilizes reversible adhesion-based transfer printing for material transferring and thermal processing for material joining at the microscale. The interfacial joining characteristics between materials assembled by this approach are systematically investigated upon different joining mechanisms using blister tests. The device level capabilities of this approach are further demonstrated through assembling and testing of a microtoroid resonator and a radio frequency (RF) microelectromechanical systems (MEMS) switch that involve optical and electrical functionalities with mechanical motion. This work opens up a unique route towards 3D heterogeneous material integration to fabricate microsystems.

  9. Microassembly of Heterogeneous Materials using Transfer Printing and Thermal Processing

    PubMed Central

    Keum, Hohyun; Yang, Zining; Han, Kewen; Handler, Drew E.; Nguyen, Thong Nhu; Schutt-Aine, Jose; Bahl, Gaurav; Kim, Seok

    2016-01-01

    Enabling unique architectures and functionalities of microsystems for numerous applications in electronics, photonics and other areas often requires microassembly of separately prepared heterogeneous materials instead of monolithic microfabrication. However, microassembly of dissimilar materials while ensuring high structural integrity has been challenging in the context of deterministic transferring and joining of materials at the microscale where surface adhesion is far more dominant than body weight. Here we present an approach to assembling microsystems with microscale building blocks of four disparate classes of device-grade materials including semiconductors, metals, dielectrics, and polymers. This approach uniquely utilizes reversible adhesion-based transfer printing for material transferring and thermal processing for material joining at the microscale. The interfacial joining characteristics between materials assembled by this approach are systematically investigated upon different joining mechanisms using blister tests. The device level capabilities of this approach are further demonstrated through assembling and testing of a microtoroid resonator and a radio frequency (RF) microelectromechanical systems (MEMS) switch that involve optical and electrical functionalities with mechanical motion. This work opens up a unique route towards 3D heterogeneous material integration to fabricate microsystems. PMID:27427243

  10. Microassembly of Heterogeneous Materials using Transfer Printing and Thermal Processing.

    PubMed

    Keum, Hohyun; Yang, Zining; Han, Kewen; Handler, Drew E; Nguyen, Thong Nhu; Schutt-Aine, Jose; Bahl, Gaurav; Kim, Seok

    2016-01-01

    Enabling unique architectures and functionalities of microsystems for numerous applications in electronics, photonics and other areas often requires microassembly of separately prepared heterogeneous materials instead of monolithic microfabrication. However, microassembly of dissimilar materials while ensuring high structural integrity has been challenging in the context of deterministic transferring and joining of materials at the microscale where surface adhesion is far more dominant than body weight. Here we present an approach to assembling microsystems with microscale building blocks of four disparate classes of device-grade materials including semiconductors, metals, dielectrics, and polymers. This approach uniquely utilizes reversible adhesion-based transfer printing for material transferring and thermal processing for material joining at the microscale. The interfacial joining characteristics between materials assembled by this approach are systematically investigated upon different joining mechanisms using blister tests. The device level capabilities of this approach are further demonstrated through assembling and testing of a microtoroid resonator and a radio frequency (RF) microelectromechanical systems (MEMS) switch that involve optical and electrical functionalities with mechanical motion. This work opens up a unique route towards 3D heterogeneous material integration to fabricate microsystems.

  11. Microgravity Processing and Photonic Applications of Organic and Polymeric Materials

    NASA Technical Reports Server (NTRS)

    Frazier, Donald O.; Paley, Mark S.; Penn, Benjamin G.; Abdeldayem, Hossin A.; Smith, David D.; Witherow, William K.

    1997-01-01

    Some of the primary purposes of this work are to study important technologies, particularly involving thin films, relevant to organic and polymeric materials for improving applicability to optical circuitry and devices and to assess the contribution of convection on film quality in unit and microgravity environments. Among the most important materials processing techniques of interest in this work are solution-based and by physical vapor transport, both having proven gravitational and acceleration dependence. In particular, PolyDiAcetylenes (PDA's) and PhthaloCyanines (Pc's) are excellent NonLinear Optical (NLO) materials with the promise of significantly improved NLO properties through order and film quality enhancements possible through microgravity processing. Our approach is to focus research on integrated optical circuits and optoelectronic devices relevant to solution-based and vapor processes of interest in the Space Sciences Laboratory at the Marshall Space Flight Center (MSFC). Modification of organic materials is an important aspect of achieving more highly ordered structures in conjunction with microgravity processing. Parallel activities include characterization of materials for particular NLO properties and determination of appropriation device designs consistent with selected applications. One result of this work is the determination, theoretically, that buoyancy-driven convection occurs at low pressures in an ideal gas in a thermalgradient from source to sink. Subsequent experiment supports the theory. We have also determined theoretically that buoyancy-driven convection occurs during photodeposition of PDA, an MSFC-patented process for fabricating complex circuits, which is also supported by experiment. Finally, the discovery of intrinsic optical bistability in metal-free Pc films enables the possibility of the development of logic gate technology on the basis of these materials.

  12. Observation of Materials Processes in Liquids in the Electron Microscope

    SciTech Connect

    Wang, Chong M.; Liao, Honggang; Ross, Frances M.

    2015-01-01

    Materials synthesis and the functioning of devices often indispensably involve liquid media. But direct visualization of dynamic process in liquids, especially with high spatial and temporal resolution, has been challenging. For solid materials, advances in aberration corrected electron microscopy have made observation of atomic level features a routine practice. Here we discuss the extent to which one can take advantage of the resolution of modern electron microscopes to image phenomenon occuring in liquids. We will describe the fundamentals of two different experimental approaches, closed and open liquid cells. We will illustrate the capabilities of each approach by considering processes in batteries and nucleation and growth of nanoparticles from solution. We conclude that liquid cell electron microscopy appears to be duly fulfilling its role for in situ studies of nanoscale processes in liquids, revealing physical and chemical processes otherwise difficult to observe.

  13. Microgravity Processing and Photonic Applications of Organic and Polymeric Materials

    NASA Technical Reports Server (NTRS)

    Frazier, Donald 0; Penn, Benjamin G.; Smith, David; Witherow, William K.; Paley, M. S.; Abdeldayem, Hossin A.

    1998-01-01

    In recent years, a great deal of interest has been directed toward the use of organic materials in the development of high-efficiency optoelectronic and photonic devices. There is a myriad of possibilities among organic which allow flexibility in the design of unique structures with a variety of functional groups. The use of nonlinear optical (NLO) organic materials such as thin-film waveguides allows full exploitation of their desirable qualities by permitting long interaction lengths and large susceptibilities allowing modest power input. There are several methods in use to prepare thin films, such as Langmuir-Blodgett (LB) and self-assembly techniques, vapor deposition, growth from sheared solution or melt, and melt growth between glass plates. Organics have many features that make Abstract: them desirable for use in optical devices such as high second- and third-order nonlinearities, flexibility of molecular design, and damage resistance to optical radiation. However, their use in devices has been hindered by processing difficulties for crystals and thin films. In this chapter, we discuss photonic and optoelectronic applications of a few organic materials and the potential role of microgravity on processing these materials. It is of interest to note how materials with second- and third-order nonlinear optical behavior may be improved in a diffusion-limited environment and ways in which convection may be detrimental to these materials. We focus our discussion on third-order materials for all-optical switching, and second-order materials for all-optical switching, and second-order materials for frequency conversion and electrooptics.

  14. Evaluation criteria for commercially oriented materials processing in space proposals

    NASA Technical Reports Server (NTRS)

    Moore, W. F.; Mcdowell, J. R.

    1979-01-01

    An approach and criteria for evaluating NASA funded experiments and demonstrations which have commercial potential were developed. Methods for insuring quick initial screening of commercial proposals are presented. Recommendations are given for modifying the current evaluation approach. New criteria for evaluating commercially orientated materials processing in space (MPS) proposals are introduced. The process for selection of qualified individuals to evaluate the phases of this approach and criteria is considered and guidelines are set for its implementation.

  15. Am/Cm Vitrification Process: Vitrification Material Balance Calculations

    SciTech Connect

    Smith, F.G.

    2000-08-15

    This report documents material balance calculations for the Americium/Curium vitrification process and describes the basis used to make the calculations. The material balance calculations reported here start with the solution produced by the Am/Cm pretreatment process as described in ``Material Balance Calculations for Am/Cm Pretreatment Process (U)'', SRT-AMC-99-0178 [1]. Following pretreatment, small batches of the product will be further treated with an additional oxalic acid precipitation and washing. The precipitate from each batch will then be charged to the Am/Cm melter with glass cullet and vitrified to produce the final product. The material balance calculations in this report are designed to provide projected compositions of the melter glass and off-gas streams. Except for decanted supernate collected from precipitation and precipitate washing, the flowsheet neglects side streams such as acid washes of empty tanks that would go directly to waste. Complete listings of the results of the material balance calculations are provided in the Appendices to this report.

  16. Development of a polysilicon process based on chemical vapor deposition. Phase 1. Fourth quarterly progress report, 1 July-30 September 1980

    SciTech Connect

    Sharp, K.; Arvidson, A.; Sawyer, D.

    1980-12-01

    The goal of this program is to demonstrate that a dichlorosilane-based reductive chemical vapor deposition (CVD) process is capable of producing, at low cost, high quality polycrystalline silicon for use in the manufacture of high efficiency solar cells. The feasibility of silicon generation from dichlorosilane (DCS) has been well established. The feasibility and optimization portions of the experimental reactor program have been completed, with a number of runs having been conducted over a broad range of conditions in an experimental CVD reactor. Activities relating to feed of commercially purchased DCS to an intermediate sized reactor and to construction of a Process Development Unit (PDU) to generate and feed DCS to one or more production scale reactors were suspended during the previous quarter because of the receipt of new safety-related information about DCS from Hazards Research Corp. Experimental data generated by Hazards Research Corp. indicate that DCS/air mixtures possess about four times the explosive severity potential as hydrogen/air mixtures, and that DCS/air mixtures are very readily ignited. As a consequence of this new information, designs and procedures for the intermediate reactor feed and PDU tasks were deemed inadequate and new designs incorporating new safety-related elements are being formulated. A preliminary economic evaluation of the Hemlock Semiconductor process has been completed. The analysis for a plant to generate 1000 metric tonne of silicon indicates a plant investment of $21.9 M, and a product selling price of $19.85/kg.

  17. Microgravity Processing and Photonic Applications of Organic and Polymeric Materials

    NASA Technical Reports Server (NTRS)

    Frazier, Donald O.; Penn, Benjamin G.; Smith, David D.; Witherow, William K.; Paley, Mark S.; Abdeldayem, Hossin A.

