On a common critical state in localized and diffuse failure modes

NASA Astrophysics Data System (ADS)

Zhu, Huaxiang; Nguyen, Hien N. G.; Nicot, François; Darve, Félix

2016-10-01

Accurately modeling the critical state mechanical behavior of granular material largely relies on a better understanding and characterizing the critical state fabric in different failure modes, i.e. localized and diffuse failure modes. In this paper, a mesoscopic scale is introduced, in which the organization of force-transmission paths (force-chains) and cells encompassed by contacts (meso-loops) can be taken into account. Numerical drained biaxial tests using a discrete element method are performed with different initial void ratios, in order to investigate the critical state fabric on the meso-scale in both localized and diffuse failure modes. According to the displacement and strain fields extracted from tests, the failure mode and failure area of each specimen are determined. Then convergent critical state void ratios are observed in failure area of specimens. Different mechanical features of two kinds of meso-structures (force-chains and meso-loops) are investigated, to clarify whether there exists a convergent meso-structure inside the failure area of granular material, as the signature of critical state. Numerical results support a positive answer. Failure area of both localized and diffuse failure modes therefore exhibits the same fabric in critical state. Hence, these two failure modes prove to be homological with respect to the concept of the critical state.

Meso-scale Computational Investigation of Polyurea Microstructure and Its Role in Shockwave Attenuation/dispersion

DTIC Science & Technology

2015-07-01

grained simulations of the formation of meso-segregated microstructure and its interaction with the shockwave is analyzed in the present work. It is...help identify these phenomena and processes, meso-scale coarse-grained simulations of the formation of meso-segregated microstructure and its...of shockwave-induced hard-domain densification. Keywords: Polyurea; Meso-scale; Coarse-grained simulations ; Shockwave attenuation; shockwave

X-ray transparent microfluidic chips for high-throughput screening and optimization of in meso membrane protein crystallization

PubMed Central

Schieferstein, Jeremy M.; Pawate, Ashtamurthy S.; Wan, Frank; Sheraden, Paige N.; Broecker, Jana; Ernst, Oliver P.; Gennis, Robert B.

2017-01-01

Elucidating and clarifying the function of membrane proteins ultimately requires atomic resolution structures as determined most commonly by X-ray crystallography. Many high impact membrane protein structures have resulted from advanced techniques such as in meso crystallization that present technical difficulties for the set-up and scale-out of high-throughput crystallization experiments. In prior work, we designed a novel, low-throughput X-ray transparent microfluidic device that automated the mixing of protein and lipid by diffusion for in meso crystallization trials. Here, we report X-ray transparent microfluidic devices for high-throughput crystallization screening and optimization that overcome the limitations of scale and demonstrate their application to the crystallization of several membrane proteins. Two complementary chips are presented: (1) a high-throughput screening chip to test 192 crystallization conditions in parallel using as little as 8 nl of membrane protein per well and (2) a crystallization optimization chip to rapidly optimize preliminary crystallization hits through fine-gradient re-screening. We screened three membrane proteins for new in meso crystallization conditions, identifying several preliminary hits that we tested for X-ray diffraction quality. Further, we identified and optimized the crystallization condition for a photosynthetic reaction center mutant and solved its structure to a resolution of 3.5 Å. PMID:28469762

Non-contact tensile viscoelastic characterization of microscale biological materials

NASA Astrophysics Data System (ADS)

Li, Yuhui; Hong, Yuan; Xu, Guang-Kui; Liu, Shaobao; Shi, Qiang; Tang, Deding; Yang, Hui; Genin, Guy M.; Lu, Tian Jian; Xu, Feng

2018-06-01

Many structures and materials in nature and physiology have important "meso-scale" structures at the micron length-scale whose tensile responses have proven difficult to characterize mechanically. Although techniques such as atomic force microscopy and micro- and nano-identation are mature for compression and indentation testing at the nano-scale, and standard uniaxial and shear rheometry techniques exist for the macroscale, few techniques are applicable for tensile-testing at the micrometre-scale, leaving a gap in our understanding of hierarchical biomaterials. Here, we present a novel magnetic mechanical testing (MMT) system that enables viscoelastic tensile testing at this critical length scale. The MMT system applies non-contact loading, avoiding gripping and surface interaction effects. We demonstrate application of the MMT system to the first analyses of the pure tensile responses of several native and engineered tissue systems at the mesoscale, showing the broad potential of the system for exploring micro- and meso-scale analysis of structured and hierarchical biological systems.

Non-contact tensile viscoelastic characterization of microscale biological materials

NASA Astrophysics Data System (ADS)

Li, Yuhui; Hong, Yuan; Xu, Guang-Kui; Liu, Shaobao; Shi, Qiang; Tang, Deding; Yang, Hui; Genin, Guy M.; Lu, Tian Jian; Xu, Feng

2018-01-01

Many structures and materials in nature and physiology have important "meso-scale" structures at the micron length-scale whose tensile responses have proven difficult to characterize mechanically. Although techniques such as atomic force microscopy and micro- and nano-identation are mature for compression and indentation testing at the nano-scale, and standard uniaxial and shear rheometry techniques exist for the macroscale, few techniques are applicable for tensile-testing at the micrometre-scale, leaving a gap in our understanding of hierarchical biomaterials. Here, we present a novel magnetic mechanical testing (MMT) system that enables viscoelastic tensile testing at this critical length scale. The MMT system applies non-contact loading, avoiding gripping and surface interaction effects. We demonstrate application of the MMT system to the first analyses of the pure tensile responses of several native and engineered tissue systems at the mesoscale, showing the broad potential of the system for exploring micro- and meso-scale analysis of structured and hierarchical biological systems.

Implications of meso- to micro-scale deformation for fault sealing capacity: Insights from the Lenghu5 fold-and-thrust belt, Qaidam Basin, NE Tibetan Plateau

NASA Astrophysics Data System (ADS)

Xie, Liujuan; Pei, Yangwen; Li, Anren; Wu, Kongyou

2018-06-01

As faults can be barriers to or conduits for fluid flow, it is critical to understand fault seal processes and their effects on the sealing capacity of a fault zone. Apart from the stratigraphic juxtaposition between the hanging wall and footwall, the development of fault rocks is of great importance in changing the sealing capacity of a fault zone. Therefore, field-based structural analysis has been employed to identify the meso-scale and micro-scale deformation features and to understand their effects on modifying the porosity of fault rocks. In this study, the Lenghu5 fold-and-thrust belt (northern Qaidam Basin, NE Tibetan Plateau), with well-exposed outcrops, was selected as an example for meso-scale outcrop mapping and SEM (Scanning Electron Microscope) micro-scale structural analysis. The detailed outcrop maps enabled us to link the samples with meso-scale fault architecture. The representative rock samples, collected in both the fault zones and the undeformed hanging walls/footwalls, were studied by SEM micro-structural analysis to identify the deformation features at the micro-scale and evaluate their influences on the fluid flow properties of the fault rocks. Based on the multi-scale structural analyses, the deformation mechanisms accounting for porosity reduction in the fault rocks have been identified, which are clay smearing, phyllosilicate-framework networking and cataclasis. The sealing capacity is highly dependent on the clay content: high concentrations of clay minerals in fault rocks are likely to form continuous clay smears or micro- clay smears between framework silicates, which can significantly decrease the porosity of the fault rocks. However, there is no direct link between the fault rocks and host rocks. Similar stratigraphic juxtapositions can generate fault rocks with very different magnitudes of porosity reduction. The resultant fault rocks can only be predicted only when the fault throw is smaller than the thickness of a faulted bed, in which scenario self-juxtaposition forms between the hanging wall and footwall.

Onset of meso-scale turbulence in active nematics

NASA Astrophysics Data System (ADS)

Doostmohammadi, Amin; Shendruk, Tyler N.; Thijssen, Kristian; Yeomans, Julia M.

2017-05-01

Meso-scale turbulence is an innate phenomenon, distinct from inertial turbulence, that spontaneously occurs at low Reynolds number in fluidized biological systems. This spatiotemporal disordered flow radically changes nutrient and molecular transport in living fluids and can strongly affect the collective behaviour in prominent biological processes, including biofilm formation, morphogenesis and cancer invasion. Despite its crucial role in such physiological processes, understanding meso-scale turbulence and any relation to classical inertial turbulence remains obscure. Here we show how the motion of active matter along a micro-channel transitions to meso-scale turbulence through the evolution of locally disordered patches (active puffs) from an ordered vortex-lattice flow state. We demonstrate that the stationary critical exponents of this transition to meso-scale turbulence in a channel coincide with the directed percolation universality class. This finding bridges our understanding of the onset of low-Reynolds-number meso-scale turbulence and traditional scale-invariant turbulence in confinement.

Time-resolved Sensing of Meso-scale Shock Compression with Multilayer Photonic Crystal Structures

NASA Astrophysics Data System (ADS)

Scripka, David; Lee, Gyuhyon; Summers, Christopher J.; Thadhani, Naresh

2017-06-01

Multilayer Photonic Crystal structures can provide spatially and temporally resolved data needed to validate theoretical and computational models relevant for understanding shock compression in heterogeneous materials. Two classes of 1-D photonic crystal multilayer structures were studied: optical microcavities (OMC) and distributed Bragg reflectors (DBR). These 0.5 to 5 micron thick structures were composed of SiO2, Al2O3, Ag, and PMMA layers fabricated primarily via e-beam evaporation. The multilayers have unique spectral signatures inherently linked to their time-resolved physical states. By observing shock-induced changes in these signatures, an optically-based pressure sensor was developed. Results to date indicate that both OMCs and DBRs exhibit nanosecond-resolved spectral shifts of several to 10s of nanometers under laser-driven shock compression loads of 0-10 GPa, with the magnitude of the shift strongly correlating to the shock load magnitude. Additionally, spatially and temporally resolved spectral shifts under heterogeneous laser-driven shock compression created by partial beam blocking have been successfully demonstrated. These results illustrate the potential for multilayer structures to serve as meso-scale sensors, capturing temporal and spatial pressure profile evolutions in shock-compressed heterogeneous materials, and revealing meso-scale pressure distributions across a shocked surface. Supported by DTRA Grant HDTRA1-12-1-005 and DoD, AFOSR, National Defense Science and Eng. Graduate Fellowship, 32 CFR 168a.

Shock Wave Propagation in Cementitious Materials at Micro/Meso Scales

NASA Astrophysics Data System (ADS)

Rajendran, Arunachalam

2015-06-01

The mechanical and constitutive response of materials like cement, and bio materials like fish scale and abalone shell is very complex due to heterogeneities that are inherently present in the nano and microstructures. The intrinsic constitutive behaviors are driven by the chemical composition and the molecular, micro, and meso structures. Therefore, it becomes important to identify the material genome as the building block for the material. For instance, in cementitious materials, the genome of C-S-H phase (the glue or the paste) that holds the various clinkers, such as the dicalcium silicate, tricalcium silicate, calcium ferroaluminates, and others is extremely complex. Often mechanical behaviors of C-S-H type materials are influenced by the chemistry and the structures at all nano to micro length scales. By explicitly modeling the molecular structures using appropriate potentials, it is then possible to compute the elastic tensor from molecular dynamics simulations using all atom method. The elastic tensors for the C-S-H gel and other clinkers are determined using the software suite ``Accelrys Materials Studio.'' A strain rate dependent, fracture mechanics based tensile damage model has been incorporated into ABAQUS finite element code to model spall evolution in the heterogeneous cementitious material with all constituents explicitly modeled through one micron element resolution. This paper presents results from nano/micro/meso scale analyses of shock wave propagation in a heterogeneous cementitious material using both molecular dynamic and finite element codes.

Influence of Kuroshio Oceanic Eddies on North Pacific Weather Patterns

NASA Astrophysics Data System (ADS)

Ma, X.; Chang, P.; Saravanan, R.; Montuoro, R.; Hsieh, J. S.; Wu, D.; Lin, X.; Wu, L.; Jing, Z.

2016-02-01

High-resolution satellite observations reveal energetic meso-scale ocean eddy activity and positive correlation between meso-scale sea surface temperature (SST) and surface wind along oceanic frontal zones, such as the Kuroshio and Gulf Stream, suggesting a potential role of meso-scale oceanic eddies in forcing the atmosphere. Using a 27 km horizontal resolution Weather Research Forecasting (WRF) model forced with observed daily SST at 0.09° spatial resolution during boreal winter season, two ensembles of 10 WRF simulations, in one of which meso-scale SST variability induced by ocean eddies was suppressed, were conducted in the North Pacific to study the local and remote influence of meso-scale oceanic eddies in the Kuroshio Extention Region (KER) on the atmosphere. Suppression of meso-scale oceanic eddies results in a deep tropospheric response along and downstream of the KER, including a significant decrease (increase) in winter season mean rainfall along the KER (west coast of US), a reduction of storm genesis in the KER, and a southward shift of the jet stream and North Pacific storm track in the eastern North Pacific. The simulated local and remote rainfall response to meso-scale oceanic eddies in the KER is also supported by observational analysis. A mechanism invoking moist baroclinic instability is proposed as a plausible explanation for the linkage between meso-scale oceanic eddies in the KER and large-scale atmospheric response in the North Pacific. It is argued that meso-scale oceanic eddies can have a rectified effect on planetary boundary layer moisture, the stability of the lower atmosphere and latent heat release, which in turn affect cyclogenesis. The accumulated effect of the altered storm development downstream further contributes to the equivalent barotropic mean flow change in the eastern North Pacific basin.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siranosian, Antranik Antonio; Schembri, Philip Edward; Luscher, Darby Jon

The Los Alamos National Laboratory's Weapon Systems Engineering division's Advanced Engineering Analysis group employs material constitutive models of composites for use in simulations of components and assemblies of interest. Experimental characterization, modeling and prediction of the macro-scale (i.e. continuum) behaviors of these composite materials is generally difficult because they exhibit nonlinear behaviors on the meso- (e.g. micro-) and macro-scales. Furthermore, it can be difficult to measure and model the mechanical responses of the individual constituents and constituent interactions in the composites of interest. Current efforts to model such composite materials rely on semi-empirical models in which meso-scale properties are inferredmore » from continuum level testing and modeling. The proposed approach involves removing the difficulties of interrogating and characterizing micro-scale behaviors by scaling-up the problem to work with macro-scale composites, with the intention of developing testing and modeling capabilities that will be applicable to the mesoscale. This approach assumes that the physical mechanisms governing the responses of the composites on the meso-scale are reproducible on the macro-scale. Working on the macro-scale simplifies the quantification of composite constituents and constituent interactions so that efforts can be focused on developing material models and the testing techniques needed for calibration and validation. Other benefits to working with macro-scale composites include the ability to engineer and manufacture—potentially using additive manufacturing techniques—composites that will support the application of advanced measurement techniques such as digital volume correlation and three-dimensional computed tomography imaging, which would aid in observing and quantifying complex behaviors that are exhibited in the macro-scale composites of interest. Ultimately, the goal of this new approach is to develop a meso-scale composite modeling framework, applicable to many composite materials, and the corresponding macroscale testing and test data interrogation techniques to support model calibration.« less

Transport Structure and Energetic of the North Atlantic Current in Subpolar Gyre from Observations

NASA Astrophysics Data System (ADS)

Houpert, Loïc; Inall, Mark; Dumont, Estelle; Gary, Stefan; Porter, Marie; Johns, William; Cunningham, Stuart

2017-04-01

We present the first 2 years of UK-OSNAP glider missions on the Rockall Plateau in the North Atlantic subpolar gyre. From July 2014 to August 2016, 20 gliders sections were realized along 58°N, between 22°W and 15°W. Depth-averaged currents estimated from gliders show very strong values (up to 45cm.s-1) associated with meso-scale variability, due particularly to eddies and subpolar mode water formation. The variability of the flow on the eastern slope of the Iceland basin and on the Rockall Plateau is presented. Meridional absolute geostrophic transports are calculated from the glider data, and we discuss the vertical structure of the absolute meridional transport, especially the part associated with the North Atlantic Current.

Scaling of water vapor in the meso-gamma (2-20km) and lower meso-beta (20-50km) scales from tall tower time series

NASA Astrophysics Data System (ADS)

Pressel, K. G.; Collins, W.; Desai, A. R.

2011-12-01

Deficiencies in the parameterization of boundary layer clouds in global climate models (GCMs) remains one of the greatest sources of uncertainty in climate change predictions. Many GCM cloud parameterizations, which seek to include some representation of subgrid-scale cloud variability, do so by making assumptions regarding the subgrid-scale spatial probability density function (PDF) of total water content. Properly specifying the form and parameters of the total water PDF is an essential step in the formulation of PDF based cloud parameterizations. In the cloud free boundary layer, the PDF of total water mixing ratio is equivalent to the PDF of water vapor mixing ratio. Understanding the PDF of water vapor mixing ratio in the cloud free atmosphere is a necessary step towards understanding the PDF of water vapor in the cloudy atmosphere. A primary challenge in empirically constraining the PDF of water vapor mixing ratio is a distinct lack of a spatially distributed observational dataset at or near cloud scale. However, at meso-beta (20-50km) and larger scales, there is a wealth of information on the spatial distribution of water vapor contained in the physically retrieved water vapor profiles from the Atmospheric Infrared Sounder onboard NASA`s Aqua satellite. The scaling (scale-invariance) of the observed water vapor field has been suggested as means of using observations at satellite observed (meso-beta) scales to derive information about cloud scale PDFs. However, doing so requires the derivation of a robust climatology of water vapor scaling from in-situ observations across the meso- gamma (2-20km) and meso-beta scales. In this work, we present the results of the scaling of high frequency (10Hz) time series of water vapor mixing ratio as observed from the 447m WLEF tower located near Park Falls, Wisconsin. Observations from a tall tower offer an ideal set of observations with which to investigate scaling at meso-gamma and meso-beta scales requiring only the assumption of Taylor`s Hypothesis to convert observed time scales to spatial scales. Furthermore, the WLEF tower holds an instrument suite offering a diverse set of variables at the 396m, 122m, and 30m levels with which to characterize the state of the boundary layer. Three methods are used to compute scaling exponents for the observed time series; poor man`s variance spectra, first order structure functions, and detrended fluctuation analysis. In each case scaling exponents are computed by linear regression. The results for each method are compared and used to build a climatology of scaling exponents. In particular, the results for June 2007 are presented, and it is shown that the scaling of water vapor time series at the 396m level is characterized by two regimes that are determined by the state of the boundary layer. Finally, the results are compared to, and shown to be roughly consistent with, scaling exponents computed from AIRS observations.

Small-scale and mesoscale lake surface water temperature structure: Thermography and in situ measurements from Lake Geneva, Switzerland

NASA Astrophysics Data System (ADS)

Irani Rahaghi, Abolfazl; Lemmin, Ulrich; Bouffard, Damien; Riffler, Michael; Wunderle, Stefan; Barry, Andrew

2017-04-01

Lake surface water temperature (LSWT), which varies spatially and temporarily, reflects meteorological and climatological forcing more than any other physical lake parameter. There are different data sources for LSWT mapping, including remote sensing and in situ measurements. Depending on cloud cover, satellite data can depict large-scale thermal patterns, but not the meso- or small-scale processes. Meso-scale thermography allows complementing (and hence ground-truth) satellite imagery at the sub-pixel scale. A Balloon Launched Imaging and Monitoring Platform (BLIMP) was used to measure the LSWT at the meso-scale. The BLIMP consists of a small balloon tethered to a boat and is equipped with thermal and RGB cameras, as well as other instrumentation for geo-location and communication. A feature matching-based algorithm was implemented to create composite thermal images. Simultaneous ground-truthing of the BLIMP data were achieved using an autonomous craft measuring among other in situ surface/near surface temperatures, radiation and meteorological data. Latent and sensible surface heat fluxes were calculated using the bulk parameterization algorithm based on similarity theory. Results are presented for the day-time stratified low wind speed (up to 3 ms-1) conditions over Lake Geneva for two field campaigns, each of 6 h on 18 March and 19 July 2016. The meso-scale temperature field ( 1-m pixel resolution) had a range and standard deviation of 2.4°C and 0.3°C, respectively, over a 1-km2 area (typical satellite pixel size). Interestingly, at the sub-pixel scale, various temporal and spatial thermal structures are evident - an obvious example being streaks in the along-wind direction during March, which we hypothesize are caused by the steady 3 h wind condition. The results also show that the spatial variability of the estimated total heat flux is due to the corresponding variability of the longwave cooling from the water surface and the latent heat flux.

ModObs: Atmospheric modelling for wind energy, climate and environment applications: exploring added value from new observation technique. Work in progress within a FP6 Marie Curie Research Training Network

NASA Astrophysics Data System (ADS)

Sempreviva, A. M.

2009-09-01

The EC FP6 Marie Curie Training Network "ModObs” http://www.modobs.windeng.net addresses the improvement of atmospheric boundary layer (ABL) models to investigate the interplay of processes at different temporal and spatial scales, and to explore the added value from new observation techniques. The overall goal is to bring young scientists to work ogether with experienced researchers in developing a better interaction amongst scientific communities of modelers and experimentalists, using a comprehensive approach to "Climate Change”, "Clean Energy assessment” and "Environmental Policies”, issues. This poster describes the work in progress of ten students, funded by the network, under the supervision of a team of scientists within atmospheric physics, engineering and satellite remote sensing and end-users such as companies in the private sector, all with the appropriate expertise to integrate the most advanced research methods and techniques in the following topics. MODELING: GLOBAL-TO-MESO SCALE: Analytical and process oriented numerical models will be used to study the interaction between the atmosphere and the ocean on a regional scale. Initial results indicate an interaction between the intensity of polar lows and the subsurface warm core often present in the Nordic Seas (11). The presence of waves, mainly swell, influence the MABL fluxes and turbulence structure. The regional and global wave effect on the atmosphere will be also studied and quantified (7) MESO-SCALE: Applicability of the planetary boundary layer (PBL) parametrizations in the meso-scale WRF model to marine atmospheric boundary layer (MABL) over the North Sea is investigated. The most suitable existing PBL parametrization will be additionally improved and used for downscaling North Sea past and future climates (2). Application of the meso-scale model (MM5 and WRF) for the wind energy in off-shore and coastal area. Set-up of the meso-scale model, post-processing and verification of the data from the long simulation. Research of meso-scale phenomena for meteorological case study in Gulf of Finland (3). MICRO-SCALE: Large eddy simulation (LES) is used to study the planetary boundary layer under different complex effects: (a) Forcing from general circulation model (GCM): Comparison between GCM outputs and GCM-forced LES for maritime boundary layer (MBL) cases, namely the LASIE campaign (5). (b) Heterogeneity of the Marine Surface Layer (MSL ): Investigation of the air-sea turbulent exchange mechanisms under the effects of coastal discontinuity and horizontal gradient of temperature (1)(6). (c) Heterogeneity of land surface: Turbulence self-organization and its interaction with complex earth topography is studied (8). (d) Wind farm complexity: Wind site assessment as well as turbulent effects for terrains with different complexity are studied (2). OBSERVATIONS: CONTRIBUTION OF SATELLITE OBSERVATIONS FOR THE STUDY AND PARAMETRIZATION OF MARINE BOUNDARY LAYER: Evaluate the added-value of observations from the current generation of satellite with emphasis on the potential of remote sensing data in describing temporal and spatial structures. Foreseen applications include: improvement of MBL description on coastal areas, identification of areas of interest for wind energy applications, gain of information of temporal and spatial scales of variability useful for numerical model parameterizations (6). LIDAR, SODAR: REMOTE SENSING TECHNIQUES APPLIED FOR WIND ENERGY. According to aeroelastic simulations, the production of the power curve of a large wind turbine (rotor diameter larger than 100m) requires wind speed measurements at several heights within the rotor disc. Suitable wind profiles can be measured by LiDARs and SoDARs (1). EVOLUTION OF THE VERTICAL STRUCTURE OF THE ATMOSPHERIC MARINE BOUNDARY LAYER:The evolution of the vertical structure of the MABL following the change of surface conditions in a sequence of onshore - offshore - onshore flow, was observed by both ceilometer and radiosoundings during the LASIE (Ligurian Air-Sea Interaction Experiment) campaign sponsored by NATO in the Mediterranean Sea. In-situ and remote-sensing measurements were performed from two measuring platforms, A buoy ODAS, Italia1 and a ship N/O URANIA from the Italian National Council of Research CNR (1), (6) and (7).

ModObs: Atmospheric modelling for wind energy, climate and environment applications : exploring added value from new observation technique

NASA Astrophysics Data System (ADS)

Sempreviva, A. M.

2009-04-01

The EC FP6 Marie Curie Training Network "ModObs" http://www.modobs.windeng.net addresses the improvement of atmospheric boundary layer (ABL) models to investigate the interplay of processes at different temporal and spatial scales, and to explore the added value from new observation techniques. The overall goal is to bring young scientists to work together with experienced researchers in developing a better interaction amongst scientific communities of modelers and experimentalists, using a comprehensive approach to "Climate Change", "Clean Energy assessment" and "Environmental Policies", issues. This poster describes the work in progress of ten students, funded by the network, under the supervision of a team of scientists within atmospheric physics, engineering and satellite remote sensing and end-users such as companies in the private sector, all with the appropriate expertise to integrate the most advanced research methods and techniques in the following topics. MODELING: GLOBAL-TO-MESO SCALE: Analytical and process oriented numerical models will be used to study the interaction between the atmosphere and the ocean on a regional scale. Initial results indicate an interaction between the intensity of polar lows and the subsurface warm core often present in the Nordic Seas (11). The presence of waves, mainly swell, influence the MABL fluxes and turbulence structure. The regional and global wave effect on the atmosphere will be also studied and quantified (7) MESO-SCALE: Applicability of the planetary boundary layer (PBL) parametrizations in the meso-scale WRF model to marine atmospheric boundary layer (MABL) over the North Sea is investigated. The most suitable existing PBL parametrization will be additionally improved and used for downscaling North Sea past and future climates (2). Application of the meso-scale model (MM5 and WRF) for the wind energy in off-shore and coastal area. Set-up of the meso-scale model, post-processing and verification of the data from the long simulation. Research of meso-scale phenomena for meteorological case study in Gulf of Finland (3). MICRO-SCALE: Large eddy simulation (LES) is used to study the planetary boundary layer under different complex effects: (a) Forcing from general circulation model (GCM): Comparison between GCM outputs and GCM-forced LES for maritime boundary layer (MBL) cases, namely the LASIE campaign (5). (b) Heterogeneity of the Marine Surface Layer (MSL ): Investigation of the air-sea turbulent exchange mechanisms under the effects of coastal discontinuity and horizontal gradient of temperature (1)(6). (c) Heterogeneity of land surface: Turbulence self-organization and its interaction with complex earth topography is studied (8). (d) Wind farm complexity: Wind site assessment as well as turbulent effects for terrains with different complexity are studied (2). OBSERVATIONS: CONTRIBUTION OF SATELLITE OBSERVATIONS FOR THE STUDY AND PARAMETRIZATION OF MARINE BOUNDARY LAYER: Evaluate the added-value of observations from the current generation of satellite with emphasis on the potential of remote sensing data in describing temporal and spatial structures. Foreseen applications include: improvement of MBL description on coastal areas, identification of areas of interest for wind energy applications, gain of information of temporal and spatial scales of variability useful for numerical model parameterizations (6). LIDAR, SODAR: REMOTE SENSING TECHNIQUES APPLIED FOR WIND ENERGY. According to aeroelastic simulations, the production of the power curve of a large wind turbine (rotor diameter larger than 100m) requires wind speed measurements at several heights within the rotor disc. Suitable wind profiles can be measured by LiDARs and SoDARs (1). EVOLUTION OF THE VERTICAL STRUCTURE OF THE ATMOSPHERIC MARINE BOUNDARY LAYER:The evolution of the vertical structure of the MABL following the change of surface conditions in a sequence of onshore - offshore - onshore flow, was observed by both ceilometer and radiosoundings during the LASIE (Ligurian Air-Sea Interaction Experiment) campaign sponsored by NATO in the Mediterranean Sea. In-situ and remote-sensing measurements were performed from two measuring platforms, A buoy ODAS, Italia1 and a ship N/O URANIA from the Italian National Council of Research CNR (1), (6) and (7).

Fabrication of meso- and nano-scale structures on surfaces of chalcogenide semiconductors by surface hydrodynamic interference patterning

NASA Astrophysics Data System (ADS)

Bilanych, V.; Komanicky, V.; Lacková, M.; Feher, A.; Kuzma, V.; Rizak, V.

2015-10-01

We observe the change of surface relief on amorphous Ge-As-Se thin films after irradiation with an electron beam. The beam softens the glass and induces various topological surface changes in the irradiated area. The film relief change depends on the film thickness, deposited charge, and film composition. Various structures are formed: Gausian-like cones, extremely sharp Taylor cones, deep craters, and craters with large spires grown on the side. Our investigation shows that these effects can be at least partially a result of electro-hydrodynamic material flow, but the observed phenomena are likely more complex. When we irradiated structural patterns formed by the electron beam with a red laser beam, we could not only fully relax the produced patterns, but also form very complex and intricate superstructures. These organized meso- and nano-scale structures are formed by a combination of photo-induced structural relaxation, light interference on structures fabricated by the e-beam, and photo-induced material flow.

Multi-scale habitat selection of the endangered Hawaiian Goose

USGS Publications Warehouse

Leopold, Christina R.; Hess, Steven C.

2013-01-01

After a severe population reduction during the mid-20th century, the endangered Hawaiian Goose (Branta sandvicensis), or Nēnē, has only recently re-established its seasonal movement patterns on Hawai‘i Island. Little is currently understood about its movements and habitat use during the nonbreeding season. The objectives of this research were to identify habitats preferred by two subpopulations of the Nēnē and how preferences shift seasonally at both meso-and fine scales. From 2009 to 2011, ten Nēnē ganders were outfitted with 40-to 45-g satellite transmitters with GPS capability. We used binary logistic regression to compare habitat use versus availability and an information-theoretic approach for model selection. Meso-scale habitat modeling revealed that Nēnē preferred exotic grass and human-modified landscapes during the breeding and molting seasons and native subalpine shrubland during the nonbreeding season. Fine-scale habitat modeling further indicated preference for exotic grass, bunch grass, and absence of trees. Proximity to water was important during molt, suggesting that the presence of water may provide escape from introduced mammalian predators while Nēnē are flightless. Finescale species-composition data added relatively little to understanding of Nēnē habitat preferences modeled at the meso scale, suggesting that the meso-scale is appropriate for management planning. Habitat selection during our study was consistent with historical records, although dissimilar from more recent studies of other subpopulations. Nēnē make pronounced seasonal movements between existing reserves and use distinct habitat types; understanding annual patterns has implications for the protection and restoration of important seasonal habitats.

Active Salt/Silica-Templated 2D Mesoporous FeCo-Nx -Carbon as Bifunctional Oxygen Electrodes for Zinc-Air Batteries.

PubMed

Li, Shuang; Cheng, Chong; Zhao, Xiaojia; Schmidt, Johannes; Thomas, Arne

2018-02-12

Two types of templates, an active metal salt and silica nanoparticles, are used concurrently to achieve the facile synthesis of hierarchical meso/microporous FeCo-N x -carbon nanosheets (meso/micro-FeCo-N x -CN) with highly dispersed metal sites. The resulting meso/micro-FeCo-N x -CN shows high and reversible oxygen electrocatalytic performances for both ORR and OER, thus having potential for applications in rechargeable Zn-air battery. Our approach creates a new pathway to fabricate 2D meso/microporous structured carbon architectures for bifunctional oxygen electrodes in rechargeable Zn-air battery as well as opens avenues to the scale-up production of rationally designed heteroatom-doped catalytic materials for a broad range of applications. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Exploring image data assimilation in the prospect of high-resolution satellite oceanic observations

NASA Astrophysics Data System (ADS)

Durán Moro, Marina; Brankart, Jean-Michel; Brasseur, Pierre; Verron, Jacques

2017-07-01

Satellite sensors increasingly provide high-resolution (HR) observations of the ocean. They supply observations of sea surface height (SSH) and of tracers of the dynamics such as sea surface salinity (SSS) and sea surface temperature (SST). In particular, the Surface Water Ocean Topography (SWOT) mission will provide measurements of the surface ocean topography at very high-resolution (HR) delivering unprecedented information on the meso-scale and submeso-scale dynamics. This study investigates the feasibility to use these measurements to reconstruct meso-scale features simulated by numerical models, in particular on the vertical dimension. A methodology to reconstruct three-dimensional (3D) multivariate meso-scale scenes is developed by using a HR numerical model of the Solomon Sea region. An inverse problem is defined in the framework of a twin experiment where synthetic observations are used. A true state is chosen among the 3D multivariate states which is considered as a reference state. In order to correct a first guess of this true state, a two-step analysis is carried out. A probability distribution of the first guess is defined and updated at each step of the analysis: (i) the first step applies the analysis scheme of a reduced-order Kalman filter to update the first guess probability distribution using SSH observation; (ii) the second step minimizes a cost function using observations of HR image structure and a new probability distribution is estimated. The analysis is extended to the vertical dimension using 3D multivariate empirical orthogonal functions (EOFs) and the probabilistic approach allows the update of the probability distribution through the two-step analysis. Experiments show that the proposed technique succeeds in correcting a multivariate state using meso-scale and submeso-scale information contained in HR SSH and image structure observations. It also demonstrates how the surface information can be used to reconstruct the ocean state below the surface.

Micro-scale and meso-scale architectural cues cooperate and compete to direct aligned tissue formation

PubMed Central

Gilchrist, Christopher L.; Ruch, David S.; Little, Dianne; Guilak, Farshid

2014-01-01

Tissue and biomaterial microenvironments provide architectural cues that direct important cell behaviors including cell shape, alignment, migration, and resulting tissue formation. These architectural features may be presented to cells across multiple length scales, from nanometers to millimeters in size. In this study, we examined how architectural cues at two distinctly different length scales, “micro-scale” cues on the order of ~1–2 μm, and “meso-scale” cues several orders of magnitude larger (>100 μm), interact to direct aligned neo-tissue formation. Utilizing a micro-photopatterning (μPP) model system to precisely arrange cell-adhesive patterns, we examined the effects of substrate architecture at these length scales on human mesenchymal stem cell (hMSC) organization, gene expression, and fibrillar collagen deposition. Both micro- and meso-scale architectures directed cell alignment and resulting tissue organization, and when combined, meso cues could enhance or compete against micro-scale cues. As meso boundary aspect ratios were increased, meso-scale cues overrode micro-scale cues and controlled tissue alignment, with a characteristic critical width (~500 μm) similar to boundary dimensions that exist in vivo in highly aligned tissues. Meso-scale cues acted via both lateral confinement (in a cell-density-dependent manner) and by permitting end-to-end cell arrangements that yielded greater fibrillar collagen deposition. Despite large differences in fibrillar collagen content and organization between μPP architectural conditions, these changes did not correspond with changes in gene expression of key matrix or tendon-related genes. These findings highlight the complex interplay between geometric cues at multiple length scales and may have implications for tissue engineering strategies, where scaffold designs that incorporate cues at multiple length scales could improve neo-tissue organization and resulting functional outcomes. PMID:25263687

Linking composition of extracellular polymeric substances (EPS) to the physical structure and hydraulic resistance of membrane biofilms.

PubMed

Desmond, Peter; Best, James P; Morgenroth, Eberhard; Derlon, Nicolas

2018-04-01

The effect of extracellular polymeric substances (EPS) on the meso-scale physical structure and hydraulic resistance of membrane biofilms during gravity driven membrane (GDM) filtration was investigated. Biofilms were developed on the surface of ultrafiltration membranes during dead-end filtration at ultra-low pressure (70 mbar). Biofilm EPS composition (total protein, polysaccharide and eDNA) was manipulated by growing biofilms under contrasting nutrient conditions. Nutrient conditions consisted of (i) a nutrient enriched condition with a nutrient ratio of 100:30:10 (C: N: P), (ii) a phosphorus limitation (C: N: P ratio: 100:30:0), and (iii) a nitrogen limitation (C: N: P ratio: 100:0:10). The structure of the biofilm was characterised at meso-scale using Optical Coherence Tomography (OCT). Biofilm composition was analysed with respect to total organic carbon, total cellular mass and extracellular concentrations of proteins, polysaccharides, and eDNA. 2D-confocal Raman mapping was used to characterise the functional group composition and micro-scale distribution of the biofilms EPS. Our study reveals that the composition of the EPS matrix can determine the meso-scale physical structure of membrane biofilms and in turn its hydraulic resistance. Biofilms grown under P limiting conditions were characterised by dense and homogeneous physical structures with high concentrations of polysaccharides and eDNA. Biofilm grown under nutrient enriched or N limiting conditions were characterised by heterogeneous physical structures with lower concentrations of polysaccharides and eDNA. For P limiting biofilms, 2D-confocal Raman microscopy revealed a homogeneous spatial distribution of anionic functional groups in homogeneous biofilm structures with higher polysaccharide and eDNA concentrations. This study links EPS composition, physical structure and hydraulic resistance of membrane biofilms, with practical relevance for the hydraulic performances of GDM ultrafiltration. Copyright © 2018 Elsevier Ltd. All rights reserved.

Mesos-scale modeling of irradiation in pressurized water reactor concrete biological shields

DOE Office of Scientific and Technical Information (OSTI.GOV)

Le Pape, Yann; Huang, Hai

Neutron irradiation exposure causes aggregate expansion, namely radiation-induced volumetric expansion (RIVE). The structural significance of RIVE on a portion of a prototypical pressurized water reactor (PWR) concrete biological shield (CBS) is investigated by using a meso- scale nonlinear concrete model with inputs from an irradiation transport code and a coupled moisture transport-heat transfer code. RIVE-induced severe cracking onset appears to be triggered by the ini- tial shrinkage-induced cracking and propagates to a depth of > 10 cm at extended operation of 80 years. Relaxation of the cement paste stresses results in delaying the crack propagation by about 10 years.

Insight into Evolution, Processing and Performance of Multi-length-scale Structures in Planar Heterojunction Perovskite Solar Cells.

PubMed

Huang, Yu-Ching; Tsao, Cheng-Si; Cho, Yi-Ju; Chen, Kuan-Chen; Chiang, Kai-Ming; Hsiao, Sheng-Yi; Chen, Chang-Wen; Su, Chun-Jen; Jeng, U-Ser; Lin, Hao-Wu

2015-09-04

The structural characterization correlated to the processing control of hierarchical structure of planar heterojunction perovskite layer is still incomplete due to the limitations of conventional microscopy and X-ray diffraction. This present study performed the simultaneously grazing-incidence small-angle scattering and wide-angle scattering (GISAXS/GIWAXS) techniques to quantitatively probe the hierarchical structure of the planar heterojunction perovskite solar cells. The result is complementary to the currently microscopic study. Correlation between the crystallization behavior, crystal orientation, nano- and meso-scale internal structure and surface morphology of perovskite film as functions of various processing control parameters is reported for the first time. The structural transition from the fractal pore network to the surface fractal can be tuned by the chloride percentage. The GISAXS/GIWAXS measurement provides the comprehensive understanding of concurrent evolution of the film morphology and crystallization correlated to the high performance. The result can provide the insight into formation mechanism and rational synthesis design.

Insight into Evolution, Processing and Performance of Multi-length-scale Structures in Planar Heterojunction Perovskite Solar Cells

NASA Astrophysics Data System (ADS)

Huang, Yu-Ching; Tsao, Cheng-Si; Cho, Yi-Ju; Chen, Kuan-Chen; Chiang, Kai-Ming; Hsiao, Sheng-Yi; Chen, Chang-Wen; Su, Chun-Jen; Jeng, U.-Ser; Lin, Hao-Wu

2015-09-01

The structural characterization correlated to the processing control of hierarchical structure of planar heterojunction perovskite layer is still incomplete due to the limitations of conventional microscopy and X-ray diffraction. This present study performed the simultaneously grazing-incidence small-angle scattering and wide-angle scattering (GISAXS/GIWAXS) techniques to quantitatively probe the hierarchical structure of the planar heterojunction perovskite solar cells. The result is complementary to the currently microscopic study. Correlation between the crystallization behavior, crystal orientation, nano- and meso-scale internal structure and surface morphology of perovskite film as functions of various processing control parameters is reported for the first time. The structural transition from the fractal pore network to the surface fractal can be tuned by the chloride percentage. The GISAXS/GIWAXS measurement provides the comprehensive understanding of concurrent evolution of the film morphology and crystallization correlated to the high performance. The result can provide the insight into formation mechanism and rational synthesis design.

Driving of Dramatic Geomagnetic Activity by Enhancement of Meso-Scale Polar-cap Flows

NASA Astrophysics Data System (ADS)

Lyons, L. R.; Gallardo-Lacourt, B.; Zou, Y.; Nishimura, Y.; Anderson, P. C.; Angelopoulos, V.; Ruohoniemi, J. M.; Mitchell, E. J.; Paxton, L. J.; Nishitani, N.

2017-12-01

Recent studies have shown that mesoscale flows are common within the polar cap ionosphere. They often cross the magnetic separatrix, and become are critical to the driving of geomagnetic activity. They lead, for example, to plasma sheet flow bursts, auroral poleward boundary intensifications, auroral streamers, substorms, auroral omega bands, and poleward motion of the polar cap boundary from reconnection. We have found large enhancements of these meso-scale ionospheric polar cap flows heading towards the nightside separatrix. These enhancements are common immediately after the impact of CME shocks under southward IMF, but can also occur in other situations, including without substantial change in the solar wind or IMF. These meso-scale flow enhancements, which must extent outward along magnetospheric field lines from the ionosphere, are seen to drive an almost immediate strong auroral, ionospheric and field-aligned current, and reconnection activity. The resulting activity is particularly dramatic during the initiation of CME storms, but may reflect a more generally occurring phenomenon of mesoscale flow enhancements leading to similar oval responses without a shock impact, including during and following the expansion phase some substorms. If this phenomenon is indeed common, it could lead to possibly fundamental questions, such as when do polar cap convection enhancements lead to a substorm growth phase versus leading directly to strong poleward expansion of, and strong activity within, the auroral oval field line region? Another critical question would be what leads to and causes the enhancements in meso-scale polar cap flows?

Electrical Characteristics, Electrode Sheath and Contamination Layer Behavior of a Meso-Scale Premixed Methane-Air Flame Under AC/DC Electric Fields

NASA Astrophysics Data System (ADS)

Chen, Qi; Yan, Limin; Zhang, Hao; Li, Guoxiu

2016-05-01

Electrical characteristics of a nozzle-attached meso-scale premixed methane-air flame under low-frequency AC (0-4300 V, 0-500 Hz) and DC (0-3300 V) electric fields were studied. I-V curves were measured under different experimental conditions to estimate the magnitude of the total current 100-102 μA, the electron density 1015-1016 m-3 and further the power dissipation ≤ 0.7 W in the reaction zone. At the same time, the meso-scale premixed flame conductivity 10-4-10-3 Ω-1·m-1 as a function of voltage and frequency was experimentally obtained and was believed to represent a useful order-of magnitude estimate. Moreover, the influence of the collision sheath relating to Debye length (31-98 μm) and the contamination layer of an active electrode on measurements was discussed, based on the combination of simulation and theoretical analysis. As a result, the electrode sheath dimension was evaluated to less than 0.5 mm, which indicated a complex effect of the collision sheath on the current measurements. The surface contamination effect of an active electrode was further analyzed using the SEM imaging method, which showed elements immigration during the contamination layer formation process. supported by National Natural Science Foundation of China (No. 51376021), and the Fundamental Research Fund for Major Universities (No. 2013JBM079)

Wavelet-based multiscale window transform and energy and vorticity analysis

NASA Astrophysics Data System (ADS)

Liang, Xiang San

A new methodology, Multiscale Energy and Vorticity Analysis (MS-EVA), is developed to investigate sub-mesoscale, meso-scale, and large-scale dynamical interactions in geophysical fluid flows which are intermittent in space and time. The development begins with the construction of a wavelet-based functional analysis tool, the multiscale window transform (MWT), which is local, orthonormal, self-similar, and windowed on scale. The MWT is first built over the real line then modified onto a finite domain. Properties are explored, the most important one being the property of marginalization which brings together a quadratic quantity in physical space with its phase space representation. Based on MWT the MS-EVA is developed. Energy and enstrophy equations for the large-, meso-, and sub-meso-scale windows are derived and their terms interpreted. The processes thus represented are classified into four categories: transport; transfer, conversion, and dissipation/diffusion. The separation of transport from transfer is made possible with the introduction of the concept of perfect transfer. By the property of marginalization, the classical energetic analysis proves to be a particular case of the MS-EVA. The MS-EVA developed is validated with classical instability problems. The validation is carried out through two steps. First, it is established that the barotropic and baroclinic instabilities are indicated by the spatial averages of certain transfer term interaction analyses. Then calculations of these indicators are made with an Eady model and a Kuo model. The results agree precisely with what is expected from their analytical solutions, and the energetics reproduced reveal a consistent and important aspect of the unknown dynamic structures of instability processes. As an application, the MS-EVA is used to investigate the Iceland-Faeroe frontal (IFF) variability. A MS-EVA-ready dataset is first generated, through a forecasting study with the Harvard Ocean Prediction System using the data gathered during the 1993 NRV Alliance cruise. The application starts with a determination of the scale window bounds, which characterize a double-peak structure in either the time wavelet spectrum or the space wavelet spectrum. The resulting energetics, when locally averaged, reveal that there is a clear baroclinic instability happening around the cold tongue intrusion observed in the forecast. Moreover, an interaction analysis shows that the energy released by the instability indeed goes to the meso-scale window and fuel the growth of the intrusion. The sensitivity study shows that, in this case, the key to a successful application is a correct decomposition of the large-scale window from the meso-scale window.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Du, Jincheng; Rimsza, Jessica

Computational simulations at the atomistic level play an increasing important role in understanding the structures, behaviors, and the structure-property relationships of glass and amorphous materials. In this paper, we reviewed atomistic simulation methods ranging from first principles calculations and ab initio molecular dynamics (AIMD), to classical molecular dynamics (MD) and meso-scale kinetic Monte Carlo (KMC) simulations and their applications to glass-water interactions and glass dissolutions. Particularly, the use of these simulation methods in understanding the reaction mechanisms of water with oxide glasses, water-glass interfaces, hydrated porous silica gels formation, the structure and properties of multicomponent glasses, and microstructure evolution aremore » reviewed. Here, the advantages and disadvantageous of these methods are discussed and the current challenges and future direction of atomistic simulations in glass dissolution are presented.« less

Meso-scopic Densification in Brittle Granular Materials

NASA Astrophysics Data System (ADS)

Neal, William; Appleby-Thomas, Gareth; Collins, Gareth

2013-06-01

Particulate materials are ideally suited to shock absorbing applications due to the large amounts of energy required to deform their inherently complex meso-structure. Significant effort is being made to improve macro-scale material models to represent these atypical materials. On the long road towards achieving this capability, an important milestone would be to understand how particle densification mechanisms are affected by loading rate. In brittle particulate materials, the majority of densification is caused by particle fracture. Macro-scale quasi-static and dynamic compaction curves have been measured that show good qualitative agreement. There are, however, some differences that appear to be dependent on the loading rate that require further investigation. This study aims to investigate the difference in grain-fracture behavior between the quasi-static and shock loading response of brittle glass microsphere beds using a combination of quasi-static and dynamic loading techniques. Results from pressure-density measurements, sample recovery, and meso-scale hydrocode models (iSALE, an in-house simulation package) are discussed to explain the differences in particle densification mechanisms between the two loading rate regimes. Gratefully funded by AWE.plc.

Evaluation of WRF Model Against Satellite and Field Measurements During ARM March 2000 IOP

NASA Astrophysics Data System (ADS)

Wu, J.; Zhang, M.

2003-12-01

Meso-scale WRF model is employed to simulate the organization of clouds related with the cyclogenesis occurred during March 1-4, 2000 over ARM SGP CART site. Qualitative comparisons of simulated clouds with GOES8 satellite images show that the WRF model can capture the main features of clouds related with the cyclogenesis. The simulated precipitation patterns also match the Radar reflectivity images well. Further evaluation of the simulated features on GCM grid-scale is conducted against ARM field measurements. The evaluation shows that the evolutions of the simulated state fields such as temperature and moisture, the simulated wind fields and the derived large-scale temperature and moisture tendencies closely follow the observed patterns. These results encourages us to use meso-scale WRF model as a tool to verify the performance of GCMs in simulating cloud feedback processes related with the frontal clouds such that we can test and validate the current cloud parameterizations in climate models, and make possible improvements to different components of current cloud parameterizations in GCMs.

Isolating causal pathways between flow and fish in the regulated river hierarchy

Treesearch

Ryan McManamay; Donald J. Orth; Charles A. Dolloff; David C. Mathews

2015-01-01

Unregulated river systems are organized in a hierarchy in which large scale factors (i.e. landscape and segment scales) influence local habitats (i.e. reach, meso- and microhabitat scales), and both differentially exert selective pressures on biota. Dams, however, create discontinua in these processes and change the hierarchical structure. We examined the relative...

An investigation of relationships between meso- and synoptic-scale phenomena

NASA Technical Reports Server (NTRS)

Scoggins, J. R.; Wood, J. E.; Fuelberg, H. E.; Read, W. L.

1972-01-01

Methods based on the vorticity equation, the adiabatic method, the curvature of the vertical wind profile, and the structure of synoptic waves are used to determine areas of positive vertical motion in the mid-troposphere for a period in each season. Parameters indicative of low-level moisture and conditional instability are areas in which mesoscale systems may be present. The best association between mesoscale and synoptic-scale phenomena was found for a period during December when synoptic-scale systems were well developed. A good association between meso- and synoptic-scale events also was found for a period during March, while the poorest association was found for a June period. Daytime surface heating apparently is an important factor in the formation of mesoscale systems during the summer. It is concluded that the formation of mesoscale phenomena may be determined essentially from synoptic-scale conditions during winter, late fall, and early spring.

The paradox of vertical σ2 in foreland fold and thrust belts

NASA Astrophysics Data System (ADS)

Tavani, Stefano

2014-05-01

Occurrence of aesthetically appealing thrust systems and associated large scale anticlines, in both active and fossil foreland fold and thrust belts, is commonly interpreted as an evidence for Andersonian compressional framework. Indeed, these structures would testify for a roughly vertical σ3. Such a correlation between thrusts occurrence and stress field orientation, however, frequently fails to explain denser observations at a smaller scale. The syn-orogenic deformation meso-structures hosted in exposed km-scale thrust-related folds, in fact, frequently and paradoxically witness for a syn-thrusting strike-slip stress configuration, with a near-vertical σ2 and a sub-horizontal σ3. This apparent widespread inconsistency between syn-orogenic meso-structures and stress field orientation is here named "the σ2 paradox". A possible explanation for such a paradox is provided by inherited extensional deformation structures commonly developed prior to thrusting, in the flexural foreland basins located ahead of fold and thrust belts. Thrust nucleation and propagation is facilitated and driven by the positive inversion of the extensional inheritances, and their subsequent linkage. This process eventually leads to the development of large reverse fault zones and can occur both in compressive and strike-slip stress configurations.

An Israeli haboob: Sea breeze activating local anthropogenic dust sources in the Negev loess

NASA Astrophysics Data System (ADS)

Crouvi, Onn; Dayan, Uri; Amit, Rivka; Enzel, Yehouda

2017-02-01

Meso-scale weather systems, such as convective haboobs, are considered to be an important dust generation mechanism. In Israel, however, rather than of meso-scale weather systems, most dust storms are generated by synoptic-scale systems, originating from Sahara and Arabia. Consequently, only distal sources of suspended and deposited dust in Israel are currently reported. Here we report the first detailed study on the merging of synoptic- and meso-scale weather systems leading to a prominent dust outbreak over the Negev, Israel. During the afternoon of May 2nd, 2007, a massive dust storm covered the northern Negev, forming a one kilometer high wall of dust. The haboob was associated with PM10 concentrations of 1000-1500 μg m-3 that advanced at a speed of 10-15 m s-1 and caused temporary closure of local airports. In contrast to most reported haboobs, this one was generated by a sea breeze front acting as a weak cold front enhanced by a cold core cyclone positioned over Libya and Egypt. The sea breeze that brought cold and moist marine air acted as a gravity current with strong surface winds. The sources for the haboob were the loessial soils of the northwestern Negev, especially agricultural fields that were highly disturbed in late spring to early summer. Such surface disturbance is caused by agricultural and/or intensive grazing practices. Our study emphasizes the importance of local dust sources in the Negev and stresses loess recycling as an important process in contemporary dust storms over Israel.

Dominance of debonding defect of CFST on PZT sensor response considering the meso-scale structure of concrete with multi-scale simulation

NASA Astrophysics Data System (ADS)

Xu, Bin; Chen, Hongbing; Mo, Y.-L.; Zhou, Tianmin

2018-07-01

Piezoelectric-lead-zirconate-titanate(PZT)-based interface debonding defects detection for concrete filled steel tubulars (CFSTs) has been proposed and validated through experiments, and numerical study on its mechanism has been carried out recently by assuming that concrete material is homogenous. However, concrete is composed of coarse and fine aggregates, mortar and interface transition zones (ITZs) and even initial defects and is a typical nonhomogeneous material and its mesoscale structure might affect the wave propagation in the concrete core of CFST members. Therefore, it is significantly important to further investigate the influence of mesoscale structure of concrete on the stress wave propagation and the response of embedded PZT sensor for the interface debonding detection. In this study, multi-physical numerical simulation on the wave propagation and embedded PZT sensor response of rectangular CFST members with numerical concrete core considering the randomness in circular aggregate distribution, and coupled with surface-mounted PZT actuator and embedded PZT sensor is carried out. The effect of randomness in the circular aggregates distribution and the existence of ITZs are discussed. Both a local stress wave propagation behavior including transmission, reflection, and diffraction at the interface between concrete core and steel tube under a pulse signal excitation and a global wave field in the cross-section of the rectangular CFST models without and with interface debonding defects under sweep frequency excitation are simulated. The sensitivity of an evaluation index based on wavelet packet analysis on the embedded PZT sensor response on the variation of mesoscale parameters of concrete core without and with different interface debonding defects under sweep frequency voltage signal is investigated in details. The results show that the effect of the interface debondings on the embedded PZT measurement is dominant when compared to the meso-scale structures of concrete core. This study verified the feasibility of the PZT based debonding detection for rectangular CFST members even the meso-scale structure of concrete core is considered.

Micro- and meso-scale pore structure in mortar in relation to aggregate content

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gao, Yun, E-mail: yun.gao@ugent.be; De Schutter, Geert; Ye, Guang

2013-10-15

Mortar is often viewed as a three-phase composite consisting of aggregate, bulk paste, and an interfacial transition zone (ITZ). However, this description is inconsistent with experimental findings because of the basic assumption that larger pores are only present within the ITZ. In this paper, we use backscattered electron (BSE) imaging to investigate the micro- and meso-scale structure of mortar with varying aggregate content. The results indicate that larger pores are present not only within the ITZ but also within areas far from aggregates. This phenomenon is discussed in detail based on a series of analytical calculations, such as the effectivemore » water binder ratio and the inter-aggregate spacing. We developed a modified computer model that includes a two-phase structure for bulk paste. This model interprets previous mercury intrusion porosimetry data very well. -- Highlights: •Based on BSE, we examine the HCSS model. •We develop the HCSS-DBLB model. •We use the modified model to interpret the MIP data.« less

Core-periphery structure requires something else in the network

NASA Astrophysics Data System (ADS)

Kojaku, Sadamori; Masuda, Naoki

2018-04-01

A network with core-periphery structure consists of core nodes that are densely interconnected. In contrast to a community structure, which is a different meso-scale structure of networks, core nodes can be connected to peripheral nodes and peripheral nodes are not densely interconnected. Although core-periphery structure sounds reasonable, we argue that it is merely accounted for by heterogeneous degree distributions, if one partitions a network into a single core block and a single periphery block, which the famous Borgatti–Everett algorithm and many succeeding algorithms assume. In other words, there is a strong tendency that high-degree and low-degree nodes are judged to be core and peripheral nodes, respectively. To discuss core-periphery structure beyond the expectation of the node’s degree (as described by the configuration model), we propose that one needs to assume at least one block of nodes apart from the focal core-periphery structure, such as a different core-periphery pair, community or nodes not belonging to any meso-scale structure. We propose a scalable algorithm to detect pairs of core and periphery in networks, controlling for the effect of the node’s degree. We illustrate our algorithm using various empirical networks.

Optogenetic stimulation of a meso-scale human cortical model

NASA Astrophysics Data System (ADS)

Selvaraj, Prashanth; Szeri, Andrew; Sleigh, Jamie; Kirsch, Heidi

2015-03-01

Neurological phenomena like sleep and seizures depend not only on the activity of individual neurons, but on the dynamics of neuron populations as well. Meso-scale models of cortical activity provide a means to study neural dynamics at the level of neuron populations. Additionally, they offer a safe and economical way to test the effects and efficacy of stimulation techniques on the dynamics of the cortex. Here, we use a physiologically relevant meso-scale model of the cortex to study the hypersynchronous activity of neuron populations during epileptic seizures. The model consists of a set of stochastic, highly non-linear partial differential equations. Next, we use optogenetic stimulation to control seizures in a hyperexcited cortex, and to induce seizures in a normally functioning cortex. The high spatial and temporal resolution this method offers makes a strong case for the use of optogenetics in treating meso scale cortical disorders such as epileptic seizures. We use bifurcation analysis to investigate the effect of optogenetic stimulation in the meso scale model, and its efficacy in suppressing the non-linear dynamics of seizures.

Fatal Attraction? Intraguild Facilitation and Suppression among Predators.

PubMed

Sivy, Kelly J; Pozzanghera, Casey B; Grace, James B; Prugh, Laura R

2017-11-01

Competition and suppression are recognized as dominant forces that structure predator communities. Facilitation via carrion provisioning, however, is a ubiquitous interaction among predators that could offset the strength of suppression. Understanding the relative importance of these positive and negative interactions is necessary to anticipate community-wide responses to apex predator declines and recoveries worldwide. Using state-sponsored wolf (Canis lupus) control in Alaska as a quasi experiment, we conducted snow track surveys of apex, meso-, and small predators to test for evidence of carnivore cascades (e.g., mesopredator release). We analyzed survey data using an integrative occupancy and structural equation modeling framework to quantify the strengths of hypothesized interaction pathways, and we evaluated fine-scale spatiotemporal responses of nonapex predators to wolf activity clusters identified from radio-collar data. Contrary to the carnivore cascade hypothesis, both meso- and small predator occupancy patterns indicated guild-wide, negative responses of nonapex predators to wolf abundance variations at the landscape scale. At the local scale, however, we observed a near guild-wide, positive response of nonapex predators to localized wolf activity. Local-scale association with apex predators due to scavenging could lead to landscape patterns of mesopredator suppression, suggesting a key link between occupancy patterns and the structure of predator communities at different spatial scales.

Fatal attraction? Intraguild facilitation and suppression among predators

USGS Publications Warehouse

Sivy, Kelly J.; Pozzanghera, Casey B.; Grace, James B.; Prugh, Laura R.

2017-01-01

Competition and suppression are recognized as dominant forces that structure predator communities. Facilitation via carrion provisioning, however, is a ubiquitous interaction among predators that could offset the strength of suppression. Understanding the relative importance of these positive and negative interactions is necessary to anticipate community-wide responses to apex predator declines and recoveries worldwide. Using state-sponsored wolf (Canis lupus) control in Alaska as a quasi experiment, we conducted snow track surveys of apex, meso-, and small predators to test for evidence of carnivore cascades (e.g., mesopredator release). We analyzed survey data using an integrative occupancy and structural equation modeling framework to quantify the strengths of hypothesized interaction pathways, and we evaluated fine-scale spatiotemporal responses of nonapex predators to wolf activity clusters identified from radio-collar data. Contrary to the carnivore cascade hypothesis, both meso- and small predator occupancy patterns indicated guild-wide, negative responses of nonapex predators to wolf abundance variations at the landscape scale. At the local scale, however, we observed a near guild-wide, positive response of nonapex predators to localized wolf activity. Local-scale association with apex predators due to scavenging could lead to landscape patterns of mesopredator suppression, suggesting a key link between occupancy patterns and the structure of predator communities at different spatial scales.

Meso-scale turbulence in living fluids

PubMed Central

Wensink, Henricus H.; Dunkel, Jörn; Heidenreich, Sebastian; Drescher, Knut; Goldstein, Raymond E.; Löwen, Hartmut; Yeomans, Julia M.

2012-01-01

Turbulence is ubiquitous, from oceanic currents to small-scale biological and quantum systems. Self-sustained turbulent motion in microbial suspensions presents an intriguing example of collective dynamical behavior among the simplest forms of life and is important for fluid mixing and molecular transport on the microscale. The mathematical characterization of turbulence phenomena in active nonequilibrium fluids proves even more difficult than for conventional liquids or gases. It is not known which features of turbulent phases in living matter are universal or system-specific or which generalizations of the Navier–Stokes equations are able to describe them adequately. Here, we combine experiments, particle simulations, and continuum theory to identify the statistical properties of self-sustained meso-scale turbulence in active systems. To study how dimensionality and boundary conditions affect collective bacterial dynamics, we measured energy spectra and structure functions in dense Bacillus subtilis suspensions in quasi-2D and 3D geometries. Our experimental results for the bacterial flow statistics agree well with predictions from a minimal model for self-propelled rods, suggesting that at high concentrations the collective motion of the bacteria is dominated by short-range interactions. To provide a basis for future theoretical studies, we propose a minimal continuum model for incompressible bacterial flow. A detailed numerical analysis of the 2D case shows that this theory can reproduce many of the experimentally observed features of self-sustained active turbulence. PMID:22908244

Meso-scale turbulence in living fluids.

PubMed

Wensink, Henricus H; Dunkel, Jörn; Heidenreich, Sebastian; Drescher, Knut; Goldstein, Raymond E; Löwen, Hartmut; Yeomans, Julia M

2012-09-04

Turbulence is ubiquitous, from oceanic currents to small-scale biological and quantum systems. Self-sustained turbulent motion in microbial suspensions presents an intriguing example of collective dynamical behavior among the simplest forms of life and is important for fluid mixing and molecular transport on the microscale. The mathematical characterization of turbulence phenomena in active nonequilibrium fluids proves even more difficult than for conventional liquids or gases. It is not known which features of turbulent phases in living matter are universal or system-specific or which generalizations of the Navier-Stokes equations are able to describe them adequately. Here, we combine experiments, particle simulations, and continuum theory to identify the statistical properties of self-sustained meso-scale turbulence in active systems. To study how dimensionality and boundary conditions affect collective bacterial dynamics, we measured energy spectra and structure functions in dense Bacillus subtilis suspensions in quasi-2D and 3D geometries. Our experimental results for the bacterial flow statistics agree well with predictions from a minimal model for self-propelled rods, suggesting that at high concentrations the collective motion of the bacteria is dominated by short-range interactions. To provide a basis for future theoretical studies, we propose a minimal continuum model for incompressible bacterial flow. A detailed numerical analysis of the 2D case shows that this theory can reproduce many of the experimentally observed features of self-sustained active turbulence.

Ionic liquid-mediated synthesis of meso-scale porous lanthanum-transition-metal perovskites with high CO oxidation performance

DOE PAGES

Lu, Hanfeng; Zhang, Pengfei; Qiao, Zhen-An; ...

2015-02-19

Lanthanum-transition-metal perovskites with robust meso-scale porous frameworks (meso-LaMO 3) are synthesized through use of ionic liquids. The resultant samples demonstrate a rather high activity for CO oxidation, by taking advantage of unique nanostructure-derived benefits. This synthesis strategy opens up a new opportunity for preparing functional mesoporous complex oxides of various compositions.

Ionic liquid-mediated synthesis of meso-scale porous lanthanum-transition-metal perovskites with high CO oxidation performance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lu, Hanfeng; Zhang, Pengfei; Qiao, Zhen-An

Lanthanum-transition-metal perovskites with robust meso-scale porous frameworks (meso-LaMO 3) are synthesized through use of ionic liquids. The resultant samples demonstrate a rather high activity for CO oxidation, by taking advantage of unique nanostructure-derived benefits. This synthesis strategy opens up a new opportunity for preparing functional mesoporous complex oxides of various compositions.

Initialization of high resolution surface wind simulations using NWS gridded data

Treesearch

J. Forthofer; K. Shannon; Bret Butler

2010-01-01

WindNinja is a standalone computer model designed to provide the user with simulations of surface wind flow. It is deterministic and steady state. It is currently being modified to allow the user to initialize the flow calculation using National Digital Forecast Database. It essentially allows the user to downscale the coarse scale simulations from meso-scale models to...

Shock-induced mechanochemistry in heterogeneous reactive powder mixtures

NASA Astrophysics Data System (ADS)

Gonzales, Manny; Gurumurthy, Ashok; Kennedy, Gregory; Neel, Christopher; Gokhale, Arun; Thadhani, Naresh

The bulk response of compacted powder mixtures subjected to high-strain-rate loading conditions in various configurations is manifested from behavior at the meso-scale. Simulations at the meso-scale can provide an additional confirmation of the possible origins of the observed response. This work investigates the bulk dynamic response of Ti +B +Al reactive powder mixtures under two extreme loading configurations - uniaxial stress and strain loading - leveraging highly-resolved in-situ measurements and meso-scale simulations. Modified rod-on-anvil impact tests on a reactive pellet demonstrate an optimized stoichiometry promoting reaction in Ti +B +Al. Encapsulated powders subjected to shock compression via flyer plate tests provide possible evidence of a shock-induced reaction at high pressures. Meso-scale simulations of the direct experimental configurations employing highly-resolved microstructural features of the Ti +B compacted mixture show complex inhomogeneous deformation responses and reveal the importance of meso-scale features such as particle size and morphology and their effects on the measured response. Funding is generously provided by DTRA through Grant No. HDTRA1-10-1-0038 (Dr. Su Peiris - Program Manager) and by the SMART (AFRL Wright Patterson AFB) and NDSEG fellowships (High Performance Computing and Modernization Office).

A mesostate-space model for EEG and MEG.

PubMed

Daunizeau, Jean; Friston, Karl J

2007-10-15

We present a multi-scale generative model for EEG, that entails a minimum number of assumptions about evoked brain responses, namely: (1) bioelectric activity is generated by a set of distributed sources, (2) the dynamics of these sources can be modelled as random fluctuations about a small number of mesostates, (3) mesostates evolve in a temporal structured way and are functionally connected (i.e. influence each other), and (4) the number of mesostates engaged by a cognitive task is small (e.g. between one and a few). A Variational Bayesian learning scheme is described that furnishes the posterior density on the models parameters and its evidence. Since the number of meso-sources specifies the model, the model evidence can be used to compare models and find the optimum number of meso-sources. In addition to estimating the dynamics at each cortical dipole, the mesostate-space model and its inversion provide a description of brain activity at the level of the mesostates (i.e. in terms of the dynamics of meso-sources that are distributed over dipoles). The inclusion of a mesostate level allows one to compute posterior probability maps of each dipole being active (i.e. belonging to an active mesostate). Critically, this model accommodates constraints on the number of meso-sources, while retaining the flexibility of distributed source models in explaining data. In short, it bridges the gap between standard distributed and equivalent current dipole models. Furthermore, because it is explicitly spatiotemporal, the model can embed any stochastic dynamical causal model (e.g. a neural mass model) as a Markov process prior on the mesostate dynamics. The approach is evaluated and compared to standard inverse EEG techniques, using synthetic data and real data. The results demonstrate the added-value of the mesostate-space model and its variational inversion.

Error characterization of microwave satellite soil moisture data sets using fourier analysis

USDA-ARS?s Scientific Manuscript database

Soil moisture is a key geophysical variable in hydrological and meteorological processes. Accurate and current observations of soil moisture over meso to global scales used as inputs to hydrological, weather and climate modelling will benefit the predictability and understanding of these processes. ...

Characterisation of physical environmental factors on an intertidal sandflat, Manukau Harbour, New Zealand

USGS Publications Warehouse

Bell, R.G.; Hume, T.M.; Dolphin, T.J.; Green, M.O.; Walters, R.A.

1997-01-01

Physical environmental factors, including sediment characteristics, inundation time, tidal currents and wind waves, likely to influence the structure of the benthic community at meso-scales (1-100 m) were characterised for a sandflat off Wiroa Island (Manukau Harbour, New Zealand). In a 500 x 250 m study site, sediment characteristics and bed topography were mostly homogenous apart from patches of low-relief ridges and runnels. Field measurements and hydrodynamic modelling portray a complex picture of sediment or particulate transport on the intertidal flat, involving interactions between the larger scale tidal processes and the smaller scale wave dynamics (1-4 s; 1-15 m). Peak tidal currents in isolation are incapable of eroding bottom sediments, but in combination with near-bed orbital currents generated by only very small wind waves, sediment transport can be initiated. Work done on the bed integrated over an entire tidal cycle by prevailing wind waves is greatest on the elevated and flatter slopes of the study site, where waves shoal over a wider surf zone and water depths remain shallow e enough for wave-orbital currents to disturb the bed. The study also provided physical descriptors quantifying static and hydrodynamic (tidal and wave) factors which were used in companion studies on ecological spatial modelling of bivalve distributions and micro-scale sediment reworking and transport.

Atomistic Computer Simulations of Water Interactions and Dissolution of Inorganic Glasses

DOE PAGES

Du, Jincheng; Rimsza, Jessica

2017-09-01

Computational simulations at the atomistic level play an increasing important role in understanding the structures, behaviors, and the structure-property relationships of glass and amorphous materials. In this paper, we reviewed atomistic simulation methods ranging from first principles calculations and ab initio molecular dynamics (AIMD), to classical molecular dynamics (MD) and meso-scale kinetic Monte Carlo (KMC) simulations and their applications to glass-water interactions and glass dissolutions. Particularly, the use of these simulation methods in understanding the reaction mechanisms of water with oxide glasses, water-glass interfaces, hydrated porous silica gels formation, the structure and properties of multicomponent glasses, and microstructure evolution aremore » reviewed. Here, the advantages and disadvantageous of these methods are discussed and the current challenges and future direction of atomistic simulations in glass dissolution are presented.« less

Intrinsic Origins of Crack Generation in Ni-rich LiNi0.8Co0.1Mn0.1O2 Layered Oxide Cathode Material.

PubMed

Lim, Jin-Myoung; Hwang, Taesoon; Kim, Duho; Park, Min-Sik; Cho, Kyeongjae; Cho, Maenghyo

2017-01-03

Ni-rich LiNi 0.8 Co 0.1 Mn 0.1 O 2 layered oxide cathodes have been highlighted for large-scale energy applications due to their high energy density. Although its specific capacity is enhanced at higher voltages as Ni ratio increases, its structural degradation due to phase transformations and lattice distortions during cycling becomes severe. For these reasons, we focused on the origins of crack generation from phase transformations and structural distortions in Ni-rich LiNi 0.8 Co 0.1 Mn 0.1 O 2 using multiscale approaches, from first-principles to meso-scale phase-field model. Atomic-scale structure analysis demonstrated that opposite changes in the lattice parameters are observed until the inverse Li content x = 0.75; then, structure collapses due to complete extraction of Li from between transition metal layers. Combined-phase investigations represent the highest phase barrier and steepest chemical potential after x = 0.75, leading to phase transformations to highly Li-deficient phases with an inactive character. Abrupt phase transformations with heterogeneous structural collapse after x = 0.81 (~220 mAh g -1 ) were identified in the nanodomain. Further, meso-scale strain distributions show around 5% of anisotropic contraction with lower critical energy release rates, which cause not only micro-crack generations of secondary particles on the interfaces between the contracted primary particles, but also mechanical instability of primary particles from heterogeneous strain changes.

Up-scaling of multi-variable flood loss models from objects to land use units at the meso-scale

NASA Astrophysics Data System (ADS)

Kreibich, Heidi; Schröter, Kai; Merz, Bruno

2016-05-01

Flood risk management increasingly relies on risk analyses, including loss modelling. Most of the flood loss models usually applied in standard practice have in common that complex damaging processes are described by simple approaches like stage-damage functions. Novel multi-variable models significantly improve loss estimation on the micro-scale and may also be advantageous for large-scale applications. However, more input parameters also reveal additional uncertainty, even more in upscaling procedures for meso-scale applications, where the parameters need to be estimated on a regional area-wide basis. To gain more knowledge about challenges associated with the up-scaling of multi-variable flood loss models the following approach is applied: Single- and multi-variable micro-scale flood loss models are up-scaled and applied on the meso-scale, namely on basis of ATKIS land-use units. Application and validation is undertaken in 19 municipalities, which were affected during the 2002 flood by the River Mulde in Saxony, Germany by comparison to official loss data provided by the Saxon Relief Bank (SAB).In the meso-scale case study based model validation, most multi-variable models show smaller errors than the uni-variable stage-damage functions. The results show the suitability of the up-scaling approach, and, in accordance with micro-scale validation studies, that multi-variable models are an improvement in flood loss modelling also on the meso-scale. However, uncertainties remain high, stressing the importance of uncertainty quantification. Thus, the development of probabilistic loss models, like BT-FLEMO used in this study, which inherently provide uncertainty information are the way forward.

Ecological Realism of U.S. EPA Experimental Stream Facility Studies

EPA Science Inventory

The USEPA’s Experimental Stream Facility (ESF) conducts meso-scale ecotoxicology studies that account for both structural and functional responses of whole stream communities to contaminants or other stressors. The 16 mesocosms of ESF are indoors and consist of a tiled run sectio...

Robust X-ray angular correlations for the study of meso-structures

DOE PAGES

Lhermitte, Julien R.; Tian, Cheng; Stein, Aaron; ...

2017-05-08

As self-assembling nanomaterials become more sophisticated, it is becoming increasingly important to measure the structural order of finite-sized assemblies of nano-objects. These mesoscale clusters represent an acute challenge to conventional structural probes, owing to the range of implicated size scales (10 nm to several micrometres), the weak scattering signal and the dynamic nature of meso-clusters in native solution environments. The high X-ray flux and coherence of modern synchrotrons present an opportunity to extract structural information from these challenging systems, but conventional ensemble X-ray scattering averages out crucial information about local particle configurations. Conversely, a single meso-cluster scatters too weakly tomore » recover the full diffraction pattern. Using X-ray angular cross-correlation analysis, it is possible to combine multiple noisy measurements to obtain robust structural information. This paper explores the key theoretical limits and experimental challenges that constrain the application of these methods to probing structural order in real nanomaterials. A metric is presented to quantify the signal-to-noise ratio of angular correlations, and it is used to identify several experimental artifacts that arise. In particular, it is found that background scattering, data masking and inter-cluster interference profoundly affect the quality of correlation analyses. A robust workflow is demonstrated for mitigating these effects and extracting reliable angular correlations from realistic experimental data.« less

Synthesis of Meso-Octamethylporphyrinogen: An Undergraduate Laboratory Mini-Scale Experiment in Organic Heterocyclic Chemistry

ERIC Educational Resources Information Center

Sobral, Abilio J. F. N.

2005-01-01

The synthesis of meso-octamethylporphyrinogen that involves a mini-scale preparation and uses acetone as reactant and also as solvent is presented. It results in a product of almost analytical grade directly from the reaction medium.

Meteorological determinants of air quality

NASA Astrophysics Data System (ADS)

Turoldo, F.; Del Frate, S.; Gallai, I.; Giaiotti, D. B.; Montanari, F.; Stel, F.; Goi, D.

2010-09-01

Air quality is the result of complex phenomena, among which the major role is played by human emissions of pollutants. Atmospheric processes act as determinants, e.g., modulating, dumping or amplifying the effects of emissions as an orchestra's director does with musical instruments. In this work, a series of small-scale and meso-scale meteorological determinants of air-quality are presented as they are observed in an area characterized by complex orography (Friuli Venezia Giulia, in the north-eastern side of Italy). In particular, attention is devoted to: i) meso-scale flows favouring the persistence of high concentrations of particulate matter; ii) meso-scale periodic flows (breezes) favouring high values of particulate matter; iii) local-scale thermodynamic behaviour favouring high atmospheric values of nitrogen oxides. The effects of these different classes of determinants are shown through comparisons between anthropic emissions (mainly traffic) and ground-based measurements. The relevance of complex orography (relatively steep relieves near to the sea) is shown for the meso-scale flows and, in particular, for local-scale periodic flows, which favour the increase of high pollutants concentrations mainly in summer, when the breezes regime is particularly relevant. Part of these results have been achieved through the ETS - Alpine Space EU project iMONITRAF!

Landauer’s formula with finite-time relaxation: Kramers’ crossover in electronic transport

DOE PAGES

Gruss, Daniel; Velizhanin, Kirill A.; Zwolak, Michael

2016-04-20

Landauer’s formula is the standard theoretical tool to examine ballistic transport in nano- and meso-scale junctions, but it necessitates that any variation of the junction with time must be slow compared to characteristic times of the system, e.g., the relaxation time of local excitations. Transport through structurally dynamic junctions is, however, increasingly of interest for sensing, harnessing fluctuations, and real-time control. Here, we calculate the steady-state current when relaxation of electrons in the reservoirs is present and demonstrate that it gives rise to three regimes of behavior: weak relaxation gives a contact-limited current; strong relaxation localizes electrons, distorting their naturalmore » dynamics and reducing the current; and in an intermediate regime the Landauer view of the system only is recovered. Lastly, we also demonstrate that a simple equation of motion emerges, which is suitable for efficiently simulating time-dependent transport.« less

Borneo vortex and meso-scale convective rainfall

NASA Astrophysics Data System (ADS)

Koseki, S.; Koh, T.-Y.; Teo, C.-K.

2013-08-01

We have investigated how the Borneo vortex develops over the equatorial South China Sea under cold surge conditions in December during the Asian winter monsoon. Composite analysis using reanalysis and satellite datasets has revealed that absolute vorticity and water vapour are transported by strong cold surges from upstream of the South China Sea to around the equator. Rainfall is correspondingly enhanced over the equatorial South China Sea. A semi-idealized experiment reproduced the Borneo vortex over the equatorial South China Sea during a "perpetual" cold surge. The Borneo vortex is manifested as a meso-α cyclone with a comma-shaped rainband in the northeast sector of the cyclone. Vorticity budget analysis showed that the growth of the meso-α cyclone was achieved mainly by vortex stretching. The comma-shaped rainband consists of clusters of meso-β scale rainfall patches. The warm and wet cyclonic southeasterly flow meets with the cold and dry northeasterly surge forming a confluence front in the northeastern sector of the cyclone. Intense upward motion and heavy rainfall result both due to the low-level convergence and the favourable thermodynamic profile at the confluence front. At both meso-α and meso-β scales, the convergence is ultimately caused by the deviatoric strain in the confluence wind pattern but is much enhanced by nonlinear self-enhancement dynamics.

Geophysics and Nanosciences: Nano to Micro to Meso to Macro Scale Swelling Soils

NASA Astrophysics Data System (ADS)

Cushman, J.

2003-04-01

We use statistical mechanical simulations of nanoporous materials to motivate a choice of independent constitutive variables for a multiscale mixture theory of swelling soils. A video will illustrate the structural behavior of fluids in nanopores when they are adsorbed from a bulk phase vapor to form capillaries on the nanoscale. These simulations suggest that when a swelling soil is very dry, the full strain tensor for the liquid phase should be included in the list of independent variables in any mixture theory. We use this information to develop a three-scale (micro, meso, macro) mixture theory for swelling soils. For a simplified case, we present the underlying multiscale field equations and constitutive theory, solve the resultant well posed system numerically, and present some graphical results for a drying and shrinking body.

Model studies on the role of moist convection as a mechanism for interaction between the mesoscales

NASA Technical Reports Server (NTRS)

Waight, Kenneth T., III; Song, J. Aaron; Zack, John W.; Price, Pamela E.

1991-01-01

A three year research effort is described which had as its goal the development of techniques to improve the numerical prediction of cumulus convection on the meso-beta and meso-gamma scales. Two MESO models are used, the MASS (mesoscale) and TASS (cloud scale) models. The primary meteorological situation studied is the 28-29 Jun. 1986 Cooperative Huntsville Meteorological Experiment (COHMEX) study area on a day with relatively weak large scale forcing. The problem of determining where and when convection should be initiated is considered to be a major problem of current approaches. Assimilation of moisture data from satellite, radar, and surface data is shown to significantly improve mesoscale simulations. The TASS model is shown to reproduce some observed mesoscale features when initialized with 3-D observational data. Convection evolution studies center on comparison of the Kuo and Fritsch-Chappell cumulus parameterization schemes to each other, and to cloud model results. The Fritsch-Chappell scheme is found to be superior at about 30 km resolution, while the Kuo scheme does surprisingly well in simulating convection down to 10 km in cases where convergence features are well-resolved by the model grid. Results from MASS-TASS interaction experiments are presented and discussed. A discussion of the future of convective simulation is given, with the conclusion that significant progress is possible on several fronts in the next few years.

A Multiscale Surface Water Temperature Data Acquisition Platform: Tests on Lake Geneva, Switzerland

NASA Astrophysics Data System (ADS)

Barry, D. A.; Irani Rahaghi, A.; Lemmin, U.; Riffler, M.; Wunderle, S.

2015-12-01

An improved understanding of surface transport processes is necessary to predict sediment, pollutant and phytoplankton patterns in large lakes. Lake surface water temperature (LSWT), which varies in space and time, reflects meteorological and climatological forcing more than any other physical lake parameter. There are different data sources for LSWT mapping, including remote sensing and in situ measurements. Satellite data can be suitable for detecting large-scale thermal patterns, but not meso- or small scale processes. Lake surface thermography, investigated in this study, has finer resolution compared to satellite images. Thermography at the meso-scale provides the ability to ground-truth satellite imagery over scales of one to several satellite image pixels. On the other hand, thermography data can be used as a control in schemes to upscale local measurements that account for surface energy fluxes and the vertical energy budget. Independently, since such data can be collected at high frequency, they can be also useful in capturing changes in the surface signatures of meso-scale eddies and thus to quantify mixing processes. In the present study, we report results from a Balloon Launched Imaging and Monitoring Platform (BLIMP), which was developed in order to measure the LSWT at meso-scale. The BLIMP consists of a small balloon that is tethered to a boat and equipped with thermal and RGB cameras, as well as other instrumentation for location and communication. Several deployments were carried out on Lake Geneva. In a typical deployment, the BLIMP is towed by a boat, and collects high frequency data from different heights (i.e., spatial resolutions) and locations. Simultaneous ground-truthing of the BLIMP data is achieved using an autonomous craft that collects a variety of data, including in situ surface/near surface temperatures, radiation and meteorological data in the area covered by the BLIMP images. With suitable scaling, our results show good consistency between in situ, BLIMP and concurrent satellite data. In addition, the BLIMP thermography reveals (hydrodynamically-driven) structures in the LSWT - an obvious example being mixing of river discharges.

