Graphene/Poly(aniline-co-pyrrole) Nanocomposite: Potential Candidate for Supercapacitor and Microwave Absorbing Applications.

PubMed

Sahoo, Sumanta; Bhattacharya, Pallab; Dhibar, Saptarshi; Hatui, Goutam; Das, Tanya; Das, Chapal Kumar

2015-09-01

A simple and cost-effective in-situ chemical route to prepare the nanocomposites based on graphene and Poly(aniline-co-pyrrole) [PPP] has been proposed. Introduction of graphene changes the morphology of copolymer from spherical to fiber like. Graphene/Poly(aniline-co-pyrrole) [GPPP] nanocomposite achieved highest specific capacitance of 351 F/g and energy density of 124.8 Wh/Kg at 10 mV/s scan rate. The composite also obtained moderate specific capacitance retention of 66% after 500 cycles, which establish its potentiality as supercapacitor electrode materials. The composite also exhibited high electrical conductivity and superior microwave absorbing properties (maximum reflection loss is -29.97 dB). The absorption range corresponding to ≥ 90% absorption (or -10 dB) is 2.72 GHz which is excellent for the microwave absorbing applications.

Determination of 2-isovaleryl-1,3-indandione with 2, 4-dinitro-phenylhydrazine

USGS Publications Warehouse

Menzie, C.M.; Adomaitis, V.A.; Reichel, W.L.

1962-01-01

At present, three 2-alkyl-1,3-indandiones (PMP, pival, and diphacinon) are widely used as rodenticides. Because analytical procedures now in use are empirical and do not furnish adequate or positive means for distinguishing among these closely related compounds, studies were undertaken to develop a sensitive and specific method for the determination of PMP. The relation between KCN and the 2,4-dinitrophenylhydrazone of PMP was investigated and shown to be sensitive and specific. A deeply colored solution is produced with an absorption maximum at 540 mu. This solution obeys Beer?s law over a wide range. The molar absorptivity for the developed color was calculated to be 3.0 X 104. This reaction can be used also as a spot test to detect as little as 1 ug. of PMP.

Resonance properties of the biological objects in the RF field

NASA Astrophysics Data System (ADS)

Cocherova, E.; Kupec, P.; Stofanik, V.

2011-12-01

Irradiation of people with electromagnetic fields emitted from miscellaneous devices working in the radio-frequency (RF) range may have influence, for example may affect brain processes. The question of health impact of RF electromagnetic fields on population is still not closed. This article is devoted to an investigation of resonance phenomena of RF field absorption in the models of whole human body and body parts (a head) of different size and shape. The values of specific absorption rate (SAR) are evaluated for models of the different shapes: spherical, cylindrical, realistic shape and for different size of the model, that represents the case of new-born, child and adult person. In the RF frequency region, absorption depends nonlinearly on frequency. Under certain conditions (E-polarization), absorption reaches maximum at frequency, that is called "resonance frequency". The whole body absorption and the resonance frequency depends on many further parameters, that are not comprehensively clarified. The simulation results showed the dependence of the whole-body average SAR and resonance frequency on the body dimensions, as well as the influence of the body shape.

Five-Channel Infrared Laser Absorption Spectrometer for Combustion Product Monitoring Aboard Manned Spacecraft

NASA Technical Reports Server (NTRS)

Briggs, Ryan M.; Frez, Clifford; Borgentun, Carl E.; Bagheri, Mahmood; Forouhar, Siamak; May, Randy D.

2014-01-01

Continuous combustion product monitoring aboard manned spacecraft can prevent chronic exposure to hazardous compounds and also provides early detection of combustion events. As future missions extend beyond low-Earth orbit, analysis of returned environmental samples becomes impractical and safety monitoring should be performed in situ. Here, we describe initial designs of a five-channel tunable laser absorption spectrometer to continuously monitor combustion products with the goal of minimal maintenance and calibration over long-duration missions. The instrument incorporates dedicated laser channels to simultaneously target strong mid-infrared absorption lines of CO, HCl, HCN, HF, and CO2. The availability of low-power-consumption semiconductor lasers operating in the 2 to 5 micron wavelength range affords the flexibility to select absorption lines for each gas with maximum interaction strength and minimal interference from other gases, which enables the design of a compact and mechanically robust spectrometer with low-level sensitivity. In this paper, we focus primarily on absorption line selection based on the availability of low-power single-mode semiconductor laser sources designed specifically for the target wavelength range.

Grazing incidence modeling of a metamaterial-inspired dual-resonance acoustic liner

NASA Astrophysics Data System (ADS)

Beck, Benjamin S.

2014-03-01

To reduce the noise emitted by commercial aircraft turbofan engines, the inlet and aft nacelle ducts are lined with acoustic absorbing structures called acoustic liners. Traditionally, these structures consist of a perforated facesheet bonded on top of a honeycomb core. These traditional perforate over honeycomb core (POHC) liners create an absorption spectra where the maximum absorption occurs at a frequency that is dictated by the depth of the honeycomb core; which acts as a quarter-wave resonator. Recent advances in turbofan engine design have increased the need for thin acoustic liners that are effective at low frequencies. One design that has been developed uses an acoustic metamaterial architecture to improve the low frequency absorption. Specifically, the liner consists of an array of Helmholtz resonators separated by quarter-wave volumes to create a dual-resonance acoustic liner. While previous work investigated the acoustic behavior under normal incidence, this paper outlines the modeling and predicted transmission loss and absorption of a dual-resonance acoustic metamaterial when subjected to grazing incidence sound.

Excited-state absorption and fluorescence dynamics of Er3+:KY3F10

NASA Astrophysics Data System (ADS)

Labbé, C.; Doualan, J. L.; Moncorgé, R.; Braud, A.; Camy, P.

2018-05-01

We report here on a complete investigation of the excited-state absorption and fluorescence dynamics of Er3+ doped KY3F10 single crystals versus dopant concentrations and optical excitation conditions. Radiative and effective (including non-radiative relaxations) emission lifetimes and branching ratios are determined from a Judd-Ofelt analysis of the absorption spectra and via specific fluorescence experiments using wavelength selective laser excitations. Excited-state absorption and emission spectra are registered within seven spectral domains, i.e. 560 nm, 650 nm, 710 nm, 810 nm, 970 nm, 1550 nm and 2750 nm. A maximum gain cross-section of 0.93 × 10-21 cm2 is determined at the potential laser wavelength of 2.801 μm for a population ratio of 0.48. Saturation of fluorescence intensities and variations of population ratios versus pumping rates are registered and confronted with a rate equation model to derive the rates of the most important up-conversion and cross-relaxation energy transfers occurring at high dopant concentrations.

LED Systems Target Plant Growth

NASA Technical Reports Server (NTRS)

2010-01-01

To help develop technologies for growing edible biomass (food crops) in space, Kennedy Space Center partnered with Orbital Technologies Corporation (ORBITEC), of Madison, Wisconsin, through the Small Business Innovation Research (SBIR) program. One result of this research was the High Efficiency Lighting with Integrated Adaptive Control (HELIAC) system, components of which have been incorporated into a variety of agricultural greenhouse and consumer aquarium lighting features. The new lighting systems can be adapted to a specific plant species during a specific growth stage, allowing maximum efficiency in light absorption by all available photosynthetic tissues.

Radiation absorption and optimization of solar photocatalytic reactors for environmental applications.

PubMed

Colina-Márquez, Jose; Machuca-Martínez, Fiderman; Li Puma, Gianluca

2010-07-01

This study provides a systematic and quantitative approach to the analysis and optimization of solar photocatalytic reactors utilized in environmental applications such as pollutant remediation and conversion of biomass (waste) to hydrogen. Ray tracing technique was coupled with the six-flux absorption scattering model (SFM) to analyze the complex radiation field in solar compound parabolic collectors (CPC) and tubular photoreactors. The absorption of solar radiation represented by the spatial distribution of the local volumetric rate of photon absorption (LVRPA) depends strongly on catalyst loading and geometry. The total radiation absorbed in the reactors, the volumetric rate of absorption (VRPA), was analyzed as a function of the optical properties (scattering albedo) of the photocatalyst. The VRPA reached maxima at specific catalyst concentrations in close agreement with literature experimental studies. The CPC has on average 70% higher photon absorption efficiency than a tubular reactor and requires 39% less catalyst to operate under optimum conditions. The "apparent optical thickness" is proposed as a new dimensionless parameter for optimization of CPC and tubular reactors. It removes the dependence of the optimum catalyst concentration on tube diameter and photocatalyst scattering albedo. For titanium dioxide (TiO(2)) Degussa P25, maximum photon absorption occurs at apparent optical thicknesses of 7.78 for CPC and 12.97 for tubular reactors.

Design of Miniaturized Double-Negative Material for Specific Absorption Rate Reduction in Human Head

PubMed Central

Faruque, Mohammad Rashed Iqbal; Islam, Mohammad Tariqul

2014-01-01

In this study, a double-negative triangular metamaterial (TMM) structure, which exhibits a resounding electric response at microwave frequency, was developed by etching two concentric triangular rings of conducting materials. A finite-difference time-domain method in conjunction with the lossy-Drude model was used in this study. Simulations were performed using the CST Microwave Studio. The specific absorption rate (SAR) reduction technique is discussed, and the effects of the position of attachment, the distance, and the size of the metamaterials on the SAR reduction are explored. The performance of the double-negative TMMs in cellular phones was also measured in the cheek and the tilted positions using the COMOSAR system. The TMMs achieved a 52.28% reduction for the 10 g SAR. These results provide a guideline to determine the triangular design of metamaterials with the maximum SAR reducing effect for a mobile phone. PMID:25350398

Design of miniaturized double-negative material for specific absorption rate reduction in human head.

PubMed

Faruque, Mohammad Rashed Iqbal; Islam, Mohammad Tariqul

2014-01-01

In this study, a double-negative triangular metamaterial (TMM) structure, which exhibits a resounding electric response at microwave frequency, was developed by etching two concentric triangular rings of conducting materials. A finite-difference time-domain method in conjunction with the lossy-Drude model was used in this study. Simulations were performed using the CST Microwave Studio. The specific absorption rate (SAR) reduction technique is discussed, and the effects of the position of attachment, the distance, and the size of the metamaterials on the SAR reduction are explored. The performance of the double-negative TMMs in cellular phones was also measured in the cheek and the tilted positions using the COMOSAR system. The TMMs achieved a 52.28% reduction for the 10 g SAR. These results provide a guideline to determine the triangular design of metamaterials with the maximum SAR reducing effect for a mobile phone.

Solvatochromic Effects on the Absorption Spectrum of 2-Thiocytosine

PubMed Central

2017-01-01

The solvatochromic effects of six different solvents on the UV absorption spectrum of 2-thiocytosine have been studied by a combination of experimental and theoretical techniques. The steady-state absorption spectra show significant shifts of the absorption bands, where in more polar solvents the first absorption maximum shifts to higher transition energies and the second maximum to lower energies. The observed solvatochromic shifts have been rationalized using three popular solvatochromic scales and with high-level multireference quantum chemistry calculations including implicit and explicit solvent effects. It has been found that the dipole moments of the excited states account for some general shifts in the excitation energies, whereas the explicit solvent interactions explain the differences in the spectra recorded in the different solvents. PMID:28452483

CALCIUM ABSORPTION IN MAN: BASED ON LARGE VOLUME LIQUID SCINTILLATION COUNTER STUDIES.

PubMed

LUTWAK, L; SHAPIRO, J R

1964-05-29

A technique has been developed for the in vivo measurement of absorption of calcium in man after oral administration of 1 to 5 microcuries of calcium-47 and continuous counting of the radiation in the subject's arm with a large volume liquid scintillation counter. The maximum value for the arm counting technique is proportional to the absorption of tracer as measured by direct stool analysis. The rate of uptake by the arm is lower in subjects with either the malabsorption syndrome or hypoparathyroidism. The administration of vitamin D increases both the absorption rate and the maximum amount of calcium absorbed.

The gas-phase absorption spectrum of a neutral GFP model chromophore.

PubMed

Lammich, L; Petersen, M Axman; Nielsen, M Brøndsted; Andersen, L H

2007-01-01

We have studied the gas-phase absorption properties of the green fluorescent protein (GFP) chromophore in its neutral (protonated) charge state in a heavy-ion storage ring. To accomplish this we synthesized a new molecular chromophore with a charged NH(3) group attached to a neutral model chromophore of GFP. The gas-phase absorption cross section of this chromophore molecule as a function of the wavelength is compared to the well-known absorption profile of GFP. The chromophore has a maximum absorption at 415 +/- 5 nm. When corrected for the presence of the charged group attached to the GFP model chromophore, the unperturbed neutral chromophore is predicted to have an absorption maximum at 399 nm in vacuum. This is very close to the corresponding absorption peak of the protein at 397 nm. Together with previous data obtained with an anionic GFP model chromophore, the present data show that the absorption of GFP is primarily determined by intrinsic chromophore properties. In other words, there is strong experimental evidence that, in terms of absorption, the conditions in the hydrophobic interior of this protein are very close to those in vacuum.

Light absorption coefficients by phytoplankton pigments, suspended particles and colored dissolved organic matter in the Crimea coastal water (the Black sea) in June 2016

NASA Astrophysics Data System (ADS)

Moiseeva, N.; Churilova, T.; Efimova, T.; Krivenko, O.; Latushkin, A.

2017-11-01

Variability of the bio-optical properties of the Crimean coastal waters in June 2016 has been analyzed. The type of vertical distribution chlorophyll a concentration and phytoplankton light absorption coefficients and spectra shape differed between shallow and deeper water. In the deeper water seasonal stratification divided euphotic zone into layers with different environmental conditions. In the deeper part of the euphotic zone (below the thermocline) phytoplankton absorption spectra had local maximum at 550 nm, which was likely to be associated with high abundance of cyanobacteria (Synechococcus sps.) in the phytoplankton community. The concentration of chlorophyll a specific light absorption coefficient of phytoplankton decreased with depth (especially pronounced in the blue domain of the spectrum). In the shallow water the vertical distributions of all absorption properties were relatively homogeneous due to vertical water mixing. In the shallow water non-algal particles light absorption coefficient and its contribution to total particulate absorption were higher than those in the deeper water. The non-algal particles (NAP) and colored dissolved organic matter (CDOM) light absorption spectra were well described by an exponential function with a slope averaging 0.010 nm-1 (SD = 0.001 nm-1) and 0.022 nm-1 (SD = 0.0060 nm-1), correspondingly. The CDOM absorption at 440 nm and slope coefficient varied significantly across the investigated area, which was possibly associated with the terrestrial influences. The assessment of the contribution of phytoplankton, NAP and CDOM to total light absorption showed that CDOM dominated in the absorption at 440 nm.

Inner filter effect and the onset of concentration dependent red shift of synchronous fluorescence spectra.

PubMed

Tarai, Madhumita; Mishra, Ashok Kumar

2016-10-12

The phenomenon of concentration dependent red shift, often observed in synchronous fluorescence spectra (SFS) of monofluorophoric as well as multifluorophoric systems at high chromophore concentrations, is known to have good analytical advantages. This was previously understood in terms of large inner filter effect (IFE) through the introduction of a derived absorption spectral profile that closely corresponds to the SFS profile. Using representative monofluorophoric and multifluorophoric systems, it is now explained how the SF spectral maximum changes with concentration of the fluorophore. For dilute solutions of monofluorophores the maximum is unchanged as expected. It is shown here that the onset of red shift of SFS maximum of both the mono as well as the multifluorophoric systems must occur at the derived absorption spectral parameter value of 0.32 that corresponds to the absorbance value of 0.87. This value is unique irrespective of the nature of the fluorophore under study. For monofluorophoric systems, the wavelength of derived absorption spectral maximum and the wavelength of synchronous fluorescence spectral maximum closely correspond with each other in the entire concentration range. In contrast, for multifluorophoric systems like diesel and aqueous humic acid, large deviations were noted that could be explained as to be due to the presence of non-fluorescing chromophores in the system. This work bridges the entire fluorophore concentration range over which the red shift of SFS maximum sets in; and in the process it establishes the importance of the derived absorption spectral parameter in understanding the phenomenon of concentration dependent red shift of SFS maximum. Copyright © 2016 Elsevier B.V. All rights reserved.

Remote sensing of particle dynamics: a two-component unmixing model in a western UK shelf sea.

NASA Astrophysics Data System (ADS)

Mitchell, Catherine; Cunningham, Alex

2014-05-01

The relationship between the backscattering and absorption coefficients, in particular the backscattering to absorption ratio, is mediated by the type of particles present in the water column. By considering the optical signals to be driven by phytoplankton and suspended minerals, with a relatively constant influence from CDOM, radiative transfer modelling is used to propose a method for retrieving the optical contribution of phytoplankton and suspended minerals to the total absorption coefficient with mean percentage errors of below 5% for both components. These contributions can be converted to constituent concentrations if the appropriate specific inherent optical properties are known or can be determined from the maximum and minimum backscattering to absorption ratios of the data. Remotely sensed absorption and backscattering coefficients from eight years of MODIS data for the Irish Sea reveal maximum backscattering to absorption coefficient ratios over the winter (with an average for the region of 0.27), which then decrease to a minimum over the summer months (with an average of 0.06) before increasing again through to winter, indicating a change in the particles present in the water column. Application of the two-component unmixing model to this data showed seasonal cycles of both phytoplankton and suspended mineral concentrations which vary in both amplitude and periodicity depending on their location. For example, in the Bristol Channel the amplitude of the suspended mineral concentration throughout one cycle is approximately 75% greater than a yearly cycle in the eastern Irish Sea. These seasonal cycles give an insight into the complex dynamics of particles in the water column, indicating the suspension of sediment throughout the winter months and the loss of sediments from the surface layer over the summer during stratification. The relationship between the timing of the phytoplankton spring bloom and changes in the availability of light in the water column can be studied to gain an understanding into the phytoplankton phenology across the region.

Preparation of Sm-doped ceria (SDC) nanowires and tubes by gas-liquid co-precipitation at room temperature

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gu Lina; School of Chemistry and Chemical Engineering, Anhui University, 230039 Hefei; Meng Guangyao

Sm-doped cerium dioxide (SDC) with fcc structure was formed using a gas-liquid chemical co-precipitation process at room temperature. Morphology and structure of the as-prepared samples were characterized using TG, XRD, TEM, HRTEM and SAED techniques. Under our specific experimental conditions, two kinds of 1D nano-structures SDC have been mainly obtained. SDC nanowires are 0.3-1.2 {mu}m in lengths and 5-20 nm in diameters. SDC nanotubes have outer diameters in 10-40 nm with lengths up to 2 {mu}m. The as-prepared SDC shows very strong UV absorption ability and the maximum absorption peak redshifts compared with that of SDC nanoparticles.

Role of specific activators of intestinal amino acid transport in Bombyx mori larval growth and nutrition.

PubMed

Leonardi, M G; Casartelli, M; Fiandra, L; Parenti, P; Giordana, B

2001-12-01

Nutrient absorption and its modulation are critical for animal growth. In this paper, we demonstrate that leucine methyl ester (Leu-OMe) can greatly increase the activity of the transport system responsible for the absorption of most essential amino acids in the larval midgut of the silkworm Bombyx mori. We investigated leucine uptake activation by Leu-OMe in brush border membrane vesicles and in the apical membrane of epithelial cells in the midgut incubated in vitro. Moreover, the addition of this strong activator of amino acid absorption to diet significantly affected larval growth. Silkworms fed on artificial diet supplemented with Leu-OMe reached maximum body weight 12-18 h before control larvae, and produced cocoon shells up to 20% heavier than those of controls. The activation of amino acid absorption plays an essential role in larval development so that larval growth and cocoon production similar to controls reared on an artificial diet with 25% of dry mulberry leaf powder were observed in silkworms fed on an artificial diet with only 5% of mulberry powder. Arch. Copyright 2001 Wiley-Liss, Inc.

Development and validation of a general derivatization HPLC method for the trace analysis of acyl chlorides in lipophilic drug substances.

PubMed

Zheng, Xiangyuan; Luo, Lan; Zhou, Jie; Ruan, Xiaoling; Liu, Wenyuan; Zheng, Feng

2017-06-05

Acyl chlorides are important acylating agents in the synthesis of active pharmaceutical ingredients. Determining the residual acyl chlorides in drug substances is a challenge due to their high reactivity and the matrix interferences from drug substances and their related impurities. This paper describes a general derivatization HPLC method for the determination of aromatic and aliphatic acyl chlorides in lipophilic drug substances. Since most drug substances have weak absorptions in the visible range (above 380nm), the nitro-substituted anilines and nitro-substituted phenylhydrazines were selected as the derivatization reagents due to their weak basicity and red-shift of UV absorption spectra. The maximum wavelength and absorption intensity of nitro-substituted anilines decreased after derivatization with acyl chlorides, whereas the derivatization products of nitro-substituted phenylhydrazines showed the slight increases of maximum wavelength and absorbance intensity. Hence, 2-nitrophenylhydrazine was selected as the suitable derivatization reagent because the derivatives have the maximum UV wavelength absorbance at 395nm, which could largely minimize the matrix interferences. The optimization of the concentration of 2-nitrophenylhydrazine is important for the sensitivity and stability of derivatives. Other reaction conditions including reaction temperature, time and the influence of three competitive solvents (water, methanol and ethanol) on the reaction efficiency were also studied. After derivatization with 100μgmL -1 2-nitrophenylhydrazine at room temperature for 30min, the method was validated for high specificity and sensitivity with the detection limits in the range of 0.01-0.03μgmL -1 . The proposed method was applied as a generic method to determine the residual acyl chlorides in lipophilic drug substances. Copyright © 2017 Elsevier B.V. All rights reserved.

Comparison of FDTD-calculated specific absorption rate in adults and children when using a mobile phone at 900 and 1800 MHz

NASA Astrophysics Data System (ADS)

Martínez-Búrdalo, M.; Martín, A.; Anguiano, M.; Villar, R.

2004-01-01

In this paper, the specific absorption rate (SAR) in scaled human head models is analysed to study possible differences between SAR in the heads of adults and children and for assessment of compliance with the international safety guidelines, while using a mobile phone. The finite-difference time-domain method (FDTD) has been used for calculating SAR values for models of both children and adults, at 900 and 1800 MHz. Maximum 1 g averaged SAR (SAR1 g) and maximum 10 g averaged SAR (SAR10 g) have been calculated in adults and scaled head models for comparison and assessment of compliance with ANSI/IEEE and European guidelines. Results show that peak SAR1 g and peak SAR10 g all trend downwards with decreasing head size but as head size decreases, the percentage of energy absorbed in the brain increases. So, higher SAR in children's brains can be expected depending on whether the thickness of their skulls and surrounding tissues actually depends on age. The SAR in eyes of different sizes, as a critical organ, has also been studied and very similar distributions for the full size and the scaled models have been obtained. Standard limits can only be exceeded in the unpractical situation where the antenna is located at a very short distance in front of the eye.

Research on disposal of copper(II)-containing wastewater by secondary strontium residue

NASA Astrophysics Data System (ADS)

Qing, Duowen; Xu, Longjun; Cui, Caixi

2018-01-01

Secondary strontium residue (SSR) was used as absorbent to remove Cu2+ in solution and the effects of experimental conditions on absorption of Cu2+ were investigated. The results showed that the absorption process reached balance in around 40 min. The absorption capacity achieved the maximum when PH value reached 6, and the maximum adsorption of Cu2+-containing wastewater by secondary strontium residue was 5.46 mg/g. Removal ratio of Cu2+ was in relation to initial concentration of Cu2+ in solution. Adsorptive process tallied with Langmuir Isothermal adsorption model.

Anomalous absorption of isolated silver nanoparticulate films in visible region of electromagnetic field.

PubMed

Kim, Sang Woo; Hui, Bang Jae; Bae, Dong-Sik

2008-02-01

Anomalous absorption of isolated silver nanoparticulate films with different morphological patterns prepared by the wet colloidal route and followed by thermal treatment were investigated. A polymer embedded silver nanoparticulate film thermally treated at 200 degrees C showed maximum absorbance at approximately 412 nm. The peak position of the surface plasmon band was slightly different but still consistent with theoretical prediction derived by the Mie theory. An isolated nanopariculate film thermally treated at 300 degrees C showed anomalous absorption. Its maximum absorption band was shifted to green regime of 506.9 nm and the bandwidth at half-maximum absorbance of the surface plasmon band was greatly broadened. The plasmon band and its bandwidth were much deviated compared to the theoretical prediction calculated for the silver nanoparticles in the surrounding medium of air and poly(vinyl pyrrolidone) or soda-lime-silica glass. Even though there was no significant growth of silver nanoparticles during thermal treatment at 300 degrees C, the anomalous absorption was observed. The anomalous absorption was not attributed to effects of particle shape and size but to effects of pores induced by development of a great number of pores in the nanoparticulate film. The anomalous absorption greatly decreased with increase in heating temperature from 400 degrees C to 500 degrees C. The extraordinary plasmon damping of the isolated film decreased and the plasmon absorption band was re-shifted to violet regime of 416 nm because of large decrease in size of particles with dramatic change of pore morphology from circular pores with rim to small continuous pores induced by spontaneous formation of new silver nanoparticles.

Dynamical resonance shift and unification of resonances in short-pulse laser-cluster interaction

NASA Astrophysics Data System (ADS)

Mahalik, S. S.; Kundu, M.

2018-06-01

Pronounced maximum absorption of laser light irradiating a rare-gas or metal cluster is widely expected during the linear resonance (LR) when Mie-plasma wavelength λM of electrons equals the laser wavelength λ . On the contrary, by performing molecular dynamics (MD) simulations of an argon cluster irradiated by short 5-fs (FWHM) laser pulses it is revealed that, for a given laser pulse energy and a cluster, at each peak intensity there exists a λ —shifted from the expected λM—that corresponds to a unified dynamical LR at which evolution of the cluster happens through very efficient unification of possible resonances in various stages, including (i) the LR in the initial time of plasma creation, (ii) the LR in the Coulomb expanding phase in the later time, and (iii) anharmonic resonance in the marginally overdense regime for a relatively longer pulse duration, leading to maximum laser absorption accompanied by maximum removal of electrons from cluster and also maximum allowed average charge states for the argon cluster. Increasing the laser intensity, the absorption maxima is found to shift to a higher wavelength in the band of λ ≈(1 -1.5 ) λM than permanently staying at the expected λM. A naive rigid sphere model also corroborates the wavelength shift of the absorption peak as found in MD and unequivocally proves that maximum laser absorption in a cluster happens at a shifted λ in the marginally overdense regime of λ ≈(1 -1.5 ) λM instead of λM of LR. The present study is important for guiding an optimal condition laser-cluster interaction experiment in the short-pulse regime.

Absorption Voltages and Insulation Resistance in Ceramic Capacitors with Cracks

NASA Technical Reports Server (NTRS)

Teverovsky, Alexander

2016-01-01

Time dependence of absorption voltages (Vabs) in different types of low-voltage X5R and X7R ceramic capacitors was monitored for a maximum duration of hundred hours after polarization. To evaluate the effect of mechanical defects on Vabs, cracks in the dielectric were introduced either mechanically or by thermal shock. The maximum absorption voltage, time to roll-off, and the rate of voltage decrease are shown to depend on the crack-related leakage currents and insulation resistance in the parts. A simple model that is based on the Dow equivalent circuit for capacitors with absorption has been developed to assess the insulation resistance of capacitors. Standard measurements of the insulation resistance, contrary to the measurements based on Vabs, are not sensitive to the presence of mechanical defects and fail to reveal capacitors with cracks. Index Terms: Ceramic capacitor, insulation resistance, dielectric absorption, cracking.

Synthesis and evaluation of changes induced by solvent and substituent in electronic absorption spectra of some azo disperse dyes

NASA Astrophysics Data System (ADS)

Mohammadi, Asadollah; Yazdanbakhsh, Mohammad Reza; Farahnak, Lahya

2012-04-01

Five azo disperse dyes were prepared by diazotizing 4'-aminoacetophenone and p-anisidine and coupling with varies N-alkylated aromatic amines. Characterization of the dyes was carried out by using UV-vis, FTIR and 1H NMR spectroscopic techniques. The electronic absorption spectra of dyes are determined at room temperature in fifteen solvents with different polarities. The solvent dependent maximum absorption band shifts, were investigated using dielectric constant (ɛ), refractive index (n) and Kamlet-Taft polarity parameters (hydrogen bond donating ability (α), hydrogen bond accepting ability (β) and dipolarity/polarizability polarity scale (π*)). Acceptable agreement was found between the maximum absorption band of dyes and solvent polarity parameters especially with π*. The effect of substituents of coupler and/or diazo component on the color of dyes was investigated. The effects of acid and base on the visible absorption maxima of the dyes are also reported.

Toward maximum transmittance into absorption layers in solar cells: investigation of lossy-film-induced mismatches between reflectance and transmittance extrema.

PubMed

Chang, Yin-Jung; Lai, Chi-Sheng

2013-09-01

The mismatch in film thickness and incident angle between reflectance and transmittance extrema due to the presence of lossy film(s) is investigated toward the maximum transmittance design in the active region of solar cells. Using a planar air/lossy film/silicon double-interface geometry illustrates important and quite opposite mismatch behaviors associated with TE and TM waves. In a typical thin-film CIGS solar cell, mismatches contributed by TM waves in general dominate. The angular mismatch is at least 10° in about 37%-53% of the spectrum, depending on the thickness combination of all lossy interlayers. The largest thickness mismatch of a specific interlayer generally increases with the thickness of the layer itself. Antireflection coating designs for solar cells should therefore be optimized in terms of the maximum transmittance into the active region, even if the corresponding reflectance is not at its minimum.

Optical tomographic detection of rheumatoid arthritis with computer-aided classification schemes

NASA Astrophysics Data System (ADS)

Klose, Christian D.; Klose, Alexander D.; Netz, Uwe; Beuthan, Jürgen; Hielscher, Andreas H.

2009-02-01

A recent research study has shown that combining multiple parameters, drawn from optical tomographic images, leads to better classification results to identifying human finger joints that are affected or not affected by rheumatic arthritis RA. Building up on the research findings of the previous study, this article presents an advanced computer-aided classification approach for interpreting optical image data to detect RA in finger joints. Additional data are used including, for example, maximum and minimum values of the absorption coefficient as well as their ratios and image variances. Classification performances obtained by the proposed method were evaluated in terms of sensitivity, specificity, Youden index and area under the curve AUC. Results were compared to different benchmarks ("gold standard"): magnet resonance, ultrasound and clinical evaluation. Maximum accuracies (AUC=0.88) were reached when combining minimum/maximum-ratios and image variances and using ultrasound as gold standard.

Fe3O4 nanoparticles decorated MWCNTs @ C ferrite nanocomposites and their enhanced microwave absorption properties

NASA Astrophysics Data System (ADS)

Zhang, Kaichuang; Gao, Xinbao; Zhang, Qian; Chen, Hao; Chen, Xuefang

2018-04-01

Fe3O4 nanoparticles decorated MWCNTs @ C ferrite nanocomposites were synthesized using a co-precipitation method and a calcination process. As one kind absorbing material, we researched the electromagnetic absorption properties of the composites that were mixed with a filler loading of 80 wt% paraffin. In addition, we studied the influence of the magnetic nanoparticle content on the absorbing properties. The results showed that the frequency corresponding to the maximum absorptions shifted to lower frequency when the magnetic nanoparticles content increased. The Fe3O4 nanoparticles decorated MWCNTs @ C ferrite nanocomposites with approximately 60% Fe3O4 nanoparticles showed the best electromagnetic absorption properties. The maximum reflection loss was -52.47 dB with a thickness of 2.0 mm at 10.4 GHz.

Design and chemical synthesis of iodine-containing molecules for application to solar-pumped I* lasers

NASA Technical Reports Server (NTRS)

Shiner, C. S.

1986-01-01

The design and chemical synthesis of new media for solar pumped iodine molecule lasers are explored. In an effort to prepare an iodo fluorocarbon compound absorbing strongly at 300 nm or above, the synthesis of perfluoro allylic iodides was investigated. These compounds furnish especially stable allylic radicals upon photodissociation. The desired red shift is anticipated in the absorption maximum could correlate with increasing radical stability. This expectation was based upon the analysis, previously reported, of the structures and absorption maxima of compounds studied earlier. A previously unknown substance was prepared, a prototypical target molecule, perfluoro-3-iodocyclopent-1-ene. It was obtained by reaction of perfluorocyclopentene with sulfur trioxide under the influence of antimony pentafluoride catalyst, followed by treatment of the resulting allylic fluorosulfonate with sodium iodide in sulfoland solvent. Preliminary data indicate that the absorption maximum for the iodo fluorocarbon is not shifted significantly to longer wavelength. It is not certain whether this result reflects an unexpected influence of the cyclic structure upon the position of the absorption maximum.

Directional power absorption in helicon plasma sources excited by a half-helix antenna

NASA Astrophysics Data System (ADS)

Afsharmanesh, Mohsen; Habibi, Morteza

2017-10-01

This paper deals with the investigation of the power absorption in helicon plasma excited through a half-helix antenna driven at 13.56 {{MHz}}. The simulations were carried out by means of a code, HELIC. They were carried out by taking into account different inhomogeneous radial density profiles and for a wide range of plasma densities, from {10}11 {{{cm}}}-3 to {10}13 {{{cm}}}-3. The magnetic field was 200, 400, 600 and 1000 {{G}}. A three-parameter function was used for generating various density profiles with different volume gradients, edge gradients and density widths. The density profile had a large effect on the efficient Trivelpiece-Gould (TG) and helicon mode excitation and antenna coupling to the plasma. The fraction of power deposition via the TG mode was extremely dependent on the plasma density near the plasma boundary. Interestingly, the obtained efficient parallel helicon wavelength was close to the anticipated value for Gaussian radial density profile. Power deposition was considerably asymmetric when the \\tfrac{n}{{B}0} ratio was more than a specific value for a determined density width. The longitudinal power absorption was symmetric at approximately {n}0={10}11 {{{cm}}}-3, irrespective of the magnetic field supposed. The asymmetry became more pronounced when the plasma density was {10}12 {{{cm}}}-3. The ratio of density width to the magnetic field was an important parameter in the power coupling. At high magnetic fields, the maximum of the power absorption was reached at higher plasma density widths. There was at least one combination of the plasma density, magnetic field and density width for which the RF power deposition at both side of the tube reached its maximum value.

Flash photolysis and pulse radiolysis studies on collagen Type I in acetic acid solution.

PubMed

Sionkowska, Alina

2006-07-03

An investigation of the photochemical properties of collagen Type I in acetic acid solution was carried out using nanosecond laser irradiation. The transient spectra of collagen solution excited at 266 nm show two bands. One of them with maximum at 295 nm and the second one with maximum at 400 nm. The peak at 400 nm is assigned to tyrosyl radicals. The first peak of the transient absorption spectra at 295 nm is probably due to photoionisation producing collagen radical cation. The transient for collagen solution in acetic acid at 640 nm was not observed. It is evidence that there is no hydrated electron in the irradiated collagen solution. The reactions of hydrated electrons and (*)OH radicals with collagen have been studied by pulse radiolysis. In the absorption spectra of products resulting from the reaction of collagen with e(aq)(-) no characteristic maximum absorption in UV and visible light region has been observed. In the absorption spectra of products resulting from the reaction of the hydroxyl radicals with collagen two bands have been observed. The first one at 320 nm and the second one at 405 nm. Reaction of (*)OH radicals with tyrosine residues in collagen chains gives rise to Tyr phenoxyl radicals (absorption at 400 nm).

An analysis of dissolved organic matter from freshwater Karelian Lakes using reversed-phase high-performance liquid chromatography with online absorbance and fluorescence analysis

NASA Astrophysics Data System (ADS)

Khundzhua, D. A.; Patsaeva, S. V.; Trubetskoj, O. A.; Trubetskaya, O. E.

2017-01-01

The spectral and optical properties of the fractionated components of dissolved organic matter (DOM) of three freshwater lakes in Karelia were studied using reversed-phase high-performance liquid chromatography (RP-HPLC) with online detection of fluorescence and absorption spectra. It is shown that the DOM fractions are qualitatively similar, but differ quantitatively in the ratio of components and consist of at least three types of fluorophores: (1) hydrophilic "humic-like" fluorophore(s) with the emission maximum in the region of 420 nm and an absorption band at 260-270 nm; (2) hydrophobic "humic-like" fluorophore(s) with the emission maximum at approximately 450 nm that has no characteristic absorption maxima in the region from 220 to 400 nm; and (3) a "protein-like" fluorophore with the emission maximum in the region of 340-350 nm, which is typical of proteins and peptides containing tryptophan.

Calcination Conditions on the Properties of Porous TiO2 Film

NASA Astrophysics Data System (ADS)

Zhang, Wenjie; Pei, Xiaobei; Bai, Jiawei; He, Hongbo

2014-03-01

Porous TiO2 films were deposited on SiO2 precoated glass-slides by sol-gel method using PEG1000 as template. The strongest XRD diffraction peak at 2θ = 25.3° is attributed to [101] plane of anatase TiO2 in the film. The increases of calcination temperature and time lead to stronger diffraction peak intensity. High transmittance and blue shift of light absorption edge are the properties of the film prepared at high calcination temperature. The average pore size of the films increases with the increasing calcination temperature as the result of TiO2 crystalline particles growing up and aggregation, accompanied with higher specific surface area. Photocatalytic activity of porous TiO2 films increases with the increasing calcination temperature. The light absorption edge of the films slightly moves to longer wavelength region along with the increasing calcination time. The mesoporous film calcinated at 500 °C for 2 h has the highest transmittance, the maximum surface area, and the maximum total pore volume. Consequently, the optimum degradation activity is achieved on the porous TiO2 film calcinated at 500 °C for 2 h.

Synthesis and Characterization of Water-Soluble Polythiophene Derivatives for Cell Imaging

NASA Astrophysics Data System (ADS)

Wang, Fengyan; Li, Meng; Wang, Bing; Zhang, Jiangyan; Cheng, Yongqiang; Liu, Libing; Lv, Fengting; Wang, Shu

2015-01-01

In this work, four water-soluble polythiophene derivatives (PT, PT-DDA, PT-ADA, and PT-ADA-PPR) with different pendant moieties were synthesized via oxidative copolymerization by FeCl3. By increasing the hydrophobic ability of side chain moieties, there is a gradually blue shift for the maximum absorption wavelength and red shift for the maximum emission wavelength, a reducing trend for fluorescence quantum yields, a growing trend for Stokes shift, and an increasing trend for the mean sizes in the order of PT, PT-ADA, and PT-DDA. All the synthesized polymers show low toxicity and good photostability and accumulate in the lysosomes of A549 cells. Furthermore, the introduction of porphyrin group to PT-ADA side chain (PT-ADA-PPR) broadens the absorption and emission ranges of PT-ADA. PT-ADA-PPR could be excited at two different excitation wavelengths (488 nm and 559 nm) and exhibits two emission pathways, and dual-color fluorescence images (orange and red) of PT-ADA-PPR accumulated in A549 cells are observed. Thus, PT-ADA-PPR could be used as an excellent dual-color fluorescent and lysosome-specific imaging material.

From Broadband to Electrochromic Notch Filters with Printed Monochiral Carbon Nanotubes

PubMed Central

2018-01-01

Dense layers of semiconducting single-walled carbon nanotubes (SWNTs) serve as electrochromic (EC) materials in the near-infrared with high optical density and high conductivity. EC cells with tunable notch filter properties instead of broadband absorption are created via highly selective dispersion of specific semiconducting SWNTs through polymer-wrapping followed by deposition of thick films by aerosol-jet printing. A simple planar geometry with spray-coated mixed SWNTs as the counter electrode renders transparent metal oxides redundant and facilitates complete bleaching within a few seconds through iongel electrolytes with high ionic conductivities. Monochiral (6,5) SWNT films as working electrodes exhibit a narrow absorption band at 997 nm (full width at half-maximum of 55–73 nm) with voltage-dependent optical densities between 0.2 and 4.5 and a modulation depth of up to 43 dB. These (6,5) SWNT notch filters can retain more than 95% of maximum bleaching for several hours under open-circuit conditions. In addition, different levels of transmission can be set by applying constant low voltage (1.5 V) pulses with modulated width or by a given number of fixed short pulses. PMID:29521086

Measurements of spectral optical properties and their relation to biogeochemical variables and processes in Crater Lake, Crater Lake National Park, OR

USGS Publications Warehouse

Boss, E.S.; Collier, R.; Larson, G.; Fennel, K.; Pegau, W.S.

2007-01-01

Spectral inherent optical properties (IOPs) have been measured at Crater Lake, OR, an extremely clear sub-alpine lake. Indeed Pure water IOPs are major contributors to the total IOPs, and thus to the color of the lake. Variations in the spatial distribution of IOPs were observed in June and September 2001, and reflect biogeochemical processes in the lake. Absorption by colored dissolved organic material increases with depth and between June and September in the upper 300 m. This pattern is consistent with a net release of dissolved organic materials from primary and secondary production through the summer and its photo-oxidation near the surface. Waters fed by a tributary near the lake's rim exhibited low levels of absorption by dissolved organic materials. Scattering is mostly dominated by organic particulate material, though inorganic material is found to enter the lake from the rim following a rain storm. Several similarities to oceanic oligotrophic regions are observed: (a) The Beam attenuation correlates well with particulate organic material (POM) and the relationship is similar to that observed in the open ocean. (b) The specific absorption of colored dissolved organic material has a value similar to that of open ocean humic material. (c) The distribution of chlorophyll with depth does not follow the distribution of particulate organic material due to photo-acclimation resulting in a subsurface pigment maximum located about 50 m below the POM maximum. ?? 2007 Springer Science+Business Media B.V.

Shock-Absorbing Effects of Various Padding Conditions in Improving Efficacy of Wrist Guards

PubMed Central

Hwang, Il-Kyu; Kim, Kyu-Jung

2004-01-01

The use of wrist guards has limited efficacy in preventing wrist injuries during falling in many sports activities. The objectives of this study were to measure the ground reaction force of the hand under simulated impact of the forearm and hand complex with different padding conditions of wrist guards and to analyze their impact force attenuation and maximum energy absorption for improved functional efficiency. A total of 15 subjects, wearing a commercial wrist guard, participated in a cable-released hand impact experiment to test four different conditions on the volar aspect of the hand, which include a wrist guard without a volar splint (bare hand), with a volar splint (normal use), with a volar splint and additional viscoelastic polymeric padding, and a volar splint and additional air cell padding. The ground reaction force and acceleration of the hand were measured using a force platform mounted on an anti-vibration table and a miniature accelerometer, respectively. Additional padding on the bare hand could substantially improve the maximum energy absorption by more than 39%, with no differences with each other. However, only the air cell padding could simultaneously improve the impact force attenuation by 32% compared with the bare hand impact without compromising the maximum energy absorption. It is recommended that common wrist guard design should provide more compliant padding in the volar aspect to improve the impact force attenuation through optimal material selection and design. Key Points The controversial efficacy of wrist guards in preventing wrist injuries during falling was tested through investigation of their impact force attenuation and maximum energy absorption from the measured ground reaction force of the hand under simulated impact of the forearm and hand complex with four different padding conditions of wrist guards: a wrist guard without a volar splint (bare hand), with a volar splint (normal use), with a volar splint and additional viscoelastic polymeric padding, and a volar splint and additional air cell padding. In general, padding on the bare hand could improve the maximum energy absorption by more than 39%, while only the air cell padding could simultaneously attenuate the peak impact force by 32% without compromising the maximum energy absorption. Common wrist guard design requires more compliant padding in the volar aspect to improve the impact force attenuation, which should be done through optimal material selection and design. PMID:24497817

Tunneling induced absorption with competing Nonlinearities.

PubMed

Peng, Yandong; Yang, Aihong; Xu, Yan; Wang, Peng; Yu, Yang; Guo, Hongju; Ren, Tingqi

2016-12-13

We investigate tunneling induced nonlinear absorption phenomena in a coupled quantum-dot system. Resonant tunneling causes constructive interference in the nonlinear absorption that leads to an increase of more than an order of magnitude over the maximum absorption in a coupled quantum dot system without tunneling. Resonant tunneling also leads to a narrowing of the linewidth of the absorption peak to a sublinewidth level. Analytical expressions show that the enhanced nonlinear absorption is largely due to the fifth-order nonlinear term. Competition between third- and fifth-order nonlinearities leads to an anomalous dispersion of the total susceptibility.

Multiepoch Spectropolarimetry of SN 2011fe

DOE Office of Scientific and Technical Information (OSTI.GOV)

Milne, Peter A.; Williams, G. Grant; Smith, Paul S.

2017-01-20

We present multiple spectropolarimetric observations of the nearby Type Ia supernova (SN) 2011fe in M101, obtained before, during, and after the time of maximum apparent visual brightness. The excellent time coverage of our spectropolarimetry has allowed better monitoring of the evolution of polarization features than is typical, which has allowed us new insight into the nature of normal SNe Ia. SN 2011fe exhibits time-dependent polarization in both the continuum and strong absorption lines. At early epochs, red wavelengths exhibit a degree of continuum polarization of up to 0.4%, likely indicative of a mild asymmetry in the electron-scattering photosphere. This behaviormore » is more common in subluminous SNe Ia than in normal events, such as SN 2011fe. The degree of polarization across a collection of absorption lines varies dramatically from epoch to epoch. During the earliest epoch, a λ 4600–5000 Å complex of absorption lines shows enhanced polarization at a different position angle than the continuum. We explore the origin of these features, presenting a few possible interpretations, without arriving at a single favored ion. During two epochs near maximum, the dominant polarization feature is associated with the Si ii λ 6355 Å absorption line. This is common for SNe Ia, but for SN 2011fe the polarization of this feature increases after maximum light, whereas for other SNe Ia, that polarization feature was strongest before maximum light.« less

Magnetic hyperthermia study in water based magnetic fluids containing TMAOH coated Fe3O4 using infrared thermography

NASA Astrophysics Data System (ADS)

Lahiri, B. B.; Ranoo, Surojit; Philip, John

2017-01-01

We study the alternating magnetic field induced heating of a water based ferrofluid containing tetramethyl ammonium hydroxide coated iron oxide nanoparticles using infrared thermography and compare the results obtained from the conventional fiber optic temperature sensor. Experiments are performed on ferrofluid samples of five different concentrations and under four different external field amplitudes at a fixed frequency. The temperature rise curves measured using both the infrared thermography and fiber optic sensor are found to be very similar up to a certain time interval, above which deviations are observed, which are attributed to the internal and external convection phenomena. A correction methodology is developed to account for the convection losses. The convection corrected specific absorption rate is found to be in good agreement with the values obtained from the conventional fiber optic temperature sensor, within a maximum error of ±3.4%. The highest specific absorption rate obtained in the present study is 135.98 (±4.6) W/gFe for a sample concentration of 3 wt.%, at an external field amplitude and a frequency of 63.0 kA m-1 and 126 kHz, respectively. The specific absorption rate is found to decrease with increasing sample concentration, due to the enhancement of dipolar interaction with increasing sample concentration due to agglomeration. This study validates the efficacy and universal applicability of IRT as an alternate, real time, non-contact and wide area temperature measurement methodology for magnetic fluid hyperthermia experiments without any sample contamination.

Developability assessment of clinical drug products with maximum absorbable doses.

PubMed

Ding, Xuan; Rose, John P; Van Gelder, Jan

2012-05-10

Maximum absorbable dose refers to the maximum amount of an orally administered drug that can be absorbed in the gastrointestinal tract. Maximum absorbable dose, or D(abs), has proved to be an important parameter for quantifying the absorption potential of drug candidates. The purpose of this work is to validate the use of D(abs) in a developability assessment context, and to establish appropriate protocol and interpretation criteria for this application. Three methods for calculating D(abs) were compared by assessing how well the methods predicted the absorption limit for a set of real clinical candidates. D(abs) was calculated for these clinical candidates by means of a simple equation and two computer simulation programs, GastroPlus and an program developed at Eli Lilly and Company. Results from single dose escalation studies in Phase I clinical trials were analyzed to identify the maximum absorbable doses for these compounds. Compared to the clinical results, the equation and both simulation programs provide conservative estimates of D(abs), but in general D(abs) from the computer simulations are more accurate, which may find obvious advantage for the simulations in developability assessment. Computer simulations also revealed the complex behavior associated with absorption saturation and suggested in most cases that the D(abs) limit is not likely to be achieved in a typical clinical dose range. On the basis of the validation findings, an approach is proposed for assessing absorption potential, and best practices are discussed for the use of D(abs) estimates to inform clinical formulation development strategies. Copyright © 2012 Elsevier B.V. All rights reserved.

Narrow band perfect absorber for maximum localized magnetic and electric field enhancement and sensing applications

PubMed Central

Yong, Zhengdong; Zhang, Senlin; Gong, Chensheng; He, Sailing

2016-01-01

Plasmonics offer an exciting way to mediate the interaction between light and matter, allowing strong field enhancement and confinement, large absorption and scattering at resonance. However, simultaneous realization of ultra-narrow band perfect absorption and electromagnetic field enhancement is challenging due to the intrinsic high optical losses and radiative damping in metals. Here, we propose an all-metal plasmonic absorber with an absorption bandwidth less than 8 nm and polarization insensitive absorptivity exceeding 99%. Unlike traditional Metal-Dielectric-Metal configurations, we demonstrate that the narrowband perfect absorption and field enhancement are ascribed to the vertical gap plasmonic mode in the deep subwavelength scale, which has a high quality factor of 120 and mode volume of about 10−4 × (λres/n)3. Based on the coupled mode theory, we verify that the diluted field enhancement is proportional to the absorption, and thus perfect absorption is critical to maximum field enhancement. In addition, the proposed perfect absorber can be operated as a refractive index sensor with a sensitivity of 885 nm/RIU and figure of merit as high as 110. It provides a new design strategy for narrow band perfect absorption and local field enhancement, and has potential applications in biosensors, filters and nonlinear optics. PMID:27046540

[Spectrum simulation based on data derived from red tide].

PubMed

Liu, Zhen-Yu; Cui, Ting-Wei; Yue, Jie; Jiang, Tao; Cao, Wen-Xi; Ma, Yi

2011-11-01

The present paper utilizes the absorption data of red tide water measured during the growing and dying course to retrieve imaginary part of the index of refraction based on Mie theory, carries out the simulation and analysis of average absorption efficiency factors, average backscattering efficiency factors and scattering phase function. The analysis of the simulation shows that Mie theory can be used to reproduce the absorption property of Chaetoceros socialis with an average error of 11%; the average backscattering efficiency factors depend on the value of absorption whose maximum value corresponds to the wavelength range from 400 to 700 nanometer; the average backscattering efficiency factors showed a maximum value on 17th with a low value during the outbreak of red tide and the minimum on 21th; the total scattering, weakly depending on the absorption, is proportional to the size parameters which represent the relative size of cell diameter with respect to the wavelength, while the angle scattering intensity is inversely proportional to wavelength.