    1997-01-01

    In recent years, a great deal of interest has been directed toward the use of organic materials in the development of high-efficiency optoelectronic and photonic devices. There is a myriad of possibilities among organics which allow flexibility in the design of unique structures with a variety of functional groups. The use of nonlinear optical (NLO) organic materials such as thin-film waveguides allows full exploitation of their desirable qualities by permitting long interaction lengths and large susceptibilities allowing modest power input. There are several methods in use to prepare thin films, such as Langmuir-Blodgett (LB) and self-assembly techniques, vapor deposition, growth from sheared solution or melt, and melt growth between glass plates. Organics have many features that make them desirable for use in optical devices such as high second- and third-order nonlinearities, flexibility of molecular design, and damage resistance to optical radiation. However, their use in devices has been hindered by processing difficulties for crystals and thin films. In this chapter, we discuss photonic and optoelectronic applications of a few organic materials and the potential role of microgravity on processing these materials. It is of interest to note how materials with second- and third-order nonlinear optical behavior may be improved in a diffusion-limited environment and ways in which convection may be detrimental to these materials.

  18. Summaries of early materials processing in space experiments

    NASA Technical Reports Server (NTRS)

    Naumann, R. J.; Mason, D.

    1979-01-01

    Objectives, methods, and results of low-gravity materials processing experiments are summarized, and a bibliography of published results for each experiment is provided. Included are drop tower experiments, the Apollo demonstration experiments, the skylab experiments and demonstration experiments, and the Apollo-Soyuz experiments and demonstrations. The findings of these experiments in the fields of crystal growth, metallurgy, and fluid behavior are summarized.

  19. CIGS Material and Device Stability: A Processing Perspective (Presentation)

    SciTech Connect

    Ramanathan, K.

    2012-03-01

    This is a general overview of CIGS material and device fundamentals. In the first part, the basic features of high efficiency CIGS absorbers and devices are described. In the second part, some examples of previous collaboration with Shell Solar CIGSS graded absorbers and devices are shown to illustrate how process information was used to correct deviations and improve the performance and stability.

  20. Processing fissile material mixtures containing zirconium and/or carbon

    DOEpatents

    Johnson, Michael Ernest; Maloney, Martin David

    2013-07-02

    A method of processing spent TRIZO-coated nuclear fuel may include adding fluoride to complex zirconium present in a dissolved TRIZO-coated fuel. Complexing the zirconium with fluoride may reduce or eliminate the potential for zirconium to interfere with the extraction of uranium and/or transuranics from fission materials in the spent nuclear fuel.

  1. Dielectric-Particle Injector For Processing Of Materials

    NASA Technical Reports Server (NTRS)

    Leung, Philip L.; Gabriel, Stephen B.

    1992-01-01

    Device generates electrically charged particles of solid, or droplets of liquid, fabricated from dielectric material and projects them electrostatically, possibly injecting them into electrostatic-levitation chamber for containerless processing. Dielectric-particle or -droplet injector charges dielectric particles or droplets on zinc plate with photo-electrons generated by ultraviolet illumination, then ejects charged particles or droplets electrostatically from plate.

  2. TOPICAL REVIEW: High-temperature microwave processing of materials

    NASA Astrophysics Data System (ADS)

    Bykov, Yu V.; Rybakov, K. I.; Semenov, V. E.

    2001-07-01

    This article reviews the physical aspects of a cross-disciplinary science and technology field: the microwave processing of materials. High-temperature microwave processing has a clear industrial perspective in such areas as the production of advanced ceramics, the deposition of thermal barrier coatings, the remediation of hazardous wastes etc. This review starts with the relevant fundamental notions regarding the absorption of electromagnetic waves, heat transfer and the electrodynamics of single- and multimode microwave cavities. Useful formulae, estimates, and interrelations between process variables are presented. This is followed by a review of process examples illustrating the specific features of microwave processing: reduction in energy consumption and process duration, rapid and controllable heating, peculiar temperature distribution, and selectivity of energy deposition. Much attention is given to the advantages of higher-frequency millimetre-wave processing, which include the enhanced absorption in many materials of industrial interest, improved uniformity of electromagnetic energy and temperature, and the possibility of surface treatment. The phenomenon of microwave process rate enhancement is addressed in connection with the problem of the non-thermal microwave effect on mass transport in solids. Both experimental and theoretical approaches to the identification of the mechanism responsible for this effect are illustrated. Finally, the physical and technical factors influencing microwave technology scaleup and transfer to industry are discussed.

  3. Process for Low Cost Domestic Production of LIB Cathode Materials

    SciTech Connect

    Thurston, Anthony

    2012-10-31

    The objective of the research was to determine the best low cost method for the large scale production of the Nickel-Cobalt-Manganese (NCM) layered cathode materials. The research and development focused on scaling up the licensed technology from Argonne National Laboratory in BASF’s battery material pilot plant in Beachwood Ohio. Since BASF did not have experience with the large scale production of the NCM cathode materials there was a significant amount of development that was needed to support BASF’s already existing research program. During the three year period BASF was able to develop and validate production processes for the NCM 111, 523 and 424 materials as well as begin development of the High Energy NCM. BASF also used this time period to provide free cathode material samples to numerous manufactures, OEM’s and research companies in order to validate the ma-terials. The success of the project can be demonstrated by the construction of the production plant in Elyria Ohio and the successful operation of that facility. The benefit of the project to the public will begin to be apparent as soon as material from the production plant is being used in electric vehicles.

  4. Status and potential of atmospheric plasma processing of materials

    SciTech Connect

    Pappas, Daphne

    2011-03-15

    This paper is a review of the current status and potential of atmospheric plasma technology for materials processing. The main focus is the recent developments in the area of dielectric barrier discharges with emphasis in the functionalization of polymers, deposition of organic and inorganic coatings, and plasma processing of biomaterials. A brief overview of both the equipment being used and the physicochemical reactions occurring in the gas phase is also presented. Atmospheric plasma technology offers major industrial, economic, and environmental advantages over other conventional processing methods. At the same time there is also tremendous potential for future research and applications involving both the industrial and academic world.

  5. Materials and processes laboratory composite materials characterization task, part 1. Damage tolerance

    NASA Technical Reports Server (NTRS)

    Nettles, A. T.; Tucker, D. S.; Patterson, W. J.; Franklin, S. W.; Gordon, G. H.; Hart, L.; Hodge, A. J.; Lance, D. G.; Russel, S. S.

    1991-01-01

    A test run was performed on IM6/3501-6 carbon-epoxy in which the material was processed, machined into specimens, and tested for damage tolerance capabilities. Nondestructive test data played a major role in this element of composite characterization. A time chart was produced showing the time the composite material spent within each Branch or Division in order to identify those areas which produce a long turnaround time. Instrumented drop weight testing was performed on the specimens with nondestructive evaluation being performed before and after the impacts. Destructive testing in the form of cross-sectional photomicrography and compression-after-impact testing were used. Results show that the processing and machining steps needed to be performed more rapidly if data on composite material is to be collected within a reasonable timeframe. The results of the damage tolerance testing showed that IM6/3501-6 is a brittle material that is very susceptible to impact damage.

  6. Process feasibility study in support of silicon material, task 1

    NASA Technical Reports Server (NTRS)

    Li, K. Y.; Hansen, K. C.; Yaws, C. L.

    1979-01-01

    Analyses of process system properties were continued for materials involved in the alternate processes under consideration for semiconductor silicon. Primary efforts centered on physical and thermodynamic property data for dichlorosilane. The following property data are reported for dichlorosilane which is involved in processing operations for solar cell grade silicon: critical temperature, critical pressure, critical volume, critical density, acentric factor, vapor pressure, heat of vaporization, gas heat capacity, liquid heat capacity and density. Work was initiated on the assembly of a system to prepare binary gas mixtures of known proportions and to measure the thermal conductivity of these mixtures between 30 and 350 C. The binary gas mixtures include silicon source material such as silanes and halogenated silanes which are used in the production of semiconductor silicon.

  7. Oxygen production on the Lunar materials processing frontier

    NASA Technical Reports Server (NTRS)

    Altenberg, Barbara H.

    1992-01-01

    During the pre-conceptual design phase of an initial lunar oxygen processing facility, it is essential to identify and compare the available processes and evaluate them in order to ensure the success of such an endeavor. The focus of this paper is to provide an overview of materials processing to produce lunar oxygen as one part of a given scenario of a developing lunar occupation. More than twenty-five techniques to produce oxygen from lunar materials have been identified. While it is important to continue research on any feasible method, not all methods can be implemented at the initial lunar facility. Hence, it is necessary during the pre-conceptual design phase to evaluate all methods and determine the leading processes for initial focus. Researchers have developed techniques for evaluating the numerous proposed methods in order to suggest which processes would be best to go to the Moon first. As one section in this paper, the recent evaluation procedures that have been presented in the literature are compared and contrasted. In general, the production methods for lunar oxygen fall into four categories: thermochemical, reactive solvent, pyrolytic, and electrochemical. Examples from two of the four categories are described, operating characteristics are contrasted, and terrestrial analogs are presented when possible. In addition to producing oxygen for use as a propellant and for life support, valuable co-products can be derived from some of the processes. This information is also highlighted in the description of a given process.

  8. Cadmium sulfide/copper sulfide heterojunction cell research: critical studies in materials and durability. Quarterly progress report No. 3, January 1-March 31, 1980

    SciTech Connect

    1980-10-01

    Characterization of the CdS and (CdZn)S substrate material has continued. The morphological differences between heterojunctions made by solid and solution reaction processes have been further detailed. The results of cell stability testing under open circuit and 0.3V loading are reported.