Inferring Upper Ocean Dynamics from Horizontal Wavenumber Spectra in the Southern California Current System

NASA Astrophysics Data System (ADS)

Chereskin, T. K.; Gille, S. T.; Rocha, C. B.; Menemenlis, D.

2016-02-01

At the largest horizontal scales (> 100 km), the surface kinetic energy of the ocean appears dominated by a regime of balanced geostrophic motions. At the smallest scales, it transitions to a regime where unbalanced motions (such as internal waves, mixed-layer instabilities, etc.) dominate the surface kinetic energy. The length scale at which the transition occurs depends on the relative energies of balanced and unbalanced motions, which in turn display significant geographic variability. Wavenumber spectra in the upper ocean have been hypothesized to have slopes consistent with either quasi-geostrophic (QG) or surface quasi-geostrophic (SQG) theory. In previous analyses of repeat-track shipboard acoustic Doppler Current profiler (ADCP) velocity observations in the Gulf Stream and the Antarctic Circumpolar Current, spectral slopes were more consistent with QG than SQG theory for length scales between 40 km and 200 km. For scales less than 40 km, the spectra deviated from both QG and SQG theory, and this was attributed in part to internal wave effects. A spectral Helmholtz decomposition was used to split the kinetic energy spectra into rotational and divergent components, identified with balanced and ageostrophic motions, respectively. The California Current System (CCS) provides a contrasting environment characterized by a weak mean flow and an energetic meso- and submeso- scale. It is a nonlinear regime where the amplitude of eddies can be as large as the total steric height increase across the California Current, and hence southward flow in the CCS can, and often is, disrupted by its eddies. This study uses 10 years of shipboard ADCP observations collected on the quarterly cruises of the California Cooperative Oceanic Fisheries Investigations. Horizontal wavenumber spectra from 36 cruises along 6 repeated tracks in the southern CCS that extend from the coast to the subtropical gyre are used to diagnose the dominant governing dynamics at meso- to submeso- scales (10-200 km), with particular attention to the partition into balanced and ageostrophic flows.

Discrete space charge affected field emission: Flat and hemisphere emitters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jensen, Kevin L., E-mail: kevin.jensen@nrl.navy.mil; Shiffler, Donald A.; Tang, Wilkin

Models of space-charge affected thermal-field emission from protrusions, able to incorporate the effects of both surface roughness and elongated field emitter structures in beam optics codes, are desirable but difficult. The models proposed here treat the meso-scale diode region separate from the micro-scale regions characteristic of the emission sites. The consequences of discrete emission events are given for both one-dimensional (sheets of charge) and three dimensional (rings of charge) models: in the former, results converge to steady state conditions found by theory (e.g., Rokhlenko et al. [J. Appl. Phys. 107, 014904 (2010)]) but show oscillatory structure as they do. Surfacemore » roughness or geometric features are handled using a ring of charge model, from which the image charges are found and used to modify the apex field and emitted current. The roughness model is shown to have additional constraints related to the discrete nature of electron charge. The ability of a unit cell model to treat field emitter structures and incorporate surface roughness effects inside a beam optics code is assessed.« less

Multi-component quantitation of meso/nanostructural surfaces and its application to local chemical compositions of copper meso/nanostructures self-organized on silica

NASA Astrophysics Data System (ADS)

Huang, Chun-Yi; Chang, Hsin-Wei; Chang, Che-Chen

2018-03-01

Knowledge about the chemical compositions of meso/nanomaterials is fundamental to development of their applications in advanced technologies. Auger electron spectroscopy (AES) is an effective analysis method for the characterization of meso/nanomaterial structures. Although a few studies have reported the use of AES for the analysis of the local composition of these structures, none have explored in detail the validity of the meso/nanoanalysis results generated by the AES instrument. This paper addresses the limitations of AES and the corrections necessary to offset them for this otherwise powerful meso/nanoanalysis tool. The results of corrections made to the AES multi-point analysis of high-density copper-based meso/nanostructures provides major insights into their local chemical compositions and technological prospects, which the primitive composition output of the AES instrument failed to provide.

Intrinsic Origins of Crack Generation in Ni-rich LiNi0.8Co0.1Mn0.1O2 Layered Oxide Cathode Material

PubMed Central

Lim, Jin-Myoung; Hwang, Taesoon; Kim, Duho; Park, Min-Sik; Cho, Kyeongjae; Cho, Maenghyo

2017-01-01

Ni-rich LiNi0.8Co0.1Mn0.1O2 layered oxide cathodes have been highlighted for large-scale energy applications due to their high energy density. Although its specific capacity is enhanced at higher voltages as Ni ratio increases, its structural degradation due to phase transformations and lattice distortions during cycling becomes severe. For these reasons, we focused on the origins of crack generation from phase transformations and structural distortions in Ni-rich LiNi0.8Co0.1Mn0.1O2 using multiscale approaches, from first-principles to meso-scale phase-field model. Atomic-scale structure analysis demonstrated that opposite changes in the lattice parameters are observed until the inverse Li content x = 0.75; then, structure collapses due to complete extraction of Li from between transition metal layers. Combined-phase investigations represent the highest phase barrier and steepest chemical potential after x = 0.75, leading to phase transformations to highly Li-deficient phases with an inactive character. Abrupt phase transformations with heterogeneous structural collapse after x = 0.81 (~220 mAh g−1) were identified in the nanodomain. Further, meso-scale strain distributions show around 5% of anisotropic contraction with lower critical energy release rates, which cause not only micro-crack generations of secondary particles on the interfaces between the contracted primary particles, but also mechanical instability of primary particles from heterogeneous strain changes. PMID:28045118

The microdopant effects of surfactant elements on structure-phase transitions during the rapid quenched crystallization of Fe-C-based melts

NASA Astrophysics Data System (ADS)

Polukhin, V. A.; Belyakova, R. M.; Rigmant, L. K.

2008-02-01

The nature of microdopant effects of surfactant Te and H2 reagents on structure-phase transitions in rapidly quenched and crystallized eutectic Fe-C-based melts were studied by experimental and computer methods. On the base of results of statistic-geometrical analysis the new information about the structure changes in multi-scaling systems -from meso- to nano-ones were obtained.

Multiscale analysis of the correlation of processing parameters on viscidity of composites fabricated by automated fiber placement

NASA Astrophysics Data System (ADS)

Han, Zhenyu; Sun, Shouzheng; Fu, Yunzhong; Fu, Hongya

2017-10-01

Viscidity is an important physical indicator for assessing fluidity of resin that is beneficial to contact resin with the fibers effectively and reduce manufacturing defects during automated fiber placement (AFP) process. However, the effect of processing parameters on viscidity evolution is rarely studied during AFP process. In this paper, viscidities under different scales are analyzed based on multi-scale analysis method. Firstly, viscous dissipation energy (VDE) within meso-unit under different processing parameters is assessed by using finite element method (FEM). According to multi-scale energy transfer model, meso-unit energy is used as the boundary condition for microscopic analysis. Furthermore, molecular structure of micro-system is built by molecular dynamics (MD) method. And viscosity curves are then obtained by integrating stress autocorrelation function (SACF) with time. Finally, the correlation characteristics of processing parameters to viscosity are revealed by using gray relational analysis method (GRAM). A group of processing parameters is found out to achieve the stability of viscosity and better fluidity of resin.

Shock Interaction of Metal Particles in Condensed Explosive Detonation

NASA Astrophysics Data System (ADS)

Ripley, Robert; Zhang, Fan; Lien, Fue-Sang

2005-07-01

For detonation propagation in a condensed explosive with metal particles, a macro-scale physical model describing the momentum transfer between the explosive and particles has yet to be completely established. Previous 1D and 2D meso-scale modeling studies indicated that significant momentum transfer from the explosive to the particles occurs as the leading shock front crosses the particles, thus influencing the initiation and detonation structure. In this work, 3D meso-scale modeling is conducted to further study the two-phase momentum transfer during the shock diffraction and subsequent detonation in liquid nitromethane containing packed metal particles. Detonation of the condensed explosive is computed using an Arrhenius reaction model and a hybrid EOS model that combines the Mie-Gruneisen equation for reactants and the JWL equation for products. The compressible particles are modeled using the Tait EOS, where the material strength is negligible. The effect of particle packing configuration and inter-particle spacing is shown by parametric studies. Finally, a physical description of the momentum transfer is discussed.

Evaluation of planetary boundary layer schemes in meso-scale simulations above the North and Baltic Sea

NASA Astrophysics Data System (ADS)

Wurps, Hauke; Tambke, Jens; Steinfeld, Gerald; von Bremen, Lueder

2014-05-01

The development and design of wind energy converters for offshore wind farms require profound knowledge of the wind profile in the lower atmosphere. Especially an accurate and reliable estimation of turbulence, shear and veer are necessary for the prediction of energy production and loads. Currently existing wind energy turbines in the North Sea have hub heights of around 90 m and upper tip heights around 150 m, which is already higher than the highest measurement masts (e.g. FINO1: 103 m). The next generation of wind turbines will clearly outrange these altitudes, so the interest is to examine the atmosphere's properties above the North Sea up to 300 m. Therefore, besides the Prandtl layer also the Ekman layer has to be taken into account, which implies that changes of the wind direction with height become more relevant. For this investigation we use the Weather Research and Forecasting Model (WRF), a meso-scale numerical weather prediction system. In this study we compare different planetary boundary layer (PBL) schemes (MYJ, MYNN, QNSE) with the same high quality input from ECMWF used as boundary conditions (ERA-Interim). It was found in previous studies that the quality of the boundary conditions is crucially important for the accuracy of comparisons between different PBL schemes. This is due to the fact that the major source of meso-scale simulation errors is introduced by the driving boundary conditions and not by the different schemes of the meso-scale model itself. Hence, small differences in results from different PBL schemes can be distorted arbitrarily by coarse input data. For instance, ERA-Interim data leads to meso-scale RMSE values of 1.4 m/s at 100 m height above sea surface with mean wind speeds around 10 m/s, whereas other Reanalysis products lead to RMSEs larger than 2 m/s. Second, we compare our simulations to operational NWP results from the COSMO model (run by the DWD). In addition to the wind profile, also the turbulent kinetic energy (TKE) and the atmosphere's thermal stability are important to estimate power production and loads. Especially the TKE is in the focus of our research since the Master Length Scale of the closure schemes depends on it. A third step is the validation of the results using wind measurements around the North Sea. Because the considered heights are much larger than available data from met masts, we use LiDAR observations (light detection and ranging) and prospectively UAVs (unmanned aerial vehicle).

Micro-CT Characterization on the Meso-Structure of Three-Dimensional Full Five-Directional Braided Composite

NASA Astrophysics Data System (ADS)

Ya, Jixuan; Liu, Zhenguo; Wang, Yuanhang

2017-06-01

The meso-structure is important in predicting mechanical properties of the three-dimensional (3D) braided composite. In this paper, the internal structure and porosity of three-dimensional full five-directional (3DF5D) braided composite is characterized at mesoscopic scale (the scale of the yarns) using micro-computed tomography (micro-CT) non-destructively. Glass fiber yarns as tracer are added into the sample made of carbon fiber to enhance the contrast in the sectional images. The model of tracer yarns is established with 3D reconstruction method to analyze the cross-section and path of yarns. The porosities are reconstructed and characterized in the end. The results demonstrate that the cross sections of braiding yarns and axial yarns change with the regions and the heights in one pitch of 3DF5D braided composites. The path of braiding yarns are various in the different regions while the axial yarns are always straight. Helical indentations appear on the surfaces of the axial yarns because of the squeeze from braiding yarns. Moreover, the porosities in different shapes and sizes are almost located in the matrix and between the yarns.

Meso-Decorated Switching-Knot Gels

NASA Astrophysics Data System (ADS)

Gong, Jin; Sawamura, Kensuke; Makino, Masato; Kabir, M. H.; Furukawa, Hidemitsu

Gels are a new material having three-dimensional network structures of macromolecules. They possess excellent properties as swellability, high permeability and biocompatibility, and have been applied in various fields of daily life, food, medicine, architecture, and chemistry .In this study, we tried to prepare new multi-functional and high-strength gels by using Meso-Decoration (Meso-Deco), one new method of structure design at intermediate mesoscale. High-performance rigid-rod aromatic polymorphic crystals. The strengthening of gels can be realized by meso-decorating the gels' structure using high-performance polymorphic crystals. New gels with good mechanical properties, novel optical properties and thermal properties are expected to be developed.

Distant Influence of Kuroshio Eddies on North Pacific Weather Patterns?

PubMed

Ma, Xiaohui; Chang, Ping; Saravanan, R; Montuoro, Raffaele; Hsieh, Jen-Shan; Wu, Dexing; Lin, Xiaopei; Wu, Lixin; Jing, Zhao

2015-12-04

High-resolution satellite measurements of surface winds and sea-surface temperature (SST) reveal strong coupling between meso-scale ocean eddies and near-surface atmospheric flow over eddy-rich oceanic regions, such as the Kuroshio and Gulf Stream, highlighting the importance of meso-scale oceanic features in forcing the atmospheric planetary boundary layer (PBL). Here, we present high-resolution regional climate modeling results, supported by observational analyses, demonstrating that meso-scale SST variability, largely confined in the Kuroshio-Oyashio confluence region (KOCR), can further exert a significant distant influence on winter rainfall variability along the U.S. Northern Pacific coast. The presence of meso-scale SST anomalies enhances the diabatic conversion of latent heat energy to transient eddy energy, intensifying winter cyclogenesis via moist baroclinic instability, which in turn leads to an equivalent barotropic downstream anticyclone anomaly with reduced rainfall. The finding points to the potential of improving forecasts of extratropical winter cyclones and storm systems and projections of their response to future climate change, which are known to have major social and economic impacts, by improving the representation of ocean eddy-atmosphere interaction in forecast and climate models.

Overview of the Meso-NH model version 5.4 and its applications

NASA Astrophysics Data System (ADS)

Lac, Christine; Chaboureau, Jean-Pierre; Masson, Valéry; Pinty, Jean-Pierre; Tulet, Pierre; Escobar, Juan; Leriche, Maud; Barthe, Christelle; Aouizerats, Benjamin; Augros, Clotilde; Aumond, Pierre; Auguste, Franck; Bechtold, Peter; Berthet, Sarah; Bielli, Soline; Bosseur, Frédéric; Caumont, Olivier; Cohard, Jean-Martial; Colin, Jeanne; Couvreux, Fleur; Cuxart, Joan; Delautier, Gaëlle; Dauhut, Thibaut; Ducrocq, Véronique; Filippi, Jean-Baptiste; Gazen, Didier; Geoffroy, Olivier; Gheusi, François; Honnert, Rachel; Lafore, Jean-Philippe; Lebeaupin Brossier, Cindy; Libois, Quentin; Lunet, Thibaut; Mari, Céline; Maric, Tomislav; Mascart, Patrick; Mogé, Maxime; Molinié, Gilles; Nuissier, Olivier; Pantillon, Florian; Peyrillé, Philippe; Pergaud, Julien; Perraud, Emilie; Pianezze, Joris; Redelsperger, Jean-Luc; Ricard, Didier; Richard, Evelyne; Riette, Sébastien; Rodier, Quentin; Schoetter, Robert; Seyfried, Léo; Stein, Joël; Suhre, Karsten; Taufour, Marie; Thouron, Odile; Turner, Sandra; Verrelle, Antoine; Vié, Benoît; Visentin, Florian; Vionnet, Vincent; Wautelet, Philippe

2018-05-01

This paper presents the Meso-NH model version 5.4. Meso-NH is an atmospheric non hydrostatic research model that is applied to a broad range of resolutions, from synoptic to turbulent scales, and is designed for studies of physics and chemistry. It is a limited-area model employing advanced numerical techniques, including monotonic advection schemes for scalar transport and fourth-order centered or odd-order WENO advection schemes for momentum. The model includes state-of-the-art physics parameterization schemes that are important to represent convective-scale phenomena and turbulent eddies, as well as flows at larger scales. In addition, Meso-NH has been expanded to provide capabilities for a range of Earth system prediction applications such as chemistry and aerosols, electricity and lightning, hydrology, wildland fires, volcanic eruptions, and cyclones with ocean coupling. Here, we present the main innovations to the dynamics and physics of the code since the pioneer paper of Lafore et al. (1998) and provide an overview of recent applications and couplings.

An explicit three-dimensional nonhydrostatic numerical simulation of a tropical cyclone

NASA Technical Reports Server (NTRS)

Tripoli, G. J.

1992-01-01

A nonhydrostatic numerical simulation of a tropical cyclone is performed with explicit representation of cumulus on a meso-beta scale grid and for a brief period on a meso-gamma scale grid. Individual cumulus plumes are represented by a combination of explicit resolution and a 1.5 level closure predicting turbulent kinetic energy (TKE).

Borneo Vortex and Meso-scale Convective Rainfall

NASA Astrophysics Data System (ADS)

Koh, T. Y.; Koseki, S.; Teo, C. K.

2014-12-01

We have investigated how the Borneo vortex develops over the equatorial South China Sea under cold surge conditions in December during the Asian winter monsoon. Composite analysis using reanalysis and satellite datasets has revealed that absolute vorticity and water vapour are transported by strong cold surges from upstream of the South China Sea to around the equator. Rainfall is correspondingly enhanced over the equatorial South China Sea. A semi-idealized experiment reproduced the Borneo vortex over the equatorial South China Sea during a perpetual cold surge. The Borneo vortex is manifested as a meso-alpha cyclone with a comma-shaped rainband in the northeast sector of the cyclone. Vorticity budget analysis showed that the growth/maintenance of the meso-alpha cyclone was achieved mainly by the vortex stretching. This vortex stretching is due to the upward motion forced by the latent heat release around the cyclone centre. The comma-shaped rainband consists of clusters of meso-beta scale rainfall cells. The intense rainfall in the comma-head (comma-tail) is generated by the confluence of the warmer and wetter cyclonic easterly flow (cyclonic southeasterly flow) and the cooler and drier northeasterly surge in the northwestern (northeastern) sector of the cyclone. Intense upward motion and heavy rainfall resulted due to the low-level convergence and the favourable thermodynamic profile at the confluence zone. In particular, the convergence in the northwestern sector is responsible for maintenance of the meso-alpha cyclone system. At both meso-alpha and meso-beta scales, the convergence is ultimately caused by the deviatoric strain in the confluence wind pattern but is significantly self-enhanced by the nonlinear dynamics. Reference: Koseki, S., T.-Y. Koh and C.-K. Teo (2014), Atmospheric Chemistry and Physics, 14, 4539-4562, doi:10.5194/acp-14-4539-2014, 2014.

Meso-decorated self-healing gels: network structure and properties

NASA Astrophysics Data System (ADS)

Gong, Jin; Sawamura, Kensuke; Igarashi, Susumu; Furukawa, Hidemitsu

2013-04-01

Gels are a new material having three-dimensional network structures of macromolecules. They possess excellent properties as swellability, high permeability and biocompatibility, and have been applied in various fields of daily life, food, medicine, architecture, and chemistry. In this study, we tried to prepare new multi-functional and high-strength gels by using Meso-Decoration (Meso-Deco), one new method of structure design at intermediate mesoscale. High-performance rigid-rod aromatic polymorphic crystals, and the functional groups of thermoreversible Diels-Alder reaction were introduced into soft gels as crosslinkable pendent chains. The functionalization and strengthening of gels can be realized by meso-decorating the gels' structure using high-performance polymorphic crystals and thermoreversible pendent chains. New gels with good mechanical properties, novel optical properties and thermal properties are expected to be developed.

Toward Scalable Fabrication of Hierarchical Silica Capsules with Integrated Micro-, Meso-, and Macropores.

PubMed

Zhou, Weizheng; Tong, Gangsheng; Wang, Dali; Zhu, Bangshang; Ren, Yu; Butler, Michael; Pelan, Eddie; Yan, Deyue; Zhu, Xinyuan; Stoyanov, Simeon D

2016-04-06

Hierarchical porous structures are ubiquitous in biological organisms and inorganic systems. Although such structures have been replicated, designed, and fabricated, they are often inferior to naturally occurring analogues. Apart from the complexity and multiple functionalities developed by the biological systems, the controllable and scalable production of hierarchically porous structures and building blocks remains a technological challenge. Herein, a facile and scalable approach is developed to fabricate hierarchical hollow spheres with integrated micro-, meso-, and macropores ranging from 1 nm to 100 μm (spanning five orders of magnitude). (Macro)molecules, micro-rods (which play a key role for the creation of robust capsules), and emulsion droplets have been successfully employed as multiple length scale templates, allowing the creation of hierarchical porous macrospheres. Thanks to their specific mechanical strength, these hierarchical porous spheres could be incorporated and assembled as higher level building blocks in various novel materials. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

The Role of Jet Adjustment Processes in Subtropical Dust Storms

NASA Astrophysics Data System (ADS)

Pokharel, Ashok Kumar; Kaplan, Michael L.; Fiedler, Stephanie

2017-11-01

Meso-α/β/γ scale atmospheric processes of jet dynamics responsible for generating Harmattan, Saudi Arabian, and Bodélé Depression dust storms are analyzed with observations and high-resolution modeling. The analysis of the role of jet adjustment processes in each dust storm shows similarities as follows: (1) the presence of a well-organized baroclinic synoptic scale system, (2) cross mountain flows that produced a leeside inversion layer prior to the large-scale dust storm, (3) the presence of thermal wind imbalance in the exit region of the midtropospheric jet streak in the lee of the respective mountains shortly after the time of the inversion formation, (4) dust storm formation accompanied by large magnitude ageostrophic isallobaric low-level winds as part of the meso-β scale adjustment process, (5) substantial low-level turbulence kinetic energy (TKE), and (6) emission and uplift of mineral dust in the lee of nearby mountains. The thermally forced meso-γ scale adjustment processes, which occurred in the canyons/small valleys, may have been the cause of numerous observed dust streaks leading to the entry of the dust into the atmosphere due to the presence of significant vertical motion and TKE generation. This study points to the importance of meso-β to meso-γ scale adjustment processes at low atmospheric levels due to an imbalance within the exit region of an upper level jet streak for the formation of severe dust storms. The low level TKE, which is one of the prerequisites to deflate the dust from the surface, cannot be detected with the low resolution data sets; so our results show that a high spatial resolution is required for better representing TKE as a proxy for dust emission.

Keratin-lipid structural organization in the corneous layer of snake.

PubMed

Ripamonti, Alberto; Alibardi, Lorenzo; Falini, Giuseppe; Fermani, Simona; Gazzano, Massimo

2009-12-01

The shed epidermis (molt) of snakes comprises four distinct layers. The upper two layers, here considered as beta-layer, contain essentially beta-keratin. The following layer, known as mesos-layer, is similar to the human stratum corneum, and is formed by thin cells surrounded by intercellular lipids. The latter layer mainly contains alpha-keratin. In this study, the molecular assemblies of proteins and lipids contained in these layers have been analyzed in the scale of two species of snakes, the elapid Tiger snake (TS, Notechis scutatus) and the viperid Gabon viper (GV, Bitis gabonica). Scanning X-ray micro-diffraction, FTIR and Raman spectroscopies, thermal analysis, and scanning electron microscopy experiments confirm the presence of the three layers in the GV skin scale. Conversely, in the TS molt a typical alpha-keratin layer appears to be absent. In the latter, experimental data suggest the presence of two domains similar to those found in the lipid intercellular matrix of stratum corneum. X-ray diffraction data also allow to determine the relative orientation of keratins and lipids. The keratin fibrils are randomly oriented inside the layers parallel to the surface of scales while the lipids are organized in lamellar structures having aliphatic chains normal to the scale surface. The high ordered lipid organization in the mature mesos layer probably increases its effectiveness in limiting water-loss.

Chemical control of electrical contact to sp² carbon atoms.

PubMed

Frederiksen, Thomas; Foti, Giuseppe; Scheurer, Fabrice; Speisser, Virginie; Schull, Guillaume

2014-04-16

Carbon-based nanostructures are attracting tremendous interest as components in ultrafast electronics and optoelectronics. The electrical interfaces to these structures play a crucial role for the electron transport, but the lack of control at the atomic scale can hamper device functionality and integration into operating circuitry. Here we study a prototype carbon-based molecular junction consisting of a single C60 molecule and probe how the electric current through the junction depends on the chemical nature of the foremost electrode atom in contact with the molecule. We find that the efficiency of charge injection to a C60 molecule varies substantially for the considered metallic species, and demonstrate that the relative strength of the metal-C bond can be extracted from our transport measurements. Our study further suggests that a single-C60 junction is a basic model to explore the properties of electrical contacts to meso- and macroscopic sp(2) carbon structures.

Chemical control of electrical contact to sp2 carbon atoms

NASA Astrophysics Data System (ADS)

Frederiksen, Thomas; Foti, Giuseppe; Scheurer, Fabrice; Speisser, Virginie; Schull, Guillaume

2014-04-01

Carbon-based nanostructures are attracting tremendous interest as components in ultrafast electronics and optoelectronics. The electrical interfaces to these structures play a crucial role for the electron transport, but the lack of control at the atomic scale can hamper device functionality and integration into operating circuitry. Here we study a prototype carbon-based molecular junction consisting of a single C60 molecule and probe how the electric current through the junction depends on the chemical nature of the foremost electrode atom in contact with the molecule. We find that the efficiency of charge injection to a C60 molecule varies substantially for the considered metallic species, and demonstrate that the relative strength of the metal-C bond can be extracted from our transport measurements. Our study further suggests that a single-C60 junction is a basic model to explore the properties of electrical contacts to meso- and macroscopic sp2 carbon structures.

Are Hydrostatic Models Still Capable of Simulating Oceanic Fronts

DTIC Science & Technology

2016-11-10

Coriolis effect is added to the model momentum equations...nonhydrostatic (NH) models to address the relevance of NH effects on the evolution of density fronts and the development of meso- and submeso-scale vertical...nonhydrostatic (NH) models to address the relevance of NH effects on the evolution of density fronts and the development of meso- and submeso-scale vertical

Distant Influence of Kuroshio Eddies on North Pacific Weather Patterns?

PubMed Central

Ma, Xiaohui; Chang, Ping; Saravanan, R.; Montuoro, Raffaele; Hsieh, Jen-Shan; Wu, Dexing; Lin, Xiaopei; Wu, Lixin; Jing, Zhao

2015-01-01

High-resolution satellite measurements of surface winds and sea-surface temperature (SST) reveal strong coupling between meso-scale ocean eddies and near-surface atmospheric flow over eddy-rich oceanic regions, such as the Kuroshio and Gulf Stream, highlighting the importance of meso-scale oceanic features in forcing the atmospheric planetary boundary layer (PBL). Here, we present high-resolution regional climate modeling results, supported by observational analyses, demonstrating that meso-scale SST variability, largely confined in the Kuroshio-Oyashio confluence region (KOCR), can further exert a significant distant influence on winter rainfall variability along the U.S. Northern Pacific coast. The presence of meso-scale SST anomalies enhances the diabatic conversion of latent heat energy to transient eddy energy, intensifying winter cyclogenesis via moist baroclinic instability, which in turn leads to an equivalent barotropic downstream anticyclone anomaly with reduced rainfall. The finding points to the potential of improving forecasts of extratropical winter cyclones and storm systems and projections of their response to future climate change, which are known to have major social and economic impacts, by improving the representation of ocean eddy–atmosphere interaction in forecast and climate models. PMID:26635077

Two-dimensional analysis of coupled heat and moisture transport in masonry structures

NASA Astrophysics Data System (ADS)

Krejčí, Tomáš

2016-06-01

Reconstruction and maintenance of historical buildings and bridges require good knowledge of temperature and moisture distribution. Sharp changes in the temperature and moisture can lead to damage. This paper describes analysis of coupled heat and moisture transfer in masonry based on two-level approach. Macro-scale level describes the whole structure while meso-scale level takes into account detailed composition of the masonry. The two-level approach is very computationally demanding and it was implemented in parallel. The two-level approach was used in analysis of temperature and moisture distribution in Charles bridge in Prague, Czech Republic.

Investigating influences on current community pharmacy practice at micro, meso, and macro levels.

PubMed

Hermansyah, Andi; Sainsbury, Erica; Krass, Ines

The nature of Australian community pharmacy is continually evolving, raising the need to explore the current situation in order to understand the potential impact of any changes. Although community pharmacy has the potential to play a greater role in health care, it is currently not meeting this potential. To investigate the nature of the contemporary practice of community pharmacy in Australia and examine the potential missed opportunities for role expansion in health care. In-depth semi-structured interviews with a wide-range of key stakeholders within and beyond community pharmacy circles were conducted. Interviews were audio-recorded, transcribed verbatim and analyzed for emerging themes. Twenty-seven key informants across Eastern half of Australia were interviewed between December 2014 and August 2015. Several key elements of the current situation representing the social, economic and policy context of community pharmacy have been identified. These elements operate interdependently, influence micro, meso and macro levels of community pharmacy operation and are changing in the current climate. Community pharmacy has untapped potential in primary health care, but it has been slow to change to meet opportunities available in the current situation. As the current situation is complex, interrelated and dynamic with often unintended and unpredictable consequences, this paper suggests that policy makers to consider the micro, meso and macro levels of community pharmacy operation when making significant policy changes. The framework proposed in this study can be a helpful tool to analyze the processes operating at these three levels and their influences on practice. Copyright © 2016 Elsevier Inc. All rights reserved.

A dual theory of price and value in a meso-scale economic model with stochastic profit rate

NASA Astrophysics Data System (ADS)

Greenblatt, R. E.

2014-12-01

The problem of commodity price determination in a market-based, capitalist economy has a long and contentious history. Neoclassical microeconomic theories are based typically on marginal utility assumptions, while classical macroeconomic theories tend to be value-based. In the current work, I study a simplified meso-scale model of a commodity capitalist economy. The production/exchange model is represented by a network whose nodes are firms, workers, capitalists, and markets, and whose directed edges represent physical or monetary flows. A pair of multivariate linear equations with stochastic input parameters represent physical (supply/demand) and monetary (income/expense) balance. The input parameters yield a non-degenerate profit rate distribution across firms. Labor time and price are found to be eigenvector solutions to the respective balance equations. A simple relation is derived relating the expected value of commodity price to commodity labor content. Results of Monte Carlo simulations are consistent with the stochastic price/labor content relation.

A kinetic energy analysis of the meso beta-scale severe storm environment

NASA Technical Reports Server (NTRS)

Fuelberg, H. E.; Printy, M. F.

1984-01-01

Analyses are performed of the meso beta-scale (20-200 km wavelengths and several hours to one-day periods) severe storm kinetic energy balance on the fifth day of the AVE SESAME campaign of May 1979. A 24-hr interval covering the antecedent, active and post-convective outbreak activity over Oklahoma are considered. Use is made of the kinetic energy budget equation (KEBE) for a finite volume in an isobaric coordinate system. Rawindsonde data with 75 km resolution were treated. The KEBE model covered changes in kinetic energy due to the cross contour flows, horizontal and vertical components of flux divergence, and volumic mass changes on synoptic and subsynoptic scales. The greatest variability was concentrated above 400 mb height and over the most intense storm activity. Energy was generated at the highest rates in divergence and decreased the most in convection. The meso beta-scale lacked sufficient resolution for analyzing mesoscale activity.

LES-based generation of high-frequency fluctuation in wind turbulence obtained by meteorological model

NASA Astrophysics Data System (ADS)

Tamura, Tetsuro; Kawaguchi, Masaharu; Kawai, Hidenori; Tao, Tao

2017-11-01

The connection between a meso-scale model and a micro-scale large eddy simulation (LES) is significant to simulate the micro-scale meteorological problem such as strong convective events due to the typhoon or the tornado using LES. In these problems the mean velocity profiles and the mean wind directions change with time according to the movement of the typhoons or tornadoes. Although, a fine grid micro-scale LES could not be connected to a coarse grid meso-scale WRF directly. In LES when the grid is suddenly refined at the interface of nested grids which is normal to the mean advection the resolved shear stresses decrease due to the interpolation errors and the delay of the generation of smaller scale turbulence that can be resolved on the finer mesh. For the estimation of wind gust disaster the peak wind acting on buildings and structures has to be correctly predicted. In the case of meteorological model the velocity fluctuations have a tendency of diffusive variation without the high frequency component due to the numerically filtering effects. In order to predict the peak value of wind velocity with good accuracy, this paper proposes a LES-based method for generating the higher frequency components of velocity and temperature fields obtained by meteorological model.

Application of a Meso-scale Based Ballistic Fabric Model to the Development of Advanced Lightweight Engine Fan Blade-Out Containment Structure

DTIC Science & Technology

2012-09-01

composed of a basic metallic shell structure with a dry Kevlar wrap around it is considered. The fan blade is made of titanium alloy modeled by a Johnson...material. A multilayered Kevlar woven dry fabric structure is wrapped around the thin aluminum shell to form a soft hybrid fan case. A woven fabric material...debris protection fan case composed of a basic metallic shell structure with a dry Kevlar wrap around it is considered. The fan blade is made of titanium

Beta diversity at different spatial scales: plant communities in organic and conventional agriculture.

PubMed

Gabriel, Doreen; Roschewitz, Indra; Tscharntke, Teja; Thies, Carsten

2006-10-01

Biodiversity studies that guide agricultural subsidy policy have generally compared farming systems at a single spatial scale: the field. However, diversity patterns vary across spatial scales. Here, we examined the effects of farming system (organic vs. conventional) and position in the field (edge vs. center) on plant species richness in wheat fields at three spatial scales. We quantified alpha-, beta-, and gamma-diversity at the microscale in 800 plots, at the mesoscale in 40 fields, and at the macroscale in three regions using the additive partitioning approach, and evaluated the relative contribution of beta-diversity at each spatial scale to total observed species richness. We found that alpha-, beta-, and gamma-diversity were higher in organic than conventional fields and higher at the field edge than in the field center at all spatial scales. In both farming systems, beta-diversity at the meso- and macroscale explained most of the overall species richness (up to 37% and 25%, respectively), indicating considerable differences in community composition among fields and regions due to environmental heterogeneity. The spatial scale at which beta-diversity contributed the most to overall species richness differed between rare and common species. Total richness of rare species (present in < or = 5% of total samples) was mainly explained by differences in community composition at the meso- and macroscale (up to 27% and 48%, respectively), but only in organic fields. Total richness of common species (present in > or = 25% of total samples) was explained by differences in community composition at the micro- and mesoscale (up to 29% and 47%, respectively), i.e., among plots and fields, independent of farming system. Our results show that organic farming made the greatest contribution to total species richness at the meso (among fields) and macro (among regions) scale due to environmental heterogeneity. Hence, agri-environment schemes should exploit this large-scale contribution of beta-diversity by tailoring schemes at regional scales to maximize dissimilarity between conservation areas using geographic information systems rather than focusing entirely at the classical local-field scale, which is the current practice.

Hierarchical Materials Design by Pattern Transfer Printing of Self-Assembled Binary Nanocrystal Superlattices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Paik, Taejong; Yun, Hongseok; Fleury, Blaise

We demonstrate the fabrication of hierarchical materials by controlling the structure of highly ordered binary nanocrystal superlattices (BNSLs) on multiple length scales. Combinations of magnetic, plasmonic, semiconducting, and insulating colloidal nanocrystal (NC) building blocks are self-assembled into BNSL membranes via the liquid–interfacial assembly technique. Free-standing BNSL membranes are transferred onto topographically structured poly(dimethylsiloxane) molds via the Langmuir–Schaefer technique and then deposited in patterns onto substrates via transfer printing. BNSLs with different structural motifs are successfully patterned into various meso- and microstructures such as lines, circles, and even three-dimensional grids across large-area substrates. A combination of electron microscopy and grazing incidencemore » small-angle X-ray scattering (GISAXS) measurements confirm the ordering of NC building blocks in meso- and micropatterned BNSLs. This technique demonstrates structural diversity in the design of hierarchical materials by assembling BNSLs from NC building blocks of different composition and size by patterning BNSLs into various size and shape superstructures of interest for a broad range of applications.« less

Improved analysis and visualization of friction loop data: unraveling the energy dissipation of meso-scale stick-slip motion

NASA Astrophysics Data System (ADS)

Kokorian, Jaap; Merlijn van Spengen, W.

2017-11-01

In this paper we demonstrate a new method for analyzing and visualizing friction force measurements of meso-scale stick-slip motion, and introduce a method for extracting two separate dissipative energy components. Using a microelectromechanical system tribometer, we execute 2 million reciprocating sliding cycles, during which we measure the static friction force with a resolution of \

Performance Assessment of Discontinuous Fibers in Fiber Reinforced Concrete: Current State-of-the-Art

DTIC Science & Technology

2017-07-01

this report are not to be construed as an official Department of the Army position unless so designated by other authorized documents. DESTROY...non-destructively evaluate fiber distributions, orientation, and FRC posttest damage. This technique allows for a closer to meso scale investigation...performance all the while optimizing the material and improving desired performance by designing materials based on individual constituent

Microbial community shifts in a farm-scale anaerobic digester treating swine waste: Correlations between bacteria communities associated with hydrogenotrophic methanogens and environmental conditions.

PubMed

Cho, Kyungjin; Shin, Seung Gu; Kim, Woong; Lee, Joonyeob; Lee, Changsoo; Hwang, Seokhwan

2017-12-01

Microbial community structure in a farm-scale anaerobic digester treating swine manure was investigated during three process events: 1) prolonged starvation, and changes of 2) operating temperature (between meso- and thermophilic) and 3) hydraulic retention time (HRT). Except during the initial period, the digester was dominated by hydrogenotrophic methanogens (HMs). The bacterial community structure significantly shifted with operating temperature and HRT but not with long-term starvation. Clostridiales (26.5-54.4%) and Bacteroidales (2.5-13.7%) became dominant orders in the digester during the period of HM dominance. Abundance of diverse meso- and thermophilic bacteria increased during the same period; many of these species may be H 2 producers, and/or syntrophic acetate oxidizers. Some of these species showed positive correlations with [NH 4 + -N] (p<0.1); this relationship suggests that ammonia was a significant parameter for bacterial selection. The bacterial niche information reported in this study can be useful to understand the ecophysiology of anaerobic digesters treating swine manure that contains high ammonia content. Copyright © 2017 Elsevier B.V. All rights reserved.

The Solomon Sea eddy activity from a 1/36° regional model

NASA Astrophysics Data System (ADS)

Djath, Bughsin; Babonneix, Antoine; Gourdeau, Lionel; Marin, Frédéric; Verron, Jacques

2013-04-01

In the South West Pacific, the Solomon Sea exhibits the highest levels of eddy kinetic energy but relatively little is known about the eddy activity in this region. This Sea is directly influenced by a monsoonal regime and ENSO variability, and occupies a strategical location as the Western Boundary Currents exiting it are known to feed the warm pool and to be the principal sources of the Equatorial UnderCurrent. During their transit in the Solomon Sea, meso-scale eddies are suspected to notably interact and influence these water masses. The goal of this study is to give an exhaustive description of this eddy activity. A dual approach, based both on altimetric data and high resolution modeling, has then been chosen for this purpose. First, an algorithm is applied on nearly 20 years of 1/3° x 1/3° gridded SLA maps (provided by the AVISO project). This allows eddies to be automatically detected and tracked, thus providing some basic eddy properties. The preliminary results show that two main and distinct types of eddies are detected. Eddies in the north-eastern part shows a variability associated with the mean structure, while those in the southern part are associated with generation/propagation processes. However, the resolution of the AVISO dataset is not very well suited to observe fine structures and to match with the numerous islands bordering the Solomon Sea. For this reason, we will confront these observations with the outputs of a 1/36° resolution realistic model of the Solomon Sea. The high resolution numerical model (1/36°) indeed permits to reproduce very fine scale features, such as eddies and filaments. The model is two-way embedded in a 1/12° regional model which is itself one-way embedded in the DRAKKAR 1/12° global model. The NEMO code is used as well as the AGRIF software for model nestings. Validation is realized by comparison with AVISO observations and available in situ data. In preparing the future wide-swath altimetric SWOT mission that is expected to provide observations of small-scale sea level variability, spectral analysis is performed from the 1/36° resolution realistic model in order to characterize the finer scale signals in the Solomon sea region. The preliminary SSH spectral analysis shows a k-4 slope, in good agreement with the suface quasigeostrophic (SQG) turbulence theory. Keywords: Solomon Sea; meso-scale activity; eddy detection, tracking and properties; wavenumber spectrum.

Content validity and electronic PRO (ePRO) usability of the Lung Cancer Symptom Scale-Mesothelioma (LCSS-Meso) in mesothelioma patients.

PubMed

Gelhorn, Heather L; Skalicky, Anne M; Balantac, Zaneta; Eremenco, Sonya; Cimms, Tricia; Halling, Katarina; Hollen, Patricia J; Gralla, Richard J; Mahoney, Martin C; Sexton, Chris

2018-07-01

Obtaining qualitative data directly from the patient perspective enhances the content validity of patient-reported outcome (PRO) instruments. The objective of this qualitative study was to evaluate the content validity of the Lung Cancer Symptom Scale for Mesothelioma (LCSS-Meso) and its usability on an electronic device. A cross-sectional methodological study, using a qualitative approach, was conducted among patients recruited from four clinical sites. The primary target population included patients with pleural mesothelioma; data were also collected from patients with peritoneal mesothelioma on an exploratory basis. Semi-structured interviews were conducted consisting of concept elicitation, cognitive interviewing, and evaluation of electronic patient-reported outcome (ePRO) usability. Participants (n = 21) were interviewed in person (n = 9) or by telephone (n = 12); 71% were male with a mean age of 69 years (SD = 14). The most common signs and symptoms experienced by participants with pleural mesothelioma (n = 18) were shortness of breath, fluid build-up, pain, fatigue, coughing, and appetite loss. The most commonly described symptoms for those with peritoneal mesothelioma (n = 4) were bloating, changes in appetite, fatigue, fluid build-up, shortness of breath, and pain. Participants with pleural mesothelioma commonly described symptoms assessed by the LCSS-Meso in language consistent with the questionnaire and a majority understood and easily completed each of the items. The ePRO version was easy to use, and there was no evidence that the electronic formatting changed the way participants responded to the questions. Results support the content validity of the LCSS-Meso and the usability of the electronic format for use in assessing symptoms among patients with pleural mesothelioma.

Coastal Foredune Evolution, Part 2: Modeling Approaches for Meso-Scale Morphologic Evolution

DTIC Science & Technology

2017-03-01

ERDC/CHL CHETN-II-57 March 2017 Approved for public release; distribution is unlimited. Coastal Foredune Evolution, Part 2: Modeling Approaches...for Meso-Scale Morphologic Evolution by Margaret L. Palmsten1, Katherine L. Brodie2, and Nicholas J. Spore2 PURPOSE: This Coastal and Hydraulics...Engineering Technical Note (CHETN) is the second of two CHETNs focused on improving technologies to forecast coastal foredune evolution. Part 1

Development of Powder Processing Models and Techniques for Meso-scale Devices: Perspirable Skin

DTIC Science & Technology

2008-03-31

of Powder Processing Models and Techniques for Meso-scale Devices: Perspirable Skin Contract Number ...Skin 5a. CONTRACT NUMBER 5b. GRANT NUMBER FA9550-05-1-0202 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) Patrick Kwon, Michigan State University 5d...PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) Patrick Kwon Department of

Short-Pulse Laser-Matter Computational Workshop Proceedings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Town, R; Tabak, M

For three days at the end of August 2004, 55 plasma scientists met at the Four Points by Sheraton in Pleasanton to discuss some of the critical issues associated with the computational aspects of the interaction of short-pulse high-intensity lasers with matter. The workshop was organized around the following six key areas: (1) Laser propagation/interaction through various density plasmas: micro scale; (2) Anomalous electron transport effects: From micro to meso scale; (3) Electron transport through plasmas: From meso to macro scale; (4) Ion beam generation, transport, and focusing; (5) ''Atomic-scale'' electron and proton stopping powers; and (6) K{alpha} diagnostics.

Atmospheric Dynamics of Sub-Tropical Dust Storms

NASA Astrophysics Data System (ADS)

Pokharel, Ashok Kumar

Meso-alpha/beta scale observational and meso-beta/gamma scale numerical model analyses were performed to study the atmospheric dynamics responsible for generating Harmattan, Saudi Arabian, and Bodele Depression dust storms. For each dust storm case study, MERRA reanalysis datasets, WRF simulated very high resolution datasets, MODIS/Aqua and Terra images, EUMETSAT images, NAAPS aerosol modelling plots, CALIPSO images, surface observations, and rawinsonde soundings were analyzed. The analysis of each dust storm carried out separately and an in-depth comparison of the events shows some similarities among the three case studies: (1) the presence of a well-organized baroclinic synoptic scale system, (2) small scale dust emission events which occurred prior to the formation of the primary large-scale dust storms, (3) cross mountain flows which produced a strong leeside inversion layer prior to the large scale dust storm, (4) the presence of thermal wind imbalance in the exit region of the mid-tropospheric jet streak in the lee of the mountains shortly after the time of the inversion formation, (5) major dust storm formation was accompanied by large magnitude ageostrophic isallobaric low-level winds as part of the meso-beta scale adjustment process, (6) substantial low-level turbulence kinetic energy (TKE), (7) formation in the lee of nearby mountains, and (8) the emission of the dust occurred initially in narrow meso-beta scale zones parallel to the mountains, and later reached the meso-alpha scale when suspended dust was transported away from the mountains. In addition to this there were additional meso-beta scale and meso-gamma scale adjustment processes resulting in Kelvin waves in the Harmattan and the Bodele Depression cases and the thermally-forced MPS circulation in all of these three cases. The Kelvin wave preceded a cold pool accompanying the air behind the large scale cold front instrumental in the major dust storm. The Kelvin wave organized the major dust storm in a narrow zone parallel to the mountains before it expanded upscale. The thermally-forced meos-gamma scale adjustment processes, which occurred in the canyons/small valleys, resulted in the numerous dust streaks leading to the entry of the dust into the atmosphere due to the presence of significant vertical motion and the TKE generation. This indicates that there were meso-beta to meso-gamma scale adjustment processes at the lower levels after the imbalance within the exit region of the upper level jet streaks and these processes were responsible for causing the large scale dust storms. Most notably, the sub-tropical jet streak caused the dust storm nearer to the equatorial region after its interaction with the thermally perturbed air mass on the lee of the Tibesti Mountains in the Bodele case study, which is different than the two other cases where the polar jet streaks played this same role at higher latitudes. This represents an original finding. Additionally, a climatological analysis of 15 years (1997-2011) of dust events over the NASA Dryden Flight Research Center (DFRC) in the desert of Southern California was performed to evaluate how the extratropical systems influenced the cause of dust storms over this region. This study indicates that dust events were associated with the development of a deep convective boundary layer, turbulent kinetic energy ≥3 J/kg, a lapse rate between dry adiabatic and moist adiabatic, wind speed above the frictional threshold wind speed necessary to ablate dust from the surface (≥7.3m/s), above the surface the presence of a cold trough, and strong cyclonic jet. These processes are similar in many ways to the dynamics in the other subtropical case studies. This also indicated that the annual mean number of dust events, their mean duration, and the unit duration per number of event were positively correlated with each of the visibility ranges, when binned for <11.2km, <8km, <4.8km, <1.6km, and <1km. The percentage of the dust events by season show that most of the dust events occurred in autumn (44.7%), followed by spring (38.3%) and equally in summer and winter with these seasons each accounting for 8.5% of events.

High-frequency and meso-scale winter sea-ice variability in the Southern Ocean in a high-resolution global ocean model

NASA Astrophysics Data System (ADS)

Stössel, Achim; von Storch, Jin-Song; Notz, Dirk; Haak, Helmuth; Gerdes, Rüdiger

2018-03-01

This study is on high-frequency temporal variability (HFV) and meso-scale spatial variability (MSV) of winter sea-ice drift in the Southern Ocean simulated with a global high-resolution (0.1°) sea ice-ocean model. Hourly model output is used to distinguish MSV characteristics via patterns of mean kinetic energy (MKE) and turbulent kinetic energy (TKE) of ice drift, surface currents, and wind stress, and HFV characteristics via time series of raw variables and correlations. We find that (1) along the ice edge, the MSV of ice drift coincides with that of surface currents, in particular such due to ocean eddies; (2) along the coast, the MKE of ice drift is substantially larger than its TKE and coincides with the MKE of wind stress; (3) in the interior of the ice pack, the TKE of ice drift is larger than its MKE, mostly following the TKE pattern of wind stress; (4) the HFV of ice drift is dominated by weather events, and, in the absence of tidal currents, locally and to a much smaller degree by inertial oscillations; (5) along the ice edge, the curl of the ice drift is highly correlated with that of surface currents, mostly reflecting the impact of ocean eddies. Where ocean eddies occur and the ice is relatively thin, ice velocity is characterized by enhanced relative vorticity, largely matching that of surface currents. Along the ice edge, ocean eddies produce distinct ice filaments, the realism of which is largely confirmed by high-resolution satellite passive-microwave data.

Integrated Modeling and Experimental Studies at the Meso Scale for Advanced Reactive Materials

DTIC Science & Technology

2016-07-01

T E C H N IC A L R E P O R T DTRA-TR-16-76 Integrated Modeling and Experimental Studies at the Meso- Scale for Advanced Reactive Materials ...study the energy release processes that thermitic and/or exothermic intermetallic reactive materials experience when they are subjected to...thermitic and/or exothermic intermetallic materials experience when they are subjected to sustained shock loading. Data from highly spatially and

Multi-Scale Effects in the Strength of Ceramics

PubMed Central

Cook, Robert F.

2016-01-01

Multiple length-scale effects are demonstrated in indentation-strength measurements of a range of ceramic materials under inert and reactive conditions. Meso-scale effects associated with flaw disruption by lateral cracking at large indentation loads are shown to increase strengths above the ideal indentation response. Micro-scale effects associated with toughening by microstructural restraints at small indentation loads are shown to decrease strengths below the ideal response. A combined meso-micro-scale analysis is developed that describes ceramic inert strength behaviors over the complete indentation flaw size range. Nano-scale effects associated with chemical equilibria and crack velocity thresholds are shown to lead to invariant minimum strengths at slow applied stressing rates under reactive conditions. A combined meso-micro-nano-scale analysis is developed that describes the full range of reactive and inert strength behaviors as a function of indentation load and applied stressing rate. Applications of the multi-scale analysis are demonstrated for materials design, materials selection, toughness determination, crack velocity determination, bond-rupture parameter determination, and prediction of reactive strengths. The measurements and analysis provide strong support for the existence of sharp crack tips in ceramics such that the nano-scale mechanisms of discrete bond rupture are separate from the larger scale crack driving force mechanics characterized by continuum-based stress-intensity factors. PMID:27563150

Physical Habitat Characteristics on the North Fork Shenandoah River, VA in 2002-2003

USGS Publications Warehouse

Krstolic, Jennifer L.; Hayes, Donald C.; Ruhl, Peter M.

2010-01-01

This dataset was collected with a PLGR government-issue GPS, and through manual measurement in the field. Points were gathered while canoeing along the North Fork Shenandoah River. Each location marked a change in meso-scale habitat type. GPS points were supplemented with GIS-derived points in areas where manual measurements were made. The points were used to generate a line coverage. This coverage represents physical habitat at a meso-scale (width of stream).

Combined meso-scale modeling and experimental investigation of the effect of mechanical damage on the transport properties of cementitious composites

NASA Astrophysics Data System (ADS)

Raghavan, Balaji; Niknezhad, Davood; Bernard, Fabrice; Kamali-Bernard, Siham

2016-09-01

The transport properties of cementitious composites such as concrete are important indicators of their durability, and are known to be heavily influenced by mechanical loading. In the current work, we use meso-scale hygro-mechanical modeling with a morphological 3D two phase mortar-aggregate model, in conjunction with experimentally obtained properties, to investigate the coupling between mechanical loading and damage and the permeability of the composite. The increase in permeability of a cylindrical test specimen at 28% aggregate fraction during a uniaxial displacement-controlled compression test at 85% of the peak load was measured using a gas permeameter. The mortar's mechanical behavior is assumed to follow the well-known compression damaged plasticity (CDP) model with isotropic damage, at varying thresholds, and obtained from different envelope curves. The damaged intrinsic permeability of the mortar evolves according to a logarithmic matching law with progressive loading. We fit the matching law parameters to the experimental result for the test specimen by inverse identification using our meso-scale model. We then subject a series of virtual composite specimens to quasi-static uniaxial compressive loading with varying boundary conditions to obtain the simulated damage and strain evolutions, and use the damage data and the previously identified parameters to determine the evolution of the macroscopic permeability tensor for the specimens, using a network model. We conduct a full parameter study by varying aggregate volume fraction, granulometric distribution, loading/boundary conditions and "matching law" parameters, as well as for different strain-damage thresholds and uniaxial loading envelope curves. Based on this study, we propose Avrami equation-based upper and lower bounds for the evolution of the damaged permeability of the composite.

Structural parallels between terrestrial microbialites and Martian sediments: are all cases of `Pareidolia'?

NASA Astrophysics Data System (ADS)

Rizzo, Vincenzo; Cantasano, Nicola

2017-10-01

The study analyses possible parallels of the microbialite-known structures with a set of similar settings selected by a systematic investigation from the wide record and data set of images shot by NASA rovers. Terrestrial cases involve structures both due to bio-mineralization processes and those induced by bacterial metabolism, that occur in a dimensional field longer than 0.1 mm, at micro, meso and macro scales. The study highlights occurrence on Martian sediments of widespread structures like microspherules, often organized into some higher-order settings. Such structures also occur on terrestrial stromatolites in a great variety of `Microscopic Induced Sedimentary Structures', such as voids, gas domes and layer deformations of microbial mats. We present a suite of analogies so compelling (i.e. different scales of morphological, structural and conceptual relevance), to make the case that similarities between Martian sediment structures and terrestrial microbialites are not all cases of `Pareidolia'.

Nonholonomic Hamiltonian Method for Meso-macroscale Simulations of Reacting Shocks

NASA Astrophysics Data System (ADS)

Fahrenthold, Eric; Lee, Sangyup

2015-06-01

The seamless integration of macroscale, mesoscale, and molecular scale models of reacting shock physics has been hindered by dramatic differences in the model formulation techniques normally used at different scales. In recent research the authors have developed the first unified discrete Hamiltonian approach to multiscale simulation of reacting shock physics. Unlike previous work, the formulation employs reacting themomechanical Hamiltonian formulations at all scales, including the continuum. Unlike previous work, the formulation employs a nonholonomic modeling approach to systematically couple the models developed at all scales. Example applications of the method show meso-macroscale shock to detonation simulations in nitromethane and RDX. Research supported by the Defense Threat Reduction Agency.

Modeling process-structure-property relationships for additive manufacturing

NASA Astrophysics Data System (ADS)

Yan, Wentao; Lin, Stephen; Kafka, Orion L.; Yu, Cheng; Liu, Zeliang; Lian, Yanping; Wolff, Sarah; Cao, Jian; Wagner, Gregory J.; Liu, Wing Kam

2018-02-01

This paper presents our latest work on comprehensive modeling of process-structure-property relationships for additive manufacturing (AM) materials, including using data-mining techniques to close the cycle of design-predict-optimize. To illustrate the processstructure relationship, the multi-scale multi-physics process modeling starts from the micro-scale to establish a mechanistic heat source model, to the meso-scale models of individual powder particle evolution, and finally to the macro-scale model to simulate the fabrication process of a complex product. To link structure and properties, a highefficiency mechanistic model, self-consistent clustering analyses, is developed to capture a variety of material response. The model incorporates factors such as voids, phase composition, inclusions, and grain structures, which are the differentiating features of AM metals. Furthermore, we propose data-mining as an effective solution for novel rapid design and optimization, which is motivated by the numerous influencing factors in the AM process. We believe this paper will provide a roadmap to advance AM fundamental understanding and guide the monitoring and advanced diagnostics of AM processing.

Global Modeling of Internal Tides Within an Eddying Ocean General Circulation Model

DTIC Science & Technology

2012-06-01

atmosphere and ocean (Yu and Weller, 2007 ). Salinities in the upper ocean are set by the difference between evaporation and precipitation at the ocean...surface (Yu, 2007 ; Schmitt, 2008). Because the buoyancy (density) of seawater at the ocean surface is con- trolled by temperature and salinity, the...days, these currents mean- der and generate highly energetic meso- scale eddies (Schmitz, 1996a,b; Stammer , 1997), the spinning oceanic dynamical

Integrated detection of fractures and caves in carbonate fractured-vuggy reservoirs based on seismic data and well data

NASA Astrophysics Data System (ADS)

Cao, Zhanning; Li, Xiangyang; Sun, Shaohan; Liu, Qun; Deng, Guangxiao

2018-04-01

Aiming at the prediction of carbonate fractured-vuggy reservoirs, we put forward an integrated approach based on seismic and well data. We divide a carbonate fracture-cave system into four scales for study: micro-scale fracture, meso-scale fracture, macro-scale fracture and cave. Firstly, we analyze anisotropic attributes of prestack azimuth gathers based on multi-scale rock physics forward modeling. We select the frequency attenuation gradient attribute to calculate azimuth anisotropy intensity, and we constrain the result with Formation MicroScanner image data and trial production data to predict the distribution of both micro-scale and meso-scale fracture sets. Then, poststack seismic attributes, variance, curvature and ant algorithms are used to predict the distribution of macro-scale fractures. We also constrain the results with trial production data for accuracy. Next, the distribution of caves is predicted by the amplitude corresponding to the instantaneous peak frequency of the seismic imaging data. Finally, the meso-scale fracture sets, macro-scale fractures and caves are combined to obtain an integrated result. This integrated approach is applied to a real field in Tarim Basin in western China for the prediction of fracture-cave reservoirs. The results indicate that this approach can well explain the spatial distribution of carbonate reservoirs. It can solve the problem of non-uniqueness and improve fracture prediction accuracy.

Atomistic- and Meso-Scale Computational Simulations for Developing Multi-Timescale Theory for Radiation Degradation in Electronic and Optoelectronic Devices

DTIC Science & Technology

2017-02-13

3550 Aberdeen Ave., SE 11. SPONSOR/MONITOR’S REPORT Kirtland AFB, NM 87117-5776 NUMBER(S) AFRL -RV-PS-TR-2016-0161 12. DISTRIBUTION / AVAILABILITY...RVIL Kirtland AFB, NM 87117-5776 2 cys Official Record Copy AFRL /RVSW/David Cardimona 1 cy 22 Approved for public release; distribution is unlimited. ... AFRL -RV-PS- AFRL -RV-PS- TR-2016-0161 TR-2016-0161 ATOMISTIC- AND MESO-SCALE COMPUTATIONAL SIMULATIONS FOR DEVELOPING MULTI-TIMESCALE THEORY FOR

Meso-scale turbulence in living fluids

NASA Astrophysics Data System (ADS)

Dunkel, Jorn; Wensink, Rik; Heidenreich, Sebastian; Drescher, Knut; Goldstein, Ray; Loewen, Hartmut; Yeomans, Julia

2012-11-01

The mathematical characterization of turbulence phenomena in active non-equilibrium fluids proves even more difficult than for conventional liquids or gases. It is not known which features of turbulent phases in living matter are universal or system-specific, or which generalizations of the Navier-Stokes equations are able to describe them adequately. We combine experiments, particle simulations, and continuum theory to identify the statistical properties of self-sustained meso-scale turbulence in active systems. To study how dimensionality and boundary conditions affect collective bacterial dynamics, we measured energy spectra and structure functions in dense Bacillus subtilis suspensions in quasi-2D and 3D geometries. Our experimental results for the bacterial flow statistics agree well with predictions from a minimal model for self-propelled rods, suggesting that at high concentrations the collective motion of the bacteria is dominated by short-range interactions. To provide a basis for future theoretical studies, we propose a minimal continuum model for incompressible bacterial flow. A detailed numerical analysis of the 2D case shows that this theory can reproduce many of the experimentally observed features of self-sustained active turbulence. Supported by the ERC, EPSRC and DFG.

Meso scale MEMS inertial switch fabricated using an electroplated metal-on-insulator process

NASA Astrophysics Data System (ADS)

Gerson, Y.; Schreiber, D.; Grau, H.; Krylov, S.

2014-02-01

In this work, we report on a novel simple yet robust two-mask metal-on-insulator (MOI) process and illustrate its implementation for the fabrication of a meso scale MEMS inertial switch. The devices were fabricated of a ˜40 µm thick layer of nickel electrodeposited on top of a 4 µm thick thermal field oxide (TOX) covering a single crystal silicon wafer. A 40 µm thick layer of KMPR® resist was used as a mold and allowed the formation of high-aspect-ratio (1:5) metal structures. The devices were released by the sacrificial etching of the TOX layer in hydrofluoric acid. The fabricated devices were mounted in a ceramic enclosure and were characterized using both an electromagnet shaker and a drop tester. The functionality of the switch, aimed to trigger an electrical circuit when subjected to an acceleration pulse with amplitude of 300 g and duration of 200 µs, was demonstrated experimentally and the performance targets were achieved. The experimental results were consistent with the model predictions obtained through finite element simulations.

Meso-pores carbon nano-tubes (CNTs) tissues-perfluorocarbons (PFCs) hybrid air-electrodes for Li-O2 battery

NASA Astrophysics Data System (ADS)

Balaish, Moran; Ein-Eli, Yair

2018-03-01

Adding immiscible perfluorocarbons (PFCs), possessing superior oxygen solubility and diffusivity, to a free-standing (metal-free and binder-free) CNTs air-electrode tissues with a meso-pore structure, fully maximized the advantages of PFCs as oxygenated-species' channels-providers. The discharge behavior of hybrid PFCs-CNT Li-O2 systems demonstrated a drastic increase in cell capacity at high current density (0.2 mA cm-2), where oxygen transport limitations are best illustrated. The results of this research revealed several key factors affecting PFCs-Li-O2 systems. The incorporation of PFCs with higher superoxide solubility and oxygen diffusivity, but more importantly higher PFCs/electrolyte miscibility, in a meso-pore air-electrode enabled better exploitation of PFCs potential. Consequently, the utilization of the air-electrode' surface area was enhanced via the formation of artificial three phase reaction zones with additional oxygen transportation routes, leading to uniform and intimate Li2O2 deposit at areas further away from the oxygen reservoir. Associated mechanisms are discussed along with insights into an improved Li-O2 battery system.

Optimization of macropore evolution towards high photocatalytic activity enhancement in meso/macro porous Anatase TiO2

NASA Astrophysics Data System (ADS)

Nair, Radhika V.; Gayathri, P. K.; Siva Gummaluri, Venkata; Vijayan, C.

2017-01-01

We report on an optimization strategy for macro pore evolution leading to the design of highly photocatalytic 3D hierarchical meso/macroporous TiO2 via much simpler, faster and cost effective synthesis scheme. Meso/macro porous TiO2 is an excellent candidate material for photocatalytic applications owing to the availability of internal surfaces as active sites for redox reactions. The current research scenario focuses on the design of highly efficient photocatalytic systems as well as rapid, facile and cost effective methods of synthesis and optimization of parameters. The present report is on the gradual evolution of macropores in anatase TiO2 by the effective control of pH of the solvent, reaction time, temperature, solvent ratio and reactant concentration via a facile hydrothermal method in this regard. 3D hierarchical macroporous structures are obtained at pH 7 within a comparatively short reaction time of 5 h and demonstrated to be highly photocatalytic (with rate constant four times that of P25 nanoparticles) through photodegradation of Rhodamine B dye.

Meso and micro-scale response of post carbon removal nitrifying MBBR biofilm across carrier type and loading.

PubMed

Young, Bradley; Banihashemi, Bahman; Forrest, Daina; Kennedy, Kevin; Stintzi, Alain; Delatolla, Robert

2016-03-15

This study investigates the effects of three specific moving bed biofilm reactor (MBBR) carrier types and two surface area loading rates on biofilm thickness, morphology and bacterial community structure of post carbon removal nitrifying MBBR systems along with the effects of carrier type and loading on ammonia removal rates and effluent solids settleability. The meso and micro analyses show that the AOB kinetics vary based on loading condition, but irrespective of carrier type. The meso-scale response to increases in loading was shown to be an increase in biofilm thickness with higher surface area carriers being more inclined to develop and maintain thicker biofilms. The pore spaces of these higher surface area to volume carriers also demonstrated the potential to become clogged at higher loading conditions. Although the biofilm thickness increased during higher loading conditions, the relative percentages of both the embedded viable and non-viable cells at high and conventional loading conditions remained stable; indicating that the reduced ammonia removal kinetics observed during carrier clogging events is likely due to the observed reduction in the surface area of the attached biofilm. Microbial community analyses demonstrated that the dominant ammonia oxidizing bacteria for all carriers is Nitrosomonas while the dominant nitrite oxidizing bacteria is Nitrospira. The research showed that filamentous species were abundant under high loading conditions, which likely resulted in the observed reduction in effluent solids settleability at high loading conditions as opposed to conventional loading conditions. Although the settleability of the effluent solids was correlated to increases in abundances of filamentous organisms in the biofilm, analyzed using next generation sequencing, the ammonia removal rate was not shown to be directly correlated to specific meso or micro-scale characteristics. Instead post carbon removal MBBR ammonia removal kinetics were shown to be related to the viable AOB cell coverage of the carriers; which was calculated by normalizing the surface area removal rate by the biofilm thickness, the bacterial percent abundance of ammonia oxidizing bacteria and the percentage of viable cells. Copyright © 2016 Elsevier Ltd. All rights reserved.

Three-dimensional analysis of anisotropic spatially reinforced structures

NASA Technical Reports Server (NTRS)

Bogdanovich, Alexander E.

1993-01-01

The material-adaptive three-dimensional analysis of inhomogeneous structures based on the meso-volume concept and application of deficient spline functions for displacement approximations is proposed. The general methodology is demonstrated on the example of a brick-type mosaic parallelepiped arbitrarily composed of anisotropic meso-volumes. A partition of each meso-volume into sub-elements, application of deficient spline functions for a local approximation of displacements and, finally, the use of the variational principle allows one to obtain displacements, strains, and stresses at anypoint within the structural part. All of the necessary external and internal boundary conditions (including the conditions of continuity of transverse stresses at interfaces between adjacent meso-volumes) can be satisfied with requisite accuracy by increasing the density of the sub-element mesh. The application of the methodology to textile composite materials is described. Several numerical examples for woven and braided rectangular composite plates and stiffened panels under transverse bending are considered. Some typical effects of stress concentrations due to the material inhomogeneities are demonstrated.

Borneo vortex and mesoscale convective rainfall

NASA Astrophysics Data System (ADS)

Koseki, S.; Koh, T.-Y.; Teo, C.-K.

2014-05-01

We have investigated how the Borneo vortex develops over the equatorial South China Sea under cold surge conditions in December during the Asian winter monsoon. Composite analysis using reanalysis and satellite data sets has revealed that absolute vorticity and water vapour are transported by strong cold surges from upstream of the South China Sea to around the Equator. Rainfall is correspondingly enhanced over the equatorial South China Sea. A semi-idealized experiment reproduced the Borneo vortex over the equatorial South China Sea during a "perpetual" cold surge. The Borneo vortex is manifested as a meso-α cyclone with a comma-shaped rainband in the northeast sector of the cyclone. Vorticity budget analysis showed that the growth/maintenance of the meso-α cyclone was achieved mainly by the vortex stretching. This vortex stretching is due to the upward motion forced by the latent heat release around the cyclone centre. The comma-shaped rainband consists of clusters of meso-β-scale rainfall cells. The intense rainfall in the comma head (comma tail) is generated by the confluence of the warmer and wetter cyclonic easterly flow (cyclonic southeasterly flow) and the cooler and drier northeasterly surge in the northwestern (northeastern) sector of the cyclone. Intense upward motion and heavy rainfall resulted due to the low-level convergence and the favourable thermodynamic profile at the confluence zone. In particular, the convergence in the northwestern sector is responsible for maintenance of the meso-α cyclone system. At both meso-α and meso-β scales, the convergence is ultimately caused by the deviatoric strain in the confluence wind pattern but is significantly self-enhanced by the nonlinear dynamics.

A mechanism for the formation and sustainment of the self-organized global profile and E   ×   B staircase in tokamak plasmas

NASA Astrophysics Data System (ADS)

Wang, W.; Kishimoto, Y.; Imadera, K.; Li, J. Q.; Wang, Z. X.

2018-05-01

The mechanism for the formation and sustainment of a self-organized global profile and the ‘ E   ×   B staircase’ are investigated through simulations of a flux-driven ion temperature gradient (ITG) turbulence based on GKNET, a 5D global gyrokinetic code. The staircase is found to be initiated from the radially extended ITG mode structures with nearly up-down symmetry during the saturation phase, and is established as it evolves into a quasi-steady turbulence, leading to a self-organized global temperature profile and to meso-scale isomorphic profiles of the radial electric field and the temperature gradient. It is found that the quasi-regular E   ×   B shear flow pattern is primarily originated from an even-symmetrical zonal flow produced by the extended ITG mode, which flow pattern exhibits an in-phase relation with the mean flow variation induced by the temperature relaxation. Consequently, the staircase is initiated through the profiles of total electric field and temperature gradient with a self-organized manner. Since the sign of E   ×   B shear flow at the central part are opposite to that at both edges, it disintegrates the ITG mode into smaller scale eddies. Meanwhile, smaller scale eddies tend to be aligned radially by spontaneous phase matching, which can provide the growth of mode amplitude and the formation of radially extended mode structures, leading to the bursty heat transport. This process is repeated quasi-periodically, sustaining self-organized structures and the E   ×   B staircase. Moreover, the equilibrium mean field is found to be of specific importance in causing the structures and dynamics from meso- to macro scales in toroidal plasmas.

Global Modeling of Internal Tides Within an Eddying Ocean General Circulation Model

DTIC Science & Technology

2012-05-31

heat between the atmosphere and ocean (Yu and Weller, 2007 ). Salinities in the upper ocean are set by the difference between evaporation and...precipitation at the ocean surface (Yu, 2007 ; Schmitt, 2008). Because the buoyancy (density) of seawater at the ocean surface is con- trolled by...timescales of about 10–200 days, these currents mean- der and generate highly energetic meso- scale eddies (Schmitz, 1996a,b; Stammer , 1997), the spinning

A Comparative Investigation of the use of Laminate-Level Meso-Scale and Fracture-Mechanics-Enriched Meso-Scale Composite-Material Models in Ballistic-Resistance Analyses

DTIC Science & Technology

2010-04-06

strain range (0.05, 0.5) Initial Velocity, m/s R es id ua lV el oc ity ,m /s 100 200 300 400 500 600 0 100 200 300 400 500 Laminate Scale Best Fit...DISTRIBUTION AVAILIBILITY STATEMENT Approved for public release; distribution is unlimited. UU 9. SPONSORING/MONITORING AGENCY NAME(S) AND ADDRESS( ES ) 6...state during loading is determined by integrating the rate-form of the Hooke’s law in the form: rij ¼ Cijkl ekl; el ¼ Cijkl ekl ekl;p ; ð19Þ where

Tip-induced nanoreactor for silicate

NASA Astrophysics Data System (ADS)

Gao, Ming; Ma, Liran; Liang, Yong; Gao, Yuan; Luo, Jianbin

2015-09-01

Nanoscale scientific issues have attracted an increasing amount of research interest due to their specific size-effect and novel structure-property. From macro to nano, materials present some unique chemical reactivity that bulk materials do not own. Here we introduce a facile method to generate silicate with nanoscale control based on the establishment of a confined space between a meso/nanoscale tungsten tip and a smooth silica/silicon substrate. During the process, local water-like droplets deposition can be obviously observed in the confinement between the Si/SiO2 surfaces and the KOH-modified tungsten tip. By the combination of in-situ optical microscopy and Raman spectroscopy, we were able to take a deep insight of both the product composition and the underlying mechanism of such phenomena. It was indicated that such nanoreactor for silicate could be quite efficient as a result of the local capillarity and electric field effect, with implications at both nano and meso scales.

Tip-induced nanoreactor for silicate.

PubMed

Gao, Ming; Ma, Liran; Liang, Yong; Gao, Yuan; Luo, Jianbin

2015-09-14

Nanoscale scientific issues have attracted an increasing amount of research interest due to their specific size-effect and novel structure-property. From macro to nano, materials present some unique chemical reactivity that bulk materials do not own. Here we introduce a facile method to generate silicate with nanoscale control based on the establishment of a confined space between a meso/nanoscale tungsten tip and a smooth silica/silicon substrate. During the process, local water-like droplets deposition can be obviously observed in the confinement between the Si/SiO2 surfaces and the KOH-modified tungsten tip. By the combination of in-situ optical microscopy and Raman spectroscopy, we were able to take a deep insight of both the product composition and the underlying mechanism of such phenomena. It was indicated that such nanoreactor for silicate could be quite efficient as a result of the local capillarity and electric field effect, with implications at both nano and meso scales.

Tip-induced nanoreactor for silicate

PubMed Central

Gao, Ming; Ma, Liran; Liang, Yong; Gao, Yuan; Luo, Jianbin

2015-01-01

Nanoscale scientific issues have attracted an increasing amount of research interest due to their specific size-effect and novel structure-property. From macro to nano, materials present some unique chemical reactivity that bulk materials do not own. Here we introduce a facile method to generate silicate with nanoscale control based on the establishment of a confined space between a meso/nanoscale tungsten tip and a smooth silica/silicon substrate. During the process, local water-like droplets deposition can be obviously observed in the confinement between the Si/SiO2 surfaces and the KOH-modified tungsten tip. By the combination of in-situ optical microscopy and Raman spectroscopy, we were able to take a deep insight of both the product composition and the underlying mechanism of such phenomena. It was indicated that such nanoreactor for silicate could be quite efficient as a result of the local capillarity and electric field effect, with implications at both nano and meso scales. PMID:26364882

Development of an integrated chemical weather prediction system for environmental applications at meso to global scales: NMMB/BSC-CHEM

NASA Astrophysics Data System (ADS)

Jorba, O.; Pérez, C.; Karsten, K.; Janjic, Z.; Dabdub, D.; Baldasano, J. M.

2009-09-01

This contribution presents the ongoing developments of a new fully on-line chemical weather prediction system for meso to global scale applications. The modeling system consists of a mineral dust module and a gas-phase chemistry module coupled on-line to a unified global-regional atmospheric driver. This approach allows solving small scale processes and their interactions at local to global scales. Its unified environment maintains the consistency of all the physico-chemical processes involved. The atmospheric driver is the NCEP/NMMB numerical weather prediction model (Janjic and Black, 2007) developed at National Centers for Environmental Prediction (NCEP). It represents an evolution of the operational WRF-NMME model extending from meso to global scales. Its unified non-hydrostatic dynamical core supports regional and global simulations. The Barcelona Supercomputing Center is currently designing and implementing a chemistry transport model coupled online with the new global/regional NMMB. The new modeling system is intended to be a powerful tool for research and to provide efficient global and regional chemical weather forecasts at sub-synoptic and mesoscale resolutions. The online coupling of the chemistry follows the approach similar to that of the mineral dust module already coupled to the atmospheric driver, NMMB/BSC-DUST (Pérez et al., 2008). Chemical species are advected and mixed at the corresponding time steps of the meteorological tracers using the same numerical scheme. Advection is eulerian, positive definite and monotone. The chemical mechanism and chemistry solver is based on the Kinetic PreProcessor KPP (Damian et al., 2002) package with the main purpose of maintaining a wide flexibility when configuring the model. Such approach will allow using a simplified chemical mechanism for global applications or a more complete mechanism for high-resolution local or regional studies. Moreover, it will permit the implementation of a specific configuration for forecasting applications in regional or global domains. An emission process allows the coupling of different emission inventories sources such as RETRO, EDGAR and GEIA for the global domain, EMEP for Europe and HERMES for Spain. The photolysis scheme is based on the Fast-J scheme, coupled with physics of each model layer (e.g., aerosols, clouds, absorbers as ozone) and it considers grid-scale clouds from the atmospheric driver. The dry deposition scheme follows the deposition velocity analogy for gases, enabling the calculation of deposition fluxes from airborne concentrations. No cloud-chemistry processes are included in the system yet (no wet deposition, scavenging and aqueous chemistry). The modeling system developments will be presented and first results of the gas-phase chemistry at global scale will be discussed. REFERENCES Janjic, Z.I., and Black, T.L., 2007. An ESMF unified model for a broad range of spatial and temporal scales, Geophysical Research Abstracts, 9, 05025. Pérez, C., Haustein, K., Janjic, Z.I., Jorba, O., Baldasano, J.M., Black, T.L., and Nickovic, S., 2008. An online dust model within the meso to global NMMB: current progress and plans. AGU Fall Meeting, San Francisco, A41K-03, 2008. Damian, V., Sandu, A., Damian, M., Potra, F., and Carmichael, G.R., 2002. The kinetic preprocessor KPP - A software environment for solving chemical kinetics. Comp. Chem. Eng., 26, 1567-1579. Sandu, A., and Sander, R., 2006. Technical note:Simulating chemical systems in Fortran90 and Matlab with the Kinetic PreProcessor KPP-2.1. Atmos. Chem. and Phys., 6, 187-195.

Shock compression response of cold-rolled Ni/Al multilayer composites

DOE PAGES

Specht, Paul E.; Weihs, Timothy P.; Thadhani, Naresh N.

2017-01-06

Uniaxial strain, plate-on-plate impact experiments were performed on cold-rolled Ni/Al multilayer composites and the resulting Hugoniot was determined through time-resolved measurements combined with impedance matching. The experimental Hugoniot agreed with that previously predicted by two dimensional (2D) meso-scale calculations. Additional 2D meso-scale simulations were performed using the same computational method as the prior study to reproduce the experimentally measured free surface velocities and stress profiles. Finally, these simulations accurately replicated the experimental profiles, providing additional validation for the previous computational work.

Meso and Micro Scale Propulsion Concepts for Small Spacecraft

DTIC Science & Technology

2005-06-14

the inner diameter of the fuel jet tube was 500 gm, while the inner diameter of the air jet tube was 760 pim. Figure 2. Meso-scale whirl combustion of...decomposition. This mechanism was developed by comparison of model predictions with experimental data obtained from shock tube and static reactor...relative to the true gas phase temperature. Air on for exhaust tube cooling•" 2500 0L- CH3 NO 2 off 񓟰 Air off 򒶜 CH3NO 2 on H2 off T Ŕ 1000 S500 Air

Effectiveness of Iron Ethylenediamine-N,N'-bis(hydroxyphenylacetic) Acid (o,o-EDDHA/Fe3+) Formulations with Different Ratios of Meso and d,l-Racemic Isomers as Iron Fertilizers.

PubMed

Alcañiz, Sara; Jordá, Juana D; Cerdán, Mar

2017-01-18

Two o,o-EDDHA/Fe 3+ formulations (meso, 93.5% w/w of meso isomer; and d,l-racemic, 91.3% w/w of d,l-racemic mixture) were prepared, and their efficacy to avoid or to relieve iron deficiency in Fe-sufficient and Fe-deficient tomato plants grown on hydroponic solution was compared with that of the current o,o-EDDHA/Fe 3+ formulations (50% of meso and d,l-racemic isomers). The effectiveness of the three o,o-EDDHA/Fe 3+ formulations was different depending on the iron nutritional status of plants. The three o,o-EDDHA/Fe 3+ formulations tested were effective in preventing iron chlorosis in healthy plants. However, the higher the meso concentration in the formulations, the higher the effectiveness in the recovery of iron chlorotic plants from iron deficiency. Accordingly, o,o-EDDHA/Fe 3+ formulations rich in meso isomer are recommended in hydroponic systems.

Thermo-Oxidative Induced Damage in Polymer Composites: Microstructure Image-Based Multi-Scale Modeling and Experimental Validation

NASA Astrophysics Data System (ADS)

Hussein, Rafid M.; Chandrashekhara, K.

2017-11-01

A multi-scale modeling approach is presented to simulate and validate thermo-oxidation shrinkage and cracking damage of a high temperature polymer composite. The multi-scale approach investigates coupled transient diffusion-reaction and static structural at macro- to micro-scale. The micro-scale shrinkage deformation and cracking damage are simulated and validated using 2D and 3D simulations. Localized shrinkage displacement boundary conditions for the micro-scale simulations are determined from the respective meso- and macro-scale simulations, conducted for a cross-ply laminate. The meso-scale geometrical domain and the micro-scale geometry and mesh are developed using the object oriented finite element (OOF). The macro-scale shrinkage and weight loss are measured using unidirectional coupons and used to build the macro-shrinkage model. The cross-ply coupons are used to validate the macro-shrinkage model by the shrinkage profiles acquired using scanning electron images at the cracked surface. The macro-shrinkage model deformation shows a discrepancy when the micro-scale image-based cracking is computed. The local maximum shrinkage strain is assumed to be 13 times the maximum macro-shrinkage strain of 2.5 × 10-5, upon which the discrepancy is minimized. The microcrack damage of the composite is modeled using a static elastic analysis with extended finite element and cohesive surfaces by considering the modulus spatial evolution. The 3D shrinkage displacements are fed to the model using node-wise boundary/domain conditions of the respective oxidized region. Microcrack simulation results: length, meander, and opening are closely matched to the crack in the area of interest for the scanning electron images.

Meso-beta scale numerical simulation studies of terrain-induced jet streak mass and momentum perturbations

NASA Technical Reports Server (NTRS)

Lin, Yuh-Lang; Kaplan, Michael L.