Axial Crushing of Thin-Walled Columns with Octagonal Section: Modeling and Design

NASA Astrophysics Data System (ADS)

Liu, Yucheng; Day, Michael L.

This chapter focus on numerical crashworthiness analysis of straight thinwalled columns with octagonal cross sections. Two important issues in this analysis are demonstrated here: computer modeling and crashworthiness design. In the first part, this chapter introduces a method of developing simplified finite element (FE) models for the straight thin-walled octagonal columns, which can be used for the numerical crashworthiness analysis. Next, this chapter performs a crashworthiness design for such thin-walled columns in order to maximize their energy absorption capability. Specific energy absorption (SEA) is set as the design objective, side length of the octagonal cross section and wall thickness are selected as design variables, and maximum crushing force (Pm) occurs during crashes is set as design constraint. Response surface method (RSM) is employed to formulate functions for both SEA and Pm.

Microwave absorption performance of Ni(OH)2 decorating biomass carbon composites from Jackfruit peel

NASA Astrophysics Data System (ADS)

Guan, Hongtao; Wang, Huiya; Zhang, Yanlin; Dong, Chengjun; Chen, Gang; Wang, Yude; Xie, Jianbin

2018-07-01

The composite material of Ni(OH)2/biomass carbon have been prepared by a facile "carbonization-activation" procedure from Jackfruit peel and a subsequent water-bathing precipitation process. The biomass carbon material after activation (AC) is constituted of small particles and achieves a large specific surface area of 1602 m2/g. After decoration of Ni(OH)2 nanosheets, the Ni(OH)2/AC composites were investigated the microwave absorption performances in 2-18 GHz. The maximum reflection loss of the Ni(OH)2/AC composites reached -23.6 dB at 15.48 GHz with a thickness of 6 mm. Moreover, the fundamental mechanism based on conductivity, the polarization and defects is discussed. The present investigation offers a new possibility for the biomass based fabrication of potential microwave absorbing materials.

Precise Determination of the Absorption Maximum in Wide Bands

ERIC Educational Resources Information Center

Eriksson, Karl-Hugo; And Others

1977-01-01

A precise method of determining absorption maxima where Gaussian functions occur is described. The method is based on a logarithmic transformation of the Gaussian equation and is suited for a mini-computer. (MR)

Magnetic and hydrogel composite materials for hyperthermia applications.

PubMed

Lao, L L; Ramanujan, R V

2004-10-01

Micron-sized magnetic particles (Fe3O4) were dispersed in a polyvinyl alcohol hydrogel to study their potential for hyperthermia applications. Heating characteristics of this ferrogel in an alternating magnetic field (375 kHz) were investigated. The results indicate that the amount of heat generated depends on the Fe3O4 content and magnetic field amplitude. A stable maximum temperature ranging from 43 to 47 degrees C was successfully achieved within 5-6 min. The maximum temperature was a function of Fe3O4 concentration. A specific absorption rate of up to 8.7 W/g Fe3O4 was achieved; this value was found to depend on the magnetic field strength. Hysteresis loss is the main contribution to the heating effect experienced by the sample.

Science and software support for spacecraft solar occultation experiments

NASA Technical Reports Server (NTRS)

Hessameddin, G.; Becher, J.

1982-01-01

The temperature dependence of absorption coefficients of ozone was studied between 7567 A and 3630 A. When the gas was cooled from room temperature to -108 C, an overall increase in the absorption coefficients was noticed. The maximum increase of 5% occurred at lambda = 6020 A. In general, the absorption is linearly dependent on temperature.

Comparison of radio frequency energy absorption in ear and eye region of children and adults at 900, 1800 and 2450 MHz.

PubMed

Keshvari, J; Lang, S

2005-09-21

The increasing use of mobile communication devices, especially mobile phones by children, has triggered discussions on whether there is a larger radio frequency (RF) energy absorption in the heads of children compared to that of adults. The objective of this study was to clarify possible differences in RF energy absorption in the head region of children and adults using computational techniques. Using the finite-difference time-domain (FDTD) computational method, a set of specific absorption rate (SAR) calculations were performed for anatomically correct adult and child head models. A half-wave dipole was used as an exposure source at 900, 1800 and 2450 MHz frequencies. The ear and eye regions were studied representing realistic exposure scenarios to current and upcoming mobile wireless communication devices. The differences in absorption were compared with the maximum energy absorption of the head model. Four magnetic resonance imaging (MRI) based head models, one female, one adult, two child head models, aged 3 and 7 years, were used. The head models greatly differ from each other in terms of size, external shape and the internal anatomy. The same tissue dielectric parameters were applied for all models. The analyses suggest that the SAR difference between adults and children is more likely caused by the general differences in the head anatomy and geometry of the individuals rather than age. It seems that the external shape of the head and the distribution of different tissues within the head play a significant role in the RF energy absorption.

Absorption Voltages and Insulation Resistance in Ceramic Capacitors with Cracks

NASA Technical Reports Server (NTRS)

Teverovsky, Alexander

2014-01-01

Time dependence of absorption voltages (V(sub abs)) in different types of low-voltage X5R and X7R ceramic capacitors was monitored for a maximum duration of hundred hours after polarization. To evaluate the effect of mechanical defects on V(sub abs)), cracks in the dielectric were introduced either mechanically or by thermal shock. The maximum absorption voltage, time to roll-off, and the rate of voltage decrease are shown to depend on the crack-related leakage currents and insulation resistance in the parts. A simple model that is based on the Dow equivalent circuit for capacitors with absorption has been developed to assess the insulation resistance of capacitors. Standard measurements of the insulation resistance, contrary to the measurements based on V(sub abs)), are not sensitive to the presence of mechanical defects and fail to reveal capacitors with cracks.

Effects of heat induced by two-photon absorption and free-carrier absorption in silicon-on-insulator nanowaveguides operating as all-optical wavelength converters.

PubMed

Abdollahi, Siamak; Moravvej-Farshi, Mohammad Kazem

2009-05-01

We propose a new numerical model to analyze heat induced by two-photon absorption and free-carrier absorption, while high intensity optical pulses propagate along silicon-on-insulator (SOI) nanowaveguides (NWGs). Using this model, we demonstrate that such induced heat causes a shift in the amount of wavelength conversion and hence deteriorates the converter output characteristics for pulses in the picosecond regime. The wavelength shift induced by a pulse with maximum input intensity and full width at half-maximum of I(max)=1.5x10(10) W x cm(-2) and T(FWHM)=30 ps, propagating along a SOI NWG with an effective cross-sectional area of a(eff)=0.15 microm(2), is shown to be Delta lambda(s) approximately 8 pm. We also demonstrate that such a shift can be compensated by tuning the pump intensity down by approximately 6.33%.

Physiologically Based Pharmacokinetic and Absorption Modeling for Osmotic Pump Products.

PubMed

Ni, Zhanglin; Talattof, Arjang; Fan, Jianghong; Tsakalozou, Eleftheria; Sharan, Satish; Sun, Dajun; Wen, Hong; Zhao, Liang; Zhang, Xinyuan

2017-07-01

Physiologically based pharmacokinetic (PBPK) and absorption modeling approaches were employed for oral extended-release (ER) drug products based on an osmotic drug delivery system (osmotic pumps). The purpose was to systemically evaluate the in vivo relevance of in vitro dissolution for this type of formulation. As expected, in vitro dissolution appeared to be generally predictive of in vivo PK profiles, because of the unique feature of this delivery system that the in vitro and in vivo release of osmotic pump drug products is less susceptible to surrounding environment in the gastrointestinal (GI) tract such as pH, hydrodynamic, and food effects. The present study considered BCS (Biopharmaceutics Classification System) class 1, 2, and 3 drug products with half-lives ranging from 2 to greater than 24 h. In some cases, the colonic absorption models needed to be adjusted to account for absorption in the colon. C max (maximum plasma concentration) and AUCt (area under the concentration curve) of the studied drug products were sensitive to changes in colon permeability and segmental GI transit times in a drug product-dependent manner. While improvement of the methodology is still warranted for more precise prediction (e.g., colonic absorption and dynamic movement in the GI tract), the results from the present study further emphasized the advantage of using PBPK modeling in addressing product-specific questions arising from regulatory review and drug development.

Numerical evaluation of human exposure to WiMax patch antenna in tablet or laptop.

PubMed

Siervo, Beatrice; Morelli, Maria Sole; Landini, Luigi; Hartwig, Valentina

2018-04-30

The use of wireless communication devices, such as tablets or laptops, is increasing among children. Only a few studies assess specific energy absorption rate (SAR) due to exposure from wireless-enabled tablets and laptops, in particular with Worldwide Interoperability for Microwave Access (WiMax) technology. This paper reports the estimation of the interaction between an E-shaped patch antenna (3.5 GHz) and human models, by means of finite-difference time-domain (FDTD) method. Specifically, four different human models (young adult male, young adult female, pre-teenager female, male child) in different exposure conditions (antenna at different distances from the human model, in different positions, and orientations) were considered and whole-body, 10 and 1 g local SAR and magnetic field value (Bmax) were evaluated. From our results, in some worst-case scenarios involving male and female children's exposure, the maximum radiofrequency energy absorption (hot spots) is located in more sensitive organs such as eye, genitals, and breast. Bioelectromagnetics. © 2018 Wiley Periodicals, Inc. © 2018 Wiley Periodicals, Inc.

Tunneling induced absorption with competing Nonlinearities

PubMed Central

Peng, Yandong; Yang, Aihong; Xu, Yan; Wang, Peng; Yu, Yang; Guo, Hongju; Ren, Tingqi

2016-01-01

We investigate tunneling induced nonlinear absorption phenomena in a coupled quantum-dot system. Resonant tunneling causes constructive interference in the nonlinear absorption that leads to an increase of more than an order of magnitude over the maximum absorption in a coupled quantum dot system without tunneling. Resonant tunneling also leads to a narrowing of the linewidth of the absorption peak to a sublinewidth level. Analytical expressions show that the enhanced nonlinear absorption is largely due to the fifth-order nonlinear term. Competition between third- and fifth-order nonlinearities leads to an anomalous dispersion of the total susceptibility. PMID:27958303

Mobile phone types and SAR characteristics of the human brain.

PubMed

Lee, Ae-Kyoung; Hong, Seon-Eui; Kwon, Jong-Hwa; Choi, Hyung-Do; Cardis, Elisabeth

2017-04-07

Mobile phones differ in terms of their operating frequency, outer shape, and form and location of the antennae, all of which affect the spatial distributions of their electromagnetic field and the level of electromagnetic absorption in the human head or brain. For this paper, the specific absorption rate (SAR) was calculated for four anatomical head models at different ages using 11 numerical phone models of different shapes and antenna configurations. The 11 models represent phone types accounting for around 86% of the approximately 1400 commercial phone models released into the Korean market since 2002. Seven of the phone models selected have an internal dual-band antenna, and the remaining four possess an external antenna. Each model was intended to generate an average absorption level equivalent to that of the same type of commercial phone model operating at the maximum available output power. The 1 g peak spatial SAR and ipsilateral and contralateral brain-averaged SARs were reported for all 11 phone models. The effects of the phone type, phone position, operating frequency, and age of head models on the brain SAR were comprehensively determined.

Mobile phone types and SAR characteristics of the human brain

NASA Astrophysics Data System (ADS)

Lee, Ae-Kyoung; Hong, Seon-Eui; Kwon, Jong-Hwa; Choi, Hyung-Do; Cardis, Elisabeth

2017-04-01

Mobile phones differ in terms of their operating frequency, outer shape, and form and location of the antennae, all of which affect the spatial distributions of their electromagnetic field and the level of electromagnetic absorption in the human head or brain. For this paper, the specific absorption rate (SAR) was calculated for four anatomical head models at different ages using 11 numerical phone models of different shapes and antenna configurations. The 11 models represent phone types accounting for around 86% of the approximately 1400 commercial phone models released into the Korean market since 2002. Seven of the phone models selected have an internal dual-band antenna, and the remaining four possess an external antenna. Each model was intended to generate an average absorption level equivalent to that of the same type of commercial phone model operating at the maximum available output power. The 1 g peak spatial SAR and ipsilateral and contralateral brain-averaged SARs were reported for all 11 phone models. The effects of the phone type, phone position, operating frequency, and age of head models on the brain SAR were comprehensively determined.

Rapid Optimization of External Quantum Efficiency of Thin Film Solar Cells Using Surrogate Modeling of Absorptivity.

PubMed

Kaya, Mine; Hajimirza, Shima

2018-05-25

This paper uses surrogate modeling for very fast design of thin film solar cells with improved solar-to-electricity conversion efficiency. We demonstrate that the wavelength-specific optical absorptivity of a thin film multi-layered amorphous-silicon-based solar cell can be modeled accurately with Neural Networks and can be efficiently approximated as a function of cell geometry and wavelength. Consequently, the external quantum efficiency can be computed by averaging surrogate absorption and carrier recombination contributions over the entire irradiance spectrum in an efficient way. Using this framework, we optimize a multi-layer structure consisting of ITO front coating, metallic back-reflector and oxide layers for achieving maximum efficiency. Our required computation time for an entire model fitting and optimization is 5 to 20 times less than the best previous optimization results based on direct Finite Difference Time Domain (FDTD) simulations, therefore proving the value of surrogate modeling. The resulting optimization solution suggests at least 50% improvement in the external quantum efficiency compared to bare silicon, and 25% improvement compared to a random design.

Dependence of Aerosol Light Absorption and Single-Scattering Albedo On Ambient Relative Humidity for Sulfate Aerosols with Black Carbon Cores

NASA Technical Reports Server (NTRS)

Redemann, Jens; Russell, Philip B.; Hamill, Patrick

2001-01-01

Atmospheric aerosols frequently contain hygroscopic sulfate species and black carbon (soot) inclusions. In this paper we report results of a modeling study to determine the change in aerosol absorption due to increases in ambient relative humidity (RH), for three common sulfate species, assuming that the soot mass fraction is present as a single concentric core within each particle. Because of the lack of detailed knowledge about various input parameters to models describing internally mixed aerosol particle optics, we focus on results that were aimed at determining the maximum effect that particle humidification may have on aerosol light absorption. In the wavelength range from 450 to 750 nm, maximum absorption humidification factors (ratio of wet to 'dry=30% RH' absorption) for single aerosol particles are found to be as large as 1.75 when the RH changes from 30 to 99.5%. Upon lesser humidification from 30 to 80% RH, absorption humidification for single particles is only as much as 1.2, even for the most favorable combination of initial ('dry') soot mass fraction and particle size. Integrated over monomodal lognormal particle size distributions, maximum absorption humidification factors range between 1.07 and 1.15 for humidification from 30 to 80% and between 1.1 and 1.35 for humidification from 30 to 95% RH for all species considered. The largest humidification factors at a wavelength of 450 nm are obtained for 'dry' particle size distributions that peak at a radius of 0.05 microns, while the absorption humidification factors at 700 nm are largest for 'dry' size distributions that are dominated by particles in the radius range of 0.06 to 0.08 microns. Single-scattering albedo estimates at ambient conditions are often based on absorption measurements at low RH (approx. 30%) and the assumption that aerosol absorption does not change upon humidification (i.e., absorption humidification equal to unity). Our modeling study suggests that this assumption alone can introduce absolute errors in estimates of the midvisible single-scattering albedo of up to 0.05 for realistic dry particle size distributions. Our study also indicates that this error increases with increasing wavelength. The potential errors in aerosol single-scattering albedo derived here are comparable in magnitude and in addition to uncertainties in single-scattering albedo estimates that are based on measurements of aerosol light absorption and scattering.

CaFe2O4 as a self-sufficient solar energy converter

NASA Astrophysics Data System (ADS)

Tablero, C.

2017-10-01

An ideal solar energy to electricity or fuel converter should work without the use of any external bias potential. An analysis of self-sufficiency when CaFe2O4 is used to absorb the sunlight is carried out based on the CaFe2O4 absorption coefficient. We started to obtain this coefficient theoretically within the experimental bandgap range in order to fix the interval of possible values of photocurrents, maximum absorption efficiencies, and photovoltages and thus that of self-sufficiency considering only the radiative processes. Also for single-gap CaFe2O4, we evaluate an alternative for increasing the photocurrent and maximum absorption efficiency based on inserting an intermediate band using high doping or alloying.

The absorption spectra of the complexes of uranium (VI) with some β-diketones

USGS Publications Warehouse

Feinstein, H.I.

1956-01-01

The absorption spectra of the complexes of uranium (VI) with four β-dike tones were determined under various conditions of pH, concentration of uranium, and alcohol concentration. Under optimum conditions, the maximum molar absorptivity (31,200) is obtained using 2-furoyltrifluoroacetone. This compares with about 4,000 and 19,000 for the thiocyanate and dibenzoylmethane complexes, respectively.

Trace of heavy metals in maternal and umbilical cord blood samples in association with birth outcomes in Baghdad, Iraq

NASA Astrophysics Data System (ADS)

Hasan Rhaif Al-Sahlanee, Mayyadah; Maizan Ramli, Ramzun; Abdul Hassan Ali, Miami; Fadhil Tawfiq, Nada; Zahirah Noor Azman, Nurul; Abdul Rahman, Azhar; Shahrim Mustafa, Iskandar; Noor Ashikin Nik Abdul Razak, Nik; Zakiah Yahaya, Nor; Mohammed Al-Marri, Hana; Syuhada Ayob, Nur; Zakaria, Nabela

2017-10-01

Trace elements are essential nutritional components in humans and inconvenient tissue content that have a significant influence on infant size. The aim of this study is to evaluate the effects of concentration of elements (uranium (U), lead (Pb) and iron (Fe)) and absorption of Pb and Fe on maternal and umbilical cord blood samples. The concentration and absorption of Pb and Fe in blood samples were determined by using atomic absorption spectrophotometry device, while the uranium concentration was determined by using CR-39 detector. Fifty women of age 16-44 years are involved in this study. Results show that the maximum and minimum values of both concentration and absorption in the maternal samples were for Pb and Fe, respectively. In addition, for umbilical cord, the maximum values of concentration and absorption were for Fe and the minimum concentration and absorption were for U and Pb, respectively. A significant correlation between maternal and umbilical cord blood samples was found. This indicates that the Pb, U and Fe elements can easily transfer from maternal to the fetal body which impacts the growth of fetus.

Characterization of an intraluminal differential frequency-domain photoacoustics system

NASA Astrophysics Data System (ADS)

Lashkari, Bahman; Son, Jungik; Liang, Simon; Castelino, Robin; Foster, F. Stuart; Courtney, Brian; Mandelis, Andreas

2016-03-01

Cardiovascular related diseases are ranked as the second highest cause of death in Canada. Among the most important cardiovascular diseases is atherosclerosis. Current methods of diagnosis of atherosclerosis consist of angiography, intravascular ultrasound (IVUS) and optical coherence tomography (OCT). None of these methods possesses adequate sensitivity, as the ideal technique should be capable of both depth profiling, as well as functional imaging. An alternative technique is photoacoustics (PA) which can perform deep imaging and spectroscopy. The presented study explores the application of wavelength-modulated differential photoacoustic radar (WM-DPAR) for characterizing arterial vessels. The wavelength-modulated differential photoacoustic technique was shown to be able to substantially increase the dynamic range and sensitivity of hemoglobin oxygenation level detection. In this work the differential PA technique was used with a very high frequency modulation range. To perform spectroscopic PA imaging, at least two wavelengths are required. The selected wavelengths for this work are 1210 nm and 980 nm. 1210 nm corresponds to the maximum optical absorption coefficient of cholesterol and cholesteryl esters which are the main constituents of plaques. Since water, elastin and collagen also have high absorption coefficients at 1210 nm, this wavelength alone cannot provide very high sensitivity and specificity. The additional wavelength, 980 nm corresponds to high absorption coefficient of those constituents of healthy artery tissue. The simultaneous application of the abovementioned wavelengths can provide higher sensitivity and improved specificity in detecting lipids in the arterial vessels.

Effects of pulsed electromagnetic field (PEMF) on the tensile biomechanical properties of diabetic wounds at different phases of healing

PubMed Central

Cheing, Alex K. K.; Ng, Gabriel Y. F.; Cheing, Gladys L. Y.

2018-01-01

The present study investigated the effects of pulsed electromagnetic field (PEMF) on the tensile biomechanical properties of diabetic wounds at different phases of healing. Two intensities of PEMF were adopted for comparison. We randomly assigned 111 10-week-old male streptozotocin-induced diabetic Sprague-Dawley rats to two PEMF groups and a sham control group. Six-millimetre biopsy punched full thickness wounds were made on the lateral side of their hindlimbs. The PEMF groups received active PEMF delivered at 25 Hz with intensity of either 2 mT or 10 mT daily, while the sham group was handled in a similar way except they were not exposed to PEMF. Wound tissues were harvested for tensile testing on post-wounding days 3, 5, 7, 10, 14 and 21. Maximum load, maximum stress, energy absorption capacity, Young’s modulus and thickness of wound tissue were measured. On post-wounding day 5, the PEMF group that received 10-mT intensity had significantly increased energy absorption capacity and showed an apparent increase in the maximum load. However, the 10-mT PEMF group demonstrated a decrease in Young’s modulus on day 14. The 10-mT PEMF groups showed a significant increase in the overall thickness of wound tissue whereas the 2-mT group showed a significant decrease in the overall maximum stress of the wounds tissue. The present findings demonstrated that the PEMF delivered at 10 mT can improve energy absorption capacity of diabetic wounds in the early healing phase. However, PEMF (both 2-mT and 10-mT) seemed to impair the material properties (maximum stress and Young’s modulus) in the remodelling phase. PEMF may be a useful treatment for promoting the recovery of structural properties (maximum load and energy absorption capacity), but it might not be applied at the remodelling phase to avoid impairing the recovery of material properties. PMID:29324868

Energy cost of riding bicycles with shock absorption systems on a flat surface.

PubMed

Nielens, H; Lejeune, T M

2001-08-01

Bike shock absorption systems reduce the energy variation induced by terrain irregularities, leading to a greater comfort. However, they may also induce an increase in energy expenditure for the rider. More specifically, cross-country racers claim that rear shock absorption systems generate significant energy loss. The energy losses caused by such systems may be divided in terrain-induced or rider-induced. This study aims at evaluating the rider-induced energy loss of modern suspended bicycles riding on a flat surface. Twelve experienced competitive racers underwent three multistage gradational tests (50 to 250 W) on a cross-country bicycle mounted on an electromagnetically braked cycle ergometer. Three different tests were performed on a fully suspended bike, front suspended and non-suspended bicycle, respectively. The suspension mode has no significant effect on VO2. The relative difference of VO2 between the front-suspended or full-suspended bike and the rigid bike reaches a non significant maximum of only 3%. The claims of many competitors who still prefer front shock absorption systems could be related to a possible significant energy loss that could be present at powers superior to 250 W or when they stand on the pedals. It could also be generated by terrain-induced energy loss.

Qualification of a Multi-Channel Infrared Laser Absorption Spectrometer for Monitoring CO, HCl, HCN, HF, and CO2 Aboard Manned Spacecraft

NASA Technical Reports Server (NTRS)

Briggs, Ryan M.; Frez, Clifford; Forouhar, Siamak; May, Randy D.; Meyer, Marit E.; Kulis, Michael J.; Berger, Gordon M.

2015-01-01

Monitoring of specific combustion products can provide early-warning detection of accidental fires aboard manned spacecraft and also identify the source and severity of combustion events. Furthermore, quantitative in situ measurements are important for gauging levels of exposure to hazardous gases, particularly on long-duration missions where analysis of returned samples becomes impractical. Absorption spectroscopy using tunable laser sources in the 2 to 5 micrometer wavelength range enables accurate, unambiguous detection of CO, HCl, HCN, HF, and CO2, which are produced in varying amounts through the heating of electrical components and packaging materials commonly used aboard spacecraft. Here, we report on calibration and testing of a five-channel laser absorption spectrometer designed to accurately monitor ambient gas-phase concentrations of these five compounds, with low-level detection limits based on the Spacecraft Maximum Allowable Concentrations. The instrument employs a two-pass absorption cell with a total optical pathlength of 50 cm and a dedicated infrared semiconductor laser source for each target gas. We present results from testing the five-channel sensor in the presence of trace concentrations of the target compounds that were introduced using both gas sources and oxidative pyrolysis (non-flaming combustion) of solid material mixtures.

Glycosylated Porphyra-334 and Palythine-Threonine from the Terrestrial Cyanobacterium Nostoc commune

PubMed Central

Nazifi, Ehsan; Wada, Naoki; Yamaba, Minami; Asano, Tomoya; Nishiuchi, Takumi; Matsugo, Seiichi; Sakamoto, Toshio

2013-01-01

Mycosporine-like amino acids (MAAs) are water-soluble UV-absorbing pigments, and structurally different MAAs have been identified in eukaryotic algae and cyanobacteria. In this study novel glycosylated MAAs were found in the terrestrial cyanobacterium Nostoc commune (N. commune). An MAA with an absorption maximum at 334 nm was identified as a hexose-bound porphyra-334 derivative with a molecular mass of 508 Da. Another MAA with an absorption maximum at 322 nm was identified as a two hexose-bound palythine-threonine derivative with a molecular mass of 612 Da. These purified MAAs have radical scavenging activities in vitro, which suggests multifunctional roles as sunscreens and antioxidants. The 612-Da MAA accounted for approximately 60% of the total MAAs and contributed approximately 20% of the total radical scavenging activities in a water extract, indicating that it is the major water-soluble UV-protectant and radical scavenger component. The hexose-bound porphyra-334 derivative and the glycosylated palythine-threonine derivatives were found in a specific genotype of N. commune, suggesting that glycosylated MAA patterns could be a chemotaxonomic marker for the characterization of the morphologically indistinguishable N. commune. The glycosylation of porphyra-334 and palythine-threonine in N. commune suggests a unique adaptation for terrestrial environments that are drastically fluctuating in comparison to stable aquatic environments. PMID:24065157

Wearable slot antenna at 2.45 GHz for off-body radiation: Analysis of efficiency, frequency shift, and body absorption.

PubMed

Fernandez, Marta; Espinosa, Hugo G; Thiel, David V; Arrinda, Amaia

2018-01-01

The interaction of body-worn antennas with the human body causes a significant decrease in antenna efficiency and a shift in resonant frequency. A resonant slot in a small conductive box placed on the body has been shown to reduce these effects. The specific absorption rate is less than international health standards for most wearable antennas due to small transmitter power. This paper reports the linear relationship between power absorbed by biological tissues at different locations on the body and radiation efficiency based on numerical modeling (r = 0.99). While the -10 dB bandwidth of the antenna remained constant and equal to 12.5%, the maximum frequency shift occurred when the antenna was close to the elbow (6.61%) and on the thigh (5.86%). The smallest change was found on the torso (4.21%). Participants with body-mass index (BMI) between 17 and 29 kg/m 2 took part in experimental measurements, where the maximum frequency shift was 2.51%. Measurements showed better agreement with simulations on the upper arm. These experimental results demonstrate that the BMI for each individual had little effect on the performance of the antenna. Bioelectromagnetics. 39:25-34, 2018. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

Improvement of the Shock Absorption Ability of a Face Guard by Incorporating a Glass-Fiber-Reinforced Thermoplastic and Buffering Space

PubMed Central

Churei, Hiroshi; Takayanagi, Haruka; Iwasaki, Naohiko; Takahashi, Hidekazu; Uo, Motohiro

2018-01-01

This study aimed to evaluate the shock absorption ability of trial face guards (FGs) incorporating a glass-fiber-reinforced thermoplastic (GF) and buffering space. The mechanical properties of 3.2 mm and 1.6 mm thick commercial medical splint materials (Aquaplast, AP) and experimental GF prepared from 1.6 mm thick AP and fiberglass cloth were determined by a three-point bending test. Shock absorption tests were conducted on APs with two different thicknesses and two types of experimental materials, both with a bottom material of 1.6 mm thick AP and a buffering space of 30 mm in diameter (APS) and with either (i) 1.6 mm thick AP (AP-APS) or (ii)  1.6 mm thick GF (GF-APS) covering the APS. The GF exhibited significantly higher flexural strength (64.4 MPa) and flexural modulus (7.53 GPa) than the commercial specimens. The maximum load of GF-APS was 75% that of 3.2 mm AP, which is widely used clinically. The maximum stress of the GF-APS only could not be determined as its maximum stress is below the limits of the analysis materials used (<0.5 MPa). Incorporating a GF and buffering space would enhance the shock absorption ability; thus, the shock absorption ability increased while the total thickness and weight decreased. PMID:29854774

Improvement of the Shock Absorption Ability of a Face Guard by Incorporating a Glass-Fiber-Reinforced Thermoplastic and Buffering Space.

PubMed

Wada, Takahiro; Churei, Hiroshi; Takayanagi, Haruka; Iwasaki, Naohiko; Ueno, Toshiaki; Takahashi, Hidekazu; Uo, Motohiro

2018-01-01

This study aimed to evaluate the shock absorption ability of trial face guards (FGs) incorporating a glass-fiber-reinforced thermoplastic (GF) and buffering space. The mechanical properties of 3.2 mm and 1.6 mm thick commercial medical splint materials (Aquaplast, AP) and experimental GF prepared from 1.6 mm thick AP and fiberglass cloth were determined by a three-point bending test. Shock absorption tests were conducted on APs with two different thicknesses and two types of experimental materials, both with a bottom material of 1.6 mm thick AP and a buffering space of 30 mm in diameter (APS) and with either (i) 1.6 mm thick AP (AP-APS) or (ii)  1.6 mm thick GF (GF-APS) covering the APS. The GF exhibited significantly higher flexural strength (64.4 MPa) and flexural modulus (7.53 GPa) than the commercial specimens. The maximum load of GF-APS was 75% that of 3.2 mm AP, which is widely used clinically. The maximum stress of the GF-APS only could not be determined as its maximum stress is below the limits of the analysis materials used (<0.5 MPa). Incorporating a GF and buffering space would enhance the shock absorption ability; thus, the shock absorption ability increased while the total thickness and weight decreased.

Multi-Shaped Ag Nanoparticles in the Plasmonic Layer of Dye-Sensitized Solar Cells for Increased Power Conversion Efficiency.

PubMed

Song, Da Hyun; Kim, Ho-Sub; Suh, Jung Sang; Jun, Bong-Hyun; Rho, Won-Yeop

2017-06-04

The use of dye-sensitized solar cells (DSSCs) is widespread owing to their high power conversion efficiency (PCE) and low cost of manufacturing. We prepared multi-shaped Ag nanoparticles (NPs) and introduced them into DSSCs to further enhance their PCE. The maximum absorption wavelength of the multi-shaped Ag NPs is 420 nm, including the shoulder with a full width at half maximum (FWHM) of 121 nm. This is a broad absorption wavelength compared to spherical Ag NPs, which have a maximum absorption wavelength of 400 nm without the shoulder of 61 nm FWHM. Therefore, when multi-shaped Ag NPs with a broader plasmon-enhanced absorption were coated on a mesoporous TiO₂ layer on a layer-by-layer structure in DSSCs, the PCE increased from 8.44% to 10.22%, equivalent to an improvement of 21.09% compared to DSSCs without a plasmonic layer. To confirm the plasmon-enhanced effect on the composite film structure in DSSCs, the PCE of DSSCs based on the composite film structure with multi-shaped Ag NPs increased from 8.58% to 10.34%, equivalent to an improvement of 20.51% compared to DSSCs without a plasmonic layer. This concept can be applied to perovskite solar cells, hybrid solar cells, and other solar cells devices.

Low-Radiation Cellular Inductive Powering of Rodent Wireless Brain Interfaces: Methodology and Design Guide.

PubMed

Soltani, Nima; Aliroteh, Miaad S; Salam, M Tariqus; Perez Velazquez, Jose Luis; Genov, Roman

2016-08-01

This paper presents a general methodology of inductive power delivery in wireless chronic rodent electrophysiology applications. The focus is on such systems design considerations under the following key constraints: maximum power delivery under the allowable specific absorption rate (SAR), low cost and spatial scalability. The methodology includes inductive coil design considerations within a low-frequency ferrite-core-free power transfer link which includes a scalable coil-array power transmitter floor and a single-coil implanted or worn power receiver. A specific design example is presented that includes the concept of low-SAR cellular single-transmitter-coil powering through dynamic tracking of a magnet-less receiver spatial location. The transmitter coil instantaneous supply current is monitored using a small number of low-cost electronic components. A drop in its value indicates the proximity of the receiver due to the reflected impedance of the latter. Only the transmitter coil nearest to the receiver is activated. Operating at the low frequency of 1.5 MHz, the inductive powering floor delivers a maximum of 15.9 W below the IEEE C95 SAR limit, which is over three times greater than that in other recently reported designs. The power transfer efficiency of 39% and 13% at the nominal and maximum distances of 8 cm and 11 cm, respectively, is maintained.

The flaky porous Fe3O4 with tunable dimensions for enhanced microwave absorption performance in X and C bands

NASA Astrophysics Data System (ADS)

Zhao, Huanqin; Cheng, Yan; Liu, Wei; Yang, Zhihong; Zhang, Baoshan; Ji, Guangbin; Du, Youwei

2018-07-01

Special electric and magnetic characteristics make Fe3O4 widely applied in the electromagnetic (EM) wave absorption region. However, for pure Fe3O4, it is still a challenge to simultaneously obtain high absorption intensity and broadband absorption at a low thickness, owing to its low dielectric property. As we realized, flake configuration and the porous structure have obviously promote the EM wave absorption property. Because the former can lead to multi-reflection between flakes and the latter is conductive to interface polarization, flaky Fe3O4 with a porous and coarse surface was designed to overcome the deficiency of traditional Fe3O4 particles. The experimental results demonstrate that the flaky configuration is conductive to enhancing the dielectric coefficient and optimizing impedance matching. Moreover, the complex permittivity rises with the aspect ratio of the sheet. Under a suitable dimension, the flaky Fe3O4 could acquire targeted EM wave absorption capacity in the X band (8–12 GHz). In detail, the maximum reflection loss (RL) could reach a strong intensity of ‑49 dB at 2.05 mm. The effective absorption bandwidth (EAB) with RL below ‑10 dB is 4.32 (7.52–11.84) GHz, which is almost equivalent to the whole X band (8–12 GHz). Even more exciting, when regulating the thickness between 2.05 and 3.05 mm, the EAB could cover the entire C and X bands (4–12 GHz). This study provides a good reference for the future development of other ferromagnetic materials toward specific microwave bands.

The flaky porous Fe3O4 with tunable dimensions for enhanced microwave absorption performance in X and C bands.

PubMed

Zhao, Huanqin; Cheng, Yan; Liu, Wei; Yang, Zhihong; Zhang, Baoshan; Ji, Guangbin; Du, Youwei

2018-07-20

Special electric and magnetic characteristics make Fe 3 O 4 widely applied in the electromagnetic (EM) wave absorption region. However, for pure Fe 3 O 4 , it is still a challenge to simultaneously obtain high absorption intensity and broadband absorption at a low thickness, owing to its low dielectric property. As we realized, flake configuration and the porous structure have obviously promote the EM wave absorption property. Because the former can lead to multi-reflection between flakes and the latter is conductive to interface polarization, flaky Fe 3 O 4 with a porous and coarse surface was designed to overcome the deficiency of traditional Fe 3 O 4 particles. The experimental results demonstrate that the flaky configuration is conductive to enhancing the dielectric coefficient and optimizing impedance matching. Moreover, the complex permittivity rises with the aspect ratio of the sheet. Under a suitable dimension, the flaky Fe 3 O 4 could acquire targeted EM wave absorption capacity in the X band (8-12 GHz). In detail, the maximum reflection loss (RL) could reach a strong intensity of -49 dB at 2.05 mm. The effective absorption bandwidth (EAB) with RL below -10 dB is 4.32 (7.52-11.84) GHz, which is almost equivalent to the whole X band (8-12 GHz). Even more exciting, when regulating the thickness between 2.05 and 3.05 mm, the EAB could cover the entire C and X bands (4-12 GHz). This study provides a good reference for the future development of other ferromagnetic materials toward specific microwave bands.

Relative importance of black carbon, brown carbon, and absorption enhancement from clear coatings in biomass burning emissions

NASA Astrophysics Data System (ADS)

Pokhrel, Rudra P.; Beamesderfer, Eric R.; Wagner, Nick L.; Langridge, Justin M.; Lack, Daniel A.; Jayarathne, Thilina; Stone, Elizabeth A.; Stockwell, Chelsea E.; Yokelson, Robert J.; Murphy, Shane M.

2017-04-01

A wide range of globally significant biomass fuels were burned during the fourth Fire Lab at Missoula Experiment (FLAME-4). A multi-channel photoacoustic absorption spectrometer (PAS) measured dry absorption at 405, 532, and 660 nm and thermally denuded (250 °C) absorption at 405 and 660 nm. Absorption coefficients were broken into contributions from black carbon (BC), brown carbon (BrC), and lensing following three different methodologies, with one extreme being a method that assumes the thermal denuder effectively removes organics and the other extreme being a method based on the assumption that black carbon (BC) has an Ångström exponent of unity. The methodologies employed provide ranges of potential importance of BrC to absorption but, on average, there was a difference of a factor of 2 in the ratio of the fraction of absorption attributable to BrC estimated by the two methods. BrC absorption at shorter visible wavelengths is of equal or greater importance to that of BC, with maximum contributions of up to 92 % of total aerosol absorption at 405 nm and up to 58 % of total absorption at 532 nm. Lensing is estimated to contribute a maximum of 30 % of total absorption, but typically contributes much less than this. Absorption enhancements and the estimated fraction of absorption from BrC show good correlation with the elemental-carbon-to-organic-carbon ratio (EC / OC) of emitted aerosols and weaker correlation with the modified combustion efficiency (MCE). Previous studies have shown that BrC grows darker (larger imaginary refractive index) as the ratio of black to organic aerosol (OA) mass increases. This study is consistent with those findings but also demonstrates that the fraction of total absorption attributable to BrC shows the opposite trend: increasing as the organic fraction of aerosol emissions increases and the EC / OC ratio decreases.

Substitution determination of Fmoc‐substituted resins at different wavelengths

PubMed Central

Kley, Markus; Bächle, Dirk; Loidl, Günther; Meier, Thomas; Samson, Daniel

2017-01-01

In solid‐phase peptide synthesis, the nominal batch size is calculated using the starting resin substitution and the mass of the starting resin. The starting resin substitution constitutes the basis for the calculation of a whole set of important process parameters, such as the number of amino acid derivative equivalents. For Fmoc‐substituted resins, substitution determination is often performed by suspending the Fmoc‐protected starting resin in 20% (v/v) piperidine in DMF to generate the dibenzofulvene–piperidine adduct that is quantified by ultraviolet–visible spectroscopy. The spectrometric measurement is performed at the maximum absorption wavelength of the dibenzofulvene–piperidine adduct, that is, at 301.0 nm. The recorded absorption value, the resin weight and the volume are entered into an equation derived from Lambert–Beer's law, together with the substance‐specific molar absorption coefficient at 301.0 nm, in order to calculate the nominal substitution. To our knowledge, molar absorption coefficients between 7100 l mol−1 cm−1 and 8100 l mol−1 cm−1 have been reported for the dibenzofulvene–piperidine adduct at 301.0 nm. Depending on the applied value, the nominal batch size may differ up to 14%. In this publication, a determination of the molar absorption coefficients at 301.0 and 289.8 nm is reported. Furthermore, proof is given that by measuring the absorption at 289.8 nm the impact of wavelength accuracy is reduced. © 2017 The Authors Journal of Peptide Science published by European Peptide Society and John Wiley & Sons Ltd. PMID:28635051

[Biomechanical study on effects of bone mineral density on fixation strength of expansive pedicle screw].

PubMed

Gao, Mingxuan; Li, Xusheng; Zhen, Ping; Wu, Zhigang; Zhou, Shenghu; Tian, Qi; Lei, Wei

2013-08-01

To evaluate the fixation strength of expansive pedicle screw (EPS) at different bone mineral density (BMD) levels, further to provide theoretical evidence for the clinical application of the EPS in patients with osteoporosis. Fresh human cadaver spines (T12-L5 spines) were divided into 4 levels: normal BMD, osteopenia, osteoporosis, and severe osteoporosis according to the value of BMD, 12 vertebra in each level. Conventional pedicle screw (CPS) or EPS was implanted into the bilateral vertebra in CPS group and EPS group, respectively, 12 screws in each group per BMD level. Screw pullout tests were conducted. The maximum pullout strength, stiffness, and energy absorption were determined by an AG-IS material testing machine with constant rate of loading in a speed of 5 mm/min. With the decline of BMD from normal to severe osteoporosis level, the maximum pullout strength and the stiffness correspondingly declined (P < 0.05). In CPS group, the energy absorption gradually decreased (P < 0.05); in EPS group, significant difference was found between other different BMD levels (P < 0.05) except between normal BMD and osteopenia and between osteoporosis and severe osteoporosis (P > 0.05). At the same BMD level, the maximum pullout strength of EPS group was significantly larger than that of CPS group (P < 0.05); the stiffness of EPS group was significantly higher than that of CPS group (P < 0.05) except one at normal BMD level; and no significant difference was found in the energy absorption between 2 groups (P > 0.05) except one at osteopenia level. No significant difference was found in maximum pullout strength, stiffness, and energy absorption between EPS group at osteoporosis level and CPS group at osteopenia level (P > 0.05); however, the maximum pullout strength, stiffness, and energy absorption of EPS group at severe osteoporosis level were significantly lower than those of CPS group at osteopenia level (P < 0.05). Compared with CPS, the EPS can significantly improve the fixation strength, especially in patients with osteopenia or osteoporosis.

[Shock absorption of mouthguard materials--influence of temperature conditions and shore hardness on shock absorption].

PubMed

Tomita, Takashi; Tsukimura, Naoki; Ohno, Shigeru; Umekawa, Yoshitada; Sawano, Muneyuki; Fujimoto, Toshiki; Takamura, Masaaki; Majima, Aiko; Katakura, Yuusuke; Kurata, Akemi; Ohyama, Tetsuo; Ishigami, Tomohiko

2006-04-01

To consider changes in the physical properties of mouthguard materials with the change of temperature, shock-absorbing examination and Shore hardness measurement of existing MG materials and other elastic materials were carried out. Both examinations were done under two temperature conditions: at room temperature (25 degrees C) and simulated intraoral temperature (37 degrees C). In addition, a comparative study of the relation between Shore hardness and shock absorption of the materials was made. A self-made drop impact machine was used for the shock-absorbing examination. The thickness of a sample was assumed to be 3 mm. The loading was applied by dropping 3 kinds of steel ball, phi 10 mm (4.0 g), phi 15 mm (13.7 g), and phi 20 mm (32.6 g) from a height of 60 cm. The shock absorption of all materials was compared by the maximum impact force. Shore hardness was measured based on the JIS standard. The shock absorption of each material showed a different tendency depending on the loading condition. Furthermore, the shock absorption of the same material showed different results depending on the temperature condition. Shore hardness measurements tended to show low values with the condition of 37 degrees C for all materials. From the relation between shock absorption and Shore hardness, it was confirmed that there is a correlation between hardness and the maximum impact force in the materials that showed shock absorption by elastic deformation. Some materials showed high shock absorption compared with existing MG materials.

Energy absorption studied to reduce aircraft crash forces

NASA Technical Reports Server (NTRS)

1981-01-01

The NASA/FAA aircraft safety reseach programs for general aviation aircraft are discussed. Energy absorption of aircraft subflooring and redesign of interior flooring are being studied. The testing of energy absorbing configurations is described. The three NASA advanced concepts performed at neary the maximum possible amount of energy absorption, and one of two minimum modifications concepts performed well. Planned full scale tests are described. Airplane seat concepts are being considered.

FDTD modeling of solar energy absorption in silicon branched nanowires.

PubMed

Lundgren, Christin; Lopez, Rene; Redwing, Joan; Melde, Kathleen

2013-05-06

Thin film nanostructured photovoltaic cells are increasing in efficiency and decreasing the cost of solar energy. FDTD modeling of branched nanowire 'forests' are shown to have improved optical absorption in the visible and near-IR spectra over nanowire arrays alone, with a factor of 5 enhancement available at 1000 nm. Alternate BNW tree configurations are presented, achieving a maximum absorption of over 95% at 500 nm.

Long-term spectroscopic monitoring of the Luminous Blue Variable AG Carinae

NASA Astrophysics Data System (ADS)

Stahl, O.; Jankovics, I.; Kovács, J.; Wolf, B.; Schmutz, W.; Kaufer, A.; Rivinius, Th.; Szeifert, Th.

2001-08-01

We have extensively monitored the Luminous Blue Variable AG Car (HD 94910) spectroscopically. Our data cover the years 1989 to 1999. In this period, the star underwent almost a full S Dor cycle from visual minimum to maximum and back. Over several seasons, up to four months of almost daily spectra are available. Our data cover most of the visual spectral range with a high spectral resolution (lambda /Delta lambda ~ 20 000). This allows us to investigate the variability in many lines on time scales from days to years. The strongest variability occurs on a time scale of years. Qualitatively, the variations can be understood as changes of the effective temperature and radius, which are in phase with the optical light curve. Quantitatively, there are several interesting deviations from this behaviour, however. The Balmer lines show P Cygni profiles and have their maximum strength (both in equivalent width and line flux) after the peak of the optical light curve, at the descending branch of the light curve. The line-width during maximum phase is smaller than during minimum, but it has a local maximum close to the peak of the visual light curve. We derive mass-loss rates over the cycle from the Hα line and find the highest mass loss rates (log dot {M}/({M}_sun yr-1) ~ -3.8, about a factor of five higher than in the minimum, where we find log dot {M}/({M}_sun yr-1) ~ -4.5) after the visual maximum. Line-splitting is very commonly observed, especially on the rise to maximum and on the descending branch from maximum. The components are very long-lived (years) and are probably unrelated to similar-looking line-splitting events in normal supergiants. Small apparent accelerations of the components are observed. The change in radial velocity could be due to successive narrowing of the components, with the absorption disappearing at small expansion velocities first. In general, the line-splitting is more likely the result of missing absorption at intermediate velocities than of excess absorption at the velocities of the components. The HeI lines and other lines which form deep in the atmosphere show the most peculiar variations. The HeI lines show a central absorption with variable blue- and red-shifted emission components. Due to the variations of the emission components, the HeI lines can change their line profile from a normal P Cyg profile to an inverse P Cyg-profile or double-peak emission. In addition, very broad (+/-1500 km s-1) emission wings are seen at the strongest HeI lines of AG Car. At some phases, a blue-shifted absorption is also present. The central absorption of the HeI lines is blue-shifted before and red-shifted after maximum. Possibly, we directly see the expansion and contraction of the photosphere. If this explanation is correct, the velocity of the continuum-forming layer is not dominated by expansion but is only slightly oscillating around the systemic velocity. Based on observations collected at the European Southern Observatory at La Silla, Chile.

Surface Plasmon Absorption in MoS2 and Graphene-MoS2 Micro-Gratings and the Impact of a Liquid Crystal Substrate (Postprint)

DTIC Science & Technology

2018-04-27

ABSTRACT (Maximum 200 words) The absorption coefficients of a far-infrared wave are calculated at normal incidence for MoS2 and graphene-MoS2 micro...ribbon gratings placed between a nematic LC and an isotropic dielectric medium. Maxima in the absorption spectra, which are related to the...excitation of the surface plasmons in micro-ribbons of these gratings, are observed. The spectral position of absorption maxima depends on the grating spacing

Index extraction for electromagnetic field evaluation of high power wireless charging system.

PubMed

Park, SangWook

2017-01-01

This paper presents the precise dosimetry for highly resonant wireless power transfer (HR-WPT) system using an anatomically realistic human voxel model. The dosimetry for the HR-WPT system designed to operate at 13.56 MHz frequency, which one of the ISM band frequency band, is conducted in the various distances between the human model and the system, and in the condition of alignment and misalignment between transmitting and receiving circuits. The specific absorption rates in the human body are computed by the two-step approach; in the first step, the field generated by the HR-WPT system is calculated and in the second step the specific absorption rates are computed with the scattered field finite-difference time-domain method regarding the fields obtained in the first step as the incident fields. The safety compliance for non-uniform field exposure from the HR-WPT system is discussed with the international safety guidelines. Furthermore, the coupling factor concept is employed to relax the maximum allowable transmitting power. Coupling factors derived from the dosimetry results are presented. In this calculation, the external magnetic field from the HR-WPT system can be relaxed by approximately four times using coupling factor in the worst exposure scenario.

Assessment of specific energy absorption rate (SAR) in the head from a TETRA handset.

PubMed

Dimbylow, Peter; Khalid, Mohammed; Mann, Simon

2003-12-07

Finite-difference time-domain (FDTD) calculations of the specific energy absorption rate (SAR) from a representative TETRA handset have been performed in an anatomically realistic model of the head. TETRA (Terrestrial Trunked Radio) is a modern digital private mobile radio system designed to meet the requirements of professional users, such as the police and fire brigade. The current frequency allocations in the UK are 380-385 MHz and 390-395 MHz for the public sector network. A comprehensive set of calculations of SAR in the head was performed for positions of the handset in front of the face and at both sides of the head. The representative TETRA handset considered. operating at 1 W in normal use, will show compliance with both the ICNIRP occupational and public exposure restrictions. The handset with a monopole antenna operating at 3 W in normal use will show compliance with both the ICNIRP occupational and public exposure restrictions. The handset with a helical antenna operating at 3 W in normal use will show compliance with the ICNIRP occupational exposure restriction but will be over the public exposure restriction by up to approximately 50% if kept in the position of maximum SAR for 6 min continuously.

Octahedron Fe3O4 particles supported on 3D MWCNT/graphene foam: In-situ method and application as a comprehensive microwave absorption material

NASA Astrophysics Data System (ADS)

Shi, Luolin; Zhao, Yan; Li, Ye; Han, Xiao; Zhang, Tong

2017-09-01

In this work, we used in-situ method to directly prepare a novel structure consisting of well-distributed octahedron Fe3O4 particles, porous graphene foam (GF) and fibrous multiwalled carbon nanotube (MWCNT): started with an intense stir to anchor Fe3+ on the surfaces of graphene oxide and oxided MWCNT, followed by solvothermal reaction to synthesize 3D lightweight Fe3O4/MWCNT/GF hybrids with high performance microwave absorption (MA). The maximum Reflection Loss (RL) value of -35.30 dB and 9.01 GHz bandwidth with RL below -10 dB detected with the thickness of 3.0 mm are achieved by Fe3O4/MWCNT/GF with an ultralow bulk density of 5.0 mg cm-3, of which the Specific Microwave Absorption Performance is much higher than most available MA materials reported. Impedance matching, high loss characteristic, interfacial polarization and polarization relaxation significantly improve MA properties, which serves as a guide for fabricating comprehensive MA materials enjoying numerous advantages of high RL value, broad bandwidth, low density and thin thickness.