  9. Quarterly progress report for Q1 FY06 for Complex Transient Events in Materials Studied Using Ultrafast Electron Probes and Terascale Simulation (FWP SCW0289)

    SciTech Connect

    Campbell, G

    2005-12-27

    This quarter (Q1 FY06) marked the first time that the LLNL dynamic transmission electron microscope (DTEM) configuration had advanced to the point whereby it was possible to conduct in-situ experiments on specimens. DTEM improvements continue to progress at a rapid pace. We summarize important achievements in the following list: (1) Instrument performance and design improvements - (a) Reproducibly achieving >1 x 10{sup 7} e{sup -} per pulse. Adjustments in the cathode laser system design led to an improved quantum efficiency and electron yield per pulse. The current number of electrons in the pulse is sufficient for acquiring high quality, single-shot electron diffraction patterns. (b) Implementation of computer interface and Labview{reg_sign} programs for cathode and specimen drive alignment and cathode and pump laser trigger and delay settings. These controls provide a user friendly interface and ease in the experimental setup and implementation. (c) Cathode test chamber (offline test apparatus to asses photocathode design and laser induced photoemission) construction has been completed. (2) Notable instrument features brought into service - (a) Drive laser system was enhanced to improve beam shape and uniformity and to include continuous laser energy monitoring. The drive laser spot size on the specimen was also reduced from 70 {mu}m x 110 {mu}m to 50 {mu}m x 75 {mu}m. (b) New phosphor coated face plate manufactured by TVIPS was installed. The sensitivity and signal noise ratio improved by factor 2 (sensitivity {approx}110 CCD counts/e{sup -} and signal to noise ratio {approx}5). (3) Experimental Progress - (a) First time-resolved experiment: observation of the {alpha} (hcp) to {beta} (bcc) phase transition in pure Ti films via single shot electron diffraction. Results of this experiment were published in the MRS Fall 2005 proceedings and are under review for article in the FEMMS proceedings, which will to be published in Journal of Material Science. See

  10. Cadmium isotope fractionation of materials derived from various industrial processes.

    PubMed

    Martinková, Eva; Chrastný, Vladislav; Francová, Michaela; Šípková, Adéla; Čuřík, Jan; Myška, Oldřich; Mižič, Lukáš

    2016-01-25

    Our study represents ϵ(114/110) Cd NIST3108 values of materials resulting from anthropogenic activities such as coal burning, smelting, refining, metal coating, and the glass industry. Additionally, primary sources (ore samples, pigment, coal) processed in the industrial premises were studied. Two sphalerites, galena, coal and pigment samples exhibited ϵ(114/110) CdNIST3108 values of 1.0±0.2, 0.2±0.2, 1.3±0.1, -2.3±0.2 and -0.1±0.3, respectively. In general, all studied industrial processes were accompanied by Cd isotope fractionation. Most of the industrial materials studied were clearly distinguishable from the samples used as a primary source based on ϵ(114/110) Cd NIST3108 values. The heaviest ϵ(114/110) CdNIST3108 value of 58.6±0.9 was found for slag resulting from coal combustion, and the lightest ϵ(114/110) CdNIST3108 value of -23±2.5 was observed for waste material after Pb refinement. It is evident that ϵ(114/110) Cd NIST3108 values depend on technological processes, and in case of incomplete Cd transfer from source to final waste material, every industrial activity creates differences in Cd isotope composition. Our results show that Cd isotope analysis is a promising tool to track the origins of industrial waste products. PMID:26452089

  11. Cadmium isotope fractionation of materials derived from various industrial processes.

    PubMed

    Martinková, Eva; Chrastný, Vladislav; Francová, Michaela; Šípková, Adéla; Čuřík, Jan; Myška, Oldřich; Mižič, Lukáš

    2016-01-25

    Our study represents ϵ(114/110) Cd NIST3108 values of materials resulting from anthropogenic activities such as coal burning, smelting, refining, metal coating, and the glass industry. Additionally, primary sources (ore samples, pigment, coal) processed in the industrial premises were studied. Two sphalerites, galena, coal and pigment samples exhibited ϵ(114/110) CdNIST3108 values of 1.0±0.2, 0.2±0.2, 1.3±0.1, -2.3±0.2 and -0.1±0.3, respectively. In general, all studied industrial processes were accompanied by Cd isotope fractionation. Most of the industrial materials studied were clearly distinguishable from the samples used as a primary source based on ϵ(114/110) Cd NIST3108 values. The heaviest ϵ(114/110) CdNIST3108 value of 58.6±0.9 was found for slag resulting from coal combustion, and the lightest ϵ(114/110) CdNIST3108 value of -23±2.5 was observed for waste material after Pb refinement. It is evident that ϵ(114/110) Cd NIST3108 values depend on technological processes, and in case of incomplete Cd transfer from source to final waste material, every industrial activity creates differences in Cd isotope composition. Our results show that Cd isotope analysis is a promising tool to track the origins of industrial waste products.

  12. Food material properties and early hominin processing techniques.

    PubMed

    Zink, Katherine D; Lieberman, Daniel E; Lucas, Peter W

    2014-12-01

    Although early Homo is hypothesized to have used tools more than australopiths to process foods prior to consumption, it is unknown how much the food processing techniques they used altered the material properties of foods, and therefore the masticatory forces they generated, and how well they were able to comminute foods. This study presents experimental data on changes to food material properties caused by mechanical tenderization (pounding with a stone tool) and cooking (dry roasting) of two foods likely to have been important components of the hominin diet: meat and tubers. Mechanical tenderization significantly decreased tuber toughness by 42%, but had no effect on meat toughness. Roasting significantly decreased several material properties of tubers correlated with masticatory effort including toughness (49%), fracture stress (28%) and elastic modulus (45%), but increased the toughness (77%), fracture stress (50%-222%), and elastic modulus of muscle fibers in meat (308%). Despite increasing many material properties of meat associated with higher masticatory forces, roasting also decreased measured energy loss by 28%, which likely makes it easier to chew. These results suggest that the use of food processing techniques by early Homo probably differed for meat and tubers, but together would have reduced masticatory effort, helping to relax selection to maintain large, robust faces and large, thickly enameled teeth.

  13. Process Feasibility Study in Support of Silicon Material Task 1

    NASA Technical Reports Server (NTRS)

    Li, K. Y.; Hansen, K. C.; Yaws, C. L.

    1979-01-01

    Analysis of process system properties was continued for silicon source materials under consideration for producing silicon. The following property data are reported for dichlorosilane which is involved in processing operations for silicon: critical constants, vapor pressure, heat of vaporization, heat capacity, density, surface tension, thermal conductivity, heat of formation and Gibb's free energy of formation. The properties are reported as a function of temperature to permit rapid engineering usage. The preliminary economic analysis of the process is described. Cost analysis results for the process (case A-two deposition reactors and six electrolysis cells) are presented based on a preliminary process design of a plant to produce 1,000 metric tons/year of silicon. Fixed capital investment estimate for the plant is $12.47 million (1975 dollars) ($17.47 million, 1980 dollars). Product cost without profit is 8.63 $/kg of silicon (1975 dollars)(12.1 $/kg, 1980 dollars).

  14. Processing and nanostructure influences on mechanical properties of thermoelectric materials

    NASA Astrophysics Data System (ADS)

    Schmidt, Robert David

    Thermoelectric (TE) materials are materials that can generate an electric current from a thermal gradient, with possible service in recovery of waste heat such as engine exhaust. Significant progress has been made in improving TE conversion efficiency, typically reported according to the figure of merit, ZT, with several recent papers publishing ZT values above 2. Furthermore, cost reductions may be made by the use of lower cost elements such as Mg, Si, Sn, Pb, Se and S in TE materials, while achieving ZT values between 1.3 and 1.8. To be used in a device, the thermoelectric material must be able to withstand the applied thermal and mechanical forces without failure. However, these materials are brittle, with low fracture toughness typically less than 1.5 MPa-m1/2, and often less than 0.5 MPa-m1/2. For comparison, window glass is approximately 0.75 MPa-m1/2. They have been optimized with nanoprecipitates, nanoparticles, doping, alterations in stoichiometry, powder processing and other techniques, all of which may alter the mechanical properties. In this study, the effect of SiC nanoparticle additions in Mg2Si, SnTe and Ag nanoparticle additions in the skutterudite Ba0.3Co 4Sb12 on the elastic moduli, hardness and fracture toughness are measured. Large changes (˜20%) in the elastic moduli in SnTe 1+x as a function of x at 0 and 0.016 are shown. The effect on mechanical properties of doping and precipitates of CdS or ZnS in a PbS or PbSe matrix have been reported. Changes in sintering behavior of the skutterudite with the Ag nanoparticle additions were explored. Possible liquid phase sintering, with associated benefits in lower processing temperature, faster densification and lower cost, has been shown. A technique has been proposed for determining additional liquid phase sintering aids in other TE materials. The effects of porosity, grain size, powder processing method, and sintering method were explored with YbAl3 and Ba0.3Co4Sb 12, with the porosity dependence of

  15. Development of the selective coagulation process. Fourth quarter technical progress report, July 1, 1991--September 30, 1991

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.

    1991-12-31

    The aim of this project is to develop an economical method for producing low-sulfur and low-ash coals using the selective hydrophobic coagulation (SHC) process. This work has been divided into three tasks: (1) project planning and sample acquisition; (2) studies of the fundamental mechanism(s) of the selective coagulation process and the parameters that affect the process of separating coal from both the ash-forming minerals and pyritic sulfur; and (3) bench-scale process development test work to establish the best possible method(s) of separating the hydrophobic and coagula from the dispersed mineral matter.

  16. Processing of solid mixed waste containing radioactive and hazardous materials

    DOEpatents

    Gotovchikov, Vitaly T.; Ivanov, Alexander V.; Filippov, Eugene A.

    1998-05-12

    Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter.

  17. Processing of solid mixed waste containing radioactive and hazardous materials

    DOEpatents

    Gotovchikov, V.T.; Ivanov, A.V.; Filippov, E.A.

    1998-05-12

    Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter. 6 figs.

  18. Multiscale characterization and representation of composite materials during processing.

    PubMed

    Zobeiry, Navid; Forghani, Alireza; Li, Chao; Gordnian, Kamyar; Thorpe, Ryan; Vaziri, Reza; Fernlund, Goran; Poursartip, Anoush

    2016-07-13

    Given the importance of residual stresses and dimensional changes in composites manufacturing, process simulation has been the focus of many studies in recent years. Consequently, various constitutive models and simulation approaches have been developed and implemented for composites process simulation. In this paper, various constitutive models, ranging from elastic to nonlinear viscoelastic; and simulation approaches ranging from separated flow/solid phases to multiscale integrated phases are presented and their applicability for process simulation is discussed. Attention has been paid to practical aspects of the problem where the complexity of the model coupled with the complexity and size scaling of the structure increases the characterization and simulation costs. Two specific approaches and their application are presented in detail: the pseudo-viscoelastic cure hardening instantaneously linear elastic (CHILE) and linear viscoelastic (VE). It is shown that CHILE can predict the residual stress formation in simple cure cycles such as the one-hold cycle for HEXCEL AS4/8552 where the material does not devitrify during processing. It is also shown that using this simple approach, the cure cycle can be modified to lower the residual stress level and therefore increase the mechanical performance of the composite laminate. For a more complex cure cycle where the material is devitrified during a post-cure, it is shown that a more complex model such as VE is required. This article is part of the themed issue 'Multiscale modelling of the structural integrity of composite materials'. PMID:27242297

  19. Measurement and modeling of advanced coal conversion processes. 19th quarterly report, April 1, 1991--June 30, 1991

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.; Smoot, L.D.; Brewster, B.S.