1994-01-01

An in-depth analysis of observed gravity waves and their relationship to precipitation bands over the Montana mesonetwork during the 11-12 July 1981 CCOPE case study indicated two episodes of coherent waves. While geostrophic adjustment, shearing instability, and terrain were all implicated separately or in combination as possible wave generation mechanisms, the lack of upper-air data within the wave genesis region made it difficult to define the genesis processes from observations alone. The first part of this paper, 3D Numerical Modeling Studies of Terrain-Induced Mass/Momentum Perturbations, employs a mesoscale numerical model to help diagnose the intricate early wave generation mechanisms during the first observed gravity wave episode. The meso-beta scale numerical model is used to study various simulations of the role of multiple geostrophic adjustment processes in focusing a region for gravity wave genesis. The second part of this paper, Linear Theory and Theoretical Modeling, investigates the response of non-resting rotating homogeneous and continuously stratified Boussinesq models of the terrestrial atmosphere to temporally impulsive and uniformly propagating three-dimensional localized zonal momentum sources representative of midlatitude jet streaks. The methods of linear perturbation theory applied to the potential vorticity (PV) and wave field equations are used to study the geostrophic adjustment dynamics. The total zonal and meridional wind perturbations are separated into geostrophic and ageostrophic components in order to define and follow the evolution of both the primary and secondary mesocirculations accompanying midlatitude jetogenesis forced by geostrophic adjustment processes. This problem is addressed to help fill the gap in understanding the dynamics and structure of mesoscale inertia-gravity waves forced by geostrophic adjustment processes in simple two-dimensional quiescent current systems and those produced by mesoscale numerical models simulating the orographic and diabatic perturbation of three-dimensional quasi-geostrophically balanced synoptic scale jet streaks associated with complex baroclinic severe storm producing environments.

The scientific targets of the SCOPE mission

NASA Astrophysics Data System (ADS)

Fujimoto, M.; Saito, Y.; Tsuda, Y.; Shinohara, I.; Kojima, H.

Future Japanese magnetospheric mission "SCOPE" is now under study (planned to be launched in 2012). The main purpose of this mission is to investigate the dynamic behaviors of plasmas in the Earth's magnetosphere from the view-point of cross-scale coupling. Dynamical collisionless space plasma phenomena, be they large scale as a whole, are chracterized by coupling over various time and spatial scales. The best example would be the magnetic reconnection process, which is a large scale energy conversion process but has a small key region at the heart of its engine. Inside the key region, electron scale dynamics plays the key role in liberating the frozen-in constraint, by which reconnection is allowed to proceed. The SCOPE mission is composed of one large mother satellite and four small daughter satellites. The mother spacecraft will be equiped with the electron detector that has 10 msec time resolution so that scales down to the electron's will be resolved. Three of the four daughter satellites surround the mother satellite 3-dimensionally with the mutual distances between several km and several thousand km, which are varied during the mission. Plasma measurements on these spacecrafts will have 1 sec resolution and will provide information on meso-scale plasma structure. The fourth daughter satellite stays near the mother satellite with the distance less than 100km. By correlation between the two plasma wave instruments on the daughter and the mother spacecrafts, propagation of the waves and the information on the electron scale dynamics will be obtained. By this strategy, both meso- and micro-scale information on dynamics are obtained, that will enable us to investigate the physics of the space plasma from the cross-scale coupling point of view.

Microstructural Evolution at Micro/Meso-Scale in an Ultrafine-Grained Pure Aluminum Processed by Equal-Channel Angular Pressing with Subsequent Annealing Treatment.

PubMed

Xu, Jie; Li, Jianwei; Zhu, Xiaocheng; Fan, Guohua; Shan, Debin; Guo, Bin

2015-11-04

Micro-forming with ultrafine-grained (UFG) materials is a promising direction for the fabrication of micro-electro-mechanical systems (MEMS) components due to the improved formability, good surface quality, and excellent mechanical properties it provides. In this paper, micro-compression tests were performed using UFG pure aluminum processed by equal-channel angular pressing (ECAP) with subsequent annealing treatment. Microstructural evolution was investigated by electron back-scattered diffraction (EBSD) and transmission electron microscopy (TEM). The results show that microstructural evolutions during compression tests at the micro/meso-scale in UFG pure Al are absolutely different from the coarse-grained (CG) materials. A lot of low-angle grain boundaries (LAGBs) and recrystallized fine grains are formed inside of the original large grains in CG pure aluminum after micro-compression. By contrast, ultrafine grains are kept with few sub-grain boundaries inside the grains in UFG pure aluminum, which are similar to the original microstructure before micro-compression. The surface roughness and coordinated deformation ability can be signmicrostructure; micro/meso-forming; ultrafine grains; ECAP; aluminumificantly improved with UFG pure aluminum, which demonstrates that the UFG materials have a strong potential application in micro/meso-forming.

Sandy beaches: state of the art of nematode ecology.

PubMed

Maria, Tatiana F; Vanaverbeke, Jan; Vanreusel, Ann; Esteves, André M

2016-01-01

In this review, we summarize existing knowledge of the ecology of sandy-beach nematodes, in relation to spatial distribution, food webs, pollution and climate change. We attempt to discuss spatial scale patterns (macro-, meso- and microscale) according to their degree of importance in structuring sandy-beach nematode assemblages. This review will provide a substantial background on current knowledge of sandy-beach nematodes, and can be used as a starting point to delineate further investigations in this field. Over decades, sandy beaches have been the scene of studies focusing on community and population ecology, both related to morphodynamic models. The combination of physical factors (e.g. grain size, tidal exposure) and biological interactions (e.g. trophic relationships) is responsible for the spatial distribution of nematodes. In other words, the physical factors are more important in structuring nematodes communities over large scale of distribution while biological interactions are largely important in finer-scale distributions. It has been accepted that biological interactions are assumed to be of minor importance because physical factors overshadow the biological interactions in sandy beach sediments; however, the most recent results from in-situ and ex-situ experimental investigations on behavior and biological factors on a microscale have shown promise for understanding the mechanisms underlying larger-scale patterns and processes. Besides nematodes are very promising organisms used to understand the effects of pollution and climate changes although these subjects are less studied in sandy beaches than distribution patterns.

Continuum-Kinetic Models and Numerical Methods for Multiphase Applications

NASA Astrophysics Data System (ADS)

Nault, Isaac Michael

This thesis presents a continuum-kinetic approach for modeling general problems in multiphase solid mechanics. In this context, a continuum model refers to any model, typically on the macro-scale, in which continuous state variables are used to capture the most important physics: conservation of mass, momentum, and energy. A kinetic model refers to any model, typically on the meso-scale, which captures the statistical motion and evolution of microscopic entitites. Multiphase phenomena usually involve non-negligible micro or meso-scopic effects at the interfaces between phases. The approach developed in the thesis attempts to combine the computational performance benefits of a continuum model with the physical accuracy of a kinetic model when applied to a multiphase problem. The approach is applied to modeling a single particle impact in Cold Spray, an engineering process that intimately involves the interaction of crystal grains with high-magnitude elastic waves. Such a situation could be classified a multiphase application due to the discrete nature of grains on the spatial scale of the problem. For this application, a hyper elasto-plastic model is solved by a finite volume method with approximate Riemann solver. The results of this model are compared for two types of plastic closure: a phenomenological macro-scale constitutive law, and a physics-based meso-scale Crystal Plasticity model.

[Community structure of soil meso- and micro-fauna in different habitats of urbanized region].

PubMed

Qin, Zhong; Zhang, Jia-en; Li, Qing-fang

2009-12-01

Investigations were made in May, June, and November 2007 and January 2008 to study the structural characteristics and their seasonal variations of soil meso- and micro-fauna communities in six habitats of three land use types (forest land, constructed grassland and farmland) in Tianhe District of Guangzhou City. The horizontal spatial distribution of soil fauna differed with habitat. During the investigation periods, the Botanical Garden of South China Agricultural University had the highest individual number (1286) of soil mesa- and micro-fauna, while the farmland, especially in the Fenghuang Street area, had the lowest number of individuals and groups. The seasonal variation of the individual number was in order of autumn (1815) > spring (1623) > winter (1365) > summer (1276). Hierarchical clustering and detrended correspondence analysis also showed that the community composition of soil meso- and micro-fauna in different habitats exhibited distinct seasonal variation. In the same seasons, the community structure and composition of soil meso- and micro-fauna in different habitats were correlated to the degrees of human interferences and the properties of soil environment.

High transparent shape memory gel

NASA Astrophysics Data System (ADS)

Gong, Jin; Arai, Masanori; Kabir, M. H.; Makino, Masato; Furukawa, Hidemitsu

2014-03-01

Gels are a new material having three-dimensional network structures of macromolecules. They possess excellent properties as swellability, high permeability and biocompatibility, and have been applied in various fields of daily life, food, medicine, architecture, and chemistry. In this study, we tried to prepare new multi-functional and high-strength gels by using Meso-Decoration (Meso-Deco), one new method of structure design at intermediate mesoscale. High-performance rigid-rod aromatic polymorphic crystals, and the functional groups of thermoreversible Diels-Alder reaction were introduced into soft gels as crosslinkable pendent chains. The functionalization and strengthening of gels can be realized by meso-decorating the gels' structure using high-performance polymorphic crystals and thermoreversible pendent chains. New gels with good mechanical properties, novel optical properties and thermal properties are expected to be developed.

A review of major progresses in mesoscale dynamic research in China since 1999

NASA Astrophysics Data System (ADS)

Zhou, Xiaoping; Lu, Hancheng; Ni, Yunqi; Tan, Zhemin

2004-06-01

Mesoscale research conducted by Chinese meteorologists during the past four years is reviewed. Advances in theoretical studies include (a) mesoscale quasi-balanced and semi-balanced dynamics, derived through scale analysis and the perturbation method which are suitable for describing mesoscale vortices; (b) subcritical instability and vortex-sheet instability; (c) frontal adjustment mechanism and the effect of topography on frontgenesis; and (d) slantwise vorticity development theories, the slantwise vortex equation, and moist potential vorticity (MPV) anomalies with precipitation-related heat and mass sinks and MPV impermeability theorem. From the MPV conservation viewpoint, the transformation mechanism between different scale weather systems is analyzed. Based on the data analysis, a new dew-point front near the periphery of the West Pacific subtropical high is identified. In the light of MPV theory and Q-vector theory, some events associated with torrential rain systems and severe storms are analyzed and diagnosed. Progress in mesoscale numerical simulation has been made in the development of meso-α, meso-β vortices, meso-γ-scale downbursts and precipitation produced by deep convective systems with MM5 and other mesoscale models.

An objective and reproducible landform and topography description approach based on digital terrain analysis used for soil profile site characteristics

NASA Astrophysics Data System (ADS)

Gruber, Fabian E.; Baruck, Jasmin; Hastik, Richard; Geitner, Clemens

2015-04-01

All major soil description and classification systems, including the World Reference Base (WRB) and the German Soil description guidelines (KA5), require the characterization of landform and topography for soil profile sites. This is commonly done at more than one scale, for instance at macro-, meso- and micro scale. However, inherent when humans perform such a task, different surveyors will reach different conclusions due to their subjective perception of landscape structure, based on their individual mind-model of soil-landscape structure, emphasizing different aspects and scales of the landscape. In this study we apply a work-flow using the GRASS GIS extension module r.geomorphon to make use of high resolution digital elevation models (DEMs) to characterize the landform elements and topography of soil profile sites at different scales, and compare the results with a large number of soil profile site descriptions performed during the course of forestry surveys in South and North Tyrol (Italy and Austria, respectively). The r.geomorphon extension module for the open source geographic information system GRASS GIS applies a pattern recognition algorithm to delineate landform elements based on an input DEM. For each raster cell it computes and characterizes the visible neighborhood using line-of-sight calculations and then applies a lookup-table to classify the raster cell into one of ten landform elements (flat, peak, ridge, shoulder, slope, spur, hollow, footslope, valley and pit). The input parameter search radius (L) represents the maximum number of pixels for line-of-sight calculation, resulting in landforms larger than L to be split into landform components. The use of these visibility calculations makes this landform delineation approach suitable for comparison with the landform descriptions of soil surveyors, as their spatial perception of the landscape surrounding a soil profile site certainly influences their classification of the landform on which the profile is situated (aided by additional information such as topographic maps and aerial images). Variation of the L-value furthermore presents the opportunity to mimic the different scales at which surveyors describe soil profile locations. We first illustrate the use of r.geomorphon for site descriptions using exemplary artificial elevation profiles resembling typic catenas at different scales (L-values). We then compare the results of a landform element map computed with r.geomorphon to the relief descriptions in the test dataset. We link the surveyors' landform classification to the computed landform elements. Using a multi-scale approach we characterize raster cell locations in a way similar to the micro-, meso- and macroscale definitions used in soil survey, resulting in so-called geomorphon-signatures, such as "pit (meso-scale) located on a ridge (macro-scale)". We investigate which ranges of L-values best represent the different observation-scales as noted by soil surveyors and discuss the impacts of using a large dataset of profile location descriptions performed by different surveyors. Issues that arise are possible individual differences in landscape structure perception, but also questions regarding the accuracy of position and resulting topographic measurements in soil profile site description.

Meso-Scale Finite Element Analysis of Mechanical Behavior of 3D Braided Composites Subjected to Biaxial Tension Loadings

NASA Astrophysics Data System (ADS)

Zhang, Chao; Curiel-Sosa, Jose L.; Bui, Tinh Quoc

2018-04-01

In many engineering applications, 3D braided composites are designed for primary loading-bearing structures, and they are frequently subjected to multi-axial loading conditions during service. In this paper, a unit-cell based finite element model is developed for assessment of mechanical behavior of 3D braided composites under different biaxial tension loadings. To predict the damage initiation and evolution of braiding yarns and matrix in the unit-cell, we thus propose an anisotropic damage model based on Murakami damage theory in conjunction with Hashin failure criteria and maximum stress criteria. To attain exact stress ratio, force loading mode of periodic boundary conditions which never been attempted before is first executed to the unit-cell model to apply the biaxial tension loadings. The biaxial mechanical behaviors, such as the stress distribution, tensile modulus and tensile strength are analyzed and discussed. The damage development of 3D braided composites under typical biaxial tension loadings is simulated and the damage mechanisms are revealed in the simulation process. The present study generally provides a new reference to the meso-scale finite element analysis (FEA) of multi-axial mechanical behavior of other textile composites.

Development of a Meso-Scale SMA-Based Torsion Actuator for Image-Guided Procedures.

PubMed

Sheng, Jun; Gandhi, Dheeraj; Gullapalli, Rao; Simard, J Marc; Desai, Jaydev P

2017-02-01

This paper presents the design, modeling, and control of a meso-scale torsion actuator based on shape memory alloy (SMA) for image-guided surgical procedures. Developing a miniature torsion actuator is challenging, but it opens the possibility of significantly enhancing the robot agility and maneuverability. The proposed torsion actuator is bi-directionally actuated by a pair of antagonistic SMA torsion springs through alternate Joule heating and natural cooling. The torsion actuator is integrated into a surgical robot prototype to demonstrate its working performance in the humid environment under C-Arm CT image guidance.

Shock compression response of cold-rolled Ni/Al multilayer composites

NASA Astrophysics Data System (ADS)

Specht, Paul E.; Weihs, Timothy P.; Thadhani, Naresh N.

2017-01-01

Uniaxial strain, plate-on-plate impact experiments were performed on cold-rolled Ni/Al multilayer composites and the resulting Hugoniot was determined through time-resolved measurements combined with impedance matching. The experimental Hugoniot agreed with that previously predicted by two dimensional (2D) meso-scale calculations [Specht et al., J. Appl. Phys. 111, 073527 (2012)]. Additional 2D meso-scale simulations were performed using the same computational method as the prior study to reproduce the experimentally measured free surface velocities and stress profiles. These simulations accurately replicated the experimental profiles, providing additional validation for the previous computational work.

Development of a Meso-Scale SMA-Based Torsion Actuator for Image-Guided Procedures

PubMed Central

Sheng, Jun; Gandhi, Dheeraj; Gullapalli, Rao; Simard, J. Marc; Desai, Jaydev P.

2016-01-01

This paper presents the design, modeling, and control of a meso-scale torsion actuator based on shape memory alloy (SMA) for image-guided surgical procedures. Developing a miniature torsion actuator is challenging, but it opens the possibility of significantly enhancing the robot agility and maneuverability. The proposed torsion actuator is bi-directionally actuated by a pair of antagonistic SMA torsion springs through alternate Joule heating and natural cooling. The torsion actuator is integrated into a surgical robot prototype to demonstrate its working performance in the humid environment under C-Arm CT image guidance. PMID:28210189

From a meso- to micro-scale connectome: array tomography and mGRASP

PubMed Central

Rah, Jong-Cheol; Feng, Linqing; Druckmann, Shaul; Lee, Hojin; Kim, Jinhyun

2015-01-01

Mapping mammalian synaptic connectivity has long been an important goal of neuroscience because knowing how neurons and brain areas are connected underpins an understanding of brain function. Meeting this goal requires advanced techniques with single synapse resolution and large-scale capacity, especially at multiple scales tethering the meso- and micro-scale connectome. Among several advanced LM-based connectome technologies, Array Tomography (AT) and mammalian GFP-Reconstitution Across Synaptic Partners (mGRASP) can provide relatively high-throughput mapping synaptic connectivity at multiple scales. AT- and mGRASP-assisted circuit mapping (ATing and mGRASPing), combined with techniques such as retrograde virus, brain clearing techniques, and activity indicators will help unlock the secrets of complex neural circuits. Here, we discuss these useful new tools to enable mapping of brain circuits at multiple scales, some functional implications of spatial synaptic distribution, and future challenges and directions of these endeavors. PMID:26089781

Replacing critical rare earth materials in high energy density magnets

NASA Astrophysics Data System (ADS)

McCallum, R. William

2012-02-01

High energy density permanent magnets are crucial to the design of internal permanent magnet motors (IPM) for hybride and electric vehicles and direct drive wind generators. Current motor designs use rare earth permanent magnets which easily meet the performance goals, however, the rising concerns over cost and foreign control of the current supply of rare earth resources has motivated a search for non-rare earth based permanent magnets alloys with performance metrics which allow the design of permanent magnet motors and generators without rare earth magnets. This talk will discuss the state of non-rare-earth permanent magnets and efforts to both improve the current materials and find new materials. These efforts combine first principles calculations and meso-scale magnetic modeling with advance characterization and synthesis techniques in order to advance the state of the art in non rare earth permanent magnets. The use of genetic algorithms in first principle structural calculations, combinatorial synthesis in the experimental search for materials, atom probe microscopy to characterize grain boundaries on the atomic level, and other state of the art techniques will be discussed. In addition the possibility of replacing critical rare earth elements with the most abundant rare earth Ce will be discussed.

Time Processing in Children with Tourette's Syndrome

ERIC Educational Resources Information Center

Vicario, Carmelo Mario; Martino, Davide; Spata, Felice; Defazio, Giovanni; Giacche, Roberta; Martino, Vito; Rappo, Gaetano; Pepi, Anna Maria; Silvestri, Paola Rosaria; Cardona, Francesco

2010-01-01

Background: Tourette syndrome (TS) is characterized by dysfunctional connectivity between prefrontal cortex and sub-cortical structures, and altered meso-cortical and/or meso-striatal dopamine release. Since time processing is also regulated by fronto-striatal circuits and modulated by dopaminergic transmission, we hypothesized that time…

Effect of densifying the GNSS GBAS network on monitoring the troposphere zenith total delay and precipitable water vapour content during severe weather events

NASA Astrophysics Data System (ADS)

Kapłon, Jan; Stankunavicius, Gintautas

2016-04-01

The dense ground based augmentation networks can provide the important information for monitoring the state of neutral atmosphere. The GNSS&METEO research group at Wroclaw University of Environmental and Life Sciences (WUELS) is operating the self-developed near real-time service estimating the troposphere parameters from GNSS data for the area of Poland. The service is operational since December 2012 and it's results calculated from ASG-EUPOS GBAS network (120 stations) data are supporting the EGVAP (http://egvap.dmi.dk) project. At first the zenith troposphere delays (ZTD) were calculated in hourly intervals, but since September 2015 the service was upgraded to include SmartNet GBAS network (Leica Geosystems Polska - 150 stations). The upgrade included as well: increasing the result interval to 30 minutes, upgrade from Bernese GPS Software v. 5.0 to Bernese GNSS Software v. 5.2 and estimation of the ZTD and it's horizontal gradients. Processing includes nowadays 270 stations. The densification of network from 70 km of mean distance between stations to 40 km created the opportunity to investigate on it's impact on resolution of estimated ZTD and integrated water vapour content (IWV) fields during the weather events of high intensity. Increase in density of ZTD measurements allows to define better the meso-scale features within different synoptic systems (e.g. frontal waves, meso-scale convective systems, squall lines etc). These meso-scale structures, as a rule are short living but fast developing and hardly predictable by numerical models. Even so, such limited size systems can produce very hazardous phenomena - like widespread squalls and thunderstorms, tornadoes, heavy rains, snowfalls, hail etc. because of prevalence of Cb clouds with high concentration of IWV. Study deals with two meteorological events: 2015-09-01 with the devastating squalls and rainfall bringing 2M Euro loss of property in northern Poland and 2015-10-12 with the very active front bringing snowfall in southern part of the country. There are presented as well: the evaluation of differences in 2D fields of ZTD and IWV obtained from ASG-EUPOS network only and from ASG-EUPOS and SmartNet networks, their validation using IWV from numerical weather model and CM-SAF (Satellite Application Facility on Climate Monitoring) data. The results are interpreted towards the increase of possibility to detect the meso-scale weather features with densification of GNSS sensors network.

The role of climate on inter-annual variation in stream nitrate fluxes and concentrations.

PubMed

Gascuel-Odoux, Chantal; Aurousseau, Pierre; Durand, Patrick; Ruiz, Laurent; Molenat, Jérôme

2010-11-01

In recent decades, temporal variations in nitrate fluxes and concentrations in temperate rivers have resulted from the interaction of anthropogenic and climatic factors. The effect of climatic drivers remains unclear, while the relative importance of the drivers seems to be highly site dependent. This paper focuses on 2-6 year variations called meso-scale variations, and analyses the climatic drivers of these variations in a study site characterized by high N inputs from intensive animal farming systems and shallow aquifers with impervious bedrock in a temperate climate. Three approaches are developed: 1) an analysis of long-term records of nitrate fluxes and nitrate concentrations in 30 coastal rivers of Western France, which were well-marked by meso-scale cycles in the fluxes and concentration with a slight hysteresis; 2) a test of the climatic control using a lumped two-box model, which demonstrates that hydrological assumptions are sufficient to explain these meso-scale cycles; and 3) a model of nitrate fluxes and concentrations in two contrasted catchments subjected to recent mitigation measures, which analyses nitrate fluxes and concentrations in relation to N stored in groundwater. In coastal rivers, hydrological drivers (i.e., effective rainfall), and particularly the dynamics of the water table and rather stable nitrate concentration, explain the meso-scale cyclic patterns. In the headwater catchment, agricultural and hydrological drivers can interact according to their settings. The requirements to better distinguish the effect of climate and human changes in integrated water management are addressed: long-term monitoring, coupling the analysis and the modelling of large sets of catchments incorporating different sizes, land uses and environmental factors. Copyright © 2009 Elsevier B.V. All rights reserved.

Spectral Gap Energy Transfer in Atmospheric Boundary Layer

NASA Astrophysics Data System (ADS)

Bhushan, S.; Walters, K.; Barros, A. P.; Nogueira, M.

2012-12-01

Experimental measurements of atmospheric turbulence energy spectra show E(k) ~ k-3 slopes at synoptic scales (~ 600 km - 2000 km) and k-5/3 slopes at the mesoscales (< 400 km). The -5/3 spectra is presumably related to 3D turbulence which is dominated by the classical Kolmogrov energy cascade. The -3 spectra is related to 2D turbulence, which is dominated by strong forward scatter of enstrophy and weak forward scatter of energy. In classical 2D turbulence theory, it is expected that a strong backward energy cascade would develop at the synoptic scale, and that circulation would grow infinitely. To limit this backward transfer, energy arrest at macroscales must be introduced. The most commonly used turbulence models developed to mimic the above energy transfer include the energy backscatter model for 2D turbulence in the horizontal plane via Large Eddy Simulation (LES) models, dissipative URANS models in the vertical plane, and Ekman friction for the energy arrest. One of the controversial issues surrounding the atmospheric turbulence spectra is the explanation of the generation of the 2D and 3D spectra and transition between them, for energy injection at the synoptic scales. Lilly (1989) proposed that the existence of 2D and 3D spectra can only be explained by the presence of an additional energy injection in the meso-scale region. A second issue is related to the observations of dual peak spectra with small variance in meso-scale, suggesting that the energy transfer occurs across a spectral gap (Van Der Hoven, 1957). Several studies have confirmed the spectral gap for the meso-scale circulations, and have suggested that they are enhanced by smaller scale vertical convection rather than by the synoptic scales. Further, the widely accepted energy arrest mechanism by boundary layer friction is closely related to the spectral gap transfer. This study proposes an energy transfer mechanism for atmospheric turbulence with synoptic scale injection, wherein the generation of 2D and 3D spectra is explained using spectral gap energy transfer. The existence of the spectral gap energy transfer is validated by performing LES for the interaction of large scale circulation with a wall, and studying the evolution of the energy spectra both near to and far from the wall. Simulations are also performed using the Advanced Weather and Research Forecasting (WRF-ARW) for moist zonal flow over Gaussian ridge, and the energy spectra close and away from the ground are studied. The energy spectra predicted by WRF-ARW are qualitatively compared with LES results to emphasize the limitations of the currently used turbulence parameterizations. Ongoing validation efforts include: (1) extending the interaction of large scale circulation with wall simulations to finer grids to capture a wider range of wavenumbers; and (2) a coupled 2D-3D simulation is planned to predict the entire atmospheric turbulence spectra at a very low computational expense. The overarching objective of this study to develop turbulence modeling capability based on the energy transfer mechanisms proposed in this study. Such a model will be implemented in WRF-ARW, and applied to atmospheric simulations, for example the prediction of moisture convergence patterns at the meso-scale in the southeast United States (Tao & Barros, 2008).

New strategy for surface functionalization of periodic mesoporous silica based on meso-HSiO1.5.

PubMed

Xie, Zhuoying; Bai, Ling; Huang, Suwen; Zhu, Cun; Zhao, Yuanjin; Gu, Zhong-Ze

2014-01-29

Organic functionalization of periodic mesoporous silicas (PMSs) offers a way to improve their excellent properties and wide applications owing to their structural superiority. In this study, a new strategy for organic functionalization of PMSs is demonstrated by hydrosilylation of the recently discovered "impossible" periodic mesoporous hydridosilica, meso-HSiO1.5. This method overcomes the disadvantages of present pathways for organic functionalization of PMSs with organosilica. Moreover, compared to the traditional functionalization on the surface of porous silicon by hydrosilylation, the template-synthesized meso-HSiO1.5 is more flexible to access functional-groups-loaded PMSs with adjustable microstructures. The new method and materials will have wider applications based on both the structure and surface superiorities.

Multi-scale simulations of apatite-collagen composites: from molecules to materials

NASA Astrophysics Data System (ADS)

Zahn, Dirk

2017-03-01

We review scale-bridging simulation studies for the exploration of atomicto-meso scale processes that account for the unique structure and mechanic properties of apatite-protein composites. As the atomic structure and composition of such complex biocomposites only partially is known, the first part (i) of our modelling studies is dedicated to realistic crystal nucleation scenarios of inorganic-organic composites. Starting from the association of single ions, recent insights range from the mechanisms of motif formation, ripening reactions and the self-organization of nanocrystals, including their interplay with growth-controlling molecular moieties. On this basis, (ii) reliable building rules for unprejudiced scale-up models can be derived to model bulk materials. This is exemplified for (enamel-like) apatite-protein composites, encompassing up to 106 atom models to provide a realistic account of the 10 nm length scale, whilst model coarsening is used to reach μm length scales. On this basis, a series of deformation and fracture simulation studies were performed and helped to rationalize biocomposite hardness, plasticity, toughness, self-healing and fracture mechanisms. Complementing experimental work, these modelling studies provide particularly detailed insights into the relation of hierarchical composite structure and favorable mechanical properties.

Meso-scale eddies and the impacts on variability of carbonate chemistry over deep coral reefs in the Florida Straits

NASA Astrophysics Data System (ADS)

Jiang, M.; Pan, C.; Barbero, L.; Hu, C.; Reed, J.; Salisbury, J.; Wanninkhof, R. H.

2016-02-01

Abundant and diverse cold-water corals and associated fish communities can be found in the deep waters of the Florida Straits. Preliminary evidence suggests that corals in these deep coral habitats are living under sub-optimal conditions with the ambient aragonite saturation state (Ω) being only marginally above 1. Yet little is known regarding the temporal variability of carbonate chemistry parameters and their dynamic drivers in these critical habitats. In this presentation, we addressed this issue by using a recently developed circulation model and in situ data collected during two research cruises: the second Florida Shelf Edge Exploration Expedition (FloSEE2) in September 2011 and the second Gulf of Mexico East Coast Carbon Cruise (GOMECC2) in July 2012, both supported by NOAA. A numerical simulation was carried out for 2011-2012. In particular, we focused on two contrasting habitats: Pourtalès Terrace (200-450m) and Miami Terrace (270-600m) in the Florida Straits. The results suggest that there is strong weekly to seasonal variability in the bottom water properties including temperature, salinity, total CO2 and total alkalinity on the upper slope of the Straits. In particular, the minimum saturation state over Pourtalès Terrace can be as low as 1.5 whereas even at the top of Miami Terrace, Ω can be very close to 1. Further analysis suggests that the variability of water properties in the upper slope is largely driven by the large-scale transport, and upwelling of cold and CO2-rich deep waters due to meandering of Florida Current, and/or associated meso-scale eddies. In contrast, the water properties at the bottom of the slope are very stable but with much lower aragonite saturation state. The roles of local biochemical processes including the potentially elevated productivity and export driven by meso-scale eddies are yet to be explored. We further project that the aragonite saturation state in deep waters of the Florida Straits may be further decreased to around or below 1 in 2050 under the IPCC RCP 8.5 scenario.

Exploring New Challenges of High-Resolution SWOT Satellite Altimetry with a Regional Model of the Solomon Sea

NASA Astrophysics Data System (ADS)

Brasseur, P.; Verron, J. A.; Djath, B.; Duran, M.; Gaultier, L.; Gourdeau, L.; Melet, A.; Molines, J. M.; Ubelmann, C.

2014-12-01

The upcoming high-resolution SWOT altimetry satellite will provide an unprecedented description of the ocean dynamic topography for studying sub- and meso-scale processes in the ocean. But there is still much uncertainty on the signal that will be observed. There are many scientific questions that are unresolved about the observability of altimetry at vhigh resolution and on the dynamical role of the ocean meso- and submesoscales. In addition, SWOT data will raise specific problems due to the size of the data flows. These issues will probably impact the data assimilation approaches for future scientific or operational oceanography applications. In this work, we propose to use a high-resolution numerical model of the Western Pacific Solomon Sea as a regional laboratory to explore such observability and dynamical issues, as well as new data assimilation challenges raised by SWOT. The Solomon Sea connects subtropical water masses to the equatorial ones through the low latitude western boundary currents and could potentially modulate the tropical Pacific climate. In the South Western Pacific, the Solomon Sea exhibits very intense eddy kinetic energy levels, while relatively little is known about the mesoscale and submesoscale activities in this region. The complex bathymetry of the region, complicated by the presence of narrow straits and numerous islands, raises specific challenges. So far, a Solomon sea model configuration has been set up at 1/36° resolution. Numerical simulations have been performed to explore the meso- and submesoscales dynamics. The numerical solutions which have been validated against available in situ data, show the development of small scale features, eddies, fronts and filaments. Spectral analysis reveals a behavior that is consistent with the SQG theory. There is a clear evidence of energy cascade from the small scales including the submesoscales, although those submesoscales are only partially resolved by the model. In parallel, investigations have been conducted using image assimilation approaches in order to explore the richness of high-resolution altimetry missions. These investigations illustrate the potential benefit of combining tracer fields (SST, SSS and spiciness) with high-resolution SWOT data to estimate the fine-scale circulation.

Direct growth of NiO nanosheets on mesoporous TiN film for energy storage devices

NASA Astrophysics Data System (ADS)

Lee, Jae Hun; Lim, Jung Yup; Lee, Chang Soo; Park, Jung Tae; Kim, Jong Hak

2017-10-01

We report an efficient energy storage electrode based on well-defined, interconnected NiO nanosheets (NiO-NS) grown directly on a mesoporous TiN (meso-TiN) film via a solvothermal method. A mesoporous TiO2 (meso-TiO2) film is prepared using a graft copolymer template and then thermally annealed in ammonia at 800 °C to convert meso-TiO2 into meso-TiN. The ultrathin interconnected NiO-NS provide a large surface area and effective electron pathway, which enhance their specific capacitance and electrochemical properties. In contrast, a less-organized structure with poor homogeneity, low porosity and some cracks is formed for dense-TiN film prepared without the PVC-g-POEM. The meso-TiN film acts as an efficient conductive support to grow the NiO-NS and enhances the diffusion of electron/electrolyte ions. Despite its low thickness (<1.3 μm), the NiO-NS/meso-TiN supercapacitor exhibits a high capacitance of 104 mF cm-2 and good cycle stability (86% capacitance retention) owing to the synergetic effects of the NiO-NS and meso-TiN heteronanostructure. The NiO-NS/meso-TiN film is also applied to a flexible substrate and exhibits no cracks after bending; thus, our work provides an efficient way to design flexible energy storage devices using graft-copolymer-directed heteronanostructures.

Numerical models for fluid-grains interactions: opportunities and limitations

NASA Astrophysics Data System (ADS)

Esteghamatian, Amir; Rahmani, Mona; Wachs, Anthony

2017-06-01

In the framework of a multi-scale approach, we develop numerical models for suspension flows. At the micro scale level, we perform particle-resolved numerical simulations using a Distributed Lagrange Multiplier/Fictitious Domain approach. At the meso scale level, we use a two-way Euler/Lagrange approach with a Gaussian filtering kernel to model fluid-solid momentum transfer. At both the micro and meso scale levels, particles are individually tracked in a Lagrangian way and all inter-particle collisions are computed by a Discrete Element/Soft-sphere method. The previous numerical models have been extended to handle particles of arbitrary shape (non-spherical, angular and even non-convex) as well as to treat heat and mass transfer. All simulation tools are fully-MPI parallel with standard domain decomposition and run on supercomputers with a satisfactory scalability on up to a few thousands of cores. The main asset of multi scale analysis is the ability to extend our comprehension of the dynamics of suspension flows based on the knowledge acquired from the high-fidelity micro scale simulations and to use that knowledge to improve the meso scale model. We illustrate how we can benefit from this strategy for a fluidized bed, where we introduce a stochastic drag force model derived from micro-scale simulations to recover the proper level of particle fluctuations. Conversely, we discuss the limitations of such modelling tools such as their limited ability to capture lubrication forces and boundary layers in highly inertial flows. We suggest ways to overcome these limitations in order to enhance further the capabilities of the numerical models.

Modeling Time-Dependent Behavior of Concrete Affected by Alkali Silica Reaction in Variable Environmental Conditions.

PubMed

Alnaggar, Mohammed; Di Luzio, Giovanni; Cusatis, Gianluca

2017-04-28

Alkali Silica Reaction (ASR) is known to be a serious problem for concrete worldwide, especially in high humidity and high temperature regions. ASR is a slow process that develops over years to decades and it is influenced by changes in environmental and loading conditions of the structure. The problem becomes even more complicated if one recognizes that other phenomena like creep and shrinkage are coupled with ASR. This results in synergistic mechanisms that can not be easily understood without a comprehensive computational model. In this paper, coupling between creep, shrinkage and ASR is modeled within the Lattice Discrete Particle Model (LDPM) framework. In order to achieve this, a multi-physics formulation is used to compute the evolution of temperature, humidity, cement hydration, and ASR in both space and time, which is then used within physics-based formulations of cracking, creep and shrinkage. The overall model is calibrated and validated on the basis of experimental data available in the literature. Results show that even during free expansions (zero macroscopic stress), a significant degree of coupling exists because ASR induced expansions are relaxed by meso-scale creep driven by self-equilibriated stresses at the meso-scale. This explains and highlights the importance of considering ASR and other time dependent aging and deterioration phenomena at an appropriate length scale in coupled modeling approaches.

Modeling Time-Dependent Behavior of Concrete Affected by Alkali Silica Reaction in Variable Environmental Conditions

PubMed Central

Alnaggar, Mohammed; Di Luzio, Giovanni; Cusatis, Gianluca

2017-01-01

Alkali Silica Reaction (ASR) is known to be a serious problem for concrete worldwide, especially in high humidity and high temperature regions. ASR is a slow process that develops over years to decades and it is influenced by changes in environmental and loading conditions of the structure. The problem becomes even more complicated if one recognizes that other phenomena like creep and shrinkage are coupled with ASR. This results in synergistic mechanisms that can not be easily understood without a comprehensive computational model. In this paper, coupling between creep, shrinkage and ASR is modeled within the Lattice Discrete Particle Model (LDPM) framework. In order to achieve this, a multi-physics formulation is used to compute the evolution of temperature, humidity, cement hydration, and ASR in both space and time, which is then used within physics-based formulations of cracking, creep and shrinkage. The overall model is calibrated and validated on the basis of experimental data available in the literature. Results show that even during free expansions (zero macroscopic stress), a significant degree of coupling exists because ASR induced expansions are relaxed by meso-scale creep driven by self-equilibriated stresses at the meso-scale. This explains and highlights the importance of considering ASR and other time dependent aging and deterioration phenomena at an appropriate length scale in coupled modeling approaches. PMID:28772829

Synthesis, characterization and photoactivity of bi-crystalline mesoporous TiO2

NASA Astrophysics Data System (ADS)

Nguyen, Dongthanh; Wang, Wei; Long, Haibo; Ru, Hongqiang

2016-03-01

Mesoporous titania (meso-TiO2) has received extensive attention owing to its versatile potential applications. This paper reports a low-temperature templating approach for the fabrication of meso-TiO2 using the peroxo titanic acid (PTA) sol as precursor and Pluronic P123 as nonionic template. The TGA, XRD, N2 sorption, FE-SEM and HRTEM were used to characterize the obtained samples. The results showed that meso-TiO2 with high surface area up to 163 m2·g-1 and large pore volume of 0.65 cm3·g-1 can be obtained. The mesopore sizes can be varied between 13 and 20 nm via this synthesis approach. The amount of P123 and the calcination conditions were found to have great influence on the mesoporous and crystalline structures of meso-TiO2. The photocatalytic activity testing clearly shows that the high surface area and bi-crystallinity phases of meso-TiO2 play important roles in enhancing photocatalytic properties of meso-TiO2 in photo-decomposing Rhodamine B in water.

Community structure of copepods in the oceanic and neritic waters off Adélie and George V Land, East Antarctica, during the austral summer of 2008

NASA Astrophysics Data System (ADS)

Tachibana, Aiko; Watanabe, Yuko; Moteki, Masato; Hosie, Graham W.; Ishimaru, Takashi

2017-06-01

Copepods are one of the most important components of the Southern Ocean food web, and are widely distributed from surface to deeper waters. We conducted discrete depth sampling to clarify the community structure of copepods from the epi- to bathypelagic layers of the oceanic and neritic waters off Adélie and George V Land, East Antarctica, in the austral summer of 2008. Notably high diversity and species numbers were observed in the meso- and bathypelagic layers. Cluster analysis based on the similarity of copepod communities identified seven cluster groups, which corresponded well with water masses. In the epi- and upper- mesopelagic layers of the oceanic zone, the SB (Southern Boundary of the Antarctic Circumpolar Current) divided copepod communities. Conversely, in the lower meso- and bathypelagic layers (500-2000 m depth), communities were consistent across the SB. In these layers, the distributions of copepod species were separated by habitat depth ranges and feeding behaviour. The different food webs occur in the epipelagic layer with habitat segregation by zooplankton in their horizontal distribution ranges.

Quantifying the Hierarchical Order in Self-Aligned Carbon Nanotubes from Atomic to Micrometer Scale.

PubMed

Meshot, Eric R; Zwissler, Darwin W; Bui, Ngoc; Kuykendall, Tevye R; Wang, Cheng; Hexemer, Alexander; Wu, Kuang Jen J; Fornasiero, Francesco

2017-06-27

Fundamental understanding of structure-property relationships in hierarchically organized nanostructures is crucial for the development of new functionality, yet quantifying structure across multiple length scales is challenging. In this work, we used nondestructive X-ray scattering to quantitatively map the multiscale structure of hierarchically self-organized carbon nanotube (CNT) "forests" across 4 orders of magnitude in length scale, from 2.0 Å to 1.5 μm. Fully resolved structural features include the graphitic honeycomb lattice and interlayer walls (atomic), CNT diameter (nano), as well as the greater CNT ensemble (meso) and large corrugations (micro). Correlating orientational order across hierarchical levels revealed a cascading decrease as we probed finer structural feature sizes with enhanced sensitivity to small-scale disorder. Furthermore, we established qualitative relationships for single-, few-, and multiwall CNT forest characteristics, showing that multiscale orientational order is directly correlated with number density spanning 10 9 -10 12 cm -2 , yet order is inversely proportional to CNT diameter, number of walls, and atomic defects. Lastly, we captured and quantified ultralow-q meridional scattering features and built a phenomenological model of the large-scale CNT forest morphology, which predicted and confirmed that these features arise due to microscale corrugations along the vertical forest direction. Providing detailed structural information at multiple length scales is important for design and synthesis of CNT materials as well as other hierarchically organized nanostructures.

Developing a novel hierarchical approach for multiscale structural reliability predictions for ultra-high consequence applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Emery, John M.; Coffin, Peter; Robbins, Brian A.

Microstructural variabilities are among the predominant sources of uncertainty in structural performance and reliability. We seek to develop efficient algorithms for multiscale calcu- lations for polycrystalline alloys such as aluminum alloy 6061-T6 in environments where ductile fracture is the dominant failure mode. Our approach employs concurrent multiscale methods, but does not focus on their development. They are a necessary but not sufficient ingredient to multiscale reliability predictions. We have focused on how to efficiently use concurrent models for forward propagation because practical applications cannot include fine-scale details throughout the problem domain due to exorbitant computational demand. Our approach begins withmore » a low-fidelity prediction at the engineering scale that is sub- sequently refined with multiscale simulation. The results presented in this report focus on plasticity and damage at the meso-scale, efforts to expedite Monte Carlo simulation with mi- crostructural considerations, modeling aspects regarding geometric representation of grains and second-phase particles, and contrasting algorithms for scale coupling.« less

Dissipative structures in magnetorotational turbulence

NASA Astrophysics Data System (ADS)

Ross, Johnathan; Latter, Henrik N.

2018-07-01

Via the process of accretion, magnetorotational turbulence removes energy from a disc's orbital motion and transforms it into heat. Turbulent heating is far from uniform and is usually concentrated in small regions of intense dissipation, characterized by abrupt magnetic reconnection and higher temperatures. These regions are of interest because they might generate non-thermal emission, in the form of flares and energetic particles, or thermally process solids in protoplanetary discs. Moreover, the nature of the dissipation bears on the fundamental dynamics of the magnetorotational instability (MRI) itself: local simulations indicate that the large-scale properties of the turbulence (e.g. saturation levels and the stress-pressure relationship) depend on the short dissipative scales. In this paper we undertake a numerical study of how the MRI dissipates and the small-scale dissipative structures it employs to do so. We use the Godunov code RAMSES and unstratified compressible shearing boxes. Our simulations reveal that dissipation is concentrated in ribbons of strong magnetic reconnection that are significantly elongated in azimuth, up to a scale height. Dissipative structures are hence meso-scale objects, and potentially provide a route by which large scales and small scales interact. We go on to show how these ribbons evolve over time - forming, merging, breaking apart, and disappearing. Finally, we reveal important couplings between the large-scale density waves generated by the MRI and the small-scale structures, which may illuminate the stress-pressure relationship in MRI turbulence.

Programmable Potentials: Approximate N-body potentials from coarse-level logic.

PubMed

Thakur, Gunjan S; Mohr, Ryan; Mezić, Igor

2016-09-27

This paper gives a systematic method for constructing an N-body potential, approximating the true potential, that accurately captures meso-scale behavior of the chemical or biological system using pairwise potentials coming from experimental data or ab initio methods. The meso-scale behavior is translated into logic rules for the dynamics. Each pairwise potential has an associated logic function that is constructed using the logic rules, a class of elementary logic functions, and AND, OR, and NOT gates. The effect of each logic function is to turn its associated potential on and off. The N-body potential is constructed as linear combination of the pairwise potentials, where the "coefficients" of the potentials are smoothed versions of the associated logic functions. These potentials allow a potentially low-dimensional description of complex processes while still accurately capturing the relevant physics at the meso-scale. We present the proposed formalism to construct coarse-grained potential models for three examples: an inhibitor molecular system, bond breaking in chemical reactions, and DNA transcription from biology. The method can potentially be used in reverse for design of molecular processes by specifying properties of molecules that can carry them out.

Seasonal meso- and microhabitat selection by the northern snakehead (Channa argus) in the Potomac river system

USGS Publications Warehouse

Lapointe, N.W.R.; Thorson, J.T.; Angermeier, P.L.

2010-01-01

 The northern snakehead (Channa argus) is a large piscivorous fish that is invasive in eastern Europe and has recently been introduced in North America. We examined the seasonal habitat selection at meso- and microhabitat scales using radio-telemetry to increase understanding of the ecology of this species, which will help to inform management decisions. After the spawning season (postspawn season, September–November), northern snakeheads preferred offshore Eurasian water-milfoil (Myriophyllum spicatum) beds with shallow water (∼115 cm) and soft substrate. In the winter (November–April), these fish moved to deeper water (∼135 cm) with warmer temperatures, but habitat selection was weak at both scales. Northern snakeheads returned to shallower water (∼95 cm) in the prespawn season (April–June) and used milfoil and other cover. Habitat selection was the strongest at both meso- and microhabitat scales during the spawning season (June–September), when fish preferred macrophytes and cover in shallow water (∼88 cm). Our results help to identify habitats at the risk of invasion by northern snakeheads. We suggest that control efforts and future research focus on shallow waters, and take into consideration the seasonal habitat preferences.

Seasonal meso- and microhabitat selection by the northern snakehead (Channa argus) in the Potomac river system

USGS Publications Warehouse

Lapointe, N.W.R.; Thorson, J.T.; Angermeier, P.L.

2010-01-01

The northern snakehead (Channa argus) is a large piscivorous fish that is invasive in eastern Europe and has recently been introduced in North America. We examined the seasonal habitat selection at meso- and microhabitat scales using radio-telemetry to increase understanding of the ecology of this species, which will help to inform management decisions. After the spawning season (postspawn season, September-November), northern snakeheads preferred offshore Eurasian water-milfoil (Myriophyllum spicatum) beds with shallow water (115 cm) and soft substrate. In the winter (November-April), these fish moved to deeper water (135 cm) with warmer temperatures, but habitat selection was weak at both scales. Northern snakeheads returned to shallower water (95 cm) in the prespawn season (April-June) and used milfoil and other cover. Habitat selection was the strongest at both meso- and microhabitat scales during the spawning season (June-September), when fish preferred macrophytes and cover in shallow water (88 cm). Our results help to identify habitats at the risk of invasion by northern snakeheads. We suggest that control efforts and future research focus on shallow waters, and take into consideration the seasonal habitat preferences. ?? 2010 John Wiley & Sons A/S.

Selective on site separation and detection of molecules in diluted solutions with super-hydrophobic clusters of plasmonic nanoparticles.

PubMed

Gentile, Francesco; Coluccio, Maria Laura; Zaccaria, Remo Proietti; Francardi, Marco; Cojoc, Gheorghe; Perozziello, Gerardo; Raimondo, Raffaella; Candeloro, Patrizio; Di Fabrizio, Enzo

2014-07-21

Super-hydrophobic surfaces are bio-inspired interfaces with a superficial texture that, in its most common evolution, is formed by a periodic lattice of silicon micro-pillars. Similar surfaces reveal superior properties compared to conventional flat surfaces, including very low friction coefficients. In this work, we modified meso-porous silicon micro-pillars to incorporate networks of metal nano-particles into the porous matrix. In doing so, we obtained a multifunctional-hierarchical system in which (i) at a larger micrometric scale, the super-hydrophobic pillars bring the molecules dissolved in an ultralow-concentration droplet to the active sites of the device, (ii) at an intermediate meso-scale, the meso-porous silicon film adsorbs the low molecular weight content of the solution and, (iii) at a smaller nanometric scale, the aggregates of silver nano-particles would measure the target molecules with unprecedented sensitivity. In the results, we demonstrated how this scheme can be utilized to isolate and detect small molecules in a diluted solution in very low abundance ranges. The presented platform, coupled to Raman or other spectroscopy techniques, is a realistic candidate for the protein expression profiling of biological fluids.

Programmable Potentials: Approximate N-body potentials from coarse-level logic

NASA Astrophysics Data System (ADS)

Thakur, Gunjan S.; Mohr, Ryan; Mezić, Igor

2016-09-01

This paper gives a systematic method for constructing an N-body potential, approximating the true potential, that accurately captures meso-scale behavior of the chemical or biological system using pairwise potentials coming from experimental data or ab initio methods. The meso-scale behavior is translated into logic rules for the dynamics. Each pairwise potential has an associated logic function that is constructed using the logic rules, a class of elementary logic functions, and AND, OR, and NOT gates. The effect of each logic function is to turn its associated potential on and off. The N-body potential is constructed as linear combination of the pairwise potentials, where the “coefficients” of the potentials are smoothed versions of the associated logic functions. These potentials allow a potentially low-dimensional description of complex processes while still accurately capturing the relevant physics at the meso-scale. We present the proposed formalism to construct coarse-grained potential models for three examples: an inhibitor molecular system, bond breaking in chemical reactions, and DNA transcription from biology. The method can potentially be used in reverse for design of molecular processes by specifying properties of molecules that can carry them out.

Programmable Potentials: Approximate N-body potentials from coarse-level logic

PubMed Central

Thakur, Gunjan S.; Mohr, Ryan; Mezić, Igor

2016-01-01

This paper gives a systematic method for constructing an N-body potential, approximating the true potential, that accurately captures meso-scale behavior of the chemical or biological system using pairwise potentials coming from experimental data or ab initio methods. The meso-scale behavior is translated into logic rules for the dynamics. Each pairwise potential has an associated logic function that is constructed using the logic rules, a class of elementary logic functions, and AND, OR, and NOT gates. The effect of each logic function is to turn its associated potential on and off. The N-body potential is constructed as linear combination of the pairwise potentials, where the “coefficients” of the potentials are smoothed versions of the associated logic functions. These potentials allow a potentially low-dimensional description of complex processes while still accurately capturing the relevant physics at the meso-scale. We present the proposed formalism to construct coarse-grained potential models for three examples: an inhibitor molecular system, bond breaking in chemical reactions, and DNA transcription from biology. The method can potentially be used in reverse for design of molecular processes by specifying properties of molecules that can carry them out. PMID:27671683

Meso-Cenozoic morphological evolution of NW Africa, the case of the Tuareg swell.

NASA Astrophysics Data System (ADS)

Rougier, S.; Gautheron, C.; Barbarand, J.; Missenard, Y.; Zeyen, H.; Pinna, R.; Bonin, B.; Liégeois, J.-P.; Ouabadi, A.; Frizon de Lamotte, D.

2012-04-01

The continental crust of Africa, largely built during the Pan-African orogeny (late Neoproterozoic) has acquired in its northern part, during Paleozoic times, an arch and basin morphology. Meso-Cenozoic large scale topographic anomalies, associated to Cenozoic intraplate volcanism, such as Hoggar, Tibesti or Darfur domes, are superimposed to these structures. Precise ages of swells, as well as their relations with Paleozoic arch and basin morphology of the area, remain controversial. The aim of this study, focussed on the Hoggar dome, in southern Algeria, is to produce new constraints on the Post-Paleozoic evolution of this region. The Tuareg shield, from which Hoggar is the main central part and Aïr a SE extension, forms a topographic high reaching an altitude >2900m (Mt Tahat, Atakor district), exposing Precambrian rocks over 500000km2. While presumed Cretaceous sedimentary remnants suggest a possible stage of slightly positive topography during the Mesozoic, current high topography is emphasized by Cenozoic volcanic formations, mostly basaltic in composition. We present new low-temperature thermochronology data, with apatite fission track and (U-Th)/He ages on Hoggar and Aïr substratum. We combine these results with thermal, gravimetric and isostatic two-dimensional lithosphere-scale geophysical models, following the method of Zeyen & Fernandez (1994). Preliminary thermochronological results present ages from 99+-6 to 166+-10 Myr for AFT, and AHe from 10 to 300 Myr. Thermal simulations of these data suggest that currently outcropping Precambrian Hoggar basement could have experienced temperatures of approximately 80°C between Upper Cretaceous and Eocene. We propose that these elevated temperatures are related to burial beneath a 1 to 3 km thick sedimentary cover, depending on thermal gradient. The base of this sedimentary cover could correspond to the poorly described Upper Cretaceous remnants, currently uplifted up to 1450 m. These results are in agreement with geophysical calculations showing that, when eliminating the topographical effect of lithosphere heating related to recent volcanism and assuming an Upper Cretaceous to Late Eocene thermally unperturbed lithosphere, a sedimentary basin may have existed. Up to 2 km of Cretaceous sediments could have been deposited on the Hoggar, confirming the thermochronological results. Ref: Zeyen, H. and M. Fernàndez (1994): Integrated lithospheric modeling combining thermal, gravity and local isostasy analysis: application to the NE Spanish Geotransect. J. Geophys. Res. 99: 18089-18102.

Improvement in the accuracy of back trajectories using WRF to identify pollen sources in southern Iberian Peninsula.

PubMed

Hernández-Ceballos, M A; Skjøth, C A; García-Mozo, H; Bolívar, J P; Galán, C

2014-12-01

Airborne pollen transport at micro-, meso-gamma and meso-beta scales must be studied by atmospheric models, having special relevance in complex terrain. In these cases, the accuracy of these models is mainly determined by the spatial resolution of the underlying meteorological dataset. This work examines how meteorological datasets determine the results obtained from atmospheric transport models used to describe pollen transport in the atmosphere. We investigate the effect of the spatial resolution when computing backward trajectories with the HYSPLIT model. We have used meteorological datasets from the WRF model with 27, 9 and 3 km resolutions and from the GDAS files with 1° resolution. This work allows characterizing atmospheric transport of Olea pollen in a region with complex flows. The results show that the complex terrain affects the trajectories and this effect varies with the different meteorological datasets. Overall, the change from GDAS to WRF-ARW inputs improves the analyses with the HYSPLIT model, thereby increasing the understanding the pollen episode. The results indicate that a spatial resolution of at least 9 km is needed to simulate atmospheric flows that are considerable affected by the relief of the landscape. The results suggest that the appropriate meteorological files should be considered when atmospheric models are used to characterize the atmospheric transport of pollen on micro-, meso-gamma and meso-beta scales. Furthermore, at these scales, the results are believed to be generally applicable for related areas such as the description of atmospheric transport of radionuclides or in the definition of nuclear-radioactivity emergency preparedness.

Improvement in the accuracy of back trajectories using WRF to identify pollen sources in southern Iberian Peninsula

NASA Astrophysics Data System (ADS)

Hernández-Ceballos, M. A.; Skjøth, C. A.; García-Mozo, H.; Bolívar, J. P.; Galán, C.

2014-12-01

Airborne pollen transport at micro-, meso-gamma and meso-beta scales must be studied by atmospheric models, having special relevance in complex terrain. In these cases, the accuracy of these models is mainly determined by the spatial resolution of the underlying meteorological dataset. This work examines how meteorological datasets determine the results obtained from atmospheric transport models used to describe pollen transport in the atmosphere. We investigate the effect of the spatial resolution when computing backward trajectories with the HYSPLIT model. We have used meteorological datasets from the WRF model with 27, 9 and 3 km resolutions and from the GDAS files with 1 ° resolution. This work allows characterizing atmospheric transport of Olea pollen in a region with complex flows. The results show that the complex terrain affects the trajectories and this effect varies with the different meteorological datasets. Overall, the change from GDAS to WRF-ARW inputs improves the analyses with the HYSPLIT model, thereby increasing the understanding the pollen episode. The results indicate that a spatial resolution of at least 9 km is needed to simulate atmospheric flows that are considerable affected by the relief of the landscape. The results suggest that the appropriate meteorological files should be considered when atmospheric models are used to characterize the atmospheric transport of pollen on micro-, meso-gamma and meso-beta scales. Furthermore, at these scales, the results are believed to be generally applicable for related areas such as the description of atmospheric transport of radionuclides or in the definition of nuclear-radioactivity emergency preparedness.

Challenges in Ocean Data Assimilation for the US West Coast

NASA Astrophysics Data System (ADS)

Li, Z.; Chao, Y.; Farrara, J.; Wang, X.

2006-12-01

A three-dimensional variational data assimilation (3DVAR) system has been developed for the Regional Ocean Modeling System (ROMS), and it is called ROMS-DAS. This system provides a capability of predicting meso- to small-scale variations with temporal scales from hours to days in the coastal oceans. To cope with the particular difficulties that result from complex coastlines and bottom topography, unbalanced flows and sparse observations, ROMS-DAS utilizes several novel strategies. These strategies include the implementation of three-dimensional anisotropic and inhomogeneous error correlations, application of particular weak dynamic constraints, and implementation of efficient and reliable algorithms for minimizing the cost function. The ROMS-DAS system was applied in field experiments for Monterey Bay during both 2003 (Autonomous Ocean Sampling Network - AOSN) and 2006 (MB06). These two experiments included intensive data collection from a variety of observational platforms, including satellites, airplanes, High Frequency radars, Acoustic Doppler Current Profilers, ships, drifters, buoys, autonomous underwater vehicles (AUV), and particularly a fleet of undersea gliders. Using these data sets, various data assimilation experiments were performed to address several major data assimilation challenges that arise from multi-scales structures, inhomogeneous properties, dynamical imbalance of the flow, and tides. Basing on these experiments, a set of strategies were formulated to deal with those challenges.

Semi-isolated, flat-topped carbonate platform (Oligo-Miocene, Sardinia, Italy): Sedimentary architecture and processes

NASA Astrophysics Data System (ADS)

Andreucci, Stefano; Pistis, Marco; Funedda, Antonio; Loi, Alfredo

2017-11-01

The Chattian-Aquitanian carbonate system of Isili sub-basin (SE Sardinia, Italy) were studied to better understand the hydrodynamic processes controlling the formation of landward-downlapping, rhodolith-rich, giant clinoforms. The studied flat-topped platform was attached to an island (semi-isolated) and migrated onshore (landward) over a shallow marine, protected embayment. The depositional profile is characterized by four, sea to land, zones: seaward slope, flat-topped platform (submerged flat), landward slope and mixed siliciclastic-carbonate embayment. In particular, these zones record different levels, from high to moderate, of hydrodynamic energy and persistency. The paleodepth of the studied succession, based on T/D test on Amphistegina specimens, red-algal genera and geometric reconstruction of the overall system, ranges from - 10 to - 30 m for the platform up to around - 40 m for the landward slope base. Thus, the flat-topped platform was permanently submerged and an extensive carbonate (sea grass, algal and bryozoan-algal) factory along with oyster framestones developed. The widespread presence in the barren zones of rhodolith-to-shell rich small to very small compound dunes (high-energy zone) suggests that the flat-topped platform was periodically swept by unidirectional, landward-directed currents. These currents allow the formation of large-scale, rhodolith-rich clinobeds along the landward slope (washover fan-like system). The presence of rodolith pavements developed along the flat-topped platform at or slightly below the fairweather wave base suggests that clinobeds were formed in a nearshore, shallow subtidal setting. Finally, the shallow marine, protected embayment (moderate-energy zone) represents the widening distal reaches of the currents flowing or along the clinoforms or from the coast basinward (river floods and/or ebb tidal currents). Despite few tidal-related sedimentary structures such as bi-directional ripples and small compound dunes separated by finer-grained ;drapes; or reactivation surfaces were observed, the prevailing processes acting over the platform are unidirectional, landward-directed currents possibly associated with longshore currents and/or wave actions. However, the resultant migration of the whole system onshore (landward) cannot be easily explained with storm or wind-related processes. Thus the studied flat-topped platform seems to be controlled by long term tidal regulation within a meso to macro tidal regime. In particular, such meso/macro tidal environments experience multiannual to multidecennial phases of stronger/weaker tidal range fluctuations resembling periods of relatively sea highs and lows with respect to the mean sea level (0 m). All the (wind, storm, wave and tidal) currents sweeping the flat-topped platform were maxima during phases of strong tidal fluctuations generating erosion and sediment transportation over the flat and accumulation on the landward slope (clinobeds). Conversely, during phases of weaker tidal range fluctuations overall currents were minima, clinoforms did not develop and factories widespread re-colonized the submerged flat. Therefore, the studied platform developed in a current-dominated and tidal modulated setting. Finally, the studied carbonates of Sardinia suggest that the Sardinian seaway and the incipient Provençal basin during the Chattian-Aquitanian were, locally, capable to generate meso to macro tidal conditions.

Using container orchestration to improve service management at the RAL Tier-1

NASA Astrophysics Data System (ADS)

Lahiff, Andrew; Collier, Ian

2017-10-01

In recent years container orchestration has been emerging as a means of gaining many potential benefits compared to a traditional static infrastructure, such as increased utilisation through multi-tenancy, improved availability due to self-healing, and the ability to handle changing loads due to elasticity and auto-scaling. To this end we have been investigating migrating services at the RAL Tier-1 to an Apache Mesos cluster. In this model the concept of individual machines is abstracted away and services are run in containers on a cluster of machines, managed by schedulers, enabling a high degree of automation. Here we describe Mesos, the infrastructure deployed at RAL, and describe in detail the explicit example of running a batch farm on Mesos.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boybeyi, Zafer

The Department of Energy (DOE) awarded George Mason University (GMU) with a research project. This project started on June, 2009 and ended July 2014. Main objectives of this research project are; a) to assess the indirect and semi-direct aerosol effects on microphysical structure and radiative properties of Arctic clouds, b) to assess the impact of feedback between the aerosol-cloud interactions and atmospheric boundary layer (ABL) processes on the surface energy balance, c) to better understand and characterize the important unresolved microphysical processes, aerosol effects, and ABL processes and feedbacks, over meso-γ spatial (~1-2 km) and temporal scales (a few minutesmore » to days), and d) to investigate the scale dependency of microphysical parameterizations and its effect on simulations.« less

Controlled In Meso Phase Crystallization – A Method for the Structural Investigation of Membrane Proteins

PubMed Central

Kubicek, Jan; Schlesinger, Ramona; Baeken, Christian; Büldt, Georg; Schäfer, Frank; Labahn, Jörg

2012-01-01

We investigated in meso crystallization of membrane proteins to develop a fast screening technology which combines features of the well established classical vapor diffusion experiment with the batch meso phase crystallization, but without premixing of protein and monoolein. It inherits the advantages of both methods, namely (i) the stabilization of membrane proteins in the meso phase, (ii) the control of hydration level and additive concentration by vapor diffusion. The new technology (iii) significantly simplifies in meso crystallization experiments and allows the use of standard liquid handling robots suitable for 96 well formats. CIMP crystallization furthermore allows (iv) direct monitoring of phase transformation and crystallization events. Bacteriorhodopsin (BR) crystals of high quality and diffraction up to 1.3 Å resolution have been obtained in this approach. CIMP and the developed consumables and protocols have been successfully applied to obtain crystals of sensory rhodopsin II (SRII) from Halobacterium salinarum for the first time. PMID:22536388

Polyethylenimine-incorporated zeolite 13X with mesoporosity for post-combustion CO2 capture

NASA Astrophysics Data System (ADS)

Chen, Chao; Kim, Su-Sung; Cho, Won-Seung; Ahn, Wha-Seung

2015-03-01

X-type zeolite with mesoporosity (Meso-13X) was prepared by using dimethyloctadecyl[3-(trimethoxysilyl)propyl]ammonium chloride as a mesopore-generating agent, and then modified with polyethylenimine (PEI) through a physical impregnation method to form a hybrid material (Meso-13X-PEI). Meso-13X with and without PEI was characterized by X-ray powder diffraction (XRD), N2 adsorption-desorption isotherm at 77 K, scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). Meso-13X-PEI exhibited higher CO2 capture capacity than PEI-modified zeolite 13X owing to its larger pore volume that accommodates more amine species inside the pore structure, and the mesoporosity also can facilitate dispersion of PEI molecules inside the pore channels. Compared to zeolite 13X, Meso-13X-PEI showed much higher CO2 capture selectivity (against N2) as well as higher CO2 capture capacity at relatively high temperature (e.g. 100 °C) and dilute CO2 concentration relevant to post-combustion conditions.

Direct observation of macrostructure formation of hierarchically structured meso-macroporous aluminosilicates with 3D interconnectivity by optical microscope.

PubMed

Lemaire, Arnaud; Rooke, Joanna Claire; Chen, Li-Hua; Su, Bao-Lian

2011-03-15

Hierarchically structured spongy meso-macroporous aluminosilicates with high tetrahedral aluminum content were synthesized from a mixture of single molecular alkoxide precursor, (sec-BuO)2-Al-O-Si(OEt)3, already containing Si-O-Al bonds, and a silica coreactant, tetramethoxysilane (TMOS). The spontaneous byproduct templated macroporous structure formation has been directly visualized using in situ high-resolution optical microscopy (OM), allowing the crucial observation of a microbubble dispersion which is directly correlated to the macrostructure observed by electronic microscopies (SEM and TEM). This discovery leads to a comparative study with meso-macroporous pure metal oxide and to a proposal of the formation mechanism of meso-macroporous aluminosilicates with 3D interconnectivity. The aluminosilicate phase/microbubbles emulsion is produced by a phase separation process occurring between the aluminosilicate nanoparticles and the liquid hydrolysis-condensation reaction byproducts (water, methanol, ethanol, and butanol). The use of alkoxysilane improves the heterocondensation rates between the highly reactive aluminum alkoxide part of the single precursor and added silica species but, above all, leads to the spontaneous generation of an unusual meso-macroporosity in alkaline media. The particles obtained at pH = 13.0 featured regular micrometer-sized macrospheres separated by very thin mesoporous walls and connected by submicrometric openings, providing a 3D interconnectivity. The slight increase in pH value to 13.5 induced significant modifications in morphology and textural properties due to the slower gelification process of the aluminosilicate phase, resulting in the formation of an aluminosilicate material constituted of 1-2 µm large independent hollow mesoporous spheres.

Ocean Striations Detecting and Its Features

NASA Astrophysics Data System (ADS)

Guan, Y. P.; Zhang, Y.; Chen, Z.; Liu, H.; Yu, Y.; Huang, R. X.

2016-02-01

Over the past 10 years or so, ocean striations has been one of the research frontiers as reported in many investigators. With suitable filtering subroutines, striations can be revealed from many different types of ocean datasets. It is clear that striations are some types of meso-scale phenomena in the large-scale circulation system, which in the form of alternating band-like structure. We present a comprehensive study on the effectiveness of the different detection approaches to unveiling the striations. Three one-dimensional filtering methods: Gaussian smoothing, Hanning and Chebyshev high-pass filtering. Our results show that all three methods can reveal ocean banded structures, but the Chebyshev filtering is the best choice. The Gaussian smoothing is not a high pass filter, and it can merely bring regional striations, such as those in the Eastern Pacific, to light. The Hanning high pass filter can introduce a northward shifting of stripes, so it is not as good as the Chebyshev filter. On the other hand, striations in the open ocean are mostly zonally oriented; however, there are always exceptions. In particular, in coastal ocean, due to topography constraint and along shore currents, striations can titled in the meridional direction. We examined the band-like structure of striation for some selected regions of the open ocean and the semi-closed sub-basins, such as the South China sea, the Gulf of Mexico, the Mediterranean Sea and the Japan Sea. A reasonable interpretation is given here.

Multi-Scale Modeling of an Integrated 3D Braided Composite with Applications to Helicopter Arm

NASA Astrophysics Data System (ADS)

Zhang, Diantang; Chen, Li; Sun, Ying; Zhang, Yifan; Qian, Kun

2017-10-01

A study is conducted with the aim of developing multi-scale analytical method for designing the composite helicopter arm with three-dimensional (3D) five-directional braided structure. Based on the analysis of 3D braided microstructure, the multi-scale finite element modeling is developed. Finite element analysis on the load capacity of 3D five-directional braided composites helicopter arm is carried out using the software ABAQUS/Standard. The influences of the braiding angle and loading condition on the stress and strain distribution of the helicopter arm are simulated. The results show that the proposed multi-scale method is capable of accurately predicting the mechanical properties of 3D braided composites, validated by the comparison the stress-strain curves of meso-scale RVCs. Furthermore, it is found that the braiding angle is an important factor affecting the mechanical properties of 3D five-directional braided composite helicopter arm. Based on the optimized structure parameters, the nearly net-shaped composite helicopter arm is fabricated using a novel resin transfer mould (RTM) process.

Properties of the Agulhas Current's Inshore Front During The Shelf Agulhas Glider Experiment (SAGE)

NASA Astrophysics Data System (ADS)

Krug, M.; Swart, S.; Goschen, W.

2016-02-01

The response of coastal and shelf regions to changes in the Agulhas Current remains poorly studied. This is partly due to observational challenges associated with sampling western boundary currents. Cross-shelf exchange in such energetic current systems occurs through a range of meso- ( 50-200 km) and sub-meso (<10 km) scale processes which are difficult to observe using moored current arrays or Lagrangian platforms. Profiling gliders offer a revolutionary technology to continuously sample the energetic inshore regions of the Agulhas Current at a high spatial (100's of meters to 3km - well within the sub-mesoscale range) and temporal (0.5-4 hourly) resolution. In April 2015, two SeaGliders were deployed off Port Elizabeth (34S) at the inshore edge of the Agulhas Current as part of the Shelf Agulhas Glider Experiment (SAGE), testing for the very 1st time the feasibility of operating autonomous platforms in this highly turbulent and energetic western boundary current system. For a period of approximately two months, the Seagliders provided continuous observations at the inshore boundary of the Agulhas Current at an unprecedented spatial resolution. Observations from the Seagliders showed that at the inshore edge of the Agulhas Current, both surface and depth averaged currents are aligned in a south-west / north- east direction, with stronger flows encountered over deeper regions of the shelf, when the gliders are closer to the Agulhas Current. In the absence of large meanders, the mean flow at the inshore boundary of the Agulhas Current is characterised by strong shear with a counter current flowing in opposite direction to the mean current field. Instances of counter currents occur 45% of the time in the surface flow and 54% of the time in the depth-averaged record. More than 80% of return flow occurrences occur when glider is in water depth of less than 200m.

A unique skeletal microstructure of the deep-sea micrabaciid scleractinian corals

NASA Astrophysics Data System (ADS)

Janiszewska, Katarzyna; Stolarski, Jaroslaw; Benzerara, Karim; Meibom, Anders; Mazur, Maciej; Kitahara, Marcelo; Cairns, Stephen D.

2010-05-01

Structural and biogeochemical properties of the skeleton of many invertebrates rely on organic matrix-mediated biomineralization processes. Organic matrices, composed of complex assemblages of macromolecules (proteins, polysaccharides), may control nucleation, spatial delineation and organization of basic microstructural units. Biologically controlled mineralization is also suggested for the scleractinian corals whose different, molecularly recognized clades are supported by distinct types of skeletal microstructures. Main differences in scleractinian coral skeletal microstructures suggested so far consist in (1) varying spatial relationships between Rapid Accretion Deposits (RAD, 'centers of calcification') and thickening deposits (TD, 'fibers'), and (2) varying arrangements of biomineral fibers into higher order structures (e.g., bundles of fibers perpendicular to skeletal surfaces in some 'caryophylliid' corals vs. scale-like units with fibers parallel to the surface in acroporiids). However, a common feature of biomineral fibers in corals described thus far was their similar crystallographic arrangement within larger meso-scale structures (bundles of fibers) and continuity between successive growth layers. Herein we show that representatives of the deep-sea scleractinian family Micrabaciidae (genera: Letepsammia, Rhombopsammia, Stephanophyllia, Leptopenus) have thickening deposits composed of irregular meshwork of short (1-2 μm) and extremely thin (ca. 100-300 nm) fibers organized into small bundles (ca. 1-2 μm thick). Longer axes of fibers are aligned within individual bundles that, in turn, show rather irregular arrangement on the growing surfaces and within the skeleton (irregular criss-cross pattern). In contrast to other scleractinians (including deep-water 'caryophylliids', fungiacyathids, and anthemiphyllids sympatric with micrabaciids), growth layers are not distinct. Also the regions of rapid accretion and thickening deposits are not clearly separated at the meso-scale. However, AFM and FESEM observations of RAD show nanogranular units (ca. 30-100 nm in diameter) typical of fast growing skeletal regions. Unique microstructural organization of the micrabaciid skeleton supports their monophyletic status (reinforced by macromorphological and molecular data), and points to a diversity of organic matrix-mediated biomineralization strategies in Scleractinia.

Relation between the Hurst Exponent and the Efficiency of Self-organization of a Deformable System

NASA Astrophysics Data System (ADS)

Alfyorova, E. A.; Lychagin, D. V.

2018-04-01

We have established the degree of self-organization of a system under plastic deformation at different scale levels. Using fractal analysis, we have determined the Hurst exponent and correlation lengths in the region of formation of a corrugated (wrinkled) structure in [111] nickel single crystals under compression. This has made it possible to single out two (micro-and meso-) levels of self-organization in the deformable system. A qualitative relation between the values of the Hurst exponent and the stages of the stress-strain curve has been established.

Crystal Plasticity Model of Reactor Pressure Vessel Embrittlement in GRIZZLY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chakraborty, Pritam; Biner, Suleyman Bulent; Zhang, Yongfeng

2015-07-01

The integrity of reactor pressure vessels (RPVs) is of utmost importance to ensure safe operation of nuclear reactors under extended lifetime. Microstructure-scale models at various length and time scales, coupled concurrently or through homogenization methods, can play a crucial role in understanding and quantifying irradiation-induced defect production, growth and their influence on mechanical behavior of RPV steels. A multi-scale approach, involving atomistic, meso- and engineering-scale models, is currently being pursued within the GRIZZLY project to understand and quantify irradiation-induced embrittlement of RPV steels. Within this framework, a dislocation-density based crystal plasticity model has been developed in GRIZZLY that captures themore » effect of irradiation-induced defects on the flow stress behavior and is presented in this report. The present formulation accounts for the interaction between self-interstitial loops and matrix dislocations. The model predictions have been validated with experiments and dislocation dynamics simulation.« less

Comparative CYP-dependent binding of the adrenocortical toxicants 3-methylsulfonyl-DDE and o,p'-DDD in Y-1 adrenal cells.

PubMed

Hermansson, Veronica; Asp, Vendela; Bergman, Ake; Bergström, Ulrika; Brandt, Ingvar

2007-11-01

The environmental pollutant 3-MeSO(2)-DDE [2-(3-methylsulfonyl-4-chlorophenyl)-2-(4-chlorophenyl)-1,1-dichloroethene] is an adrenocortical toxicant in mice, specifically in the glucocorticoid-producing zona fasciculata, due to a cytochrome P450 11B1 (CYP11B1)-catalysed bioactivation and formation of covalently bound protein adducts. o,p'-DDD [2-(2-chlorophenyl)-2-(4-chlorophenyl)-1,1-dichloroethane] is toxic and inhibits steroidogenesis in the human adrenal cortex after bioactivation by unidentified CYPs, but does not exert any toxic effects on the mouse adrenal. As a step towards determining in vitro/in vivo relationships for the CYP-catalysed binding and toxicity of 3-MeSO(2)-DDE and o,p'-DDD, we have investigated the irreversible protein binding of these two toxicants in the murine adrenocortical cell line Y-1. The irreversible binding of 3-MeSO(2)-DDE previously demonstrated in vivo was successfully reproduced and could be inhibited by the CYP-inhibitors etomidate, ketoconazole and metyrapone. Surprisingly, o,p'-DDD reached similar levels of binding as 3-MeSO(2)-DDE. The binding of o,p'-DDD was sensitive to etomidate and ketoconazole, but not to metyrapone. Moreover, GSH depletion increased the binding of 3-MeSO(2)-DDE, but not of o,p'-DDD, indicating an important role of GSH conjugation in the detoxification of the 3-MeSO(2)-DDE-derived reactive metabolite. In addition, the specificity of CYP11B1 in activating 3-MeSO(2)-DDE was investigated using structurally analogous compounds. None of the analogues produced histopathological lesions in the mouse adrenal in vivo following a single i.p. injection of 100 mg/kg body weight, but two of the compounds were able to decrease the irreversible binding of 3-MeSO(2)-DDE to Y-1 cells. These results indicate that the bioactivation of 3-MeSO(2)-DDE by CYP11B1 is highly structure-dependent. In conclusion, both 3-MeSO(2)-DDE and o,p'-DDD bind irreversibly to Y-1 cells despite differences in binding and adrenotoxicity in mice in vivo. This reveals a notable in vitro/in vivo discrepancy, the contributing factors of which remain unexplained. We consider the Y-1 cell line as appropriate for studies of the cellular mechanisms behind the adrenocortical toxicity of these substances.

Development of a Meso-Scale Fiberoptic Rotation Sensor for a Torsion Actuator.

PubMed

Sheng, Jun; Desai, Jaydev P

2018-01-01

This paper presents the development of a meso-scale fiberoptic rotation sensor for a shape memory alloy (SMA) torsion actuator for neurosurgical applications. Within the sensor, a rotary head with a reflecting surface is capable of modulating the light intensity collected by optical fibers when the rotary head is coupled to the torsion actuator. The mechanism of light intensity modulation is modeled, followed by experimental model verification. Meanwhile, working performances for different rotary head designs, optical fibers, and fabrication materials are compared. After the calibration of the fiberoptic rotation sensor, the sensor is capable of precisely measuring rotary motion and controlling the SMA torsion actuator with feedback control.

Evolution of Meso-Cenozoic lithospheric thermal-rheological structure in the Jiyang sub-basin, Bohai Bay Basin, eastern North China Craton

NASA Astrophysics Data System (ADS)

Xu, Wei; Qiu, Nansheng; Wang, Ye; Chang, Jian

2018-01-01

The Meso-Cenozoic lithospheric thermal-rheological structure and lithospheric strength evolution of the Jiyang sub-basin were modeled using thermal history, crustal structure, and rheological parameter data. Results indicate that the thermal-rheological structure of the Jiyang sub-basin has exhibited obvious rheological stratification and changes over time. During the Early Mesozoic, the uppermost portion of the upper crust, middle crust, and the top part of the upper mantle had a thick brittle layer. During the early Early Cretaceous, the top of the middle crust's brittle layer thinned because of lithosphere thinning and temperature increase, and the uppermost portion of the upper mantle was almost occupied by a ductile layer. During the late Early Cretaceous, the brittle layer of the middle crust and the upper mantle changed to a ductile one. Then, the uppermost portion of the middle crust changed to a thin brittle layer in the late Cretaceous. During the early Paleogene, the thin brittle layer of the middle crust became even thinner and shallower under the condition of crustal extension. Currently, with the decrease in lithospheric temperature, the top of the upper crust, middle crust, and the uppermost portion of the upper mantle are of a brittle layer. The total lithospheric strength and the effective elastic thickness ( T e) in Meso-Cenozoic indicate that the Jiyang sub-basin experienced two weakened stages: during the late Early Cretaceous and the early Paleogene. The total lithospheric strength (approximately 4-5 × 1013 N m-1) and T e (approximately 50-60 km) during the Early Mesozoic was larger than that after the Late Jurassic (2-7 × 1012 N m-1 and 19-39 km, respectively). The results also reflect the subduction, and rollback of Pacific plate is the geodynamic mechanism of the destruction of the eastern North China Craton.

Density functional theory studies on the structures and electronic communication of meso-ferrocenylporphyrins: long range orbital coupling via porphyrin core.

PubMed

Zhang, Lijuan; Qi, Dongdong; Zhang, Yuexing; Bian, Yongzhong; Jiang, Jianzhuang

2011-02-01

The molecular and electronic structures together with the electronic absorption spectra of a series of metal free meso-ferrocenylporphyrins, namely 5-ferrocenylporphyrin (1), 5,10-diferrocenylporphyrin (2), 5,15-diferrocenylporphyrin (3), 5,10,15-triferrocenylporphyrin (4), and 5,10,15,20-tetraferrocenylporphyrin (5) have been studied with the density functional theory (DFT) and time-dependent density functional theory (TD-DFT) methods. For the purpose of comparative studies, metal free porphyrin without any ferrocenyl group (0) and isolated ferrocene (6) were also calculated. The effects of the number and position of meso-attached ferrocenyl substituents on their molecular and electronic structures, atomic charges, molecular orbitals, and electronic absorption spectra of 1-5 were systematically investigated. The orbital coupling is investigated in detail, explaining well the long range coupling of ferrocenyl substituents connected via porphyrin core and the systematic change in the electronic absorption spectra of porphyrin compounds. Copyright © 2010 Elsevier Inc. All rights reserved.

Production of ultra-thin nano-scaled graphene platelets from meso-carbon micro-beads

DOEpatents

Zhamu, Aruna; Guo, Jiusheng; Jang, Bor Z

2014-11-11

A method of producing nano-scaled graphene platelets (NGPs) having an average thickness no greater than 50 nm, typically less than 2 nm, and, in many cases, no greater than 1 nm. The method comprises (a) intercalating a supply of meso-carbon microbeads (MCMBs) to produce intercalated MCMBs; and (b) exfoliating the intercalated MCMBs at a temperature and a pressure for a sufficient period of time to produce the desired NGPs. Optionally, the exfoliated product may be subjected to a mechanical shearing treatment, such as air milling, air jet milling, ball milling, pressurized fluid milling, rotating-blade grinding, or ultrasonicating. The NGPs are excellent reinforcement fillers for a range of matrix materials to produce nanocomposites. Nano-scaled graphene platelets are much lower-cost alternatives to carbon nano-tubes or carbon nano-fibers.