Performance optimization of dye-sensitized solar cells by multilayer gradient scattering architecture of TiO2 microspheres.

PubMed

Li, Mingyue; Li, Meiya; Liu, Xiaolian; Bai, Lihua; Luoshan, Mengdai; Lei, Wen; Wang, Zhen; Zhu, Yongdan; Zhao, Xingzhong

2017-01-20

TiO 2 microspheres (TMSs) with unique hierarchical structure and unusual high specific surface area are synthesized and incorporated into a photoanode in various TMS multilayer gradient architectures to form novel photoanodes and dye-sensitized solar cells (DSSCs). Significant influences of these architectures on the photoelectric properties of DSSCs are obtained. The DSSC with the optimal TMS gradient-ascent architecture of M036 has the largest amounts of dye absorption, strongest light absorption, longest electron lifetime and lowest electron recombination, and thus exhibits the maximum short circuit current density (J sc ) of 16.49 mA cm -2 and photoelectric conversion efficiency (η) of 7.01%, notably higher than those of conventional DSSCs by 21% and 22%, respectively. These notable improvements in the properties of DSSCs can be attributed to the TMS gradient-ascent architecture of M036 which can most effectively increase dye absorption and localize incident light within the photoanode by the light scattering of TMSs, and thus utilize the incident light thoroughly. This study provides an optimized and universal configuration for the scattering microspheres incorporated in the hybrid photoanode, which can significantly improve the performance of DSSCs.

Supersaturation-nucleation behavior of poorly soluble drugs and its impact on the oral absorption of drugs in thermodynamically high-energy forms.

PubMed

Ozaki, Shunsuke; Minamisono, Takuma; Yamashita, Taro; Kato, Takashi; Kushida, Ikuo

2012-01-01

In order to better understand the oral absorption behavior of poorly water-soluble drugs, their supersaturation-nucleation behavior was characterized in fasted state simulated intestinal fluid. The induction time (t(ind)) for nucleation was measured for four model drugs: itraconazole, erlotinib, troglitazone, and PLX4032. Supersaturated solutions were prepared by solvent shift method, and nucleation initiation was monitored by ultraviolet detection. The relationship between t(ind) and degree of supersaturation was analyzed in terms of classical nucleation theory. The defined supersaturation stability proved to be compound specific. Clinical data on oral absorption were investigated for drugs in thermodynamically high-energy forms such as amorphous forms and salts and was compared with in vitro supersaturation-nucleation characteristics. Solubility-limited maximum absorbable dose was proportionate to intestinal effective drug concentrations, which are related to supersaturation stability and thermodynamic solubility. Supersaturation stability was shown to be an important factor in determining the effect of high-energy forms. The characterization of supersaturation-nucleation behavior by the presented method is, therefore, valuable for assessing the potential absorbability of poorly water-soluble drugs. Copyright © 2011 Wiley-Liss, Inc.

Theoretical Prediction of Si 2–Si 33 Absorption Spectra

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhao, Li -Zhen; Lu, Wen -Cai; Qin, Wei

Here, the optical absorption spectra of Si 2–Si 33 clusters were systematically studied by a time-dependent density functional theory approach. The calculations revealed that the absorption spectrum becomes significantly broad with increasing cluster size, stretching from ultraviolet to the infrared region. The absorption spectra are closely related to the structural motifs. With increasing cluster size, the absorption intensity of cage structures gradually increases, but the absorption curves of the prolate and the Y-shaped structures are very sensitive to cluster size. If the transition energy reaches ~12 eV, it is noted that all the clusters have remarkable absorption in deep ultravioletmore » region of 100–200 nm, and the maximum absorption intensity is ~100 times that in the visible region. Further, the optical responses to doping in the Si clusters were studied.« less

Theoretical Prediction of Si 2–Si 33 Absorption Spectra

DOE PAGES

Zhao, Li -Zhen; Lu, Wen -Cai; Qin, Wei; ...

2017-07-07

Here, the optical absorption spectra of Si 2–Si 33 clusters were systematically studied by a time-dependent density functional theory approach. The calculations revealed that the absorption spectrum becomes significantly broad with increasing cluster size, stretching from ultraviolet to the infrared region. The absorption spectra are closely related to the structural motifs. With increasing cluster size, the absorption intensity of cage structures gradually increases, but the absorption curves of the prolate and the Y-shaped structures are very sensitive to cluster size. If the transition energy reaches ~12 eV, it is noted that all the clusters have remarkable absorption in deep ultravioletmore » region of 100–200 nm, and the maximum absorption intensity is ~100 times that in the visible region. Further, the optical responses to doping in the Si clusters were studied.« less

[The Diagnostics of Detonation Flow External Field Based on Multispectral Absorption Spectroscopy Technology].

PubMed

Lü, Xiao-jing; Li, Ning; Weng, Chun-sheng

2016-03-01

Compared with traditional sampling-based sensing method, absorption spectroscopy technology is well suitable for detonation flow diagnostics, since it can provide with us fast response, nonintrusive, sensitive solution for situ measurements of multiple flow-field parameters. The temperature and concentration test results are the average values along the laser path with traditional absorption spectroscopy technology, while the boundary of detonation flow external field is unknown and it changes all the time during the detonation engine works, traditional absorption spectroscopy technology is no longer suitable for detonation diagnostics. The trend of line strength with temperature varies with different absorption lines. By increasing the number of absorption lines in the test path, more information of the non-uniform flow field can be obtained. In this paper, based on multispectral absorption technology, the reconstructed model of detonation flow external field distribution was established according to the simulation results of space-time conservation element and solution element method, and a diagnostic method of detonation flow external field was given. The model deviation and calculation error of the least squares method adopted were studied by simulation, and the maximum concentration and temperature calculation error was 20.1% and 3.2%, respectively. Four absorption lines of H2O were chosen and detonation flow was scanned at the same time. The detonation external flow testing system was set up for the valveless gas-liquid continuous pulse detonation engine with the diameter of 80 mm. Through scanning H2O absorption lines with a high frequency of 10 kHz, the on-line detection of detonation external flow was realized by direct absorption method combined with time-division multiplexing technology, and the reconstruction of dynamic temperature distribution was realized as well for the first time, both verifying the feasibility of the test method. The test results show that both of the temperature and H2O concentration rose with the arrival of detonation wave. With the increase of the vertical distance between the detonation tube nozzle and the laser path, the time of temperature and concentration coming to the peak delayed, and the temperature variation trend tended to slow down. At 20 cm from detonation tube nozzle, the maximum temperature hit 1 329 K and the maximum H2O concentration of 0.19 occurred at 4 ms after ignition. The research can provide with us the support for expanding the detonation test field with absorption spectroscopy technology, and can also help to promote the detonation mechanism research and to enhance the level of detonation engine control technology.

Adsorption of methyl orange on mesoporous γ-Fe2O3/SiO2 nanocomposites

NASA Astrophysics Data System (ADS)

Deligeer, W.; Gao, Y. W.; Asuha, S.

2011-02-01

Mesoporous γ-Fe2O3/SiO2 nanocomposite containing 30 mol% of γ-Fe2O3 was prepared by a template-free sol-gel method, and its removal ability for methyl orange (MO) was investigated. The nanocomposite was characterized using X-ray powder diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscope (SEM), Fourier transform infrared (FTIR) absorption measurements, nitrogen adsorption-desorption measurements, and magnetic measurements. The synthesized γ-Fe2O3/SiO2 nanocomposite has a mesoporous structure with an average pore size of 3.5 nm and a specific surface area of 245 m2/g, and it exhibits ferrimagnetic characteristics with the maximum saturation magnetization of 20.9 emu/g. The adsorption of MO on the nanocomposite reaches the maximum adsorbed percentage of ca. 80% within a few minutes, showing that most of MO can be removed in a short time. The MO adsorption data fit well with both Langmuir and Freundlich adsorption isotherms. The maximum adsorption capacity of MO is estimated to be 476 mg/g.

Effects of maximum aggregate size on UPV of brick aggregate concrete.

PubMed

Mohammed, Tarek Uddin; Mahmood, Aziz Hasan

2016-07-01

Investigation was carried out to study the effects of maximum aggregate size (MAS) (12.5mm, 19.0mm, 25.0mm, 37.5mm, and 50.0mm) on ultrasonic pulse velocity (UPV) of concrete. For investigation, first class bricks were collected and broken to make coarse aggregate. The aggregates were tested for specific gravity, absorption capacity, unit weight, and abrasion resistance. Cylindrical concrete specimens were made with different sand to aggregate volume ratio (s/a) (0.40 and 0.45), W/C ratio (0.45, 0.50, and 0.55), and cement content (375kg/m(3) and 400kg/m(3)). The specimens were tested for compressive strength and Young's modulus. UPV through wet specimen was measured using Portable Ultrasonic Non-destructive Digital Indicating Tester (PUNDIT). Results indicate that the pulse velocity through concrete increases with an increase in MAS. Relationships between UPV and compressive strength; and UPV and Young's modulus of concrete are proposed for different maximum sizes of brick aggregate. Copyright © 2016 Elsevier B.V. All rights reserved.

Sound Absorption Characteristics of Aluminum Foams Treated by Plasma Electrolytic Oxidation

PubMed Central

Jin, Wei; Liu, Jiaan; Wang, Zhili; Wang, Yonghua; Cao, Zheng; Liu, Yaohui; Zhu, Xianyong

2015-01-01

Open-celled aluminum foams with different pore sizes were fabricated. A plasma electrolytic oxidation (PEO) treatment was applied on the aluminum foams to create a layer of ceramic coating. The sound absorption coefficients of the foams were measured by an impedance tube and they were calculated by a transfer function method. The experimental results show that the sound absorption coefficient of the foam increases gradually with the decrease of pore size. Additionally, when the porosity of the foam increases, the sound absorption coefficient also increases. The PEO coating surface is rough and porous, which is beneficial for improvement in sound absorption. After PEO treatment, the maximum sound absorption of the foam is improved to some extent. PMID:28793653

Two-photon absorption spectrum of the photoinitiator Lucirin TPO-L

NASA Astrophysics Data System (ADS)

Mendonca, C. R.; Correa, D. S.; Baldacchini, T.; Tayalia, P.; Mazur, E.

2008-03-01

Two-photon absorption induced polymerization provides a powerful method for the fabrication of intricate three-dimensional microstructures. Recently, Lucirin TPO-L was shown to be a photoinitiator with several advantageous properties for two-photon induced polymerization. Here we measure the two-photon absorption cross-section spectrum of Lucirin TPO-L, which presents a maximum of 1.2 GM at 610 nm. Despite its small two-photon absorption cross-section, it is possible to fabricate excellent microstructures by two-photon polymerization due to the high polymerization quantum yield of Lucirin TPO-L. These results indicate that optimization of the two-photon absorption cross-section is not the only material parameter to be considered when searching for new photoinitiators for microfabrication via two-photon absorption.

Substitution determination of Fmoc-substituted resins at different wavelengths.

PubMed

Eissler, Stefan; Kley, Markus; Bächle, Dirk; Loidl, Günther; Meier, Thomas; Samson, Daniel

2017-10-01

In solid-phase peptide synthesis, the nominal batch size is calculated using the starting resin substitution and the mass of the starting resin. The starting resin substitution constitutes the basis for the calculation of a whole set of important process parameters, such as the number of amino acid derivative equivalents. For Fmoc-substituted resins, substitution determination is often performed by suspending the Fmoc-protected starting resin in 20% (v/v) piperidine in DMF to generate the dibenzofulvene-piperidine adduct that is quantified by ultraviolet-visible spectroscopy. The spectrometric measurement is performed at the maximum absorption wavelength of the dibenzofulvene-piperidine adduct, that is, at 301.0 nm. The recorded absorption value, the resin weight and the volume are entered into an equation derived from Lambert-Beer's law, together with the substance-specific molar absorption coefficient at 301.0 nm, in order to calculate the nominal substitution. To our knowledge, molar absorption coefficients between 7100 l mol -1  cm -1 and 8100 l mol -1  cm -1 have been reported for the dibenzofulvene-piperidine adduct at 301.0 nm. Depending on the applied value, the nominal batch size may differ up to 14%. In this publication, a determination of the molar absorption coefficients at 301.0 and 289.8 nm is reported. Furthermore, proof is given that by measuring the absorption at 289.8 nm the impact of wavelength accuracy is reduced. © 2017 The Authors Journal of Peptide Science published by European Peptide Society and John Wiley & Sons Ltd. © 2017 The Authors Journal of Peptide Science published by European Peptide Society and John Wiley & Sons Ltd.

DISCOVERY OF THE TRANSITION OF A MINI-BROAD ABSORPTION LINE INTO A BROAD ABSORPTION LINE IN THE SDSS QUASAR J115122.14+020426.3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hidalgo, Paola Rodriguez; Eracleous, Michael; Charlton, Jane

We present the detection of a rare case of dramatic strengthening in the UV absorption profiles in the spectrum of the quasar J115122.14+020426.3 between observations {approx}2.86 yr apart in the quasar rest frame. A spectrum obtained in 2001 by the Sloan Digital Sky Survey shows a C IV ''mini-broad'' absorption line (FWHM = 1220 km s{sup -1}) with a maximum blueshift velocity of {approx}9520 km s{sup -1}, while a later spectrum from the Very Large Telescope shows a significantly broader and stronger absorption line, with a maximum blueshift velocity of {approx}12, 240 km s{sup -1} that qualifies as a broadmore » absorption line. A similar variability pattern is observed in two additional systems at lower blueshifted velocities and in the Ly{alpha} and N V transitions as well. One of the absorption systems appears to be resolved and shows evidence for partial covering of the quasar continuum source (C{sub f} {approx} 0.65), indicating a transverse absorber size of, at least, {approx}6 Multiplication-Sign 10{sup 16} cm. In contrast, a cluster of narrower C IV lines appears to originate in gas that fully covers the continuum and broad emission line sources. There is no evidence for changes in the centroid velocity of the absorption troughs. This case suggests that at least some of the absorbers that produce ''mini-broad'' and broad absorption lines in quasar spectra do not belong to intrinsically separate classes. Here, the ''mini-broad'' absorption line is most likely interpreted as an intermediate phase before the appearance of a broad absorption line due to their similar velocities. While the current observations do not provide enough constraints to discern among the possible causes for this variability, future monitoring of multiple transitions at high resolution will help achieve this goal.« less

How Much Cranberry Juice Is in Cranberry-Apple Juice? A General Chemistry Spectrophotometric Experiment

ERIC Educational Resources Information Center

Edionwe, Etinosa; Villarreal, John R.; Smith, K. Christopher

2011-01-01

A laboratory experiment that spectrophotometrically determines the percent of cranberry juice in cranberry-apple juice is described. The experiment involves recording an absorption spectrum of cranberry juice to determine the wavelength of maximum absorption, generating a calibration curve, and measuring the absorbance of cranberry-apple juice.…

Influence of refractive index and solar concentration on optical power absorption in slabs

NASA Technical Reports Server (NTRS)

Williams, M. D.

1988-01-01

The optical power absorbed by a slab at the focus of a parabolic dish concentrator is calculated. The calculations are plotted versus maximum angle of incidence of irradiation (which corresponds to solar concentration) with absorption coefficient as a parameter for several different indices of refraction that represent real materials.

Exciton-polariton state in nanocrystalline SiC films

NASA Astrophysics Data System (ADS)

Semenov, A. V.; Lopin, A. V.

2016-05-01

We studied the features of optical absorption in the films of nanocrystalline SiC (nc-SiC) obtained on the sapphire substrates by the method of direct ion deposition. The optical absorption spectra of the films with a thickness less than ~500 nm contain a maximum which position and intensity depend on the structure and thickness of the nc-SiC films. The most intense peak at 2.36 eV is observed in the nc-SiC film with predominant 3C-SiC polytype structure and a thickness of 392 nm. Proposed is a resonance absorption model based on excitation of exciton polaritons in a microcavity. In the latter, under the conditions of resonance, there occurs strong interaction between photon modes of light with λph=521 nm and exciton of the 3С polytype with an excitation energy of 2.36 eV that results in the formation of polariton. A mismatch of the frequencies of photon modes of the cavity and exciton explains the dependence of the maximum of the optical absorption on the film thickness.

Combined optical and photoelectric study of the photocycle of 13-cis bacteriorhodopsin.

PubMed Central

Gergely, C; Ganea, C; Váró, G

1994-01-01

The photocycle of the 13-cis retinal containing bacteriorhodopsin was studied by three different techniques. The optical multichannel analyzer monitored the spectral changes during the photocycle and gave information about the number and the spectrum of the intermediates. The absorption kinetic measurements provided the possibility of following the absorbance changes at several characteristic wavelengths. The electric signal provided information about the charge motions during the photocycle. The results reveal the existence of two intermediates in the 13-cis photocycle, one with a short lifetime having an average of 1.7 microseconds and an absorption maximum at 620 nm. The other, a long-living intermediate, has a lifetime of about 50 ms and an absorption maximum around 585 nm. The data analysis suggests that these intermediates are in two parallel branches of the photocycle, and branching from the intermediate with the shorter lifetime might be responsible for the light-adaptation process. PMID:7948698

Toothbrush abrasion of paint-on resins for shade modification and crown resins: effect of water absorption.

PubMed

Fujii, Koichi; Arikawa, Hiroyuki; Kanie, Takahito; Ban, Seiji

2004-06-01

In order to investigate the clinical application of paint-on resins, the effect of water absorption on toothbrush abrasion and light transmittance of ten crown resins including three paint-on resins was examined. Water absorption into each material ranged from 0.29 to 0.89 mg/cm2 after storage in distilled-water for 6 weeks and their hardnesses decreased by 3.5-22.3%. Maximum surface roughness (Rmax) of the materials stored in distilled water for 6 weeks increased with an increasing number of toothbrush abrasion cycles and ranged from 1.9 to 10.5 microm after 100,000 cycles. Also, Maximum depth and weight loss as an indicator of the amount of each material lost by abrasion showed similar behaviors similar to Rmax. These results indicated that the abrasion resistance of paint-on resins was located in the middle among all materials examined.

Development of a Physiologically Relevant Population Pharmacokinetic in Vitro-in Vivo Correlation Approach for Designing Extended-Release Oral Dosage Formulation.

PubMed

Kim, Tae Hwan; Shin, Soyoung; Bulitta, Jürgen B; Youn, Yu Seok; Yoo, Sun Dong; Shin, Beom Soo

2017-01-03

Establishing a level A in vitro-in vivo correlation (IVIVC) for a drug with complex absorption kinetics is challenging. The objective of the present study was to develop an IVIVC approach based on population pharmacokinetic (POP-PK) modeling that incorporated physiologically relevant absorption kinetics. To prepare three extended release (ER) tablets of loxoprofen, three types of hydroxypropyl methylcellulose (HPMC 100, 4000, and 15000 cps) were used as drug release modifiers, while lactose and magnesium stearate were used as the diluent and lubricant, respectively. An in vitro dissolution test in various pH conditions showed that loxoprofen dissolution was faster at higher pH. The in vivo pharmacokinetics of loxoprofen was assessed following oral administration of the different loxoprofen formulations to Beagle dogs (n = 22 in total). Secondary peaks or shoulders were observed in many of the individual plasma concentration vs time profiles after ER tablet administration, which may result from secondary absorption in the intestine due to a dissolution rate increase under intestinal pH compared to that observed at stomach pH. In addition, in vivo oral bioavailability was found to decrease with prolonged drug dissolution, indicating site-specific absorption. Based on the in vitro dissolution and in vivo absorption data, a POP-PK IVIVC model was developed using S-ADAPT software. pH-dependent biphasic dissolution kinetics, described using modified Michaelis-Menten kinetics with varying V max , and site-specific absorption, modeled using a changeable absorbed fraction parameter, were applied to the POP-PK IVIVC model. To experimentally determine the biphasic dissolution profiles of the ER tablets, another in vitro dissolution test was conducted by switching dissolution medium pH based on an in vivo estimate of gastric emptying time. The model estimated, using linear regression, that in vivo initial maximum dissolution rate (V max (0) in vivo ) was highly correlated (r 2 > 0.998) with in vitro (V max (0) in vitro ), indicating that in vivo dissolution profiles obtained from POP-PK modeling could be converted to in vitro dissolution profiles and vice versa. Monte Carlo simulations were performed for model validation, and prediction errors for C max and AUC were all within the acceptable range (90 to 110%) according to the FDA guidelines. The developed model was successfully applied for the prediction of in vivo pharmacokinetics of a loxoprofen double-layered tablet using the in vitro dissolution profile. In conclusion, a level A IVIVC approach was developed and validated using population modeling that accounted for pH-dependent dissolution and site-specific absorption. Excellent correlations were observed between in vitro and in vivo dissolution profiles. This new approach holds great promise for the establishment of IVIVCs for drug and formulation development where absorption kinetics strongly depend on complex physiologically absorption processes.

Gold nanoparticles prepared by electro-exploding wire technique in aqueous solutions

NASA Astrophysics Data System (ADS)

Kumar, Lalit; Kapoor, Akanksha; Meghwal, Mayank; Annapoorni, S.

2016-05-01

This article presents an effective approach for the synthesis of Au nanoparticles via an environmentally benevolent electro-exploding wire (EEW) technique. In this process, Au nanoparticles evolve through the plasma generated from the parent Au metal. Compared to other typical chemical methods, electro-exploding wire technique is a simple and economical technique which normally operates in water or organic liquids under ambient conditions. Efficient size control was achieved using different aqueous medium like (1mM) NaCl, deionized water and aqueous solution of sodium hydroxide (NaOH, pH 9.5) using identical electro-exploding conditions. The gold nanoparticles exhibited the UV-vis absorption spectrum with a maximum absorption band at 530 nm, similar to that of gold nanoparticles chemically prepared in a solution. The mechanism of size variation of Au nanoparticles is also proposed. The results obtained help to develop methodologies for the control of EEW based nanoparticle growth and the functionalization of nanoparticle surfaces by specific interactions.

Post-absorptive muscle protein turnover affects resistance training hypertrophy

PubMed Central

Reidy, Paul T.; Borack, Michael S.; Markofski, Melissa M.; Dickinson, Jared M.; Fry, Christopher S.; Deer, Rachel R.; Volpi, Elena; Rasmussen, Blake B.

2017-01-01

Purpose Acute bouts of resistance exercise and subsequent training alters protein turnover in skeletal muscle. The mechanisms responsible for the changes in basal post-absorptive protein turnover and its impact on muscle hypertrophy following resistance exercise training are unknown. To determine whether post-absorptive muscle protein turnover following 12 weeks of resistance exercise training (RET) plays a role in muscle hypertrophy. In addition, we were interested in determining potential molecular mechanisms responsible for altering post-training muscle protein turnover. Methods Healthy young men (n=31) participated in supervised whole body progressive RET at 60-80% 1 repetition maximum (1-RM), 3d/wk for 3 months. Pre- and post-training vastus lateralis muscle biopsies and blood samples taken during an infusion of 13C6 and 15N phenylalanine and were used to assess skeletal muscle protein turnover in the post-absorptive state. Lean body mass (LBM), muscle strength (determined by dynamometry), vastus lateralis muscle thickness (MT), myofiber type-specific cross-sectional area (CSA), and mRNA were assessed pre- and post-RET. Results RET increased strength (12-40%), LBM (∼5%), MT (∼15%) and myofiber CSA (∼20%) (p<0.05). Muscle protein synthesis (MPS) increased 24% while muscle protein breakdown (MPB) decreased 21% respectively. These changes in protein turnover resulted in an improved net muscle protein balance in the basal state following RET. Further, the change in basal MPS is positively associated (r=0.555, p=0.003) with the change in muscle thickness. Conclusion Post-absorptive muscle protein turnover is associated with muscle hypertrophy during resistance exercise training. PMID:28280974

Absorption of ethanol, acetone, benzene and 1,2-dichloroethane through human skin in vitro: a test of diffusion model predictions.

PubMed

Gajjar, Rachna M; Kasting, Gerald B

2014-11-15

The overall goal of this research was to further develop and improve an existing skin diffusion model by experimentally confirming the predicted absorption rates of topically-applied volatile organic compounds (VOCs) based on their physicochemical properties, the skin surface temperature, and the wind velocity. In vitro human skin permeation of two hydrophilic solvents (acetone and ethanol) and two lipophilic solvents (benzene and 1,2-dichloroethane) was studied in Franz cells placed in a fume hood. Four doses of each (14)C-radiolabed compound were tested - 5, 10, 20, and 40μLcm(-2), corresponding to specific doses ranging in mass from 5.0 to 63mgcm(-2). The maximum percentage of radiolabel absorbed into the receptor solutions for all test conditions was 0.3%. Although the absolute absorption of each solvent increased with dose, percentage absorption decreased. This decrease was consistent with the concept of a stratum corneum deposition region, which traps small amounts of solvent in the upper skin layers, decreasing the evaporation rate. The diffusion model satisfactorily described the cumulative absorption of ethanol; however, values for the other VOCs were underpredicted in a manner related to their ability to disrupt or solubilize skin lipids. In order to more closely describe the permeation data, significant increases in the stratum corneum/water partition coefficients, Ksc, and modest changes to the diffusion coefficients, Dsc, were required. The analysis provided strong evidence for both skin swelling and barrier disruption by VOCs, even by the minute amounts absorbed under these in vitro test conditions. Copyright © 2014 Elsevier Inc. All rights reserved.

Modulation of electromagnetic and absorption properties in 18-26.5 GHz frequency range of strontium hexaferrites with doping of cobalt-zirconium

NASA Astrophysics Data System (ADS)

Pubby, Kunal; Narang, Sukhleen Bindra; Kaur, Prabhjyot; Chawla, S. K.

2017-05-01

Hexaferrite nano-particles of stoichiometric composition {{Sr}}{({{CoZr}})_x}{{F}}{{{e}}_{12 - 2x}}{{{O}}_{19}}, with x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0 were prepared using sol-gel auto-combustion route owing to its advantages such as low sintering temperature requirement, homogeneity and uniformity of grains. Tartaric acid as a fuel was utilized to complete the chemical reaction. The goal of this study is to analyse the effect of co-substitution of cobalt and zirconium on the electromagnetic and absorption properties of pure {{SrF}}{{{e}}_{12}}{{{O}}_{19}} hexaferrite. The properties were measured on the rectangular pellets of thickness 2.5 mm for K-frequency band using Vector Network Analyzer. The doping of Co-Zr has resulted in increase in real as well as imaginary parts of permittivity. The values of real permittivity lie in the range 3.6-7.0 for all the composition. The real part of permeability remains in range 0.7-1.6 in the studied frequency band for all the samples and shows slightly increasing trend with frequency. The maximum values of dielectric loss tangent peak (3.04) and magnetic loss tangent peak (2.34), among all the prepared compositions, have been observed for composition x = 0.2. Compositions with x = 0.6 and x = 0.0 also have high dielectric and magnetic loss peaks. Dielectric loss peaks are attributed to dielectric resonance and magnetic loss peaks are attributed to natural resonance. Experimentally determined reflection loss results show that all six compositions of prepared series have high values of absorption to propose them as single-layer absorbers in 18-26.5 GHz frequency range. The composition with x = 0.2 has maximum absorption capacity with reflection loss peak of -37.2 dB at 24.3 GHz frequency. The undoped composition also has high absorption peak (-25.46 dB), but -10 dB absorption bandwidth is minimum (2.2 GHz) out of the present series. Maximum absorption bandwidth is obtained for x = 1.0 (4.1 GHz). Other doped compositions also have high absorption bandwidth in range 3.4-3.9 GHz. The results of absorption were related to the dielectric phase angle to conclude that high electro-magnetic losses are dominant factor in deciding absorption properties of ferrites in comparison to impedance matching.

Analysis of RF exposure in the head tissues of children and adults

NASA Astrophysics Data System (ADS)

Wiart, J.; Hadjem, A.; Wong, M. F.; Bloch, I.

2008-07-01

This paper analyzes the radio frequencies (RF) exposure in the head tissues of children using a cellular handset or RF sources (a dipole and a generic handset) at 900, 1800, 2100 and 2400 MHz. Based on magnetic resonance imaging, child head models have been developed. The maximum specific absorption rate (SAR) over 10 g in the head has been analyzed in seven child and six adult heterogeneous head models. The influence of the variability in the same age class is carried out using models based on a morphing technique. The SAR over 1 g in specific tissues has also been assessed in the different types of child and adult head models. Comparisons are performed but nevertheless need to be confirmed since they have been derived from data sets of limited size. The simulations that have been performed show that the differences between the maximum SAR over 10 g estimated in the head models of the adults and the ones of the children are small compared to the standard deviations. But they indicate that the maximum SAR in 1 g of peripheral brain tissues of the child models aged between 5 and 8 years is about two times higher than in adult models. This difference is not observed for the child models of children above 8 years old: the maximum SAR in 1 g of peripheral brain tissues is about the same as the one in adult models. Such differences can be explained by the lower thicknesses of pinna, skin and skull of the younger child models.

A method for safety testing of radiofrequency/microwave-emitting devices using MRI.

PubMed

Alon, Leeor; Cho, Gene Y; Yang, Xing; Sodickson, Daniel K; Deniz, Cem M

2015-11-01

Strict regulations are imposed on the amount of radiofrequency (RF) energy that devices can emit to prevent excessive deposition of RF energy into the body. In this study, we investigated the application of MR temperature mapping and 10-g average specific absorption rate (SAR) computation for safety evaluation of RF-emitting devices. Quantification of the RF power deposition was shown for an MRI-compatible dipole antenna and a non-MRI-compatible mobile phone via phantom temperature change measurements. Validation of the MR temperature mapping method was demonstrated by comparison with physical temperature measurements and electromagnetic field simulations. MR temperature measurements alongside physical property measurements were used to reconstruct 10-g average SAR. The maximum temperature change for a dipole antenna and the maximum 10-g average SAR were 1.83°C and 12.4 W/kg, respectively, for simulations and 1.73°C and 11.9 W/kg, respectively, for experiments. The difference between MR and probe thermometry was <0.15°C. The maximum temperature change and the maximum 10-g average SAR for a cell phone radiating at maximum output for 15 min was 1.7°C and 0.54 W/kg, respectively. Information acquired using MR temperature mapping and thermal property measurements can assess RF/microwave safety with high resolution and fidelity. © 2014 Wiley Periodicals, Inc.

A Method for Safety Testing of Radiofrequency/Microwave-Emitting Devices Using MRI

PubMed Central

Alon, Leeor; Cho, Gene Y.; Yang, Xing; Sodickson, Daniel K.; Deniz, Cem M.

2015-01-01

Purpose Strict regulations are imposed on the amount of radiofrequency (RF) energy that devices can emit to prevent excessive deposition of RF energy into the body. In this study, we investigated the application of MR temperature mapping and 10-g average specific absorption rate (SAR) computation for safety evaluation of RF-emitting devices. Methods Quantification of the RF power deposition was shown for an MRI-compatible dipole antenna and a non–MRI-compatible mobile phone via phantom temperature change measurements. Validation of the MR temperature mapping method was demonstrated by comparison with physical temperature measurements and electromagnetic field simulations. MR temperature measurements alongside physical property measurements were used to reconstruct 10-g average SAR. Results The maximum temperature change for a dipole antenna and the maximum 10-g average SAR were 1.83° C and 12.4 W/kg, respectively, for simulations and 1.73° C and 11.9 W/kg, respectively, for experiments. The difference between MR and probe thermometry was <0.15° C. The maximum temperature change and the maximum 10-g average SAR for a cell phone radiating at maximum output for 15 min was 1.7° C and 0.54 W/kg, respectively. Conclusion Information acquired using MR temperature mapping and thermal property measurements can assess RF/microwave safety with high resolution and fidelity. PMID:25424724

Characterization of erythrosine B binding to bovine serum albumin and bilirubin displacement.

PubMed

Mathavan, Vinodaran M K; Boh, Boon Kim; Tayyab, Saad

2009-08-01

The interaction of crythrosine B (ErB), a commonly used dye for coloring foods and drinks, with bovine scrum albumin (BSA) was investigated both in the absence and presence of bilirubin (BR) using absorption and absorption difference spectroscopy. ErB binding to BSA was reflected from a significant red shift of 11 nm in the absorption maximum of ErB (527 nm) with the change in absorbance at lamdamax. Analysis of absorption difference spectroscopic titration results of BSA with increasing concentrations of ErB3 using Benesi-Hildebrand equation gave the association constant, K as 6.9 x 10(4) M(-1). BR displacing action of ErB was revealed by a significant blue shift in the absorption maximum, accompanied by a decrease in absorbance difference at lamdamax in the difference spectrum of BR-BSA complex upon addition of increasing concentrations of ErB. This was further substantiated by fluorescence spectroscopy, as addition of increasing concentrations of ErB to BR-BSA complex caused a significant decrease in fluoresccnce at 510 nm. The results suggest that ErB binds to a site in the vicinity of BR binding site on BSA. Therefore, intake of ErB may increase the risk of hyperbilirubinemia in the healthy subjects.

Sub-wavelength plasmon laser

DOEpatents

Bora, Mihail; Bond, Tiziana C.

2016-04-19

A plasmonic laser device has resonant nanocavities filled with a gain medium containing an organic dye. The resonant plasmon frequencies of the nanocavities are tuned to align with both the absorption and emission spectra of the dye. Variables in the system include the nature of the dye and the wavelength of its absorption and emission, the wavelength of the pumping radiation, and the resonance frequencies of the nanocavities. In addition the pumping frequency of the dye is selected to be close to the absorption maximum.

Development and Evaluation of a Spectral Analysis Method to Eliminate Organic Interference with Cavity Ring-Down Measurements of Water Isotope Ratios.

NASA Astrophysics Data System (ADS)

Lin, Z.; Kim-Hak, D.; Popp, B. N.; Wallsgrove, N.; Kagawa-Viviani, A.; Johnson, J.

2017-12-01

Cavity ring-down spectroscopy (CRDS) is a technology based on the spectral absorption of gas molecules of interest at specific spectral regions. The CRDS technique enables the analysis of hydrogen and oxygen stable isotope ratios of water by directly measuring individual isotopologue absorption peaks such as H16OH, H18OH, and D16OH. Early work demonstrated that the accuracy of isotope analysis by CRDS and other laser-based absorption techniques could be compromised by spectral interference from organic compounds, in particular methanol and ethanol, which can be prevalent in ecologically-derived waters. There have been several methods developed by various research groups including Picarro to address the organic interference challenge. Here, we describe an organic fitter and a post-processing algorithm designed to improve the accuracy of the isotopic analysis of the "organic contaminated" water specifically for Picarro models L2130-i and L2140-i. To create the organic fitter, the absorption features of methanol around 7200 cm-1 were characterized and incorporated into spectral analysis. Since there was residual interference remaining after applying the organic fitter, a statistical model was also developed for post-processing correction. To evaluate the performance of the organic fitter and the postprocessing correction, we conducted controlled experiments on the L2130-i for two water samples with different isotope ratios blended with varying amounts of methanol (0-0.5%) and ethanol (0-5%). When the original fitter was not used for spectral analysis, the addition of 0.5% methanol changed the apparent isotopic composition of the water samples by +62‰ for δ18O values and +97‰ for δ2H values, and the addition of 5% ethanol changed the apparent isotopic composition by -0.5‰ for δ18O values and -3‰ for δ2H values. When the organic fitter was used for spectral analysis, the maximum methanol-induced errors were reduced to +4‰ for δ18O values and +5‰ for δ2H values, and the maximum ethanol-induced errors were unchanged. When the organic fitter was combined with the post-processing correction, up to 99.8% of the total methanol-induced errors and 96% of the total ethanol-induced errors could be corrected. The applicability of the algorithm to natural samples such as plant and soil waters will be investigated.

SAR Simulation with Magneto Chiral Effects for Human Head Radiated from Cellular Phones

NASA Astrophysics Data System (ADS)

Torres-Silva, H.

2008-09-01

A numerical method for a microwave signal emitted by a cellular phone, propagating in a magneto-chiral media, characterized by an extended Born-Fedorov formalism, is presented. It is shown that the use of a cell model, combined with a real model of the human head, derived from the magnetic resonance of images allows a good determination of the near fields induced in the head when the brain chirality and the battery magnetic field are considered together. The results on a 2-Dim human head model show the evolution of the specific absorption rate, (SAR coefficient) and the spatial peak specific absorption rate which are sensitives to the magneto-chiral factor, which is important in the brain layer. For GSM/PCN phones, extremely low frequency real pulsed magnetic fields (in the order of 10 to 60 milligauss) are added to the model through the whole of the user's head. The more important conclusion of our work is that the head absorption is bigger than the results for a classical model without the magneto chiral effect. Hot spots are produced due to the combination of microwave and the magnetic field produced by the phone's operation. The FDTD method was used to compute the SARs inside the MRI based head models consisting of various tissues for 1.8 GHz. As a result, we found that in the head model having more than four kinds of tissue, the localized peak SAR reaches maximum inside the head for over five tissues including skin, bone, blood and brain cells.

Thin-walled composite tubes using fillers subjected to quasistatic axial compression

NASA Astrophysics Data System (ADS)

AL-Qrimli, Haidar F.; Mahdi, Fadhil A.; Ismail, Firas B.; Alzorqi, Ibrahim S.

2015-04-01

It has been demonstrated that composites are lightweight, fatigue resistant and easily melded, a seemingly attractive alternative to metals. However, there has been no widespread switch from metals to composites in the automotive sector. This is because there are a number of technical issues relating to the use of composite materials that still need to be resolved including accurate material characterization, manufacturing and joining process. The total of 36 specimens have been fabricated using the fibre-glass and resin (epoxy) with a two different geometries (circular and corrugated) each one will be filled with five types of filler (Rice Husk, Wood Chips, Aluminium Chips, Coconut Fibre, Palm Oil Fibre) all these type will be compared with empty Tubes for circular and corrugated in order to comprehend the crashworthiness parameters (initial failure load, average load, maximum crushing load, load ratio, energy absorption, specific energy absorption, volumetric energy absorption, crushing force efficiency and crush strain relation) which are considered very sufficient parameters in the design of automotive industry parts. All the tests have been done using the “INSTRON Universal machine” which is computerized in order to simply give a high precision to the collection of the results, along with the use of quasi-static load to test and observe the behaviour of the fabricated specimens.

Tunable Semiconducting Polymer Nanoparticles with INDT-Based Conjugated Polymers for Photoacoustic Molecular Imaging.

PubMed

Stahl, Thomas; Bofinger, Robin; Lam, Ivan; Fallon, Kealan J; Johnson, Peter; Ogunlade, Olumide; Vassileva, Vessela; Pedley, R Barbara; Beard, Paul C; Hailes, Helen C; Bronstein, Hugo; Tabor, Alethea B

2017-06-21

Photoacoustic imaging combines both excellent spatial resolution with high contrast and specificity, without the need for patients to be exposed to ionizing radiation. This makes it ideal for the study of physiological changes occurring during tumorigenesis and cardiovascular disease. In order to fully exploit the potential of this technique, new exogenous contrast agents with strong absorbance in the near-infrared range, good stability and biocompatibility, are required. In this paper, we report the formulation and characterization of a novel series of endogenous contrast agents for photoacoustic imaging in vivo. These contrast agents are based on a recently reported series of indigoid π-conjugated organic semiconductors, coformulated with 1,2-dipalmitoyl-sn-glycero-3-phosphocholine, to give semiconducting polymer nanoparticles of about 150 nm diameter. These nanoparticles exhibited excellent absorption in the near-infrared region, with good photoacoustic signal generation efficiencies, high photostability, and extinction coefficients of up to three times higher than those previously reported. The absorption maximum is conveniently located in the spectral region of low absorption of chromophores within human tissue. Using the most promising semiconducting polymer nanoparticle, we have demonstrated wavelength-dependent differential contrast between vasculature and the nanoparticles, which can be used to unambiguously discriminate the presence of the contrast agent in vivo.

An Inverse Modeling Approach to Estimating Phytoplankton Pigment Concentrations from Phytoplankton Absorption Spectra

NASA Technical Reports Server (NTRS)

Moisan, John R.; Moisan, Tiffany A. H.; Linkswiler, Matthew A.

2011-01-01

Phytoplankton absorption spectra and High-Performance Liquid Chromatography (HPLC) pigment observations from the Eastern U.S. and global observations from NASA's SeaBASS archive are used in a linear inverse calculation to extract pigment-specific absorption spectra. Using these pigment-specific absorption spectra to reconstruct the phytoplankton absorption spectra results in high correlations at all visible wavelengths (r(sup 2) from 0.83 to 0.98), and linear regressions (slopes ranging from 0.8 to 1.1). Higher correlations (r(sup 2) from 0.75 to 1.00) are obtained in the visible portion of the spectra when the total phytoplankton absorption spectra are unpackaged by multiplying the entire spectra by a factor that sets the total absorption at 675 nm to that expected from absorption spectra reconstruction using measured pigment concentrations and laboratory-derived pigment-specific absorption spectra. The derived pigment-specific absorption spectra were further used with the total phytoplankton absorption spectra in a second linear inverse calculation to estimate the various phytoplankton HPLC pigments. A comparison between the estimated and measured pigment concentrations for the 18 pigment fields showed good correlations (r(sup 2) greater than 0.5) for 7 pigments and very good correlations (r(sup 2) greater than 0.7) for chlorophyll a and fucoxanthin. Higher correlations result when the analysis is carried out at more local geographic scales. The ability to estimate phytoplankton pigments using pigment-specific absorption spectra is critical for using hyperspectral inverse models to retrieve phytoplankton pigment concentrations and other Inherent Optical Properties (IOPs) from passive remote sensing observations.

Index extraction for electromagnetic field evaluation of high power wireless charging system

PubMed Central

2017-01-01

This paper presents the precise dosimetry for highly resonant wireless power transfer (HR-WPT) system using an anatomically realistic human voxel model. The dosimetry for the HR-WPT system designed to operate at 13.56 MHz frequency, which one of the ISM band frequency band, is conducted in the various distances between the human model and the system, and in the condition of alignment and misalignment between transmitting and receiving circuits. The specific absorption rates in the human body are computed by the two-step approach; in the first step, the field generated by the HR-WPT system is calculated and in the second step the specific absorption rates are computed with the scattered field finite-difference time-domain method regarding the fields obtained in the first step as the incident fields. The safety compliance for non-uniform field exposure from the HR-WPT system is discussed with the international safety guidelines. Furthermore, the coupling factor concept is employed to relax the maximum allowable transmitting power. Coupling factors derived from the dosimetry results are presented. In this calculation, the external magnetic field from the HR-WPT system can be relaxed by approximately four times using coupling factor in the worst exposure scenario. PMID:28708840

Computation of temperature elevation in rabbit eye irradiated by 2.45-GHz microwaves with different field configurations.

PubMed

Hirata, Akimasa; Watanabe, Soichi; Taki, Masao; Fujiwara, Osamu; Kojima, Masami; Sasaki, Kazuyuki

2008-02-01

This study calculated the temperature elevation in the rabbit eye caused by 2.45-GHz near-field exposure systems. First, we calculated specific absorption rate distributions in the eye for different antennas and then compared them with those observed in previous studies. Next, we re-examined the temperature elevation in the rabbit eye due to a horizontally-polarized dipole antenna with a C-shaped director, which was used in a previous study. For our computational results, we found that decisive factors of the SAR distribution in the rabbit eye were the polarization of the electromagnetic wave and antenna aperture. Next, we quantified the eye average specific absorption rate as 67 W kg(-1) for the dipole antenna with an input power density at the eye surface of 150 mW cm(-2), which was specified in the previous work as the minimum cataractogenic power density. The effect of administrating anesthesia on the temperature elevation was 30% or so in the above case. Additionally, the position where maximum temperature in the lens appears is discussed due to different 2.45-GHz microwave systems. That position was found to appear around the posterior of the lens regardless of the exposure condition, which indicates that the original temperature distribution in the eye was the dominant factor.

Petawatt laser absorption bounded

PubMed Central

Levy, Matthew C.; Wilks, Scott C.; Tabak, Max; Libby, Stephen B.; Baring, Matthew G.

2014-01-01

The interaction of petawatt (1015 W) lasers with solid matter forms the basis for advanced scientific applications such as table-top particle accelerators, ultrafast imaging systems and laser fusion. Key metrics for these applications relate to absorption, yet conditions in this regime are so nonlinear that it is often impossible to know the fraction of absorbed light f, and even the range of f is unknown. Here using a relativistic Rankine-Hugoniot-like analysis, we show for the first time that f exhibits a theoretical maximum and minimum. These bounds constrain nonlinear absorption mechanisms across the petawatt regime, forbidding high absorption values at low laser power and low absorption values at high laser power. For applications needing to circumvent the absorption bounds, these results will accelerate a shift from solid targets, towards structured and multilayer targets, and lead the development of new materials. PMID:24938656

Absorption spectra and nonlinear transmission (at λ = 2940 nm) of a diffusion-doped Fe{sup 2+}:ZnSe single crystal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bufetova, G A; Gulyamova, E S; Il'ichev, N N

2015-06-30

Transmission spectra of a ZnSe sample diffusion-doped with Fe{sup 2+} ions have been measured in the wavelength range 500 – 7000 nm. A broad absorption band in the range 500 – 1500 nm has been observed in both doped and undoped regions of the sample. This band is possibly due to deviations from stoichiometry in the course of diffusion doping. The transmission of the Fe{sup 2+}:ZnSe sample at a wavelength of 2940 nm has been measured at various dopant concentrations and high peak pulse intensities (up to 8 MW cm{sup -2}). The samples have been shown to be incompletely bleached:more » during a laser pulse, the transmission first increases, reaches a maximum, and then falls off. Our results suggest that the incomplete bleaching cannot be accounted for by excited-state absorption. The incomplete bleaching (as well as the transmission maximum) is due to the heating of the sample, which leads to a reduction in upper level lifetime and, accordingly, to an increase in absorption saturation intensity. (nonlinear optical phenomena)« less

Protonation effects on the UV/Vis absorption spectra of imatinib: a theoretical and experimental study.

PubMed

Grante, Ilze; Actins, Andris; Orola, Liana

2014-08-14

An experimental and theoretical investigation of protonation effects on the UV/Vis absorption spectra of imatinib showed systematic changes of absorption depending on the pH, and a new absorption band appeared below pH 2. These changes in the UV/Vis absorption spectra were interpreted using quantum chemical calculations. The geometry of various imatinib cations in the gas phase and in ethanol solution was optimized with the DFT/B3LYP method. The resultant geometries were compared to the experimentally determined crystal structures of imatinib salts. The semi-empirical ZINDO-CI method was employed to calculate the absorption lines and electronic transitions. Our study suggests that the formation of the extra near-UV absorption band resulted from an increase of imatinib trication concentration in the solution, while the rapid increase of the first absorption maximum could be attributed to both the formation of imatinib trication and tetracation. Copyright © 2014 Elsevier B.V. All rights reserved.

Gated photochemical hole burning in photoadducts of polyacenes

NASA Technical Reports Server (NTRS)

Iannone, Mark; Scott, Gary W.; Brinza, David; Coulter, Daniel R.

1986-01-01

A photoadduct of anthracene and tetracene (A-T) in a polymer matrix at 1.5 K generates an absorption spectrum which exhibits two-color, photon-gated photochemical hole burning (PHB) when irradiated with narrowband exciting light into the 0-0 band of the S1-S0 absorption. The efficiency of this PHB process is found to be enhanced by simultaneous irradiation near the maximum of the Tn-T1 absorption of A-T; hole widths of less than 0.07/cm have been observed for this photochemical cleavage of A-T.

Ultraviolet interstellar lines in the spectrum of Pi Scorpii recorded at 2 kilometers per second resolution

NASA Technical Reports Server (NTRS)

Joseph, Charles L.; Jenkins, Edward B.

1991-01-01

A spectrum of Pi Scorpii has been recorded from 1003 to 1172 A with a maximum SNR of about 20 and a velocity resolution of 2.4 km/s. Three types of H I as well as two discrete H II regions are distinguished in velocity space, allowing independent analyses of physical conditions and abundances for the individual gas components. A direct evaluation of optical depths and column densities across the absorption features is applied for the first time to the dominant ionization stage of Fe, Si, and P. Based on an analysis of the spectrum, it is concluded that all of the Ti II absorption seen toward Pi Sco arises in the warm, neutral intercloud medium while the other elements have their maximum absorption associated with cold clouds. A conservative value of log delta less than -3.4 is inferred for the Ti depletion in the cold clouds, a value more extreme than any integrated, line-of-sight measurement made to date.

New photocycle intermediates in the photoactive yellow protein from Ectothiorhodospira halophila: picosecond transient absorption spectroscopy.

PubMed

Ujj, L; Devanathan, S; Meyer, T E; Cusanovich, M A; Tollin, G; Atkinson, G H

1998-07-01

Previous studies have shown that the room temperature photocycle of the photoactive yellow protein (PYP) from Ectothiorhodospira halophila involves at least two intermediate species: I1, which forms in <10 ns and decays with a 200-micros lifetime to I2, which itself subsequently returns to the ground state with a 140-ms time constant at pH 7 (Genick et al. 1997. Biochemistry. 36:8-14). Picosecond transient absorption spectroscopy has been used here to reveal a photophysical relaxation process (stimulated emission) and photochemical intermediates in the PYP photocycle that have not been reported previously. The first new intermediate (I0) exhibits maximum absorption at approximately 510 nm and appears in

Sound absorption by subwavelength membrane structures: A geometric perspective

NASA Astrophysics Data System (ADS)

Yang, Min; Li, Yong; Meng, Chong; Fu, Caixing; Mei, Jun; Yang, Zhiyu; Sheng, Ping

2015-12-01

Decorated membranes comprising a thin layer of elastic film with small rigid platelets fixed on top have been found to be efficient absorbers of low-frequency sound. In this work we consider the problem of sound absorption from a perspective aimed at deriving upper bounds under different scenarios, i.e., whether the sound is incident from one side only or from both sides, and whether there is a reflecting surface on the back side of the membrane. By considering the negligible thickness of the membrane, usually on the order of a fraction of one millimeter, we derive a relation showing that the sum of the incoming sound waves' (complex) pressure amplitudes, averaged over the area of the membrane, must be equal to that of the outgoing waves. By using this relation, and without going to any details of the wave solutions, it is shown that the maximum absorption achievable from one-sided incidence is 50%, while the maximum absorption with a back-reflecting surface can reach 100%. The latter was attained by the hybridized resonances. All the results are shown to be in excellent agreement with the experiments. This generalized perspective, when used together with the Green function's formalism, can be useful in gaining insights into the constraints on what are achievable in scatterings and absorption by thin film structures and delineating them.