    1991-09-25

    The objectives of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. (VC)

  20. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, April 1--June 30, 1996

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.

    1997-03-01

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of chemical analyses to direct coal liquefaction process development. Independent analyses by well-established methods are obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, new analytical instruments and techniques to examine coal-derived samples are being evaluated. The data obtained form this study are used to guide process development and to develop an improved data base on coal and coal liquids properties. A sample bank, established and maintained for use in this project, is available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) is being examined. From the literature and experimental data, a kinetic model of resid conversion will be constructed. Such a model will provide insights to improve process performance and the economics of direct coal liquefaction.

  1. Investigation of Test Methods, Material Properties, and Processes for Solar Cell Encapsulants

    NASA Technical Reports Server (NTRS)

    1979-01-01

    During this quarter the technical activities were directed toward the reformulation of ethylene/vinyl acetate copolymer for use as a compound in solar cell module fabrication. Successful formulations were devised that lowered the temperature required for cure and raised the gel content. A major volatile component was also eliminated (acrylate crosslinking agent) which should aid in the production of bubble free laminates. Adhesive strengths and primers for the bonding of ethylene/vinyl acetate to supersyrate and substrate materials was assessed with encouraging results. The incorporation of silane compounds gave high bond strengths. A survey of scrim materials was also conducted.

  2. Material flow simulation in a nuclear chemical process

    SciTech Connect

    Mahgerefteh, M.

    1984-01-01

    At a nuclear fuel reprocessing plant the special nuclear materials (SNM) are received as constituents of spent fuel assemblies, are converted to liquid form, and undergo a series of chemical processes. Uncertainties in measurements of SNM at each stage of reprocessing limit the accuracy of simple material balance accounting as a safeguards method. To be effective, a formal safeguards program must take into account all sources of measurement error yet detect any diversion of SNM. An analytical method for assessing the accountability of selected constituent SNM is demonstrated. A combined discrete-continuous, time-dependent model using the GASP IV simulation language is developed to simulate mass flow, material accountability and measurement error at each stage of the reprocessing plant.

  3. MISSE in the Materials and Processes Technical Information System (MAPTIS )

    NASA Technical Reports Server (NTRS)

    Burns, DeWitt; Finckenor, Miria; Henrie, Ben

    2013-01-01

    Materials International Space Station Experiment (MISSE) data is now being collected and distributed through the Materials and Processes Technical Information System (MAPTIS) at Marshall Space Flight Center in Huntsville, Alabama. MISSE data has been instrumental in many programs and continues to be an important source of data for the space community. To facilitate great access to the MISSE data the International Space Station (ISS) program office and MAPTIS are working to gather this data into a central location. The MISSE database contains information about materials, samples, and flights along with pictures, pdfs, excel files, word documents, and other files types. Major capabilities of the system are: access control, browsing, searching, reports, and record comparison. The search capabilities will search within any searchable files so even if the desired meta-data has not been associated data can still be retrieved. Other functionality will continue to be added to the MISSE database as the Athena Platform is expanded

  4. Bridging Microstructure, Properties and Processing of Polymer Based Advanced Materials

    SciTech Connect

    Li, Dongsheng; Ahzi, Said; Khaleel, Mohammad A.

    2012-01-01

    This is a guest editorial for a special issue in Journal of Engineering Materials and Technology. The papers collected in this special issue emphasize significant challenges, current approaches and future strategies necessary to advance the development of polymer-based materials. They were partly presented at the symposium of 'Bridging microstructure, properties and processing of polymer based advanced materials' in the TMS 2011 annual conference meeting, which was held in San Diego, US, on Feb 28 to March 3, 2011. This symposium was organized by the Pacific Northwest National Laboratory (USA) and the Institute of Mechanics of Fluids and Solids of the University of Strasbourg (France). The organizers were D.S. Li, S. Ahzi, and M. Khaleel.

  5. Improving IC process efficiency with critical materials management

    NASA Astrophysics Data System (ADS)

    Hanson, Kathy L.; Andrews, Robert E.

    2003-06-01

    The management of critical materials in a high technology manufacturing facility is crucial to obtaining consistently high production yield. This is especially true in an industry like semiconductors where the success of the product is so dependent on the integrity of the critical production materials. Bar code systems, the traditional management tools, are voluntary, defeatable, and do not continuously monitor materials when in use. The significant costs associated with mis-management of chemicals can be captured with a customized model resulting in highly favorable ROI"s for the NOWTrak RFID chemical management system. This system transmits reliable chemical data about each individual container and generates information that can be used to increase wafer production efficiency and yield. The future of the RFID system will expand beyond the benefits of chemical management and into dynamic IC process management

  6. Development of a coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, January--March 1994

    SciTech Connect

    Not Available

    1994-04-30

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system, controls, and then test the complete system in order to evaluate its potential marketability. The past quarter began with a two-day test performed in January to determine the cause of pulsations in the batch feed system observed during pilot-scale testing of surrogate TSCA incinerator ash performed in December of 1993. Two different batch feedstocks were used during this test: flyash and cullet. The cause of the pulsations was traced to a worn part in the feeder located at the bottom of the batch feed tank. The problem was corrected by replacing the wom part with the corresponding part on the existing coal feed tank. A new feeder for the existing coal tank, which had previously been ordered as part of the new coal handling system, was procured and installed. The data from the pilot-scale tests performed on surrogate TSCA incinerator ash during December of 1993 was collected and analyzed. All of the glass produced during the test passed both the Toxicity characteristics Leach Procedure (TCLP) and the Product Consistency Test (PCT) by approximately two orders of magnitude.

  7. New spin-on metal hardmask materials for lithography processes

    NASA Astrophysics Data System (ADS)

    Yao, Huirong; Mullen, Salem; Wolfer, Elizabeth; Rahman, Dalil; Anyadiegwu, Clement; Mckenzie, Douglas; Dioses, Alberto; Cho, Joonyeon; Padmanaban, Munirathna

    2013-03-01

    Since the critical dimensions in integrated circuit (IC) device fabrication continue to shrink below 32 nm, multilayer stacks with alternating etch selectivities are required for successful pattern transfer from the exposed photoresist to the substrate. Inorganic resist underlayer materials are used as hard masks in reactive ion etching (RIE) with oxidative gases. The conventional silicon hardmask has demonstrated good reflectivity control and reasonable etch selectivity. However, some issues such as the rework of trilayer stacks and cleaning of oxide residue by wet chemistry are challenging problems for manufacturability. The present work reveals novel spin-on underlayer materials containing significant amounts of metal oxides in the film after baking at normal processing conditions. Such an inorganic metal hardmask (MHM) has excellent etch selectivity in plasma etch processes of the trilayer stack. The composition has good long term shelf life and pot life stability based on solution LPC analysis and wafer defect studies, respectively. The material absorbs DUV wavelengths and can be used as a spin-on inorganic or hybrid antireflective coating to control substrate reflectivity under DUV exposure of photoresist. Some of these metal-containing materials can be used as an underlayer in EUV lithography to significantly enhance photospeed. Specific metal hard masks are also developed for via or trench filling applications in IRT processes. The materials have shown good coating and lithography performance with a film thicknesses as low as 10 nm under ArF dry or immersion conditions. In addition, the metal oxide films or residues can be partially or completely removed by using various wet-etching solutions at ambient temperature.

  8. Early differential processing of material images: Evidence from ERP classification.

    PubMed

    Wiebel, Christiane B; Valsecchi, Matteo; Gegenfurtner, Karl R

    2014-06-24

    Investigating the temporal dynamics of natural image processing using event-related potentials (ERPs) has a long tradition in object recognition research. In a classical Go-NoGo task two characteristic effects have been emphasized: an early task independent category effect and a later task-dependent target effect. Here, we set out to use this well-established Go-NoGo paradigm to study the time course of material categorization. Material perception has gained more and more interest over the years as its importance in natural viewing conditions has been ignored for a long time. In addition to analyzing standard ERPs, we conducted a single trial ERP pattern analysis. To validate this procedure, we also measured ERPs in two object categories (people and animals). Our linear classification procedure was able to largely capture the overall pattern of results from the canonical analysis of the ERPs and even extend it. We replicate the known target effect (differential Go-NoGo potential at frontal sites) for the material images. Furthermore, we observe task-independent differential activity between the two material categories as early as 140 ms after stimulus onset. Using our linear classification approach, we show that material categories can be differentiated consistently based on the ERP pattern in single trials around 100 ms after stimulus onset, independent of the target-related status. This strengthens the idea of early differential visual processing of material categories independent of the task, probably due to differences in low-level image properties and suggests pattern classification of ERP topographies as a strong instrument for investigating electrophysiological brain activity.

  9. Materials processing in space - A strategy for commercialization

    NASA Technical Reports Server (NTRS)

    Naumann, R. J.

    1978-01-01

    Major aerospace companies are talking about space factories manufacturing billions of dollars worth of high technology materials per year. On the other hand, a recent National Academy of Sciences study team saw little prospect for space manufacturing because, in their opinion, most of the disturbing effects of gravity in the processes they considered could be overcome on the ground for much less expenditure. This paper presents a current assessment of the problems and promises of the Materials Processing in Space Program and outlines a strategy for developing the first products of commercial value. These early products are expected to serve as paradigms of what can be accomplished by manufacturing in space and should stimulate industry to develop space manufacturing to whatever degree is economically justifiable.

  10. Some limitations on processing materials in acoustic levitation devices

    NASA Technical Reports Server (NTRS)

    Oran, W. A.; Witherow, W. K.; Ross, B. B.; Rush, J. E.

    1979-01-01

    The spot heating of samples, suspended in an acoustic field, was investigated to determine if the technique could be used to process materials. A single axis resonance device operating in air at 25 C with an rms pressure maximum of 160 to 170 db was used in the experiments. The heat flow from a hot object suspended in a levitation node is dominated by the effects of the field, with the heat loss approximately 20 times larger than that due to natural convection. The acoustic forces which suspend the body at a node also serve to eject the heated air. The coupling between the locally heated region around the body and the acoustic field results in instabilities in both the pressure wave and force field. The investigations indicated the extreme difficulties in developing a materials processing device based on acoustic/spot heating for use in a terrestrial environment.