Similar local order in disordered fluorite and aperiodic pyrochlore structures

DOE PAGES

Shamblin, Jacob; Tracy, Cameron; Palomares, Raul; ...

2017-10-01

A major challenge to understanding the response of materials to extreme environments (e.g., nuclear fuels/waste forms and fusion materials) is to unravel the processes by which a material can incorporate atomic-scale disorder, and at the same time, remain crystalline. While it has long been known that all condensed matter, even liquids and glasses, possess short-range order, the relation between fully-ordered, disordered, and aperiodic structures over multiple length scales is not well understood. For example, when defects are introduced (via pressure or irradiation) into materials adopting the pyrochlore structure, these complex oxides either disorder over specific crystallographic sites, remaining crystalline, ormore » become aperiodic. Here we present neutron total scattering results characterizing the irradiation response of two pyrochlores, one that is known to disorder (Er2Sn2O7) and the other to amorphize (Dy2Sn2O7) under ion irradiation. The results demonstrate that in both cases, the local pyrochlore structure is transformed into similar short range configurations that are best fit by the orthorhombic weberite structure, even though the two compositions have distinctly different structures, aperiodic vs. disordered-crystalline, at longer length scales. Thus, a material's resistance to amorphization may not depend primarily on local defect formation energies, but rather on the structure's compatibility with meso-scale modulations of the local order in a way that maintains long-range periodicity.« less

Experiences with the ALICE Mesos infrastructure

NASA Astrophysics Data System (ADS)

Berzano, D.; Eulisse, G.; Grigoraş, C.; Napoli, K.

2017-10-01

Apache Mesos is a resource management system for large data centres, initially developed by UC Berkeley, and now maintained under the Apache Foundation umbrella. It is widely used in the industry by companies like Apple, Twitter, and Airbnb and it is known to scale to 10 000s of nodes. Together with other tools of its ecosystem, such as Mesosphere Marathon or Metronome, it provides an end-to-end solution for datacenter operations and a unified way to exploit large distributed systems. We present the experience of the ALICE Experiment Offline & Computing in deploying and using in production the Apache Mesos ecosystem for a variety of tasks on a small 500 cores cluster, using hybrid OpenStack and bare metal resources. We will initially introduce the architecture of our setup and its operation, we will then describe the tasks which are performed by it, including release building and QA, release validation, and simple Monte Carlo production. We will show how we developed Mesos enabled components (called “Mesos Frameworks”) to carry out ALICE specific needs. In particular, we will illustrate our effort to integrate Work Queue, a lightweight batch processing engine developed by University of Notre Dame, which ALICE uses to orchestrate release validation. Finally, we will give an outlook on how to use Mesos as resource manager for DDS, a software deployment system developed by GSI which will be the foundation of the system deployment for ALICE next generation Online-Offline (O2).

Structural characterization of 1,3-propanedithiols that feature carboxylic acids: Homologues of mercury chelating agents ✩

PubMed Central

Sattler, Wesley; Palmer, Joshua H.; Bridges, Christy C.; Joshee, Lucy; Zalups, Rudolfs K.; Parkin, Gerard

2013-01-01

The molecular structures of a series of 1,3-propanedithiols that contain carboxylic acid groups, namely rac- and meso-2,4-dimercaptoglutaric acid (H4DMGA) and 2-carboxy-1,3-propanedithiol (H3DMCP), have been determined by X-ray diffraction. Each compound exhibits two centrosymmetric intermolecular hydrogen bonding interactions between pairs of carboxylic acid groups, which result in a dimeric structure for H3DMCP and a polymeric tape-like structure for rac- and meso-H4DMGA. Significantly, the hydrogen bonding motifs observed for rac- and meso-H4DMGA are very different to those observed for the 1,2-dithiol, rac-2,3-dimercaptosuccinic acid (rac-H4DMSA), in which the two oxygen atoms of each carboxylic acid group hydrogen bond to two different carboxylic acid groups, thereby resulting in a hydrogen bonded sheet-like structure rather than a tape. Density functional theory calculations indicate that 1,3-dithiolate coordination to mercury results in larger S–Hg–S bond angles than does 1,2-dithiolate coordination, but these angles are far from linear. As such, κ2-S2 coordination of these dithiolate ligands is expected to be associated with mercury coordination numbers of greater than two. In vivo studies demonstrate that both rac-H4DMGA and H3DMCP reduce the renal burden of mercury in rats, although the compounds are not as effective as either 2,3-dimercaptopropane-1-sulfonic acid (H3DMPS) or meso-H4DMSA. PMID:24187425

Defining environmental flows requirements at regional scale by using meso-scale habitat models and catchments classification

NASA Astrophysics Data System (ADS)

Vezza, Paolo; Comoglio, Claudio; Rosso, Maurizio

2010-05-01

The alterations of the natural flow regime and in-stream channel modification due to abstraction from watercourses act on biota through an hydraulic template, which is mediated by channel morphology. Modeling channel hydro-morphology is needed in order to evaluate how much habitat is available for selected fauna under specific environmental conditions, and consequently to assist decision makers in planning options for regulated river management. Meso-scale habitat modeling methods (e.g., MesoHABSIM) offer advantages over the traditional physical habitat evaluation, involving a larger range of habitat variables, allowing longer length of surveyed rivers and enabling understanding of fish behavior at larger spatial scale. In this study we defined a bottom-up method for the ecological discharge evaluation at regional scale, focusing on catchments smaller than 50 km2, most of them located within mountainous areas of Apennines and Alps mountain range in Piedmont (NW Italy). Within the regional study domain we identified 30 representative catchments not affected by water abstractions in order to build up the habitat-flow relationship, to be used as reference when evaluating regulated watercourses or new projects. For each stream we chose a representative reach and obtained fish data by sampling every single functional habitat (i.e. meso-habitat) within the site, keeping separated each area by using nets. The target species were brown trout (Salmo trutta), marble trout (Salmo trutta marmoratus), bullhead (Cottus gobius), chub (Leuciscus cephalus), barbel (Barbus barbus), vairone (Leuciscus souffia) and other rheophilic Cyprinids. The fish habitat suitability criteria was obtained from the observation of habitat use by a selected organism described with a multivariate relationship between habitat characteristics and fish presence. Habitat type, mean slope, cover, biotic choriotop and substrate, stream depth and velocity, water pH, temperature and percentage of dissolved oxygen were collected for each sampled area and considered as independent variables. According to the MesoHABSIM method, we performed a stepwise forward logistic regression in order to build up a biological model identifying the habitat characteristics mostly used by a target fish. For each stream we predicted changes in habitat area over a range of discharges by building the habitat-flow rating curves. Finally, in order to define a regional criteria needed to fulfill environmental flow requirements, we split the study domain according to the regression tree classification criterion defining homogenous sub-regions distinct on both environmental flows and catchment characteristics.

Human heme oxygenase oxidation of 5- and 15-phenylhemes.

PubMed

Wang, Jinling; Niemevz, Fernando; Lad, Latesh; Huang, Liusheng; Alvarez, Diego E; Buldain, Graciela; Poulos, Thomas L; de Montellano, Paul R Ortiz

2004-10-08

Human heme oxygenase-1 (hHO-1) catalyzes the O2-dependent oxidation of heme to biliverdin, CO, and free iron. Previous work indicated that electrophilic addition of the terminal oxygen of the ferric hydroperoxo complex to the alpha-meso-carbon gives 5-hydroxyheme. Earlier efforts to block this reaction with a 5-methyl substituent failed, as the reaction still gave biliverdin IXalpha. Surprisingly, a 15-methyl substituent caused exclusive cleavage at the gamma-meso-rather than at the normal, unsubstituted alpha-meso-carbon. No CO was formed in these reactions, but the fragment cleaved from the porphyrin eluded identification. We report here that hHO-1 cleaves 5-phenylheme to biliverdin IXalpha and oxidizes 15-phenylheme at the alpha-meso position to give 10-phenylbiliverdin IXalpha. The fragment extruded in the oxidation of 5-phenylheme is benzoic acid, one oxygen of which comes from O2 and the other from water. The 2.29- and 2.11-A crystal structures of the hHO-1 complexes with 1- and 15-phenylheme, respectively, show clear electron density for both the 5- and 15-phenyl rings in both molecules of the asymmetric unit. The overall structure of 15-phenylheme-hHO-1 is similar to that of heme-hHO-1 except for small changes in distal residues 141-150 and in the proximal Lys18 and Lys22. In the 5-phenylheme-hHO-1 structure, the phenyl-substituted heme occupies the same position as heme in the heme-HO-1 complex but the 5-phenyl substituent disrupts the rigid hydrophobic wall of residues Met34, Phe214, and residues 26-42 near the alpha-meso carbon. The results provide independent support for an electrophilic oxidation mechanism and support a role for stereochemical control of the reaction regiospecificity.

The impact of radiatively active water-ice clouds on Martian mesoscale atmospheric circulations

NASA Astrophysics Data System (ADS)

Spiga, A.; Madeleine, J.-B.; Hinson, D.; Navarro, T.; Forget, F.

2014-04-01

Background and Goals Water ice clouds are a key component of the Martian climate [1]. Understanding the properties of the Martian water ice clouds is crucial to constrain the Red Planet's climate and hydrological cycle both in the present and in the past [2]. In recent years, this statement have become all the more true as it was shown that the radiative effects of water ice clouds is far from being as negligible as hitherto believed; water ice clouds plays instead a key role in the large-scale thermal structure and dynamics of the Martian atmosphere [3, 4, 5]. Nevertheless, the radiative effect of water ice clouds at lower scales than the large synoptic scale (the so-called meso-scales) is still left to be explored. Here we use for the first time mesoscale modeling with radiatively active water ice clouds to address this open question.

Managing cancer care through service delivery networks: The role of professional collaboration in two European cancer networks.

PubMed

Prades, Joan; Morando, Verdiana; Tozzi, Valeria D; Verhoeven, Didier; Germà, Jose R; Borras, Josep M

2017-01-01

Background The study examines two meso-strategic cancer networks, exploring to what extent collaboration can strengthen or hamper network effectiveness. Unlike macro-strategic networks, meso-strategic networks have no hierarchical governance structures nor are they institutionalised within healthcare services' delivery systems. This study aims to analyse the models of professional cooperation and the tools developed for managing clinical practice within two meso-strategic, European cancer networks. Methods Multiple case study design based on the comparative analysis of two cancer networks: Iridium, in Antwerp, Belgium and the Institut Català d'Oncologia in Catalonia, Spain. The case studies applied mixed methods, with qualitative research based on semi-structured interviews ( n = 35) together with case-site observation and material collection. Results The analysis identified four levels of collaborative intensity within medical specialties as well as in multidisciplinary settings, which became both platforms for crosscutting clinical work between hubs' experts and local care teams and the levers for network-based tools development. The organisation of clinical practice relied on professional-based cooperative processes and tiers, lacking vertical integration mechanisms. Conclusions The intensity of professional linkages largely shaped the potential of meso-strategic cancer networks to influence clinical practice organisation. Conversely, the introduction of managerial techniques or network governance structures, without introducing vertical hierarchies, was found to be critical solutions.

Exploring the binding mechanisms of diaminopimelic acid analogs to meso-diaminopimelate dehydrogenase by molecular modeling.

PubMed

Wang, Huiqun; Kellogg, Glen E; Xu, Ping; Zhang, Yan

2018-06-02

Meso-Diaminopimelic acid (meso-2,6-diamino-heptanedioic acid, DAP) is an important component of the cell wall of many bacteria. Meso-diaminopimelate dehydrogenase (m-Ddh) is a critical enzyme in the process of converting tetrahydrodipicolinate to DAP. Here, we are proposing that DAP analogs targeting m-Ddh may be considered as potential antibiotics. Four DAP analogs without significant structural change from DAP have been obtained and their inhibitory potencies against m-Ddh from the P. gingivalis strain W83 show significant differences from that of DAP. However, their inhibitory mechanisms as for how simple structural change influences the inhibitory potency remain unknown. Therefore, we employed molecular modeling methods to obtain insight into the inhibitory mechanisms of DAP and analogs with m-Ddh. The predicted binding mode of DAP was highly consistent with the experimental structural data and disclosed the important roles played by the binding pocket residues. According to our predictions, the isoxazoline ring of compounds 1 and 2 and the double bonds in compounds 3 and 4 had distinct influences on these compounds' binding to m-Ddh. This enriched understanding of the inhibitory mechanisms of DAP and these four analogs to m-Ddh has provided new and relevant information for future rational development of potent inhibitors targeting m-Ddh. Copyright © 2018. Published by Elsevier Inc.

Towards Monitoring Biodiversity in Amazonian Forests: How Regular Samples Capture Meso-Scale Altitudinal Variation in 25 km2 Plots

PubMed Central

Norris, Darren; Fortin, Marie-Josée; Magnusson, William E.

2014-01-01

Background Ecological monitoring and sampling optima are context and location specific. Novel applications (e.g. biodiversity monitoring for environmental service payments) call for renewed efforts to establish reliable and robust monitoring in biodiversity rich areas. As there is little information on the distribution of biodiversity across the Amazon basin, we used altitude as a proxy for biological variables to test whether meso-scale variation can be adequately represented by different sample sizes in a standardized, regular-coverage sampling arrangement. Methodology/Principal Findings We used Shuttle-Radar-Topography-Mission digital elevation values to evaluate if the regular sampling arrangement in standard RAPELD (rapid assessments (“RAP”) over the long-term (LTER [“PELD” in Portuguese])) grids captured patters in meso-scale spatial variation. The adequacy of different sample sizes (n = 4 to 120) were examined within 32,325 km2/3,232,500 ha (1293×25 km2 sample areas) distributed across the legal Brazilian Amazon. Kolmogorov-Smirnov-tests, correlation and root-mean-square-error were used to measure sample representativeness, similarity and accuracy respectively. Trends and thresholds of these responses in relation to sample size and standard-deviation were modeled using Generalized-Additive-Models and conditional-inference-trees respectively. We found that a regular arrangement of 30 samples captured the distribution of altitude values within these areas. Sample size was more important than sample standard deviation for representativeness and similarity. In contrast, accuracy was more strongly influenced by sample standard deviation. Additionally, analysis of spatially interpolated data showed that spatial patterns in altitude were also recovered within areas using a regular arrangement of 30 samples. Conclusions/Significance Our findings show that the logistically feasible sample used in the RAPELD system successfully recovers meso-scale altitudinal patterns. This suggests that the sample size and regular arrangement may also be generally appropriate for quantifying spatial patterns in biodiversity at similar scales across at least 90% (≈5 million km2) of the Brazilian Amazon. PMID:25170894

Carbon budgets of biological soil crusts at micro-, meso-, and global scales

USGS Publications Warehouse

Sancho, Leopoldo G; Belnap, Jayne; Colesie, Claudia; Raggio, Jose; Weber, Bettina

2016-01-01

The importance of biocrusts in the ecology of arid lands across all continents is widely recognized. In spite of this broad distribution, contributions of biocrusts to the global biogeochemical cycles have only recently been considered. While these studies opened a new view on the global role of biocrusts, they also clearly revealed the lack of data for many habitats and of overall standards for measurements and analysis. In order to understand carbon cycling in biocrusts and the progress which has been made during the last 15 years, we offer a multi-scale approach covering different climatic regions. We also include a discussion on available measurement techniques at each scale: A micro-scale section focuses on the individual organism level, including modeling based on the combination of field and lab data. The meso-scale section addresses the CO2 exchange of a complete ecosystem or at the community level. Finally, we consider the contribution of biocrusts at a global scale, giving a general perspective of the most relevant findings regarding the role of biological soil crusts in the global terrestrial carbon cycle.

The Boundary of Tectonic Units of the South China Continent in the Meso-Neoproterozoic - Early Paleozoic: Insights from Integrated Geophysical Study

NASA Astrophysics Data System (ADS)

Guo, L.; Gao, R.; Meng, X.; Zhang, J.; Wang, H.; Liu, Y.

2013-12-01

The South China continent (SCC), located in the transition zone of the Eurasia, India and Pacific plates, formed in the Meso-Neoproterozoic by collision of the Yangtze block and the Cathaysia block. However, the boundaries of the two blocks before the late Paleozoic (from Meso-Neoproterozoic to early Paleozoic) remain debated in the literature due to strong and complex tectonic and magmatic activities since then. The south of Jiangnan archicontinent is covered mostly by the thick strata since the late Paleozoic, the surface of which is widely covered by the vegetation. And the regional tectonic deformation is extremely complicated with few basal outcrops. For decades, a variety of geophysical detections have been performed in the SCC for understanding the deep structure and tectonic evolution, including deep seismic sounding (DSS) profiles, magnetotelluric sounding (MT) profiles, gravity and magnetic surveys and a small amount of deep seismic reflection profiles. However, due to the limitations of resolution and accuracy of the observed geophysical data in the past, especially short of the deep seismic reflection profiles to reveal fine lithosphere structure, different scientists presented various views on the division of tectonic units in the SCC. In quite recent years, the SinoProbe-02 project launched a long profile of geophysical detections across the two blocks in the SCC, including deep seismic reflection, DSS, MT, and broadband seismic observation, the resolution and accuracy of which had been improved greatly. These newly data will benefit better understanding the deep structure and tectonic evolution of the SCC. Here, we assembled high-resolution Bouguer gravity anomalies and aeromagnetic anomalies data in the SCC. The magnetic data were reduced to the pole by used a varying magnetic inclinations algorithm. We then performed anomaly separation and multi-scales lineation structure analysis on the gravity and RTP magnetic data, and then did 3D fusion analysis on them. Seismic reflection profiles focus on fine lithosphere structure vertically along the profile, while gravity and magnetic methods are beneficial to reveal regional tectonic features laterally. The integrate study of seismic, gravity and magnetic data will play the advantages of various methods and constraint and confirm each other. Hence, we did the interpretation of gravity and magnetic data with constraints of the newly seismic reflection profile. Based on the above studies, we traced the boundaries of tectonic units in the SCC from Meso-Neoproterozoic to early Paleozoic, and formed a certain understanding of the tectonic evolution in the SCC before the late Paleozoic. Acknowledgment: We acknowledge the financial support of the SinoProbe-02-01 and SinoProbe-01-05 projects, and the Fundamental Research Funds for the Central Universities.

Fully Coupled Micro/Macro Deformation, Damage, and Failure Prediction for SiC/Ti-15-3 Laminates

NASA Technical Reports Server (NTRS)

Bednarcyk, Brett A.; Arnold, Steven M.; Lerch, Brad A.

2001-01-01

The deformation, failure, and low cycle fatigue life of SCS-6/Ti-15-3 composites are predicted using a coupled deformation and damage approach in the context of the analytical generalized method of cells (GMC) micromechanics model. The local effects of inelastic deformation, fiber breakage, fiber-matrix interfacial debonding, and fatigue damage are included as sub-models that operate on the micro scale for the individual composite phases. For the laminate analysis, lamination theory is employed as the global or structural scale model, while GMC is embedded to operate on the meso scale to simulate the behavior of the composite material within each laminate layer. While the analysis approach is quite complex and multifaceted, it is shown, through comparison with experimental data, to be quite accurate and realistic while remaining extremely efficient.

Molecular Origins of Mesoscale Ordering in a Metalloamphiphile Phase

PubMed Central

2015-01-01

Controlling the assembly of soft and deformable molecular aggregates into mesoscale structures is essential for understanding and developing a broad range of processes including rare earth extraction and cleaning of water, as well as for developing materials with unique properties. By combined synchrotron small- and wide-angle X-ray scattering with large-scale atomistic molecular dynamics simulations we analyze here a metalloamphiphile–oil solution that organizes on multiple length scales. The molecules associate into aggregates, and aggregates flocculate into meso-ordered phases. Our study demonstrates that dipolar interactions, centered on the amphiphile headgroup, bridge ionic aggregate cores and drive aggregate flocculation. By identifying specific intermolecular interactions that drive mesoscale ordering in solution, we bridge two different length scales that are classically addressed separately. Our results highlight the importance of individual intermolecular interactions in driving mesoscale ordering. PMID:27163014

Shear behavior of thermoformed woven-textile thermoplastic prepregs: An analysis combining bias-extension test and X-ray microtomography

NASA Astrophysics Data System (ADS)

Gassoumi, M.; Rolland du Roscoat, S.; Casari, P.; Dumont, P. J. J.; Orgéas, L.; Jacquemin, F.

2017-10-01

Thermoforming allows the manufacture of structural parts for the automotive and aeronautical domains using long fiber thermoplastic prepregs with short cycle times. During this operation, several sheets of molten prepregs are stacked and subjected to large macroscale strains, mainly via in-plane shear, out-of-plane consolidation or dilatation, and bending of the fibrous reinforcement. These deformation modes and the related meso and microstructure evolutions are still poorly understood. However, they can drastically alter the end-use macroscale properties of fabricated parts. To better understand these phenomena, bias extension tests were performed using specimens made of several stacked layers of glass woven fabrics and polyamide matrix. The macroscale shear behavior of these prepregs was investigated at various temperatures. A multiscale analysis of deformed samples was performed using X-ray microtomography images of the deformed specimens acquired at two different spatial resolutions. The low-resolution images were used to analyze the deformation mechanisms and the structural characteristics of prepregs at the macroscale and bundle scales. It was possible to analyze the 3D shapes of deformed samples and, in particular, the spatial variations of their thickness so as to quantify the out-of-plane dilatancy or consolidation phenomena induced by the in-plane shear of prepregs. At a lower scale, the analysis of the high-resolution images showed that these mechanisms were accompanied by the growth of pores and the deformation of fiber bundles. The orientation of the fiber bundles and its through-thickness evolution were measured along the weft and warp directions in the deformed samples, allowing the relevance of geometrical models currently used to analyze bias extension tests to be discussed. Results can be used to enhance the current rheological models for the prediction of thermoforming of thermoplastic prepregs.

Micro- and meso-scale simulations of magnetospheric processes related to the aurora and substorm morphology

NASA Technical Reports Server (NTRS)

Swift, Daniel W.

1991-01-01

The primary methodology during the grant period has been the use of micro or meso-scale simulations to address specific questions concerning magnetospheric processes related to the aurora and substorm morphology. This approach, while useful in providing some answers, has its limitations. Many of the problems relating to the magnetosphere are inherently global and kinetic. Effort during the last year of the grant period has increasingly focused on development of a global-scale hybrid code to model the entire, coupled magnetosheath - magnetosphere - ionosphere system. In particular, numerical procedures for curvilinear coordinate generation and exactly conservative differencing schemes for hybrid codes in curvilinear coordinates have been developed. The new computer algorithms and the massively parallel computer architectures now make this global code a feasible proposition. Support provided by this project has played an important role in laying the groundwork for the eventual development or a global-scale code to model and forecast magnetospheric weather.

Development of a parallel FE simulator for modeling the whole trans-scale failure process of rock from meso- to engineering-scale

NASA Astrophysics Data System (ADS)

Li, Gen; Tang, Chun-An; Liang, Zheng-Zhao

2017-01-01

Multi-scale high-resolution modeling of rock failure process is a powerful means in modern rock mechanics studies to reveal the complex failure mechanism and to evaluate engineering risks. However, multi-scale continuous modeling of rock, from deformation, damage to failure, has raised high requirements on the design, implementation scheme and computation capacity of the numerical software system. This study is aimed at developing the parallel finite element procedure, a parallel rock failure process analysis (RFPA) simulator that is capable of modeling the whole trans-scale failure process of rock. Based on the statistical meso-damage mechanical method, the RFPA simulator is able to construct heterogeneous rock models with multiple mechanical properties, deal with and represent the trans-scale propagation of cracks, in which the stress and strain fields are solved for the damage evolution analysis of representative volume element by the parallel finite element method (FEM) solver. This paper describes the theoretical basis of the approach and provides the details of the parallel implementation on a Windows - Linux interactive platform. A numerical model is built to test the parallel performance of FEM solver. Numerical simulations are then carried out on a laboratory-scale uniaxial compression test, and field-scale net fracture spacing and engineering-scale rock slope examples, respectively. The simulation results indicate that relatively high speedup and computation efficiency can be achieved by the parallel FEM solver with a reasonable boot process. In laboratory-scale simulation, the well-known physical phenomena, such as the macroscopic fracture pattern and stress-strain responses, can be reproduced. In field-scale simulation, the formation process of net fracture spacing from initiation, propagation to saturation can be revealed completely. In engineering-scale simulation, the whole progressive failure process of the rock slope can be well modeled. It is shown that the parallel FE simulator developed in this study is an efficient tool for modeling the whole trans-scale failure process of rock from meso- to engineering-scale.

A new concept of the anatomy of the thoracic oesophagus: the meso-oesophagus. Observational study during thoracoscopic esophagectomy.

PubMed

Cuesta, Miguel A; Weijs, Teus J; Bleys, Ronald L A W; van Hillegersberg, Richard; van Berge Henegouwen, Mark I; Gisbertz, Suzanne S; Ruurda, Jelle P; Straatman, Jennifer; Osugi, Harushi; van der Peet, Donald L

2015-09-01

During thoracoscopic oesophageal surgery, we observed not previously described fascia-like structures. Description of similar structures in rectal cancer surgery was of paramount importance in improving the quality of resection. Therefore, we aimed to describe a new comprehensive concept of the surgical anatomy of the thoracic oesophagus with definition of the meso-oesophagus. We retrospectively evaluated 35 consecutive unedited videos of thoracoscopic oesophageal resections for cancer, to determine the surgical anatomy of the oesophageal fascia's vessels and lymphatic drainage. The resulting concept was validated in a prospective study, including 20 patients at three different centres. Additional confirmation was sought by a histologic study of a cadaver's thorax. A thin layer of connective tissue around the infracarinal oesophagus, involving the lymph nodes at the level of the carina, was observed during thoracoscopic esophagectomy in 32 of the 35 patients included in the retrospective study and in 19 of the 20 patients included in the prospective study. A thick fascia-like structure from the upper thoracic aperture to the lower thoracic aperture was visualized in all patients. This fascia is encountered between the descending aorta and left aspect of the infracarinal oesophagus. Above the carina it expands on both sides of the oesophagus to lateral mediastinal structures. This fascia contains oesophageal vessels, lymph vessels and nodes and nerves. The histologic study confirmed these findings. Here we described the concept of the "meso-oesophagus". Applying the description of the meso-oesophagus will create a better understanding of the oesophageal anatomy, leading to more adequate and reproducible surgery.

LHCbDIRAC as Apache Mesos microservices

NASA Astrophysics Data System (ADS)

Haen, Christophe; Couturier, Benjamin

2017-10-01

The LHCb experiment relies on LHCbDIRAC, an extension of DIRAC, to drive its offline computing. This middleware provides a development framework and a complete set of components for building distributed computing systems. These components are currently installed and run on virtual machines (VM) or bare metal hardware. Due to the increased workload, high availability is becoming more and more important for the LHCbDIRAC services, and the current installation model is showing its limitations. Apache Mesos is a cluster manager which aims at abstracting heterogeneous physical resources on which various tasks can be distributed thanks to so called “frameworks” The Marathon framework is suitable for long running tasks such as the DIRAC services, while the Chronos framework meets the needs of cron-like tasks like the DIRAC agents. A combination of the service discovery tool Consul together with HAProxy allows to expose the running containers to the outside world while hiding their dynamic placements. Such an architecture brings a greater flexibility in the deployment of LHCbDirac services, allowing for easier deployment maintenance and scaling of services on demand (e..g LHCbDirac relies on 138 services and 116 agents). Higher reliability is also easier, as clustering is part of the toolset, which allows constraints on the location of the services. This paper describes the investigations carried out to package the LHCbDIRAC and DIRAC components into Docker containers and orchestrate them using the previously described set of tools.

Electrical conductivity of nanocomposites based on carbon nanotubes: a 3D multiscale modeling approach

NASA Astrophysics Data System (ADS)

Grabowski, Krzysztof; Zbyrad, Paulina; Staszewski, Wieslaw J.; Uhl, Tadeusz; Wiatr, Kazimierz; Packo, Pawel

2016-04-01

Remarkable electrical properties of carbon nanotubes (CNT) have lead to increased interest in studying CNT- based devices. Many of current researches are devoted to using all kinds of carbon nanomaterials in the con- struction of sensory elements. One of the most common applications is the development of high performance, large scale sensors. Due to the remarkable conductivity of CNT's such devices represent very high sensitivity. However, there are no sufficient tools for studying and designing such sensors. The main objective of this paper is to develop and validate a multiscale numerical model for a carbon nanotubes based sensor. The device utilises the change of electrical conductivity of a nanocomposite material under applied deformation. The nanocomposite consists of a number of CNTs dispersed in polymer matrix. The paper is devoted to the analysis of the impact of spatial distribution of carbon nanotubes in polymer matrix on electrical conductivity of the sensor. One of key elements is also to examine the impact of strain on electric charge ow in such anisotropic composite structures. In the following work a multiscale electro-mechanical model for CNT - based nanocomposites is proposed. The model comprises of two length scales, namely the meso- and the macro-scale for mechanical and electrical domains. The approach allows for evaluation of macro-scale mechanical response of a strain sensor. Electrical properties of polymeric material with certain CNT fractions were derived considering electrical properties of CNTs, their contact and the tunnelling effect.

Ecological Realism of US EPA Experimental Stream Facility ...

EPA Pesticide Factsheets

The USEPA’s Experimental Stream Facility (ESF) conducts meso-scale ecotoxicology studies that account for both structural and functional responses of whole stream communities to contaminants or other stressors. The 16 mesocosms of ESF are indoors and consist of a tiled run section (0.152 m W x 4.268 m L x 0.105 m D) that widens to a gravel riffle section (0.305 m W x 4.268 m L x 0.19 m D). They are intermediate size among studies reporting stream mesocosm results. Their set-up is unique for their size, with a high degree of engineering controls for continuous flow-through dose-response designs, yet fixed, chronic exposures to contaminants under conditions that quantifiably mimic real stream riffle/run habitat with consistent upstream renewal. With fifty standard operating procedures serving ESF studies, the background and boundary condition information is collected to determine the realism critical to the field relevance of the results. Parallel ex situ and in situ single species exposure formats including fish survival and fecundity metrics are also included. With this framework studies at ESF provide scientifically defensible evaluation of proposed aquatic life criteria. This presentation discusses the relevance and realism of USEPA's mesocosms studies conducted using the Experimental Stream Facility in Milford, OH within the context of understanding the role meso-scale results can play in validating aquatic life criteria for streams and, more generally, man

Irradiation Induced Fluorescence Enhancement in PEGylated Cyanine-based NIR Nano- and Meso-scale GUMBOS

PubMed Central

Lu, Chengfei; Das, Susmita; Magut, Paul K. S.; Li, Min; El Zahab, Bilal; Warner, Isiah M.

2014-01-01

We report on the synthesis and characterization of a PEGylated IR786 GUMBOS (Group of Uniform Materials Based on Organic Salts). The synthesis of this material was accomplished using a three step protocol: (1) substitution of chloride on the cyclohexenyl ring in the heptamethine chain of IR786 by 6-aminohexanoic acid, (2) grafting of methoxy poly ethyleneglycol (MeOPEG) onto the 6-aminohexanoic acid via an esterification reaction, and (3) anion exchange between [PEG786][I] and lithium bis(trifluoromethylsulfonyl)imide (LiNTf2) or sodium bis(2-ethylhexyl)sulfosuccinate (AOT) in order to obtain PEG786 GUMBOS. Examination of spectroscopic data for this PEG786 GUMBOS indicates a large stokes shift (122 nm). It was observed that this PEG786 GUMBOS associates in aqueous solution to form nano-and meso-scale self-assemblies with sizes ranging from 100 to 220 nm. These nano- and meso-scale GUMBOS are also able to resist nonspecific binding to proteins. PEGylation of the original IR786 leads to reduced cytotoxicity. In addition, it was noted that anions, such as NTf2 and AOT, play a significant role in improving the photostability of PEG786 GUMBOS. Irradiation-induced J aggregation in [PEG786][NTf2] and to some extent in [PEG786][AOT] produced enhanced photostability. This observation was supported by use of both steady state and time-resolved fluorescence measurements. PMID:22957476

Control of Partial Coalescence of Self-Assembled Metal Nano-Particles across Lyotropic Liquid Crystals Templates towards Long Range Meso-Porous Metal Frameworks Design

PubMed Central

Dumée, Ludovic F.; Lemoine, Jean-Baptiste; Ancel, Alice; Hameed, Nishar; He, Li; Kong, Lingxue

2015-01-01

The formation of purely metallic meso-porous metal thin films by partial interface coalescence of self-assembled metal nano-particles across aqueous solutions of Pluronics triblock lyotropic liquid crystals is demonstrated for the first time. Small angle X-ray scattering was used to study the influence of the thin film composition and processing conditions on the ordered structures. The structural characteristics of the meso-structures formed demonstrated to primarily rely on the lyotropic liquid crystal properties while the nature of the metal nano-particles used as well as the their diameters were found to affect the ordered structure formation. The impact of the annealing temperature on the nano-particle coalescence and efficiency at removing the templating lyotropic liquid crystals was also analysed. It is demonstrated that the lyotropic liquid crystal is rendered slightly less thermally stable, upon mixing with metal nano-particles and that low annealing temperatures are sufficient to form purely metallic frameworks with average pore size distributions smaller than 500 nm and porosity around 45% with potential application in sensing, catalysis, nanoscale heat exchange, and molecular separation. PMID:28347094

Stiffness and Poisson ratio in longitudinal compression of fiber yarns in meso-FE modelling of composite reinforcement forming

NASA Astrophysics Data System (ADS)

Wang, D.; Naouar, N.; Vidal-Salle, E.; Boisse, P.

2018-05-01

In meso-scale finite element modeling, the yarns of the reinforcement are considered to be solids made of a continuous material in contact with their neighbors. The present paper consider the mechanical behavior of these yarns that can happen for some loadings of the reinforcement. The yarns present a specific mechanical behavior when under longitudinal compression because they are made up of a large number of fibers, Local buckling of the fibers causes the compressive stiffness of the continuous material representing the yarn to be much weaker than when under tension. In addition, longitudinal compression causes an important transverse expansion. It is shown that the transverse expansion can be depicted by a Poisson ratio that remained roughly constant when the yarn length and the compression strain varied. Buckling of the fibers significantly increases the transverse dimensions of the yarn which leads to a large Poisson ratio (up to 12 for a yarn analyzed in the present study). Meso-scale finite element simulations of reinforcements with binder yarns submitted to longitudinal compression showed that these improvements led to results in good agreement with micro-CT analyses.

Economic evaluations of health technologies in Dutch healthcare decision-making: a qualitative study of the current and potential use, barriers, and facilitators.

PubMed

Roseboom, Kitty J; van Dongen, Johanna M; Tompa, Emile; van Tulder, Maurits W; Bosmans, Judith E

2017-01-26

The use of economic evaluations in healthcare decision-making can potentially help decision-makers in allocating scarce resources as efficiently as possible. Over a decade ago, the use of such studies was found to be limited in Dutch healthcare decision-making, but their current use is unknown. Therefore, this study aimed to provide insight into the current and potential use of economic evaluations in Dutch healthcare decision-making and to identify barriers and facilitators to the use of such studies. Interviews containing semi-structured and structured questions were conducted among Dutch healthcare decision-makers. Participants were purposefully selected and special efforts were made to include decision-makers working at the macro- (national), meso- (local/regional), and micro-level (patient setting). During the interviews, a topic list was used that was based on the research questions and a literature search, and was developed in consultation with the Dutch National Healthcare Institute. Responses to the semi-structured questions were analyzed using a constant comparative approach. As for the structured questions, participants' definitions of various economic evaluation concepts were scored as either being "correct" or "incorrect" by two researchers, and summary statistics were prepared. Sixteen healthcare decision-makers were interviewed and two health economists. Decision-makers' knowledge of economic evaluations was only modest, and their current use appeared to be limited. Nonetheless, decision-makers recognized the importance of economic evaluations and saw several opportunities for extending their use at the macro- and meso-level, but not at the micro-level. The disparity between the limited use and recognition of the importance of economic evaluations is likely due to the many barriers decision-makers experience preventing their use (e.g. lack of resources, lack of formal willingness-to-pay threshold). Possible facilitators for extending the use of economic evaluations include, amongst others, educating decision-makers and the general population about economic evaluations and presenting economic evaluation results in a clearer and more understandable way. This study demonstrated that the current use and impact of economic evaluations in Dutch healthcare decision-making is limited at best. Therefore, strategies are needed to overcome the barriers that currently prevent economic evaluations from being used extensively.

A Normal-faulting Paleostress in the Vicinity of Up-dip Limit of Seismogenic Zone Detected by Meso-scale Fault Analysis in a Tectonic Mélange

NASA Astrophysics Data System (ADS)

Sato, K.; Ikesawa, E.; Kimura, G.

2003-12-01

The Mugi mélange in the Shimanto Belt, SW Japan, is a mixture of terrigenous and oceanic materials of late Cretaceous to Paleocene. Intermittent bedding planes trend ENE-WSW to E-W (subparallel to the Nankai trough axis) and dip steeply northward. The Mugi mélange consists of several duplex units accompanied by shear zones of basalt layers at their boundaries. Systematic shear fabrics and P-T conditions estimated from analyses of vitrinite reflectance and fluid inclusions indicate that the Mugi mélange had once been subducted to a significant depth (6-7 km below sea floor, which appears to coincide with the up-dip limit of the seismogenic zone), then underplated to the Shimanto accretionary prism, and is now exhumed on ground surface. In this study, for the purpose of determining paleostress fields related to the processes in which subducted materials were deformed, underplated and uplifted to surface, orientations of meso-scale faults and striations were analyzed. Stress inversion techniques including Angelier's Inversion, Multiple Inversion and Ginkgo Method were applied to fault-slip data obtained in each duplex unit of the Mugi mélange, and the results were almost consistent with each other. Most of the resultant σ 1 axes trend N-S horizontally, and are parallel to poles of shale cleavages, which are roughly parallel to bedding planes. Although the cleavages slightly vary their orientations according to later rotation, σ 1 axis changes together with them. This cleavage-controlled paleostress has a low Bishop's stress ratio (i.e. low magnitude of σ 2), therefore is an axial compressional stress normal to cleavages. The restored paleostress was probably exerted just before or at the same time of the formation of duplex structure and the rotation of bedding planes. The meso-scale faults appear to have been formed as normal ones due to overburden. P-T conditions estimated by analysis of fluid inclusions, which occur in the mineral veins sealing measured faults, and cross-cutting relationships between the faults and unit boundary shear zones indicate the simultaneity of these faulting and duplexing. The duplex structure is thought to be formed at the moment of underplating and be caused by stepdown of the décollement. A great variety of drastic changes in properties of material and circumstance such as stress field may occur at the very point of the stepdown, underplating of subducted material, and the up-dip limit of the seismogenic zone.

Complex fragmentation and silicification structures in fault zones: quartz crystallization and repeated fragmentation in the Rusey fault zone (Cornwall/UK)

NASA Astrophysics Data System (ADS)

Yilmaz, Tim I.; Blenkinsop, Tom; Duschl, Florian; Kruhl, Jörn H.

2015-04-01

Silicified fault rocks typically show structures resulting from various stages of fragmentation and quartz crystallization. Both processes interact episodically and result in complex structures on various scales, which require a wide spectrum of analysis tools. Based on field and microstructural data, the spatial-temporal connection between deformation, quartz crystallization and fluid and material flow along the Rusey fault zone was investigated. The fault can be examined in detail in three dimensions on the north Cornwall coast, UK. It occurs within Carboniferous sandstones, siltstones, mudstones and slates of the Culm basin, and is likely to have had a long history. The fault rocks described here formed during the younger events, possibly due to Tertiary strike-slip reactivation. Frequent fragmentation, flow and crystallization events and their interaction led to various generations of complex-structured quartz units, among them quartz-mantled and partly silicified wall-rock fragments, microcrystalline quartz masses of different compositions and structures, and quartz vein patterns of various ages. Lobate boundaries of quartz masses indicate viscous flow. Fragments are separated by quartz infill, which contains cm-sized open pores, in which quartz crystals have pyramidal terminations. Based on frequent occurrence of feathery textures and the infill geometry, quartz crystallization from chalcedony appears likely, and an origin from silica gel is discussed. Fragmentation structures are generally fractal. This allows differentiation between various processes, such as corrosive wear, wear abrasion and hydraulic brecciation. Material transport along the brittle shear zone, and displacement of the wall-rocks, were at least partly governed by flow of mobile fluid-quartz-particle suspensions. The complex meso- to microstructures were generated by repeated processes of fragmentation, quartz precipitation and grain growth. In general, the brittle Rusey fault zone represents a zone of multiple fragmentation, fluid flow, crystallization and quartz dissolution and precipitation, and is regarded as key example of large-scale cyclic interaction of these processes. The geological evidence of interactions between processes implies that feedbacks and highly non-linear mechanical behaviour generated the complex meso- and microstructures. The fault zone rheology may also therefore have been complex.

Stabilizing g-States in Centrosymmetric Tetrapyrroles: Two-Photon-Absorbing Porphyrins with Bright Phosphorescence.

PubMed

Esipova, Tatiana V; Rivera-Jacquez, Héctor J; Weber, Bruno; Masunov, Artëm E; Vinogradov, Sergei A

2017-08-24

Using time-dependent density functional theory (TDDFT) and sum-overstates (SOS) formalism, we predicted significant stabilization of 2P-active g-states in a compact fully symmetric porphyrin, in which all four pyrrolic fragments are fused with phathalimide residues via the β-carbon positions. The synthesis of a soluble, nonaggregating meso-unsubstituted tetraarylphthalimidoporphyrin (TAPIP) was then developed, and the spectroscopic measurements confirmed that a strongly 2P-active state in this porphyrin is stabilized below the B (Soret) state level. Single-crystal X-ray analysis revealed near-ideally planar geometry of the TAPIP macrocycle, while its tetra-meso-arylated analogue (meso-Ar 4 TAPIP) was found to be highly saddled. Consistent with these structural features, Pt meso-Ar 4 TAPIP phosphoresces rather weakly (ϕ phos = 0.05 in DMF at 22 °C), while both Pt and Pd complexes of TAPIP are highly phosphorescent (ϕ phos = 0.45 and 0.23, respectively). In addition PdTAPIP exhibits non-negligible thermally activated (E-type) delayed fluorescence (ϕ fl (d) ∼ 0.012). Taken together, these photophysical properties make metal complexes of meso-unsubstituted tetaarylphthalimidoporphyrins the brightest 2P-absorbing phosphorescent chromophores known to date.

Meso-America and the Andes. Grade 7 Model Lesson for Standard 7.7. World History and Geography: Medieval and Early Modern Times. California History-Social Science Course Models.

ERIC Educational Resources Information Center

Zachlod, Michelle, Ed.

California State Standard 7.7 is delineated in the following manner: "Students compare and contrast the geographic, political, economic, religious, and social structures of the Meso-American and Andean civilizations." Seventh-grade students study the locations, landforms, and climates of Mexico and Central and South America and their…

Photophysical study of meso-phenothiazinyl-porphyrins metallocomplexes

NASA Astrophysics Data System (ADS)

Starukhin, Aleksander; Gorski, Aleksander; Knyukshto, Valery; Panarin, Andrei; Pavich, Tatiana; Gaina, Luiza; Gal, Emese

2017-10-01

Photophysical parameters of a set of metallocomplexes of meso-phenylthiazinylporphyrins with Zn (II), Pd (II) and Cu (II) ions were studied in different organic solvents, solid solutions and polymeric matrices at room and liquid nitrogen temperatures. The dependence of the spectral and photophysical parameters on changing the molecular structure with increasing number of branched substituents attached to aryl groups in different positions of the porphyrin macrocycle has been established.

Augmenting comprehension of geological relationships by integrating 3D laser scanned hand samples within a GIS environment

NASA Astrophysics Data System (ADS)

Harvey, A. S.; Fotopoulos, G.; Hall, B.; Amolins, K.

2017-06-01

Geological observations can be made on multiple scales, including micro- (e.g. thin section), meso- (e.g. hand-sized to outcrop) and macro- (e.g. outcrop and larger) scales. Types of meso-scale samples include, but are not limited to, rocks (including drill cores), minerals, and fossils. The spatial relationship among samples paired with physical (e.g. granulometric composition, density, roughness) and chemical (e.g. mineralogical and isotopic composition) properties can aid in interpreting geological settings, such as paleo-environmental and formational conditions as well as geomorphological history. Field samples are collected along traverses in the area of interest based on characteristic representativeness of a region, predetermined rate of sampling, and/or uniqueness. The location of a sample can provide relative context in seeking out additional key samples. Beyond labelling and recording of geospatial coordinates for samples, further analysis of physical and chemical properties may be conducted in the field and laboratory. The main motivation for this paper is to present a workflow for the digital preservation of samples (via 3D laser scanning) paired with the development of cyber infrastructure, which offers geoscientists and engineers the opportunity to access an increasingly diverse worldwide collection of digital Earth materials. This paper describes a Web-based graphical user interface developed using Web AppBuilder for ArcGIS for digitized meso-scale 3D scans of geological samples to be viewed alongside the macro-scale environment. Over 100 samples of virtual rocks, minerals and fossils populate the developed geological database and are linked explicitly with their associated attributes, characteristic properties, and location. Applications of this new Web-based geological visualization paradigm in the geosciences demonstrate the utility of such a tool in an age of increasing global data sharing.

A summary of research on mesoscale energetics of severe storm environments

NASA Technical Reports Server (NTRS)

Fuelberg, H. E.

1985-01-01

The goals of this research were to better understand interactions between areas of intense convection and their surrounding mesoscale environments by using diagnostic budgets of kinetic (KE) and available potential energy (APE). Three cases of intense convection were examined in detail. 1) Atmospheric Variability Experiments (AVE) carried out on 24 to 25 April 1975 were studied. Synoptic scale data at 3 to 6 hour intervals, contained two mesoscale convective complexes (MCCs). Analyses included total KE budgets and budgets of divergent and rotational components of KE. 2) AVE-Severe Environmental Storms and Mesoscale Experiments (SESAME)-4 carried out on 10 to 11 April 1979 were studied. Synotpic and meso alpha-scale data (250 km spacing, 3 hour intervals), contained the Red River Valley tornado outbreak. Analyses included total KE budgets (separate synoptic and mesoscale version), budgets for the divergent and rotational components, and the generation of APE by diabatic processes. 3) AVE-SESAME 5 studies were carried out on 20 to 31 May 1979. Synoptic and meso beta-scale data (75 km spacing, 1 1/2 to 3 hour intervals), contained a small MCC. Analyses include separate KE budgets for the synotic and meso beta-scales and a water vapor budget. Major findings of these investigations are: (1) The synoptic scale storm environment contains energy conversions and transports that are comparable to those of mature midlatitude cyclones. (2) Energetic in the mesoscale storm environment are often an order of magnitude larger than those in an undisturbed region. (3) Mesoscale wind maxima form in the upper troposphere on the poleward sides of convective areas, whereas speeds decrease south of storm regions.

a Cumulus Parameterization Study with Special Attention to the Arakawa-Schubert Scheme

NASA Astrophysics Data System (ADS)

Kao, Chih-Yue Jim

Arakawa and Schubert (1974) developed a cumulus parameterization scheme in a framework that conceptually divides the mutual interaction of the cumulus convection and large-scale disturbance into the categories of large -scale budget requirements and the quasi-equilibrium assumption of cloud work function. We have applied the A-S scheme through a semi-prognostic approach to two different data sets: one is for an intense tropical cloud band event; the other is for tropical composite easterly wave disturbances. Both were observed in GATE. The cloud heating and drying effects predicted by the Arakawa-Schubert scheme are found to agree rather well with the observations. However, it is also found that the Arakawa-Schubert scheme underestimates both condensation and evaporation rates substantially when compared with the cumulus ensemble model results (Soong and Tao, 1980; Tao, 1983). An inclusion of the downdraft effects, as formulated by Johnson (1976), appears to alleviate this deficiency. In order to examine how the Arakawa-Schubert scheme works in a fully prognostic problem, a simulation of the evolution and structure of the tropical cloud band, mentioned above, under the influence of an imposed large-scale low -level forcing has been made, using a two-dimensional hydrostatic model with the inclusion of the Arakawa-Schubert scheme. Basically, the model result indicates that the meso-scale convective system is driven by the excess of the convective heating derived from the Arakawa-Schubert scheme over the adiabatic cooling due to the imposed large-scale lifting and induced meso-scale upward motion. However, as the convective system develops, the adiabatic warming due to the subsidence outside the cloud cluster gradually accumulates into a secondary temperature anomaly which subsequently reduces the original temperature contrast and inhibits the further development of the convective system. A 24 hour integration shows that the model is capable of simulating many important features such as the life cycle, intensity of circulation, and rainfall rates.

A process proof test for model concepts: Modelling the meso-scale

NASA Astrophysics Data System (ADS)

Hellebrand, Hugo; Müller, Christoph; Matgen, Patrick; Fenicia, Fabrizio; Savenije, Huub

In hydrological modelling the use of detailed soil data is sometimes troublesome, since often these data are hard to obtain and, if available at all, difficult to interpret and process in a way that makes them meaningful for the model at hand. Intuitively the understanding and mapping of dominant runoff processes in the soil show high potential for improving hydrological models. In this study a labour-intensive methodology to assess dominant runoff processes is simplified in such a way that detailed soil maps are no longer needed. Nonetheless, there is an ongoing debate on how to integrate this type of information in hydrological models. In this study, dominant runoff processes (DRP) are mapped for meso-scale basins using the permeability of the substratum, land use information and the slope in a GIS. During a field campaign the processes are validated and for each DRP assumptions are made concerning their water storage capacity. The latter is done by means of combining soil data obtained during the field campaign with soil data obtained from the literature. Second, several parsimoniously parameterized conceptual hydrological models are used that incorporate certain aspects of the DRP. The result of these models are compared with a benchmark model in which the soil is represented as only one lumped parameter to test the contribution of the DRP in hydrological models. The proposed methodology is tested for 15 meso-scale river basins located in Luxembourg. The main goal of this study is to investigate if integrating dominant runoff processes, which have high information content concerning soil characteristics, with hydrological models allows the improvement of simulation results models with a view to regionalization and predictions in ungauged basins. The regionalization procedure gave no clear results. The calibration procedure and the well-mixed discharge signal of the calibration basins are considered major causes for this and it made the deconvolution of discharge signals of meso-scale basins problematic. From the results it is also suggested that DRP could very well display some sort of uniqueness of place, which was not foreseen in the methods from which they were derived. Furthermore, a strong seasonal influence on model performance was observed, implying a seasonal dependence of the DRP. When comparing the performance between the DRP models and the benchmark model no real distinction was found. To improve the performance of the DRP models, which are used in this study and also for then use of conceptual models in general, there is a need for an improved identification of the mechanisms that cause the different dominant runoff processes at the meso-scale. To achieve this, more orthogonal data could be of use for a better conceptualization of the DRPs. Then, models concepts should be adapted accordingly.

IMPLEMENTATION OF AN URBAN CANOPY PARAMETERIZATION IN MM5 FOR MESO-GAMMA-SCALE AIR QUALITY MODELING APPLICATIONS

EPA Science Inventory

The U.S. Environmental Protection Agency (U.S. EPA) is extending its Models-3/Community Multiscale Air Quality (CMAQ) Modeling System to provide detailed gridded air quality concentration fields and sub-grid variability characterization at neighborhood scales and in urban areas...

Implicit SPH v. 1.0

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Kyungjoo; Parks, Michael L.; Perego, Mauro

2016-11-09

ISPH code is developed to solve multi-physics meso-scale flow problems using implicit SPH method. In particular, the code can provides solutions for incompressible, multi phase flow and electro-kinetic flows.

Single room occupancy (SRO) hotels as mental health risk environments among impoverished women: the intersection of policy, drug use, trauma, and urban space.

PubMed

Knight, Kelly R; Lopez, Andrea M; Comfort, Megan; Shumway, Martha; Cohen, Jennifer; Riley, Elise D

2014-05-01

Due to the significantly high levels of comorbid substance use and mental health diagnosis among urban poor populations, examining the intersection of drug policy and place requires a consideration of the role of housing in drug user mental health. In San Francisco, geographic boundedness and progressive health and housing polices have coalesced to make single room occupancy hotels (SROs) a key urban built environment used to house poor populations with co-occurring drug use and mental health issues. Unstably housed women who use illicit drugs have high rates of lifetime and current trauma, which manifests in disproportionately high rates of post-traumatic stress disorder (PTSD), anxiety, and depression when compared to stably housed women. We report data from a qualitative interview study (n=30) and four years of ethnography conducted with housing policy makers and unstably housed women who use drugs and live in SROs. Women in the study lived in a range of SRO built environments, from publicly funded, newly built SROs to privately owned, dilapidated buildings, which presented a rich opportunity for ethnographic comparison. Applying Rhodes et al.'s framework of socio-structural vulnerability, we explore how SROs can operate as "mental health risk environments" in which macro-structural factors (housing policies shaping the built environment) interact with meso-level factors (social relations within SROs) and micro-level, behavioral coping strategies to impact women's mental health. The degree to which SRO built environments were "trauma-sensitive" at the macro level significantly influenced women's mental health at meso- and micro-levels. Women who were living in SROs which exacerbated fear and anxiety attempted, with limited success, to deploy strategies on the meso- and micro-level to manage their mental health symptoms. Study findings underscore the importance of housing polices which consider substance use in the context of current and cumulative trauma experiences in order to improve quality of life and mental health for unstably housed women. Copyright © 2013 Elsevier B.V. All rights reserved.

Single Room Occupancy (SRO) hotels as mental health risk environments among impoverished women: the intersection of policy, drug use, trauma, and urban space

PubMed Central

Knight, Knight R.; Lopez, Andrea M.; Comfort, Megan; Shumway, Martha; Cohen, Jennifer; Riley, Elise

2014-01-01

Due to the significantly high levels of comorbid substance use and mental health diagnosis among urban poor populations, examining the intersection of drug policy and place requires a consideration of the role of housing in drug user mental health. In San Francisco, geographic boundedness and progressive health and housing polices have coalesced to make single room occupancy hotels (SROs) a key urban built environment used to house poor populations with co-occurring drug use and mental health issues. Unstably housed women who use illicit drugs have high rates of lifetime and current trauma, which manifests in disproportionately high rates of post-traumatic stress disorder (PTSD), anxiety, and depression when compared to stably housed women. We report data from a qualitative interview study (n=30) and four years of ethnography conducted with housing policy makers and unstably housed women who use drugs and live in SROs. Women in the study lived in a range of SRO built environments, from publicly-funded, newly built SROs to privately-owned, dilapidated buildings, which presented a rich opportunity for ethnographic comparison. Applying Rhodes et al.’s framework of socio-structural vulnerability, we explore how SROs can operate as “mental health risk environments” in which macro-structural factors (housing policies shaping the built environment) interact with meso-level factors (social relations within SROs) and micro-level, behavioral coping strategies to impact women’s mental health. The degree to which SRO built environments were “trauma-sensitive” at the macro level significantly influenced women’s mental health at meso- and micro- levels. Women who were living in SROs which exacerbated fear and anxiety attempted, with limited success, to deploy strategies on the meso- and micro- level to manage their mental health symptoms. Study findings underscore the importance of housing polices which consider substance use in the context of current and cumulative trauma experiences in order to improve quality of life and mental health for unstably housed women. PMID:24411945

[Soil meso- and micro-fauna community structures in different urban forest types in Shanghai, China.

PubMed

Jin, Shi Ke; Wang, Juan Juan; Zhu, Sha; Zhang, Qi; Li, Xiang; Zheng, Wen Jing; You, Wen Hui

2016-07-01

Soil meso- and micro-fauna of four urban forest types in Shanghai were investigated in four months which include April 2014, July 2014, October 2014 and January 2015. A total of 2190 soil fauna individuals which belong to 6 phyla, 15 classes and 22 groups were collected. The dominant groups were Nematoda and Arcari, accounting for 56.0% and 21.8% of the total in terms of individual numbers respectively. The common groups were Enchytraeidae, Rotatoria, Collembola and Hymenoptera and they accounted for 18.7% of the total in terms of individual numbers. There was a significant difference (P<0.05) among soil meso- and micro-fauna density in the four urban forest types and the largest density was found in Metasequoia glyptostroboides forest, the smallest in Cinnamomum camphora forest. The largest groupe number was found in near-nature forest, the smallest was found in M. glyptostroboides forest. There was obvious seasonal dynamics in each urban forest type and green space which had larger density in autumn and larger groupe number in summer and autumn. In soil profiles, the degree of surface accumulation of soil meso- and micro-fauna in C. camphora forest was higher than in other forests and the vertical distribution of soil meso- and micro-fauna in near-nature forest was relatively homogeneous in four layers. Density-group index was ranked as: near-nature forest (6.953)> C. camphora forest (6.351)> Platanus forest (6.313)>M. glyptostroboides forest (5.910). The community diversity of soil fauna in each vegetation type could be displayed preferably by this index. It could be inferred through redundancy analysis (RDA) that the soil bulk density, organic matter and total nitrogen were the main environmental factors influencing soil meso- and micro-fauna community structure in urban forest. The positive correlations occurred between the individual number of Arcari, Enchytraeidae and soil organic matter and total nitrogen, as well as between the individual number of Diptera larvae, Rotatoria and soil water content.

Developing a nutrient pollution model to assist policy makers by using a meso-scale Minimum Information Requirement (MIR) approach

NASA Astrophysics Data System (ADS)

Adams, R.; Quinn, P. F.; Bowes, M. J.

2014-09-01

A model for simulating runoff pathways and water quality fluxes has been developed using the Minimum Information (MIR) approach. The model, the Catchment Runoff Attenuation Tool (CRAFT) is applicable to meso-scale catchments which focusses primarily on hydrological pathways that mobilise nutrients. Hence CRAFT can be used investigate the impact of management intervention strategies designed to reduce the loads of nutrients into receiving watercourses. The model can help policy makers, for example in Europe, meet water quality targets and consider methods to obtain "good" ecological status. A case study of the 414 km2 Frome catchment, Dorset UK, has been described here as an application of the CRAFT model. The model was primarily calibrated on ten years of weekly data to reproduce the observed flows and nutrient (nitrate nitrogen - N - and phosphorus - P) concentrations. Also data from two years of sub-daily high resolution monitoring at the same site were also analysed. These data highlighted some additional signals in the nutrient flux, particularly of soluble reactive phosphorus, which were not observable in the weekly data. This analysis has prompted the choice of using a daily timestep for this meso-scale modelling study as the minimum information requirement. A management intervention scenario was also run to show how the model can support catchment managers to investigate how reducing the concentrations of N and P in the various flow pathways. This scale appropriate modelling tool can help policy makers consider a range of strategies to to meet the European Union (EU) water quality targets for this type of catchment.

Toward Improved Parameterization of a Meso-Scale Hydrologic Model in a Discontinuous Permafrost, Boreal Forest Ecosystem

NASA Astrophysics Data System (ADS)

Endalamaw, A. M.; Bolton, W. R.; Young, J. M.; Morton, D.; Hinzman, L. D.

2013-12-01

The sub-arctic environment can be characterized as being located in the zone of discontinuous permafrost. Although the distribution of permafrost is site specific, it dominates many of the hydrologic and ecologic responses and functions including vegetation distribution, stream flow, soil moisture, and storage processes. In this region, the boundaries that separate the major ecosystem types (deciduous dominated and coniferous dominated ecosystems) as well as permafrost (permafrost verses non-permafrost) occur over very short spatial scales. One of the goals of this research project is to improve parameterizations of meso-scale hydrologic models in this environment. Using the Caribou-Poker Creeks Research Watershed (CPCRW) as the test area, simulations of the headwater catchments of varying permafrost and vegetation distributions were performed. CPCRW, located approximately 50 km northeast of Fairbanks, Alaska, is located within the zone of discontinuous permafrost and the boreal forest ecosystem. The Variable Infiltration Capacity (VIC) model was selected as the hydrologic model. In CPCRW, permafrost and coniferous vegetation is generally found on north facing slopes and valley bottoms. Permafrost free soils and deciduous vegetation is generally found on south facing slopes. In this study, hydrologic simulations using fine scale vegetation and soil parameterizations - based upon slope and aspect analysis at a 50 meter resolution - were conducted. Simulations were also conducted using downscaled vegetation from the Scenarios Network for Alaska and Arctic Planning (SNAP) (1 km resolution) and soil data sets from the Food and Agriculture Organization (FAO) (approximately 9 km resolution). Preliminary simulation results show that soil and vegetation parameterizations based upon fine scale slope/aspect analysis increases the R2 values (0.5 to 0.65 in the high permafrost (53%) basin; 0.43 to 0.56 in the low permafrost (2%) basin) relative to parameterization based on coarse scale data. These results suggest that using fine resolution parameterizations can be used to improve meso-scale hydrological modeling in this region.

Physics of magnetospheric boundary layers

NASA Technical Reports Server (NTRS)

Cairns, I. H.

1993-01-01

The central ideas of this grant are that the magnetospheric boundary layers link disparate regions of the magnetosphere together, and the global behavior of the magnetosphere can be understood only by understanding the linking mechanisms. Accordingly the present grant includes simultaneous research on the global, meso-, and micro-scale physics of the magnetosphere and its boundary layers. These boundary layers include the bow shock, magnetosheath, the plasma sheet boundary layer, and the ionosphere. Analytic, numerical and simulation projects have been performed on these subjects, as well as comparison of theoretical results with observational data. Very good progress has been made, with four papers published or in press and two additional papers submitted for publication during the six month period 1 June - 30 November 1993. At least two projects are currently being written up. In addition, members of the group have given papers at scientific meetings. The further structure of this report is as follows: section two contains brief accounts of research completed during the last six months, while section three describes the research projects intended for the grant's final period.

Piezoelectric Energy Harvesting: A Green and Clean Alternative for Sustained Power Production

ERIC Educational Resources Information Center

Cook-Chennault, Kimberly Ann; Thambi, Nithya; Bitetto, Mary Anne; Hameyie, E. B.

2008-01-01

Providing efficient and clean power is a challenge for devices that range from the micro to macro in scale. Although there has been significant progress in the development of micro-, meso-, and macro-scale power supplies and technologies, realization of many devices is limited by the inability of power supplies to scale with the diminishing sizes…

Variability of the Somali Current and eddies during the southwest monsoon regimes

NASA Astrophysics Data System (ADS)

Trott, Corinne B.; Subrahmanyam, Bulusu; Murty, V. S. N.

2017-09-01

The meso-scale eddies and currents in the Arabian Sea are analyzed using different satellite observations, Simple Oceanic Data Assimilation (SODA) reanalysis, and Ocean Reanalysis System 4 (ORAS4) from 1993 to 2016 to investigate the impacts of Southwest (SW) Monsoon strength on Somali Current (SC) mesoscale circulations such as the Great Whirl (GW), the Socotra Eddy (SE), the Southern Gyre (SG), and smaller eddies. Increased Ekman pumping during stronger SW monsoons strengthens coastal upwelling along the Somali coast. The Arabian Sea basin-wide anticyclonic circulation and presence of the GW form mesoscale circulation patterns favourable to advection of upwelled waters eastward into the central Arabian Sea. In September, after the SW monsoon winds reach peak strength in July and August, a higher number of discrete anticyclonic eddies with higher (> 20 cm) sea surface height anomalies develop in strong and normal intensity SW monsoon seasons than weaker SW monsoon seasons.

Assessing the indirect effects due to natural hazards on a mesoscale

NASA Astrophysics Data System (ADS)

Pfurtscheller, C.; Schwarze, R.

2009-04-01

Measuring indirect economic costs and other effects from natural hazards, especially floods in alpine and other mountainous regions, are a necessary part of a comprehensive economic assessment. Their omission seriously affects the relative economic benefits of structural or non structural measures of flood defence. Surpassing controversial, IO-model-based economic estimates, analysing indirect economic effects lead to the key question of identifying and evaluating the drivers of indirect economic effects and resilience to system effects in the regional economy, i.e. at the meso-level. This investigation takes place for the catastrophic floods in summer 2005 in the provinces of Tyrol and Vorarlberg, Austria, which caused an estimated € 670 Mio direct loss on private and public assets and severe interruptions in lifeline services. The paper starts out with differentiating the concept of indirect economic costs from direct costs, examing different temporal (short vs. long-term) and spatial (macro-, meso- vs. microeconomic) system boundaries. It surveys common theories of economic resilience and vulnerability at the regional economy level. Indirect effects at the regional economy level can be defined as interferences of the economic exchange of goods and services triggered by breakdowns of transport lines and critical production inputs. The extent and persistence of indirect effects of natural hazards is not only by parameters of the extreme event, such as duration and amplitude of the flood, but much more by resilience parameters of the regional economy such as size of enterprises, the network structure (linkages) of the regional economy, availability of insurance and relief funds, and the stock of inventory. These effects can only be dissected by means of expert judgement and event studies. This paper presents the results of a survey conducted among business practioneers, members of chamber of commerce, civil protection agencies to identify and scale the drivers of indirect costs triggered by floods on a local and regional scale. We develop a risk point scale and explain how it can be nested into IO-model-based economic tools such as the HAZUS indirect economic loss calculator

Emergence of reconfigurable wires and spinners via dynamic self-assembly

DOE PAGES

Kokot, Gasper; Piet, David; Whitesides, George M.; ...

2015-03-26

Dissipative colloidal materials use energy to generate and maintain structural complexity. The energy injection rate, and properties of the environment are important control parameters that influence the outcome of dynamic self-assembly. Here we demonstrate that dispersions of magnetic microparticles confined at the air-liquid interface, and energized by a uniaxial in-plane alternating magnetic field, self-assemble into a variety of structures that range from pulsating clusters and single-particle-thick wires to dynamic arrays of spinners (self-assembled short chains) rotating in either direction. The spinners emerge via spontaneous breaking of the uniaxial symmetry of the energizing magnetic field. Demonstration of the formation and disaggregationmore » of particle assemblies suggests strategies to form new meso-scale structures with the potential to perform functions such as mixing and sensing.« less

Observations and modeling of the effects of waves and rotors on submeso and turbulence variability within the stable boundary layer over central Pennsylvania

NASA Astrophysics Data System (ADS)

Suarez Mullins, Astrid

Terrain-induced gravity waves and rotor circulations have been hypothesized to enhance the generation of submeso motions (i.e., nonstationary shear events with spatial and temporal scales greater than the turbulence scale and smaller than the meso-gamma scale) and to modulate low-level intermittency in the stable boundary layer (SBL). Intermittent turbulence, generated by submeso motions and/or the waves, can affect the atmospheric transport and dispersion of pollutants and hazardous materials. Thus, the study of these motions and the mechanisms through which they impact the weakly to very stable SBL is crucial for improving air quality modeling and hazard predictions. In this thesis, the effects of waves and rotor circulations on submeso and turbulence variability within the SBL is investigated over the moderate terrain of central Pennsylvania using special observations from a network deployed at Rock Springs, PA and high-resolution Weather Research and Forecasting (WRF) model forecasts. The investigation of waves and rotors over central PA is important because 1) the moderate topography of this region is common to most of the eastern US and thus the knowledge acquired from this study can be of significance to a large population, 2) there have been little evidence of complex wave structures and rotors reported for this region, and 3) little is known about the waves and rotors generated by smaller and more moderate topographies. Six case studies exhibiting an array of wave and rotor structures are analyzed. Observational evidence of the presence of complex wave structures, resembling nonstationary trapped gravity waves and downslope windstorms, and complex rotor circulations, resembling trapped and jump-type rotors, is presented. These motions and the mechanisms through which they modulate the SBL are further investigated using high-resolution WRF forecasts. First, the efficacy of the 0.444-km horizontal grid spacing WRF model to reproduce submeso and meso-gamma motions, generated by waves and rotors and hypothesized to impact the SBL, is investigated using a new wavelet-based verification methodology for assessing non-deterministic model skill in the submeso and meso-gamma range to complement standard deterministic measures. This technique allows the verification and/or intercomparison of any two nonstationary stochastic systems without many of the limitations of typical wavelet-based verification approaches (e.g., selection of noise models, testing for significance, etc.). Through this analysis, it is shown that the WRF model largely underestimates the number of small amplitude fluctuations in the small submeso range, as expected; and it overestimates the number of small amplitude fluctuations in the meso-gamma range, generally resulting in forecasts that are too smooth. Investigation of the variability for different initialization strategies shows that deterministic wind speed predictions are less sensitive to the choice of initialization strategy than temperature forecasts. Similarly, investigation of the variability for various planetary boundary layer (PBL) parameterizations reveals that turbulent kinetic energy (TKE)-based schemes have an advantage over the non-local schemes for non-deterministic motions. The larger spread in the verification scores for various PBL parameterizations than initialization strategies indicates that PBL parameterization may play a larger role modulating the variability of non-deterministic motions in the SBL for these cases. These results confirm previous findings that have shown WRF to have limited skill forecasting submeso variability for periods greater than ~20 min. The limited skill of the WRF at these scales in these cases is related to the systematic underestimation of the amplitude of observed fluctuations. These results are implemented in the model design and configuration for the investigation of nonstationary waves and rotor structures modulating submeso and mesogamma motions and the SBL. Observations and WRF forecasts of two wave cases characterized by nonstationary waves and rotors are investigated to show the WRF model to have reasonable accuracy forecasting low-level temperature and wind speed in the SBL and to qualitatively produce rotors, similar to those observed, as well as some of the mechanisms modulating their development and evolution. Finally, observations and high-resolution WRF forecasts under different environmental conditions using various initialization strategies are used to investigate the impact of nonlinear gravity waves and rotor structures on the generation of intermittent turbulence and valley transport in the SBL. Evidence of the presence of elevated regions of TKE generated by the complex waves and rotors is presented and investigated using an additional four case studies, exhibiting two synoptic flow regimes and different wave and rotor structures. Throughout this thesis, terrain-induced gravity waves and rotors in the SBL are shown to synergistically interact with the surface cold pool and to enhance low-level turbulence intermittency through the development of submeso and meso-gamma motions. These motions are shown to be an important source of uncertainty for the atmospheric transport and dispersion of pollutants and hazardous materials under very stable conditions. (Abstract shortened by ProQuest.).

Hierarchical meso/macro-porous carbon fabricated from dual MgO templates for direct electron transfer enzymatic electrodes.

PubMed

Funabashi, Hiroto; Takeuchi, Satoshi; Tsujimura, Seiya

2017-03-23

We designed a three-dimensional (3D) hierarchical pore structure to improve the current production efficiency and stability of direct electron transfer-type biocathodes. The 3D hierarchical electrode structure was fabricated using a MgO-templated porous carbon framework produced from two MgO templates with sizes of 40 and 150 nm. The results revealed that the optimal pore composition for a bilirubin oxidase-catalysed oxygen reduction cathode was a mixture of 33% macropores and 67% mesopores (MgOC 33 ). The macropores improve mass transfer inside the carbon material, and the mesopores improve the electron transfer efficiency of the enzyme by surrounding the enzyme with carbon.

Hierarchical meso/macro-porous carbon fabricated from dual MgO templates for direct electron transfer enzymatic electrodes

NASA Astrophysics Data System (ADS)

Funabashi, Hiroto; Takeuchi, Satoshi; Tsujimura, Seiya

2017-03-01

We designed a three-dimensional (3D) hierarchical pore structure to improve the current production efficiency and stability of direct electron transfer-type biocathodes. The 3D hierarchical electrode structure was fabricated using a MgO-templated porous carbon framework produced from two MgO templates with sizes of 40 and 150 nm. The results revealed that the optimal pore composition for a bilirubin oxidase-catalysed oxygen reduction cathode was a mixture of 33% macropores and 67% mesopores (MgOC33). The macropores improve mass transfer inside the carbon material, and the mesopores improve the electron transfer efficiency of the enzyme by surrounding the enzyme with carbon.

The High-Resolution Wave-Propagation Method Applied to Meso- and Micro-Scale Flows

NASA Technical Reports Server (NTRS)

Ahmad, Nashat N.; Proctor, Fred H.

2012-01-01

The high-resolution wave-propagation method for computing the nonhydrostatic atmospheric flows on meso- and micro-scales is described. The design and implementation of the Riemann solver used for computing the Godunov fluxes is discussed in detail. The method uses a flux-based wave decomposition in which the flux differences are written directly as the linear combination of the right eigenvectors of the hyperbolic system. The two advantages of the technique are: 1) the need for an explicit definition of the Roe matrix is eliminated and, 2) the inclusion of source term due to gravity does not result in discretization errors. The resulting flow solver is conservative and able to resolve regions of large gradients without introducing dispersion errors. The methodology is validated against exact analytical solutions and benchmark cases for non-hydrostatic atmospheric flows.

Physical Habitat Characteristics on the North and South Forks of the Shenandoah River, VA in 2002-2007

USGS Publications Warehouse

Krstolic, Jennifer L.; Hayes, Donald C.

2010-01-01

Data collected with the GeoXT Trimble GPS unit using ArcPad 6.1. (summer 2006-2007). Files were created within a geodatabase to create a data dictionary for use in ArcPad during data collection. Drop down lists for habitat type, substrate, depth, width, length, and descriptions were included. Data files produced on the GeoXT were point shapefiles that could be checked back into the geodatabase and viewable as a layer. Points were gathered while canoeing along the South Fork Shenandoah River. Each location marked a change in meso-scale habitat type. GPS points were supplemented with GIS-derived points in areas where manual measurements were made. The points were used to generate a line coverage. This coverage represents physical habitat at a meso-scale (width of stream).

Army Maneuver Center of Excellence

DTIC Science & Technology

2012-10-18

agreements throughout DoD DARPA, JIEDDO, DHS, FAA, DoE, NSA , NASA, SMDC, etc. Strategic Partnerships Benefit the Army Materiel Enterprise External... Neuroscience Network Sciences Hierarchical Computing Extreme Energy Science Autonomous Systems Technology Emerging Sciences Meso-scale (grain...scales • Improvements in Soldier-system overall performance → operational neuroscience and advanced simulation and training technologies

Eddy forced variations in on- and off-margin summertime circulation along the 1000-m isobath of the northern Gulf of Mexico, 2000-2003, and links with sperm whale distributions along the middle slope

NASA Astrophysics Data System (ADS)

Biggs, Douglas C.; Jochens, Ann E.; Howard, Matthew K.; DiMarco, Steven F.; Mullin, Keith D.; Leben, Robert R.; Muller-Karger, Frank E.; Hu, Chuanmin

In summers 2000-2003, NOAA Ship Gordon Gunter and TAMU R/V Gyre dropped XBTs and logged ADCP data while carrying out visual and passive-acoustic surveys for sperm whales along the 1000-m isobath of the northern Gulf of Mexico. The ships also made CTD casts, particularly when/where the XBT and ADCP data indicated the ships were passing into or out of anticyclonic and/or cyclonic slope eddies. The fine-scale resolution of the ship surveys, when combined with the meso-scale resolution of remote sensing surveys of sea surface height and ocean color, document the summer-to-summer variability in the intensity and geographic location of Loop Current eddies, warm slope eddies, and areas of cyclonic circulation over this middle slope region of the northern Gulf of Mexico. These variations forced striking year-to-year differences in the locations along the 1000-m isobath where there was on-margin and off-margin flow, and in locations where sperm whales were encountered along the 1000-m isobath. For example, when there was on-margin flow into the Mississippi Canyon region in early summer 2003, sperm whales were very rarely seen or heard there. In contrast, later that summer and during other summers when flow was along-margin or off-margin there, sperm whales were locally abundant. In this report we describe how eddy-forced variations in on-margin and off-margin flow changed the meso-scale circulation along the 1000-m isobath, and we show that most sperm whales were encountered in regions of negative SSH and/or higher-than-average surface chlorophyll.

Evaluation of high intensity precipitation from 16 Regional climate models over a meso-scale catchment in the Midlands Regions of England

NASA Astrophysics Data System (ADS)

Wetterhall, F.; He, Y.; Cloke, H.; Pappenberger, F.; Freer, J.; Wilson, M.; McGregor, G.

2009-04-01

Local flooding events are often triggered by high-intensity rain-fall events, and it is important that these can be correctly modelled by Regional Climate Models (RCMs) if the results are to be used in climate impact assessment. In this study, daily precipitation from 16 RCMs was compared with observations over a meso-scale catchment in the Midlands Region of England. The RCM data was provided from the European research project ENSEMBLES and the precipitation data from the UK MetOffice. The RCMs were all driven by reanalysis data from the ERA40 dataset over the time period 1961-2000. The ENSEMBLES data is on the spatial scale of 25 x 25 km and it was disaggregated onto a 5 x 5 km grid over the catchment and compared with interpolated observational data with the same resolution. The mean precipitation was generally underestimated by the ENSEMBLES data, and the maximum and persistence of high intensity rainfall was even more underestimated. The inter-annual variability was not fully captured by the RCMs, and there was a systematic underestimation of precipitation during the autumn months. The spatial pattern in the modelled precipitation data was too smooth in comparison with the observed data, especially in the high altitudes in the western part of the catchment where the high precipitation usually occurs. The RCM outputs cannot reproduce the current high intensity precipitation events that are needed to sufficiently model extreme flood events. The results point out the discrepancy between climate model output and the high intensity precipitation input needs for hydrological impact modelling.

Formation of Electrostatic Potential Drops in the Auroral Zone

NASA Technical Reports Server (NTRS)

Schriver, D.; Ashour-Abdalla, M.; Richard, R. L.

2001-01-01

In order to examine the self-consistent formation of large-scale quasi-static parallel electric fields in the auroral zone on a micro/meso scale, a particle in cell simulation has been developed. The code resolves electron Debye length scales so that electron micro-processes are included and a variable grid scheme is used such that the overall length scale of the simulation is of the order of an Earth radii along the magnetic field. The simulation is electrostatic and includes the magnetic mirror force, as well as two types of plasmas, a cold dense ionospheric plasma and a warm tenuous magnetospheric plasma. In order to study the formation of parallel electric fields in the auroral zone, different magnetospheric ion and electron inflow boundary conditions are used to drive the system. It has been found that for conditions in the primary (upward) current region an upward directed quasi-static electric field can form across the system due to magnetic mirroring of the magnetospheric ions and electrons at different altitudes. For conditions in the return (downward) current region it is shown that a quasi-static parallel electric field in the opposite sense of that in the primary current region is formed, i.e., the parallel electric field is directed earthward. The conditions for how these different electric fields can be formed are discussed using satellite observations and numerical simulations.

A kinetic energy study of the meso beta-scale storm environment during AVE-SESAME 5 (20-21 May 1979)

NASA Technical Reports Server (NTRS)

Printy, M. F.; Fuelberg, H. E.

1984-01-01

Kinetic energy of the near storm environment was analyzed by meso beta scale data. It was found that horizontal winds in the 400 to 150 mb layer strengthen rapidly north of the developing convection. Peak values then decrease such that the maximum disappears 6 h later. Southeast of the storms, wind speeds above 300 mb decrease nearly 50% during the 3 h period of most intense thunderstorm activity. When the convection dissipates, wind patterns return to prestorm conditions. The mesoscale storm environment of AVE-SESAME 5 is characterized by large values of cross contour generation of kinetic energy, transfers of energy to nonresolvable scales of motion, and horizontal flux divergence. These processes are maximized within the upper troposphere and are greatest during times of strongest convection. It is shown that patterns agree with observed weather features. The southeast area of the network is examined to determine causes for vertical wind variations.

Towards mechanism-based simulation of impact damage using exascale computing

NASA Astrophysics Data System (ADS)

Shterenlikht, Anton; Margetts, Lee; McDonald, Samuel; Bourne, Neil K.

2017-01-01

Over the past 60 years, the finite element method has been very successful in modelling deformation in engineering structures. However the method requires the definition of constitutive models that represent the response of the material to applied loads. There are two issues. Firstly, the models are often difficult to define. Secondly, there is often no physical connection between the models and the mechanisms that accommodate deformation. In this paper, we present a potentially disruptive two-level strategy which couples the finite element method at the macroscale with cellular automata at the mesoscale. The cellular automata are used to simulate mechanisms, such as crack propagation. The stress-strain relationship emerges as a continuum mechanics scale interpretation of changes at the micro- and meso-scales. Iterative two-way updating between the cellular automata and finite elements drives the simulation forward as the material undergoes progressive damage at high strain rates. The strategy is particularly attractive on large-scale computing platforms as both methods scale well on tens of thousands of CPUs.

[Community structure of soil fauna in Eucalyptus grandis plantations at different slope locations].

PubMed

Zhao, Yu; Zhong, Yu; Zhang, Jian; Yang, Wan-qin

2010-09-01

To understand the effects of slope location on the community structure of soil fauna in Eucalyptus grandis plantation, an investigation was made on the soil fauna in 3 E. grandis plantations at different slope locations in the hilly area of Sichuan Province from January to October 2009. A total of 39,2762 individuals were observed, belonging to 146 groups, 7 phyla, 16 classes, and 31 orders. The community composition, trophic group, diversity, and seasonal dynamics of soil fauna in the plantations all varied with slope. The abundance of macro-fauna, xeric meso- and micro-fauna, saprophagous macro-fauna, and omnivorous xeric meso- and micro-fauna increased with the decrease of slope, indicating that soil fauna had sensitive responses to the soil environmental factors affected by slope. Significant differences in the diversity of soil saprophagous macro-fauna and hygrophilous meso- and micro-fauna were observed at different slope locations, suggesting that these two faunal groups could be used as the indicators of the habitat heterogeneity of E. grandis plantations at different slope. Overall, slope location had definite effects on the community structure and distribution of soil fauna in the E. grandis plantations, but the effects were not statistically significant.

Use of a robot for high-throughput crystallization of membrane proteins in lipidic mesophases.