Absorption enhancement and sensing properties of Ag diamond nanoantenna arrays

NASA Astrophysics Data System (ADS)

Yuan, Yu-Yang; Yuan, Zong-Heng; Li, Xiao-Nan; Wu, Jun; Zhang, Wen-Tao; Ye, Song

2015-07-01

Noble metal nanoantenna could effectively enhance light absorption and increase detection sensitivity. In this paper, we propose a periodic Ag diamond nanoantenna array to increase the absorption of thin-film solar cells and to improve the detection sensitivity via localized surface plasmon resonance. The effect of nanoantenna arrays on the absorption enhancement is theoretically investigated using the finite difference time domain (FDTD) method with manipulating the spectral response by geometrical parameters of nanoantennas. A maximum absorption enhancement factor of 1.51 has been achieved in this study. In addition, the relation between resonant wavelength (intensity reflectivity) and refractive index is discussed in detail. When detecting the environmental index using resonant wavelengths, a maximum detection sensitivity of about 837 nm/RIU (refractive index unit) and a resolution of about 10-3 RIU can be achieved. Moreover, when using the reflectivity, the sensitivity can be as high as 0.93 AU/RIU. Furthermore, we also have theoretically studied the effectiveness of nanoantennas in distinguishing chemical reagents, solution concentrations, and solution allocation ratios by detecting refractive index. From the results presented in this paper, we conclude that this work might be useful for biosensor detection and other types of detections. Project supported by the International Scientific and Technological Cooperation Projects of Guizhou Province, China (Grant No. 20117035) and the Program for Innovative Research Team of Guilin University of Electronic Technology, China (Grant No. IRTGUET).

Impact of pinna compression on the RF absorption in the heads of adult and juvenile cell phone users.

PubMed

Christ, Andreas; Gosselin, Marie-Christine; Kühn, Sven; Kuster, Niels

2010-07-01

The electromagnetic exposure of cell phone users depends on several parameters. One of the most dominant of these is the distance between the cell phone and the head tissue. The pinna can be regarded as a spacer between the top of the phone and the head tissue. The size of this spacer has not yet been systematically studied. The objective of this article is to investigate the variations of distance as a function of age of the exposed person, and the mechanical force on the pinna and how it affects the peak spatial specific absorption rate (psSAR). The distances were measured for adults and children (6-8 years of age) while applying a well-defined force on the pinna using a custom-developed measurement device. The average distances of the pinnae to the heads and their standard deviations showed no major differences between the two age groups: 10.5 +/- 2.0 mm for children (6-8 years) and 9.5 +/- 2.0 mm for adults. The pinnae of our anatomical high-resolution head models of one adult and two children were transformed according to the measurement results. The numerical exposure analysis showed that the reduced distance due to the pinna compression can increase the maximum 10 g psSAR by approximately 2 dB for adults and children, if the exposure maximum is associated with the upper part of the phone. 2010 Wiley-Liss, Inc.

Micromagnetic evaluation of the dissipated heat in cylindrical magnetic nanowires

NASA Astrophysics Data System (ADS)

Fernandez-Roldan, Jose Angel; Serantes, David; del Real, Rafael P.; Vazquez, Manuel; Chubykalo-Fesenko, Oksana

2018-05-01

Magnetic nanowires (NWs) are promising candidates for heat generation under AC-field application due to their large shape anisotropy. They may be used for catalysis, hyperthermia, or water purification treatments. In the present work, we theoretically evaluate the heat dissipated by a single magnetic nanowire, originated from the domain wall (DW) dynamics under the action of an AC-field. We compare the Permalloy NWs (which demagnetize via the transverse wall propagation) with the Co fcc NWs whose reversal mode is via a vortex domain wall. The average hysteresis loop areas—which are proportional to the Specific Absorption Rate (SAR)—as a function of the field frequency have a pronounced maximum in the range 200 MHz-1 GHz. This maximum frequency is smaller in Permalloy than that in Co and depends on the nanowire length. A simple model related to the nucleation and propagation time and DW velocity (higher for the vortex than for the transverse domain wall) is proposed to explain the non-monotonic SAR dependence on the frequency.

Lactobacillus brevis G101 inhibits the absorption of monosodium glutamate in mice.

PubMed

Jang, Se-Eun; Han, Myung Joo; Kim, Se-Young; Kim, Dong-Hyun

2014-11-28

To evaluate the effect of Lactobacillus brevis G-101 on absorption of monosodium glutamate (MSG), we orally administered MSG with or without G-101 in mice and measured the maximum concentration (Cmax) and blood concentration curve (AUC) of MSG and γ- aminobutyric acid (GABA). Oral administration of G-101 (1 × 10(9) CFU/mouse) potently inhibited Cmax and AUC of MSG by 97.8% and 94.3%, respectively (p < 0.05), but increased those of GABA by 32.1% and 67.7%, respectively (p < 0.05). G-101 inhibited the absorption of MSG. These results suggest that G-101 may reduce the side effect of MSG by inhibiting the absorption of MSG.

UV absorption and photoisomerization of p-methoxycinnamate grafted silicone.

PubMed

Pattanaargson, Supason; Hongchinnagorn, Nantawan; Hirunsupachot, Piyawan; Sritana-anant, Yongsak

2004-01-01

p-Methoxycinnamate moieties, UV-B-absorptive chromophores of the widely used UV-B filter, 2-ethylhexyl p-methoxycinnamate (OMC), were grafted onto the 7 mol% amino functionalized silicone polymer through amide linkages. Comparing with OMC, the resulting poly [3-(p-methoxycinnamido)(propyl)(methyl)-dimethyl] siloxane copolymer (CAS) showed less E to Z isomerization when exposed to UV-B light. The absorption profiles of the product showed the maximum absorption wavelength to be similar to that of OMC but with less sensitivity to the type of solvent. Poly (methylhydrosiloxane) grafted with 10 mol% p-methoxycinnamoyl moieties was prepared through hydrosilylations of 2-propenyl-p-methoxycinnamate, in which the resulting copolymer showed similar results to those of CAS.

Ultraviolet absorption spectrum of HOCl

NASA Technical Reports Server (NTRS)

Burkholder, James B.

1993-01-01

The room temperature UV absorption spectrum of HOCl was measured over the wavelength range 200 to 380 nm with a diode array spectrometer. The absorption spectrum was identified from UV absorption spectra recorded following UV photolysis of equilibrium mixtures of Cl2O/H2O/HOCl. The HOCl spectrum is continuous with a maximum at 242 nm and a secondary peak at 304 nm. The measured absorption cross section at 242 nm was (2.1 +/- 0.3) x 10 exp -19/sq cm (2 sigma error limits). These results are in excellent agreement with the work of Knauth et al. (1979) but in poor agreement with the more recent measurements of Mishalanie et al. (1986) and Permien et al. (1988). An HOCl nu2 infrared band intensity of 230 +/- 35/sq cm atm was determined based on this UV absorption cross section. The present results are compared with these previous measurements and the discrepancies are discussed.

Fundamental studies of black chrome for solar collector use

NASA Technical Reports Server (NTRS)

Mcdonald, G.; Buzek, B.; Curtis, H.

1976-01-01

The thicknesses of black chrome plated for various times have been measured from electron photomicrographs and correlated with the solar spectrum absorptance and infrared emittance as calculated from spectral reflectance measurements. The maximum absorptance is reached at an average thickness of 0.5 micrometer. The emittance increases only slightly up to 1.0 micrometer but increases rapidly at thickness above 1.0 micrometer.

Design study of large area 8 cm x 8 cm wrapthrough cells for space station

NASA Technical Reports Server (NTRS)

Garlick, George F. J.; Lillington, David R.

1987-01-01

The design of large area silicon solar cells for the projected NASA space station is discussed. It is based on the NASA specification for the cells which calls for an 8 cm by 8 cm cell of wrapthrough type with gridded back contacts. The beginning of life (BOL) power must be 1.039 watts per cell or larger and maximum end of life (EOL) after 10 years in the prescribed orbit under an equivalent 1MeV electron radiation damage fluence of 5 times 10 to the 13th power e/square cm. On orbit efficiency is to be optimized by a low thermal absorptance goal (thermal alpha) of .63.

Preparation and characterization of Ba0.2Sr0.2La0.6MnO3 nanoparticles and investigation of size & shape effect on microwave absorption

NASA Astrophysics Data System (ADS)

Peymanfar, Reza; Javanshir, Shahrzad

2017-06-01

In this paper, the design and characterization of a radar absorbing material (RAM) was investigated at microwave frequency. Ba0.2Sr0.2La0.6MnO3 magnetic nanoparticles was synthesized thru a facile hydrothermal method in the presence of polymethyl methacrylate (PMMA) and the possibility of shape and size-controlled synthesis of nanoparticles (NPs) over the range 15-50 Nm was also explored. Afterward, the effect of shape and size of the synthesized Ba0.2Sr0.2La0.6MnO3 NPs on microwave absorption properties was investigated in KU-band. The crystal structures and morphology of as-synthesized nanoparticles were characterized and confirmed by FESEM, XRD, VSM, FTIR analysis. The RAM samples were prepared by dispersion of magnetic NPs in silicone rubber in an ultrasonic bath. The maximum reflection loss (RL) values NPs were 12.04 dB at 14.82 GHz and a broad absorption band (over 1.22 GHz) with RL values <-10 dB are obtained and the maximum reflection loss (RL) values of decrease and shaped NPs were 22.36 dB at 14.78 GHz and a broad absorption band (over 2.67 GHz) with RL values <-10 dB are obtained. The results indicated that the particle size and shape play a major role on the absorption properties of the composites in the 12.4-18 GHz frequency range. It is observed that microwave absorption properties increased with the decrease in average particle size of NPs.

Water absorption characteristic of interlocking compressed earth brick units

NASA Astrophysics Data System (ADS)

Bakar, B. H. Abu; Saari, S.; Surip, N. A.

2017-10-01

This study aims to investigate the water absorption characteristic of interlocking compressed earth brick (ICEB) units. Apart from compressive strength, water absorption is an important property in masonry. This property can affect the quality of the brick itself and the bond strength between the brick and mortar in masonry structures and can result in reducing its strength properties. The units were tested for 24 h water absorption and 5 h boiling water absorption. A total of 170 ICEB units from four ICEB types underwent both tests. For the 24 h water absorption, the ICEB units were dried in the oven for 24 h and then cooled before being weighed. Thereafter, each brick was immersed in water for 24 h and weighed. The same specimens used for the 24 h water absorption test were re-used for the 5 h boiling water absorption test. After completing the 24 h water absorption test, the brick was boiled for 5-hours and weighed. The highest water absorption for the ICEBs in the 24-hour water absorption and 5 h boiling water absorption tests are 15.09% and 17.18%, respectively. The half brick has the highest water absorption (15.87%), whereas the beam brick has the lowest (13.20%). The water absorption of an ICEB unit is higher than that of normal bricks, although the water absorption of the former remains below the maximum rate of the brick water absorption (21%).

Temperature evolution in silver nanoparticle doped PETN composite

NASA Astrophysics Data System (ADS)

Kameswari, D. P. S. L.; Kiran, P. Prem

2018-04-01

Optical absorption and the associated spatio-temporal evolution of temperature silver nanoparticles doped energetic material composite is presented. Silver nanoparticles of radii 10 - 150 nm are doped in Penta Erythrtol Tetra Nitrate (PETN), a secondary energetic material to form the composite materials. Of all the composites the ones doped with 35 nm sized nanoparticles have shown maximum absorption at excitation wavelength of 532 nm. The spatio-temporal evolution of temperature within these composites up on excitation with ns laser pulses of energy density 0.5 J/cm2 is studied. The role of particle sizes on the temperature of composites is studied and a maximum temperature of 2200 K at the nanoparticle interface is observed for 35 nm doped PETN composite.

Phonons in Confinement and the Boson Peak Using Nuclear Inelastic Absorption

NASA Astrophysics Data System (ADS)

Asthalter, T.; Bauer, M.; van Bürck, U.; Sergueev, I.; Franz, H.; Chumakov, A. I.

2002-12-01

We have applied nuclear inelastic absorption (NIA) to the molecular glass former dibutylphthalate/ferrocene, both in bulk and in nanoporous matrices having pore sizes of 50 and 25 Å, respectively. The quantity g(E)/E 2, where g(E) is the vibrational phonon density of states (VDOS) of the resonant nuclei, exhibits a pronounced maximum at low energies. Confinement in pores leads to a suppression of the VDOS below 1.5 meV, independent of the pore size. Also in the scaled heat capacity C(T)/T 3, we observe a decrease of the peak maximum for low temperatures. Our observations are discussed in the light of experimental and theoretical results on nanocrystals and a recent theoretical model for the boson peak.

Variable Sodium Absorption in a Low-extinction Type Ia Supernova

NASA Astrophysics Data System (ADS)

Simon, Joshua D.; Gal-Yam, Avishay; Gnat, Orly; Quimby, Robert M.; Ganeshalingam, Mohan; Silverman, Jeffrey M.; Blondin, Stephane; Li, Weidong; Filippenko, Alexei V.; Wheeler, J. Craig; Kirshner, Robert P.; Patat, Ferdinando; Nugent, Peter; Foley, Ryan J.; Vogt, Steven S.; Butler, R. Paul; Peek, Kathryn M. G.; Rosolowsky, Erik; Herczeg, Gregory J.; Sauer, Daniel N.; Mazzali, Paolo A.

2009-09-01

Recent observations have revealed that some Type Ia supernovae exhibit narrow, time-variable Na I D absorption features. The origin of the absorbing material is controversial, but it may suggest the presence of circumstellar gas in the progenitor system prior to the explosion, with significant implications for the nature of the supernova (SN) progenitors. We present the third detection of such variable absorption, based on six epochs of high-resolution spectroscopy of the Type Ia supernova SN 2007le from the Keck I Telescope and the Hobby-Eberly Telescope. The data span a time frame of approximately three months, from 5 days before maximum light to 90 days after maximum. We find that one component of the Na I D absorption lines strengthened significantly with time, indicating a total column density increase of ~2.5 × 1012 cm-2. The data limit the typical timescale for the variability to be more than 2 days but less than 10 days. The changes appear to be most prominent after maximum light rather than at earlier times when the ultraviolet flux from the SN peaks. As with SN 2006X, we detect no change in the Ca II H and K absorption lines over the same time period, rendering line-of-sight effects improbable and suggesting a circumstellar origin for the absorbing material. Unlike the previous two supernovae exhibiting variable absorption, SN 2007le is not highly reddened (E B - V = 0.27 mag), also pointing toward circumstellar rather than interstellar absorption. Photoionization calculations show that the data are consistent with a dense (107 cm-3) cloud or clouds of gas located ~0.1 pc (3 × 1017 cm) from the explosion. These results broadly support the single-degenerate scenario previously proposed to explain the variable absorption, with mass loss from a nondegenerate companion star responsible for providing the circumstellar gas. We also present possible evidence for narrow Hα emission associated with the SN, which will require deep imaging and spectroscopy at late times to confirm. Some of the data presented herein were obtained at the W. M. Keck Observatory, which is operated as a scientific partnership among the California Institute of Technology, the University of California, and NASA. The Observatory was made possible by the generous financial support of the W. M. Keck Foundation. Based in part on observations obtained with the Hobby-Eberly Telescope, which is a joint project of the University of Texas at Austin, the Pennsylvania State University, Stanford University, Ludwig-Maximilians-Universität München, and Georg-August-Universität Göttingen.

Spatio-Temporal Convergence of Maximum Daily Light-Use Efficiency Based on Radiation Absorption by Canopy Chlorophyll

NASA Astrophysics Data System (ADS)

Zhang, Yao; Xiao, Xiangming; Wolf, Sebastian; Wu, Jin; Wu, Xiaocui; Gioli, Beniamino; Wohlfahrt, Georg; Cescatti, Alessandro; van der Tol, Christiaan; Zhou, Sha; Gough, Christopher M.; Gentine, Pierre; Zhang, Yongguang; Steinbrecher, Rainer; Ardö, Jonas

2018-04-01

Light-use efficiency (LUE), which quantifies the plants' efficiency in utilizing solar radiation for photosynthetic carbon fixation, is an important factor for gross primary production estimation. Here we use satellite-based solar-induced chlorophyll fluorescence as a proxy for photosynthetically active radiation absorbed by chlorophyll (APARchl) and derive an estimation of the fraction of APARchl (fPARchl) from four remotely sensed vegetation indicators. By comparing maximum LUE estimated at different scales from 127 eddy flux sites, we found that the maximum daily LUE based on PAR absorption by canopy chlorophyll (ɛmaxchl), unlike other expressions of LUE, tends to converge across biome types. The photosynthetic seasonality in tropical forests can also be tracked by the change of fPARchl, suggesting the corresponding ɛmaxchl to have less seasonal variation. This spatio-temporal convergence of LUE derived from fPARchl can be used to build simple but robust gross primary production models and to better constrain process-based models.

Comparison between fluorimetry and oximetry techniques to measure photosynthesis in the diatom Skeletonema costatum cultivated under simulated seasonal conditions.

PubMed

Lefebvre, Sébastien; Mouget, Jean-Luc; Loret, Pascale; Rosa, Philippe; Tremblin, Gérard

2007-02-01

This study reports comparison of two techniques measuring photosynthesis in the ubiquitous diatom Skeletonema costatum, i.e., the classical oximetry and the recent modulated fluorimetry. Microalgae in semi-continuous cultures were exposed to five different environmental conditions simulating a seasonal effect with co-varying temperature, photoperiod and incident light. Photosynthesis was assessed by gross rate of oxygen evolution (P(B)) and the electron transport rate (ETR) measurements. The two techniques were linearly related within seasonal treatments along the course of the P/E curves. The light saturation intensity parameters (Ek and Ek(ETR)), and the maximum electron transport rate increased significantly with the progression of the season while the maximum light utilization efficiency for ETR (alpha(ETR)) was constant. By contrast, the maximum gross oxygen photosynthetic capacity (Pmax(B)) and the maximum light utilization efficiency for P(B) (alpha(B)) increased from December to May treatment but decreased from May to July treatment. Both techniques showed clear photoacclimation in microalgae with the progression of the season, as illustrated by changes in photosynthetic parameters. The relationship between the two techniques changed when high temperature, photoperiod and incident light were combined, possibly due to an overestimation of the PAR--averaged chlorophyll-specific absorption cross-section. Despite this change, our results illustrate the strong suitability of in vivo chlorophyll fluorimetry to estimate primary production in the field.

Two schemes for quantitative photoacoustic tomography based on Monte Carlo simulation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Yubin; Yuan, Zhen, E-mail: zhenyuan@umac.mo

Purpose: The aim of this study was to develop novel methods for photoacoustically determining the optical absorption coefficient of biological tissues using Monte Carlo (MC) simulation. Methods: In this study, the authors propose two quantitative photoacoustic tomography (PAT) methods for mapping the optical absorption coefficient. The reconstruction methods combine conventional PAT with MC simulation in a novel way to determine the optical absorption coefficient of biological tissues or organs. Specifically, the authors’ two schemes were theoretically and experimentally examined using simulations, tissue-mimicking phantoms, ex vivo, and in vivo tests. In particular, the authors explored these methods using several objects withmore » different absorption contrasts embedded in turbid media and by using high-absorption media when the diffusion approximation was not effective at describing the photon transport. Results: The simulations and experimental tests showed that the reconstructions were quantitatively accurate in terms of the locations, sizes, and optical properties of the targets. The positions of the recovered targets were accessed by the property profiles, where the authors discovered that the off center error was less than 0.1 mm for the circular target. Meanwhile, the sizes and quantitative optical properties of the targets were quantified by estimating the full width half maximum of the optical absorption property. Interestingly, for the reconstructed sizes, the authors discovered that the errors ranged from 0 for relatively small-size targets to 26% for relatively large-size targets whereas for the recovered optical properties, the errors ranged from 0% to 12.5% for different cases. Conclusions: The authors found that their methods can quantitatively reconstruct absorbing objects of different sizes and optical contrasts even when the diffusion approximation is unable to accurately describe the photon propagation in biological tissues. In particular, their methods are able to resolve the intrinsic difficulties that occur when quantitative PAT is conducted by combining conventional PAT with the diffusion approximation or with radiation transport modeling.« less

Numerical study for identification of influence of energy absorption and frontal crush for vehicle crashworthiness

NASA Astrophysics Data System (ADS)

Suman, Shwetabh; Shah, Haard; Susarla, Vaibhav; Ravi, K.

2017-11-01

According to the statistics it has been seen that everyday nearly 400 people are killed due to road accidents. Due to this it has become an important concern to concentrate on the safety of the passengers which can be done by improving the crashworthiness of the vehicle. During the impact, a large amount of energy is released which if not absorbed, will be transmitted to the passenger compartment. For the safety of the passenger this energy has to be absorbed. Front rail is one of the main energy absorbing components in the vehicle front structure. When it comes to the structure and material of the part or component of the vehicle that is to be designed for crash, it is done based on three parameters: Specific Energy of Absorption, Mass of the front rail and maximum crush force. In this work, we are considering different internal geometries with different materials to increase the energy absorbing capacity of the front rail. Based on the extensive analysis carried aluminium seizes to be the opt material for frontal crash.

Identification of Paracoccidioides brasiliensis by gold nanoprobes

NASA Astrophysics Data System (ADS)

Martins, Jaciara F. S.; Castilho, Maiara L.; Cardoso, Maria A. G.; Carreiro, Andrea P.; Martin, Airton A.; Raniero, Leandro

2012-01-01

Paracoccidioides brasiliensis (P. brasiliensis) is a thermal dimorphic fungus and causal agent of paracoccidioidomycosis. Epidemiological data shows that it is mainly concentrated in Central and South America countries, with most registered cases in Colombia, Brazil, and Venezuela. The histopathological similarity with others fungal infection makes the diagnosis of P. brasiliensis more complicated. Therefore, the aim of this work was to find a positive and negative test for P. brasiliensis using gold nanoprobes as a new tool for P. brasiliensis detection. Gold nanoparticles were synthesized by reduction of gold chloride with sodium citrate. The results of this procedure is a wine-red solution with a maximum absorption in the range of ~520-530nm. A specific P. brasiliensis sequence of oligonucleotide was bonded to the nanoparticles, which maintained the wine-red color. The color changes from red to blue for negative diagnostic and is unchanged for a positive test. The H-bond interaction of DNA with the complementary DNA keeps strands together and forms double helical structure, maintaining the colloid stability. However, for non-complimentary DNA sequence the nanoprobes merge into a cluster, changing the light absorption.

Recent Advancement and Technological Aspects of Pulsatile Drug Delivery System - A Laconic Review.

PubMed

Pandit, Vinay; Kumar, Ajay; Ashawat, Mahendra S; Verma, Chander P; Kumar, Pravin

2017-01-01

Pulsatile drug delivery system (PDDS) shows potential significance in the field of drug delivery to release the maximum amount of drug at a definite site and at specific time. PDDS are mainly time controlled delivery devices having a definite pause period for drug release, which is not affected by acidity, alkalinity, motility and enzymes present in the gastrointestinal tract. Pulsatile medication possess the potential to deliver the drugs in the therapy of diseases where drug dose is essential during sleep, drugs having greater first pass metabolism and absorption at precise location in digestive tract. The review article, discuss the general concepts, marketed formulations and patents or any other recent advancement in pulsatile release technology. It also highlights on diseases requiring therapy by pulsatile release, various researches on herbal pulsatile formulations and quality control aspects of PDDS. Pulsatile medication possess the potential to deliver the drugs in the therapy of diseases where drug dose is essential during sleep, drugs having greater first pass metabolism and absorption at precise location in digestive tract. Copyright© Bentham Science Publishers; For any queries, please email at epub@benthamscience.org.

The absorption of protons with specific amino acids and carbohydrates by yeast

PubMed Central

Seaston, A.; Inkson, C.; Eddy, A. A.

1973-01-01

1. Proton uptake in the presence of various amino acids was studied in washed yeast suspensions containing deoxyglucose and antimycin to inhibit energy metabolism. A series of mutant strains of Saccharomyces cerevisiae with defective amino acid permeases was used. The fast absorption of glycine, l-citrulline and l-methionine through the general amino acid permease was associated with the uptake of about 2 extra equivalents of protons per mol of amino acid absorbed, whereas the slower absorption of l-methionine, l-proline and, possibly, l-arginine through their specific permeases was associated with about 1 proton equivalent. l-Canavanine and l-lysine were also absorbed with 1–2 equivalents of protons. 2. A strain of Saccharomyces carlsbergensis behaved similarly with these amino acids. 3. Preparations of the latter yeast grown with maltose subsequently absorbed it with 2–3 equivalents of protons. The accelerated rate of proton uptake increased up to a maximum value with the maltose concentration (Km=1.6mm). The uptake of protons was also faster in the presence of α-methylglucoside and sucrose, but not in the presence of glucose, galactose or 2-deoxyglucose. All of these compounds except the last could cause acid formation. The uptake of protons induced by maltose, α-methylglucoside and sucrose was not observed when the yeast was grown with glucose, although acid was then formed both from sucrose and glucose. 4. A strain of Saccharomyces fragilis that both fermented and formed acid from lactose absorbed extra protons in the presence of lactose. 5. The observations show that protons were co-substrates in the systems transporting the amino acids and certain of the carbohydrates. PMID:4587071

Preparation and electromagnetic wave absorption of RGO/Cu nanocomposite

NASA Astrophysics Data System (ADS)

Zhang, Hui; Tian, Xingyou; Zhang, Xian; Li, Shikuo; Shen, Yuhua; Xie, Anjian

2017-09-01

We use a facile pyrolysis method to prepare reduced graphene oxide and copper nanocomposite (RGO/Cu) based on it. The product shows an outstanding wave absorption properties. The maximum reflection loss is up to-50.7 dB at 3.8 GHz. The reflection loss of-10 dB (90% power absorption) corresponds to a bandwidth of 11.2 GHz (3.4-14.6 GHz range) for the layer thickness of 2-5 mm. Therefore, it is suggested that the RGO/Cu nanocomposite is also a new kind of lightweight and high-performance EM wave absorbing material.

4-channels coherent perfect absorption (CPA)-type demultiplexer using plasmonic nano spheres

NASA Astrophysics Data System (ADS)

Soltani, Mohamadreza; Keshavarzi, Rasul

2017-10-01

The current research represents a nanoscale and compact 4-channels plasmonic demultiplexer. It includes eight coherent perfect absorption (CPA) - type filters. The operation principle is based on the absorbable formation of a conductive path in the dielectric layer of a plasmonic nano-spheres waveguide. Since the CPA efficiency depends strongly on the number of plasmonic nano-spheres and the nano spheres location, an efficient binary optimization method based on the Particle Swarm Optimization algorithm is used to design an optimized array of the plasmonic nano-sphere in order to achieve the maximum absorption coefficient in the 'off' state.

Results of Several Years Experiments on the Absorption of Radioactive Strontium and Cesium by Cultivated Plants; COMPTE RENDU D'EXPERIENCES DE PLUSIEURS ANNEES SUR L'ABSORPTION DU STRONTIUM ET DU CESIUM RADIOACTIES PAR DES PLANTES CULTIVEES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huguet, F. et al.

1962-01-01

The absorption of cesium-137 and strontium-90 by vines, permanent pasture, potatoes, green vegetables, tomatoes, onions, cabbage, and beans in France in 1960 is presented. The strontium coefficient has varied very little from one year to the next and that of cesium has slightly diminished. The values obtained suggest that the concentrations in irrigation water should not exceed one fifth of the maximum permissible concentration in drinking water. (auth)

INFRARED STUDIES OF HUMAN SALIVA. IDENTIFICATION OF A FACTOR IN HUMAN SALIVA PRODUCING AN INFRARED ABSORBANCE MAXIMUM AT 4.9 MICRONS

DTIC Science & Technology

An absorption maximum was observed at 4.9 microns in infrared spectra of human parotid saliva. The factor causing this absorbance was found to be a...nitrate, and heat stability. Thiocyanate was then determined in 16 parotid saliva samples by a spectrophotometric method, which involved formation of

Direct absorption spectroscopy sensor for temperature and H2O concentration of flat flame burner

NASA Astrophysics Data System (ADS)

Duan, Jin-hu; Jin, Xing; Wang, Guang-yu; Qu, Dong-sheng

2016-01-01

A tunable diode laser absorption sensor, based on direct absorption spectroscopy and time division multiplexing scheme, was developed to measure H2O concentration and temperature of flat flame burner. At the height of 15mm from the furnace surface, temperature and concentration were measured at different equivalence ratios. Then the distance between the laser and the furnace surface was changed while the equivalence ratio was fixed at 1 and experiments were performed to measure temperature and H2O concentration at every height. At last flame temperatures and H2O concentrations were obtained by simulation and computational analysis and these combustion parameters were compared with the reference. The results showed that the experimental results were in accordance with the reference values. Temperature errors were less than 4% and H2O component concentration errors were less than 5%and both of them reached their maximum when the equivalent ratio was set at 1. The temperature and H2O concentration increased with the height from furnace surface to laser when it varied from 3mm to 9mm and it decreased when it varied from 9mm to 30mm and they reached their maximum at the height of 9mm. Keywords: tunable diode laser, direct absorption spectroscopy

The effect of moisture absorption on the physical properties of polyurethane shape memory polymer foams.

PubMed

Yu, Ya-Jen; Hearon, Keith; Wilson, Thomas S; Maitland, Duncan J

2011-08-01

The effect of moisture absorption on the glass transition temperature (T(g)) and stress/strain behavior of network polyurethane shape memory polymer (SMP) foams has been investigated. With our ultimate goal of engineering polyurethane SMP foams for use in blood contacting environments, we have investigated the effects of moisture exposure on the physical properties of polyurethane foams. To our best knowledge, this study is the first to investigate the effects of moisture absorption at varying humidity levels (non-immersion and immersion) on the physical properties of polyurethane SMP foams. The SMP foams were exposed to differing humidity levels for varying lengths of time, and they exhibited a maximum water uptake of 8.0% (by mass) after exposure to 100% relative humidity for 96 h. Differential scanning calorimetry results demonstrated that water absorption significantly decreased the T(g) of the foam, with a maximum water uptake shifting the T(g) from 67 °C to 5 °C. Samples that were immersed in water for 96 h and immediately subjected to tensile testing exhibited 100% increases in failure strains and 500% decreases in failure stresses; however, in all cases of time and humidity exposure, the plasticization effect was reversible upon placing moisture-saturated samples in 40% humidity environments for 24 h.

The effect of moisture absorption on the physical properties of polyurethane shape memory polymer foams

PubMed Central

Yu, Ya-Jen; Hearon, Keith; Wilson, Thomas S.; Maitland, Duncan J.

2011-01-01

The effect of moisture absorption on the glass transition temperature (Tg) and stress/strain behavior of network polyurethane shape memory polymer (SMP) foams has been investigated. With our ultimate goal of engineering polyurethane SMP foams for use in blood contacting environments, we have investigated the effects of moisture exposure on the physical properties of polyurethane foams. To our best knowledge, this study is the first to investigate the effects of moisture absorption at varying humidity levels (non-immersion and immersion) on the physical properties of polyurethane SMP foams. The SMP foams were exposed to differing humidity levels for varying lengths of time, and they exhibited a maximum water uptake of 8.0% (by mass) after exposure to 100% relative humidity for 96 h. Differential scanning calorimetry results demonstrated that water absorption significantly decreased the Tg of the foam, with a maximum water uptake shifting the Tg from 67 °C to 5 °C. Samples that were immersed in water for 96 h and immediately subjected to tensile testing exhibited 100% increases in failure strains and 500% decreases in failure stresses; however, in all cases of time and humidity exposure, the plasticization effect was reversible upon placing moisture-saturated samples in 40% humidity environments for 24 h. PMID:21949469

The effect of moisture absorption on the physical properties of polyurethane shape memory polymer foams

NASA Astrophysics Data System (ADS)

Yu, Ya-Jen; Hearon, Keith; Wilson, Thomas S.; Maitland, Duncan J.

2011-08-01

The effect of moisture absorption on the glass transition temperature (Tg) and the stress/strain behavior of network polyurethane shape memory polymer (SMP) foams has been investigated. With our ultimate goal of engineering polyurethane SMP foams for use in blood-contacting environments, we have investigated the effects of moisture exposure on the physical properties of polyurethane foams. To the best of our knowledge, this study is the first to investigate the effects of moisture absorption at varying humidity levels (non-immersion and immersion) on the physical properties of polyurethane SMP foams. The SMP foams were exposed to differing humidity levels for varying lengths of time, and they exhibited a maximum water uptake of 8.0% (by mass) after exposure to 100% relative humidity for 96 h. Differential scanning calorimetry results demonstrated that water absorption significantly decreased the Tg of the foam, with a maximum water uptake shifting the Tg from 67 to 5 °C. Samples that were immersed in water for 96 h and immediately subjected to tensile testing exhibited 100% increases in failure strains and 500% decreases in failure stresses; however, in all cases of time and humidity exposure, the plasticization effect was reversible upon placing moisture-saturated samples in 40% humidity environments for 24 h.

Primary photophysical properties of moxifloxacin--a fluoroquinolone antibiotic.

PubMed

Lorenzo, Fernando; Navaratnam, Suppiah; Edge, Ruth; Allen, Norman S

2008-01-01

The photophysical properties of the fluoroquinolone antibiotic moxifloxacin (MOX) were investigated in aqueous media. MOX in water, at pH 7.4, shows two intense absorption bands at 287 and 338 nm (epsilon = 44,000 and 17,000 dm(3) mol(-1) cm(-1), respectively). The absorption and emission properties of MOX are pH-dependent, pK(a) values for the protonation equilibria of both the ground (6.1 and 9.6) and excited singlet states (6.8 and 9.1) of MOX were determined spectroscopically. MOX fluoresces weakly, the quantum yield for fluorescence emission being maximum (0.07) at pH 8. Phosphorescence from the excited triplet state in frozen ethanol solution has a quantum yield of 0.046. Laser flash photolysis and pulse radiolysis studies have been carried out to characterize the transient species of MOX in aqueous solution. On laser excitation, MOX undergoes monophotonic photoionization with a quantum yield of 0.14. This leads to the formation of a long-lived cation radical whose absorption is maximum at 470 nm (epsilon(470) = 3400 dm(3) mol(-1) cm(-1)). The photoionization process releases hydrated electron which rapidly reacts (k = 2.8 x 10(10) dm(3) mol(-1) s(-1)) with ground state MOX, yielding a long-lived anion radical with maximum absorption at 390 nm (epsilon(390) = 2400 dm(3) mol(-1) cm(-1)). The cation radical of MOX is able to oxidize protein components tryptophan and tyrosine. The bimolecular rate constants for these reactions are 2.3 x 10(8) dm(3) mol(-1) s(-1) and 1.3 x 10(8) dm(3) mol(-1) s(-1), respectively. Singlet oxygen sensitized by the MOX triplet state was also detected only in oxygen-saturated D(2)O solutions, with a quantum yield of 0.075.

p-Aminohippurate transport in airways: competitive inhibition.

PubMed

Cloutier, M M; Guernsey, L

1992-05-01

p-Aminohippurate (PAH) transport in canine tracheal epithelium occurs by a HCO3- -PAH exchange process that is located on the luminal membrane and is inhibited by stilbene derivatives. The effects of increasing concentrations of other organic anions, including probenecid (10-250 microM), dibutyryl adenosine 3',5'-cyclic monophosphate (cAMP; 10-1,000 microM), phenol red (10-250 microM), and urate (25-500 microM), and the organic cation tetraethylammonium bromide (TEA; 250 microM) on PAH transport were examined in canine tracheal epithelium mounted in Ussing chambers. Neither phenol red, urate, nor TEA had any effect on electrophysiological properties or unidirectional or net PAH fluxes. In contrast, beginning at 10 microM, both probenecid and cAMP produced significant decreases in unidirectional and net PAH absorption without change in unidirectional PAH secretion. The initial change in net PAH absorption occurred in the absence of any change in electrophysiological properties. Higher concentrations of both probenecid and cAMP produced further decreases in net PAH absorption and significant changes in electrophysiological properties. Probenecid and cAMP increased the apparent Michaelis constant for PAH absorption without affecting maximum transport rate. The inhibitory constant for probenecid was 1.01 +/- 0.06 x 10(-4) M (mean +/- SE) and for cAMP was 5.18 +/- 0.20 x 10(-4) M. We conclude that PAH transport in canine tracheal epithelium demonstrates competitive inhibition by other organic anions and substrate specificity. We also conclude that the affinity of the exchange transport system is higher for probenecid than for PAH and cAMP.

Mid-IR absorption sensing of heavy water using a silicon-on-sapphire waveguide.

PubMed

Singh, Neetesh; Casas-Bedoya, Alvaro; Hudson, Darren D; Read, Andrew; Mägi, Eric; Eggleton, Benjamin J

2016-12-15

We demonstrate a compact silicon-on-sapphire (SOS) strip waveguide sensor for mid-IR absorption spectroscopy. This device can be used for gas and liquid sensing, especially to detect chemically similar molecules and precisely characterize extremely absorptive liquids that are difficult to detect by conventional infrared transmission techniques. We reliably measure concentrations up to 0.25% of heavy water (D₂O) in a D₂O-H₂O mixture at its maximum absorption band at around 4 μm. This complementary metal-oxide-semiconductor (CMOS) compatible SOS D₂O sensor is promising for applications such as measuring body fat content or detection of coolant leakage in nuclear reactors.

Radiative transitions involving the (2p2)(3 Pe) metastable autodetaching of H(-)

NASA Technical Reports Server (NTRS)

Jacobs, V. L.; Bhatia, A. K.; Temkin, A.

1974-01-01

The absorption coefficient for the free-bound transition H (ls) + e(-)+ h omega yields H(-)(2 sq p,(3)P(e)) is calculated (together with the differential emission rate for the inverse process) using ls - 2s - 2p close coupling continuum wave functions and a Hylleraas bound state wave function. A maximum in the absorption and emission spectra is found to occur at a photon wavelength of 1219.5 A, which is 2 A closer to the Lyman alpha line than predicted by the calculations of Drake, and is in closer agreement with the stellar absorption feature identified by Heap and Stecher. The free-bound absorption process appears to be a significant source of continuous ultraviolet opacity.

Contrast-enhanced near-infrared laser mammography with a prototype breast scanner: feasibility study with tissue phantoms and preliminary results of imaging experimental tumors.

PubMed

Boehm, T; Hochmuth, A; Malich, A; Reichenbach, J R; Fleck, M; Kaiser, W A

2001-10-01

Near-infrared (NIR) optical mammography without contrast has a low specificity. The application of optical contrast medium may improve the performance. The concentration-dependent detectability of a new NIR contrast medium was determined with a prototype optical breast scanner. In vivo imaging of experimental tumors was performed. The NIR contrast agent NIR96010 is a newly synthesized, hydrophilic contrast agent for NIR mammography. A concentration-dependent contrast resolution was determined for tissue phantoms consisting of whole milk powder and gelatin. A central part of the phantoms measuring 2 x 2 cm2 without contrast was replaced with phantom material containing 1 micromol/L to 25 nmol/L NIR96010. The composite phantoms were measured with a prototype NIR breast scanner with lasers of lambda1 = 785 nm and lambda2 = 850 nm wavelength. Intensity profiles and standard deviations of the transmission signal in areas with and without contrast were determined by linear fit procedures. Signal-to-noise ratios and spatial resolution as a function of contrast concentration were determined. Near-infrared imaging of five tumor-bearing SCID mice (MX1 breast adenocarcinoma, tumor diameter 5-10 mm) was performed before and after intravenous application of 2 micromol/kg NIR96010. Spectrometry showed an absorption maximum of the contrast agent at 755 nm. No spectral shifts occurred in protein-containing solution. Signal-to-noise ratio in the transmission intensity profiles ranged from 1.1 at 25 nmol/L contrast to 28 at 1 micromol/L. At concentrations <40 nmol/L, no differentiation from the background was possible. The transitional area between the contrast-free edge of the phantom and the central contrast-containing part appeared in the profiles as a steep increase with a width of 4.2 +/- 1.8 mm. The experimental tumors were detectable in nonenhanced images as well as contrast-enhanced images, with better delineation after contrast administration. In postcontrast absorption profiles, a 44.1% +/- 11.3% greater absorption increase was seen in tumor tissue compared with normal tissue. The laser wavelength lambda1 of the prototype laser mammography device was not situated at maximum absorption of the contrast agent NIR96010 but on the descending shoulder of the absorption spectrum. This implies a 20% signal loss for contrast detection. Despite the nonideal measurement conditions, concentrations as low as 40 nmol/L were detectable in vitro. In vivo, all tumors were detectable in color-coded nonenhanced scans as well as in contrast-enhanced scans, with better delineation after contrast administration.

Selective spectrophotometric determination of TNT using a dicyclohexylamine-based colorimetric sensor.

PubMed

Erçağ, Erol; Uzer, Ayşem; Apak, Reşat

2009-05-15

Because of the extremely heterogeneous distribution of explosives in contaminated soils, on-site colorimetric methods are efficient tools to assess the nature and extent of contamination. To meet the need for rapid and low-cost chemical sensing of explosive traces or residues in soil and post-blast debris, a colorimetric absorption-based sensor for trinitrotoluene (TNT) determination has been developed. The charge-transfer (CT) reagent (dicyclohexylamine, DCHA) is entrapped in a polyvinylchloride (PVC) polymer matrix plasticised with dioctylphtalate (DOP), and moulded into a transparent sensor membrane sliced into test strips capable of sensing TNT showing an absorption maximum at 530 nm when placed in a 1-mm spectrophotometer cell. The sensor gave a linear absorption response to 5-50 mg L(-1) TNT solutions in 30% aqueous acetone with limit of detection (LOD): 3 mg L(-1). The sensor is only affected by tetryl, but not by RDX, pentaerythritoltetranitrate (PETN), dinitrotoluene (DNT), and picric acid. The proposed method was statistically validated for TNT assay against high performance liquid chromatography (HPLC) using a standard sample of Comp B. The developed sensor was relatively resistant to air and water, was of low-cost and high specificity, gave a rapid and reproducible response, and was suitable for field use of TNT determination in both dry and humid soil and groundwater with a portable colorimeter.

H(+)/solute-induced intracellular acidification leads to selective activation of apical Na(+)/H(+) exchange in human intestinal epithelial cells.

PubMed

Thwaites, D T; Ford, D; Glanville, M; Simmons, N L

1999-09-01

The intestinal absorption of many nutrients and drug molecules is mediated by ion-driven transport mechanisms in the intestinal enterocyte plasma membrane. Clearly, the establishment and maintenance of the driving forces - transepithelial ion gradients - are vital for maximum nutrient absorption. The purpose of this study was to determine the nature of intracellular pH (pH(i)) regulation in response to H(+)-coupled transport at the apical membrane of human intestinal epithelial Caco-2 cells. Using isoform-specific primers, mRNA transcripts of the Na(+)/H(+) exchangers NHE1, NHE2, and NHE3 were detected by RT-PCR, and identities were confirmed by sequencing. The functional profile of Na(+)/H(+) exchange was determined by a combination of pH(i), (22)Na(+) influx, and EIPA inhibition experiments. Functional NHE1 and NHE3 activities were identified at the basolateral and apical membranes, respectively. H(+)/solute-induced acidification (using glycylsarcosine or beta-alanine) led to Na(+)-dependent, EIPA-inhibitable pH(i) recovery or EIPA-inhibitable (22)Na(+) influx at the apical membrane only. Selective activation of apical (but not basolateral) Na(+)/H(+) exchange by H(+)/solute cotransport demonstrates that coordinated activity of H(+)/solute symport with apical Na(+)/H(+) exchange optimizes the efficient absorption of nutrients and Na(+), while maintaining pH(i) and the ion gradients involved in driving transport.

Multistage quantum absorption heat pumps.

PubMed

Correa, Luis A

2014-04-01

It is well known that heat pumps, while being all limited by the same basic thermodynamic laws, may find realization on systems as "small" and "quantum" as a three-level maser. In order to quantitatively assess how the performance of these devices scales with their size, we design generalized N-dimensional ideal heat pumps by merging N-2 elementary three-level stages. We set them to operate in the absorption chiller mode between given hot and cold baths and study their maximum achievable cooling power and the corresponding efficiency as a function of N. While the efficiency at maximum power is roughly size-independent, the power itself slightly increases with the dimension, quickly saturating to a constant. Thus, interestingly, scaling up autonomous quantum heat pumps does not render a significant enhancement beyond the optimal double-stage configuration.

A cloud physics investigation utilizing Skylab data

NASA Technical Reports Server (NTRS)

Alishouse, J.; Jacobowitz, H.; Wark, D. (Principal Investigator)

1975-01-01

The author has identified the following significant results. The Lowtran 2 program, S191 spectral response, and solar spectrum were used to compute the expected absorption by 2.0 micron band for a variety of cloud pressure levels and solar zenith angles. Analysis of the three long wavelength data channels continued in which it was found necessary to impose a minimum radiance criterion. It was also found necessary to modify the computer program to permit the computation of mean values and standard deviations for selected subsets of data on a given tape. A technique for computing the integrated absorption in the A band was devised. The technique normalizes the relative maximum at approximately .78 micron to the solar irradiance curve and then adjusts the relative maximum at approximately .74 micron to fit the solar curve.

Optical switching property of electromagnetically induced transparency in a Λ system

NASA Astrophysics Data System (ADS)

Zhang, Lianshui; Wang, Jian; Feng, Xiaomin; Yang, Lijun; Li, Xiaoli; Zhao, Min

2008-12-01

In this paper we study the coherent transient property of a Λ-three-level system (Ωd = 0) and a quasi- Λ -four-level system (Ωd>0). Optical switching of the probe field can be achieved by applying a pulsed coupling field or rf field. In Λ -shaped three-level system, when the coupling field was switched on, there is a almost total transparency of the probe field and the time required for the absorption changing from 90% to 10% of the maximum absorption is 2.9Γ0 (Γ0 is spontaneous emission lifetime). When the coupling field was switched off, there is an initial increase of the probe field absorption and then gradually evolves to the maximum of absorption of the two-level absorption, the time required for the absorption of the system changing from 10% to 90% is 4.2Γ0. In four-level system, where rf driving field is used as switching field, to achieve the same depth of the optical switching, the time of the optical switching is 2.5Γ0 and 6.1Γ0, respectively. The results show that with the same depth of the optical switching, the switch-on time of the four-level system is shorter than that of the three-level system, while the switch-off time of the four-level system is longer. The depth of the optical switching of the four-level system was much larger than that of the three-level system, where the depth of the optical switching of the latter is merely 14.8% of that of the former. The speed of optical switching of the two systems can be increased by the increase of Rabi frequency of coupling field or rf field.

International Intercomparison of Specific Absorption Rates in a Flat Absorbing Phantom in the Near-Field of Dipole Antennas

PubMed Central

Davis, Christopher C.; Beard, Brian B.; Tillman, Ahlia; Rzasa, John; Merideth, Eric; Balzano, Quirino

2018-01-01

This paper reports the results of an international intercomparison of the specific absorption rates (SARs) measured in a flat-bottomed container (flat phantom), filled with human head tissue simulant fluid, placed in the near-field of custom-built dipole antennas operating at 900 and 1800 MHz, respectively. These tests of the reliability of experimental SAR measurements have been conducted as part of a verification of the ways in which wireless phones are tested and certified for compliance with safety standards. The measurements are made using small electric-field probes scanned in the simulant fluid in the phantom to record the spatial SAR distribution. The intercomparison involved a standard flat phantom, antennas, power meters, and RF components being circulated among 15 different governmental and industrial laboratories. At the conclusion of each laboratory’s measurements, the following results were communicated to the coordinators: Spatial SAR scans at 900 and 1800 MHz and 1 and 10 g maximum spatial SAR averages for cubic volumes at 900 and 1800 MHz. The overall results, given as meanstandard deviation, are the following: at 900 MHz, 1 g average 7.850.76; 10 g average 5.160.45; at 1800 MHz, 1 g average 18.44 ± 1.65; 10 g average 10.14 ± 0.85, all measured in units of watt per kilogram, per watt of radiated power. PMID:29520117

Would the solvent effect be the main cause of band shift in the theoretical absorption spectrum of large lanthanide complexes?

NASA Astrophysics Data System (ADS)

Freire, Ricardo O.; Rodrigues, Nailton M.; Rocha, Gerd B.; Gimenez, Iara F.; da Costa Junior, Nivan B.

2011-06-01

As most reactions take place in solution, the study of solvent effects on relevant molecular properties - either by experimental or theoretical methods - is crucial for the design of new processes and prediction of technological properties. In spite of this, only few works focusing the influence of the solvent nature specifically on the spectroscopic properties of lanthanide complexes can be found in the literature. The present work describes a theoretical study of the solvent effect on the prediction of the absorption spectra for lanthanide complexes, but other possible relevant factors have been also considered such as the molecular geometry and the excitation window used for interaction configuration (CI) calculations. The [Eu(ETA) 2· nH 2O] +1 complex has been chosen as an ideal candidate for this type of study due to its small number of atoms (only 49) and also because the absorption spectrum exhibits a single band. Two Monte Carlo simulations were performed, the first one considering the [Eu(ETA) 2] +1 complex in 400 water molecules, evidencing that the complex presents four coordinated water molecules. The second simulation considered the [Eu(ETA) 2·4H 2O] +1 complex in 400 ethanol molecules, in order to evaluate the solvent effect on the shift of the maximum absorption in calculated spectra, compared to the experimental one. Quantum chemical studies were also performed in order to evaluate the effect of the accuracy of calculated ground state geometry on the prediction of absorption spectra. The influence of the excitation window used for CI calculations on the spectral shift was also evaluated. No significant solvent effect was found on the prediction of the absorption spectrum for [Eu(ETA) 2·4H 2O] +1 complex. A small but significant effect of the ground state geometry on the transition energy and oscillator strength was also observed. Finally it must be emphasized that the absorption spectra of lanthanide complexes can be predicted with great accuracy by the combined use of semiempirical Sparkle/AM1 and INDO/S-CIS as long as the largest possible excitation window is used in the configuration interaction calculation.