  11. Process research on non-CZ silicon material

    NASA Technical Reports Server (NTRS)

    1982-01-01

    High risk, high payoff research areas associated with he process for producing photovoltaic modules using non-CZ sheet material are investigated. All investigations are being performed using dendritic web silicon, but all processes are directly applicable to other ribbon forms of sheet material. The technical feasibility of forming front and back junctions in non-CZ silicon using liquid dopant techniques was determined. Numerous commercially available liquid phosphorus and boron dopant solutions are investigated. Temperature-time profiles to achieve N(+) and P(+) sheet resistivities of 60 + or - 10 and 40 + or - s10 ohms per square centimeter respectively are established. A study of the optimal method of liquid dopant application is performed. The technical feasibility of forming a liquid applied diffusion mask to replace the more costly chemical vapor deposited SiO2 diffusion mask was also determined.

  12. Study on processing immiscible materials in zero gravity

    NASA Technical Reports Server (NTRS)

    Reger, J. L.; Mendelson, R. A.

    1975-01-01

    An experimental investigation was conducted to evaluate mixing immiscible metal combinations under several process conditions. Under one-gravity, these included thermal processing, thermal plus electromagnetic mixing, and thermal plus acoustic mixing. The same process methods were applied during free fall on the MSFC drop tower facility. The design is included of drop tower apparatus to provide the electromagnetic and acoustic mixing equipment, and a thermal model was prepared to design the specimen and cooling procedure. Materials systems studied were Ca-La, Cd-Ga and Al-Bi; evaluation of the processed samples included the morphology and electronic property measurements. The morphology was developed using optical and scanning electron microscopy and microprobe analyses. Electronic property characterization of the superconducting transition temperatures were made using an impedance change-tuned coil method.

  13. Expert model process control of composite materials in a press

    NASA Astrophysics Data System (ADS)

    Saliba, Tony E.; Quinter, Suzanne R.; Abrams, Frances L.

    An expert model for the control of the press processing of thermoset composite materials has been developed. The knowledge base written using the PC PLUS expert system shell was interfaced with models written in FORTRAN. The expert model, which is running on a single computer with a single processor, takes advantage of the symbol-crunching capability of LISP and the number crunching capability of FORTRAN. The Expert Model control system is a qualitative-quantitative process automation (QQPA) system since it includes both quantitative model-based and qualitative rule-based expert system operations. Various physical and mechanical properties were measured from panels processed using the two cycles. Using QQPA, processing time has been reduced significantly without altering product quality.

  14. Multi-material processing by LENS{trademark}

    SciTech Connect

    Griffith, M.L.; Harwell, L.D.; Romero, J.T.; Schlienger, E.; Atwood, C.L.; Smugeresky, J.E.

    1997-10-01

    During the past few years, solid freeform fabrication has evolved into direct fabrication of metallic components using computer aided design (CAD) solid models. Laser Engineered Net Shaping (LENS{trademark}) is one such technique being developed at Sandia to fabricate high strength, near net shape metallic components. In the past two years a variety of components have been fabricated using LENS{trademark} for applications ranging from prototype parts to injection mold tooling. To advance direct fabrication capabilities, a process must be able to accommodate a wide range of materials, including alloys and composites. This is important for tailoring certain physical properties critical to component performance. Examples include graded deposition for matching coefficient of thermal expansion between dissimilar materials, layered fabrication for novel mechanical properties, and new alloy design where elemental constituents and/or alloys are blended to create new materials. In this paper, the authors will discuss the development of precise powder feeding capabilities for the LENS{trademark} process to fabricate graded or layered material parts. They also present preliminary results from chemical and microstructural analysis.

  15. Quarterly coal report

    SciTech Connect

    Young, P.

    1996-05-01

    The Quarterly Coal Report (QCR) provides comprehensive information about U.S. coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for October through December 1995 and aggregated quarterly historical data for 1987 through the third quarter of 1995. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  16. Advanced direct liquefaction concepts for PETC generic units. Quarterly technical progress report, July 1992--September 1992

    SciTech Connect

    Not Available

    1992-11-01

    Preparation of the baseline economic assessment, based on Wilsonville Run {number_sign}263J, continued. This baseline study will serve as the reference against which the results of this program will be compared. During the quarter calculation of the material and energy balances for the conceptual commercial plant were completed and estimation of the investment for the main process units was begun (Wyoming plant site basis). A presentation on the technical results of the baseline study was prepared and delivered at the Quarterly Project Review Meeting in Pittsburgh.

  17. Process for converting cellulosic materials into fuels and chemicals

    DOEpatents

    Scott, Charles D.; Faison, Brendlyn D.; Davison, Brian H.; Woodward, Jonathan

    1994-01-01

    A process for converting cellulosic materials, such as waste paper, into fuels and chemicals utilizing enzymatic hydrolysis of the major constituent of paper, cellulose. A waste paper slurry is contacted by cellulase in an agitated hydrolyzer. The cellulase is produced from a continuous, columnar, fluidized-bed bioreactor utilizing immobilized microorganisms. An attritor and a cellobiase reactor are coupled to the agitated hydrolyzer to improve reaction efficiency. The cellulase is recycled by an adsorption process. The resulting crude sugars are converted to dilute product in a fluidized-bed bioreactor utilizing microorganisms. The dilute product is concentrated and purified by utilizing distillation and/or a biparticle fluidized-bed bioreactor system.

  18. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, July 1994--September 1994

    SciTech Connect

    1994-12-01

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a {open_quotes}Coal-Fired Combustion System for Industrial Process Heating Applications{close_quotes} is a project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability.

  19. 6. Interior of quarters (executive officer's quarters), living room, looking ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. Interior of quarters (executive officer's quarters), living room, looking west - Naval Air Station Chase Field, Quarters S, Essex Street, .45 mile South-Southeast of intersection of Texas State Highway 202 & Independence Street, Beeville, Bee County, TX

  20. 3. Southwest side of quarters (executive officer's quarters), looking northeast ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. Southwest side of quarters (executive officer's quarters), looking northeast - Naval Air Station Chase Field, Quarters S, Essex Street, .45 mile South-Southeast of intersection of Texas State Highway 202 & Independence Street, Beeville, Bee County, TX

  1. 1. North side of quarters (executive officer's quarters), looking southeast ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. North side of quarters (executive officer's quarters), looking southeast - Naval Air Station Chase Field, Quarters S, Essex Street, .45 mile South-Southeast of intersection of Texas State Highway 202 & Independence Street, Beeville, Bee County, TX

  2. 4. South side of quarters (executive officer's quarters), looking north ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. South side of quarters (executive officer's quarters), looking north - Naval Air Station Chase Field, Quarters S, Essex Street, .45 mile South-Southeast of intersection of Texas State Highway 202 & Independence Street, Beeville, Bee County, TX

  3. 2. West side of quarters (executive officer's quarters), looking east ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. West side of quarters (executive officer's quarters), looking east - Naval Air Station Chase Field, Quarters S, Essex Street, .45 mile South-Southeast of intersection of Texas State Highway 202 & Independence Street, Beeville, Bee County, TX

  4. 5. East side of quarters (executive officer's quarters), looking west ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    5. East side of quarters (executive officer's quarters), looking west - Naval Air Station Chase Field, Quarters S, Essex Street, .45 mile South-Southeast of intersection of Texas State Highway 202 & Independence Street, Beeville, Bee County, TX

  5. Contextual view of quarters no. 2 quarters no. 1, and ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Contextual view of quarters no. 2 quarters no. 1, and water tower, looking southwest. - Sacramento National Wildlife Refuge, Headquarters Complex, Quarters No. 2, 752 County Road 99W, Willows, Glenn County, CA

  6. Process optimization electrospinning fibrous material based on polyhydroxybutyrate

    NASA Astrophysics Data System (ADS)

    Olkhov, A. A.; Tyubaeva, P. M.; Staroverova, O. V.; Mastalygina, E. E.; Popov, A. A.; Ischenko, A. A.; Iordanskii, A. L.

    2016-05-01

    The article analyzes the influence of the main technological parameters of electrostatic spinning on the morphology and properties of ultrathin fibers on the basis of polyhydroxybutyrate. It is found that the electric conductivity and viscosity of the spinning solution affects the process of forming fibers macrostructure. The fiber-based materials PHB lets control geometry and optimize the viscosity and conductivity of a spinning solution. The resulting fibers have found use in medicine, particularly in the construction elements musculoskeletal.

  7. Low cost materials of construction for biological processes: Proceedings

    SciTech Connect

    Not Available

    1993-05-13

    The workshop was held, May 1993 in conjunction with the 15th Symposium on Biotechnology for Fuels and Chemicals. The purpose of this workshop was to present information on the biomass to ethanol process in the context of materials selection and through presentation and discussion, identify promising avenues for future research. Six technical presentations were grouped into two sessions: process assessment and technology assessment. In the process assessment session, the group felt that the pretreatment area would require the most extensive materials research due the complex chemical, physical and thermal environment. Discussion centered around the possibility of metals being leached into the process stream and their effect on the fermentation mechanics. Linings were a strong option for pretreatment assuming the economics were favorable. Fermentation was considered an important area for research also, due to the unique complex of compounds and dual phases present. Erosion in feedstock handling equipment was identified as a minor concern. In the technology assessment session, methodologies in corrosion analysis were presented in addition to an overview of current coatings/linings technology. Widely practiced testing strategies, including ASTM methods, as well as novel procedures for micro-analysis of corrosion were discussed. Various coatings and linings, including polymers and ceramics, were introduced. The prevailing recommendations for testing included keeping the testing simple until the problem warranted a more detailed approach and developing standardized testing procedures to ensure the data was reproducible and applicable. The need to evaluate currently available materials such as coatings/linings, carbon/stainless steels, or fiberglass reinforced plastic was emphasized. It was agreed that economic evaluation of each material candidate must be an integral part of any research plan.

  8. Comparisons of processes and performance of SSC-VQP material

    SciTech Connect

    Seuntjens, J.; Clark, F.; Erdmann, M.; Coleman, E.; Jones, B.

    1993-05-01

    The Superconducting Super Collider's (SSC) cable Vendor Qualification Program (VQP) will end in FY 1993. At the time of this writing, all 8 vendors involved in this program have demonstrated capability to fabricate conductor which meets SSC specifications. The magnet vendors have hard choices to make in calendar year 1993 in deciding which cable vendors will make the production cable. It is well accepted that because of requirements of magnet uniformity, that only one vendor will be chosen for dipole Inner cable, one vendor for dipole Outer cable, and one vendor for quadrupole Outer cable. The production quantities are nominally 500, 500, and 200 metric tonnes, respectively. Among the many deciding factors are a technically sound production process, process control, and production quantity capability of each cable vendor. Qualified vendors will have proven their technical process and process control is adequate for production quantities. This paper is part of ongoing effort to provide technical information for the magnet vendor's decision making process. Some of the Phase IB process data is summarized and well as results of a portion of the materials characterization performed at the SSC Laboratory. Key process and final product parameters for each cable vendor are compared without identifying specific vendor's process detail.