PubMed

Li, Dianfan; Boland, Coilín; Walsh, Kilian; Caffrey, Martin

2012-09-01

Structure-function studies of membrane proteins greatly benefit from having available high-resolution 3-D structures of the type provided through macromolecular X-ray crystallography (MX). An essential ingredient of MX is a steady supply of ideally diffraction-quality crystals. The in meso or lipidic cubic phase (LCP) method for crystallizing membrane proteins is one of several methods available for crystallizing membrane proteins. It makes use of a bicontinuous mesophase in which to grow crystals. As a method, it has had some spectacular successes of late and has attracted much attention with many research groups now interested in using it. One of the challenges associated with the method is that the hosting mesophase is extremely viscous and sticky, reminiscent of a thick toothpaste. Thus, dispensing it manually in a reproducible manner in small volumes into crystallization wells requires skill, patience and a steady hand. A protocol for doing just that was developed in the Membrane Structural & Functional Biology (MS&FB) Group(1-3). JoVE video articles describing the method are available(1,4). The manual approach for setting up in meso trials has distinct advantages with specialty applications, such as crystal optimization and derivatization. It does however suffer from being a low throughput method. Here, we demonstrate a protocol for performing in meso crystallization trials robotically. A robot offers the advantages of speed, accuracy, precision, miniaturization and being able to work continuously for extended periods under what could be regarded as hostile conditions such as in the dark, in a reducing atmosphere or at low or high temperatures. An in meso robot, when used properly, can greatly improve the productivity of membrane protein structure and function research by facilitating crystallization which is one of the slow steps in the overall structure determination pipeline. In this video article, we demonstrate the use of three commercially available robots that can dispense the viscous and sticky mesophase integral to in meso crystallogenesis. The first robot was developed in the MS&FB Group(5,6). The other two have recently become available and are included here for completeness. An overview of the protocol covered in this article is presented in Figure 1. All manipulations were performed at room temperature (~20 °C) under ambient conditions.

Characterization and quantification of racemic and meso-ethylenediamine-N,N'-bis(2-hydroxy-5-sulfophenylacetic) acid/iron (III) by ion-pair ultra-high performance liquid chromatography coupled with diode array detector and electrospray tandem mass spectrometry.

PubMed

Biasone, Alessandro; Cianci, Giusto; Di Tommaso, Donata; Piaggesi, Alberto; Tagliavini, Emilio; Galletti, Paola; Moretti, Fabio

2013-03-22

EDDHSA/Fe is a promising substitute of EDDHA/Fe to fight iron chlorosis. o,o-EDDHSA structure contains two chiral carbons giving the racemic and meso couples of stereoisomers. Ion-pair HPLC and UHPLC-UV/Vis-ESI-MS/MS methods were developed for the determination of racemic and meso-o,o-EDDHSA/Fe in commercial samples of chelates. The lack of a commercial EDDHSA standard was overcome by sulfonation of a commercial available o,o-EDDHA standard and subsequent quantification by (1)H-NMR. Assignment of configurations was carried out starting from racemic and meso-o,o-EDDHA/Fe by direct sulfonation to give the corresponding o,o-EDDHSA/Fe isomers. The performances of these methods were assessed in terms of intra and inter-day precision, linearity and selectivity. The high selectivity and lower detection limit (nanomolar) of the UHPLC-ESI-MS/MS method could allow to deepen the knowledge relative to meso and rac-o,o-EDDHSA/Fe interactions with plants, its fate in different soil conditions, its mobility and other environmental aspects. Copyright © 2013 Elsevier B.V. All rights reserved.

Predicting the size and elevation of future mountain forests: Scaling macroclimate to microclimate

NASA Astrophysics Data System (ADS)

Cory, S. T.; Smith, W. K.

2017-12-01

Global climate change is predicted to alter continental scale macroclimate and regional mesoclimate. Yet, it is at the microclimate scale that organisms interact with their physiochemical environments. Thus, to predict future changes in the biota such as biodiversity and distribution patterns, a quantitative coupling between macro-, meso-, and microclimatic parameters must be developed. We are evaluating the impact of climate change on the size and elevational distribution of conifer mountain forests by determining the microclimate necessary for new seedling survival at the elevational boundaries of the forest. This initial life stage, only a few centimeters away from the soil surface, appears to be the bottleneck to treeline migration and the expansion or contraction of a conifer mountain forest. For example, survival at the alpine treeline is extremely rare and appears to be limited to facilitated microsites with low sky exposure. Yet, abundant mesoclimate data from standard weather stations have rarely been scaled to the microclimate level. Our research is focusing on an empirical downscaling approach linking microclimate measurements at favorable seedling microsites to the meso- and macro-climate levels. Specifically, mesoclimate values of air temperature, relative humidity, incident sunlight, and wind speed from NOAA NCEI weather stations can be extrapolated to the microsite level that is physiologically relevant for seedling survival. Data will be presented showing a strong correlation between incident sunlight measured at 2-m and seedling microclimate, despite large differences from seedling/microsite temperatures. Our downscaling approach will ultimately enable predictions of microclimate from the much more abundant mesoclimate data available from a variety of sources. Thus, scaling from macro- to meso- to microclimate will be possible, enabling predictions of climate change models to be translated to the microsite level. This linkage between measurement scales will enable a more precise prediction of the effects of climate change on the future extent and elevational distribution of our mountain forests and an accompanying array of critical ecosystem services.

Regionalization of meso-scale physically based nitrogen modeling outputs to the macro-scale by the use of regression trees

NASA Astrophysics Data System (ADS)

Künne, A.; Fink, M.; Kipka, H.; Krause, P.; Flügel, W.-A.

2012-06-01

In this paper, a method is presented to estimate excess nitrogen on large scales considering single field processes. The approach was implemented by using the physically based model J2000-S to simulate the nitrogen balance as well as the hydrological dynamics within meso-scale test catchments. The model input data, the parameterization, the results and a detailed system understanding were used to generate the regression tree models with GUIDE (Loh, 2002). For each landscape type in the federal state of Thuringia a regression tree was calibrated and validated using the model data and results of excess nitrogen from the test catchments. Hydrological parameters such as precipitation and evapotranspiration were also used to predict excess nitrogen by the regression tree model. Hence they had to be calculated and regionalized as well for the state of Thuringia. Here the model J2000g was used to simulate the water balance on the macro scale. With the regression trees the excess nitrogen was regionalized for each landscape type of Thuringia. The approach allows calculating the potential nitrogen input into the streams of the drainage area. The results show that the applied methodology was able to transfer the detailed model results of the meso-scale catchments to the entire state of Thuringia by low computing time without losing the detailed knowledge from the nitrogen transport modeling. This was validated with modeling results from Fink (2004) in a catchment lying in the regionalization area. The regionalized and modeled excess nitrogen correspond with 94%. The study was conducted within the framework of a project in collaboration with the Thuringian Environmental Ministry, whose overall aim was to assess the effect of agro-environmental measures regarding load reduction in the water bodies of Thuringia to fulfill the requirements of the European Water Framework Directive (Bäse et al., 2007; Fink, 2006; Fink et al., 2007).

The Transition Region Explorer: Observing the Multi-Scale Dynamics of Geospace

NASA Astrophysics Data System (ADS)

Donovan, E.

2015-12-01

Meso- and global-scale IT remote sensing is accomplished via satellite imagers and ground-based instruments. On the ground, the approach is arrays providing extensive as possible coverage (the "net") and powerful observatories that drill deep to provide detailed information about small-scale processes (the "drill"). Always, there is a trade between cost, spatial resolution, coverage (extent), number of parameters, and more, such that in general the larger the network the sparser the coverage. Where are we now? There are important gaps. With THEMIS-ASI, we see processes that quickly evolve beyond the field of view of one observatory, but involve space/time scales not captured by existing meso- and large-scale arrays. Many forefront questions require observations at heretofore unexplored space and time scales, and comprehensive inter-hemispheric conjugate observations than are presently available. To address this, a new ground-based observing initiative is being developed in Canada. Called TREx, for Transition Region Explorer, this new facility will incorporate dedicated blueline, redline, and Near-Infrared All-Sky Imagers, together with an unprecedented network of ten imaging riometers, with a combined field of view spanning more than three hours of magnetic local time and from equatorward to poleward of typical auroral latitudes (spanning the ionospheric footprint of the "nightside transition region" that separates the highly stretched tail and the inner magnetosphere). The TREx field-of-view is covered by HF radars, and contains a dense network of magnetometers and VLF receivers, as well as other geospace and upper atmospheric remote sensors. Taken together, TREx and these co-located instruments represent a quantum leap forward in terms of imaging, in multiple parameters (precipitation, ionization, convection, and currents), ionospheric dynamics in the above-mentioned scale gap. This represents an exciting new opportunity for studying geospace at the system level, especially for using the aurora to remote sense magnetospheric plasma physics and dynamics, and comes with a set of Big Data challenges that are going to be exciting. One such challenge is the development of a fundamentally new type of data product, namely time series of multi-parameter, geospatially referenced 'data cubes'.

Monitoring Meso-Scale Ordering of Cellulose in Intact Plant Cell Walls Using Sum Frequency Generation Spectroscopy1[C][W][OPEN

PubMed Central

Park, Yong Bum; Lee, Christopher M.; Koo, Bon-Wook; Park, Sunkyu; Cosgrove, Daniel J.; Kim, Seong H.

2013-01-01

Sum frequency generation (SFG) vibration spectroscopy can selectively detect crystalline cellulose without spectral interference from cell wall matrix components. Here, we show that the cellulose SFG spectrum is sensitive to cellulose microfibril alignment and packing within the cell wall. SFG intensity at 2,944 cm−1 correlated well with crystalline cellulose contents of various regions of the Arabidopsis (Arabidopsis thaliana) inflorescence, while changes in the 3,320/2,944 cm−1 intensity ratio suggest subtle changes in cellulose ordering as tissues mature. SFG analysis of two cellulose synthase mutants (irx1/cesa8 and irx3/cesa7) indicates a reduction in cellulose content without evidence of altered cellulose structure. In primary cell walls of Arabidopsis, cellulose exhibited a characteristic SFG peak at 2,920 and 3,320 cm−1, whereas in secondary cell walls, it had peaks at 2,944 and 3,320 cm−1. Starch (amylose) gave an SFG peak at 2,904 cm−1 (CH methine) whose intensity increased with light exposure prior to harvest. Selective removal of matrix polysaccharides from primary cell walls by acid hydrolysis resulted in an SFG spectrum resembling that of secondary wall cellulose. Our results show that SFG spectroscopy is sensitive to the ordering of cellulose microfibrils in plant cell walls at the meso scale (nm to μm) that is important for cell wall architecture but cannot be probed by other spectroscopic or diffraction techniques. PMID:23995148

Monitoring meso-scale ordering of cellulose in intact plant cell walls using sum frequency generation spectroscopy.

PubMed

Park, Yong Bum; Lee, Christopher M; Koo, Bon-Wook; Park, Sunkyu; Cosgrove, Daniel J; Kim, Seong H

2013-10-01

Sum frequency generation (SFG) vibration spectroscopy can selectively detect crystalline cellulose without spectral interference from cell wall matrix components. Here, we show that the cellulose SFG spectrum is sensitive to cellulose microfibril alignment and packing within the cell wall. SFG intensity at 2,944 cm(-1) correlated well with crystalline cellulose contents of various regions of the Arabidopsis (Arabidopsis thaliana) inflorescence, while changes in the 3,320/2,944 cm(-1) intensity ratio suggest subtle changes in cellulose ordering as tissues mature. SFG analysis of two cellulose synthase mutants (irx1/cesa8 and irx3/cesa7) indicates a reduction in cellulose content without evidence of altered cellulose structure. In primary cell walls of Arabidopsis, cellulose exhibited a characteristic SFG peak at 2,920 and 3,320 cm(-1), whereas in secondary cell walls, it had peaks at 2,944 and 3,320 cm(-1). Starch (amylose) gave an SFG peak at 2,904 cm(-1) (CH methine) whose intensity increased with light exposure prior to harvest. Selective removal of matrix polysaccharides from primary cell walls by acid hydrolysis resulted in an SFG spectrum resembling that of secondary wall cellulose. Our results show that SFG spectroscopy is sensitive to the ordering of cellulose microfibrils in plant cell walls at the meso scale (nm to μm) that is important for cell wall architecture but cannot be probed by other spectroscopic or diffraction techniques.

Implementing of lognormal humidity and cloud-related control variables for the NCEP GSI hybrid EnVAR Assimilation scheme.

NASA Astrophysics Data System (ADS)

Fletcher, S. J.; Kleist, D.; Ide, K.

2017-12-01

As the resolution of operational global numerical weather prediction system approach the meso-scale, then the assumption of Gaussianity for the errors at these scales may not valid. However, it is also true that synoptic variables that are positive definite in behavior, for example humidity, cannot be optimally analyzed with a Gaussian error structure, where the increment could force the full field to go negative. In this presentation we present the initial work of implementing a mixed Gaussian-lognormal approximation for the temperature and moisture variable in both the ensemble and variational component of the NCEP GSI hybrid EnVAR. We shall also lay the foundation for the implementation of the lognormal approximation to cloud related control variables to allow for a possible more consistent assimilation of cloudy radiances.

Structural integrity--Searching the key factor to suppress the voltage fade of Li-rich layered cathode materials through 3D X-ray imaging and spectroscopy techniques

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, Yahong; Hu, Enyuan; Yang, Feifei

Li-rich layered materials are important cathode compounds used in commercial lithium ion batteries, which, however, suffers from some drawbacks including the so-called voltage fade upon electrochemical cycling. Here, our study employs novel transmission X-ray microscopy to investigate the electrochemical reaction induced morphological and chemical changes in the Li-rich Li 2Ru 0.5Mn 0.5O 3 cathode particles at the meso to nano scale. We performed combined X-ray spectroscopy, diffraction and microscopy experiments to systematically study this cathode material's evolution upon cycling as well as to establish a comprehensive understanding of the structural origin of capacity fade through 2D and 3D fine lengthmore » scale morphology and heterogeneity change of this material. This work suggests that atomic manipulation (e.g. doping, substitution etc.) or nano engineering (e.g. nano-sizing, heterogeneous structure) are important strategies to mitigate the internal strain and defects induced by extensive lithium insertion/extraction. It also shows that maintaining the structural integrity is the key in designing and synthesizing lithium-rich layered materials with better cycle stability.« less

CONTINUOUS SPATIAL MAPPING FROM VESSELS: RESULTS AND EXPERIENCE USING VARIOUS SENSORS FOR WATER AND SEDIMENTS IN THE GREAT LAKES

EPA Science Inventory

U.S. EPA research has been exploring the use of vessel-towed sensor and underway acoustic technologies in an effort to develop spatial mapping tools and insights for a next generation of Great Lakes monitoring. Technologies allow fine-scale (meters) to meso-scale (100s of kilome...

Self-Supported Mesostructured Pt-Based Bimetallic Nanospheres Containing an Intermetallic Phase as Ultrastable Oxygen Reduction Electrocatalysts.

PubMed

Kim, Ho Young; Cho, Seonghun; Sa, Young Jin; Hwang, Sun-Mi; Park, Gu-Gon; Shin, Tae Joo; Jeong, Hu Young; Yim, Sung-Dae; Joo, Sang Hoon

2016-10-01

Developing highly active and stable cathode catalysts is of pivotal importance for proton exchange membrane fuel cells (PEMFCs). While carbon-supported nanostructured Pt-based catalysts have so far been the most active cathode catalysts, their durability and single-cell performance are yet to be improved. Herein, self-supported mesostructured Pt-based bimetallic (Meso-PtM; M = Ni, Fe, Co, Cu) nanospheres containing an intermetallic phase are reported, which can combine the beneficial effects of transition metals (M), an intermetallic phase, a 3D interconnected framework, and a mesoporous structure. Meso-PtM nanospheres show enhanced oxygen reduction reaction (ORR) activity, compared to Pt black and Pt/C catalysts. Notably, Meso-PtNi containing an intermetallic phase exhibits ultrahigh stability, showing enhanced ORR activity even after 50 000 potential cycles, whereas Pt black and Pt/C undergo dramatic degradation. Importantly, Meso-PtNi with an intermetallic phase also demonstrated superior activity and durability when used in a PEMFC single-cell, with record-high initial mass and specific activities. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Upper Ocean Meso-Submesoscale Eddy Variability in the Northwestern Pacific from Repeat ADCP Measurements and 1/48-deg MITgcm Simulation

NASA Astrophysics Data System (ADS)

Qiu, B.; Nakano, T.; Chen, S.; Wang, J.; Fu, L. L.; Klein, P.

2016-12-01

With the use of Ka-band radar interferometry, the Surface Water and Ocean Topography (SWOT) satellite will improve the measured sea surface height (SSH) resolution down to the spectral wavelength of 15km, allowing us to investigate for the first time the upper oceancirculation variability at the submesoscale range on the global scale. By analyzing repeat shipboardAcoustic Doppler Current Profiler (ADCP) measurements along 137°E, as well as the 1/48-deg MITgcm simulation output, in the northwest Pacific, we demonstrate that the observed/modeled upper ocean velocities are comprised of balanced geostrophic motions and unbalanced ageostrophic wave motions. The length scale, Lc, that separates the dominance between these two types of motions is found to depend sensitively on the energy level of local mesoscale eddy variability. In the eddy-abundant western boundary current region of Kuroshio, Lc can be shorter than 15km, whereas Lc exceeds 200km along the path of relatively stable North Equatorial Current. Judicious separation between the balanced and unbalanced surface ocean signals will both be a challenge and opportunity for the SWOT mission.

Structural and morphological properties of mesoporous carbon coated molybdenum oxide films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dayal, Saurabh, E-mail: saurabhdayal153@gmail.com; Kumar, C. Sasi, E-mail: csasimv@gmail.com

2016-05-06

In the present study, we report the structural and morphological properties of mesoporous carbon coated molybdenum oxide films. The deposition of films was carried out in a two-step process, the first step involves deposition of molybdenum and carbon bilayer thin films using DC magnetron sputtering. In the second step the sample was ex-situ annealed in a muffle furnace at different temperatures (400°C to 600°C) and air cooled in the ambient atmosphere. The formation of the meso-porous carbon clusters on molybdenum oxide during the cooling step was investigated using FESEM and AFM techniques. The structural details were explored using XRD. Themore » meso-porous carbon were found growing over molybdenum oxide layer as a result of segregation phenomena.« less

Meso-Scale Modeling of Spall in a Heterogeneous Two-Phase Material

DOE Office of Scientific and Technical Information (OSTI.GOV)

Springer, Harry Keo

2008-07-11

The influence of the heterogeneous second-phase particle structure and applied loading conditions on the ductile spall response of a model two-phase material was investigated. Quantitative metallography, three-dimensional (3D) meso-scale simulations (MSS), and small-scale spall experiments provided the foundation for this study. Nodular ductile iron (NDI) was selected as the model two-phase material for this study because it contains a large and readily identifiable second- phase particle population. Second-phase particles serve as the primary void nucleation sites in NDI and are, therefore, central to its ductile spall response. A mathematical model was developed for the NDI second-phase volume fraction that accountedmore » for the non-uniform particle size and spacing distributions within the framework of a length-scale dependent Gaussian probability distribution function (PDF). This model was based on novel multiscale sampling measurements. A methodology was also developed for the computer generation of representative particle structures based on their mathematical description, enabling 3D MSS. MSS were used to investigate the effects of second-phase particle volume fraction and particle size, loading conditions, and physical domain size of simulation on the ductile spall response of a model two-phase material. MSS results reinforce existing model predictions, where the spall strength metric (SSM) logarithmically decreases with increasing particle volume fraction. While SSM predictions are nearly independent of applied load conditions at lower loading rates, which is consistent with previous studies, loading dependencies are observed at higher loading rates. There is also a logarithmic decrease in SSM for increasing (initial) void size, as well. A model was developed to account for the effects of loading rate, particle size, matrix sound-speed, and, in the NDI-specific case, the probabilistic particle volume fraction model. Small-scale spall experiments were designed and executed for the purpose of validating closely-coupled 3D MSS. While the spall strength is nearly independent of specimen thickness, the fragment morphology varies widely. Detailed MSS demonstrate that the interactions between the tensile release waves are altered by specimen thickness and that these interactions are primarily responsible for fragment formation. MSS also provided insights on the regional amplification of damage, which enables the development of predictive void evolution models.« less

Modelling Middle Infrared Thermal Imagery from Observed or Simulated Active Fire

NASA Astrophysics Data System (ADS)

Paugam, R.; Gastellu-Etchegorry, J. P.; Mell, W.; Johnston, J.; Filippi, J. B.

2016-12-01

The Fire Radiative Power (FRP) is used in the atmospheric and fire communities to estimate fire emission. For example, the current version of the emission inventory GFAS is using FRP observation from the MODIS sensors to derive daily global distribution of fire emissions. Although the FRP product is widely accepted, most of its theoretical justifications are still based on small scale burns. When up-scaling to large fires effects of view angle, canopy cover, or smoke absorption are still unknown. To cover those questions, we are building a system based on the DART radiative transfer model to simulate the middle infrared radiance emitted by a propagating fire front and propagating in the surrounding scene made of ambient vegetation and plume aerosols. The current version of the system was applied to fire ranging from a 1m2 to 7ha. The 3D fire scene used as input in DART is made of the flame, the vegetation (burnt and unburnt), and the plume. It can be either set up from [i] 3D physical based model scene (ie WFDS, mainly applicable for small scale burn), [ii] coupled 2D fire spread - atmospheric models outputs (eg ForeFire-MesoNH) or [iii] derived from thermal imageries observations (here plume effects are not considered). In the last two cases, as the complexity of physical processes occurring in the flame (in particular soot formation and emission) is not to solved, the flames structures are parameterized with (a) temperature and soot concentration based on empirical derived profiles and (b) 3D triangular shape hull interpolated at the fire front location. Once the 3D fire scene is set up, DART is then used to render thermal imageries in the middle infrared. Using data collected from burns conducted at different scale, the modelled thermal imageries are compared against observations, and effects of view angle are discussed.

The cubicon method for concentrating membrane proteins in the cubic mesophase.

PubMed

Ma, Pikyee; Weichert, Dietmar; Aleksandrov, Luba A; Jensen, Timothy J; Riordan, John R; Liu, Xiangyu; Kobilka, Brian K; Caffrey, Martin

2017-09-01

The lipid cubic phase (in meso) method is an important approach for generating crystals and high-resolution X-ray structures of integral membrane proteins. However, as a consequence of instability, it can be impossible-using traditional methods-to concentrate certain membrane proteins and complexes to values suitable for in meso crystallization and structure determination. The cubicon method described here exploits the amphiphilic nature of membrane proteins and their natural tendency to partition preferentially into lipid bilayers from aqueous solution. Using several rounds of reconstitution, the protein concentration in the bilayer of the cubic mesophase can be ramped up stepwise from less than a milligram per milliliter to tens of milligrams per milliliter for crystallogenesis. The general applicability of the method is demonstrated with five integral membrane proteins: the β 2 -adrenergic G protein-coupled receptor (β 2 AR), the peptide transporter (PepT St ), diacylglycerol kinase (DgkA), the alginate transporter (AlgE) and the cystic fibrosis transmembrane conductance regulator (CFTR). In the cases of β 2 AR, PepT St , DgkA and AlgE, an effective 20- to 45-fold concentration was realized, resulting in a protein-laden mesophase that allowed the formation of crystals using the in meso method and structure determination to resolutions ranging from 2.4 Å to 3.2 Å. In addition to opening up in meso crystallization to a broader range of integral membrane protein targets, the cubicon method should find application in situations that require membrane protein reconstitution in a lipid bilayer at high concentrations. These applications include functional and biophysical characterization studies for ligand screening, drug delivery, antibody production and protein complex formation. A typical cubicon experiment can be completed in 3-5 h.

Inter-subject FDG PET Brain Networks Exhibit Multi-scale Community Structure with Different Normalization Techniques.

PubMed

Sperry, Megan M; Kartha, Sonia; Granquist, Eric J; Winkelstein, Beth A

2018-07-01

Inter-subject networks are used to model correlations between brain regions and are particularly useful for metabolic imaging techniques, like 18F-2-deoxy-2-(18F)fluoro-D-glucose (FDG) positron emission tomography (PET). Since FDG PET typically produces a single image, correlations cannot be calculated over time. Little focus has been placed on the basic properties of inter-subject networks and if they are affected by group size and image normalization. FDG PET images were acquired from rats (n = 18), normalized by whole brain, visual cortex, or cerebellar FDG uptake, and used to construct correlation matrices. Group size effects on network stability were investigated by systematically adding rats and evaluating local network connectivity (node strength and clustering coefficient). Modularity and community structure were also evaluated in the differently normalized networks to assess meso-scale network relationships. Local network properties are stable regardless of normalization region for groups of at least 10. Whole brain-normalized networks are more modular than visual cortex- or cerebellum-normalized network (p < 0.00001); however, community structure is similar at network resolutions where modularity differs most between brain and randomized networks. Hierarchical analysis reveals consistent modules at different scales and clustering of spatially-proximate brain regions. Findings suggest inter-subject FDG PET networks are stable for reasonable group sizes and exhibit multi-scale modularity.

Development of a Meso-Scale Material Model for Ballistic Fabric and Its Use in Flexible-Armor Protection Systems

NASA Astrophysics Data System (ADS)

Grujicic, M.; Bell, W. C.; Arakere, G.; He, T.; Xie, X.; Cheeseman, B. A.

2010-02-01

A meso-scale ballistic material model for a prototypical plain-woven single-ply flexible armor is developed and implemented in a material user subroutine for the use in commercial explicit finite element programs. The main intent of the model is to attain computational efficiency when calculating the mechanical response of the multi-ply fabric-based flexible-armor material during its impact with various projectiles without significantly sacrificing the key physical aspects of the fabric microstructure, architecture, and behavior. To validate the new model, a comparative finite element method analysis is carried out in which: (a) the plain-woven single-ply fabric is modeled using conventional shell elements and weaving is done in an explicit manner by snaking the yarns through the fabric and (b) the fabric is treated as a planar continuum surface composed of conventional shell elements to which the new meso-scale unit-cell based material model is assigned. The results obtained show that the material model provides a reasonably good description for the fabric deformation and fracture behavior under different combinations of fixed and free boundary conditions. Finally, the model is used in an investigation of the ability of a multi-ply soft-body armor vest to protect the wearer from impact by a 9-mm round nose projectile. The effects of inter-ply friction, projectile/yarn friction, and the far-field boundary conditions are revealed and the results explained using simple wave mechanics principles, high-deformation rate material behavior, and the role of various energy-absorbing mechanisms in the fabric-based armor systems.

Macro- and meso-fabric structures of peritidal tufa stromatolites along the Eastern Cape coast of South Africa

NASA Astrophysics Data System (ADS)

Edwards, Mark Joseph Kalahari; Anderson, Callum Robert; Perissinotto, Renzo; Rishworth, Gavin Midgley

2017-08-01

Stromatolites are rare in modern ecosystems due to factors associated with seawater chemistry or biological competition that restrict their formation. Actively calcifying stromatolites, near the Kei Mouth in the Eastern Cape, South Africa, were discovered in the early 2000s. Similar deposits were later described along a 200 km stretch on the south coast of Port Elizabeth. This study aims to describe the environmental setting, the macro- and meso-structures, as well as the evolution of the deposits near Port Elizabeth compared to other similar formations. Results show that the general environmental setting is consistent amongst peritidal stromatolites, including those described in this study. In all instances stromatolite growth occurs on a wave-cut rocky platform in and around rock pools. Growth is maximal within the intertidal to supratidal zone, as a result of freshwater inflow via emerging mineral springs at the base of landward slopes, and the periodic intrusion of seawater via storm surges or wave splash. In comparison with other systems, the South African stromatolite formations exhibit an additional macro-structure (beachrock/conglomerate) and four previously undescribed meso-structures: wrinkled laminar, laminar flat, rhizoliths, and blistered types. The South African stromatolites are also larger and more concentrated than other peritidal stromatolites, which could be due to this area having more suitable growth conditions.

Multi-scale structure and topological anomaly detection via a new network statistic: The onion decomposition.

PubMed

Hébert-Dufresne, Laurent; Grochow, Joshua A; Allard, Antoine

2016-08-18

We introduce a network statistic that measures structural properties at the micro-, meso-, and macroscopic scales, while still being easy to compute and interpretable at a glance. Our statistic, the onion spectrum, is based on the onion decomposition, which refines the k-core decomposition, a standard network fingerprinting method. The onion spectrum is exactly as easy to compute as the k-cores: It is based on the stages at which each vertex gets removed from a graph in the standard algorithm for computing the k-cores. Yet, the onion spectrum reveals much more information about a network, and at multiple scales; for example, it can be used to quantify node heterogeneity, degree correlations, centrality, and tree- or lattice-likeness. Furthermore, unlike the k-core decomposition, the combined degree-onion spectrum immediately gives a clear local picture of the network around each node which allows the detection of interesting subgraphs whose topological structure differs from the global network organization. This local description can also be leveraged to easily generate samples from the ensemble of networks with a given joint degree-onion distribution. We demonstrate the utility of the onion spectrum for understanding both static and dynamic properties on several standard graph models and on many real-world networks.

The impact of wind energy turbine piles on ocean dynamics

NASA Astrophysics Data System (ADS)

Grashorn, Sebastian; Stanev, Emil V.

2016-04-01

The small- and meso-scale ocean response to wind parks has not been investigated in the southern North Sea until now with the help of high-resolution numerical modelling. Obstacles such as e.g. wind turbine piles may influence the ocean current system and produce turbulent kinetic energy which could affect sediment dynamics in the surrounding area. Two setups of the unstructured-grid model SCHISM (Semi-implicit Cross-scale Hydroscience Integrated System Model) have been developed for an idealized channel including a surface piercing cylindrical obstacle representing the pile and a more realistic test case including four exemplary piles. Experiments using a constant flow around the obstacles and a rotating M2 tidal wave are carried out. The resulting current and turbulence patterns are investigated to estimate the influence of the obstacles on the surrounding ocean dynamics. We demonstrate that using an unstructured ocean model provides the opportunity to embed a high-resolution representation of a wind park turbine pile system into a coarser North Sea setup, which is needed in order to perform a seamless investigation of the resulting geophysical processes.

Regional turbulence patterns driven by meso- and submesoscale processes in the Caribbean Sea

NASA Astrophysics Data System (ADS)

C. Pérez, Juan G.; R. Calil, Paulo H.

2017-09-01

The surface ocean circulation in the Caribbean Sea is characterized by the interaction between anticyclonic eddies and the Caribbean Upwelling System (CUS). These interactions lead to instabilities that modulate the transfer of kinetic energy up- or down-cascade. The interaction of North Brazil Current rings with the islands leads to the formation of submesoscale vorticity filaments leeward of the Lesser Antilles, thus transferring kinetic energy from large to small scales. Within the Caribbean, the upper ocean dynamic ranges from large-scale currents to coastal upwelling filaments and allow the vertical exchange of physical properties and supply KE to larger scales. In this study, we use a regional model with different spatial resolutions (6, 3, and 1 km), focusing on the Guajira Peninsula and the Lesser Antilles in the Caribbean Sea, in order to evaluate the impact of submesoscale processes on the regional KE energy cascade. Ageostrophic velocities emerge as the Rossby number becomes O(1). As model resolution is increased submesoscale motions are more energetic, as seen by the flatter KE spectra when compared to the lower resolution run. KE injection at the large scales is greater in the Guajira region than in the others regions, being more effectively transferred to smaller scales, thus showing that submesoscale dynamics is key in modulating eddy kinetic energy and the energy cascade within the Caribbean Sea.

Incorporation of a Cumulus Fraction Scheme in the GRAPES_Meso and Evaluation of Its Performance

NASA Astrophysics Data System (ADS)

Zheng, X.

2016-12-01

Accurate simulation of cloud cover fraction is a key and difficult issue in numerical modeling studies. Preliminary evaluations have indicated that cloud fraction is generally underestimated in GRAPES_Meso simulations, while the cloud fraction scheme (CFS) of ECMWF can provide more realistic results. Therefore, the ECMWF cumulus fraction scheme is introduced into GRAPES_Meso to replace the original CFS, and the model performance with the new CFS is evaluated based on simulated three-dimensional cloud fractions and surface temperature. Results indicate that the simulated cloud fractions increase and become more accurate with the new CFS; the simulation for vertical cloud structure has improved too; errors in surface temperature simulation have decreased. The above analysis and results suggest that the new CFS has a positive impact on cloud fraction and surface temperature simulation.

Structure, function and carcinogenicity of metabolites of methylated and non-methylated polycyclic aromatic hydrocarbons: a comprehensive review.

PubMed

Flesher, James W; Lehner, Andreas F

2016-01-01

The Unified Theory of PAH Carcinogenicity accommodates the activities of methylated and non-methylated polycyclic aromatic hydrocarbons (PAHs) and states that substitution of methyl groups on meso-methyl substituted PAHs with hydroxy, acetoxy, chloride, bromide or sulfuric acid ester groups imparts potent cancer producing properties. It incorporates specific predictions from past researchers on the mechanism of carcinogenesis by methyl-substituted hydrocarbons, including (1) requirement for metabolism to an ArCH2X type structure where X is a good leaving group and (2) biological substitution of a meso-methyl group at the most reactive center in non-methylated hydrocarbons. The Theory incorporates strong inferences of Fieser: (1) The mechanism of carcinogenesis involves a specific metabolic substitution of a hydrocarbon at its most reactive center and (2) Metabolic elimination of a carcinogen is a detoxifying process competitive with that of carcinogenesis and occurring by a different mechanism. According to this outlook, chemical or biochemical substitution of a methyl group at the reactive meso-position of non-methylated hydrocarbons is the first step in the mechanism of carcinogenesis for most, if not all, PAHs and the most potent metabolites of PAHs are to be found among the meso methyl-substituted hydrocarbons. Some PAHs and their known or potential metabolites and closely related compounds have been tested in rats for production of sarcomas at the site of subcutaneous injection and the results strongly support the specific predictions of the Unified Theory.

Crystallizing Membrane Proteins in the Lipidic Mesophase. Experience with Human Prostaglandin E2 Synthase 1 and an Evolving Strategy.

PubMed

Li, Dianfan; Howe, Nicole; Dukkipati, Abhiram; Shah, Syed T A; Bax, Benjamin D; Edge, Colin; Bridges, Angela; Hardwicke, Phil; Singh, Onkar M P; Giblin, Ged; Pautsch, Alexander; Pfau, Roland; Schnapp, Gisela; Wang, Meitian; Olieric, Vincent; Caffrey, Martin

2014-04-02

The lipidic mesophase or in meso method for crystallizing membrane proteins has several high profile targets to its credit and is growing in popularity. Despite its success, the method is in its infancy as far as rational crystallogenesis is concerned. Consequently, significant time, effort, and resources are still required to generate structure-grade crystals, especially with a new target type. Therefore, a need exists for crystallogenesis protocols that are effective with a broad range of membrane protein types. Recently, a strategy for crystallizing a prokaryotic α-helical membrane protein, diacylglycerol kinase (DgkA), by the in meso method was reported (Cryst. Growth. Des.2013, 14, 2846-2857). Here, we describe its application to the human α-helical microsomal prostaglandin E2 synthase 1 (mPGES1). While the DgkA strategy proved useful, significant modifications were needed to generate structure-quality crystals of this important therapeutic target. These included protein engineering, using an additive phospholipid in the hosting mesophase, performing multiple rounds of salt screening, and carrying out trials at 4 °C in the presence of a tight binding ligand. The crystallization strategy detailed here should prove useful for generating structures of other integral membrane proteins by the in meso method.

Synthesis, spectral, and structural studies of porphyrins having sterically hindered [η(5)-CpCo(η(4)-C4Ph4)] cobalt sandwich units at the meso positions.

PubMed

Keshav, Karunesh; Kumar, Dheeraj; Elias, Anil J

2013-11-04

Synthesis, spectral, and structural studies of the first examples of porphyrins substituted at the meso positions with sterically hindered η(5)-CpCo(η(4)-C4Ph4) cobalt sandwich units are described. The novel dipyrromethane derived cobalt sandwich compound {η(5)-[(C4H4N)2CH]C5H4}Co(η(4)-C4Ph4) 1, as well as its parent aldehyde, η(5)-[C5H4(CHO)]Co(η(4)-C4Ph4), were used in the synthesis of porphyrins having one or two η(5)-CpCo(η(4)-C4Ph4) groups at their meso positions. 1,9-Diformyldipyrromethane derived η(5)-CpCo(η(4)-C4Ph4) 2 was synthesized using dipyrromethane 1 under Vilsmeier conditions. A reaction of 2 with unsubstituted dipyrromethane under basic conditions in the presence of Pd(C6H5CN)2Cl2 yielded an A-type palladium coordinated porphyrin 3 [where A = η(5)-CpCo(η(4)-C4Ph4)]. A similar reaction of 2 with meso aryl and ferrocenyl-substituted dipyrromethanes yielded trans-AB type palladium coordinated porphyrins 4-6 [where A = η(5)-CpCo(η(4)-C4Ph4) and B = 4-tert-butylphenyl 4, ferrocenyl 5, and pentafluorophenyl 6]. Reactions of 2 with 5-ferrocenyl dipyrromethane under the same reaction conditions in the presence of Ni(acac)2 and Zn(OAc)2 gave the trimetallic nickel(II) and zinc(II) complexed trans-AB type porphyrins 7 and 8 having both cobalt and iron sandwich units at the meso positions. Crystal structure of the Pd(II) porphyrin 5 and nickel(II) porphyrin 7 showed nonplanar structures having distinct ruffle type distortion of the porphyrin ring. Demetalation of the zinc(II) trans-AB type porphyrin 8 in the presence of trifluoroacetic acid gave the metal free base porphyrin 9. Reactions of the cobalt sandwich aldehyde [(η(5)-C5H4(CHO)]Co(η(4)-C4Ph4) with sterically hindered dipyrromethane derivatives under acid-catalyzed condensation reactions gave trans-A2B2 type porphyrins [where A = η(5)-CpCo(η(4)-C4Ph4) and B = pentafluorophenyl, 10 mesityl 11]. In contrast, reactions of [η(5)-C5H4(CHO)]Co(η(4)-C4Ph4) with sterically unhindered meso-4-tert-butylphenyl dipyrromethane resulted in both AB3 12 and cis-A2B2 13 type porphyrins [where A = η(5)-CpCo(η(4)-C4Ph4) and B = (4-tert-butylphenyl] as a result of scrambling. The new porphyrin derivatives have been structurally characterized, and their spectral and electrochemical features were determined.

Epidermal differentiation during ontogeny and after hatching in the snake Liasis fuscus (Pythonidae, Serpentes, Reptilia), with emphasis on the formation of the shedding complex.

PubMed

Alibardi, L; Thompson, M B

2003-04-01

Differentiation and localization of keratin in the epidermis during embryonic development and up to 3 months posthatching in the Australian water python, Liasis fuscus, was studied by ultrastructural and immunocytochemical methods. Scales arise from dome-like folds in the skin that produce tightly imbricating scales. The dermis of these scales is completely differentiated before any epidermal differentiation begins, with a loose dermis made of mesenchymal cells beneath the differentiating outer scale surface. At this stage (33) the embryo is still unpigmented and two layers of suprabasal cells contain abundant glycogen. At Stage 34 (beginning of pigmentation) the first layers of cells beneath the bilayered periderm (presumptive clear and oberhautchen layers) have not yet formed a shedding complex, within which prehatching shedding takes place. At Stage 35 the shedding complex, consisting of the clear and oberhautchen layers, is discernible. The clear layer contains a fine fibrous network that faces the underlying oberhautchen, where the spinulae initially contain a core of fibrous material and small beta-keratin packets. Differentiation continues at Stage 36 when the beta-layer forms and beta-keratin packets are deposited both on the fibrous core of the oberhautchen and within beta-cells. Mesos cells are produced from the germinal layer but remain undifferentiated. At Stage 37, before hatching, the beta-layer is compact, the mesos layer contains mesos granules, and cells of the alpha-layer are present but are not yet keratinized. They are still only partially differentiated a few hours after hatching, when a new shedding complex is forming underneath. Using antibodies against chick scale beta-keratin resolved at high magnification with immunofluorescent or immunogold conjugates, we offer the first molecular confirmation that in snakes only the oberhautchen component of the shedding complex and the underlying beta cells contain beta-keratin. Initially, there is little immunoreactivity in the small beta-packets of the oberhautchen, but it increases after fusion with the underlying cells to produce the syncytial beta layer. The beta-keratin packets coalesce with the tonofilaments, including those attached to desmosomes, which rapidly disappear in both oberhautchen and beta-cells as differentiation progresses. The labeling is low to absent in forming mesos-cells beneath the beta-layer. This study further supports the hypothesis that the shedding complex in lepidosaurian reptiles evolved after there was a segregation between alpha-keratogenic cells from beta-keratogenic cells during epidermal renewal. Copyright 2003 Wiley-Liss, Inc.

Seven 3d-4f coordination polymers of macrocyclic oxamide with polycarboxylates: Syntheses, crystal structures and magnetic properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xin, Na; Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education; Tianjin Key Laboratory of Structure and Performance for Functional Molecules

2016-11-15

Seven new 3d–4f heterometallic coordination polymers, [Ln(CuL){sub 2}(Hbtca)(btca)(H{sub 2}O)]·2H{sub 2}O (Ln = Tb{sup III}1, Pr{sup III}2, Sm{sup III}3, Eu{sup III}4, Yb{sup III}5), [Nd(NiL)(nip)(Rnip)]·0·25H{sub 2}O·0.25CH{sub 3}OH (R= 0.6CH{sub 3}, 0.4H) 6 and [Nd{sub 2}(NiL)(nip){sub 3}(H{sub 2}O)]·2H{sub 2}O 7(CuL or NiL, H{sub 2}L = 2, 3-dioxo-5, 6, 14, 15-dibenzo-1, 4, 8, 12-tetraazacyclo-pentadeca-7, 13-dien; H{sub 2}btca = benzotriazole-5-carboxylic acid; H{sub 2}nip = 5-nitroisophthalic acid) have been synthesized by a solvothermal method and characterized by single-crystal X-ray diffraction. Complexes 1–5 exhibit a double-strand meso-helical chain structures formed by [Ln{sup III}Cu{sup II}{sub 2}] units via the oxamide and benzotriazole-5-carboxylate bridges, while complex 6 exhibits amore » four-strand meso-helical chain formed by NdNi unit via the oxamide and 5-nitroisophthalate bridges. Complex 7 consists of a 2D layer framework formed by four-strand meso-helical chain via the nip{sup 2−} bridges. Moreover, the magnetic properties of them were investigated, and the best-fit analysis of χ{sub M}T versus T show that the anisotropic contribution of Ln(III) ions (arising from the spin-orbit coupling or the crystal field perturbation) dominates (weak exchange limit) in these complexes(for 3, λ = 214.6 cm{sup −1}, zj’ = −0.33 cm{sup −1}, g{sub av} = 1.94; for 5, Δ = 6.98 cm{sup −1}, zj’ = 1.53 cm{sup −1}, g{sub av} = 1.85). - Graphical-abstract: Seven novel oxamido-bridged 3d-4f heterometallic coordination polymers with benzotriazole-5-carboxylate or 5-nitroisophthalate co-ligands under solvothermal reaction conditions. Polymers 1–7 hold 1D or 2D framework structure, viz., double-strand meso-helical chain of 1–5, four-strand meso-helical chain of 6, and 2D net of 7 consisting of four-strand meso-helical chain. Moreover, the temperature dependences of magnetic susceptibilities of compounds 1–7 were also studied.« less

Techniques and resources for storm-scale numerical weather prediction

NASA Technical Reports Server (NTRS)

Droegemeier, Kelvin; Grell, Georg; Doyle, James; Soong, Su-Tzai; Skamarock, William; Bacon, David; Staniforth, Andrew; Crook, Andrew; Wilhelmson, Robert

1993-01-01

The topics discussed include the following: multiscale application of the 5th-generation PSU/NCAR mesoscale model, the coupling of nonhydrostatic atmospheric and hydrostatic ocean models for air-sea interaction studies; a numerical simulation of cloud formation over complex topography; adaptive grid simulations of convection; an unstructured grid, nonhydrostatic meso/cloud scale model; efficient mesoscale modeling for multiple scales using variable resolution; initialization of cloud-scale models with Doppler radar data; and making effective use of future computing architectures, networks, and visualization software.

Influence of surface modification of halloysite nanotubes on their dispersion in epoxy matrix: Mesoscopic DPD simulation

NASA Astrophysics Data System (ADS)

Komarov, P.; Markina, A.; Ivanov, V.

2016-06-01

The problems of constructing of a meso-scale model of composites based on polymers and aluminosilicate nanotubes for prediction of the filler's spatial distribution at early stages of material formation have been considered. As a test system for the polymer matrix, the mixture of 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate as epoxy resin monomers and 4-methylhexahydrophthalic anhydride as curing agent has been used. It is shown that the structure of a mixture of uncured epoxy resin and nanotubes is (mainly) determined by the surface functionalization of nanotubes. The results indicate that only nanotubes with maximum functionalization can preserve a uniform distribution in space.

Bioretention Systems: Partial Factorial Designs for Nitrate Removal

EPA Science Inventory

Changes in nutrient loadings are monitored by introducing captured stormwater runoff into eight outdoor rain gardens at EPA’s Urban Water Research Facility in Edison, New Jersey scaled for residential and urban landscapes. The partial factorial design includes non-vegetated meso...

Nanoscale Morphology to Macroscopic Performance in Ultra High Molecular Weight Polyethylene Fibers

NASA Astrophysics Data System (ADS)

McDaniel, Preston B.

Ultra high molecular weight polyethylene (UHMWPE) fibers are increasingly used in high -performance applications where strength, stiffness, and the ability to dissipate energy are of critical importance. Despite their use in a variety of applications, the influence of morphological features at the meso/nanoscale on the macroscopic performance of the fibers has not been well understood. There is particular interest in gaining a better understanding of the nanoscale structure-property relationships in UHMWPE fibers used in ballistics applications. In order to accurately model and predict failure in the fiber, a more complete understanding of the complex load pathways that dictate the ways in which load is transferred through the fiber, across interfaces and length scales is required. The goal of the work discussed herein is to identify key meso/nanostructural features evolved in high performance fibers and determine how these features influence the performance of the fiber through a variety of different loading mechanisms. The important structural features in high-performance UHMWPE fibers are first identified through examination of the meso/nanostructure of a series of fibers with different processing conditions. This is achieved primarily through the use of wide-angle x-ray diffraction (WAXD) and atomic force microscopy (AFM). Analysis of AFM images and WAXD data allows identification and quantifications of important structural features at these length scales. Key meso/nanostructural features are then examined with respect to their influence on the transverse compression behavior of single fibers. Through post-mortem AFM analysis of samples at incremental compressive strains, the evolution of damage is examined and compared with macroscopic fiber mechanical response. It was found that collapse of mesoscale voids, followed by nanoscale fibrillation and reorganization of a fibrillar network has a significant influence on the mechanical response of the fiber. Through this work, the importance of nanoscale fibril adhesive interactions is highlighted. However, very little information exists in the literature as to the nature and magnitude of these interactions. Examination of nanoscale fibrillar adhesive interactions is experimentally difficult, and necessitated the development of an AFM based nanoscale splitting technique to quantify the interactions between fibrils. Through analysis of split geometry and careful partitioning of energies, the adhesive energy between fibrils in UHMWPE fibers are determined. The calculated average adhesive energies are significantly larger than the estimated energy due to van der Waals interactions, suggesting that there are physical connections (e.g., tie chains, tie fibrils, and lamellar crystalline bridges) that influence the interactions between fibrils. The interactions identified through this work are believed to be responsible for the creation of load pathways across fibril interfaces where load may be translated through the fiber in tension, compression, and shear. Finally, the nature of the mesoscale fibrillar network is explored through the development of a variable angle, single fiber peel test. This peel test enables the quantification of Mode I and Mode II peel energies. The modes of deformation observed in the peel test are representative of the mechanisms experienced during tensile and transverse compression loading. The quantification of peel energies in both Mode I and Mode II failure highlight the importance of the fibrillar network as a key mechanism for the translation of load through the fiber. In both modes of failure, the fibril network acts as a framework for the orientation and subsequent failure of nanoscale fibrils.

Brugga basin's TACD Model Adaptation to current GIS PCRaster 4.1

NASA Astrophysics Data System (ADS)

Lopez Rozo, Nicolas Antonio; Corzo Perez, Gerald Augusto; Santos Granados, Germán Ricardo

2017-04-01

The process-oriented catchment model TACD (Tracer-Aided Catchment model - Distributed) was developed in the Brugga Basin (Dark Forest, Germany) with a modular structure in the Geographic Information System PCRaster Version 2, in order to dynamically model the natural processes of a complex Basin, such as rainfall, air temperature, solar radiation, evapotranspiration and flow routing among others. Further research and application on this model has been done, such as adapting other meso-scaled basins and adding erosion processes in the hydrological model. However, TACD model is computationally intensive. This has made it not efficient on large and well discretized river basins. Aswell, the current version is not compatible with latest PCRaster Version 4.1, which offers new capabilities on 64-bit hardware architecture, hydraulic calculation improvements, in maps creation, some error and bug fixes. The current work studied and adapted TACD model into the latest GIS PCRaster Version 4.1. This was done by editing the original scripts, replacing deprecated functionalities without losing correctness of the TACD model. The correctness of the adapted TACD model was verified by using the original study case of the Brugga Basin and comparing the adapted model results with the original model results by Stefan Roser in 2001. Small differences were found due to the fact that some hydraulic and hydrological routines were optimized since version 2 of GIS PCRaster. Therefore, the hydraulic and hydrological processes are well represented. With this new working model, further research and development on current topics like uncertainty analysis, GCM downscaling techniques and spatio-temporal modelling are encouraged.

Electrically conducting porphyrin and porphyrin-fullerene electropolymers

DOEpatents

Gust, Jr., John Devens; Liddell, Paul Anthony; Gervaldo, Miguel Andres; Bridgewater, James Ward; Brennan, Bradley James; Moore, Thomas Andrew; Moore, Ana Lorenzelli

2014-03-11

Compounds with aryl ring(s) at porphyrin meso position(s) bearing an amino group in position 4 relative to the porphyrin macrocycle, and at least one unsubstituted 5 (hydrogen-bearing) meso position with the 10-, 15-, and/or 20-relationship to the aryl ring bearing the amino group, and metal complexes thereof, feature broad spectral absorption throughout the visible region. These compounds are electropolymerized to form electrically conducting porphyrin and porphyrin-fullerene polymers that are useful in photovoltaic applications. The structure of one such electrically conducting porphyrin polymer is shown below. ##STR00001##

Multi-scale Multi-mechanism Design of Tough Hydrogels: Building Dissipation into Stretchy Networks

PubMed Central

Zhao, Xuanhe

2014-01-01

As swollen polymer networks in water, hydrogels are usually brittle. However, hydrogels with high toughness play critical roles in many plant and animal tissues as well as in diverse engineering applications. Here we review the intrinsic mechanisms of a wide variety of tough hydrogels developed over past few decades. We show that tough hydrogels generally possess mechanisms to dissipate substantial mechanical energy but still maintain high elasticity under deformation. The integrations and interactions of different mechanisms for dissipating energy and maintaining elasticity are essential to the design of tough hydrogels. A matrix that combines various mechanisms is constructed for the first time to guide the design of next-generation tough hydrogels. We further highlight that a particularly promising strategy for the design is to implement multiple mechanisms across multiple length scales into nano-, micro-, meso-, and macro-structures of hydrogels. PMID:24834901

Synthesis, characterization and antimicrobial activity of novel platinum(IV) and palladium(II) complexes with meso-1,2-diphenyl-ethylenediamine-N,N‧-di-3-propanoic acid - Crystal structure of H2-1,2-dpheddp·2HCl·H2O

NASA Astrophysics Data System (ADS)

Radić, Gordana P.; Glođović, Verica V.; Ratković, Zoran R.; Novaković, Slađana B.; Garcia-Granda, Santiago; Roces, Laura; Menéndez-Taboada, Laura; Radojević, Ivana D.; Stefanović, Olgica D.; Čomić, Ljiljana R.; Trifunović, Srećko R.

2012-12-01

In the reaction of meso-1,2-diphenyl-ethylenediamine (1,2-dphen) with neutralized 3-chlor-propanoic acid, the new linear tetradentate edda-like ligand (edda = ethylenediamine-N,N'-diacetic ion) meso-1,2-diphenyl-ethylenediamine-N,N'-di-3-propanoic acid dihydrochloride monohydrate (H2-1,2-dpheddp·2HCl·H2O) was prepared. The corresponding platinum(IV) complex, s-cis-dichlorido-(meso-1,2-diphenyl-ethylenediamine-N,N'-di-3-propanoate)-platinum(IV) ([PtCl2(1,2-dpheddp)]) was synthesized by heating potassium-hexachloridoplatinate(IV) and H2-1,2-dpheddp·2HCl·H2O on steam bath for 12 h with neutralization by means of lithium-hydroxide. The palladium(II) complex, cis-dichlorido-(meso-1,2-diphenyl-ethylenediamine-N,N'-di-3-propanoate)-palladium(II) ([PdCl2(1,2-dpheddp)]) was obtained in the similar way using potassium-tetrachloridopalladate(II), H2-1,2-dpheddp·2HCl·H2O and lithium-hydroxide. The compounds were characterized by elemental analysis and infrared spectroscopy. The spectroscopically predicted structure of the synthesized tetradentate ligand was confirmed by X-ray analysis of the H2-1,2-dpheddp·2HCl·H2O. Antimicrobial activity of the ligand and corresponding palladium(II) and platinum(IV) complexes is investigated against 25 species of microorganisms. Testing is preformed by microdilution method and minimum inhibitory concentrations (MIC) and minimum microbicidal concentration (MMC) have been determined. The difference between antimicrobial activity of the ligand and corresponding platinum(IV) and palladium(II) complex is noticed and, in general, palladium(II) complex was the most active.

Mining the modular structure of protein interaction networks.

PubMed

Berenstein, Ariel José; Piñero, Janet; Furlong, Laura Inés; Chernomoretz, Ariel

2015-01-01

Cluster-based descriptions of biological networks have received much attention in recent years fostered by accumulated evidence of the existence of meaningful correlations between topological network clusters and biological functional modules. Several well-performing clustering algorithms exist to infer topological network partitions. However, due to respective technical idiosyncrasies they might produce dissimilar modular decompositions of a given network. In this contribution, we aimed to analyze how alternative modular descriptions could condition the outcome of follow-up network biology analysis. We considered a human protein interaction network and two paradigmatic cluster recognition algorithms, namely: the Clauset-Newman-Moore and the infomap procedures. We analyzed to what extent both methodologies yielded different results in terms of granularity and biological congruency. In addition, taking into account Guimera's cartographic role characterization of network nodes, we explored how the adoption of a given clustering methodology impinged on the ability to highlight relevant network meso-scale connectivity patterns. As a case study we considered a set of aging related proteins and showed that only the high-resolution modular description provided by infomap, could unveil statistically significant associations between them and inter/intra modular cartographic features. Besides reporting novel biological insights that could be gained from the discovered associations, our contribution warns against possible technical concerns that might affect the tools used to mine for interaction patterns in network biology studies. In particular our results suggested that sub-optimal partitions from the strict point of view of their modularity levels might still be worth being analyzed when meso-scale features were to be explored in connection with external source of biological knowledge.

Design and development of surface rainfall forecast products on GRAPES_MESO model

NASA Astrophysics Data System (ADS)

Zhili, Liu

2016-04-01

In this paper, we designed and developed the surface rainfall forecast products using medium scale GRAPES_MESO model precipitation forecast products. The horizontal resolution of GRAPES_MESO model is 10km*10km, the number of Grids points is 751*501, vertical levels is 26, the range is 70°E－145.15°E, 15°N－64.35 °N. We divided the basin into 7 major watersheds. Each watersheds was divided into a number of sub regions. There were 95 sub regions in all. Tyson polygon method is adopted in the calculation of surface rainfall. We used 24 hours forecast precipitation data of GRAPES_MESO model to calculate the surface rainfall. According to the site of information and boundary information of the 95 sub regions, the forecast surface rainfall of each sub regions was calculated. We can provide real-time surface rainfall forecast products every day. We used the method of fuzzy evaluation to carry out a preliminary test and verify about the surface rainfall forecast product. Results shows that the fuzzy score of heavy rain, rainstorm and downpour level forecast rainfall were higher, the fuzzy score of light rain level was lower. The forecast effect of heavy rain, rainstorm and downpour level surface rainfall were better. The rate of missing and empty forecast of light rainfall level surface rainfall were higher, so it's fuzzy score were lower.

Surface current patterns suggested by suspended sediment distribution over the outer continental margin, Bering Sea

USGS Publications Warehouse

Karl, Herman A.; Carlson, P.R.

1987-01-01

Samples of total suspended matter (TSM) were collected at the surface over the northern outer continental margin of the Bering Sea during the summers of 1980 and 1981. Volume concentrations of surface TSM averaged 0.6 and 1.1 mg l-1 for 1980 and 1981, respectively. Organic matter, largely plankton, made up about 65% of the near-surface TSM for both years. Distributions of TSM suggested that shelf circulation patterns were characterized either by meso- and large- scale eddies or by cross-shelf components of flow superimposed on a general northwesterly net drift. These patterns may be caused by large submarine canyons which dominate the physiography of this part of the Bering Sea continental margin. ?? 1987.

Supersonic Combustion Ramjet Research

DTIC Science & Technology

2012-08-01

was in collaboration with Prof. R. Bowersox (Texas A&M University) and Dr. K. Kobayashi ( Japanese Aerospace Exploration Agency, JAXA). 4.2 Ignition... cinema stereoscopic PIV system for the measurement of micro- and meso-scale turbulent premixed flame dynamics,” Paper B13, 5th US Combustion

Large-scale geomorphology: Classical concepts reconciled and integrated with contemporary ideas via a surface processes model

NASA Astrophysics Data System (ADS)

Kooi, Henk; Beaumont, Christopher

1996-02-01

Linear systems analysis is used to investigate the response of a surface processes model (SPM) to tectonic forcing. The SPM calculates subcontinental scale denudational landscape evolution on geological timescales (1 to hundreds of million years) as the result of simultaneous hillslope transport, modeled by diffusion, and fluvial transport, modeled by advection and reaction. The tectonically forced SPM accommodates the large-scale behavior envisaged in classical and contemporary conceptual geomorphic models and provides a framework for their integration and unification. The following three model scales are considered: micro-, meso-, and macroscale. The concepts of dynamic equilibrium and grade are quantified at the microscale for segments of uniform gradient subject to tectonic uplift. At the larger meso- and macroscales (which represent individual interfluves and landscapes including a number of drainage basins, respectively) the system response to tectonic forcing is linear for uplift geometries that are symmetric with respect to baselevel and which impose a fully integrated drainage to baselevel. For these linear models the response time and the transfer function as a function of scale characterize the model behavior. Numerical experiments show that the styles of landscape evolution depend critically on the timescales of the tectonic processes in relation to the response time of the landscape. When tectonic timescales are much longer than the landscape response time, the resulting dynamic equilibrium landscapes correspond to those envisaged by Hack (1960). When tectonic timescales are of the same order as the landscape response time and when tectonic variations take the form of pulses (much shorter than the response time), evolving landscapes conform to the Penck type (1972) and to the Davis (1889, 1899) and King (1953, 1962) type frameworks, respectively. The behavior of the SPM highlights the importance of phase shifts or delays of the landform response and sediment yield in relation to the tectonic forcing. Finally, nonlinear behavior resulting from more general uplift geometries is discussed. A number of model experiments illustrate the importance of "fundamental form," which is an expression of the conformity of antecedent topography with the current tectonic regime. Lack of conformity leads to models that exhibit internal thresholds and a complex response.

Modeling Near-Crack-Tip Plasticity from Nano- to Micro-Scales

NASA Technical Reports Server (NTRS)

Glaessgen, Edward H.; Saether, Erik; Hochhalter, Jake D.; Yamakov, Vesselin I.

2010-01-01

Several efforts that are aimed at understanding the plastic deformation mechanisms related to crack propagation at the nano-, meso- and micro-length scales including atomistic simulation, discrete dislocation plasticity, strain gradient plasticity and crystal plasticity are discussed. The paper focuses on discussion of newly developed methodologies and their application to understanding damage processes in aluminum and its alloys. Examination of plastic mechanisms as a function of increasing length scale illustrates increasingly complex phenomena governing plasticity

Study of satellite retrieved aerosol optical depth spatial resolution effect on particulate matter concentration prediction

NASA Astrophysics Data System (ADS)

Strandgren, J.; Mei, L.; Vountas, M.; Burrows, J. P.; Lyapustin, A.; Wang, Y.

2014-10-01

The Aerosol Optical Depth (AOD) spatial resolution effect is investigated for the linear correlation between satellite retrieved AOD and ground level particulate matter concentrations (PM2.5). The Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm was developed for the Moderate Resolution Imaging Spectroradiometer (MODIS) for obtaining AOD with a high spatial resolution of 1 km and provides a good dataset for the study of the AOD spatial resolution effect on the particulate matter concentration prediction. 946 Environmental Protection Agency (EPA) ground monitoring stations across the contiguous US have been used to investigate the linear correlation between AOD and PM2.5 using AOD at different spatial resolutions (1, 3 and 10 km) and for different spatial scales (urban scale, meso-scale and continental scale). The main conclusions are: (1) for both urban, meso- and continental scale the correlation between PM2.5 and AOD increased significantly with increasing spatial resolution of the AOD, (2) the correlation between AOD and PM2.5 decreased significantly as the scale of study region increased for the eastern part of the US while vice versa for the western part of the US, (3) the correlation between PM2.5 and AOD is much more stable and better over the eastern part of the US compared to western part due to the surface characteristics and atmospheric conditions like the fine mode fraction.

Storm Prediction Center Convective Outlooks

Science.gov Websites

Current Watches Meso. Discussions Conv. Outlooks Tstm. Outlooks Fire Wx Outlooks XML logo RSS Feeds E-Mail : Retrieve Outlooks Weather Topics: Watches, Mesoscale Discussions, Outlooks, Fire Weather, All Products

Convection Constraints and Current Sheet Thinning During the Substorm Growth Phase

NASA Astrophysics Data System (ADS)

Otto, A.; Hsieh, M.

2012-12-01

A typical property during the growth phase of geomagnetic substorms is the thinning of the near-Earth current sheet, most pronounced in the region between 6 and 15 RE. We propose that the cause for this current sheet thinning is convection from the midnight tail region to the dayside to replenish magnetospheric magnetic flux that is eroded at the dayside as a result of dayside reconnection. Slow (adiabatic) convection from the near-Earth tail region toward the dayside must conserve the entropy on magnetic field lines. This constraint prohibits a source of magnetic flux from a region further out in the magnetotail. Thus the near-Earth tail region is increasingly depleted of magnetic flux (the Erickson and Wolf [1980] problem) with entropy matching that of flux tubes that are eroded on the dayside. It is proposed that the magnetic flux depletion in the near-Earth tail forces the formation of thin current layers. The process is illustrated and examined by three-dimensional meso-scale MHD simulations. It is shown that the simulations yield a time scale, location, and other general characteristics of the current sheet evolution consistent with observations during the substorm growth phase. The developing thin current sheet is easily destabilized and can undergo localized reconnection events. We present properties of the thinning current sheet, the associated entropy evolution, examples of localized reconnection onset and we discuss the dependence of this process on external parameters such the global reconnection rate.

Apatite and sodalite based glass-bonded waste forms for immobilization of 129I and mixed halide radioactive wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goel, Ashutosh; McCloy, John S.; Riley, Brian J.

The goal of the project was to utilize the knowledge accumulated by the team, in working with minerals for chloride wastes and biological apatites, toward the development of advanced waste forms for immobilizing 129I and mixed-halide wastes. Based on our knowledge, experience, and thorough literature review, we had selected two minerals with different crystal structures and potential for high chemical durability, sodalite and CaP/PbV-apatite, to form the basis of this project. The focus of the proposed effort was towards: (i) low temperature synthesis of proposed minerals (iodine containing sodalite and apatite) leading to the development of monolithic waste forms, (ii)more » development of a fundamental understanding of the atomic-scale to meso-scale mechanisms of radionuclide incorporation in them, and (iii) understanding of the mechanism of their chemical corrosion, alteration mechanism, and rates. The proposed work was divided into four broad sections. deliverables. 1. Synthesis of materials 2. Materials structural and thermal characterization 3. Design of glass compositions and synthesis glass-bonded minerals, and 4. Chemical durability testing of materials.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Xiao; Martínez-González, José A.; Hernández-Ortiz, Juan P.

Liquid crystal blue phases (BPs) are highly ordered at two levels. Molecules exhibit orientational order at nanometer length scales, while chirality leads to ordered arrays of doubletwisted cylinders over micrometer scales. Past studies of polycrystalline BPs were challenged by grain boundaries between randomly oriented crystalline nanodomains. Here, the nucleation of BPs is controlled with considerable precision by relying on chemically nano-patterned surfaces, leading to macroscopic single-crystal BP specimens where the dynamics of meso-crystal formation can be directly observed. Theory and experiments show that transitions between two BPs having a different network structure proceed through local re-organization of the crystalline array,more » without diffusion of the double twisted cylinders. In solid crystals, martensitic transformations between crystal structures involve the concerted motion of a few atoms, without diffusion. The transformation between BPs, where crystal features arise in the sub-micron regime, is found to be martensitic in nature, with the diffusion-less feature associated to the collective behavior of the double twist cylinders. Single-crystal BPs are shown to offer fertile grounds for the study of directed crystal-nucleation and the controlled growth of soft matter.« less

Handling of subpixel structures in the application of satellite derived irradiance data for solar energy system analysis - a review

NASA Astrophysics Data System (ADS)

Beyer, Hans Georg

2016-04-01

With the increasing availability of satellite derived irradiance information, this type of data set is more and more in use for the design and operation of solar energy systems, most notably PV- and CSP-systems. By this, the need for data measured on-site is reduced. However, due to basic limitations of the satellite-derived data, several requirements put by the intended application cannot be coped with this data type directly. Traw satellite information has to be enhanced in both space and time resolution by additional information to be fully applicable for all aspects of the modelling od solar energy systems. To cope with this problem, several individual and collaborative projects had been performed in the recent years or are ongoing. Approaches are on one hand based on pasting synthesized high-resolution data into the low-resolution original sets. Pre-requite is an appropriate model, validated against real world data. For the case of irradiance data, these models can be extracted either directly from ground measured data sets or from data referring to the cloud situation as gained from the images of sky cameras or from monte -carlo initialized physical models. The current models refer to the spatial structure of the cloud fields. Dynamics are imposed by moving the cloud structures according to a large scale cloud motion vector, either extracted from the dynamics interfered from consecutive satellite images or taken from a meso-scale meteorological model. Dynamic irradiance information is then derived from the cloud field structure and the cloud motion vector. This contribution, which is linked to subtask A - Solar Resource Applications for High Penetration of Solar Technologies - of IEA SHC task 46, will present the different approaches and discuss examples in view of validation, need for auxiliary information and respective general applicability.

Think locally, act locally: detection of small, medium-sized, and large communities in large networks.

PubMed

Jeub, Lucas G S; Balachandran, Prakash; Porter, Mason A; Mucha, Peter J; Mahoney, Michael W

2015-01-01

It is common in the study of networks to investigate intermediate-sized (or "meso-scale") features to try to gain an understanding of network structure and function. For example, numerous algorithms have been developed to try to identify "communities," which are typically construed as sets of nodes with denser connections internally than with the remainder of a network. In this paper, we adopt a complementary perspective that communities are associated with bottlenecks of locally biased dynamical processes that begin at seed sets of nodes, and we employ several different community-identification procedures (using diffusion-based and geodesic-based dynamics) to investigate community quality as a function of community size. Using several empirical and synthetic networks, we identify several distinct scenarios for "size-resolved community structure" that can arise in real (and realistic) networks: (1) the best small groups of nodes can be better than the best large groups (for a given formulation of the idea of a good community); (2) the best small groups can have a quality that is comparable to the best medium-sized and large groups; and (3) the best small groups of nodes can be worse than the best large groups. As we discuss in detail, which of these three cases holds for a given network can make an enormous difference when investigating and making claims about network community structure, and it is important to take this into account to obtain reliable downstream conclusions. Depending on which scenario holds, one may or may not be able to successfully identify "good" communities in a given network (and good communities might not even exist for a given community quality measure), the manner in which different small communities fit together to form meso-scale network structures can be very different, and processes such as viral propagation and information diffusion can exhibit very different dynamics. In addition, our results suggest that, for many large realistic networks, the output of locally biased methods that focus on communities that are centered around a given seed node (or set of seed nodes) might have better conceptual grounding and greater practical utility than the output of global community-detection methods. They also illustrate structural properties that are important to consider in the development of better benchmark networks to test methods for community detection.

The Stability of Outcropping Ocean Eddies

NASA Astrophysics Data System (ADS)

Paldor, N.; Cohen, Y.; Dvorkin, Y.

2017-12-01

In the end of the last century numerous ship-borne observations and linear instability studies have addressed the long life span of meso-scale ocean eddies. These eddies are observed to persist in the ocean for periods of 2-3 years with little deformation. As eddy instabilities occur because Rossby waves in the surrounding (assumed motionless) ocean interact with various waves in the eddy itself, the stability was attributed to some eddy structure that hinders such wave-wave interactions. However, instabilities with growthrates of the order of the inertial period were found in various multilayer models including hypothesized structures and several observed eddy structures. A solution to the difference between instability theory and observed stability was ultimately suggested by relaxing the assumption of a motionless ocean that surrounds the eddy and prescribing the mean flow in the ocean such that it counterbalances the depth changes imposed by the eddy while maintaining a constant PV-ocean. This hypothesis was successfully applied to Gaussian eddies for mathematical simplicity. Yet, the Gaussian eddy has no surface front - thus avoiding instabilities that involve frontal waves - and it disagrees with observation that clearly show that most eddies have surface fronts. Here the constant PV ocean hypothesis is applied to two frontal eddies: constant PV-eddies and solidly rotating eddy. A complete account of the mean flow of the coupled eddy-ocean system is analyzed using a canonical formulation of the gradient balance. The phase speeds of waves in the eddy-ocean system are computed by a shooting method. Both eddies are found to be unstable in motionless ocean, yet in a constant PV-ocean no instabilities are found using the exact same numerical search. While many eddy structures can be hypothesized there are only a handful of physical mechanisms for instability and in these eddies the assumed constant PV-ocean negates many of these physical mechanisms for instability. This implies that meso-scale eddies should be stable in a constant PV ocean, regardless to their structure, which is not precisely one of the above mentioned. This theory stimulates observations of the ocean under the eddies. To maintain the uniform PV value, relative vorticity must develop in the ocean under the eddy as it moves in the ocean.

Think locally, act locally: Detection of small, medium-sized, and large communities in large networks

NASA Astrophysics Data System (ADS)

Jeub, Lucas G. S.; Balachandran, Prakash; Porter, Mason A.; Mucha, Peter J.; Mahoney, Michael W.

2015-01-01

It is common in the study of networks to investigate intermediate-sized (or "meso-scale") features to try to gain an understanding of network structure and function. For example, numerous algorithms have been developed to try to identify "communities," which are typically construed as sets of nodes with denser connections internally than with the remainder of a network. In this paper, we adopt a complementary perspective that communities are associated with bottlenecks of locally biased dynamical processes that begin at seed sets of nodes, and we employ several different community-identification procedures (using diffusion-based and geodesic-based dynamics) to investigate community quality as a function of community size. Using several empirical and synthetic networks, we identify several distinct scenarios for "size-resolved community structure" that can arise in real (and realistic) networks: (1) the best small groups of nodes can be better than the best large groups (for a given formulation of the idea of a good community); (2) the best small groups can have a quality that is comparable to the best medium-sized and large groups; and (3) the best small groups of nodes can be worse than the best large groups. As we discuss in detail, which of these three cases holds for a given network can make an enormous difference when investigating and making claims about network community structure, and it is important to take this into account to obtain reliable downstream conclusions. Depending on which scenario holds, one may or may not be able to successfully identify "good" communities in a given network (and good communities might not even exist for a given community quality measure), the manner in which different small communities fit together to form meso-scale network structures can be very different, and processes such as viral propagation and information diffusion can exhibit very different dynamics. In addition, our results suggest that, for many large realistic networks, the output of locally biased methods that focus on communities that are centered around a given seed node (or set of seed nodes) might have better conceptual grounding and greater practical utility than the output of global community-detection methods. They also illustrate structural properties that are important to consider in the development of better benchmark networks to test methods for community detection.

Comparing methods for assessing the effectiveness of subnational REDD+ initiatives

NASA Astrophysics Data System (ADS)

Bos, Astrid B.; Duchelle, Amy E.; Angelsen, Arild; Avitabile, Valerio; De Sy, Veronique; Herold, Martin; Joseph, Shijo; de Sassi, Claudio; Sills, Erin O.; Sunderlin, William D.; Wunder, Sven

2017-07-01

The central role of forests in climate change mitigation, as recognized in the Paris agreement, makes it increasingly important to develop and test methods for monitoring and evaluating the carbon effectiveness of REDD+. Over the last decade, hundreds of subnational REDD+ initiatives have emerged, presenting an opportunity to pilot and compare different approaches to quantifying impacts on carbon emissions. This study (1) develops a Before-After-Control-Intervention (BACI) method to assess the effectiveness of these REDD+ initiatives; (2) compares the results at the meso (initiative) and micro (village) scales; and (3) compares BACI with the simpler Before-After (BA) results. Our study covers 23 subnational REDD+ initiatives in Brazil, Peru, Cameroon, Tanzania, Indonesia and Vietnam. As a proxy for deforestation, we use annual tree cover loss. We aggregate data into two periods (before and after the start of each initiative). Analysis using control areas (‘control-intervention’) suggests better REDD+ performance, although the effect is more pronounced at the micro than at the meso level. Yet, BACI requires more data than BA, and is subject to possible bias in the before period. Selection of proper control areas is vital, but at either scale is not straightforward. Low absolute deforestation numbers and peak years influence both our BA and BACI results. In principle, BACI is superior, with its potential to effectively control for confounding factors. We conclude that the more local the scale of performance assessment, the more relevant is the use of the BACI approach. For various reasons, we find overall minimal impact of REDD+ in reducing deforestation on the ground thus far. Incorporating results from micro and meso level monitoring into national reporting systems is important, since overall REDD+ impact depends on land use decisions on the ground.

Giant Electrocaloric Effect in Ferroelectrics with Tailored Polaw-Nanostructures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Qiming

2015-06-24

Electrocaloric effect (ECE) is the temperature and/or entropy change in a dielectric material caused by an electric field induced polarization change. Although ECE has been studied since 1930s, the very small ECE observed in earlier studies in bulk materials before 2007 makes it not attractive for practical cooling applications. The objectives of this DOE program are to carry out a systematical scientific research on the entropy change and ECE in polar-dielectrics, especially ferroelectrics based on several fundamental hypotheses and to search for answers on a few scientific questions. Especially, this research program developed a series of polar-dielectric materials with controlledmore » nano- and meso-structures and carried out studies on how these structures affect the polar-ordering, correlations, energy landscapes, and consequently the entropy states at different phases and ECE. The key hypotheses of the program include: (i) Whether a large ECE can be obtained near the ferroelectric-paraelectric (FE-PE) transition in properly designed ferroelectrics which possess large polarization P and large ß (the coefficient in the thermodynamic Landau theory where the Gibbs free energy G = G = G 0+ ½ a P 2 +1/4 b P 4 + 1/6 c P 6 – EP, and a = ß (T-T c), where b,c,ß and Tc are constants)? (ii) What determines/determine ß? Whether a ferroelectric material with built-in disorders, which disrupt the polar-correlations and enabling a large number of local polar-states, such as a properly designed ferroelectric relaxor, can achieve a large ECE? (iii) How to design a ferroelectric material which has flat energy landscape so that the energy barriers for switching among different phases are vanishingly small? What are the necessary conditions to maximize the number of coexisting phases? (iv) How to design ferroelectric materials with a large tunable dielectric response? That is, at zero electric field, the material possesses very low polar-correlation and hence a very small dielectric constant, under the application of electric field, the material develops long range polar-correlation and hence a high dielectric response. Studying and developing these materials will deepen our understanding on the polarization responses in strongly coupled materials and the roles of molecular and nano, meso-, and micro-scale defects and structures on the polarization responses. On the application front, besides ECE, these dielectrics will also have great impact on micro-electronics and communications. (v) The multi-field effect, besides the electric, elastic and even magnetic effects, could be made use of to tune the energy landscape of polar-materials and hence enhance the ECE. Hence the question is what are the suitable material systems to develop and maximize the multi-field effects? (vi) Besides solid dielectric, liquid dielectrics with properly designed molecular structures and dipolar coupling can also exhibit a large ECE near the dipolar order-disorder transition. The study of order-disorder transition and their influence on entropy change and ECE will provide additional avenue to study dielectrics and understand relationship between the polar-ordering and dipolar entropy in dielectrics. (vii) Besides the regular ECE in which applying an electric field will induce dipolar ordering, there are dielectric material systems which can exhibit negative ECE in which the applied field will reduce the dipolar ordering and anomalous ECE in which applying an electric field pulse will generate cooling only. The question is how to control and balance the nano- and meso-scale polar coupling in dielectrics to achieve such effects? ECE in dielectrics provides an interesting and effective avenue to probe the polar-correlation in dielectrics. Thus the study of ECE in polar-dielectrics, besides the application values, will also deepen our understanding of strongly coupled materials systems, phase transitions, and materials systems with nano- and meso-scale disorders. Through the efforts of this DoE program, we have developed understandings for many questions and materials approaches for many hypotheses listed above. The major accomplishments include: (i) The first one to show that a giant ECE can be obtained in bulk materials of ferroelectric P(VDF-TrFE) copolymer, which has a large ß coefficient and high polarization, near FE-PE transition.[1,3,12] (ii) The first who developed the theoretical analyses on the upper bound of dipolar entropy change in polar-materials and the general approach to maximize the coexisting phases with vanishingly small switching fields among the coexisting phases[10,23] Experimental results confirm these theoretical predictions.[24] (iii) The first to show that the relaxor ferroelectrics, due to built-in defects structures at nano- and meso scale, exhibit a giant ECE over a broad temperature range.[1,3,7,14] (iv) The first to show that a large ECE can be obtained near order-disorder transition in dielectric fluids such as liquid crystals with large dielectric anisotropy. Also the study developed a general approach for developing dielectric fluids to achieve a large electric field induced entropy change.[26] (v) We are starting to explore the multi-field effect (multiferroic effect) in nanocomposites in which there exist large dielectric contrasts between the matrix and nanofilelrs and showed that a significantly enhanced ECE compared with polymer matrix.[36] (vi) By facially tuning the nano- and meso-scale dipolar coupling, we are the first to show that an anomalous ECE can be obtained in a relaxor/normal ferroelectric blend.[39] (vii) Introduced and demonstrated that the internal bias field approach can be effective in enhancing the EC response at low electric field. The result is significant since for practical applications, a low applied field is highly desired. (viii) A high sensitivity ECE characterization system has been developed. This program has made major contributions to the advancement of the EC materials and understandings of EC phenomena. To reflect the advancement in the EC materials development and scientific understandings on ECE through in this time period (from Sept. 1, 2007 to May 2015), this final report is written based on the reports complied each year through the program. Some early works on the ECE which were obtained using the indirect method are not included in this report.« less

Storm Prediction Center Storm Reports

Science.gov Websites

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Palliative Care Development in European Care Homes and Nursing Homes: Application of a Typology of Implementation.

PubMed

Froggatt, Katherine; Payne, Sheila; Morbey, Hazel; Edwards, Michaela; Finne-Soveri, Harriet; Gambassi, Giovanni; Pasman, H Roeline; Szczerbińska, Katarzyna; Van den Block, Lieve

2017-06-01

The provision of institutional long-term care for older people varies across Europe reflecting different models of health care delivery. Care for dying residents requires integration of palliative care into current care work, but little is known internationally of the different ways in which palliative care is being implemented in the care home setting. To identify and classify, using a new typology, the variety of different strategic, operational, and organizational activities related to palliative care implementation in care homes across Europe. We undertook a mapping exercise in 29 European countries, using 2 methods of data collection: (1) a survey of country informants, and (2) a review of data from publically available secondary data sources and published research. Through a descriptive and thematic analysis of the survey data, we identified factors that contribute to the development and implementation of palliative care into care homes at different structural levels. From these data, a typology of palliative care implementation for the care home sector was developed and applied to the countries surveyed. We identified 3 levels of palliative care implementation in care homes: macro (national/regional policy, legislation, financial and regulatory drivers), meso (implementation activities, such as education, tools/frameworks, service models, and research), and micro (palliative care service delivery). This typology was applied to data collected from 29 European countries and demonstrates the diversity of palliative care implementation activity across Europe with respect to the scope, type of development, and means of provision. We found that macro and meso factors at 2 levels shape palliative care implementation and provision in care homes at the micro organizational level. Implementation at the meso and micro levels is supported by macro-level engagement, but can happen with limited macro strategic drivers. Ensuring the delivery of consistent and high-quality palliative care in care homes is supported by implementation activity at these 3 levels. Understanding where each country is in terms of activity at these 3 levels (macro, meso, and micro) will allow strategic focus on future implementation work in each country. Copyright © 2017 AMDA – The Society for Post-Acute and Long-Term Care Medicine. Published by Elsevier Inc. All rights reserved.

The Plasmaspheric Role in Coupled Inner Magnetospheric Dynamics

NASA Astrophysics Data System (ADS)

Goldstein, J.

2006-05-01

The plasmasphere is a near-Earth cold, dense, corotating plasma region that plays both passive and active roles in inner magnetospheric coupling. The plasmasphere plays a passive role with respect to electrodynamic coupling associated with enhanced magnetospheric convection; i.e., zero-order plasmaspheric dynamics result from convection. Following extended periods of quiet geomagnetic conditions, the equatorial extent of the plasmasphere can be several Earth radii (RE), with an internal density distribution that contains a great deal of fine-scale (under 0.1 RE) and meso-scale (0.1 to 1 RE) density structure. Enhanced geomagnetic activity causes erosion of the plasmasphere, in which the outer plasma-filled flux tubes are caught up in the convection field and carried sunward, forming plumes of dense plasmaspheric material on the dayside. The electrodynamic coupling between the ring current and ionosphere (leading to shielding and sub-auroral polarization stream, or SAPS) can either reduce or intensify the global convection field that arises from solar-wind-magnetosphere coupling, and the plasmasphere is subject to the variations of this convection. There is also good evidence that ionosphere-thermosphere coupling plays an important role in determination of the convection field during quiet conditions. The plasmasphere plays an active role in determining the global distribution of warmer inner magnetospheric plasmas (ring current and radiation belts), by providing plasma conditions that can favor or discourage the growth of waves such as whistler, chorus, and electromagnetic ion-cyclotron (EMIC) waves, all of which are believed to be crucial in the various acceleration and loss processes that affect warmer particles. Thus, knowledge of the global plasmasphere configuration and composition is critical for understanding and predicting the behavior of the inner magnetosphere.