Stellar Contrails in Quasi-stellar Objects: The Origin of Broad Absorption Lines

NASA Astrophysics Data System (ADS)

Scoville, Nick; Norman, Colin

1995-10-01

Active galactic nuclei (AGNs) and quasars often exhibit infrared excesses at λ = 2-10 microns attributable to thermal dust emission. In this paper we propose that this hot dust is supplied by circumstellar mass loss from evolved stars in the nuclear star cluster. The physics of the mass-loss dust, specifically the evaporation temperature, is a critical parameter in determining the accretion rate of mass-loss material onto the central AGN. For standard interstellar dust grains with an evaporation temperature of 1800 K the dust is destroyed inside a radius of 1 pc from a central luminosity source of 5 × 10 Lsun. The mass-loss material inside 1 pc will therefore have a lower radiation pressure efficiency and accrete inward. Outside this critical radius, dust may survive, and the mass loss is accelerated outward owing to the high radiation pressure efficiency of the dust mixed with the gas. The outflowing material will consist of discrete trails of debris shed by the individual mass-loss stars, and we suggest that these trails produce the broad absorption lines (BALs) seen in 5%-10% of QSOs. The model accounts naturally for the maximum outflow velocities seen in the BALs (˜30,000 km s-1 and varying as L¼) since this maximum terminal velocity occurs for matter originating at the inner edge of the radiative equilibrium dust survival zone. Although the radiation pressure acts on the dust, individual grains will be highly charged (Z ˜ 103+), and the grains are therefore strongly coupled to the gas through the ambient magnetic fields. Numerical hydrodynamic calculations were done to follow the evolution of mass-loss material. As the orbiting debris is driven outward by radiation pressure, the trail forms a spiral with initially high pitch angle (˜85°). The trails are compressed into thin ribbons in the radial direction initially by the radiation pressure gradients due to absorption within the trail. After reaching > 104 km s-1 radial velocity, the compression can be maintained by ram pressure due to an ambient gas of modest density (˜102 cm-3). Each of the stellar contrails will have mean column density ˜1019-1021 cm-2, volume density ˜108-109 cm-3, and thickness 1011-1012 cm along the line of sight to the AGN corresponding to parameters deduced from observations of the BAL clouds. Assuming minimal expansion perpendicular to the line of sight at the speed of sound, the width of the trails is 1015-1016 cm, or 102-103 times the line-of-sight depth. Since the UV-emitting accretion disk probably has a radius of about 2 × 1016 cm, a single trail will only partially cover the continuum, but for the column densities quoted above the observed absorption lines (e.g., C IV) will be optically thick with τ > 10. Since the contrails are nearly radial just after leaving the star when the maximum outward acceleration occurs, a large range of velocities (˜4000 km s-1) will be seen in absorption of the QSO light from each trail, and only a few disk-crossing trails are needed to account for the full width of broad absorption line troughs.

Measuring Binding Affinity of Protein-Ligand Interaction Using Spectrophotometry: Binding of Neutral Red to Riboflavin-Binding Protein

ERIC Educational Resources Information Center

Chenprakhon, Pirom; Sucharitakul, Jeerus; Panijpan, Bhinyo; Chaiyen, Pimchai

2010-01-01

The dissociation constant, K[subscript d], of the binding of riboflavin-binding protein (RP) with neutral red (NR) can be determined by titrating RP to a fixed concentration of NR. Upon adding RP to the NR solution, the maximum absorption peak of NR shifts to 545 nm from 450 nm for the free NR. The change of the absorption can be used to determine…

High-Performance Liquid Chromatography (HPLC) Measurements of Phytoplankton Pigment Distributions of Ocean Waters

DTIC Science & Technology

1988-11-01

coccolithophorids 19. ABSTRACT (CanMyw on rviosfe Inhcesway aM den*t byblock nmber) Until the application of high-performance liquid chromatography (HPLC) to... phycocyanin , has a maximum 0 01 absorption peak. The spectra for the 008 chlorophyll degradation products (chlo- 0.06 rophyllides, phaeophorbides and...phaeo- phytins) which are not shown in Figure z I have similar absorption maxima as their associated chlorophylls, 002 , Until the application of high

Quantification of water in hydrous ringwoodite

DOE PAGES

Thomas, Sylvia -Monique; Jacobsen, Steven D.; Bina, Craig R.; ...

2015-01-28

Here, ringwoodite, γ-(Mg,Fe) 2SiO 4, in the lower 150 km of Earth’s mantle transition zone (410-660 km depth) can incorporate up to 1.5-2 wt% H 2O as hydroxyl defects. We present a mineral-specific IR calibration for the absolute water content in hydrous ringwoodite by combining results from Raman spectroscopy, secondary ion mass spectrometery (SIMS) and proton-proton (pp)-scattering on a suite of synthetic Mg- and Fe-bearing hydrous ringwoodites. H 2O concentrations in the crystals studied here range from 0.46 to 1.7 wt% H 2O (absolute methods), with the maximum H 2O in the same sample giving 2.5 wt% by SIMS calibration.more » Anchoring our spectroscopic results to absolute H-atom concentrations from pp-scattering measurements, we report frequency-dependent integrated IR-absorption coefficients for water in ringwoodite ranging from 78180 to 158880 L mol -1cm -2, depending upon frequency of the OH absorption. We further report a linear wavenumber IR calibration for H 2O quantification in hydrous ringwoodite across the Mg 2SiO 4-Fe 2SiO 4 solid solution, which will lead to more accurate estimations of the water content in both laboratory-grown and naturally occurring ringwoodites. Re-evaluation of the IR spectrum for a natural hydrous ringwoodite inclusion in diamond from the study of the crystal contains 1.43 ± 0.27 wt% H 2O, thus confirming near-maximum amounts of H 2O for this sample from the transition zone.« less

Upconversion single-microbelt photodetector via two-photon absorption simultaneous

NASA Astrophysics Data System (ADS)

Lou, Guanlin; Wu, Yanyan; Zhu, Hai; Li, Jinyu; Chen, Anqi; Chen, Zhiyang; Liang, Yunfeng; Ren, Yuhao; Gui, Xuchun; Zhong, Dingyong; Qiu, Zhiren; Tang, Zikang; Su, Shi C.

2018-05-01

Single microbelt (MB) photodetectors with metal–semiconductor-metal structure have been demonstrated and characterized comprehensively. For single-photon absorption, the maximum responsivity of ZnO-MB photodetector can reach as high as 1.4  ×  105 A W‑1 at 20 V bias. The results about photoresponse of MB-detector reveals that two relaxation mechanisms contribute to the carrier decay time. Moreover, the two-photon absorption upconversion photoresponsivity in the single-MB detector has also been realized, which is the first report about the two-photon absorption detector to the best of our knowledge. The excellent two-photon absorption photoresponsivity characteristic of the MB device can be available not only for detector but also for solar cell and biomedical imaging. The above results present a significant step towards future fabrication of single micro/nano-structure based multiphoton excitation optoelectronic devices.

Application of gas cyclone-liquid jet absorption separator for purification of tail gas containing ammonia.

PubMed

Ma, Liang; Zhao, Zhi-Huang; Peng, Lv; Yang, Xue-Jing; Fu, Peng-Bo; Liu, Yi; Huang, Yuan

2018-05-31

In this experiment, with stainless steel gas cyclone-liquid jet absorption separator as carrier, NH 3 as experimental gas, and water and H 3 PO 4 solution as absorbents, corresponding NH 3 absorption rate change is obtained through the adjustment of experimental parameters, such as NH 3 inlet concentration, inlet velocity of mixed gas, injection flow rate of absorbent, temperature of absorbent, and H 3 PO 4 absorbent concentration. The NH 3 absorption rate decreases with the increase in NH 3 inlet concentration and inlet gas velocity. The NH 3 absorption rate will increase first and then tends to remain unchanged after reaching a certain degree with the increase in liquid injection flow rate and absorbent concentration. The NH 3 absorption rate will increase first and then decrease with the increase in the absorbent temperature. The maximum NH 3 removal efficiencies of water and H 3 PO 4 were 96% and 99%, respectively.

Estimation of head tissue-specific exposure from mobile phones based on measurements in the homogeneous SAM head.

PubMed

Gosselin, Marie-Christine; Kühn, Sven; Crespo-Valero, Pedro; Cherubini, Emilio; Zefferer, Marcel; Christ, Andreas; Kuster, Niels

2011-09-01

The maximum spatial peak exposure of each commercial mobile phone determined in compliance with the relevant safety and product standards is publicly available. However, this information is not sufficient for epidemiological studies aiming to correlate the use of mobile phones with specific cancers or to behavioral alterations, as the dominant location of the exposure may be anywhere in the head between the chin to above the ear, depending on the phone design. The objective of this study was to develop a methodology to determine tissue-specific exposure by expanding the post-processing of the measured surface or volume scans using standardized compliance testing equipment, that is, specific absorption rate (SAR) scanners. The transformation matrix was developed using the results from generic dipoles to evaluate the relation between the SAR in many brain regions of the Virtual Family anatomical phantoms and in virtual brain regions mapped onto the homogeneous SAM head. A set of transformation factors was derived to correlate the SAR induced in the SAM head to the SAR in the anatomical heads. The evaluation included the uncertainty associated with each factor, arising from the anatomical differences between the phantoms (typically less than 6 dB (4×)). The applicability of these factors was validated by performing simulations of four head models exposed to four realistic mobile phone models. The new methodology enables the reliable determination of the maximum and averaged exposure of specific tissues and functional brain regions to mobile phones when combined with mobile phone power control data, and therefore greatly strengthens epidemiological evaluations and improves information for the consumer. Copyright © 2011 Wiley-Liss, Inc.

Phosphoric acid purification through different raw and activated clay materials (Southern Tunisia)

NASA Astrophysics Data System (ADS)

Trabelsi, Wafa; Tlili, Ali

2017-05-01

This study concerns the purification of Tunisian phosphoric acid produced by the Tunisian Chemical Group (TCG), using raw and activated clays materials from Southern Tunisia. The Gafsa basin clays samples (Jebel Hamadi (JHM); Jebel Stah (JS) and the El Hamma sample (Jebel Aïdoudi (JAD)) were activated with 3 M, HCl solution. Phosphoric acid purification was performed on raw and activated clays. Mineralogical characterisation was carried out using the X-ray powder diffraction method and infrared absorption spectroscopy. Textural changes between raw and activated clays were identified using SEM observations and specific surface analysis. Jebel Hamadi clays were almost dominated by smectite associated with kaolinite and illite traces, while Jebel Stah and Jebel Aïdoudi clays were composed of the association of smectite, illite and kaolinite. It is worth noting that the position of the smectite (001) reflection increased after the acidic activation in all studied samples, indicating the relaxation of the smectite structure along the c-axis. This was corroborated by the increasing specific surface area of the clay particles with the activation process. The specific surface area was close to 50 m2/g and 200 m2/g, for raw and activated materials, respectively. The maximum phosphoric acid purification was obtained by using activated clays with 3 N HCl for 4 h. This performance correlated with the maximum of the external specific surface area which generated strong acid sites. Furthermore, the best results of phosphoric acids purification from TCG were obtained at a specific consumption equivalent to 30 Kg of clay/ton of P2O5. These results showed that the best phosphoric acid purification was yielded by Jebel Aïdoudi clay. In all cases, the highest organic carbon reduction rates in the phosphoric acid after filtration were obtained at 90°C.

Dissociative absorption: An empirically unique, clinically relevant, dissociative factor.

PubMed

Soffer-Dudek, Nirit; Lassri, Dana; Soffer-Dudek, Nir; Shahar, Golan

2015-11-01

Research of dissociative absorption has raised two questions: (a) Is absorption a unique dissociative factor within a three-factor structure, or a part of one general dissociative factor? Even when three factors are found, the specificity of the absorption factor is questionable. (b) Is absorption implicated in psychopathology? Although commonly viewed as "non-clinical" dissociation, absorption was recently hypothesized to be specifically associated with obsessive-compulsive symptoms. To address these questions, we conducted exploratory and confirmatory factor analyses on 679 undergraduates. Analyses supported the three-factor model, and a "purified" absorption scale was extracted from the original inclusive absorption factor. The purified scale predicted several psychopathology scales. As hypothesized, absorption was a stronger predictor of obsessive-compulsive symptoms than of general psychopathology. In addition, absorption was the only dissociative scale that longitudinally predicted obsessive-compulsive symptoms. We conclude that absorption is a unique and clinically relevant dissociative tendency that is particularly meaningful to obsessive-compulsive symptoms. Copyright © 2015 Elsevier Inc. All rights reserved.

Activated carbon electrode from banana-peel waste for supercapacitor applications

NASA Astrophysics Data System (ADS)

Taer, E.; Taslim, R.; Aini, Z.; Hartati, S. D.; Mustika, W. S.

2017-01-01

Seven types of activated carbon electrode (ACM) have been produced from the banana peel waste for supercapacitor application. The difference type of the electrode was synthesized by the various conditions of carbonization and activation. The production of the ACM was begun by the milling process and molded by a solution casting technique. The next step was followed by drying, carbonization and activation process. Physical properties of the ACM were studied by the N2 gas absorption-desorption method to characterize the specific surface area of the sample. On the other side, the electrochemical properties such as specific capacitance (Csp), specific energy (E) and specific power (P) were resulted by calculating the current (I) and voltage (V) data from the cyclic voltammetry testing. Based on the data obtained the surface area of the ACM has a significant relationship with the electrochemical properties. The specific surface area (SBET), Csp, E and P were found the maximum value as high as 581m2 / g, 68 F/g, 0.75 Wh/kg and 31 W/kg, respectively. Further more, this paper were also analyzed the relationship between electrochemical properties of supercapacitor with the degree of crystallization of the ACM.

Synthesis, photophysical, structural and electronic properties of novel regioisomerically pure 1,7-disubstituted perylene-3,4,9,10-tetracarboxylic monoimide dibutylester derivatives

NASA Astrophysics Data System (ADS)

Ozser, Mustafa E.; Mohiuddin, Obaidullah

2018-04-01

Three new isomerically pure 1,7-disubstituted perylene-3,4,9,10-tetracarboxylic monoimide dibutylester derivatives namely; N-[2-(diethylamino)ethyl]-1,7-dibromoperylene-3,4,9,10-tetracarboxy monoimide dibutylester (PMD-1), N-[2-(diethylamino)ethyl]-1,7-di(4-tert-butylphenoxy)perylene-3,4,9,10-tetracarboxy monoimide dibutylester (PMD-2) and N-[2-(diethylamino)ethyl]-1,7-di(pyrrolidinyl)perylene-3,4,9,10-tetracarboxy monoimide dibutylester (PMD-3), have been synthesized and their electronic absorption spectra, and steady-state fluorescence were investigated experimentally as well as by using density functional theory (DFT) calculations. All three compounds show good solubility in toluene and chloroform. Attachment of two tert-butylphenoxy groups at the 1,7-positions in PMD-2 resulted in a red shifted absorption band with an absorption maximum at 518 nm. UV/Vis absorption spectrum of PMD-3 bearing electron donating pyrrolidinyl groups at the 1,7-positions shows a broad absorption band within the visible region, extending to red region. Absorption maximum of lowest energy transition now shifts to 653 nm. In addition to the S0 → S1 absorption bands, bands belonging to S0 → S2 electronic transitions were observed at 378, 386, and 411 nm for PMD-1, PMD-2, and PMD-3 respectively. Compounds PMD-1, PMD-2 and PMD-3 display low fluorescence quantum yields of 0.027, 0.040 and 0.001, respectively in chloroform. DFT calculations revealed that the attachment of electron donating groups at 1,7-positions of perylene core, results in an increase in frontier orbitals energy levels. Observed energy increase in HOMO level is larger in each case, compared to the energy increase in LUMO levels, due to the higher contribution of side groups to HOMO. DFT calculated band gaps for PMD-1, PMD-2 and PMD-3 are 2.68, 2.63 and 2.29 eV respectively.

Thermal emission and absorption of radiation in finite inverted-opal photonic crystals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Florescu, Marian; Stimpson, Andrew J.; Lee, Hwang

We study theoretically the optical properties of a finite inverted-opal photonic crystal. The light-matter interaction is strongly affected by the presence of the three-dimensional photonic crystal and the alterations of the light emission and absorption processes can be used to suppress or enhance the thermal emissivity and absorptivity of the dielectric structure. We investigate the influence of the absorption present in the system on the relevant band edge frequencies that control the optical response of the photonic crystal. Our study reveals that the absorption processes cause spectral broadening and shifting of the band edge optical resonances, and determine a strongmore » reduction of the photonic band gap spectral range. Using the angular and spectral dependence of the band edge frequencies for stop bands along different directions, we argue that by matching the blackbody emission spectrum peak with a prescribed maximum of the absorption coefficient, it is possible to achieve an angle-sensitive enhancement of the thermal emission/absorption of radiation. This result opens a way to realize a frequency-sensitive and angle-sensitive photonic crystal absorbers/emitters.« less

A new chlorophycean nickel hyperaccumulator.

PubMed

Harish; Sundaramoorthy, S; Kumar, Devendra; Vaijapurkar, S G

2008-06-01

Bioremediation of nickel by chlorophycean bioremediator, Chlorococcum hemicolum was investigated. The growth rates at various concentrations of Ni2+ were assessed in terms of protein level and 12 mg L(-1) of the Ni2+ is the tolerance limit (46.76% level of growth kinetics). Absorption/adsorption kinetics was estimated after 240 h of Ni2+ treatments. Absorptions were higher than adsorption with maximum accumulation factor (AF) of 1.37. Ni2+ concentration and absorption were linearly related (r=0.98; p>0.01). Other biochemical parameters like total sugar, chlorophyll and carotenoids were also quantified to correlate the state of metabolism and these exhibited reduction due to heavy metal stress.

Analysis of in situ electric field and specific absorption rate in human models for wireless power transfer system with induction coupling.

PubMed

Sunohara, Tetsu; Hirata, Akimasa; Laakso, Ilkka; Onishi, Teruo

2014-07-21

This study investigates the specific absorption rate (SAR) and the in situ electric field in anatomically based human models for the magnetic field from an inductive wireless power transfer system developed on the basis of the specifications of the wireless power consortium. The transfer system consists of two induction coils covered by magnetic sheets. Both the waiting and charging conditions are considered. The transfer frequency considered in this study is 140 kHz, which is within the range where the magneto-quasi-static approximation is valid. The SAR and in situ electric field in the chest and arm of the models are calculated by numerically solving the scalar potential finite difference equation. The electromagnetic modelling of the coils in the wireless power transfer system is verified by comparing the computed and measured magnetic field distributions. The results indicate that the peak value of the SAR averaged over a 10 g of tissue and that of the in situ electric field are 72 nW kg(-1) and 91 mV m(-1) for a transmitted power of 1 W, Consequently, the maximum allowable transmitted powers satisfying the exposure limits of the SAR (2 W kg(-1)) and the in situ electric field (18.9 V m(-1)) are found to be 28 MW and 43 kW. The computational results show that the in situ electric field in the chest is the most restrictive factor when compliance with the wireless power transfer system is evaluated according to international guidelines.

Electromagnetic properties of absorber fabric coated with BaFe12O19/MWCNTs/PANi nanocomposite in X and Ku bands frequency

NASA Astrophysics Data System (ADS)

Afzali, Arezoo; Mottaghitalab, Vahid; Seyyed Afghahi, Seyyed Salman; Jafarian, Mojtaba; Atassi, Yomen

2017-11-01

Current investigation focuses on the electromagnetic properties of nonwoven fabric coated with BaFe12O19 (BHF) /MWCNTs/PANi nanocomposite in X and Ku bands. The BHF/MWCNTs and BHF/MWCNTs/PANi nanocomposites are prepared using the sol gel and in-situ polymerization methods respectively. The absorbent fabric was prepared based on applying a 40 wt% of BHF/MWCNTs/PANi nanocomposite in silicon resin on nonwoven fabric via roller coating technique The X-ray diffraction (XRD), scanning electron microscopy (SEM), vibrating sample magnetometer (VSM) and vector network analysis (VNA) are used to peruse microstructural, magnetic and electromagnetic features of the composite and absorber fabric respectively. The microscopic images of the fabric coated with magnetic nanocomposite shows a homogenous layer of nanoparticles on the fabric surface. The maximum reflection loss of binary nano-composite BHF/MWCNTs was measured about -28.50 dB at 11.72 GHz with 1.7 GHz bandwidth (RL < -10 dB) in X band. Moreover in Ku band, the maximum reflection loss is -29.66 dB at 15.78 GHz with 3.2 GHz bandwidths. Also the ternary nanocomposite BHF/MWCNTs/PANi exhibits a broad band absorber over a wide range of X band with a maximum reflection loss of -36.2 dB at 10.2 GHz with 1.5 GHz bandwidth and in the Ku band has arrived a maximum reflection loss of -37.65 dB at 12.84 GHz with 2.43 GHz bandwidth. This result reflects the synergistic effect of the different components with different loss mechanisms. As it is observed due to the presence of PANi in the structure of nanocomposite, the amount of absorption has increased extraordinarily. The absorber fabric exhibits a maximum reflection loss of -24.2 dB at 11.6 GHz with 4 GHz bandwidth in X band. However, in Ku band, the absorber fabric has had the maximum absorption in 16.88 GHz that is about -24.34 dB with 6 GHz bandwidth. Therefore, results indicate that the fabric samples coated represents appreciable maximum absorption value of more than 99% in X and Ku bands which can be attributed to presence of carbon and polyaniline structure in composite material.

Improving Assessments of Chlorophyll Concentration From In Situ Optical Measurements

NASA Astrophysics Data System (ADS)

Nardelli, S.; Twardowski, M.

2016-02-01

Florescence as a chlorophyll proxy has poor accuracy because it is dependent on specific absorption (effective molar absorptivity of packaged chlorophyll in living cells) and fluorescence quantum yield, both of which are highly variable. Absorption is a better proxy, as it is only dependent on specific absorption for packaged chlorophyll, although excepted accuracy in using a nominal specific absorption for all phytoplankton is still about 50%. Bricaud et al. (1995), Ciotti et al. (2002), Mouw et al. (2010), etc. have shown, however, that specific absorption is closely related to the average size of phytoplankton due to the relative packaging effect. Through other methods that have been developed over the years (Morel 1973; Diehl and Haart 1980; Boss et al. 2001; Slade and Boss 2015), it has been shown that measurements of spectral particulate attenuation (i.e., light transmission), and perhaps spectral particulate backscattering, can be used as simple proxies for the average size of the particle field. We therefore test the hypothesis that information on average particle size may be used to better estimate specific absorption for packaged chlorophyll, possibly enabling more accurate retrievals of chlorophyll concentration from optical measurements. The required optical measurements can be made with compact commercial off-the-shelf sensors with high sampling frequency that can be operated from autonomous vehicles; as a result, derived chlorophyll concentration could be resolved at far higher temporal and spatial frequency than is currently possible through extracting chlorophyll from discretely collected samples. This study examines the relationship between specific absorption and the attenuation spectral slope in extensive datasets from Case I and Case II waters found globally in an attempt to assess the link between pigment packaging and phytoplankton size dynamics and the impact on improving the derivation of chlorophyll from in situ optical measurements.

Magneto-optical properties of semi-parabolic plus semi-inverse squared quantum wells

NASA Astrophysics Data System (ADS)

Tung, Luong V.; Vinh, Pham T.; Phuc, Huynh V.

2018-06-01

We theoretically study the optical absorption in a quantum well with the semi-parabolic potential plus the semi-inverse squared potential (SPSIS) in the presence of a static magnetic field in which both one- and two-photon absorption processes have been taken into account. The expression of the magneto-optical absorption coefficient (MOAC) is expressed by the second-order golden rule approximation including the electron-LO phonon interaction. We also use the profile method to obtain the full width at half maximum (FWHM) of the absorption peaks. Our numerical results show that either MOAC or FWHM strongly depends on the confinement frequency, temperature, and magnetic field but their dependence on the parameter β is very weak. The temperature dependence of FWHM is consistent with the previous theoretical and experimental works.

Calculations of a wideband metamaterial absorber using equivalent medium theory

NASA Astrophysics Data System (ADS)

Huang, Xiaojun; Yang, Helin; Wang, Danqi; Yu, Shengqing; Lou, Yanchao; Guo, Ling

2016-08-01

Metamaterial absorbers (MMAs) have drawn increasing attention in many areas due to the fact that they can achieve electromagnetic (EM) waves with unity absorptivity. We demonstrate the design, simulation, experiment and calculation of a wideband MMA based on a loaded double-square-loop (DSL) array of chip resisters. For a normal incidence EM wave, the simulated results show that the absorption of the full width at half maximum is about 9.1 GHz, and the relative bandwidth is 87.1%. Experimental results are in agreement with the simulations. More importantly, equivalent medium theory (EMT) is utilized to calculate the absorptions of the DSL MMA, and the calculated absorptions based on EMT agree with the simulated and measured results. The method based on EMT provides a new way to analysis the mechanism of MMAs.

Improvement of absorption enhancing effects of n-dodecyl-beta-D-maltopyranoside by its colon-specific delivery using chitosan capsules.

PubMed

Fetih, Gihan; Lindberg, Sara; Itoh, Katsuhito; Okada, Naoki; Fujita, Takuya; Habib, Fawsia; Artersson, Per; Attia, Mohammed; Yamamoto, Akira

2005-04-11

In general, absorption enhancing effects of various absorption enhancers were greater in the large intestine than those in the small intestinal regions. Therefore, the effectiveness of absorption enhancers is expected to be remarkably observed, if these enhancers can be delivered to the large intestine with some poorly absorbable drugs after oral administration. In this study, therefore, we examined whether chitosan capsules were effective for the colon-specific delivery of a certain absorption enhancer and can improve the absorption enhancing action of the absorption enhancer after oral administration. 5(6)-Carboxyfluorescein (CF) was used as a model drug to investigate the site-dependent effectiveness of various absorption enhancers by an in situ closed loop method. Sodium glycocholate (NaGC), n-dodecyl-beta-d-maltopyranoside (LM), sodium salicylate (NaSal) and sodium caprate (NaCap) were used as models of absorption enhancers in this study. Overall, the absorption enhancing effects of these enhancers for intestinal absorption of CF were greater in the colon than those in the jejunum and the ileum. Especially, among these enhancers tested in this study, LM showed much greater absorption enhancing effect in the colon than in the jejunum and the ileum. Therefore, LM was selected as a model absorption enhancer to examine the effect of chitosan capsules on the absorption enhancing effect of LM. When CF and LM were orally administered to rats using chitosan capsules, the plasma concentration of CF was much higher than those in other dosage forms including solution and gelatin capsules. Therefore, chitosan capsules may be useful carriers for colon-specific delivery of LM, thereby increasing its absorption enhancing effect from the intestinal membranes.

Passive energy absorption by human muscle-tendon unit is unaffected by increase in intramuscular temperature.

PubMed

Magnusson, S P; Aagaard, P; Larsson, B; Kjaer, M

2000-04-01

The present study measured hamstring intramuscular temperature and muscle-tendon unit viscoelastic properties in healthy young men before and after 10 and 30 min of running with (day S) or without stretch (day NS). On day NS, passive energy absorption and intramuscular temperature were measured before running (Preex), after 10 min of running at 70% of maximum O(2) uptake (Postex10), and after 30 min of running at 75% of maximum O(2) uptake (Postex30). On day S, the protocol was repeated with three stretches (stretches 1-3) added after Postex10. Intramuscular temperature was elevated Postex10 (P < 0.01) and further Postex30 (P < 0.05). On day NS, the total energy absorbed Preex (14.3 +/- 2.3 J), Postex10 (14.5 +/- 3.2 J), and Postex30 (13.5 +/- 2.4 J) was not different. On day S, the total energy absorbed in stretch 3 (10.8 +/- 1.8 J) was lower than that Preex (14.5 +/- 1.7 J, P < 0.01) and Postex10 (13.5 +/- 1.9 J, P < 0.05) but not Postex30 (13.3 +/- 1.8 J). The total energy absorbed Postex30 did not differ from Preex. In conclusion, warm-up and continuous running elevated intramuscular temperature but did not affect the passive energy absorption. Repeated passive stretching reduced the energy absorption immediately; however, the effect did not remain after 30 min of running. These data suggest that passive energy absorption of the human skeletal muscle is insensitive to physiological increases in intramuscular temperature.

Spatio-temporal Convergence of Maximum Daily Light-Use Efficiency Based on Radiation Absorption by Canopy Chlorophyll

DOE PAGES

Zhang, Yao; Xiao, Xiangming; Wolf, Sebastian; ...

2018-04-03

Light-use efficiency (LUE), which quantifies the plants’ efficiency in utilizing solar radiation for photosynthetic carbon fixation, is an important factor for gross primary production (GPP) estimation. Here we use satellite-based solar-induced chlorophyll fluorescence (SIF) as a proxy for photosynthetically active radiation absorbed by chlorophyll (APAR chl) and derive an estimation of the fraction of APAR chl (fPAR chl) from four remotely-sensed vegetation indicators. By comparing maximum LUE estimated at different scales from 127 eddy flux sites, we found that the maximum daily LUE based on PAR absorption by canopy chlorophyll (εmore » $$chl\\atop{max}$$), unlike other expressions of LUE, tends to converge across biome types. The photosynthetic seasonality in tropical forests can also be tracked by the change of fPAR chl, suggesting the corresponding (ε$$chl\\atop{max}$$}$) to have less seasonal variation. Finally, this spatio-temporal convergence of LUE derived from fPAR chl can be used to build simple but robust GPP models and to better constrain process-based models.« less

Influence of synthetic calcium silicates on the strength properties of fine-grained concrete

NASA Astrophysics Data System (ADS)

Yarusova, S. B.; Gordienko, P. S.; Kozin, A. V.; Zhevtun, I. G.; Perfilev, A. V.

2018-04-01

The effect of additives based on acicular calcium hydrosilicates (xonotlite and tobermorite) and wollastonite, obtained from boric acid production waste in autoclave synthesis at a temperature of 220 °C, on the strength of fine-grained concrete, has been studied in this paper. It was shown that when the calcium hydrosilicates and wollastonite are introduced, an increase in the strength characteristics of concrete is observed. After heat and moisture treatment, the maximum increase in strength is observed with the addition of 4% of mass content of calcium hydrosilicates and 6% of mass content of wollastonite. After 28 days of hardening under normal conditions, the maximum increase in strength of concrete is observed with the addition of 4% of mass content of both types of additives. It was shown that the water absorption of concrete decreases with a maximum when 4% of mass content is added, as in the case of the introduction of calcium hydrosilicates, and wollastonite. With a further increase in the number of additives, the amount of water absorption increases, but these values remain below the values for the control sample without additives.

Spatio-temporal Convergence of Maximum Daily Light-Use Efficiency Based on Radiation Absorption by Canopy Chlorophyll

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Yao; Xiao, Xiangming; Wolf, Sebastian

Light-use efficiency (LUE), which quantifies the plants’ efficiency in utilizing solar radiation for photosynthetic carbon fixation, is an important factor for gross primary production (GPP) estimation. Here we use satellite-based solar-induced chlorophyll fluorescence (SIF) as a proxy for photosynthetically active radiation absorbed by chlorophyll (APAR chl) and derive an estimation of the fraction of APAR chl (fPAR chl) from four remotely-sensed vegetation indicators. By comparing maximum LUE estimated at different scales from 127 eddy flux sites, we found that the maximum daily LUE based on PAR absorption by canopy chlorophyll (εmore » $$chl\\atop{max}$$), unlike other expressions of LUE, tends to converge across biome types. The photosynthetic seasonality in tropical forests can also be tracked by the change of fPAR chl, suggesting the corresponding (ε$$chl\\atop{max}$$}$) to have less seasonal variation. Finally, this spatio-temporal convergence of LUE derived from fPAR chl can be used to build simple but robust GPP models and to better constrain process-based models.« less

Exposure system to study hypotheses of ELF and RF electromagnetic field interactions of mobile phones with the central nervous system.

PubMed

Murbach, Manuel; Christopoulou, Maria; Crespo-Valero, Pedro; Achermann, Peter; Kuster, Niels

2012-09-01

A novel exposure system for double-blind human electromagnetic provocation studies has been developed that satisfies the precision, control of fields and potential artifacts, and provides the flexibility to investigate the response of hypotheses-driven electromagnetic field exposure schemes on brain function, ranging from extremely low frequency (ELF) to radio frequency (RF) fields. The system can provide the same exposure of the lateral cerebral cortex at two different RF frequencies (900 and 2140 MHz) but with different exposure levels at subcortical structures, and also allows uniform ELF magnetic field exposure of the brain. The RF modulation and ELF signal are obtained by a freely programmable arbitrary signal generator allowing a wide range of worst-case exposure scenarios to be simulated, including those caused by wireless devices. The maximum achievable RF exposure is larger than 60 W/kg peak spatial specific absorption rate averaged over 10 g of tissue. The maximum ELF magnetic field exposure of the brain is 800 A/m at 50 Hz with a deviation from uniformity of 8% (SD). Copyright © 2012 Wiley Periodicals, Inc.

Absorption spectrum of the firefly luciferin anion isolated in vacuo.

PubMed

Støchkel, Kristian; Milne, Bruce F; Brøndsted Nielsen, Steen

2011-03-24

The excited-state physics of the firefly luciferin anion depends on its chemical environment, and it is therefore important to establish the intrinsic behavior of the bare ion. Here we report electronic absorption spectra of the anion isolated in vacuo obtained at an electrostatic ion storage ring and an accelerator mass spectrometer where ionic dissociation is monitored on a long time scale (from 33 μs and up to 3 ms) and on a short time scale (0-3 μs), respectively. In the ring experiment the yield of all neutrals (mainly CO(2)) as a function of wavelength was measured whereas in the single pass experiment, the abundance of daughter ions formed after loss of CO(2) was recorded to provide action spectra. We find maxima at 535 and 265 nm, and that the band shape is largely determined by the sampling time interval, which is due to the kinetics of the dissociation process. Calculations at the TD-B3LYP/TZVPP++ level predict maximum absorption at 533 and 275 nm for the carboxylate isomer in excellent agreement with the experimental findings. The phenolate isomer lies higher in energy by 0.22 eV, and also its absorption maximum is calculated to be at 463 nm, which is far away from the experimental value. Our data serve to benchmark future theoretical models for bioluminescence from fireflies.

Investigating the 3.3 micron infrared fluorescence from naphthalene following ultraviolet excitation

NASA Technical Reports Server (NTRS)

Williams, Richard M.; Leone, Stephen R.

1994-01-01

Polycyclic aromatic hydrocarbon (PAH) type molecules are proposed as the carriers of the unidentified infrared (UIR) bands. Detailed studies of the 3.3 micrometer infrared emission features from naphthalene, the simplest PAH, following ultraviolet laser excitation are used in the interpretation of the 3.29 micrometer (3040 cm(sup -1)) UIR band. A time-resolved Fourier transform spectrometer is used to record the infrared emission spectrum of gas-phase naphthalene subsequent to ultraviolet excitation facilitated by an excimer laser operated at either 193 nm or 248 nm. The emission spectra differ significantly from the absorption spectrum in the same spectral region. Following 193 nm excitation the maximum in the emission profile is red-shifted 45 cm(sup -1) relative to the absorption maximum; a 25 cm(sup -1) red-shift is observed after 248 nm excitation. The red-shifting of the emission spectrum is reduced as collisional and radiative relaxation removes energy from the highly vibrationally excited molecules. Coupling between the various vibrational modes is thought to account for the differences between absorption and emission spectra. Strong visible emission is also observed following ultraviolet excitation. Visible emission may play an important role in the rate of radiative relaxation, which according to the interstellar PAH hypothesis occurs only by the slow emission of infrared photons. Studying the visible emission properties of PAH type molecules may be useful in the interpretation of the DIB's observed in absorption.

Impact of pentacene film thickness on the photoresponse spectra: Determination of the photocarrier generation mechanism

NASA Astrophysics Data System (ADS)

Gorgolis, S.; Giannopoulou, A.; Anastassopoulos, D.; Kounavis, P.

2012-07-01

Photocurrent response, optical absorption, and x-ray diffraction (XRD) measurements in pentacene films grown on glass substrates are performed in order to obtain an insight into the mobile photocarriers generation mechanism. For film thickness of the order of 50 nm and lower, the photocurrent response spectra are found to follow the optical absorption spectra demonstrating the so-called symbatic response. Upon increasing the film thickness, the photoresponse demonstrates a transition to the so-called antibatic response, which is characterized by a maximum and minimum photocurrent for photon energies of minimum and maximum optical absorption, respectively. The experimental results are not in accordance with the model of important surface recombination rate. By taking into account the XRD patterns, the experimental photoresponse spectra can be reproduced by model simulations assuming efficient exciton dissociation at a narrow layer of the order of 20 nm near the pentacene-substrate interface. The simulated spectra are found sensitive to the film thickness, the absolute optical absorption coefficient, and the diffusion exciton length. By comparing the experimental with the simulated spectra, it is deduced that the excitons, which are created by optical excitation in the spectral region of 1.7-2.2 eV, diffuse with a diffusion length of the order of 10-80 nm to the pentacene-substrate interface where efficiently dissociate into mobile charge carriers.

Polarization dependent two-photon absorption spectroscopy on a naturally occurring biomarker (curcumin) in solution: A theoretical-experimental study

NASA Astrophysics Data System (ADS)

Tiburcio-Moreno, Jose A.; Alvarado-Gil, J. J.; Diaz, Carlos; Echevarria, Lorenzo; Hernández, Florencio E.

2013-09-01

We report on the theoretical-experimental analysis of the two-photon absorption (TPA) and two-photon circular-linear dichroism (TPCLD) spectra of (1E,6E)-1,7-bis(4-hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione (curcumin) in Tetrahydrofuran (THF) solution. The measurement of the full TPA spectrum of this molecule reveals a maximum TPA cross-section at 740 nm, i.e. more than 10 times larger than the maximum reported in the literature at 800 nm for the application of curcumin in bioimaging. The TPCLD spectrum exposes the symmetry of the main excited-states involved in the two-photon excitation process. TD-DFT calculations support the experimental results. These outcomes are expected to expand the application of natural-occurring dyes in bioimaging.

Nonequilibrium quantum absorption refrigerator

NASA Astrophysics Data System (ADS)

Du, Jian-Ying; Zhang, Fu-Lin

2018-06-01

We study a quantum absorption refrigerator, in which a target qubit is cooled by two machine qubits in a nonequilibrium steady-state. It is realized by a strong internal coupling in the two-qubit fridge and a vanishing tripartite interaction among the whole system. The coherence of a machine virtual qubit is investigated as quantumness of the fridge. A necessary condition for cooling shows that the quantum coherence is beneficial to the nonequilibrium fridge, while it is detrimental as far as the maximum coefficient of performance (COP) and the COP at maximum power are concerned. Here, the COP is defined only in terms of heat currents caused by the tripartite interaction, with the one maintaining the two-qubit nonequilibrium state being excluded. The later can be considered to have no direct involvement in extracting heat from the target, as it is not affected by the tripartite interaction.

A rule of unity for human intestinal absorption 3: Application to pharmaceuticals.

PubMed

Patel, Raj B; Yalkowsky, Samuel H

2018-02-01

The rule of unity is based on a simple absorption parameter, Π, that can accurately predict whether or not an orally administered drug will be well absorbed or poorly absorbed. The intrinsic aqueous solubility and octanol-water partition coefficient, along with the drug dose are used to calculate Π. We show that a single delineator value for Π exist that can distinguish whether a drug is likely to be well absorbed (FA ≥ 0.5) or poorly absorbed (FA < 0.5) at any specified dose. The model is shown to give 82.5% correct predictions for over 938 pharmaceuticals. The maximum well-absorbed dose (i.e. the maximum dose that will be more than 50% absorbed) calculated using this model can be utilized as a guideline for drug design and synthesis. Copyright © 2017 John Wiley & Sons, Ltd.

Use of electrothermal atomic absorption spectrometry for size profiling of gold and silver nanoparticles.

PubMed

Panyabut, Teerawat; Sirirat, Natnicha; Siripinyanond, Atitaya

2018-02-13

Electrothermal atomic absorption spectrometry (ETAAS) was applied to investigate the atomization behaviors of gold nanoparticles (AuNPs) and silver nanoparticles (AgNPs) in order to relate with particle size information. At various atomization temperatures from 1400 °C to 2200 °C, the time-dependent atomic absorption peak profiles of AuNPs and AgNPs with varying sizes from 5 nm to 100 nm were examined. With increasing particle size, the maximum absorbance was observed at the longer time. The time at maximum absorbance was found to linearly increase with increasing particle size, suggesting that ETAAS can be applied to provide the size information of nanoparticles. With the atomization temperature of 1600 °C, the mixtures of nanoparticles containing two particle sizes, i.e., 5 nm tannic stabilized AuNPs with 60, 80, 100 nm citrate stabilized AuNPs, were investigated and bimodal peaks were observed. The particle size dependent atomization behaviors of nanoparticles show potential application of ETAAS for providing size information of nanoparticles. The calibration plot between the time at maximum absorbance and the particle size was applied to estimate the particle size of in-house synthesized AuNPs and AgNPs and the results obtained were in good agreement with those from flow field-flow fractionation (FlFFF) and transmission electron microscopy (TEM) techniques. Furthermore, the linear relationship between the activation energy and the particle size was observed. Copyright © 2017 Elsevier B.V. All rights reserved.

Contribution to a bio-optical model for remote sensing of Lena River water

NASA Astrophysics Data System (ADS)

Örek, H.; Doerffer, R.; Röttgers, R.; Boersma, M.; Wiltshire, K. H.

2013-11-01

Bio-optical measurements and sampling were carried out in the delta of the Lena River (northern Siberia, Russia) between 26 June and 4 July 2011. The aim of this study was to determine the inherent optical properties of the Lena water, i.e., absorption, attenuation, and scattering coefficients, during the period of maximum runoff. This aimed to contribute to the development of a bio-optical model for use as the basis for optical remote sensing of coastal water of the Arctic. In this context the absorption by CDOM (colored dissolved organic matter) and particles, and the concentrations of total suspended matter, phytoplankton-pigments, and carbon were measured. CDOM was found to be the most dominant parameter affecting the optical properties of the river, with an absorption coefficient of 4.5-5 m-1 at 442 nm, which was almost four times higher than total particle absorption values at visible wavelength range. The wavelenght-dependence of absorption of the different water constituents was chracterized by determining the semi logarithmic spectral slope. Mean CDOM, and detritus slopes were 0.0149 nm-1(standard deviation (stdev) = 0.0003, n = 18), and 0.0057 nm-1 (stdev = 0.0017, n = 19), respectively, values which are typical for water bodies with high concentrations of dissolved and particulate carbon. Mean chlorophyll a and total suspended matter were 1.8 mg m-3 (stdev = 0.734 n = 18) and 31.9 g m-3 (stdev = 19.94, n = 27), respectively. DOC (dissolved organic carbon) was in the range 8-10 g m-3 and the total particulate carbon (PC) in the range 0.25-1.5 g m-3. The light penetration depth (Secchi disc depth) was in the range 30-90 cm and was highly correlated with the suspended matter concentration. The period of maximum river runoff in June was chosen to obtain bio-optical data when maximum water constituents are transported into the Laptev Sea. However, we are aware that more data from other seasons and other years need to be collected to establish a general bio-optical model of the Lena water and conclusively characterize the light climate with respect to primary production.

Absorption and pharmacokinetics of grapefruit flavanones in beagles.

PubMed

Mata-Bilbao, Maria de Lourdes; Andrés-Lacueva, Cristina; Roura, Elena; Jáuregui, Olga; Escribano, Elvira; Torre, Celina; Lamuela-Raventós, Rosa Maria

2007-07-01

The present study evaluated the pharmacokinetics of three different grapefruit flavanone forms in dog plasma and demonstrated their absorption after an oral intake of a grapefruit extract; pharmacokinetic parameters of these forms were also determined. Ten healthy beagles were administered 70 mg citrus flavonoids as a grapefruit extract contained in capsules, while two additional dogs were used as controls and given an excipient. The grapefruit flavanone naringin, along with its metabolites naringenin and naringenin glucuronide, was detected in dog plasma. Blood samples were collected between 0 and 24 h after administration of the extract. Naringin reached its maximun plasma concentration at around 80 min, whereas naringenin and naringenin glucuronide reached their maximun plasma concentrations at around 20 and 30 min, respectively. Maximum plasma concentrations of naringin, naringenin and naringenin glucuronide (medians and ranges) were 0.24 (0.05-2.08), 0.021 (0.001-0.3) and 0.09 (0.034-0.12) micromol/l, respectively. The areas under the curves were 23.16 l (14.04-70.62) min x micromol/for nariningin, 1.78 (0.09-4.95) min x micromol/l for naringenin and 22.5 (2.74-99.23) min x micromol/l for naringenin glucuronide. The median and range values for mean residence time were 3.3 (1.5-9.3), 2.8 (0.8-11.2) and 8.0 (2.3-13.1) h for naringin, naringenin and naringenin glucuronide, respectively. The results of the present study demonstrate the absorption of grapefruit flavanones via the presence of their metabolites in plasma, thus making an important contribution to the field since the biological activities ascribed to these compounds rely on their specific forms of absorption.

Preliminary evaluation of septic-system absorption-field architecture types in a profile-limited soil.

PubMed

Mathis, Amanda J; Brye, Kristofor R; Dunn, Sam

2011-01-01

Managing household wastewater is an issue that affects hundreds of thousands of people in rural communities nationwide, many of whom rely on septic systems as their primary means of household wastewater disposal. Septic system absorption field products with architectures quite different from traditional pipe-and-gravel systems are being installed in many states with variances from initial design specifications. The objective of this study was to evaluate the performance, as measured by the in-product height of stored solution, of four differing absorption-field product architecture types in a profile-limited soil that was loaded at the maximum allowable rate based on soil morphology. Five chamber, two gravel-less pipe, two polystyrene aggregate, and four pipe-and-gravel systems were installed in a profile-limited, Captina silt loam soil (fine-silty, siliceous, active, mesic Typic Fragiudult) and dosed with raw effluent at rates determined by current State of Arkansas regulations via individual peristaltic pumps. Free-solution monitoring ports were installed within each product, where the depth to free solution was measured periodically and used to evaluate product performance. Data collected from January through August 2009 indicated that preliminary system performance was unaffected by product architecture type. All products performed similarly under dry soil conditions. However, differences among individual products were observed during periods of hydrologic stress (i.e., wet soil conditions). Surfacing of effluent was not observed atop any product, indicating that the current loading rate design method is functioning properly. Preliminary results indicate that some alternative absorption-field products perform similarly to the traditional pipe-and-gravel system, thus providing flexibility and options for homeowners. by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Radiation-damped profiles of extremely high column density neutral hydrogen: implications of cosmic reionization

NASA Astrophysics Data System (ADS)

Bach, Kiehunn

2017-01-01

Incorporating the time-dependent second-order perturbation theory for the Lyman scattering cross-section, we investigate the intergalactic absorption profiles of extremely high column density systems near the end of cosmic reionization. Assuming a representative set of the redshift distribution of neutral hydrogen, we quantitatively examined the impact of inhomogeneous density on the intrinsic absorption profiles. The cumulative absorption by neutral patches in the line of sight mainly affects the far off-centre region of the red damping wing, but the effect is not significant. The shape of the line centre can be modified by the near-zone distribution due to high opacities of the near-resonance scattering. On the other hand, the HWHM (half width at half-maximum) as an effective line width is relatively less sensitive to the local inhomogeneity. Specifically, when the two local damping wings of Lyα and Lyβ are close in spectra of the strongly damped systems, accurate profiles of both lines are required. In the case of N_{H I}≲ 10^{21} { cm^{-2}}, the two-level approximation is marginally applicable for the damping wing fit within 5 - 7 per cent errors. However, as the local column density reaches N_{H I}˜ 10^{22.3} { cm^{-2}}, this classical approximation yields a relative error of a 10 per cent overestimation in the red wing and a 20 per cent underestimation in the blue wing of Lyα. If severe extinction by the Lyα forests is carefully subtracted, the intrinsic absorption profile will provide a better constraint on the local ionized states. For practical applications, an analytic fitting function for the Lyβ scattering is derived.

Photoabsorption cross-section measurements of 32S, 33S, 34S, and 36S sulfur dioxide from 190 to 220 nm

NASA Astrophysics Data System (ADS)

Endo, Yoshiaki; Danielache, Sebastian O.; Ueno, Yuichiro; Hattori, Shohei; Johnson, Matthew S.; Yoshida, Naohiro; Kjaergaard, Henrik G.

2015-03-01

The ultraviolet absorption cross sections of the SO2 isotopologues are essential to understanding the photochemical fractionation of sulfur isotopes in planetary atmospheres. We present measurements of the absorption cross sections of 32SO2, 33SO2, 34SO2, and 36SO2, recorded from 190 to 220 nm at room temperature with a resolution of 0.1 nm (~25 cm-1) made using a dual-beam photospectrometer. The measured absorption cross sections show an apparent pressure dependence and a newly developed analytical model shows that this is caused by underresolved fine structure. The model made possible the calculation of absorption cross sections at the zero-pressure limit that can be used to calculate photolysis rates for atmospheric scenarios. The 32SO2, 33SO2, and 34SO2 cross sections improve upon previously published spectra including fine structure and peak widths. This is the first report of absolute absorption cross sections of the 36SO2 isotopologue for the C1B2-X1A2 band where the amplitude of the vibrational structure is smaller than the other isotopologues throughout the spectrum. Based on the new results, solar UV photodissociation of SO2 produces 34ɛ, 33Ε, and 36Ε isotopic fractionations of +4.6 ± 11.6‰, +8.8 ± 9.0‰, and -8.8 ± 19.6‰, respectively. From these spectra isotopic effects during photolysis in the Archean atmosphere can be calculated and compared to the Archean sedimentary record. Our results suggest that broadband solar UV photolysis is capable of producing the mass-independent fractionation observed in the Archean sedimentary record without involving shielding by specific gaseous compounds in the atmosphere including SO2 itself. The estimated magnitude of 33Ε, for example, is close to the maximum Δ33S observed in the geological record.