  9. Process for stabilizing the viscosity characteristics of coal derived materials and the stabilized materials obtained thereby

    DOEpatents

    Bronfenbrenner, James C.; Foster, Edward P.; Tewari, Krishna

    1985-01-01

    A process is disclosed for stabilizing the viscosity of coal derived materials such as an SRC product by adding up to 5.0% by weight of a light volatile phenolic viscosity repressor. The viscosity will remain stabilized for a period of time of up to 4 months.

  10. Development of Optical Diagnostic Techniques for Microgravity Materials Processing

    NASA Technical Reports Server (NTRS)

    Cha, Soyoung Stephen

    1999-01-01

    Materials processing including crystal growth, either under a gravity environment on ground or a microgravity environment in space, involves complicated phenomena of fluid motions in gas or liquid phases as well as interaction of various species. To obtain important physical insight, it is very necessary to provide gross-field optical diagnostics for monitoring various physical properties. Materials processing inhibits easy access by ordinary instruments and thus characterizing gross-field physical properties is very challenging. Typical properties of importance can be fluid velocity, temperature, and species concentration for fluids, and surface topology and defects for solids. Observing surface grow rate during crystal growth is also important. Material microstructures, i.e., integrity of crystal structures, is strongly influenced by the existence of thermally-induced flow as well as local nucleation of particles during solidification, which may act in many detrimental ways. In both ground-based and microgravity experiments, the nature of product property changes resulting from three-dimensional fluid or particle motions need be characterized. Gross-field diagnostics is thus required to identify their effects on product defects and process deficiencies. The quantitative visualization techniques can also be used for validation of numerical modeling. For optical nonintrusive gross-field diagnostic techniques, two approaches were developed as summer projects. One optical approach allows us to provide information of species concentration and temperature for monitoring in real time. The other approach, that is, the concept which is formulated for detection of surface topography measurement can provide unprecedented spatial resolution during crystal growth.

  11. Molecular basis of processing wheat gluten toward biobased materials.

    PubMed

    Lagrain, Bert; Goderis, Bart; Brijs, Kristof; Delcour, Jan A

    2010-03-01

    The unique properties of the wheat grain reside primarily in the gluten-forming storage proteins of its endosperm. Wheat gluten's structural and functional properties have led to an expanding diversity of applications in food products. However, its viscoelastic properties and low water solubility also are very interesting features for nonfood applications. Moreover, gluten is annually renewable and perfectly biodegradable. In the processing and setting of gluten containing products, temperature plays a very important role. In this review, the structure and reactivity of gluten are discussed and the importance of sulfhydryl (SH) and disulfide (SS) groups is demonstrated. Wheat gluten aggregation upon thermosetting proceeds through direct covalent cross-linking in and between its protein groups, glutenin and gliadin. Predominant reactions include SH oxidation and SH/SS interchange reactions leading to the formation of SS cross-links. Additionally, thermal treatment of gluten can result in the formation of other than SS covalent bonds. We here review two main technological approaches to make gluten-based materials: wet processes resulting in thin films and dry processes, such as extrusion or compression molding, exploiting the thermoplastic properties of proteins under low moisture conditions and potentially resulting in very useful materials. Gluten bioplastics can also be reinforced with natural fibers, resulting in biocomposites. Although a lot of progress has been made the past decade, the current gluten materials are still outperformed by their synthetic polymer counterparts. PMID:20141101

  12. Kilowatt average-power laser for subpicosecond materials processing

    NASA Astrophysics Data System (ADS)

    Benson, Stephen V.; Neil, George R.; Bohn, Courtlandt L.; Biallas, George; Douglas, David; Dylla, H. Frederick; Fugitt, Jock; Jordan, Kevin; Krafft, Geoffrey; Merminga, Lia; Preble, Joe; Shinn, Michelle D.; Siggins, Tim; Walker, Richard; Yunn, Byung

    2000-04-01

    The performance of laser pulses in the sub-picosecond range for materials processing is substantially enhanced over similar fluences delivered in longer pulses. Recent advances in the development of solid state lasers have progressed significantly toward the higher average powers potentially useful for many applications. Nonetheless, prospects remain distant for multi-kilowatt sub-picosecond solid state systems such as would be required for industrial scale surface processing of metals and polymers. We present operation results from the world's first kilowatt scale ultra-fast materials processing laser. A Free Electron Laser (FEL) called the IR Demo is operational as a User Facility at Thomas Jefferson National Accelerator Facility in Newport News, Virginia, USA. In its initial operation at high average power it is capable of wavelengths in the 2 to 6 micron range and can produce approximately 0.7 ps pulses in a continuous train at approximately 75 MHz. This pulse length has been shown to be nearly optimal for deposition of energy in materials at the surface. Upgrades in the near future will extend operation beyond 10 kW CW average power in the near IR and kilowatt levels of power at wavelengths from 0.3 to 60 microns. This paper will cover the design and performance of this groundbreaking laser and operational aspects of the User Facility.

  13. Development of Processing Techniques for Advanced Thermal Protection Materials

    NASA Technical Reports Server (NTRS)

    Selvaduray, Guna; Cox, Michael; Srinivasan, Vijayakumar

    1997-01-01

    Thermal Protection Materials Branch (TPMB) has been involved in various research programs to improve the properties and structural integrity of the existing aerospace high temperature materials. Specimens from various research programs were brought into the analytical laboratory for the purpose of obtaining and refining the material characterization. The analytical laboratory in TPMB has many different instruments which were utilized to determine the physical and chemical characteristics of materials. Some of the instruments that were utilized by the SJSU students are: Scanning Electron Microscopy (SEM), Energy Dispersive X-ray analysis (EDX), X-ray Diffraction Spectrometer (XRD), Fourier Transform-Infrared Spectroscopy (FTIR), Ultra Violet Spectroscopy/Visible Spectroscopy (UV/VIS), Particle Size Analyzer (PSA), and Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES). The above mentioned analytical instruments were utilized in the material characterization process of the specimens from research programs such as: aerogel ceramics (I) and (II), X-33 Blankets, ARC-Jet specimens, QUICFIX specimens and gas permeability of lightweight ceramic ablators. In addition to analytical instruments in the analytical laboratory at TPMB, there are several on-going experiments. One particular experiment allows the measurement of permeability of ceramic ablators. From these measurements, physical characteristics of the ceramic ablators can be derived.

  14. A coal-fired combustion system for industrial processing heating applications. Quarterly technical progress report, January 1995--March 1995

    SciTech Connect

    1995-04-01

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a {open_quotes}Coal-Fired Combustion System for Industrial Process Heating Applications{close_quotes} is a project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. The test program consisted of one test run, with a duration of 100 hours at a nominal feed rate of 1000 lbs/hr. Throughout the test, the CMS was fired with coal and a coal by-product (i.e. coal-fired boiler fly ash) as the primary fuels. Natural gas was used as an auxiliary fuel as necessary to provide process trim. The feedstock consisted of a coal-fired utility boiler fly ash and dolomite and produced a stable, fully-reacted vitrified product. The fly ash, supplied by PENELEC, contained between 6 and 12% by weight of carbon because of the low NOx burners on the PENELEC boilers. Therefore, a substantial portion of the required thermal input came from the fly ash.

  15. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1992--June 1992

    SciTech Connect

    Not Available

    1992-09-03

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a ``Coal-Fired Combustion System for Industrial Process Heating Applications`` is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelling and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, approval of Vortec`s Environmental Assessment (EA) required under the National Environmental Policy Act (NEPA) was approved. The EA approval cycle took approximately 9 months. The preliminary test program which was being held in abeyance pending approval of the EA was initiated. Six preliminary test runs were successfully competed during the period. Engineering and design activities in support of the Phase III proof of concept are continuing, and modifications to the existing test system configuration to allow performance of the preliminary tests were completed.

  16. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, October 1--December 31, 1995

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1996-05-01

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. During this reporting period, CONSOL completed analyses of 81 feed and process stream samples from HTI bench Run CMSL-9. HTI liquefaction bench unit Run CMSL-9 (227-87) was operated with all-dispersed catalyst and Black Thunder Mine (Wyodak and Anderson seam) coal, with and without mixed plastics or high density polyethylene (HDPE) as coprocessing feedstocks. The dispersed catalysts used were Molyvan A and HTI`s iron catalyst, a sulfated iron hydroxide. Results are discussed in this report.

  17. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, July 1993--September 1993

    SciTech Connect

    Not Available

    1994-01-30

    The Pittsburgh Energy Technology Center (PETC) of the US Department of Energy awarded Vortec Corporation this Phase III contract (No. DE-AC22-91PC91161) for the development of {open_quotes}A Coal-Fired Combustion System for Industrial Process Heating Applications{close_quotes}. The effective contrast start date was September 3, 1991. The contract period of performance is 36 months. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. Final detailed installation designs for the integrated test system configuration are being completed. The equipment is being fabricated and deliveries have begun. The industry funded testing consisted of vitrifying Spent Aluminum Potliner (SPL) which is a listed hazardous waste. This testing has verified that SPL can be vitrified into a safe recyclable glass product.

  18. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, January 1, 1996--March 31, 1996

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1996-07-01

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. This project builds on work performed in DOE Contract No. DE-AC22-89PC89883. Independent analyses by well-established methods are obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently under utilized for the purpose of examining coal-derived samples are being evaluated. The data obtained from this study is used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank, established and maintained for use in this project, is available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) is being examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction.

  19. Material modeling for multistage tube hydroforming process simulation

    NASA Astrophysics Data System (ADS)

    Saboori, Mehdi

    The Aerospace industries of the 21st century demand the use of cutting edge materials and manufacturing technology. New manufacturing methods such as hydroforming are relatively new and are being used to produce commercial vehicles. This process allows for part consolidation and reducing the number of parts in an assembly compared to conventional methods such as stamping, press forming and welding of multiple components. Hydroforming in particular, provides an endless opportunity to achieve multiple crosssectional shapes in a single tube. A single tube can be pre-bent and subsequently hydroformed to create an entire component assembly instead of welding many smaller sheet metal sections together. The knowledge of tube hydroforming for aerospace materials is not well developed yet, thus new methods are required to predict and study the formability, and the critical forming limits for aerospace materials. In order to have a better understanding of the formability and the mechanical properties of aerospace materials, a novel online measurement approach based on free expansion test is developed using a 3D automated deformation measurement system (AramisRTM) to extract the coordinates of the bulge profile during the test. These coordinates are used to calculate the circumferential and longitudinal curvatures, which are utilized to determine the effective stresses and effective strains at different stages of the tube hydroforming process. In the second step, two different methods, a weighted average method and a new hardening function are utilized to define accurately the true stress-strain curve for post-necking regime of different aerospace alloys, such as inconel 718 (IN 718), stainless steel 321 (SS 321) and titanium (Ti6Al4V). The flow curves are employed in the simulation of the dome height test, which is utilized for generating the forming limit diagrams (FLDs). Then, the effect of stress triaxiality, the stress concentration factor and the effective plastic

  20. Scale-up of miscible flood processes for heterogeneous reservoirs. Quarterly report, April 1, 1994--June 30, 1994

    SciTech Connect

    Orr, F.M. Jr.