SPRAYTRAN USER'S GUIDE: A GIS-BASED ATMOSPHERIC SPRAY DROPLET DISPERSION MODELING SYSTEM

EPA Science Inventory

The offsite drift of pesticide from spray operations is an ongoing source of concern. The SPRAY TRANsport (SPRAYTRAN) system, documented in this report, incorporates the near-field spray application model, AGDISP, into a meso-scale atmospheric transport model. The AGDISP model ...

A novel approach for osteocalcin detection by competitive ELISA using porous silicon as a substrate.

PubMed

Rahimi, Fereshteh; Mohammadnejad Arough, Javad; Yaghoobi, Mona; Davoodi, Hadi; Sepehri, Fatemeh; Amirabadizadeh, Masood

2017-11-01

In this study, porous silicon (PSi) was utilized instead of prevalent polystyrene platforms, and its capability in biomolecule screening was examined. Here, two types of porous structure, macroporous silicon (Macro-PSi) and mesoporous silicon (Meso-PSi), were produced on silicon wafers by electrochemical etching using different electrolytes. Moreover, both kinds of fresh and oxidized PSi samples were investigated. Next, osteocalcin as a biomarker of the bone formation process was used as a model biomarker, and the colorimetric detection was performed by competitive enzyme-linked immunosorbent assay (ELISA). Both Macro-PSi and Meso-PSi substrates in the oxidized state, specifically the Meso-porous structure, were reported to have higher surface area to volume ratio, more capacitance of surface-antigen interaction, and more ability to capture antigen in comparison with the prevalent platforms. Moreover, the optical density signal of osteocalcin detected by the ELISA technique was notably higher than the common platforms. Based on the findings of this study, PSi can potentially be used in the ELISA to achieve better results and consequently more sensitivity. A further asset of incorporating such a nanometer structure in the ELISA technique is that the system response to analyte concentration could be maintained by consuming lower monoclonal antibody (or antigen) and consequently reduces the cost of the experiment. © 2016 International Union of Biochemistry and Molecular Biology, Inc.

A smoothed particle hydrodynamics framework for modelling multiphase interactions at meso-scale

NASA Astrophysics Data System (ADS)

Li, Ling; Shen, Luming; Nguyen, Giang D.; El-Zein, Abbas; Maggi, Federico

2018-01-01

A smoothed particle hydrodynamics (SPH) framework is developed for modelling multiphase interactions at meso-scale, including the liquid-solid interaction induced deformation of the solid phase. With an inter-particle force formulation that mimics the inter-atomic force in molecular dynamics, the proposed framework includes the long-range attractions between particles, and more importantly, the short-range repulsive forces to avoid particle clustering and instability problems. Three-dimensional numerical studies have been conducted to demonstrate the capabilities of the proposed framework to quantitatively replicate the surface tension of water, to model the interactions between immiscible liquids and solid, and more importantly, to simultaneously model the deformation of solid and liquid induced by the multiphase interaction. By varying inter-particle potential magnitude, the proposed SPH framework has successfully simulated various wetting properties ranging from hydrophobic to hydrophilic surfaces. The simulation results demonstrate the potential of the proposed framework to genuinely study complex multiphase interactions in wet granular media.

Probabilistic, meso-scale flood loss modelling

NASA Astrophysics Data System (ADS)

Kreibich, Heidi; Botto, Anna; Schröter, Kai; Merz, Bruno

2016-04-01

Flood risk analyses are an important basis for decisions on flood risk management and adaptation. However, such analyses are associated with significant uncertainty, even more if changes in risk due to global change are expected. Although uncertainty analysis and probabilistic approaches have received increased attention during the last years, they are still not standard practice for flood risk assessments and even more for flood loss modelling. State of the art in flood loss modelling is still the use of simple, deterministic approaches like stage-damage functions. Novel probabilistic, multi-variate flood loss models have been developed and validated on the micro-scale using a data-mining approach, namely bagging decision trees (Merz et al. 2013). In this presentation we demonstrate and evaluate the upscaling of the approach to the meso-scale, namely on the basis of land-use units. The model is applied in 19 municipalities which were affected during the 2002 flood by the River Mulde in Saxony, Germany (Botto et al. submitted). The application of bagging decision tree based loss models provide a probability distribution of estimated loss per municipality. Validation is undertaken on the one hand via a comparison with eight deterministic loss models including stage-damage functions as well as multi-variate models. On the other hand the results are compared with official loss data provided by the Saxon Relief Bank (SAB). The results show, that uncertainties of loss estimation remain high. Thus, the significant advantage of this probabilistic flood loss estimation approach is that it inherently provides quantitative information about the uncertainty of the prediction. References: Merz, B.; Kreibich, H.; Lall, U. (2013): Multi-variate flood damage assessment: a tree-based data-mining approach. NHESS, 13(1), 53-64. Botto A, Kreibich H, Merz B, Schröter K (submitted) Probabilistic, multi-variable flood loss modelling on the meso-scale with BT-FLEMO. Risk Analysis.

Dyadic Affective Flexibility and Emotional Inertia in Relation to Youth Psychopathology: An Integrated Model at Two Timescales.

PubMed

Mancini, Kathryn J; Luebbe, Aaron M

2016-06-01

The current review examines characteristics of temporal affective functioning at both the individual and dyadic level. Specifically, the review examines the following three research questions: (1) How are dyadic affective flexibility and emotional inertia operationalized, and are they related to youth psychopathology? (2) How are dyadic affective flexibility and emotional inertia related, and does this relation occur at micro- and meso-timescales? and (3) How do these constructs combine to predict clinical outcomes? Using the Flex3 model of socioemotional flexibility as a frame, the current study proposes that dyadic affective flexibility and emotional inertia are bidirectionally related at micro- and meso-timescales, which yields psychopathological symptoms for youth. Specific future directions for examining individual, dyadic, and cultural characteristics that may influence relations between these constructs and psychopathology are also discussed.

Solid-state electrochemistry on the nanometer and atomic scales: the scanning probe microscopy approach

DOE PAGES

Strelcov, Evgheni; Yang, Sang Mo; Jesse, Stephen; ...

2016-04-21

Energy technologies of the 21st century require an understanding and precise control over ion transport and electrochemistry at all length scales – from single atoms to macroscopic devices. Our short review provides a summary of recent studies dedicated to methods of advanced scanning probe microscopy for probing electrochemical transformations in solids at the meso-, nano- and atomic scales. In this discussion we present the advantages and limitations of several techniques and a wealth of examples highlighting peculiarities of nanoscale electrochemistry.

Solid-state electrochemistry on the nanometer and atomic scales: the scanning probe microscopy approach

PubMed Central

Strelcov, Evgheni; Yang, Sang Mo; Jesse, Stephen; Balke, Nina; Vasudevan, Rama K.; Kalinin, Sergei V.

2016-01-01

Energy technologies of the 21st century require understanding and precise control over ion transport and electrochemistry at all length scales – from single atoms to macroscopic devices. This short review provides a summary of recent works dedicated to methods of advanced scanning probe microscopy for probing electrochemical transformations in solids at the meso-, nano- and atomic scales. Discussion presents advantages and limitations of several techniques and a wealth of examples highlighting peculiarities of nanoscale electrochemistry. PMID:27146961

Membrane-electrode structures for molecular catalysts for use in fuel cells and other electrochemical devices

DOEpatents

Kerr, John B.; Zhu, Xiaobing; Hwang, Gi Suk; Martin, Zulima; He, Qinggang; Driscoll, Peter; Weber, Adam; Clark, Kyle

2016-09-27

Water soluble catalysts, (M)meso-tetra(N-Methyl-4-Pyridyl)Porphinepentachloride (M=Fe, Co, Mn & Cu), have been incorporated into the polymer binder of oxygen reduction cathodes in membrane electrode assemblies used in PEM fuel cells and found to support encouragingly high current densities. The voltages achieved are low compared to commercial platinum catalysts but entirely consistent with the behavior observed in electroanalytical measurements of the homogeneous catalysts. A model of the dynamics of the electrode action has been developed and validated and this allows the MEA electrodes to be optimized for any chemistry that has been demonstrated in solution. It has been shown that improvements to the performance will come from modifications to the structure of the catalyst combined with optimization of the electrode structure and a well-founded pathway to practical non-platinum group metal catalysts exists.

Squid inks-derived nanocarbons with unique ;shell@pearls; structure for high performance supercapacitors

NASA Astrophysics Data System (ADS)

Cheng, Fengli; Liu, Wei; Zhang, Yuan; Wang, Huanlei; Liu, Shuang; Hao, Enchao; Zhao, Shuping; Yang, Hongzhan

2017-06-01

Porous carbons derived from biomass are one current hotspot in exploring advanced electrode materials for supercapacitors. In this work, based on nanoparticles from squid inks, an N-doping porous carbons with a unique "shell@pearls" structure has been fabricated through a direct carbonization/activation procedure. Remarkably, a fantastic structural evolution from core-shell, yolk-shell to the porous matrix embedded with small spheres (like pears in shell) has been observed. The as-obtained products exhibit a hierarchical porosity comprised of micro-, meso- and macropores, as well with a large surface area (1957 m2 g-1) and N-doping (2.09%). As the electrode materials for supercapacitors, the "shell@pearls"bio-carbons show the very high capacitance of 329 F g-1 at 0.5 A g-1 and 265 F g-1 at 30 A g-1 and also a superior retention of 99.5% after 10000 cycles at 5 A g-1.

Eigenvector centrality is a metric of elastomer modulus, heterogeneity, and damage

DOE Office of Scientific and Technical Information (OSTI.GOV)

Welch, Jr., Paul Michael; Welch, Cynthia F.

Here, we present an application of eigenvector centrality to encode the connectivity of polymer networks resolved at the micro- and meso-scopic length scales. This method captures the relative importance of different nodes within the network structure and provides a route toward the development of a statistical mechanics model that correlates connectivity with mechanical response. This scheme may be informed by analytical and semi-analytical models for the network structure, or through direct experimental examination. It may be used to predict the reduction in mechanical performance for heterogeneous materials subjected to specific modes of damage. Here, we develop the method and demonstratemore » that it leads to the prediction of established trends in elastomers. We also apply the model to the case of a self-healing polymer network reported in the literature, extracting insight about the fraction of bonds broken and re-formed during strain and recovery.« less

Eigenvector centrality is a metric of elastomer modulus, heterogeneity, and damage

DOE PAGES

Welch, Jr., Paul Michael; Welch, Cynthia F.

2017-04-27

Here, we present an application of eigenvector centrality to encode the connectivity of polymer networks resolved at the micro- and meso-scopic length scales. This method captures the relative importance of different nodes within the network structure and provides a route toward the development of a statistical mechanics model that correlates connectivity with mechanical response. This scheme may be informed by analytical and semi-analytical models for the network structure, or through direct experimental examination. It may be used to predict the reduction in mechanical performance for heterogeneous materials subjected to specific modes of damage. Here, we develop the method and demonstratemore » that it leads to the prediction of established trends in elastomers. We also apply the model to the case of a self-healing polymer network reported in the literature, extracting insight about the fraction of bonds broken and re-formed during strain and recovery.« less

Compression instrument for tissue experiments (cite) at the meso-scale: device validation - biomed 2011.

PubMed

Evans, Douglas W; Rajagopalan, Padma; Devita, Raffaella; Sparks, Jessica L

2011-01-01

Liver sinusoidal endothelial cells (LSECs) are the primary site of numerous transport and exchange processes essential for liver function. LSECs rest on a sparse extracellular matrix layer housed in the space of Disse, a 0.5-1LSECs from hepatocytes. To develop bioengineered liver tissue constructs, it is important to understand the mechanical interactions among LSECs, hepatocytes, and the extracellular matrix in the space of Disse. Currently the mechanical properties of space of Disse matrix are not well understood. The objective of this study was to develop and validate a device for performing mechanical tests at the meso-scale (100nm-100m), to enable novel matrix characterization within the space of Disse. The device utilizes a glass micro-spherical indentor attached to a cantilever made from a fiber optic cable. The 3-axis translation table used to bring the specimen in contact with the indentor and deform the cantilever. A position detector monitors the location of a laser passing through the cantilever and allows for the calculation of subsequent tissue deformation. The design allows micro-newton and nano-newton stress-strain tissue behavior to be quantified. To validate the device accuracy, 11 samples of silicon rubber in two formulations were tested to experimentally confirm their Young's moduli. Prior macroscopic unconfined compression tests determined the formulations of EcoFlex030 (n-6) and EcoFlex010 (n-5) to posses Young's moduli of 92.67+-6.22 and 43.10+-3.29 kPa respectively. Optical measurements taken utilizing CITE's position control and fiber optic cantilever found the moduli to be 106.4 kPa and 47.82 kPa.

The AMMA-CATCH Gourma observatory site in Mali: Relating climatic variations to changes in vegetation, surface hydrology, fluxes and natural resources

NASA Astrophysics Data System (ADS)

Mougin, E.; Hiernaux, P.; Kergoat, L.; Grippa, M.; de Rosnay, P.; Timouk, F.; Le Dantec, V.; Demarez, V.; Lavenu, F.; Arjounin, M.; Lebel, T.; Soumaguel, N.; Ceschia, E.; Mougenot, B.; Baup, F.; Frappart, F.; Frison, P. L.; Gardelle, J.; Gruhier, C.; Jarlan, L.; Mangiarotti, S.; Sanou, B.; Tracol, Y.; Guichard, F.; Trichon, V.; Diarra, L.; Soumaré, A.; Koité, M.; Dembélé, F.; Lloyd, C.; Hanan, N. P.; Damesin, C.; Delon, C.; Serça, D.; Galy-Lacaux, C.; Seghieri, J.; Becerra, S.; Dia, H.; Gangneron, F.; Mazzega, P.

2009-08-01

SummaryThe Gourma site in Mali is one of the three instrumented meso-scale sites deployed in West-Africa as part of the African Monsoon Multi-disciplinary Analysis (AMMA) project. Located both in the Sahelian zone sensu stricto, and in the Saharo-Sahelian transition zone, the Gourma meso-scale window is the northernmost site of the AMMA-CATCH observatory reached by the West African Monsoon. The experimental strategy includes deployment of a variety of instruments, from local to meso-scale, dedicated to monitoring and documentation of the major variables characterizing the climate forcing, and the spatio-temporal variability of surface processes and state variables such as vegetation mass, leaf area index (LAI), soil moisture and surface fluxes. This paper describes the Gourma site, its associated instrumental network and the research activities that have been carried out since 1984. In the AMMA project, emphasis is put on the relations between climate, vegetation and surface fluxes. However, the Gourma site is also important for development and validation of satellite products, mainly due to the existence of large and relatively homogeneous surfaces. The social dimension of the water resource uses and governance is also briefly analyzed, relying on field enquiry and interviews. The climate of the Gourma region is semi-arid, daytime air temperatures are always high and annual rainfall amounts exhibit strong inter-annual and seasonal variations. Measurements sites organized along a north-south transect reveal sharp gradients in surface albedo, net radiation, vegetation production, and distribution of plant functional types. However, at any point along the gradient, surface energy budget, soil moisture and vegetation growth contrast between two main types of soil surfaces and hydrologic systems. On the one hand, sandy soils with high water infiltration rates and limited run-off support almost continuous herbaceous vegetation with scattered woody plants. On the other hand, water infiltration is poor on shallow soils, and vegetation is sparse and discontinuous, with more concentrated run-off that ends in pools or low lands within structured endorheic watersheds. Land surface in the Gourma is characterized by rapid response to climate variability, strong intra-seasonal, seasonal and inter-annual variations in vegetation growth, soil moisture and energy balance. Despite the multi-decadal drought, which still persists, ponds and lakes have increased, the grass cover has largely recovered, and there are signs of increased tree cover at least in the low lands.

Development of an Efficient Meso- scale Multi-phase Flow Solver in Nuclear Applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, Taehun

2015-10-20

The proposed research aims at formulating a predictive high-order Lattice Boltzmann Equation for multi-phase flows relevant to nuclear energy related application - namely, saturated and sub-cooled boiling in reactors, and liquid- liquid mixing and extraction for fuel cycle separation. An efficient flow solver will be developed based on the Finite Element based Lattice Boltzmann Method (FE- LBM), accounting for phase-change heat transfer and capable of treating multiple phases over length scales from the submicron to the meter. A thermal LBM will be developed in order to handle adjustable Prandtl number, arbitrary specific heat ratio, a wide range of temperature variations,more » better numerical stability during liquid-vapor phase change, and full thermo-hydrodynamic consistency. Two-phase FE-LBM will be extended to liquid–liquid–gas multi-phase flows for application to high-fidelity simulations building up from the meso-scale up to the equipment sub-component scale. While several relevant applications exist, the initial applications for demonstration of the efficient methods to be developed as part of this project include numerical investigations of Critical Heat Flux (CHF) phenomena in nuclear reactor fuel bundles, and liquid-liquid mixing and interfacial area generation for liquid-liquid separations. In addition, targeted experiments will be conducted for validation of this advanced multi-phase model.« less

Mesoscale Computational Investigation of Shocked Heterogeneous Materials with Application to Large Impact Craters

NASA Technical Reports Server (NTRS)

Crawford, D. A.; Barnouin-Jha, O. S.; Cintala, M. J.

2003-01-01

The propagation of shock waves through target materials is strongly influenced by the presence of small-scale structure, fractures, physical and chemical heterogeneities. Pre-existing fractures often create craters that appear square in outline (e.g. Meteor Crater). Reverberations behind the shock from the presence of physical heterogeneity have been proposed as a mechanism for transient weakening of target materials. Pre-existing fractures can also affect melt generation. In this study, we are attempting to bridge the gap in numerical modeling between the micro-scale and the continuum, the so-called meso-scale. To accomplish this, we are developing a methodology to be used in the shock physics hydrocode (CTH) using Monte-Carlo-type methods to investigate the shock properties of heterogeneous materials. By comparing the results of numerical experiments at the micro-scale with experimental results and by using statistical techniques to evaluate the performance of simple constitutive models, we hope to embed the effect of physical heterogeneity into the field variables (pressure, stress, density, velocity) allowing us to directly imprint the effects of micro-scale heterogeneity at the continuum level without incurring high computational cost.

Self-Assembly of Porphyrin J-Aggregates

NASA Astrophysics Data System (ADS)

Snitka, Valentinas; Rackaitis, Mindaugas; Navickaite, Gintare

2006-03-01

The porphyrin nanotubes were built by ionic self-assembly of two oppositely charged porphyrins in aqueous solution. The porphyrins in the acid aqueous solution self-assemble into J-aggregates, wheels or other structures. The electrostatic forces between these porphyrin blocks contribute to the formation of porphyrin aggregates in the form of nanotubes, enhance the structural stability of these nanostructures. The nanotubes were composed mixing aqueous solutions of the two porphyrins - anionic Meso-tetra(4- sulfonatophrnyl)porhine dihydrochloride (TPPS4) and cationic Meso-tetra(4-pyridyl)porphine (T4MPyP). The porphyrin nanotubes obtained are hollow structures with the length of 300 nm and diameter 50 nm. Photocatalytic porphyrins are used to reduce metal complexes from aqueous solution and to control the deposition of Au from AuHCl4 and Au nanoparticles colloid solutions onto porphyrin nanotubes. Porphyrin nanotubes are shown to reduce metal complexes and deposit the metal selectively onto the inner or outer surface of the tubes, leading to nanotube-metal composite structures.

Interactions Between Convective Storms and Their Environment

NASA Technical Reports Server (NTRS)

Maddox, R. A.; Hoxit, L. R.; Chappell, C. F.

1979-01-01

The ways in which intense convective storms interact with their environment are considered for a number of specific severe storm situations. A physical model of subcloud wind fields and vertical wind profiles was developed to explain the often observed intensification of convective storms that move along or across thermal boundaries. A number of special, unusually dense, data sets were used to substantiate features of the model. GOES imagery was used in conjunction with objectively analyzed surface wind data to develop a nowcast technique that might be used to identify specific storm cells likely to become tornadic. It was shown that circulations associated with organized meso-alpha and meso-beta scale storm complexes may, on occasion, strongly modify tropospheric thermodynamic patterns and flow fields.

LABORATORY AND FIELD RESULTS LINKING HIGH CONDUCTIVITIES TO THE MICROBIAL DEGRADATION OF PETROLEUM HYDROCARBONS

EPA Science Inventory

The results of a l6-month field and l6-month meso-scale laboratory investigation of unconsolidated sandy environments contaminated by petroleum hydrocarbons that are undergoing natural biodegradation is presented. The purpose was to understand the processes responsible for causin...

Paleostress Reconstruction from 3D seismic, Natural Fracture and Calcite Twin Analyses: Structural Insights into the Otway Basin, Australia

NASA Astrophysics Data System (ADS)

Burgin, Hugo; Amrouch, Khalid; Holford, Simon

2017-04-01

The Otway Basin, Australia, is of particular interest due to its significance as an Australian hydrocarbon producing province and a major global CO2 burial project. Structural data was collected in the form of natural fractures from wellbore image logs and outcrop in addition to calcite twin analyses, within formations from the mid cretaceous from both on and offshore. Evidence for four structural events within the study area have been identified including NE-SW and NW-SE orientated extension, in addition to a NW-SE compressive event. Natural fracture data also reveals a previously "un-detected" NE-SW compression within the Otway Basin. This study presents the first investigation of paleostress environments within the region from micro, meso and macro scale tectonic data in both onshore and offshore in addition to the first quantification of differential paleostresses. This work highlights the importance of a comprehensive understanding of four dimensional stress evolution within the sedimentary basins of Australia's southern margin.

Canonical Genetic Signatures of the Adult Human Brain

PubMed Central

Hawrylycz, Michael; Miller, Jeremy A.; Menon, Vilas; Feng, David; Dolbeare, Tim; Guillozet-Bongaarts, Angela L.; Jegga, Anil G.; Aronow, Bruce J.; Lee, Chang-Kyu; Bernard, Amy; Glasser, Matthew F.; Dierker, Donna L.; Menche, Jörge; Szafer, Aaron; Collman, Forrest; Grange, Pascal; Berman, Kenneth A.; Mihalas, Stefan; Yao, Zizhen; Stewart, Lance; Barabási, Albert-László; Schulkin, Jay; Phillips, John; Ng, Lydia; Dang, Chinh; Haynor, David R.; Jones, Allan; Van Essen, David C.; Koch, Christof; Lein, Ed

2015-01-01

The structure and function of the human brain are highly stereotyped, implying a conserved molecular program responsible for its development, cellular structure, and function. We applied a correlation-based metric of “differential stability” (DS) to assess reproducibility of gene expression patterning across 132 structures in six individual brains, revealing meso-scale genetic organization. The highest DS genes are highly biologically relevant, with enrichment for brain-related biological annotations, disease associations, drug targets, and literature citations. Using high DS genes we identified 32 anatomically diverse and reproducible gene expression signatures, which represent distinct cell types, intracellular components, and/or associations with neurodevelopmental and neurodegenerative disorders. Genes in neuron-associated compared to non-neuronal networks showed higher preservation between human and mouse; however, many diversely-patterned genes displayed dramatic shifts in regulation between species. Finally, highly consistent transcriptional architecture in neocortex is correlated with resting state functional connectivity, suggesting a link between conserved gene expression and functionally relevant circuitry. PMID:26571460

The impact of fullerenes on the ordering of polyacrylonitrile during nanocomposites formation

DOE PAGES

Imel, Adam E.; Dadmun, Mark D.

2015-08-18

The production of polymer nanocomposites from solution consists of the mixing of the polymer and nanoparticle in solution and subsequent evaporation of the solvent. Here, we examine the formation of polyacrylonitrile and C60 fullerene nanocomposites, with a focus on monitoring these two steps.This study indicates that the nanoparticles are individually dispersed with the polymer chains in solution prior to deposition and in the final film. As the solution becomes more concentrated, the nanoparticles are sequestered to the outer edges of the polymer crystals, altering the detected crystal structure. The self-assembled structure of the crystalline polymer is directed by the additionmore » of C 60 and manifests itself as a peak in small-angle X-ray scattering on a length scale of ~150 . Moreover, our results suggest that the non-covalent molecular interactions between C60 and polyacrylonitrile matrix are sufficiently strong to alter the self-assembled morphology of the polymer and the meso- and nanoscale structures in the nanocomposite.« less

Meso-beta scale perturbations of the wind field by thunderstorm cells

NASA Technical Reports Server (NTRS)

Ulanski, S. L.; Heymsfield, G. M.

1986-01-01

Data from the high density storm-scale rawinsonde network of the Severe Environmental Storms and Mesoscale Experiment revealed temporal and spatial changes in the divergence fields of the troposphere in response to severe storm evolution on May 2, 1979; these changes were detectable on the meso-beta scale. This unique set of data was subsequently used to study the evolution of the wind, divergence and vertical motion fields in the presence of intense convection. Mid- and upper-tropospheric divergence was superimposed over low-level convergence. The divergence, which has a maximum value of .0004/s, occurred 75 to 100 km upwind as well as over the tornadic cells. To the south of the storm cells, the kinematic pattern was in reverse, upper level convergence was superimposed over low-level divergence. A vertical motion doublet was found to ascend over the squall line and descend about 70 km south of the squall line. It is suggested that the following effects are accountable for the nature of the kinematic fields: (1) blocking of tropospheric environmental flow by the storm cells, (2) anvil outflows, particularly from the tornadic cells, and (3) divergence from the exit region of the jet stream.

Radiosonde observational evidence of the influence of extreme SST gradient upon atmospheric meso-scale circulation

NASA Astrophysics Data System (ADS)

Nishikawa, H.; Tachibana, Y.; Udagawa, Y.

2012-12-01

Although the influence of the anomalous midlatitude SST upon atmospheric local circulation has been getting common in particular over the Kuroshio and the Gulf Stream regions, observational studies on the influence of the Okhotsk Sea, which is to the north of the Kuroshio, upon the atmospheric local circulation is much less than those of the Kuroshio. The climate of the Okhotsk SST is very peculiar. Extremely cold SST spots, whose summertime SST is lower than 5 Celsius degrees, are formed around Kuril Islands. Because SSTs are generally determined by local air-sea interaction as well as temperature advection, it is very difficult to isolate only the oceanic influence upon the atmosphere. The SST in this cold spot is, however, dominated by the tidal mixing, which is independent of the atmospheric processes. This unique condition may ease the account for the oceanic influence only. Although the SST environment of the Okhotsk Sea is good for understanding the oceanic influence upon the atmosphere, only a few studies has been executed in this region because of the difficulty of observations by research vessels in this region, where territory problems between Japan and Russia is unsolved. Because of the scant of direct observation, the Okhotsk Sea was still mysterious. In 2006 August, GPS radiosonde observation was carried out by Russian research vessel Khromov in the Sea of Okhotsk by the cooperation between Japan and Russia, and strong SST gradient of about 7 Celsius degrees/10km was observed around the Kuril Islands. The purpose of this study is to demonstrate observational finding of meso-scale atmospheric anticyclonic circulation influenced by the cold oceanic spot around the Kuril Island. The summaries of the observation are as follows. Meso-scale atmospheric ageostrophic anticyclonic circulation in the atmospheric marine-boundary layer is observed in and around the cold spot. A high air pressure area as compared with other surrounding areas is also located at the area of the ageostrophic anticyclonic circulation. In addition, the location of the cold dome in the atmospheric marine-boundary layer is in accordance with that of the large SST gradient. The cold dome with denser air than the surroundings probably strengthened the high pressure associated with subsidence over the cold dome. The downward direction of the sensible heat flux estimated by surface meteorological observation suggests that the cold dome was formed by the cooling by the cold sea. During the observation period around this area, the synoptic-scale sea level pressure field hardly changed. No reanalysis data sets resolve this anticyclonic circulation in this area. Therefore, we can conclude that the meso-scale anticyclone was formed by the influence of this cold SST and its large gradient.

Synoptic and Mesoscale Climatologies of Severe Local Storms for the American Midwest.

NASA Astrophysics Data System (ADS)

Arnold, David Leslie

This study investigates the synoptic and mesoscale environments associated with severe local storms (SELS) in the heart of the American Midwest. This region includes west-central Illinois, most of Indiana, the extreme western counties of Ohio, and a small part of northeastern Kentucky. The primary objectives of this study are to determine the surface and middle-tropospheric synoptic circulation patterns and thermodynamic and kinematic environments associated with SELS event types (tornadoes, hail, severe straight -line winds), and to assess the degree to which the synoptic circulation patterns and meso-beta scale kinematic and thermodynamic climatology of the Midwest differ from that of the Great Plains. A secondary objective is to investigate the possible role that land-surface atmosphere interactions play in the spatial distribution of SELS. A new subjective synoptic typing scheme is developed and applied to determine the synoptic-scale circulation patterns associated with the occurrence of SELS event types. This scheme is based on a combination of surface and middle -tropospheric patterns. Thermodynamic and kinematic parameters are analyzed to determine meso-scale environments favorable for the development of SELS. Results indicate that key synoptic-scale circulation patterns, and specific ranges of thermodynamic and kinematic parameters are related to specific SELS event types. These circulation types and ranges of thermodynamic and kinematic parameters may be used to help improve the medium-range forecasting of severe local storms. Results of the secondary objective reveal that the spatial distribution of SELS events is clustered within the study region, and most occur under a negative climate division-level soil moisture gradient; that is, a drier upwind division than the division in which the event occurs. Moreover, the spatial distribution of SELS events is compared against a map of soil types and vegetation. The resulting distribution depicts a visual correlation between the primary soil and vegetative boundaries and clusters of SELS. This supports the likely role of meso-scale land-surface-atmosphere interactions in severe weather development for humid lowlands of the Midwest United States.

The potential of near-surface geophysical methods in a hierarchical monitoring approach for the detection of shallow CO2 seeps at geological storage sites

NASA Astrophysics Data System (ADS)

Sauer, U.; Schuetze, C.; Dietrich, P.

2013-12-01

The MONACO project (Monitoring approach for geological CO2 storage sites using a hierarchic observation concept) aims to find reliable monitoring tools that work on different spatial and temporal scales at geological CO2 storage sites. This integrative hierarchical monitoring approach based on different levels of coverage and resolutions is proposed as a means of reliably detecting CO2 degassing areas at ground surface level and for identifying CO2 leakages from storage formations into the shallow subsurface, as well as CO2 releases into the atmosphere. As part of this integrative hierarchical monitoring concept, several methods and technologies from ground-based remote sensing (Open-path Fourier-transform infrared (OP-FTIR) spectroscopy), regional measurements (near-surface geophysics, chamber-based soil CO2 flux measurement) and local in-situ measurements (using shallow boreholes) will either be combined or used complementary to one another. The proposed combination is a suitable concept for investigating CO2 release sites. This also presents the possibility of adopting a modular monitoring concept whereby our monitoring approach can be expanded to incorporate other methods in various coverage scales at any temporal resolution. The link between information obtained from large-scale surveys and local in-situ monitoring can be realized by sufficient geophysical techniques for meso-scale monitoring, such as geoelectrical and self-potential (SP) surveys. These methods are useful for characterizing fluid flow and transport processes in permeable near-surface sedimentary layers and can yield important information concerning CO2-affected subsurface structures. Results of measurements carried out a natural analogue site in the Czech Republic indicate that the hierarchical monitoring approach represents a successful multidisciplinary modular concept that can be used to monitor both physical and chemical processes taking place during CO2 migration and seepage. The application of FTIR spectroscopy in combination with soil gas surveys and geophysical investigations results in a comprehensive site characterization, including atmospheric and near-surface CO2 distribution, as well as subsurface structural features. We observed a correlation of higher CO2 concentration and flux rates at the meso-scale that coincides with distinct geophysical anomalies. Here, we found prominent SP anomalies and zones of lower resistivity in the geoelectrical images compared to undisturbed regions nearby. This presentation will discuss the results we obtained and illustrate the influence of CO2 on electrical parameters measured under field conditions in relation to environmental parameters.

Nanoscale Structure Of Organic Matter Explain Its Recalcitrance To Degradation

NASA Astrophysics Data System (ADS)

Spagnol, M.; Salati, S.; Papa, G.; Tambone, F.; Adani, F.

2009-04-01

Recalcitrance can be defined as the natural resistance of organic matter (OM) to microbial and enzymatic deconstruction (Himmel et al., 2007). The nature of OM recalcitrance remained not completely understood and more studies need above all to elucidate the role of the chemical topography of the OM at nanometer scale. Hydrolytic enzymes responsible of OM degradation have a molecular weight of 20-25 kD, corresponding to a size of about 4 nm, hardly penetrate into micropores (i.e. the pore having a diameter < 2 nm) and small mesopores (i.e. pores having a diameter 2 < 50 nm) of OM structures, so that their activities are confined only to a portion of the total surface (Zimmerman et al., 2004; Chesson, 1997; Adani et al., 2006). As consequence of that the characterization of the organic matter at nano-scale became interesting in view to explain OM recalcitrance. The aim of this work was to asses the effect of the nano-scale structure of OM versus its recalcitrance. The evolution of organic matter of organic matrices was studied in two systems: plant residue-soil system and simulated landfill system. Plant residues were incubated in soil for one year and recalcitrant fraction, i.e. humic acid, was isolated and studied. Laboratory simulated landfill considered organic fraction of municipal solid waste sampled at different stages of evolution from a full scale plant and incubated under anaerobic condition for one year. In addition the nano-scale structure of fossilized OM (leonardite, chair coal and graphite) was detected as used as model of recalcitrant OM. Nano-scale structures were detected by using meso and microporosity detection. In particular microporosity was determined by adsorption method using CO2 at 273 K and Non Local Density Functional Theory (NLDFT) method was applied to measure the CO2 adsorption isotherms. On the other hand mesoporosity was detected by using N2 adsorption method at 77 K. The BET (Brunauer-Emmett-Teller) equation and the BJH (Barret-Joyner-Halenda) equation were applied respectively to measure specific surface area and mesoporosity. Macromolecular composition of OM was investigated by using CP MAS 13NMR and wet chemical analyses. Results obtained showed how OM evolved increasing microporosity and decreasing meso porosity. This was the result of the preservation of recalcitrant OM versus degradation of the more labile fraction, suggesting that the more recalcitrant fraction was characterized by high microporosity. Another confirmation of these results comes from the analysis of the same OM after the removing of the labile fraction by acid hydrolysis to discover the core-OM, which was characterized by a higher microposrosity with respect the bulk OM. In conclusion it can be showed that not only the chemical composition but, also, the physical structure of organic matter defined its recalcitrance. References Adani, F.; Spagnol, M.; Genevini, P. Biogeochemistry 2006, 78, 85-96. Himmel, M.E.; Ding S.Y.; Johnson, D.K.; Adney, W.S.; Nimlos, M.R.; Brady, J.W.; Foust, T.D. Sci. 2007, 315, 804-807. Chesson, A. In Driven by nature Plant Litter Quality and Decomposition. Cadisch, G.; Giller, K.E. Eds.; CAB International: Wallinford, UK 1997, pp 47-66. Zimmerman, A.R.; Goyne, K.W.; Chorover, J, Komarneni, S.; Brantley, S.L. Org Geochem. 2004, 35, 355-375.

Multisensor satellite observations of meso- and submesoscale surface circulation in the Liguro-Provençal Basin

NASA Astrophysics Data System (ADS)

Karimova, Svetlana; Alvera-Azcarate, Aida

2017-04-01

Despite great efforts being paid to studying circulation of the Western Mediterranean Basin and the factors triggering bioproductivity of its marine ecosystem, the evidence provided by satellite imagery has not been fully analysed yet. In the present paper, we concentrate our attention on mesoscale and submesoscale circulation features of the Liguro-Provençal Basin captured by satellite radiometer, spectroradiometer, and radar images. Using such a dataset makes it possible to observe the circulation features from a wide spatial range, from the basin scale through mesoscale to the scales of a few kilometers. Mesoscale features in this study are being mostly observed with thermal infrared imagery retrieved by AVHRR and AATSR sensors. Special attention in the work was paid to an analysis of the data coming from a geostationary satellite, namely ones provided by SEVIRI. Due to their uniquely high temporal resolution, such imagery allows observing circulation features in their evolution. During the winter blooming events, surface circulation at meso- to submesoscales in the region of interest was additionally highlighted by images obtained in the visible range. Full spatial resolution images provided by Envisat MERIS, Sentinel-2 MSI, and Landsat TM/ETM+/OLI made the greatest contribution to this part. The smallest scales (namely submesoscale) are being observed with synthetic aperture radar (SAR) imagery provided by Envisat ASAR and Sentinel-1 SAR. During an analysis of SAR images, it was noted that there was strikingly great amount of biogenic surfactants on the water surface in the region of interest. Apparently, low biological productivity typical for the Western Mediterranean ecosystem is not a limiting factor for the formation of surfactant films seen in SAR imagery. This finding though requires further consideration in some other researches, and hereafter we just benefited from the presence of surfactants, because they behave as good tracers of surface currents. Even though the region of interest belongs to the areas with low mean eddy kinetic energy, analysis of the images listed above revealed that the Liguro-Provençal Basin was showing a surprisingly high eddy activity among submesoscale and mesoscale features. However, the typical size of eddies in this area was smaller than that in the southern part of the Western Mediterranean. The general impression retrieved from the observations performed is that the main contributors to generation of observed mesoscale vortical structures are (i) the instability of the main currents in the region of interest and especially frontal instability at the Liguro-Provençal front and (ii) instabilities caused by the coastline inhomogeneity, especially in the eastern part of the Basin. Submesoscale eddy activity seems to be developed to its full extent during the periods when the mesoscale activity in the region of interest is not so prominent. This study is supported by the University of Liege and the EU in the context of the FP7-PEOPLE-COFUND-BeIPD project. Satellite imagery is provided by the European Space Agency.

Spatial variability of soil salinity in coastal saline soil at different scales in the Yellow River Delta, China.

PubMed

Wang, Zhuoran; Zhao, Gengxing; Gao, Mingxiu; Chang, Chunyan

2017-02-01

The objectives of this study were to explore the spatial variability of soil salinity in coastal saline soil at macro, meso and micro scales in the Yellow River delta, China. Soil electrical conductivities (ECs) were measured at 0-15, 15-30, 30-45 and 45-60 cm soil depths at 49 sampling sites during November 9 to 11, 2013. Soil salinity was converted from soil ECs based on laboratory analyses. Our results indicated that at the macro scale, soil salinity was high with strong variability in each soil layer, and the content increased and the variability weakened with increasing soil depth. From east to west in the region, the farther away from the sea, the lower the soil salinity was. The degrees of soil salinization in three deeper soil layers are 1.14, 1.24 and 1.40 times higher than that in the surface soil. At the meso scale, the sequence of soil salinity in different topographies, soil texture and vegetation decreased, respectively, as follows: depression >flatland >hillock >batture; sandy loam >light loam >medium loam >heavy loam >clay; bare land >suaeda salsa >reed >cogongrass >cotton >paddy >winter wheat. At the micro scale, soil salinity changed with elevation in natural micro-topography and with anthropogenic activities in cultivated land. As the study area narrowed down to different scales, the spatial variability of soil salinity weakened gradually in cultivated land and salt wasteland except the bare land.

Meso and Micro Scale Propulsion Concepts for Small Spacecraft

DTIC Science & Technology

2006-07-28

flame length , QF is the volumetric flow rate of the fuel, D is the binary diffusion coefficient of the fuel in the oxidizer, and YFsoi, is the...R, can yield the same flame length . Most laminar diffusion flames are buoyancy-controlled since a small exit velocity is generally required to

Interaction Rescaled: How Monastic Debate Became a Diasporic Pedagogy

ERIC Educational Resources Information Center

Lempert, Michael

2012-01-01

Rather than assume the relevance of "a priori" scalar distinctions (micro-, macro-, meso-), this article examines scale as an emergent dimension of sociospatial practice in educational institutions. Focusing on Buddhist debate at Tibetan monasteries in India, I describe how this educational practice has been placed as a rite of…

Particulate Meso-scale Mechanics Diagnostics: Magnetic Sensors for Dynamic State Orientation

DTIC Science & Technology

2013-12-01

Research Laboratory for giving this opportunity to work at the Eglin AFB, FL. REFERENCES 1. Brian D. Reding , “Development of Particulate Materials...Measurements," Sandia Report, 1984. 15. I.N. Tansel, B. Reding , W. L. Cooper, “Lagrangian Point State Estimation with Optimized, Redundant Induction Coil

Transversing the Vertical Case Study: A Methodological Approach to Studies of Educational Policy as Practice

ERIC Educational Resources Information Center

Bartlett, Lesley; Vavrus, Frances

2014-01-01

How can scholars trace the global production and circulation of educational policies? The vertical case study incorporates three elements: "vertical" attention across micro-, meso-, and macro-levels, or scales; a "horizontal" comparison of how policies unfold in distinct locations; and a "transversal," processual…

DEVELOPMENT OF AN ADJUSTABLE BUOYANCY BALLOON TRACER OF ATMOSPHERIC MOTION. PHASE 1. SYSTEMS DESIGN AND DEMONSTRATION OF FEASIBILITY

EPA Science Inventory

An Adjustable Buoyancy Balloon Tracer of Atmospheric Motion is a research tool which allows one to follow atmospheric flows in both the horizontal and the vertical, including the weak, sustained vertical motion associated with meso- and synoptic- scale atmospheric disturbances. T...

Some Observational and Modeling Studies of the Atmospheric Boundary Layer at Mississippi Gulf Coast for Air Pollution Dispersion Assessment

PubMed Central

Yerramilli, Anjaneyulu; Challa, Venkata Srinivas; Indracanti, Jayakumar; Dasari, Hariprasad; Baham, Julius; Patrick, Chuck; Young, John; Hughes, Robert; White, Lorren D.; Hardy, Mark G.; Swanier, Shelton

2008-01-01

Coastal atmospheric conditions widely vary from those over inland due to the land-sea interface, temperature contrast and the consequent development of local circulations. In this study a field meteorological experiment was conducted to measure vertical structure of boundary layer during the period 25–29 June, 2007 at three locations Seabee base, Harrison and Wiggins sites in the Mississippi coast. A GPS Sonde along with slow ascent helium balloon and automated weather stations equipped with slow and fast response sensors were used in the experiment. GPS sonde were launched at three specific times (0700 LT, 1300 LT and 1800 LT) during the experiment days. The observations indicate shallow boundary layer near the coast which gradually develops inland. The weather research and forecasting (WRF) meso-scale atmospheric model and a Lagrangian particle dispersion model (HYSPLIT) are used to simulate the lower atmospheric flow and dispersion in a range of 100 km from the coast for 28–30 June, 2007. The simulated meteorological parameters were compared with the experimental observations. The meso-scale model results show significant temporal and spatial variations in the meteorological fields as a result of development of sea breeze flow, its coupling with the large scale flow field and the ensuing alteration in the mixing depth across the coast. Simulated ground-level concentrations of SO2 from four elevated point sources located along the coast indicate diurnal variation and impact of the local sea-land breeze on the direction of the plume. Model concentration levels were highest during the stable morning condition and during the sea-breeze time in the afternoon. The highest concentrations were found up to 40 km inland during sea breeze time. The study illustrates the application of field meteorological observations for the validation of WRF which is coupled to HYSPLIT for dispersion assessment in the coastal region. PMID:19151446

A unified bond theory, probabilistic meso-scale modeling, and experimental validation of deformed steel rebar in normal strength concrete

NASA Astrophysics Data System (ADS)

Wu, Chenglin

Bond between deformed rebar and concrete is affected by rebar deformation pattern, concrete properties, concrete confinement, and rebar-concrete interfacial properties. Two distinct groups of bond models were traditionally developed based on the dominant effects of concrete splitting and near-interface shear-off failures. Their accuracy highly depended upon the test data sets selected in analysis and calibration. In this study, a unified bond model is proposed and developed based on an analogy to the indentation problem around the rib front of deformed rebar. This mechanics-based model can take into account the combined effect of concrete splitting and interface shear-off failures, resulting in average bond strengths for all practical scenarios. To understand the fracture process associated with bond failure, a probabilistic meso-scale model of concrete is proposed and its sensitivity to interface and confinement strengths are investigated. Both the mechanical and finite element models are validated with the available test data sets and are superior to existing models in prediction of average bond strength (< 6% error) and crack spacing (< 6% error). The validated bond model is applied to derive various interrelations among concrete crushing, concrete splitting, interfacial behavior, and the rib spacing-to-height ratio of deformed rebar. It can accurately predict the transition of failure modes from concrete splitting to rebar pullout and predict the effect of rebar surface characteristics as the rib spacing-to-height ratio increases. Based on the unified theory, a global bond model is proposed and developed by introducing bond-slip laws, and validated with testing of concrete beams with spliced reinforcement, achieving a load capacity prediction error of less than 26%. The optimal rebar parameters and concrete cover in structural designs can be derived from this study.

Evaluation of Cloud Microphysics Simulated using a Meso-Scale Model Coupled with a Spectral Bin Microphysical Scheme through Comparison with Observation Data by Ship-Borne Doppler and Space-Borne W-Band Radars

NASA Technical Reports Server (NTRS)

Iguchi, T.; Nakajima, T.; Khain, A. P.; Saito, K.; Takemura, T.; Okamoto, H.; Nishizawa, T.; Tao, W.-K.

2012-01-01

Equivalent radar reflectivity factors (Ze) measured by W-band radars are directly compared with the corresponding values calculated from a three-dimensional non-hydrostatic meso-scale model coupled with a spectral-bin-microphysical (SBM) scheme for cloud. Three case studies are the objects of this research: one targets a part of ship-borne observation using 95 GHz Doppler radar over the Pacific Ocean near Japan in May 2001; other two are aimed at two short segments of space-borne observation by the cloud profiling radar on CloudSat in November 2006. The numerical weather prediction (NWP) simulations reproduce general features of vertical structures of Ze and Doppler velocity. A main problem in the reproducibility is an overestimation of Ze in ice cloud layers. A frequency analysis shows a strong correlation between ice water contents (IWC) and Ze in the simulation; this characteristic is similar to those shown in prior on-site studies. From comparing with the empirical correlations by the prior studies, the simulated Ze is overestimated than the corresponding values in the studies at the same IWC. Whereas the comparison of Doppler velocities suggests that large-size snowflakes are necessary for producing large velocities under the freezing level and hence rules out the possibility that an overestimation of snow size causes the overestimation of Ze. Based on the results of several sensitivity tests, we conclude that the source of the overestimation is a bias in the microphysical calculation of Ze or an overestimation of IWC. To identify the source of the problems needs further validation research with other follow-up observations.

Meso-Scale Experimental & Numerical Studies for Predicting Macro-scale Performance of Advanced Reactive Materials (ARMs)

DTIC Science & Technology

2015-04-01

of impact-initiated reactions in Ti-Al-B based reactive materials in the form of compacts of powders of different sizes and morphologies . The major...More specifically, the influence of material-inherent elastic/plastic properties and reactant configuration (e.g., porosity, morphology , spacing...materials in the form of compacts of powders of different sizes and morphologies . The major goal is to delineate how processes of localized deformation and

Final Report, University of California Merced: Uranium and strontium fate in waste-weathered sediments: Scaling of molecular processes to predict reactive transport

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chorover, Jon; Mueller, Karl; O'Day, Peggy Anne

2016-06-30

Objectives of the Project: 1. Determine the process coupling that occurs between mineral transformation and contaminant (U and Sr) speciation in acid-uranium waste weathered Hanford sediments. 2. Establish linkages between molecular-scale contaminant speciation and meso-scale contaminant lability, release and reactive transport. 3. Make conjunctive use of molecular- to bench-scale data to constrain the development of a mechanistic, reactive transport model that includes coupling of contaminant sorption-desorption and mineral transformation reactions. Hypotheses Tested: Uranium and strontium speciation in legacy sediments from the U-8 and U-12 Crib sites can be reproduced in bench-scale weathering experiments conducted on unimpacted Hanford sediments from themore » same formations; Reactive transport modeling of future uranium and strontium releases from the vadose zone of acid-waste weathered sediments can be effectively constrained by combining molecular-scale information on contaminant bonding environment with grain-scale information on contaminant phase partitioning, and meso-scale kinetic data on contaminant release from the waste-weathered porous media; Although field contamination and laboratory experiments differ in their diagenetic time scales (decades for field vs. months to years for lab), sediment dissolution, neophase nucleation, and crystal growth reactions that occur during the initial disequilibrium induced by waste-sediment interaction leave a strong imprint that persists over subsequent longer-term equilibration time scales and, therefore, give rise to long-term memory effects. Enabling Capabilities Developed: Our team developed an iterative measure-model approach that is broadly applicable to elucidate the mechanistic underpinnings of reactive contaminant transport in geomedia subject to active weathering.« less

Meso-oblate spheroids of thermal-stabile linker-free aggregates with size-tunable subunits for reversible lithium storage.

PubMed

Deng, Da; Lee, Jim Yang

2014-01-22

The organization of nanoscale materials as building units into extended structures with specific geometry and functional properties is a challenging endeavor. Hereby, an environmentally benign, simple, and scalable method for preparation of stable, linker-free, self-supported, high-order 3D meso-oblate spheroids of CuO nanoparticle aggregates with size-tunable building nanounits for reversible lithium-ion storage is reported. In contrast to traditional spherical nanoparticle aggregation, a unique oblate spheroid morphology is achieved. The formation mechanism of the unusual oblate spheroid of aggregated nanoparticles is proposed. When tested for reversible lithium ion storage, the unique 3D meso-oblate spheroids of CuO nanoparticle aggregate demonstrated highly improved electrochemical performance (around ∼600 mAh/g over 20 cycles), which could be ascribed to the nanoporous aggregated mesostructure with abundant crystalline imperfection. Furthermore, the size of building units can be controlled (12 and 21 nm were tested) to further improve their electrochemical performance.

Methylsulfonyl polychlorinated biphenyls in fish from an electronic waste-recycling site in South China: levels, congener profiles, and chiral signatures.

PubMed

Zhang, Ying; Wu, Jiang-Ping; Luo, Xiao-Jun; She, Ya-Zhe; Mo, Ling; Mai, Bi-Xian

2012-11-01

Great concerns have been raised about the fate and effects of polychlorinated biphenyls (PCBs) and other organic contaminants contained in electronic waste (e-waste) exported from industrialized countries at midlatitudes to subtropical and tropical regions. Information on the metabolites of these chemicals, for example, methylsulfonyl-PCBs (MeSO(2)-PCBs) in wildlife from the later regions is scarce. In the present study, 17 MeSO(2)-PCBs, including five chiral congeners, were detected in the muscle, liver, and brain tissues of two benthic fish species--northern snakehead and mud carp--from a small pond near an electronic waste recycling site in South China. The mean concentrations of the sum of the MeSO(2)-PCBs ranged from 80 to 340 ng/g lipid weight in the tissues, with relative higher levels in the liver than the muscle and brain tissues. These levels were one order of magnitude greater than the highest levels of MeSO(2)-PCBs previously reported in fish. The 3'-MeSO(2)-CB 87, 3'- and 4'-MeSO(2)-CB 101, 4-MeSO(2)-CB 110, and 4-MeSO(2)-CB 149 were dominant, collectively comprising more than 55% of the total MeSO(2)-PCBs. Except for 4-MeSO(2)-CB149, all of the investigated chiral MeSO(2)-PCBs displayed a clear, congener-specific enantiomeric enrichment in the tissues. No tissue-specific enantioselective retention of the enantiomers was observed in the investigated fish. This is the first report on chiral signatures of MeSO(2)-PCBs in fish tissues. Copyright © 2012 SETAC.

In meso in situ serial X-ray crystallography of soluble and membrane proteins

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, Chia-Ying; Olieric, Vincent; Ma, Pikyee

A method for performing high-throughput in situ serial X-ray crystallography with soluble and membrane proteins in the lipid cubic phase is described. It works with microgram quantities of protein and lipid (and ligand when present) and is compatible with the most demanding sulfur SAD phasing. The lipid cubic phase (LCP) continues to grow in popularity as a medium in which to generate crystals of membrane (and soluble) proteins for high-resolution X-ray crystallographic structure determination. To date, the PDB includes 227 records attributed to the LCP or in meso method. Among the listings are some of the highest profile membrane proteins,more » including the β{sub 2}-adrenoreceptor–G{sub s} protein complex that figured in the award of the 2012 Nobel Prize in Chemistry to Lefkowitz and Kobilka. The most successful in meso protocol to date uses glass sandwich crystallization plates. Despite their many advantages, glass plates are challenging to harvest crystals from. However, performing in situ X-ray diffraction measurements with these plates is not practical. Here, an alternative approach is described that provides many of the advantages of glass plates and is compatible with high-throughput in situ measurements. The novel in meso in situ serial crystallography (IMISX) method introduced here has been demonstrated with AlgE and PepT (alginate and peptide transporters, respectively) as model integral membrane proteins and with lysozyme as a test soluble protein. Structures were solved by molecular replacement and by experimental phasing using bromine SAD and native sulfur SAD methods to resolutions ranging from 1.8 to 2.8 Å using single-digit microgram quantities of protein. That sulfur SAD phasing worked is testament to the exceptional quality of the IMISX diffraction data. The IMISX method is compatible with readily available, inexpensive materials and equipment, is simple to implement and is compatible with high-throughput in situ serial data collection at macromolecular crystallography synchrotron beamlines worldwide. Because of its simplicity and effectiveness, the IMISX approach is likely to supplant existing in meso crystallization protocols. It should prove particularly attractive in the area of ligand screening for drug discovery and development.« less

Morphological and performance measures of polyurethane foams using X-ray CT and mechanical testing.

PubMed

Patterson, Brian M; Henderson, Kevin; Gilbertson, Robert D; Tornga, Stephanie; Cordes, Nikolaus L; Chavez, Manuel E; Smith, Zachary

2014-08-01

Meso-scale structure in polymeric foams determines the mechanical properties of the material. Density variations, even more than variations in the anisotropic void structure, can greatly vary the compressive and tensile response of the material. With their diverse use as both a structural material and space filler, polyurethane (PU) foams are widely studied. In this manuscript, quantitative measures of the density and anisotropic structure are provided by using micro X-ray computed tomography (microCT) to better understand the results of mechanical testing. MicroCT illustrates the variation in the density, cell morphology, size, shape, and orientation in different regions in blown foam due to the velocity profile near the casting surface. "Interrupted" in situ imaging of the material during compression of these sub-regions indicates the pathways of the structural response to the mechanical load and the changes in cell morphology as a result. It is found that molded PU foam has a 6 mm thick "skin" of higher density and highly eccentric morphological structure that leads to wide variations in mechanical performance depending upon sampling location. This comparison is necessary to understand the mechanical performance of the anisotropic structure.

Qualitative study to understand the barriers to recruiting young people with cancer to BRIGHTLIGHT: a national cohort study in England

PubMed Central

Kenten, Charlotte; Martins, Ana; Fern, Lorna A; Gibson, Faith; Lea, Sarah; Ngwenya, Nothando; Whelan, Jeremy S; Taylor, Rachel M

2017-01-01

Objectives BRIGHTLIGHT is a national evaluation of cancer services for teenagers and young adults in England. Following challenges with recruitment, our aim was to understand more fully healthcare professionals’ perspectives of the challenges of recruiting young people to a low-risk observational study, and to provide guidance for future recruitment processes. Design Qualitative. Setting National Health Service (NHS) hospitals in England. Methods Semistructured telephone interviews with a convenience sample of 23 healthcare professionals. Participants included principal investigators/other staff recruiting into the BRIGHTLIGHT study. Data were analysed using framework analysis. Results The emergent themes were linked to levels of research organisational management, described using the levels of social network analysis: micro-level (the individual; in this case the target population to be recruited—young people with cancer); meso-level (the organisation; refers to place of recruitment and people responsible for recruitment); and macro-level (the large-scale or global structure; refers to the wider research function of the NHS and associated policies). Study-related issues occurred across all three levels, which were influenced by the context of the study. At the meso-level, professionals’ perceptions of young people and communication between professionals generated age/cancer type silos, resulting in recruitment of either children or adults, but not both by the same team, and only in the cancer type the recruiting professional was aligned to. At the macro-level the main barrier was discordant configuration of a research service with a clinical service. Conclusions This study has identified significant barriers to recruitment mainly at the meso-level and macro-level, which are more challenging for research teams to influence. We suggest that interconnected whole-system changes are required to facilitate the success of interventions designed to improve recruitment. Interventions targeted at study design/management and the micro-level only may be less successful. We offer solutions to be considered by those involved at all levels of research for this population. PMID:29122799

The Mega Mesospheric Parachute

NASA Technical Reports Server (NTRS)

Kloesel, Kurt J.; Oberto, Robert; Kinsey, Robert

2005-01-01

The current understanding and modeling of the upper reaches of the atmosphere is incomplete. Upper atmospheric interactions with the lower atmosphere, effects of ionizing radiation, high altitude cloud phenomena, and the dynamical interaction with the magnetosphere require greater definition. The scientific objective of obtaining a greater understanding of the upper atmosphere can be achieved by designing, implementing, testing, and utilizing a facility that provides long period in-situ measurements of the mesosphere. Current direct sub-sonic measurements of the upper atmosphere are hampered by the approximately one minute sub-sonic observation window of a ballistic sounding rocket regardless of the launch angle. In-situ measurements at greater than transonic speeds impart energy into the molecular atmospheric system and distort the true atmospheric chemistry. A long duration, sub-sonic capability will significantly enhance our ability to observe and measure: (1) mesospheric lightning phenomena (sprites and blue jets) (2) composition, structure and stratification of noctilucent clouds (3) physics of seasonal radar echoes, gravity wave phenomena (4) chemistry of mesospheric gaseous ratio mixing (5) mesospheric interaction of ionizing radiation (6) dynamic electric and magnetic fields This new facility will also provide local field measurements which complement those that can be obtained through external measurements from satellite and ground-based platforms. The 400 foot (approximately 130 meter) diameter lightweight mega-mesospheric parachute system, deployed with a sounding rocket, is proposed herein as a method to increase sub-sonic mesospheric measurement time periods by more than an order of magnitude. The report outlines a multi-year evolving science instrumentation suite in parallel with the development of the mega meso-chute facility. The developmental issues surrounding the meso-chute are chiefly materials selection (thermal and structural) and deployment mechanism physics. Three mission cases were conceived and developed to include cost and schedules estimates. Each scenario has increasing scientific utility with paralleling launch weight, parachute hang-time, deployment altitude, and parachute size: (1) Case #1: $8.4M@24 months, 6kg payload, 20 min., 50km alt., 80 m. dia. (2) Case #2: $10.4M@24 months, 6kg payload, 20 min., 60km alt, 130m. dia. (3) Case #3: $13.6M@36 months, 30kg payload, 30 min., 90km alt., 200m. dia. The initial breakout cost for the parachute system is approximately $2M@24 months. This report identifies that although the challenges of the mega-meso-chute may be difficult, they can be surmounted and valuable results can be achieved.

3D hierarchical porous graphene aerogel with tunable meso-pores on graphene nanosheets for high-performance energy storage

PubMed Central

Ren, Long; Hui, K. N.; Hui, K. S.; Liu, Yundan; Qi, Xiang; Zhong, Jianxin; Du, Yi; Yang, Jianping

2015-01-01

New and novel 3D hierarchical porous graphene aerogels (HPGA) with uniform and tunable meso-pores (e.g., 21 and 53 nm) on graphene nanosheets (GNS) were prepared by a hydrothermal self-assembly process and an in-situ carbothermal reaction. The size and distribution of the meso-pores on the individual GNS were uniform and could be tuned by controlling the sizes of the Co3O4 NPs used in the hydrothermal reaction. This unique architecture of HPGA prevents the stacking of GNS and promises more electrochemically active sites that enhance the electrochemical storage level significantly. HPGA, as a lithium-ion battery anode, exhibited superior electrochemical performance, including a high reversible specific capacity of 1100 mAh/g at a current density of 0.1 A/g, outstanding cycling stability and excellent rate performance. Even at a large current density of 20 A/g, the reversible capacity was retained at 300 mAh/g, which is larger than that of most porous carbon-based anodes reported, suggesting it to be a promising candidate for energy storage. The proposed 3D HPGA is expected to provide an important platform that can promote the development of 3D topological porous systems in a range of energy storage and generation fields. PMID:26382852

Organocatalyzed enantioselective desymmetrization of aziridines and epoxides

PubMed Central

2013-01-01

Summary Enantioselective desymmetrization of meso-aziridines and meso-epoxides with various nucleophiles by organocatalysis has emerged as a cutting-edge approach in recent years. This review summarizes the origin and recent developments of enantioselective desymmetrization of meso-aziridines and meso-epoxides in the presence of organocatalysts. PMID:24062828

Effects of biotic and abiotic factors on the distribution and abundance of larval two-lined salamanders (Eurycea bislineata) across spatial scales.

PubMed

Barr, Garrett E; Babbitt, Kimberly J

2002-10-01

We sampled eight streams in the White Mountain National Forest, New Hampshire, throughout their elevational reach for larval salamanders and predatory fish to examine the effects of abiotic factors and predation on the distribution and abundance of larval salamanders. Eurycea bislineata (two-lined salamander) and Salvelinus fontinalis (brook trout) abundance varied among and within streams. Eurycea bislineata showed a negative association with S. fontinalis across spatial scales (micro-scale, among quadrats; meso-scale, among pool/riffle pairs; macro-scale, among streams). At the smallest scale, the average density of larval E. bislineata was greatest in microhabitats with relatively high boulder cover and low sand and bare rock cover only in the presence of S. fontinalis; no such relationship was observed in the absence of S. fontinalis. In a mesocosm experiment, larval salamander survival was higher in enclosures containing cobbles than enclosures containing a gravel mix, illustrating the advantage of coarse substrates with interstitial spaces that are inaccessible to predatory fish. At the meso-scale, E. bislineata larvae were less abundant in stream sections with S. fontinalis than those without. Among streams, those with many S. fontinalis had fewer E. bislineata. Of the abiotic parameters measured, water temperature and pH were positively related to E. bislineata presence, and elevation, water temperature, pH, canopy cover, and gradient were positively related to E. bislineata abundance. Larval Plethodontid salamanders can reach high densities and appear to have strong interactions with stream biota, thus their functional role in stream communities deserves further attention.

The influence of mesoscale and submesoscale heterogeneity on ocean biogeochemical reactions

NASA Astrophysics Data System (ADS)

Levy, M.; Martin, A. P.

2013-12-01

The oceanic circulation in the meso to submesoscale regime generates heterogeneity in the concentrations of biogeochemical components over these scales, horizontally between 1 and 100 km. Due to nonlinearities in the biogeochemical reactions, such as phytoplankton primary production and zooplankton grazing, this small-scale heterogeneity can lead to departure from the mean field approximation, whereby plankton reactions are evaluated from mean distributions at coarser scale. Here we explore the magnitude of these eddy reactions and compare their strength to those of the more widely studied eddy transports. We use the term eddy to denote effects arising from scales smaller than ˜ 100 km. This is done using a submesoscale permitting biogeochemical model, representative of the seasonally varying subtropical and subpolar gyres. We found that the eddy reactions associated with primary production and grazing account for ±5-30% of productivity and grazing, respectively, depending on location and time of year, and are scale dependent: two thirds are due to heterogeneities at scales 30-100 km and one third to those at scales below 30 km. Moreover, eddy productivities are systematically negative, implying that production tends to be reduced by nonlinear interactions at the mesoscale and smaller. The opposite result is found for eddy grazing, which is generally positive. The contrasting effects result from vertical advection, which negatively correlates phytoplankton and nutrients and positively correlates phytoplankton and zooplankton in the meso to submesoscale range. Moreover, our results highlight the central role played by eddy reactions for ecological aspects and the distribution of organisms and by eddy transport for biogeochemical aspects and nutrient budgets.

AuRu/meso-Mn2O3: A Highly Active and Stable Catalyst for Methane Combustion

NASA Astrophysics Data System (ADS)

Han, Z.; Fang, J. Y.; Xie, S. H.; Deng, J. G.; Liu, Y. X.; Dai, H. X.

2018-05-01

Three-dimensionally ordered mesoporous Mn2O3 (meso-Mn2O3) and its supported Au, Ru, and AuRu alloy (0.49 wt% Au/meso-Mn2O3, 0.48 wt% Ru/meso-Mn2O3, and 0.97 wt% AuRu/meso-Mn2O3 (Au/Ru molar ratio = 0.98)) nanocatalysts were prepared using the KIT-6-templating and polyvinyl alcohol-protected reduction methods, respectively. Physicochemical properties of the samples were characterized by means of numerous techniques, and their catalytic activities were evaluated for the combustion of methane. It is found that among all of the samples, 0.48 wt% Ru/meso-Mn 2O3 and 0.97 wt% AuRu/meso-Mn2O3 performed the best (the reaction temperature (T90% ) at 90% methane conversion was 530-540°C), but the latter showed a better thermal stability than the former. The partial deactivation of 0.97 wt% AuRu/meso-Mn2O3 due to H2O or CO2 introduction was reversible. It is concluded that the good catalytic activity and thermal stability of 0.97 wt% AuRu/meso-Mn2O3 was associated with the high dispersion of AuRu alloy NPs (2-5 nm) on the surface of meso-Mn2O3 and good low-temperature reducibility.

Effects of dominant somatotype on aerobic capacity trainability

PubMed Central

Chaouachi, M; Chaouachi, A; Chamari, K; Chtara, M; Feki, Y; Amri, M; Trudeau, F

2005-01-01

Purpose: This study examined the association between dominant somatotype and the effect on aerobic capacity variables of individualised aerobic interval training. Methods: Forty one white North African subjects (age 21.4±1.3 years; V·o2max = 52.8±5.7 ml kg–1 min–1) performed three exercise tests 1 week apart (i) an incremental test on a cycle ergometer to determine V·o2max and V·o2 at the second ventilatory threshold (VT2); (ii) a VAM-EVAL track test to determine maximal aerobic speed (vV·o2max); and (iii) an exhaustive constant velocity test to determine time limit performed at 100% vV·o2max (tlim100). Subjects were divided into four somatometric groups: endomorphs-mesomorphs (Endo-meso; n = 9), mesomorphs (Meso; n = 11), mesomorphs-ectomorphs (Meso-ecto; n = 12), and ectomorphs (Ecto; n = 9). Subjects followed a 12 week training program (two sessions/week). Each endurance training session consisted of the maximal number of successive fractions for each subject. Each fraction consisted of one period of exercise at 100% of vV·o2max and one of active recovery at 60% of vV·o2max. The duration of each period was equal to half the individual tlim100 duration (153.6±39.7 s). After the training program, all subjects were re-evaluated for comparison with pre-test results. Results: Pre- and post-training data were grouped by dominant somatotype. Two way ANOVA revealed significant somatotype-aerobic training interaction effects (p<0.001) for improvements in vV·o2max, V·o2max expressed classically and according to allometric scaling, and V·o2 at VT2. There were significant differences among groups post-training: the Meso-ecto and the Meso groups showed the greatest improvements in aerobic capacity. Conclusion: The significant somatotype-aerobic training interaction suggests different trainability with intermittent and individualised aerobic training according to somatotype. PMID:16306506

Effects of dominant somatotype on aerobic capacity trainability.

PubMed

Chaouachi, M; Chaouachi, A; Chamari, K; Chtara, M; Feki, Y; Amri, M; Trudeau, F

2005-12-01

This study examined the association between dominant somatotype and the effect on aerobic capacity variables of individualised aerobic interval training. Forty one white North African subjects (age 21.4+/-1.3 years; Vo2max = 52.8+/-5.7 ml kg(-1) min(-1)) performed three exercise tests 1 week apart (i) an incremental test on a cycle ergometer to determine Vo2max and Vo2 at the second ventilatory threshold (VT2); (ii) a VAM-EVAL track test to determine maximal aerobic speed (vVo2max); and (iii) an exhaustive constant velocity test to determine time limit performed at 100% vVo2max (tlim100). Subjects were divided into four somatometric groups: endomorphs-mesomorphs (Endo-meso; n = 9), mesomorphs (Meso; n = 11), mesomorphs-ectomorphs (Meso-ecto; n = 12), and ectomorphs (Ecto; n = 9). Subjects followed a 12 week training program (two sessions/week). Each endurance training session consisted of the maximal number of successive fractions for each subject. Each fraction consisted of one period of exercise at 100% of vVo2max and one of active recovery at 60% of vVo2max. The duration of each period was equal to half the individual tlim100 duration (153.6+/-39.7 s). After the training program, all subjects were re-evaluated for comparison with pre-test results. Pre- and post-training data were grouped by dominant somatotype. Two way ANOVA revealed significant somatotype-aerobic training interaction effects (p<0.001) for improvements in vVo2max, Vo2max expressed classically and according to allometric scaling, and Vo2 at VT2. There were significant differences among groups post-training: the Meso-ecto and the Meso groups showed the greatest improvements in aerobic capacity. The significant somatotype-aerobic training interaction suggests different trainability with intermittent and individualised aerobic training according to somatotype.

The influence of air-conditioning on street temperatures in the city of Paris

NASA Astrophysics Data System (ADS)

de Munck, C. S.; Pigeon, G.; Masson, V.; Marchadier, C.; Meunier, F.; Tréméac, B.; Merchat, M.

2010-12-01

A consequence of urban heat islands in summer is the increased use of air-conditioning during extreme heat events : the use of air-conditioning systems, while cooling the inside of buildings releases waste heat (as latent and sensible heat) in the lower part of the urban atmosphere, hence potentially increasing air street temperatures where the heat is released. This may lead locally to a further increase in air street temperatures, therefore increasing the air cooling demand, while at the same time lowering the efficiency of air-conditioning units. A coupled model consisting of a meso-scale meteorological model (MESO-NH) and an urban energy balance model (TEB) has been implemented with an air-conditioning module and used in combination to real spatialised datasets to understand and quantify potential increases in temperature due to air-conditioning heat releases for the city of Paris . In a first instance, the current types of air-conditioning systems co-existing in the city were simulated (underground chilled water network, wet cooling towers and individual air-conditioning units) to study the effects of latent and sensible heat releases on street temperatures. In a third instance, 2 scenarios were tested to characterise the impacts of likely future trends in air-conditioning equipment in the city : a first scenario for which current heat releases were converted to sensible heat, and a second based on 2030s projections of air-conditioning equipment at the scale of the city. All the scenarios showed an increase in street temperature which, as expected, was greater at night time than day time. For the first two scenarios, this increase in street temperatures was localised at or near the sources of air-conditioner heat releases, while the 2030s air-conditioning scenario impacted wider zones in the city. The amplitude of the increase in temperature varied from 0,25°C to 1°C for the air-conditioning current state, between 0,25°C and 2°C for the sensible heat release only scenario, and finally from 0,25°C to 2 °C for the 2030s scenario, with impacts of up to 3°C locally. Overall, these results demonstrated to which extend the use air-conditioning could enhance street temperatures in the city of Paris and the importance of a spatialised approach.

Long-term controls on continental-scale bedrock river terrace deposition from integrated clast and heavy mineral assemblage analysis: An example from the lower Orange River, Namibia

NASA Astrophysics Data System (ADS)

Nakashole, Albertina N.; Hodgson, David M.; Chapman, Robert J.; Morgan, Dan J.; Jacob, Roger J.

2018-02-01

Establishing relationships between the long-term landscape evolution of drainage basins and the fill of sedimentary basins benefits from analysis of bedrock river terrace deposits. These fragmented detrital archives help to constrain changes in river system character and provenance during sediment transfer from continents (source) to oceans (sink). Thick diamondiferous gravel terrace deposits along the lower Orange River, southern Namibia, provide a rare opportunity to investigate controls on the incision history of a continental-scale bedrock river. Clast assemblage and heavy mineral data from seven localities permit detailed characterisation of the lower Orange River gravel terrace deposits. Two distinct fining-upward gravel terrace deposits are recognised, primarily based on mapped stratigraphic relationships (cross-cutting relationships) and strath and terrace top elevations, and secondarily on the proportion of exotic clasts, referred to as Proto Orange River deposits and Meso Orange River deposits. The older early to middle Miocene Proto Orange River gravels are thick (up to 50 m) and characterised by a dominance of Karoo Supergroup shale and sandstone clasts, whereas the younger Plio-Pleistocene Meso Orange River gravels (6-23 m thick) are characterised by more banded iron formation clasts. Mapping of the downstepping terraces indicates that the Proto gravels were deposited by a higher sinuosity river, and are strongly discordant to the modern Orange River course, whereas the Meso deposits were deposited by a lower sinuosity river. The heavy minerals present in both units comprise magnetite, garnet, amphibole, epidote and ilmenite, with rare titanite and zircon grains. The concentration of amphibole-epidote in the heavy minerals fraction increases from the Proto to the Meso deposits. The decrease in incision depths, recorded by deposit thicknesses above strath terraces, and the differences in clast character (size and roundness) and type between the two units, are ascribed to a more powerful river system during Proto-Orange River time, rather than reworking of older deposits, changes in provenance or climatic variations. In addition, from Proto- to Meso-Orange River times there was an increase in the proportion of sediments supplied from local bedrock sources, including amphibole-epidote in the heavy mineral assemblages derived from the Namaqua Metamorphic Complex. This integrated study demonstrates that clast assemblages are not a proxy for the character of the matrix, and vice versa, because they are influenced by the interplay of different controls. Therefore, an integrated approach is needed to improve prediction of placer mineral deposits in river gravels, and their distribution in coeval deposits downstream.

MP-Pic simulation of CFB riser with EMMS-based drag model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, F.; Song, F.; Benyahia, S.

2012-01-01

MP-PIC (multi-phase particle in cell) method combined with the EMMS (energy minimization multi- scale) drag force model was implemented with the open source program MFIX to simulate the gas–solid flows in CFB (circulatingfluidizedbed) risers. Calculated solid flux by the EMMS drag agrees well with the experimental value; while the traditional homogeneous drag over-predicts this value. EMMS drag force model can also predict the macro-and meso-scale structures. Quantitative comparison of the results by the EMMS drag force model and the experimental measurements show high accuracy of the model. The effects of the number of particles per parcel and wall conditions onmore » the simulation results have also been investigated in the paper. This work proved that MP-PIC combined with the EMMS drag model can successfully simulate the fluidized flows in CFB risers and it serves as a candidate to realize real-time simulation of industrial processes in the future.« less

Multiscale Geoarchaeological Approaches from the Laurentine Shore, Castelporziano, Lazio, Italy

NASA Astrophysics Data System (ADS)

Bicket, A. R.; Rendell, H. M.; Claridge, A.; Rose, P.; Brown, F. S. J.

2009-04-01

The relationship between the meso-scale record of human activity during the Roman period and the larger-scale coastal development of the Tiber Delta (ca. 20 ka) is investigated using the archaeological and sedimentary record from a large aquaculture pond and its wider meso- to macro-scale geomorphological setting. The position of the pond is adjacent to the Roman period shoreline, known as the Laurentine Shore on the southern, distal flank of the Tiber delta, Lazio Italy, within what is now the Castelporziano Estate. The pond is thought to have been constructed in the wet dune slack behind the active coastal foredune. Magnetometer survey and excavation of the archaeological structures around this pond have shown them to be substantial features ca. 80m in length with high-status Imperial Roman architecture and with evidence for water management. Sedimentological analysis of sediment cores from within the ponds are supplemented with diatom analysis to assess the period of pre-construction, use and abandonment of this aquaculture pond. Diatom analysis suggests a relatively short period of use and it is argued that abandonment of the aquaculture structures may be linked to both alkali groundwater conditions and the dynamism of the coastal zone preventing effective management. Optical luminescence dating of the archaeological sediments and the post-abandonment dunes that bury part of the site suggest that the aquaculture pond was abandoned ca. 100 years prior to final abandonment of the Roman settlement. This case-study also highlights the implications for meso-scale investigations of human/environment relationships utilising relatively low-sensitivity sedimentary records without high-resolution proxy records. D-GPS survey in conjunction with a high-quality DEM has permitted important archaeological remains to be understood relative to sea level; a key variable for examining the formation and development of the dune ridge record. These surveys have also permitted the effective mapping of dune ridges, from aerial photography, under the extremely dense vegetation that hinders easy access across much of the site. The D-GPS georeferenced DEM has been linked to the diatom analysis of a cored salt marsh to peat sediment transition providing valuable biostratigraphic information for deriving an accurate measurement of the Roman period sea level (Lambeck et al., 2004a). This measurement is in line with published literature from nearby coastal sites, ca. - 1.3m RSL (Lambeck et al., 2004b). Understanding the sites geomorphological development in the context of eustatic sea level is a key consideration for issues of sand supply driving dune formation, linked ultimately to the development of the Tiber Delta since the Last Glacial Maximum and throughout the Holocene. On this larger spatial scale, the archaeological sites described within the Laurentine Shore, built upon the Roman period coastline, are now preserved several hundred metres inland of the contemporary shoreline. The development of the shoreline can now be investigated within the macro-scale progradation of the Tiber delta relative to eustatic sea level rise. Archaeological excavations since the 1980's have provided a rich record of high status villas, and also the supporting infrastructure of a village settlement (vicus), roads, aqueduct and the large aquaculture ponds. The dominant geomorphological features on the site are preserved coastal dune ridges. Sampling was undertaken along an alongshore transect and three inland transects. This sampling regime focuses upon the contemporary deposition of sands on the beach and the phases of dune formation, preservation and alteration recorded by the relict dune crests in relation to the archaeological record. A campaign of optical dating of the relict dune crests has provided a Late Pleistocene and Holocene record of sandsheet and dune formation linked to delta progradation that permits the larger spatial- and temporal-scale context of the archaeological record to be discussed. Sedimentary petrology techniques allow the provenance and transportation dynamics of both the sand-sized and dust-sized sediments to be assessed. Furthermore this approach also enables an investigation of carbonate and iron oxide diagenetic cements, which are an important product of the long-term in situ weathering of the dune ridges' mineralogical assemblages, but is also a feature of short-term weathering of archaeological contexts. This work has implications for locations of interest to geoarchaeological surveys. There are also important implications for the mineralogy, provenance and preservation of luminescent minerals; and some form mineralogical/provenance analysis is recommended for all optical dating studies as a result. In summary, the geoarchaeological approach undertaken at Castelporziano allows the meso-scale human/environment interactions to be considered within the broader temporal scales of the late Quaternary. It also permits consideration within the macro-spatial scales of the Tiber Delta's development during the last 15-20ka within the context of eustatic sea level rise. REFERENCES LAMBECK, K., ANTONIOLI, F., PURCELL, A. & SILENZI, S. (2004a) Sea-level change along the Italian coast for the past 10,000 yr. Quaternary Science Reviews, 23, 1567-1598. LAMBECK, K., ANZIDEI, M., ANTONIOLI, F., BENINI, A. & ESPOSITO, A. (2004b) Sea level in Roman time in the Central Mediterranean and implications for recent change. Earth and Planetary Science Letters, 224, 563-575.

Interactionist Neuroscience.

PubMed

Badre, David; Frank, Michael J; Moore, Christopher I

2015-12-02

We argue that bidirectional interaction between animal and human studies is essential for understanding the human brain. The revolution in meso-scale study of circuits in non-human species provides a historical opportunity. However, to fully realize its potential requires integration with human neuroscience. We describe three strategies for successful interactionist neuroscience. Copyright © 2015 Elsevier Inc. All rights reserved.

Decline of phosphorus, copper, and zinc in anaerobic swine lagoon columns receiving pretreated influent

USDA-ARS?s Scientific Manuscript database

Land application of both anaerobic lagoon liquid and sludge can increase nutrient accumulation beyond soil assimilative capacity and become a threat to water quality in regions with intensive confined swine production. In a 15-month meso-scale column study, we evaluated the effect of manure pretreat...

Water quality and nitrogen mass loss from anaerobic lagoon columns receiving pretreated influent

USDA-ARS?s Scientific Manuscript database

Control methods are needed to abate ammonia losses from swine anaerobic lagoons to reduce contribution of confined swine operations to air pollution. In a 15-month meso-scale column study, we evaluated the effect of manure pretreatment on water quality, reduction of N losses, and sludge accumulation...

Decline of phosphorus, copper, and zinc in anaerobic lagoon columns receiving pretreated influent

USDA-ARS?s Scientific Manuscript database

In a 15-month meso-scale column study, we evaluated the effect of manure pretreatment on reduction of total suspended solids (TSS), total phosphorus (TP), soluble reactive phosphorus (SRP), copper (Cu) and zinc (Zn) in swine lagoons using (i) enhanced solid–liquid separation with polymer (SS) and (i...

Continuous formation of N-chloro-N,N-dialkylamine solutions in well-mixed meso-scale flow reactors

PubMed Central

Jolley, Katherine E

2015-01-01

Summary The continuous flow synthesis of a range of organic solutions of N,N-dialkyl-N-chloramines is described using either a bespoke meso-scale tubular reactor with static mixers or a continuous stirred tank reactor. Both reactors promote the efficient mixing of a biphasic solution of N,N-dialkylamine in organic solvent, and aqueous sodium hypochlorite to achieve near quantitative conversions, in 72–100% in situ yields, and useful productivities of around 0.05 mol/h with residence times from 3 to 20 minutes. Initial calorimetric studies have been carried out to inform on reaction exotherms, rates and safe operation. Amines which partition mainly in the organic phase require longer reaction times, provided by the CSTR, to compensate for low mass transfer rates in the biphasic system. The green metrics of the reaction have been assessed and compared to existing procedures and have shown the continuous process is improved over previous procedures. The organic solutions of N,N-dialkyl-N-chloramines produced continuously will enable their use in tandem flow reactions with a range of nucleophilic substrates. PMID:26734089

Evaluation of Test Methods for Triaxially Braided Composites using a Meso-Scale Finite Element Model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Chao

The characterization of triaxially braided composite is complicate due to the nonuniformity of deformation within the unit cell as well as the possibility of the freeedge effect related to the large size of the unit cell. Extensive experimental investigation has been conducted to develop more accurate test approaches in characterizing the actual mechanical properties of the material we are studying. In this work, a meso-scale finite element model is utilized to simulate two complex specimens: notched tensile specimen and tube tensile specimen, which are designed to avoid the free-edge effect and free-edge effect induced premature edge damage. The full fieldmore » strain data is predicted numerically and compared with experimental data obtained by Digit Image Correlation. The numerically predicted tensile strength values are compared with experimentally measured results. The discrepancy between numerically predicted and experimentally measured data, the capability of different test approaches are analyzed and discussed. The presented numerical model could serve as assistance to the evaluation of different test methods, and is especially useful in identifying potential local damage events.« less

MesoNAM Verification Phase II

NASA Technical Reports Server (NTRS)

Watson, Leela R.