Absolute determination of local tropospheric OH concentrations

NASA Technical Reports Server (NTRS)

Armerding, Wolfgang; Comes, Franz-Josef

1994-01-01

Long path absorption (LPA) according to Lambert Beer's law is a method to determine absolute concentrations of trace gases such as tropospheric OH. We have developed a LPA instrument which is based on a rapid tuning of the light source which is a frequency doubled dye laser. The laser is tuned across two or three OH absorption features around 308 nm with a scanning speed of 0.07 cm(exp -1)/microsecond and a repetition rate of 1.3 kHz. This high scanning speed greatly reduces the fluctuation of the light intensity caused by the atmosphere. To obtain the required high sensitivity the laser output power is additionally made constant and stabilized by an electro-optical modulator. The present sensitivity is of the order of a few times 10(exp 5) OH per cm(exp 3) for an acquisition time of a minute and an absorption path length of only 1200 meters so that a folding of the optical path in a multireflection cell was possible leading to a lateral dimension of the cell of a few meters. This allows local measurements to be made. Tropospheric measurements have been carried out in 1991 resulting in the determination of OH diurnal variation at specific days in late summer. Comparison with model calculations have been made. Interferences are mainly due to SO2 absorption. The problem of OH self generation in the multireflection cell is of minor extent. This could be shown by using different experimental methods. The minimum-maximum signal to noise ratio is about 8 x 10(exp -4) for a single scan. Due to the small size of the absorption cell the realization of an open air laboratory is possible in which by use of an additional UV light source or by additional fluxes of trace gases the chemistry can be changed under controlled conditions allowing kinetic studies of tropospheric photochemistry to be made in open air.

Accuracy of available methods for quantifying the heat power generation of nanoparticles for magnetic hyperthermia.

PubMed

Andreu, Irene; Natividad, Eva

2013-12-01

In magnetic hyperthermia, characterising the specific functionality of magnetic nanoparticle arrangements is essential to plan the therapies by simulating maximum achievable temperatures. This functionality, i.e. the heat power released upon application of an alternating magnetic field, is quantified by means of the specific absorption rate (SAR), also referred to as specific loss power (SLP). Many research groups are currently involved in the SAR/SLP determination of newly synthesised materials by several methods, either magnetic or calorimetric, some of which are affected by important and unquantifiable uncertainties that may turn measurements into rough estimates. This paper reviews all these methods, discussing in particular sources of uncertainties, as well as their possible minimisation. In general, magnetic methods, although accurate, do not operate in the conditions of magnetic hyperthermia. Calorimetric methods do, but the easiest to implement, the initial-slope method in isoperibol conditions, derives inaccuracies coming from the lack of matching between thermal models, experimental set-ups and measuring conditions, while the most accurate, the pulse-heating method in adiabatic conditions, requires more complex set-ups.

Microwave absorption properties of Ni/(C, silicides) nanocapsules

PubMed Central

2012-01-01

The microwave absorption properties of Ni/(C, silicides) nanocapsules prepared by an arc discharge method have been studied. The composition and the microstructure of the Ni/(C, silicides) nanocapsules were determined by means of X-ray diffraction, X-ray photoelectric spectroscopy, and transmission electron microscope observations. Silicides, in the forms of SiOx and SiC, mainly exist in the shells of the nanocapsules and result in a large amount of defects at the ‘core/shell’ interfaces as well as in the shells. The complex permittivity and microwave absorption properties of the Ni/(C, silicides) nanocapsules are improved by the doped silicides. Compared with those of Ni/C nanocapsules, the positions of maximum absorption peaks of the Ni/(C, silicides) nanocapsules exhibit large red shifts. An electric dipole model is proposed to explain this red shift phenomenon. PMID:22548846

Impact of absorption in the top layer of a two layer sample on spectroscopic spectral domain interferometry of the bottom layer

NASA Astrophysics Data System (ADS)

Fleischhauer, F.; Feuchter, T.; Leick, L.; Rajendram, R.; Podoleanu, A.

2018-03-01

Spectroscopic spectral domain interferometry and spectroscopic optical coherence tomography combine depth information with spectrally-resolved localised absorption data. These additional data can improve diagnostics by giving access to functional information of the investigated sample. One possible application is measuring oxygenation levels at the retina for earlier detection of several eye diseases. Here measurements with different hollow glass tube phantoms are shown to measure the impact of a superficial absorbing layer on the precision of reconstructed attenuation spectra of a deeper layer. Measurements show that a superficial absorber has no impact on the reconstructed absorption spectrum of the deeper absorber. Even when diluting the concentration of the deeper absorber so far that an incorrect absorption maximum is obtained, still no influence of the superficially placed absorber is identified.

Development of new test procedures for measuring fine and coarse aggregates specific gravity.

DOT National Transportation Integrated Search

2009-09-01

The objective of the research is to develop and evaluate new test methods at determining the specific gravity and absorption of both fine and coarse aggregates. Current methods at determining the specific gravity and absorption of fine and coarse agg...

Analysis and design of an ultrahigh temperature hydrogen-fueled MHD generator

NASA Technical Reports Server (NTRS)

Moder, Jeffrey P.; Myrabo, Leik N.; Kaminski, Deborah A.

1993-01-01

A coupled gas dynamics/radiative heat transfer analysis of partially ionized hydrogen, in local thermodynamic equilibrium, flowing through an ultrahigh temperature (10,000-20,000 K) magnetohydrodynamic (MHD) generator is performed. Gas dynamics are modeled by a set of quasi-one-dimensional, nonlinear differential equations which account for friction, convective and radiative heat transfer, and the interaction between the ionized gas and applied magnetic field. Radiative heat transfer is modeled using nongray, absorbing-emitting 2D and 3D P-1 approximations which permit an arbitrary variation of the spectral absorption coefficient with frequency. Gas dynamics and radiative heat transfer are coupled through the energy equation and through the temperature- and density-dependent absorption coefficient. The resulting nonlinear elliptic problem is solved by iterative methods. Design of such MHD generators as onboard, open-cycle, electric power supplies for a particular advanced airbreathing propulsion concept produced an efficient and compact 128-MWe generator characterized by an extraction ratio of 35.5 percent, a power density of 10,500 MWe/cu m, and a specific (extracted) energy of 324 MJe/kg of hydrogen. The maximum wall heat flux and total wall heat load were 453 MW/sq m and 62 MW, respectively.

[Study on the choice of functional monomer before preparation of myclobutanil molecularly imprinted polymer].

PubMed

Gao, Wen-Hui; Liu, Bo; Li, Xing-Feng; Han, Jun-Hua; Jia, Ying-Min

2014-03-01

To prepare myclobutanil molecularly imprinted polymer, a method was established for the choice of the appropriate functional monomer and its dosage. UV spectra was applied to study the combination form, the effect intensity, the optimal concentration ratio and the numbers of binding sites between myclobutanil and methyl acrylic acid (MAA) or acrylamide (AM) functional monomer. The results showed that hydrogen-bonding interaction could be formed between myclobutanil and methyl acrylic acid (MAA) or acrylamide (AM) functional monomer. The pi electron of the triazole ring conjugated double bond in my clobutanil could transit to pi* conjugate antibonding orbital when it absorbed energy. The formation of hydrogen bond could make pi-->pi* absorption band transit. Maximum absorption wavelength produced red shift with the increase in the functional monomer concentration in the system. The research revealed that the optimal concentration ratios between myclobutanil and the two monomers were c(M):c(MAA) = 1:4, c(M):c(AM) = 1:2. Myclobutanil and the both the functional monomers had the bonding ability, and strong bonding force. The prepared molecularly imprinted polymer using AM as a functional monomer had better stability and specificity of recognition for myclobutanil.

Facile synthesis and photo electrochemical performance of SnSe thin films

NASA Astrophysics Data System (ADS)

Pusawale, S. N.; Jadhav, P. S.; Lokhande, C. D.

2018-05-01

Orthorhombic structured SnSe thin films are synthesized via SILAR (successive ionic layer adsorption and reaction) method on glass substrates. The structural properties of thin films are characterized by x-ray diffraction, scanning electron microscopy studies from which nanoparticles with an elongated shape and hydrophilic behavior are observed. UV -VIS absorption spectroscopy study showed the maximum absorption in the visible region with a direct band gap of 1.55 eV. The photo electrochemical study showed p-type electrical conductivity.

Improved colorimetric determination of serum zinc.

PubMed

Johnson, D J; Djuh, Y Y; Bruton, J; Williams, H L

1977-07-01

We show how zinc may easily be quantified in serum by first using an optimum concentration of guanidine hydrochloride to cause release of zinc from proteins, followed by complexation of released metals with cyanide. The cyanide complex of zinc is preferentially demasked with chloral hydrate, followed by a colorimetric reaction between zinc and 4-(2-pyridylazo)resorcinol. This is a sensitive water-soluble ligand; its complex with zinc has an absorption maximum at 497 nm. Values found by this technique compare favorably with those obtained by atomic absorption spectroscopy.

[Photometric determination of cobalt by the formation of a multi-ligand complex of Co(II)-C16H16N2S2O2-DEA].

PubMed

Xue, Zhao-ming; Xie, An-jian; Huang, Fang-zhi; Ma, Wen

2002-08-01

The new ligand vanillin S-benzyldithocarbazte(HL) and its complex Co(II)-C16H16N2S2O2-DEA was synthesized and characterized by IR, UV-Vis. The optimum color conditions of the complex in 95% ethanol solution(including reaction temperature T, heating time t, and the concentrations of the three components) have been studied by quadratic regression orthogonal design method. According to the quadratic-regression equation, the maximum absorption intensity and optimum color conditions of the complex were calculated. The results were consistent with those gotten by experiment. The influences of common ions on the determination of cobalt and the methods to eliminate the influence are investigated. The maximum absorption peak of the complex is found at 404 nm and molar absorptivity is 5.29 x 10(4) L.mol-1.cm-1. Beer's law is obeyed in the range of 0-20 micrograms.(25 mL)-1 for Co(II). The composition of Co2+ to HL, and DEA in the complex is 1:2:1. The new method was successfully utilized to the determination of cobalt in VB12 and medicine.

A 50-kW Module Power Station of Directly Solar-Pumped Iodine Laser

NASA Technical Reports Server (NTRS)

Choi, S. H.; Lee, J. H.; Meador, W. E.; Conway, E. J.

1997-01-01

The conceptual design of a 50 kW Directly Solar-Pumped Iodine Laser (DSPIL) module was developed for a space-based power station which transmits its coherent-beam power to users such as the moon, Martian rovers, or other satellites with large (greater than 25 kW) electric power requirements. Integration of multiple modules would provide an amount of power that exceeds the power of a single module by combining and directing the coherent beams to the user's receiver. The model developed for the DSPIL system conservatively predicts the laser output power (50 kW) that appears much less than the laser output (93 kW) obtained from the gain volume ratio extrapolation of experimental data. The difference in laser outputs may be attributed to reflector configurations adopted in both design and experiment. Even though the photon absorption by multiple reflections in experimental cavity setup was more efficient, the maximum secondary absorption amounts to be only 24.7 percent of the primary. However, the gain volume ratio shows 86 percent more power output than theoretical estimation that is roughly 60 percent more than the contribution by the secondary absorption. Such a difference indicates that the theoretical model adopted in the study underestimates the overall performance of the DSPIL. This fact may tolerate more flexible and radical selection of design parameters than used in this design study. The design achieves an overall specific power of approximately 5 W/kg and total mass of 10 metric tons.

Plasmonic Enhancement Mechanisms in Solar Energy Harvesting

NASA Astrophysics Data System (ADS)

Cushing, Scott K.

Semiconductor photovoltaics (solar-to-electrical) and photocatalysis (solar-to-chemical) requires sunlight to be converted into excited charge carriers with sufficient lifetimes and mobility to drive a current or photoreaction. Thin semiconductor films are necessary to reduce the charge recombination and mobility losses, but thin films also limit light absorption, reducing the solar energy conversion efficiency. Further, in photocatalysis, the band edges of semiconductor must straddle the redox potentials of a photochemical reaction, reducing light absorption to half the solar spectrum in water splitting. Plasmonics transforms metal nanoparticles into antennas with resonances tuneable across the solar spectrum. If energy can be transferred from the plasmon to the semiconductor, light absorption in the semiconductor can be increased in thin films and occur at energies smaller than the band gap. This thesis investigates why, despite this potential, plasmonic solar energy harvesting techniques rarely appear in top performing solar architectures. To accomplish this goal, the possible plasmonic enhancement mechanisms for solar energy conversion were identified, isolated, and optimized by combining systematic sample design with transient absorption spectroscopy, photoelectrochemical and photocatalytic testing, and theoretical development. Specifically, metal semiconductor nanostructures were designed to modulate the plasmon's scattering, hot carrier, and near field interactions as well as remove heating and self-catalysis effects. Transient absorption spectroscopy then revealed how the structure design affected energy and charge carrier transfer between metal and semiconductor. Correlating this data with wavelength-dependent photoconversion efficiencies and theoretical developments regarding metal-semiconductor interactions identified the origin of the plasmonic enhancement. Using this methodology, it has first been proven that three plasmonic enhancement routes are possible: i) increasing light absorption in the semiconductor by light trapping through scattering, ii) transferring hot carriers from metal to semiconductor after light absorption in the metal, and iii) non-radiative excitation of interband transitions in the semiconductor by plasmon-induced resonant energy transfer (PIRET). The effects of the metal on charge transport and carrier recombination were also revealed. Next, it has been shown that the strength and balance of the three enhancement mechanisms is rooted in the plasmon's dephasing time, or how long it takes the collective electron oscillations to stop being collective. The importance of coherent effects in plasmonic enhancement is also shown. Based on these findings, a thermodynamic balance framework has been used to predict the theoretical maximum efficiency of solar energy conversion in plasmonic metal-semiconductor heterojunctions. These calculations have revealed how plasmonics is best used to address the different light absorption problems in semiconductors, and that not taking into account the plasmon's dephasing is the origin of low plasmonic enhancement Finally, to prove these guidelines, each of the three enhancement mechanisms has been translated into optimal device geometries, showing the plasmon's potential for solar energy harvesting. This dissertation identifies the three possible plasmonic enhancement mechanisms for the first time, discovering a new enhancement mechanism (PIRET) in the process. It has also been shown for the first time that the various plasmon-semiconductor interactions could be rooted in the plasmon's dephasing. This has allowed for the first maximum efficiency estimates which have combined all three enhancement mechanisms to be performed, and revealed that changes in the plasmon's dephasing leads to the disparity in reported plasmonic enhancements. These findings are combined to create optimal device design guidelines, which are proven by fabrication of several devices with top efficiencies in plasmonic solar energy conversion. The knowledge obtained will guide the design of efficient photovoltaics and photocatalysts, helping usher in a renewable energy economy and address current needs of climate change.

Absorption of ethanol, acetone, benzene and 1,2-dichloroethane through human skin in vitro: a test of diffusion model predictions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gajjar, Rachna M.; Kasting, Gerald B., E-mail: Gerald.Kasting@uc.edu

The overall goal of this research was to further develop and improve an existing skin diffusion model by experimentally confirming the predicted absorption rates of topically-applied volatile organic compounds (VOCs) based on their physicochemical properties, the skin surface temperature, and the wind velocity. In vitro human skin permeation of two hydrophilic solvents (acetone and ethanol) and two lipophilic solvents (benzene and 1,2-dichloroethane) was studied in Franz cells placed in a fume hood. Four doses of each {sup 14}C-radiolabed compound were tested — 5, 10, 20, and 40 μL cm{sup −2}, corresponding to specific doses ranging in mass from 5.0 tomore » 63 mg cm{sup −2}. The maximum percentage of radiolabel absorbed into the receptor solutions for all test conditions was 0.3%. Although the absolute absorption of each solvent increased with dose, percentage absorption decreased. This decrease was consistent with the concept of a stratum corneum deposition region, which traps small amounts of solvent in the upper skin layers, decreasing the evaporation rate. The diffusion model satisfactorily described the cumulative absorption of ethanol; however, values for the other VOCs were underpredicted in a manner related to their ability to disrupt or solubilize skin lipids. In order to more closely describe the permeation data, significant increases in the stratum corneum/water partition coefficients, K{sub sc}, and modest changes to the diffusion coefficients, D{sub sc}, were required. The analysis provided strong evidence for both skin swelling and barrier disruption by VOCs, even by the minute amounts absorbed under these in vitro test conditions. - Highlights: • Human skin absorption of small doses of VOCs was measured in vitro in a fume hood. • The VOCs tested were ethanol, acetone, benzene and 1,2-dichloroethane. • Fraction of dose absorbed for all compounds at all doses tested was less than 0.3%. • The more aggressive VOCs absorbed at higher levels than diffusion model predictions. • We conclude that even small exposures to VOCs temporarily alter skin permeability.« less

Comparison of experimental and modeled absorption enhancement by black carbon (BC) cored polydisperse aerosols under hygroscopic conditions.

PubMed

Shamjad, P M; Tripathi, S N; Aggarwal, S G; Mishra, S K; Joshi, Manish; Khan, Arshad; Sapra, B K; Ram, Kirpa

2012-08-07

The quantification of the radiative impacts of light absorbing ambient black carbon (BC) particles strongly depends on accurate measurements of BC mass concentration and absorption coefficient (β(abs)). In this study, an experiment has been conducted to quantify the influence of hygroscopic growth of ambient particles on light absorption. Using the hygroscopic growth factor (i.e., Zdanovskii-Stokes-Robinson (ZSR) approach), a model has been developed to predict the chemical composition of particles based on measurements, and the absorption and scattering coefficients are derived using a core-shell assumption with light extinction estimates based on Mie theory. The estimated optical properties agree within 7% for absorption coefficient and 30% for scattering coefficient with that of measured values. The enhancement of absorption is found to vary according to the thickness of the shell and BC mass, with a maximum of 2.3 for a shell thickness of 18 nm for the particles. The findings of this study underline the importance of considering aerosol-mixing states while calculating their radiative forcing.

Estimation of the molar absorption coefficient of copper salicylate within the spectral range 300-350 nm

NASA Astrophysics Data System (ADS)

Lavrik, N. L.; Mulloev, N. U.

2017-12-01

Additional absorption was detected in absorption spectra within the range 300-350 nm after addition of copper sulfate CuSO4(aq) to a solution of sodium salicylate NaНSal (рН = 7.8). The additional maximum absorption was observed at 320 nm. Assuming that the additional absorption depends on the formation of copper salicylate CuSal, the molar absorption coefficient εCuSal of this complex was determined to be (3.8 ± 0.02) · 103 М- 1 сm- 1. This value is almost equal to that of monoanion HSal-, εHSal - = (3.6 ± 0.04) · 103 М- 1 сm- 1, and is 2.5 times as much as εFe3 + HSal - = (1.55 ± 0.05) · 103 М- 1 сm- 1 for iron salicylate. The difference in εCuSal and εFe3 + HSal - is due to the difference in the initial electron states of Cu2 + and Fe3 + ions that have the d9 and d5 configurations, respectively.

Electromagnetic Wave Absorption Property of Graphene with FeO4 Nanoparticles.

PubMed

Yang, Cheng; Dai, Shenglong; Zhang, Xiaoyan; Zhao, Tianyu; Yan, Shaojiu; Zhao, Xiuying

2016-02-01

Nanomaterials consisting of various ratios of Fe3O4 and graphene (defined C-Fe3O4/GR) were pre- pared by an in situ coordination complex hydro-thermal synthesis method. The structure and morphology of the nanomaterials C-Fe3O4/GR obtained were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and transmission electron microscopy (TEM). It was found that the Fe3O4 nanoparticles distributed on the surfaces of graphene, and had a spinel structure and a uniform chemical phase when the weight ratios of Fe3O4 to graphene oxide (GO) were 9:1 or 9:2. It was suggested that GO had been successfully reduced to graphene and the Fe3O4 nanoparticles were chemically bonded to graphene. The SQUID vibrating sample magnetometer (SQUID-VSM) indicated that the maximum of the saturation magnetization was 83.6 emmicro g(-1) when the mass ratio of Fe3O4 to GO was 9:2. Electromagnetic wave absorption showed that the chemical compound of Fe3O4 and graphene had a better electromagnetic property than the mechanical blend of Fe3O4 and graphene (M-Fe3O4/GR). The C-Fe3O4/GR had a reflection loss larger than -10 dB in the frequency range 12.9-17.0 GHz for an absorber thickness of 3 mm, and a maximum reflection loss of -12.3 dB at 14.8 GHz and a maximum reflection loss of -31.2 dB at 10.5 GHz for an absorber thickness of 10 mm. Theoretical analysis showed that the electromagnetic wave absorption behavior obeyed the quarter-wave principles. These results showed that the C-Fe3O4/GR nanomaterials can meet the requirements for some engineering applications, showing great application potential in electromagnetic wave absorption.

[Acoustic conditions in open plan offices - Pilot test results].

PubMed

Mikulski, Witold

The main source of noise in open plan office are conversations. Office work standards in such premises are attained by applying specific acoustic adaptation. This article presents the results of pilot tests and acoustic evaluation of open space rooms. Acoustic properties of 6 open plan office rooms were the subject of the tests. Evaluation parameters, measurement methods and criterial values were adopted according to the following standards: PN-EN ISO 3382- 3:2012, PN-EN ISO 3382-2:2010, PN-B-02151-4:2015-06 and PN-B-02151-3:2015-10. The reverberation time was 0.33- 0.55 s (maximum permissible value in offices - 0.6 s; the criterion was met), sound absorption coefficient in relation to 1 m2 of the room's plan was 0.77-1.58 m2 (minimum permissible value - 1.1 m2; 2 out of 6 rooms met the criterion), distraction distance was 8.5-14 m (maximum permissible value - 5 m; none of the rooms met the criterion), A-weighted sound pressure level of speech at a distance of 4 m was 43.8-54.7 dB (maximum permissible value - 48 dB; 2 out of 6 rooms met the criterion), spatial decay rate of the speech was 1.8-6.3 dB (minimum permissible value - 7 dB; none of the rooms met the criterion). Standard acoustic treatment, containing sound absorbing suspended ceiling, sound absorbing materials on the walls, carpet flooring and sound absorbing workplace barriers, is not sufficient. These rooms require specific advanced acoustic solutions. Med Pr 2016;67(5):653-662. This work is available in Open Access model and licensed under a CC BY-NC 3.0 PL license.

Optical absorption, TL and IRSL of basic plagioclase megacrysts from the pinacate (Sonora, Mexico) quaternary alkalic volcanics.

PubMed

Chernov, V; Paz-Moreno, F; Piters, T M; Barboza-Flores, M

2006-01-01

The paper presents the first results of an investigation on optical absorption (OA), thermally and infrared stimulated luminescence (TL and IRSL) of the Pinacate plagioclase (labradorite). The OA spectra reveal two bands with maxima at 1.0 and 3.2 eV connected with absorption of the Fe3+ and Fe2+ and IR absorption at wavelengths longer than 2700 nm. The ultraviolet absorption varies exponentially with the photon energy following the 'vitreous' empirical Urbach rule indicating exponential distribution of localised states in the forbidden band. The natural TL is peaked at 700 K. Laboratory beta irradiation creates a very broad TL peak with maximum at 430 K. The change of the 430 K TL peak shape under the thermal cleaning procedure and dark storage after irradiation reveals a monotonous increasing of the activation energy that can be explained by the exponential distribution of traps. The IRSL response is weak and exhibits a typical decay behaviour.

Co-sensitization of natural dyes for improved efficiency in dye-sensitized solar cell application

NASA Astrophysics Data System (ADS)

Kumar, K. Ashok; Subalakshmi, K.; Senthilselvan, J.

2016-05-01

In this paper, a new approach of co-sensitized DSSC based on natural dyes is investigated to explore the possible way to improve the power conversion efficiency. To realize this purpose 10 DSSC devices were fabricated using mono-sensitization and co-sensitization of ethanolic extracts of natural dye sensitizers obtained from Cactus fruit, Jambolana fruit, Curcumin and Bermuda grass. The optical absorption spectrum of the mono and hybrid dye extracts were studied by UV-Visible absorption spectrum. It shows the characteristic absorption peaks in visible region corresponds to the presence of natural pigments of anthocyanin, betacyanin and chlorophylls. Absorption spectrum of hybrid dyes reveals a wide absorption band in visible region with improved extinction co-efficient and it is favorable for increased light harvesting nature. The power conversion efficiency of DSSC devices were calculated using J-V curve and the maximum efficiency achieved in the present work is noted to be ~0.61% for Cactus-Bermuda co-sensitized DSSC.

ORIGINS OF ABSORPTION SYSTEMS OF CLASSICAL NOVA V2659 CYG (NOVA CYG 2014)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arai, A.; Kawakita, H.; Shinnaka, Y.

2016-10-10

We report on high-dispersion spectroscopy results of a classical nova V2659 Cyg (Nova Cyg 2014) that are taken 33.05 days after the V -band maximum. The spectrum shows two distinct blueshifted absorption systems originating from H i, Fe ii, Ca ii, etc. The radial velocities of the absorption systems are −620 km s{sup −1}, and −1100 to −1500 km s{sup −1}. The higher velocity component corresponds to the P-Cygni absorption features frequently observed in low-resolution spectra. Much larger numbers of absorption lines are identified at the lower velocity. These mainly originate from neutral or singly ionized Fe-peak elements (Fe i,more » Ti ii, Cr ii, etc.). Based on the results of our spectroscopic observations, we discuss the structure of the ejecta of V2659 Cyg. We conclude that the low- and high-velocity components are likely to be produced by the outflow wind and the ballistic nova ejecta, respectively.« less

Synthesis, photophysical, and electrochemical properties of wide band gap tetraphenylsilane-carbazole derivatives: Effect of the substitution position and naphthalene side chain

NASA Astrophysics Data System (ADS)

Ho, Kar Wei; Ariffin, A.

2016-12-01

Four tetraphenylsilane-carbazole derivatives with wide bandgaps (3.38-3.55 eV) were synthesized. The effects of the substitution position and of the presence of naphthalene groups on the photophysical, electrochemical and thermal properties were investigated. The derivatives exhibited maximum absorption peaks ranging from 293 to 304 nm and maximum emission peaks ranging from 347 to 386 nm. Changing the carbazole substitution position on the tetraphenylsilane did not significantly change the photophysical and electrochemical properties. However, p-substituted compounds exhibited higher glass transition temperatures than m-substituted compounds. Naphthalene groups with bulky structures had extended the conjugation lengths that red-shifted both the absorption and emission spectra. The LUMO level was decreased, which reduced the optical bandgap and triplet energy level. However, the naphthalene groups significantly improved the thermal stability by increasing the glass transition temperature of the compounds.

Nuclear magnetic resonance properties of lunar samples.

NASA Technical Reports Server (NTRS)

Kline, D.; Weeks, R. A.

1972-01-01

Nuclear magnetic resonance spectra of Na-23, Al-27, and P-31 in fines samples 10084,60 and 14163,168 and in crystalline rock samples 12021,55 and 14321,166, have been recorded over a range of frequencies up to 20 MHz. A shift in the field at which maximum absorption occurs for all of the spectra relative to the field at which maximum absorption occurs for terrestrial analogues is attributed to a sample-dependent magnetic field at the Na, Al, and P sites opposing the laboratory field. The magnitude of these fields internal to the samples is sample dependent and varies from 5 to 10 G. These fields do not correlate with the iron content of the samples. However, the presence of single-domain particles of iron distributed throughout the plagioclase fraction that contains the principal fraction of Na and Al is inferred from electron magnetic resonance spectra shapes.

Dynamic impact testing with servohydraulic testing machines

NASA Astrophysics Data System (ADS)

Bardenheier, R.; Rogers, G.

2006-08-01

The design concept of “Crashworthiness” requires the information on material behaviour under dynamic impact loading in order to describe and predict the crash behaviour of structures. Especially the transport related industries, like car, railway or aircraft industry, pursue the concept of lightweight design for a while now. The materials' maximum constraint during loading is pushed to permanently increasing figures. This means in terms of crashworthiness that the process of energy absorption in structures and the mechanical behaviour of materials must well understood and can be described appropriately by material models. In close cooperation with experts from various industries and research institutes Instron has developed throughout the past years a new family of servohydraulic testing machines specifically designed to cope with the dynamics of high rate testing. Main development steps are reflected versus their experimental necessities.

Experimental investigation of a metasurface resonator for in vivo imaging at 1.5 T

NASA Astrophysics Data System (ADS)

Shchelokova, Alena V.; Slobozhanyuk, Alexey P.; de Bruin, Paul; Zivkovic, Irena; Kallos, Efthymios; Belov, Pavel A.; Webb, Andrew

2018-01-01

In this work, we experimentally demonstrate an increase in the local transmit efficiency of a 1.5 T MRI scanner by using a metasurface formed by an array of brass wires embedded in a high permittivity low loss medium. Placement of such a structure inside the scanner results in strong coupling of the radiofrequency field produced by the body coil with the lowest frequency electromagnetic eigenmode of the metasurface. This leads to spatial redistribution of the near fields with enhancement of the local magnetic field and an increase in the transmit efficiency per square root maximum specific absorption rate in the region-of-interest. We have investigated this structure in vivo and achieved a factor of 3.3 enhancement in the local radiofrequency transmit efficiency.

Preliminary Thermal Characterization of a Fully-Passive Wireless Backscattering Neuro-Recording Microsystem

NASA Technical Reports Server (NTRS)

Schwerdt, H. N.; Xu, W.; Shekhar, S.; Chae, J.; Miranda, F. A.

2011-01-01

We present analytical and experimental thermal characteristics of a battery-less, fully-passive wireless backscattering microsystem for recording of neuropotentials. A major challenge for cortically implantable microsystems involves minimizing the heat dissipated by on-chip circuitry, which can lead to permanent brain damage. Therefore, knowledge of temperature changes induced by implantable microsystems while in operation is of utmost importance. In this work, a discrete diode appended to the neuro-recording microsystem has been used to indirectly monitor the aforesaid temperature changes. Using this technique, the maximum temperature rise measured for the microsystem while in operation was 0.15 +/- 0.1 C, which is significantly less than current safety guidelines. Specific absorption ratio (SAR) due to the microsystem was also computed to further demonstrate fully-passive functionality of the neuro-recording microsystem.

Particulate and dissolved spectral absorption on the continental shelf of the southeastern United States

NASA Astrophysics Data System (ADS)

Nelson, James R.; Guarda, Sonia

1995-05-01

Visible absorption spectra of particulate and dissolved materials were characterized on the continental shelf off the southeastern United States (the South Atlantic Bight), emphasizing cross-shelf and seasonal variability. A coastal front separates turbid coastal waters from clearer midshelf waters. Spatial and seasonal patterns were evident in absorption coefficients for phytoplankton, detritus, and colored dissolved organic matter (CDOM); spectral shape parameters for CDOM and detritus; and phytoplankton chlorophyll-specific absorption. The magnitude of CDOM absorption reflected seasonal differences in freshwater discharge and the salinity of the midshelf waters. In the spring of 1993 (high discharge), CDOM absorption at 443 nm was >10 times that of total particulate absorption between 12 and 50 km offshore (0.28-0.69 m-1 versus 0.027-0.062 m-1) and up to 10 times the CDOM absorption measured in the previous summer (low discharge). Phytoplankton chlorophyll-specific absorption in the blue increased with distance from shore (from <0.03 m2 mg-1 in inner shelf waters to ˜0.1 m2 mg-1 at the most seaward stations in summer) and, for similar chlorophyll concentrations, was higher in summer than in the winter-spring. These spatial and seasonal patterns in phytoplankton chlorophyll-specific absorption can be attributed to a shift in phytoplankton species composition (from predominantly diatoms inshore to a cyanobacteria-dominated assemblage midshelf in summer), pigment packaging, and higher carotenoid:chlorophyll with distance from shore.

Characterization of Yb{sup 3+}:Sr{sub 5{minus}x}Ba{sub x}(PO{sub 4}){sub 3}F crystals for diode pumped lasers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bayramian, A.J.; Marshall, C.D.; Schaffers, K.I.

Ytterbium-doped Sr{sub 5}(PO{sub 4}){sub 3}F (S-FAP) has been shown to be a useful material for diode pumping, since it displays high gain, low loss, and a long radiative lifetime. One of the issues with S-FAP is that it has a relatively narrow absorption bandwidth ({approximately}5 nm) at 900 nm, the diode-pumping wavelength, while the diode`s output bandwidth can be large ({approximately}10 nm). By changing the host slightly, the absorption feature can be broadened to better match the pump bandwidth. Four mixed crystal boules of Yb{sup 3+}:Sr{sub 5{minus}x}Ba{sub x}(PO{sub 4}){sub 3}F were grown by the Czochralski method with x = 0.25,more » 0.5, 1, and 2. The bandwidth of the 900-nm absorption feature was found to grow with increasing barium concentration from 4.7 nm to a maximum of 15.9 nm. Emission spectra showed a similar bandwidth increase with barium content from 4.9 nm to a maximum of 10 nm. Emission cross sections for these materials were deduced by the methods of reciprocity, the Einstein method, and small-signal gain. The absorption feature`s homogeneity was probed using a tunable pump source which qualitatively showed that the barium-broadened lines were at least partly inhomogeneous. Each of these materials lased with a variety of output couplers. This family of materials was found to provide suitable laser hosts where a broader absorption and/or emission bandwidth is desired.« less

Accelerated aging tests on ENEA-ASE solar coating for receiver tube suitable to operate up to 550 °C

NASA Astrophysics Data System (ADS)

Antonaia, A.; D'Angelo, A.; Esposito, S.; Addonizio, M. L.; Castaldo, A.; Ferrara, M.; Guglielmo, A.; Maccari, A.

2016-05-01

A patented solar coating for evacuated receiver, based on innovative graded WN-AlN cermet layer, has been optically designed and optimized to operate at high temperature with high performance and high thermal stability. This solar coating, being designed to operate in solar field with molten salt as heat transfer fluid, has to be thermally stable up to the maximum temperature of 550 °C. With the aim of determining degradation behaviour and lifetime prediction of the solar coating, we chose to monitor the variation of the solar absorptance αs after each thermal annealing cycle carried out at accelerated temperatures under vacuum. This prediction method was coupled with a preliminary Differential Thermal Analysis (DTA) in order to give evidence for any chemical-physical coating modification in the temperature range of interest before performing accelerated aging tests. In the accelerated aging tests we assumed that the temperature dependence of the degradation processes could be described by Arrhenius behaviour and we hypothesized that a linear correlation occurs between optical parameter variation rate (specifically, Δαs/Δt) and degradation process rate. Starting from Δαs/Δt values evaluated at 650 and 690 °C, Arrhenius plot gave an activation energy of 325 kJ mol-1 for the degradation phenomenon, where the prediction on the coating degradation gave a solar absorptance decrease of only 1.65 % after 25 years at 550 °C. This very low αs decrease gave evidence for an excellent stability of our solar coating, also when employed at the maximum temperature (550 °C) of a solar field operating with molten salt as heat transfer fluid.

Charge storage mechanisms of manganese oxide nanosheets and N-doped reduced graphene oxide aerogel for high-performance asymmetric supercapacitors

NASA Astrophysics Data System (ADS)

Iamprasertkun, Pawin; Krittayavathananon, Atiweena; Seubsai, Anusorn; Chanlek, Narong; Kidkhunthod, Pinit; Sangthong, Winyoo; Maensiri, Santi; Yimnirun, Rattikorn; Nilmoung, Sukanya; Pannopard, Panvika; Ittisanronnachai, Somlak; Kongpatpanich, Kanokwan; Limtrakul, Jumras; Sawangphruk, Montree

2016-11-01

Although manganese oxide- and graphene-based supercapacitors have been widely studied, their charge storage mechanisms are not yet fully investigated. In this work, we have studied the charge storage mechanisms of K-birnassite MnO2 nanosheets and N-doped reduced graphene oxide aerogel (N-rGOae) using an in situ X-ray absorption spectroscopy (XAS) and an electrochemical quart crystal microbalance (EQCM). The oxidation number of Mn at the MnO2 electrode is +3.01 at 0 V vs. SCE for the charging process and gets oxidized to +3.12 at +0.8 V vs. SCE and then reduced back to +3.01 at 0 V vs. SCE for the discharging process. The mass change of solvated ions, inserted to the layers of MnO2 during the charging process is 7.4 μg cm-2. Whilst, the mass change of the solvated ions at the N-rGOae electrode is 8.4 μg cm-2. An asymmetric supercapacitor of MnO2//N-rGOae (CR2016) provides a maximum specific capacitance of ca. 467 F g-1 at 1 A g-1, a maximum specific power of 39 kW kg-1 and a specific energy of 40 Wh kg-1 with a wide working potential of 1.6 V and 93.2% capacity retention after 7,500 cycles. The MnO2//N-rGOae supercapacitor may be practically used in high power and energy applications.

Charge storage mechanisms of manganese oxide nanosheets and N-doped reduced graphene oxide aerogel for high-performance asymmetric supercapacitors.

PubMed

Iamprasertkun, Pawin; Krittayavathananon, Atiweena; Seubsai, Anusorn; Chanlek, Narong; Kidkhunthod, Pinit; Sangthong, Winyoo; Maensiri, Santi; Yimnirun, Rattikorn; Nilmoung, Sukanya; Pannopard, Panvika; Ittisanronnachai, Somlak; Kongpatpanich, Kanokwan; Limtrakul, Jumras; Sawangphruk, Montree

2016-11-18

Although manganese oxide- and graphene-based supercapacitors have been widely studied, their charge storage mechanisms are not yet fully investigated. In this work, we have studied the charge storage mechanisms of K-birnassite MnO 2 nanosheets and N-doped reduced graphene oxide aerogel (N-rGO ae ) using an in situ X-ray absorption spectroscopy (XAS) and an electrochemical quart crystal microbalance (EQCM). The oxidation number of Mn at the MnO 2 electrode is +3.01 at 0 V vs. SCE for the charging process and gets oxidized to +3.12 at +0.8 V vs. SCE and then reduced back to +3.01 at 0 V vs. SCE for the discharging process. The mass change of solvated ions, inserted to the layers of MnO 2 during the charging process is 7.4 μg cm -2 . Whilst, the mass change of the solvated ions at the N-rGO ae electrode is 8.4 μg cm -2 . An asymmetric supercapacitor of MnO 2 //N-rGO ae (CR2016) provides a maximum specific capacitance of ca. 467 F g -1 at 1 A g -1 , a maximum specific power of 39 kW kg -1 and a specific energy of 40 Wh kg -1 with a wide working potential of 1.6 V and 93.2% capacity retention after 7,500 cycles. The MnO 2 //N-rGO ae supercapacitor may be practically used in high power and energy applications.

Charge storage mechanisms of manganese oxide nanosheets and N-doped reduced graphene oxide aerogel for high-performance asymmetric supercapacitors

PubMed Central

Iamprasertkun, Pawin; Krittayavathananon, Atiweena; Seubsai, Anusorn; Chanlek, Narong; Kidkhunthod, Pinit; Sangthong, Winyoo; Maensiri, Santi; Yimnirun, Rattikorn; Nilmoung, Sukanya; Pannopard, Panvika; Ittisanronnachai, Somlak; Kongpatpanich, Kanokwan; Limtrakul, Jumras; Sawangphruk, Montree

2016-01-01

Although manganese oxide- and graphene-based supercapacitors have been widely studied, their charge storage mechanisms are not yet fully investigated. In this work, we have studied the charge storage mechanisms of K-birnassite MnO2 nanosheets and N-doped reduced graphene oxide aerogel (N-rGOae) using an in situ X-ray absorption spectroscopy (XAS) and an electrochemical quart crystal microbalance (EQCM). The oxidation number of Mn at the MnO2 electrode is +3.01 at 0 V vs. SCE for the charging process and gets oxidized to +3.12 at +0.8 V vs. SCE and then reduced back to +3.01 at 0 V vs. SCE for the discharging process. The mass change of solvated ions, inserted to the layers of MnO2 during the charging process is 7.4 μg cm−2. Whilst, the mass change of the solvated ions at the N-rGOae electrode is 8.4 μg cm−2. An asymmetric supercapacitor of MnO2//N-rGOae (CR2016) provides a maximum specific capacitance of ca. 467 F g−1 at 1 A g−1, a maximum specific power of 39 kW kg−1 and a specific energy of 40 Wh kg−1 with a wide working potential of 1.6 V and 93.2% capacity retention after 7,500 cycles. The MnO2//N-rGOae supercapacitor may be practically used in high power and energy applications. PMID:27857225

In Vivo Absorption and Disposition of Cefadroxil after Escalating Oral Doses in Wild-Type and PepT1 Knockout Mice

PubMed Central

Posada, Maria M.; Smith, David E.

2013-01-01

Purpose To determine the effect of PepT1 on the absorption and disposition of cefadroxil, including the potential for saturable intestinal uptake, after escalating oral doses of drug. Methods The absorption and disposition kinetics of [3H]cefadroxil was determined in wild-type and PepT1 knockout mice after 44.5, 89.1, 178, and 356 nmol/g oral doses of drug. The pharmacokinetics of [3H]cefadroxil was also determined in both genotypes after 44.5 nmol/g intravenous bolus doses. Results PepT1 deletion reduced the area under the plasma concentration-time profile (AUC0-120) of cefadroxil by 10-fold, the maximum plasma concentration (Cmax) by 17.5-fold, and increased the time to reach a maximum plasma concentration (Tmax) by 3-fold. There was no evidence of nonlinear intestinal absorption since AUC0-120 and Cmax values changed in a dose-proportional manner. Moreover, the pharmacokinetics of cefadroxil was not different between genotypes after intravenous bolus doses, indicating that PepT1 did not affect drug disposition. Finally, no differences were observed in the peripheral tissue distribution of cefadroxil (i.e., outside gastrointestinal tract) once these tissues were corrected for differences in perfusing blood concentrations. Conclusions The findings demonstrate convincingly the critical role of intestinal PepT1 in both the rate and extent of oral administration for cefadroxil and potentially other aminocephalosporin drugs. PMID:23959853

On The Dynamics and Design of a Two-body Wave Energy Converter

NASA Astrophysics Data System (ADS)

Liang, Changwei; Zuo, Lei

2016-09-01

A two-body wave energy converter oscillating in heave is studied in this paper. The energy is extracted through the relative motion between the floating and submerged bodies. A linearized model in the frequency domain is adopted to study the dynamics of such a two-body system with consideration of both the viscous damping and the hydrodynamic damping. The closed form solution of the maximum absorption power and corresponding power take-off parameters are obtained. The suboptimal and optimal designs for a two-body system are proposed based on the closed form solution. The physical insight of the optimal design is to have one of the damped natural frequencies of the two body system the same as, or as close as possible to, the excitation frequency. A case study is conducted to investigate the influence of the submerged body on the absorption power of a two-body system subjected to suboptimal and optimal design under regular and irregular wave excitations. It is found that the absorption power of the two-body system can be significantly higher than that of the single body system with the same floating buoy in both regular and irregular waves. In regular waves, it is found that the mass of the submerged body should be designed with an optimal value in order to achieve the maximum absorption power for the given floating buoy. The viscous damping on the submerged body should be as small as possible for a given mass in both regular and irregular waves.

Theoretical study of the design dye-sensitivity for usage in the solar cell device

NASA Astrophysics Data System (ADS)

Alrikabi, Alaa

There are many applications in the polymer chemistry, pharmaceutical, agricultural and industrial fields of the thiadiazole molecule and their derivatives. Allowance of the energy gap of the polymer conjugated is an object of great interesting debit for the possible removal of a doping in the preparation of highly conductivity polymers. Thiadiazoles derivatives are structural foundation of the polymer materials. In this present work, the electronic properties of graphene nanoflakes (GNFs)-phenanthrene-1,3,4-thiadiazoles oligomers are studied and discussed. Where thiadiazoles is expanded from one to 9 unit's molecules at the structure. The energy gap, HOMO, LUMO distribution, total energy, Fermi level energy, work function, maximum wavelength absorption, vertical absorption energies, and oscillator strengths are calculated for each molecule. All calculations are carry out by usage density function theory (DFT) and depended time density function theory (TD-DFT) with the B3LYP/6-31G model in the Gaussian 09W software packages. Results show that increasing the number of monomeric units lead to great enhance in the electronic properties, which caused it decreased the band gap from 3.17 eV in the system with one unit of thiadiazole just to 1.35 eV in the system with 9 units of thiadiazole. This case is raised the value of maximum absorption wavelengths to >500 nm to give the better performance in optoelectronic and solar cell, as these structures have prime absorption bands within the solar spectrum.

SPIRE Data Evaluation and Nuclear IR Fluorescence Processes.

DTIC Science & Technology

1982-11-30

so that all isotopes can be dealt with in a single run rather than a number of separate runs. At lower altitudes the radiance calculation needs to be...approximation can be inferred from the work of Neuendorffer (1982) on developing an analytic expression for the absorption of a single non-overlapping line...personnel by using prominent atmospheric infrared features such as the OH maximum, the HNO3 maximum, the CO3 4.3 um knee, etc. The azimuth however

Carbon X-ray absorption in the local ISM: fingerprints in X-ray Novae spectra

NASA Astrophysics Data System (ADS)

Gatuzz, Efraín; Ness, J.-U.; Gorczyca, T. W.; Hasoglu, M. F.; Kallman, Timothy R.; García, Javier A.

2018-06-01

We present a study of the C K-edge using high-resolution LETGS Chandra spectra of four novae during their super-soft-source (SSS) phase. We identified absorption lines due to C II Kα, C III Kα and C III Kβ resonances. We used these astronomical observations to perform a benchmarking of the atomic data, which involves wavelength shifts of the resonances and photoionization cross-sections. We used improved atomic data to estimate the C II and C III column densities. The absence of physical shifts for the absorption lines, the consistence of the column densities between multiple observations and the high temperature required for the SSS nova atmosphere modeling support our conclusion about an ISM origin of the respective absorption lines. Assuming a collisional ionization equilibrium plasma the maximum temperature derived from the ratio of C II/C III column densities of the absorbers correspond to Tmax < 3.05 × 104 K.

Method for mapping a natural gas leak

DOEpatents

Reichardt, Thomas A [Livermore, CA; Luong, Amy Khai [Dublin, CA; Kulp, Thomas J [Livermore, CA; Devdas, Sanjay [Albany, CA

2009-02-03

A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formatted into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimposed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

Natural gas leak mapper

DOEpatents

Reichardt, Thomas A [Livermore, CA; Luong, Amy Khai [Dublin, CA; Kulp, Thomas J [Livermore, CA; Devdas, Sanjay [Albany, CA

2008-05-20

A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formated into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimosed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

Galactic Outflows and Their Correlation with Galaxy Properties at 0.8 < z < 1.6

NASA Astrophysics Data System (ADS)

Whiting, Lindsey M.

Out. ows have been shown to be ubiquitous in galaxies between z = 1 and z=2, and many models and observations have attempted to correlate the absorption line. properties of these out. ows with morphological characteristics of their host galaxies. In this study, we examined the spectra of 71 galaxies with redshifts 1< z<2, paying. particular attention to the FeII and MgII absorption lines. We plotted the equivalent. width, velocity, and maximum velocity of the absorption features against various. physical properties of the galaxies, obtained from catalogues created by Skelton et. al., (2014) and van der Wel et al., (2012). We conrmed the presence of out. ows in. our galaxy sample, and found a signicant trend between the equivalent width and. star formation rate - out. owing gas has stronger absorption lines in galaxies with. higher star formation rates.

Multioctave infrared supercontinuum generation in large-core As₂S₃ fibers.

PubMed

Théberge, Francis; Thiré, Nicolas; Daigle, Jean-François; Mathieu, Pierre; Schmidt, Bruno E; Messaddeq, Younès; Vallée, Réal; Légaré, François

2014-11-15

We report on infrared supercontinuum (SC) generation through laser filamentation and subsequent nonlinear propagation in a step-index As2S3 fiber. The 100 μm core and high-purity As2S3 fiber used exhibit zero-dispersion wavelength around 4.5 μm, a mid-infrared background loss of 0.2  dB/m, and a maximum loss of only 0.55  dB/m at the S-H absorption peak around 4.05 μm. When pumping with ultrashort laser pulses slightly above the S-H absorption band, broadband infrared supercontinua were generated with a 20 dB spectral flatness spanning from 1.5 up to 7 μm. The efficiency and spectral shape of the SC produced by ultrashort pulses in large-core As2S3 fiber are mainly determined by its dispersion, the S-H contaminant absorption, and the mid-infrared nonlinear absorption.

Effect of Sequential Exposition to Short- and Long-Wavelength Radiation on the Optical Absorption in the Bismuth Titanium Oxide Crystal Doped by Aluminum

NASA Astrophysics Data System (ADS)

Dyu, V. G.; Kisteneva, M. G.; Shandarov, S. M.; Khudyakova, E. S.; Smirnov, S. V.; Kargin, Yu. F.

Changes in the spectral dependences of the optical absorption induced in the bismuth titanium oxide crystal doped by aluminum as a result of sequential exposition to cw laser radiation first with the wavelength λi = 532 nm and then with the longer wavelength λn = 633, 655, 663, 780, 871, or 1064 nm are investigated. Our experiments show that after the short-wavelength exposition to radiation with λi = 532 nm, the optical absorption in the crystal increases, and in the range 470-1000 nm, yields the spectrum whose form is independent of the initial crystal state. The subsequent exposition to longer-wavelength radiation leads to enhanced transmittance of the crystal in the examined spectral range. A maximum decrease of the optical absorption in the crystal is observed upon exposure to radiation with the wavelength λn = 663 nm.

CW laser damage testing of RAR nano-textured fused silica and YAG

NASA Astrophysics Data System (ADS)

MacLeod, Bruce D.; Hobbs, Douglas S.; Manni, Anthony D.; Sabatino, Ernest; Bernot, David M.; DeFrances, Sage; Randi, Joseph A.; Thomas, Jeffrey

2017-11-01

A study of the continuous wave (CW) laser induced damage threshold (LiDT) of fused silica and yttrium aluminum garnet (YAG) optics was conducted to further illustrate the enhanced survivability within high power laser systems of an anti-reflection (AR) treatment consisting of randomly distributed surface relief nanostructures (RAR). A series of three CW LiDT tests using the 1070nm wavelength, 16 KW fiber laser test bed at Penn State Electro-Optic Center (PSEOC) were designed and completed, with improvements in the testing protocol, areal coverage, and maximum exposure intensities implemented between test cycles. Initial results for accumulated power, stationary site exposures of RAR nano-textured optics showed no damage and low surface temperatures similar to the control optics with no AR treatment. In contrast, optics with thin-film AR coatings showed high surface temperatures consistent with absorption by the film layers. Surface discriminating absorption measurements made using the Photothermal Common-path Interferometry (PCI) method, showed zero added surface absorption for the RAR nanotextured optics, and absorption levels in the 2-5 part per million range for thin-film AR coated optics. In addition, the surface absorption of thin-film AR coatings was also found to have localized absorption spikes that are likely pre-cursors for damage. Subsequent CW LiDT testing protocol included raster scanning an increased intensity focused beam over the test optic surface where it was found that thin-film AR coated optics damaged at intensities in the 2 to 5 MW/cm2 range with surface temperatures over 250C during the long-duration exposures. Significantly, none of the 10 RAR nano-textured fused silica optics tested could be damaged up to the maximum system intensity of 15.5 MW/cm2, and surface temperatures remained low. YAG optics tested during the final cycle exhibited a similar result with RAR nano-textured surfaces surviving intensities over 3 times higher than thin-film AR coated surfaces. This result was correlated with PCI measurements that also show zero-added surface absorption for the RAR nano-textured YAG optics.