    1994-07-01

    The current project is a systematic research effort to quantify relationships between process mechanisms that can lead to improved recovery from gas injection processes performed in heterogeneous Class 1 and Class 2 reservoirs. It will provide a rational basis for the design of displacement processes that take advantage of crossflow due to capillary, gravity and viscous forces to offset partially the adverse effects of heterogeneity. In effect, the high permeability zones are used to deliver fluid by crossflow to zones that would otherwise be flooded only very slowly. Thus, the research effort is divided into five areas: (a) Development of miscibility in multicomponent systems, (b) Design estimates for nearly miscible displacements, (c) Design of miscible floods for fractured reservoirs (d), Compositional flow visualization experiments, and (e) Simulation of near-miscible flow in heterogeneous systems. The status of the research effort in each area is reviewed briefly in the following section.

  1. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, July 1992--September 1992

    SciTech Connect

    Not Available

    1992-10-30

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashesand industrial wastes. ne primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order toevaluate its potential marketability. During the current reporting period, three preliminary coal-fired tests were successfully completed. These tests used industrial boiler flyash, sewer sludge ash, and waste glass collet as feedstocks. The coal-fired ash vitrification tests are considered near term potential commercial applications of the CMS technology. The waste glass cullet provided necessary dam on the effect of coal firing with respect to vitrified product oxidation state. Engineering and design activities in support of the Phase III proof of concept are continuing, and modifications to the existing test system configuration to allow performance of the proof-of-concept tests are continuing. The economic evaluation of commercial scale CMS processes is continuing. Preliminary designs for 15, 25, 100 and 400 ton/day systems are in progress. This dam will serve as input data to the life cycle cost analysis which will be-an integral part of the CMS commercialization plan.

  2. Development of enhanced sulfur rejection processes. Second quarterly technical progress report, January 1, 1993--March 31, 1993

    SciTech Connect

    Yoon, R.H.; Luttrell, G.; Adel, G.; Richardson, P.E.

    1993-06-14

    Research at Virginia Tech led to the development of two complementary concepts for improving the removal of inorganic sulfur from many eastern US coals. These concepts are referred to as Electrochemically Enhanced Sulfur Rejection (EESR) and Polymer Enhanced Sulfur Rejection (PESR). The EESR process uses electrochemical techniques to suppress the formation of hydrophobic oxidation products believed to be responsible for the floatability of coal pyrite. The PESR process uses polymeric reagents that react with pyrite and convert floatable middlings, i.e., composite particles composed of pyrite with coal inclusions, into hydrophilic particles. These new pyritic-sulfur rejection processes do not require significant modifications to existing coal preparation facilities, thereby enhancing their adoptability by the coal industry. It is believed that these processes can be used simultaneously to maximize the rejection of both well-liberated pyrite and composite coal-pyrite particles. The technical research was initiated on October 1, 1992, and a detailed work plan and work schedule were developed. During this reporting period, research was conducted to evaluate the liberation characteristics of various pyrite samples, to determine the electrochemical reactions that influence the hydrophobicity of pyrite, and to examine the potential use of electrochemical methods for controlling the flotation and depression of pyrite.

  3. Development of automated welding process for field fabrication of thick walled pressure vessels. Fourth quarter, FY 1980

    SciTech Connect

    Not Available

    1980-12-19

    Progress is reported in research on the automated welding of heavy steel plate for the fabrication of pressure vessels. Information is included on: torch and shield adaptation; mechanical control of the welding process; welding parameters; joint design; filler wire optimizaton; nondestructive testing of welds; and weld repair. (LCL)

  4. Field study of disposed wastes from advanced coal processes. Quarterly technical progress report: April--June 1993

    SciTech Connect

    Not Available

    1993-12-31

    The Department of Energy/Morgantown Energy Technology Center (DOE/METC) has initiated research on the disposal of solid wastes from advanced coal processes. The objective of this research is to develop information to be used by private industry and government agencies for planning waste disposal practices associated with advanced coal processes. To accomplish this objective, DOE has contracted Radian Corporation and the North Dakota Energy & Environmental Research Center (EERC) to design, construct, and monitor a limited number of field disposal tests with advanced coal process wastes. These field tests will be monitored over a three year period with the emphasis on collecting data on the field disposal of these wastes. There has been considerable research on the characteristics and laboratory leaching behavior of coal wastes -- a lesser amount on wastes from advanced coal processes. However, very little information exists on the field disposal behavior of these wastes. Information on field disposal behavior is needed (a) as input to predictive models being developed, (b) as input to the development of rule of thumb design guidelines for the disposal of these wastes, and (c) as evidence of the behavior of these wastes in the natural environment.

  5. Powder processing of nitrides (excluding hot isostatic processing). (Latest citations from Engineered Materials abstracts). Published Search

    SciTech Connect

    1996-02-01

    The bibliography contains citations concerning the properties and processing of metal nitride ceramics and refractories. Citations consider compacting and sintering processes. Phase transformations, crystallization, and devitrification processes are considered. Aluminum nitride, boron nitride, silicon nitride, silicon oxynitride, and titanium nitride are among materials discussed. The use of hot isostatic pressing is considered in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  6. System design considerations for free-fall materials processing

    NASA Technical Reports Server (NTRS)

    Seidensticker, R. G.

    1974-01-01

    The design constraints for orbiting materials processing systems are dominated by the limitations of the flight vehicle/crew and not by the processes themselves. Although weight, size and power consumption are all factors in the design of normal laboratory equipment, their importance is increased orders of magnitude when the equipment must be used in an orbital facility. As a result, equipment intended for space flight may have little resemblance to normal laboratory apparatus although the function to be performed may be identical. The same considerations influence the design of the experiment itself. The processing requirements must be carefully understood in terms of basic physical parameters rather than defined in terms of equipment operation. Preliminary experiments and analysis are much more vital to the design of a space experiment than they are on earth where iterative development is relatively easy. Examples of these various considerations are illustrated with examples from the M518 and MA-010 systems. While these are specific systems, the conclusions apply to the design of flight materials processing systems both present and future.

  7. Materials and Process Activities for NASA's Composite Crew Module

    NASA Technical Reports Server (NTRS)

    Polis, Daniel L.

    2012-01-01

    In January 2007, the NASA Administrator and Associate Administrator for the Exploration Systems Mission Directorate chartered the NASA Engineering and Safety Center (NESC) to design, build, and test a full-scale Composite Crew Module (CCM). The overall goal of the CCM project was to develop a team from the NASA family with hands-on experience in composite design, manufacturing, and testing in anticipation of future space exploration systems being made of composite materials. The CCM project was planned to run concurrently with the Orion project s baseline metallic design within the Constellation Program so that features could be compared and discussed without inducing risk to the overall Program. The materials and process activities were prioritized based on a rapid prototype approach. This approach focused developmental activities on design details with greater risk and uncertainty, such as out-of-autoclave joining, over some of the more traditional lamina and laminate building block levels. While process development and associated building block testing were performed, several anomalies were still observed at the full-scale level due to interactions between process robustness and manufacturing scale-up. This paper describes the process anomalies that were encountered during the CCM development and the subsequent root cause investigations that led to the final design solutions. These investigations highlight the importance of full-scale developmental work early in the schedule of a complex composite design/build project.

  8. A calcium oxide sorbent process for bulk separation of carbon dioxide. Quarterly progress report, October--December 1991

    SciTech Connect

    Silaban, A.; Narcida, M.; Harrison, D.P.

    1992-02-01

    The expected commercialization of coal gasification technology in the US and world-wide will create a need for advanced gas purification and separation processes capable of operating at higher temperatures and in more hostile environments than is common today. For example, a high-temperature, high-pressure process capable of separating CO{sub 2} from coal-derived gas may find application in purifying synthesis gas for H{sub 2}, NH{sub 3}, or CH{sub 3}OH production. High temperature CO{sub 2} removal has the potential for significantly improving the operating efficiency of integrated gasification-molten carbonate fuel cells for electric power generation. This study proved the technical feasibility of a CO{sub 2}-separation process based upon the regenerable noncatalytic gas-solid reaction between CaO and CO{sub 2} to form CACO{sub 3}. Such a process operating at 650{degree}C and 15 atm with 15% CO{sub 2} in the coal gas has the potential for removing in excess of 99% of the CO{sub 2} fed. Selection of a sorbent precursor which, upon calcination, produces high-porosity CaO is important for achieving rapid and complete reaction. The addition of magnesium to the sorbent appears to improve the multicycle durability at a cost of reduced CO{sub 2} capacity per unit mass of sorbent. Reaction conditions, principally calcination and carbonation temperatures, are important factors in multicycle durability. Reaction pressure and CO{sub 2} concentration are important in so far as the initial rapid reaction rate is concerned, but are relatively unimportant in terms of sorbent capacity and durability. Indirect evidence for the simultaneous occurrence of the shift reaction and CO{sub 2}-removal reaction creates the possibility of a direct one-step process for the production of hydrogen from coal-derived gas.

  9. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, October 1992--December 1992

    SciTech Connect

    Not Available

    1993-01-29

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashesand industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, a majority of the effort was spent relining the separator/reservoir and the cyclone melter. The relinings were completed, the cyclonemelter was reinstalled, and the test system was returned to operational status. The wet ESP was delivered and placed on its foundation. The focus during the upcoming months will be completing the integration ofthe wet ESP and conducting the first industrial proof-of-concept test. The other system modifications are well underway with the designs of the recuperator installation and the batch/coal feed system progressing smoothly. The program is still slightly behind the original schedule but it is anticipated that it will be back on schedule by the end of the year. The commercialization planning is continuing with the identification of seven potential near-term commercial demonstration opportunities.

  10. Scale-up of miscible flood processes for heterogeneous reservoirs. Quarterly report, 1 January--31 March 1994

    SciTech Connect

    Orr, F.M. Jr.