2011-01-01

The 45th Weather Squadron Launch Weather Officers use the 12-km resolution North American Mesoscale model (MesoNAM) forecasts to support launch weather operations. In Phase I, the performance of the model at KSC/CCAFS was measured objectively by conducting a detailed statistical analysis of model output compared to observed values. The objective analysis compared the MesoNAM forecast winds, temperature, and dew point to the observed values from the sensors in the KSC/CCAFS wind tower network. In Phase II, the AMU modified the current tool by adding an additional 15 months of model output to the database and recalculating the verification statistics. The bias, standard deviation of bias, Root Mean Square Error, and Hypothesis test for bias were calculated to verify the performance of the model. The results indicated that the accuracy decreased as the forecast progressed, there was a diurnal signal in temperature with a cool bias during the late night and a warm bias during the afternoon, and there was a diurnal signal in dewpoint temperature with a low bias during the afternoon and a high bias during the late night.

A Hierarchical Approach to Fracture Mechanics

NASA Technical Reports Server (NTRS)

Saether, Erik; Taasan, Shlomo

2004-01-01

Recent research conducted under NASA LaRC's Creativity and Innovation Program has led to the development of an initial approach for a hierarchical fracture mechanics. This methodology unites failure mechanisms occurring at different length scales and provides a framework for a physics-based theory of fracture. At the nanoscale, parametric molecular dynamic simulations are used to compute the energy associated with atomic level failure mechanisms. This information is used in a mesoscale percolation model of defect coalescence to obtain statistics of fracture paths and energies through Monte Carlo simulations. The mathematical structure of predicted crack paths is described using concepts of fractal geometry. The non-integer fractal dimension relates geometric and energy measures between meso- and macroscales. For illustration, a fractal-based continuum strain energy release rate is derived for inter- and transgranular fracture in polycrystalline metals.

Composite S-layer lipid structures

PubMed Central

Schuster, Bernhard; Sleytr, Uwe B.

2010-01-01

Designing and utilization of biomimetic membrane systems generated by bottom-up processes is a rapidly growing scientific and engineering field. Elucidation of the supramolecular construction principle of archaeal cell envelopes composed of S-layer stabilized lipid membranes led to new strategies for generating highly stable functional lipid membranes at meso- and macroscopic scale. In this review, we provide a state of the art survey how S-layer proteins, lipids, and polysaccharides may be used as basic building blocks for the assembly of S-layer supported lipid membranes. These biomimetic membrane systems are distinguished by a nanopatterned fluidity, enhanced stability and longevity and thus, provide a dedicated reconstitution matrix for membrane-active peptides and transmembrane proteins. Exciting areas for application of composite S-layer membrane systems concern sensor systems involving specific membrane functions. PMID:19303933

Isolating causal pathways between flow and fish in the regulated river hierarchy

DOE Office of Scientific and Technical Information (OSTI.GOV)

McManamay, Ryan A.; Peoples, Brandon K.; Orth, Donald J.

Unregulated river systems are organized in a hierarchy in which large-scale factors (i.e., landscape and segment scales) influence local habitats (i.e., reach, meso-, and microhabitat scales), and both differentially exert selective pressures on biota. Dams, however, create discontinua in these processes and change the hierarchical structure. We examined the relative roles of hydrology and other instream factors, within a hierarchical landscape context, in organizing fish communities in regulated and unregulated tributaries to the Upper Tennessee River, USA. We also used multivariate regression trees to identify factors that partition fish assemblages based on trait similarities, irrespective of spatial scale. Then, wemore » used classical path analysis and structural equation modeling to evaluate the most plausible hierarchical causal structure of specific trait-based community components, given the data. Both statistical approaches suggested that river regulation affects stream fishes through a variety of reach-scale variables, not always through hydrology itself. Though we observed different changes in flow, temperature, and biotic responses according to regulation types, the most predominant path in which dam regulation affected biota was via temperature alterations. Diversion dams had the strongest effects on fish assemblages. Diversion dams reduced flow magnitudes, leading to declines in fish richness but increased temperatures, leading to lower abundances in equilibrium species and nest guarders. Peaking and run-of-river dams increased flow variability, leading to lower abundances in nest-guarding fishes. Flow displayed direct relationships with biotic responses; however, results indicated that changes in temperature and substrate had equal, if not stronger, effects on fish assemblage composition. The strength and nature of relationships depended on whether flow metrics were standardized for river size. Here, we suggest that restoration efforts in regulated rivers focus on improving flow conditions in conjunction with temperature and substrate restoration.« less

Isolating causal pathways between flow and fish in the regulated river hierarchy

DOE PAGES

McManamay, Ryan A.; Peoples, Brandon K.; Orth, Donald J.; ...

2015-07-07

Unregulated river systems are organized in a hierarchy in which large-scale factors (i.e., landscape and segment scales) influence local habitats (i.e., reach, meso-, and microhabitat scales), and both differentially exert selective pressures on biota. Dams, however, create discontinua in these processes and change the hierarchical structure. We examined the relative roles of hydrology and other instream factors, within a hierarchical landscape context, in organizing fish communities in regulated and unregulated tributaries to the Upper Tennessee River, USA. We also used multivariate regression trees to identify factors that partition fish assemblages based on trait similarities, irrespective of spatial scale. Then, wemore » used classical path analysis and structural equation modeling to evaluate the most plausible hierarchical causal structure of specific trait-based community components, given the data. Both statistical approaches suggested that river regulation affects stream fishes through a variety of reach-scale variables, not always through hydrology itself. Though we observed different changes in flow, temperature, and biotic responses according to regulation types, the most predominant path in which dam regulation affected biota was via temperature alterations. Diversion dams had the strongest effects on fish assemblages. Diversion dams reduced flow magnitudes, leading to declines in fish richness but increased temperatures, leading to lower abundances in equilibrium species and nest guarders. Peaking and run-of-river dams increased flow variability, leading to lower abundances in nest-guarding fishes. Flow displayed direct relationships with biotic responses; however, results indicated that changes in temperature and substrate had equal, if not stronger, effects on fish assemblage composition. The strength and nature of relationships depended on whether flow metrics were standardized for river size. Here, we suggest that restoration efforts in regulated rivers focus on improving flow conditions in conjunction with temperature and substrate restoration.« less

Synthesis of "Meso"-Diethyl-2,2'-Dipyrromethane in Water: An Experiment in Green Organic Chemistry

ERIC Educational Resources Information Center

Sobral, Abilio J. F. N.

2006-01-01

Dipyrromethanes (or dipyrrilmethanes) are important building blocks for many of the structures of interest in the areas of porphyrins, materials science, optics, and medicine. A variety of conditions have been established for the synthesis of dipyrromethanes of diverse structures, from substituted pyrroles to unsubstituted pyrrole and carbonyl…

SamuROI, a Python-Based Software Tool for Visualization and Analysis of Dynamic Time Series Imaging at Multiple Spatial Scales.

PubMed

Rueckl, Martin; Lenzi, Stephen C; Moreno-Velasquez, Laura; Parthier, Daniel; Schmitz, Dietmar; Ruediger, Sten; Johenning, Friedrich W

2017-01-01

The measurement of activity in vivo and in vitro has shifted from electrical to optical methods. While the indicators for imaging activity have improved significantly over the last decade, tools for analysing optical data have not kept pace. Most available analysis tools are limited in their flexibility and applicability to datasets obtained at different spatial scales. Here, we present SamuROI (Structured analysis of multiple user-defined ROIs), an open source Python-based analysis environment for imaging data. SamuROI simplifies exploratory analysis and visualization of image series of fluorescence changes in complex structures over time and is readily applicable at different spatial scales. In this paper, we show the utility of SamuROI in Ca 2+ -imaging based applications at three spatial scales: the micro-scale (i.e., sub-cellular compartments including cell bodies, dendrites and spines); the meso-scale, (i.e., whole cell and population imaging with single-cell resolution); and the macro-scale (i.e., imaging of changes in bulk fluorescence in large brain areas, without cellular resolution). The software described here provides a graphical user interface for intuitive data exploration and region of interest (ROI) management that can be used interactively within Jupyter Notebook: a publicly available interactive Python platform that allows simple integration of our software with existing tools for automated ROI generation and post-processing, as well as custom analysis pipelines. SamuROI software, source code and installation instructions are publicly available on GitHub and documentation is available online. SamuROI reduces the energy barrier for manual exploration and semi-automated analysis of spatially complex Ca 2+ imaging datasets, particularly when these have been acquired at different spatial scales.

SamuROI, a Python-Based Software Tool for Visualization and Analysis of Dynamic Time Series Imaging at Multiple Spatial Scales

PubMed Central

Rueckl, Martin; Lenzi, Stephen C.; Moreno-Velasquez, Laura; Parthier, Daniel; Schmitz, Dietmar; Ruediger, Sten; Johenning, Friedrich W.

2017-01-01

The measurement of activity in vivo and in vitro has shifted from electrical to optical methods. While the indicators for imaging activity have improved significantly over the last decade, tools for analysing optical data have not kept pace. Most available analysis tools are limited in their flexibility and applicability to datasets obtained at different spatial scales. Here, we present SamuROI (Structured analysis of multiple user-defined ROIs), an open source Python-based analysis environment for imaging data. SamuROI simplifies exploratory analysis and visualization of image series of fluorescence changes in complex structures over time and is readily applicable at different spatial scales. In this paper, we show the utility of SamuROI in Ca2+-imaging based applications at three spatial scales: the micro-scale (i.e., sub-cellular compartments including cell bodies, dendrites and spines); the meso-scale, (i.e., whole cell and population imaging with single-cell resolution); and the macro-scale (i.e., imaging of changes in bulk fluorescence in large brain areas, without cellular resolution). The software described here provides a graphical user interface for intuitive data exploration and region of interest (ROI) management that can be used interactively within Jupyter Notebook: a publicly available interactive Python platform that allows simple integration of our software with existing tools for automated ROI generation and post-processing, as well as custom analysis pipelines. SamuROI software, source code and installation instructions are publicly available on GitHub and documentation is available online. SamuROI reduces the energy barrier for manual exploration and semi-automated analysis of spatially complex Ca2+ imaging datasets, particularly when these have been acquired at different spatial scales. PMID:28706482

Multiscale wind cycles and current pulses at the Black Sea eastern boundary

NASA Astrophysics Data System (ADS)

Melnikov, Vasiliy; Moskalenko, Lidija; Piotoukh, Vladimir; Zatsepin, Andrey

2015-04-01

The goal of the research is to examine meteorological descriptive elements, sea-water properties, regional hydrodynamics and energy conversion fluxes in order to study sea responses to the local and far-field weather system. The Black Sea is situated in the chain of internal basins between the North Atlantic and Central Asia deserts in the marginal interaction zone and, accordingly, is under the influence of the Azores and Siberian anticyclones, Arctic cold-air surges and subtropical desert belt to the south. The analysis is based on the data of modern oceanographic measuring network "Hydro-physical Polygon" of the Institute of oceanology, using contact and remote sensing methods, weather stations around the Black Sea coasts, including long-term (1938-2014) measurements at the Gelendzhik weather station. Various satellite and Reanalysis databases are used. Currently, there are three long-time measuring moored stations (each contains ADCP and thermistor chain) and scanning profiling system "Akvalog". Hydrological sections and field surveys using towed ADCP and CTD are performed on a regular basis. The data are accumulated in the coastal archive which allows calibration of satellite measurements and testing results of numerical modeling. Data processing includes data sets preparation, editing, time series statistical calculations using histograms, progressive vector diagrams, traditional Fourier spectral analysis including auto- and cross spectra, auto and mutual wavelet diagrams, moving spectrograms, vector data methods using rotary components, spectral invariants, empirical modes, hodograph and pre-specified spectrum representations on the basis of stochastic models with imposed dynamical assumptions. Due to the intermittent nature of the time rows, spectral representation is misleading, often. In order to identify the individual evolving dynamical phenomenon, typical background (seasonal) three-dimensional structures of the hydrological field, as well as quantified anomalies, associated with different frequency components of variability, such as sub-meso-scale eddies, marginal shelf waves, inertial oscillations, diurnal, semi-diurnal and short-period internal waves, long surface waves, were estimated. Based on estimates of the statistical relationships between the different parameters of hydro-meteorological system, including meteorological elements, sea level, sea temperature and flow fields, space/time scales of the observed fields variability were estimated. Several new features of the physical mechanisms of multiscale hydro-physical processes in the shelf zone of the Black Sea, have been revealed. In particular, it is shown, that there are wind self-similar cycles at different time scales, each cycle being consisted of a pair of northeast and then southeast winds, which corresponds to the alternative influences of the Azores and Siberian highs(in winter). In the range of decadal (10 years) scale and in macro space view, long-term wind cycles support basic Black Sea circulation(Rim Current).Wind cycles with a time scale of about 20 days give rise to distinct upwellings, appeared with the same frequency. Along with each upwelling, radical hydrological restructuring of the stratification is accompanied by intense advection with high velocities(up to 1 m/s). Kinetic energy is dominated by alongshore currents, the direction being reversed periodically. The vertical structure of currents is rather complicated. When the current speed exceeds some threshold value, the flow gives rise to relaxation oscillations with a period of about 24 hours with counterclockwise velocity vector rotation. All the above mentioned events and current pulses cause significant variations of air-sea fluxes. This research was jointly supported by Ministry of Education of the RF (Agreement №14.604.21.0044), Russian Academy of Sciences(Program No 23), RFBR grant 14-05-00159,contract No 10/2013 RGS-RFBR.

Stratigraphic and structural relationships between Meso-Cenozoic Lagonegro basin and coeval carbonate platforms in southern Apennines, Italy

NASA Astrophysics Data System (ADS)

Pescatore, Tullio; Renda, Pietro; Schiattarella, Marcello; Tramutoli, Mariano

1999-12-01

Stratigraphic studies and facies analysis integrated with a new geological and structural survey of the Meso-Cenozoic units outcropping in the Campania-Lucania Apennines, southern Italy, allowed us to restore the palaeogeographic pattern and the tectonic evolution of the chain during Oligo-Miocene times. The southern Apennines are a N150°-striking and NE-verging fold-and-thrust belt mainly derived from the deformation of the African-Apulian passive margin. Four wide belts with different features have been recognized in the chain area. From east to west the following units outcrop: (a) successions characterized by basinal to marginal facies, ranging in age from Cretaceous to Miocene, tectonically lying on Plio-Pleistocene foredeep deposits; (b) successions characterized by shallow-water, basinal and shelf-margin facies, ranging in age from middle Triassic to Miocene ('Lagonegro units'), overthrust on the previous ones; (c) Triassic to Miocene carbonate platform successions ('Apenninic platform units'), overthrust on the Lagonegro units; (d) Jurassic-Cretaceous to Miocene deep-water successions (ophiolite-bearing or 'internal' units and associated siliciclastic wedges), outcropping along the Tyrrhenian belt and the Calabria-Lucania boundary, overthrust on the Apenninic platform units. All these units tectonically lie on the buried Apulian platform which is covered, at least in the eastern sector of the chain, by Pliocene to Pleistocene foredeep deposits. Stratigraphic patterns of the Cretaceous to lower Miocene Lagonegro successions are coherent with the platform margin ones. Calcareous clastics of the Lagonegro basin are in fact supplied by an adjacent western platform, as inferred by several sedimentological evidences (slump and palaeocurrent directions and decreasing grain size towards the depocentre of the basin). Tectonic relationships among the different units of the chain — with particular emphasis on the Lagonegro and Apenninic platform units of the Lucanian segment — are shown by means of both regional and detailed geological cross-sections. The Lagonegro units constantly underlie the carbonate units originating from detachment and thrusting of the western platform and overlie the eastern (i.e. Apulian) platform. The Lagonegro units show a strong lateral variability of map-scale structures. Dome-and-basin folds are in fact largely observable in the Lucanian Apennine. Further, the belt is widely affected by Plio-Quaternary strike-slip and extensional faults. Yet, excluding the brittle deformation due to Quaternary faulting, the complexity of structural styles seems to result from the Neogene refolding of more ancient structures produced by Oligo-Miocene intraplate deformation. This hypothesis is supported by two independent lines of evidence: the first is the recognition of unconformities between the lower Miocene Numidian sandstone and the underlying Lagonegro successions, at least in the southwestern sectors; the second is that the internal (i.e. western) platform remains undeformed until the early Miocene. Both stratigraphic and structural data suggest an external position of the Meso-Cenozoic Lagonegro basin with regard to the coeval Apenninic platform.

The Vertical Transport in the Ocean: a Pump Driven by Meso and Submesoscale Structures

NASA Astrophysics Data System (ADS)

Rosso, I.; Hogg, A. M.; Strutton, P. G.; Kiss, A. E.

2012-04-01

The upper ocean can be considered as a vehicle for the exchange of gases between air and the deep ocean. Furthermore, the transport of nutrients through the mixed layer occurs via a combination of biogeochemical and physical pumps; both of these mechanisms play a fundamental role in the carbon cycle. In the surface layer phytoplankton convert carbon dioxide into organic compounds using nutrients and light. Nutrients, which are depleted at the surface, can be transported into the mixed layer by vertical motion; recently, it has been discovered that this vertical transport is more often associated with submesoscale fronts of O(10) km (rather than inside mesoscale structures, of O(100) km, like eddies). At the submesoscale fronts, rates of O(100) m day-1 can emerge, particularly high compared to values of 10 m/day found at the mesoscales [M. Lèvy, et al. J. Mar. Res., 2001]. At this fine scale, the vertical transport of nutrients is highly effective, upwelling waters from the depth rich of nutrients and downwelling depleted waters from the surface. The fine-scale vertical transport mechanism has recently become of great interest, though is not completely understood. We investigate the dynamics and the transport of tracers at the meso and sub-mesoscales by running numerical simulations with a domain of 1024 km x 512 km x 1600 m, at 3 different resolutions: 8 km, 4km and 1km. We use the MIT general circulation model with free surface, linear bottom drag and free slip condition at the north and south walls. Non-linear 3rd order advection scheme and biharmonic viscosity are applied. Furthermore, the fluid is forced by a constant zonal wind stress. The flow is zonally periodic and presents an idealized topography. We started from an initial vertical stratification and run the model to reach an equilibrium flow state. A passive tracer is released after the equilibrium is reached. We investigate how the fine scales are affecting the rate of vertical transport and the distribution of the tracer. We show that also the presence of the topography has an impact in driving this transport. Furthermore, the model can run in a non-hydrostatic configuration, allowing us to investigate the effect of this parameterization on the transport.

Crystal structures and catalytic performance of three new methoxy substituted salen type nickel(II) Schiff base complexes derived from meso-1,2-diphenyl-1,2-ethylenediamine

NASA Astrophysics Data System (ADS)

Ghaffari, Abolfazl; Behzad, Mahdi; Pooyan, Mahsa; Amiri Rudbari, Hadi; Bruno, Giuseppe

2014-04-01

Three new nickel(II) complexes of a series of methoxy substituted salen type Schiff base ligands were synthesized and characterized by IR, UV-Vis and 1H NMR spectroscopy and elemental analysis. The ligands were synthesized from the condensation of meso-1,2-diphenyl-1,2-ethylenediamine with n-methoxysalicylaldehyde (n = 3, 4 and 5). Crystal structures of these complexes were determined. Electrochemical behavior of the complexes was studied by means of cyclic voltammetry in DMSO solutions. Catalytic performance of the complexes was studied in the epoxidation of cyclooctene using tert-butylhydroperoxide (TBHP) as oxidant under various conditions to find the optimum operating parameters. Low catalytic activity with moderate epoxide selectivity was observed in in-solvent conditions but in the solvent-free conditions, enhanced catalytic activity with high epoxide selectivity was achieved.

Meso-beta scale numerical simulation studies of terrain-induced jet streak mass/momentum perturbations

NASA Technical Reports Server (NTRS)

Lin, Yuh-Lang; Kaplan, Michael L.

1992-01-01

Work performed during the report period is summarized. The first numerical experiment which was performed on the North Carolina Supercomputer Center's CRAY-YMP machine during the second half of FY92 involved a 36 hour simulation of the CCOPE case study. This first coarse-mesh simulation employed the GMASS model with a 178 x 108 x 32 matrix of grid points spaced approximately 24 km apart. The initial data was comprised of the global 2.5 x 2.5 degree analyses as well as all available North American rawinsonde data valid at 0000 UTC 11 July 1981. Highly-smoothed LFM-derived terrain data were utilized so as to determine the mesoscale response of the three-dimensional atmosphere to weak terrain forcing prior to including the observed highly complex terrain of the northern Rocky Mountain region. It was felt that the model should be run with a spectrum of terrain geometries, ranging from observed complex terrain to no terrain at all, to determine how crucial the terrain was in forcing the mesoscale phenomena. Both convection and stratiform (stable) precipitation were not allowed in this simulation so that their relative importance could be determined by inclusion in forth-coming simulations. A full suite of planetary boundary layer forcing was allowed in the simulation, including surface sensible and latent heat fluxes employing the Blakadar PBL formulation. The details of this simulation, which in many ways could be considered the control simulation, including the important synoptic-scale, meso-alpha scale, and meso-beta scale circulations is described. These results are compared to the observations diagnosed by Koch and his colleagues as well as hypotheses set forth in the project proposal for terrain-influences upon the jet stream and their role in the generation of mesoscale wave phenomenon. The fundamental goal of the analyses being the discrimination among background geostrophic adjustment, terrain influences, and shearing instability in the initiation and maintainance of mesoscale internal wave phenomena. Based upon these findings, FY93 plans are discussed. A review of linear theory and theoretical modeling of a geostrophic zonal wind anomaly is included.

Lagrangian Statistics and Intermittency in Gulf of Mexico.

PubMed

Lin, Liru; Zhuang, Wei; Huang, Yongxiang

2017-12-12

Due to the nonlinear interaction between different flow patterns, for instance, ocean current, meso-scale eddies, waves, etc, the movement of ocean is extremely complex, where a multiscale statistics is then relevant. In this work, a high time-resolution velocity with a time step 15 minutes obtained by the Lagrangian drifter deployed in the Gulf of Mexico (GoM) from July 2012 to October 2012 is considered. The measured Lagrangian velocity correlation function shows a strong daily cycle due to the diurnal tidal cycle. The estimated Fourier power spectrum E(f) implies a dual-power-law behavior which is separated by the daily cycle. The corresponding scaling exponents are close to -1.75 and -2.75 respectively for the time scale larger (resp. 0.1 ≤ f ≤ 0.4 day -1 ) and smaller (resp. 2 ≤ f ≤ 8 day -1 ) than 1 day. A Hilbert-based approach is then applied to this data set to identify the possible multifractal property of the cascade process. The results show an intermittent dynamics for the time scale larger than 1 day, while a less intermittent dynamics for the time scale smaller than 1 day. It is speculated that the energy is partially injected via the diurnal tidal movement and then transferred to larger and small scales through a complex cascade process, which needs more studies in the near future.

Analysis of erythritol in foods by polyclonal antibody-based indirect competitive ELISA.

PubMed

Sreenath, Kundimi; Venkatesh, Yeldur P

2008-05-01

Sugar alcohols are widely used as food additives and drug excipients. Erythritol (INS 968) is an important four-carbon sugar alcohol in the food industry. Erythritol occurs naturally in certain fruits, vegetables, and fermented foods. Currently, HPLC and GC methods are in use for the quantification of erythritol in natural/processed foods. However, an immunoassay for erythritol has not been developed so far. We have utilized affinity-purified erythritol-specific antibodies generated earlier [9] to develop an indirect competitive ELISA. With erythritol-BSA conjugate (54 mol/mol; 100 ng/well) as the coating antigen, a calibration curve was prepared using known amounts of standard meso-erythritol (0.1-100,000 ng) in the immunoassay. Watermelon (Citrullus lanatus) and red wine were selected as the food sources containing meso-erythritol. The amount of meso-erythritol was calculated as 2.36 mg/100 g fresh weight of watermelon and 206.7 mg/L of red wine. The results obtained from the immunoassay are in close agreement with the reported values analyzed by HPLC and GC (22-24 mg/kg in watermelon and 130-300 mg/L in red wine). The recovery analyses showed that added amounts of meso-erythritol were recovered fairly accurately with recoveries of 86-105% (watermelon) and 85-93.3% (red wine). The method described here for erythritol is the first report of an immunoassay for a sugar alcohol.

Impact of upper-level fine-scale structures in the deepening of a Mediterranean "hurricane"

NASA Astrophysics Data System (ADS)

Claud, C.; Chaboureau, J.-P.; Argence, S.; Lambert, D.; Richard, E.; Gauthier, N.; Funatsu, B.; Arbogast, P.; Maynard, K.; Hauchecorne, A.

2009-09-01

Subsynoptic scale vortices that have been likened to tropical cyclones or polar lows (Medicanes) are occasionally observed over the Mediterranean Sea. They are usually associated with strong winds and heavy precipitation and thus can have highly destructive effects in densely-populated regions. Only a precise forecasting of such systems could mitigate these effects. In this study, the role of an approaching upper-level Potential Vorticity (PV) maximum close to the vicinity of a Medicane which appeared early in the morning of 26 September 2006 over the Ionian Sea and moved north-eastwards affecting Apulia, is evaluated using the anelastic non-hydrostatic model Méso-NH initialized with forecasts from ARPEGE, the French operational forecasting system. To this end, in a first step, high resolution PV fields have been determined using a semi-Lagrangian advection model, MIMOSA (Modelisation Isentrope du transport Meso-echelle de l'Ozone Stratospherique par Advection). MIMOSA PV fields at and around 320 K for 25 September 2006 at 1800 UTC clearly show a stratospheric intrusion under the form of a filament crossing UK, western Europe and the Tyrrhenian Sea. MIMOSA fields show a number of details that do not appear in ECMWF analysed PV fields, and in particular an area of high PV values just west of Italy over the Tyrrhenian Sea. While the overall structure of the filament is well described by ARPEGE analysis, the high PV values in the Tyrrhenian Sea close to the coast of Italy are missing. In order to take into account these differences, ARPEGE upper-level fields have been corrected after a PV inversion guided by MIMOSA fields. Modifications of PV in ARPEGE lead to a deepest system and improved rain fields (both in location and intensity), when evaluated against ground-based observations. In a second step, Meso-NH simulations coupled with corrected and non-corrected ARPEGE forecasts have been performed. The impact of the corrections on the intensity, the trajectory and the associated precipitation has been evaluated using in situ and satellite observations, in the latter case through a model to satellite approach. When the PV corrections are applied, the track of the simulated Medicane is closer to the observed one. The deepening of the low is also better reproduced, even if it is over-estimated (982 hPa instead of 986 hPa), as well as the precipitation. This study confirms the role of fine-scale upper level structures for short range forecasting of sub-synoptic vortices over the Mediterranean Sea. It also suggests that ensemble prediction models should include perturbations related to upper-level coherent structures.

Effect of Impact Compression on the Age-Hardening of Rapidly Solidified Al-Zn-Mg Base Alloys

NASA Astrophysics Data System (ADS)

Horikawa, Keitaro; Kobayashi, Hidetoshi

Effect of impact compression on the age-hardening behavior and the mechanical properties of Mesoalite aluminum alloy was examined by means of the high-velocity plane collision between a projectile and Mesoalite by using a single powder gun. By imposing the impact compression to the Meso10 and Meso20 alloys in the state of quenching after the solution heat treatment, the following age-hardening at 110 °C was highly increased, comparing with the Mesoalite without the impact compression. XRD results revealed that high plastic strain was introduced on the specimen inside after the impact compression. Compression test results also clarified that both Meso10 and Meso20 alloy specimens imposed the impact compressive stresses more than 5 GPa after the peak-aging at 110°C showed higher yield stresses, comparing with the alloys without the impact compression. It was also shown that the Meso10 and Meso20 specimens after the solution heat treatment, followed by the high-velocity impact compression (12 GPa) and the peak-aging treatment indicated the highest compressive yield stresses such as 994 GPa in Meso10 and 1091 GPa in Meso20.

Movement sense determination in sheared rocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Simpson, C.

1985-01-01

Deformation within fault zones produces sheared rocks that range from cataclasites at high structural level, to mylonites and mylonitic gneiss at deeper levels. These rocks are easily recognized and mapped in the field and the strike and dip of the fault zone established. However, present-day geometry of the fault zone does not necessarily indicate relative motion - a zone dipping at 15/sup 0/ could represent a listric normal, thrust, oblique-slip or tilted strike-slip fault. Where offset stratigraphic or lithological markers are absent, the movement sense may be determined from meso- and micro-structural features within the sheared rocks. Of prime importancemore » is the orientation of mineral elongation or stretching lineations which record the finite X direction of strain in the rock; this direction approaches the bulk movement direction with increase in strain. At mesoscopic scale the most reliable shear sense indicators are shear bands and associated features. Use of fold vergence requires caution. On a micro-structural scale, shear bands, mica fish, microfolds, rotated grains, asymmetrical augen structure and fiber growth patterns all give reliable results. Thin sections should be cut parallel to lineation and perpendicular to foliation in order to view maximum rotational component. Asymmetry of crystallographic fabric patterns gives consistent results in zones of relatively simple movement history. For high confidence shear sense determination, all structural elements should be internally consistent. If inconsistency occurs this may indicate a complex, multidirectional movement history for the fault zone.« less

Two-Scale Simulation of Drop-Induced Failure of Polysilicon MEMS Sensors

PubMed Central

Mariani, Stefano; Ghisi, Aldo; Corigliano, Alberto; Martini, Roberto; Simoni, Barbara

2011-01-01

In this paper, an industrially-oriented two-scale approach is provided to model the drop-induced brittle failure of polysilicon MEMS sensors. The two length-scales here investigated are the package (macroscopic) and the sensor (mesoscopic) ones. Issues related to the polysilicon morphology at the micro-scale are disregarded; an upscaled homogenized constitutive law, able to describe the brittle cracking of silicon, is instead adopted at the meso-scale. The two-scale approach is validated against full three-scale Monte-Carlo simulations, which allow for stochastic effects linked to the microstructural properties of polysilicon. Focusing on inertial MEMS sensors exposed to drops, it is shown that the offered approach matches well the experimentally observed failure mechanisms. PMID:22163885

Modeling and Characterization of Near-Crack-Tip Plasticity from Micro- to Nano-Scales

NASA Technical Reports Server (NTRS)

Glaessgen, Edward H.; Saether, Erik; Hochhalter, Jacob; Smith, Stephen W.; Ransom, Jonathan B.; Yamakov, Vesselin; Gupta, Vipul

2010-01-01

Methodologies for understanding the plastic deformation mechanisms related to crack propagation at the nano-, meso- and micro-length scales are being developed. These efforts include the development and application of several computational methods including atomistic simulation, discrete dislocation plasticity, strain gradient plasticity and crystal plasticity; and experimental methods including electron backscattered diffraction and video image correlation. Additionally, methodologies for multi-scale modeling and characterization that can be used to bridge the relevant length scales from nanometers to millimeters are being developed. The paper focuses on the discussion of newly developed methodologies in these areas and their application to understanding damage processes in aluminum and its alloys.

Modeling and Characterization of Near-Crack-Tip Plasticity from Micro- to Nano-Scales

NASA Technical Reports Server (NTRS)

Glaessgen, Edward H.; Saether, Erik; Hochhalter, Jacob; Smith, Stephen W.; Ransom, Jonathan B.; Yamakov, Vesselin; Gupta, Vipul

2011-01-01

Methodologies for understanding the plastic deformation mechanisms related 10 crack propagation at the nano, meso- and micro-length scales are being developed. These efforts include the development and application of several computational methods including atomistic simulation, discrete dislocation plasticity, strain gradient plasticity and crystal plasticity; and experimental methods including electron backscattered diffraction and video image correlation. Additionally, methodologies for multi-scale modeling and characterization that can be used to bridge the relevant length scales from nanometers to millimeters are being developed. The paper focuses on the discussion of newly developed methodologies in these areas and their application to understanding damage processes in aluminum and its alloys.

Porphyrins and their synthesis from dipyrromethanes and aldehydes

DOEpatents

Wijesekera, Tilak; Lyons, James E.; Ellis, Jr., Paul E.

1998-01-01

The invention comprises new compositions of matter, which are iron, manganese, cobalt or ruthenium complexes of porphyrins having hydrogen, haloalkyl or haloaryl groups in meso positions, two of the opposed meso atoms or groups being hydrogen or haloaryl, and two of the opposed meso atoms or groups being hydrogen or haloalkyl, but not all four of the meso atoms or groups being hydrogen. The invention also comprises new compositions of matter in which all four of the meso positions are substituted with haloalkyl groups and the beta positions are substituted with halogen atoms. A new method of synthesizing porphyrinogens is also provided.

Porphyrins and their synthesis from dipyrromethanes and aldehydes

DOEpatents

Wijesekera, T.; Lyons, J.E.; Ellis, P.E. Jr.

1998-06-02

The invention comprises new compositions of matter, which are iron, manganese, cobalt or ruthenium complexes of porphyrins having hydrogen, haloalkyl or haloaryl groups in meso positions, two of the opposed meso atoms or groups being hydrogen or haloaryl, and two of the opposed meso atoms or groups being hydrogen or haloalkyl, but not all four of the meso atoms or groups being hydrogen. The invention also comprises new compositions of matter in which all four of the meso positions are substituted with haloalkyl groups and the beta positions are substituted with halogen atoms. A new method of synthesizing porphyrinogens is also provided.

GFS-10/10/2007-12Z

Science.gov Websites

Mountainous Coasts: A change to the GFS post codes will remove a persistent, spurious high pressure system ENVIRONMENTAL PREDICTION /NCEP/ WILL UPGRADE THE GFS POST PROCESSOR. THE PRIMARY EFFORT BEHIND THIS UPGRADE WILL BE TO UNIFY THE POST PROCESSING CODE FOR THE NORTH AMERICAN MESO SCALE /NAM/ MODEL AND THE GFS INTO

Oak Seedling Establishment in Relation to Environmental Factors at Annadel State Park

Treesearch

Stephen J. Barnhart; Joe R. McBride; Peter Warner

1991-01-01

As part of an ongoing study of oak ecology in Sonoma County, California, we have begun to evaluate various environmental factors relative to oak seedling establishment at Annadel State Park. These factors, identified at three spatial scales (macro, meso and microscales), were correlated with the presence of oak seedlings in two contrasting northern oak woodland...

“FEST-C 1.0 for CMAQ Bi-directional NH3 Modeling and Apatial Allocator 4.1”

EPA Science Inventory

Accurate estimation of ammonia emissions in space and time has been a challenge in meso-scale air quality modeling. For instance, fertilizer applications vary in the date of application and amount by crop types and geographical area. With the support of the U.S EPA, we have devel...

Income Inequality across Micro and Meso Geographic Scales in the Midwestern United States, 1979-2009

ERIC Educational Resources Information Center

Peters, David J.

2012-01-01

This article examines the spatial distribution of income inequality and the socioeconomic factors affecting it using spatial analysis techniques across 16,285 block groups, 5,050 tracts, and 618 counties in the western part of the North Central Region of the United States. Different geographic aggregations result in different inequality outcomes,…

Testing Timescales for Rhythms Recorded in the 2.5 Ga Banded Iron Formation of the Dales Gorge Member (Brockman Iron Formation, Hamersley Group, Australia)

NASA Astrophysics Data System (ADS)

Hinnov, L. A.; de Oliveira Carvalho Rodrigues, P.; Franco, D.

2017-12-01

The classic, Superior-type banded iron formation (BIF) of the Precambrian Dales Gorge Member (DGM) of the Brockman Iron Formation, Hamersley Basin, Western Australia consists of a succession of micro- (millimeter-scale) and meso- (centimeter to decimeter-scale) bands of primarily iron-silica chemical sediment alternations, separated into macro- (meter to decameter-scale) bands by shales (1). Here, we present a time-frequency analysis of a gray-scale scan of the DGM "type section core" Hole 47A with small contributions from Hole EC10 (1) to provide a comprehensive characterization of banding patterns and periodicity throughout the 140 m section. SHRIMP zircon ages (2) indicate that the DGM was deposited over approximately 30 myr during the Archean-Proterozoic transition just prior to the Great Oxidation Event. This suggests that the banding patterns recorded Milankovitch cycles, although with orbital-rotational parameters significantly different from present-day due to Earth's tidal dissipation and chaotic episodes in the Solar System since 2.5 Ga. Banding patterns change systematically within the formation in response to slowly varying environmental conditions, which have been interpreted previously to be related to sea level change and basin evolution (3). Researchers, including (2), have questioned the 30 myr duration, suggesting instead that the micro-bands may be annual in scale. This would indicate a much shorter duration of less than 150 kyr for the DGM. In an attempt to determine whether Milankovitch cycles could have generated the meso-band patterns, we present detailed studies of BIF0 and BIF12, which typify the marked changes in meso-banding along the section. Objective procedures are also applied, including ASM (4) and TIMEOPT (5) to test for a range of potential alternative timescales assuming orbital-rotational parameter values modeled for 2.5 Ga. References: (1) Trendall, A.K., Blockley, J.G., GSWA Ann. Rep. 1967, 48, 1968; (2) Trendall, A.K., et al., Austr. J. Earth Sci., 51, 621, 2004; (3) Pickard, A., Barley, M., Krapez, B., Sed. Geol., 170, 37, 2004; (4) Meyers, S.R., Sageman, B.B., Amer. J. Sci., 307, 773, 2007; (5) Meyers, S.R., Paleocean., 30, 2015.

Multi-scale coupled modelling of waves and currents on the Catalan shelf.

NASA Astrophysics Data System (ADS)

Grifoll, M.; Warner, J. C.; Espino, M.; Sánchez-Arcilla, A.

2012-04-01

Catalan shelf circulation is characterized by a background along-shelf flow to the southwest (including some meso-scale features) plus episodic storm driven patterns. To investigate these dynamics, a coupled multi-scale modeling system is applied to the Catalan shelf (North-western Mediterranean Sea). The implementation consists of a set of increasing-resolution nested models, based on the circulation model ROMS and the wave model SWAN as part of the COAWST modeling system, covering from the slope and shelf region (~1 km horizontal resolution) down to a local area around Barcelona city (~40 m). The system is initialized with MyOcean products in the coarsest outer domain, and uses atmospheric forcing from other sources for the increasing resolution inner domains. Results of the finer resolution domains exhibit improved agreement with observations relative to the coarser model results. Several hydrodynamic configurations were simulated to determine dominant forcing mechanisms and hydrodynamic processes that control coastal scale processes. The numerical results reveal that the short term (hours to days) inner-shelf variability is strongly influenced by local wind variability, while sea-level slope, baroclinic effects, radiation stresses and regional circulation constitute second-order processes. Additional analysis identifies the significance of shelf/slope exchange fluxes, river discharge and the effect of the spatial resolution of the atmospheric fluxes.

NMMB/BSC-DUST: an online mineral dust atmospheric model from meso to global scales

NASA Astrophysics Data System (ADS)

Haustein, K.; Pérez, C.; Jorba, O.; Baldasano, J. M.; Janjic, Z.; Black, T.; Nickovic, S.

2009-04-01

While mineral dust distribution and effects are important at global scales, they strongly depend on dust emissions that are controlled on small spatial and temporal scales. Most global dust models use prescribed wind fields provided by meteorological centers (e.g., NCEP and ECMWF) and their spatial resolution is currently never better than about 1°×1°. Regional dust models offer substantially higher resolution (10-20 km) and are typically coupled with weather forecast models that simulate processes that GCMs either cannot resolve or can resolve only poorly. These include internal circulation features such as the low-level nocturnal jet which is a crucial feature for dust emission in several dust ‘hot spot' sources in North Africa. Based on our modeling experience with the BSC-DREAM regional forecast model (http://www.bsc.es/projects/earthscience/DREAM/) we are currently implementing an improved mineral dust model [Pérez et al., 2008] coupled online with the new global/regional NMMB atmospheric model under development in NOAA/NCEP/EMC [Janjic, 2005]. The NMMB is an evolution of the operational WRF-NMME extending from meso to global scales. The NMMB will become the next-generation NCEP model for operational weather forecast in 2010. The corresponding unified non-hydrostatic dynamical core ranges from meso to global scale allowing regional and global simulations. It has got an add-on non-hydrostatic module and it is based on the Arakawa B-grid and hybrid pressure-sigma vertical coordinates. NMMB is fully embedded into the Earth System Modeling Framework (ESMF), treating dynamics and physics separately and coupling them easily within the ESMF structure. Our main goal is to provide global dust forecasts up to 7 days at mesoscale resolutions. New features of the model include a physically-based dust emission scheme after White [1979], Iversen and White [1982] and Marticorena and Bergametti [1995] that takes the effects of saltation and sandblasting into account. Viscous sublayer approach [Janjic, 1994] for dust injection in the lower atmosphere is maintained as applied in DREAM [Nickovic et al., 2001]. Soil moisture effects are considered following Fecan et al. [1999]. A new source function for the land surface is calculated using the USGS 1km landuse database, the NESDIS 5-years monthly climatology for the vegetation fraction, and preferential source areas according the topographic approach after Ginoux et al. [2001]. Furthermore, 4 top soil texture classes (coarse sand, fine/medium sand, silt, clay) are introduced, based on the new STASGO-FAO 1km soil database and modified following Tegen et al. [2002]. The dry deposition scheme accounts for the effects of sedimentation and turbulent mixout following the approach of Giorgi [1986]. Finally, in-cloud and below-cloud wet scavenging for grid-scale and convective precipitation is applied following Slinn [1983; 1984] and Loosmore and Cederwall [2004]. Dust radiative feedback on meteorology is not yet considered. In order to explore the assets and drawbacks of the new model, we perform global simulations of the dust cycle at 0.3°x0.45° to demonstrate the ability of the model to capture the large scale and seasonal patterns. These fundamental evaluations serve as starting point for further testing as well as future developments of the NMMb-DUST. In a second step, we study the behavior of the model during the SAMUM-I phase [Haustein et al., 2009] and the BODEX campaign [Todd et al., 2008], focusing on how the model reproduces moist convection and low level jet in North Africa at mesoscale resolutions. References: Fecan, F., B. Marticorena and G. Bergametti. (1999). Parameterization of the increase of the aeolian erosion threshold wind friction velocity due to soil moisture for arid and semi arid areas. Annales Geophysicae, 17, 149-157. Ginoux, P. et al. (2001). Sources and distribution of dust aerosols simulated with the GOCART model. J. Geophys. Res., 106, D17, 20255-20273. Giorgi, F. (1986). A particle dry-deposition parameterization scheme for use in tracer transport models. J. Geophys. Res., 91, 9794-9804. Haustein, K. et al. (2009). Regional dust model performance during SAMUM-I 2006. Geophys. Res. Letters, in press. Iversen, J.D. and B. R. White (1982). Saltation threshold on Earth, Mars and Venus. Sedimentology, 29, 111-119. Janjic, Z. I. (1994). The Step-Mountain Eta Coordinate Model: Further Developments of the Convection, Viscous Sublayer, and Turbulence Closure Schemes. Monthly Weather Review, 122, 927-945. Janjic, Z. I. (2005). A unified model approach from meso to global scales. Geophysical Research Abstracts, 7, 05582, 2005, EGU05-A-05582. Loosmore, G. A. and Cederwall, R. T. (2004). Precipitation scavenging of atmospheric aerosols for emergency response applications: testing an updated model with new real-time data. Atmospheric Environment, 38, 993-1003. Marticorena, B. and G. Bergametti (1995). Modeling the atmospheric dust cycle: 1. Design of a soil-derived dust emission scheme. J. Geophys. Res., 100, D8, 16415-16430. Nickovic, S., G. Kallos, A. Papadopoulos, and O. Kakaliagou (2001). A model for prediction of desert dust cycle in the atmosphere. Journal of Geophysical Research 106, D16, 18113-18129. Pérez, C. et al. (2008). An online mineral dust model within the global/regional NMMB: Current progress and plans. AGU Fall Meeting, 14-19 December 2008, San Francisco, USA. Slinn, W. G. N. (1983). A potpourri of deposition and resuspension questions. In: Pruppacher, Semonin and Slinn (Editors), Precip. Scavenging., Dry Deposition, and Resuspension. Elsevier, New York (1983), 1361-1416. Slinn, W.G.N. (1984). Precipitation scavenging. In: Randerson, D. (Editor), Atmospheric Science and Power Production. OSTI, Oak Ridge, 466-532. Tegen, I. et al. (2002). Impact of vegetation and preferential source areas on global dust aerosol: Results from a model study. J. Geophys. Res., 107, D21, doi:10.1029/2001JD000963. Todd, M. (2008). Quantifying uncertainty in estimates of mineral dust flux: An intercomparison of model performance over the Bodele Depression, northern Chad. J. Geophys. Res., 113, D24107, doi:10.1029/2008JD010476. White, B. (1979). Soil transport by winds on Mars. J. Geophys. Res., 84, 4643-4651.

Obesity and the built environment at different urban scales: examining the literature.

PubMed

Garfinkel-Castro, Andrea; Kim, Keuntae; Hamidi, Shima; Ewing, Reid

2017-01-01

The majority of people now live in an urban (or suburban) environment. The built (material) environment, its vehicular and pedestrian infrastructure, buildings, and public realm places, are the places used for working, living, and recreating. The environment currently favors and facilitates motorized vehicles generally, and private automobiles especially. The prioritization given to vehicles reduces opportunities for other, more active modes of travel such as walking and bicycling. Though the built environment cannot be said to directly affect human obesity, the built environment clearly has a relationship to obesity as a consequence of physical activity. Most concerning is that rates of obesity have risen as cars have become increasingly privileged, leading to places that favor driving over walking or bicycling. This review examines current empirical literature on the environment and obesity at 3 key urban scales: macro, meso, and micro. Other key issues examined include longitudinal studies and self-selection bias. Evidence for a relationship between urban and suburban environments and obesity is found in the literature, but the lack of longitudinal research and research controlling for self-selection bias remains underrepresented. © The Author(s) 2016. Published by Oxford University Press on behalf of the International Life Sciences Institute. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

RESONANT AMPLIFICATION OF TURBULENCE BY THE BLAST WAVES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zankovich, A. M.; Kovalenko, I. G., E-mail: ilya.g.kovalenko@gmail.com

2015-02-10

We discuss the idea of whether spherical blast waves can amplify by a nonlocal resonant hydrodynamic mechanism inhomogeneities formed by turbulence or phase segregation in the interstellar medium. We consider the problem of a blast-wave-turbulence interaction in the Linear Interaction Approximation. Mathematically, this is an eigenvalue problem for finding the structure and amplitude of eigenfunctions describing the response of the shock-wave flow to forced oscillations by external perturbations in the ambient interstellar medium. Linear analysis shows that the blast wave can amplify density and vorticity perturbations for a wide range of length scales with amplification coefficients of up to 20,more » with increasing amplification the larger the length. There also exist resonant harmonics for which the gain becomes formally infinite in the linear approximation. Their orbital wavenumbers are within the range of macro- (l ∼ 1), meso- (l ∼ 20), and microscopic (l > 200) scales. Since the resonance width is narrow (typically, Δl < 1), resonance should select and amplify discrete isolated harmonics. We speculate on a possible explanation of an observed regular filamentary structure of regularly shaped round supernova remnants such as SNR 1572, 1006, or 0509-67.5. Resonant mesoscales found (l ≈ 18) are surprisingly close to the observed scales (l ≈ 15) of ripples in the shell's surface of SNR 0509-67.5.« less

Elliptical Instability of Rotating Von Karman Street

NASA Astrophysics Data System (ADS)

Stegner, A.; Pichon, T.; Beunier, M.

Clouds often reveal a meso-scale vortex shedding in the wake of mountainous islands. Unlike the classical bi-dimensional Von-Karman street, these observed vortex street are affected by the earth rot ation and vertical stratification. Theses effects could induce a selective destabilization of anticyclonic vortices. It is well known that inertial instability (also called centrifugal instability) induce a three- dimensional destabilization of anticyclonic structures when the absolute vorticity is larger than the local Coriolis parameter. However, we have shown, by the mean of laboratory experiments, that it is a different type of instability which is mainly responsible for asymmetric rotating Von-Karman street. A serie of experiments were performed to study the wake of a cylinder in a rotating fluid, at medium Reynolds number and order one Rossby number. We have shown that the vertical structure of unstable anticyclonic vortices is characteristic of an elliptical instability. Besides, unlike the inertial instability, the vertical unstable wavelength depends on the Rossby number.

Advances in modelling of biomimetic fluid flow at different scales

PubMed Central

2011-01-01

The biomimetic flow at different scales has been discussed at length. The need of looking into the biological surfaces and morphologies and both geometrical and physical similarities to imitate the technological products and processes has been emphasized. The complex fluid flow and heat transfer problems, the fluid-interface and the physics involved at multiscale and macro-, meso-, micro- and nano-scales have been discussed. The flow and heat transfer simulation is done by various CFD solvers including Navier-Stokes and energy equations, lattice Boltzmann method and molecular dynamics method. Combined continuum-molecular dynamics method is also reviewed. PMID:21711847

Progressive structural changes of Avicel, bleached softwood, and bacterial cellulose during enzymatic hydrolysis

PubMed Central

Kafle, Kabindra; Shin, Heenae; Lee, Christopher M.; Park, Sunkyu; Kim, Seong H.

2015-01-01

A comprehensive picture of structural changes of cellulosic biomass during enzymatic hydrolysis is essential for a better understanding of enzymatic actions and development of more efficient enzymes. In this study, a suite of analytical techniques including sum frequency generation (SFG) spectroscopy, infrared (IR) spectroscopy, x-ray diffraction (XRD), and x-ray photoelectron spectroscopy (XPS) were employed for lignin-free model biomass samples—Avicel, bleached softwood, and bacterial cellulose—to find correlations between the decrease in hydrolysis rate over time and the structural or chemical changes of biomass during the hydrolysis reaction. The results showed that the decrease in hydrolysis rate over time appears to correlate with the irreversible deposition of non-cellulosic species (either reaction side products or denatured enzymes, or both) on the cellulosic substrate surface. The crystallinity, degree of polymerization, and meso-scale packing of cellulose do not seem to positively correlate with the decrease in hydrolysis rate observed for all three substrates tested in this study. It was also found that the cellulose Iα component of the bacterial cellulose is preferentially hydrolyzed by the enzyme than the cellulose Iβ component. PMID:26463274

The presence of lead decreases the availability of meso-2, 3-dimercaptosuccinic acid for analysis in the monobromobimane assay.

PubMed

Lever, S Z; Parsons, T L

1999-11-01

meso-2,3-Dimercaptosuccinic acid is a suitable chelating agent for routine pharmacotherapy of lead poisoning in children. Administration of meso-2,3-dimercaptosuccinic acid presumably permits complexation of lead in vivo, allowing excretion through urine or feces. Quantification of the lead is achieved independently from the analysis of meso-2,3-dimercaptosuccinic acid and metabolites from the monobromobimane assay. To date, no direct chemical characterization of the Pb species excreted in urine has been successful. Pharmacokinetic correlation of lead excretion with excretion of meso-2,3-dimercaptosuccinic acid and metabolites has been utilized as an indirect method to draw conclusions regarding the identity of the active chelating agent. In this study, we hypothesized that the Pb-coordinated thiols are not reactive with respect to monobromobimane, and thus, the active chelator contained in the lead complex escapes detection. We performed variations of the assay and found that (1) the fluorescence detector response for the meso-2,3-dimercaptosuccinic acid-monobromobimane adduct was clearly attenuated as a function of added Pb, (2) when meso-2, 3-dimercaptosuccinic acid and monobromobimane were mixed prior to the addition of lead, the lead had no effect on detector response, (3) the addition of dithiothreitol does not affect the ability of Pb to react with meso-2,3-dimercaptosuccinic acid and verifies that oxidation of meso-DMSA had not occurred, and (4) the addition of ethylenediaminetetraacetic acid to the assay reverses the result found in point 1, presumably through trans chelation of the Pb-DMSA complex. Indirect quantification of the Pb-DMSA complexes found in urine might be accomplished through modification of the standard monobromobimane assay for analysis of meso-2,3-dimercaptosuccinic acid.

Lutein, Zeaxanthin, and meso-Zeaxanthin: The Basic and Clinical Science Underlying Carotenoid-based Nutritional Interventions against Ocular Disease

PubMed Central

Bernstein, Paul S.; Li, Binxing; Vachali, Preejith P.; Gorusupudi, Aruna; Shyam, Rajalekshmy; Henriksen, Bradley S.; Nolan, John M.

2015-01-01

The human macula uniquely concentrates three carotenoids: lutein, zeaxanthin, and meso-zeaxanthin. Lutein and zeaxanthin must be obtained from dietary sources such as green leafy vegetables and orange and yellow fruits and vegetables, while meso-zeaxanthin is rarely found in diet and is believed to be formed at the macula by metabolic transformations of ingested carotenoids. Epidemiological studies and large-scale clinical trials such as AREDS2 have brought attention to the potential ocular health and functional benefits of these three xanthophyll carotenoids consumed through the diet or supplements, but the basic science and clinical research underlying recommendations for nutritional interventions against age-related macular degeneration and other eye diseases are underappreciated by clinicians and vision researchers alike. In this review article, we first examine the chemistry, biophysics, and physiology of these yellow pigments that are specifically concentrated in the macula lutea through the means of high-affinity binding proteins and specialized transport and metabolic proteins where they play important roles as short-wavelength (blue) light-absorbers and localized, efficient antioxidants in a region at high risk for light-induced oxidative stress. Next, we turn to clinical evidence supporting functional benefits of these carotenoids in normal eyes and for their potential protective actions against ocular disease from infancy to old age. PMID:26541886

Evaluation of the 29-km Eta Model for Weather Support to the United States Space Program

NASA Technical Reports Server (NTRS)

Manobianco, John; Nutter, Paul

1997-01-01

The Applied Meteorology Unit (AMU) conducted a year-long evaluation of NCEP's 29-km mesoscale Eta (meso-eta) weather prediction model in order to identify added value to forecast operations in support of the United States space program. The evaluation was stratified over warm and cool seasons and considered both objective and subjective verification methodologies. Objective verification results generally indicate that meso-eta model point forecasts at selected stations exhibit minimal error growth in terms of RMS errors and are reasonably unbiased. Conversely, results from the subjective verification demonstrate that model forecasts of developing weather events such as thunderstorms, sea breezes, and cold fronts, are not always as accurate as implied by the seasonal error statistics. Sea-breeze case studies reveal that the model generates a dynamically-consistent thermally direct circulation over the Florida peninsula, although at a larger scale than observed. Thunderstorm verification reveals that the meso-eta model is capable of predicting areas of organized convection, particularly during the late afternoon hours but is not capable of forecasting individual thunderstorms. Verification of cold fronts during the cool season reveals that the model is capable of forecasting a majority of cold frontal passages through east central Florida to within +1-h of observed frontal passage.

A microstructural model of motion of macro-twin interfaces in Ni-Mn-Ga 10 M martensite

NASA Astrophysics Data System (ADS)

Seiner, Hanuš; Straka, Ladislav; Heczko, Oleg

2014-03-01

We present a continuum-based model of microstructures forming at the macro-twin interfaces in thermoelastic martensites and apply this model to highly mobile interfaces in 10 M modulated Ni-Mn-Ga martensite. The model is applied at three distinct spatial scales observed in the experiment: meso-scale (modulation twinning), micro-scale (compound a-b lamination), and nano-scale (nanotwining in the concept of adaptive martensite). We show that two mobile interfaces (Type I and Type II macro-twins) have different micromorphologies at all considered spatial scales, which can directly explain their different twinning stress observed in experiments. The results of the model are discussed with respect to various experimental observations at all three considered spatial scales.

Guanidinium ionic liquid-controlled synthesis of zeolitic imidazolate framework for improving its adsorption property.

PubMed

Fan, Chen; Liang, You; Dong, Hongqiang; Yang, Jiale; Tang, Gang; Zhang, Wenbing; Kong, Dandan; Li, Jianqiang; Cao, Yongsong

2018-05-30

The massive release of rhodamine B (RhB) to water system is an emerging problem, which dramatically threaten environment and human health. The development of an adsorbent with enhanced removal efficiency for RhB is urgently needed. Herein, we report an environment-friendly synthesis of high quality zeolitic imidazolate framework-8 (ZIF-8) and functional ionic liquid@ZIF-8 in water-based system without heat treatment for improving its adsorption property. Guanidinium ionic liquids (ILs) could not only act as greener agents instead of volatile bases and toxic surfactants to efficiently control the nucleation and growth rate of ZIF-8, but also were incorporated as shell material to add specific adsorption sites. The relationship between nanoparticle structure and adsorption performance for RhB was systematically investigated. Due to high surface area (1167 m 2  g -1 ), high porosity (0.79 cm 3  g -1 ), high crystallinity, nano size (about 100 nm) and monodispersity, the as-obtained ZIF-8 showed improved adsorption capacity toward RhB (80% removal efficiency). Heteropolyanion-based guanidinium IL@meso-ZIF-8 (HPAIL@meso-ZIF-8) exhibited the high RhB uptake capacity of 278 mg g -1 (higher than most of the reported adsorbents) and effectively removed 99% of RhB within 15 min. The results showed that the adsorption process of prepared materials fitted well with pseudo-second-order kinetics and Langmuir isotherm model. The existence of mesopores in ZIF-8 facilitated the diffusion of RhB and the incorporated guanidinium IL played a significant role in enhancing the adsorption affinity. Moreover, the reusability results revealed the HPAIL@meso-ZIF-8 as a highly efficient adsorbent for RhB removal with satisfactory performance and structural stability. Therefore, HPAIL@meso-ZIF-8 is one of the most promising adsorbents for organic dye removal from water. Copyright © 2018 Elsevier B.V. All rights reserved.

Bio-derived hierarchically macro-meso-micro porous carbon anode for lithium/sodium ion batteries

NASA Astrophysics Data System (ADS)

Elizabeth, Indu; Singh, Bhanu Pratap; Trikha, Sunil; Gopukumar, Sukumaran

2016-10-01

Nitrogen doped hierarchically porous carbon derived from prawn shells have been efficiently synthesized through a simple, economically viable and environmentally benign approach. The prawn shell derived carbon (PSC) has high inherent nitrogen content (5.3%) and possesses a unique porous structure with the co-existence of macro, meso and micropores which can afford facile storage and transport channels for both Li and Na ions. PSC is well characterized using X-ray diffraction (XRD), Field Emission Scanning Electron Microscopy (FE-SEM), Transmission electron Microscopy (TEM), High resolution TEM (HR-TEM) and X-ray photoelectron spectroscopy (XPS). Electron Paramagnetic Resonance (EPR) and Solid state-Nuclear Magnetic Resonance (NMR) studies have been conducted on pristine PSC and Li/Na interacted PSC. PSC as anode for Lithium ion batteries (LIBs) delivers superior electrochemical reversible specific capacity (740 mAh g-1 at 0.1 Ag-1 current density for 150 cycles) and high rate capability. When used as anode material for Sodium ion batteries (SIBs), PSC exhibits excellent reversible specific capacity of 325 mAh g-1 at 0.1 Ag-1 for 200 cycles and rate capability of 107 mAh g-1 at 2 Ag-1. Furthermore, this study demonstrates the employment of natural waste material as a potential anode for both LIB and SIB, which will definitively make a strike in the energy storage field.

The Canadian Teaching Commons: The Scholarship of Teaching and Learning in Canadian Higher Education

ERIC Educational Resources Information Center

Wuetherick, Brad; Yu, Stan

2016-01-01

This chapter reports on a national study exploring the current state of the Scholarship of Teaching and Learning (SoTL) and assessing the perceptions of Canadian SoTL scholars at the micro (individual), meso (departmental), macro (institutional), and mega (disciplinary) contexts.

Tools for Virtual Collaboration Designed for High Resolution Hydrologic Research with Continental-Scale Data Support

NASA Astrophysics Data System (ADS)

Duffy, Christopher; Leonard, Lorne; Shi, Yuning; Bhatt, Gopal; Hanson, Paul; Gil, Yolanda; Yu, Xuan

2015-04-01

Using a series of recent examples and papers we explore some progress and potential for virtual (cyber-) collaboration inspired by access to high resolution, harmonized public-sector data at continental scales [1]. The first example describes 7 meso-scale catchments in Pennsylvania, USA where the watershed is forced by climate reanalysis and IPCC future climate scenarios (Intergovernmental Panel on Climate Change). We show how existing public-sector data and community models are currently able to resolve fine-scale eco-hydrologic processes regarding wetland response to climate change [2]. The results reveal that regional climate change is only part of the story, with large variations in flood and drought response associated with differences in terrain, physiography, landuse and/or hydrogeology. The importance of community-driven virtual testbeds are demonstrated in the context of Critical Zone Observatories, where earth scientists from around the world are organizing hydro-geophysical data and model results to explore new processes that couple hydrologic models with land-atmosphere interaction, biogeochemical weathering, carbon-nitrogen cycle, landscape evolution and ecosystem services [3][4]. Critical Zone cyber-research demonstrates how data-driven model development requires a flexible computational structure where process modules are relatively easy to incorporate and where new data structures can be implemented [5]. From the perspective of "Big-Data" the paper points out that extrapolating results from virtual observatories to catchments at continental scales, will require centralized or cloud-based cyberinfrastructure as a necessary condition for effectively sharing petabytes of data and model results [6]. Finally we outline how innovative cyber-science is supporting earth-science learning, sharing and exploration through the use of on-line tools where hydrologists and limnologists are sharing data and models for simulating the coupled impacts of catchment hydrology on lake eco-hydrology (NSF-INSPIRE, IIS1344272). The research attempts to use a virtual environment (www.organicdatascience.org) to break down disciplinary barriers and support emergent communities of science. [1] Source: Leonard and Duffy, 2013, Environmental Modelling & Software; [2] Source: Yu et al, 2014, Computers in Geoscience; [3] Source: Duffy et al, 2014, Procedia Earth and Planetary Science; [4] Source: Shi et al, Journal of Hydrometeorology, 2014; [5] Source: Bhatt et al, 2014, Environmental Modelling & Software ; [6] Leonard and Duffy, 2014, Environmental Modelling and Software.

An online mineral dust model within the global/regional NMMB: current progress and plans

NASA Astrophysics Data System (ADS)

Perez, C.; Haustein, K.; Janjic, Z.; Jorba, O.; Baldasano, J. M.; Black, T.; Nickovic, S.

2008-12-01

While mineral dust distribution and effects are important on global scales, they strongly depend on dust emissions that are occurring on small spatial and temporal scales. Indeed, the accuracy of surface wind speed used in dust models is crucial. Due to the high-order power dependency on wind friction velocity and the threshold behaviour of dust emissions, small errors in surface wind speed lead to large dust emission errors. Most global dust models use prescribed wind fields provided by major meteorological centres (e.g., NCEP and ECMWF) and their spatial resolution is currently about 1 degree x 1 degree . Such wind speeds tend to be strongly underestimated over arid and semi-arid areas and do not account for mesoscale systems responsible for a significant fraction of dust emissions regionally and globally. Other significant uncertainties in dust emissions resulting from such approaches are related to the misrepresentation of high subgrid-scale spatial heterogeneity in soil and vegetation boundary conditions, mainly in semi-arid areas. In order to significantly reduce these uncertainties, the Barcelona Supercomputing Center is currently implementing a mineral dust model coupled on-line with the new global/regional NMMB atmospheric model using the ESMF framework under development in NOAA/NCEP/EMC. The NMMB is an evolution of the operational WRF-NMME extending from meso to global scales, and including non-hydrostatic option and improved tracer advection. This model is planned to become the next-generation NCEP mesoscale model for operational weather forecasting in North America. Current implementation is based on the well established regional dust model and forecast system Eta/DREAM (http://www.bsc.es/projects/earthscience/DREAM/). First successful global simulations show the potentials of such an approach and compare well with DREAM regionally. Ongoing developments include improvements in dust size distribution representation, sedimentation, dry deposition, wet scavenging and dust-radiation feedback, as well as the efficient implementation of the model on High Performance Supercomputers for global simulations and forecasts at high resolution.

Application and comparison of the SCS-CN-based rainfall-runoff model in meso-scale watershed and field scale

NASA Astrophysics Data System (ADS)

Luo, L.; Wang, Z.

2010-12-01

Soil Conservation Service Curve Number (SCS-CN) based hydrologic model, has widely been used for agricultural watersheds in recent years. However, there will be relative error when applying it due to differentiation of geographical and climatological conditions. This paper introduces a more adaptable and propagable model based on the modified SCS-CN method, which specializes into two different scale cases of research regions. Combining the typical conditions of the Zhanghe irrigation district in southern part of China, such as hydrometeorologic conditions and surface conditions, SCS-CN based models were established. The Xinbu-Qiao River basin (area =1207 km2) and the Tuanlin runoff test area (area =2.87 km2)were taken as the study areas of basin scale and field scale in Zhanghe irrigation district. Applications were extended from ordinary meso-scale watershed to field scale in Zhanghe paddy field-dominated irrigated . Based on actual measurement data of land use, soil classification, hydrology and meteorology, quantitative evaluation and modifications for two coefficients, i.e. preceding loss and runoff curve, were proposed with corresponding models, table of CN values for different landuse and AMC(antecedent moisture condition) grading standard fitting for research cases were proposed. The simulation precision was increased by putting forward a 12h unit hydrograph of the field area, and 12h unit hydrograph were simplified. Comparison between different scales show that it’s more effectively to use SCS-CN model on field scale after parameters calibrated in basin scale These results can help discovering the rainfall-runoff rule in the district. Differences of established SCS-CN model's parameters between the two study regions are also considered. Varied forms of landuse and impacts of human activities were the important factors which can impact the rainfall-runoff relations in Zhanghe irrigation district.

Relation between alternating open/closed-conduit conditions and deformation patterns: An example from the Somma-Vesuvius volcano (southern Italy)

NASA Astrophysics Data System (ADS)

Tramparulo, F. D. A.; Vitale, S.; Isaia, R.; Tadini, A.; Bisson, M.; Prinzi, E. P.

2018-07-01

We present the results of a meso-scale systematic structural analysis of fractures, faults and dykes exposed at the Somma-Vesuvius volcano (southern Italy). Observed fractures include: (i) radial and tangential (with respect the caldera axis), sub-metric to metric joints associated with the edifice load and volcano-tectonic activity (i.e. inflation, deflation and caldera collapse stages) and (ii) decameter-scale fractures related to volcano flank instabilities. For the Somma-Vesuvius volcano, preexisting radial joints were commonly reactivated as transfer faults during the caldera formation, allowing different blocks to move toward the center of the collapsing area. Dykes occur with different geometries, including en-echelon structures bounding structural depressions. The orientation analysis of all structures indicates that they are preferentially oriented. Furthermore, we provide a morphological lineament analysis using high-resolution Digital Terrain Models of Somma-Vesuvius. Azimuth and spatial distribution of dykes and morphological lineaments were analyzed for comparison with the old Somma Crater and Gran Cono axes, respectively. Results highlight the overprinting of radial and clustered strain patterns recorded in different volcano-tectonic evolution stages. We suggest a possible deformation evolution model in which structures develop along either radial or preferential trends, highlighting different volcanic conditions: (i) where radial patterns occur, the structures developed during volcanic inflation cycles with a closed magmatic conduit condition whereas (ii) clustered patterns are probably associated with a regional strain field that overcomes the local deformation field, a situation typical in the case of open-conduit activity.

An Ideal Electrode Material, 3D Surface-Microporous Graphene for Supercapacitors with Ultrahigh Areal Capacitance

DOE PAGES

Chang, Liang; Stacchiola, Dario J.; Hu, Yun Hang

2017-07-03

The efficient charge accumulation of an ideal supercapacitor electrode requires abundant micropores and its fast electrolyte-ions transport prefers meso/macropores. But, current electrode materials cannot meet both requirements, resulting in poor performance. We creatively constructed three-dimensional cabbage-coral-like graphene as an ideal electrode material, in which meso/macro channels are formed by graphene walls and rich micropores are incorporated in the surface layer of the graphene walls. The unique 3D graphene material can achieve a high gravimetric capacitance of 200 F/g with aqueous electrolyte, 3 times larger than that of commercially used activated carbon (70.8 F/g). Furthermore, it can reach an ultrahigh arealmore » capacitance of 1.28 F/cm 2 and excellent rate capability (83.5% from 0.5 to 10 A/g) as well as high cycling stability (86.2% retention after 5000 cycles). The excellent electric double-layer performance of the 3D graphene electrode can be attributed to the fast electrolyte ion transport in the meso/macro channels and the rapid and reversible charge adsorption with negligible transport distance in the surface micropores.« less

An Ideal Electrode Material, 3D Surface-Microporous Graphene for Supercapacitors with Ultrahigh Areal Capacitance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chang, Liang; Stacchiola, Dario J.; Hu, Yun Hang

The efficient charge accumulation of an ideal supercapacitor electrode requires abundant micropores and its fast electrolyte-ions transport prefers meso/macropores. But, current electrode materials cannot meet both requirements, resulting in poor performance. We creatively constructed three-dimensional cabbage-coral-like graphene as an ideal electrode material, in which meso/macro channels are formed by graphene walls and rich micropores are incorporated in the surface layer of the graphene walls. The unique 3D graphene material can achieve a high gravimetric capacitance of 200 F/g with aqueous electrolyte, 3 times larger than that of commercially used activated carbon (70.8 F/g). Furthermore, it can reach an ultrahigh arealmore » capacitance of 1.28 F/cm 2 and excellent rate capability (83.5% from 0.5 to 10 A/g) as well as high cycling stability (86.2% retention after 5000 cycles). The excellent electric double-layer performance of the 3D graphene electrode can be attributed to the fast electrolyte ion transport in the meso/macro channels and the rapid and reversible charge adsorption with negligible transport distance in the surface micropores.« less

Analysis of context factors in compulsory and incentive strategies for improving attraction and retention of health workers in rural and remote areas: a systematic review.

PubMed

Liu, Xiaoyun; Dou, Lixia; Zhang, Huan; Sun, Yang; Yuan, Beibei

2015-07-21

Current literature systematically reports that interventions to attract and retain health workers in underserved areas need to be context specific but rarely defines what that means. In this systematic review, we try to summarize and analyse context factors influencing the implementation of interventions to attract and retain rural health workers. We searched online databases, relevant websites and reference lists of selected literature to identify studies on compulsory rural service programmes and financial incentives. Forty studies were selected. Information regarding context factors at macro, meso and micro levels was extracted and synthesized. Macro-level context factors include political, economic and social factors. Meso-level factors include health system factors such as maldistribution of health workers, growing private sector, decentralization and health financing. Micro-level factors refer to the policy implementation process including funding sources, administrative agency, legislation process, monitoring and evaluation. Macro-, meso- and micro-level context factors can play different roles in agenda setting, policy formulation and implementation of health interventions to attract and retain rural health workers. These factors should be systematically considered in the different stages of policy process and evaluation.

Impact of oceanic submesoscale coherent structures on marine top predators: new tools and challenges

NASA Astrophysics Data System (ADS)

Tew-Kai, E.; Sudre, J.; Gremillet, D.; Yahia, H.; Rossi, V.; Hernandez-Garcia, E.; López, C.; Marsac, F.; Weimerskirch, H.; Garçon, V.

2011-12-01

In recent years it appears that meso- and submesoscale features (fronts, eddies, filaments) in surface ocean flow have a crucial influence on marine ecosystems. Their dynamics partly control the foraging behaviour and the movements of marine top. One of the challenges in ecology is to define critical habitats and understand the rules of habitat selection. Recently new tools for detection of coherent structures at submesoscale open the way for new studies never investigated before in marine ecology. Through two examples we highlight novel research on the importance of submesoscale structures for the spatial distribution of marine top predators. We studied two seabird populations with contrasting characteristics: Frigatebirds in the Mozambique Channel, and Cape gannets in the Benguela upwelling off southern Africa. Frigatebirds are mainly offshore birds while Cape gannets do not venture beyond the continental shelf. For these two studies, we used products derived from remote sensing data, to describe submesoscale coherent structures (<10km). In the first example, using Finite-Size Lyapunov Exponents (FSLE), we have identified Lagrangian coherent structures (LCSs) present in the surface flow of the Mozambique Channel resulting from an intense mesoscale activity. By comparing seabird satellite positions with LCSs locations, we demonstrate that frigatebirds track precisely these structures in the Mozambique Channel, providing the first evidence that a top predator is able to track these FSLE ridges to locate food patches. Although many questions remain unanswered, this work remains a pioneering on this topic. Despite the interest of FSLE, they are limited to offshore areas due to altimetry products limitation on continental shelves. However, many seabirds operate in coastal areas undergoing stronger anthropogenic pressures, such as Cape gannets off South Africa. The Benguela system is characterized by an upwelling inhabited by numerous fronts and filaments that very likely have a strong impact on seabird spatial distribution, and it was not possible to implement FSLE in this area. Thus, we used a newly developed method based on the singularity exponents calculated from remotely sensed data of ocean colour and SST, which delivers a precise picture of meso and submeso-scale structures off the coast. Preliminary results on understanding the rules of habitat selection by Cape gannets, and contribution to the conservation of this endangered species will be presented.

Lightning climatology over Jakarta, Indonesia, based on long-term surface operational, satellite, and campaign observations

NASA Astrophysics Data System (ADS)

Mori, Shuichi; Wu, Peiming; Yamanaka, Manabu D.; Hattori, Miki; Hamada, Jun-Ichi; Arbain, Ardhi A.; Lestari, Sopia; Sulistyowati, Reni; Syamsudin, Fadli

2016-04-01

Lightning frequency over Indonesian Maritime Continent (MC) is quite high (Petersen and Rutledge 2001, Christian et al. 2003, Takayabu 2006, etc). In particular, Bogor (south of Jakarta, west Jawa) had 322 days of lightning in one year (Guinness Book in 1988). Lightning causes serious damage on nature and society over the MC; forest fore, power outage, inrush/surge currents on many kinds of electronics. Lightning climatology and meso-scale characteristics of thunderstorm over the MC, in particular over Jakarta, where social damage is quite serious, were examined. We made Statistical analysis of lightning and thunderstorm based on TRMM Lightning Image Sensor (LIS) and Global Satellite Mapping of Precipitation (GSMaP) together with long-term operational surface observation data (SYNOP) in terms of diurnal, intraseasonal, monsoonal, and interannual variations. In addition, we carried out a campaign observation in February 2015 in Bogor to obtain meso-scale structure and dynamics of thunderstorm over Jakarta to focus on graupel and other ice phase particles inside by using an X-band dual-polarimetric (DP) radar. Recently, Virts et al. (2013a, b) showed comprehensive lightning climatology based on the World Wide Lightning Location Network (WWLLN). However, they also reported problems with its detection efficiency (< 10%) and small sampling frequency (< 0.1% of the time fly over tropics) by satellites. Therefore, we firstly examine in situ lightning data based on SYNOP observed by the Indonesian Agency for Meteorology, Climatology, and Geophysics (BMKG) because lightning is quite local and sporadic phenomena. We've started to analyze lightning characteristics over Jakarta region based on SYNOP as the ground truth data and GSMaP. Variability of lightning frequency around Jakarta was affected much by local conditions, e.g., topography (elevation) and proximity to the coastline. We confirmed the lightning frequency and its diurnal variation around Jakarta were much modulated by Cross Equatorial Northerly Serge (CENS), Madden-Julian Oscillation (MJO), El Nino and Indian Ocean Dipole mode events. Some of the results were inconsistent with previous studies over the equatorial ocean because we focused on lightning over land region in west Jawa. Results from the DP radar observation during the campaign around Bogor in February 2015 are also presented. This work was supported by the Japan Society for the Promotion of Science (JSPS) KAKENHI (Grants-in-Aid for Scientific Research) grant number 25350515 and the Japan Aerospace Exploration Agency (JAXA) 7th Research Announcement (RA).

Uranium and strontium fate in waste-weathered sediments: Scaling of molecular processes to predict reactive transport

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chorover, Jon; Mueller, Karl; O'Day, Peggy

2016-04-02

Objectives of the project: 1. Determine the process coupling that occurs between mineral transformation and contaminant (U and Sr) speciation in acid-uranium waste weathered Hanford sediments. 2. Establish linkages between molecular-scale contaminant speciation and meso-scale contaminant lability, release and reactive transport. 3. Make conjunctive use of molecular- to bench-scale data to constrain the development of a mechanistic, reactive transport model that includes coupling of contaminant sorption-desorption and mineral transformation reactions. Hypotheses tested: - Uranium and strontium speciation in legacy sediments from the U-8 and U-12 Crib sites can be reproduced in bench-scale weathering experiments conducted on unimpacted Hanford sediments frommore » the same formations. - Reactive transport modeling of future uranium and strontium releases from the vadose zone of acid-waste weathered sediments can be effectively constrained by combining molecular-scale information on contaminant bonding environment with grain-scale information on contaminant phase partitioning, and meso-scale kinetic data on contaminant release from the waste-weathered porous media. - Although field contamination and laboratory experiments differ in their diagenetic time scales (decades for field vs. months to years for lab), sediment dissolution, neophase nucleation, and crystal growth reactions that occur during the initial disequilibrium induced by waste-sediment interaction leave a strong imprint that persists over subsequent longer-term equilibration time scales and, therefore, give rise to long-term memory effects. Enabling capabilities developed: Our team developed an iterative measure-model approach that is broadly applicable to elucidate the mechanistic underpinnings of reactive contaminant transport in geomedia subject to active weathering. Experimental design: Hypotheses were tested by comparing (with a similar set of techniques) the geochemical transformations and transport behaviors that occured in bench-scale studies of waste-sediment interaction with parallel model systems studies of homogeneous nucleation and neo-phase dissolution. Initial plans were to compare results with core sample extractions from the acid uranium waste impacted U-8 and U-12 Cribs at Hanford (see original proposal and letter of collaboration from J. Zachara). However, this part of the project was impossible because funding for core extractions were eliminated from the DoE budget. Three distinct crib waste aqueous simulants (whose composition is based on the most up-to-date information from field site investigations) were reacted with Hanford sediments in batch and column systems. Coupling of contaminant uptake to mineral weathering was monitored using a suite of methods both during waste-sediment interaction, and after, when waste-weathered sediments were subjected to infusion with circumneutral background pore water solutions. Our research was designed to adapt as needed to maintain a strong dialogue between laboratory and modeling investigations so that model development was increasingly constrained by emergent data and understanding. Potential impact of the project to DOE: Better prediction of contaminant uranium transport was achieved by employing multi-faceted lines of inquiry to build a strong bridge between molecular- and field-scale information. By focusing multiple lines and scales of observation on a common experimental design, our collaborative team revealed non-linear and emergent behavior in contaminated weathering systems. A goal of the current project was to expand our modeling capabilities, originally focused on hyperalkaline legacy waste streams, to include acidic weathering reactions that, as described above, were expected to result in profoundly different products. We were able to achieve this goal, and showed that these products nonetheless undergo analogous silicate and non-silicate transformation, ripening and aging processes. Our prediction that these weathering reactions would vary with waste stimulant chemistry resulted in data that was incorporated directly into a reactive transport model structure.« less

Carbon dioxide emission and bio-capacity indexing for transportation activities: A methodological development in determining the sustainability of vehicular transportation systems.

PubMed

Labib, S M; Neema, Meher Nigar; Rahaman, Zahidur; Patwary, Shahadath Hossain; Shakil, Shahadat Hossain

2018-06-09

CO 2 emissions from urban traffic are a major concern in an era of increasing ecological disequilibrium. Adding to the problem net CO 2 emissions in urban settings are worsened due to the decline of bio-productive areas in many cities. This decline exacerbates the lack of capacity to sequestrate CO 2 at the micro and meso-scales resulting in increased temperatures and decreased air quality within city boundaries. Various transportation and environmental strategies have been implemented to address traffic related CO 2 emissions, however current literature identifies difficulties in pinpointing these critical areas of maximal net emissions in urban transport networks. This study attempts to close this gap in the literature by creating a new lay-person friendly index that combines CO 2 emissions from vehicles and the bio-capacity of specific traffic zones to identify these areas at the meso-scale within four ranges of values with the lowest index values representing the highest net CO 2 levels. The study used traffic volume, fuel types, and vehicular travel distance to estimate CO 2 emissions at major links in Dhaka, Bangladesh's capital city's transportation network. Additionally, using remote-sensing tools, adjacent bio-productive areas were identified and their bio-capacity for CO 2 sequestration estimated. The bio-productive areas were correlated with each traffic zone under study resulting in an Emission Bio-Capacity index (EBI) value estimate for each traffic node. Among the ten studied nodes in Dhaka City, nine had very low EBI values, correlating to very high CO 2 emissions and low bio-capacity. As a result, the study considered these areas unsustainable as traffic nodes going forward. Key reasons for unsustainability included increasing use of motorized traffic, absence of optimized signal systems, inadequate public transit options, disincentives for fuel free transport (FFT), and a decline in bio-productive areas. Copyright © 2018 Elsevier Ltd. All rights reserved.

Chemometric Analysis of Bacterial Peptidoglycan Reveals Atypical Modifications That Empower the Cell Wall against Predatory Enzymes and Fly Innate Immunity.