High power, widely tunable, mode-hop free, continuous wave external cavity quantum cascade laser for multi-species trace gas detection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Centeno, R.; Marchenko, D.; Mandon, J.

We present a high power, widely tunable, continuous wave external cavity quantum cascade laser designed for infrared vibrational spectroscopy of molecules exhibiting broadband and single line absorption features. The laser source exhibits single mode operation with a tunability up to 303 cm{sup −1} (∼24% of the center wavelength) at 8 μm, with a maximum optical output power of 200 mW. In combination with off-axis integrated output spectroscopy, trace-gas detection of broadband absorption gases such as acetone was performed and a noise equivalent absorption sensitivity of 3.7 × 10{sup −8 }cm{sup −1 }Hz{sup −1/2} was obtained.

A quantum rings based on multiple quantum wells for 1.2-2.8 THz detection

NASA Astrophysics Data System (ADS)

Mobini, Alireza; Solaimani, M.

2018-07-01

In this paper optical properties of a new QR based on MQWs have been investigated for detection in the THz range. The QR composed of a periodic effective quantum sites that each one considered as QW in theta direction. Using Tight binding method, eigen value problem for a QR with circumstance of 100 nm number with different number of wells i.e. 2, 4, 6 and 8 are solved and the absorption spectrum have been calculated. The results show that absorption has maximum value in range of (1.2-2.88 THz) that can be used for THz detection. Finally, it is realized that by increasing the number of wells, the numbers of absorption line also increase.

On the bathochromic shift of the absorption by astaxanthin in crustacyanin: a quantum chemical study

NASA Astrophysics Data System (ADS)

Durbeej, Bo; Eriksson, Leif A.

2003-06-01

The structural origin of the bathochromic shift assumed by the electronic absorption spectrum of protein-bound astaxanthin, the carotenoid that upon binding to crustacyanin is responsible for the blue colouration of lobster shell, is investigated by means of quantum chemical methods. The calculations suggest that the bathochromic shift is largely due to one of the astaxanthin C4 keto groups being hydrogen-bonded to a histidine residue of the surrounding protein, and that the effect of this histidine is directly dependent on its protonation state. Out of the different methodologies (CIS, TD-DFT, and ZINDO/S) employed to calculate wavelengths of maximum absorption, the best agreement with experimental data is obtained using the semiempirical ZINDO/S method.

The examination of berberine excited state by laser flash photolysis

NASA Astrophysics Data System (ADS)

Cheng, Lingli; Wang, Mei; Zhao, Ping; Zhu, Hui; Zhu, Rongrong; Sun, Xiaoyu; Yao, Side; Wang, Shilong

2009-07-01

The property of the excited triplet state of berberine (BBR) was investigated by using time-resolved laser flash photolysis of 355 nm in acetonitrile. The transient absorption spectra of the excited triplet BBR were obtained in acetonitrile, which have an absorption maximum at 420 nm. And the ratio of excitation to ionization of BBR in acetonitrile solvent was calculated. The self-decay and self-quenching rate constants, and the absorption coefficient of 3BBR* were investigated and the excited state quantum yield was determined. Furthermore utilizing the benzophenone (BEN) as a triplet sensitizer, and the β-carotene (Car) as an excited energy transfer acceptor, the assignment of 3BBR* was further confirmed and the related energy transfer rate constants were also determined.

Intraband light absorption by holes in InGaAsP/InP quantum wells

NASA Astrophysics Data System (ADS)

Pavlov, N. V.; Zegrya, G. G.

2018-03-01

A microscopic analysis of the mechanism of intraband radiation absorption by holes with their transition to a spin-split band for quantum wells based on InGaAsP/InP solid solutions is performed within the framework of the four-band Kane model. The calculation is made for two polarizations of the incident radiation: along the crystal growth axis and in the plane of the quantum well. It is shown that this process can be the main mechanism of internal radiation losses for quantum well lasers. It is also shown that the dependence of the absorption coefficient on the width of the quantum well has a maximum at a well width from 40 to 60 A.

Psychological absorption. Affect investment in marijuana intoxication.

PubMed

Fabian, W D; Fishkin, S M

1991-01-01

Absorption (a trait capacity for total attentional involvement) was reported to increase during episodes of marijuana intoxication. Several subsets of the absorption scale items specifically characterized marijuana intoxication, and groups of users and nonusers showed differential affective involvement with these experiences. Additionally, within the drug-using group, a positive correlation between frequency of marijuana use and affective ratings of these experiences was found. The findings support the hypothesis that a specific type of alteration in consciousness that enhances capacity for total attentional involvement (absorption) characterizes marijuana intoxication, and that this enhancement may act as a reinforcer, possibly influencing future use.

49 CFR 178.516 - Standards for fiberboard boxes.

Code of Federal Regulations, 2010 CFR

2010-10-01

... minutes by the Cobb method of determining water absorption, is not greater than 155 g per square meter (0...) Maximum net mass: 400 kg (882 pounds). [Amdt. 178-97, 55 FR 52717, Dec. 21, 1990, and amended by Amdt. 178...

Study on the behavior and mechanism of polycarbonate with hot-water aging

NASA Astrophysics Data System (ADS)

Kong, L. P.; Zhao, Y. X.; Zhou, C. H.; Huang, Y. H.; Tang, M.; Gao, J. G.

2016-07-01

The present work was concerned with hot-water aging behavior and mechanism of Bisphenol A polycarbonate (PC) used as food and packaging materials. It indicated that with the aging time prolonged, PC sample had internal defects and the mechanical properties of PC materials changed not too much, molecular weight decreased, thermal stability declined. Phenolic hydroxyl absorption intensity enhanced in IR spectra and the maximum absorption wavelength red shift of benzene in UV-Vis spectra, the level of BPA increased. The color change of PC sample was not apparent.

Optically induced excitonic electroabsorption in a periodically delta-doped InGaAs/GaAs multiple quantum well structure

NASA Technical Reports Server (NTRS)

Larsson, A.; Maserjian, J.

1991-01-01

Large optically induced Stark shifts have been observed in a periodically delta-doped InGaAs/GaAs multiple quantum well structure. With an excitation intensity of 10 mW/sq cm, an absolute quantum well absorption change of 7000/cm was measured with a corresponding differential absorption change as high as 80 percent. The associated maximum change in the quantum well refractive index is 0.04. This material is promising for device development for all-optical computing and signal processing.

Enhancement radiative cooling performance of nanoparticle crystal via oxidation

NASA Astrophysics Data System (ADS)

Jia, Zi-Xun; Shuai, Yong; Li, Meng; Guo, Yanmin; Tan, He-ping

2018-03-01

Nanoparticle-crystal is a promising candidate for large scale metamaterial fabrication. However, in radiative cooling application, the maximum blackbody radiation wavelength locates far from metal's plasmon wavelength. In this paper, it will be shown if the metallic nanoparticle crystal can be properly oxidized, the absorption performance within room temperature blackbody radiation spectrum can be improved. Magnetic polariton and surface plasmon polariton have been explained for the mechanism of absorption improvement. Three different oxidation patterns have been investigated in this paper, and the results show they share a similar enhancing mechanism.

Limits to Maximum Absorption Length in Waveguide Photodiodes

DTIC Science & Technology

2011-04-13

InGaAsP to InGaAs graded layer (35 nm), a very thin undoped InGaAs absorber layer (20 nm), a p- InP cla~din~ layer (1 J.Lm, Zn = 1x1018 em·\\ a p- InP ...expected excess opticall_oss results from non-ideal coupling, excess waveguide scattering, Zn diffusion from the p-doped InP , larger than...waveguide scattering, Zn diffusion from the p-doped InP , n-doped region absorption, or a combination of the above. The SCOWPD has demonst:r:ated an

Absorption of CO2 from modified flue gases of power generation Tarahan chemically using NaOH and Na2CO3 and biologically using microalgae

NASA Astrophysics Data System (ADS)

Purba, Elida; Agustina, Dewi; Putri Pertama, Finka; Senja, Fita

2018-03-01

This research was carried out on the absorption of CO2 from the modified flue gases of power generation Tarahan using NaOH (sodium hydroxide) and Na2CO3 (sodium carbonate). The operation was conducted in a packed column absorber and then the output gases from the packed column was fed into photo-bioreactor for biological absorption. In the photo-bioreactor, two species of microalgae, N. occulata and T. chuii, were cultivated to both absorb CO2 gas and to produce biomass for algal oil. The aims of this research were, first, to determine the effect of absorbent flow rate on the reduction of CO2 and on the decrease of output gas temperature, second, to determine the characteristics of methyl ester obtained from biological absorption process. Flow rates of the absorbent were varied as 1, 2, and 3 l/min. The concentrations of NaOH and Na2CO3 were 1 M at a constant gas flow rate of 6 l/min. The output concentrations of CO2 from the absorber was analyzed using Gas Chromatography 2014-AT SHIMADZU Corp 08128. The results show that both of the absorbents give different trends. From the absorption using NaOH, it can be concluded that the higher the flow rate, the higher the absorption rate obtained. The highest flow rate achieved maximum absorption of 100%. On the other hand, absorption with Na2CO3 revealed the opposite trend where the higher the flow rates the lower the absorption rate. The highest absorption using Na2CO3 was obtained with the lowest flow rate, 1 l/min, that was 45,5%. As the effect of flow rate on output gas temperature, the temperature decreased with increasing flow rates for both absorbents. The output gas temperature for NaOH and Na2CO3 were consecutively 35 °C and 31 °C with inlet gas temperature of 50°C. Absorption of CO2 biologically resulted a reduction of CO2 up to 60% from the input gas concentration. Algal oil was extracted with mixed hexane and chloroform to obtain algal oil. Extracted oil was transesterified to methyl ester using sodium hydroxide as a catalyst. The results of in-situ transesterification method cannot be identified. Both microalgae achieved maximum yield at 2% catalyst concentration. Nannochloropsis occulata achieved the highest yield of algal oil that is 88.5%. The highest content of methyl ester from Nannochloropsis occulata was undecanoic acid methyl ester by 55.42% and the result from Tetraselmis chuii was palmitic acid methyl ester by 81.58%.

Optimization of the sources in local hyperthermia using a combined finite element-genetic algorithm method.

PubMed

Siauve, N; Nicolas, L; Vollaire, C; Marchal, C

2004-12-01

This article describes an optimization process specially designed for local and regional hyperthermia in order to achieve the desired specific absorption rate in the patient. It is based on a genetic algorithm coupled to a finite element formulation. The optimization method is applied to real human organs meshes assembled from computerized tomography scans. A 3D finite element formulation is used to calculate the electromagnetic field in the patient, achieved by radiofrequency or microwave sources. Space discretization is performed using incomplete first order edge elements. The sparse complex symmetric matrix equation is solved using a conjugate gradient solver with potential projection pre-conditionning. The formulation is validated by comparison of calculated specific absorption rate distributions in a phantom to temperature measurements. A genetic algorithm is used to optimize the specific absorption rate distribution to predict the phases and amplitudes of the sources leading to the best focalization. The objective function is defined as the specific absorption rate ratio in the tumour and healthy tissues. Several constraints, regarding the specific absorption rate in tumour and the total power in the patient, may be prescribed. Results obtained with two types of applicators (waveguides and annular phased array) are presented and show the faculties of the developed optimization process.

The Type Ia supernova 1989B in NGC 3627 (M66)

NASA Technical Reports Server (NTRS)

Wells, Lisa A.; Phillips, M. M.; Suntzeff, Nicholas B.; Heathcote, S. R.; Hamuy, Mario; Navarrete, M.; Fernandez, M.; Weller, W. G.; Schommer, R. A.; Kirshner, Robert P.

1994-01-01

We report extensive optical photometry and spectroscopy of the Type Ia supernova 1989B. Maximum light in B occurred approximately seven days after discovery on JD 2447565.3 +/- 1.0 (1989 February 7.8 +/- 1.0) at a magnitude of 12.34 +/- 0.05. The UBV light curves of this supernova were very similar to those of other well observed Type Ia events such as SN 1981B and SN 1980N. From a comparison of the UBVRIJHK photometry, we derive an extinction for SN 1989B of E(B-V) = 0.37 +/- 0.03 mags relative to the unobscured Type Ia SN 1980N. The properties of the dust responsible for the reddening of SN 1989B appear to have been similar to those of normal dust in the Milky Way. In particular, we find no evidence for an unusually low value of the ratio of the total to selective absorption. We derive a distance modulus of delta mu(sub 0) = -1.62 +/- 0.03 mag relative to the Type Ia SN 1980N. We present optical spectra which provide essentially continuous coverage of the spectral evolution of SN 1989B over the first month following B maximum. These data show the transition from the maximum-light spectrum, in which lines of elements such as Ca, Si, S, Mg, and O are most prominent, to the Fe-dominated spectrum observed a few weeks after maximum. This transition occurred quite smoothly over a two-week period following B maximum. Comparison of the spectra of SN 1989B with data for two other well observed Type Ia supernovae -- 1981B and 1986G -- reveals subtle differences in the relative strengths of the S II and Si II absorption lines at maximum light. However, these differences disappeared within a week or so after maximum with the onset of the Fe-dominated phase.

Absorption coefficients and frequency shifts measurement in the spectral range of 1071.88-1084.62 cm-1 vs. pressure for chlorodifluoromethane (CHClF2) using tunable CW CO2 laser

NASA Astrophysics Data System (ADS)

Al-Hawat, Sharif

2013-02-01

Infrared (IR) absorption in the spectral range of (1071.88-1084.62 cm-1) vs. pressure in chlorodifluoromethane (CFC-22, F-22, and CHClF2) was studied using a tunable continuous wave (CW) CO2 laser radiation on 9R branch lines with a maximum output power of about 2.12 W, provided with an absorber cell located outside the laser cavity. The absorption coefficients were determined vs. the gas pressure between 0.2 mbar and 170 mbar at lines from 9R branch for CFC-22. The frequency shifts of the absorption lines of CFC-22 in relative to the central frequencies of laser lines were calculated vs. the pressure on the basis of these absorption coefficients. The chosen lines were selected according to IR spectrum of the studied gas given by HITRAN cross section database. So the absorption was achieved for CFC-22 at the spectral lines of 9R branch situated from 9R (10) to 9R (30) emitted by a tunable CW CO2 laser. The absorption cross sections of CFC-22 determined in this work were compared with the relevant data given by HITRAN cross section database and a reasonable agreement was observed.

[Preparation and spectral analysis of a new type of blue light-emitting material delta-Alq3].

PubMed

Wang, Hua; Hao, Yu-ying; Gao, Zhi-xiang; Zhou, He-feng; Xu, Bing-she

2006-10-01

In the present article, delta-Alq3, a new type of blue light-emitting material, was synthesized and investigated by IR spectra, XRD spectra, UV-Vis absorption spectra, photoluminescence (PL) spectra, and electroluminescence (EL) spectra. The relationship between molecular spatial structure and spectral characteristics was studied by the spectral analysis of delta-Alq3 and alpha-Alq3. Results show that a new phase of Alq3 (delta-Alq3) can be obtained by vacuum heating alpha-Alq3, and the molecular spatial structure of alpha-Alq3 changes during the vacuum heating. The molecular spatial structure of delta-Alq3 lacks symmetry compared to alpha-Alq3. This transformation can reduce the electron cloud density on phenoxide of Alq3 and weaken the intermolecular conjugated interaction between adjacent Alq3 molecules. Hence, the pi--pi* electron transition absorption peak of delta-Alq3 shifts toward short wavelength in UV-Vis absorption spectra, and the maximum emission peak of delta-Alq3 (lamda max = 480 nm) blue-shifts by 35 nm compared with that of alpha-Alq3 (lamda max = 515 nm) in PL spectra. The maximum emission peaks of delta-Alq3 and alpha-Alq3 are all at 520 nm in EL spectra.

Synthesis of FeCo magnetic nanoalloys and investigation of heating properties for magnetic fluid hyperthermia

NASA Astrophysics Data System (ADS)

Çelik, Özer; Fırat, Tezer

2018-06-01

In this study, size controlled FeCo colloidal magnetic nanoalloys in the range of 11.5-37.2 nm were synthesized by surfactant assistant ball milling method. Magnetic separation technique was performed subsequent to synthesis process so as to obtain magnetic nanoalloy fluid with narrow size distribution. Particle distribution was determined by transmission electron microscope (TEM) while X-ray diffraction (XRD) measurements verified FeCo alloy formation as BCC structure. Vibrating sample magnetometer (VSM) method was used to investigate magnetic properties of nanoalloys. Maximum saturation magnetization and maximum coercivity were obtained as 172 Am2/kg for nanoparticles with the mean size of 37.2 nm and 19.4 mT for nanoparticles with the mean size of 13.3 nm, respectively. The heating ability of FeCo magnetic nanoalloys was determined through calorimetrical measurements for magnetic fluid hyperthermia (MFH) applications. Heat generation mechanisms were investigated by using linear response theory and Stoner-Wohlfarth (S-W) model. Specific absorption rate (SAR) values were obtained in the range of 2-15 W/g for magnetic field frequency of 171 kHz and magnetic field strength in between 6 and 14 mT.

Constant-dose microwave irradiation of insect pupae

NASA Astrophysics Data System (ADS)

Olsen, Richard G.

Pupae of the yellow mealworm Tenebrio molitor L. were subjected to microwave irradiation for 1.5-24 hours at power density levels adjusted to produce a total dosage of approximately 1123 J/g in each insect for every experiment. Insects without visible blemishes were exposed in a standing wave irradiation system such that half of them were exposed in the plane of maximum electric field (E field) and the other half were exposed in the plane of maximum magnetic field (H field). Both E field and H field insects exhibited nearly the same specific absorption rate (SAR) for pupal orientation parallel to the magnetic field vector at 5.95 GHz. Irradiations were conducted both with and without the use of a ventilating fan to control the temperature rise in the irradiation chamber. Abnormal development as a result of the microwave exposure was seen only in the high-power, short-duration experiment without chamber ventilation. This result suggests a thermal interaction mechanism for explanation of observed microwave-induced abnormalities. A study of the time course of the average temperature rise in the irradiated insects indicates that teratological effects for this configuration have a temperature threshold of approximately 40°C.

Five-Photon Absorption and Selective Enhancement of Multiphoton Absorption Processes

PubMed Central

2015-01-01

We study one-, two-, three-, four-, and five-photon absorption of three centrosymmetric molecules using density functional theory. These calculations are the first ab initio calculations of five-photon absorption. Even- and odd-order absorption processes show different trends in the absorption cross sections. The behavior of all even- and odd-photon absorption properties shows a semiquantitative similarity, which can be explained using few-state models. This analysis shows that odd-photon absorption processes are largely determined by the one-photon absorption strength, whereas all even-photon absorption strengths are largely dominated by the two-photon absorption strength, in both cases modulated by powers of the polarizability of the final excited state. We demonstrate how to selectively enhance a specific multiphoton absorption process. PMID:26120588

Five-Photon Absorption and Selective Enhancement of Multiphoton Absorption Processes.

PubMed

Friese, Daniel H; Bast, Radovan; Ruud, Kenneth

2015-05-20

We study one-, two-, three-, four-, and five-photon absorption of three centrosymmetric molecules using density functional theory. These calculations are the first ab initio calculations of five-photon absorption. Even- and odd-order absorption processes show different trends in the absorption cross sections. The behavior of all even- and odd-photon absorption properties shows a semiquantitative similarity, which can be explained using few-state models. This analysis shows that odd-photon absorption processes are largely determined by the one-photon absorption strength, whereas all even-photon absorption strengths are largely dominated by the two-photon absorption strength, in both cases modulated by powers of the polarizability of the final excited state. We demonstrate how to selectively enhance a specific multiphoton absorption process.

Comparison of different Aethalometer correction schemes and a reference multi-wavelength absorption technique for ambient aerosol data

NASA Astrophysics Data System (ADS)

Saturno, Jorge; Pöhlker, Christopher; Massabò, Dario; Brito, Joel; Carbone, Samara; Cheng, Yafang; Chi, Xuguang; Ditas, Florian; Hrabě de Angelis, Isabella; Morán-Zuloaga, Daniel; Pöhlker, Mira L.; Rizzo, Luciana V.; Walter, David; Wang, Qiaoqiao; Artaxo, Paulo; Prati, Paolo; Andreae, Meinrat O.

2017-08-01

Deriving absorption coefficients from Aethalometer attenuation data requires different corrections to compensate for artifacts related to filter-loading effects, scattering by filter fibers, and scattering by aerosol particles. In this study, two different correction schemes were applied to seven-wavelength Aethalometer data, using multi-angle absorption photometer (MAAP) data as a reference absorption measurement at 637 nm. The compensation algorithms were compared to five-wavelength offline absorption measurements obtained with a multi-wavelength absorbance analyzer (MWAA), which serves as a multiple-wavelength reference measurement. The online measurements took place in the Amazon rainforest, from the wet-to-dry transition season to the dry season (June-September 2014). The mean absorption coefficient (at 637 nm) during this period was 1.8 ± 2.1 Mm-1, with a maximum of 15.9 Mm-1. Under these conditions, the filter-loading compensation was negligible. One of the correction schemes was found to artificially increase the short-wavelength absorption coefficients. It was found that accounting for the aerosol optical properties in the scattering compensation significantly affects the absorption Ångström exponent (åABS) retrievals. Proper Aethalometer data compensation schemes are crucial to retrieve the correct åABS, which is commonly implemented in brown carbon contribution calculations. Additionally, we found that the wavelength dependence of uncompensated Aethalometer attenuation data significantly correlates with the åABS retrieved from offline MWAA measurements.

Solar cells based on particulate structure of active layer: Investigation of light absorption by an ordered system of spherical submicron silicon particles

NASA Astrophysics Data System (ADS)

Miskevich, Alexander A.; Loiko, Valery A.

2015-12-01

Enhancement of the performance of photovoltaic cells through increasing light absorption due to optimization of an active layer is considered. The optimization consists in creation of particulate structure of active layer. The ordered monolayers and multilayers of submicron crystalline silicon (c-Si) spherical particles are examined. The quasicrystalline approximation (QCA) and the transfer matrix method (TMM) are used to calculate light absorption in the wavelength range from 0.28 μm to 1.12 μm. The integrated over the terrestial solar spectral irradiance "Global tilt" ASTM G173-03 absorption coefficient is calculated. In the wavelength range of small absorption index of c-Si (0.8-1.12 μm) the integral absorption coefficient of monolayer can be more than 20 times higher than the one of the plane-parallel plate of the equivalent volume of material. In the overall considered range (0.28-1.12 μm) the enhancement factor up to ~1.45 for individual monolayer is observed. Maximum value of the spectral absorption coefficient approaches unity for multilayers consisting of large amount of sparse monolayers of small particles. Multilayers with variable concentration and size of particles in the monolayer sequences are considered. Absorption increasing by such gradient multilayers as compared to the non-gradient ones is illustrated. The considered structures are promising for creation of high efficiency thin-film solar cells.

Gender differences in lower extremity kinematics, kinetics and energy absorption during landing.

PubMed

Decker, Michael J; Torry, Michael R; Wyland, Douglas J; Sterett, William I; Richard Steadman, J

2003-08-01

To determine whether gender differences exist in lower extremity joint motions and energy absorption landing strategies between age and skill matched recreational athletes. Mixed factor, repeated measures design. Compared to males, females execute high demand activities in a more erect posture potentially predisposing the anterior cruciate ligament to greater loads and injury. The preferred energy absorption strategy may provide insight for this performance difference. Inverse dynamic solutions estimated lower extremity joint kinematics, kinetics and energetic profiles for twelve males and nine females performing a 60 cm drop landing. Females demonstrated a more erect landing posture and utilized greater hip and ankle joint range of motions and maximum joint angular velocities compared to males. Females also exhibited greater energy absorption and peak powers from the knee extensors and ankle plantar-flexors compared to the males. Examinations of the energy absorption contributions revealed that the knee was the primary shock absorber for both genders, whereas the ankle plantar-flexors muscles was the second largest contributor to energy absorption for the females and the hip extensors muscles for the males. Females may choose to land in a more erect posture to maximize the energy absorption from the joints most proximal to ground contact. Females may be at a greater risk to anterior cruciate ligament injury during landing due to their energy absorption strategy.

Parents: Avoid Kids Foot Problems with the Right Shoes

MedlinePlus

... pain, Achilles tendonitis and even ankle sprains and stress fractures. Children with Flat Feet Children with flat feet need shoes with a wide toe box, maximum arch support and shock absorption. The best shoes to buy are oxford, lace-up shoes ...

Heterogeneous and Evolving Distributions of Pluto's Volatile Surface Ices

NASA Astrophysics Data System (ADS)

Grundy, William M.; Olkin, C. B.; Young, L. A.; Buie, M. W.; Young, E. F.

2013-10-01

We report observations of Pluto's 0.8 to 2.4 µm reflectance spectrum with IRTF/SpeX on 70 nights over the 13 years from 2001 to 2013. The spectra show numerous vibrational absorption features of simple molecules CH4, CO, and N2 condensed as ices on Pluto's surface. These absorptions are modulated by the planet's 6.39 day rotation period, enabling us to constrain the longitudinal distributions of the three ices. Absorptions of CO and N2 are concentrated on Pluto's anti-Charon hemisphere, unlike absorptions of less volatile CH4 ice that are offset by roughly 90° from the longitude of maximum CO and N2 absorption. In addition to the diurnal/longitudinal variations, the spectra show longer term trends. On decadal timescales, Pluto's stronger CH4 absorption bands have deepened, while the amplitude of their diurnal variation has diminished, consistent with additional CH4 absorption by high northern latitude regions rotating into view as the sub-Earth latitude moves north (as defined by the system's angular momentum vector). Unlike the CH4 absorptions, Pluto's CO and N2 absorptions are declining over time, suggesting more equatorial or southerly distributions of those species. The authors gratefully thank the staff of IRTF for their tremendous assistance over the dozen+ years of this project. The work was funded in part by NSF grants AST-0407214 and AST-0085614 and NASA grants NAG5-4210 and NAG5-12516.

Nonlinear intestinal absorption kinetics of cefuroxime axetil in rats.

PubMed Central

Ruiz-Balaguer, N; Nacher, A; Casabo, V G; Merino, M

1997-01-01

Cefuroxime is commercially available for parenteral administration as a sodium salt and for oral administration as cefuroxime axetil, the 1-(acetoxy)ethyl ester of the drug. Cefuroxime axetil is a prodrug of cefuroxime and has little, if any, antibacterial activity until hydrolyzed in vivo to cefuroxime. In this study, the absorption of cefuroxime axetil in the small intestines of anesthetized rats was investigated in situ, by perfusion at four concentrations (11.8, 5, 118 and 200 microM). Oral absorption of cefuroxime axetil can apparently be described as a specialized transport mechanism which obeys Michaelis-Menten kinetics. Parameters characterizing absorption of prodrug in free solution were obtained: maximum rate of absorption (Vmax) = 289.08 +/- 46.26 microM h-1, and Km = 162.77 +/- 31.17 microM. Cefuroxime axetil transport was significantly reduced in the presence of the enzymatic inhibitor sodium azide. On the other hand, the prodrug was metabolized in the gut wall through contact with membrane-bound enzymes in the brush border membrane before absorption occurred. This process reduces the prodrug fraction directly available for absorption. From a bioavailability point of view, therefore, the effects mentioned above can explain the variable and poor bioavailability following oral administration of cefuroxime axetil. Thus, future strategies in oral cefuroxime axetil absorption should focus on increasing the stability of the prodrug in the intestine by modifying the prodrug structure and/or targeting the compound to the absorption site. PMID:9021205

Experimental investigation of a metasurface resonator for in vivo imaging at 1.5 T.

PubMed

Shchelokova, Alena V; Slobozhanyuk, Alexey P; de Bruin, Paul; Zivkovic, Irena; Kallos, Efthymios; Belov, Pavel A; Webb, Andrew

2018-01-01

In this work, we experimentally demonstrate an increase in the local transmit efficiency of a 1.5 T MRI scanner by using a metasurface formed by an array of brass wires embedded in a high permittivity low loss medium. Placement of such a structure inside the scanner results in strong coupling of the radiofrequency field produced by the body coil with the lowest frequency electromagnetic eigenmode of the metasurface. This leads to spatial redistribution of the near fields with enhancement of the local magnetic field and an increase in the transmit efficiency per square root maximum specific absorption rate in the region-of-interest. We have investigated this structure in vivo and achieved a factor of 3.3 enhancement in the local radiofrequency transmit efficiency. Copyright © 2017 Elsevier Inc. All rights reserved.

Time-dependent efficiency measurements of polymer solar cells with dye additives: unexpected initial increase of efficiency

NASA Astrophysics Data System (ADS)

Bandaccari, Kyle J.; Chesmore, Grace E.; Bugaj, Mitchel; Valverde, Parisa Tajalli-Tehrani; Barber, Richard P.; McNelis, Brian J.

2018-04-01

We report the effects of the addition of two azo-dye additives on the time-dependent efficiency of polymer solar cells. Although the maximum efficiencies of devices containing different amounts of dye do not vary greatly over the selected concentration range, the time dependence results reveal a surprising initial increase in efficiency in some samples. We observe this effect to be correlated with a leakage current, although a specific mechanism is not yet identified. We also present the measured lifetimes of these solar cells, and find that variations in dye concentrations produce a small effect at most. Characterization of the bulk heterojunction layer (active layer) morphology using atomic-force microscope (AFM) imaging reveals reordering patterns which suggest that the primary effects of the dyes arise via structural, not absorptive, characteristics.

Assessing the MR compatibility of dental retainer wires at 7 Tesla.

PubMed

Wezel, Joep; Kooij, Bert Jan; Webb, Andrew G

2014-10-01

To determine the MR compatibility of common dental retainer wires at 7 Tesla in terms of potential RF heating and magnetic susceptibility effects. Electromagnetic simulations and experimental results were compared for dental retainer wires placed in tissue-mimicking phantoms. Simulations were then performed for a human model with wire in place. Finally, image quality was assessed for different scanning protocols and wires. Simulations and experimental data in phantoms agreed well, with the length of the wire correlating to maximum heating in phantoms being approximately 47 mm. Even in this case, no substantial heating occurs when scanning within the specific absorption rate (SAR) guidelines for the head. Image distortions from the most ferromagnetic dental wire were not significant for any brain region. Dental retainer wires appear to be MR compatible at 7 Tesla. Copyright © 2013 Wiley Periodicals, Inc.

Multijunction solar cell design revisited: disruption of current matching by atmospheric absorption bands: Disruption of current matching by atmospheric absorption bands

DOE PAGES

McMahon, William E.; Friedman, Daniel J.; Geisz, John F.

2017-05-23

This paper re-examines the impact of atmospheric absorption bands on series-connected multijunction cell design, motivated by the numerous local efficiency maxima that appear as the number of junctions is increased. Some of the local maxima are related to the bottom subcell bandgap and are already well understood: As the bottom subcell bandgap is varied, a local efficiency maximum is produced wherever the bottom cell bandgap crosses an atmospheric absorption band. The optimal cell designs at these local maxima are generally current matched, such that all subcells have nearly the same short-circuit current. We systematically describe additional local maxima that occurmore » wherever an upper subcell bandgap encounters an atmospheric absorption band. Moreover, these local maxima are not current matched and become more prevalent as the number of junctions increases, complicating the solution space for five-junction and six-junction designs. A systematic framework for describing this complexity is developed, and implications for numerical convergence are discussed.« less

Doppler-free satellites of resonances of electromagnetically induced transparency and absorption on the D 2 lines of alkali metals

NASA Astrophysics Data System (ADS)

Sargsyan, A.; Sarkisyan, D.; Staedter, D.; Akulshin, A. M.

2006-11-01

The peculiarities of intra-Doppler structures that are observed in the atomic absorption spectrum of alkali metals with the help of two independent lasers have been studied. These structures accompany ultranarrow coherent resonances of electromagnetically induced transparency and absorption. With the D 2 line of rubidium taken as an example, it is shown that, in the scheme of unidirectional waves, the maximum number of satellite resonances caused by optical pumping selective with respect to the atomic velocity is equal to seven, while only six resonances are observed in the traditional scheme of saturated absorption with counterpropagating waves of the same frequency. The spectral position of the resonances and their polarity depend on the frequency of the saturating radiation, while their number and relative amplitude depend also on the experimental geometry. These features are of general character and should show themselves in the absorption spectrum on the D 2 lines of all alkali metals. An explanation of these features is given. The calculated spectral separations between the resonances are compared to the experimental ones, and their possible application is discussed.

Influence of the helium-pressure on diode-pumped alkali-vapor laser

NASA Astrophysics Data System (ADS)

Gao, Fei; Chen, Fei; Xie, Ji-jiang; Zhang, Lai-ming; Li, Dian-jun; Yang, Gui-long; Guo, Jing

2013-05-01

Diode-pumped alkali-vapor laser (DPAL) is a kind of laser attracted much attention for its merits, such as high quantum efficiency, excellent beam quality, favorable thermal management, and potential scalability to high power and so on. Based on the rate-equation theory of end-pumped DPAL, the performances of DPAL using Cs-vapor collisionally broadened by helium are simulated and studied. With the increase of helium pressure, the numerical results show that: 1) the absorption line-width increases and the stimulated absorption cross-section decreases contrarily; 2) the threshold pumping power decreases to minimum and then rolls over to increase linearly; 3) the absorption efficiency rises to maximum initially due to enough large stimulated absorption cross-section in the far wings of collisionally broadened D2 transition (absorption transition), and then begins to reduce; 4) an optimal value of helium pressure exists to obtain the highest output power, leading to an optimal optical-optical efficiency. Furthermore, to generate the self-oscillation of laser, a critical value of helium pressure occurs when small-signal gain equals to the threshold gain.

Integrated three-dimensional photonic nanostructures for achieving near-unity solar absorption and superhydrophobicity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuang, Ping; Lin, Shawn-Yu, E-mail: sylin@rpi.edu; Hsieh, Mei-Li

2015-06-07

In this paper, we proposed and realized 3D photonic nanostructures consisting of ultra-thin graded index antireflective coatings (ARCs) and woodpile photonic crystals. The use of the integrated ARC and photonic crystal structure can achieve broadband, broad-angle near unity solar absorption. The amorphous silicon based photonic nanostructure experimentally shows an average absorption of ∼95% for λ = 400–620 nm over a wide angular acceptance of θ = 0°–60°. Theoretical studies show that a Gallium Arsenide (GaAs) based structure can achieve an average absorption of >95% for λ = 400–870 nm. Furthermore, the use of the slanted SiO{sub 2} nanorod ARC surface layer by glancing angle deposition exhibits Cassie-Baxter statemore » wetting, and superhydrophobic surface is obtained with highest water contact angle θ{sub CB} ∼ 153°. These properties are fundamentally important for achieving maximum solar absorption and surface self-cleaning in thin film solar cell applications.« less

Qualitative analysis of Pb liquid sample using laser-induced breakdown spectroscopy (LIBS)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Suyanto, Hery; Rupiasih, Ni Nyoman; Winardi, T. B.

2013-09-03

Qualitative analysis of liquid sample containing 1,000 ppm of Pb was performed by using LIBS technique. In order to avoid splashing off of the liquid sample during laser irradiation, a sample pretreatment was done, namely the liquid sample was absorbed by using commercial available stomach medicine. Two kinds of absorbent materials were chosen in this experiment, first containing 125 mg activated carbon and second 600 mg activated attapulgite. These absorbent materials were used since carbon sample gives better absorption of infrared laser irradiation used in this experiment. In order to characterize the absorption process, three treatments were conducted in thismore » experiment; first, without heating the sample but varying the absorption time before laser irradiation; second by varying the heating temperature after certain time of absorption process and third by varying the temperature only. The maximum emission intensity of Pb I 405.7 nm was found in the second treatment of heating the sample till 85°C after 30 minutes absorption of the liquid sample in both absorbent materials.« less

Multijunction solar cell design revisited: disruption of current matching by atmospheric absorption bands: Disruption of current matching by atmospheric absorption bands

DOE Office of Scientific and Technical Information (OSTI.GOV)

McMahon, William E.; Friedman, Daniel J.; Geisz, John F.

This paper re-examines the impact of atmospheric absorption bands on series-connected multijunction cell design, motivated by the numerous local efficiency maxima that appear as the number of junctions is increased. Some of the local maxima are related to the bottom subcell bandgap and are already well understood: As the bottom subcell bandgap is varied, a local efficiency maximum is produced wherever the bottom cell bandgap crosses an atmospheric absorption band. The optimal cell designs at these local maxima are generally current matched, such that all subcells have nearly the same short-circuit current. We systematically describe additional local maxima that occurmore » wherever an upper subcell bandgap encounters an atmospheric absorption band. Moreover, these local maxima are not current matched and become more prevalent as the number of junctions increases, complicating the solution space for five-junction and six-junction designs. A systematic framework for describing this complexity is developed, and implications for numerical convergence are discussed.« less

Parallel transmission RF pulse design with strict temperature constraints.

PubMed

Deniz, Cem M; Carluccio, Giuseppe; Collins, Christopher

2017-05-01

RF safety in parallel transmission (pTx) is generally ensured by imposing specific absorption rate (SAR) limits during pTx RF pulse design. There is increasing interest in using temperature to ensure safety in MRI. In this work, we present a local temperature correlation matrix formalism and apply it to impose strict constraints on maximum absolute temperature in pTx RF pulse design for head and hip regions. Electromagnetic field simulations were performed on the head and hip of virtual body models. Temperature correlation matrices were calculated for four different exposure durations ranging between 6 and 24 min using simulated fields and body-specific constants. Parallel transmission RF pulses were designed using either SAR or temperature constraints, and compared with each other and unconstrained RF pulse design in terms of excitation fidelity and safety. The use of temperature correlation matrices resulted in better excitation fidelity compared with the use of SAR in parallel transmission RF pulse design (for the 6 min exposure period, 8.8% versus 21.0% for the head and 28.0% versus 32.2% for the hip region). As RF exposure duration increases (from 6 min to 24 min), the benefit of using temperature correlation matrices on RF pulse design diminishes. However, the safety of the subject is always guaranteed (the maximum temperature was equal to 39°C). This trend was observed in both head and hip regions, where the perfusion rates are very different. Copyright © 2017 John Wiley & Sons, Ltd.

Studies on the absorption and disposition of meptazinol following rectal administration.

PubMed Central

Franklin, R A; Southgate, P J; Coleman, A J

1977-01-01

1 Rectal administration of the new analgesic drug, meptazinol, resulted in rapid absorption of the compound both in the monkey and in man. Peak plasma levels were observed within 0.5 h of dosing. 2 Absorption of the drug following rectal administration was extensive as shown by the recovery of 65-90% of the dose in the urine. 3 Despite substantial inter-individual variation in the observed maximum plasma concentrations of the drug, it was still evident that concentrations after rectal dosage were considerably higher than when the same dosage was given orally. 4 Elimination of the drug from plasma took place rapidly in an apparently mono-exponential manner in both species. The half-life of elimination in monkeys was 1.25 h and in man 2.0 h. PMID:405029

21-cm radiation: a new probe of variation in the fine-structure constant.

PubMed

Khatri, Rishi; Wandelt, Benjamin D

2007-03-16

We investigate the effect of variation in the value of the fine-structure constant (alpha) at high redshifts (recombination > z > 30) on the absorption of the cosmic microwave background (CMB) at 21 cm hyperfine transition of the neutral atomic hydrogen. We find that the 21 cm signal is very sensitive to the variations in alpha and it is so far the only probe of the fine-structure constant in this redshift range. A change in the value of alpha by 1% changes the mean brightness temperature decrement of the CMB due to 21 cm absorption by >5% over the redshift range z < 50. There is an effect of similar magnitude on the amplitude of the fluctuations in the brightness temperature. The redshift of maximum absorption also changes by approximately 5%.

Dynamic Response and Optimal Design of Curved Metallic Sandwich Panels under Blast Loading

PubMed Central

Yang, Shu; Han, Shou-Hong; Lu, Zhen-Hua

2014-01-01

It is important to understand the effect of curvature on the blast response of curved structures so as to seek the optimal configurations of such structures with improved blast resistance. In this study, the dynamic response and protective performance of a type of curved metallic sandwich panel subjected to air blast loading were examined using LS-DYNA. The numerical methods were validated using experimental data in the literature. The curved panel consisted of an aluminum alloy outer face and a rolled homogeneous armour (RHA) steel inner face in addition to a closed-cell aluminum foam core. The results showed that the configuration of a “soft” outer face and a “hard” inner face worked well for the curved sandwich panel against air blast loading in terms of maximum deflection (MaxD) and energy absorption. The panel curvature was found to have a monotonic effect on the specific energy absorption (SEA) and a nonmonotonic effect on the MaxD of the panel. Based on artificial neural network (ANN) metamodels, multiobjective optimization designs of the panel were carried out. The optimization results revealed the trade-off relationships between the blast-resistant and the lightweight objectives and showed the great use of Pareto front in such design circumstances. PMID:25126606

Dynamic response and optimal design of curved metallic sandwich panels under blast loading.

PubMed

Qi, Chang; Yang, Shu; Yang, Li-Jun; Han, Shou-Hong; Lu, Zhen-Hua

2014-01-01

It is important to understand the effect of curvature on the blast response of curved structures so as to seek the optimal configurations of such structures with improved blast resistance. In this study, the dynamic response and protective performance of a type of curved metallic sandwich panel subjected to air blast loading were examined using LS-DYNA. The numerical methods were validated using experimental data in the literature. The curved panel consisted of an aluminum alloy outer face and a rolled homogeneous armour (RHA) steel inner face in addition to a closed-cell aluminum foam core. The results showed that the configuration of a "soft" outer face and a "hard" inner face worked well for the curved sandwich panel against air blast loading in terms of maximum deflection (MaxD) and energy absorption. The panel curvature was found to have a monotonic effect on the specific energy absorption (SEA) and a nonmonotonic effect on the MaxD of the panel. Based on artificial neural network (ANN) metamodels, multiobjective optimization designs of the panel were carried out. The optimization results revealed the trade-off relationships between the blast-resistant and the lightweight objectives and showed the great use of Pareto front in such design circumstances.

Specific absorption rate and electric field measurements in the near field of six mobile phone base station antennas.

PubMed

Toivonen, Tommi; Toivo, Tim; Puranen, Lauri; Jokela, Kari

2009-05-01

In this article, the exposure to radio frequency electromagnetic fields was studied in close proximity (distances of 10, 100, 300, and 600 mm) to six base station antennas. The specific absorption rate (SAR) in 800 mm x 500 mm x 200 mm box phantom as well as unperturbed electric field (E) in air was measured. The results were used to determine whether the measurement of local maximum of unperturbed electric field can be used as a compliance check for local exposure. Also, the conservativeness of this assessment method compared to the ICNIRP basic restriction was studied. Moreover, the assessment of whole-body exposure was discussed and the distance ranges presented in which the ICNIRP limit for local exposure could be exceeded before the limit for whole-body SAR. These results show that the electric field measurement alone can be used for easy compliance check for the local exposure at all distances and for all antenna types studied. However, in some cases when the local peak value of E was compared directly to the ICNIRP reference level for unperturbed E, the exposure was overestimated only very slightly (by factor 1.1) compared to the basic restriction for localized SAR in a human, and hence these results can not be generalized to all antenna types. Moreover, it was shown that the limit for localized exposure could be exceeded before the limit for the whole-body average SAR, if the distance to the antenna was less than 240 mm. Copyright 2009 Wiley-Liss, Inc.

Phthalocyanine Blends Improve Bulk Heterojunction Solar Cells

PubMed Central

Varotto, Alessandro; Nam, Chang-Yong; Radivojevic, Ivana; Tomé, Joao; Cavaleiro, José A.S.; Black, Charles T.; Drain, Charles Michael

2010-01-01

A core phthalocyanine platform allows engineering the solubility properties the band gap; shifting the maximum absorption toward the red. A simple method to increase the efficiency of heterojunction solar cells uses a self-organized blend of the phthalocyanine chromophores fabricated by solution processing. PMID:20136126

Bioremediation of Cephalexin with non-living Chlorella sp., biomass after lipid extraction.

PubMed

Angulo, E; Bula, L; Mercado, I; Montaño, A; Cubillán, N

2018-06-01

In this work, the removal of the Cephalexin by Chlorella sp., nonliving modified by extraction of lipids was evaluated. First, the microalga was grown to completing 20 days and later, the biomass of crop was centrifuged and the extraction of lipids was performed. Two adsorption experiments were performed: (1) with nonliving Chlorella sp. (control), and (2) the obtained biomass after lipid extraction. The high antibiotic removal, 71.19% and 82.77% (control), were obtained at the lowest initial concentration. The contact time between the biosorbent and the antibiotic was 2 h. The adsorption isotherm follows the Freundlich model and the obtained maximum absorption capacity was 63.29 mg of antibiotic/g of biosorbent for lipid-extracted biomass, while the control follows best to the Langmuir model with 129.87 mg/g in maximum absorption capacity. In summary, this biosorbent provides a potential alternative in the removal of Cephalexin. Copyright © 2018 Elsevier Ltd. All rights reserved.

NEUTRONIC REACTOR

DOEpatents

Wigner, E.P.

1958-04-22

A nuclear reactor for isotope production is described. This reactor is designed to provide a maximum thermal neutron flux in a region adjacent to the periphery of the reactor rather than in the center of the reactor. The core of the reactor is generally centrally located with respect tn a surrounding first reflector, constructed of beryllium. The beryllium reflector is surrounded by a second reflector, constructed of graphite, which, in tune, is surrounded by a conventional thermal shield. Water is circulated through the core and the reflector and functions both as a moderator and a coolant. In order to produce a greatsr maximum thermal neutron flux adjacent to the periphery of the reactor rather than in the core, the reactor is designed so tbat the ratio of neutron scattering cross section to neutron absorption cross section averaged over all of the materials in the reflector is approximately twice the ratio of neutron scattering cross section to neutron absorption cross section averaged over all of the material of the core of the reactor.

Utilization of hydroxypropyl carboxymethyl cellulose in synthesis of silver nanoparticles.

PubMed

Abdel-Halim, E S; Alanazi, Humaid H; Al-Deyab, Salem S

2015-04-01

Hydroxypropyl carboxymethyl cellulose samples having varying degrees of substitution and varying degrees of polymerization were used to reduce silver nitrate to silver nanoparticles. UV spectral analysis of silver nanoparticles colloidal solution reveal that increasing the pH of the reduction solution leads to improvement in the intensity of the absorption band for silver nanoparticles, to be maximum at pH 11. The absorption peak intensity also enhanced upon prolonging the reaction duration up to 60 min. The conversion of silver ions to metallic silver nanoparticles was found to be temperature-dependent and maximum transformation occurs at 60 °C. The reduction efficiency of hydroxypropyl carboxymethyl cellulose was found to be affected by its degree of polymerization. Colloidal solutions of silver nanoparticles having concentration up to 1000 ppm can be prepared upon fixing the ratio between silver nitrate and hydroxypropyl carboxymethyl cellulose at 0.017-0.3g per each 100ml of the reduction solution. Copyright © 2015 Elsevier B.V. All rights reserved.

Leaf Optical Properties in Higher Plants: Linking Spectral Characteristics to Stress and Chlorophyll Concentration

NASA Technical Reports Server (NTRS)

Carter, Gregory A.; Knapp, Alan K.

2000-01-01

A number of studies have linked responses in leaf spectral reflectance, transmittance or absorptance to physiological stress. A variety of stressors including dehydration, flooding,freezing, ozone, herbicides, competition, disease, insects and deficiencies in ectomycorrhizal development and N fertilization have been imposed on species ranging from grasses to conifers and deciduous trees. In this cases, the maximum difference in reflectance within the 400 - 850 nm wavelength range between control and stressed states occurred as a reflectance increase at wavelength near 700 nm. In studies that included transmittance and absorptance as well as reflectance, maximum differences occurred as increases and decreases, respectively, near 700 nm. This common optical response to stress could be simulated closely by varying the chlorophyll concentrations in senescent leaves of five species. The optical response to stress near 700 nm, as well as corresponding changes in reflectance that occur in the green-yellow spectrum, can be explained by the general tendency of stress to reduce leaf chlorophyll concentration.

Synthesis and application of a highly selective copper ions fluorescent probe based on the coumarin group

NASA Astrophysics Data System (ADS)

He, Guangjie; Liu, Xiangli; Xu, Jinhe; Ji, Liguo; Yang, Linlin; Fan, Aiying; Wang, Songjun; Wang, Qingzhi

2018-02-01

A highly selective copper ions fluorescent probe based on the coumarin-type Schiff base derivative 1 (probe) was produced by condensation reaction between coumarin carbohydrazide and 1H-indazole-3-carbaldehyde. The UV-vis spectroscopy showed that the maximum absorption peak of compound 1 appeared at 439 nm. In the presence of Cu2 + ions, the maximum peak decreased remarkably compared with other physiological important metal ions and a new absorption peak at 500 nm appeared. The job's plot experiments showed that complexes of 1:2 binding mode were formed in CH3CN:HEPES (3:2, v/v) solution. Compound 1 exhibited a strong blue fluorescence. Upon addition of copper ions, the fluorescence gradually decreased and reached a plateau with the fluorescence quenching rate up to 98.73%. The detection limit for Cu2 + ions was estimated to 0.384 ppm. Fluorescent microscopy experiments demonstrated that probe 1 had potential to be used to investigate biological processes involving Cu2 + ions within living cells.

Nanosized amorphous (Co‚ Fe) oxide particles decorated PANI-CNT: facile synthesis‚ characterization‚ magnetic‚ electromagnetic properties and their application

NASA Astrophysics Data System (ADS)

Heydari, Farhood; Afghahi, Seyyed Salman Seyyed; Manteghian, Mehrdad; Taghizadeh, Mohammad Javad

2017-11-01

In this research (PANI/CNT) core/shell nanocomposite were synthesized via in situ chemical oxidative seeding polymerization‚ the results of SEM indicated the structure of synthesized nanocomposite. TEM‚ FTIR‚ UV-Vis‚ XRD analyses of samples showed that this nanocomposite is decorated with (Fe‚ Co) oxide nanoparticles. The VSM test of as prepared and annealed nanocomposite exhibited the saturated magnetization of 1.1 and 3.86 emu/g, respectively; the coercivity values were also - 350 and - 110 Oe, respectively. The reflection loss characteristics of (Fe‚ Co) oxide-Pani-CNT core/shell nanocomposite were also investigated with a vector network analyzer‚ in the 8.2-12.4 GHz range (X band). The maximum absorption increases with enhancement of the dispersed nanoparticles percent in polyurethane matrix from 1 to 10%. The value of the maximum reflection loss in the absorption samples with 1 and 10% of nanoparticles is - 2.14 dB at 9.33 GHz and - 7.32 dB at 11.97 GHZ, respectively.