    1994-04-01

    The current project is a systematic research effort aimed at quantifying relationships between process mechanisms that can lead to improved recovery from gas injection processes performed in heterogeneous Class 1 and Class 2 reservoirs. It will provide a rational basis for the design of displacement processes that take advantage of crossflow due to capillary, gravity and viscous forces to offset partially the adverse effects of heterogeneity. In effect, the high permeability zones are used to deliver fluid by crossflow to zones that would otherwise be flooded only very slowly. Thus, the research effort is divided into five areas: Development of miscibility in multicomponent systems; design estimates for nearly miscible displacements; design of miscible floods for fractured reservoirs; compositional flow visualization experiments; simulation of near-miscible flow in heterogeneous systems. The status of the research effort in each area is reviewed briefly in the following section. From this work, we can make the following conclusions: (1) We demonstrated theoretically and experimentally that a linear combination of gravity and viscous forces can be used to correlate residual nonwetting phase saturations for both gravity-favorable and gravity-unfavorable displacements. (2) When gravity forces are comparable to or larger than the viscous forces) gravity unfavorable displacements have significantly higher residual nonwetting phase saturation than gravity-favorable displacements. (3) Because soils have much higher permeabilities than oil reservoirs, gravity effects on residual nonwetting phase saturations are much more significant in spilled-oil clean-up than in oil recovery processes. (4) The effective correlation length for a percolation process can be related to a linear combination of the gravity and viscous forces.

  11. Materials processing in space programs tasks. [NASA research tasks

    NASA Technical Reports Server (NTRS)

    Pentecost, E.

    1981-01-01

    Active research tasks as of the end of fiscal year 1981 of the materials processing in space program, NASA Office of Space and Terrestrial Applications are summarized to provide an overview of the program scope for managers and scientists in industry, university, and government communities. The program, its history, strategy, and overall goal are described the organizational structures and people involved are identified and a list of recent publications is given for each research task. Four categories: Crystal Growth; Solidification of Metals, Alloys, and Composites; Fluids, Transports, and Chemical Processes, and Ultrahigh Vacuum and Containerless Processing Technologies are used to group the tasks. Some tasks are placed in more than one category to insure complete coverage of each category.

  12. Applying commercial robotic technology to radioactive material processing

    SciTech Connect

    Grasz, E.L. ); Sievers, R.H. Jr. )

    1990-11-01

    The development of robotic systems for glove box process automation is motivated by the need to reduce operator radiation dosage, minimize the generation of process waste, and to improve the security of nuclear materials. Commercial robotic systems are available with the required capabilities but are not compatible with a glove box environment. Alpha radiation, concentrated dust, a dry atmosphere and restricted work space result in the need for unique adaptations to commercial robotics. Implementation of these adaptations to commercial robotics require performance trade-offs. A design and development effort has been initiated to evaluate the feasibility of using a commercial overhead gantry robot for glove box processing. This paper will present the initial results and observations for this development effort. 1 ref.

  13. MATERIAL PROCESSING FOR SELF-ASSEMBLING MACHINE SYSTEMS

    SciTech Connect

    K. LACKNER; D. BUTT; C. WENDT

    1999-06-01

    We are developing an important aspect of a new technology based on self-reproducing machine systems. Such systems could overcome resource limitations and control the deleterious side effects of human activities on the environment. Machine systems capable of building themselves promise an increase in industrial productivity as dramatic as that of the industrial revolution. To operate successfully, such systems must procure necessary raw materials from their surroundings. Therefore, next to automation, most critical for this new technology is the ability to extract important chemicals from readily available soils. In contrast to conventional metallurgical practice, these extraction processes cannot make substantial use of rare elements. We have designed a thermodynamically viable process and experimentally demonstrated most steps that differ from common practice. To this end we had to develop a small, disposable vacuum furnace system. Our work points to a viable extraction process.

  14. Novel cost controlled materials and processing for primary structures

    NASA Technical Reports Server (NTRS)

    Dastin, S. J.

    1993-01-01

    Textile laminates, developed a number of years ago, have recently been shown to be applicable to primary aircraft structures for both small and large components. Such structures have the potential to reduce acquisition costs but require advanced automated processing to keep costs controlled while verifying product reliability and assuring structural integrity, durability and affordable life-cycle costs. Recently, resin systems and graphite-reinforced woven shapes have been developed that have the potential for improved RTM processes for aircraft structures. Ciba-Geigy, Brochier Division has registered an RTM prepreg reinforcement called 'Injectex' that has shown effectivity for aircraft components. Other novel approaches discussed are thermotropic resins producing components by injection molding and ceramic polymers for long-duration hot structures. The potential of such materials and processing will be reviewed along with initial information/data available to date.

  15. Development of a gas-promoted oil agglomeration process. Quarterly technical progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    Wheelock, T.D.

    1995-12-31

    The preliminary laboratory-scale development of a gas-promoted, oil agglomeration process for cleaning coal advanced in three major research areas. One area of research resulted in the development of a method for measuring the rate of agglomeration of dilute particle suspensions and using the method to relate the rate of agglomeration of coal particles to various key parameters. A second area of research led to the development of a method for monitoring a batch agglomeration process by measuring changes in agitator torque. With this method it was possible to show that the agglomeration of a concentrated coal particle suspension is triggered by the introduction of a small amount of gas. The method was also used in conjunction with optical microscopy to study the mechanism of agglomeration. A third area of research led to the discovery that highly hydrophobic particles in an aqueous suspension can be agglomerated by air alone.

  16. Materials processing research opportunities in powder injection molding

    SciTech Connect

    German, R.M.

    1995-12-31

    Materials processing is an active area with many research opportunities for advanced instrumentation, control, and modeling. Among new materials processing routes, powder injection molding (PIM) has rapidly grown from a curiosity to a viable production technique over just a few years. This manufacturing technique is applicable to all materials, and is the preferred fabrication route for many complex-shaped, high-performance components for surgical tools, computer hardware, automotive systems, consumer products, and turbine components. This presentation introduces the use of a computer controlled injection molding machine to shape powders (metal, carbide, composite, and ceramic) in a high productivity setting. After molding the organic is extracted and the powder structure is sintered to full density. Much research is needed in process modeling, control, inspection, and optimization. This presentation summarizes the basic technology and several important factors relevant to manufacturing. An important development is in minimization of molding defects via closed-loop feedback control using pressure, temperature, and optical sensors. Recent progress has occurred using in situ guided waves for ultrasonic inspection of the molded part. Neural networks are being generated to allow assessment of processing changes as required from the integrated robot, visual imaging, pressure, and ultrasonic sensors. Similar, but less refined efforts are occurring in die compaction technology. As another example, computer simulation of heat transfer is needed during sintering to understand sources of component warpage during densification. A furnace equipped with visual imaging and residual gas analysis is being used to assist in verification of such computer simulations. These tools are still in the research stage, so future integration into the manufacturing environment will bring new challenges.

  17. Microwave Processing for Advance Electro-Optic Materials

    SciTech Connect

    Boatner, L.A.

    2000-06-01

    This project addressed the technical and scientific goals of developing new methods for the formation of striation-free single crystals of potassium tantalate niobate. This solid-solution system has the potential for serving as a general electro-optic material with a wide range of optical applications. The performance of the material is, however, severely limited by the effects of compositional inhomogeneity that is generally induced during the single crystal growth process due to the nature of the binary phase diagram of the mixed tantalatehiobate system. Single-crystal boules of potassium tantalate niobate (KTa{sub 1-x}Nb{sub x}O{sub 3} or KTN) with varying tantalum-to-niobium ratios (or values of x) were grown under a variety of experimental conditions. The resulting single crystals were characterized in terms of their compositional homogeneity and optical quality. Single crystals were grown using both the most-favorable established set of growth parameters as well as in the presence of programmed oscillatory temperature variations. The purpose of these deliberately induced variations was to introduce controlled compositional variations and associated optical striations in the solid-solution single crystals. The overall objective of the effort was to utilize microwave heating and processing methods to treat the inhomogeneous single crystals for the purpose of eliminating the compositional variations that lead to striations and the associated varying changes in the refractive index of the material. In order to realize the ultimate goal of the effort, it was necessary to develop methods that would lead to the effective coupling of the microwave field to the KTN single crystals. Achieving the technical and commercial goals of this effort would have made it possible to introduce an important new electro-optic product into the market place, to improve our fundamental understanding of solid-state diffusion processes in general (and of microwave-assisted thermal

  18. A calcium oxide sorbent process for bulk separation of carbon dioxide. Quarterly progress report No. 12, July 1992--September 1992

    SciTech Connect

    Harrison, D.P.

    1992-10-01

    Objective is to investigate the feasibility of a high-temperature, high-pressure process for bulk separation of CO{sub 2} from coal- derived gas. An electrobalance reactor was used in Phase I; in Phase II, the switch was made to a fixed-bed reactor with capability for feed and product gas analysis. A gas chromatograph was delivered, installed, and operator training carried out. The sampling valve sequence is discussed.

  19. Enhanced control of mercury and other HAPs by innovative modifications to wet FGD processes. First quarter 1996 technical progress report

    SciTech Connect

    Carey, T.R.; Hargrove, O.W.

    1996-06-03

    The overall objective of this project is to learn more about controlling emissions of hazardous air pollutants (HAPs) from coal- fired power plants that are equipped with wet flue gas desulfurization (FGD) systems. This project focuses on three research areas: (1) catalytic oxidation of vapor-phase elemental mercury, (2) enhanced particulate-phase HAPs removal by electrostatic charging of liquid droplets, and (3) enhanced mercury removal by additional of additives to FGD process liquor.

  20. Field study of disposed wastes from advanced coal processes. Quarterly technical progress report, January to April 1994

    SciTech Connect

    Not Available

    1994-06-01

    The Department of Energy/Morgantown Energy Technology Center (DOE/METC) has initiated research on the disposal solid processes. The objective of this research is to develop information to be used by private industry and government agencies for planning waste disposal practices associated with advanced coal processes. To accomplish this objective, DOE has contracted Radian Corporation and the North Dakota Energy & Environmental Research Center (EERC) to design, construct, and monitor a limited number of field disposal tests with advanced coal process wastes. These field tests will be monitored over a three year period with the emphasis on collecting data on the field disposal of these wastes. Information on field disposal behavior is needed (a) as input to predictive models being developed, (b) as input to the development of rule of thumb design guidelines for the disposal of these wastes, and (c) as evidence of the behavior of these wastes in the natural environment.This study is organized into four major Tasks. Task 1 and 2 were devoted to planning the Task 3 field study. Task 4 uses the results of the field testing to produce an Engineering Design Manual for the utilities and industrial users who manage wastes from advanced coal combustion technologies.