PubMed

Espaillat, Akbar; Forsmo, Oskar; El Biari, Khouzaima; Björk, Rafael; Lemaitre, Bruno; Trygg, Johan; Cañada, Francisco Javier; de Pedro, Miguel A; Cava, Felipe

2016-07-27

Peptidoglycan is a fundamental structure for most bacteria. It contributes to the cell morphology and provides cell wall integrity against environmental insults. While several studies have reported a significant degree of variability in the chemical composition and organization of peptidoglycan in the domain Bacteria, the real diversity of this polymer is far from fully explored. This work exploits rapid ultraperformance liquid chromatography and multivariate data analysis to uncover peptidoglycan chemical diversity in the Class Alphaproteobacteria, a group of Gram negative bacteria that are highly heterogeneous in terms of metabolism, morphology and life-styles. Indeed, chemometric analyses revealed novel peptidoglycan structures conserved in Acetobacteria: amidation at the α-(l)-carboxyl of meso-diaminopimelic acid and the presence of muropeptides cross-linked by (1-3) l-Ala-d-(meso)-diaminopimelate cross-links. Both structures are growth-controlled modifications that influence sensitivity to Type VI secretion system peptidoglycan endopeptidases and recognition by the Drosophila innate immune system, suggesting relevant roles in the environmental adaptability of these bacteria. Collectively our findings demonstrate the discriminative power of chemometric tools on large cell wall-chromatographic data sets to discover novel peptidoglycan structural properties in bacteria.

Implementation of an online chemical mechanism within a global-regional atmospheric model: design and initial steps

NASA Astrophysics Data System (ADS)

Jorba, O.; Pérez, C.; Baldasano, J. M.

2009-04-01

Chemical processes in air quality modelling systems are usually treated independently from the meteorological models. This approach is computationally attractive since off-line chemical transport simulations only require a single meteorological dataset to produce many chemical simulations. However, this separation of chemistry and meteorology produces a loss of important information about atmospheric processes and does not allow for feedbacks between chemistry and meteorology. To take into account such processes current models are evolving to an online coupling of chemistry and meteorology to produce consistent chemical weather predictions. The Earth Sciences Department of the Barcelona Supercomputing Center (BSC) develops the NMMB/BSC-DUST (Pérez et al., 2008), an online dust model within the global-regional NCEP/NMMB numerical weather prediction model (Janjic and Black, 2007) under development at National Centers for Environmental Prediction (NCEP). Current implementation is based on the well established regional dust model and forecast system DREAM (Nickovic et al., 2001). The most relevant characteristics of NMMB/BSC-DUST are its on-line coupling of the dust scheme with the meteorological driver, the wide range of applications from meso to global scales, and the inclusion of dust radiative effects allowing feedbacks between aerosols and meteorology. In order to complement such development, BSC works also in the implementation of a fully coupled online chemical mechanism within NMMB/BSC-DUST. The final objective is to develop a fully chemical weather prediction system able to resolve gas-aerosol-meteorology interactions from global to local scales. In this contribution we will present the design of the chemistry coupling and the current progress of its implementation. Following the NCEP/NMMB approach, the chemistry part will be coupled through the Earth System Modeling Framework (ESMF) as a pluggable component. The chemical mechanism and chemistry solver is based on the Kinetic PreProcessor KPP (Sandu and Sander, 2006) package with the main purpose to maintain a wide flexibility when configuring the model. Such approach will allow using a simple general chemical mechanism for global applications or a more complex mechanism for regional to local applications at higher resolution. REFERENCES Janjic, Z.I., and Black, T.L., 2007. An ESMF unified model for a broad range of spatial and temporal scales, Geophysical Research Abstracts, 9, 05025. Nickovic, S., Papadopoulos, A., Kakaliagou, O., and Kallos, G., 2001. Model for prediciton of desert dust cycle in the atmosphere. J. Geophys. Res., 106, 18113-18129. Pérez, C., Haustein, K., Janjic, Z.I., Jorba, O., Baldasano, J.M., Black, T.L., and Nickovic, S., 2008. An online dust model within the meso to global NMMB: current progress and plans. AGU Fall Meeting, San Francisco, A41K-03, 2008. Sandu, A., and Sander, R., 2006. Technical note:Simulating chemical systems in Fortran90 and Matlab with the Kinetic PreProcessor KPP-2.1. Atmos. Chem. and Phys., 6, 187-195.

Instrumentation for Performance, Blade Loads and Flowfield Measurement of Novel Hover-Capable Meso-Scale Aerial Platforms

DTIC Science & Technology

2016-12-07

many DoD sponsored MAV projects including one task from ARO and another one as part of Army/Navy/ NASA - sponsored VLRCOE at Maryland all requiring...has undertaken many DoD sponsored MAV projects including one task from ARO and another one as part of Army/Navy/ NASA sponsored Vertical Lift Research

Development of a Meso-Scale Material Model for Ballistic Fabric and Its Use in Flexible-Armor Protection Systems

DTIC Science & Technology

2010-02-01

s mobility. Early materials used included leather , silk, metal chain mail, and metal plates. Replacement of metal with a nylon (poly-amide) fabric...tests of flexible-fabric armor, and as shown by Tan et al. (Ref 24) in a series of postimpact fabric-inspection studies, play an important role in

Increasingly inbred and fragmented populations of Plasmodium vivax associated with the eastward decline in malaria transmission across the Southwest Pacific

PubMed Central

Waltmann, Andreea; Koepfli, Cristian; Tessier, Natacha; Karl, Stephan; Fola, Abebe; Darcy, Andrew W.; Wini, Lyndes; Harrison, G. L. Abby; Barnadas, Céline; Jennison, Charlie; Karunajeewa, Harin; Boyd, Sarah; Whittaker, Maxine; Kazura, James; Bahlo, Melanie; Mueller, Ivo

2018-01-01

The human malaria parasite Plasmodium vivax is more resistant to malaria control strategies than Plasmodium falciparum, and maintains high genetic diversity even when transmission is low. To investigate whether declining P. vivax transmission leads to increasing population structure that would facilitate elimination, we genotyped samples from across the Southwest Pacific region, which experiences an eastward decline in malaria transmission, as well as samples from two time points at one site (Tetere, Solomon Islands) during intensified malaria control. Analysis of 887 P. vivax microsatellite haplotypes from hyperendemic Papua New Guinea (PNG, n = 443), meso-hyperendemic Solomon Islands (n = 420), and hypoendemic Vanuatu (n = 24) revealed increasing population structure and multilocus linkage disequilibrium yet a modest decline in diversity as transmission decreases over space and time. In Solomon Islands, which has had sustained control efforts for 20 years, and Vanuatu, which has experienced sustained low transmission for many years, significant population structure was observed at different spatial scales. We conclude that control efforts will eventually impact P. vivax population structure and with sustained pressure, populations may eventually fragment into a limited number of clustered foci that could be targeted for elimination. PMID:29373596

Structural integrity—Searching the key factor to supress the voltage fade of Li-rich layered cathode materials through 3D X-ray imaging and spectroscopy techniques

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, Yahong; Hu, Enyuan; Yang, Feifei

Li-rich layered materials are important cathode compounds used in commercial lithium ion batteries, which, however, suffers from some drawbacks including the so-called voltage fade upon electrochemical cycling. This study employs novel transmission X-ray microscopy to investigate the electrochemical reaction induced morphological and chemical changes in the Li-rich Li 2Ru 0.5Mn 0.5O 3 cathode particles at the meso to nano scale. Combined X-ray spectroscopy, diffraction and microscopy experiments are performed to systematically study this cathode material's evolution upon cycling as well as to establish a comprehensive understanding of the structural origin of capacity fade through 2D and 3D fine length scalemore » morphology and heterogeneity change of this material. This work suggests that atomic manipulation (e.g. doping, substitution etc.) or nano engineering (e.g. nano-sizing, heterogeneous structure) are important strategies to mitigate the internal strain and defects induced by extensive lithium insertion/extraction. In conclusion, it also shows that maintaining the structural integrity is the key in designing and synthesizing lithium-rich layered materials with better cycle stability.« less

Structural integrity—Searching the key factor to supress the voltage fade of Li-rich layered cathode materials through 3D X-ray imaging and spectroscopy techniques

DOE PAGES

Xu, Yahong; Hu, Enyuan; Yang, Feifei; ...

2016-08-17

Li-rich layered materials are important cathode compounds used in commercial lithium ion batteries, which, however, suffers from some drawbacks including the so-called voltage fade upon electrochemical cycling. This study employs novel transmission X-ray microscopy to investigate the electrochemical reaction induced morphological and chemical changes in the Li-rich Li 2Ru 0.5Mn 0.5O 3 cathode particles at the meso to nano scale. Combined X-ray spectroscopy, diffraction and microscopy experiments are performed to systematically study this cathode material's evolution upon cycling as well as to establish a comprehensive understanding of the structural origin of capacity fade through 2D and 3D fine length scalemore » morphology and heterogeneity change of this material. This work suggests that atomic manipulation (e.g. doping, substitution etc.) or nano engineering (e.g. nano-sizing, heterogeneous structure) are important strategies to mitigate the internal strain and defects induced by extensive lithium insertion/extraction. In conclusion, it also shows that maintaining the structural integrity is the key in designing and synthesizing lithium-rich layered materials with better cycle stability.« less

Polymer-based platform for microfluidic systems

DOEpatents

Benett, William [Livermore, CA; Krulevitch, Peter [Pleasanton, CA; Maghribi, Mariam [Livermore, CA; Hamilton, Julie [Tracy, CA; Rose, Klint [Boston, MA; Wang, Amy W [Oakland, CA

2009-10-13

A method of forming a polymer-based microfluidic system platform using network building blocks selected from a set of interconnectable network building blocks, such as wire, pins, blocks, and interconnects. The selected building blocks are interconnectably assembled and fixedly positioned in precise positions in a mold cavity of a mold frame to construct a three-dimensional model construction of a microfluidic flow path network preferably having meso-scale dimensions. A hardenable liquid, such as poly (dimethylsiloxane) is then introduced into the mold cavity and hardened to form a platform structure as well as to mold the microfluidic flow path network having channels, reservoirs and ports. Pre-fabricated elbows, T's and other joints are used to interconnect various building block elements together. After hardening the liquid the building blocks are removed from the platform structure to make available the channels, cavities and ports within the platform structure. Microdevices may be embedded within the cast polymer-based platform, or bonded to the platform structure subsequent to molding, to create an integrated microfluidic system. In this manner, the new microfluidic platform is versatile and capable of quickly generating prototype systems, and could easily be adapted to a manufacturing setting.

Increasingly inbred and fragmented populations of Plasmodium vivax associated with the eastward decline in malaria transmission across the Southwest Pacific.

PubMed

Waltmann, Andreea; Koepfli, Cristian; Tessier, Natacha; Karl, Stephan; Fola, Abebe; Darcy, Andrew W; Wini, Lyndes; Harrison, G L Abby; Barnadas, Céline; Jennison, Charlie; Karunajeewa, Harin; Boyd, Sarah; Whittaker, Maxine; Kazura, James; Bahlo, Melanie; Mueller, Ivo; Barry, Alyssa E

2018-01-01

The human malaria parasite Plasmodium vivax is more resistant to malaria control strategies than Plasmodium falciparum, and maintains high genetic diversity even when transmission is low. To investigate whether declining P. vivax transmission leads to increasing population structure that would facilitate elimination, we genotyped samples from across the Southwest Pacific region, which experiences an eastward decline in malaria transmission, as well as samples from two time points at one site (Tetere, Solomon Islands) during intensified malaria control. Analysis of 887 P. vivax microsatellite haplotypes from hyperendemic Papua New Guinea (PNG, n = 443), meso-hyperendemic Solomon Islands (n = 420), and hypoendemic Vanuatu (n = 24) revealed increasing population structure and multilocus linkage disequilibrium yet a modest decline in diversity as transmission decreases over space and time. In Solomon Islands, which has had sustained control efforts for 20 years, and Vanuatu, which has experienced sustained low transmission for many years, significant population structure was observed at different spatial scales. We conclude that control efforts will eventually impact P. vivax population structure and with sustained pressure, populations may eventually fragment into a limited number of clustered foci that could be targeted for elimination.

Experimental Investigation of Minimum Quantity Lubrication in Meso-scale Milling with Varying Tool Diameter

NASA Astrophysics Data System (ADS)

Yusof, M. Q. M.; Harun, H. N. S. B.; Bahar, R.

2018-01-01

Minimum quantity lubrication (MQL) is a method that uses a very small amount of liquid to reduce friction between cutting tool and work piece during machining. The implementation of MQL machining has become a viable alternative to flood cooling machining and dry machining. The overall performance has been evaluated during meso-scale milling of mild steel using different diameter milling cutters. Experiments have been conducted under two different lubrication condition: dry and MQL with variable cutting parameters. The tool wear and its surface roughness, machined surfaces microstructure and surface roughness were observed for both conditions. It was found from the results that MQL produced better results compared to dry machining. The 0.5 mm tool has been selected as the most optimum tool diameter to be used with the lowest surface roughness as well as the least flank wear generation. For the workpiece, it was observed that the cutting temperature possesses crucial effect on the microstructure and the surface roughness of the machined surface and bigger diameter tool actually resulted in higher surface roughness. The poor conductivity of the cutting tool may be one of reasons behind.

Meso-Scale Progressive Damage Behavior Characterization of Triaxial Braided Composites under Quasi-Static Tensile Load

NASA Astrophysics Data System (ADS)

Ren, Yiru; Zhang, Songjun; Jiang, Hongyong; Xiang, Jinwu

2018-04-01

Based on continuum damage mechanics (CDM), a sophisticated 3D meso-scale finite element (FE) model is proposed to characterize the progressive damage behavior of 2D Triaxial Braided Composites (2DTBC) with 60° braiding angle under quasi-static tensile load. The modified Von Mises strength criterion and 3D Hashin failure criterion are used to predict the damage initiation of the pure matrix and fiber tows. A combining interface damage and friction constitutive model is applied to predict the interface damage behavior. Murakami-Ohno stiffness degradation scheme is employed to predict the damage evolution process of each constituent. Coupling with the ordinary and translational symmetry boundary conditions, the tensile elastic response including tensile strength and failure strain of 2DTBC are in good agreement with the available experiment data. The numerical results show that the main failure modes of the composites under axial tensile load are pure matrix cracking, fiber and matrix tension failure in bias fiber tows, matrix tension failure in axial fiber tows and interface debonding; the main failure modes of the composites subjected to transverse tensile load are free-edge effect, matrix tension failure in bias fiber tows and interface debonding.

Development and application of a coupled bio-geochmical and hydrological model for point and non-point source river water pollution

NASA Astrophysics Data System (ADS)

Pohlert, T.

2007-12-01

The aim of this paper is to present recent developments of an integrated water- and N-balance model for the assessment of land use changes on water and N-fluxes for meso-scale river catchments. The semi-distributed water-balance model SWAT was coupled with algorithms of the bio-geochemical model DNDC as well as the model CropSyst. The new model that is further denoted as SWAT-N was tested with leaching data from a long- term lysimeter experiment as well as results from a 5-years sampling campaign that was conducted at the outlet of the meso-scale catchment of the River Dill (Germany). The model efficiency for N-load as well as the spatial representation of N-load along the river channel that was tested with results taken from longitudinal profiles show that the accuracy of the model has improved due to the integration of the aforementioned process-oriented models. After model development and model testing, SWAT-N was then used for the assessment of the EU agricultural policy (CAP reform) on land use change and consequent changes on N-fluxes within the Dill Catchment. giessen.de/geb/volltexte/2007/4531/

Method for oxidizing alkanes using novel porphyrins synthesized from dipyrromethanes and aldehydes

DOEpatents

Wijesekera, Tilak; Lyons, James E.; Ellis, Jr., Paul E.

1999-01-01

The invention comprises a method for the oxidation of alkanes to alcohols and for decomposition of hydroperoxides to alcohols utilizing new compositions of matter, which are metal complexes of porphyrins. Preferred complexes have hydrogen, haloalkyl or haloaryl groups in meso positions, two of the opposed meso atoms or groups being hydrogen or haloaryl, and two of the opposed meso atoms or groups being hydrogen or haloalkyl, but not all four of the meso atoms or groups being hydrogen. Other preferred complexes are ones in which all four of the meso positions are substituted with haloalkyl groups and the beta positions are substituted with halogen atoms. A new method of synthesizing porphyrinogens is also disclosed.

Method for hydroperoxide decomposition using novel porphyrins synthesized from dipyrromethanes and aldehydes

DOEpatents

Wijesekera, T.; Lyons, J.E.; Ellis, P.E. Jr.

1998-03-03

The invention comprises a method for the oxidation of alkanes to alcohols and for decomposition of hydroperoxides to alcohols utilizing new compositions of matter, which are metal complexes of porphyrins. Preferred complexes have hydrogen, haloalkyl or haloaryl groups in meso positions, two of the opposed meso atoms or groups being hydrogen or haloaryl, and two of the opposed meso atoms or groups being hydrogen or haloalkyl, but not all four of the meso atoms or groups being hydrogen. Other preferred complexes are ones in which all four of the meso positions are substituted with haloalkyl groups and the beta positions are substituted with halogen atoms. A new method of synthesizing porphyrinogens is also disclosed.

Method for hydroperoxide decomposition using novel porphyrins synthesized from dipyrromethanes and aldehydes

DOEpatents

Wijesekera, Tilak; Lyons, James E.; Ellis, Jr., Paul E.

1998-01-01

The invention comprises a method for the oxidation of alkanes to alcohols and for decomposition of hydroperoxides to alcohols utilizing new compositions of matter, which are metal complexes of porphyrins. Preferred complexes have hydrogen, haloalkyl or haloaryl groups in meso positions, two of the opposed meso atoms or groups being hydrogen or haloaryl, and two of the opposed meso atoms or groups being hydrogen or haloalkyl, but not all four of the meso atoms or groups being hydrogen. Other preferred complexes are ones in which all four of the meso positions are substituted with haloalkyl groups and the beta positions are substituted with halogen atoms. A new method of synthesizing porphyrinogens is also disclosed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bakach, G. P.; Dudarev, E. F., E-mail: dudarev@spti.tsu.ru; Skosyrskii, A. B.

The results are presented of an experimental investigation into the regularities and mechanisms of the development of thermoelastic martensitic transformation in submicrocrystalline alloy Ti{sub 49.4}Ni{sub 50.6} with different ways of thermo-power actions using the methods of optical microscopy in situ and X-ray diffraction. The peculiarities of localization of martensite transformation at the meso- and macroscale levels in this alloy with submicrocrystalline structure are considered. Experimental data on the relay mechanism of propagation of the martensitic transformation are presented. The interrelation between the localization of the martensitic transformation on the meso-and macroscale levels and deformation behavior under isothermal loading alloy Ti{submore » 49.4}Ni5{sub 0.6} in submicrocrystalline condition are shown and discussed.« less

In Search of the Perfect Photocage: Structure-Reactivity Relationships in meso-Methyl BODIPY Photoremovable Protecting Groups.

PubMed

Slanina, Tomáš; Shrestha, Pradeep; Palao, Eduardo; Kand, Dnyaneshwar; Peterson, Julie A; Dutton, Andrew S; Rubinstein, Naama; Weinstain, Roy; Winter, Arthur H; Klán, Petr

2017-10-25

A detailed investigation of the photophysical parameters and photochemical reactivity of meso-methyl BODIPY photoremovable protecting groups was accomplished through systematic variation of the leaving group (LG) and core substituents as well as substitutions at boron. Efficiencies of the LG release were evaluated using both steady-state and transient absorption spectroscopies as well as computational analyses to identify the optimal structural features. We find that the quantum yields for photorelease with this photocage are highly sensitive to substituent effects. In particular, we find that the quantum yields of photorelease are improved with derivatives with higher intersystem crossing quantum yields, which can be promoted by core heavy atoms. Moreover, release quantum yields are dramatically improved by boron alkylation, whereas alkylation in the meso-methyl position has no effect. Better LGs are released considerably more efficiently than poorer LGs. We find that these substituent effects are additive, for example, a 2,6-diiodo-B-dimethyl BODIPY photocage features quantum yields of 28% for the mediocre LG acetate and a 95% quantum yield of release for chloride. The high chemical and quantum yields combined with the outstanding absorption properties of BODIPY dyes lead to photocages with uncaging cross sections over 10 000 M -1 cm -1 , values that surpass cross sections of related photocages absorbing visible light. These new photocages, which absorb strongly near the second harmonic of an Nd:YAG laser (532 nm), hold promise for manipulating and interrogating biological and material systems with the high spatiotemporal control provided by pulsed laser irradiation, while avoiding the phototoxicity problems encountered with many UV-absorbing photocages. More generally, the insights gained from this structure-reactivity relationship may aid in the development of new highly efficient photoreactions.

Chiral SiO2 and Ag@SiO2 Materials Templated by Complexes Consisting of Comblike Polyethyleneimine and Tartaric Acid.

PubMed

Yao, Dong-Dong; Murata, Hiroki; Tsunega, Seiji; Jin, Ren-Hua

2015-10-26

A facile avenue to fabricate micrometer-sized chiral (L-, D-) and meso-like (dl-) SiO2 materials with unique structures by using crystalline complexes (cPEI/tart), composed of comblike polyethyleneimine (cPEI) and L-, D-, or dl-tartaric acid, respectively, as catalytic templates is reported. Interestingly, both chiral crystalline complexes appeared as regularly left- and right-twisted bundle structures about 10 μm in length and about 5 μm in diameter, whereas the dl-form occurred as circular structures with about 10 μm diameter. Subsequently, SiO2 @cPEI/tart hybrids with high silica content (>55.0 wt %) were prepared by stirring a mixture containing tetramethoxysilane (TMOS) and the aggregates of the crystalline complexes in water. The chiral SiO2 hybrids and calcined chiral SiO2 showed very strong CD signals and a nanofiber-based morphology on their surface, whereas dl-SiO2 showed no CD activity and a nanosheet-packed disklike shape. Furthermore, metallic silver nanoparticles (Ag NPs) were encapsulated in each silica hybrid to obtain chiral (D and L forms) and meso-like (dl form) Ag@SiO2 composites. Also, the reaction between L-cysteine (Lcys) and these Ag@SiO2 composites was preliminarily investigated. Only chiral L- and D-Ag@SiO2 composites promoted the reaction between Lcys and Ag NPs to produce a molecular [Ag-Lcys]n complex with remarkable exciton chirality, whereas the reaction hardly occurred in the case of meso-like (dl-) Ag@SiO2 composite. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Community structure and function of planktonic Crenarchaeota: changes with depth in the South China Sea.

PubMed

Hu, Anyi; Jiao, Nianzhi; Zhang, Chuanlun L

2011-10-01

Marine Crenarchaeota represent a widespread and abundant microbial group in marine ecosystems. Here, we investigated the abundance, diversity, and distribution of planktonic Crenarchaeota in the epi-, meso-, and bathypelagic zones at three stations in the South China Sea (SCS) by analysis of crenarchaeal 16S rRNA gene, ammonia monooxygenase gene amoA involved in ammonia oxidation, and biotin carboxylase gene accA putatively involved in archaeal CO(2) fixation. Quantitative PCR analyses indicated that crenarchaeal amoA and accA gene abundances varied similarly with archaeal and crenarchaeal 16S rRNA gene abundances at all stations, except that crenarchaeal accA genes were almost absent in the epipelagic zone. Ratios of the crenarchaeal amoA gene to 16S rRNA gene abundances decreased ~2.6 times from the epi- to bathypelagic zones, whereas the ratios of crenarchaeal accA gene to marine group I crenarchaeal 16S rRNA gene or to crenarchaeal amoA gene abundances increased with depth, suggesting that the metabolism of Crenarchaeota may change from the epi- to meso- or bathypelagic zones. Denaturing gradient gel electrophoresis profiling of the 16S rRNA genes revealed depth partitioning in archaeal community structures. Clone libraries of crenarchaeal amoA and accA genes showed two clusters: the "shallow" cluster was exclusively derived from epipelagic water and the "deep" cluster was from meso- and/or bathypelagic waters, suggesting that niche partitioning may take place between the shallow and deep marine Crenarchaeota. Overall, our results show strong depth partitioning of crenarchaeal populations in the SCS and suggest a shift in their community structure and ecological function with increasing depth.

Multi-scale learning based segmentation of glands in digital colonrectal pathology images.

PubMed

Gao, Yi; Liu, William; Arjun, Shipra; Zhu, Liangjia; Ratner, Vadim; Kurc, Tahsin; Saltz, Joel; Tannenbaum, Allen

2016-02-01

Digital histopathological images provide detailed spatial information of the tissue at micrometer resolution. Among the available contents in the pathology images, meso-scale information, such as the gland morphology, texture, and distribution, are useful diagnostic features. In this work, focusing on the colon-rectal cancer tissue samples, we propose a multi-scale learning based segmentation scheme for the glands in the colon-rectal digital pathology slides. The algorithm learns the gland and non-gland textures from a set of training images in various scales through a sparse dictionary representation. After the learning step, the dictionaries are used collectively to perform the classification and segmentation for the new image.

Multi-scale learning based segmentation of glands in digital colonrectal pathology images

NASA Astrophysics Data System (ADS)

Gao, Yi; Liu, William; Arjun, Shipra; Zhu, Liangjia; Ratner, Vadim; Kurc, Tahsin; Saltz, Joel; Tannenbaum, Allen

2016-03-01

Digital histopathological images provide detailed spatial information of the tissue at micrometer resolution. Among the available contents in the pathology images, meso-scale information, such as the gland morphology, texture, and distribution, are useful diagnostic features. In this work, focusing on the colon-rectal cancer tissue samples, we propose a multi-scale learning based segmentation scheme for the glands in the colon-rectal digital pathology slides. The algorithm learns the gland and non-gland textures from a set of training images in various scales through a sparse dictionary representation. After the learning step, the dictionaries are used collectively to perform the classification and segmentation for the new image.

Lateral Comparative Investigation of Stromatolites: Astrobiological Implications and Assessment of Scales of Control

NASA Astrophysics Data System (ADS)

Ibarra, Yadira; Corsetti, Frank A.

2016-04-01

The processes that govern the formation of stromatolites, structures that may represent macroscopic manifestation of microbial processes and a clear target for astrobiological investigation, occur at various scales (local versus regional), yet determining their relative importance remains a challenge, particularly for ancient deposits and/or if similar deposits are discovered elsewhere in the Solar System. We build upon the traditional multiscale level approach of investigation (micro-, meso-, macro-, mega-) by including a lateral comparative investigational component of fine- to large-scale features to determine the relative significance of local and/or nonlocal controls on stromatolite morphology, and in the process, help constrain the dominant influences on microbialite formation. In one example of lateral comparative investigation, lacustrine microbialites from the Miocene Barstow Formation (California) display two main mesofabrics: (1) micritic bands that drastically change in thickness and cannot directly be traced between adjacent decimeter-scale subunits and (2) sparry fibrous layers that are strikingly consistent across subunits, suggesting the formation of sparry fibrous layers was influenced by a process larger than the length scale between the subunits (likely lake chemistry). Microbialites from the uppermost Triassic Cotham Member, United Kingdom, occur as meter-scale mounds and contain a characteristic succession of laminated and dendrolitic mesofabrics. The same succession of laminated/dendrolitic couplets can be traced, not only from mound to mound, but over 100 km, indicating a regional-scale influence on very small structures (microns to centimeters) that would otherwise not be apparent without the lateral comparative approach, and demonstrating that the scale of the feature does not necessarily scale with the scope of the process. Thus, the combination of lateral comparative investigations and multiscale analyses can provide an effective approach for evaluating the dominant controls on stromatolite texture and morphology throughout the rock record and potentially on other planets via rover-scale analyses (e.g., Mars).

Chemical and biosynthetic studies of chlorophylls

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huster, M.S.

1988-01-01

Chlorophyll occurrence, structure, biosynthesis, and degradation are discussed. Degradation and ring cleavage of heme is also discussed. The author examines the formation of dihydrobiliverdins by alkaline hydrolysis of zinc(II) meso-trifluoroacetoxypheophoribides, as a possible model for chlorophyll catabolism. {sup 18}O{sub 2}-labelling experiments show that the dihydrobiliverdin terminal lactam oxygens are derived from two different dioxygen molecules, also analogous to the Two Oxygen Molecular mechanism observed in heme degradation. The initially obtained dihydrobiliverdin readily undergoes an isomeric structural transformation, which is proposed as a model for the P{sub R}-P{sub FR} interconversion of the light sensor pigment phytochrome. The generality of the ring-openingmore » reaction is demonstrated with various chlorophyll-derived zinc(II) trifluoroacetoxychlorins, and side reactions of the isocyclic ring are discussed. The synthesis and properties of a chlorophyll-derived meso-oxochlorin are described. Facile one-electron oxidation, and its inhibition by protonation, is demonstrated by NMR, ESR, and cyclic voltammetry studies. Cyclic voltammetry is also used to measure redox potentials of a range of pheophorbide and meso-trifluoroacetoxypheophorbide metal complexes, including an oxochlorin nickel(II) complex. The results are presented of biosynthetic feeding studies of green sulfur bacteria with {sup 13}C- and {sup 14}C-labelled glutamate, glycine, and methionine. This study examines an unusual oxidation of a bacteriomethylpheophorbide 5-ethyl substituent, and describes attempts to elucidate the mechanism by {sup 18}O-labelling studies. Attempts to similarily derivatize a pyropheophorbide 5-methyl substituent are discussed.« less

Multiphysics Simulations of Hot-Spot Initiation in Shocked Insensitive High-Explosive

NASA Astrophysics Data System (ADS)

Najjar, Fady; Howard, W. M.; Fried, L. E.

2010-11-01

Solid plastic-bonded high-explosive materials consist of crystals with micron-sized pores embedded. Under mechanical or thermal insults, these voids increase the ease of shock initiation by generating high-temperature regions during their collapse that might lead to ignition. Understanding the mechanisms of hot-spot initiation has significant research interest due to safety, reliability and development of new insensitive munitions. Multi-dimensional high-resolution meso-scale simulations are performed using the multiphysics software, ALE3D, to understand the hot-spot initiation. The Cheetah code is coupled to ALE3D, creating multi-dimensional sparse tables for the HE properties. The reaction rates were obtained from MD Quantum computations. Our current predictions showcase several interesting features regarding hot spot dynamics including the formation of a "secondary" jet. We will discuss the results obtained with hydro-thermo-chemical processes leading to ignition growth for various pore sizes and different shock pressures.

LB3D: A parallel implementation of the Lattice-Boltzmann method for simulation of interacting amphiphilic fluids

NASA Astrophysics Data System (ADS)

Schmieschek, S.; Shamardin, L.; Frijters, S.; Krüger, T.; Schiller, U. D.; Harting, J.; Coveney, P. V.

2017-08-01

We introduce the lattice-Boltzmann code LB3D, version 7.1. Building on a parallel program and supporting tools which have enabled research utilising high performance computing resources for nearly two decades, LB3D version 7 provides a subset of the research code functionality as an open source project. Here, we describe the theoretical basis of the algorithm as well as computational aspects of the implementation. The software package is validated against simulations of meso-phases resulting from self-assembly in ternary fluid mixtures comprising immiscible and amphiphilic components such as water-oil-surfactant systems. The impact of the surfactant species on the dynamics of spinodal decomposition are tested and quantitative measurement of the permeability of a body centred cubic (BCC) model porous medium for a simple binary mixture is described. Single-core performance and scaling behaviour of the code are reported for simulations on current supercomputer architectures.

The Role of Auroral Imaging in Understanding Ionosphere-Inner Magnetosphere Interactions

NASA Technical Reports Server (NTRS)

Spann, Jim; Khazanov, George; Mende, Stephen

2004-01-01

The more ways we probe the ionosphere and inner magnetosphere, the better we can understand their interaction. For example, the multifaceted imaging of geospace with the IMAGE mission complements the more traditional in situ measurements made with many previous missions. Together they have enabled new knowledge of the ionosphere-magnetosphere (IM) coupling. The role of imaging the aurora in understanding this interaction has received renewed attention recently. Based on in situ data, such as FAST or DMSP, and our recent theories, we believe that imaging multiscale features of the aurora is a key component to gaining insight into the processes and mechanisms at work. This talk will explore how auroral imaging can be used to provide improved insight of the dynamics of IM interaction on micro and meso scales, with an emphasis on the current limitations and future possibilities of quantitative analyses.

Lipid rafts generate digital-like signal transduction in cell plasma membranes.

PubMed

Suzuki, Kenichi G N

2012-06-01

Lipid rafts are meso-scale (5-200 nm) cell membrane domains where signaling molecules assemble and function. However, due to their dynamic nature, it has been difficult to unravel the mechanism of signal transduction in lipid rafts. Recent advanced imaging techniques have revealed that signaling molecules are frequently, but transiently, recruited to rafts with the aid of protein-protein, protein-lipid, and/or lipid-lipid interactions. Individual signaling molecules within the raft are activated only for a short period of time. Immobilization of signaling molecules by cytoskeletal actin filaments and scaffold proteins may facilitate more efficient signal transmission from rafts. In this review, current opinions of how the transient nature of molecular interactions in rafts generates digital-like signal transduction in cell membranes, and the benefits this phenomenon provides, are discussed. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Ultra small angle x-ray scattering in complex mixtures of triacylglycerols

NASA Astrophysics Data System (ADS)

Peyronel, Fernanda; Quinn, Bonnie; Marangoni, Alejandro G.; Pink, David A.

2014-11-01

Ultra-small angle x-ray scattering (USAXS) has been used to elucidate, in situ, the aggregation structure of unsheared model edible oils. Each system comprised one or two solid lipids and a combination of liquid lipids. The 3D nano- to micro-structures of each system were characterized. The length scale investigated, using the Bonse-Hart camera at beamline ID-15D at the Advanced Photon Source, ANL, ranged from 300 Å-10 µm. Using the Unified Fit model, level-1 analysis showed that the scatterers were 2D objects with either a smooth, a rough, or a diffuse surface. These 2D objects had an average radius of gyration Rg1 between 200-1500 Å. Level-2 analysis displayed a slope between -1 and -2. Use of the Guinier-Porod model gave s ≈ 1 thus showing that it was cylinders (TAGwoods) aggregating with fractal dimension 1 ≤ D2 ≤ 2. D2 = 1 is consistent with 1D structures formed from TAGwoods, while D2 = 2 implies that the TAGwoods had formed structures characteristic of diffusion or reaction limited cluster-cluster aggregation (DLCA/RLCA). These aggregates exhibited radii of gyration, Rg2, between 2500 and 6500 Å. Level-3 analyses showed diffuse surfaces, for most of the systems. These interpretations are in accord with theoretical models which studied crystalline nano-platelets (CNPs) coated with nano-scale layers arising from phase separation at the CNP surfaces. These layers could be due to either liquid-liquid phase separation with the CNPs coated, uniformly or non-uniformly, by a diffuse layer of TAGs, or solid-liquid phase separation with the CNPs coated by a rough layer of crystallites. A fundamental understanding of the self-organizing structures arising in these systems helps advance the characterization of fat crystal networks from nanometres to micrometres. This research can be used to design novel fat structures that use healthier fats via nano- and meso-scale structural engineering.

High-performance ionic diode membrane for salinity gradient power generation.

PubMed

Gao, Jun; Guo, Wei; Feng, Dan; Wang, Huanting; Zhao, Dongyuan; Jiang, Lei

2014-09-03

Salinity difference between seawater and river water is a sustainable energy resource that catches eyes of the public and the investors in the background of energy crisis. To capture this energy, interdisciplinary efforts from chemistry, materials science, environmental science, and nanotechnology have been made to create efficient and economically viable energy conversion methods and materials. Beyond conventional membrane-based processes, technological breakthroughs in harvesting salinity gradient power from natural waters are expected to emerge from the novel fluidic transport phenomena on the nanoscale. A major challenge toward real-world applications is to extrapolate existing single-channel devices to macroscopic materials. Here, we report a membrane-scale nanofluidic device with asymmetric structure, chemical composition, and surface charge polarity, termed ionic diode membrane (IDM), for harvesting electric power from salinity gradient. The IDM comprises heterojunctions between mesoporous carbon (pore size ∼7 nm, negatively charged) and macroporous alumina (pore size ∼80 nm, positively charged). The meso-/macroporous membrane rectifies the ionic current with distinctly high ratio of ca. 450 and keeps on rectifying in high-concentration electrolytes, even in saturated solution. The selective and rectified ion transport furthermore sheds light on salinity-gradient power generation. By mixing artificial seawater and river water through the IDM, substantially high power density of up to 3.46 W/m(2) is discovered, which largely outperforms some commercial ion-exchange membranes. A theoretical model based on coupled Poisson and Nernst-Planck equations is established to quantitatively explain the experimental observations and get insights into the underlying mechanism. The macroscopic and asymmetric nanofluidic structure anticipates wide potentials for sustainable power generation, water purification, and desalination.

Effects of Meso-Scale and Small-Scale Interactions on Global Climate. Volume I. Orographic Effects on Global Climate

DTIC Science & Technology

1975-02-28

STATEMENT (ol Ih, »b.tfet »nftod in Block 30. II d/ ffa ,en( Irom Report) It. SUPPLEMENTARY NOTES 19. KEY WORDS (Conllnue on rev«., «ij» (/ nee» fry...given by 3-29 a^M—. K^^M^^M— ■ - - ■ ■■■■ ’■^-•—- P?B«BWWI^WW™’W"W,SIW!«W5F«^IIW»! BPP ^!^^ ..’ i •’ SSS-R-75-2556 Res(T0) L(T" - WC

Meso-Scale and Small-Scale Interactions on Global Climate. Volume II. Radiation Transport Effects on Global Climate

DTIC Science & Technology

1975-02-28

max this peak , which varies substantially over Az = a A0 = 1 , r max we pick an angular increment Ae = T5— o 2 a max 2-72...22°, as into the main diffraction peak . This effect if. en- tirely missed by an equi"alent sphere model. The error incurred by assumption (7...minimize the sum of squares, we pick Q so that this expression is as negative as possible (if it is never negative for 0 ^ 0 £ 1, we are already

Quantitative modeling of soil genesis processes

NASA Technical Reports Server (NTRS)

Levine, E. R.; Knox, R. G.; Kerber, A. G.

1992-01-01

For fine spatial scale simulation, a model is being developed to predict changes in properties over short-, meso-, and long-term time scales within horizons of a given soil profile. Processes that control these changes can be grouped into five major process clusters: (1) abiotic chemical reactions; (2) activities of organisms; (3) energy balance and water phase transitions; (4) hydrologic flows; and (5) particle redistribution. Landscape modeling of soil development is possible using digitized soil maps associated with quantitative soil attribute data in a geographic information system (GIS) framework to which simulation models are applied.

Porting LAMMPS to GPUs.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brown, William Michael; Plimpton, Steven James; Wang, Peng

2010-03-01

LAMMPS is a classical molecular dynamics code, and an acronym for Large-scale Atomic/Molecular Massively Parallel Simulator. LAMMPS has potentials for soft materials (biomolecules, polymers) and solid-state materials (metals, semiconductors) and coarse-grained or mesoscopic systems. It can be used to model atoms or, more generically, as a parallel particle simulator at the atomic, meso, or continuum scale. LAMMPS runs on single processors or in parallel using message-passing techniques and a spatial-decomposition of the simulation domain. The code is designed to be easy to modify or extend with new functionality.

Air-Sea Interaction in the Somali Current Region

NASA Astrophysics Data System (ADS)

Jensen, T. G.; Rydbeck, A.

2017-12-01

The western Indian Ocean is an area of high eddy-kinetic energy generated by local wind-stress curl, instability of boundary currents as well as Rossby waves from the west coast of India and the equatorial wave guide as they reflect off the African coast. The presence of meso-scale eddies and coastal upwelling during the Southwest Monsoon affects the air-sea interaction on those scales. The U.S. Navy's Coupled Ocean-Atmosphere Mesoscale Prediction System (COAMPS) is used to understand and quantify the surface flux, effects on surface waves and the role of Sea Surface Temperature anomalies on ocean-atmosphere coupling in that area. The COAMPS atmosphere model component with 9 km resolution is fully coupled to the Navy Coastal Ocean Model (NCOM) with 3.5 km resolution and the Simulating WAves Nearshore (SWAN) wave model with 10 km resolution. Data assimilation using a 3D-variational approach is included in hindcast runs performed daily since June 1, 2015. An interesting result is that a westward jet associated with downwelling equatorial Rossy waves initiated the reversal from the southward Somali Current found during the northeast monsoon to a northward flow in March 2016 more than a month before the beginning of the southwest monsoon. It is also found that warm SST anomalies in the Somali Current eddies, locally increase surface wind speed due to an increase in the atmospheric boundary layer height. This results in an increase in significant wave height and also an increase in heat flux to the atmosphere. Cold SST anomalies over upwelling filaments have the opposite impacts on air-sea fluxes.

A solid with a hierarchical tetramodal micro-meso-macro pore size distribution

PubMed Central

Ren, Yu; Ma, Zhen; Morris, Russell E.; Liu, Zheng; Jiao, Feng; Dai, Sheng; Bruce, Peter G.

2013-01-01

Porous solids have an important role in addressing some of the major energy-related problems facing society. Here we describe a porous solid, α-MnO2, with a hierarchical tetramodal pore size distribution spanning the micro-, meso- and macro pore range, centred at 0.48, 4.0, 18 and 70 nm. The hierarchical tetramodal structure is generated by the presence of potassium ions in the precursor solution within the channels of the porous silica template; the size of the potassium ion templates the microporosity of α-MnO2, whereas their reactivity with silica leads to larger mesopores and macroporosity, without destroying the mesostructure of the template. The hierarchical tetramodal pore size distribution influences the properties of α-MnO2 as a cathode in lithium batteries and as a catalyst, changing the behaviour, compared with its counterparts with only micropores or bimodal micro/mesopores. The approach has been extended to the preparation of LiMn2O4 with a hierarchical pore structure. PMID:23764887

Porphyrins

DOEpatents

Wijesekera, T.; Lyons, J.E.; Ellis, P.E. Jr.

1996-11-05

The invention comprises new compositions of matter, which are iron, manganese, cobalt or ruthenium complexes of porphyrins having hydrogen, haloalkyl or haloaryl groups in meso positions, two of the opposed meso atoms or groups being hydrogen or haloaryl, and two of the opposed meso atoms or groups being hydrogen or haloalkyl, but not all four of the meso atoms or groups being hydrogen. The invention also comprises new compositions of matter in which all four of the meso positions are substituted with haloalkyl groups and the beta positions are substituted with halogen atoms. A new method of synthesizing porphyrinogens is also provided. The novel compositions and others made according to the process of the invention are useful as hydrocarbon conversion catalysts; for example, for the oxidation of alkanes and the decomposition of hydroperoxides.

Porphyrins

DOEpatents

Wijesekera, Tilak; Lyons, James E.; Ellis, Jr., Paul E.

1996-01-01

The invention comprises new compositions of matter, which are iron, manganese, cobalt or ruthenium complexes of porphyrins having hydrogen, haloalkyl or haloaryl groups in meso positions, two of the opposed meso atoms or groups being hydrogen or haloaryl, and two of the opposed meso atoms or groups being hydrogen or haloalkyl, but not all four of the meso atoms or groups being hydrogen. The invention also comprises new compositions of matter in which all four of the meso positions are substituted with haloalkyl groups and the beta positions are substituted with halogen atoms. A new method of synthesizing porphyrinogens is also provided. The novel compositions and others made according to the process of the invention are useful as hydrocarbon conversion catalysts; for example, for the oxidation of alkanes and the decomposition of hydroperoxides.

Investigation of the Mesoporous Metal-Organic Framework as a New Platform To Study the Transport Phenomena of Biomolecules.

PubMed

Chen, Yao; Hong, Seongmin; Fu, Chung-Wei; Hoang, Tran; Li, Xiao; Valencia, Veronica; Zhang, Zhenjie; Perman, Jason A; Ma, Shengqian

2017-03-29

Mesoporous materials, Tb-mesoMOF and MCM-41, were used to study the transport phenomena of biomolecules entering the interior pores from solution. Vitamins B 12 and B 2 were successfully encapsulated into these mesoporous materials, whereas Tb-mesoMOF (0.33 g of B 12 /g, 0.01 g of B 2 /g) adsorbed a higher amount of vitamin per mass than MCM-41 (0.21 g of B 12 /g, 0.002 g of B 2 /g). The diffusion mechanism of the biomolecules entering Tb-mesoMOF was evaluated using a mathematical model. The Raman spectroscopy studies showed vitamin B 12 has been encapsulated within Tb-mesoMOF's pores, and evaluation of the peak shifts indicated strong interactions linking vitamin B 12 's pyrroline moiety with Tb-mesoMOF's triazine and benzoate rings. Because of these stronger interactions between the vitamins and Tb-mesoMOF, longer egress times were observed than with MCM-41.

First example of a modular porphyrinoid assembly capable of stabilizing different metal ions in a single molecular scaffold.

PubMed

Murugavel, Muthuchamy; Reddy, R V Ramana; Dey, Dhananjay; Sankar, Jeyaraman

2015-10-05

We report the synthesis and characterization of porphyrin-corrole-porphyrin (Por-Cor-Por) hybrids directly linked at the meso-meso positions for the first time. The stability and solubility of the trimer are carefully balanced by adding electron-withdrawing substituents to the corrole ring and sterically bulky groups on the porphyrins. The new hybrids are capable of stabilizing more than one metal ion in a single molecular scaffold. The versatility of the triad has been demonstrated by successfully stabilizing homo- (Ni) and heterotrinuclear (Ni-Cu-Ni) coordination motifs. The solid-state structure of the NiPor-CuCor-PorNi hybrid was revealed by single-crystal X-ray diffraction studies. The Ni(II) porphyrins are significantly ruffled and tilted by 83° from the plane of corrole. The robustness of the synthesized hybrids was reflected in the electrochemical investigations and the redox behaviour of the hybrids show that the oxidation processes are mostly corrole-centred. In particular it is worth noting that the Por-Cor-Por hybrid can further be manipulated due to the presence of substituent-free meso-positions on both the terminals. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Synthesis of hierarchically meso-macroporous TiO2/CdS heterojunction photocatalysts with excellent visible-light photocatalytic activity.

PubMed

Zhao, Haixin; Cui, Shu; Yang, Lan; Li, Guodong; Li, Nan; Li, Xiaotian

2018-02-15

Photocatalysts with a hierarchically porous structure have attracted considerable attention owing to their wide pore size distribution and high surface area, which enhance the efficiency of transporting species to active sites. In this study, hierarchically meso-macroporous TiO 2 photocatalysts decorated with highly dispersed CdS nanoparticles were synthesized via hydrolysis, followed by a hydrothermal treatment. The textural mesopores and interconnected pore framework provided more accessible active sites and efficient mass transport for the photocatalytic process. The light collection efficiency was enhanced because of multiple scattering of incident light in the macropores. Moreover, the formation of a heterojunction between the CdS and TiO 2 nanoparticles extended the photoresponse of TiO 2 to the visible-light range and enhanced the charge separation efficiency. Therefore, the hierarchically meso-macroporous TiO 2 /CdS photocatalysts exhibited excellent photocatalytic activity for the degradation of rhodaming B under visible-light irradiation. Trapping experiments demonstrated that superoxide radicals (O 2 - ) and hydroxyl radicals (OH) were the main active species in photocatalysis. A reasonable photocatalytic mechanism of TiO 2 /CdS heterojunction photocatalysts was also presented. Copyright © 2017 Elsevier Inc. All rights reserved.

Highly hydrophilic poly(vinylidene fluoride)/meso-titania hybrid mesoporous membrane for photocatalytic membrane reactor in water

NASA Astrophysics Data System (ADS)

Wang, Meng; Yang, Guang; Jin, Peng; Tang, Hao; Wang, Huanhuan; Chen, Yong

2016-01-01

The high hydrophobicity of poly(vinylidene fluoride) (PVDF) membrane remains an obstacle to be applied in some purification processes of water or wastewater. Herein, a highly hydrophilic hybrid mesoporous titania membrane composed of mesoporous anatase titania (meso-TiO2) materials inside the three-dimensional (3D) macropores of PVDF membrane was successfully prepared by using the dual-templated synthesis method combined with solvent extraction and applied as the photocatalytic membrane reactor for the photodegredation of organic dye in water. The structure and the properties of as-prepared hybrid membranes were characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), X-ray diffraction (XRD), nitrogen adsorption-desorption and contact angle measurements. It was found that the hydrophilicity of PVDF membrane can be significantly improved by filling mesoporous TiO2 inside the 3D macropores of PVDF membrane. Moreover, such a PVDF/meso-TiO2 hybrid membrane exhibits promising photocatalytic degradation of dye in water due to the existence of mesoporous anatase TiO2 materials inside PVDF membrane. This study provides a new strategy to simultaneously introduce hydrophilicity and some desirable properties into PVDF and other hydrophobic membranes.

Linking landscape characteristics to mineral site use by band-tailed pigeons in Western Oregon: Coarse-filter conservation with fine-filter tuning

USGS Publications Warehouse

Overton, C.T.; Schmitz, R.A.; Casazza, Michael L.

2006-01-01

Mineral sites are scarce resources of high ion concentration used heavily by the Pacific Coast subpopulation of band-tailed pigeons. Over 20% of all known mineral sites used by band-tailed pigeons in western Oregon, including all hot springs, have been abandoned. Prior investigations have not analyzed stand or landscape level habitat composition in relation to band-tailed pigeon use of mineral sites. We used logistic regression models to evaluate the influence of habitat types, identified from Gap Analysis Program (GAP) products at two spatial scales, on the odds of mineral site use in Oregon (n = 69 currently used and 20 historically used). Our results indicated that the odds of current use were negatively associated with non-forested terrestrial and private land area around mineral sites. Similarly, the odds of current mineral site use were positively associated with forested and special status (GAP stewardship codes 1 and 2) land area. The most important variable associated with the odds of mineral site use was the amount of non-forested land cover at either spatial scale. Our results demonstrate the utility of meso-scale geographic information designed for regional, coarse-filter approaches to conservation in fine-filter investigation of wildlife-habitat relationships. Adjacent landcover and ownership status explain the pattern of use for known mineral sites in western Oregon. In order for conservation and management activities for band-tailed pigeons to be successful, mineral sites need to be addressed as important and vulnerable resources. Management of band-tailed pigeons should incorporate the potential for forest management activities and land ownership patterns to influence the risk of mineral site abandonment.

Anti-inflammation performance of curcumin-loaded mesoporous calcium silicate cement.

PubMed

Chen, Yuan-Chien; Shie, Ming-You; Wu, Yuan-Haw Andrew; Lee, Kai-Xing Alvin; Wei, Li-Ju; Shen, Yu-Fang

2017-09-01

Calcium silicate (CS) cements have excellent bioactivity and can induce the bone-like apatite formation. They are good biomaterials for bone tissue engineering and bone regenerative medicine. However, they have degradability and the dissolved CS can cause the inflammatory response at the early post-implantation stage. The purpose of this study was to design and prepare the curcumin-loaded mesoporous CS (MesoCS/curcumin) cements as a strategy to reduce the inflammatory reaction after implantation. The MesoCS/curcumin cements were designed and prepared. The characteristics of MesoCS/curcumin specimens were examined by transmission electron microscopy (TEM), X-ray diffraction (XRD) and scanning electron microscopy (SEM). Their physical properties, biocompatibility, and anti-inflammatory ability were also evaluated. The MesoCS/curcumin cements displayed excellent biocompatibility and physical properties. Their crystalline characterizations were very similar with MesoCS cements. After soaking in simulated body fluid, the bone-like apatite layer of the MesoCS/curcumin cements could be formed. In addition, it could inhibit the expression of tumor necrosis factor-α (TNF-α) and interleukin-1 (IL-1) after inflammation reaction induced by lipopolysaccharides and had good anti-inflammatory ability. Adding curcumin in MesoCS cements can reduce the inflammatory reaction, but does not affect the original biological activity and properties of MesoCS cements. It can provide a good strategy to inhibit the inflammatory reaction after implantation for bone tissue engineering and bone regenerative medicine. Copyright © 2017. Published by Elsevier B.V.

High-Performance Multi-Fuel AMTEC Power System

DTIC Science & Technology

2000-12-01

AMTEC technology has demonstrated thermal to electric conversion efficiencies and power densities which make it an attractive option for meso-scaic...power generation. This report details development of an integrated, logistics-fueled, 500 W AMTEC power supply. The development targeted 2O% AMTEC ...cylindrical multi-tube/single cell AMTEC configuration with effective management of alkali metal flow; scaling down and integrating a multi-fuel micro-combustor

Shock Wave Propagation in Cementitious Materials at Micro/Meso Scales

DTIC Science & Technology

2015-08-31

ABSTRACT 16. SECURITY CLASSIFICATION OF: Shock wave response of heterogeneous materials like cement and concrete is greatly influenced by the...constituents and their statistical distributions. The microstructure of cement is complex due to the presence of unhydrated water, nano /micro pores, and other...heterogeneous materials like cement and concrete is greatly influenced by the constituents and their statistical distributions. The microstructure of cement

Trends in spatio-temporal dynamics of visceral leishmaniasis cases in a highly-endemic focus of Bihar, India: an investigation based on GIS tools.

PubMed

Mandal, Rakesh; Kesari, Shreekant; Kumar, Vijay; Das, Pradeep

2018-04-02

Visceral leishmaniasis (VL) in Bihar State (India) continues to be endemic, despite the existence of effective treatment and a vector control program to control disease morbidity. A clear understanding of spatio-temporal distribution of VL may improve surveillance and control implementation. This study explored the trends in spatio-temporal dynamics of VL endemicity at a meso-scale level in Vaishali District, based on geographical information systems (GIS) tools and spatial statistical analysis. A GIS database was used to integrate the VL case data from the study area between 2009 and 2014. All cases were spatially linked at a meso-scale level. Geospatial techniques, such as GIS-layer overlaying and mapping, were employed to visualize and detect the spatio-temporal patterns of a VL endemic outbreak across the district. The spatial statistic Moran's I Index (Moran's I) was used to simultaneously evaluate spatial-correlation between endemic villages and the spatial distribution patterns based on both the village location and the case incidence rate (CIR). Descriptive statistics such as mean, standard error, confidence intervals and percentages were used to summarize the VL case data. There were 624 endemic villages with 2719 (average 906 cases/year) VL cases during 2012-2014. The Moran's I revealed a cluster pattern (P < 0.05) of CIR distribution at the meso-scale level. On average, 68 villages were newly-endemic each year. Of which 93.1% of villages' endemicity were found to have occurred on the peripheries of the previous year endemic villages. The mean CIR of the endemic villages that were peripheral to the following year newly-endemic villages, compared to all endemic villages of the same year, was higher (P < 0.05). The results show that the VL endemicity of new villages tends to occur on the periphery of villages endemic in the previous year. High-CIR plays a major role in the spatial dispersion of the VL cases between non-endemic and endemic villages. This information can help achieve VL elimination throughout the Indian subcontinent by improving vector control design and implementation in highly-endemic district.

Lutein, zeaxanthin, and meso-zeaxanthin: The basic and clinical science underlying carotenoid-based nutritional interventions against ocular disease.

PubMed

Bernstein, Paul S; Li, Binxing; Vachali, Preejith P; Gorusupudi, Aruna; Shyam, Rajalekshmy; Henriksen, Bradley S; Nolan, John M

2016-01-01

The human macula uniquely concentrates three carotenoids: lutein, zeaxanthin, and meso-zeaxanthin. Lutein and zeaxanthin must be obtained from dietary sources such as green leafy vegetables and orange and yellow fruits and vegetables, while meso-zeaxanthin is rarely found in diet and is believed to be formed at the macula by metabolic transformations of ingested carotenoids. Epidemiological studies and large-scale clinical trials such as AREDS2 have brought attention to the potential ocular health and functional benefits of these three xanthophyll carotenoids consumed through the diet or supplements, but the basic science and clinical research underlying recommendations for nutritional interventions against age-related macular degeneration and other eye diseases are underappreciated by clinicians and vision researchers alike. In this review article, we first examine the chemistry, biochemistry, biophysics, and physiology of these yellow pigments that are specifically concentrated in the macula lutea through the means of high-affinity binding proteins and specialized transport and metabolic proteins where they play important roles as short-wavelength (blue) light-absorbers and localized, efficient antioxidants in a region at high risk for light-induced oxidative stress. Next, we turn to clinical evidence supporting functional benefits of these carotenoids in normal eyes and for their potential protective actions against ocular disease from infancy to old age. Copyright © 2015 Elsevier Ltd. All rights reserved.

Macro-meso-microsystems integration in LTCC : LDRD report.

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Smet, Dennis J.; Nordquist, Christopher Daniel; Turner, Timothy Shawn

2007-03-01

Low Temperature Cofired Ceramic (LTCC) has proven to be an enabling medium for microsystem technologies, because of its desirable electrical, physical, and chemical properties coupled with its capability for rapid prototyping and scalable manufacturing of components. LTCC is viewed as an extension of hybrid microcircuits, and in that function it enables development, testing, and deployment of silicon microsystems. However, its versatility has allowed it to succeed as a microsystem medium in its own right, with applications in non-microelectronic meso-scale devices and in a range of sensor devices. Applications include silicon microfluidic ''chip-and-wire'' systems and fluid grid array (FGA)/microfluidic multichip modulesmore » using embedded channels in LTCC, and cofired electro-mechanical systems with moving parts. Both the microfluidic and mechanical system applications are enabled by sacrificial volume materials (SVM), which serve to create and maintain cavities and separation gaps during the lamination and cofiring process. SVMs consisting of thermally fugitive or partially inert materials are easily incorporated. Recognizing the premium on devices that are cofired rather than assembled, we report on functional-as-released and functional-as-fired moving parts. Additional applications for cofired transparent windows, some as small as an optical fiber, are also described. The applications described help pave the way for widespread application of LTCC to biomedical, control, analysis, characterization, and radio frequency (RF) functions for macro-meso-microsystems.« less

Seasonal variability of water transport through the Straits of Gibraltar, Sicily and Corsica, derived from a high-resolution model of the Mediterranean circulation

NASA Astrophysics Data System (ADS)

Béranger, K.; Mortier, L.; Crépon, M.

2005-08-01

The variability of the water transport through three major straits of the Mediterranean Sea (Gibraltar, Sicily and Corsica) was investigated using a high-resolution model. This model of the Mediterranean circulation was developed in the context of the Mercator project. The region of interest is the western Mediterranean between the Strait of Gibraltar and the Strait of Sicily. The major water masses and the winter convection in the Gulf of Lions were simulated. The model reproduced the meso-scale and large-scale patterns of the circulation in very good agreement with recent observations. The western and the eastern gyres of the Alboran Sea were observed but high interannual variability was noticed. The Algerian Current splits into several branches at the longitude of the Strait of Sicily level, forming the Tyrrhenian branch, and, the Atlantic Ionian Stream and the Atlantic Tunisian Current in the eastern Mediterranean. The North Current retroflexed north of the Balearic Islands and a dome structure was observed in the Gulf of Lions. The cyclonic barotropic Algerian gyre, which was recently observed during the MATER and ELISA experiment, was evidenced in the simulation. From time-series of 10-day mean transport, the three straits presented a high variability at short time-scales. The transport was generally maximum, in April for the Strait of Gibraltar, in November for the Strait of Sicily, and in January for the Strait of Corsica. The amplitudes of the transport through the Straits of Gibraltar (0.11 Sv) and Sicily (0.30 Sv) presented a weaker seasonal variability than that of the Strait of Corsica (0.70 Sv). The study of the relation between transport and wind forcing showed that the transport through the Strait of Gibraltar is dependent on local zonal wind over short time-scales (70%), which was not the case for the other straits (less than 30%). The maximum (minimum) of the transport occurred for an eastward (westward) wind stress in the strait. An interannual event was noticed in November-December 2001, which corresponded to a very low transport (0.3 Sv), which was characterised by a cyclonic circulation in the western Alboran Sea. That circulation was also reproduced by the model for other periods than winter during the interannual simulation. The transport through the Strait of Sicily is not influenced by local wind. The wind stress curl of the northwestern Mediterranean influenced the transport through the Strait of Corsica.

Facile and green synthesis of mesoporous Co3O4 nanocubes and their applications for supercapacitors

NASA Astrophysics Data System (ADS)

Liu, Xiangmei; Long, Qing; Jiang, Chunhui; Zhan, Beibei; Li, Chen; Liu, Shujuan; Zhao, Qiang; Huang, Wei; Dong, Xiaochen

2013-06-01

Nanostructured Co3O4 materials attracted significant attention due to their exceptional electrochemical (pseudo-capacitive) properties. However, rigorous preparation conditions are needed to control the size (especially nanosize), morphology and size distribution of the products obtained by conventional methods. Herein, we describe a novel one step shape-controlled synthesis of uniform Co3O4 nanocubes with a size of 50 nm with the existence of mesoporous carbon nanorods (meso-CNRs). In this synthesis process, meso-CNRs not only act as a heat receiver to directly obtain Co3O4 eliminating the high-temperature post-calcination, but also control the morphology of the resulting Co3O4 to form nanocubes with uniform distribution. More strikingly, mesoporous Co3O4 nanocubes are obtained by further thermal treatment. The structure and morphology of the samples were characterized by scanning electron microscopy, transmission electron microscopy and X-ray diffraction. A possible formation mechanism of mesoporous Co3O4 nanocubes is proposed here. Electrochemical tests have revealed that the prepared mesoporous Co3O4 nanocubes demonstrate a remarkable performance in supercapacitor applications due to the porous structure, which endows fast ion and electron transfer.Nanostructured Co3O4 materials attracted significant attention due to their exceptional electrochemical (pseudo-capacitive) properties. However, rigorous preparation conditions are needed to control the size (especially nanosize), morphology and size distribution of the products obtained by conventional methods. Herein, we describe a novel one step shape-controlled synthesis of uniform Co3O4 nanocubes with a size of 50 nm with the existence of mesoporous carbon nanorods (meso-CNRs). In this synthesis process, meso-CNRs not only act as a heat receiver to directly obtain Co3O4 eliminating the high-temperature post-calcination, but also control the morphology of the resulting Co3O4 to form nanocubes with uniform distribution. More strikingly, mesoporous Co3O4 nanocubes are obtained by further thermal treatment. The structure and morphology of the samples were characterized by scanning electron microscopy, transmission electron microscopy and X-ray diffraction. A possible formation mechanism of mesoporous Co3O4 nanocubes is proposed here. Electrochemical tests have revealed that the prepared mesoporous Co3O4 nanocubes demonstrate a remarkable performance in supercapacitor applications due to the porous structure, which endows fast ion and electron transfer. Electronic supplementary information (ESI) available. See DOI: 10.1039/c3nr00495c

Meso-Cenozoic evolution of the Tuareg Shield (Algeria, Sahara): insights from new thermochronological data

NASA Astrophysics Data System (ADS)

Rougier, Sylvain; Missenard, Yves; Gautheron, Cécile; Barbarand, Jocelyn; Zeyen, Hermann; Pinna, Rosella; Liégeois, Jean-Paul; Bonin, Bernard; Ouabadi, Aziouz; El-Messaoud Derder, Mohammed; Frizon de Lamotte, Dominique; Kettouche, Djouher

2013-04-01

In North Africa, Meso-Cenozoic large scale topographic swells, such as Hoggar, Tibesti or Darfur domes, are superimposed to a Paleozoic arch and basin morphology which characterizes this region. Although these topographic highs are associated to Cenozoic intraplate volcanism, their development remains poorly constrained, both from temporal and spatial points of view. This study is focused on the Tuareg Shield bulge, a topographic high where Precambrian rocks, exposed over 500000 km², can reach 2400 m above sea level (Atakor district, Hoggar, South Algeria). While presumed Cretaceous sedimentary remnants, resting unconformably over the basement, suggest a possible stage of weak topography during the Mesozoic, current high topography is emphasized by <35 Ma volcanic formations, mostly basaltic in composition. In this context, we present first apatite (U-Th)/He thermochronological data acquired across the whole swell (Rougier et al., Geology, in press). Mean ages range from 78 ± 22 Ma to 13 ± 3 Ma. These results demonstrate the existence of a widespread Eocene exhumation of the shield before volcanic activity began. In the northeastern part of the swell, Cretaceous sedimentary remnants unconformably lying on the basement close to our samples evidence that they were near the surface at that time. We show that basement rocks have thus suffered a subsequent heating stage at 60-80 °C. We also present new apatite fission track ages on same samples. Central ages range from 71 ± 6 to 285 ± 29 Ma. When track length measurements were possible, preliminary modelings of the time-temperature history were performed. As previously deduced from apatite (U-Th)/He analyzes, these modelings show that samples underwent a heating to at least 80°C before their Late Eocene exhumation. Moreover, they also indicate that samples underwent another cooling stage during Lower Cretaceous, prior to Upper Cretaceous/Paleogene heating. We interpret these results as an evidence of a large-scale subsidence stage after the Cretaceous and until the Eocene, which allowed the deposition of a 1.5 to 3 km thick sedimentary cover and a heating at ~80°C of the currently outcropping basement. During the Eocene, the establishment of a thermal anomaly beneath the Tuareg Shield lithosphere resulted in erosion of the major part of this cover and, since 35 Ma, the development of intraplate volcanism.

Protein-protein binding before and after photo-modification of albumin

NASA Astrophysics Data System (ADS)

Rozinek, Sarah C.; Glickman, Randolph D.; Thomas, Robert J.; Brancaleon, Lorenzo

2016-03-01

Bioeffects of directed-optical-energy encompass a wide range of applications. One aspect of photochemical interactions involves irradiating a photosensitizer with visible light in order to induce protein unfolding and consequent changes in function. In the past, irradiation of several dye-protein combinations has revealed effects on protein structure. Beta lactoglobulin, human serum albumin (HSA) and tubulin have all been photo-modified with meso-tetrakis(4- sulfonatophenyl)porphyrin (TSPP) bound, but only in the case of tubulin has binding caused a verified loss of biological function (loss of ability to form microtubules) as a result of this light-induced structural change. The current work questions if the photo-induced structural changes that occur to HSA, are sufficient to disable its biological function of binding to osteonectin. The albumin-binding protein, osteonectin, is about half the molecular weight of HSA, so the two proteins and their bound product can be separated and quantified by size exclusion high performance liquid chromatography. TSPP was first bound to HSA and irradiated, photo-modifying the structure of HSA. Then native HSA or photo-modified HSA (both with TSPP bound) were compared, to assess loss in HSA's innate binding ability as a result of light-induced structure modification.

Marine boundary layer structure as observed by A-train satellites

DOE PAGES

Luo, Tao; Wang, Zhien; Zhang, Damao; ...

2016-05-13

The marine boundary layer (MBL) structure is important to the marine low cloud processes, and the exchange of heat, momentum, and moisture between oceans and the low atmosphere. This study examines the MBL structure over the eastern Pacific region and further explores the controlling factors of MBL structure over the global oceans with a new 4-year satellite-based data set. The MBL top (boundary layer height, BLH) and the mixing layer height (MLH) were identified using the MBL aerosol lidar backscattering from the CALIPSO (Cloud–Aerosol Lidar and Infrared Pathfinder Satellite Observations). Results showed that the MBL is generally decoupled with MLH ∕ BLHmore » ratio ranging from  ∼  0.5 to  ∼  0.8 over the eastern Pacific Ocean region. The MBL decoupling magnitude is mainly controlled by estimated inversion strength (EIS), which in turn controls the cloud top entrainment process. The systematic differences between drizzling and non-drizzling stratocumulus tops also show dependence on EIS. This may be related to the meso-scale circulations or gravity wave in the MBL. Further analysis indicates that the MBL shows a similar decoupled structure for clear-sky and cumulus-cloud-topped conditions, but is better mixed under stratiform cloud breakup and overcast conditions.« less

Dynamical tests on fiber optic data taken from the riser section of a circulating fluidized bed

DOE Office of Scientific and Technical Information (OSTI.GOV)

Taylor, E.M.; Guenther, C.P.; Breault, R.W.

2007-11-01

Dynamical tests have been applied to fiber optic data taken from a cold-flow circulating fluidized bed to characterize flow conditions, identify three time and/or length scales (macro, meso, and micro), and understand the contribution these scales have on the raw data. The characteristic variable analyzed is the raw voltage signal obtained from a fiber-optic probe taken at various axial and radial positions under different loading conditions so that different flow regimes could be attained. These experiments were carried out with the bed material of 812 μm cork particles. The characterization was accomplished through analysis of the distribution of the signalmore » through the third and fourth moments of skewness and excess kurtosis. A generalization of the autocorrelation function known as the average mutual information function was analyzed by examining the function’s first minimum, identifying the point at which successive elements are no longer correlated. Further characterization was accomplished through the correlation dimension, a measure of the complexity of the attractor. Lastly, the amount of disorder of the system is described by a Kolmogorov-type entropy estimate. All six aforementioned tests were also implemented on ten levels of detail coefficients resulting from a discrete wavelet transformation of the same signal as used above. Through this analysis it is possible to identify and describe micro (particle level), meso (clustering or turbulence level), and macro (physical or dimensional level) length scales even though some literature considers these scales inseparable [6]. This investigation also used detail wavelet coefficients in conjunction with ANOVA analysis to show which scales have the most impact on the raw signal resulting from local hydrodynamic conditions.« less

Method of preparing meso-haloalkylporphyrins

DOEpatents

Wijesekera, Tilak; Lyons, James E.; Ellis, Jr., Paul E.; Bhinde, Manoj V.

1998-01-01

Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides. Also disclosed is a process for the preparation of meso-halocarbyl-porphyrins which comprises contacting a halocarbyl dipyrromethane with a halocarbyl-substituted aldehyde in the presence of an acid granular solid catalyst. Also disclosed is a process for the preparation of meso-halocarbyl-porphyrins which comprises contacting a halocarbyl dipyrromethane with a halocarbyl-substituted aldehyde in the presence of an acid granular solic catalyst.

Ge/GeO2-Ordered Mesoporous Carbon Nanocomposite for Rechargeable Lithium-Ion Batteries with a Long-Term Cycling Performance.

PubMed

Zeng, Lingxing; Huang, Xiaoxia; Chen, Xi; Zheng, Cheng; Qian, Qingrong; Chen, Qinghua; Wei, Mingdeng

2016-01-13

Germanium-based nanostructures are receiving intense interest in lithium-ion batteries because they have ultrahigh lithium ion storage ability. However, the Germanium-based anodes undergo the considerably large volume change during the charge/discharge processes, leading to a fast capacity fade. In the present work, a Ge/GeO2-ordered mesoporous carbon (Ge/GeO2-OMC) nanocomposite was successfully fabricated via a facile nanocasting route by using mesoporous carbon as a nanoreactor, and was then used as an anode for lithium-ion batteries. Benefited from its unique three-dimensional "meso-nano" structure, the Ge/GeO2-OMC nanocomposite exhibited large reversible capacity, excellent long-time cycling stability and high rate performance. For instance, a large reversible capacity of 1018 mA h g(-1) was obtained after 100 cycles at a current density of 0.1 A g(-1), which might be attributed to the unique structure of the Ge/GeO2-OMC nanocomposite. In addition, a reversible capacity of 492 mA h g(-1) can be retained when cycled to 500 cycles at a current density of 1 A g(-1).

A comprehensive review of the lipid cubic phase or in meso method for crystallizing membrane and soluble proteins and complexes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Caffrey, Martin, E-mail: martin.caffrey@tcd.ie

A comprehensive and up-to-date review of the lipid cubic phase or in meso method for crystallizing membrane and soluble proteins and complexes is reported. Recent applications of the method for in situ serial crystallography at X-ray free-electron lasers and synchrotrons are described. The lipid cubic phase or in meso method is a robust approach for crystallizing membrane proteins for structure determination. The uptake of the method is such that it is experiencing what can only be described as explosive growth. This timely, comprehensive and up-to-date review introduces the reader to the practice of in meso crystallogenesis, to the associated challengesmore » and to their solutions. A model of how crystallization comes about mechanistically is presented for a more rational approach to crystallization. The possible involvement of the lamellar and inverted hexagonal phases in crystallogenesis and the application of the method to water-soluble, monotopic and lipid-anchored proteins are addressed. How to set up trials manually and automatically with a robot is introduced with reference to open-access online videos that provide a practical guide to all aspects of the method. These range from protein reconstitution to crystal harvesting from the hosting mesophase, which is noted for its viscosity and stickiness. The sponge phase, as an alternative medium in which to perform crystallization, is described. The compatibility of the method with additive lipids, detergents, precipitant-screen components and materials carried along with the protein such as denaturants and reducing agents is considered. The powerful host and additive lipid-screening strategies are described along with how samples that have low protein concentration and cell-free expressed protein can be used. Assaying the protein reconstituted in the bilayer of the cubic phase for function is an important element of quality control and is detailed. Host lipid design for crystallization at low temperatures and for large proteins and complexes is outlined. Experimental phasing by heavy-atom derivatization, soaking or co-crystallization is routine and the approaches that have been implemented to date are described. An overview and a breakdown by family and function of the close to 200 published structures that have been obtained using in meso-grown crystals are given. Recommendations for conducting the screening process to give a more productive outcome are summarized. The fact that the in meso method also works with soluble proteins should not be overlooked. Recent applications of the method for in situ serial crystallography at X-ray free-electron lasers and synchrotrons are described. The review ends with a view to the future and to the bright prospects for the method, which continues to contribute to our understanding of the molecular mechanisms of some of nature’s most valued proteinaceous robots.« less

Re-Making the Middle: Dis-Intermediation in International Context

ERIC Educational Resources Information Center

Lubienski, Christopher

2014-01-01

Recent reforms in England's education system have been justified on the grounds that other countries have pursued similar approaches to education reform. Many such policies that by-pass or otherwise diminish meso-level institutions demonstrate a commitment to the idea of devolving authority to local actors. The current reforms in England and…

Periodization in Team Sport Games - A Review of Current Knowledge and Modern Trends in Competitive Sports

PubMed Central

Lyakh, Vladimir; Bujas, Przemysław; Witkowski, Zbigniew; Zając, Tomasz; Litkowycz, Ryszard; Banyś, Damian

2016-01-01

Abstract The main goal of this study was to present a review of current knowledge and modern trends in periodization of the training process in team sports. The research objectives were: an analysis of various aspects of periodization of the annual training cycle for elite athletes practicing team sport games, an attempt to determine both the examined and unexamined issues related with periodization of training as well as to indicate directions for further research, and finally, presentation of different training loads and competitions in micro-, meso- and macrocycles. The research consisted of the analysis and generalization of the bibliography, methods of monitoring training and competition loads of the Polish national U17 female soccer team in the seasons 2011/2012 and 2012/2013, as well as of the female basketball division one club in the season 2014/2015. Findings of the present study indicate resolved as well as unresolved aspects of annual training cycle periodization in team sport games and provide information on the types of training and competitive workload planning in micro-, meso- and macrocycles.

The dual pathway model of AD/HD: an elaboration of neuro-developmental characteristics.

PubMed

Sonuga-Barke, Edmund J S

2003-11-01

The currently dominant neuro-cognitive model of Attention Deficit Hyperactivity Disorder (AD/HD) presents the condition as executive dysfunction (EDF) underpinned by disturbances in the fronto-dorsal striatal circuit and associated dopaminergic branches (e.g. meso-cortical). In contrast, motivationally-based accounts focus on altered reward processes and implicate fronto-ventral striatal reward circuits and those meso-limbic branches that terminate in the ventral striatum especially the nucleus accumbens. One such account, delay aversion (DEL), presents AD/HD as a motivational style-characterised by attempts to escape or avoid delay-arising from fundamental disturbances in these reward centres. While traditionally regarded as competing, EDF and DEL models have recently been presented as complimentary accounts of two psycho-patho-physiological subtypes of AD/HD with different developmental pathways, underpinned by different cortico-striatal circuits and modulated by different branches of the dopamine system. In the current paper we describe the development of this model in more detail. We elaborate on the neuro-circuitry possibly underpinning these two pathways and explore their developmental significance within a neuro-ecological framework.

Differences in meiofauna communities with sediment depth are greater than habitat effects on the New Zealand continental margin: implications for vulnerability to anthropogenic disturbance

PubMed Central

Leduc, Daniel; Rowden, Ashley A.; Clark, Malcolm R.; Probert, P. Keith; Berkenbusch, Katrin; Neira, Carlos

2016-01-01

Studies of deep-sea benthic communities have largely focused on particular (macro) habitats in isolation, with few studies considering multiple habitats simultaneously in a comparable manner. Compared to mega-epifauna and macrofauna, much less is known about habitat-related variation in meiofaunal community attributes (abundance, diversity and community structure). Here, we investigated meiofaunal community attributes in slope, canyon, seamount, and seep habitats in two regions on the continental slope of New Zealand (Hikurangi Margin and Bay of Plenty) at four water depths (700, 1,000, 1,200 and 1,500 m). We found that patterns were not the same for each community attribute. Significant differences in abundance were consistent across regions, habitats, water and sediment depths, while diversity and community structure only differed between sediment depths. Abundance was higher in canyon and seep habitats compared with other habitats, while between sediment layer, abundance and diversity were higher at the sediment surface. Our findings suggest that meiofaunal community attributes are affected by environmental factors that operate on micro- (cm) to meso- (0.1–10 km), and regional scales (> 100 km). We also found a weak, but significant, correlation between trawling intensity and surface sediment diversity. Overall, our results indicate that variability in meiofaunal communities was greater at small scale than at habitat or regional scale. These findings provide new insights into the factors controlling meiofauna in these deep-sea habitats and their potential vulnerability to anthropogenic activities. PMID:27441114

Examples of data assimilation in mesoscale models

NASA Technical Reports Server (NTRS)

Carr, Fred; Zack, John; Schmidt, Jerry; Snook, John; Benjamin, Stan; Stauffer, David

1993-01-01

The keynote address was the problem of physical initialization of mesoscale models. The classic purpose of physical or diabatic initialization is to reduce or eliminate the spin-up error caused by the lack, at the initial time, of the fully developed vertical circulations required to support regions of large rainfall rates. However, even if a model has no spin-up problem, imposition of observed moisture and heating rate information during assimilation can improve quantitative precipitation forecasts, especially early in the forecast. The two key issues in physical initialization are the choice of assimilating technique and sources of hydrologic/hydrometeor data. Another example of data assimilation in mesoscale models was presented in a series of meso-beta scale model experiments with and 11 km version of the MASS model designed to investigate the sensitivity of convective initiation forced by thermally direct circulations resulting from differential surface heating to four dimensional assimilation of surface and radar data. The results of these simulations underscore the need to accurately initialize and simulate grid and sub-grid scale clouds in meso- beta scale models. The status of the application of the CSU-RAMS mesoscale model by the NOAA Forecast Systems Lab for producing real-time forecasts with 10-60 km mesh resolutions over (4000 km)(exp 2) domains for use by the aviation community was reported. Either MAPS or LAPS model data are used to initialize the RAMS model on a 12-h cycle. The use of MAPS (Mesoscale Analysis and Prediction System) model was discussed. Also discussed was the mesobeta-scale data assimilation using a triply-nested nonhydrostatic version of the MM5 model.

Spatial heterogeneity and risk factors for stunting among children under age five in Ethiopia: A Bayesian geo-statistical model.

PubMed

Hagos, Seifu; Hailemariam, Damen; WoldeHanna, Tasew; Lindtjørn, Bernt

2017-01-01

Understanding the spatial distribution of stunting and underlying factors operating at meso-scale is of paramount importance for intervention designing and implementations. Yet, little is known about the spatial distribution of stunting and some discrepancies are documented on the relative importance of reported risk factors. Therefore, the present study aims at exploring the spatial distribution of stunting at meso- (district) scale, and evaluates the effect of spatial dependency on the identification of risk factors and their relative contribution to the occurrence of stunting and severe stunting in a rural area of Ethiopia. A community based cross sectional study was conducted to measure the occurrence of stunting and severe stunting among children aged 0-59 months. Additionally, we collected relevant information on anthropometric measures, dietary habits, parent and child-related demographic and socio-economic status. Latitude and longitude of surveyed households were also recorded. Local Anselin Moran's I was calculated to investigate the spatial variation of stunting prevalence and identify potential local pockets (hotspots) of high prevalence. Finally, we employed a Bayesian geo-statistical model, which accounted for spatial dependency structure in the data, to identify potential risk factors for stunting in the study area. Overall, the prevalence of stunting and severe stunting in the district was 43.7% [95%CI: 40.9, 46.4] and 21.3% [95%CI: 19.5, 23.3] respectively. We identified statistically significant clusters of high prevalence of stunting (hotspots) in the eastern part of the district and clusters of low prevalence (cold spots) in the western. We found out that the inclusion of spatial structure of the data into the Bayesian model has shown to improve the fit for stunting model. The Bayesian geo-statistical model indicated that the risk of stunting increased as the child's age increased (OR 4.74; 95% Bayesian credible interval [BCI]:3.35-6.58) and among boys (OR 1.28; 95%BCI; 1.12-1.45). However, maternal education and household food security were found to be protective against stunting and severe stunting. Stunting prevalence may vary across space at different scale. For this, it's important that nutrition studies and, more importantly, control interventions take into account this spatial heterogeneity in the distribution of nutritional deficits and their underlying associated factors. The findings of this study also indicated that interventions integrating household food insecurity in nutrition programs in the district might help to avert the burden of stunting.

2,2′-Dimethoxy-4,4′-[rel-(2R,3S)-2,3-di­methylbutane-1,4-diyl]diphenol

PubMed Central

Salinas-Salazar, Carmen L.; del Rayo Camacho-Corona, María; Bernès, Sylvain; Waksman de Torres, Noemi

2009-01-01

The title mol­ecule, C20H26O4, commonly known as meso-dihydro­guaiaretic acid, is a naturally occurring lignan extracted from Larrea tridentata and other plants. The mol­ecule has a noncrystallographic inversion center situated at the midpoint of the central C—C bond, generating the meso stereoisomer. The central C—C—C—C alkyl chain displays an all-trans conformation, allowing an almost parallel arrangement of the benzene rings, which make a dihedral angle of 5.0 (3)°. Both hydr­oxy groups form weak O—H⋯O—H chains of hydrogen bonds along [100]. The resulting supra­molecular structure is an undulating plane parallel to (010). PMID:21583141