Reflection by absorbing periodically stratified media

NASA Astrophysics Data System (ADS)

Lekner, John

2014-03-01

Existing theory gives the optical properties of a periodically stratified medium in terms of a two by two matrix. This theory is valid also for absorbing media, because the matrix remains unimodular. The main effect of absorption is that the reflection (of either polarization) becomes independent of the number of periods N, and of the substrate properties, provided N exceeds a certain value which depends on the absorption. The s and p reflections are then given by simple formulae. The stop-band structure, which gives total reflection in bands of frequency and angle of incidence in the non-absorbing case, remains influential in weakly absorbing media, causing strong variations in reflectivity. The theory is applied to the frequency dependence of the normal-incidence reflectivity of a quarter-wave stack in which the high-index and low-index layers both absorb weakly. Analytical expressions are obtained for the frequency at which the reflectivity is maximum, the maximum reflectivity, and also for the reflectivity at the band edges of the stop band of the non-absorbing stack.

Two-Flux Method for Transient Radiative Transfer in a Semitransparent Layer

NASA Technical Reports Server (NTRS)

Siegel, Robert

1996-01-01

The two-flux method was used to obtain transient solutions for a plane layer including internal reflections and scattering. The layer was initially at uniform temperature, and was heated or cooled by external radiation and convection. The two-flux equations were examined as a means for evaluating the radiative flux gradient in the transient energy equation. Comparisons of transient temperature distributions using the two-flux method were made with results where the radiative flux gradient was evaluated from the exact radiative transfer equations. Good agreement was obtained for optical thicknesses from 0.5 to 5 and for refractive indices of 1 and 2. Illustrative results obtained with the two-flux method demonstrate the effect of isotropic scattering coupled with changing the refractive index. For small absorption with large scattering the maximum layer temperature is increased when the refractive index is increased. For larger absorption the effect is opposite, and the maximum temperature decreases with increased refractive index .

Nonlinear Relationships Between Particulate Absorption and Chlorophyll: Detritus or Pigment Packaging

DTIC Science & Technology

1993-06-15

for another polar area. For samples from Antartic waters, the mean a*pan(4 3 5 ), normalized to chl a + pheo, was 0.0 18 m2 (mg chl a)-I (Mitchell and...specific absorption coefficients, was suggested as the cause of relatively low mean specific absorption coefficients in the Antartic . The values of c1...moored optical sensors in the Sargasso Sea. J. Geophys. Res. 97, 7399-7412. Mitchell, B.G., and 0. Holm-Hansen 1991. Bio-optical properties of Antartic

The aquatic optics of Lake Tahoe, California-Nevada

NASA Astrophysics Data System (ADS)

Swift, Theodore John

The causes of visual clarity decline and variability in Lake Tahoe, USA, were investigated within the framework of hydrologic optics theory. Ultra-oligotrophic subalpine (1898 m elevation) Lake Tahoe is among the world's clearest, deepest (499 m) and largest (500 km2), representing a unique environmental and economic resource. University of California Davis has documented a ˜0.3 m y-1 trend of decreasing Secchi depth, with ˜3 m interannual variations. Previous work strongly suggested two seasonal modes due to independent processes: A June minimum is due primarily to tributary sediment discharge during snowmelt. A December minimum is due to the deepening mixed layer bringing up phytoplankton and other particles that form a deep particle maximum (DCM) well below the summer mixed layer and Secchi depth stratum. SEM and elemental analysis confirmed as much as 60 percent of near-surface suspended particles were of terrestrial inorganic origin in summer, with inorganic particles minimal (˜20 percent) in winter. Chromophoric dissolved organic matter (CDOM) light absorption in Tahoe is extremely low, comparable to pelagic marine waters, and plays a minor role in clarity loss in Tahoe. However, CDOM reduces ultraviolet light penetration. Mean absorption is 0.040 +/- 0.003 m-1 at 400 nm with 0.023 +/- 0.004 nm-1 exponential slope. The CDOM appears to be autochthonous (phytoplankton), rather than allocthonous (terrestrial humic substances). Chlorophyll-specific particulate absorption is similar to that found for temperate oceans, implying that ocean color models can be successfully applied to Lake Tahoe. Chlorophyll-specific diffuse attenuation along with increased scattering by sediments has caused an upward shift of the DCM from 60--90 m (early 1970s) to 40--70 m recently. Increased attenuation will reduce benthic relative to pelagic primary production. Since measurements in 1971, the lake's color has shifted slightly from blue towards green, though more seasonal measurements are needed to fully quantify the recent range of variation. A clarity model was developed that predicts Secchi depth and diffuse attenuation from inorganic particle and chlorophyll concentration. While organic particles are generally the numerical majority, inorganic particles cause ˜60% of clarity loss, algal-derived particles contribute ˜25%, with the remainder due to CDOM and pure water absorption.

Exciton Absorption in Semiconductor Quantum Wells Driven by a Strong Intersubband Pump Field

NASA Technical Reports Server (NTRS)

Liu, Ansheng; Ning, Cun-Zheng

1999-01-01

Optical interband excitonic absorption of semiconductor quantum wells (QW's) driven by a coherent pump field is investigated based on semiconductor Bloch equations. The pump field has a photon energy close to the intersubband spacing between the first two conduction subbands in the QW's. An external weak optical field probes the interband transition. The excitonic effects and pump-induced population redistribution within the conduction subbands in the QW system are included. When the density of the electron-hole pairs in the QW structure is low, the pump field induces an Autler-Townes splitting of the exciton absorption spectrum. The split size and the peak positions of the absorption doublet depend not only on the pump frequency and intensity but also on the carrier density. As the density of the electron-hole pairs is increased, the split contrast (the ratio between the maximum and minimum values) is decreased because the exciton effect is suppressed at higher densities due to the many-body screening.

Ketoprofen suppository dosage forms: in vitro release and in vivo absorption studies in rabbits.

PubMed

Babar, A; Bellete, T; Plakogiannis, F M

1999-02-01

In vitro release of ketoprofen from suppository bases and in vivo absorption in rabbits were studied. Suppositories containing 50 mg of ketoprofen were prepared using theobroma oil, esterified (c10-c18) fatty acids, and polyethylene glycol 1000 bases. The displacement values of the drug were determined and found to be of the order of theobroma oil > esterified (c10-c18) fatty acids and polyethylene glycol 1000 bases. The suppository hardness data revealed that the theobroma oil base produced relatively brittle suppositories. Using the USP dissolution method, the release of ketoprofen was observed to be greatest from polyethylene glycol 1000 suppositories. With the dialysis technique, the maximum release of drug was obtained from theobroma oil suppository containing polysorbate 40 at a 6% level. Selected suppository formulations were evaluated for rectal absorption studies in rabbits. The in vivo data showed that the optimum drug absorption took place from the polyethylene glycol 1000 base and theobroma oil formulation containing 6% polysorbate 40.

Electrical potential difference and absorption of water, sodium, and potassium by the terminal ileum of ileostomy patients

PubMed Central

De Moraes-Filho, J. Prado P.; Salas-Coll, C.; Blendis, Laurie; Edmonds, C. J.

1974-01-01

Measurements of electrical potential difference (pd) and of absorption by a dialysis method were carried out in the terminal ileum of patients with an ileostomy. The pd measured with saline in the lumen and at a few centimetres within the stoma averaged 9.2 mV, lumen negatively charged. The pd values were similar whether the ileostomy had been recently or long established. The pd rose considerably when glucose was added to the luminal solution, the maximum effect being attained with a concentration of 40 mmol/1. With a saline bicarbonate solution (Na 145 or 140 m-equiv/1, K 5, or 10 m-equiv/1) in the dialysis tube, considerable absorption of fluid and sodium was demonstrable with little change in sodium concentration. Potassium secretion occurred with the lower, and absorption with the higher, concentration. The final luminal potassium concentration reached was consistent with a passive distribution between blood and lumen. PMID:4448413

Preparation of novel oxidized mesoporous carbon with excellent adsorption performance for removal of malachite green and lead ion

NASA Astrophysics Data System (ADS)

Zhang, Xialan; Lin, Qilang; Luo, Shiyuan; Ruan, Kezhao; Peng, Kaiping

2018-06-01

An oxidized mesoporous carbon (OMC) with fluffy structure was fabricated from the mixture of petroleum asphalt and aluminum isopropoxide, and its structures were characterized by FESEM, TEM, BET, TG, XPS and FT-IR. In addition, bath absorption experiments for malachite green (MG) and lead ion (Pb2+) were carried out to explore the effects of pH, initial concentration, contact time and temperature on its absorption process. Results show that the OMC prepared has a fluffy ultrathin-wall structure with narrow pore size distribution and rich oxygen-containing groups. It exhibits excellent absorption performance for the removal of MG as well as Pb2+, as indicated by that its maximum adsorption capacity is 963.1 mg g-1 for MG and 198.6 mg g-1 for Pb2+. The absorption experimental data are all fitted well with pseudo-second-order model and Frendlich isotherm, respectively. More importantly, the OMC still maintains relatively high adsorption capacity after five cycles.

Flower-like BiOI microsphere/Ni@C nanocapsule hybrid composites and their efficient microwave absorbing activity

NASA Astrophysics Data System (ADS)

Liu, Xianguo; Yu, Jieyi; Cui, Caiyun; Sun, Yuping; Li, Xiaolong; Li, Zhenxing

2018-07-01

At present, microwave absorbers are prepared by dispersing absorbing nanomaterials in a binder, which can lead to the aggregation of nanomaterials in the binder and further affect the optimization of the absorption performances. Hybrid micro/nano-scale structures are beneficial for buffering agglomeration phenomena and the construction of multiple interfaces. Here, Ni@C nanocapsules are conjugated onto flower-like BiOI microspheres, forming micro/nano-scale hybrid composites. The multiple interfaces between BiOI microspheres and Ni@C nanocapsules can bring enhanced dielectric loss and increased attenuation constant, resulting in the enhancement of absorption capacity (the optimal reflection loss reaches  ‑61.35 dB), increased width of the effective absorption band (the maximum effective bandwidth, f Emax , is 5.86 GHz) and the reduction of absorption thickness (the thickness corresponding to f Emax is 1.7 mm). This study highlights a simple idea for the optimization of electromagnetic absorbing performance, which is of great significance in the development of microwave absorbers.

Optical levitation of 10-ng spheres with nano-g acceleration sensitivity

NASA Astrophysics Data System (ADS)

Monteiro, Fernando; Ghosh, Sumita; Fine, Adam Getzels; Moore, David C.

2017-12-01

We demonstrate optical levitation of SiO2 spheres with masses ranging from 0.1 to 30 ng. In high vacuum, we observe that the measured acceleration sensitivity improves for larger masses and obtain a sensitivity of 0.4 ×10-6g /√{Hz } for a 12-ng sphere, more than an order of magnitude better than previously reported for optically levitated masses. In addition, these techniques permit long integration times and a mean acceleration of (-0.7 ±2.4 [stat] ±0.2 [syst] ) ×10-9g is measured in 1.4 ×104 s. Spheres larger than 10 ng are found to lose mass in high vacuum where heating due to absorption of the trapping laser dominates radiative cooling. This absorption constrains the maximum size of spheres that can be levitated and allows a measurement of the absorption of the trapping light for the commercially available spheres tested here. Spheres consisting of material with lower absorption may allow larger objects to be optically levitated in high vacuum.

Estimation of alga growth stage and lipid content growth rate

NASA Technical Reports Server (NTRS)

Embaye, Tsegereda N. (Inventor); Trent, Jonathan D. (Inventor)

2012-01-01

Method and system for estimating a growth stage of an alga in an ambient fluid. Measured light beam absorption or reflection values through or from the alga and through an ambient fluid, in each of two or more wavelength sub-ranges, are compared with reference light beam absorption values for corresponding wavelength sub-ranges for in each alga growth stage to determine (1) which alga growth stage, if any, is more likely and (2) whether estimated lipid content of the alga is increasing or has peaked. Alga growth is preferably terminated when lipid content has approximately reached a maximum value.

Functional characterization of folic acid transport in the intestine of the laying hen using the everted intestinal sac model.

PubMed

Tactacan, G B; Rodriguez-Lecompte, J C; Karmin, O; House, J D

2011-01-01

Absorption at the level of the intestine is likely a primary regulatory mechanism for the deposition of dietary supplemented folic acid into the chicken egg. Therefore, factors affecting the intestinal transport of folic acid in the laying hen may influence the level of egg folate concentrations. To this end, a series of experiments using intestinal everted sacs were conducted to characterize intestinal folic acid absorption processes in laying hens. Effects of naturally occurring folate derivatives (5-methyl and 10-formyltetrahydrofolate) as well as heme on folic acid absorption were also investigated. Folic acid absorption was measured based on the rate of uptake of (3)H-labeled folic acid in the everted sac from various segments of the small and large intestines. Folic acid concentration, incubation length, and pH condition were optimized before the performance of uptake experiments. The distribution profile of folic acid transport along the intestine was highest in the upper half of the small intestine. Maximum uptake rate (nmol·100 g tissue(-1)·min(-1)) was observed in the duodenum (20.6 ± 1.9) and jejunum (22.3 ± 2.0) and decreased significantly in the ileum (15.3 ± 1.1) and cecum (9.3 ± 0.9). Transport increased proportionately (P < 0.05) between 0.0001 and 0.1 µM folic acid. Above 0.1 µM, the slope of the regression line was not significantly different from zero (P < 0.137). Folic acid uptake in the jejunum showed a maximum rate of transport at pH 6.0, but was lowest at pH 7.5. The presence of 5-methyl and 10-formyltetrahydrofolate as well as heme impeded folic acid uptake, reducing intestinal folic acid absorption when added at concentrations ranging from 0 to 100 µM. Overall, these data indicated the presence of a folic acid transport system in the entire intestine of the laying hen. Uptake of folic acid in the cecum raises the likelihood of absorption of bacterial-derived folate.

Mass Spectrometry Imaging proves differential absorption profiles of well-characterised permeability markers along the crypt-villus axis.

PubMed

Nilsson, Anna; Peric, Alexandra; Strimfors, Marie; Goodwin, Richard J A; Hayes, Martin A; Andrén, Per E; Hilgendorf, Constanze

2017-07-25

Knowledge about the region-specific absorption profiles from the gastrointestinal tract of orally administered drugs is a critical factor guiding dosage form selection in drug development. We have used a novel approach to study three well-characterized permeability and absorption marker drugs in the intestine. Propranolol and metoprolol (highly permeable compounds) and atenolol (low-moderate permeability compound) were orally co-administered to rats. The site of drug absorption was revealed by high spatial resolution matrix-assisted laser desorption ionization mass spectrometry imaging (MALDI-MSI) and complemented by quantitative measurement of drug concentration in tissue homogenates. MALDI-MSI identified endogenous molecular markers that illustrated the villi structures and confirmed the different absorption sites assigned to histological landmarks for the three drugs. Propranolol and metoprolol showed a rapid absorption and shorter transit distance in contrast to atenolol, which was absorbed more slowly from more distal sites. This study provides novel insights into site specific absorption for each of the compounds along the crypt-villus axis, as well as confirming a proximal-distal absorption gradient along the intestine. The combined analytical approach allowed the quantification and spatial resolution of drug distribution in the intestine and provided experimental evidence for the suggested absorption behaviour of low and highly permeable compounds.

Development of population pharmacokinetics model of icotinib with non-linear absorption characters in healthy Chinese volunteers to assess the CYP2C19 polymorphism and food-intake effect.

PubMed

Hu, Pei; Chen, Jia; Liu, Dongyang; Zheng, Xin; Zhao, Qian; Jiang, Ji

2015-07-01

Icotinib is a potent and selective inhibitor of epidermal growth factor receptors (EGFR) approved to treat non-small cell lung cancer (NSCLC). However, its high variability may impede its application. The objectives of this analysis were to assess plasma pharmacokinetics and identify covariates that may explain variability in icotinib absorption and/or disposition following single dose of icotinib in healthy volunteers. Data from two clinical studies (n = 22) were analyzed. One study was designed as three-period and Latin-squared (six sequence) trial to evaluate dose proportionality, and the other one was designed as two-way crossover trial to evaluate food effect on pharmacokinetics (PK) characters. Icotinib concentrations in plasma were analyzed using non-linear mixed-effects model (NONMEM) method. The model was used to assess influence of food, demographic characteristics, measurements of blood biochemistry, and CYP2C19 genotype on PK characters of icotinib in humans. The final model was diagnosed by goodness-of-fit plots and evaluated by visual predictive check (VPC) and bootstrap methods. A two-compartment model with saturated absorption character was developed to capture icotinib pharmacokinetics. Typical value of clearance, distribution clearance, central volume of distribution, maximum absorption rate were 29.5 L/h, 24.9 L/h, 18.5 L, 122.2 L and 204,245 μg/h, respectively. When icotinib was administrated with food, bioavailability was estimated to be increased by 48%. Inter-occasion variability was identified to affect on maximum absorption rate constant in food-effect study. CL was identified to be significantly influenced by age, albumin concentration (ALB), and CYP2C19 genotype. No obvious bias was found by VPC and bootstrap methods. The developed model can capture icotinib pharmacokinetics well in healthy volunteers. Food intake can increase icotinib exposure. Three covariates, age, albumin concentration, and CYP2C19 genotype, were identified to significantly affect icotinib PK profiles in healthy subjects.

Spectroscopic studies of two spectral variants of light-harvesting complex 2 (LH2) from the photosynthetic purple sulfur bacterium Allochromatium vinosum.

PubMed

Niedzwiedzki, Dariusz M; Bina, David; Picken, Nichola; Honkanen, Suvi; Blankenship, Robert E; Holten, Dewey; Cogdell, Richard J

2012-09-01

Two spectral forms of the peripheral light-harvesting complex (LH2) from the purple sulfur photosynthetic bacterium Allochromatium vinosum were purified and their photophysical properties characterized. The complexes contain bacteriochlorophyll a (BChl a) and multiple species of carotenoids. The composition of carotenoids depends on the light conditions applied during growth of the cultures. In addition, LH2 grown under high light has a noticeable split of the B800 absorption band. The influence of the change of carotenoid distribution as well as the spectral change of the excitonic absorption of the bacteriochlorophylls on the light-harvesting ability was studied using steady-state absorption, fluorescence and femtosecond time-resolved absorption at 77K. The results demonstrate that the change of the distribution of the carotenoids when cells were grown at low light adapts the absorptive properties of the complex to the light conditions and maintains maximum photon-capture performance. In addition, an explanation for the origin of the enigmatic split of the B800 absorption band is provided. This spectral splitting is also observed in LH2 complexes from other photosynthetic sulfur purple bacterial species. According to results obtained from transient absorption spectroscopy, the B800 band split originates from two spectral forms of the associated BChl a monomeric molecules bound within the same complex. Copyright © 2012 Elsevier B.V. All rights reserved.

Gallic Acid as an Oxygen Scavenger in Bio-Based Multilayer Packaging Films

PubMed Central

Pant, Astrid F.; Sängerlaub, Sven; Müller, Kajetan

2017-01-01

Oxygen scavengers are used in food packaging to protect oxygen-sensitive food products. A mixture of gallic acid (GA) and sodium carbonate was used as an oxygen scavenger (OSc) in bio-based multilayer packaging films produced in a three-step process: compounding, flat film extrusion, and lamination. We investigated the film surface color as well as oxygen absorption at different relative humidities (RHs) and temperatures, and compared the oxygen absorption of OSc powder, monolayer films, and multilayer films. The films were initially brownish-red in color but changed to greenish-black during oxygen absorption under humid conditions. We observed a maximum absorption capacity of 447 mg O2/g GA at 21 °C and 100% RH. The incorporation of GA into a polymer matrix reduced the rate of oxygen absorption compared to the GA powder because the polymer acted as a barrier to oxygen and water vapor diffusion. As expected, the temperature had a significant effect on the initial absorption rate of the multilayer films; the corresponding activation energy was 75.4 kJ/mol. Higher RH significantly increased the oxygen absorption rate. These results demonstrate for the first time the production and the properties of a bio-based multilayer packaging film with GA as the oxygen scavenger. Potential applications include the packaging of food products with high water activity (aw > 0.86). PMID:28772849

Gallic Acid as an Oxygen Scavenger in Bio-Based Multilayer Packaging Films.

PubMed

Pant, Astrid F; Sängerlaub, Sven; Müller, Kajetan

2017-05-03

Oxygen scavengers are used in food packaging to protect oxygen-sensitive food products. A mixture of gallic acid (GA) and sodium carbonate was used as an oxygen scavenger (OSc) in bio-based multilayer packaging films produced in a three-step process: compounding, flat film extrusion, and lamination. We investigated the film surface color as well as oxygen absorption at different relative humidities (RHs) and temperatures, and compared the oxygen absorption of OSc powder, monolayer films, and multilayer films. The films were initially brownish-red in color but changed to greenish-black during oxygen absorption under humid conditions. We observed a maximum absorption capacity of 447 mg O₂/g GA at 21 °C and 100% RH. The incorporation of GA into a polymer matrix reduced the rate of oxygen absorption compared to the GA powder because the polymer acted as a barrier to oxygen and water vapor diffusion. As expected, the temperature had a significant effect on the initial absorption rate of the multilayer films; the corresponding activation energy was 75.4 kJ/mol. Higher RH significantly increased the oxygen absorption rate. These results demonstrate for the first time the production and the properties of a bio-based multilayer packaging film with GA as the oxygen scavenger. Potential applications include the packaging of food products with high water activity (a w > 0.86).

Toxic metals in imported fruits and vegetables marketed in Kuwait

DOE Office of Scientific and Technical Information (OSTI.GOV)

Husain, A.; Baroon, Z.; Al-Khalafawi, M.

1995-12-31

The concentration of lead, cadmium, and mercury in 134 samples of imported fruits and vegetables marketed in Kuwait were determined using an atomic absorption spectrophotometer with a graphite furnace and the cold vapor technique. Results obtained showed that the concentration of these metal ions in most cases did not exceed the maximum permissible concentration of metals in fresh fruits and vegetables as restricted by some countries. Only a few samples of fruits and vegetables contained levels of mercury, cadmium, and lead which exceeded these maximum permissible levels.

EDGES result versus CMB and low-redshift constraints on ionization histories

NASA Astrophysics Data System (ADS)

Witte, Samuel; Villanueva-Domingo, Pablo; Gariazzo, Stefano; Mena, Olga; Palomares-Ruiz, Sergio

2018-05-01

We examine the results from the Experiment to Detect the Global Epoch of Reionization Signature (EDGES), which has recently claimed the detection of a strong absorption in the 21 cm hyperfine transition line of neutral hydrogen, at redshifts demarcating the early stages of star formation. More concretely, we study the compatibility of the shape of the EDGES absorption profile, centered at a redshift of z ˜17.2 , with measurements of the reionization optical depth, the Gunn-Peterson optical depth, and Lyman-α emission from star-forming galaxies, for a variety of possible reionization models within the standard Λ CDM framework (that is, a Universe with a cosmological constant Λ and cold dark matter CDM). When, conservatively, we only try to accommodate the location of the absorption dip, we identify a region in the parameter space of the astrophysical parameters that successfully explains all of the aforementioned observations. However, one of the most abnormal features of the EDGES measurement is the absorption amplitude, which is roughly a factor of 2 larger than the maximum allowed value in the Λ CDM framework. We point out that the simple considered astrophysical models that produce the largest absorption amplitudes are unable to explain the depth of the dip and of reproducing the observed shape of the absorption profile.

Changes in the optical absorption induced by sequential exposition to short- and long-wavelength radiation in the BTO:Al crystal

NASA Astrophysics Data System (ADS)

Shandarov, S. M.; Dyu, V. G.; Kisteneva, M. G.; Khudyakova, E. S.; Smirnov, S. V.; Akrestina, A. S.; Kargin, Yu F.

2017-02-01

Modifications of the spectral dependences of the optical absorption induced in the Bi12TiO20:Al crystal as a result of sequential exposition to cw laser radiation first with the wavelength λ g = 532 nm and then with the longer wavelength λ l,n = 588, 633, 655, 658, 663, 700, 780, 871, or 1064 nm are investigated. We revealed that after the short-wavelength exposition to radiation with λg = 532 nm, the optical absorption in the crystal increases, and in the range 470-1000 nm, yields the spectrum whose form is independent of a prehistory. The subsequent exposition to longer-wavelength radiation leads to bleaching of the crystal in the examined spectral range. A maximum diminishing of the optical absorption in the crystal is observed upon exposure to radiation with the wavelength λ l,5 = 663 nm. To describe the experimentally observed reversible changes in the optical absorption spectrum in the Bi12TiO20:Al we use the impurity absorption model that takes into account the photoinduced transitions between two metastable states of a deep defect center leading to the change of its position in the crystal lattice under conditions of strong lattice relaxation.

Research on filling process of fuel and oxidant during detonation based on absorption spectrum technology

NASA Astrophysics Data System (ADS)

Lv, Xiao-Jing; Li, Ning; Weng, Chun-Sheng

2014-12-01

Research on detonation process is of great significance for the control optimization of pulse detonation engine. Based on absorption spectrum technology, the filling process of fresh fuel and oxidant during detonation is researched. As one of the most important products, H2O is selected as the target of detonation diagnosis. Fiber distributed detonation test system is designed to enable the detonation diagnosis under adverse conditions in detonation process. The test system is verified to be reliable. Laser signals at different working frequency (5Hz, 10Hz and 20Hz) are detected. Change of relative laser intensity in one detonation circle is analyzed. The duration of filling process is inferred from the change of laser intensity, which is about 100~110ms. The peak of absorption spectrum is used to present the concentration of H2O during the filling process of fresh fuel and oxidant. Absorption spectrum is calculated, and the change of absorption peak is analyzed. Duration of filling process calculated with absorption peak consisted with the result inferred from the change of relative laser intensity. The pulse detonation engine worked normally and obtained the maximum thrust at 10Hz under experiment conditions. The results are verified through H2O gas concentration monitoring during detonation.

Observation of confinement effects through liner and nonlinear absorption spectroscopy in cuprous oxide

NASA Astrophysics Data System (ADS)

Sekhar, H.; Rakesh Kumar, Y.; Narayana Rao, D.

2015-02-01

Cuprous oxide nano clusters, micro cubes and micro particles were successfully synthesized by reducing copper (II) salt with ascorbic acid in the presence of sodium hydroxide via a co-precipitation method. The X-ray diffraction studies revealed the formation of pure single phase cubic. Raman spectrum shows the inevitable presence of CuO on the surface of the Cu2O powders which may have an impact on the stability of the phase. Transmission electron microscopy (TEM) data revealed that the morphology evolves from nanoclusters to micro cubes and micro particles by increasing the concentration of NaOH. Linear optical measurements show that the absorption peak maximum shifts towards red with changing morphology from nano clusters to micro cubes and micro particles. The nonlinear optical properties were studied using open aperture Z-scan technique with 532 nm, 6 ns laser pulses. Samples exhibited saturable as well as reverse saturable absorption. The results show that the transition from SA to RSA is ascribed to excited-state absorption (ESA) induced by two-photon absorption (TPA) process. Due to confinement effects (enhanced band gap) we observed enhanced nonlinear absorption coefficient (βeff) in the case of nano-clusters compared to their micro-cubes and micro-particles.

Specific absorption rate analysis of broadband mobile antenna with negative index metamaterial

NASA Astrophysics Data System (ADS)

Alam, Touhidul; Faruque, Mohammad Rashed Iqbal; Islam, Mohammad Tariqul

2016-03-01

This paper presents a negative index metamaterial-inspired printed mobile wireless antenna that can support most mobile applications such as GSM, UMTS, Bluetooth and WLAN frequency bands. The antenna consists of a semi-circular patch, a 50Ω microstrip feed line and metamaterial ground plane. The antenna occupies a very small space of 37 × 47 × 0.508 mm3, making it suitable for mobile wireless application. The perceptible novelty shown in this proposed antenna is that reduction of specific absorption rate using the negative index metamaterial ground plane. The proposed antenna reduced 72.11 and 75.53 % of specific absorption rate at 1.8 and 2.4 GHz, respectively.

Survey on Different Samsung with Nokia Smart Mobile Phones in the Specific Absorption Rate Electrical Field of Head

PubMed Central

Fakhri, Yadolah; Alinejad, Azim; Keramati, Hassan; Bay, Abotaleb; Avazpour, Moayed; Zandsalimi, Yahya; Moradi, Bigard; Amirhajeloo, Leila Rasouli; Mirzaei, Maryam

2016-01-01

The use of smart phones is increasing in the world. This excessive use, especially in the last two decades, has created too much concern on the effects of emitted electromagnetic fields and specific absorption rate on human health. In this descriptive-analytical study of the electric field resulting from smart phones of Samsung and Nokia by portable measuring device, electromagnetic field, Model HI-3603-VDT/VLF, were measured. Then, head absorption rate was calculated in these two mobiles by ICNIRP equation. Finally, the comparison of specific absorption rate, especially between Samsung and Nokia smart phones, was conducted by T-Test statistics analysis. The mean of electric field for Samsung and Nokia smart mobile phones was obtained 1.8 ±0.19 v/m and 2.23±0.39 v/m, respectively, while the range of the electric field was obtained as 1.56-2.21 v/m and 1.69-2.89 v/m for them, respectively. The mean of specific absorption rate in Samsung and Nokia was obtained 0.002 ± 0.0005 W/Kg and 0.0041±0.0013 W/Kg at the frequency of 900 MHz and 0.004±0.001 W/Kg and 0.0062±0.0002 W/Kg at the frequency of 1800 MHz respectively. The ratio of mean electronic field to guidance in the Samsung mobile phone at the frequency of 900 MHz and 1800 MHz was 4.36% and 3.34%, while was 5.62% and 4.31% in the Nokia mobile phone, respectively. The ratio of mean head specific absorption rate in smart mobile phones of Samsung and Nokia in the guidance level at the frequency of 900 was 0.15% and 0.25%, respectively, while was 0.23% and 0.38% at the frequency of 1800 MHz, respectively. The rate of specific absorption of Nokia smart mobile phones at the frequencies of 900 and 1800 MHz was significantly higher than Samsung (p value <0.05). Hence, we can say that in a fixed period, health risks of Nokia smart phones is higher than Samsung smart mobile phone. PMID:27157169

Survey on Different Samsung with Nokia Smart Mobile Phones in the Specific Absorption Rate Electrical Field of Head.

PubMed

Fakhri, Yadolah; Alinejad, Azim; Keramati, Hassan; Bay, Abotaleb; Avazpour, Moayed; Zandsalimi, Yahya; Moradi, Bigard; Rasouli Amirhajeloo, Leila; Mirzaei, Maryam

2016-09-01

The use of smart phones is increasing in the world. This excessive use, especially in the last two decades, has created too much concern on the effects of emitted electromagnetic fields and specific absorption rate on human health. In this descriptive-analytical study of the electric field resulting from smart phones of Samsung and Nokia by portable measuring device, electromagnetic field, Model HI-3603-VDT/VLF, were measured. Then, head absorption rate was calculated in these two mobiles by ICNIRP equation. Finally, the comparison of specific absorption rate, especially between Samsung and Nokia smart phones, was conducted by T-Test statistics analysis. The mean of electric field for Samsung and Nokia smart mobile phones was obtained 1.8 ±0.19 v/m  and 2.23±0.39 v/m , respectively, while the range of the electric field was obtained as 1.56-2.21 v/m and 1.69-2.89 v/m for them, respectively. The mean of specific absorption rate in Samsung and Nokia was obtained 0.002 ± 0.0005 W/Kg and 0.0041±0.0013 W/Kg at the frequency of 900 MHz and 0.004±0.001 W/Kg and 0.0062±0.0002 W/Kg at the frequency of 1800 MHz respectively. The ratio of mean electronic field to guidance in the Samsung mobile phone at the frequency of 900 MHz and 1800 MHz was 4.36% and 3.34%, while was 5.62% and 4.31% in the Nokia mobile phone, respectively. The ratio of mean head specific absorption rate in smart mobile phones of Samsung and Nokia in the guidance level at the frequency of 900 was 0.15% and 0.25%, respectively, while was 0.23 %and 0.38% at the frequency of 1800 MHz, respectively. The rate of specific absorption of Nokia smart  mobile phones at the frequencies of 900 and 1800 MHz  was significantly higher than Samsung (p value <0.05). Hence, we can say that in a fixed period, health risks of Nokia smart phones is higher than Samsung smart mobile phone.

Confirmation and mechanism of glyphosate resistance in tall windmill grass (Chloris elata) from Brazil.

PubMed

Brunharo, Caio Acg; Patterson, Eric L; Carrijo, Daniela R; de Melo, Marcel Sc; Nicolai, Marcelo; Gaines, Todd A; Nissen, Scott J; Christoffoleti, Pedro J

2016-09-01

Overreliance on glyphosate as a single tool for weed management in agricultural systems in Brazil has selected glyphosate-resistant populations of tall windmill grass (Chloris elata Desv.). Two C. elata populations, one glyphosate resistant (GR) and one glyphosate susceptible (GS), were studied in detail for a dose-response experiment and for resistance mechanism. The dose causing 50% reduction in dry weight was 620 g a.e. ha(-1) for GR and 114 g ha(-1) for GS, resulting in an R/S ratio of 5.4. GS had significantly higher maximum (14) C-glyphosate absorption into the treated leaf (51.3%) than GR (39.5%), a difference of 11.8% in maximum absorption. GR also retained more (14) C-glyphosate in the treated leaf (74%) than GS (51%), and GR translocated less glyphosate (27%) to other plant parts (stems, roots and root exudation) than GS (36%). There were no mutations at the Pro106 codon in the gene encoding 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS). There was no difference in EPSPS genomic copy number or EPSPS transcription between GS and GR populations. Based on these data, reduced glyphosate absorption and increased glyphosate retention in the treated leaf contribute to glyphosate resistance in this C. elata population from Brazil. © 2015 Society of Chemical Industry. © 2015 Society of Chemical Industry.

Coherent stimulated light emission (lasing) in covalently linked chlorophyll dimers

PubMed Central

Hindman, James C.; Kugel, Roger; Wasielewski, Michael R.; Katz, Joseph J.

1978-01-01

The covalently linked chlorophyll a dimer exhibits remarkably different properties in the folded and open configurations. In the folded configuration the absorption maximum is at 695 nm and the fluorescence maximum is at 730 nm. Laser output at 733 and 735 nm is obtained for solutions in wet benzene and 0.1 M ethanol/toluene, respectively. Measurements of fluorescence lineshapes, made with a transverse excited atmospheric (TEA) nitrogen laser for excitation, show the lifetime shortening associated with stimulated emission resulting from appreciable concentrations of molecules in S1 excited states. In contrast, the open dimer has absorption and fluorescence spectra essentially the same as those of chlorophyll a monomer. Unlike either the folded dimer or chlorophyll a monomer, the open dimer shows no laser emission or fluorescene lifetime shortening. It does not appear that the behavior of the open dimer can be explained in terms of excimer or triplet formation or by nonradiative decay processes. It is suggested that absorption of the exciting radiation by S1, leading to the formation of an exciplex or charge transfer state, may be involved. Significantly, no large changes in fluorescence quantum yield or fluorescence lifetime are observed for these dimers as compared to monomer chlorophyll. This suggests that concentration quenching and lifetime shortening in condensed chlorophyll systems involve more than the simple proximity of two chlorophyll molecules. Images PMID:16592524

Electronic theoretical study of the influences of O adsorption on the electronic structure and optical properties of graphene

NASA Astrophysics Data System (ADS)

Shuang, Zhou; Guili, Liu; Dazhi, Fan

2017-02-01

The electronic structure and optical properties of adsorbing O atoms on graphene with different O coverage are researched using the density functional theory based upon the first-principle study to obtain further insight into properties of graphene. The adsorption energies, band structures, the density of states, light absorption coefficient and reflectivity of each system are calculated theoretically after optimizing structures of each system with different O coverage. Our calculations show that adsorption of O atoms on graphene increases the bond length of C-C which adjacent to the O atoms. When the O coverage is 9.4%, the adsorption energy (3.91 eV) is the maximum, which only increases about 1.6% higher than that of 3.1% O coverage. We find that adsorbed O atoms on pristine graphene opens up indirect gap of about 0.493-0.952 eV. Adsorbing O atoms make pristine graphene from metal into a semiconductor. When the O coverage is 9.4%, the band gap (0.952 eV) is the maximum. Comparing with pristine graphene, we find the density of states at Fermi level of O atoms adsorbing on graphene with different coverage are significantly increased. We also find that light absorption coefficient and reflectivity peaks are significantly reduced, and the larger the coverage, the smaller the absorption coefficient and reflectivity peaks are. And the blue shift phenomenon appears.

Thermally switchable meta-material absorber involving vanadium dioxide semiconductor-metal transition for thermo photovoltaic conversion

NASA Astrophysics Data System (ADS)

Bendelala, Fathi; Cheknane, Ali; Hilal, Hikmat S.

2018-01-01

A new switchable absorber design using meta-materials for thermo photovoltaic applications is proposed here. Conventional absorbents are normally non-adjustable with narrow band-widths and polarization-dependence. The present study describes an alternative infrared absorber structure with tunable characteristics. The absorber is based on VO2 which exhibits transition from semiconductor to metallic conductor by thermal effect. With this design, the results show that wide-band absorption can be achieved. The absorption bandwidth can be improved from 15.94 to 36.75 THz. With 40.42% relative shift in the peak frequency, a maximum absorption efficiency of 99% can be achieved. This structure design is polarization-independent of normal incident radiations, and may accommodate radiations from wide oblique angles. These new features make the new thermally adjustable absorber potentially useful in thermo-photovoltaic conversion devices.

Solvent effects on the vibronic one-photon absorption profiles of dioxaborine heterocycles

NASA Astrophysics Data System (ADS)

Wang, Yan-Hua; Halik, Marcus; Wang, Chuan-Kui; Marder, Seth R.; Luo, Yi

2005-11-01

The vibronic profiles of one-photon absorption spectra of dioxaborine heterocycles in gas phase and solution have been calculated at the Hartree-Fock and density-functional-theory levels. The polarizable continuum model has been applied to simulate the solvent effect, while the linear coupling model is used to compute the Franck-Condon and Herzberg-Teller contributions. It is found that a good agreement between theory and experiment can be achieved when the solvent effect and electron correlation are taken into account simultaneously. For the first excited charge-transfer state, the maximum of its Herzberg-Teller profile is blueshifted from that of the Franck-Condon profile. The shifted energy is found to be around 0.2eV, which agrees well with the measured energy difference between two- and one-photon absorptions of the first excited state.

Robust electromagnetic absorption by graphene/polymer heterostructures

NASA Astrophysics Data System (ADS)

Lobet, Michaël; Reckinger, Nicolas; Henrard, Luc; Lambin, Philippe

2015-07-01

Polymer/graphene heterostructures present good shielding efficiency against GHz electromagnetic perturbations. Theory and experiments demonstrate that there is an optimum number of graphene planes, separated by thin polymer spacers, leading to maximum absorption for millimeter waves Batrakov et al (2014 Sci. Rep. 4 7191). Here, electrodynamics of ideal polymer/graphene multilayered material is first approached with a well-adapted continued-fraction formalism. In a second stage, rigorous coupled wave analysis is used to account for the presence of defects in graphene that are typical of samples produced by chemical vapor deposition, namely microscopic holes, microscopic dots (embryos of a second layer) and grain boundaries. It is shown that the optimum absorbance of graphene/polymer multilayers does not weaken to the first order in defect concentration. This finding testifies to the robustness of the shielding efficiency of the proposed absorption device.

Design and chemical synthesis of iodine-containing molecules for application to solar-pumped I* lasers

NASA Technical Reports Server (NTRS)

Shiner, C. S.

1985-01-01

This work is directed toward the design and chemical synthesis of new media for solar-pumped I* lasers. In view of the desirability of preparing a perfluoroalkyl iodide absorbing strongly at 300 nm, the relationship betwen perfluoroalkyl iodide structure and the corresponding absorption wavelength was reexamined. Analysis of existing data suggests that, in this family of compounds, the absorption maximum shifts to longer wavelength, as desired, as the C-I bond in the lasant is progressively weakened. Weakening of the C-I bond correlates, in turn, with increasing stability of the perfluoroalkyl radical formed upon photodissociation of the iodide. The extremely promising absorption characteristics of perfluoro-tert-butyl iodide can be accounted for on this basis. A new technique of diode laser probing to obtain precise yields of I* atoms in photodissociation was also developed.

Absorption and Scattering of Aerosol measured onboard R/V Gisang1 over the Yellow Sea

NASA Astrophysics Data System (ADS)

Inae, K.; Lee, M.; Shin, B.; Ryoo, S.; Jung, J.; Kim, S. W.

2017-12-01

Absorption and scattering coefficient were measured onboard RV Gisang 1 over the Yellow Sea (covering 124° 127°E, 31° 38°N) during May June, 2016. BC concentration was analyzed at seven wavelengths (370, 470, 520, 590, 660, 880, and 950nm) every 1 minute by Aethalometer. Scattering coefficient was measured at three wavelengths (450, 550, and 750nm) every 5 minutes with Nephelometer. The mean absorption coefficient was 1.2 Mm-1 at 880nm and the mean scattering coefficient was 116Mm-1 at 550nm. Single scattering albedo(SSA) reached the maximum value of 3.0 at 700nm. The calculated mean scattering angstrom exponent(SAE) was 1.6 and absorbing angstrom exponent(AAE) was 1.1. The AAE and SAE were higher in aged Chinese plume.

12 CFR Appendix A to Subpart D of... - Interagency Guidelines for Real Estate Lending

Code of Federal Regulations, 2014 CFR

2014-01-01

... comprehensive, and consistent with safe and sound lending practices, and must ensure that the institution... employment trends. • Zoning requirements. • Current and projected vacancy, construction, and absorption rates... property. • Maximum loan maturities by type of property. • Amortization schedules. • Pricing structure for...

12 CFR Appendix A to Subpart D of... - Interagency Guidelines for Real Estate Lending

Code of Federal Regulations, 2011 CFR

2011-01-01

... comprehensive, and consistent with safe and sound lending practices, and must ensure that the institution... employment trends. • Zoning requirements. • Current and projected vacancy, construction, and absorption rates... property. • Maximum loan maturities by type of property. • Amortization schedules. • Pricing structure for...

12 CFR Appendix A to Subpart D of... - Interagency Guidelines for Real Estate Lending

Code of Federal Regulations, 2013 CFR

2013-01-01

... comprehensive, and consistent with safe and sound lending practices, and must ensure that the institution... employment trends. • Zoning requirements. • Current and projected vacancy, construction, and absorption rates... property. • Maximum loan maturities by type of property. • Amortization schedules. • Pricing structure for...

A Film Canister Colorimeter.

ERIC Educational Resources Information Center

Gordon, James; James, Alan; Harman, Stephanie; Weiss, Kristen

2002-01-01

A low-cost, low-tech colorimeter was constructed from a film canister. The student-constructed colorimeter was used to show the Beer-Lambert relationship between absorbance and concentration and to calculate the value of the molar absorptivity for permanganate at the wavelength emission maximum for an LED. Makes comparisons between this instrument…

CHANGES IN QUALITY AND COMPOSITION PRODUCED IN WINE BY COBALT-60 GAMMA IRRADIATION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singleton, V.L.

1963-06-01

Glass-bottled red port, white port, dry red table wine, and dry white table wine purged with nitrogen and airsaturated dry sherry material were irradiated with and sensory evaluation showed considerable changes after irradiation. The bottle glass changed from colorless to greenish-brown. The wines were under a small positive pressure when opened, both white and red wines were bleached, and odor and flavor were changed. Analytical results showed no changes in extract, ethanol, volatile esters, or volatile acid, but a slight increase in pH and decrease in total acidity upon irradiation. Changes in spectral absorption were great; absorbance diminished at everymore » wavelength, but not proportionately. All untreated wines showed a maximum at 265 to 85 m mu and a shoulder at about 320 m mu , and the red wines the typical maximum near 520 m mu , which was much decreased by irradiation. The absorbance at 320 m mu was greatly decreased and the shoulder disappeared, leaving only the residual absorption from the more intense but less affected peak at 265 to 85 m mu (absorption at these wavelengths is attributed largely to their content of flavonoid, polyphenolic substances). No appreciable change in the tannin (total polyphenolic) constant was seen, but paper chromatographic studies showed definite qualitative and quantitative changes in polyphenols The oxidation- reduction potential was greatly lowered by irradiation, and volatile substances reacting as aldehydes were produced in considerable amounts, confirming that definite, selective, and specific compositional changes are produced in wine by gamma irradiation at feasible dose levels. With wines flavor-rated by experienced judges with reference to standard wine types, large changes were produced by 500,000 and 1,000,000 rad. Grape aroma rating was significantly decreased in all cases by the higher levels of irradiation. A radiation-induced flavor seemed similar, regardless of the type of wine irradiated. Descriptive terms suggested by the panel for this flavor included cheesy, fishy, perfumy, leathery, sulfurish, fatty, metallic, aged-European-wine-like, whey-like, burned, mushroomy, and fruity. However, comments were favorable on the flavor and odor induced by high levels of radiation by 5 of the 14 panelists. The possibility of favorably influencing the quality of standard types of wine by irradiation near or below 100,000 rad seems worthy of further study, it was concluded. (BBB)« less

The ammonia absorption behavior on Jupiter during 2005-2015

NASA Astrophysics Data System (ADS)

Tejfel, Victor G.; V.G.Tejfel, V.D.Vdovichenko, A.M.Karimov, P.G.Lysenko, , G.A.Kirienko, , V.A.Filippov, G.A.Kharitonova, A.S. Khozhenetz

2017-10-01

V.G.Tejfel, V.D.Vdovichenko, A.M.Karimov, P.G.Lysenko, , G.A.Kirienko, , V.A.Filippov, G.A.Kharitonova, A.S. KhozhenetzFessenkov Astrophysical Institute, Almaty, KazakhstanWe measured the intensity of the 645 and 787 nm NH3 absorption bands in five latitudinal belts of Jupiter (STrZ, SEB, EZ, NEB and NTrZ) during almost full period of its revolution around the Sun: from 2005 to 2015. The variations in the equivalent widths of the bands were investigated. The permanently lowered intensity of the 787 nm NH3 band in NEB is confirmed. There are also some systematic differences in latitudinal and temporal variations between the 645 and 787 nm ammonia bands. The equivalent width of the 787 nm NH3 band was averaged for all years of observations. Its maximum (W = 18.95 ± 0.75 A) corresponds to EZ, its minimum (W = 15.82 ± 0.68 A) corresponds to NEB. The 645 nm NH3 band shows the maximum in SEB (W = 6.78 ± 0.45 A), and the minimum in NTrZ (W = 5.38 ± 0.36 A). The weakened ammonia absorption is also observed in the Great Red Spot. However, this is due to the increased density of the clouds inside the Spot storm, but not to decreased gaseous ammonia abundance, in contrast to NEB. The brightness temperature of GRS in the infrared and millimeter ranges of thermal radiation is lower, in contrast to NEB, where an increased brightness temperature is observed. The enhanced cloud density may explain also a pretty high brightness of GRS observed in strong methane absorption bands such as the 887 nm CH4 band and more long waved ones.

Factors in the intestinal absorption of oral cholecystopaques.

PubMed

Amberg, J R; Thompson, W M; Golberger, L; Williamson, S; Alexander, R; Bates, M

1980-01-01

Interest in the pharmacokinetics of cholecystopaques initially centered on transport from blood to bile. The data obtained in this effort have been valuable and have shown that the maximal iodine concentration achievable in the bile is quite similar for all of the currently available compounds. This concentration is, of course, dose dependent. the transport of contrast material from the bowel to the blood has been shown to be quite variable. Considerable progress was made in understanding this. The tremendous differences in absorption of iopanoic acid depending upon the pH of the administered solution was an initial revelation. The development of the concept that there is a water layer through which the cholecystopaque must pass before reaching the lipid membrane of the intestinal cell has added clarity to understanding the difference in absorption between water-soluble and water-insoluble cholecystopaques. A complete knowledge of what might enhance or inhibit absorption is not known. There is beginning to be an understanding of how intestinal dose relates to plasma levels. This should lead to an optimal dose-timing scheme for each cholecystopaque. The basic assumption is that the highest iodine concentration in the gallbladder leads to the most accurate cholecystography. If this is true, the gallbladder needs to be offered bile at the maximum concentrations during the period preceding filming. To accomplish this, the appropriate plasma level necessary for maximum excretion is needed. Experimental data suggest that our current clinical methods in regard to dose and dose timing need revision to optimize cholecystography. This revision needs to take place with a careful look at toxicity. Accepting the present premise that oral cholecystography can be improved, perhaps without a significant increase in morbidity, a fundamental question to be asked is: is it worth it?

Photophysiological and light absorption properties of phytoplankton communities in the river-dominated margin of the northern Gulf of Mexico

NASA Astrophysics Data System (ADS)

Chakraborty, Sumit; Lohrenz, Steven E.; Gundersen, Kjell

2017-06-01

Spatial and temporal variability in photophysiological properties of phytoplankton were examined in relationship to phytoplankton community composition in the river-dominated continental margin of the northern Gulf of Mexico (NGOM). Observations made during five research cruises in the NGOM included phytoplankton photosynthetic and optical properties and associated environmental conditions and phytoplankton community structure. Distinct patterns of spatial and temporal variability in photophysiological parameters were found for waters dominated by different phytoplankton groups. Photophysiological properties for locations associated with dominance by a particular group of phytoplankton showed evidence of photoacclimation as reflected by differences in light absorption and pigment characteristics in relationship to different light environments. The maximum rate of photosynthesis normalized to chlorophyll (PmaxB) was significantly higher for communities dominated (>60% biomass) by cyanobacteria + prochlorophyte (cyano + prochl). The initial slope of the photosynthesis-irradiance (P-E) curve normalized to chlorophyll (αB) was not clearly related to phytoplankton community structure and no significant differences were found in PmaxB and αB between different geographic regions. In contrast, maximum quantum yield of carbon fixation in photosynthesis (Φcmax) differed significantly between regions and was higher for diatom-dominated communities. Multiple linear regression models, specific for the different phytoplankton communities, using a combination of environmental and bio-optical proxies as predictor variables showed considerable promise for estimation of the photophysiological parameters on a regional scale. Such an approach may be utilized to develop size class-specific or phytoplankton group-specific primary productivity models for the NGOM.